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HomeMy WebLinkAbout1403_Caldwell_Foothills_MSWLF_July22GW_FID1717471_20220906REPUBLIC sE► MES September 6, 2022 Ms. Jaclynne Drummond Hydrogeologist Solid Waste Section Division of Waste Management North Carolina Department of Environmental Quality 2090 US Highway 70 Swannanoa, North Carolina 28778 RE: Second Semi -Annual Water Quality Monitoring Report of 2022 Foothills Regional Landfill, Permit No. 14-03 Caldwell County, North Carolina Dear Ms. Drummond: Republic Services of North Carolina, LLC is submitting the Second Semi -Annual Water Quality Monitoring Report of 2022 for the Foothills Regional Landfill and Environmental Monitoring Reporting Form in electronic format. The report completes the second semi-annual compliance monitoring event of 2022 for the Foothills Regional Landfill, Permit No. 14-03, as required by the North Carolina Division of Waste Management, Solid Waste Section. If you have any questions, please contact Steve Jett with Jett Environmental Consulting at (314) 496-4654, or me at (314) 302-3634. Sincerely, Republic Services of North Carolina, LLC 2022.09.06 10:32: 34-04'00' Mr. Derek Bouchard Environmental Manager Enclosure cc: Stephen Hunter, Foothills Regional Landfill, Republic Services Joe Montello, Republic Services Steve Jett, Jett Environmental Consulting Page 1 of 1 DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Jett Environmental Consulting, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Steve Jett E-mail: steve.jett@jettenviro.com Phone: (314) 496-4654 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Foothills Regional Landfill 2800 Cheraw Road 14-03 .0500 July 25-26, 2022 Lenoir, NC 28645 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steve Jett Owner (314) 496-4654 Facility Representative Name (Print) f/j A a Title (Area Code) Telephone Number Signature 09/06/2022 Date Jett Environmental Consulting, PLLC, 18 Lexington Oaks Court, Foristell, MO 63348 Facility Representative Address NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal Groundwater Statistical Analysis Report Second Semi -Annual 2022 Sampling Event Foothills Regional Landfill Caldwell County, North Carolina September 2022 Prepared by: 4 0 JETT ENVIRONMENTAL CONS U LT ING 18 Lexington Oaks Court 314-496-4654 Foristell, MO 63348 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK................1 3.0 SITE HYDROGEOLOGY................................................................2 4.0 DATA EVALUATION......................................................................3 5.0 STATISTICAL PROCEDURES.......................................................3 5.1 Outlier Analysis...........................................................................4 5.2 Inter -Well Prediction Intervals....................................................4 5.3 Intra-Well Confidence Limits......................................................4 5.4 Statistical Results Summary.......................................................5 6.0 CONCLUSIONS..............................................................................5 7.0 RECOMMENDATIONS...................................................................6 Table 1 Groundwater Monitoring Program Table 2 Groundwater Analytical Data Summary Table 3 Surface Water Analytical Data Summary Table 4 Underdrain Analytical Data Summary Table 5 Leachate Analytical Data Summary APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Reports & Field Sampling Forms Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Foothills Regional Landfill, Jett Environmental Consulting statistically evaluated the Second Semi -Annual 2022 water quality monitoring data. Groundwater, surface water, underdrain, and leachate sampling were completed by Environmental Sampling & Services, Inc. (ES&S) on July 25-26, 2022, and analytical testing was performed by Pace Analytical Services, LLC. The statistical analysis software package utilized, Sanitasr', follows a documented decision logic that incorporates the following applicable document: USEPA "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance" (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK In compliance with North Carolina Department of Environmental Quality (DEQ) Solid Waste Management Regulations, Section .1600 "Requirements for Municipal Solid Waste Landfill Facilities," Jett Environmental Consulting statistically evaluated parameters from the Second Semi -Annual 2022 event using inter -well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. The facility's monitoring network is comprised of eleven monitoring wells: MW-1 R2 (background), MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, and MW-11, which monitor the uppermost aquifer beneath the facility. The monitoring wells are sampled on a semi-annual basis, with the groundwater samples submitted to a qualified laboratory for required analyses in accordance with the facility's environmental monitoring program and permit requirements. The monitoring wells are equipped with dedicated bladder pumps and were purged and sampled via the low -flow method. Table 1 lists the groundwater monitoring wells for the site. Each of the wells was sampled during the Second Semi -Annual 2022 event. Groundwater monitoring was initiated in August 1998. Statistical background is defined as samples collected from former upgradient well MW-1, former upgradient well MW-1 R, and current upgradient well MW-1 R2 from 1998 through the current event. The parameters subject to statistical evaluation during detection monitoring are noted in DEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 "Constituents for Detection Monitoring". The following is a chronology of well replacement and abandonment. Well MW-3R2 was added to the monitoring well network on August 17, 2006 as a replacement well for MW-3 and MW-3R. Monitoring wells MW-3 and MW-3R remain for water level data collection purposes only. Monitoring well MW-7 was installed in April 2010 to monitor groundwater beneath Cell 4, which began receiving waste in September 2010. MW-8 was installed in April 2013 to monitor Cell 8A, which was constructed in January 2013. MW-10 was installed in October 2015 to monitor Cell 5A. The former background well MW-1 was abandoned in preparation for construction of Cell 5A and the new background well, MW-1 R, was installed in October 2015. MW-9 was installed June 2016 to monitor Cell 5A. Soil and bedrock removal in the Northern Borrow Area rendered well MW-1 R dry and inaccessible. Therefore, a replacement monitoring well (MW-1 R2) was installed in September 2018. New well MW-11 was also installed in September 2018 as part of the Cell No. 5B construction. The site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and four downstream points (SW-2, SW-3, SW-4, and SW-5). These points are sampled semi- annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. Each surface water monitoring point was sampled during the Second Semi -Annual 2022 event. A sample point from the underdrain for Cell 1 (LID-1) was added to the monitoring program prior to the January 2008 sampling event. A sample point from the underdrain for Cells 4 and 8A (LID-2) was added to the monitoring program prior to the January 2014 sampling event. The underdrains are to be sampled Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 2 semi-annually (contingent on flow availability) for the 40 CFR Part 258 Appendix I list. Both underdrains were able to be sampled during the Second Semi -Annual 2022 event. A leachate sample is also routinely collected for analysis. The leachate sample was analyzed for the 40 CFR Part 258 Appendix I list, biochemical oxygen demand, chemical oxygen demand, nitrate as N, nitrite as N, phosphorus, and sulfate. In accordance with a November 28, 2018 DEQ letter, 1,4-dioxane is no longer required be analyzed for the groundwater and surface water samples; however, will be analyzed annually for the leachate sample. The leachate was sampled and analyzed for 1,4-dioxane during the First Semi -Annual 2022 (annual) event. The facility was in an Assessment Monitoring Program in 2006. An Alternate Source Demonstration (ASD) for volatile organic compounds (VOCs) detected in wells MW-3 and MW-3R was approved by DEQ on December 14, 2006, and the facility reverted to a Detection Monitoring Program. An ASD for cobalt and a request to use background as the groundwater protection standard (GWPS) for cobalt was submitted to the DEQ in November 2016. The ASD is currently under DEQ review. An ASD for benzene and vinyl chloride at MW-2R was submitted to DEQ in June 2017; however, it was not approved in a letter from DEQ dated October 11, 2017 and Assessment Monitoring was initiated. Therefore, during the First Semi -Annual 2018 event, the initial Appendix II Assessment constituent list was sampled at each well. The constituents detected at quantifiable concentrations (barium, benzene, and cobalt) were consistent with past events and also on the Appendix I Detection Monitoring list. On May 18, 2018, the site requested deleting all non -Appendix I monitoring from future sampling events, with the exception of well MW-2R, which will continue with annual Appendix 11 monitoring. In correspondence dated July 9, 2018, DEQ approved the request to only include MW-2R for future annual Appendix II monitoring. The annual Appendix II monitoring for MW-2R was performed during the First Semi -Annual 2022 event. No Appendix 11 constituents, not also on the Appendix I list, were detected above their respective PQLs during the First Semi -Annual 2022 event. The next annual Appendix 11 sampling event for MW-2R will be the First Semi -Annual 2023 (January 2023) event. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Geologically, the facility is located in the northwestern portion of the Inner Piedmont Belt of the Piedmont Physiographic Province, approximately 20 miles east of the thrust belt (Brevard Shear Zone) delineating the boundary between the westerly Blue Ridge Belt and the easterly Inner Piedmont Belt. The metamorphic rocks of the Inner Piedmont Belt generally group within the sillimanite facies of the amphibolite metamorphic sequence. Locally, the bedrock underlying the facility has been mapped as migmatitic granitic gneiss of the Ordovician and older Cambrian Periods. These rocks are described as ranging in composition from granitic to quartz dioritic with smaller biotite gneiss and amphibolite facies present locally. The unit as a whole exhibits a variable massive to foliated fabric. The uppermost aquifer beneath the facility is present within weathered bedrock saprolite and fractured bedrock. The saprolite ranges in texture from clayey silt in the upper, most weathered sections to micaceous sandy silt in the lower sections. Immediately above the competent bedrock surface, a variable thickness transitional zone composed of highly weathered and degraded friable bedrock is present. The uppermost aquifer is laterally continuous across the site, with depth to water ranging from less than 31 feet in low-lying areas to greater than 77 feet beneath topographic highs. Groundwater in the uppermost aquifer generally flows from recharge areas associated with broad gently sloping topographic areas towards topographically lower areas that are generally delineated by the presence of stream channels, some of which are perennial receiving streams (groundwater discharge areas) and others of which are intermittent Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 3 discharging streams. In the vicinity of the facility, the general groundwater flow direction is towards the south and west. Appendix A provides a potentiometric surface map utilizing groundwater level data from the Second Semi - Annual 2022 event. Groundwater flow direction for the Second Semi -Annual 2022 event was to the southwest, which is consistent with previous interpretations for this facility. Groundwater flow rate for the Second Semi -Annual 2022 event was estimated at 168 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION Appendix C contains a copy of the laboratory analytical report and field sampling forms for the Second Semi -Annual 2022 groundwater, surface water, underdrain, and leachate sampling event. The analytical results for the Second Semi -Annual 2022 event for the groundwater, surface water, underdrain, and leachate samples are summarized on Tables 2, 3, 4, and 5, respectively. One VOC was detected at a quantified concentration at or above a PQL: benzene at MW-2R. The trace level VOC detection is typical for the site. As shown on Table 2, two Appendix I inorganic constituents (barium at MW-2R, MW-5, and MW-6; and cobalt at MW-4) were detected at quantified concentrations. Two Appendix I constituents (benzene at MW-2R and cobalt at MW-4) were detected above an NC 2L Standard during the Second Semi -Annual 2022 sampling event. Per 15A NCAC 02L .0202(b)(1), for the NC 2L Standards, only detections of a substance at or above the PQL can constitute a violation of the standard. Therefore, estimated values below the PQL are not considered a violation of a NC 2L Rule standard. As shown on Table 3, during the Second Semi -Annual 2022 event, no inorganics were detected in surface water samples at quantified concentrations above a respective NC 2B Surface Water Standard. No VOCs were detected in surface water samples at quantified concentrations above their respective PQLs during the Second Semi -Annual 2022 event (see Table 3). During the Second Semi -Annual 2022 event, no VOCs were detected in the underdrain samples at quantified concentrations above their respective PQLs (see Table 4). The constituents detected in the leachate sample collected during the Second Semi -Annual 2022 event were typical for leachate at this facility (see Table 5). 5.0 STATISTICAL PROCEDURES Statistical analyses (i.e., inter -well prediction limits) were performed to establish background concentrations and determine if the 2L Standard value -to -value exceedances for cobalt exhibited a statistically significant increase (SSI). Statistical analyses (i.e., lower confidence limits) were performed to determine if the 2L Standard value -to -value exceedance for benzene statistically exceeded the 2L Standard. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 4 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the USEPA Unified Guidance. Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According to the USEPA Unified Guidance above, data that are not normally or log -normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log -normally distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Inter -Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, inter -well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are non -detects, the non -detects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data's sample mean and standard deviation are adjusted according to the Kaplan -Meier method. However, when the background data are not transformed -normal or contain greater than 50% observations below the reporting limit, SanitasTm automatically constructs a non -parametric prediction interval. During non -parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Due to the wide range of laboratory reporting limits utilized over time, the historical reporting limits were conservatively replaced with the current event reporting limit prior to performing statistical analyses. Summary tables and graphs for the inter -well prediction interval analysis are available in Appendix B. Included in Appendix B are time series plots for each of the inorganic constituents. For the Second Semi -Annual 2022 event, one inorganic SSI was exhibited for cobalt at MW-4. The Second Semi -Annual 2022 concentration of total cobalt at MW-4 (14.1 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). An ASD for cobalt and a request to use background for the Groundwater Protection Standards (GWPSs) was submitted to the DEQ by the site on November 4, 2016. The statistical background value for cobalt was determined to be 44.1 ug/L based on an Upper Poisson Prediction Limit, which is higher than the detected concentration at MW-4. The ASD requested that the background value be considered the GWPS for cobalt per 15A NCAC13B.1634.(g).5. The ASD is currently under DEQ review. 5.3 Intra-Well Confidence Limits Per DEQ Regulation .1634(H), GWPSs are equal to the National Primary Drinking Water Standard - Maximum Contaminant Level (MCL) or North Carolina 15A NCAC 2L Water Quality Standard, whichever is lower. In instances where an MCL or 2L Standard are not established, the GWPSs were derived from the DEQ-Solid Waste Section published GWPSs. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 5 In order to determine if the groundwater concentrations exhibit a statistical exceedance of the GWPS, a statistical comparison was made to the GWPSs to determine if further action is warranted. The following text outlines the procedures that were used to statistically compare concentrations to GWPSs. Per the USEPA Unified Guidance, a Confidence Interval is constructed from sample data and is designed to contain the mean concentration of a well analyte in groundwater monitoring, with a designated level of confidence. A confidence interval generally is used when samples are being compared to a GWPS, which is typically the MCL or alternate limit (i.e., 2L Standard). A lower confidence interval analysis was used to statistically compare to GWPSs. The method constructs a normal confidence interval on the mean concentration of a constituent incorporating, at a minimum, the four most recent measurements. The lower confidence interval on the mean was compared to the GWPS to determine whether the mean concentration exceeded its GWPS. If the lower confidence interval on the mean exceeds the GWPS then there is statistically significant evidence that the mean concentration of that constituent exceeds the GWPS. The distribution of the data is evaluated by applying the Shapiro -Wilk or Shapiro -Francis test for normality to the raw data or, when applicable, transformed data. If less than 15 percent of the observations are non - detects, the non -detects will be replaced with one half the reporting limit prior to performing the normality test and constructing the confidence limit. Per .1634(g)(5), if background (statistical limit based on upgradient well data) is higher than the 2L Standard, then background may be utilized as the GWPS. Background for organics is considered the non - detect level (equivalent to the PQL). Organic concentrations detected above PQLs and GWPSs (See Table 2) were statistically compared to their respective GWPSs utilizing intra-well lower confidence limits. As provided in Appendix B, benzene at MW-2R statistically exceeded the GWPS for the Second Semi -Annual 2022 event, consistent with recent events. Time series graphs for VOC detections during recent events are provided in Appendix B. 5.4 Statistical Results Summary For the Second Semi -Annual 2022 event, one inorganic SSI was exhibited for cobalt at MW-4. The Second Semi -Annual 2022 concentration of total cobalt at MW-4 (14.1 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). However, cobalt concentrations at MW-4 have been decreasing since the July 2012 event (25.4 ug/L). Intra-well lower confidence limits determined benzene at MW-2R (3.2 ug/L) statistically exceeded the GWPS (1.0 ug/L) for the Second Semi -Annual 2022 event, consistent with recent events. Benzene concentrations at MW-2R have been reported at varying low levels (1.0 to 3.2 ug/L) since the July 2016 event. 6.0 CONCLUSIONS For the Second Semi -Annual 2022 event, one inorganic SSI was confirmed exhibited for cobalt at MW-4, consistent with recent events. One Appendix I constituent (benzene at MW-2R) was confirmed detected above an NC 2L Standard during the Second Semi -Annual 2022 sampling event. Intra-well lower confidence limits determined benzene at MW-2R statistically exceeded the GWPS for the Second Semi -Annual 2022 event, consistent with recent events. Benzene concentrations at MW-2R have been reported at varying low levels (1.0 to 3.2 ug/L) since the July 2016 event. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 6 During the Second Semi -Annual 2022 event, no Appendix I VOCs were confirmed detected in surface water and underdrain samples at quantifiable concentrations. No inorganics were detected in surface water samples at quantified concentrations above a respective NC 2B Surface Water Standard during the Second Semi -Annual 2022 event. The Foothills Regional Landfill will continue monitoring in accordance with the requirements for Detection and Assessment Monitoring as outlined in Title 15A NCAC 13B .1633 and .1634, respectively. The next semi-annual event is scheduled for January 2023. 7.0 RECOMMENDATIONS Wells in the proximity of MW-2R exist directly upgradient (MW-9) and directly downgradient (MW-3R2). No VOCs have been confirmed detected at quantified concentrations at MW-9 or MW-3R2; therefore, the extent of quantified VOC detections (i.e., benzene) has been defined to only MW-2R. As described in the site's June 2017 ASD for benzene/vinyl chloride at MW-2R, the VOCs appear to be related to landfill gas. Wells MW-9, MW-2R, and MW-3R2 would effectively cover the exterior perimeter of the cell (Cell 1A) suspected as the source of potential gas migration. The site implemented landfill gas extraction and collection upgrades in the Cell 1A area in late 2017 and installed a horizontal active landfill gas collection/mitigation trench in the vicinity of MW-2R in Fall 2018 (see map in Appendix A). Additional groundwater monitoring events are recommended before any further actions are considered to determine if benzene levels at MW-2R (3.2 ug/L) decrease to levels below the lab PQL (1.0 ug/L) as a result of the landfill gas system upgrades. It is recommended that well MW-4 continues in Detection Monitoring. The decrease in concentration of cobalt at MW-4 from 25.4 ug/L in July 2012 to 14.1 ug/L during the Second Semi -Annual 2022 event, indicates a decreasing trend near the laboratory PQL (10 ug/L). Since the landfill is lined, it is unlikely the cobalt detections are related to a landfill release. The lack of receptors of water use in this shallow well, which would not feasibly produce a well with sufficient yield for potable use, is evidence of a lack of risk associated with this level of detection. Cobalt is naturally occurring at the site, evident by the historical cobalt detections in various wells across this site, and is a common element occurring naturally in minerals commonly found in the bedrock, soil, and sediments in the North Carolina Piedmont. According to A Geochemical Atlas of North Carolina (by Jeffery C. Reid, dated 1993 in the North Carolina Geological Survey's Bulletin 93), which displays the distribution of cobalt in stream sediments across the state, Caldwell County has been highlighted. Cobalt was found at concentrations as high as 10 mg/kg throughout Caldwell County; with a significant amount of variability. Metals in the soil and bedrock can easily leach into the groundwater, especially if the groundwater is acidic (pH < 7.0). The pH of groundwater samples from the Foothills Regional Landfill during the Second Semi - Annual 2022 sampling event ranged from 5.29 to 7.98 SU. The pH of the sample from MW-4, which had the highest cobalt concentration, was 5.29 SU. Review of leachate data for the last 12 years indicates cobalt has ranged from J 7.3 to J 43.7 ug/L, with an average concentration of 24.8 ug/L. The occurrence and levels of cobalt at the site has no indication of being related to a release from the waste unit. The site recommends utilizing the upcoming First Semi -Annual 2023 (January 2023) event to continue to verify the downward/stable trends of cobalt levels at MW-4 and benzene at MW-2R, since levels are approaching the laboratory PQL of 10 ug/L and 1.0 ug/L, respectively. The proposed actions are protective of human health and the environment and the values at this time do not further action, especially for a naturally occurring element (cobalt). TABLES TABLE 1 GROUNDWATER MONITORING PROGRAM SECOND SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL UPGRADIENT WELLS DOWNGRADIENT WELLS MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-1 R2 MW-8, MW-9, MW-10, MW-11 TABLE 2 GROUNDWATER ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units 2L Std MDL PQL MW-1R2 MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 Antimony Total u /L 1 0.78 6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 Arsenic Total u /L 10 2.2 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Barium Total u /L 700 0.67 100 62.1J 312 4.0J 47.1J 140 115 77AJ 77.3J 15.5J 25.9J 91.3J Beryllium Total u /L 4 0.054 1 <1 0.15J <1 0.082J 0.074J 0.27J 0.16J <1 <1 <1 <1 Cadmium Total u /L 2 0.11 1 <1 <1 <1 <1 <1 0.12J 0.15J <1 <1 <1 <1 Chromium Total u /L 10 1.1 10 <10 <10 <10 <10 1.4J 1.2J <10 <10 <10 1.1J <10 Cobalt Total u /L 1 0.39 10 <10 <10 <10 14.1 <10 4.7J <10 <10 0.62J <10 <10 Copper Total u /L 1,000 1 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Lead Total u /L 15 0.89 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Nickel Total u /L 100 0.71 50 <50 <50 <50 <50 <50 <50 <50 <50 1.3J <50 <50 Selenium Total u /L 20 1.4 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Silver Total u /L 20 0.44 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Thallium Total u /L 2 0.18 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total u /L 7 1.9 25 <25 <25 <25 <25 4.5J <25 <25 <25 2.8J 4.6J <25 Zinc Total u /L 1,000 7.0 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Field Dissovled Oxygen m /L NE NE NE 1.74 2.26 3.32 1.64 2.39 2.05 4.70 2.28 3.28 5.04 1.98 Field pH SU NE NE NE 6.49 5.62 7.98 5.29 5.88 5.61 5.48 5.82 5.90 6.26 6.06 Field Redox mV NE NE NE 37.6 70.9 -30.9 88.0 55.9 70.1 77.3 67.2 54.3 34.3 45.1 Field Specific Conductance umhos/cm NE NE NE 76.6 165.2 225 38.6 202 143.0 284 93.9 197.7 59.2 68.9 Field Temperature °C NE NE NE 18.6 21.7 20.8 20.0 20.2 18.5 17.8 16.2 18.6 17.1 16.7 Field Turbidity NTU NE NE NE 0.78 0.34 0.50 0.84 0.31 1.96 3.22 2.16 0.78 1.04 0.27 Benzene u /L 1 0.34 1 <1 3.2 <1 <1 0.77J <1 <1 <1 <1 <1 <1 For VOCs, only constituents with one or more detections above a PQL are included on table. NE: Denotes a NC 2L Standard is not established. NS: Not required to be sampled. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. Denotes a concentration at or above a PQL is also above a NC 2L Standard: Denotes a concentration is above a NC 2L Standard, but but below the PQL: TABLE 3 SURFACE WATER ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units NC 2B Std MDL PQL SW-1 SW-2 SW-3 SW-4 SW-5 Antimony Total ug/L 640 0.78 6 <6 <6 <6 <6 <6 Arsenic Total ug/L 10 2.2 10 <10 <10 <10 <10 <10 Barium Total u /L 21,000 0.67 100 24.3J 28.3J 23.OJ 23.7J 24.9J Beryllium Total u /L 6.5 0.054 1 <1 <1 <1 <1 <1 Cadmium Total ug/L NE 0.11 1 <1 <1 <1 <1 <1 Chromium Total u /L NE 1.1 10 <10 <10 <10 <10 <10 Cobalt Total u /L 4 0.39 10 0.51 J 0.63J <10 <10 0.58J Copper Total u /L NE 1 10 <10 <10 <10 <10 <10 Lead Total u /L NE 0.89 10 <10 <10 <10 <10 <10 Nickel Total u /L NE 0.71 50 <50 <50 <50 <50 <50 Selenium Total ug/L 5 1.4 10 <10 <10 <10 <10 <10 Silver Total ug/L 0.06 0.44 10 <10 <10 <10 <10 <10 Thallium Total u /L 0.47 0.18 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total u /L NE 1.9 25 <25 <25 <25 <25 <25 Zinc Total ug/L NE 7.0 10 <10 <10 <10 <10 <10 Field Dissolved Oxygen m /L NE NE NE 3.94 3.58 5.03 5.10 3.80 Field pH SU NE NE NE 6.52 6.57 6.85 6.92 7.44 Field Redox mV NE NE NE 15.8 17.8 2.2 -1.6 -18.2 Field Specific Conductance I umhos/cm I NE NE I NE 1 84.6 1 97.5 1 72.5 74.1 1 140.6 Field Temperature °C NE NE NE 21.9 21.7 21.7 21.9 20.6 Field Turbidity NTU NE NE NE 7.90 8.84 5.15 11.10 6.08 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. NE: Denotes a NC 2B Standard is not established. No VOCs detected above a PQL, therefore not included on this table. TABLE 4 UNDERDRAIN ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units MDL PQL UD-1 UD-2 Antimony Total ug/L 0.78 6 <6 <6 Arsenic Total ug/L 2.2 10 <10 <10 Barium Total ug/L 0.67 100 77.4J 56.9J Beryllium Total ug/L 0.054 1 0.15J 0.17J Cadmium Total ug/L 0.11 1 <1 <1 Chromium Total ug/L 1.1 10 1.11 1.5,1 Cobalt Total ug/L 0.39 10 7.2J 5.1 J Copper Total ug/L 1 10 <10 <10 Lead Total ug/L 0.89 10 <10 1.2,1 Nickel Total ug/L 0.71 50 1.4J 1.1J Selenium Total ug/L 1.4 10 <10 <10 Silver Total ug/L 0.44 10 <10 <10 Thallium Total ug/L 0.18 5.5 <5.5 <5.5 Vanadium Total ug/L 1.9 25 5.2,1 6.1J Zinc Total ug/L 7.0 10 <10 <10 Field Dissolved Oxygen mg/L NE NE 3.90 3.72 Field pH SU NE NE 5.80 6.02 Field Redox mV NE NE 60.7 60.4 Field Specific Conductance umhos/cm NE NE 217 192.6 Field Temperature °C NE NE 22.2 21.1 Field Turbidity NTU NE NE 49.80 29.60 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. No VOCs detected above a PQL, therefore not included on this table. NE: Not established. TABLE 5 LEACHATE ANALYTICAL DATA SUMMARY SECOND SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Indicator Parameters Units MDL PQL Leachate Antimony u /L 19.5 150 138J Arsenic ug/L 54 250 1901 Barium u /L 16.8 2500 521 J Beryllium ug/L 1.3 25 <25 BOD, 5 day u /L 2000 2000 540000 Cadmium ug/L 2.8 25 <25 Chemical Oxygen Demand u /L 125000 250000 4550000 Chromium ug/L 27.4 250 396 Cobalt u /L 9.9 250 35.5J Copper ug/L 25.1 250 <250 Lead u /L 22.2 250 <250 Nickel ug/L 17.7 1250 202J Nitrogen, Nitrate u /L 1200 2000 <2000 Nitrogen, Nitrite ug/L 1000 2000 <2000 Phosphorus u /L 125 250 7390 Selenium ug/L 34.2 250 <250 Silver u /L 10.9 250 <250 Sulfate u /L 10000 20000 <20000 Thallium u /L 4.5 138 <138 Vanadium u /L 46.5 625 82.2J Zinc u /L 174 250 <250 Field pH SU NE NE 7.84 Field Specific Conductance umhos/cm NE NE 16850 Field Temperature °C NE NE 32.5 Field Turbidity NTU NE NE 58.30 2-Butanone ug/L 500 19.8 640 Acetone u /L 500 25.6 1470 Benzene ug/L 5 1.7 3.8J Eth (benzene u /L 5 1.5 13.4 Toluene ug/L 5 2.4 9.0 Trichloroethene u /L 5 1.9 4.7J X lenes u /L 25 1.7 22.8J Metals reported as Total. For VOCs, only constituents with detections above a PQL are included on table. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP NORTH 0 100 200 400 &SW-1 MW 8 165.60 \ M W-7A 1 1153.64� U D- M W-6 1133.80 I I MW-5 1127.48— Ir�MW-4 1129.48 0 �S zo 'TING 23� NO. SA�\ o \\y 0 EXISTING ° ELL NO. 0 i -1300 310 C4� ISTI 3B l SF,2 1250 11 VIStll 1 1 AW-1 R2' 1499.99: .I :�\\ \�l LL J MW-11 1318.62 19 EXISTI CELL NO. 5 (UNDE 1 l STRUC ION) WL X IN CEL 0.1 I, MW-9 �1220.74 M / ea lzop—� BMW-3R2� o U" 1183.48'-�Z \ 3 \ 1�/ 121p / i SSW-3 :11 Scale in Feet Graphic Scale: 1 inch = 400 feet SSW-4 1 10 Oki a LEGEND t 1 SMW-7 Monitoring Well Location Lj SUD-1 Underdrain Location 1153.64 Groundwater Elevation (fmsl) —1300 — Potentiometric Surface Contour (fmsl) Hydraulic Gradient & Inferred 1 0.1226 Groundwater Flow Direction SW-1 Surface Water Sampling Location (Approx) Landfill Cell Boundary __ LFG Trench (Approx) Water levels collected by Environmental Sampling & Services, Inc. on July 26, 2022. Basemap provided by Joyce Engineering, with topographic survey completed by Cooper Aerial Surveys Co., date of Photography is January 20, 2014. JETT Figure 1 18 Lexington Oaks Court Second Semi -Annual 2022 Event Potentiometric Surface Map Forlstell, MO 63348 314 nviro. om J E 0VN S U L Tt I NG www.jettenvlro.com Foothills Regional Landfill, Caldwell County, North Carolina Groundwater Elevation Summary Table Foothills Regional Landfill Well Top of PVC Casing Elevation (fmsl)' 2 Depth to Water (ft) Groundwater Elevation (fmsl) MW-1 R2 1516.22 16.23 1499.99 MW-2R 1253.36 50.94 1202.42 MW-3 1241.95 54.44 1187.51 MW-3R 1242.69 59.21 1183.48 MW-3R2 1240.83 40.55 1200.28 MW-4 1171.18 41.70 1129.48 MW-5 1175.07 47.59 1127.48 MW-6 1176.82 43.02 1133.80 MW-7 1183.13 29.49 1153.64 MW-8 1195.18 29.58 1165.60 MW-9 1290.79 70.05 1220.74 MW-10 1358.53 78.04 1280.49 MW-11 1401.71 83.09 1318.62 Note 1: Top of PVC Casing Elevations from Table 1 of the Water Quality Monitoring Plan dated March 20, 2019 by BLE. Note 2: Depth to water measured by Environmental Sampling & Services, Inc. on July 26, 2022. Groundwater Flow Velocity Calculations Foothills Regional Landfill Second Semi -Annual 2022 Event Velocity V = [(k)(i)]/(n) V = [(0.374 ft/day)(0.1226 ft/ft)] / 0.1 V = 0.459 ft/day V = 168 ft/year Where, Hydraulic conductivity (k) and effective porosity (n) values from the following document: Table 2 of the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path is From Point A (1450 contour) to Point 8 (1150 contour) = 300 ft / 2,447 ft = 0.1226 ft/ft APPENDIX B STATISTICAL EVALUATIONS Prediction Limit Foothills Client: RSI Data: Foothills Printed 8/22/2022, 10:48 AM Constituent Well Uooer Lim. Lower Lim. Date Observ. Sia.. Ba N Ba Mean Std. Day. %NDs ND Adi. Transform Aloha Method Cobalt Total (ug/L) MW-4 10.0 n/a 7/26/2022 14.1 Yes 52 n/a n/a 94.23 n/a n/a 0.0007079 NP Inter (NDs) 1 of 2 Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-4 30 24 18 M 12 A 0 4- 7/19/99 Prediction Limit Interwell Non -parametric 2/24/04 10/2/08 5/10/13 12/17/17 7/26/22 ♦ MW-4 Limit = 10.0 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 52 background values. 94.23% NDs. Annual per -constituent alpha = 0.001415. Individual comparison alpha = 0.0007079 (1 of 2). After outlier removal distribution was non -normal, so outlier results were invalidated. Constituent: Cobalt Total Analysis Run 8/22/2022 10:47 AM Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 5 4 3 2 J � 1 [II Constituent: Benzene Analysis Run 8/23/2022 8:33 AM View: Cl Foothills Client: RSI Data: Foothills Confidence Interval Constituent: Benzene (ug/L) Analysis Run 8/23/2022 8:34 AM View: Cl Foothills Client: RSI Data: Foothills MW-2R 2/1/2021 2 7/26/2021 2.5 1/26/2022 2.4 7/26/2022 3.2 Mean 2.525 Std. Dev. 0.4992 Upper Lim. 3.658 Lower Lim. 1.392 TIME SERIES TREND ANALYSIS Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 6 4.8 3.6 J 0) Z3 2.4 1.2 0 1 /6/09 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 Constituent: Antimony Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 20 16 12 N �'W7 IXXX 11 1 KA I 3L. E. Z3 8 - 4 MAX 8/10/98 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Arsenic Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 700 560 420 J 280 140 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Barium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) Constituent: Beryllium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. J Z3 5 4 01 2 1 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Cadmium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 40 32 24 J 16 8 Time Series 8/10/98 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Chromium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) 0 4- 8/10/98 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Cobalt Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 500 400 300 J 0) 200 100 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) 0 4- 8/10/98 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Copper Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Lead Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) SanitasTM v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 - 30 - J 20 10 0 1 •: 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Nickel Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) Constituent: Selenium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 20 10 0 4- 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Silver Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) SanitasTM v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. J 10 8 rX 4 2 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Thallium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 60 48 36 J 24 12 0 4- 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Vanadium Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 80 40 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 Constituent: Zinc Total Analysis Run 8/22/2022 10:54 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 2 1 0 1 /6/09 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) Constituent: 11-Dichloroethane Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 0 4- 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) Constituent: Benzene Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 0 1 /6/09 Time Series 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) Constituent: cis- 12-Dichloroethene Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 8/10/98 Time Series 5/26/03 3/10/08 12/24/12 10/9/17 7/26/22 MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 MW-11 ♦ MW-1 R2 (bg) Constituent: Tetrachloroethene Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) 0 4- 1 /6/09 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 Constituent: Toluene Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) 0 4- 1 /6/09 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 Constituent: Trichloroethene Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 M W-4 MW-5 MW-6 MW-7 MW-8 MW-11 MW-1 R2 (bg) 0 4- 1 /6/09 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 Constituent: Vinyl chloride Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.35 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 7 71 4 3 J 2 1 0 1 /6/09 9/22/11 6/8/14 2/22/17 11 /9/19 7/26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Xylenes [Total] Analysis Run 8/22/2022 10:58 AM View: TS VOCs Foothills Client: RSI Data: Foothills APPENDIX C LABORATORY ANALYTICAL REPORTS FIELD SAMPLING FORMS leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 10, 2022 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on July 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, 01A-i'l -�--� Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 92 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab ID Sample ID Matrix Date Collected Date Received 92616984001 1403-MW-1 R2 Water 07/26/22 14:08 07/27/22 10:22 92616984002 1403-MW-2R Water 07/26/2215:32 07/27/22 10:22 92616984003 1403-MW-3R2 Water 07/26/2213:10 07/27/22 10:22 92616984004 1403-MW-4 Water 07/26/2212:20 07/27/22 10:22 92616984005 1403-DUP@MW-2R Water 07/26/2215:34 07/27/22 10:22 92616984006 1403-MW-5 Water 07/26/2211:33 07/27/22 10:22 92616984007 1403-MW-6 Water 07/26/2210:46 07/27/22 10:22 92616984008 1403-MW-7 Water 07/26/22 09:57 07/27/22 10:22 92616984009 1403-MW-8 Water 07/26/22 09:07 07/27/22 10:22 92616984010 1403-MW-9 Water 07/26/22 08:14 07/27/22 10:22 92616984011 1403-MW-10 Water 07/26/22 07:24 07/27/22 10:22 92616984012 1403-MW-11 Water 07/26/22 06:34 07/27/22 10:22 92616984013 1403-Field Blank Water 07/25/22 14:10 07/27/22 10:22 92616984014 1403-SW1 Water 07/25/2214:20 07/27/22 10:22 92616984015 1403-SW2 Water 07/25/2215:25 07/27/22 10:22 92616984016 1403-SW3 Water 07/25/2216:38 07/27/22 10:22 92616984017 1403-SW4 Water 07/25/2216:15 07/27/22 10:22 92616984018 1403-SW5 Water 07/25/2215:48 07/27/22 10:22 92616984019 1403-UD1 Water 07/25/2215:06 07/27/22 10:22 92616984020 1403-UD2 Water 07/25/2214:44 07/27/22 10:22 92616984021 1403-Trip Blank Water 07/25/22 14:12 07/27/22 10:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/SemiAnnual 92616984 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92616984001 1403-MW-1R2 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984002 1403-MW-2R EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984003 1403-MW-3R2 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984004 1403-MW-4 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984005 1403-DUP@MW-2R EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984006 1403-MW-5 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984007 1403-MW-6 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984008 1403-MW-7 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984009 1403-MW-8 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92616984010 1403-MW-9 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92616984011 1403-MW-10 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92616984012 1403-MW-11 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92616984013 1403-Field Blank EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984014 1403-SW1 EPA6020B CW1 18 PASI-GA EPA 8260D SAS 50 PASI-C 92616984015 1403-SW2 EPA6020B CW1 18 PASI-GA EPA 8260D SAS 50 PASI-C 92616984016 1403-SW3 EPA6020B CW1 18 PASI-GA EPA 8260D SAS 50 PASI-C 92616984017 1403-SW4 EPA6020B CW1 18 PASI-GA EPA 8260D SAS 50 PASI-C 92616984018 1403-SW5 EPA6020B CW1 18 PASI-GA EPA 8260D SAS 50 PASI-C 92616984019 1403-UD1 EPA6020B CW1 15 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/SemiAnnual 92616984 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D SAS 50 PASI-C 92616984020 1403-UD2 EPA6020B CW1 15 PASI-GA EPA 8260D SAS 50 PASI-C 92616984021 1403-Trip Blank EPA 8260D SAS 50 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92616984001 1403-MW-1 R2 Performed by ES&S 07/26/22 14:08 pH 6.49 Std. Units 07/26/22 14:08 Temperature 18.6 deg C 07/26/22 14:08 Static Water Level 16.36 feet 07/26/22 14:08 Specific Conductance 76.6 umhos/cm 07/26/22 14:08 Oxidation Potential 37.6 mV 07/26/22 14:08 Oxygen, Dissolved 1.74 mg/L 07/26/22 14:08 Total Well Depth 43.34 feet 07/26/22 14:08 Turbidity 0.78 NTU 07/26/22 14:08 EPA 6020B Barium 62.1 J ug/L 100 07/28/22 16:19 92616984002 1403-MW-2R Performed by ES&S 07/26/22 15:32 pH 5.62 Std. Units 07/26/22 15:32 Temperature 21.7 deg C 07/26/22 15:32 Static Water Level 51.15 feet 07/26/22 15:32 Specific Conductance 165.2 umhos/cm 07/26/22 15:32 Oxidation Potential 70.9 mV 07/26/22 15:32 Oxygen, Dissolved 2.26 mg/L 07/26/22 15:32 Total Well Depth 63.60 feet 07/26/22 15:32 Turbidity 0.34 NTU 07/26/22 15:32 EPA 6020B Barium 312 ug/L 100 07/28/22 16:25 EPA 6020B Beryllium 0.15J ug/L 1.0 07/28/22 16:25 EPA 8260D Benzene 3.2 ug/L 1.0 07/28/22 17:24 EPA 8260D 1,1-Dichloroethane 0.88J ug/L 5.0 07/28/22 17:24 EPA 8260D cis-1,2-Dichloroethene 3.5J ug/L 5.0 07/28/22 17:24 EPA 8260D Vinyl chloride 0.52J ug/L 1.0 07/28/22 17:24 EPA 8260D Xylene (Total) 3.7J ug/L 5.0 07/28/22 17:24 92616984003 1403-MW-3R2 Performed by ES7S 07/26/22 13:10 pH 7.98 Std. Units 07/26/22 13:10 Temperature 20.8 deg C 07/26/22 13:10 Static Water Level 40.68 feet 07/26/22 13:10 Specific Conductance 225 umhos/cm 07/26/22 13:10 Oxidation Potential -30.9 mV 07/26/22 13:10 Oxygen, Dissolved 3.32 mg/L 07/26/22 13:10 Total Well Depth 73.91 feet 07/26/22 13:10 Turbidity 0.50 NTU 07/26/22 13:10 EPA 6020B Barium 4.OJ ug/L 100 07/28/22 16:31 92616984004 1403-MW-4 Performed by ES&S 07/26/22 12:20 pH 5.29 Std. Units 07/26/22 12:20 Temperature 20.0 deg C 07/26/22 12:20 Static Water Level 41.82 feet 07/26/22 12:20 Specific Conductance 38.6 umhos/cm 07/26/22 12:20 Oxidation Potential 88.0 mV 07/26/22 12:20 Oxygen, Dissolved 1.64 mg/L 07/26/22 12:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab Sample ID Method Client Sample ID Parameters 92616984004 1403-MW-4 Total Well Depth Turbidity EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Cobalt 92616984005 1403-DUP@MW-2R EPA 6020B Antimony EPA 6020B Barium EPA 6020B Beryllium EPA 8260D Benzene EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene EPA 8260D Ethylbenzene EPA 8260D Vinyl chloride EPA 8260D Xylene (Total) 92616984006 1403-MW-5 Performed by pH Temperature Static Water Level Specific Conductance Oxidation Potential Oxygen, Dissolved Total Well Depth Turbidity EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Chromium EPA 6020B Vanadium EPA 8260D Benzene EPA 8260D 1,2-Dichloroethane EPA 8260D cis-1,2-Dichloroethene 92616984007 1403-MW-6 Performed by pH Temperature Static Water Level Specific Conductance Oxidation Potential Oxygen, Dissolved Total Well Depth Turbidity EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Cadmium EPA 6020B Chromium SUMMARY OF DETECTION Result Units Report Limit Analyzed 52.20 feet 07/26/2212:20 0.84 NTU 07/26/2212:20 47.1 J ug/L 100 07/28/22 16:37 0.082J ug/L 1.0 07/28/2216:37 14.1 ug/L 10.0 07/28/2216:37 1.1 J ug/L 6.0 07/28/22 17:01 320 ug/L 100 07/28/2217:01 0.17J ug/L 1.0 07/28/2217:01 2.8 ug/L 1.0 07/28/2217:43 0.901 ug/L 5.0 07/28/2217:43 3.3J ug/L 5.0 07/28/2217:43 0.36J ug/L 1.0 07/28/2217:43 0.63J ug/L 1.0 07/28/2217:43 4.1 J ug/L 5.0 07/28/22 17:43 ES&S 07/26/22 11:33 5.88 Std. Units 07/26/22 11:33 20.2 deg C 07/26/22 11:33 47.71 feet 07/26/22 11:33 202 umhos/cm 07/26/22 11:33 55.9 mV 07/26/22 11:33 2.39 mg/L 07/26/22 11:33 54.50 feet 07/26/22 11:33 0.31 NTU 07/26/22 11:33 140 ug/L 100 07/28/2217:26 0.074J ug/L 1.0 07/28/2217:26 1 AJ ug/L 10.0 07/28/22 17:26 4.5J ug/L 25.0 07/28/2217:26 0.77J ug/L 1.0 07/28/2218:02 0.42J ug/L 1.0 07/28/2218:02 2.2J ug/L 5.0 07/28/2218:02 ES&S 07/26/22 10:46 5.61 Std. Units 07/26/22 10:46 18.5 deg C 07/26/22 10:46 43.14 feet 07/26/22 10:46 143.0 umhos/cm 07/26/22 10:46 70.1 mV 07/26/22 10:46 2.05 mg/L 07/26/22 10:46 50.55 feet 07/26/22 10:46 1.96 NTU 07/26/22 10:46 115 ug/L 100 07/28/2217:32 0.27J ug/L 1.0 07/28/2217:32 0.12J ug/L 1.0 07/28/2217:32 1.2J ug/L 10.0 07/28/2217:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Oimlifiars Page 7 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/SemiAnnual 92616984 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92616984007 1403-MW-6 EPA 6020B Cobalt 4.7J ug/L 10.0 07/28/22 17:32 92616984008 1403-MW-7 Performed by ES&S 07/26/22 09:57 pH 5.48 Std. Units 07/26/22 09:57 Temperature 17.8 deg C 07/26/22 09:57 Static Water Level 29.60 feet 07/26/22 09:57 Specific Conductance 284 umhos/cm 07/26/22 09:57 Oxidation Potential 77.3 mV 07/26/22 09:57 Oxygen, Dissolved 4.70 mg/L 07/26/22 09:57 Total Well Depth 40.13 feet 07/26/22 09:57 Turbidity 3.22 NTU 07/26/22 09:57 EPA 6020B Barium 77AJ ug/L 100 07/28/22 17:38 EPA 6020B Beryllium 0.16J ug/L 1.0 07/28/22 17:38 EPA 6020B Cadmium 0.15J ug/L 1.0 07/28/22 17:38 92616984009 1403-MW-8 Performed by ES&S 07/26/22 09:07 pH 5.82 Std. Units 07/26/22 09:07 Temperature 16.2 deg C 07/26/22 09:07 Static Water Level 29.72 feet 07/26/22 09:07 Specific Conductance 93.9 umhos/cm 07/26/22 09:07 Oxidation Potential 67.2 mV 07/26/22 09:07 Oxygen, Dissolved 2.28 mg/L 07/26/22 09:07 Total Well Depth 49.56 feet 07/26/22 09:07 Turbidity 2.16 NTU 07/26/22 09:07 EPA 6020B Barium 77.3J ug/L 100 07/28/22 17:44 92616984010 1403-MW-9 Performed by ES&S 07/26/22 08:14 pH 5.90 Std. Units 07/26/22 08:14 Temperature 18.6 deg C 07/26/22 08:14 Static Water Level 70.17 feet 07/26/22 08:14 Specific Conductance 197.7 umhos/cm 07/26/22 08:14 Oxidation Potential 54.3 mV 07/26/22 08:14 Oxygen, Dissolved 3.28 mg/L 07/26/22 08:14 Total Well Depth 73.40 feet 07/26/22 08:14 Turbidity 0.78 NTU 07/26/22 08:14 EPA 6020B Barium 15.5J ug/L 100 07/28/22 17:50 EPA 6020B Cobalt 0.62J ug/L 10.0 07/28/22 17:50 EPA 6020B Nickel 1.3J ug/L 50.0 07/28/22 17:50 EPA 6020B Vanadium 2.8J ug/L 25.0 07/28/22 17:50 92616984011 1403-MW-10 Performed by ES&S 07/26/22 07:24 pH 6.26 Std. Units 07/26/22 07:24 Temperature 17.1 deg C 07/26/22 07:24 Static Water Level 78.16 feet 07/26/22 07:24 Specific Conductance 59.2 umhos/cm 07/26/22 07:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92616984011 1403-MW-10 Oxidation Potential 34.3 mV 07/26/22 07:24 Oxygen, Dissolved 5.04 mg/L 07/26/22 07:24 Total Well Depth 88.21 feet 07/26/22 07:24 Turbidity 1.04 NTU 07/26/22 07:24 EPA 6020B Barium 25.9J ug/L 100 07/28/22 17:56 EPA 6020B Chromium 1.1J ug/L 10.0 07/28/22 17:56 EPA 6020B Vanadium 4.6J ug/L 25.0 07/28/22 17:56 92616984012 1403-MW-11 Performed by ES&S 07/26/22 06:34 pH 6.06 Std. Units 07/26/22 06:34 Temperature 16.7 deg C 07/26/22 06:34 Static Water Level 83.23 feet 07/26/22 06:34 Specific Conductance 68.9 umhos/cm 07/26/22 06:34 Oxidation Potential 45.1 mV 07/26/22 06:34 Oxygen, Dissolved 1.98 mg/L 07/26/22 06:34 Total Well Depth 108.40 feet 07/26/22 06:34 Turbidity 0.27 NTU 07/26/22 06:34 EPA 6020B Barium 91.3J ug/L 100 07/28/22 18:02 92616984014 1403-SW1 Performed by ES&S 07/25/22 14:20 pH 6.52 Std. Units 07/25/22 14:20 Temperature 21.9 deg C 07/25/22 14:20 Specific Conductance 84.6 umhos/cm 07/25/22 14:20 Oxidation Potential 15.8 mV 07/25/22 14:20 Oxygen, Dissolved 3.94 mg/L 07/25/22 14:20 Turbidity 7.90 NTU 07/25/22 14:20 EPA 6020B Barium 24.3J ug/L 100 07/28/22 18:14 EPA 6020B Calcium 7680 ug/L 100 07/28/22 18:14 EPA 6020B Cobalt 0.51 J ug/L 10.0 07/28/22 18:14 EPA 6020B Magnesium 2180 ug/L 50.0 07/28/22 18:14 EPA 6020B Total Hardness 28200 ug/L 456 07/28/22 18:14 92616984015 1403-SW2 Performed by ES&S 07/26/22 15:25 pH 6.57 Std. Units 07/26/22 15:25 Temperature 21.7 deg C 07/26/22 15:25 Specific Conductance 97.5 umhos/cm 07/26/22 15:25 Oxidation Potential 17.8 mV 07/26/22 15:25 Oxygen, Dissolved 3.58 mg/L 07/26/22 15:25 Turbidity 8.84 NTU 07/26/22 15:25 EPA 6020B Barium 28.3J ug/L 100 07/28/22 18:20 EPA 6020B Calcium 8840 ug/L 100 07/28/22 18:20 EPA 6020B Cobalt 0.63J ug/L 10.0 07/28/22 18:20 EPA 6020B Magnesium 2610 ug/L 50.0 07/28/22 18:20 EPA 6020B Total Hardness 32800 ug/L 456 07/28/22 18:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92616984016 1403-SW3 Performed by ES&S 07/25/22 16:38 pH 6.85 Std. Units 07/25/22 16:38 Temperature 21.7 deg C 07/25/22 16:38 Specific Conductance 72.5 umhos/cm 07/25/22 16:38 Oxidation Potential 2.2 my 07/25/22 16:38 Oxygen, Dissolved 5.03 mg/L 07/25/22 16:38 Turbidity 5.15 NTU 07/25/22 16:38 EPA 6020B Barium 23.OJ ug/L 100 07/28/22 18:38 EPA 6020B Calcium 5940 ug/L 100 07/28/22 18:38 EPA 6020B Magnesium 2200 ug/L 50.0 07/28/22 18:38 EPA 6020B Total Hardness 23900 ug/L 456 07/28/22 18:38 92616984017 1403-SW4 Performed by ES&S 07/25/22 16:15 pH 6.92 Std. Units 07/25/22 16:15 Temperature 21.9 deg C 07/25/22 16:15 Specific Conductance 74.1 umhos/cm 07/25/22 16:15 Oxidation Potential -1.6 my 07/25/22 16:15 Oxygen, Dissolved 5.10 mg/L 07/25/22 16:15 Turbidity 11.10 NTU 07/25/22 16:15 EPA 6020B Barium 23.7J ug/L 100 07/28/22 18:44 EPA 6020B Calcium 5980 ug/L 100 07/28/22 18:44 EPA 6020B Magnesium 2170 ug/L 50.0 07/28/22 18:44 EPA 6020B Total Hardness 23900 ug/L 456 07/28/22 18:44 92616984018 1403-SW5 Performed by ES&S 07/25/22 15:48 pH 7.44 Std. Units 07/25/22 15:48 Temperature 20.6 deg C 07/25/22 15:48 Specific Conductance 140.6 umhos/cm 07/25/22 15:48 Oxidation Potential -18.2 my 07/25/22 15:48 Oxygen, Dissolved 3.80 mg/L 07/25/22 15:48 Turbidity 6.08 NTU 07/25/22 15:48 EPA 6020B Barium 24.9J ug/L 100 07/28/22 18:50 EPA 6020B Calcium 7750 ug/L 100 07/28/22 18:50 EPA 6020B Cobalt 0.58J ug/L 10.0 07/28/22 18:50 EPA 6020B Magnesium 2270 ug/L 50.0 07/28/22 18:50 EPA 6020B Total Hardness 28700 ug/L 456 07/28/22 18:50 92616984019 1403-UD1 Performed by ES&S 07/25/22 15:06 pH 5.80 Std. Units 07/25/22 15:06 Temperature 22.2 deg C 07/25/22 15:06 Specific Conductance 217 umhos/cm 07/25/22 15:06 Oxidation Potential 60.7 my 07/25/22 15:06 Oxygen, Dissolved 3.90 mg/L 07/25/22 15:06 Turbidity 49.80 NTU 07/25/22 15:06 EPA 6020B Barium 77AJ ug/L 100 07/28/22 18:55 EPA 6020B Beryllium 0.151 ug/L 1.0 07/28/22 18:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab Sample ID Method Client Sample ID Parameters 92616984019 1403-UD1 EPA 6020B Chromium EPA 6020B Cobalt EPA 6020B Nickel EPA 6020B Vanadium 92616984020 1403-U D2 Performed by pH Temperature Specific Conductance Oxidation Potential Oxygen, Dissolved Turbidity EPA 6020B Barium EPA 6020B Beryllium EPA 6020B Chromium EPA 6020B Cobalt EPA 6020B Copper EPA 6020B Lead EPA 6020B Nickel EPA 6020B Vanadium SUMMARY OF DETECTION Result Units Report Limit Analyzed 1.1 J ug/L 10.0 07/28/22 18:55 7.2J ug/L 10.0 07/28/22 18:55 1 AJ ug/L 50.0 07/28/22 18:55 5.2J ug/L 25.0 07/28/22 18:55 ES&S 07/25/22 14:44 6.02 Std. Units 07/25/22 14:44 21.1 deg C 07/25/22 14:44 192.6 umhos/cm 07/25/22 14:44 60.4 mV 07/25/22 14:44 3.72 mg/L 07/25/22 14:44 29.60 NTU 07/25/22 14:44 56.9J ug/L 100 07/28/22 19:01 0.17J ug/L 1.0 07/28/22 19:01 1.5J ug/L 10.0 07/28/22 19:01 5.1 J ug/L 10.0 07/28/22 19:01 1 AJ ug/L 10.0 07/28/22 19:01 1.2J ug/L 10.0 07/28/22 19:01 1.1 J ug/L 50.0 07/28/22 19:01 6.1 J ug/L 25.0 07/28/22 19:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 11 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-1R2 Lab ID: 92616984001 Collected: 07/26/22 14:08 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 14:08 pH 6.49 Std. Units 1 07/26/22 14:08 Temperature 18.6 deg C 1 07/26/22 14:08 Static Water Level 16.36 feet 1 07/26/22 14:08 Specific Conductance 76.6 umhos/c 1 07/26/22 14:08 m Oxidation Potential 37.6 mV 1 07/26/22 14:08 Oxygen, Dissolved 1.74 mg/L 1 07/26/22 14:08 7782-44-7 Total Well Depth 43.34 feet 1 07/26/22 14:08 Turbidity 0.78 NTU 1 07/26/22 14:08 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2216:19 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2216:19 7440-38-2 Barium 62.1J ug/L 100 0.67 1 07/28/2210:11 07/28/2216:19 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2216:19 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2216:19 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2216:19 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2216:19 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2216:19 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2216:19 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2216:19 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2216:19 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2216:19 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2216:19 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2216:19 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2216:19 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 15:33 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 15:33 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 15:33 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 15:33 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 15:33 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 15:33 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 15:33 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 15:33 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 15:33 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 15:33 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 15:33 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 15:33 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 15:33 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 15:33 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-1R2 Lab ID: 92616984001 Collected: 07/26/22 14:08 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 96 % 70-130 105 % 70-130 102 % 70-130 1 07/28/22 15:33 96-12-8 1 07/28/22 15:33 124-48-1 1 07/28/22 15:33 106-93-4 1 07/28/22 15:33 74-95-3 1 07/28/22 15:33 95-50-1 1 07/28/22 15:33 106-46-7 1 07/28/22 15:33 110-57-6 1 07/28/22 15:33 75-34-3 1 07/28/22 15:33 107-06-2 1 07/28/22 15:33 75-35-4 1 07/28/22 15:33 156-59-2 1 07/28/22 15:33 156-60-5 1 07/28/22 15:33 78-87-5 1 07/28/22 15:33 10061-01-5 1 07/28/22 15:33 10061-02-6 1 07/28/22 15:33 100-41-4 1 07/28/22 15:33 591-78-6 1 07/28/22 15:33 74-88-4 1 07/28/22 15:33 75-09-2 1 07/28/22 15:33 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 15:33 100-42-5 07/28/22 15:33 630-20-6 07/28/22 15:33 79-34-5 07/28/22 15:33 127-18-4 07/28/22 15:33 108-88-3 07/28/22 15:33 71-55-6 07/28/22 15:33 79-00-5 07/28/22 15:33 79-01-6 07/28/22 15:33 75-69-4 07/28/22 15:33 96-18-4 07/28/22 15:33 108-05-4 07/28/22 15:33 75-01-4 07/28/22 15:33 1330-20-7 07/28/22 15:33 460-00-4 07/28/22 15:33 17060-07-0 07/28/22 15:33 2037-26-5 Page 13 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-2R Lab ID: 92616984002 Collected: 07/26/22 15:32 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 15:32 pH 5.62 Std. Units 1 07/26/22 15:32 Temperature 21.7 deg C 1 07/26/22 15:32 Static Water Level 51.15 feet 1 07/26/22 15:32 Specific Conductance 165.2 umhos/c 1 07/26/22 15:32 m Oxidation Potential 70.9 mV 1 07/26/22 15:32 Oxygen, Dissolved 2.26 mg/L 1 07/26/22 15:32 7782-44-7 Total Well Depth 63.60 feet 1 07/26/22 15:32 Turbidity 0.34 NTU 1 07/26/22 15:32 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2216:25 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2216:25 7440-38-2 Barium 312 ug/L 100 0.67 1 07/28/2210:11 07/28/2216:25 7440-39-3 Beryllium 0.15J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2216:25 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2216:25 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2216:25 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2216:25 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2216:25 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2216:25 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2216:25 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2216:25 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2216:25 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2216:25 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2216:25 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2216:25 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 17:24 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 17:24 107-13-1 Benzene 3.2 ug/L 1.0 0.34 1 07/28/22 17:24 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 17:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 17:24 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 17:24 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 17:24 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 17:24 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 17:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 17:24 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 17:24 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 17:24 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 17:24 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 17:24 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-2R Lab ID: 92616984002 Collected: 07/26/22 15:32 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 1 07/28/22 17:24 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 17:24 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 17:24 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 17:24 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 17:24 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 17:24 106-46-7 ND ug/L 100 0.56 1 07/28/22 17:24 110-57-6 0.88J ug/L 5.0 0.37 1 07/28/22 17:24 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 17:24 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 17:24 75-35-4 3.5J ug/L 5.0 0.38 1 07/28/22 17:24 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 17:24 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 17:24 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 17:24 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 17:24 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 17:24 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 17:24 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 17:24 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 17:24 75-09-2 ND ug/L 100 2.7 1 07/28/22 17:24 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 17:24 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 17:24 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 17:24 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 17:24 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 17:24 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 17:24 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 17:24 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 17:24 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 17:24 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 17:24 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 17:24 108-05-4 0.52J ug/L 1.0 0.39 1 07/28/22 17:24 75-01-4 3.7J ug/L 5.0 0.34 1 07/28/22 17:24 1330-20-7 91 % 70-130 1 07/28/22 17:24 460-00-4 103 % 70-130 1 07/28/22 17:24 17060-07-0 101 % 70-130 1 07/28/22 17:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 15 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-3R2 Lab ID: 92616984003 Collected: 07/26/22 13:10 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES7S 1 07/26/22 13:10 pH 7.98 Std. Units 1 07/26/22 13:10 Temperature 20.8 deg C 1 07/26/22 13:10 Static Water Level 40.68 feet 1 07/26/22 13:10 Specific Conductance 225 umhos/c 1 07/26/22 13:10 m Oxidation Potential -30.9 mV 1 07/26/22 13:10 Oxygen, Dissolved 3.32 mg/L 1 07/26/22 13:10 7782-44-7 Total Well Depth 73.91 feet 1 07/26/22 13:10 Turbidity 0.50 NTU 1 07/26/22 13:10 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2216:31 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2216:31 7440-38-2 Barium 4.OJ ug/L 100 0.67 1 07/28/2210:11 07/28/2216:31 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2216:31 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2216:31 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2216:31 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2216:31 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2216:31 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2216:31 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2216:31 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2216:31 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2216:31 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2216:31 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2216:31 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2216:31 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 15:51 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 15:51 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 15:51 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 15:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 15:51 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 15:51 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 15:51 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 15:51 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 15:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 15:51 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 15:51 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 15:51 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 15:51 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 15:51 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-3R2 Lab ID: 92616984003 Collected: 07/26/22 13:10 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 104 % 70-130 101 % 70-130 1 07/28/22 15:51 96-12-8 1 07/28/22 15:51 124-48-1 1 07/28/22 15:51 106-93-4 1 07/28/22 15:51 74-95-3 1 07/28/22 15:51 95-50-1 1 07/28/22 15:51 106-46-7 1 07/28/22 15:51 110-57-6 1 07/28/22 15:51 75-34-3 1 07/28/22 15:51 107-06-2 1 07/28/22 15:51 75-35-4 1 07/28/22 15:51 156-59-2 1 07/28/22 15:51 156-60-5 1 07/28/22 15:51 78-87-5 1 07/28/22 15:51 10061-01-5 1 07/28/22 15:51 10061-02-6 1 07/28/22 15:51 100-41-4 1 07/28/22 15:51 591-78-6 1 07/28/22 15:51 74-88-4 1 07/28/22 15:51 75-09-2 1 07/28/22 15:51 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 15:51 100-42-5 07/28/22 15:51 630-20-6 07/28/22 15:51 79-34-5 07/28/22 15:51 127-18-4 07/28/22 15:51 108-88-3 07/28/22 15:51 71-55-6 07/28/22 15:51 79-00-5 07/28/22 15:51 79-01-6 07/28/22 15:51 75-69-4 07/28/22 15:51 96-18-4 07/28/22 15:51 108-05-4 07/28/22 15:51 75-01-4 07/28/22 15:51 1330-20-7 07/28/22 15:51 460-00-4 07/28/22 15:51 17060-07-0 07/28/22 15:51 2037-26-5 Page 17 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-4 Lab ID: 92616984004 Collected: 07/26/22 12:20 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 12:20 pH 5.29 Std. Units 1 07/26/22 12:20 Temperature 20.0 deg C 1 07/26/22 12:20 Static Water Level 41.82 feet 1 07/26/22 12:20 Specific Conductance 38.6 umhos/c 1 07/26/22 12:20 m Oxidation Potential 88.0 mV 1 07/26/22 12:20 Oxygen, Dissolved 1.64 mg/L 1 07/26/22 12:20 7782-44-7 Total Well Depth 52.20 feet 1 07/26/22 12:20 Turbidity 0.84 NTU 1 07/26/22 12:20 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2216:37 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2216:37 7440-38-2 Barium 47.1J ug/L 100 0.67 1 07/28/2210:11 07/28/2216:37 7440-39-3 Beryllium 0.082J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2216:37 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2216:37 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2216:37 7440-47-3 Cobalt 14.1 ug/L 10.0 0.39 1 07/28/2210:11 07/28/2216:37 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2216:37 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2216:37 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2216:37 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2216:37 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2216:37 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2216:37 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2216:37 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2216:37 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 13:04 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 13:04 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 13:04 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 13:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 13:04 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 13:04 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 13:04 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 13:04 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 13:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 13:04 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 13:04 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 13:04 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 13:04 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 13:04 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-4 Lab ID: 92616984004 Collected: 07/26/22 12:20 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 103 % 70-130 102 % 70-130 1 07/28/22 13:04 96-12-8 1 07/28/22 13:04 124-48-1 1 07/28/22 13:04 106-93-4 1 07/28/22 13:04 74-95-3 1 07/28/22 13:04 95-50-1 1 07/28/22 13:04 106-46-7 1 07/28/22 13:04 110-57-6 1 07/28/22 13:04 75-34-3 1 07/28/22 13:04 107-06-2 1 07/28/22 13:04 75-35-4 1 07/28/22 13:04 156-59-2 1 07/28/22 13:04 156-60-5 1 07/28/22 13:04 78-87-5 1 07/28/22 13:04 10061-01-5 1 07/28/22 13:04 10061-02-6 1 07/28/22 13:04 100-41-4 1 07/28/22 13:04 591-78-6 1 07/28/22 13:04 74-88-4 1 07/28/22 13:04 75-09-2 1 07/28/22 13:04 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 13:04 100-42-5 07/28/22 13:04 630-20-6 07/28/22 13:04 79-34-5 07/28/22 13:04 127-18-4 07/28/22 13:04 108-88-3 07/28/22 13:04 71-55-6 07/28/22 13:04 79-00-5 07/28/22 13:04 79-01-6 07/28/22 13:04 75-69-4 07/28/22 13:04 96-18-4 07/28/22 13:04 108-05-4 07/28/22 13:04 75-01-4 07/28/22 13:04 1330-20-7 07/28/22 13:04 460-00-4 07/28/22 13:04 17060-07-0 07/28/22 13:04 2037-26-5 Page 19 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-DUP@MW-2R Lab ID: 92616984005 Collected: 07/26/22 15:34 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 1.1J ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:01 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:01 7440-38-2 Barium 320 ug/L 100 0.67 1 07/28/2210:11 07/28/2217:01 7440-39-3 Beryllium 0.17J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:01 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:01 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:01 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:01 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:01 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:01 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:01 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:01 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:01 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:01 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:01 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:01 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 17:43 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 17:43 107-13-1 Benzene 2.8 ug/L 1.0 0.34 1 07/28/22 17:43 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 17:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 17:43 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 17:43 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 17:43 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 17:43 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 17:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 17:43 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 17:43 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 17:43 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 17:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 17:43 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 07/28/22 17:43 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.36 1 07/28/22 17:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.27 1 07/28/22 17:43 106-93-4 Dibromomethane ND ug/L 10.0 0.39 1 07/28/22 17:43 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.34 1 07/28/22 17:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 07/28/22 17:43 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.56 1 07/28/22 17:43 110-57-6 butene 1,1-Dichloroethane 0.90J ug/L 5.0 0.37 1 07/28/22 17:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 07/28/22 17:43 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.35 1 07/28/22 17:43 75-35-4 cis-1,2-Dichloroethene 3.3J ug/L 5.0 0.38 1 07/28/22 17:43 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-DUP@MW-2R Lab ID: 92616984005 Collected: 07/26/22 15:34 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.40 1 07/28/2217:43 156-60-5 ND ug/L 1.0 0.36 1 07/28/2217:43 78-87-5 ND ug/L 1.0 0.36 1 07/28/2217:43 10061-01-5 ND ug/L 1.0 0.36 1 07/28/2217:43 10061-02-6 0.36J ug/L 1.0 0.30 1 07/28/2217:43 100-41-4 ND ug/L 50.0 0.48 1 07/28/2217:43 591-78-6 ND ug/L 20.0 9.7 1 07/28/2217:43 74-88-4 ND ug/L 5.0 2.0 1 07/28/2217:43 75-09-2 ND ug/L 100 2.7 1 07/28/2217:43 108-10-1 ND ug/L 1.0 0.29 1 07/28/2217:43 100-42-5 ND ug/L 5.0 0.31 1 07/28/2217:43 630-20-6 ND ug/L 3.0 0.22 1 07/28/2217:43 79-34-5 ND ug/L 1.0 0.29 1 07/28/2217:43 127-18-4 ND ug/L 1.0 0.48 1 07/28/2217:43 108-88-3 ND ug/L 1.0 0.33 1 07/28/2217:43 71-55-6 ND ug/L 1.0 0.32 1 07/28/2217:43 79-00-5 ND ug/L 1.0 0.38 1 07/28/2217:43 79-01-6 ND ug/L 1.0 0.30 1 07/28/2217:43 75-69-4 ND ug/L 1.0 0.26 1 07/28/2217:43 96-18-4 ND ug/L 50.0 1.3 1 07/28/2217:43 108-05-4 0.63J ug/L 1.0 0.39 1 07/28/2217:43 75-01-4 4.1J ug/L 5.0 0.34 1 07/28/2217:43 1330-20-7 95 % 70-130 1 07/28/2217:43 460-00-4 103 % 70-130 1 07/28/2217:43 17060-07-0 99 % 70-130 1 07/28/2217:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 21 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-5 Lab ID: 92616984006 Collected: 07/26/22 11:33 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 11:33 pH 5.88 Std. Units 1 07/26/22 11:33 Temperature 20.2 deg C 1 07/26/22 11:33 Static Water Level 47.71 feet 1 07/26/22 11:33 Specific Conductance 202 umhos/c 1 07/26/22 11:33 m Oxidation Potential 55.9 mV 1 07/26/22 11:33 Oxygen, Dissolved 2.39 mg/L 1 07/26/22 11:33 7782-44-7 Total Well Depth 54.50 feet 1 07/26/22 11:33 Turbidity 0.31 NTU 1 07/26/22 11:33 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:26 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:26 7440-38-2 Barium 140 ug/L 100 0.67 1 07/28/2210:11 07/28/2217:26 7440-39-3 Beryllium 0.074J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:26 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:26 7440-43-9 Chromium 1.4J ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:26 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:26 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:26 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:26 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:26 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:26 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:26 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:26 7440-28-0 Vanadium 4.5J ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:26 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:26 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 18:02 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 18:02 107-13-1 Benzene 0.77J ug/L 1.0 0.34 1 07/28/22 18:02 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 18:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 18:02 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 18:02 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 18:02 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 18:02 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 18:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 18:02 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 18:02 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 18:02 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 18:02 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 18:02 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-5 Lab ID: 92616984006 Collected: 07/26/22 11:33 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 1 07/28/22 18:02 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 18:02 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 18:02 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 18:02 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 18:02 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 18:02 106-46-7 ND ug/L 100 0.56 1 07/28/22 18:02 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 18:02 75-34-3 0.42J ug/L 1.0 0.32 1 07/28/22 18:02 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 18:02 75-35-4 2.2J ug/L 5.0 0.38 1 07/28/22 18:02 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 18:02 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 18:02 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 18:02 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 18:02 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 18:02 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 18:02 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 18:02 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 18:02 75-09-2 ND ug/L 100 2.7 1 07/28/22 18:02 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 18:02 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 18:02 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 18:02 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 18:02 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 18:02 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 18:02 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 18:02 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 18:02 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 18:02 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 18:02 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 18:02 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 18:02 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 18:02 1330-20-7 97 % 70-130 1 07/28/22 18:02 460-00-4 100 % 70-130 1 07/28/22 18:02 17060-07-0 103 % 70-130 1 07/28/22 18:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 23 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-6 Lab ID: 92616984007 Collected: 07/26/22 10:46 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 10:46 pH 5.61 Std. Units 1 07/26/22 10:46 Temperature 18.5 deg C 1 07/26/22 10:46 Static Water Level 43.14 feet 1 07/26/22 10:46 Specific Conductance 143.0 umhos/c 1 07/26/22 10:46 m Oxidation Potential 70.1 mV 1 07/26/22 10:46 Oxygen, Dissolved 2.05 mg/L 1 07/26/22 10:46 7782-44-7 Total Well Depth 50.55 feet 1 07/26/22 10:46 Turbidity 1.96 NTU 1 07/26/22 10:46 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:32 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:32 7440-38-2 Barium 115 ug/L 100 0.67 1 07/28/2210:11 07/28/2217:32 7440-39-3 Beryllium 0.27J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:32 7440-41-7 Cadmium 0.12J ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:32 7440-43-9 Chromium 1.2J ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:32 7440-47-3 Cobalt 4.7.1 ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:32 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:32 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:32 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:32 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:32 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:32 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:32 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:32 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:32 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 16:10 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 16:10 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 16:10 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 16:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 16:10 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 16:10 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 16:10 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 16:10 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 16:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 16:10 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 16:10 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 16:10 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 16:10 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 16:10 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-6 Lab ID: 92616984007 Collected: 07/26/22 10:46 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 95 % 70-130 102 % 70-130 99 % 70-130 1 07/28/22 16:10 96-12-8 1 07/28/22 16:10 124-48-1 1 07/28/22 16:10 106-93-4 1 07/28/22 16:10 74-95-3 1 07/28/22 16:10 95-50-1 1 07/28/22 16:10 106-46-7 1 07/28/22 16:10 110-57-6 1 07/28/22 16:10 75-34-3 1 07/28/22 16:10 107-06-2 1 07/28/22 16:10 75-35-4 1 07/28/22 16:10 156-59-2 1 07/28/22 16:10 156-60-5 1 07/28/22 16:10 78-87-5 1 07/28/22 16:10 10061-01-5 1 07/28/22 16:10 10061-02-6 1 07/28/22 16:10 100-41-4 1 07/28/22 16:10 591-78-6 1 07/28/22 16:10 74-88-4 1 07/28/22 16:10 75-09-2 1 07/28/22 16:10 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 16:10 100-42-5 07/28/22 16:10 630-20-6 07/28/22 16:10 79-34-5 07/28/22 16:10 127-18-4 07/28/22 16:10 108-88-3 07/28/22 16:10 71-55-6 07/28/22 16:10 79-00-5 07/28/22 16:10 79-01-6 07/28/22 16:10 75-69-4 07/28/22 16:10 96-18-4 07/28/22 16:10 108-05-4 07/28/22 16:10 75-01-4 07/28/22 16:10 1330-20-7 07/28/22 16:10 460-00-4 07/28/22 16:10 17060-07-0 07/28/22 16:10 2037-26-5 Page 25 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-7 Lab ID: 92616984008 Collected: 07/26/22 09:57 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 09:57 pH 5.48 Std. Units 1 07/26/22 09:57 Temperature 17.8 deg C 1 07/26/22 09:57 Static Water Level 29.60 feet 1 07/26/22 09:57 Specific Conductance 284 umhos/c 1 07/26/22 09:57 m Oxidation Potential 77.3 mV 1 07/26/22 09:57 Oxygen, Dissolved 4.70 mg/L 1 07/26/22 09:57 7782-44-7 Total Well Depth 40.13 feet 1 07/26/22 09:57 Turbidity 3.22 NTU 1 07/26/22 09:57 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:38 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:38 7440-38-2 Barium 77.4J ug/L 100 0.67 1 07/28/2210:11 07/28/2217:38 7440-39-3 Beryllium 0.16J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:38 7440-41-7 Cadmium 0.15J ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:38 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:38 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:38 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:38 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:38 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:38 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:38 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:38 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:38 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:38 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:38 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 16:28 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 16:28 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 16:28 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 16:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 16:28 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 16:28 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 16:28 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 16:28 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 16:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 16:28 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 16:28 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 16:28 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 16:28 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 16:28 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-7 Lab ID: 92616984008 Collected: 07/26/22 09:57 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 93 % 70-130 97 % 70-130 103 % 70-130 1 07/28/22 16:28 96-12-8 1 07/28/22 16:28 124-48-1 1 07/28/22 16:28 106-93-4 1 07/28/22 16:28 74-95-3 1 07/28/22 16:28 95-50-1 1 07/28/22 16:28 106-46-7 1 07/28/22 16:28 110-57-6 1 07/28/22 16:28 75-34-3 1 07/28/22 16:28 107-06-2 1 07/28/22 16:28 75-35-4 1 07/28/22 16:28 156-59-2 1 07/28/22 16:28 156-60-5 1 07/28/22 16:28 78-87-5 1 07/28/22 16:28 10061-01-5 1 07/28/22 16:28 10061-02-6 1 07/28/22 16:28 100-41-4 1 07/28/22 16:28 591-78-6 1 07/28/22 16:28 74-88-4 1 07/28/22 16:28 75-09-2 1 07/28/22 16:28 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 16:28 100-42-5 07/28/22 16:28 630-20-6 07/28/22 16:28 79-34-5 07/28/22 16:28 127-18-4 07/28/22 16:28 108-88-3 07/28/22 16:28 71-55-6 07/28/22 16:28 79-00-5 07/28/22 16:28 79-01-6 07/28/22 16:28 75-69-4 07/28/22 16:28 96-18-4 07/28/22 16:28 108-05-4 07/28/22 16:28 75-01-4 07/28/22 16:28 1330-20-7 07/28/22 16:28 460-00-4 07/28/22 16:28 17060-07-0 07/28/22 16:28 2037-26-5 Page 27 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-8 Lab ID: 92616984009 Collected: 07/26/22 09:07 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 09:07 pH 5.82 Std. Units 1 07/26/22 09:07 Temperature 16.2 deg C 1 07/26/22 09:07 Static Water Level 29.72 feet 1 07/26/22 09:07 Specific Conductance 93.9 umhos/c 1 07/26/22 09:07 m Oxidation Potential 67.2 mV 1 07/26/22 09:07 Oxygen, Dissolved 2.28 mg/L 1 07/26/22 09:07 7782-44-7 Total Well Depth 49.56 feet 1 07/26/22 09:07 Turbidity 2.16 NTU 1 07/26/22 09:07 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:44 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:44 7440-38-2 Barium 77.3J ug/L 100 0.67 1 07/28/2210:11 07/28/2217:44 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:44 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:44 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:44 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:44 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:44 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:44 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:44 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:44 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:44 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:44 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:44 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:44 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 21:29 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 21:29 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 21:29 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 21:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 21:29 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 21:29 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 21:29 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 21:29 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 21:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 21:29 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 21:29 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 21:29 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 21:29 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 21:29 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-8 Lab ID: 92616984009 Collected: 07/26/22 09:07 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 101 % 70-130 108 % 70-130 97 % 70-130 1 07/28/22 21:29 96-12-8 1 07/28/22 21:29 124-48-1 1 07/28/22 21:29 106-93-4 1 07/28/22 21:29 74-95-3 1 07/28/22 21:29 95-50-1 1 07/28/22 21:29 106-46-7 1 07/28/22 21:29 110-57-6 1 07/28/22 21:29 75-34-3 1 07/28/22 21:29 107-06-2 1 07/28/22 21:29 75-35-4 1 07/28/22 21:29 156-59-2 1 07/28/22 21:29 156-60-5 1 07/28/22 21:29 78-87-5 1 07/28/22 21:29 10061-01-5 1 07/28/22 21:29 10061-02-6 1 07/28/22 21:29 100-41-4 1 07/28/22 21:29 591-78-6 1 07/28/22 21:29 74-88-4 1 07/28/22 21:29 75-09-2 1 07/28/22 21:29 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 21:29 100-42-5 07/28/22 21:29 630-20-6 07/28/22 21:29 79-34-5 07/28/22 21:29 127-18-4 07/28/22 21:29 108-88-3 07/28/22 21:29 71-55-6 07/28/22 21:29 79-00-5 07/28/22 21:29 79-01-6 07/28/22 21:29 75-69-4 07/28/22 21:29 96-18-4 07/28/22 21:29 108-05-4 07/28/22 21:29 75-01-4 07/28/22 21:29 1330-20-7 07/28/22 21:29 460-00-4 07/28/22 21:29 17060-07-0 07/28/22 21:29 2037-26-5 Page 29 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-9 Lab ID: 92616984010 Collected: 07/26/22 08:14 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 08:14 pH 5.90 Std. Units 1 07/26/22 08:14 Temperature 18.6 deg C 1 07/26/22 08:14 Static Water Level 70.17 feet 1 07/26/22 08:14 Specific Conductance 197.7 umhos/c 1 07/26/22 08:14 m Oxidation Potential 54.3 mV 1 07/26/22 08:14 Oxygen, Dissolved 3.28 mg/L 1 07/26/22 08:14 7782-44-7 Total Well Depth 73.40 feet 1 07/26/22 08:14 Turbidity 0.78 NTU 1 07/26/22 08:14 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:50 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:50 7440-38-2 Barium 15.5J ug/L 100 0.67 1 07/28/2210:11 07/28/2217:50 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:50 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:50 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:50 7440-47-3 Cobalt 0.62J ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:50 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:50 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:50 7439-92-1 Nickel 1.3J ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:50 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:50 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:50 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:50 7440-28-0 Vanadium 2.8J ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:50 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:50 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 21:48 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 21:48 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 21:48 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 21:48 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 21:48 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 21:48 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 21:48 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 21:48 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 21:48 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 21:48 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 21:48 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 21:48 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 21:48 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 21:48 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-9 Lab ID: 92616984010 Collected: 07/26/22 08:14 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 100 % 70-130 114 % 70-130 100 % 70-130 1 07/28/22 21:48 96-12-8 1 07/28/22 21:48 124-48-1 1 07/28/22 21:48 106-93-4 1 07/28/22 21:48 74-95-3 1 07/28/22 21:48 95-50-1 1 07/28/22 21:48 106-46-7 1 07/28/22 21:48 110-57-6 1 07/28/22 21:48 75-34-3 1 07/28/22 21:48 107-06-2 1 07/28/22 21:48 75-35-4 1 07/28/22 21:48 156-59-2 1 07/28/22 21:48 156-60-5 1 07/28/22 21:48 78-87-5 1 07/28/22 21:48 10061-01-5 1 07/28/22 21:48 10061-02-6 1 07/28/22 21:48 100-41-4 1 07/28/22 21:48 591-78-6 1 07/28/22 21:48 74-88-4 1 07/28/22 21:48 75-09-2 1 07/28/22 21:48 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 21:48 100-42-5 07/28/22 21:48 630-20-6 07/28/22 21:48 79-34-5 07/28/22 21:48 127-18-4 07/28/22 21:48 108-88-3 07/28/22 21:48 71-55-6 07/28/22 21:48 79-00-5 07/28/22 21:48 79-01-6 07/28/22 21:48 75-69-4 07/28/22 21:48 96-18-4 07/28/22 21:48 108-05-4 07/28/22 21:48 75-01-4 07/28/22 21:48 1330-20-7 07/28/22 21:48 460-00-4 07/28/22 21:48 17060-07-0 07/28/22 21:48 2037-26-5 Page 31 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-10 Lab ID: 92616984011 Collected: 07/26/22 07:24 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 07:24 pH 6.26 Std. Units 1 07/26/22 07:24 Temperature 17.1 deg C 1 07/26/22 07:24 Static Water Level 78.16 feet 1 07/26/22 07:24 Specific Conductance 59.2 umhos/c 1 07/26/22 07:24 m Oxidation Potential 34.3 mV 1 07/26/22 07:24 Oxygen, Dissolved 5.04 mg/L 1 07/26/22 07:24 7782-44-7 Total Well Depth 88.21 feet 1 07/26/22 07:24 Turbidity 1.04 NTU 1 07/26/22 07:24 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2217:56 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2217:56 7440-38-2 Barium 25.9J ug/L 100 0.67 1 07/28/2210:11 07/28/2217:56 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2217:56 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2217:56 7440-43-9 Chromium 1.1J ug/L 10.0 1.1 1 07/28/2210:11 07/28/2217:56 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2217:56 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2217:56 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2217:56 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2217:56 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2217:56 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2217:56 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2217:56 7440-28-0 Vanadium 4.6J ug/L 25.0 1.9 1 07/28/2210:11 07/28/2217:56 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2217:56 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 22:06 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 22:06 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 22:06 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 22:06 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 22:06 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 22:06 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 22:06 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 22:06 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 22:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 22:06 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 22:06 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 22:06 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 22:06 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 22:06 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-10 Lab ID: 92616984011 Collected: 07/26/22 07:24 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 98 % 70-130 113 % 70-130 101 % 70-130 1 07/28/22 22:06 96-12-8 1 07/28/22 22:06 124-48-1 1 07/28/22 22:06 106-93-4 1 07/28/22 22:06 74-95-3 1 07/28/22 22:06 95-50-1 1 07/28/22 22:06 106-46-7 1 07/28/22 22:06 110-57-6 1 07/28/22 22:06 75-34-3 1 07/28/22 22:06 107-06-2 1 07/28/22 22:06 75-35-4 1 07/28/22 22:06 156-59-2 1 07/28/22 22:06 156-60-5 1 07/28/22 22:06 78-87-5 1 07/28/22 22:06 10061-01-5 1 07/28/22 22:06 10061-02-6 1 07/28/22 22:06 100-41-4 1 07/28/22 22:06 591-78-6 1 07/28/22 22:06 74-88-4 1 07/28/22 22:06 75-09-2 1 07/28/22 22:06 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 22:06 100-42-5 07/28/22 22:06 630-20-6 07/28/22 22:06 79-34-5 07/28/22 22:06 127-18-4 07/28/22 22:06 108-88-3 07/28/22 22:06 71-55-6 07/28/22 22:06 79-00-5 07/28/22 22:06 79-01-6 07/28/22 22:06 75-69-4 07/28/22 22:06 96-18-4 07/28/22 22:06 108-05-4 07/28/22 22:06 75-01-4 07/28/22 22:06 1330-20-7 07/28/22 22:06 460-00-4 07/28/22 22:06 17060-07-0 07/28/22 22:06 2037-26-5 Page 33 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-11 Lab ID: 92616984012 Collected: 07/26/22 06:34 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 06:34 pH 6.06 Std. Units 1 07/26/22 06:34 Temperature 16.7 deg C 1 07/26/22 06:34 Static Water Level 83.23 feet 1 07/26/22 06:34 Specific Conductance 68.9 umhos/c 1 07/26/22 06:34 m Oxidation Potential 45.1 mV 1 07/26/22 06:34 Oxygen, Dissolved 1.98 mg/L 1 07/26/22 06:34 7782-44-7 Total Well Depth 108.40 feet 1 07/26/22 06:34 Turbidity 0.27 NTU 1 07/26/22 06:34 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:02 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:02 7440-38-2 Barium 91.3J ug/L 100 0.67 1 07/28/2210:11 07/28/2218:02 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:02 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:02 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:02 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:02 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:02 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:02 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:02 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:02 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:02 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:02 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:02 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:02 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 22:25 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 22:25 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 22:25 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 22:25 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 22:25 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 22:25 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 22:25 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 22:25 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 22:25 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 22:25 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 22:25 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 22:25 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 22:25 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 22:25 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-MW-11 Lab ID: 92616984012 Collected: 07/26/22 06:34 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 101 % 70-130 107 % 70-130 99 % 70-130 1 07/28/22 22:25 96-12-8 1 07/28/22 22:25 124-48-1 1 07/28/22 22:25 106-93-4 1 07/28/22 22:25 74-95-3 1 07/28/22 22:25 95-50-1 1 07/28/22 22:25 106-46-7 1 07/28/22 22:25 110-57-6 1 07/28/22 22:25 75-34-3 1 07/28/22 22:25 107-06-2 1 07/28/22 22:25 75-35-4 1 07/28/22 22:25 156-59-2 1 07/28/22 22:25 156-60-5 1 07/28/22 22:25 78-87-5 1 07/28/22 22:25 10061-01-5 1 07/28/22 22:25 10061-02-6 1 07/28/22 22:25 100-41-4 1 07/28/22 22:25 591-78-6 1 07/28/22 22:25 74-88-4 1 07/28/22 22:25 75-09-2 1 07/28/22 22:25 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/28/22 22:25 100-42-5 07/28/22 22:25 630-20-6 07/28/22 22:25 79-34-5 07/28/22 22:25 127-18-4 07/28/22 22:25 108-88-3 07/28/22 22:25 71-55-6 07/28/22 22:25 79-00-5 07/28/22 22:25 79-01-6 07/28/22 22:25 75-69-4 07/28/22 22:25 96-18-4 07/28/22 22:25 108-05-4 07/28/22 22:25 75-01-4 07/28/22 22:25 1330-20-7 07/28/22 22:25 460-00-4 07/28/22 22:25 17060-07-0 07/28/22 22:25 2037-26-5 Page 35 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-Field Blank Lab ID: 92616984013 Collected: 07/25/22 14:10 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:08 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:08 7440-38-2 Barium ND ug/L 100 0.67 1 07/28/2210:11 07/28/2218:08 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:08 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:08 7440-43-9 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:08 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:08 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:08 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:08 7439-92-1 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:08 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:08 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:08 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:08 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:08 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:08 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 12:27 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 12:27 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 12:27 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 12:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 12:27 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 12:27 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 12:27 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 12:27 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 12:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 12:27 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 12:27 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 12:27 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 12:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 12:27 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 07/28/22 12:27 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.36 1 07/28/22 12:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.27 1 07/28/22 12:27 106-93-4 Dibromomethane ND ug/L 10.0 0.39 1 07/28/22 12:27 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.34 1 07/28/22 12:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 07/28/22 12:27 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.56 1 07/28/22 12:27 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.37 1 07/28/22 12:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 07/28/22 12:27 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.35 1 07/28/22 12:27 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.38 1 07/28/22 12:27 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-Field Blank Lab ID: 92616984013 Collected: 07/25/22 14:10 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.40 1 07/28/22 12:27 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 12:27 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 12:27 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 12:27 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 12:27 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 12:27 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 12:27 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 12:27 75-09-2 ND ug/L 100 2.7 1 07/28/22 12:27 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 12:27 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 12:27 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 12:27 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 12:27 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 12:27 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 12:27 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 12:27 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 12:27 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 12:27 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 12:27 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 12:27 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 12:27 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 12:27 1330-20-7 97 % 70-130 1 07/28/22 12:27 460-00-4 96 % 70-130 1 07/28/22 12:27 17060-07-0 102 % 70-130 1 07/28/22 12:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW1 Lab ID: 92616984014 Collected: 07/25/22 14:20 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/25/22 14:20 pH 6.52 Std. Units 1 07/25/22 14:20 Temperature 21.9 deg C 1 07/25/22 14:20 Specific Conductance 84.6 umhos/c 1 07/25/22 14:20 m Oxidation Potential 15.8 mV 1 07/25/22 14:20 Oxygen, Dissolved 3.94 mg/L 1 07/25/22 14:20 7782-44-7 Turbidity 7.90 NTU 1 07/25/22 14:20 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:14 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:14 7440-38-2 Barium 24.3J ug/L 100 0.67 1 07/28/2210:11 07/28/2218:14 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:14 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:14 7440-43-9 Calcium 7680 ug/L 100 38.0 1 07/28/2210:11 07/28/2218:14 7440-70-2 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:14 7440-47-3 Cobalt 0.51J ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:14 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:14 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:14 7439-92-1 Magnesium 2180 ug/L 50.0 10.2 1 07/28/2210:11 07/28/2218:14 7439-95-4 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:14 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:14 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:14 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:14 7440-28-0 Total Hardness 28200 ug/L 456 456 1 07/28/22 10:11 07/28/22 18:14 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:14 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:14 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 13:22 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 13:22 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 13:22 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 13:22 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 13:22 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 13:22 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 13:22 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 13:22 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 13:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 13:22 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 13:22 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 13:22 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 13:22 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW1 Lab ID: 92616984014 Collected: 07/25/22 14:20 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/28/22 13:22 74-87-3 ND ug/L 13.0 0.34 1 07/28/22 13:22 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 13:22 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 13:22 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 13:22 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 13:22 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 13:22 106-46-7 ND ug/L 100 0.56 1 07/28/22 13:22 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 13:22 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 13:22 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 13:22 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 13:22 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 13:22 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 13:22 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 13:22 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 13:22 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 13:22 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 13:22 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 13:22 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 13:22 75-09-2 ND ug/L 100 2.7 1 07/28/22 13:22 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 13:22 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 13:22 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 13:22 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 13:22 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 13:22 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 13:22 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 13:22 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 13:22 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 13:22 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 13:22 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 13:22 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 13:22 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 13:22 1330-20-7 92 % 70-130 1 07/28/22 13:22 460-00-4 101 % 70-130 1 07/28/22 13:22 17060-07-0 102 % 70-130 1 07/28/22 13:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW2 Lab ID: 92616984015 Collected: 07/25/22 15:25 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 15:25 pH 6.57 Std. Units 1 07/26/22 15:25 Temperature 21.7 deg C 1 07/26/22 15:25 Specific Conductance 97.5 umhos/c 1 07/26/22 15:25 m Oxidation Potential 17.8 mV 1 07/26/22 15:25 Oxygen, Dissolved 3.58 mg/L 1 07/26/22 15:25 7782-44-7 Turbidity 8.84 NTU 1 07/26/22 15:25 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:20 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:20 7440-38-2 Barium 28.3J ug/L 100 0.67 1 07/28/2210:11 07/28/2218:20 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:20 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:20 7440-43-9 Calcium 8840 ug/L 100 38.0 1 07/28/2210:11 07/28/2218:20 7440-70-2 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:20 7440-47-3 Cobalt 0.63J ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:20 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:20 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:20 7439-92-1 Magnesium 2610 ug/L 50.0 10.2 1 07/28/2210:11 07/28/2218:20 7439-95-4 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:20 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:20 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:20 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:20 7440-28-0 Total Hardness 32800 ug/L 456 456 1 07/28/22 10:11 07/28/22 18:20 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:20 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:20 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 13:41 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 13:41 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 13:41 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 13:41 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 13:41 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 13:41 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 13:41 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 13:41 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 13:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 13:41 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 13:41 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 13:41 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 13:41 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW2 Lab ID: 92616984015 Collected: 07/25/22 15:25 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/28/22 13:41 74-87-3 ND ug/L 13.0 0.34 1 07/28/22 13:41 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 13:41 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 13:41 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 13:41 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 13:41 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 13:41 106-46-7 ND ug/L 100 0.56 1 07/28/22 13:41 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 13:41 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 13:41 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 13:41 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 13:41 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 13:41 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 13:41 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 13:41 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 13:41 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 13:41 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 13:41 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 13:41 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 13:41 75-09-2 ND ug/L 100 2.7 1 07/28/22 13:41 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 13:41 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 13:41 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 13:41 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 13:41 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 13:41 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 13:41 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 13:41 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 13:41 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 13:41 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 13:41 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 13:41 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 13:41 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 13:41 1330-20-7 96 % 70-130 1 07/28/22 13:41 460-00-4 98 % 70-130 1 07/28/22 13:41 17060-07-0 103 % 70-130 1 07/28/22 13:41 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW3 Lab ID: 92616984016 Collected: 07/25/22 16:38 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/25/22 16:38 pH 6.85 Std. Units 1 07/25/22 16:38 Temperature 21.7 deg C 1 07/25/22 16:38 Specific Conductance 72.5 umhos/c 1 07/25/22 16:38 m Oxidation Potential 2.2 mV 1 07/25/22 16:38 Oxygen, Dissolved 5.03 mg/L 1 07/25/22 16:38 7782-44-7 Turbidity 5.15 NTU 1 07/25/22 16:38 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:38 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:38 7440-38-2 Barium 23.OJ ug/L 100 0.67 1 07/28/2210:11 07/28/2218:38 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:38 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:38 7440-43-9 Calcium 5940 ug/L 100 38.0 1 07/28/2210:11 07/28/2218:38 7440-70-2 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:38 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:38 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:38 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:38 7439-92-1 Magnesium 2200 ug/L 50.0 10.2 1 07/28/2210:11 07/28/2218:38 7439-95-4 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:38 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:38 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:38 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:38 7440-28-0 Total Hardness 23900 ug/L 456 456 1 07/28/22 10:11 07/28/22 18:38 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:38 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:38 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 13:59 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 13:59 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 13:59 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 13:59 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 13:59 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 13:59 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 13:59 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 13:59 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 13:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 13:59 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 13:59 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 13:59 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 13:59 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW3 Lab ID: 92616984016 Collected: 07/25/22 16:38 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/28/22 13:59 74-87-3 ND ug/L 13.0 0.34 1 07/28/22 13:59 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 13:59 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 13:59 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 13:59 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 13:59 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 13:59 106-46-7 ND ug/L 100 0.56 1 07/28/22 13:59 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 13:59 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 13:59 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 13:59 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 13:59 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 13:59 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 13:59 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 13:59 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 13:59 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 13:59 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 13:59 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 13:59 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 13:59 75-09-2 ND ug/L 100 2.7 1 07/28/22 13:59 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 13:59 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 13:59 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 13:59 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 13:59 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 13:59 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 13:59 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 13:59 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 13:59 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 13:59 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 13:59 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 13:59 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 13:59 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 13:59 1330-20-7 100 % 70-130 1 07/28/22 13:59 460-00-4 103 % 70-130 1 07/28/22 13:59 17060-07-0 102 % 70-130 1 07/28/22 13:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW4 Lab ID: 92616984017 Collected: 07/25/22 16:15 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/25/22 16:15 pH 6.92 Std. Units 1 07/25/22 16:15 Temperature 21.9 deg C 1 07/25/22 16:15 Specific Conductance 74.1 umhos/c 1 07/25/22 16:15 m Oxidation Potential -1.6 mV 1 07/25/22 16:15 Oxygen, Dissolved 5.10 mg/L 1 07/25/22 16:15 7782-44-7 Turbidity 11.10 NTU 1 07/25/22 16:15 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:44 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:44 7440-38-2 Barium 23.7J ug/L 100 0.67 1 07/28/2210:11 07/28/2218:44 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:44 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:44 7440-43-9 Calcium 5980 ug/L 100 38.0 1 07/28/2210:11 07/28/2218:44 7440-70-2 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:44 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:44 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:44 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:44 7439-92-1 Magnesium 2170 ug/L 50.0 10.2 1 07/28/2210:11 07/28/2218:44 7439-95-4 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:44 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:44 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:44 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:44 7440-28-0 Total Hardness 23900 ug/L 456 456 1 07/28/22 10:11 07/28/22 18:44 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:44 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:44 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 14:18 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 14:18 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 14:18 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 14:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 14:18 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 14:18 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 14:18 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 14:18 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 14:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 14:18 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 14:18 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 14:18 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 14:18 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW4 Lab ID: 92616984017 Collected: 07/25/22 16:15 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/28/22 14:18 74-87-3 ND ug/L 13.0 0.34 1 07/28/22 14:18 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 14:18 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 14:18 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 14:18 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 14:18 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 14:18 106-46-7 ND ug/L 100 0.56 1 07/28/22 14:18 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 14:18 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 14:18 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 14:18 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 14:18 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 14:18 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 14:18 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 14:18 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 14:18 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 14:18 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 14:18 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 14:18 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 14:18 75-09-2 ND ug/L 100 2.7 1 07/28/22 14:18 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 14:18 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 14:18 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 14:18 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 14:18 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 14:18 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 14:18 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 14:18 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 14:18 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 14:18 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 14:18 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 14:18 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 14:18 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 14:18 1330-20-7 97 % 70-130 1 07/28/22 14:18 460-00-4 99 % 70-130 1 07/28/22 14:18 17060-07-0 100 % 70-130 1 07/28/22 14:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW5 Lab ID: 92616984018 Collected: 07/25/22 15:48 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/25/22 15:48 pH 7.44 Std. Units 1 07/25/22 15:48 Temperature 20.6 deg C 1 07/25/22 15:48 Specific Conductance 140.6 umhos/c 1 07/25/22 15:48 m Oxidation Potential -18.2 mV 1 07/25/22 15:48 Oxygen, Dissolved 3.80 mg/L 1 07/25/22 15:48 7782-44-7 Turbidity 6.08 NTU 1 07/25/22 15:48 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:50 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:50 7440-38-2 Barium 24.9J ug/L 100 0.67 1 07/28/2210:11 07/28/2218:50 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:50 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:50 7440-43-9 Calcium 7750 ug/L 100 38.0 1 07/28/2210:11 07/28/2218:50 7440-70-2 Chromium ND ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:50 7440-47-3 Cobalt 0.58J ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:50 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:50 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:50 7439-92-1 Magnesium 2270 ug/L 50.0 10.2 1 07/28/2210:11 07/28/2218:50 7439-95-4 Nickel ND ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:50 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:50 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:50 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:50 7440-28-0 Total Hardness 28700 ug/L 456 456 1 07/28/22 10:11 07/28/22 18:50 Vanadium ND ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:50 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:50 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 14:37 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 14:37 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 14:37 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 14:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 14:37 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 14:37 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 14:37 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 14:37 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 14:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 14:37 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 14:37 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 14:37 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 14:37 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-SW5 Lab ID: 92616984018 Collected: 07/25/22 15:48 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/28/22 14:37 74-87-3 ND ug/L 13.0 0.34 1 07/28/22 14:37 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 14:37 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 14:37 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 14:37 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 14:37 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 14:37 106-46-7 ND ug/L 100 0.56 1 07/28/22 14:37 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 14:37 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 14:37 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 14:37 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 14:37 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 14:37 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 14:37 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 14:37 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 14:37 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 14:37 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 14:37 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 14:37 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 14:37 75-09-2 ND ug/L 100 2.7 1 07/28/22 14:37 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 14:37 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 14:37 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 14:37 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 14:37 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 14:37 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 14:37 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 14:37 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 14:37 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 14:37 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 14:37 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 14:37 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 14:37 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 14:37 1330-20-7 98 % 70-130 1 07/28/22 14:37 460-00-4 103 % 70-130 1 07/28/22 14:37 17060-07-0 101 % 70-130 1 07/28/22 14:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 47 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-UD1 Lab ID: 92616984019 Collected: 07/25/22 15:06 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/25/22 15:06 pH 5.80 Std. Units 1 07/25/22 15:06 Temperature 22.2 deg C 1 07/25/22 15:06 Specific Conductance 217 umhos/c 1 07/25/22 15:06 m Oxidation Potential 60.7 mV 1 07/25/22 15:06 Oxygen, Dissolved 3.90 mg/L 1 07/25/22 15:06 7782-44-7 Turbidity 49.80 NTU 1 07/25/22 15:06 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2218:55 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2218:55 7440-38-2 Barium 77.4J ug/L 100 0.67 1 07/28/2210:11 07/28/2218:55 7440-39-3 Beryllium 0.15J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2218:55 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2218:55 7440-43-9 Chromium 1.1J ug/L 10.0 1.1 1 07/28/2210:11 07/28/2218:55 7440-47-3 Cobalt 7.2J ug/L 10.0 0.39 1 07/28/2210:11 07/28/2218:55 7440-48-4 Copper ND ug/L 10.0 1.0 1 07/28/2210:11 07/28/2218:55 7440-50-8 Lead ND ug/L 10.0 0.89 1 07/28/2210:11 07/28/2218:55 7439-92-1 Nickel 1.4J ug/L 50.0 0.71 1 07/28/2210:11 07/28/2218:55 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2218:55 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2218:55 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2218:55 7440-28-0 Vanadium 5.2J ug/L 25.0 1.9 1 07/28/2210:11 07/28/2218:55 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2218:55 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 14:55 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 14:55 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 14:55 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 14:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 14:55 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 14:55 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 14:55 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 14:55 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 14:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 14:55 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 14:55 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 14:55 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 14:55 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 14:55 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 07/28/22 14:55 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-UD1 Lab ID: 92616984019 Collected: 07/25/22 15:06 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 07/28/22 14:55 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 14:55 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 14:55 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 14:55 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 14:55 106-46-7 ND ug/L 100 0.56 1 07/28/22 14:55 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 14:55 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 14:55 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 14:55 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 14:55 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 14:55 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 14:55 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 14:55 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 14:55 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 14:55 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 14:55 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 14:55 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 14:55 75-09-2 ND ug/L 100 2.7 1 07/28/22 14:55 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 14:55 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 14:55 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 14:55 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 14:55 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 14:55 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 14:55 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 14:55 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 14:55 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 14:55 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 14:55 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 14:55 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 14:55 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 14:55 1330-20-7 99 % 70-130 1 07/28/22 14:55 460-00-4 104 % 70-130 1 07/28/22 14:55 17060-07-0 100 % 70-130 1 07/28/22 14:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-UD2 Lab ID: 92616984020 Collected: 07/25/22 14:44 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/25/22 14:44 pH 6.02 Std. Units 1 07/25/22 14:44 Temperature 21.1 deg C 1 07/25/22 14:44 Specific Conductance 192.6 umhos/c 1 07/25/22 14:44 m Oxidation Potential 60.4 mV 1 07/25/22 14:44 Oxygen, Dissolved 3.72 mg/L 1 07/25/22 14:44 7782-44-7 Turbidity 29.60 NTU 1 07/25/22 14:44 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 07/28/2210:11 07/28/2219:01 7440-36-0 Arsenic ND ug/L 10.0 2.2 1 07/28/2210:11 07/28/2219:01 7440-38-2 Barium 56.9J ug/L 100 0.67 1 07/28/2210:11 07/28/2219:01 7440-39-3 Beryllium 0.17J ug/L 1.0 0.054 1 07/28/2210:11 07/28/2219:01 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 07/28/2210:11 07/28/2219:01 7440-43-9 Chromium 1.5J ug/L 10.0 1.1 1 07/28/2210:11 07/28/2219:01 7440-47-3 Cobalt 5.1J ug/L 10.0 0.39 1 07/28/2210:11 07/28/2219:01 7440-48-4 Copper 1.4J ug/L 10.0 1.0 1 07/28/2210:11 07/28/2219:01 7440-50-8 Lead 1.2J ug/L 10.0 0.89 1 07/28/2210:11 07/28/2219:01 7439-92-1 Nickel 1.1J ug/L 50.0 0.71 1 07/28/2210:11 07/28/2219:01 7440-02-0 Selenium ND ug/L 10.0 1.4 1 07/28/2210:11 07/28/2219:01 7782-49-2 Silver ND ug/L 10.0 0.44 1 07/28/2210:11 07/28/2219:01 7440-22-4 Thallium ND ug/L 5.5 0.18 1 07/28/2210:11 07/28/2219:01 7440-28-0 Vanadium 6.1J ug/L 25.0 1.9 1 07/28/2210:11 07/28/2219:01 7440-62-2 Zinc ND ug/L 10.0 7.0 1 07/28/2210:11 07/28/2219:01 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 07/28/22 15:14 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 07/28/22 15:14 107-13-1 Benzene ND ug/L 1.0 0.34 1 07/28/22 15:14 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 07/28/22 15:14 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 07/28/22 15:14 75-27-4 Bromoform ND ug/L 3.0 0.34 1 07/28/22 15:14 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 07/28/22 15:14 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 07/28/22 15:14 78-93-3 Carbon disulfide ND ug/L 100 0.36 1 07/28/22 15:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 07/28/22 15:14 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 07/28/22 15:14 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 07/28/22 15:14 75-00-3 Chloroform ND ug/L 5.0 0.43 1 07/28/22 15:14 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 07/28/22 15:14 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 07/28/22 15:14 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-UD2 Lab ID: 92616984020 Collected: 07/25/22 14:44 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 07/28/22 15:14 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 15:14 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 15:14 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 15:14 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 15:14 106-46-7 ND ug/L 100 0.56 1 07/28/22 15:14 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 15:14 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 15:14 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 15:14 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 15:14 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 15:14 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 15:14 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 15:14 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 15:14 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 15:14 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 15:14 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 15:14 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 15:14 75-09-2 ND ug/L 100 2.7 1 07/28/22 15:14 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 15:14 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 15:14 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 15:14 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 15:14 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 15:14 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 15:14 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 15:14 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 15:14 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 15:14 75-69-4 ND ug/L 1.0 0.26 1 07/28/22 15:14 96-18-4 ND ug/L 50.0 1.3 1 07/28/22 15:14 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 15:14 75-01-4 ND ug/L 5.0 0.34 1 07/28/22 15:14 1330-20-7 98 % 70-130 1 07/28/22 15:14 460-00-4 106 % 70-130 1 07/28/22 15:14 17060-07-0 100 % 70-130 1 07/28/22 15:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 51 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-Trip Blank Lab ID: 92616984021 Collected: 07/25/22 14:12 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrach loroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Date: 08/10/2022 03:31 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 07/28/22 12:45 67-64-1 ND ug/L 200 1.8 1 07/28/22 12:45 107-13-1 ND ug/L 1.0 0.34 1 07/28/22 12:45 71-43-2 ND ug/L 3.0 0.47 1 07/28/22 12:45 74-97-5 ND ug/L 1.0 0.31 1 07/28/22 12:45 75-27-4 ND ug/L 3.0 0.34 1 07/28/22 12:45 75-25-2 ND ug/L 10.0 1.7 1 07/28/22 12:45 74-83-9 ND ug/L 100 4.0 1 07/28/22 12:45 78-93-3 ND ug/L 100 0.36 1 07/28/22 12:45 75-15-0 ND ug/L 1.0 0.33 1 07/28/22 12:45 56-23-5 ND ug/L 3.0 0.28 1 07/28/22 12:45 108-90-7 ND ug/L 10.0 0.65 1 07/28/22 12:45 75-00-3 ND ug/L 5.0 0.43 1 07/28/22 12:45 67-66-3 ND ug/L 1.0 0.54 1 07/28/22 12:45 74-87-3 ND ug/L 13.0 0.34 1 07/28/22 12:45 96-12-8 ND ug/L 3.0 0.36 1 07/28/22 12:45 124-48-1 ND ug/L 2.0 0.27 1 07/28/22 12:45 106-93-4 ND ug/L 10.0 0.39 1 07/28/22 12:45 74-95-3 ND ug/L 5.0 0.34 1 07/28/22 12:45 95-50-1 ND ug/L 1.0 0.33 1 07/28/22 12:45 106-46-7 ND ug/L 100 0.56 1 07/28/22 12:45 110-57-6 ND ug/L 5.0 0.37 1 07/28/22 12:45 75-34-3 ND ug/L 1.0 0.32 1 07/28/22 12:45 107-06-2 ND ug/L 5.0 0.35 1 07/28/22 12:45 75-35-4 ND ug/L 5.0 0.38 1 07/28/22 12:45 156-59-2 ND ug/L 5.0 0.40 1 07/28/22 12:45 156-60-5 ND ug/L 1.0 0.36 1 07/28/22 12:45 78-87-5 ND ug/L 1.0 0.36 1 07/28/22 12:45 10061-01-5 ND ug/L 1.0 0.36 1 07/28/22 12:45 10061-02-6 ND ug/L 1.0 0.30 1 07/28/22 12:45 100-41-4 ND ug/L 50.0 0.48 1 07/28/22 12:45 591-78-6 ND ug/L 20.0 9.7 1 07/28/22 12:45 74-88-4 ND ug/L 5.0 2.0 1 07/28/22 12:45 75-09-2 ND ug/L 100 2.7 1 07/28/22 12:45 108-10-1 ND ug/L 1.0 0.29 1 07/28/22 12:45 100-42-5 ND ug/L 5.0 0.31 1 07/28/22 12:45 630-20-6 ND ug/L 3.0 0.22 1 07/28/22 12:45 79-34-5 ND ug/L 1.0 0.29 1 07/28/22 12:45 127-18-4 ND ug/L 1.0 0.48 1 07/28/22 12:45 108-88-3 ND ug/L 1.0 0.33 1 07/28/22 12:45 71-55-6 ND ug/L 1.0 0.32 1 07/28/22 12:45 79-00-5 ND ug/L 1.0 0.38 1 07/28/22 12:45 79-01-6 ND ug/L 1.0 0.30 1 07/28/22 12:45 75-69-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Sample: 1403-Trip Blank Lab ID: 92616984021 Collected: 07/25/22 14:12 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/10/2022 03:31 PM ND ug/L 1.0 0.26 1 07/28/2212:45 96-18-4 ND ug/L 50.0 1.3 1 07/28/2212:45 108-05-4 ND ug/L 1.0 0.39 1 07/28/22 12:45 75-01-4 ND ug/L 5.0 0.34 1 07/28/2212:45 1330-20-7 100 % 70-130 1 07/28/2212:45 460-00-4 97 % 70-130 1 07/28/2212:45 17060-07-0 101 % 70-130 1 07/28/2212:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 QC Batch: 713414 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92616984001, 92616984002, 92616984003, 92616984004, 92616984005, 92616984006, 92616984007, 92616984008,92616984009,92616984010,92616984011,92616984012,92616984013,92616984014, 92616984015,92616984016,92616984017,92616984018,92616984019,92616984020 METHOD BLANK: 3719520 Matrix: Water Associated Lab Samples: 92616984001, 92616984002, 92616984003, 92616984004, 92616984005, 92616984006, 92616984007, 92616984008,92616984009,92616984010,92616984011,92616984012,92616984013,92616984014, 92616984015,92616984016,92616984017,92616984018,92616984019,92616984020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 07/28/2216:07 Arsenic ug/L ND 10.0 2.2 07/28/2216:07 Barium ug/L ND 100 0.67 07/28/2216:07 Beryllium ug/L ND 1.0 0.054 07/28/2216:07 Cadmium ug/L ND 1.0 0.11 07/28/2216:07 Calcium ug/L ND 100 38.0 07/28/2216:07 Chromium ug/L ND 10.0 1.1 07/28/2216:07 Cobalt ug/L ND 10.0 0.39 07/28/2216:07 Copper ug/L ND 10.0 1.0 07/28/2216:07 Lead ug/L ND 10.0 0.89 07/28/2216:07 Magnesium ug/L ND 50.0 10.2 07/28/2216:07 Nickel ug/L ND 50.0 0.71 07/28/2216:07 Selenium ug/L ND 10.0 1.4 07/28/2216:07 Silver ug/L ND 10.0 0.44 07/28/2216:07 Thallium ug/L ND 5.5 0.18 07/28/2216:07 Total Hardness ug/L ND 456 456 07/28/22 16:07 Vanadium ug/L ND 25.0 1.9 07/28/2216:07 Zinc ug/L ND 10.0 7.0 07/28/2216:07 LABORATORY CONTROL SAMPLE: Parameter 3719521 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 103 103 80-120 Arsenic ug/L 100 94.3 94 80-120 Barium ug/L 100 95.6J 96 80-120 Beryllium ug/L 100 96.3 96 80-120 Cadmium ug/L 100 96.1 96 80-120 Calcium ug/L 1000 964 96 80-120 Chromium ug/L 100 96.7 97 80-120 Cobalt ug/L 100 94.6 95 80-120 Copper ug/L 100 92.5 92 80-120 Lead ug/L 100 97.2 97 80-120 Magnesium ug/L 1000 988 99 80-120 Nickel ug/L 100 96.4 96 80-120 Selenium ug/L 100 95.4 95 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 LABORATORY CONTROL SAMPLE: 3719521 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Silver ug/L 100 96.5 97 80-120 Thallium ug/L 100 97.4 97 80-120 Total Hardness ug/L 6470 Vanadium ug/L 100 96.2 96 80-120 Zinc ug/L 100 101 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719522 3719523 MS MSD 92616984004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 105 103 105 103 75-125 2 20 Arsenic ug/L ND 100 100 96.8 95.4 97 95 75-125 1 20 Barium ug/L 47.1J 100 100 152 148 105 101 75-125 2 20 Beryllium ug/L 0.082J 100 100 102 96.6 102 97 75-125 5 20 Cadmium ug/L ND 100 100 98.4 98.6 98 99 75-125 0 20 Calcium ug/L 1260 1000 1000 2390 2290 113 103 75-125 4 20 Chromium ug/L ND 100 100 102 99.6 102 99 75-125 2 20 Cobalt ug/L 14.1 100 100 114 110 100 96 75-125 3 20 Copper ug/L ND 100 100 94.7 91.4 95 91 75-125 4 20 Lead ug/L ND 100 100 100 97.3 100 97 75-125 3 20 Magnesium ug/L 1090 1000 1000 2170 2110 108 102 75-125 3 20 Nickel ug/L ND 100 100 99.7 95.8 99 95 75-125 4 20 Selenium ug/L ND 100 100 96.9 96.4 97 96 75-125 1 20 Silver ug/L ND 100 100 97.9 96.3 98 96 75-125 2 20 Thallium ug/L ND 100 100 101 98.0 100 98 75-125 3 20 Total Hardness ug/L 7650 14900 14400 4 Vanadium ug/L ND 100 100 101 97.8 101 98 75-125 3 20 Zinc ug/L ND 100 100 105 104 103 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 QC Batch: 713425 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92616984001, 92616984002, 92616984003, 92616984004, 92616984005, 92616984006, 92616984007, 92616984008,92616984013,92616984014,92616984015,92616984016,92616984017,92616984018, 92616984019,92616984020,92616984021 METHOD BLANK: 3719551 Matrix: Water Associated Lab Samples: 92616984001, 92616984002, 92616984003, 92616984004, 92616984005, 92616984006, 92616984007, 92616984008,92616984013,92616984014,92616984015,92616984016,92616984017,92616984018, 92616984019,92616984020,92616984021 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 07/28/22 12:08 1,1,1-Trichloroethane ug/L ND 1.0 0.33 07/28/22 12:08 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 07/28/22 12:08 1,1,2-Trichloroethane ug/L ND 1.0 0.32 07/28/22 12:08 1,1-Dichloroethane ug/L ND 5.0 0.37 07/28/22 12:08 1,1-Dichloroethene ug/L ND 5.0 0.35 07/28/22 12:08 1,2,3-Trichloropropane ug/L ND 1.0 0.26 07/28/22 12:08 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 07/28/22 12:08 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 07/28/22 12:08 1,2-Dichlorobenzene ug/L ND 5.0 0.34 07/28/22 12:08 1,2-Dichloroethane ug/L ND 1.0 0.32 07/28/22 12:08 1,2-Dichloropropane ug/L ND 1.0 0.36 07/28/22 12:08 1,4-Dichlorobenzene ug/L ND 1.0 0.33 07/28/22 12:08 2-Butanone (MEK) ug/L ND 100 4.0 07/28/22 12:08 2-Hexanone ug/L ND 50.0 0.48 07/28/22 12:08 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 07/28/22 12:08 Acetone ug/L ND 100 5.1 07/28/22 12:08 Acrylonitrile ug/L ND 200 1.8 07/28/22 12:08 Benzene ug/L ND 1.0 0.34 07/28/22 12:08 Bromochloromethane ug/L ND 3.0 0.47 07/28/22 12:08 Bromodichloromethane ug/L ND 1.0 0.31 07/28/22 12:08 Bromoform ug/L ND 3.0 0.34 07/28/22 12:08 Bromomethane ug/L ND 10.0 1.7 07/28/22 12:08 Carbon disulfide ug/L ND 100 0.36 07/28/22 12:08 Carbon tetrachloride ug/L ND 1.0 0.33 07/28/22 12:08 Chlorobenzene ug/L ND 3.0 0.28 07/28/22 12:08 Chloroethane ug/L ND 10.0 0.65 07/28/22 12:08 Chloroform ug/L 0.89J 5.0 0.43 07/28/22 12:08 Chloromethane ug/L ND 1.0 0.54 07/28/22 12:08 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 07/28/22 12:08 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 07/28/22 12:08 Dibromochloromethane ug/L ND 3.0 0.36 07/28/22 12:08 Dibromomethane ug/L ND 10.0 0.39 07/28/22 12:08 Ethylbenzene ug/L ND 1.0 0.30 07/28/22 12:08 lodomethane ug/L ND 20.0 9.7 07/28/22 12:08 Methylene Chloride ug/L ND 5.0 2.0 07/28/22 12:08 Styrene ug/L ND 1.0 0.29 07/28/22 12:08 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 METHOD BLANK: 3719551 Matrix: Water Associated Lab Samples: 92616984001, 92616984002, 92616984003, 92616984004, 92616984005, 92616984006, 92616984007, 92616984008,92616984013,92616984014,92616984015,92616984016,92616984017,92616984018, 92616984019,92616984020,92616984021 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.29 07/28/22 12:08 Toluene ug/L ND 1.0 0.48 07/28/22 12:08 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 07/28/22 12:08 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 07/28/22 12:08 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 07/28/22 12:08 Trichloroethene ug/L ND 1.0 0.38 07/28/22 12:08 Trichlorofluoromethane ug/L ND 1.0 0.30 07/28/22 12:08 Vinyl acetate ug/L ND 50.0 1.3 07/28/22 12:08 Vinyl chloride ug/L ND 1.0 0.39 07/28/22 12:08 Xylene (Total) ug/L ND 5.0 0.34 07/28/22 12:08 1,2-Dichloroethane-d4 (S) % 100 70-130 07/28/22 12:08 4-Bromofluorobenzene (S) % 98 70-130 07/28/22 12:08 Toluene-d8 (S) % 105 70-130 07/28/22 12:08 LABORATORY CONTROL SAMPLE: 3719552 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.0 106 70-130 1,1,1-Trichloroethane ug/L 50 55.0 110 70-130 1,1,2,2-Tetrachloroethane ug/L 50 43.7 87 70-130 1,1,2-Trichloroethane ug/L 50 47.6 95 70-130 1,1-Dichloroethane ug/L 50 45.2 90 70-130 1,1-Dichloroethene ug/L 50 51.1 102 70-132 1,2,3-Trichloropropane ug/L 50 41.8 84 70-130 1,2-Dibromo-3-chloropropane ug/L 50 48.6 97 70-132 1,2-Dibromoethane (EDB) ug/L 50 50.8 102 70-130 1,2-Dichlorobenzene ug/L 50 49.1 98 70-130 1,2-Dichloroethane ug/L 50 47.9 96 70-130 1,2-Dichloropropane ug/L 50 45.3 91 70-130 1,4-Dichlorobenzene ug/L 50 45.6 91 70-130 2-Butanone (MEK) ug/L 100 99.11 99 70-133 2-Hexanone ug/L 100 99.3 99 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 93.1J 93 70-130 Acetone ug/L 100 104 104 70-144 Acrylonitrile ug/L 250 250 100 70-130 Benzene ug/L 50 46.0 92 70-130 Bromochloromethane ug/L 50 50.2 100 70-130 Bromodichloromethane ug/L 50 49.9 100 70-130 Bromoform ug/L 50 49.4 99 70-131 Bromomethane ug/L 50 52.2 104 30-177 Carbon disulfide ug/L 50 49.OJ 98 70-133 Carbon tetrachloride ug/L 50 55.9 112 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 LABORATORY CONTROL SAMPLE: Parameter 3719552 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Chlorobenzene ug/L 50 49.6 99 70-130 Chloroethane ug/L 50 54.3 109 46-131 Chloroform ug/L 50 44.6 89 70-130 Chloromethane ug/L 50 52.6 105 49-130 cis-1,2-Dichloroethene ug/L 50 46.2 92 70-130 cis-1,3-Dichloropropene ug/L 50 52.0 104 70-130 Dibromochloromethane ug/L 50 57.3 115 70-130 Dibromomethane ug/L 50 48.3 97 70-130 Ethylbenzene ug/L 50 49.2 98 70-130 lodomethane ug/L 100 117 117 47-140 Methylene Chloride ug/L 50 41.4 83 68-130 Styrene ug/L 50 47.8 96 70-130 Tetrachloroethene ug/L 50 52.1 104 70-130 Toluene ug/L 50 44.7 89 70-130 trans-1,2-Dichloroethene ug/L 50 49.2 98 70-130 trans- 1,3-Dichloropropene ug/L 50 52.6 105 70-130 trans-1,4-Dichloro-2-butene ug/L 50 60.7J 121 25-200 Trichloroethene ug/L 50 53.0 106 70-130 Trichlorofluoromethane ug/L 50 56.9 114 61-130 Vinyl acetate ug/L 100 91.6 92 70-140 Vinyl chloride ug/L 50 57.6 115 59-142 Xylene (Total) ug/L 150 149 99 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 92 70-130 Toluene-d8 (S) % 93 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719553 MS 92616984004 Spike Parameter Units Result Conc. MSD Spike Conc. 3719554 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.8 21.4 109 107 70-135 2 30 1,1,1-Trichloroethane ug/L ND 20 20 21.7 23.1 108 116 70-148 7 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 18.2 18.6 91 93 70-131 2 30 1,1,2-Trichloroethane ug/L ND 20 20 19.5 21.6 98 108 70-136 10 30 1,1-Dichloroethane ug/L ND 20 20 19.0 18.2 95 91 70-147 5 30 1,1-Dichloroethene ug/L ND 20 20 19.7 20.2 98 101 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 18.5 19.1 92 95 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 19.2 20.0 96 100 69-136 4 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.3 22.1 107 111 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 20.6 19.7 103 98 70-133 5 30 1,2-Dichloroethane ug/L ND 20 20 19.8 20.2 99 101 67-138 2 30 1,2-Dichloropropane ug/L ND 20 20 17.3 18.3 86 91 70-138 6 30 1,4-Dichlorobenzene ug/L ND 20 20 19.2 19.6 96 98 70-133 2 30 2-Butanone (MEK) ug/L ND 40 40 43.7J 45.3J 109 113 61-147 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719553 3719554 MS MSD 92616984004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2-Hexanone ug/L ND 40 40 42.9J 45.3J 107 113 67-139 5 30 4-Methyl-2-pentanone ug/L ND 40 40 40.8J 42.OJ 102 105 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 44.6J 48.1J 111 120 55-159 8 30 Acrylonitrile ug/L ND 100 100 99.2J 1091 99 109 68-140 9 30 Benzene ug/L ND 20 20 17.9 19.3 90 97 67-150 7 30 Bromochloromethane ug/L ND 20 20 21.9 19.3 109 96 70-146 12 30 Bromodichloromethane ug/L ND 20 20 19.4 20.1 97 101 70-138 4 30 Bromoform ug/L ND 20 20 18.0 18.0 90 90 57-138 0 30 Bromomethane ug/L ND 20 20 15.6 20.4 78 102 10-200 27 30 Carbon disulfide ug/L ND 20 20 18.1J 18AJ 90 92 70-152 2 30 Carbon tetrachloride ug/L ND 20 20 21.8 23.1 109 115 70-147 6 30 Chlorobenzene ug/L ND 20 20 20.5 21.1 102 105 70-137 3 30 Chloroethane ug/L ND 20 20 21.4 19.7 107 99 51-166 8 30 Chloroform ug/L ND 20 20 20.7 18.5 103 93 70-144 11 30 Chloromethane ug/L ND 20 20 21.2 21.6 106 108 24-161 2 30 cis-1,2-Dichloroethene ug/L ND 20 20 17.2 18.9 86 95 67-148 10 30 cis-1,3-Dichloropropene ug/L ND 20 20 18.4 18.9 92 95 70-142 3 30 Dibromochloromethane ug/L ND 20 20 21.8 21.5 109 107 68-138 1 30 Dibromomethane ug/L ND 20 20 20.8 20.2 104 101 70-134 3 30 Ethylbenzene ug/L ND 20 20 20.9 20.8 105 104 68-143 1 30 lodomethane ug/L ND 40 40 41.1 47.7 103 119 20-161 15 30 Methylene Chloride ug/L ND 20 20 15.0 17.1 75 86 64-148 13 30 Styrene ug/L ND 20 20 20.2 20.4 101 102 70-136 1 30 Tetrachloroethene ug/L ND 20 20 21.5 21.6 108 108 70-139 0 30 Toluene ug/L ND 20 20 18.3 19.1 91 95 47-157 4 30 trans-1,2-Dichloroethene ug/L ND 20 20 19.9 19.5 99 97 70-149 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 18.8 19.8 94 99 70-138 6 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 18.5J 18.6J 93 93 31-145 0 30 Trichloroethene ug/L ND 20 20 21.7 21.8 109 109 70-149 0 30 Trichlorofluoromethane ug/L ND 20 20 24.0 23.7 120 118 61-154 1 30 Vinyl acetate ug/L ND 40 40 31.5J 32.7J 79 82 48-156 4 30 Vinyl chloride ug/L ND 20 20 22.1 23.7 111 119 55-172 7 30 Xylene (Total) ug/L ND 60 60 61.4 62.6 102 104 66-145 2 30 1,2-Dichloroethane-d4 (S) % 102 103 70-130 4-Bromofluorobenzene (S) % 96 96 70-130 Toluene-d8 (S) % 91 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 QC Batch: 713486 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92616984009, 92616984010, 92616984011, 92616984012 METHOD BLANK: 3719945 Matrix: Water Associated Lab Samples: 92616984009, 92616984010, 92616984011, 92616984012 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 07/28/22 13:27 1,1,1-Trichloroethane ug/L ND 1.0 0.33 07/28/22 13:27 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 07/28/22 13:27 1,1,2-Trichloroethane ug/L ND 1.0 0.32 07/28/22 13:27 1,1-Dichloroethane ug/L ND 5.0 0.37 07/28/22 13:27 1,1-Dichloroethene ug/L ND 5.0 0.35 07/28/22 13:27 1,2,3-Trichloropropane ug/L ND 1.0 0.26 07/28/22 13:27 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 07/28/22 13:27 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 07/28/22 13:27 1,2-Dichlorobenzene ug/L ND 5.0 0.34 07/28/22 13:27 1,2-Dichloroethane ug/L ND 1.0 0.32 07/28/22 13:27 1,2-Dichloropropane ug/L ND 1.0 0.36 07/28/22 13:27 1,4-Dichlorobenzene ug/L ND 1.0 0.33 07/28/22 13:27 2-Butanone (MEK) ug/L ND 100 4.0 07/28/22 13:27 2-Hexanone ug/L ND 50.0 0.48 07/28/22 13:27 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 07/28/22 13:27 Acetone ug/L ND 100 5.1 07/28/22 13:27 Acrylonitrile ug/L ND 200 1.8 07/28/22 13:27 Benzene ug/L ND 1.0 0.34 07/28/22 13:27 Bromochloromethane ug/L ND 3.0 0.47 07/28/22 13:27 Bromodichloromethane ug/L ND 1.0 0.31 07/28/22 13:27 Bromoform ug/L ND 3.0 0.34 07/28/22 13:27 Bromomethane ug/L ND 10.0 1.7 07/28/22 13:27 Carbon disulfide ug/L ND 100 0.36 07/28/22 13:27 Carbon tetrachloride ug/L ND 1.0 0.33 07/28/22 13:27 Chlorobenzene ug/L ND 3.0 0.28 07/28/22 13:27 Chloroethane ug/L ND 10.0 0.65 07/28/22 13:27 Chloroform ug/L ND 5.0 0.43 07/28/22 13:27 Chloromethane ug/L ND 1.0 0.54 07/28/22 13:27 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 07/28/22 13:27 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 07/28/22 13:27 Dibromochloromethane ug/L ND 3.0 0.36 07/28/22 13:27 Dibromomethane ug/L ND 10.0 0.39 07/28/22 13:27 Ethylbenzene ug/L ND 1.0 0.30 07/28/22 13:27 lodomethane ug/L ND 20.0 9.7 07/28/22 13:27 Methylene Chloride ug/L ND 5.0 2.0 07/28/22 13:27 Styrene ug/L ND 1.0 0.29 07/28/22 13:27 Tetrachloroethene ug/L ND 1.0 0.29 07/28/22 13:27 Toluene ug/L ND 1.0 0.48 07/28/22 13:27 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 07/28/22 13:27 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 METHOD BLANK: 3719945 Matrix: Water Associated Lab Samples: 92616984009, 92616984010, 92616984011, 92616984012 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 07/28/22 13:27 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 07/28/22 13:27 Trichloroethene ug/L ND 1.0 0.38 07/28/22 13:27 Trichlorofluoromethane ug/L ND 1.0 0.30 07/28/22 13:27 Vinyl acetate ug/L ND 50.0 1.3 07/28/22 13:27 Vinyl chloride ug/L ND 1.0 0.39 07/28/22 13:27 Xylene (Total) ug/L ND 5.0 0.34 07/28/22 13:27 1,2-Dichloroethane-d4 (S) % 103 70-130 07/28/22 13:27 4-Bromofluorobenzene (S) % 101 70-130 07/28/22 13:27 Toluene-d8 (S) % 99 70-130 07/28/22 13:27 LABORATORY CONTROL SAMPLE: Parameter 3719946 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 50.1 100 70-130 1,1,1-Trichloroethane ug/L 50 45.4 91 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.3 95 70-130 1,1,2-Trichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethane ug/L 50 44.8 90 70-130 1,1-Dichloroethene ug/L 50 45.4 91 70-132 1,2,3-Trichloropropane ug/L 50 44.5 89 70-130 1,2-Dibromo-3-chloropropane ug/L 50 45.1 90 70-132 1,2-Dibromoethane (EDB) ug/L 50 47.7 95 70-130 1,2-Dichlorobenzene ug/L 50 48.1 96 70-130 1,2-Dichloroethane ug/L 50 47.0 94 70-130 1,2-Dichloropropane ug/L 50 45.0 90 70-130 1,4-Dichlorobenzene ug/L 50 46.9 94 70-130 2-Butanone (MEK) ug/L 100 92.1J 92 70-133 2-Hexanone ug/L 100 96.0 96 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 90.5J 91 70-130 Acetone ug/L 100 89AJ 89 70-144 Acrylonitrile ug/L 250 225 90 70-130 Benzene ug/L 50 43.6 87 70-130 Bromochloromethane ug/L 50 49.6 99 70-130 Bromodichloromethane ug/L 50 47.5 95 70-130 Bromoform ug/L 50 49.5 99 70-131 Bromomethane ug/L 50 43.7 87 30-177 Carbon disulfide ug/L 50 46.3J 93 70-133 Carbon tetrachloride ug/L 50 49.4 99 70-130 Chlorobenzene ug/L 50 46.3 93 70-130 Chloroethane ug/L 50 52.4 105 46-131 Chloroform ug/L 50 40.8 82 70-130 Chloromethane ug/L 50 46.2 92 49-130 cis-1,2-Dichloroethene ug/L 50 45.3 91 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 LABORATORY CONTROL SAMPLE: Parameter 3719946 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 47.8 96 70-130 Dibromochloromethane ug/L 50 49.0 98 70-130 Dibromomethane ug/L 50 46.1 92 70-130 Ethylbenzene ug/L 50 46.9 94 70-130 lodomethane ug/L 100 102 102 47-140 Methylene Chloride ug/L 50 43.5 87 68-130 Styrene ug/L 50 49.1 98 70-130 Tetrachloroethene ug/L 50 45.9 92 70-130 Toluene ug/L 50 44.0 88 70-130 trans-1,2-Dichloroethene ug/L 50 47.4 95 70-130 trans- 1,3-Dichloropropene ug/L 50 48.1 96 70-130 trans-1,4-Dichloro-2-butene ug/L 50 45.3J 91 25-200 Trichloroethene ug/L 50 48.1 96 70-130 Trichlorofluoromethane ug/L 50 45.5 91 61-130 Vinyl acetate ug/L 100 93.5 94 70-140 Vinyl chloride ug/L 50 51.9 104 59-142 Xylene (Total) ug/L 150 142 95 70-130 1,2-Dichloroethane-d4 (S) % 103 70-130 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719947 MS 92616984009 Spike Parameter Units Result Conc. MSD Spike Conc. 3719948 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.1 22.3 111 111 70-135 1 30 1,1,1-Trichloroethane ug/L ND 20 20 22.5 22.6 112 113 70-148 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.9 21.4 104 107 70-131 3 30 1,1,2-Trichloroethane ug/L ND 20 20 21.5 21.9 107 109 70-136 2 30 1,1-Dichloroethane ug/L ND 20 20 22.3 22.0 111 110 70-147 1 30 1,1-Dichloroethene ug/L ND 20 20 22.4 22.4 112 112 70-158 0 30 1,2,3-Trichloropropane ug/L ND 20 20 20.3 20.6 101 103 67-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 18.6 20.7 93 104 69-136 11 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.1 21.5 106 108 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 21.6 22.2 108 111 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 22.0 21.8 110 109 67-138 1 30 1,2-Dichloropropane ug/L ND 20 20 21.5 21.4 108 107 70-138 1 30 1,4-Dichlorobenzene ug/L ND 20 20 21.0 21.7 105 109 70-133 3 30 2-Butanone (MEK) ug/L ND 40 40 45.7J 47.7J 114 119 61-147 4 30 2-Hexanone ug/L ND 40 40 44.9J 46.7J 112 117 67-139 4 30 4-Methyl-2-pentanone ug/L ND 40 40 43AJ 43AJ 109 109 67-136 0 30 (MIBK) Acetone ug/L ND 40 40 45.3J 48.1J 113 120 55-159 6 30 Acrylonitrile ug/L ND 100 100 97.3J 1011 97 101 68-140 3 30 Benzene ug/L ND 20 20 20.2 21.0 101 105 67-150 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719947 MS 92616984009 Spike Parameter Units Result Conc. MSD Spike Conc. 3719948 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 22.3 22.5 112 112 70-146 1 30 Bromodichloromethane ug/L ND 20 20 21.2 21.8 106 109 70-138 3 30 Bromoform ug/L ND 20 20 17.6 18.9 88 95 57-138 7 30 Bromomethane ug/L ND 20 20 20.1 20.4 100 102 10-200 1 30 v3 Carbon disulfide ug/L ND 20 20 23.7J 22.7J 118 114 70-152 4 30 Carbon tetrachloride ug/L ND 20 20 23.0 23.3 115 117 70-147 1 30 Chlorobenzene ug/L ND 20 20 21.2 21.4 106 107 70-137 1 30 Chloroethane ug/L ND 20 20 28.1 27.2 140 136 51-166 3 30 Chloroform ug/L ND 20 20 21.0 22.2 104 110 70-144 5 30 Chloromethane ug/L ND 20 20 25.5 23.9 128 120 24-161 6 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.3 21.7 107 109 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.4 22.0 107 110 70-142 2 30 Dibromochloromethane ug/L ND 20 20 19.3 19.6 96 98 68-138 2 30 Dibromomethane ug/L ND 20 20 20.6 21.3 103 106 70-134 3 30 Ethylbenzene ug/L ND 20 20 21.6 22.1 108 111 68-143 2 30 lodomethane ug/L ND 40 40 47.6 47.0 119 118 20-161 1 30 Methylene Chloride ug/L ND 20 20 17.5 17.6 88 88 64-148 0 30 Styrene ug/L ND 20 20 21.1 21.6 106 108 70-136 2 30 Tetrachloroethene ug/L ND 20 20 21.2 21.7 106 108 70-139 2 30 Toluene ug/L ND 20 20 20.9 21.4 105 107 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.4 22.9 117 115 70-149 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.2 21.8 106 109 70-138 3 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 14.7J 19.6J 74 98 31-145 28 30 Trichloroethene ug/L ND 20 20 22.6 21.8 113 109 70-149 4 30 Tri ch lo rofl u oro m eth a n e ug/L ND 20 20 23.6 23.1 118 116 61-154 2 30 Vinyl acetate ug/L ND 40 40 44.2J 44.5J 110 111 48-156 1 30 Vinyl chloride ug/L ND 20 20 26.1 27.0 131 135 55-172 3 30 Xylene (Total) ug/L ND 60 60 64.7 65.5 108 109 66-145 1 30 1,2-Dichloroethane-d4 (S) % 111 106 70-130 4-Bromofluorobenzene (S) % 101 101 70-130 Toluene-d8 (S) % 101 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS CO Result confirmed by second analysis. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92616984001 1403-MW-1R2 716244 92616984002 1403-MW-2R 716244 92616984003 1403-MW-3R2 716244 92616984004 1403-MW-4 716244 92616984006 1403-MW-5 716244 92616984007 1403-MW-6 716244 92616984008 1403-MW-7 716244 92616984009 1403-MW-8 716244 92616984010 1403-MW-9 716244 92616984011 1403-MW-10 716244 92616984012 1403-MW-11 716244 92616984014 1403-SW1 716244 92616984015 1403-SW2 716244 92616984016 1403-SW3 716244 92616984017 1403-SW4 716244 92616984018 1403-SW5 716244 92616984019 1403-U D1 716244 92616984020 1403-U D2 716244 92616984001 1403-MW-1R2 EPA 3005A 713414 EPA 6020B 713532 92616984002 1403-MW-2R EPA 3005A 713414 EPA 6020B 713532 92616984003 1403-MW-3R2 EPA 3005A 713414 EPA 6020B 713532 92616984004 1403-MW-4 EPA 3005A 713414 EPA 6020B 713532 92616984005 1403-DUP@MW-2R EPA 3005A 713414 EPA 6020B 713532 92616984006 1403-MW-5 EPA 3005A 713414 EPA 6020B 713532 92616984007 1403-MW-6 EPA 3005A 713414 EPA 6020B 713532 92616984008 1403-MW-7 EPA 3005A 713414 EPA 6020B 713532 92616984009 1403-MW-8 EPA 3005A 713414 EPA 6020B 713532 92616984010 1403-MW-9 EPA 3005A 713414 EPA 6020B 713532 92616984011 1403-MW-10 EPA 3005A 713414 EPA 6020B 713532 92616984012 1403-MW-11 EPA 3005A 713414 EPA 6020B 713532 92616984013 1403-Field Blank EPA 3005A 713414 EPA 6020B 713532 92616984014 1403-SW1 EPA 3005A 713414 EPA 6020B 713532 92616984015 1403-SW2 EPA 3005A 713414 EPA 6020B 713532 92616984016 1403-SW3 EPA 3005A 713414 EPA 6020B 713532 92616984017 1403-SW4 EPA 3005A 713414 EPA 6020B 713532 92616984018 1403-SW5 EPA 3005A 713414 EPA 6020B 713532 92616984019 1403-U D1 EPA 3005A 713414 EPA 6020B 713532 92616984020 1403-U D2 EPA 3005A 713414 EPA 6020B 713532 92616984001 1403-MW-1R2 EPA 8260D 713425 92616984002 1403-MW-2R EPA 8260D 713425 92616984003 1403-MW-3R2 EPA 8260D 713425 92616984004 1403-MW-4 EPA 8260D 713425 92616984005 1403-DUP@MW-2R EPA 8260D 713425 92616984006 1403-MW-5 EPA 8260D 713425 92616984007 1403-MW-6 EPA 8260D 713425 92616984008 1403-MW-7 EPA 8260D 713425 92616984009 1403-MW-8 EPA 8260D 713486 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/10/2022 03:31 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/SemiAnnual Pace Project No.: 92616984 Lab ID Sample ID QC Batch Method QC Batch 92616984010 1403-MW-9 EPA 8260D 713486 92616984011 1403-MW-10 EPA 8260D 713486 92616984012 1403-MW-11 EPA 8260D 713486 92616984013 1403-Field Blank EPA 8260D 713425 92616984014 1403-SW1 EPA 8260D 713425 92616984015 1403-SW2 EPA 8260D 713425 92616984016 1403-SW3 EPA 8260D 713425 92616984017 1403-SW4 EPA 8260D 713425 92616984018 1403-SW5 EPA 8260D 713425 92616984019 1403-UD1 EPA 8260D 713425 92616984020 1403-UD2 EPA 8260D 713425 92616984021 1403-Trip Blank EPA 8260D 713425 Date: 08/10/2022 03:31 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 66 of 92 "n z �+ m o a c a r m Fi fa a� A � N Ii Go of J.]J J�iJ �7J J.]-J a-13 o 9iN N N N . N . nr t N N N N N v Oz P N~ i`� N N N N N N N m o N N I� co too LA .0 C J vi 4 C- 6 � G • d W N C m pp GC)GC)G{{}GCC)C0CGCC)GC)GCC)G)GCC7GC)GCC) $f vx0 xxxIx xXXXXXi:iCmaz 40, w 1r m w w p 0 0 0 0 O w O (.0+ Co wwwwwCw + co 0 CD O-4 O Cn N� N N z Z m ? A C- m 01010lcn.101 1C." Io ICAlcnlcrlcnl-0 wmmz-a-Izoo X I X IX 'IX IX iX IX IX fX IX IX IX IAPPENDIX I - VOC BY8260 X IX IX i>C IX IX ]X f>C IX IX IX IX (APPENDIX I- METALS r 0 a ' Z In m N v m 0 X O m o c W r N m S 0 � N 0 n V -4m> w03 < o0 o0 b nQ xp to o��0 �m m m �n CD GO V 1 CO C3i 1.A, j w N" If. X m W 3 C Z o- m Dy r r i i COED O <0n 1 N �mv z W) 0 mr z�> o ; V �rDOry-fA n �+wcnAma j m O Eck coo �Z ZZS 2 so z ' ci . P ge 6 �f 92 0 In o �c c F. m°Q9J�JVJJJJ oa— a h Mh H %J � m m -q C 9 C rr O D N N r N r { n7 r N r m :« N •L C 40 00 O G 4 = � r ���� CC CC CC CC CC CC CC ox0cs 4 "� Z X x x X X w > m 0. O m ,r m p 0 0 0 0 0 0 (�j) ra m o �wwwwwwwm — a m r �r c .D i I I r Cl) a oopcp������� Z L z ro 0 y m Ni 10 IL" ic" ICA 10 lo 10 Im lcn 1 4 0mmz—a-1z0a z a �� oov000000 ���000000000 N..a ..4 O co o� �I �— ;r m m 2- c z .o — Im as v v M,;,o 0, z az x *9 �a Ma O F'ar'> O rdl r r r T '0ry�0)o 005r-Cp �v Gm � m n m a Z m C N 0 v m 0 O m M V v c N m S 0 N 0 n Off$ -4 m c7 xm M Zj. N O C C7 O1 >�3 y�$ J Y w C$ 0 5rO z N a r � n S N A, I N V W (A A f0 IV � �Zlzxxx O Op o m A � P ge6 1192 A s DC# Title: ENV-FRM-HUN1-0083 01 Sample Condition Upon Receipt Effective Date: 05112/2022 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlantaff--Kernersville❑ Sample• • • Client Name: Upon Recel-pt WO# : 92fi 1 fi984 904, Seto AM/ u r} Project M.Courier: x 1 J� ❑DPS ��Cs❑LISPS ❑Client PM- MP Due Dale: 08/05/22 ❑Commercial ❑Pace ❑Other:_ _ CLIENT: GAReoNC Custody Seal Present? ❑Yes E3 o Seals Intact? 7/00 Packing Material: Bubble Wrap ubble Bags ❑Yes ❑No ❑None ❑ Other Thermometer: ❑ un ID: Type of Ice: et Correction Factor: 00 Cooler Temp:F Add/Subtract (*Q Cooler Temp Corrected (`C): USDA Regulated Soil (❑ N/A, water sample Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check mans)? MYes 17INn Date/Initials Person Examining Contents: 1� Biological Tissue Frozen? �v i []Yes ❑No ❑N/A []Blue []None Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (international y, Comments/Discrepancy: Chain of Custody Present? Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? es ❑N-, ❑N?A 2. Short Hold Time Analysis (<72 hr.)? ❑Yr_: i9N'C"' [IN -'A 3. Rush Turn Around Time Requested? ❑Vc,21rc ❑NiA 4. Sufficient Volume? 4R�e`s ❑Na ❑N/A 5. Correct Containers Used? -Pace Containers Used? Yes Y ❑No ❑No ❑N/A ❑N/A 6. Containers Intact? es ❑No ❑N/A 7 Dissolved analysis: Samples Field Filtered? [:]Yes, ❑No [JITrA 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: es 6—tw [:]No ❑N/A 9. Headspace in VOA Vials (>5-6mm)? []Yes [31 o ❑NiA 10. Trip Blank Present? Trip Blank Custody Seals Present? 017es 2<1 ❑No ❑NO ❑N,A ❑NiA 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: Field Data Required? ❑Yes ❑No Page 69 of 92 Qualtrax 1D: 69614 Page 1 of 2 DC#_Title: ENV-FRM-HUN1-0083 v01 Sample Condition Upon Receipt ace Effective Date: 05/12/2022 *Check mark top half of box if pH and/or dechlorination is verified and Project # within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine W04-:926169$ 22 Pli : IV CLI91Y: MR.pNC A Y Z a�i d C 7 V N a J Ln N e�l 7 a a m 2 a d C V N a J N N N1 n. in Z a C � V N a J g In > N 6 m Q 2 v d Q C !a d =' rl > W a m V N v 0 2 V i-• a J E „Ny d m v Z 2 V N lO a J 0 O N Z MI 0. m Q Z °� V Q N H A 'a J Ln E ,Nj 1y� Q a m V N n Q 2 0 Z u 0. J n N m v d Cl V Q N l7 M �+ C C G v ur u Z v W N d C N d E Q « rl .w V' Q _ V Q V Q7 E Q « rl 2 W 47 Q 2 '-' y y C 7 W A E Q J Ln N rn �7 Q v a N = v E Q ;, e-1 Yf W C7 a iN v g O N 2 y Q J E N VI T V a ¢ V V i Z N E Q J E N l7 4 Q Z _ V = Q 0 > E R X X. l7 O1j'' Z H1 0 N N Z Q 0 'I E R O1 �7 > z d d v. 0Y Q. C Q 0 > E q O1 [7 S ` ? 0.0 rn 2 Q > E: Q C1 C7 Q z '7 N i Q O E Q Of l7 M _ d 5 Y, i C' (�. > e Z V :+ A d N N rNl N d N L Z V :+ A 1 N N a N N d N T N N = Z V a+ M d o N on a m u N C. c 2 N Q J g e-1 O C7 Q N c O C V V1 o N l4 ul 7 y 01 i O. C N E Q 0 C a+ t7 O � f ! 2 `y. 1�I 3 4 5 6 7 X\\ 8 9 10 li 12 NN I pH Adjustment Log for Preserved Samples Sample ID Type of preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect conta'ners. Page 70 of 92 Qualtrax ID: 69614 Page 2 of 2 *Check mark top half of box if pH and/or dechlorination is verified and project # within the acceptance range for preservation samples. Exceptions: VOA, Col !form, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Ace, DC# Title: ENV-FRM-HUN1-0083 v01 Sample Condition Upon Receipt ��MNIM Effective Date: 05/12J2022 WOC 92616984 PP: nP Due Dale: 08/05/22 CLIENT- GAROIaNC A 2 « L m Q C a J E rNl Q a d a C a J E o ref o IS a a C a J E g N 0. m 4 ? 4 it L Q. c m 0. m •= N a m N V O N = `a J E ,n Q d m N V V O Z Z n r E o N rn d m T Z A Q Z ii J E uti Q 6 m V �..� A .M Q ra Z a J £ Q o m N N C M -a C E ° V `-• = Z V z d d C E ¢ m = t7 q V G V E ¢ a� N t7 q Z a m N N 4 ¢ J E o N M c7 q N v S Q. H N E ¢ :: rl N [7 q N a O N T ¢ J £ c N M l7 a -- V Q z i Z ¢ J E o N OQi t7 o Z _ 7 E M L7 0 z O N VI 0 > E V Q�1 C7 7 < Z -a d w N O '! E g CM t7 A Q ? 0 O 7 £ Q Cy1 t7 o ? Q O O , E 0�1 l7 o '= a 7 m �. _N '° w U' :: N E N d w � N E N N M- h r O M o T Z f0 d E N M m Q Y a a C ¢ J E pp �•�1 ca a C O V) J E N 7 Z N v a E ¢ , E OI C i \IV 2 � 3 4 5 6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEN Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect conta"ners. Page 71 of 92 Qualtrax 1D: 69614 Page 2 of 2 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA POINT ID: FIELD BLANK FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION INITIAC'�R LEVEL (FT) ELEV., MEAS. PT. (MSL):---- DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER S.S. BAILER GRUNDFOS PUMP YES NO S.S. BAILER QED PUMP OTHER WELL RISER DIAMETER (IN.): 2 3 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNES TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (Fl TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA ( )NO Wmw"L-(Sw pH its) mill maNOR SAMPLING INFORMATION DATE/TIME r7-25--?Z METHOD OF SAMPLING: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: GRUNDFOS PUMP YES OTHER NO TIME pH (Std.Units) TEMP. (C) CONDUCT. umhos/cm) TURBIDITY (N 'U) OTHER eh (mV) ] DISS. OXY. (PPM) OTHER NA NA NA NA NA NA — NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: k bV, SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER- I Page 72 of 92 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA POINT ID: TRIP BLANK FIELD REPRESENTATIVE: ES&S-B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE/ PROJECT#: EVACJJATION INFORMATION INITIAL WjV VEL (FT) ELEV., MEAS. PT. (MSL): IST-11,110 METHOD OF EVACUATION: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA GRUNDFOS OTHER 3 ( ) 4 NA DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) 6 ( ) OTHEI"�'_� WAS WELL PURGED TO DRYI` WATER LEVEL END PURGE FINISH )YES( )NO Iwo pH (Std.UnitsLismi TURBIDITY NTU) im ��= Cam- � SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: GRUNDFOS PUMP YES OTHER NO TIME pH (Std. U n its) TEMP. (C) CONDUCT. (umhos/cm) TURBIDITY _(NTU) OTHER eh (mV) DISS. OXY. (PPM) OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C LEARL COMMENTS: VOA ONLY SAMPLE COLLECTION NUMBER Page 73 of 92 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA ELEVATION, MEAS.PT.(MSL): F_ NA METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP POINT ID: Sw - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT M NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS YES ( ) NO PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) ( ) NO TIME PUR � m/htz CUMULATIVE VOLU TEMP. C pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME / METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) WATERRA PUMP (X) YES (X) DIP BOTTLE ( ) NO TIME pH Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1.9 790 is'.is's 3.94NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C i J COMMENTS: SAMPLE COLLECTION NUMBER 3 Page 74 of 92 SITE NAME: FOOTHILLS LF POINT ID: UD-2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER EVACUATION INFORMATION INITIAL WA L FEET) NA PT.(MSL)���_ To� ELEVATION, MEAS.PT.(MSL): DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS YES ( ) NO PUMPING WELL 'LL 4 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) CM%UbAXUF— VOLUME TEMP. pH Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (mV) I NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME LILI WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 0 ;1,I 1. l 4- e 0o. q 3.72 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: c— C 0 (.l SAMPLE CHARACTERISTICS: COMMENTS: Page 75 of 92 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER INITIAL R LEVEL (FEET) NA ELEVATION, MEAS.PT. S); NA DATE METHOD OF EVACUATION: ``�•• ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTIN 3.1� ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) OTHER WAS WELL PURGED TO D SS WATER LEVEL AFTER PURGE (FT.) FINISH ( ) YES ( ) NO TIME PURGER m/htz f-'Up(IUL�AT�IVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) WATERRA PUMP (X) YES (X) DIP BOTTLE ( ) NO TIME pH Std.Units) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 15; D �C 1 o +60,7 3.90 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: C- �i SAMPLE CHARACTERISTICS: C ®` l -T.-, COMMENTS: Page 76 of 92 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: SW-2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA-I`EEET) NA ELEVATION, MEAS.PT.(MSL): NA___ DATE ~~~' METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( ) NO TIME PURGE RA m/htz I.lLATIVE VOLUME--.` TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME -Z z/ 1 -5: 5 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 90 I. SAMPLE CHARACTERISTICS: A.r-I 0"rioit COMMENTS: SAMPLE COLLECTION NUMBER Page 77 of 92 SITE NAME: FOOTHILLS LF POINT ID: SW-5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL VVA$ LEVEL (FEET) NA ELEVATION, MEAS.PT.(M NA _ DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE ! PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINU ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRY S WATER LEVEL AFTER PURGE (FT.) FINISH ( ) YES ( ) NO TIME PUR m/htz UMULATIVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 ---. NA NA NA SAMPLING INFORMATION DATE/TIME 15 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER GENERAL INFORMATION ^ 0r WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: COMMENTS: Page 78 of 92 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: SW-4 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAL Wgrnk-!=-EL (FEET) NA ELEVATION, MEAS,Plr;;L DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) -MMbl-AT4VF— VOLUME TEMP. pH d.Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh NA 0 _(mV) I NA NA NA SAMPLING INFORMATION DATE / TIME r7-Zy-?-'L- / WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 10-7 I, 11,10 5-•0 NA GENERAL INFORMATION e-% '2 0' WEATHER CONDITIONS AT TIME OF SAMPLING: c (.-jo " b SAMPLE CHARACTERISTICS: C COMMENTS: Page 79 of 92 SAMPLE COLLECTION NUMBER 9 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION NA N::A:: N ER LEV EL (FEET) INITIA ER LEVEL (FEET) NA ELEVATION, MEAS. (A DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA ) CONTTt PUMPING ( ) 4 ( ) 6 POINT ID: SW - 3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT#: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: DUS YES NO ( ) OTHER WAS WELL PURGED TO NESS( )YES( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpm/htz) -C VE VOLUME TEMP. C pH Std.Units), SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh NA 0 _(mV) NA NA NA SAMPLING INFORMATION DATE / TIME r7-25-.2-Z/ W3k WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) ]+.?,2, REDOX eh (mV) DISS. OXY. (PPM) OTHER W40 (" go 57 r? P. 's 1, .7 5-15- 5-.03 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: b SAMPLE CHARACTERISTICS: f COMMENTS: Page 80 of 92 SAMPLE COLLECTION NUMBER 9 SITE NAME FOOTHILLS LF POINT ID: 11 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION 83,o9 INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSQ: I LP 1 "T DATE 7 - a (0 ® 2-'- FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): 10 ELEVATION, G/W (MSQ: TIME: START/FINISH 6. 0 a / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 4 6 OTHER ONE -(1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) 0 u WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START C LEAZ- FINISH df C LE4f- EVACUATION STABILIZATION DATA lbim pH Std.Units) 1 ® i1 }F '� � �*!': ,III ®® it 4 1 i ®® � : ., .,, , .' ;♦ t. , ,. ... � <�I SAMPLING INFORMATION DATE / TIME ?-?-& DEPTH TO GROUNDWATER (FT) ff?, c?-? METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP OTHER NO GENERAL INFORMATION . F WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c k64 COMMENTS: APPENDIX I LIST Page 81 of 92 SAMPLE COLLECTION NUMBER I I) SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSL): 1358-.53 DATE "? ® ?-- 2 2- POINT ID: mW-10 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: mm DEPTH TO BOTTOM (FT): ELEVATION, G/W (MSQ: sloml TIME: START/FINISH �a I ?12q METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 3 ONE (1) RISER VOLUME(GAL) l,(v3 TOTAL VOL. EVACUATED (GAL) Q.00 TURBIDITY OF PURGINGS 9 k �Tlfl EVACUATION STABILIZATION DATA ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) FINISH Illm a pH (Std.Units) i ": ..,; , � �, � #�. ® ' .. �; � r '�.,: � .- ems:, ...,�. `", ,.,: �® SAMPLING INFORMATION "7 '79-n DATE / TIME DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: Su � ri SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I I Page 82 of 92 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION r� INITIAL WATER LEVEL (FT): 1 POINT ID: MW — 9 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): . YO ELEV., MEAS. PT. (MSL): I 0 . ELEVATION, G/W (MSL): c1 DATE -- Z. TIME: START/FINISH / • / METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) 0.54 TOTAL VOL. EVACUATED (GAL) s00 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) o, / TURBIDITY OF PURGINGS: START C, FINISH EVACUATION STABILIZATION DATA WWI= PH ' . �i ,.- a ,� 1 � � „t: ^. .�. ,�,.. /;_ �' �■®� M � ♦` ... , '!. �: ✓> ,�, .�.. fir, . , SAMPLING INFORMATION DATE/TIME DEPTH TO GROUNDWATER (FT) to• / METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: t',N S SAMPLE CHARACTERISTICS: c— COMMENTS: APPENDIX 1 LIST Page 83 of 92 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 8 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION �.- INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT): t ELEV., MEAS. PT. (MSL): 1 ELEVATION, G/W (MSL): 0 r/ DATE m TIME: START/FINISH - / r METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: (X)2 ( )3 ( )4 ( )6 ( )OTHER . let WAS WELL PURGED TO DRYNESS ( ) YES (X) NO 00 WATER LEVEL END PURGE (FT) -2. 7 START EVACUATION STABILIZATION DATA FINISH C, ` E � SAMPLING INFORMATION DATE/TIME d 2(" 2 Z / l DEPTH TO GROUNDWATER (FT) , '2 z METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0 WEATHER CONDITIONS AT TIME OF SAMPLING: 1.4 Pimy, SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 13 Page 84 of 92 SITE NAME FOOTHILLS LF POINT ID: MW - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): - ELEV., MEAS. PT. (MSL): DATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA ELEVATION, G/W (MSL): I TIME: START/FINISH : / -'S 7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) I. WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) • 0® WATER LEVEL END PURGE (FT) O TURBIDITY OF PURGINGS: START c FINISH CLFAR- EVACUATION STABILIZATION DATA • pH • 1 SAMPLING INFORMATION DATE/TIME r7 -2-.. / ' DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION ci' WEATHER CONDITIONS AT TIME OF SAMPLING: o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1 Page 85 of 92 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): r DATE 0 2- - 2- FIELD REPRESENTATIVE: LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): MW-6 E S & S - B.CHIODO NA S- 0.55 ELEVATION, G/W (MSL): TIME: START/FINISH 101.114 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.20 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . ® Q WATER LEVEL END PURGE (FT) , J TURBIDITY OF PURGINGS: START e, FINISH EVACUATION STABILIZATION DATA PURGE RATE • pH �'' 1� , ®® �� III tom. { ', ! ", c✓+ �v�,` � ,:. t`! `:. SAMPLING INFORMATION DATE/TIME -2"2 T- / DEPTH TO GROUNDWATER (FT) q3. METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c L54z- COMMENTS: APPENDIX I LIST Page 86 of 92 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 1 r75. 07 * DATE `tl-'' Z POINT ID: Mw - 5 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 22 DEPTH TO BOTTOM (FT): 0 ELEVATION, G/W (MSL): 1 . 41 TIME: START/FINISH 1 I; 0 1 / 1 /4' METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: (X)2 ( )3 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) 4/7 *7/ START FINISH C EVACUATION STABILIZATION DATA PURGE RATE • • • SAMPLING INFORMATION DATE / TIME °' 6 - Zz'- / 11 ' 33 DEPTH TO GROUNDWATER (FT) . 7/ METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 1") ' ,� f. WEATHER CONDITIONS AT TIME OF SAMPLING: ^Itea P .� SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I Page 87 of 92 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): DATE ® 2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): gg ELEVATION, G/W (MSL): t qg TIME: START/FINISH H, - 9 / 0 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) , TURBIDITY OF PURGINGS: START FINISH C, (X) 2 ( ) 3 1-(03 00 EVACUATION STABILIZATION DATA pH SAMPLING INFORMATION DATE / TIME - 2-6 - Z DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: ss SAMPLE CHARACTERISTICS: c- COMMENTS: APPENDIX I LIST tA S / m s SAMPLE COLLECTION NUMBER 17 4- 18 Page 88 of 92 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): s DATE t®-II,,® -. POINT ID: MW - 3R2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: im DEPTH TO BOTTOM (FT): , ! ELEVATION, G/W (MSL): 100. _.._....... TIME: START/FINISH 12.39 / 13%10 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 5,134 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) Q, 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START O FINISH C LW EVACUATION STABILIZATION DATA 01 PURGE RATE (ML /'MIN) TOM pH (S-td.Units) MINE 1 r MW SAMPLING INFORMATION DATE /TIME "' / DEPTH TO GROUNDWATER (FT) 0. METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION ,. 0t' WEATHER CONDITIONS AT TIME OF SAMPLING: C4 , � SAMPLE CHARACTERISTICS: C Lr--A COMMENTS: APPENDIX I LIST ~ Page 89 of 92 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION g INITIAL WATER LEVEL (FT): 1 ELEV., MEAS. PT. (MSL): r! DATE ® 2(' - POINT ID: MW - I R2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA ELEVATION, G/W (MSL): 1 419.97 TIME: START/FINISH 1 : 3 to/ I METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) 2.00 WATER LEVEL END PURGE (FT) 16• 36 TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RATE (ML MIN)• 3Y VW 1 SAMPLING INFORMATION DATE / TIME 2' ® �- i DEPTH TO GROUNDWATER (FT) j METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: a.fr�/�+✓ �~ SAMPLE CHARACTERISTICS: C- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 070Page 90 of 92 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE -A INITIAL W TER+EV-F-L (FEET) NA ELEVATION, MEAS.PT;Z DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GAN (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: CONTINUOUS NO PUMPING WELL 4 6 ( ) OTHER WAS WELL PURGED TO DRYNESS �( ) ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpmlhtz) CUMUL-ATrVE- VOLUME EMP. (C) pH "-----4SLd. Units SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh mV) NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME 1q:qo METHOD OF SAMPLING: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA WATERRA PUMP (X) SAMPLE PORT SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) No TIME pH (Std. U n its) SPEC. CONDUCT. (umhos/cm) TEMP. —(C) 1 TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 111;liz ?, 00 ly 1&95'0 3;?- 5 — 5-9-..3 0 NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 5CA" IV SAMPLE CHARACTERISTICS: -774zA i b - COMMENTS: Page 91 of 92 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): DATE P (p 2 z- FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA • ELEVATION, G/W (MSL): O TIME: START/FINISH % . 5 2 / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUNIP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) g,03 TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) 51, START FINISH EVACUATION STABILIZATION DATA '?, 50 PURGE m SAMPLING INFORMATION DATE / TIME - "'� / -F- J DEPTH TO GROUNDWATER (FT) 1, I METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0 cdc WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: CLEAt COMMENTS: APPENDIX I LIST NAF SAMPLE COLLECTION NUMBER + Page 92 of 92 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 05, 2022 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Leachate Pace Project No.: 92616971 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on July 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, "Ai� 5 Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92616971 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92616971 Lab ID Sample ID SAMPLE SUMMARY Matrix Date Collected Date Received 92616971001 1403-Leachate Water 07/26/2214:40 07/27/2210:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Foothills LF/Leachate Pace Project No.: 92616971 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92616971001 1403-Leachate EPA6020B CW1 15 PASI-GA SM 5210B-2016 TBM 1 PASI-GA EPA 8260D SAS 50 PASI-C EPA 300.0 Rev 2.1 1993 CDC 3 PASI-A EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A SM 5220D-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92616971 Lab Sample ID Method 92616971001 EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B EPA 6020B SM 521OB-2016 EPA 8260D EPA 8260D EPA 8260D EPA 8260D EPA 8260D EPA 8260D EPA 8260D EPA 365.1 Rev 2.0 1993 SM 5220D-2011 Client Sample ID Parameters 1403-Leachate Performed by pH Temperature Specific Conductance Turbidity Antimony Arsenic Barium Chromium Cobalt Nickel Vanadium BOD, 5 day Acetone Benzene 2-Butanone (MEK) Ethylbenzene Toluene Trichloroethene Xylene (Total) Phosphorus Chemical Oxygen Demand SUMMARY OF DETECTION Result Units ES&S 7.84 Std. Units 32.5 deg C 16,850 umhos/cm 58.30 NTU 138J ug/L 1901 ug/L 521 J ug/L 396 ug/L 35.5J ug/L 202J ug/L 82.2J ug/L 540000 ug/L 1470 ug/L 3.8J ug/L 640 ug/L 13.4 ug/L 9.0 ug/L 4.7J ug/L 22.8J ug/L 7390 ug/L 4550000 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Report Limit Analyzed 07/26/22 14:40 07/26/22 14:40 07/26/22 14:40 07/26/22 14:40 07/26/22 14:40 150 08/01/2214:21 D3 250 08/01/2214:21 D3 2500 08/01/2214:21 D3 250 08/01/2214:21 250 08/01/2214:21 D3 1250 08/01/2214:21 D3 625 08/01/2214:21 D3 2000 08/01 /22 18:05 500 07/30/2218:54 5.0 07/30/2218:54 500 07/30/2218:54 5.0 07/30/2218:54 5.0 07/30/2218:54 5.0 07/30/2218:54 25.0 07/30/2218:54 250 08/02/22 20:31 250000 08/04/22 06:17 Qualifiers Page 5 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92616971 Sample: 1403-Leachate Lab ID: 92616971001 Collected: 07/26/22 14:40 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 07/26/22 14:40 pH 7.84 Std. Units 1 07/26/22 14:40 Temperature 32.5 deg C 1 07/26/22 14:40 Specific Conductance 16,850 umhos/c 1 07/26/22 14:40 m Turbidity 58.30 NTU 1 07/26/22 14:40 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 138J ug/L 150 19.5 5 07/29/2213:14 08/01/2214:21 7440-36-0 Arsenic 190J ug/L 250 54.0 5 07/29/2213:14 08/01/2214:21 7440-38-2 Barium 521J ug/L 2500 16.8 5 07/29/2213:14 08/01/2214:21 7440-39-3 Beryllium ND ug/L 25.0 1.3 5 07/29/2213:14 08/01/2214:21 7440-41-7 Cadmium ND ug/L 25.0 2.8 5 07/29/2213:14 08/01/2214:21 7440-43-9 Chromium 396 ug/L 250 27.4 5 07/29/2213:14 08/01/2214:21 7440-47-3 Cobalt 35.5J ug/L 250 9.9 5 07/29/2213:14 08/01/2214:21 7440-48-4 Copper ND ug/L 250 25.1 5 07/29/2213:14 08/01/2214:21 7440-50-8 Lead ND ug/L 250 22.2 5 07/29/2213:14 08/01/2214:21 7439-92-1 Nickel 202J ug/L 1250 17.7 5 07/29/2213:14 08/01/2214:21 7440-02-0 Selenium ND ug/L 250 34.2 5 07/29/2213:14 08/01/2214:21 7782-49-2 Silver ND ug/L 250 10.9 5 07/29/2213:14 08/01/2214:21 7440-22-4 Thallium ND ug/L 138 4.5 5 07/29/2213:14 08/01/2214:21 7440-28-0 Vanadium 82.2J ug/L 625 46.5 5 07/29/2213:14 08/01/2214:21 7440-62-2 Zinc ND ug/L 250 174 5 07/29/2213:14 08/01/2214:21 7440-66-6 5210B BOD, 5 day Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Peachtree Corners, GA BOD, 5 day 540000 ug/L 2000 2000 1 07/27/22 15:05 08/01/22 18:05 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 1470 ug/L 500 25.6 5 07/30/22 18:54 67-64-1 Acrylonitrile ND ug/L 1000 9.2 5 07/30/22 18:54 107-13-1 Benzene 3.8J ug/L 5.0 1.7 5 07/30/22 18:54 71-43-2 Bromochloromethane ND ug/L 15.0 2.3 5 07/30/22 18:54 74-97-5 Bromodichloromethane ND ug/L 5.0 1.5 5 07/30/22 18:54 75-27-4 Bromoform ND ug/L 15.0 1.7 5 07/30/22 18:54 75-25-2 Bromomethane ND ug/L 50.0 8.3 5 07/30/22 18:54 74-83-9 2-Butanone (MEK) 640 ug/L 500 19.8 5 07/30/22 18:54 78-93-3 Carbon disulfide ND ug/L 500 1.8 5 07/30/22 18:54 75-15-0 Carbon tetrachloride ND ug/L 5.0 1.7 5 07/30/22 18:54 56-23-5 Chlorobenzene ND ug/L 15.0 1.4 5 07/30/22 18:54 108-90-7 Chloroethane ND ug/L 50.0 3.2 5 07/30/22 18:54 75-00-3 Chloroform ND ug/L 25.0 2.2 5 07/30/22 18:54 67-66-3 Chloromethane ND ug/L 5.0 2.7 5 07/30/22 18:54 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. D3 D3 D3 D3, P4 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 IK IK,v2 Page 6 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92616971 Sample: 1403-Leachate Lab ID: 92616971001 Collected: 07/26/22 14:40 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 300.0 IC anions 48hr Nitrate as N Nitrite as N Sulfate Date: 08/05/2022 03:11 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 65.0 1.7 5 07/30/2218:54 96-12-8 ND ug/L 15.0 1.8 5 07/30/2218:54 124-48-1 ND ug/L 10.0 1.4 5 07/30/2218:54 106-93-4 ND ug/L 50.0 2.0 5 07/30/2218:54 74-95-3 ND ug/L 25.0 1.7 5 07/30/2218:54 95-50-1 ND ug/L 5.0 1.7 5 07/30/2218:54 106-46-7 ND ug/L 500 2.8 5 07/30/2218:54 110-57-6 ND ug/L 25.0 1.8 5 07/30/2218:54 75-34-3 ND ug/L 5.0 1.6 5 07/30/2218:54 107-06-2 ND ug/L 25.0 1.7 5 07/30/2218:54 75-35-4 ND ug/L 25.0 1.9 5 07/30/2218:54 156-59-2 ND ug/L 25.0 2.0 5 07/30/2218:54 156-60-5 ND ug/L 5.0 1.8 5 07/30/2218:54 78-87-5 ND ug/L 5.0 1.8 5 07/30/2218:54 10061-01-5 ND ug/L 5.0 1.8 5 07/30/2218:54 10061-02-6 13.4 ug/L 5.0 1.5 5 07/30/2218:54 100-41-4 ND ug/L 250 2.4 5 07/30/2218:54 591-78-6 ND ug/L 100 48.6 5 07/30/2218:54 74-88-4 ND ug/L 25.0 9.8 5 07/30/2218:54 75-09-2 ND ug/L 500 13.6 5 07/30/2218:54 108-10-1 ND ug/L 5.0 1.5 5 07/30/2218:54 100-42-5 ND ug/L 25.0 1.6 5 07/30/2218:54 630-20-6 ND ug/L 15.0 1.1 5 07/30/2218:54 79-34-5 ND ug/L 5.0 1.5 5 07/30/2218:54 127-18-4 9.0 ug/L 5.0 2.4 5 07/30/2218:54 108-88-3 ND ug/L 5.0 1.7 5 07/30/2218:54 71-55-6 ND ug/L 5.0 1.6 5 07/30/2218:54 79-00-5 4.7J ug/L 5.0 1.9 5 07/30/2218:54 79-01-6 ND ug/L 5.0 1.5 5 07/30/2218:54 75-69-4 ND ug/L 5.0 1.3 5 07/30/2218:54 96-18-4 ND ug/L 250 6.6 5 07/30/2218:54 108-05-4 ND ug/L 5.0 1.9 5 07/30/2218:54 75-01-4 22.8J ug/L 25.0 1.7 5 07/30/2218:54 1330-20-7 99 % 70-130 5 07/30/2218:54 460-00-4 97 % 70-130 5 07/30/2218:54 17060-07-0 98 % 70-130 5 07/30/2218:54 2037-26-5 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville ND ug/L 2000 1200 20 ND ug/L 2000 1000 20 ND ug/L 20000 10000 20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK CO 07/27/22 23:22 14797-55-8 D3,M1 07/27/22 23:22 14797-65-0 D3,M1 07/27/22 23:22 14808-79-8 D3,M1 Page 7 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92616971 Sample: 1403-Leachate Lab ID: 92616971001 Collected: 07/26/22 14:40 Received: 07/27/22 10:22 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 7390 ug/L 250 125 5 08/02/22 16:44 08/02/22 20:31 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen 4550000 ug/L 250000 125000 1 08/04/22 02:33 08/04/22 06:17 Demand REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 QC Batch: 713723 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92616971001 METHOD BLANK: 3721162 Associated Lab Samples: 92616971001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 0.78 08/01/2214:09 Arsenic ug/L ND 10.0 2.2 08/01/2214:09 Barium ug/L ND 100 0.67 08/01/2214:09 Beryllium ug/L ND 1.0 0.054 08/01/2214:09 Cadmium ug/L ND 1.0 0.11 08/01/2214:09 Chromium ug/L ND 10.0 1.1 08/01/2214:09 Cobalt ug/L ND 10.0 0.39 08/01/2214:09 Copper ug/L ND 10.0 1.0 08/01/2214:09 Lead ug/L ND 10.0 0.89 08/01/2214:09 Nickel ug/L ND 50.0 0.71 08/01/2214:09 Selenium ug/L ND 10.0 1.4 08/01/2214:09 Silver ug/L ND 10.0 0.44 08/01/2214:09 Thallium ug/L ND 5.5 0.18 08/01/2214:09 Vanadium ug/L ND 25.0 1.9 08/01/2214:09 Zinc ug/L ND 10.0 7.0 08/01/2214:09 LABORATORY CONTROL SAMPLE: Parameter 3721163 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 105 105 80-120 Arsenic ug/L 100 99.8 100 80-120 Barium ug/L 100 96.3J 96 80-120 Beryllium ug/L 100 100 100 80-120 Cadmium ug/L 100 102 102 80-120 Chromium ug/L 100 104 104 80-120 Cobalt ug/L 100 98.6 99 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 99.0 99 80-120 Nickel ug/L 100 100 100 80-120 Selenium ug/L 100 99.8 100 80-120 Silver ug/L 100 98.7 99 80-120 Thallium ug/L 100 99.0 99 80-120 Vanadium ug/L 100 105 105 80-120 Zinc ug/L 100 108 108 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Leachate 92616971 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3721164 3721165 MS MSD 92617242005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 106 105 106 105 75-125 1 20 Arsenic ug/L ND 100 100 101 101 101 101 75-125 0 20 Barium ug/L 150 100 100 241 243 91 93 75-125 1 20 Beryllium ug/L ND 100 100 95.9 95.8 96 96 75-125 0 20 Cadmium ug/L ND 100 100 101 100 101 100 75-125 0 20 Chromium ug/L ND 100 100 102 103 101 103 75-125 1 20 Cobalt ug/L ND 100 100 95.2 97.2 95 97 75-125 2 20 Copper ug/L 1.7J 100 100 97.5 97.4 96 96 75-125 0 20 Lead ug/L ND 100 100 96.5 96.3 96 96 75-125 0 20 Nickel ug/L ND 100 100 97.6 98.0 98 98 75-125 0 20 Selenium ug/L ND 100 100 99.9 98.6 100 99 75-125 1 20 Silver ug/L ND 100 100 95.9 94.7 96 95 75-125 1 20 Thallium ug/L ND 100 100 97.1 95.9 97 96 75-125 1 20 Vanadium ug/L ND 100 100 104 102 104 102 75-125 2 20 Zinc ug/L ND 100 100 106 106 104 104 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 QC Batch: 713177 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92616971001 METHOD BLANK: 3718410 Matrix: Water Associated Lab Samples: 92616971001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 08/01/22 17:12 B3 LABORATORY CONTROL SAMPLE: 3718411 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD,5 day ug/L 198000 227000 115 84.6-115 SAMPLE DUPLICATE: 3718413 92616919001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1300 mg/L 1280000 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 QC Batch: 713994 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92616971001 METHOD BLANK: 3722513 Associated Lab Samples: 92616971001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 07/30/22 09:09 1,1,1-Trichloroethane ug/L ND 1.0 0.33 07/30/22 09:09 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 07/30/22 09:09 1,1,2-Trichloroethane ug/L ND 1.0 0.32 07/30/22 09:09 1,1-Dichloroethane ug/L ND 5.0 0.37 07/30/22 09:09 1,1-Dichloroethene ug/L ND 5.0 0.35 07/30/22 09:09 1,2,3-Trichloropropane ug/L ND 1.0 0.26 07/30/22 09:09 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 07/30/22 09:09 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 07/30/22 09:09 1,2-Dichlorobenzene ug/L ND 5.0 0.34 07/30/22 09:09 1,2-Dichloroethane ug/L ND 1.0 0.32 07/30/22 09:09 1,2-Dichloropropane ug/L ND 1.0 0.36 07/30/22 09:09 1,4-Dichlorobenzene ug/L ND 1.0 0.33 07/30/22 09:09 2-Butanone (MEK) ug/L ND 100 4.0 07/30/22 09:09 2-Hexanone ug/L ND 50.0 0.48 07/30/22 09:09 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 07/30/22 09:09 Acetone ug/L ND 100 5.1 07/30/22 09:09 Acrylonitrile ug/L ND 200 1.8 07/30/22 09:09 Benzene ug/L ND 1.0 0.34 07/30/22 09:09 Bromochloromethane ug/L ND 3.0 0.47 07/30/22 09:09 Bromodichloromethane ug/L ND 1.0 0.31 07/30/22 09:09 Bromoform ug/L ND 3.0 0.34 07/30/22 09:09 Bromomethane ug/L ND 10.0 1.7 07/30/22 09:09 Carbon disulfide ug/L ND 100 0.36 07/30/22 09:09 Carbon tetrachloride ug/L ND 1.0 0.33 07/30/22 09:09 Chlorobenzene ug/L ND 3.0 0.28 07/30/22 09:09 Chloroethane ug/L ND 10.0 0.65 07/30/22 09:09 Chloroform ug/L 0.49J 5.0 0.43 07/30/22 09:09 Chloromethane ug/L ND 1.0 0.54 07/30/22 09:09 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 07/30/22 09:09 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 07/30/22 09:09 Dibromochloromethane ug/L ND 3.0 0.36 07/30/22 09:09 Dibromomethane ug/L ND 10.0 0.39 07/30/22 09:09 Ethylbenzene ug/L ND 1.0 0.30 07/30/22 09:09 lodomethane ug/L ND 20.0 9.7 07/30/22 09:09 Methylene Chloride ug/L ND 5.0 2.0 07/30/22 09:09 Styrene ug/L ND 1.0 0.29 07/30/22 09:09 Tetrachloroethene ug/L ND 1.0 0.29 07/30/22 09:09 Toluene ug/L ND 1.0 0.48 07/30/22 09:09 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 07/30/22 09:09 Qualifiers IK I:/ IK I K,v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92616971 METHOD BLANK: 3722513 Associated Lab Samples: 92616971001 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 3722514 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 100 ND 1.0 ND 1.0 ND 50.0 ND 1.0 ND 5.0 104 70-130 99 70-130 101 70-130 MDL Analyzed 0.36 07/30/22 09:09 0.56 07/30/22 09:09 0.38 07/30/22 09:09 0.30 07/30/22 09:09 1.3 07/30/22 09:09 0.39 07/30/22 09:09 0.34 07/30/22 09:09 07/30/22 09:09 07/30/22 09:09 07/30/22 09:09 IK Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.9 98 70-130 1,1,1-Trichloroethane ug/L 50 47.3 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 45.6 91 70-130 1,1,2-Trichloroethane ug/L 50 47.2 94 70-130 1,1-Dichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethene ug/L 50 51.3 103 70-132 1,2,3-Trichloropropane ug/L 50 39.6 79 70-130lK 1,2-Dibromo-3-chloropropane ug/L 50 47.1 94 70-132 1,2-Dibromoethane (EDB) ug/L 50 49.3 99 70-130 1,2-Dichlorobenzene ug/L 50 44.8 90 70-130 1,2-Dichloroethane ug/L 50 45.1 90 70-130 1,2-Dichloropropane ug/L 50 47.3 95 70-130 1,4-Dichlorobenzene ug/L 50 43.3 87 70-130 2-Butanone (MEK) ug/L 100 88.2J 88 70-133 2-Hexanone ug/L 100 99.3 99 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 101 101 70-130 Acetone ug/L 100 97.3J 97 70-144 Acrylonitrile ug/L 250 232 93 70-130 Benzene ug/L 50 42.5 85 70-130 Bromochloromethane ug/L 50 55.9 112 70-130lK Bromodichloromethane ug/L 50 48.0 96 70-130 Bromoform ug/L 50 50.4 101 70-131 Bromomethane ug/L 50 40.3 81 30-177lK Carbon disulfide ug/L 50 50.11 100 70-133 Carbon tetrachloride ug/L 50 47.8 96 70-130 Chlorobenzene ug/L 50 47.2 94 70-130 Chloroethane ug/L 50 35.0 70 46-131 IK,v3 Chloroform ug/L 50 42.3 85 70-130 Chloromethane ug/L 50 52.8 106 49-130 cis-1,2-Dichloroethene ug/L 50 47.5 95 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 LABORATORY CONTROL SAMPLE: Parameter 3722514 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 52.1 104 70-130 Dibromochloromethane ug/L 50 50.3 101 70-130 Dibromomethane ug/L 50 47.6 95 70-130 Ethylbenzene ug/L 50 47.1 94 70-130 lodomethane ug/L 100 108 108 47-140 Methylene Chloride ug/L 50 44.7 89 68-130 Styrene ug/L 50 49.8 100 70-130 Tetrachloroethene ug/L 50 48.7 97 70-130 Toluene ug/L 50 47.0 94 70-130 trans-1,2-Dichloroethene ug/L 50 52.9 106 70-130 trans- 1,3-Dichloropropene ug/L 50 51.7 103 70-130 trans-1,4-Dichloro-2-butene ug/L 50 51.1J 102 25-2001K Trichloroethene ug/L 50 46.8 94 70-130 Trichlorofluoromethane ug/L 50 38.4 77 61-130 Vinyl acetate ug/L 100 102 102 70-140 Vinyl chloride ug/L 50 51.3 103 59-142 Xylene (Total) ug/L 150 148 98 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8(S) % 104 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3722515 MS 92617451001 Spike Parameter Units Result Conc. MSD Spike Conc. 3722516 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 19.3 22.9 97 115 70-135 17 30 1,1,1-Trichloroethane ug/L ND 20 20 23.6 24.0 118 120 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 16.6 17.4 83 87 70-131 5 30 1,1,2-Trichloroethane ug/L ND 20 20 17.9 20.1 89 100 70-136 11 30 1,1-Dichloroethane ug/L ND 20 20 19.2 19.4 96 97 70-147 1 30 1,1-Dichloroethene ug/L ND 20 20 22.5 21.6 112 108 70-158 4 30 1,2,3-Trichloropropane ug/L ND 20 20 17.2 18.5 86 92 67-137 7 30 1,2-Dibromo-3- ug/L ND 20 20 18.1 21.2 91 106 69-136 15 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.0 21.7 100 108 70-137 8 30 1,2-Dichlorobenzene ug/L ND 20 20 19.0 20.4 95 102 70-133 7 30 1,2-Dichloroethane ug/L ND 20 20 20.1 20.4 100 102 67-138 2 30 1,2-Dichloropropane ug/L ND 20 20 17.6 18.9 88 94 70-138 7 30 1,4-Dichlorobenzene ug/L ND 20 20 18.6 19.6 93 98 70-133 5 30 2-Butanone (MEK) ug/L ND 40 40 31.3J 38.6J 78 97 61-147 21 30 2-Hexanone ug/L ND 40 40 34.9J 39.6J 87 99 67-139 13 30 4-Methyl-2-pentanone ug/L ND 40 40 31.1J 36.7J 78 92 67-136 16 30 (MIBK) Acetone ug/L ND 40 40 38.3J 42.3J 96 106 55-159 10 30 Acrylonitrile ug/L ND 100 100 88.1J 97.2J 88 97 68-140 10 30 Benzene ug/L ND 20 20 18.7 20.7 93 103 67-150 10 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3722515 MS 92617451001 Spike Parameter Units Result Conc. MSD Spike Conc. 3722516 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 21.7 22.6 109 113 70-146 4 30 Bromodichloromethane ug/L ND 20 20 20.5 21.9 102 110 70-138 7 30 Bromoform ug/L ND 20 20 19.4 20.9 97 105 57-138 7 30 Bromomethane ug/L ND 20 20 24.0 23.1 120 115 10-200 4 30 Carbon disulfide ug/L ND 20 20 20.2J 21.1J 101 106 70-152 4 30 Carbon tetrachloride ug/L ND 20 20 23.8 25.6 119 128 70-147 7 30 Chlorobenzene ug/L ND 20 20 19.6 21.0 98 105 70-137 7 30 Chloroethane ug/L ND 20 20 24.7 25.6 124 128 51-166 3 30 Chloroform ug/L ND 20 20 19.6 19.5 98 97 70-144 1 30 Chloromethane ug/L ND 20 20 22.3 22.0 111 110 24-161 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 19.4 19.1 97 96 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 19.7 21.6 99 108 70-142 9 30 Dibromochloromethane ug/L ND 20 20 23.0 22.3 115 112 68-138 3 30 v1 Dibromomethane ug/L ND 20 20 19.4 21.6 97 108 70-134 10 30 Ethylbenzene ug/L ND 20 20 19.4 20.7 97 103 68-143 7 30 lodomethane ug/L ND 40 40 40.4 41.0 94 96 20-161 2 30 Methylene Chloride ug/L ND 20 20 15.3 17.0 76 85 64-148 10 30 v3 Styrene ug/L ND 20 20 19.6 20.5 98 103 70-136 4 30 Tetrachloroethene ug/L ND 20 20 20.9 22.3 104 111 70-139 6 30 Toluene ug/L ND 20 20 18.0 19.5 90 97 47-157 8 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.9 21.3 110 107 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 18.9 20.3 95 102 70-138 7 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.9J 20.5J 90 103 31-145 13 30 Trichloroethene ug/L ND 20 20 22.5 24.5 113 122 70-149 8 30 Tri ch lo rofl u oro m eth a n e ug/L ND 20 20 27.8 26.1 139 130 61-154 6 30 Vinyl acetate ug/L ND 40 40 34.1J 35.2J 85 88 48-156 3 30 Vinyl chloride ug/L ND 20 20 26.7 24.9 134 125 55-172 7 30 Xylene (Total) ug/L ND 60 60 60.6 64.8 101 108 66-145 7 30 1,2-Dichloroethane-d4 (S) % 104 101 70-130 4-Bromofluorobenzene (S) % 97 96 70-130 Toluene-d8 (S) % 91 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 QC Batch: 713329 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92616971001 METHOD BLANK: 3719307 Matrix: Water Associated Lab Samples: 92616971001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N ug/L ND 100 60.0 07/27/22 21:40 Nitrite as N ug/L ND 100 50.0 07/27/22 21:40 Sulfate ug/L ND 1000 500 07/27/22 21:40 LABORATORY CONTROL SAMPLE: 3719308 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 2500 2440 98 90-110 Nitrite as N ug/L 2500 2510 100 90-110 Sulfate ug/L 50000 49100 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3719309 3719310 MS MSD 92616971001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L ND 2500 2500 ND ND 41 40 90-110 10 D3,M1 Nitrite as N ug/L ND 2500 2500 1320J 1360J 53 54 90-110 10 D3,M1 Sulfate ug/L ND 50000 50000 23900 24200 45 46 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 QC Batch: 714249 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92616971001 METHOD BLANK: 3723864 Associated Lab Samples: 92616971001 Parameter Units Phosphorus ug/L LABORATORY CONTROL SAMPLE: 3723865 Parameter Units Phosphorus ug/L Matrix: Water Blank Reporting Result Limit ND 50.0 Spike LCS Conc. Result 2500 2530 MDL Analyzed Qualifiers 25.0 08/02/22 20:17 LCS % Rec % Rec Limits Qualifiers 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3723866 3723867 MS MSD 92616363002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L ND 2500 2500 2570 2650 103 106 90-110 3 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3723868 3723869 MS MSD 92616364001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 3.1 mg/L 2500 2500 5640 5380 103 92 90-110 5 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92616971 QC Batch: 714859 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92616971001 METHOD BLANK: 3727057 Matrix: Water Associated Lab Samples: 92616971001 Blank Reporting Parameter Units Result Limit Chemical Oxygen Demand ug/L ND 25000 LABORATORY CONTROL SAMPLE: 3727058 Spike LCS Parameter Units Conc. Result Chemical Oxygen Demand ug/L 750000 774000 MDL Analyzed Qualifiers 12500 08/04/22 06:13 LCS % Rec % Rec Limits Qualifiers 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3727059 3727060 MS MSD 92616657001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 158 mg/L 100000 100000 273000 273000 116 116 90-110 0 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3727061 3727062 MS MSD 92617135001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 127000 125000 111 109 90-110 2 3 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Foothills LF/Leachate Pace Project No.: 92616971 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L. CO Result confirmed by second analysis. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. P4 Sample field preservation does not meet EPA or method recommendations for this analysis. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF/Leachate 92616971 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92616971001 1403-Leachate 92616971001 1403-Leachate EPA 3005A 713723 EPA 6020B 713911 92616971001 1403-Leachate SM 5210B-2016 713177 SM 5210B-2016 714223 92616971001 1403-Leachate EPA 8260D 713994 92616971001 1403-Leachate EPA 300.0 Rev 2.1 1993 713329 92616971001 1403-Leachate EPA 365.1 Rev 2.0 1993 714249 EPA 365.1 Rev 2.0 1993 714494 92616971001 1403-Leachate SM 5220D-2011 714859 SM 5220D-2011 714901 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2022 03:11 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 23 cr o X2 c m v =o � g a 03 Q v C i —0 � cO �� x O m Jt O O1 v Z m ' d m = 1 a' m c 4 Z m C �c00 _ n X m>;a0 't N 0 m N m CA)M a i m 0 n —r r m c a _ o In z o m w 4s r -4 4 — (axmZ--)0-4Z0O X APPENDIX I- VOC BY 8260 t m m 2 � ..-1 >C APPENDIX I - METALS w T co X BOD co >C NITRATE, NITRITE w v >C COD N M X PHOSPHORUS N -o m` >C SULFATE w V o m � h � fn 1� m r v oco<oD ��� om; O OAK C z m D m O z �K>z m y xm amz n a� � �r>O�fA �taas.wro i y o 1)0_550Ejo ce ImzC r_ c 3000E ± 4: o� o 304 Pa 0 Z In C v n O s m e21 f23 Ace DC# Title: ENV-FRM-HUN1-0083 �01 Sample Condition Upon Receipt Effective Date: 05/12/2022 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlanta Kernersvjlle❑ Sample Condition Client Name: Upon Receipt` / Project #: f [ 0 Courier: a ft 1 ❑UPS CUSPS ❑Client ❑ Commercial ❑Pace ❑Other: Custody Seal Present? ❑Yes seals Intact? ❑Yes ❑No Toll / rif f 3/�- :?— Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Thermontet eff I Gun ID: Type of Ice: et Correction Factor - Cooler Temp: 3,,6 Add/Subtract (•C) Cooler Temp Corrected ("C): C5 USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States- CA, NY, or SC (check maps)? ❑Yes [7]No Date/Initials Person Examining Contents: f Biological Tissue Fro en? [-] Yes ❑No ❑Blue ❑Nore Temp should be above freezing to 6•C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, including Hawa-i and Puerto R'co)? ❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? e's []NO ❑N/A 1. Samples Arrived within Hold Time? [r]Ks ❑Nc- ❑N/A 2. Short Hold Time Analysis 1<72 hr.)? 2yef ❑N.) ❑N{A 3. Rush Turn Around Time Requested? ❑Yt a No ❑N.- A 4. Sufficient Volume? es ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? es es ❑No [:]No ❑N/A ❑N/A 6. Containers Intact? es [:]No []N/A 7. Dissolved analysis: Samples Field Filtered? []Yes ❑No /A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: , /� Yes vV [:]No❑N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes 04 [nN/A 10. Trip Blank Present? Trip Blank Custody Seals Present? [--]Yes ❑Yes [; IVo []No ❑N/A ?N/A/ 11 COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: Field Data Required? []Yes [:]No Page 22 of 23 Qualtrax ID: 69614 Page 1 of 2 DC# Title: ENV-FRM-HUN1-0083 v01 Sample Condition Upon Receipt .Ace, Mu�SIMMS 'Check mark top half of box if pH and/or dechlorination is verified and Project # within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine W Z a d c J E ry V 0. m Z ♦: w c J E uoi M G m Z v m c J E $ N G m ? v a u N 1 �, = r=i 0. m u V fl. a0 N N U CL J E `^ Q 0. m N a m Z 'W J E ,� M 0. m m O Z 03 o Q Z tNJ J E 0. N S O m Z m J E u, rNl Q 4 m w v m l7 L c E 3 u. a Z 'o y c a Q — eel n I7 Q _ v n v 2 w Q ° - a -I S t7 Q u 2 d c M E J of ,n N in l7 Q N 2 O n 2 Q �, .Y V� ay l7 a N V S O ry = N E J E N n�1 19 Q V v Z UQ x Z N a E J E ,o N M U' C = Z = a O £ 0 V i in [7 O Z m u, Z q O 0 >- Of U' 7 _ a Z v a N a Q a O E 0 Ch l7 Q ? O a 2 a > E 0 V 7 O1 (J G = Z v O T a O E o Vi M l7 C ¢ Z .+ N m = a 7 Y a N ° s fYl n[ (7 MN I Z u y N J E N L N a N I Z u v N J E o N H N 0. N a; N _ Z V o J E N N aC M ca ii a y Q = o C E Q E $ rl > O C H a p _ c V1 J E o N > > a v a c GI Q J E 0 7 M G 1 2 3 4 5 6 8 F97 30 li 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjUsted Amount of Preservative � � added'} Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEN Certification Ciffice (I.e. Out of hold, incorrect preservative, out of temp, incorrect containers. 7-- Page 23 of 23 Qualtrax ID: 69614 Page 2 of 2 FOOTHILLS LANDFILL J U LY 26, 2022 SAMPLE ID # DEPTH TO WATER (FT.) * RISER ELEV. (FT.) * WATER ELEV. (FT.) * MW-1 R2 16.23 1516.22 1499.99 MW-2R 50.94 1253.36 1202.42 MW-3 54.44 1241.95 1187.51 MW-3R 59.21 1242.69 1183.48 MW-3R2 40.55 1240.83 1200.28 MW-4 41.70 1171.18 1129.48 MW-5 47.59 1175.07 1127.48 MW-6 43.02 1176.82 1133.80 MW-7 29.49 1183.13 1153.64 MW-8 29.58 1195.18 1165.60 MW-9 70.05 1290.79 1220.74 MW-10 78.04 1358.53 1280.49 MW-11 83.09 1401.71 1318.62 * FROM THE TOP OF RISER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA POINT ID: FIELD BLANK FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION INITIAC'�R LEVEL (FT) ELEV., MEAS. PT. (MSL):---- DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER S.S. BAILER GRUNDFOS PUMP YES NO S.S. BAILER QED PUMP OTHER WELL RISER DIAMETER (IN.): 2 3 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNES TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (Fl TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA ( )NO Wom"L-(Sw pH its) mol maNOR SAMPLING INFORMATION DATE/TIME r7-25--?Z METHOD OF SAMPLING: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: GRUNDFOS PUMP YES OTHER NO TIME pH (Std.Units) TEMP. (C) CONDUCT. umhos/cm) TURBIDITY (N 'U) OTHER eh (mV) ] DISS. OXY. (PPM) OTHER NA NA NA NA NA NA — NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: k bV, SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA POINT ID: TRIP BLANK FIELD REPRESENTATIVE: ES&S-B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE/ PROJECT#: EVACJJATION INFORMATION INITIAL WjV VEL (FT) ELEV., MEAS. PT. (MSL): IST-11,110 METHOD OF EVACUATION: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA GRUNDFOS OTHER 3 ( ) 4 NA DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) 6 ( ) OTHEI"�'_� WAS WELL PURGED TO DRYI` WATER LEVEL END PURGE FINISH )YES( )NO Iwo pH (Std.UnitsLismi TURBIDITY NTU) im ��= Cam- � SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: GRUNDFOS PUMP YES OTHER NO TIME pH (Std. U n its) TEMP. (C) CONDUCT. (umhos/cm) TURBIDITY _(NTU) OTHER eh (mV) DISS. OXY. (PPM) OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C LEARL COMMENTS: VOA ONLY SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA ELEVATION, MEAS.PT.(MSL): F_ NA METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP POINT ID: Sw - 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT M NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS YES ( ) NO PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) ( ) NO TIME PUR � m/htz CUMULATIVE VOLU TEMP. C pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME / METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) WATERRA PUMP (X) YES (X) DIP BOTTLE ( ) NO TIME pH Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1.9 790 is'.is's 3.94NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C i J COMMENTS: SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: UD-2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER EVACUATION INFORMATION INITIAL WA L FEET) NA PT.(MSL)���_ To� ELEVATION, MEAS.PT.(MSL): DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS YES ( ) NO PUMPING WELL 'LL 4 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) CM%UbAXUF— VOLUME TEMP. pH Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (mV) I NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME LILI WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER o ;I,I I. l 4- e oo. q 3.72 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: c— C 0 (.l SAMPLE CHARACTERISTICS: COMMENTS: SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER INITIAL R LEVEL (FEET) NA ELEVATION, MEAS.PT. S); NA DATE METHOD OF EVACUATION: ``�•• ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTIN 3.1� ( ) S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) OTHER WAS WELL PURGED TO D SS WATER LEVEL AFTER PURGE (FT.) FINISH ( ) YES ( ) NO TIME PURGER m/htz f-'Up(IUL�AT�IVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA SAMPLING EQUIPMENT DEDICATED: ( ) WATERRA PUMP (X) YES (X) DIP BOTTLE ( ) NO TIME pH Std.Units) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 15; o �C 1 o +60,7 3.90 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: C- �i SAMPLE CHARACTERISTICS: C ®` l -T.-, COMMENTS: SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: SW-2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA-I`EEET) NA ELEVATION, MEAS.PT.(MSL): NA___ DATE ~~~' METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( ) NO TIME PURGE RA m/htz I.lLATIVE VOLUME--.` TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME -Z z/ 1 -5: 5 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 90 I. SAMPLE CHARACTERISTICS: A.r-I 0"rioit COMMENTS: SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: SW-5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL VVA$ LEVEL (FEET) NA ELEVATION, MEAS.PT.(M NA _ DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE ! PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINU ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRY S WATER LEVEL AFTER PURGE (FT.) FINISH ( ) YES ( ) NO TIME PUR m/htz UMULATIVE VOLUME TEMP. pH Std.Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 ---. NA NA NA SAMPLING INFORMATION DATE/TIME 15 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER GENERAL INFORMATION ^ 0r WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: COMMENTS: SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: SW-4 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAL Wgrnk-!=-EL (FEET) NA ELEVATION, MEAS,Plr;;L DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOUS YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) -MMbl-AT4VF— VOLUME TEMP. pH d.Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh NA 0 _(mV) I NA NA NA SAMPLING INFORMATION DATE / TIME r7-Zy-?-'L- / WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 10-7 I, 11,10 5-•0 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: c (.-jo " b SAMPLE CHARACTERISTICS: C COMMENTS: SAMPLE COLLECTION NUMBER 9 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION NA N::A:: N ER LEV EL (FEET) INITIA ER LEVEL (FEET) NA ELEVATION, MEAS. (A DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA ) CONTTt PUMPING ( ) 4 ( ) 6 POINT ID: SW - 3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT#: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: DUS YES NO ( ) OTHER WAS WELL PURGED TO NESS( )YES( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpm/htz) -C VE VOLUME TEMP. C pH Std.Units), SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh NA 0 _(mV) NA NA NA SAMPLING INFORMATION DATE / TIME r7-25-.2-Z/ W3k WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) ]+.?,2, REDOX eh (mV) DISS. OXY. (PPM) OTHER W40 (" go 57 r? P. 's 1, .7 5-15- 5-.03 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: b SAMPLE CHARACTERISTICS: f COMMENTS: SAMPLE COLLECTION NUMBER 9 SITE NAME FOOTHILLS LF POINT ID: 11 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION g3,o9 INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSQ: I LP 1 "T DATE 7 - a (o ® 2-'- FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): 10 ELEVATION, G/W (MSQ: TIME: START/FINISH 6. o a / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 4 6 OTHER ONE -(1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) Igo WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START C LEAZ- FINISH df C LE4f- EVACUATION STABILIZATION DATA lbim pH Std.Units) 1 ® i1 }F '� � �*!': ,III ®® it 4 1 i ®® � : ., .,, , .' ;♦ t. , ,. ... � <�I SAMPLING INFORMATION DATE / TIME ?-?-& DEPTH TO GROUNDWATER (FT) ff?, c?-? METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP OTHER NO GENERAL INFORMATION . F WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c k64 COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I I) SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSL): 1358-.53 DATE "? ® ?-- 2 2- POINT ID: mw-lo FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: mm DEPTH TO BOTTOM (FT): oog-..2/ ELEVATION, G/W (MSQ: sloml TIME: START/FINISH �a I ?12q METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 4 6 OTHER ONE (1) RISER VOLUME (GAL) l.(o3 WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) Q.00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA lolm a pH (Std.Units) i I , t }" i � ', i , � f .,.; '. ✓h. : � tom' i'.w. ®® ": ..,; , � �, � #�. ® ' .. �; � r '�.,: � .- ems:, ...,�. `", ,.,: �® SAMPLING INFORMATION "7 '79-n DATE / TIME DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0.1r. WEATHER CONDITIONS AT TIME OF SAMPLING: Su �v ri SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I I SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION r� INITIAL WATER LEVEL (FT): 1 POINT ID: MW — 9 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): . YO ELEV., MEAS. PT. (MSL): I 0 . ELEVATION, G/W (MSL): c1 DATE -- Z. TIME: START/FINISH / • / METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) 0.54 TOTAL VOL. EVACUATED (GAL) s00 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) o, / TURBIDITY OF PURGINGS: START C, FINISH EVACUATION STABILIZATION DATA WWI= PH ' . �i ,.- a ,� 1 � � „t: ^. .�. ,�,.. /;_ �' �■®� M � ♦` ... , '!. �: ✓> ,�, .�.. fir, . , SAMPLING INFORMATION DATE/TIME DEPTH TO GROUNDWATER (FT) to• / METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: t',N S SAMPLE CHARACTERISTICS: c— COMMENTS: APPENDIX 1 LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - S LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION �.- INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT): t ELEV., MEAS. PT. (MSL): 1 ELEVATION, G/W (MSL): I 0 r/ DATE m TIME: START/FINISH - / r METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: (X)2 ( )3 ( )4 ( )6 ( )OTHER . let WAS WELL PURGED TO DRYNESS ( ) YES (X) NO 00 WATER LEVEL END PURGE (FT) -2. 7 START EVACUATION STABILIZATION DATA FINISH C, ` s � SAMPLING INFORMATION DATE/TIME 2(" 2 Z / l DEPTH TO GROUNDWATER (FT) , '2 z METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0 WEATHER CONDITIONS AT TIME OF SAMPLING: 1.4 Pimy, SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER ! SITE NAME FOOTHILLS LF POINT ID: MW - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): - ELEV., MEAS. PT. (MSL): DATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA ELEVATION, G/W (MSL): I TIME: START/FINISH : / -'S 7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) I. WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) • 0® WATER LEVEL END PURGE (FT) O TURBIDITY OF PURGINGS: START c FINISH CLFAR- EVACUATION STABILIZATION DATA • pH • 1 SAMPLING INFORMATION DATE/TIME r7 -2-.. / ' DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION ci' WEATHER CONDITIONS AT TIME OF SAMPLING: o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): r DATE 0 2- - 2- FIELD REPRESENTATIVE: LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): MW-6 E S & S - B.CHIODO NA S- 0.55 ELEVATION, G/W (MSL): TIME: START/FINISH 101.114 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.20 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . ® Q WATER LEVEL END PURGE (FT) , J TURBIDITY OF PURGINGS: START e, FINISH EVACUATION STABILIZATION DATA PURGE RATE • pH �'' 1� , ®® �� III tom. { ', ! ", c✓+ �v�,` � ,:. t`! `:. SAMPLING INFORMATION DATE/TIME -2"2 T- / DEPTH TO GROUNDWATER (FT) q3. METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c L54z- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 15 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 1 r75. 07 * DATE `tl-'' Z POINT ID: Mw - 5 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 22 DEPTH TO BOTTOM (FT): Co ELEVATION, G/W (MSL): 1 . 41 TIME: START/FINISH 1 I; 0 1 / 1 /4' METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: (X)2 ( )3 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) 4/7 *7/ START FINISH C EVACUATION STABILIZATION DATA PURGE RATE • • • SAMPLING INFORMATION DATE / TIME °' 6 - Zz'- / 11 ' 33 DEPTH TO GROUNDWATER (FT) . 7/ METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 1") ' ,� f. WEATHER CONDITIONS AT TIME OF SAMPLING: ^Itea P .� SAMPLE CHARACTERISTICS: C COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): �, I DATE ® 2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): gg ELEVATION, G/W (MSL): t qg TIME: START/FINISH H, - 9 / 0 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) , TURBIDITY OF PURGINGS: START FINISH C, (X) 2 ( ) 3 1-tog oo EVACUATION STABILIZATION DATA pH SAMPLING INFORMATION DATE / TIME - 2-6 - Z DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: ss SAMPLE CHARACTERISTICS: c- COMMENTS: APPENDIX I LIST tA S / m s SAMPLE COLLECTION NUMBER 17 4•• 18 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): s DATE t®-II,,® -. POINT ID: MW - 3R2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: im DEPTH TO BOTTOM (FT): , ! ELEVATION, G/W (MSL): 100. _.._....... TIME: START/FINISH 12.39 / 13%10 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 5,134 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) Q, 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START 0 FINISH C LW EVACUATION STABILIZATION DATA 01 PURGE RATE (ML /'MIN) TOM pH (S-td.Units) MINE 1 r MW SAMPLING INFORMATION DATE /TIME "' / DEPTH TO GROUNDWATER (FT) 0. METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION ,. 0t' WEATHER CONDITIONS AT TIME OF SAMPLING: C4 , � SAMPLE CHARACTERISTICS: C Lr--A COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION g INITIAL WATER LEVEL (FT): 1 ELEV., MEAS. PT. (MSL): r! DATE ® 2(' - POINT ID: MW - I R2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA ELEVATION, G/W (MSL): 1 419.97 TIME: START/FINISH 1 : 3 to/ I METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) 2.00 WATER LEVEL END PURGE (FT) 16• 36 TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RATE (ML MIN)• 3Y VW 1 SAMPLING INFORMATION DATE / TIME 2' ® �— i DEPTH TO GROUNDWATER (FT) j METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: a.fr�/�+✓ �~ SAMPLE CHARACTERISTICS: C- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 070 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE -A INITIAL W TER+EV-F-L (FEET) NA ELEVATION, MEAS.PT;Z DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GAN (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: CONTINUOUS NO PUMPING WELL 4 6 ( ) OTHER WAS WELL PURGED TO DRYNESS �( ) ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpmlhtz) CUMUL-ATrVE- VOLUME EMP. (C) pH "-----4SLd. Units SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh mV) NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME 1q:qo METHOD OF SAMPLING: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) NA WATERRA PUMP (X) SAMPLE PORT SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) No TIME pH (Std. U n its) SPEC. CONDUCT. (umhos/cm) TEMP. —(C) 1 TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 111;liz ?, 00 ly 1&95'0 3;?- 5 — 5-9-..3 0 NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 5CA" IV SAMPLE CHARACTERISTICS: -774zA i b - COMMENTS: SAMPLE COLLECTION NUMBER a f SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): DATE P (p 2 z- FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA • ELEVATION, G/W (MSL): O TIME: START/FINISH % . 5 2 / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUNIP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) g,03 TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) 51, START FINISH EVACUATION STABILIZATION DATA '?, 50 PURGE m SAMPLING INFORMATION DATE / TIME - "'� / -F- J DEPTH TO GROUNDWATER (FT) 1, I METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0 cdc WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: CLEAt COMMENTS: APPENDIX I LIST NAF SAMPLE COLLECTION NLIMBER '� +