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23022_Chapel Hill Police Property_OAR_20150818
LOON � I N LEKIIIN ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property 828 Martin Luther King Jr. Boulevard Chapel Hill, Orange County, NC Revised: August 18, 2015 ENVIRONMENTAL SITE CHARACTERIZATION Q,t1k CA►90 �r�FE88% C� SEAL�� :LU V. Chapel Hill Police Department Property 828 Martin Luther King Jr. Boulevard Chapel Hill, Orange County, NC Prepared for: Town of Chapel Hill Chapel Hill Town Hall 405 Martin Luther King, Jr. Blvd. Chapel Hill, NC 27514 Submitted by: Christopher Norville P.E. Falcon Engineering, Inc. 1210 Trinity Road Suite 110 Raleigh, North Carolina 27607 (919) 871-0800 www.falconengineers.com Firm: C-3193 Falcon Project Number I El3047.10 March 11, 2014 Revised: August 18, 2015 TABLE OF CONTENTS Page SECTION1..................................................................................................................................................................4 INTRODUCTION.......................................................................................................................................................4 1.1 SITE LOCATION AND DESCRIPTION............................................................................................ 5 1.2 SITE HISTORY AND PREVIOUS SCOPE OF WORK......................................................................... 5 1.3 CURRENT PROJECT OBJECTIVE AND SCOPE OF WORK............................................................... 6 1.4 CURRENT LAND USE.................................................................................................................. 6 1.5 DESCRIPTION OF SOILS.............................................................................................................. 7 1.6 HYDROGEOLOGIC CONDITIONS.................................................................................................. 7 METHODSOF INVESTIGATION...........................................................................................................................8 2.1 MONITORING WELL ABANDONMENT, INSTALLATION, AND DEVELOPMENT .............................. 8 2.2 GROUNDWATER ANALYTICAL METHODS.................................................................................. 9 Table 1 I Groundwater Analytical Methods....................................................................................... 9 2.3 GROUNDWATER SAMPLING METHODS....................................................................................... 9 ANALYTICAL RESULTS.......................................................................................................................................10 Table 2 May 2015 Initial Sampling Results (pre -well stabilization) .............................................. 10 Table 3 July 2015 Additional Sampling Results (post -well stabilization) ..................................... 11 SUMMARY OF FINDINGS.....................................................................................................................................12 RECOMMENDATIONS..........................................................................................................................................12 FIGURES....................................................................................................................................................................A PHOTOGRAPHS....................................................................................................................................................... B WELLRECORDS...................................................................................................................................................... C LABORATORYDATA............................................................................................................................................. D FIELDNOTES........................................................................................................................................................... E Table4 1 MW3A Field Data................................................................................................................ I Table 51 MW4A Field Data................................................................................................................ I Table 61 MWI Field Data................................................................................................................... 2 k JF SECTION 1 INTRODUCTION Falcon Engineering, Inc. (Falcon) completed an Environmental Site Characterization (ESC) Report for the Town of Chapel Hill property located at 828 Martin Luther King Jr. Boulevard in Chapel Hill, Orange County, North Carolina. The purpose of the investigation was to evaluate the on -site groundwater for potential impacts from previously identified coal combustion products (CCPs) within the property boundaries. Falcon has previously mobilized to the site in an effort to install, purge, and sample monitoring wells. However, due to the local recharge rates and the nature of the CCPs to increase turbidity the initial wells were either too turbid or ran dry before they could be adequately purged and stabilized. New wells were installed to greater depth and purged; however, due to inclement weather and time constraints the wells were initially sampled prior to stabilizing and therefore, did not yield accurate analysis of the dissolved phase contamination. This report discusses the initial sampling results from the reinstalled wells as well as the successful results of additional sampling performed after the wells were purged a second time and stabilized. The most recent sampling activities were successful in sampling for dissolved phase constituents through monitoring the wells for stability and sampling immediately after purging. Sampling included the collection of three (3) groundwater samples from the two existing down gradient monitoring wells, one un-filtered sample each from MW3A and MW4A along with filtered MW4A samples due to the slightly elevated turbidity of 24.7 NTU in MW4A. This sampling event was monitored by the North Carolina Department of Environment and Natural Resources (NCDENR) through ongoing correspondence before and during the sampling event. The following list provides the identified constituents (barium and boron) and their concentrations. The identified contaminant's do not exceed the 15A NCAC 02L .0202 Groundwater Standards. Hexavalent Chromium was not identified in the collected samples. It appears that the previously identified CCPs have not exceeded the groundwater standards down gradient of the landfill within the property boundaries. Barium - 67 Ng/L Barium - 64 pg/L Barium - 61 pg/L Boron - 520 Ng/L BRL BRL The Environmental Site Characterization (ESC) was conducted in general accordance with the January 2014 Inactive Hazardous Sites Program's Guidelines for Assessment and Cleanup. The assessment was performed on a property with the property identification number (PIN) 9789413949. Figure 1 (Appendix A) provides a general site location map of the subject property. An additional figure detailing sample locations is also provided in Appendix A of this report. 1.1 Site Location and Description The evaluated property is approximately a 10.24-acre property located along Martin Luther King Jr. Blvd. in Chapel Hill, North Carolina. The site is located to the east of Martin Luther King Jr. Blvd., with development primarily focused in the northwest corner. The property is located immediately north of Bolin Creek, beginning approximately 200 feet north of the centerline of Hillsborough Street. The property is currently developed with a 2 story structure approximately 25,000 square feet in size. There are also two parking lots and a few cargo containers used for storage present on site. The site is currently occupied by the Chapel Hill Police Department. The building is located in the northwest corner, with the majority of parking in the center of the site. The eastern and southern portions of the site are wooded. 1.2 Site History and Previous Scope of Work The Town of Chapel Hill retained Falcon to conduct the ESC. Previous work conducted at the site (Phase I ESA & Limited Phase II) is detailed below and was previously provided under separate cover. The past project goals of the Phase I were accomplished through the completion of the following tasks: • Review of environmental databases and lists obtained from Federal, State, and local regulatory agencies including historic maps and directories of the site and the surrounding areas. • Visual inspection of the subject site, including photographic documentation of existing conditions and notation of adjacent property use and conditions. • Interviews with those knowledgeable of the site's history (as appropriate or required). The past project goals of the Limited Phase II were accomplished through the completion of the following tasks: • Sediment and groundwater sampling to determine the existing conditions within identified areas on the subject property. Sampling included two sediment samples and 3 water samples. • Laboratory analyses of samples for Chemicals of Concern (COC). • Comparison of analytical results to applicable criteria. Based on findings of those investigations NCDENR requested the lab results from two down gradient monitoring wells. Falcon also conducted geoprobe drilling on site to better assess the extent of potential Coal Combustion Products (CCPs) on the subject property. 1.3 Current Project Objective and Scope of Work The Town of Chapel Hill retained Falcon to continue efforts in completing the ESC. The purpose of the ESC was to further delineate environmental conditions present at the site in regards to the former use as a landfill. Previous work at the site is mentioned in the above section. The current project goals of the ESC were accomplished through the completion of the following tasks: • Abandonment of the two (2) original down gradient monitoring wells that produced highly turbid samples. • Installation and development of two (2) new down gradient monitoring wells at increased depths. • Sampling groundwater to determine the existing conditions within identified areas on the subject property. Laboratory analyses of samples for Chemicals of Concern. • Comparison of analytical results to applicable criteria. 1.4 Current Land Use The subject property was generally undeveloped until the current police station was constructed after 1980. However, as discussed in the Historical Usage section, it appears the site was used as a borrow pit in the late 1950's through early 1960's then as a fill site from the mid-1960's to mid- 1970's. The site has been the home of the Chapel Hill Police Station since the town acquired it in 1980. During the site reconnaissance, it became apparent that fill materials including some coal combustion products (CCPs) were previously placed adjacent to a steep slope along the southern portion of the property. UF 1.5 Description of Soils The US Natural Resource Conservation Service's Orange County Soil Survey provides two (2) different native soil types on the subject site: • TaE - Tatum Silt Loam Complex (15 to 25 percent slopes) - well drained soil derived from red saprolite (50% of the overall subject site). • WmE - Wedowee Sandy Loam Complex (15 to 25 percent slopes) - well drained soil derived from red saprolite (50% of the overall subject site). 1.6 Hydrogeologic Conditions A review of the Chapel Hill, NC USGS 7.5-minute 1946 topographic map, which includes the project site, indicates that the site is located on varying elevations from 375 feet above mean sea level (msl) in the northwest corner of the site to 284 feet msl in the southeast corner where the site meets Bolin Creek. The 2010 Topographic Map from Orange County GIS indicates significantly different contours from the USGS maps. This data supports the filling and leveling of the site which would explain the soil/debris layers observed within the (previously taken) geoprobe soil profiles seen. The site is bounded on the north and west by paved streets, to the east by residential developed woodlands and to the south by Bolin Creek. The general site drainage is to the South via overland flow and along stormwater trenches aside Martin Luther King Jr. Blvd. Stormwater drains from this site into Bolin Creek. Very little, if any, surface water comes onto the site from offsite. The property and surrounding area are serviced by municipal water from Orange Water and Sewer Authority (OWASA) and does not currently utilize groundwater. Falcon contacted the Orange County Health Department (OCHD) to request information on potable water wells registered and/or known within the area. According to OCHD, the closest drinking water or other potable water well is located approximately 460 feet from the subject property. This well is located at 3 Mt Bolus Road and is up -gradient from the subject property. Known or registered down -gradient drinking water wells within 500 feet of site property line were not reported or visually observed by Falcon staff. The closest down -stream water supply system is Jordan Lake. The closest public water supply intake for this lake is located approximately 12.5 miles away from the subject property. SECTION 2 METHODS OF INVESTIGATION 2.1 Monitoring Well Abandonment, Installation, and Development During previous investigative efforts, three (3) groundwater monitoring wells had been installed, MW1, MW3, and MW4. MW1 was installed within the area of fill including some CCPs adjacent to the southwest corner of the Police Station Building. NC DENR requested the remaining two (2) wells (MW3 and MW4) be installed down gradient of the fill. MW3 was placed towards the western side of property within the wooded area north of Bolin Creek Greenway Trail. MW4 was placed towards the eastern side of property also within the wooded area north of Bolin Creek Greenway Trail. It should be noted that shallow depths and auger refusal were encountered. This may have been due to the natural geology and proximity to Bolin Creek. During previous attempts to collect samples, MW3 and MW4 produced insufficient groundwater with high turbidity readings that prevented accurate results. Results from these sampling activities were provided in previously submitted reports to NC DENR. The first phase of this investigation involved abandoning MW3 and MW4. Trigon Exploration was contracted by Falcon to abandon the two wells on January 6 and 7, 2015, respectively. The Well Abandonment Records are provided in Appendix C of this report Additional phase of the investigation involved the installation of two (2) new down gradient monitoring wells, MW3A and MW4A, on May 12 and 15, 2015, respectively. Falcon contracted American Environmental Drilling, Inc. to complete well installation. MW3A was located directly down gradient of the exposed fill materials just outside of the fence north of the Bolin Creek Greenway Trail. MW4A was placed farther east towards the eastern property boundary and just outside of the gate to the fence north of the Bolin Creek Greenway Trail. Refer to Figure 2 in Appendix A for well locations. The installation depth of MW3A was 16.0 ft below ground surface (bgs) and the installation depth of MW4A was 19.0 ft bgs. The static water level depth at time of install for MW3A was 10.0 ft bgs and MW4A was 4.0 ft bgs. Drill cuttings and purge water were contained to the proximity of well locations through the use of earthen berms as needed. The well were constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards. Well Construction records are provided in Appendix C of this report. The wells were purged on May 21-22 and July 20-22, 2015. MW 1 was purged on Aug 5, and 6, 2015. The method of purging the wells was by low flow pumping. Per the established guidance, After installing the wells 24- hours was allowed for the surface pad and protective casing to cure 8 prior to purging. The wells recharged following adequate purging of five (5) or more well volumes. To determine the number of gallons within one (1) well volume, the following equation was used: (Total depth of water) X (0.48 -conversion to well volumes in gallons) = # of gallons to purge. According to the US Environmental Protection Agency's (EPA's) Sampling Guidelines; "With respect to the ground water chemistry, an adequate purge is achieved when the pH and specific conductance of the ground water have stabilized and the turbidity has either stabilized or is below 10 Nephelometric Turbidity Units (NTUs)". While purging the three (3) wells, to determine when sampling could commence, a Hanna HI 98703 Turbidity Meter and YSI 556 MPS instrument were utilized to define turbidity, specific conductivity, temperature, and pH of groundwater within. 2.2 Groundwater Analytical Methods Samples were analyzed for volatile organic compounds (VOCs), 1,4-dioxane, semi -volatile organic compounds (SVOCs), metals, and hexavalent chromium. Table 1 provides the analytical methods that were used in the collection of these samples. Analytical methods including laboratory quality control and quality assurance (QA/QC) procedures were performed by Prism Laboratories, Inc. (NC Certification No. 402). Table I I Groundwater Analytical Methods Volatile Organic Compounds (VOC) 1,4-Dioxane Semi -volatile Organic Compounds (SVOC) Metals Hexavalent chromium 2.3 Groundwater Sampling Methods SW 846 Method 8260 SW 846 Method 8260 SIM USEPA method for detection limits below the 15A NCAC 2L standards USEPA Method 218.7 or 218.6 as modified by US EPA Region IV Sampling was done in general accordance with the January 2014 Inactive Hazardous Sites Program's Guidelines for Assessment and Cleanup (DENR Guidance\NC DENR Guidance Inactive Haz Sites.pdf) and the USEPA Technical Guidance (DENR Guidance\EPA Groundwater- Sampling.pdf) documents except as noted below. Sampling was performed following adequate WF. purging and after chemical parameter stabilization criteria have been reasonably met. According to the EPA sampling guidelines "Stabilization occurs when, for at least three consecutive measurements, the pH remains constant within 0.1 Standard Unit (SU) and specific conductance varies no more than approximately 5 percent." SECTION 3 ANALYTICAL RESULTS MW1, MW3A, and MW4A were initially sampled on May 26, 2015. The May 26 sampling event occurred before the wells met the chemical parameter stabilization criteria (as defined above) including low turbidity; therefore, the May sampling results are not an accurate indication of the dissolved phase concentration levels of the constituents of concern. However, most constituents were not identified during the May sampling event with the exception of the following metals: mercury, arsenic, barium, chromium, and lead. Table 2 below provides a summary of constituents of interest including those above the analytical reporting limits. A full laboratory report including QC/QA data is provided in Appendix D of this report. Table 2 1 May 2015 Initial Sampling Results (pre -well stabilization) Hexavalent Chromium Mercury Arsenic Barium Boron Cadmium Chromium (total) Lead Selenium Silver pg/L BRL BRL BRL N/A* pg/L BRL BRL 0.31 1 pg/L BRL 42 110 10 pg/L 54 770 150 700 pg/L BRL BRL BRL 700 pg/L BRL BRL BRL 2 pg/L BRL 460 98 10 pg/L BRL 89 61 15 pg/L BRL BRL BRL 20 pg/L BRL BRL BRL 20 * There is no 15A NCAC 02L .0202 Standard for Hexavalent Chromium, The Nation Primary Drinking Water Regulations set the Maximum Concentration Level for Total Chromium (which includes Hexavalent Chromium) at 100 Ng1L. The 15A NCAC 02L .0202 Standard for Total Chromium is 10 Ng1L UF Falcon returned to the site to purge and sample the three (3) wells. The analytical methods were also the same as provide in Table 1 above with the exception of not sampling for VOCs and SVOCs. Not sampling for organic compounds was pre -approved by NCDENR due to not detecting organic compound's during previous sampling events. MW3A and MW4A were purged of 9 well volumes on July 20 and 21 2015. MW3A stabilized with less than 10 NTUs. MW4A was also stable; however, the turbidity was at 24.7. NCDENR pre - approved filtered and non -filtered samples from MW4A. MW 1 was purged of 17 well volumes on July 21 and 22 but did not stabilize. Turbidity remained in the mid 100 NTUs. MW 1 was not sampled in July. MW 1 was purged again on August 5 and 6, 2015 in another effort to obtain samples from a stable well with low turbidity. However, turbidly ranged from unreadable to the high 100 NTUs. MW1 was not sampled in August. Not sampling MW1 was also monitored by NCDENR before and during sampling due to MW1 being installed already within the landfill material and having previously documented contamination. Table 3 below provides a summary of constituents of interest including those above the analytical reporting limits. A full laboratory report including QC/QA data is provided in Appendix D of this report. Table 3 1 July 2015 Additional Sampling Results (post -well stabilization) Hexavalent Chromium pg/L BRL BRL BRL N/A* Mercury pg/L BRL BRL BRL 1 Arsenic pg/L BRL BRL BRL 10 Barium pg/L 67 61 64 700 Boron pg/L 520 BRL BRL 700 Cadmium pg/L BRL BRL BRL 2 Total Chromium pg/L BRL BRL BRL 10 Lead pg/L BRL BRL BRL 15 Selenium pg/L BRL BRL BRL 20 Silver pg/L BRL BRL BRL 20 Values shown in BOLD are above the applicable standard BRL = Below Reporting Limit * There is no 15A NCAC 02L .0202 Standard for Hexavalent Chromium, The Nation Primary Drinking Water Regulations set the Maximum Concentration Level for Total Chromium (which includes Hexavalent Chromium) at 100 pg/L The 15A NCAC 02L .0202 Standard for Total Chromium is 10 pg/L 02F SECTION 4 SUMMARY OF FINDINGS Falcon completed an ESC Report for the Town of Chapel Hill at 828 Martin Luther King Jr. Boulevard located in Chapel Hill, Orange County, North Carolina. The purpose of the investigation was to evaluate the on -site groundwater for potential impacts within the property boundaries. Based upon our completed field activities and subsequent laboratory analysis Falcon was able to provide the following findings: 1. MW 1 was purged for two (2) additional days but failed to stabilize and was not sampled; 2. Barium, and Boron were detected at a concentration below the NC DENR 2L Groundwater Standard at MW3A; 3. Barium was detected at a concentration below the NC DENR 2L Groundwater Standard at MW4A in both the filtered and unfiltered samples; 4. Hexavalent Chromium was not detected in either down -gradient well. SECTION 5 RECOMMENDATIONS Falcon recommends that this report be submitted to NC DENR for their further review to assist them in recommending next steps. Based on the sampling results, it appears the previously identified coal combustion products have not exceeded the groundwater standards down gradient of the landfill within the property boundaries. NC DENR will likely consider the Town of Chapel Hill Police Department a low priority site. Following NC DENR review Falcon is available to provide additional consultation and recommended courses of action to comply with possible next steps. 12 APPENDIX A FIGURES k JF FIGURE 1 I GENERAL SITE LOCATION LF I& A 0 FIGURE 2 1 APPROXIMATE SAMPLING LOCATION MAP LF APPENDIX B PHOTOGRAPHS t JF ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police LeFa.Lt rent Proptl LY Groundwater Monitoring Well Installation — May 2015 k_ Typical Drill Rig Under -reamer Bit ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police LeF"L t rent Proptl LY Groundwater Monitoring Well Installation — May 2015 Typical set up Tarp used to protect the greenway ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police LeFa.Lt rent Proptl LY Groundwater Monitoring Well Installation — May 2015 Typical well MW3-A ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policc- LV�yaI «.Lient Property Groundwater Monitoring Well Installation — May 2015 �t M W4-A MW3-A ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policu- LVyFUL «.L1ent Property Groundwater Monitoring Well Installation — May 2015 TMA . ERICAN nvironmental Drilling, 111C. Aberdeen, NC 910-944-3140 WELL ID#- • CONTRACTOR# � 7 DATE. 2e4WDEPTH FT. CASING DEPTH:,—t�— FT, DIA; IN. SCREEN: ■:! TO SAND: _ at TO BENTONITE; �R T[[ GROUT �[ 'A�[ WARNING GROUND WATER MONITORING CAUTION NO- "ATEI Typical signage C _ k t � •. � k ON i OFF 0 CAL ■ LIGHT GLP • E RCL M LOG lCFM ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Polio LVyFUI «.L1ent Property Groundwater Sampling Event — July 2015 Second Purge Turbidity Reading — MW-3A YSI Instrument Reading— Between 1st and 2nd Purge — MW-3A ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Polices LeFa.Lt rent Proptl LY Groundwater Sampling Event — July 2015 MW-4A Purging 7/20/2015 YSI Instrument Reading— Before 15t Purge MW-4A ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Polices LeF"L t rent Proptl LY Groundwater Sampling Event — July 2015 Turbidity Reading— MW-4A— Before 111 Purge Turbidity Reading— MW-4A— Before 2nd Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 YSI Instrument Reading — Before 2nd Purge — MW-4A Purging Well-1— 7/20/2015 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 J YSI Instrument Reading — 3rd Purge — MW-4A Turbidity Reading— MW-4A ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Polices LeF"L t rent Proptl LY Groundwater Sampling Event — July 2015 YSI Instrument Reading —4th Purge— MW-4A Turbidity Reading— MW-4A 5th Purge 7/21/2015 ENVIRONMENTAL SITE CHARACTERIZATION r- Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 YSI Instrument Reading — 6t" Purge — MW-3A 7/21/2015 Turbidity Reading — MW-3A — 6t" Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policc- Lv�YaI «.L1ent Property Groundwater Sampling Event — July 2015 YSI Instrument Readine — 6th Puree — MW-4A Lt� H198703 im6idimere Fae� T—ke Turbidity Reading — MW-4A — 6' Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 YSI Instrument Reading — Th Purge — MW-3A YSI Instrument Reading — MW-3A — 8th Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policc- Lv�YaI «.L1ent Property Groundwater Sampling Event — July 2015 Turbidity Reading — 81h Purge — MW-3A Turbidity Reading — Well-1— 8th Purge 7/21/2015 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 Turbidity Reading — 10th Purge —Well 1 7/22/2015 Purging Well-1-7/22/2015 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 Turbidity Reading — 11t" Purge — Well-1 Turbidity Reading— 13th Purge at Well-1 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Polices LeF"L t rent Proptl LY Groundwater Sampling Event — July 2015 YSI Instrument Reading — 131" Purge — Well-1 YSI Instrument Reading — 14' Purge at Well-1 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 Turbidity Reading — 14t" Purge — Well-1 �Al ��� = Turbidity Reading— 16th Purge at Well-1 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policc- Lv�YaI «.L1ent Property Groundwater Sampling Event — July 2015 YSI Instrument Reading — 161h Purge — Well-1 • :3 0 NTU Turbidimeter Turbidity Reading — 17th Purge at Well-1 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Groundwater Sampling Event — July 2015 YSI Instrument Reading — 17th Purge — Well-1 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Purging Well-1 —August 2015 Purging—Well-1 8/5/2015 YSI Instrument Reading — Well-1— First Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policu- Lv�YaI «.L1ent Property Purging Well-1 —August 2015 Turbidity Reading —1st Purge, too high Purged Well Water— Well 1 ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policu- LeFaJLtment Proptl LY Purging Well-1 —August 2015 YSI Instrument Reading — 2nd Purge — Well-1 Turbidity Reading — Well-1— 2nd Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policu- LeFaJLtment Proptl LY Purging Well-1 —August 2015 YSI Instrument Reading — 3rd Purge — Well-1 Turbidity Reading — Well-1— 3rd Purge ENVIRONMENTAL SITE CHARACTERIZATION Lj Chapel Hill Policu- LeFaJLtment Proptl LY Purging Well-1 —August 2015 Turbidity Reading — 4t" Purge — Well-1 YSI Instrument Reading — Well-1— 4t" Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policu- LeFaJLtment Proptl LY Purging Well-1 —August 2015 Turbidity Reading — 5t" Purge — Well-1 Y51 Instrument Reading — Well-1— 5t" Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Police Department Property Purging Well-1 —August 2015 Turbidity Reading — 61h Purge —Well-1 8/6/2015 7 YSI Instrument Reading — Well-1— 61h Purge ENVIRONMENTAL SITE CHARACTERIZATION Chapel Hill Policu- LeFaJLtment Proptl LY Purging Well-1 —August 2015 Turbidity Reading — 7t" Purge — Well-1 APPENDIX C WELL RECORDS k JF WELL CONSTRUCTION RECORD This form can be used for single or multiple wells For Internal Use ONLY: 1. Well Contractor Information: Kelly Grant Well Contractor Name 2730 A NC Well Contractor Certification Number American Environmental Drilling, Inc. Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, Injection, etc) 3. Well Use (check well use): Water Supply Well: ❑Agricultural ❑Geothermal (Heating/Cooling Supply) ❑ lndustrial/Commercial ❑ Irrigation Non -Water Supply Well: El Aquifer Recharge El Aquifer Storage and Recovery ❑Aquifer Test ❑Experimental Technology ❑Geothermal (Closed Loop) ❑Geothermal (Heating/Cooling ❑Municipal/Public El Residential Water Supply (single) ❑Residential Water Supply (shared) El Groundwater Remediation ❑ Salinity Barrier ❑ Stormwater Drainage ❑Subsidence Control ❑Tracer ❑Other (explain under #21 F 4. Date Well(s) Completed: 5-12-15 Well ID# MW-3A 5a. Well Location: CITY OF CHAPEL HILL Facility/Owner Name Facility ID# (if applicable) 828 Martin Luther King Blvd. Physical Address, City, and Zip ORANGE County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) 35.925603 N-79.052656 W 6. Is (are) the well(s): ❑1 Permanent or El Temporary 7. Is this a repair to an existing well: ❑Yes or FINo If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. Number of wells constructed: 1 For multiple injection or non -water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: 16 (ft.) For multiple wells list all depths if different (example- 3@200' and 2@100') 10. Static water level below top of casing: 10 (ft.) If water level is above casing, use "+" 11. Borehole diameter: 6" (in.) 12. Well construction method: AI R ROTARY (i.e. auger, rotary, cable, direct push, etc.) 14. WATER ZONES FROM TO DESCRIPTION 10 rt 16 rt ft. ft. 15. OUTER CASING for multi -cased wells OR LINER if a licable FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. 16. INNER CASING OR TUBING eother at closed -loop) FROM TO I DIAMETER I THICKNESS I MATERIAL -.6 rt. 1 rt. 2 " SCH40 I PVC fL fL in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL 1 rt• 16 ft' 2 in. .010 SCH40 PVC ft. ft, in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT 6 rt. 1 1" BENTONITE POUR O ft. .6 ft. NEAT CEMEP POUR rt. rt. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD 1 rL 16 rt #2 POUR rt. rt. 20. DRILLING LOG attach additional sheets if necessary) FROM TO DESCRIPTION color, hardness, soil/rock type, grain size, etc.) O rt. 5 rt. BROWN CLAY AND ROCK 5 rt 16 rt GRAY BLACK ROCK ft. rt. rt. rt. rt. rL ft. ft. rt. rt. 21. REMARKS 22. Certification: 5-18-15 Signature o!Sprilffied Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Iniection Wells ONLY: In addition to sending the form to the address in 24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636 13a. Yield m Method of test: 24c. For Water Supply & Injection Wells: (gP ) Also submit one copy of this form within 30 days of completion of 13b. Disinfection type: Amount: well construction to the county health department of the county where constructed. Form GW-1 North Carolina Department of Environment and Natural Resources - Division of Water Resources Revised August 2013 WELL CONSTRUCTION RECORD This form can be used for single or multiple wells For Internal Use ONLY: 1. Well Contractor Information: Kelly Grant Well Contractor Name 2730 A NC Well Contractor Certification Number American Environmental Drilling, Inc. Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, Injection, etc) 3. Well Use (check well use): Water Supply Well: ❑Agricultural ❑Geothermal (Heating/Cooling Supply) ❑ lndustrial/Commercial ❑ Irrigation Non -Water Supply Well: El Aquifer Recharge El Aquifer Storage and Recovery ❑Aquifer Test ❑Experimental Technology ❑Geothermal (Closed Loop) ❑Geothermal (Heating/Cooling ❑Municipal/Public El Residential Water Supply (single) ❑Residential Water Supply (shared) El Groundwater Remediation ❑ Salinity Barrier ❑ Stormwater Drainage ❑Subsidence Control ❑Tracer ❑Other (explain under #21 F 4. Date Well(s) Completed: 5-14-15 Well ID# MW-4A 5a. Well Location: CITY OF CHAPEL HILL Facility/Owner Name Facility ID# (if applicable) 828 Martin Luther King Blvd. Physical Address, City, and Zip ORANGE County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) 35.925526 N-79.052109 W 6. Is (are) the well(s): ❑1 Permanent or El Temporary 7. Is this a repair to an existing well: ❑Yes or FINo If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form. 8. Number of wells constructed: 1 For multiple injection or non -water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: 19 (ft.) For multiple wells list all depths if different (example- 3@200' and 2@100') 10. Static water level below top of casing: 4 (ft.) If water level is above casing, use "+" 11. Borehole diameter: 6" (in.) 12. Well construction method: AI R ROTARY (i.e. auger, rotary, cable, direct push, etc.) 14. WATER ZONES FROM TO DESCRIPTION 4 rt 19 rt ft. ft. 15. OUTER CASING for multi -cased wells OR LINER if a licable FROM TO DIAMETER THICKNESS MATERIAL ft. ft. in. 16. INNER CASING OR TUBING eother at closed -loop) FROM TO I DIAMETER I THICKNESS I MATERIAL -.6 ft' 4 12 "' I SCH40 I PVC fL fL in. 17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL 4 ft. 19 ft. 2 in. .010 SCH40 PVC ft. ft, in. 18. GROUT FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT 1 rt. 2 rt. BENTONITE POUR 0 ft. 1 ft. NEAT CEMEP POUR rt. rt. 19. SAND/GRAVEL PACK (if applicable) FROM TO MATERIAL EMPLACEMENT METHOD 2 fL 19 ft #2 POUR rt. rt. 20. DRILLING LOG attach additional sheets if necessary) FROM TO DESCRIPTION color, hardness, soillrock type, grain size, etc.) O ft 15 ft BROWN CLAY AND ROCK 15 ft 19 ft GRAY BLACK ROCK ft. rt. rt. rt. rt. rL ft. ft. rt. rt. 21. REMARKS 22. Certification: 5-18-15 Signature o!Sprilffied Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Iniection Wells ONLY: In addition to sending the form to the address in 24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636 13a. Yield m Method of test: 24c. For Water Supply & Injection Wells: (gP ) Also submit one copy of this form within 30 days of completion of 13b. Disinfection type: Amount: well construction to the county health department of the county where constructed. Form GW-1 North Carolina Department of Environment and Natural Resources - Division of Water Resources Revised August 2013 WELL ARANDONW NT MEC ORD This form can he used ror single or muhipic wells Fur lularunl Use ONLY 1. Well Contractor Information: So 1)rti W,264,E-1j [ L� 1r+ t Lf4A A-') ., Well Contractor Name (or- wcl l ownor personally aWndoning well nn hislltor pr'nliatly) 3, D 1Z 12^ 4 No Well corilra:lnr Corti[5knlirnt Nmulwr WELL ARANDONMEN1 DETAtL5 !! 7a, dumber of wells being abandoned: 1 P'or multiple fnjrcrt(ur or trgtr-walet stlPply wells ONLY with eliv .sums L'lr119fr1rC'tlnlefu6undGhm('III, yore IXtn submit 0"a lbrmr. 7b. Approuluiate volume of water remaining in well(s). ___ _ ^(gal.) �L�i bnto 1FOR WATER SUPPLY WF,I,I S ONLY: companyNeme NIA 7t;'Type of disinfectant used: 2. Well Construction Permit#: 1 Y i List all npplicnhle wrhperlluts (.e. Courrry, Sl te. 61(rrimnce, hjccrion, etc) i07?nwn 7d. Amount of diitinfectang used' 3. Well use (check well ase): Water Supply Well: nAgricpinrral ❑{ cothermal (I lea[ing/Cuoling Supply) fl Industrial/Commercial FIVIirnicipafliluhl io ❑Residential Water Supply (single) MReaidential Water Supply (Shared) Non -Water Supply Well: em onitoring EIRccovery OAquifcr RecharSc DAquilcr Staragc and Rccovery ❑Aquitbr Test ❑Experimental Technology ❑Geothermal (Closed L(Kip) ❑Geothermal (HcudnSk;ouling DGroundwatcr Remcdiation OSelinity Barrier ❑Siormwater Drainage ❑Subsidence Control ❑Truccr ❑othcr (explain under 79) A. Date well(s) ahsudnned: I — '7 ^ 1 S Sa. Well location: j Facilityl0wnerName I+neilit Ifill(if aFpllcnble) Blvd 'I Physi a) Address. City, and Zip J -2 :]WIS i� ` A Yap CounlYU llanxt ldcmilla;ttion Na, (PIN) Sb. Latilude and longitude In pr decimal degrees: (ifwoll fsold, one tatlloug is sufficient) CONS RIA PION 13FTA11 W11S)_ICINGABANDONED Attach well cnnstructran recorrf(v) 1favWlONIJP. Aire rnrJrttdd lhjeerina nr non-wufer.rvpprji wells ONLY with the mma colrarrrrctlolr/{rhgrtdotundnl, you corn suhnill Vhe f&m. 6a. Well IWO: &\ 6b, Total well dcplh: 1 L (ft.) 6c. Borehole diainater: e (ire.) 6d. Water level below ground aurfecc: (ft.) 6e. Outer cas lug length (if known): ._ _ (ft.) !f. Inner casing/tubing length (if known): (ft.) 6g. Screen length (if known): _ (ft.) 7e. Sealing materials used (check all that apply): D Neat Content Grout ❑ 13entunitc Chips or Ncllct% ❑ Sand Ct:menl Grout ❑ Concrete Gmp[ ❑ Speciulty UTOMI. ❑ Beulonite 51uny 13 Dry Clay ❑ Drill Cuttings © Gravel n'fXhcr (explain under 7g) 7f. For each material selected above, provide amount of materials ilsed, 7g. Provide a brief description of the abandonment procedttlre: _ N"Lj+ 1U L �'I I K `T l Cds.0 c C d 11V7-0 ll. Ccr•tiflcatiuu: SignahtreafCerdfiedWell 0mimrrnr„rWilli Owner Date Dy sigrrfng tlrlrforrm, 1 lrar* Mrl(1y thee/ 11rc rvc'll(s) 111as (were) ahandlaned Ili accordance: with I SA NCi1C 02C .0100 or.2(7, .0200 Well C.'q»slrr�c/lptr Stctq<larrls and that a copy of Ili& record fray been provided to the well owner. 9. Site diagram or additional well details: You may use the back of ibis page to provide additional well sift details or well abandonment details, Yntr may also attach additional pages if necessary. SUIliyiITTAI, iNSTRUCTIONS Ina. Fnr All Wells: Stlhntil this funn within 34) slays of completion of well abandonment to the fit'llowing: Division of Water Resources, Information Processing trait, 1617 Mall Scrvlev Ccolcr, Knlclgh, NC 27699-1617 10b. For 1p : In addition to Serldinb the form to the addreis in 10a above, also submit one copy of this form within 30 days of coinpletiotr of well 0bal1d0nment to the following; DIvisinn of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Rnlelgh, NC 27699-1636 We. EaWater supply & Infection. Welln; In addition to sending [tie form to the addr@M{ea) above; ulsu submit one copy of this form within 30 days of completion (if well abandonment to the county healrli department of the county where abandoned. Fenn 0W-30 North (_nrrrlirrn Dqurrlment of Frnvwunmenl find Noturnl Resources — Division of Water fZo%nartes Revised Augus12013 coo 0 YVA To:ZT STOZ/99/TO WELL ABANDONMENT REC OHD This Form can be uscd for single or multiple wcllq 1. Well Contractor Information: Well Contraeior Name (or well owner personally nbandoning well on hirlher properly) a 079 - NC WO C;onrraetor Certification Number Foe internal Use-, ONLY: WFLL ARANDONIV11PN t' OETAILA 7a. Nnmberofwells being abnndoned: f _ For mulfiph• or/eclinn ur pan-v-tttt!r .,,pnry 'ellm !lNi,Y with the son,rr can,rlrvcrirfrr/nhnrrdrrrtAunrr, Y�rr van swbaiii one firrm, 7b. Approximate volume of water remaining In well(s): (gal.) E V- P4.0 k-4 /t o6'V I FOR WATER SUPPLY WELLS ONLY: Uur„ puny Nomo ! , � 7c. xj+[rc of d(sfnfccatnt uscd: 2. Well Construction permit it: N l,7xi rhli applicably welllx'naili ftt!' ("aunIJA .State. Vaelwuv. huaction, etc) fl'knawrr 17d. Amount ordisinfectam used: 3. Well u:se (check well use): ❑Agriuultural ❑Gs±otltetrnal {Hcating/C'vnlint; Supply) f:] lnduslriai/Co:tutlercial Supply Well: FJAquifer Recharge []Aquifer Storage and Rcuurcry ❑Aquiler'lcst 71hxperimenwi Technology Csf ieotherowl (Closed Loop) ❑Ucotherrhul (I leating/Cooling ❑Municipal/public []Residential Water Supply (single) r-lResidemial Water Supply (shared) FEI nCroundwaler Remediation EISalinity Harrier ❑Stormwater Drainage t lSubsidcnee Control zlTrucer oothcr (explain under 7Z) d, 92tte well(s) abandoned: t S 7e. Seaiing Materials used (check all that apply): ❑ Neat Cement Croat E3 Bcntonitc Chips or pellets ❑ Sand C Crot-apt Grout ❑ Concrete Grout rl SpecialtyCrout ❑ Benlonite Slurry 0 Dry Clay L] Dtill Cuttings ❑ Caravel C�Othcr (explain under 7g) 7E For each material selected above, provide amount of material* used: 7g. Provide a brief dewription of the abandonment procedure: v rt1 i i = Ib li •'C- 'f'ii, Q( ( .._ C I)CA( CD c,%er- J' C-014tp c.) r zt- ip J2JQr. eFf i,Ll 110 /r; r:46ou C rc��-��� 5 ccC J uc Sa. Well location: fuy4 C Is. Certification; dnoilily/Owner Name Facility IDh (if applicable) Ul Ma All Vd r4y) YL01 Physical Addresx, City, and tin GSil{nniwe a t'rrrined Well Ca,ntr+Wlrte oe Well Owner Al/'A van n 4-1a011 t 2L n - WIC fly signing 1hls,form. I hereby reriffy that the evell(s) was (were) zhal7doned in enwHy ,J rrarcal Idcntiflulion No. (PIN) accordance with 15.4 NCAC 02C .0100 or 7C .0200 Will C..odslrttCllgn .Standards and thal a tajry of this record has been prmNded 10 1/w upell owner. Sh. Lolitudc and longitude In degreeslminuteslaceneids or decimal degrees; (if welt field, one lift/lonit is sulticiaar) 9. Site diagram or additional Well detalls- 161 W You may use the back of this page to provide additional well site dcialls or well abandonment details, `'vu may also otinch additional pages if necessary. BEING A1IANDONEfl 1 S Attach wcl/ eunrfrrrrllan reewtf(s) if available, 1'or Mulliple infecIdan err r1im-waler supply wctlrONLY with the.mmerrrnsrrhrrtlannArlrrdunmcnf, {�arrtarr.whmin,nc,fr,rno. 102 For All Wells: Submit this form within 30 da s of c I t! n rw If ra, Wcn ID#: �(�ll! L C� 6b. Total well depth: I , (fit.} fie, 6orehoie diameter; (in.) 6d, Water level below ground surface: --42 (fit.) abandonment to the fallowing: y amp 4 to u c Division of Water Resources, I.nformatiurt Proec"Ing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 Itch. for infection Wells: in addition to sending the form to the address in l0a above, also submit one copy of this furm within 30 days of completion of well abandonment to the fallowing: Division of Water Resources, Underground injection Control Program. 1636 Mail Ccrvice Center, Raleigh, NC 27699-1636 10c. jrgr War Sunnly & Injcctfun W0111: In addition to sending the fnrm to 6e, outer casing length (if known): (ft.) the nddrms(e) above, Also .submit one copy of thix filrrn within 30 clays of complclion of well abandonment to the county health department of the county Gf- Inner casing/tubing length (if known): (fit.) where abandoned. 6g. Screen length (If known): (ft,) Form GW-10 worth Carolina of Favironment and Natural Resowces- Division of Walel' Retowcol Revised August 2013 ZOOM] XYd 93 :TT STOZ/9Z/TO APPENDIX D LABORATORY DATA k JF RIS Full -Service Analytical Environmental Solutions /PM 1W_Z1�, LABOFATOAIES.INC. Falcon Engineering Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 NC Certification No. 402 SC Certification No. 99012 NC Drinkinq Water Cent No. 37735 VA Certification No. 460211 DoD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Project: 828 MLK - CHPD Lab Submittal Date: 07/22/2015 Prism Work Order: 5070434 Case Narrative 08/10/2015 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. a�'J Angela D. Overcash VP Laboratory Services Data Qualifiers Key Reference: Reviewed By Terri W. Cole For Angela D. Overcash Project Manager D RPD value outside of the control limits. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). SR Surrogate recovery outside the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 38 bnRISM Fullironm n Analyticals-' Environmental Solutions �Ili —a ATIEs,ING Sample Receipt Summary 08/10/2015 Prism Work Order: 5070434 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received MW3A 5070434-01 Water 07/21/15 07/22/15 MW4A 5070434-02 Water 07/21/15 07/22/15 MW4A Filtered 5070434-03 Water 07/21/15 07/22/15 Samples were received in good condition at 3.1 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 38 Summary of Detections P Full -Service Analytical &Environmental RI Solutions SM 08/10/2015 a Prism Work Order: 5070434 Prism ID Client ID Parameter Method Result Units 5070434-01 MW3A Barium `6010C 0.067 mg/L 5070434-01 MW3A Boron '6010C 0.52 mg/L 5070434-02 MW4A Barium '6010C 0.064 mg/L 5070434-03 MW4A Filtered Barium `6010C 0.061 mg/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Project: 828 MLK - CHPD Sample Matrix: Water Client Sample ID: MW3A Prism Sample ID: 5070434-01 Prism Work Order: 5070434 Time Collected: 07/21/15 15:33 Time Submitted: 07/22/15 10:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hexavalent Chromium BRL mg/L 0.010 0.0037 1 *SM3500-Cr B 7/22/15 13:30 CDL P5G0401 Organochlorine Pesticides by GC/ECD 4,4'-DDD BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:28 JMC P5G0466 4,4'-DDE BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:28 JMC P5G0466 4,4'-DDT BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:28 JMC P5G0466 Aldrin BRL ug/L 0.050 0.015 1 8081B 8/6/15 22:28 JMC P5G0466 alpha-BHC BRL ug/L 0.050 0.012 1 8081B 8/6/15 22:28 JMC P5G0466 cis -Chlordane BRL ug/L 0.050 0.018 1 8081B 8/6/15 22:28 JMC P5G0466 beta-BHC BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:28 JMC P5G0466 Chlordane BRL ug/L 0.50 0.34 1 8081B 8/6/15 22:28 JMC P5G0466 delta-BHC BRL ug/L 0.050 0.017 1 8081B 8/6/15 22:28 JMC P5G0466 Dieldrin BRL ug/L 0.050 0.022 1 8081B 8/6/15 22:28 JMC P5G0466 Endosulfan I BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:28 JMC P5G0466 Endosulfan II BRL ug/L 0.050 0.025 1 8081B 8/6/15 22:28 JMC P5G0466 Endosulfan Sulfate BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:28 JMC P5G0466 Endrin BRL ug/L 0.050 0.020 1 8081B 8/6/15 22:28 JMC P5G0466 Endrin Aldehyde BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:28 JMC P5G0466 Endrin Ketone BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:28 JMC P5G0466 gamma-BHC BRL ug/L 0.050 0.013 1 8081B 8/6/15 22:28 JMC P5G0466 trans -Chlordane BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:28 JMC P5G0466 Heptachlor BRL ug/L 0.050 0.015 1 8081B 8/6/15 22:28 JMC P5G0466 Heptachlor Epoxide BRL ug/L 0.050 0.018 1 8081B 8/6/15 22:28 JMC P5G0466 Methoxychlor BRL ug/L 0.050 0.033 1 8081B 8/6/15 22:28 JMC P5G0466 Toxaohene BRL ua/L 050 0.16 1 9081R R/6/15 22-28 IMC P5G0466 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 BRL ug/L Aroclor 1221 BRL ug/L Aroclor 1232 BRL ug/L Aroclor 1242 BRL ug/L Aroclor 1248 BRL ug/L Aroclor 1254 BRL ug/L Aroclor 1260 BRL ug/L Semivolatile Organic Compounds by GC/MS Surrogate Recovery Control Limits Decachlorobiphenyl 70 % 13-186 Tetrachloro-m-xylene 64 % 40-134 0.50 0.18 1 8082A 8/6/15 22:28 JMC P5G0467 1.0 0.11 1 8082A 8/6/15 22:28 JMC P5G0467 0.50 0.16 1 8082A 8/6/15 22:28 JMC P5G0467 0.50 0.14 1 8082A 8/6/15 22:28 JMC P5G0467 0.50 0.14 1 8082A 8/6/15 22:28 JMC P5G0467 0.50 0.16 1 8082A 8/6/15 22:28 JMC P5130467 0.50 0.18 1 8082A 8/6/15 22:28 JMC P5130467 Surrogate Recovery Control Limits Tetrachloro-m-xylene 64 % 30-161 Decachlorobiphenyl 69 % 32-178 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW3A Attn: Jessica Hoglen Prism Sample ID: 5070434-01 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:33 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 1-Methyl naphthalene BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 8270D 7/24/15 17:01 JMV P5G0413 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 8270D 7/24/15 17:01 JMV P5G0413 2,4-Dichlorophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 2,4-Dimethyl phenol BRL ug/L 10 2.3 1 8270D 7/24/15 17:01 JMV P5G0413 2,4-Dinitrophenol BRL ug/L 10 3.7 1 8270D 7/24/15 17:01 JMV P5G0413 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 8270D 7/24/15 17:01 JMV P5G0413 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 2-Chloronaphthalene BRL ug/L 10 3.4 1 8270D 7/24/15 17:01 JMV P5G0413 2-Chlorophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 2-Methyl naphthalene BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 2-Methylphenol BRL ug/L 10 2.1 1 8270D 7/24/15 17:01 JMV P5G0413 2-Nitroaniline BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 2-Nitrophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 3/4-Methyl phenol BRL ug/L 10 1.9 1 8270D 7/24/15 17:01 JMV P5G0413 3-Nitroaniline BRL ug/L 10 1.2 1 8270D 7/24/15 17:01 JMV P5G0413 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 8270D 7/24/15 17:01 JMV P5G0413 4-Chloroaniline BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 4-Nitroaniline BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 4-Nitrophenol BRL ug/L 10 0.66 1 8270D 7/24/15 17:01 JMV P5G0413 Acenaphthene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 Acenaphthylene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 Aniline BRL ug/L 10 2.1 1 8270D 7/24/15 17:01 JMV P5G0413 Anthracene BRL ug/L 10 3.0 1 8270D 7/24/15 17:01 JMV P5G0413 Azobenzene BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 Benzo(a)anthracene BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 Benzo(a)pyrene BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 8270D 7/24/15 17:01 JMV P5G0413 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 Benzoic Acid BRL ug/L 100 2.7 1 8270D 7/24/15 17:01 JMV P5G0413 Benzyl alcohol BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 Butyl benzyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW3A Attn: Jessica Hoglen Prism Sample ID: 5070434-01 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:33 Time Submitted: 07/22/15 10:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chrysene BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 Dibenzo(a,h)anth racene BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 Dibenzofuran BRL ug/L 10 2.3 1 8270D 7/24/15 17:01 JMV P5G0413 Diethyl phthalate BRL ug/L 10 1.9 1 8270D 7/24/15 17:01 JMV P5G0413 Dimethyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 Di-n-butyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:01 JMV P5G0413 Di-n-octyl phthalate BRL ug/L 10 1.7 1 8270D 7/24/15 17:01 JMV P5G0413 Fluoranthene BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 Fluorene BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 Hexachlorobenzene BRL ug/L 10 1.9 1 8270D 7/24/15 17:01 JMV P5G0413 Hexachlorobutadiene BRL ug/L 10 2.6 1 8270D 7/24/15 17:01 JMV P5G0413 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 Hexachloroethane BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 8270D 7/24/15 17:01 JMV P5G0413 Isophorone BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 Naphthalene BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 Nitrobenzene BRL ug/L 10 2.4 1 8270D 7/24/15 17:01 JMV P5G0413 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 Pentachlorophenol BRL ug/L 10 2.5 1 8270D 7/24/15 17:01 JMV P5G0413 Phenanthrene BRL ug/L 10 1.8 1 8270D 7/24/15 17:01 JMV P5G0413 Phenol BRL ug/L 10 1.2 1 8270D 7/24/15 17:01 JMV P5G0413 Pyrene BRL ug/L 10 2.2 1 8270D 7/24/15 17:01 JMV P5G0413 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 90 % 49-109 2-Fluorobiphenyl 75 % 55-96 2-Fluorophenol 46 % 27-74 Nitrobenzene-d5 66 % 53-99 Phenol-d5 31 % 11-52 Terphenyl-d14 99 % 42-133 Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/23/15 12:52 JAB P5G0417 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/30/15 17:29 BGM P5G0450 Barium 0.067 mg/L 0.010 0.00070 1 *6010C 7/30/15 17:29 BGM P5G0450 Boron 0.52 mg/L 0.50 0.0043 1 *6010C 7/30/15 17:29 BGM P5G0450 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/30/15 17:29 BGM P5G0450 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/30/15 17:29 BGM P5G0450 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/30/15 17:29 BGM P5G0450 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/31/15 16:48 BGM P5G0450 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/30/15 17:29 BGM P5G0450 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 8260B 7/28/15 15:29 MSC P5G0524 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 8260B 7/28/15 15:29 MSC P5G0524 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW3A Attn: Jessica Hoglen Prism Sample ID: 5070434-01 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:33 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 8260B 7/28/15 15:29 MSC P5G0524 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 8260B 7/28/15 15:29 MSC P5G0524 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 8260B 7/28/15 15:29 MSC P5G0524 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 8260B 7/28/15 15:29 MSC P5G0524 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 8260B 7/28/15 15:29 MSC P5G0524 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 8260B 7/28/15 15:29 MSC P5G0524 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 8260B 7/28/15 15:29 MSC P5G0524 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 8260B 7/28/15 15:29 MSC P5G0524 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 8260B 7/28/15 15:29 MSC P5G0524 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 8260B 7/28/15 15:29 MSC P5G0524 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 8260B 7/28/15 15:29 MSC P5G0524 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:29 MSC P5G0524 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 8260B 7/28/15 15:29 MSC P5G0524 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 7/28/15 15:29 MSC P5G0524 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:29 MSC P5G0524 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 8260B 7/28/15 15:29 MSC P5G0524 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 8260B 7/28/15 15:29 MSC P5G0524 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 8260B 7/28/15 15:29 MSC P5G0524 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 7/28/15 15:29 MSC P5G0524 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 8260B 7/28/15 15:29 MSC P5G0524 2-Chlorotoluene BRL ug/L 0.50 0.066 1 8260B 7/28/15 15:29 MSC P5G0524 4-Chlorotoluene BRL ug/L 0.50 0.050 1 8260B 7/28/15 15:29 MSC P5G0524 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 8260B 7/28/15 15:29 MSC P5G0524 Acetone BRL ug/L 5.0 0.31 1 8260B 7/28/15 15:29 MSC P5G0524 Acrolein BRL ug/L 20 0.20 1 8260B 7/28/15 15:29 MSC P5G0524 Acrylonitrile BRL ug/L 20 0.20 1 8260B 7/28/15 15:29 MSC P5G0524 Benzene BRL ug/L 0.50 0.048 1 8260B 7/28/15 15:29 MSC P5G0524 Bromobenzene BRL ug/L 0.50 0.057 1 8260B 7/28/15 15:29 MSC P5G0524 Bromochloromethane BRL ug/L 0.50 0.14 1 8260B 7/28/15 15:29 MSC P5G0524 Bromodichloromethane BRL ug/L 0.50 0.062 1 8260B 7/28/15 15:29 MSC P5G0524 Bromoform BRL ug/L 1.0 0.040 1 8260B 7/28/15 15:29 MSC P5G0524 Bromomethane BRL ug/L 1.0 0.18 1 8260B 7/28/15 15:29 MSC P5G0524 Carbon disulfide BRL ug/L 5.0 0.075 1 8260B 7/28/15 15:29 MSC P5G0524 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 8260B 7/28/15 15:29 MSC P5G0524 Chlorobenzene BRL ug/L 0.50 0.062 1 8260B 7/28/15 15:29 MSC P5G0524 Chloroethane BRL ug/L 0.50 0.22 1 8260B 7/28/15 15:29 MSC P5G0524 Chloroform BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:29 MSC P5G0524 Chloromethane BRL ug/L 0.50 0.079 1 8260B 7/28/15 15:29 MSC P5G0524 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 8260B 7/28/15 15:29 MSC P5G0524 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 8260B 7/28/15 15:29 MSC P5G0524 Dibromochloromethane BRL ug/L 0.50 0.081 1 8260B 7/28/15 15:29 MSC P5G0524 Dibromomethane BRL ug/L 0.50 0.065 1 8260B 7/28/15 15:29 MSC P5G0524 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 8260B 7/28/15 15:29 MSC P5G0524 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW3A Attn: Jessica Hoglen Prism Sample ID: 5070434-01 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:33 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Ethylbenzene BRL ug/L 0.50 0.061 1 8260B 7/28/15 15:29 MSC P5G0524 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 8260B 7/28/15 15:29 MSC P5G0524 Isopropyl Ether BRL ug/L 0.50 0.050 1 8260B 7/28/15 15:29 MSC P5G0524 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 8260B 7/28/15 15:29 MSC P5G0524 m,p-Xylenes BRL ug/L 1.0 0.12 1 8260B 7/28/15 15:29 MSC P5G0524 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 8260B 7/28/15 15:29 MSC P5G0524 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 8260B 7/28/15 15:29 MSC P5G0524 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 8260B 7/28/15 15:29 MSC P5G0524 Methylene Chloride BRL ug/L 1.0 0.083 1 8260B 7/28/15 15:29 MSC P5G0524 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 8260B 7/28/15 15:29 MSC P5G0524 Naphthalene BRL ug/L 1.0 0.19 1 8260B 7/28/15 15:29 MSC P5G0524 n-Butylbenzene BRL ug/L 1.0 0.076 1 8260B 7/28/15 15:29 MSC P5G0524 n-Propylbenzene BRL ug/L 0.50 0.087 1 8260B 7/28/15 15:29 MSC P5G0524 o-Xylene BRL ug/L 0.50 0.044 1 8260B 7/28/15 15:29 MSC P5G0524 sec-Butylbenzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:29 MSC P5G0524 Styrene BRL ug/L 0.50 0.047 1 8260B 7/28/15 15:29 MSC P5G0524 tert-Butylbenzene BRL ug/L 0.50 0.088 1 8260B 7/28/15 15:29 MSC P5G0524 Tetrachloroethylene BRL ug/L 0.50 0.098 1 8260B 7/28/15 15:29 MSC P5G0524 Toluene BRL ug/L 0.50 0.044 1 8260B 7/28/15 15:29 MSC P5G0524 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 8260B 7/28/15 15:29 MSC P5G0524 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 8260B 7/28/15 15:29 MSC P5G0524 Trichloroethylene BRL ug/L 0.50 0.078 1 8260B 7/28/15 15:29 MSC P5G0524 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 8260B 7/28/15 15:29 MSC P5G0524 Vinyl acetate BRL ug/L 2.0 0.060 1 8260B 7/28/15 15:29 MSC P5G0524 Vinyl chloride BRL ug/L 0.50 0.097 1 8260B 7/28/15 15:29 MSC P5G0524 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Project: 828 MLK - CHPD Sample Matrix: Water Client Sample ID: MW4A Prism Sample ID: 5070434-02 Prism Work Order: 5070434 Time Collected: 07/21/15 15:50 Time Submitted: 07/22/15 10:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hexavalent Chromium BRL mg/L 0.010 0.0037 1 *SM3500-Cr B 7/22/15 13:30 CDL P5G0401 Organochlorine Pesticides by GC/ECD 4,4'-DDD BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:40 JMC P5G0466 4,4'-DDE BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:40 JMC P5G0466 4,4'-DDT BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:40 JMC P5G0466 Aldrin BRL ug/L 0.050 0.015 1 8081B 8/6/15 22:40 JMC P5G0466 alpha-BHC BRL ug/L 0.050 0.012 1 8081B 8/6/15 22:40 JMC P5G0466 cis -Chlordane BRL ug/L 0.050 0.018 1 8081B 8/6/15 22:40 JMC P5G0466 beta-BHC BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:40 JMC P5G0466 Chlordane BRL ug/L 0.50 0.34 1 8081B 8/6/15 22:40 JMC P5G0466 delta-BHC BRL ug/L 0.050 0.017 1 8081B 8/6/15 22:40 JMC P5G0466 Dieldrin BRL ug/L 0.050 0.022 1 8081B 8/6/15 22:40 JMC P5G0466 Endosulfan I BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:40 JMC P5G0466 Endosulfan II BRL ug/L 0.050 0.025 1 8081B 8/6/15 22:40 JMC P5G0466 Endosulfan Sulfate BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:40 JMC P5G0466 Endrin BRL ug/L 0.050 0.020 1 8081B 8/6/15 22:40 JMC P5G0466 Endrin Aldehyde BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:40 JMC P5G0466 Endrin Ketone BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:40 JMC P5G0466 gamma-BHC BRL ug/L 0.050 0.013 1 8081B 8/6/15 22:40 JMC P5G0466 trans -Chlordane BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:40 JMC P5G0466 Heptachlor BRL ug/L 0.050 0.015 1 8081B 8/6/15 22:40 JMC P5G0466 Heptachlor Epoxide BRL ug/L 0.050 0.018 1 8081B 8/6/15 22:40 JMC P5G0466 Methoxychlor BRL ug/L 0.050 0.033 1 8081B 8/6/15 22:40 JMC P5G0466 Toxaohene BRL ua/L 050 0.16 1 9081R R16115 22-40 IMC P5G0466 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 BRL ug/L Aroclor 1221 BRL ug/L Aroclor 1232 BRL ug/L Aroclor 1242 BRL ug/L Aroclor 1248 BRL ug/L Aroclor 1254 BRL ug/L Aroclor 1260 BRL ug/L Semivolatile Organic Compounds by GC/MS Surrogate Recovery Control Limits Decachlorobiphenyl 79 % 13-186 Tetrachloro-m-xylene 73 % 40-134 0.50 0.18 1 8082A 8/6/15 22:40 JMC P5G0467 1.0 0.11 1 8082A 8/6/15 22:40 JMC P5G0467 0.50 0.16 1 8082A 8/6/15 22:40 JMC P5G0467 0.50 0.14 1 8082A 8/6/15 22:40 JMC P5G0467 0.50 0.14 1 8082A 8/6/15 22:40 JMC P5G0467 0.50 0.16 1 8082A 8/6/15 22:40 JMC P5130467 0.50 0.18 1 8082A 8/6/15 22:40 JMC P5130467 Surrogate Recovery Control Limits Tetrachloro-m-xylene 73 % 30-161 Decachlorobiphenyl 81 % 32-178 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Attn: Jessica Hoglen Prism Sample ID: 5070434-02 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:50 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 1-Methyl naphthalene BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 8270D 7/24/15 17:23 JMV P5G0413 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 8270D 7/24/15 17:23 JMV P5G0413 2,4-Dichlorophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 2,4-Dimethyl phenol BRL ug/L 10 2.3 1 8270D 7/24/15 17:23 JMV P5G0413 2,4-Dinitrophenol BRL ug/L 10 3.7 1 8270D 7/24/15 17:23 JMV P5G0413 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 8270D 7/24/15 17:23 JMV P5G0413 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 2-Chloronaphthalene BRL ug/L 10 3.4 1 8270D 7/24/15 17:23 JMV P5G0413 2-Chlorophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 2-Methyl naphthalene BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 2-Methylphenol BRL ug/L 10 2.1 1 8270D 7/24/15 17:23 JMV P5G0413 2-Nitroaniline BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 2-Nitrophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 3/4-Methyl phenol BRL ug/L 10 1.9 1 8270D 7/24/15 17:23 JMV P5G0413 3-Nitroaniline BRL ug/L 10 1.2 1 8270D 7/24/15 17:23 JMV P5G0413 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 8270D 7/24/15 17:23 JMV P5G0413 4-Chloroaniline BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 4-Nitroaniline BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 4-Nitrophenol BRL ug/L 10 0.66 1 8270D 7/24/15 17:23 JMV P5G0413 Acenaphthene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 Acenaphthylene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 Aniline BRL ug/L 10 2.1 1 8270D 7/24/15 17:23 JMV P5G0413 Anthracene BRL ug/L 10 3.0 1 8270D 7/24/15 17:23 JMV P5G0413 Azobenzene BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 Benzo(a)anthracene BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 Benzo(a)pyrene BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 8270D 7/24/15 17:23 JMV P5G0413 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 Benzoic Acid BRL ug/L 100 2.7 1 8270D 7/24/15 17:23 JMV P5G0413 Benzyl alcohol BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 Butyl benzyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Attn: Jessica Hoglen Prism Sample ID: 5070434-02 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:50 Time Submitted: 07/22/15 10:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chrysene BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 Dibenzo(a,h)anth racene BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 Dibenzofuran BRL ug/L 10 2.3 1 8270D 7/24/15 17:23 JMV P5G0413 Diethyl phthalate BRL ug/L 10 1.9 1 8270D 7/24/15 17:23 JMV P5G0413 Dimethyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 Di-n-butyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:23 JMV P5G0413 Di-n-octyl phthalate BRL ug/L 10 1.7 1 8270D 7/24/15 17:23 JMV P5G0413 Fluoranthene BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 Fluorene BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 Hexachlorobenzene BRL ug/L 10 1.9 1 8270D 7/24/15 17:23 JMV P5G0413 Hexachlorobutadiene BRL ug/L 10 2.6 1 8270D 7/24/15 17:23 JMV P5G0413 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 Hexachloroethane BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 8270D 7/24/15 17:23 JMV P5G0413 Isophorone BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 Naphthalene BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 Nitrobenzene BRL ug/L 10 2.4 1 8270D 7/24/15 17:23 JMV P5G0413 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 Pentachlorophenol BRL ug/L 10 2.5 1 8270D 7/24/15 17:23 JMV P5G0413 Phenanthrene BRL ug/L 10 1.8 1 8270D 7/24/15 17:23 JMV P5G0413 Phenol BRL ug/L 10 1.2 1 8270D 7/24/15 17:23 JMV P5G0413 Pyrene BRL ug/L 10 2.2 1 8270D 7/24/15 17:23 JMV P5G0413 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 93 % 49-109 2-Fluorobiphenyl 88 % 55-96 2-Fluorophenol 57 % 27-74 Nitrobenzene-d5 83 % 53-99 Phenol-d5 40 % 11-52 Terphenyl-d14 105 % 42-133 Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/23/15 13:04 JAB P5G0417 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/30/15 17:37 BGM P5G0450 Barium 0.064 mg/L 0.010 0.00070 1 *6010C 7/30/15 17:37 BGM P5G0450 Boron BRL mg/L 0.50 0.0043 1 *6010C 7/30/15 17:37 BGM P5G0450 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/30/15 17:37 BGM P5G0450 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/30/15 17:37 BGM P5G0450 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/30/15 17:37 BGM P5G0450 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/31/15 16:56 BGM P5G0450 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/30/15 17:37 BGM P5G0450 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 8260B 7/28/15 15:56 MSC P5G0524 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 8260B 7/28/15 15:56 MSC P5G0524 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Attn: Jessica Hoglen Prism Sample ID: 5070434-02 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:50 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 8260B 7/28/15 15:56 MSC P5G0524 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 8260B 7/28/15 15:56 MSC P5G0524 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 8260B 7/28/15 15:56 MSC P5G0524 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 8260B 7/28/15 15:56 MSC P5G0524 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 8260B 7/28/15 15:56 MSC P5G0524 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 8260B 7/28/15 15:56 MSC P5G0524 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 8260B 7/28/15 15:56 MSC P5G0524 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 8260B 7/28/15 15:56 MSC P5G0524 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 8260B 7/28/15 15:56 MSC P5G0524 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 8260B 7/28/15 15:56 MSC P5G0524 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 8260B 7/28/15 15:56 MSC P5G0524 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:56 MSC P5G0524 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 8260B 7/28/15 15:56 MSC P5G0524 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 7/28/15 15:56 MSC P5G0524 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:56 MSC P5G0524 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 8260B 7/28/15 15:56 MSC P5G0524 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 8260B 7/28/15 15:56 MSC P5G0524 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 8260B 7/28/15 15:56 MSC P5G0524 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 7/28/15 15:56 MSC P5G0524 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 8260B 7/28/15 15:56 MSC P5G0524 2-Chlorotoluene BRL ug/L 0.50 0.066 1 8260B 7/28/15 15:56 MSC P5G0524 4-Chlorotoluene BRL ug/L 0.50 0.050 1 8260B 7/28/15 15:56 MSC P5G0524 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 8260B 7/28/15 15:56 MSC P5G0524 Acetone BRL ug/L 5.0 0.31 1 8260B 7/28/15 15:56 MSC P5G0524 Acrolein BRL ug/L 20 0.20 1 8260B 7/28/15 15:56 MSC P5G0524 Acrylonitrile BRL ug/L 20 0.20 1 8260B 7/28/15 15:56 MSC P5G0524 Benzene BRL ug/L 0.50 0.048 1 8260B 7/28/15 15:56 MSC P5G0524 Bromobenzene BRL ug/L 0.50 0.057 1 8260B 7/28/15 15:56 MSC P5G0524 Bromochloromethane BRL ug/L 0.50 0.14 1 8260B 7/28/15 15:56 MSC P5G0524 Bromodichloromethane BRL ug/L 0.50 0.062 1 8260B 7/28/15 15:56 MSC P5G0524 Bromoform BRL ug/L 1.0 0.040 1 8260B 7/28/15 15:56 MSC P5G0524 Bromomethane BRL ug/L 1.0 0.18 1 8260B 7/28/15 15:56 MSC P5G0524 Carbon disulfide BRL ug/L 5.0 0.075 1 8260B 7/28/15 15:56 MSC P5G0524 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 8260B 7/28/15 15:56 MSC P5G0524 Chlorobenzene BRL ug/L 0.50 0.062 1 8260B 7/28/15 15:56 MSC P5G0524 Chloroethane BRL ug/L 0.50 0.22 1 8260B 7/28/15 15:56 MSC P5G0524 Chloroform BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:56 MSC P5G0524 Chloromethane BRL ug/L 0.50 0.079 1 8260B 7/28/15 15:56 MSC P5G0524 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 8260B 7/28/15 15:56 MSC P5G0524 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 8260B 7/28/15 15:56 MSC P5G0524 Dibromochloromethane BRL ug/L 0.50 0.081 1 8260B 7/28/15 15:56 MSC P5G0524 Dibromomethane BRL ug/L 0.50 0.065 1 8260B 7/28/15 15:56 MSC P5G0524 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 8260B 7/28/15 15:56 MSC P5G0524 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Attn: Jessica Hoglen Prism Sample ID: 5070434-02 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 15:50 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Ethylbenzene BRL ug/L 0.50 0.061 1 8260B 7/28/15 15:56 MSC P5G0524 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 8260B 7/28/15 15:56 MSC P5G0524 Isopropyl Ether BRL ug/L 0.50 0.050 1 8260B 7/28/15 15:56 MSC P5G0524 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 8260B 7/28/15 15:56 MSC P5G0524 m,p-Xylenes BRL ug/L 1.0 0.12 1 8260B 7/28/15 15:56 MSC P5G0524 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 8260B 7/28/15 15:56 MSC P5G0524 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 8260B 7/28/15 15:56 MSC P5G0524 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 8260B 7/28/15 15:56 MSC P5G0524 Methylene Chloride BRL ug/L 1.0 0.083 1 8260B 7/28/15 15:56 MSC P5G0524 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 8260B 7/28/15 15:56 MSC P5G0524 Naphthalene BRL ug/L 1.0 0.19 1 8260B 7/28/15 15:56 MSC P5G0524 n-Butylbenzene BRL ug/L 1.0 0.076 1 8260B 7/28/15 15:56 MSC P5G0524 n-Propylbenzene BRL ug/L 0.50 0.087 1 8260B 7/28/15 15:56 MSC P5G0524 o-Xylene BRL ug/L 0.50 0.044 1 8260B 7/28/15 15:56 MSC P5G0524 sec-Butylbenzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 15:56 MSC P5G0524 Styrene BRL ug/L 0.50 0.047 1 8260B 7/28/15 15:56 MSC P5G0524 tert-Butylbenzene BRL ug/L 0.50 0.088 1 8260B 7/28/15 15:56 MSC P5G0524 Tetrachloroethylene BRL ug/L 0.50 0.098 1 8260B 7/28/15 15:56 MSC P5G0524 Toluene BRL ug/L 0.50 0.044 1 8260B 7/28/15 15:56 MSC P5G0524 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 8260B 7/28/15 15:56 MSC P5G0524 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 8260B 7/28/15 15:56 MSC P5G0524 Trichloroethylene BRL ug/L 0.50 0.078 1 8260B 7/28/15 15:56 MSC P5G0524 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 8260B 7/28/15 15:56 MSC P5G0524 Vinyl acetate BRL ug/L 2.0 0.060 1 8260B 7/28/15 15:56 MSC P5G0524 Vinyl chloride BRL ug/L 0.50 0.097 1 8260B 7/28/15 15:56 MSC P5G0524 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 99 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Project: 828 MLK - CHPD Sample Matrix: Water Client Sample ID: MW4A Filtered Prism Sample ID: 5070434-03 Prism Work Order: 5070434 Time Collected: 07/21/15 16:15 Time Submitted: 07/22/15 10:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hexavalent Chromium BRL mg/L 0.010 0.0037 1 *SM3500-Cr B 7/22/15 13:30 CDL P5G0401 Organochlorine Pesticides by GC/ECD 4,4'-DDD BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:51 JMC P5G0466 4,4'-DDE BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:51 JMC P5G0466 4,4'-DDT BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:51 JMC P5G0466 Aldrin BRL ug/L 0.050 0.015 1 8081B 8/6/15 22:51 JMC P5G0466 alpha-BHC BRL ug/L 0.050 0.012 1 8081B 8/6/15 22:51 JMC P5G0466 cis -Chlordane BRL ug/L 0.050 0.018 1 8081B 8/6/15 22:51 JMC P5G0466 beta-BHC BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:51 JMC P5G0466 Chlordane BRL ug/L 0.50 0.34 1 8081B 8/6/15 22:51 JMC P5G0466 delta-BHC BRL ug/L 0.050 0.017 1 8081B 8/6/15 22:51 JMC P5G0466 Dieldrin BRL ug/L 0.050 0.022 1 8081B 8/6/15 22:51 JMC P5G0466 Endosulfan I BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:51 JMC P5G0466 Endosulfan II BRL ug/L 0.050 0.025 1 8081B 8/6/15 22:51 JMC P5G0466 Endosulfan Sulfate BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:51 JMC P5G0466 Endrin BRL ug/L 0.050 0.020 1 8081B 8/6/15 22:51 JMC P5G0466 Endrin Aldehyde BRL ug/L 0.050 0.027 1 8081B 8/6/15 22:51 JMC P5G0466 Endrin Ketone BRL ug/L 0.050 0.028 1 8081B 8/6/15 22:51 JMC P5G0466 gamma-BHC BRL ug/L 0.050 0.013 1 8081B 8/6/15 22:51 JMC P5G0466 trans -Chlordane BRL ug/L 0.050 0.019 1 8081B 8/6/15 22:51 JMC P5G0466 Heptachlor BRL ug/L 0.050 0.015 1 8081B 8/6/15 22:51 JMC P5G0466 Heptachlor Epoxide BRL ug/L 0.050 0.018 1 8081B 8/6/15 22:51 JMC P5G0466 Methoxychlor BRL ug/L 0.050 0.033 1 8081B 8/6/15 22:51 JMC P5G0466 Toxaohene BRL ua/L 050 0.16 1 9081R R/6/15 22-51 IMC P5G0466 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 BRL ug/L Aroclor 1221 BRL ug/L Aroclor 1232 BRL ug/L Aroclor 1242 BRL ug/L Aroclor 1248 BRL ug/L Aroclor 1254 BRL ug/L Aroclor 1260 BRL ug/L Semivolatile Organic Compounds by GC/MS Surrogate Recovery Control Limits Decachlorobiphenyl 74 % 13-186 Tetrachloro-m-xylene 71 % 40-134 0.50 0.18 1 8082A 8/6/15 22:51 JMC P5G0467 1.0 0.11 1 8082A 8/6/15 22:51 JMC P5G0467 0.50 0.16 1 8082A 8/6/15 22:51 JMC P5G0467 0.50 0.14 1 8082A 8/6/15 22:51 JMC P5G0467 0.50 0.14 1 8082A 8/6/15 22:51 JMC P5G0467 0.50 0.16 1 8082A 8/6/15 22:51 JMC P5G0467 0.50 0.18 1 8082A 8/6/15 22:51 JMC P5130467 Surrogate Recovery Control Limits Tetrachloro-m-xylene 70 % 30-161 Decachlorobiphenyl 75 % 32-178 1,2,4-Trichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 1,2-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Filtered Attn: Jessica Hoglen Prism Sample ID: 5070434-03 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 16:15 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID 1,3-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 1,4-Dichlorobenzene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 1-Methyl naphthalene BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 2,4,5-Trichlorophenol BRL ug/L 10 2.3 1 8270D 7/24/15 17:44 JMV P5G0413 2,4,6-Trichlorophenol BRL ug/L 10 2.6 1 8270D 7/24/15 17:44 JMV P5G0413 2,4-Dichlorophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 2,4-Dimethyl phenol BRL ug/L 10 2.3 1 8270D 7/24/15 17:44 JMV P5G0413 2,4-Dinitrophenol BRL ug/L 10 3.7 1 8270D 7/24/15 17:44 JMV P5G0413 2,4-Dinitrotoluene BRL ug/L 10 1.9 1 8270D 7/24/15 17:44 JMV P5G0413 2,6-Dinitrotoluene BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 2-Chloronaphthalene BRL ug/L 10 3.4 1 8270D 7/24/15 17:44 JMV P5G0413 2-Chlorophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 2-Methyl naphthalene BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 2-Methylphenol BRL ug/L 10 2.1 1 8270D 7/24/15 17:44 JMV P5G0413 2-Nitroaniline BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 2-Nitrophenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 3,3'-Dichlorobenzidine BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 3/4-Methyl phenol BRL ug/L 10 1.9 1 8270D 7/24/15 17:44 JMV P5G0413 3-Nitroaniline BRL ug/L 10 1.2 1 8270D 7/24/15 17:44 JMV P5G0413 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 4-Chloro-3-methylphenol BRL ug/L 10 1.9 1 8270D 7/24/15 17:44 JMV P5G0413 4-Chloroaniline BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 4-Chlorophenyl phenyl ether BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 4-Nitroaniline BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 4-Nitrophenol BRL ug/L 10 0.66 1 8270D 7/24/15 17:44 JMV P5G0413 Acenaphthene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 Acenaphthylene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 Aniline BRL ug/L 10 2.1 1 8270D 7/24/15 17:44 JMV P5G0413 Anthracene BRL ug/L 10 3.0 1 8270D 7/24/15 17:44 JMV P5G0413 Azobenzene BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 Benzo(a)anthracene BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 Benzo(a)pyrene BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 8270D 7/24/15 17:44 JMV P5G0413 Benzo(g,h,i)perylene BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 Benzo(k)fluoranthene BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 Benzoic Acid BRL ug/L 100 2.7 1 8270D 7/24/15 17:44 JMV P5G0413 Benzyl alcohol BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 Bis(2-Chloroethyl)ether BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 Bis(2-chloroisopropyl)ether BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 Butyl benzyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Filtered Attn: Jessica Hoglen Prism Sample ID: 5070434-03 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 16:15 Time Submitted: 07/22/15 10:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chrysene BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 Dibenzo(a,h)anth racene BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 Dibenzofuran BRL ug/L 10 2.3 1 8270D 7/24/15 17:44 JMV P5G0413 Diethyl phthalate BRL ug/L 10 1.9 1 8270D 7/24/15 17:44 JMV P5G0413 Dimethyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 Di-n-butyl phthalate BRL ug/L 10 2.0 1 8270D 7/24/15 17:44 JMV P5G0413 Di-n-octyl phthalate BRL ug/L 10 1.7 1 8270D 7/24/15 17:44 JMV P5G0413 Fluoranthene BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 Fluorene BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 Hexachlorobenzene BRL ug/L 10 1.9 1 8270D 7/24/15 17:44 JMV P5G0413 Hexachlorobutadiene BRL ug/L 10 2.6 1 8270D 7/24/15 17:44 JMV P5G0413 Hexachlorocyclopentadiene BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 Hexachloroethane BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 Indeno(1,2,3-cd)pyrene BRL ug/L 10 2.1 1 8270D 7/24/15 17:44 JMV P5G0413 Isophorone BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 Naphthalene BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 Nitrobenzene BRL ug/L 10 2.4 1 8270D 7/24/15 17:44 JMV P5G0413 N-Nitroso-di-n-propylamine BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 N-Nitrosodiphenylamine BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 Pentachlorophenol BRL ug/L 10 2.5 1 8270D 7/24/15 17:44 JMV P5G0413 Phenanthrene BRL ug/L 10 1.8 1 8270D 7/24/15 17:44 JMV P5G0413 Phenol BRL ug/L 10 1.2 1 8270D 7/24/15 17:44 JMV P5G0413 Pyrene BRL ug/L 10 2.2 1 8270D 7/24/15 17:44 JMV P5G0413 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 84 % 49-109 2-Fluorobiphenyl 76 % 55-96 2-Fluorophenol 45 % 27-74 Nitrobenzene-d5 69 % 53-99 Phenol-d5 29 % 11-52 Terphenyl-d14 93 % 42-133 Total Metals Mercury BRL mg/L 0.00020 0.000011 1 *7470A 7/23/15 13:08 JAB P5G0417 Arsenic BRL mg/L 0.010 0.00070 1 *6010C 7/30/15 17:44 BGM P5G0450 Barium 0.061 mg/L 0.010 0.00070 1 *6010C 7/30/15 17:44 BGM P5G0450 Boron BRL mg/L 0.50 0.0043 1 *6010C 7/30/15 17:44 BGM P5G0450 Cadmium BRL mg/L 0.0010 0.00010 1 *6010C 7/30/15 17:44 BGM P5G0450 Chromium BRL mg/L 0.0050 0.00060 1 *6010C 7/30/15 17:44 BGM P5G0450 Lead BRL mg/L 0.0050 0.0013 1 *6010C 7/30/15 17:44 BGM P5G0450 Selenium BRL mg/L 0.020 0.0032 1 *6010C 7/31/15 17:04 BGM P5G0450 Silver BRL mg/L 0.0050 0.00020 1 *6010C 7/30/15 17:44 BGM P5G0450 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.11 1 8260B 7/28/15 16:23 MSC P5G0524 1,1,1-Trichloroethane BRL ug/L 0.50 0.061 1 8260B 7/28/15 16:23 MSC P5G0524 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Filtered Attn: Jessica Hoglen Prism Sample ID: 5070434-03 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 16:15 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.036 1 8260B 7/28/15 16:23 MSC P5G0524 1,1,2-Trichloroethane BRL ug/L 0.50 0.066 1 8260B 7/28/15 16:23 MSC P5G0524 1,1-Dichloroethane BRL ug/L 0.50 0.083 1 8260B 7/28/15 16:23 MSC P5G0524 1,1-Dichloroethylene BRL ug/L 0.50 0.083 1 8260B 7/28/15 16:23 MSC P5G0524 1,1-Dichloropropylene BRL ug/L 0.50 0.051 1 8260B 7/28/15 16:23 MSC P5G0524 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.40 1 8260B 7/28/15 16:23 MSC P5G0524 1,2,3-Trichloropropane BRL ug/L 1.0 0.14 1 8260B 7/28/15 16:23 MSC P5G0524 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.13 1 8260B 7/28/15 16:23 MSC P5G0524 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.054 1 8260B 7/28/15 16:23 MSC P5G0524 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.17 1 8260B 7/28/15 16:23 MSC P5G0524 1,2-Dibromoethane BRL ug/L 0.50 0.051 1 8260B 7/28/15 16:23 MSC P5G0524 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 16:23 MSC P5G0524 1,2-Dichloroethane BRL ug/L 0.50 0.066 1 8260B 7/28/15 16:23 MSC P5G0524 1,2-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 7/28/15 16:23 MSC P5G0524 1,3,5-Trimethyl benzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 16:23 MSC P5G0524 1,3-Dichlorobenzene BRL ug/L 0.50 0.054 1 8260B 7/28/15 16:23 MSC P5G0524 1,3-Dichloropropane BRL ug/L 0.50 0.043 1 8260B 7/28/15 16:23 MSC P5G0524 1,4-Dichlorobenzene BRL ug/L 0.50 0.050 1 8260B 7/28/15 16:23 MSC P5G0524 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 7/28/15 16:23 MSC P5G0524 2-Chloroethyl Vinyl Ether BRL ug/L 5.0 0.37 1 8260B 7/28/15 16:23 MSC P5G0524 2-Chlorotoluene BRL ug/L 0.50 0.066 1 8260B 7/28/15 16:23 MSC P5G0524 4-Chlorotoluene BRL ug/L 0.50 0.050 1 8260B 7/28/15 16:23 MSC P5G0524 4-Isopropyltoluene BRL ug/L 0.50 0.089 1 8260B 7/28/15 16:23 MSC P5G0524 Acetone BRL ug/L 5.0 0.31 1 8260B 7/28/15 16:23 MSC P5G0524 Acrolein BRL ug/L 20 0.20 1 8260B 7/28/15 16:23 MSC P5G0524 Acrylonitrile BRL ug/L 20 0.20 1 8260B 7/28/15 16:23 MSC P5G0524 Benzene BRL ug/L 0.50 0.048 1 8260B 7/28/15 16:23 MSC P5G0524 Bromobenzene BRL ug/L 0.50 0.057 1 8260B 7/28/15 16:23 MSC P5G0524 Bromochloromethane BRL ug/L 0.50 0.14 1 8260B 7/28/15 16:23 MSC P5G0524 Bromodichloromethane BRL ug/L 0.50 0.062 1 8260B 7/28/15 16:23 MSC P5G0524 Bromoform BRL ug/L 1.0 0.040 1 8260B 7/28/15 16:23 MSC P5G0524 Bromomethane BRL ug/L 1.0 0.18 1 8260B 7/28/15 16:23 MSC P5G0524 Carbon disulfide BRL ug/L 5.0 0.075 1 8260B 7/28/15 16:23 MSC P5G0524 Carbon Tetrachloride BRL ug/L 0.50 0.11 1 8260B 7/28/15 16:23 MSC P5G0524 Chlorobenzene BRL ug/L 0.50 0.062 1 8260B 7/28/15 16:23 MSC P5G0524 Chloroethane BRL ug/L 0.50 0.22 1 8260B 7/28/15 16:23 MSC P5G0524 Chloroform BRL ug/L 0.50 0.076 1 8260B 7/28/15 16:23 MSC P5G0524 Chloromethane BRL ug/L 0.50 0.079 1 8260B 7/28/15 16:23 MSC P5G0524 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.056 1 8260B 7/28/15 16:23 MSC P5G0524 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.079 1 8260B 7/28/15 16:23 MSC P5G0524 Dibromochloromethane BRL ug/L 0.50 0.081 1 8260B 7/28/15 16:23 MSC P5G0524 Dibromomethane BRL ug/L 0.50 0.065 1 8260B 7/28/15 16:23 MSC P5G0524 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 8260B 7/28/15 16:23 MSC P5G0524 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 38 P R I S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/10/2015 LA6pAATOA Falcon Engineering Project: 828 MLK - CHPD Client Sample ID: MW4A Filtered Attn: Jessica Hoglen Prism Sample ID: 5070434-03 1210 Trinity Road #110 Prism Work Order: 5070434 Raleigh, NC 27607 Sample Matrix: Water Time Collected: 07/21/15 16:15 Time Submitted: 07/22/15 10:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Ethylbenzene BRL ug/L 0.50 0.061 1 8260B 7/28/15 16:23 MSC P5G0524 Hexachlorobutadiene BRL ug/L 2.0 0.16 1 8260B 7/28/15 16:23 MSC P5G0524 Isopropyl Ether BRL ug/L 0.50 0.050 1 8260B 7/28/15 16:23 MSC P5G0524 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.054 1 8260B 7/28/15 16:23 MSC P5G0524 m,p-Xylenes BRL ug/L 1.0 0.12 1 8260B 7/28/15 16:23 MSC P5G0524 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.065 1 8260B 7/28/15 16:23 MSC P5G0524 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.24 1 8260B 7/28/15 16:23 MSC P5G0524 Methyl Isobutyl Ketone BRL ug/L 5.0 0.078 1 8260B 7/28/15 16:23 MSC P5G0524 Methylene Chloride BRL ug/L 1.0 0.083 1 8260B 7/28/15 16:23 MSC P5G0524 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.042 1 8260B 7/28/15 16:23 MSC P5G0524 Naphthalene BRL ug/L 1.0 0.19 1 8260B 7/28/15 16:23 MSC P5G0524 n-Butylbenzene BRL ug/L 1.0 0.076 1 8260B 7/28/15 16:23 MSC P5G0524 n-Propylbenzene BRL ug/L 0.50 0.087 1 8260B 7/28/15 16:23 MSC P5G0524 o-Xylene BRL ug/L 0.50 0.044 1 8260B 7/28/15 16:23 MSC P5G0524 sec-Butylbenzene BRL ug/L 0.50 0.076 1 8260B 7/28/15 16:23 MSC P5G0524 Styrene BRL ug/L 0.50 0.047 1 8260B 7/28/15 16:23 MSC P5G0524 tert-Butylbenzene BRL ug/L 0.50 0.088 1 8260B 7/28/15 16:23 MSC P5G0524 Tetrachloroethylene BRL ug/L 0.50 0.098 1 8260B 7/28/15 16:23 MSC P5G0524 Toluene BRL ug/L 0.50 0.044 1 8260B 7/28/15 16:23 MSC P5G0524 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.094 1 8260B 7/28/15 16:23 MSC P5G0524 trans-1,3-Dichloropropylene BRL ug/L 0.50 0.070 1 8260B 7/28/15 16:23 MSC P5G0524 Trichloroethylene BRL ug/L 0.50 0.078 1 8260B 7/28/15 16:23 MSC P5G0524 Trichlorofluoromethane BRL ug/L 0.50 0.062 1 8260B 7/28/15 16:23 MSC P5G0524 Vinyl acetate BRL ug/L 2.0 0.060 1 8260B 7/28/15 16:23 MSC P5G0524 Vinyl chloride BRL ug/L 0.50 0.097 1 8260B 7/28/15 16:23 MSC P5G0524 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 99 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 38 P R I S M FullAnalytical Environmental tal Solutions LA6-QRIES INC. Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:00AM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5G0524 - 5030B Blank (P5G0524-BLK1) Prepared & Analyzed: 07/28/15 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethyl benzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethyl benzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 5.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 8/10/15 Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO524 - 5030B Blank (P5G0524-BLK1) Prepared & Analyzed: 07/28/15 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 48.6 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.2 ug/L 50.00 98 75-129 Surrogate: Toluene-d8 48.1 ug/L 50.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 38 _�, P R 1 S M Full -Service Analytical Environmental Solutions -, uaP�.�ONiES, �NF Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Prism Work Order: 5070434 Attn: Jessica Hoglen Time Submitted: 7/22/2015 10:40:OOAM 1210 Trinity Road #110 Raleigh, NC 27607 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO524 - 5030B LCS (P5G0524-BSI) Prepared & Analyzed: 07/28/15 1,1,1,2-Tetrachloroethane 20.3 0.50 ug/L 20.00 102 79-134 1,1,1-Trichloroethane 19.7 0.50 ug/L 20.00 99 75-136 1,1,2,2-Tetrachloroethane 22.5 0.50 ug/L 20.00 112 62-127 1,1,2-Trichloroethane 20.1 0.50 ug/L 20.00 101 70-140 1,1-Dichloroethane 19.7 0.50 ug/L 20.00 98 78-130 1,1-Dichloroethylene 19.9 0.50 ug/L 20.00 100 70-154 1, 1 -Dichloropropylene 20.3 0.50 ug/L 20.00 102 71-136 1,2,3-Trichlorobenzene 17.9 2.0 ug/L 20.00 90 58-144 1,2,3-Trichloropropane 21.7 1.0 ug/L 20.00 109 71-127 1,2,4-Trichlorobenzene 22.0 1.0 ug/L 20.00 110 66-139 1,2,4-Trimethylbenzene 21.0 0.50 ug/L 20.00 105 75-133 1,2-Dibromo-3-chloropropane 20.8 2.0 ug/L 20.00 104 63-134 1,2-Dibromoethane 20.7 0.50 ug/L 20.00 104 77-135 1,2-Dichlorobenzene 21.2 0.50 ug/L 20.00 106 78-128 1,2-Dichloroethane 20.1 0.50 ug/L 20.00 100 68-131 1,2-Dichloropropane 20.9 0.50 ug/L 20.00 105 77-130 1,3,5-Trimethylbenzene 21.3 0.50 ug/L 20.00 106 75-131 1,3-Dichlorobenzene 21.3 0.50 ug/L 20.00 107 77-125 1,3-Dichloropropane 21.2 0.50 ug/L 20.00 106 76-132 1,4-Dichlorobenzene 20.7 0.50 ug/L 20.00 103 75-126 2,2-Dichloropropane 23.5 2.0 ug/L 20.00 118 29-149 2-Chloroethyl Vinyl Ether 18.6 5.0 ug/L 20.00 93 34-144 2-Chlorotoluene 21.0 0.50 ug/L 20.00 105 74-126 4-Chlorotoluene 21.3 0.50 ug/L 20.00 106 78-129 4-Isopropyltoluene 21.4 0.50 ug/L 20.00 107 69-132 Acetone 41.2 5.0 ug/L 40.00 103 40-166 Acrolein 39.3 20 ug/L 40.00 98 70-130 Acrylonitrile 40.1 20 ug/L 40.00 100 81-127 Benzene 21.3 0.50 ug/L 20.00 107 77-128 Bromobenzene 20.2 0.50 ug/L 20.00 101 78-129 Bromochloromethane 21.5 0.50 ug/L 20.00 108 78-135 Bromodichloromethane 19.3 0.50 ug/L 20.00 96 76-138 Bromoform 19.0 1.0 ug/L 20.00 95 71-135 Bromomethane 22.2 1.0 ug/L 20.00 111 41-168 Carbon disulfide 23.9 5.0 ug/L 20.00 120 59-135 Carbon Tetrachloride 21.5 0.50 ug/L 20.00 108 72-142 Chlorobenzene 20.9 0.50 ug/L 20.00 104 78-119 Chloroethane 21.6 0.50 ug/L 20.00 108 57-142 Chloroform 18.5 0.50 ug/L 20.00 92 77-130 Chloromethane 20.1 0.50 ug/L 20.00 100 47-145 cis-1,2-Dichloroethylene 20.1 0.50 ug/L 20.00 100 76-141 cis-1,3-Dichloropropylene 21.5 0.50 ug/L 20.00 108 65-140 Dibromochloromethane 19.9 0.50 ug/L 20.00 99 75-134 Dibromomethane 21.7 0.50 ug/L 20.00 108 76-138 Dichlorodifluoromethane 20.9 1.0 ug/L 20.00 105 28-163 Ethylbenzene 21.0 0.50 ug/L 20.00 105 80-127 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO524 - 5030B LCS (P5G0524-BS1) Prepared & Analyzed: 07/28/15 Hexachlorobutadiene 22.5 2.0 ug/L 20.00 113 61-134 Isopropyl Ether 19.0 0.50 ug/L 20.00 95 60-154 Isopropylbenzene (Cumene) 22.9 0.50 ug/L 20.00 114 70-130 m,p-Xylenes 41.4 1.0 ug/L 40.00 103 77-133 Methyl Butyl Ketone (2-Hexanone) 21.2 5.0 ug/L 20.00 106 64-137 Methyl Ethyl Ketone (2-Butanone) 18.8 5.0 ug/L 20.00 94 71-134 Methyl Isobutyl Ketone 20.1 5.0 ug/L 20.00 100 69-134 Methylene Chloride 19.5 1.0 ug/L 20.00 98 73-131 Methyl-tert-Butyl Ether 20.0 0.50 ug/L 20.00 100 68-135 Naphthalene 21.7 1.0 ug/L 20.00 108 64-136 n-Butylbenzene 22.0 1.0 ug/L 20.00 110 68-134 n-Propylbenzene 21.9 0.50 ug/L 20.00 109 72-132 o-Xylene 20.7 0.50 ug/L 20.00 104 78-128 sec-Butylbenzene 22.4 0.50 ug/L 20.00 112 71-131 Styrene 21.0 0.50 ug/L 20.00 105 78-129 tert-Butylbenzene 21.2 0.50 ug/L 20.00 106 70-132 Tetrachloroethylene 20.8 0.50 ug/L 20.00 104 80-129 Toluene 20.7 0.50 ug/L 20.00 103 76-131 trans-1,2-Dichloroethylene 20.4 0.50 ug/L 20.00 102 76-135 trans-1,3-Dichloropropylene 21.7 0.50 ug/L 20.00 108 67-140 Trichloroethylene 19.8 0.50 ug/L 20.00 99 77-133 Trichlorofluoromethane 23.2 0.50 ug/L 20.00 116 62-148 Vinyl acetate 21.0 2.0 ug/L 20.00 105 34-167 Vinyl chloride 22.4 0.50 ug/L 20.00 112 57-141 Surrogate:4-Bromofluorobenzene 49.8 ug/L 50.00 100 80-124 Surrogate: Dibromofluoromethane 49.2 ug/L 50.00 98 75-129 Surrogate: Toluene-d8 50.3 ug/L 50.00 101 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 38 _�, P R 1 S M Full -Service Analytical Environmental Solutions -, uaP�.�ONiES, �NF Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Prism Work Order: 5070434 Attn: Jessica Hoglen Time Submitted: 7/22/2015 10:40:OOAM 1210 Trinity Road #110 Raleigh, NC 27607 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO524 - 5030B LCS Dup (P5G0524-BSD1) Prepared & Analyzed: 07/28/15 1,1,1,2-Tetrachloroethane 20.1 0.50 ug/L 20.00 101 79-134 1 20 1,1,1-Trichloroethane 18.8 0.50 ug/L 20.00 94 75-136 5 20 1,1,2,2-Tetrachloroethane 22.6 0.50 ug/L 20.00 113 62-127 0.4 20 1,1,2-Trichloroethane 19.9 0.50 ug/L 20.00 100 70-140 0.9 20 1,1-Dichloroethane 18.9 0.50 ug/L 20.00 94 78-130 4 20 1,1-Dichloroethylene 18.8 0.50 ug/L 20.00 94 70-154 6 20 1, 1 -Dichloropropylene 19.6 0.50 ug/L 20.00 98 71-136 4 20 1,2,3-Trichlorobenzene 16.5 2.0 ug/L 20.00 82 58-144 9 20 1,2,3-Trichloropropane 21.2 1.0 ug/L 20.00 106 71-127 2 20 1,2,4-Trichlorobenzene 22.2 1.0 ug/L 20.00 111 66-139 0.8 20 1,2,4-Trimethylbenzene 20.5 0.50 ug/L 20.00 102 75-133 3 20 1,2-Dibromo-3-chloropropane 21.2 2.0 ug/L 20.00 106 63-134 2 20 1,2-Dibromoethane 20.7 0.50 ug/L 20.00 104 77-135 0.05 20 1,2-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 78-128 2 20 1,2-Dichloroethane 19.6 0.50 ug/L 20.00 98 68-131 2 20 1,2-Dichloropropane 20.3 0.50 ug/L 20.00 102 77-130 3 20 1,3,5-Trimethylbenzene 20.9 0.50 ug/L 20.00 104 75-131 2 20 1,3-Dichlorobenzene 20.7 0.50 ug/L 20.00 104 77-125 3 20 1,3-Dichloropropane 21.0 0.50 ug/L 20.00 105 76-132 0.9 20 1,4-Dichlorobenzene 20.9 0.50 ug/L 20.00 104 75-126 1 20 2,2-Dichloropropane 22.5 2.0 ug/L 20.00 112 29-149 4 20 2-Chloroethyl Vinyl Ether 17.9 5.0 ug/L 20.00 89 34-144 4 20 2-Chlorotoluene 20.6 0.50 ug/L 20.00 103 74-126 2 20 4-Chlorotoluene 20.7 0.50 ug/L 20.00 104 78-129 3 20 4-Isopropyltoluene 20.7 0.50 ug/L 20.00 103 69-132 4 20 Acetone 41.7 5.0 ug/L 40.00 104 40-166 1 20 Acrolein 43.9 20 ug/L 40.00 110 70-130 11 20 Acrylonitrile 40.3 20 ug/L 40.00 101 81-127 0.6 20 Benzene 20.3 0.50 ug/L 20.00 102 77-128 5 20 Bromobenzene 19.9 0.50 ug/L 20.00 99 78-129 2 20 Bromochloromethane 20.8 0.50 ug/L 20.00 104 78-135 3 20 Bromodichloromethane 18.4 0.50 ug/L 20.00 92 76-138 5 20 Bromoform 19.4 1.0 ug/L 20.00 97 71-135 2 20 Bromomethane 21.2 1.0 ug/L 20.00 106 41-168 5 20 Carbon disulfide 22.8 5.0 ug/L 20.00 114 59-135 5 20 Carbon Tetrachloride 20.9 0.50 ug/L 20.00 105 72-142 3 20 Chlorobenzene 20.5 0.50 ug/L 20.00 103 78-119 2 20 Chloroethane 20.2 0.50 ug/L 20.00 101 57-142 7 20 Chloroform 18.2 0.50 ug/L 20.00 91 77-130 1 20 Chloromethane 18.9 0.50 ug/L 20.00 95 47-145 6 20 cis-1,2-Dichloroethylene 19.5 0.50 ug/L 20.00 97 76-141 3 20 cis-1,3-Dichloropropylene 20.9 0.50 ug/L 20.00 104 65-140 3 20 Dibromochloromethane 19.2 0.50 ug/L 20.00 96 75-134 4 20 Dibromomethane 21.6 0.50 ug/L 20.00 108 76-138 0.4 20 Dichlorodifluoromethane 19.6 1.0 ug/L 20.00 98 28-163 6 20 Ethylbenzene 20.2 0.50 ug/L 20.00 101 80-127 4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO524 - 5030B LCS Dup (P5G0524-BSD1) Prepared & Analyzed: 07/28/15 Hexachlorobutadiene 20.9 2.0 ug/L 20.00 105 61-134 7 20 Isopropyl Ether 18.8 0.50 ug/L 20.00 94 60-154 1 20 Isopropylbenzene (Cumene) 22.4 0.50 ug/L 20.00 112 70-130 2 20 m,p-Xylenes 40.0 1.0 ug/L 40.00 100 77-133 3 20 Methyl Butyl Ketone (2-Hexanone) 21.0 5.0 ug/L 20.00 105 64-137 1 20 Methyl Ethyl Ketone (2-Butanone) 19.9 5.0 ug/L 20.00 99 71-134 5 20 Methyl Isobutyl Ketone 19.5 5.0 ug/L 20.00 98 69-134 3 20 Methylene Chloride 18.8 1.0 ug/L 20.00 94 73-131 4 20 Methyl-tert-Butyl Ether 19.6 0.50 ug/L 20.00 98 68-135 2 20 Naphthalene 21.7 1.0 ug/L 20.00 108 64-136 0.05 20 n-Butylbenzene 21.1 1.0 ug/L 20.00 106 68-134 4 20 n-Propylbenzene 21.3 0.50 ug/L 20.00 106 72-132 3 20 o-Xylene 20.0 0.50 ug/L 20.00 100 78-128 3 20 sec-Butylbenzene 22.1 0.50 ug/L 20.00 ill 71-131 1 20 Styrene 20.5 0.50 ug/L 20.00 103 78-129 2 20 tert-Butylbenzene 20.8 0.50 ug/L 20.00 104 70-132 2 20 Tetrachloroethylene 19.8 0.50 ug/L 20.00 99 80-129 5 20 Toluene 20.0 0.50 ug/L 20.00 100 76-131 3 20 trans-1,2-Dichloroethylene 19.4 0.50 ug/L 20.00 97 76-135 5 20 trans-1,3-Dichloropropylene 21.3 0.50 ug/L 20.00 106 67-140 2 20 Trichloroethylene 18.6 0.50 ug/L 20.00 93 77-133 6 20 Trichlorofluoromethane 22.1 0.50 ug/L 20.00 110 62-148 5 20 Vinyl acetate 20.7 2.0 ug/L 20.00 103 34-167 1 20 Vinyl chloride 20.8 0.50 ug/L 20.00 104 57-141 8 20 Surrogate:4-Bromofluorobenzene 49.7 ug/L 50.00 99 80-124 Surrogate: Dibromofluoromethane 48.8 ug/L 50.00 98 75-129 Surrogate: Toluene-d8 49.7 ug/L 50.00 99 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Analyte Result Limit Units Batch P5GO413 - 351 OC MS Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0413-BLK1) Prepared: 07/23/15 Analyzed: 07/24/15 1,2,4-Trichlorobenzene BRL 10 ug/L 1,2-Dichlorobenzene BRL 10 ug/L 1,3-Dichlorobenzene BRL 10 ug/L 1,4-Dichlorobenzene BRL 10 ug/L 1-Methyl naphthalene BRL 10 ug/L 2,4,5-Trichlorophenol BRL 10 ug/L 2,4,6-Trichlorophenol BRL 10 ug/L 2,4-Dichlorophenol BRL 10 ug/L 2,4-Dimethylphenol BRL 10 ug/L 2,4-Dinitrophenol BRL 10 ug/L 2,4-Dinitrotoluene BRL 10 ug/L 2,6-Dinitrotoluene BRL 10 ug/L 2-Chloronaphthalene BRL 10 ug/L 2-Chlorophenol BRL 10 ug/L 2-Methyl naphthalene BRL 10 ug/L 2-Methylphenol BRL 10 ug/L 2-Nitroaniline BRL 10 ug/L 2-Nitrophenol BRL 10 ug/L 3,3'-Dichlorobenzidine BRL 10 ug/L 3/4-Methyl phenol BRL 10 ug/L 3-Nitroaniline BRL 10 ug/L 4,6-Dinitro-2-methylphenol BRL 10 ug/L 4-Bromophenyl phenyl ether BRL 10 ug/L 4-Chloro-3-methylphenol BRL 10 ug/L 4-Chloroaniline BRL 10 ug/L 4-Chlorophenyl phenyl ether BRL 10 ug/L 4-Nitroaniline BRL 10 ug/L 4-Nitrophenol BRL 10 ug/L Acenaphthene BRL 10 ug/L Acenaphthylene BRL 10 ug/L Aniline BRL 10 ug/L Anthracene BRL 10 ug/L Azobenzene BRL 10 ug/L Benzo(a)anthracene BRL 10 ug/L Benzo(a)pyrene BRL 10 ug/L Benzo(b)fluoranthene BRL 10 ug/L Benzo(g,h,i)perylene BRL 10 ug/L Benzo(k)fluoranthene BRL 10 ug/L Benzoic Acid BRL 100 ug/L Benzyl alcohol BRL 10 ug/L bis(2-Chloroethoxy)methane BRL 10 ug/L Bis(2-Chloroethyl)ether BRL 10 ug/L Bis(2-chloroisopropyl)ether BRL 10 ug/L Bis(2-Ethylhexyl)phthalate BRL 10 ug/L Butyl benzyl phthalate BRL 10 ug/L Chrysene BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Analyte Result Limit Units Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Batch P5GO413 - 351 OC MS Blank (P5G0413-BLK1) Prepared: 07/23/15 Analyzed: 07/24/15 Dibenzo(a,h)anthracene BRL 10 ug/L Dibenzofuran BRL 10 ug/L Diethyl phthalate BRL 10 ug/L Dimethyl phthalate BRL 10 ug/L Di-n-butyl phthalate BRL 10 ug/L Di-n-octyl phthalate BRL 10 ug/L Fluoranthene BRL 10 ug/L Fluorene BRL 10 ug/L Hexachlorobenzene BRL 10 ug/L Hexachlorobutadiene BRL 10 ug/L Hexachlorocyclopentadiene BRL 10 ug/L Hexachloroethane BRL 10 ug/L Indeno(1,2,3-cd)pyrene BRL 10 ug/L Isophorone BRL 10 ug/L Naphthalene BRL 10 ug/L Nitrobenzene BRL 10 ug/L N-Nitroso-di-n-propylamine BRL 10 ug/L N-Nitrosodiphenylamine BRL 10 ug/L Pentachlorophenol BRL 10 ug/L Phenanthrene BRL 10 ug/L Phenol BRL 10 ug/L Pyrene BRL 10 ug/L Surrogate: 2,4,6-Tribromophenol 120 ug/L 100.0 120 49-109 SR Surrogate:2-Fluorobiphenyl 55.3 ug/L 50.00 111 55-96 SR Surrogate:2-Fluorophenol 71.4 ug/L 100.0 71 27-74 Surrogate: Nitrobenzene-d5 51.0 ug/L 50.00 102 53-99 SR Surrogate: Phenol-d5 45.6 ug/L 100.0 46 11-52 Surrogate: Terphenyl-d14 62.0 ug/L 50.00 124 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Prism Work Order: 5070434 Attn: Jessica Hoglen Time Submitted: 7/22/2015 10:40:OOAM 1210 Trinity Road #110 Raleigh, NC 27607 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO413 - 351 OC MS LCS (P5G0413-BS1) Prepared: 07/23/15 Analyzed: 07/24/15 1,2,4-Trichlorobenzene 37.9 10 ug/L 50.00 76 45-103 1,2-Dichlorobenzene 37.6 10 ug/L 50.00 75 43-100 1,3-Dichlorobenzene 36.8 10 ug/L 50.00 74 42-98 1,4-Dichlorobenzene 36.9 10 ug/L 50.00 74 42-100 1-Methyl naphthalene 39.0 10 ug/L 50.00 78 45-135 2,4,5-Trichlorophenol 47.4 10 ug/L 50.00 95 66-120 2,4,6-Trichlorophenol 45.8 10 ug/L 50.00 92 62-121 2,4-Dichlorophenol 40.3 10 ug/L 50.00 81 58-113 2,4-Dimethylphenol 40.1 10 ug/L 50.00 80 42-120 2,4-Dinitrophenol 24.6 10 ug/L 50.00 49 27-129 2,4-Dinitrotoluene 49.9 10 ug/L 50.00 100 62-136 2,6-Dinitrotoluene 49.5 10 ug/L 50.00 99 64-129 2-Chloronaphthalene 51.5 10 ug/L 50.00 103 38-141 2-Chlorophenol 37.4 10 ug/L 50.00 75 49-107 2-Methyl naphthalene 38.5 10 ug/L 50.00 77 55-112 2-Methylphenol 35.6 10 ug/L 50.00 71 40-106 2-Nitroaniline 46.6 10 ug/L 50.00 93 65-122 2-Nitrophenol 40.3 10 ug/L 50.00 81 57-115 3,3'-Dichlorobenzidine 51.6 10 ug/L 50.00 103 58-139 3/4-Methyl phenol 33.6 10 ug/L 50.00 67 34-101 3-Nitroaniline 47.5 10 ug/L 50.00 95 52-155 4,6-Dinitro-2-methylphenol 35.8 10 ug/L 50.00 72 49-138 4-Bromophenyl phenyl ether 44.1 10 ug/L 50.00 88 63-135 4-Chloro-3-methylphenol 44.6 10 ug/L 50.00 89 33-149 4-Chloroaniline 41.3 10 ug/L 50.00 83 44-163 4-Chlorophenyl phenyl ether 42.1 10 ug/L 50.00 84 63-129 4-Nitroaniline 45.5 10 ug/L 50.00 91 63-147 4-Nitrophenol 21.4 10 ug/L 50.00 43 10-77 Acenaphthene 45.0 10 ug/L 50.00 90 64-118 Acenaphthylene 45.1 10 ug/L 50.00 90 65-119 Aniline 38.7 10 ug/L 50.00 77 12-197 Anthracene 50.1 10 ug/L 50.00 100 69-134 Azobenzene 50.8 10 ug/L 50.00 102 56-129 Benzo(a)anthracene 46.8 10 ug/L 50.00 94 71-125 Benzo(a)pyrene 49.7 10 ug/L 50.00 99 67-135 Benzo(b)fluoranthene 49.2 10 ug/L 50.00 98 56-145 Benzo(g,h,i)perylene 48.8 10 ug/L 50.00 98 44-149 Benzo(k)fluoranthene 46.5 10 ug/L 50.00 93 65-138 Benzoic Acid 8.00 100 ug/L 50.00 16 10-125 1 Benzyl alcohol 34.2 10 ug/L 50.00 68 35-111 bis(2-Chloroethoxy)methane 37.8 10 ug/L 50.00 76 49-126 Bis(2-Chloroethyl)ether 31.8 10 ug/L 50.00 64 47-124 Bis(2-chloroisopropyl)ether 39.2 10 ug/L 50.00 78 42-126 Bis(2-Ethylhexyl)phthalate 53.0 10 ug/L 50.00 106 59-139 Butyl benzyl phthalate 53.3 10 ug/L 50.00 107 67-133 Chrysene 48.3 10 ug/L 50.00 97 64-124 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Analyte Result Limit Units Batch P5GO413 - 351 OC MS Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0413-BS1) Prepared: 07/23/15 Analyzed: 07/24/15 Dibenzo(a,h)anthracene 48.3 10 ug/L 50.00 97 49-144 Dibenzofuran 46.7 10 ug/L 50.00 93 68-113 Diethyl phthalate 48.7 10 ug/L 50.00 97 70-124 Dimethyl phthalate 48.4 10 ug/L 50.00 97 71-117 Di-n-butyl phthalate 51.2 10 ug/L 50.00 102 69-128 Di-n-octyl phthalate 52.7 10 ug/L 50.00 105 52-150 Fluoranthene 48.0 10 ug/L 50.00 96 66-135 Fluorene 46.9 10 ug/L 50.00 94 67-124 Hexachlorobenzene 49.0 10 ug/L 50.00 98 62-124 Hexachlorobutadiene 35.2 10 ug/L 50.00 70 42-105 Hexachlorocyclopentadiene 19.0 10 ug/L 50.00 38 32-117 Hexachloroethane 34.8 10 ug/L 50.00 70 40-99 Indeno(1,2,3-cd)pyrene 49.1 10 ug/L 50.00 98 40-150 Isophorone 41.4 10 ug/L 50.00 83 54-125 Naphthalene 37.8 10 ug/L 50.00 76 54-111 Nitrobenzene 39.0 10 ug/L 50.00 78 51-117 N-Nitroso-di-n-propylamine 39.6 10 ug/L 50.00 79 55-115 N-Nitrosodiphenylamine 50.8 10 ug/L 50.00 102 70-152 Pentachlorophenol 47.4 10 ug/L 50.00 95 23-139 Phenanthrene 50.6 10 ug/L 50.00 101 68-128 Phenol 19.2 10 ug/L 50.00 38 12-58 Pyrene 51.3 10 ug/L 50.00 103 62-139 Surrogate: 2,4,6-Tribromophenol 103 ug/L 100.0 103 49-109 Surrogate:2-Fluorobiphenyl 47.0 ug/L 50.00 94 55-96 Surrogate:2-Fluorophenol 56.4 ug/L 100.0 56 27-74 Surrogate: Nitrobenzene-d5 41.9 ug/L 50.00 84 53-99 Surrogate: Phenol-d5 36.8 ug/L 100.0 37 11-52 Surrogate: Terphenyl-d14 52.6 ug/L 50.00 105 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� ueoAAroAiEs iN� Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Prism Work Order: 5070434 Attn: Jessica Hoglen Time Submitted: 7/22/2015 10:40:OOAM 1210 Trinity Road #110 Raleigh, NC 27607 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO413 - 351 OC MS LCS Dup (P5G0413-BSD1) Prepared: 07/23/15 Analyzed: 07/24/15 1,2,4-Trichlorobenzene 48.0 10 ug/L 50.00 96 45-103 23 20 D 1,2-Dichlorobenzene 49.3 10 ug/L 50.00 99 43-100 27 20 D 1,3-Dichlorobenzene 47.4 10 ug/L 50.00 95 42-98 25 20 D 1,4-Dichlorobenzene 48.3 10 ug/L 50.00 97 42-100 27 20 D 1-Methyl naphthalene 47.1 10 ug/L 50.00 94 45-135 19 20 2,4,5-Trichlorophenol 53.4 10 ug/L 50.00 107 66-120 12 20 2,4,6-Trichlorophenol 53.0 10 ug/L 50.00 106 62-121 15 20 2,4-Dichlorophenol 50.0 10 ug/L 50.00 100 58-113 21 20 D 2,4-Dimethylphenol 48.7 10 ug/L 50.00 97 42-120 19 20 2,4-Dinitrophenol 33.6 10 ug/L 50.00 67 27-129 31 20 D 2,4-Dinitrotoluene 53.6 10 ug/L 50.00 107 62-136 7 20 2,6-Dinitrotoluene 55.8 10 ug/L 50.00 112 64-129 12 20 2-Chloronaphthalene 60.1 10 ug/L 50.00 120 38-141 16 20 2-Chlorophenol 47.6 10 ug/L 50.00 95 49-107 24 20 D 2-Methyl naphthalene 47.2 10 ug/L 50.00 94 55-112 20 20 2-Methylphenol 44.8 10 ug/L 50.00 90 40-106 23 20 D 2-Nitroaniline 51.7 10 ug/L 50.00 103 65-122 10 20 2-Nitrophenol 51.4 10 ug/L 50.00 103 57-115 24 20 D 3,3'-Dichlorobenzidine 57.5 10 ug/L 50.00 115 58-139 11 20 3/4-Methyl phenol 42.4 10 ug/L 50.00 85 34-101 23 20 D 3-Nitroaniline 51.7 10 ug/L 50.00 103 52-155 8 20 4,6-Dinitro-2-methylphenol 41.3 10 ug/L 50.00 83 49-138 14 20 4-Bromophenyl phenyl ether 48.7 10 ug/L 50.00 97 63-135 10 20 4-Chloro-3-methylphenol 50.4 10 ug/L 50.00 101 33-149 12 20 4-Chloroaniline 46.2 10 ug/L 50.00 92 44-163 11 20 4-Chlorophenyl phenyl ether 46.3 10 ug/L 50.00 93 63-129 10 20 4-Nitroaniline 49.4 10 ug/L 50.00 99 63-147 8 20 4-Nitrophenol 22.9 10 ug/L 50.00 46 10-77 7 20 Acenaphthene 51.6 10 ug/L 50.00 103 64-118 14 20 Acenaphthylene 52.2 10 ug/L 50.00 104 65-119 15 20 Aniline 46.8 10 ug/L 50.00 94 12-197 19 20 Anthracene 53.6 10 ug/L 50.00 107 69-134 7 20 Azobenzene 55.2 10 ug/L 50.00 110 56-129 8 20 Benzo(a)anthracene 51.1 10 ug/L 50.00 102 71-125 9 20 Benzo(a)pyrene 55.5 10 ug/L 50.00 111 67-135 11 20 Benzo(b)fluoranthene 54.0 10 ug/L 50.00 108 56-145 9 20 Benzo(g,hJ)perylene 55.1 10 ug/L 50.00 110 44-149 12 20 Benzo(k)fluoranthene 52.3 10 ug/L 50.00 105 65-138 12 20 Benzoic Acid 19.0 100 ug/L 50.00 38 10-125 82 20 D, J Benzyl alcohol 42.8 10 ug/L 50.00 86 35-111 22 20 D bis(2-Chloroethoxy)methane 47.6 10 ug/L 50.00 95 49-126 23 20 D Bis(2-Chloroethyl)ether 41.0 10 ug/L 50.00 82 47-124 25 20 D Bis(2-chloroisopropyl)ether 51.3 10 ug/L 50.00 103 42-126 27 20 D Bis(2-Ethylhexyl)phthalate 59.0 10 ug/L 50.00 118 59-139 11 20 Butyl benzyl phthalate 60.5 10 ug/L 50.00 121 67-133 13 20 Chrysene 51.8 10 ug/L 50.00 104 64-124 7 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Analyte Result Limit Units Batch P5GO413 - 351 OC MS Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (P5G0413-BSD1) Prepared: 07/23/15 Analyzed: 07/24/15 Dibenzo(a,h)anthracene 53.7 10 ug/L 50.00 107 49-144 11 20 Dibenzofuran 53.0 10 ug/L 50.00 106 68-113 13 20 Diethyl phthalate 53.7 10 ug/L 50.00 107 70-124 10 20 Dimethyl phthalate 54.0 10 ug/L 50.00 108 71-117 11 20 Di-n-butyl phthalate 56.1 10 ug/L 50.00 112 69-128 9 20 Di-n-octyl phthalate 59.1 10 ug/L 50.00 118 52-150 11 20 Fluoranthene 51.3 10 ug/L 50.00 103 66-135 7 20 Fluorene 52.6 10 ug/L 50.00 105 67-124 11 20 Hexachlorobenzene 53.2 10 ug/L 50.00 106 62-124 8 20 Hexachlorobutadiene 45.7 10 ug/L 50.00 91 42-105 26 20 D Hexachlorocyclopentadiene 25.9 10 ug/L 50.00 52 32-117 31 20 D Hexachloroethane 45.7 10 ug/L 50.00 91 40-99 27 20 D Indeno(1,2,3-cd)pyrene 54.5 10 ug/L 50.00 109 40-150 10 20 Isophorone 49.1 10 ug/L 50.00 98 54-125 17 20 Naphthalene 47.2 10 ug/L 50.00 94 54-111 22 20 D Nitrobenzene 48.8 10 ug/L 50.00 98 51-117 22 20 D N-Nitroso-di-n-propylamine 50.0 10 ug/L 50.00 100 55-115 23 20 D N-Nitrosodiphenylamine 55.6 10 ug/L 50.00 ill 70-152 9 20 Pentachlorophenol 52.3 10 ug/L 50.00 105 23-139 10 20 Phenanthrene 55.1 10 ug/L 50.00 110 68-128 8 20 Phenol 23.9 10 ug/L 50.00 48 12-58 22 20 D Pyrene 56.3 10 ug/L 50.00 113 62-139 9 20 Surrogate: 2,4,6-Tribromophenol 105 ug/L 100.0 105 49-109 Surrogate:2-Fluorobiphenyl 52.5 ug/L 50.00 105 55-96 SR Surrogate:2-Fluorophenol 67.1 ug/L 100.0 67 27-74 Surrogate: Nitrobenzene-d5 47.7 ug/L 50.00 95 53-99 Surrogate: Phenol-d5 41.9 ug/L 100.0 42 11-52 Surrogate: Terphenyl-d14 53.2 ug/L 50.00 106 42-133 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� ueoAAroAiEs iN� Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Prism Work Order: 5070434 Attn: Jessica Hoglen Time Submitted: 7/22/2015 10:40:OOAM 1210 Trinity Road #110 Raleigh, NC 27607 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO466 - 351 OC GC Blank (P5G0466-BLK1) Prepared: 07/25/15 Analyzed: 08/06/15 4,4'-DDD BRL 0.050 ug/L 4,4'-DDE BRL 0.050 ug/L 4,4'-DDT BRL 0.050 ug/L Aldrin BRL 0.050 ug/L alpha-BHC BRL 0.050 ug/L cis -Chlordane BRL 0.050 ug/L beta-BHC BRL 0.050 ug/L Chlordane BRL 0.50 ug/L delta-BHC BRL 0.050 ug/L Dieldrin BRL 0.050 ug/L Endosulfan I BRL 0.050 ug/L Endosulfan II BRL 0.050 ug/L Endosulfan Sulfate BRL 0.050 ug/L Endrin BRL 0.050 ug/L Endrin Aldehyde BRL 0.050 ug/L Endrin Ketone BRL 0.050 ug/L gamma-BHC BRL 0.050 ug/L trans -Chlordane BRL 0.050 ug/L Heptachlor BRL 0.050 ug/L Heptachlor Epoxide BRL 0.050 ug/L Methoxychlor BRL 0.050 ug/L Toxaphene BRL 0.50 ug/L Surrogate: Decachlorobiphenyl 0.718 ug/L 1.000 72 13-186 Surrogate: Tetrachloro-m-xylene 0.705 ug/L 1.000 71 40-134 LCS (P5G0466-BS1) Prepared: 07/25/15 Analyzed: 08/06/15 4,4'-DDD 0.971 0.050 ug/L 1.000 97 66-138 4,4'-DDE 0.938 0.050 ug/L 1.000 94 67-127 4,4'-DDT 0.933 0.050 ug/L 1.000 93 66-142 Aldrin 0.848 0.050 ug/L 1.000 85 62-124 alpha-BHC 0.889 0.050 ug/L 1.000 89 63-125 cis -Chlordane 0.880 0.050 ug/L 1.000 88 68-126 beta-BHC 0.892 0.050 ug/L 1.000 89 65-137 delta-BHC 0.882 0.050 ug/L 1.000 88 65-132 Dieldrin 0.916 0.050 ug/L 1.000 92 69-130 Endosulfan 1 0.839 0.050 ug/L 1.000 84 71-129 Endosulfan II 0.911 0.050 ug/L 1.000 91 73-135 Endosulfan Sulfate 0.901 0.050 ug/L 1.000 90 72-137 Endrin 1.01 0.050 ug/L 1.000 101 69-144 Endrin Aldehyde 0.736 0.050 ug/L 1.000 74 68-139 Endrin Ketone 0.834 0.050 ug/L 1.000 83 68-150 gamma-BHC 0.872 0.050 ug/L 1.000 87 66-129 trans -Chlordane 0.892 0.050 ug/L 1.000 89 66-126 Heptachlor 0.903 0.050 ug/L 1.000 90 61-136 Heptachlor Epoxide 0.878 0.050 ug/L 1.000 88 69-131 Methoxychlor 0.963 0.050 ug/L 1.000 96 70-157 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 38 Level II QC Report _�, P R 1 S M Full -Service Analytical 8/10/15 Environmental Solutions -, uapAniONiES, �NF Falcon Engineering Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Project: 828 MLK - CHPD Organochlorine Pesticides by GC/ECD - Quality Control Analyte Batch P5GO466 - 3510C GC Reporting Result Limit Units Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P5G0466-BS1) Prepared: 07/25/15 Analyzed: 08/06/15 Surrogate: Decachlorobiphenyl 0.792 ug/L 1.000 79 13-186 Surrogate: Tetrachloro-m-xylene 0.773 ug/L 1.000 77 40-134 LCS (P5G0466-BS2) Prepared: 07/25/15 Analyzed: 08/06/15 Chlordane 9.41 0.50 ug/L 10.00 94 50-150 Surrogate: Decachlorobiphenyl 0.735 ug/L 1.000 74 13-186 Surrogate: Tetrachloro-m-xylene 0.685 ug/L 1.000 69 40-134 LCS (P5G0466-BS3) Prepared: 07/25/15 Analyzed: 08/06/15 Toxaphene 9.88 0.50 ug/L 10.00 99 50-150 Surrogate: Decachlorobiphenyl 0.773 ug/L 1.000 77 13-186 Surrogate: Tetrachloro-m-xylene 0.790 ug/L 1.000 79 40-134 LCS Dup (P5G0466-BSD1) Prepared: 07/25/15 Analyzed: 08/06/15 4,4'-DDD 0.958 0.050 ug/L 1.000 96 66-138 1 20 4,4'-DDE 0.925 0.050 ug/L 1.000 92 67-127 1 20 4,4'-DDT 0.916 0.050 ug/L 1.000 92 66-142 2 20 Aldrin 0.835 0.050 ug/L 1.000 83 62-124 2 20 alpha-BHC 0.875 0.050 ug/L 1.000 88 63-125 2 20 cis -Chlordane 0.864 0.050 ug/L 1.000 86 68-126 2 20 beta-BHC 0.882 0.050 ug/L 1.000 88 65-137 1 20 delta-BHC 0.890 0.050 ug/L 1.000 89 65-132 0.9 20 Dieldrin 0.904 0.050 ug/L 1.000 90 69-130 1 20 Endosulfan 1 0.822 0.050 ug/L 1.000 82 71-129 2 20 Endosulfan 11 0.885 0.050 ug/L 1.000 88 73-135 3 20 Endosulfan Sulfate 0.872 0.050 ug/L 1.000 87 72-137 3 20 Endrin 0.978 0.050 ug/L 1.000 98 69-144 3 20 Endrin Aldehyde 0.738 0.050 ug/L 1.000 74 68-139 0.2 20 Endrin Ketone 0.808 0.050 ug/L 1.000 81 68-150 3 20 gamma-BHC 0.863 0.050 ug/L 1.000 86 66-129 1 20 trans -Chlordane 0.882 0.050 ug/L 1.000 88 66-126 1 20 Heptachlor 0.878 0.050 ug/L 1.000 88 61-136 3 20 Heptachlor Epoxide 0.868 0.050 ug/L 1.000 87 69-131 1 20 Methoxychlor 0.940 0.050 ug/L 1.000 94 70-157 2 20 Surrogate: Decachlorobiphenyl 0.809 ug/L 1.000 81 13-186 Surrogate: Tetrachloro-m-xylene 0.716 ug/L 1.000 72 40-134 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Level II QC Report 8/10/15 Falcon Engineering Project: 828 MLK - CHPD Prism Work Order: 5070434 Attn: Jessica Hoglen Time Submitted: 7/22/2015 10:40:OOAM 1210 Trinity Road #110 Raleigh, NC 27607 Polychlorinated Biphenyls (PCBs) by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5G0467 - 3510C GC Blank (P5G0467-BLK1) Prepared: 07/25/15 Analyzed: 08/06/15 Aroclor 1016 BRL 0.50 ug/L Aroclor 1221 BRL 1.0 ug/L Aroclor 1232 BRL 0.50 ug/L Aroclor 1242 BRL 0.50 ug/L Aroclor 1248 BRL 0.50 ug/L Aroclor 1254 BRL 0.50 ug/L Aroclor 1260 BRL 0.50 ug/L Surrogate: Tetrachloro-m-xylene 0.638 ug/L 1.000 64 30-161 Surrogate: Decachlorobiphenyl 0.691 ug/L 1.000 69 32-178 LCS (P5G0467-BS1) Prepared: 07/25/15 Analyzed: 08/06/15 Aroclor 1016 8.28 0.50 ug/L 10.00 83 50-114 Aroclor 1260 7.96 0.50 ug/L 10.00 80 10-127 Surrogate: Tetrachloro-m-xylene 0.698 ug/L 1.000 70 30-161 Surrogate: Decachlorobiphenyl 0.707 ug/L 1.000 71 32-178 LCS Dup (P5G0467-BSD1) Prepared: 07/25/15 Analyzed: 08/06/15 Aroclor 1016 8.59 0.50 ug/L 10.00 86 50-114 4 50 Aroclor 1260 8.40 0.50 ug/L 10.00 84 10-127 5 50 Surrogate: Tetrachloro-m-xylene 0.752 ug/L 1.000 75 30-161 Surrogate: Decachlorobiphenyl 0.750 ug/L 1.000 75 32-178 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 38 _�, P R 1 S M Full -Service Analytical Environmental Solutions -, uapAni0NiE5, �NF Level II QC Report 8/10/15 Falcon Engineering Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 Total Metals - Quality Control Analyte Batch P5G0417 - 7470A Project: 828 MLK - CHPD Reporting Result Limit Units Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P5G0417-BLK1) Prepared & Analyzed: 07/23/15 Mercury BRL 0.00020 mg/L LCS (P5G0417-BS1) Prepared & Analyzed: 07/23/15 Mercury 0.00908 0.00020 mg/L 0.009375 97 80-120 Matrix Spike (P5G0417-MS1) Source: 5070434-01 Prepared & Analyzed: 07/23/15 Mercury 0.00910 0.00020 mg/L 0.009375 BRL 97 80-120 Matrix Spike Dup (P5G0417-MSD1) Source: 5070434-01 Prepared & Analyzed: 07/23/15 Mercury 0.00941 0.00020 mg/L 0.009375 BRL 100 80-120 3 20 Batch P5G0450 - 3010A Blank (P5G0450-BLK1) Prepared: 07/24/15 Analyzed: 07/30/15 Arsenic BRL 0.010 mg/L Barium BRL 0.010 mg/L Boron BRL 0.50 mg/L Cadmium BRL 0.0010 mg/L Chromium BRL 0.0050 mg/L Lead BRL 0.0050 mg/L Selenium BRL 0.020 mg/L Silver BRL 0.0050 mg/L LCS (P5G0450-BS1) Prepared: 07/24/15 Analyzed: 07/30/15 Arsenic 0.252 0.010 mg/L 0.2500 101 80-120 Barium 0.255 0.010 mg/L 0.2500 102 80-120 Boron 5.05 0.50 mg/L 5.000 101 80-120 Cadmium 0.259 0.0010 mg/L 0.2500 104 80-120 Chromium 0.248 0.0050 mg/L 0.2500 99 80-120 Lead 0.262 0.0050 mg/L 0.2500 105 80-120 Selenium 0.251 0.020 mg/L 0.2500 101 80-120 Silver 0.104 0.0050 mg/L 0.1000 104 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 38 /P R I S M Environmental Full -Service Analytical Environmental Solutions �� uaoanroAies iNa Falcon Engineering Attn: Jessica Hoglen 1210 Trinity Road #110 Raleigh, NC 27607 General Chemistry Parameters - Quality Control Project: 828 MLK - CHPD Level II QC Report 8/10/15 Prism Work Order: 5070434 Time Submitted: 7/22/2015 10:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P5GO401 - NO PREP Blank (P5G0401-BLK1) Prepared & Analyzed: 07/22/15 Hexavalent Chromium BRL 0.010 mg/L LCS (P5G0401-BS1) Prepared & Analyzed: 07/22/15 Hexavalent Chromium 0.395 0.010 mg/L 0.4000 99 90-110 Matrix Spike (P5G0401-MS1) Source: 5070434-03 Prepared & Analyzed: 07/22/15 Hexavalent Chromium 0.392 0.010 mg/L 0.4000 BRL 98 85-115 Matrix Spike Dup (P5G0401-MSD1) Source: 5070434-03 Prepared & Analyzed: 07/22/15 Hexavalent Chromium 0.389 0.010 mg/L 0.4000 BRL 97 85-115 0.9 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 38 Sample Extraction Data Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 5070434-01 P5G0466 1000 mL 10 mL 07/25/15 8:00 5070434-02 P5G0466 1000 mL 10 mL 07/25/15 8:00 5070434-03 P5G0466 1000 mL 10 mL 07/25/15 8:00 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 5070434-01 135G0467 1000 mL 10 mL 07/25/15 8:00 5070434-02 P5G0467 1000 mL 10 mL 07/25/15 8:00 5070434-03 P5G0467 1000 mL 10 mL 07/25/15 8:00 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 5070434-01 P5G0413 1000 mL 1 mL 07/23/15 15:00 5070434-02 P5G0413 1000 mL 1 mL 07/23/15 15:00 5070434-03 P5G0413 1000 mL 1 mL 07/23/15 15:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 5070434-01 P5G0450 50 mL 50 mL 07/24/15 8:35 5070434-01 135G0450 50 mL 50 mL 07/24/15 8:35 5070434-02 P5G0450 50 mL 50 mL 07/24/15 8:35 5070434-02 P5G0450 50 mL 50 mL 07/24/15 8:35 5070434-03 P5G0450 50 mL 50 mL 07/24/15 8:35 5070434-03 P5G0450 50 mL 50 mL 07/24/15 8:35 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 5070434-01 P5G0417 20 mL 30 mL 07/23/15 8:50 5070434-02 P5G0417 20 mL 30 mL 07/23/15 8:50 5070434-03 P5G0417 20 mL 30 mL 07/23/15 8:50 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 5070434-01 P5G0524 10 mL 10 mL 07/28/15 12:59 5070434-02 P5G0524 10 mL 10 mL 07/28/15 12:59 5070434-03 P5G0524 10 mL 10 mL 07/28/15 12:59 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. 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M C, z Paqe 38 of 38 APPENDIX E FIELD NOTES Table 4 1 M W3A Field Data 1 7/20/2015 10:58 1.486 717 16.06 6.58 2 7/20/2015 15:22 2.014 182 16.52 6.39 3 7/20/2015 15:54 2.020 166 15.62 6.67 4 7/20/2015 16:26 1.959 75.9 16.27 6.53 5 7/21/2015 9:43 2.272 268 15.61 6.59 6 7/21/2015 10:35 2.347 12.5 16.03 6.57 7 7/21/2015 11:26 1.533 11.5 15.37 6.50 8 7/21/2015 13:30 2.326 14.42 16.79 6.51 9 7/21/2015 15:04 2.321 5.7 15.80 6.50 Table 5 1 M W4A Field Data 1 7/20/2015 11:50 0.190 324 15.43 6.41 2 7/20/2015 12:19 0.002 211 22.75 5.76 3 7/20/2015 12:55 0.964 141 13.73 6.09 4 7/20/2015 14:20 0.369 203 15.61 5.80 5 7/20/2015 16:12 0.367 79.1 16.13 6.96 6 7/21/2015 10:15 0.933 503 15.38 6.52 7 7/21/2015 11:12 0.748 46.3 15.47 6.08 8 7/21/2015 13:20 0.800 19.4 15.86 5.94 9 7/21/2015 14:49 0.831 24.7 15.64 6.25 k JF Table 6 1 M W 1 Field Data 1-S 5/20/2015 1-7 7/21/2015 8 7/21/2015 14:35 * 403 10 7/22/2015 11:30 * 95.8 12 7/22/2015 12:01 * 92.2 13 7/22/2015 12:21 0.007 66.4 20.48 6.35 14 7/22/2015 14:18 1.808 558 18.85 6.46 16 7/22/2015 15:S7 0.985 126 20.63 6.28 17 7/22/2015 16:40 1.887 156 22.05 6.44 1 8/5/2015 9:31 0.999 HIGH 18.2 6.52 2 8/5/201S 10:20 1.003 HIGH 19.42 6.81 3 8/5/2015 11:50 1.008 204 20.69 6.81 4 8/5/2015 14:46 1.012 172 19.54 6.93 5 8/5/2015 16:27 1.013 HIGH 19.18 7.11 6 8/6/201S 14:23 1.012 212 20.03 6.81 7 8/6/201S 14:S6 N/A S03 N/A N/A *No data pi - - -- I - - , I - _I .. . . - - - i ' --- . . t(I / f6L -52 I'V--Ll [ rMt 4TIA r, (6 A iv yl l- ,6, V\/L+ A V� I tq C � - -- I RNV V wb . b l 9c N .� okly, f4 Cyr, VY yr, ti M\M A- V\jI/-N- [� Z4--G f i 7- 010- /r V-161% >1, � 4 In" r- IN-4 71 wq-4 wt e� � StjVV .� sc I - • :Zb Zvi I"> Df 4r 7y�— 6,09 Ll s c • 3 C M kA �- -f cm Ll sc, 74 :; r S•7 r i � � l ► _ _— _ _ �/'i '�} y1 /p�� /�+ in A ��/][�J�,�AI�.+J- [� [J YY I - -� T}S 1• F -- :}tea R I•{JI l�i: �Y �r. ` f�� �"�' ` ��Y� l��n+ l 9 _ s s I i wo 3-�"Ats -tom Ua,l7 c�h riS 613 9 it �0��5I V�.ad�n� �efim�e �nh"al qm Z zryt� -rv.4 6 �