3902_Granville_Butner_MSWLF_Feb22GW_FID1684613_202220617

GARRETT� /
& MOORE
Engineering for the Power and Waste Industries
June 15, 2022
Ms. Jaclynne Drummond
Department. of Environmental Quality
Solid Waste Section
Asheville Regional Office
2090 US Highway 70
Swannanoa, North Carolina 28778
0aclynne.drummond(a)-ncdenr.gov
RE: Water Quality Monitoring Report — February 2022 Event
Granville County Butner Landfill
Butner, North Carolina
Permit # 39-02
Dear Jackie:
On behalf of Granville County, please find attached the Water Quality Monitoring Report for the
Butner Landfill for the 11t semi-annual sampling event of 2022. If you have any questions or
require further assistance regarding this matter, please do not hesitate to call me at 919-792-
1903.
Sincerely,
Garrett & Moore, Inc.
S efan Bra , P.E.
Cc: Jason Falls, Granville County
1029 West South Street • Raleigh, North Carolina 27 • O: 919-792-1900 • F: 866-311-7206

hart '� hickman
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Via E-Mail
[e-mail]
June 15, 2022
Garrett & Moore, Inc.
1029 West South Street
Raleigh, NC 27603
sbrayk Barrett-moore. com
Attn: Mr. Stefan Bray, PE
Re: Water Quality Monitoring Report — February 2022
Granville County Butner Landfill
Butner, Granville County, NC
Facility Permit No. 39-02
H&H Job No. GMI-003
Dear Stefan:
Hart & Hickman, PC (H&H) is submitting the attached Water Quality Monitoring Report —
February 2022 documenting sample results for the Butner Landfill for the first semiannual
sampling event of 2022. H&H appreciates the opportunity to work with you on this project. If
you have any questions or require additional information, please do not hesitate to contact us at
704-586-0007.
Very truly yours,
Hart & Hickman, PC
Jason Soban, PG
Project Manager
Jeffrey 011ison
Project Environmental Scientist
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
704_S86.0007 main
3921 Sunset Ridge Rd, Suite 301
Raleigh, NC 27607 www.harthickman.com
919.847.4241 main

ENR USE ONLY: ❑Paper Report ©Electronic Data - Email CD (data loaded: Yes / No) DoclEvent #:
NC ❑ENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Inforrnation
Name of entity submitting data (laboratory, consultant, facility owner):
Garrett & Moore, Inc.
Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address:
Name: Stefan Bray Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g
Facility name: Facility Address: Facility Permit # (.0500 or 1600) October 20-24, 2006)
Granville County State Road 1004
Butner Landfill Butner, NC 27565 39-02 .1600 February 16, 2022
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring Detection Monitoring QX Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells ❑X
Leachate monitoring data ❑
Surface water monitoring data
Methane gas monitoring data
Corrective action data (specify) MNA Parameters
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values. NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Fj Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Jason Soban, PG Consultant for Facility [phone]
Facility Representative Name (Print)
)a Title (Area Code) Telephone Number
.yf S ) 9.5 2 L Affix NC Licensed/ Professional Geologist Seal
Signature
2923 S Tryon Street, Suite 100. Charlotte, NC 28203
Facility Representative Address
C-1269 (Engineering) 245 (Geology)
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
Date AjO,14%i rurrrrr"P
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Water Quality Monitoring Report
February 2022
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
June 15, 2022
op THE COUNTY OF
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Engineering for the Power and Waste Industries
hart � hickman
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2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919.847.4241 main

Water Quality Monitoring Report — February 2022
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
Table of Contents
Section Pate
1.0 Introduction................................................................................................................. I
1.1
Site Information........................................................................................................1
1.2
Regulatory Status......................................................................................................1
1.3
Groundwater Monitoring Program...........................................................................2
1.4
Surface Water Monitoring Program.........................................................................3
2.0 Water Quality Monitoring Activities........................................................................4
2.1
Water Level Measurements......................................................................................4
2.2
Groundwater Sampling Methods..............................................................................4
2.3
Surface Water Sampling Methods............................................................................5
2.4
Sample Equipment Management..............................................................................5
2.5
Sample Handling and Laboratory Analyses.............................................................6
3.0 Water Quality Monitoring Results............................................................................7
3.1
Groundwater Flow and Hydraulic Gradient.............................................................7
3.2
Groundwater Analytical Results...............................................................................8
3.3
Surface Water Analytical Results.............................................................................9
3.4
Quality Assurance/Quality Control Results............................................................10
4.0 Corrective
Action Evaluation..................................................................................12
4.1
Monitored Natural Attenuation Parameters............................................................12
4.2
Phytoremediation....................................................................................................12
4.3
Evaluation of Plume Stability and Trends..............................................................13
5.0 Conclusions
................................................................................................................15
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List of Tables
Table 1
Summary of Well Construction Details
Table 2
Summary of Groundwater Elevations
Table 3
Summary of Field Parameters
Table 4
Summary of Groundwater Flow Velocity
Table 5
Summary of Constituent Detections (February 2022)
Table 6
Summary of Constituent Exceedances (February 2022)
Table 7
Summary of Monitored Natural Attenuation Parameters
List of Figures
Figure 1 Site Location Map
Figure 2 Site Plan
Figure 3 Groundwater Potentiometric Map (February 15, 2022)
List of Appendices
Appendix A
Groundwater and Surface Water Sampling Records
Appendix B
Laboratory Analytical Report
Appendix C
Summary of Historical Groundwater Elevations
Appendix D
Summary of Historical Constituents in Groundwater
Appendix E
Summary of Historical Constituents in Surface Water
Appendix F
Summary of Historical Monitoring Natural Attenuation Parameters
Appendix G
Concentration vs. Time Charts
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Water Quality Monitoring Report — February 2022
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
1.0 Introduction
This Water Quality Monitoring Report (Report) has been prepared by Hart & Hickman, PC (H&H)
to document the methods and results of semiannual groundwater and surface water monitoring
activities conducted at the Butner Landfill located off State Route 1004 near the Town of Butner,
Granville County, North Carolina. A site location map is included as Figure 1. Water quality
monitoring at the site was performed in general accordance with the Water Quality Monitoring
Program as described in the Corrective Action Plan (May 2014), which was approved by the North
Carolina Department of Environmental Quality (DEQ) Solid Waste Section (SWS).
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the Town of Butner, Granville County, North Carolina. The Butner facility started receiving
solid waste prior to May 1973. Permit Number 39-02 was issued by the State of North Carolina
on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the present, a
small recycling center and transfer station are operated by the County of Granville at the entrance
of the closed landfill. A site layout map that depicts the facility features is included as Figure 2.
1.2 Regulatory Status
The Butner Landfill entered an Assessment Monitoring Program in December of 1997 because of
detections of volatile organic compounds (VOCs) and pesticides above the North Carolina 2L
Groundwater Standards (2L Standards). An Assessment of Corrective Measures (ACM) was
initiated in 2003, and then suspended by DEQ since there had been no more 2L Standard
exceedances. The Nature and Extent Study (NES) and ACM were recommenced in 2007 when
apparent VOC exceedances of the 2L Standard began to appear; however, they were again
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suspended when it was determined that the apparent exceedances were not statistically significant
increases (SSIs) above background. An ACM was reinitiated after an exceedance of benzene in
monitoring well MW-2R in December 2012 and was submitted to DEQ in May 2013. Approval
of the ACM was granted in a letter from DEQ dated June 27, 2013. A Corrective Action Plan
(CAP) for monitored natural attenuation (MNA) plus phytoremediation was submitted to DEQ on
May 23, 2014, and was approved by DEQ on June 18, 2014.
The site is currently in an Assessment Monitoring Program and Corrective Action Monitoring
Program. Groundwater and surface water samples are collected semiannually and analyzed in
accordance with the approved CAP. An overview of the monitoring program is provided in the
following sections.
1.3 Groundwater Monitoring Program
The groundwater monitoring program at the Butner Landfill consists of the following seven
monitoring wells: MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Monitoring
well MW-IR is located northwest and upgradient of the landfill and serves as a background
location. The compliance network consists of monitoring wells MW-2R, MW-3R, MW-4, MW-
5, and MW-6, which are situated cross -gradient and downgradient of the landfill. Compliance
monitoring wells MW-2R and MW-3R are located at the southern downgradient side of the landfill
and also serve as CAP performance wells. Monitoring well NES-1 is located downgradient of
MW-2R and MW-3R and serves as a CAP sentry well. The monitoring well locations and other
site features are identified on Figure 2. A summary of well construction details is provided in
Table 1.
Groundwater samples are collected semiannually and analyzed for North Carolina Solid Waste
Management Rules Appendix I and Appendix II constituents (hereafter referred to as NC
Appendix I constituents and NC Appendix II constituents, respectively). In addition, groundwater
samples collected during the second half semiannual monitoring event each year are analyzed for
monitored natural attenuation (MNA) constituents. Note, although not required, MNA samples
were collected from site wells during the subject first half semiannual sampling event.
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1.4 Surface Water Monitoring Program
The surface water monitoring program at the Butner Landfill consists of collecting samples from
two locations (SW-1 and SW-2) along an unnamed tributary to Picture Creek which is situated
along the southern downgradient boundary of the site. Picture Creek is classified as a Class IV
(Water Supply) stream. The surface water sampling points are located downgradient of the facility
at upstream (SW-1) and downstream (SW-2) locations. The locations of the surface water
monitoring points are identified on Figure 2. Surface water samples are collected semiannually
and analyzed for NC Appendix I constituents plus 1,4-dioxane.
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2.0 Water Quality Monitoring Activities
2.1 Water Level Measurements
On February 15, 2022, Environmental Field Management, Inc. (EFM) measured depth -to -water
and total depths in monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-
1. Depth -to -water measurements were collected from the top -of -casing utilizing a decontaminated
electronic water level indicator. Depth -to -water measurements were made after the wells were
opened for a sufficient period of time to allow water levels to equilibrate with atmospheric
pressure. Water level measurements and calculated groundwater elevations are presented in Table
2.
2.2 Groundwater Sampling Methods
On February 16, 2022, EFM collected groundwater samples from site monitoring wells MW-1R,
MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Monitoring well MW-1R serves as the
upgradient background well for the facility, and monitoring wells MW-2R, MW- 3R, MW-4, MW-
5, MW-6, and NES-1 serve as compliance monitoring wells. The groundwater samples were
collected and handled in accordance with the sampling protocols included in the site Water Quality
Monitoring Plan as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water
Sampling document.
The monitoring wells were purged utilizing a peristaltic pump or submersible pump under low
flow (< 200 milliliters/minute) conditions. Water levels were recorded during the purging process
to ensure the pump rate did not cause significant drawdown of the water column, and samples were
collected following stabilization of field parameters over three consecutive readings. Field
measurements of pH, temperature, specific conductance, oxygen reduction potential (ORP), and
dissolved oxygen (DO) were measured using a YSI Pro Plus water quality meter. Turbidity was
measured using a Hach 2100Q turbidity meter. A summary of the final field parameters recorded
prior to sample collection is presented in Table 3. Copies of groundwater sampling forms
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containing pertinent information recorded in the field during purging and sampling at each
monitoring well are presented in Appendix A.
The results of the field -measured water quality parameters indicate that the values measured in
groundwater collected from site monitoring wells were within applicable stabilization criteria.
Groundwater at the site is acidic based on the pH values measured in the field (4.95 to 6.77
Standard Units). Specific conductance values in site groundwater ranged from 81.4 (NES-1) to
2,095 (MW-2R) microsiemens per centimeter (µS/cm) with higher values measured at well
locations immediately downgradient of the landfill. Turbidity values ranged from 0.03 (MW-3R)
to 19.8 (NES-1) nephelometric turbidity units (NTUs). The collected groundwater sample from
NES-1 exhibited a turbidity above the target level of 10 NTU.
2.3 Surface Water Sampling Methods
On February 16, 2022, EFM collected surface water samples from sample locations SW-1 and
SW-2 (Figure 2). Surface water samples were collected in general accordance with the site Water
Quality Monitoring Plan as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface
Water Sampling document. Surface water sampling was conducted starting downstream and
working upstream. Field parameters were measured during sample collection and copies of
surface water sampling forms are provided in Appendix A. A summary of field parameters
recorded prior to sample collection is provided in Table 3.
2.4 Sample Equipment Management
Reusable sampling equipment (e.g., water level indicator, submersible pump) was properly
decontaminated between sampling locations with a non -phosphate soap and water wash, followed
by multiple rinses with distilled water. New disposable nitrile or latex gloves were worn during
sampling activities. Disposable sampling equipment/material was discarded after each use.
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2.5 Sample Handling and Laboratory Analyses
Upon sample collection, samples for laboratory analysis were placed directly into dedicated
laboratory -supplied sample bottles, labeled, and placed into ice -filled coolers. A chain -of -custody
record was completed and included sample description, analyses required, matrix, sample
container information, and date and time of sample collection. The samples were transported on
ice, under standard chain -of -custody protocol, to Pace Analytical Services, Inc. (Pace) in
Huntersville, North Carolina. Pace is a North Carolina -certified laboratory. The laboratory
analytical report and chain -of -custody record for the February 2022 sampling event are included
in Appendix B. A summary of samples collected during the subject reporting period is provided
below.
The groundwater samples from monitoring wells MW-1R, MW-2R, and MW-3R were analyzed
for the NC Appendix I and II list of constituents, plus 1,4-dioxane. Additionally, the groundwater
sample from monitoring well NES-1 was analyzed for benzene, 1,4-dioxane, and cobalt as
constituents of concern (COCs). The groundwater samples from monitoring wells MW-1R, MW-
2R, MW-3R and NES- 1 were also analyzed for MNA parameters. The groundwater samples from
monitoring wells MW-4, MW-5, and MW- 6 were analyzed for the NC Appendix I list of
constituents plus 1,4-dioxane. The surface water samples from SW-1 and SW- 2 were analyzed
for NC Appendix I constituents plus 1,4-dioxane.
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3.0 Water Quality Monitoring Results
Groundwater and surface water monitoring activities were conducted at the site on February 15
and 16, 2022. Groundwater and surface water samples were collected and analyzed in accordance
with the DEQ approved CAP and changes to the CAP documented in DEQ approved Corrective
Action Evaluation Reports (CAER; December 2016 and December 2020). The monitoring results
are discussed in the following sections.
3.1 Groundwater Flow and Hydraulic Gradient
A summary of monitoring well gauging and water level elevation data is provided in Table 2.
Historical groundwater elevation data is provided in Appendix C. Groundwater flow direction,
average hydraulic gradient, and average interstitial flow velocity were derived from water -level
measurements recorded during the February 2022 sampling event. A potentiometric map
generated from the February 15, 2022 gauging event is provided as Figure 3. The February 2022
water levels measured at downgradient wells are on average slightly lower than the August 2021
event, but within the range of historical seasonal fluctuations. Consistent with historical trends,
the overall direction of shallow groundwater flow at the site is south to southeast towards the
unnamed tributary to Picture Creek.
The hydraulic gradient in the vicinity of each well was derived by dividing the elevation difference
between water table elevations measured at the monitoring wells and proximal potentiometric
contour lines, by the perpendicular horizontal distance between the wells and potentiometric
contours (Figure 3 and Table 4). The potentiometric contours indicate an average hydraulic
gradient of approximately 0.044 ft./ft. Results of in -situ slug testing reported by others (LaBella,
2021) indicate an average hydraulic conductivity value in the shallow surficial aquifer of 6.18 x
10-2 feet/day (approximately 22.6 feet/year). Using the horizontal hydraulic gradient
measurements, the individual estimate of hydraulic conductivity, and an assumed effective
porosity of 0.18 (LaBella, 2021), the range of average interstitial groundwater flow velocities for
the shallow surficial aquifer was calculated using the following equation: Vx = (K/ne) x dh/dl.
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Where:
V,, = average interstitial groundwater flow velocity;
K = hydraulic conductivity;
ne = effective porosity; and,
dh/dl = horizontal hydraulic gradient
Average linear flow velocities are estimated to range between approximately 3.30 to 7.66 feet/year
(0.009 to 0.021 feet/day), with a geometric mean of 5.47 feet/year (0.015 feet/day). These values
are consistent with prior monitoring events. Table 4 summarizes the data used to calculate the
average interstitial groundwater flow velocity in the vicinity of each monitoring well.
3.2 Groundwater Analytical Results
Semiannual groundwater sampling consisted of collecting samples from seven site monitoring
wells. A summary of groundwater constituent detections from the February 2022 sampling event
is provided in Table 5. A summary of groundwater constituent exceedances from the February
2022 sampling event is provided in Table 6. Historical analytical results are presented in
Appendix D. Consistent with the CAP and subsequent changes documented in DEQ approved
CAERs (December 2016 and December 2020), the primary COCs for the site include benzene,
1,4-dioxane, and cobalt. A summary of groundwater results for site COCs and other exceedances
is provided below.
Organic Analyses
The analytical results indicate VOCs benzene, chlorobenzene, chloroethane, 1,4-dioxane,
naphthalene, toluene, and xylene were detected at concentrations above laboratory method
detection limits (MDLs) in one or more wells during the February 2022 sampling event. Benzene
was detected at a concentration above its 2L Standard (1 µg/L) in MW-2R (1.5 µg/L). The
concentration of benzene detected in MW-2R is consistent with historical data and has been
addressed in the ACM (approved in June 2013) and the CAP (approved in June 2014). 1,4-
Dioxane (up to 107 µg/L) was detected at concentrations above its 2L Standard (3 µg/L) in
monitoring wells MW- 2R, MW-3R, MW-4, and MW-5, and concentrations are consistent with
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historical detections. No other organic constituents were detected above 2L Standards during the
February 2022 sampling event.
Inorganic Anal
The analytical results indicate metals arsenic, barium, cobalt, copper, lead, nickel, selenium, tin,
vanadium, and zinc were detected at concentrations above MDLs in one or more wells during the
February 2022 sampling event. Arsenic was detected at concentrations slightly above its 2L
Standard (10 µg/L) in MW-2R (11.5 µg/L) and MW-3R (11.2 µg/L), and concentrations are
consistent with historical detections at these locations. As detailed in prior reports, arsenic
detections in site groundwater were not considered to be statistically significant increases
compared to background values. Cobalt (up to 40.2 µg/L) was detected at concentrations above
its 2L Standard (1 µg/L) in MW-2R, MW-3R, MW-4, MW-5, and MW-6. Historic concentrations
of cobalt have fluctuated above 2L Standards and below laboratory MDLs in MW-3R, MW-4 and
MW-6, and current concentrations are comparable to historical detections. The concentrations of
cobalt in MW-2R and MW-5 are consistent with historical data. No other inorganic constituents
were detected above 2L Standards during the February 2022 sampling event.
3.3 Surface Water Analytical Results
Semiannual surface water sampling consisted of collecting samples from two locations, one
upstream (SW-1) and one downstream (SW-2) location. A summary of surface water constituent
detections from the February 2022 sampling event is provided in Table 5. A summary of surface
water constituent exceedances from the February 2022 sampling event is provided in Table 6.
Historical analytical results are presented in Appendix E. A discussion of the results for the
February 2022 sampling event is provided below.
The analytical results indicate three constituents (1,4-dioxane, barium, and nickel) were detected
above the MDL in the sample collected from upstream location SW-1. In addition, two
constituents (barium and vanadium) were detected in the sample collected from downstream
location SW-2. The detected concentrations of barium, nickel, and vanadium do not exceed the
North Carolina 2B Surface Water Standards. With regard to 1,4-dioxane, North Carolina has not
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established a 2B Surface Water Standards, results of the surface water sampling indicate 1,4-
dioxane was detected in upstream sample SW-1 (6.0 µg/L) at a concentration above the North
Carolina In -Stream Target Value for Surface Water (ISTV; 0.35 µg/L). 1,4-Dioxane was not
detected above the laboratory MDL in downstream location SW-2. Review of historical data
indicates the current concentrations at SW-1 are comparable to prior detections at this location.
No other constituents were reported above the applicable surface water standards during the
February 2022 sampling event.
3.4 Quality Assurance/Quality Control Results
Quality assurance procedures and protocols for sampling activities were conducted in general
accordance with the DEQ-approved CAP. Quality assurance samples included the collection of a
trip blank and field blank sample. Samples were received by the lab in good condition and met
holding times and preservation requirements. Based upon a review of the data packages, no
significant quality assurance/quality control (QA/QC) issues were identified for the laboratory
analyses. In summary, the QA/QC results indicate that the data collected during the semiannual
monitoring event is suitable for its intended purpose.
Trip Blanks
Laboratory -filled trip blanks accompanied the sampling team during sampling and the transport of
VOC samples to the laboratory. The trip blank samples serve as a QC check on potential external
contamination and/or cross -contamination between VOC water samples during shipping and
storage. The trip blank sample was analyzed for Appendix I VOCs and 1,4-dioxane. The results
indicate no constituents were detected above laboratory MDLs.
Fialrl Rlanke
A field blank sample was collected in the field by exposing laboratory -supplied deionized water
to the sampling environment. The field blank is used to evaluate the potential for contamination
of a sample by site contaminants from a source not associated with the samples collected. The
field blank sample was analyzed for Appendix I and II constituents and 1,4-dioxane. The field
blank sample was non -detect with the exception of a low concentration of methylene chloride.
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However, site samples collected during the sampling event did not indicate detectable
concentrations of methylene chloride. Methylene chloride is a common laboratory contaminant
and the low detection in the field blank sample may be a result of laboratory cleaning processes.
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4.0 Corrective Action Evaluation
4.1 Monitored Natural Attenuation Parameters
Groundwater samples collected during the February 2022 sampling event from monitoring wells
MW-1R, MW-2R, MW-3R, and NES-1 were analyzed for MNA parameters. The groundwater
MNA parameter results for the current sampling event are summarized in Table 7. Historical
groundwater MNA parameter results are provided as Appendix F. A summary of the MNA
parameters collected from the above locations is provided below:
• MNA Field Parameters: temperature, pH, conductivity, ORP, turbidity, and DO.
• MNA Laboratory Parameters: alkalinity, biological oxygen demand (BOD), chemical
oxygen demand (COD), dissolved hydrogen, methane, nitrogen/nitrate, sulfate, sulfide,
total organic carbon (TOC), and volatile fatty acids.
Based on the January 13, 2021 response from DEQ to the CAER dated December 21, 2020, the
additional parameters including dissolved carbon dioxide, dissolved hydrogen, sulfide, volatile
fatty acids, dissolved methane, ethene, and ethane will be analyzed for two events every five years,
corresponding to the two events immediately preceding each CAER. The next CAER is due after
the second half semiannual sampling event of 2025. Although not required, samples for MNA
analysis were collected during the current semiannual sampling event, and the results will
supplement the above mentioned future MNA sampling conducted in advance of the next CAER.
4.2 Phytoremediation
The CAP requires annual phytoremediation tree surveys and the next survey will be scheduled
for summer 2022. The results of the next phytoremediation tree survey for the Butner Landfill
will be presented in the second half 2022 Water Quality Monitoring Report.
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4.3 Evaluation of Plume Stability and Trends
As required by the CAP, this Water Quality Monitoring Report includes an evaluation of plume
stability and contaminant concentration trends based on analytical results obtained from
performance wells MW-2R and MW-3R. In addition, constituent exceedances at other compliance
monitoring wells (i.e., MW-4 and MW-5) are discussed in this section. The February 2022 results
indicate organic compounds benzene and 1,4-dioxane, and inorganic compounds arsenic and
cobalt, are the only constituents detected in site groundwater at concentrations above 2L Standards.
Charts that depict constituent concentrations versus time for site COCs (benzene, 1,4-dioxane, and
cobalt) are provided in Appendix G. A discussion of the concentration trends in site groundwater
is provided below.
Benzene
Chart 1 presents a plot of benzene concentrations for monitoring wells with previous detections
(MW-2R, MW-3R, and MW-4). Historical results indicate there were no benzene detections in
site groundwater prior to December 2006; however, from December 2006 to present,
concentrations of benzene in MW-2R were detected above its 2L Standard (1.0 µg/L) with
concentrations ranging between 1.2 µg/L and 2.1 µg/L. During prior monitoring events, benzene
was also detected in MW-3R (up to 0.73J µg/L) and MW-4 (up to 0.44J µg/L) at estimated J-flag
concentrations below its 2L Standard. The benzene concentrations from the February 2022
sampling event are consistent within historical detections at the site.
Site monitoring results indicate benzene detections and exceedances are localized and limited to
three compliance monitoring wells. Since there have been no detections of benzene in samples
collected from surface water or sentinel well NES-1, there is no indication that the plume is
migrating toward the property boundary. This COC will continue to be monitored during future
semiannual sampling events.
1,4-Dioxane
As required by the DEQ Solid Waste Section, beginning in 2018 groundwater and surface water
samples collected at the site have been analyzed for 1,4-dioxane. Chart 2 presents a plot of 1,4-
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dioxane concentrations for monitoring wells with previous detections (MW-2R, MW-3R, MW-4,
and MW-5). The results of the February 2022 sampling event indicate 1,4-dioxane was detected
above its 2L Standard in compliance monitoring wells MW-2R, MW-3R, MW-4, and MW-5. As
shown on the chart, the 1,4-dioxane concentrations are generally stable and current concentrations
are consistent with historical detections at the site. This COC will continue to be monitored during
future semiannual sampling events.
Surface water results indicate 1,4-dioxane was detected in the upstream sample collected from
SW-1 at a concentration of 6.0 µg/L and above its ISTV. The results indicate 1,4-dioxane was not
detected above the MDL in the downstream sample collected from SW-2. 1,4-Dioxane
concentrations in surface water have historically fluctuated between non -detect and 22.3 µg/L.
Based on the available data collected since 2018, 1,4-dioxane concentrations in groundwater
appear to be stable, while detections in surface water have fluctuated to varying degrees. This
COC will continue to be monitored during future semiannual sampling events.
A roan i r
The February 2022 sample results indicate arsenic was detected slightly above its 2L Standard in
compliance monitoring wells MW-2R and MW-3R. Review of historical data indicates current
concentrations at these locations are comparable to prior detections and it was previously
determined that arsenic detections in site groundwater were not considered to be statistically
significant increases compared to background values.
Cnhalt
Chart 3 presents a plot of the cobalt concentrations versus time for select monitoring wells where
it has consistently been detected in exceedance of its 2L Standard of 1 µg/L (MW-2R and MW-
5). Cobalt in MW-2R has ranged between non -detect and 38.0 µg/L, but has been consistently
between 7.4 and 16.2 µg/L since August 2014. Cobalt in MW-5 has fluctuated between non -detect
and 251 µg/L. This COC will continue to be monitored during future semiannual sampling events.
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5.0 Conclusions
Semiannual water quality monitoring activities were conducted at the site in February 2022. The
groundwater results indicate the landfill monitoring well network remains adequate to monitor the
site. Review of plume stability and concentration trends indicate that the selected remedies of
natural attenuation and phytoremediation are adequately controlling the plume. Based on the
February 2022 results, site COCs remain consistent with the prior sampling event, and the facility
will continue work in the Assessment Monitoring and Corrective Action programs. A summary
of the results is provided below.
• Consistent with historical trends, the overall direction of groundwater flow at the site is
south to southeast towards the unnamed tributary to Picture Creek.
• Benzene (MW-2R and MW-3R) and 1,4-dioxane (MW-2R, MW-3R, MW-4, and MW-5)
were detected in groundwater at concentrations above their 2L Standards. The benzene
and 1,4-dioxane concentrations are consistent with historical concentrations detected at
each location. No other organic constituents were detected above 2L Standards.
• Cobalt (MW-2R, MW-3R, MW-4, MW-5, and MW-6) was detected in groundwater at
concentrations above its 2L Standard. The cobalt concentrations are consistent with
historical concentrations detected at each location. Arsenic (MW-2R and MW-3R) was
detected slightly above its 2L Standard; however, current concentrations are comparable
to prior detections, and it was previously determined that arsenic detections in site
groundwater were not considered to be statistically significant increases compared to
background values. No other inorganic constituents were detected above 2L Standards.
• 1,4-Dioxane was detected in the upstream surface water sample (SW-1) at a concentration
above its ISTV. The 1,4-dioxane concentration is consistent with historical concentrations
at this location. The downstream surface water sample (SW-2) was non -detect for 1,4-
dioxane.
15
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Table 1
Summary of Well Construction Details
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Ground
TOC
Top of
Top of
Bottom of
Total Well
Depth to
Geologic
Well ID
Latitude
Longitude
Elevation
Elevation
Casing
Screen
Screen
Depth
Bedrock
Unit
(ft AMSL)
(ft AMSL)
(ft AGS)
(ft BTOC)
(ft BTOC)
(ft BTOC)
(ft BTOC)
Fractured
MW-1 R
N36° 09' 55.49"
W78° 45' 37.80"
461.01
460.51
0.00
41.00
56.00
56.00
30.00
Bedrock
Weathered
MW-2R
N36° 09' 38.57"
W78° 45' 34.97"
326.60
331.60
2.34
3.85
18.85
18.85
13.00
Bedrock
Fractured
MW-3R
N36° 09' 38.58"
W78° 45' 34.85"
328.77
330.96
2.18
25.83
35.83
35.83
13.00
Bedrock
Fractured
MW-4
N36° 09' 38.93"
W78° 45' 30.15"
338.97
340.80
1.95
16.43
31.43
31.43
13.00
Bedrock
Fractured
MW-5
N36° 09' 39.35"
W78° 45' 23.77"
341.88
343.88
2.12
8.52
23.52
23.52
17.00
Bedrock
Fractured
MW-6
N36° 09' 47.00"
W78° 45' 25.47"
360.80
362.53
2.00
17.63
32.63
32.63
21.20
Bedrock
Fractured
NES-1
N36° 09' 35.65"
W78° 45' 31.59"
326.22
328.40
2.50
15.00
32.80
32.80
26.00
Bedrock
Notes:
Well information obtained from LaBella 2021 Water Quality Monitoring Report
ft = feet; AMSL = above mean sea level
AGS = above ground surface
BTOC = below top of casing
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Table 2
Summary of Groundwater Elevations
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Total Depth
ft BTOC
( )
TOC Elevation
ft AMSL
( )
February 15, 2022
Depth to
Groundwater
(ft BTOC)
Groundwater Elevation
(ft AMSL)
MW-1 R
56.00
460.51
44.52
415.99
MW-2R
18.85
331.60
2.03
329.57
MW-3R
35.83
330.96
1.96
329.00
MW-4
31.43
340.80
6.65
334.15
MW-5
23.52
343.88
13.35
330.53
M W-6
32.63
362.53
12.41
350.12
N ES-1
32.80
328.40
15.85
312.55
Notes:
Well information obtained from LaBella 2021 Water Quality Monitoring Report
ft = feet; AMSL = above mean sea level
BTOC = Feet below top of casing
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Table 3
Summary of Field Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Sample ID
Sample Date
Field Parameter
Result
Unit
Groundwater
MW-1 R
2/16/22
pH
5.64
S. U.
Temperature
14.9
oC
Conductivity
91.6
PS/CM
Turbidity
4.6
NTU
Dissolved Oxygen
2.06
mg/L
ORP
172.3
mV
MW-2R
2/16/22
pH
6.29
S. U.
Temperature
20.6
oC
Conductivity
2,095
PS/cm
Turbidity
0.8
NTU
Dissolved Oxygen
0.14
mg/L
ORP
-48.0
mV
MW-3R
2/16/22
pH
6.77
S. U.
Temperature
10.7
oC
Conductivity
1,543
PS/Cm
Turbidity
0.3
NTU
Dissolved Oxygen
0.99
mg/L
ORP
-8.8
mV
MW-4
2/16/22
pH
6.41
S. U.
Temperature
16.9
oC
Conductivity
1,421
PS/cm
Turbidity
2.13
NTU
Dissolved Oxygen
0.34
m /L
ORP
88.0
mV
MW-5
2/16/22
pH
6.73
S. U.
Temperature
14.2
oC
Conductivity
1,056
PS/CM
Turbidity
7.10
NTU
Dissolved Oxygen
0.32
mg/L
ORP
-1.5
mV
MW-6
2/16/22
pH
6.62
S. U.
Temperature
10.4
oC
Conductivity
604.8
PS/CM
Turbidity
2.13
NTU
Dissolved Oxygen
3.62
mg/L
ORP
194.7
mV
NES-1
2/16/22
pH
4.95
S. U.
Temperature
14.7
oC
Conductivity
81.4
PS/cm
Turbidity
19.8
NTU
Dissolved Oxygen
2.94
mg/L
ORP
282.8
mV
Table 3 (Page 1 of 2)
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Table 3
Summary of Field Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Sample ID
Sample Date
Field Parameter
Result
Unit
Surface Water
SW-1
2/16/22
pH
7.13
S.U.
Temperature
4.8
oC
Conductivity
432
PS/cm
Turbidity
6.9
NTU
Dissolved Oxygen
9.90
mg/L
ORP
182.8
mV
SW-2
2/16/22
pH
7.62
S. U.
Temperature
3.6
oC
Conductivity
179
PS/cm
Turbidity
8.1
NTU
Dissolved Oxygen
10.69
mg/L
ORP
169.2
mV
Notes:
S.U. = standard units; oC = degrees Celsius; pS/cm = microsiemens per centimeter
NTU = nephelometric turbidity unit; mg/L = milligrams per liter; mV = millivolts
ORP = oxidation reduction potential
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Table 4
Summary of Groundwater Flow Velocity
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Hydraulic
Conductivity (ft/day)
Groundwater
Elevation
(ft AMSL)
Reference
Elevation
(ft AMSL)
Delta
Elevation
(ft)
Map Length
(ft)
Hydraulic
Gradient (ft/ft)
Effective
Porosity ��>
Groundwater
Flow Velocity
(ft/day)
Groundwater
Flow Velocity
(ft/year)
MW-1 R
6.18E-02
415.99
410.00
5.99
104.66
0.057
0.18
0.020
7.17
MW-2R
6.18E-02
329.57
340.00
10.43
210.18
0.050
0.18
0.017
6.22
MW-3R
6.18E-02
329.00
340.00
11.00
212.69
0.052
0.18
0.018
6.48
MW-4
6.18E-02
334.15
340.00
5.85
222.47
0.026
0.18
0.009
3.30
MW-5
6.18E-02
330.53
340.00
9.47
359.78
0.026
0.18
0.009
3.30
MW-6
6.18E-02
350.12
360.00
1 9.88
203.63
1 0.049
0.18
0.017
6.08
NES-1
6.18E-02
312.55
330.00
17.45
285.60
0.061
0.18
0.021
7.66
Minimum
--
--
--
--
0.026
--
0.009
3.30
Maximum
--
--
--
--
0.061
--
0.021
7.66
Geometric Mean
--
--
--
--
0.044
--
0.015
5.47
Notes:
1) Hydraulic conductivity and porosity values used from Labella 2021 Water Quality Monitoring Report
ft = feet; ft/day = feet per day; ft/year = feet per year
AMSL = feet above mean sea level; -- = not applicable
Vx = (K/ne) x dh/dl
Vx = groundwater flow velocity
K = hydraulic conductivity
ne = effective porosity
dh/dl = hydraulic gradient
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Table 5
Summary of Constituent Detections (February 2022)
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter
Result
(µg/L)
Qualifier
Analytical Method
MDL
(ug/L)
MRL
(ug/L)
Standard
(Ng/L)
Source (1 8,2)
Groundwater
MW-1 R
2/16/2022
Barium
4.4
J
EPA 601 OD
3.5
5.0
700
NC 2L
Copper
7.9
EPA 601 OD
4.3
5.0
1,000
NC 2L
Nickel
4.8
J
EPA 601 OD
3.5
5.0
100
NC 2L
Zinc
36.0
--
EPA 601 OD
9.5
10
1,000
NC 2L
MW-2R
2/16/2022
1,2-Dichlorobenzene
0.61
J
EPA 8260D
0.34
1.0
20
NC 2L
1,4-Dichlorobenzene
0.80
J
EPA 8260D
0.33
1.0
6
NC 2L
1,4-Dioxane
107
EPA 8260D SIM
1.7
4.0
3
NC 2L
Arsenic
11.5
EPA 601 OD
4.7
10.0
10
NC 2L
Barium
111
EPA 601 OD
3.5
5.0
700
NC 2L
Benzene
1.5
EPA 8260D
0.34
1.0
1
NC 2L
Cadmium
0.46
1
EPA 601 OD
0.40
1.0
2
NC 2L
Chlorobenzene
11.4
EPA 8260D
0.28
1.0
50
NC 2L
Chloroethane
1.6
IK, v2
EPA 8260D
0.65
1.0
3,000
NC 2L
Cobalt
16.2
--
EPA 601 OD
3.6
5.0
1
NC 2L
Ethylbenzene
0.40
J
EPA 8260D
0.3
1.0
600
NC 2L
Lead
6.6
EPA 601 OD
4.5
5.0
15
NC 2L
Naphthalene
1.5
EPA 601 OD
0.64
1.0
6
NC 2L
Nickel
99.3
EPA 601 OD
3.5
5.0
100
NC 2L
Selenium
7.7
J
EPA 601 OD
4.7
10.0
20
NC 2L
Tin
28.2
EPA 601 OD
4.7
5.0
2,000
NC 2L
Toluene
1.1
EPA 8260D
0.48
1.0
600
NC 2L
Vanadium
5.1
EPA 6010D
3.9
5.0
7
NC 2L
X lene Total
2.9
EPA 8260D
0.34
1.0
500
NC 2L
MW-3R
2/16/2022
1,4-Dioxane
50.3
-
EPA 8260D SIM
0.86
2.0
1 3
NC 2L
Arsenic
11.2
--
EPA 601 OD
4.7
10.0
10
NC 2L
Barium
61.2
EPA 601 OD
3.5
5.0
700
NC 2L
Chlorobenzene
4.5
EPA 8260D
0.3
1.0
50
NC 2L
Chloroethane
1.4
IK, v2
EPA 8260D
0.65
1.0
3,000
NC 2L
Cobalt
6.2
--
EPA 601 OD
3.6
5.0
1
NC 2L
Ethylbenzene
0.57
J
EPA 8260D
0.3
1.0
600
NC 2L
Lead
5.4
EPA 601 OD
4.5
5.0
15
NC 2L
Nickel
19.9
EPA 601 OD
3.5
5.0
100
NC 2L
Tin
11.2
EPA 601 OD
4.7
5.0
2,000
NC 2L
Toluene
1.9
EPA 8260D
0.48
1.0
600
NC 2L
X lene Total
3.8
EPA 8260D
0.34
1.0
500
NC 2L
Table 5 (Page 1 of
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Table 5
Summary of Constituent Detections (February 2022)
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter
Result
(Rg/L)
Qualifier
Analytical Method
MDL
(Ng/L)
MRL
(Ng/L)
Standard
(Ng/L)
Source (1112)
Groundwater
MW-4
2/16/2022
1,4-Dioxane
37.4
EPA 8260D SIM
0.86
2.0
3
NC 2L
Arsenic
9.0
J
EPA 601 OD
4.70
10.0
10
NC 2L
Cadmium
0.43
J
EPA 601 OD
0.40
1.0
2
NC 2L
Chlorobenzene
1.3
EPA 8260D
0.28
1.0
50
NC 2L
Chloroethane
1.5
IK, v2
EPA 8260D
0.65
1.0
3,000
NC 2L
Cobalt
7.6
EPA 601 OD
3.6
5.0
1
NC 2L
Lead
6.4
EPA 601 OD
4.5
5.0
15
NC 2L
Nickel
16.2
EPA 601 OD
3.5
5.0
100
NC 2L
Selenium
5.8
J
EPA 601 OD
4.7
10.0
20
NC 2L
MW-5
2/16/2022
1,4-Dioxane
5.5
EPA 8260D SIM
0.86
2.0
3
NC 2L
Arsenic
5.2
J
EPA 601 OD
4.7
10.0
10
NC 2L
Barium
78.3
EPA 601 OD
3.5
5.0
700
NC 2L
Cadmium
0.47
J
EPA 601 OD
0.4
1.0
2
NC 2L
Chlorobenzene
0.49
J
EPA 8260D
0.3
1.0
50
NC 2L
Cobalt
40.2
EPA 601 OD
3.6
5.0
1
NC 2L
Nickel
9.1
EPA 601 OD
3.5
5.0
100
NC 2L
MW-6
2/16/2022
Arsenic
5.9
J
EPA 601 OD
4.7
10.0
10
NC 2L
Cobalt
3.8
J
EPA 601 OD
3.6
5.0
1
NC 2L
NES-1
2/16/2022
1,4-Dioxane
0.92
J, C8
EPA 8260D SIM
0.86
2.0
3
NC 2L
Cobalt
0.26
J
EPA 601 OD
0.05
1.0
1
NC 2L
Surface Water
2/16/2022
1,4-Dioxane
6.0
EPA 8260D SIM
0.86
2.0
0.35
ISTV 13)
SW-1
2/16/2022
Arsenic
6.6
J
EPA 601 OD
4.7
10.0
10
NC 2B
2/16/2022
Barium
41.8
EPA 601 OD
3.5
5.0
1,000
NC 2B
2/16/2022
Nickel
6.5
EPA 601 OD
3.5
5.0
25
NC 213
2/16/2022
Barium
27.9
EPA 601 OD
3.5
5.0
1,000
NC 2B
SW 2
2/16/2022
Vanadium
4.4
J
EPA 601 OD
3.9
5.0
25
SWSL l4>
Notes:
1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022.
2. 15A NCAC 26 Water Quality Standards (26 Standards) for Surface Water (Class WS IV, nutrient sensitive waters [NSW]) dated July 26, 2021.
3. No 213 Standard established, value shown is North Carolina In -Stream Target Value for Surface Water (ISTV).
4. No 2B Standard or ISTV established, value shown is Solid Waste Section Limit (SWSL).
Bold concentrations exceed the NC 2L Standard for groundwater or NC 213 Standard for surface water.
pg/L = micrograms per liter; MDL = method detection limit; MRL = method reporting limit
J = Estimated concentration above the MDL and below the MRL; -- = not applicable
C8 = Result may be biased high due to carryover from previously analyzed sample
IK = The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria, this result should be considered an estimated value
v2 = The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the
sensitivity of the instrument was verified with a reporting limit check standard.
Table 5 (Page 2 of 2)
https://harthlck.sharepointcom/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Butner Tables 1-7 FINAL Hart & Hickman, PC

Table 6
Summary of Constituent Exceedances (February 2022)
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
ample Date
T
Parameter
Result
(µg/L)
qualifier
Method
MDL
(Ng/L)
MRL
(Ng/L)
Standard
(Ng/L)
Source
Groundwater
MW-2R
2/16/2022
1,4-Dioxane
107
--
EPA 8260D SIM
1.7
4.0
3.0
NC 2L
Arsenic
11.5
--
EPA 601 OD
4.7
10.0
10.0
NC 2L
Benzene
1.5
--
EPA 8260D
0.34
1.0
1.0
NC 2L
Cobalt
16.2
--
EPA 601 OD
3.6
5.0
1.0
NC 2L
MW-3R
2/16/2022
1,4-Dioxane
50.3
--
EPA 8260D SIM
0.86
2.0
3.0
NC 2L
Arsenic
11.2
--
EPA 601 OD
4.7
10.0
10.0
NC 2L
Cobalt
6.2
--
EPA 601 OD
3.6
5.0
1.0
NC 2L
MW-4
2/16/2022
1,4-Dioxane
37.4
--
EPA 8260D SIM
0.86
2.0
3.0
NC 2L
Cobalt
7.6
--
EPA 601 OD
3.6
5.0
1.0
NC 2L
MW-5
2/16/2022
1,4-Dioxane
5.5
--
EPA 8260D SIM
0.86
2.0
3.0
NC 2L
Cobalt
40.2
--
EPA 601 OD
3.6
5.0
1.0
NC 2L
MW-6
2/16/2022
Cobalt
3.8
--
EPA 601 OD
3.6
5.0
1.0
NC 2L
Surface Water
SW-1
2/16/2022
1,4-Dioxane
6.0
--
I EPA 8260D SIM
0.86
2.0
0.35
ISTV
Notes:
1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022.
2. 15A NCAC 2B Water Quality Standards (213 Standards) for Surface Water (Class WS IV, nutrient sensitive waters [NSW]) dated July 26, 2021.
3. No 2B Standard established, value shown is North Carolina In -Stream Target Value for Surface Waters (ISTV).
pg/L = micrograms per liter; MDL = method detection limit; MRL = method reporting limit
-- = not applicable
Table 6 (Page 1 of 1)
Hart & Hickman, PC

Table 7
Summary of Monitored Natural Attenuation Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter
Result
(pg/L)
Qualifier
Method
MDL
(pg/L)
MRL
(pg/L)
MW-1 R
2/16/2022
Hydrogen
1.2
J
AM20GAX
0.49
1.9
MW-2R
2/16/2022
1.3
J
AM20GAX
0.49
1.9
MW-3R
2/16/2022
3.2
--
AM20GAX
0.49
1.9
NES-1
2/16/2022
2.4
AM20GAX
0.49
1.9
MW-1R
2/16/2022
Acetic Acid
ND
AM23G
500
500
MW-2R
2/16/2022
ND
AM23G
5,000
5,000
MW-3R
2/16/2022
ND
AM23G
5,000
5,000
NES-1
2/16/2022
130
J
AM23G
500
500
MW-1R
2/16/2022
Butyric Acid
ND
AM23G
58
500
MW-2R
2/16/2022
ND
AM23G
580
5,000
MW-3R
2/16/2022
ND
AM23G
580
5,000
NES-1
2/16/2022
ND
AM23G
58
500
MW-1R
2/16/2022
Formic acid
1,200
AM23G
55
500
MW-2R
2/16/2022
42,000
AM23G
550
5,000
MW-3R
2/16/2022
9,200
AM23G
550
5,000
NES-1
2/16/2022
4,000
AM23G
55
500
MW-1R
2/16/2022
Hexanoic Acid
ND
AM23G
58
500
MW-2R
2/16/2022
580
AM23G
580
5,000
MW-3R
9/16/2022
ND
AM23G
580
5,000
NES-1
2/16/2022
ND
AM23G
58
500
MW-1R
2/16/2022
i-Hexanoic Acid
ND
AM23G
56
500
MW-2R
2/16/2022
ND
AM23G
560
5,000
MW-3R
2/16/2022
ND
AM23G
560
5,000
NES-1
2/16/2022
ND
AM23G
56
500
MW-1R
2/16/2022
i-Pentanoic Acid
ND
AM23G
61
500
MW-2R
2/16/2022
ND
AM23G
610
5,000
MW-3R
2/16/2022
ND
AM23G
610
5,000
NES-1
2/16/2022
ND
AM23G
61
500
MW-1 R
2/16/2022
Lactic Acid
230
J
AM23G
53
500
MW-2R
2/16/2022
ND
AM23G
530
5,000
MW-3R
2/16/2022
ND
AM23G
530
5,000
NES-1
2/16/2022
ND
AM23G
53
500
MW-1R
2/16/2022
Pentanoic Acid
ND
AM23G
56
500
MW-2R
2/16/2022
ND
AM23G
560
5,000
MW-3R
2/16/2022
ND
AM23G
560
5,000
NES-1
2/16/2022
ND
AM23G
56
500
MW-1R
2/16/2022
Propionic Acid
ND
AM23G
53
500
MW-2R
2/16/2022
ND
AM23G
530
5,000
MW-3R
2/16/2022
ND
AM23G
530
5,000
NES-1
2/16/2022
ND
AM23G
53
500
MW-1R
2/16/2022
Pyruvic Acid
ND
AM23G
60
500
MW-2R
2/16/2022
ND
AM23G
600
5,000
MW-3R
2/16/2022
ND
AM23G
600
5,000
NES-1
2/16/2022
ND
AM23G
60
500
Table 7 (Page 1 of
2)
https:/Iharthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWIA/Tables/Butner Tables 1-7 FINAL Hart & Hickman, PC

Table 7
Summary of Monitored Natural Attenuation Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter
Result
(µg/L)
Qualifier
Method
MDL
(Ng/L)
MRL
(Ng/L)
MW-1R
2/16/2022
Chloride
NS
EPA 300.0 rev2.1
600
1,000
MW-2R
2/16/2022
NS
EPA 300.0 rev2.1
600
1,000
MW-3R
2/16/2022
NS
EPA 300.0 rev2.1
600
1,000
NES-1
2/16/2022
NS
EPA 300.0 rev2.1
600
1,000
MW-1R
2/16/2022
Sulfate
ND
EPA 300.0 rev2.1
500
1,000
MW-2R
2/16/2022
ND
EPA 300.0 rev2.1
500
1,000
MW-3R
2/16/2022
543
J
EPA 300.0 rev2.1
500
1,000
NES-1
2/16/2022
6,620
EPA 300.0 rev2.1
500
1,000
MW-1R
2/16/2022
Nitrogen, Nitrate
ND
HACH 10206
150
300
MW-2R
2/16/2022
ND
HACH 10206
150
300
MW-3R
2/16/2022
ND
HACH 10206
150
300
NES-1
2/16/2022
ND
HACH 10206
150
300
MW-1 R
2/16/2022
Ethane
NS
RSK 175 Modified
1.0
10.0
MW-2R
2/16/2022
NS
RSK 175 Modified
1.0
10.0
MW-3R
2/16/2022
NS
RSK 175 Modified
1.0
10.0
NES-1
2/16/2022
NS
RSK 175 Modified
1.0
10.0
MW-1 R
2/16/2022
Ethene
NS
RSK 175 Modified
1.0
10.0
MW-2R
2/16/2022
NS
RSK 175 Modified
1.0
10.0
MW-3R
2/16/2022
NS
RSK 175 Modified
1.0
10.0
NES-1
2/16/2022
NS
RSK 175 Modified
1.0
10.0
MW-1 R
2/16/2022
Methane
ND
RSK 175 Modified
3.4
10.0
MW-2R
2/16/2022
4,610
RSK 175 Modified
3.4
10.0
MW-3R
2/16/2022
397
RSK 175 Modified
3.4
10.0
NES-1
2/16/2022
ND
RSK 175 Modified
3.4
10.0
MW-1R
2/16/2022
Alkalinity
35,000
H-03, PR-18
SM 2320B-2011
650
1,000
MW-2R
2/16/2022
820,000
H-03, PR-18
SM 2320B-2011
650
1,000
MW-3R
2/16/2022
630,000
H-03, PR-18
SM 2320B-2011
650
1,000
NES-1
2/16/2022
5,000
H-03, PR-18
SM 2320B-2011
650
1,000
MW-1R
2/16/2022
Sulfide
ND
SM4500-S2-D
50
100
MW-2R
2/16/2022
ND
SM 4500-S2-D
50
100
MW-3R
2/16/2022
ND
SM 4500-S2-D
50
100
NES-1
2/16/2022
ND
SM 4500-S2-D
50
100
MW-1 R
2/16/2022
Bilogical Oxygen Demand
(5 day)
ND
SM 5210-B
2,000
2,000
MW-2R
2/16/2022
8,000
SM 5210-B
2,000
2,000
MW-3R
2/16/2022
ND
SM 5210-B
2,000
2,000
NES-1
2/16/2022
ND
SM 5210-B
2,000
2,000
MW-1 R
2/16/2022
Chemical Oxygen
Demand
ND
SM 5220D
12,500
25,000
MW-2R
2/16/2022
105,000
SM 5220D
12,500
25,000
MW-3R
2/16/2022
32,100
SM 5220D
12,500
25,000
NES-1
2/16/2022
ND
SM 5220D
12,500
25,000
MW-1R
2/16/2022
Total Organic Carbon
ND
SM 5310-B
500
1,000
MW-2R
2/16/2022
26,500
SM 5310-B
500
1,000
MW-3R
2/16/2022
7,800
SM 5310-B
500
1,000
NES-1
2/16/2022
1,180
SM 5310-B
500
1,000
Notes:
ug/L = micrograms per liter; NS = Not Sampled; ND = Not Detected
MDL = method detection limit; MRL = method reporting limit;
J = Estimated concentration above the MDL and below the MRL
H-03 = Sample received after recommended holding time was exceeded
PR-18 = Headspace present in sample container
Table 7 (Page 2 of
2)
https:/Iharthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWIA/Tables/Butner Tables 1-7 FINAL Hart & Hickman, PC

PROPERTY BOUNDARY
APPROXIMATE
LIMITS OF WASTE
USGS The National Map: National Boundaries Dataset, 3DEP Elevation
Program; Geographic Names Information System, National Hydrography
Dataset, National Land Cover Database, National Structures Dataset, and
National Transportation Dataset; USGS Global Ecosystems; U.S. Census
Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.
Department of State Humanitarian Information Unit; and NOAA National
Centers for Environmental Information, U.S. Coastal Relief Model. Data
refreshed August, 2021.
0 2,000 4,000
Niiii
SCALE IN FEET
U.S.G.S. QUADRANGLE MAP
LAKE MICHIE, NORTH CAROLINA 2019
QUADRANGLE
7.5 MINUTE SERIES (TOPOGRAPHIC)

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— — — — ��------- I — — — —

Appendix A
Groundwater and Surface Water Sampling Records
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

WELL NO.;. -�
GROUNDWATER SAMPLE pF,Amrr
COLLECTION RECORD - - _- -- -
- "' • `• `-
Project No.: j Client; . Garrett and Moore
Project Name: Butner Landfill Permit# 39-02 Project Location: Granville County
Weather Conditions: S.., .., or S Sampling Date: 21 J2022
I. WATER LEVEL DATA (measu'ed m top of inner well casing)
a. Depth to LNAPL; NA (ft) b. Depth to Water.
$'lam
(ft)
C. Depth to DNAPL: i NA (ft) d. Total Well Depth:
54-0a
(ft)
e. LNAPL Thickness: (a-b) NA (ft) f. DNAPL Thickness:
(c-d) NA (ft)
g. Length of Water Column: j 4, (ft) (a-d)
It. Well Volume: (gal)
Conversion Factors
2. WELL PURGE DATA
(a x cf— h)
A. Purge Method: Peristalti ubtn um ailer(3 voIHTe�
Well I.D.. Conv. Fact. (oo
_
b. Field Testing Equipment; j YSI PRO+; Hach 2100
1 0.041
c. Required Total Purge Volulne (1fx 2c) (gals.); t!
2 0.163
d. Total Volume and Number of Well Volumes Removed:
e. Begin Pu a Time; 12.SEnd Pu a Time:
4 0-653
6 1.470
Read
Lapse
Time
Purge
Rate
Temp
(deg. C)
pH ;
(ULu.)
Spec. Cond.
(O.luSlcm)
EhIORP
(I.OmV)
Diss 02
(0.1mglL)
TURB
(LO.NTU)
Color Odor
Water
Level
No.
(min.)
(mllmin)
(fl0%)
(10.1)
(110%)
(41omV)
(±10%.)
(<IONTU)
(R)
;a
ti
7,L
111,7 s o.
1 3's-0
t s.ci
V
On
[
.9
t a 0
14A
'577t
U 7 M .3
2,11 .
.
_ ,�Ab
9YZ?
.1
dAV
�g
qz#
z
[(. -
cte�o
4F
<
s
ram
r
III
. &Y
1?
.3v/
foo
RR
�r0
��.}�
d,47
4L
► d
ift
i
i
i
I
1
I
3. SAMPLE COLLECTION DATA Sampling Personnel:
Sampling Method(s) & Equip: JC
Sample I.D. (Name, Date, Time); hAJ 02 (o ez- 1333
Sample Analytical ParametersllVlethod: APP I CAPP I N CoCs
HACH s/n: 1i Ws" ; YSI s/n: 1 � ef601.4
Fe+2= I.D m CO2=1 0.0 mgA
Sample Start Time: [ End SampleTime: I�,!;S
COMMENTS:
�� i S ,A fc,` a S r,1 -"a

WELL NO.:
GROUNDWATER SAMPLE
PERMIT NO.:
COLLECTION RECORD
Project No.: Client: Garrett and Moore
Project Name: Butner Landfill Permit# 39-02 Project Location: Granville Caun
Weather Conditions: S01VN ! Sampling Date: 21 IL 12022
1. WATER LEVEL DATA (mea aired from, top.of inner well casing)
a. Depth to LNAPL: NA (ft) b. Depth to Water: C2. oz (ft)
C. Depth to DNAPL: NA (ft) d. Total Well Depth: ' (ft)
e. LNAPL Thickness: (a-b) NA (ft) f, DNAPL Thickness:(.c-d) NA (A)
g. Length of Water Column: T % * $ P— (ft) (a-d)
h. Well Volume: (gal) Conversion Factors
2. WELL PURGE DATA 1 (a x ef.= h)
a. Purge Method: eristaltic/ bm pump/Bailer(3 volume) Well I.D. Conv. Fact. (cf)
b. Field Testing Equipment: YSI PRQ.+; Hach 21OOr 0,041 .
C. Required Total Purge Vol�hne (lf x 2c) (gals.): 2 , 0.163
d. Total Volume and Number of Well Volumes Removed: 66A a 0.653
e. Begin Purge Time: A �17 End Pur a Time: J 3 p 1 6 1,470
Lapse Purge Temp plll Spec. Cond. Ub/ORP Diss 02 TURD Water
Rcad Time Rate {dcg C} (0.1st1.) (0.1USfcm) "Amv) (0.1mgIL.) (1.ONTU) I Color I Odor Level
No {min.] {mUmin} I {tIO°/a} (iO.l} (!E10'/o) (±IUmV) (±10%) (<IONTU) [gi)
y "
��
w ■
y
•
YIrIriw
®�OI�MEMM
1 I F E II
. SAMPLE COLLECTION DATA
Sampling Method(s) & Equip: Cdc )
Sample I.D. (Name, Date, Time):; �c
Sample Analytical ParameterslMetihodi:
HACfi sln: 011 ,1-o U ; YSI Soli:
Fe+2= I. y mg/1 CO2= ASV
ample Start Time: 13 fir /
OMMENTS:
Sampling Personnel:
CLJ Air /0
A.PP APP A OCs
End SanmpleTime: 101
r
I. leyr
of

WELL NO.: lqw — 3
GROUNDWATER SAMPLE
COLLECTION RECORD PERMIT NO.:
Project No.: ! Client: Garrett and Moore
Project Name: Butner Landfill Permit!# 39-02 Project Location. Granville Count
eather Conditions: CvjjyVo Sampling Date: 21 IL 12022
1. WATER LEVEL DATA (me sued from top of inner well casing) `
a. Depth to LNAPL: 1 NA (ft) b. Depth to Water:
(ft)
C. Depth to DNAPL: I NA (1't) d. Total Well Depth:
�$'T 9 3;
(ft)
C. LNAPL Thickness: (a-b) NA (ft) f. DNAPL Thickness:
(c-d) NA
(ft)
g. Length of Water Column:, j}'� (ft) - (a-d) .
h. Well Volume::. S� (gal)
Conversion Factors
2. WELL PURGE DATA i
(a x cf = b)
a. Purge Method: Peds i#ic ubm pump/Bailer(3 volume)
Well I.D. Conv. Fact.
(co
__
b. Field Testing Equipment: I YSJPR0+;Havh2l00P
1 0.041
c. Required Total Purge Volume (If x.2c) (gain.):
0-163
d. Total Volume and Number 'of Well Volumes Removed:
L__2
4 0.653
e. Be in Purge Time: Cog End Purge Time: to-6
1.470
Lapse
Purge
Temp
pH 1
Spec. Ca©d.
EWORP
Disc 02
TURB
Water
Read
Time
Rate
(deg. C)
(0.1s.u.)
(O.1aSlcm)
(1.OmV)
(0.1mglL)
(LONTU)
Color
Odor
Level
No.
(min.)
(mllmin)
(t10•Jo)
(i0.1)
(t10%)
(t10mV)
(.M%)
(a10NTU)
(ft)
yrc
man
U
M
®m®N
LI ft�Fa
. SAMPLE COLLECTION DATA
Sampling Method(s) & Equip:40(
Sample LD. (Name, Date, 'Time). 3
Sample Analytical Parametersf dhc
t1ACF1 A: ; Ysl s/n:
Fe+2= 0,,. 6 mg/1 Cat 1 m
ample Start Time: t&o0
nM1L4Wf r'rc.
!S-Yo
,y I
G,11,
61gib
0.
-3 --7
0,
APP
e • 7
A
el:
End SampleTime: i.;Zt2-0�

vV
� WELL NO.: L
GROUNDWATER SAMPLE
COLLECTION RECORD PERMTT No.:
Project No.: I Client: Garrett and Moore
Project Name: Butner Landfill Permt# 39-02 Project Location: Granville County
Weather Conditions: S u AAIJ rp o" Sampling Date: 211 12022
1. WATER LEVEL DATA (measuired from t p of inner well easing)
a. Depth to LNAPL: NA (ft) b. Depth to Water:
C. Depth to DNAPL: NA (ft) d. Total Well Depth: l ,
(ft}
C. LNAPL Thickness: (a-b) NA (fit) f. DNAPL Thickness: (c-d) NA
(ft)
g. Length of Water Column: ,12 (ft) (a-d)
h. Well Volume: Q (gal) Conversion Factors
2. WELL PURGE DATA (a x cf m h)
a. Purge Method: Pellit ielSubin um IBailer(3 volume) well I.D. Conv. Fact. (cf)
b. Field Testing Equipment. { YSl PRO+; Hach 2100 1 0.041
G Required Total Purge Volume (if x 2c) (gals.): 0 0.163
d. Total Volume and Number of Well Volumes Removed: N1w 4 0.653
e. in Pure Time: tt q SI End Pu a Time: 6 1.470
Lapse Purge TemppI Spec. Cond. EhfORP hiss 01 TUR.B
Read Time Rate (deg.Cl (a.ls.u.) (u.INSrcm) (1.0mv) (0-1m1IL) . JLONTU) Color Odor
Water
Level
No. (min.) w1min] (f10%) {to.1J {t14°/n} (tlomv) (fl %) (a10NTU)
00
7
® oS
I
I Et3l
i
j
3. SAMPLE COLLECTION DATA Sampling Personnel:
r
Sampling Method(s) & Equip: JO(/jLa
Sample I.D. (Name, Date, Time)! --N[ 1 P 2;;- d
Sample Analytical Parameters/Method: 60>pp 1i MNA CM
HACH sln: YSI sM: (y H(06 f �
Fe+2= mrZ1 CO2= mg/1
Sample Start Time: (,yf � End .SampleTime:
COMMENTS:

WELL NO.: M w` s—
GROUNDWATER SAMPLE
PERMIT NO.:
COLLECTION RECORD
Project No.: Client; Garrett and Moore
Project Name: Butner Landfill Permit 39-02 Project Location: Granville Count
Bather Conditions: ,5VA.A` sb4lI Sampling Date: 21 12022
1. WATER LEVEL DATA (measured from top a inner well casing)
A. Depth to LNAPL: NA (ft) b. Depth to Water: 11B. (11t}
c. Depth to DNAPL; NA (ft) d. Total Well Depth: d :. $ (ft)
C. LNAPL Thickness; (a-6) NA (ft) E DNAPL Thiclmess: (c-d) NA (ft)
g. Length of Water Column: a l j (ft) (a-d)
h. Well Volume: (gal) Conversion Factors
2. WELL PURGE DATA (a x cf = h)
a. Purge Method: _ ris tic/Subm pump113aile 3 volume)- well I.D. Conv. FaLt (cf)
b, Field Testing Equipmeii : I YSI PRO+; Hach 2100 1 0.041
G Required Total Purge Vol 'me (If x 2e) (gals.): [ 0.163
d. Total Volume and Numbed of Well Volumes Removed: a 0.653
e. Begin Pu a Time: lfjqEnd Pu a Time; if f to 1 6 1.470
Lapse Purge Temp pHi Spec. Cond. Eh/ORP ❑iss 02 T.URS Water
Read Time Rate (deg,C) (0.1a1r.) (0.luSlcm) (1.OmV) (0.1mglL) (L.ONTU) Color Odor Level
No. {min.} (miiminJ (t10°/s) (204) { lfl'la] (11)mV) (t10%) (CXONTU) 00
00 1 [?,-1 1 w7�6�I R(o1 .I �� I Ile1 b3 I OT I Wul QO I k
3. SAMPLE COLLECTION DATA
Sampling Method(s) & Equip;
Sample I.D. (Name, Date, Time).
Sample Analytical Parameters/Method:
HACH sin: ; YS1' sin:
Fe+2= i i A.--mo/i C42 ' A -
Sample Start Time:
COMMENTS:
Sampling Personnel;
)f(PLA/
210 a-
a P APP 1I MNA COCs
End SampleTime: I.13. 0

WELL.NO.: NW-61
GROUNDWATER SAMPLE
COLLECTION RECORD PERMIT NO.:
Project No.: ! Client: Garrett and Moore
Project Name: Butner Landfill Permit# 39-02 Project Location: Granville County__
Weather Conditions; I _ SCAAALfQ' Sampling Date. 21
l2022
L WATER LEVEL DATA (measu d from top . f inner well casing)
a. Depth to LNAPL: NA (ft) b. Depth to Water:
(ft)
C. Depth to DNAPL: f NA (ft) d. Total Well Depth:
$
(ft)
e. LNAPL Thickness: (n-l) NA (ft) f. DNAPL Thickness: (e-d)
NA (ft)
Z. Length of Water Column: (ft) (a-d)
h. Well Volume: `. (gal) Conversion Factors
2. WELL PURGE DATA
(a x cf = h)
a, Purge Method; P 's� i tic/Subm pump/Bailer(3 volume) Wcil I.D.
Conv. Fact. (c*
b. Field Testing Equipment: i YSI PIED+; Hach 2100 1
0.041
C. Required Total Purge Volume (1f x 2c) (gals.):
0.163
d. Total Volume and Number of Well Volumes Removed: d
0.653
e. Beg'n Purge Time: 09 LOH End Pu a Time: 0 14 6
1.4Z0
Lapse
Purge
Temp pH{ Spec. Cend.
EhIORP
Diss 2
TURB
Water
Read
Time
Rate
(deg. Q (0.1s u.) (O.laSlem)
(Lamv)
(O.1mg)L}
(LONTU)
Color
Odor
Level
No.
(min.)
(MI/Min]
(t10%) WA) [tliti°/.j
(t10mV)
[tlo'�a}
[aIONTU}
00
o I p&(p 13.q l 15•�
G�1�
MMMI
, ,
gym,
Mims
li
3. SAMPLE COLLECTION DATA
Sampling Method(s) & Equip:
Sample I.D. (Name, Date, Time):;
Sample Analytical Parameters/Method:
��
HACH "J A ; YSI sln
Fe+2= t4k rngll Cat=, N rr
Sample Start Time: ty1'
COMMENTS: !
Sampling Personnel:
II MNA
End SampleTime: �'�'

I
WELL NO.: AJ E S
GROUNDWATER SAMPLE
COLLECTION RECORD PERM T No.:
Project No.: ! Client: Garrett and Moore
Project Name; Butner Landfill Permit# 39-02 Project Location: Granville County
Weather Conditions: ] 4 Oil k" _ Sampling Date: 21 12022
I. WATER LEVEL DATA (measu.red from tdp of inner well casing)
a. Depth to LNAPL: 'NA (ft) b. Depth to Water: g (ft)
c. Depth to DNAPL: NA (ft) d. Total Well Depth: [ CJ (ft)
e. LNAPL Thickness: (a-b) NA (ft) f. DNAPL Thickness: (c-d) NA (ft)
g. Length of Water Column: b , �- (ft) (a-d)
h.. Well Volume: 3 ,`3 (gal} Conversion Factors
2. WELL PURGE DATA (a x of= h)
a. Purge Method; PeristalticlSubm pumplBailer(3 volume) _ Well IR Conv. Fact. (cf)
b. FYeld Testing Equipment: 1 YSI PRO+; Hach 2100 1 0.041
e. Required Total Purge Vol me (If x 2e) (gals.): �,j 0.163
d. Total Volume and Number of Well Volumes Removed: -� f-- ¢ 0.653
e. Begin Purme Time: End Pu a Time. 6 1A70
Lapse Purge Temp I pHI Spec, Cond. EbIORP in Oz TURB water
Rend Time Rite (deg. C) (0.ts.u,) (0.1uSlem) (1,0mv) (0.1mglL) (1.ONTU) Color Odor Level
No. (min.] (mllmin) (t10%) (N-1) (±10%) (t10mv) (±10%) (<IONTU) (R)
t 1 57 1_200 1 JI(,1 16.1f7_ 1 10 3, 3 I -;� 4 •1 1 Y�oI I ft t i amr I I.9i) I (�<C)O
W�
I
MI
,
1
®
A
SAMPLE COLLECTION DATA �( Sampling Personnel:
Sampling Method(s) & Equip: ' �. T
IRA—
Samplel.D. (Name, Date, Time):' 290 — v s 11 1�
Sample Analytical Parameters/Method: APP 1 APP 11 1 IA 1C
HACH sfre ,Ysls/tr l
Fe+2= 0,0 tngll CO2= 3 p.y mg/I
mple Start Time: t End SampleTime: 15,[o
)MMENTS:
rrn wwww w ■ww
,�© M t.A J j a 1'5 3 0
r_ rt

i
I
I
GROUNDWATER SAMPLE
�, OLLECTIaN RECORD
WELL NO.: Sty s
PERMIT NO.: 3 q -o
Project No.:
Project Name:: Butner Landfill Permit'
Weather Conditions:
1. WATER LEVEL DATA (measuPed
a. Depth to LNAPL:
C. Depth to DNAPL:
e. LNAPL Thickness: (a-b
g. Length of Water Column:
h. Well Volume:
2. WELL PURGE DATA
a. Purge Method: Surface
b. Field Testing Equipment:
C. Required Total Purge Volu'
d. Total Volume and Number
{ Client. Garrett and Moore
39-02 Project Location: Granville Count
do. Sampling Date: 21 t1, 12022
from top of inner well casing)
NA (ft) b. Depth to Water. NA (ft)
NA (#t) d. Total Well Depth: NA (ft)
NA (ft) f. DNAPL Thickness: (c-d) NA (ft)
NA (ft) (a-d)
A (gal) Conversion Factors
(a x of = h)
Water well I.D. Conv. Fact. (cp
YSI PRO+; Hach 2100[2 1 0.041
a (if x 2c) (gals.): NA 2 0.163
4 Well Volumes Removed: NA 4 0.653
SW
Sample
Point
i
i
Temp
(deg.Q
pH
(0.11 .)
Spec. Cond.
(O.luSlcm)
(t10%)
EhlORP
(1.0mV)
(310ntV)
Dins 02
(0.1mgjL)
(110%)
TURB
(LONTU)
(C10NTU)
Color
.
Odor
Sample
Time
sw-
?,
"Zf
n C�
f U-kq
tOS5—
sw-
340?i
-7.t3
Lt3`t,
t 1. CO
I
i
i
i
i
i
i
i
T
3. SAMPLE COLLECTION DATA Sampling Personnel:
Sampling Method(s) & Equip: j Grab
Sample Analytical Parameters/Method: APP 1+ 1,4-Dioxine
HAC[ i sln; ; YSI �n:
Sample Start Time: -End SampleTime:
COMMENTS:

Appendix B
Laboratory Analytical Report
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

aceAnalytical
www.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
June 15, 2022
Stefan Bray, PE
Garrett & Moore
1029 West South Street
Raleigh, NC 27603
RE: Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Dear Stefan Bray, PE:
Enclosed are the analytical results for sample(s) received by the laboratory on February 16, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
A revised laboratory report is being submitted on 6/15/22 to correct an interregional laboratory reporting error.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 122

accAnafyfical
www, pa c elo bs.co m
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification M 460025
REPORT OF LABORATORY ANALYSIS
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laceAnalytical"
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
OXFORD COMPLIANCE/BUTNER COMPL
92588907
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92588907001
3902-TRIP BLANK 02
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907002
3902-SW2
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907003
3902-SW1
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907004
3902-MW6
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907005
3902-MW5
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907006
3902-FB02
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907007
3902-MW4
EPA 601 OD
RDT
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92588907008
3902-MW1R
HACH 10206
LRB
1
PASI-E
SM 521OB-2016
SRS
1
PASI-E
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
RSK 175 Modified
MAD
1
PASI-C
EPA 601 OD
RDT
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
DBB
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
NSCQ
66
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
92588907009
3902-MW2R
HACH 10206
LRB
1
PASI-E
SM 521OB-2016
SRS
1
PASI-E
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
RSK 175 Modified
MAD
1
PASI-C
EPA 601 OD
RDT
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
DBB
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
NSCQ
66
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
92588907010
3902-MW3R
HACH 10206
LRB
1
PASI-E
SM 521OB-2016
SRS
1
PASI-E
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
RSK 175 Modified
MAD
1
PASI-C
EPA 601 OD
RDT
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
DBB
1
PASI-A
EPA 8270E
PKS
112
PASI-C
EPA 8260D
NSCQ
66
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
92588907011
3902-NES1
HACH 10206
LRB
1
PASI-E
SM 521OB-2016
SRS
1
PASI-E
RSK 175 Modified
MAD
1
PASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 122

laceAnalytical"
WWW.pacalahs.000l
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
EPA 6020E
JOR
1
PASI-A
EPA 8260D
NSCQ
4
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
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[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-TRIP BLANK 02
Lab ID: 92588907001 Collected:
02/16/22
00:00
Received: 02/16/22 16:50 Matrix: Water
Parameters
Results
Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 13:32
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 13:32
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 13:32
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 13:32
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 13:32
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 13:32
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 13:32
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 13:32
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 13:32
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 13:32
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
02/18/22 13:32
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 13:32
75-00-3 IK,v2
Chloroform
ND
ug/L
1.0
1
02/18/22 13:32
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 13:32
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 13:32
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 13:32
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 13:32
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 13:32
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 13:32
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 13:32
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 13:32
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 13:32
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 13:32
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 13:32
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 13:32
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 13:32
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 13:32
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 13:32
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 13:32
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 13:32
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 13:32
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 13:32
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
02/18/22 13:32
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 13:32
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 13:32
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 13:32
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 13:32
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 13:32
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 13:32
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 13:32
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 13:32
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 13:32
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 13:32
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 13:32
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 13:32
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 13:32
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-TRIP BLANK 02
Parameters
Lab ID: 92588907001 Collected: 02/16/22 00:00
Results Units Report Limit DF
Received: 02/16/22 16:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Xylene (Total)
ND ug/L
1.0
1
02/18/22 13:32
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99 %
70-130
1
02/18/22 13:32
460-00-4
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
02/18/22 13:32
17060-07-0
Toluene-d8 (S)
102 %
70-130
1
02/18/22 13:32
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L
2.0
1
02/18/22 11:51
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
88 %
70-130
1
02/18/22 11:51
17060-07-0
Toluene-d8 (S)
95 %
66-133
1
02/18/22 11:51
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-SW2
Lab ID: 92588907002 Collected:
02/16/22
10:55
Received: 02/16/22 16:50 Matrix: Water
Parameters
Results
Units Report Limit
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method:
EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 21:54
7440-38-2
Barium
27.9
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 21:54
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 21:54
7440-43-9
Chromium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-48-4
Copper
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-50-8
Lead
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7439-92-1
Nickel
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-02-0
Selenium
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 21:54
7782-49-2
Silver
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-22-4
Vanadium
4AJ
ug/L
5.0
1
03/01/22 10:25
03/13/22 21:54
7440-62-2
Zinc
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 21:54
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020B Preparation Method:
EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.47
1
02/25/22 12:06
02/28/22 06:06
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 14:08
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 14:08
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 14:08
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 14:08
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 14:08
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 14:08
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 14:08
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 14:08
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 14:08
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 14:08
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
02/18/22 14:08
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 14:08
75-00-3 IK,v2
Chloroform
ND
ug/L
1.0
1
02/18/22 14:08
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 14:08
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 14:08
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 14:08
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 14:08
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 14:08
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 14:08
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 14:08
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 14:08
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 14:08
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 14:08
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:08
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-SW2 Lab ID: 92588907002 Collected: 02/16/22 10:55 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:08
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:08
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:08
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:08
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:08
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 14:08
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 14:08
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 14:08
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
02/18/22 14:08
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 14:08
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 14:08
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 14:08
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 14:08
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 14:08
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 14:08
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 14:08
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 14:08
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 14:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 14:08
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 14:08
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 14:08
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 14:08
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
02/18/22 14:08
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
02/18/22 14:08
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
02/18/22 14:08
17060-07-0
Toluene-d8 (S)
103
%
70-130
1
02/18/22 14:08
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
02/18/22 12:31
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
02/18/22 12:31
17060-07-0
Toluene-d8 (S)
103
%
66-133
1
02/18/22 12:31
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-SW1 Lab ID: 92588907003 Collected: 02/16/22 11:10 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-36-0
Arsenic
6.6J
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:15
7440-38-2
Barium
41.8
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:15
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:15
7440-43-9
Chromium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-48-4
Copper
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-50-8
Lead
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7439-92-1
Nickel
6.5
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-02-0
Selenium
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:15
7782-49-2
Silver
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-22-4
Vanadium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:15
7440-62-2
Zinc
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:15
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020B Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.47
1
02/25/22 12:06
02/28/22 06:26
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 14:26
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 14:26
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 14:26
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 14:26
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 14:26
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 14:26
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 14:26
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 14:26
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 14:26
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 14:26
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
02/18/22 14:26
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 14:26
75-00-3
Chloroform
ND
ug/L
1.0
1
02/18/22 14:26
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 14:26
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 14:26
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 14:26
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 14:26
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 14:26
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 14:26
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 14:26
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 14:26
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 14:26
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 14:26
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:26
75-35-4
REPORT OF LABORATORY ANALYSIS
IK,v2
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-SW1 Lab ID: 92588907003 Collected: 02/16/22 11:10 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:26
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:26
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:26
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:26
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:26
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 14:26
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 14:26
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 14:26
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
02/18/22 14:26
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 14:26
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 14:26
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 14:26
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 14:26
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 14:26
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 14:26
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 14:26
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 14:26
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 14:26
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 14:26
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 14:26
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 14:26
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 14:26
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
02/18/22 14:26
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
02/18/22 14:26
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
02/18/22 14:26
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
02/18/22 14:26
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
6.0
ug/L
2.0
1
02/18/22 12:51
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
104
%
70-130
1
02/18/22 12:51
17060-07-0
Toluene-d8(S)
104
%
66-133
1
02/18/22 12:51
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW6 Lab ID: 92588907004 Collected: 02/16/22 10:15 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-36-0
Arsenic
5.9J
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:18
7440-38-2
Barium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:18
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:18
7440-43-9
Chromium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-47-3
Cobalt
3.8J
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-48-4
Copper
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-50-8
Lead
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7439-92-1
Nickel
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-02-0
Selenium
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:18
7782-49-2
Silver
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-22-4
Vanadium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:18
7440-62-2
Zinc
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:18
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020B Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.47
1
02/25/22 12:06
02/28/22 06:30
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 16:33
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 16:33
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 16:33
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 16:33
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 16:33
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 16:33
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 16:33
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 16:33
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 16:33
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 16:33
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
02/18/22 16:33
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 16:33
75-00-3
Chloroform
ND
ug/L
1.0
1
02/18/22 16:33
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 16:33
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 16:33
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 16:33
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 16:33
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 16:33
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 16:33
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 16:33
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 16:33
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 16:33
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 16:33
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 16:33
75-35-4
REPORT OF LABORATORY ANALYSIS
IK,v2
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW6 Lab ID: 92588907004 Collected: 02/16/22 10:15 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 16:33
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 16:33
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 16:33
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 16:33
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 16:33
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 16:33
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 16:33
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 16:33
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
02/18/22 16:33
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 16:33
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 16:33
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 16:33
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 16:33
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 16:33
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 16:33
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 16:33
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 16:33
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 16:33
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 16:33
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 16:33
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 16:33
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 16:33
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
02/18/22 16:33
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
02/18/22 16:33
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
02/18/22 16:33
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
02/18/22 16:33
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
02/18/22 13:10
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
104
%
70-130
1
02/18/22 13:10
17060-07-0
Toluene-d8 (S)
104
%
66-133
1
02/18/22 13:10
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW5 Lab ID: 92588907005 Collected: 02/16/22 11:17 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-36-0
Arsenic
5.2J
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:22
7440-38-2
Barium
78.3
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:22
7440-41-7
Cadmium
0.47J
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:22
7440-43-9
Chromium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-47-3
Cobalt
40.2
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-48-4
Copper
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-50-8
Lead
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7439-92-1
Nickel
9.1
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-02-0
Selenium
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:22
7782-49-2
Silver
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-22-4
Vanadium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:22
7440-62-2
Zinc
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:22
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020B Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.47
1
02/25/22 12:06
02/28/22 06:42
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 14:44
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 14:44
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 14:44
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 14:44
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 14:44
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 14:44
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 14:44
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 14:44
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 14:44
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 14:44
56-23-5
Chlorobenzene
0.49J
ug/L
1.0
1
02/18/22 14:44
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 14:44
75-00-3
Chloroform
ND
ug/L
1.0
1
02/18/22 14:44
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 14:44
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 14:44
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 14:44
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 14:44
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 14:44
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 14:44
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 14:44
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 14:44
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 14:44
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 14:44
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:44
75-35-4
REPORT OF LABORATORY ANALYSIS
IK,v2
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW5 Lab ID: 92588907005 Collected: 02/16/22 11:17 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:44
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 14:44
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:44
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:44
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 14:44
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 14:44
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 14:44
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 14:44
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
02/18/22 14:44
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 14:44
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 14:44
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 14:44
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 14:44
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 14:44
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 14:44
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 14:44
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 14:44
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 14:44
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 14:44
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 14:44
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 14:44
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 14:44
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
02/18/22 14:44
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
02/18/22 14:44
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
02/18/22 14:44
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
02/18/22 14:44
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
5.5
ug/L
2.0
1
02/18/22 13:29
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
109
%
70-130
1
02/18/22 13:29
17060-07-0
Toluene-d8 (S)
106
%
66-133
1
02/18/22 13:29
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-FB02 Lab ID: 92588907006 Collected: 02/16/22 13:40 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:25
7440-38-2
Barium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:25
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:25
7440-43-9
Chromium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-48-4
Copper
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-50-8
Lead
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7439-92-1
Nickel
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-02-0
Selenium
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:25
7782-49-2
Silver
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-22-4
Vanadium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:25
7440-62-2
Zinc
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:25
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020B Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.47
1
02/25/22 12:06
02/28/22 06:46
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 13:50
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 13:50
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 13:50
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 13:50
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 13:50
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 13:50
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 13:50
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 13:50
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 13:50
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 13:50
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
02/18/22 13:50
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 13:50
75-00-3
Chloroform
ND
ug/L
1.0
1
02/18/22 13:50
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 13:50
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 13:50
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 13:50
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 13:50
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 13:50
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 13:50
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 13:50
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 13:50
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 13:50
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 13:50
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 13:50
75-35-4
REPORT OF LABORATORY ANALYSIS
IK,v2
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-FB02 Lab ID: 92588907006 Collected: 02/16/22 13:40 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 13:50
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 13:50
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 13:50
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 13:50
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 13:50
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 13:50
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 13:50
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 13:50
74-88-4
Methylene Chloride
4.1J
ug/L
5.0
1
02/18/22 13:50
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 13:50
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 13:50
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 13:50
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 13:50
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 13:50
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 13:50
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 13:50
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 13:50
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 13:50
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 13:50
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 13:50
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 13:50
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 13:50
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
02/18/22 13:50
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
02/18/22 13:50
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
02/18/22 13:50
17060-07-0
Toluene-d8(S)
102
%
70-130
1
02/18/22 13:50
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
02/18/22 12:10
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
86
%
70-130
1
02/18/22 12:10
17060-07-0
Toluene-d8 (S)
95
%
66-133
1
02/18/22 12:10
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW4 Lab ID: 92588907007 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-36-0
Arsenic
9.01
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:29
7440-38-2
Barium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:29
7440-41-7
Cadmium
0.43J
ug/L
1.0
1
03/01/22 10:25
03/13/22 22:29
7440-43-9
Chromium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-47-3
Cobalt
7.6
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-48-4
Copper
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-50-8
Lead
6.4
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7439-92-1
Nickel
16.2
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-02-0
Selenium
5.8J
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:29
7782-49-2
Silver
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-22-4
Vanadium
ND
ug/L
5.0
1
03/01/22 10:25
03/13/22 22:29
7440-62-2
Zinc
ND
ug/L
10.0
1
03/01/22 10:25
03/13/22 22:29
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020B Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.47
1
02/25/22 12:06
02/28/22 06:50
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 15:02
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 15:02
107-13-1
Benzene
ND
ug/L
1.0
1
02/18/22 15:02
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 15:02
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 15:02
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 15:02
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 15:02
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 15:02
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 15:02
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 15:02
56-23-5
Chlorobenzene
1.3
ug/L
1.0
1
02/18/22 15:02
108-90-7
Chloroethane
1.5
ug/L
1.0
1
02/18/22 15:02
75-00-3
Chloroform
ND
ug/L
1.0
1
02/18/22 15:02
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 15:02
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 15:02
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 15:02
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 15:02
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 15:02
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 15:02
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 15:02
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 15:02
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 15:02
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 15:02
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:02
75-35-4
REPORT OF LABORATORY ANALYSIS
IK,v2
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW4 Lab ID: 92588907007 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:02
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:02
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
02/18/22 15:02
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 15:02
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
02/18/22 15:02
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
02/18/22 15:02
100-41-4
2-Hexanone
ND
ug/L
5.0
1
02/18/22 15:02
591-78-6
lodomethane
ND
ug/L
20.0
1
02/18/22 15:02
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
02/18/22 15:02
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
02/18/22 15:02
108-10-1
Styrene
ND
ug/L
1.0
1
02/18/22 15:02
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 15:02
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
02/18/22 15:02
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
02/18/22 15:02
127-18-4
Toluene
ND
ug/L
1.0
1
02/18/22 15:02
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
02/18/22 15:02
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
02/18/22 15:02
79-00-5
Trichloroethene
ND
ug/L
1.0
1
02/18/22 15:02
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
02/18/22 15:02
75-69-4 v2
1,2,3-Trichloropropane
ND
ug/L
1.0
1
02/18/22 15:02
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
02/18/22 15:02
108-05-4 IH
Vinyl chloride
ND
ug/L
1.0
1
02/18/22 15:02
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
02/18/22 15:02
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
103
%
70-130
1
02/18/22 15:02
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
02/18/22 15:02
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
02/18/22 15:02
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
37.4
ug/L
2.0
1
02/18/22 13:48
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
107
%
70-130
1
02/18/22 13:48
17060-07-0
Toluene-d8 (S)
103
%
66-133
1
02/18/22 13:48
2037-26-5
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 122

laceAnalytical"
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R Lab ID: 92588907008 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Nitrogen, Nitrate
5210B BOD, 5 day EDN
BOD, 5 day
8081 OC Pesticides RVE
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
Date: 06/15/2022 11:21 AM
Analytical Method: HACH 10206
Pace Analytical Services - Eden
ND mg/L 0.30 1 02/17/2214:26 14797-55-8
Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016
Pace Analytical Services - Eden
ND mg/L 2.0 1 02/17/22 22:24 02/22/22 16:57
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
309-00-2
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
319-84-6
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
319-85-7
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
319-86-8
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
58-89-9
ND
ug/L
0.45
1
02/23/2217:48
02/28/2210:17
57-74-9
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
72-54-8
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
72-55-9
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
50-29-3
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
60-57-1
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
959-98-8
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
33213-65-9
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
1031-07-8
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
72-20-8
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
7421-93-4
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
76-44-8
ND
ug/L
0.045
1
02/23/2217:48
02/28/2210:17
1024-57-3
ND
ug/L
0.14
1
02/23/2217:48
02/28/2210:17
72-43-5
ND
ug/L
0.45
1
02/23/2217:48
02/28/2210:17
8001-35-2
79
%
10-184
1
02/23/2217:48
02/28/2210:17
877-09-8
123
%
10-154
1
02/23/2217:48
02/28/2210:17
2051-24-3
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
12674-11-2
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
11104-28-2
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
11141-16-5
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
53469-21-9
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
12672-29-6
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
11097-69-1
ND
ug/L
0.50
1
02/24/22 16:01
02/28/22 21:54
11096-82-5
B2
93 % 10-181 1 02/24/22 16:01 02/28/22 21:54 2051-24-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 20 of 122

laceAnalytical"
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R Lab ID: 92588907008 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND ug/L
10.0
1
02/22/2214:23
74-82-8
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-36-0
Arsenic
ND ug/L
10.0
1
03/01/22 10:25
03/13/22 22:32
7440-38-2
Barium
4AJ ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-39-3
Beryllium
ND ug/L
1.0
1
03/01/22 10:25
03/13/22 22:32
7440-41-7
Cadmium
ND ug/L
1.0
1
03/01/22 10:25
03/13/22 22:32
7440-43-9
Chromium
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-47-3
Cobalt
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-48-4
Copper
7.9 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-50-8
Lead
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7439-92-1
Nickel
4.8J ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-02-0
Selenium
ND ug/L
10.0
1
03/01/22 10:25
03/13/22 22:32
7782-49-2
Silver
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-22-4
Tin
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-31-5
Vanadium
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:32
7440-62-2
Zinc
36.0 ug/L
10.0
1
03/01/22 10:25
03/13/22 22:32
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Thallium
ND ug/L
0.47
1
02/25/22 12:06
02/28/22 06:54
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L
0.20
1
03/02/2211:15
03/03/2214:36
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
83-32-9
Acenaphthylene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
208-96-8
Acetophenone
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
98-86-2
2-Acetylaminofluorene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
53-96-3
4-Aminobiphenyl
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
92-67-1
Anthracene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
120-12-7
Benzo(a)anthracene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
56-55-3
Benzo(a)pyrene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
50-32-8
Benzo(b)fluoranthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
205-99-2
Benzo(g,h,i)perylene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
191-24-2
Benzo(k)fluoranthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
207-08-9
Benzyl alcohol
ND ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
100-51-6
4-Bromophenylphenyl ether
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
101-55-3
Butylbenzylphthalate
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
85-68-7
4-ChIoro-3-methyl phenol
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
59-50-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 21 of 122

laceAnalytical"
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R
Lab ID: 92588907008
Collected: 02/16/22
13:16
Received: 02/16/22 16:50 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical Method:
EPA 8270E
Preparation Method: EPA 3510C
Pace Analytical
Services -
Charlotte
4-Chloroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
106-47-8
Chlorobenzilate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
111-44-4
2-Chloronaphthalene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
91-58-7
2-Chlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
7005-72-3
Chrysene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
218-01-9
Diallate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
53-70-3
Dibenzofuran
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
91-94-1
2,4-Dichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
120-83-2
2,6-Dichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
87-65-0
Diethylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
84-66-2
Dimethoate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 03:39
60-11-7
IL
7,12-Dimethylbenz(a)anthracene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 03:39
119-93-7
IH
2,4-Dimethylphenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
105-67-9
Dimethylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
131-11-3
Di-n-butylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
534-52-1
1,3-Dinitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
99-65-0
2,4-Dinitrophenol
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 03:39
51-28-5
2,4-Dinitrotoluene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
121-14-2
2,6-Dinitrotoluene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
606-20-2
Di-n-octylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
117-84-0
Diphenylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
122-39-4
Disulfoton
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.5
1
02/23/22 09:21
02/26/22 03:39
117-81-7
Ethyl methanesulfonate
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
62-50-0
Famphur
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
52-85-7
IH
Fluoranthene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
206-44-0
Fluorene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
87-68-3
Hexachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
77-47-4
Hexachloroethane
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
67-72-1
Hexachloropropene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
193-39-5
Isodrin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
465-73-6
Isophorone
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
78-59-1
Isosafrole
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
120-58-1
Kepone
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
143-50-0
Methapyrilene
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 03:39
91-80-5
IH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 122

laceAnalytical"
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R Lab ID: 92588907008 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
3-Methylcholanthrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
56-49-5
Methyl methanesulfonate
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 03:39
66-27-3
2-Methylnaphthalene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
91-57-6
Methyl parathion
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
15831-10-4
1-Naphthalenamine
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 03:39
134-32-7
2-Naphthalenamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 03:39
130-15-4
2-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
88-74-4
3-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
99-09-2
4-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
100-01-6
Nitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
98-95-3
2-Nitrophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
88-75-5
4-Nitrophenol
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 03:39
100-02-7
5-Nitro-o-toluidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
99-55-8
N-Nitrosodiethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
55-18-5
N-Nitrosodimethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
10595-95-6
N-Nitrosopiperidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
56-38-2
Pentachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
608-93-5
Pentachloronitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
82-68-8
Pentachlorophenol
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 03:39
87-86-5
Phenacetin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
62-44-2
Phenanthrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
85-01-8
Phenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
108-95-2
p-Phenylenediamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
106-50-3
Phorate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
298-02-2
Pronamide
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
23950-58-5
Pyrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
129-00-0
Safrole
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
58-90-2
Thionazin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
297-97-2
O-Toluidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 03:39
99-35-4
REPORT OF LABORATORY ANALYSIS
IL
Qual
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 122

laceAnalytical"
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R Lab ID: 92588907008 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5(S)
65
%
10-144
1 02/23/22 09:21
02/26/22 03:39
4165-60-0
2-Fluorobiphenyl (S)
61
%
10-130
1 02/23/22 09:21
02/26/22 03:39
321-60-8
Terphenyl-d14 (S)
67
%
34-163
1 02/23/22 09:21
02/26/22 03:39
1718-51-0
Phenol-d6 (S)
35
%
10-130
1 02/23/22 09:21
02/26/22 03:39
13127-88-3
2-Fluorophenol (S)
45
%
10-130
1 02/23/22 09:21
02/26/22 03:39
367-12-4
2,4,6-Tribromophenol (S)
69
%
10-144
1 02/23/22 09:21
02/26/22 03:39
118-79-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 15:21
67-64-1
Acetonitrile
ND
ug/L
50.0
1
02/18/22 15:21
75-05-8
Acrolein
ND
ug/L
10.0
1
02/18/22 15:21
107-02-8 IH,v1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 15:21
107-13-1
AIIyl chloride
ND
ug/L
2.0
1
02/18/22 15:21
107-05-1
Benzene
ND
ug/L
1.0
1
02/18/22 15:21
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 15:21
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 15:21
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 15:21
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 15:21
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 15:21
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 15:21
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 15:21
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
02/18/22 15:21
108-90-7
Chloroethane
ND
ug/L
1.0
1
02/18/22 15:21
75-00-3 IK,v2
Chloroform
ND
ug/L
1.0
1
02/18/22 15:21
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 15:21
74-87-3
Chloroprene
ND
ug/L
5.0
1
02/18/22 15:21
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 15:21
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 15:21
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 15:21
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 15:21
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 15:21
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 15:21
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 15:21
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 15:21
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
1
02/18/22 15:21
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 15:21
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 15:21
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:21
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:21
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:21
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
1
02/18/22 15:21
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
1
02/18/22 15:21
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
1
02/18/22 15:21
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
1
02/18/22 15:21
563-58-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM
without
the written consent of Pace Analytical Services, LLC.
Page 24 of 122

laceAnalytical"
www.pacalahs.Com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R Lab ID: 92588907008 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 06/15/2022 11:21 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
100 %
97 %
102 %
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
1.0
1
02/18/22 15:21
10061-01-5
1.0
1
02/18/22 15:21
10061-02-6
1.0
1
02/18/22 15:21
100-41-4
1.0
1
02/18/22 15:21
97-63-2
5.0
1
02/18/22 15:21
591-78-6
20.0
1
02/18/22 15:21
74-88-4
100
1
02/18/22 15:21
78-83-1
10.0
1
02/18/22 15:21
126-98-7
5.0
1
02/18/22 15:21
75-09-2
2.0
1
02/18/22 15:21
80-62-6
5.0
1
02/18/22 15:21
108-10-1
1.0
1
02/18/22 15:21
91-20-3
20.0
1
02/18/22 15:21
107-12-0
1.0
1
02/18/22 15:21
100-42-5
1.0
1
02/18/22 15:21
630-20-6
1.0
1
02/18/22 15:21
79-34-5
1.0
1
02/18/22 15:21
127-18-4
1.0
1
02/18/22 15:21
108-88-3
1.0
1
02/18/22 15:21
120-82-1
1.0
1
02/18/22 15:21
71-55-6
1.0
1
02/18/22 15:21
79-00-5
1.0
1
02/18/22 15:21
79-01-6
1.0
1
02/18/22 15:21
75-69-4
1.0
1
02/18/22 15:21
96-18-4
2.0
1
02/18/22 15:21
108-05-4
1.0
1
02/18/22 15:21
75-01-4
1.0
1
02/18/22 15:21
1330-20-7
70-130 1
70-130 1
70-130 1
2.0 1
102 % 70-130 1
105 % 66-133 1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
ND ug/L 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
02/18/22 15:21 460-00-4
02/18/22 15:21 17060-07-0
02/18/22 15:21 2037-26-5
02/18/22 14:07 123-91-1
02/18/22 14:0 7 17060-07-0
02/18/2214:07 2037-26-5
02/19/22 04:08 18496-25-8
02/23/22 14:50 14808-79-8
v2
IH
Page 25 of 122

laceAnalytical"
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW1R Lab ID: 92588907008 Collected: 02/16/22 13:16 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand ND ug/L 25000 1 02/24/22 02:07 02/24/22 05:06
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND ug/L 1000 1 02/25/22 07:31 7440-44-0
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R Lab ID: 92588907009 Collected: 02/16/22 13:44 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L
0.30
1
02/17/22 14:26
14797-55-8
5210B BOD, 5 day EDN
Analytical Method: SM 521OB-2016 Preparation Method:
SM 521OB-2016
Pace Analytical Services - Eden
BOD, 5 day
8.0 mg/L
2.0
1
02/17/22 22:24
02/22/22 17:02
8081 OC Pesticides RVE
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Aldrin
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
309-00-2
alpha-BHC
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
319-84-6
beta-BHC
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
319-85-7
delta-BHC
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
319-86-8
gamma-BHC (Lindane)
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
58-89-9
Chlordane (Technical)
ND ug/L
0.45
1
02/23/22 17:48
02/28/22 10:30
57-74-9
4,4'-DDD
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
72-54-8
4,4'-DDE
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
72-55-9
4,4'-DDT
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
50-29-3
Dieldrin
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
60-57-1
Endosulfan I
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
959-98-8
Endosulfan II
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
33213-65-9
Endosulfan sulfate
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
1031-07-8
Endrin
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
72-20-8
Endrin aldehyde
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
7421-93-4
Heptachlor
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
76-44-8
Heptachlor epoxide
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:30
1024-57-3
Methoxychlor
ND ug/L
0.14
1
02/23/22 17:48
02/28/22 10:30
72-43-5
Toxaphene
ND ug/L
0.45
1
02/23/22 17:48
02/28/22 10:30
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
54 %
10-184
1
02/23/22 17:48
02/28/22 10:30
877-09-8
Decachlorobiphenyl (S)
99 %
10-154
1
02/23/22 17:48
02/28/22 10:30
2051-24-3
8082 GCS PCB RVE
Analytical Method: EPA 8082A Preparation Method:
EPA 3510C
Pace Analytical Services - Charlotte
PCB-1016 (Aroclor 1016)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
12674-11-2
PCB-1221 (Aroclor 1221)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
11104-28-2
PCB-1232 (Aroclor 1232)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
11141-16-5
PCB-1242 (Aroclor 1242)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
53469-21-9
PCB-1248 (Aroclor 1248)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
12672-29-6
PCB-1254 (Aroclor 1254)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
11097-69-1
PCB-1260 (Aroclor 1260)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:07
11096-82-5
Surrogates
Decachlorobiphenyl (S)
82 %
10-181
1
02/24/22 16:01
02/28/22 22:07
2051-24-3
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 06/15/2022 11:21 AM
without the written consent of Pace Analytical Services,
LLC.
Page 27 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R Lab ID: 92588907009 Collected: 02/16/22 13:44 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
4610 ug/L
10.0
1
02/18/2219:58
74-82-8
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-36-0
Arsenic
11.5 ug/L
10.0
1
03/01/22 10:25
03/13/22 22:36
7440-38-2
Barium
111 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-39-3
Beryllium
ND ug/L
1.0
1
03/01/22 10:25
03/13/22 22:36
7440-41-7
Cadmium
0.46J ug/L
1.0
1
03/01/22 10:25
03/13/22 22:36
7440-43-9
Chromium
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-47-3
Cobalt
16.2 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-48-4
Copper
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-50-8
Lead
6.6 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7439-92-1
Nickel
99.3 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-02-0
Selenium
7.7J ug/L
10.0
1
03/01/22 10:25
03/13/22 22:36
7782-49-2
Silver
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-22-4
Tin
28.2 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-31-5
Vanadium
5.1 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:36
7440-62-2
Zinc
ND ug/L
10.0
1
03/01/22 10:25
03/13/22 22:36
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Thallium
ND ug/L
0.47
1
02/25/22 12:06
02/28/22 06:58
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L
0.20
1
03/02/2211:15
03/03/2214:39
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
83-32-9
Acenaphthylene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
208-96-8
Acetophenone
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
98-86-2
2-Acetylaminofluorene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
53-96-3
4-Aminobiphenyl
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
92-67-1
Anthracene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
120-12-7
Benzo(a)anthracene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
56-55-3
Benzo(a)pyrene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
50-32-8
Benzo(b)fluoranthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
205-99-2
Benzo(g,h,i)perylene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
191-24-2
Benzo(k)fluoranthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
207-08-9
Benzyl alcohol
ND ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
100-51-6
4-Bromophenylphenyl ether
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
101-55-3
Butylbenzylphthalate
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
85-68-7
4-ChIoro-3-methyl phenol
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
59-50-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 28 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R
Lab ID: 92588907009
Collected: 02/16/22
13:44
Received: 02/16/22 16:50 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical Method:
EPA 8270E
Preparation Method: EPA 3510C
Pace Analytical
Services -
Charlotte
4-Chloroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
106-47-8
Chlorobenzilate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
111-44-4
2-Chloronaphthalene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
91-58-7
2-Chlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
7005-72-3
Chrysene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
218-01-9
Diallate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
53-70-3
Dibenzofuran
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
91-94-1
2,4-Dichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
120-83-2
2,6-Dichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
87-65-0
Diethylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
84-66-2
Dimethoate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:04
60-11-7
IL
7,12-Dimethylbenz(a)anthracene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:04
119-93-7
IH
2,4-Dimethylphenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
105-67-9
Dimethylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
131-11-3
Di-n-butylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
534-52-1
1,3-Dinitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
99-65-0
2,4-Dinitrophenol
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:04
51-28-5
2,4-Dinitrotoluene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
121-14-2
2,6-Dinitrotoluene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
606-20-2
Di-n-octylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
117-84-0
Diphenylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
122-39-4
Disulfoton
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.5
1
02/23/22 09:21
02/26/22 04:04
117-81-7
Ethyl methanesulfonate
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
62-50-0
Famphur
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
52-85-7
IH
Fluoranthene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
206-44-0
Fluorene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
87-68-3
Hexachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
77-47-4
Hexachloroethane
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
67-72-1
Hexachloropropene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
193-39-5
Isodrin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
465-73-6
Isophorone
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
78-59-1
Isosafrole
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
120-58-1
Kepone
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
143-50-0
Methapyrilene
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:04
91-80-5
IH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R Lab ID: 92588907009 Collected: 02/16/22 13:44 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
3-Methylcholanthrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
56-49-5
Methyl methanesulfonate
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:04
66-27-3
2-Methylnaphthalene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
91-57-6
Methyl parathion
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
15831-10-4
1-Naphthalenamine
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:04
134-32-7
2-Naphthalenamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:04
130-15-4
2-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
88-74-4
3-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
99-09-2
4-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
100-01-6
Nitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
98-95-3
2-Nitrophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
88-75-5
4-Nitrophenol
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:04
100-02-7
5-Nitro-o-toluidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
99-55-8
N-Nitrosodiethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
55-18-5
N-Nitrosodimethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
10595-95-6
N-Nitrosopiperidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
56-38-2
Pentachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
608-93-5
Pentachloronitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
82-68-8
Pentachlorophenol
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:04
87-86-5
Phenacetin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
62-44-2
Phenanthrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
85-01-8
Phenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
108-95-2
p-Phenylenediamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
106-50-3
Phorate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
298-02-2
Pronamide
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
23950-58-5
Pyrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
129-00-0
Safrole
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
58-90-2
Thionazin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
297-97-2
O-Toluidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:04
99-35-4
REPORT OF LABORATORY ANALYSIS
IL
Qual
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R Lab ID: 92588907009 Collected: 02/16/22 13:44 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Surrogates
Nitrobenzene-d5(S)
48
%
10-144
1 02/23/22 09:21
02/26/22 04:04
4165-60-0
2-Fluorobiphenyl (S)
49
%
10-130
1 02/23/22 09:21
02/26/22 04:04
321-60-8
Terphenyl-d14 (S)
71
%
34-163
1 02/23/22 09:21
02/26/22 04:04
1718-51-0
Phenol-d6 (S)
23
%
10-130
1 02/23/22 09:21
02/26/22 04:04
13127-88-3
2-Fluorophenol (S)
10
%
10-130
1 02/23/22 09:21
02/26/22 04:04
367-12-4
2,4,6-Tribromophenol (S)
14
%
10-144
1 02/23/22 09:21
02/26/22 04:04
118-79-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
1
02/18/22 15:39
67-64-1
Acetonitrile
ND
ug/L
50.0
1
02/18/22 15:39
75-05-8
Acrolein
ND
ug/L
10.0
1
02/18/22 15:39
107-02-8 IH,v1
Acrylonitrile
ND
ug/L
10.0
1
02/18/22 15:39
107-13-1
AIIyl chloride
ND
ug/L
2.0
1
02/18/22 15:39
107-05-1
Benzene
1.5
ug/L
1.0
1
02/18/22 15:39
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
02/18/22 15:39
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
02/18/22 15:39
75-27-4
Bromoform
ND
ug/L
1.0
1
02/18/22 15:39
75-25-2
Bromomethane
ND
ug/L
2.0
1
02/18/22 15:39
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
02/18/22 15:39
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
02/18/22 15:39
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
02/18/22 15:39
56-23-5
Chlorobenzene
11.4
ug/L
1.0
1
02/18/22 15:39
108-90-7
Chloroethane
1.6
ug/L
1.0
1
02/18/22 15:39
75-00-3 IK,v2
Chloroform
ND
ug/L
1.0
1
02/18/22 15:39
67-66-3
Chloromethane
ND
ug/L
1.0
1
02/18/22 15:39
74-87-3
Chloroprene
ND
ug/L
5.0
1
02/18/22 15:39
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
02/18/22 15:39
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
02/18/22 15:39
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
02/18/22 15:39
106-93-4
Dibromomethane
ND
ug/L
1.0
1
02/18/22 15:39
74-95-3
1,2-Dichlorobenzene
0.61J
ug/L
1.0
1
02/18/22 15:39
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
1
02/18/22 15:39
541-73-1
1,4-Dichlorobenzene
0.80J
ug/L
1.0
1
02/18/22 15:39
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
02/18/22 15:39
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
1
02/18/22 15:39
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
1
02/18/22 15:39
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
02/18/22 15:39
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:39
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:39
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
02/18/22 15:39
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
1
02/18/22 15:39
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
1
02/18/22 15:39
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
1
02/18/22 15:39
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
1
02/18/22 15:39
563-58-6
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM
without
the written consent of Pace Analytical Services, LLC.
Page 31 of 122

laceAnalytical"
www.pacalahs.Com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R Lab ID: 92588907009 Collected: 02/16/22 13:44 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 06/15/2022 11:21 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
0.40J
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
1.5
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
1.1
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
2.9
ug/L
100 %
97 %
102 %
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
107 ug/L
1.0
1
02/18/22 15:39
10061-01-5
1.0
1
02/18/22 15:39
10061-02-6
1.0
1
02/18/22 15:39
100-41-4
1.0
1
02/18/22 15:39
97-63-2
5.0
1
02/18/22 15:39
591-78-6
20.0
1
02/18/22 15:39
74-88-4
100
1
02/18/22 15:39
78-83-1
10.0
1
02/18/22 15:39
126-98-7
5.0
1
02/18/22 15:39
75-09-2
2.0
1
02/18/22 15:39
80-62-6
5.0
1
02/18/22 15:39
108-10-1
1.0
1
02/18/22 15:39
91-20-3
20.0
1
02/18/22 15:39
107-12-0
1.0
1
02/18/22 15:39
100-42-5
1.0
1
02/18/22 15:39
630-20-6
1.0
1
02/18/22 15:39
79-34-5
1.0
1
02/18/22 15:39
127-18-4
1.0
1
02/18/22 15:39
108-88-3
1.0
1
02/18/22 15:39
120-82-1
1.0
1
02/18/22 15:39
71-55-6
1.0
1
02/18/22 15:39
79-00-5
1.0
1
02/18/22 15:39
79-01-6
1.0
1
02/18/22 15:39
75-69-4
1.0
1
02/18/22 15:39
96-18-4
2.0
1
02/18/22 15:39
108-05-4
1.0
1
02/18/22 15:39
75-01-4
1.0
1
02/18/22 15:39
1330-20-7
70-130 1
70-130 1
70-130 1
4.0 2
91 % 70-130 2
97 % 66-133 2
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
ND ug/L 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
02/18/22 15:39 460-00-4
02/18/22 15:39 17060-07-0
02/18/22 15:39 2037-26-5
02/18/22 17:33 123-91-1
02/18/22 17:33 17060-07-0
02/18/22 17:33 2037-26-5
02/19/22 04:09 18496-25-8
02/23/22 15:04 14808-79-8
v2
IH
Page 32 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW2R Lab ID: 92588907009 Collected: 02/16/22 13:44 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand 105000 ug/L 25000 1 02/24/22 02:07 02/24/22 05:06
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 26500 ug/L 1000 1 02/25/22 07:47 7440-44-0
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R Lab ID: 92588907010 Collected: 02/16/22 10:00 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L
0.30
1
02/17/22 14:25
14797-55-8 M1
5210B BOD, 5 day EDN
Analytical Method: SM 521OB-2016 Preparation Method:
SM 521OB-2016
Pace Analytical Services - Eden
BOD, 5 day
ND mg/L
2.0
1
02/17/22 22:24
02/22/22 16:54
R6
8081 OC Pesticides RVE
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Aldrin
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
309-00-2
alpha-BHC
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
319-84-6
beta-BHC
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
319-85-7
delta-BHC
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
319-86-8
gamma-BHC (Lindane)
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
58-89-9
Chlordane (Technical)
ND ug/L
0.45
1
02/23/22 17:48
02/28/22 10:42
57-74-9
4,4'-DDD
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
72-54-8
4,4'-DDE
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
72-55-9
4,4'-DDT
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
50-29-3
Dieldrin
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
60-57-1
Endosulfan I
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
959-98-8
Endosulfan II
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
33213-65-9
Endosulfan sulfate
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
1031-07-8
Endrin
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
72-20-8
Endrin aldehyde
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
7421-93-4
Heptachlor
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
76-44-8
Heptachlor epoxide
ND ug/L
0.045
1
02/23/22 17:48
02/28/22 10:42
1024-57-3
Methoxychlor
ND ug/L
0.14
1
02/23/22 17:48
02/28/22 10:42
72-43-5
Toxaphene
ND ug/L
0.45
1
02/23/22 17:48
02/28/22 10:42
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
82 %
10-184
1
02/23/22 17:48
02/28/22 10:42
877-09-8
Decachlorobiphenyl (S)
99 %
10-154
1
02/23/22 17:48
02/28/22 10:42
2051-24-3
8082 GCS PCB RVE
Analytical Method: EPA 8082A Preparation Method:
EPA 3510C
Pace Analytical Services - Charlotte
PCB-1016 (Aroclor 1016)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
12674-11-2
PCB-1221 (Aroclor 1221)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
11104-28-2
PCB-1232 (Aroclor 1232)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
11141-16-5
PCB-1242 (Aroclor 1242)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
53469-21-9
PCB-1248 (Aroclor 1248)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
12672-29-6
PCB-1254 (Aroclor 1254)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
11097-69-1
PCB-1260 (Aroclor 1260)
ND ug/L
0.50
1
02/24/22 16:01
02/28/22 22:19
11096-82-5
Surrogates
Decachlorobiphenyl (S)
99 %
10-181
1
02/24/22 16:01
02/28/22 22:19
2051-24-3
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 06/15/2022 11:21 AM
without the written consent of Pace Analytical Services,
LLC.
Page 34 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R Lab ID: 92588907010 Collected: 02/16/22 10:00 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
397 ug/L
10.0
1
02/18/22 20:13
74-82-8
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-36-0
Arsenic
11.2 ug/L
10.0
1
03/01/22 10:25
03/13/22 22:40
7440-38-2
Barium
61.2 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-39-3
Beryllium
ND ug/L
1.0
1
03/01/22 10:25
03/13/22 22:40
7440-41-7
Cadmium
ND ug/L
1.0
1
03/01/22 10:25
03/13/22 22:40
7440-43-9
Chromium
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-47-3
Cobalt
6.2 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-48-4
Copper
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-50-8
Lead
5.4 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7439-92-1
Nickel
19.9 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-02-0
Selenium
ND ug/L
10.0
1
03/01/22 10:25
03/13/22 22:40
7782-49-2
Silver
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-22-4
Tin
11.2 ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-31-5
Vanadium
ND ug/L
5.0
1
03/01/22 10:25
03/13/22 22:40
7440-62-2
Zinc
ND ug/L
10.0
1
03/01/22 10:25
03/13/22 22:40
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Thallium
ND ug/L
0.47
1
02/25/22 12:06
02/28/22 07:02
7440-28-0
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L
0.20
1
03/02/2211:15
03/03/2214:41
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
83-32-9
Acenaphthylene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
208-96-8
Acetophenone
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
98-86-2
2-Acetylaminofluorene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
53-96-3
4-Aminobiphenyl
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
92-67-1
Anthracene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
120-12-7
Benzo(a)anthracene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
56-55-3
Benzo(a)pyrene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
50-32-8
Benzo(b)fluoranthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
205-99-2
Benzo(g,h,i)perylene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
191-24-2
Benzo(k)fluoranthene
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
207-08-9
Benzyl alcohol
ND ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
100-51-6
4-Bromophenylphenyl ether
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
101-55-3
Butylbenzylphthalate
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
85-68-7
4-ChIoro-3-methyl phenol
ND ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
59-50-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 35 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R
Lab ID: 92588907010
Collected: 02/16/22
10:00
Received: 02/16/22 16:50 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
8270E APP9 RV
Analytical Method:
EPA 8270E
Preparation Method: EPA 3510C
Pace Analytical
Services -
Charlotte
4-Chloroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
106-47-8
Chlorobenzilate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
111-44-4
2-Chloronaphthalene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
91-58-7
2-Chlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
7005-72-3
Chrysene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
218-01-9
Diallate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
53-70-3
Dibenzofuran
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
91-94-1
2,4-Dichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
120-83-2
2,6-Dichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
87-65-0
Diethylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
84-66-2
Dimethoate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:29
60-11-7
IL
7,12-Dimethylbenz(a)anthracene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:29
119-93-7
IH
2,4-Dimethylphenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
105-67-9
Dimethylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
131-11-3
Di-n-butylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
534-52-1
1,3-Dinitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
99-65-0
2,4-Dinitrophenol
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:29
51-28-5
2,4-Dinitrotoluene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
121-14-2
2,6-Dinitrotoluene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
606-20-2
Di-n-octylphthalate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
117-84-0
Diphenylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
122-39-4
Disulfoton
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.5
1
02/23/22 09:21
02/26/22 04:29
117-81-7
Ethyl methanesulfonate
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
62-50-0
Famphur
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
52-85-7
IH
Fluoranthene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
206-44-0
Fluorene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
87-68-3
Hexachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
77-47-4
Hexachloroethane
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
67-72-1
Hexachloropropene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
193-39-5
Isodrin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
465-73-6
Isophorone
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
78-59-1
Isosafrole
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
120-58-1
Kepone
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
143-50-0
Methapyrilene
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:29
91-80-5
IH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R Lab ID: 92588907010 Collected: 02/16/22 10:00 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical
Services - Charlotte
3-Methylcholanthrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
56-49-5
Methyl methanesulfonate
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:29
66-27-3
2-Methylnaphthalene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
91-57-6
Methyl parathion
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
15831-10-4
1-Naphthalenamine
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:29
134-32-7
2-Naphthalenamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
91-59-8
1,4-Naphthoquinone
ND
ug/L
4.5
1
02/23/22 09:21
02/26/22 04:29
130-15-4
2-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
88-74-4
3-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
99-09-2
4-Nitroaniline
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
100-01-6
Nitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
98-95-3
2-Nitrophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
88-75-5
4-Nitrophenol
ND
ug/L
45.5
1
02/23/22 09:21
02/26/22 04:29
100-02-7
5-Nitro-o-toluidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
99-55-8
N-Nitrosodiethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
55-18-5
N-Nitrosodimethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
62-75-9
N-Nitroso-di-n-butylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
924-16-3
N-Nitroso-di-n-propylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
86-30-6
N-Nitrosomethylethylamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
10595-95-6
N-Nitrosopiperidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
100-75-4
N-Nitrosopyrrolidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
930-55-2
O,O,O-Triethylphosphorothioate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
126-68-1
2,2'-Oxybis(1-chloropropane)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
108-60-1
Parathion (Ethyl parathion)
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
56-38-2
Pentachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
608-93-5
Pentachloronitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
82-68-8
Pentachlorophenol
ND
ug/L
18.2
1
02/23/22 09:21
02/26/22 04:29
87-86-5
Phenacetin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
62-44-2
Phenanthrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
85-01-8
Phenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
108-95-2
p-Phenylenediamine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
106-50-3
Phorate
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
298-02-2
Pronamide
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
23950-58-5
Pyrene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
129-00-0
Safrole
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
94-59-7
1,2,4,5-Tetrachlorobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
95-94-3
2,3,4,6-Tetrachlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
58-90-2
Thionazin
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
297-97-2
O-Toluidine
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
95-53-4
2,4,5-Trichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
88-06-2
1,3,5-Trinitrobenzene
ND
ug/L
9.1
1
02/23/22 09:21
02/26/22 04:29
99-35-4
REPORT OF LABORATORY ANALYSIS
IL
Qual
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R Lab ID: 92588907010 Collected: 02/16/22 10:00 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
Date: 06/15/2022 11:21 AM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
52
%
10-144
1
02/23/22 09:21
02/26/22 04:29
4165-60-0
50
%
10-130
1
02/23/22 09:21
02/26/22 04:29
321-60-8
83
%
34-163
1
02/23/22 09:21
02/26/22 04:29
1718-51-0
13
%
10-130
1
02/23/22 09:21
02/26/22 04:29
13127-88-3
4
%
10-130
1
02/23/22 09:21
02/26/22 04:29
367-12-4
2
%
10-144
1
02/23/22 09:21
02/26/22 04:29
118-79-6
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
25.0
1
02/18/2215:57
67-64-1
ND
ug/L
50.0
1
02/18/2215:57
75-05-8
ND
ug/L
10.0
1
02/18/2215:57
107-02-8
ND
ug/L
10.0
1
02/18/2215:57
107-13-1
ND
ug/L
2.0
1
02/18/2215:57
107-05-1
ND
ug/L
1.0
1
02/18/2215:57
71-43-2
ND
ug/L
1.0
1
02/18/2215:57
74-97-5
ND
ug/L
1.0
1
02/18/2215:57
75-27-4
ND
ug/L
1.0
1
02/18/2215:57
75-25-2
ND
ug/L
2.0
1
02/18/2215:57
74-83-9
ND
ug/L
5.0
1
02/18/2215:57
78-93-3
ND
ug/L
2.0
1
02/18/2215:57
75-15-0
ND
ug/L
1.0
1
02/18/2215:57
56-23-5
4.5
ug/L
1.0
1
02/18/2215:57
108-90-7
1.4
ug/L
1.0
1
02/18/2215:57
75-00-3
ND
ug/L
1.0
1
02/18/2215:57
67-66-3
ND
ug/L
1.0
1
02/18/2215:57
74-87-3
ND
ug/L
5.0
1
02/18/2215:57
126-99-8
ND
ug/L
2.0
1
02/18/2215:57
96-12-8
ND
ug/L
1.0
1
02/18/2215:57
124-48-1
ND
ug/L
1.0
1
02/18/2215:57
106-93-4
ND
ug/L
1.0
1
02/18/2215:57
74-95-3
ND
ug/L
1.0
1
02/18/2215:57
95-50-1
ND
ug/L
1.0
1
02/18/2215:57
541-73-1
ND
ug/L
1.0
1
02/18/2215:57
106-46-7
ND
ug/L
1.0
1
02/18/2215:57
110-57-6
ND
ug/L
1.0
1
02/18/2215:57
75-71-8
ND
ug/L
1.0
1
02/18/2215:57
75-34-3
ND
ug/L
1.0
1
02/18/2215:57
107-06-2
ND
ug/L
1.0
1
02/18/2215:57
75-35-4
ND
ug/L
1.0
1
02/18/2215:57
156-59-2
ND
ug/L
1.0
1
02/18/2215:57
156-60-5
ND
ug/L
1.0
1
02/18/2215:57
78-87-5
ND
ug/L
1.0
1
02/18/2215:57
142-28-9
ND
ug/L
1.0
1
02/18/2215:57
594-20-7
ND
ug/L
1.0
1
02/18/2215:57
563-58-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IH,v1
IK,v2
Page 38 of 122

laceAnalytical"
www.pacalahs.Com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R Lab ID: 92588907010 Collected: 02/16/22 10:00 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 06/15/2022 11:21 AM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
0.57J
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
1.9
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
3.8
ug/L
100 %
97 %
101 %
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
50.3 ug/L
1.0
1
02/18/22 15:57
10061-01-5
1.0
1
02/18/22 15:57
10061-02-6
1.0
1
02/18/22 15:57
100-41-4
1.0
1
02/18/22 15:57
97-63-2
5.0
1
02/18/22 15:57
591-78-6
20.0
1
02/18/22 15:57
74-88-4
100
1
02/18/22 15:57
78-83-1
10.0
1
02/18/22 15:57
126-98-7
5.0
1
02/18/22 15:57
75-09-2
2.0
1
02/18/22 15:57
80-62-6
5.0
1
02/18/22 15:57
108-10-1
1.0
1
02/18/22 15:57
91-20-3
20.0
1
02/18/22 15:57
107-12-0
1.0
1
02/18/22 15:57
100-42-5
1.0
1
02/18/22 15:57
630-20-6
1.0
1
02/18/22 15:57
79-34-5
1.0
1
02/18/22 15:57
127-18-4
1.0
1
02/18/22 15:57
108-88-3
1.0
1
02/18/22 15:57
120-82-1
1.0
1
02/18/22 15:57
71-55-6
1.0
1
02/18/22 15:57
79-00-5
1.0
1
02/18/22 15:57
79-01-6
1.0
1
02/18/22 15:57
75-69-4
1.0
1
02/18/22 15:57
96-18-4
2.0
1
02/18/22 15:57
108-05-4
1.0
1
02/18/22 15:57
75-01-4
1.0
1
02/18/22 15:57
1330-20-7
70-130 1
70-130 1
70-130 1
2.0 1
99 % 70-130 1
104 % 66-133 1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
543J ug/L 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
02/18/22 15:57 460-00-4
02/18/22 15:57 17060-07-0
02/18/22 15:57 2037-26-5
02/18/22 14:46 123-91-1
02/18/22 14:46 17060-07-0
02/18/22 14:46 2037-26-5
02/19/22 04:09 18496-25-8
02/23/22 15:17 14808-79-8
v2
IH
Page 39 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-MW3R Lab ID: 92588907010 Collected: 02/16/22 10:00 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand 32100 ug/L 25000 1 02/24/22 02:07 02/24/22 05:07
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 7800 ug/L 1000 1 02/25/22 08:09 7440-44-0
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 40 of 122

laceAnalytical"
www.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
Sample: 3902-NES1 Lab ID: 92588907011 Collected: 02/16/22 14:55 Received: 02/16/22 16:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L
0.30
1
02/17/22 14:26
14797-55-8
5210B BOD, 5 day EDN
Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016
Pace Analytical Services - Eden
BOD, 5 day
ND mg/L
2.0
1 02/17/22 22:24
02/22/22 17:15
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND ug/L
10.0
1
02/18/22 20:28
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation
Method: EPA 3010A
Pace Analytical Services -Asheville
Cobalt
0.26J ug/L
1.0
1 02/25/22 12:06
02/28/22 07:06
7440-48-4
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Benzene
ND ug/L
1.0
1
02/18/22 16:15
71-43-2
Surrogates
4-Bromofluorobenzene (S)
102 %
70-130
1
02/18/22 16:15
460-00-4
1,2-Dichloroethane-d4 (S)
99 %
70-130
1
02/18/22 16:15
17060-07-0
Toluene-d8 (S)
102 %
70-130
1
02/18/22 16:15
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
0.92J ug/L
2.0
1
02/18/22 15:05
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
106 %
70-130
1
02/18/22 15:05
17060-07-0
Toluene-d8 (S)
107 %
66-133
1
02/18/22 15:05
2037-26-5
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND ug/L
100
1
02/19/22 04:10
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
6620 ug/L
1000
1
02/23/2215:30
14808-79-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND ug/L
25000
1 02/24/22 02:07
02/24/22 05:07
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1180 ug/L
1000
1
02/25/22 08:30
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
B2
I:4i 1
Page 41 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679109 Analysis Method: HACH 10206
QC Batch Method: HACH 10206 Analysis Description: 10206 Nitrogen, Nitrate
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
METHOD BLANK: 3553456
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.30
02/17/22 14:24
LABORATORY CONTROL SAMPLE:
3553457
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
5
5.0
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3554117 3554118
MS MSD
92588907010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L ND 5 5 3.8 3.7 76 75 90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 42 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679198 Analysis Method: SM 521 OB-2016
QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Final EDN
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
METHOD BLANK: 3554156
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
BOD, 5 day
mg/L
ND
2.0
02/22/22 16:41
LABORATORY CONTROL SAMPLE:
3554157
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
BOD, 5 day
mg/L
198
194
98 84.6-115
SAMPLE DUPLICATE: 3554159
92588780001 Dup
Parameter Units Result Result RPD Qualifiers
BOD, 5 day mg/L 89.6 72.0 22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 43 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679501 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907009, 92588907010, 92588907011
METHOD BLANK: 3555557 Matrix: Water
Associated Lab Samples: 92588907009, 92588907010, 92588907011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Methane ug/L ND 10.0 02/18/2218:42
LABORATORY CONTROL SAMPLE: 3555558
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits
Qualifiers
Methane ug/L
396 391
99
70-130
MATRIX SPIKE SAMPLE: 3555639
92588124005 Spike
MS
MS
% Rec
Parameter Units
Result Conc.
Result
% Rec
Limits Qualifiers
Methane ug/L
10300 396
10300
4 70-130 M1
SAMPLE DUPLICATE: 3555638
92588124003 Dup
Parameter Units Result Result RPD Qualifiers
Methane ug/L 1680 1610 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 44 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680064 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907008
METHOD BLANK: 3557982
Associated Lab Samples: 92588907008
Parameter
Units
Methane
ug/L
LABORATORY CONTROL SAMPLE:
3557983
Parameter
Units
Methane
ug/L
MATRIX SPIKE SAMPLE:
3563766
Parameter
Units
Methane
ug/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 02/22/22 14:08
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
396 402 101 70-130
92589109003 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
2550 396 2910 92 70-130
SAMPLE DUPLICATE: 3563765
92588907008 Dup
Parameter Units Result Result
Methane ug/L ND ND
SAMPLE DUPLICATE: 3563767
92589296004 Dup
Parameter Units Result Result
Methane ug/L 142 141
RPD Qualifiers
RPD Qualifiers
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 45 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 681648 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907008, 92588907009, 92588907010
METHOD BLANK: 3565706
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Mercury
ug/L
ND
0.20
03/03/2214:07
LABORATORY CONTROL SAMPLE:
3565707
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Mercury
ug/L
2.5
2.5
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3565708 3565709
MS MSD
92588471014 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 2.5 2.6 98 104 75-125 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 46 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 681459 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007, 92588907008,
92588907009,92588907010
METHOD BLANK: 3565066 Matrix: Water
Associated Lab Samples: 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007, 92588907008,
92588907009,92588907010
Parameter
Blank
Units Result
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Cadmium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Lead
ug/L
Nickel
ug/L
Selenium
ug/L
Silver
ug/L
Tin
ug/L
Vanadium
ug/L
Zinc
ug/L
Reporting
Limit
Analyzed Qualifiers
ND
5.0
03/13/22 21:47
ND
10.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
1.0
03/13/22 21:47
ND
1.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
10.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
5.0
03/13/22 21:47
ND
10.0
03/13/22 21:47
LABORATORY CONTROL SAMPLE:
Parameter
3565067
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
491
98
80-120
Arsenic
ug/L
500
485
97
80-120
Barium
ug/L
500
486
97
80-120
Beryllium
ug/L
500
496
99
80-120
Cadmium
ug/L
500
482
96
80-120
Chromium
ug/L
500
491
98
80-120
Cobalt
ug/L
500
479
96
80-120
Copper
ug/L
500
507
101
80-120
Lead
ug/L
500
491
98
80-120
Nickel
ug/L
500
478
96
80-120
Selenium
ug/L
500
477
95
80-120
Silver
ug/L
250
245
98
80-120
Tin
ug/L
500
489
98
80-120
Vanadium
ug/L
500
479
96
80-120
Zinc
ug/L
500
477
95
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 47 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3565068
MS
92588907002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3565069
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
530
530
106
106
75-125
0
Arsenic
ug/L
ND
500
500
525
522
104
104
75-125
0
Barium
ug/L
27.9
500
500
538
539
102
102
75-125
0
Beryllium
ug/L
ND
500
500
534
534
107
107
75-125
0
Cadmium
ug/L
ND
500
500
512
513
102
103
75-125
0
Chromium
ug/L
ND
500
500
524
524
104
104
75-125
0
Cobalt
ug/L
ND
500
500
502
502
100
100
75-125
0
Copper
ug/L
ND
500
500
536
537
107
107
75-125
0
Lead
ug/L
ND
500
500
513
514
102
103
75-125
0
Nickel
ug/L
ND
500
500
504
506
100
101
75-125
0
Selenium
ug/L
ND
500
500
546
546
109
109
75-125
0
Silver
ug/L
ND
250
250
260
261
104
104
75-125
0
Tin
ug/L
ND
500
500
523
520
105
104
75-125
0
Vanadium
ug/L
4AJ
500
500
513
514
102
102
75-125
0
Zinc
ug/L
ND
500
500
511
512
102
102
75-125
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 48 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680097 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007, 92588907008,
92588907009,92588907010,92588907011
METHOD BLANK: 3558303 Matrix: Water
Associated Lab Samples: 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007, 92588907008,
92588907009,92588907010,92588907011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cobalt ug/L ND 1.0 02/28/22 05:58
Thallium ug/L ND 0.47 02/28/22 05:58
LABORATORY CONTROL SAMPLE: 3558304
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cobalt ug/L 50 51.7 103 80-120
Thallium ug/L 25 25.2 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3558305
3558306
MS
MSD
92588907002 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Cobalt ug/L 0.34J 50
50 51.9
51.9 103
103
75-125 0
Thallium ug/L ND 25
25 25.2
25.3 101
101
75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 49 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679201 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907001, 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007,
92588907008,92588907009,92588907010,92588907011
METHOD BLANK: 3554185 Matrix: Water
Associated Lab Samples: 92588907001, 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007,
92588907008,92588907009,92588907010,92588907011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
02/18/22 08:23
1,1,1-Trichloroethane
ug/L
ND
1.0
02/18/22 08:23
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
02/18/22 08:23
1,1,2-Trichloroethane
ug/L
ND
1.0
02/18/22 08:23
1,1-Dichloroethane
ug/L
ND
1.0
02/18/22 08:23
1,1-Dichloroethene
ug/L
ND
1.0
02/18/22 08:23
1,1-Dichloropropene
ug/L
ND
1.0
02/18/22 08:23
1,2,3-Trichloropropane
ug/L
ND
1.0
02/18/22 08:23
1,2,4-Trichlorobenzene
ug/L
ND
1.0
02/18/22 08:23
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
02/18/22 08:23
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
02/18/22 08:23
1,2-Dichlorobenzene
ug/L
ND
1.0
02/18/22 08:23
1,2-Dichloroethane
ug/L
ND
1.0
02/18/22 08:23
1,2-Dichloropropane
ug/L
ND
1.0
02/18/22 08:23
1,3-Dichlorobenzene
ug/L
ND
1.0
02/18/22 08:23
1,3-Dichloropropane
ug/L
ND
1.0
02/18/22 08:23
1,4-Dichlorobenzene
ug/L
ND
1.0
02/18/22 08:23
2,2-Dichloropropane
ug/L
ND
1.0
02/18/22 08:23
2-Butanone (MEK)
ug/L
ND
5.0
02/18/22 08:23
2-Hexanone
ug/L
ND
5.0
02/18/22 08:23
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
02/18/22 08:23
Acetone
ug/L
ND
25.0
02/18/22 08:23
Acetonitrile
ug/L
ND
50.0
02/18/22 08:23
Acrolein
ug/L
ND
10.0
02/18/22 08:23
Acrylonitrile
ug/L
ND
10.0
02/18/22 08:23
Allyl chloride
ug/L
ND
2.0
02/18/22 08:23
Benzene
ug/L
ND
1.0
02/18/22 08:23
Bromochloromethane
ug/L
ND
1.0
02/18/22 08:23
Bromodichloromethane
ug/L
ND
1.0
02/18/22 08:23
Bromoform
ug/L
ND
1.0
02/18/22 08:23
Bromomethane
ug/L
ND
2.0
02/18/22 08:23
Carbon disulfide
ug/L
ND
2.0
02/18/22 08:23
Carbon tetrachloride
ug/L
ND
1.0
02/18/22 08:23
Chlorobenzene
ug/L
ND
1.0
02/18/22 08:23
Chloroethane
ug/L
ND
1.0
02/18/22 08:23
Chloroform
ug/L
ND
1.0
02/18/22 08:23
Chloromethane
ug/L
ND
1.0
02/18/22 08:23
Chloroprene
ug/L
ND
5.0
02/18/22 08:23
cis-1,2-Dichloroethene
ug/L
ND
1.0
02/18/22 08:23
111ml
IK,v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 50 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
METHOD BLANK: 3554185 Matrix: Water
Associated Lab Samples: 92588907001, 92588907002, 92588907003, 92588907004, 92588907005, 92588907006, 92588907007,
92588907008,92588907009,92588907010,92588907011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
cis-1,3-Dichloropropene
ug/L
ND
1.0
02/18/22 08:23
Dibromochloromethane
ug/L
ND
1.0
02/18/22 08:23
Dibromomethane
ug/L
ND
1.0
02/18/22 08:23
Dichlorodifluoromethane
ug/L
ND
1.0
02/18/22 08:23
Ethyl methacrylate
ug/L
ND
1.0
02/18/22 08:23
Ethylbenzene
ug/L
ND
1.0
02/18/22 08:23
lodomethane
ug/L
ND
20.0
02/18/22 08:23
Isobutanol
ug/L
ND
100
02/18/22 08:23
Methacrylonitrile
ug/L
ND
10.0
02/18/22 08:23
Methyl methacrylate
ug/L
ND
2.0
02/18/22 08:23
Methylene Chloride
ug/L
ND
5.0
02/18/22 08:23
Naphthalene
ug/L
ND
1.0
02/18/22 08:23
Propionitrile
ug/L
ND
20.0
02/18/22 08:23
Styrene
ug/L
ND
1.0
02/18/22 08:23
Tetrachloroethene
ug/L
ND
1.0
02/18/22 08:23
Toluene
ug/L
ND
1.0
02/18/22 08:23
trans-1,2-Dichloroethene
ug/L
ND
1.0
02/18/22 08:23
trans- 1,3-Dichloropropene
ug/L
ND
1.0
02/18/22 08:23
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
02/18/22 08:23
Trichloroethene
ug/L
ND
1.0
02/18/22 08:23
Trichlorofluoromethane
ug/L
ND
1.0
02/18/22 08:23 v2
Vinyl acetate
ug/L
ND
2.0
02/18/22 08:23 IH
Vinyl chloride
ug/L
ND
1.0
02/18/22 08:23
Xylene (Total)
ug/L
ND
1.0
02/18/22 08:23
1,2-Dichloroethane-d4 (S)
%
99
70-130
02/18/22 08:23
4-Bromofluorobenzene (S)
%
101
70-130
02/18/22 08:23
Toluene-d8 (S)
%
99
70-130
02/18/22 08:23
LABORATORY CONTROL SAMPLE:
Parameter
3554186
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
47.8
96
70-130
1,1,1-Trichloroethane
ug/L
50
47.2
94
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.5
97
70-130
1,1,2-Trichloroethane
ug/L
50
48.0
96
70-130
1,1-Dichloroethane
ug/L
50
50.1
100
70-130
1,1-Dichloroethene
ug/L
50
52.8
106
70-132
1,1-Dichloropropene
ug/L
50
49.2
98
70-131
1,2,3-Trichloropropane
ug/L
50
46.9
94
70-130
1,2,4-Trichlorobenzene
ug/L
50
48.7
97
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
47.2
94
70-132
1,2-Dibromoethane (EDB)
ug/L
50
49.0
98
70-130
1,2-Dichlorobenzene
ug/L
50
48.0
96
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 51 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
LABORATORY CONTROL SAMPLE: 3554186
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,2-Dichloroethane
ug/L
50
45.3
91
70-130
1,2-Dichloropropane
ug/L
50
48.8
98
70-130
1,3-Dichlorobenzene
ug/L
50
47.2
94
70-130
1,3-Dichloropropane
ug/L
50
48.8
98
70-130
1,4-Dichlorobenzene
ug/L
50
47.6
95
70-130
2,2-Dichloropropane
ug/L
50
47.4
95
70-130
2-Butanone (MEK)
ug/L
100
95.0
95
70-133
2-Hexanone
ug/L
100
98.8
99
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
96.1
96
70-130
Acetone
ug/L
100
92.0
92
70-144
Acetonitrile
ug/L
500
504
101
68-134
Acrolein
ug/L
250
426
171
32-2001H,v1
Acrylonitrile
ug/L
250
253
101
70-130
Allyl chloride
ug/L
50
49.5
99
70-134
Benzene
ug/L
50
49.8
100
70-130
Bromochloromethane
ug/L
50
47.9
96
70-130
Bromodichloromethane
ug/L
50
45.6
91
70-130
Bromoform
ug/L
50
45.6
91
70-131
Bromomethane
ug/L
50
40.9
82
30-177
Carbon disulfide
ug/L
50
51.2
102
70-133
Carbon tetrachloride
ug/L
50
46.3
93
70-130
Chlorobenzene
ug/L
50
48.0
96
70-130
Chloroethane
ug/L
50
26.2
52
46-131 IK,v2
Chloroform
ug/L
50
47.4
95
70-130
Chloromethane
ug/L
50
46.1
92
49-130
Chloroprene
ug/L
50
49.8
100
70-130
cis-1,2-Dichloroethene
ug/L
50
49.3
99
70-130
cis-1,3-Dichloropropene
ug/L
50
50.1
100
70-130
Dibromochloromethane
ug/L
50
47.9
96
70-130
Dibromomethane
ug/L
50
44.6
89
70-130
Dichlorodifluoromethane
ug/L
50
42.3
85
52-134
Ethyl methacrylate
ug/L
50
50.6
101
70-130
Ethylbenzene
ug/L
50
48.7
97
70-130
Iodomethane
ug/L
100
98.6
99
47-140
Isobutanol
ug/L
1000
1060
106
62-136
Methacrylonitrile
ug/L
500
487
97
70-130
Methyl methacrylate
ug/L
50
48.2
96
70-130
Methylene Chloride
ug/L
50
48.8
98
68-130
Naphthalene
ug/L
50
51.6
103
70-133
Propionitrile
ug/L
500
496
99
70-130
Styrene
ug/L
50
52.1
104
70-130
Tetrachloroethene
ug/L
50
45.6
91
70-130
Toluene
ug/L
50
48.0
96
70-130
trans-1,2-Dichloroethene
ug/L
50
51.6
103
70-130
trans- 1,3-Dichloropropene
ug/L
50
48.7
97
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
46.7
93
25-200
Trichloroethene
ug/L
50
46.8
94
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 52 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
LABORATORY CONTROL SAMPLE:
3554186
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Trichlorofluoromethane
ug/L
50
39.8
80
61-130
v2
Vinyl acetate
ug/L
100
119
119
70-140
IH
Vinyl chloride
ug/L
50
47.2
94
59-142
Xylene (Total)
ug/L
150
151
101
70-130
1,2-Dichloroethane-d4 (S)
%
88
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3554187
3554188
MS
MSD
92588907004
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.0
21.5
105
108
70-135
3
1,1,1-Trichloroethane
ug/L
ND
20
20
20.1
21.0
100
105
70-148
4
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.8
21.4
104
107
70-131
3
1,1,2-Trichloroethane
ug/L
ND
20
20
19.4
21.5
97
108
70-136
10
1,1-Dichloroethane
ug/L
ND
20
20
20.6
22.5
103
113
70-147
9
1,1-Dichloroethene
ug/L
ND
20
20
22.1
23.6
111
118
70-158
6
1,1-Dichloropropene
ug/L
ND
20
20
20.5
22.4
103
112
70-149
9
1,2,3-Trichloropropane
ug/L
ND
20
20
20.4
20.7
102
103
67-137
1
1,2,4-Trichlorobenzene
ug/L
ND
20
20
21.9
22.5
109
112
70-139
3
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.6
22.2
108
111
69-136
2
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
20.6
21.7
103
108
70-137
5
1,2-Dichlorobenzene
ug/L
ND
20
20
21.1
22.1
106
111
70-133
5
1,2-Dichloroethane
ug/L
ND
20
20
18.6
19.8
93
99
67-138
6
1,2-Dichloropropane
ug/L
ND
20
20
20.7
22.1
104
110
70-138
6
1,3-Dichlorobenzene
ug/L
ND
20
20
21.3
22.4
106
112
70-133
5
1,3-Dichloropropane
ug/L
ND
20
20
20.6
21.9
103
109
70-136
6
1,4-Dichlorobenzene
ug/L
ND
20
20
21.0
22.4
105
112
70-133
6
2,2-Dichloropropane
ug/L
ND
20
20
22.0
23.8
110
119
52-155
8
2-Butanone (MEK)
ug/L
ND
40
40
36.9
38.6
92
97
61-147
4
2-Hexanone
ug/L
ND
40
40
43.1
42.3
108
106
67-139
2
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40
38.1
41.1
95
103
67-136
7
Acetone
ug/L
ND
40
40
35.7
38.1
89
95
55-159
7
Acetonitrile
ug/L
ND
200
200
198
210
99
105
66-145
6
Acrolein
ug/L
ND
100
100
182
193
182
193
10-200
61H,v1,v2
Acrylonitrile
ug/L
ND
100
100
102
110
102
110
68-140
7
Allyl chloride
ug/L
ND
20
20
19.6
21.9
98
109
70-147
11
Benzene
ug/L
ND
20
20
21.0
21.9
105
109
67-150
4
Bromochloromethane
ug/L
ND
20
20
19.4
21.1
97
105
70-146
8
Bromodichloromethane
ug/L
ND
20
20
19.3
21.1
97
105
70-138
9
Bromoform
ug/L
ND
20
20
19.4
20.6
97
103
57-138
6
Bromomethane
ug/L
ND
20
20
20.6
22.3
103
112
10-200
8 v2
Carbon disulfide
ug/L
ND
20
20
20.9
22.7
104
113
70-152
8
Carbon tetrachloride
ug/L
ND
20
20
20.5
21.1
102
106
70-147
3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 53 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3554187
3554188
MS
MSD
92588907004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Chlorobenzene
ug/L
ND
20
20
21.2
22.0
106
110
70-137
4
Chloroethane
ug/L
ND
20
20
15.4
17.0
77
85
51-166
101K
Chloroform
ug/L
ND
20
20
19.3
21.5
97
108
70-144
11
Chloromethane
ug/L
ND
20
20
17.1
18.4
86
92
24-161
7
Chloroprene
ug/L
ND
20
20
21.0
22.7
105
114
70-143
8
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.5
22.4
103
112
67-148
9
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.7
22.4
103
112
70-142
8
Dibromochloromethane
ug/L
ND
20
20
20.6
21.5
103
108
68-138
5
Dibromomethane
ug/L
ND
20
20
18.7
20.4
93
102
70-134
9
Dichlorodifluoromethane
ug/L
ND
20
20
12.2
13.1
61
66
43-155
7
Ethyl methacrylate
ug/L
ND
20
20
21.5
22.1
108
110
70-137
2
Ethylbenzene
ug/L
ND
20
20
22.1
22.8
111
114
68-143
3
lodomethane
ug/L
ND
40
40
31.5
36.3
79
91
20-161
14
Isobutanol
ug/L
ND
400
400
392
407
98
102
44-145
4
Methacrylonitrile
ug/L
ND
200
200
197
202
98
101
67-139
3
Methyl methacrylate
ug/L
ND
20
20
19.7
20.5
99
102
70-130
4
Methylene Chloride
ug/L
ND
20
20
19.7
21.5
99
108
64-148
9
Naphthalene
ug/L
ND
20
20
23.1
23.3
116
116
57-150
1
Propionitrile
ug/L
ND
200
200
203
209
101
105
70-138
3
Styrene
ug/L
ND
20
20
22.4
23.4
112
117
70-136
4
Tetrachloroethene
ug/L
ND
20
20
20.5
21.2
102
106
70-139
3
Toluene
ug/L
ND
20
20
20.7
22.2
104
111
47-157
7
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.5
23.0
108
115
70-149
7
trans- 1,3-Dichloropropene
ug/L
ND
20
20
19.9
22.1
100
111
70-138
10
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
15.0
15.5
75
78
31-145
3 v2
Trichloroethene
ug/L
ND
20
20
20.1
20.6
101
103
70-149
2
Trichlorofluoromethane
ug/L
ND
20
20
16.4
18.0
82
90
61-154
9
Vinyl acetate
ug/L
ND
40
40
46.4
50.0
116
125
48-156
7 IH
Vinyl chloride
ug/L
ND
20
20
17.3
18.6
87
93
55-172
7
Xylene (Total)
ug/L
ND
60
60
67.7
69.8
113
116
66-145
3
1,2-Dichloroethane-d4 (S)
%
96
96
70-130
4-Bromofluorobenzene (S)
%
104
102
70-130
Toluene-d8(S)
%
98
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 54 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679312 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907001, 92588907006, 92588907009
METHOD BLANK: 3554438
Matrix:
Water
Associated Lab Samples:
92588907001, 92588907006, 92588907009
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
02/18/22 11:12
1,2-Dichloroethane-d4 (S)
%
88
70-130
02/18/22 11:12
Toluene-d8 (S)
%
95
66-133
02/18/22 11:12
LABORATORY CONTROL SAMPLE: 3554439
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 19.1 95 70-130
1,2-Dichloroethane-d4 (S) % 88 70-130
Toluene-d8 (S) % 94 66-133
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3554440
3554441
MS
MSD
92588929002 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 19.2
18.4 96
92
64-141 4
1,2-Dichloroethane-d4 (S)
%
92
91
70-130
Toluene-d8(S)
%
97
97
66-133
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 55 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679313 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907002, 92588907003, 92588907004, 92588907005, 92588907007, 92588907008, 92588907010,
92588907011
METHOD BLANK: 3554442
Matrix:
Water
Associated Lab Samples:
92588907002, 92588907003, 92588907004, 92588907005, 92588907007,
92588907008, 92588907010,
92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
02/18/22 11:15
1,2-Dichloroethane-d4 (S)
%
99
70-130
02/18/22 11:15
Toluene-d8 (S)
%
101
66-133
02/18/22 11:15
LABORATORY CONTROL SAMPLE: 3554443
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.9 95 70-130
1,2-Dichloroethane-d4 (S) % 98 70-130
Toluene-d8 (S) % 100 66-133
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3554444
3554445
MS
MSD
92588929012 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 9.1 20
20 27.5
27.6 92
93
64-141 0
1,2-Dichloroethane-d4 (S)
%
111
105
70-130
Toluene-d8(S)
%
108
106
66-133
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 56 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680340 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907008, 92588907009, 92588907010
METHOD BLANK: 3559373 Matrix:
Associated Lab Samples: 92588907008, 92588907009, 92588907010
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
4,4'-DDD
ug/L
ND
0.050
02/28/22 09:01
4,4'-DDE
ug/L
ND
0.050
02/28/22 09:01
4,4'-DDT
ug/L
ND
0.050
02/28/22 09:01
Aldrin
ug/L
ND
0.050
02/28/22 09:01
alpha-BHC
ug/L
ND
0.050
02/28/22 09:01
beta-BHC
ug/L
ND
0.050
02/28/22 09:01
Chlordane (Technical)
ug/L
ND
0.50
02/28/22 09:01
delta-BHC
ug/L
ND
0.050
02/28/22 09:01
Dieldrin
ug/L
ND
0.050
02/28/22 09:01
Endosulfan I
ug/L
ND
0.050
02/28/22 09:01
Endosulfan II
ug/L
ND
0.050
02/28/22 09:01
Endosulfan sulfate
ug/L
ND
0.050
02/28/22 09:01
Endrin
ug/L
ND
0.050
02/28/22 09:01
Endrin aldehyde
ug/L
ND
0.050
02/28/22 09:01
gamma-BHC (Lindane)
ug/L
ND
0.050
02/28/22 09:01
Heptachlor
ug/L
ND
0.050
02/28/22 09:01
Heptachlor epoxide
ug/L
ND
0.050
02/28/22 09:01
Methoxychlor
ug/L
ND
0.15
02/28/22 09:01
Toxaphene
ug/L
ND
0.50
02/28/22 09:01
Decachlorobiphenyl (S)
%
82
10-154
02/28/22 09:01
Tetrachloro-m-xylene (S)
%
71
10-184
02/28/22 09:01
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3559374
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
4,4'-DDD
ug/L
0.25
0.22
89
45-158
4,4'-DDE
ug/L
0.25
0.20
79
37-141
4,4'-DDT
ug/L
0.25
0.23
91
52-160
Aldrin
ug/L
0.25
0.19
75
10-130
alpha-BHC
ug/L
0.25
0.21
85
37-139
beta-BHC
ug/L
0.25
0.22
86
39-176
delta-BHC
ug/L
0.25
0.22
87
39-144
Dieldrin
ug/L
0.25
0.19
78
40-149
Endosulfan I
ug/L
0.25
0.21
86
44-145
Endosulfan II
ug/L
0.25
0.24
97
47-153
Endosulfan sulfate
ug/L
0.25
0.24
96
48-159
Endrin
ug/L
0.25
0.23
91
41-155
Endrin aldehyde
ug/L
0.25
0.21
84
45-146
gamma-BHC (Lindane)
ug/L
0.25
0.21
86
42-146
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 57 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
LABORATORY CONTROL SAMPLE:
3559374
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Heptachlor
ug/L
0.25
0.20 82
23-135
Heptachlor epoxide
ug/L
0.25
0.21 85
39-142
Methoxychlor
ug/L
0.75
0.66 88
55-173
Decachlorobiphenyl (S)
%
95
10-154
Tetrachloro-m-xylene (S)
%
82
10-184
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3559375
MS
92587167004 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3559376
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
4,4'-DDD
ug/L
ND
0.25
0.25
0.28
0.11
113
43
36-169
90 R1
4,4'-DDE
ug/L
ND
0.25
0.25
0.23
0.11
90
42
31-154
73 R1
4,4'-DDT
ug/L
ND
0.25
0.25
0.27
0.13
108
51
23-187
72 R1
Aldrin
ug/L
ND
0.25
0.25
0.20
0.11
82
46
10-141
56 R1
alpha-BHC
ug/L
ND
0.25
0.25
0.24
0.14
94
54
25-151
54 R1
beta-BHC
ug/L
ND
0.25
0.25
0.23
0.22
92
87
30-188
6
delta-BHC
ug/L
ND
0.25
0.25
0.24
0.19
95
75
32-157
23
Dieldrin
ug/L
ND
0.25
0.25
0.23
0.089
90
35
24-165
87 R1
Endosulfan I
ug/L
ND
0.25
0.25
0.23
0.11
93
44
19-168
72 R1
Endosulfan II
ug/L
ND
0.25
0.25
0.30
0.13
119
52
27-176
78 R1
Endosulfan sulfate
ug/L
ND
0.25
0.25
0.27
0.18
108
73
31-174
39 R1
Endrin
ug/L
ND
0.25
0.25
0.27
0.12
108
47
23-171
79 R1
Endrin aldehyde
ug/L
ND
0.25
0.25
0.24
0.18
95
73
16-177
26
gamma-BHC (Lindane)
ug/L
ND
0.25
0.25
0.24
0.16
94
64
29-157
38 R1
Heptachlor
ug/L
ND
0.25
0.25
0.21
0.12
85
48
11-149
56 R1
Heptachlor epoxide
ug/L
ND
0.25
0.25
0.23
0.12
91
47
21-157
64 R1
Methoxychlor
ug/L
ND
0.75
0.75
0.75
0.42
100
56
33-193
56 R1
Decachlorobiphenyl (S)
%
102
68
10-154
Tetrachloro-m-xylene (S)
%
78
25
10-184
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 58 of 122

laceAnalytical"
wwmpacalahs.Com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680708 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907008, 92588907009, 92588907010
METHOD BLANK: 3561079
Matrix:
Water
Associated Lab Samples:
92588907008, 92588907009, 92588907010
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
03/01/22 02:45
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
03/01/22 02:45
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
03/01/22 02:45
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
03/01/22 02:45
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
03/01/22 02:45
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
03/01/22 02:45
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
03/01/22 02:45
Decachlorobiphenyl (S)
%
81
10-181
03/01/22 02:45
LABORATORY CONTROL SAMPLE: 3561075
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 5 4.0 80 41-137
PCB-1260 (Aroclor 1260) ug/L 5 3.7 73 42-156
Decachlorobiphenyl (S) % 85 10-181
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3561076
3561077
MS
MSD
92589151004 Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc. Result
Result
% Rec
% Rec
Limits RPD Qual
PCB-1016 (Aroclor 1016)
ug/L
ND 10
10 13.8
10.9
138
109
22-145 23
PCB-1260 (Aroclor 1260)
ug/L
ND 10
10 8.9
6.6
89
66
10-167 30
Decachlorobiphenyl (S)
%
99
75
10-181
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 59 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680247 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92588907008, 92588907009, 92588907010
METHOD BLANK: 3558848 Matrix:
Associated Lab Samples: 92588907008, 92588907009, 92588907010
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
02/25/22 23:25
1,3,5-Trinitrobenzene
ug/L
ND
10.0
02/25/22 23:25
1,3-Dinitrobenzene
ug/L
ND
10.0
02/25/22 23:25
1,4-Naphthoquinone
ug/L
ND
5.0
02/25/22 23:25
1-Naphthalenamine
ug/L
ND
5.0
02/25/22 23:25
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
02/25/22 23:25
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
02/25/22 23:25
2,4,5-Trichlorophenol
ug/L
ND
10.0
02/25/22 23:25
2,4,6-Trichlorophenol
ug/L
ND
10.0
02/25/22 23:25
2,4-Dichlorophenol
ug/L
ND
10.0
02/25/22 23:25
2,4-Dimethylphenol
ug/L
ND
10.0
02/25/22 23:25
2,4-Dinitrophenol
ug/L
ND
50.0
02/25/22 23:25
2,4-Dinitrotoluene
ug/L
ND
10.0
02/25/22 23:25
2,6-Dichlorophenol
ug/L
ND
10.0
02/25/22 23:25
2,6-Dinitrotoluene
ug/L
ND
10.0
02/25/22 23:25
2-Acetylaminofluorene
ug/L
ND
10.0
02/25/22 23:25
2-Chloronaphthalene
ug/L
ND
10.0
02/25/22 23:25
2-Chlorophenol
ug/L
ND
10.0
02/25/22 23:25
2-Methylnaphthalene
ug/L
ND
10.0
02/25/22 23:25
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
02/25/22 23:25
2-Naphthalenamine
ug/L
ND
10.0
02/25/22 23:25
2-Nitroaniline
ug/L
ND
20.0
02/25/22 23:25
2-Nitrophenol
ug/L
ND
10.0
02/25/22 23:25
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
02/25/22 23:25
3,3'-Dichlorobenzidine
ug/L
ND
20.0
02/25/22 23:25
3,3'-Dimethylbenzidine
ug/L
ND
50.0
02/25/22 23:25
3-Methylcholanthrene
ug/L
ND
10.0
02/25/22 23:25
3-Nitroaniline
ug/L
ND
20.0
02/25/22 23:25
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
02/25/22 23:25
4-Aminobiphenyl
ug/L
ND
10.0
02/25/22 23:25
4-Bromophenylphenyl ether
ug/L
ND
10.0
02/25/22 23:25
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
02/25/22 23:25
4-Chloroaniline
ug/L
ND
20.0
02/25/22 23:25
4-Chlorophenylphenyl ether
ug/L
ND
10.0
02/25/22 23:25
4-Nitroaniline
ug/L
ND
20.0
02/25/22 23:25
4-Nitrophenol
ug/L
ND
50.0
02/25/22 23:25
5-Nitro-o-toluidine
ug/L
ND
10.0
02/25/22 23:25
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
02/25/22 23:25
Acenaphthene
ug/L
ND
10.0
02/25/22 23:25
Acenaphthylene
ug/L
ND
10.0
02/25/22 23:25
IH
IL
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 60 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
METHOD BLANK: 3558848 Matrix:
Associated Lab Samples: 92588907008, 92588907009, 92588907010
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Acetophenone
ug/L
ND
10.0
02/25/22 23:25
Anthracene
ug/L
ND
10.0
02/25/22 23:25
Benzo(a)anthracene
ug/L
ND
10.0
02/25/22 23:25
Benzo(a)pyrene
ug/L
ND
10.0
02/25/22 23:25
Benzo(b)fluoranthene
ug/L
ND
10.0
02/25/22 23:25
Benzo(g,h,i)perylene
ug/L
ND
10.0
02/25/22 23:25
Benzo(k)fluoranthene
ug/L
ND
10.0
02/25/22 23:25
Benzyl alcohol
ug/L
ND
20.0
02/25/22 23:25
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
02/25/22 23:25
bis(2-Chloroethyl) ether
ug/L
ND
10.0
02/25/22 23:25
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
02/25/22 23:25
Butylbenzylphthalate
ug/L
ND
10.0
02/25/22 23:25
Chlorobenzilate
ug/L
ND
10.0
02/25/22 23:25
Chrysene
ug/L
ND
10.0
02/25/22 23:25
Di-n-butylphthalate
ug/L
ND
10.0
02/25/22 23:25
Di-n-octylphthalate
ug/L
ND
10.0
02/25/22 23:25
Diallate
ug/L
ND
10.0
02/25/22 23:25
Dibenz(a,h)anthracene
ug/L
ND
10.0
02/25/22 23:25
Dibenzofuran
ug/L
ND
10.0
02/25/22 23:25
Diethylphthalate
ug/L
ND
10.0
02/25/22 23:25
Dimethoate
ug/L
ND
10.0
02/25/22 23:25
Dimethylphthalate
ug/L
ND
10.0
02/25/22 23:25
Diphenylamine
ug/L
ND
10.0
02/25/22 23:25
Disulfoton
ug/L
ND
10.0
02/25/22 23:25
Ethyl methanesulfonate
ug/L
ND
20.0
02/25/22 23:25
Famphur
ug/L
ND
10.0
02/25/22 23:25
Fluoranthene
ug/L
ND
10.0
02/25/22 23:25
Fluorene
ug/L
ND
10.0
02/25/22 23:25
Hexachloro-1,3-butadiene
ug/L
ND
10.0
02/25/22 23:25
Hexachlorobenzene
ug/L
ND
10.0
02/25/22 23:25
Hexachlorocyclopentadiene
ug/L
ND
10.0
02/25/22 23:25
Hexachloroethane
ug/L
ND
10.0
02/25/22 23:25
Hexachloropropene
ug/L
ND
10.0
02/25/22 23:25
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
02/25/22 23:25
Isodrin
ug/L
ND
10.0
02/25/22 23:25
Isophorone
ug/L
ND
10.0
02/25/22 23:25
Isosafrole
ug/L
ND
10.0
02/25/22 23:25
Kepone
ug/L
ND
20.0
02/25/22 23:25
Methapyrilene
ug/L
ND
50.0
02/25/22 23:25
Methyl methanesulfonate
ug/L
ND
5.0
02/25/22 23:25
Methyl parathion
ug/L
ND
10.0
02/25/22 23:25
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
02/25/22 23:25
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
02/25/22 23:25
N-Nitrosodiethylamine
ug/L
ND
10.0
02/25/22 23:25
N-Nitrosodimethylamine
ug/L
ND
10.0
02/25/22 23:25
IH
IH
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 61 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
METHOD BLANK: 3558848 Matrix:
Associated Lab Samples: 92588907008, 92588907009, 92588907010
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
N-Nitrosodiphenylamine
ug/L
ND
10.0
02/25/22 23:25
N-Nitrosomethylethylamine
ug/L
ND
10.0
02/25/22 23:25
N-Nitrosopiperidine
ug/L
ND
10.0
02/25/22 23:25
N-Nitrosopyrrolidine
ug/L
ND
10.0
02/25/22 23:25
Nitrobenzene
ug/L
ND
10.0
02/25/22 23:25
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
02/25/22 23:25
O-Toluidine
ug/L
ND
10.0
02/25/22 23:25
P-Dimethylaminoazobenzene
ug/L
ND
5.0
02/25/22 23:25 IL
p-Phenylenediamine
ug/L
ND
10.0
02/25/22 23:25
Parathion (Ethyl parathion)
ug/L
ND
10.0
02/25/22 23:25
Pentachlorobenzene
ug/L
ND
10.0
02/25/22 23:25
Pentachloronitrobenzene
ug/L
ND
10.0
02/25/22 23:25
Pentachlorophenol
ug/L
ND
20.0
02/25/22 23:25
Phenacetin
ug/L
ND
10.0
02/25/22 23:25
Phenanthrene
ug/L
ND
10.0
02/25/22 23:25
Phenol
ug/L
ND
10.0
02/25/22 23:25
Phorate
ug/L
ND
10.0
02/25/22 23:25
Pronamide
ug/L
ND
10.0
02/25/22 23:25
Pyrene
ug/L
ND
10.0
02/25/22 23:25
Safrole
ug/L
ND
10.0
02/25/22 23:25
Thionazin
ug/L
ND
10.0
02/25/22 23:25
2,4,6-Tribromophenol (S)
%
66
10-144
02/25/22 23:25
2-Fluorobiphenyl (S)
%
53
10-130
02/25/22 23:25
2-Fluorophenol (S)
%
28
10-130
02/25/22 23:25
Nitrobenzene-d5 (S)
%
54
10-144
02/25/22 23:25
Phenol-d6 (S)
%
31
10-130
02/25/22 23:25
Terphenyl-d14 (S)
%
86
34-163
02/25/22 23:25
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3558849
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2,4,5-Tetrachlorobenzene
ug/L
50
33.4
67
17-130
1,3,5-Trinitrobenzene
ug/L
50
54.6
109
44-200
1,3-Dinitrobenzene
ug/L
50
52.8
106
39-159
1,4-Naphthoquinone
ug/L
50
55.0
110
10-159
1-Naphthalenamine
ug/L
50
30.0
60
10-130
2,2'-Oxybis(1-chloropropane)
ug/L
50
39.8
80
28-130
2,3,4,6-Tetrachlorophenol
ug/L
50
47.8
96
10-200
2,4,5-Trichlorophenol
ug/L
50
48.4
97
35-130
2,4,6-Trichlorophenol
ug/L
50
45.6
91
31-130
2,4-Dichlorophenol
ug/L
50
45.5
91
35-130
2,4-Dimethylphenol
ug/L
50
42.0
84
34-130
2,4-Dinitrophenol
ug/L
250
228
91
10-153
2,4-Dinitrotoluene
ug/L
50
50.1
100
37-136
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 62 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
LABORATORY CONTROL SAMPLE:
Parameter
3558849
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,6-Dichlorophenol
ug/L
50
48.5
97
31-139
2,6-Dinitrotoluene
ug/L
50
50.9
102
33-136
2-Acetylaminofluorene
ug/L
50
48.5
97
19-181
2-Chloronaphthalene
ug/L
50
38.6
77
26-130
2-Chlorophenol
ug/L
50
39.6
79
37-130
2-Methylnaphthalene
ug/L
50
39.3
79
29-130
2-Methylphenol(o-Cresol)
ug/L
50
39.3
79
35-130
2-Naphthalenamine
ug/L
50
27.2
54
10-136
2-Nitroaniline
ug/L
100
96.4
96
37-130
2-Nitrophenol
ug/L
50
46.9
94
32-130
3&4-Methyl phenol (m&p Cresol)
ug/L
50
37.9
76
34-130
3,3'-Dichlorobenzidine
ug/L
100
86.4
86
34-136
3,3'-Dimethylbenzidine
ug/L
100
94.6
95
10-2001H
3-Methylcholanthrene
ug/L
50
40.1
80
39-190
3-Nitroaniline
ug/L
100
100
100
37-138IL
4,6-Dinitro-2-methyl phenol
ug/L
100
85.2
85
21-157
4-Aminobiphenyl
ug/L
50
29.6
59
17-137
4-Bromophenylphenyl ether
ug/L
50
44.3
89
38-130
4-ChIoro-3-methyl phenol
ug/L
100
90.6
91
37-130
4-Chloroaniline
ug/L
100
87.4
87
38-130
4-Chlorophenylphenyl ether
ug/L
50
45.3
91
33-130
4-Nitroaniline
ug/L
100
102
102
42-137
4-Nitrophenol
ug/L
250
156
62
10-130
5-Nitro-o-toluidine
ug/L
50
50.9
102
39-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
37.8
76
33-139
Acenaphthene
ug/L
50
43.1
86
33-130
Acenaphthylene
ug/L
50
44.0
88
35-130
Acetophenone
ug/L
50
43.7
87
36-130
Anthracene
ug/L
50
43.1
86
48-130
Benzo(a)anthracene
ug/L
50
45.9
92
48-137
Benzo(a)pyrene
ug/L
50
31.0
62
49-138
Benzo(b)fluoranthene
ug/L
50
31.6
63
52-138
Benzo(g,h,i)perylene
ug/L
50
31.1
62
48-140
Benzo(k)fluoranthene
ug/L
50
30.5
61
48-139
Benzyl alcohol
ug/L
100
85.6
86
35-130
bis(2-Chloroethoxy)methane
ug/L
50
45.2
90
34-130
bis(2-Chloroethyl) ether
ug/L
50
42.8
86
36-130
bis(2-Ethylhexyl)phthalate
ug/L
50
47.3
95
32-165
Butylbenzylphthalate
ug/L
50
48.9
98
34-161
Chlorobenzilate
ug/L
50
44.2
88
43-176
Chrysene
ug/L
50
45.0
90
47-131
Di-n-butylphthalate
ug/L
50
47.8
96
39-144
Di-n-octylphthalate
ug/L
50
44.7
89
30-170
Diallate
ug/L
50
44.8
90
33-143
Dibenz(a,h)anthracene
ug/L
50
33.0
66
49-138
Dibenzofuran
ug/L
50
44.0
88
33-130
Diethylphthalate
ug/L
50
47.4
95
38-131
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 63 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
LABORATORY CONTROL SAMPLE:
Parameter
3558849
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethoate
ug/L
50
50.4
101
46-173
Dimethylphthalate
ug/L
50
46.6
93
37-130
Diphenylamine
ug/L
50
40.6
81
35-135
Disulfoton
ug/L
50
39.1
78
34-139
Ethyl methanesulfonate
ug/L
50
44.0
88
33-133
Famphur
ug/L
100
69.0
69
10-1301H
Fluoranthene
ug/L
50
47.7
95
46-137
Fluorene
ug/L
50
46.1
92
37-130
Hexachloro-1,3-butadiene
ug/L
50
26.2
52
11-130
Hexachlorobenzene
ug/L
50
42.6
85
38-130
Hexachlorocyclopentadiene
ug/L
50
31.0
62
10-130
Hexachloroethane
ug/L
50
24.8
50
14-130
Hexachloropropene
ug/L
50
18.5
37
10-130
Indeno(1,2,3-cd)pyrene
ug/L
50
31.3
63
41-130
Isodrin
ug/L
50
43.1
86
36-139
Isophorone
ug/L
50
45.1
90
33-130
Isosafrole
ug/L
50
39.0
78
22-130
Kepone
ug/L
100
67.5
68
10-130
Methapyrilene
ug/L
50
ND
20
10-1731H
Methyl methanesulfonate
ug/L
50
38.6
77
33-130
Methyl parathion
ug/L
50
58.1
116
39-200
N-Nitroso-di-n-butylamine
ug/L
50
40.7
81
22-130
N-Nitroso-di-n-propylamine
ug/L
50
45.9
92
36-130
N-Nitrosodiethylamine
ug/L
50
43.6
87
23-136
N-Nitrosodimethylamine
ug/L
50
33.6
67
34-130
N-Nitrosodiphenylamine
ug/L
50
40.6
81
37-130
N-Nitrosomethylethylamine
ug/L
50
41.0
82
18-137
N-Nitrosopiperidine
ug/L
50
47.3
95
25-142
N-Nitrosopyrrolidine
ug/L
50
42.7
85
24-146
Nitrobenzene
ug/L
50
42.9
86
36-130
O,O,O-Triethylphosphorothioate
ug/L
50
43.9
88
29-130
O-Toluidine
ug/L
50
39.7
79
27-132
P-Dimethylaminoazobenzene
ug/L
50
20.5
41
17-130IL
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
51.3
103
32-200
Pentachlorobenzene
ug/L
50
41.2
82
27-130
Pentachloronitrobenzene
ug/L
50
53.4
107
47-164
Pentachlorophenol
ug/L
100
86.0
86
23-149
Phenacetin
ug/L
50
52.5
105
44-181
Phenanthrene
ug/L
50
44.1
88
44-130
Phenol
ug/L
50
26.1
52
18-130
Phorate
ug/L
50
44.0
88
18-183
Pronamide
ug/L
50
52.0
104
45-163
Pyrene
ug/L
50
42.8
86
47-134
Safrole
ug/L
50
43.0
86
27-130
Thionazin
ug/L
50
49.7
99
36-162
2,4,6-Tribromophenol (S)
%
93
10-144
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 64 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
LABORATORY CONTROL SAMPLE:
3558849
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
2-Fluorobiphenyl (S)
%
78
10-130
2-Fluorophenol(S)
%
61
10-130
Nitrobenzene-d5 (S)
%
86
10-144
Phenol-d6 (S)
%
51
10-130
Terphenyl-d14 (S)
%
82
34-163
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3558850
MS
35697686001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3558851
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
4.51-1
50
50
16.3
23.7
33
47
10-130
37 R1
1,3,5-Trinitrobenzene
ug/L
5.51-1
50
50
21.6
30.1
43
60
50-200
33 M1,R1
1,3-Dinitrobenzene
ug/L
3.81-1
50
50
29.9
43.0
60
86
43-161
36 R1
1,4-Naphthoquinone
ug/L
4.41-1
50
50
11.2
17.4
22
35
10-184
43 R1
1-Naphthalenamine
ug/L
4.1U
50
50
16.1
28.7
32
57
10-130
56 R1
2,2'-Oxybis(1-chloropropane)
ug/L
1.21-1
50
50
19.3
28.8
39
58
12-142
39 R1
2,3,4,6-Tetrachlorophenol
ug/L
1.51-1
50
50
24.6
34.0
49
68
10-198
32 R1
2,4,5-Trichlorophenol
ug/L
1.41-1
50
50
27.6
30.0
55
60
10-143
8
2,4,6-Trichlorophenol
ug/L
1.61-1
50
50
23.7
33.2
47
66
10-147
33 R1
2,4-Dichlorophenol
ug/L
1.41-1
50
50
22.9
34.8
46
70
10-138
41 R1
2,4-Dimethylphenol
ug/L
1.71-1
50
50
22.5
34.1
45
68
25-130
41 R1
2,4-Dinitrophenol
ug/L
26.01-1
250
250
ND
ND
10
10
10-165
2,4-Dinitrotoluene
ug/L
1.61-1
50
50
29.7
41.2
59
82
29-148
33 R1
2,6-Dichlorophenol
ug/L
4.21-1
50
50
21.6
31.2
43
62
33-139
36 R1
2,6-Dinitrotoluene
ug/L
1.71-1
50
50
46.9
63.8
94
128
26-146
31 R1
2-Acetylaminofluorene
ug/L
4.1 U
50
50
35.6
48.3
71
97
27-172
30
2-Chloronaphthalene
ug/L
1.71-1
50
50
19.6
29.4
39
59
11-130
40 R1
2-Chlorophenol
ug/L
1.21-1
50
50
19.8
29.6
40
59
10-133
40 R1
2-Methylnaphthalene
ug/L
1.91-1
50
50
19.1
28.7
38
57
13-130
40 R1
2-Methylphenol(o-Cresol)
ug/L
1.91-1
50
50
21.6
32.1
43
64
20-130
39 R1
2-Naphthalenamine
ug/L
5.41-1
50
50
19.8
30.5
40
61
10-135
42 R1
2-Nitroaniline
ug/L
3.01-1
100
100
55.0
73.7
55
74
24-136
29
2-Nitrophenol
ug/L
1.41-1
50
50
22.3
33.4
45
67
10-153
40 R1
3&4-Methyl phenol (m&p
ug/L
1.21-1
50
50
20.2
36.2
40
72
16-130
57 R1
Cresol)
3,3'-Dichlorobenzidine
ug/L
8.1U
100
100
8.9J
12.1J
9
12
10-153
M1
3,3'-Dimethylbenzidine
ug/L
31.1U
100
100
ND
ND
0
0
10-200
IH,M1
3-Methylcholanthrene
ug/L
5.81-1
50
50
27.8
39.6
56
79
53-181
35 R1
3-Nitroaniline
ug/L
3.81-1
100
100
61.0
82.6
61
83
22-151
30IL
4,6-Dinitro-2-methyl phenol
ug/L
3.41-1
100
100
23.3
27.0
23
27
10-180
14
4-Aminobiphenyl
ug/L
4.71-1
50
50
11.5
18.0
23
36
10-139
44 R1
4-Bromophenylphenyl ether
ug/L
1.81-1
50
50
25.5
36.1
51
72
25-130
34 R1
4-Chloro-3-methyl phenol
ug/L
3.31-1
100
100
61.6
90.0
62
90
25-133
37 R1
4-Chloroaniline
ug/L
3.61-1
100
100
47.9
67.9
48
68
14-132
34 R1
4-Chlorophenylphenyl ether
ug/L
2.01-1
50
50
23.2
34.3
46
69
19-130
38 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 65 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3558850
MS
35697686001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3558851
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
4-Nitroaniline
ug/L
5.1 U
100
100
62.1
84.3
62
84
29-150
30
4-Nitrophenol
ug/L
6.61-1
250
250
38.1J
54.4
15
22
10-130
5-Nitro-o-toluidine
ug/L
3.81-1
50
50
26.2
39.0
52
78
48-163
39 R1
7,12-
ug/L
3.01-1
50
50
23.0
32.8
46
66
40-140
35 R1
Di methyl benz(a)anth racene
Acenaphthene
ug/L
2.01-1
50
50
21.7
32.8
43
66
16-130
41 R1
Acenaphthylene
ug/L
2.01-1
50
50
22.4
33.7
45
67
15-137
40 R1
Acetophenone
ug/L
1.51-1
50
50
22.2
33.4
44
67
28-130
40 R1
Anthracene
ug/L
2.31-1
50
50
26.5
38.2
53
76
37-136
36 R1
Benzo(a)anthracene
ug/L
2.71-1
50
50
27.4
40.6
55
81
40-145
39 R1
Benzo(a)pyrene
ug/L
2.81-1
50
50
18.2
27.3
36
55
41-146
40 M1,R1
Benzo(b)fluoranthene
ug/L
2.61-1
50
50
18.1
26.9
36
54
39-151
39 M1,R1
Benzo(g,h,i)perylene
ug/L
2.81-1
50
50
19.1
28.8
38
58
40-147
40 M1,R1
Benzo(k)fluoranthene
ug/L
2.71-1
50
50
17.0
25.8
34
52
40-146
41 M1,R1
Benzyl alcohol
ug/L
2.91-1
100
100
43.1
65.9
43
66
25-130
42 R1
bis(2-Chloroethoxy)methane
ug/L
1.81-1
50
50
26.2
38.7
52
77
23-130
39 R1
bis(2-Chloroethyl) ether
ug/L
1.91-1
50
50
20.8
31.2
42
62
25-130
40 R1
bis(2-Ethylhexyl)phthalate
ug/L
3.71-1
50
50
31.2
45.1
59
87
28-166
36 R1
Butylbenzylphthalate
ug/L
3.1 U
50
50
29.7
44.4
59
89
33-165
40 R1
Chlorobenzilate
ug/L
3.81-1
50
50
29.6
49.2
59
98
55-170
50 R1
Chrysene
ug/L
2.81-1
50
50
27.1
39.7
54
79
38-141
38 R1
Di-n-butylphthalate
ug/L
2.21-1
50
50
30.1
43.1
60
86
32-153
36 R1
Di-n-octylphthalate
ug/L
3.91-1
50
50
27.1
40.7
54
81
30-175
40 R1
Diallate
ug/L
3.41-1
50
50
25.5
36.7
51
73
39-141
36 R1
Dibenz(a,h)anthracene
ug/L
3.01-1
50
50
19.6
30.2
39
60
39-148
42 R1
Dibenzofuran
ug/L
2.1 U
50
50
22.4
33.6
45
67
20-130
40 R1
Diethylphthalate
ug/L
2.01-1
50
50
28.0
39.9
56
80
28-142
35 R1
Dimethoate
ug/L
3.71-1
50
50
30.6
40.1
61
80
57-167
27
Dimethylphthalate
ug/L
2.1 U
50
50
26.2
37.6
52
75
26-136
36 R1
Diphenylamine
ug/L
3.01-1
50
50
27.4
38.2
55
76
38-132
33 R1
Disulfoton
ug/L
4.61-1
50
50
25.0
34.4
50
69
40-140
32 R1
Ethyl methanesulfonate
ug/L
3.01-1
50
50
21.3
31.8
43
64
38-134
40 R1
Famphur
ug/L
6.1 U
100
100
29.6
25.8
30
26
10-130
14 IH
Fluoranthene
ug/L
2.21-1
50
50
28.0
41.1
56
82
39-143
38 R1
Fluorene
ug/L
2.1U
50
50
24.0
36.0
48
72
24-132
40 R1
Hexachloro-1,3-butadiene
ug/L
1.81-1
50
50
13.8
20.6
28
41
10-130
39 R1
Hexachlorobenzene
ug/L
2.21-1
50
50
22.9
33.5
46
67
29-130
37 R1
Hexachlorocyclopentadiene
ug/L
1.61-1
50
50
11.1
12.2
22
24
10-130
9
Hexachloroethane
ug/L
1.41-1
50
50
13.8
19.8
28
40
10-130
36 R1
Hexachloropropene
ug/L
7.01-1
50
50
8.3J
11.7
17
23
10-130
Indeno(1,2,3-cd)pyrene
ug/L
2.91-1
50
50
19.0
28.5
38
57
39-148
40 M1,R1
Isodrin
ug/L
2.81-1
50
50
27.6
38.6
55
77
45-138
33 R1
Isophorone
ug/L
1.71-1
50
50
23.1
34.2
46
68
23-130
39 R1
Isosafrole
ug/L
2.51-1
50
50
20.3
29.7
41
59
25-130
38 R1
Kepone
ug/L
14.1 U
100
100
37.9
30.1
38
30
10-130
23
Methapyrilene
ug/L
17.01-1
50
50
49.3J
71.5
99
143
10-181
IH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 66 of 122

laceAnalytical"
WWW.pacalabs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3558850
MS
35697686001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3558851
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Methyl methanesulfonate
ug/L
3.1U
50
50
18.8
27.1
38
54
31-130
37 R1
Methyl parathion
ug/L
3.71-1
50
50
34.7
45.2
69
90
53-197
26
N-Nitroso-di-n-butylamine
ug/L
8.71-1
50
50
26.4
40.3
53
81
28-130
42 R1
N-Nitroso-di-n-propylamine
ug/L
1.31-1
50
50
23.1
34.0
46
68
25-130
38 R1
N-Nitrosodiethylamine
ug/L
2.31-1
50
50
22.2
32.2
44
64
29-132
37 R1
N-Nitrosodimethylamine
ug/L
1.91-1
50
50
17.5
25.4
35
51
22-130
37 R1
N-Nitrosodiphenylamine
ug/L
3.01-1
50
50
27.4
38.2
55
76
26-134
33 R1
N-Nitrosomethylethylamine
ug/L
7.51-1
50
50
21.3
30.1
43
60
24-133
34 R1
N-Nitrosopiperidine
ug/L
2.51-1
50
50
22.6
32.3
45
65
29-141
35 R1
N-Nitrosopyrrolidine
ug/L
3.1 U
50
50
21.3
31.9
43
64
29-140
40 R1
Nitrobenzene
ug/L
1.91-1
50
50
21.1
31.3
42
63
25-130
39 R1
0,0,0-
ug/L
2.61-1
50
50
19.8
29.4
40
59
30-130
39 R1
Triethyl phosphorothioate
O-Toluidine
ug/L
3.1J
50
50
32.8
47.1
59
88
27-130
36 R1
P-Dimethylaminoazobenzene
ug/L
2.41-1
50
50
13.6
19.3
27
39
20-130
341L,R1
p-Phenylenediamine
ug/L
10.01-1
ND
ND
Parathion (Ethyl parathion)
ug/L
3.91-1
50
50
33.3
45.8
67
92
48-200
32 R1
Pentachlorobenzene
ug/L
3.41-1
50
50
20.3
30.0
41
60
23-130
39 R1
Pentachloronitrobenzene
ug/L
3.31-1
50
50
31.1
43.4
62
87
57-159
33 R1
Pentachlorophenol
ug/L
3.81-1
100
100
43.0
55.7
43
56
10-175
26
Phenacetin
ug/L
3.61-1
50
50
38.8
47.8
78
96
57-179
21
Phenanthrene
ug/L
2.01-1
50
50
26.6
37.8
53
76
36-133
35 R1
Phenol
ug/L
1.41-1
50
50
14.5
24.2
29
48
10-130
50 R1
Phorate
ug/L
3.61-1
50
50
25.7
35.8
51
72
21-192
33 R1
Pronamide
ug/L
3.1U
50
50
34.0
47.3
68
95
55-162
33 R1
Pyrene
ug/L
2.21-1
50
50
27.2
39.4
54
79
40-143
37 R1
Safrole
ug/L
2.31-1
50
50
19.5
29.9
39
60
25-130
42 R1
Thionazin
ug/L
2.91-1
50
50
32.4
48.1
65
96
50-157
39 R1
2,4,6-Tribromophenol (S)
%
58
84
10-144
2-Fluorobiphenyl (S)
%
37
56
10-130
2-Fluorophenol(S)
%
29
44
10-130
Nitrobenzene-d5 (S)
%
43
64
10-144
Phenol-d6 (S)
%
28
42
10-130
Terphenyl-d14(S)
%
49
73
34-163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 67 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 679516 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
METHOD BLANK: 3555616
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Sulfide
ug/L
ND
100
02/19/22 04:05
LABORATORY CONTROL SAMPLE:
3555617
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Sulfide
ug/L
500
512
102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3555618 3555619
MS MSD
92588963002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfide ug/L ND 500 500 498 530 99 105 80-120 6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3555620 3555621
MS MSD
92588963001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfide ug/L ND 500 500 484 486 97 97 80-120 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 68 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680171 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
METHOD BLANK: 3558693
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Sulfate
ug/L
ND
1000
02/23/22 08:25
LABORATORY CONTROL SAMPLE:
3558694
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Sulfate
ug/L
50000
49600
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3558695 3558696
MS MSD
92588489001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate ug/L 25.3 50000 50000 86300 87300 122 124 90-110 1 M1
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3558697 3558698
MS MSD
92588489011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate ug/L ND 50000 50000 60800 59800 121 119 90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 69 of 122

laceAnalytical"
wwmpacalahs,com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680490 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
METHOD BLANK: 3560339
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chemical Oxygen Demand
ug/L
ND
25000
02/24/22 05:03
LABORATORY CONTROL SAMPLE:
3560340
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chemical Oxygen Demand
ug/L
750000
812000
108 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3560341 3560342
MS MSD
92588526001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand ug/L 85.2 100000 100000 199000 204000 114 118 90-110 2 M1
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3560343 3560344
MS MSD
92589430003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand ug/L 51.4 100000 100000 163000 163000 111 111 90-110 0 M1
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 70 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
wwmpacalahs.00m [phone]
QUALITY CONTROL DATA
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
QC Batch: 680715 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
METHOD BLANK: 3561110
Matrix:
Water
Associated Lab Samples: 92588907008, 92588907009, 92588907010, 92588907011
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
ug/L
ND
1000
02/24/22 23:28
LABORATORY CONTROL SAMPLE:
3561111
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
ug/L
25000
24200
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3561975 3561976
MS MSD
92588578001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon ug/L ND 25000 25000 24500 24600 98 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3561977 3561978
MS MSD
92588649001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon ug/L 5.5 25000 25000 30100 30000 98 98 90-110 0
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC.
Page 71 of 122

Pace Analytical Services, LLC
�e A u�rytica r� 9800 Kincey Ave. Suite 100
078
�r r J Huntersville, NC 28078
WWW.pacalabs.Com [phone]
QUALIFIERS
Project: OXFORD COMPLIANCE/BUTNER COMPL
Pace Project No.: 92588907
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
1g Re -extraction conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.
B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.
C8 Result may be biased high due to carryover from previously analyzed sample.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
R6 The RPD between valid sample dilutions exceeded 30%.
SO Surrogate recovery outside laboratory control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/15/2022 11:21 AM without the written consent of Pace Analytical Services, LLC. Page 72 of 122

laceAnalyticaf`
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
OXFORD COMPLIANCE/BUTNER COMPL
92588907
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92588907008
3902-MW1R
HACH 10206
679109
92588907009
3902-MW2R
HACH 10206
679109
92588907010
3902-MW3R
HACH 10206
679109
92588907011
3902-NES1
HACH 10206
679109
92588907008
3902-MW1R
SM 521OB-2016
679198
SM 521OB-2016
679441
92588907009
3902-MW2R
SM 521OB-2016
679198
SM 521OB-2016
679441
92588907010
3902-MW3R
SM 521OB-2016
679198
SM 521OB-2016
679441
92588907011
3902-NES1
SM 521OB-2016
679198
SM 521OB-2016
679441
92588907008
3902-MW1R
EPA 3510C
680340
EPA 8081B
681224
92588907009
3902-MW2R
EPA 3510C
680340
EPA 8081B
681224
92588907010
3902-MW3R
EPA 3510C
680340
EPA 8081B
681224
92588907008
3902-MW1 R
EPA 3510C
680708
EPA 8082A
681222
92588907009
3902-MW2R
EPA 3510C
680708
EPA 8082A
681222
92588907010
3902-MW3R
EPA 3510C
680708
EPA 8082A
681222
92588907008
3902-MW1R
RSK 175 Modified
680064
92588907009
3902-MW2R
RSK 175 Modified
679501
92588907010
3902-MW3R
RSK 175 Modified
679501
92588907011
3902-NES1
RSK 175 Modified
679501
92588907002
3902-SW2
EPA 3010A
681459
EPA 6010D
681665
92588907003
3902-SW1
EPA 3010A
681459
EPA 6010D
681665
92588907004
3902-MW6
EPA 3010A
681459
EPA 6010D
681665
92588907005
3902-MW5
EPA 3010A
681459
EPA 6010D
681665
92588907006
3902-FB02
EPA 3010A
681459
EPA 6010D
681665
92588907007
3902-MW4
EPA 3010A
681459
EPA 6010D
681665
92588907008
3902-MW1R
EPA 3010A
681459
EPA6010D
681665
92588907009
3902-MW2R
EPA 3010A
681459
EPA 6010D
681665
92588907010
3902-MW3R
EPA 3010A
681459
EPA 6010D
681665
92588907002
3902-SW2
EPA 3010A
680097
EPA 6020B
681083
92588907003
3902-SW1
EPA 3010A
680097
EPA 6020B
681083
92588907004
3902-MW6
EPA 3010A
680097
EPA 6020B
681083
92588907005
3902-MW5
EPA 3010A
680097
EPA 6020B
681083
92588907006
3902-FB02
EPA 3010A
680097
EPA 6020B
681083
92588907007
3902-MW4
EPA 3010A
680097
EPA 6020B
681083
92588907008
3902-MW1 R
EPA 3010A
680097
EPA 6020B
681083
92588907009
3902-MW2R
EPA 3010A
680097
EPA 6020B
681083
92588907010
3902-MW3R
EPA 3010A
680097
EPA 6020B
681083
92588907011
3902-NES1
EPA 3010A
680097
EPA 6020B
681083
92588907008
3902-MW1 R
EPA 7470A
681648
EPA 7470A
682130
92588907009
3902-MW2R
EPA 7470A
681648
EPA 7470A
682130
92588907010
3902-MW3R
EPA 7470A
681648
EPA 7470A
682130
92588907008
3902-MW1 R
EPA 3510C
680247
EPA 8270E
680584
92588907009
3902-MW2R
EPA 3510C
680247
EPA 8270E
680584
92588907010
3902-MW3R
EPA 3510C
680247
EPA 8270E
680584
92588907001
3902-TRIP BLANK 02
EPA 8260D
679201
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 06/15/2022 11:21
AM
without the written consent of Pace Analytical Services, LLC.
Page 73 of 122

laceAnalyticaf`
WWW.pacalahs'com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
OXFORD COMPLIANCE/BUTNER
92588907
COMPL
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92588907002
3902-SW2
EPA 8260D
679201
92588907003
3902-SW1
EPA 8260D
679201
92588907004
3902-MW6
EPA 8260D
679201
92588907005
3902-MW5
EPA 8260D
679201
92588907006
3902-FB02
EPA 8260D
679201
92588907007
3902-MW4
EPA 8260D
679201
92588907008
3902-MW1R
EPA 8260D
679201
92588907009
3902-MW2R
EPA 8260D
679201
92588907010
3902-MW3R
EPA 8260D
679201
92588907011
3902-N ES1
EPA 8260D
679201
92588907001
3902-TRIP BLANK 02
EPA 8260D Mod.
679312
92588907002
3902-SW2
EPA 8260D Mod.
679313
92588907003
3902-SW1
EPA 8260D Mod.
679313
92588907004
3902-MW6
EPA 8260D Mod.
679313
92588907005
3902-MW5
EPA 8260D Mod.
679313
92588907006
3902-FB02
EPA 8260D Mod.
679312
92588907007
3902-MW4
EPA 8260D Mod.
679313
92588907008
3902-MW1R
EPA 8260D Mod.
679313
92588907009
3902-MW2R
EPA 8260D Mod.
679312
92588907010
3902-MW3R
EPA 8260D Mod.
679313
92588907011
3902-N ES1
EPA 8260D Mod.
679313
92588907008
3902-MW1R
SM 4500-S2D-2011
679516
92588907009
3902-MW2R
SM 4500-S2D-2011
679516
92588907010
3902-MW3R
SM 4500-S2D-2011
679516
92588907011
3902-N ES1
SM 4500-S2D-2011
679516
92588907008
3902-MW1 R
EPA 300.0 Rev 2.1 1993
680171
92588907009
3902-MW2R
EPA 300.0 Rev 2.1 1993
680171
92588907010
3902-MW3R
EPA 300.0 Rev 2.1 1993
680171
92588907011
3902-NES1
EPA 300.0 Rev 2.1 1993
680171
92588907008
3902-MW1R
SM 5220D-2011
680490
SM 5220D-2011 680504
92588907009
3902-MW2R
SM 5220D-2011
680490
SM 5220D-2011 680504
92588907010
3902-MW3R
SM 5220D-2011
680490
SM 5220D-2011 680504
92588907011
3902-N ES1
SM 5220D-2011
680490
SM 5220D-2011 680504
92588907008
3902-MW1R
SM 531OB-2014
680715
92588907009
3902-MW2R
SM 531OB-2014
680715
92588907010
3902-MW3R
SM 531OB-2014
680715
92588907011
3902-N ES1
SM 531OB-2014
680715
Date: 06/15/2022 11:21 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 74 of 122

Document Name.
Document fievised! November 15, 2021
` aceAnalytical ~
Sample Condition Upon Receipt (SCUR)
Page 1 of 2
Document No.:
issuing Authority:
F-CAR-CS-033-Rev.08
Pace Carolinas Quality Office
Laboratory receiving samples:
t
Asheville 1-1Eden❑ Greenwood ❑ Huntersvi4l Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
ConditionSample Up -an ReceiptClient Name: Project p: WO# . 9Lr58$,907
V tiJ
Courier: RFed Pace x ❑UPS ❑Client
❑Camrnercial Other: fJ j+jjJJ
92SB8907
Custody Seat Present? Dyes No Seals Intact? []Yes �Ko
Date/Initials Person Examining Contents:
Packing Material: Bubble Wrap tgg6bble Bags []None ❑ other Blologicaf Tis u�e Frozen?
TherTnc�$Z
�-j��❑Yes ❑No (r{Nivn 10: !'Vet ❑glue ❑None
Type of ice:
Canectlon Factor: i']
Coo ler Temp; ' [ Add/Subtract i'CJ C� Temp should be above freezing to VC
❑Samples out of temp criteria_ Samples on ice, coaling process
t:ooler•Temp-Carrected-IrCl. _ • r` niT un
USDA Regulated Sall (❑ NJA, water sample)
Did samples originate !n a quarantine tone within the United States: CA, NY, or SC (check maps)? Old samples anginate from a I'velgn source (internationally,
❑Yes ❑No includingFdawali and Puerto Rico1? ❑Yes I7ND
Comrments/fllscrepanc :
Chain of Custody Present?
tifes
[]No
❑N/A
1.
Samples Arrived within Hold Time?
`ffYes
❑No
N/A
2.
Short Hold Time Analysis a72 hr. 7
Yes
No
N/A
3.
Rush Turn Araund Time Requested?
Dyes
o
CNIA
4.
Sufficient Volume?
es
oft
NJA
S-
Correct Containers Used?
es
❑No
❑N/A
6.
Pace Containers Used?
ZEts
No
[]N/A
Containers Intact?
,fires
❑No
NNIA
7.
Dissolved analysis: Samples Field Filtered?
yes
Na
,_
pyu/A
8.
Sample Labels Match COC7
ea
❑Na
[:]N/A
9.
\-i ++
Includes oate/Tlme/ID/Analysis Matrl*
Headspaee in VOA Vials (nS•Smmj?
❑yes
)�No
❑N/A
10.
Trip Blank Present?
Yes
(]NO
❑N/A
11-
Trip Blank Custody Seals Present?
oyes
❑N❑
❑NIA
COMMENTS/SAMPLE 0ISCREPANCY
A&\A/ 2) i
Field Uato Required? ❑Ye$ [-]No
_ 'n ;,- /'o 6"u'L i
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
C i GLi GLkY1 n d i
Person contacted: y"r G{_.Y Date/Time; .-+ O' — 1 0 �o
Project Manager SCURF Review: � i x � �� Date:
Project Manager SRF Review: Date:
Page 75 of 122

Document Name: Document Issued: November 15, 2021
Bottle Identification Form (BIF) Page 1 of I
aCeRlT�lytlCa� document No.: Issuing Authority:
F-CAR-CS.043-Rev-01 Pace Carolinas Quality Office
'Check mark top half of box if pH and/or dechlorinatlon is
verified and within the acceptance range for preservation
samples,
Exceptlons: VOA, Collform, TOC, Oil and Grease, DRCtf8015 (water) DOC, LLHg
"*Bottom half of box Is to list number of bottles
Project 1 WO# ■ 9L,588907
PM: FMB Due date: 03/02/22
CLIENT: 92-Garrett.
C
A
1
z
z
z
V
ry
2
ti
r
iv
Q
Q
a
v
a
V
r�+e
v
°ti
a
N
v
a
n
2
a
z
a
N
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Lotk
Note: wnenever tnere is a d1screpancy affecting Nana Carallna compliance samples, a ropy or this +orm will ne sent to the North Carohna DEHNR Cerllhration oFnce {i.e.
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Page 76 of 122

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Ne 78 of 122

ton -test°
A Pace Analyb'cale LaboWxy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
March 9, 2022
Angela Baioni
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: NC
Client Job Number:
Project Number: 92588907
Laboratory Work Order Number: 22B 1220
Enclosed are results of analyses for samples as received by the laboratory on February 19, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Raymond J. McCarthy
Project Manager
srrsc-nzrrir
IRRI •

Table of Contents
Table of Contents
Sample Summary
Case Narrative
Sample Results
22B 1220-01
22B 1220-02
22B 1220-03
Sample Preparation Information
QC Data
Herbicides by GC/ECD
B302586
Dual Column RPD Report
Flag/Qualifier Summary
Certifications
Chain of Custody/Sample Receipt
3
4
5
5
6
7
8
9
9
9
10
12
13
14
srrsrnzrrir
'. is, - •

Table of Contents
con -testa
A Pace Analyb'cale LaboWxy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100 REPORT DATE: 3/9/2022
Huntersville, NC 28078 PURCHASE ORDER NUMBER:
ATTN: Angela Baioni
PROJECT NUMBER: 92588907
ANALYTICAL SUMMARY
WORK ORDER NUMBER: 22B1220
The results of analyses performed on the following samples submitted to CON -TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION: NC
FIELD SAMPLE # LAB ID: MATRIX SAMPLE DESCRIPTION TEST SUB LAB
3902-MW1R 22B1220-01 Water SW-8468151A
3902-MW2R 22B1220-02 Water SW-8468151A
3902- MW3R 22B1220-03 Water SW-846 8151A
Page 3 of 16

ton -test°
A Pace Analyb'cale LaboWxy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method 8151 samples were derivatized on 03/08/22
For method 8151 samples analysis bracketed by LCS to monitor esterification. All recoveries in the bracketing LCS met method criteria.
SW-846 8151A
Qualifications:
R-05
Laboratory fortified blank duplicate RPD is outside of control limits. Reduced precision is anticipated for any reported value for this
compound.
Analyte & Samples(s) Qualified:
Dinoseb
22B1220-01[3902- MW1R], 22B1220-02[3902- MW2R], 22B1220-03[3902- MW3R], B302586-BLKI, B302586-BSI, B302586-BSDI
Dinoseb [2C]
22B1220-01[3902- MW1R], 22B1220-02[3902- MW2R], 22B1220-03[3902- MW3R], B302586-BLKI, B302586-BSI, B302586-BSD1
The results of analyses reported only relate to samples submitted to Con -Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
d�
Lisa A. Worthington
Technical Representative
ST.TS_i►ntiD➢
0 E • 0

Table of Contents
ton -test°
A Pace Analyb'cale LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: NC Sample Description: Work Order: 22B 1220
Date Received: 2/19/2022
Field Sample #: 3902- MWlR Sampled: 2/16/2022 13:16
Sample ID: 22B1220-01
Sample Matrix: Water
Herbicides by GC/ECD
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qua] Method Prepared Analyzed Analyst
2,4-D [1]
ND
0.54 0.11
µg/L 1
SW-846 8151A
3/6/22
3/8/22 18:09
TG
2,4,5-TP (Silvex) [1]
ND
0.054 0.011
µg/L 1
SW-846 8151A
3/6/22
3/8/22 18:09
TG
2,4,5-T [1]
ND
0.11 0.026
µg/L 1
SW-846 8151A
3/6/22
3/8/22 18:09
TG
Dinoseb [1]
ND
0.27 0.050
µg/L 1
R-05 SW-846 8151A
3/6/22
3/8/22 18:09
TG
Surrogates
% Recovery
Recovery Limits
Flag/Qual
2,4-Dichlorophenylacetic acid [1]
79.1
30-150
3/8/22 18:09
2,4-Dichlorophenylacetic acid [2]
88.8
30-150
3/8/22 18:09
Page 5 of 16

Table of Contents
ton -test°
A Pace Analyb'cale LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: NC Sample Description: Work Order: 22B 1220
Date Received: 2/19/2022
Field Sample #: 3902- MW2R Sampled: 2/16/2022 13:44
Sample ID: 22B1220-02
Samule Matrix: Water
Herbicides by GC/ECD
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qual Method Prepared Analyzed Analyst
2,4-D [1]
ND
0.51 0.11
µg/L 1
SW-846 8151A
3/6/22
3/8/22 18:49
TG
2,4,5-TP (Silvex) [1]
ND
0.051 0.010
µg/L 1
SW-846 8151A
3/6/22
3/8/22 18:49
TG
2,4,5-T [1]
ND
0.10 0.025
µg/L 1
SW-846 8151A
3/6/22
3/8/22 18:49
TG
Dinoseb [1]
ND
0.25 0.047
µg/L 1
R-05 SW-846 8151A
3/6/22
3/8/22 18:49
TG
Surrogates
% Recovery
Recovery Limits
Flag/Qual
2,4-Dichlorophenylacetic acid [1]
77.9
30-150
3/8/22 18:49
2,4-Dichlorophenylacetic acid [2]
89.2
30-150
3/8/22 18:49
Ragia Ad of 122
Page 6 of 16

Table of Contents
ton -test°
A Pace Analyb'cale LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: NC Sample Description: Work Order: 22B 1220
Date Received: 2/19/2022
Field Sample #: 3902- MW3R Sampled: 2/16/2022 10:00
Sample ID: 22B1220-03
Sample Matrix: Water
Herbicides by GC/ECD
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qual Method Prepared Analyzed Analyst
2,4-D [1]
ND
0.49 0.10
µg/L 1
SW-846 8151A
3/6/22
3/8/22 19:29
TG
2,4,5-TP (Silvex) [1]
ND
0.049 0.0099
µg/L 1
SW-846 8151A
3/6/22
3/8/22 19:29
TG
2,4,5-T [1]
ND
0.098 0.024
µg/L 1
SW-846 8151A
3/6/22
3/8/22 19:29
TG
Dinoseb [1]
ND
0.25 0.046
µg/L 1
R-05 SW-846 8151A
3/6/22
3/8/22 19:29
TG
Surrogates
% Recovery
Recovery Limits
Flag/Qual
2,4-Dichlorophenylacetic acid [1]
104
30-150
3/8/22 19:29
2,4-Dichlorophenylacetic acid [2]
94.0
30-150
3/8/22 19:29
Ragia AS of 122
Page 7 of 16

Table of Contents
ton -test°
A Pace Analyb'cale LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Sample Extraction Data
Prep Method: SW-846 3510C Analytical Method: SW-846 8151A
Lab Number [Field ID] Batch Initial [mL] Final [mL] Date
22B1220-01 [3902-MW1R]
B302586
930
5.00
03/06/22
22131220-02[3902-MW2R]
B302586
990
5.00
03/06/22
22131220-03 [3902-MW3R]
B302586
1020
5.00
03/06/22
STUMT-61.10
'.•9 : • 0

ton -test°
A Pace Analyb'cale LaboWxy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
QUALITY CONTROL
Herbicides by GC/ECD - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch B302586 - SW-846 3510C
Blank (B302586-BLK1)
Prepared: 03/06/22 Analyzed: 03/08/22
2,4-D
ND
0.50
µg/L
2,4-D [2C]
ND
0.50
µg/L
2,4,5-TP (Silvex)
ND
0.050
µg/L
2,4,5-TP (Silvex) [2C]
ND
0.050
µg/L
2,4,5-T
ND
0.10
µg/L
2,4,5-T [2C]
ND
0.10
µg/L
Dinoseb
ND
0.25
µg/L
R-05
Dinoseb [2C]
ND
0.25
µg/L
R-05
Surrogate: 2,4-Dichlorophenylacetic acid
1.68
µg/L
2.00
83.9
30-150
Surrogate: 2,4-Dichlorophenylacetic acid
1.71
µg/L
2.00
85.3
30-150
[2C]
LCS (B302586-BSI)
Prepared: 03/06/22 Analyzed: 03/08/22
2,4-D
2.15
0.50
µg/L
2.50
85.9
40-140
2,4-D [2C]
2.43
0.50
µg/L
2.50
97.0
40-140
2,4,5-TP (Silvex)
0.225
0.050
µg/L
0.250
90.1
40-140
2,4,5-TP (Silvex) [2C]
0.231
0.050
µg/L
0.250
92.4
40-140
2,4,5-T
0.214
0.10
µg/L
0.250
85.6
40-140
2,4,5-T [2C]
0.228
0.10
µg/L
0.250
91.3
40-140
Dinoseb
0.512
0.25
µg/L
1.25
40.9
21.9-78.5
R-05
Dinoseb [2C]
0.558
0.25
µg/L
1.25
44.7
23.9-84.2
R-05
Surrogate: 2,4-Dichlorophenylacetic acid
1.69
µg/L
2.00
84.7
30-150
Surrogate: 2,4-Dichlorophenylacetic acid
1.75
µg/L
2.00
87.4
30-150
[2C]
LCS Dup (B302586-BSD1)
Prepared: 03/06/22 Analyzed: 03/09/22
2,4-D
2.27
0.50
µg/L
2.50
90.6
40-140
5.30
20
2,4-D [2C]
2.51
0.50
µg/L
2.50
100
40-140
3.51
20
2,4,5-TP (Silvex)
0.233
0.050
µg/L
0.250
93.3
40-140
3.51
20
2,4,5-TP (Silvex) [2C]
0.247
0.050
µg/L
0.250
99.0
40-140
6.91
20
2,4,5-T
0.219
0.10
µg/L
0.250
87.7
40-140
2.47
20
2,4,5-T [2C]
0.238
0.10
µg/L
0.250
95.2
40-140
4.19
20
Dinoseb
0.950
0.25
µg/L
1.25
76.0
21.9-78.5
60.0 *
20
R-05
Dinoseb [2C]
1.00
0.25
µg/L
1.25
80.3
23.9-84.2
57.0 *
20
R-05
Surrogate: 2,4-Dichlorophenylacetic acid
1.74
µg/L
2.00
86.9
30-150
Surrogate:2,4-Dichlorophenylacetic acid
1.83
µg/L
2.00
91.4
30-150
[2C]
Page 9 of 16

Table of Contents
ton -testa
A Pace Analy6cat' Labwa#ary
39 Spruce Street' East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
IDENTIFICATION SUMMARY
FOR SINGLE COMPONENT ANALYTES LCS
SW-846 8151A
Lab Sample ID: B302586-BS1 Date(s) Analyzed: 03/08/2022 03/08/2022
Instrument ID (1): ECD 8 Instrument ID (2): ECD 8
GC Column (1): ID: (mm) GC Column (2): ID: (mm)
ANALYTE
2,4,5-T
2,4,5-TP (Silvex)
2,4-D
Dinoseb
COL RT RT WINDOW CONCENTRATION %RPD
FROM TO
1 17 42-1 n nnn n nnn n 214
2
17.240
0.000
0.000
0.228
8.2
1
17.208
0.000
0.000
0.225
2 16.902 0.000 0.000 0.231 1 0.4
1 1-, AAA n nnn n nnn 9 1 r;
2
15.308
0.000
0.000
2.43
9.9
1
18.285
0.000
0.000
0.512
2 1 17.741 1 0.000 1 0.000 1 0.558 1 9.0
Page 10 of 16

ton -testa
A Pace Analy6cat' Labwa#ary
Table of Contents
Lab Sample ID:
Instrument ID (1)
GC Column (1):
ANALYTE
2,4,5-T
2,4,5-TP (Silvex)
2,4-D
Dinoseb
39 Spruce Street' East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
IDENTIFICATION SUMMARY
FOR SINGLE COMPONENT ANALYTES LCS Dup
SW-846 8151A
B302586-BSD1 Date(s) Analyzed: 03/09/2022 03/09/2022
ECD 8 Instrument ID (2): ECD 8
ID: (mm) GC Column (2): ID:
COL RT RT WINDOW CONCENTRATION %RPD
FROM TO
1 17 diQ n nnn n nnn n qiQ
2
17.237
0.000
0.000
0.238
7.9
1
17.206
0.000
0.000
0.233
2 16.902 0.000 0.000 0.247 7.1
1 1 5 QAR n nnn n nnn 997
2
15.308
0.000
0.000
2.51
8.7
1
18.280
0.000
0.000
0.950
2 1 17.737 1 0.000 1 0.000 1 1.00 1 5.1
(mm)
Page 11 of 16

ton -test°
A Pace Analyb'cale LaboWoiy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
FLAG/QUALIFIER SUMMARY
* QC result is outside of established limits.
j Wide recovery limits established for difficult compound.
$ Wide RPD limits established for difficult compound.
# Data exceeded client recommended or regulatory level
ND Not Detected
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
R-05 Laboratory fortified blank duplicate RPD is outside of control limits. Reduced precision is anticipated for any
reported value for this compound.
STTS!T•ES�iD➢

con -testa
A Pace Analyb'caie LaboWoiy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
CERTIFICATIONS
Certified Analyses included in this Report
Analyte Certifications
SW-846 8151A in Soil
2,4-D
2,4-D [2C]
2,4,5-TP (Silvex)
2,4,5-TP (Silvex) [2C]
2,4,5-T
2,4,5-T [2C]
Dinoseb
Dinoseb [2C]
SW-846 8151A in Water
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
NY,ME,NC,NH,VA,CT
2,4-D
ME,NCNH,CT,NY,VA
2,4-D [2C]
ME,NCNH,CT,NY,VA
2,4,5-TP (Silvex)
ME,NCNH,CT,NY,VA
2,4,5-TP (Silvex) [2C] ME,NC,NH,CT,NY,VA
2,4,5-T
ME,NC,NH,CT,NY,VA
2,4,5-T [2C]
ME,NC,NH,CT,NY,VA
Dinoseb
ME,NC,NH,CT,NYVA
Dinoseb [2C]
ME,NCNH,CT,NY,VA
Con -Test, a Pace Environmental Laboratory, operates under the following certifications and
accreditations:
Code
Description
Number
Expires
AIHA
AIHA-LAP, LLC - ISO17025:2017
100033
03/l/2024
MA
Massachusetts DEP
M-MA100
06/30/2022
CT
Connecticut Department of Publilc Health
PH-0165
12/31/2022
NY
New York State Department of Health
10899 NELAP
04/l/2022
NH-S
New Hampshire Environmental Lab
2516 NELAP
02/5/2023
RI
Rhode Island Department of Health
LA000373
12/30/2022
NC
North Carolina Div. of Water Quality
652
12/31/2022
NJ
New Jersey DEP
MA007 NELAP
06/30/2022
FL
Florida Department of Health
E871027 NELAP
06/30/2022
VT
Vermont Department of Health Lead Laboratory
LL720741
07/30/2022
ME
State of Maine
MA00100
06/9/2023
VA
Commonwealth of Virginia
460217
12/14/2022
NH-P
New Hampshire Environmental Lab
2557 NELAP
09/6/2022
VT-DW
Vermont Department of Health Drinking Water
VT-255716
06/12/2022
NC-DW
North Carolina Department of Health
25703
07/31/2022
PA
Commonwealth of Pennsylvania DEP
68-05812
06/30/2022
MI
Dept. of Env, Great Lakes, and Energy
9100
09/6/2022
srrss1101.10 -ir
'.•rm• •

Table of Contents
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Table of Contents
FedEx Tracking
Travel History
TW9 ZONE
Local Scan Time
Saturday, February 19,
2022
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Friday, February 18,
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987548492555
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Saturday, February 19, 2022 at 10:01 am
DELIVERED
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Page 15 of 16

Table of Contents
Have Not Confirmed Sample Container
Numbers With Lab Staff Before Relinquishing
tell
=
Over Samples
AiVALYi"1Ci�L LA13C34RA7-C>"V
Login Sample Receipt Checklist - (Rejection Criteria Listing- Using Acceptance Policy) Any False .......
Statement will be brought to the attention of the Client - Stake True or False
Client ; �k �-,L
Received By S-,.�_ _
Date Time
How were the samples In Cooler -T
No Cooler On Ice 1 No Ice
received? Direct from Sampling p 9
Ambient Melted Ice
Were samples within By Can #
.7 Actual Ten)p -J. �
Temperature? 2-6°C 1 By Blank #
Actual Temp. -
Was Custody Seal Intact? _ A;A
Were Samples Tampered with? A�
Was COC Relinquished ? i
Does Chain Agree With Samples?
Are there broken/leaking/loose caps on any samples? F
Is COC in inkf Legible?
Were samples received within holding time? T-
Did COC include all Client i
Analysis Sampler Name
pertinent Information? Project
A
ID's ; Collection DateslTimes y
re Sample labels need out and legible?
Are there Lab to Filters?
Are there Rushes?
Are there Short Holds?
Is there enough Volume?
Is these Headspace where applicable?
Proper Media/Containers Used?
Were trip blanks received?
Do all samples have the proper pH?
Who was notified?
Who was notified?
Who was noted?
MSfMSD? 4=
Is splitting samples required?
On COC? i
Base
Page 16 of 16 1

Table of Contents
ton -test°
A Pace Analyb'cale LaboWwy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
March 15, 2022
Angela Baioni
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Oxford Complaince/Butner
Client Job Number:
Project Number: 92588907
Laboratory Work Order Number: 22C0321
Enclosed are results of analyses for samples as received by the laboratory on March 4, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Raymond J. McCarthy
Project Manager

Table of Contents
Table of Contents
Sample Summary
Case Narrative
Sample Results
22CO321-01
22CO321-02
22CO321-03
22CO321-04
Sample Preparation Information
QC Data
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)
B303123
Flag/Qualifier Summary
Certifications
Chain of Custody/Sample Receipt
3
4
5
5
6
7
8
9
10
10
10
11
12
13
wEsr -Wltm morrir
inje, NZE910

Table of Contents
con -testa
A Pace Analyb'cale LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100 REPORT DATE: 3/15/2022
Huntersville, NC 28078 PURCHASE ORDER NUMBER:
ATTN: Angela Baioni
PROJECT NUMBER: 92588907
ANALYTICAL SUMMARY
WORK ORDER NUMBER: 22C0321
The results of analyses performed on the following samples submitted to CON -TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION: Oxford Complaince/Butner
FIELD SAMPLE # LAB ID: MATRIX SAMPLE DESCRIPTION TEST SUB LAB
3902-MWlR
22C0321-01
Water
SM21-232320B
3902-MW2R
22C0321-02
Water
SM21-23 2320B
3902-MW3R
22C0321-03
Water
SM21-23 2320B
3902-NEST
22C0321-04
Water
SM21-23 2320B
Page 3 of 15

ton -test°
A Pace Analyb'cale LaboWoiy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
Qualifications:
H-03
Sample received after recommended holding time was exceeded.
SM21-23 2320B
Analyte & Samples(s) Qualified:
Alkalinity
22C0321-01[3902-MW1R], 22C0321-02[3902-MW2R], 22C0321-03[3902-MW3R], 22C0321-04[3902-NEST]
PR-18
Headspace present in sample container.
Analyte & Samples(s) Qualified:
Alkalinity
22C0321-01[3902-MW1R], 22C0321-02[3902-MW2R], 22C0321-03[3902-MW3R], 22C0321-04[3902-NEST]
The results of analyses reported only relate to samples submitted to Con -Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
d�
Lisa A. Worthington
Technical Representative
STTS!T_�IS -
■U➢
- 0

Table of Contents
con -testa
A Pace AwWca& LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: Oxford ComplainceButner Sample Description: Work Order: 22C0321
Date Received: 3/4/2022
Field Sample #: 3902-MWlR Sampled: 2/16/2022 13:16
Sample ID: 22C0321-01
Sample Matrix: Water
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qua] Method Prepared Analyzed Analyst
Alkalinity 35 1.0 0.65 mg/L 1 H-03, PR-18 SM21-23 2320B 3/14/22 3/14/22 13:11 IS
Page 5 of 15

Table of Contents
con -testa
A Pace AwWca& LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: Oxford ComplainceButner Sample Description: Work Order: 22C0321
Date Received: 3/4/2022
Field Sample #: 3902-MW2R Sampled: 2/16/2022 13:44
Sample ID: 22C0321-02
Samule Matrix: Water
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qua] Method Prepared Analyzed Analyst
Alkalinity 820 1.0 0.65 mg/L 1 H-03, PR-18 SM21-23 2320B 3/14/22 3/14/22 13:28 IS
Page 6 of 15

Table of Contents
con -testa
A Pace AwWca& LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: Oxford ComplainceButner Sample Description: Work Order: 22C0321
Date Received: 3/4/2022
Field Sample #: 3902-MW3R Sampled: 2/16/2022 10:00
Sample ID: 22C0321-03
Sample Matrix: Water
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qua] Method Prepared Analyzed Analyst
Alkalinity 630 1.0 0.65 mg/L 1 H-03, PR-18 SM21-23 2320B 3/14/22 3/14/22 13:41 IS
Page 7 of 15

Table of Contents
con -testa
A Pace AwWca& LaboWoiy
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Project Location: Oxford ComplainceButner Sample Description: Work Order: 22C0321
Date Received: 3/4/2022
Field Sample #: 3902-NES1 Sampled: 2/16/2022 14:55
Sample ID: 22C0321-04
Sample Matrix: Water
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total)
Date Date/Time
Analyte Results RL DL Units Dilution Flag/Qua] Method Prepared Analyzed Analyst
Alkalinity 5.0 1.0 0.65 mg/L 1 H-03, PR-18 SM21-23 2320B 3/14/22 3/14/22 13:53 IS
Page 8 of 15

ton -test°
A Pace Analyb'cale LaboWoiy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
Sample Extraction Data
SM21-23 2320B
Lab Number [Field ID] Batch Initial [mL] Final [mL] Date
22CO321-01[3902-MW1R]
B303123
100
100
03/14/22
22CO321-02 [3902-MW2R]
B303123
100
100
03/14/22
22CO321-03 [3902-MW3R]
B303123
100
100
03/14/22
22CO321-04[3902-NES1]
B303123
100
100
03/14/22
Page 9 of 15

ton -test°
A Pace Analyb'cale LaboWxy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
QUALITY CONTROL
Conventional Chemistry Parameters by EPA/APHA/SW-846 Methods (Total) - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch B303123 - SM21-23 2320B
Blank (B303123-BLK1) Prepared & Analyzed: 03/14/22
Alkalinity ND 1.0 mg/L
LCS (B303123-BS1) Prepared & Analyzed: 03/14/22
Alkalinity 30 1.0 mg/L 32.5 92.3 90-110
LCS Dup (B303123-BSD1) Prepared & Analyzed: 03/14/22
Alkalinity 30 1.0 mg/L 32.5 92.3 90-110 0.00 5.47
Page 10 of 15

ton -test°
A Pace Analyb'cale LaboWoiy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
FLAG/QUALIFIER SUMMARY
* QC result is outside of established limits.
j Wide recovery limits established for difficult compound.
$ Wide RPD limits established for difficult compound.
# Data exceeded client recommended or regulatory level
ND Not Detected
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
H-03 Sample received after recommended holding time was exceeded.
PR-18 Headspace present in sample container.
STTSiHUMNS -➢
.p Iz�M 0

con -testa
A Pace Analyb'cale LaboWoiy
Table of Contents
39 Spruce Street* East Longmeadow, MA 01028 *FAX [phone] "TEL. [phone]
CERTIFICATIONS
Certified Analyses included in this Report
Analyte Certifications
SM21-23 2320B in Water
Alkalinity CT,MA,NH,NY,RI,NC,ME,VA
Con -Test, a Pace Environmental Laboratory, operates under the following certifications and accreditation:
Code Description Number
Expires
AIHA
AIHA-LAP, LLC - ISO17025:2017
100033
03/l/2024
MA
Massachusetts DEP
M-MA100
06/30/2022
CT
Connecticut Department of Publilc Health
PH-0165
12/31/2022
NY
New York State Department of Health
10899 NELAP
04/l/2022
NH-S
New Hampshire Environmental Lab
2516 NELAP
02/5/2023
RI
Rhode Island Department of Health
LA000373
12/30/2022
NC
North Carolina Div. of Water Quality
652
12/31/2022
NJ
New Jersey DEP
MA007 NELAP
06/30/2022
FL
Florida Department of Health
E871027 NELAP
06/30/2022
VT
Vermont Department of Health Lead Laboratory
LL720741
07/30/2022
ME
State of Maine
MA00100
06/9/2023
VA
Commonwealth of Virginia
460217
12/14/2022
NH-P
New Hampshire Environmental Lab
2557 NELAP
09/6/2022
VT-DW
Vermont Department of Health Drinking Water
VT-255716
06/12/2022
NC-DW
North Carolina Department of Health
25703
07/31/2022
PA
Commonwealth of Pennsylvania DEP
68-05812
06/30/2022
MI
Dept. of Env, Great Lakes, and Energy
9100
09/6/2022
srrsrST-amaIplr
'.•'U VX@l

Table of Contents
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FedEx® Tracking
346528651536 LJ
ADD NICKNAME
❑elivered
Friday, March 4, 2022 at 9:01 am
DELIVERED
Signed for by: R.REBECCA
GET STATUS UPDATES
OBTAIN PROOF OF DELIVERY
FROM TO
ASHEVILLF, NC US EAST LONGMEADOW MA US
MANAGE DELfVEPY
STTSiFulanamp
•RM C we]

Table of Contents
I Have Not Confirmed Sample Container
Numbers With Lab Staff Before Relinquishing
Over Samples
-------------
Doc# VY-: Rea" a 2017::
........................................
Login Sample Receipt Checklist - (Rejec#ion Criteria Listing - Using Acceptance Policy) Any False
Statement will be brought to the attention of the Client - State True or False
Client '
Received By
Date
7 Time
How were the samples In Cooler
No Cooler On Ice No Ice
_ T
received? Direct from Sampling^ Ambient Melted Ice
By Gun # 1 Actual Tern - C
Were samples within
Temperature? 2-6'C E
By Blank # Actual Temp -
Was Custody Seal Intact?
Were Samples Tampered with? ;
Was COC Relinquished ?
Does Chain Agree With Samples? l'
Are there broke n/leakinglloose caps on any samples? EL
Is COC in ink/ Legible? 7'
Were samples received within holding time?
Did COC include all Client
G Analysis Sampler Name
pertinent Iriformation? Project
�7 10's Collection Dates/Times�
Are Sample labels filled out and legible? :Z
Are there Lab to Filters?
Who was notified?
Are there Rushes?
Who was notified?
Are there Short Holds?
(~: Who was notified?
Is there enough Volume?
Is there HeadsPace . where applicable
_
Proper Media/Containers Used?
Is splitting samples r0uiredl
Were trip blanks receiver!?
� On COC?
Do all samples have the proper pH?
AA A Acid Base
Un -
1 Liter Amb.
1 Liter Plastic
16 oz Amb.
HCL-
500 mL Amb.
500 mL Plastic
8oz Arab/Clear
Meoh-
250 mL Amb.
250 mL Plastic
4oz Amb/Clear
Bisulfate-
Flashpoint
Col./Bacteria
2oz Amb/Clear
D€-
Other Glass
Other Plastic
Encore
Thiosulfate-
SOC Kit
Plastic Bag
Frozen:
Sulfuric-
I
I Perchlorate
Ziglock
Un -
f Liter Arab.
1 Liter Plastic
16 oz Amb.
HCL-
500 mL Amb.
500 mL Plastic
8oz Amb/Clear
Meoh-
250 mL Amb.
250 mL Plastic
4oz Amb/Clear
Bisulfate-
Coi.leacteria
Flashpoint
2oz Amb/Clear
DI-
Other Plastic
Other Glass
Encore
Thlosulfate-
SOC Kit
Plastic Bag
Frozen:
Sulfuric-
I
I Perchlorate
Ziplock
Comments,
Page 15 of 15

(� aceAnalytical "-
LELAP CERTIFICATE NUMBER: 01955
DOD-ELAP ACCREDITATION NUMBER: 74960
ANALYTICAL RESULTS
•:I
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 03/03/2022
Report Y 222021908
�1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III
Project 92588907 Oxford Compliance
Samples Collected 2/16/22
Deliver To Additional Recipients
Angela Baioni Vivian Sipe, Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
9800 Kincey Ave
Suite 100
Huntersville, NC 28078
[phone]
1*6.Mlk
PJLA
1XMINg
DOD EU1P
ZVV
so
7025
F%ccek
Papa 110 of 192
Pace Gulf Coast Report#: 222021908 Page 1 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub -Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re -analysis
CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non -compliant QC Result (See Q Flag Application Report)
" Indicates a non -compliant or not applicable QC recovery or RPD — see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk -based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis — when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results
contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.
Authorized Signature
Pace Gulf Coast Report 222021908
Pages 111 of 1
Pace Gulf Coast Report#: 222021908 Page 2 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
Certifications
Certification
Certification Number
DOD ELAP
74960
Alabama
01955
Arkansas
88-0655
Colorado
01955
Delaware
01955
Florida
E87854
Georgia
01955
Hawaii
01955
Idaho
01955
Illinois
200048
Indiana
01955
Kansas
E-10354
Kentucky
95
Louisiana
01955
Maryland
01955
Massachusetts
01955
Michigan
01955
Mississippi
01955
Missouri
01955
Montana
N/A
Nebraska
01955
New Mexico
01955
North Carolina
618
North Dakota
R-195
Oklahoma
9403
South Carolina
73006001
South Dakota
01955
Tennessee
01955
Texas
T104704178
Vermont
01955
Virginia
460215
Washington
C929
USDA Soil Permit
P330-16-00234
Pages 112 of 1
Pace Gulf Coast Report#: 222021908 Page 3 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
Case Narrative
Client: Pace Analytical Services Report: 222021908
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
No anomalies were found for the analyzed sample(s).
Pages 113 of 1
Pace Gulf Coast Report#: 222021908 Page 4 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance
Report Date:
03/03/2022
Sample Summary
Lab ID
Client ID
Matrix
Collect Date
Receive Date
22202190801
3902-MW 1 R
Water
2/16/22 13:16
2/19/22 11:00
22202190802
3902-MW2R
Water
2/16/2213:44
2/19/22 11:00
22202190803
3902-MW3R
Water
2/16/2210:00
2/19/22 11:00
22202190804
3902-NES1
Water
2/16/2214:55
2/19/22 11:00
22202190805
3902-MW1R
Bubble Strip
2/16/22 15:54
2/19/22 11:00
22202190806
3902-MW2R
Bubble Strip
2/16/22 14:57
2/19/22 11:00
22202190807
3902-MW3R
Bubble Strip
2/16/22 12:04
2/19/22 11:00
22202190808
3902-NES1
Bubble Strip
2/16/22 15:30
2/19/22 11:00
Pages 114 of 1 ??
Pace Gulf Coast Report#: 222021908 Page 5 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance
Report Date: 03/03/2022
Detect Summary
Results and Detection Limits are adjusted for dilution and moisture when applicable
AM23G
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22202190801
3902-MW 1 R
Formic Acid
mg/L
1.2
1
NA
22202190801
3902-MW 1 R
Lactic Acid
mg/L
0.23J
1
NA
22202190802
3902-MW2R
Formic Acid
mg/L
42
10
NA
22202190802
3902-MW2R
Hexanoic Acid
mg/L
0.58J
10
NA
22202190803
3902-MW3R
Formic Acid
mg/L
9.2
10
NA
22202190804
3902-NES1
Acetic Acid
mg/L
0.13J
1
NA
22202190804
3902-NES1
Formic Acid
mg/L
4.0
1
NA
AM20GAX
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22202190805
3902-MW1R
Hydrogen
nM
1.2J
1
NA
22202190806
3902-MW2R
Hydrogen
nM
1.3J
1
NA
22202190807
3902-MW3R
Hydrogen
nM
3.2
1
NA
22202190808
3902-NES1
Hydrogen
nM
2.4
1
NA
Pala 11.ri of 1??
Pace Gulf Coast Report#: 222021908 Page 6 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
Sample Results
3902-MW1 R Collect Date 02/16/2022 13:16 Lab ID 22202190801
Receive Date 02/19/2022 11:00 Matrix Water
13G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 03/02/2212:00 734593 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.12U
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
1.2
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.058U
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.23J
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
3902-MW2R Collect Date 02/16/2022 13:44 Lab ID 22202190802
Receive Date 02/19/2022 11:00 Matrix Water
AM23G *Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 03/02/2212:24 734593 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
1.2U
1.2
5.0
mg/L
107-92-6
Butyric Acid
0.58U
0.58
5.0
mg/L
64-18-6
Formic Acid
42
0.55
5.0
mg/L
142-62-1
Hexanoic Acid
0.58J
0.58
5.0
mg/L
646-07-1
i-Hexanoic Acid
0.56U
0.56
5.0
mg/L
503-74-2
i-Pentanoic Acid
0.61 U
0.61
5.0
mg/L
50-21-5
Lactic Acid
0.53U
0.53
5.0
mg/L
109-52-4
Pentanoic Acid
0.56U
0.56
5.0
mg/L
79-09-4
Propionic Acid
0.53U
0.53
5.0
mg/L
127-17-3
Pyruvic Acid
0.60U
0.60
5.0
mg/L
3902-MW3R Collect Date 02/16/2022 10:00 Lab ID 22202190803
Receive Date 02/19/2022 11:00 Matrix Water
AM23G *Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 03/02/2212:48 734593 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
1.2U
1.2
5.0
mg/L
107-92-6
Butyric Acid
0.58U
0.58
5.0
mg/L
64-18-6
Formic Acid
9.2
0.55
5.0
mg/L
142-62-1
Hexanoic Acid
0.58U
0.58
5.0
mg/L
646-07-1
i-Hexanoic Acid
0.56U
0.56
5.0
mg/L
Pages 116 of 1
Pace Gulf Coast Report#: 222021908 Page 7 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
Sample Results
3902-MW3R Collect Date 02/16/2022 10:00 Lab ID 22202190803
Receive Date 02/19/2022 11:00 Matrix Water
AM23G (Continued) "Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 10 03/02/2212:48 734593 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
503-74-2
i-Pentanoic Acid
0.61 U
0.61
5.0
mg/L
50-21-5
Lactic Acid
0.53U
0.53
5.0
mg/L
109-52-4
Pentanoic Acid
0.56U
0.56
5.0
mg/L
79-09-4
Propionic Acid
0.53U
0.53
5.0
mg/L
127-17-3
Pyruvic Acid
0.60U
0.60
5.0
mg/L
3902-NES1 Collect Date 02/16/2022 14:55 Lab ID 22202190804
Receive Date 02/19/2022 11:00 Matrix Water
3G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 03/02/2213:45 734593 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
0.13J
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
64-18-6
Formic Acid
4.0
0.055
0.50
mg/L
142-62-1
Hexanoic Acid
0.058U
0.058
0.50
mg/L
646-07-1
i-Hexanoic Acid
0.056U
0.056
0.50
mg/L
503-74-2
i-Pentanoic Acid
0.061 U
0.061
0.50
mg/L
50-21-5
Lactic Acid
0.053U
0.053
0.50
mg/L
109-52-4
Pentanoic Acid
0.056U
0.056
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
3902-MW1 R Collect Date 02/16/2022 15:54 Lab ID 22202190805
Receive Date 02/19/2022 11:00 Matrix Bubble Strip
OGAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 03/02/2217:29 735123 CWB NA
CAS# Parameter
1333-74-0 Hydrogen
Result DL LOQ
1.2J 0.49 1.9
Units
nM
Pages 117 of 1
Pace Gulf Coast Report#: 222021908 Page 8 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
Sample Results
3902-MW2R Collect Date 02/16/2022 14:57 Lab ID 22202190806
Receive Date 02/19/2022 11:00 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 03/02/2217:41 735123 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
1.3J
0.49
1.9
nM
3902-MW3R Collect Date 02/16/2022 12:04 Lab ID 22202190807
Receive Date 02/19/2022 11:00 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 03/02/2217:53 735123 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
3.2
0.49
1.9
nM
3902-NES1 Collect Date 02/16/2022 15:30 Lab ID 22202190808
Receive Date 02/19/2022 11:00 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 03/02/2218:05 735123 CWB NA
CAS# Parameter
1333-74-0 Hydrogen
Result
DL
LOQ
Units
2.4
0.49
1.9
nM
Pages 118 of 1
Pace Gulf Coast Report#: 222021908 Page 9 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
General Chemistry QC Summary
Analytical Batch Client ID
MB734593
LCS734593
LCSD734593
734593 Lab ID
2311373
2311374
2311375
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
03/01/22 14:40
03/01/22 14:19
03/01/22 18:53
Matrix
Water
Water
Water
AM23G
Units
mg/L
Spike
Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Acetic Acid
64-19-7
0.12U
0.12
2.0
1.8
91
70 - 130
2.0
1.8
93
2
20
Butyric Acid
107-92-6
0.058U
0.058
2.0
1.8
92
70 - 130
2.0
1.8
90
3
20
Formic Acid
64-18-6
0.055U
0.055
2.0
1.7
84
70 - 130
2.0
1.6
82
3
20
Hexanoic Acid
142-62-1
0.058U
0.058
2.0
1.7
85
70 - 130
2.0
1.8
91
7
20
i-Hexanoic Acid
646-07-1
0.056U
0.056
2.0
2.5
125
70 - 130
2.0
2.5
125
0
20
i-Pentanoic Acid
503-74-2
0.061 U
0.061
2.0
2.0
98
70 - 130
2.0
1.9
95
4
20
Lactic Acid
50-21-5
0.053U
0.053
2.0
2.6
129
70 - 130
2.0
2.4
122
5
20
Pentanoic Acid
109-52-4
0.056U
0.056
2.0
2.0
103
70 - 130
2.0
1.9
94
9
20
Propionic Acid
79-09-4
0.053U
0.053
2.0
1.8
92
70 - 130
2.0
1.8
89
3
20
Pyruvic Acid
127-17-3
0.060U
0.060
2.0
1.8
92
70 - 130
2.0
1.7
88
5
20
Pages 11 q of 1
Pace Gulf Coast Report#: 222021908 Page 10 of 13

Report#: 222021908
Project ID: 92588907 Oxford Compliance Report Date: 03/03/2022
General Chromatography QC Summary
Analytical Batch Client ID
MB735123
LCS735123
LCSD735123
735123 Lab ID
2314316
2314317
2314318
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
03/02/22 17:04
03/02/22 16:40
03/02/22 16:52
Matrix
Bubble Strip
Bubble Strip
Bubble Strip
AM20GAX
Units
nM
Spike
Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Hydrogen 1333-74-0
0.49U
1 0.491
121
9.01
76
1 70 - 130
1 121
9.7
182
1 8
1 20
Pages 19f1 of 199
Pace Gulf Coast Report#: 222021908 Page 11 of 13

Internal Transfer Chain of Custody
�aceAnalytical `
�Iljl1l����I�IIIII11��II�Ij`��II��I�`�If IIIIIII
J j` II 4 III I I` I
❑ Samples Pre -Logged into eCOC.
State Of Origin:
Gert, Deeded: L Yes ❑ No www.prr�la6c.com
f
Workorder: 925a8907 Wnrkorder Name: OXFORD COMPLIANCEIBUTNER C011 Olyner Received Date: 211612022 Results Requested By: 3/212022
Report To
Subcontract To
Requested Analysis
Angela Baioni
Pace Gulf Coast
Pace Analytical Charlotte
7979 Innovation Park Dr
9800 Kincey Ave. Suite 100
Baton Rouge, LA 70820
Huntersville, NC 28078
Phone [phone]
Phone [phone]
}
s �
v �
s
Preserved Containers
a
ry
Sample
Collect
Matrix
LAB USE ONLY
Item Sample 10 Type
Ratelrime Lab ID
1 39o7-MW1R PS
21161202213:15 92588907008 Water
1 x
2 39o2-10W2R PS
21161202213:44 92586907009 Water
1 X
3 kQ2.MW3R PS
2n o;202210:00 92588907010 Water
1ffr�
d 9w-NES1 PS
21161202214:55 92588907011 Water
1
b 39WA WIR P5
21161202215:54 92588907012 Water
t
6 39e2-MW2R PS
21161202214:57 92888907013 Water
1
+
7 39u2-MW3R PS
2/ 612022 12,04 92588907014 Water
1 7
8 3902-NES1 P5
21IeW02215:30 92588907015 Water
iComments
Transfers Released By
0aterrlmaecelved By
r'�1�
2
s
Cooler Temperature on Receipt
"GI Custody Seal Y or N
Received on Ice Y or N Sant les Intact Y or N
"In order to maintain client confidentiality,
location/name of the sampling site, sampler's name and signature may not be provided an this COG document -
This chain of custody is considered complete as is since this information is available in the owner laboratory,
Client ID: 4367 - Pace Analytical Services
SI]G: 222021908
III 1111111111111111111111111
FP PM: RWe
Friday, February 18, 20224:33:21 PM
Papa 121 of 1,22
Pace Gulf Coast Report#: 222021908 Page 12 of 13

.�acetuw.'itrcai SAMPLE RECEIVING CHECKLIST IIIIIIIIIIIII
SAMPLE DELIVERY GROUP
222021908
CHECKLIST
YES
NO
Client PM RIUe
Transport Method
Samples received with proper thermal preservation?
*❑
❑
4367 - Pace Analytical Services
F®DC
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including samplelDs, collect times, and sampler)?
*❑
*❑
❑
❑
Profile Number
Received By
282148
Henderson, Jacob R
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
0
0
❑
❑
Line Item(s)
Receive Date(s)
10 - IVY, 002, VFA
02/19/22
11 - Hydrogen
Preservative added to any containers?
❑
I❑
If received, was headspace for VOC water containers < 6mm?
*❑
❑
Samples collected in containers provided by Pace Gulf Coast?
0
❑
COOLERS
DISCREPANCIES
LAB PRESERVATIONS
Airbill Thermometer ID: E34
Temp °C
None
None
9875 4849 2566
2.8
NOTES
Revision 1.6
Pace Gulf Coast Report#: 222021908
Page 1 of 1
Papa 122 of 1?2
Page 13 of 13

Appendix C
Summary of Historical Groundwater Elevations
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix C
Summary of Historical Groundwater Elevations
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Groundwater Elevations (ft AMSL)
Date
Background
Downgradient
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
8/21 /99
418.68
329.13
328.06
330.50
330.83
352.10
N 1
11/16/99
419.75
325.38
324.51
331.53
334.33
352.97
NI
5/10/00
424.53
329.60
328.83
334.15
334.49
355.72
NI
10/26/00
419.21
329.26
328.15
331.33
330.94
352.78
N 1
4/18/01
418.76
329.42
328.63
333.57
334.36
354.22
NI
10/26/01
412.53
329.04
327.94
330.57
330.23
350.92
N 1
6/13/02
413.70
328.38
327.41
330.21
330.29
351.04
NI
11/19/02
413.40
329.25
328.35
331.57
337.17
350.94
NI
06/27/03
423.61
329.57
328.93
334.24
333.99
355.21
N 1
12/29/03
420.23
329.70
329.11
334.49
334.78
354.92
N 1
06/30/04
418.81
329.38
328.48
332.26
331.39
353.10
N 1
12/28/04
418.02
329.50
328.91
333.45
334.14
355.14
N 1
06/29/05
418.81
329.10
329.26
331.62
330.90
352.76
N 1
12/29/05
413.38
329.29
328.71
332.78
334.27
351.52
N 1
06/27/06
414.75
329.17
328.40
332.18
333.56
353.43
N 1
12/28/06
415.54
329.40
328.86
333.57
335.24
354.02
N 1
07/12/07
438.64
328.69
327.97
331.31
330.52
352.30
NI
12/18/07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
07/08/08
414.52
329.20
326.00
331.46
330.85
351.03
N M
12/17/08
412.79
329.39
328.84
333.15
335.03
350.82
NM
07/09/09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
12/16/29
418.11
329.55
329.09
334.57
336.94
352.87
NM
06/24/10
422.42
329.41
328.77
333.65
333.15
353.62
NM
12/13/10
415.96
329.49
328.85
332.81
330.34
350.08
NM
06/20/11
416.00
328.95
328.18
336.77
331.38
351.83
NM
12/05/11
412.94
329.31
328.65
332.32
329.51
349.87
NM
06/12/11
414.56
329.10
328.35
332.52
331.33
351.75
312.5
12/12/12
412.83
329.19
328.36
331.67
330.35
349.48
NM
05/01/13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
08/05/13
417.97
329.02
328.41
333.32
332.83
353.01
NM
02/24/14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
08/11/14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
03/10/15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
08/17/15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
02/17/16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
08/09/16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
02/13/17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
08/22/17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
02/05/18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
08/14/18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
02/04/19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
08/06/19
420.05
329.35
328.37
332.98
329.73
351.46
310.34
02/12/20
417.43
329.75
329.30
335.65
336.08
352.38
317.67
08/27/20
418.84
329.18
328.55
333.42
330.48
351.34
310.90
02/11/21
421.71
329.93
329.62
336.59
336.17
355.52
318.10
08/19/21
420.22
329.50
328.71
333.67
330.13
351.84
310.29
02/15/22
415.99
329.57
329.00
334.15
330.53
350.12
312.55
Notes:
Groundwater elevations from 1999 through 2021 obtained from LaBella Water Quality Monitoring Report
TOC = Top of casing; ft AMSL = ft above mean sea level
NM = water level not measured; NI = well not yet installed
Appendix C (Page 1 of 1)
https://harthick.shampoint.wm/sites/MasterF!Ies-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/ Hart &Hickman PC
Historic Tables

Appendix D
Summary of Historical Constituents in Groundwater
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
1,1-Dichloroethane
12/01/97
---
5
ND
ND
1
ND
ND
ND
---
---
05/20/98
---
5
ND
ND
ND
ND
ND
ND
---
---
NC2L1�1=6µg/L
11/19/98
---
5
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
5
ND
ND
ND
ND
ND
ND
---
---
11/16/99
--
5
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
5
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
5
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
5
ND
ND
ND
ND
ND
ND
---
---
10/27/01
--
5
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
5
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/30/03
--
5
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
--
5
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
5
ND
ND
0.36
0.52
ND
ND
---
ND
12/19/07
---
5
ND
ND
ND
0.57
ND
ND
ND
ND
07/08/08
---
5
ND
ND
ND
0.6
ND
ND
---
ND
12/17/08
0.32
5
ND
ND
ND
0.51
ND
ND
---
ND
07/09/09
0.32
5
ND
ND
ND
0.84
ND
ND
ND
ND
12/16/09
0.32
5
ND
ND
ND
0.73
ND
ND
---
ND
06/24/10
0.32
5
ND
ND
ND
0.53
ND
ND
---
ND
12/13/10
0.32
5
ND
ND
ND
0.6
ND
ND
---
ND
06/20/11
0.32
5
ND
ND
ND
0.63
ND
ND
---
ND
12/05/11
0.32
5
ND
ND
ND
0.67
ND
ND
ND
ND
06/11/12
0.32
5
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
0.32
5
ND
ND
ND
1.61
ND
ND
ND
ND
05/01/13
0.32
5
ND
ND
ND
1.62
ND
ND
---
ND
05/08/13
0.32
5
ND
ND
ND
0.53
ND
ND
ND
ND
02/24/14
0.32
5
ND
ND
ND
0.5
ND
ND
ND
ND
08/12/14
0.32
5
ND
ND
ND
0.47
ND
ND
ND
ND
03/10/15
0.32
5
ND
ND
ND
0.5
ND
ND
---
ND
08/18/15
0.32
5
ND
ND
ND
0.49
ND
ND
ND
ND
02/16/16
0.32
5
ND
ND
ND
0.45
ND
ND
---
ND
08/09/16
0.32
5
ND
ND
ND
0.34
ND
ND
---
ND
02/13/17
0.32
5
ND
ND
ND
0.33
ND
ND
---
ND
08/22/17
0.32
5
ND
ND
ND
1.37
ND
ND
---
ND
02/05/18
0.32
5
ND
ND
ND
1.38
ND
ND
---
ND
08/13/18
0.32
5
ND
ND
ND
0.37
ND
ND
---
ND
02/04/19
0.27
1
ND
ND
ND
0.36
ND
ND
---
ND
08/07/19
0.27
1
ND
ND
ND
ND
ND
ND
-
ND
02/12/20
0.27
1
ND
ND
ND
0.33
ND
ND
---
ND
08/27/20
0.27
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.27
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.37
1
ND
ND
ND
ND
ND
ND
---
ND
1,2-Dichlorobenzene
12/01/97
---
5
ND
3
2
1
ND
ND
---
---
05/20/98
---
5
ND
ND
ND
ND
ND
ND
---
---
NC2L = 20 µg/L
11/19/98
---
5
ND
2.4
2.3
ND
ND
ND
07/21/99
---
5
ND
ND
ND
ND
ND
ND
---
---
11/16/99
--
5
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
5
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
5
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
5
ND
ND
ND
ND
ND
ND
---
---
10/27/01
--
5
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
5
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
5
ND
ND
ND
ND
ND
ND
---
---
12/30/03
--
5
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
5
ND
1.5
2.3
ND
ND
ND
---
ND
07/12/07
---
5
ND
1.4
1.7
0.31
ND
ND
---
ND
12/19/07
---
5
ND
1.6
2
0.37
ND
ND
ND
ND
07/08/08
---
5
ND
1.6
2
0.39
ND
ND
---
ND
12/17/08
0.3
5
ND
1.4
1.9
ND
ND
ND
---
ND
07/09/09
0.3
5
ND
1.6
2
0.36
ND
ND
ND
ND
12/16/09
0.3
5
ND
0.96
2
0.33
ND
ND
---
ND
06/24/10
0.3
5
ND
1.9
1.7
0.31
ND
ND
---
ND
12/13/10
0.3
5
ND
1.9
1.9
0.43
ND
ND
---
ND
06/20/11
0.3
5
ND
1.5
1.7
0.37
ND
ND
---
ND
12/05/11
0.3
5
ND
1.3
1.6
ND
ND
ND
---
ND
06/11/12
0.3
5
ND
1
1.5
ND
ND
ND
ND
ND
12/12/12
0.3
5
ND
1.3
1.7
ND
ND
ND
---
ND
05/01/13
0.3
5
ND
1.2
1.6
ND
ND
ND
ND
ND
08/05/13
0.3
5
ND
1.2
1.6
0.3
ND
ND
---
ND
02/24/14
0.3
5
ND
1.4
0.64
ND
ND
ND
ND
ND
08/12/14
0.3
5
ND
1.2
1.5
ND
ND
ND
ND
ND
03/10/15
0.3
5
ND
1.1
1.1
ND
ND
ND
ND
ND
08/18/15
0.3
5
ND
0.88
1.3
ND
ND
ND
---
ND
02/16/16
0.3
5
ND
1.1
1.4
ND
ND
ND
ND
ND
08/09/16
0.3
5
ND
1.2
1.4
ND
ND
ND
---
ND
02/13/17
0.3
5
ND
1.2
1.4
ND
ND
ND
---
ND
08/22/17
0.3
5
ND
1.2
1.5
ND
ND
ND
---
ND
02/05/18
0.3
5
ND
1
1.4
ND
ND
ND
---
ND
08/13/18
0.3
5
ND
1.2
1.6
ND
ND
ND
---
ND
02/04/19
0.29
1
ND
1
ND
ND
ND
ND
---
ND
08/07/19
0.29
1
ND
0.62
1.2
ND
ND
ND
---
ND
02/12/20
0.29
1
ND
0.82
0.71
ND
ND
ND
---
ND
08/27/20
0.29
1
ND
1.2
1.3
ND
ND
ND
---
ND
02/11/21
0.29
1
ND
1.1
0.83
ND
ND
ND
---
ND
08/19/21
0.29
1
ND
1.1
1.1
ND
ND
ND
ND
ND
02/16/22
0.34
1
ND
0.61
ND
ND
ND
ND
---
ND
Appendix (Page 1 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h ebD--tslHPA�v to ,Proj,-G-,tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
1,2-Dichloroethane
12/17/08
0.12
1
ND
ND
0.15
ND
ND
ND
---
ND
07/09/09
0.12
1
ND
ND
ND
ND
ND
ND
ND
1.19
NC2LIll=0.4µg/L
12/16/09
0.12
1
ND
ND
0.14
ND
ND
ND
---
ND
06/24/10
0.12
1
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.12
1
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.12
1
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.12
1
ND
ND
ND
ND
0.18
ND
---
ND
06/11/12
0.12
1
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.12
1
ND
ND
ND
ND
-0.2
ND
---
ND
05/01/13
0.12
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.12
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.12
1
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.12
1
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.12
1
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.24
1
ND
ND
0.33
0.29
0.36
ND
---
---
02/16/16
0.24
1
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.24
1
0.25
ND
0.37
ND
0.43
ND
---
ND
08/13/18
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.34
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.34
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.34
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.34
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.34
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.32
1
ND
ND
ND
ND
ND
ND
--
ND
1,4-Dichlorobenzene
09/08/94
---
5
ND
ND
5
ND
ND
ND
---
---
12/01/94
---
5
ND
ND
5
ND
ND
ND
---
---
NC2LIll = 6 µg/L
02/09/95
---
5
ND
8
6
ND
ND
ND
---
---
03/02/95
---
5
ND
7
6
ND
ND
ND
---
---
11/15/95
---
5
ND
7
6
ND
ND
ND
---
---
05/28/96
--
5
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
5
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
5
ND
7.6
6.2
ND
ND
ND
---
---
12/01/97
---
5
ND
6
5
4
ND
ND
---
---
05/20/98
--
5
ND
7.6
ND
ND
ND
ND
---
---
11/19/98
---
5
ND
3.7
2.8
ND
ND
ND
---
---
07/21/99
---
5
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
5
ND
ND
ND
ND
ND
ND
---
---
05/10/00
--
5
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
5
ND
5
6
ND
ND
ND
---
---
04/18/01
---
5
ND
ND
5
6
ND
ND
---
---
10/27/01
---
5
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
5
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
5
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
--
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
3
ND
3
3.3
ND
ND
ND
---
ND
02/23/07
---
3
--
3.2
3.3
---
---
---
---
ND
07/12/07
---
1
ND
3.3
2.9
0.31
ND
ND
---
ND
12/19/07
---
1
ND
3
2.7
ND
ND
ND
ND
ND
07/08/08
---
1
ND
3
2.4
ND
ND
ND
---
ND
12/17/08
0.33
1
ND
2.9
2.5
ND
ND
ND
---
ND
07/09/09
0.33
1
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
0.33
1
ND
2.8
2.2
ND
ND
ND
--
ND
06/24/10
0.33
1
ND
1.6
ND
ND
ND
ND
---
ND
12/13/10
0.33
1
ND
3.1
1.9
ND
ND
ND
---
ND
06/20/11
0.33
1
ND
2.7
1.6
ND
ND
ND
---
ND
12/05/11
0.33
1
ND
2.2
1.4
ND
ND
ND
---
ND
06/11/12
0.33
1
ND
1.8
1.4
ND
ND
ND
ND
ND
12/12/12
0.33
1
ND
2.4
1.3
ND
ND
ND
---
ND
05/01/13
0.33
1
ND
2.1
1.2
ND
ND
ND
ND
ND
08/05/13
0.33
1
ND
2
1.3
ND
ND
ND
---
ND
02/24/14
0.33
1
ND
2.2
1.8
ND
ND
ND
ND
ND
08/12/14
0.33
1
ND
2.4
1.3
ND
ND
ND
ND
ND
03/10/15
0.33
1
ND
2.2
1.1
ND
ND
ND
ND
ND
08/18/15
0.33
1
ND
1.5
1.1
ND
ND
ND
---
ND
02/16/16
0.33
1
ND
2
1
ND
ND
ND
ND
ND
08/09/16
0.33
1
ND
1.9
1
ND
ND
ND
---
ND
02/13/17
0.33
1
ND
1.9
0.9
ND
ND
ND
---
ND
08/22/17
0.33
1
ND
1.9
0.96
ND
ND
ND
---
ND
02/OS/18
0.33
1
ND
1.6
1.1
ND
ND
ND
---
ND
08/13/18
0.33
1
ND
1.9
1.1
ND
ND
ND
---
ND
02/04/19
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.26
1
ND
2.1
1.4
ND
ND
ND
---
ND
02/11/21
0.26
1
ND
1.9
0.8
ND
ND
ND
---
ND
08/19/21
0.33
1
ND
2.0
1.1
ND
ND
ND
ND
ND
02/16/22
0.33
1
ND
0.8
ND
ND
ND
ND
---
ND
1,4-Dioxane (p-Dioxane)
08/13/18
1.9
10
ND
88.0
53.1
40.7
2.0
ND
---
ND
02/04/19
1.9
2
ND
132
49.6
49.8
ND
ND
ND
ND
NC2L Ill = 3 µg/L
08/07/19
1.2
2
ND
98.1
51.7
32.7
3.1
ND
---
ND
02/12/20
1.2
2
ND
98.2
44.4
36
ND
ND
---
ND
08/27/20
1.2
2
ND
113
50.0
39.3
3.0
ND
ND
ND
02/11/21
1.2
2
ND
118
53.1
40.6
1.8
ND
---
ND
08/19/21
1.2
2
ND
89.7
52.8
39.8
5.2
ND
ND
ND
02/16/22
1.7
4
ND
107
50.3
37.4
5.5
ND
0.92
ND
Appendix (Page 2 of 2!1'r)
bffpsJlbartM1ick,-,epinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-G-,tt&Moo,alGMI-3-G,amille Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
2,4-D
06/27/03
---
3
---
5.9
ND
ND
ND
---
---
---
12/30/03
--
2
ND
ND
ND
ND
ND
ND
---
ND
NC2LIll=70µg/L
06/30/04
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
--
2
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
2
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
--
2
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
2
ND
ND
ND
ND
ND
ND
ND
ND
04/08/08
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
--
2
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/16/09
0.11
5
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.23
2.1
ND
ND
ND
ND
ND
ND
---
ND
12/10/10
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.22
2
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
0.22
2
ND
ND
ND
---
--
--
---
ND
03/10/15
0.24
2.1
ND
ND
ND
---
---
---
---
ND
08/18/15
0.24
2.1
ND
ND
ND
---
---
---
---
ND
02/16/16
0.23
1
ND
ND
ND
---
---
---
---
ND
08/09/16
0.24
1
ND
ND
ND
--
--
--
---
ND
02/13/17
0.22
0.9
ND
ND
ND
---
---
---
---
ND
08/22/17
0.24
1
ND
ND
ND
---
---
---
---
ND
02/05/18
0.24
1
ND
ND
ND
---
---
---
---
ND
02/04/19
1.6
5
ND
ND
ND
---
---
---
---
ND
2-Butanone (MEK)
12/17/08
0.96
100
ND
ND
ND
ND
1.2
ND
---
ND
07/09/09
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
NC2LIll=4,000pg/L
12/16/09
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
05/08/13
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
3.3
5
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
3.3
5
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
3.3
5
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
3.3
5
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
3.3
5
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
4
5
ND
4.9J
ND
ND
ND
ND
ND
ND
02/16/22
4
5
ND
ND
ND
ND
ND
ND
---
ND
2-Methylnaphthalene
06/24/10
5.1
12.2
ND
38.9
ND
ND
ND
ND
---
ND
08/12/10
4.2
10
--
ND
--
--
--
--
--
ND
NC2L Ill = 30 µg/L
12/13/10
---
---
---
---
---
---
---
---
06/20/11
0.3
10
ND
ND
ND
ND
ND
ND
--
ND
12/05/11
---
---
---
---
---
---
---
---
---
---
06/11/12
0.28
10
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
---
---
---
---
---
---
---
---
---
---
05/01/13
0.28
10
ND
ND
ND
ND
ND
ND
--
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.28
10
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
1
10
ND
ND
ND
---
---
--
--
ND
02/16/16
0.3
10
ND
ND
ND
---
---
---
---
ND
02/13/17
0.3
10
ND
ND
ND
---
---
---
---
ND
08/22/17
1.4
10
ND
ND
ND
---
---
---
---
ND
02/05/18
1.5
10.4
ND
ND
ND
--
--
--
--
ND
02/04/19
2.8
10
ND
ND
ND
---
---
---
---
ND
02/16/22
1.7
9.1
ND
ND
ND
---
---
---
---
---
4,4'-DDD
06/11/12
0.05
0.05
ND
ND
0.13
ND
ND
ND
---
ND
07/19/12
0.05
0.1
--
---
ND
--
--
--
--
---
Ill - 0.1 µg/L
NC2L -
12/12/12
---
---
---
---
---
---
05/01/13
0.05
0.1
ND
ND
ND
ND
ND
ND
--
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.05
0.1
ND
ND
ND
--
---
---
---
ND
02/16/16
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/13/17
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/05/18
0.052
0.1
ND
ND
ND
---
---
---
---
ND
02/04/19
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/22
0.015
0.045
ND
ND
ND
---
---
---
---
---
4,4'DDT
06/11/12
0.05
0.05
ND
ND
0.1
ND
ND
ND
---
ND
07/19/12
0.05
0.1
---
---
0.063
---
---
---
---
---
Ill = 0.1 µg/L
12/12/12
---
---
---
---
---
---
05/01/13
05/01/13
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
--
---
---
---
---
---
---
---
02/24/14
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/16/16
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/13/17
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/05/18
0.052
0.1
ND
ND
ND
---
---
---
---
ND
02/04/19
0.05
0.05
ND
ND
ND
---
---
---
---
ND
Appendix (Page 3 of 2!1'r)
bffpsJlbartM1ick,-,epinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-G-,tt&Moo,alGMI-3-G,amille Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-311
MW-4
MW-5
MW-6
NES-1
BLANKS
Acetone
10/27/01
---
100
244
109
ND
130
128
476
---
479
06/13/02
---
100
ND
ND
ND
ND
ND
ND
--
--
NC2L1�1=6,000pg/L
11/19/02
---
100
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
100
ND
ND
ND
ND
ND
ND
--
---
12/30/03
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
100
ND
ND
ND
ND
ND
ND
--
ND
12/19/07
---
100
ND
ND
ND
ND
ND
ND
ND
4.5
07/08/08
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
20
100
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
20
100
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
2.2
100
ND
ND
ND
ND
ND
ND
---
2.8
06/24/10
2.2
100
ND
18.5
6.5
ND
2.2
ND
---
7.7
12/13/10
2.2
100
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
2.2
100
ND
ND
ND
ND
ND
2.4
---
3.9
12/05/11
2.2
100
ND
2.3
ND
ND
ND
ND
---
8.8
06/11/12
2.2
100
ND
3.5
ND
ND
ND
ND
ND
4.7
12/12/12
10
100
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
10
100
ND
ND
ND
ND
ND
ND
ND
14.6
08/05/13
10
100
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
10
100
ND
ND
ND
ND
ND
ND
ND
25.7
08/12/14
10
100
ND
ND
ND
ND
ND
ND
ND
22
03/10/15
10
100
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
10
100
ND
ND
ND
ND
ND
ND
ND
ND
02/16/16
10
100
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
10
100
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
10
100
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
10
100
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
10
100
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
10
100
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
25
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
5.1
25
ND
ND
ND
ND
ND
ND
---
ND
Antimony
09/08/94
---
30
ND
ND
ND
ND
ND
ND
---
---
12/01/94
---
30
ND
ND
ND
ND
ND
ND
---
---
NC2L1�1=1µg/L
02/09/95
---
30
ND
ND
ND
ND
ND
ND
---
---
03/02/95
---
30
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
30
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
30
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
30
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
30
ND
ND
ND
ND
ND
ND
---
---
12/01/97
---
30
ND
ND
ND
ND
ND
ND
---
---
05/20/98
---
30
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
30
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
30
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
30
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
30
ND
80
38
32
33
31
---
---
10/26/00
---
30
30
ND
ND
ND
ND
ND
---
---
04/18/01
---
30
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
30
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
30
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
30
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
30
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
30
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
30
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
30
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
30
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
30
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
30
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
6
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
6
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
6
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
6
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
2.6
6
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
2.6
6
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
2.6
6
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
2.6
6
ND
ND
ND
2.9
ND
ND
---
ND
12/13/10
2.6
6
ND
ND
3.0
ND
2.8
ND
---
ND
06/20/11
5
6
ND
ND
ND
ND
6.0
ND
---
ND
12/05/11
5
6
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
5
6
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
6
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
5
6
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
6
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
5
6
8.8
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
6
ND
10.5
8.0
ND
ND
ND
---
ND
03/10/15
3.8
6
ND
7.1
6.5
3.9
ND
ND
---
ND
08/18/15
3.8
6
ND
6.2
4.8
4.1
ND
ND
---
ND
02/16/16
3.8
6
ND
9.9
6.5
4.3
ND
ND
---
ND
08/09/16
3.8
6
ND
7.7
ND
ND
ND
ND
---
ND
02/13/17
3.9
6
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
3.9
6
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
3.9
6
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
3.9
6
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
3.9
5
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
3
5
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
3
5
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
3
5
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
3
5
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
5
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
3
5
ND
ND
ND
ND
ND
ND
---
ND
Appendix (Page 4 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-G-,tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Arsenic
09/08/94
---
10
ND
ND
ND
ND
ND
ND
---
--
12/01/94
---
10
ND
ND
ND
ND
ND
ND
---
--
NC2L1�1=10µg/L
02/09/95
---
10
ND
ND
ND
ND
ND
ND
03/02/95
---
10
ND
ND
ND
ND
ND
ND
-
--
11/15/95
---
10
ND
ND
ND
ND
ND
ND
---
--
05/28/96
---
10
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
10
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
10
6.0
15.0
ND
ND
ND
ND
---
---
12/01/97
---
10
ND
5.0
ND
ND
ND
ND
---
---
05/20/98
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
10
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
10
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
2.0
ND
ND
ND
ND
ND
---
ND
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
ND
4.1
ND
ND
ND
ND
ND
ND
07/08/08
---
10
ND
4.9
ND
ND
ND
ND
---
ND
12/17/08
2.7
10
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
2.7
10
ND
13.5
10.9
5.6
ND
4.0
ND
ND
12/16/09
2.7
10
ND
10.6
6.4
5.0
ND
3.6
---
ND
06/24/10
2.7
10
ND
11.8
8.1
8.2
3.3
3.1
---
ND
08/12/10
2.7
10
---
7.2
---
---
---
---
ND
08/31/10
2.7
10
15.4
--
---
---
---
---
ND
12/13/10
2.7
10
ND
4.9
2.7
5.4
ND
ND
---
ND
06/20/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
5
10
ND
5.4
ND
ND
ND
ND
ND
ND
12/12/12
5
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
10
ND
ND
5.6
ND
ND
ND
---
ND
02/24/14
5
10
ND
6.4
ND
ND
ND
ND
ND
ND
08/12/14
5
10
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
2.5
10
4.1
5.4
ND
ND
3.1
3.2
---
3
08/18/15
2.5
10
ND
5.1
ND
ND
ND
ND
---
ND
02/16/16
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
2.5
10
ND
ND
ND
ND
ND
ND
---
5.1
02/13/17
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
5
10
ND
5.4
ND
ND
ND
ND
---
ND
02/04/19
5
10
ND
5.7
ND
ND
ND
ND
---
ND
08/07/19
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
4.7
10
4.9
10
ND
ND
ND
ND
---
ND
08/19/21
NR
10
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
4.7
10
ND
11.5
11.2
9.0
5.2
5.9
---
ND
Barium
09/08/94
---
500
ND
270
ND
ND
830
860
---
---
12/01/94
---
500
ND
ND
ND
ND
ND
ND
---
---
NC21. 700 µg/L
02/09/95
---
500
ND
ND
ND
ND
510
ND
---
---
03/02/95
---
500
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
500
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
500
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
500
ND
82
30
ND
15
ND
---
---
06/17/97
---
500
200
320
37
17
210
31
---
---
12/01/97
---
500
61
180
43
46
220
33
---
---
05/20/98
---
500
30
150
45
13
180
22
---
---
11/19/98
---
500
48
120
42
ND
380
12
---
---
07/21/99
---
500
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
500
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
500
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
500
ND
ND
ND
ND
ND
ND
---
---
10/26/01
---
500
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
500
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
500
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
500
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
500
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
500
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
500
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
500
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
500
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
500
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
500
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
100
5.2
120
64.9
1.5
64.1
1.8
---
0.2
07/12/07
---
100
2.5
129
65.7
1.1
77
1.3
---
ND
12/19/07
---
100
2.8
99.2
50
1.4
49.6
1.7
87.8
11.7
07/08/08
---
100
5.8
102
58.4
1.1
57.9
1.2
---
0.29
12/17/08
0.2
100
2.7
92.9
53.1
1.2
55.5
1.1
---
10.7
07/09/09
0.2
100
4.6
121
63.4
0.37
81.4
0.94
72.4
17.6
12/16/09
0.2
100
2.9
108
62.8
0.61
56.8
0.87
---
17.1
06/24/10
0.2
100
2.5
115
61.1
1.6
93.5
1.4
---
27.3
12/13/10
0.2
100
4.3
122
67.9
1.3
90.6
1.5
---
12.1
06/20/11
5
100
ND
108
70.7
ND
84.7
ND
---
ND
12/05/11
5
100
ND
118
73
ND
90.6
ND
---
ND
06/11/12
5
100
ND
138
65.2
ND
76.4
ND
61.3
ND
12/12/12
5
100
ND
113
64.7
ND
73.6
ND
---
ND
05/01/13
5
100
ND
118
69.1
ND
84.2
ND
81.2
ND
08/05/13
5
100
ND
111
65.1
ND
95.6
ND
---
ND
02/24/14
5
100
ND
93.8
44.8
ND
139
ND
ND
ND
08/12/14
5
100
ND
125
66.4
ND
121
ND
---
ND
03/10/15
2.5
100
3.0
109
61.8
ND
116
ND
---
ND
08/18/15
2.5
100
4.4
119
63.1
ND
81.3
ND
---
ND
02/16/16
2.5
100
5.2
123
72.7
3.0
126
ND
---
ND
08/09/16
2.5
100
4.5
123
73.3
ND
109
ND
---
ND
02/13/17
2.5
100
7.8
112
68.3
ND
151
5.6
---
ND
08/22/17
2.5
100
ND
102
64.5
ND
99.9
ND
---
ND
02/05/18
2.5
100
8.0
117
73.5
ND
161
ND
---
ND
08/13/18
2.5
100
3.8
116
67.6
ND
103
ND
---
ND
02/04/19
2.5
5
ND
104
44.3
ND
110
ND
---
ND
08/07/19
1
5
5.4
113
73.8
1.2
95.1
1.9
---
ND
02/12/20
1
5
3.6
110
56.2
2.5
147
1.6
---
ND
08/27/20
3.5
5
4.5
127
83.2
ND
128
ND
---
ND
02/11/21
3.5
5
5.3
116
74.4
ND
161
ND
---
ND
08/19/21
3.5
5
6.2
119
72.7
ND
131
ND
72.3
ND
02/16/22
3.5
5
4.4
111
61.2
ND
78.3
ND
---
ND
Appendix D (Page 5 of 211)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1IBM1ared W,...nts/ -Master ProJ,,WG,-&M-IGMWO3-GrenvilleCo. Butner LF2022 First ..If GWM/rablea Hlstorlc Tables Hart & Hickman, Pa.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Benzene
09/08/94
---
5
ND
ND
ND
ND
ND
ND
---
---
12/01/94
--
5
ND
ND
ND
ND
ND
ND
---
---
NC2L1�1=1µg/L
02/09/95
---
5
ND
ND
ND
ND
ND
ND
---
---
03/02/95
--
5
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
5
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
5
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
5
ND
ND
ND
ND
ND
ND
---
---
06/17/97
--
5
ND
ND
ND
ND
ND
ND
---
---
12/01/97
---
5
ND
ND
ND
ND
ND
ND
---
---
05/20/98
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
5
ND
ND
ND
ND
ND
ND
---
---
07/21/99
--
5
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
5
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
5
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
5
ND
ND
ND
ND
ND
ND
---
---
04/18/01
--
5
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
5
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
5
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
5
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
--
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
3
ND
1.5
ND
ND
ND
ND
---
ND
02/23/07
---
3
--
1.2
---
---
---
---
---
ND
07/12/07
---
1
ND
1.9
ND
ND
ND
ND
---
ND
12/19/07
---
1
ND
1.8
0.48
0.26
ND
ND
ND
ND
07/08/08
---
1
ND
1.4
0.51
0.32
ND
ND
---
ND
12/17/08
0.25
1
ND
1.7
0.54
ND
ND
ND
---
ND
07/09/09
0.25
1
ND
1.7
0.34
ND
ND
ND
ND
ND
12/16/09
0.25
1
ND
1.7
0.60
0.29
ND
ND
---
ND
06/24/10
0.25
1
ND
0.77
0.49
0.33
ND
ND
---
ND
12/13/10
0.25
1
ND
1.8
0.59
0.37
ND
ND
---
ND
02/08/11
0.25
1
--
1.4
---
---
---
---
---
ND
06/20/11
0.25
1
ND
1.7
0.6
0.39
ND
ND
---
ND
12/05/11
0.25
1
ND
1.4
0.69
0.40
ND
ND
---
ND
06/11/12
0.25
1
ND
ND
0.51
ND
ND
ND
ND
ND
12/12/12
0.25
1
ND
1.6
0.73
0.32
ND
ND
---
ND
01/10/13
0.25
1
ND
1.4
---
---
---
ND
ND
ND
05/01/13
0.25
1
ND
1.3
0.56
0.27
ND
ND
ND
ND
08/05/13
0.25
1
ND
1.6
0.64
0.44
ND
ND
---
ND
02/24/14
0.25
1
ND
1.4
ND
ND
ND
ND
ND
ND
08/12/14
0.25
1
ND
1.7
0.61
0.25
ND
ND
ND
ND
03/10/15
0.25
1
ND
1.3
0.54
ND
ND
ND
ND
ND
08/18/15
0.25
1
ND
1.5
0.66
0.32
ND
ND
---
ND
02/16/16
0.25
1
ND
1.3
0.56
ND
ND
ND
ND
ND
08/09/16
0.25
1
ND
1.4
0.53
0.29
ND
ND
ND
ND
02/13/17
0.25
1
ND
1.2
0.61
ND
ND
ND
ND
ND
08/22/17
0.25
1
ND
1.3
0.54
ND
ND
ND
ND
ND
02/05/18
0.25
1
ND
1.2
0.67
ND
ND
ND
ND
ND
08/13/18
0.25
1
ND
1.3
0.61
0.29
ND
ND
ND
ND
02/04/19
0.15
1
ND
1.6
ND
ND
ND
ND
ND
ND
08/07/19
0.15
1
ND
1.7
0.54
0.30
ND
ND
ND
ND
02/12/20
0.15
1
ND
1.5
ND
ND
ND
ND
ND
ND
08/27/20
0.15
1
ND
1.9
0.49
ND
ND
ND
ND
ND
02/11/21
0.15
1
ND
1.8
ND
ND
ND
ND
---
ND
08/19/21
0.30
1
ND
2.1
0.491
ND
0.381
ND
ND
ND
02/16/22
0.34
1
ND
1.5
ND
ND
ND
ND
ND
ND
Benzo(g,h,i)perylene
06/20/11
0.4
10
ND
ND
ND
ND
ND
1.4
---
ND
12/05/11
---
---
---
---
---
---
---
---
---
---
NC2L1�1=200µg/L
06/11/12
0.38
10
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
---
---
---
---
---
---
---
---
---
---
05/01/13
0.38
10
ND
ND
ND
ND
ND
ND
--
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.38
10
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.5
10
ND
ND
ND
--
--
--
--
ND
02/16/16
0.4
10
ND
ND
ND
---
---
---
---
ND
02/13/17
0.4
10
ND
ND
ND
---
---
---
---
ND
08/22/17
2.1
10
ND
ND
ND
---
---
---
---
ND
02/05/18
2.2
10.4
ND
ND
ND
--
--
--
--
ND
02/04/19
1.8
10
ND
ND
ND
---
---
---
---
ND
02/16/22
2.6
9.1
ND
ND
ND
---
---
---
---
---
Appendix (Page 6 of 2!1'r)
bffpsJlbartM1ick,-,epinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-G-,tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-311
MW-4
MW-5
MW-6
NES-1
BLANKS
Beryllium
09/08/94
---
2
ND
ND
ND
ND
ND
ND
---
---
12/01/94
--
2
ND
ND
ND
ND
4
ND
---
---
NC21- 4 µg/L
02/09/95
---
2
ND
ND
ND
ND
ND
ND
---
---
03/02/95
--
2
ND
ND
ND
ND
2
ND
---
---
11/15/95
---
2
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
2
ND
ND
ND
ND
6
ND
---
---
11/22/96
---
2
ND
ND
ND
ND
3
ND
---
---
06/17/97
--
2
2
3
ND
ND
1
ND
---
---
12/01/97
---
2
ND
ND
ND
ND
ND
ND
---
---
05/20/98
---
2
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
2
ND
ND
ND
ND
2
ND
---
---
07/21/99
--
2
ND
ND
ND
ND
ND
ND
-
--
11/16/99
---
2
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
2
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
2
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
2
ND
12
ND
ND
ND
ND
---
---
10/27/01
---
2
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
2
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
2
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
2
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
2
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
2
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
--
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
2
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
1
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
0.1
1
ND
ND
ND
ND
0.14
ND
---
ND
07/09/09
0.1
1
ND
0.18
0.22
0.17
ND
ND
0.23
ND
12/16/09
0.1
1
ND
0.15
0.17
0.15
0.25
ND
---
ND
06/24/10
0.1
1
ND
ND
0.27
0.16
ND
ND
---
ND
12/13/10
0.1
1
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
1
1
ND
ND
ND
ND
ND
ND
--
ND
12/05/11
1
1
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
1
1
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
1
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
1
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
1
1
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
1
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/18/15
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.5
1
ND
ND
ND
ND
0.57
ND
---
ND
08/22/17
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.2
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.2
1
0.27
ND
ND
ND
ND
0.21
---
ND
08/27/20
0.7
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.7
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.7
1
ND
ND
ND
ND
ND
ND
---
ND
Beta-BHC
06/11/12
0.05
0.05
ND
ND
0.16
ND
ND
ND
---
ND
07/19/12
0.05
0.05
--
--
ND
--
--
---
---
---
Ill - 0.02 µg/L
NC2L -
12/12/12
---
---
---
---
---
---
05/01/13
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.05
0.05
ND
0.052
ND
ND
ND
ND
---
ND
04/15/14
0.05
0.05
---
ND
---
---
---
---
---
ND
08/12/14
---
---
--
---
03/10/15
0.1
0.1
ND
ND
ND
---
---
---
---
ND
02/16/16
0.1
0.1
ND
ND
ND
---
---
---
---
ND
02/13/17
0.1
0.1
ND
ND
ND
---
---
---
---
ND
02/05/18
0.1
0.1
ND
ND
ND
---
--
---
--
ND
02/04/19
0.1
0.1
ND
ND
ND
---
---
---
---
ND
02/16/22
0.044
0.045
ND
ND
ND
---
---
---
---
---
Bis(2- Ethyl hexl)phtha late
02/24/14
0.79
15
2.6
ND
ND
ND
ND
ND
ND
ND
04/15/14
0.79
15
ND
ND
ND
ND
ND
ND
ND
ND
NC21- Ill = 3 µg/L
08/12/14
---
---
---
---
---
---
---
---
03/10/15
0.5
15
ND
ND
ND
---
---
---
---
ND
02/16/16
0.9
15
ND
ND
ND
---
---
---
---
ND
02/13/17
0.9
15
ND
ND
ND
---
---
---
---
ND
08/22/17
2.3
15
ND
ND
ND
---
---
---
---
ND
02/05/18
2.4
15.6
ND
ND
ND
---
---
---
---
ND
02/04/19
1.4
6
ND
ND
ND
---
---
---
---
ND
Bromomethane
12/17/08
0.29
10
ND
ND
0.58
ND
ND
ND
---
ND
07/09/09
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
NC21- Ill=10 µg/L
12/16/09
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
06/11/12
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.29
10
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.62
2
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.62
2
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.62
2
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.62
2
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.62
2
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
2
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
1.7
2
ND
ND
ND
ND
ND
ND
---
ND
Appendix (Page 7 of 2!1'r)
bttpsJlba-t k,-repoinLwmisitaslMaslerFles1/8h dD--tslHPAvlasler ProjectslGarrett&MooralGMI-3-Granville Co. Bu- LF12022 First Half GW-bles-toric Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Cadmium
09/08/94
---
1
ND
ND
ND
ND
ND
4
---
---
12/01/94
---
1
ND
ND
ND
ND
ND
ND
---
---
NC2L1�1=2µg/L
02/09/95
---
1
ND
ND
ND
ND
ND
ND
---
---
03/02/95
---
1
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
1
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
1
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
1
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
1
ND
3
1
ND
ND
ND
---
---
12/01/97
---
1
ND
2
ND
ND
ND
ND
---
---
05/20/98
---
1
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
1
ND
ND
ND
ND
ND
ND
---
---
07/21/99
--
1
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
1
ND
3
3
ND
2
ND
---
---
05/10/00
---
1
5
ND
ND
ND
ND
ND
---
---
10/26/00
---
1
ND
2
ND
ND
ND
ND
---
---
04/18/01
---
1
ND
11
ND
ND
ND
ND
---
---
10/27/01
---
1
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
1
ND
2
ND
ND
ND
ND
---
---
11/19/02
---
1
2
2
ND
ND
2
ND
---
---
06/27/03
---
1
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
1
ND
1
ND
ND
ND
ND
---
ND
06/30/04
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
1
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
1
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
1
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
0.5
1
ND
1.4
ND
ND
ND
ND
ND
ND
12/16/09
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
1
1
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
1
1
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
1
1
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
1
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
1
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
1
1
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
1
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
0.5
1
ND
ND
ND
ND
ND
ND
-
ND
08/18/15
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.5
1
ND
ND
ND
ND
ND
ND
-
ND
08/22/17
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.5
1
ND
ND
ND
ND
ND
ND
-
ND
08/07/19
0.4
1
ND
ND
ND
0.48
ND
ND
---
ND
02/12/20
0.4
1
ND
ND
ND
0.69
ND
ND
---
ND
08/27/20
0.4
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.4
1
ND
0.7
0.7
1.1
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.4
1
ND
0.46
ND
0.43
0.47
ND
---
ND
Carbon disulfide
06/17/97
---
100
ND
64
ND
ND
ND
ND
---
---
12/01/97
---
100
ND
5
8
ND
ND
ND
--
---
NC2L 1�1 = 700 µg/L
05/20/98
---
100
ND
7.5
6.2
ND
ND
ND
---
---
11/19/98
---
100
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
100
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
100
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
100
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
100
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
100
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
100
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
100
ND
ND
ND
ND
ND
ND
--
---
06/27/03
---
100
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
2
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.73
2
ND
ND
ND
ND
ND
ND
---
ND
Appendix (Page 8 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-G-,tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart& Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Chlorobenzene
09/08/94
---
5
ND
10
7
ND
ND
ND
---
--
12/01/94
---
5
ND
ND
7
ND
ND
ND
---
--
NC2L1�1=50µg/L
02/09/95
---
5
ND
13
8
6
ND
ND
03/02/95
---
5
ND
12
9
ND
ND
ND
---
--
11/15/95
---
5
ND
14
8
9
ND
ND
---
--
05/28/96
---
5
ND
15
9
10
ND
ND
---
---
11/22/96
---
5
ND
15
ND
11
ND
ND
---
---
06/17/97
---
5
ND
19
11
14
ND
ND
---
---
12/01/97
---
5
ND
17
9
14
ND
ND
---
---
05/20/98
---
5
ND
20
8.6
12
ND
ND
---
---
11/19/98
---
5
ND
17.2
9.2
10
ND
ND
---
---
07/21/99
---
5
ND
14
10
11
ND
ND
---
---
11/16/99
---
5
ND
16
10
8
ND
ND
---
---
05/10/00
---
5
ND
17
11
10
ND
ND
---
---
10/26/00
---
5
ND
16
12
9
ND
ND
---
---
04/18/01
---
5
ND
16
13
6
ND
ND
---
---
10/27/01
---
0.5
ND
17
12
9
ND
ND
---
---
06/13/02
---
0.5
ND
16
11
8
ND
ND
---
---
11/19/02
---
0.5
ND
18
15
9
ND
ND
---
---
06/27/03
---
0.5
ND
17.7
13.3
7.4
ND
ND
---
ND
12/30/03
---
5
ND
20
15
6.1
ND
ND
---
ND
06/30/04
---
5
ND
18
15
9.9
ND
ND
---
ND
12/29/04
---
5
ND
19
16
9.4
ND
ND
---
ND
06/29/05
---
5
ND
15
13
8
ND
ND
---
ND
12/29/05
---
5
ND
18
16
5
ND
ND
---
ND
06/28/06
---
5
ND
16.5
10.8
7.8
ND
ND
---
ND
12/29/06
---
3
ND
17.0
17.0
4.2
ND
ND
---
ND
07/12/07
---
3
ND
17.0
16.0
ND
ND
ND
---
ND
12/19/07
---
3
ND
17.3
16.9
4.7
ND
ND
ND
ND
07/08/08
---
3
ND
17.2
17.4
6.5
ND
ND
---
ND
12/17/08
0.23
3
ND
15.9
15.6
2.6
ND
ND
---
ND
07/09/09
0.23
3
ND
16.1
17.2
6.1
ND
ND
ND
ND
12/16/09
0.23
3
ND
15.5
17.7
4.8
ND
ND
---
ND
06/24/10
0.23
3
ND
8.3
15.7
6.3
ND
ND
---
ND
12/13/10
0.23
3
ND
17.7
18.2
6.4
ND
ND
---
0.28
06/20/11
0.23
3
ND
16.3
17.2
6.7
ND
ND
---
ND
12/05/11
0.23
3
ND
14.2
17.0
5.8
ND
ND
---
ND
06/11/12
0.23
3
ND
12.0
14.8
4.4
ND
ND
ND
ND
12/12/12
0.23
3
ND
15.8
17.9
4.5
ND
ND
---
ND
05/01/13
0.23
3
ND
14.0
16.6
3.0
ND
ND
ND
ND
08/05/13
0.23
3
ND
14.4
15.9
4.6
ND
ND
---
ND
02/24/14
0.23
3
ND
16.3
2.5
1.4
ND
ND
ND
ND
08/12/14
0.23
3
ND
15.6
18.3
3.6
ND
ND
ND
ND
03/10/15
0.23
3
ND
16
17
2.1
ND
ND
ND
ND
08/18/15
0.23
3
ND
12.8
17.6
4.3
ND
ND
---
ND
02/16/16
0.23
3
ND
13.5
16.4
1.5
ND
ND
ND
ND
08/09/16
0.23
3
ND
13.5
16.9
4.2
ND
ND
---
ND
02/13/17
0.23
3
ND
13.6
18
1.3
ND
ND
---
ND
08/22/17
0.23
3
ND
14.2
19.9
1.2
ND
ND
---
ND
02/05/18
0.23
3
ND
13.5
17.3
0.54
ND
ND
---
ND
08/13/18
0.23
3
ND
14.5
22.2
3.4
ND
ND
---
ND
02/04/19
0.23
1
ND
13.6
0.35
1.3
ND
ND
---
ND
08/07/19
0.23
1
ND
10.2
16.9
ND
ND
ND
---
ND
02/12/20
0.23
1
ND
ND
ND
2.0
0.32
ND
---
ND
08/27/20
0.23
1
ND
16.1
17.5
4.1
ND
ND
---
ND
02/11/21
0.23
1
ND
15.1
7.3
2.2
ND
ND
---
ND
08/19/21
0.30
1
ND
15.4
15.7
4.2
ND
ND
ND
ND
02/16/22
0.28
1
ND
11.4
4.5
1.3
0.49
ND
---
ND
Chloroethane
12/01/97
---
10
ND
5
2
2
ND
ND
---
---
05/20/98
---
10
ND
ND
ND
ND
ND
ND
---
---
NC2L1�1=3,000Vg/L
11/19/98
---
10
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
10
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
ND
2.2
1.9
ND
ND
ND
---
ND
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
ND
1.9
1.9
1.5
ND
ND
ND
ND
07/08/08
---
10
ND
2.2
2.5
1.8
ND
ND
---
ND
12/17/08
0.54
10
ND
1.6
ND
ND
ND
ND
---
ND
07/09/09
0.54
10
ND
ND
ND
3.8
ND
ND
ND
ND
12/16/09
0.54
10
ND
ND
2.2
2.0
ND
ND
---
ND
06/24/10
0.54
10
ND
ND
2.1
2.0
ND
ND
---
ND
12/13/10
0.54
10
ND
1.8
2.0
1.7
ND
ND
---
ND
06/20/11
0.54
10
ND
1.2
2.2
2
ND
ND
---
ND
12/05/11
0.54
10
ND
1.3
2.0
1.7
ND
ND
---
ND
06/11/12
0.54
10
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.54
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.54
10
ND
ND
1.9
2.7
ND
ND
ND
ND
08/05/13
0.54
10
ND
ND
2.0
2.2
ND
ND
---
ND
02/24/14
0.54
10
ND
1.1
0.82
ND
ND
ND
ND
ND
08/12/14
0.54
10
ND
1.1
1.5
1.1
ND
ND
ND
ND
03/10/15
0.54
10
ND
1
1.8
0.81
ND
ND
ND
ND
08/18/15
0.54
10
ND
1.2
2
3.7
ND
ND
---
ND
02/16/16
0.54
10
ND
1.1
1.8
0.79
ND
ND
ND
ND
08/09/16
0.54
10
ND
0.68
2.4
1.5
ND
ND
---
ND
02/13/17
0.54
10
ND
0.76
1.6
1.1
ND
ND
---
ND
08/22/17
0.54
10
ND
1.3
2.0
1.6
ND
ND
---
ND
02/05/18
0.54
10
ND
1.7
1.7
0.68
ND
ND
---
ND
08/13/18
0.54
10
ND
1.2
2.4
1.4
ND
ND
---
ND
02/04/19
0.49
1
ND
1.3
ND
0.79
ND
ND
---
ND
08/07/19
0.49
1
ND
0.94
1.9
1.3
ND
ND
---
ND
02/12/20
0.49
1
ND
1.6
1.3
1.5
ND
ND
---
ND
08/27/20
0.49
1
ND
0.87
1.5
1.1
ND
ND
---
ND
02/11/21
0.49
1
ND
1.2
1
1.3
ND
ND
---
ND
08/19/21
0.70
1
ND
0.92J
1.4
1.2
ND
ND
ND
ND
02/16/22
0.65
1
ND
1.6
1.4
1.5
ND
ND
---
ND
Appendix D (Page 9 of 21)
M1Xps:IIM1aMick.sharepolntcomislteslMasterFiles-1ISM1ared DOCuments/ -Master ProJ,,WG,-&M-o GMI-003-Grenville Co. Butner LF2022 First Half GWMabl,a Hls,, Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Chloromethane
07/09/09
0.11
1
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
0.11
1
ND
ND
ND
ND
ND
ND
--
ND
NC2L1�1=3µg/L
06/24/10
0.11
1
ND
ND
ND
ND
ND
0.11
---
ND
12/13/10
0.11
1
ND
ND
ND
ND
ND
ND
--
ND
06/20/11
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.11
1
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.11
1
ND
ND
ND
ND
ND
ND
--
ND
05/01/13
0.11
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.11
1
ND
ND
ND
ND
ND
ND
ND
0.25
08/12/14
0.11
1
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.11
1
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
0.11
1
ND
ND
ND
ND
ND
ND
--
ND
02/13/17
0.11
1
0.2
ND
0.22
0.23
0.19
0.32
---
0.18
08/22/17
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.11
1
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.39
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.39
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.39
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.39
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.39
1
ND
ND
ND
ND
ND
ND
ND
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.54
1
ND
ND
ND
ND
ND
ND
---
ND
Chromium
09/08/94
---
10
8
44
ND
6
48
80
---
---
12/01/94
---
10
14
ND
ND
ND
18
ND
---
---
NC2L1�1=10µg/L
02/09/95
---
10
14
ND
ND
10
ND
ND
---
---
03/02/95
---
10
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
10
13
13
ND
ND
ND
ND
---
---
05/28/96
---
10
33
ND
ND
ND
ND
ND
---
---
11/22/96
---
10
3
ND
ND
ND
ND
3
---
---
06/17/97
---
10
57
43
ND
3
2
6
---
---
12/01/97
---
10
29
ND
ND
ND
ND
ND
---
---
05/20/98
---
10
10
3
ND
ND
12
ND
---
---
11/19/98
---
10
17
3
ND
ND
5
ND
---
---
07/21/99
---
10
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
12
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
ND
2.0
ND
ND
ND
ND
1.1
1.4
07/08/08
---
10
ND
0.54
0.58
ND
ND
ND
---
ND
12/17/08
0.4
10
0.73
1.8
0.96
ND
0.96
0.7
---
ND
07/09/09
0.4
10
1.2
2.4
1.1
1.6
0.68
0.53
4.8
ND
12/16/09
0.4
10
1.3
ND
ND
ND
0.95
ND
---
ND
06/24/10
0.4
10
1.1
3.5
2.8
2.4
1.2
1.4
---
0.71
12/13/10
0.4
10
2.5
1.3
1.8
0.69
0.57
1.2
--
ND
06/20/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
5
10
ND
8.6
ND
ND
ND
ND
ND
ND
12/12/12
5
10
ND
5.2
ND
ND
ND
ND
---
ND
05/01/13
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
10
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/18/15
2.5
10
ND
2.7
ND
ND
ND
6.7
---
ND
02/16/16
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
2.5
10
2.8
2.8
ND
ND
ND
ND
---
2.9
02/13/17
2.5
10
ND
2.6
ND
ND
ND
ND
---
ND
08/22/17
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
1
5
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
1
5
1.5
ND
ND
1.1
ND
ND
---
ND
08/27/20
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
3.7
5
4.1
4.0
ND
ND
ND
ND
---
ND
08/19/21
NR
5
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
Appendix OD (Page 10 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-Ga-tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Cobalt
09/08/94
---
10
ND
ND
ND
ND
ND
ND
---
--
12/01/94
---
10
11
ND
13
16
22
ND
---
--
NC2LIll = 1 µg/L
02/09/95
---
10
20
14
ND
48
39
ND
03/02/95
---
10
16
21
ND
29
121
ND
---
--
11/15/95
---
10
20
21
ND
ND
27
ND
---
--
05/28/96
---
10
30
16
ND
ND
122
ND
---
---
11/22/96
---
10
6
13
ND
4.7
93
ND
---
--
06/17/97
---
10
130
38
ND
6
45
3
---
--
12/01/97
---
10
32
21
ND
12
36
4
---
---
05/20/98
---
10
15
16
2
9
100
3
---
---
11/19/98
---
10
21
16
2
7
180
3
---
---
07/21/99
---
10
ND
16
ND
ND
100
ND
---
---
11/16/99
---
10
ND
15
ND
ND
38
ND
---
---
05/10/00
---
10
ND
17
ND
ND
61
ND
---
---
10/26/00
---
10
ND
15
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
27
ND
ND
74
ND
---
---
10/27/01
---
10
ND
12
ND
ND
47
ND
---
---
06/13/02
---
10
ND
14
ND
ND
251
ND
---
---
11/19/02
---
10
ND
10
ND
ND
57
ND
---
---
06/27/03
---
10
ND
15
ND
ND
75
ND
---
---
12/30/03
---
10
ND
17
ND
ND
52
ND
---
ND
06/30/04
---
10
ND
16
ND
ND
31
ND
---
ND
12/29/04
---
10
ND
11
ND
ND
46
ND
---
ND
06/29/05
---
10
ND
11
ND
ND
43
ND
---
ND
12/29/05
---
10
ND
12
ND
ND
30
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
72.5
ND
---
ND
12/29/06
---
10
ND
11.4
ND
ND
37.5
ND
---
ND
07/12/07
---
10
ND
11.8
ND
2.7
58.4
ND
---
ND
12/19/07
---
10
2.5
ND
ND
2.0
103
2.6
8.0
1.8
07/08/08
---
10
10.3
12.1
2.0
9.0
130
4.8
---
6.2
12/17/08
0.6
10
2.1
11.8
2.3
3.6
43.7
1.6
---
2.5
07/09/09
0.6
10
ND
6.2
ND
ND
100
ND
2.2
ND
12/16/09
0.6
10
ND
4.7
ND
ND
6.6
ND
---
ND
06/24/10
0.6
10
ND
16.3
ND
ND
25.0
ND
---
ND
12/13/10
0.6
10
2.5
15.5
ND
ND
129
ND
---
1.0
06/20/11
5
10
ND
14.2
ND
ND
81.8
ND
---
ND
12/05/11
5
10
ND
12.7
ND
ND
146
ND
---
ND
01/25/12
5
10
--
---
---
---
47.5
---
---
ND
06/11/12
5
10
ND
14.2
ND
ND
101
ND
ND
ND
12/12/12
5
10
ND
11.3
ND
ND
113
ND
---
ND
05/01/13
5
10
ND
24.3
ND
ND
34.0
ND
ND
ND
08/05/13
5
10
ND
24.7
ND
ND
50.9
ND
---
ND
02/24/14
5
10
ND
18.4
ND
ND
9.6
ND
ND
ND
08/12/14
5
10
ND
9.4
ND
ND
46.3
ND
---
ND
03/10/15
2.5
10
ND
8.7
ND
ND
39.2
ND
---
ND
08/18/15
2.5
10
ND
9.3
ND
ND
116
ND
---
ND
02/16/16
2.5
10
ND
10.0
ND
ND
13.1
ND
---
ND
08/09/16
2.5
10
ND
10.0
ND
ND
144
ND
---
ND
02/13/17
2.5
10
ND
8.3
ND
ND
78.7
ND
---
ND
08/22/17
2.5
10
ND
7.4
ND
ND
51.1
ND
---
ND
02/05/18
2.5
10
ND
8.3
ND
ND
172
ND
---
ND
08/13/18
2.5
10
ND
10.7
ND
ND
97.7
ND
---
ND
02/04/19
2.5
5
ND
9.9
ND
ND
24
ND
---
ND
08/07/19
1.1
5
ND
11.3
ND
ND
127
ND
ND
ND
02/12/20
1.1
5
ND
7.5
ND
ND
11.4
ND
1.1
ND
08/27/20
3.6
5
ND
9.7
ND
ND
88.7
ND
ND
ND
02/11/21
3.6
5
ND
10.8
ND
ND
18.6
ND
3.8
ND
08/19/21
3.6
5
ND
11.1
ND
ND
91.0
ND
ND
ND
02/16/22
3.6
5
ND
16.2
6.2
7.6
40.2
3.8
0.26
ND
Copper
09/08/94
---
200
ND
ND
ND
ND
ND
660
---
---
12/01/94
---
200
ND
ND
ND
ND
ND
ND
---
---
NC21.Ill = 1,000 µg/L
02/09/95
---
200
ND
ND
ND
ND
ND
ND
---
---
03/02/95
---
200
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
200
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
200
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
200
ND
ND
32
13
100
ND
---
---
06/17/97
---
200
34
350
13
37
28
77
---
---
12/01/97
---
200
19
72
14
88
15
34
---
---
05/20/98
---
200
12
48
380
41
53
28
---
---
11/19/98
---
200
10
ND
410
28
53
14
---
---
07/21/99
---
200
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
200
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
200
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
200
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
200
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
200
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
200
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
200
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
200
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
200
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
200
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
200
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
200
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
200
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
200
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
ND
ND
11.3
5.50
10.4
1.90
---
0.6
07/12/07
---
10
ND
ND
13.4
7.9
2.6
ND
---
ND
12/19/07
---
10
2
ND
8.6
3.8
7.0
0.73
5.8
9.8
07/08/08
---
10
0.64
ND
12.1
3.7
8.5
ND
---
ND
12/17/08
0.3
10
0.8
13.6
10.2
3.9
11.9
0.37
---
ND
07/09/09
0.3
10
ND
ND
6.3
ND
5.7
ND
8.8
ND
12/16/09
0.3
10
ND
ND
9.2
1.6
5.7
ND
---
ND
06/24/10
0.3
10
ND
ND
10
1.2
5.1
ND
---
ND
12/13/10
0.3
10
1.1
ND
13.6
5.8
5.6
0.59
---
0.49
06/20/11
5
10
ND
ND
15.3
8.1
8.7
ND
---
ND
12/05/11
5
10
ND
ND
16.9
10.0
7.6
ND
---
ND
06/11/12
5
10
ND
10.7
12.2
6.3
7.4
ND
ND
ND
12/12/12
5
10
ND
ND
11.6
8.5
10.4
ND
---
ND
05/01/13
5
10
ND
ND
13.6
5.8
9.6
ND
ND
ND
08/05/13
5
10
ND
ND
14.3
ND
10.2
ND
---
ND
02/24/14
5
10
ND
ND
12.2
ND
5.1
ND
ND
ND
08/12/14
5
10
ND
ND
10.5
ND
ND
ND
---
ND
03/10/15
2.5
10
ND
ND
8.7
ND
15.5
ND
---
ND
08/18/15
2.5
10
ND
ND
6.7
5.6
10.1
ND
---
ND
02/16/16
2.5
10
ND
ND
7.8
ND
5.1
ND
---
ND
08/09/16
2.5
10
ND
ND
5.4
ND
7.8
ND
---
ND
02/13/17
2.5
10
ND
ND
6.8
4.3
14.5
9.4
---
ND
08/22/17
2.5
10
ND
ND
6.5
ND
5.7
4.4
---
ND
02/05/18
2.5
10
ND
6.5
9.0
5.5
12.4
2.6
---
ND
08/13/18
2.5
10
ND
5.5
12.2
3.7
48.8
ND
---
ND
02/04/19
2.5
5
ND
3.0
5.4
8.0
4.3
ND
---
ND
08/07/19
2.1
5
ND
3.5
6.0
7.2
4.4
2.3
---
ND
02/12/20
2.1
5
ND
ND
9.8
12.7
3.3
ND
---
ND
08/27/20
4.3
5
ND
ND
5.3
13.5
5.6
ND
---
ND
02/11/21
4.3
5
ND
ND
84.8
9.6
ND
ND
---
ND
08/19/21
4.3
5
13.7
ND
ND
ND
ND
ND
ND
ND
02/16/22
4.3
5
7.9
ND
ND
ND
ND
ND
---
ND
Appendix D (Page 11 of 21)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1IBM1ared W,...nts/ -Master ProJ,,WG,-&M-IGMWO3-Grenville Co. Butner LF2022 First Half GWMabl,a Hls,, Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Cyanide
07/09/09
5
10
ND
ND
ND
ND
46.9
ND
ND
ND
09/28/09
5
10
---
---
---
ND
---
--
ND
NC2L 1�1= 70 µg/L
12/16/09
06/24/10
5
10
ND
ND
ND
ND
ND
ND
--
ND
12/13/10
---
---
--
---
---
---
---
---
---
---
06/20/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
---
---
---
---
---
---
---
---
---
06/11/12
5
10
ND
6.4
ND
ND
8.7
ND
---
ND
12/12/12
---
---
--
---
---
---
---
---
---
---
05/01/13
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
02/24/14
5
10
ND
ND
ND
ND
ND
ND
ND
5.5
08/12/14
5
10
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
5
10
9.5
7.5
8.5
8.8
11.8
6.6
---
5.6
02/16/16
4
10
ND
ND
ND
---
---
---
---
ND
02/13/17
4
10
ND
ND
ND
---
---
---
---
ND
08/22/17
4
10
ND
ND
ND
---
---
---
---
ND
02/05/18
4
10
ND
ND
ND
---
---
---
---
ND
02/04/19
6
8
ND
ND
ND
---
---
---
---
ND
Delta-BHC
06/11/12
0.05
0.05
ND
ND
0.09
ND
ND
ND
---
ND
07/19/12
0.05
0.05
---
---
ND
---
---
---
---
---
Ill- NE
NC2L -
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/16
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/13/17
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/05/18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
02/04/19
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/22
0.013
0.045
ND
ND
ND
---
---
---
---
---
Dibenz(a,h)anth racene
06/20/11
0.55
10
ND
ND
ND
ND
ND
1.5
---
ND
12/05/11
---
---
---
---
---
---
---
---
---
---
NC2LI'1=0.005µg/L
06/11/12
0.55
10
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
--
---
--
--
---
---
---
---
---
---
05/01/13
0.55
10
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.55
10
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.5
10
ND
ND
ND
---
---
---
---
ND
02/16/16
0.6
10
ND
ND
ND
---
---
---
---
ND
02/13/17
0.6
10
ND
ND
ND
---
---
---
---
ND
08/22/17
2
10
ND
ND
ND
---
---
---
---
ND
02/05/18
2.1
10.4
ND
ND
ND
---
---
---
---
ND
02/04/19
1.9
10
ND
ND
ND
---
---
---
---
ND
02/16/22
2.7
9.1
ND
ND
ND
---
---
---
---
---
Dichlorodifluoromethane
02/05/18
0.21
5
ND
0.36
ND
---
---
---
ND
02/04/19
0.23
1
ND
ND
ND
---
---
---
---
ND
NC21.Ill=1,000µg/L
02/11/21
0.23
1
ND
ND
ND
---
---
---
---
02/16/22
0.35
1
ND
ND
ND
---
---
---
---
---
Diethyl phthalate
NC21. ") = 6,000 M/L
02/04/19
2
10
ND
7.1
ND
---
---
---
---
ND
Dinoseb
03/10/15
0.061
1.1
ND
ND
0.11
---
---
---
---
ND
02/16/16
0.058
0.19
ND
ND
ND
---
---
---
---
ND
NC2LIll=7µg/L
02/13/17
0.057
0.19
ND
ND
ND
---
---
---
---
ND
08/22/17
0.062
0.2
ND
ND
ND
---
---
---
---
ND
02/05/18
0.061
0.2
ND
ND
ND
--
---
---
---
ND
02/04/19
1.2
1 5
ND
ND
ND
---
---
---
---
ND
Endosulfan 1
02/04/19
0.05
0.05
---
0.078
0.19
---
---
---
---
---
NC21.I11=40µg/L
02/16/22
0.016
0.045
ND
ND
ND
---
---
---
---
---
Endrin aldehyde
06/11/12
0.05
0.05
ND
ND
0.14
ND
ND
ND
---
---
12/12/12
0.05
0.1
ND
ND
ND
ND
ND
ND
---
---
NC2LIll=2µg/L
05/01/13
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
0.05
0.1
ND
ND
ND
---
---
---
---
ND
03/10/15
0.05
0.1
ND
ND
ND
---
---
---
---
ND
08/18/15
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/16/16
0.05
0.1
ND
ND
ND
---
---
---
---
ND
08/09/16
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/13/17
0.05
0.1
ND
ND
ND
---
---
---
---
ND
02/05/18
0.052
0.1
ND
ND
ND
---
---
---
---
ND
02/04/19
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/22
0.015
0.045
ND
ND
ND
---
---
---
---
---
Ethylbenzene
12/17/08
0.3
1
ND
0.31
ND
ND
ND
ND
---
ND
07/09/09
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
NC2LIl1=600µg/L
12/16/09
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.3
1
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.3
1
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.3
1
ND
0.4
0.57
ND
ND
ND
---
ND
Appendix D (Page 12 of 21)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1IBM1ared W,.... WH -Master ProJ,,WG,-&M-o GMW03-G-AlleC.. Butner LFM22 First ..If GWM/rablea Hls ,.Tables Hart& Hickman, PC

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Fluorene
06/24/10
3.8
12.2
ND
4.3
ND
ND
ND
ND
--
ND
08/12/10
3.1
10
---
ND
---
---
---
---
--
ND
Ill = 300 µg/L
12/13/10
---
---
---
---
---
---
--
---
6/20/11
06/20/11
0
0.2
10
ND
ND
ND
ND
ND
ND
-
ND
12/05/11
---
---
---
---
---
---
---
---
---
---
06/11/12
0.21
10
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
---
---
---
---
---
---
---
---
---
---
05/01/13
0.21
10
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.21
10
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
1
10
ND
ND
ND
---
---
---
---
ND
02/16/16
0.2
10
ND
ND
ND
---
---
---
---
ND
02/13/17
0.2
10
ND
ND
ND
---
---
---
---
ND
08/22/17
1.6
10
ND
ND
ND
---
---
---
---
ND
02/05/18
1.6
10.4
ND
ND
ND
---
---
---
---
ND
02/04/19
3
10
ND
ND
ND
---
---
---
---
ND
02/16/22
1.9
9.1
ND
ND
ND
---
---
---
---
---
gamma-BHC(Lindane)
06/27/03
---
1.05
ND
0.085
ND
ND
ND
ND
---
ND
12/30/03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC2LIll=0.03µg/L
06/30/04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/16/09
0.01
0.1
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.00021
0.01
ND
ND
0.052
ND
ND
ND
---
ND
08/12/10
0.0002
0.01
---
---
ND
---
---
---
---
ND
12/13/10
0.0002
0.05
ND
ND
0.013
ND
ND
ND
---
ND
06/20/11
0.0002
0.05
ND
ND
0.066
ND
ND
ND
---
ND
07/28/11
0.0002
---
---
---
ND
---
---
---
---
ND
12/05/11
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
0.05
0.05
ND
ND
ND
---
---
---
---
ND
03/10/15
0.05
0.05
ND
ND
ND
---
---
---
---
ND
08/18/15
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/16
0.05
0.05
ND
ND
ND
---
---
---
---
ND
08/09/16
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/13/17
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/05/18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
02/04/19
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/22
0.011
0.045
ND
ND
ND
---
---
---
---
---
Heptachlor
06/27/03
---
1.05
ND
0.03
0.17
ND
ND
ND
---
ND
12/30/03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC2L Ill=0.008 µg/L
06/30/04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/16/09
0.02
0.1
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
0.0015
0.01
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.05
---
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.05
0.0015
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.05
0.056
ND
0.062
ND
ND
ND
ND
---
ND
01/25/12
0.05
0.05
---
ND
---
---
---
---
---
ND
06/11/12
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.05
0.05
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
0.05
0.05
ND
ND
ND
---
---
---
---
ND
03/10/15
0.05
0.05
ND
ND
ND
---
---
---
---
ND
08/18/15
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/16/16
0.05
0.05
ND
ND
ND
--
---
---
---
ND
08/09/16
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/13/17
0.05
0.05
ND
ND
ND
---
---
---
---
ND
02/05/18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
02/04/19
0.05
0.05
ND
ND
ND
---
--
---
---
ND
02/16/22
0.018
0.045
ND
ND
ND
---
---
---
---
---
Indeno(1,2,3-cd)pyrene
06/20/11
0.29
10
ND
ND
ND
ND
ND
1.3
---
ND
12/05/11
---
---
---
---
---
---
---
---
---
---
NC2LI11=0.05µg/L
06/11/12
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
---
---
---
---
---
---
---
---
---
---
05/01/13
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.29
10
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.5
10
ND
ND
ND
---
---
---
---
ND
02/16/16
0.3
10
ND
ND
ND
---
---
---
---
ND
02/13/17
0.3
10
ND
ND
ND
---
---
---
---
ND
08/22/17
2
10
ND
ND
ND
---
---
---
---
ND
02/05/18
2.1
10.4
ND
ND
ND
--
-
---
---
ND
02/04/19
1.7
10
ND
ND
ND
---
---
---
---
ND
02/16/22
2.6
9.1
ND
ND
ND
---
---
---
---
---
Isobutanol
06/24/10
35
100
ND
59
ND
ND
ND
ND
---
ND
12/13/10
---
---
---
---
NC2LI1l=NE
06/20/11
35
100
ND
39.5
ND
ND
ND
ND
---
ND
12/05/11
---
---
---
--
---
--
---
--
ND
---
06/11/12
35
100
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
---
---
---
---
---
---
---
---
---
---
05/01/13
35
100
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
ND
---
---
---
---
---
---
---
02/24/14
35
100
ND
ND
ND
ND
ND
ND
---
ND
08/12/14
35
100
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
35
100
ND
ND
ND
---
---
---
---
ND
02/16/16
35
100
ND
42.5
ND
--
---
---
---
ND
02/13/17
35
100
ND
ND
ND
---
---
---
---
ND
08/22/17
35
100
ND
ND
ND
---
---
---
---
ND
02/05/18
35
100
ND
ND
ND
---
---
---
---
ND
02/04/19
66.4
100
ND
ND
ND
--
---
---
---
ND
02/11/21
66.4
100
ND
ND
ND
---
---
---
---
---
02/16/22
52.3
100
ND
ND
ND
---
---
---
---
---
Appendix D (Page 13 of 21)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1IGM1ared DOCumenta/H -Master ProJ,,WGa-&M-o GMW03-GrenvilleCa. Butner LF2022 First Half GWM/rablee/Hlat,a. Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Lead
09/08/94
---
10
ND
13
ND
ND
30
36
---
--
12/01/94
---
10
11
ND
ND
ND
36
ND
---
--
NC2LIll = 15 µg/L
02/09/95
---
10
ND
ND
ND
10
37
ND
03/02/95
---
10
ND
ND
ND
ND
44
ND
---
--
11/15/95
---
10
ND
ND
ND
ND
ND
ND
---
--
05/28/96
---
10
ND
ND
ND
ND
42
ND
---
---
11/22/96
---
10
ND
ND
ND
ND
13
ND
---
---
06/17/97
---
10
20
29
ND
ND
13
ND
---
---
12/01/97
---
10
8
14
ND
5
14
ND
---
---
05/20/98
---
10
ND
6
ND
6
21
ND
---
---
11/19/98
---
10
5
ND
ND
ND
58
ND
---
---
07/21/99
---
10
ND
12
14
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
11
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
12
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
ND
ND
ND
ND
ND
2.1
---
ND
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
4
10
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
4
10
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
4
10
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
4
10
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
4
10
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
5
10
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
10
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/18/15
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
2.5
10
ND
5.1
ND
ND
ND
ND
---
ND
02/13/17
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
2.5
10
ND
2.8
ND
ND
ND
ND
---
ND
02/05/18
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
2.5
10
ND
ND
ND
ND
4.6
ND
---
ND
02/04/19
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
1.6
5
ND
2
ND
ND
ND
ND
---
ND
02/12/20
1.6
5
1.9
2.1
2.1
2.8
3.1
2.3
---
ND
08/27/20
4.5
5
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
4.5
5
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
4.5
5
ND
4.71
ND
ND
ND
ND
ND
ND
02/16/22
4.5
5
ND
6.6
5.4
6.4
ND
ND
---
ND
Mercury
12/01/97
---
0.5
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
0.5
ND
ND
ND
ND
ND
ND
---
---
NC2LIll = 1 µg/L
11/16/99
---
0.5
ND
0.59
0.65
0.65
0.76
ND
05/10/00
---
0.5
ND
ND
ND
ND
---
---
---
10/26/00
---
0.5
N D
ND
ND
ND
---
---
---
04/18/01
---
0.5
--
N D
ND
ND
ND
---
---
---
06/13/02
---
0.5
--
ND
ND
ND
ND
---
---
---
06/27/03
---
0.5
-
ND
ND
ND
ND
---
---
---
12/30/03
---
0.5
---
---
---
---
---
---
---
06/30/04
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
---
---
---
---
---
---
---
---
06/29/05
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
---
--
---
---
---
---
---
---
---
06/28/06
---
2
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
---
---
---
---
---
---
---
---
07/12/07
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
---
---
---
---
---
---
ND
---
07/08/08
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
---
---
---
---
---
---
---
---
---
07/09/09
0.07
0.2
ND
ND
ND
ND
ND
ND
---
ND
12/16/09
---
---
--
---
---
---
---
---
---
---
06/24/10
0.07
0.2
ND
ND
ND
ND
ND
0.098
---
ND
12/13/10
---
---
---
---
---
---
---
---
---
06/20/11
0.1
0.2
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
---
---
--
---
---
---
---
---
---
---
06/11/12
0.1
0.2
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
---
---
---
---
---
---
---
---
---
05/01/13
0.1
0.2
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
02/24/14
0.1
0.2
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
---
---
---
---
---
---
---
---
---
03/10/15
0.1
0.2
ND
ND
ND
---
---
---
---
ND
02/16/16
0.1
0.2
ND
ND
ND
---
---
---
---
ND
02/13/17
0.1
0.2
ND
ND
ND
---
---
---
---
ND
08/22/17
0.1
0.2
ND
ND
ND
---
---
---
---
ND
02/05/18
0.1
0.2
ND
ND
ND
---
---
---
---
ND
02/04/19
0.1
0.2
ND
ND
ND
---
---
---
---
ND
02/11/21
0.12
0.2
ND
ND
ND
---
---
---
---
---
02/16/22
0.12
0.2
ND
ND
ND
---
---
---
---
---
Appendix D (Page 14 of 21)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1ISM1ared W,.... WH -Master ProJ,,WGar-&M-o GMW03-G-AlleC.. Butner UM022 First Half GWM/rabl.e HI-1. Tables Hart& Hickman, PC

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Methylene Chloride
07/09/09
0.97
2
ND
ND
ND
ND
ND
ND
ND
9.6
12/16/09
0.97
2
ND
ND
ND
ND
ND
ND
---
ND
NC2L1�1=5µg/L
06/24/10
0.97
1
ND
19
ND
ND
ND
ND
---
ND
08/12/10
0.97
1
---
ND
---
---
---
---
---
ND
12/13/10
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.97
1
ND
ND
---
ND
ND
ND
ND
ND
12/12/12
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.97
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.97
1
1.0
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.97
1
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.97
1
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.97
1
1.3
1.1
1.6
ND
ND
ND
ND
ND
02/16/16
0.97
1
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.97
1
ND
ND
1.0
ND
ND
ND
---
2.2
02/13/17
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.97
1
ND
ND
ND
ND
ND
ND
---
1.4
02/05/18
0.97
1
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.97
1
ND
ND
ND
ND
ND
ND
---
6.6
02/04/19
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
3.7
5
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
5
ND
ND
ND
ND
ND
ND
ND
12.9
02/16/22
2
5
ND
ND
ND
ND
ND
ND
---
4.1
Naphthalene
07/08/08
---
10
ND
3.8
ND
ND
ND
---
---
ND
12/17/08
---
---
---
---
---
---
---
---
---
---
NC21. 6 µg/L
07/09/09
0.24
10
ND
2.4
ND
ND
ND
---
---
ND
12/16/09
---
---
---
---
---
---
---
---
---
---
06/24/10
0.24
10
ND
7.4
ND
ND
ND
---
---
ND
12/13/10
---
---
---
---
---
---
---
---
---
---
06/20/11
0.24
10
ND
4.6
ND
ND
ND
---
---
0.39
12/05/11
---
---
---
---
---
---
---
---
---
---
06/11/12
0.2
10
ND
4.6
ND
ND
ND
ND
ND
ND
12/12/12
---
---
---
--
---
---
---
---
---
---
05/01/13
0.24
10
ND
5.1
ND
ND
ND
---
---
ND
08/05/13
---
---
---
---
---
---
---
---
---
---
02/24/14
0.24
10
ND
5.8
ND
ND
ND
---
---
ND
08/12/14
---
---
---
--
---
---
---
---
---
---
03/10/15
0.2
10
ND
5.4
ND
---
---
---
---
ND
02/16/16
0.2
10
ND
5.7
ND
---
---
---
---
ND
02/13/17
0.2
10
ND
6.1
ND
---
---
---
---
ND
08/22/17
0.2
10
ND
7.0
0.45
---
---
---
---
ND
02/05/18
0.2
10
ND
5.7
ND
---
---
---
---
ND
02/04/19
0.4
1
ND
4.2
ND
---
---
---
---
ND
02/11/21
0.4
1
ND
3.7
ND
---
---
---
---
---
02/16/22
0.64
1
ND
1.5
ND
---
---
---
---
---
Nickel
09/08/94
---
50
ND
ND
ND
ND
ND
ND
---
---
12/01/94
---
50
ND
ND
ND
ND
ND
ND
---
---
NC21. 100 µg/L
02/09/95
---
50
ND
72
ND
ND
ND
ND
---
---
03/02/95
---
50
ND
100
ND
ND
ND
ND
---
---
11/15/95
---
50
ND
61
ND
ND
ND
ND
---
---
05/28/96
---
50
ND
85
ND
ND
ND
ND
---
---
11/22/96
---
50
ND
72
ND
ND
ND
ND
---
---
06/17/97
---
50
75
98
ND
ND
ND
ND
---
---
12/01/97
---
50
ND
89
ND
ND
ND
ND
---
---
05/20/98
---
50
ND
91
ND
ND
ND
ND
---
---
11/19/98
---
50
ND
83
ND
ND
ND
ND
---
---
07/21/99
---
50
ND
109
ND
ND
ND
ND
---
---
11/16/99
---
50
ND
122
ND
ND
ND
ND
---
---
05/10/00
---
50
ND
104
ND
ND
ND
ND
---
---
10/26/00
---
50
ND
93
ND
ND
ND
ND
---
---
04/18/01
---
50
ND
107
ND
ND
ND
ND
---
---
10/27/01
---
50
ND
92
ND
ND
ND
ND
---
---
06/13/02
---
50
ND
98
ND
ND
ND
ND
---
---
11/19/02
---
50
ND
74
ND
ND
ND
ND
---
---
06/27/03
---
50
ND
85
ND
ND
ND
ND
---
---
12/30/03
---
50
ND
100
ND
ND
ND
ND
---
ND
06/30/04
---
50
ND
120
ND
ND
ND
ND
---
ND
12/29/04
---
50
ND
100
ND
ND
ND
ND
---
ND
06/29/05
---
50
ND
150
ND
ND
ND
ND
---
ND
12/29/05
---
50
ND
96.0
ND
ND
ND
ND
---
ND
06/28/06
---
50
ND
88.7
ND
ND
ND
ND
---
ND
12/29/06
---
50
ND
94.7
30.1
14.2
8.9
ND
---
ND
07/12/07
---
50
ND
99.0
30.6
13.9
13.7
ND
---
ND
12/19/07
---
50
ND
83.4
23.7
11
18.3
ND
11.4
ND
07/08/08
---
50
ND
76.0
28.1
11.5
27
ND
---
ND
12/17/08
1.7
50
ND
75.5
27.8
12.2
11.0
ND
---
2.4
07/09/09
1.7
50
2.2
93.5
29.4
11.7
23.2
ND
13.1
ND
12/16/09
1.7
50
ND
81.2
28.2
11.8
2.6
ND
---
3.0
06/24/10
1.7
50
ND
76.3
19.7
9.0
7.0
4.5
---
ND
12/13/10
1.7
50
ND
83.0
23.5
6.8
20.7
ND
---
2.7
06/20/11
5
50
ND
78.8
30.1
11.2
15.3
ND
---
ND
12/05/11
5
50
ND
89.1
32.8
11.7
24.3
ND
---
ND
06/11/12
5
50
ND
91.8
28.9
10.0
17.3
ND
ND
ND
12/12/12
5
50
ND
91.8
29.2
9.3
21.1
ND
---
ND
05/01/13
5
50
ND
89.6
31.9
10.4
5.7
ND
ND
ND
08/05/13
5
50
ND
87.9
28.1
9.0
8.4
ND
---
ND
02/24/14
5
50
ND
83.1
16.7
10.4
ND
ND
ND
ND
08/12/14
5
50
ND
97.9
29.0
12.9
13.2
ND
---
ND
03/10/15
2.5
50
ND
91.9
32.9
12.3
8.2
ND
---
ND
08/18/15
2.5
50
ND
98.0
28.0
11.9
26.2
5.4
---
ND
02/16/16
2.5
50
ND
92.0
35.4
12.7
3.7
ND
---
ND
08/09/16
2.5
50
3.3
88.9
29.0
12.2
30.7
ND
---
ND
02/13/17
2.5
50
ND
89.6
30.4
13.5
16.2
ND
---
ND
08/22/17
2.5
50
ND
84.2
28.2
12.3
13.5
ND
---
ND
02/05/18
2.5
50
ND
87.6
29.8
11.7
28.5
ND
---
ND
08/13/18
2.5
50
ND
88.9
29.0
12.3
21.9
ND
---
ND
02/04/19
2.5
5
ND
85.7
17.4
10.7
5.5
ND
---
ND
08/07/19
0.9
5
ND
92.6
27.8
11.7
18.7
ND
---
ND
02/12/20
0.9
5
1.1
89.9
20.5
13.2
3.4
ND
---
ND
08/27/20
3.5
5
ND
99.1
19.5
12.2
18.1
ND
---
ND
02/11/21
3.5
5
ND
91.8
21.4
13.5
3.9
ND
---
ND
08/19/21
3.5
5
3.51
100
24.8
15.1
15.9
ND
7.1
ND
02/16/22
3.5
5
4.8
99.3
19.9
16.2
9.1
ND
---
ND
N-Nitroso-di-n-butylamine
02/24/14
7.5
10
ND
ND
ND
8.6
ND
ND
ND
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
NC2L(�)= NE
03/10/15
1.3
10
ND
ND
ND
---
---
---
---
ND
02/16/16
2.2
10
ND
ND
ND
---
---
---
---
ND
02/13/17
2.2
10
ND
ND
ND
---
---
---
---
ND
08/22/17
1.6
10
ND
ND
ND
---
---
---
---
ND
02/05/18
1.6
10
ND
ND
ND
---
---
---
---
ND
02/04/19
2.2
10
ND
ND
ND
---
---
---
---
ND
02/16/22
7.9
9.1
ND
ND
ND
---
I ---
I ---
I ---
I ---
Appendix D (Page 15 of 21)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1IBM1ared Documents/-MasterProjectelG.-&M..re GMW03-GrenvilleCo. Butner LF2022 First ..If GWMa.U.a HI-I.Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Phorate
04/18/01
---
10
---
3.2
ND
ND
ND
---
---
---
10/27/01
--
5
ND
8.1
ND
ND
ND
ND
---
---
NC21- 1 µg/L
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
5
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
---
---
---
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
---
---
---
---
---
---
---
---
---
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
---
---
--
--
--
---
---
ND
---
07/08/08
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
---
---
---
---
---
---
---
---
---
---
07/09/09
6.6
22.2
ND
ND
ND
ND
ND
ND
---
ND
12/16/09
---
---
---
---
---
---
---
--
---
---
06/24/10
6.5
24.1
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
---
---
---
---
---
---
---
---
---
---
06/20/11
5.4
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
---
---
---
---
---
---
---
---
---
---
06/11/12
5.4
10
ND
ND
ND
ND
ND
ND
---
ND
12/12/12
---
---
---
---
---
---
---
---
---
---
05/01/13
5.4
10
ND
ND
ND
ND
ND
ND
---
ND
08/05/13
---
---
--
---
---
---
---
---
---
---
02/24/14
5.4
10
---
ND
ND
ND
ND
ND
---
ND
08/12/14
---
---
---
---
---
---
---
---
---
---
03/10/15
0.8
10
ND
ND
ND
---
---
---
---
ND
02/16/16
1.1
10
ND
---
ND
--
---
---
---
ND
02/13/17
1.1
10
ND
ND
ND
---
---
---
---
ND
08/22/17
1.7
10
ND
ND
ND
---
---
---
---
ND
02/05/18
1.8
10.4
ND
ND
ND
---
---
---
---
ND
02/04/19
1.1
10
ND
ND
ND
--
---
---
---
ND
02/16/22
3.2
9.1
ND
ND
ND
---
---
---
---
---
Selenium
09/08/94
---
20
ND
ND
ND
ND
ND
ND
---
---
12/01/94
---
20
ND
ND
ND
ND
ND
ND
---
---
NC21- 20 µg/L
02/09/95
---
20
ND
ND
ND
ND
ND
ND
03/02/95
---
20
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
20
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
20
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
20
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
20
ND
ND
ND
ND
ND
ND
---
---
12/01/97
---
20
ND
ND
ND
ND
ND
ND
---
---
05/20/98
---
20
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
20
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
20
ND
ND
ND
ND
36
ND
---
---
11/16/99
---
20
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
20
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
20
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
20
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
20
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
20
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
20
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
20
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
20
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
20
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
20
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
20
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
20
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
20
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
ND
11.5
ND
ND
ND
ND
ND
ND
07/08/08
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
3.8
10
4.8
5.1
4.8
ND
ND
ND
---
4.9
07/09/09
3.8
10
ND
ND
4.2
ND
ND
ND
ND
ND
12/16/09
3.8
10
ND
ND
ND
5.1
ND
ND
--
ND
06/24/10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
10
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
10
10
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
10
10
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
10
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
10
10
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
10
10
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
10
10
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
10
10
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/18/15
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
5
10
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
4.7
10
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
10
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
4.7
10
ND
7.7
ND
5.8
ND
ND
---
ND
Appendix OD (Page 16 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-Ga-tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Silver
09/08/94
---
10
ND
ND
ND
ND
ND
ND
---
---
12/01/94
---
10
ND
ND
ND
ND
ND
ND
---
---
NC21- 20 µg/L
02/09/95
---
10
ND
ND
ND
ND
ND
ND
---
---
03/02/95
---
10
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
10
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
10
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
10
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
10
ND
ND
ND
ND
ND
ND
---
---
12/01/97
---
10
ND
8
ND
ND
ND
ND
---
---
05/20/98
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
10
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
10
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
15
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
ND
0.57
0.6
0.55
ND
0.33
ND
ND
07/08/08
---
10
ND
2.7
2.3
1.1
0.22
0.69
---
0.12
12/17/08
0.1
10
0.13
1.8
1.4
0.85
0.12
0.51
---
ND
07/09/09
0.1
10
ND
0.84
0.63
0.45
ND
0.11
ND
ND
12/16/09
0.1
10
0.12
2.0
1.6
1.0
0.12
0.52
---
ND
06/24/10
0.1
10
ND
0.38
0.33
0.35
ND
ND
---
ND
12/13/10
0.1
10
0.15
1.3
0.99
0.45
ND
ND
---
0.19
06/20/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
5
10
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
5
10
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
10
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
5
10
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
10
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/18/15
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
2.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
5
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
2.5
5
ND
ND
ND
ND
ND
ND
---
ND
Thallium
09/08/94
---
10
ND
ND
ND
ND
ND
ND
---
---
12/01/94
---
10
ND
ND
ND
ND
ND
ND
---
---
NC21- 2 µg/L
02/09/95
---
10
ND
ND
ND
ND
ND
ND
---
---
03/02/95
---
10
ND
ND
ND
ND
ND
ND
---
---
11/15/95
---
10
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
10
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
10
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
10
ND
3
ND
ND
ND
ND
---
---
12/01/97
---
10
ND
ND
ND
ND
ND
ND
---
---
05/20/98
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
10
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
10
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
10
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
22
13
ND
ND
ND
---
ND
12/29/05
---
10
ND
23
20
ND
ND
ND
---
ND
06/28/06
---
10
ND
25.7
12.6
ND
ND
ND
---
ND
12/29/06
---
6
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
5.5
ND
ND
ND
ND
ND
ND
--
ND
12/19/07
---
5.5
ND
4.0
ND
ND
ND
ND
ND
ND
07/08/08
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
3
5.5
ND
3.2
3.2
ND
ND
ND
---
ND
07/09/09
3
5.5
ND
ND
ND
4.1
ND
ND
ND
ND
12/16/09
3
5.5
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
3
5.5
ND
ND
5.2
3.1
ND
ND
---
ND
12/13/10
3
5.5
ND
ND
7.7
ND
ND
ND
---
ND
06/20/11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
03/10/15
5
5.5
ND
ND
ND
ND
ND
ND
---
ND
08/18/15
5
5.5
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
5
5.5
ND
ND
ND
ND
ND
ND
---
ND
08/09/16
5
5.5
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.02
5.5
0.023
0.04
ND
ND
0.035
ND
---
ND
08/22/17
0.02
5.5
ND
ND
ND
ND
0.033
ND
---
ND
02/05/18
0.03
0.1
ND
ND
ND
ND
0.047
ND
---
ND
08/13/18
0.02
5.5
ND
ND
ND
ND
0.037
ND
---
ND
02/04/19
0.06
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.06
0.1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.06
0.1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.05
0.1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.05
0.1
ND
ND
ND
ND
ND
ND
--
ND
08/19/21
NR
0.47
ND
ND
ND
ND
ND
ND
0.0691
ND
02/16/22
0.05
0.47
ND
ND
ND
ND
ND
ND
---
ND
Appendix OD (Page 17 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-Ga-tt&MoorelGMI-3-Granville Ce.Bu-LF12022 First HalfGWM-bI--t.-Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Tin
12/01/97
---
100
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
100
ND
ND
ND
ND
ND
ND
--
---
NC21- 2,000 pg/L
11/16/99
---
100
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
100
-
ND
ND
ND
ND
---
--
---
04/18/01
---
100
--
ND
ND
ND
ND
---
---
---
10/27/01
---
100
--
---
---
---
---
---
---
---
06/13/02
---
100
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
100
---
---
---
---
---
---
---
06/27/03
---
100
ND
149
127
ND
ND
ND
---
---
12/30/03
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
100
ND
41.1
14.4
3.2
ND
ND
---
ND
07/12/07
---
100
ND
35.2
13.9
5.2
ND
ND
---
ND
12/19/07
---
100
ND
33.6
7.4
ND
ND
ND
ND
ND
07/08/08
---
100
4.4
28.6
15.1
5.4
3
3.6
---
ND
12/17/08
1.8
100
ND
22.5
9.2
ND
ND
ND
---
ND
07/09/09
1.8
100
ND
21.4
8.6
ND
ND
ND
---
ND
12/16/09
1.8
100
ND
26.3
10.7
ND
ND
ND
---
ND
06/24/10
1.8
100
ND
23.4
10.7
3.2
2.2
1.9
---
ND
12/13/10
1.8
100
ND
30.3
12.1
5.8
ND
ND
---
ND
06/20/11
5
100
ND
26.8
13.8
ND
ND
ND
---
ND
12/05/11
5
100
ND
25.8
13.9
ND
ND
ND
---
ND
06/11/12
5
100
ND
22.2
9
ND
ND
ND
ND
ND
12/12/12
5
100
ND
30.0
13.2
ND
ND
ND
---
ND
05/01/13
5
100
ND
25.8
12.2
ND
ND
ND
---
ND
08/05/13
5
100
ND
22.7
12.5
ND
ND
ND
---
ND
02/24/14
5
100
ND
26.7
11.7
9.8
ND
ND
ND
ND
08/12/14
5
100
ND
30.7
8.2
ND
ND
ND
---
ND
03/10/15
2.5
100
ND
28.7
11.1
ND
ND
ND
---
ND
08/18/15
2.5
100
ND
27.7
7.5
ND
ND
ND
---
ND
02/16/16
2.5
100
ND
28.6
10.4
---
---
---
---
ND
08/09/16
2.5
100
ND
20.9
5.4
---
---
---
---
ND
02/13/17
2.5
100
ND
25.5
7.8
---
---
---
---
3.6
08/22/17
2.5
100
ND
17.2
5.3
---
---
---
---
ND
02/05/18
2.5
100
ND
20.3
9.5
---
---
---
---
ND
08/13/18
2.5
100
ND
22.2
7.4
--
---
ND
---
ND
02/04/19
2.5
5
ND
24.8
5.5
---
---
---
---
ND
08/07/19
1.6
5
ND
29.3
9.7
---
---
---
---
ND
02/12/20
1.6
5
ND
26.0
5.8
---
---
---
---
ND
08/27/20
4.7
5
ND
27.6
5.1
---
---
---
---
ND
02/11/21
4.7
5
ND
30.1
8.0
---
---
---
---
---
08/19/21
4.7
5
ND
26.2
6.5
ND
---
ND
---
ND
02/16/22
4.7
5
ND
28.2
11.2
---
---
---
---
---
Toluene
05/20/98
---
5
ND
ND
8.1
ND
ND
ND
---
---
11/19/98
---
5
ND
ND
ND
ND
ND
ND
---
---
NC21- 600 µg/L
07/21/99
--
5
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
5
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
5
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
5
ND
ND
ND
ND
ND
ND
---
---
10/26/01
--
5
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
5
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
5
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
5
ND
ND
ND
ND
ND
ND
---
---
06/27/03
--
5
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
--
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
5
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
5
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
1
ND
0.49
ND
ND
ND
ND
---
0.34
12/19/07
---
1
ND
0.51
ND
ND
ND
ND
ND
ND
07/08/08
---
1
ND
0.39
ND
ND
1.3
ND
---
ND
12/17/08
0.26
1
1.4
1.6
ND
ND
11.7
ND
---
ND
07/09/09
0.26
1
ND
0.46
ND
ND
ND
ND
ND
ND
12/16/09
0.26
1
ND
0.42
ND
ND
ND
ND
---
ND
06/24/10
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
0.26
1
ND
0.54
ND
ND
ND
ND
---
ND
06/20/11
0.26
1
ND
0.34
ND
ND
ND
ND
---
ND
12/OS/11
0.26
1
ND
0.28
ND
ND
0.3
ND
---
ND
06/11/12
0.26
1
ND
0.28
ND
ND
ND
ND
ND
ND
12/12/12
0.26
1
ND
0.29
ND
ND
0.36
ND
---
ND
05/01/13
0.26
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.26
1
ND
0.29
ND
ND
ND
ND
---
ND
02/24/14
0.26
1
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.26
1
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.26
1
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.26
1
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.26
1
ND
0.33
ND
ND
ND
ND
---
ND
02/13/17
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.26
1
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.26
1
ND
ND
ND
ND
0.44
ND
---
ND
02/04/19
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.48
1
ND
1.1
1.9
ND
ND
ND
---
ND
Appendix OD (Page 18 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-Ga-tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
trans-1,4-Dichloro-2-butene
05/20/98
---
100
ND
ND
5.1
ND
ND
ND
---
---
11/19/98
---
100
ND
ND
ND
ND
ND
ND
---
---
NC2L1�1=NE
07/21/99
---
100
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
100
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
100
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
100
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
100
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
100
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
100
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
100
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
100
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
100
ND
ND
ND
ND
ND
ND
---
ND
07/12/07
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
100
ND
ND
ND
ND
ND
ND
---
ND
12/17/08
1
100
ND
ND
ND
ND
ND
ND
---
ND
07/09/09
1
100
ND
ND
ND
ND
ND
ND
ND
ND
12/16/09
1
100
ND
ND
ND
ND
ND
ND
---
ND
06/24/10
1
100
ND
ND
ND
ND
ND
ND
---
ND
12/13/10
1
100
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
1
100
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
1
100
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
1
100
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
100
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
1
100
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
100
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
1
100
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
100
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
1
100
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
1
100
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
1
100
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
1
100
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
1
100
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
1
100
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
1
100
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
1
100
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.54
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.54
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.54
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.54
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
NR
1
ND
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.56
1
ND
ND
ND
ND
ND
ND
---
ND
Vanadium
09/08/94
---
40
ND
ND
ND
ND
ND
130
---
---
12/01/94
---
40
63
ND
ND
45
ND
ND
---
---
NC2L1�1=7µg/L
02/09/95
---
40
ND
ND
ND
ND
ND
ND
---
---
03/02/95
---
40
41
ND
ND
45
ND
ND
---
---
11/15/95
---
40
ND
ND
ND
ND
ND
ND
---
---
05/28/96
---
40
83
ND
ND
ND
ND
ND
---
---
11/22/96
---
40
7
17
ND
21
ND
ND
---
---
06/17/97
---
40
450
560
ND
19
ND
ND
---
---
12/01/97
---
40
62
88
ND
41
ND
10
---
---
05/20/98
---
40
25
15
ND
10
5
ND
---
---
11/19/98
---
40
33
29
5
16
9
5
---
---
07/21/99
---
40
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
40
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
40
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
40
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
40
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
40
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
40
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
40
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
40
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
40
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
40
ND
ND
ND
ND
ND
ND
-
ND
12/29/04
---
40
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
40
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
40
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
40
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
25
2.7
ND
ND
14.5
ND
1.0
---
ND
07/12/07
---
25
ND
ND
ND
19.4
ND
ND
---
ND
12/19/07
---
25
2.2
2.2
ND
15.7
3
1.2
4.0
0.62
07/08/08
---
25
2.6
2.4
ND
14.6
1.4
1.2
---
0.2
12/17/08
0.2
25
1.9
2.3
ND
13.9
2.5
1.2
---
0.76
07/09/09
0.2
25
3.9
9.7
2.5
18.4
2.9
2.2
8.5
1.3
12/16/09
0.2
25
2.0
4.4
1.3
14.0
2.2
1.5
---
0.53
06/24/10
0.2
25
1.8
4.4
1.5
13.3
2.2
1.3
---
ND
12/13/10
0.2
25
3.2
3.6
0.35
16.6
1.8
1.0
---
0.36
06/20/11
5
25
ND
ND
ND
14.5
ND
ND
---
ND
12/05/11
5
25
ND
ND
ND
13.5
ND
ND
---
ND
06/11/12
5
25
ND
18.0
ND
12.3
ND
ND
ND
ND
12/12/12
5
25
ND
ND
ND
13.6
ND
ND
---
ND
05/01/13
5
25
ND
ND
ND
6.3
ND
ND
ND
ND
08/05/13
5
25
ND
ND
ND
10.2
ND
ND
---
ND
02/24/14
5
25
ND
ND
ND
12.9
ND
ND
ND
ND
08/12/14
5
25
ND
ND
ND
18.6
ND
ND
---
ND
03/10/15
2.5
25
3.1
11.6
6.2
13.4
ND
ND
---
ND
08/18/15
2.5
25
3.4
6.8
3.6
19.6
2.8
ND
---
ND
02/16/16
2.5
25
2.7
3.3
ND
14.4
ND
ND
--
ND
08/09/16
2.5
25
2.5
3.5
ND
21.2
ND
ND
---
ND
02/13/17
2.5
25
4.4
4.1
ND
18.4
3.0
2.9
---
ND
08/22/17
2.5
25
ND
6.6
ND
20.6
2.6
ND
---
ND
02/05/18
2.5
25
3.6
4.4
ND
17.6
ND
2.5
---
ND
08/13/18
2.5
25
ND
5.3
ND
20.4
2.9
ND
---
ND
02/04/19
2.5
5
ND
3.5
ND
12.0
ND
ND
---
ND
08/07/19
1.3
5
2.6
4.1
1.9
22.1
1.7
2.4
---
ND
02/12/20
1.3
5
ND
ND
ND
17.0
ND
1.4
---
ND
08/27/20
3.9
5
ND
ND
ND
21.1
ND
ND
6.8
ND
02/11/21
3.9
5
ND
ND
ND
13.4
ND
ND
7.2
ND
08/19/21
3.9
5
ND
4.8J
ND
ND
ND
ND
ND
ND
02/16/22
3.9
5
ND
5.1
ND
ND
ND
ND
---
ND
Appendix OD (Page 19 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-Ga-tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Vinyl chloride
09/08/94
---
10
ND
ND
12
ND
ND
ND
---
---
12/01/94
---
10
ND
ND
13
ND
ND
ND
---
---
NC21- 0.03 µg/L
02/09/95
---
10
ND
ND
15
ND
ND
ND
---
---
03/02/95
---
10
ND
ND
14
ND
ND
ND
---
---
11/15/95
---
10
ND
ND
11
ND
ND
ND
---
---
05/28/96
---
10
ND
ND
ND
ND
ND
ND
---
---
11/22/96
---
10
ND
ND
ND
ND
ND
ND
---
---
06/17/97
---
10
ND
ND
ND
ND
ND
ND
---
---
12/01/97
---
10
ND
ND
7
4
ND
ND
---
---
05/20/98
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/98
---
10
ND
ND
ND
ND
ND
ND
---
---
07/21/99
---
10
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
10
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
10
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
10
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
10
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
10
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
10
ND
ND
ND
ND
ND
ND
---
---
11/19/02
---
10
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
10
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/05
---
10
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
5.5
ND
ND
0.98
ND
ND
ND
---
ND
02/23/07
---
5.5
--
--
1.0
--
--
--
---
ND
07/12/07
---
1
ND
ND
ND
ND
ND
ND
---
ND
12/19/07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
1
ND
ND
0.76
ND
ND
ND
---
ND
12/17/08
0.62
1
ND
ND
0.76
ND
ND
ND
---
ND
07/09/09
0.62
1
ND
ND
0.99
ND
ND
ND
ND
ND
12/16/09
0.62
1
ND
ND
0.81
ND
ND
ND
---
ND
06/24/10
0.62
1
ND
ND
0.77
ND
ND
ND
---
ND
12/13/10
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
06/20/11
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
06/11/12
0.62
1
ND
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
0.62
1
ND
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.62
1
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.62
1
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.62
1
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.62
1
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.62
1
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.62
1
ND
ND
0.63
ND
ND
ND
---
ND
08/13/18
0.62
1
ND
ND
0.72
ND
ND
ND
--
ND
02/04/19
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.24
1
ND
ND
1.1
ND
ND
ND
---
ND
09/04/19
0.24
1
--
--
ND
--
--
--
---
ND
02/12/20
0.24
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.24
1
ND
ND
1.1
ND
ND
ND
---
ND
09/30/20
0.24
1
--
--
ND
--
--
--
---
ND
02/11/21
0.24
1
ND
ND
0.53
ND
ND
ND
---
ND
08/19/21
0.39
1
ND
ND
0.84J
ND
ND
ND
ND
ND
02/16/22
0.39
1
ND
ND
ND
ND
ND
ND
---
ND
Xylenes, total
12/29/06
---
5
ND
1.4
ND
ND
ND
ND
---
ND
07/12/07
---
4
ND
1.2
ND
ND
ND
ND
---
ND
NC21- 500 µg/L
12/19/07
---
4
ND
2
ND
ND
ND
ND
ND
ND
07/08/08
---
4
ND
1.1
ND
ND
ND
ND
---
ND
12/17/08
0.66
2
1.4
2.7
ND
ND
ND
ND
-
ND
07/09/09
0.66
2
ND
1.5
ND
ND
ND
ND
ND
ND
12/16/09
0.66
2
ND
2.2
ND
ND
ND
ND
---
ND
06/24/10
0.66
2
ND
0.73
ND
ND
ND
ND
---
ND
12/13/10
0.66
2
ND
2
ND
ND
ND
ND
--
ND
06/20/11
0.66
2
ND
1.4
ND
ND
ND
ND
---
ND
12/05/11
0.66
2
ND
1.1
ND
ND
ND
ND
---
ND
06/11/12
0.66
2
ND
0.91
ND
ND
ND
ND
ND
ND
12/12/12
0.66
5
ND
0.97
ND
ND
ND
ND
---
ND
05/01/13
0.66
5
ND
0.68
ND
ND
ND
ND
ND
ND
08/05/13
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
0.66
5
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.66
5
ND
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.66
5
ND
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
02/16/16
0.66
5
ND
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
02/13/17
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
08/22/17
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
02/05/18
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
08/13/18
0.66
5
ND
ND
ND
ND
ND
ND
---
ND
02/04/19
0.63
1
ND
ND
ND
ND
ND
ND
---
ND
08/07/19
0.63
1
ND
ND
ND
ND
ND
ND
---
ND
02/12/20
0.63
1
ND
ND
ND
ND
ND
ND
---
ND
08/27/20
0.63
1
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
0.63
1
ND
ND
ND
ND
ND
ND
---
ND
08/19/21
0.34
1
ND
0.82J
ND
ND
ND
0.351
ND
ND
02/16/22
0.34
1
ND
2.9
3.8
ND
ND
ND
---
ND
Appendix OD (Page 20 of 2!1'r)
bffpsJlbartM1ick,-,epoinLwmisitaslMaslerFles1/8h dD--tslHPA�v to ,Proj,-Ga-tt&MooralGMI-3-Granville Co. Bu- LF12022 First HalfGW-bI--t,-Tables Hart & Hickman, Pl.

Appendix D
Summayr of Hisotircal Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MRL
MW-1R
MW-211
MW-3R
MW-4
MW-5
MW-6
NES-1
BLANKS
Zinc
09/08/94
---
50
110
160
ND
ND
320
430
--
--
12/01/94
---
50
132
ND
ND
70
164
ND
--
--
NC2L hl = 1,000 µg/L
02/09/95
---
50
144
89
ND
91
79
74
---
--
03/02/95
---
50
67
ND
ND
ND
ill
ND
---
--
11/15/95
---
50
ND
50
ND
ND
ND
ND
---
--
05/28/96
---
50
136
ND
ND
ND
122
ND
---
---
11/22/96
---
50
79
48
28
ND
38
ND
---
---
06/17/97
---
50
370
410
33
39
36
69
---
---
12/01/97
---
50
140
110
11
45
34
30
---
---
05/20/98
---
50
70
63
23
31
47
34
---
---
11/19/98
---
50
61
33
21
17
53
10
---
---
07/21/99
---
50
ND
ND
ND
ND
ND
ND
---
---
11/16/99
---
50
ND
ND
ND
ND
ND
ND
---
---
05/10/00
---
50
ND
ND
ND
ND
ND
ND
---
---
10/26/00
---
50
ND
ND
ND
ND
ND
ND
---
---
04/18/01
---
50
ND
ND
ND
ND
ND
ND
---
---
10/27/01
---
50
ND
ND
ND
ND
ND
ND
---
---
06/13/02
---
50
ND
ND
ND
ND
382
ND
---
---
11/19/02
---
50
ND
ND
ND
ND
ND
ND
---
---
06/27/03
---
50
ND
ND
ND
ND
ND
ND
---
---
12/30/03
---
50
ND
ND
ND
ND
ND
ND
---
ND
06/30/04
---
50
ND
ND
ND
ND
ND
ND
---
ND
12/29/04
---
50
ND
ND
ND
66
ND
ND
---
ND
06/29/05
---
50
ND
54
56
ND
ND
ND
---
ND
12/29/05
---
50
ND
ND
ND
ND
ND
ND
---
ND
06/28/06
---
50
ND
ND
ND
ND
ND
ND
---
ND
12/29/06
---
50
8
ND
ND
4.1
4.3
4.1
---
ND
07/12/07
---
10
9.6
ND
ND
ND
ND
ND
---
ND
12/19/07
---
10
4.3
14.3
6.3
ND
ND
ND
2.4
102
07/08/08
---
10
5.9
ND
ND
ND
4.1
ND
---
1.2
12/17/08
0.4
10
2.4
6.3
ND
ND
4.6
0.6
---
0.49
07/09/09
0.4
10
3.4
ND
ND
ND
ND
ND
6.1
1.6
12/16/09
0.4
10
4.6
ND
ND
ND
7.4
ND
---
7.7
06/24/10
0.4
10
0.58
ND
ND
ND
ND
1.3
---
ND
12/13/10
0.4
10
4.5
ND
ND
ND
ND
ND
---
6.7
06/20/11
10
10
ND
ND
ND
ND
ND
ND
---
ND
12/05/11
10
10
ND
ND
ND
ND
ND
ND
---
12.4
06/11/12
10
10
ND
20.9
ND
ND
ND
ND
ND
ND
12/12/12
10
10
ND
ND
ND
ND
ND
ND
---
ND
05/01/13
10
10
ND
ND
ND
ND
11.8
ND
10
ND
08/05/13
10
10
ND
ND
ND
ND
ND
ND
---
ND
02/24/14
10
10
ND
ND
ND
ND
ND
ND
ND
ND
08/12/14
10
10
ND
ND
ND
ND
16.9
ND
---
ND
08/18/15
5
10
7.4
ND
ND
ND
5.2
ND
---
ND
02/16/16
5
10
14.5
16.7
17.8
46.1
5.9
ND
---
ND
08/09/16
5
10
12.0
7.7
ND
ND
ND
ND
---
ND
02/13/17
5
10
12.3
ND
ND
ND
9.8
6
---
ND
08/22/17
5
10
ND
6.3
ND
ND
ND
ND
---
ND
02/05/18
5
10
6.7
17.9
ND
ND
ND
ND
---
ND
08/13/18
5
10
ND
ND
ND
ND
8.1
ND
---
ND
02/04/19
5
10
6.8
ND
5
ND
ND
ND
---
ND
08/07/19
3.9
10
8.3
ND
ND
ND
ND
ND
---
ND
02/12/20
3.9
30
4.3
ND
ND
ND
4.5
ND
---
ND
08/27/20
9.5
10
ND
ND
ND
ND
ND
ND
---
ND
02/11/21
9.5
10
12.9
ND
ND
ND
ND
ND
---
ND
08/19/21
9.5
10
44.2
ND
ND
ND
ND
ND
ND
ND
02/16/22
9.5
10
36.0
ND
ND
ND
ND
ND
ND
Notes:
1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022.
Analytical results from 1994 through 2021 obtained from La Bella 2021 Water Quality Monitoring Report
Bold concentrations exceed the NC 2L Standard.
All results are in micrograms per liter (ug/L).
ND = Not Detected; NR = Not Reported; NE = Not Established; --- = Not Sampled
MDL = Method Detection Limit; MRL = Method Reporting Limit; Blanks = Field Blank
1 = Estimated concentration above the method detection limit but below the laboratory reporting limit.
Appendix D (Page 21 of 21)
M1tlps:llM1aMick.sharepolntcomislteslMasterFiles-1IGM1ared DOoumenta/H -Master Projeote/Gar-&M-IGIAW03-GrenvilleCo. Butner LM022 First Half GWM/rablee/Hlaoa. Tables Hart& Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
INORGANICS
Arsenic
06/24/10
2.7
10.00
4.30 J
2.90 J
ND
12/13/10
2.7
10.0
ND
ND
ND
NC2B tj = 10 pg/L
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
5.0
10.0
---
ND
ND
03/10/15
2.5
10.0
ND
ND
3.0 J
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
10.0
ND
ND
ND
08/09/16
2.5
10.0
3.10 B
ND
5.1 J
02/13/17
5.0
10.0
ND
ND
ND
08/22/17
5.0
10.0
ND
ND
ND
02/05/18
5.0
10.0
ND
ND
ND
08/13/18
5.0
10.0
ND
ND
ND
02/04/19
5.0
10.0
ND
ND
---
08/07/19
4.7
10.0
ND
ND
ND
02/12/20
4.7
10.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
4.7
10.0
---
ND
---
08/19/21
NR
10.0
ND
ND
ND
02/16/22
4.7
1 10.0
6.6 J
ND
---
Barium
11/22/96
---
500
37.0
37.0
---
06/17/97
---
500
37.0
62.0
---
NC2B tj = 1,000 pg/L
12/01/97
---
500
53.0
45.0
---
05/20/98
---
500
24.0
69.0
---
11/19/98
---
500
ND
100
---
07/21/99
---
500
ND
ND
---
11/16/99
---
500
ND
ND
---
05/10/00
---
500
ND
ND
---
10/26/00
---
500
ND
ND
---
04/18/01
---
500
ND
ND
---
10/27/01
---
500
ND
ND
---
06/13/02
---
500
---
---
---
11/19/02
---
500
ND
ND
---
06/27/03
---
500
ND
ND
---
12/30/03
---
500
ND
ND
ND
06/30/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
06/29/05
---
500
ND
ND
ND
12/29/05
---
500
ND
ND
ND
06/28/06
---
500
ND
ND
ND
12/29/06
---
100
37.5
40.6
0.20 J
07/12/07
---
100
33.3 J
---
ND
12/19/07
---
100
52.6 B
149.0
11.7
07/08/08
---
100
33.8 J
161.0
0.3 J
12/17/08
0.2
100
30.2 B
33.5 B
10.7 J
07/09/09
0.2
100
36.8 B
78.4 B
17.6 J
12/16/09
0.2
100
31.2 B
36.2 B
17.1 J
06/24/10
0.2
100
34.5 B
71.3 B
27.3 J
12/13/10
0.2
100
36.1 B
91.0 J
12.1 J
06/20/11
5.0
100
40.3 J
93.0 J
ND
12/05/11
5.0
100
32.9 J
59 .0 J
ND
06/11/12
5.0
100
40.0 J
95.6 J
ND
12/12/12
5.0
100
45.0 J
97.8 J
ND
05/01/13
5.0
100
32.7 J
43.1 J
ND
08/05/13
5.0
100
49.9 J
79.8 J
ND
02/24/14
5.0
100
29.0 J
30.4 J
ND
08/12/14
5.0
100
---
121
ND
03/10/15
2.5
100
29.0 J
32.1 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
100
33.1 J
33 .5 J
ND
08/09/16
2.5
100
43.3 J
105
ND
02/13/17
2.5
100
45.3 J
60.4 J
ND
08/22/17
2.5
100
39.7 J
88 .7 J
ND
02/05/18
2.5
100
32.5 J
29.1 J
ND
08/13/18
2.5
100
70.0 J
86 .6 J
ND
02/04/19
2.5
5
29.1
33.1
---
08/07/19
1.0
5.0
70.0
94.4
ND
02/12/20
1.0
5.0
27.6
30.3
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
3.5
5.0
---
31.20
---
08/19/21
3.5
5.0
45.1
91.90
ND
02/16/22
1 3.5
1 5.0
1 41.8
1 27.9
Appendix E (Page 1 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
Beryllium
07/08/08
---
1.0
0.32 J
ND
ND
12/17/08
0.1
1.0
ND
ND
ND
NC2B tj= 6.5 pg/L
07/09/09
0.1
1.0
ND
ND
ND
12/16/09
0.1
1.0
0.12 J
ND
ND
06/24/10
0.1
1.0
ND
ND
ND
12/13/10
0.1
1.0
ND
ND
ND
06/20/11
1.0
1.0
ND
ND
ND
12/05/11
1.0
1.0
ND
ND
ND
06/11/12
1.0
1.0
ND
ND
ND
12/12/12
1.0
1.0
ND
ND
ND
05/01/13
1.0
1.0
ND
ND
ND
08/05/13
1.0
1.0
ND
ND
ND
02/24/14
1.0
1.0
ND
ND
ND
08/12/14
1.0
1.0
---
ND
ND
03/10/15
0.50
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
0.50
1.0
ND
ND
ND
08/09/16
0.50
1.0
ND
ND
ND
02/13/17
0.50
1.0
ND
ND
ND
08/22/17
0.50
1.0
ND
ND
ND
02/05/18
0.50
1.0
ND
ND
ND
08/13/18
0.50
1.0
ND
ND
ND
02/04/19
0.50
1.0
ND
ND
---
08/07/19
0.20
1.0
ND
ND
ND
02/12/20
0.20
1.0
0.21 J
0.25 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
0.7
1.0
---
ND
---
08/19/21
NR
1.0
ND
ND
ND
02/16/22
0.7
1 1.0
ND
ND
---
Chromium
06/17/97
---
10.0
ND
3.00
---
12/01 /97
---
10.0
ND
ND
---
NC2B tj = 11 pg/L
05/20/98
---
10.0
ND
ND
---
11/19/98
---
10.0
ND
ND
---
07/21 /99
---
10.0
ND
ND
---
11/16/99
---
10.0
ND
ND
---
05/10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
2.20 B
2.60 B
1.40 J
07/08/08
---
10.0
2.50 J
2.20 J
ND
12/17/08
0.4
10.0
1.40 J
2.60 J
ND
07/09/09
0.4
10.0
2.6 J
1 .2 J
ND
12/16/09
0.4
10.0
4.1 J
3.4 J
ND
06/24/10
0.4
10.0
3.3 B
7.3 J
0.71 J
12/13/10
0.4
10.0
1.4 J
1.5 J
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
7.2 J
ND
12/12/12
5.0
10.0
ND
8.2 J
ND
05/01/13
5.0
10.0
5.7 J
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
5.0
10.0
---
ND
ND
03/10/15
2.5
10.0
4.4 J
3.6 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
10.0
4.6 J
6.8 J
ND
08/09/16
2.5
10.0
ND
ND
2.90 J
02/13/17
2.5
10.0
ND
ND
ND
08/22/17
2.5
10.0
ND
ND
ND
02/05/18
2.5
10.0
6.9 J
7.9 J
ND
08/13/18
2.5
10.0
5.9 J
ND
ND
02/04/19
2.5
5.0
ND
ND
---
08/07/19
1.0
5.0
ND
ND
ND
02/12/20
1.0
5.0
5.3
4.7 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
3.7
5.0
---
4.00 J
---
08/19/21
NR
5.0
ND
ND
ND
02/16/22
13.7
5.0
ND
ND
Appendix E (Page 2 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
Cobalt
05/20/98
---
10
2.0
2.0
---
11/19/98
---
10
ND
3.0
---
ISTV (3> = 3 pg/L
07/21/99
---
10
ND
ND
---
11/16/99
---
10
ND
ND
---
05/10/00
---
10
ND
ND
---
10/26/00
---
10
ND
ND
---
04/18/01
---
10
ND
ND
---
10/27/01
---
10.0
ND
22.0
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
10.0
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
4.2 B
1.20 B
1.8 J
07/08/08
---
10.0
4.80 B
10.5 B
6.20 J
12/17/08
0.6
10.0
1.70 B
1.1 B
2.50 J
07/09/09
0.6
10.0
ND
ND
ND
12/16/09
0.6
10.0
ND
1.0 J
ND
06/24/10
0.6
10.0
ND
ND
ND
12/13/10
0.6
10.0
4.4 B
ND
1.6 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
Resampled
01/25/12
5.0
10.0
---
---
ND
06/11/12
5.0
10.0
ND
5.10 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
5.0
10.0
---
ND
ND
03/10/15
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
10.0
ND
ND
ND
08/09/16
2.5
10.0
ND
ND
ND
02/13/17
2.5
10.0
ND
ND
ND
08/22/17
2.5
10.0
ND
ND
ND
02/05/18
2.5
10.0
ND
ND
ND
08/13/18
2.5
10.0
6.0 J
ND
ND
02/04/19
2.5
5.0
ND
ND
---
08/07/19
1.1
5.0
2.5 J
ND
ND
02/12/20
1.1
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
3.6
5.0
---
ND
---
08/19/21
NR
5.0
ND
ND
ND
02/16/22
3.6
5.0
ND
ND
---
Copper
12/29/06
---
10.0
1.3 B
1.10 B
0.60 J
07/12/07
---
10.0
ND
---
ND
NRWQC 121 = 1,300 pg/L
12/19/07
---
10.0
5.3 B
ND
9.8
07/08/08
---
10.0
1.7 J
4.20 J
ND
12/17/08
0.3
10.0
1.40 J
1.50 J
ND
07/09/09
0.3
10.0
ND
ND
ND
12/16/09
0.3
10.0
1.90 J
2.00 J
ND
06/24/10
0.3
10.0
ND
3.10 J
ND
12/13/10
0.3
10.0
0.31 B
ND
0.49 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
5.50 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
5.0
10.0
---
ND
ND
03/10/15
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
10.0
2.90 J
3.40 J
ND
08/09/16
2.5
10.0
ND
ND
ND
02/13/17
2.5
10.0
ND
ND
ND
08/22/17
2.5
10.0
ND
ND
ND
2/5/2018
2.5
10
3.8 J
3.8 J
ND
08/13/18
2.5
10.0
4.1 J
ND
ND
02/04/19
2.5
5.0
ND
ND
---
08/07/19
2.1
5.0
3.2 J
3.3 J
ND
02/12/20
2.1
5.0
3.9 J
3.4 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
4.3
5.0
---
ND
---
08/19/21
NR
5.0
ND
ND
ND
02/16/22
1 4.3
1 5.0
1 ND
I ND
Appendix E (Page 3 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
Lead
05/20/98
---
10.0
ND
8.00
---
11/19/98
---
10.0
ND
ND
---
NC2B tj = 1.70 pg/L
07/21/99
---
10.0
ND
10.0
---
NC2B = Hardness Dependent
11/16/99
---
10.0
ND
ND
---
05/10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
ND
ND
ND
07/08/08
---
10.0
ND
ND
ND
12/17/08
4.0
10.0
ND
ND
ND
07/09/09
4.0
10.0
ND
ND
ND
12/16/09
4.0
10.0
ND
ND
ND
06/24/10
4.0
10.0
ND
ND
ND
12/13/10
4.0
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
5.0
10.0
---
ND
ND
03/10/15
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
10.0
ND
ND
ND
08/09/16
2.5
10.0
ND
ND
ND
02/13/17
2.5
10.0
ND
ND
ND
08/22/17
2.5
10.0
ND
ND
ND
2/5/2018
2.5
10.0
ND
ND
ND
08/13/18
2.5
10.0
ND
ND
ND
02/04/19
2.5
5.0
ND
ND
---
08/07/19
1.6
5.0
2.2 J
ND
ND
02/12/20
1.6
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
4.5
5.0
---
ND
---
08/19/21
NR
5.0
ND
ND
ND
02/16/22
4.5
1 5.0
ND
ND
---
Nickel
12/29/04
---
50.0
ND
ND
ND
06/29/05
---
50.0
ND
ND
ND
NC2B tj=25 pg/L
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
2.9 J
ND
07/12/07
---
50.0
3.8 J
---
ND
12/19/07
---
50.0
6.0
31.5
ND
07/08/08
---
50.0
3.2 J
29.8 J
ND
12/17/08
1.7
50.0
2.4 B
4.0 B
2.4 J
07/09/09
1.7
50.0
4.1 J
12.3 J
ND
12/16/09
1.7
50.0
3.8 B
4.4 B
3.0 J
06/24/10
1.7
50.0
ND
2.0 J
ND
12/13/10
1.7
50.0
ND
14.2 J
2.7 J
06/20/11
5.0
50.0
ND
7.8 J
ND
12/05/11
5.0
50.0
ND
5.3 J
ND
06/11/12
5.0
50.0
ND
11.0 J
ND
12/12/12
5.0
50.0
ND
13 .8 J
ND
05/01/13
5.0
50.0
ND
ND
ND
08/05/13
5.0
50.0
ND
5.6 J
ND
02/24/14
5.0
50.0
ND
ND
ND
08/12/14
5.0
50.0
---
20.3 J
ND
03/10/15
2.5
50.0
3.0 J
3.8 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
50.0
2.9 J
4.7 J
ND
08/09/16
2.5
50.0
3.3 J
15.2 J
ND
02/13/17
2.5
50.0
ND
7.3 J
ND
08/22/17
2.5
50.0
ND
16 .3 J
ND
02/05/18
2.5
50
5.3 J
4.4 J
ND
08/13/18
2.5
50.0
7.3 J
12.4 J
ND
02/04/19
2.5
5.0
ND
2.7 J
---
08/07/19
0.90
5.0
8.8
14.8
ND
02/12/20
0.90
5.0
3.1 J
4.6 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
3.5
5.0
---
4.40 J
---
08/19/21
3.5
5.0
ND
25.1
ND
02/16/22
1 3.5
1 5.0
1 6.5
1 ND
Appendix E (Page 4 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
Silver
07/12/07
---
10.0
2.20 J
---
ND
12/19/07
---
10.0
ND
0.34 J
ND
NC2B tj = 0.06 pg/L
07/08/08
---
10.0
0.35 B
1.00 J
0.12 J
12/17/08
0.1
10.0
ND
ND
ND
07/09/09
0.1
10.0
ND
0.10 J
ND
12/16/09
0.1
10.0
ND
0.16 J
ND
06/24/10
0.1
10.0
ND
0.26 J
ND
12/13/10
0.1
10.0
ND
0 .28 B
0.21 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
5.0
10.0
---
ND
ND
03/10/15
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
10.0
ND
ND
ND
08/09/16
2.5
10.0
ND
ND
ND
02/13/17
2.5
10.0
ND
ND
ND
08/22/17
2.5
10.0
ND
ND
ND
02/05/18
2.5
10.0
ND
ND
ND
08/13/18
2.5
10.0
ND
ND
ND
02/04/19
2.5
5.0
ND
ND
---
08/07/19
2.5
5.0
ND
ND
ND
02/12/20
2.5
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
2.5
5.0
---
ND
---
08/19/21
NR
5.0
ND
ND
ND
02/16/22
2.5
1 5.0
ND
ND
---
Thallium
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
ISTV 3 = 2 pg/L
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
6.00
ND
ND
ND
07/12/07
---
5.5
ND
---
ND
12/19/07
---
5.5
3.60 J
ND
ND
07/08/08
---
5.5
3.40 J
ND
ND
12/17/08
3.0
5.5
ND
ND
ND
07/09/09
3.0
5.5
ND
ND
ND
12/16/09
3.0
5.5
ND
ND
ND
06/24/10
3.0
5.5
ND
ND
ND
12/13/10
3.0
5.5
3.80 J
ND
ND
06/20/11
5.4
5.5
ND
ND
ND
12/05/11
5.4
5.5
ND
ND
ND
06/11/12
5.4
5.5
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
05/01/13
5.4
5.5
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
02/24/14
5.4
5.5
ND
ND
ND
08/12/14
5.4
5.5
---
ND
ND
03/10/15
5.0
5.5
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
5.0
5.5
ND
ND
ND
08/09/16
5.0
5.5
ND
ND
ND
02/13/17
0.020
5.5
ND
ND
ND
08/22/17
0.020
5.5
ND
ND
ND
02/05/18
0.028
0.10
ND
ND
ND
08/13/18
0.020
5.50
ND
ND
ND
02/04/19
0.060
0.10
ND
ND
---
08/07/19
0.060
0.10
ND
ND
ND
02/12/20
0.060
0.10
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
0.1
0.1
---
ND
---
08/19/21
NR
0.47
ND
ND
ND
02/16/22
1 0.05
1 0.47
1 ND
I ND
Appendix E (Page 5 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
Vanadium
12/29/06
---
25.0
1.60 J
2.00 J
ND
07/12/07
---
25.0
4.60 J
---
ND
SWSL(4) 25 pg/L
12/19/07
---
25.0
3.30 J
1.40 B
0.62 J
07/08/08
---
25.0
5.20 J
2.30 J
0.20 J
12/17/08
0.2
25.0
1.80 B
2.70 B
0.76 J
07/09/09
0.2
25.0
5.00 B
3.40 B
1.30 J
12/16/09
0.2
25.0
3.60 J
3.50 J
0.53 J
06/24/10
0.2
25.0
5.80 J
2.60 J
ND
12/13/10
0.2
25.0
1.60 B
0.67 B
0.36 J
06/20/11
5.0
25.0
ND
ND
ND
12/05/11
5.0
25.0
ND
ND
ND
06/11/12
5.0
25.0
ND
11.5 J
ND
12/12/12
5.0
25.0
ND
ND
ND
05/01/13
5.0
25.0
ND
ND
ND
08/05/13
5.0
25.0
ND
ND
ND
02/24/14
5.0
25.0
ND
ND
ND
08/12/14
5.0
25.0
---
ND
ND
03/10/15
2.5
25.0
3.9 J
4.7 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
2.5
25.0
4.1 J
5.8 J
ND
08/09/16
2.5
25.0
2.9 J
2.8 J
ND
02/13/17
2.5
25.0
ND
ND
ND
08/22/17
2.5
25.0
2.8 J
ND
ND
02/05/18
2.5
25.0
6.6 J
5.9 J
ND
08/13/18
2.5
25.0
8.3 J
3.1 J
ND
02/04/19
2.5
5.0
2.9 J
2.7 J
---
08/07/19
1.3
5.0
1.4 J
2.3 J
ND
02/12/20
1.3
5.0
4.5 J
5.0
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
3.9
5.0
---
ND
---
08/19/21
NR
5.0
ND
ND
ND
02/16/22
3.9
1 5.0
ND
4.4
---
Zinc
11/22/96
---
50.0
11.0
ND
---
06/17/97
---
50.0
ND
ND
---
NC2B tj = 86.62 pg/L
12/01/97
---
50.0
20.0
ND
---
NC2B = Hardness Dependent
05/20/98
---
50.0
20.0
28.0
---
11/19/98
---
50.0
ND
ND
---
07/21/99
---
50.0
ND
ND
---
11/16/99
---
50.0
ND
ND
---
05/10/00
---
50.0
ND
ND
---
10/26/00
---
50.0
ND
ND
---
04/18/01
---
50.0
ND
ND
---
10/27/01
---
50.0
ND
ND
---
06/13/02
---
50.0
---
---
---
11/19/02
---
50.0
ND
ND
---
06/27/03
---
50.0
ND
ND
---
12/30/03
---
50.0
ND
ND
ND
06/30/04
---
50.0
ND
ND
ND
12/29/04
---
50.0
ND
ND
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
24.6 B
ND
102
07/08/08
---
10.0
ND
ND
1.20 J
12/17/08
0.4
10.0
ND
0.89 B
0.49 J
07/09/09
0.4
10.0
ND
4.90 B
1.60 J
12/16/09
0.4
10.0
2.60 B
2.60 B
7.70 J
06/24/10
0.4
10.0
ND
14.9
ND
12/13/10
0.4
10.0
ND
9.80 B
6.70 J
06/20/11
10.0
10.0
ND
ND
ND
12/05/11
10.0
10.0
ND
ND
12.4
06/11/12
10.0
10.0
ND
ND
ND
12/12/12
10.0
10.0
ND
ND
ND
05/01/13
10.0
10.0
ND
16.80
ND
08/05/13
10.0
10.0
ND
ND
ND
02/24/14
10.0
10.0
ND
ND
ND
08/12/14
10.0
10.0
---
ND
ND
03/10/15
5.0
10.0
7.7 B
7.8 B
5.6 J
08/18/15
---
---
Dry
Dry
---
02/16/16
5.0
10.0
7.0 J
ND
ND
08/09/16
5.0
10.0
ND
ND
ND
02/13/17
5.0
10.0
ND
5.2 J
ND
08/22/17
5.0
10.0
ND
ND
ND
2/5/2018
5.0
10.0
ND
ND
ND
08/13/18
5.0
10.0
6.0 J
ND
ND
02/04/19
5.0
10.0
ND
ND
---
08/07/19
3.9
10.0
ND
ND
ND
02/12/20
3.9
10.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
9.5
10.0
---
ND
---
08/19/21
NR
10.0
ND
ND
ND
02/16/22
9.5
1 10.0
ND
ND
---
Total Hardness (SM 2340B)
02/04/19
662
662
57.1
85.3
---
08/07/19
131
662
316
460
ND
02/12/20
131
662
18,300
60,200
---
08/27/20
---
---
---
---
Appendix E (Page 6 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
ORGANICS
Acetone
10/27/01
---
100
168 B
337 B
479
06/13/02
---
100
---
---
---
ISTV (3> = 3,100 Ng/L
06/13/02
---
100
---
---
---
11/19/02
---
100
ND
ND
---
06/27/03
---
100
ND
ND
---
12/30/03
---
100
ND
ND
ND
06/30/04
---
100
ND
ND
ND
12/29/04
---
100
ND
ND
ND
06/29/05
---
100
ND
ND
ND
12/29/05
---
100
ND
ND
ND
06/28/06
---
100
ND
ND
ND
12/29/06
---
100
ND
ND
ND
07/12/07
---
100
ND
---
ND
12/19/07
---
100
12.7 B
ND
4.50 J
07/08/08
---
100
ND
ND
ND
12/17/08
20
100
ND
ND
ND
07/09/09
20
100
ND
ND
ND
12/16/09
2.2
100
ND
ND
2.80 J
06/24/10
2.2
100
2.80 B
ND
7.70 J
12/13/10
2.2
100
ND
3.00 J
ND
06/20/11
2.2
100
ND
3.80 B
3.90 J
12/05/11
2.2
100
ND
7.20 B
8.80 J
06/11/12
2.2
100
ND
5.50 B
4.70 J
12/12/12
10.0
100
ND
ND
ND
05/01/13
10.0
100
ND
ND
14.6 J
08/05/13
10.0
100
ND
ND
ND
02/24/14
10.0
100
ND
ND
25.7 J
08/12/14
10.0
100
---
ND
22.0 J
03/10/15
10.0
100
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
10.0
100
ND
ND
ND
08/09/16
10.0
100
ND
ND
ND
02/13/17
10.0
100
ND
ND
ND
08/22/17
10.0
100
ND
ND
ND
02/05/18
10.0
100
ND
ND
ND
08/13/18
10.0
100
ND
ND
ND
02/04/19
6.2
25
ND
ND
---
08/07/19
6.2
25.0
ND
ND
ND
02/12/20
6.2
25.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
6.2
25.0
---
ND
---
08/19/21
NR
25.0
ND
ND
ND
02/16/22
5.1
25.0
ND
ND
---
Chlorobenzene
06/27/03
---
5.0
ND
7.20
ND
12/30/03
---
5.0
ND
ND
ND
NC2B 1) = 488 lag/L
06/30/04
---
5.0
ND
ND
ND
12/29/04
---
5.0
ND
ND
ND
06/29/05
---
5.0
ND
ND
ND
12/29/05
---
5.0
ND
ND
ND
06/28/06
---
5.0
ND
ND
ND
12/29/06
---
3.0
ND
ND
ND
07/12/07
---
3.0
ND
---
ND
12/19/07
---
3.0
ND
ND
ND
07/08/08
---
3.0
ND
ND
ND
12/17/08
0.23
3.0
ND
ND
ND
07/09/09
0.23
3.0
ND
ND
ND
12/16/09
0.23
3.0
ND
ND
ND
06/24/10
0.23
3.0
ND
ND
ND
12/13/10
0.23
3.0
ND
ND
0.28 J
06/20/11
0.23
3.0
ND
ND
ND
12/05/11
0.23
3.0
ND
ND
ND
06/11/12
0.23
3.0
ND
ND
ND
12/12/12
0.23
3.0
ND
ND
ND
05/01/13
0.23
3.0
ND
ND
ND
08/05/13
0.23
3.0
ND
ND
ND
02/24/14
0.23
3.0
ND
ND
ND
08/12/14
0.23
3.0
---
ND
ND
03/10/15
0.23
3.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
0.23
3.0
ND
ND
ND
08/09/16
0.23
3.0
ND
ND
ND
02/13/17
0.23
3.0
ND
ND
ND
08/22/17
0.23
3.0
ND
ND
ND
02/05/18
0.23
3.0
ND
ND
ND
08/13/18
0.23
3.0
ND
ND
ND
02/04/19
0.23
1.0
ND
ND
---
08/07/19
0.23
1.0
ND
ND
ND
02/12/20
0.23
1.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
0.2
1.0
---
ND
---
08/19/21
NR
1.0
ND
ND
ND
02/16/22
1 0.28
1 1.0
1 ND
IND
Appendix E (Page 7 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
MRL
SW-1
SW-2
Blanks
Chloromethane
07/09/09
0.11
1.0
ND
0.19 J
ND
12/16/09
0.11
1.0
ND
ND
ND
NC2B tj = NE
06/24/10
0.11
1.0
ND
ND
ND
12/13/10
0.11
1.0
ND
ND
ND
06/20/11
0.11
1.0
ND
ND
ND
12/05/11
0.11
1.0
ND
ND
ND
06/11/12
0.11
1.0
ND
ND
ND
12/12/12
0.11
1.0
ND
ND
ND
05/01/13
0.11
1.0
ND
ND
ND
08/05/13
0.11
1.0
ND
ND
ND
02/24/14
0.11
1.0
ND
ND
0.25 J
08/12/14
0.11
1
---
ND
ND
03/10/15
0.11
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
0.11
1.0
ND
ND
ND
08/09/16
0.11
1.0
ND
ND
ND
02/13/17
0.11
1.0
0.17 J
0.19 J
0.18 J
08/22/17
0.11
1.0
ND
ND
ND
02/05/18
0.11
1.0
ND
ND
ND
08/13/18
0.11
1.0
ND
ND
ND
02/04/19
0.39
1.0
ND
ND
---
08/07/19
0.39
1.0
ND
ND
ND
02/12/20
0.39
1.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
0.4
1.0
---
ND
---
08/19/21
NR
1.0
ND
ND
ND
02/16/22
0.5
1.0
ND
ND
---
1,4-Dioxane (p-Dioxane)
08/13/18
1.9
2.0
ND
14.1
ND
02/04/19
1.9
2.0
ND
ND
---
ISTV (3)= 0.35 ua/L
08/07/19
1.2
2.0
10.50
22.3
ND
02/12/20
1.2
2.0
ND
1.2 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
1.2
2.0
---
3.00
---
08/19/21
1.0
2.0
ND
26.0
ND
02/16/22
0.86
1 2.0
6.0
ND
---
Methylene Chloride
08/09/16
0.97
1.0
ND
ND
2.20 J
02/13/17
0.97
1.0
ND
ND
ND
NRWQC (2) = 20 pg/L
08/22/17
0.97
1.0
ND
ND
1.4 C9
02/05/18
0.97
1.0
ND
ND
ND
08/13/18
0.97
1.0
ND
ND
6.60
02/04/19
3.7
5.0
ND
ND
---
08/07/19
3.7
5.0
ND
ND
ND
02/12/20
3.7
5.0
ND
ND
ND
08/27/20
---
Dry
Dry
2/11/2021
3.7
5.0
---
ND
---
08/19/21
NR
5.0
ND
ND
12.9
2/16/2022
2.0
1 5.0
ND
I ND
I ---
Notes:
1. 15A NCAC 2B Water Quality Standards (213 Standards) for Surface Water (Class WS IV, nutrient sensitive waters [NSW]).
2. No 2B Standard established, value shown is EPA Nationally Recommended Water Quality Criteria (NRWQC) for Aquatic
Life & Human Health.
3. No 2B Standard or NWQC established, value shown is North Carolina In -Stream Target Values for Surface Waters (ISTV).
4. No 2B Standard, NWQC, or ISTV established, value shown is Solid Waste Section Limits (SWSL).
Analytical results from 1996 through 2021 obtained from LaBella 2021 Water Quality Monitoring Report.
Bold concentrations exceed the NC 2B Standard.
All concentrations are in micrograms per liter (pg/L).
J = Estimated concentration above the adjusted method detection limit and below the adjusted method reporting limit;
MRL = method reporting limit; MDL = laboratory detection limit; ND = Not detected above laboratory method reporting limit;
B = Blank -qualified data, result is expected to be biased high based on concentrations in the blanks
NR = Not Reported; NE= Not established; --- = Not Sampled.
Appendix E (Page 8 of 8)
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, PC

Appendix F
Summary of Historical Monitoring Natural Attenuation Parameters
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Temperature (FP)
12/30/2003
°C
---
---
15.40
11.10
11.20
12.50
13.60
14.20
---
12/19/2007
°C
---
---
12.30
12.50
13.10
14.40
14.90
14.40
13.30
5/1/2013
°C
---
---
15.70
13.70
15.10
14.40
14.20
14.20
12.50
8/14/2014
°C
---
---
17.80
18.00
19.20
19.40
16.80
17.20
16.00
3/10/2015
°C
---
---
17.30
16.00
15.90
13.80
13.30
13.70
16.10
8/18/2015
°C
---
---
16.43
17.78
17.79
17.25
16.47
16.64
16.05
2/16/2016
°C
---
---
14.60
13.80
14.40
14.00
12.00
13.40
13.10
8/9/2016
°C
---
---
16.40
17.30
19.40
18.20
17.10
16.80
17.90
2/13/2017
°C
---
---
14.80
14.40
14.90
15.70
14.10
15.30
15.20
8/22/2017
°C
---
---
17.40
17.90
17.90
17.50
17.40
16.60
17.80
2/5/2018
°C
---
---
13.06
11.66
13.05
14.46
13.83
14.53
12.25
8/13/2018
°C
---
---
17.40
21.10
18.20
19.30
20.60
18.40
16.60
2/4/2019
°C
---
---
13.20
15.50
16.50
14.90
14.50
15.40
13.70
8/6/2019
°C
---
---
17.00
22.70
17.60
19.90
17.30
18.20
16.00
8/14/2019
°C
---
---
---
---
---
---
---
24.30
---
2/12/2020
°C
---
---
17.20
14.30
14.80
16.50
15.10
16.40
14.80
8/27/2020
°C
---
---
17.20
18.90
19.90
22.20
20.30
21.10
20.10
9/30/2020
°C
---
---
---
---
19.30
---
---
--
2/11/2021
°C
---
---
15.10
12.40
13.60
11.80
11.50
11.30
14.00
8/19/2021
°C
---
---
19.70
19.40
19.90
25.30
19.30
22.30
17.70
2/16/2022
°C
---
---
14.90
1 20.60
10.70
16.90
14.20
1 10.40
14.70
pH (FP)
12/30/2003
S.U.
---
---
7.31
6.54
6.81
6.90
7.24
7.29
---
12/19/2007
S.U.
---
---
6.89
6.90
7.07
6.87
7.39
6.67
7.64
5/1/2013
S.U.
---
---
7.32
6.37
6.61
6.42
6.92
7.13
6.10
8/14/2014
S.U.
---
---
5.84
6.36
6.96
6.79
7.00
6.48
5.59
3/10/2015
S.U.
---
---
6.11
6.37
6.56
6.30
6.25
6.55
5.68
8/18/2015
S.U.
---
---
5.12
6.68
6.48
6.76
7.03
6.78
4.94
2/16/2016
S.U.
---
---
6.15
6.15
6.61
6.69
7.14
6.10
6.52
8/9/2016
S.U.
---
---
4.79
5.05
5.30
5.06
4.41
5.75
6.46
2/13/2017
S.U.
---
---
6.10
6.55
6.76
6.78
6.24
7.37
6.23
8/22/2017
S.U.
---
---
6.58
6.46
6.45
6.98
7.53
7.16
7.16
2/5/2018
S.U.
---
---
7.11
6.80
7.01
7.33
7.22
7.54
5.53
8/13/2018
S.U.
---
---
6.30
6.45
6.64
6.38
7.15
7.03
5.54
2/4/2019
S.U.
---
---
6.17
6.44
7.16
6.87
6.07
7.02
5.13
8/6/2019
S.U.
---
---
8.84
6.17
6.49
6.69
7.44
7.49
6.79
8/14/2019
S.U.
---
---
---
---
---
---
---
6.47
---
2/12/2020
S.U.
---
---
5.63
4.88
6.30
6.73
6.27
7.10
8.72
8/27/2020
S.U.
---
---
5.08
6.13
6.42
6.45
6.71
6.73
5.48
9/30/2020
S.U.
---
---
---
---
6.57
---
---
---
---
2/11/2021
S.U.
---
---
5.65
6.13
6.45
5.94
6.30
6.15
4.38
8/19/2021
S.U.
---
---
5.52
6.27
6.59
6.36
6.52
6.60
4.94
2/16/2022
S.U.
---
---
5.64
6.29
6.77
6.41
6.73
6.62
4.95
Conductivity (FP)
12/19/2007
PS/cm
---
---
96.00
1964.00
1591.00
1245.00
---
---
510.00
5/1/2013
PS/cm
---
---
111.00
1587.00
1357.00
1150.00
195.00
594.00
69.60
8/14/2014
PS/cm
---
---
231.00
1897.00
1534.00
1413.00
522.00
565.00
172.60
3/10/2015
PS/cm
---
---
90.00
996.00
1277.00
1186.00
106.00
504.00
114.00
8/18/2015
PS/cm
---
---
134.00
1630.00
1680.00
1244.00
617.00
534.00
83.00
2/16/2016
PS/cm
---
---
72.40
1611.00
1369.00
1234.00
164.00
474.00
78.20
8/9/2016
PS/cm
---
---
100.70
1924.00
1535.00
1475.00
660.00
600.00
95.60
2/13/2017
PS/cm
---
---
68.00
1535.00
1314.00
1155.00
272.00
508.00
89.60
8/22/2017
PS/cm
---
---
77.10
1,752
1350.00
1446.00
755.00
560.00
175.00
2/5/2018
PS/cm
---
---
80.00
1460.00
1247.00
1230.00
676.00
633.00
50.00
8/13/2018
PS/cm
---
---
101.20
2013.00
1608.00
1569.00
870.00
620.00
131.20
2/4/2019
PS/cm
---
---
107.90
1692.00
1266.00
1364.00
276.10
546.00
91.60
8/6/2019
PS/cm
---
---
113.40
1719.00
1307.00
1287.00
775.00
545.30
98.50
8/14/2019
PS/cm
---
---
---
---
---
---
---
559.00
---
2/12/2020
PS/cm
---
---
94.80
1946.00
1475.00
1471.00
276.90
588.30
95.50
8/27/2020
PS/cm
---
---
82.40
1601.00
1217.00
1335.00
773.00
577.00
140.50
9/30/2020
PS/cm
---
---
---
---
1409.00
---
---
---
---
2/11/2021
PS/cm
---
---
85.20
1251.00
1004.00
838.00
211.30
323.80
65.90
8/19/2021
PS/cm
---
---
127.40
206.20
1568.00
1658.00
1044.00
630.00
125.60
2/16/2022
PS/cm
---
---
91.60
2095.00
1543.00
1421.00
1056.00
604.80
81.40
Redox Potential (ORP) (FP)
12/30/2003
mV
---
---
257 .2
76.20
207 .6
212.70
187.30
123.60
---
12/19/2007
mV
---
---
146.00
45.00
142.00
134.00
---
---
138.00
5/1/2013
mV
---
---
111.70
-26.70
55.20
120.50
---
---
227.10
8/14/2014
mV
---
---
115.80
-37.20
86.90
---
---
---
---
3/10/2015
mV
---
---
87.00
0.80
56.30
---
---
---
96.70
8/18/2015
mV
---
---
134.70
-96.30
-68.80
-33.90
-49.90
---
182.80
2/16/2016
mV
---
---
111.70
-47.30
16.90
---
---
---
173.40
8/9/2016
mV
---
---
56.00
-43.10
-6.90
---
---
---
---
2/13/2017
mV
---
---
87.40
0.80
-16.50
---
---
---
---
8/22/2017
mV
---
---
102.90
-37.10
87.00
---
---
---
116.70
2/5/2018
mV
---
---
57.10
29.50
49.40
---
---
---
109.20
8/13/2018
mV
---
---
117.90
-60.50
-49.30
---
---
64.40
28.40
2/4/2019
mV
---
---
197.70
-64.30
132.20
---
9.60
---
281.20
8/6/2019
mV
---
---
164.70
-69.30
-33.70
171.60
188.60
232.60
231.80
8/14/2019
mV
---
---
---
---
---
---
---
237.60
---
2/12/2020
mV
---
---
336.50
33.40
22.40
254.50
299.90
282.00
245.60
8/27/2020
mV
---
---
242.70
-10.80
12.40
190.30
196.50
188.00
240.60
9/30/2020
mV
---
---
---
---
232.30
---
---
---
---
2/11/2021
mV
---
---
166.80
4.10
34.80
197.40
---
278.80
284.50
8/19/2021
mV
---
---
112.30
65.00
79.90
58.70
52.50
125.00
42.30
2/16/2022
mV
---
I ---
1 172.30
1 -48.00
1 -8.80
1 88.00
1 -1.50
1 194.70
1 282.80
Appendix F (Page 1 of /6)
hftps:/Iharthick.shampoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Oxygen (DO) (FP)
12/30/2003
mg/L
---
---
9.49
4.84
---
---
---
---
---
12/19/2007
mg/L
---
---
---
1.88
1.44
3.21
---
---
0.70
5/1/2013
mg/L
---
---
4.40
1.37
1.79
4.65
---
---
2.90
8/14/2014
mg/L
---
---
4.44
3.26
2.48
---
---
---
2.80
3/10/2015
mg/L
---
---
3.84
1.47
1.80
---
---
---
1.85
8/18/2015
mg/L
---
---
4.95
5.75
1.30
---
3.79
---
1.77
2/16/2016
mg/L
---
---
4.45
3.66
2.51
---
---
---
3.72
8/9/2016
mg/L
---
---
3.17
2.87
2.29
---
---
---
---
2/13/2017
mg/L
---
---
5.37
3.16
2.14
---
---
---
---
8/22/2017
mg/L
---
---
5.43
2.24
4.02
---
---
---
5.86
2/5/2018
mg/L
---
---
8.08
6.61
9.16
---
---
---
8.36
8/13/2018
mg/L
---
---
6.31
3.20
2.35
---
---
4.80
3.91
2/4/2019
mg/L
---
---
1.26
1.82
4.17
---
4.17
---
1.63
8/6/2019
mg/L
---
---
3.77
0.32
0.26
4.55
5.30
2.76
3.04
8/14/2019
mg/L
---
---
---
---
---
---
---
1.95
---
2/12/2020
mg/L
---
---
5.11
0.65
1.36
4.30
3.48
2.44
6.37
8/27/2020
mg/L
---
---
0.63
0.22
0.48
5.04
6.22
4.14
3.16
9/30/2020
mg/L
---
2.00
---
---
---
---
2/11/2021
mg/L
---
---
1.75
1.05
0.40
7.40
5.41
3.23
2.18
8/19/2021
mg/L
---
---
0.68
3.55
1.02
0.31
0.19
1.88
2.07
2/16/2022
mg/L
---
---
2.06
0.14
1 0.99
0.34
0.32
3.62
1 2.94
Dissolved CO2 (FP)
12/19/2007
mg/L
--
---
25.00
365.00
175.00
295.00
---
---
60.00
5/1/2013
mg/L
---
---
30.00
245.00
125.00
225.00
---
---
45.00
8/14/2014
mg/L
---
---
60.00
390.00
185.00
---
---
---
75.00
3/10/2015
mg/L
---
---
50.00
110.00
75.00
---
---
---
50.00
8/18/2015
mg/L
---
---
30.00
275.00
125.00
---
---
---
60.00
2/16/2016
mg/L
---
---
30.00
210.00
230.00
---
---
---
20.00
8/9/2016
mg/L
---
185.00
210.00
---
---
---
---
2/13/2017
mg/L
---
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
---
2/4/2019
mg/L
---
---
75.00
---
130.00
---
---
---
---
8/6/2019
mg/L
---
475.00
250.00
---
---
---
---
2/12/2020
mg/L
---
---
---
260.00
---
---
---
---
---
8/27/2020
mg/L
---
---
---
---
---
---
2/11/2021
mg/L
---
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
---
2/16/2022
mg/L
---
---
--
---
---
---
---
---
---
Fe, Ferrous (+2) (FP)
12/30/2003
mg/L
---
---
ND
1.50
ND
ND
0.22
ND
---
12/19/2007
mg/L
---
---
ND
7.20
ND
ND
---
---
0.20
5/1/2013
mg/L
---
ND
1.00
ND
ND
---
---
ND
8/14/2014
mg/L
---
---
ND
2.50
ND
---
---
---
ND
3/10/2015
mg/L
---
---
ND
5.30
ND
---
---
---
ND
8/18/2015
mg/L
---
---
ND
4.50
1.00
---
---
---
ND
2/16/2016
mg/L
---
---
ND
4.00
1.30
---
---
---
ND
8/9/2016
mg/L
---
---
---
3.10
1.00
---
---
---
---
2/13/2017
mg/L
---
ND
3.00
1.50
---
---
---
8/22/2017
mg/L
---
---
N D
3.50
1.50
---
---
---
N D
2/5/2018
mg/L
---
---
N D
4.00
0.50
---
---
---
N D
8/13/2018
mg/L
---
ND
5.50
0.20
---
---
---
---
2/4/2019
mg/L
---
---
ND
---
ND
---
---
---
---
8/6/2019
mg/L
---
---
---
3.50
0.50
---
---
---
---
2/12/2020
mg/L
---
---
---
1.00
0.50
---
---
---
---
8/27/2020
mg/L
---
---
---
4.50
1.00
---
---
---
---
2/11/2021
mg/L
---
---
0.00
1.50
0.50
---
---
---
0.00
8/19/2021
mg/L
---
---
---
---
---
2/16/2022
mg/L
---
---
---
---
---
---
---
---
---
Alkalinity (CaCO3)
12/30/2003
mg/L
9.00
10.00
37.00
800.00
690.00
640.00
68.00
350.00
---
12/19/2007
mg/L
---
5.00
39.00
763.00
726.00
619.00
---
---
190.00
5/1/2013
mg/L
1.00
5.00
43.40
757.00
660.00
645.00
---
---
10.40
8/14/2014
mg/L
1.00
5.00
41.10
784.00
661.00
---
---
---
14.50
3/10/2015
mg/L
1.00
5.00
38.00
744.00
653.00
---
---
---
8.80
8/18/2015
mg/L
1.00
5.00
37.80
772.00
664.00
---
---
---
10.30
2/16/2016
mg/L
1.00
5.00
41.20
792.00
741.00
---
---
---
8.73
8/9/2016
mg/L
1.00
5.00
---
783.00
629.00
---
---
---
---
2/13/2017
mg/L
1.00
5.00
37.90
753.00
654.00
---
---
---
8.79
8/22/2017
mg/L
1.00
5.00
42.40
766.00
678.00
---
---
---
10.20
2/5/2018
mg/L
1.00
5.00
44.40
821.00
752.00
---
---
---
7.52
8/13/2018
mg/L
1.00
5.00
---
768.00
722.00
---
---
---
---
2/4/2019
mg/L
1.00
5.00
62.00
856.00
638.00
---
---
---
7.02
8/6/2019
mg/L
5.00
5.00
---
839.00
754.00
---
---
---
---
2/2/2020
mg/L
5.00
5.00
---
818.00
646.00
---
---
---
---
8/27/2020
mg/L
5.00
5.00
47.60
909.00
735.00
---
---
---
---
2/11/2021
mg/L
5.00
5.00
53.90
875.00
724.00
---
---
---
ND
8/19/2021
mg/L
5.00
5.00
---
914.00
636.00
---
---
---
---
2/16/2022
mg/L
0.65
1.00
35.00
820.00
630.00
---
---
---
5.00
Appendix F (Page 2 of 66)
https:/Iharthick.sharepoint.wm/sites/MasterFiles l/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWMPC Tables Hart & Hickman, 1.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Chloride
12/30/2003
mg/L
0.20
1.00
3.50
280.00
170.00
82.00
13.00
44.00
---
12/19/2007
mg/L
---
5.00
ND
13.10
297.00
89.10
---
---
7.90
5/1/2013
mg/L
0.50
1.00
3.54
258.00
180.00
123.00
---
---
2.85
8/14/2014
mg/L
0.50
1.00
5.53
264.00
144.00
---
---
---
5.00
3/10/2015
mg/L
0.50
1.00
3.80
266.00
194.00
---
---
---
4.09
8/18/2015
mg/L
0.50
1.00
4.69
267.00
178.00
---
---
---
3.90
2/16/2016
mg/L
0.50
1.00
3.92
274.00
186.00
---
---
---
3.24
8/9/2016
mg/L
0.50
1.00
---
269.00
191.00
---
---
---
---
2/13/2017
mg/L
0.50
1.00
3.45
309.00
215.00
---
---
---
5.09
8/22/2017
mg/L
0.50
1.00
3.73
318.00
214.00
---
---
---
5.86
2/5/2018
mg/L
0.50
1.00
3.92
280.00
205.00
---
---
---
2.52
8/13/2018
mg/L
0.50
1.00
-
221.00
165.00
---
---
---
---
2/4/2019
mg/L
0.50
1.00
3.42
221.00
147.00
---
---
---
4.52
8/6/2019
mg/L
2.40
4.00
---
203.00
154.00
---
---
---
---
2/12/2020
mg/L
2.40
4.00
---
224.00
153.00
---
---
---
---
8/27/2020
mg/L
2.40
4.00
3.84
208.00
148.00
---
---
---
5.33
2/11/2021
mg/L
2.40
4.00
3.67
201.00
148.00
---
---
---
4.06
8/19/2021
mg/L
2.40
4.00
---
0.217
0.157
---
---
---
---
2/16/2022
mg/L
0.60
1.00
---
---
---
---
---
---
Dissolved Hydrogen
5/1/2013
nM
0.07
0.60
0.40
0.63
0.61
0.50
---
---
0.47
8/14/2014
nM
0.13
0.60
1.40
1.60
5.40
-
---
---
1.40
3/10/2015
nM
0.13
0.60
1.20
1.40
1.40
1.00
---
---
1.40
8/18/2015
nM
0.13
0.60
1.70
2.20
1.70
---
---
---
1.50
2/16/2016
nM
0.13
0.60
2.00
1.70
1.90
---
---
---
1.50
8/9/2016
nM
0.13
0.60
---
1.50
1.60
---
---
---
---
2/13/2017
nM
---
---
---
---
---
---
---
---
---
8/22/2017
nM
---
---
---
---
---
2/5/2018
nM
---
---
---
---
---
---
---
---
---
8/13/2018
nM
---
---
---
---
---
2/4/2019
nM
0.65
1.00
6.70
7.60
7.40
---
---
---
---
8/6/2019
nM
0.75
1.00
---
2.00
5.40
---
---
---
6.80
2/12/2020
nM
---
---
---
5.80
2.70
---
---
---
---
8/27/2020
nM
0.49
0.49
---
1.0 J
1.2 J
---
---
---
---
9/10/2020
nM
0.49
1.90
1.80
---
---
---
---
---
---
2/11/2021
nM
---
---
---
---
---
---
---
---
2.40
8/19/2021
nM
---
---
---
---
2/16/2022
nM
0.49
1.90
1.2 J
---
1.30
---
---
2.40
Nitrate-N
12/30/2003
mg/L
0.02
0.05
0.12
ND
ND
ND
ND
0.13
---
12/19/2007
mg/L
---
0.10
ND
ND
ND
ND
---
---
13.00
5/1/2013
mg/L
0.00
10.00
0.16
ND
ND
ND
---
---
3.58
8/14/2014
mg/L
0.00
10.00
.115 J
ND
ND
---
---
---
2.02 J
3/10/2015
mg/L
0.00
10.00
.252 J
ND
ND
---
---
---
2.56 J
8/18/2015
mg/L
0.00
10.00
.124 J
ND
ND
---
---
---
3.27 J
2/16/2016
mg/L
0.00
10.00
.36 J
ND
ND
---
---
---
2.54 J
8/9/2016
mg/L
0.00
10.00
---
ND
ND
---
---
---
---
2/13/2017
mg/L
0.00
10.00
.248 J
.189 J
ND
---
---
---
2.63 J
8/22/2017
mg/L
0.00
10.00
.118 J
.0186 J
.0451 J
---
---
---
4.06 J
2/5/2018
mg/L
0.01
10.00
.310 J
ND
.0120 J
---
---
---
1.15 J
8/13/2018
mg/L
0.05
0.10
---
ND
ND
---
---
---
---
2/4/2019
mg/L
0.05
0.10
0.20
ND
0.11
---
---
---
6.50
8/6/2019
mg/L
0.01
0.00
---
ND
ND
---
---
---
---
2/12/2020
mg/L
0.01
0.00
---
0.07
0.36
---
---
---
---
8/27/2020
mg/L
0.05
0.10
ND
ND
ND
---
---
---
6.34
2/11/2021
mg/L
0.01
0.04
0.06
ND
0.06
---
---
---
4.65
8/19/2021
mg/L
0.01
0.04
---
ND
ND
---
---
---
---
2/16/2022
mg/L
0.15
0.30
ND
ND
ND
---
---
---
ND
Sulfate
12/30/2003
mg/L
0.06
2.00
ND
ND
ND
2.60
9.60
9.00
---
12/19/2007
mg/L
---
5.00
ND
ND
ND
ND
---
---
36.80
5/1/2013
mg/L
1.00
250.00
ND
ND
ND
4.69
---
---
10.70
8/14/2014
mg/L
1.00
250.00
1.08 J
1.2 J
ND
---
---
---
5.84 J
3/10/2015
mg/L
1.00
250.00
1.52 J
1.13 J
1.52 J
---
---
---
7.04 J
8/18/2015
mg/L
1.00
250.00
1.56 J
1.31 J
2.49 J
---
---
---
5.24 J
2/16/2016
mg/L
1.00
250.00
1.5 J
1.7 J
1.8 J
---
---
---
10.0 J
8/9/2016
mg/L
1.00
250.00
---
1.22
1.75 J
---
---
---
---
2/13/2017
mg/L
1.00
250.00
1.53 J
1.59 J
1.78 J
---
---
---
11.9 J
8/22/2017
mg/L
1.00
250.00
ND
ND
.626 J
---
---
---
11.2 J
2/5/2018
mg/L
0.50
250.00
ND
ND
.627 J
---
---
---
7.48 J
8/13/2018
mg/L
0.50
250.00
ND
ND
.630 J
---
---
---
---
2/4/2019
mg/L
0.50
250.00
1.15
ND
1.10
---
---
---
6.75
8/6/2019
mg/L
0.50
1.00
---
ND
.711 J
---
---
---
---
2/12/2020
mg/L
0.50
1.00
---
ND
.85 J
---
---
---
---
8/27/2020
mg/L
0.50
1.00
ND
ND
ND
---
---
---
5.21
2/11/2021
mg/L
0.50
1.00
1.41
ND
0.82
---
---
---
5.92
8/19/2021
mg/L
0.50
1.00
---
ND
ND
---
---
---
---
2/16/2022
mg/L
0.50
1.00
ND
I ND
0.543 J
---
---
---
6.62
Sulfide
8/14/2014
mg/L
0.05
1.00
ND
ND
ND
---
---
---
ND
3/10/2015
mg/L
0.05
1.00
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
0.05
1.00
ND
ND
ND
---
---
---
1.00
2/16/2016
mg/L
0.05
1.00
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
0.05
1.00
---
ND
ND
---
---
---
---
2/13/2017
mg/L
0.05
1.00
ND
ND
ND
---
---
---
---
8/22/2017
mg/L
0.05
1.00
ND
ND
ND
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
---
---
---
---
2/4/2019
mg/L
0.05
1.00
ND
ND
ND
---
---
---
ND
8/6/2019
mg/L
0.05
0.10
ND
ND
---
---
---
---
2/12/2020
mg/L
0.05
0.10
0.083 J
ND
---
---
---
---
8/27/2020
mg/L
0.05
0.10
ND
ND
ND
---
---
---
ND
2/11/2021
mg/L
---
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
2/16/2022
mg/L
0.05
0.10
ND
ND
ND
---
---
---
ND
Appendix F (Page 3 of /6)
hftps:/Iharthick.shampoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Total Organic Carbon
12/19/2007
mg/L
---
1.0 *
2.90
54.30
23.20
17.20
---
---
7.20
5/1/2013
mg/L
0.50
1.00
2.24
29.50
30.00
19.40
---
---
5.74
8/14/2014
mg/L
0.50
1.00
ND
229.00
25.50
---
---
---
8.39
3/10/2015
mg/L
0.50
1.00
0.781J
34.80
9.54
---
---
---
1.88
8/18/2015
mg/L
0.50
1.00
0.917J
32.90
9.86
---
---
---
27.80
2/16/2016
mg/L
0.50
1.00
1.50
27.60
8.46
---
---
---
40.90
8/9/2016
mg/L
0.50
1.00
---
29.40
9.53
---
---
---
---
2/13/2017
mg/L
0.50
1.00
ND
28.50
9.72
---
---
---
1.36
8/22/2017
mg/L
0.50
1.00
ND
29.10
9.92
---
---
---
1.71
2/5/2018
mg/L
0.50
1.00
ND
25.90
11.40
---
---
---
4.24
8/13/2018
mg/L
0.50
1.00
ND
25.80
10.20
---
---
---
ND
2/4/2019
mg/L
0.50
1.00
ND
27.90
8.02
---
---
---
1.60
8/6/2019
mg/L
2.50
5.00
---
33.30
15.10
---
---
---
---
2/12/2020
mg/L
2.50
5.00
---
25.40
7.46
---
---
---
---
8/27/2020
mg/L
0.50
1.00
0.689 J
29.80
8.19
---
---
---
0.916 J
2/11/2021
mg/L
0.50
1.00
ND
28.20
7.68
---
---
---
1.61
8/19/2021
mg/L
0.50
1.00
---
28.20
7.69
---
---
---
---
2/16/2022
mg/L
0.50
1.00
ND
26.50
7.80
---
---
---
1.18
Biochemical Oxygen Demand (BOD 5-day)
8/14/2014
mg/L
2.00
2.00
ND
83.40
2.49
---
---
---
-
3/10/2015
mg/L
2.00
2.00
2.55
10.60
ND
---
---
---
ND
8/18/2015
mg/L
2.00
2.00
2.22
11.80
2.00
---
---
---
2.00
2/16/2016
mg/L
2.00
2.00
ND
60.00
6.60
---
---
---
ND
8/9/2016
mg/L
2.00
2.00
---
11.60
ND
---
---
---
2/13/2017
mg/L
2.00
2.00
ND
9.5 J
ND
---
---
---
ND
8/22/2017
mg/L
2.00
2.00
ND
ND
ND
---
---
---
ND
2/5/2018
mg/L
2.00
2.00
ND
5.60
ND
---
---
---
ND
8/13/2018
mg/L
2.00
2.00
ND
71.80
3.56
---
---
---
ND
2/4/2019
mg/L
2.00
2.00
ND
7.50
ND
---
---
---
ND
8/6/2019
mg/L
2.00
2.00
---
8.00
ND
---
---
---
---
2/12/2020
mg/L
2.00
2.00
---
6.30
ND
---
---
---
---
8/27/2020
mg/L
2.00
2.00
ND
9.45
ND
---
---
---
ND
2/11/2021
mg/L
2.00
2.00
ND
9.87
ND
---
---
---
ND
8/19/2021
mg/L
2.00
2.00
---
6.38
ND
---
---
---
2/16/2022
mg/L
2.00
2.00
ND
8.00
ND
---
---
---
ND
Chemical Oxygen Demand (COD)
8/14/2014
mg/L
12.50
25.00
ND
132.00
ND
---
---
---
50.00
3/10/2015
mg/L
12.50
25.00
15.0 J
235.00
96.00
---
---
---
ND
8/18/2015
mg/L
12.50
25.00
25.00
110.00
756.00
---
---
---
25.00
2/16/2016
mg/L
12.50
25.00
ND
295.00
50.00
---
---
---
ND
8/9/2016
mg/L
12.50
25.00
-
131.00
50.00
---
---
---
-
2/13/2017
mg/L
12.50
25.00
17 J
119.00
43.00
---
---
---
22 J
8/22/2017
mg/L
12.50
25.00
ND
121.00
74.00
---
---
---
16 J
2/5/2018
mg/L
12.50
25.00
ND
113.00
51.00
---
---
---
46.00
8/13/2018
mg/L
12.50
25.00
ND
112.00
73.90
---
---
---
ND
2/4/2019
mg/L
12.50
25.00
ND
101.00
26.50
---
---
---
ND
8/6/2019
mg/L
12.50
25.00
123.00
45.50
---
---
---
2/12/2020
mg/L
12.50
25.00
160.00
36.10
---
---
---
8/27/2020
mg/L
12.50
25.00
ND
112.00
35.90
---
---
---
ND
2/11/2021
mg/L
12.50
25.00
ND
108.00
38.00
---
---
---
ND
8/19/2021
mg/L
12.50
25.00
121.00
48.20
---
---
---
2/16/2022
mg/L
12.50
25.00
ND
105.00
32.10
---
---
---
ND
Dissolved Ethane
12/30/2003
mg/L
0.00
0.00
ND
ND
ND
---
---
---
---
12/19/2007
mg/L
---
20.00
ND
ND
ND
ND
ND
ND
---
5/1/2013
mg/L
0.00
0.01
ND
ND
ND
ND
---
---
ND
8/14/2014
mg/L
0.00
0.01
ND
ND
0.0036 J
ND
---
---
ND
3/10/2015
mg/L
0.00
0.01
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
0.00
0.01
0.01
0.01
0.01
---
---
---
ND
2/16/2016
mg/L
0.00
0.01
ND
ND
ND
---
---
---
0.01
8/9/2016
mg/L
0.00
0.01
---
1.6 J
2.6 J
---
---
---
ND
2/13/2017
mg/L
---
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
2/4/2019
mg/L
0.00
0.00
ND
ND
ND
ND
ND
ND
ND
8/6/2019
mg/L
0.00
0.01
ND
2.0 J
---
---
---
---
ND
2/12/2020
mg/L
0.00
0.01
ND
0.0026 J
---
---
---
---
ND
8/27/2020
mg/L
0.00
0.01
ND
ND
---
---
---
---
ND
2/11/2021
mg/L
---
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
---
---
---
---
2/16/2022
mg/L
0.001
0.01
---
I ---
---
---
---
---
---
Dissolved Ethene
12/1/2003
mg/L
0.00
0.00
ND
ND
ND
ND
ND
ND
---
12/19/2007
mg/L
-
20.00
ND
ND
ND
ND
ND
---
ND
5/1/2013
mg/L
0.00
0.01
ND
ND
0.0017
0.00
ND
---
ND
8/14/2014
mg/L
0.00
0.01
ND
ND
ND
ND
---
---
ND
3/10/2015
mg/L
0.00
0.01
ND
ND
ND
ND
---
---
ND
8/18/2015
mg/L
0.00
0.01
0.01
0.01
0.01
0.01
---
---
0.01
2/16/2016
mg/L
0.00
0.01
ND
ND
ND
ND
---
---
ND
8/9/2016
mg/L
0.00
0.01
---
ND
ND
ND
---
---
---
2/13/2017
mg/L
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
--
8/13/2018
mg/L
---
---
---
---
---
---
---
---
2/4/2019
mg/L
0.00
0.00
ND
ND
ND
ND
ND
ND
ND
8/6/2019
mg/L
0.00
0.01
ND
ND
0.0016 J
.0016 J
---
---
ND
2/12/2020
mg/L
0.00
0.01
ND
0.00
ND
ND
---
---
ND
8/27/2020
mg/L
0.00
0.01
ND
ND
ND
ND
---
---
ND
2/11/2021
mg/L
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
2/16/2022
mg/L
0.001
0.01
---
---
---
---
---
---
---
Appendix F (Page 4 of /6)
hftps:/Iharthick.shampoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, Pl.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Methane
12/30/2003
mg/L
0.00
0.00
ND
0.66
0.13
0.01
0.00
ND
---
12/19/2007
mg/L
-
10.00
ND
0.12
0.19
ND
---
---
ND
5/1/2013
mg/L
0.00
0.01
ND
0.04
0.10
0.03
---
---
ND
8/14/2014
mg/L
0.00
0.01
ND
1.29
0.28
---
---
---
ND
3/10/2015
mg/L
0.00
0.01
0.01
1.00
0.16
---
---
---
ND
8/18/2015
mg/L
0.00
0.01
0.00
2.16
0.32
---
---
---
0.00
2/16/2016
mg/L
0.00
0.01
0.007 J
0.87
0.10
---
---
---
0.0016 J
8/9/2016
mg/L
0.00
0.01
-
1.85
0.21
---
---
---
---
2/13/2017
mg/L
---
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
2/4/2019
mg/L
0.00
0.00
ND
27.20
ND
ND
ND
ND
ND
8/6/2019
mg/L
0.00
0.01
ND
5.00
0.49
---
---
---
ND
2/12/2020
mg/L
0.00
0.01
ND
4.50
0.38
---
---
---
ND
8/27/2020
mg/L
0.00
0.01
ND
6.00
0.50
---
---
---
ND
2/11/2021
mg/L
0.00
0.01
ND
6.66
0.52
---
---
---
ND
8/19/2021
mg/L
0.003
0.01
---
7.21
0.603
---
---
---
---
2/16/2022
mg/L
0.0034
0.01
ND
4.61
0.397
---
--
---
ND
Pyruvic Acid
12/19/2007
mg/L
---
---
2.50
ND
1.50
2.00
---
---
1.20
5/1/2013
mg/L
2.00
10.00
ND
ND
ND
ND
---
---
ND
8/14/2014
mg/L
0.77
10.00
ND
ND
ND
---
---
---
ND
3/10/2015
mg/L
0.77
10.00
0.41 J
0.41 J
0.41 J
---
---
---
0.41 J
8/18/2015
mg/L
0.77
10.00
ND
ND
ND
---
---
---
ND
2/16/2016
mg/L
0.77
10.00
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
0.77
10.00
---
ND
ND
---
---
---
---
2/13/2017
mg/L
---
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
2/4/2019
mg/L
---
---
---
---
---
---
---
---
---
8/6/2019
mg/L
---
---
ND
ND
ND
---
---
---
ND
2/12/2020
mg/L
---
---
---
---
---
---
---
---
---
8/27/2020
mg/L
---
---
ND
ND
ND
ND
2/11/2021
mg/L
---
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
---
--
2/16/2022
mg/L
0.60
5.00
ND
ND
ND
---
---
---
ND
Lactic Acid
12/19/2007
mg/L
--
---
ND
5.40
11.90
3.10
---
---
ND
5/1/2013
mg/L
2.30
25.00
ND
ND
ND
ND
---
---
ND
8/14/2014
mg/L
2.50
25.00
4.2 J
ND
ND
---
---
---
ND
3/10/2015
mg/L
2.50
25.00
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
2.50
25.00
ND
ND
ND
---
---
---
ND
2/16/2016
mg/L
2.50
25.00
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
2.50
25.00
---
ND
ND
---
---
---
2/13/2017
mg/L
---
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
2/4/2019
mg/L
---
---
---
---
---
---
---
---
---
8/6/2019
mg/L
0.04
0.20
ND
ND
0.087 J
---
---
---
ND
2/12/2020
mg/L
---
---
---
---
---
---
---
---
---
8/27/2020
mg/L
0.05
0.05
ND
ND
ND
---
---
---
ND
2/11/2021
mg/L
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
--
--
2/16/2022
mg/L
1 0.53
5.0
1 230 J
ND
ND
---
---
---
ND
Acetic Acid
12/19/2007
mg/L
---
---
ND
ND
ND
ND
---
---
ND
5/1/2013
mg/L
1.80
5.00
ND
ND
ND
ND
---
---
ND
8/14/2014
mg/L
0.81
5.00
ND
ND
ND
---
---
---
ND
3/10/2015
mg/L
0.81
5.00
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
0.81
5.00
ND
ND
0.97 J
---
---
---
ND
2/16/2016
mg/L
0.81
5.00
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
0.81
5.00
ND
ND
---
---
---
---
2/13/2017
mg/L
---
---
---
---
---
--
8/22/2017
mg/L
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
--
8/13/2018
mg/L
---
---
---
---
---
2/4/2019
mg/L
---
---
---
---
---
--
8/6/2019
mg/L
0.03
0.10
ND
0.097 J
0.34
---
---
---
ND
2/12/2020
mg/L
---
---
---
---
---
---
8/27/2020
mg/L
0.12
0.12
0.53
4.7 J
0.53
---
---
---
0.56
2/11/2021
mg/L
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
--
2/16/2022
mg/L
5.00
5.00
ND
ND
ND
---
---
---
0.13
Propionic Acid
12/19/2007
mg/L
---
---
ND
63.70
38.30
12.80
---
---
ND
5/1/2013
mg/L
1.00
5.00
ND
ND
ND
ND
---
---
ND
8/14/2014
mg/L
0.66
5.00
ND
ND
ND
---
---
---
ND
3/10/2015
mg/L
0.66
5.00
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
0.66
5.00
ND
ND
ND
---
---
---
ND
2/16/2016
mg/L
0.66
5.00
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
0.66
5.00
---
ND
ND
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
2/13/2017
mg/L
---
---
---
--
---
8/22/2017
mg/L
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
--
---
8/13/2018
mg/L
---
---
---
---
---
---
2/4/2019
mg/L
---
---
---
--
---
---
8/6/2019
mg/L
0.00
0.10
---
0.0058 J
0.0045 J
---
---
---
---
2/12/2020
mg/L
---
---
---
--
---
8/27/2020
mg/L
0.05
0.05
ND
ND
ND
---
---
---
ND
2/11/2021
mg/L
---
---
---
---
--
---
---
---
8/19/2021
mg/L
---
---
---
---
---
---
2/16/2022
mg/L
0.53
5.00
ND
ND
ND
---
---
---
ND
Appendix F (Page 5 of 66)
https:/Iharthick.sharepoint.wm/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWMPC Tables Hart & Hickman, 1.

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MDL
MRL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Butyric Acid
12/19/2007
mg/L
---
---
ND
ND
ND
ND
---
---
ND
5/1/2013
mg/L
0.87
5.00
ND
ND
ND
ND
---
---
ND
8/14/2014
mg/L
0.70
5.00
ND
ND
ND
---
---
---
ND
3/10/2015
mg/L
0.70
5.00
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
0.70
5.00
ND
ND
ND
---
---
---
ND
2/16/2016
mg/L
0.70
5.00
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
0.70
5.00
---
ND
ND
---
---
---
---
2/13/2017
mg/L
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
---
2/4/2019
mg/L
---
---
---
---
---
8/6/2019
mg/L
0.01
0.10
---
0.22
ND
---
---
---
---
2/12/2020
mg/L
---
---
---
---
---
8/27/2020
mg/L
0.06
0.06
ND
ND
0.066 J
---
---
---
ND
2/11/2021
mg/L
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
--
2/16/2022
mg/L
0.58
5.00
ND
ND
ND
---
---
---
ND
Formic Acid
8/6/2019
mg/L
0.09
0.50
---
1.10
1.60
---
---
---
---
2/12/2020
mg/L
---
---
---
---
---
---
---
---
---
8/27/2020
mg/L
0.06
0.06
4.90
45.00
4.80
---
---
---
5.10
2/11/2021
mg/L
---
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
---
--
2/16/2022
mg/L
0.55
5.00
1.2
42
9.2
---
---
4
Total Volatile Fatty Acids (sum of above 6 acids)
12/19/2007
mg/L
---
---
2.50
69.10
51.70
17.90
---
---
1.20
5/1/2013
mg/L
---
ND
ND
ND
---
---
---
ND
8/14/2014
mg/L
---
4.2 J
ND
ND
---
---
---
ND
3/10/2015
mg/L
---
ND
ND
ND
---
---
---
ND
8/18/2015
mg/L
---
ND
ND
0.97 J
---
---
---
ND
2/16/2016
mg/L
---
ND
ND
ND
---
---
---
ND
8/9/2016
mg/L
---
ND
ND
---
---
2/13/2017
mg/L
---
---
---
---
---
---
---
---
---
8/22/2017
mg/L
---
---
---
---
---
---
---
---
---
2/5/2018
mg/L
---
---
---
---
---
---
---
---
---
8/13/2018
mg/L
---
---
---
---
---
---
---
---
---
2/4/2019
mg/L
---
---
---
---
---
---
---
---
---
8/6/2019
mg/L
---
1.32
1.94
---
---
2/12/2020
mg/L
---
---
---
---
---
---
---
---
---
8/27/2020
mg/L
---
---
5.43
49.70
5.40
---
---
---
5.66
2/11/2021
mg/L
---
---
---
---
---
---
---
---
---
8/19/2021
mg/L
---
---
---
---
2/16/2022
mg/L
---
---
231.20
42.00
9.20
---
---
---
4.13
Notes:
Results from 2003 through 2021 obtained from LaBella 2021 Water Quality Monitoring Report.
Method detection limits vary between samples for fatty acid analysis, the higher method detection limit reported for each constituent for samples collected in February 2022 is shown.
mg/L = milligrams per liter; nanometers; --- = Not Sampled and/or Not Reported; ND = Not Detected; MDL = method detection limit;
MRL = method reporting limit; J = Estimated concentration above the adjusted method detection limit and below the adjusted
method reporting limit; S.U. = standard units; °C = degrees Celsius; µS/cm = microsiemens per centimeter; mV = millivolts.
Appendix F (Page 6 of /6)
hftps:/Iharthick.shampoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 First Half GWM/Tables/Historic Tables Hart & Hickman, Pl.

Appendix G
Concentration vs. Time Charts
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Chart 1
Benzene Concentrations vs. Time
MW-2R, MW-3R, & MW-4
2.5
2.0
J '7
i r\
1.5
o +MW-2R
�a
c
u M W-4
p 1.0
U 2L Standard (1 µg/L)
0.5
0.0
10/10/06 9/19/08 8/30/10 8/9/12 7/20/14 6/29/16 6/9/18 5/19/20 4/29/22
Note: Non -detect values are graphed equal to the reporting limit. Date

Chart 2
1,4-Dioxane Concentrations vs. Time
MW-2R, MW-3R, MW-4, & MW-5
140.0
120.0
100.0
J
bA
=- 80.0
C
MW-2R
0
L
MW-3R
u 60.0
c
c
MW-5
U
2L Standard (3 µg/L)
40.0
20.0
0.0
07/19/18
02/04/19 08/23/19 03/10/20 09/26/20 04/14/21 10/31/21 05/19/22
Note: Non -detect
values are graphed equal to the reporting limit. Date

Chart 3
Cobalt Concentrations vs. Time
MW-2R & MW-S
300
250
200
J
C
0
150 MW-2R
c
v
U
0 2L Standard (1 µg/L)
u
100
50
0
6/15/94 12/16/97 6/18/01 12/19/04 6/21/08 12/23/11 6/25/15 12/26/18 6/28/22
Note: Non -detect values are graphed equal to the reporting limit. Date