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1107_Buncombe_MSWLF_CDLF_April22GW_FID1724979_20220921
DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander. PG RSM Phone: (864)288-1265 E-mail: andy.alexander(cDblecorp.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) 1107-MSWLF 1 Panther Branch Road -1996 .1600 Buncombe County Landfill Alexander, NC, 28701 April 26-28, 2022 1107-CDLF .0500 -1998 0 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, PG RSM Consultant Hydrogeologist (864) 288-1265 Facility Representative Name (Print) / Title (Area Code) Telephone Number A, 2022-09-21 Affix NC Licensed/ Professional Geologist Seal Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 • ���1111 CAR i NSF'titi 9 1 5 M' W A1.E�'.�`• �fIf1111111101 WATER QUALITY REPORT 1st SEMI-ANNUAL EVENT 2022 BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA Permit No. 1107-MSWLF-1996 Permit No. 1107-CDLF-1998 Prepared For: Buncombe County BLE Project Number J21-9378-26 ,�����irrrrrrrr�• September 2, 2022 `• �,'[H CAR f''•, f 5 ¢ - IDLO BLE North Carolina Business Licenses C-284 & C-1538 it IM IM 11UNNELL LAMMEINS ENGINEERmr. 6004 Ponders Court I Greenville, 5C 29515 864.288.1265 AI 854.288,433D 0 Info@hl2corp.com BLECQRMOM � CANNONS ENGINEERING September 2, 2022 Buncombe County Solid Waste Department 81 Panther Branch Road Alexander, North Carolina 28701 Attention: Ms. Kristy Smith Subject: Water Quality Report 11t Semi -Annual Event 2022 Buncombe County Landfill Alexander, North Carolina Permit Nos. 1107-MSWLF-1996 & BLE Project Number J21-9378-26 Dear Ms. Smith: 1107-CDLF-1998 Pursuant to authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J21-9378-26, dated June 22, 2021, BLE has prepared this water quality report for the 1st semi-annual sampling event of 2022 at the Buncombe County Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) approved monitoring program, sampling and analysis will be conducted twice in 2022. This report contains the information required by the DWM to document the sampling and analysis activities for the first event of 2022 in the State's permanent project record. Sincerely, BUNNELL LAMMONs ENGINEERING INC. Ivan A. Irizarry Staff Hydrogeolog t cc: Ms. Jaclynne Drummond — DWM-ARO Acl Andrew W. Ale der, P.G., RSM Consultant Hydrogeologist Registered, NC #1475 '6004 Panders Court, Greenvll€e, SC 29615 1,864,288.1265 r,-#864,288.4430 info@hlecorp,com BLECORP.COM 1s 1m 1i Water Quality Report — I sr Semi -Annual Event 2022 September 2, 2022 Buncombe County Landfill —Alexander, North Carolina BLE Project No. J21-9378-26 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 2 4.3 Leak Detectors and Leachate Samples............................................................................................. 2 5.0 CONCLUSIONS AND RECOMMENDATIONS....................................................................... 3 6.0 QUALIFICATIONS OF REPORT.............................................................................................. 3 7.0 CLOSING.......................................................................................................................................3 Tables Table 1 SWS Approved Sampling Matrix Table 2 Well Construction and Monitoring Well Data Table 3 Range of Groundwater Flow Velocities Table 4 Groundwater VOCs Table 5 Groundwater Field Parameters, Geochemical Parameters, and Total Metals Table 6 Surface Water VOCs Table 7 Surface Water Field Parameters and Total Metals Table 8 Leak Detector and Leachate VOCs Table 9 Leak Detector and Leachate Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — April 26 — 28, 2022 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Water Quality Report — I s' Semi -Annual Event 2022 Buncombe County Landfill —Alexander, North Carolina 1.0 PROJECT INFORMATION September 2, 2022 BLE Project No. J21-9378-26 The subject 654-acre landfill site is located in Buncombe County, North Carolina, approximately nine miles north of the city of Asheville with a physical address of 81 Panther Branch Road in Alexander, North Carolina. Buncombe County owns and operates a Subtitle D MSWLF which includes Cell 1 through Cell 6 and a CDLF consisting of Phase 1 through Phase 6. Currently Cell 6 of the MSWLF and Phase 6 of the CDLF are the active waste units. MSWLF Cell 7 and CDLF Phase 7 have been permitted and are under construction and MSWLF Cells 8 through 10 are planned (but not permitted) for future expansion. A Water Quality Monitoring Plan (WQMP) was finalized by BLE and submitted to the North Carolina Solid Waste Section (SWS). The WQMP was approved on April 16, 2021 (FID 1576846). The facility requires semi-annual groundwater, surface water, and leachate monitoring and reporting in accordance with the WQMP. Semi-annual sampling is typically conducted each April and October and those events are designated "Spring" and "Fall," respectively. This report represents the 1 st semi-annual (Spring) sampling event of 2022. The existing groundwater monitoring network for the Buncombe County Landfill consists of two (2) upgradient (background) wells (MW-1 and MW-1D) and twenty-four (24) downgradient (compliance) wells (MW-2, MW-2D, MW-3R, MW-4, MW-41), MW-5, MW-51), MW-6, MW-7, MW-8, MW-8D, MW-10, MW-IOD, MW-11, MW-11D, MW-12, MW-12D, MW-13, MW-13D, MW-14, MW-14D, MW-17R, MW- 17DR, and MW-18). Wells MW-17 and MW-17D were abandoned September 14, 2020 and replaced by MW-17R and MW-17DR respectively. Wells MW-15 and MW-15D were removed as compliance points and replaced by MW-18 as approved by the SWS on August 3, 2021 (FID 1595460). The MW-15/MW-15D well pair remains in place for the collection of water levels only. The current SWS approved sampling matrix is included as Table 1. In accordance with Rule .0602 and Rule .0544(c), eight (8) surface water monitoring locations have been established for the facility to monitor surface water quality surrounding the existing waste footprint (Table 1). The existing surface water locations consist of one (1) upstream (background) point (SW-1) and seven (7) downstream (compliance) points (SW-2 through SW-8). In accordance with Rule .1626(12)(c), eight (8) active leak detector and leachate sampling locations have been established for the facility (Table 1). The locations include six (6) existing leak detection sampling locations associated with each MSWLF cell (Cells 1 through 6) designated LD-1 through LD-6, one (1) leachate leak detection sampling location near the leachate pond designated Leachate LD, and the Leachate Pond itself. 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater, surface water, and leachate samples were collected for the 1 st semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina between April 26-28, 2022. Groundwater samples were collected from the 26 monitoring wells as specified on Table 1. The eight (8) surface water locations were sampled during the event. Additionally, the seven (7) leak detection and one (1) leachate pond locations were sampled. The groundwater, surface water, and leachate samples were delivered and analyzed in Pace's Columbia, South Carolina laboratory for the constituents in the approved matrix (Table 1). The field parameters of dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. 1 of 3 1s 1M 1i Water Quality Report — I s' Semi -Annual Event 2022 Buncombe County Landfill —Alexander, North Carolina 3.0 GROUNDWATER FLOW September 2, 2022 BLE Project No. J21-9378-26 The water level data collected during the sampling event on April 26-28, 2022 is presented in Table 2. Groundwater flow velocity estimates are presented in Table 3. A groundwater elevation contour map with generalized groundwater flow directions is presented in Figure 2. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized in Tables 4 and 5 and the laboratory analytical data is included in Appendix B. Please refer to Tables 4 and 5 for a summary of which groundwater constituents exceeded North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included pH, specific conductance, turbidity, and temperature. The field parameter of pH was below its NC2L standard in sixteen (16) wells. However, previous semi-annual reports for the subject site indicate that pH frequently varies between values both below and within the NC2L standards in the majority of the wells on site. No other field parameters were outside their NC2L standard limits for groundwater if established. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized in Tables 6 and 7 and the laboratory analytical data is included in Appendix B. Please refer to Tables 6 and 7 for a summary of which surface water constituents exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. The field parameter of turbidity exceeded its NC2B standards at three (3) locations. None of the other sampled field parameters exceeded their NC2B standard for surface water if established. 4.3 Leak Detectors and Leachate Samples The results of the leak detector field and laboratory analyses are summarized in Tables 8 and 9 and the laboratory analytical data is included in Appendix B. 'North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L.0202, April 1, 2022. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated July 26, 2022. 2 of 3 1s 1M 1i Water Quality Report — I s' Semi -Annual Event 2022 Buncombe County Landfill —Alexander, North Carolina September 2, 2022 BLE Project No. J21-9378-26 Please note that the NC2L standards shown on Tables 8 and 9 are for reference only. There is no regulatory standard for leak detectors or leachate. Field parameters measured in the leak detectors and leachate samples included pH, specific conductance, turbidity, and temperature. 5.0 CONCLUSIONS Semi-annual assessment monitoring was performed during the 1 st semi-annual event of 2022 in general accordance with the approved WQMP and SWS approved sampling matrix (Table 1). Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Buncombe County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other parry (excluding the DWM) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Buncombe County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 3 of 3 TABLES Table 1 SWS Approved Sampling Matrix Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 April October Station ID *Analytical Suite* 1,4-Dioxane *Analytical Suite* 1,4-Dioxane a MW-1 A-1 Plus A-1 Plus x � u Pa MW-ID A-1 Plus A-1 Plus MW-2 A-1 A-1 MW-21) A-1 A-1 MW-3R A-1 A-1 MW-4 A-1 yes A-1 yes MW-41) A-1 yes A-1 yes MW-5 A-1 A-1 MW-5D A-1 A-1 MW-6 A-1 A-1 MW-7 A-1 A-1 MW-8 A-1 A-1 MW-8D A-1 A-1 MW-10 A-1 yes A-1 yes MW-lOD A-1 yes A-1 yes MW-11 A-1 A-1 u e MW-11D A-1 A-1 UMW-12 A-1 Plus yes A-1 Plus yes MW-12D A-1 Plus yes A-1 Plus yes MW-13 A-1 A-1 MW-13D A-1 A-1 MW-14 A-1 Plus A-1 Plus MW-14D A-1 Plus A-1 Plus MW-15 W W MW-15D W W MW-16 A-1 yes A-1 yes MW-16D A-1 yes A-1 yes MW-17 Abandoned September 14, 2020 MW-17D Abandoned September 14, 2020 MW-17R A-1 Plus yes A-1 Plus yes MW-17DR A-1 Plus yes A-1 Plus yes MW-18 A-1 Plus yes A-1 Plus yes SW-1 A-1 yes A-1 yes SW-2 A-1 yes A-1 yes SW-3 A-1 yes A-1 yes d SW-4 A-1 yes A-1 yes o SW-5 A-1T yes A -IT yes SW-6 A-1T yes A -IT yes SW-7 A-1 yes A-1 yes SW-8 A-1T yes A -IT yes LD-1 A-1 A-1 i, LD-2 A-1 A-1 0 LD-3 A-1 A-1 Ca R LD-4 A-1 A-1 u �? LD-5 A-1 A-1 yes d R LD-6 A-1 A-1 u LD-7 A-1 A-1 .a Leachate LD A-1 A-1 Leachate Pond LMP LMP Notes: A-1 —Appendix I VOCs & Metals A -IT = Appendix I VOCs plus Tetrahydrofuran & Metals A-1 Plus = Appendix I VOCs plus Tetrahydrofuran, & Metals plus Mercury, Manganese, Iron, Sulfate, Chloride, Alkalinity, & Total Dissolved Solids LMP (Leachate Monitoring Parameters) = Appendix I VOCs & Metals, pH, specific conductance, BOD, COD, Nitrates, Sulfates, & Phosphates. W = Water Level Only LD = Leak Detector Does Not Exist - Permitted for Future MSWLF Cell 7 1,4-Dioxane removed for these points Table revised July 16, 2019 (SW-8 and 1,4-doxane) Table revised February 27, 2020 (BLE Project No. 9378-20 for Spring 2020) Table revised June 19, 2020 (Change 1,4-Dioxane Matrix) Table revised October 14, 2020 (Abandon MW-17/MW-17D) Table revised July 20, 2021 (Remove MW-15/MW-15D & add MW-18) Prepared by: AWA Checked by: TJD S:\Buncombe County Active LF, NC\9378-26B FY22 Spring 2022 Report\04 Tables\9378-26 SWS Approved Matrix Table 2 Well Construction and Monitoring Well Data Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Monitoring Point MSW or C&D Latitude Longitude Northing' Easting' TOC Elevation (ft)' Ground Surface Elevation (ft)' Depth to GW (ft) April 24-28, 2022 Groundwater Elevation (ft) Well Depth (ft)' Screen Depth (below GS)' Waste Unit Monitored Installation Date' Geology Monitored' Well Status/Purpose Well Diameter (in)' MW-1 Facility 33.570245 -85.567196 737,383.3 923,481.5 2021.22 2019.28 65.66 1955.56 76 61.0 - 76.0 Facility 1990's Saprolite/PWR Background 2.0 MW-11) Facility 33.570242 -85.567236 737,371.0 923,468.7 2021.57 2019.97 67.20 1954.37 200 85.0 - 95.0 Facility 1990's Bedrock Background 2.0 MW-2 MSW 33.570284 -85.566586 739,569.6 921,033.3 1920.86 1918.54 8.12 1912.74 20 5.0 20.0 Cell 1990's Saprolite/PWR Compliance 2.0 MW-21) MSW 33.570283 -85.566599 739,565.7 921,027.7 1920.51 1918.63 8.71 1911.80 55 45.0 - 55.0 Cell 1990's Bedrock Compliance 2.0 MW-3R MSW 33.570271 -85.566817 739,499.1 920,384.3 1973.18 1975.67 54.23 1918.95 55 45.0 - 55.0 Cell 7/28/2014 PWR Compliance 2.0 MW-4 MSW 33.570228 -85.567590 739,263.0 920,192.1 1944.35 1942.48 13.30 1931.05 25 9.0 24.0 Cell 1011011996 Saprolite/PWR Compliance 2.0 MW-41) MSW 33.570228 -85.567597 739,261.0 920,177.3 1944.64 1942.79 14.82 1929.82 55 45.0 - 55.0 Cell 1011111996 Bedrock Compliance 2.0 MW-5 MSW 33.570201 -85.568087 739,111.5 920,246.7 1977.12 1975.39 33.75 1943.37 50 35.0 - 50.0 Cell 101911996 Saprolite/PWR Compliance 2.0 MW-51) MSW 33.570199 -85.568112 739,103.6 920,242.3 1976.92 1975.31 35.50 1941.42 81 71.0 - 81.0 Cell 1011011996 Bedrock Compliance 2.0 MW-6 MSW 33.570317 -85.565937 738,767.9 920,223.6 1987.34 1985.39 24.76 1962.58 50 35.0 - 50.0 Cell 101811996 Saprolite/PWR Compliance 2.0 MW-7 MSW 33.570230 -85.567514 738,286.3 920,586.8 2022.83 2020.72 42.51 1980.32 61 42.0 - 61.0 Cell 101411996 Saprolite/PWR Compliance 2.0 MW-8 MSW 33.570196 -85.568117 738,102.0 920,801.7 1962.06 1959.85 30.62 1931.44 70 55.0 - 70.0 Cell 1990's Saprolite/PWR Compliance 2.0 MW-81) MSW 33.570199 -85.568069 738,116.7 920,812.0 1962.47 1960.57 29.61 1932.86 95 85.0 - 95.0 Cell 1990's Bedrock Compliance 2.0 MW-10 MSW 33.570239 -85.567391 739,324.0 921,597.0 2010.54 2007.50 67.75 1942.79 73 58.0 - 73.0 Cell 3/6/2002 Saprolite/PWR Compliance 2.0 MW-101) MSW 33.570239 -85.567391 739,324.0 921,590.8 2010.56 2007.50 68.15 1942.41 117 102.0 - 117.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-11 MSW 33.570208 -85.567897 738,169.2 921,422.1 1966.71 1963.70 32.77 1933.94 50 35.0 - 50.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-111) MSW 33.570206 -85.567947 738,154.0 921,406.0 1966.15 1963.20 34.08 1932.07 70 60.0 - 70.0 Cell 3/6/2002 Bedrock Compliance 2.0 MW-12 C&D 33.570306 -85.566147 738,703.7 919,192.4 1947.39 1944.70 12.30 1935.09 17 7.0 17.0 Phases 1 - 5 6/25/2002 Saprolite/PWR/Bedrock Compliance 2.0 MW-12D C&D 33.570269 -85.566849 739,489.5 921,966.6 1947.10 1944.30 12.85 1934.25 37 27.0 - 37.0 Phases 1 - 5 6/25/2002 Bedrock Compliance 2.0 MW-13 MSW 33.570269 -85.566849 739,489.5 921,966.6 1953.92 1951.30 4.28 1949.64 16 6.0 16.0 Cell 612412005 Bedrock Compliance 2.0 MW-13D MSW 33.570316 -85.565957 738,761.6 919,055.7 1953.82 1951.40 7.02 1946.80 44 39.0 - 44.0 Cell 6/23/2005 Bedrock Compliance 2.0 MW-14 C&D 33.570320 -85.565889 738,782.5 919,037.1 1952.77 1949.80 29.52 1923.25 49 39.0 - 49.0 Phases 1 -5 4/5/2006 Bedrock Compliance 2.0 MW-14D C&D 33.570306 -85.566147 738,703.7 919,192.4 1953.76 1950.70 29.99 1923.77 88 78.0 - 88.0 Phases 1 - 5 4/6/2006 Bedrock Compliance 2.0 MW-15 C&D 33.570207 -85.567982 739,143.4 919,829.3 1973.29 1970.21 21.41 1951.88 26 16.0 - 26.0 Phases 1 - 5 6/7/2012 Saprolite/PWR WL 2.0 MW-15D C&D 33.570207 -85.567982 739,143.4 919,829.3 1973.51 1970.25 25.02 1948.49 43 33.0 - 43.0 Phases 1 - 5 6/7/2012 Bedrock WL 2.0 MW-17 Abandoned - September 14, 2020 MW-17D Abandoned - September 14, 2020 MW-17R C&D 33.570283 -85.566553 738,579.7 918,662.0 1891.61 1888.96 15.25 1876.36 23.5 8.5 23.5 Phase 6 9/3/2020 Bedrock Compliance 2.0 MW-17DR C&D 33.570281 -85.566586 738,569.7 918,659.3 1891.70 1889.14 13.48 1878.22 39 34.0 - 39.0 Phase 6 9/2/2020 Bedrock Compliance 2.0 MW-18 C&D 33.570214 -85.567851 739,183.2 919,705.2 1940.67 1937.97 44.62 1896.05 51.5 41.5 - 51.5 Phases 1 - 5 6/11/2008 Bedrock Compliance 2.0 ' - Data from Table 3, Well Construction, New Buncombe County Landfill, Buncombe County, North Carolina, provided by SCS Engineers. Z - Based on visual observation of Sheet No I Groundwater and Methane Monitoring Well Locations by CDM Smith dated August 2014. Some well installation dates appear inconsistent with water level records and may not be accurate. Changes to some dates (italics) made based on water level records and dates from SHR and DHR documents by CDM. The top of casing and ground surface elevations for MW-3R are a probable error (reversed) based on April 2016 water levels in the SCS Engineers report. The top of casing and ground surface elevations for MW-14 and MW-14D do not match those in the SHR and DHR documents by CDM. The well construction and survey data for MW-17R and MW-17DR are from a report by SCS dated October 13, 2020 Location accuracy of the monitoing wells is limited by the references themselves The well construction data for MW-18 from the DHR table and boring log by CDM. Surveying was performed by Ed Holmes and Associates of Asheville, NC in September 2021. TOC - Top of Casing. GS - Ground Surface. All depth measurments in feet -- All elevations in feet above an arbitrary site datum 9378-26B GW Tables (Completion, water levels, detections) Prepared by: IAI T2 (4-28-22) MW Points Checked by: RLB/AWA Table 3 Range of Groundwater Flow Velocities Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Hydraulic Conductivity K(ft/min) K(cm/sec) K(ft/day) High Estimate 8.0E-03 4.1E-03 11.5 Low Estimate 9.7E-05 4.9E-05 0.14 Geometric Mean 8.8E-04 4.5E-04 1.269 Geometric Mean Hydraulic Conductivity K(ft/day) Hydraulic Grad. (ft/ft) Effective Porosity Flow Vel. (ft/day) Flow Vel. (ft/year) High Estimate 1.269 0.308 5% 7.81 2,850 Low Estimate 1.269 0.025 28% 0.12 42 Notes 1. Hydraulic conductivity and effeictive porosity values obtainted from Tables 5 and 6 of the Design Hydrogeologic Report - Phase 6 C&D prepared by BLE dated September 21, 2017. 3. The hydraulic gradients were measured from the April 24-26, 2021 groundwater elevation contour map (Figure 2). The high hydraulic gradient was measured between the 1880-ft & 1900-ft groundwater contours near MW-17R . The low hydraulic gradient was measured between the 1950-ft & 1960-ft groundwater contours near MW-12. 4. Groundwater velocity derived from V = Ki/n, where: K = geometric mean hydraulic conductivity, i = hydraulic gradient, and n, = effective porosity. 5. The high and low velocity estimates are calculated using the geometric mean K and the high and low range of site hydraulic data obtained from BLE's 2017 DHR. 9378-26B GW Tables (Completion, water levels, detections) Prepared By: IAI Table 3 GW Flow Vel. Checked By: RLB/AWA Table 4 Groundwater VOCs Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Sampled by Pace Analytical Services, LLC. April 26-28, 2022 TEST UNITS LOQ DL MCL MW-1 MW-ID MW-2 MW-21) MW-311 MW4 MW4D KW-5 MW-51) KW-6 MW-7 KW-8 MW-81) MW-10 MW-IOD KW-11 MW-11D MW-12 MW-12D MW-13 MW-13D MW-14 MW-14D MW-15 MW-15D MW-17R MW-17DR MW-18 EQUIP. BLANK Acetone µg" 20 5.0 6,000 7.1 JL <5.0 15.0 <5.0 <5.0 6.0 JL <5.0 <5.0 <5.0 5.0 JL 5.1 JL <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Ili <5.0 <5.0 <5.0 <5.0 <5.0 NS NS <5.0 <5.0 <5.0 <5.0 Acrylonitrile 99/1 20 0.8 NE <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 NS NS <0.8 <0.8 <0.8 <0.8 Benzene µg" 1.0 0.4 1.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Bromochloromethane 99/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Bromodichloromethane 99/1 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Bromoform µg/1 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/1 1.0 0.4 700 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.81 J <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 1 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) 99/1 2.0 0.4 10 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µg" 1.0 0.4 0.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 1 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µg/l 1.0 0.4 50.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Chloroethane 99/1 2.0 0.4 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Chloroform µg/1 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µg/1 1.0 0.5 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NS NS <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µg/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µg/1 1.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1,2-Drbromoethane; Ethylene dibromide µg" 1.0 0.4 0.02 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 1 <0.4 <0.4 <0.4 Dibromomethane µg/1 1.0 0.4 70.0 (i) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 112-Dichlorobenzene 99/1 1.0 0.4 20 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene 99/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 1 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2-butene 99/1 2.0 0.5 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NS NS <0.5 <0.5 <0.5 <0.5 1,1-Dichloroethane 99/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.42 J <0.4 <0.4 <0.4 0.65 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane µg/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1, 1-Dichlomethene (-ethylene) µg/1 1.0 0.4 350 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µg" 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µg" 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 1 <0.4 <0.4 <0.4 1,2-Dichloropropane µg/1 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichlmopropene (-propylene) 99/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) 99/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Ethylbenzene 99/1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 2-Hexanone 99/1 10 2.0 40 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 NS NS <2.0 <2.0 <2.0 <2.0 Iodomethane µg/l 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µg/l 1.0 0.4 5.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/l 10 2.0 4,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 NS NS <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µg/l 10 2.0 100 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 1 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 NS NS <2.0 <2.0 <2.0 <2.0 Styrene 99/1 1.0 0.41 70 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachloroethane 99/1 1.0 0.4 1.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1, 1,2,2-Tetrachloroethane µg/1 1.0 0.4 0.2 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µg/1 1.0 0.4 0.7 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Toluene 99/1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1, 1, 1 -Trichloroethane µg/1 1.0 0.4 200 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/1 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) 99/1 1.0 0.4 3.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µg" 1.0 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane 99/1 1.0 0.4 0.005 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Vinyl acetate 99/1 5.0 1.2 88.0 (i) <1.2 <1.2<1.2 <1.2<1.2 <1.2<1.2 <1.2<1.2 <1.2<1.2 <1.2<1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 NS NS <1.2 <1.2 <1.2 <1.2 Vinyl chloride 99/1 1.0 0.4 0.03 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Total Xylenes µg" 1.0 0.4 500 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 NS NS <0.4 <0.4 <0.4 <0.4 Tetrahydrofuran 99/1 5.0 1.0 2,000 (1) <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 2.1 J 1.0 J <1.0 <1.0 <1.0 <1.0 NS NS <1.0 <1.0 <1.0 <1.0 1,4-Dioxane µ 1 3.0 1.0 3.0 NT NT NT NT NT 1.1 J <1.0 NT NT NT NT NT NT <1.0 <1.0 NT NT 2.1 J 1.6 J NT NT NT NT NS NS <1.0 <1.0 <1.0 <1.0 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDEQ, Groundwater Classifications and Standards Section 15A NCAC 21, .0202. Updated April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate excmdances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = method Detection Limit 8. NT = Not Tested 9. NS = Not Sampled 10. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 11. "L" flagged data denote LCS/LCSD failure 9378-26B GW Tables (Completion, water levels, detections) Prepared by: IAI T4 (4-28-22) VOC Checked by: RLB/AWA Table 5 Groundwater Field Parameters, Geochemical Parameters, and Total Metals Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Sampled by Pace Analytical Services, LLC. April 26-28, 2022 TEST UNITS LOQ DL MCL MW-1 MW-1D MW-2 MW-2D MW-3R MW-4 MW-4D MW-5 MW-5D MW-6 MW-7 MW-8 MW-8D MW-10 MW-10D MW-11 MW-11D MW-12 MW-12D MW-13 MW-13D MW-14 MW-14D MW-15 MW-15D MW-17R MW-17DR MW-18 EQUIP. BLANK pH S.U. <6.5; >8.5 6.4 7.4 6.3 6.5 6.2 6.2 7.2 6.0 6.0 5.8 6.3 6.3 6.3 6.0 6.4 6.4 6.5 6.5 6.5 6.6 6.3 6.2 7.3 NS NS 6.3 7.1 6.6 NT Specific Conductance µmhos/cm NE 181.7 258.4 366.6 260.7 112.7 259.5 253.6 232.3 201.6 139.2 714.0 385.8 442.6 296.6 394.5 450.6 425.9 1,043 677.0 391.4 334.7 183.5 334.3 NS NS 209.3 288.6 223.5 NT Temperature °C NE 20.6 24.8 17.2 10.9 15.8 20.8 20.2 16.7 16.0 14.9 16.1 19.6 13.2 15.7 17.3 18.9 22.0 14.1 14.8 15.2 15.7 18.2 14.6 NS NS 13.2 18.4 18.7 NT Turbidity NTU NE 8.4 9.2 9.5 0.1 9.0 2.9 0.6 8.4 0.1 5.6 7.3 9.8 1.7 5.6 4.0 8.8 9.5 1.7 1.4 4.1 5.3 8.6 2.1 NS NS 2.4 2.5 9 NT Alkalinity mg/1 20 20 NE 62 93 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 300 200 NT NT 71 150 NS NS 76 130 83 NT Total Dissolved Solids (TDS) mg/1 25 25 500 130 180 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 770 470 NT NT 97 130 NS NS 150 77 150 NT Iron H (Fe 2) µ 50 13 300 1,700 150 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 170 180 NT NT 540 130 NS NS 130 280 260 NT Sulfate mg/l 1.0 0.25 250 18 39 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 280 B 140 NT NT 19 30 NS NS 30 23 32 NT Chloride mg/l 1.0 0.25 250 6.3 2.5 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 33 20 NT NT 2.5 4.1 NS NS 2.8 4.1 1.7 NT Total Antimony (Sb) µg/I 2.0 0.5 1.0 <0.5 0.55 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.68 J <0.5 1.8 J <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NS NS <0.5 <0.5 <0.5 <0.5 Total Arsenic (As) µg/l 2.0 1.3 10 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 NS NS <1.3 <1.3 <1.3 <1.3 Total Barium (Ba) µgfl 5.0 1.3 700 150 34 140 110 70 97 36 120 68 50 170 150 170 27 130 120 45 67 90 170 83 51 6.9 NS NS 61 73 14 <1.3 Total Beryllium (Be) µg/l 0.4 0.15 4.0 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NS NS <0.2 <0.2 <0.2 <0.2 Total Cadmium (Cd) µgfl 0.5 0.13 2.0 <0.1 <0.1 0.31 J <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 NS NS <0.1 <0.1 <0.1 <0.1 Total Chromium (Cr) µg/l 5.0 1.3 10 5.4 <1.3 2.4 J <1.3 2.6 J 1.7 J <1.3 2.5 J <1.3 <1.3 <1.3 4.8 J <1.3 1.5 J 3.9 J <1.3 <1.3 3.3 J 1.3 J <1.3 <1.3 1.3 J 1.4 J NS NS <1.3 <1.3 1.6 J <1.3 Total Cobalt (Co) µg/I 5.0 1.3 1.0 1.3 J <1.3 5 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.6 J <1.3 <1.3 <1.3 2.5 J 6.9 <1.3 43 4.3 J 24 4.3 J <1.3 <1.3 NS NS <1.3 <1.3 <1.3 <1.3 Total Copper (Cu) µg/1 5.0 1.3 11000 4.7 J <1.3 1.5 J <1.3 <1.3 1.5 J <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 3.5 J 2.5 J 1.8 J 3.7 J <1.3 <1.3 <1.3 <1.3 <1.3 NS NS 4.1 J 1.8 J 1.5 J <1.3 Total Lead (Ph) µgfl 1.0 0.25 15 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 0.40 J 1.9 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 NS NS <0.3 <0.3 <0.3 <0.3 Total Manganese (Mn) µg/1 5.0 1.3 50 24 18 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT 3,500 510 NT NT 7.7 11 NS NS 31 66 47 NT Total Mercury (Hg) µgfl 0.20 0.091 1.0 <0.1 <0.1 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT <0.1 <0.1 NT NT <0.1 <0.1 NS NS <0.1 <0.1 <0.1 NT Total Nickel (Ni) µg/I 5.0 1.3 100 3.9 J 3.0 J 14 <1.3 3.4 J 5 <1.3 3.9 J 3.7 J <1.3 11 4.8 J 4.1 J 6.6 9.5 28 4.6 J 35 8 5.8 1.8 J 2.6 J <1.3 NS NS 14 <1.3 1.8 J <1.3 Total Selenium (Se) µg/I 5.0 1.3 20 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 NS NS <1.3 <1.3 1.3 J <1.3 Total Silver (Ag) µg/l 1.0 0.25 20 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 NS NS <0.3 <0.3 <0.3 <0.3 Total Thallium (Tl) µg/I 0.5 0.15 2.0 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NS NS <0.2 <0.2 <0.2 <0.2 Total Vanadium (V) µg/1 5.0 2.5 7.0 6.7 <2.5 3.2 J 2.5 J 3.6 J <2.5 3.5 J 2.7 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 3.6 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 3.4 J <2.5 NS NS <2.5 <2.5 <2.5 <2.5 Total Zinc (Zn) ggf, 10 2.5 1,000 9.1 J 2.7 J 6.2 J 2.9 J <2.5 <2.5 <2.5 6.2 J <2.5 2.5 J 2.5 J 7.0 J <2.5 13 33 11 11 3.5 J <2.5 <2.5 3.6 J <2.5 2.7 J NS NS 7.8 J <2.5 4.2 J <2.5 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDEQ, Groundwater Classifications and Standards Section 15A NCAC 2L .0202. Updated April 1, 2022 2. (i) =Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quanfitation 7. DL = method Detection Limit 8. NT = Not Tested 9. NS = Not Sampled 10. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 11. 'B"-flagged data detected in the method blank.. 9378-26B GW Tables (Completion, water levels, detections) Prepared by: IAI T5 (4-28-22) Metals Checked by: RLB/AWA Table 6 Surface Water VOCs Buncombe County Landfill Alexander, North Carolina Permit No.1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-23 Sampled by Pace Analytical Services, LLC. April 26-28, 2022 TEST UNITS LOQ DL NC2B SW-1 SW-2 SW-3 SW4 SW-5 SW-6 SW-7 SW-8 Acetone µg/l 20 5.0 2,000 <5.0 <5.0 19 J 8.1 J 16 J 5.8 J 16 HJ <5.0 Acrylonitrile AgIl 20 0.8 7 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/1 1.0 0.4 51 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromochloromethane AgIl 1.0 0.4 NE <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane 99ft 1.0 0.4 17 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform AgIl 1.0 0.4 120 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/1 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µg/l 2.0 0.4 0.04 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µgFl 1.0 0.4 1.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) AgIl 1.0 0.4 800 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 2.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/l 1.0 0.4 2,000 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µgFl 1.0 0.5 96 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane AgIl 1.0 0.4 21 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µg/1 1.0 0.4 0.13 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide AgIl 1.0 0.4 0.1 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µgFl 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene AgIl 1.0 0.4 3,000 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µg/1 1.0 0.4 900 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2butene µ 2.0 0.5 NE <0,5 <0.5 <0,5 <0.5 <0.5 <0.5 <0.5 <0.5 1,1-Dichloroethane µgFl 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane AgIl 1.0 0.4 650 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichloroethene(-ethylene) 99/1 1.0 0.4 20,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µ 1.0 0.4 720 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µgFl 1.0 0.4 4,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloro ro ane AgIl 1.0 0.4 31 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloro roene (-propylene) µ 1.0 0.4 NE <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µgFl 1.0 0.4 97 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone AgIl 10 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 lodomethane µgFl 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µ 1.0 0.4 11000 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/l 10 2.0 26,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Meth-2-Pentanone AgIl 10 2.0 26000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µgFl 1.0 0.41 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachloroedme AgIl 1.0 0.4 NE <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1,2,2-Tetrachloroethane 99/1 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µgFl 1.0 0.4 3.3 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µgFl 1.0 0.4 11 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,1-Trichloroethane AgIl 1.0 0.4 200,000 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/1 1.0 0.4 8.9 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) AgIl 1.0 0.4 30 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µgFl 1.0 0.4 67,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloro ro ane AgIl 1.0 0.4 0.001 <0,4 <0.4 <0,4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/1 5.0 1.2 NE <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µ911 1.0 0.4 2.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Total Xylenes µgFl 1.0 0.4 670 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrahydrofuran AgIl 5.0 1.0 110,000 NT NT NT NT 2.0 J <1.0 NT <1.0 1,4-Dioxane AgIl 3.0 1.0 80 <1.0 <1.0 26 <1.0 6.1 <1.0 1.0 J <1.0 Noter• 1. NC2B = North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 2B. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-21) 2. NE = Not Established; North Carolina has not established a MCL 3. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 4. Shaded cells indicated exceedances of MCLs 5. LOQ = Limit of Quantitation 6. DL = Method Detection Limit 7. NT = Not Tested 8. DNA = Data Not Available 9 "H"- Sample out of hold time 9378-26B SW Tables Prepared by: IAI T6 SW VOC (4-28-22) Checked by: RLB/AWA Table 7 Surface Water Field Parameters and Total Metals Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Sampled by Pace Analytical Services, LLC. April 26-28, 2022 TEST UNITS LOQ DL NC2B SW-1 NC2B SW-2 NC2B SW-3 NC2B SW4 NC2B SW-5 NC2B SW-6 NC2B SW-7 NC2B SW-8 pH s.u. (on -site) - - <6.0; >9.0 6.9 <6.0; >9.0 7.4 <6.0; >9.0 8 <6.0; >9.0 7.4 <6.0; >9.0 8.0 <6.0; >9.0 7.70 <6.0; >9.0 7.9 <6.0; >9.0 7.6 Specific Conductance µmhos/cm (on -site) - - NE 128.8 NE 205.6 NE 2,124 NE 366.3 NE 1,423 NE 356.6 NE 1,884 NE 170.8 Temperature °C (on -site) - - 29 15.6 29.0 13.2 29.0 18.7 29.0 12.9 29.0 18.1 29.0 13.2 29.0 14.2 29.0 12.3 Turbidity NTU (on -site) - - 50 12.4 50.0 46.9 50.0 423.4 50.0 62.1 50.0 21.7 50.0 74.50 50.0 43.8 50.0 11.9 Hardness mg/1 10 2.0 NE NT NE NT NE NT NE NT NE NT NE NT NE NT NE NT Total Antimony (Sb) µgd 2.0 0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 640 <0.5 Total Arsenic (As) µg/l 2.0 1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 10 <1.3 Total Barium (Ba) µg/l 5.0 1.3 21,000 110 21,000 82 21,000 280 21,000 120 21,000 160 21,000 150 21,000 210 21,000 51 Total Beryllium (Be) µgd 0.4 0.15 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 65 <0.2 Total Cadmium (Cd) µg/l 0.5 0.13 0.79 <0.1 1.6 <0.1 3.7 <0.1 3.9 <0.1 17 <0.1 5.0 <0.1 52 <0.1 4.6 <0.1 Total Chromium (Cr) µg/l 5.0 1.3 177 <1.3 344 4.2 J 751 11 794 6.7 3,160 5.7 1,005 5.4 9,235 24 922 1.4 J Total Cobalt (Co) µg/l 5.0 1.3 16 2.2 J 16 1.8 J 16 12 16 4.2J 16 11 16 5.1 16 39 16 <1.3 Total Copper (Cu) µg/l 5.0 1.3 3.5 <1.3 33 2.9 J 18 6.2 20 5 96 1.4 J 26 3.4 J 331 21 23 3.0 J Total Lead (Ph) µg/l 1.0 0.25 13 0.75 J 1.3 0.68 J 93 1.9 100 1.6 569 <0.3 136 0.94 J 1,831 <0.3 122 <0.3 Total Nickel (Ni) µg/l 5.0 1.3 140 <1.3 278 4.0 J 622 31 660 7.8 2,748 13 842 9.5 8,320 55 770 <1.3 Total Selenium (Se) µg/l 5.0 1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 Total Silver (Ag) µg/l 1.0 0.25 0.28 <0.3 1.1 <0.3 5.7 <0.3 6.5 <0.3 117 <0.3 11 <0.3 1,117 <0.3 8.8 <0.3 Total Thallium (Tl) µg/l 0.5 0.15 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 NE <0.2 Total Vanadium (V) µg/l 5.0 2.5 NE 3.8 J NE 6.7 NE 12 NE 10 NE 2.8 J NE 8.1 NE <2.5 NE 2.9 J Total Zinc (Zn) l 10 2.5 35 2.7 J 70 5.0 J 156 19 165 10 695 <2.5 211 6.9 J 2,091 13 J 193 <2.5 Notes: 1. NC213 = North Carolina Surface Water Standards for Class C freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-21) Measured values of hardness were utilized to calculate an acute standard at each surface water location for metals highlighted in green. Hardness values were reported in Report of Water Quality Sampling and Analysis 1st Semi -Annual Event 2020 Buncombe County Landfill Alexander, North Carolina prepared by BLE, dated July 13, 2020. 2. NE = Not Established; North Carolina has not established a standard 3. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 4. Shaded cells indicated exceedances of MCLs 5. LOQ = Limit of Quantitation 6. DL = Method Detection Limit 7. NT = Not Tested 8. DNA = Data Not Available 9378-26B SW Tables T7 SW Metals (4-28-22) Prepared by: IAI Checked by: RLB/AWA Table 8 Leak Detector and Leachate VOCs Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Sampled by Pace Analytical Services, LLC. April 26-28, 2022 TEST UNITS LOQ DL MCL LD-1 LD-2 LD-3 LD-4 LD-5 LD-6 Leachate LD Leachate Pond Acetone µg/1 20 5.0 6,000 8.3 JL 15.0 <5.0 10 JL <5.0 <5.0 <5.0 36 Acrylonmile µ 1 20 0.8 NE <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/1 1.0 0.4 LO 1.9 0.71 J <0.4 2.3 <0.4 <0.4 <0.4 0.46 J Bro atchloromethane µ 1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane 99/1 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µ 1 1.0 0.4 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide 99/1 1.0 0.4 700 <0.4 <0.4 <0.4 <0.4 <0.4 0.42 J <0.4 0.51 J Bromomethane (Meth bromide) µ 1 2.0 0.4 10 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride 99/1 1.0 0.4 0.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (m mo) µ 1 1.0 0.4 50 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 2.0 0.4 3,000 0.65 J 0.44 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µ 1 1.0 0.4 70.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylohloride) 99/1 1.0 0.5 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µ I 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chlompropane; DBCP 99/1 1.0 0.4 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane, Ethylene dibromide µ 1 1.0 0.4 0.02 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/1 1.0 0.4 70.0 (1) <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlmobenzene µ 1 1.0 0.4 20.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Diehlorobenzene 99/1 1.0 0.4 6.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.85 J trans-1,4-Dichloro-2butene µ 1 2.0 0.5 NE <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 1,1-Diehloroethane 99/1 1.0 0.4 6.0 0.43 J 1.3 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlomethane µ 1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1-Dichlomethene(-ethylene) 99/1 1.0 0.4 7.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene(-ethylene) µ 1 LO 0.4 70 <0.4 0.71 J <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) 99/1 1.0 0.4 100 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlororo ane µ 1 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) 99/1 1.0 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichlor ro ene (-propylene) µ 1 LO 0.4 0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbeozene µg/1 1.0 0.4 600 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 0.68 J 2-Hexanone µ 1 10 2.0 40 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Iodomethane µg/I 5.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µ 1 1.0 0.4 5.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/1 10 2.0 4000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µ 1 10 2.0 100 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2.2 J Styrene 99/1 1.0 0.41 70 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachlorcethane µ 1 1.0 0.4 1.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1,2,2-Tetrachloroethane 99/1 1.0 0.4 NE <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachlomethene (-eda ene) µ I 1.0 0.4 0.7 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µg/1 1.0 0.4 600 <0.4 <0.4 <0.4 0.45 J <0.4 <0.4 <0.4 0.93 J 1,1,1-Trichloroethane µ 1 1.0 0.4 200 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trlchloroethane 99/1 1.0 0.4 0.6 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) µ 1 LO 0.4 3.0 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane 99/1 1.0 0.4 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichlororo ane µ 1 LO 0.4 0.005 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate 99/1 5.0 1.2 88.0 (i) <1.2 <1.2 <1.2 11.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µ 1 LO 0.4 0.03 <0.4 <0.4 <0.4 0.86 J <0.4 <0.4 <0.4 <0.4 Total Xylenes µg/1 1.0 0.4 500 <0.4 <0.4 <0.4 0.50 J <0.4 <0.4 <0.4 2.1 1,4-dioxane l 1 3.0 1 1.0 1 3.0 1 <1.0 I <1.0 I <1.0 I <1.0 I <1.0 I <1.0 I <1.0 I <1.0 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate-codances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE=Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Qmmitatlon 7. DL = method Deteaion Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 10. "IT flagged data denote LCS/LCSD failure 9378-26B Leachate Tables Prepared by IM T8 LD VOC (4-28-22) Checked by. RLB/AWA Table 9 Leak Detector and Leachate Field Parameters and Total Metals Buncombe County Landfill Alexander, North Carolina Permit No. 1107-CDLF-1998 Permit No. 1107-MSWLF-1996 BLE Project Number J21-9378-26 Sampled by Pace Analytical Services, LLC. April 26-28, 2022 TEST UNITS LOQ DL MCL LD-1 LD-2 LD-3 LD-4 LD-5 LD-6 Leachate LD Leachate Pond pH s.u. units (on -site) <6.5; >8.5 6.6 5.9 6.5 6.6 7.2 6.5 4.5AN 8.3 Specific Conductance µmhos/cm (on -site) NE 4,069 485.2 695 3,436 729 538 436.2 6,170 Temperature °C (on -site) NE 15.9 17.5 18.1 19.6 16.7 20.2 14.6 24.2 Turbidity NTU (on -site) NE 27.1 5.5 4.4 21.1 96.5 21.8 2.5 105.1 Biologic Oxygen Demand (BOD) mg/1 2.0 0.2 NE NT NT NT NT NT NT NT 71 Chemical Oxygen Demand (COD) mg/1 80 80 NE NT NT NT NT NT NT NT 770 Nitrates mg/1 0.2 0.05 10 NT NT NT NT NT NT NT <0.05 Sulfates mg/1 1.0 0.25 250 NT NT NT NT NT NT NT 21 Phosphates mg/1 0.1 0.04 NE NT NT NT NT NT NT NT 2.5 Total Antimony (Sb) µg/1 2.0 0.5 1.0 <0.5 <0.5 <0.5 3.2 J <0.5 <0.5 <0.5 12 J Total Arsenic (As) µg/1 2.0 1.3 10 1.3 J <1.3 <1.3 4.2 <1.3 <1.3 2.2 32 Total Barium (Ba) µg/1 5.0 1.3 700 1700 180 230 490 57 380 30 470 Total Beryllium (Be) µg/1 0.4 0.15 4.0 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 0.37 J <0.15 Total Cadmium (Cd) µg/1 0.5 0.13 2.0 <0.13 <0.13 <0.13 0.34 J <0.13 <0.13 0.16 J <0.13 Total Chromium (Cr) µg/1 5.0 1.3 10 2.5 J <1.3 <1.3 400 <1.3 <1.3 <1.3 86 Total Cobalt (Co) µg/1 5.0 1.3 1.0 260 59 4.6 J 80 22 64 38 21 J Total Copper (Cu) µg/1 5.0 1.3 1,000 <1.3 2.0 J <1.3 140 <1.3 <1.3 11 <1.3 Total Lead (Pb) µg/1 1.0 0.25 15 <0.25 <0.25 <0.25 1.5 J <0.25 <0.25 <0.25 <0.25 Total Mercury (Hg) µg/1 NT NT 1.0 NT NT NT NT NT NT NT NT Total Nickel (Ni) µg/1 5.0 1.3 100 74 11 2.0 J 220 10 2.7 J 270 82 Total Selenium (Se) µg/1 5.0 1.3 20 2.3 J <1.3 <1.3 <1.3 <1.3 <1.3 2.5 J <1.3 Total Silver (Ag) µg/1 1.0 0.25 20 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 Total Thallium (Tl) µg/1 0.5 0.15 2 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Total Vanadium (V) µg/1 5.0 2.5 7 <2.5 <2.5 <2.5 17 <2.5 <2.5 <2.5 39 J Total Zinc (Zn) gg/1 10 2.5 1,000 2.8 J 8.7 J <2.5 40 <2.5 <2.5 140 <2.5 Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENR, Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L .0202. Amended Eff. April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 9378-26B Leachate Tables T9 LD Metals (4-28-22) 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = Method Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. Prepared by: IAI Checked by: RLB/AWA FIGURES J o M � \ 1751 a 1745 �1 D R1PRW0DD � \l l w; I, $ N F ti ,s�J �1, - RTi Af �D 2\ 1 Alexander 2000 1000 0 2000 4000 APPROXIMATE SCALE IN FEET DRAWN: KLW DATE: 9-2-22 ' IM I BUNNELL � LAMMONS CHECKED: RLB CAD: BCLF26B-SLM ENGINEERING 6004 Ponders Court, Greenville, SC 29615 APPROVED: AWA JOB NO: J21-9378-26 Phone: (864) 288-1265 Fax: (864] 288-4430 REFERENCE: USGS TOPOGRAPHIC MAP, 7.5 MINUTE SERIES, LEICESTER AND WEAVERVILLE, N.C. QUADRANGLES, PHOTOREMSED 2017 AND PHOTOREMSED 2017. SITE LOCATION MAP I BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA FIGURE •/ N N � CONVE IE CE CENTER LANDFILL OFFICE BUILDING � F 14 OO BL � , FLOW) �SW-2 , .. _ - �t _-�— � WELL �� jM-4 1912.74 / I \, HOUSE — MW-2 sw-6,- �/ — SCALE HOUSE 10 oMW-3R MW-2D ? 1 / 1918.95 1911.80 PANTHER BRANCH *1e\ ' 1942179 (� FLOW) �� -� MW =10 Q \\ / 1931.05�� '_L_3, LLD 44 JkSW-8 ♦ 1 MW-18)K MW-4D)K21— �,� 1896.05 _---192918•2 j 1_941,42 MW � 1 95188 \ MW-5,1943,37 1� INACTIVE 1 INp S W- 3 1 r`) I r\ CI 1 z -h -b c o0 I I � I cn cL[1878.22 MW-17R CD R@1876 j6 I7DR) ! j I c cn MW-17 MW-17D ® (AB) (AB) V MW-i�D]LI��-M= I___ ` ---- - - '1 'CELL 4 I 1948149 II I .INACTIVE 1 CELL 1 1 -� SW-5 \ 1 I 1 I MW-14 z 11 --.... \ _ '1923125-MW-14D�/I I \/ 1923,7- / " MW-12, 01935.09 MW-12D)K I1934.25 \ T ......-------------- O \ Mw_6 196�1 BUNCOMBE COUNTY EMERGENCY SERVICES h RADIO TOWER EXISTING PHASE 1-5 C&D AREA PERMITTED PHASE 6 \ ` C&D AREA � � 1 L \ \1A oe / / INACTIVE CELL 2 I INACTIVE / __-----CELL 5 � I MW-7 WLD- J O 1980,32 M-2 /LEACHATE* r-- LLD • i MW-8 1931144 l S MW-11 MW-8D)K 1933,9 / 1932,86 ' EMPLOYEE I �EACHATE TRAILER POND 4. 101*1 SW-4 1960 1 1 1 1 1 1 1 1 1 B10 1 1 >g0 1850 \ fog" a � � r� \ 1j9 ����n��♦ FRENCH BROAD RIVER ♦n �w 1 8so &N CAR��/.1, NS�c'titi9 1 5 rrrr1111 1980 \ 1 PERMITTED FUTURE `\ CELL 7 ACTIVE \ �� CELL 6 / 198080 a i i O�to .o \ 'A 1955.56 1960 MW-1 S MW-1D) .954,37 �-- 1950 MONITORING WELL --I IVIYJ, V V1 ..,1.1111 I, I I..,,,LV I I\ll. ITT, I J5257. FILE%: SITEMAP 2014.DWG. 2) SURFACE WATER LOCATIONS FROM SHEET NO. 1 GROUNDWATER AND METHANE MONITORING WELL LOCATION MAP, CDM SMITH, NOVEMBER 2012 PROJECT NO. 6447-93318. FILE: SITEMAP. DWG. 3) PHASE 6 C&D BOUNDARY PROVIDED BY MCGILL. 4) SHEET NO. OP-1 EXISTING CONDITIONS, CDM SMITH, PROJECT NO. 6447-97693. FILE: OP-1.DWG. 5) FIGURE NO. 3-1 WATER QUALITY MONITORING PLAN CELL 6 AREA, CDM, PROJECT NO. 6447, DATED NOVEMBER 2004. 6) SURVEY DATA FOR MW-17R, MW-17DR AND M-12R IN SCS REPORT DATED OCTOBER 13, 2020 7) SURVEYING FOR MW-18 PERFORMED BY ED HOLMES AND ASSOCIATES DATED SEPTEMBER 24, 2021 NOTES. LOCATION ACCURACY OF THE FEATURES SHOWN IS LIMITED BY THE REFERENCES THEMSELVES. LEGEND —1980 TOPOGRAPHIC CONTOUR - - - - - WASTE UNIT BOUNDARY FACILITY BOUNDARY MW-10 EXISTING GROUNDWATER MONITORING WELL �MW- 16 PERMITTED FUTURE GROUNDWATER MONITORING WELL EXISTING SURFACE WATER SW-2 MONITORING LOCATION * LD-1 LEAK DETECTOR *LD-7 PERMITTED FUTURE LEAK DETECTOR 0 M-3 EXISTING LANDFILL GAS MONITORING WELL +M-5 PERMITTED FUTURE LANDFILL GAS MONITORING WE ■ EXISTING STRUCTURE MONITORED FOR LANDFILL GAS 1950 GROUNDWATER ELEVATION CONTOUR (FEET MSL) CONTOUR INTERVAL = 10 FEET ■ GROUNDWATER FLOW DIRECTION * DEEP WELL NOT USED FOR CONTOURING PURPOSES (AB) ABANDONED _ I - I - I - I _ STREAM 200 100 0 200 400 APPROXIMATE SCALE IN FEET REVISIONS No. DESCRIPTION BY DRAWN: IAI CHECKED: RLB APPROVED: AWA DATE: 9-2-22 CAD FILE: BCLF 9378-26BWMT042622 JOB NO: J21-9378-26 BUNNELL � LAMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone: (864) 288-1265 Fox; (864) 288-4430 GROUNDWATER ELEVATION CONTOUR MAP-APRIL 25-26, 2022 BUNCOMBE COUNTY LANDFILL ALEXANDER, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. �kik7( lCc i p i Document Name: Field data Sheet Date Issued. 1Viarch $ 2019 " Page 1 off, Document NliYl beT., E-CAR-l�LD-001-rev,U3 issuffi e ualtty �'� A�tthoiit - ��. Pace Huntersvill - - � Office Field Data Sheeti LE t #: Name and A ffiliatioi-t(Samoter(s}.: Field Data Sheet Review: Name.and AiEiliaticrt (Inspectrj:,. N Da J( tl�1� te: Well Information `( Z .2 Well ID: /'^ t'r r Well Locked: Y / 1V0 / Rush ouant ) Well Diameter, Construction: dU Steel%StaiiIless Steel) Total. Well Depth 71,03 ft Static: Water Level: ft Height a.f. Water Column: � ft Multi Fktor#: 01 i6l NRad.!us/12)2x 3.14 x 7,491 Casing. Volume: 2 , l 0 gallons Cal, 3. Volumes: cF g4lion.M . Dump Intake: "' .7 ft By: i'urge'Informat'ion Date I'urged:� Start 3-_ Finish-.. 1436 Purge Rate: 1,0 o CFOf Purging: Method: !"P--) a� nmon400a'Y Total Volume Purged: (gallons/t71ls 'L). Saml?ling Information Date Collected.�,t I L9 / "2- Time Collected:—) te a ---- (anI Saix plug Equipment Used. Me j, ,ri._......�..._y_no.....�` [nstrurne��t D: y 5 l 0 &b ���w �i, g iN Bottle Type Preservation Analysis Required HIAQ NI 2"2-50MI. P.t'.4..a_4 u.nj�—e5 �iµiE�ie, ,AIK Field Measurement&/Ob" nations Sample ) TempC : 2-0 . [� Time: I q_� `� Turbfdi.. ntu : � t- Time: (° --( ` Kiss Oxy (rng/L): i . Time: Fe 2+ ing/L:��. J_._._._._ ` hrie: Specific Cond. (uS).; . 1 '-51, Time: Res. 0 (mg/L)/(gg/L): Time: Sample pH _............. e.Time: Qdr�r:��(.�iip _T rr�e: j._'1 LA 0 ._. ReDox (rTW): Time, Appearance: t; . !. Time., � - RclDox (EEH value)-.YST.ProPlur,.+2F1QmV ?X by • E7 Other: Tiiite: _1 General/Weather Observations: (sunn cloudy/rainy) Temp.,_ ('F) WInd0--6"__(mph) Sampler Signature: RY an 2 � —Date: Stabilization Test Spec. Volume Tinne Temp. Diss Qxy. Cond. pI-i (s.u.) Repox Turbidity remove V�iater tither Purged a (C) (Ing/I,) (u�) (mV) (ntu) (gallons/ftillss level (ft) L ig 6A L3 49. a ,ab, '2-� 13 i1,6 b, � 4'3z -2-t.3 Is0© g�:= +�7.7 €,, Docuutent:Nante: i OC41rrent.Issued . March 8, 2(r19. 74 el4risljrifcsl y Field i]atuk#et Page Z. of Z IDoctunent !`lumber: lssueeng Rrtthontys F-CAIt FLIP-fttfl.r u:{)3 Pace Huntersville. Quality Office Ckht:. R L is Location., i ez mc,ar. N C //��? Project; CQ,G A o• A&-L, e L i= A 1.22 Reviewed Date and By- y�l� ALPn Stabilization Test' VV eD Diameter � :lultiplication Factor+ .1 0,0408 1.2 O 091E 0.10la0 0.16,30 .. 03670 . 4 0.6530 6 1.4680 3 2.6100 Time Purged Temp. (C). Diss Oxy. (:mg./L) apec> Conde (US) pH (s.u) ReDox (mu) Turbidity (ntu) Volume Removed (gallon 1� L) circle. ne Water level (). Other 1405 Zo, fSoa #L% 15 216, LJ �i. 3 55®0 Aw ���� A'tr6�lytTcG�I 6 Document Name .,.Field data Sheet Odle Issued: Marth.8; 2fri9 P. i of z Document Numbex: F-CAR-FID-opi rev 03 Issuing Authority Face Hwitersvilte Quality Office Field Data Sheet pp CIient: LC L�aeaticsrt:� s evi l t 4� C ..Pr€jeet#: vwtc%, ive.LF sA- Ar, Z.A�Z. Name:and Affiliation (Sarnpler(s) NE - i gtLe Field. Datat Sheet Review Name and Affiliation (Inspector•):_. iVi4 Date: ��helY Well Information Weil ID: Well Lacked:. NO / Flushnrount Well Diameten •, Construction: t /Steel/ Stainless 'Steel) Total Well Depth: � 5 � ft Multi .Fktw*:_,Q � �� [*fradiuF/12j2x s.-t4 x.748] Static 'Water Level: te-t- 2.1 fk Casing tialutne: ` gallons Fleight: of Water Colurhn; dal. 3 Volumes; [5 Pump Intake:. ft C._ By: Pure Information Date Purged: % a / a a Start : 31 D Fixiish: '� 5 5 1'� rge Rate: 'a'= °• . ft%k Pur .. Metho:d: O g MeS�. (ko�sao�,._.. Tt�al�plumel�urged: Sampling Information. .... -- Date Catieeteri:�_/ gj 3'DI 'Time Collected: _" Sampling Equipment Used: M �, /"Lot,So 61-L Instrumen . HDAsi oLovHD: Bottle Type Preservation Analysis Required M��ls ZS�M� f us ri'S• 5-Jr G folk Field MeasurementqOborvation Sample Temp.(°C);. aK r-6 Time:: 0-A-0_0 Turbidity (ntu)': 1, Z Tlnie: t -t O tQ Diss Oxy (mg/L)- Fe 2+ mg/L:_ .. --Time. Specific Cond. (uS): a s `l T"itne: i � 60 Res. Cl T ime SaznplepN.(s.tt.)a 1`4 \ ReDox (mV)c Time, u Appearance: C e a / `rime., Re0ax (EH valia.e);YST. ProPlus +200mv.._.. I � � �...-..._ Other: ~- _` Time: r General/Weather Observations:` Sampler signature Stabilization 'rest Temp.=(°F) Wind 3 (mph) It-a8-tea Time Temp. Diss Oxy: Spec. Corm. pH (s.u.) ReDax TuTurbidity Volume remove tVater- Other Purgecl (aC) (irtg/I) (�S). (znV) (ntu) (galloitns/ / level (ft) L ?25 t1y I.t. 212-3 1 1Le -`tb, 13-0 EC>00 1$ "bv ( i " . L, Z? 2. 3 -1. Co�- Q 3 L0, t3 35 3 0-5 ')6),k 50o t.t-g (01,7j) 04o t,5 ©-U 352.4 '-7-q -61.5 to.-7 Dmainent'Name: Field Data Sheet Document Issued: March So 2:CY19 ia}�e 2af .2- Ckiemneut Numbor: 'Issueing Authority- t F-CAR-FLD-©01.rev:Cl3 ?ace Hunleisvi[Ic Quality Office Client: P LE Location: Asktvi ll e NC Project: F;,vncom6 e AJ,,J e L F. A w l Well III: _ M W � Reviewed Date:and By;_Q^1���'� 4 �� Stabilization Test 9 LG-- VVen Ehameter tuitiplication Factoe' 0.t?�Q8 f�:Ci�1,8 0.10so 0.16,30 0.3670 0.6530 1.4680 2.61€ 0 Time Purged hemp, (°C) Hiss Uxy. ,mg/L Spec' Cond. (us) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Re ved (gallons/Wi li.) circle one Water level (ft) Other 13SO a3.3` �� )5SS:5 T'l -3Is0a 9.1 Cot-sb -- 1� e tytiC r Document Name: Fidd dAta Sheit late Issued March.8, 2(n9r Pager 0Q, POCU pent Number: F-EAR-FLD401-rev.Q� Issuiatg Authority.: [pare Htuttersville (duality Office } FL F Name and Affiliation (Sampler(s):. S Name and Affiliation (Inspector) - Well Information Weil LIB: $A,Well Diameter- _� TotI Well Depth: Et Static Water Level:., Height of Water Column 0� ft Purge Information Date Purged: L _/ Z 0 Field DaFa Sheet Well Locked: Data Sheet Review: Date: �� ZZ NO / Flushmoun Vs06 L F SK6Jj, 2 By: M &2 Construction:. (Ift f Stee(/Stainless Steel:) Multi factor*,� �(Radius/12)2x 114 x 7.48) Casiang Vilume: gallons CaL 3 Volumes. gallons IV Pump Intake: p� Start: 0 Finish: I Rake: i `h Purging Method, . 4 fi' I C Total Volume Purged:52gallons j tr Jl� � l° I £ �. atrt In n ormation Date Cr�llectecl: li .._fZ` Z�' 'Cin�e Code€tad; yy t fi SamptIng Equipment Used: t S `�' i iC Instrument ID: Bottle Type Preservation Analysis Required p Cass iC b NJ _ . Field IVleasurernertts/Observations.,.,.. 4 � Sample Temp (°C): n4Z Time; �.�,_ _ Turbidity (ntu). Time: I___.....� 1 Diss Oxy (mg/L),_Q i Time: { % Fe 2+� mg/L: Tlme: Specific Cond. (uS): Time:. �LRes. CI (Mg/L)/(Ag/L): rime: Sample PH (s, u.): ---- � �1_ `rime: ji_ ReDox (mV): Time: c Appearance: ReDox (EH value):YS.I ProPlus +200m.V ,) Other: Time- General/Weather Observations: (S&/cloudy/rainy) Temp.�(°F) Wind Sampler Signature: hate: �" � Stabilization Test Time Temp, ° Diss Oxy.ReDox Spec.volume Cond. pH (s.u.) Turbidity removed Water Other Purged g C ( ) I. {m gf ) (uS) (n1V) (r.�tu.) (gallons%ij` level (ft) L 0 4 2 b -,,Q '%AnZ Document Name. Document tssueii::'Marct ti; 2019 f Field DA.ta Sheet pagg cif Document Number: Is§ueing Authcyri.q:c ( F-CAi FLD) 001 rev.tl3 Pace Huntersville Quality Office Client: Location:_....t'1.. h.._P-_V _I I r a Project; 12 lk, A C. U V��' Well ID; 12. Reviewed Date and By. 4, 'LZ M 62 Stabilization TestG - -z , � - CJ- 6- Vbelt Diameter Multiplication Factory' 0.0403 1.Z 0.0913 1.625 €3.1080 2 0.1630 fi.b33.[3 6 1.4630 3 2.6100 Spec. Volume Removed Time Temp. Diss oxy. Turbidity. Water level 6 ) Cond.. pH (s.u:J ReDox (rnV) {gallants/Ze L) other Purged (C) (g/L) (US) Q tV � �-`�i2 circle () 0 Document Name: l it�i�i daE�+. heeF. Tate Issued: Marclt'�4i 2019 c0Al1,71YliMI P°tge: 1 of _ Docutttent Number FCAR-Fl.ii_I}aj' MV,Qi Issuing AuthorityNceRunterwille Quality r Office Nan -Le and Affiliation (Samp'ler(sj:. �.✓' G ys Name.and Affiliation (Inspector):_ N�v� Well Information Well ID- _ �✓1 i.,/ Well Diameter: -� Total Well Depth: �S Oc�� —it Static. Water Level: s-75 ft sleight of Water Coluri n 3ft Well Locked: A✓!i`arojeet * 1✓ a r7e. eo.—AG 1" VL G 7r 5,h 2o2'L old Data Sheet Review: Date G z By: GM Z Cr- Construction:. (i0/Steel/Stainless Steel) Multi Factor* 0 (6:. (Rad us/1z)z x s;1a 0.48i Casing Volume; Q , 6,6 gallons Cal, 3 Volumes: l` ! U oalloits PumpC-CG' ,ft Purge Information Date Purged Start: Finish: 0 2�5 purge late: l'ttrg rigMethadc� t°�i a Total Volume Purged: ` SCi0 (gallons/ Ill l.,). Sa�npliitgLtiforntakian i' QOB i�'5�;,� Date Cot1ected,._._.....1 ... /5!'Z/;......igz,_ Time CgUeetetl ... Sampling, Equipment Used: �G'Y an ' instrument ID: it � 1 31/.b �_...__. Bottle Type � 001t, Sr 23G ".L.. Field Measurements/Observations Sample Temp ("C) �� 2 Time;. hiss Oxy (mg/L): 21 S —Time; Specific Cond. (uS): 140, 1 Tune:. Sample pH (s.u.): � �..._ .,..,, Time: ReDox (mV) �� Tin ee ReDox ((EH value):YSI ProPlus +200mV_ General/Weather Observations: Preservation e mm Ii/it� G Analysis Required _Turlbitiity {rttu); I 0 C Pe 2+ mg/L: Ines. Cl (mg/L)/(Rg/L): 'l°imer.- C7dor•__.. 1/Z, Tune: L Appearance. C,%C� Time, 4 f Other; Time: unal cloudy/rainy) Temp.(°F) Wind Q (mph) Samples Signature: —7 ._—M hate: g Z7,_. Stabilization Test Time Temp. Diss Oxy: Spec. Conti. pH (s.u.) ReDox Turbidity Volume remove Water. Other Purged (C) CC) (mg/L) (US) (mv) (ntu.) (gallons m, / level (ft) I. a tE1 4J Q6 © � G (-1,7 G,25 Cc 3 ! (o 0 ----� , � 3 C90, 1 NS jq 7/o 5, r S FD l A `f 961 ±C015 S13"i 6 m 10 "� d,®5 6o(5c;- 6fs <I,"T 0• ( vL,50c> T >�cr�unYc;nt-Nan\c:.P.is�lct dat,� 5h��t Vate Issued: March.$, 2019 page: 1 of I.�E1C11[►teilt t urf'iGL'L: = �1R-I•I..17-QdI-reV.03 - '- ... Issuffig Authoffty: race Huntersvlll Quajlij+- office. Field Data Sheet: AS�.eVi^tle, pie 1?rarect#:$v.hccI. Narne and Affiliation (Samoler(s): t" ER - Pctc_e Name and Affiliation (Inspector) -. �J Well Information Well n Mw - 32 Well Locked: Well Diameter:'t'z�"� v� � Construction:. Total W011 Depth: 5'2 � 10 -Ft Static Water Level: S Li , 15 fk Height o:f Water Column: k $5 ft NewLF-AfrZZ -Sem" Pield Data Sheet Review: 'Lei- ?-Z G_C G DateBy- ;s Steel) Multi F clor*: b • 1 V . [ (IWius/12)2.x 3,14 x 7,481 Casing V6,ulne: 0 ,1 `� gallons Cal. 3 Volumes: • 3-7 gallons Pump Intake, ft purge Information . . . ✓4L 0 `% 2 S Fi � slt . @ `l �� Purge;Rate: t 3 C) /.►, � , \ Purging lvlethodr_ M f!;, �ortiSoo k�. Total Volume Purged: 'A 5 a c7 (gallons/1 1 /l.,) Samoline .Information Date Collected.- t _%�/ �..c�........ Ti e Co lleeted;_S.S- a /pin) Sampling Equipment Eased: Me_5et Moos6oyx strument ID:T_ `/ S t 0 20..''[._. tl TA., In. (p Battle Type Reservation Ana.iysis Required . Z50N,t �i�Sr: .Field Measurements - servations q Sample Temp: (°(2):. 15,5 Time:— `I `-S 5 _Turbidity (ntu.); __L-_�'n_...._. Tillie-, 0 1Y S Diss pxy(mg/L,}: S• ( Time: 0 Fe 2+ mg/L; N 8 Time. 4........._9.1.._� Specific Conn. (uS): 1 12. -] Time: 0555 Res.Cl (Inb/L)/(Glg/ Sample p.H (s,ti. ): Lo ._Z_,._ Time: 5� d N _ O `i Ucior:_.._..__._ RdDox (mV): �7 Time: Appearance: C 1 Time. d q 5 $ ReDox (EH value):Y.eil FroPlus+2001ilV 7_3 9. 7 Other: "y Time: General/Weather Observatiaais: cloudy/rainy) Temp.,U.0 (aF) Wind 3 (mph) Sampler Sign Stabilization Y-a�- Spec. 0 ue Time Temp. Disc Oxy: pH (s'iE') ReDox Turbidity remove Water Other Purged. CC} (!ng/I} { �� (MV) (ntu) (gallons/ 11 / level (ft) l 013 j Z_U 5,18 901 501 43.S .s4.4 5 F e 2-U 035 H.3 U.a P14 U,a 3U.3 -33.9 i %00 5`1.%49 10146 1 t5,a 110.E 1 Ce [ _34.9 DLot a-700 © '- rj 64 1 5. Z 0.9 &.,1 Le .9 l & • 3 3UO() O-A `7 U t 7, 1 51 -2- 1 t'4,-t Co, Z -34. 4 9 .'A `L> L)U .`a `1, `lrg 4� DoCuntertt IVttzne:l%ield-data . Sheet. Lute Issued: March 8, 20119 GeArt:7fy�i ,?f Page; I of _' - Document Number: F-CA9-FLD-001-rev.03 7ssuhig Authority: Dace Fitutte'sville Quality F Office Name and Affiliation (Sam ler(s}:: I„/•;�✓��� Name and Affiliation (Inspector):_.,4-11A_ Well Information L Well ID: MVI/ " .. ......_ Well Diameter: Total Well. Depth: ' ft Static Water T.evel, Height of Water Cdlumn: . � 3%t L__Project #. a1✓,C0,47 k- j Cp . .4e t.ve J_F ,ld Data Sheet Review: � U. zZ Mtr(Z Hate: .ByC:_� r Well Lacked: (Y / NO / Fiushmount ) Construction. V /Steel/Stainle% Steel,) Multi Factor-,, 0. / C 3 ( (Radius/ 12)2 x 3:14 x 7.4$] Casing Vciliuxne.: �- gallons Cal. 3 Volumes: 0!5 Falioits Pump Intake: , S 0 t .ft Purge Information j Date Purged._/ -f 2—Statt : Finish: /36- 6 Purge irge mate: / 06 �7 Purging Method, Gar _Total Volume.Purged: �1�(gallons/.ra7l /la) Sarn lin lnformation Date Collected-,_. $/. �� r Cline CollecEeci:If �-5 (am/0 Sampling Equipment Used. Pe . � Instrument ID: ils 3� r Bottle Type 3......r��p ��rrrtr. fJl�rl� Field_Measurements/Observations Sample Ternp (" C):. Time:. Diss Oxy (mg/L): Time: Specific Cond. (uS): Time: Sample p I (s, u. ): p__..... _� . Time, ReDox (mV)t �. lei Time. Preservation Analysis Required .Vt-_7 /5' G Turbidity (nte,): Time, 1 3 0- .Fe 2+ mg/ L �/1� —Time. f Res. Cl (mg/L)/(leg/L): 'rime: — 1—�7 ---�- Odor: - 4111) Thee: r JG- Appearance: -LIP 6 Time, ReDox (EH value):YSI ProPl€is +200 mV 9. Other: nze: General/Weather Observations;____ Sampler Signature Stabilization Test �,/cloudy/rainy) Temp..(° Wind �57 (mph) Date:. Spec. Vo time Time Pur Temp. °C Diss Oxy. Cond. pH (s.u.) ReDox Turbidity remove Water Other g ed ( ) L. (ix� g%) (US) (Inv) (ntu) (gallons/ 1s level (ft) L I 'i _ VQ, 1 v r,, I �, 250S 6,a ios, Z � o � jC V 3-5' r.` 25 T fjo, I c '00 D-CIO AILS 3 d 0 � 13. � . -5 -!;c1GP..IQ ialjtl%c? Doc ntentName: Field DWP Street 0 ument lssuGd. lYfarcit, 8, 2fi11 Pal e`;of - C Dcurttertt Nixtatlycr: F C AR-FLD-001.rev.03 Issueutg Authority; Nce Huntersville Quality Office Client: 6 Location- pFE3ji'Gt;. L'O: Lis ✓L, 2- Well ID: L -- Reviewed late and By: i� - ZZ M �� Stabilization Test` G ' L Z G-L - VeU Diameter Xlul4johcat on Factor' 0.�l09 .1.2 ti:Ex918 1.625 0.1080 2 .. 0.1630 0.3"f 0.6530 1.4680 8 2-6100 0 DTurbidit e' • ► s is one ! Doj�unwnt Nome: Field data sheet. Date Issued' Mart 8; 2019 ee/trtatytiC�?F Ira e: l0 t7ixun ent Number F=CAR-FL.IJ-001-rev.03 Issuing Authaeity: Pare Huilters"Me Quality Office 0 Field Data Sheet 0 - . . Name and Afl`iliallon Name a-nd Affiliation (Inspector)- Shell Information Well ID. i .......... VIFeII Diameter• ..�.__._ Total Well Depth.: � - ft Static Water Level:LI V JG _£t Height of Water CQl:umn:_q_"ft Well Locked: V(I t*ieid Data Sheet Review: B : MCR 5'-6-zz �` Ck(C / mo / Construcdon Q 'C/Steel/Stainless Steel:) Multi FacWr*: r(Radius/l2)2 x 114 x 7,48] Casing Volume: � "' gallons Cal. 3 Volumes, gFilions Pump Intake: .'�ft Purge Infonnation. Date Purged: / n /��'�... Start : � F nislt: Z Purge Rate:__ 'eft-, /M d Purging Method: �°-- r�4 -i- , t _Total Volume Purged:.... .Sampling.atmpling Information Date Collected: —/2_v [''uric Collected: Sampling: Equipment Useci:.._.._�... Instrument ID: Bottle Type Preservation Analysis Required X' i ;G fkLMIC Ly f 2 V/fin ( — Field Measurements Observations °'1 L Sample TL-mP ('DC): Time: Time: 1 1.50 Tuibidity (ntu): -0� �'� Time: In y Diss Oxy (mg/l,): s G _ Time. .32 Fe 2+ mg/L.TIme: :17 Specific Ctnd, (u5): Time: f � ' Res. Cl (ing/l_)/(}Eg/1;):Tin�e:n �� 1Z Sample pFl. sm.) .._..---- -Time: -Odor: � ReDox (mV): Time: _ � Appearance: _ �...t v—D C Time: ReDox (EH value):YST. ProPlus +200 .V_�' ca. Other.: r' Time: Generalf Weather Observations: su y/cloudy/rainy) Temp:. (aP) Wind_04-�Jmph) Sampler Signature: Stabilization Test 1� Time Temp. Diss Oxy, Spec. pI1 (s.u.) ReDox Turbidity o wine removed Water Other Purged (°C) (mg/") (US) (MV) (I-Ltu) (gallons/ it level. (ft) "i e" 9 �^ Qocument-Name Field data Sheet - fake ISs ed: March 8s2QE9 Page: 1.eflj AnNylkdl issulilg AutharEt}� Pare H� tterSvrEyeQ iity Documer3t Nuni eF: F-CAR-FLDn W-rev.IX3 office Feld Data SheeE L Name and Affiliation (Sannpler(s):. S Name and Afliilation (Inspector):: Well Infvr atittn _ WLHIJDLA Weh Diameter: Total Well. Depth: 2J ft Static Water Level: t `` `i ft Height of Water Columi-1 e ft Well Locked: Construction,. Data.Sheet Review: late:. NO / Fluft'lount:) Steel) .Multi FACtor*:Qt 163 ('4($hdius/12)2 x114 x 7,45] Casing Volume. Z i gallons Cal. 3 Volumes: gallop Fump Intake: By: Purge Infa�nation Date Pi rgei;/.6 / 2 Z . Start : Fii'rsl: :l'czrge Rate:�39 Purging Method: �iV 1117 ,5�1i�� 1 Taal Volume Purged: (gallon l r la). Ssmoing Information Date C_6 .lected _ / Tim6 Collected:, boa (am/ 1& Sampling Equipment Used., '.Instrument ID: Bottle Type Preservation Analysis Required: �.5. t i. r-�� a Field Measurements/Observations Sample Temp. (°C): � Tine; r`.,� Turbidity (ntu):: Time: Diss Oxy ) r Time: ) Fe 2+ mg/L, time. (a n Specific Cond. u.S). � Time: Res. CI m L. p. L . Th-ae: Sample p:H. (s. U. )" --"------.Time ._ ... Odor: ._.. �— R Dox (mV)! Time:Appearance: C. 4. •P'2 r `lime: GOO ReDox (EH value).YSI PtoPlus +200 V � ,ice � Other.: Time: General/Weather Observations. (sunny/ r uu� /rany). Temp:,�_, _.(a Wind _-_(mph) Sampler Signature: Date: L 216 1 2,- Stabilizatio e. Test Spec' a unte Time Temp. Disc Oxy, Coed. pH (s.u.) ReDox Turbidity removed Water Other Purged . °C M L niV ntu (gallons/ 1 / level ft L Li f/� r F� 44 L A pegs Doeunimit Nanie: Doc uty. ent Issued: Mardi 8 � t9. rtC?c7}%�IGr?st u Field Data Sheet rage - f D cunieiit Nunybor: F-CAR-FLD-0()1Av.pa Issueirng. Autlrcirity: mace Huntersvitle Quality office Client: L Location: Project:+A C L--Lo Well ID: Reviewed Date and By: ' I v Z-L Stabilization Test IN"ell Diameter Multiplication Factoe 1 €).€1408 1.2 0.0918 1.623 0.10,30 2 0.1630 3 0.3670 0.6530 _46 0 S 2.6100 Time Purged Temp.Di (el ppry /pry Y L V Dx y (mg/�) Spec. Cond. pH (.s.u. (us) } ReDox rn.tif } Turbidity (ntu} Volume Removed (gallons/L) circle.€ ne Water level (Et} Other — — 17 ,��I Ll, q ? a D cu.ment-Narne: Field data Shea D&W- issued March 8, 2010 Page: 1 0 i �i OI�il t Mis'�i 1 Docurnent Number: F-CAR-FLD-0.01-rev.03 issuing Authority: Pace.. Hulitersville t',it4alj� 7 __ Office Narne and A.Efi.l. ation (Sampler(s);: Name and Affiliation (Inspector):: N4 Well Information Well ID: L✓" Well Diameter: , .9 Z Taal Well Depth;. T l • &/ & _ft Static Water Level: 3 q, co.3 ft Height of Water Column- ft Well Locked: Construction. l Project m D_yI ✓l.Co m } e 60. Id Data Sheet Review: Hate: y z By: ML NO / Flushmount ) yet/Stainless Steel) Multi r-actor•*: V • /6- I" (Radius[12)2 x 3:14 x 7.48I Casing `Volume, 7� `3 gallons Cal. 3 Volumes: �' galIons Pump Intake: 7 ft Purge Inforrmation. yy� Date Purged: /)w'-/ Start: 1.L 12 Fi isl3e G Purge Rate: Purging Method- MCi1?soen Total Volume l'urgetl: C1.500 (gallons/ 0 Saxa�pling ixtfciriixatiort Date Cofiected:.........V.........,./4 /-.-..-... �:,- . (am' i ?) Tlino Collected:; .�Ll C� Sampling Equipment Useel: YI .CCYI Instrument ID:_ Bottle Type s2rqto tri- ass Preservation Analysis Required -I ..... le C1 S Field MeasurernentabObservations r- Sriutple 1xnp (°C): �G • Tlme;G..... _Turbiiiity {rat}: r _Time: f Criss 'Oxy (xng/L): 0 6 S Time; Fe 2+ mg/L: me: f Specific Cond. (uS): 901.6 Time: Iles. 0 (ing/ L)/(gg/ L) 'rime..�—;� Sample PH (s.u,): �. ��_..._. Time: C?dor: _.. VA�yQ Time....... re / 7V ReDox (mV) LS �'�� Time; Appearance: G G 'rime: RLe Dox (PH valLie);YS.I l?roPlus.+20.0mly 'J 0 Other- Time: General/Weather (surety/cloudy/Kti Tem Sampler Signature Stabilization 'Pest k. 4,'�,e `F Spec. Volume Time Temp. Diss Oxy. Cord. pH (s.u.) ReDox Turbidity removed Water Other Puy ed g °C ( ) to i. ( g/ } (u5}. mV ( } ntu ( } allons nits (g / / : level (ft). L c W , a0 G' 7 ©. ill 6 ( ISQ, c 0 ,5' 3,` t 5p r/-11.5 07 153 � all LISG 47 3 6 , C13 Document -[*lame; Field data Sheet Date lssued March $, 2019 iJ scunieat Number: F-CAR-FI.I3 all-rev.©3 Issuing.Author4y°,PaceHuntersville Quality Office l ent 6 f _ Locati.onn �✓lP d/) �j /I!G Pra ect #: axt Nae and A,Efiliation (Sampler(s). 9i�9"1SU'�V' 6214CO Pield Data Sheet Review: Nam. e an.cl Affiliation (Inspector): � Well Information 57 , lv Date: S-G�az. Well ID. Well Locked / NO / Flushmount ) Well Dicameten e /{/ Cgnstruction: "rsteel/Stainless Steel:) TQ.tal Well Depth: 5G, Multi Factor*: aC rl C V(Radiu5/12)2.x3 4 x.7.481 C Static Water Level: 5 m ft 4 Casing Volume: Qq gallons Freight of Water Cralurtiri; 95�J�.9 fI Cal. 3 Valurnes; �o e : g lions Purtip intake: q Y • 561iL ft ®. AGi, ve G{ g�. ME2 Purge Information DatePurgecl: / / Start: .Fi lish:._. s P rge'Pate: pttgrMethodaetal i1utPurged: {gallons/ Sam Iin inform Lion J Bate Collected,.... /► / a2, Time Collected:. (ant/ In . Sainp.ling Equipment Used. Let / • Instrument ID: Battle Type 3xYV mt S(GSS Zr 02 56 VL k"lc Field .Measurements/Observations Sample Temp (°C):. / GI . "1 Time:; Diss Oxy (mg/L): Time: Specific Cnzxci. (u5); f 3 Time: Sample p.H (s.u.): J __-Time: Preservation a.iysis Required _ r4h l S _ CIO Turbidity (ntu)': - 6 Tillie, T.Fe 2* mg/L: /1//0 Time: i Res. Cl (tiig/L)/(gg/L): '� 'rime: Time:..... � � 1J 6 ReDox (mV): I Time Appearance: �C'Y Time- ReDox (EH vale+e):YSt ProPlus +200inV 2✓ , 3 Other: Tirrte: Genteral/Weather Observations: Sampler Signature Stabilization Test G Temp.,'.(-F) Wind 5.,.,,..,..___(mph) Spec,. Vea ume Time Temp. Diss Oxy. Cortd. pH(s'u') ReDox Turbidity removed Water C�E11er Purged ed °C Ira L, 111V t1.tu all.ons cols level ft l.. . , P 12C141 [!J, 73 500 $ fee - CA L9 rq, q 13 g _;rtgr 1 2 LI" 1SkJ 5� 2zy, too 5� x A17r7�1Gi1r d Docunignt ]Nome Field data Sheet. Date Issued: M rch,si 2[? % Pa e:.1 of Document Number: F-CAR-FLD-0Ql-rev.43 lbsuiitg Auth ity, PaceHimtersville Quality Office Field DAW SheeE'. Client: Location: Prnjeet ## i i1 C L Name and Affiliation (5amgler(s)z � I �1 1?ie[d Data Sheet l�evsew: Name and Affiliation (Inspector):: Z`t- M 6R . Doke: . 5-4 By: L �� Well ln€ognation Well ID: iN " `� Well Locked- (�'/ NO / :Plushmoutit) Well Diameter: �~ Construction: ( Steel/StaiTtles.s Steel) Tbw well Depth. � �Ft Multi Factor; j j 6; [r(Ra�lius/iz)z x 3:i4 x 7,4a1 Static Water Level: _fit Casing, Vt lum e. � � gallon Height: of Water ColumndUNR Cal. 3 'Volu esi 3 .gallons Pump Intake: l*ttr&e lnformatian �2�..Start: Finish, cxrgeDate Purged:�/Rate: t Ga L 5 b? Purging lvlethocl: i v "� d1 f% 7 s tal Volume Purged:- _ -is/(gallo/L) SaxrtplinglnfornYatynrt Date Collected �_/ Z�/ � � Time Colleeted:�� (aml& Sampling.Equipment Used: qN Q l[1 Instrument ID- Bottle Type Preservation . Analysis Required, Field Measurements/€)b_seryations Sample Tim-Lp (�C): Time:. _ Turbidity. (ptu) Time .. Diss Oxy (mg/L): Time: Fe 2+ mg/L. Tune: l.7) Specific Cond. (uS); 4 I ime: _L Res. Cl (ig/L)/(deg/L): ru-ne: �~ Sample pH (s.cc); ReDox (mV): � Thue:. 1. �' appearance:. rime: .ReDox (IMH value)NSI ProPlus +200nLV :) Other.: Time: General/Weather Observations. �g � /eloudy/rainy} TempS�� Wine[ -(mph) Sampler Signature: P�.Date: Stabilization Stabirlization Test Spec. Vo Un e Time Temp. Diss ©xT Cone[. H p (su ) ReDox. Turbidity removed Water Other Purged (C) (cng/T). (US) (mv) (ntu) (gallons/no/ L level (ft) 15• rJ a u�4 3 Br A DocutijentNunibw: F-CAWRD-Wl-rev,03 Issuin; Pace Usw oQual0y, Office yven utaxneter, j Construction: /Steel/ Stainless Steel) Total Well Depth, 11A) — ff MumpActw. Static Water Level: 10-44, ---Jt pflons n0ght Qf wAter Column- 4-1 10-5'� CaL 3'.V6IuAIQs! gallons Pump ln'tgk&-'7'70 ft PmMe Intomation. Date. Pukged---q—/�-2�/ J-)-. Start: VO�-K Fjhjsh7 i Purge Method:�. Volume Purged, .Sampling Informatim Date:CoUect6&-cj—/,j$ Thhe Colleeted.. Sampling .Equipment Used: WA, Instrument ID, C) -f Pw (,0;")-+ Bottle Type Preservation Analysis Required . .......... ..... Field Measurements/Observations Sample Temp ('C)-, Ij.L Time; tLq_ Turbidity (ntu). Time-, _LLoo Diss Oxy (m S/L): tI -4 Time. 1 G Fe 2+.mg./L; Time. Specific Coud. uS)..... wi-� Time, Res. Cl (mg/L)/(gg/L): 'nine, Sample pH: (s. u,): (PA Time: i aq 0 P" ReDox (mV).- w s-3 'I line: Sao Appearance: Fime: 0LFU .ReDox (EH value)-.YSlProPlus.+200mV Other: Tie, General/Weather Observations; /rainy) Temp.--?,O (OF) Wind I (mph) Sampler Signature Stabilization Test Spec , Volume Time Temp, Diss Oxy, Cond. PH (".) ReDox Turbidity removed Water Other purged (OC). (us) (MV) (ntu) (gallons/e/ level. (ft) Is 0-3 Jos; 111-1 4 30, IK 1105 15 S- •15r 13ILi.1 G I Iwo Document Name: Docament Issued: >Glarch S, 2019 Field Data Sheet Page 2af I. Ce Analytical Document Number: Issueing Authority: F-CAR-FLD-001.rev.4. Pace Huntersville Cuallty Office Client: Location-, A��,-11c, Project: xl, emAe-_ CA �.�-�, 4.E � 141 Well ID, - Reviewed Date and By: Stabilization Test V eU Diameter Multipheation Factor'" 1 G. D403 1.2 0.0918 2 0.1630 3 0.3670 4 0.6530 6 1.4630 8 2.6100 Time Purged Temp. (°C) Diss Oxy. (mg/L) Spec. Cond. (us) pH (s.u,) ReDox (mV) Turbidity (ntu) Volume RemovedVilater (gallons/O/l.) Circle one -level (ft) Other Ijiii �Ly�Lo S�- �`t0.} 6•� }l,� ��a.l �� �5.5� m W10 f v5o )7,t, �i.�l 33 .W 4i5.0 i , C. (If - IiSS 3�G�".`3 y.c �j.4i l�Ic c�.41I — Dqmhi Namp: Pi,44,data shof bate P of. Pocumelit Number, AR-FLP-001-ray.0 IssuingAuttion -Pace-Muntfzr3Vf Office ? Clien : ) Name -and Affillation (Sainpler(s)k(� o -7 _e t . . Namc,and AffWation (Inspecto*z K4yu- Well Wormation W0111-D- L-,,7 -- k � Well Locked, I Well Diameten d- Construction, ftel/5taffiiess Steel) Total WdI Depth. — ft Muwaetdr*:LI'43 r(fI,,db.,,/1,2)2x3A4x7A8] Static Water Level: 7ft ('Stbg volume:... gallons Height of Water Columi�._ 7,� 3 ft CAI, 3.,V(jlumes, Fumalntako:_ Pmme: Information /60 Date. PtIrge.d..:Start: Purge Rate� 2.6 o r, PurgingMethod- V&111 alVbl..eFurged: .SaMlingInforinatiort Date CoUecfed, L( 2'Ir/. Z- Time Colleeted- Q/ pm) Sampling Equipment Used: e:�c t I C trumentID: � Bottle Type Preservation Anatysis Required 2,60; AA Fie] dMeasurements/Observations sainple Temp (Qq: / 3 _�-- me, Ti T�rbidity (ptu): 7 Time: / 0 / f Diss Oxy (mg/L)., O,V—Time. "M Fe 2+ mg/Lw b _-Jime. Specific Cozad. (uS): �YZ-6 Time IbIl Res, Cl (Mg/L)/(gg/L): uIrte., Sample pfi (s4u.): Time.- 0 1 I Odor, 4 e: ReDox (Triv)� Time., Appearance:. 41 + 6 r Time. ReDox (EH value)-.YST ProPlus +20OmV 5iQ er: — Time: General/Weather Observations: I sufcloudy/ rainy) Temp:. 11 ('F) Wind (mph) Sampler Signature: Date: Stabilization Test Spec.. Vo ume Time PUrged Temp. CC) Diss.Oxy, (mg/f.), Cond. pH (s.u.) ReDox (mV) Turbidity (nt .. u) removed (gallons/d G-d/ Water level (ft) Other (US� L) 1) VIIZ 0. "x 61, S 72,0 2 -3 a 7 Z --7 0.95< r 3 e 7, f 1 a ca7_29,7 L) Document Name. I�WIJ data8hept Date Issued. �f�reh $i 20i9' eo4A74NCN, Pa_t;e: I of r' Dcxu ment Nutliber: F-CAR-FI.t7-QDT-rcv:43 Issuing Aildhority. Pace.dItmfersvilleQualify i Office Field Data Sheet . I Name and Affiliation (5ampler(a):. i dl%1 " Ex4� Name.and. Affiliation (Inspector}:.. �✓ Well Information Well.ID: _ /t4 - 10 Well Diameter: Total Well Depth: -76' 9 7 ft rr4 y rac,A?- Statk Water [.eveff Height of Water Colu.rm, , 4-7ft Welt Locked: construction: Pro eet #: `-' 144 old Data Sheet Date - NO / Flushmount ) eel/Stainless Steel.) Multi Facioe- 0, / C3 r(twjus/12)2x -3:14 x.7,4si Casing Volume: 2 5-1 . .gallons Cat. 3 Uolunles iU S gallols Pump Intake: 7 GQ � ft G°- he i;v'e L F By: M642- C-C Cr Purge Information xzn Date Purged: -.-.--/ iPf.._.cj2 : Start: 3Finish. 10 5 1�argelate: 00./>"i') Purging Method: 111075900 Total Volume I'ur$eci: C/l G4 (gailaras J�'/ �} Samplin Ir�fo�:ation f �a0� S/5e2� Date Collected: 9-7— 'rime Collected:_'.--.-. pin) Sampling Equipment Used: /f147►_,k.-C C' Y7 Instrument ID: YS 3 7 70 I � � O Battle 'Type 3x 116or hiss 2k � ►wG ��fc Preservation G!. ��a 3 Analysis Required Field MeasuremeritsZObseryations f l0 o �;vs��2 Sample Temp (°C): _ i�ne:^II' 1zj._Turbidity (into), Time: 00 Diss Oxy (mg/L): d�yG Time, Fe 2°+ mg/L: Time: J Specific Cond. (uS): Time: Ides. Cl. (mg/L)/(ttg/L)- '�- Time: �~ �� 5"S,422- Safnple p.H (s.u.); — -.-Time: Cldor: ...—._ ��___ Time:.... _..._. RdDox (mV):. . T'ime: Appearance ��G��`s l Time: ReDox (PH v.alue):YSI. ProPlus #200 V...�'...3,.q.............Other: Time,- General/Weather Observations, cloudy/rainy) Sampler Signature Stabilization Test Wind F' (mph) Spec. Volume Time Temp. Diss ©xy. Cond • pH (s.u.) ReDox Turbidity removed Water off -ter Purged CC;) Ong/1.} (,,IV). (ntu) (gallons level (ft) L 10 Q l Q, 3G� ,3 S°'. 17, ` O o u 8 Ptn 0 1,6,d . [ -7, Z co r3�N t- 5, 7 0 �.6 �S (Q)N Document None Field data Shed Date! issued: March 8: 20 t9 t. C�i4lkff}�l�Cu?i' page:, 1 of bocumeni Number: F-CAN-EID-001-rev.0 i&Slllil� AUf�l� 1 race ,HlA13tQ $Vl7�C Quality w Offke _ Field Dais Sheet.- - n . Client:. Location; .- A5 IN -P, 0_ tl xaJect # AC f i Ve 5 Name:and Affiliation (Sampler(s):: S 1 1 AJ&& [NCO Yield Data Sheet preview: Q� r, �4 Name and Affiliation (Inspector).:' =� S- U Bate: : Well InforAkation Welt 0- � C±!leIl Locked: (�'/ NO :/ Vfushmount:)' Well Dieter: Construct onn ( /S(eel/Stainless Steel) Total Well Depth: �. �' Multi. Factor*: � V(Rac[iusjl2}i x 3;i i x i. t8] Static Water Level: ft Casing Volume: � gallons Height of Water // Cal. 3 Volumm � 5 � iJ -g�ifo is F uxnp. ntake Purge Information: Lv 14 / Z (,2 Bate Purged / / S.tart:�y� Fizirsii: Q_I't�rge Rater Lj 1% l,n Purging Me th,od: V_� �j •.,•• Total Volume Purged: I �� � (gallons/I,/f;): Samoing Infokmatio Date C Ilected:. L 1 Time Collected.:.— V �/� �� Pin). Sampling Equipment Used: C90 Instrument ID. . i °�� /� (� (�1 [� '3 - t -..- Bottl.e Type Preservation Analysis Required Field MeasurementsfObservations SampleTi�mp (°C) 5 ` irn,-:. -� _Turbidity (situ): Time: �— CDiss Oxy (mg/L)- t Time: 1E3r Fe 2+ mg/L:_ ���- Time: Specific Cond. W)., Time:. i f�Res. Cl (ing/L)&g�/)L): Tune: — Sample pFf. (s.u. ): �� — - Time,.� � .Odor:._._._ �!— Time:. = s iZeDax (mV): Time: Appearance: (E t" Fiore: RefDox (EH value):YSI Pro.Plus +20O.in.V Dther:: --'Time: General/Weather Observations: (sunny/c a�i 1 /rainy) Temp. .(d17) Sampler Signature.... lj ilir- Date: Stabilization Test Time Purged Temp. n (C) Disc Ox-y. (in$/l.) Spec. Cond. (us) pH (s.u.) IteDox (mv) Turbidity (E1tu.) Volume removed (gallons/no/ L Water level: (ft) Other n d!�eELk71y(1CQl Doom got €tme itEeld data5bec�f I]ate Tsaued IVTareh 8, 2�19 C)oeumeu#Nuriber F=CAR-RID-€01-rev.A I�suingAutltanEy.PareHtu�he�svilleQua[i,[y` office Tielid Dat .. S MenE: !✓ �' Location: Nawe and Affiliation (Sampler(s) �r L�i /�Yj - c� eL, Nama ,Arad Aff lWion (Inspector)-. Well Infoxtnation Well ID: _MLI'_ Well Locked: 0 . % Flushiitouz t. Well Diameter: construction � /Steel/Stainless Steel) 1 Total Well Dept,:. tt Multi.Faetot, t0 %�j, J r(Aadi a/-12)2x544x7.4,S1 Static Water Level: fE Casibg Volume.-�: gallarns" ,Height of Water Colum ii:1 �" ft Cal. 3 Voluzness gallons i'ur a In�vrlriaticr�t ' Date I'ux ed. / start Fi isl-�:�,,,: Purge Rate: O i'lA, f Purging .Method : - 'N\•,5V s d Total Volume Purged:..... v cs (gallonsQ Sampling Information. Date Collected Li 2iS D-Z Time Collected: / Z f-l. (am Sam piing Equipment Use& NV&J'l 5 c' 0"--n nstrument tD: ,/LB'{o�ttle Type PrreeJserva�ti�o. n Analysis Required; - vvL Field MeasurementsfObservations Sample Temp:.(°C). 1 � . � � irme: � �j � Z Turbidity (ntu).. Time: l 1 -2- Dins Oxy (rng/L):_ C1 ' � 7 Time;j J � Z Ise 2+ mg/ G: `Time: SpecificCond. (uS): �{faG� Time: /3/ Z Res. Ct (mg/L)/(gg/ L): ."- 'rime: � Sample p:H (s:u, ): � ' � _y Time: _ Z Odor: Time. ReDox (mV). `tS -7 ,�L Time: f' Appearance: C-Iva ( Time: / 3 / Z ReDox (EH value):YSI ProPtus:+20llmV Other:: Time: � General/Weather Observations: h, A rIA6 �-6% wcl, -4- C: &x ,n141! cloudy/rain}) Temp. � `! (°'F) Sampler Signature Stabilization Test Spey.. Volume Time Temp. a I7isa C� cy. Cored. pI-i (s.u.) ReDox Turbidity removed Water Other l?urged (C) (mg./I.), (US) (Tnv (ntu) (gall.c�1s / Ievel(ft) L l ��z 1,0, 014, 1 q,92, 65, 0.9 Zbou 33,b avo 3 y. 85 Docum ait Narne: Document lssucd: Mardi 8, 2019 Field Data Sheet Pal;e�t-af � 11,�acek7x iytical Document Number: Issueing Authority: F-OAR-FLD-001.re.vM Face Huntersville Quality Office Client: " L location: *5 '_L� A) Project; Well ID: I f Reviewed Date and By. q ��� I � AV\ Stabilization Test '��'a� M&tz Nell Diameter Multiplication Factor" 1 O.D4€}3 1.2 0.0918 1.623 0.1080 2 0.1630 3 0.36 0 4 0.6530 6 1,4680 3 2.6100 Time Purged Temp. (AC) Hiss Oxy. (mg%L) Spec. Cond. (us) pH (s.u.) ReDox (mV) Turbidity (ntu) Volu.rne Removed (gallons/efL) circle one Water level (ft) Other �{1. 51 ;z 56c �3 5, 0fr 02 ac,o 35.E f 30,� ,7 L( ' S . 3 u �5,� Date Wuhig AuthoAHy- Pace %noe Office: field Data. aheet. Client S )IJC-I. project.#: Ar Ion blame and Affillation (Sampler(s).Z.-A-04 WL& -AW- : Field Data nSheet Review: Noxneand Affiliation qnspector 14 - hate : H Well Igforfnafiaii Well ID IAO-Ilb Well Locked: N0 PfUshmount Well biameter., d C . onstruction., f Steel/Staiftless'Steel:) 7 Tpth otal Well De:. 31. 1c) ft Multi Fad&*'�-Q- V(R:ad -I�his/1232xM40.481 Static:W-ater Level:. 5'5-,.0b -ft Casing Volume: 5" gallant. H60itof WAter cqlumrt-!' L) ft C volu 5:. me AHons. Pump Infaki. A fE Tn By: iZ Purge Information Da -�,1411 Start. Finis Purge -Rate: P5 01 Bate Purged: ,Pttr&g Metho& Nyp ---jotal Volume Purged: (gaffo'15/04) j SaInplingInfortnation. Date CP'lloct�d Time Collected:. 133 0 Sampling Equipment Used, A&,-vN Alo-kAw' -----ffistrument ID: Bottle Type Preservation Analysis .Required. M/00 Field MeasureinentWObservations Sample Temp (Oq: 3-2.6 Time., I At _Turbidity bidity (ntu) Time; Ji3 6 Kiss Oxy (Mg/L): i,Q Time. )350 Fe 2+ in e. ) 3.5 0 Specific Conti., (-uS). q-15--CI Time: 630 Res. Time! Sample pH. (s;u).- C,S' ------- Time: 13 3O Odor: MN" --Time:j 5) 0 IK)ox (mil); 77-� Time: 056 Appearance- (($-I- 05';At, Tjme.--L?3 d ReDox (EH value)-.YSI ProPlus +200mV_2:7 Other: Time., General/Weather Observations, . U, /cloudy/rainy) Ternp.91� (*F)' Wind I (mph) Sampler Signatuxe;-64 -Dke Stabilization Test Spec..Volume Time Temp. hiss Oxy.Re Cond. PH (S.U.) lox Turbidity removed Water Other. Purged o (C) (Ing/4' (US) (MV) (ntu) (gallons I I L) level (ft) 51 (D -.1 6'T I 15 35.21 10, 131ti '2).6 9.1 C -q IL6.3 16.7 �G�A�k�dytiCat Document Nda PiOQ date shut I]attp Issued: Mftrdv&; 2019 lacx:ut�enk (`funaber E-C/#R-FI C��ft7 rev:0 Issuing AictlimRy Puce l-Ittntersville 06altty Office cloudy/rainy). Temp.: 79 _ T Wind G—S (Tnph Sampler Signature Stabilization Spec.. Volume Time �ttr��a Temp. e� CC) Di.ss-Oxy. Cond. pH is.t�.� lWox Turbidity removed Water ��„�� Other � ft�t�/�.) (�) (V) {tatty.) f��rr��f�l G��}; l 1ZU, RZ l.K qss te.s S��.Y. � bap 13.75 V 1R.1 l.�[ 95� (P-s bb.K I0. �--- 1235 14.1 a.t4 CM 6.5 ,,..o #ZOO J3.7S — )Zqv 6.4 100q (01:5 $H.Z ,., low 1S.7S 1245 1q.1 1 11030 1 �.5 .%3.0 Lj.s 2-400 M'7 ILsa 14.1 o.' 1046 ta.5 ja..v t.� 60Jvv 13.75 r- a ! ry��� �OCE139tNttt�€tritC t!ILI({ datd�alCi?E. Cate issued March 8, 2019 . Par: : � p{ L. .. G�An��tytictf Wcurnent Number., F-QAR-I.1D-o01-rev. Issuing, Authority. I ce t urifersvtlle Quality i, (]ffICB L Name and Affiliation Namplerfsl. xC ti D .Na meand: Affiliation (Inspector):-1 Well Information Well. III: M ~ P- D Well Diameter: yVI /� Total Well Depth: 39,X 9, X Static Water Level; Height of Water Column: ). OG ff N Project4: Field Data Sheet Review: M a,(- as Bate: H Well Locked: YES / NO / Flushmoutnt ) Construction: Steel/.Stahlless Steel.) Multi Factor*:.... Q � 63 dius/12)3 x 114. x 7.481 C8ing Volume., gallons Cal. 3 Volumesl -gallons Pump Intake: 37, 0 ft I da, Acbve LF 5A Purge Information. cc L Date Purged: LA./ g / 2), Start: 11 J Fin isIx Purge .Rate:�l vl f a Pu W Total Volume Pur e&. 3500 i Purging Method: � l`I5 l (: � g � _ (gallons. nos , L) Sampling Information Hate Collected:'_ _/L�/ �; U {� "ihue Cofleeted s �(am/ fe f Sampling Equipment Used: A6 4 �� 1�C- PIA M t`� Iaastrument ID; ki � �j T" 1f � # f �� Battle Type Preservation Analysis Required S! a wt L � �as�i ' �,n tires, 3-qD M(- as _ HCl VOL 3�-�i0 ML g ss ��r✓ i,y Field MeasarementsQbservationts �J Sample Temp (°C): � �T ante, �. G .-Turbidity (ntu): Time: 1),5 Diss Oxy (mg/L): Time: Tune: r� 55 Specific Cond. (uS): G77 Time: Res. Cl (nag/L)AA/(�� t /L)Time- Sample PH (s.u.); Qd.ar:�. _f_. . _ Time. ._„12.51_.._.. R Dox (mV): G7. Time: Appearance: ....cleaF li:nte.. 115-7 ReDox (EH valise):YSI ProPlus +200m.V outer: Time: General/Weather Observations. RM 56N� bc`% +tp5 I A +ke- f:�,+ FfbviapAj 50 Ohl? Ni�5 cvo55 owk- RA& ice,-1c'►b�,�e-A"��7" saran cloudy/rain{) Ternp. d�,("I) Wind i� '�J (inplt) Sampler Signatuxe. l & J� Date;q,hs,har Stabilization. Test Time Put eci Temp. oe Diss Oxy. M l.. Spec, Co.nd. PH (s.u.). ReDox Turbidity ntu a uine removed allons nil Water level ft Other zttV Q. 0 ,3 77� 6. �,MO6 3-35 a' 61 4. --� DtAp i 0. o 65 1019- 3] . 6 � r . 7 9� ia-g0 H 5 LJ � B 6.5 11017 off .! 0 q -- rjl�)u Rlt5 0.', 67S 65 47.6 X'3 �35UU 14,15 Dos'unient-Nome Field data 5t'ieet Pate Issued' March 8i 2019 Gotk7t liCr 1 iaf `Z . T7csrunient Number F-CAR Fl.t�-fi07-rev.p3 issuing Authmity;.Pace.Nuntersville CQuality'. r Office Field .Data Shea CIient: BLG Locafion A s eve l C Pra ect #: n u Name :and A.ffilzation (Sampler(s): MC - A Field Data SheetReview; Name and Affiliation (lnspector):� & Date: Well Inforanatiou 1-z Well ID; _Mw - l 3 Well Locked: ( E NO / Flushniounf Well Diameter..,, ,• Construction ('V %Steel/Stainless teei) Total Well Depth; I S• 3 6 ft Multi Factor*;. O• k U 3 r(Radius/12)2x3.14 x 7A&j Static Water Level: 4_ 31. ft Casing Volume. l 9 D gallons Height of wai ter columnJ 1 0 ft Cal.,3. Volumes: s' � � gallons rump intake: 3 ft By: I; F?Jew -AD "ZZ-S@rw� Pu a informatran Date Prra'ged: 4 / $ / 2- Start: 1 t 20 Fiz't'rst ., H05 Purge'Ra.te: &) 3 l.a.0 o Purging Method:S �a i�, c p �: P Tntal Vcslure. purged: ........... {gallons/Q'li} SaMligg Information: Date Collected: 1 Q 31 .k a- Time Coileeteci;_. Sampling Equipment Used-, �e�:s�c � �'� �v,�� Instrument 1D _ _'I S L D 2.O`[ , T_�� ��I (PL, Bottle Type Preservation Analysis Required Field Measurements/Observations Sample Temp (°C) l 5= -Time:. 1., l O—_Turbidity (ntu); t Time: I l D Diss Oxy-(rng/L) o-LI Time; I 10 Fe 2+ rng/L: Specific Cond. (US).: 11, `t Time:. l l I0 Res. Cl (nag/L)&g/L): ....._ 'l'izne: Sample pFr (&U.); —....,..._.�_...._._._. Le -(4 Time- . � I I o� C1dor: � 110 _ ._...� �.__.� l�eDox ( V): y �� �T me,, g L � to Appea a ce: C e cL . rime. 1 110 .ReDox (£.H value):YSI ProPlus +200mv 1 L "i 'a Otber.: 'T"ixrte: General/Weather Observations: u� %cloudy/rainy) Temp.. � ('F,) Wind 3 (mph) Sampler Signature: _Date.: - Stabilization Test Spec. Vea uia�e Time Tetxt.p: Diss C)xy: Cond. PI ReDax. Turbidity re��rgve Water th Other Purged Q (C) (rang/L) (us) (MV) (rito) (gallons/ / Level (ft) I to 5. LI l)o 4 -S L b 33 ' 32 0. ;t 't 4 Lo • S o (._v.'7 goo 1 1 10,55 .3,U 0•1 1,35.4 U-S —&,U Sr 3 1100 `A,UO [040 3. 0.co 385.0 G•5 —1z.-7 11.l IUOO ,03 DoeuiiteniNani ; DocanzentIssued- March 8 Field DAU..Sb. cet Pal eb£ _ Z. Dodmient #*#tunber: Issuiing Authority: '.. F--CAP.-FI..D-0014rev,03 Puce Hmitersvillo Quality Office Client t3LE Location: As1t e, NC Project:-- met..., t_F Apr Well lD: M w - 13 Reviewed Date:and By:._n�t1�,1 Stabilization Test lVell Diameter` � Xfultiplication Factor' 1 0.0408 12 0.0918 1.625 0-10so 2 0,1630 0.3670 4 0..6530 1.4630 2.6100 Time Purged Temp. ( 6C) ©,iss c�xy. (mg/L) Spec Cond. (ii5) pH (5.u.) ReDox(mvj Turbidity (ntu) oved Volume R. (gallons is%k). circle.one Water level � Other IiD`15 14O 0:5 361, t (n:5 -1$..�i `t.a 2000 1050 011A 0`1 36$.`t C.e. - ale, 4,1 2k00 Lk, 1055 N-U p.S 35i,`t (015 - a� 3 s ��� 4,-10 [to -Cl 0"1 3`ll.Z G,LP - 3k ' .a 320o y.-16 ilo� .15. 1 0.1 311.t U'U ---3 t.p 4A 3Uoo-- Dmument Name: Field data Sheet. Date Issued: March $, 2019, ::✓s'firr�7lyftG�l I?� e: 7 of Issuii1g Dace l t Document Nuniber: F-CAR-r7L i-001-rev:03 ftuiho ity. tuntersville Quality Office j, Field Data. Sheet VA 4 /2. Narneand Affiliation (Sari Namezrid Affiliation (Irtspector): M % Well Information Well ID: "M W ^ l3 !i Well Diameter: "i ; 11 Total Well Depth: 4 b , S 3 —it Static Water Level. TO 2 it He glit of Water Colxzmm 3_ , � ft Well Locked:. Construction: Proiect #:_.. ie -ld Data Sheet review: Date: NO / Flushmout t Steel) Multi Factor*: CAI0 r(Radiusf12)2x3,14x7,481 Casing Volume: V 4 4 - gallons Cal. 3 Volumes: 19 .3 _ gallons Pump Intake: By: Purge Information Dgte.PurgedStart: Q F'i.jisle: Cq40 P rgeRate: lUc�M�tl�t�} ve LP 5A A-, ��4 Purging Method:_ i'�i fit t°,�Total Volume Purged; Saanpling infor mation mate Collected:. 4/ / a Time Coiieet6d: Sampling Equipment Used:Pe,r 4* +4i" PaM P Irrstrumerit ID: Y5-1 0 56 Battle Type Field Measurements/Observations Sample Temp (IC): Dis's oxy (mg/i}: �J `Time: Specific Cocci: (US): °7 Time: Time: ReDox (mv): �,` '_5 Time: Preservation HtL . HNO3 Analysis Required _Tl A t,,, Z me -to, 1 .. ©T55. Turblclity (ntu) ' aA% - . i Time: ——..._..-..1 a 2+ .mg/L: ......_ Time: 1 Res. Cl. (gag/L)/(itb/L): �` hne: Odor:_ ...._ 4 ctf _Tirrte:— Appearatsce, „b cl ?-w4iluI.jL+K Time: ReDox (EH val€ze):YS.t..l ra.Plus +200mV : - � `�.5 Other: General/Weather Observations: Tune: rainy) Temp_ t7 (-r) Wind 4-14 (mph) Sampler SigilatumRmn B;r�1 StabilizationTest Time Temp, Feiss Oxy. Spec. on • pH (s.u.) ReDox Turbidity VO Lane removed Water Other Purged (°C) (mg/L) (mv) (ntu.) (gallons/ ils level (ft) L. o `z C5. 5 3ab.a b,'2 Go.q 00 3 6_ -z b Q. q b . f� c o0 "3 3� 6� Cr - 'Z 5 . q o o a. �! 0,6 1 �1 i t. ' S �aqS[) 5 �. 5. f�• act. S Znoo A, 12 � I?neunicynf N;�tnte_ I?acid data 5h4cf Elate fsaued: Marrh 8; 20,19 page; I of Document 1VuniGer: F=CiIIZ FI..tM01-rev:0 issuing Authority: Face fiuntersvitleQuality Office E� 1 blame and Affiliation (Sampler(s): i Narne and Affillat ion (Inspector):: , Well Information Weil 1D. NiV '" ILI Well Diameter:,..I Total Well Depth: rJ ft Static Water Level:29.97 ft Height of Water Colunin-12 iLft Protect #: L C Cel Field Data Sheet Review: Date.. 4WI1 Lacked: ' Y1 S / NCB / Flushmount ) CConstxuctiotm:: VC' Steel/Stairtless steel.) Multi,Faetor*, l ! t7 r(Radius/12)2 x 114, x 7.481 Casing Volume: 3,73 gatlons. Cale 3 VolurnQs. —H.,1gulio is Puna Intake°� fl Ac-b"I2 Cp .�LF�-5A Aprr 1 T — . a0 MC-- p Pmmt Information Date Purged: /.�/� °� Start :� � � Finish.—D.,30 Purge .l ate: i'Vlt A Fur&gMethod: j-je / j0rt50c�ln Total Volume Purged, SamDate r � deck �{ rntakion P - i' ..........--/2s/ Time Coltaeted;__p ) arri e,�. Sampling Equipment Used: Q a MM,5OOA Instrument ID: Bottle Type Preservation Anatysis Required 2GO A— IASfi �d �s _._ _....... Field .Measurements/Observationg y sample Temp (°C ;. l�, Time: 13 7 _Turbidity (ntu): o. L7 ,._ Time; A 35 Diss Ox. m L i 35 Fe 2+ mg/L: Specific'Cond: (uS); Time. 11 lies, Cl (nig/L.)/6--- g/L): Tirr�e: Sample pH (s;u,);� ...__._ _ Titne: I,........1_._� Odor: __. _._Titrt:e:. 3J _. . ReDox (rxmV): _ ©k�,� Time:. 35 _..,,l�ppearance., �� �1 Q 'iirne. 1135 ReDox (EH value) YSI ProPlus +200MV Other: - — TiM.E General/WeatherObservations: Sampler Signature: _Date-_ Stabilization. Test Time Purged Temp. °C ( ) hiss Oxy. m L ( g/ ) Spec. Conn. pH (s.tz,) ReDox mV (. ) Turbidity (ntu) o unme removed (gallons/ mTs Water level (.f:t) Otherg (us) L 6,2 0 la- - o �30. 6, G o � h 200 o, 3 7, ,� 5. 6. i0$. ES.1 5 '93 G. a '931.1 171,3 3600 30IT7 I�--� A I c���%Analyfical DOt'UmpntName: Field DAta Sheet Documentlssucck Mardi 8, 2}19: Pbcument Nuntlier: lswWft Authority; P-CAR-Fi D-tlf}7.rev.03 Face Huntersviile Quality Offiee Client: B L E Location, iL'�'Th�ilwl�C Reviewed Date and By: - �i - �`1- a ME A Stabilization Test Avelt I: ameter Multxpltcatxon Factor*. 0.0403 1.2 0.0918 2 0.1630 3 .. 0.3670 0-6530 6 1.4630 s 2_6100 Time Purged • -�Cond.s R # -Cf Turbidity; • s 1 circle one fOn ff I o Pogn: Iq#t Name biettl Data act Date I UE4 ] uMh.&, 2019. . g {{ t I'age: it ofZ' :.I. .: :.C7C3CUit1C�]t�]'.11t!.�?F"Ci�Ti FI.i�-0UI.FeY.fi.i:: 4suing uthority, Pace'Hunt@rsville . Qt4ofit . ..:f.lC£ .," .. .. f . tznn ciaudy/rainy) Temp.-6 Ak_._,.("F) Wind D 3 (mg ) Sampler signature:V,4e��. Dat OBI 2$(2oz2 :Stabilization Test Spec. a ua�ie. Time Purged: Tezxtp: a { C). Diss ©xy. (7ng/i..): Cond.: pH (s.�.) ReDox Turbrdity removed (galians/& Water levr I Other (us) (zztV) (ntu) vq L . . 1030 14.7 T (o 3S4.? -7..3 37.0 . 2.1 Soy 31.To bu 14.7 7.1e .3S4.(. 7.3 36.% 2.1 , 1035 iS Z 3.5 TJ.93 7.S 3q:4 Z.q: ►oaa 32 . f'I r- : . 1040 15.5 7.4 1.3 '44.% x.� 45CO 32.s6 �- joy5 S.'7 2.4 395.3 -7.3 35.1 3,3 2daa 32.71 DocumentName: Dg4'litllent I6S12ed:March'$, 2019 . elf`,B'Af7 lylica Held -Data Sheet Pal;esof� D6=11efil NuMber: fssueing Andlonrx: F CAR-Fi:D-001-re:.v,03 Price Hwiteisville Quality Office Temp:. hiss axy; Spec. ohd. pH (s.u. Re.Dbx (MV) Turbidity VolumeRemovedTime t-ril (gallons w Water leu€[. other Purled (00 (mg/L (US) (ntu). circle one. (fi ) 105a 1 b. 0 . q 333 fo "'. 3 35 5 . 2. b 2soo 33. c6 1055 i b. i 1.8 33 &3 7.3 37,E 3 G 30d0 33. 111 Docuoic;nt N,inje! I�ietd dnta Sheet Late Issued: March.8, 2019 c8FAnvlytieal Page:. 1 of � Document Numtev F-QAWFLD-001-rev.03 Issuing Authority: bare Runtersvitle Oua lily Office Erteict tiara bueet E Name and Affiliation (Sampler(s). 90 L iL Name and Affiliation (Inspector):A Well Information Well ID Aw-@ 7Z Well Diameter: 2 , (\ Total Well Deptb '21c,.'-t ' Et Static Water Level, I � •-L Height of Witter Columh- ll.'1) ft Well Leached: Construction: Field Data Sheet Review: Am Date YES ) NO / Steel) Multi Factor*: 040 0 r(R"u.us/42)2x.3A4x7A8l Casing Vriitime: 4 . s 3 galtons Cal. 3 volumes. �• a � . gallons Pump Intake: e-1 14 ft Purge Information Date Purged. �J /1A_/ 1A Start: r 0 Finish: V)iy auxge Rate: logm6f,�; � Purging Itsiethod: AIf c, '; _ �' m P Total Volume Purged, I,) (gallons/&'I.) Samulina Information Date C'aliecte>i: ... -22 Time Cotlecteitj _. SamplingEquiprnenl Used: {NOrEL FArnp InstrurrtentID: Y 1-056� Bottle Type Preservation Analysis Required L L - 4 `er4f,h,gd�o G�raR V fa4.1 i 0 3 ttt A r F pQk_>+5 ^tirCxr J'. y, N`a'�,�a�l� _-._. w �a .r t. i[y f C VLF rnr,. •1F�'�� e P,.1, `#'6 `l .. Field Measurements Observations Sample Temp (°C}; -_ z. 1 ime;� J `�_ Turbidityntu : 2 IQ Sn (: Time: ) i-i.,„........._ miss Oxy (mg/L):. o�,y'�... 'Time• Fe 2+ mg/L: V a lime RFS y/a3�zz Specific Cond. (US): _� _� ���, Time: Res. Cl (mg/L)/(ltg/L): Time: �— Sample 1IT_l (s;rt.): Time: C?dar �•�e `� ReDox (mV):..ii , g Time: Appearance: F tne: �. ReDox (EH value):Y51 ProPlus +200ttt.V 2 & 4,1 _ Other: Time: y/ratt y) Temp. 5 7 (7) Wind f),- 5 (mph) Sampler Signature: P.Y,5,A Pi '� -- -.--,Date: 2 Stabilization. Test Time Purged Temp. o { C) Diss Oxy, (tog/L) Sl3L'C. Cond. (uS) pH (s.u.) ReDox.. (mV) Turbidity (ntu) fi 1,tll1e removed (gatlot,.s nil Water level (ft) Other V3 715 3:9 q, Ztnq h4j A5. iFJ K Zko, r Document Name: Biala dato Sheet Date Issued,., arch 8; 2019 ' IxNge:_ I of:2 Document Number: -C 2-} I.I3 Q(tI-rev. Issuing Authonty ['are Htintersville QualityOffite �t Field Data Sheet Clientt—R-LV Location:_ALe_ rnn r !JL Prcaject.#: QrL�L �L1,yPl.�yY3Fr+i Z��� Narne and Affiliation (Sampler(s): M i 6�L &) Field Date Sheet Review; Name and Affiliation (Inspector): NZA- Well Inforinatioit Bate: � . By- Well ID.,. /A v/ —17 l2 Well Locked: Yl�sS` NO / Flushivtouni )' WeTI Diameter: , Zj, Construction T'V Steel/.Stainless Steel) Total Well Depth: 4l , 9 f ft Multi actor: 0 1t'3 ( (Ratiius/12)2:.x,114 x 7.481 Static Water Level: ft Casi.ng`Volume: 4.(y 3 gallons Height of Water Coludin: j, �j i ft Cal. 3 Volumes:i � �l Q gallons Pump intake: ft Purge Information Date Purged: 'i �_/ -L2- Start: 1 12 � Finish: . Pdrge:Rate: Purging Method. Per 3 ¢�1 #,'c ' ,r Total Volume Purged: � �O (gallons ls 1). Sarnplix Z Information: Date C:dilected: 27- Time Ce ected; 1ZtJ0 ._----- _ (a i'Iri) Sampling. Equipment Used:? 9 r; 4,w-f� & ?4 /-P Instrurnen t lD:_ 41< D S b �/ i ti��✓ 6 Y _._.e Bottle Type 11�JrnL Lf�a f or tali 4 _: S l mL Preservation H GL N . IAA�eS. Analysis Required t4 e- A g t v oG ._._._.___....•... L`IL APR'L M �kaf4i �7i 11r1^�•'-- �P .. Field Measurements/Observations Sample Temp CC): T.ime:;___I 2.49 Turbidity (ntu):, - , i Time: i 2� Diss Oxy (mg/I..): 4 Time: Fe 2+ zmg/L: jb Tirane: Specific Cond: (uS): _1 �606, Tinge: Res. Cl--- Sample pli.. (s.u.): �_ —Odor:— _ .Q ... lime:....._. 2T ReDox (.mV): . 0 Time, Appearance: Time, � ReTDox (E,H value):YSI ProPlus +200ni.V, ,0 Other: Time: �----- General/Weather Observations. /rainy) Temp." —(OF) Wind SA p (rnph) Sampler Signature. y r�5 — Date, --Stabilization Test Epee. Volume Time Tei1-p. hiss Oxy. Cond. pH (s.u.) ReDox Turbidity reillove Water ryy� Other Purged A (C) (ing/ L) (US). (mV) (ntu) (gallons/ Is level ft) 1 7. 7.0 61,4 1-9. &00 5, , 113 o ) b , "4 . ? ( 1,900 I1 `�-, Z7- 1 1_3 A iso 11 ti 17.'� Sk4U 3 1 4 A 3-0 1�na� ! 5C`��fi7lylltaa "s Docliirl nt.Neame. Field Data.Sheet ......... . ) CIE"iitYient I5Siwd. Ma.k'Ch:.�9, 2019. Paged of 2 Document Number: lssueing Rutlionty: F-CAR FLD-00I.rev.0a Pace Hurytelsville.Quality Office t'Vell Diameter Multiplfeati01% Factor* Cl lent: e L O:0408 � ender t 1.2 0i 0913 Location: � . � � 1.625 0.1030 Project, . �qnc� . Gy._A G4 _e- L-F A 14r.4'z 2 well ID. _ .M w- 17 1) lZ 3 063670 4 0.6530 c �� a� Reviewed: Date and. By: �� � ALM 6 1468t? Stabilization test � Z `� �� G-L G 8 2;6100 Time Purged Temp. {e Cj Disc C xy_ �jL) Spec. Co.nd. {usj pH {s.u.) ReDox (mV) Turbidity (:ntu) Volume Removed (gall'ons/&L) circle one Mter level { }' ` Other 114d1 J -7 1. i Lc7 -1000 t l. 15,14I. U&3 7 1 Y 6. b �. 3500 Docament Name: Mu1d data Sect fa�� issued: Mar�Ir,B; 2IM9 .. s G t?r?1 11C 1 . Pa: 1 of 2 Document Number F-CATt-T1.t5-4Ql-rev.Q3 Issuing AtItliaritydaree: �-iuntersville Quality i. Office Field Data Nlteef.. , : Client �•� _ mLocation, ��� �L Project #: he-4t%re S4 Lr hF?l _ 2p�t Name and Affiliation (Samp%er(s):: C3%jTC-R[A Ce Field DataSheet Review; Narne:.and Affiliation (Inspector):: ,.N(a 4 - Yl- a to n late::. By: Well Information 4 � Well ID: Mw - Well Locked: E NC) / Fltrslanlount Well Diameter: 2" Construction, 0/steel/Stainless Steel) Total Well Depth: 511:Ze ft Multi `Factcrr*' 0.163 . N[taellu9/12j2:x3,i4x7.481 Static Water Level, �W.55 fr Casing`Vciluane:: ` 0 gallons Heigh of Water Colurriii; .l'i:73 Jt Cal. 3 Volumes 40- 7:20 gallcins IL rZ Pump I'nfake: 51.,78 it Purge lnfoarruatiora Date Paged: 0 H 2� 2G22 Start 1�12a Finish; 1 5S � $0 Vt4yniri g � / / - �� I-tirge Rate: Purging Methoc : I4,s ,, NavlSoovl ,, �, Total Volume Purged: 2�oa (gallons jl L) Saraio:linLrInforina tion Date Collected: Time Coll&ted: 1500 (amE Sampling Equipment Cased :M" M"Soon nstrua en% li):r `1Sr 7wf -mW it 1e1ZZ,_ Bottle Type Preservation Analysis Required YpL i - 2SQm 3-4 0;rwl lass �QPt 3 - tf a Mt, tab!, VGC. H CL 1lQtr �'�elc1. Me_ asurementa/C)#sezyativ�is Sam' Ole T rrap:(° .): 18,1 lime: 1540 Titrhidity (zlth). 41,0s Time:. 1{ Diss Oxy (rng/L)- 24 Time _ I.5;00 Fe 2+ m . L: No Time: j 5ors Specific Cond'. (uS): ZU S Tirne:. 1500 Res. Cl (rng/. Ly(ug/L):. riff., --� Sample p.H (s.u.): {e.6 _. Time. /566 Odor: 1V'D Time: RdPox .(imV)c. 130.1 Time: 150 Appearance: {'.lQ Ti. rae: r ReDox :(EH value),YSI ProPlus t200mV '330,.1 Other: ~" Time: �r cloudy/rainy) Temp. S .CF) Wind O -S (mph) Sampler. Sign Stabilization Spec. an Vo ue Time ' Temp: Diss Gxy Cond. pH (s.a ReDox Turbidity removed Water Purged a (C:) (rng/L) (US) (mV) (ntu) (giallons na level (ft) L 1425 lb.+t 2.2 231.6 6.7 !2+ I 33.5 g00 soa 16.'f 2•Z 231.0 (0•7 121.1 291.3 r- nil 1430 161 2.7- 221.2 6•1 1zz.7 34.3 15W q's- xo l't35 1b.1 2.3 ZZJ.4 V.10 INO jq.8 lZ00 gs.(nl �-- KKa 16.3 2. ZZS..S to.V 127.6 2x.T 600 45.77- �- Dac neirtN rne: .......... . C)Cx �t nmiL lssu ck: March 8, 2012. ,. 11 !wield Data Spec t Rage 2-Of I Docunlent. N.r mbor: lsswing AA$Ority 3 P-CAR-FLD-001.cev;05 Pace Tili ntersville Q Mity office Lid ANTell Di eW -fultipheatiort Factor" Gll�ri�:.. 0.0408 Locatiom : Asher m.- , tJC, 12 1.625 0.10so Project:_L7uACGINb� _Qwf_ � PgAttrQ SA �F. AP [ 2z 2 011630 Well ID; ." i*8 W fl.36, [3 4 0.65M Reviewed Date and By; � ' � `1 � a a. Ep_ 6 A6130 Stabilization Test . q - .3 2.6100 Time 'hemp. (oC) Diss Oxy. (mg/) Spec. Corid:' (us) pH (S:u) ReDox (MV) _ _ Turbidity tntu) Volume removed (gail'ons/�1L) circle one Water level' (its, otherPurged l4�5 i�.2 3.0 2�i.'7 , t�.b. .. [27•�- Ig 8 �, Zcaa ' Ks.�t Itiso I .s ZA 222.'7 fo.lo 7,400 YS.-12 Ig55 Jt-7 3.0 223.3 129.8 a.5 Z$ao ys.�z _ Document i` amar Field data 5hett .. iafe Issued tvlar�h 8 2019 rage: 1 of! i�'CeAnatyiiC`r'� l)tx:antent Number: �-CAR-FI.i]-0fi1-cev.0,� hi ssuing Atithonly: Pace - I'�tuitenville Quality _,...-. � Office Field Data Sheet' one % ,,Z V-o t.,r Lte . i blame and Affiliation (Sampler(s};:L�"— (A Narne and Affiliation (Inspector):: rvjA .Well Informs an Well ID S w Well Diameter: Total. Well Depth:: tatto Water 'Level: Jt Heiglif of Water Column_ 77 ft Project.##: L(-' 5 APr, _ZXJ2Q Id Data Sheet Review: °# �0, C._2 G- Date: _ a - a by' Meg Multi Fodor, [*(Radius/ 12)2.x 3.14 x 7,481 Casing Vc lumei gallons Cale 3 Volumes: gallons Pump Int0e: ft Purge Information Date Purged . � / � / Start: Finish: r. Purge Rate: Purging Method: � Total Volume Purged-, gallons/utls/L) Sanin.iina:Information Date CoUecPte€!`.�/A / fiTime. Sampling. Equipment Used 6 cab Instrument ID;_rp"'a. Brittle Type Preservation Analysis Required aA Field Measurement§L0bservations Sample Temp- CC): S Time:-AAI-, ,_ _Turbidity (ntu): Time: Diss Oxy- (m /L): t"1 ,rime: 1 11 Sf Pe 2+ mg/ L: K D Time: 11l �._. Specific Cond. (aS): it`d-` Tune: l 1 ti �' lies. Cl {zz g/l )/(icg/l j: Iitne: Sample pH (0,u.): .._..... Tine:.... 11 Odor:.._.....-_.___-_N�) EE Time:... ReDox (mV): L47 S'5 Time: OK_ Appearance: C.le" w 1 f�"5 Time: 11. ReDox (EH value):YSI..Pro.Plus +200rxrV Dom` t�J other: Time: General/Weather Observations; 5S" L3 -fit` T N, — T)" 3T4 • I VJ (ni1 /cloudy/rainy) `l'emp k�_(aF), Wind"�— (r. Sampler ler Signature: _Date: Q`11-a--3 Stabilization 'Test Time Purged Temp. °C Diss Oxy. in I. Spec Cond. pH (s.u.) ReDox 111V Turbidity ntu Vo ume removed allans mis Water level. ft Other Document Name.: Field data Sheet Pate Issue& March 8 2019 �'i4t � 1yt1i x11..: I'a o: 1 ai �oc�arent Number: F-CAR-FF,17-f}Q1-rev.63 Issuing Authority; Pare Huntersuille Quali y Office Field Data Sheet' LF 5 A 0pn2o�)Q Name and Affiliation (Sampler(s): �� _�� Meld Data Sheet Review: Name and Affiliation (inspector }:..vl Bate: 'A JL i 3. By: l+'►CA Well Infor iation WWII IT3; �1 ' 41 Ln IaL YFS 7 NQ- Flushmount Well Diameten Cn Steel,) `i'iital ;!;Tell. Depth: ft Static Water Level: -- ft Height of Water Column-, ft Multi Factor-: rpzR'dius/12)2 0114 x 7481 Casing Volume: gallons Cal.3``Volumes" g lions Puiilp Intake: ft Purge Information Date Purged: " / — � �sart :- Finish- Purge Rite: -- Purging Method: Total Volume Purged-, (gallons/mls/L). .Sampling Information Late C oUecto&f: q_ /_- / Time Collected: ia2� ____ (&pin) Same ing.EquipmentUsed c- lnstru entlD:_.'Y5r..�i Bottle Type Preservation Analysis Required: �ti l r�jL Al? P 14S.i. l 4 Txc]yrnnaa Field MeasurementsObservations Sample Temp (OC):. }�}� Time: 1C1 S�;Tuxbid.ity{ntuj;: Lll�,r1 liaa�e. �Q�� Diss Oxy (mS/I }; Time: �a-�_.Fe 2+ Ong/i LI\i -:rime: 1 Q 3 �— Spec:iilc Co.nd. (uS); 4. Time: A_Q�� Res. Cl Sample f Fl, (s.u.); -_--- ------ T.i e:.Q�S_ Odor: ReDox (mV) `a Time; Appearance:5lcyln� ReDox (EH value),,YSl ProPlus +2OOmV; S� ,�- Other: Time- ---- General/Weather Observations: S y LA-3 "N -"$S° 3$, S" � �' V+/ su /etoudy/rainy) Tem' p., 6 t (°I') Wind(mph) Sampler Signature: late: Stabilization Test Time Purged Temp. //aC Diss Oxy. m L. Sliec. Cond. ply (s.u.) ReDox MV : Turbidity ntu V.oluilie removed / allans `mis ` L Water level ft Other p V3. S71a s . Document Name: Field data Sheet. Date Issued: March.8; 2019: /' tW e 7WIY Cxf ' Fa e: I of -4 DOCunient Number: F-CAR_FLD-001-rev.03 Issuing Authority: (pace Huntersville Quality tf Office L� Naive and Affiliation (Sampler(s); Nacre a°nd Affiliation (Inspector): Well Information We11 ID. Well Diameter - Total Wolf Depth: ft Static Water Level. -•===ft Height of Water Colurrtrr:— ft Project Field Data Sheet Review: Date: nS A �� By: t Well Locked: (YESY-N&I FhwhmoufEO Construction: (l' C Steele t rixdess•StL1) Multi FaCt0r*: .-- - ftRadius/12)2 x w A4 x 7.481 Casing. V01-U-Me: ---��� gallops Cal. 3 Volumes: gallons Pump Intake: - ft Purge Information. Date Purged , Start, Finish: — Purge Rate:— 1 urguig Method: Total Volume Purged: Sampligg Information Date Collected: / % L Time Collected. Sampling. Equipment used: Instrument ID. - Bottle Type 3x' -'V/- f� L c� Field MeasurefnentslObservations Preservation YC..( IAO 3 Analysis Required -- -04—:. _ ekgv V0C Sample Temp ): __._......Time: S. / Turbidity (ritu): /0I Time: �r Diss Oxy (mg/L): CQ Time: V Fe 2+ mg/L: &(,0_Ciane r Specific Cond. (uS): Time: Fees. Cl. (mg/L)/(gg/L): �"- Time:' Sample pH. (s. Lt.): � II _. Time: Odor:__.... ✓d/� �. -- Time: _ � � (�� ReDox (mV): i � . I _ Time: Appearance: % cJ, Time: ReUox (EH valrxe);YSI PrcrPlus r200mV 3-G Other: Tine: General/Weather Observatioiis 6_ cm� 3 S. -7 9- C 10 S - 9-2 • a 39 $ cig Sampler Signature Stabilization Test 9cloudy/ra:iity) Temp,' (°F) Wind (mph) Date: Z Time Purged Tentg. CC) Diss Oxy, (mg/L) Spec. Cond. (us) pH (s.u.) ReDox (Inv) Turbidity (ntu) volume removed (gallons/mis/ L Water level (ft) Other U e-115 N e- /� � ��sAn�dyti�al' [�aCun�ert#-Name: i?eeld daka ShceE Date Issued: March 8; 2t119 page: 1 of I . . T7�rc�in3ent Number: F-CAWFLIJ-0.01-rev.Q3 Issulrt�. Authority Pare,Htri3tersville'Quafjq Offke E Field Data Sheet Client., ..22 ....Location-.- � � �� 6� Project Name and Affiliation (Sanrpler(q):: _ �u .(,p .:. Field Data Sheet Reviews y Name and Affiliation (Ixnspertor):' Dater 4:Z j Well Information Well i17: Well Diameter- - -__ � ns €rc ` - Steel) Total Well. Depth: � ft Static Water Level: it FIeight of Water Colum=—ft Multi FactOr-- r (°(Radius/12)2 x 3'I4x7,481 Casing Volume: gallons Cal. 3 Volumes. gallons Pump Intake: ft Purge Iinformation Date Purged; Start Fitaisl : � purge Rate; f&—A 4�t LP S A A_� r , '11�1� 6— C C_ By ML-Vq Purging Method: Total Volume laurged:......: � {ga [oras%rinls/L) Salnv ing:Information Date Co llected;_�-i......._nl/ as Th e Colieeteclnn�pin,) Samling Equipment Used: 6 v,.ko—Instrument ID: 5—!����[�1 Bottle Type preservation Analysis Required l Hc4 :Field Measurements Obsm tions Sample Temp ,(°C): �a . �1�Ti�ne: alz✓ Turbidity (ntu) Time:..... Diss Oxy (mg/L): .C5 Tirane; ire 2+ mg/L:� Specific Conn. (uS): Time: _. Res. Cl. ( g/L (gg/L)., 71me; Sample pH (s.tl.): `__ Time: C>�I��Qdcar: _,._ ta��1n 1._ - , ReDox (mV): q. Time; Appearance: QavA, ReDox (EIS value):YSI ProPlus.+200m_V_aA_ I Other: Time: Generai/Weather Observations: QS " c- s Bunn eiaudy`/rainyy) Temp. � (-F) Wind (n1ph) Samplers Signature: -Date:Stabilization Test Test Time Purged Temp. °C Diss Oxy: rn L Spec... Cozad. pH I (s,u.) ReDox m Turbidity ntu Volume removed all.ons . rnls L Water level ft Other �� 'llnient Manic.- Field dale Sheet bake Iswec1, March &; 2.Eil9 - 1'a ye:: !of. ...... .Do.c inient, Nu 1I?= I CA.R-F7I.I�-QQI,-reV.,w - Issuing A(At ariiy e Quality Pare Mwtersvill y . _ 1 Office Field.Data She rst= ; . cuent., SLE T �catic�n:. r SL►2�rrl ia.. N� PrniorF 9- Runeal Sander Signature: " Uake: Stabilization Teat &Y_Lc�v►n4y. A& m Is I} L P F}prZ I. Time .Purged Temp. (�j Diss Oxy. (ing(T.) Spee, Cond.: (u5) pH (s.u.} ReDox (mV), Turbidity (ntu) Volume removed (gai.l:o��/nzls�/ L Water level {ft} Other Yr. � Do IE.1 b.s 14Z,4 a•a 156.3 ZI.6' Document Name:.field dat'l Sheet. Date Issued: March.% 2019 �11i<71}�llCt71� Page:. 1 of l DocumentNumbe[ F CAR-f'LD-001-rev;'0� Issuing �1uthoxtty.fareHu�ttersvilleQttal9ty' I Office Field Data Sheet Client:.Location-_&' .::.�, _ Name and Affiliation (Sarnpler(s):. i��t.CO— Name and Affiliation (Inspector); NA Ps Well Information ' S A- A P. a-0 � Field Data Sheet Review: Date y - a�1 By, Mc 2 Well Diameter: feet) Total Well DeptN.. tt Multi Factor`: r(RUtius/12j2x.114 x 7,481 Static dater Level: ft Casing Volume: gallons Height of Wafer Colunvl- �: ft Cal. 3 Volumes: gallons Puirip Irttal<e; ft Purize Information Date Puxgecl: /. / "_ Start: Pioisb: I'tgge Rate: Purging MMethod. Total Volume Purged: (gallons/nils/`L) SaMRIing:Ififormation ... .. . Date allectee[;.,. �lt-1 _/ / Time Collected _.�Q_._.__ k- j/p ) Sampling Equipment Used: � Instrument lD. _y /T Bottle Type Preservation Analysis Required Z=gomi. vtAs j- C.l . /iLfto Zyoc- 3--` Q s-iL vret �s' !-� ► �-1 7 aka :Field Measurements/Observations Sample Temp_ eC): 3 , - Time: L—Q..0—_ Turbid1ty: (ntu).; "� a T%�ne: �,C,1�0,�,� Days Caxy (gJt) ���_ 1'ircte; �_ Fe 2+ mg/[ : !V ] Time: u...... Specific Cond. (uS): Time: _Res. Cl (1 g/L")&.g/L): '" Time. —� Sainple pH (s,u.): `r __.. --- Time: M QC) odor:_.... -..—._.... .._._._ Time :..... _ �.,_.....— ReDox (mV): (,3 , Time. 1 ono Appearance: t n Time. I nop ReDox (EH value):YSI..ProPlus +200mV _� 6 3..3 Culler: Time: GeneraVWeather Observations: 61Q� Coo,ots � a` 3 3�z-t � �• / suru-ty/c oudy/raixty) e p. S`� .(°F) Wind (inph) Sampler Signature Stabilization Test Time Purged Temp. CC) Diss.Oxy. Ong/t.) Spec.. (n • pI-i (s.u.) ReDox (MV) Turbidity (tutu) Volume removed (gallons/nlls/ L Water level (ft) Other ------------- �� [)pwment Name -I- field data Sheet Date Issued. Marche: 2019: -� e�AnNy(iCd l Page:; 1 of '. doe ur€tenl IJurrstier: hlt f lai3 QQl-rev.©�; Jssuiiig Authority: Pare Auntersvil]e oUalfty Office :Field Data Sheet 3L Client: ocaton: As vt lt� . %F A{'% ZU L2 Name and A:ffilialon (Sarnpler(s) M GP- - Chet e Field Data Sheet Review: Ar Narne and Affiliation (Inspector) NA By: TTL Well lnfoLmrnatinn at G Well ID- Sw slzixtaurii J Well Diameter: C Total. Well Depth: � ft Static Water Level: - £t Height of Water Column. � ft Multi Fa0or*': ((Radius/12)2.014 x 7,481 Casing`Ydiume: gallons Cal. 3 VoluznM goom , Pump intake: ft Date Puxged:... /:. / Start: Purge e Rate, Purging Method- Total Volume Purged: Sarn€pling Information Date Collected: i4 /D S/ J a Time Cotleeted: Sampling Equipment Used: G instrument D:._ S 1 D. 2p 4 � T P,,r J sCQ& Battle Type Preservation Analysis Required 1C Ls{jn.L �lcs �`a H N0 3... � M e '3X k0Ci l�{-laiax�i..P Field Measuren ents/Observations Sainple Temp, (oC): 1 `t . ][azne: _IwI t'l C) Turbidity (ntu; 3. gTime : i t'i 0 Diss Oxy(mg/L): 5• `l Time.- �� (_ _ Fe 2+ rag/L° YbTirxme: 1H o Specific Cond. (uS): t i5$"1 Time: Res, Cl. (rngjd:)/(gg/LTime: Sam to �l. �.>�.: �.� l� ( ) _.._ _... Time:: E d Qciar: _,_..—.._.__ _ . C� �r�^�y Tine . _ ReDox (m V) L e S . i . Time: Appearance: rl v r k.4 'iT me. f ReDox (EH value):YSI: Pro.I'lus:+20.OmV --�tBs. t Other: Time: Genaral/Weatltex Observatioxts: (� S [.Qorcis ` 3 S l S$Q N - $� ° 3 S, SLo(; ` L &/cloudy/ ra r y) TempAP S (°F) Wind 3 (>nph) Sampler Signature: StaWlixati.on Test' Time Purged Temp. °C Diss Oxy. �� l Spec. Caa<d. pH (s.u.) ReDox M Turbidity ntu Vo tune removed allons rnls L Water level(ft)Other Le5. Z,I tjY Dmumenf-Name: Field data Sheet Date issued: iviarrh' 8; 2ii t9 � �Ai& tyttrr x71, Pa{�e: I of L i�omropt Number F-Ci R-r-1D-00I-rev.0 �ss�iiitg Authority: Pace,Fittftteesvlie Qualiey ` f Office rxem iiata bfteet Client. I�) Location: U Narne and A.ffaliaLion (Sampler(s)::��� - 16LLg_ Name and Affiliation (Inspecttrr):. _ h 1(r'4 _ ,_ Well Information Well LD, (yW4LLwked, Well Diameter: J-J Pro*ec..t #: aeO( Field Data Si eetReview; Day: Lk - )q as (PVC/Steel/Stairdess Steel) Total Well Depth: ft Multi Fa r(itad us j 2)2 x 3; !4 x 7,481 Static Water.Level: Et Casing VnIizrne: gallons Height of Water Colu x n �ft Cal. 3 VoNmesi —gallons r� SA APn aoa� :By: txn�p intake: Ft . Pur a Infortuation Date Purged: ,./ Mart : l'itaslt — - Purge Rate:__ Purging Method: Total Valzrme Purged: "� (gallons/mis/l>). Sate lin 1 iiformation Date Collected ,._C�` �f�/:_ .....Time Collected- 0 Li5�.___ n1 m) Sarnptirfg Equipment Used: Ir►strurnen(ID: '{ SL p M4 I -Pt' 9 30 P Preservation3-7 Analysis Required. Bottle e Alt tc,6, /,j 9 --LQ(- ULP—M Field Measurements/£ bservaticzris Sampli? Temp (°C): _.... ..__.Tznte: _j9`'t: . _Turbidity (,ntu): ( `�1 Time: Days Ox:y (mg/L): Time; a A Fe 2+ mg/'L:_t4� Time. Specific Cond. (uS).: \qQ •!j Time., I Res. Cl (nng/1,)&g/i,)'. '' ittrie: Sample l-f.. s.u. Time l� ) _�__......_....._ � �0dor:____N_1�._._____ Time:..._. R Dox (MV): s T me:. 10L Appearance: GI.C' Tin1e:�C�Ut,� ReDox (EH value):YSI ProPlus +200mV Di'_5 ` Oilier: Time: General/Weather Observations: is e 6 "3Li_'_ N , — �' 3�.`� S"r „✓ y/rainy) Tern Sampler Signature Stabilization Test mph) Time Purged Tenip. CC) Diss Oxy. (mg/I.) Spec. Cozad. (US). pH (s.rr,)Other ReDox (znV) Turbidity (ntu.) ei ume reproved (gal.Ioz�/n�ls/ L lEel kQ i "S .� t Sa� 1 1 t• Nci nient Name: Field data Shea Fate Issued: Ivtareh$; 21)19 /72COAna icdr rAKumentNumber: F-CARd F.J D-OoT-rev.o3 Issuing Authaaaty.: Nceffiuitersvillie Qua lily Office L- rieiu Lima. meet -- in, Name and Afffllation (Sampler(s) ;Field Data Sheet Review Name and Affiliation (Inspector): Well Information : Date al -aa . -' L % 1, *ES � ,.- e , Fin,! Well ilk' �,�..............__�. J�'�ll-l�0�2�; nt 1 Well Diameter, I `fatal Well Depth:. -ft Static Water Level: €t Height of Water Column. - '� ft Multi Factor*; - r(RadEus/22)2.ae 3.1 x Z, 3] Casitig'volume. gallons Cal. 3 Volumes: gallons Pump intake: It Purge Information Date:Purged,—/ � ./ Start: Finish- PLIx ate:ge G-LC� By ME R Purging Method: Total'Volume .Purged: � (gallons/.m1sJ`L) Sairinl ng Information Date Collected, O�-k ./ / a Tiizre Cvlleeteu _�Q� {am/ Satrtpling. Equipment Used:_ Instrument ID--e Bottle Type Preservation Analysis Required L Figld MeasurexnentgQbservations SampleTezx7p.(°C):. S OA_.._._ znie: Turbidi.ty (ntu): Time-, Digs Clxy (mS%L) `grr:_ 1`iirte: —L-Af&—_.Fe 2+ mg/L: .. ...—Tame'.__ Specific Coiid. (uS): b Time 1 �I � Res. Cl (tijg/L)/(gg/L.): _ Thne: --- Sample pH (s,u.): �1�._.M..._.,_.._ Time: Odor:—_. ReDox (mV)— S3Time . �� Appearance: �W�` �le'� Time: +�l ReDox (EH value):YSI ProPlus +2OOmV Other: Time: �— y/:rainy} Temp. . ff) Sampler Signature Stabilization 'Test Time Purged Temp. (°C) Disc Qxy. (ing/T). Spec.. Cond. pH (s_u') ReDox (MV) Turbidity (ntti) vo ume removed (gallons/mIs/ Water level (ft) Other Document Name: Field data Shut Date Is��ied: March8; 2R19' Inge:: 1 of t7G h7iyliCGf(M Issuing Atithority raceF{iuitersvil]e Quality f Document liltiYrkbmF-CAR-i.lD-001-rev.03 'off.ICE'. Field.Data Sheet' Client: L Location:5.. . N.� Project #:nC . C0 ,E +vc { [' a Narne and Affiliation (Sampler(s)., Z� R4 4-9- field Data Sheet Name'and Affillation (l peetor}:; Y. MAR Well Information Well ID: Well Diameter- Total Well Depth'.. -Et Static Water :Level: ft Height of Water CalurEin; ft PuMe Information Multi'Factor*- ( (Riadius/12)2x. 1.4 x 7.48] Casing Volume: gallons Cal, 3 volu rtes; �gallons Pump intake: ft Start : Fi tr"sh ' Forge Rate: .--- Purging Method. --Total Volume Purged: (gallons/mis/f ) Sarr[wligg_Information Cate Cai7ectec .,..W. ..,_./��..... ate._ Tint Collected:. m. Sampling .equipment Used, r�InstrumentID: Y tc, i Una }k Oao Cry 1'Pt. 3 Bottle "hype Preservation Analysis Required Field Measurer ents/Observatioes Sample Temp (°C): 1� ,�� Time, i ��a ._Tiixl�stlity:(niu}: ' .Time; Diss Oxy (mg/L): ' L Time. Fe 2.+ tig/ L. ) , C) Tune: J —. Specific Cond. (uS)Thne:. 1 �� 0 Res. Cl (Mg/Ly(pg/ L): ' ime: Repox (mV): Time: Q Appearance;CyneThiie- ReDox (F.I-1 value):YSI ProPlus +200 V Other: Time: General/Weather Observations. 1 cloudy/rainy) Sampler Signature Stabilization 'Test Wind !I Time Purged Temp. CC).. Diss Oxy. (rrtg/I.) Spec. Conci. (us) pH (s.u.) ReQox (IIIV). Turbidity (tutu) Volume removed (gal.l:ons/mis/ Water . level (ft). Other `3 -7 = . i]cxunitnf IVanSe_.Fieltt clnta5heet Date Isxuecl:?1Viarch.8; 2019 � Lk lyflCc?I Page:: 1 of Docunoent Number, F-CAR-FLD-001-rev.03 issuing Attti-io ity° Pace tiuuitersville C�ua.lily Office Field Data Sheist Client: Narne and Affiliation (Sampler(s) ' '?u.U2 FPieldDatcaSheet lieview: Name and Affiliatioxn (Inspector) /i�Well Information Well ID: 1--� Mali_i:nekP& r YES I BI � >~tti�l,.;,..Funt Well Diameter- � Const ess Steel) C�. •�-e L r� S A AA) r D By: MR Total Well Depth: ft `Multi Factor*: � V(LW uR/ 2)2 x3:1.4 x 7,48] Static Water Level: ft Casing Volume: gal Ions Height of Water Columf; ft Cal, 3 Volumes: � gatlorts PUITip intake: ft Purge Information Start: `-' Punish: Purge late: Purging :Method :. Total. Volume Purged:.........(gallons/ml.s/L) SaznWinLyInformation Date Collected: Time. Collected:' 1 ` _ (azzt/: in)` Sampling;Equipment Used:J_7-er�,SW. r —.......... ,—InstrumentID: YS:C t P r —- Bottle Type Preservation Analysis Required L.. G Field Measurementslobservations Sample Temp: (°C); AS , � _ Tine ._: j _Turbidity (ntti): �"i , Time; Diss Oxy (ptg/L): .o Time. Fe 2+ mg/ L;__...... ..:.Q......_---- Tune: Specific Coiid. (uS); _K_ Time `-t _�Q Res. Cl (mg/L)/(gg/L)i — `I"izne: Sample pH: (s.u,); 5 Time., ti' Odor: ._. 3 G� Tune• ..._. ReDox (mv): -"� �� Time: l ` ',O Appearance: GiE C i xne; k �1 7Q ReDox (EH value):Y5I ProPlus +200mV Other- Time: General/Weather Observations: cloudy/:rah-ty) Terr Sampler Signature Stabilization Test Time Purged Temp. (atu) Diss OXy: (ing/I.) Spec. Cond. (uS). pH (s.u.) ReDox (inV) Turbidity (,�ltu) Volume removed (ga.11:ons/ntls/ L Water 'level (ft) Other i�ocunicnt dame. Field data Shed Date IrAuecf Mamb &; znq. C�"A17rfyitCe?l I of �: I)EiC1iEA@I7( Number . -'.I, -00Z T'W,0,'�i fss€ ing Authorily:. Dace faint rsvflle Quality .1 Office Field.Data Sheet Client: Location: Protect #: Name and Affiliation (Sampler(s),= — r Q Field Data Sheet Review: q C L G_ Name:and Affiliation (Inspector):... NA > G Date:: %4 a 1- By: Well information Well Diameter: Co � ' a Steel Total Well Depth- ft Multi'Faator*: V(Rgd us/I2)2x,%14x7A81 Static Water Level: ft Casing Volume: gallons .Fleighf pf Water Column- � ft Ca[. 3 Volumes: gollans Pump Intake: � ft Purge Information Date Pu ged- Start "` _ 1?!nis ; Purge Rate: Purging Method. -- - Total 'Volume Purged: (gallonsf mis/L) SamulinE:Information True Collected: � " 1 S.-._ (ari / Sampling:Equipment Used. ���1 l2 ( Instrument ID: _7- s Bottle Type Preservation Analysis Required t aS`z1 �•�L l �c LNG Field Measurements/Observations Sample Temp (oc): bidity (ntu): Time:.... Diss Oxy (mg/L)-, 1, Time: l k K . Fe 2+ mg/ L: ND e: Specific Cond. (uS): � Time:. "t`-l- Res. Cl (ling/L)%(µg/L): Time: Sample p.11. (s.u); ReDox (mV); I. Time: I `i Appearance: 6e: 1 1- . ReAox (EH value):YSI ProPlus.+2OOmV I (Other: "� Time: General/Weather Observations: sur�n cloudy/rainy) Temp.4- ) Wind (mph) Sampler Signature: 0,1L. Stabilization Test Time Purged Tem:..p. CC) D3ss Oxy. to L Spec.. Cus) IaIi (s.u.) ReDox m Turbidity ntu Volume removed allons niis 1 Water level(ft)Other c� ��� CeAtt�iyfiGF71 r Dmuetent Name-- Field da(a Sheet. Date Issued: March &, 2019 Page: I of J i)cun►er►t Number: I-2AR-FI.D-001-rev;0i Issuing Authority: lace lituttersvil[e Quality Office Llp�_ . Narne:and Affiliation (Sampler(s): Name and AffBiation (Inspector) ,r 3 i . Well Information Well ID. r -- 5 e t' Project #:�W1f field Data Sheet .Review: Date: Li Welt Diameter* C s teel:j Total Well Depth � ft Static Water Level: ft height of Water Colur n: ft Multi Factor*: [*(Radius/12?2. x3. 4 x 7.481 Casing Vbluzne: gallons Cal. 3`Volumes: gallons Fun-fp Intake ft Co. ,A-c, ,F sA a� C-C G- By l`� E R Pyx a Information Date Pux&d. � ./ / 7- Siart : --- pia lsl' Purge Rate: Purging Method: Total Volume Purged:(ga.Rons/.mls/L) Sampling Information. .. .. . Date Coilectei{: ct,� Time Ccsllecteo Sampling: Equipment Used: 'Y S it jlc � C� � O - �ttra r{'c �t 3 o Bottle Type Preservation Analysis Required Field Moasurewegt0bservations Sample Tom C ; b Time: Turbid* ntu ': CI 6 Time; hiss Oxy (xng/L); s Time: Fe 2+ Ong/L.; N� Cime: Specific Coed. (uS).: Res. Ci (nig%L)/(lib/L): --nine: Sample pH (s,u.): � � ..__ _ 1 fire: ���� Odor: Rel ox (rnV) g '� Time: J 3-OS Appearance: Claud, ReDox (EH value):YS:I ProPlus.+200mV 2EL(7ttier: Time: rainy) Temp....., (-F)' Wind K (m.pn) Sampler Signature, Stabilization Test Time P Purged Temp. °C Kiss DXy. m 1. Spec. Coed. PH (s.u.) ReDox my Turbidity tltu Volume removed a lons nlls L Water level ft ether 93, , f C]a un�tnt i` ame-Yield data Sheet: Vate lssued:March 8, 2010 Page: 1 of T Qcurment Number- f -CAR-FI.D OQ1-mv,63 .. l"uffig Authority. Pare.Huntersville Quality Office Meld Data Sheet Client: —Location yl_e Name and Affiliation (Sampler(s). �0`�-� -Pa L'C_ Field Data Sheet Review: Name end Affiliation (Izlmpector) N Pr. i4 Well Information Date: Well. ID: UD 11 Well Diaineter: COtee tarn e. Steel) Total Well Dpptb:. Static Water level: ft: Heiglit:of Water Column: ft Purse Infoarntation Mu1tl.FiieW* . V(Radius/ j2)?x M4 x 7A8j Casing Volume. gallons Cal. 3 Muincs —gallons Pump Intake: ft urSal Ape �n Cos_ By: MEA Date Purged: / = / Start: . vihisll: Purge Rate: purging Method: Total Volume Purged: (gallons/mis/L) Sa nRlin&Mforntation . . Date Collected,. O/ / Time Collected, `95 QQ Sampling, Equipment Used: _00Q . 5c,'Lar ..,..._Instrument ID: `I rn UA Sur (a)_Q Bottle Type Preservrattion, Analysis Required. 7 Field Measurementt3LMservat.ions Sample Tern,p-(°C): Q,a. Tune:QO ,_Tirlaidi.ty (ntu};:_a, Time: Diss Oxy (mg/L): a.�J Time: 1 5CO Fe 2+ €ng/L: "I':ime Specific Cond. (uS): Time: I Res. Cl (mg/1 (ttg/l ): I ime Sample p:1-t (s.u.): ..z_=. ...... ...w'Time: I QQ Odor:AJD ReeDox (mv): _-- Time: i Sow Appearance: C�POC Time:. ReDox (PI-1 value):YSI: Pro.Plus +200mv �1 S O Other: Time: General/Weather Observations: ---- -- cloudy/rainy) Temp? �.. (,IF) Wind (mph) Sampler Signature Stabilization Test done Pu.r edi Temp. °C. DissQxy. 111 . 1. Spec. Cond. ply (s.u.) ReDox MV TUrbidity ntU V.n tiime removed allans ells L Water level ft Other :�c���t}�tiCF7C � . i�pcumwnt Name: I�Ic�lc� clataShec( ::O9 DAteIssued:March;, 2 Page: ; 1 of i?c7Gunierit Number. P-CAi?-f'I I;3-0UI-rev.; Imuing Authofity: Pace Runtersvitle Ouaitty Office Field Data Sheet CIient.: Location: A_)L Prca'ect#:&LL_. Name and A:Efillation (Sampler(s):_�� Field Data Sheet Review: Name and Affiliation (Inspector):..N3 A .Well Information Well ID: � LfC&C%�� L� . nth Well Diameter- `^ - Steel) Total Well Depth: -ft Static Water Level: ft Helght.af. Water CO]umn- ft Multi Factor*: ((Radius/ 12)7 x .i x 71481 Casing Volu-me:. gallons Cal. 3 Volumes; g�ItIns Fume Intake: ft P%Me'Information. Date Purged-.' / " / . Start: Finish.,Purge !Fate: Purging Method:— Tonal Volume Purged: (901lons/.rnls/1;) Sanivliniz Information L� 54 Date Collected: 01A 7 Tiillt? COileCt d (cam 72It /? SamplingInstrument.lD: , Equipment[used:_ (J �i� .. ,...`. Bottle Type Preservation Ana.lys.is Required AQ)V I-' Field Measurements/Observations Sample Temp (°C): _ `"� Time: Turbidity (ntu): Time: hiss Oxy (mg%L): `a-,� Time: X_�) Fe 2+ mg/ : N17 Titzte....�.��'J��f SpecificCoael. (uS): <�6�_ Time: Res. Oi(mg/L)/(pg/L) 'Tine: Sample.pH.(s.u.): �__.-._.,.Time: Odor:N..D.__..._._.___ _lime:..,.�W ReDox (mV): Y',L Time: _ Appearance: CS rime: 1 Z�-(. _ ReDox (EH value),,YSI ProPlus +200mv Other: Time: General/Weather Observations; . 1"C'Y un-n . cloudy/rainy) Temp (°II) Wind 9 (mph) ,171 r Sampler Signature Stabilization Test Time Purged Temp. a (C) hiss Oxy; (�rrg/f } Swec. Cond. (US) pH (s.u.) ReDox (irYV} Turbidity (ntu) Volume removed (gall.ort5/znls/ Water ,level. (ft) Other -•6 V � L V r� 1 Y � � Q"� Fapcuntent Dime 1?ieycl data 5hc;tt r7G i�ilrr lj/�1�r i Page: 10f � Pocument Number: F-C�tR-FI D-001-rev.6 1"ubig AttflEoiily: Cacti Hunterwille Quality r (iffica Field_Data Sheet Client ent; i- Location: S vt �_ ruC_ 'rafert`#, LV75A AoS aU c� Name.and AEfillation (Sampler(s).: 74 P6 CZ Field Data.Shaet Review: C Name and Affiliation (lnspectar}: tv �� . �(, zR L? C G Uate: ►� _ �°� as By: Well Inforinatipn. Well ID: Lea Gyvx�e- Ana Well Diameter: Total WolfDepth: � ft Multi.Faefor*: [�(Raelius/12)2.x 3,14 x 7,48] Static Water level: ft Casing Vblurne: —` gallons Height of Water Calumn, r ft Cal. 3 Volumesgallons twillliif�zl<e: ft Pur a Informatioa Date.Fuxged: / `'` % Start: Finish: Purge Rate: .Purging Method: Total Volume purged: _ (gallons/rrds/L) Sampling Information / Tate Collected lz,- 2Q_ Thne Collected: t?�'t <q (an Sampling Equipment Cased: 2. (V-- Instrument ID: � � Battle Type Preservation Analysis Required 547 �o i co Field Meeasu€rementglObse:rvations. Sample Temp (°C):. �-"� �� Time; ti ._ Turbidity (ntu); j Q S .1 Time: Diss Oxy (mg/L) 1'3• Time. Fe 2+ mg/L: Specific Cond. (uS): J�nQS Time: c�`'� lies. Ci (zi g/C.)&g/L): Tune: Sample pH (s.u.); .,...m.... ........., Time: ,. J�-tS................Odor:_ ReDox (mV)Time,. 1.'ZC- Appearance. Aq . n Time: ReDox (E, H value).YS1..Pro.Plus +200m-V L- Other., `�T Time: ""— General/Weather Observations; cloudy./rainy) Temp.,,('F) Wind `I (mph) Sampler Signature Stabilization Test Time Purged Temp. °C Diss Oxy. rn spec. Coed. pi .(S.tr.}' ReDox. MV Turbidity t1tu. a tame rernoved al.tons oils L Water level -ft tither APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Active Buncombe County Landfill Lot Number:XD27064 Date Completed:06/01/2022 NO N � � J N N � 06/03/2022 10:37 AM Approved and released by: Project Manager II: Lucas Odom pCC/►F� 24r�A SOA ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 183 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: XD27064 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. Inorganic Metals The following samples were murky in appearance therefore in order to protect the integrity of the instrument they were diluted: XD27064-016, XD27064-035, XD27064-040. The LOQ has been elevated to reflect the dilution. The instrument blank for analytical batch 40010 contained Be greater than one-half the LOQ. The data have been qualified and reported with a "B". The associated samples are non -detect for this compound. Inorganic Non -Metals The following sample was analyzed outside of analytical holding time as it needed to be analyzed at a dilution: XD27064-035. The associated MS/MSD was not spiked so an LCSD was added to the batch. Reanalysis of the following sample was performed outside of the Sulfate analytical holding time as it required a dilution. XD27064-032. VOCs by GUMS Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 40161. An LCS/LCSD was run in lieu of an MS/MSD. The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 183 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 batch 40827 exceeded acceptance criteria for Acetone and 2-butanone (MEK). These analytes were biased high but not detected in the samples affected. The laboratory control sample (LCS) for analytical batch 40807 exceeded acceptance criteria for Acetone and 2-Hexanone. This analyte is biased high but not detected in the samples affected. The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for analytical batch 41354 exceeded acceptance criteria for Acetone. These analytes were biased high and were not detected in the samples affected. The laboratory control sample (LCS) for analytical batch 41247 exceeded acceptance criteria for the following analytes: Acetone and 2-Hexanone detected in the samples affected. Due to the large number of spiked analytes, there is a high probability that one or more analytes will recover outside acceptance limits. The laboratory's SOP allows for 10% of analytes to recover marginally outside criteria. 2-Butanone recovered marginally outside LCS criteria in batch 41247. Surrogate recovery for the following sample was outside the upper control limit: XD27064-017. This sample did not contain any target analytes; therefore, re -extraction and/or re -analysis was not performed. The laboratory control sample (LCS) for analytical batch 41438 exceeded acceptance criteria for Bromomethane. This analyte is biased high but not detected in the samples affected. The laboratory control sample (LCS) for analytical batch 41457 exceeded acceptance criteria for Acetone. This analyte is biased high and not detected in the samples affected: XD27064-024. Reanalysis of the following sample was performed outside of the analytical holding time: XD27064-016. The sample was initially analyzed within hold time at a 5x but needed to be rerun at a lower dilution. Re- analysis was performed at a 1x with concurring results. Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 42503. An LCS/LCSD was run in lieu of an MS/MSD. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 3 of 183 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: XD27064 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-13D Aqueous 04/26/2022 0955 04/27/2022 002 MW-1OD Aqueous 04/26/20221015 04/27/2022 003 MW-10 Aqueous 04/26/20221040 04/27/2022 004 MW-6 Aqueous 04/26/20221240 04/27/2022 005 MW-7 Aqueous 04/26/20221345 04/27/2022 006 MW-51D Aqueous 04/26/20221450 04/27/2022 007 MW-5 Aqueous 04/26/20221600 04/27/2022 008 MW-3R Aqueous 04/28/2022 0955 04/29/2022 009 MW-17R Aqueous 04/28/20221050 04/29/2022 010 MW-13 Aqueous 04/28/20221110 04/29/2022 011 SW-4 Aqueous 04/28/2022 0935 04/29/2022 012 SW-6 Aqueous 04/28/20221000 04/29/2022 013 SW-2 Aqueous 04/28/20221025 04/29/2022 014 SW-8 Aqueous 04/28/20221045 04/29/2022 015 SW-1 Aqueous 04/28/20221115 04/29/2022 016 SW-7 Aqueous 04/28/20221140 04/29/2022 017 MW-14D Aqueous 04/28/20221100 04/29/2022 018 MW-14 Aqueous 04/28/20221135 04/29/2022 019 MW-8D Aqueous 04/28/20221011 04/29/2022 020 MW-8 Aqueous 04/28/20221200 04/29/2022 021 MW-21D Aqueous 04/28/20221000 04/29/2022 022 MW-2 Aqueous 04/28/20221110 04/29/2022 023 MW-4D Aqueous 04/28/20221230 04/29/2022 024 MW-4 Aqueous 04/28/20221305 04/29/2022 025 SW-3 Aqueous 04/28/20221400 04/29/2022 026 MW-11 Aqueous 04/28/20221312 04/29/2022 027 MW-11D Aqueous 04/28/20221330 04/29/2022 028 MW-1D Aqueous 04/28/20221400 04/29/2022 029 MW-1 Aqueous 04/28/20221440 04/29/2022 030 MW-17DR Aqueous 04/28/20221200 04/29/2022 031 SW-5 Aqueous 04/28/20221345 04/29/2022 032 MW-12 Aqueous 04/28/20221255 04/29/2022 033 MW-12D Aqueous 04/28/20221255 04/29/2022 034 LD-5 Aqueous 04/28/20221205 04/29/2022 035 Leachate Pond Aqueous 04/28/2022 1245 04/29/2022 036 Leachate LID Aqueous 04/28/2022 1325 04/29/2022 037 LD-2 Aqueous 04/28/20221340 04/29/2022 038 LD-1 Aqueous 04/28/20221405 04/29/2022 039 LD-3 Aqueous 04/28/20221430 04/29/2022 040 LD-4 Aqueous 04/28/20221445 04/29/2022 041 LD-6 Aqueous 04/28/20221500 04/29/2022 042 MW-18 Aqueous 04/28/20221500 04/29/2022 043 Trip Blank Aqueous 04/28/2022 04/29/2022 (43 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 183 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-13D Aqueous Barium 6020B 83 ug/L 19 001 MW-13D Aqueous Cobalt 6020B 4.3 J ug/L 19 001 MW-13D Aqueous Nickel 6020B 1.8 J ug/L 19 001 MW-13D Aqueous Zinc 6020B 3.6 J ug/L 19 002 MW-1OD Aqueous Carbon disulfide 8260D 0.81 J ug/L 21 002 MW-1OD Aqueous 1, 1 -Dichloroethane 8260D 0.65 J ug/L 21 002 MW-1OD Aqueous Barium 6020B 130 ug/L 23 002 MW-1OD Aqueous Chromium 6020B 3.9 J ug/L 23 002 MW-1OD Aqueous Cobalt 6020B 2.5 J ug/L 23 002 MW-1OD Aqueous Copper 6020B 3.5 J ug/L 23 002 MW-1OD Aqueous Lead 6020B 0.40 J ug/L 23 002 MW-1OD Aqueous Nickel 6020B 9.5 ug/L 23 002 MW-1OD Aqueous Vanadium 6020B 3.6 J ug/L 23 002 MW-1OD Aqueous Zinc 6020B 33 ug/L 23 003 MW-10 Aqueous Antimony 6020B 1.8 J ug/L 27 003 MW-10 Aqueous Barium 6020B 27 ug/L 27 003 MW-10 Aqueous Chromium 6020B 1.5 J ug/L 27 003 MW-10 Aqueous Nickel 6020B 6.6 ug/L 27 003 MW-10 Aqueous Zinc 6020B 13 ug/L 27 004 MW-6 Aqueous Acetone 8260D 5.0 JL ug/L 28 004 MW-6 Aqueous Barium 6020B 50 ug/L 30 004 MW-6 Aqueous Zinc 6020B 2.5 J ug/L 30 005 MW-7 Aqueous Acetone 8260D 5.1 JL ug/L 31 005 MW-7 Aqueous 1, 1 -Dichloroethane 8260D 0.42 J ug/L 31 005 MW-7 Aqueous Barium 6020B 170 ug/L 33 005 MW-7 Aqueous Cobalt 6020B 1.6 J ug/L 33 005 MW-7 Aqueous Nickel 6020B 11 ug/L 33 005 MW-7 Aqueous Zinc 6020B 2.5 J ug/L 33 006 MW-51D Aqueous Barium 6020B 68 ug/L 36 006 MW-51D Aqueous Nickel 6020B 3.7 J ug/L 36 007 MW-5 Aqueous Barium 6020B 120 ug/L 39 007 MW-5 Aqueous Chromium 6020B 2.5 J ug/L 39 007 MW-5 Aqueous Nickel 6020B 3.9 J ug/L 39 007 MW-5 Aqueous Vanadium 6020B 2.7 J ug/L 39 007 MW-5 Aqueous Zinc 6020B 6.2 J ug/L 39 008 MW-3R Aqueous Barium 6020B 70 ug/L 42 008 MW-3R Aqueous Chromium 6020B 2.6 J ug/L 42 008 MW-3R Aqueous Nickel 6020B 3.4 J ug/L 42 008 MW-3R Aqueous Vanadium 6020B 3.6 J ug/L 42 009 MW-17R Aqueous Alkalinity @ pH 4.5 su SM 2320B- 76 mg CaCO3/L 43 009 MW-17R Aqueous Chloride 9056A 2.8 mg/L 43 009 MW-17R Aqueous Sulfate 9056A 30 mg/L 43 009 MW-17R Aqueous TDS SM 2540C- 150 mg/L 43 009 MW-17R Aqueous Barium 6020B 61 ug/L 48 009 MW-17R Aqueous Copper 6020B 4.1 J ug/L 48 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 183 Detection Summary (Continued) Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 009 MW-17R Aqueous Iron 6020B 130 ug/L 48 009 MW-17R Aqueous Manganese 6020B 31 ug/L 48 009 MW-17R Aqueous Nickel 6020B 14 ug/L 48 009 MW-17R Aqueous Zinc 6020B 7.8 J ug/L 48 010 MW-13 Aqueous Barium 6020B 170 ug/L 51 010 MW-13 Aqueous Cobalt 6020B 24 ug/L 51 010 MW-13 Aqueous Nickel 6020B 5.8 ug/L 51 011 SW-4 Aqueous Acetone 8260D 8.1 J ug/L 53 011 SW-4 Aqueous Barium 6020B 120 ug/L 55 011 SW-4 Aqueous Chromium 6020B 6.7 ug/L 55 011 SW-4 Aqueous Cobalt 6020B 4.2 J ug/L 55 011 SW-4 Aqueous Copper 6020B 5.0 ug/L 55 011 SW-4 Aqueous Lead 6020B 1.6 ug/L 55 011 SW-4 Aqueous Nickel 6020B 7.8 ug/L 55 011 SW-4 Aqueous Vanadium 6020B 10 ug/L 55 011 SW-4 Aqueous Zinc 6020B 10 ug/L 55 012 SW-6 Aqueous Acetone 8260D 5.8 J ug/L 57 012 SW-6 Aqueous Barium 6020B 150 ug/L 59 012 SW-6 Aqueous Chromium 6020B 5.4 ug/L 59 012 SW-6 Aqueous Cobalt 6020B 5.1 ug/L 59 012 SW-6 Aqueous Copper 6020B 3.4 J ug/L 59 012 SW-6 Aqueous Lead 6020B 0.94 J ug/L 59 012 SW-6 Aqueous Nickel 6020B 9.5 ug/L 59 012 SW-6 Aqueous Vanadium 6020B 8.1 ug/L 59 012 SW-6 Aqueous Zinc 6020B 6.9 J ug/L 59 013 SW-2 Aqueous Barium 6020B 82 ug/L 63 013 SW-2 Aqueous Chromium 6020B 4.2 J ug/L 63 013 SW-2 Aqueous Cobalt 6020B 1.8 J ug/L 63 013 SW-2 Aqueous Copper 6020B 2.9 J ug/L 63 013 SW-2 Aqueous Lead 6020B 0.68 J ug/L 63 013 SW-2 Aqueous Nickel 6020B 4.0 J ug/L 63 013 SW-2 Aqueous Vanadium 6020B 6.7 ug/L 63 013 SW-2 Aqueous Zinc 6020B 5.0 J ug/L 63 014 SW-8 Aqueous Barium 6020B 51 ug/L 67 014 SW-8 Aqueous Chromium 6020B 1.4 J ug/L 67 014 SW-8 Aqueous Copper 6020B 3.0 J ug/L 67 014 SW-8 Aqueous Vanadium 6020B 2.9 J ug/L 67 015 SW-1 Aqueous Barium 6020B 110 ug/L 71 015 SW-1 Aqueous Cobalt 6020B 2.2 J ug/L 71 015 SW-1 Aqueous Lead 6020B 0.75 J ug/L 71 015 SW-1 Aqueous Vanadium 6020B 3.8 J ug/L 71 015 SW-1 Aqueous Zinc 6020B 2.7 J ug/L 71 016 SW-7 Aqueous 1,4-Dioxane 8260D (SIM) 1.0 J ug/L 72 016 SW-7 Aqueous Acetone 8260D 16 HJ ug/L 73 016 SW-7 Aqueous Barium 6020B 210 ug/L 75 016 SW-7 Aqueous Chromium 6020B 24 ug/L 75 016 SW-7 Aqueous Cobalt 6020B 39 ug/L 75 016 SW-7 Aqueous Copper 6020B 21 ug/L 75 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 183 Detection Summary (Continued) Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 016 SW-7 Aqueous Nickel 6020B 55 ug/L 75 016 SW-7 Aqueous Zinc 6020B 13 J ug/L 75 017 MW-14D Aqueous Alkalinity @ pH 4.5 su SM 232013- 150 mg CaCO3/1- 76 017 MW-14D Aqueous Chloride 9056A 4.1 mg/L 76 017 MW-14D Aqueous Sulfate 9056A 30 mg/L 76 017 MW-14D Aqueous TDS SM 2540C- 130 mg/L 76 017 MW-14D Aqueous Barium 6020B 6.9 ug/L 80 017 MW-14D Aqueous Chromium 6020B 1.4 J ug/L 80 017 MW-14D Aqueous Iron 6020B 130 ug/L 80 017 MW-14D Aqueous Manganese 6020B 11 ug/L 80 017 MW-14D Aqueous Zinc 6020B 2.7 J ug/L 80 018 MW-14 Aqueous Alkalinity @ pH 4.5 su SM 232013- 71 mg CaCO3/1- 81 018 MW-14 Aqueous Chloride 9056A 2.5 mg/L 81 018 MW-14 Aqueous Sulfate 9056A 19 mg/L 81 018 MW-14 Aqueous TDS SM 2540C- 97 mg/L 81 018 MW-14 Aqueous Barium 6020B 51 ug/L 85 018 MW-14 Aqueous Chromium 6020B 1.3 J ug/L 85 018 MW-14 Aqueous Iron 6020B 540 ug/L 85 018 MW-14 Aqueous Manganese 6020B 7.7 ug/L 85 018 MW-14 Aqueous Nickel 6020B 2.6 J ug/L 85 018 MW-14 Aqueous Vanadium 6020B 3.4 J ug/L 85 019 MW-81D Aqueous Barium 6020B 170 ug/L 88 019 MW-81D Aqueous Nickel 6020B 4.1 J ug/L 88 020 MW-8 Aqueous Antimony 6020B 0.68 J ug/L 91 020 MW-8 Aqueous Barium 6020B 150 ug/L 91 020 MW-8 Aqueous Chromium 6020B 4.8 J ug/L 91 020 MW-8 Aqueous Nickel 6020B 4.8 J ug/L 91 020 MW-8 Aqueous Zinc 6020B 7.0 J ug/L 91 021 MW-21D Aqueous Barium 6020B 110 ug/L 94 021 MW-21D Aqueous Vanadium 6020B 2.5 J ug/L 94 021 MW-21D Aqueous Zinc 6020B 2.9 J ug/L 94 022 MW-2 Aqueous Barium 6020B 140 ug/L 97 022 MW-2 Aqueous Cadmium 6020B 0.31 J ug/L 97 022 MW-2 Aqueous Chromium 6020B 2.4 J ug/L 97 022 MW-2 Aqueous Cobalt 6020B 5.0 ug/L 97 022 MW-2 Aqueous Copper 6020B 1.5 J ug/L 97 022 MW-2 Aqueous Nickel 6020B 14 ug/L 97 022 MW-2 Aqueous Vanadium 6020B 3.2 J ug/L 97 022 MW-2 Aqueous Zinc 6020B 6.2 J ug/L 97 023 MW-41D Aqueous Barium 6020B 36 ug/L 101 023 MW-41D Aqueous Vanadium 6020B 3.5 J ug/L 101 024 MW-4 Aqueous 1,4-Dioxane 8260D (SIM) 1.1 J ug/L 102 024 MW-4 Aqueous Acetone 8260D 6.0 JL ug/L 103 024 MW-4 Aqueous Barium 6020B 97 ug/L 105 024 MW-4 Aqueous Chromium 6020B 1.7 J ug/L 105 024 MW-4 Aqueous Copper 6020B 1.5 J ug/L 105 024 MW-4 Aqueous Nickel 6020B 5.0 ug/L 105 025 SW-3 Aqueous 1,4-Dioxane 8260D (SIM) 26 ug/L 106 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 183 Detection Summary (Continued) Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 025 SW-3 Aqueous Acetone 8260D 19 J ug/L 107 025 SW-3 Aqueous Barium 6020B 280 ug/L 109 025 SW-3 Aqueous Chromium 6020B 11 ug/L 109 025 SW-3 Aqueous Cobalt 6020B 12 ug/L 109 025 SW-3 Aqueous Copper 6020B 6.2 ug/L 109 025 SW-3 Aqueous Lead 6020B 1.9 ug/L 109 025 SW-3 Aqueous Nickel 6020B 31 ug/L 109 025 SW-3 Aqueous Vanadium 6020B 12 ug/L 109 025 SW-3 Aqueous Zinc 6020B 19 ug/L 109 026 MW-11 Aqueous Barium 6020B 120 ug/L 112 026 MW-11 Aqueous Cobalt 6020B 6.9 ug/L 112 026 MW-11 Aqueous Copper 6020B 2.5 J ug/L 112 026 MW-11 Aqueous Lead 6020B 1.9 ug/L 112 026 MW-11 Aqueous Nickel 6020B 28 ug/L 112 026 MW-11 Aqueous Zinc 6020B 11 ug/L 112 027 MW-11D Aqueous Barium 6020B 45 ug/L 115 027 MW-11D Aqueous Copper 6020B 1.8 J ug/L 115 027 MW-11D Aqueous Nickel 6020B 4.6 J ug/L 115 027 MW-11D Aqueous Zinc 6020B 11 ug/L 115 028 MW-1 D Aqueous Alkalinity @ pH 4.5 su SM 232013- 93 mg CaCO3/1- 116 028 MW-1D Aqueous Chloride 9056A 2.5 mg/L 116 028 MW-1D Aqueous Sulfate 9056A 39 mg/L 116 028 MW-1D Aqueous TDS SM 2540C- 180 mg/L 116 028 MW-1D Aqueous Antimony 6020B 0.55 J ug/L 120 028 MW-1D Aqueous Barium 6020B 34 ug/L 120 028 MW-1D Aqueous Iron 6020B 150 ug/L 120 028 MW-1D Aqueous Manganese 6020B 18 ug/L 120 028 MW-1D Aqueous Nickel 6020B 3.0 J ug/L 120 028 MW-1D Aqueous Zinc 6020B 2.7 J ug/L 120 029 MW-1 Aqueous Alkalinity @ pH 4.5 su SM 232013- 62 mg CaCO3/1- 121 029 MW-1 Aqueous Chloride 9056A 6.3 mg/L 121 029 MW-1 Aqueous Sulfate 9056A 18 mg/L 121 029 MW-1 Aqueous TDS SM 2540C- 130 mg/L 121 029 MW-1 Aqueous Acetone 8260D 7.1 JL ug/L 122 029 MW-1 Aqueous Barium 6020B 150 ug/L 125 029 MW-1 Aqueous Chromium 6020B 5.4 ug/L 125 029 MW-1 Aqueous Cobalt 6020B 1.3 J ug/L 125 029 MW-1 Aqueous Copper 6020B 4.7 J ug/L 125 029 MW-1 Aqueous Iron 6020B 1700 ug/L 125 029 MW-1 Aqueous Manganese 6020B 24 ug/L 125 029 MW-1 Aqueous Nickel 6020B 3.9 J ug/L 125 029 MW-1 Aqueous Vanadium 6020B 6.7 ug/L 125 029 MW-1 Aqueous Zinc 6020B 9.1 J ug/L 125 030 MW-17DR Aqueous Alkalinity @ pH 4.5 su SM 232013- 130 mg CaCO3/1- 126 030 MW-17DR Aqueous Chloride 9056A 4.1 mg/L 126 030 MW-17DR Aqueous Sulfate 9056A 23 mg/L 126 030 MW-17DR Aqueous TDS SM 2540C- 77 mg/L 126 030 MW-17DR Aqueous Barium 6020B 73 ug/L 131 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 183 Detection Summary (Continued) Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 030 MW-17DR Aqueous Copper 6020B 1.8 J ug/L 131 030 MW-17DR Aqueous Iron 6020B 280 ug/L 131 030 MW-17DR Aqueous Manganese 6020B 66 ug/L 131 031 SW-5 Aqueous 1,4-Dioxane 8260D (SIM) 6.1 ug/L 132 031 SW-5 Aqueous Acetone 8260D 16 J ug/L 133 031 SW-5 Aqueous Tetrahydrofuran 8260D 2.0 J ug/L 133 031 SW-5 Aqueous Barium 6020B 160 ug/L 135 031 SW-5 Aqueous Chromium 6020B 5.7 ug/L 135 031 SW-5 Aqueous Cobalt 6020B 11 ug/L 135 031 SW-5 Aqueous Copper 6020B 1.4 J ug/L 135 031 SW-5 Aqueous Nickel 6020B 13 ug/L 135 031 SW-5 Aqueous Vanadium 6020B 2.8 J ug/L 135 032 MW-12 Aqueous Alkalinity @ pH 4.5 su SM 232013- 300 mg CaCO3/- 136 032 MW-12 Aqueous Chloride 9056A 33 mg/L 136 032 MW-12 Aqueous Sulfate 9056A 280 B mg/L 136 032 MW-12 Aqueous TDS SM 2540C- 770 mg/L 136 032 MW-12 Aqueous 1,4-Dioxane 8260D (SIM) 2.1 J ug/L 137 032 MW-12 Aqueous Acetone 8260D 11 J ug/L 138 032 MW-12 Aqueous Tetrahydrofuran 8260D 2.1 J ug/L 138 032 MW-12 Aqueous Barium 6020B 67 ug/L 141 032 MW-12 Aqueous Chromium 6020B 3.3 J ug/L 141 032 MW-12 Aqueous Cobalt 6020B 43 ug/L 141 032 MW-12 Aqueous Copper 6020B 3.7 J ug/L 141 032 MW-12 Aqueous Iron 6020B 170 ug/L 141 032 MW-12 Aqueous Manganese 6020B 3500 ug/L 141 032 MW-12 Aqueous Nickel 6020B 35 ug/L 141 032 MW-12 Aqueous Zinc 6020B 3.5 J ug/L 141 033 MW-12D Aqueous Alkalinity @ pH 4.5 su SM 232013- 200 mg CaCO3/- 142 033 MW-12D Aqueous Chloride 9056A 20 mg/L 142 033 MW-12D Aqueous Sulfate 9056A 140 mg/L 142 033 MW-12D Aqueous TDS SM 2540C- 470 mg/L 142 033 MW-12D Aqueous 1,4-Dioxane 8260D (SIM) 1.6 J ug/L 143 033 MW-12D Aqueous Tetrahydrofuran 8260D 1.0 J ug/L 144 033 MW-12D Aqueous Barium 6020B 90 ug/L 147 033 MW-12D Aqueous Chromium 6020B 1.3 J ug/L 147 033 MW-12D Aqueous Cobalt 6020B 4.3 J ug/L 147 033 MW-12D Aqueous Iron 6020B 180 ug/L 147 033 MW-12D Aqueous Manganese 6020B 510 ug/L 147 033 MW-12D Aqueous Nickel 6020B 8.0 ug/L 147 034 LD-5 Aqueous Barium 6020B 57 ug/L 150 034 LD-5 Aqueous Cobalt 6020B 22 ug/L 150 034 LD-5 Aqueous Nickel 6020B 10 ug/L 150 035 Leachate Pond Aqueous BOD, 5 day SM 521013- 71 mg/L 151 035 Leachate Pond Aqueous COD SM 5220D- 770 mg/L 151 035 Leachate Pond Aqueous Phosphorus 365.1 2.5 mg/L 151 035 Leachate Pond Aqueous Sulfate 9056A 21 mg/L 151 035 Leachate Pond Aqueous Acetone 8260D 36 ug/L 152 035 Leachate Pond Aqueous Benzene 8260D 0.46 J ug/L 152 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 183 Detection Summary (Continued) Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 035 Leachate Pond Aqueous Carbon disulfide 8260D 0.51 J ug/L 152 035 Leachate Pond Aqueous 1,4-Dichlorobenzene 8260D 0.85 J ug/L 152 035 Leachate Pond Aqueous Ethylbenzene 8260D 0.68 J ug/L 152 035 Leachate Pond Aqueous 4-Methyl-2-pentanone 8260D 2.2 J ug/L 152 035 Leachate Pond Aqueous Toluene 8260D 0.83 J ug/L 152 035 Leachate Pond Aqueous Xylenes (total) 8260D 2.1 ug/L 153 035 Leachate Pond Aqueous Antimony 6020B 12 J ug/L 154 035 Leachate Pond Aqueous Arsenic 6020B 32 ug/L 154 035 Leachate Pond Aqueous Barium 6020B 470 ug/L 154 035 Leachate Pond Aqueous Chromium 6020B 86 ug/L 154 035 Leachate Pond Aqueous Cobalt 6020B 21 J ug/L 154 035 Leachate Pond Aqueous Nickel 6020B 82 ug/L 154 035 Leachate Pond Aqueous Vanadium 6020B 39 J ug/L 154 036 Leachate LID Aqueous Arsenic 6020B 2.2 ug/L 157 036 Leachate LID Aqueous Barium 6020B 30 ug/L 157 036 Leachate LID Aqueous Beryllium 6020B 0.37 J ug/L 157 036 Leachate LID Aqueous Cadmium 6020B 0.16 J ug/L 157 036 Leachate LID Aqueous Cobalt 6020B 38 ug/L 157 036 Leachate LID Aqueous Copper 6020B 11 ug/L 157 036 Leachate LID Aqueous Nickel 6020B 270 ug/L 157 036 Leachate LID Aqueous Selenium 6020B 2.5 J ug/L 157 036 Leachate LID Aqueous Zinc 6020B 140 ug/L 157 037 LD-2 Aqueous Benzene 8260D 0.71 J ug/L 158 037 LD-2 Aqueous Chloroethane 8260D 0.44 J ug/L 158 037 LD-2 Aqueous 1,1-Dichloroethane 8260D 1.3 ug/L 158 037 LD-2 Aqueous cis-1,2-Dichloroethene 8260D 0.71 J ug/L 158 037 LD-2 Aqueous Barium 6020B 180 ug/L 160 037 LD-2 Aqueous Cobalt 6020B 59 ug/L 160 037 LD-2 Aqueous Copper 6020B 2.0 J ug/L 160 037 LD-2 Aqueous Nickel 6020B 11 ug/L 160 037 LD-2 Aqueous Zinc 6020B 8.7 J ug/L 160 038 LID-1 Aqueous Acetone 8260D 8.3 JL ug/L 161 038 LD-1 Aqueous Benzene 8260D 1.8 ug/L 161 038 LID-1 Aqueous Chloroethane 8260D 0.65 J ug/L 161 038 LID-1 Aqueous 1,1-Dichloroethane 8260D 0.43 J ug/L 161 038 LID-1 Aqueous Arsenic 6020B 1.3 J ug/L 163 038 LD-1 Aqueous Barium 6020B 1700 ug/L 163 038 LID-1 Aqueous Chromium 6020B 2.5 J ug/L 163 038 LID-1 Aqueous Cobalt 6020B 260 ug/L 163 038 LID-1 Aqueous Nickel 6020B 74 ug/L 163 038 LID-1 Aqueous Selenium 6020B 2.3 J ug/L 163 038 LID-1 Aqueous Zinc 6020B 2.8 J ug/L 163 039 LD-3 Aqueous Barium 6020B 230 ug/L 166 039 LD-3 Aqueous Cobalt 6020B 4.6 J ug/L 166 039 LD-3 Aqueous Nickel 6020B 2.0 J ug/L 166 040 LD-4 Aqueous Acetone 8260D 10 JL ug/L 167 040 LD-4 Aqueous Benzene 8260D 2.3 ug/L 167 040 LD-4 Aqueous Toluene 8260D 0.45 J ug/L 167 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 183 Detection Summary (Continued) Lot Number: XD27064 Sample Sample ID Matrix Parameter Method Result Q Units Page 040 LID-4 Aqueous Vinyl chloride 8260D 0.86 J ug/L 168 040 LID-4 Aqueous Xylenes (total) 8260D 0.50 J ug/L 168 040 LID-4 Aqueous Antimony 6020B 3.2 J ug/L 169 040 LID-4 Aqueous Arsenic 6020B 4.2 ug/L 169 040 LID-4 Aqueous Barium 6020B 490 ug/L 169 040 LID-4 Aqueous Cadmium 6020B 0.34 J ug/L 169 040 LID-4 Aqueous Chromium 6020B 400 ug/L 169 040 LID-4 Aqueous Cobalt 6020B 80 ug/L 169 040 LID-4 Aqueous Copper 6020B 140 ug/L 169 040 LID-4 Aqueous Lead 6020B 1.5 J ug/L 169 040 LID-4 Aqueous Nickel 6020B 220 ug/L 169 040 LID-4 Aqueous Vanadium 6020B 17 ug/L 169 040 LID-4 Aqueous Zinc 6020B 40 ug/L 169 041 LID-6 Aqueous Carbon disulfide 8260D 0.42 J ug/L 170 041 LID-6 Aqueous Barium 6020B 380 ug/L 172 041 LID-6 Aqueous Cobalt 6020B 64 ug/L 172 041 LID-6 Aqueous Nickel 6020B 2.7 J ug/L 172 042 MW-18 Aqueous Alkalinity @ pH 4.5 su SM 232013- 83 mg CaCO3/1- 173 042 MW-18 Aqueous Chloride 9056A 1.7 mg/L 173 042 MW-18 Aqueous Sulfate 9056A 32 mg/L 173 042 MW-18 Aqueous TDS SM 2540C- 150 mg/L 173 042 MW-18 Aqueous Barium 6020B 14 ug/L 178 042 MW-18 Aqueous Chromium 6020B 1.6 J ug/L 178 042 MW-18 Aqueous Copper 6020B 1.5 J ug/L 178 042 MW-18 Aqueous Iron 6020B 260 ug/L 178 042 MW-18 Aqueous Manganese 6020B 47 ug/L 178 042 MW-18 Aqueous Nickel 6020B 1.8 J ug/L 178 042 MW-18 Aqueous Selenium 6020B 1.3 J ug/L 178 042 MW-18 Aqueous Zinc 6020B 4.2 J ug/L 178 (314 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-001 Description: MW-13D Matrix: Aqueous Date Sampled:04/26/2022 0955 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0050 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-001 Description: MW-13D Matrix: Aqueous Date Sampled:04/26/2022 0955 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0050 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 111 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 115 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-001 Description: MW-13D Matrix: Aqueous Date Sampled:04/26/2022 0955 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1500 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 83 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-002 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2022 1015 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1437 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-002 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2022 1015 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0113 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.81 J 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.65 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-002 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2022 1015 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0113 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 111 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 116 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-002 Description: MW-10D Matrix: Aqueous Date Sampled:04/26/2022 1015 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1504 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.9 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.40 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.5 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 33 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-003 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2022 1040 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1501 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-003 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2022 1040 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0136 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-003 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2022 1040 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0136 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 110 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 114 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-003 Description: MW-10 Matrix: Aqueous Date Sampled:04/26/2022 1040 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1507 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.8 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 27 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 6.6 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 13 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-004 Description: MW-6 Matrix: Aqueous Date Sampled:04/26/2022 1240 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0159 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.0 JL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-004 Description: MW-6 Matrix: Aqueous Date Sampled:04/26/2022 1240 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0159 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 110 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 115 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-004 Description: MW-6 Matrix: Aqueous Date Sampled:04/26/2022 1240 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1511 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 50 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-005 Description: MW-7 Matrix: Aqueous Date Sampled:04/26/2022 1345 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0221 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.1 JL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.42 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-005 Description: MW-7 Matrix: Aqueous Date Sampled:04/26/2022 1345 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0221 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 113 70-130 1,2-Dichloroethane-d4 116 70-130 Toluene-d8 118 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-005 Description: MW-7 Matrix: Aqueous Date Sampled:04/26/2022 1345 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1514 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.6 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-006 Description: MW-5D Matrix: Aqueous Date Sampled:04/26/2022 1450 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0244 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-006 Description: MW-5D Matrix: Aqueous Date Sampled:04/26/2022 1450 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0244 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 111 70-130 1,2-Dichloroethane-d4 114 70-130 Toluene-d8 116 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-006 Description: MW-5D Matrix: Aqueous Date Sampled:04/26/2022 1450 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1518 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 68 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-007 Description: MW-5 Matrix: Aqueous Date Sampled:04/26/2022 1600 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0307 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-007 Description: MW-5 Matrix: Aqueous Date Sampled:04/26/2022 1600 Date Received:04/27/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/2022 0307 BWS 40827 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 115 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-007 Description: MW-5 Matrix: Aqueous Date Sampled:04/26/2022 1600 Date Received:04/27/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 04/29/2022 1521 BPK Prep Date Batch 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.9 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.7 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-008 Description: MW-3R Matrix: Aqueous Date Sampled:04/28/2022 0955 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0203 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-008 Description: MW-3R Matrix: Aqueous Date Sampled:04/28/2022 0955 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0203 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 77 70-130 1,2-Dichloroethane-d4 122 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-008 Description: MW-3R Matrix: Aqueous Date Sampled:04/28/2022 0955 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1221 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 70 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.4 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.6 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-009 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2022 1050 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1718 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 1824 CAW 42838 1 (Sulfate) 9056A 1 05/24/2022 1824 CAW 42840 1 (TDS) SM 2540C-2011 1 05/04/2022 1823 CVR 40419 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 76 20 20 mg CaCO3/L 1 9056A 2.8 1.0 0.25 mg/L 1 9056A 30 1.0 0.25 mg/L 1 SM 254OC-2011 150 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-009 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2022 1050 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1314 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-009 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2022 1050 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221846 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-009 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2022 1050 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221846 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 109 70-130 96 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-009 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2022 1050 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0723 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-009 Description: MW-17R Matrix: Aqueous Date Sampled:04/28/2022 1050 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1239 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 61 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.1 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 130 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 31 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 14 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-010 Description: MW-13 Matrix: Aqueous Date Sampled:04/28/2022 1110 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221911 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-010 Description: MW-13 Matrix: Aqueous Date Sampled:04/28/2022 1110 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221911 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 111 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-010 Description: MW-13 Matrix: Aqueous Date Sampled:04/28/2022 1110 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1249 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 24 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.8 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-011 Description: SW-4 Matrix: Aqueous Date Sampled:04/28/2022 0935 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1339 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-011 Description: SW-4 Matrix: Aqueous Date Sampled:04/28/2022 0935 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221936 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 8.1 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-011 Description: SW-4 Matrix: Aqueous Date Sampled:04/28/2022 0935 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221936 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 111 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-011 Description: SW-4 Matrix: Aqueous Date Sampled:04/28/2022 0935 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1253 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 6.7 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.2 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.6 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 7.8 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 10 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-012 Description: SW-6 Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1403 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-012 Description: SW-6 Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2001 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.8 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-012 Description: SW-6 Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2001 JWO 41252 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 93 70-130 112 70-130 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-012 Description: SW-6 Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1256 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.4 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.1 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.94 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.5 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 8.1 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-013 Description: SW-2 Matrix: Aqueous Date Sampled:04/28/2022 1025 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1428 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-013 Description: SW-2 Matrix: Aqueous Date Sampled:04/28/2022 1025 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221545 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-013 Description: SW-2 Matrix: Aqueous Date Sampled:04/28/2022 1025 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221545 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 125 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-013 Description: SW-2 Matrix: Aqueous Date Sampled:04/28/2022 1025 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1300 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 82 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.2 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.8 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.9 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.68 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 6.7 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 5.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-014 Description: SW-8 Matrix: Aqueous Date Sampled:04/28/2022 1045 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1452 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 105 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-014 Description: SW-8 Matrix: Aqueous Date Sampled:04/28/2022 1045 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221610 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-014 Description: SW-8 Matrix: Aqueous Date Sampled:04/28/2022 1045 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221610 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 87 70-130 126 70-130 96 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-014 Description: SW-8 Matrix: Aqueous Date Sampled:04/28/2022 1045 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1303 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 51 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.0 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.9 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-015 Description: SW-1 Matrix: Aqueous Date Sampled:04/28/2022 1115 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1517 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-015 Description: SWA Matrix: Aqueous Date Sampled:04/28/2022 1115 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221636 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-015 Description: SWA Matrix: Aqueous Date Sampled:04/28/2022 1115 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221636 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 82 70-130 1,2-Dichloroethane-d4 126 70-130 Toluene-d8 96 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-015 Description: SWA Matrix: Aqueous Date Sampled:04/28/2022 1115 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1307 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.2 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.75 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.8 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-016 Description: SW-7 Matrix: Aqueous Date Sampled:04/28/2022 1140 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 2259 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.0 J 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-016 Description: SW-7 Matrix: Aqueous Date Sampled:04/28/2022 1140 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D 1 05/20/20221737 ECB 42503 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 16 HJ 20 5.0 ug/L 2 Acrylonitrile 107-13-1 8260D ND H 20 0.80 ug/L 2 Benzene 71-43-2 8260D ND H 1.0 0.40 ug/L 2 Bromochloromethane 74-97-5 8260D ND H 1.0 0.40 ug/L 2 Bromodichloromethane 75-27-4 8260D ND H 1.0 0.40 ug/L 2 Bromoform 75-25-2 8260D ND H 1.0 0.40 ug/L 2 Bromomethane (Methyl bromide) 74-83-9 8260D ND H 2.0 0.40 ug/L 2 2-Butanone (MEK) 78-93-3 8260D ND H 10 2.0 ug/L 2 Carbon disulfide 75-15-0 8260D ND H 1.0 0.40 ug/L 2 Carbon tetrachloride 56-23-5 8260D ND H 1.0 0.40 ug/L 2 Chlorobenzene 108-90-7 8260D ND H 1.0 0.40 ug/L 2 Chloroethane 75-00-3 8260D ND H 2.0 0.40 ug/L 2 Chloroform 67-66-3 8260D ND H 1.0 0.40 ug/L 2 Chloromethane (Methyl chloride) 74-87-3 8260D ND H 1.0 0.50 ug/L 2 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND H 1.0 0.40 ug/L 2 Dibromochloromethane 124-48-1 8260D ND H 1.0 0.40 ug/L 2 1,2-Dibromoethane (EDB) 106-93-4 8260D ND H 1.0 0.40 ug/L 2 Dibromomethane (Methylene bromide) 74-95-3 8260D ND H 1.0 0.40 ug/L 2 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND H 2.0 0.50 ug/L 2 1,2-Dichlorobenzene 95-50-1 8260D ND H 1.0 0.40 ug/L 2 1,4-Dichlorobenzene 106-46-7 8260D ND H 1.0 0.40 ug/L 2 1,1-Dichloroethane 75-34-3 8260D ND H 1.0 0.40 ug/L 2 1,2-Dichloroethane 107-06-2 8260D ND H 1.0 0.40 ug/L 2 1,1-Dichloroethene 75-35-4 8260D ND H 1.0 0.40 ug/L 2 cis- 1,2-Dichloroethene 156-59-2 8260D ND H 1.0 0.40 ug/L 2 trans- 1,2-Dichloroethene 156-60-5 8260D ND H 1.0 0.40 ug/L 2 1,2-Dichloropropane 78-87-5 8260D ND H 1.0 0.40 ug/L 2 cis- 1,3-Dichloropropene 10061-01-5 8260D ND H 1.0 0.40 ug/L 2 trans- 1,3-Dichloropropene 10061-02-6 8260D ND H 1.0 0.40 ug/L 2 Ethylbenzene 100-41-4 8260D ND H 1.0 0.40 ug/L 2 2-Hexanone 591-78-6 8260D ND H 10 2.0 ug/L 2 Methyl iodide (lodomethane) 74-88-4 8260D ND H 5.0 0.40 ug/L 2 4-Methyl-2-pentanone 108-10-1 8260D ND H 10 2.0 ug/L 2 Methylene chloride 75-09-2 8260D ND H 1.0 0.40 ug/L 2 Styrene 100-42-5 8260D ND H 1.0 0.41 ug/L 2 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND H 1.0 0.40 ug/L 2 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND H 1.0 0.40 ug/L 2 Tetrachloroethene 127-18-4 8260D ND H 1.0 0.40 ug/L 2 Toluene 108-88-3 8260D ND H 1.0 0.40 ug/L 2 1,1,1-Trichloroethane 71-55-6 8260D ND H 1.0 0.40 ug/L 2 1,1,2-Trichloroethane 79-00-5 8260D ND H 1.0 0.40 ug/L 2 Trichloroethene 79-01-6 8260D ND H 1.0 0.40 ug/L 2 Trichlorofluoromethane 75-69-4 8260D ND H 1.0 0.40 ug/L 2 1,2,3-Trichloropropane 96-18-4 8260D ND H 1.0 0.40 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-016 Description: SW-7 Matrix: Aqueous Date Sampled:04/28/2022 1140 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D 1 05/20/20221737 ECB 42503 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND H 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND H 1.0 0.40 ug/L 2 Xylenes (total) 1330-20-7 8260D ND H 1.0 0.40 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 H 105 70-130 H 105 70-130 H 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-016 Description: SW-7 Matrix: Aqueous Date Sampled:04/28/2022 1140 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1310 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 4.0 1.0 ug/L 1 Arsenic 7440-38-2 6020B ND 4.0 2.5 ug/L 1 Barium 7440-39-3 6020B 210 10 2.5 ug/L 1 Beryllium 7440-41-7 6020B ND 0.80 0.30 ug/L 1 Cadmium 7440-43-9 6020B ND 1.0 0.25 ug/L 1 Chromium 7440-47-3 6020B 24 10 2.5 ug/L 1 Cobalt 7440-48-4 6020B 39 10 2.5 ug/L 1 Copper 7440-50-8 6020B 21 10 2.5 ug/L 1 Lead 7439-92-1 6020B ND 2.0 0.50 ug/L 1 Nickel 7440-02-0 6020B 55 10 2.5 ug/L 1 Selenium 7782-49-2 6020B ND 10 2.5 ug/L 1 Silver 7440-22-4 6020B ND 2.0 0.50 ug/L 1 Thallium 7440-28-0 6020B ND 1.0 0.30 ug/L 1 Vanadium 7440-62-2 6020B ND 10 5.0 ug/L 1 Zinc 7440-66-6 6020B 13 J 20 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-017 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2022 1100 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1725 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 1843 CAW 42838 1 (Sulfate) 9056A 1 05/24/2022 1843 CAW 42840 1 (TDS) SM 2540C-2011 1 05/04/2022 1823 CVR 40419 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 150 20 20 mg CaCO3/L 1 Chloride 9056A 4.1 1.0 0.25 mg/L 1 Sulfate 9056A 30 1.0 0.25 mg/L 1 TDS SM 2540C-2011 130 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-017 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2022 1100 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221701 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND QL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND Q 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND Q 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND Q 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND Q 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND Q 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND Q 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND QL 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND Q 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND Q 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND Q 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND Q 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND Q 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND Q 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND Q 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND Q 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND Q 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND Q 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND Q 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND Q 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND Q 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND Q 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND Q 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND Q 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND Q 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND Q 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND Q 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND Q 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND Q 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND Q 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND QL 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND Q 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND Q 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND Q 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND Q 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND Q 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND Q 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND Q 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND Q 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND Q 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND Q 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND Q 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND Q 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND Q 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-017 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2022 1100 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221701 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND Q 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND Q 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND Q 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND Q 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 85 70-130 N 137 70-130 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-017 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2022 1100 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0726 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-017 Description: MW-14D Matrix: Aqueous Date Sampled:04/28/2022 1100 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1314 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 6.9 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 130 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 11 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-018 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2022 1135 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1731 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 1902 CAW 42838 1 (Sulfate) 9056A 1 05/24/2022 1902 CAW 42840 1 (TDS) SM 2540C-2011 1 05/04/2022 1823 CVR 40419 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 71 20 20 mg CaCO3/L 1 9056A 2.5 1.0 0.25 mg/L 1 9056A 19 1.0 0.25 mg/L 1 SM 254OC-2011 97 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-018 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2022 1135 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221727 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-018 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2022 1135 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221727 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 83 70-130 126 70-130 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-018 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2022 1135 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0734 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-018 Description: MW-14 Matrix: Aqueous Date Sampled:04/28/2022 1135 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1317 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 51 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 540 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 7.7 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 2.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.4 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-019 Description: MW-8D Matrix: Aqueous Date Sampled:04/28/2022 1011 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221752 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-019 Description: MW-8D Matrix: Aqueous Date Sampled:04/28/2022 1011 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221752 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 129 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-019 Description: MW-8D Matrix: Aqueous Date Sampled:04/28/2022 1011 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1321 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.1 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-020 Description: MW-8 Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221817 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-020 Description: MW-8 Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221817 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 86 70-130 1,2-Dichloroethane-d4 128 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-020 Description: MW-8 Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1331 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.68 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.8 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.0 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-021 Description: MW-2D Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221842 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-021 Description: MW-2D Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221842 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 124 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-021 Description: MW-2D Matrix: Aqueous Date Sampled:04/28/2022 1000 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1335 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.5 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-022 Description: MW-2 Matrix: Aqueous Date Sampled:04/28/2022 1110 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221908 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-022 Description: MW-2 Matrix: Aqueous Date Sampled:04/28/2022 1110 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221908 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 125 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-022 Description: MW-2 Matrix: Aqueous Date Sampled:04/28/2022 1110 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1338 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 140 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.31 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 14 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.2 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-023 Description: MW-4D Matrix: Aqueous Date Sampled:04/28/2022 1230 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1541 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-023 Description: MW-4D Matrix: Aqueous Date Sampled:04/28/2022 1230 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221519 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-023 Description: MW-4D Matrix: Aqueous Date Sampled:04/28/2022 1230 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/20221519 JWO 41247 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 85 70-130 1,2-Dichloroethane-d4 124 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-023 Description: MW-4D Matrix: Aqueous Date Sampled:04/28/2022 1230 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1342 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 36 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.5 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2022 1305 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1606 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.1 J 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2022 1305 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221845 BWS 41457 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 6.0 JL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2022 1305 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221845 BWS 41457 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 112 70-130 Toluene-d8 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/28/2022 1305 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1345 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 97 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.7 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-025 Description: SW-3 Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1630 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 26 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-025 Description: SW-3 Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221247 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 19 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 102 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-025 Description: SW-3 Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221247 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 85 70-130 1,2-Dichloroethane-d4 115 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 103 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-025 Description: SW-3 Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1349 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 280 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 11 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 12 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 6.2 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.9 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 31 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 12 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 19 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 104 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-026 Description: MW-11 Matrix: Aqueous Date Sampled:04/28/2022 1312 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2329 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 105 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-026 Description: MW-11 Matrix: Aqueous Date Sampled:04/28/2022 1312 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2329 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 106 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-026 Description: MW-11 Matrix: Aqueous Date Sampled:04/28/2022 1312 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1352 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 6.9 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.9 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 28 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 11 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 107 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-027 Description: MW-11D Matrix: Aqueous Date Sampled:04/28/2022 1330 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2352 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 108 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-027 Description: MW-11D Matrix: Aqueous Date Sampled:04/28/2022 1330 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2352 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 89 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-027 Description: MW-11D Matrix: Aqueous Date Sampled:04/28/2022 1330 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1356 BNW Prep Date Batch 04/30/2022 1038 39929 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 45 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.8 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 11 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 110 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-028 Description: MW-1D Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1738 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 2018 CAW 42839 1 (Sulfate) 9056A 1 05/24/2022 2018 CAW 42841 1 (TDS) SM 2540C-2011 1 05/05/2022 1225 CAM 40509 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 93 20 20 mg CaCO3/L 1 9056A 2.5 1.0 0.25 mg/L 1 9056A 39 1.0 0.25 mg/L 1 SM 254OC-2011 180 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 111 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-028 Description: MW-1D Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0015 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 112 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-028 Description: MW-1D Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0015 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 99 70-130 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 113 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-028 Description: MW-1D Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0737 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 114 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-028 Description: MW-1D Matrix: Aqueous Date Sampled:04/28/2022 1400 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1030 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.55 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 34 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 150 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 18 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 3.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 115 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-029 Description: MW-1 Matrix: Aqueous Date Sampled:04/28/2022 1440 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1744 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 2037 CAW 42839 1 (Sulfate) 9056A 1 05/24/2022 2037 CAW 42841 1 (TDS) SM 2540C-2011 1 05/05/2022 1225 CAM 40509 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 62 20 20 mg CaCO3/L 1 9056A 6.3 1.0 0.25 mg/L 1 9056A 18 1.0 0.25 mg/L 1 SM 254OC-2011 130 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 116 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-029 Description: MW-1 Matrix: Aqueous Date Sampled:04/28/2022 1440 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0038 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 7.1 JL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 117 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-029 Description: MW-1 Matrix: Aqueous Date Sampled:04/28/2022 1440 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0038 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 101 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 118 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-029 Description: MW-1 Matrix: Aqueous Date Sampled:04/28/2022 1440 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0739 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 119 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-029 Description: MW-1 Matrix: Aqueous Date Sampled:04/28/2022 1440 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1033 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.4 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.7 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 1700 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 24 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 3.9 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 6.7 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 9.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 120 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-030 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1751 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 2056 CAW 42839 1 (Sulfate) 9056A 1 05/24/2022 2056 CAW 42841 1 (TDS) SM 2540C-2011 1 05/04/2022 1823 CVR 40419 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 130 20 20 mg CaCO3/L 1 Chloride 9056A 4.1 1.0 0.25 mg/L 1 Sulfate 9056A 23 1.0 0.25 mg/L 1 TDS SM 254OC-2011 77 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 121 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-030 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1654 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 122 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-030 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221312 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 123 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-030 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221312 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 88 70-130 116 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 124 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-030 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0742 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 125 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-030 Description: MW-17DR Matrix: Aqueous Date Sampled:04/28/2022 1200 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1058 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 73 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.8 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 280 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 66 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 126 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-031 Description: SW-5 Matrix: Aqueous Date Sampled:04/28/2022 1345 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 05/11/2022 0210 BBW 41173 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.1 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 127 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-031 Description: SW-5 Matrix: Aqueous Date Sampled:04/28/2022 1345 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221337 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 16 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 2.0 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 128 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-031 Description: SW-5 Matrix: Aqueous Date Sampled:04/28/2022 1345 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221337 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 87 70-130 119 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 129 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-031 Description: SW-5 Matrix: Aqueous Date Sampled:04/28/2022 1345 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1101 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 160 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.7 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 11 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 13 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 2.8 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 130 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-032 Description: MW-12 Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1759 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 2153 CAW 42839 2 (Sulfate) 9056A 5 05/26/2022 1119 CAW 42996 1 (TDS) SM 2540C-2011 1 05/05/2022 1225 CAM 40509 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 300 20 20 mg CaCO3/L 1 Chloride 9056A 33 1.0 0.25 mg/L 1 Sulfate 9056A 280 B 5.0 1.3 mg/L 2 TDS SM 2540C-2011 770 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 131 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-032 Description: MW-12 Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260D (SIM) 1 05/11/2022 0234 BBW 41173 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 2.1 J 3.0 1.0 ug/L 2 Run 2 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 132 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-032 Description: MW-12 Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221403 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 11 J 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 2.1 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 133 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-032 Description: MW-12 Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221403 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 87 70-130 117 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 134 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-032 Description: MW-12 Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0745 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 135 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-032 Description: MW-12 Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1105 BNW 6020B 10 05/04/2022 1012 BNW Prep Date Batch 04/30/2022 1125 39932 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 67 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 43 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.7 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 170 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 3500 50 13 ug/L 2 Nickel 7440-02-0 6020B 35 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 136 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-033 Description: MW-12D Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1815 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 2212 CAW 42839 1 (Sulfate) 9056A 1 05/24/2022 2212 CAW 42841 1 (TDS) SM 2540C-2011 1 05/05/2022 1225 CAM 40509 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 200 20 20 mg CaCO3/L 1 Chloride 9056A 20 1.0 0.25 mg/L 1 Sulfate 9056A 140 1.0 0.25 mg/L 1 TDS SM 254OC-2011 470 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 137 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-033 Description: MW-12D Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 2324 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.6 J 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 138 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-033 Description: MW-12D Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0229 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 1.0 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 139 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-033 Description: MW-12D Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0229 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 87 70-130 125 70-130 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 140 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-033 Description: MW-12D Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0747 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 141 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-033 Description: MW-12D Matrix: Aqueous Date Sampled:04/28/2022 1255 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1108 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 90 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 180 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 510 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 8.0 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 142 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-034 Description: LD-5 Matrix: Aqueous Date Sampled:04/28/2022 1205 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0254 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 143 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-034 Description: LD-5 Matrix: Aqueous Date Sampled:04/28/2022 1205 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0254 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 82 70-130 1,2-Dichloroethane-d4 123 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 144 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-034 Description: LD-5 Matrix: Aqueous Date Sampled:04/28/2022 1205 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1112 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 57 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 22 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 10 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 145 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-035 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/28/2022 1245 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (BOD, 5 day) SM 521OB-2011 1 05/05/2022 1247 CLL 04/29/2022 2310 39918 1 (COD) SM 5220D-2011 4 05/03/2022 1351 KKP 40102 3 (Nitrate - N) 9056A 10 05/10/2022 2134 CAW 41425 1 (Phosphorus) 365.1 2 05/03/2022 1557 DMA 40137 1 (Sulfate) 9056A 1 05/02/2022 1211 CAW 40239 Parameter CAS Analytical Number Method Result Q LOQ DL Units Run BOD, 5 day SM 521 OB-2011 71 2.0 0.18 mg/L 1 COD SM 5220D-2011 770 80 80 mg/L 1 Nitrate - N 9056A ND H 0.20 0.050 mg/L 3 Phosphorus 7723-14-0 365.1 2.5 0.10 0.040 mg/L 1 Sulfate 9056A 21 1.0 0.25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 146 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-035 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/28/2022 1245 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221222 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 36 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.46 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.51 J 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.85 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.68 J 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 2.2 J 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D 0.83 J 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 147 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-035 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/28/2022 1245 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221222 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 2.1 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 115 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 148 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-035 Description: Leachate Pond Matrix: Aqueous Date Sampled:04/28/2022 1245 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1115 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 12 J 20 5.0 ug/L 1 Arsenic 7440-38-2 6020B 32 20 13 ug/L 1 Barium 7440-39-3 6020B 470 50 13 ug/L 1 Beryllium 7440-41-7 6020B ND 4.0 1.5 ug/L 1 Cadmium 7440-43-9 6020B ND 5.0 1.3 ug/L 1 Chromium 7440-47-3 6020B 86 50 13 ug/L 1 Cobalt 7440-48-4 6020B 21 J 50 13 ug/L 1 Copper 7440-50-8 6020B ND 50 13 ug/L 1 Lead 7439-92-1 6020B ND 10 2.5 ug/L 1 Nickel 7440-02-0 6020B 82 50 13 ug/L 1 Selenium 7782-49-2 6020B ND 50 13 ug/L 1 Silver 7440-22-4 6020B ND 10 2.5 ug/L 1 Thallium 7440-28-0 6020B ND 5.0 1.5 ug/L 1 Vanadium 7440-62-2 6020B 39 J 50 25 ug/L 1 Zinc 7440-66-6 6020B ND 100 25 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 149 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-036 Description: Leachate LD Matrix: Aqueous Date Sampled:04/28/2022 1325 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0101 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 150 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-036 Description: Leachate LD Matrix: Aqueous Date Sampled:04/28/2022 1325 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0101 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 91 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 151 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-036 Description: Leachate LD Matrix: Aqueous Date Sampled:04/28/2022 1325 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1126 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.2 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 30 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.37 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.16 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 38 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 11 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 270 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.5 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 140 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 152 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-037 Description: LD-2 Matrix: Aqueous Date Sampled:04/28/2022 1340 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0319 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.71 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.44 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.3 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.71 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 153 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-037 Description: LD-2 Matrix: Aqueous Date Sampled:04/28/2022 1340 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0319 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 87 70-130 1,2-Dichloroethane-d4 126 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 154 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-037 Description: LD-2 Matrix: Aqueous Date Sampled:04/28/2022 1340 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1129 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 180 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 59 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.0 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 155 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-038 Description: LD-1 Matrix: Aqueous Date Sampled:04/28/2022 1405 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0124 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 8.3 JL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.8 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.65 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.43 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 156 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-038 Description: LD-1 Matrix: Aqueous Date Sampled:04/28/2022 1405 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0124 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 157 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-038 Description: LD-1 Matrix: Aqueous Date Sampled:04/28/2022 1405 Date Received:04/29/2022 Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1133 BNW 6020B 10 05/04/2022 1016 BNW Prep Date Batch 04/30/2022 1125 39932 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 1.3 J 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 1700 50 13 ug/L 2 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.5 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 260 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 74 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.3 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 158 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-039 Description: LD-3 Matrix: Aqueous Date Sampled:04/28/2022 1430 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0344 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND L 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 159 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-039 Description: LD-3 Matrix: Aqueous Date Sampled:04/28/2022 1430 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 0344 BBW 40807 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 86 70-130 1,2-Dichloroethane-d4 122 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 160 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-039 Description: LD-3 Matrix: Aqueous Date Sampled:04/28/2022 1430 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1136 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 230 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.6 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 2.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 161 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-040 Description: LD-4 Matrix: Aqueous Date Sampled:04/28/2022 1445 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0147 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 JL 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 2.3 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D 0.45 J 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 162 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-040 Description: LD-4 Matrix: Aqueous Date Sampled:04/28/2022 1445 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0147 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.86 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.50 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 91 70-130 99 70-130 101 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 163 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-040 Description: LD-4 Matrix: Aqueous Date Sampled:04/28/2022 1445 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1140 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 3.2 J 4.0 1.0 ug/L 1 Arsenic 7440-38-2 6020B 4.2 4.0 2.5 ug/L 1 Barium 7440-39-3 6020B 490 10 2.5 ug/L 1 Beryllium 7440-41-7 6020B ND 0.80 0.30 ug/L 1 Cadmium 7440-43-9 6020B 0.34 J 1.0 0.25 ug/L 1 Chromium 7440-47-3 6020B 400 10 2.5 ug/L 1 Cobalt 7440-48-4 6020B 80 10 2.5 ug/L 1 Copper 7440-50-8 6020B 140 10 2.5 ug/L 1 Lead 7439-92-1 6020B 1.5 J 2.0 0.50 ug/L 1 Nickel 7440-02-0 6020B 220 10 2.5 ug/L 1 Selenium 7782-49-2 6020B ND 10 2.5 ug/L 1 Silver 7440-22-4 6020B ND 2.0 0.50 ug/L 1 Thallium 7440-28-0 6020B ND 1.0 0.30 ug/L 1 Vanadium 7440-62-2 6020B 17 10 5.0 ug/L 1 Zinc 7440-66-6 6020B 40 20 5.0 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 164 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-041 Description: LD-6 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0210 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.42 J 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 165 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-041 Description: LD-6 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/2022 0210 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 100 70-130 Toluene-d8 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 166 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-041 Description: LD-6 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1143 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 380 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 64 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 2.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 167 of 183 Inorganic non-metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-042 Description: MW-18 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 05/02/2022 1830 TAD 40142 1 (Chloride) 9056A 1 05/24/2022 2230 CAW 42839 1 (Sulfate) 9056A 1 05/24/2022 2230 CAW 42841 1 (TDS) SM 2540C-2011 1 05/05/2022 1323 CAM 40533 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su Chloride Sulfate TDS SM 2320B-2011 83 20 20 mg CaCO3/L 1 9056A 1.7 1.0 0.25 mg/L 1 9056A 32 1.0 0.25 mg/L 1 SM 254OC-2011 150 25 25 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 168 of 183 Volatile Organic Compounds by GC/MS (SIM) Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-042 Description: MW-18 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 1807 JWO 40082 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 169 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-042 Description: MW-18 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221428 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 170 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-042 Description: MW-18 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/12/20221428 JWO 41438 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 85 70-130 117 70-130 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 171 of 183 CVAA Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-042 Description: MW-18 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 05/03/2022 0750 JA132 05/03/2022 0301 40151 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 172 of 183 ICP-MS Metals Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-042 Description: MW-18 Matrix: Aqueous Date Sampled:04/28/2022 1500 Date Received:04/29/2022 Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 05/03/2022 1147 BNW Prep Date Batch 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 14 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 260 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 47 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 1.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.3 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 173 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-043 Description: Trip Blank Matrix: Aqueous Date Sampled:04/28/2022 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2306 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 174 of 183 Volatile Organic Compounds by GC/MS Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27064-043 Description: Trip Blank Matrix: Aqueous Date Sampled:04/28/2022 Date Received:04/29/2022 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/11/2022 2306 JMM2 41354 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 90 70-130 99 70-130 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 175 of 183 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 176 of 183 ,-0 Ow v PACE ANALYTICAL SERVICES, LLC CD ! 146 Vanly a Poi It f7ryua ' 1J05t C(ALlmbla, 9C P-9172 - a) [ � � [ I 7ela, l ro No. 803-7J1 9700 Fax No. 802-7914R111 CD www_paralab3_cam v� 0 m N Y °aacr+eoo•�,,cr * mn u.�ra C7 o AdckM!t �argakr� ^ r1921ra c 3 cD rn Fbrirdsd Nam 3 n a) N F4 'cr rvc, WAX CD $ w � (Cd7V nr7kf2a&,;U,WWWDO00Kkt"'arrulfico CD Nl0.j IKYl jr,mr, !} ; o0 n0— i " W aq co Vj 4 w 0 E3 .-L- ZI Tian Aruwj c , MI RMM'M fFrcn' laB PP i �d ars�q&�d e� 17L�J Sazrro-c s� St�ndar0 = ROM f5PsVf'y2 � YcihY� fo e,Paad Q p�t�ar m+s TVW t f7r�i�quk�adbx' � ,vim I'f� Tr�r= z" .riB'b1Q ushrdby , Ck [ : Mr# I D a�, r�ekrn3ue74d by EL969 TVfJD 4.,9sd4�arJ�5ed�y F J+io7e; A rr re#arJxed bf tour wxcdrs frorra rer,�rot eln�.s erD7t�' �rrrgemeraIs #rrc maf1 �— DJSTR+&UT+W4- WF - A YELLOW"P9v'xr+ jv �saaJaro*f ws6h Sa aga'f4YC FnnkCLar: Cary Number 13 , � T§'anhwj&pia I&Xgir — Ami}aie (14EI&A W Nf. 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Nm,H.w'ifd F Rmlrp.Ne 1 ° Ym IrnLard J POMOIL CJ U1I7 w .44CGiVP� } vary Tmb �. riKI-4 erby hire TYfre 2 w7cr+iorndby L'sfa Ts•Y'o 4 R klgUA3nao oy Dalo Tr" 3. fi 'Ladby oaia Tore n2W IL LTbr fifary fdC2 aLTDro — Note' A1� sa rrpir�s are retained w four weeks from mcdor LAC U.Z ramp 04k J ;�r'r V orli6W plhcr afro -.Q0 W4 i5 Bre MRIPiR. 4ac� .60 on fce (ti J ►rn i�a r'ACIJ faamq T rrri : O Wl$TR1Cvmfdr werTE.& YEtLOVARpthfllZ42wirtyH5, 45rr4- Nl-F7WfFtirJd[lYanr fryry 1i - Z— .adcu anrNjmbar VMVaW-oy D m D D n D r m 0 m cn r rl PACE ANALYTICAL SERVICES, LLC CeAr1, Samprgp Rec ipt CheCUSt ISK) IMEQ01SC-IS) Revtsed:9f�9I2020 y1 IssufrgAUtharity:PaneENV -WCOL pl{ge1of1 Sat plc R,becipt Checklist ( fitQ lianr; fiLT C ciolm l,ts' eCLt!J by/date: KE)Rw Lol 7'D27C64 Means of nC4G.p� . �11L'li. UR5 !Fj Eed7x , .` Ies J N I, Wofl custody seals prac,tt tm the cooler? 1{Cs T+it3 / h'A , It'custad scale yarn spit, vk rq It�c intact artd unLuokeu? PH Strip 11); 11-ss. Chlorine 5trfp Ja. NA TCstcd by.'-3i} OTT ginal ternperature Upon receipt l D_rived {rnrrectedj te"TUafure upon: receipt 0,,�SDlid tivap-C.-ip ID: 4.3 f4.3 're NA IAAA oC NA rKA eC 11�� /NA oC Mrthod ✓❑TGrtneratu� �3fanJ€ ailisclBotkl" 1KCiw11[k S iKGk,nComcction f'aCtur; ¢ °C MrthodoCt;orllant: 0 1tir-cc lee ❑ ice PSr:IC: ary rct� Tfrin Yes ❑ Nis ❑� NA 'S 1f temperutllr� 6f arlj+ Cg41e1' �Kee�icd 8,U'�C, w�,s f}rujeci A4o-lnagcr Notified? Pfwl �4as T rlCi fed b ftl7ona t emr,il .+ face-tD-face (¢ ircl a ul rt_ 1'e3L Na NA 4. Is tho winmemial couri�i''s puk-ilt;g slip auylehed to lhi� fnFM? 7'eS T*t0 5_ WCre 1]rp CCk13CadV prrtned�lr S=rIIRiJlLiS1L dIweived) folivw'adl J 'Yc3 N fi_ W-vre sa_'1-Ifle fl)3 Iisterjpr. ncc COC? •Yes flu 7. W-mre satnplk lUs Jismdpn a]Isarnpir econtainers? y-M I\la S. Was oolL�-tiau d� &. time iimd o:] the COC-r Q Y ND 9, Was collection dQW & thv liatd on a[- s:rrrPp1Q contaitl If `'es E,Rio -rq 10. Did a]1 container labin1 infordvuliun (ID, dar o, time) h The COC? - Y _ TO 11. Wffe Msts to be performed tiStCd or, the CoC:? ❑ Yea r] 1tia 12. Did aJf .5arrrplcs arrive i� the prDperc6nndnem !_or eaall test andJpr :n LGaod condition (unbroken, 'ids or., 4 ,)? +� Yes N!o L3_ Was ade .... availablG? �' Yfm Lj No 14. Wme all samples :-eceiWed wiltin 'IT the rigiding times Dr 48 hours, whiaevcr comes fist`% W Yes Li No 15. Were any saln deA 4n)rtainers mi55i] 'ct a 'y circle Oro so les h1gt lisaed on COC? _ [] yt* 0 No ❑Nit 16. For VOA Hnd RSI.C-17{'s&rnplaN, r1! hub�Jo present >"pea -size" 6rnrn in disrlle� 2N In ally Df tl:t: VOA vials? i Yr., N NA 17. Were aJl URO� me a lr. ni6tric.it sane J Cs received at a pia o f < 2? El Yes Na NA 18. Were: all yEn de samples feut�ivefl W a � 12 and suEfdo satn Je5 rcaci��cd at a Pk � 9? El Y s r] Jff ❑ lA 1 ,xpp tea [e NH�rTLCNrcyarli jA1egL4 .S.11�1jB, < O.51nG/[.) sarttpl 3 f'iuC a residual rhlcrinel ❑Yes ❑Na ]NA 20, VdnxJ:ienr,t=4;rksfequevs (i.e. ]equested dilutinrti IMMSD sir-igrlatians, eltw___j Correcty transcribed fvm the CDC into rite. comment se .Hou hi LTMS? Yesi Nlo 11. Yvan the c4ota r nlm}�pr lisW on the cwin4wr label? Jf .e Pu ult: 9 3ampre Proseyvitlou (Must ae cnmpleted For any sa.mPfo(g) inromr ;Lly pncscrved or witl] 11�ud�Tace,} ianlpl-(s) "el I ,nrcm received inc10ll*4tly p-Warvad and were adjusted aacordiwgly n sarnpla receiMiFir, %*L NA rRL ofrirolc ones 142S.?4, J JN03. 1 C], NaOH tL-sing SR 0 NA _ Cimc of prenervstian Jf;ttore lNa:i tine prieservaFye is needed, please oats in the C41)M rCllt4 hef4w, sa�nple(gj JNA were r'xaeivcd wilh bubbles >6 rrm in di= Mer. 3arnplos sj rra ! }k,rc received wick TRC.> 0.5 mgI. ((f 4f1 is rtp) and were Ajumtd acrond'olgly it, F41rnple reooiving with soCiun 1iJQ3uladc (Na,..g20;) with. Slws y I.D. Nl�. SR harcade lebc7s appJi5d by; XDTZW C6rhments- t val bate.. 1hr r p-j L:x :is samp'e UW-1S n71 ]1Shvd ao C:r)C: , D,,tm; O'111n02"c, Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 183 of 183