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8003_Rowan_MSWLF_CDLF_PTC_WQMP_FID1706002_20220812
Rowan County Landfill I Phase V Construction Permit Application 6 — Water Quality Monitoring Plan 6 — Water Quality Monitoring Plan Rowan County Landfill I Phase V Construction Permit Application ��� 6 — Water Quality Monitoring Plan This page intentionally left blank. �Z0 WAN 9Ap'�rHEw� O`y This page intentionally left blank. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Contents Contents 1 Introduction....................................................................................................................... 1 1.1 Site Description................................................................................................ 1 1.2 Site Geology and Hydrogeology....................................................................... 2 2 Groundwater Monitoring System..................................................................................... 2 2.1 Monitoring Well Network................................................................................... 2 2.2 Monitoring Well Construction............................................................................ 4 2.3 Monitoring Well Development........................................................................... 4 2.4 Maintenance and Recordkeeping..................................................................... 5 2.5 Monitoring Well Decommissioning.................................................................... 5 3 Groundwater Monitoring Program................................................................................... 5 3.1 Detection Monitoring......................................................................................... 6 3.1.1 Sampling Frequency......................................................................................... 6 3.1.2 Establishment of Background Data................................................................... 6 3.1.3 Evaluation of Detection Monitoring Data........................................................... 6 3.2 Assessment Monitoring.................................................................................... 7 3.3 MSW Unit......................................................................................................... 7 3.3.1 C&D Unit.......................................................................................................... 8 3.4 Evaluation and Reporting of Monitoring Data .................................................... 9 4 Groundwater Sampling Methodology.............................................................................. 9 4.1 Sample Collection............................................................................................. 9 4.2 Sampling Frequency......................................................................................... 9 4.3 Static Water Elevations..................................................................................... 9 4.3.1 Well Evacuation...............................................................................................10 4.4 Sample Preservation and Handling..................................................................13 4.5 Chain -of -Custody Program..............................................................................13 4.5.1 Sample Labels.................................................................................................13 4.5.2 Sample Seal....................................................................................................13 4.5.3 Field Logbook..................................................................................................13 4.5.4 Chain -of -Custody Record................................................................................14 4.6 Analytical Procedures......................................................................................14 4.7 Quality Assurance and Quality Control Program..............................................15 5 Statistical Methods..........................................................................................................16 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Contents 6 Surface Water Monitoring (Rule.0602)...........................................................................16 7 References.......................................................................................................................17 8 Professional Certification................................................................................................19 Tables Table 1 Summary of Groundwater Monitoring Well Construction Information Figures Figure 1 Water Quality Monitoring Plan Figure 2 Typical Groundwater Monitoring Well Schematic Appendices Appendix A — Regulatory Requirements Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Introduction 1 Introduction This Water Quality Monitoring Plan (WQMP) was initially prepared by Golder Associates NC, Inc. (Golder) for the Phase IV expansion of the Rowan County Landfill, Permit No. 80-03, located in Rowan County, North Carolina (NC). Under contract with Rowan County, HDR Engineering of the Carolinas, Inc. (HDR) conducted a hydrogeologic investigation of the proposed Phase V cell of the landfill in 2021 and 2022. The hydrogeologic investigation included installation of six groundwater monitoring wells that at the time of installation, were intended to be re -purposed as compliance monitoring wells under this WMQP. Since HDR designed and installed the wells, HDR has prepared this WQMP. However, it is our understanding that Golder will be responsible for implementation of this WQMP. Thus, HDR has not changed record keeping, sampling, statistics, or reporting means and methodology from the previously approved WQMP prepared by Golder and dated April 12, 2021. This WQMP will serve as a guidance document for collecting and analyzing groundwater and surface water samples, evaluating the associated analytical results, and monitoring for any potential releases to the uppermost aquifer from the Rowan County Landfill. The WQMP complies with NC Solid Waste Management Regulations (SWMR) Subchapter 13B .1630 through .1637 as part of the updated permit application for the active municipal solid waste (MSW) facility and section .0544 through .0545 for the closed construction and demolition (C&D) facility. The C&D facility closed in 2008. This Plan also addresses the requirements for surface water monitoring specified in Rule .0602. The pertinent geologic and hydrogeologic characteristics of the site, as described in the Design Hydrogeologic Report for the Cell IV expansion of the Rowan County Landfill, prepared by Buxton Environmental, Inc. (September 2011), Design Hydrogeologic Report for the Phase V expansion of the Rowan County Landfill by HDR (August 2022), and previous water quality monitoring reports prepared by Golder are summarized below. 1.1 Site Description The location of the facility is shown on the inlay on Figure 1. As presented, the Rowan County solid waste facility is located approximately 1.5 miles southeast of the town of Woodleaf on Campbell Road, Rowan County, NC. The landfill facility covers approximately 375 acres of land and is bounded to the north by Campbell Road, Second Creek and woodlands to the south and east, and wooded, residential and agricultural properties to the west. Surrounding land use is primarily rural residential, agricultural, or undeveloped and wooded. Access to the facility is via the drive off Campbell Road to the north. The facility is comprised of an active Subtitle D MSW unit, a closed C&D unit, and a closed land clearing inert debris (LCID) unit (Figure 1). Topographic elevations outside of the existing waste areas at the facility range from approximately 758 feet above mean sea level (AMSL) east of the existing scale house to approximately 640 feet AMSL at the edge of Second Creek along the southern property boundary. Elevations within the existing waste area range from 798 feet AMSL in Cell/Phase I to 680 feet AMSL at the southeast corner of Cell/Phase IV. Surface drainage from the landfill and surrounding areas is directed by one of the two main drainage features that drain into Second Creek, which flows from the southwest to the northeast (S&ME October 2005). Groundwater Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Monitoring System monitoring at the facility was initiated in December 1989 under the Detection Monitoring Program for MSW landfills. 1.2 Site Geology and Hydrogeology Geologically, the facility is located within the Charlotte Belt of the Piedmont Physiographic Province of NC (NCGS 1985). The Charlotte Belt is composed of Precambrian and Paleozoic bedrock, which is dominantly plutonic with plutons ranging from granite to gabbro. The oldest rocks in the Charlotte Belt are mafic gneisses, amphibolites, metagabbros, and metavolcanic rocks, with lesser amounts of biotite gneiss, granitic gneiss, mica schist, quartzite, and ultramafic rocks. Mica schists and mica hornblende gneisses locally have been intruded by granite. The rocks underlying the facility consist of mostly diorite, gabbro, and granite (NCGS 1985). The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of partially weathered, fractured, meta -volcanic rock. Groundwater occurs at depths ranging from near ground surface in valleys to more than 100 feet below grade on steep hills (S&ME October 2005). Depth -to -water measurements obtained during the January 2020 monitoring event were used to prepare a groundwater surface contour map of Cells/Phases I -IV, as presented on Figure 1 (Golder March 2020). As presented, the groundwater flow in the uppermost aquifer beneath the site is to the southeast toward Second Creek. The groundwater surface contour map and interpreted flow directions are consistent with previously submitted groundwater surface contour maps for this facility. Based on calculations from Golder, the average estimated linear groundwater flow velocity for the subsurface at the facility (Cell/Phase I -IV) is around 300 feet per year, which ranges from approximately 169 feet/year in the MSW area to approximately 509 feet/year in the C&D area (Golder August 2021). The range of groundwater flow is expected to vary depending on the topographic and hydrogeologic conditions. This was most notable in the Phase V area where the average estimated liner flow was 21 feet/year (HDR August 2022). 2 Groundwater Monitoring System The following sections present the proposed monitoring well network for the active MSW landfill unit and the closed C&D landfill unit, along with specifications associated with installing, developing, maintaining, and decommissioning facility monitoring wells. The proposed well locations are selected to yield groundwater samples representative of the conditions in the uppermost aquifer underlying the facility, and to monitor for potential releases from each landfill unit. Groundwater monitoring wells shall be sampled during the active life of the landfill as well as the post -closure period, in accordance with Rule .1630 and .0544 of the NC SWMR. 2.1 Monitoring Well Network The proposed monitoring network, as shown on Figure 1, is designed to monitor for potential releases to the uppermost aquifer from the MSW and C&D units. Existing monitoring wells MW- Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan Groundwater Monitoring System 9 and MW-16 are the background compliance wells for the MSW unit, and are located upgradient of the MSW unit. Similarly, well MW-17 is the background compliance well for the C&D unit. The need for additional background wells will be evaluated based on analytical results, if appropriate. The active MSW landfill monitoring network is currently comprised of 13 downgradient monitoring wells, which monitor the uppermost aquifer beneath the facility: MW-1, MW-7, MW- 11, MW-12, MW-13, MW-20, MW-23, MW-23A, MW-24R, MW-25, MW-26, MW-27, and MW- 28R. The following monitoring wells will be added to the network to monitor the Phase V expansion area: MW-30, MW-31, MW-32, MW-33, and MW-34. In addition, monitoring wells MW-6, MW-23, MW-27A, and MW-28 are monitored during each semi-annual sampling event for water levels only. Note that well MW-26 is located within the Phase V expansion area and will be monitored until commencement of construction of Phase V, at which time the well will be abandoned in accordance with Section 2.5 of this plan. A French Drain that lies within the Phase III footprint is also monitored. Two downgradient monitoring wells (MW-18R and MW-19) are sampled to monitor the C&D landfill. Additional downgradient wells will be added to the monitoring network, if needed, as future phases are constructed. Refer to the table below for a summary of proposed monitoring wells. Monitoring Point Identification Monitoring Well Location MSW Facility MW-9 Upgradient MW-16 Upgradient MW-1 Downgradient MW-7 Downgradient MW-11 Downgradient MW-12 Downgradient MW-13 Downgradient MW-20 Downgradient MW-23 Downgradient MW-24R Downgradient MW-25 Downgradient MW-26* Downgradient MW-27 Downgradient MW-28R Downgradient MW-30 Downgradient MW-31 Downgradient MW-32 Downgradient MW-33 Downgradient MW-34 Downgradient French Drain Downgradient MW-6 Water Levels Only MW-23A Water Levels Only MW-27A Water Levels Only MW-28 Water Levels Only C&D Facility MW-17 Upgradient MW-18R Downaradient Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Monitoring System Monitoring Point Identification Monitoring Well Location MW-19 Downgradient - MW-26 to be decommissioned prior to Phase V construction. 2.2 Monitoring Well Construction The well completion details for the existing groundwater compliance monitoring wells are included in Table 1. Drilling and installation of any new monitoring wells will be performed in accordance with the specifications outlined in 15A NCAC Subchapter 2C, Section .0100. A typical groundwater monitoring well schematic is provided as Figure 2. Further guidance is provided in the Draft and US EPA Region 4 Science and Ecosystem Support Division (SESD)'s Design and Installation of Monitoring Wells (February 2008). Drilling and well installation activities will be conducted in under the supervision of a licensed geologist. New wells will be located by a licensed surveyor to within +0.1 foot on the horizontal plane and +0.01 foot vertically in reference to existing survey points. A boring log, well construction log, groundwater monitoring network map, well installation certification, and survey data will be submitted to the Solid Waste Section (SWS) upon completion. 2.3 Monitoring Well Development Newly constructed wells will be developed to remove particulates present in the well due to construction activities, and to interconnect the well with the aquifer. Groundwater monitoring wells will be developed to reduce turbidity, as outlined in US EPA Region 4 Science and Ecosystem Support Division (SESD)'s Groundwater Sampling Operating Procedure (April 2017). Development of new monitoring wells will be performed no sooner than 24 hours after well construction. Wells may be developed with disposable bailers, a well development pump, or other approved method. A surge block may be used as a means of assessing the integrity of the well screen and riser. In the event a pump is employed, the design of the pump will be such that any groundwater that has come into contact with air is not allowed to drain back into the well. In general, each well will be developed until sediment -free water with stabilized field parameters (i.e., temperature, pH, and specific conductance) is obtained. Well development equipment (i.e., bailers, pumps, surge blocks) and any additional equipment that contacts subsurface formations will be decontaminated prior to on -site use, between consecutive on -site uses, and/or between consecutive well installations. The purge water will be disposed of on the ground surface at least 10 feet downgradient of the monitoring well, unless field characteristics suggest the water will need to be disposed of otherwise. If field characteristics suggest, the purge water will be containerized and disposed of by other approved means. Samples withdrawn from the facility's monitoring wells should be clay- and silt -free; therefore, existing wells may require re -development from time to time based upon observed turbidity levels during sampling activities. If re -development of an existing monitoring well is required, it will be performed in a manner similar to that used for a new well. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Monitoring Program 2.4 Maintenance and Recordkeeping The monitoring wells will be used and maintained in accordance with design specifications throughout the life of the monitoring program. Routine well maintenance will include inspection and correction/repair of, as necessary, identification labels, concrete aprons, locking caps and locks, and access to the wells. Should it be determined that background or compliance monitoring wells no longer provide samples representative of the quality of groundwater passing the relevant point of compliance, the SWS will be notified. The owner will re-evaluate the monitoring network, and provide recommendations to the SWS for modifying, rehabilitating, decommissioning, or installing replacement or additional monitoring wells, as appropriate. Laboratory analytical results will be submitted to the SWS semi-annually. Analytical data, calculations, and other relevant groundwater monitoring records will be kept throughout the active life of the facility and the post -closure care period, including notices and reports of any NC (2L) Groundwater Protection Standard or Interim Maximum Allowable Concentration (IMAC) exceedances, re -sampling notifications, and re -sampling results. 2.5 Monitoring Well Decommissioning Piezometers and wells installed within the MSW waste footprint will be properly decommissioned in accordance with the procedures for permanent decommissioning, as described in 15A NCAC 2C Rule .0113(b). The piezometers and wells will be progressively decommissioned as necessary to complete landfill construction activities. The piezometers and wells that are within the proposed footprint will be overdrilled to remove well construction materials, and then grouted with a cement-bentonite grout. Other piezometers and wells that will potentially interfere with clearing and construction activities will be grouted in place without overdrilling with a cement-bentonite grout and removing surface features, such as concrete aprons, protective casings, and stick-ups. In each case, the bentonite content of the cement- bentonite grout shall be approximately 5%, and a tremie pipe will be used to ensure that grout is continuously placed from the bottom of the borehole/monitoring well upward. If a monitoring well becomes unusable during the monitoring period of the landfill, the well will be decommissioned in accordance with the procedures described above. Approval from the SWS will be obtained prior to decommissioning any monitoring well. For each monitoring well decommissioned, the following information will be provided to the SWS in a report sealed by a licensed geologist: the monitoring well name, a description of the procedure by which the monitoring well was decommissioned, the date when the monitoring well was considered to be taken out of service, and the date when the monitoring well was decommissioned. 3 Groundwater Monitoring Program The following sections present the monitoring requirements for this facility. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Monitoring Program 3.1 Detection Monitoring Groundwater samples for the MSW unit will be analyzed semi-annually for the Appendix I list of constituents as defined in Rule .1633 (i.e., Detection Monitoring Program), during the life of the facility and the post -closure care period. Groundwater samples for the closed C&D unit will be analyzed semi-annually for the constituents listed in NC Appendix I plus mercury, chloride, manganese, sulfate, iron, specific conductance, pH, temperature, alkalinity, and total dissolved solids (TDS) as defined in Rule .0544(b)(1)(D) under Detection Monitoring, during the post - closure care period. The current SWS analyte list is included in Appendix A. Note that analytical methods should be consistent with SWS-846 approved methodology. 3.1.1 Sampling Frequency Groundwater samples will be collected semi-annually and analyzed for constituents outlined above along with required field parameters, including but not limited to, pH, conductivity, and temperature. If either the MSW or C&D units must progress to Assessment Monitoring, notification and sampling will be conducted according to the schedule specified in Rules .1634 and .0545. 3.1.2 Establishment of Background Data During each phase of facility development, a minimum of four independent groundwater samples will be collected from the newly installed monitoring wells (other than replacement wells) or as specified in the permit. Samples collected from these wells will be analyzed for the detection monitoring constituents. The intent of background sampling is to collect data to more accurately reflect the natural fluctuations that may occur with these constituents. The data will be submitted to the SWS after completion of the fourth background sampling event. 3.1.3 Evaluation of Detection Monitoring Data During the Detection Monitoring Program, the reported constituent concentrations from downgradient compliance wells will be compared to the groundwater protection standards or GPS (i.e., NC 2L Standards and IMACs). If inorganic Detection Monitoring parameters are determined to be above the groundwater protection standards, the reported constituent concentrations from downgradient compliance wells will be statistically compared to the site - specific background standard using approved statistical procedures in .1632(g), (h) and (i) to determine if a release has occurred. If a constituent is detected above both its groundwater quality standard and its site -specific background standard, the following procedures will be followed for the MSW unit: Notify SWS within 14 days of this finding, report to the Division and place a notice in the operating record indicating which constituents have exceeded groundwater protection standards. 2. Within 90 days, establish an Assessment Monitoring Program meeting the requirements of Rule .1634 or .0545 as appropriate, except as discussed below. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Monitoring Program If a constituent is detected above both its groundwater quality standard and its site -specific background standard at the C&D unit, the following procedures will be followed in accordance with Rule .0545: 1. Within 30 days, submit an Assessment Monitoring Work Plan to the SWS for review. 2. Upon the SWS's approval of the Assessment Monitoring Work Plan, initiate Assessment Monitoring. The data may be evaluated within 90 days following the exceedance, and wells may be resampled if appropriate, to determine if the concentration resulted from an error in sampling, analysis, statistical evaluation, or natural variation in groundwater quality; or a source other than the facility. If it can be demonstrated that one of these factors occurred, a report [an Alternate Source Demonstration (ASD)] certified by a licensed geologist or engineer will be submitted to the SWS within 90 days of identifying the suspect GPS and/or statistical increase. A copy of this report will be placed in the operating record. If the SWS approves the ASD, the Detection Monitoring Program will be resumed with the required semi-annual sampling and analysis. If SWS does not accept the demonstration, Assessment Monitoring will be initiated. 3.2 Assessment Monitoring Assessment Monitoring is required for either waste unit whenever one or more detection monitoring constituents are detected at concentrations that exceed the GPS and no source of error or naturally occurring condition can be identified. If an error or naturally occurring condition cannot be identified Assessment Monitoring will be initiated at the MSW and C&D units as described below. 3.3 MSW Unit In accordance with Rule .1634. within 90 days of triggering the Assessment Monitoring Program, and annually thereafter, groundwater will be sampled for analysis of the NC Appendix II list of constituents. A minimum of one groundwater sample will be collected from each downgradient well and submitted for analysis during each Assessment Monitoring sampling event. However, the NCSWMR allow for petitions to the SWS for an appropriate subset of wells or a reduction in the NC Appendix 11 sampling list. If any NC Appendix II constituents are detected in groundwater from the downgradient wells, a minimum of four independent samples will be collected from each background and downgradient well to establish background concentrations for the detected NC Appendix II constituents. Within 14 days after receipt of the sampling analytical data, a report identifying the detected NC Appendix II constituents will be submitted to the SWS, and a notice will be placed in the operating record. Background concentrations of any detected NC Appendix II constituents will be established and reported to the SWS. Within 90 days, and on at least a semi-annual basis thereafter, the wells will be sampled and analyzed for the NC Appendix I list plus any additional detected Appendix 11 constituents. An Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Monitoring Program analytical results report of each sampling event will be submitted to the SWS and placed in the facility operational record. The SWS will determine whether site -specific GPS will be established for the facility and may specify a more appropriate alternate sampling frequency for repeated sampling and analysis for the full set of NC Appendix II constituents. Groundwater monitoring will continue in one of two ways, based on the results of the Assessment Monitoring statistical analyses: 1. If the NC Appendix II constituents are at or less than approved GPS for two consecutive sampling events, the facility may resume Detection Monitoring with the approval of SWS. 2. If one or more NC Appendix II constituents are detected at statistically significant concentrations in excess of the approved GPS, and no source of error can be identified, within 14 days of determination the SWS will be notified, a notice will be placed in the operating record, and all appropriate local government officials will be notified. The facility will proceed to a characterization of the nature and extent of the release (Rule .1634(f)(1)). Next, the facility operator will initiate an Assessment of Corrective Measures and corrective action and proceed according to Rules .1635 through .1637. If the facility proceeds to corrective action, a Corrective Action Monitoring Plan will be submitted to the SWS with the Corrective Action Plan. 3.3.1 C&D Unit After triggering Assessment Monitoring, water quality monitoring will be performed in accordance with the approved Assessment Monitoring Work Plan, which will include at a minimum one sampling event where monitoring wells are sampled for NC Appendix II constituents. A minimum of one groundwater sample will be collected from each downgradient groundwater monitoring well and submitted for analysis If any Appendix II constituents are detected in groundwater from the downgradient wells, a minimum of 4 independent samples will be collected from each background and downgradient groundwater monitoring well to establish background concentrations for the detected NC Appendix II constituents. After approval of the Assessment Monitoring Work Plan and completion of an initial NC Appendix II sampling event, and on at least a semi-annual basis thereafter, the wells will be sampled and analyzed for the Appendix I list plus any additional detected Appendix 11 constituents. An analytical results report of each sampling event will be submitted to the SWS and placed in the facility operational record. The SWS will determine whether site -specific GPS will be established for the facility and may specify a more appropriate alternate sampling frequency for repeated sampling and analysis for the full set of NC Appendix II constituents. Groundwater monitoring will continue in one of two ways, based on the results of the assessment monitoring statistical analyses: If the NC Appendix 11 constituents are at or less than background values using approved statistical procedures for two consecutive sampling events, the facility may resume detection monitoring with the approval of SWS. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology 2. If one or more NC Appendix II constituents are detected at statistically significant concentrations in excess of the approved GPS, and no source of error can be identified, a notice will be placed in the operating record, and all appropriate local government officials will be notified. The facility will proceed to a characterization of the nature and extent of the release. If the facility proceeds to corrective action, an Assessment of Corrective Measures will be submitted to the SWS and a remedy will be selected. 3.4 Evaluation and Reporting of Monitoring Data Reports will be submitted electronically with analytical and field data submitted in the required formats, and be accompanied by the required Environmental Monitoring Form, which will be signed and sealed by a licensed geologist in the State of NC. A copy of this form is also included in Appendix A. The reported constituent concentrations from downgradient compliance wells will be compared to background values, NC 2L Standards and/or IMACs using a value -to - value comparison. Any exceedances will be identified in the semi-annual submittals to the SWS and 14-day notifications for new exceedances submitted for the MSW facility. 4 Groundwater Sampling Methodology Groundwater samples will be collected in accordance with Rules .1632 or .0544/.0545 and this Water Quality Monitoring Plan. The most current US EPA Region 4 SESD guidance will be utilized for sampling, as applicable, including: Management of Investigation Derived Waste (May 2020), Field Equipment Cleaning and Decontamination (June 2020), and Groundwater Sampling Operating Procedure (April 2017). Procedures for well purging, sample withdrawal, decontamination methods, and chain -of -custody procedures are outlined below. Field parameter measurements will be submitted electronically to the SWS in a format consistent with SWS policies. 4.1 Sample Collection The procedures for collecting groundwater samples are presented below. The background wells for the MSW unit (MW 9 and MW-16) and C&D unit (MW-17) will be sampled first, followed by the downgradient compliance wells. The downgradient wells will be sampled so that the most contaminated well, if one is identified from the previous sampling event, will be sampled last. 4.2 Sampling Frequency The above -mentioned samples will be collected on a semi-annual basis throughout the life of the facility and post -closure care period. 4.3 Static Water Elevations The static groundwater level will be measured with an electronic water level indicator, to the nearest 0.01 foot, in each well prior to sampling. Static groundwater elevations will be calculated from groundwater depth measurements and top of casing elevations. A reference point will be marked on the top of casing of each well to ensure the same measuring point is used each time static groundwater levels are measured. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology If a monitoring well contains a dedicated pump, the depth -to -water shall be measured without removing the pump. Depth -to -bottom measurements should be taken from the well construction data and updated when pumps are removed for maintenance. 4.3.1 Well Evacuation Existing monitoring wells in the current compliance network contain dedicated bladder pumps and pumps will be installed in any new wells. The preferred well evacuation and sampling procedure for the site is a low -flow purge (micropurge) and sample methodology and procedure. Standard evacuation and sample methodology and procedures are also outlined below based on the US EPA Groundwater Sampling Operating Procedure (April 2017), as an alternate. 4.3.1.1 LOW -FLOW PROCEDURES Monitoring wells may be purged and sampled using the low -flow sampling method in accordance with the procedures presented below. Depth -to -water measurements will be obtained using an electronic water level indicator capable of recording the depth to an accuracy of 0.01 foot. A determination of whether or not the water table is located within the screened interval of the well will be made. If the water table is not within the screened interval, the amount of drawdown that can be achieved before the screen is intersected will be calculated and the amount of drawdown should be minimized to keep the screen from being exposed. The water level should not fall within 1 foot of the top of the well screen. If the water table is within the screened interval, total drawdown should not exceed 1 foot so as to minimize the amount of aeration and turbidity. If the purging equipment is non -dedicated, the equipment will be lowered into the well, taking care to minimize the disturbance to the water column. If conditions (i.e., water column height and well yield) allow, the pump will be placed in the uppermost portion of the water column (minimum of 18 inches of pump submergence is recommended). The minimum volume/time period for obtaining independent water quality parameter measurements (WQPM) will be determined. The minimum volume/time period is determined based on the stabilized flow rate and the amount of volume in the pump and the discharge tubing (alternatively, the volume of the flow cell can be used, provided it is greater than the volume of the pump and discharge tubing). Volume of the bladder pump should be obtained from the manufacturer. Volume of the discharge tubing is as follows: • 3/8-inch inside diameter tubing: 20 milliliters per foot • 1/4-inch inside diameter tubing:10 milliliters per foot • 3/16-inch inside diameter tubing: 5 milliliters per foot Once the volume of the flow -cell or the pump and the discharge tubing has been calculated, the well purge will begin. The flow rate should be based on historical data for that well (if available) and should not exceed 500 milliliters per minute. The initial round of WQPM should be recorded and the flow rate adjusted until drawdown in the well stabilizes. Water levels should be measured periodically to maintain a stabilized water level. If the purge rate has been reduced to 100 milliliters or less and the head level in the well continues to decline, the required water 10 Rowan County Landfill i Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology samples should be collected following stabilization of the WQPM, based on the criteria presented below. If neither the head level nor the WQPM stabilize, a passive sample should be collected. Passive sampling is defined as sampling before WQMP have stabilized if the well yield is low enough that the well will purge dry at the lowest possible purge rate (generally less than 100 milliliters per minute). WQPM stabilization is defined as follows: pH (+/- 0.2 S.U.), conductance (+/- 5% of reading), temperature (+/- 0.2°Celsius or C), and dissolved oxygen or DO [+/- 20% of reading or 0.2 milligrams per liter or mg/L (whichever is greater)]. Oxidation reduction potential (ORP) will be measured and ideally should also fall within +/- 10 mV of reading; however, this is not a required parameter. At a minimum, turbidity measurements should also be recorded at the beginning of purging, following the stabilization of the WQPM, and following the collection of the samples. The optimal turbidity range for micropurging is 10 Nephelometric Turbidity Units (NTU) or less. Turbidity measurements above 10 NTU are generally indicative of an excessive purge rate or natural conditions related to excessive fines in the aquifer matrix. Stabilization of the WQPM should occur in most wells within five to six rounds of measurements. If stabilization does not occur following the removal of a purge volume equal to three well volumes, a passive sample will be collected. The direct -reading equipment used at each well will be calibrated in the field according to the manufacturer's specifications prior to each day's use and checked at a minimum at the end of each sampling day. Calibration information should be documented in the instrument's calibration logbook and the field book. Each well is to be sampled immediately following stabilization of the WQPM. The sampling flow rate must be maintained at a rate that is less than or equal to the purging rate. For volatile organic compounds (VOCs), lower sampling rates (100 - 200 milliliters/minute) should be used. Final field parameter readings should be recorded at the time of sampling. 4.3.1.2 STANDARD EVACUATION PROCEDURES Monitoring wells may be evacuated with a submersible pump or a disposable bailer. If the pump is used for multiple wells, it and any other non -dedicated equipment will be decontaminated before use and between use at each well. A low -yield well (one that yields less than 0.5 gallon per minute) will be purged so that water is removed from the bottom of the screened interval. Low -yield wells will be evacuated to dryness once. However, at no time will a well be evacuated to dryness if the recharge rate causes the formation water to vigorously cascade down the sides of the screen and cause an accelerated loss of VOCs. Upon recharging of the well and no longer than 24 hours from completing the purge, the first sample will be field-tested for pH, temperature, specific conductivity, and turbidity. Samples will then be collected and containerized in the order of the volatilization sensitivity of the target constituents. 11 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology A high -yield well (one that yields 0.5 gallon per minute or more) will be purged so that water is drawn down from above the screen in the uppermost part of the water column to ensure that fresh water from the formation will move upward in the screen. If a pump is used for purging, a high -yield well should be purged at less than 4 gallons per minute to prevent further well development. A minimum of three casing volumes will be evacuated from each well prior to sampling. An alternative purge will be considered complete if the monitoring well goes dry before removing the calculated minimum purge volume. The well casing volume for a 2-inch well will be calculated using the following formula: Vc (gallons) = 0.163 x hw where: Vc = volume in the well casing = (dc2/4) x 3.14 x hw x 7.48 gallons/cubic foot do = casing diameter in feet (dc = 0.167) hw = height of the water column (i.e., well depth minus depth to water) The purge water will be disposed of on the ground surface at least 10 feet downgradient of the monitoring well, unless field characteristics suggest the water will need to be disposed of otherwise. The bailers will be equipped with a check valve and bottom -emptying device. The bailer will be lowered gently into the well to minimize the possibility of degassing the water. Field measurements of temperature, pH, specific conductance, and turbidity will be made before and after sample collection as a check on the stability of the groundwater sampled over time. Precautions to minimize turbidity will be taken. The direct -reading equipment used at each well will be calibrated in the field according to the manufacturer's specifications prior to each day's use and checked at a minimum at the end of each sampling day. Calibration information should be documented in the instrument's calibration logbook and the field book. 4.3.1.3 COLLECTION Samples will be collected and containerized in the order described below. • VOCs (SW- 846 Method 8260) • Semi -Volatile Organic Compounds (SW- 846 Method 8270) • Herbicides (SW-846 Method 8151) • Pesticides (SW- 846 Method 8080) • Polychlorinated Biphenyls (PCBs; SW-846 Method 8082) • Cyanide and Sulfide • Total Metals • Field and General Chemistry Parameters (as applicable) 12 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology Samples will be transferred directly from field sampling equipment into pre -preserved, laboratory -supplied containers. 4.3.1.4 DECONTAMINATION Non -dedicated field equipment that is used for purging or sample collection shall be cleaned with a phosphate -free detergent, and triple -rinsed with distilled water. Any disposable tubing used with non -dedicated pumps should be discarded after use at each well. Clean, chemical - resistant nitrile gloves will be worn by sampling personnel during well evacuation and sample collection. Measures will be taken to prevent contact with surface soils, which could introduce contaminants into the well or sample. 4.4 Sample Preservation and Handling Upon containerizing groundwater samples, the samples will be packed into pre -chilled, ice -filled coolers and either hand -delivered or shipped overnight by a commercial carrier to a NC -certified laboratory for analysis. Sample preservation methods will be used to retard biological action and hydrolysis, as well as to reduce sorption effects. These methods will include chemical preservation, cooling/refrigeration at 4° C, and protection from light. 4.5 Chain -of -Custody Program The chain -of -custody program will allow for tracing sample possession and handling from the time of field collection through laboratory analysis. The chain -of -custody program includes sample labels, sample seal, field logbook, and chain -of -custody record. 4.5.1 Sample Labels Legible labels sufficiently durable to remain legible when wet will contain the following information: • Site and sample identification number • Monitoring well number or other location • Date and time of collection • Name of collector • Parameters to be analyzed • Preservative, if applicable 4.5.2 Sample Seal The shipping container will be sealed to ensure that the samples have not been disturbed during transport to the laboratory. The tape is labeled with instructions to notify the shipper if the seal is broken prior to receipt at the laboratory. 4.5.3 Field Logbook The field logbook will contain sheets documenting the following information: • Identification of the well • Well depth • Field meter calibration information 13 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology • Static water level depth and measurement technique • Purge volume (given in gallons) • Time well was purged • Date and time of sample collection • Well sampling sequence • Types of sample containers used and sample identification numbers • Preservative used • Field analysis data and methods • Field observations on sampling event • Name of collector(s) • Climatic conditions including air temperatures and precipitation 4.5.4 Chain -of -Custody Record The chain -of -custody record is required for tracing sample possession from time of collection to time of receipt at the laboratory. A chain -of -custody record will accompany each individual shipment. The record will contain the following information: • Sample destination and transporter • Sample identification numbers • Signature of collector • Date and time of collection • Sample type • Identification of well • Number of sample containers in shipping container • Parameters requested for analysis • Signature of person(s) involved in the chain of possession • Inclusive dates of possession • Internal temperature of shipping container upon opening in laboratory (noted by the laboratory) A copy of the completed chain -of -custody form will accompany the shipment and will be returned to the shipper after the shipping container reaches its destination. The chain -of -custody record will also be used as the analysis request sheet. 4.6 Analytical Procedures A laboratory certified by the North Carolina Department of Environmental Quality (NC DEQ) will be utilized for analysis of the groundwater and surface water samples. Analyses will be performed in accordance with United States Environmental Protection Agency (US EPA) SW- 846 methods in accordance with the US EPA guidance document (US EPA 1997; Update VI I). The monitoring parameters are listed in Appendix A. Alternate SW-846 methods may be used if they have the same or lower reporting limits. The laboratory must report any detection of any constituent to the method detection limit (MDL) and identify the practical quantitation limit (PQL). The MDL should be at or below established groundwater and surface water standards, where applicable. 14 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Groundwater Sampling Methodology The laboratory certificates -of -analyses shall, at a minimum, include the following information: • Narrative: Must include a brief description of the sample group (number and type of samples, field and associated lab sample identification numbers, preparation and analytical methods used). The data reviewer shall also include a statement that all holding times and Quality Control (QC) criteria were met, samples were received intact and properly preserved, with a brief discussion of any deviations potentially affecting data usability. This includes, but is not limited to, test method deviation(s), holding time violations, out -of -control incidents occurring during the processing of QC or field samples and corrective actions taken, and repeated analyses and reasons for the re -analyses (including, for example, contamination, failing surrogate recoveries, matrix effects, or dilutions). The narrative shall be signed by the laboratory director or authorized laboratory representative, signifying that all statements are true to the best of the reviewer's knowledge, and that the data meet the data quality objectives as described in this plan (except as noted). One narrative is required for each sample group. • Original Chain -of- Custody Form. • Target Analyte List (TAL)/Target Compound List (TCL): The laboratory shall list all compounds for which the samples were analyzed. The TAL/TCL is typically included as part of the analytical reporting forms. • Dilution factors with a narrative of the sample results, including the reasons for the dilution (if any). • Blank Data: For organic analyses, the laboratory shall report the results of any method blanks, reagent blanks, trip blanks, field blanks, and any other blanks associated with the sample group. For inorganic analyses, the laboratory shall provide the results of any preparation or initial calibration blanks associated with the sample group. • QC Summary: The laboratory will provide summary forms detailing laboratory QC sample results, which include individual recoveries and relative percent differences (if appropriate) for the following Quality Assurance (QA)/QC criteria: surrogates, Matrix Spike (MS) analyses, MS Duplicate analyses, Laboratory Control Standard (LCS), and sample duplicate analyses. QC control limits shall also be reported; if any QC limits are exceeded, a flag or footnote shall be placed to indicate the affected samples. Additional QA data and/or other pertinent data may be reported as requested by the owner/operator of the facility. 4.7 Quality Assurance and Quality Control Program A field blank may be collected and analyzed during each monitoring event to verify that the sample collection and handling process has not affected the quality of the samples. The field blank will be prepared in the field and exposed to the sampling environment. As with all other samples, the time of the blank exposure will be recorded so that the sampling sequence is documented. The field blank will be analyzed for the same list of constituents as the groundwater samples. The assessment of blank analysis results will be in general accordance with US EPA guidance documents (US EPA 1993 and 1994). No positive sample results will be relied upon unless the 15 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Statistical Methods concentration of the compound in the sample exceeds ten times the amount in any blank for common laboratory contaminants, or five times the amount for other compounds. If necessary, re -sampling will be performed to confirm or refute suspect data; such re -sampling will occur within the individual compliance monitoring period. The "B" qualifier designates that the reported detection is considered to represent cross -contamination and that the reported constituent is not considered to be present in the sample at the reported concentration. 5 Statistical Methods Statistical analysis of groundwater monitoring data is not required by regulation for landfill compliance. However, it is allowed by regulation for the purposes of determining naturally occurring (i.e., background) concentrations of constituents. If utilized, statistical evaluation of groundwater monitoring data will be performed in compliance with Rule .1632 (g), (h), and (i) and the US EPA's Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance (March 2009). Statistics will not be utilized for the water quality and indicator parameters, which are collected for qualitative and informational purposes only. Intra-well statistical comparisons may be used to evaluate the inorganic groundwater data, if appropriate. Intra-well monitoring does not require background monitoring at upgradient wells or pooling of the data because water chemistry of a well is compared to itself over time. However, upgradient well(s) are useful for detecting any potential offsite influences on the monitoring network and will be monitored. Intra-well monitoring is generally preferable to inter -well monitoring for lined facilities because it eliminates the spatial component of natural groundwater chemistry variability; this spatial component can comprise a significant portion of the total variability that must be accounted for by the statistical methodology. 6 Surface Water Monitoring (Rule .0602) In accordance with Rule .0602 of the NCSWMR, surface water monitoring locations have been established to monitor surface water quality at the facility. Four surface water locations (SW-1 through SW-4) will be monitored at the MSW unit. An additional surface water location (SW-5) will be monitored downstream of the C&D unit. Monitoring locations are shown on Figure 1. The upstream monitoring point for both the MSW and C&D units (SW-1) is along Second Creek. Downstream monitoring points SW-3 and SW-4 are downstream monitoring locations along unnamed tributaries to Second Creek. Downstream monitoring point SW-5 monitors Second Creek downgradient of the C&D unit, and SW-2 monitors Second Creek downstream of both units near the property line. Note that location SW-3 captures discharge from the underdrain and runoff from the proposed Cell/Phase V expansion area, thus, no additional surface water samples are proposed. Samples will only be collected at each location if flowing water is observed during the sampling event. Samples will be collected in accordance with the US EPA SESD's Surface Water Sampling Operating Procedures (December 2021). Surface Water Monitoring Location Unit(s) Monitored Point Identification SW-1 Upstream (Second Creek) MSW/C&D 16 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� References Surface Water Monitoring Location Unit(s) Monitored Point Identification SW-2 Downstream (Second Creek) MSW/C&D SW-3 Downstream (Unnamed Tributary) MSW SW-4 Downstream (Unnamed Tributary) MSW SW-5 Downstream (Second Creek) C&D The surface water monitoring points will be sampled semi-annually for analysis of NC Appendix I constituents, and pH, specific conductivity, and temperature. The results of the analysis of the surface water data will be submitted to the SWS at least semi-annually in conjunction with the groundwater data. Data will be compared to applicable NC surface water standards, and those comparisons will be included with each submittal. 7 References The references cited below were used in the preparation of this report and may or may not be referenced in the text. Butler, R.J., and Secor, Jr., D.T., 1991, The Central Piedmont, in Horton, J. W., Jr., and Zullo, V.A., eds., The Geology of the Carolinas: The University of Tennessee Press, pp. 59-78. Buxton Environmental, Inc., September 2011, Design Hydrogeologic Report, Proposed Phase IV Landfill. Subtitle D Municipal Solid Waste Landfill Expansion, Rowan County Landfill. HDR Engineering of the Carolinas, Inc., August 2022, Design Hydrogeologic Report, Proposed Phase V Landfill. Subtitle D Municipal Solid Waste Landfill Expansion, Rowan County Landfill. Golder Associates NC, Inc., March 2020. Water Quality Monitoring Report, First Semi - Annual 2020 Sampling Event, Active Rowan County Landfill, Permit No. 80-03, Rowan County, Golder Associates NC, Inc., August 2021. Water Quality Monitoring Report, Second Semi - Annual 2021 Sampling Event, Active Rowan County Landfill, Permit No. 80-03, Rowan County, North Carolina. NCGS, 1985. Geologic Map of North Carolina. Scale1:500,000. S&ME, October 2005. Water Quality Monitoring Plan —Rowan County Landfill, Woodleaf, NC. US EPA. 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. Puls, Robert W. and Barcelona, Michael J. US EPA. 1993. Region III Modifications to Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, EPA 540/R-01-008. April. US EPA, 1994. Region III Modifications to National Functional Guidelines for Organic Data Review Multi -Media, Multi -Concentration (OLMO1.0-OLMO0.9), EPA 540/R-99-008. September. US EPA. 1986. RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD). US EPA Region 4, 2008. Science and Ecosystem Support Division Design and Installation of Monitoring Wells. February. 17 Rowan County Landfill i Phase V Construction Permit Application — Water Quality Monitoring Plan ��� References US EPA Region 4, 2020. Science and Ecosystem Support Division Field Equipment Cleaning and Decontamination. June. US EPA Region 4, 2017. Science and Ecosystem Support Division Groundwater Sampling Operating Procedures. April. US EPA Region 4, 2020. Science and Ecosystem Support Division Management of Investigation Derived Waste. May. US EPA Region 4, 2021. Science and Ecosystem Support Division Surface Water Sampling Operating Procedures. December. US EPA. 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, EPA 530-R-09-007. March. US EPA. June 1997. SW-846 Methods for Evaluating Solid Waste, Physical/Chemical Methods, Final Update VII (June 2022). 18 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Professional Certification 8 Professional Certification The Water Quality Monitoring Plan for the Rowan County active MSW and closed C&D units at this facility has been prepared by a qualified geologist who is licensed to practice in the State of North Carolina. The plan has been prepared based on first-hand knowledge of site conditions and familiarity with North Carolina solid waste rules and industry standard protocol. This certification is made in accordance with North Carolina Solid Waste Regulations, indicating this Water Quality Monitoring Plan should provide early detection of any release of hazardous constituents to the uppermost aquifer, so as to be protective of public health and the environment. No other warranties, expressed or implied, are made. HDR En the Carolinas, Inc. •��q'�,GEWSFp�y • • a r k FIL Mark Filardi, 1886) Southeast Remediation Lead Not valid unless this document bears the seal of the above -mentioned licensed professional. Engineering Lic. No. F-0116 /Geology Lic. No. C-503 19 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Professional Certification This page intentionally left blank. 20 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Tables Tables Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Tables This page intentionally left blank. August 2022 Table 1 Summary of Groundwater Monitoring Well Construction Information Rowan County Landfill (Active MSW and Closed C&D Facilities) Permit No. 80-03 Well Identification Northing Easting Date of Construction Ground Surface Elevation ft AMSL TOC Elevation (ft AMSL) Well Depth (ft bgs) Well Diameter (inches) Screened Interval (ft AMSL) Geology of Screened Interval Well Type MW-1 1536611.82 733038.15 715.00 717.50 27.0 2 690.50 - 700.50 Partially Weathered Rock MSW Compliance Monitoring Point MW-6 1538418.99 732034.90 665.55 668.15 53.7 2 614.45 - 619.45 Water Level Only MW-7 1538340.33 731108.57 660.60 663.14 28.5 2 634.64 - 644.64 MSW Compliance Monitoring Point MW-9 1536844.42 733960.05 698.63 738.13 39.5 2 698.63 - 708.63 MSW Compliance Monitoring Point MW-11 1538285.50 732876.62 680.94 683.27 23.9 2 659.32 - 669.32 MSW Compliance Monitoring Point MW-12 1538299.11 733113.18 682.94 685.88 22.6 2 663.28 - 673.28 MSW Compliance Monitoring Point MW-13 1538303.87 733395.18 694.31 696.33 24.5 2 671.80 - 681.80 MSW Compliance Monitoring Point MW-16 1539006.79 734292.09 750.50 752.69 56.7 2 695.99 - 705.99 MSW Compliance Monitoring Point MW-17 1539992.75 733886.30 752.42 755.36 55.0 2 697.42 - 712.42 C&D Compliance Monitoring Point MW-18R 1540067.64 732809.77 07/24/07 658.30 661.39 30.0 2 628.30 - 643.30 Saprolite/PWR C&D Compliance Monitoring Point MW-19 1540348.55 732908.08 - 650.47 653.45 20.0 2 630.47 - 645.47 C&D Compliance Monitoring Point MW-20 1536619.71 732537.54 04/05/05 713.90 717.00 33.0 2 680.9 - 695.9 Saprolite/PWR MSW Compliance Monitoring Point MW-23 1537990.80 732183.59 04/08/05 1 694.29 697.25 38.5 2 655.79 - 670.79 Saprolite MSW Compliance Monitoring Point MW-23A 1537990.80 732173.30 04/11/05 693.82 696.91 68.5 2 625.32 - 640.32 PWR Water Level Only MW-24R 1537954.02 732801.79 04/12/11 714.39 717.10 43.6 2 686.39 - 671.39 Saprolite/PWR MSW Compliance Monitoring Point MW-25 1536603.20 731757.27 04/15/11 704.98 707.46 40.6 2 679.42 - 664.42 MSW Compliance Monitoring Point MW-26 1537383.59 731382.04 04/21/11 694.80 697.30 38.9 2 670.88 - 655.88 MSW Compliance Monitoring Point* MW-27 1538076.45 731358.39 04/26/11 661.46 663.90 18.5 2 657.96 - 642.96 MSW Compliance Monitoring Point MW-27A 1538084.39 731350.62 04/25/11 661.27 664.02 64.3 2 602.27 - 597.27 Water Level Only MW-28 1538097.33 731753.26 04/26/11 679.23 682.03 26.2 2 668.02 - 653.02 Water Level Only MW-28R 731882.07 1538013.18 07/11/17 683.04 685.26 35.3 2 666.04 - 651.04 MSW Compliance Monitoring Point MW-30 730616.08 1538120.74 09/20/21 653.10 656.15 24.3 2 641.82 - 631.82 Saprolite/PWR MSW Compliance Monitoring Point MW-31 730729.74 1537399.50 09/22/21 667.69 670.12 23.8 2 656.36 - 646.36 MSW Compliance Monitoring Point MW-32 730774.20 1537037.41 09/22/21 663.69 666.16 25.1 2 651.08 - 641.08 MSW Compliance Monitoring Point MW-33 731038.18 1536789.87 09/23/21 680.64 683.19 32.6 2 660.59 - 650.59 MSW Compliance Monitoring Point MW-34 731468.50 1 1536632.93 10/01/21 702.06 704.75 46.9 2 667.83 - 1 MSW Compliance Monitoring Point Notes: ft AMSL = feet above mean sea level MW-26 to be abandoned immediately prior to Phase V construction ft bgs = feet below ground surface TOC = Top of Well Casing Elevation Monitoring wells MW-6, MW-27A, and MW 28 are monitored for water levels only. FN Page 1 of 1 This page intentionally left blank. Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Figures Figures Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Figures This page intentionally left blank. 1 V 3 M 5 R N OLD EXISTING LANDFILL SEDIMENT ENTRANCE BASIN r — — — — — — — — , — -- 00 00 00 AW- d d MWIW-4 00 - - - 00 MMW-5A I I �� ) ��� 00.■ 00 I ' PHABE I ■ I y, , I III LA DF71 ■' ►�`1 Irtew EXISTING 00, I SEDIMENTS ,00 BASIN I _� ■ ■ 1 MW-1E 1 702$� 1 �- 1 ■... ■ -6A ■0ofo 00 ou OA J ...:. 69 I I s$ -sow 00 I 00 I -MMW-7.. j , `._._. r - ■ � •-.^,�"�� �; i 1 00 T( I �. ....... it f oo �. MW-250�' hBW LAIyDR.L - o 6703j3► _ � y j FUTURE MSW LANDFILL MW-33 _ (PHASE V) 1 O a MW-32 O mow_ 1, HDR Engineering, Inc. of the Carolinas N.C.B.E.L.S. License Number: F-0116 440 S Church Street, Suite 1200 Charlotte, NC 28202-2075 704.338.6700 SCALE HOUSE 706.42 PROPERTY `•` .. 1�= f LINE ❑ 1010 2A o 1---- �� l ' � 'ram -�r _ •; : f �� � -. MW-2 --- dMW-17 MEN 706.07 00 CR go,00 00 lol low 00 1 08/2022 ISSUED FOR APPROVAL ISSUE DATE DESCRIPTION r• I Ai r t= 1 z I TO SW-1 (SEE NOTE 6) i� PROJECT MANAGER P. WESTMORELAND, PE PROJECT ENGINEER P. WESTMORELAND, PE DESIGNER N. HAREDY, El DRAWN BY J. GAUL LEGEND EXISTING TOPOGRAPHIC CONTOUR — — FACILITY BOUNDARY — — — APPROXIMATE LIMITS OF WASTE — — — — — 650 GROUNDWATER SURFACE CONTOURS APPROXIMATE GROUNDWATER FLOW SEGMENT USED TO CALCULATE GRADIENT 0647,56 EXISTING GROUNDWATER MONITORING WELL WITH GROUNDWATER ELEVATION ❑SW-4 SURFACE WATER MONITORING POINT COMPLIANCE METHANE MONITORING POINT ASSESSMENT METHANE MONITORING POINT NM NOT MEASURED 0 FRENCH DRAIN MONITORING POINT NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET, 2, GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET, 3. GROUNDWATER ELEVATIONS MEASURED ON JANUARY 16, 2020. 4, GROUNDWATER CONTOURS ARE BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL GROUNDWATER CONDITIONS. 5- GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL. THE GROUNDWATER FLOW DIRECTION IS GENERALLY PERPENDICULAR TO THE GROUNDWATER SURFACE CONTOURS, SIMILAR TO THE RELATIONSHIP BETWEEN SURFACE WATER FLOW AND TOPOGRAPHIC CONTOURS. 6. SURFACE WATER MONITORING POINT SW-1 IS APPROXIMATELY 550 FEET OFF THE MAPPING LIMITS SHOWN AND IS COLLECTED FROM SECOND CREEK. 7. MONITORING WELLS MW-27A, MW-28 AND MW-6 ARE UTILIZED FOR WATER LEVEL MONITORING ONLY. 8. THE LOCATION OF THE FRENCH DRAIN MONITORING POINT 13 APPROXIMATE. 9. MW-28R WAS INSTALLED JULY 11, 2017 TO REPLACE MW-28. MW-28 WILL CONTINUE TO BE UTILIZED FOR WATER LEVEL MONITORING. REFERENCE 1. EXISTING CONDITIONS INSIDE OF DASHED LINE COMPILED BY CARTOGRAPHIC AERIAL MAPPING, INC- USING PHOTOGRAMMETRIC METHODS, FROM AERIAL PHOTOGRAPHY DATED JUNE 26, 2020- EXISTING CONDITIONS OUTSIDE OF DASHED LINE PROVIDED BY S&ME ENGINEERING, INC., DATE UNKNOWN. 0 250 500 SITE LOCATION MAP SCALE FEET 1 11 _ 1 a,ono} cod Salisbury ROWAN COUNTY LANDFILL PHASE V CONSTRUCTION PERMIT APPLICATION NOTES: 1. INFORMATION SHOWN IN THIS DRAWING DEVELOPED FROM A GOLDER ASSOCIATES NC, INC DRAWING DATED 11-04-2020. MONITORING WELLS MW-30 TO MW-34, ASSOCIATED WITH PHASE V, COMMENCED WATER LEVEL MONITORING IN NOVEMBER 2021 AND IS CURRENTLY MEASURED MONTHLY. THIS DATA HAS BEEN REPORTING IN THE HDR HYDRO -GEOLOGICAL INVESTIGATION REPORT, AUGUST 2022. WATER QUALITY MONITORING PLAN 0 1" 2" FILENAME I WATER QUALITY MONITORING PLAN.DWGI SHEET SCALE I AS SHOWN 1 IC C w PROJECT NUMBER 110337481 PROTECTIVE CASING WITH LOCK 1/4" WEEP HOLE SURVEYOR'S PIN (FLUSH MOUNT) CONCRETE WELL APRON GROUND MINIMUM 2'x2' SQUARE PAD SURFACE 0.5" 47, o a SLOPED TO DRAIN o CONTINUOUS POUR CONCRETE v ' a v CAP AND WELL APRON I v v ev CEMENT AND SODIUM BENTONITE MIXTURE WELL DIAMETER 2" PVC THREADED BOREHOLE DIAMETER 6" MINIMUM BENTONITE LAYER (2' MIN.) = FILTER PACK 20-40 SAND (2' OR LESS ABOVE SCREEN) _ - = POTENTIOMETRIC SURFACE - SCREENED INTERVAL 0.010 INCH = SLOT MANUFACTURED SCREEN BOTTOM CAP TYPICAL GROUNDWATER MONITORING WELL SCHEMATIC ROWAN COUNTY ACTIVE AND CLOSED LANDFILLS PERMIT NO. 80-03 ROWAN COUNTY, NORTH CAROLINA DATE 08/12/2022 FIGURE 2 Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Figures AppendixA— Regulatory Requirements Rowan County Landfill I Phase V Construction Permit Application — Water Quality Monitoring Plan ��� Figures This page intentionally left blank. DENR USE ONLY ❑Paper Report [:]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: E-mail: Phone: NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? B No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Facility Representative Name (Print) Title (Area Code) Telephone Number Signature Facility Representative Address Date Affix NC Licensed/ Professional Geologist Seal NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 NC Solid Waste Section Environmental Monitoring List NC Solid Waste Section Environmental Monitoring Groundwater Protection Compliance Standards - Constituents List (updated April 11, 2022) All units are ug/L unless otherwise noted. NE = Not Established Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 2L 2L IMAC MCL GWP Std Reference List 4 67-64-1 3 Acetone Acrylonitrile 6000 NE NE NE NE NE Appendix1 NE NE Appendix 1 107-13-1 8 7440-36-0 13 Antimony 1 NE 6 NE Appendix I 7440-38-2 14 Arsenic 30 NE 10 NE Appendix 1 7440-39-3 15 Barium 700 NE 2000 NE Appendix 1 71-43-2 16 Benzene 1 NE 5 NE Appendix1 7440-41-7 23 Beryllium 4 NE 4 NE Appendix I 74-97-5 28 Bromochloromethane; Chlorobromethane NE I NE NE 0.6 Appendix 1 75-27-4 29 Bromodichloromethane; Dibromochloromethane 0.6 NE 80 NE Appendix 1 75-25-2 30 Bromoform; Tribromomethane 4 NE 80 NE Appendix I 7440-43-9 34 Cadmium 2 NE 5 NE Appendix I 75-15-0 35 Carbon disulfide 700 NE NE NE Appendix 1 56-23-5 36 Carbon tetrachloride 0.3 NE 5 NE Appendix 1 108-90-7 39 Chlorobenzene 50 NE 100 NE Appendix 1 75-00-3 41 Chloroethane; Ethyl chloride 3000 NE NE NE Appendix1 67-66-3 44 Chloroform; Trichloromethane 70 NE 80 NE Appendix 1 7440-47-3 51 Chromium 10 NE 100 NE Appendix 1 7440-48-4 53 Cobalt 1 NE NE NE Appendix 1 7440-50-8 54 Copper 1000 NE 1300 NE AppendixI 124-48-1 66 Dibromochloromethane; Chlorodibromomethane 0.4 NE 80 NE Appendix 1 96-12-8 67 1,2-Dibromo-3-chloropropane; DBCP 0.04 NE 0.2 NE Appendix 1 106-93-4 68 1,2-Dibromoethane; Ethylene dibromide; EDB 0.02 NE 0.05 NE Appendix I 95-50-1 69 o-Dichlorobenzene; 1,2-Dichlorobenzene 20 NE 600 NE Appendix1 106-46-7 71 p-Dichlorobenzene; 1,4-Dichlorobenzene 6 NE 75 NE Appendix 1 110-57-6 73 trans-1,4-Dichloro-2-butene NE NE NE NE Appendix 1 75-34-3 75 1,1-Dichloroethane; Ethyldidene chloride 6 NE NE NE Appendix I 107-06-2 76 1 1,2-Dichloroethane; Ethylene dichloride 0.4 NE 5 NE Appendix 1 75-35-4 77 1 1,1-Dichloroethylene; 1,1-Dichloroethene; 350 NE 7 NE Appendix I Page 1 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 156-59-2 78 Vinylidene chloride cis-1,2-Dichloroethylene; cis-1,2- Dichloroethene 70 NE 70 NE Appendix 1 156-60-5 79 trans-1,2-Dichloroethylene;trans-1,2-Dichloroethene 100 NE 100 NE AppendixI 78-87-5 82 1,2-Dichloropropane 0.6 NE 5 NE Appendix I 10061-01-5 86 cis-1,3-Dichloropropene 0.4 NE I NE NE Appendix 1 10061-02-6 87 trans-1,3-Dichloropropene 0.4 NE NE NE Appendix I 100-41-4 110 Ethylbenzene 600 NE 700 NE Appendix 1 591-78-6 124 2-Hexanone; Methyl butyl ketone 40 NE NE NE Appendix 1 7439-92-1 131 Lead 15 NE 15 NE Appendix1 74-83-9 136 Methyl bromide; Bromomethane 30 NE NE NE Appendix I 74-87-3 137 Methyl chloride; Chloromethane 3 NE NE NE Appendix 1 74-95-3 139 Methylene bromide; Dibromomethane NE 70 1 NE NE Appendix 1 75-09-2 140 Methylene chloride; Dichloromethane 5 NE 5 NE Appendix I 78-93-3 141 Methyl ethyl ketone; MEK; 2-Butanone 4000 NE NE NE Appendix 1 74-88-4 142 Methyl iodide; Iodomethane NE NE NE NE Appendix 1 108-10-1 147 4-Methyl-2-pentanone; Methyl isobutyl ketone 100 NE I NE NE Appendix I 7440-02-0 152 Nickel 100 NE NE NE Appendix 1 7782-49-2 183 Selenium 20 NE 50 NE Appendix I 7440-22-4 184 Silver 20 NE NE NE Appendix 1 100-42-5 186 Styrene 70 NE 1 100 NE Appendix 1 630-20-6 190 1,1,1,2-Tetrachloroethane 1 NE NE I NE Appendix 1 79-34-5 191 1,1,2,2-Tetrachloroethane 0.2 NE NE NE Appendix I 127-18-4 192 Tetrachloroethylene; Tetrachloroethene; Perchloroethylene 0.7 NE 5 NE Appendix 1 7440-28-0 194 Thallium 2 NE 2 NE Appendix I 108-88-3 196 Toluene 600 NE 1000 NE Appendix 1 71-55-6 200 1,1,1-Trichloroethane; Methylchloroform 200 NE 200 NE Appendix 1 79-01-6 201 Trichloroethylene; Trichloroethene 3 NE 5 NE Appendix I 79-00-5 202 1,1,2-Trichloroethane 0.6 NE 5 NE Appendix 1 75-69-4 203 Trichlorofluoromethane; CFC-11 2000 NE NE NE Appendix 1 96-18-4 206 1,2,3-Trichloropropane 0.005 NE NE NE Appendix 1 7440-62-2 209 Vanadium 7 NE NE NE Appendix 1 108-OS-4 210 1 Vinyl acetate NE 88 1 NE I NE Appendix 1 75-01-4 211 1 Vinyl chloride; Chloroethene 0.03 NE 1 2 1 NE Appendix I Page 2 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 7440-66-6 213 Zinc 1000 NE NE NE Appendix 1 1330-20-7 346 Xylene (total) S00 NE 10000 NE Appendix I 83-32-9 1 Acenaphthene 80 NE I NE NE Appendixll 208-96-8 2 Acenaphthylene 200 NE NE NE Appendix II 75-05-8 4 Acetonitrile; Methyl cyanide NE NE NE NE Appendix II 98-86-2 5 Acetophenone 700 NE NE NE Appendix II 53-96-3 6 2-Acetylaminofluorene; 2-AAF NE NE NE NE Appendix II 107-02-8 7 Acrolein 4 NE NE NE Appendix II 309-00-2 9 Aldrin 0.002 NE NE NE Appendix II 107-05-1 10 Allyl chloride NE NE NE NE Appendix II 92-67-1 11 4-Aminobiphenyl NE NE NE NE Appendix II 120-12-7 12 Anthracene 2000 NE NE NE Appendixll 56-55-3 17 Benzo[a]anthracene; Benzanthracene O.OS NE NE NE Appendix II 205-99-2 18 Benzo[b]fluoranthene O.OS NE NE NE Appendix II 207-08-9 19 Benzo[k]fluoranthene O.S NE NE NE Appendix II 191-24-2 20 Benzo[ghi]perylene 200 NE NE NE Appendix II 50-32-8 21 Benzo[a]pyrene O.00S NE 0.2 NE Appendix II 100-51-6 22 Benzyl alcohol 700 NE NE NE Appendix II 319-84-6 24 alpha-BHC NE 0.006 NE NE Appendix II 319-85-7 25 beta-BHC NE 0.02 1 NE NE Appendix II 319-86-8 26 delta-BHC NE NE NE 0.019 Appendix II 58-89-9 27 gamma-BHC; Lindane 0.03 NE 0.2 NE Appendix II 101-55-3 31 4-Bromophenyl phenyl ether NE NE NE NE Appendix II 85-68-7 32 Butyl benzyl phthalate; Benzyl butyl phthalate 1000 NE I NE NE Appendix II 84-74-2 33 Di-n-butyl phthalate 700 NE NE NE Appendix II 106-47-8 38 p-Chloroaniline NE NE NE NE Appendix II 510-15-6 40 Chlorobenzilate NE NE NE NE Appendix II 111-91-1 42 Bis(2-chloroethoxy)methane NE NE I NE NE Appendix II 111-44-4 43 Bis(2-chloroethyl)ether; Dichloroethyl ether NE NE NE 0.031 Appendix II 59-50-7 45 p-Chloro-m-cresol; 4-Chloro-3-methyl phenol NE NE NE NE Appendix II 108-60-1 46 Bis(2-chloro-l-methylethyl) ether; 2,2'- Dichlorodiisopropyl ether; DCIP NE NE NE NE Appendix II 91-58-7 47 2-Chloronaphthalene NE NE NE NE Appendix II Page 3 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 95-57-8 48 2-Chlorophenol 0.4 NE NE NE Appendix II 7005-72-3 49 4-Chlorophenyl phenyl ether NE NE NE NE Appendix II 126-99-8 50 Chloroprene NE NE I NE NE Appendix II 218-01-9 52 Chrysene 5 NE NE NE Appendix II 95-48-7 56 o-Cresol; 2-Methylphenol 400 NE NE NE Appendix II 57-12-5 58 Cyanide 70 NE 200 NE Appendix II 94-75-7 59 2,4-D; 2,4-Dichlorophenoxyacetic acid 70 NE 1 70 NE Appendix II 72-54-8 60 4,4'-DDD 0.1 NE NE NE Appendix II 72-55-9 61 4,4'-DDE NE NE NE NE Appendix II 50-29-3 62 4,4'-DDT 0.1 NE NE I NE Appendix II 2303-16-4 63 Diallate NE I NE NE NE Appendix II 53-70-3 64 Dibenz[a,h]anth racene 0.005 NE NE NE Appendix II 132-64-9 65 Dibenzofuran 28 NE NE NE Appendix II 541-73-1 70 m-Dichlorobenzene; 1,3-Dichlorobenzene 200 NE NE NE Appendix II 91-94-1 72 3,3'-Dichlorobenzidine NE I NE NE NE Appendix II 75-71-8 74 Dichlorodifluoromethane; CFC 12 1000 NE NE NE Appendix II 120-83-2 80 2,4-Dichlorophenol 0.98 NE NE I NE Appendix II 87-65-0 81 2,6-Dichlorophenol NE NE NE NE Appendix II 142-28-9 83 1,3-Dichloropropane; Trimethylene dichloride NE NE NE NE Appendix II 594-20-7 84 2,2-Dichloropropane; Isopropylidene chloride NE NE NE NE Appendix II 563-58-6 85 1,1-Dichloropropene NE NE NE NE Appendix II 60-57-1 88 Dieldrin 0.002 NE NE NE Appendix II 297-97-2 89 O,O-Diethyl 0-2-pyrazinyl phosphorothioate; Thionazin NE NE NE NE Appendix II 84-66-2 90 Diethyl phthalate 6000 NE NE NE Appendix II 60-51-5 91 Dimethoate NE NE NE NE Appendix II 60-11-7 92 p-(Dimethylamino)azobenzene NE NE NE NE Appendix II 57-97-6 93 7,12-Dimethylbenz[a]anthracene NE NE NE NE Appendix II 119-93-7 94 3,3'-Dimethylbenzidine NE NE NE NE Appendix II 105-67-9 95 2,4-Dimethylphenol; m-Xylenol 100 NE NE NE Appendix II 131-11-3 96 Dimethyl phthalate NE NE NE NE Appendix II 99-65-0 97 m-Dinitrobenzene NE NE NE NE Appendix II 534-52-1 98 4,6-Dinitro-o-cresol; 4,6-Dinitro-2-methyl phenol NE NE NE NE Appendix II Page 4 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 51-28-5 99 2,4-Dinitrophenol NE NE NE NE Appendix II 121-14-2 100 2,4-Dinitrotoluene 0.05 NE NE NE Appendix II 606-20-2 101 2,6-Dinitrotoluene NE NE I NE NE Appendix II 88-85-7 102 Dinoseb; DNBP; 2-sec-Butyl-4,6-dinitrophenol 7 NE 7 NE Appendix II 122-39-4 103 Diphenylamine NE NE NE NE Appendix II 298-04-4 104 Disulfoton 0.3 NE NE NE Appendix II 959-98-8 105 Endosulfan 1 40 NE NE NE Appendix II 33213-65-9 106 Endosulfan 11 NE NE NE 42 Appendix II 1031-07-8 107 Endosulfan sulfate 40 NE NE NE Appendix II 72-20-8 108 Endrin 2 NE 2 NE Appendix II 7421-93-4 109 Endrin aldehyde 2 NE NE NE Appendix II 117-81-7 111 Bis(2-ethylhexyl) phthalate 3 NE NE NE Appendix II 97-63-2 112 Ethyl methacrylate NE NE NE NE Appendix II 62-50-0 113 Ethyl methanesulfonate NE NE NE NE Appendix II 52-85-7 114 Famphur NE NE NE NE Appendix II 206-44-0 115 Fluoranthene 300 NE NE NE Appendix II 86-73-7 116 Fluorene 300 NE NE NE Appendix II 76-44-8 117 Heptachlor 0.008 NE 0.4 NE Appendix II 1024-57-3 118 Heptachlor epoxide 0.004 NE 0.2 NE Appendix 11 118-74-1 119 Hexachlorobenzene 0.02 NE 1 NE Appendix II 87-68-3 120 Hexachlorobutadiene 0.4 NE NE NE I Appendix II 77-47-4 121 Hexachlorocyclopentadiene NE NE 50 50 Appendix II 67-72-1 122 Hexachloroethane NE NE NE 2.5 Appendix II 1888-71-7 123 Hexachloropropene NE NE I NE NE Appendix II 193-39-5 125 Indeno(1,2,3-cd)pyrene 0.05 NE NE NE Appendix II 78-83-1 126 Isobutyl alcohol NE NE NE NE Appendix II 465-73-6 127 Isodrin NE NE NE NE Appendix II 78-59-1 128 Isophorone 40 NE NE NE Appendix II 120-58-1 129 Isosafrole NE NE NE NE Appendix II 143-50-0 130 Kepone NE NE NE NE Appendix II 7439-97-6 132 Mercury 1 NE 2 NE I App. II/C&D 126-98-7 133 Methacrylonitrile NE NE NE NE I Appendix II Page 5 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 91-80-5 134 Methapyrilene NE NE NE NE Appendix II 72-43-5 135 Methoxychlor 40 NE NE NE Appendix II 56-49-5 138 3-Methylcholanthrene NE NE I NE NE Appendix II 80-62-6 143 Methyl methacrylate 2S NE NE NE Appendix II 66-27-3 144 Methyl methanesulfonate NE NE NE NE Appendix II 91-57-6 145 2-Methyl naphthalene 30 NE NE NE Appendix II 298-00-0 146 Methyl parathion; Parathion methyl NE NE NE NE Appendix II 91-20-3 148 Naphthalene 6 NE NE NE Appendix II 130-15-4 149 1,4-Naphthoquinone NE NE NE NE Appendix II 134-32-7 150 1-Naphthylamine NE NE NE NE Appendix II 91-59-8 151 2-Naphthylamine NE NE NE NE Appendix II 99-09-2 153 m-Nitroaniline; 3-Nitroaniline NE NE NE NE Appendix II 88-74-4 154 o-Nitroaniline; 2-Nitroaniline NE NE NE NE Appendix II 100-01-6 155 p-Nitroaniline; 4-Nitroaniline NE NE NE NE Appendix II 98-95-3 156 Nitrobenzene NE NE NE NE Appendix II 99-55-8 157 5-Nitro-o-toluidine NE NE NE NE Appendix II 88-75-5 158 o-Nitrophenol; 2-Nitrophenol NE NE NE NE Appendix II 100-02-7 159 p-Nitrophenol; 4-Nitrophenol NE NE NE NE Appendix II 55-18-5 160 N-Nitrosodiethylamine NE NE NE NE Appendix II 62-75-9 161 N-Nitrosodimethylamine 0.0007 NE NE NE Appendix II 924-16-3 162 N-Nitrosodi-n-butylamine NE NE NE NE Appendix II 86-30-6 163 N-Nitrosodiphenylamine NE NE NE NE Appendix II 621-64-7 164 N-Nitrosodipropylamine; N-Nitroso-N-dipropylamine; Di- n-propylnitrosamine NE NE NE NE Appendix II 10595-95-6 165 N-Nitrosomethylethalamine NE NE NE NE Appendix II 100-75-4 166 N-Nitrosopiperidine NE NE NE NE Appendix II 930-55-2 167 N-Nitrosopyrrolidine NE NE NE NE Appendix II 117-84-0 168 Di-n-octyl phthalate 100 NE NE NE Appendix II 56-38-2 169 Parathion NE NE NE NE Appendix II 1336-36-3 170 Polychlorinated biphenyls; PCBs NE 0.09 0.5 NE Appendix II 608-93-5 171 Pentachlorobenzene NE NE NE NE Appendix II 82-68-8 172 Pentachloronitrobenzene NE NE NE NE Appendix II 87-86-5 173 Pentachlorophenol 0.3 NE 1 NE Appendix II Page 6 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 62-44-2 174 Phenacetin NE NE NE NE Appendix II 85-01-8 175 Phenanthrene 200 NE NE NE Appendix II 106-50-3 176 p-Phenylenediamine NE NE NE NE Appendix II 108-95-2 177 Phenol 30 NE NE NE Appendix II 298-02-2 178 Phorate 1 NE NE NE Appendix II 23950-58-5 179 Pronamide NE NE NE NE Appendix II 107-12-0 180 Propionitrile; Ethyl cyanide NE NE NE NE Appendix II 129-00-0 181 Pyrene 200 NE NE NE Appendix II 94-59-7 182 Safrole NE NE NE NE Appendix II 93-72-1 185 Silvex; 2,4,5-TP 50 NE NE NE Appendix II 18496-25-8 187 Sulfide NE NE NE NE Appendix II 93-76-5 188 2,4,5-T; 2,4,5-Trichlorophenoxyacetic acid NE NE NE NE Appendix II 95-94-3 189 1,2,4,5-Tetrachlorobenzene 2 NE NE NE Appendix II 58-90-2 193 2,3,4,6-Tetrachlorophenol 200 NE NE NE Appendix II 7440-31-5 195 Tin 2000 NE NE NE Appendix II 95-53-4 197 o-Toluidine NE NE NE NE Appendix II 8001-35-2 198 Toxaphene 0.03 NE 3 NE Appendix II 120-82-1 199 1,2,4-Trichlorobenzene 70 NE 70 NE Appendix II 95-95-4 204 2,4,5-Trichlorophenol 63 NE NE NE Appendix II 88-06-2 205 2,4,6-Trichlorophenol 4 NE NE NE Appendix II 126-68-1 207 O,O,O-Triethyl phosphorothioate NE NE NE NE Appendix II 99-35-4 208 sym-Trinitrobenzene NE NE NE NE Appendix II 57-74-9 339 Chlordane 0.1 NE NE NE Appendix II 106-44-5 344 p-Cresol; 4-Methylphenol 40 NE NE NE Appendix II 108-39-4 345 m-Cresol; 3-Methylphenol 400 NE NE NE Appendix II 122-09-8 386 Benzeneethanamine, alpha,alpha-dimethyl i NE NE NE NE Appendix II 1746-01-6 440 2,3,7,8-TCDD; 2,3,7,8-Tetrachlorodiben zo- p-dioxin 0.0002 ng/L NE 0.03 NE Appendix II 123-91-1 422 1,4-dioxane 3 NE NE NE ALL' SW301 301 Chloride 250000 NE NE Total Dissolved Solids 500000 NE NE NE C&D SW311 311 NE C&D 14808-79-8 315 Sulfate 250000 NE NE NE C&D/Leachate SW337 337 Alkalinity NE NE NE NE C&D Page 7 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" 7439-89-6 340 Iron 300 NE NE NE C&D 7439-96-5 342 Manganese Tetrahydrofuran 50 NE NE NE C&D 109-99-9 441 NE 2000 NE NE C&D SW316 316 Biological Oxygen Demand NE NE NE NE Leachate SW317 317 Chemical Oxygen Demand NE NE NE NE Leachate SW419 419 No2/No3 (nitrate & nitrite reported together) NE NE NE NE Leachate SW437 437 Orthophosphate Phosphorus NE NE NE NE NE Leachate Leachate Leachate SW321 321 pH (lab) 7.0 NE NE NE SW324 324 SpecCond (lab) NE NE NE 226-36-8 385 1,2,5,6-Dibenzacridine NE NE NE NE Other 122-66-7 394 1,2-Diphenylhydrazine NE NE NE NE Other 87-61-6 371 1-2-3-Trichlorobenzene NE NE NE NE Other 120-36-5 352 2-(2-4-dichlorophenoxy)propionic acid NE NE NE NE Other 94-82-6 350 2-4 DB NE NE NE NE Other 110-75-8 358 2-Chloroethylvinylether NE NE NE NE Other 109-06-8 390 2-Picoline NE NE NE NE Other 56-57-5 388 4-nitroquinoline-l-oxide NE NE NE NE Other 64-19-7 416 Acetic Acid 5000 NE NE NE Other 62-53-3 381 Aniline NE NE NE NE Other 140-57-8 382 Aramite NE NE NE NE Other 12674-11-2 401 Aroclor 1016 NE NE NE NE Other 11104-28-2 402 Aroclor1221 NE NE NE NE Other 11141-16-5 403 Aroclor1232 NE NE NE NE Other 53469-21-9 404 Aroclor1242 NE NE I NE NE Other 12672-29-6 405 Aroclor1248 NE NE NE NE Other 11097-69-1 406 Aroclor1254 NE NE NE NE Other 11096-82-5 407 Aroclor 1260 NE NE NE NE Other 92-87-5 383 Benzidine NE I NE NE NE Other 7440-42-8 428 Boron 700 NE NE NE Other SW347 347 Bicarbonate (as CaCO3) NE NE NE NE Other 101-84-8 423 biphenyl ether I NE NE NE NE Other 108-86-1 360 1 Bromobenzene NE INE NE NE Other Page 8 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN Z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" SW418 418 Butyric Acid NE NE NE NE Other 7440-70-2 375 Calcium NE NE NE NE Other SW413 413 Carbon Dioxide (CO2) NE NE NE NE Other SW348 348 Carbonate (as CaCO3) NE NE NE NE Other 12789-03-6 400 Chlordane (constituents) NE NE NE NE Other 79-06-1 429 1 Acrylamide 0.008 NE NE NE Other 5103-71-9 379 Chlordane, alpha NE NE I NE NE Other 5103-74-2 378 Chlordane, beta NE NE 2 NE Other 5566-34-7 399 Chlordane, gamma NE NE NE NE Other 75-99-0 355 Dalapon 200 NE 200 NE Other SW318 318 Depth To Water (ft) NE I NE NE NE Other 1918-00-9 353 Dicamba NE NE NE NE Other SW334 334 Ferrous Iron- Dissolved NE NE NE NE Other SW427 427 Groundwater Elevation (feet) NE NE NE NE Other SW319 319 Head (ft mean sea level) NE NE NE NE Other 70-30-4 387 Hexachlorophene NE NE NE NE Other SW338 338 Hydrogen Sulfide NE NE NE NE Other SW415 415 Lactic Acid NE I NE NE NE Other SW329 329 Landfill Gas NE NE NE NE Other SW374 374 m-&p-Cresol (combined) NE NE NE NE Other 92-52-4 421 1,1-biphenyl 400 NE NE NE Other SW359 359 m-&p-Xylene (combined) NE NE NE NE Other 1563-66-2 430 Carbofuran 40 NE 40 NE Other 107-21-1 424 ethylene glycol 10000 NE NE NE Other 142-82-5 432 Heptane 400 NE NE NE Other 7439-95-4 376 Magnesium NE NE NE NE Other 94-74-6 351 MCPA NE NE NE NE Other 76-13-1 398 1,1,2-Trichlorotrifluoroethane 200000 NE NE NE Other 93-65-2 354 Mecopop, MCPP NE NE NE NE Other SW333 333 Methane- Dissolved NE NE NE NE Other 7439-98-7 397 Molybdenum NE NE NE NE Other 108-38-3 409 m-Xylene NE NE NE NE Other Page 9 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 21. 2L IMAC MCL GWP Std Reference List" SW426 426 N-nitrosodiphenylamine/diphenylamine NE NE NE NE Other SW439 439 N-Nitrosodiphenylamine/Diphenylamine NE NE NE NE Other 65-85-0 395 Benzoic Acid 30000 NE NE NE Other 39638-32-9 384 Bis(2-chloroisopropyl) ether 0.03 NE NE NE Other 59-89-2 389 N-Nitrosomorpholine NE NE NE NE Other SW309 309 Coliform (total) 1 NE 5 NE Other SW310 310 Color (color units) 15 NE NE NE Other SW336 336 Oxygen Reduction Potential (mV) NE NE NE NE Other SW313 313 Foaming Agents 500 NE NE NE Other SW314 314 Gross Alpha 15 NE NE NE Other 106-43-4 365 4-Chlorotoluene 24 NE NE NE Other 99-87-6 368 p-Cymene 25 NE NE NE Other 108-20-3 366 Isopropyl ether 70 NE NE NE Other 98-82-8 367 Isopropyl benzene 70 NE NE NE Other 76-01-7 380 Pentachloroethane NE NE NE NE Other SW335 335 Manganese- Dissolved 50 NE NE NE Other 108-67-8 373 Mesitylene (1-3-5-trimethylbenzene) 400 NE NE NE Other 7440-09-7 377 Potassium NE NE NE NE Other 1634-04-4 369 Methyl-tert-butyl ether (MTBE) 20 NE NE NE Other 104-51-8 361 n-Butylbenzene 70 NE NE NE Other SW417 417 Propionic Acid NE NE NE NE Other 106-42-3 410 p-Xylene NE NE NE NE Other 103-65-1 370 n-Propylbenzene 70 NE NE NE Other 95-49-8 364 o-Chlorotoluene 100 NE NE NE Other 110-86-1 391 Pyridine NE NE NE 7 Other SW414 414 Pyruvic Acid NE NE NE NE Other 7440-23-5 322 Sodium NE NE NE 20000 Other SW323 323 SpecCond (field) NE NE NE NE Other SW307 307 petroleum aliphatic carbon fraction class C19 - C36 10000 NE NE NE Other SW305 305 petroleum aliphatic carbon fraction class C5 - C8 400 NE NE NE Other SW306 306 petroleum aliphatic carbon fraction class C9 - C18 700 NE NE NE Other SW308 308 petroleum aromatics carbon fraction class C9 - C22 200 NE NE NE Other Page 10 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z SWS ID' DEQ Calculated CHEMICAL NAME 2L 2L IMAC MCL GWP Sid Reference List" SW320 320 pH (field) 7.0 NE NE NE Other 95-63-6 372 Pseudocumene (1-2-4-trimethylbenzene) 400 NE NE NE Other 3689-24-5 392 Sulfotep NE NE NE NE Other SW325 325 Temp (oC) NE NE NE NE Other 135-98-8 362 sec -Butyl benzene 70 NE NE NE Other SW328 328 Top Of Casing (fit mean sea level) NE NE NE NE Other SW425 425 Total BHC 0.02 NE NE NE Other SW436 436 Total Fatty Acids NE NE NE NE Other E-10195 357 Total Organic Carbon NE NE NE NE Other 98-06-6 363 tert-Butyl benzene 70 NE NE NE Other SW396 396 Total Organic Halides NE NE NE NE Other SW343 343 Total Suspended Solids NE NE NE NE Other SW411 411 Total Well Depth (ft) NE NE NE NE Other SW330 330 Turbidity NE NE NE NE Other NOTE: G WPSs as listed are current as of April 11, 2022 and are subject to change. Refer to originating sources for any changes. 1 Groundwater Protection Standard (GWPS) - For compliance purposes, the applicable GWPS is the lower of the listed standards. 2 CAS RN = Chemical Abstract Service Registry Number. For listed contituents with no CAS, the SWS ID is used. 3 SWS ID = Solid Waste Section ID. Unique ID assigned by the Section. 4 Constituents Reference Lists APPENDIX I - Constituents for Detection Monitoring per 40 CFR Part 258 (7-1-2017 Edition) APPENDIX II - List of Hazardous Inorganic & Organic Constituents per 40 CFR Part 258 (7-1-2017 Edition). Appendix 11 list includes all Appendix 1 constituents. C&D - Additional monitored constituents required for Construction & Demolition landfills (CDLFs) LEACHATE - Monitored constituents for leachate sampling as specified in permit conditions. Other - Other constituents, field testing, field measurements, or miscellaneous data that may be required by the Section. 5 ALL-1,4-Dioxane sampling required for all MSW, C&D, & Industrial landfills (active and closed) per SWS Memo dated May 29, 2018. GW Protection Standards References 2L - NC groundwater water standards per 15A NCAC 02L .0202 2L IMAC (Interim Maximum Allowable Concentrations) - Interim NC groundwater standards per 15A NCAC 02L .0202 MCL (Maximum Contaminant Level) - National primary drinking water standards per Safe Drinking Water Act under 40 CFR Part 141 NC GWP Std (NC Groundwater Protected Standard) - Groundwater value calculated by NC DEQ for constituents with no established 2L standard. Values are calculated using criteria 1 & 2 of the NC Groundwater standards and do not consider taste, odor, MCLs, MCLG, and secondary drinking water standards. 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