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23022_Chapel Hill Police Property_Soil Risk Eval_20160502
WasteManagement ENVIRONMENTAL OVALITY May 2, 2016 Mr. Lance Norris, Public Works Director Town of Chapel Hill 405 Martin Luther King Jr Blvd Chapel Hill NC 27514 Re: Chapel Hill Police Department Property 828 Martin Luther King Jr Blvd Chapel Hill, Orange County NONCD0001486 Dear Mr. Norris PAT MCCRORY Governor DONALD R. VAN DER VAART Secretary MICHAEL E. SCOTT Acting Director This letter is written regarding the soil sample results from the requested testing in and around the proposed greenway construction that will cross onto the Chapel Hill Police Department Property Site (Site). The sample results were evaluated by our industrial hygienist to determine if they exceed safe levels for park/recreational use and worker exposure. The complete results of the evaluation are attached for your review. In summary, the risk of adverse health effects to park visitors and construction workers is below the US EPA and NC DEQ maximum acceptable limits. If you have any questions, please contact me at (919) 707-8371. Sincerely, Amy Axon, Hydrogeologist Inactive Hazardous Sites Branch Enclosures CC: Curtis Brooks State of North Carolina I Environmental Quality I Waste Management 1646 Mail Service Center 1217 West Jones Street I Raleigh, NC 27699-1646 919 707 8200 T Axon, Amy From: Assefa, Hanna Sent: Tuesday, March 22, 2016 5:13 PM To: Axon, Amy Subject: Risk Assessment for the Chapel Hill Police Department soil contamination-828 Martin Luther King Jr Blvd. Chapel Hill, Orange County, NONCDD0001486 Attachments: recreator risk calc chapel hil pd property 03 212016.pdf; Construction_Worker_chem_ 22MAR2016_prg6491 Chapel Hill Police Department Soil.pdf Amy, I have evaluated the maximum contaminant concentrations you provided for the subject site, for risk posed for a recreational/park scenario and a construction worker scenario. I used the USEPA risk calculator for this calculation. For the recreational/park scenario I assumed several age groups including infants going to the park twice a week 110 days a year for 1 hr. This is likely very conservative. Under these assumptions the risk of adverse health effects to the park visitor is below the USEPA and NCDEQ acceptable limits. Similarly, I assumed that construction workers would be exposed to the contaminants when they are grading the land when converting to a park. I ultra -conservatively assumed that they would work in the same area for 1 year. The risk of adverse health effects calculated for the construction worker was also below the USEPA and NCDEQ maximum acceptable limits. The USEPA and the NCDEQ maximum acceptable limits are a cumulative 1.0E-04 cancer risk a hazard index of 1.0 for non -cancer adverse health effects. I have attached the calculations for your records. Chapel Hill Police Department Property, 828 Martin Luther King Jr Blvd Chapel Hill, Orange County Incident #NONCD0001486 Site -specific Construction Worker Equation Inputs for Soil - Other Construction Activities Variable TR (target cancer risk) unitless THQ (target hazard quotient) unitless EF ,,, (exposure frequency - construction worker) day/yr ED ,,, (exposure duration - construction worker) yr ET ,,, (exposure time - construction worker) hr/day LT (lifetime) yr BW ,,, (body weight - construction worker) kg IR ,,, (soil ingestion rate - construction worker) mg/day SAW (surface area - construction worker) cm z/day AF W (skin adherence factor - construction worker) mg/cm AT,,, (averaging time - construction worker) EW ,,, (overall duration of construction) weeks/year DW ,,, (days worked - construction worker) days/week A (acres) PR (areal extent of tilling) acres A excav (area of excavation site) m z A �o (areal extent of grading) acres A,-_,,, (areal extent of dozing) acres M, _, , (Gravimetric soil moisture content) % M a „ (Gravimetric soil moisture content) % ρ 5o,i (density) g/cm 3 - chemical -specific NA -I,,, (number of times soil is dumped) N,,,,, (number of times soil is tilled) s,,,, (soil silt content) % s, , (soil silt content) % B, (dozing blade length) m B, (grading blade length) m NA -I.. (number of times site was dozed) NA -,,.I. (number of times site was graded) S, , (dozing speed) kph S ,o (dozing speed) kph do „ (average depth of excavation site) m V (fraction of vegetative cover) z 1.0E-6 1 250 1 8 70 80 330 3527 0.3 365 50 5 0.13 0.13 0.13 0.13 0.13 7.9 12 1.68 2 2 18 6.9 1 1 2 4 11.4 11.4 .6 0 Value 1 Output generated 22MAR2016:15:16:25 Site -specific Construction Worker Equation Inputs for Soil - Other Construction Activities Variable Value U, (mean annual wind speed) m/s 4.69 U, (equivalent threshold value) m/s 11.32 t (overall duration of construction) hours 8400 F Unitless Dispersion Correction Factor 0.185837208 T (time over which traffic occurs) s 7200000 YT (g/m2s) 0.0000010282552 F(x) (function dependant on U , /U, derived using Cowherd et al. (1985)) 0.194 M,,, ' (dust emitted by wind erosion) g 2289.0175219211 M, , (dust emitted from dozing operations) g 31.265918140303 M,,,, (dust emitted from tilling operations) g 655.63592234891 M ,o (dust emitted from grading operations) g 918.93655526399 Mo „ (dust emitted from excavation soil dumping) g 0.0319584249322 ΣVKT, , (sum of fleet vehicle km traveled) km 1.05222 ΣVKT ,o (sum of fleet vehicle km traveled) km 2.10444 Q/C (inverse of the ratio of the geometric mean air concentration to the emission flu 18.747540287861 PEPS (particulate emission factor) m 3/kg 98109416.470716 A (PEF Dispersion Constant) 2.4538 B (PEF Dispersion Constant) 17.5660 C (PEF Dispersion Constant) 189.0426 A.., (areal extent of site) m z 526.0918 A (VF,,,,, acres) 0.5 T (temperature) °C 25 foc (fraction organic carbon in soil) g/g 0.006 ρ, (dry soil bulk density) g/cm 3 1.5 ρ. (soil particle density) g/cm 3 2.65 θ,,, (water -filled soil porosity) L o /L 0.15 A (VF Dispersion Constant) 2.4538 B (VF Dispersion Constant) 17.5660 C (VF Dispersion Constant) 189.0426 Q/C (inverse of the ratio of the geometric mean air concentration to the emission flu 14.31407 n (total soil porosity) L ,o/L ;, 0.43396 θ (air -filled soil porosity) L ,,/L 0.28396 As (VFmlm_s acres) 0.5 K Output generated 22MAR2016:15:16:25 Site -specific Construction Worker Equation Inputs for Soil - Other Construction Activities Variable Value ρb (dry soil bulk density) g/cm 3 1.5 d (average source depth) m Q/C„ , (inverse of the ratio of the geometric mean air concentration to the emission fl 14.31407 VFmu,,,c (volitization factor) m 3air /kgso, 3 Output generated 22MAR2016:15:16:25 Site -specific 4 Construction Worker Screening Levels (RSL) for Soil - Other Construction Activities ca=Cancer, nc=Noncancer, ca* (Where nc SL < 100 x ca SL), ca** (Where nc SL < 10 x ca SL), max=SL exceeds ceiling limit (see User's Guide), sat=SL exceeds csat, Smax=Soil SL exceeds ceiling limit and has been substituted with the max value (see User's Guide), Ssat=Soil inhalation SL exceeds csat and has been substituted with the csat Ingestion Inhalation SF Unit Subchronic Subchronic Subchronic Subchronic CAS SFO Risk IUR RfD RfD RfC RfC Chemical Number Mutagen? VOC? (mg/kg-day) ' Ref (ug/m 3)-' Ref (mg/kg-day) Ref (mg/m 3) Ref Arsenic, 7440-38-2 No No 1.50E+00 I 4.30E-03 I 3.00E-04 I 1.50E-05 C Inorganic Barium 7440-39-3 No No - - 2.00E-01 A 5.00E-03 H Beryllium and 7440-41-7 No No - 2.40E-03 I 5.00E-03 H 2.00E-05 I compounds Chromium(III), 16065-83-1 No No - - 1.50E+00 H 5.00E-03 A Insoluble Salts Cobalt 7440-48-4 No No - 9.00E-03 P 3.00E-03 P 2.00E-05 P Copper 7440-50-8 No No - - 1.00E-02 A - Mercury 7439-97-6 No Yes - - - 3.00E-04 H (elemental) Molybdenum 7439-98-7 No No - - 5.00E-03 H - Nickel Soluble 7440-02-0 No No - 2.60E-04 C 2.00E-02 H 2.00E-04 A Salts Selenium 7782-49-2 No No - - 5.00E-03 H 2.00E-02 C Strontium, 7440-24-6 No No - - 2.00E+00 A - Stable Thallium 7440-28-0 No No - - 4.00E-05 S - (Soluble Salts) Vanadium and 7440-62-2 No No - - 1.00E-02 A 1.00E-04 A Compounds Zinc and 7440-66-6 No No - - 3.00E-01 A - Compounds Volatilization Factor GIABS ABS RBA (m3/kg) 1 0.03 0.6 - 0.07 - 1 - 0.007 - 1 - 0.013 - 1 - 1 - 1 7.53E+03 0.04 1 1 1 0.026 1 Output generated 22MAR2016:15:16:25 Site -specific 5 Construction Worker Screening Levels (RSL) for Soil - Other Construction Activities ca=Cancer, nc=Noncancer, ca* (Where nc SL < 100 x ca SQ, ca** (Where nc SL < 10 x ca SQ, max=SL exceeds ceiling limit (see User's Guide), sat=SL exceeds csat, Smax=Soil SL exceeds ceiling limit and has been substituted with the max value (see User's Guide), Ssat=Soil inhalation SL exceeds csat and has been substituted with the csat Soil Particulate Ingestion Dermal Inhalation Carcinogenic Ingestion Dermal Inhalation Noncarcinogenic Saturation Emission SL SL SL SL SL SL SL SL Screening Concentration Factor TR=1.0E-6 TR=1.0E-6 TR=1.0E-6 TR=1.0E-6 THQ=1 THQ=1 THQ=1 THI=1 Level Chemical (mg/kg) (m3/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) Arsenic, - 9.81 E+07 2.75E+01 1.72E+02 7.00E+03 2.36E+01 1.70E+02 1.06E+03 6.18E+03 1.43E+02 2.36E+01 Inorganic ca** Barium - 9.81 E+07 - - - - 6.79E+04 - 2.06E+06 6.57E+04 6.57E+04 nc Beryllium and - 9.81 E+07 - - 1.25E+04 1.25E+04 1.70E+03 - 8.24E+03 1.41 E+03 1.41 E+03 compounds nc Chromium(III), - 9.81 E+07 - - - - 5.09E+05 - 2.06E+06 4.08E+05 4.08E+05 Insoluble max Salts Cobalt - 9.81 E+07 - - 3.34E+03 3.34E+03 1.02E+03 - 8.24E+03 9.06E+02 9.06E+02 nc Copper - 9.81 E+07 - - - - 3.39E+03 - - 3.39E+03 3.39E+03 nc Mercury 3.13E+00 9.81 E+07 - - - - - - 9.49E+00 9.49E+00 9.49E+00 (elemental) sat Molybdenum - 9.81 E+07 - - - - 1.70E+03 - - 1.70E+03 1.70E+03 nc Nickel Soluble - 9.81 E+07 - - 1.16E+05 1.16E+05 6.79E+03 - 8.24E+04 6.27E+03 6.27E+03 Salts nc Selenium - 9.81 E+07 - - - - 1.70E+03 - 8.24E+06 1.70E+03 1.70E+03 nc Strontium, - 9.81 E+07 - - - - 6.79E+05 - - 6.79E+05 6.79E+05 Stable max Thallium - 9.81 E+07 - - - - 1.36E+01 - - 1.36E+01 1.36E+01 (Soluble nc Salts) Vanadium and - 9.81 E+07 - - - - 3.39E+03 - 4.12E+04 3.14E+03 3.14E+03 Compounds nc Zinc and - 9.81 E+07 - - - - 1.02E+05 - - 1.02E+05 1.02E+05 Compounds max Output generated 22MAR2016:15:16:25 Site -specific Construction Worker Risk for Soil - Other Construction Activities Chemical Arsenic, Inorganic Barium Beryllium and compounds Chromium(III), Insoluble Salts Cobalt Copper Mercury (elemental) Molybdenum Nickel Soluble Salts Selenium Strontium, Stable Thallium (Soluble Salts) Vanadium and Compounds Zinc and Compounds *Total Risk/HI 1.1 Ingestion Inhalation Soil SF Unit Subchronic Subchronic Subchronic Subchronic Volatilization Saturation SFO Risk IUR RfD RfD RfC RfC Factor Concentration (mg/kg-day) -' Ref (ug/m 3)-' Ref (mg/kg-day) Ref (mg/m 3) Ref GIABS ABS RBA (m3/kg) (mg/kg) 1.50E+00 I 4.30E-03 I 3.00E-04 I 1.50E-05 C 1 0.03 0.6 - - - - 2.00E-01 A 5.00E-03 H 0.07 - 1 - - - 2.40E-03 I 5.00E-03 H 2.00E-05 1 0.007 - 1 - - - - 1.50E+00 H 5.00E-03 A 0.013 - 1 - - - 9.00E-03 P 3.00E-03 P 2.00E-05 P 1 - 1 - - - - 1.00E-02 A - 1 - 1 - - - - - 3.00E-04 H 1 - 1 7.53E+03 3.13E+00 - - 5.00E-03 H - 1 - 1 - - - 2.60E-04 C 2.00E-02 H 2.00E-04 A 0.04 - 1 - - - - 5.00E-03 H 2.00E-02 C 1 - 1 - - - - 2.00E+00 A - 1 - 1 - - - - 4.00E-05 S - 1 - 1 - - - - 1.00E-02 A 1.00E-04 A 0.026 - 1 - - - - 3.00E-01 A - 1 - 1 - - Output generated 22MAR2016:15:16:25 Site -specific Construction Worker Risk for Soil - Other Construction Activities Particulate Emission Factor Concentration Ingestion Dermal Inhalation Carcinogenic Ingestion Dermal Inhalation Noncarcinogenic Chemical (m3/kg) (mg/kg) Risk Risk Risk Risk HQ HQ HQ HI Arsenic, Inorganic 9.81 E+07 2.40E+01 8.72E-07 1.40E-07 3.43E-09 1.02E-06 0.1414286 0.0226736 0.0038829 0.1679851 Barium 9.81 E+07 8.30E+02 - - - - 0.0122277 - 0.0004029 0.0126305 Beryllium and compounds 9.81 E+07 3.50E+00 - - 2.79E-10 2.79E-10 0.0020625 - 0.0004247 0.0024872 Chromium(III), Insoluble 9.81 E+07 3.50E+01 - - - - 0.0000688 - 0.000017 0.0000857 Salts Cobalt 9.81 E+07 2.80E+01 - - 8.38E-09 8.38E-09 0.0275 - 0.0033976 0.0308976 Copper 9.81 E+07 5.70E+01 - - - - 0.0167946 - - 0.0167946 Mercury (elemental) 9.81 E+07 2.10E+00 - - - - - - 0.2213331 0.2213331 Molybdenum 9.81 E+07 1.70E+00 - - - - 0.0010018 - - 0.0010018 Nickel Soluble Salts 9.81 E+07 1.90E+01 - - 1.64E-10 1.64E-10 0.0027991 - 0.0002305 0.0030297 Selenium 9.81 E+07 2.40E+00 - - - - 0.0014143 - 2.9122E-7 0.0014146 Strontium, Stable 9.81 E+07 1.90E+02 - - - - 0.0002799 - - 0.0002799 Thallium (Soluble Salts) 9.81 E+07 1.70E+00 - - - - 0.1252232 - - 0.1252232 Vanadium and Compounds 9.81 E+07 9.50E+01 - - - - 0.0279911 - 0.0023055 0.0302966 Zinc and Compounds 9.81 E+07 1.10E+02 - - - - 0.0010804 - - 0.0010804 *Total Risk/HI - - 8.72E-07 1.40E-07 1.23E-08 1.02E-06 0.3598719 0.0226736 0.2319945 0.61454 Output generated 22MAR2016:15:16:25 Site -specific Recreator Equation Inputs for Soil Variable Value TR (target cancer risk) unitless 1.0E-6 THQ (target hazard quotient) unitless 1 SA rec-c (skin surface area - child) cm 2/day 2373 SA rec-a (skin surface area - adult) cm 2/day 6032 SAo-2 (skin surface area - mutagenic) cm 2/day 2373 SA2_6 (skin surface area - mutagenic) cm 2/day 2373 SA6-16 (skin surface area - mutagenic) cm 2/day 6032 SA,,-,,) (skin surface area - mutagenic) cm 2/day 6032 SA rec-a (skin surface area - adult) cm 2/day 6032 LT (lifetime - recreator) year 70 IFS_,_,,-, (age -adjusted soil ingestion factor) mg/kg 11550 DFS_ _ ,, (age -adjusted soil dermal factor) mg/kg 32494 IFSM,o ,. (mutagenic age -adjusted soil ingestion factor) mg/kg 52433.333 DFSM,o ,, (mutagenic age -adjusted soil dermal factor) mg/kg 134596 EFL_, (exposure frequency) day/year 110 EF (exposure frequency) day/year 110 EF,_,F (exposure frequency) day/year 110 EF,,_,, (exposure frequency) day/year 110 EFYe (exposure frequency - child) day/year 110 EFYe (exposure frequency - adult) day/year 110 EF,o (exposure frequency - adult) day/year 110 EF,o (exposure frequency - recreator) day/year 110 IRS_, (soil intake rate) mg/day 200 IRS,_ (soil intake rate) mg/day 200 IRS,, (soil intake rate) mg/day 100 IRS,,_,, (soil intake rate) mg/day 100 IRS_ (soil intake rate - child) mg/day 200 IRS_ (soil intake rate - adult) mg/day 100 IRS_ (soil intake rate - adult) mg/day 100 EDP_, (exposure duration) year 2 ED (exposure duration) year 4 ED,, (exposure duration) year 10 ED16-so (exposure duration) year 10 1 Output generated 21 MAR2016:14:44:13 Site -specific Recreator Equation Inputs for Soil Variable Value ED_ (exposure duration - child) year 6 ED_ (exposure duration - adult) year 20 ED_ (exposure duration - adult) year 20 ED,o (exposure duration - recreator) year 26 ETA_, (exposure time) hr/day 1 ET- (exposure time) hr/day 1 ET,_,, (exposure time) hr/day 1 ET,,_,, (exposure time) hr/day 1 ETYe (exposure time - child) hr/day 1 ET_ (exposure time - adult) hr/day 1 ET_ (exposure time - adult) hr/day 1 ET- (exposure time - recreator) hr/day 1 BW,_, (body weight) kg 15 BW,_, (body weight) kg 15 BW,_,, (body weight) kg 80 BW,,_,, (body weight) kg 80 BW_,_, (body weight - child) kg 15 BW_,_, (body weight - adult) kg 80 BW_,_, (body weight - adult) kg 80 AFo-2 (skin adherence factor) mg/cm 2 0.2 AFz_6 (skin adherence factor) mg/cm 2 0.2 AF6_16 (skin adherence factor) mg/cm 2 0.07 AF16_30 (skin adherence factor) mg/cm 2 0.07 AFrec-c (skin adherence factor - child) mg/cm 2 0.2 AFrec-a (skin adherence factor - adult) mg/cm 2 0.07 AFrec-a (skin adherence factor - adult) mg/cm 2 0.07 City (Climate Zone) PEF Selection Default A (acres) .5 Q/CWP (g/m2-s per kg/m3) 93.77 PEF (particulate emission factor) m 3/kg 1359344438 A (PEF Dispersion Constant) 16.2302 B (PEF Dispersion Constant) 18.7762 C (PEF Dispersion Constant) 216.108 z Output generated 21 MAR2016:14:44:13 Site -specific Recreator Equation Inputs for Soil Variable Value V (fraction of vegetative cover) unitless 0.5 U, (mean annual wind speed) m/s 4.69 U, (equivalent threshold value) 11.32 F(x) (function dependant on U , /U,) unitless 0.194 City (Climate Zone) VF Selection Default A (acres) .5 Q/C , (g/m2-s per kg/m 3) 68.18 foc (fraction organic carbon in soil) g/g 0.006 ρb (dry soil bulk density) g/cm 3 1.5 ρ. (soil particle density) g/cm 3 2.65 n (total soil porosity) L ,o/L ;, 0.43396 θ (air -filled soil porosity) L ,,/L 0.28396 θ (water -filled soil porosity) L ,o,/L 0.15 T (exposure interval) s 819936000 A (VF Dispersion Constant) 11.911 B (VF Dispersion Constant) 18.4385 C (VF Dispersion Constant) 209.7845 City (Climate Zone) VF m, Selection Default VF. (volitization factor) m 3/kg Q/C , (g/m2-s per kg/m 3) 68.18365 A (acres) .5 T (exposure interval) yr 26 d (depth of source) m ρb (dry soil bulk density) g/cm 3 1.5 A (VF Dispersion Constant - Mass Limit) 11.911 B (VF Dispersion Constant - Mass Limit) 18.4385 C (VF Dispersion Constant- Mass Limit) 209.7845 3 Output generated 21 MAR2016:14:44:13 Site -specific 4 Recreator Screening Levels (RSL) for Soil ca=Cancer, nc=Noncancer, ca* (Where nc SL < 100 x ca SL), ca** (Where nc SL < 10 x ca SL), max=SL exceeds ceiling limit (see User's Guide), sat=SL exceeds csat, Smax=Soil SL exceeds ceiling limit and has been substituted with the max value (see User's Guide), Ssat=Soil inhalation SL exceeds csat and has been substituted with the csat Ingestion SF CAS SFO Chemical Number Mutagen? VOC? (mg/kg-day) ' Ref Arsenic, Inorganic 7440-38-2 No No 1.50E+00 I Barium 7440-39-3 No No - Beryllium and compounds 7440-41-7 No No - Chromium(III), Insoluble Salts 16065-83-1 No No - Cobalt 7440-48-4 No No - Copper 7440-50-8 No No - Manganese (Non -diet) 7439-96-5 No No - Mercury (elemental) 7439-97-6 No Yes - Molybdenum 7439-98-7 No No - Nickel Soluble Salts 7440-02-0 No No - Selenium 7782-49-2 No No - Strontium, Stable 7440-24-6 No No - Thallium (Soluble Salts) 7440-28-0 No No - Vanadium and Compounds 7440-62-2 No No - Zinc and Compounds 7440-66-6 No No - Inhalation Unit Subchronic Subchronic Subchronic Subchronic Risk IUR RfD RfD RfC RfC (ug/m 3)-' Ref (mg/kg-day) Ref (mg/m 3) Ref 4.30E-03 I 3.00E-04 I 1.50E-05 C - 2.00E-01 A 5.00E-03 H 2.40E-03 I 5.00E-03 H 2.00E-05 I - 1.50E+00 H 5.00E-03 A 9.00E-03 P 3.00E-03 P 2.00E-05 P - 1.00E-02 A - - 2.40E-02 S 5.00E-05 I - - 3.00E-04 H - 5.00E-03 H - 2.60E-04 C 2.00E-02 H 2.00E-04 A - 5.00E-03 H 2.00E-02 C - 2.00E+00 A - - 4.00E-05 S - - 1.00E-02 A 1.00E-04 A - 3.00E-01 A - Output generated 21 MAR2016:14:44:13 Site -specific 5 Recreator Screening Levels (RSL) for Soil ca=Cancer, nc=Noncancer, ca* (Where nc SL < 100 x ca SL), ca** (Where nc SL < 10 x ca SL), max=SL exceeds ceiling limit (see User's Guide), sat=SL exceeds csat, Smax=Soil SL exceeds ceiling limit and has been substituted with the max value (see User's Guide), Ssat=Soil inhalation SL exceeds csat and has been substituted with the csat Chemical GIABS ABS RBA Arsenic, Inorganic 1 0.03 0.6 Barium 0.07 - 1 Beryllium and compounds 0.007 - 1 Chromium(III), Insoluble Salts 0.013 - 1 Cobalt 1 - 1 Copper 1 - 1 Manganese (Non -diet) 0.04 - 1 Mercury (elemental) 1 - 1 Molybdenum 1 - 1 Nickel Soluble Salts 0.04 - 1 Selenium 1 - 1 Strontium, Stable 1 - 1 Thallium (Soluble Salts) 1 - 1 Vanadium and Compounds 0.026 - 1 Zinc and Compounds 1 - 1 Soil Volatilization Saturation Factor Concentration (m3/kg) (mg/kg) 3.47E+04 3.13E+00 Particulate Ingestion Dermal Inhalation Carcinogenic Emission SL SL SL SL Factor TR=1.0E-6 TR=1.0E-6 TR=1.0E-6 TR=1.0E-6 (m3/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) 1.36E+09 2.46E+00 1.75E+01 6.78E+04 2.15E+00 1.36E+09 - - - - 1.36E+09 - - 1.21 E+05 1.21 E+05 1.36E+09 - - - - 1.36E+09 - - 3.24E+04 3.24E+04 1.36E+09 - - - - 1.36E+09 - - - - 1.36E+09 - - - - 1.36E+09 - - - - 1.36E+09 - - 1.12E+06 1.12E+06 1.36E+09 - - - - 1.36E+09 - - - - 1.36E+09 - - - - 1.36E+09 - - - - 1.36E+09 - - - - Output generated 21 MAR2016:14:44:13 Site -specific 1.1 Recreator Screening Levels (RSL) for Soil ca=Cancer, nc=Noncancer, ca* (Where nc SL < 100 x ca SQ, ca** (Where nc SL < 10 x ca SQ, max=SL exceeds ceiling limit (see User's Guide), sat=SL exceeds csat, Smax=Soil SL exceeds ceiling limit and has been substituted with the max value (see User's Guide), Ssat=Soil inhalation SL exceeds csat and has been substituted with the csat Ingestion Dermal Inhalation Noncarcinogenic Ingestion Dermal Inhalation Noncarcinogenic SL SL SL SL SL SL SL SL Child Child Child Child Adult Adult Adult Adult Screening THQ=1 THQ=1 THQ=1 THI=1 THQ=1 THQ=1 THQ=1 THI=1 Level Chemical (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) Arsenic, Inorganic 1.24E+02 1.05E+03 1.62E+06 1.11 E+02 1.33E+03 6.29E+03 1.62E+06 1.10E+03 2.15E+00 ca* Barium 4.98E+04 - 5.41 E+08 4.98E+04 5.31 E+05 - 5.41 E+08 5.30E+05 4.98E+04 nc Beryllium and compounds 1.24E+03 - 2.17E+06 1.24E+03 1.33E+04 - 2.17E+06 1.32E+04 1.24E+03 nc Chromium(III), Insoluble Salts 3.73E+05 - 5.41 E+08 3.73E+05 3.98E+06 - 5.41 E+08 3.95E+06 3.73E+05 max Cobalt 7.47E+02 - 2.17E+06 7.46E+02 7.96E+03 - 2.17E+06 7.93E+03 7.46E+02 nc Copper 2.49E+03 - - 2.49E+03 2.65E+04 - - 2.65E+04 2.49E+03 nc Manganese (Non -diet) 5.97E+03 - 5.41 E+06 5.97E+03 6.37E+04 - 5.41 E+06 6.30E+04 5.97E+03 nc Mercury (elemental) - - 8.29E+02 8.29E+02 - - 8.29E+02 8.29E+02 8.29E+02 sat Molybdenum 1.24E+03 - - 1.24E+03 1.33E+04 - - 1.33E+04 1.24E+03 nc Nickel Soluble Salts 4.98E+03 - 2.17E+07 4.98E+03 5.31 E+04 - 2.17E+07 5.30E+04 4.98E+03 nc Selenium 1.24E+03 - 2.17E+09 1.24E+03 1.33E+04 - 2.17E+09 1.33E+04 1.24E+03 nc Strontium, Stable 4.98E+05 - - 4.98E+05 5.31 E+06 - - 5.31 E+06 4.98E+05 max Thallium (Soluble Salts) 9.95E+00 - - 9.95E+00 1.06E+02 - - 1.06E+02 9.95E+00 nc Vanadium and Compounds 2.49E+03 - 1.08E+07 2.49E+03 2.65E+04 - 1.08E+07 2.65E+04 2.49E+03 nc Zinc and Compounds 7.47E+04 - - 7.47E+04 7.96E+05 - - 7.96E+05 7.47E+04 nc Output generated 21 MAR2016:14:44:13 Site -specific Recreator Risk for Soil Ingestion Inhalation SF Unit Subchronic Subchronic Subchronic Subchronic SFO Risk IUR RfD RfD RfC RfC Chemical (mg/kg-day) -' Ref (ug/m 3)-' Ref (mg/kg-day) Ref (mg/m 3) Ref GIABS ABS RBA Arsenic, Inorganic 1.50E+00 I 4.30E-03 I 3.00E-04 I 1.50E-05 C 1 0.03 0.6 Barium - - 2.00E-01 A 5.00E-03 H 0.07 - 1 Beryllium and compounds - 2.40E-03 I 5.00E-03 H 2.00E-05 1 0.007 - 1 Chromium(III), Insoluble Salts - - 1.50E+00 H 5.00E-03 A 0.013 - 1 Cobalt - 9.00E-03 P 3.00E-03 P 2.00E-05 P 1 - 1 Copper - - 1.00E-02 A - 1 - 1 Manganese (Non -diet) - - 2.40E-02 S 5.00E-05 1 0.04 - 1 Mercury (elemental) - - - 3.00E-04 H 1 - 1 Molybdenum - - 5.00E-03 H - 1 - 1 Nickel Soluble Salts - 2.60E-04 C 2.00E-02 H 2.00E-04 A 0.04 - 1 Selenium - - 5.00E-03 H 2.00E-02 C 1 - 1 Strontium, Stable - - 2.00E+00 A - 1 - 1 Thallium (Soluble Salts) - - 4.00E-05 S - 1 - 1 Vanadium and Compounds - - 1.00E-02 A 1.00E-04 A 0.026 - 1 Zinc and Compounds - - 3.00E-01 A - 1 - 1 *Total Risk/HI - - - - - - - Output generated 21 MAR2016:14:44:13 Site -specific Recreator Risk for Soil Chemical Arsenic, Inorganic Barium Beryllium and compounds Chromium(III), Insoluble Salts Cobalt Copper Manganese (Non -diet) Mercury (elemental) Molybdenum Nickel Soluble Salts Selenium Strontium, Stable Thallium (Soluble Salts) Vanadium and Compounds Zinc and Compounds *Total Risk/HI Soil Particulate Volatilization Saturation Emission Factor Concentration Factor (m3/kg) (mg/kg) (m3/kg) - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 3.47E+04 3.13E+00 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 - - 1.36E+09 Concentration Ingestion Dermal Inhalation Carcinogenic (mg/kg) Risk Risk Risk Risk 2.40E+01 9.76E-06 1.37E-06 3.54E-10 1.11 E-05 8.30E+02 - - - - 3.50E+00 - - 2.88E-11 2.88E-11 3.50E+01 - - - - 2.80E+01 - - 8.65E-10 8.65E-10 5.70E+01 - - - - 3.90E+01 - - - - 2.10E+00 - - - - 1.70E+00 - - - - 1.90E+01 - - 1.69E-11 1.69E-11 2.40E+00 - - - - 1.90E+02 - - - - 1.70E+00 - - - - 9.50E+01 - - - - 1.10E+02 - - - - - 9.76E-06 1.37E-06 1.26E-09 1.11E-05 1.1 Output generated 21 MAR2016:14:44:13 Site -specific Recreator Risk for Soil Ingestion Dermal Inhalation Noncarcinogenic Ingestion Dermal Child Child Child Child Adult Adult Chemical HQ HQ HQ HI HQ HQ Arsenic, Inorganic 1.93E-01 2.29E-02 1.48E-05 2.16E-01 1.81 E-02 3.82E-03 Barium 1.67E-02 - 1.53E-06 1.67E-02 1.56E-03 Beryllium and compounds 2.81 E-03 - 1.62E-06 2.81 E-03 2.64E-04 Chromium(III), Insoluble Salts 9.38E-05 - 6.47E-08 9.38E-05 8.79E-06 Cobalt 3.75E-02 - 1.29E-05 3.75E-02 3.52E-03 Copper 2.29E-02 - - 2.29E-02 2.15E-03 Manganese (Non -diet) 6.53E-03 - 7.21 E-06 6.54E-03 6.12E-04 Mercury (elemental) - - 2.53E-03 2.53E-03 - Molybdenum 1.37E-03 - - 1.37E-03 1.28E-04 Nickel Soluble Salts 3.82E-03 - 8.78E-07 3.82E-03 3.58E-04 Selenium 1.93E-03 - 1.11 E-09 1.93E-03 1.81 E-04 Strontium, Stable 3.82E-04 - - 3.82E-04 3.58E-05 Thallium (Soluble Salts) 1.71 E-01 - - 1.71 E-01 1.60E-02 Vanadium and Compounds 3.82E-02 - 8.78E-06 3.82E-02 3.58E-03 Zinc and Compounds 1.47E-03 - - 1.47E-03 1.38E-04 *Total Risk/HI 4.97E-01 2.29E-02 2.58E-03 5.23E-01 4.66E-02 3.82E-03 Inhalation Noncarcinogenic Adult Adult HQ HI 1.48E-05 2.19E-02 1.53E-06 1.56E-03 1.62E-06 2.65E-04 6.47E-08 8.85E-06 1.29E-05 3.53E-03 - 2.15E-03 7.21 E-06 6.19E-04 2.53E-03 2.53E-03 - 1.28E-04 8.78E-07 3.59E-04 1.11 E-09 1.81 E-04 - 3.58E-05 - 1.60E-02 8.78E-06 3.59E-03 - 1.38E-04 2.58E-03 5.30E-02 P] Output generated 21 MAR2016:14:44:13