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HomeMy WebLinkAbout3404_Forsyth_Kernersville_MSWLF_Feb2022GW_FID1691370_20220630DENR USE ONLY ❑Paper Report []Electronic Data -Email CD (data loaded: Yes / No Doc/Event #: NC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): WithersRavenel, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Matthew James, PG E-mail: mjames@withersravenel.com I,r . r - •]R1P&1.1 1I9191". NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Town of Kernersville Landfill Freeman Road 34-04 .0500 July 20, 2021 Kernersville, NC 27284 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Matthew James PG Director of Geosciences 919.238.0335 Facility Representative Name (Print) Title (Area Code) Telephone Number �� June 29, 2022 0 Signature Date 115 MacKenan Drive, Cary, NC 27511 Facility Representative Address F-1479 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal oAtN GA SO SEAL 2310 4- 5 '..,qq e0tO G3e 40 �oo WithersRavenel Our People. Your Success. June 29, 2022 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management -Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: February 2022 Water Quality Monitoring Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.48 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached February 2022 Water Quality Monitoring Report for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report, appendices for the February 2022 sampling event, and historic data from previous sampling events. Also attached is the North Carolina Environmental Monitoring Reporting Form for the February 2022 monitoring event. Please contact me at miames@withersravenel.com with comments, questions, or requests. Sincerely WithersRavenel G. Matthew James, PG Director of Geosciences Attachment C: Brad Beeson -Town of Kernersville, Solid Waste Superintendent 115 MacKenan Drive I Cary, NC 27511 t: 919.469.3340 1 f: 919.467.6008 1 www.withersravenel.com I License No. F-1479 Asheville I Cary I Greensboro I Pittsboro I Raleigh I Wilmington ■■ WithersRavenel 00 Our People. Your Success. FEBRUARY 2022 WATER QUALITY MONITORING REPORT Town of Kernersville Closed Landfill 9900 Freeman Road Kernersville, Forsyth County, North Carolina NCDEQ Permit ID #: 34-04 Prepared for: Town of Kernersville Public Works Department PO Box 728 Kernersville, North Carolina 27285 Prepared By: WithersRavenel, Inc. 115 MacKenan Drive Cary, North Carolina 27511 WR Project #: 06140180.48 June 29, 2022 Mati Maltba Environmental Technician I G. Matthew James, PG Director of Geosciences 0- s9-204 QQ s Lor. DP�� ` ■■ WithersRavenel .. Our People. Your Success. TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................................1 1.1 Site Information............................................................................................................................1 1.2 Site Geology and Hydrogeology....................................................................................................1 1.3 Regulatory Status..........................................................................................................................1 2.0 FACILITY MONITORING PROGRAM...................................................................................................3 2.1 Groundwater Monitoring Program...............................................................................................3 2.2 Surface Water Monitoring Program.............................................................................................3 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT.............................................................4 3.1 Field Services.................................................................................................................................4 3.2 Quality Control..............................................................................................................................5 4.0 ANALYTICAL RESULTS........................................................................................................................6 4.1 Groundwater.................................................................................................................................6 4.2 Surface Water...............................................................................................................................6 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION ...........................................................8 5.1 MINA Parameters...........................................................................................................................8 6.0 FINDINGS...........................................................................................................................................6 7.0 REFERENCES......................................................................................................................................7 Page i of ii ■■ WithersRavenel .. Our People. Your Success. Figures Figure 1 General Location Map Figure 2 Monitoring Well Location Map Figure 3A Potentiometric Map February 2022 Figure 3B Potentiometric Map July 2021 Figure 4 Groundwater 2L/GWP Exceedances Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents Appendices Appendix I Laboratory Analytical Reports and Field Notes Appendix II Historical Summary Tables (reproduced from Joyce Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Page ii of ii ■■ WithersRavenel .. Our People. Your Success. 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the Town of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5-minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina Quadrangle (Quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM), Solid Waste Section (Section) on May 15, 1985, and a Letter of Closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont Physiographic Province of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian -to -Permian age, which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well-connected. Groundwater at the site has historically been reported flowing generally to the southwest. Joyce Engineering (JOYCE) conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft. • An effective porosity value (n) of 30 percent was estimated. • Hydraulic conductivity (K) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. 1.3 Regulatory Status The Town of Kernersville (Town) is currently monitoring groundwater at the landfill in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. Samples are analyzed for all constituents listed in 40 CFR Part 258, Appendix I Constituents for Detection Monitoring ("Appendix I") and compared to the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the "2L Standards"); or, when a 2L Standard is not established, the Section's Groundwater Protection Standards (GWPs) or Interim Maximum Allowable Concentrations (IMACs). February 2022 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.48 June 2022 Page 1 of 7 ■■ WithersRavenel .. Our People. Your Success. Based on the presence of targeted Appendix I constituents detected at concentrations above the referenced standards that could potentially be crossing the facility boundary, the Section requested that the Town submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to the Section on May 13, 2013, and concluded that, based on site hydrogeology, it would be very unlikely that the site impacts at concentrations above their respective standards would cross the property boundaries. In a July 16, 2013, response to information presented in the Groundwater Assessment Report, the Section determined that, despite the conclusions presented in JOYCE's Groundwater Assessment Report, the detection of volatile organic compounds (VOCs) at concentrations that exceeded the referenced standards beyond the compliance boundary of the site constituted a violation of Section regulations. JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town in July 2014, which the Section approved on November 4, 2014. Note that the NCDENR is now doing business as the North Carolina Department of Environmental Quality (NCDEQ). On April 11, 2022 in response to the Corrective Action Evaluation Report dated March 19, 2022, the Town has requested to continue current monitoring procedures of Monitoring Natural Attenuation and Phytoremediation without modification. The Section approved the report with the following conditions: 1. Replacing or repairing the consistently dry monitoring well MW-1 before the end of 2022, 2. Including a new surface water sample location to the July 2022 monitoring event between existing surface water sample locations SW-2 and SW-3 in relation to protection of human health and the environment, and 3. Including the analysis of 1,4-Dioxane for the groundwater monitoring well and surface water samples in future semiannual monitoring events. February 2022 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.48 June 2022 Page 2 of 7 ■■ WithersRavenel .. Our People. Your Success. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background monitoring well MW-1 was replaced (by monitoring well MW-6) due to slow recharge in the well, low well volumes, or being dry during sampling events. Downgradient monitoring wells MW-2R, MW-3S, MW-3D, MW-4, and MW-5R are monitored for the Appendix I list of constituents as part of the compliance network for the facility. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2R, MW-3S, MW-3D, MW-4 and MW-6 are also periodically monitored for the following Monitored Natural Attenuation (MNA) constituents: • Nitrate, sulfate, chloride, sulfide, alkalinity, and • Total organic carbon (TOC); Groundwater samples collected semiannually are analyzed for the Appendix I list of constituents and periodically for the above -referenced MNA parameters. Sample analyses are then compared to the 2L Standards or IMACs or GWPs, where appropriate. 2.2 Surface Water Monitoring Program Surface water at the landfill is monitored semi-annually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Water Designation SW-1 SW-2 SW-3 Classification Upstream/Compliance Compliance Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semiannual monitoring events. Analytical results are compared to the Classifications and Water Quality Standards Applicable to Surface Waters of NC as listed in 15A NCAC 2B (213 Standards). February 2022 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.48 June 2022 Page 3 of 7 ■■ WithersRavenel .. Our People. Your Success. 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT 3.1 Field Services On February 3, 2021, WithersRavenel (WR) personnel mobilized to the facility to purge and sample monitoring wells MW-1, MW-2R MW-3S, MW-3D, MW-4, MW-5R, and MW-6 and sample surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01-foot. Due to the lack of water encountered within monitoring well MW-1, a sample was not collected for laboratory analysis. Table 2, Groundwater Surface Elevations presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top -of -well casing elevations reported by JOYCE in their 2015 reports. Figure 3A, Potentiometric Map (February 2022) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the February 2022 sampling event. Figure 313, Potentiometric Map (July 2021) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2021 sampling event. As shown on these figures and in recent sampling events, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of East Belews Creek. Table 3, Historical Groundwater Elevations presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR between 2016 and 2022. The monitoring wells were purged and sampled using either disposable bailers or submersible pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity, were recorded in the site -specific sampling forms after purging and before sampling. Groundwater Sampling Methods Groundwater samples from each monitoring well were collected directly from a submersible pump or decanted from disposable bailers into the laboratory -prepared and -provided containers immediately after purging. Samples were then placed into laboratory -provided coolers, chilled on ice to approximately 4°C, and delivered to a State of North Carolina -certified laboratory (Pace Laboratories) under standard Chain -of -Custody (COC) protocol. Field data logs are provided in the Appendix to this report. Surface Water Sampling Methods Surface water samples were collected either directly into laboratory -provided, non -preserved sample containers, or by decanting the sample from a non -preserved 1-Liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. When used, care was taken to not overfill the preserved sample containers (which could lead to preservative loss). To avoid sample -induced turbidity the were collected initially from the downstream sample location (previously designated SW-2 by others), and in sequence upstream, SW-3 and then SW-1 to reduce potential turbidity in the samples (Figure 2). After sample collection, the samples were placed in a laboratory -provided cooler, chilled on ice to approximately 4°C, and submitted to Pace Laboratories under standard COC protocol. February 2022 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.48 June 2022 Page 4 of 7 ■■ WithersRavenel .. Our People. Your Success. 3.2 Quality Control Two Trip Blanks were prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Trip Blanks were analyzed for VOCs only. February 2022 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.48 June 2022 Page 5 of 7 ■■ WithersRavenel .. Our People. Your Success. 4.0 ANALYTICAL RESULTS 4.1 Groundwater Groundwater samples were analyzed for the Appendix I list and the modified list of MNA constituents and compared to the respective 2L Standards or GWPs where appropriate. The following table provides a summary of the compounds detected above the current 2L Standard(s) or GWP(s) in the groundwater samples collected during the February 2022 event. Constituent Referenced Standard Compliance Wells (2L/GWP) MW-1 MW-2R MW-3S MW-31D MW-4 MW-5R MW-6 Benzene 1.0 Dry - Not Sampled 3.3 BDL 0.41 0.40 BDL BDL 1,1-Dichloroethane 6.0 10.6 0.530 1.3 1.4 BDL BDL 1,2-Dichloroethane 0.4 BDL BDL 0.47 BDL BDL BDL 1,2-Dichloropropane 0.6 3.50 BDL 0.84 BDL BDL BDL Vinyl chloride 0.03 4.0 1.2 4.2 10.7 BDL BDL Cadmium 2 1.9 24.4 BDL BDL 0.83 BDL Chromium 10 BDL 66.5 BDL 24.0 14.7 BDL Cobalt 1 4.0 33.1 0.31 4.4 16.3 0.78 Lead 15 BDL 27.6 BDL 5.6 37.8 BDL Vanadium 7 4.1 230 BDL 21.3 52.0 6.4 Zinc 1,000 11.2 2,510 BDL 20.4 125 BDL Notes: BDL Below Laboratory Method Detection Limit Result Result Exceeds 2L Standard or GWP All Concentration reported in µg/L Figure 4, Groundwater Standard Exceedances Map illustrates exceedances to the referenced standards at the monitoring well locations and Table 4, Groundwater Analytical Results provides a full summary of the results from the February 2022 sampling event. In general, the organic and inorganic results are consistent with historical data. Historical groundwater data, laboratory quality assurance/quality control information and the chain -of - custody records are included in the Appendix. 4.2 Surface Water Surface water samples were analyzed for the Appendix I list only. No analytes were detected at concentrations above the 213 Standards in surface water samples collected during the February 2022 sampling event. The results were consistent with historical data. Surface water data can be found in Table 5, Surface Water Analytical Results. The results, as reported by the laboratory, historical surface water data, the laboratory quality/assurance/quality control information, and the chain -of -custody records are included in February 2022 Water Quality Monitoring Report WR Project Number 06140180.48 Town of Kernersville Closed Landfill, Permit 34-04 June 2022 Page 6 of 7 ■■ WithersRavenel .. Our People. Your Success. the Appendix. February 2022 Water Quality Monitoring Report WR Project Number 06140180.48 Town of Kernersville Closed Landfill, Permit 34-04 June 2022 Page 7 of 7 ■■ WithersRavenel .. Our People. Your Success. 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION 5.1 MNA Parameters According to previous reports, in accordance with the facility CAP, MNA baseline sampling was initiated during the November 2014 sampling event and finished during the November 2015 sampling event. During those events, the full list of MNA parameters (shown below) were measured in samples collected from monitoring wells MW-2, MW-3S, MW-3D, and MW-4. MNA field (geochemical) parameters included: • Temperature • pH • Specific conductance • Oxidation-reduction potential (ORP) • Turbidity; and • Dissolved oxygen. Laboratory parameters included: • Biological Oxygen Demand (BOD) • Chemical Oxygen Demand (COD) • Dissolved hydrogen • Nitrate • Sulfate • Chloride • Alkalinity as CaCO3 • Sulfide • Total Organic Carbon (TOC) • Ethane, ethene, and methane; and • Volatile fatty acids. The full list of MNA parameters were not analyzed during the February 2022 sampling event. MNA parameters analyzed during the February 2022 sampling event are presented on Table 6, Summary of MNA Constituents, and included: • Chloride, • Nitrogen, Nitrate • Sulfate • Sulfide, and • Total Organic Carbon (TOC) Laboratory reports and field data forms are included in the Appendix. Analysis of the full list of MNA parameters is planned for the July 2022 event. February 2022 Water Quality Monitoring Report WR Project Number 06140180.48 Town of Kernersville Closed Landfill, Permit 34-04 June 2022 Page 8 of 7 ■■ WithersRavenel .. Our People. Your Success. 6.0 FINDINGS Target analytes detected above the established 2L Standards and/or GWPs in groundwater samples collected during the February 2022 sampling event appear to generally be consistent with previous events. One or more compounds were detected above the established 2L Standards and/or GWPs in monitoring wells MW-2R, MW-31D, MW-4, and MW-5R. Monitoring well MW-1 was not sampled as it was dry, and no compounds were reported in MW-6 at a concentration that exceeded the established 2L Standards and/or GWPs. No target analytes were detected in the surface water samples at concentrations above their respective 2B Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for July 2022. February 2022 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.48 June 2022 Page 6 of 7 ■■ WithersRavenel .. Our People. Your Success. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Drummond, Jaclynne. "Re: Closed Town of Kernersville MSW Landfill - WQ Parameter Clarification 06140180.33" Message to Laura Elliott, June 29, 2020. E-mail. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semiannual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semiannual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, 2016 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. Technical Protocol for Evaluation Natural Attenuation of Chlorinated Solvents in Groundwater, EPA/600/R-98/128, September 1998. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina WithersRavenel, Inc., 2017 Annual Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, April 2, 2018. -----, 2018 Annual Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, April 16, 2019 -----, July 2019 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34- 04, October 7, 2019 -----, January 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, March 6, 2020. -----, July 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34- 04, September 2, 2020. ----, January 2021 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, May 7, 2021 ----, July 2021 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34- 04, January 25, 2022 February 2022 Water Quality Monitoring Report WR Project Number 06140180.48 Town of Kernersville Closed Landfill, Permit 34-04 June 2022 Page 7 of 7 FIGURES % bum) 'A r 00 L 4, K, I;0 INN, % e STE DISPOSAL BOUNDARY j 01 A AW" -7, ------ Rb X -\I. tj SMOKE HOL R r CO "j X0 X., LI 'f'—) jI CALE rn RAPHIC S V 500 1000 2 0 oo 16- t Jl TOWN OF KERNERSVILLE DRAWN BY: SCALE: FIGURE NO.: 1/ 0 WithersRavenet CLOSED LANDFILL - PERMIT #34-04 MGM 1"=1000' GOODWILL CHURCH ROAD Engineers I Planners I Surveyors KERNERSVILLE, GUILFORD/FORSYTH COUNTY, NC APPROVED BY: DATE: PROJECT NO.: 115 VacKenan Drivel Cary, NC 275111 t: 919A69.3340 I license #: F-1479 I —withersravenel.com GENERAL LOCATION MAP mi 06/21/22 06140180.48 ft\14\14-01W\14018l)A8—T0"_&.D" L.WM S-1— FW 20n\E.*o\CAD\2M1.0821O..n.o—Ka,-"b Lan4l A— 21. 2022 — l Wn Ro A D V. 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Ware - ,wER. w7T Ro A D M W-4 (754.52) 770 76S (751.14) I W-21 Ul (759.65) <n MW-1 (DRY) >>c 0 I MW-5 V (769.54) a Ln MW-6 (790.61) U, ,fig t GOODWILL CHURCH ROAD a LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION II NOTES: GROUNDWATER SURFACE ELEVATION II CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION 1.) AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 POTENTIOMETRIC MAP MGM 1"=300' 313 1/ Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (JULY 2021) APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKcnan Drivc Cary, NC 27511 t 919.469.3340 license #: F-1479 www.withersraveneLcom Mi 06/21/22 06140180.48 Ik\14\14-0180\1401WA8-MJ4-9—M L-M 11-i . 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L-MA.o- A— 2. 2= - JIMM w7T F� ti Ro A D MW-3S Jul-21 Feb-22 21-s (ug/L) ANTIMONY 4.4 1 CADMIUM 7.95 24.4 2 CHROMIUM 15.6 66.5 10 COBALT 15.5 33.1 1 LEAD 12.5 27.6 15 THALLIUM 4.57 0.66 2 VANADIUM 76.8 230 7 ZINC 61`=' 2510 1000 VINYL CHLORIDE 1.13 1.2 0.03 MW-4 Jul-21 Feb-22 21-s (ug/L) CHROMIUM 12.1 24 10 COBALT 3.5 4.4 1 VANADIUM 17.2 21.3 7 VINYLCHLORIDE 9.62 10.7 0.03 ►m SW-2 0- rm"W,*, 4 m MW-3113 Jul-21 Feb-22 2Ls (ug/L) 1,2-DICHLOROETHANE 0.571 0.47 0.4 1,2-DICHLOROPROPANE 0.977 0.89 0.6 VINYL CHLORIDE 5.74 4.2 0.03 V`�3D P MW-3S MW-2R SW-3 1%, GOODWILL CHURCH ROAD MW-6 Jul-21 I Feb-22 21-s (ug/L) COBALTI 1.12 1 MW-6 \BMW-1 Jul-21 I Feb-22 NOT SAMPLED - DRY WELL MW-5 MW-5R Jul-21 Feb-22 2Ls (ug/L) ANTIMONY 11.8 BUL 1 CHROMIUM 11.3 14.7 10 COBALT 33.9 16.3 1 LEAD 99.5 37.8 15 VANADIUM 110 52 7 MW-2R Jul-21 Feb-22 2Ls (ug/L) COBALT 3.95 4.0 1 BENZENE 3.07 3.3 1 1,1-DICHLOROETHANE 9.24 10.6 6 1,2-DICHLOROETHANE 0.520 BDL 0.4 1,2-DICHLOROPROPANE 3.64 3.5 0.6 VINYL CHLORIDE 4.02 4.0 0.03 LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 SHALLOW MONITORING WELL ® DEEP MONITORING WELL Q SURFACE WATER SAMPLE LOCATION 11 NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) ONLY ANALYTICAL RESULTS THAT EXCEEDED THE 2L STANDARD ARE ILLUSTRATED. 4.) FOR WELLS FROM WHICH DUPLICATE SAMPLES WERE COLLECTED, THE HIGHEST DETECTED CONCENTRATION OF EACH CONTAMINANT IS SHOWN. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 GROUNDWATER 2L STANDARD/GWP EXCEEDANCES MGM 1"=300 4 1/ Engineers I Planners I Surveyors GOODWILL CHURCH ROAD MAP APPROVED BY: I DATE. PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive I Cary, NC 275111 t: 919.469.3340 1 license k: F-1479 I www.withersraveneLcom MJ 06/21/22 06140180.48 1O\74\14-0110\1401OM4$-TO/4Sw..M L-dM S-low M 2022\En*O\GDXMIA&23-BOMro -YAM410 LarANAha- Am 21. 2= - MALTM W71 TABLES TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft bTOC) Screen Interval (ft bTOC) Total Depth (ft bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 2 6.36 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 2 10.46 10.46 - 20.46 20.46 804.87 Notes: 1) ft-bTOC = Feet below top of casing 2) MSL = Mean sea level Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring 3) Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 2/3/2022 GROUNDWATER SCREENED TOP OF CASING DEPTH WELL ID INTERVAL ELEVATION SURFACE (ft-bTOC) (feet above MSL) WATERR ELEVATION (ft-bTOC) (feet above MSL) MW-1 24.96 - 34.96 806.42 DRY -- MW-2R 3.18 - 13.18 762.19 3.09 759.10 MW-3S 14.00 - 24.00 764.57 13.57 751.00 MW-3D 36.96 - 56.96 764.56 12.00 752.56 MW-4 4.40 - 14.40 760.26 6.17 754.09 MW-5 6.36 - 11.36 773.32 3.51 769.81 MW-6 10.46 - 20.46 804.87 17.23 787.64 Notes: 1) All measurements are in feet. 2) Elevation data is measured in feet above Mean Sea Level (MSL). 3) Depth to water measured in feet below top of casing (ft-bTOC) 4) "Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater(feet) Groundwater Elevation (feet) MW-1 806.42 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 9/13/2017 DRY DRY 7/10/2018 DRY DRY 1/9/2019 DRY DRY 7/24/2019 DRY DRY 1/8/2020 DRY DRY 7/15/2020 DRY DRY 1/13/2021 30.62 775.80 7/20/2021 DRY DRY 2/3/2022 DRY DRY MW-2R 762.19 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 9/13/2017 4.22 757.97 7/10/2018 4.41 757.78 1/9/2019 2.84 759.35 7/24/2019 3.40 758.79 1/8/2020 3.17 759.02 7/15/2020 3.02 759.17 1/13/2021 2.38 759.81 7/20/2021 2.54 759.65 2/3/2022 3.09 759.10 MW-3S 764.57 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 9/13/2017 14.29 750.28 7/10/2018 15.00 749.57 1/10/2019 12.50 752.07 7/24/2019 13.96 750.61 1/8/2020 13.23 751.34 7/15/2020 13.47 751.10 1/13/2021 12.89 751.68 7/20/2021 13.43 751.14 2/3/2022 13.57 751.00 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 1 of 3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-31D 764.56 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29/2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 9/13/2017 12.96 751.60 7/10/2018 15.00 749.56 1/10/2019 11.25 753.31 7/24/2019 11.86 752.70 1/8/2020 11.68 752.88 7/15/2020 11.94 752.62 1/13/2021 11.23 753.33 7/20/2021 11.30 753.26 2/3/2022 12.00 752.56 MW-4 760.26 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 9/13/2017 7.33 752.93 7/10/2018 7.00 753.26 1/9/2019 5.24 755.02 7/24/2019 5.89 754.37 1/8/2020 5.71 754.55 7/15/2020 6.04 754.22 1/13/2021 1 5.44 754.82 7/20/2021 5.74 754.52 2/3/2022 6.17 754.09 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 2of3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-5 773.32 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 9/14/2017 5.48 767.84 7/10/2018 NM NM 1/10/2019 10.50 762.82 7/24/2019 4.03 769.29 1/8/2020 3.54 769.78 7/15/2020 4.75 768.57 1/13/2021 3.75 769.57 7/20/2021 3.78 769.54 2/3/2022 3.51 769.81 MW-6 804.87 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 9/14/2017 20.64 784.23 7/10/2018 DRY DRY 1/9/2019 17.49 787.38 7/24/2019 16.51 788.36 1/8/2020 17.19 787.68 7/15/2020 15.97 788.90 1/13/2021 1 14.56 790.31 7/20/2021 14.26 790.61 2/3/2022 17.23 787.64 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 3of3 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA6010 C V E E j ++ E E E Contaminant Of Concern E v '- E £ a ° " > a m 0 O � Z N s IV a co u u CAS # 7440-36-0 7440-38-2 1 7440-39-3 1 7440-41-7 1 7440-43-9 1 7440-47-3 1 7440-48-4 1 7440-50-8 1 7439-92-1 1 7440-02-0 1 7782-49-2 1 7440-22-4 1 7440-28-0 1 7440-62-2 1 7440-66-6 Well ID Date Collected Res &I Quail Result Quail Result Quail Result Quail Result Quail It Qual Result Qual Result Qual Result Quail Result Qu Qual Result Qual Result Quail Result Quail Result Qua 7/20/2021 DRY - NOT SAMPLED MW-1 2/3/2022 DRY - NOT SAMPLED 7/20/2021 <4.30 <4.40 253 0.333 J 0.504 J 2.15 J 3.95 J <3.68 3.25 J <1.61 <7.35 <1.54 <4.31 6.89 J 7.27 J MW-2R 2/3/2022 <3.0 5.7 J 222 <0.70 1.9 <3.7 4.0 <4.3 <4.5 <3.5 <4.7 1 <2.5 1 <0.050 4.1 J 11.2 7/20/2021 4.40 J <4.40 236 0.880 J 7.95 15.6 15.5 44.7 12.5 8.10 J <7.35 <1.54 4.57 BJ 76.8 619 MW-3S 2/3/2022 <3.0 7.4 J 402 0.92 J 24.4 66.5 33.1 146 27.6 33.5 4.9 J <2.5 0.66 230 2510 7/20/2021 <4.30 <4.40 38.0 <0.330 <0.479 <1.40 <0.840 <3.68 3.43 J <1.61 <7.35 <1.54 <4.31 6.52 J <6.52 MW-3D 2/3/2022 <3.0 6.6 J 44.6 <0.70 <0.40 <3.7 0.31 J <4.3 <4.5 <3.5 <4.7 <2.5 <0.050 <3.9 <9.5 7/20/2021 5.65 J <4.40 49.2 <0.330 <0.479 <1.40 <0.840 <3.68 <2.99 <1.61 <7.35 <1.54 <4.31 7.49 J <6.52 Duplicate (MW-3D) 2/3/2022 <3.0 <4.7 45.6 <0.70 <0.40 1 <3.7 0.30 J <4.3 <4.5 1 <3.5 <4.7 <2.5 <0.050 <3.9 <9.5 7/20/2021 <4.30 <4.40 127 <0.330 0.580 J 12.1 3.50 J 6.32 J 5.96 J 3.84 J <7.35 <1.54 <4.31 17.2 J 20.1 J MW-4 2/3/2022 <3.0 6.1 J 122 <0.70 <0.40 24.0 4.4 10.9 5.6 5.5 4.9 J <2.5 0.072 J 21.3 20A 7/20/2021 11.8 <4.40 268 2.93 1.05 J 11.3 33.9 35.9 99.5 6.56 J <7.35 <1.54 <4.31 110 327 MW-5R 2/3/2022 <3.0 7.2 J 159 <0.70 0.83 J 14.7 16.3 34.1 37.8 7.3 <4.7 <2.5 0.29 J 52.0 125 7/20/2021 <4.30 <4.40 50.3 <0.330 <0.479 1.99 J 1.12 J <3.68 5.68 J <1.61 <7.35 <1.54 <4.31 6.69 J 7.56 J MW-6 2/3/2022 <3.0 <4.7 102 <0.70 <0.40 <3.7 0.78 J <4.3 <4.5 <3.5 <4.7 <2.5 0.091 J 6.4 <9.5 7/20/2021 NA NA NA NA 4 NA NA NA NA NA NA NA NA NA NA NA Trip Blank 2/3/2022 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2L Standard/GWP (µg/L) 10 700 4 2 30 1 1,000 15 100 20 20 2 L_K7 1,00 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. Qualifiers NA Not Analyzed by Method Shown J Estimated concentration above the adjused method detection limit and below the adjusted reporting limit. Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Page 1 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA8260 v � � � C � � v s aL+ Lu C N W a)E £ ra N L u W C C & C O O O +' N y N � N i C s O w Contaminant Of Concern .2£W E c o O o Q u O E O Ou U -0 O U £ E m U V U a o N U m m CAS # 67-64-1 107-13-1 71-43-2 1 74-97-5 1 75-27-4 1 75-25-2 1 74-83-9 78-93-3 135-98-8 75-15-0 1 56-23-5 1 108-90-7 1 75-00-3 67-66-3 Well ID Date Colle I Result Qual Result Qual Result Qual Result I Qual I J1111111MILt Qual Result I Qual Result Qual Result Qual Result Qual iiMii Qual Result Qual 7/20/2021 DRY - NOT SAMPLED MW-1 2/3/2022 DRY - NOT SAMPLED 7/20/2021 <11.3 <0.671 3.07 NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 0.155 J <0.192 <0.111 MW-2R 2/3/2022 <5.1 <1.8 3.3 <0.47 <0.31 <0.34 <1.7 <4.0 NA <0.73 <0.33 <0.28 <0.65 1 <0.43 7/20/2021 34.9 J <0.671 0.284 J NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 1.55 0.410 J <0.111 MW-3S 2/3/2022 14.6 J <1.8 <0.34 <0.47 <0.31 <0.34 <1.7 <4.0 NA <0.73 <0.33 1.1 <0.65 <0.43 7/20/2021 <11.3 <0.671 0.451 J NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 0.583 J 0.362 J <0.111 MW-3D 2/3/2022 <5.1 <1.8 0.41 J <0.47 <0.31 <0.34 <1.7 <4.0 NA <0.73 <0.33 0.53 J <0.65 <0.43 7/20/2021 <11.3 <0.671 0.472 J NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 0.566 J 0.334 J <0.111 Duplicate (MW-3D) 2/3/2022 <5.1 <1.8 0.41 J <0.47 <0.31 1 <0.34 1 <1.7 1 <4.0 NA <0.73 <0.33 0.49 J <0.65 <0.43 7/20/2021 <11.3 <0.671 0.384 J NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 0.163 J 0.606 J <0.111 MW-4 2/3/2022 <5.1 <1.8 0.40 J <0.47 <0.31 <0.34 <1.7 <4.0 NA <0.73 <0.33 <0.28 0.81 J <0.43 7/20/2021 <11.3 <0.671 <0.0941 NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 <0.116 <0.192 <0.111 MW-5R 2/3/2022 <5.1 <1.8 <0.34 <0.47 <0.31 <0.34 <1.7 <4.0 NA <0.73 <0.33 <0.28 <0.65 <0.43 7/20/2021 <11.3 <0.671 <0.0941 NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 <0.116 <0.192 <0.111 MW-6 2/3/2022 <5.1 <1.8 <0.34 <0.47 <0.31 <0.34 <1.7 <4.0 NA <0.73 <0.33 <0.28 <0.65 <0.43 7/20/2021 <11.3 <0.671 <0.0941 NA NA <0.129 <0.605 <1.19 <0.125 NA <0.128 <0.116 <0.192 <0.111 Trip Blank 2/3/2022 <5.1 <t a <0.34 <0.47 <0.31 <0.34 <1.7 <4.0 <0.73 <0.33 <0.28 <0.65 <0.43 2L Standard/GWP (µg/L) L 6,000 NE 1 0.6 4 0.6 14 JU 10 1 4.000 1 70 1 700 0 3,000 1 70 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J Estimated concentration above the adjused method detection limit and below the adjusted reporting limit. Page 2 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA8260 c v a� m C a W C N C W 7 W W 4) N t N aL+ y O Y C t tOo tcc f0 O E O N N0 O `o Contaminant Of Concern v E u o o `o o L ° o o z t E Cl)° o o p o u u p 0 s U p E �_ 0 N a-i N Cli ut 0 Q N.0 e-i ati e-i i N 74-87-3 96-12-8 124-48-1 1 106-93-4 1 74-95-3 1 95-50-1 1 106-46-7 1 110-57-6 1 75-34-3 1 107-06-2 1 75-35-4 1 156-59-2 156-60-5 Well ID Result Qual Result Qual Result Qual Qual Result Qual Result Qual Result Qual Result Qual Result Qual Qual Result Qual Result Qual Result Qua 7/20/2021 DRY - NOT SAMPLED MW-1 2/3/2022 DRY - NOT SAMPLED 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 0.215 J 4.81 NA 9.24 0.520 J <0.188 C3 26.2 0.850 J MW-2R 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 3.8 <0.56 10.6 <0.32 <0.35 30.3 0.820 J 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 0.116 J <0.120 NA 0.451 J 0.272 J <0.188 C3 0.984 J <0.149 MW-3S 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 1.7 <0.56 0.530 J <0.32 <0.35 1.6 <0.40 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 0.174 J 5.00 NA 1.26 0.571 J <0.188 C3 8.81 <0.149 MW-3D 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 3.8 <0.56 1.3 0.47 J <0.35 9.8 <0.40 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 0.168 J 4.87 NA 1.19 0.530 J <0.188 C3 7.58 <0.149 Duplicate (MW-3D) 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 3.8 <0.56 1 1.2 <0.32 <0.35 9.5 <0.40 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 <0.107 <0.120 NA 1.15 <0.0819 <0.188 C3 14.4 <0.149 MW-4 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 1.9 <0.56 1.4 <0.32 <0.35 1 16.8 <0.40 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 <0.107 <0.120 NA <0.100 <0.0819 <0.188 C3 <0.126 <0.149 MW-5R 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 <0.33 <0.56 <0.37 <0.32 <0.35 <0.38 <0.40 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 <0.107 <0.120 NA <0.100 <0.0819 <0.188 C3 <0.126 <0.149 MW-6 2/3/2022 <0.54 <0.34 <0.36 <0.27 <0.39 <0.34 <0.33 <0.56 <0.37 <0.32 <0.35 <0.38 <0.40 7/20/2021 <0.960 <0.276 <0.140 <0.126 <0.122 <0.107 <0.120 NA <0.100 <0.0819 <0.188 C3 <0.126 <0.149 Trip Blank 2/3/2022 1 <0.54 1 <0.34 1 <0.36 1 1 <0.27 1 1 <0.39 1 1 <0.34 <0.33 <0.56 <0.37 <0.32 <0.35 <0.38 <0.40 2L Standard/GWP (µg/L) 1 3 0.04 1 0.4 1 0.02 E 703 20 6 0.4 350 70 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Estimated concentration above the adjused method detection limit and below the adjusted reporting limit. Page 3 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA W R Project # 06140180.48 Analytical Method EPA8260 Y c o o o w y v c O C. O N C C N O O pp 7• C O O L G O as+ N O R C O r t V C G) 41 p O O y N C Contaminant Of Concern O p N C C ++ C Y m R L S O O O cu L. LO£ O O . O O. ~ y ~O p w N O C O Z It ~ i p Cli N yN CAS # 78-87-5 1 10061-01-5 1 10061-02-6 1 108-20-3 1 100-41-4 1 591-78-6 1 74-88-4 1 98-82-8 1 99-87-6 1 75-09-2 1 108-10-1 1634-04-4 91-20-3 1 100-42-5 1 630-20-6 1 79-34-5 1 127-18-4 1 108-88-3 Date Collected Result Qual AIIIIIIIIIIIIIIIIIII Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual R esult Qual Result Qual Result Qual Result I Qual I dJ111111hLQual JJ§NJ§hLQuaI 7/20/2021 DRY - NOT SAMPLED MW-1 2/3/2022 DRY - NOT SAMPLED 7/20/2021 3.64 <0.111 <0.118 0.241 J <0.137 NA NA 0.421 J <0.120 <0.430 <0.478 0.313 J <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 MW-2R 2/3/2022 3.50 <0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA <2.0 <2.7 NA NA <0.29 <0.31 <0.22 <0.29 <0.48 7/20/2021 0.394 J <0.111 <0.118 <0.105 <0.137 NA NA <0.105 <0.120 <0.430 <0.478 0.187 J <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 MW-3S 2/3/2022 <0.36 <0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA <2.0 <2.7 NA NA <0.29 <0.31 <0.22 <0.29 0.60 J 7/20/2021 0.977 J <0.111 <0.118 <0.105 <0.137 NA NA <0.105 <0.120 <0.430 <0.478 0.360 J <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 MW-3D 2/3/2022 0.84 J <0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA <2.0 <2.7 NA NA <0.29 <0.31 <0.22 <0.29 <0.48 7/20/2021 0.959 J <0.111 <0.118 <0.105 <0.137 NA NA <0.105 <0.120 <0.430 <0.478 0.303 J <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 Duplicate (MW-3D) 2/3/2022 0.89 J <0.36 <0.36 NA <0.30 <0.48 1 <9.7 1 NA NA <2.0 <2.7 NA NA <0.29 1 <0.31 <0.22 <0.29 1 <0.48 7/20/2021 0.286 J <0.111 <0.118 <0.105 <0.137 NA NA 0.118 J <0.120 <0.430 <0.478 0.243 J <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 MW-4 2/3/2022 <0.36 <0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA <2.0 <2.7 NA NA <0.29 <0.31 <0.22 <0.29 <0.48 7/20/2021 <0.149 <0.111 <0.118 <0.105 0.139 J NA NA <0.105 <0.120 <0.430 <0.478 <0.101 <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 MW-5R 2/3/2022 <0.36 <0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA <2.0 <2.7 NA NA <0.29 <0.31 <0.22 <0.29 <0.48 7/20/2021 <0.149 <0.111 <0.118 <0.105 1.02 NA NA <0.105 <0.120 <0.430 <0.478 <0.101 <1.00 <0.118 <0.147 <0.133 <0.300 7.10 MW-6 2/3/2022 <0.36 <0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA <2.0 <2.7 NA NA <0.29 <0.31 <0.22 <0.29 <0.48 7/20/2021 <0.149 <0.111 <0.118 <0.105 <0.137 NA NA <0.105 <0.120 <0.430 <0.478 <0.101 <1.00 <0.118 <0.147 <0.133 <0.300 <0.278 Trip Blank 2/3/2022 <0.36 0.36 <0.36 NA <0.30 <0.48 <9.7 NA NA 7 NA NA <0.29 <0.31 <0.22 Li <0.29 <0.48 2LStandard/GWP (µg/L) .6 0.4 70 600 40 NE 25 5 100 20 70 1 0.2 1 0.7 600 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J Estimated concentration above the adjused method detection limit and below the adjusted reporting limit. Page 4 of 5 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA W R Project # 06140180.48 Analytical Method EPA 8260 R +� �• y N N N 0 o s E o C +' T T T y O F Contaminant Of Concern s L L 3 ° m E cu E u c " E c17 e- N ._ O H F F F > > X L U M C9 Lf N N N CM CAS # 71-55-6 79-00-5 1 79-01-6 1 75-69-4 1 96-18-4 95-63-6 526-73-8 108-67-8 1 108-05-4 1 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Qual Result Qual Result Qual dnn�ua 7/20/2021 DRY-NOTSAMPi D MW 1 2/3/2022 DRY - NOT SAMPLED 7/20/2021 <0.149 <0.158 0.700 J 0.160 C3 J <0.237 <0.322 <0.104 <0.104 NA 4.02 C3 <0.174 MW-2R 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA NA NA <1.3 4.0 <0.34 7/20/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 <0.322 <0.104 <0.104 NA 1.13 C3 <0.174 MW-3S 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA NA NA <1.3 1.2 <0.34 7/25/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 <0.322 <0.104 <0.104 NA 5.74 C3 0.390 J MW-3D 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA NA NA <1.3 4.2 <0.34 7/20/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 <0.322 <0.104 <0.104 NA 5.73 C3 0.936 J Duplicate (MW-3D) 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA NA NA 1 <1.3 4.1 <0.34 7/20/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 4 <0.104 NA 9.62 C3 <0.174 MW-4 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA <1.3 10.7 <0.34 7/20/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 4 <0.104 NA <0.234 C3 <0.174 MW-5R 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA <1.3 <0.39 <0.34 7/20/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 MNANA 04 <0.104 NA <0.234 C3 <0.174 MW-6 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA <1.3 <0.39 <0.34 7/20/2021 <0.149 <0.158 <0.190 <0.160 C3 <0.237 04 <0.104 NA <0.234 C3 <0.174 Trip Blank 2/3/2022 <0.33 <0.32 <0.38 <0.30 <0.26 NA <1.3 <0.39 <0.34 2LStandard/GWP (µg/L) 00 0.6 3 2,000 0.005 1 400 N 400 883 0.03 500 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J The identification of the analyte is acceptable; the reported value is an estimate. C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. Page 5 of 5 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 6010 T E E E E E Contaminant Of Concern E ' 3 E ° Y a`, ° c Q Q m y ° u° o Z 0 in r N m U u u ,,, CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/20/2021 4.31 J 4.40 36.6 <0.330 <0.479 1.71 J <3.68 3.02 J 1.61 7.35 <1.54 <4.31 <6.25 SW-1 2/3/2022 <3.0 <4.7 31.4 <0.70 <0.40 <3.7 0.99 J <4.3 <4.5 <3.5 <4.7 <2.5 <0.050 5.8 <9.5 7/20/2021 <4.30 <4.40 41.1 <0.330 <0.479 1.69 J 1.44 J <3.68 <2.99 <1.61 <7.35 <1.54 <4.31 <6.25 SW-2 2/3/2022 <3.0 <4.7 37.2 <0.70 <0.40 <3.7 1.3 <4.3 <4.5 <3.5 <4.7 <2.5 <0.050 6.3 <9.5 7/20/2021 <4.30 <4.40 38.4 <0.330 <0.479 <1.40 0.866 J <3.68 <2.99 <1.61 <7.35 <1.54 <4.31 6.86 J <6.25 SW-3 2/3/2022 <3.0 <4.7 35.1 n 7n n 40 ,2 7 4.5 <3.5 <4 7 <0.050 7.0 213 Standard /L 21000 1 65 1 0.82 1 183.07 ` 16 AM= 3.64 ` 13.88 ` 144.92 ` 5 0.30 ' E NE 36.2 N otes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 213 Standard = Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. * Hardness -Dependent 15A NCAC 02B Water Quality Standard, Calculated with default in -stream hardness of 25 mg/L Qualifiers J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 213 Standard Page 1 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA8260 C CL v c c f6 y o a v `o E E w y c E 0 w w N -^ c ° y y Contaminant Of Concern v o c r c c c 2 E CV) Q °° c Q o c m o o t u r E E m m U U U U o 22 O N U o pp m N ai CAS # 67-64-1 107-13-1 71-43-2 74-97-5 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 96-12-8 Well ID Date Collected Result Qual Result Qua[ Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result QualtResultQual Result Qual Result Qual Result Qual 7/20/2021 <11.3 <0.671 <0.0941 NA NA <0.129 <0.605 <1.19 <0.128 <0.116 <0.111 <0.960 <0.276 SW 1 2/3/2022 <5.1 <1.8 <0.34 <0.47 <0.31 <0.34 <1.7 <4.0 v1 <0.73 IK <0.33 <0.28 <0.43 <0.54 <0.34 7/20/2021 <11.3 <0.671 <0.0941 NA NA <0.129 <0.605 <1.19 NA <0.128 <0.116 <0.111 <0.960 <0.276 SW 2 2/3/2022 <5.1 <1.8 <0.34 <0.47 <0.31 <0.34 <1.7 <4.0 v1 <0.73 IK <0.33 <0.28 <0.43 <0.54 <0.34 7/20/2021 <11.3 <0.671 <0.0941 NA NA <0.129 <0.605 <1.19 NA <0.128 <0.116 <0.111 <0.960 <0.276 SW-3 2/3/2022 <1.8 <0.34 ^ <0.31 <0.34 <1.7 7n 0 v1 <0.? K <0.3, Q <0.65 <0.43 <0.54 0.34 2BStandard /L 2000 E NE NE NE 260 100 560 140 NE E I NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 213 Standard = Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 213 Standard Qualifiers v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. IK The recalculated concentrations of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. Page 2 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA8260 v L W N C C C O L O C C O. O W r L N N N +L+ +L+ aL+ C O O O. p W O O O i O O OL Contaminant Of Concern C p O O O L O O O p L L U O p L C O O O U_ U_ U O -2 U p O U_ U_ Q Q � 2 Q Q L 0 �_ -0 Q Q � Q Q Q N M M a+ W OL Q Q CV p.i eti N ei e-I ,n N e-I CV e-i e-i C a-i e-i a-i u i ri in r e i r Y a+ u Y CAS # 124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41 4 Well ID Date Collected Result Qual Result Qua[ Result Qual Result Qual Result Qual Result Qual Result Qua] Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 7/20/2021 <0.140 <0.126 <0.122 <0.107 0.120 NA <0.100 <0.0819 <0.188 C3 <0.126 <0.149 <0.149 <0.111 <0.118 <0.137 SW 1 2/3/2022 <0.36 <0.27 <0.39 <0.34 <0.33 <0.56 <0.37 <0.32 <0.35 <0.38 <0.40 <0.36 <0.36 <0.36 <0.30 7/20/2021 <0.140 <0.126 <0.122 <0.107 <0.120 NA <0.100 <0.0819 <0.188 C3 <0.126 <0.149 <0.149 <0.111 <0.118 <0.137 SW-2 2/3/2022 <0.36 <0.27 <0.39 <0.34 <0.33 <0.56 <0.37 <0.32 <0.35 <0.38 <0.40 <0.36 <0.36 <0.36 <0.30 7/20/2021 <0.140 <0.126 <0.122 <0.107 <0.120 NA <0.100 <0.0819 <0.188 C3 <0.126 <0.149 <0.149 <0.111 <0.118 <0.137 SW-3 2/3/2022 <0.36 <0.27 <0.39 <0.34 <0.3' <0.56 <0.37 <0.32 <U? n 2Q n nn <0.36 <0.36 'n W 'n 'n 2B Standard /L E 470 100 NE NE NE NE 97 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 213 Standard = Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 213 Standard Qualifiers C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. Page 3 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA8260 m ° ° C C O C O O t N a0+ "G + c ° N N +' ate+ L a+ V C L L O C O O O i Contaminant Of Concern E o. ° `o ' r U ° O U -' u E U T _ 0 L N V W W H H H L u O C N N L >a a~ N 0 F7 , ' T X N N a-i N N N H i..i iy H L U Cl N G F- Nr a-i a-i CAS # 591-78-6 74-88-4 75-09-2 108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 71-55-b 79-00-5 79-01-b 75-69-4 96-18-4 108-05-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result I Qual Result Qual 7/20/2021 <0.430 <0.478 <0.118 <0.147 <0.133 <0.300 <0.278 <0.149 <0.158 <0.190 <0.160 C3 <0.237 NA <0.234 C3 A174 SW-1 2/3/2022 <0.48 <9.7 <2.0 <2.7 <0.29 <0.31 <0.22 <0.29 <0.48 <0.33 <0.32 <0.38 <0.30 <0.26 <1.3 L1,v1 <0.39 <0.34 7/20/2021 NA NA <0.430 <0.478 <0.118 <0.147 <0.133 <0.300 <0.278 <0.149 <0.158 <0.190 <0.160 C3 <0.237 NA <0.234 C3 <0.174 SW 2 2/3/2022 <0.48 7 <9"NA <2.0 <2.7 <0.29 <0.31 <0.22 <0.29 <0.48 <0.33 <0.32 <0.38 <0.30 <0.26 <1.3 L1,v1 <0.39 <0.34 7/20/2021 NA <0.430 <0.478 <0.118 <0.147 <0.133 <0.300 <0.278 <0.149 <0.158 <0.190 <0.160 C3 <0.237 NA <0.234 C3 <0.174 SW-3 2/3/2022 0.48 n <2 7 n o n <0.22 <0.29 <0.48 <0.33 n n 2R <0.30 <0.26 <1.3 L1,v1 <0.39 <0.3/1 2B Standard /L 11000 26,000 NE NE 1 00 2300 2.5 670 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Resul J Result Exceeds 213 Standard Qualifiers C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. L1 Analyte recovery in the laboratory control sample (LCS) was above QC Limits. Results for this analyte in associated samples may be biased high. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. Page 4 of 4 TABLE 6 SUMMARY OF MNA CONSTITUENTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 300.0 EPA 353.2 SM 2320B SM 4500-CI-E SM 4500-S2D SM 5310B U 41 °� *' +� �a M OU 'a r- to 0 U Contaminant Of Concern 4- o o O O cn ZZ 41 Q0U v toU41 0 H CAS # 14808-79-8 NA NA 16887-00-6 18496-25-8 7440-44-0 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-2R 7/20/2021 986 J 141,000 10,500 1,170 B 2/3/2022 <500 <3.3 10,000 <500 MW-3S 7/20/2021 938 J <48.0 167,000 36,500 3,020 B 2/3/2022 3550 <3.3 34,400 1 2,960 MW-31D 7/20/2021 858 J < 178,000 27,000 1,460 B 2/3/2022 549 J 30 200 <5u.0 825 J 7/20/2021 NA NA NA Duplicate (MW-3D) 2/3/2022 585 J 3.4 J 30,400 816 J MW-4 7/20/2021 662 J 189,000 24,000 1,250 B 2/3/2022 <500 24 600 670 J 7/20/2021 NA NA MW-5R 2/3/2022 9770 3,200 6,010 MW-6 7/20/2021 5,130 9,960 J 1,550 2,280 B 2/3/2022 1 5,070 1 1600 749 J 2L Standard/GWP (µg/L) 1 250,000 10,000 NE 250,000 NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 4) NE = Not Established 5) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2L Standard or GWP J The identification of the analyte is acceptable; the reported value is an estimate. Page 1 of 1 APPENDIX I Laboratory Analytical Reports and Field Notes leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 22, 2022 Mark Brown Withers & Ravenel 7011 Albert Pick Rd Suite G Greensboro, NC 27409 RE: Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Dear Mark Brown: Enclosed are the analytical results for sample(s) received by the laboratory on February 04, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is attached to this report in its entirety. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Laura Elliott, Withers Ravenel REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 58 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification M 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Lab ID Sample ID Matrix Date Collected Date Received 92586338001 MW-2R Water 02/03/2212:00 02/04/2211:10 92586338002 MW-3S Water 02/03/2212:20 02/04/2211:10 92586338003 MW-313 Water 02/03/2211:20 02/04/2211:10 92586338004 MW-4 Water 02/03/2211:05 02/04/2211:10 92586338005 MW-5 Water 02/03/2213:45 02/04/2211:10 92586338006 MW-6 Water 02/03/2213:20 02/04/2211:10 92586338007 DUPLICATE Water 02/03/2211:30 02/04/2211:10 92586338008 SW-1 Water 02/03/2212:30 02/04/2211:10 92586338009 SW-2 Water 02/03/2212:10 02/04/2211:10 92586338010 SW-3 Water 02/03/2212:25 02/04/2211:10 92586338011 TRIP BLANK (X2) Water 02/03/22 00:00 02/04/22 11:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: KERNERSVILLE LANDFILL 92586338 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92586338001 MW-2R SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338002 MW-3S SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338003 MW-31) SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338004 MW-4 SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338005 MW-5 SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338006 MW-6 SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338007 DUPLICATE SM 4500-NO2 B-2011 DAW 1 PASI-E EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 531OB-2014 MDW 1 PASI-A 92586338008 SW-1 EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C 92586338009 SW-2 EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C 92586338010 SW-3 EPA 601 OD RDT 13 PASI-A EPA 6020E JOR 2 PASI-A EPA 8260D BSH 50 PASI-C 92586338011 TRIP BLANK (X2) EPA 8260D BSH 50 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-2R Lab ID: 92586338001 Collected: 02/03/22 12:00 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite ND mg/L 0.010 0.0033 1 02/04/22 20:39 14797-65-0 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:17 7440-36-0 Arsenic 5.7J ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:08 7440-38-2 Barium 222 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:17 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:17 7440-41-7 Cadmium 1.9 ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:17 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:17 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:17 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:17 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:17 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:17 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:17 7440-22-4 Vanadium 4.1J ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:17 7440-62-2 Zinc 11.2 ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 4.0 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 02:23 7440-48-4 Thallium ND ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 02:23 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 17:08 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 17:08 107-13-1 Benzene 3.3 ug/L 1.0 0.34 1 02/08/22 17:08 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 17:08 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 17:08 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 17:08 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 17:08 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 17:08 78-93-3 v1 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 17:08 75-15-0 IK Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 17:08 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 17:08 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 17:08 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 17:08 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 17:08 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 17:08 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 17:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 17:08 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 17:08 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 17:08 95-50-1 1,4-Dichlorobenzene 3.8 ug/L 1.0 0.33 1 02/08/22 17:08 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-2R Lab ID: 92586338001 Collected: 02/03/22 12:00 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2217:08 110-57-6 10.6 ug/L 1.0 0.37 1 02/08/2217:08 75-34-3 ND ug/L 1.0 0.32 1 02/08/2217:08 107-06-2 ND ug/L 1.0 0.35 1 02/08/2217:08 75-35-4 30.3 ug/L 1.0 0.38 1 02/08/2217:08 156-59-2 0.82J ug/L 1.0 0.40 1 02/08/2217:08 156-60-5 3.5 ug/L 1.0 0.36 1 02/08/2217:08 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 17:08 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2217:08 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2217:08 100-41-4 ND ug/L 5.0 0.48 1 02/08/2217:08 591-78-6 ND ug/L 20.0 9.7 1 02/08/2217:08 74-88-4 ND ug/L 5.0 2.0 1 02/08/2217:08 75-09-2 ND ug/L 5.0 2.7 1 02/08/2217:08 108-10-1 ND ug/L 1.0 0.29 1 02/08/2217:08 100-42-5 ND ug/L 1.0 0.31 1 02/08/2217:08 630-20-6 ND ug/L 1.0 0.22 1 02/08/2217:08 79-34-5 ND ug/L 1.0 0.29 1 02/08/2217:08 127-18-4 ND ug/L 1.0 0.48 1 02/08/2217:08 108-88-3 ND ug/L 1.0 0.33 1 02/08/2217:08 71-55-6 ND ug/L 1.0 0.32 1 02/08/2217:08 79-00-5 ND ug/L 1.0 0.38 1 02/08/2217:08 79-01-6 ND ug/L 1.0 0.30 1 02/08/2217:08 75-69-4 ND ug/L 1.0 0.26 1 02/08/2217:08 96-18-4 ND ug/L 2.0 1.3 1 02/08/2217:08 108-05-4 4.0 ug/L 1.0 0.39 1 02/08/2217:08 75-01-4 ND ug/L 1.0 0.34 1 02/08/2217:08 1330-20-7 105 % 70-130 1 02/08/2217:08 460-00-4 110 % 70-130 1 02/08/2217:08 17060-07-0 105 % 70-130 1 02/08/2217:08 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 02/09/22 03:09 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 10 mg/L 1.0 0.60 1 02/17/2213:43 16887-00-6 ND ug/L 1000 500 1 02/17/2213:43 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville ND ug/L 1000 500 1 02/12/22 09:45 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 7 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-3S Lab ID: 92586338002 Collected: 02/03/22 12:20 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite ND mg/L 0.010 0.0033 1 02/04/22 20:41 14797-65-0 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:20 7440-36-0 Arsenic 7.4J ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:12 7440-38-2 Barium 402 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:20 7440-39-3 Beryllium 0.92J ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:20 7440-41-7 Cadmium 24.4 ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:20 7440-43-9 Chromium 66.5 ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:20 7440-47-3 Copper 146 ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:20 7440-50-8 Lead 27.6 ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:20 7439-92-1 Nickel 33.5 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:20 7440-02-0 Selenium 4.9J ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:20 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:20 7440-22-4 Vanadium 230 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:20 7440-62-2 Zinc 2510 ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 33.1 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 02:43 7440-48-4 Thallium 0.66 ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 02:43 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 14.6J ug/L 25.0 5.1 1 02/08/22 17:25 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 17:25 107-13-1 Benzene ND ug/L 1.0 0.34 1 02/08/22 17:25 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 17:25 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 17:25 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 17:25 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 17:25 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 17:25 78-93-3 v1 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 17:25 75-15-0 IK Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 17:25 56-23-5 Chlorobenzene 1.1 ug/L 1.0 0.28 1 02/08/22 17:25 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 17:25 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 17:25 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 17:25 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 17:25 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 17:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 17:25 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 17:25 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 17:25 95-50-1 1,4-Dichlorobenzene 1.7 ug/L 1.0 0.33 1 02/08/22 17:25 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-3S Lab ID: 92586338002 Collected: 02/03/22 12:20 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2217:25 110-57-6 0.53J ug/L 1.0 0.37 1 02/08/2217:25 75-34-3 ND ug/L 1.0 0.32 1 02/08/2217:25 107-06-2 ND ug/L 1.0 0.35 1 02/08/2217:25 75-35-4 1.6 ug/L 1.0 0.38 1 02/08/2217:25 156-59-2 ND ug/L 1.0 0.40 1 02/08/2217:25 156-60-5 ND ug/L 1.0 0.36 1 02/08/2217:25 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 17:25 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2217:25 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2217:25 100-41-4 ND ug/L 5.0 0.48 1 02/08/2217:25 591-78-6 ND ug/L 20.0 9.7 1 02/08/2217:25 74-88-4 ND ug/L 5.0 2.0 1 02/08/2217:25 75-09-2 ND ug/L 5.0 2.7 1 02/08/2217:25 108-10-1 ND ug/L 1.0 0.29 1 02/08/2217:25 100-42-5 ND ug/L 1.0 0.31 1 02/08/2217:25 630-20-6 ND ug/L 1.0 0.22 1 02/08/2217:25 79-34-5 ND ug/L 1.0 0.29 1 02/08/2217:25 127-18-4 0.60J ug/L 1.0 0.48 1 02/08/2217:25 108-88-3 ND ug/L 1.0 0.33 1 02/08/2217:25 71-55-6 ND ug/L 1.0 0.32 1 02/08/2217:25 79-00-5 ND ug/L 1.0 0.38 1 02/08/2217:25 79-01-6 ND ug/L 1.0 0.30 1 02/08/2217:25 75-69-4 ND ug/L 1.0 0.26 1 02/08/2217:25 96-18-4 ND ug/L 2.0 1.3 1 02/08/2217:25 108-05-4 L1,v1 1.2 ug/L 1.0 0.39 1 02/08/2217:25 75-01-4 ND ug/L 1.0 0.34 1 02/08/2217:25 1330-20-7 104 % 70-130 1 02/08/2217:25 460-00-4 108 % 70-130 1 02/08/2217:25 17060-07-0 105 % 70-130 1 02/08/2217:25 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 500 250 5 02/09/22 03:10 18496-25-8 D3 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 34.4 mg/L 1.0 0.60 1 02/17/2214:25 16887-00-6 3550 ug/L 1000 500 1 02/17/2214:25 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 2960 ug/L 1000 500 1 02/12/2210:02 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-31) Lab ID: 92586338003 Collected: 02/03/22 11:20 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite ND mg/L 0.010 0.0033 1 02/04/22 20:36 14797-65-0 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:24 7440-36-0 Arsenic 6.6J ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:15 7440-38-2 Barium 44.6 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:24 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:24 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:24 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:24 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:24 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:24 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:24 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:24 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:24 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:24 7440-62-2 Zinc ND ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:24 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 0.31J ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 02:47 7440-48-4 Thallium ND ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 02:47 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 17:43 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 17:43 107-13-1 Benzene 0.41J ug/L 1.0 0.34 1 02/08/22 17:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 17:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 17:43 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 17:43 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 17:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 17:43 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 17:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 17:43 56-23-5 Chlorobenzene 0.53J ug/L 1.0 0.28 1 02/08/22 17:43 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 17:43 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 17:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 17:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 17:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 17:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 17:43 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 17:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 17:43 95-50-1 1,4-Dichlorobenzene 3.8 ug/L 1.0 0.33 1 02/08/22 17:43 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. v1 IK Page 10 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-3D Lab ID: 92586338003 Collected: 02/03/22 11:20 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2217:43 110-57-6 1.3 ug/L 1.0 0.37 1 02/08/2217:43 75-34-3 0.47J ug/L 1.0 0.32 1 02/08/2217:43 107-06-2 ND ug/L 1.0 0.35 1 02/08/2217:43 75-35-4 9.8 ug/L 1.0 0.38 1 02/08/2217:43 156-59-2 ND ug/L 1.0 0.40 1 02/08/2217:43 156-60-5 0.84J ug/L 1.0 0.36 1 02/08/2217:43 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 17:43 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2217:43 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2217:43 100-41-4 ND ug/L 5.0 0.48 1 02/08/2217:43 591-78-6 ND ug/L 20.0 9.7 1 02/08/2217:43 74-88-4 ND ug/L 5.0 2.0 1 02/08/2217:43 75-09-2 ND ug/L 5.0 2.7 1 02/08/2217:43 108-10-1 ND ug/L 1.0 0.29 1 02/08/2217:43 100-42-5 ND ug/L 1.0 0.31 1 02/08/2217:43 630-20-6 ND ug/L 1.0 0.22 1 02/08/2217:43 79-34-5 ND ug/L 1.0 0.29 1 02/08/2217:43 127-18-4 ND ug/L 1.0 0.48 1 02/08/2217:43 108-88-3 ND ug/L 1.0 0.33 1 02/08/2217:43 71-55-6 ND ug/L 1.0 0.32 1 02/08/2217:43 79-00-5 ND ug/L 1.0 0.38 1 02/08/2217:43 79-01-6 ND ug/L 1.0 0.30 1 02/08/2217:43 75-69-4 ND ug/L 1.0 0.26 1 02/08/2217:43 96-18-4 ND ug/L 2.0 1.3 1 02/08/2217:43 108-05-4 4.2 ug/L 1.0 0.39 1 02/08/2217:43 75-01-4 ND ug/L 1.0 0.34 1 02/08/2217:43 1330-20-7 104 % 70-130 1 02/08/2217:43 460-00-4 107 % 70-130 1 02/08/2217:43 17060-07-0 106 % 70-130 1 02/08/2217:43 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 02/09/22 03:10 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 30.2 mg/L 1.0 0.60 1 02/17/2214:39 16887-00-6 549J ug/L 1000 500 1 02/17/2214:39 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 825J ug/L 1000 500 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/12/2210:19 7440-44-0 L1,v1 Page 11 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-4 Lab ID: 92586338004 Collected: 02/03/22 11:05 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite ND mg/L 0.010 0.0033 1 02/04/22 20:33 14797-65-0 M1 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:27 7440-36-0 Arsenic 6.1J ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:26 7440-38-2 Barium 122 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:27 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:27 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:27 7440-43-9 Chromium 24.0 ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:27 7440-47-3 Copper 10.9 ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:27 7440-50-8 Lead 5.6 ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:27 7439-92-1 Nickel 5.5 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:27 7440-02-0 Selenium 4.9J ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:27 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:27 7440-22-4 Vanadium 21.3 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:27 7440-62-2 Zinc 20.4 ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:27 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 4.4 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 02:51 7440-48-4 Thallium 0.072J ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 02:51 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 18:00 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 18:00 107-13-1 Benzene 0.40J ug/L 1.0 0.34 1 02/08/22 18:00 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 18:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 18:00 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 18:00 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 18:00 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 18:00 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 18:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 18:00 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 18:00 108-90-7 Chloroethane 0.81J ug/L 1.0 0.65 1 02/08/22 18:00 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 18:00 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 18:00 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 18:00 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 18:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 18:00 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 18:00 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 18:00 95-50-1 1,4-Dichlorobenzene 1.9 ug/L 1.0 0.33 1 02/08/22 18:00 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. v1 IK Page 12 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-4 Lab ID: 92586338004 Collected: 02/03/22 11:05 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2218:00 110-57-6 1.4 ug/L 1.0 0.37 1 02/08/2218:00 75-34-3 ND ug/L 1.0 0.32 1 02/08/2218:00 107-06-2 ND ug/L 1.0 0.35 1 02/08/2218:00 75-35-4 16.8 ug/L 1.0 0.38 1 02/08/2218:00 156-59-2 ND ug/L 1.0 0.40 1 02/08/2218:00 156-60-5 ND ug/L 1.0 0.36 1 02/08/2218:00 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 18:00 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2218:00 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2218:00 100-41-4 ND ug/L 5.0 0.48 1 02/08/2218:00 591-78-6 ND ug/L 20.0 9.7 1 02/08/2218:00 74-88-4 ND ug/L 5.0 2.0 1 02/08/2218:00 75-09-2 ND ug/L 5.0 2.7 1 02/08/2218:00 108-10-1 ND ug/L 1.0 0.29 1 02/08/2218:00 100-42-5 ND ug/L 1.0 0.31 1 02/08/2218:00 630-20-6 ND ug/L 1.0 0.22 1 02/08/2218:00 79-34-5 ND ug/L 1.0 0.29 1 02/08/2218:00 127-18-4 ND ug/L 1.0 0.48 1 02/08/2218:00 108-88-3 ND ug/L 1.0 0.33 1 02/08/2218:00 71-55-6 ND ug/L 1.0 0.32 1 02/08/2218:00 79-00-5 ND ug/L 1.0 0.38 1 02/08/2218:00 79-01-6 ND ug/L 1.0 0.30 1 02/08/2218:00 75-69-4 ND ug/L 1.0 0.26 1 02/08/2218:00 96-18-4 ND ug/L 2.0 1.3 1 02/08/2218:00 108-05-4 10.7 ug/L 1.0 0.39 1 02/08/2218:00 75-01-4 ND ug/L 1.0 0.34 1 02/08/2218:00 1330-20-7 101 % 70-130 1 02/08/2218:00 460-00-4 105 % 70-130 1 02/08/2218:00 17060-07-0 103 % 70-130 1 02/08/2218:00 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 02/09/22 03:11 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 24.6 mg/L 1.0 0.60 1 02/17/2214:53 16887-00-6 ND ug/L 1000 500 1 02/17/2214:53 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 670J ug/L 1000 500 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/12/2210:39 7440-44-0 L1,v1 Page 13 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-5 Lab ID: 92586338005 Collected: 02/03/22 13:45 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite ND mg/L 0.010 0.0033 1 02/04/22 20:46 14797-65-0 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:31 7440-36-0 Arsenic 7.2J ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:30 7440-38-2 Barium 159 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:31 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:31 7440-41-7 Cadmium 0.83J ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:31 7440-43-9 Chromium 14.7 ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:31 7440-47-3 Copper 34.1 ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:31 7440-50-8 Lead 37.8 ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:31 7439-92-1 Nickel 7.3 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:31 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:31 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:31 7440-22-4 Vanadium 52.0 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:31 7440-62-2 Zinc 125 ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:31 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 16.3 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 03:03 7440-48-4 Thallium 0.29J ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 03:03 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 18:18 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 18:18 107-13-1 Benzene ND ug/L 1.0 0.34 1 02/08/22 18:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 18:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 18:18 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 18:18 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 18:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 18:18 78-93-3 v1 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 18:18 75-15-0 IK Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 18:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 18:18 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 18:18 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 18:18 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 18:18 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 18:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 18:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 18:18 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 18:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 18:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 02/08/22 18:18 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-5 Lab ID: 92586338005 Collected: 02/03/22 13:45 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2218:18 110-57-6 ND ug/L 1.0 0.37 1 02/08/2218:18 75-34-3 ND ug/L 1.0 0.32 1 02/08/2218:18 107-06-2 ND ug/L 1.0 0.35 1 02/08/2218:18 75-35-4 ND ug/L 1.0 0.38 1 02/08/2218:18 156-59-2 ND ug/L 1.0 0.40 1 02/08/2218:18 156-60-5 ND ug/L 1.0 0.36 1 02/08/2218:18 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 18:18 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2218:18 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2218:18 100-41-4 ND ug/L 5.0 0.48 1 02/08/2218:18 591-78-6 ND ug/L 20.0 9.7 1 02/08/2218:18 74-88-4 ND ug/L 5.0 2.0 1 02/08/2218:18 75-09-2 ND ug/L 5.0 2.7 1 02/08/2218:18 108-10-1 ND ug/L 1.0 0.29 1 02/08/2218:18 100-42-5 ND ug/L 1.0 0.31 1 02/08/2218:18 630-20-6 ND ug/L 1.0 0.22 1 02/08/2218:18 79-34-5 ND ug/L 1.0 0.29 1 02/08/2218:18 127-18-4 ND ug/L 1.0 0.48 1 02/08/2218:18 108-88-3 ND ug/L 1.0 0.33 1 02/08/2218:18 71-55-6 ND ug/L 1.0 0.32 1 02/08/2218:18 79-00-5 ND ug/L 1.0 0.38 1 02/08/2218:18 79-01-6 ND ug/L 1.0 0.30 1 02/08/2218:18 75-69-4 ND ug/L 1.0 0.26 1 02/08/2218:18 96-18-4 ND ug/L 2.0 1.3 1 02/08/2218:18 108-05-4 L1,v1 ND ug/L 1.0 0.39 1 02/08/2218:18 75-01-4 ND ug/L 1.0 0.34 1 02/08/2218:18 1330-20-7 104 % 70-130 1 02/08/2218:18 460-00-4 98 % 70-130 1 02/08/2218:18 17060-07-0 112 % 70-130 1 02/08/2218:18 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 500 250 5 02/09/22 03:12 18496-25-8 D3 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 3.2 mg/L 1.0 0.60 1 02/17/2215:07 16887-00-6 9770 ug/L 1000 500 1 02/17/2215:07 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 6010 ug/L 1000 500 1 02/12/2210:55 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-6 Lab ID: 92586338006 Collected: 02/03/22 13:20 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite ND mg/L 0.010 0.0033 1 02/04/22 20:42 14797-65-0 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:34 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:33 7440-38-2 Barium 102 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:34 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:34 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:34 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:34 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:34 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:34 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:34 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:34 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:34 7440-22-4 Vanadium 6.4 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:34 7440-62-2 Zinc ND ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 0.78J ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 03:07 7440-48-4 Thallium 0.0911 ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 03:07 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 18:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 18:35 107-13-1 Benzene ND ug/L 1.0 0.34 1 02/08/22 18:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 18:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 18:35 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 18:35 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 18:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 18:35 78-93-3 v1 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 18:35 75-15-0 IK Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 18:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 18:35 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 18:35 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 18:35 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 18:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 18:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 18:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 18:35 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 18:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 18:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 02/08/22 18:35 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: MW-6 Lab ID: 92586338006 Collected: 02/03/22 13:20 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2218:35 110-57-6 ND ug/L 1.0 0.37 1 02/08/2218:35 75-34-3 ND ug/L 1.0 0.32 1 02/08/2218:35 107-06-2 ND ug/L 1.0 0.35 1 02/08/2218:35 75-35-4 ND ug/L 1.0 0.38 1 02/08/2218:35 156-59-2 ND ug/L 1.0 0.40 1 02/08/2218:35 156-60-5 ND ug/L 1.0 0.36 1 02/08/2218:35 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 18:35 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2218:35 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2218:35 100-41-4 ND ug/L 5.0 0.48 1 02/08/2218:35 591-78-6 ND ug/L 20.0 9.7 1 02/08/2218:35 74-88-4 ND ug/L 5.0 2.0 1 02/08/2218:35 75-09-2 ND ug/L 5.0 2.7 1 02/08/2218:35 108-10-1 ND ug/L 1.0 0.29 1 02/08/2218:35 100-42-5 ND ug/L 1.0 0.31 1 02/08/2218:35 630-20-6 ND ug/L 1.0 0.22 1 02/08/2218:35 79-34-5 ND ug/L 1.0 0.29 1 02/08/2218:35 127-18-4 ND ug/L 1.0 0.48 1 02/08/2218:35 108-88-3 ND ug/L 1.0 0.33 1 02/08/2218:35 71-55-6 ND ug/L 1.0 0.32 1 02/08/2218:35 79-00-5 ND ug/L 1.0 0.38 1 02/08/2218:35 79-01-6 ND ug/L 1.0 0.30 1 02/08/2218:35 75-69-4 ND ug/L 1.0 0.26 1 02/08/2218:35 96-18-4 ND ug/L 2.0 1.3 1 02/08/2218:35 108-05-4 ND ug/L 1.0 0.39 1 02/08/2218:35 75-01-4 ND ug/L 1.0 0.34 1 02/08/2218:35 1330-20-7 105 % 70-130 1 02/08/2218:35 460-00-4 104 % 70-130 1 02/08/2218:35 17060-07-0 105 % 70-130 1 02/08/2218:35 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 02/09/22 03:13 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 1.6 mg/L 1.0 0.60 1 02/17/2215:21 16887-00-6 5070 ug/L 1000 500 1 02/17/2215:21 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 749J ug/L 1000 500 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/12/2211:13 7440-44-0 L1,v1 Page 17 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: DUPLICATE Lab ID: 92586338007 Collected: 02/03/22 11:30 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 450ONO2B Nitrite, unpres Analytical Method: SM 4500-NO2 B-2011 Pace Analytical Services - Eden Nitrogen, Nitrite 0.0034J mg/L 0.010 0.0033 1 02/04/22 20:38 14797-65-0 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:38 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:37 7440-38-2 Barium 45.6 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:38 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:38 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:38 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:38 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:38 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:38 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:38 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:38 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:38 7440-62-2 Zinc ND ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 0.30J ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 03:11 7440-48-4 Thallium ND ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 03:11 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 18:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 18:52 107-13-1 Benzene 0.41J ug/L 1.0 0.34 1 02/08/22 18:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 18:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 18:52 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 18:52 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 18:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 18:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 18:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 18:52 56-23-5 Chlorobenzene 0.49J ug/L 1.0 0.28 1 02/08/22 18:52 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 18:52 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 18:52 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 18:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 18:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 18:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 18:52 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 18:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 18:52 95-50-1 1,4-Dichlorobenzene 3.8 ug/L 1.0 0.33 1 02/08/22 18:52 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. v1 IK Page 18 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: DUPLICATE Lab ID: 92586338007 Collected: 02/03/22 11:30 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Chloride Sulfate 5310B TOC Total Organic Carbon Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 02/08/2218:52 110-57-6 1.2 ug/L 1.0 0.37 1 02/08/2218:52 75-34-3 ND ug/L 1.0 0.32 1 02/08/2218:52 107-06-2 ND ug/L 1.0 0.35 1 02/08/2218:52 75-35-4 9.5 ug/L 1.0 0.38 1 02/08/2218:52 156-59-2 ND ug/L 1.0 0.40 1 02/08/2218:52 156-60-5 0.891 ug/L 1.0 0.36 1 02/08/2218:52 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 18:52 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2218:52 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2218:52 100-41-4 ND ug/L 5.0 0.48 1 02/08/2218:52 591-78-6 ND ug/L 20.0 9.7 1 02/08/2218:52 74-88-4 ND ug/L 5.0 2.0 1 02/08/2218:52 75-09-2 ND ug/L 5.0 2.7 1 02/08/2218:52 108-10-1 ND ug/L 1.0 0.29 1 02/08/2218:52 100-42-5 ND ug/L 1.0 0.31 1 02/08/2218:52 630-20-6 ND ug/L 1.0 0.22 1 02/08/2218:52 79-34-5 ND ug/L 1.0 0.29 1 02/08/2218:52 127-18-4 ND ug/L 1.0 0.48 1 02/08/2218:52 108-88-3 ND ug/L 1.0 0.33 1 02/08/2218:52 71-55-6 ND ug/L 1.0 0.32 1 02/08/2218:52 79-00-5 ND ug/L 1.0 0.38 1 02/08/2218:52 79-01-6 ND ug/L 1.0 0.30 1 02/08/2218:52 75-69-4 ND ug/L 1.0 0.26 1 02/08/2218:52 96-18-4 ND ug/L 2.0 1.3 1 02/08/2218:52 108-05-4 4.1 ug/L 1.0 0.39 1 02/08/2218:52 75-01-4 ND ug/L 1.0 0.34 1 02/08/2218:52 1330-20-7 104 % 70-130 1 02/08/2218:52 460-00-4 106 % 70-130 1 02/08/2218:52 17060-07-0 105 % 70-130 1 02/08/2218:52 2037-26-5 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 02/09/22 03:13 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 30.4 mg/L 1.0 0.60 1 02/17/2216:02 16887-00-6 585J ug/L 1000 500 1 02/17/2216:02 14808-79-8 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 816J ug/L 1000 500 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/12/2211:30 7440-44-0 L1,v1 Page 19 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: SW-1 Lab ID: 92586338008 Collected: 02/03/22 12:30 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:41 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 02/15/22 00:38 02/22/22 13:40 7440-38-2 Barium 31.4 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:41 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:41 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:41 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:41 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:41 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:41 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:41 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:41 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:41 7440-22-4 Vanadium 5.8 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:41 7440-62-2 Zinc ND ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:41 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 0.991 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 03:15 7440-48-4 Thallium ND ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 03:15 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 19:10 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 19:10 107-13-1 Benzene ND ug/L 1.0 0.34 1 02/08/22 19:10 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 19:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 19:10 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 19:10 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 19:10 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 19:10 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 19:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 19:10 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 19:10 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 19:10 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 19:10 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 19:10 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 19:10 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 19:10 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 19:10 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 19:10 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 19:10 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 02/08/22 19:10 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 02/08/22 19:10 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 02/08/22 19:10 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 02/08/22 19:10 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 02/08/22 19:10 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. v1 IK Page 20 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: SW-1 Lab ID: 92586338008 Collected: 02/03/22 12:30 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 02/08/2219:10 156-59-2 ND ug/L 1.0 0.40 1 02/08/2219:10 156-60-5 ND ug/L 1.0 0.36 1 02/08/2219:10 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 19:10 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2219:10 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2219:10 100-41-4 ND ug/L 5.0 0.48 1 02/08/2219:10 591-78-6 ND ug/L 20.0 9.7 1 02/08/2219:10 74-88-4 ND ug/L 5.0 2.0 1 02/08/2219:10 75-09-2 ND ug/L 5.0 2.7 1 02/08/2219:10 108-10-1 ND ug/L 1.0 0.29 1 02/08/2219:10 100-42-5 ND ug/L 1.0 0.31 1 02/08/2219:10 630-20-6 ND ug/L 1.0 0.22 1 02/08/2219:10 79-34-5 ND ug/L 1.0 0.29 1 02/08/2219:10 127-18-4 ND ug/L 1.0 0.48 1 02/08/2219:10 108-88-3 ND ug/L 1.0 0.33 1 02/08/2219:10 71-55-6 ND ug/L 1.0 0.32 1 02/08/2219:10 79-00-5 ND ug/L 1.0 0.38 1 02/08/2219:10 79-01-6 ND ug/L 1.0 0.30 1 02/08/2219:10 75-69-4 ND ug/L 1.0 0.26 1 02/08/2219:10 96-18-4 ND ug/L 2.0 1.3 1 02/08/2219:10 108-05-4 ND ug/L 1.0 0.39 1 02/08/2219:10 75-01-4 ND ug/L 1.0 0.34 1 02/08/2219:10 1330-20-7 103 % 70-130 1 02/08/2219:10 460-00-4 107 % 70-130 1 02/08/2219:10 17060-07-0 106 % 70-130 1 02/08/2219:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 21 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: SW-2 Lab ID: 92586338009 Collected: 02/03/22 12:10 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:52 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:52 7440-38-2 Barium 37.2 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:52 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:52 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:52 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:52 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:52 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:52 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:52 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:52 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:52 7440-22-4 Vanadium 6.3 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:52 7440-62-2 Zinc ND ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:52 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 1.3 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 03:19 7440-48-4 Thallium ND ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 03:19 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 19:27 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 19:27 107-13-1 Benzene ND ug/L 1.0 0.34 1 02/08/22 19:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 19:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 19:27 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 19:27 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 19:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 19:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 19:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 19:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 19:27 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 19:27 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 19:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 19:27 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 19:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 19:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 19:27 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 19:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 19:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 02/08/22 19:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 02/08/22 19:27 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 02/08/22 19:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 02/08/22 19:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 02/08/22 19:27 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. v1 IK Page 22 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: SW-2 Lab ID: 92586338009 Collected: 02/03/22 12:10 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 02/08/2219:27 156-59-2 ND ug/L 1.0 0.40 1 02/08/2219:27 156-60-5 ND ug/L 1.0 0.36 1 02/08/2219:27 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 19:27 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2219:27 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2219:27 100-41-4 ND ug/L 5.0 0.48 1 02/08/2219:27 591-78-6 ND ug/L 20.0 9.7 1 02/08/2219:27 74-88-4 ND ug/L 5.0 2.0 1 02/08/2219:27 75-09-2 ND ug/L 5.0 2.7 1 02/08/2219:27 108-10-1 ND ug/L 1.0 0.29 1 02/08/2219:27 100-42-5 ND ug/L 1.0 0.31 1 02/08/2219:27 630-20-6 ND ug/L 1.0 0.22 1 02/08/2219:27 79-34-5 ND ug/L 1.0 0.29 1 02/08/2219:27 127-18-4 ND ug/L 1.0 0.48 1 02/08/2219:27 108-88-3 ND ug/L 1.0 0.33 1 02/08/2219:27 71-55-6 ND ug/L 1.0 0.32 1 02/08/2219:27 79-00-5 ND ug/L 1.0 0.38 1 02/08/2219:27 79-01-6 ND ug/L 1.0 0.30 1 02/08/2219:27 75-69-4 ND ug/L 1.0 0.26 1 02/08/2219:27 96-18-4 ND ug/L 2.0 1.3 1 02/08/2219:27 108-05-4 ND ug/L 1.0 0.39 1 02/08/2219:27 75-01-4 ND ug/L 1.0 0.34 1 02/08/2219:27 1330-20-7 103 % 70-130 1 02/08/2219:27 460-00-4 101 % 70-130 1 02/08/2219:27 17060-07-0 103 % 70-130 1 02/08/2219:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 23 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: SW-3 Lab ID: 92586338010 Collected: 02/03/22 12:25 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 02/15/22 00:38 02/21/22 12:56 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:56 7440-38-2 Barium 35.1 ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:56 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 02/15/22 00:38 02/21/22 12:56 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 02/15/22 00:38 02/21/22 12:56 7440-43-9 Chromium ND ug/L 5.0 3.7 1 02/15/22 00:38 02/21/22 12:56 7440-47-3 Copper ND ug/L 5.0 4.3 1 02/15/22 00:38 02/21/22 12:56 7440-50-8 Lead ND ug/L 5.0 4.5 1 02/15/22 00:38 02/21/22 12:56 7439-92-1 Nickel ND ug/L 5.0 3.5 1 02/15/22 00:38 02/21/22 12:56 7440-02-0 Selenium ND ug/L 10.0 4.7 1 02/15/22 00:38 02/21/22 12:56 7782-49-2 Silver ND ug/L 5.0 2.5 1 02/15/22 00:38 02/21/22 12:56 7440-22-4 Vanadium 7.0 ug/L 5.0 3.9 1 02/15/22 00:38 02/21/22 12:56 7440-62-2 Zinc ND ug/L 10.0 9.5 1 02/15/22 00:38 02/21/22 12:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt 1.1 ug/L 1.0 0.050 1 02/11/22 10:07 02/17/22 03:23 7440-48-4 Thallium ND ug/L 0.47 0.050 1 02/11/22 10:07 02/17/22 03:23 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 02/08/22 19:45 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 02/08/22 19:45 107-13-1 Benzene ND ug/L 1.0 0.34 1 02/08/22 19:45 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 02/08/22 19:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 02/08/22 19:45 75-27-4 Bromoform ND ug/L 1.0 0.34 1 02/08/22 19:45 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 02/08/22 19:45 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 02/08/22 19:45 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 02/08/22 19:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 02/08/22 19:45 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 02/08/22 19:45 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 02/08/22 19:45 75-00-3 Chloroform ND ug/L 1.0 0.43 1 02/08/22 19:45 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 02/08/22 19:45 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 02/08/22 19:45 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 02/08/22 19:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 02/08/22 19:45 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 02/08/22 19:45 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 02/08/22 19:45 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 02/08/22 19:45 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 02/08/22 19:45 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 02/08/22 19:45 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 02/08/22 19:45 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 02/08/22 19:45 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. v1 IK Page 24 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: SW-3 Lab ID: 92586338010 Collected: 02/03/22 12:25 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 02/08/2219:45 156-59-2 ND ug/L 1.0 0.40 1 02/08/2219:45 156-60-5 ND ug/L 1.0 0.36 1 02/08/2219:45 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 19:45 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2219:45 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2219:45 100-41-4 ND ug/L 5.0 0.48 1 02/08/2219:45 591-78-6 ND ug/L 20.0 9.7 1 02/08/2219:45 74-88-4 ND ug/L 5.0 2.0 1 02/08/2219:45 75-09-2 ND ug/L 5.0 2.7 1 02/08/2219:45 108-10-1 ND ug/L 1.0 0.29 1 02/08/2219:45 100-42-5 ND ug/L 1.0 0.31 1 02/08/2219:45 630-20-6 ND ug/L 1.0 0.22 1 02/08/2219:45 79-34-5 ND ug/L 1.0 0.29 1 02/08/2219:45 127-18-4 ND ug/L 1.0 0.48 1 02/08/2219:45 108-88-3 ND ug/L 1.0 0.33 1 02/08/2219:45 71-55-6 ND ug/L 1.0 0.32 1 02/08/2219:45 79-00-5 ND ug/L 1.0 0.38 1 02/08/2219:45 79-01-6 ND ug/L 1.0 0.30 1 02/08/2219:45 75-69-4 ND ug/L 1.0 0.26 1 02/08/2219:45 96-18-4 ND ug/L 2.0 1.3 1 02/08/2219:45 108-05-4 ND ug/L 1.0 0.39 1 02/08/2219:45 75-01-4 ND ug/L 1.0 0.34 1 02/08/2219:45 1330-20-7 105 % 70-130 1 02/08/2219:45 460-00-4 101 % 70-130 1 02/08/2219:45 17060-07-0 108 % 70-130 1 02/08/2219:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 25 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: TRIP BLANK (X2) Lab ID: 92586338011 Collected: 02/03/22 00:00 Received: 02/04/22 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 02/22/2022 05:36 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 02/08/2215:05 67-64-1 ND ug/L 10.0 1.8 1 02/08/2215:05 107-13-1 ND ug/L 1.0 0.34 1 02/08/2215:05 71-43-2 ND ug/L 1.0 0.47 1 02/08/2215:05 74-97-5 ND ug/L 1.0 0.31 1 02/08/2215:05 75-27-4 ND ug/L 1.0 0.34 1 02/08/2215:05 75-25-2 ND ug/L 2.0 1.7 1 02/08/2215:05 74-83-9 ND ug/L 5.0 4.0 1 02/08/2215:05 78-93-3 v1 ND ug/L 2.0 0.73 1 02/08/2215:05 75-15-0 IK ND ug/L 1.0 0.33 1 02/08/2215:05 56-23-5 ND ug/L 1.0 0.28 1 02/08/2215:05 108-90-7 ND ug/L 1.0 0.65 1 02/08/2215:05 75-00-3 ND ug/L 1.0 0.43 1 02/08/2215:05 67-66-3 ND ug/L 1.0 0.54 1 02/08/2215:05 74-87-3 ND ug/L 2.0 0.34 1 02/08/2215:05 96-12-8 ND ug/L 1.0 0.36 1 02/08/2215:05 124-48-1 ND ug/L 1.0 0.27 1 02/08/2215:05 106-93-4 ND ug/L 1.0 0.39 1 02/08/2215:05 74-95-3 ND ug/L 1.0 0.34 1 02/08/2215:05 95-50-1 ND ug/L 1.0 0.33 1 02/08/2215:05 106-46-7 ND ug/L 1.0 0.56 1 02/08/2215:05 110-57-6 ND ug/L 1.0 0.37 1 02/08/2215:05 75-34-3 ND ug/L 1.0 0.32 1 02/08/2215:05 107-06-2 ND ug/L 1.0 0.35 1 02/08/2215:05 75-35-4 ND ug/L 1.0 0.38 1 02/08/2215:05 156-59-2 ND ug/L 1.0 0.40 1 02/08/2215:05 156-60-5 ND ug/L 1.0 0.36 1 02/08/2215:05 78-87-5 ND ug/L 1.0 0.36 1 02/08/22 15:05 10061-01-5 ND ug/L 1.0 0.36 1 02/08/2215:05 10061-02-6 ND ug/L 1.0 0.30 1 02/08/2215:05 100-41-4 ND ug/L 5.0 0.48 1 02/08/2215:05 591-78-6 ND ug/L 20.0 9.7 1 02/08/2215:05 74-88-4 ND ug/L 5.0 2.0 1 02/08/2215:05 75-09-2 ND ug/L 5.0 2.7 1 02/08/2215:05 108-10-1 ND ug/L 1.0 0.29 1 02/08/2215:05 100-42-5 ND ug/L 1.0 0.31 1 02/08/2215:05 630-20-6 ND ug/L 1.0 0.22 1 02/08/2215:05 79-34-5 ND ug/L 1.0 0.29 1 02/08/2215:05 127-18-4 ND ug/L 1.0 0.48 1 02/08/2215:05 108-88-3 ND ug/L 1.0 0.33 1 02/08/2215:05 71-55-6 ND ug/L 1.0 0.32 1 02/08/2215:05 79-00-5 ND ug/L 1.0 0.38 1 02/08/2215:05 79-01-6 ND ug/L 1.0 0.30 1 02/08/2215:05 75-69-4 ND ug/L 1.0 0.26 1 02/08/2215:05 96-18-4 ND ug/L 2.0 1.3 1 02/08/2215:05 108-05-4 L1,v1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Sample: TRIP BLANK (X2) Parameters Lab ID: Results 92586338011 Units Collected: Report Limit 02/03/22 00:00 MDL DF Received: 02/04/22 11:10 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 02/08/22 15:05 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 02/08/22 15:05 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 02/08/22 15:05 460-00-4 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 02/08/22 15:05 17060-07-0 Toluene-d8 (S) 110 % 70-130 1 02/08/22 15:05 2037-26-5 Date: 02/22/2022 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 676207 Analysis Method: SM 4500-NO2 B-2011 QC Batch Method: SM 4500-NO2 B-2011 Analysis Description: 4500NO2B, Nitrite, unpres Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 METHOD BLANK: 3539648 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrite mg/L ND 0.010 0.0033 02/04/22 20:31 LABORATORY CONTROL SAMPLE: 3539649 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrite mg/L 0.1 0.10 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3539650 3539651 MS MSD 92586338004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrite mg/L ND 0.1 0.1 0.056 0.055 56 55 90-110 2 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 678247 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010 METHOD BLANK: 3549624 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 02/21/2211:41 Arsenic ug/L ND 10.0 4.7 02/22/2212:47 Barium ug/L ND 5.0 3.5 02/21/2211:41 Beryllium ug/L ND 1.0 0.70 02/21/2211:41 Cadmium ug/L ND 1.0 0.40 02/21/2211:41 Chromium ug/L ND 5.0 3.7 02/21/2211:41 Copper ug/L ND 5.0 4.3 02/21/2211:41 Lead ug/L ND 5.0 4.5 02/21/2211:41 Nickel ug/L ND 5.0 3.5 02/21/2211:41 Selenium ug/L ND 10.0 4.7 02/21/2211:41 Silver ug/L ND 5.0 2.5 02/21/2211:41 Vanadium ug/L ND 5.0 3.9 02/21/2211:41 Zinc ug/L ND 10.0 9.5 02/21/2211:41 LABORATORY CONTROL SAMPLE: Parameter 3549625 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 513 103 80-120 Arsenic ug/L 500 484 97 80-120 Barium ug/L 500 504 101 80-120 Beryllium ug/L 500 521 104 80-120 Cadmium ug/L 500 511 102 80-120 Chromium ug/L 500 522 104 80-120 Copper ug/L 500 530 106 80-120 Lead ug/L 500 514 103 80-120 Nickel ug/L 500 513 103 80-120 Selenium ug/L 500 511 102 80-120 Silver ug/L 250 258 103 80-120 Vanadium ug/L 500 509 102 80-120 Zinc ug/L 500 499 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3549626 3549627 MS MSD 92584984005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 38.5J 37.5J 8 8 75-125 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: KERNERSVILLE LANDFILL 92586338 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3549626 3549627 MS MSD 92584984005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 142 165 22 26 75-125 15 20 M1 Barium ug/L 1620 500 500 2100 2200 97 117 75-125 5 20 Beryllium ug/L ND 500 500 384 392 76 77 75-125 2 20 Cadmium ug/L 8.2J 500 500 458 465 90 91 75-125 1 20 Chromium ug/L 960 500 500 1490 1550 106 119 75-125 4 20 Copper ug/L 489 500 500 988 1030 100 108 75-125 4 20 Lead ug/L ND 500 500 446 456 85 87 75-125 2 20 Nickel ug/L 1350 500 500 1860 1950 102 121 75-125 5 20 Selenium ug/L ND 500 500 48.8J ND 10 9 75-125 20 M1 Silver ug/L ND 250 250 225 228 90 91 75-125 2 20 Vanadium ug/L 922 500 500 1510 1560 118 127 75-125 3 20 M1 Zinc ug/L 703 500 500 1190 1240 97 108 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 677605 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010 METHOD BLANK: 3546349 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cobalt ug/L ND 1.0 0.050 02/17/22 02:15 Thallium ug/L ND 0.47 0.050 02/17/22 02:15 LABORATORY CONTROL SAMPLE: 3546350 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cobalt ug/L 50 52.6 105 80-120 Thallium ug/L 25 25.8 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3546351 3546352 MS MSD 92586338001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cobalt ug/L 4.0 50 50 55.4 55.1 103 102 75-125 0 20 Thallium ug/L ND 25 25 26.1 25.1 104 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 676585 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010,92586338011 METHOD BLANK: 3541444 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010,92586338011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 02/08/22 14:48 1,1,1-Trichloroethane ug/L ND 1.0 0.33 02/08/22 14:48 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 02/08/22 14:48 1,1,2-Trichloroethane ug/L ND 1.0 0.32 02/08/22 14:48 1,1-Dichloroethane ug/L ND 1.0 0.37 02/08/22 14:48 1,1-Dichloroethene ug/L ND 1.0 0.35 02/08/22 14:48 1,2,3-Trichloropropane ug/L ND 1.0 0.26 02/08/22 14:48 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 02/08/22 14:48 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 02/08/22 14:48 1,2-Dichlorobenzene ug/L ND 1.0 0.34 02/08/22 14:48 1,2-Dichloroethane ug/L ND 1.0 0.32 02/08/22 14:48 1,2-Dichloropropane ug/L ND 1.0 0.36 02/08/22 14:48 1,4-Dichlorobenzene ug/L ND 1.0 0.33 02/08/22 14:48 2-Butanone (MEK) ug/L ND 5.0 4.0 02/08/22 14:48 2-Hexanone ug/L ND 5.0 0.48 02/08/22 14:48 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 02/08/22 14:48 Acetone ug/L ND 25.0 5.1 02/08/22 14:48 Acrylonitrile ug/L ND 10.0 1.8 02/08/22 14:48 Benzene ug/L ND 1.0 0.34 02/08/22 14:48 Bromochloromethane ug/L ND 1.0 0.47 02/08/22 14:48 Bromodichloromethane ug/L ND 1.0 0.31 02/08/22 14:48 Bromoform ug/L ND 1.0 0.34 02/08/22 14:48 Bromomethane ug/L ND 2.0 1.7 02/08/22 14:48 Carbon disulfide ug/L ND 2.0 0.73 02/08/22 14:48 Carbon tetrachloride ug/L ND 1.0 0.33 02/08/22 14:48 Chlorobenzene ug/L ND 1.0 0.28 02/08/22 14:48 Chloroethane ug/L ND 1.0 0.65 02/08/22 14:48 Chloroform ug/L ND 1.0 0.43 02/08/22 14:48 Chloromethane ug/L ND 1.0 0.54 02/08/22 14:48 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 02/08/22 14:48 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 02/08/22 14:48 Dibromochloromethane ug/L ND 1.0 0.36 02/08/22 14:48 Dibromomethane ug/L ND 1.0 0.39 02/08/22 14:48 Ethylbenzene ug/L ND 1.0 0.30 02/08/22 14:48 lodomethane ug/L ND 20.0 9.7 02/08/22 14:48 Methylene Chloride ug/L ND 5.0 2.0 02/08/22 14:48 Styrene ug/L ND 1.0 0.29 02/08/22 14:48 Tetrachloroethene ug/L ND 1.0 0.29 02/08/22 14:48 Toluene ug/L ND 1.0 0.48 02/08/22 14:48 v1 III Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 METHOD BLANK: 3541444 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007, 92586338008,92586338009,92586338010,92586338011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 02/08/22 14:48 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 02/08/22 14:48 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 02/08/22 14:48 Trichloroethene ug/L ND 1.0 0.38 02/08/22 14:48 Trichlorofluoromethane ug/L ND 1.0 0.30 02/08/22 14:48 Vinyl acetate ug/L ND 2.0 1.3 02/08/22 14:48 v1 Vinyl chloride ug/L ND 1.0 0.39 02/08/22 14:48 Xylene (Total) ug/L ND 1.0 0.34 02/08/22 14:48 1,2-Dichloroethane-d4 (S) % 97 70-130 02/08/22 14:48 4-Bromofluorobenzene (S) % 100 70-130 02/08/22 14:48 Toluene-d8 (S) % 107 70-130 02/08/22 14:48 LABORATORY CONTROL SAMPLE: Parameter 3541445 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.7 97 70-130 1,1,1-Trichloroethane ug/L 50 51.1 102 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.9 98 70-130 1,1,2-Trichloroethane ug/L 50 49.9 100 70-130 1,1-Dichloroethane ug/L 50 56.8 114 70-130 1,1-Dichloroethene ug/L 50 55.2 110 70-132 1,2,3-Trichloropropane ug/L 50 48.6 97 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.1 98 70-132 1,2-Dibromoethane (EDB) ug/L 50 49.5 99 70-130 1,2-Dichlorobenzene ug/L 50 46.1 92 70-130 1,2-Dichloroethane ug/L 50 50.7 101 70-130 1,2-Dichloropropane ug/L 50 57.0 114 70-130 1,4-Dichlorobenzene ug/L 50 47.2 94 70-130 2-Butanone (MEK) ug/L 100 128 128 70-133 v1 2-Hexanone ug/L 100 119 119 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 118 118 70-130 Acetone ug/L 100 114 114 70-144 Acrylonitrile ug/L 250 304 122 70-130 Benzene ug/L 50 52.7 105 70-130 Bromochloromethane ug/L 50 51.4 103 70-130 Bromodichloromethane ug/L 50 51.4 103 70-130 Bromoform ug/L 50 49.1 98 70-131 Bromomethane ug/L 50 47.8 96 30-177 Carbon disulfide ug/L 50 53.0 106 70-133 IK Carbon tetrachloride ug/L 50 50.8 102 70-130 Chlorobenzene ug/L 50 47.7 95 70-130 Chloroethane ug/L 50 52.5 105 46-131 Chloroform ug/L 50 50.2 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 LABORATORY CONTROL SAMPLE: Parameter 3541445 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 55.4 cis-1,2-Dichloroethene ug/L 50 55.1 cis-1,3-Dichloropropene ug/L 50 55.5 Dibromochloromethane ug/L 50 50.4 Dibromomethane ug/L 50 46.7 Ethylbenzene ug/L 50 48.1 lodomethane ug/L 100 96.1 Methylene Chloride ug/L 50 57.1 Styrene ug/L 50 49.1 Tetrachloroethene ug/L 50 46.1 Toluene ug/L 50 49.5 trans-1,2-Dichloroethene ug/L 50 58.1 trans- 1,3-Dichloropropene ug/L 50 53.1 trans-1,4-Dichloro-2-butene ug/L 50 58.7 Trichloroethene ug/L 50 49.6 Trichlorofluoromethane ug/L 50 44.7 Vinyl acetate ug/L 100 148 Vinyl chloride ug/L 50 54.6 Xylene (Total) ug/L 150 141 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 111 49-130 110 70-130 111 70-130 101 70-130 93 70-130 96 70-130 96 47-140 114 68-130 98 70-130 92 70-130 99 70-130 116 70-130 106 70-130 117 25-200 99 70-130 89 61-130 148 70-140 L1,v1 109 59-142 94 70-130 106 70-130 100 70-130 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3541446 MS 92585718001 Spike Parameter Units Result Conc. MSD Spike Conc. 3541447 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.5 19.8 102 99 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 25.3 23.2 126 116 70-148 9 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.2 20.4 106 102 70-131 4 30 1,1,2-Trichloroethane ug/L ND 20 20 22.3 21.6 111 108 70-136 3 30 1,1-Dichloroethane ug/L 3.9 20 20 31.1 28.7 136 124 70-147 8 30 1,1-Dichloroethene ug/L 0.87J 20 20 26.7 24.1 129 116 70-158 10 30 1,2,3-Trichloropropane ug/L ND 20 20 20.4 19.9 102 100 67-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 18.8 18.2 94 91 69-136 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.8 20.3 104 101 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 19.9 19.4 100 97 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 21.7 20.1 108 101 67-138 7 30 1,2-Dichloropropane ug/L ND 20 20 24.0 22.4 120 112 70-138 7 30 1,4-Dichlorobenzene ug/L ND 20 20 20.3 19.8 102 99 70-133 3 30 2-Butanone (MEK) ug/L ND 40 40 50.1 48.5 125 121 61-147 3 30 v1 2-Hexanone ug/L ND 40 40 45.9 45.4 115 114 67-139 1 30 4-Methyl-2-pentanone ug/L ND 40 40 48.3 47.7 121 119 67-136 1 30 (MIBK) Acetone ug/L ND 40 40 48.5 44.5 121 111 55-159 9 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 02/22/2022 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3541446 3541447 MS MSD 92585718001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 134 125 134 125 68-140 7 30 Benzene ug/L ND 20 20 25.2 23.3 126 116 67-150 8 30 Bromochloromethane ug/L ND 20 20 23.9 22.0 120 110 70-146 8 30 Bromodichloromethane ug/L ND 20 20 21.8 20.5 109 103 70-138 6 30 Bromoform ug/L ND 20 20 19.6 18.6 98 93 57-138 6 30 Bromomethane ug/L ND 20 20 25.6 23.9 128 119 10-200 7 30 Carbon disulfide ug/L ND 20 20 25.7 22.6 129 113 70-152 13 30 IK Carbon tetrachloride ug/L ND 20 20 24.8 22.9 124 114 70-147 8 30 Chlorobenzene ug/L ND 20 20 20.8 20.1 104 100 70-137 4 30 Chloroethane ug/L ND 20 20 25.9 24.1 129 121 51-166 7 30 Chloroform ug/L 0.46J 20 20 24.1 22.4 118 110 70-144 8 30 Chloromethane ug/L ND 20 20 22.6 21.0 113 105 24-161 7 30 cis-1,2-Dichloroethene ug/L ND 20 20 26.2 24.3 131 121 67-148 8 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.8 21.1 114 106 70-142 8 30 Dibromochloromethane ug/L ND 20 20 20.8 19.9 104 99 68-138 5 30 Dibromomethane ug/L ND 20 20 21.8 20.0 109 100 70-134 8 30 Ethylbenzene ug/L ND 20 20 21.5 21.0 107 105 68-143 2 30 Iodomethane ug/L ND 40 40 38.0 32.4 95 81 20-161 16 30 Methylene Chloride ug/L ND 20 20 27.4 25.6 137 128 64-148 7 30 v1 Styrene ug/L ND 20 20 21.0 20.7 105 104 70-136 1 30 Tetrachloroethene ug/L 0.53J 20 20 21.4 20.8 105 101 70-139 3 30 Toluene ug/L ND 20 20 23.1 21.8 115 109 47-157 6 30 trans-1,2-Dichloroethene ug/L ND 20 20 27.8 25.4 139 127 70-149 9 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.3 22.0 117 110 70-138 6 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 16.5 15.0 83 75 31-145 10 30 v3 Trichloroethene ug/L ND 20 20 23.0 21.2 115 106 70-149 8 30 Trichlorofluoromethane ug/L 0.74J 20 20 21.1 18.9 102 91 61-154 11 30 Vinyl acetate ug/L ND 40 40 60.8 57.4 152 144 48-156 6 30 v1 Vinyl chloride ug/L ND 20 20 22.6 20.6 113 103 55-172 9 30 Xylene (Total) ug/L ND 60 60 63.9 62.2 107 104 66-145 3 30 1,2-Dichloroethane-d4 (S) % 102 98 70-130 4-Bromofluorobenzene (S) % 102 103 70-130 Toluene-d8 (S) % 105 104 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 676918 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 METHOD BLANK: 3542979 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 02/09/22 03:08 LABORATORY CONTROL SAMPLE: 3542980 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 497 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3542981 3542982 MS MSD 92586721004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 480 478 95 95 80-120 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3542983 3542984 MS MSD 92586721001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 515 531 99 103 80-120 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 678978 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 METHOD BLANK: 3552932 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride mg/L ND 1.0 0.60 02/17/2213:15 Sulfate ug/L ND 1000 500 02/17/2213:15 LABORATORY CONTROL SAMPLE: 3552933 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 50 50.5 101 90-110 Sulfate ug/L 50000 49700 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3552934 3552935 MS MSD 92586338001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 10 50 50 63.3 64.5 107 109 90-110 2 10 Sulfate ug/L ND 50000 50000 53500 54600 106 108 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3552936 3552937 MS MSD 92587319020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L 31.4 50 50 84.4 85.8 106 109 90-110 2 10 Sulfate ug/L 95.9 mg/L 50000 50000 140000 142000 88 91 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 QC Batch: 677848 Analysis Method: SM 531 OB-2014 QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 METHOD BLANK: 3547974 Matrix: Water Associated Lab Samples: 92586338001, 92586338002, 92586338003, 92586338004, 92586338005, 92586338006, 92586338007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Organic Carbon ug/L ND 1000 500 02/12/22 06:07 LABORATORY CONTROL SAMPLE: 3547975 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon ug/L 25000 24000 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3547976 3547977 MS MSD 92585013022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Total Organic Carbon ug/L ND 25000 25000 24000 24000 96 96 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3547978 3547979 MS MSD 92585013024 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Total Organic Carbon ug/L 0.60J 25000 25000 25100 24900 98 97 90-110 1 10 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92586338001 MW-2R SM 4500-NO2 B-2011 676207 92586338002 MW-3S SM 4500-NO2 B-2011 676207 92586338003 MW-31) SM 4500-NO2 B-2011 676207 92586338004 MW-4 SM 4500-NO2 B-2011 676207 92586338005 MW-5 SM 4500-NO2 B-2011 676207 92586338006 MW-6 SM 4500-NO2 B-2011 676207 92586338007 DUPLICATE SM 4500-NO2 B-2011 676207 92586338001 MW-2R EPA 3010A 678247 EPA 6010D 678274 92586338002 MW-3S EPA 3010A 678247 EPA 6010D 678274 92586338003 MW-3D EPA 3010A 678247 EPA 6010D 678274 92586338004 MW-4 EPA 3010A 678247 EPA 6010D 678274 92586338005 MW-5 EPA 3010A 678247 EPA 6010D 678274 92586338006 MW-6 EPA 3010A 678247 EPA 6010D 678274 92586338007 DUPLICATE EPA 3010A 678247 EPA 6010D 678274 92586338008 SW-1 EPA 3010A 678247 EPA 6010D 678274 92586338009 SW-2 EPA 3010A 678247 EPA 6010D 678274 92586338010 SW-3 EPA 3010A 678247 EPA 6010D 678274 92586338001 MW-2R EPA 3010A 677605 EPA 6020B 677794 92586338002 MW-3S EPA 3010A 677605 EPA 6020B 677794 92586338003 MW-31) EPA 3010A 677605 EPA 6020B 677794 92586338004 MW-4 EPA 3010A 677605 EPA 6020B 677794 92586338005 MW-5 EPA 3010A 677605 EPA 6020B 677794 92586338006 MW-6 EPA 3010A 677605 EPA 6020B 677794 92586338007 DUPLICATE EPA 3010A 677605 EPA 6020B 677794 92586338008 SW-1 EPA 3010A 677605 EPA 6020B 677794 92586338009 SW-2 EPA 3010A 677605 EPA 6020B 677794 92586338010 SW-3 EPA 3010A 677605 EPA 6020B 677794 92586338001 MW-2R EPA 8260D 676585 92586338002 MW-3S EPA 8260D 676585 92586338003 MW-3D EPA 8260D 676585 92586338004 MW-4 EPA 8260D 676585 92586338005 MW-5 EPA 8260D 676585 92586338006 MW-6 EPA 8260D 676585 92586338007 DUPLICATE EPA 8260D 676585 92586338008 SW-1 EPA 8260D 676585 92586338009 SW-2 EPA 8260D 676585 92586338010 SW-3 EPA 8260D 676585 92586338011 TRIP BLANK (X2) EPA 8260D 676585 92586338001 MW-2R SM 4500-S2D-2011 676918 92586338002 MW-3S SM 4500-S2D-2011 676918 92586338003 MW-31) SM 4500-S2D-2011 676918 92586338004 MW-4 SM 4500-S2D-2011 676918 92586338005 MW-5 SM 4500-S2D-2011 676918 92586338006 MW-6 SM 4500-S2D-2011 676918 92586338007 DUPLICATE SM 4500-S2D-2011 676918 92586338001 MW-2R EPA 300.0 Rev 2.1 1993 678978 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 05:36 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: KERNERSVILLE LANDFILL Pace Project No.: 92586338 Lab ID Sample ID QC Batch Method QC Batch 92586338002 MW-3S EPA 300.0 Rev 2.1 1993 678978 92586338003 MW-31) EPA 300.0 Rev 2.1 1993 678978 92586338004 MW-4 EPA 300.0 Rev 2.1 1993 678978 92586338005 MW-5 EPA 300.0 Rev 2.1 1993 678978 92586338006 MW-6 EPA 300.0 Rev 2.1 1993 678978 92586338007 DUPLICATE EPA 300.0 Rev 2.1 1993 678978 92586338001 MW-2R SM 5310B-2014 677848 92586338002 MW-3S SM 5310B-2014 677848 92586338003 MW-313 SM 5310B-2014 677848 92586338004 MW-4 SM 5310B-2014 677848 92586338005 MW-5 SM 5310B-2014 677848 92586338006 MW-6 SM 5310B-2014 677848 92586338007 DUPLICATE SM 5310B-2014 677848 Date: 02/22/2022 05:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 41 of 58 Document Name: Document Revised: November 15,;021 Sample Condition Upon Receipt (SCUR) page 1 of 2 Document No.: Issuing Authority: a�eAnaY& F-CAR•CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[:] Greenwood ❑ Huntersville ❑ Ralejgh Mechanicsville❑ Atlanta❑ KernersvilleF Client Name: Project lf: w011 92'586338 Courier: ❑Fed x ❑UPS ❑USPS ❑Client ❑ CammeTcial ' ace ❑Other. 92586:338 Custody Seal Present? OY_es to Seals Intact? ❑Yes to 7 DeteJhklels Person EYeminlne Contents:-, `%Z� Packing Material' ❑Bubble Wrap Xbble Bags []None ❑ Other Biological Tissue Frozen? Thermometer: / []Yes []No Xg/A ❑ IR Gun ID: y et ❑Blue []NoneType of Ito: Correction Factor: Cooler Temp: - Add/Subtract ('C) r� Temp should be above freezing to 6'C []Samples out of temp criteria. Samples on Ice, coaling process Cooler Temp Corrected (7Cj: has begun USDA Regulated Soil { q` `I N/Ar water sample) Did samples originate In quarantine zone within the United States: CA, NY, or SC (check maps)? Old samples originate from a foreign source (Internationally, _ ��.,1,r.lire.4aawaliandDimRnRinrsl7-nHa_�1-iNa eras ul.0 - - Commenua Discre an : Chain of Custody Present? es No N/A I. Samples Arrived within Hold Time? Na QN1A 2. Short Hold Time Analysis (c72 hr.)? ges Na ENLA 3. Rush Turn Around Time Requested? Yes o NIA 4. Sufficient Volume? es No NA 5, Correct Containers Used? es []No❑N/A 6. -Pace Containers Used? es No WA Containers Intact? es Na N A 7. Dissolved analysis- Samles Field Filtered? Yes ONO /A S. Sample Labels Match COCZ V�s []No❑ No NIA 9. r t , (v / -includesOate/Time/ID/Analysis Matrix: Heads ace In VOA Vials >S-6mm ? Dyes o N 10. Trip Blank Present? []Yes [:)No /A 11. Trip Blank custody Seals Present? rlv.. ❑No M N/A COMMENTS/5AMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: Date: Date: Field Data Required? ❑Yes []No. Page 42 of 58 Document Name: Dmutnent Revised: November15, 2021 sample Condition Up2n Receipt SCUR) Page 2 of 2 aceAIlafytfC81 Document No.: Issuing Authority: F-CAR•CS-033•Rov.08 Pace Carolinas Quality office "Check mark top half of box if pH and/or dechlorfnation is verified and within the acceptance range For preservation samples. Exceptions: VOA, Collform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box Is to list number of bottles 2 3 4 S 5 7 tS 9 10 11 12 i1rofe" rs WUI; : 9211586338 PM: M14B Due Date: 02/18/22 CLIENT: M ithers&Ra v v v v °a A a v x `ci a a a Z ?1 g q rQr � a C a3 �3 4u Q c tt j �F LA itd m s •Y z c� 2 7 2 xis d m o.�Gny iJ 4 0 a aJ y J E a R J J J a J J J J E E E E E E S_ /pE tE E E E e E o� lryll O pO Q r4 N S .-1 rl N ei. N $ $ q a inIL N CL to Go cc 14 m- m Q 4 Q 4 a � 1111160 N U E N IEEE i� moot INE ME No MENEM INN MEN a I OEM a MEMEMM M MEN pH Adjustment Log for Preserved Samples m Type of preservative pH upon receipt Date preservation adjusted Time preservatlon adjusted Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this farm well be sent to the out of hold, Incorrect preservative, out of temp, Incorrect containers. Amount of Preservative Lot N added DEHNR Certification Office (Le. Page 43 of 58 i l m I E I 0 �. rr 0 J o-U.J. H m LL F. 'ro I � %i FE !'tYicc �= sold. �� Pis CQ INlhl 4 Y, BSI 110 pBhI0J0�! F Z-\� INlAI eu!1o143 re�Pleall � , puldNf31 i, ifi' 9 0-01 eP!1mS `iL °C 6 `ZON'sP!1�40 `liWra fM jC J� 0log AgSmErW 7� i2 7l x 7L 7i 7t 'bL i rt!': IOU aylew m EDZSZaN R ! I�rY}Si HION gym? IOH a a m o a s a` P©Nese7dun SN3NItl11i09dOY t^ y _y t ' ik'. a w NOI1031'10O1'ddW3139dNNe 3 } 75 y 3dA131dWVS (Ngio!seAmplshaen) NOOVI1l M (L $ d � GC rg a s h t B J E w n Fyo$ TLT S� r Al Y Wall 5 y 4'di 1� �s/T•! 1� { 'il �! N a Page 44 of 58 Waypointo ANALYTICAL 2/10/2022 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville, NC, 28078 Ref: Analytical Testing Lab Report Number: 22-040-0003 Client Project Description: Kernersville Landfill 92586338 Dear Matt Brainard: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/9/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a'-1 Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 45 of 58 Page 1 of 14 Waypoint.0 ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2022 North Carolina State Program 402 12/31/2022 South Carolina State Program 99012 07/31/2022 South Carolina State Program 99012 12/31/2021 Page 46 of 58 Page 1 of 1 00016/22-040-0003 Page 2 of 14 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Sample Summary Table Report Number: 22-040-0003 Client Project Description: Kernersville Landfill 92586338 Lab No Client Sample ID Matrix Date Collected Date Received 93752 MW-2R Aqueous 02/03/2022 12:00 02/09/2022 07:30 93753 MW-3S Aqueous 02/03/2022 12:20 02/09/2022 07:30 93754 MW-3D Aqueous 02/03/2022 11:20 02/09/2022 07:30 93755 MW-4 Aqueous 02/03/2022 11:05 02/09/2022 07:30 93756 MW-5 Aqueous 02/03/2022 13:45 02/09/2022 07:30 93757 MW-6 Aqueous 02/03/2022 13:20 02/09/2022 07:30 93758 DUPLICATE Aqueous 02/03/2022 11:30 02/09/2022 07:30 Page 47 of 58 Page 3 of 14 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: Kernersville Landfill Report Number: 22-040-0003 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-211 V 93752 2320B-2011 Alkalinity (as CaCO3) 133 mq/L 5 02/10/2022 09:00 MW-3S V 93753 2320B-2011 Alkalinity (as CaCO3) 155 mq/L 5 02/10/2022 09:00 MW-3D V 93754 2320B-2011 Alkalinity (as CaCO3) 167 mq/L 5 02/10/2022 09:00 MW-4 V 93755 2320B-2011 Alkalinity (as CaCO3) 174 mq/L 5 02/10/2022 09:00 MW-5 V 93756 2320B-2011 Alkalinity (as CaCO3) 11 mq/L 5 02/10/2022 09:00 MW-6 V 93757 2320B-2011 Alkalinity (as CaCO3) 6 mq/L 5 02/10/2022 09:00 DUPLICATE V 93758 2320B-2011 Alkalinity (as CaCO3) 167 mq/L 5 02/10/2022 09:00 Page 48 of 58 Page 4 of 14 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 93752 Matrix: Aqueous Sample ID: MW-2R Sampled: 2/3/2022 12:00 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 133 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 5 of 14 Page 1 of 7 Page 49 of 58 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 93753 Matrix: Aqueous Sample ID: MW-3S Sampled: 2/3/2022 12:20 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 155 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 6 of 14 Page 2 of 7 Page 50 of 58 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 93754 Matrix: Aqueous Sample ID: MW-31D Sampled: 2/3/2022 11:20 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 167 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 7 of 14 Page 3 of 7 Page 51 of 58 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 937SS Matrix: Aqueous Sample ID: MW-4 Sampled: 2/3/2022 11:05 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 174 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 8 of 14 Page 4 of 7 Page 52 of 58 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 93756 Matrix: Aqueous Sample ID: MW-5 Sampled: 2/3/2022 13:45 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 11 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 9 of 14 Page 5 of 7 Page 53 of 58 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 937S7 Matrix: Aqueous Sample ID: MW-6 Sampled: 2/3/2022 13:20 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 6 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 10 of 14 Page 6 of 7 Page 54 of 58 WavDdibnto ANALYTICAL 00148 Pace Analytical - Huntersville, NC Matt Brainard 9800 Kincey Avenue, Suite 100 Huntersville , NC 28078 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Project Kernersville Landfill Information : 92586338 Report Date : 02/10/2022 Received : 02/09/2022 Report Number : 22-040-0003 REPOR T OF A NA L YSIS Lab No : 93758 Matrix: Aqueous Sample ID: DUPLICATE Sampled: 2/3/2022 11:30 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Alkalinity (as CaCO3) Qualifiers/ DF Dilution Factor Definitions 167 mg/L 5 1 02/10/22 09:00 CLB 2320B-2011 MQL Method Quantitation Limit Page 11 of 14 Page 7 of 7 Page 55 of 58 • Charlotte, NC 28217 Waypoint, 449 Springbrook Rd, Ch Main 704.529.6364 ANALYTICAL www.waypoi ntana lytica l.com Quality Control Data Client ID: Pace Analytical - Huntersville, NC Project Description: Kernersville Landfill Report No: 22-040-0003 QC Analytical Batch: V14786 Analysis Method: 2320B-2011 Analysis Description: Alkalinity Lab Reagent Blank LRB Matrix: AQU Associated Lab Samples: 93752, 93753, 93754, 93755, 93756, 93757, 93758 Blank MQL Analyzed Parameter Units Result Alkalinity (as CaCO3) mg/L < 5 5 02/10/22 09:00 Laboratory Control Sample LCS Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Alkalinity (as CaCO3) mg/L 250 254 102 90-110 Duplicate V 93423-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) mg/L 182 183 0.5 20 02/10/22 09:00 Duplicate V 93503-DUP Result DUP RPD Max RPD Analyzed Parameter Units Result Alkalinity (as CaCO3) mg/L 345 348 0.8 20 02/10/22 09:00 Date: 02/10/2022 02:02 PM PageF'age f or 1 Page 12 of 14 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 00148 Customer Name: Pace Analytical - Huntersville, NC Report Number: 22-040-0003 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IRT-15 4.1C Shipping container/cooler uncompromised? CO,) Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? 0 Yes 0 No # Not Present Custody seals intact on sample bottles? 0 Yes 0 No # Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Sarah J. Locklear Date & Time: 02/09/2022 10:09:23 Page 13 of 14 Page 57 of 58 C) w n, -• 4 V a1 [31 $ W N ca ITT -0 x -u K m I 3 3 = fy fp CDcn Em q — m tp m Q c~rt0n� 0 (0 (D S a C N N a rn v tV p �; O a aoj� O 'a fl CD w z n 0 n n W cr N w w w w w w w • 1� Z� wl G ll N N N m N N N n s [J f.i N N al SA M 0 V1 fit p 0 0 Q p• Q a N N N N N N N d o 0000wwcoCa� w caa ca.� w c°a w w v N D 4 o 0 0 0 0 m 0 N y 4 m M w O pli O V m c � ro R Ev ER m ER m x m I_hp'2se�r�� �--� r� r--• r� r--� w N 2 Duo .M n w rC S7 0 w 0 00 ro CD a O � 3 m x X x X X X X Alkalinity @ z n n 0 N n n cu m En n °° w N 7 d n o r a W c z m z j * n C.)Q N p C) CL Q o Lrl r 0 M CST W O (� CO �� D 0 Q E T m T] 2 m CI7 C r m z T1 r r CD N C LA IA [G C CD N Ca a co •[ Page 14 of 14 Im7- v Z �_ Z 5►!i!� LV p�»v�goi.Lk9 0 m--bo — _L-- APPENDIX II Historical Summary Tables (2009-2014) TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Background Downgradient Well ID: MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 TOC Elevation: 806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth: 34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY WELL NUMBER CASING DIAMETER inches WELL ELEVATIONS TOTAL DEPTH SCREENED INTERVAL* LITHOLOGY OF SCREENED INTERVAL* GROUND SURFACE T.O.C. B.G.S. feet B.T.O.C. feet DEPTH B.G.S. ELEV. M.S.L. feet above M.S.L. from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S. Below Ground Surface M.S.L. Mean Sea Level B.T.O.C. Below Top of Casing T.O.C. Top of Casing * = Due to limited information this data is assumed based on field conditions Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY November 2014 GRADIENT FLOW LINE GROUND- HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW WATER GRADIENT, CONDUCTIVITY POROSITY VELOCITY, CALCULATION LENGTH DIRECTION ELEV. i K n V SEGMENT (feet) feet ft/ft ft/da ft/da l i 851 SW 0.04 1.73 0.30 0.20 785 Notes: 1. Hydraulic conductivities ("K") was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 --- ND 5.4 B ND ND 4.5 B --- 1.4 J GWPS = 1.4 µg/L (10/23/07) 01-Jun-10 1.2 6.0 --- ND ND ND ND ND --- 3.9 1 GAPS = 1 µg/L (8/1/10) 29-Dec-10 2.6 6.0 --- ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 6.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 --- --- ND ND ND ND --- ND 09-May-13 5.0 6.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 6.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 6.0 --- ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 --- --- ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10) O1-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 --- --- 1.43 B 1.42 B 0.87 B 1.04 B --- 1.0 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 --- 74.1 J 496 178 18.2 J 89.0 J --- 3.6 J NC 2L = 700 µg/L (1/11/10) 01-Jun-10 1.1 100 --- 58.1 J 326 187 22.2 J 94.9 J --- 2.0 J 29-Dec-10 0.20 100 --- 46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 --- 77.7 J 370 128 41.2 J 98.4 J 113 ND O1-Nov-11 5.0 100 --- 125 413 132 41.7 J 111 72.1 J ND O1-May-12 5.0 100 --- 78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 --- --- 369 127 41.0 B 98.7 J --- 12.2 J 09-May-13 5.0 100 --- 78.6 J 307 112 40.0 J 85.6 J --- ND 07-Nov-13 5.0 100 --- --- 302 113 38.0 J 89.6 J --- ND 05-Jun-14 5.0 100 --- 60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 --- --- 301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 --- ND 0.5 J ND ND ND --- ND GWPS = 4 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- 0.6 1 0.7 J ND ND ND --- ND 29-Dec-10 0.10 1.0 --- ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 --- --- 0.34 J ND ND 0.099 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 --- ND 0.5 J 5.6 ND ND --- ND NC 2L = 2 µg/L (1/11/10) 01-Jun-10 0.2 1.0 -- 2.9 1.0 B 5.3 0.4 B 0.4 B --- 0.4 J 29-Dec-10 0.50 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 --- --- 0.15 J ND ND 0.043 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 --- ND 2.7 J 9.7 J ND 3.1 J --- ND NC 2L = 10 µg/L (1/11/10) 01-Jun-10 0.7 10.0 --- 3.5 J 1.6 J 12.4 1.2 J 3.2 J --- ND 29-Dec-10 0.40 10.0 --- 0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 10.0 --- ND ND ND ND 10.3 ND ND O1-May-12 5.0 10.0 --- ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 --- --- 0.71 J 0.12 B 0.094 B 7.31 J --- 0.099 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 --- ND 6.4 J 11.2 ND 1.8 J --- ND GAPS = 70 µg/L (10/23/07) 01-Jun-10 0.7 10.0 --- 1.8 J 2.5 J 8.5 J ND 1.7 J --- ND GAPS = 1 µg/L (10/1/10) 29-Dec-10 0.60 10.0 --- ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 --- ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 --- --- 1.98 J 3.89 J 0.43 B 2.02 J --- 0.24 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 --- ND ND 10.6 ND 1.5 J --- ND NC 2L = 1,000 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 12.2 B 3.3 B 33.2 3.9 B 6.8 B --- 4.8 .1 29-Dec-10 0.30 10.0 --- ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 --- 3.56 B 0.54 B 0.98 B 1.83 B --- 1.23 1 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 --- ND ND 10.2 ND ND --- ND NC 2L = 15 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 9.1 B 8.2 B 8.7 B 3.0 B 3.9 B --- 3.2 .I 29-Dec-10 4.0 10.0 --- ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 --- 5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 --- --- 1.00 B 0.091 B 0.066 B 1.12 B --- 0.58 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 --- ND ND 8.1 1 1.8 J 1.6 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.6 50.0 --- ND ND 6.0 J ND 0.9 J --- ND 29-Dec-10 1.7 50.0 --- ND ND ND ND ND 2.0 B 3.1 1 29-Jun-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 50.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 --- --- 0.73 B 1.19 B 0.65 B 5.57 J --- 0.84 1 09-May-13 5.0 50.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 50.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 50.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 --- --- ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 --- ND ND 8.4 J ND ND --- ND NC 2L = 20 µg/L (1/11/10) 01-Jun-10 6.3 10.0 --- ND ND 6.3 J ND ND --- ND 29-Dec-10 3.8 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 10.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 --- --- 0.16 J 0.38 J 0.20 J 0.25 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 --- --- ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 --- ND 1.7 B 2.2 B ND ND --- 1.9 J NC 2L = 20 µg/L (1/11/10) 01-Jun-10 1.1 10.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.10 10.0 --- ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 --- 0.18 J ND ND 0.078 J --- ND 09-May-13 5.0 10.0 --- NI) ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- NI) ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 --- ND ND ND ND ND --- 3.7 1 GWPS = 0.28 µg/L (10/23/07) 01-Jun-10 2.7 5.5 --- ND ND ND ND ND --- ND GWPS = 0.2 µg/L (10/1/10) 29-Dec-10 3.0 5.5 --- ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-May-12 5.4 5.5 --- ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 --- --- 0.16 J ND ND 0.76 J --- ND 09-May-13 5.4 5.5 --- ND ND ND ND ND --- ND 07-Nov-13 5.4 5.5 --- --- ND ND ND ND --- ND 05-Jun-14 5.4 5.5 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 --- --- ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 --- ND 1.4 J 37.4 1.5 J 4.3 J --- ND GWPS = 3.5 µg/L (10/23/07) 01-Jun-10 0.4 25.0 --- 1.2 J 3.4 J 84.2 1.4 J 4.8 J --- ND GWPS = 0.3 µg/L (10/1/10) 29-Dec-10 0.20 25.0 --- 1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 1 29-Jun-11 5.0 25.0 --- ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 --- 7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 --- ND ND ND ND 7.2 J 7.6 1 ND 07-Nov-12 0.085 25.0 --- --- 2.48 J 2.02 J 2.35 J 4.55 J --- ND 09-May-13 5.0 25.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 25.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 25.0 --- ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 --- --- ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 --- ND 10.1 B 204 15.9 B 24.8 B --- 5.8 .I NC 2L = 1,000 µg/L (1/11/10) 01-Jun-10 2.7 10.0 --- 16.2 13.5 415 8.5 J 22.2 --- ND 29-Dec-10 0.40 10.0 --- 12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 --- ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 --- 16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 --- ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 --- --- 8.61 J 5.20 J 3.98 J 4.65 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- 13.8 10.4 ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 --- --- ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 --- ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 1 NC 2L = 6,000 µg/L (1/11/10) 01-Nov-11 2.2 100 --- ND ND ND ND ND ND 14.6 1 01-May-12 2.2 100 --- ND ND ND ND ND ND ND 07-Nov-12 0.193 100 --- --- ND ND ND ND --- ND 09-May-13 10.0 100 --- ND ND ND ND ND --- 12.0 1 07-Nov-13 10.0 100 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 100 --- ND ND ND ND ND ND ND 20-Nov-14 10.0 100 --- ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 --- ND 8.4 0.3 J 0.4 J 0.3 J --- ND NC 2L = 1 µg/L (10/23/07) 01-Jun-10 0.1 1.0 -- ND 2.9 ND ND ND --- ND 29-Dec-10 0.25 1.0 --- ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 --- ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 --- ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 --- ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 --- --- 8.63 0.430 J 0.504 J 0.478 J --- ND 09-May-13 0.25 1.0 --- ND 5.2 0.27 J 0.32 J 0.30 J --- ND 07-Nov-13 0.25 1.0 --- --- 6.9 0.33 J 0.38 J 0.39 J --- ND 05-Jun-14 0.25 1.0 --- ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 --- --- 6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 --- ND ND 0.37 B ND ND --- 0.37 J NC 2L = µg/L 4 (10/23/07) 07-Nov-13 0.26 3.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 3.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 --- --- ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 --- ND 0.5 J 0.6 J ND ND --- ND NC 2L = 50 µg/L (10/23/07) 01-Jun-10 0.1 3.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.23 3.0 --- ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 --- ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 --- ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 --- ND {0.42} J 0.94 B 0.38 B ND ND 0.30 {ND} .I 07-Nov-12 0.083 3.00 --- --- 0.468 J 1.30 J 0.476 J ND --- ND 09-May-13 0.23 3.0 --- ND 0.27 J 0.72 J 0.27 J ND --- ND 07-Nov-13 0.23 3.0 --- --- 0.42 J 0.97 J 0.38 J ND --- ND 05-Jun-14 0.23 3.0 --- ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 --- ND ND 0.5 J 0.5 J ND --- 0.1 J NC 2L = 3,000 µg/L (1/11/10) 01-Jun-10 0.1 10.0 --- ND ND 0.4 J ND ND --- ND 29-Dec-10 0.54 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 --- ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 --- ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 --- --- ND ND ND ND --- ND 09-May-13 0.54 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.54 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.54 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 --- --- ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 --- ND 3.8 2.2 2.3 3.1 --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.2 0.9 J ND 1.2 --- ND 29-Dec-10 0.33 1.0 --- ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 --- ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 --- ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 --- ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 --- 5.12 2.93 4.08 3.64 --- ND 09-May-13 0.33 1.0 --- ND 3.6 2.0 3.1 2.3 --- ND 07-Nov-13 0.33 1.0 --- --- 5.4 2.5 4.2 3.2 --- ND 05-Jun-14 0.33 1.0 --- ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 --- --- 4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 --- ND 22.8 1.9 J 4.0 J 2.4 J --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.2 5.0 --- ND 11.0 1.1 J ND 1.2 J --- ND 29-Dec-10 0.32 5.0 --- ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 --- ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 --- ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 --- ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 --- --- 28.1 2.06 J 4.08 J ND --- ND 09-May-13 0.32 5.0 --- ND 18.7 1.4 J 3.0 J 1.6 J --- ND 07-Nov-13 0.32 5.0 --- --- 26.6 1.7 J 4.2 J 2.2 J --- ND 05-Jun-14 0.32 5.0 --- ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 --- --- 21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 --- ND 1.2 0.7 J 1.2 ND --- ND NC 2L = 0.4 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.12 1.0 --- ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 --- ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 --- ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 --- ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.12 1.0 --- ND 0.50 J 0.49 J 0.81 J ND --- ND 07-Nov-13 0.12 1.0 --- --- 0.93 J 0.66 J 1.3 ND --- ND 05-Jun-14 0.12 1.0 --- ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 --- --- 0.68 J 0.47 J 0.81 J ND ND ND 1,1-Dichloroethylene 30-Dec-09 0.1 5.0 --- ND 0.4 J ND ND ND --- ND NC 2L = 7 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.56 5.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-May-12 0.56 5.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 --- --- ND ND ND ND --- ND NC 2L = 350 µg/L (04/01/2013) 09-May-13 0.56 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.56 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.56 5.0 --- ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 --- ND ND ND ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 68.2 11.0 51.0 21.8 --- ND NC 2L = 70 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 23.0 7.6 ND 10.2 --- ND 29-Dec-10 0.19 5.0 --- ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 --- ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 --- ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 --- ND {48.7{ 14.2 59.5 22.1 ND 0.21 {ND} J 07-Nov-12 0.103 5.00 --- 59.7 13.6 71.3 26.4 --- ND 09-May-13 0.19 5.0 --- ND 39.9 10.9 49.7 17.4 --- ND 07-Nov-13 0.19 5.0 --- 53.9 10.7 67.1 21.8 --- ND 05-Jun-14 0.19 5.0 --- ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 --- 44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 1.4 J ND 0.2 J 0.2 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 0.6 J ND ND ND --- ND 29-Dec-10 0.49 5.0 --- ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 --- ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 --- ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 --- --- 1.59 J ND ND ND --- ND 09-May-13 0.49 5.0 --- ND 1.1 J ND ND ND --- ND 07-Nov-13 0.49 5.0 --- --- 1.6 J ND ND ND --- ND 05-Jun-14 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 --- --- 1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 --- ND 5.7 0.6 J 1.1 0.7 J --- ND NC 2L = 0.6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.9 ND ND ND --- ND 29-Dec-10 0.27 1.0 --- ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 --- ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 --- ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 --- ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 --- 4.93 ND 1.66 ND --- ND 09-May-13 0.27 1.0 --- ND 3.3 0.51 J 0.96 J 0.45 J --- ND 07-Nov-13 0.27 1.0 --- --- 4.4 0.63 J 1.3 0.57 J --- ND 05-Jun-14 0.27 1.0 --- ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 --- --- 4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 --- ND ND ND 0.4 J ND --- ND NC 2L = 600 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.30 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.30 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.30 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.30 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.30 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 --- --- ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 --- ND 1.2 ND ND ND --- ND NC 2L = 0.7 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- ND 1.4 ND ND ND --- ND 29-Dec-10 0.46 1.0 --- ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 --- ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 --- ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 --- ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 --- --- 2.52 ND ND ND --- ND 09-May-13 0.46 1.0 --- ND 1.9 ND ND ND --- ND 07-Nov-13 0.46 1.0 --- --- 1.8 ND ND ND --- ND 05-Jun-14 0.46 1.0 --- ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 --- --- 1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 --- ND ND ND ND ND 0.76 J ND NC 2L= 600 µg/L (1/11/10) 01-Nov-11 0.26 1.0 -- ND ND ND ND ND ND ND 01-May-12 0.26 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.26 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.26 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 --- --- ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 --- ND 8.0 ND ND 0.2 J --- ND NC 2L = 3 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 6.4 ND ND ND --- ND 29-Dec-10 0.47 1.0 --- ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 --- ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 --- ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 --- ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 --- 9.97 ND ND ND --- ND 09-May-13 0.47 1.0 --- ND 8.4 ND ND ND --- ND 07-Nov-13 0.47 1.0 --- 8.0 ND ND ND --- ND 05-Jun-14 0.47 1.0 --- ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 --- --- 5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 --- ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10) 01-Nov-11 0.20 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.20 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.20 1.0 --- ND 0.66 J ND ND ND --- ND 07-Nov-13 0.20 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.20 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Analyte Sample Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 --- ND 4.0 2.8 4.1 26.2 --- ND NC 2L = 0.03 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 2.2 3.0 ND 26.7 --- ND 29-Dec-10 0.62 1.0 --- ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 --- ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 --- ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 --- ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 --- --- 7.94 2.73 6.99 29.9 --- ND 09-May-13 0.62 1.0 --- ND 2.8 1.9 4.2 18.6 --- ND 07-Nov-13 0.62 1.0 --- --- 6.3 2.1 6.0 21.9 --- ND 05-Jun-14 0.62 1.0 --- ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 --- --- 5.2 2.1 5.3 16.2 ND ND Xylene (Total) 30-Dec-09 0.3 4.0 --- ND ND ND 3.5 J ND --- ND NC 2L= 500 µg/L (1/11/10) 01-Jun-10 0.3 4.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.66 2.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-May-12 0.66 2.0 --- ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 --- --- ND ND ND ND --- ND 09-May-13 0.66 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.66 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.66 5.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07) 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 02 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07) 01-Jun-10 02 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07) 01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 .1 ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07) 01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07) 01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07) 09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 020 25.0 0.67 B 0.37 B 0.62 B 0.26 1 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07) O1-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND O 1-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07) 01-Nov-11 2.2 100 ND ND ND 14.6 J O1-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 1 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) O1-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND) J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 --- 4600 J 148000 147000 160000 186000 (ug/L) Nov-14 1000.0 5000 --- --- 159000 151000 159000 181000 Sulfate Jun-14 2000 250000 --- 6500 J ND ND ND ND (ug/L) Nov-14 1000 250000 --- --- 1760 J 1730 J 1870 J 1560 J Nitrogen, Nitrate Jun-14 20.0 1000 --- 72 J 56 J ND ND ND (ug/L) Nov-14 10.0 1000 --- --- 45 J ND ND ND Methane Jun-14 3.3 6.6 --- --- 5530 254 242 515 (ug/L) Nov-14 3.3 6.6 --- --- 4980 159 182 186 Chloride Jun-14 1000 1000 --- 2220 11200 25900 16800 15600 (ug/L) Nov-14 500 1000 --- --- 17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 --- 3100 10600 8300 1500 8200 (ug/L) Nov-14 500 1000 --- --- 2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 --- --- 1.5 1.2 120 3.5 (nM) Nov-14 0.13 0.6 --- --- 2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 --- ND ND ND ND ND (ug/L) Nov-14 2000 2000 --- --- 4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 --- N D ND ND ND ND (ug/L) Nov-14 12500 25000 --- --- ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP points Points Awarded without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 1 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 I 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >200 C At T > 200C biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product I 1 I 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine I 2 I 2 I 2 Hydrogen > 1 nM Reductive pathway possible 3 1 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination I 2 0 I 0 Tetrachloroethene (PCE) --- Material released 0 0 0 Trichloroethene (TCE) --- Material released 0 0 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE) --- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2, --- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC) --- Material released 0 0 0 --- Daughter product of DCE 2 2 0 1, 1, 1 -Trichloroethane (TCA) --- Material released 1 0 0 0 1,1-Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC) --- Material released 0 0 0 (Methylene Chloride) --- Daughter product of chloroform 2 0 1 0 Based on data collected in November 2014. Total Points Awarded : 23 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evid. of Nat. Atten. < 5 inadequate 6-14 limited 15-19 adequate > 20 strong Town of Kernersville Joyce Engineering