5802_Madison_MSWLF_March22GW_FID1695540_20220714

DENR USE ONLY ❑Paper Report [:]Electronic Data - Email CD (data loaded: Yes / No Doc/Event#:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Anchor QEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Chuck Pippin Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Madison County Closed Solid 389 Long Branch Road 58-02 .0500 March 10, 2022
Waste Facility Marshall, NC 28753
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data ❑
Surface water monitoring data
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Chuck Pippin, P.G. Project Manager
Facility Represents i Title
Signature
231 Haywood Street Asheville, North Carolina 28801
Facility Representative Address
P-1649
NC PE Firm License Number (if applicable effective May 1, 2009)
828-281-3350
(Area Code) Telephone Number
7/14/2022 Affix NC Licensed/ Professional Geologist Seal
Date
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2 'y3
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1587
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•y'9 OLO...... ,•'
Revised 6/2009

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June 2022
Madison County Closed Solid Waste Management Facility, Permit No. 58-02
Spring 2022
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

June 2022
Madison County Closed Solid Waste Management Facility, Permit No. 58-02
Spring 2022
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
Post Office Box 579
Marshall, North Carolina 28753
Chuck Pippin UPeu
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
KP�� RUal —
Katie Pressley, PG
Project Number: C21500-01.01
\\Athena\Asheville\Projects\Madison County\,-Reports\2022\01_Spring 2022\58-02_Closed\Text\5802_Madison Closed_March 2022 Semiannual Water
Quality Report.docx

TABLE OF CONTENTS
1 Introduction
2 Methods
1
2
2.1 Monitoring Well Sampling Methods...........................................................................................................2
2.1.1 Monitoring Well BG SPRING OLD.................................................................................................2
2.1.2 Monitoring Wells MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD ........... 2
2.2 Surface Water Sampling Methods................................................................................................................3
2.3 Sample Handling, Documentation, and Analysis....................................................................................3
3 Findings........................................................................................................................................5
3.1 Groundwater.........................................................................................................................................................5
3.1.1 Field Parameters..................................................................................................................................6
3.1.2 RCRA Metals..........................................................................................................................................6
3.1.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................6
3.2 Surface Water.......................................................................................................................................................7
3.2.1 Field Parameters..................................................................................................................................7
3.2.2 RCRA Metals..........................................................................................................................................8
3.2.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................8
3.3 Site Hydrogeology..............................................................................................................................................8
4 Summary......................................................................................................................................9
4.1 Future Activities................................................................................................................................................ 10
5 References
TABLES
Table 1
Table 2
FIGURES
Figure 1
Figure 2
Summary of Laboratory Analyses Performed on Samples
Summary of Detected Constituents
Site Location Map
Sample Location Map
11
Spring 2022 Semiannual
Water Quality Monitoring Report i June 2022

APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data
Sheets
Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation
Spring 2022 Semiannual
Water Quality Monitoring Report ii June 2022

ABBREVIATIONS
µg/L
micrograms per liter
µmhos/cm
micromhos per centimeter
Closed Landfill
closed municipal solid waste landfill
DEQ
North Carolina Department of Environmental Quality
DO
dissolved oxygen
DWM
Division of Waste Management
EPA
U.S. Environmental Protection Agency
IMAC
interim maximum allowable concentration
MDL
method detection limit
mg/L
milligrams per liter
MRL
method reporting limit
mV
millivolt
NCAC
North Carolina Administrative Code
NTU
nephelometric turbidity unit
ORP
oxidation-reduction potential
PVC
polyvinyl chloride
RCRA
Resource Conservation and Recovery Act
SC
specific conductivity
SU
standard unit
SWS
Solid Waste Section
TOC
top of well casing
VOC
volatile organic compound
Waypoint
Waypoint
Laboratories, Inc.
Spring 2022 Semiannual
Water Quality Monitoring Report iii June 2022

Introduction
The Madison County Solid Waste Department maintains a closed municipal solid waste landfill
(Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch Road
(State Route 1582) in Madison County, North Carolina. The site location is presented in Figure 1.
The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ)
Division of Waste Management (DWM), under Permit No. 58-02 (the permit), which requires
semiannual monitoring of groundwater and surface water quality. This report, prepared by
Anchor QEA of North Carolina, PLLC (Anchor QEA), is being submitted in accordance with monitoring
requirements for the Closed Landfill as stipulated in the permit, with regulations codified in the DEQ
Solid Waste Management Rules, Title 15A, Subchapter 13B, Section .1600 of the North Carolina
Administrative Code (15A North Carolina Administrative Code [NCAC] 1313.1600).
This report describes the first semiannual groundwater and surface water quality monitoring event
performed in 2022. The water quality monitoring network for the Closed Landfill consists of four
monitoring wells (MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background
groundwater quality sampling location (BG SPRING OLD), and two surface water sampling locations
(SW-01 OLD [upstream] and SW-02 OLD [downstream]) located along Profitt Branch (Figure 2).
Monitoring wells MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the
western part of the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower
elevations within topographic drainages in the southern part of the landfill parcel and are screened
in the upper saturated zone.
The water sample collected from background sampling location BG SPRING OLD is treated as a
groundwater sample for the following reasons:
• Groundwater does not discharge to the ground surface at the sampling point.
• Construction of the sampling point is similar to that of a temporary monitoring well and is
located upslope and upgradient of a springhead.
• The sampling point consists of a polyvinyl chloride (PVC) casing extending below ground
surface with a screened interval from which groundwater is collected and recharges.
Anchor QEA personnel attempted to contact the resident of the property owned by Ms. J.V. Edwards
(99 Log Branch Road, Marshall, North Carolina) but were unsuccessful. Because of the unsuccessful
attempt to contact Ms. Edwards, coupled with COVID-19 concerns, Anchor QEA did not collect a
sample from the residential well (DW-01 OLD) owned by Ms. Edwards during the spring 2022
sampling event. The well was last sampled in 2017 and the results were non -detect for VOCs and had
detections of barium and chromium that were below 2L standards. Anchor QEA will contact DEQ to
determine if the well can be removed from the monitoring list or request their assistance with
contacting the owner for sampling.
Spring 2022 Semiannual
Water Quality Monitoring Report 1 June 2022

2 Methods
On March 10, 2022, Anchor QEA collected five groundwater samples from the monitoring wells
(including background well BG SPRING OLD) and two surface water samples from the established
surface water locations. Sampling locations are shown in Figure 2. Water level measurements, field
parameters, and observations pertaining to water quality are included in the sampling logs in
Appendix A.
2.1 Monitoring Well Sampling Methods
Prior to groundwater sample collection from the monitoring wells, the static water level was
measured and recorded to calculate the volume of water within the well.
At each sample location, an initial round of field parameters (consisting of pH, specific conductivity
[SC], dissolved oxygen [DO], oxidation-reduction potential [ORP], turbidity, and temperature) was
measured and recorded. Water level measurements, field parameters, and observations pertaining to
water quality are included in the sampling logs in Appendix A.
2. 7.1 Monitoring Well BG SPRING OLD
Due to poor well access, which inhibited the use of pump, controller, and associated tubing for
purging the well, sampling point BG SPRING OLD was purged using a new disposable polyethylene
bailer. Following initial field parameter collection, as each consecutive well volume was removed with
the bailer, a round of groundwater field parameters was recorded.
The well was purged until a minimum of three well volumes had been removed and field parameters
had stabilized. All groundwater samples were collected by a technician wearing a new pair of non -
reactive nitrile gloves. Each sample was placed directly into laboratory -supplied sample containers.
2. 7.2 Monitoring Wells MW-01 OLD, MW-02 OLD, MW-03 OLD, and
MW-04 OLD
Monitoring wells MW-01 OLD and MW-02 OLD were purged and sampled with a peristaltic pump.
MW-03 OLD and MW-04 OLD were purged and sampled with a bladder pump. These wells were
purged using low -flow techniques in accordance with the procedures described in Low -Flow
(Minimal Drawdown) Ground -Water Sampling Procedures (Puls and Barcelona 1996).
During purging, pH, SC, DO, ORP, turbidity, and temperature were measured and recorded
approximately every 3 minutes. Well purging continued until these parameters had stabilized for
three consecutive readings. The following required stabilization criteria have been established by the
Spring 2022 Semiannual
Water Quality Monitoring Report 2 June 2022

U.S. Environmental Protection Agency (EPA) Region 4 Science and Ecosystem Support Division
Operating Procedure: Groundwater Sampling (EPA SESD 2017):
• pH values within ± 0.1 unit
• SC values within ± 5%
• Temperature, DO, and turbidity values within ± 10%
Following stabilization of these parameters, a groundwater sample was collected by a technician
wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into
laboratory -supplied sample containers.
2.2 Surface Water Sampling Methods
Surface water samples SW-01 OLD and SW-02 OLD are collected semiannually at designated
locations along Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a
westerly direction (Figure 2). The surface water sample collected at the SW-01 OLD location is
interpreted to represent surface water quality upstream of the Closed Landfill, and the surface water
sample collected at the SW-02 OLD location is interpreted to represent surface water quality
downstream of the Closed Landfill.
For the samples SW-01 OLD and SW-02 OLD, field parameters, including temperature, pH, SC, DO,
ORP, and turbidity were measured and recorded at the surface water sampling location prior to
sample collection (Appendix A). One surface water sample was collected and transferred into
laboratory -supplied sample containers by a technician wearing a new pair of non -reactive nitrile gloves.
2.3 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to water quality sampling at the
Closed Landfill sampling locations are provided in the sampling logs in Appendix A.
Following sample collection, groundwater and surface water samples were immediately placed on ice
in sample coolers for transport to Waypoint Laboratories, Inc. (Waypoint), a laboratory certified in
North Carolina and located in Charlotte, North Carolina.
Anchor QEA submitted all collected groundwater and surface water samples to Waypoint for the
following analyses:
• Appendix I volatile organic compounds (VOCs), using EPA Method 8260D
— Appendix I parameters are identified in Appendix I of the Code of Federal Regulations,
Title 40, Part 258 (40 Code of Federal Regulations 258).
• 1,4-dioxane, using EPA Method 8260DSIM
Spring 2022 Semiannual
Water Quality Monitoring Report 3 June 2022

• Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 6020B
and 7470A
- In addition to this "totals" metal analysis, if the associated turbidity was measured at a
value that exceeded 10 nephelometric turbidity units (NTU), the laboratory was
requested to filter the associated sample, run the metals analysis, and report the
dissolved metal concentrations (in addition to the total metals analysis)
• Hardness, using EPA method SM2340C-2011; surface water samples only
A summary of laboratory analyses performed on the samples is provided in Table 1. One trip blank
for groundwater and one trip blank for surface water, provided by the laboratory and stored in the
sample cooler, was analyzed for Appendix I VOCs. Proper chain -of -custody documentation
procedures were followed during collection and transport of each sample. The laboratory analytical
reports and chain -of -custody documentation are included in Appendix B.
Spring 2022 Semiannual
Water Quality Monitoring Report 4 June 2022

3 Findings
The field parameter data and laboratory analytical results for the groundwater, surface water, and
trip blank samples collected at the Closed Landfill are included in Appendices A and B, respectively,
and are also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data
Deliverable format (DEQ 2020).
All laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections are values reported by the laboratory as "below method
detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The MDL is the
minimum concentration of a substance that can be measured and reported by a laboratory
with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "Y' Qualified: A "Y' qualifier is used by the laboratory for parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that
can be accurately determined by the referenced method.
• Groundwater Quality Standards: Detected concentrations of constituents in groundwater
samples were compared to applicable North Carolina groundwater quality standards. For
most constituents, this standard is the 2L standard, defined in 15A NCAC 02L. 0202. Detected
concentrations of analytes in groundwater with no established 2L standard were compared to
the interim maximum allowable concentrations (IMAQ for Class GA and GSA groundwater (in
accordance with 15A NCAC 02L.0202). For the purposes of this report, groundwater standards
were taken from the November 1, 2021, list published by the North Carolina SWS (DEQ 2021).
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Table 2 summarizes the field parameter results and laboratory analytical results for detected
constituents. The following discussion outlines constituents detected at concentrations that
exceeded their respective groundwater quality standards or 2B standards.
3.1 Groundwater
The following sections summarize the results of field parameter and laboratory analyses of
groundwater samples collected on March 10, 2022.
Spring 2022 Semiannual
Water Quality Monitoring Report 5 June 2022

3. 7. 7 Field Parameters
A summary of the field parameter measurements follows:
• pH: The pH readings obtained from monitoring wells MW-01 OLD (6.3 standard units [SUs]),
MW-03 OLD (6.4 SU) and BG SPRING OLD (6.2 SU) were less than the range for pH (6.5 to
8.5 SU) specified in the 2L standard (Table 2). The pH readings obtained from monitoring
wells MW-02 OLD (6.8 SU) and MW-04 OLD (6.5 SU) were within the 2L standard.
• Turbidity: Turbidity in the monitoring wells ranged from 6.61 NTU in monitoring well
MW-03 OLD to an estimated value of >1,000 NTU in BG SPRING OLD and MW-01 OLD.
• DO: Measured DO values ranged from 0.45 milligrams per liter (mg/L) in MW-01 OLD to
8.97 mg/L in MW-04 OLD.
• SC: SC values ranged from 116.1 micromhos per centimeter (pmhos/cm) in BG SPRING OLD to
1,049 pmhos/cm in MW-03 OLD.
• ORP: ORP values in the monitoring wells ranged from -66.4 millivolts (mV) in MW-03 OLD to
485.2 mV in MW-02 OLD (Table 2). These parameters do not have established groundwater
quality standards.
The field parameters measured for this sampling event are generally consistent with historical data.
3. 7.2 RCRA Metals
Five metals (arsenic, barium, cadmium, chromium, and lead) were detected in groundwater samples
collected from one or more monitoring wells (Table 2). Only one of these metals, barium, was
detected at concentrations that exceeded its associated groundwater protection standard of
700 micrograms per liter (pg/L).
The exceedance occurred in the samples collected from MW-03 OLD (869 pg/L) and MW-04 OLD
(736 pg/L). Laboratory findings indicate concentrations of barium have increased slightly since the
fall 2022 sampling event. In fall 2021, barium exceedances were reported in MW-03 OLD only at
830 pg/L. Concentrations of chromium have decreased since spring 2020. In spring 2020, a
chromium exceedance was reported in BG SPRING OLD.
Samples collected from all groundwater monitoring wells were analyzed for laboratory -filtered
metals due to turbidity readings greater than 10 NTU. No analytes were detected at concentrations
greater than applicable groundwater protection standards in the samples collected and analyzed for
dissolved metals.
3. 7.3 Appendix 1 VOCs and 1,4-Dioxane
Fifteen VOCs (1,1-dichloroethane, cis-1,2-dichloroethene, 1,4-dioxane, acetone, benzene,
chlorobenzene, chloroethane, ethylbenzene, m,p-xylene, methyl ethyl ketone, o-xylene,
Spring 2022 Semiannual
Water Quality Monitoring Report 6 June 2022

tetra hyd rofura n, toluene, total xylene, and vinyl chloride) were detected in groundwater samples
collected from one or more of the Site monitoring wells (Table 2). Of the detected compounds, two
(benzene and vinyl chloride) were detected at concentrations that exceeded their associated
groundwater quality standard. A benzene concentration of 2.82 pg/L was detected in monitoring well
MW-03 OLD, exceeding benzene's 2L standard of 1 pg/L. Vinyl chloride was detected in monitoring
well MW-01 OLD at an estimated concentration of 0.307 J pg/L, which exceeded its 2L standard of
0.03 pg/L.
These low concentration VOC detections are generally consistent with recent historical data
(Anchor QEA 2020a, 2020b, 2021 a, 2021 b). For example:
• MW-01 OLD
— During the fall 2021 sampling event, vinyl chloride was reported at a concentration of
0.1.05 pg/L which is greater than its 2L standard of 0.03 pg/L, and 1,4-dioxane was
detected at a concentration of 6.47 pg/L, above its 2L standard of 3 pg/L.
— In fall 2020, 1,4-dioxane was detected in MW-01 OLD at 7 pg/L.
• MW-03 OLD
— Benzene was detected at a concentration of 2.37 pg/L in spring 2021 above its 2L
standard (1 pg/L) but was not detected during the fall 2021 sampling event.
— Benzene was detected at a concentration of 2 pg/L in spring 2020.
3.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 OLD and SW-02 OLD.
3.2.7 Field Parameters
A summary of the field parameter measurements follows:
• pH: The pH readings collected from SW-01 OLD and SW-02 OLD were 7.5 and 7.4 SU,
respectively. The readings were within the 2B standard range established at 6 to 9 SU.
• Turbidity: The turbidity readings collected from SW-01 OLD and SW-02 OLD were 32.7 and
60.1 NTU, respectively. The reading for SW-01 OLD was within the 2B standard established of
less than 50 NTU. The SW-02 OLD reading was greater than the established 2B standard. The
SW-02 OLD sample was collected following significant rain events during two preceding days,
which likely influenced the turbidity readings collected at this location.
• DO: DO readings collected from SW-01 OLD and SW-02 OLD were 10.33 and 12.96 mg/L,
respectively. The values are within the 2B standard for Class C waters (greater than or equal to
5 mg/L).
• SC: The SC measurements in SW-01 OLD and SW-02 OLD were recorded at 216.4 and
135.4 pmhos/cm, respectively.
Spring 2022 Semiannual
Water Quality Monitoring Report 7 June 2022

• ORP: The ORP values for these samples were recorded at 367.1 and 380.5 mV (Table 2). These
parameters do not have established surface water quality standards.
3.2.2 RCRA Metals
Three metals (cadmium, chromium, and lead) were detected in the surface water samples. A
concentration of lead (1.21 pg/L) was detected in surface water sample SW-02 OLD above its
2B standard of 0.97 pg/L.
Samples collected from both surface water locations were analyzed for laboratory -filtered metals due
to turbidity readings greater than 10 NTU. No analytes were detected at concentrations greater than
applicable surface water protection standards in the samples collected and analyzed for dissolved
metals.
3.2.3 Appendix 1 VOCs and 7,4-Dioxone
Acetone was detected in surface water samples SW-01 OLD and SW-02 OLD at estimated
concentrations of 2.24 pg/L and 4.99 J mg/L, respectively. These detected concentrations of acetone
in SW-01 OLD and SW-02 OLD are likely laboratory artifacts and were not reported above its
associated 2B standard of 2,000 pg/L. All other VOCs were reported at less than MDL in SW-01 OLD
and SW-02 OLD.
3.3 Site Hydrogeology
Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD,
MW-03 OLD, and MW-04 OLD, at the Closed Landfill at depths of 4.95, 6.89, 38.11, and 41.35 feet
below the top of the well casing (TOC), respectively (Appendix A).
The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit
an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the
shallow groundwater is interpreted to generally mimic topography, flowing primarily southward
toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll, with an
elevation of approximately 2,100 feet above mean sea level, and slopes downward toward
Profitt Branch.
Spring 2022 Semiannual
Water Quality Monitoring Report 8 June 2022

4 Summary
Anchor QEA completed the first semiannual water quality monitoring event of 2022 at the
Closed Landfill on March 10, 2022. Table 1 summarizes the sampling and analyses that were
performed. Table 2, the field sampling logs (Appendix A), and the Waypoint Reports of Laboratory
Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and
surface water quality at the Closed Landfill. The following is a summary of the results from the
sampling event:
• Groundwater
— Detected concentrations of barium exceeded the associated 2L standard of 700 pg/L in
the samples collected from MW-03 OLD (869 pg/L) and MW-04 OLD (736 pg/L). No
other sample locations exceeded 2L standards for metals.
— VOCs that exceeded 2L groundwater standards include the following:
• Benzene: Benzene (2.82 pg/L) was detected in the sample collected from MW-03
OLD at a concentration exceeding its associated groundwater quality standard
(21- standards) of 1 pg/L.
• Vinyl chloride: Vinyl chloride (0.307 J pg/L) was detected in the sample collected
from MW-01 OLD at an estimated concentration exceeding its associated
groundwater quality standard (21- standards) of 0.03 pg/L.
— The measured depths to groundwater in the upper saturated zone within the
topographic drainages at the landfill ranged from 4.95 to 6.89 feet below TOC. The
groundwater depths in the bedrock monitoring wells at top of the ridge ranged from
38.11 to 41.35 feet below TOC. The shallow groundwater is interpreted to generally
mimic topography, flowing primarily southward toward Profitt Branch.
• Surface Water
— In the surface water samples, lead (1.21 pg/L) was detected in SW-02 at a concentration
that exceeded its associated 2B standard of 0.97 pg/L. This exceedance was likely due to
elevated turbidity following a major rain event. SW-02 has been reported with lead
exceedances previously: in fall 1997, fall 1998, fall 2017, and spring 2020. The upstream
sample location, SW-01, was also reported with a concentration of lead greater than
2B standards in spring 2020. Metal concentrations at SW-02 will continue to be
monitored in fall 2022 to determine if the lead exceedance in Proffitt Branch is a
persistent issue.
— Estimated concentrations of acetone were detected in surface water samples SW-01
OLD (2.24 J mg/L) and SW-02 OLD (4.99 J mg/L), but the concentration was less than
the associated 2B standard (2,000 pg/L). No other VOCs were detected in the surface
water samples.
Spring 2022 Semiannual
Water Quality Monitoring Report 9 June 2022

4.1 Future Activities
Anchor QEA will continue to measure field parameters and collect water quality samples from
groundwater and surface water monitoring points associated with the Closed Landfill. Water quality
samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and
Appendix I VOCs, including 1,4-dioxane, on a semiannual basis. The next sampling event is scheduled
for October 2022.
Spring 2022 Semiannual
Water Quality Monitoring Report 10 June 2022

5 References
Anchor QEA (Anchor QEA of North Carolina, PLLC), 2020a. Fall 2020 Semiannual Water Quality
Monitoring Report. Prepared for Madison County, North Carolina. December 2020.
Anchor QEA, 2020b. Spring 2020 Semiannual Water Quality Monitoring Report. Prepared for Madison
County, North Carolina. June 2020.
Anchor QEA, 2021. Spring 2027 Semiannual Water Quality Monitoring Report. Prepared for Madison
County, North Carolina. June 2021.
DEQ (North Carolina Department of Environmental Quality), 2020. Memorandum to Solid Waste
Facility Owners and Operators/SW Directors/County Managers/Consultants/Laboratories.
Regarding: New Electronic Data Deliverable (EDD) Format. July 20, 2020.
DEQ, 2021. "Groundwater Protection Compliance Standards — Constituents List." Last modified
November 1, 2021. Available at: https:Hedocs.deq.nc.gov/WasteManagement/0/edoc/
1257181/SWS_EnviroMon itoring_Constituents_List.pdf?searchid=13f8efbl -eel 1-485a-b03f-
718f2287b271.
EPA SESD (U.S. Environmental Protection Agency Science and Ecosystem Support Division), 2017.
Operating Procedure: Groundwater Sampling. April 26, 2017.
Puls, R.W., and M.J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling
Procedures. Prepared for the U.S. Environmental Protection Agency Office of Solid Waste and
Emergency Response. EPA/540/5-95/504. April 1996.
Spring 2022 Semiannual
Water Quality Monitoring Report 11 June 2022

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Facility Permit
Well ID
Collection Date
Sample ID
Appendix I VOCs
1,4-Dioxane
RCRA Metals
EPA 8260D
EPA 8260D SIM
EPA 6020B
EPA 7470A
58-02
MW-01 OLD
3/10/2022
MW-01-OLD-20220310
X
X
X1
58-02
MW-02 OLD
3/10/2022
MW-02-OLD-20220310
X
X
X1
58-02
MW-03 OLD
3/10/2022
MW-03-OLD-20220310
X
X
X1
58-02
MW-04 OLD
3/10/2022
MW-04-OLD-20220310
X
X
X1
58-02
BG SPRING OLD
3/10/2022
BG-Spring-OLD-20220310
X
X
X1
NA
DW-01 OLD
NS
NS
NS
NS
NS
Surface Water Samples
Facility Permit
Location ID
Collection Date
Sample ID
Appendix I VOCs
1,4-Dioxane
RCRA Metals
Total Hardness
EPA 8260D
EPA 8260D SIM
EPA 6020B
EPA 7470A
EPA SM 2340C-
2011
58-02
SW-01 OLD
3/10/2022
SW-01-OLD-20220310
X
X
X
X
58-02
SW-02 OLD
311012022
SW-02-OLD-20220310
X
X
X
X
Quality Control Samples
Facility Permit
ID
Collection Date
Sample ID
Appendix I VOCs
EPA 8260D
58-02
Groundwater Trip Blank
3/10/2022
TB-MWOLD-20220310
X
58-02
Surface Water Trip Blank
3/10/2022
TB-MWOLD-20220310
X
Notes:
Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258).
A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event.
1. Additional sample for lab -filtered metals analysis was collected due to turbidity.
EPA: U.S. Environmental Protection Agency
NA: Not applicable
NS: Not sampled
RCRA: Resource Conservation and Recovery Act
SM: standard method
SIM: selective ion monitoring
VOC: volatile organic compound
Spring 2022 Semiannual Water Quality Monitoring Report Page 1 of 1
Madison County Closed Solid Waste Management Facility, Permit No. 58-02 June 2022

Table 2
Summary of Detected Constituents
Location ID
SamplelD
Sample Date
Sample Type
Matrix
X
NC2L NC2L IMAC Yj
Chemical Method (2013) (2013) NC 2B
Groundwater
Samples
Surface Water
Samples
QC Sample
QC Sample
BG SPRING OLD
MW-01 OLD
MW-02 OLD
MW-03 OLD
MW-04 OLD
SW-01 OLD
SW-02 OLD
FieldQC
FieIdQC
BG SPRING OLD-
20220310
MW-01-OLD-
20220310
MW-02-OLD-
20220310
MW-03-OLD-
20220310
MW-04-OLD-
20220310
SW-01-OLD-
20220310
SW-02-OLD-
20220310
TRIPBLANK-
MWOLD-
20220310
TRIPBLANK-
SWOLD-
20220310
3/10/2022
3/10/2022
3/10/2022
3/10/2022
3/10/2022
3/10/2022
3/10/2022
3/10/2022
3/10/2022
N
N
N
N
N
N
N
N
N
WG
WG
WG
WG
WG
WS
WS
WQ
WQ
917884.7
917267.7
917989.3
917134.3
917135.2
918644.2
916592.4
768038.1
766244.6
765984.1
766754.9
766695.2
766458.9
766226.2
Conventional Parameters
Water Level Depth (feet TOC) Field
--
--
-
4.03
4.95
6.89
38.11
41.35
--
--
Temperature (°C) Field
--
--
--
10
10.2
11.9
13.8
14
10.4
11.5
--
Dissolved oxygen (mg/L) Field
--
--
_>5.0
3.4
0.45
5.47
0.47
8.97
10.33
12.96
--
Hardness as Ca and Mg (mg/L) SM2340C
--
--
--
--
--
--
--
--
44
42
--
--
Oxidation Reduction Potential (mV) Field
--
-
--
411.2
46.4
485.2
-66.4
330.8
367.1
380.5
--
--
Turbidity (NTU) Field
--
--
<50
>1000
>1000
12.3
6.61
40.5
32.7
60.1
--
--
pH (SU) Field
6.5-8.5
6.0-9.0
6.2
6.3
6.8
6.4
6.5
7.5
7.4
--
--
Specific Conductivity ( mhos/cm) Field
--
--
116.1
417.7
236.7
1049
859
216.4
135.4
--
--
Metals (Ng/L)
Arsenic SW6020B
10
--
10
0.765 J
0.815 J
0.490 U
0.49 U
0.559 J
0.490 U
0.490 U
--
--
Barium SW6020B
700
--
21000
111
319
55.1
869
736
71.8
54.9
--
--
Cadmium SW6020B
2
--
*0.22
0.150 U
0.150 U
0.153 J
0.150 U
0.344 J
0.150 U
0.150 U
--
--
Chromium SW6020B
10
--
*36.42
8.35
1.00 U
1.00 U
1.00 U
3.26
1.62 J
3.56
--
--
Lead SW6020B
15
--
*0.97
1.78
0.500 U
0.500 U
0.500 U
1.83
0.572 J
1.21
--
--
Metals, Dissolved (Ng/L)
Arsenic SW6020B
10
--
10
0.505 J
0.490 U
0.490 U
0.490 U
0.490 U
0.490 U
0.490 U
--
--
Barium SW6020B
700
--
21000
91.3
219
56.8
621
666
67.4
51.2
-
--
Cadmium SW6020B
2
--
*0.22
0.150 U
0.150 U
0.150 U
0.150 U
0.301 J
0.150 U
0.150 U
--
--
Chromium SW6020B
10
--
*36.42
6.00
1.00 U
1.00 U
1.00 U
1.00 U
1.00 U
2.15
-
--
Lead SW6020B
15
--
*0.97
1.33
0.500 U
0.500 U
0.500 U
1.15
0.500 U
0.702 J
-
--
Volatile Organics L
1,1-Dichloroethane SW8260D
6
--
100
0.240 U
0.261 J
0.509
0.433 J
0.240 U
0.240 U
0.240 U
0.240 U
0.240 U
1,2-Dichloroethene, cis- SW8260D
70
--
720
0.200 U
1.05
0.200 U
0.200 U
0.421 J
0.200 U
0.200 U
0.200 U
0.200 U
1,4-Dioxane SW8260DSIM
3
--
80
0.139 U
2.70
0.139 U
0.139 U
0.139 U
0.139 U
0.139 U
--
--
Acetone SW8260D
6000
--
2000
2.56 J
2.27 J
1.80 U
2.13 J
3.23 J
2.24 J
4.99 J
1.80 U
1.80 U
Benzene SW8260D
1
--
51
0.180 U
0.180 U
0.180 U
2.82
0.391 J
0.180 U
0.180 U
0.180 U
0.180 U
Chlorobenzene SW8260D
50
--
800
0.190 U
1.28
0.190 U
8.89
5.15
0.190 U
0.190 U
0.190 U
0.190 U
Chloroethane SW8260D
3000
--
--
0.430 U
0.430 U
0.430 U
0.997 J
0.570 J
0.430 U
0.430 U
0.430 U
0.430 U
Ethylbenzene SW8260D
600
--
130
0.170 U
0.170 U
0.170 U
6.03
0.170 U
0.170 U
0.170 U
0.170 U
0.170 U
m,p-X lene SW8260D
500
--
420
0.420 U
0.420 U
0.420 U
0.456 J
0.552 J
0.420 U
0.420 U
0.420 U
0.420 U
Methyl ethyl ketone (2-Butanone) SW8260D
4000
--
26000
0.710 U
0.710 U
0.710 U
0.710 U
1.21 J
0.710 U
0.710 U
0.710 U
0.710 U
o-Xylene SW8260D
500
--
600
0.210 U
0.210 U
0.210 U
0.367 J
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
Tetrahydrofuran SW8260D
--
--
110000
1.50 U
1.50 U
1.50 U
1.64 J
1.50 U
1.50 U
1.50 U
1.50 U
1.50 U
Toluene SW8260D
600
--
11
0.220 U
0.220 U
0.220 U
0.274 J
0.344 J
0.220 U
0.220 U
0.220 U
0.220 U
Total Xylene SW8260D
500
--
670
0.21 U
0.21 U
0.21 U
0.823 J
0.552 J
0.21 U
0.21 U
0.21 U
0.21 U
Vinyl chloride SW8260D
0.03
--
2.4
0.770 U
0.307 J
0.770 U
0.770 U
0.770 U
0.170 U
0.170 U
0.170 U
0.170 U
Semivolatile Organics L
1,2-Dichlorobenzene SW8260D
20
--
470
0.220 U
0.220 U
0.220 U
0.220 U
0.405 J
0.220 U
0.220 U
0.220 U
0.220 U
1,4-Dichlorobenzene SW8260D
6
--
100
0.210 U
1.84
0.210 U
3.70
2.29
0.210 U
0.210 U
0.210 U
0.210 U
Spring 2022 Semiannual Water Quality Monitoring Report Page 1 of 2
Madison County Closed Solid Waste Mangaement Facility, Permit No. 58-02 June 2022

Table 2
Summary of Detected Constituents
Notes:
Detected concentration is greater than (or out of range of) NCH (2013) screening level
Detected concentration is greater than NC2L IMAC (2013) screening level
Detected concentration is greater than NC2B screening level
Bold: Detected result
Italicized: Non -detected concentration is above one or more identified screening levels
*: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department
of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017).
pg/L: micrograms per liter
213: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water
Quality Criteria for Aquatic Life and Human Health.
2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A
All nondetect results are reported at the method detection limit.
Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258
°C: degrees Celsius
ft: feet
Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (US Survey Feet).
IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L
J: Estimated value
mg/L: milligrams per liter
mv: millivolts
N: normal environmental sample
NTU: Nephelometric Turbidity Units
SU: standard units
TB: Trip Blank
TOC: top of casing
U: Compound analyzed for, but not detected above detection limit
umhos/cm: micromhos per centimeter
Spring 2022 Semiannual Water Quality Monitoring Report Page 2 of 2
Madison County Closed Solid Waste Mangaement Facility, Permit No. 58-02 June 2022

Figures

fQ
�✓ C. d- o Q ! •-
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1 ���`�� `- �+\` �-1` / -h � ,� � .� + � `' sue" • ; r
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-46
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O���.�Ij
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LEGEND: SOURCES:
Basemap: USGS 1:24,000 Scale Topo Maps,
Landfill Parcel Marshall Quadrangle, 1990 0
Parcels: Madison County GIS 0 2,000
Feet
Publish Date: 2022/04/21, 3:17 PM I User: kpressleybernal
Filepath: Q:\Jobs\Madison County_NC_1500\Maps\2022\SpringWaterQuality\AQ_F01_SiteLocationMap_ClosedLF_SpringWQ2022.mxd
kzANCHOR Figure 1
QEA�- Site Location Map
Anchor QEA of North Carolina, PLLC
Spring 2022 Semiannual Water Quality Report
Madison County Closed Solid Waste Management Facility, Permit No. 58-02

Publish Date: 2022/06/27, 1:22 PM I User: kpressleybernal
Filepath: Q:\Jobs\MadisonCounty_NC_1500\Maps\2022\Spring WaterQuality\AQ_F02_SampleLocationMap_ClosedLF_SpringWQ2022.mxd
z�? ANCHOR Figure 2
QEA-- Sample Location Map
Anchor QEA of North Carolina, PLLC
Spring 2022 Semiannual Water Quality Report
Madison County Closed Solid Waste Management Facility, Permit No. 58-02

Appendix A
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

It 1`1
.ANCHOR
QEA
Equipment Documentation and Instrument Calibration Data Sheet
Project Name: Madison COunIyQ49etl UPWR Analyst Conducting Calibration: S '
Project Number.—Cl 1500-01.01 P Date of Calibration:
Project Location: Marshall, NC Date of Field Measurements:
Facility ID or Permit # (if applicable): 58-01
LQUIVIALNI UOCUMIN[A] ION
Rental sample analysis equipment or meters used to take measurements:
Equipment Type Brand Serial Number Date of Use Rental Company
Select Turbidimeter. x Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
H 13 n Instrument Readings
Instrument Readings
cT (Hach 2100Q)
(HF Scientific Micro7PM
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
1,000 NTU
10.0 NTU
0.02 NTU
Lot #•
i
-3
Expiration Date:
n
Cal (NTPLt
'11��
Cal (NTUj^
�/f1
Cal (NJW)�
Cal (NTU):
Cal (NTU):
Cal (NT
Time:
�(J)(/,
Tim '.
Time:
Time:
Time:
fime:
Calibration
'Pre -Analysis
Res (N1
} l- [
Tin6 _,_ 0
*Pre -Analysis
Result
Time:
Verification:
Check (10 NTU):
Check (10 NTU):
.Post -Analysis
Result(��NTU/L7
Time:
•Post -Ana
Result (NTU):
Time:
Check (10 NTU):
1 • "FLe
0 Jf) L
Ckf k (10 NTU):
YSI Professional Plus Multiparameter Meter (s/n 1181111101802)
Cal Still Information
Instrument Readings
Date
Lot #
Opened
Exp. Date
Dissolved Oxygen
Initial (%):
' q0
Cal (%):
mmHg:
Temperature CQ*
Time:`'
(%saturation)
•
:o
( , A
D I Ul V
DO (Site #2,
Initial (%):
Cal (%):
mmHg:
Temperature CQ:
Time:
if a lireble)•
QC- Check: DO
Time::
1
Result (%): �
Tme: � -
�
Result (D �
Time:
Result (%):
PH 7 S.U.
Initial:
pHmV:
Cal (S.U.): O
pHmV:
Time:
report to0.1S.U.
1
'
��
PH 4 S.U.
Initial:,
pHmV:
Cal (S.U.):
pHmV: f
Time:
report to a S.U.14
,
i \
PH 10 S.U.
Initial:
pHmV: /
—
Cal (S.U.:
O
pHmV: �(�
r i I
Time:
1
report to 0.1 S.0
,
O V ,
(�
QC** pH 7 S.U.
Ti e:
Result U.): `
Time:
(
Result (S.U.):
Time:
Result (S.U.):
1
1
report to 0.7 S.U.
s }
t
Spec Cond.
Initial:
Cal (p hos/cm):
ri.�
Time:
—61
IC-1D
1,000 pmhos/cmb
V
t./ V t(,/
l
% Recovery=
QC"" Spec Cond.
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
1,000pmhos/cm
b 3
- -
% Recovery=
ORP 200 mV
Initial: 1
O 6, �
Cal:
CN o D
Temperature CC):
Time:
Analyst Signature: Analyst 11te ' Date: U
Notes:
Revision 6, 12/20/20, MAK
V
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4, *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at
each sample site prior to analysis.
5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. HOC readings are out of range, the
instrument needs to be recalibrated.
6. " QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 PS/cm
Abbreviations:
Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units
Temperature: SM 2550 B-2010
'C: degrees Celsius ORP: oxidation reduction potential
Specific conductivity. EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number
DO: SM 4500 O G-2011
mg/L: milligrams per liter S.U.: standard units
pH: SM 4500-H' B-2011
mV: millivolt Spec. Cond: Specific Conductivity
Turbidity: SM 2130 B-2011
Page 1 of 1

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ANCHOR
..�, QEA
.ow -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
ID: MW-01OLD
Project Name: Madison County Closed Landfill
Date:
Project Number: C11500-01.01 _
Weather.21
22 N 0
Project Location: Marshall, NC
Facility ID or Permit* (if applicable):
58-02
_
Sample Collector(s):
Sample ID (on COC):
MW-01 OLD- 2,
Well Diameter. 2
in Arrive at Well:
d b®
Screen Interval: N/A
ft bgs Start Time:
Well Depth (as constructed): 20.8
ft bgs Sample Time:
iv3�
Depth to Water: `+
ft Leave Well:
/U
Measuring Point: TOC
Well Type: KStick Up
❑Flush Mount
Depth of Pump Intake: 17
ft
Tagged Bottom: Q o 4 4 ft
at (time):
i,Qos
Pump Used (circle): Peristahic Bladder
Other (describe):
Purge Rate:
""?_ Zci .
Comments: PL4 fb
yt `co cI
r &—
Total Volume Purged:
y 10 <i .%t
v %✓"��S / i^
j c r� >
Pump Speed:
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature (°C)
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
Turbidity (NTU)
Z
S, Lip
1 0 ,
qo
6,3
)bl,
0DR
i 5 r 1i!
10, 7S
7 /I, / 6,3
rY/,
gog"
(oil , 76
iv,3
I,25 `f17,v 6„3
►2�r:
©6
d r qt `11w, 6IL
7c
rc'
02 7 t 01)
20, - ,
[0,33
7 (r
�,�
ttzZ,
Sample Analyst Signatur,G:.
Sample Analyst /t
Name: �� l ✓ fjLr' it
Date: %11G /,?
Notes:
1: Stabilization (3 successive readings, s minutes span): within +/-
70% DO and turbidity,' +/- 3% conductivity, +/- 0.1 pH unit,, +/- 10 mvfor ORP
from EPA - Low -Flow (Minimal Drawdown: Cre,undwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed oot with a single line, so
the original text is still legible,
followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
t�L f
�- f t r al = / t q /
`7
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
pmhos/cm: micromhos per centimeter ft: feet
Temperature: SM 2550 B-2010
mg/L: milligrams per liter in: inches -
Specific conductivity: EPA Method 120.1, Rev. 1982
mv: millivolt bgs: below ground surface
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOO top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

S'k
Ta
y� ANCHOR
.., QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
,ow -Flow Sampling Log
Well ID: MW-02 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Madison County Closed Landfill
C11500-01.01
Marshall, NC
C
2
N/A
43.4
TOC
40
Aefi,=talti Bladder
„S�_(l 1']�!1
i
Date:
Weather:
Facility ID or Permit # (if applicable):
Sample ID (on COC):
in Arrive at Well:
ft bgs Start Time:
ft bgs Sample Time:
ft Leave Well:
Well Type:
ft Tagged Bottom:
Other (describe):
to fi� u) od (jT.5 ta
3 1b "
14�, �llb�l 6 "
5858-02
MW-02 OLD-
Oq
KStick Up ❑Flush Mount
t yl < 7 ' ft at (time): (�
Purge Rate: (jej to L! py(1
Total Volume Purged:
Pump Speed: Oy
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
, ov
1
f
(a,
s.QY
q"
��i
1 "n
01
--A -1
�"
cSoI,
.
1,
Sample Analyst Signature:
°
]
Sample Analyst
Name: ��
Date:
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity,' +/- 0.7 pH unit, +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 PS/cm
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H` B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
w+� LwpeSuved
fbv Ic c fh[t�ced
to 9
Page 1 of 1

ANCHOR
.._v QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
.ow -Flow Sampling Log
Well ID: MW-03 OLD
Project Name:
Madison County Closed Landfill
Date:
.y �
Project Number:
C11500-01.01
Weather:
S- o4-
Project Location:
Marshall, NC
Facility ID or Permit # (if applicable):
58-02
Sample Collector(s):
'1L t� K
Sample ID (on COC):
MW-03 OLD-
be�a
Well Diameter.
2
in
Arrive at Well:
')_
Screen Interval:
44 - 49
ft bgs
Start Time:
—
Well Depth (as constructed):
49
ft bgs
Sample Time:
Depth to Water:
3 � . '1
ft
Leave Well:
Measuring Point:
TOC
Well Type:
RStick Up
❑Flush Mount
Depth of Pump Intake:
45
ft
Tagged Bottom:
.� y" ft
at (time):
Pump Used (circle):
Peristaltic
Bladder
Other (describe):
Purge Rate:
r Lj(j wLi Yv V-,
Comments:
i7UL. -q p �()
f{ i3 U
3 t 'f (,'X�
CA-) i 34 rS
Total Volume Purged:
r
Pump Speed:
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature ('C)
(mg/L)
(pmhos/cm)
report to 0.1 S. .1
Potential (mV)
Turbidity (NTU)
5
-5,
1
I
IDS
1
:11
119
In ici
U)
3
tq 014
4,1
0ty3
-43
d
Vfy
,
r0
0
i
0 L4 C1t
-Sq-►
d
Lo
106A
(o.-ir7?
14 i
13 r
H9
Sample Analyst Signature:
o
Sample Analyst
Name:
Y
Date:
1 a A
Notes: V
t: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbid +/- 3% Conductivnt 6 +/- 0.1 pH unit +/- 10 mV fbr ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection. J ,( w
4. NC Field Laboratory Certificate Number 5445 jam...[,
5. 1 pmho/cm = 1 pS/cm ) / "�' �C l
Abbreviations:
'C: degrees Celsius S.U.: standard units
pmhos/cm: micromhos per centimeter ft: feet
mg/L: milligrams per liter in: inches
mV: millivolt bgs: below ground surface
NTU: nephelometric turbidity units TOO top of casing
ls,c ed , N-eects �,c
Method Reference. -
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
1,
I
Page 1 of 1

IstANCHOR
QEA '
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
.ow -Flow Sampling Log
1well ID: MW-04 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Madison County Closed Landfill
C11500-01.01
Marshall, NC
2
70 - 90
90
. �'�
TOC
80
Peristaltic Bladder
pum a, i -
rV. T r
Date:
Weather:
Facility ID or Permit # (if applicable):
Sample ID (on COQ:
in Arrive at Well:
ft bgs Start Time:
ft bgs Sample Time:
ft Leave Well:
Well Type:
ft Tagged Bottom:
Other (describe):
l %1 �d
58-02
MW-04 OLD- ('
l
Z 0
3�
NStick Up ❑Flush Mount
Q U) ft at (time): ,
Purge Rate: -/ Z,5---
Total Volume Purged:
l�/ Pump Speed: d^tY 4;,6C)
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
i2Z
13,0
10, 3i
il 2—
�`io
Y
iL
R.33
V6 1
�=�,�
3 `
33,
. YLe
Sample Analyst Signature:
Sample Analyst
Name:
�' t R
l ,
,�' L/ 3 v Date:
e 12 S
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10%DO and turbidity,' +/- 3% Conductivity,, +/- 0.7 pH unit,, +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection. ' (� `! -, � i � `,� f J S _ / r c_'
4. NC Field Laboratory Certificate Number 5445 s'"� ✓U2 I i/ f✓ t C�
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
'C: degrees Celsius S.U.: standard units
pmhos/cm: micromhos per centimeter ft: feet
mg/L: milligrams per liter in: inches
mv: millivolt bgs: below ground surface
NTU: nephelometric turbidity units TOC: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Well Sampling Log
Well ID: BG SPRING OLD
Project Name:
Madison County Closed Landfill Date:
()3 i , v. 1
Project Number:
C11500-01.01
Weather.
Sq'Frvlmta
1
Project Location:
Marshall, NC
Facility ID or Permit # (if applicable):
58-02
Sample Collector(s):
r
Sample ID (on COC):
BG SPRING OLD- CP V.
I
Well Diameter:
2
in Sample Time:
1L`
Screen Interval:
N/A
ft bgs
Measuring Point:
TOC
Well Depth (WD):
14.3
ft TOC
Well Type:
AStick Up ❑Flush Mount
Water Level in Feet (WL):
L4,
ft TOC
Comments:
Length of Water Column (LWQ:
9 4 .A r
ft; (WD - WL)
One Casing Volume:
UA} ,
gallons; (LWC x WCV)
Three Casing Volumes:
l +
gallons,15�
Actual Volume Purged:
gallons
Tagged Bottom:
ft at (time):
Three Casing Volumes:
gallons
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.1fi Gal F 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft
8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft
Purge Method:
Bailer-Disp Bailer -Teflon Dedicated Pump Whale Pump Grundfos
8ailer-Disp Bailer -Teflon Dedicated Pump Whale Pump Grundfos
Other.
Other.
Sample Method:
Oxidation
Dissolved
Specific
pH (S.U.)
Reduction
Gallons
Temperature
Oxygen
Conductivity
report to 0.1
Potential
Turbidity
Reading
Time
Purged
VQ
(mg/L)
(pmhos/cm)
S.U.
(mv)
(NTU)
Comments
1
,
2
i
3
1
w
,
4
n
r
5
1 1K 1
6
C
-6 Lto
Ituil
t
7
8
9
10
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Protective Casing: Pad: Lock: Vegetation: Access:
Sample Analysts
ample
Signature:
Analysts
Date:
*�
05 pt
Name:
Notes: ,3
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity +/- 3% Conductivity, +/- 0.1 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
�a
v 0 4St� Page 1of1

ANCHOR
C..`,'`
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-01 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Comments:
Madison County Closed Landfill
C11500-01.01
Marshall, NC
OK � {
Upstream of landfill
Date:
Weather:
Facility ID or Permit # (if applicable):
Sample ID (on COQ:
SGOV, Dve*-casi
58-02
SW-01 OLD-ciba,�t,31b
Sample Method (circle
one):
Grate
Syringe
Pump
Bailer Disp.
Other:
Time
Temperature
VQ
Dissolved
Oxygen (mg/L)
Specific
Conductivity
(µmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mlo
Turbidity
(NTU)
Comments
166
� D, 3
a i cv,
co -ewd
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
}�
\J �J
1 L Glass
Other
Vegetation: {�iLY Jl� (. �LdLyl�i
Sample Analyst Signature:
Sample Analyst
Name:
Access: �(
Date: 03 110
'T Documentation errors are to be crossed out with a sinale line, so the oriainal text is still legible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
'C: degrees Celsius
pmhos/cm: micromhos per centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
�*tcvl P k -- 1 11 ��
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 198211+
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Turbiditv: SM 2130 B-2011
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-02 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Comments:
Madison County Closed Landfill
C11500-01.01
Marshall, NC
S }
Downstream of landfill
Date: . (b 3 "q
Weather: `a
�} O UaCGC i (-
Facility ID or Permit # (if applicable): 58-02
Sample ID (on COC): SW-02 OLD- J6 5t j
Sample Method (circle
one):
Grab
Syringe
Pump
Bailer Disp. Other:
Time
Temperature
VC)
Dissolved
Oxygen(mg/L)
Specific
Conductivity
(µmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
1� k
1 l 'b
`a . %o
`mot
.41
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
metap 1. o o ne
t
250 mL Plastic
i
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: Lover C b Access:
Sample Analyst Signature:
1. Documentation errors are to be crossed out with a single line, so the
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
°C: degrees Celsius
pmhos/cm: micromhos per centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Sample Analyst ,� } /y n j�{ J /� +
Name: l:U�r �� GJl1�l lif Date: Iola
I text is still leoible, followed by the staff members initials and date
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982'4
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Turbiditv: SM 2130 B-2011
A sampled dk� Oi+U '31g�6ca�t rain ,� e�e�rl �r Qae+ �,uo dcu�S
Page 1 of 1

Appendix B
Report of Laboratory Analysis and
Chain -of -Custody Documentation

Waypointo
ANALYTICAL
3/24/2022
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville, NC, 28801
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 22-074-0012
Client Project Description: Madison County Closed Landfill Spring 20
Site: 58-02
Project Number: 58-02
Dear Chuck Pippin:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/15/2022 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a,-1
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 55

Waypoint.0
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2022
North Carolina
State Program
402
12/31/2022
South Carolina
State Program
99012
07/31/2022
South Carolina
State Program
99012
12/31/2022
Page 1 of 1 00016/22-074-0012
Page 2 of 55

Waypoint.(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Sample Summary Table
Report Number: 22-074-0012
Client Project Description: Madison County Closed Landfill Spring 20
Lab No Client Sample ID Matrix Date Collected Date Received
96100
MW-01 OLD-20220310
Aqueous
03/10/2022
10:39
03/15/2022
11:50
96101
MW-02 OLD-20220310
Aqueous
03/10/2022
09:16
03/15/2022
11:50
96102
MW-03 OLD-20220310
Aqueous
03/10/2022
14:16
03/15/2022
11:50
96103
MW-04 OLD-20220310
Aqueous
03/10/2022
12:38
03/15/2022
11:50
96104
SW-01 OLD-20220310
Aqueous
03/10/2022
15:15
03/15/2022
11:50
96105
SW-02 OLD-20220310
Aqueous
03/10/2022
15:40
03/15/2022
11:50
96106
BG SPRING OLD-20220310
Aqueous
03/10/2022
16:34
03/15/2022
11:50
96107
TripBlank-MWOLD-20220310
Aqueous
03/10/2022
03/15/2022
11:50
96108
TripBlank-SWOLD-20220310
Aqueous
03/10/2022
03/15/2022
11:50
Page 3 of 55

Waypoint.
(2) 449 Springbrook
Rd, Charlotte, NC
28217
Main 704.529.6364
ANALYTICAL
www.waypointana lyti ca I som
Summary of Detected Analytes
Project:
Madison County Closed
Landfill Spring 20
Report Number:
22-074-0012
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-01
V 96100
OLD-20220310
6020B
Arsenic
0.815
pq/L
0.490
03/17/2022 20:06
J
6020B
Barium
319
Ng/L
3.40
03/17/2022 20:06
6020B
Dissolved Barium
219
pq/L
3.40
03/23/2022 16:45
8260D
Acetone
2.27
pg/L
1.80
03/22/2022 21:42
J
8260D
Chlorobenzene
1.28
pq/L
0.190
03/22/2022 21:42
8260D
1,4-Dichlorobenzene
1.84
pg/L
0.210
03/22/2022 21:42
8260D
1,1-Dichloroethane
0.261
pq/L
0.240
03/22/2022 21:42
J
8260D
cis-1,2-Dichloroethene
1.05
pg/L
0.200
03/22/2022 21:42
8260D
Vinyl Chloride
0.307
pg/L
0.170
03/22/2022 21:42
J
8260D SIM
1,4-Dioxane
2.70
pg/L
0.139
03/15/2022 16:51
MW-02
V 96101
OLD-20220310
6020B
Barium
55.1
pq/L
3.40
03/17/2022 20:38
6020B
Dissolved Barium
56.8
Ng/L
3.40
03/23/2022 16:52
6020B
Cadmium
0.153
pq/L
0.150
03/17/2022 20:38
J
8260D
1,1-Dichloroethane
0.509
Ng/L
0.240
03/22/2022 21:18
MW-03
V 96102
OLD-20220310
6020B
Barium
869
pq/L
3.40
03/17/2022 20:58
6020B
Dissolved Barium
621
Ng/L
3.40
03/23/2022 16:58
8260D
Acetone
2.13
pq/L
1.80
03/22/2022 22:32
J
8260D
Benzene
2.82
pg/L
0.180
03/22/2022 22:32
8260D
Chlorobenzene
8.89
pq/L
0.190
03/22/2022 22:32
8260D
Chloroethane
0.997
pg/L
0.430
03/22/2022 22:32
J
8260D
1,4-Dichlorobenzene
3.70
pq/L
0.210
03/22/2022 22:32
8260D
1,1-Dichloroethane
0.433
pg/L
0.240
03/22/2022 22:32
J
8260D
Ethylbenzene
6.03
pq/L
0.170
03/22/2022 22:32
8260D
Tetrahydrofuran
1.64
pg/L
1.50
03/22/2022 22:32
J
8260D
Toluene
0.274
pq/L
0.220
03/22/2022 22:32
J
8260D
o-Xylene
0.367
pg/L
0.210
03/22/2022 22:32
J
8260D
m,p-Xylene
0.456
pq/L
0.420
03/22/2022 22:32
J
8260D
Xylene (Total)
0.823
Ng/L
0.210
03/22/2022 22:32
J
MW-04
V 96103
OLD-20220310
6020B
Arsenic
0.559
pq/L
0.490
03/17/2022 21:05
J
6020B
Barium
736
Ng/L
3.40
03/17/2022 21:05
6020B
Dissolved Barium
666
pq/L
3.40
03/23/2022 17:05
6020B
Cadmium
0.344
Ng/L
0.150
03/17/2022 21:05
J
Page 4 of 55

Waypoint.
(2) 449 Springbrook
Rd, Charlotte, NC
28217
Main 704.529.6364
ANALYTICAL
www.waypointana lyti ca I som
Summary of Detected Analytes
Project:
Madison County Closed
Landfill Spring 20
Report Number:
22-074-0012
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-04
V 96103
OLD-20220310
6020B
Dissolved Cadmium
0.301
pq/L
0.150
03/23/2022 17:05
J
6020B
Chromium
3.26
Ng/L
1.00
03/17/2022 21:05
6020B
Lead
1.83
pq/L
0.500
03/17/2022 21:05
6020B
Dissolved Lead
1.15
pg/L
0.500
03/23/2022 17:05
8260D
Acetone
3.23
pq/L
1.80
03/22/2022 22:07
J
8260D
Benzene
0.391
pg/L
0.180
03/22/2022 22:07
J
8260D
Chlorobenzene
5.15
pq/L
0.190
03/22/2022 22:07
8260D
Chloroethane
0.570
pg/L
0.430
03/22/2022 22:07
J
8260D
1,2-Dichlorobenzene
0.405
pq/L
0.220
03/22/2022 22:07
J
8260D
1,4-Dichlorobenzene
2.29
pg/L
0.210
03/22/2022 22:07
8260D
cis-1,2-Dichloroethene
0.421
pq/L
0.200
03/22/2022 22:07
J
8260D
Methyl Ethyl Ketone (MEK)
1.21
pg/L
0.710
03/22/2022 22:07
J
8260D
Toluene
0.344
pq/L
0.220
03/22/2022 22:07
J
8260D
m,p-Xylene
0.552
Ng/L
0.420
03/22/2022 22:07
J
8260D
Xylene (Total)
0.552
pg/L
0.210
03/22/2022 22:07
J
SW-01
V 96104
OLD-20220310
2340C-2011
Hardness
44000
Ng/L
1140
03/18/202212:50
6020B
Barium
71.8
pq/L
3.40
03/17/2022 21:11
6020B
Dissolved Barium
67.4
Ng/L
3.40
03/23/2022 17:11
6020B
Chromium
1.62
pq/L
1.00
03/17/2022 21:11
J
6020B
Lead
0.572
Ng/L
0.500
03/17/2022 21:11
J
8260D
Acetone
2.24
pq/L
1.80
03/22/2022 22:56
J
SW-02
V 96105
OLD-20220310
2340C-2011
Hardness
42000
Ng/L
1140
03/18/202212:50
6020B
Barium
54.9
pq/L
3.40
03/17/2022 21:18
6020B
Dissolved Barium
51.2
pg/L
3.40
03/23/2022 17:18
6020B
Chromium
3.56
pq/L
1.00
03/17/2022 21:18
6020B
Dissolved Chromium
2.15
pg/L
1.00
03/23/2022 17:18
6020B
Lead
1.21
pq/L
0.500
03/17/2022 21:18
6020B
Dissolved Lead
0.702
Ng/L
0.500
03/23/2022 17:18
J
8260D
Acetone
4.99
pg/L
1.80
03/22/2022 23:21
J
BG SPRING
V 96106
OLD-20220310
6020B
Arsenic
0.765
Ng/L
0.490
03/17/2022 21:24
J
6020B
Dissolved Arsenic
0.505
pq/L
0.490
03/23/2022 17:24
J
6020B
Barium
111
Ng/L
3.40
03/17/2022 21:24
Page 5 of 55

Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca I som
Summary of Detected Analytes
Project: Madison County Closed Landfill Spring 20
Report Number: 22-074-0012
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
BG SPRING
V 96106
OLD-20220310
6020B
Dissolved Barium
6020B
Chromium
6020B
Dissolved Chromium
6020B
Lead
6020B
Dissolved Lead
8260D
Acetone
91.3
pq/L
3.40
03/23/202217:24
8.35
Ng/L
1.00
03/17/2022
21:24
6.00
uq/L
1.00
03/23/202217:24
1.78
Ng/L
0.500
03/17/2022
21:24
1.33
pg/L
0.500
03/23/202217:24
2.56
Ng/L
1.80
03/22/2022
23:46
J
Page 6 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96100 Matrix: Aqueous
Sample ID: MW-01 OLD-20220310 Sampled: 3/10/2022 10:39
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
1,4-Dioxane
Arsenic
Dissolved Arsenic
Barium
Dissolved Barium
Cadmium
Dissolved Cadmium
Chromium
Dissolved Chromium
Lead
Dissolved Lead
Mercury (Total)
Selenium
Dissolved Selenium
Silver
Dissolved Silver
2.70
0.815 J
<0.490
319
219
<0.150
<0.150
<1.00
<1.00
<0.500
<0.500
<0.00007
<2.30
<2.30
<0.130
<0.130
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Ng/L
0.139
2.00
Pg/L
0.490
1.00
Ng/L
0.490
1.00
Pg/L
3.40
10.0
Ng/L
3.40
10.0
Pg/L
0.150
1.00
Ng/L
0.150
1.00
Pg/L
1.00
2.00
Ng/L
1.00
2.00
Pg/L
0.500
1.00
Ng/L
0.500
1.00
mg/L
0.00007
0.00020
Ng/L
2.30
5.00
Pg/L
2.30
5.00
Ng/L
0.130
1.00
Pg/L
0.130
1.00
1 03/15/22 16:51 TBL 8260D SIM
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
1 03/18/22
17:37
EDV
7470A
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
1 03/17/22
20:06
EDV
6020B
1 03/23/22
16:45
EDV
6020B
J Estimated value
Page 7 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96100
Matrix: Aqueous
Sample ID: MW-01 OLD-20220310
Sampled:
3/10/2022
10:39
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.273
Ng/L
1.80
5.00
1
03/22/22 21:42
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 21:42
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 21:42
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 21:42
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 21:42
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 21:42
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 21:42
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 21:42
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 21:42
JLB
V16479
Chlorobenzene
1.28
u9/L
0.190
0.500
1
03/22/22 21:42
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 21:42
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 21:42
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 21:42
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 21:42
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 21:42
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 21:42
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 21:42
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 21:42
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 21:42
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 21:42
JLB
V16479
1,4-Dichlorobenzene
1.84
N9/L
0.210
0.500
1
03/22/22 21:42
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 21:42
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 8 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96100
Matrix: Aqueous
Sample ID: MW-01 OLD-20220310
Sampled:
3/10/2022
10:39
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.2613
Ng/L
0.240
0.500
1
03/22/22 21:42
JLB
V16479
1,2-Dichloroethane
<0.150
pg/L
0.150
0.500
1
03/22/22 21:42
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 21:42
JLB
V16479
cis- 1,2-Dich loroethene
1.05
pg/L
0.200
0.500
1
03/22/22 21:42
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 21:42
JLB
V16479
1,2-Dichloropropane
<0.190
pg/L
0.190
0.500
1
03/22/22 21:42
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 21:42
JLB
V16479
trans-1,3-Dichloropropene
<0.150
pg/L
0.150
0.500
1
03/22/22 21:42
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 21:42
JLB
V16479
Ethylbenzene
<0.170
pg/L
0.170
0.500
1
03/22/22 21:42
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 21:42
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
pg/L
0.710
5.00
1
03/22/22 21:42
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 21:42
JLB
V16479
Methylene Chloride
<0.330
pg/L
0.330
1.00
1
03/22/22 21:42
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 21:42
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
pg/L
0.160
0.500
1
03/22/22 21:42
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 21:42
JLB
V16479
Tetrachloroethene
<0.220
pg/L
0.220
0.500
1
03/22/22 21:42
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 21:42
JLB
V16479
Toluene
<0.220
pg/L
0.220
0.500
1
03/22/22 21:42
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 21:42
JLB
V16479
1,1,2-Trichloroethane
<0.096
pg/L
0.096
0.500
1
03/22/22 21:42
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 9 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96100 Matrix: Aqueous
Sample ID: MW-01 OLD-20220310 Sampled: 3/10/2022 10:39
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
0.3073
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
98.0
Limits: 80-124%
99.0
Limits: 75-129%
90.2
Limits: 63-136%
92.0
Limits: 77-123%
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
1 03/22/22 21:42 JLB V16479
J Estimated value
Page 10 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96101 Matrix: Aqueous
Sample ID: MW-02 OLD-20220310 Sampled: 3/10/2022 9:16
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
1,4-Dioxane
Arsenic
Dissolved Arsenic
Barium
Dissolved Barium
Cadmium
Dissolved Cadmium
Chromium
Dissolved Chromium
Lead
Dissolved Lead
Mercury (Total)
Selenium
Dissolved Selenium
Silver
Dissolved Silver
<0.139
<0.490
<0.490
55.1
56.8
0.1533
<0.150
<1.00
<1.00
<0.500
<0.500
<0.00007
<2.30
<2.30
<0.130
<0.130
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Ng/L
0.139
2.00
u9/L
0.490
1.00
Ng/L
0.490
1.00
u9/L
3.40
10.0
Ng/L
3.40
10.0
u9/L
0.150
1.00
Ng/L
0.150
1.00
u9/L
1.00
2.00
N9/L
1.00
2.00
u9/L
0.500
1.00
N9/L
0.500
1.00
mg/L
0.00007
0.00020
N9/L
2.30
5.00
u9/L
2.30
5.00
N9/L
0.130
1.00
u9/L
0.130
1.00
1 03/15/22 17:16 TBL 8260D SIM
1 03/17/22
20:38
EDV
6020B
1 03/23/22
16:52
EDV
6020E
1 03/17/22
20:38
EDV
6020B
1 03/23/22
16:52
EDV
6020E
1 03/17/22
20:38
EDV
6020B
1 03/23/22
16:52
EDV
6020E
1 03/17/22
20:38
EDV
6020B
1 03/23/22
16:52
EDV
6020E
1 03/17/22
20:38
EDV
6020B
1 03/23/22
16:52
EDV
6020E
1 03/18/22
17:40
EDV
7470A
1 03/17/22
20:38
EDV
6020E
1 03/23/22
16:52
EDV
6020B
1 03/17/22
20:38
EDV
6020B
1 03/23/22
16:52
EDV
6020B
J Estimated value
Page 11 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96101
Matrix: Aqueous
Sample ID: MW-02 OLD-20220310
Sampled:
3/10/2022
9:16
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
03/22/22 21:18
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 21:18
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 21:18
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 21:18
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 21:18
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 21:18
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 21:18
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 21:18
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 21:18
JLB
V16479
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
03/22/22 21:18
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 21:18
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 21:18
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 21:18
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 21:18
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 21:18
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 21:18
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 21:18
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 21:18
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 21:18
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 21:18
JLB
V16479
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
03/22/22 21:18
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 21:18
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 12 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96101
Matrix: Aqueous
Sample ID: MW-02 OLD-20220310
Sampled:
3/10/2022
9:16
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.509
Ng/L
0.240
0.500
1
03/22/22 21:18
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 21:18
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 21:18
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 21:18
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 21:18
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 21:18
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 21:18
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 21:18
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 21:18
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 21:18
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 21:18
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 21:18
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 21:18
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 21:18
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 21:18
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 21:18
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 21:18
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 21:18
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 21:18
JLB
V16479
Toluene
<0.220
u9/L
0.220
0.500
1
03/22/22 21:18
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 21:18
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 21:18
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 13 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96101 Matrix: Aqueous
Sample ID: MW-02 OLD-20220310 Sampled: 3/10/2022 9:16
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
98.4
Limits: 80-124%
94.0
Limits: 75-129%
84.0
Limits: 63-136%
91.2
Limits: 77-123%
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
1 03/22/22 21:18 JLB V16479
J Estimated value
Page 14 of 55

Waypoint.0
ANALYTICAL
01015
Project ID
Anchor QEA of North Carolina, PLLC
Project
Chuck Pippin
231 Haywood Street
Information
Asheville , NC 28801
Report Number : 22-074-0012
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Madison County Closed Landfill Spring 20
REPORT OF ANAL YSIS
Report Date : 03/24/2022
Received : 03/15/2022
Lab No : 96102
Sample ID: MW-03 OLD-20220310
Matrix: Aqueous
Sampled: 3/10/2022 14:16
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/15/22 17:42
TBL
8260D SIM
Arsenic
<0.490
ug/L
0.490
1.00
1
03/17/22 20:58
EDV
6020B
Dissolved Arsenic
<0.490
Ng/L
0.490
1.00
1
03/23/22 16:58
EDV
6020E
Barium
869
ug/L
3.40
10.0
1
03/17/22 20:58
EDV
6020B
Dissolved Barium
621
Ng/L
3.40
10.0
1
03/23/22 16:58
EDV
6020E
Cadmium
<0.150
ug/L
0.150
1.00
1
03/17/22 20:58
EDV
6020B
Dissolved Cadmium
<0.150
Ng/L
0.150
1.00
1
03/23/22 16:58
EDV
6020E
Chromium
<1.00
ug/L
1.00
2.00
1
03/17/22 20:58
EDV
6020B
Dissolved Chromium
<1.00
Ng/L
1.00
2.00
1
03/23/22 16:58
EDV
6020E
Lead
<0.500
ug/L
0.500
1.00
1
03/17/22 20:58
EDV
6020B
Dissolved Lead
<0.500
Ng/L
0.500
1.00
1
03/23/22 16:58
EDV
6020E
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
03/18/22 17:42
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
03/24/22 10:59
EDV
7470A
Selenium
<2.30
ug/L
2.30
5.00
1
03/17/22 20:58
EDV
6020B
Dissolved Selenium
<2.30
Ng/L
2.30
5.00
1
03/23/22 16:58
EDV
6020E
Silver
<0.130
ug/L
0.130
1.00
1
03/17/22 20:58
EDV
6020B
Dissolved Silver
<0.130
Ng/L
0.130
1.00
1
03/23/22 16:58
EDV
6020E
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 15 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96102
Matrix: Aqueous
Sample ID: MW-03 OLD-20220310
Sampled:
3/10/2022
14:16
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.133
Ng/L
1.80
5.00
1
03/22/22 22:32
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 22:32
JLB
V16479
Benzene
2.82
N9/L
0.180
0.500
1
03/22/22 22:32
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 22:32
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:32
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 22:32
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 22:32
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 22:32
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 22:32
JLB
V16479
Chlorobenzene
8.89
u9/L
0.190
0.500
1
03/22/22 22:32
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 22:32
JLB
V16479
Chloroethane
0.9973
u9/L
0.430
1.00
1
03/22/22 22:32
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 22:32
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 22:32
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 22:32
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 22:32
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 22:32
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 22:32
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 22:32
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 22:32
JLB
V16479
1,4-Dichlorobenzene
3.70
N9/L
0.210
0.500
1
03/22/22 22:32
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 22:32
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 16 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96102
Matrix: Aqueous
Sample ID: MW-03 OLD-20220310
Sampled:
3/10/2022
14:16
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.4333
Ng/L
0.240
0.500
1
03/22/22 22:32
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 22:32
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 22:32
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 22:32
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 22:32
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 22:32
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 22:32
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 22:32
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 22:32
JLB
V16479
Ethylbenzene
6.03
u9/L
0.170
0.500
1
03/22/22 22:32
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 22:32
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 22:32
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 22:32
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 22:32
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 22:32
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 22:32
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:32
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 22:32
JLB
V16479
Tetrahydrofuran
1.643
N9/L
1.50
10.0
1
03/22/22 22:32
JLB
V16479
Toluene
0.2743
u9/L
0.220
0.500
1
03/22/22 22:32
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:32
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 22:32
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 17 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96102 Matrix: Aqueous
Sample ID: MW-03 OLD-20220310 Sampled: 3/10/2022 14:16
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
0.367 J
m,p-Xylene
0.456 J
Xylene (Total)
0.8233
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
96.2
Limits: 80-124%
93.6
Limits: 75-129%
85.0
Limits: 63-136%
93.4
Limits: 77-123%
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
1 03/22/22 22:32 JLB V16479
J Estimated value
Page 18 of 55

Waypoint.0
ANALYTICAL
01015
Project ID
Anchor QEA of North Carolina, PLLC
Project
Chuck Pippin
231 Haywood Street
Information
Asheville , NC 28801
Report Number : 22-074-0012
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Madison County Closed Landfill Spring 20
REPORT OF ANAL YSIS
Report Date : 03/24/2022
Received : 03/15/2022
Lab No : 96103
Sample ID : MW-04 OLD-20220310
Matrix: Aqueous
Sampled: 3/10/2022 12:38
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/15/22 18:07
TBL
8260D SIM
Arsenic
0.559 J
ug/L
0.490
1.00
1
03/17/22 21:05
EDV
6020B
Dissolved Arsenic
<0.490
Ng/L
0.490
1.00
1
03/23/22 17:05
EDV
6020B
Barium
736
ug/L
3.40
10.0
1
03/17/22 21:05
EDV
6020B
Dissolved Barium
666
Ng/L
3.40
10.0
1
03/23/22 17:05
EDV
6020B
Cadmium
0.344 J
ug/L
0.150
1.00
1
03/17/22 21:05
EDV
6020B
Dissolved Cadmium
0.301 J
Ng/L
0.150
1.00
1
03/23/22 17:05
EDV
6020B
Chromium
3.26
ug/L
1.00
2.00
1
03/17/22 21:05
EDV
6020B
Dissolved Chromium
<1.00
Ng/L
1.00
2.00
1
03/23/22 17:05
EDV
6020B
Lead
1.83
ug/L
0.500
1.00
1
03/17/22 21:05
EDV
6020B
Dissolved Lead
1.15
Ng/L
0.500
1.00
1
03/23/22 17:05
EDV
6020B
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
03/18/22 17:45
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
03/24/22 11:02
EDV
7470A
Selenium
<2.30
ug/L
2.30
5.00
1
03/17/22 21:05
EDV
6020B
Dissolved Selenium
<2.30
Ng/L
2.30
5.00
1
03/23/22 17:05
EDV
6020B
Silver
<0.130
ug/L
0.130
1.00
1
03/17/22 21:05
EDV
6020B
Dissolved Silver
<0.130
Ng/L
0.130
1.00
1
03/23/22 17:05
EDV
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 19 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96103
Matrix: Aqueous
Sample ID : MW-04 OLD-20220310
Sampled:
3/10/2022
12:38
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
3.233
Ng/L
1.80
5.00
1
03/22/22 22:07
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 22:07
JLB
V16479
Benzene
0.3913
N9/L
0.180
0.500
1
03/22/22 22:07
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 22:07
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:07
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 22:07
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 22:07
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 22:07
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 22:07
JLB
V16479
Chlorobenzene
5.15
u9/L
0.190
0.500
1
03/22/22 22:07
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 22:07
JLB
V16479
Chloroethane
0.5701
u9/L
0.430
1.00
1
03/22/22 22:07
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 22:07
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 22:07
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 22:07
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 22:07
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 22:07
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 22:07
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 22:07
JLB
V16479
1,2-Dichlorobenzene
0.4053
u9/L
0.220
0.500
1
03/22/22 22:07
JLB
V16479
1,4-Dichlorobenzene
2.29
N9/L
0.210
0.500
1
03/22/22 22:07
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 22:07
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 20 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96103
Matrix: Aqueous
Sample ID : MW-04 OLD-20220310
Sampled:
3/10/2022
12:38
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
03/22/22 22:07
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 22:07
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 22:07
JLB
V16479
cis- 1,2-Dich loroethene
0.421 J
u9/L
0.200
0.500
1
03/22/22 22:07
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 22:07
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 22:07
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 22:07
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 22:07
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 22:07
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 22:07
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 22:07
JLB
V16479
Methyl Ethyl Ketone (MEK)
1.213
u9/L
0.710
5.00
1
03/22/22 22:07
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 22:07
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 22:07
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 22:07
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 22:07
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:07
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 22:07
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 22:07
JLB
V16479
Toluene
0.344 J
u9/L
0.220
0.500
1
03/22/22 22:07
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:07
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 22:07
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 21 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96103 Matrix: Aqueous
Sample ID : MW-04 OLD-20220310 Sampled: 3/10/2022 12:38
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
0.5523
Xylene (Total)
0.5523
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
95.6
Limits: 80-124%
94.4
Limits: 75-129%
85.0
Limits: 63-136%
98.4
Limits: 77-123%
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
1 03/22/22 22:07 JLB V16479
J Estimated value
Page 22 of 55

Waypoint.0
ANALYTICAL
01015
Project ID
Anchor QEA of North Carolina, PLLC
Project
Chuck Pippin
231 Haywood Street
Information
Asheville , NC 28801
Report Number : 22-074-0012
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Madison County Closed Landfill Spring 20
REPORT OF ANAL YSIS
Report Date : 03/24/2022
Received : 03/15/2022
Lab No : 96104
Sample ID: SW-01 OLD-20220310
Matrix: Aqueous
Sampled: 3/10/2022 15:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Hardness
44000
Ng/L
1140
10000
1
03/18/22 12:50
CLB
2340C-2011
1,4-Dioxane
<0.139
ug/L
0.139
2.00
1
03/15/22 18:32
TBL
8260D SIM
Arsenic
<0.490
Ng/L
0.490
1.00
1
03/17/22 21:11
EDV
6020E
Dissolved Arsenic
<0.490
ug/L
0.490
1.00
1
03/23/22 17:11
EDV
6020B
Barium
71.8
Ng/L
3.40
10.0
1
03/17/22 21:11
EDV
6020E
Dissolved Barium
67.4
ug/L
3.40
10.0
1
03/23/22 17:11
EDV
6020B
Cadmium
<0.150
Ng/L
0.150
1.00
1
03/17/22 21:11
EDV
6020E
Dissolved Cadmium
<0.150
ug/L
0.150
1.00
1
03/23/22 17:11
EDV
6020B
Chromium
1.623
Ng/L
1.00
2.00
1
03/17/22 21:11
EDV
6020E
Dissolved Chromium
<1.00
ug/L
1.00
2.00
1
03/23/22 17:11
EDV
6020B
Lead
0.5723
Ng/L
0.500
1.00
1
03/17/22 21:11
EDV
6020E
Dissolved Lead
<0.500
ug/L
0.500
1.00
1
03/23/22 17:11
EDV
6020B
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
03/18/22 17:47
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
03/24/22 10:41
EDV
7470A
Selenium
<2.30
Ng/L
2.30
5.00
1
03/17/22 21:11
EDV
6020E
Dissolved Selenium
<2.30
ug/L
2.30
5.00
1
03/23/22 17:11
EDV
6020B
Silver
<0.130
Ng/L
0.130
1.00
1
03/17/22 21:11
EDV
6020B
Dissolved Silver
<0.130
ug/L
0.130
1.00
1
03/23/22 17:11
EDV
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 23 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96104
Matrix: Aqueous
Sample ID: SW-01 OLD-20220310
Sampled:
3/10/2022
15:15
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.243
Ng/L
1.80
5.00
1
03/22/22 22:56
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 22:56
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 22:56
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 22:56
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:56
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 22:56
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 22:56
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 22:56
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 22:56
JLB
V16479
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
03/22/22 22:56
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 22:56
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 22:56
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 22:56
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 22:56
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 22:56
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 22:56
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 22:56
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 22:56
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 22:56
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 22:56
JLB
V16479
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
03/22/22 22:56
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 22:56
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 24 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96104
Matrix: Aqueous
Sample ID: SW-01 OLD-20220310
Sampled:
3/10/2022
15:15
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
03/22/22 22:56
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 22:56
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 22:56
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 22:56
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 22:56
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 22:56
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 22:56
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 22:56
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 22:56
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 22:56
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 22:56
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 22:56
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 22:56
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 22:56
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 22:56
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 22:56
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:56
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 22:56
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 22:56
JLB
V16479
Toluene
<0.220
u9/L
0.220
0.500
1
03/22/22 22:56
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 22:56
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 22:56
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 25 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96104 Matrix: Aqueous
Sample ID: SW-01 OLD-20220310 Sampled: 3/10/2022 15:15
Analytical Method: 8260D Prep Batch(es): V16478 03/22/22 09:00
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
105
Limits: 80-124%
94.4
Limits: 75-129%
87.8
Limits: 63-136%
89.4
Limits: 77-123%
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
1 03/22/22 22:56 JLB V16479
J Estimated value
Page 26 of 55

Waypoint.0
ANALYTICAL
01015
Project ID
Anchor QEA of North Carolina, PLLC
Project
Chuck Pippin
231 Haywood Street
Information
Asheville , NC 28801
Report Number : 22-074-0012
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Madison County Closed Landfill Spring 20
REPORT OF ANAL YSIS
Report Date : 03/24/2022
Received : 03/15/2022
Lab No : 96105
Sample ID: SW-02 OLD-20220310
Matrix: Aqueous
Sampled: 3/10/2022 15:40
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Hardness
42000
Ng/L
1140
10000
1
03/18/22 12:50
CLB
2340C-2011
1,4-Dioxane
<0.139
ug/L
0.139
2.00
1
03/15/22 18:57
TBL
8260D SIM
Arsenic
<0.490
Ng/L
0.490
1.00
1
03/17/22 21:18
EDV
6020E
Dissolved Arsenic
<0.490
ug/L
0.490
1.00
1
03/23/22 17:18
EDV
6020B
Barium
54.9
Ng/L
3.40
10.0
1
03/17/22 21:18
EDV
6020E
Dissolved Barium
51.2
ug/L
3.40
10.0
1
03/23/22 17:18
EDV
6020B
Cadmium
<0.150
Ng/L
0.150
1.00
1
03/17/22 21:18
EDV
6020E
Dissolved Cadmium
<0.150
ug/L
0.150
1.00
1
03/23/22 17:18
EDV
6020B
Chromium
3.56
Ng/L
1.00
2.00
1
03/17/22 21:18
EDV
6020E
Dissolved Chromium
2.15
ug/L
1.00
2.00
1
03/23/22 17:18
EDV
6020B
Lead
1.21
Ng/L
0.500
1.00
1
03/17/22 21:18
EDV
6020E
Dissolved Lead
0.702 J
ug/L
0.500
1.00
1
03/23/22 17:18
EDV
6020B
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
03/18/22 17:50
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
03/24/22 11:04
EDV
7470A
Selenium
<2.30
Ng/L
2.30
5.00
1
03/17/22 21:18
EDV
6020E
Dissolved Selenium
<2.30
ug/L
2.30
5.00
1
03/23/22 17:18
EDV
6020B
Silver
<0.130
Ng/L
0.130
1.00
1
03/17/22 21:18
EDV
6020E
Dissolved Silver
<0.130
ug/L
0.130
1.00
1
03/23/22 17:18
EDV
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 27 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96105
Matrix: Aqueous
Sample ID: SW-02 OLD-20220310
Sampled:
3/10/2022
15:40
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
4.993
Ng/L
1.80
5.00
1
03/22/22 23:21
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 23:21
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 23:21
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 23:21
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 23:21
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 23:21
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 23:21
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 23:21
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 23:21
JLB
V16479
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
03/22/22 23:21
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 23:21
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 23:21
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 23:21
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 23:21
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 23:21
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 23:21
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 23:21
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 23:21
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 23:21
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 23:21
JLB
V16479
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
03/22/22 23:21
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 23:21
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 28 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96105
Matrix: Aqueous
Sample ID: SW-02 OLD-20220310
Sampled:
3/10/2022
15:40
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
03/22/22 23:21
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 23:21
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 23:21
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 23:21
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 23:21
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 23:21
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 23:21
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 23:21
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 23:21
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 23:21
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 23:21
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 23:21
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 23:21
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 23:21
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 23:21
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 23:21
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 23:21
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 23:21
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 23:21
JLB
V16479
Toluene
<0.220
u9/L
0.220
0.500
1
03/22/22 23:21
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 23:21
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 23:21
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 29 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96105 Matrix: Aqueous
Sample ID: SW-02 OLD-20220310 Sampled: 3/10/2022 15:40
Analytical Method: 8260D Prep Batch(es): V16478 03/22/22 09:00
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
97.4
Limits: 80-124%
96.8
Limits: 75-129%
88.0
Limits: 63-136%
89.0
Limits: 77-123%
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
1 03/22/22 23:21 JLB V16479
J Estimated value
Page 30 of 55

Waypoint.0
ANALYTICAL
01015
Project ID
Anchor QEA of North Carolina, PLLC
Project
Chuck Pippin
231 Haywood Street
Information
Asheville , NC 28801
Report Number : 22-074-0012
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Madison County Closed Landfill Spring 20
REPORT OF ANAL YSIS
Report Date : 03/24/2022
Received : 03/15/2022
Lab No : 96106
Sample ID: BG SPRING OLD-20220310
Matrix: Aqueous
Sampled: 3/10/2022 16:34
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/15/22 19:22
TBL
8260D SIM
Arsenic
0.765 J
ug/L
0.490
1.00
1
03/17/22 21:24
EDV
6020B
Dissolved Arsenic
0.505 J
Ng/L
0.490
1.00
1
03/23/22 17:24
EDV
6020B
Barium
ill
ug/L
3.40
10.0
1
03/17/22 21:24
EDV
6020B
Dissolved Barium
91.3
Ng/L
3.40
10.0
1
03/23/22 17:24
EDV
6020B
Cadmium
<0.150
pg/L
0.150
1.00
1
03/17/22 21:24
EDV
6020B
Dissolved Cadmium
<0.150
Ng/L
0.150
1.00
1
03/23/22 17:24
EDV
6020B
Chromium
8.35
pg/L
1.00
2.00
1
03/17/22 21:24
EDV
6020B
Dissolved Chromium
6.00
Ng/L
1.00
2.00
1
03/23/22 17:24
EDV
6020B
Lead
1.78
ug/L
0.500
1.00
1
03/17/22 21:24
EDV
6020B
Dissolved Lead
1.33
Ng/L
0.500
1.00
1
03/23/22 17:24
EDV
6020B
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
03/18/22 17:53
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
03/24/22 11:14
EDV
7470A
Selenium
<2.30
ug/L
2.30
5.00
1
03/17/22 21:24
EDV
6020B
Dissolved Selenium
<2.30
Ng/L
2.30
5.00
1
03/23/22 17:24
EDV
6020E
Silver
<0.130
ug/L
0.130
1.00
1
03/17/22 21:24
EDV
6020B
Dissolved Silver
<0.130
Ng/L
0.130
1.00
1
03/23/22 17:24
EDV
6020E
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
I Estimated value
Page 31 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96106
Matrix: Aqueous
Sample ID: BG SPRING OLD-20220310
Sampled:
3/10/2022
16:34
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
2.563
Ng/L
1.80
5.00
1
03/22/22 23:46
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 23:46
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 23:46
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 23:46
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 23:46
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 23:46
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 23:46
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 23:46
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 23:46
JLB
V16479
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
03/22/22 23:46
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 23:46
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 23:46
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 23:46
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 23:46
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 23:46
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 23:46
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 23:46
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 23:46
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 23:46
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 23:46
JLB
V16479
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
03/22/22 23:46
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 23:46
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 32 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96106
Matrix: Aqueous
Sample ID: BG SPRING OLD-20220310
Sampled:
3/10/2022
16:34
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
03/22/22 23:46
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 23:46
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 23:46
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 23:46
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 23:46
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 23:46
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 23:46
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 23:46
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 23:46
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 23:46
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 23:46
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 23:46
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 23:46
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 23:46
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 23:46
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 23:46
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 23:46
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 23:46
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 23:46
JLB
V16479
Toluene
<0.220
u9/L
0.220
0.500
1
03/22/22 23:46
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 23:46
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 23:46
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 33 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96106 Matrix: Aqueous
Sample ID: BG SPRING OLD-20220310 Sampled: 3/10/2022 16:34
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
99.6
Limits: 80-124%
92.4
Limits: 75-129%
84.8
Limits: 63-136%
91.8
Limits: 77-123%
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
1 03/22/22 23:46 JLB V16479
J Estimated value
Page 34 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96107
Matrix: Aqueous
Sample ID: TripBlank-MWOLD-20220310
Sampled:
3/10/2022
0:00
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
03/22/22 18:01
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 18:01
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 18:01
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 18:01
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 18:01
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 18:01
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 18:01
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 18:01
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 18:01
JLB
V16479
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
03/22/22 18:01
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 18:01
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 18:01
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 18:01
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 18:01
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 18:01
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 18:01
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 18:01
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 18:01
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 18:01
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 18:01
JLB
V16479
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
03/22/22 18:01
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 18:01
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 35 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96107
Matrix: Aqueous
Sample ID: TripBlank-MWOLD-20220310
Sampled:
3/10/2022
0:00
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
03/22/22 18:01
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 18:01
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 18:01
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 18:01
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 18:01
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 18:01
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 18:01
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 18:01
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 18:01
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 18:01
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 18:01
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 18:01
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 18:01
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 18:01
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 18:01
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 18:01
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 18:01
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 18:01
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 18:01
JLB
V16479
Toluene
<0.220
u9/L
0.220
0.500
1
03/22/22 18:01
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 18:01
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 18:01
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 36 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96107 Matrix: Aqueous
Sample ID: TripBlank-MWOLD-20220310 Sampled: 3/10/2022 0:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
105
Limits: 80-124%
93.8
Limits: 75-129%
85.8
Limits: 63-136%
92.6
Limits: 77-123%
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
1 03/22/22 18:01 JLB V16479
J Estimated value
Page 37 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96108
Matrix: Aqueous
Sample ID : TripBlank-SWOLD-20220310
Sampled:
3/10/2022
0:00
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
03/22/22 20:53
JLB
V16479
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
03/22/22 20:53
JLB
V16479
Benzene
<0.180
N9/L
0.180
0.500
1
03/22/22 20:53
JLB
V16479
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
03/22/22 20:53
JLB
V16479
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
03/22/22 20:53
JLB
V16479
Bromoform
<1.50
u9/L
1.50
5.00
1
03/22/22 20:53
JLB
V16479
Bromomethane
<0.280
N9/L
0.280
1.00
1
03/22/22 20:53
JLB
V16479
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
03/22/22 20:53
JLB
V16479
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
03/22/22 20:53
JLB
V16479
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
03/22/22 20:53
JLB
V16479
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
03/22/22 20:53
JLB
V16479
Chloroethane
<0.430
u9/L
0.430
1.00
1
03/22/22 20:53
JLB
V16479
Chloroform
<0.220
N9/L
0.220
0.500
1
03/22/22 20:53
JLB
V16479
Chloromethane
<0.220
u9/L
0.220
0.500
1
03/22/22 20:53
JLB
V16479
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
03/22/22 20:53
JLB
V16479
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
03/22/22 20:53
JLB
V16479
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
03/22/22 20:53
JLB
V16479
Dibromomethane
<0.230
u9/L
0.230
0.500
1
03/22/22 20:53
JLB
V16479
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
03/22/22 20:53
JLB
V16479
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
03/22/22 20:53
JLB
V16479
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
03/22/22 20:53
JLB
V16479
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
03/22/22 20:53
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 38 of 55

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill Spring 20
Chuck Pippin Report Date : 03/24/2022
231 Haywood Street Information : Received : 03/15/2022
Asheville , NC 28801
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96108
Matrix: Aqueous
Sample ID : TripBlank-SWOLD-20220310
Sampled:
3/10/2022
0:00
Analytical Method: 8260D
Prep Batch(es):
V16478
03/22/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
03/22/22 20:53
JLB
V16479
1,2-Dichloroethane
<0.150
u9/L
0.150
0.500
1
03/22/22 20:53
JLB
V16479
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
03/22/22 20:53
JLB
V16479
cis- 1,2-Dich loroethene
<0.200
u9/L
0.200
0.500
1
03/22/22 20:53
JLB
V16479
trans-1,2-Dichloroethene
<0.180
N9/L
0.180
0.500
1
03/22/22 20:53
JLB
V16479
1,2-Dichloropropane
<0.190
u9/L
0.190
0.500
1
03/22/22 20:53
JLB
V16479
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
03/22/22 20:53
JLB
V16479
trans-1,3-Dichloropropene
<0.150
u9/L
0.150
0.500
1
03/22/22 20:53
JLB
V16479
1,4-Dioxane
<16.0
N9/L
16.0
150
1
03/22/22 20:53
JLB
V16479
Ethylbenzene
<0.170
u9/L
0.170
0.500
1
03/22/22 20:53
JLB
V16479
2-Hexanone
<0.380
N9/L
0.380
5.00
1
03/22/22 20:53
JLB
V16479
Methyl Ethyl Ketone (MEK)
<0.710
u9/L
0.710
5.00
1
03/22/22 20:53
JLB
V16479
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
03/22/22 20:53
JLB
V16479
Methylene Chloride
<0.330
u9/L
0.330
1.00
1
03/22/22 20:53
JLB
V16479
Styrene
<0.220
N9/L
0.220
0.500
1
03/22/22 20:53
JLB
V16479
1,1,1,2-Tetrachloroethane
<0.160
u9/L
0.160
0.500
1
03/22/22 20:53
JLB
V16479
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 20:53
JLB
V16479
Tetrachloroethene
<0.220
u9/L
0.220
0.500
1
03/22/22 20:53
JLB
V16479
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
03/22/22 20:53
JLB
V16479
Toluene
<0.220
u9/L
0.220
0.500
1
03/22/22 20:53
JLB
V16479
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
03/22/22 20:53
JLB
V16479
1,1,2-Trichloroethane
<0.096
u9/L
0.096
0.500
1
03/22/22 20:53
JLB
V16479
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 39 of 55

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill Spring 20
Report Date : 03/24/2022
Information : Received : 03/15/2022
Report Number : 22-074-0012 REPOR T OF A NA L YSIS
Lab No : 96108 Matrix: Aqueous
Sample ID : TripBlank-SWOLD-20220310 Sampled: 3/10/2022 0:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofl uorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V16478 03/22/22 09:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
99.2
Limits: 80-124%
94.2
Limits: 75-129%
86.0
Limits: 63-136%
91.6
Limits: 77-123%
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
1 03/22/22 20:53 JLB V16479
J Estimated value
Page 40 of 55

•
Waypoint,
449 Springbrook
Charlotte, NC 28217
Rd, Ch
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Analytical Batch: V16256
Analysis Method: 2340C-2011
Analysis Description: Total Hardness
Lab Reagent Blank
LRB
Matrix: AQU
Associated Lab Samples: 96104, 96105
Blank MDL
MQL
Analyzed
Parameter Units
Result
Hardness pg/L
<570 570
5000
03/18/22 12:50
Laboratory Control Sample
LCS
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Hardness pg/L
50000
50000
100 90-110
Duplicate
V 95769-DUP
Result DUP
RPD Max RPD
Analyzed
Parameter Units
Result
Hardness pg/L
<5000 <5000
0.0 20
03/18/22 12:50
Matrix Spike & Matrix Spike Duplicate
V 95867-MS V 95867-MSD
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Hardness pg/L
24000 20000
20000 44000
44000 100 100 80-120 0.0 20
Date: 03/24/2022 01:31 PM Page 1 of 13
Page 41 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Prep:
V16217
QC Analytical Batch(es): V16291
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V16217
Matrix: AQU
Associated Lab Samples:
96100, 96101, 96102, 96103,
96104, 96105, 96106
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Arsenic
pg/L
<0.490
0.490
1.00
03/17/2219:53
Barium
pg/L
<3.40
3.40
10.0
03/17/2219:53
Cadmium
pg/L
<0.150
0.150
1.00
03/17/2219:53
Chromium
pg/L
<1.00
1.00
2.00
03/17/2219:53
Lead
pg/L
<0.500
0.500
1.00
03/17/22 19:53
Selenium
pg/L
<2.30
2.30
5.00
03/17/2219:53
Silver
pg/L
<0.130
0.130
1.00
03/17/2219:53
Laboratory Control Sample
LCS-V16217
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Arsenic
pg/L
100
96.3
96.0
80-120
Barium
pg/L
100
97.6
98.0
80-120
Cadmium
pg/L
100
99.7
100
80-120
Chromium
pg/L
100
100
100
80-120
Lead
pg/L
100
101
101
80-120
Selenium
pg/L
100
99.6
100
80-120
Silver
pg/L
100
100
100
80-120
Matrix Spike & Matrix Spike Duplicate
V 96100-MS-V16217
V 96100-MSD-V16217
MS Spike
MSD
MS Result
MSD
MS
MSD
%Rec
Max
Parameter
Units
Result
Conc.
Spike
Result
%Rec
%Rec
Limits
RPD
RPD
Conc.
Arsenic
pg/L
0.815
100
100
95.7
96.5
95.0
96.0
75-125
0.8
20.0
Barium
pg/L
319
100
100
400
413
81.0
94.0
75-125
3.1
20.0
Cadmium
pg/L
< 0.150
100
100
99.0
99.6
99.0
100
75-125
0.6
20.0
Chromium
pg/L
< 1.00
100
100
96.7
96.1
97.0
96.0
75-125
0.6
20.0
Date: 03/24/2022 01:31 PM Page 2 of 13
Page 42 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill Spring
2022 WQ
Report No:
22-074-0012
QC Prep:
V16217
QC Analytical Batch(es): V16291
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 96100-MS-V16217
V 96100-MSD-V16217
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Lead
ug/L
< 0.500 100
100 98.6
100 99.0
100 75-125 1.4 20.0
Selenium
ug/L
< 2.30 100
100 98.1
95.8 98.0
96.0 75-125 2.3 20.0
Silver
ug/L
< 0.130 100
100 100
98.7 100
99.0 75-125 1.3 20.0
Post Digestion Spike
V 96100-PDS-V16217
PDS
%
Analyzed
Parameter
Units
Result Recovery
Arsenic
ug/L
50.3
100
03/17/22 20:25
Barium
ug/L
206
98.0
03/17/22 20:25
Cadmium
ug/L
50.5
101
03/17/22 20:25
Chromium
ug/L
50.2
100
03/17/22 20:25
Lead
ug/L
50.6
101
03/17/22 20:25
Selenium
ug/L
49.8
100
03/17/22 20:25
Silver
ug/L
51.0
102
03/17/22 20:25
Date: 03/24/2022 01:31 PM Page 3 of 13
Page 43 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Prep:
V16474
QC Analytical Batch(es): V16515
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V16474
Matrix: AQU
Associated Lab Samples:
96100, 96101, 96102, 96103,
96104, 96105, 96106
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Dissolved Arsenic
pg/L
<0.490
0.490
1.00
03/23/22 15:46
Dissolved Barium
pg/L
<3.40
3.40
10.0
03/23/22 15:46
Dissolved Cadmium
pg/L
<0.150
0.150
1.00
03/23/22 15:46
Dissolved Chromium
pg/L
<1.00
1.00
2.00
03/23/22 15:46
Dissolved Lead
pg/L
<0.500
0.500
1.00
03/23/22 15:46
Dissolved Selenium
pg/L
<2.30
2.30
5.00
03/23/22 15:46
Dissolved Silver
pg/L
<0.130
0.130
1.00
03/23/22 15:46
Laboratory Control Sample
LCS-V16474
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Dissolved Arsenic
pg/L
100
87.4
87.0
80-120
Dissolved Barium
pg/L
100
92.9
93.0
80-120
Dissolved Cadmium
pg/L
100
92.2
92.0
80-120
Dissolved Chromium
pg/L
100
88.1
88.0
80-120
Dissolved Lead
pg/L
100
91.2
91.0
80-120
Dissolved Selenium
pg/L
100
94.4
94.0
80-120
Dissolved Silver
pg/L
100
90.4
90.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 96645-V16471-MS-V16474
V 96645-V16471-MSD-V16474
MS Spike
MSD
MS Result
MSD
MS
MSD
%Rec
Max
Parameter
Units
Result
Conc.
Spike
Result
%Rec
%Rec
Limits
RPD
RPD
Conc.
Dissolved Arsenic
pg/L
< 0.490
100
100
88.3
92.3
88.0
92.0
75-125
4.4
20.0
Dissolved Barium
pg/L
81.0
100
100
170
181
89.0
100
75-125
6.2
20.0
Dissolved Cadmium
pg/L
3.18
100
100
94.7
99.5
92.0
96.0
75-125
4.9
20.0
Dissolved Chromium
pg/L
< 1.00
100
100
86.8
90.2
87.0
90.0
75-125
3.8
20.0
Date: 03/24/2022 01:31 PM Page 4 of 13
Page 44 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill Spring
2022 WQ
Report No:
22-074-0012
QC Prep:
V16474
QC Analytical Batch(es): V16515
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 96645-V16471-MS-V16474 V 96645-V16471-MSD-V16474
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Dissolved Lead
ug/L
< 0.500 100
100 89.7
93.6 90.0
94.0 75-125 4.2 20.0
Dissolved Selenium
ug/L
< 2.30 100
100 97.9
105 98.0
105 75-125 6.9 20.0
Dissolved Silver
ug/L
< 0.130 100
100 82.9
87.8 83.0
88.0 75-125 5.7 20.0
Post Digestion Spike
V 96645-V16471-PDS-V16474
PDS
%
Analyzed
Parameter
Units
Result
Recovery
Dissolved Arsenic
ug/L
49.1
98.0
03/23/22 16:32
Dissolved Barium
ug/L
88.1
97.0
03/23/22 16:32
Dissolved Cadmium
ug/L
49.3
96.0
03/23/22 16:32
Dissolved Chromium
ug/L
46.7
93.0
03/23/22 16:32
Dissolved Lead
ug/L
47.0
94.0
03/23/22 16:32
Dissolved Selenium
ug/L
49.4
99.0
03/23/22 16:32
Dissolved Silver
ug/L
43.7
87.0
03/23/22 16:32
Date: 03/24/2022 01:31 PM Page 5 of 13
Page 45 of 55

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Prep: V16322
QC Analytical Batch(es): V16354
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V16322
Matrix: AQU
Associated Lab Samples: 96100, 96101, 96102, 96103, 96104, 96105, 96106
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) mg/L <0.00007 0.00007
0.00020
03/18/22 16:59
Laboratory Control Sample
LCS-V16322
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) mg/L
0.00937
0.00916
98.0 80-120
Matrix Spike & Matrix Spike Duplicate
V 96280-MS-V16322
V 96280-MSD-V16322
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) mg/L < 0.00007 0.00937
0.00937 0.00927
0.00945 99.0 101 80-120 1.9 20.0
Post Digestion Spike
V 96280-PDS-V16322
PDS
%
Analyzed
Parameter Units
Result
Recovery
Mercury (Total) mg/L
0.00430
92.0
03/18/22 16:47
Date: 03/24/2022 01:31 PM Page 6 of 13
Page 46 of 55

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill Spring
2022 WQ
Report No: 22-074-0012
QC Prep: V16475
QC Analytical Batch(es): V16513
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V16475
Matrix: AQU
Associated Lab Samples: 96102, 96103, 96104, 96105, 96106
Blank MDL
MQL
Analyzed
Parameter Units
Result
Dissolved Mercury mg/L
0 0.000
0.00020
03/24/22 10:35
Laboratory Control Sample
LCS-V16475
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Dissolved Mercury mg/L
0.00937
0.00958
102 80-120
Matrix Spike & Matrix Spike Duplicate
V 96104-V16471-MS-V16475 V 96104-V16471-MSD-V16475
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Dissolved Mercury mg/L < 0.00007 0.00937
0.00937 0.00973
0.00935 104 100 80-120 3.9 20.0
Post Digestion Spike
V 96104-V16471-PDS-V16475
PDS
%
Analyzed
Parameter Units
Result
Recovery
Dissolved Mercury mg/L
0.00478
102
03/24/22 10:53
Date: 03/24/2022 01:31 PM Page 7 of 13
Page 47 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill Spring 2022 WQ
Report No:
22-074-0012
QC Prep:
V16146
QC Analytical Batch(es): V16147
QC Prep Batch Method:
5030B
Analysis Method:
8260D SIM
Analysis Description:
Volatile Organic Compounds -
GC/MS
Lab Reagent Blank
LRB-V16146
Matrix: AQU
Associated Lab Samples:
96100, 96101, 96102, 96103, 96104, 96105,
96106
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
1,4-Dioxane
pg/L
<0.139 0.139
2.00
03/15/2216:26
4-Bromofluorobenzene (S)
03/15/22 16:26
114
70-130
Laboratory Control Sample
LCS-V16146
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
1,4-Dioxane
pg/L
50.0
51.7
103
70-130
4-Bromofluorobenzene (S)
108
70-130
Matrix Spike & Matrix Spike Duplicate
V 96106-MS-V16146
V 96106-MSD-V16146
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec
Limits RPD
Conc.
1,4-Dioxane
pg/L
< 0.139 50.0
50.0 56.0
58.0 112
116
70-130
4-Bromofluorobenzene (S)
114
114
70-130
Date: 03/24/2022 01:31 PM Page 8 of 13
Page 48 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Prep: V16478
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V16479
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V16478 Matrix: AQU
Associated Lab Samples: 96100, 96101, 96102, 96103, 96104, 96105, 96106, 96107, 96108
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<1.80
1.80
5.00
03/22/22 16:22
Acrylonitrile
pg/L
<0.230
0.230
5.00
03/22/22 16:22
Benzene
pg/L
<0.180
0.180
0.500
03/22/22 16:22
Bromochloromethane
pg/L
<0.420
0.420
1.00
03/22/22 16:22
Bromodichloromethane
pg/L
<0.160
0.160
0.500
03/22/22 16:22
Bromoform
pg/L
<1.50
1.50
5.00
03/22/22 16:22
Bromomethane
pg/L
<0.280
0.280
1.00
03/22/22 16:22
Carbon Disulfide
pg/L
<0.150
0.150
5.00
03/22/22 16:22
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
03/22/22 16:22
Chlorobenzene
pg/L
<0.190
0.190
0.500
03/22/22 16:22
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
03/22/22 16:22
Chloroethane
pg/L
<0.430
0.430
1.00
03/22/22 16:22
Chloroform
pg/L
<0.220
0.220
0.500
03/22/22 16:22
Chloromethane
pg/L
<0.220
0.220
0.500
03/22/22 16:22
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
03/22/22 16:22
1,2-Dibromo-3-Chloropropane
pg/L
<1.10
1.10
2.00
03/22/22 16:22
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
03/22/22 16:22
Dibromomethane
pg/L
<0.230
0.230
0.500
03/22/22 16:22
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
03/22/22 16:22
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
03/22/22 16:22
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
03/22/22 16:22
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
03/22/22 16:22
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
03/22/22 16:22
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
03/22/22 16:22
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
03/22/22 16:22
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
03/22/22 16:22
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
03/22/22 16:22
Date: 03/24/2022 01:31 PM Page 9 of 13
Page 49 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Prep: V16478
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V16479
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V16478 Matrix: AQU
Associated Lab Samples: 96100, 96101, 96102, 96103, 96104, 96105, 96106, 96107, 96108
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,4-Dioxane
Ethylbenzene
2-Hexanone
Methyl Ethyl Ketone (MEK)
4-M ethyl-2-Penta none
Methylene Chloride
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl Acetate
Vinyl Chloride
o-Xylene
m,p-Xylene
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dichloroethane - d4 (S)
pg/L
<0.190
0.190
0.500
pg/L
<0.210
0.210
0.500
pg/L
<0.150
0.150
0.500
pg/L
<16.0
16.0
150
pg/L
<0.170
0.170
0.500
pg/L
<0.380
0.380
5.00
pg/L
<0.710
0.710
5.00
pg/L
<1.00
1.00
5.00
pg/L
<0.330
0.330
1.00
pg/L
<0.220
0.220
0.500
pg/L
<0.160
0.160
0.500
pg/L
<0.160
0.160
0.500
pg/L
<0.220
0.220
0.500
pg/L
<1.50
1.50
10.0
pg/L
<0.220
0.220
0.500
pg/L
<0.160
0.160
0.500
pg/L
<0.096
0.096
0.500
pg/L
<0.180
0.180
0.500
pg/L
<0.180
0.180
0.500
pg/L
<0.270
0.270
1.00
pg/L
<1.00
1.00
2.00
pg/L
<0.170
0.170
0.500
pg/L
<0.210
0.210
0.500
pg/L
<0.420
0.420
1.00
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
03/22/22 16:22
99.6
95.8
86.4
80-124
75-129
63-136
Date: 03/24/2022 01:31 PM Page 10 of 13
Page 50 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill Spring
2022 WQ
Report No:
22-074-0012
QC Prep:
V16478
QC Analytical Batch(es): V16479
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V16478
Matrix: AQU
Associated Lab Samples:
96100, 96101, 96102, 96103, 96104, 96105, 96106,
96107, 96108
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Toluene-d8 (S)
03/22/22 16:22
92.2
77-123
Laboratory Control Sample
& LCSD
LCS-V16478 LCSD-V16478
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
41.5
43.1
104
108
40-166
3.7
20.0
Acrylonitrile
pg/L
40.0
45.9
45.3
115
113
81-127
1.3
20.0
Benzene
pg/L
20.0
23.5
22.6
118
113
77-128
3.9
20.0
Bromochloromethane
pg/L
20.0
23.4
22.6
117
113
78-135
3.4
20.0
Bromodichloromethane
pg/L
20.0
22.6
21.8
113
109
76-138
3.6
20.0
Bromoform
pg/L
20.0
21.3
21.1
107
106
71-135
0.9
20.0
Bromomethane
pg/L
20.0
21.3
21.0
107
105
41-168
1.4
20.0
Carbon Disulfide
pg/L
20.0
22.5
21.6
113
108
59-135
4.0
20.0
Carbon Tetrachloride
pg/L
20.0
21.7
20.5
109
103
72-142
5.6
20.0
Chlorobenzene
pg/L
20.0
20.1
20.5
101
103
78-119
1.9
20.0
Chlorodibromomethane
pg/L
20.0
20.9
21.7
105
109
75-134
3.7
20.0
Chloroethane
pg/L
20.0
22.1
21.7
111
109
57-142
1.8
20.0
Chloroform
pg/L
20.0
22.2
21.9
111
110
77-130
1.3
20.0
Chloromethane
pg/L
20.0
24.6
23.3
123
117
47-145
5.4
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
22.4
22.3
112
112
60-154
0.4
20.0
1,2-Dibromo-3-Chloropropane pg/L
20.0
20.8
23.0
104
115
63-134
10.0
20.0
1,2-Dibromoethane
pg/L
20.0
21.2
21.2
106
106
77-135
0.0
20.0
Dibromomethane
pg/L
20.0
22.8
21.6
114
108
76-138
5.4
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
19.8
19.8
99.0
99.0
70-130
0.0
20.0
1,2-Dichlorobenzene
pg/L
20.0
19.9
20.1
99.5
101
78-128
1.0
20.0
1,4-Dichlorobenzene
pg/L
20.0
19.3
19.2
96.5
96.0
75-126
0.5
20.0
Date: 03/24/2022 01:31 PM Page 11 of 13
Page 51 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill Spring 2022 WQ
Report No: 22-074-0012
QC Prep: V16478 QC Analytical Batch(es): V16479
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V16478 LCSD-V16478
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Dichlorodifluoromethane
pg/L
20.0
24.6
24.5
123
123
28-163
0.4
20.0
1,1-Dichloroethane
pg/L
20.0
23.3
22.2
117
111
70-130
4.8
20.0
1,2-Dichloroethane
pg/L
20.0
20.7
20.3
104
102
68-131
1.9
20.0
1,1-Dichloroethene
pg/L
20.0
23.3
22.8
117
114
70-154
2.1
20.0
cis-1,2-Dichloroethene
pg/L
20.0
21.7
21.4
109
107
76-141
1.3
20.0
trans-1,2-Dichloroethene
pg/L
20.0
23.1
22.5
116
113
76-135
2.6
20.0
1,2-Dichloropropane
pg/L
20.0
23.7
23.1
119
116
77-130
2.5
20.0
cis-1,3-Dichloropropene
pg/L
20.0
23.1
22.7
116
114
65-140
1.7
20.0
trans-1,3-Dichloropropene
pg/L
20.0
22.2
21.9
111
110
67-140
1.3
20.0
1,4-Dioxane
pg/L
200
226
223
113
112
70-130
1.3
20.0
Ethylbenzene
pg/L
20.0
20.1
20.1
101
101
80-127
0.0
20.0
2-Hexanone
pg/L
20.0
21.9
23.2
110
116
64-137
5.7
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
21.2
21.4
106
107
71-134
0.9
20.0
4-Methyl-2-Pentanone
pg/L
20.0
23.1
23.0
116
115
69-134
0.4
20.0
Methylene Chloride
pg/L
20.0
22.1
22.2
111
111
73-131
0.4
20.0
Styrene
pg/L
20.0
20.2
20.6
101
103
78-129
1.9
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
19.5
19.9
97.5
99.5
79-134
2.0
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
20.2
20.8
101
104
62-127
2.9
20.0
Tetrachloroethene
pg/L
20.0
20.4
20.6
102
103
80-129
0.9
20.0
Tetrahydrofuran
pg/L
20.0
24.3
23.1
122
116
70-130
5.0
20.0
Toluene
pg/L
20.0
22.0
21.6
110
108
76-131
1.8
20.0
1,1,1-Trichloroethane
pg/L
20.0
22.1
21.2
111
106
75-135
4.1
20.0
1,1,2-Trichloroethane
pg/L
20.0
22.6
22.4
113
112
70-140
0.8
20.0
Trichloroethene
pg/L
20.0
22.8
22.7
114
114
77-133
0.4
20.0
Trichlorofluoromethane
pg/L
20.0
22.8
21.4
114
107
62-148
6.3
20.0
1,2,3-Trichloropropane
pg/L
20.0
20.6
19.9
103
99.5
71-127
3.4
20.0
Date: 03/24/2022 01:31 PM Page 12 of 13
Page 52 of 55

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill Spring
2022 WQ
Report No:
22-074-0012
QC Prep:
V16478
QC Analytical Batch(es): V16479
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic Compounds - GC/MS
Laboratory Control Sample
& LCSD
LCS-V16478 LCSD-V16478
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result Result
%Rec
% Rec
Limits
RPD
Max
RPD
Vinyl Acetate
pg/L
20.0
21.9 21.7
110
109
34-167
0.9
20.0
Vinyl Chloride
pg/L
20.0
25.9 25.0
130
125
57-141
3.5
20.0
o-Xylene
pg/L
20.0
20.0 20.0
100
100
78-128
0.0
20.0
m,p-Xylene
pg/L
40.0
41.3 41.2
103
103
77-133
0.2
20.0
4-Bromofluorobenzene (S)
97.0
97.6
80-124
Dibromofluoromethane (S)
91.4
92.0
75-129
1,2-Dichloroethane - d4 (S)
85.0
86.4
63-136
Toluene-d8 (S)
92.2
94.8
77-123
Date: 03/24/2022 01:31 PM Page 13 of 13
Page 53 of 55

WayPAoint.
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01015
Customer Name: Anchor QEA of North Carolina, PLLC
Report Number: 22-074-0012
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client # Courier
0 Other:
Thermometer ID:
IRT-15 2.5 C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
(*� Yes
0 No
0 Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample Iabel(s)?
(0) Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
U Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
U Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
Special precautions or instructions included?
Comments:
0 Yes 0 No U N/A
F Low concentration EnCore samplers (48 hr)
Low conc pre -weighed vials (Sod Bis -14 d)
0Yes ONo
Signature: Zoe S. Vigilant
Date & Time: 03/15/2022 12:12:28
Page 54 of 55

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