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HomeMy WebLinkAbout1101_Buncombe_MSWLF_April22GW_FID1724978_20220921DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Bunnell-Lammons Engineering, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Andrew W. Alexander, PG, RSM E-mail: andy.alexander(cDblecorp.com Phone: 864-288-1265 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Id Buncombe County Landfill 2726 Riverside Drive, Woodfin, NC, 28804 1101-MSWLF April 25-27, 2022 1979 .1600 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Andrew W. Alexander, PG RSM Consultant Hydrogeologist 864-288-1265 Facility Representative Name (Print) Title (Area Code) Telephone Number 2022-09-21 Affix NC Licensed/ Professional Geologist Seal N1111rrr�r��� NCAR�^y' NS r > 1 5 cr r � � r►r111110`11 Signature Date 6004 Ponders Court, Greenville, SC, 29615 Facility Representative Address C-284 & C-1538 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 WATER QUALITY REPORT 1st SEMI—ANNUAL EVENT 2022 OLD BUNCOMBE COUNTY LANDFILL WOODFIN, NORTH CAROLINA DWM Permit Number 1101-MSWLF-1979 DWR UIC Permit No. WI0100353 Prepared For: Buncombe County, North Carolina BLE Project Number J21-14175-06 September 2, 2022 C zo,� Dfi0LO4�� ���rriir�rrr►N� BLE North Carolina Business Licenses C-284 & C-1538 IM EJUNNELL LAMMEINS EN131NEERmr. 6004 Ponders Court I Greenville, SC 29515 864.288.1265 �I 854.288,433D 0 Info@hl2corp.com BLECQRMOM IJIMIM I RUNNELS LAIN IN ELL ONS ENGINEERING September 2, 2022 Buncombe County Solid Waste Department 81 Panther Branch Road Alexander, North Carolina 28701 Attention: Ms. Kristy Smith Subject: Water Quality Report 11t Semi -Annual Event 2022 Old Buncombe County Landfill Woodfin, North Carolina DWM Permit Number 1101-MSWLF-1979 DWR UIC Permit No. W10100353 BLE Project Number J21-14175-06 Dear Ms. Smith: Pursuant to authorization of Bunnell-Lammons Engineering, Inc. (BLE) Proposal Number J21-14175-06, dated June 22, 2021, BLE has prepared this water quality report for the 1 st semi-annual sampling event of 2022 at the Old Buncombe County Landfill. Consistent with the North Carolina Division of Waste Management (DWM) — Solid Waste Section (SWS) and the North Carolina Division of Water Resources (DWR) approved monitoring program, sampling and analysis will be conducted twice in 2022. This report contains the information required by both the DWM and DWR to document the sampling and analysis activities for the Pt semi-annual sampling event of 2022 in the State's permanent project record. Sincerely, BUNNELL LAMMONs ENGINEERING INC. At/ I Lan A.ez An wW. Al er P. R M vy Andrew e d G, S Staff Hydrogeolog Consultant Hydrogeologist Registered, NC #1475 cc: Ms. Jaclynne Drummond — DWM-ARO Mr. Brett Laverty, P.G. — DWR-ARO Mr. Michael Rogers, P.G. — DWR-CO '6004 Ponders Court, Greenvllle, SC 29615 t864.280.1265 A864,288.4430 Minfo@hle[orp,Eom BLECORP.COM 1s 1m 1i Old Buncombe County Landfill — Woodfin, North Carolina September 2, 2022 Water Quality Report — I sr Semi -Annual Event 2022 BLE Project No. J21-14175-06 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS.............................................................1 3.0 GROUNDWATER FLOW........................................................................................................... 2 4.0 RESULTS....................................................................................................................................... 2 4.1 Groundwater.................................................................................................................................... 2 4.2 Surface Water.................................................................................................................................. 2 5.0 CONCLUSIONS AND RECOMMENDATIONS.......................................................................3 6.0 QUALIFICATIONS OF REPORT..............................................................................................3 7.0 CLOSING.......................................................................................................................................3 Tables Table 1 SWS Approved Groundwater Sampling and Analysis Matrix Table 2 SWS Approved Surface Water Sampling and Analysis Matrix Table 3 Well Construction and Monitoring Well Data Table 4 Range of Groundwater Flow Velocities Table 5 Groundwater VOCs Table 6 Groundwater Field Parameters and Total Metals Table 7 Surface Water VOCs Table 8 Surface Water Field Parameters and Total Metals Figures Figure 1 Site Location Map Figure 2 Groundwater Elevation Contour Map — April 25, 2022 Appendices Appendix A Field Sampling Logs — Pace Analytical Services, LLC. Appendix B Laboratory Analytical Data — Pace Analytical Services, LLC. iofi 1s 1m 1i Old Buncombe County Landfill — Woodfin, North Carolina September 2, 2022 Water Quality Report — I sr Semi -Annual Event 2022 BLE Project No. J21-14175-06 1.0 PROJECT INFORMATION Buncombe County provides post -closure care for the Pre -Subtitle D MSWLF (unlined) located at 2726 Riverside Drive, Woodfin, North Carolina (Figure 1). The county operated the facility as a municipal solid waste (MSW), industrial solid waste (ISW), and construction and demolition (C&D) landfill. The landfill is separated into four (4) separate waste areas labeled A through D. Waste areas A, B, and C stopped receiving waste before October 9, 1991 and waste area D stopped receiving waste on September 27, 1997. Groundwater and surface water monitoring is performed semi-annually at the site in general accordance with the following documents: • Corrective Action Plan (CAP) dated September 3, 2014 prepared by SCS Engineers [FID 102260 (SCS Engineers File No 09204072.06)] • Request for Reduction of N1NA Parameters dated November 30, 2016 prepared by SCS Engineers [FID 583167 (SCS Engineers File No 09204072.141 • Report of 1,4-Dioxane Sampling and Analysis November 2018 to April 2020 dated September 1, 2020 [FID 145059 (BLE Project No. J20-14175-04] • Corrective Action Evaluation Report, Water Quality Data Through October 2021 [FID 1661864 (BLE Project No. J20-14175-03)] dated March 30, 2022 prepared by BLE. The most current SWS approved sampling matrices are provided as Table 1 and Table 2. As part of the correction action at the facility, Buncombe County applied for, and was granted a permit for subsurface injection of materials for enhanced bioremediation of VOCs in groundwater. The Underground Injection Control (UIC) Permit (No W10100353) was transmitted by the DWR on September 11, 2015. The permit issue date was September 15, 2015. The permit was renewed on September 21, 2020 and expires on August 31, 2025 (effective dates). The UIC permit requires groundwater monitoring and reporting. We understand that this semi-annual monitoring report prepared as part of the DWM approved sampling and analysis matrix is sufficient to meet the monitoring requirements of the UIC permit. The active groundwater monitoring network for the closed Buncombe County Landfill consists of one (1) upgradient (background) well and twenty-three (23) downgradient (compliance, performance, and sentinel) wells. There are a total of fourteen (14) additional wells that are considered inactive for sampling purposes and are used for collecting water levels only (Table 1). Five (5) active surface water monitoring locations have been established for the facility to monitor surface water quality. The existing surface water locations consist of one (1) upstream (background) location and four (4) downstream (compliance) locations. Five (5) inactive surface water monitoring locations have been established but are not sampled (Table 2). 2.0 FIELD ACTIVITIES, SAMPLING, AND ANALYSIS Groundwater and surface water samples were collected for the 1 st semi-annual sampling event by personnel from Pace Analytical Services, LLC. (Pace) of Asheville, North Carolina between April 25-27, 2022. Groundwater samples were collected from twenty-two (22) of the twenty-four (24) active groundwater 1 of 3 1s 1M 1i Old Buncombe County Landfill — Woodfin, North Carolina September 2, 2022 Water Quality Report — I s' Semi -Annual Event 2022 BLE Project No. J21-14175-06 monitoring well locations located on the site (Table 1). Two (2) wells (MW-24-45 and DPL-1) had insufficient volumes of water and therefore, were not sampled. Additionally, the five (5) active surface water locations were sampled during the event (Table 2). The groundwater and surface water samples were delivered to Pace Analytical Services, LLC. (Pace) of Columbia, South Carolina and analyzed in the laboratory per the approved monitoring plan. The field parameters of dissolved oxygen, iron, pH, redox potential, specific conductance, turbidity, and temperature were measured in the field by Pace. A copy of the Pace field sampling logs is included in Appendix A. A copy of the laboratory analytical data is included in Appendix B. 3.0 GROUNDWATER FLOW The water level data collected during the groundwater sampling event on April 25, 2022 is presented in Table 3. Groundwater flow velocity estimates are presented on Table 4. A groundwater elevation contour map with generalized groundwater flow direction is presented as Figure 2. 4.0 RESULTS 4.1 Groundwater The results of the groundwater field and laboratory analyses are summarized on Tables 5 and 6 and the laboratory analytical data is included in Appendix B. Please refer to Tables 5 and 6 for a summary of which groundwater constituents exceed North Carolina Groundwater Quality Standards (NC2L) maximum contaminant levels' (MCLs). Field parameters measured in the groundwater included dissolved oxygen, iron, pH, redox potential, specific conductance, turbidity, and temperature. 4.2 Surface Water The results of the surface water field and laboratory analyses are summarized on Tables 7 and 8 and the laboratory analytical data is included in Appendix B. Field parameters measured in the surface water included dissolved oxygen, pH, redox potential, specific conductance, turbidity, and temperature. Please refer to Table 7 and 8 for a summary of which surface water constituents and field parameters exceeded their established North Carolina Surface Water Quality Standards (NC2B)2 standard limits. 'North Carolina Department of Environmental Quality, Classifications of Water Quality Standards, Section 15A NCAC 2L .0202, April 1, 2022. 2 North Carolina Department of Environmental Quality, Surface Waters and Wetlands Standards, Section 15A NCAC 02B workbook dated July 26, 2022. 2 of 3 1s 1m 1i Old Buncombe County Landfill — Woodfin, North Carolina September 2, 2022 Water Quality Report — I s' Semi -Annual Event 2022 BLE Project No. J21-14175-06 5.0 CONCLUSIONS AND RECOMMENDATIONS Semi-annual assessment monitoring was performed during the 1st semi-annual event of 2022 in general accordance with the SWS approved sampling matrices (Table 1 and Table 2). Detected constituents which exceed their respective groundwater and surface water standards are identified on the summary tables. We recommend that semi-annual sampling continue in accordance the SWS approved sampling matrices. MNA parameters are scheduled to be collected and reported every five (5) years in accordance with the approved groundwater sampling matrix (Table 1). The next MNA sampling event will be performed during the Spring 2026 sampling event. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data provided to BLE. This report has been prepared on behalf of and exclusively for the use of Buncombe County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the DWM and DWR) without BLE's prior written consent. 7.0 CLOSING We appreciate the opportunity to be of service to Buncombe County, North Carolina. Please contact us at (864) 288-1265 if you have any questions or comments. 3 of 3 TABLES Table 1 SWS Approved Groundwater Sampling and Analysis Matrix Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-06B Standard Semi -Annual Laboratory Parameters Standard Semi -Annual Field Parameters Geochemical Parameters for MNA (Sampled Every 5 Years**) Monitoring Well Well Status Transect Number Appendix I VOCs (EPA 8260B) 1,4-dioxane (EPA 8260 SIM) Appendix H Full List (Various Methods) Appendix I Metals WL Turb Temp pH ORP DO SC Alkalinity DH VITA TOC BOD COD Chloride CO2 FeZ NO3 MEE SO4 Sulfide DPL-1 Active 5 Y Y O Y Y Y Y Y Y Y Y DPL-2 Injection 4 MW-A Inactive - Y MW-B Active 2 Y Y - Y Y Y Y Y Y Y Y MW-2 Active - Y O Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-3 Active 3 Y Y Y Y Y Y Y Y Y Y MW-4 Active 4 Y Y - Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-4A Active 1 Y Y - Y Y Y Y Y Y Y Y MW-5 Active 5 Y Y O Y Y Y Y Y Y Y Y MW-6 Active 5 Y Y O Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-6-192 Active 5 Y Y - Y Y Y Y Y Y Y Y MW-7 Active - Y Y Y Y Y Y Y Y Y MW-8 Inactive Y MW-9 Abandoned MW-10 Abandoned MW-12-10 Inactive - Y MW-12-25 Active 1 Y Y Y Y Y Y Y Y Y MW-13-10 Inactive - Y MW-13-35 Active 1 Y Y Y Y Y Y Y Y Y MW-13-132 Active 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-14 Inactive - Y MW-15 Active Y Y Y Y Y Y Y Y Y MW-16 Abandoned MW-17 Abandoned NM-17-60 Active 2 Y Y Y Y Y Y Y Y Y Y MW-17-137 Active 2 Y Y Y Y Y Y Y Y Y Y MW-17-310 Active - Y Y Y Y Y Y Y Y Y MW-18-3 Inactive - Y MW-18-78 Active 5 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-19-4 Inactive Y MW-19-75 Active 4 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-19-110 Active 4 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-20-3 Inactive - Y MW-20-32 Inactive Y MW-21-4 Inactive - Y MW-21-21 Active 3 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-21-94 Active 3 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y MW-22-78 Inactive - Y MW-22-143 Inactive Y MW-23-119 Inactive Y MW-23-186 Inactive - Y MW-24-45 Active 1 Y Y Y Y Y Y Y Y Y Y MW-24-160 Active 1 Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Notes: Typical Events: April (Spring) and October (Fall) BOD = Biologic Oxygen Demand 0 =October (Fall) Only COD =Chemical Oxygen Demand VOCs = Volatile Organic Compounds 40 CFR Part 258 Appendix I - Constituents for Detection Monitoring (Organics and Inorganics) SWS Approved Matrix on April 12, 2022 40 CFR Part 258 Appendix 11- Constituents for Assessment Monitoring (Full List) ** 5 Year MNA sampling to be performed twice consecutively every 5 years. MNA sampling events are scheduled for Spring and Fall 2026, Spring and Fall 2031, Spring and Fall 2036, etc. WL = Water Level ORP = Oxidation Reduction Potential DO = Dissolved Oxygen SC = Specific Conductance DH = Dissolved Hydrogen VFA = Volatile Fatty Acids TOC = Total Organic Carbon FeZ = Iron 11 NO3 = Nitrate MEE = Methane/Ethene/Ethane SO4 = Sulfate CO2 = Carbon Dioxide Prepared By: RLB T1A GW Approved Matrix of SWS Approved Matrix 14175-06B Checked By: AWA Table 2 SWS Approved Surface Water Sampling and Analysis Matrix Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J22-14175-06B Standard Semi -Annual Laboratory Parameters Standard Semi -Annual Field Parameters Surface Water Location Location Status Appendix I VOCs (EPA 8260B) 1,4-dioxane (EPA 8260 SIM) Appendix I Metals Turb Temp pH ORP DO SC SW-1 Active Y - Y Y Y Y Y Y Y SW-2 Active Y - Y Y Y Y Y Y Y SW-2A Active Y Y Y Y Y Y Y Y Y SW-3 Active Y Y Y Y Y Y Y Y Y SW-4 Active Y Y Y Y Y Y Y Y Y SW-5 Inactive - - - - - - - - - SW-6 Inactive - - - - - - - - - SW-7 Inactive - - - - - - - - - SW-8 Inactive - - - - - - - - - SW-9 1 Inactive - - - - I - I - I - I - I - Notes: Typical Events: April (Spring) and October (Fall) VOCs = Volatile Organic Compounds Y = Yes 40 CFR Part 258 Appendix I - Constituents for Detection Monitoring (Organics and Inorganics) SWS Approved Matrix on September 1, 2020 T2 SW Approved Matrix of SWS Approved Matrix 14175-06B ORP = Oxidation Reduction Potential DO = Dissolved Oxygen SC = Specific Conductance Prepared By: AWA Checked By: TJD Table 3 Well Construction and Monitoring Well Data Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J21-14175-06 Monitoring Point Northing Eastingt TOC Elevation (ft), GS Elevation (ft), Depth to GW (ft) April 25, 2022 Groundwater Elevation (ft) Well Depth (ft)1 Screen Depth (below GS)' Geology Monitored) Well Status/Purpose DPL-1 714,361.2 928,456.1 2040.73 2038.23 Dry Dry 65 55 - 65 Bedrock Compliance DPL-2 714,508.1 928,812.6 2112.15 2109.65 A A 97 87 - 97 Bedrock Injection MW-A 714,654.47 931,068.90 2063.37 2061.90 0.41 2062.96 33 23 - 33 Bedrock DNA MW-B 713,635.93 930,421.08 1960.86 1960.30 4.01 1956.85 15 5 - 15 Bedrock Compliance MW-2 715,052.9 930,063.8 2205.33 2203.40 107.82 2097.51 175 145 - 175 Bedrock Background MW-3 713,790.10 929,814.44 1991.15 1989.90 64.84 1926.31 90 60 - 90 Bedrock Compliance MW-4 714,177.83 928,875.09 2014.27 2013.60 71.96 1942.31 75 55 - 75 Bedrock Performance MW-4A 1713,351.70 931,195.02 2083.10 2082.50 68.65 2014.45 77 1 67 - 77 Bedrock Compliance MW-5 714,620.07 928,174.58 2019.73 2019.00 50.00 1969.73 80 70 - 80 Bedrock Compliance MW-6 715,103.13 928,152.69 2002.08 2000.30 0.00 2002.08 40 30 - 40 Bedrock Performance MW-6-192 715,146.34 928,113.86 2009.02 2006.73 25.55 1983.47 192 182 - 192 Bedrock Compliance MW-7 715,604.13 930,534.81 2108.86 2107.70 22.65 2086.21 29 14 - 29 Saprolite Compliance MW-8 716,107.98 930,308.94 2079.02 2077.20 24.51 2054.51 38 23 - 38 Saprolite DNA MW-9 716,024.04 928,619.48 2061.59 2060.00 A A 29 1 14 - 29 Saprolite DNA MW-10 716,086.5 929,060.5 2049.67 2047.40 A A 19 9 - 19 Saprolite DNA MW-12-10 DNA DNA 2028.03 2024.94 Dry Dry 8 4 - 8 Saprolite DNA MW-12-25 713,258.9 931,353.0 2029.98 2026.36 7.50 2022.48 26 16 - 26 Bedrock Compliance MW-13-10 713,000.2 931,279.7 2012.26 2009.85 3.32 2008.94 10 4 - 10 Saprolite DNA MW-13-35 713,023.1 931,236.9 2017.68 2014.13 6.43 2011.25 35 25 - 35 Bedrock Compliance MW-13-132 712,997.8 931,274.0 2012.89 2009.58 23.70 1989.19 132 122 - 132 Bedrock Performance MW-14 716,348.1 930,124.0 2053.46 2049.61 7.18 2046.28 55 40 - 55 Bedrock DNA MW-15 716,995.2 929,509.6 2028.08 2024.08 5.09 2022.99 72 62 - 72 Bedrock Compliance MW-16 716,170.0 929,107.2 2048.13 2045.13 A A 94 84 - 94 Bedrock DNA MW-17 DNA DNA DNA DNA A A DNA DNA - DNA DNA DNA MW-17-60 713,339.0 930,205.8 1922.97 1920.35 22.58 1900.39 60 50 - 60 Bedrock Compliance MW-17-137 713,329.8 930,199.1 1921.73 1919.24 21.18 1900.55 137 127 - 137 Bedrock Compliance MW-17-310 713,302.4 930,207.9 DNA 1918.00 0.00 DNA 310 300 - 310 Bedrock Compliance MW-18-3 714,130.9 927,843.0 1895.62 1892.62 Dry Dry 3 1 - 3 Flood Plain DNA MW-18-78 714,131.1 927,848.7 1894.62 1891.62 6.82 1887.80 78 68 - 78 Bedrock Sentinel MW-19-4 713,953.9 928,939.4 1902.27 1898.97 Dry Dry 4 2 - 4 Flood Plain DNA MW-19-75 713,948.7 928,950.0 1900.72 1898.02 9.66 1891.06 75 65 - 75 Bedrock Compliance MW-19-110 713,951.7 928,942.4 1901.43 1898.53 10.37 1891.06 110 100 - 110 Bedrock Sentinel MW-20-3 713,865.0 929,310.2 1898.90 1895.90 Dry Dry 3 2 - 3 Flood Plain DNA MW-20-32 713,879.0 929,332.7 1899.57 1896.67 1 6.50 1893.07 32 22 - 32 Bedrock DNA MW-21-4 713,810.5 929,567.5 1900.33 1896.73 6.72 1893.61 4 2 - 4 Flood Plain DNA MW-21-21 713,826.6 929,581.7 1900.49 1897.49 5.45 1895.04 21 11 - 21 Bedrock Performance MW-21-94 713,829.5 929,577.5 1901.06 1897.76 8.03 1893.03 94 84 - 94 Bedrock Sentinel MW-22-78 716,370.39 930,380.26 2068.13 2065.92 23.68 2044.45 79 69 - 79 Bedrock DNA MW-22-143 716,306.96 930,320.49 2068.34 2066.17 46.67 2021.67 148 138 - 148 Bedrock DNA MW-23-119 716,014.05 930,476.24 2076.61 2074.37 1 42.78 2033.83 120 110 - 120 Bedrock DNA MW-23-186 716,004.53 930,480.42 2076.43 2074.29 51.60 2024.83 186 176 - 186 Bedrock DNA MW-24-45 711,372.03 930,963.22 1932.07 1929.82 Dry Dry 45 35 - 45 Bedrock Compliance MW-24-160 711,435.81 931,042.73 1933.24 1930.93 94.92 1838.32 160 150 - 160 Bedrock Sentinel - Data from Table 1, Well Construction Summary, from Old Buncombe County Landfill Corrective Action Plan, by SCS Engineers, Dated September 3, 2014. TOC - Top of Casing. GS - Ground Surface. DNA - Data Not Available A - Abandoned 14175-06B GW Tables Prepared By: IAI Table 3 April 2022 Checked By: RLB/AWA Table 4 Range of Groundwater Flow Velocities Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J21-14175-06 Hydraulic Conductivity K(ft/min) K(cm/sec) K(ft/day) High Estimate 3.9E-02 2.0E-02 56.10 Low Estimate 3.3E-03 1.7E-03 4.80 Geometric Mean 1.1E-02 5.8E-03 16.41 Geometric Mean Hydraulic Conductivity K(ft/day) Hydraulic Grad. (ft/ft) Effective Porosity Flow Vel. (ft/day) Flow Vel. (ft/year) High Estimate 16.41 0.261 5% 85.62 31,250 Low Estimate 16.41 0.027 5% 8.75 3,194 Notes 1. Hydraulic conductivity and effeictive porosity values obtainted from the table titled April 2014 Groundwater Velocity Calculations from the report titled Old Buncombe County Landfill Corrective Action Plan prepared by SCS dated September 3, 2014. 3. The hydraulic gradients were measured from the April 25-28, 2022 groundwater elevation contour map (Figure 2). The high hydraulic gradient was measured between the 1900-ft & 1960-ft groundwater contours near MW-17-60 and MW-B. The low hydraulic gradient was measured between the 2040-ft & 2020-ft groundwater contours near MW-14 and MW-15. 4. Groundwater velocity derived from V = Ki/ne where: K = geometric mean hydraulic conductivity, i = hydraulic gradient, and ne = effective porosity. 5. The high and low velocity estimates are calculated using the geometric mean K and the high and low range of site hydraulic data obtained from SCS's Corrective Action Plan. The accuracy is limited by the references used. 14175-06B GW Tables Prepared By: IAI Table 4 GW Flow Vel. Checked By: RLB/AWA Table 5 Groundwater VOCs Old Buncombe County Landfill Woodlin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J21-14175-06 Sampled by Pace Analytical Services, LLC. April 25-27, 2022 TEST UNITS LOQ DL MCL NM-B MW-2 MW-3 MW4 MW-4A MW-5 MW-6 MW-6-192 MW-7 MW-12-25 MW-13-35 MW-13-132 MW-15 MW-17-60 MW-17-137 MW-17-310 MW-18-78 MW-19-75 MW-19-110 MW-21-21 MW-21-94 MW-24-45 MW-24-160 DPL-1 Acetone µg/l 20 5.0 6,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Dry <5.0 Dry Acrylomtnle µgIl 20 0.80 NE <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 Dry <0.80 Dry Benzene µg/l 1.0 0.40 1.0 <0.40 <0.40 1.1 0.93 J 5.5 0.73 J 1.1 <0.40 1.4 <0.40 0.43 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 2.3 <0.40 Dry <0.40 Dry Bromochloromethane µgIl 1.0 0.40 NE <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Bromodichloromethane µg/l 1.0 0.40 0.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Bromofia µgIl 1.0 0.40 4.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Carbon Disulfide 99/1 1.0 0.40 700 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Bromomethane (Methylbromide) 99/1 2.0 0.40 10 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Carbon tetrachloride µg/l 1.0 0.40 0.3 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Chlorobenzene (mono) 99/1 1.0 0.40 50 1.2 <0.40 3.4 5.1 37 8.2 7.5 0.84 J 8.0 <0.40 1.0 <0.40 <0.40 <0.40 <0.4 <0.40 1.1 2.5 <0.40 10 <0.40 Dry <0.40 Dry Chloroethane µg/l 2.0 0.40 3,000 <0.4 <0.40 2.4 2.0 <0.40 1.0 J 2.8 0.80 J 2.0 <0.40 <0.40 <0.40 <0.40 <0.40 0.41 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Chloroform µgIl 1.0 0.40 70 <0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Chloromethane (Methylchloride) 99/1 1.0 0.50 3.0 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Dry <0.5 Dry Dibromochloromethane µgIl 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1,2-Dibromo-3-chloropropane; DBCP 99/1 1.0 0.40 0.04 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1,2-Dibromoedme; Ethylene dibromide 99/1 1.0 0.40 0.02 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Dibromomethane 99/1 1.0 0.40 70.0 (1) <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1,2-Dichlorobenzene 99/1 1.0 0.40 20 <0.40 <0.40 0.60 J 0.77 J 4.1 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 1.6 <0.40 Dry <0.40 Dry 1,4-Dichlorobenzene µg/l 1.0 0.40 6.0 1.8 <0.40 6.1 11 13 4.1 2.8 <0.40 2.6 <0.40 0.90 J <0.40 <0.40 <0.40 <0.40 <0.40 0.64 J 2.2 <0.40 11 <0.40 Dry <0.40 Dry trans-1,4-Dichloro-2-butene µgIl 2.0 0.50 NE <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 Dry <0.50 Dry 1,1-Dichloroethane 99/1 1.0 0.40 6.0 1.4 <0.40 1.3 6.4 <0.40 <0.40 1.5 0.74 J 1.6 <0.40 <0.40 1.1 <0.40 0.93 J 0.68 J <0.40 <0.40 0.57 J <0.40 1.5 <0.40 Dry <0.40 Dry 1,2-Dichloroethane 99/1 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.56 J <0.40 Dry <0.40 Dry 1,1-Dichloroethene(-ethylene) 99/1 1.0 0.40 350 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry cis-1,2-Dichloroethene (-ethylene) 99/1 1.0 0.40 70 16 <0.40 0.66 J 16 0.58 J <0.40 <0.40 <0.40 12 <0.40 1.7 8.2 <0.40 1.2 <0.40 <0.40 <0.40 <0.40 <0.40 2.4 <0.40 Dry <0.40 Dry trans-1,2-Dichloroethene (-ylene) µg/l 1.0 0.40 100 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1,2-Dichloropropane 99/1 1.0 0.40 0.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry cis-1,3-Dichloropropene (-propylene) µg/l 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry trans-1,3-Dichloropropene (-propylene) 99/1 1.0 0.40 0.4 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Ethylbenzene µg/l 1.0 0.40 600 <0.40 <0.40 <0.40 <0.40 3.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 2-Hexanone µgIl 10.0 2.0 40 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 <2.00 Dry <2.00 Dry Iodomethane 99/1 5.0 0.40 NE <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Dichloramethane (Methylene chloride) 1.0 0.40 5.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 2-Butanone (Methyl ethyl ketone) µg/l 10.0 2.0 4,000 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 2.6 J <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry 4-Methyl-2-Pent anone 99/1 10.0 2.0 100 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 Dry <2.0 Dry Styrene µg/l 1.0 0.41 70.0 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.41 Dry <0.41 Dry 1, 1, 1,2-Tetrachloroethane µg/1 1.0 0.40 1.0 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1, 1,2,2-Tetrachloroethane µg/l 1.0 0.40 0.2 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Tetrachloroethene (-ethylene) µg/l 1.0 0.40 0.7 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Toluene µg/l 1.0 0.40 600 <0.40 <0.40 <0.40 <0.40 1.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1, 1, 1 -Trichlomethane 99/1 1.0 0.40 200 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1,1,2-Trichloroethane µg/l 1.0 0.40 0.6 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Trichloroethene (-ethylene) µg/1 1.0 0.40 3.0 <0.40 <0.40 <0.40 0.77 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Trlchlorofinoromethane µg/l 1.0 0.40 2,000 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 1,2,3-Trichloropropane 99/1 1.0 0.40 0.005 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry Vinyl acetate µg/l 5.0 1.2 88.0 (i) <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 Dry <1.2 Dry Vinyl chloride 99/1 1.0 0.40 0.03 9.7 <0.40 0.45 J 2.6 0.50 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.58 J 0.44 J <0.40 <0.40 <0.40 <0.40 1.3 <0.40 Dry <0.40 Dry Total Xylenes µg/l 1.0 0.40 500 <0.40 <0.40 0.58 J <0.40 4.1 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 0.47 J <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 Dry <0.40 Dry 14-Dioxane 3.0 1.0 3.0 34 NT 89 17 27 84 38 6.1 NT NT NT NT NT 22 35 NT 21 57 19 60 29 NT Dry Diethylphthalate µg/1 4 0.5 6,000 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Naphthalene µg/l 0.8 0.2 6 NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Other A .II Volatile Organic Compounds VOC's Various I Various I Various I Various NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT NT Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDENQ, Groundwater Classifications and Standards Section 15A NCAC 2L .0202. Updated April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = Detection Limit 8. NT = Not Tested 9. "J"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 10. Appendix II VOCs are only collected durign the fall sampling event. 14175-06B GW Tables Table 5 VOC April 2022 Prepared By: IAI Checked By: RLB/AWA Table 6 Groundwater Field Parameters and Total Metals Old Buncombe County Landfill Woodtin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J21-14175-06 Sampled by Pace Analytical Services, LLC. April 25-27, 2022 TEST UNITS LOQ DL MCL MW-B MW-2 MW-3 MW4 MW-4A MW-5 MW-6 MW-6-192 MW-7 MW-12-25 AM-13-35 MW-13- 132 MW-15 MW-17-60 MW-17- 137 MW-17- 310 AM-18-78 MW-19-75 MW-19- 110 MW-21-21 MW-21-94 MW-24-45 MW-24- 160 DPL-1 pH S.U. >6.5, <8.5 6.6 6.1 6.3 6.1 6.1 6.3 6.1 6.4 5.7 6.6 6.0 7.1 12.3 6.9 7.4 8.4 7.1 6.3 7.4 6.4 7.6 Dry 7.4 Dry Specific Conductance mmhos/cm NE 696 134 1,244 961 723 1,593 1,465 447.4 220.9 530.3 358.1 339.2 6,143 625 820 143.0 648 931 452.2 1386 808 Dry 175.5 Dry Temperature °C NE 14.4 18.3 15.2 16.7 14.7 14.2 18.3 20.3 14.6 19.6 18.2 22.3 13.9 19.8 21.9 16 19.4 20.6 24.1 20.2 22.7 Dry 15.9 Dry Turbidity NTU NE 25.2 9.9 3 1.4 0.6 1.7 1.9 0.6 6.9 0.5 0.4 1.4 1.4 0.8 1.5 9.5 0.7 0.5 0.8 4.4 1.9 Dry 30.33 Dry Dissolved Oxygen (DO) mg/L NE 0.3 1.5 4.8 0.3 0.5 7.1 5.6 0.4 0.8 2.4 3.5 0.7 6.7 0.7 1.1 0.7 0.6 0.2 2.4 0.2 4.5 Dry 0.5 Dry Redox mV NE -31 -4.5 -25.3 -0.2 -34.8 -0.6 -17.1 -9.1 48.7 191.6 308.1 -122.9 -38.1 -100.1 -80 -25 -116.5 -96.2 25.7 -56 40.1 Dry 65.6 Dry Total Antimony (Sb) µg/1 2.0 0.5 1.0 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.1 J <0.50 <0.50 <0.50 <0.50 <0.50 0.60 J <0.50 <0.50 Dry <0.50 Dry Total Arsenic (As) µg/l 2.0 1.3 10 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 <1.30 33 <1.30 <1.30 <1.30 <1.30 Dry <1.30 Dry Total Barium (Ba) µg/l 5.0 1.3 700 190 27 180 520 710 190 1,600 65 160 50 190 47 150 24 26 3.2 J <1.30 96 12 110 25 Dry 13 Dry Total Beryllium (Be) µg/l 0.4 0.15 4.0 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Dry <0.15 Dry Total Cadmium (Cd) µg/l 0.5 0.13 2.0 <0.13 <0.13 <0.13 0.94 0.17 J <0.13 <0.13 <0.13 0.15 J <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 4.4 J <0.13 <0.13 <0.13 <0.13 Dry <0.13 Dry Total Chromium (Cr) µg/1 5.0 1.3 10 <1.3 51 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 22 <1.3 <1.3 <1.3 <1.3 1.7 J 1.4 J <1.30 3.6 J Dry 1.7 J Dry Total Cobalt (Co) µg/l 5.0 1.3 1.0 <1.3 <1.3 13 60 47 12 <1.3 <1.3 250 <1.3 1.5 J <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 11 <1.3 Dry <1.3 Dry Total Copper (Cu) µg/l 5.0 1.3 11000 <1.3 3.5 J <1.3 <1.3 <1.3 <1.3 1.7 J <1.3 1.9 J 1.3 J 1.5 J <1.30 2.5 J <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Dry 1.4 J Dry Total Lead (Pb) µg/l 1.0 0.25 15 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 0.91 J <0.25 <0.25 0.26 J <0.25 <0.25 <0.25 <0.25 <0.25 Dry 1.2 Dry Total Mercury (Hg) µg/l 0.20 0.091 1.0 NT <0.091 NT NT NT <0.091 <0.091 NT NT NT NT NT NT NT NT NT NT NT NT NT NT Dry NT Dry Total Nickel (Ni) µg/l 5.0 1.3 100 <1.3 51 31 81 8.3 25 11 1.3 J 77 15 5.4 1.6 J <1.3 <1.3 <1.3 <1.3 3.9J 20 4.5 J 4.0 J 11 Dry 2.8 J Dry Total Selenium (Se) µg/l 5.0 1.3 20 <13 <1.3 <1.3 <1.3 <1.3 1.3 J <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Dry <1.3 Dry Total Silver (Ag) µg/l 1.0 0.25 20 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 Dry <0.3 Dry Total Thallium (Tl) µg/l 0.5 0.15 2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Dry <0.2 Dry Total Tin (Sn) µg/l 20 5.0 2,000 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 Dry <5.0 Dry Total Vanadium (V) µg/l 5.0 2.5 7 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 Dry <2.5 Dry Total Zinc Zn 10 2.5 1,000 <2.5 2.8 J 3.2 J 14 <2.5 7.6 J 3.4 J <2.5 15 11 6.4 J 4.2 J 11 <2.5 <2.5 26 <2.5 4.8 J 3.4 J <2.5 3.7 J Dry 7.5 J Dry Notes: 1. MCL = Maximum Contaminant Level, as established in the NCDEQ, Groundwater Classifications and Standards Section 15A NCAC 2L .0202. Updated April 1, 2022 2. (i) = Interim Maximum Allowable Concentrations (IMACs). Updated April 1, 2022 3. Shaded cells indicate exceedances of IMACs 4. Shaded cells indicated exceedances of MCLs 5. NE = Not Established; North Carolina has not established a MCL 6. LOQ = Limit of Quantitation 7. DL = Detection Limit 8. NT = Not Tested 9. "7"-flagged data (i.e., values estimated between the DL and the LOQ) are presented on this spreadsheet. 14175-06B GW Tables Table 6 Metals April 2022 Prepared By: IAI Checked By: RLB/AWA Table 7 Surface Water VOCs Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J21-14175-06 Sampled by Pace Analytical Services, LLC. April 25-27, 2022 TEST UNITS LOQ DL NC2B SW-1 SW-2 SW-2A SW-3 SW-4 Acetone µg/1 20 5.0 2,000 <5.0 <5.0 <5.0 <5.0 <5.0 Acrylonitrile µg/1 20 0.80 420 <0.8 <0.8 <0.8 <0.8 <0.8 Benzene µg/1 1.0 0.40 51 <0.4 <0.4 <0.4 <0.4 <0.4 Bromochloromethane µg/1 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 Bromodichloromethane µg/1 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 Bromoform µg/1 1.0 0.40 120 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon Disulfide µg/1 1.0 0.40 100 <0.4 <0.4 <0.4 <0.4 <0.4 Bromomethane (Methylbromide) µg/1 2.0 0.40 0.04 <0.4 <0.4 <0.4 <0.4 <0.4 Carbon tetrachloride µg/1 1.0 0.40 1.6 <0.4 <0.4 <0.4 <0.4 <0.4 Chlorobenzene (mono) µg/1 1.0 0.40 800 <0.4 <0.4 <0.4 <0.4 <0.4 Chloroethane µg/1 2.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 Chloroform µg/1 1.0 0.40 2,000 <0.4 <0.4 <0.4 <0.4 <0.4 Chloromethane (Methylchloride) µg/1 1.0 0.50 96 <0.5 <0.5 <0.5 <0.5 <0.5 Dibromochloromethane µg/1 1.0 0.40 21 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromo-3-chloropropane; DBCP µg/1 1.0 0.40 0.13 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dibromoethane; Ethylene dibromide µg/1 1.0 0.40 0.1 <0.4 <0.4 <0.4 <0.4 <0.4 Dibromomethane µg/1 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichlorobenzene µg/1 1.0 0.40 3,000 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-Dichlorobenzene µg/1 1.0 0.40 900 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,4-Dichloro-2butene µg/1 2.0 0.50 NE <0.5 <0.5 <0.5 <0.5 <0.5 1, 1 -Dichloroethane µg/1 1.0 0.40 100 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloroethane µg/1 1.0 0.40 650 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1 -Dichloroethene (-ethylene) µg/1 1.0 0.40 20,000 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,2-Dichloroethene (-ethylene) µg/1 1.0 0.40 720 <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,2-Dichloroethene (-ylene) µg/1 1.0 0.40 4,000 <0.4 <0.4 <0.4 <0.4 <0.4 1,2-Dichloropropane µg/1 1.0 0.40 31.0 <0.4 <0.4 <0.4 <0.4 <0.4 cis-1,3-Dichloropropene (-propylene) µg/1 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 trans-1,3-Dichloropropene (-propylene) µg/1 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 Ethylbenzene µg/1 1.0 0.40 97 <0.4 <0.4 <0.4 <0.4 <0.4 2-Hexanone µg/1 10 2.0 NE <2.0 <2.0 <2.0 <2.0 <2.0 Iodomethane µg/1 5.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 Dichloromethane (Methylene chloride) µg/1 1.0 0.40 1,000 <0.4 <0.4 <0.4 <0.4 <0.4 2-Butanone (Methyl ethyl ketone) µg/1 10 2.0 26,000 <2.0 <2.0 <2.0 <2.0 <2.0 4-Methyl-2-Pentanone µg/1 10 2.0 26,000 <2.0 <2.0 <2.0 <2.0 <2.0 Styrene µg/1 1.0 0.41 NE <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1,2-Tetrachloroethane µg/1 1.0 0.40 NE <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2,2-Tetrachloroethane µg/1 1.0 0.40 4.0 <0.4 <0.4 <0.4 <0.4 <0.4 Tetrachloroethene (-ethylene) µg/1 1.0 0.40 3.3 <0.4 <0.4 <0.4 <0.4 <0.4 Toluene µg/1 1.0 0.40 11 <0.4 <0.4 <0.4 <0.4 <0.4 1, 1, 1 -Trichloroethane µg/1 1.0 0.40 200,000 <0.4 <0.4 <0.4 <0.4 <0.4 1,1,2-Trichloroethane µg/1 1.0 0.40 8.9 <0.4 <0.4 <0.4 <0.4 <0.4 Trichloroethene (-ethylene) µg/1 1.0 0.40 30 <0.4 <0.4 <0.4 <0.4 <0.4 Trichlorofluoromethane µg/1 1.0 0.40 67,000 <0.4 <0.4 <0.4 <0.4 <0.4 1,2,3-Trichloropropane µg/1 1.0 0.40 0.001 <0.4 <0.4 <0.4 <0.4 <0.4 Vinyl acetate µg/1 5.0 1.2 NE <1.2 <1.2 <1.2 <1.2 <1.2 Vinyl chloride µg/1 1.0 0.40 2.4 <0.4 <0.4 <0.4 <0.4 <0.4 Total Xylenes µg/1 1.0 0.40 670 <0.4 <0.4 <0.4 <0.4 <0.4 1,4-dioxane 3.0 1.0 80 NT NT 11 45 63 Notes NC213 = North Carolina Surface Water Standards for Class B freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 7-26-21) NE = Not Established; North Carolina has not established a MCL NT = Not Tested DL = Detection Limit LOQ = Limit of Quantitation "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. Shaded cells indicated exceedances ofNC213 Surface Water Standards 14175-06B SW Tables Prepared By: IAI Table 7 SW VOC (4-26-22) Checked By: RLB/AWA Table 8 Surface Water Field Parameters and Total Metals Old Buncombe County Landfill Woodfin, North Carolina Permit No. 1101-MSWLF-1979 BLE Project Number J21-14175-06 Sampled by Pace Analytical Services, LLC. April 25-27, 2022 TEST UNITS LOQ DL NC2B SW-1 NC2B SW-2 NC213 SW-2A NC213 SW-3 NC213 SW-4 pH S.U. (on -site) <6.0; >9.0 7.6 <6.0; >9.0 7.3 <6.0; >9.0 7.5 <6.0; >9.0 7.6 <6.0; >9.0 7.9 Specific Conductance µmhos/cm (on -site) NE 44.1 NE 96.8 NE 405.7 NE 611 NE 1349 Temperature °C (on -site) 29.0 18.2 29.0 17.5 29.0 16.2 29.0 18.2 29.0 19.3 Turbidity NTU (on -site) 50.0 4.6 50.0 4.6 50.0 5.2 50.0 29.3 50.0 3.4 Hardness mg/L 10 2.0 NE NT NE NT NE NT NE NT NE NT Dissolved Oxygen mg/L - - <4.0 6.4 <4.0 5.3 <4.0 5.4 <4.0 5.2 <4.0 4.6 Redox mV - - NE 72.9 NE 83.3 NE 97.3 NE 106.3 NE 106.7 Total Antimony (Sb) µg/1 2.0 0.50 640 <0.5 640 <0.5 640 <0.5 5,300 <0.5 5,300 <0.5 Total Arsenic (As) µg/1 2.0 1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 10.0 <1.3 Total Barium (Ba) µg/1 5.0 1.3 21,000 11 21,000 14 21,000 34 21,000 120 21,000 94 Total Beryllium (Be) µg/1 0.40 0.15 65.0 <0.2 65.0 <0.2 65.0 <0.2 65.0 <0.2 65.0 <0.2 Total Cadmium (Cd) µg/1 0.50 0.13 0.82 <0.1 0.43 <0.1 2.98 <0.1 4.35 <0.1 8.95 <0.1 Total Chromium (Cr) µg/l 5.0 1.3 183.07 <1.3 100.36 <1.3 616.02 <1.3 879.9 <1.3 1736.91 <1.3 Total Cobalt (Co) µg/1 5.0 1.3 4.0 <1.3 4.0 <1.3 4.0 <1.3 4.0 3.3 J 4.0 4.8 J Total Copper (Cu) µg/1 5.0 1.3 3.64 <1.3 1.82 <1.3 14.7 <1.3 22.16 <1.3 48.45 <1.3 Total Lead (Pb) µg/1 1.0 0.25 13.88 <0.3 6.04 <0.3 71.63 <0.3 114.5 <0.3 273.64 <0.3 Total Mercury (Hg) µg/1 NT NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT 0.012 NT Total Nickel (Ni) µg/1 5.0 1.3 144.92 <1.3 77.88 <1.3 507.55 1.7 J 733.54 4.4 J 1480.83 20 Total Selenium (Se) µg/1 5.0 1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 5.0 <1.3 Total Silver (Ag) µg/1 1.0 0.25 0.3 <0.3 0.08 <0.3 3.79 <0.3 8.01 <0.3 33.42 <0.3 Total Thallium (Tl) µg/l 0.5 0.15 2.0 <0.2 2.0 <0.2 2.0 <0.2 2.0 <0.2 2.0 <0.2 Total Vanadium (V) µg/1 5.0 2.5 NE <2.5 NE <2.5 NE <2.5 NE <2.5 NE <2.5 Total Zinc (Zn) µ 1 10 2.5 36.2 2.5 J 19.44 <2.5 127.04 <2.5 183.7 2.6 J 371.25 ND Notes: NC213 = North Carolina Surface Water Standards for Class B freshwater under Title 15A Subchapter 213. per NC DWR Surface Water Quality Standards, Criteria, & In -Stream Target Values (Workbook Dated 6-10-2019) Measured values of hardness were utilized to calculate an acute standard at each surface water location for metals highlighted in green. -1 Hardness values were reported in Report of Water Quality Sampling and Analysis 1st Semi -Annual Event 2020 prepared by BLE, dated July 14, 2020 NE = Not Established; North Carolina has not established a standard "J"-flagged data (i.e., values estimated between the MDL and the MRL) are presented on this spreadsheet. Shaded cells indicated exceedances of NC213 Surface Water Standards DL = Detection Limit LOQ = Limit of Quantitation NT = Not Tested DNA = Data Not Available 14175-06B SW Tables Table 8 SW Metals (4-27-22) Prepared By: IAI Checked By: RLB/AWA FIGURES 20 �,. /� ��� �� 2000 � ✓ R 1 I � � z� (gip yr� � o< N D � A os o� 1720 o ` gj z� A1Kf/y St OR01� J WFOMCHASE'R_D �/ DO o r<GG � �� CHADWICK WADE'DR � SAA17 G - - - u- A QJ �J r Ashelawn Gardens , of Memory Q.Memorial Garden 0 I P o D d. z- �� M ocA�R��\���~ 19 ODFI-NNy ldvie v knob , ?CH �I PRO D _ ench BroQcj zUe z�D 25 gp1A $ C ; IOLivette-Cem,-----F j9oo 70 ❑ 00 1 3 Old Macedonia { v 251 N AupuBON:pR � f , Bus o 1 Il ^ Q 23 0 m, REFERENCES: Mour USGS TOPOGRAPHIC MAP, 7.5 2000 1000 0 2000 4000 r MINUTE SERIES, WEAVERVILLE AND APPROXIMATE SCALE IN FEET LEICESTER. NC. QUADRANGLE 2019 ,j ' � , DRAWN: KLW DATE: 9-2-22 FIGURE IM BUNNELL M LAMMONS SITE LOCATION MAP CHECKED: RLB CAD: BCOLF06—SLM M ENGINEERING CLOSED BUNCOMBE COUNTY LANDFILL 6004 Ponders Court, Greenville, SC 29615 WOODFIN, NORTH CAROLINA 1 APPROVED:AWA JOB NO: J21-14175-06 Phone: (864) 288-1265 Fax: (864) 288-4430 250 125 0 250 500 APPROXIMATE SCALE IN FEET �OeOpO 1 pC� cri a0 ACTIVE MONITORING WELLS INACTIVE MONITORING WELLS ABANDONED MONITORING WELLS ACTIVE SURFACE WATER SAMPLING LOCATIONS INACTIVE SURFACE WATER SAMPLING LOCATIONS MW-2 MW-8 MW-9 SW-1 SW-5 MW-3 MW-12-10 MW-10 SW-2 SW-6 MW-4 MW-13-10 MW-16 SW-2A SW-7 MW-4A MW-14 MW-17 SW-3 SW-8 MW-5 MW-18-3 DPL-2 SW-4 SW-9 MW-6 MW-19-4 MW-6-192 MW-20-3 MW-7 MW-20-32 MW-12-25 MW-21-4 MW-13-35 MW-22-78 MW-13-132 MW-22-143 MW-15 MW-23-119 MW-17-60 MW-23-186 MW-17-137 MW-A M W-17-310 MW-18-78 M W-19-75 MW-19-110 MW-21-21 M W-21-94 M W-24-45 MW-24-160 DPL-1 MW-B NOTE: ACTIVE SAMPLING MONITORING WELLS AND SURFACE LOCATIONS ARE TO BE SAMPLED AND TESTED TWICE ANNUALLY. INACTIVE MONITORING WELLS ARE TO BE CHECKED FOR DEPTH TO GROUNDWATER ONLY. *WELL NOT USED FOR CONTOURING PURPOSES. ** WATER LEVELS COLLECTED BUT NO VERIFIABLE SURVEY DATA COLLECTED FOR GROUNDWATER ELEVATION CONTOURING PURPOSES. NM - NOT MEASURED I P-rF-NIF) MW-2® ACTIVE GROUNDWATER MONITORING WELL MW-8® INACTIVE GROUNDWATER MONITORING WELL MW-8 & ABANDONED GROUNDWATER MONITORING WELL SW-1- ACTIVE SURFACE WATER MONITORING LOCATION SW-54 INACTIVE SURFACE WATER MONITORING LOCATION PROPERTY BOUNDARY SURFACE WATER POTENTIOMETRIC CONTOUR N PLAN, CONTOUR INTERVAL = 20 FEET GROUNDWATER FLOW DIRECTION TOPOGRAPHIC SURFACE CONTOUR IN FEET ABOVE MSL CONTOUR INTERVAL = 10 FEET 250 125 0 250 500 APPROXIMATE SCALE IN FEET REVISIONS No. DESCRIPTION BY DRAWN: IAI CHECKED: RLB APPROVED: AWA DATE: 9-2-22 CAD FILE: BCOLF-06POT042522 JOB NO: J21-14175-06 � LAMMONS ENGINEERING 6004 Ponders Court, Greenville, SC 29615 Phone: (864) 288-1265 Fax: (864) 288-4430 GROUNDWATER ELEVATION CONTOUR MAP — APRIL 25, 2022 OLD BUNCOMBE COUNTY LANDFILL WOODFIN, NORTH CAROLINA FIGURE NO. 2 APPENDIX A FIELD SAMPLING LOGS PACE ANALYTICAL SERVICES, LLC. t7arumant Nang field data Sheet Date Issued: March s, 2019 Page: rAC@A/tA/y(fGd1 1 aft tJoclamenFNumhec. FCAR-CAR-001-rev;0.9 IssuingAuthority Pace Huntersville:Quahty. �,.. f Office Field Data Sheet Client:9L.l:_ .._I.ocation.WOp.Lr �,[�C Projecttf:j.µa.� Name and Affiliation (Sampler(s): R M g Pki e- Field Data Sheet Review: Name and Affiliation (Inspector): N //a tlikilP Date: Well Information 4 -7-q -w> Well ID: _.. M W - 1 Well Locked: YES NO / Flushmount ) Well Diameter: _ Total Well Depth;: 8._q9,_ft Static Water Level:A O I ft Height of Water Column_ i'13'___it Construction: PV Steel/Stainless Steel) Multi Factor*:0t16� ["(Radhrx/12)2x3.14x7.48j Casing Volume: 3,1 gallons Cal.3 Volumes: �i . `i r$ gallons Pump Intake: ° It 1A1,Z4-;"e VF SA A doLi By. Q G Puree Information Date Purged:_/ jL/ 2.:� _ Start :.__(2.25 Finish: 142.5 Purge Rate: IOo N1 /,A . Purging Method. %r:6 t I+ c p in ,A? Total Volume Purged: Sampling Information Date Collected:- Time Collected: 1410 (am pen) �( Sampling Equipment Used: ?0664-WC 'y r p Instrument ID: Y5r o 5 G v /- Pw 6o611 Bottle Type Preservation Analysis Required M or^L CIe.� (o1� _ H_L L_.. 1-ZSo r t tat+;( HNoi NcAei,:L- Le-f•-K Field Measurements/Observations Sample Temp ("q: _ II _, -4__'l'ime: 0 T'urbidity (mu): S Z Time: Diss Oxy (mg/L): 'Time; Fe 2+ mg/L: 5: Time: Specific Cond. (uS): 6a dTime: Res. Cl Sample pI-] (s u ): _..-..�:.� Time:._.._ Odor: _ 1Nw 5 1-Y - _._ Thne: 14 3 0 ReDox (MY): 11 . O Time: Appearance: 6I..L19 Time: ReDox (EH value):YSl proPlus +200mV 16 Q O Other: Time: General/Weather Observations: Temp. 57 (°F) Wind O—S (mph) Sampler Signature: R y s A b i Date: Stabilization Test Time Temp, Diss Oxy. Spec' Cond. pld (s.u.) ReDox Turbidity Volume renlWater Other Purged a (C) (mg/L) ( ) (mV) (ntu) (gallonlevel (it)L2 I,0 b 3 z6,7 t,8 50q:5� z ,7 4t. 504.5�1�23 i. -q � 2D� 17, 7 DO 1140 i� �j 15010 ;off i2 �}-i 9: la= I 2aoo S 1-1!c3Clio Af%ityttcs?t ° Document Name: Field Data Sbeet Doi unient Issued: March 8, 2019 Page 2of ;4 Document Number: Issueing Authority:: j F-CAR-FLD-001.rev.03 Pace Huntersville Quality Office. Client: 9 L E Location: W eo�c in{ N ( Project: Ru.r.(,, to, =Amave-I-F sip Aer-2o22 WelliD: /utW 9 1 Reviewed. Date and By:. Stabilization Test '{ -2 1' 2a GC C- Well Diameter I'lultiplfeatimt Factor' 1 O.0408 1.2 0.0918 1.625 0.10$0 2 0.1630 3 0.3670' 4 0.6530 6 1.4680 a 2,61:00 Time Purged Pur g Temp. � (, 0 DissOxy. (mg/W Spec. Cond. (us) pH (s.w) ReDox (mV} Turbidity (ntu) Volume Removed (gallons mis) circle one Waterieuel' (ft) Other rzS 14; t3 bcjq I I h, 4 ba i- q 1'4,4q 91 b4 y .7, 114,4 4aoQ i25 35 14. 0.0 24, SoO� -7.31 R 14.b o. a _3 aS.Z 600,0 7.bS t3"3 .S 0 bq7 —1.8 163 7000 7,10 1) 15.7 0,3 6c'8 19,5 --14.6 Z5.5 $.6$ 13 ►c;.Z o,3 70( _ b- -101 0 2A. 1 g000 6,15 14o 15,2 0,3 16117 b.6 1 �2L4.4 2'1.2 ll0000 9.ki 106 .0 03 6A-2 6.L --30.0 2S.0 11o00 9,9g I tsx 1430 v4 ``30.3 "2.5.2 IiOoo 9,63 So TP JRJ, a i\; r5 nw rG r-4er 9 oc( pate Issued: March 8, 201-9' Document Nome: Field data Sheet Pa e:: 1 of '2- 11-14 alceAi7alytical Issuing. Authority: Pace Huntersville Quality' ! t Document Number F-CAR-rLD-001-rev:¢3 Office Name and Affiliation (Sampler(s): MER - Pkc 2 Name and Affiliation (Inspector): 1J Pf Well Information Well ID: Mw - 3- Well Locked: Well Diameter:2t. Construction: Total Well Depth: ), a•1 it Static Water Level: It Height of Water Column: (D g ft oject#: 13"^to,6e Co. Ci,5J L F 5A A',,r, 20 22- �Field Data Sheet Review: Datee., L112A 12.7- Multi Factor*: 011 b 3 Casing Volume: 1 o,S IS gallons Cai.3volumes; 3l•11, gallons Pump Intake: ft 7481 Bypun Purge Information ML Date Purged:__�A_/�1_:/').:I_ Start: 1 2 Finish: t S o 0 Purge Rate: i -L0 levt`h Purging Method's rn �o v 50o v. Total Volume Purged: 2 (a2o0 (gallons/r t s/L) Sampling Information Date Collected: ja-1 /' Time Collected; Sampling Equipment Used: Meta Movtsoo Instrument ID: N S 1 ti2( i l Vw I S k (o Brittle Type Preservation Analysis Required 1 x Z50,1, (lust(- 1 r( 0 M 3x An %t- 05s H0 V00 Field Measurements/Obs_ervations Sample Temp (oC):. (6.3 Time: 15rO 5 Turbidity (ntu): ! Time: t S o S' Diss Oxy (mg/L}: . S Time: 190,5 "� Fe 2+ mg/L: 7v ® Time: l So 5 Specific Cond. (uS): 13 I.0 Time: 1 $ t3 Res. CI (mg/L)/(µg/L):— —Time- Sample pH (s.u.): _ l , Time: i S O S Odor: -- --_-___—Ai � Tone: -- (SOS ReDox (mV): Time: (�©5 Appearance: C I e 4, Tinie: ReDox (EH value):YSI ProPlus +200mV 19.5. 5 Other: Time: General/Weather Observations:' (pim /cloudy/rainy) Temp., -I O (°F) Wind 3 (r Sampler Signature: Date: Time Temp. Diss Oxy. Spec Cond. pli(s.u.) ReDox Turbidity Volume. rernov Water Other Purged (L) (mg/ (us) (mV) {ntu) (gallons f j bevel (ft) L 123-0 lu .3 Z 5 3ti•0 L, 1, 4-7.I All - LP (e0C-> 109.25 v E VU-3 2..5 3`1•0 (, t ui. Z `i9 •fL — `_" — 1255 1l•5 D,`i 13`1.• L" �1k. ( 7o.`t 1 Zoo .08.40 _rate i3o5 (U.3 LT 1135,2.1 (-1 4`l i Sis,S 3Z®c� 1D,10 I- 13ZtV Ile.`1 [.-1 I 13'1[1U I U-t 5y rye 1 (e2o0 13.15 1— ' ceArkilylict�l Document Name: Field Data Sheet Document Issued: March S; 2019 Page3of 'L _r Document Number: Issueinb Authority; + F-CAR-FLD 001.rev.03 Pace Huntersville Quality Office Client: tS LE Location: As L ty" kk e' N (-- Project: B V mLu uhk e Co. L 1= SA ACI . Zo 2'L Well ID: MI^/ a Reviewed Date and By: cilyi�y ALI Stabilization Test 4tt2`i12-2 CAB I•Vell t?iameter Multiplication Factor" 1 d.-0408 1.2 0.0919 1.625 0-1030 2 0.1630 3 0.3670 4 0.6330 6 1.4680 s 2:6100 Time Purged Temp. (QC) Di ss Oxy. (mg/L) Spec. Cord. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/ s/L) circle one Water level' (ft) Other 1 330 1u,-1 I u 1)1.3 Le I 1 su.co 38,1 TS2-0c> r, 0 -- 1';40 Ita.q i.l 134,1 (.9.I >7.4 -30.3if) 2(30 1 11&,-10 - 1350 1-1,-L t•l0 13i.2 (o.t 53.9 :Ku 122..00 118.I0 lyoo l-1.1 1,U 133.d Le-1 SS.S 3o.1 0-ec av to '[1,ro tti I410 11•a a.I 133.E 1�.1 s3.Z al.g ILo2oo tZ2.l j - 14ao FI-5 a.o 133.3 U11 53,1 131l 19200 12.4.3`1 - 1430 111 11 131-1 LP•t 139.2 13.E 20200 I ZLy.-io I435 1a.1 I,1 133.4 10.1 31.M k 7 'T 112-00 12UeUc) 14yV 1$,0 1.-1 133,5 Co.t 22.4 13.Z 22Zo0 1ZL,50 1445 I 1$,0 I.g 131A•t Uk 10.E it.3 7-3Zoo T2;74L) IM5D Ig.M M.9 ('e'l 3.X 1Z.3 �4700 [Z1y,3C I'A55 talk 1•U 13M.1 (r.l -3.D to. a. 25zoo 12U.2 -) 15-00 t8.3 1•L9 134.1 (..0•1 -415 Jua00 illu.ov - Document Name: Field data Sheet Date lssued: Mareh S, 2(r19 I / eNralytiCa(' pagin Hu Document Number. F-CAR-S(.q-0OS-rev.oS �µ"tg Aµthortty:Pace -Htmtersville Quality Office Field Data Sheet Name and Affiliation (Sampler(s): VL6-. L)1 Aea Name and Affiliation (Inspector): 2 �J Al Well Inf�orm�ati Well Ip WN 3 Well Locked: Well Diameter: oZ Construction: Total WellDepth: As.t�" t Static Water Level: �y �� ft Height of WaterColumn:)0_1i It (Field Data Sheet Review: Date,. M act r1 Multi Factor*: •(,p 63 [•(Radius/12)2x3.14x7.481 Casing Volume: 3. 3 c7 gallons Cal. 3 Volumes; GI ct 0 gallons Pump Intake: ft -.Ltele"k By: puree Information DatePurged:_,�--/ 1i / 22 Start: 11✓ i Finish: 111v Purge Bate: 90". N- Purging Method: lljVJJ-%r Pii� Total Volume Purged: lacx7 _ (gallons/@l /L) Sampling Information Date Collected: ti / li /21, Time Collected:: I I S 6/pm) Sampling Equipment Used:&wa&r NAM instrument ID: j S'L -0033`'1 1 j PW d 6cxr? Bottle Type Preservation Analysis Required -1somt_ 01U05 _ AP? z - �.LIL)nL 4�t►tct u l Jew 3-°10� 1. vwj1 iiU I ,4i -I) field Measurements/Observations Sample Temp (°C): lg•L Time: 02T Turbidity intur 3•t3 Time: 1125 Diss Oxy (mg/L): N.$ Time: IIK Fe 2+ mg/L: 11) Time: 1125 Specific Cond. (uS): 1111N Time: IIK Res. CI (ug/L)/(ltg/L): rune: Sample pl-1(s u.): _ Time: t IX Odor: _ _A&- Time: _ 1125 ReDox (mV): J5',3 Time: 1lx Appearance: ReDox (EH value):YSI ProPlus +2QOanV 1 i'1 4 Other: — Time: — Temp. GS (°F) Wind -3 (mph) Sampler Signature: Date:. 027i2Z Stabilization Test Spec. Volume Time Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed WaterAmer Purged (mg/l,) (uS) (mV) (ntu) (gallons/ 11 / - level (ft) kemp L Iiluee,, 13.L� G 4 ti 2•� &�C3 �s,r15 — 112� 15- N.� IZiI ta•� 3N.et 3•U I S.r1S - eArkaIyrtoal' i Document Nome: Field data Sheet Date Issued: -Maxch S, 2019 Paget. -of Document Number: F47AR-FID-001-rev.03 Issuing Authority: Pace Iitmtenville Quality Office Client -6Lt Locatior Name and Affiliation (Sampler(s) 6-4' lj 6LM - (JgUL- Field Data Sheet Review: Name and Affiliation (Inspector): hwf\A cl Well Information ` l Well Well ID: w " YE Date:. n4lYtl�a Locked: / NO /FI"ushmount )' ti Well Diameter: Construction: ('/Steel/Stainless Steel) Total Well Depth: • Z S ft Multi Factor*; � i �3 r((R7adtue/12)2x3A4x7g8] Static Water Level: 7 2 ' 03 ft Casing Volume: •� I gallons Height of Water Column: z ft Cal. 3 VoIumes `0' ' 3 I gallons Pump Intake: 7 !2 e> It Puree Information Date Purged: 1? / 3 i Start Finish: /��? ��qq�� Purge Rate: ° n li'--`--, Purging Method: Yin .` o d-�'\ Total Volume Purged: 3 D D U (gallons n�4 s�jl,) SamulingInformation Date Collected: " /1/ 2-2 Tune Collected: 1�; 7i/ (am/gm Sampling Equipment Used:-1�151`1W1 instrumentID:7 �Slli -0i'd -#035f Bottle Type Preservation Analysis Required al wdo rn 3 Ku "A1 e,� hlc Vae - 3—Yurtc CL li-Y 1, Field Meagurements/Observations / Sample Temp Cq: —IL-1—Time.-al' , lzly Turbidity (ntu) Time; / �l Diss Oxy (mg/L): ® 3 Time: l LI `q Fe 2+ mg/L: a T me: ' Specific Cond: (uS): 9 6 Time: 12,1 Y Res. C1(mg/L)/(µg/L): A Lime: Sample pH (s u): t Time: 1Odor:— .— Time: �__ ReDox(mV): a .L Time: dl I Appearance. <<�+i Tune: �f ReDox (EH value)NSI ProPlus +200mV Other: Time: Sampler Signature Stabilization Test ., - z /- 2_'2 Wind t, (mph) Spec. Vo me Time Temp. a Diss Oxy. Cond. pH (s.u.) ReDox Turbidity remove Water Other Purged (C) (mg/L) (u5) (mV) (ntu) (gallons: % level (ft) L .5 51 ,T mdE z t,-P l .l o, s '7 Cq- ,G ILUy 0 3 960 6,( 011-/ / zG 1ui (a,C. 0-3 v G,, D 3noo 7x.zs, Document Name: Held data Sfieet Date Issued: March &i 2019 w>aryrrear' Ira e: a of Document Numhar. F-CAR-FL.F1-001-reu.03 Issuing Authority: Pace Hudofit!Ile {juality Office Name and Affiliation (Sampler(s)•&==' Name'and Affiliation (lnspector}:.- well information nn Well ID: f\kW y Well Diameter: al Total Well Depth: 1 0 ft Static WaterLevel: % ft Height of Water Column: �' ) 3 ft Fi d Dat She e Lnratinm 1,LoV i v ti PrM4,*fi. )ti11P0 L AI Field Data Sheet Review: Date: I Well Locked: ( / NO / F1"ushmount J' Construction: Rb/Steel/StalnlessSteel) Multi Factor*:I� [*(Radius/12)2x114x7481 Casing Volumes 1,33 gallons Cal. 3 voIumesi 3 . q q gallons Pump Intake: .7 yt, S O ft At^ BY: Purge In€onnatian / �% f Start: 'Id Finish: 0 5 b Purge Rate: /0 0 Date Purged: `f Purging Method, aevTotal volume Purged: 5f) 0� (gallons; m/L) Sampling Information Date Collected: Li / j7/ 2 a Time Collected: � U � 1 (a/pm)' Sampling Equipment Used: � l G p a�•l 4 Instrument ID: ,r n %FL,) 4,0355 Bottle Type Preservation Analysis Required '160 kAL I ati� N n%c/;7 1 -- qV -v,L � AC` �- ,,-uu vic � 14« leg-_)� Field Measurements/Observations Sample Temp (°C);/Time: f o b I _Turbidity (ntu): 0, 6 Time: / 0 b 1 piss Oxy (mg/L): 0 1 e� Time: / O % Fe 2+mg/L: 71 V Time: U o J Specific Bond' (uS): % 2 3 Time: C u 0 Res. Cl (iig/L)((I!`g/L): Time: — Sample Hsu.: tO' t Time: p ( } -- V f Odor:=�� r ' — --� _ Time:. / d �' / u ReDox (mv)i 3 / Time: J ofJ / Appearance CJYciL Time: ReDox (EH value):YSI ProPlus +200mV / z • Other: Time: General/Weather Observations: Sampler Signature Stabilization Test ),7• Z2— Wind I? (mph) Spec, Volume Time Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged a (C) (mg/L), (US)(mV), (mu) (gallons/ rl / level (ft) L 03 t l ® �o (7 (8 i J 1 i(. G i C(1 La C• P j SNP 15,E i?,o f➢t7 �,� �y.G �� — i,«3 UG{1 i5.1 i,4 i,ga 61I 0�51 i ).t 0.5 71ed t, I —3y,& 0.7 r e•v �. it/y D`iiz�to -t5,o lP.y (LL tart sL<•c, 016 as°u &Y,17 �Oe a cat,' IJucumnnR Nam: Field data Sheet Date Issued: March &, 2019 Pop: I oft [)ocumenR Number: F-CAR-PL.I3401-ray.03 Issuing Authoniy; Pace HsusCeeavillaQualny Office Field Data Sheet al aeon: Jfc4w ll N ( Project It: �ce�-ia¢ (' 1 Name and Affiliation (Sampler(.): I yllmu l�.-yG.--'ate. Field Data Sheet Review: -,;?A; Nameand Affiliation (Inspector), /fit 17' Z2 Well Information Date LA-�, -� 2 Weil ID: ldW - 5 Well Locked: { 16 / NO / Flushmount ) Well Diameter: Construction: (V�Z /Steel/Stainless Steel) Total Well Depth: Et%°� Multi Factor-:Q -KA ["(Radius/12)2x3:14x7.481 Static Water Level: 9�0 • Cb ft Casing Volume; /)- 8` gallons HeightofWater Columni 3o' ft Cal, 3 Volumes-, P4 G J gallons Pump intake: r 7� ft Puree -Information 6_- G_ By: Date Purged: `I / IA / 11 start: 1' 05 Finish: 1 5 Purge Rafe: 1 ^L N vs Purging Methods &JAu- PLA� Total Volume Purged: (gallons/Q)/L) SamplingInformation Date Collected: 9 / 13/ Yj- Time Collected;: 1330 (anr/ Sampling Equipment Used: VA_4,,U r Instrument ID: ` 'SI k O3bM i T�i O GO r3 Bottle Type Preservation Analysis Required 1-1S0n,l �1a t c lirUO P^0-A``1 3 `i17„L b PIC( � �IoL l_yy by{S ) 1C� iI G -1) Field Measurements/Observations SampleTempCC): 1(1.) Time: 1330 __�Turbidity(ntu); 1 Time: 133c' DissOxy(mg/L): Time: 1?i0 Fe2+mg/ L Time: 137u Specific Cond. (us): ISMS Time: )330 Res. Ct(1'ng/L)/(µg/L), Time - Sample pH. (s:tt): (4-4 --_ _ Time: 13'50 ReDox(mV): -Q,(a Time:Iz,30 Appearance: r-tw` Time: i33o ReDox (EH value)NSI ProPlus +200mV I e I `I Other: _ Time: — Temp.-70 (°F) Wind � (mph) Sampler Signature Stabilization Test Spec Volume Time Temp. Diss Oxy. Cond. pH (s.u.) dity removed Water Other Purged n (C) (nrg/L), (US) ) (gallons.(d / L level (ft) (t,tD IW.c7 $•`I IG°!c G• iii l(� 3•Sv 1h 9,c� IG 1 6.2 Cx> 53.`li G.3 3i'X? i,,3 voI 5y.a H)'�Ix Document Name: Field data Sheet Date Issued: March &, 2g14 eAira�a,ll, Page: Iof� Document Number. F-CAR-FI.D-00t-revA3 1ssumg Authority: PaceHemtenvil%Quality Office Field Data Sheet Gient:_ G Location: kauAe- uc Proiect#, faAmcu--Ax (_ti C(osaA L(- Name and Affiliation (Sampler(s): • L- A k"r Pew Field Data Sheet Review: Seen Name and Affiliation (Inspector). W1 q - z7 • zZ Well Information Date: By:� opt (1 `h`J Well ID: MW - Well Locked: (` / NO / Flushmount ) Well Diameter: ) Construction: /Steel/Stainless Steel) Total Well Depth: 1-11•too ft multi Factor*t C7•��3 [+(Radius/12)20.14x7.481 Static Water Level: a00 ft Casing Volume: �'�a gallons Height of Water Column: `11.b7 ft Cal, 3 VoIumes; i gallons Pump lntake.L' 3A ft Purge Information Date Purged: CI—/ 1 / 31-2- Start: N q Finish: t5o Purge Rate: 1 S O r.L' ✓"Ih Purging Method: Ruibh.W Total Volume Purged: 1000 (gallons/ 1&/L) Sampling Information Date Collected: cl / 1}/' as Time Collected: 1610 (am/0, Sampling Equipment Used: Instrument ID: ! 7T d U 3� I ,i nv f:1 wc/-' � t Bottle Type Preservation Analysis Required 3-40,,A- 4, i-tct VUL 3� NALA Field Measurements/Observations Sample Temp (CC); I $ • 3 Time:. I S I U Turbidity (ntu); l , 1 Tune: 1510 Diss Oxy (mg/L): 5.0 Time: 1 S 10 Fe 2+ mg/Li )10 Time: 1 SI c) Specific Cond. (uS): i 4 45 Time: I S 10 Res. Cl (mg/L)f(ltg/L): - `rime: Sample pH (s.u.): G>•I _ _Timer 14;10 Odor:_ Tune: j'; ru ReDox (mV); - 11.\ Time: 1510 _/_V_'_t Appearance: CIE,-- Time: ISIU ReDox (EH value):YST ProPlus +200mV ISI `1 Other: Time: -" Temp. 70(°F) WindS_(mph) Sampler Signature Stabilization Test Spec. Volume Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other (mg/I� (on (mV) (ntu) (gallons/ fi��/ level (ft) L Lo)� ISIG 6.a Q).H i•1- }S� a.sy-0. i.� , G I� 31 GI _o c:; 1 ,G 1 I(5 6-1 -1N•5 I.S .Document Nance; Field data Sheet Date Issued: Mard.B, 2019 page.,, 9 off BArk7lyliCa!- Issuing Authority: Pace Huntersvflte Quality �. [)ocument Number; F-CAR-EL17-001-rev.IXi Office eld Data Sheet QQ Client: Locaflon: 5 `(� ^) Project#:I�inC)xN �.Clo`� Lf` f) C 2Z Name and Affiliation (Sampler(s): 6-LG A Lm - fc c, t Field Data Sheet Review; Sea ;1 Name and Affiliation (Inspector): >tiJkti Date: Lih71;"7_ B : *10 Well Information 41 aco �1 y I -CS/ Well III: M U _ 6 -- i 9 2 Well Locked: Y E / NO / Flushmount) Well Diameter: Construction: Q/Steel/Staff -dess Steel) Total Well Depth: Multi Factor' O'/o ((Radius/1232x3.14x .tsl Static Water Level: Casing Volumes r�y gallons Height of Water Columns' �+ O� ft Cal. 3 Volumes; gE�j � g ;gallons Pump intakes g ` 2 n7 ff Purge Information u 1 Date Purged:�_/ �� / BIZ` Start: 1 C 03 Finish: / Purge Rate:L/CI � A' Purging Method: - r. L 5 � 4_``�' � L Total Volume Purged: J SV 0 (gallons/Q1' / L) Sampling Information Date Collected: `Y /47 /2-L Time Collected: 3/ (am/& Sampling, Equipment Used: t i J�o H: C InstrumentID: tt �-*02e'3 'I -( 035� Bottle Type Preservation Analysis Required tc,;;o 1 1CL 0c 7✓- L (e,,0,o HCL Field Measurements/Observations Sample Temp (eC): �� Time:. 2 �� Turbidity (ntu); © e Time: Y20 l� Diss Oxy (mg/L): 7 Time: / �-3 Fe 2+ mg/L: Time: Specific Coed. (uS): tyy i q Time: l �2 3 Res. Cl (mg/L)/(itg/L), ' '- Iime Sample pH (sm.): _. Time:. / V Z3 Odor:_VLG-�'lA , Time:.. ReDox (mV): _ n / Time: / Y 2-3 Appearance. me: V2_3 ReDox (EH value):YSI ProPlus+200mV / d J.. Other: Time: Sampler Signature Stabilization Test y - 27 - Spec. Volume Time Purged Temp. (eC) Digs Oxy. (mg/I.) Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) removed (gallons ml Water level (ft) Other (us) L I t) `/yr. 7.3 -z I Dmunlent Name: Field data Sheet bate Issued: March 8, 2019' -0G@AR<7(yhC.7l Page: 1 of I Document Number F CAR-Pl.b-001-rnv:03 Issuing Authority: Pam Htuuersville Quality j Office Field Data Sheet Name and Affiliation (Sampler(s)t iz tit t Pa cs Name and Affiliation (Inspector): N I f•F Well Information Well lD; 'A W -% Well Diameter: (\ Total Well Depth: 2A.43 ft Static Water Level; ft Height of Water Column: °• h3 ft Well Locked: 1, L P S A, Apr. 2^kt !ld Data Sheet Review: Dare: � -2� 2Z By: C C Cr Construction: PVC p teet/Stainless Steel) Multi Factor*: 0.10 (([;thus/12)2 x 3.14 x 7,481 Casing Volume: 1, t( gallons Cal, 3 Volumes: 3.3 2. gallons Pump Intake: ^ 27 ft Purpe Information DatePurged:I_/V�/ 27- Start: Finish: 10Purge Rate: 8omi3min Purging Method:_ 8 -0 —de—If-Amp Total Volume Purged: 7_n GID (gallons n_,L�L) Sampling Information Date Collected: 4 /17/_-1 Time Collected:_)tea._._.._ (am In) Sampling Equipment Used; 00ced e r P u IA P InstrumentID: f1 056°I / T Yt✓� `5 L(__ Bottle Type 3-N0AL L . $(at5 Field Measurements/Observations Preservation hoo3 Analysis Required NI t _VR f..................... NI APi�T AV:t2J ) Sample Temp ('C): Time:ja_10. ........ --Turbidity (ntu): G •'A Time: i 02 Diss Oxy (mg/L): 7 . Thne., Fe 2+ mg/L: J. 5 Time: ) Specific Cond. (uS); Z20. q Time: Res. CI (mg/L)/(µg/L): Tine:. Sample pFI (s.u.): (_� . 7 Time: Odor:N o AP _ Tirne:.,,10'2 ReDox (mV): 1.t G . 7 Time: Appearance f Pa i 'Time: ReDox (EH value):YSI ProPlus +200mV Z 4Z _j Other: Time: Temp.(°F) Wind S-I'J (mph) Sampler Signature: _Date: 4 /Z>/2? _ Stabilization Test Sped. Volume Time Temp, Diss Oxy, Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (e C) (mg/L) (us) (nnV) (ntu) (gallons. mis level (ft) L R ,5 51 '7 S 4 (fog 7M I) Lk 14.5 I. 19,1.5 5. 542 16, 4 n10, 22.-1, Dock f 3 `' 5•' 4�f.• b, � 3o�J Z toy S1 5:7 419,f 7,2, j2o0 22, g t� n �. D19 2;io,7 5.8 u8-3 6.9 1iboa 2 , s615 1y.5 0.8 221.0 5,j 48 7 7.6 2,000 z3,03 Document Name: Field data Sheet Bate Issued: March 8, 2019 ,+� Page: I of I Document Number: @CAR-CAR-0Ol-rcv.03 Issuing Authority: Pace Huntersville Quality. i Office Name and Affiliation Name and Affiliation Well lnfortnatian Well ID: AAA - Well Diameter: cZ t n Total Well Depth: G, �� Et Static Water Level:�£t Height of Water Column: V, Z 99ft ion;..11Gv �` e _, CiProject #ZitD C ci✓'y De cC, Field Data Sheet Review: (0 22 0 6- Date: , lv a a By: M C-2 Well Locked: ( / NO / Flushmount ) Construction: PV /Steel/Stainless Steel) Multl Factor*: G� t•(aadius/12)2 x 3;1q x 7.481 Casing Volume: 3. 7/ gallons Cal.3 Volumes: ' w/ :gallons Pump Intake: 95, as ft Purge Information 1 2 / 0 Date Purged: f J a S / -Start :_115 S Finish: 41519& Purge Rate: / 0 1 yrq F �va� z Purging Method;_ Pe dlt Total Volume Purged: 15C3C1 (gallons/oil /L) Sarn lin Information Date Collected: G / S/ �2 Time Collected:_l�5 -,-_ (am/p) Sampling Equipment Used: �2 P, • Instrument ID:_ VS.9iTI 7-Alt_�O a 3 Bottle Type Preservation Analysis Required l k 250 fi� f(/LC�3 ale Field Measurements/Observations Sample Temp(eC):- 9.6Time:_Turbidity(ntu):_.Q ,..._..., Time: f2IS Diss Oxy (mg/L): 2 a el Time. Fe 2+ mg/L: /I// 0 Time: t Specific Cond• (uS): S Time: Res. Cl (mg/L)/(Itg/L): � 'rune: Sam le pH. s.u.): Time:. Odor:�p Time:._�S.-_ ReDox (mV); 1 f • (o Time: Appearance: e Ie4 r 'rime: ReDox (EH value):YSI ProPlus +200n1V 3 c t, Other: Timer Spec. Volume Time Temp. Ta Diss Oxy. Cos Conti. pH (s.tt.) ReDox Turbidity remove Water other Purged (C) (mg/1.) (unt (mV) (ntu) (gallons m / level (ft) L DO ` 19.5 3� 6 0.0 0 5d& 7, 8-3 536,5 6 -C U, 3 p. 4? rqr 6 c9, I— S30• 6.(6 G� Document Name: Field data Sheet Date Issued: March 8, 2019 I / COAMllytiedf- Page: .Iofl, DMURrent Number. F-CAR-Ff.D-0Q1-rev.03 lssuiag.Authority: Pace Rmtersville Quality I / - Office V U—CC C' — k`5`P "Ieid Data Sheet Client: oeation: Project #:Li N( �G e C N Skk Name and Affiliation (Sampler(s): Field Data Sheet Review; G C G �'Ps , ZZ Name and Affiliation (Inspector)t D�. b • M C- YZ Well Information ate: By:/ Well ID Yd (a p- j 2' ^ U �l Well Locked: ( J NO / Flushmount ) Well Diameter: 2 Construction: ( V JSteel/Stainless Steel,) Total Well Depth; 33 7 it Multi Factor*: [r(Radius/12)2x3.14x4.48] Static Water Level:13 1 15 ft Casing Volume: _j 7-Y �_�_ gallons Height of Water C91umn: ©0 ft Cal. 3 Volumes�e�%_ S " :gallons Pump Intake; � � /=—it Purge In€onnation Date Purged: / .122 Start:__ Finish: r��,�' Purge Rate: i Purging Method P 7° r ( �i f(n,�^� Total Volume Purged: o (gallons/e/L) Sampling Information Date Collected1___ _/25/ ,I ., Time Collected; /pm) Sampling' Equipment Used:4P_, (S f Q If C. Instrument lD: 6 � P w Ica n yy Bottt(l—�e Type 1� 1l,� �� /Prreeservation Analysis Required Required ?. f t cl 0t 1- I✓ i a i s �A G L. A � ro � , Field Measurements/Observations Sample Temp (aC): 1 5 Time: 3 ._ Turbidity (ntu): � ° Time: Im_ Diss Oxy (mg/L): D 1 ] Time: (i 17 Fe 2+ mg/[.L 49 ----Time. r l Specific Cond. (uS); Time: V1, f 3 fi _Res. Cl (mg/L)&g/L): .� 'time: r'• I Sample pH (s.u.): J,1�Time: 3 Odor:_— __._,, ReDox (mV); 2 Time: _ � _ Appearance 9 P 2C cj Time:_ _ ReDox (EH value):YSi ProPlus +20(JmV ' Il ik Other: Time: General/Weather Observations; /Gilllalt)/rinntty (rienrr} Tamn �l/ i°F} Giinrl�r� (r T Z. Stabilization Test Spec. Volume Time Temp. Tea Diss Oxy: Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (tng/L) (u5) (mV) (ntu) (gallons/ Is L level (ft) G 23 P"5 _ 3 �� z Z o ti ' Document Name: Document Issued: Match S, 2019 Field Data Sheet Pagelof a t7ceAr�2/ytic��, f Document Number: Issueing. Authority: F-CAR-FLD-00I.rev.03 Pace Huntemille Quality Office Client: Yit IA ./> in g Co ({A 1 �i Location: k-, 6Cl Project: � (A A C . 65 �d L H 5� Aft. WE M Reviewed Date and By: > - C • 2 L US, Stabilization Test S (v - 2 ?I Mc--12— t•Veli Diameter Multiplication factory 1 0.0403 1.2 0.0913 1,625 0.1030 2 01630 a 0.36;�0 4 0.6530 6 —� 1.4630 S 2.6100 Time Purged Temp.Diss o (Cj O xy. {mg/Lj Spec, Cond. (u5} pH (s.u.) ReDox (mV): Turbidity (ntu) Volume Removed (gaitonsfa/L) .circle one Water level (ltj Other !� p 3 2 2 i _ �z p Document Name Field data Sheet Date Issued: March S, 2019 a8eM7a(yfiaal Page, 7 of Wuurg Authority: Pace-HuntersvilleQualuy t Document Number F CAR-F•I.D-0OLrev.03 Office Name and Affiliation (Sampler(s);: IMI z5op✓, Name and Affiliation (Inspector): A114 Well Information Well ID: A 1. ✓ - 1 3 - 3 S Well Locked: Well Diameter: :Q , 0 Construction: (PV /Steel/Stainless Steel) Total Well Depth: y/00/p It Multi Factor* d.1G 3 [*(ttadius/12)2x3t14x7.4e1 Static Water Level: SG ft Casing Volume: 3 A6 gallons Height of Water Column, '-t 3,59 ft Cal, 3 Volumes: Ir'&/5 gallons be Co (Field Data Sheet Review; 5-b-zZ GtG- Date: 6. U , a a- By: ,, (:-A Pump Intake: 38• DO -t It Purge Information Date Purged: If / Start Finish:%G'-'0 Purge Rate:l005o 11 Purging Method: Per e Total Volume Purged: 3 SOO (gallons/6)I,) Sampling Information ate Collected: O Time Collected: �pin) �.--: (gym Sampling Equipment Used: rr Instrument ID.IIs 3�70 y��✓ & [� 5- - Bottle Type 3 �r � rass 1 '��So � nkslc Preservation R /vd3 Analysis Required A� n,,� _o91- A W Field Measurements/Observations °rf�`V lizx Fi Sam leTemP Time: _ Turbid:t3(ntu : d,/ Time; L — G Diss Oxy (mg/L): 3. 5 Time: Fe 2+ mg/L: —Tia": ' Specific Cond: (uS): Time: Res. CI (ing/L)/(µg/L): � 'rime: -� Sample pH(su.): _ Time: Odor:_... /VI'/__- Tune....(OSS._. ReDox (mV): _ O l Time: Appearance: G rime: ReDox (EH value):YSI ProPlus +200mV 5 G Other: Time: General/Weather Observations: Sampler Signature. - Stabilization Test Temp.Z(OF) Wind �2- (mph) 2 a/c( GF Spec' Volume Time Temp. ° Diss Oxy. Cond. pH (s.u.J ReDox Turbidity removed Water Other Purged (C)- (mgfL) (us) (mV) (ntu) (gallons/0`/ Tavel (ff) L 0 0 c/ 3,153 Go l 3. T /. 3 700 6,79-- C1 J9 17.`I .G lc".i oI 1025 176 4, O y .& G,/, i. o . 7q- 0-30 s5a. a33.7 / 00 IG 5 7. 3. k 3SO.3 Co .0 2elrd 10,11, 1aOa Document Name: Docmnent Issued: March 8, 2019. FI GB f(f 1cilyl f�rT l Field Data Sheet Page2ofZ Document Number: Issueing Authority: F-CAR-FI.D-001.rev.03 Pace Huntersviile. Quality Office Client: & ff, Location: _As hev,'I%P_ + /yG Project: 6 Ln nGO✓nbC CO. Old li Well ID: W- 13 ` 3 S Reviewed Date and By: '' 6 ZZ C-L6- StabiiizationTest 5--U-4-3- MC--✓z- t%reA Diameter 11Wtiphcation Factor" 1 0.0408 1.2 0:0918 1.625 0.1080 2 0.1630 3 0.3670 4 0.6530 6 1.4680 8 2,6100 Time Purged g Temp. ° 1 C) Diss Oxy. (mg/L) Spec. Cond. (us) pH (s.u.) ReDox (mV). Turbidity (ntu) Volume Removed (gallons I L). circle one Water level. (ft) Other 10 �. 3.6 3G 1.0 l.s d.$ ZSao io.7,? 1/5 3 1 3.6 1 D, 3000 G 3,.'5 3S 7 4 3Q 5 3 50� f / BfUhYFyI%CdIT -Document Name: Field data Sheet Date Issued: Match &, 2t?i9 P a e: 1 of I Document Number: F-CAR-FL6-0oi-rev.03 lasuhig Authordg. Pau-liuntersville4ualit OfFlce Name and Affiliation (Sampler(a);: (IL6--.1 Ate— N CQ Name and Affiliation (Inspector): liWlX Well Information Well ID; M W - ) 5 Well Locked: Well Diameter: a Total Well Depth: t' �' 7 U 'Et r Static Water Level: ft Height of Water Column:/a' 6 2ft !t JC Project# �13eueow�c Cu C)° 19 L%-,Arr- 2Z Field Data Sheet Review: Pti u Date: Construction: I'V// /Steel/Stainless Steel) Multi Factor''": 6'1V 3 r(Radi„us/12)2 x 114 x7,481 Casing Volume; gallons Cal. 3 Volumes. 5 ;gallons Pum Into 73 2-b ft By: Tf I P - . Purge tiara Date Purged: `/ / a7 ./ 12Start: ) SS Finish: Purge Rite: Purging Method: L rs�q I f' L Total Volume Purged: J �' (gallons6/L) Sampling Information Date Collected: L4 /-07/' 1 � Time Collected: � �' � 6 (am/� Sampling Equipment Used: 15 �ti I t < Instrument. l 5 t -rq, 'd3,56 Bottle Type Preservation Analysis Required HA1D3 '3 _ FLU v c cj ago 14( L VUx, Field Measurements/Observations +/ Sample Temp (aC); / Time: / "/-4' Turbidity(.ntu); Time: 1616 Diss Oxy (mg/L): 6, % Time /6 14, Fe 2+ mg/L; MAID "» Time: lzye Specific Cond. (uS); 61 t/3 Time: 6/� Res. Cl (mg/L)/(gg L): Time: Sample pH (s,u.): Ja' 3 Time: 1616 Odor:✓w� e Time:. �Z16_ ReDox (mV): 3G, 1 Time: 1616 Appearance: Tune:....�6�� ReDox (EH value);YSI ProPlus +200m.V / /s % Other: Time: Sampler Signature Stabilization Test Paz U Spec. Volume Time Temp. e Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (mg/L) (u5) (mV) (ntu) (gallons r s level (it) L u 13.E (o ui-; a,Z O, . () 6,56 ��,6' �' c�,� flu ia,1 jzti•• d. .— 4:5� .9 6.s/ 4,i35 /a z _3/•1,3 / i O S , o6 Document Name:Field ciakaSheet Date Issued: March a, Zing Page: I oft aCBAth?lyllC2i - Document Number. FCAR-FLD-0Ol-rev.IX3 Issuing Authority: Pace Huntersville Quality ..Office / Field Data Sheet _ Client:— L Location: by . V ° 5 Project #: &A c: � G G F 9' (tc kl u e- L- F S Ft Name and Affiliation(Sampler(s): P&ct Field Data Sheet Review: Af'P ','.,?Y Name and Affiliation (Inspector): �c. Date. - ' (0 • a By: ivl l Well Information wen ID: __w(/ ^- 'I ➢ -60 Well Locked: ( NO /-Flushmount ) Well Diameter: 7 �4 Construction: (i /Steel/Stainless Steel) Total Well Depth; It Multi Factor•: �i r(R daua/ l2)2 x 3 i� x z d8] Static Water I.eveh L� r 8 ft Casing Volume: _gallons Height of Water Column: 3 7 It Cal. 3 Volumes: 2 % gA , ns Pump lntake: ,� ft _ Purge Information 4.3 5 Date Purged:/ 2-1t ( L Z Start Finish: Purge Rate: i ©0 Purging Method:! Q` i 5 i Gl, (} t [Total Volume Purged: 2 iJ(> (gallons/ I>�1 /L) , Sampling Information Date Collected: _/2-3/2 2- Time Collected;__ (am/ t Sampling Equipment Used: 1,� 1�1 r lnstrumentID: � `13 �7C 21T V �v a �� Bottle Type Preservation Analysis Required L• '.V.i A I ci {�f.L. _ Tt UQ�,G j-A G L 14 5 xq fv� Field Measurements/Observations t, i '(ntu): 0 e Sample Temp (0q: Timed�[40__ Turbidity Time: Diss Oxy (mg/L): Cl o Time: 110 Fe 2+ mg/L: (1/ Time: L Specific Cond. (uS): _ Time: t(i Res. Cl (ii g/L)/(µg/L): --rime:' Samplepl-1 (s.u.): �t_ ___ Time: . �U"(uc" Odor:__ ReDox (mV): Time: t_y (..Y3:�AQAppearance: ( QEQ( ((� rime: ReDox (EH value)Nsl ProPlus +200mV a 6 _ Other: I Time: General/Weather Observations: Sampler Signature: --&kh StabilizationTest Spec.W Volume Time Temp. Diss Oxy. Cond. Turbidity removed WaterOther Purged (C) (mg/L) {u5)(ntu) (gallons/no/ level (ft) L 2I ,vr 77 J ti Le, Z(� ic?1�4 C11*7 �'Z6 6,R —1c0Fi dkZ z'66 z2,6L� f!' eArmlyfi'al • Document Name.- Field data Sheet: I Date Issued: Match 8, 2019 Page:. 1 of I Document Number: F-CAR-FL.D-001-rev.03 wing Authosity:.Pace Huntersville Quality Office I Name and Affiliation (Sampler(s): /1, Name and Affiliation (Inspector): ZWA Well Information Well ID: M L✓- I'7 - 13 7 Well Diameter: 9, o Totat Well Depth: 1 3'.7/, QO ft Static Water Level: o`t _L_ t a Height of Water Column: I I S-7rft Pure Information Date Purged: L /% / 2 Well Locked: Construction: �lr 4 >}p�, �2 ild Data Sheet Review:- 6.6 -1 -2- G-(. <_ Date: �. as By. /t-t(•-yL Steel) Multi Factor*:_® G3 ('"(Radius/12)2 x 3,14 x 7.481 Casing Volume: i &"', �7 gallons Cal.3 Volumes: -T. 0 Z gallons Pump Intake: 1 3 S 06ft qq ^ T L�j�. Start:( 3 G Finish: / /0V Purge i Purging Method:_ —A r, —,Total Volume Purged: U6 (gallons/ n�l /L) Sampling Information l Date Collected: �-( /�v/ --Z Time Collected: � (am Sampling Equipment Used: Per, . Instrument i (n v Zb Bottle Type G/ r"L \a65'— 77 M& A p 31%G rnl L' Preservation /-/ C / Hya 3 FIC( Analysis Required itP� vve q j Field Measurements Observations Sample Temp CC): (, Time:__L.L�0S_Turbidity (ntu): i a S Time: I l U Diss Oxy (mg/L): Time: Fe 2+ mg/L: A//0 Time: Specific Cond. (uS): Time: Res. CI (mg/L)/(lig/L): " 'rime: Sample p1-1 (s,u.): _._gyp' -/ --_ Time: ReDox (mV): t10•o Time: Appearance: L/e�O r 'Time: I ReDox (EH value):YSI ProPlus +200mV / 'I_C), 0 Other: Time: - - General/Weather /rainy) Temp. (r,' °/ ,(°F) Sampler Signature Stabilization Test Time Temp. Diss Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity Vo ume removed Water Other Purged (aC) (mg/L) (us) (mV) (ntu) (gallons/mis/ level (ft) L -aC 9.1 's -ie-lo 7,5 slco ai •`/3 <l 77LI 7-- W P 7�, :� a, 1 sa/� S 7. s51 c a ,; 73•.2 I ,' 660 .�13 l0 G 5a,p -1.14 -'79•T� Document Name: Meld data Sheet Late Issued: March 8, 2trt9 Page; 1 of 7, CBMrRly71CRl Document Number. F-CAR Pl.l7-OQl-rev.63 altty Issuing Authority: Pace Huntersville QuOffice -� I Field Data Sheet Client: R L C Loeallon:wcodr-'n�NL Project#:g.^ Name and Affiliation(Sampler(s): Field DataSheetReview; Name and Affiliation (Inspector):. it IN Date: HI.Lh la t z5 Well Information it .?2 Well ID: M\V _ ( % - 31 n Well Locked: ES NO / Flushmount ) Well Diameter: -L A Construction: PVC . teel/Stainless Steel) Total Well Depth: 3 (2. 2 y ft Static Water level: a ft Height: of Water Column:31�2 ft Multi Factor*: 910 [+(Radius/12)2 x3.14 x 7.481 Casing Volume: 5010 gallons Cal. S Volumes: 19 'b'A gallons, Pump Intake: '" 3 Dc ft t.r, SA A pr 2oz2 By: (;_(_ Cs Purge Information Date Purged: L4 / Ik f 2-2 Start: 1S15 Finish: )SSISS5 Purge hate: go µl4 t * l •� Purging Method: PQ:r,'J A--t, 6- FtkjAl' Total Volume Purged: 32D0 (gallon utls)) Sampling Information Date Collected:__/ 1� / 2 Z Time Collected _�� -_ (am Sampling Equipment Used: 4?e, ifo- I+ G C u�mstrumentID: YrT 056q J T PW 9 QLA Bottle Type Preservation 3-yoMi lteRialotf HLL ct3 kR6T��' Field Measurements/Observations Analysis Required N c A?,? T -Y9 J( _........ N ( Apy L Me+-i) Sample Temp ('C):. 1 -) Time:. / ®__Turbidlty(ntu):_ Tune: 6 Diss Oxy (mg f L): t-3 " 7 Time: Fe 2+ mg/L: N 0 Time: Specific Cond. (uS): 1 43- o Time: Res Cl (mg/L)/(gg/L: - Time: Sample pH (s.u.): �_y .. Tirne:. Odor:__. 1PTime: _6 ReDox (mV): — 25, O Tune: Appearance: 51.61paLY Time: Q ReDox (EH value):YSI ProPlus +200mV / 75. ,O Other: Time: — General/Weather Observations: p (sumry/ ou y rainy) Temp.(, 2 Cr) Windq=5 Sampler Signature:- RYo lg l�j —__Date: Ll�Z(,�ZZ Stabilization Test Spec` Volume Time Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purgers (¢C) (mg(G) (us)(mV) (krtu) (gzillotrs/nos/ ,level. (ft) L tau 157- 150.0 6.o 0:1 ll,d eq`to 27'3. z' tSLS 1 '& 8A _2, S.Roo 4 I 15i 1 '3 146.0 9, L4 I I'Z'0Q0 I 111 00. 5 1 914 J-7-05 111, I boo I S.'2.Qk Docuurent Name: Document Issued: March 8, 2019 u c'iCG'Atk7iyilCi7/ Field Data Sheet Page lol!Z Document Number: Issuemg Authority: F-CAR-FLD-001.rev.03 Pace HuntersVille Quality Office. Client: _B LE Location: '-veod1z4A, rlL Project: (i:cnc. Le, LF S A APr 202Z Well ID: _ MeV= fa' 3(� Reviewed Date and By: Stabilization Test t4Fell Diameter Multiplication Factor'' 1 0.0409 1.2 0.1918 1,623 0.1050 P 0.1630 3 0.3670 4 06530 6 1.4680 3 16100 Time Purged Temp. o (C) Diss Oxy. (m811) Spec. Cord. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume RemovedWater (gallons ml . circle one level (ft) Other IS49 S. Q . lq32 8,_ — 3 ZooQ S. ot i S 4S 0. 8 11-0.6%-S 11-9 Z4 00 b, S tS55 i5,� _ .0117 L( 3zoo .7) Document Name: Fluid data Sheet Date Issued: March,8, 2019 f Issuing Authority: Pare Huntersville Quality - "' ""OAna"1Cr11+ Document Number: F-CAR-FISJ=001-rev.Q$ Office Name and Affiliation (Sampler(s):�Q �4 Gi IW E NameandAffiliation (Inspector)-1 Well Information Well ID: _ M W ('K—�� 2�4 Well Diameter: 1 Total WelIDepth: C) it Static Water Levei r e g ft Height of Water Column;^ _ (!%ft eld Data Sheet Review: �5A,-iz Date: 51 U - DID - Well Locked: 'V / NO / Flushmount)' Construction: (I1�)/Steel/Stainless Steel) Multi Factor*:,CZ _ ('(Radius/12)2 x 3:14 x.7.481 Casing Volume: 11 6 f2 gallons Cal.3 Volumes; 3�, 7q gallons Pump Intake; _It --,�- 046 t'f'V , L � 5 ik By: M L� Purl+e Information ] 1 p Date Purged: Start: 2� Pin"rsli:-� 7 j-%� Purge Rate: 1 d 0 6M [ j jM fy1 Purging Method: P �� T j "rG } 6 C Total Volume Purged: ZQ(gallonsJl It L) SamplingInformation Date Collected: /2S/ 2 2, Time a Sampling Equipment Used: P e tr i S,� a (f LC - Bottle Type I X_ a mL I X Wsj im L. iI �,11 Prese {ACL, w)9,9Di) Field Measurements/Observations fl 7 Sample Temp (aC):_-M.(_�-._Time:�_(,._ls _Turbidity(ntu): Time: Diss Oxy (mg/L):_ . �Time: " Fe 2+ mg/L: yt V � "T me: i� 3 ( 11 Specific Coud: (uS): _.� Time �L Res, CI (mg/L)/()tg/L): time: Sample pi-1(s.u): Time: r ReDox (mV): e - Cp I Time: j'_3 L G Appearance: . C ° C, �j Time: ReDox(EHvalue):YSIProPlus+200mV 3.-, _Other: Time: Sampler Signature Stabilization Test W indO.(mph) Spec' Volume Time Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged u (C) (Mg/ (Usk (mV) (ntu) (gallons/ nls level (ft) L LI1 1'o 2 G - -600) ( ?j / C)T,tv Document Name: Mehl data Sheet Date Issued: March &, 2019 `1Ce`?rlc`1 t Pa e� 10(1 Document Number F CAR £•I.n-0Q1 mv.63 issuing Authority: Pace Huntersville Quality ' Office Name and Affiliation (Sampler(s): W/(-`9(5 - Name and Affiliation (Inspector): A/ + WeII Information Well ID: 14W -I q - -7 s Well Diameter: 9 i O Total Well Depth: �, ?,, o Z ft Static Water LeveL•�6 9£t Height of Water Column; &8u 3-3ft Well Locked: Construction: be co, o lci G F Field Data Sheet Review: C>_( 6- Date: 5.� a a By: mere EV / NO / Flushmount ) Multi Factor*: 0, 63 ((Radius/12)2 x 3.14 x 7.481 Casing Volume: l I • 61 gallons Cal, 3 Volumes: 3 3a qj gallons Pump Intake: % 6• d Ot ft Purge Information Date Purged: 1V f 9-5' f;�-Z Start: If 61 0 Finish: l qv .Purge Rate: /QD%r+zi-%I Purging Method:_ /�Br, Total Volume Purged: -�-000 (gallons mis L) Sampling Information Date Cohected:-U—/9--5J A--, Time Collecte _0 S._._ (am/0 Sampling Equipment Used: 19 El',.. Instrument ID: tl5ilf3 rpyy 70;3 Bottle Type 3,KIYOAG ,rasa ,wG 62Sy c 2� x `IGAZ 1� Field Measurements/Observations Sample Temp (eC):. �G, C� Time;, Diss Oxy (mg/L): 0 L Time: Specific C md. (uS): Time: Sample pl-i (s.u.): �p _ Time: ReDox(mV); Time: ReDox (EH value);YSI ProPlus +200mV_ General/Weather Sampler Signature Stabilization Test Preservation y03 Analysis Required /d/,,2 Turbidity (ntu): _D-5— Time; Fe 2+ mg/ L 5, Q Time: i Res. Cl ---Time: �/ S Appearance: AkI &A 5 pee%S 'rime: 1�2.; Other: Time: rainy) Temp..(°F) WindZ _(mph) Spec. Volume Time Temp. Diss Oxy: Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C) (mg/L) (us) (mV) (ntu) (gallons mis level (ft) L ,� O 5 -1a Fj a Scaa .8 7 �, 0.3 ,3 y a.c a 3 ,5 — 1,0 P- r � 7 . O 2- ro,3 =l .2 0, sow i 20• -3 1 —76.I 0.5 O Document Name: Field data Sheet Rate Wued: March g, 2N9 at:eAndiytica7 Page: 1 of 1. Document Number F-CAR-FID•11Q1-rev.03 loumgAuthority: Pace Huntersviille Quality t Office Field Data She CIient:y Location: h l -e KC1]�._ Name and Affiliation (Sampler(s): t±1VWaCV Field Data Sheet Review: J i Name and Affiliation (Inspector): G - � ' '2_2 L WeII Information �- Date: S. L,- d a By: M E e- Well ID: M(pI j11 Well Locked: ( J NO / Flushmount )' 2 Well Diameter: Construction: (g/Steel/Stainless Steel) Total Well Depth; Il e� 1G ft Multi Factor':03 tRaaius/12)2z3:140.4e] Static Water Level:_j(p t_ IA. If Casing Volume: I q gallons Height of Water Column; q 6' it Cal. 3 Volumes; _�qtj( gallons Pump Intake: i / "---it Purge Information _ DatePurged:�/ 1 ./ 2'u StartJ Y �FFinish _�_or)PurgeRate: 166 LsI'mo°a Purging Method: q, (}- i C Total Volume Purged: (gallons/gTX/L) SamplingInformation Date Collected: �l ,_/-- / r% Time Collected:_ �T (am/&) Sampling; Equipment Used: it S' � GC It' t C Instrument ID: Bottle Type Preservation Analysis Required 12�712-n �t6��I, 40,,'i. ?(—o U ( at 1E, Field Measurements/Observations Sample Temp (°C): aA.l_(___Time: I - Turbidity (ntu). Time; �-L— Diss Oxy (mg/L): G\Time. (t; Fe 2+ mg/ L: Time: 1 Specific Cond. (uS): _14,, 1;�Z, Time: �3 Res. CI (mg/L)/(Ttg/L): '� Tune: Time: Sample FT � f'__. ..__, ReDox (mV): ^ , ( Time: 1> Appearance: C 1'G Cb ( Time: ReDox (EH value):YST ProPlus+200mV- 1_%_ (_Other: Time: aranxucauun Text Sped. Volume. Time Temp. Diss Oxy. Cond. pH (s.u.) ReDox Turbidity removed Water Other Purged (C)e (mg/L) (us) (n1V) (ntu) (gaIIons/o/ level (it) L u.Z6,W 2 4u t 5 0 4 ( Dmunient Name. Field data Sheet pate Issued: March S, 2019 OCORnntytiCal Page: I of Document Number. P-CAR FI.IJ-061 rev.63. Issuing Authority: Pace Huntersville Quality' - Office Name and Affiliation Meld Data Sheet Review: cc, 6161 2 F Name and Affiliation (Inspector): /1//1S Date. 5 (� 1 a B P e ✓e Well Information y Well ID: /M W — " oZ Well Locked: ( E / NO / Plushruount } �— Well Diameter: oZ n Construction: (Steel/Staitlless Steel) Total Well Depth: a+ 3. It Multi Factor*:0.163 [•(Radius/12)2x3:14x7.481 Static Water Level: Jam. `/ Pt Casing Volume: ®�� gallons Height of Water Column:1S ft Cal. 3 Volumes: 3,? -3 gallons Pump Intake: o� e -0-1-1, ft Purge Information 44 5(&/;Zz Date Purged: N J / 0�2 Start:_ ��5 Finish: Purge Rate:..1190 16M n Ica Purging Method: p eti . Total Volume Purged: /SGO (gallons: lil I:) Sampling Information Date Collected.. q f 'rime Collected:_f_�__ _ (am/ to Sampling Equipment Used: PPS, , Z Instrument ID: s 3V?'6 3 Bottle Type Preservation Analysis Required 3 e/0ML He l .—AP v ('_ _..._. l r Zza lNo 3 '(z0t lza- & l S Field Measurementg6Dbservations Sample Temp (eC :.2 ®, 2 Time:. 2 I-- _Turbidity (mu): ` C Time: Diss Oxy (mg/L):=-,�a.z Time: Pe 2+ mg/L: 310 Time: �. SpecificCCn , (US):13e: H�tk�� 114511t Res. Cl (mg/L)/(itg/L): _—Time: (y' Sample s.u. h......Time: Odor---.. ReDox (mV): — 5 E. Time: Appearance: Clie! ✓ 'Time: ReDox (EH value):YSt ProPlus +200ni V I `T `1. O Other: _—'— Time: General/Weather Observations: Temp.. (7) Wind__5 (mph) Sampler Signature Stabilization Test bone. Volume Time Temp. n Diss Oxy: Cond. PH (s.u,) ReDox Turbidity removed Water Other Purged (C) (mg/L) (us) (mV) (ntu) (gallons( n / level (ft) L)�/ 1000 2a.[ 103G,c rS p 3A7C �t V 90.7 a ISM K- -5C.0 3, 1 - - / K 73,0 C,r 10jaQ 5W.c 1610 90.71 0 3�5rg1-1 757,S 15 Oe S Document Nome: Field data Sheet Date Issued: March &, 2Q19 dcBJUrF1IY60l/�17' - Page: 1of Dmument Number; F-CAR-FLD-001-rev.03 Issuing Authority: Pace Himtecsville'Quality r' I Office Field Data Sheet - Name and Affiliation (Sampler(s): 43 P W H AN/ AaC ID Name and Affiliation (Inspector): ' WeII Information WeII IDt(814-211!qp Well Diameter: `Z\ \. Total Well Depth: fl ti I f it Static Water Level: %I.ri 5ft * Height of Water Column;_ ( ft Well Locked: Construction: 'field Data Sheet Review: (j- (6.- -21 Date: 5. (rt . )-,i Multi Factor*: r(Rad;us/12)2x3:14x7.48l Casing Volume:.J_{ s� j L{ gallons Cal. 3 Volumes: (A-Z _r 2 gallons Pump Intake: Z 4-1— ft CG ZC� ft(fC (_1 $bf f-C B Purge In€ormation , Date Purged:-':(__,/ -LEJ �Z�Start:_.1_,Finish: in Purge Rate: �jQ�% L Purging Method: P -e L` V'� kit 1 ±" i G—Total Volume Purged: l 5 0 n (gallons/ nO/L) Sampling Information Date CoUected:_ 9__,/�/ Z72 Time Collected:_ULL ' _ (amJry) Sampling Equipment Used: p >p f I R I i'(C Instrument ID: V Sj= 1 ^ail P / ,r P Iel -2 3 Battle Type Preservation �1 2 hen (d cz (M r, n c(� r� i l S —6 C, L Analysis Required. AP f u�1Pt�?�. i OX � Field Measurements/Observations Sample Temp (aC): `?�Time:j 6.�_ Turbidity (ntu): _$� Time: Diss Oxy (mg/L): Z Time: IF Fe 2+ mg/L: n/' Time: . Specific Cond. (us): P Time: ry Jr Res. Cl (mg/L)n/(µg/L): ---' 'rime: Sample pH (s.u.): __ tp _._ _Time:_ C 0 (K Odor:_ ReDox (mV): _(_j 0 Time: 16 15 Appearance: rime: V 6 1 ReDox (EH value):YSI ProPlus.+2Q0mV_2__q,2j+.._._.Other: ` Time: (S(nn�/cloudy/rainy) Temp,7��.(°F) Wind_O-t m h) Sampler Signature:_Date: �� ( 7f . � / 2 7 _ Stabilization Test Diss Oxy (mg/I•) Spec. Cond. (uS) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume remove��d�n (gallons./ 14 L WaterOther level (ft) 6TimeTemp. 0 0 3 5 a --� o � Document Name: Piuld data Sheet Date Issued: March 8, 2019 Page: Ioft . BCCAnaty1lC,11- Issuing. Authority: Paace untersville QualitI t document Number., P-CAR-FLD--001-rev.M Office Name and Affiliation (Sampler(a): Field Data Sheet Review: Name and Affiliation (Inspector):: $- (e - 2Z Date: Q S to 1. � 22— Well Information Well ,ID: -- i A y Z ({ Well Locked: (to/ NO / Flashmount ) Well Diameter: Construction: (I y�t /Steel/Stainless Steel) 51 k/ k )'2 T(2z fl'F e r uccl stt, Llnczcfi ve. LF, y 6 ? By: U-f � Total Well Depth; -J_ E1J—ft Multi Factor*; l/ g (C (*(Radius/12)2 x 3.14x 7A8j Static Water Level; w 8 ft Casing Volume; 1'�_ g Ilons�) W 2 lIeightof Water Column; v ft Cal.3 Volumes: i 2 `i galIons Pump lntake; h it Puree Information Date Purged: _/ Start : Finish: � Purge Rate: Purging Method: 0- Total Volume Purged: t (gallons/mils/L) Sampling Information Date Collected;—' Time Collected: _ (am/pm) Sampling, Equipment Used: — f V Instrument ID: Bottle Type Preservation AnaLysis Required Field Measurements/Observations Sam (°C): Time;____Turbidity (ntu): Time: DissOxy(mjiT Time: F Time; Specific Cond. (uS): Res. Cl (ii g/L)/(µg/L): Time: Sample pH (s.u.): Time: �Titne: ReDox ( Time: Appearance: Time: ReDox IFH value):YS1 ProPlus +200mV Other: Stabilization Test Tun Temp. Diss Oxy. (mg/I) Spey. fu pH(s-u.) 6ReDoxTurbidity (ntu) Volume removed (gallons/mts/ WaterPurged level ft ther Document Name Field data Sheet Pate Issued: March &, 2f119: Pale: I iceArtalyiical' af'L avument Number. F-CAR-FID-001-rev.03 Issuing Authority: Pace Huntersville Quality +' t Office Name and Affiliation Name and Affiliation (Inspector): W f t — Well Information Well ID: Al L✓-1�`/'/619 Well Diameter:, Total Well Depth: �;.,./1 ft Static Water LeveL•_q �0L / ft Height of Water Column: % • Lt Well Locked: Construction: !Id Data Sheet Review; 5- 6, z'Z Date: 5- xx Steel) Multi Factor*::ems (`(Radius/12)2x3.14x.7.48l Casing Volumes gallons Cal. 3 Volumes: 3 a •� gallons Pump Intake: 16 (3, CC ft he ea. 4er a2 G=�G- By' M Ct2 Purge Information L DatePutged: 11j J Start: 100 Finish:_I.2YO Purge Rate: of Purging Method: ✓"/Ott i" Total Volume Purged: 1500 (gallons oils L) Sampling Information Date Collected<__�_/21/;. , Time Collected:j (a 1m�J l Sampling Equipment Used: 1n0V1.5000 Instrument ID: (6 N% & qo 2 Bottle Type 1 > 951ki t t P66& 3,- %G Mt S� pss Sample Temp, (aC): Preservation Y41LIa Analysis Required -- —Ak—h Y . ........................ 1/o C Turbidity (mu): Time; I2e'/0 Diss Oxy (mg/L): 0.5 Time: Fe 2+ mg/L: el Time: Specific Cond. (uS): 175 s Time: Res. Cl (mg/L)/(µg/L): Tune. Sample pH (s u.): —_GI . . Time: Odor:_...._✓ ____Trine .-.. �1 �G/� ReDox (mV): 5.t0 Time: Appearance. Timer_ ReDox (EH value):YST ProPlus +200mV '� B 5. G Other: Time: General/Weather Observations: /rainy) Sampler Signature Stabilization Test WindC.1 (mph) Time Temp. Diss Oxy. Spec Cond. pH (s.u.) ReDox Turbidity Volume removed Water Other Purged (C) (mg/L) (US) (n1V) (mu) (gallons/ tls 1 level (ft) L Ole 3, I 7,1 G, Soa 1�079 3.5 7, c ---- © 3. t, 6a.z l ac3o 6/ f , d l U• ?Soo 6+' G 6 qA p`TOOU 1 W i l Document Name: DocunientImued: March 8, 2019 E ceAnnoical Field Data Sheet Pagel -of jF Document Number: Issueing Authority:. F-CAR-FLD-0m.rev.03 Pice Huntersville QualftyOffice Client: && Location: Ahe,V.'Ile 4"(f Project:8gC&I% CG, CL65e1 Li' , �2 ,•;, Well ID: TY Iy' 21/ - /6a Reviewed Date and By: 6- 6' lL G-(9- Stabilization Test S -U - d 2- M (. R- t'iTeU Diameter Multiplication Factor' .0408 1.2 0•0918 1.623 0.1080 2 0.1630 3 0.3670 4 0.6330 6 1.4680 8 2:6100 Tlme Purged Temp. (°C) Diss Oxy. (mg/L) Spec' Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume Removed (gallons/ Is' } circle one Water level (ft} Other �. GC /G la30' flS 1. ` 6 0,6^ 3000110,Z 035 3._ 0. 17 .5 , I. 1 74,i 3Soc, 6.G6 A , E� 1 ?, l, 0 �a [IG•�33r7 iff. ,0 76.D .tl �Sct3 i'19�1 55 6, 7 j� y 6o,,5 ce /1l . g3 0 ,~; ,t 16-5 1Y,6 0,CS -73,7 7'/ a 95 S1, Z oc3e l/I - "I f I5 1 L 0 17. 7 y ro 2. 3' 1 3,3 I 70ao 111,C3 i 50 1-73.5N 6 a, Z-10.6 1 2-ooc . is INS' G 0,'S 1770 G 5. ff6.q 10000_ `/,03 17> '- -7,13 / I oa9 71, -7`l ro 3. K 2 coo IS 6'Z7. i 6 a l3poo a-5 5,5 - .s 170,3 7, 31.6 '�CIO 3 �. S 175. Cos.6' w 3� lSoc�o r?CBflik?ly(iCAC n Document Name: Maid data Sheet Date Tssned: March,8, 2014 Page.: i of Document Number. F-CAR-FT.6-001-rev.09 lssuhig Authority: Paceliunteoville Quality Office Field Dat Sheet Client:3L� Location: 5 eV1 A%C Projert#.6i'Ae�r c'' 6:. C1oSref /_f 2,Z Name and Affiliation (Sampler(s.: �� G q Ln 1' {fie t_ Field Data Shee£Review: I y Name"and Affiliation (Inspector): �1 v I2f �il ALA"" Date:. By: Wellhiformation V Tn, Well ID: �� L ` ( Well Locked; <� / NO / Frushmount ) Well Diameter: -Z Total Well Depth: io�o • 6 It Static Water Level: I- �� ZS it Height of Water Column: ' 60 it Construction: / /Steel/Stainless Steel) KUIti Factor*:0116-3 ['(Radius/12)2x3.14x.7.481 Casing Volume: 01 1-5 gallons Cal.3 Volumes: 0,39 gallons Pump Intake: 4� 5. 9 ft Purge Information Date Purged: Start : — Finish:Purge Rate: Purging Method: Total Volume Purged: — (gallons/mis/L) Sampling Information Date Collected: �/`= Time Collected: (am/pin) Sampling Equipment Used: Instrument ID: (5�j d2 3 -Tr e'J Bottle Type Preservation Analysis Required Sample Temp (°C); Time:._ _Turbidity (ntu): Time: Diss Oxy (mg/L): Time: Fe SpecificCond'. (uS); Time: Res. Cl Sample pH (s.u.): ---__,Time: —Odor- ReDox (mV): Time: Appeal ReDox (EH value):YSI ProPlus +200m Other: . 1V General/Weather Observations: '(it' ll d i kr I A Sampler Signature rRabilization Test Time: L)L)/(µgo[.. Time: Time: Time: p p tiny) Temp,' (°F) Wind / '- (mph) Time Purged Temp. (oC) (mg/L) Spec (u5). PH(s'u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level(£t) Other s Ar Document (Jame: Field data Sheet Date Issued: March 8, 2019' $CEfil7e7(yKCe7t Page: 1 of Document NumberP-ChR-F•L.IJ-001-rRvA3 Issuing Authority: Pace Huntersville Quality f. i Office Field Data Sheet Client: l Location:_A� Y, � 1J C Project #t _&,nc Name and Affiliation(Sampler(s): ADZ 7acp Field Data Sheet Review: Name and Affiliation (Inspector):. (k "_�5' �Z Well Information Date. `1- 7_. 72 Well ID: 51� us moun } Well Diameter: _ t, PVC tee /Stanllegs Steel) Total Well Depth: ft Static Water Level: _ ft Height of Water Column- ft Multi Factor*:- - I'{Radius/12)2 x$.14 x7.481 Casing Volume: — gallons Cal, 3 Volumes: gallons Pump Intake: it Purge Information Date Purged: — / — ! — Start : Finish: Purge Rate: 1 05e r@ l7 SA Apr, a03a G-t C' I By: M 6 /L Purging Method. _ Total Volume Purged: I(gallons/n1Ls/L) Sampling Information Date Collected:_/2a/ a Time Collected;_) "<;�— _ (am/R Sampling Equipment Used: C��� Tnstrument ID: YC3 Bottle Type Preservation Analysis Required (- Kb'l_'Plats. vtrelr 1-1;i.to� mm_NC T ,���..... wll NCAf�ps yQ( Field Measnrenients/Observations Sample Temp (°C):. j�, J Time: b _Turbidity (mu): L• L Time: _ L t c{ Diss Oxy (mg/L): b . q Time: L'L�_ Fe 2+ mg/L: N7 Time: bct Specific Cond. (uS): Li` ( Time: 1(.,L _ Res. CI (trig/L)&g/L), Time: Sample pH(s.u.);_�____ Time: fbLrOdor:__._N_____Tune:__�b�l_ ReDox (mV): m"" � ' `t Time: �b l Appearance: C�eAK Time: I { " rrl rya ReDox (EHvalue):YSI ProPlus.+20t7mVOther: Time: General/Weather Observations: 3V 301, Wind 13 (mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Diss Oxy: (mg/I) Spec. Cond. (us) pH I (s tn) ReDox (mV) Turbidity (ntu) Volume removed (gallows/mis/ L Water level (it) Other or Z iJocument Name: Field data Sheet Date Issued: March 8, 2019' OCBA/h4lyiiCa!' Page: 9 ot_ l7ncumenf Number. P-CAR FLD-001-rev:Q$ Issuing. Authority: Pace Htmtersville Quality i Office Field Data Sheet nt:, `' Location:�5�o.,-f((�, 4. .- Proiect#:5�cb be(_Uos sd LF Vj,, Name and Affiliation Field Data Sheet Review: Name and Affiliation(Inspector): Ar 'A Dater '1 - Z9 - ZZ BY: M C—✓r, Well Information Well ID: Well Diameter: — Cot teel) Total Well Depth; It Static Water Level: ft Height of Water Column: — ft Multi Factor*: [(Radius/12)2 x31a x 7.4al Casing Volume; gallons CaL 3 Volumes: gallons Pump Intake: ft Purge Information Date Purged -,_ / Start: Finish: — Purge Rate: a Purging Method: Total Volume Purged: (gallons/mis/L) Samnline Information Date Collected:C)lj\ Time Collected;_tLQ,Q (am/ rn Sampling Equipment Used: S9Instrument ID: \1Sr PmnkASteoac, n Tfk-439"1 Bottle Type Preservation Analysis Required Field Measurements/Observations Sample Temp ('C): Time:_b QQ. _Turbidity (ntu)': Time: I Q 0 Diss Oxy (mg/L)S '3 Time: 6 Q.(Fe 2+ mg/Li ND — — ---- ffime: 6 Q Specific Cond. (uS): q6 �' Time: 60Q Res. C1 (mg/L)/(ltg/L):--'rime: — Sample pH (s.u.): � • 3 .__........ . Time: 1 b C)O ReDox (mV): .3 Time: UjQQ Appearance: CUAK Time: ) 6Q9 ReDox (EFI value):YSi ProPlus +200mV 2E33 3 Other: Time: General/Weather Observations; PS( CE) self unn /cloudy/rainy) Temp. &6 CF) Wind)—_�%_(mph) Sampler Signature: Stabilization Test Time Purged Temp. (C) CC) Diss Oxy. (mg/I) bone. (us) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (fY) Other a%7U ` Document Name: Field ci to Sheet Date Issued: March 6, 2019 Pa t CtbhWlylical e;.. of - [)�cument Number: FCAR-CAR-001-rev:IX3 lasuhtg.Au.thonty: Pace Htmtersville Quality t r Office Name and Affiliation (Sampler(s): Cl 6 : - PG [ e Field Data Sheet Review; Name and Affiliation (Inspector): AR `1- 25 Z Z Well Information Date: Lf , z5 -?2 WellID: S LJ_ ��A Well Diameter: Total Well Depth: ft Static Water Level: ft Height of Water Column: ft Purge Information Date Purged: /_m�/ � Start: ee an Multi Factor*: — (a(i;ad us/12)x x 3:1x 7,481 Casing Volume: gallons CaL 3 Volumes; gallons Pump Intake: it Finish: Purge Rate: Ih CVO• 1 By: G Cc - Purging Method: Total Volume Purged: (gallons/rails/L) Samr,line Information Date Collected:_/ 7ZY . Time Collected; 16 1 ._... _ (am/ 6mS� Sam piing Equipment Used: GL-L Instrument ID: `(STDcagq JI aac �t� �MLrrorPUa 3n q Bottle Type Preservation Analysis Required k—�-QI�, 1�0 _ PLC Am1rL... 3-YQc..L vralc IA-G1 n�C&P P -r v Field Measurements/Observations Sample Temp (oC): ) 6 Time: d (S _ _ Turbidity (ntu): % Time: 1 b 1 Diss Oxy (mg/L): '�;' A Time: ) b (� Fe 2+ mg/L: Kj> Time: Specific Cond. (uS): t-lOS - Time ) 61 C Res. Cl (mg/L)/(µg/L): —'-Time: 61 �-_ Sample pH (%u.): _� •�Time: ) ti I Odor;_. N_ _+ _.---- _------ Time: ..._L�I .._ ReDox (mV): 1_751 Time: '6 L Appearance: Gees( Time: i 61i ReDox (EH value):YSI ProPlus +200mV �r n1� .3 Other: Time: General/Weather Observations: CQc)_ 15" 5S •' , N , - -13 " > 6 , 61 Wind_1__� _(mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Diss Oxy. (mg/L.) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntu) Volume removed (gallons/cols/ L Water level (ft) Other �b.il � , 4c 9 �,3 -1-101 Document Name: Field data Sheet hate Issued: March &, 2014. Page: i BECNh'tty!%Ckt7 1 of Document Number:F CAR-CAR-Qpi-rev.0$ Issuing Authority: Pace:Huntersville Quality' _, r Office Field Data Sheet 2 ClientjC E' Locati=_��(x QC Protect#:Jtnr\(O,v,Q C,.Llose,4 L1= SA Aer.)o-*9- Nameand Affiliation (Sampler(s):�- P6((_9 Field Data Sheet Review: Name and Affiliation (Inspectar)AAtl_:LOt,22 n G-LG- Well Information Date: y . )1 _ Z2 By: H62 Well ID: Sw 3 c Flushmount ) Well Diameters i Construe i s Steel) Total Well Depth: It Multi Factor*: f (+(Ra us/12)2x3:14x7.g8] Static Water Level: ft Casing Volume: gallons Height of Water Column; ft CaL 3 Volumes; gallons Pump Intake: - It -. Puree Information Date Purged: — J / Start : Finish; Purge Rate: Purging Methods Total Volume Purged; {gallons/n is jL) Sar avlins Information Date Collected: 0 1 /Xj Time CollectedAS'LQ�__.:._ (am Sampling Equipment Used: 6 Fylh Instrument ID: `/ S q( k9a=Ca j Mc �UTQw ct 3t� 2q Bottle Type Preservation Analysis Required \-1S'o,.,,Lnla4 IAr>Oz 3•t-IQ C,/L—V�,tc la-c1 I,gDioxa A Field MeasurementalQbservations Sample Temp CC):, ��' Time:_) 5 _._._ Turbidity (ntu): 'o\9l 3 Time: Diss Oxy (mgJL): S Thne: I S?,G Fe 2+ mg/L: f\A) Time: 1 %-5q Specific Cond. (vS): f- l Time: N:30 Res. Cl (mg/L)1(ug/L)c ' Time: -- Sample pH (s;u.):. Time:.,f Odor,-- .11 Nt) -----Jime: ReDox (mV);- I Q .'� Tune: f�0 Appearaxlot,. tine.C?__ R@DOx (EH value);YSI ProPlus +200nxV 0b, Other: Time: General/WeatheYObservationg: b?scao,&AS-3, 030('�`d`1'N,-77-'3/. I`-1�1'�✓ Wind 1 oZ (mph) Sampler Signature Stabilization Test Time Purged Temp. (C) Diss Oxy: (mgf I) Spec Cored. (us) pH (s.u.) ReDox (,,IV) Turbidity (ntu) Volume removed (gallons/mis/ L Water level (ft) Other Document Name: Field Bala Sheet aceArrafyticaf J Document Number. F CAR FL.D-001 rev,0.3 issuhig Field Data SheeE nlr , Name and Affiliation (Sampler(s) -,Ia - -ce�e Field Data SheetReview: Name and Affiliation (Inspector): N A 4 - d F -'T 2- Well Information Date: �, 21)'- 21 Well ID: �> WelLl ocked: Well Diameter: Total Well Depth: ft Static Water Level: ft Height of Water Column: ft ee tan ess Steel) Multi Factor*: � 1•(fiadlus/12)20.14 x 7.481 Casing Volume: gallons Cal.3 Volumes; gallons v Fump Intake: it Purge Information DatePurgedr - // Start: Pinish; Purge R7tc: I owed /.1` Sq Afi'.') 113E�L By. Gcr� i Purging Method: Total Volume Purged: i (gallons/uils/L) Sampling Information Date Collected:_/�-/-Yct,_ Time Collecteit:_j 5�1_5._ (am' pm Sampling Equipment Used: 6"c-'1' Instrument ID: y ST Bottle Type Preservation Analysis Required 1- a. tml ?i OLS Vp NeISNis NLAnQT' VoL Field MeasurementgLObservations Sample Temp CC); 1 fL' Tune: L .� _ Turbidity (ntu):3,4Time: DissOxy (mg/L); Time; 'S- —Fe 2+ mg/L: f" C) Time: 1 V-t _ Specific Cond. (uS): Time: _Res_ Cl (mg/L)/(itg/L)t — Time: Sample pH (s:u.); `-1=i___... . Time: I S 1 Odor:__.— ReDox (mV): —4- Time: I S I i� Appearance: Gtiw LA Dtckc,.tm� �1e: ReDox (EH value):YSI ProPlus +200mV��_ Other: Time: General/WeatherObservations. 60 CcgcrdP_3,;-' Sampler Signature Stabilization Test Time Purged Temp. a (C} Diss Oxy. (mg[I•) Spec. Cond. (us) pH (s.u.) ReDox (txtVJ Turbidity (ntuJ Volume removed (gallons/mis/ L Water ]eves (ft) Other APPENDIX B LABORATORY ANALYTICAL DATA - PACE ANALYTICAL SERVICES, LLC. 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Closed Buncombe County Landfill Project Number: 14175-06B Lot Number:XD27067 Date Completed:05/11/2022 Revision Date: 07/29/2022 07/29/2022 9:17 AM Approved and released by: Project Manager II: Lucas Odom pCC/►F� 24r�A SOA ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 109 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: XD27067 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. This report supersedes all other versions of the same lot. VOCs by GC/MS Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD) for analytical batch 40161, 40778, 40764. An LCS/LCSD was run in lieu of an MS/MSD. Due to the large number of spiked analytes, there is a high probability that one or more analytes will recover outside acceptance limits. The laboratory's SOP allows for 10% of analytes to recover marginally outside criteria. The following analyte recovered marginally outside LCS criteria in batch 40823: Bromomethane. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 109 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: XD27067 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-13-132 Aqueous 04/25/20221135 04/27/2022 002 MW-13-35 Aqueous 04/25/20221055 04/27/2022 003 MW-12-25 Aqueous 04/25/20221215 04/27/2022 004 MW-18-78 Aqueous 04/25/20221315 04/27/2022 005 MW-19-110 Aqueous 04/25/20221505 04/27/2022 006 MW-19-75 Aqueous 04/25/20221425 04/27/2022 007 MW-21-21 Aqueous 04/25/20221615 04/27/2022 008 MW-21-94 Aqueous 04/25/20221615 04/27/2022 021 MW-4A Aqueous 04/27/20221001 04/29/2022 022 MW-7 Aqueous 04/27/20221020 04/29/2022 023 MW-3 Aqueous 04/27/20221125 04/29/2022 024 MW-4 Aqueous 04/27/20221214 04/29/2022 025 MW-24-160 Aqueous 04/27/20221240 04/29/2022 026 MW-17-137 Aqueous 04/27/20221405 04/29/2022 027 MW-17-60 Aqueous 04/27/20221440 04/29/2022 028 MW-2 Aqueous 04/27/20221505 04/29/2022 029 MW-5 Aqueous 04/27/2022 0330 04/29/2022 030 MW-6-192 Aqueous 04/27/20221423 04/29/2022 031 MW-6 Aqueous 04/27/20221510 04/29/2022 032 MW-15 Aqueous 04/27/20221616 04/29/2022 033 SW-3 Aqueous 04/27/20221530 04/29/2022 034 SW-4 Aqueous 04/27/20221545 04/29/2022 035 SW-2 Aqueous 04/27/20221600 04/29/2022 036 SW-2A Aqueous 04/27/20221615 04/29/2022 037 SW-1 Aqueous 04/27/20221645 04/29/2022 (25 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 109 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: XD27067 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-13-132 Aqueous 1, 1 -Dichloroethane 8260D 1.1 ug/L 10 001 MW-13-132 Aqueous cis- 1,2-Dichloroethene 8260D 8.2 ug/L 10 001 MW-13-132 Aqueous Barium 6020B 47 ug/L 11 001 MW-13-132 Aqueous Nickel 6020B 1.6 J ug/L 11 001 MW-13-132 Aqueous Zinc 6020B 4.2 J ug/L 11 002 MW-13-35 Aqueous Benzene 8260D 0.43 J ug/L 12 002 MW-13-35 Aqueous Chlorobenzene 8260D 1.0 ug/L 12 002 MW-13-35 Aqueous 1,4-Dichlorobenzene 8260D 0.90 J ug/L 12 002 MW-13-35 Aqueous cis- 1,2-Dichloroethene 8260D 1.7 ug/L 12 002 MW-13-35 Aqueous Barium 6020B 190 ug/L 13 002 MW-13-35 Aqueous Cobalt 6020B 1.5 J ug/L 13 002 MW-13-35 Aqueous Copper 6020B 1.5 J ug/L 13 002 MW-13-35 Aqueous Nickel 6020B 5.4 ug/L 13 002 MW-13-35 Aqueous Zinc 6020B 6.4 J ug/L 13 003 MW-12-25 Aqueous Barium 6020B 50 ug/L 15 003 MW-12-25 Aqueous Copper 6020B 1.3 J ug/L 15 003 MW-12-25 Aqueous Nickel 6020B 15 ug/L 15 003 MW-12-25 Aqueous Zinc 6020B 11 ug/L 15 004 MW-18-78 Aqueous 1,4-Dioxane 8260D (SIM) 21 ug/L 16 004 MW-18-78 Aqueous Chlorobenzene 8260D 1.1 ug/L 16 004 MW-18-78 Aqueous 1,4-Dichlorobenzene 8260D 0.64 J ug/L 16 004 MW-18-78 Aqueous Barium 6020B 33 ug/L 17 004 MW-18-78 Aqueous Chromium 6020B 4.4 J ug/L 17 004 MW-18-78 Aqueous Nickel 6020B 3.9 J ug/L 17 005 MW-19-110 Aqueous 1,4-Dioxane 8260D (SIM) 19 ug/L 19 005 MW-19-110 Aqueous Antimony 6020B 0.60 J ug/L 20 005 MW-19-110 Aqueous Barium 6020B 12 ug/L 20 005 MW-19-110 Aqueous Chromium 6020B 1.4 J ug/L 20 005 MW-19-110 Aqueous Nickel 6020B 4.5 J ug/L 20 005 MW-19-110 Aqueous Zinc 6020B 3.4 J ug/L 21 006 MW-19-75 Aqueous 1,4-Dioxane 8260D (SIM) 57 ug/L 22 006 MW-19-75 Aqueous Chlorobenzene 8260D 2.5 ug/L 22 006 MW-19-75 Aqueous 1,4-Dichlorobenzene 8260D 2.2 ug/L 22 006 MW-19-75 Aqueous 1, 1 -Dichloroethane 8260D 0.57 J ug/L 22 006 MW-19-75 Aqueous Barium 6020B 96 ug/L 23 006 MW-19-75 Aqueous Chromium 6020B 1.7 J ug/L 23 006 MW-19-75 Aqueous Nickel 6020B 20 ug/L 23 006 MW-19-75 Aqueous Zinc 6020B 4.8 J ug/L 24 007 MW-21-21 Aqueous 1,4-Dioxane 8260D (SIM) 60 ug/L 25 007 MW-21-21 Aqueous Benzene 8260D 2.3 ug/L 25 007 MW-21-21 Aqueous Chlorobenzene 8260D 10 ug/L 25 007 MW-21-21 Aqueous 1,2-Dichlorobenzene 8260D 1.6 ug/L 25 007 MW-21-21 Aqueous 1,4-Dichlorobenzene 8260D 11 ug/L 25 007 MW-21-21 Aqueous 1,1-Dichloroethane 8260D 1.5 ug/L 25 007 MW-21-21 Aqueous 1,2-Dichloroethane 8260D 0.56 J ug/L 25 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 109 Detection Summary (Continued) Lot Number: XD27067 Sample Sample ID Matrix Parameter Method Result Q Units Page 007 MW-21-21 Aqueous cis- 1,2-Dichloroethene 8260D 2.4 007 MW-21-21 Aqueous Vinyl chloride 8260D 1.3 007 MW-21-21 Aqueous Barium 6020B 110 007 MW-21-21 Aqueous Cobalt 6020B 11 007 MW-21-21 Aqueous Nickel 6020B 4.0 008 MW-21-94 Aqueous 1,4-Dioxane 8260D (SIM) 29 008 MW-21-94 Aqueous Barium 6020B 25 008 MW-21-94 Aqueous Chromium 6020B 3.6 008 MW-21-94 Aqueous Nickel 6020B 11 008 MW-21-94 Aqueous Zinc 6020B 3.7 021 MW-4A Aqueous 1,4-Dioxane 8260D (SIM) 27 021 MW-4A Aqueous Benzene 8260D 5.5 021 MW-4A Aqueous Chlorobenzene 8260D 37 021 MW-4A Aqueous 1,2-Dichlorobenzene 8260D 4.1 021 MW-4A Aqueous 1,4-Dichlorobenzene 8260D 13 021 MW-4A Aqueous cis- 1,2-Dichloroethene 8260D 0.58 021 MW-4A Aqueous Ethylbenzene 8260D 3.0 021 MW-4A Aqueous Toluene 8260D 1.6 021 MW-4A Aqueous Vinyl chloride 8260D 0.50 021 MW-4A Aqueous Xylenes (total) 8260D 4.1 021 MW-4A Aqueous Barium 6020B 710 021 MW-4A Aqueous Cadmium 6020B 0.17 021 MW-4A Aqueous Cobalt 6020B 47 021 MW-4A Aqueous Nickel 6020B 8.3 022 MW-7 Aqueous Benzene 8260D 1.4 022 MW-7 Aqueous Chlorobenzene 8260D 8.0 022 MW-7 Aqueous Chloroethane 8260D 2.0 022 MW-7 Aqueous 1,4-Dichlorobenzene 8260D 2.6 022 MW-7 Aqueous 1,1-Dichloroethane 8260D 1.6 022 MW-7 Aqueous cis-1,2-Dichloroethene 8260D 12 022 MW-7 Aqueous Barium 6020B 160 022 MW-7 Aqueous Cadmium 6020B 0.15 022 MW-7 Aqueous Cobalt 6020B 250 022 MW-7 Aqueous Copper 6020B 1.9 022 MW-7 Aqueous Nickel 6020B 77 022 MW-7 Aqueous Zinc 6020B 15 023 MW-3 Aqueous 1,4-Dioxane 8260D (SIM) 89 023 MW-3 Aqueous Benzene 8260D 1.1 023 MW-3 Aqueous Chlorobenzene 8260D 3.4 023 MW-3 Aqueous Chloroethane 8260D 2.4 023 MW-3 Aqueous 1,2-Dichlorobenzene 8260D 0.60 023 MW-3 Aqueous 1,4-Dichlorobenzene 8260D 6.1 023 MW-3 Aqueous 1,1-Dichloroethane 8260D 1.3 023 MW-3 Aqueous cis- 1,2-Dichloroethene 8260D 0.66 023 MW-3 Aqueous Vinyl chloride 8260D 0.45 023 MW-3 Aqueous Xylenes (total) 8260D 0.58 023 MW-3 Aqueous Barium 6020B 180 023 MW-3 Aqueous Cobalt 6020B 13 J J J J J J J J J J J J ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 25 26 26 26 26 28 29 29 29 30 31 31 31 31 31 31 32 32 32 32 32 32 32 32 34 34 34 34 34 34 35 35 35 35 35 35 36 36 36 36 36 36 36 36 37 37 37 37 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 109 Detection Summary (Continued) Lot Number: XD27067 Sample Sample ID Matrix Parameter Method Result Q Units Page 023 MW-3 Aqueous Nickel 6020B 31 ug/L 023 MW-3 Aqueous Zinc 6020B 3.2 J ug/L 024 MW-4 Aqueous 1,4-Dioxane 8260D (SIM) 17 ug/L 024 MW-4 Aqueous Benzene 8260D 0.93 J ug/L 024 MW-4 Aqueous Chlorobenzene 8260D 5.1 ug/L 024 MW-4 Aqueous Chloroethane 8260D 2.0 ug/L 024 MW-4 Aqueous 1,2-Dichlorobenzene 8260D 0.77 J ug/L 024 MW-4 Aqueous 1,4-Dichlorobenzene 8260D 11 ug/L 024 MW-4 Aqueous 1,1-Dichloroethane 8260D 6.4 ug/L 024 MW-4 Aqueous cis- 1,2-Dichloroethene 8260D 16 ug/L 024 MW-4 Aqueous Trichloroethene 8260D 0.77 J ug/L 024 MW-4 Aqueous Vinyl chloride 8260D 2.6 ug/L 024 MW-4 Aqueous Barium 6020B 520 ug/L 024 MW-4 Aqueous Cadmium 6020B 0.94 ug/L 024 MW-4 Aqueous Cobalt 6020B 60 ug/L 024 MW-4 Aqueous Nickel 6020B 81 ug/L 024 MW-4 Aqueous Zinc 6020B 14 ug/L 025 MW-24-160 Aqueous Barium 6020B 13 ug/L 025 MW-24-160 Aqueous Chromium 6020B 1.7 J ug/L 025 MW-24-160 Aqueous Copper 6020B 1.4 J ug/L 025 MW-24-160 Aqueous Lead 6020B 1.2 ug/L 025 MW-24-160 Aqueous Nickel 6020B 2.8 J ug/L 025 MW-24-160 Aqueous Zinc 6020B 7.5 J ug/L 026 MW-17-137 Aqueous 1,4-Dioxane 8260D (SIM) 35 ug/L 026 MW-17-137 Aqueous Chloroethane 8260D 0.41 J ug/L 026 MW-17-137 Aqueous 1,1-Dichloroethane 8260D 0.68 J ug/L 026 MW-17-137 Aqueous Vinyl chloride 8260D 0.44 J ug/L 026 MW-17-137 Aqueous Xylenes (total) 8260D 0.47 J ug/L 026 MW-17-137 Aqueous Barium 6020B 26 ug/L 027 MW-17-60 Aqueous 1,4-Dioxane 8260D (SIM) 22 ug/L 027 MW-17-60 Aqueous 1, 1 -Dichloroethane 8260D 0.93 J ug/L 027 MW-17-60 Aqueous cis- 1,2-Dichloroethene 8260D 1.2 ug/L 027 MW-17-60 Aqueous Vinyl chloride 8260D 0.58 J ug/L 027 MW-17-60 Aqueous Barium 6020B 24 ug/L 028 MW-2 Aqueous Barium 6020B 27 ug/L 028 MW-2 Aqueous Chromium 6020B 51 ug/L 028 MW-2 Aqueous Copper 6020B 3.5 J ug/L 028 MW-2 Aqueous Nickel 6020B 51 ug/L 028 MW-2 Aqueous Zinc 6020B 2.8 J ug/L 029 MW-5 Aqueous 1,4-Dioxane 8260D (SIM) 84 ug/L 029 MW-5 Aqueous Benzene 8260D 0.73 J ug/L 029 MW-5 Aqueous Chlorobenzene 8260D 8.2 ug/L 029 MW-5 Aqueous Chloroethane 8260D 1.0 J ug/L 029 MW-5 Aqueous 1,4-Dichlorobenzene 8260D 4.1 ug/L 029 MW-5 Aqueous Barium 6020B 190 ug/L 029 MW-5 Aqueous Cobalt 6020B 12 ug/L 029 MW-5 Aqueous Nickel 6020B 25 ug/L 029 MW-5 Aqueous Selenium 6020B 1.3 J ug/L 37 38 39 39 39 39 39 39 39 39 40 40 40 40 40 40 41 43 43 43 43 43 43 44 44 44 45 45 45 47 47 47 48 48 51 51 51 51 51 52 52 52 52 52 53 53 53 54 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 109 Detection Summary (Continued) Lot Number: XD27067 Sample Sample ID Matrix Parameter Method Result Q Units Page 029 MW-5 Aqueous Zinc 6020B 7.6 J ug/L 54 030 MW-6-192 Aqueous 1,4-Dioxane 8260D (SIM) 6.1 ug/L 55 030 MW-6-192 Aqueous Chlorobenzene 8260D 0.84 J ug/L 55 030 MW-6-192 Aqueous Chloroethane 8260D 0.80 J ug/L 55 030 MW-6-192 Aqueous 1,1-Dichloroethane 8260D 0.74 J ug/L 55 030 MW-6-192 Aqueous Barium 6020B 65 ug/L 56 030 MW-6-192 Aqueous Nickel 6020B 1.3 J ug/L 56 031 MW-6 Aqueous 1,4-Dioxane 8260D (SIM) 38 ug/L 58 031 MW-6 Aqueous Benzene 8260D 1.1 ug/L 58 031 MW-6 Aqueous Chlorobenzene 8260D 7.5 ug/L 58 031 MW-6 Aqueous Chloroethane 8260D 2.8 ug/L 58 031 MW-6 Aqueous 1,4-Dichlorobenzene 8260D 2.8 ug/L 58 031 MW-6 Aqueous 1,1-Dichloroethane 8260D 1.5 ug/L 58 031 MW-6 Aqueous Barium 6020B 1600 ug/L 59 031 MW-6 Aqueous Copper 6020B 1.7 J ug/L 59 031 MW-6 Aqueous Nickel 6020B 11 ug/L 60 031 MW-6 Aqueous Zinc 6020B 3.4 J ug/L 60 032 MW-15 Aqueous 2-Butanone (MEK) 8260D 2.6 J ug/L 61 032 MW-15 Aqueous Antimony 6020B 1.1 J ug/L 62 032 MW-15 Aqueous Barium 6020B 150 ug/L 62 032 MW-15 Aqueous Chromium 6020B 22 ug/L 62 032 MW-15 Aqueous Copper 6020B 2.5 J ug/L 62 032 MW-15 Aqueous Lead 6020B 0.91 J ug/L 62 032 MW-15 Aqueous Zinc 6020B 11 ug/L 62 033 SW-3 Aqueous 1,4-Dioxane 8260D (SIM) 45 ug/L 63 033 SW-3 Aqueous Barium 6020B 120 ug/L 64 033 SW-3 Aqueous Cobalt 6020B 3.3 J ug/L 64 033 SW-3 Aqueous Nickel 6020B 4.4 J ug/L 64 033 SW-3 Aqueous Zinc 6020B 2.6 J ug/L 65 034 SW-4 Aqueous 1,4-Dioxane 8260D (SIM) 63 ug/L 66 034 SW-4 Aqueous Barium 6020B 94 ug/L 67 034 SW-4 Aqueous Cobalt 6020B 4.8 J ug/L 67 034 SW-4 Aqueous Nickel 6020B 20 ug/L 67 035 SW-2 Aqueous Barium 6020B 14 ug/L 70 036 SW-2A Aqueous 1,4-Dioxane 8260D (SIM) 11 ug/L 71 036 SW-2A Aqueous Barium 6020B 34 ug/L 72 036 SW-2A Aqueous Nickel 6020B 1.7 J ug/L 72 037 SW-1 Aqueous Barium 6020B 11 ug/L 75 037 SW-1 Aqueous Zinc 6020B 2.5 J ug/L 75 (180 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-001 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/25/2022 1135 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0216 SDC 40778 2 5030B 8260D 1 05/07/2022 0839 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 1.1 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 8.2 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-001 Description: MW-13-132 Matrix: Aqueous Date Sampled:04/25/2022 1135 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0216 SDC 40778 2 5030B 8260D 1 05/07/2022 0839 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 81 70-130 94 70-130 1,2-Dichloroethane-d4 119 70-130 103 70-130 Toluene-d8 95 70-130 93 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1527 BNW 05/01/2022 0531 39965 2 3005A 6020B 1 05/04/2022 1026 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 47 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 2 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-002 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/25/2022 1055 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0241 SDC 40778 2 5030B 8260D 1 05/07/2022 0903 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 0.43 J 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D 1.0 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 0.90 J 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 1.7 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-002 Description: MW-13-35 Matrix: Aqueous Date Sampled:04/25/2022 1055 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0241 SDC 40778 2 5030B 8260D 1 05/07/2022 0903 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 86 70-130 95 70-130 1,2-Dichloroethane-d4 118 70-130 107 70-130 Toluene-d8 99 70-130 93 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1538 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.4 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-003 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/25/2022 1215 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0307 SDC 40778 2 5030B 8260D 1 05/08/2022 2141 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-003 Description: MW-12-25 Matrix: Aqueous Date Sampled:04/25/2022 1215 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0307 SDC 40778 2 5030B 8260D 1 05/08/2022 2141 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 2 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 84 70-130 83 70-130 1,2-Dichloroethane-d4 119 70-130 121 70-130 Toluene-d8 97 70-130 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1541 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 50 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 15 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 11 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-004 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/25/2022 1315 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1526 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 21 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2206 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.1 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.64 J 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-004 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/25/2022 1315 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2206 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 118 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1545 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 33 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 4.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.9 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-004 Description: MW-18-78 Matrix: Aqueous Date Sampled:04/25/2022 1315 Date Received:04/27/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1545 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-005 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/25/2022 1505 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1550 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 19 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2231 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-005 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/25/2022 1505 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2231 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 86 70-130 1,2-Dichloroethane-d4 122 70-130 Toluene-d8 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1548 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.60 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 12 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.5 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-005 Description: MW-19-110 Matrix: Aqueous Date Sampled:04/25/2022 1505 Date Received:04/27/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1548 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 3.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-006 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/25/2022 1425 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1614 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 57 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2257 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 2.5 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 2.2 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.57 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-006 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/25/2022 1425 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2257 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 88 70-130 1,2-Dichloroethane-d4 121 70-130 Toluene-d8 99 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1552 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 96 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.7 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 20 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-006 Description: MW-19-75 Matrix: Aqueous Date Sampled:04/25/2022 1425 Date Received:04/27/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1552 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 4.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-007 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/25/2022 1615 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1639 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 60 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2322 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 2.3 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 10 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 1.6 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 11 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.5 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.56 J 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 2.4 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-007 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/25/2022 1615 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2322 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 1.3 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 119 70-130 Toluene-d8 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1555 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 11 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.0 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-007 Description: MW-21-21 Matrix: Aqueous Date Sampled:04/25/2022 1615 Date Received:04/27/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1555 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-008 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/25/2022 1615 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1703 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 29 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2347 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND L 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-008 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/25/2022 1615 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/08/2022 2347 BWS 40823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 122 70-130 Toluene-d8 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1559 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 25 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 11 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-008 Description: MW-21-94 Matrix: Aqueous Date Sampled:04/25/2022 1615 Date Received:04/27/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1559 BNW 05/01/2022 0531 39965 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 3.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-021 Description: MW-4A Matrix: Aqueous Date Sampled:04/27/2022 1001 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/02/2022 2348 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 27 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0140 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 5.5 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 37 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 4.1 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 13 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.58 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-021 Description: MW-4A Matrix: Aqueous Date Sampled:04/27/2022 1001 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0140 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D 3.0 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D 1.6 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 4.1 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 96 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1150 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 710 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.17 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 47 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 8.3 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-021 Description: MW-4A Matrix: Aqueous Date Sampled:04/27/2022 1001 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1150 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-022 Description: MW-7 Matrix: Aqueous Date Sampled:04/27/2022 1020 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0205 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D 1.4 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D 8.0 1.0 0.40 ug/L Chloroethane 75-00-3 8260D 2.0 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D 2.6 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D 1.6 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis-1,2-Dichloroethene 156-59-2 8260D 12 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-022 Description: MW-7 Matrix: Aqueous Date Sampled:04/27/2022 1020 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0205 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1153 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 160 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.15 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 250 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.9 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 77 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 15 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-023 Description: MW-3 Matrix: Aqueous Date Sampled:04/27/2022 1125 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0012 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 89 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0229 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.1 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 3.4 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.4 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.60 J 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 6.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.3 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.66 J 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-023 Description: MW-3 Matrix: Aqueous Date Sampled:04/27/2022 1125 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0229 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.45 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.58 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 111 70-130 Toluene-d8 98 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1157 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 180 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 13 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 31 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-023 Description: MW-3 Matrix: Aqueous Date Sampled:04/27/2022 1125 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1157 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 3.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/27/2022 1214 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0037 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 17 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0254 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.93 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 5.1 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.0 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.77 J 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 11 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 6.4 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 16 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/27/2022 1214 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0254 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D 0.77 J 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 2.6 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 93 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1207 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 520 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.94 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 60 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 81 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-024 Description: MW-4 Matrix: Aqueous Date Sampled:04/27/2022 1214 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1207 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 14 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-025 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/27/2022 1240 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0319 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-025 Description: MW-24-160 Matrix: Aqueous Date Sampled:04/27/2022 1240 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0319 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 105 70-130 Toluene-d8 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1211 BNW 04/30/2022 1125 39932 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 13 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.7 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.2 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 2.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-026 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/27/2022 1405 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0101 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 35 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0344 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.41 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.68 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-026 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/27/2022 1405 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0344 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.44 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 0.47 J 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 95 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 94 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1609 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 26 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-026 Description: MW-17-137 Matrix: Aqueous Date Sampled:04/27/2022 1405 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1609 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-027 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/27/2022 1440 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0125 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 22 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0408 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.93 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.2 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-027 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/27/2022 1440 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0408 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.58 J 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 94 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1634 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 24 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-027 Description: MW-17-60 Matrix: Aqueous Date Sampled:04/27/2022 1440 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1634 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-028 Description: MW-2 Matrix: Aqueous Date Sampled:04/27/2022 1505 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0433 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-028 Description: MW-2 Matrix: Aqueous Date Sampled:04/27/2022 1505 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0433 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1637 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 27 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 51 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 51 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-029 Description: MW-5 Matrix: Aqueous Date Sampled:04/27/2022 0330 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0150 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 84 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0458 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 0.73 J 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 8.2 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.0 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 4.1 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-029 Description: MW-5 Matrix: Aqueous Date Sampled:04/27/2022 0330 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0458 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1641 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 12 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 25 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-029 Description: MW-5 Matrix: Aqueous Date Sampled:04/27/2022 0330 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1641 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B 1.3 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-030 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/27/2022 1423 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0214 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.1 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 98 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0523 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.84 J 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.80 J 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.74 J 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-030 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/27/2022 1423 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0523 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 95 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1644 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 65 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.3 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-030 Description: MW-6-192 Matrix: Aqueous Date Sampled:04/27/2022 1423 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1644 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-031 Description: MW-6 Matrix: Aqueous Date Sampled:04/27/2022 1510 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0238 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 38 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0547 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D 1.1 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 7.5 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D 2.8 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 2.8 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.5 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-031 Description: MW-6 Matrix: Aqueous Date Sampled:04/27/2022 1510 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0547 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 93 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1648 BNW 04/30/2022 1125 39935 2 3005A 6020B 5 05/04/2022 1033 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 1600 25 6.3 ug/L 2 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.7 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-031 Description: MW-6 Matrix: Aqueous Date Sampled:04/27/2022 1510 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1648 BNW 04/30/2022 1125 39935 2 3005A 6020B 5 05/04/2022 1033 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B 11 5.0 1.3 ug/L 1 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 3.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-032 Description: MW-15 Matrix: Aqueous Date Sampled:04/27/2022 1616 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0612 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D 2.6 J 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-032 Description: MW-15 Matrix: Aqueous Date Sampled:04/27/2022 1616 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0612 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 90 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1651 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 1.1 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 150 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 22 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.91 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 11 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-033 Description: SW-3 Matrix: Aqueous Date Sampled:04/27/2022 1530 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0303 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 45 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0636 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-033 Description: SW-3 Matrix: Aqueous Date Sampled:04/27/2022 1530 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0636 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 93 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1702 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 4.4 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-033 Description: SW-3 Matrix: Aqueous Date Sampled:04/27/2022 1530 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1702 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 Silver 7440-22-4 Thallium 7440-28-0 Vanadium 7440-62-2 Zinc 7440-66-6 6020B ND 5.0 1.3 ug/L 1 6020B ND 1.0 0.25 ug/L 1 6020B ND 0.50 0.15 ug/L 1 6020B ND 5.0 2.5 ug/L 1 6020B 2.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-034 Description: SW-4 Matrix: Aqueous Date Sampled:04/27/2022 1545 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0327 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 63 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0701 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-034 Description: SW-4 Matrix: Aqueous Date Sampled:04/27/2022 1545 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0701 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 92 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1705 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 94 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.8 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 20 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-034 Description: SW-4 Matrix: Aqueous Date Sampled:04/27/2022 1545 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1705 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-035 Description: SW-2 Matrix: Aqueous Date Sampled:04/27/2022 1600 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0725 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-035 Description: SW-2 Matrix: Aqueous Date Sampled:04/27/2022 1600 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0725 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 109 70-130 Toluene-d8 97 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1709 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 14 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-036 Description: SW-2A Matrix: Aqueous Date Sampled:04/27/2022 1615 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 05/03/2022 0351 JMM2 40161 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 11 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0750 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-036 Description: SW-2A Matrix: Aqueous Date Sampled:04/27/2022 1615 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0750 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 90 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 91 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1712 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 34 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.7 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-036 Description: SW-2A Matrix: Aqueous Date Sampled:04/27/2022 1615 Date Received:04/29/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1712 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-037 Description: SW-1 Matrix: Aqueous Date Sampled:04/27/2022 1645 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0814 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 109 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27067-037 Description: SW-1 Matrix: Aqueous Date Sampled:04/27/2022 1645 Date Received:04/29/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/07/2022 0814 BBW 40764 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 94 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 05/03/2022 1716 BNW 04/30/2022 1125 39935 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 11 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 109 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 109 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: XQ39871-001 Matrix: Aqueous Batch:39871 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/29/20221048 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 109 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: XQ39871-002 Matrix: Aqueous Batch:39871 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 41 1 83 70-130 04/29/2022 0946 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 98 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 109 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: XQ40161-001 Matrix: Aqueous Batch:40161 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 05/02/2022 2142 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 109 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: XQ40161-002 Matrix: Aqueous Batch:40161 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 51 1 102 70-130 05/02/2022 2007 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 111 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 109 Volatile Organic Compounds by GC/MS (SIM) - LCSD Sample ID: XQ40161-003 Matrix: Aqueous Batch:40161 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date 1,4-Dioxane 50 44 1 87 15 70-130 20 05/02/2022 2053 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 88 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 109 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40764-001 Matrix: Aqueous Batch:40764 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/07/2022 0115 Acrylonitrile ND 1 20 0.80 ug/L 05/07/2022 0115 Benzene ND 1 1.0 0.40 ug/L 05/07/2022 0115 Bromochloromethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 Bromoform ND 1 1.0 0.40 ug/L 05/07/2022 0115 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/07/2022 0115 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/07/2022 0115 Carbon disulfide ND 1 1.0 0.40 ug/L 05/07/2022 0115 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/07/2022 0115 Chlorobenzene ND 1 1.0 0.40 ug/L 05/07/2022 0115 Chloroethane ND 1 2.0 0.40 ug/L 05/07/2022 0115 Chloroform ND 1 1.0 0.40 ug/L 05/07/2022 0115 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/07/2022 0115 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/07/2022 0115 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/07/2022 0115 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/07/2022 0115 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/07/2022 0115 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0115 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0115 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/07/2022 0115 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/07/2022 0115 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/07/2022 0115 Ethylbenzene ND 1 1.0 0.40 ug/L 05/07/2022 0115 2-Hexanone ND 1 10 2.0 ug/L 05/07/2022 0115 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/07/2022 0115 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/07/2022 0115 Methylene chloride ND 1 1.0 0.40 ug/L 05/07/2022 0115 Styrene ND 1 1.0 0.41 ug/L 05/07/2022 0115 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0115 Toluene ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 Trichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0115 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/07/2022 0115 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/07/2022 0115 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 109 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40764-001 Matrix: Aqueous Batch:40764 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/07/2022 0115 Vinyl chloride ND 1 1.0 0.40 ug/L 05/07/2022 0115 Xylenes (total) ND 1 1.0 0.40 ug/L 05/07/2022 0115 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 109 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40764-002 Matrix: Aqueous Batch:40764 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 130 1 127 60-140 05/06/2022 2210 Acrylonitrile 100 120 1 116 70-130 05/06/2022 2210 Benzene 50 49 1 98 70-130 05/06/2022 2210 Bromochloromethane 50 46 1 93 70-130 05/06/2022 2210 Bromodichloromethane 50 48 1 97 70-130 05/06/2022 2210 Bromoform 50 50 1 100 70-130 05/06/2022 2210 Bromomethane (Methyl bromide) 50 47 1 94 70-130 05/06/2022 2210 2-Butanone (MEK) 100 120 1 118 70-130 05/06/2022 2210 Carbon disulfide 50 50 1 100 70-130 05/06/2022 2210 Carbon tetrachloride 50 48 1 95 70-130 05/06/2022 2210 Chlorobenzene 50 47 1 95 70-130 05/06/2022 2210 Chloroethane 50 54 1 109 70-130 05/06/2022 2210 Chloroform 50 47 1 94 70-130 05/06/2022 2210 Chloromethane (Methyl chloride) 50 50 1 101 60-140 05/06/2022 2210 1,2-Dibromo-3-chloropropane (DBCP) 50 52 1 104 70-130 05/06/2022 2210 Dibromochloromethane 50 47 1 95 70-130 05/06/2022 2210 1,2-Dibromoethane (EDB) 50 49 1 99 70-130 05/06/2022 2210 Dibromomethane (Methylene bromide) 50 48 1 96 70-130 05/06/2022 2210 trans- 1,4-Dichloro-2-butene 50 51 1 102 70-130 05/06/2022 2210 1,2-Dichlorobenzene 50 49 1 97 70-130 05/06/2022 2210 1,4-Dichlorobenzene 50 46 1 93 70-130 05/06/2022 2210 1,1-Dichloroethane 50 49 1 99 70-130 05/06/2022 2210 1,2-Dichloroethane 50 48 1 97 70-130 05/06/2022 2210 1,1-Dichloroethene 50 50 1 99 70-130 05/06/2022 2210 cis- 1,2-Dichloroethene 50 49 1 99 70-130 05/06/2022 2210 trans- 1,2-Dichloroethene 50 48 1 95 70-130 05/06/2022 2210 1,2-Dichloropropane 50 50 1 100 70-130 05/06/2022 2210 cis- 1,3-Dichloropropene 50 53 1 105 70-130 05/06/2022 2210 trans- 1,3-Dichloropropene 50 53 1 105 70-130 05/06/2022 2210 Ethylbenzene 50 53 1 106 70-130 05/06/2022 2210 2-Hexanone 100 120 1 118 70-130 05/06/2022 2210 Methyl iodide (lodomethane) 50 50 1 100 70-130 05/06/2022 2210 4-Methyl-2-pentanone 100 120 1 119 70-130 05/06/2022 2210 Methylene chloride 50 48 1 95 70-130 05/06/2022 2210 Styrene 50 55 1 111 70-130 05/06/2022 2210 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/06/2022 2210 1,1,2,2-Tetrachloroethane 50 50 1 101 70-130 05/06/2022 2210 Tetrachloroethene 50 48 1 96 70-130 05/06/2022 2210 Toluene 50 52 1 105 70-130 05/06/2022 2210 1,1,1-Trichloroethane 50 49 1 99 70-130 05/06/2022 2210 1,1,2-Trichloroethane 50 47 1 94 70-130 05/06/2022 2210 Trichloroethene 50 47 1 93 70-130 05/06/2022 2210 Trichlorofluoromethane 50 50 1 100 70-130 05/06/2022 2210 1,2,3-Trichloropropane 50 47 1 94 70-130 05/06/2022 2210 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 109 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40764-002 Matrix: Aqueous Batch:40764 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 54 1 107 60-140 05/06/2022 2210 Vinyl chloride 50 49 1 97 70-130 05/06/2022 2210 Xylenes (total) 100 110 1 109 70-130 05/06/2022 2210 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 93 70-130 Toluene-d8 90 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 109 Volatile Organic Compounds by GC/MS - LCSD Sample ID: XQ40764-003 Matrix: Aqueous Batch:40764 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Acetone 100 120 1 120 6.4 60-140 20 05/07/2022 0026 Acrylonitrile 100 100 1 103 12 70-130 20 05/07/2022 0026 Benzene 50 46 1 92 6.4 70-130 20 05/07/2022 0026 Bromochloromethane 50 44 1 87 6.2 70-130 20 05/07/2022 0026 Bromodichloromethane 50 46 1 92 4.8 70-130 20 05/07/2022 0026 Bromoform 50 48 1 97 3.4 70-130 20 05/07/2022 0026 Bromomethane (Methyl bromide) 50 42 1 85 10 70-130 20 05/07/2022 0026 2-Butanone (MEK) 100 110 1 114 3.4 70-130 20 05/07/2022 0026 Carbon disulfide 50 42 1 85 17 70-130 20 05/07/2022 0026 Carbon tetrachloride 50 43 1 86 10 70-130 20 05/07/2022 0026 Chlorobenzene 50 45 1 90 5.4 70-130 20 05/07/2022 0026 Chloroethane 50 49 1 97 11 70-130 20 05/07/2022 0026 Chloroform 50 43 1 87 7.3 70-130 20 05/07/2022 0026 Chloromethane (Methyl chloride) 50 46 1 92 9.5 60-140 20 05/07/2022 0026 1,2-Dibromo-3-chloropropane (DBCP) 50 47 1 94 9.7 70-130 20 05/07/2022 0026 Dibromochloromethane 50 46 1 93 1.8 70-130 20 05/07/2022 0026 1,2-Dibromoethane (EDB) 50 48 1 96 2.6 70-130 20 05/07/2022 0026 Dibromomethane (Methylene bromide) 50 46 1 92 4.9 70-130 20 05/07/2022 0026 trans- 1,4-Dichloro-2-butene 50 47 1 95 7.8 70-130 20 05/07/2022 0026 1,2-Dichlorobenzene 50 45 1 89 8.3 70-130 20 05/07/2022 0026 1,4-Dichlorobenzene 50 44 1 87 6.4 70-130 20 05/07/2022 0026 1,1-Dichloroethane 50 45 1 89 10 70-130 20 05/07/2022 0026 1,2-Dichloroethane 50 45 1 91 6.3 70-130 20 05/07/2022 0026 1,1-Dichloroethene 50 43 1 86 14 70-130 20 05/07/2022 0026 cis- 1,2-Dichloroethene 50 45 1 90 9.5 70-130 20 05/07/2022 0026 trans- 1,2-Dichloroethene 50 44 1 89 7.1 70-130 20 05/07/2022 0026 1,2-Dichloropropane 50 48 1 96 4.7 70-130 20 05/07/2022 0026 cis- 1,3-Dichloropropene 50 49 1 99 6.2 70-130 20 05/07/2022 0026 trans- 1,3-Dichloropropene 50 50 1 101 4.3 70-130 20 05/07/2022 0026 Ethylbenzene 50 49 1 99 6.8 70-130 20 05/07/2022 0026 2-Hexanone 100 120 1 122 3.6 70-130 20 05/07/2022 0026 Methyl iodide (lodomethane) 50 42 1 85 17 70-130 20 05/07/2022 0026 4-Methyl-2-pentanone 100 110 1 114 4.2 70-130 20 05/07/2022 0026 Methylene chloride 50 42 1 84 13 70-130 20 05/07/2022 0026 Styrene 50 53 1 105 4.9 70-130 20 05/07/2022 0026 1,1,1,2-Tetrachloroethane 50 45 1 91 7.9 70-130 20 05/07/2022 0026 1,1,2,2-Tetrachloroethane 50 48 1 96 4.5 70-130 20 05/07/2022 0026 Tetrachloroethene 50 44 1 89 7.8 70-130 20 05/07/2022 0026 Toluene 50 49 1 99 6.2 70-130 20 05/07/2022 0026 1,1,1-Trichloroethane 50 44 1 88 11 70-130 20 05/07/2022 0026 1,1,2-Trichloroethane 50 46 1 92 1.8 70-130 20 05/07/2022 0026 Trichloroethene 50 44 1 87 6.5 70-130 20 05/07/2022 0026 Trichlorofluoromethane 50 45 1 90 11 70-130 20 05/07/2022 0026 1,2,3-Trichloropropane 50 47 1 94 0.27 70-130 20 05/07/2022 0026 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 109 Volatile Organic Compounds by GC/MS - LCSD Sample ID: XQ40764-003 Matrix: Aqueous Batch:40764 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Vinyl acetate 50 44 1 89 19 60-140 20 05/07/2022 0026 Vinyl chloride 50 43 1 87 12 70-130 20 05/07/2022 0026 Xylenes (total) 100 100 1 101 7.9 70-130 20 05/07/2022 0026 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 88 70-130 Toluene-d8 85 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 109 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40778-001 Matrix: Aqueous Batch:40778 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/07/2022 0117 Acrylonitrile ND 1 20 0.80 ug/L 05/07/2022 0117 Benzene ND 1 1.0 0.40 ug/L 05/07/2022 0117 Bromochloromethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 Bromoform ND 1 1.0 0.40 ug/L 05/07/2022 0117 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/07/2022 0117 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/07/2022 0117 Carbon disulfide ND 1 1.0 0.40 ug/L 05/07/2022 0117 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/07/2022 0117 Chlorobenzene ND 1 1.0 0.40 ug/L 05/07/2022 0117 Chloroethane ND 1 2.0 0.40 ug/L 05/07/2022 0117 Chloroform ND 1 1.0 0.40 ug/L 05/07/2022 0117 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/07/2022 0117 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/07/2022 0117 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/07/2022 0117 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/07/2022 0117 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/07/2022 0117 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0117 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0117 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/07/2022 0117 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/07/2022 0117 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/07/2022 0117 Ethylbenzene ND 1 1.0 0.40 ug/L 05/07/2022 0117 2-Hexanone ND 1 10 2.0 ug/L 05/07/2022 0117 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/07/2022 0117 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/07/2022 0117 Methylene chloride ND 1 1.0 0.40 ug/L 05/07/2022 0117 Styrene ND 1 1.0 0.41 ug/L 05/07/2022 0117 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0117 Toluene ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 Trichloroethene ND 1 1.0 0.40 ug/L 05/07/2022 0117 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/07/2022 0117 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/07/2022 0117 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 109 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40778-001 Matrix: Aqueous Batch:40778 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl chloride ND 1 1.0 0.40 ug/L 05/07/2022 0117 Xylenes (total) ND 1 1.0 0.40 ug/L 05/07/2022 0117 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 83 70-130 1,2-Dichloroethane-d4 115 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 109 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40778-002 Matrix: Aqueous Batch:40778 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 96 1 96 60-140 05/06/2022 2218 Acrylonitrile 100 100 1 100 70-130 05/06/2022 2218 Benzene 50 48 1 95 70-130 05/06/2022 2218 Bromochloromethane 50 46 1 92 70-130 05/06/2022 2218 Bromodichloromethane 50 49 1 99 70-130 05/06/2022 2218 Bromoform 50 53 1 107 70-130 05/06/2022 2218 Bromomethane (Methyl bromide) 50 51 1 101 70-130 05/06/2022 2218 2-Butanone (MEK) 100 95 1 95 70-130 05/06/2022 2218 Carbon disulfide 50 45 1 90 70-130 05/06/2022 2218 Carbon tetrachloride 50 48 1 96 70-130 05/06/2022 2218 Chlorobenzene 50 48 1 95 70-130 05/06/2022 2218 Chloroethane 50 44 1 87 70-130 05/06/2022 2218 Chloroform 50 46 1 91 70-130 05/06/2022 2218 Chloromethane (Methyl chloride) 50 40 1 79 60-140 05/06/2022 2218 1,2-Dibromo-3-chloropropane (DBCP) 50 51 1 102 70-130 05/06/2022 2218 Dibromochloromethane 50 53 1 106 70-130 05/06/2022 2218 1,2-Dibromoethane (EDB) 50 51 1 101 70-130 05/06/2022 2218 Dibromomethane (Methylene bromide) 50 47 1 93 70-130 05/06/2022 2218 trans- 1,4-Dichloro-2-butene 50 54 1 109 70-130 05/06/2022 2218 1,2-Dichlorobenzene 50 47 1 95 70-130 05/06/2022 2218 1,4-Dichlorobenzene 50 49 1 98 70-130 05/06/2022 2218 1,1-Dichloroethane 50 47 1 94 70-130 05/06/2022 2218 1,2-Dichloroethane 50 47 1 93 70-130 05/06/2022 2218 1,1-Dichloroethene 50 47 1 93 70-130 05/06/2022 2218 cis- 1,2-Dichloroethene 50 46 1 91 70-130 05/06/2022 2218 trans- 1,2-Dichloroethene 50 46 1 91 70-130 05/06/2022 2218 1,2-Dichloropropane 50 49 1 98 70-130 05/06/2022 2218 cis- 1,3-Dichloropropene 50 48 1 96 70-130 05/06/2022 2218 trans- 1,3-Dichloropropene 50 51 1 101 70-130 05/06/2022 2218 Ethylbenzene 50 51 1 103 70-130 05/06/2022 2218 2-Hexanone 100 110 1 113 70-130 05/06/2022 2218 Methyl iodide (lodomethane) 50 45 1 90 70-130 05/06/2022 2218 4-Methyl-2-pentanone 100 110 1 105 70-130 05/06/2022 2218 Methylene chloride 50 46 1 92 70-130 05/06/2022 2218 Styrene 50 49 1 98 70-130 05/06/2022 2218 1,1,1,2-Tetrachloroethane 50 51 1 102 70-130 05/06/2022 2218 1,1,2,2-Tetrachloroethane 50 50 1 100 70-130 05/06/2022 2218 Tetrachloroethene 50 50 1 99 70-130 05/06/2022 2218 Toluene 50 51 1 103 70-130 05/06/2022 2218 1,1,1-Trichloroethane 50 49 1 99 70-130 05/06/2022 2218 1,1,2-Trichloroethane 50 49 1 98 70-130 05/06/2022 2218 Trichloroethene 50 44 1 88 70-130 05/06/2022 2218 Trichlorofluoromethane 50 46 1 92 70-130 05/06/2022 2218 1,2,3-Trichloropropane 50 52 1 104 70-130 05/06/2022 2218 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 109 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40778-002 Matrix: Aqueous Batch:40778 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl chloride 50 42 1 85 70-130 05/06/2022 2218 Xylenes (total) 100 100 1 104 70-130 05/06/2022 2218 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 109 Volatile Organic Compounds by GC/MS - LCSD Sample ID: XQ40778-003 Matrix: Aqueous Batch:40778 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Acetone 100 94 1 94 2.1 60-140 20 05/07/2022 1016 Acrylonitrile 100 100 1 102 2.1 70-130 20 05/07/2022 1016 Benzene 50 54 1 107 12 70-130 20 05/07/2022 1016 Bromochloromethane 50 49 1 98 6.3 70-130 20 05/07/2022 1016 Bromodichloromethane 50 55 1 110 11 70-130 20 05/07/2022 1016 Bromoform 50 59 1 118 9.9 70-130 20 05/07/2022 1016 Bromomethane (Methyl bromide) 50 55 1 110 8.4 70-130 20 05/07/2022 1016 2-Butanone (MEK) 100 94 1 94 1.8 70-130 20 05/07/2022 1016 Carbon disulfide 50 48 1 97 7.6 70-130 20 05/07/2022 1016 Carbon tetrachloride 50 53 1 105 9.2 70-130 20 05/07/2022 1016 Chlorobenzene 50 54 1 108 12 70-130 20 05/07/2022 1016 Chloroethane 50 47 1 93 7.0 70-130 20 05/07/2022 1016 Chloroform 50 49 1 99 7.5 70-130 20 05/07/2022 1016 Chloromethane (Methyl chloride) 50 42 1 84 6.2 60-140 20 05/07/2022 1016 1,2-Dibromo-3-chloropropane (DBCP) 50 55 1 110 7.8 70-130 20 05/07/2022 1016 Dibromochloromethane 50 59 1 118 11 70-130 20 05/07/2022 1016 1,2-Dibromoethane (EDB) 50 58 1 115 13 70-130 20 05/07/2022 1016 Dibromomethane (Methylene bromide) 50 53 1 106 12 70-130 20 05/07/2022 1016 trans- 1,4-Dichloro-2-butene 50 52 1 103 5.4 70-130 20 05/07/2022 1016 1,2-Dichlorobenzene 50 54 1 108 13 70-130 20 05/07/2022 1016 1,4-Dichlorobenzene 50 56 1 112 13 70-130 20 05/07/2022 1016 1,1-Dichloroethane 50 50 1 100 5.9 70-130 20 05/07/2022 1016 1,2-Dichloroethane 50 52 1 105 12 70-130 20 05/07/2022 1016 1,1-Dichloroethene 50 49 1 99 5.5 70-130 20 05/07/2022 1016 cis- 1,2-Dichloroethene 50 48 1 95 4.6 70-130 20 05/07/2022 1016 trans- 1,2-Dichloroethene 50 49 1 97 6.4 70-130 20 05/07/2022 1016 1,2-Dichloropropane 50 55 1 111 12 70-130 20 05/07/2022 1016 cis- 1,3-Dichloropropene 50 49 1 98 2.8 70-130 20 05/07/2022 1016 trans- 1,3-Dichloropropene 50 53 1 105 4.3 70-130 20 05/07/2022 1016 Ethylbenzene 50 58 1 115 11 70-130 20 05/07/2022 1016 2-Hexanone 100 130 1 128 13 70-130 20 05/07/2022 1016 Methyl iodide (lodomethane) 50 47 1 95 4.8 70-130 20 05/07/2022 1016 4-Methyl-2-pentanone 100 110 1 112 6.0 70-130 20 05/07/2022 1016 Methylene chloride 50 50 1 99 7.3 70-130 20 05/07/2022 1016 Styrene 50 56 1 112 13 70-130 20 05/07/2022 1016 1,1,1,2-Tetrachloroethane 50 58 1 116 14 70-130 20 05/07/2022 1016 1,1,2,2-Tetrachloroethane 50 52 1 104 3.9 70-130 20 05/07/2022 1016 Tetrachloroethene 50 57 1 113 13 70-130 20 05/07/2022 1016 Toluene 50 58 1 117 13 70-130 20 05/07/2022 1016 1,1,1-Trichloroethane 50 53 1 105 6.6 70-130 20 05/07/2022 1016 1,1,2-Trichloroethane 50 57 1 114 15 70-130 20 05/07/2022 1016 Trichloroethene 50 54 1 108 20 70-130 20 05/07/2022 1016 Trichlorofluoromethane 50 50 1 100 9.1 70-130 20 05/07/2022 1016 1,2,3-Trichloropropane 50 61 1 123 16 70-130 20 05/07/2022 1016 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 109 Volatile Organic Compounds by GC/MS - LCSD Sample ID: XQ40778-003 Matrix: Aqueous Batch:40778 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Vinyl chloride 50 45 1 90 5.6 70-130 20 05/07/2022 1016 Xylenes (total) 100 120 1 117 11 70-130 20 05/07/2022 1016 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 111 70-130 Toluene-d8 111 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 109 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40823-001 Matrix: Aqueous Batch:40823 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/08/2022 2020 Acrylonitrile ND 1 20 0.80 ug/L 05/08/2022 2020 Benzene ND 1 1.0 0.40 ug/L 05/08/2022 2020 Bromochloromethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 Bromoform ND 1 1.0 0.40 ug/L 05/08/2022 2020 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/08/2022 2020 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/08/2022 2020 Carbon disulfide ND 1 1.0 0.40 ug/L 05/08/2022 2020 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/08/2022 2020 Chlorobenzene ND 1 1.0 0.40 ug/L 05/08/2022 2020 Chloroethane ND 1 2.0 0.40 ug/L 05/08/2022 2020 Chloroform ND 1 1.0 0.40 ug/L 05/08/2022 2020 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/08/2022 2020 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/08/2022 2020 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/08/2022 2020 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/08/2022 2020 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/08/2022 2020 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2022 2020 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2022 2020 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/08/2022 2020 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/08/2022 2020 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/08/2022 2020 Ethylbenzene ND 1 1.0 0.40 ug/L 05/08/2022 2020 2-Hexanone ND 1 10 2.0 ug/L 05/08/2022 2020 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/08/2022 2020 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/08/2022 2020 Methylene chloride ND 1 1.0 0.40 ug/L 05/08/2022 2020 Styrene ND 1 1.0 0.41 ug/L 05/08/2022 2020 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/08/2022 2020 Toluene ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 Trichloroethene ND 1 1.0 0.40 ug/L 05/08/2022 2020 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/08/2022 2020 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/08/2022 2020 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 109 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40823-001 Matrix: Aqueous Batch:40823 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/08/2022 2020 Vinyl chloride ND 1 1.0 0.40 ug/L 05/08/2022 2020 Xylenes (total) ND 1 1.0 0.40 ug/L 05/08/2022 2020 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 81 70-130 1,2-Dichloroethane-d4 115 70-130 Toluene-d8 95 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 109 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40823-002 Matrix: Aqueous Batch:40823 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 120 1 116 60-140 05/08/2022 1929 Acrylonitrile 100 96 1 96 70-130 05/08/2022 1929 Benzene 50 53 1 106 70-130 05/08/2022 1929 Bromochloromethane 50 52 1 103 70-130 05/08/2022 1929 Bromodichloromethane 50 56 1 111 70-130 05/08/2022 1929 Bromoform 50 61 1 123 70-130 05/08/2022 1929 Bromomethane (Methyl bromide) 50 67 N 1 134 70-130 05/08/2022 1929 2-Butanone (MEK) 100 110 1 106 70-130 05/08/2022 1929 Carbon disulfide 50 44 1 89 70-130 05/08/2022 1929 Carbon tetrachloride 50 53 1 106 70-130 05/08/2022 1929 Chlorobenzene 50 52 1 105 70-130 05/08/2022 1929 Chloroethane 50 45 1 90 70-130 05/08/2022 1929 Chloroform 50 50 1 101 70-130 05/08/2022 1929 Chloromethane (Methyl chloride) 50 54 1 108 60-140 05/08/2022 1929 1,2-Dibromo-3-chloropropane (DBCP) 50 56 1 111 70-130 05/08/2022 1929 Dibromochloromethane 50 60 1 120 70-130 05/08/2022 1929 1,2-Dibromoethane (EDB) 50 56 1 113 70-130 05/08/2022 1929 Dibromomethane (Methylene bromide) 50 53 1 105 70-130 05/08/2022 1929 trans- 1,4-Dichloro-2-butene 50 59 1 118 70-130 05/08/2022 1929 1,2-Dichlorobenzene 50 52 1 105 70-130 05/08/2022 1929 1,4-Dichlorobenzene 50 53 1 106 70-130 05/08/2022 1929 1,1-Dichloroethane 50 52 1 103 70-130 05/08/2022 1929 1,2-Dichloroethane 50 53 1 106 70-130 05/08/2022 1929 1,1-Dichloroethene 50 44 1 88 70-130 05/08/2022 1929 cis- 1,2-Dichloroethene 50 50 1 100 70-130 05/08/2022 1929 trans- 1,2-Dichloroethene 50 44 1 88 70-130 05/08/2022 1929 1,2-Dichloropropane 50 55 1 110 70-130 05/08/2022 1929 cis- 1,3-Dichloropropene 50 53 1 105 70-130 05/08/2022 1929 trans- 1,3-Dichloropropene 50 57 1 113 70-130 05/08/2022 1929 Ethylbenzene 50 55 1 110 70-130 05/08/2022 1929 2-Hexanone 100 130 1 126 70-130 05/08/2022 1929 Methyl iodide (lodomethane) 50 42 1 85 70-130 05/08/2022 1929 4-Methyl-2-pentanone 100 110 1 115 70-130 05/08/2022 1929 Methylene chloride 50 45 1 91 70-130 05/08/2022 1929 Styrene 50 53 1 107 70-130 05/08/2022 1929 1,1,1,2-Tetrachloroethane 50 58 1 116 70-130 05/08/2022 1929 1,1,2,2-Tetrachloroethane 50 56 1 111 70-130 05/08/2022 1929 Tetrachloroethene 50 56 1 112 70-130 05/08/2022 1929 Toluene 50 56 1 113 70-130 05/08/2022 1929 1,1,1-Trichloroethane 50 54 1 107 70-130 05/08/2022 1929 1,1,2-Trichloroethane 50 54 1 108 70-130 05/08/2022 1929 Trichloroethene 50 49 1 99 70-130 05/08/2022 1929 Trichlorofluoromethane 50 46 1 92 70-130 05/08/2022 1929 1,2,3-Trichloropropane 50 56 1 113 70-130 05/08/2022 1929 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 109 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40823-002 Matrix: Aqueous Batch:40823 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 53 1 107 60-140 05/08/2022 1929 Vinyl chloride 50 56 1 113 70-130 05/08/2022 1929 Xylenes (total) 100 110 1 113 70-130 05/08/2022 1929 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 102 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 109 ICP-MS Metals - MB Sample ID: XQ39932-001 Matrix: Aqueous Batch: 39932 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2022 1125 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/03/20221023 Arsenic ND 1 2.0 1.3 ug/L 05/03/20221023 Barium ND 1 5.0 1.3 ug/L 05/03/20221023 Beryllium ND 1 0.40 0.15 ug/L 05/03/20221023 Cadmium ND 1 0.50 0.13 ug/L 05/03/20221023 Chromium ND 1 5.0 1.3 ug/L 05/03/20221023 Cobalt ND 1 5.0 1.3 ug/L 05/03/20221023 Copper ND 1 5.0 1.3 ug/L 05/03/20221023 Lead ND 1 1.0 0.25 ug/L 05/03/20221023 Nickel ND 1 5.0 1.3 ug/L 05/03/20221023 Selenium ND 1 5.0 1.3 ug/L 05/03/20221023 Silver ND 1 1.0 0.25 ug/L 05/03/20221023 Thallium ND 1 0.50 0.15 ug/L 05/03/20221023 Vanadium ND 1 5.0 2.5 ug/L 05/03/20221023 Zinc ND 1 10 2.5 ug/L 05/03/20221023 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 109 ICP-MS Metals - LCS Sample ID: XQ39932-002 Matrix: Aqueous Batch: 39932 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2022 1125 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 100 80-120 05/03/20221026 Arsenic 100 100 1 102 80-120 05/03/20221026 Barium 100 98 1 98 80-120 05/03/20221026 Beryllium 100 98 1 98 80-120 05/03/20221026 Cadmium 100 98 1 98 80-120 05/03/20221026 Chromium 100 100 1 102 80-120 05/03/20221026 Cobalt 100 100 1 100 80-120 05/03/20221026 Copper 100 100 1 102 80-120 05/03/20221026 Lead 100 100 1 102 80-120 05/03/20221026 Nickel 100 100 1 102 80-120 05/03/20221026 Selenium 100 110 1 106 80-120 05/03/20221026 Silver 100 100 1 101 80-120 05/03/20221026 Thallium 100 96 1 96 80-120 05/03/20221026 Vanadium 100 100 1 101 80-120 05/03/20221026 Zinc 100 100 1 100 80-120 05/03/20221026 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 109 ICP-MS Metals - MB Sample ID: XQ39935-001 Matrix: Aqueous Batch: 39935 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2022 1125 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/03/20221602 Arsenic ND 1 2.0 1.3 ug/L 05/03/20221602 Barium ND 1 5.0 1.3 ug/L 05/03/20221602 Beryllium ND 1 0.40 0.15 ug/L 05/03/20221602 Cadmium ND 1 0.50 0.13 ug/L 05/03/20221602 Chromium ND 1 5.0 1.3 ug/L 05/03/20221602 Cobalt ND 1 5.0 1.3 ug/L 05/03/20221602 Copper ND 1 5.0 1.3 ug/L 05/03/20221602 Lead ND 1 1.0 0.25 ug/L 05/03/20221602 Nickel ND 1 5.0 1.3 ug/L 05/03/20221602 Selenium ND 1 5.0 1.3 ug/L 05/03/20221602 Silver ND 1 1.0 0.25 ug/L 05/03/20221602 Thallium ND 1 0.50 0.15 ug/L 05/03/20221602 Vanadium ND 1 5.0 2.5 ug/L 05/03/20221602 Zinc ND 1 10 2.5 ug/L 05/03/20221602 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 109 ICP-MS Metals - LCS Sample ID: XQ39935-002 Matrix: Aqueous Batch: 39935 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2022 1125 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 103 80-120 05/03/20221606 Arsenic 100 100 1 102 80-120 05/03/20221606 Barium 100 100 1 102 80-120 05/03/20221606 Beryllium 100 110 1 113 80-120 05/03/20221606 Cadmium 100 100 1 103 80-120 05/03/20221606 Chromium 100 100 1 104 80-120 05/03/20221606 Cobalt 100 100 1 101 80-120 05/03/20221606 Copper 100 100 1 104 80-120 05/03/20221606 Lead 100 100 1 102 80-120 05/03/20221606 Nickel 100 100 1 103 80-120 05/03/20221606 Selenium 100 100 1 104 80-120 05/03/20221606 Silver 100 100 1 104 80-120 05/03/20221606 Thallium 100 98 1 98 80-120 05/03/20221606 Vanadium 100 100 1 103 80-120 05/03/20221606 Zinc 100 100 1 101 80-120 05/03/20221606 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 109 ICP-MS Metals - MS Sample ID: XD27067-026MS Matrix: Aqueous Batch: 39935 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2022 1125 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony ND 100 100 1 104 75-125 05/03/20221620 Arsenic ND 100 100 1 102 75-125 05/03/20221620 Barium 26 100 130 1 101 75-125 05/03/20221620 Beryllium ND 100 110 1 112 75-125 05/03/20221620 Cadmium ND 100 100 1 102 75-125 05/03/20221620 Chromium ND 100 110 1 106 75-125 05/03/20221620 Cobalt ND 100 99 1 99 75-125 05/03/20221620 Copper ND 100 100 1 100 75-125 05/03/20221620 Lead ND 100 100 1 102 75-125 05/03/20221620 Nickel ND 100 99 1 99 75-125 05/03/20221620 Selenium ND 100 100 1 104 75-125 05/03/20221620 Silver ND 100 100 1 104 75-125 05/03/20221620 Thallium ND 100 98 1 98 75-125 05/03/20221620 Vanadium ND 100 100 1 105 75-125 05/03/20221620 Zinc ND 100 99 1 99 75-125 05/03/20221620 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 109 ICP-MS Metals - MSD Sample ID: XD27067-026MD Matrix: Aqueous Batch: 39935 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/30/2022 1125 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony ND 100 100 1 103 0.83 75-125 20 05/03/20221623 Arsenic ND 100 100 1 101 1.4 75-125 20 05/03/20221623 Barium 26 100 120 1 97 3.1 75-125 20 05/03/20221623 Beryllium ND 100 110 1 106 4.7 75-125 20 05/03/20221623 Cadmium ND 100 100 1 101 0.99 75-125 20 05/03/20221623 Chromium ND 100 100 1 105 1.4 75-125 20 05/03/20221623 Cobalt ND 100 98 1 98 0.75 75-125 20 05/03/20221623 Copper ND 100 99 1 99 0.92 75-125 20 05/03/20221623 Lead ND 100 100 1 102 0.86 75-125 20 05/03/20221623 Nickel ND 100 97 1 97 1.6 75-125 20 05/03/20221623 Selenium ND 100 100 1 105 0.93 75-125 20 05/03/20221623 Silver ND 100 100 1 104 0.076 75-125 20 05/03/20221623 Thallium ND 100 98 1 98 0.11 75-125 20 05/03/20221623 Vanadium ND 100 100 1 103 1.8 75-125 20 05/03/20221623 Zinc ND 100 99 1 99 0.51 75-125 20 05/03/20221623 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 109 ICP-MS Metals - MB Sample ID: XQ39965-001 Matrix: Aqueous Batch: 39965 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/01/2022 0531 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 05/03/20221420 Arsenic ND 1 2.0 1.3 ug/L 05/03/20221420 Barium ND 1 5.0 1.3 ug/L 05/03/20221420 Beryllium ND 1 0.40 0.15 ug/L 05/04/20221019 Cadmium ND 1 0.50 0.13 ug/L 05/03/20221420 Chromium ND 1 5.0 1.3 ug/L 05/03/20221420 Cobalt ND 1 5.0 1.3 ug/L 05/03/20221420 Copper ND 1 5.0 1.3 ug/L 05/03/20221420 Lead ND 1 1.0 0.25 ug/L 05/03/20221420 Nickel ND 1 5.0 1.3 ug/L 05/03/20221420 Selenium ND 1 5.0 1.3 ug/L 05/03/20221420 Silver ND 1 1.0 0.25 ug/L 05/04/20221019 Thallium ND 1 0.50 0.15 ug/L 05/03/20221420 Vanadium ND 1 5.0 2.5 ug/L 05/03/20221420 Zinc ND 1 10 2.5 ug/L 05/03/20221420 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 102 of 109 ICP-MS Metals - LCS Sample ID: XQ39965-002 Matrix: Aqueous Batch: 39965 Prep Method: 3005A Analytical Method: 6020B Prep Date: 05/01/2022 0531 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 110 1 107 80-120 05/03/20221424 Arsenic 100 110 1 105 80-120 05/03/20221424 Barium 100 100 1 102 80-120 05/03/20221424 Beryllium 100 99 1 99 80-120 05/04/20221023 Cadmium 100 110 1 105 80-120 05/03/20221424 Chromium 100 110 1 108 80-120 05/03/20221424 Cobalt 100 100 1 104 80-120 05/03/20221424 Copper 100 100 1 104 80-120 05/03/20221424 Lead 100 100 1 103 80-120 05/03/20221424 Nickel 100 100 1 104 80-120 05/03/20221424 Selenium 100 110 1 107 80-120 05/03/20221424 Silver 100 100 1 101 80-120 05/04/20221023 Thallium 100 100 1 100 80-120 05/03/20221424 Vanadium 100 110 1 106 80-120 05/03/20221424 Zinc 100 100 1 102 80-120 05/03/20221424 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 103 of 109 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 104 of 109 '0 �CD � PACE ANALYTICAL. 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Yes Ni) ! 1, WeiC tlMl5 tD 1Y3 perfenrc3 ii5rr.d O[t l]in(Y)C? Ycs q iqc 12. DLd 911 sarn�+les ar."ivi; in the proper cvniain-am for &qri h tost8 &cw in gaud condition (urtbmbl - . lido on, etc_)? Yes No 13. Was adayir�tics3rrlple valrinca,wallable? 1 Yes lvv 14. Were all slL'nplrs MCE�ved Whhin ! Z dte hDlding rinse or 4$ ho,, s, WMcllewcr Comes first? No f 5_ 'Nzre sing sampl; s ooult�iittrns lni spin'excess ;[ i�r lr� one Srimples plat ] iSted ar. CC", 0 Yes ❑ Mo 1 A 16_ ]anr'VIDA and RSK-l75 �swmples, wcm bubbl�4 pnestatt �pccl size' {'rs °ar ftnTl in dlrxmeterj ❑ h an aftha VOA vfa75? cs A'a �i 17. Via a �11 II{O{tnc[aLsfnurr:etst sun pies rcCaid dt s 2? Ye; 7tin ItiA 18.1h'e aii c a[oidc Sam ks necei VW at n pH � 12 and sulfide sarnpics recelvt:d at nH 9? ❑ Yes10 ONAjI9. L}pie a[i [tpplical,le W;�liCi€}&nly,hc�,oll65. 48.3 0.5mr+L1 sarno r� is n itmduaJ chlixiue? _ - - ❑ yip Were client rcmt rks�reuesis {i.i•, ONO NA requeHbcdd°itiiarL�,MSIi41Sf1�desi n�tivtls,etC.,.} ovirectly lranscrihcd fi-ti,rt the COC into Shc carnmeat s�ectiun in iJms+ Yet d No 21. W03 ti�e9uote r_[.r[lbcr liatt'd on the cr)ntaLner ]a0 el? Ifves, QLLOtL H 4r�[nple P�t`a�><tiou (l�]usc $G campTetod r"o,• Inv spier, its tnto:rectl f' ) Y Preser+rcd or with haa&rmce_j�� Satnp: d s) �1 rp poce[yed illcrtrrr�ctly pivserved And were adi usted aoconding)y n arnp[e raixivine wiitlt mi, of circle one- H2SOt4, HNC)3r HCI, NAOH usiag Bit � _NA Trine afp:cse-�+at on `1�, if ntxe tJl: Inc presenati. is treelrxl pleaso rare in `he cOmmcnL; belm�.'- anrle(s} KA were r�cciveJ wits hu�bies >6 -Tim i7 difinteter_ Samples(s) NA We e i er erred x'rth '17ZC' 0.5 its IL (li #19 [s xp 1 and we rc djusled accordingly in sample lei�LiVkk� with satiia,tn thiosu]rate (Na,S,03) wifi Shealy ID; NA SR harcodr labels appl[ed by 'r> t pad: e-QM022 Comments: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 109 0 aceAnalytical Report of Analysis Bunnell-Lammons Engineering, Inc. 6004 Ponders Court Greenville, SC 29615 Attention: Andy Alexander Project Name: Closed Buncombe County Landfill Lot Number:XD27007 Date Completed:05/11/2022 05/20/2022 8:44 AM Approved and released by: Project Manager II: Lucas Odom pCC/►F� 24r�A SOA ANSI National Accreditation Board A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 21 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Bunnell-Lammons Engineering, Inc. Lot Number: XD27007 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. VOCs by GUMS The laboratory control sample (LCS) for analytical batch 40926 exceeded acceptance criteria for Acetone and 2-Butanone. These analytes were biased high but were not detected in the samples affected. Samples have been qualified with an "L" accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 21 PACE ANALYTICAL SERVICES, LLC Sample Summary Bunnell-Lammons Engineering, Inc. Lot Number: XD27007 Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-B Aqueous 04/26/20221430 04/27/2022 002 MW-17-310 Aqueous 04/26/20221600 04/27/2022 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 21 PACE ANALYTICAL SERVICES, LLC Detection Summary Bunnell-Lammons Engineering, Inc. Lot Number: XD27007 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-B Aqueous 1,4-Dioxane 8260D (SIM) 34 ug/L 6 001 MW-B Aqueous Chlorobenzene 8260D 1.2 ug/L 6 001 MW-B Aqueous 1,4-Dichlorobenzene 8260D 1.8 ug/L 6 001 MW-B Aqueous 1,1-Dichloroethane 8260D 1.4 ug/L 6 001 MW-B Aqueous cis- 1,2-Dichloroethene 8260D 16 ug/L 6 001 MW-B Aqueous Vinyl chloride 8260D 9.7 ug/L 7 001 MW-B Aqueous Barium 6020B 190 ug/L 7 002 MW-17-310 Aqueous Barium 6020B 3.2 J ug/L 10 002 MW-17-310 Aqueous Lead 6020B 0.26 J ug/L 10 002 MW-17-310 Aqueous Zinc 6020B 26 ug/L 10 (10 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 21 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27007-001 Description: MW-B Matrix: Aqueous Date Sampled:04/26/2022 1430 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 04/29/2022 1412 JWO 39871 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 34 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 97 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20221355 BWS 40926 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.2 1.0 0.40 ug/L 1 Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L 1 Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.8 1.0 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.4 1.0 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 16 1.0 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 21 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27007-001 Description: MW-B Matrix: Aqueous Date Sampled:04/26/2022 1430 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20221355 BWS 40926 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 9.7 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 109 70-130 1,2-Dichloroethane-d4 113 70-130 Toluene-d8 114 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2022 1446 BPK 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 21 Client: Bunnell-Lammons Engineering, Inc. Laboratory ID:XD27007-001 Description: MW-B Matrix: Aqueous Date Sampled:04/26/2022 1430 Date Received:04/27/2022 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2022 1446 BPK 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 21 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27007-002 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/26/2022 1600 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20221418 BWS 40926 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND L 20 5.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND L 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 21 Client: Bunnell-Lammons Engineering, Inc. Laboratory I D: XD27007-002 Description: MW-17-310 Matrix: Aqueous Date Sampled:04/26/2022 1600 Date Received:04/27/2022 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 05/09/20221418 BWS 40926 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 109 70-130 1,2-Dichloroethane-d4 115 70-130 Toluene-d8 116 70-130 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 04/29/2022 1457 BPK 04/28/2022 0906 39642 2 3005A 6020B 1 05/05/2022 1440 BNW 04/28/2022 0906 39642 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 3.2 J 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 2 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.26 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 26 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 21 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 21 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: XQ39871-001 Matrix: Aqueous Batch: 39871 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 04/29/20221048 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 95 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 21 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: XQ39871-002 Matrix: Aqueous Batch: 39871 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 41 1 83 70-130 04/29/2022 0946 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 98 40-170 ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 21 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40926-001 Matrix: Aqueous Batch:40926 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 05/09/2022 1124 Acrylonitrile ND 1 20 0.80 ug/L 05/09/2022 1124 Benzene ND 1 1.0 0.40 ug/L 05/09/2022 1124 Bromochloromethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 Bromodichloromethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 Bromoform ND 1 1.0 0.40 ug/L 05/09/2022 1124 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 05/09/2022 1124 2-Butanone (MEK) ND 1 10 2.0 ug/L 05/09/2022 1124 Carbon disulfide ND 1 1.0 0.40 ug/L 05/09/2022 1124 Carbon tetrachloride ND 1 1.0 0.40 ug/L 05/09/2022 1124 Chlorobenzene ND 1 1.0 0.40 ug/L 05/09/2022 1124 Chloroethane ND 1 2.0 0.40 ug/L 05/09/2022 1124 Chloroform ND 1 1.0 0.40 ug/L 05/09/2022 1124 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 05/09/2022 1124 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 05/09/2022 1124 Dibromochloromethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 05/09/2022 1124 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 05/09/2022 1124 trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 05/09/2022 1124 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2022 1124 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2022 1124 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 05/09/2022 1124 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2022 1124 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 05/09/2022 1124 Ethylbenzene ND 1 1.0 0.40 ug/L 05/09/2022 1124 2-Hexanone ND 1 10 2.0 ug/L 05/09/2022 1124 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 05/09/2022 1124 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 05/09/2022 1124 Methylene chloride ND 1 1.0 0.40 ug/L 05/09/2022 1124 Styrene ND 1 1.0 0.41 ug/L 05/09/2022 1124 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 Tetrachloroethene ND 1 1.0 0.40 ug/L 05/09/2022 1124 Toluene ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 Trichloroethene ND 1 1.0 0.40 ug/L 05/09/2022 1124 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 05/09/2022 1124 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 05/09/2022 1124 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 21 Volatile Organic Compounds by GC/MS - MB Sample ID: XQ40926-001 Matrix: Aqueous Batch:40926 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Vinyl acetate ND 1 5.0 1.2 ug/L 05/09/2022 1124 Vinyl chloride ND 1 1.0 0.40 ug/L 05/09/2022 1124 Xylenes (total) ND 1 1.0 0.40 ug/L 05/09/2022 1124 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 110 70-130 Toluene-d8 114 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 21 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40926-002 Matrix: Aqueous Batch:40926 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 170 N 1 172 60-140 05/09/2022 0921 Acrylonitrile 100 120 1 125 70-130 05/09/2022 0921 Benzene 50 50 1 99 70-130 05/09/2022 0921 Bromochloromethane 50 49 1 97 70-130 05/09/2022 0921 Bromodichloromethane 50 50 1 100 70-130 05/09/2022 0921 Bromoform 50 48 1 96 70-130 05/09/2022 0921 Bromomethane (Methyl bromide) 50 36 1 72 70-130 05/09/2022 0921 2-Butanone (MEK) 100 140 N 1 142 70-130 05/09/2022 0921 Carbon disulfide 50 54 1 108 70-130 05/09/2022 0921 Carbon tetrachloride 50 51 1 103 70-130 05/09/2022 0921 Chlorobenzene 50 49 1 98 70-130 05/09/2022 0921 Chloroethane 50 47 1 93 70-130 05/09/2022 0921 Chloroform 50 50 1 101 70-130 05/09/2022 0921 Chloromethane (Methyl chloride) 50 49 1 97 60-140 05/09/2022 0921 1,2-Dibromo-3-chloropropane (DBCP) 50 56 1 112 70-130 05/09/2022 0921 Dibromochloromethane 50 49 1 98 70-130 05/09/2022 0921 1,2-Dibromoethane (EDB) 50 50 1 100 70-130 05/09/2022 0921 Dibromomethane (Methylene bromide) 50 49 1 98 70-130 05/09/2022 0921 trans- 1,4-Dichloro-2-butene 50 56 1 112 70-130 05/09/2022 0921 1,2-Dichlorobenzene 50 49 1 98 70-130 05/09/2022 0921 1,4-Dichlorobenzene 50 48 1 95 70-130 05/09/2022 0921 1,1-Dichloroethane 50 54 1 109 70-130 05/09/2022 0921 1,2-Dichloroethane 50 50 1 99 70-130 05/09/2022 0921 1,1-Dichloroethene 50 53 1 105 70-130 05/09/2022 0921 cis- 1,2-Dichloroethene 50 53 1 106 70-130 05/09/2022 0921 trans- 1,2-Dichloroethene 50 53 1 105 70-130 05/09/2022 0921 1,2-Dichloropropane 50 54 1 108 70-130 05/09/2022 0921 cis- 1,3-Dichloropropene 50 54 1 108 70-130 05/09/2022 0921 trans- 1,3-Dichloropropene 50 53 1 106 70-130 05/09/2022 0921 Ethylbenzene 50 51 1 101 70-130 05/09/2022 0921 2-Hexanone 100 120 1 124 70-130 05/09/2022 0921 Methyl iodide (lodomethane) 50 49 1 97 70-130 05/09/2022 0921 4-Methyl-2-pentanone 100 120 1 120 70-130 05/09/2022 0921 Methylene chloride 50 53 1 105 70-130 05/09/2022 0921 Styrene 50 45 1 89 70-130 05/09/2022 0921 1,1,1,2-Tetrachloroethane 50 49 1 98 70-130 05/09/2022 0921 1,1,2,2-Tetrachloroethane 50 51 1 103 70-130 05/09/2022 0921 Tetrachloroethene 50 48 1 96 70-130 05/09/2022 0921 Toluene 50 50 1 101 70-130 05/09/2022 0921 1,1,1-Trichloroethane 50 51 1 103 70-130 05/09/2022 0921 1,1,2-Trichloroethane 50 49 1 99 70-130 05/09/2022 0921 Trichloroethene 50 49 1 99 70-130 05/09/2022 0921 Trichlorofluoromethane 50 48 1 96 70-130 05/09/2022 0921 1,2,3-Trichloropropane 50 50 1 100 70-130 05/09/2022 0921 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 21 Volatile Organic Compounds by GC/MS - LCS Sample ID: XQ40926-002 Matrix: Aqueous Batch:40926 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Vinyl acetate 50 58 1 116 60-140 05/09/2022 0921 Vinyl chloride 50 45 1 90 70-130 05/09/2022 0921 Xylenes (total) 100 100 1 103 70-130 05/09/2022 0921 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 101 70-130 1,2-Dichloroethane-d4 101 70-130 Toluene-d8 103 70-130 LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 21 ICP-MS Metals - MB Sample ID: XQ39642-001 Matrix: Aqueous Batch: 39642 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/28/2022 0906 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony ND 1 2.0 0.50 ug/L 04/29/20221339 Arsenic ND 1 2.0 1.3 ug/L 04/29/20221339 Barium ND 1 5.0 1.3 ug/L 04/29/20221339 Beryllium ND 1 0.40 0.15 ug/L 04/29/20221339 Cadmium ND 1 0.50 0.13 ug/L 04/29/20221339 Chromium ND 1 5.0 1.3 ug/L 04/29/20221339 Cobalt ND 1 5.0 1.3 ug/L 04/29/20221339 Copper ND 1 5.0 1.3 ug/L 04/29/20221339 Lead ND 1 1.0 0.25 ug/L 04/29/20221339 Nickel ND 1 5.0 1.3 ug/L 04/29/20221339 Selenium ND 1 5.0 1.3 ug/L 04/29/20221339 Silver ND 1 1.0 0.25 ug/L 04/29/20221339 Thallium ND 1 0.50 0.15 ug/L 04/29/20221339 Vanadium ND 1 5.0 2.5 ug/L 04/29/20221339 Zinc ND 1 10 2.5 ug/L 04/29/20221339 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 21 ICP-MS Metals - LCS Sample ID: XQ39642-002 Matrix: Aqueous Batch: 39642 Prep Method: 3005A Analytical Method: 6020B Prep Date: 04/28/2022 0906 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 97 1 97 80-120 04/29/20221343 Arsenic 100 97 1 97 80-120 04/29/20221343 Barium 100 95 1 95 80-120 04/29/20221343 Beryllium 100 97 1 97 80-120 04/29/20221343 Cadmium 100 96 1 96 80-120 04/29/20221343 Chromium 100 98 1 98 80-120 04/29/20221343 Cobalt 100 96 1 96 80-120 04/29/20221343 Copper 100 99 1 99 80-120 04/29/20221343 Lead 100 97 1 97 80-120 04/29/20221343 Nickel 100 97 1 97 80-120 04/29/20221343 Selenium 100 96 1 96 80-120 04/29/20221343 Silver 100 97 1 97 80-120 04/29/20221343 Thallium 100 96 1 96 80-120 04/29/20221343 Vanadium 100 97 1 97 80-120 04/29/20221343 Zinc 100 97 1 97 80-120 04/29/20221343 LOQ = Limit of Quantitation DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 21 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 21 �0 ID m D vv - 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Eebenaxryw-%ti x+dby rds ram'€ rut, v fiiffadmv pr, be (G" No :e Pack € Rc:stu Number Crxrs.rvc F�-:,,,, - i . j 3 0 " �6IMNAlydply X0 7007 W{ �- OG f3e��eme.�,s f�p'e+Cr7�fl rc rma Dry Tn-Ae Asb Lr.,� `1f- 7 Term biqjrh' I Y :. fd i:aeLm_Yi! hi�mbr.F: h{F,�3h'2-0? 1 ■ m D r \ J r U) m C/) r r C� PACE ANALYTICAL SERVICES, LLC Sarnpl2sReceipt Check list ISRC}(MEoo>L 1-51 2�evi5ed:-WZ9f2020 aye 4rTolRr^a� Jzsulna Autric ri ty_ I'azP =NV- WCOL Page 3 of Z Sllmple Receipt Cheekflrst (SRCt cbwa: > L,h C'eolar Tnz 7,P—x d by.'date: RSS I -�4,127j2ARZ l.at u. XD27ao7 M,eansOFre�L:eipt: PnGG C=ietlt TJIrS fCijl ]C f�Cli r, Ycs No 0. Wom cas7ody bt hL Txr�cw an 1hC Ci7QJer8 ✓ Yes 1�T4 NFL 2, Ifcust-kL1 • seHrs wera re3enL, 4trcrc they intact and unbrokertc VIA Sttip 1D: 21-95a _ C-1Wine 81. Jp ID: °#� _ Tcstcd bv:1L55 Original demperartu'-a tlpLrn receipt i Dcriwd (CaU,�Lt Lunperature upon receip' %Solid Snap-CLLP ID; �A 3.? 13.7 1.4 f Nfs c 'ttiA 7NA oe NA fNA aC -" Metltad; ❑TLanpwrsrJ-a I31aflk LVJkgainsL riottlos IR- Curi Ili ' 1K GUE! Crlkrel;jjQn h'asit3u'_ Method of ; oolan r © Wet IcC ❑ let P9L::ka ❑ Dry Tres � 1Noge � 3 Iryl YL:E ❑Flo �NA. ` tmpcTalam of ally cooler e><c�erka 6.011C. was Pr�jcct lAmLastr�la, Mod? PM was Nuffed hy. phone ! emair 1 fu=.to-rSre (ou-cle ci L)_ iE�� N, 4. Is the conimnu crcial crier's ckiii, slip attacbed to thi.k IbFm? 5, 'Were proTx,r rustodv prcx> Beres (relinqujShed,Wcej%,0a) followcd1 5 Np . Nn ere lampic• 11]s listed m the COC? ,� Yes I ❑No -i' Ware samplc IN listed im i'i sample contaiTi ml 1 Y.=s 11 No 8. Was CuLlrul ia,n date & time listed on the COC:'+ Yvis U 1jo _ W-9s C pl LeCLlon date drat li 5`bd OLt 9 J I yWTLRIC 120nta'r"? lros ❑ 1tio 10. Uid a I I cantaina_ lal : Lirg ;r adon OD, datc, tithe) n?,rca; with the CDC? J Y C.31 El Nn, I - . Wei a :m'A to be eLfgrm�j listed ark the CGC? D Y♦i5 M No L—[ L2- J11d' all farrple~ arrNe ill 113e proper container$ fnr r�c1l teA and&w iTI gchcKj C61Ld;tWn (unbroken, lkb- on, ctc.)? . 0 y 1 N�'0 13. Wus adrq'tate Barr in volimie availaU:V U No I rl , Were aLl si tmpl�u recoj%-ed with hi'f the 111131clinZ t%rTr; or 48 kLJrC, vrlt'chevcr caeles fLrst? Yes vr No 15_ Were any saT Jes cuntaine,'a rpiNrin}+ rcess (iircic one)samples Nict listed plL ODC? [>] Na [—]NA �] Yes 16. Par VQA and R5I{-J 75 samples- weTe bubbles r;resent :-3ea-3iae" (? J"uf bmm in diaflncsler) in Rnv of tfie N10A vials? No A 17, Wcm a:i f)RDhne.a'sfnutrie,tt wrnpics received at a pH of < 27 No .6 NA 18, +-;rC all -anidc scruples n uL!ivvd at a pH > 12 and sul ride sanar ❑ Yesi ❑ N aJ ❑J NA Mod at El pi-1 > 9? sarrmlm fto of �.�yes [—]No 71NA 20' WereClkMI--C-n1LI7k9!rCCUeMS (i,e_ r�U9leidi:utions, R4SlLviS�de_si&IaLions, etc_ correct.y' Cwsca'ibed frorn the C'OC illtt, LN; comment 4=Akyn it LIMY Yet; 'No J2 _ WPLL iht� n uote number listied oil the confa finer law? ii vos, Quiklc 4 5aknpie Preservetirkn (Must -�c GDmplated for anv salnple(s) irlcarr�;rdy pL+gervnf ur witlr Mudbp L!e.) mple(s) N,1— _._Wt m Taocivekd inL:orrcetly p *served s -id were adjusted accordingly sample raccivbV with NA rr,L i f c irck onc: I-i 25CA1, I -IN o -: , HCI, NtTOH using 5 R .4 NA Ine of prtscrvatian 14A _ Tf marl than nne I re5rrwative is L1ee€jr ,please no0e Irl rho CornL le1115 bclaw_ wet'e L .„:vcd uric1 bUh€ lr-q>6 mm is diamtcr, 1 kplM(s) NA WCCC MCCiV1Zt1 with 'l RC x 0.5 114), (If A 19 is no ) and were usu d stt:aordingly in oanLplc N=iYin$ with ;odium Th:osLdfbk [i%13yS2N witF Shealy TD: baroodo labels appliod by; TFC. Con3rient5: Dale: C''J27,' QM Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 21