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1403_Caldwell_Foothills_MSWLF_Jan22GW_FID1664191_20220412
eW REPUBLIC SERVICES April 11, 2022 Ms. Jaclynne Drummond Hydrogeologist Solid Waste Section Division of Waste Management North Carolina Department of Environmental Quality 2090 US Highway 70 Swannanoa, North Carolina 28778 RE: First Semi -Annual Water Quality Monitoring Report of 2022 Foothills Regional Landfill, Permit No. 14-03 Caldwell County, North Carolina Dear Ms. Drummond: Republic Services of North Carolina, LLC is submitting the First Semi -Annual Water Quality Monitoring Report of 2022 for the Foothills Regional Landfill and Environmental Monitoring Reporting Form in electronic format. The report completes the first semi-annual compliance monitoring event of 2022 for the Foothills Regional Landfill, Permit No. 14-03, as required by the North Carolina Division of Waste Management, Solid Waste Section. If you have any questions, please contact Steve Jett with Jett Environmental Consulting at (314) 496-4654, or me at (314) 302-3634. Sincerely, Republic Services of North Carolina, LLC 2022.04.12 12:46:17-04'00' Mr. Derek Bouchard Environmental Manager Enclosure cc: Stephen Hunter, Foothills Regional Landfill, Republic Services Joe Montello, Republic Services Steve Jett, Jett Environmental Consulting Page 1 of 1 DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Jett Environmental Consulting, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Steve Jett E-mail: steve.jett@jettenviro.com Phone: (314) 496-4654 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Foothills Regional Landfill 2800 Cheraw Road 14-03 .0500 January 25-26, 2022 Lenoir, NC 28645 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steve Jett Owner (314) 496-4654 Facility Representative Name (Print) f/j A a Title (Area Code) Telephone Number Signature 4/12/2022 Date Jett Environmental Consulting, PLLC, 18 Lexington Oaks Court, Foristell, MO 63348 Facility Representative Address NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal Groundwater Statistical Analysis Report First Semi -Annual 2022 Sampling Event Foothills Regional Landfill Caldwell County, North Carolina April 2022 Prepared by: JETT ENVIRONMENTAL C O N S U L T I N G 18 Lexington Oaks Court 314-496-4654 Foristell, MO 63348 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK................1 3.0 SITE HYDROGEOLOGY................................................................2 4.0 DATA EVALUATION......................................................................3 5.0 STATISTICAL PROCEDURES.......................................................3 5.1 Outlier Analysis...........................................................................4 5.2 Inter -Well Prediction Intervals....................................................4 5.3 Intra-Well Confidence Limits......................................................4 5.4 Statistical Results Summary.......................................................5 6.0 CONCLUSIONS..............................................................................5 7.0 RECOMMENDATIONS...................................................................6 TABLES Table 1 Groundwater Monitoring Program Table 2 Groundwater Analytical Data Summary Table 3 Surface Water Analytical Data Summary Table 4 Underdrain Analytical Data Summary Table 5 Leachate Analytical Data Summary APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Reports & Field Sampling Forms Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Foothills Regional Landfill, Jett Environmental Consulting statistically evaluated the First Semi - Annual 2022 water quality monitoring data. Groundwater, surface water, underdrain, and leachate sampling were completed by Environmental Sampling & Services, Inc. (ES&S) on January 25-26, 2022, and analytical testing was performed by Pace Analytical Services, LLC. The statistical analysis software package utilized, SanitasTA' follows a documented decision logic that incorporates the following applicable document: USEPA "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance" (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK In compliance with North Carolina Department of Environmental Quality (DEQ) Solid Waste Management Regulations, Section .1600 "Requirements for Municipal Solid Waste Landfill Facilities," Jett Environmental Consulting statistically evaluated parameters from the First Semi -Annual 2022 event using inter -well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. The facility's monitoring network is comprised of eleven monitoring wells: MW-1 R2 (background), MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, and MW-11, which monitor the uppermost aquifer beneath the facility. The monitoring wells are sampled on a semi-annual basis, with the groundwater samples submitted to a qualified laboratory for required analyses in accordance with the facility's environmental monitoring program and permit requirements. The monitoring wells are equipped with dedicated bladder pumps and were purged and sampled via the low -flow method. Table 1 lists the groundwater monitoring wells for the site. Each of the wells was sampled during the First Semi -Annual 2022 event. Groundwater monitoring was initiated in August 1998. Statistical background is defined as samples collected from former upgradient well MW-1, former upgradient well MW-1R, and current upgradient well MW-1 R2 from 1998 through the current event. The parameters subject to statistical evaluation during detection monitoring are noted in DEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 "Constituents for Detection Monitoring". The following is a chronology of well replacement and abandonment. Well MW-3R2 was added to the monitoring well network on August 17, 2006 as a replacement well for MW-3 and MW-3R. Monitoring wells MW-3 and MW-3R remain for water level data collection purposes only. Monitoring well MW-7 was installed in April 2010 to monitor groundwater beneath Cell 4, which began receiving waste in September 2010. MW-8 was installed in April 2013 to monitor Cell 8A, which was constructed in January 2013. MW-10 was installed in October 2015 to monitor Cell 5A. The former background well MW-1 was abandoned in preparation for construction of Cell 5A and the new background well, MW-1 R, was installed in October 2015. MW-9 was installed June 2016 to monitor Cell 5A. Soil and bedrock removal in the Northern Borrow Area rendered well MW-1 R dry and inaccessible. Therefore, a replacement monitoring well (MW-1 R2) was installed in September 2018. New well MW-11 was also installed in September 2018 as part of the Cell No. 5B construction. The site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and four downstream points (SW-2, SW-3, SW-4, and SW-5). These points are sampled semi- annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. Each surface water monitoring point was sampled during the First Semi -Annual 2022 event. A sample point from the underdrain for Cell 1 (LID-1) was added to the monitoring program prior to the January 2008 sampling event. A sample point from the underdrain for Cells 4 and 8A (LID-2) was added to the monitoring program prior to the January 2014 sampling event. The underdrains are to be sampled Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 2 semi-annually (contingent on flow availability) for the 40 CFR Part 258 Appendix I list. Both underdrains were able to be sampled during the First Semi -Annual 2022 event. A leachate sample is also routinely collected for analysis. The leachate sample was analyzed for the 40 CFR Part 258 Appendix I list, biochemical oxygen demand, chemical oxygen demand, nitrate as N, nitrite as N, phosphorus, and sulfate. In accordance with a November 28, 2018 DEQ letter, 1,4-dioxane is no longer required be analyzed for the groundwater and surface water samples; however, will be analyzed annually for the leachate sample. The leachate was sampled and analyzed for 1,4-dioxane during the First Semi -Annual 2022 (annual) event. The facility was in an Assessment Monitoring Program in 2006. An Alternate Source Demonstration (ASD) for volatile organic compounds (VOCs) detected in wells MW-3 and MW-3R was approved by DEQ on December 14, 2006, and the facility reverted to a Detection Monitoring Program. An ASD for cobalt and a request to use background as the groundwater protection standard (GWPS) for cobalt was submitted to the DEQ in November 2016. The ASD is currently under DEQ review. An ASD for benzene and vinyl chloride at MW-2R was submitted to DEQ in June 2017; however, it was not approved in a letter from DEQ dated October 11, 2017 and Assessment Monitoring was initiated. Therefore, during the First Semi -Annual 2018 event, the initial Appendix 11 Assessment constituent list was sampled at each well. The constituents detected at quantifiable concentrations (barium, benzene, and cobalt) were consistent with past events and also on the Appendix I Detection Monitoring list. On May 18, 2018, the site requested deleting all non -Appendix I monitoring from future sampling events, with the exception of well MW-2R, which will continue with annual Appendix II monitoring. In correspondence dated July 9, 2018, DEQ approved the request to only include MW-2R for future annual Appendix II monitoring. The annual Appendix 11 monitoring for MW-2R was performed during the First Semi -Annual 2022 event. No Appendix 11 constituents, not also on the Appendix I list, were detected above their respective PQLs during the First Semi -Annual 2022 event. The next annual Appendix II sampling event for MW-2R will be the First Semi -Annual 2023 (January 2023) event. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Geologically, the facility is located in the northwestern portion of the Inner Piedmont Belt of the Piedmont Physiographic Province, approximately 20 miles east of the thrust belt (Brevard Shear Zone) delineating the boundary between the westerly Blue Ridge Belt and the easterly Inner Piedmont Belt. The metamorphic rocks of the Inner Piedmont Belt generally group within the sillimanite facies of the amphibolite metamorphic sequence. Locally, the bedrock underlying the facility has been mapped as migmatitic granitic gneiss of the Ordovician and older Cambrian Periods. These rocks are described as ranging in composition from granitic to quartz dioritic with smaller biotite gneiss and amphibolite facies present locally. The unit as a whole exhibits a variable massive to foliated fabric. The uppermost aquifer beneath the facility is present within weathered bedrock saprolite and fractured bedrock. The saprolite ranges in texture from clayey silt in the upper, most weathered sections to micaceous sandy silt in the lower sections. Immediately above the competent bedrock surface, a variable thickness transitional zone composed of highly weathered and degraded friable bedrock is present. The uppermost aquifer is laterally continuous across the site, with depth to water ranging from less than 31 feet in low-lying areas to greater than 77 feet beneath topographic highs. Groundwater in the uppermost aquifer generally flows from recharge areas associated with broad gently sloping topographic areas towards topographically lower areas that are generally delineated by the presence of stream channels, some of which are perennial receiving streams (groundwater discharge areas) and others of which are intermittent Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 3 discharging streams. In the vicinity of the facility, the general groundwater flow direction is towards the south and west. Appendix A provides a potentiometric surface map utilizing groundwater level data from the First Semi - Annual 2022 event. Groundwater flow direction for the First Semi -Annual 2022 event was to the southwest, which is consistent with previous interpretations for this facility. Groundwater flow rate for the First Semi - Annual 2022 event was estimated at 161 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION Appendix C contains a copy of the laboratory analytical report and field sampling forms for the First Semi - Annual 2022 groundwater, surface water, underdrain, and leachate sampling event. The analytical results for the First Semi -Annual 2022 event for the groundwater, surface water, underdrain, and leachate samples are summarized on Tables 2, 3, 4, and 5, respectively. One VOC was detected at a quantified concentration at or above a PQL: benzene at MW-2R. The trace level VOC detection is typical for the site. As shown on Table 2, two Appendix I inorganic constituents (barium at MW-5, MW-6, and MW-7; and cobalt at MW-4) were detected at quantified concentrations. Two Appendix I constituents (benzene at MW-2R and cobalt at MW-4) were detected above an NC Interim Maximum Allowable Concentration (IMAC) or 2L Standard during the First Semi -Annual 2022 sampling event. Cobalt (MW-6) and vanadium (MW-5, MW-6, MW-8, MW-9, and MW-10) were detected above their respective IMAC; however, at estimated concentrations below their PQL. Per 15A NCAC 02L .0202(b)(1), for the NC 2L Standards and NC IMAC Standards, only detections of a substance at or above the PQL can constitute a violation of the standard. Therefore, estimated values below the PQL are not considered a violation of a NC 2L Rule standard. As shown on Table 3, during the First Semi -Annual 2022 event, no inorganics were detected in surface water samples at quantified concentrations above a respective NC 2B Surface Water Standard. No VOCs were detected in surface water samples at quantified concentrations above their respective PQLs during the First Semi -Annual 2022 event (see Table 3). During the First Semi -Annual 2022 event, no VOCs were detected in the underdrain samples at quantified concentrations above their respective PQLs (see Table 4). The constituents detected in the leachate sample collected during the First Semi -Annual 2022 event were typical for leachate at this facility (see Table 5). 5.0 STATISTICAL PROCEDURES Statistical analyses (i.e., inter -well prediction limits) were performed to establish background concentrations and determine if the IMAC value -to -value exceedances for cobalt exhibited a statistically significant increase (SSI). Statistical analyses (i.e., lower confidence limits) were performed to determine if the 2L Standard value -to -value exceedance for benzene statistically exceeded the 2L Standard. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 4 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the USEPA Unified Guidance. Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According to the USEPA Unified Guidance above, data that are not normally or log -normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log -normally distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Inter -Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, inter -well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are non -detects, the non -detects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data's sample mean and standard deviation are adjusted according to the Kaplan -Meier method. However, when the background data are not transformed -normal or contain greater than 50% observations below the reporting limit, SanitasTm automatically constructs a non -parametric prediction interval. During non -parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Due to the wide range of laboratory reporting limits utilized over time, the historical reporting limits were conservatively replaced with the current event reporting limit prior to performing statistical analyses. Summary tables and graphs for the inter -well prediction interval analysis are available in Appendix B. Included in Appendix B are time series plots for each of the inorganic constituents. For the First Semi -Annual 2022 event, one inorganic SSI was exhibited for cobalt at MW-4. The First Semi - Annual 2022 concentration of total cobalt at MW-4 (13.6 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). An ASD for cobalt and a request to use background for the Groundwater Protection Standards (GWPSs) was submitted to the DEQ by the site on November 4, 2016. The statistical background value for cobalt was determined to be 44.1 ug/L based on an Upper Poisson Prediction Limit, which is higher than the detected concentration at MW-4. The ASD requested that the background value be considered the GWPS for cobalt per 15A NCAC13B.1634.(g).5. The ASD is currently under DEQ review. 5.3 Intra-Well Confidence Limits Per DEQ Regulation .1634(H), GWPSs are equal to the National Primary Drinking Water Standard - Maximum Contaminant Level (MCL) or North Carolina 15A NCAC 2L Water Quality Standard, whichever is lower. In instances where an MCL or 2L Standard are not established, the GWPSs were derived from the DEQ-Solid Waste Section published GWPSs. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 5 In order to determine if the groundwater concentrations exhibit a statistical exceedance of the GWPS, a statistical comparison was made to the GWPSs to determine if further action is warranted. The following text outlines the procedures that were used to statistically compare concentrations to GWPSs. Per the USEPA Unified Guidance, a Confidence Interval is constructed from sample data and is designed to contain the mean concentration of a well analyte in groundwater monitoring, with a designated level of confidence. A confidence interval generally is used when samples are being compared to a GWPS, which is typically the MCL or alternate limit (i.e., 2L Standard or NC IMAC). A lower confidence interval analysis was used to statistically compare to GWPSs. The method constructs a normal confidence interval on the mean concentration of a constituent incorporating, at a minimum, the four most recent measurements. The lower confidence interval on the mean was compared to the GWPS to determine whether the mean concentration exceeded its GWPS. If the lower confidence interval on the mean exceeds the GWPS then there is statistically significant evidence that the mean concentration of that constituent exceeds the GWPS. The distribution of the data is evaluated by applying the Shapiro -Wilk or Shapiro -Francis test for normality to the raw data or, when applicable, transformed data. If less than 15 percent of the observations are non - detects, the non -detects will be replaced with one half the reporting limit prior to performing the normality test and constructing the confidence limit. Per .1634(g)(5), if background (statistical limit based on upgradient well data) is higher than the 2L Standard, then background may be utilized as the GWPS. Background for organics is considered the non - detect level (equivalent to the PQL). Organic concentrations detected above PQLs and GWPSs (See Table 2) were statistically compared to their respective GWPSs utilizing intra-well lower confidence limits. As provided in Appendix B, benzene at MW-2R statistically exceeded the GWPS for the First Semi -Annual 2022 event, consistent with recent events. Time series graphs for VOC detections during recent events are provided in Appendix B. 5.4 Statistical Results Summary For the First Semi -Annual 2022 event, one inorganic SSI was exhibited for cobalt at MW-4. The First Semi - Annual 2022 concentration of total cobalt at MW-4 (13.6 ug/L) was above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). However, cobalt concentrations at MW-4 have been decreasing since the July 2012 event (25.4 ug/L). Intra-well lower confidence limits determined benzene at MW-2R (2.4 ug/L) statistically exceeded the GWPS for the First Semi -Annual 2022 event, consistent with recent events. However, benzene concentrations at MW-2R have not exceeded the peak concentration detected in January 2018 (2.6 ug/L). 6.0 CONCLUSIONS For the First Semi -Annual 2022 event, one inorganic SSI was confirmed exhibited for cobalt at MW-4, consistent with recent events. One Appendix I constituent (benzene at MW-2R) was confirmed detected above an NC IMAC or 2L Standard during the First Semi -Annual 2022 sampling event. Intra-well lower confidence limits determined benzene at MW-2R statistically exceeded the GWPS for the First Semi -Annual 2022 event, consistent with recent events. During the First Semi -Annual 2022 event, no Appendix I VOCs were confirmed detected in surface water and underdrain samples at quantifiable concentrations. No inorganics were detected in surface water Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 6 samples at quantified concentrations above a respective NC 2B Surface Water Standard during the First Semi -Annual 2022 event. The Foothills Regional Landfill will continue monitoring in accordance with the requirements for Detection and Assessment Monitoring as outlined in Title 15A NCAC 13B .1633 and .1634, respectively. The next semi-annual event is scheduled for July 2022. 7.0 RECOMMENDATIONS Wells in the proximity of MW-2R exist directly upgradient (MW-9) and directly downgradient (MW-3R2). No VOCs have been confirmed detected at quantified concentrations at MW-9 or MW-3R2; therefore, the extent of quantified VOC detections (i.e., benzene) has been defined to only MW-2R. As described in the site's June 2017 ASD for benzene/vinyl chloride at MW-2R, the VOCs appear to be related to landfill gas. Wells MW-9, MW-2R, and MW-3R2 would effectively cover the exterior perimeter of the cell (Cell 1A) suspected as the source of potential gas migration. The site implemented landfill gas extraction and collection upgrades in the Cell 1A area in late 2017 and installed a horizontal active landfill gas collection/mitigation trench in the vicinity of MW-2R in Fall 2018 (see map in Appendix A). Benzene concentrations at MW-2R have not exceeded the peak concentration detected in January 2018 (2.6 ug/L). Additional groundwater monitoring events are recommended before any further actions are considered to determine if benzene levels at MW-2R (2.4 ug/L) decrease to levels below the lab PQL (1.0 ug/L) as a result of the landfill gas system upgrades. It is recommended that well MW-4 continues in Detection Monitoring. The decrease in concentration of cobalt at MW-4 from 25.4 ug/L in July 2012 to 13.6 ug/L during the First Semi -Annual 2022 event, indicates a decreasing trend near the laboratory PQL (10 ug/L). Since the landfill is lined, it is unlikely the cobalt detections are related to a landfill release. The lack of receptors of water use in this shallow well, which would not feasibly produce a well with sufficient yield for potable use, is evidence of a lack of risk associated with this level of detection. Cobalt is naturally occurring at the site, evident by the historical cobalt detections in various wells across this site, and is a common element occurring naturally in minerals commonly found in the bedrock, soil, and sediments in the North Carolina Piedmont. According to A Geochemical Atlas of North Carolina (by Jeffery C. Reid, dated 1993 in the North Carolina Geological Survey's Bulletin 93), which displays the distribution of cobalt in stream sediments across the state, Caldwell County has been highlighted. Cobalt was found at concentrations as high as 10 mg/kg throughout Caldwell County; with a significant amount of variability. Metals in the soil and bedrock can easily leach into the groundwater, especially if the groundwater is acidic (pH < 7.0). The pH of groundwater samples from the Foothills Regional Landfill during the First Semi -Annual 2022 sampling event ranged from 5.31 to 7.90 SU. The pH of the sample from MW-4, which had the highest cobalt concentration, was 5.31 SU. Review of leachate data for the last 12 years indicates cobalt has ranged from J 7.3 to J 43.7 ug/L, with an average concentration of 24.8 ug/L. The occurrence and levels of cobalt at the site has no indication of being related to a release from the waste unit. The site recommends utilizing the upcoming Second Semi -Annual 2022 (July 2022) event to continue to verify the downward/stable trends of cobalt levels at MW-4 and benzene at MW-2R, since levels are approaching the laboratory PQL of 10 ug/L and 1.0 ug/L, respectively. The proposed actions are protective of human health and the environment and the values at this time do not further action, especially for a naturally occurring element (cobalt). TABLES TABLE 1 GROUNDWATER MONITORING PROGRAM FIRST SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL UPGRADIENT WELLS I DOWNGRADIENT WELLS MW-1 R2 I MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11 TABLE 2 GROUNDWATER ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units 2LStd IMAC MDL PQL MW-1R2 MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 Antimony Total ug/L NE 1 0.78 6 <6 <6 <6 <6 <6 <6 <6 <6 0.84 J <6 <6 Arsenic Total u /L 10 NE 1.1 10 <10 <10 <10 <10 1.3 J 1.4 J <10 1.4 J <10 <10 <10 Barium Total ug/L 700 NE 0.67 100 70.9 J 307 J 4.1 J 62.4 J 152 121 101 45.9 J 9.0 J 25.1 J 86.9 J Beryllium Total u /L NE 4 0.054 1 <1 0.16 J <1 0.086 J 0.093 J 0.37 J 0.18 J <1 <1 <1 <1 Cadmium Total ug/L 2 NE 0.11 1 <1 0.11 J <1 <1 <1 <1 0.18 J <1 <1 <1 <1 Chromium Total u /L 10 NE 1 1.1 10 <10 <10 1.5 J I <10 1.5 J 1.5 J 1.2 J <10 <10 <10 <10 Cobalt Total ug/L NE 1 0.39 10 <10 <10 <10 13.6 <10 3.7 J <10 <10 <10 <10 I <10 Copper Total u /L 1,000 NE 0.5 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Cyanide Total ug/L 70 NE 6.0 8 NS <8.0 NS NS NS NS NS NS NS NS NS Lead Total u /L 15 NE 0.89 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Mercury Total ug/L 1 NE 0.13 0.2 NS <0.2 NS NS NS NS NS NS NS NS NS Nickel Total u /L 100 NE 0.71 50 <50 <0.2 <50 0.79 J <50 <50 <50 <50 <50 <50 <50 Selenium Total ug/L 20 NE 1 1.4 10 <10 <50 <10 <10 <10 <10 <10 <10 <10 <10 <10 Silver Total u /L 20 NE 0.44 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Tin Total ug/L NE 2000 1.5 20 NS <20 NS NS NS NS NS NS NS NS NS Thallium Total u /L NE 0.28 0.18 5.5 <5.5 <10 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total ug/L NE 0.3 1.9 25 <25 <25 <25 <25 4.1 J 2.4 J <25 2.0 J 2.0 J 3.3 J <25 Zinc Total u /L 1,000 NE 7.0 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Field Dissovled Oxygen m /L NE NE NE NE 1.85 2.45 3.15 1.70 2.32 2.26 4.62 2.42 3.35 5.15 1.90 Field pH SU NE I NE NE NE 6.44 5.74 7.90 5.31 5.83 5.57 5.56 5.85 5.98 6.54 6.78 Field Redox mV NE NE NE NE 40.2 73.6 -28.2 95.7 68.2 81.7 81.2 66.1 60.0 31.6 18.6 Field Specific Conductance umhos/cm NE NE NE NE 80.1 156.8 265 46.3 233 155.2 364 96.8 196.1 63.9 71.1 Field Temperature °C NE NE NE NE 12.1 14.4 14.5 16.2 15.4 14.8 12.3 12.2 14.0 12.5 11.3 Field Turbidity NTU NE NE NE NE 0.89 0.58 1 0.65 0.50 0.57 2.62 3.08 2.40 0.38 0.86 0.46 Benzene u /L 1 NE 1 0.34 1 <1 1 2.4 <1 <1 0.77 J <1 I <1 <1 <1 I <1 <1 For VOCs, only constituents with one or more detections above a PQL are included on table. NE: Denotes a NC 2L or IMAC Standard is not established. NS: Not required to be sampled. J. Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. Denotes a concentration at or above a PQL is also above a NC 2L Standard: Denotes a concentration at or above a PQL is also above a NC IMAC Standard: Denotes a concentration is above a NC 2L or IMAC Standard, but but below the PQL: TABLE 3 SURFACE WATER ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units NC 2B Std MDL PQL SW-1 SW-2 SW-3 SW-4 SW-5 Antimony Total ug/L 640 0.78 6 <6 <6 <6 <6 <6 Arsenic Total ug/L 10 1.1 10 <10 <10 <10 <10 1.5 J Barium Total ug/L 21,000 0.67 100 25.6 J 26.1 J 21.4 J 24.1 J 25.2 J Beryllium Total ug/L 6.5 0.054 1 <1 <1 <1 <1 <1 Cadmium Total ug/L NE 0.11 1 <1 <1 <1 <1 <1 Chromium Total ug/L NE 1.1 10 <10 <10 1.6 J <10 <10 Cobalt Total ug/L 4 0.39 10 1.1 J 1.3 J 0.45 J 0.42 J 1.1 J Copper Total ug/L NE 0.5 10 6.4 J <10 0.68 J 0.59 J <10 Lead Total ug/L NE 0.89 10 <10 <10 <10 <10 <10 Nickel Total ug/L NE 0.71 50 <50 <50 <50 <50 <50 Selenium Total ug/L 5 1.4 10 <10 <10 <10 <10 <10 Silver Total ug/L 0.06 0.44 10 <10 <10 <10 <10 <10 Thallium Total ug/L 0.47 0.18 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total ug/L NE 1.9 25 2.8 J 2.2 J 2.1 J <25 3.1 J Zinc Total ug/L NE 7.0 10 10.1 <10 <10 <10 11.4 Field Dissolved Oxygen mg/L NE NE NE 4.02 3.92 5.42 5.30 3.60 Field pH SU NE NE NE 6.56 6.66 7.87 7.65 7.35 Field Redox mV NE NE NE 20.2 24.7 -37.3 -25.7 -13.8 Field Specific Conductance umhos/cm NE NE NE 79.2 98.5 67.2 69.8 136.2 Field Temperature °C NE NE NE 11.1 11.4 10.2 10.0 10.2 Field Turbidity NTU NE NE NE 3.98 3.26 2.92 2.38 5.49 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. NE: Denotes a NC 2B Standard is not established. No VOCs detected above a PQL, therefore not included on this table. TABLE 4 UNDERDRAIN ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units MDL PQL UD-1 UD-2 Antimony Total ug/L 0.78 6 <6 <6 Arsenic Total ug/L 1.1 10 2.1 J <10 Barium Total ug/L 0.67 100 68.1 J 57.2 J Beryllium Total ug/L 0.054 1 0.074 J <1 Cadmium Total ug/L 0.11 1 <1 <1 Chromium Total ug/L 1.1 10 <10 <10 Cobalt Total ug/L 0.39 10 6.5 J 5.9 J Copper Total ug/L 0.5 10 <10 <10 Lead Total ug/L 0.89 10 <10 <10 Nickel Total ug/L 0.71 50 1.4 J 1.2 J Selenium Total ug/L 1.4 10 <10 <10 Silver Total ug/L 0.44 10 <10 <10 Thallium Total ug/L 0.18 5.5 <5.5 <5.5 Vanadium Total ug/L 1.9 25 4.3 J 3.7 J Zinc Total ug/L 7.0 10 9.6 J <10 Field Dissolved Oxygen mg/L NE NE 3.70 3.26 Field pH SU NE NE 5.94 5.92 Field Redox mV NE NE 63.1 64.2 Field Specific Conductance umhos/cm NE NE 252 201 Field Temperature °C NE NE 18.1 1 24.5 Field Turbidity NTU NE NE 4.28 1 1.96 J: Denotes sample result above the MDL but below the PQL; estimated value; value may not be accurate. No VOCs detected above a PQL, therefore not included on this table. NE: Not established. TABLE 5 LEACHATE ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2022 EVENT FOOTHILLS REGIONAL LANDFILL Indicator Parameters Units MDL PQL Leachate Antimony ug/L 19.5 150 107 J Arsenic u /L 28.3 250 213 J Barium ug/L 16.8 2500 437 J Beryllium u /L 1.3 25 <25 BOD, 5 day ug/L 2000 2000 302000 Cadmium u /L 2.8 25 <25 Chemical Oxygen Demand ug/L 50000 100000 2810000 Chromium u /L 27.4 250 378 Cobalt ug/L 9.9 250 33.2 J Copper u /L 12.6 250 273 Lead ug/L 22.2 250 <250 Mercury u /L 0.13 0.2 <0.2 Nickel ug/L 17.7 1250 172 J Nitrogen, Ammonia u /L 5420 20000 1070000 Nitrogen, Kjeldahl, Total ug/L 25000 50000 1290000 Nitrogen, Nitrate u /L 1200 2000 <2000 Nitrogen, Nitrite ug/L 1000 2000 <2000 Phosphorus u /L 125 250 7730 Selenium ug/L 34.2 250 <250 Silver u /L 10.9 250 <250 Sulfate ug/L 10000 20000 21600 Total Dissolved Solids u /L 200000 200000 4960000 Thallium ug/L 4.5 138 <138 Total Suspended Solids u /L 5000 5000 11000 Vanadium ug/L 46.5 625 97.2 J Zinc u /L 174 250 <250 Field pH SU NE NE 7.86 Field Specific Conductance umhos/cm NE NE 26000 Field Temperature °C NE NE 17.6 Field Turbidity NTU NE NE 22.80 1,4-Dioxane ug/L 2.2 5 143 2-Butanone u /L 79.2 2000 2240 Acetone ug/L 102 2000 4830 Eth (benzene u /L 6.1 20 23.7 Metals reported as Total. For VOCs, only constituents with detections above a PQL are included on table. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP &SW-1 `--� MW-8 164.31(8 I I II BMW- 1151.13 , �--� 1 D-2 MW-6 1133.66 I I / I MW-5 1127.70� a ['MMw-4 • 1129.4� E EXISTING CELL NO. 8A o^ G N / E TING ELL O. 5 I310 1 �pJ XISTI C 3B 1 SlEr 2 n UD-1 / EXIS I o L 1200 In E L O.II m5:11 i I Il I,125W 1 E I CE 1 �H ELL NO. 113 L LL �MW-11 1318.60 17 I 1 I EXISTI CELL NO. (UNDE l STRUC ION) 0_10 1282.21; 1 IN, �oBMW-3R2 1187.95 �1198.65 e 1$ MW-3R //A �� 1183.35 SW-5 W5 �� 2J \ 0 12f0 &SW-3 NORTH 0 100 200 400 800 Scale in Feet Graphic Scale: 1 inch = 400 feet Phm It LEGEND SMW-7 Monitoring Well Location 1. SUD-1 Underdrain Location VVV 1151.13 Groundwater Elevation (fmsl) —1300— Potentiometric Surface Contour (fmsl) Hydraulic Gradient & Inferred 0.1176 Groundwater Flow Direction 3W-1 Surface Water Sampling Location (Approx) Landfill Cell Boundary __ LFG Trench (Approx) Water levels collected by Environmental Sampling & Services, Inc. on January 26, 2022 Basemap provided by Joyce Engineering, with topographic survey completed by Cooper Aerial Surveys Co., date of Photography is January 20, 2014. J ETT54 Figure 1 18 Lexington Oaks Court First Semi -Annual 2022 Event Potentiometric Surface Map 40 C / 6� w' Fonstell, MO 63348 EN4VIRONMENTAG www.jettenvro.com � Foothills Regional Landfill, Caldwell County, North Carolina Groundwater Elevation Summary Table Foothills Regional Landfill Well Top of PVC Casing Elevation (fmsl)' 2 Depth to Water (ft) Groundwater Elevation (fmsl) MW-1 R2 1516.22 22.30 1493.92 MW-2R 1253.36 50.01 1203.35 MW-3 1241.95 54.00 1187.95 MW-3R 1242.69 59.34 1183.35 MW-31R2 1240.83 42.18 1198.65 MW-4 1171.18 41.69 1129.49 MW-5 1175.07 47.37 1127.70 MW-6 1176.82 43.16 1133.66 MW-7 1183.13 32.00 1151.13 MW-8 1195.18 30.80 1164.38 MW-9 1290.79 69.10 1221.69 MW-10 1358.53 76.32 1282.21 MW-11 1401.71 83.11 1318.60 Note 1: Top of PVC Casing Elevations from Table 1 of the Water Quality Monitoring Plan dated March 20, 2019 by BLE. Note 2: Depth to water measured by Environmental Sampling & Services, Inc. on January 26, 2022. Groundwater Flow Velocity Calculations Foothills Regional Landfill First Semi -Annual 2022 Event Velocity V = [(k)(i)]/(n) V = [(0.374 ft/day)(0.1176 ft/ft)] / 0.1 V = 0.440 ft/day V = 161 ft/year Where, Hydraulic conductivity (k) and effective porosity (n) values from the following document: Table 2 of the Second SemiAnnual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path is From Point A (1450 contour) to Point 8 (1150 contour) = 300 ft / 2,552 ft = 0.1176 ft/ft APPENDIX B STATISTICAL EVALUATIONS Prediction Limit Foothills Client: RSI Data: Foothills Printed 3/29/2022, 9:01 AM Constituent Well Uooer Lim. Lower Lim. Date Observ. Sia. Ba N Ba Mean Std. Day. ° NDs ND Ad. Transform Aloha Method Cobalt Total (ug/L) MW-4 10.0 n/a 1/26/2022 13.6 Yes 51 n/a n/a 94.12 n/a n/a 0.0007092 NP Inter (NDs) 1 of 2 Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-4 Prediction Limit 30 24 18 M 12 M 0 4- 7/19/99 Interwell Non -parametric 1 /19/04 7/21 /08 1 /22/13 7/25/17 1 /26/22 ♦ MW-4 Limit = 10.0 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 51 background values. 94.12% NDs. Annual per -constituent alpha = 0.01409. Individual comparison alpha = 0.0007092 (1 of 2). Assumes 9 future values. After outlier removal distribution was non -normal, so outlier results were invalidated. Constituent: Cobalt Total Analysis Run 3/29/2022 9:00 AM View: PL Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 4 3.2 2.4 1.6 J 0.8 111 "4A Constituent: Benzene Analysis Run 3/29/2022 9:19 AM View: Cl Foothills Client: RSI Data: Foothills Confidence Interval Constituent: Benzene (ug/L) Analysis Run 3/29/2022 9:19 AM View: Cl Foothills Client: RSI Data: Foothills MW-2R 7/27/2020 2.1 2/1/2021 2 7/26/2021 2.5 1/26/2022 2.4 Mean 2.25 Std. Dev. 0.238 Upper Lim. 2.79 Lower Lim. 1.71 TIME SERIES TREND ANALYSIS Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 6 4.8 3.6 J 0) Z3 2.4 1.2 0 1 /6/09 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) 8/17/11 3/28/14 11 /5/16 6/17/19 1 /26/22 Constituent: Antimony Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 8 4 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Arsenic Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 700 560 420 J 280 140 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Barium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 3 2.4 1.8 J 1.2 0.6 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Beryllium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J Z3 2 0 8/10/98 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Cadmium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 40 32 24 J 16 8 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 MW-11 MW-1 R2 (bg) 8/10/98 g" Jt 4/20/03 12/29/07 9/7/12 5/18/17 1/26/22 Constituent: Chromium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Cobalt Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 500 400 300 J 200 100-7 0 8/10/98 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Copper Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series n 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Lead Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) SanitasTM v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 - J 20 10 ixIL 0 8/10/98 4/20/03 12/29/07 9/7/12 5/18/17 1/26/22 Constituent: Nickel Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 lvl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1/26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Selenium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 20 10 0 4- 8/10/98 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Silver Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 8 6 Y �L J 4 2 - 0 8/10/98 4/20/03 12/29/07 9/7/12 5/18/17 1/26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 r Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Thallium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 60 48 36 J 24 12 0 4- 8/10/98 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Vanadium Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 0) 80 40 Time Series CI'A - Ir, I", _ , 8/10/98 4/20/03 12/29/07 9/7/12 5/18/17 1/26/22 Constituent: Zinc Total Analysis Run 3/29/2022 8:18 AM View: TS Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 0 1 /6/09 Time Series 8/17/11 3/28/14 11 /5/16 6/17/19 1 /26/22 Constituent: 11-Dichloroethane Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) 0 4- 8/10/98 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 Constituent: Benzene Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills SanitasTM v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J Z3 2 1 0 1 /6/09 Time Series 8/17/11 3/28/14 11/5/16 6/17/19 1 /26/22 MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) Constituent: cis- 1 2-Dichloroethene Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 8/10/98 Time Series 4/20/03 12/29/07 9/7/12 5/18/17 1 /26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Tetrachloroethene Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 0 4- 1 /6/09 Time Series L_! 8/17/11 3/28/14 11 /5/16 6/17/19 1 /26/22 ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 i Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Constituent: Toluene Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) 0 4- 1 /6/09 8/17/11 3/28/14 11 /5/16 6/17/19 1 /26/22 Constituent: Trichloroethene Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0.8 0.4 Time Series MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) 0 4- 1 /6/09 8/17/11 3/28/14 11 /5/16 6/17/19 1 /26/22 Constituent: Vinyl chloride Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills Sanitas" v.9.6.32 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 0 1 /6/09 Time Series 8/17/11 3/28/14 11 /5/16 6/17/19 1 /26/22 f Constituent: Xylenes [Total] Analysis Run 3/29/2022 9:22 AM View: TS VOCs Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 Ivl vv-y MW-11 MW-1 R2 (bg) APPENDIX C LABORATORY ANALYTICAL REPORTS FIELD SAMPLING FORMS lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 08, 2022 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 89 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Lab ID Sample ID Matrix Date Collected Date Received 92584821001 1403-MW-1 R2 Water 01/26/22 15:52 01/27/22 10:40 92584821002 1403-MW-3R2 Water 01/26/2213:42 01/27/22 10:40 92584821003 1403-MW-4 Water 01/26/22 12:47 01/27/22 10:40 92584821004 1403-DUP@MW-4 Water 01/26/2212:49 01/27/22 10:40 92584821005 1403-MW-5 Water 01/26/2211:57 01/27/22 10:40 92584821006 1403-MW-6 Water 01/26/2211:07 01/27/22 10:40 92584821007 1403-MW-7 Water 01/26/22 10:17 01/27/22 10:40 92584821008 1403-MW-8 Water 01/26/22 09:26 01/27/22 10:40 92584821009 1403-MW-9 Water 01/26/22 08:31 01/27/22 10:40 92584821010 1403-MW-10 Water 01/26/22 07:41 01/27/22 10:40 92584821011 1403-MW-11 Water 01/26/22 06:48 01/27/22 10:40 92584821012 1403-Field Blank Water 01/25/22 13:50 01/27/22 10:40 92584821013 1403-SW1 Water 01/25/22 13:58 01/27/22 10:40 92584821014 1403-SW2 Water 01/25/22 15:04 01/27/22 10:40 92584821015 1403-SW3 Water 01/25/2216:18 01/27/22 10:40 92584821016 1403-SW4 Water 01/25/22 15:52 01/27/22 10:40 92584821017 1403-SW5 Water 01/25/2215:28 01/27/22 10:40 92584821018 1403-UD1 Water 01/25/2214:45 01/27/22 10:40 92584821019 1403-UD2 Water 01/25/22 14:24 01/27/22 10:40 92584821020 1403-Trip Blank Water 01/25/22 13:54 01/27/22 10:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/Semi-Annual 92584821 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92584821001 1403-MW-1R2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821002 1403-MW-3R2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821003 1403-MW-4 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821004 1403-DUP@MW-4 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821005 1403-MW-5 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821006 1403-MW-6 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821007 1403-MW-7 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821008 1403-MW-8 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821009 1403-MW-9 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821010 1403-MW-10 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821011 1403-MW-11 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821012 1403-Field Blank EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821013 1403-SW1 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821014 1403-SW2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821015 1403-SW3 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821016 1403-SW4 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C 92584821017 1403-SW5 EPA6020B CW1 15 PASI-GA EPA 8260D NSCQ 50 PASI-C 92584821018 1403-UD1 EPA6020B CW1 15 PASI-GA EPA 8260D NSCQ 50 PASI-C 92584821019 1403-UD2 EPA6020B CW1 15 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D NSCQ 50 PASI-C 92584821020 1403-Trip Blank EPA 8260D NSCQ 50 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual 92584821 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584821001 1403-MW-1 R2 Performed by ES&S 01/26/22 15:52 pH 6.44 Std. Units 01/26/22 15:52 Temperature 12.1 deg C 01/26/22 15:52 Static Water Level 22.45 feet 01/26/22 15:52 Specific Conductance 80.1 umhos/cm 01/26/22 15:52 Oxidation Potential 40.2 my 01/26/22 15:52 Oxygen, Dissolved 1.85 mg/L 01/26/22 15:52 Total Well Depth 43.34 feet 01/26/22 15:52 Turbidity 0.89 NTU 01/26/22 15:52 EPA 6020B Barium 70.9J ug/L 100 02/02/22 14:42 92584821002 1403-MW-3R2 Performed by ES&S 01/26/22 13:42 pH 7.90 Std. Units 01/26/22 13:42 Temperature 14.5 deg C 01/26/22 13:42 Static Water Level 42.43 feet 01/26/22 13:42 Specific Conductance 265 umhos/cm 01/26/22 13:42 Oxidation Potential -28.2 my 01/26/22 13:42 Oxygen, Dissolved 3.15 mg/L 01/26/22 13:42 Total Well Depth 73.91 feet 01/26/22 13:42 Turbidity 0.65 NTU 01/26/22 13:42 EPA 6020B Barium 4.1 J ug/L 100 02/02/22 14:48 EPA 6020B Chromium 1.51 ug/L 10.0 02/02/22 14:48 92584821003 1403-MW-4 Performed by ES&S 01/26/22 12:47 pH 5.31 Std. Units 01/26/22 12:47 Temperature 16.2 deg C 01/26/22 12:47 Static Water Level 41.80 feet 01/26/22 12:47 Specific Conductance 46.3 umhos/cm 01/26/22 12:47 Oxidation Potential 95.7 my 01/26/22 12:47 Oxygen, Dissolved 1.70 mg/L 01/26/22 12:47 Total Well Depth 52.20 feet 01/26/22 12:47 Turbidity 0.50 NTU 01/26/22 12:47 EPA 6020B Barium 62AJ ug/L 100 02/02/22 14:54 EPA 6020B Beryllium 0.086J ug/L 1.0 02/02/22 14:54 EPA 6020B Cobalt 13.6 ug/L 10.0 02/02/22 14:54 EPA 6020B Nickel 0.79J ug/L 50.0 02/02/22 14:54 92584821004 1403-DUP@MW-4 EPA 6020B Barium 67.6J ug/L 100 02/02/22 15:00 EPA 6020B Beryllium 0.096J ug/L 1.0 02/02/22 15:00 EPA 6020B Cobalt 14.6 ug/L 10.0 02/02/22 15:00 EPA 6020B Nickel 0.76J ug/L 50.0 02/02/22 15:00 92584821005 1403-MW-5 Performed by ES&S 01/26/22 11:57 pH 5.83 Std. Units 01/26/22 11:57 Temperature 15.4 deg C 01/26/22 11:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584821005 1403-MW-5 Static Water Level 47.51 feet 01/26/22 11:57 Specific Conductance 233 umhos/cm 01/26/22 11:57 Oxidation Potential 68.2 mV 01/26/22 11:57 Oxygen, Dissolved 2.32 mg/L 01/26/22 11:57 Total Well Depth 54.50 feet 01/26/22 11:57 Turbidity 0.57 NTU 01/26/22 11:57 EPA 6020B Arsenic 1.3J ug/L 10.0 02/02/22 15:06 EPA 6020B Barium 152 ug/L 100 02/02/22 15:06 EPA 6020B Beryllium 0.093J ug/L 1.0 02/02/22 15:06 EPA 6020B Chromium 1.5J ug/L 10.0 02/02/22 15:06 EPA 6020B Vanadium 4.1 J ug/L 25.0 02/02/22 15:06 EPA 8260D Benzene 0.77J ug/L 1.0 01 /29/22 05:22 EPA8260D cis-1,2-Dichloroethene 2.2J ug/L 5.0 01/29/2205:22 92584821006 1403-MW-6 Performed by ES&S 01/26/22 11:07 pH 5.57 Std. Units 01/26/22 11:07 Temperature 14.8 deg C 01/26/22 11:07 Static Water Level 43.30 feet 01/26/22 11:07 Specific Conductance 155.2 umhos/cm 01/26/22 11:07 Oxidation Potential 81.7 mV 01/26/22 11:07 Oxygen, Dissolved 2.26 mg/L 01/26/22 11:07 Total Well Depth 50.55 feet 01/26/22 11:07 Turbidity 2.62 NTU 01/26/22 11:07 EPA 6020B Arsenic 1 AJ ug/L 10.0 02/02/22 15:12 EPA 6020B Barium 121 ug/L 100 02/02/22 15:12 EPA 6020B Beryllium 0.37J ug/L 1.0 02/02/22 15:12 EPA 6020B Chromium 1.5J ug/L 10.0 02/02/22 15:12 EPA 6020B Cobalt 3.7J ug/L 10.0 02/02/22 15:12 EPA 6020B Vanadium 2AJ ug/L 25.0 02/02/22 15:12 92584821007 1403-MW-7 Performed by ES&S 01/26/22 10:17 pH 5.56 Std. Units 01/26/22 10:17 Temperature 12.3 deg C 01/26/22 10:17 Static Water Level 32.12 feet 01/26/22 10:17 Specific Conductance 364 umhos/cm 01/26/22 10:17 Oxidation Potential 81.2 mV 01/26/22 10:17 Oxygen, Dissolved 4.62 mg/L 01/26/22 10:17 Total Well Depth 40.13 feet 01/26/22 10:17 Turbidity 3.08 NTU 01/26/22 10:17 EPA 6020B Barium 101 ug/L 100 02/02/22 15:18 EPA 6020B Beryllium 0.18J ug/L 1.0 02/02/22 15:18 EPA 6020B Cadmium 0.18J ug/L 1.0 02/02/22 15:18 EPA 6020B Chromium 1.2J ug/L 10.0 02/02/22 15:18 92584821008 1403-MW-8 Performed by ES&S 01/26/22 09:26 pH 5.85 Std. Units 01/26/22 09:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584821008 1403-MW-8 Temperature 12.2 deg C 01/26/22 09:26 Static Water Level 30.92 feet 01/26/22 09:26 Specific Conductance 96.8 umhos/cm 01/26/22 09:26 Oxidation Potential 66.1 mV 01/26/22 09:26 Oxygen, Dissolved 2.42 mg/L 01/26/22 09:26 Total Well Depth 49.56 feet 01/26/22 09:26 Turbidity 2.40 NTU 01/26/22 09:26 EPA 6020B Arsenic 1 AJ ug/L 10.0 02/02/22 15:24 EPA 6020B Barium 45.9J ug/L 100 02/02/22 15:24 EPA 6020B Vanadium 2.OJ ug/L 25.0 02/02/22 15:24 92584821009 1403-MW-9 Performed by ES&S 01/26/22 08:31 pH 5.98 Std. Units 01/26/22 08:31 Temperature 14.0 deg C 01/26/22 08:31 Static Water Level 69.25 feet 01/26/22 08:31 Specific Conductance 196.1 umhos/cm 01/26/22 08:31 Oxidation Potential 60.0 mV 01/26/22 08:31 Oxygen, Dissolved 3.35 mg/L 01/26/22 08:31 Total Well Depth 73.40 feet 01/26/22 08:31 Turbidity 0.38 NTU 01/26/22 08:31 EPA 6020B Antimony 0.84J ug/L 6.0 02/02/22 15:49 EPA 6020B Barium 9.01 ug/L 100 02/02/22 15:49 EPA 6020B Vanadium 2.OJ ug/L 25.0 02/02/22 15:49 92584821010 1403-MW-10 Performed by ES&S 01/26/22 07:41 pH 6.54 Std. Units 01/26/22 07:41 Temperature 12.5 deg C 01/26/22 07:41 Static Water Level 76.46 feet 01/26/22 07:41 Specific Conductance 63.9 umhos/cm 01/26/22 07:41 Oxidation Potential 31.6 mV 01/26/22 07:41 Oxygen, Dissolved 5.15 mg/L 01/26/22 07:41 Total Well Depth 88.21 feet 01/26/22 07:41 Turbidity 0.86 NTU 01/26/22 07:41 EPA 6020B Barium 25.1 J ug/L 100 02/02/22 15:55 EPA 6020B Vanadium 3.3J ug/L 25.0 02/02/22 15:55 92584821011 1403-MW-11 Performed by ES&S 01/26/22 06:48 pH 6.78 Std. Units 01/26/22 06:48 Temperature 11.3 deg C 01/26/22 06:48 Static Water Level 83.23 feet 01/26/22 06:48 Specific Conductance 71.1 umhos/cm 01/26/22 06:48 Oxidation Potential 18.6 mV 01/26/22 06:48 Oxygen, Dissolved 1.90 mg/L 01/26/22 06:48 Total Well Depth 108.40 feet 01/26/22 06:48 Turbidity 0.46 NTU 01/26/22 06:48 EPA 6020B Barium 86.9J ug/L 100 02/02/22 16:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual 92584821 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584821012 1403-Field Blank EPA 6020B Antimony 2.OJ ug/L 6.0 02/02/22 16:25 92584821013 1403-SW1 Performed by ES&S 01/25/22 13:58 pH 6.56 Std. Units 01/25/22 13:58 Temperature 11.1 deg C 01/25/22 13:58 Specific Conductance 79.2 umhos/cm 01/25/22 13:58 Oxidation Potential 20.2 mV 01/25/22 13:58 Oxygen, Dissolved 4.02 mg/L 01/25/22 13:58 Turbidity 3.98 NTU 01/25/22 13:58 EPA 6020B Barium 25.6J ug/L 100 02/02/22 16:31 EPA 6020B Cobalt 1.1 J ug/L 10.0 02/02/22 16:31 EPA 6020B Copper 6AJ ug/L 10.0 02/02/22 16:31 EPA 6020B Vanadium 2.8J ug/L 25.0 02/02/22 16:31 EPA 6020B Zinc 10.1 ug/L 10.0 02/02/22 16:31 92584821014 1403-SW2 Performed by ES&S 01/25/22 15:04 pH 6.66 Std. Units 01/25/22 15:04 Temperature 11.4 deg C 01/25/22 15:04 Specific Conductance 98.5 umhos/cm 01/25/22 15:04 Oxidation Potential 24.7 mV 01/25/22 15:04 Oxygen, Dissolved 3.92 mg/L 01/25/22 15:04 Turbidity 3.26 NTU 01/25/22 15:04 EPA 6020B Barium 26.1 J ug/L 100 02/02/22 16:37 EPA 6020B Cobalt 1.3J ug/L 10.0 02/02/22 16:37 EPA 6020B Vanadium 2.2J ug/L 25.0 02/02/22 16:37 92584821015 1403-SW3 Performed by ES&S 01/25/22 16:18 pH 7.87 Std. Units 01/25/22 16:18 Temperature 10.2 deg C 01/25/22 16:18 Specific Conductance 67.2 umhos/cm 01/25/22 16:18 Oxidation Potential -37.3 mV 01/25/22 16:18 Turbidity 2.92 NTU 01/25/22 16:18 EPA 6020B Barium 21 AJ ug/L 100 02/02/22 16:43 EPA 6020B Chromium 1.6J ug/L 10.0 02/02/22 16:43 EPA 6020B Cobalt 0.45J ug/L 10.0 02/02/22 16:43 EPA 6020B Copper 0.68J ug/L 10.0 02/02/22 16:43 EPA 6020B Vanadium 2.1 J ug/L 25.0 02/02/22 16:43 92584821016 1403-SW4 Performed by ES&S 01/25/22 15:52 pH 7.65 Std. Units 01/25/22 15:52 Temperature 10.0 deg C 01/25/22 15:52 Specific Conductance 69.8 umhos/cm 01/25/22 15:52 Oxidation Potential -25.7 mV 01/25/22 15:52 Turbidity 2.38 NTU 01/25/22 15:52 EPA 6020B Barium 24.1 J ug/L 100 02/02/22 17:09 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual 92584821 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584821016 1403-SW4 EPA 6020B Cobalt 0.42J ug/L 10.0 02/02/22 17:09 EPA 6020B Copper 0.591 ug/L 10.0 02/02/22 17:09 92584821017 1403-SW5 Performed by ES&S 01/25/22 15:28 pH 7.35 Std. Units 01/25/22 15:28 Temperature 10.2 deg C 01/25/22 15:28 Specific Conductance 136.2 umhos/cm 01/25/22 15:28 Oxidation Potential -13.8 mV 01/25/22 15:28 Oxygen, Dissolved 3.60 mg/L 01/25/22 15:28 Turbidity 5.49 NTU 01/25/22 15:28 EPA 6020B Arsenic 1.5J ug/L 10.0 02/02/22 17:15 EPA 6020B Barium 25.2J ug/L 100 02/02/22 17:15 EPA 6020B Cobalt 1.1 J ug/L 10.0 02/02/22 17:15 EPA 6020B Vanadium 3.1 J ug/L 25.0 02/02/22 17:15 EPA 6020B Zinc 11.4 ug/L 10.0 02/02/22 17:15 92584821018 1403-UD1 Performed by ES&S 01/25/22 14:45 pH 5.94 Std. Units 01/25/22 14:45 Temperature 18.1 deg C 01/25/22 14:45 Specific Conductance 252 umhos/cm 01/25/22 14:45 Oxidation Potential 63.1 mV 01/25/22 14:45 Oxygen, Dissolved 3.70 mg/L 01/25/22 14:45 Turbidity 4.28 NTU 01/25/22 14:45 EPA 6020B Arsenic 2.1 J ug/L 10.0 02/02/22 17:21 EPA 6020B Barium 68.1 J ug/L 100 02/02/22 17:21 EPA 6020B Beryllium 0.074J ug/L 1.0 02/02/22 17:21 EPA 6020B Cobalt 6.5J ug/L 10.0 02/02/22 17:21 EPA 6020B Nickel 1 AJ ug/L 50.0 02/02/22 17:21 EPA 6020B Vanadium 4.3J ug/L 25.0 02/02/22 17:21 EPA 6020B Zinc 9.6J ug/L 10.0 02/02/22 17:21 92584821019 1403-U D2 Performed by ES&S 01/25/22 14:24 pH 6.52 Std. Units 01/25/22 14:24 Temperature 10.6 deg C 01/25/22 14:24 Specific Conductance 182.6 umhos/cm 01/25/22 14:24 Oxidation Potential 44.6 mV 01/25/22 14:24 Oxygen, Dissolved 3.58 mg/L 01/25/22 14:24 Turbidity 2.95 NTU 01/25/22 14:24 EPA 6020B Arsenic 2.OJ ug/L 10.0 02/02/22 17:27 EPA 6020B Barium 80.OJ ug/L 100 02/02/22 17:27 EPA 6020B Beryllium 0.085J ug/L 1.0 02/02/22 17:27 EPA 6020B Cobalt 7.9J ug/L 10.0 02/02/22 17:27 EPA 6020B Nickel 1.3J ug/L 50.0 02/02/22 17:27 EPA 6020B Vanadium 3.OJ ug/L 25.0 02/02/22 17:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-1R2 Lab ID: 92584821001 Collected: 01/26/22 15:52 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 15:52 pH 6.44 Std. Units 1 01/26/22 15:52 Temperature 12.1 deg C 1 01/26/22 15:52 Static Water Level 22.45 feet 1 01/26/22 15:52 Specific Conductance 80.1 umhos/c 1 01/26/22 15:52 m Oxidation Potential 40.2 mV 1 01/26/22 15:52 Oxygen, Dissolved 1.85 mg/L 1 01/26/22 15:52 7782-44-7 Total Well Depth 43.34 feet 1 01/26/22 15:52 Turbidity 0.89 NTU 1 01/26/22 15:52 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2214:42 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2214:42 7440-38-2 Barium 70.9J ug/L 100 0.67 1 02/01/2210:55 02/02/2214:42 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2214:42 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2214:42 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2214:42 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2214:42 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2214:42 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2214:42 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2214:42 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2214:42 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2214:42 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2214:42 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2214:42 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2214:42 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 01:26 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 01:26 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 01:26 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 01:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 01:26 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 01:26 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 01:26 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 01:26 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 01:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 01:26 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 01:26 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 01:26 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 01:26 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 01:26 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-1R2 Lab ID: 92584821001 Collected: 01/26/22 15:52 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 100 % 70-130 102 % 70-130 102 % 70-130 1 01/29/22 01:26 96-12-8 1 01/29/22 01:26 124-48-1 1 01/29/22 01:26 106-93-4 1 01/29/22 01:26 74-95-3 1 01/29/22 01:26 95-50-1 1 01/29/22 01:26 106-46-7 1 01/29/22 01:26 110-57-6 1 01/29/22 01:26 75-34-3 1 01/29/22 01:26 107-06-2 1 01/29/22 01:26 75-35-4 1 01/29/22 01:26 156-59-2 1 01/29/22 01:26 156-60-5 1 01/29/22 01:26 78-87-5 1 01/29/22 01:26 10061-01-5 1 01/29/22 01:26 10061-02-6 1 01/29/22 01:26 100-41-4 1 01/29/22 01:26 591-78-6 1 01/29/22 01:26 74-88-4 1 01/29/22 01:26 75-09-2 1 01/29/22 01:26 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 01:26 100-42-5 01/29/22 01:26 630-20-6 01/29/22 01:26 79-34-5 01/29/22 01:26 127-18-4 01/29/22 01:26 108-88-3 01/29/22 01:26 71-55-6 01/29/22 01:26 79-00-5 01/29/22 01:26 79-01-6 01/29/22 01:26 75-69-4 01/29/22 01:26 96-18-4 01/29/22 01:26 108-05-4 01/29/22 01:26 75-01-4 01/29/22 01:26 1330-20-7 01/29/22 01:26 460-00-4 01/29/22 01:26 17060-07-0 01/29/22 01:26 2037-26-5 Page 12 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-3R2 Lab ID: 92584821002 Collected: 01/26/22 13:42 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 13:42 pH 7.90 Std. Units 1 01/26/22 13:42 Temperature 14.5 deg C 1 01/26/22 13:42 Static Water Level 42.43 feet 1 01/26/22 13:42 Specific Conductance 265 umhos/c 1 01/26/22 13:42 m Oxidation Potential -28.2 mV 1 01/26/22 13:42 Oxygen, Dissolved 3.15 mg/L 1 01/26/22 13:42 7782-44-7 Total Well Depth 73.91 feet 1 01/26/22 13:42 Turbidity 0.65 NTU 1 01/26/22 13:42 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2214:48 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2214:48 7440-38-2 Barium 4.1J ug/L 100 0.67 1 02/01/2210:55 02/02/2214:48 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2214:48 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2214:48 7440-43-9 Chromium 1.5J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2214:48 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2214:48 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2214:48 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2214:48 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2214:48 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2214:48 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2214:48 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2214:48 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2214:48 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2214:48 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 04:46 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 04:46 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 04:46 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 04:46 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 04:46 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 04:46 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 04:46 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 04:46 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 04:46 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 04:46 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 04:46 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 04:46 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 04:46 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 04:46 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-3R2 Lab ID: 92584821002 Collected: 01/26/22 13:42 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 97 % 70-130 102 % 70-130 103 % 70-130 1 01/29/22 04:46 96-12-8 1 01/29/22 04:46 124-48-1 1 01/29/22 04:46 106-93-4 1 01/29/22 04:46 74-95-3 1 01/29/22 04:46 95-50-1 1 01/29/22 04:46 106-46-7 1 01/29/22 04:46 110-57-6 1 01/29/22 04:46 75-34-3 1 01/29/22 04:46 107-06-2 1 01/29/22 04:46 75-35-4 1 01/29/22 04:46 156-59-2 1 01/29/22 04:46 156-60-5 1 01/29/22 04:46 78-87-5 1 01/29/22 04:46 10061-01-5 1 01/29/22 04:46 10061-02-6 1 01/29/22 04:46 100-41-4 1 01/29/22 04:46 591-78-6 1 01/29/22 04:46 74-88-4 1 01/29/22 04:46 75-09-2 1 01/29/22 04:46 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 04:46 100-42-5 01/29/22 04:46 630-20-6 01/29/22 04:46 79-34-5 01/29/22 04:46 127-18-4 01/29/22 04:46 108-88-3 01/29/22 04:46 71-55-6 01/29/22 04:46 79-00-5 01/29/22 04:46 79-01-6 01/29/22 04:46 75-69-4 01/29/22 04:46 96-18-4 01/29/22 04:46 108-05-4 01/29/22 04:46 75-01-4 01/29/22 04:46 1330-20-7 01/29/22 04:46 460-00-4 01/29/22 04:46 17060-07-0 01/29/22 04:46 2037-26-5 Page 14 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-4 Lab ID: 92584821003 Collected: 01/26/22 12:47 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 12:47 pH 5.31 Std. Units 1 01/26/22 12:47 Temperature 16.2 deg C 1 01/26/22 12:47 Static Water Level 41.80 feet 1 01/26/22 12:47 Specific Conductance 46.3 umhos/c 1 01/26/22 12:47 m Oxidation Potential 95.7 mV 1 01/26/22 12:47 Oxygen, Dissolved 1.70 mg/L 1 01/26/22 12:47 7782-44-7 Total Well Depth 52.20 feet 1 01/26/22 12:47 Turbidity 0.50 NTU 1 01/26/22 12:47 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2214:54 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2214:54 7440-38-2 Barium 62.4J ug/L 100 0.67 1 02/01/2210:55 02/02/2214:54 7440-39-3 Beryllium 0.086J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2214:54 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2214:54 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2214:54 7440-47-3 Cobalt 13.6 ug/L 10.0 0.39 1 02/01/2210:55 02/02/2214:54 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2214:54 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2214:54 7439-92-1 Nickel 0.79J ug/L 50.0 0.71 1 02/01/2210:55 02/02/2214:54 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2214:54 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2214:54 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2214:54 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2214:54 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2214:54 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 01:44 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 01:44 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 01:44 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 01:44 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 01:44 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 01:44 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 01:44 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 01:44 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 01:44 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 01:44 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 01:44 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 01:44 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 01:44 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 01:44 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-4 Lab ID: 92584821003 Collected: 01/26/22 12:47 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 98 % 70-130 100 % 70-130 103 % 70-130 1 01/29/22 01:44 96-12-8 1 01/29/22 01:44 124-48-1 1 01/29/22 01:44 106-93-4 1 01/29/22 01:44 74-95-3 1 01/29/22 01:44 95-50-1 1 01/29/22 01:44 106-46-7 1 01/29/22 01:44 110-57-6 1 01/29/22 01:44 75-34-3 1 01/29/22 01:44 107-06-2 1 01/29/22 01:44 75-35-4 1 01/29/22 01:44 156-59-2 1 01/29/22 01:44 156-60-5 1 01/29/22 01:44 78-87-5 1 01/29/22 01:44 10061-01-5 1 01/29/22 01:44 10061-02-6 1 01/29/22 01:44 100-41-4 1 01/29/22 01:44 591-78-6 1 01/29/22 01:44 74-88-4 1 01/29/22 01:44 75-09-2 1 01/29/22 01:44 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 01:44 100-42-5 01/29/22 01:44 630-20-6 01/29/22 01:44 79-34-5 01/29/22 01:44 127-18-4 01/29/22 01:44 108-88-3 01/29/22 01:44 71-55-6 01/29/22 01:44 79-00-5 01/29/22 01:44 79-01-6 01/29/22 01:44 75-69-4 01/29/22 01:44 96-18-4 01/29/22 01:44 108-05-4 01/29/22 01:44 75-01-4 01/29/22 01:44 1330-20-7 01/29/22 01:44 460-00-4 01/29/22 01:44 17060-07-0 01/29/22 01:44 2037-26-5 Page 16 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-DUP@MW-4 Lab ID: 92584821004 Collected: 01/26/22 12:49 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:00 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:00 7440-38-2 Barium 67.6J ug/L 100 0.67 1 02/01/2210:55 02/02/2215:00 7440-39-3 Beryllium 0.096J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:00 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:00 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:00 7440-47-3 Cobalt 14.6 ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:00 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:00 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:00 7439-92-1 Nickel 0.76J ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:00 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:00 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:00 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:00 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:00 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:00 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 05:04 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 05:04 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 05:04 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 05:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 05:04 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 05:04 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 05:04 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 05:04 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 05:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 05:04 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 05:04 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 05:04 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 05:04 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 05:04 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 05:04 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.36 1 01/29/22 05:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.27 1 01/29/22 05:04 106-93-4 Dibromomethane ND ug/L 10.0 0.39 1 01/29/22 05:04 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.34 1 01/29/22 05:04 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/29/22 05:04 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.56 1 01/29/22 05:04 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.37 1 01/29/22 05:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 01/29/22 05:04 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.35 1 01/29/22 05:04 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.38 1 01/29/22 05:04 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-DUP@MW-4 Lab ID: 92584821004 Collected: 01/26/22 12:49 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.40 1 01/29/22 05:04 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 05:04 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 05:04 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 05:04 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 05:04 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 05:04 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 05:04 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 05:04 75-09-2 ND ug/L 100 2.7 1 01/29/22 05:04 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 05:04 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 05:04 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 05:04 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 05:04 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 05:04 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 05:04 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 05:04 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 05:04 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 05:04 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 05:04 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 05:04 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 05:04 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 05:04 1330-20-7 99 % 70-130 1 01/29/22 05:04 460-00-4 103 % 70-130 1 01/29/22 05:04 17060-07-0 103 % 70-130 1 01/29/22 05:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-5 Lab ID: 92584821005 Collected: 01/26/22 11:57 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 11:57 pH 5.83 Std. Units 1 01/26/22 11:57 Temperature 15.4 deg C 1 01/26/22 11:57 Static Water Level 47.51 feet 1 01/26/22 11:57 Specific Conductance 233 umhos/c 1 01/26/22 11:57 m Oxidation Potential 68.2 mV 1 01/26/22 11:57 Oxygen, Dissolved 2.32 mg/L 1 01/26/22 11:57 7782-44-7 Total Well Depth 54.50 feet 1 01/26/22 11:57 Turbidity 0.57 NTU 1 01/26/22 11:57 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:06 7440-36-0 Arsenic 1.3J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:06 7440-38-2 Barium 152 ug/L 100 0.67 1 02/01/2210:55 02/02/2215:06 7440-39-3 Beryllium 0.093J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:06 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:06 7440-43-9 Chromium 1.5J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:06 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:06 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:06 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:06 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:06 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:06 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:06 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:06 7440-28-0 Vanadium 4.1J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:06 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:06 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 05:22 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 05:22 107-13-1 Benzene 0.77J ug/L 1.0 0.34 1 01/29/22 05:22 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 05:22 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 05:22 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 05:22 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 05:22 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 05:22 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 05:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 05:22 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 05:22 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 05:22 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 05:22 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 05:22 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-5 Lab ID: 92584821005 Collected: 01/26/22 11:57 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 1 01/29/22 05:22 96-12-8 ND ug/L 3.0 0.36 1 01/29/22 05:22 124-48-1 ND ug/L 2.0 0.27 1 01/29/22 05:22 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 05:22 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 05:22 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 05:22 106-46-7 ND ug/L 100 0.56 1 01/29/22 05:22 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 05:22 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 05:22 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 05:22 75-35-4 2.2J ug/L 5.0 0.38 1 01/29/22 05:22 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 05:22 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 05:22 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 05:22 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 05:22 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 05:22 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 05:22 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 05:22 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 05:22 75-09-2 ND ug/L 100 2.7 1 01/29/22 05:22 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 05:22 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 05:22 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 05:22 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 05:22 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 05:22 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 05:22 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 05:22 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 05:22 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 05:22 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 05:22 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 05:22 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 05:22 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 05:22 1330-20-7 99 % 70-130 1 01/29/22 05:22 460-00-4 101 % 70-130 1 01/29/22 05:22 17060-07-0 103 % 70-130 1 01/29/22 05:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 20 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-6 Lab ID: 92584821006 Collected: 01/26/22 11:07 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 11:07 pH 5.57 Std. Units 1 01/26/22 11:07 Temperature 14.8 deg C 1 01/26/22 11:07 Static Water Level 43.30 feet 1 01/26/22 11:07 Specific Conductance 155.2 umhos/c 1 01/26/22 11:07 m Oxidation Potential 81.7 mV 1 01/26/22 11:07 Oxygen, Dissolved 2.26 mg/L 1 01/26/22 11:07 7782-44-7 Total Well Depth 50.55 feet 1 01/26/22 11:07 Turbidity 2.62 NTU 1 01/26/22 11:07 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:12 7440-36-0 Arsenic 1.4J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:12 7440-38-2 Barium 121 ug/L 100 0.67 1 02/01/2210:55 02/02/2215:12 7440-39-3 Beryllium 0.37J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:12 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:12 7440-43-9 Chromium 1.5J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:12 7440-47-3 Cobalt 3.7J ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:12 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:12 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:12 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:12 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:12 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:12 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:12 7440-28-0 Vanadium 2.4J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:12 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:12 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 02:02 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 02:02 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 02:02 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 02:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 02:02 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 02:02 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 02:02 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 02:02 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 02:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 02:02 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 02:02 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 02:02 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 02:02 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 02:02 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-6 Lab ID: 92584821006 Collected: 01/26/22 11:07 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 100 % 70-130 101 % 70-130 104 % 70-130 1 01/29/22 02:02 96-12-8 1 01/29/22 02:02 124-48-1 1 01/29/22 02:02 106-93-4 1 01/29/22 02:02 74-95-3 1 01/29/22 02:02 95-50-1 1 01/29/22 02:02 106-46-7 1 01/29/22 02:02 110-57-6 1 01/29/22 02:02 75-34-3 1 01/29/22 02:02 107-06-2 1 01/29/22 02:02 75-35-4 1 01/29/22 02:02 156-59-2 1 01/29/22 02:02 156-60-5 1 01/29/22 02:02 78-87-5 1 01/29/22 02:02 10061-01-5 1 01/29/22 02:02 10061-02-6 1 01/29/22 02:02 100-41-4 1 01/29/22 02:02 591-78-6 1 01/29/22 02:02 74-88-4 1 01/29/22 02:02 75-09-2 1 01/29/22 02:02 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 02:02 100-42-5 01/29/22 02:02 630-20-6 01/29/22 02:02 79-34-5 01/29/22 02:02 127-18-4 01/29/22 02:02 108-88-3 01/29/22 02:02 71-55-6 01/29/22 02:02 79-00-5 01/29/22 02:02 79-01-6 01/29/22 02:02 75-69-4 01/29/22 02:02 96-18-4 01/29/22 02:02 108-05-4 01/29/22 02:02 75-01-4 01/29/22 02:02 1330-20-7 01/29/22 02:02 460-00-4 01/29/22 02:02 17060-07-0 01/29/22 02:02 2037-26-5 Page 22 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-7 Lab ID: 92584821007 Collected: 01/26/22 10:17 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 10:17 pH 5.56 Std. Units 1 01/26/22 10:17 Temperature 12.3 deg C 1 01/26/22 10:17 Static Water Level 32.12 feet 1 01/26/22 10:17 Specific Conductance 364 umhos/c 1 01/26/22 10:17 m Oxidation Potential 81.2 mV 1 01/26/22 10:17 Oxygen, Dissolved 4.62 mg/L 1 01/26/22 10:17 7782-44-7 Total Well Depth 40.13 feet 1 01/26/22 10:17 Turbidity 3.08 NTU 1 01/26/22 10:17 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:18 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:18 7440-38-2 Barium 101 ug/L 100 0.67 1 02/01/2210:55 02/02/2215:18 7440-39-3 Beryllium 0.18J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:18 7440-41-7 Cadmium 0.18J ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:18 7440-43-9 Chromium 1.2J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:18 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:18 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:18 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:18 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:18 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:18 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:18 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:18 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:18 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:18 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 02:20 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 02:20 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 02:20 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 02:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 02:20 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 02:20 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 02:20 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 02:20 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 02:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 02:20 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 02:20 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 02:20 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 02:20 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 02:20 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-7 Lab ID: 92584821007 Collected: 01/26/22 10:17 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 99 % 70-130 104 % 70-130 104 % 70-130 1 01/29/22 02:20 96-12-8 1 01/29/22 02:20 124-48-1 1 01/29/22 02:20 106-93-4 1 01/29/22 02:20 74-95-3 1 01/29/22 02:20 95-50-1 1 01/29/22 02:20 106-46-7 1 01/29/22 02:20 110-57-6 1 01/29/22 02:20 75-34-3 1 01/29/22 02:20 107-06-2 1 01/29/22 02:20 75-35-4 1 01/29/22 02:20 156-59-2 1 01/29/22 02:20 156-60-5 1 01/29/22 02:20 78-87-5 1 01/29/22 02:20 10061-01-5 1 01/29/22 02:20 10061-02-6 1 01/29/22 02:20 100-41-4 1 01/29/22 02:20 591-78-6 1 01/29/22 02:20 74-88-4 1 01/29/22 02:20 75-09-2 1 01/29/22 02:20 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 02:20 100-42-5 01/29/22 02:20 630-20-6 01/29/22 02:20 79-34-5 01/29/22 02:20 127-18-4 01/29/22 02:20 108-88-3 01/29/22 02:20 71-55-6 01/29/22 02:20 79-00-5 01/29/22 02:20 79-01-6 01/29/22 02:20 75-69-4 01/29/22 02:20 96-18-4 01/29/22 02:20 108-05-4 01/29/22 02:20 75-01-4 01/29/22 02:20 1330-20-7 01/29/22 02:20 460-00-4 01/29/22 02:20 17060-07-0 01/29/22 02:20 2037-26-5 Page 24 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-8 Lab ID: 92584821008 Collected: 01/26/22 09:26 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 09:26 pH 5.85 Std. Units 1 01/26/22 09:26 Temperature 12.2 deg C 1 01/26/22 09:26 Static Water Level 30.92 feet 1 01/26/22 09:26 Specific Conductance 96.8 umhos/c 1 01/26/22 09:26 m Oxidation Potential 66.1 mV 1 01/26/22 09:26 Oxygen, Dissolved 2.42 mg/L 1 01/26/22 09:26 7782-44-7 Total Well Depth 49.56 feet 1 01/26/22 09:26 Turbidity 2.40 NTU 1 01/26/22 09:26 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:24 7440-36-0 Arsenic 1.4J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:24 7440-38-2 Barium 45.9J ug/L 100 0.67 1 02/01/2210:55 02/02/2215:24 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:24 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:24 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:24 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:24 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:24 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:24 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:24 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:24 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:24 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:24 7440-28-0 Vanadium 2.OJ ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:24 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:24 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 02:38 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 02:38 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 02:38 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 02:38 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 02:38 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 02:38 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 02:38 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 02:38 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 02:38 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 02:38 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 02:38 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 02:38 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 02:38 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 02:38 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-8 Lab ID: 92584821008 Collected: 01/26/22 09:26 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 99 % 70-130 103 % 70-130 103 % 70-130 1 01/29/22 02:38 96-12-8 1 01/29/22 02:38 124-48-1 1 01/29/22 02:38 106-93-4 1 01/29/22 02:38 74-95-3 1 01/29/22 02:38 95-50-1 1 01/29/22 02:38 106-46-7 1 01/29/22 02:38 110-57-6 1 01/29/22 02:38 75-34-3 1 01/29/22 02:38 107-06-2 1 01/29/22 02:38 75-35-4 1 01/29/22 02:38 156-59-2 1 01/29/22 02:38 156-60-5 1 01/29/22 02:38 78-87-5 1 01/29/22 02:38 10061-01-5 1 01/29/22 02:38 10061-02-6 1 01/29/22 02:38 100-41-4 1 01/29/22 02:38 591-78-6 1 01/29/22 02:38 74-88-4 1 01/29/22 02:38 75-09-2 1 01/29/22 02:38 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 02:38 100-42-5 01/29/22 02:38 630-20-6 01/29/22 02:38 79-34-5 01/29/22 02:38 127-18-4 01/29/22 02:38 108-88-3 01/29/22 02:38 71-55-6 01/29/22 02:38 79-00-5 01/29/22 02:38 79-01-6 01/29/22 02:38 75-69-4 01/29/22 02:38 96-18-4 01/29/22 02:38 108-05-4 01/29/22 02:38 75-01-4 01/29/22 02:38 1330-20-7 01/29/22 02:38 460-00-4 01/29/22 02:38 17060-07-0 01/29/22 02:38 2037-26-5 Page 26 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-9 Lab ID: 92584821009 Collected: 01/26/22 08:31 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 08:31 pH 5.98 Std. Units 1 01/26/22 08:31 Temperature 14.0 deg C 1 01/26/22 08:31 Static Water Level 69.25 feet 1 01/26/22 08:31 Specific Conductance 196.1 umhos/c 1 01/26/22 08:31 m Oxidation Potential 60.0 mV 1 01/26/22 08:31 Oxygen, Dissolved 3.35 mg/L 1 01/26/22 08:31 7782-44-7 Total Well Depth 73.40 feet 1 01/26/22 08:31 Turbidity 0.38 NTU 1 01/26/22 08:31 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 0.84J ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:49 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:49 7440-38-2 Barium 9.OJ ug/L 100 0.67 1 02/01/2210:55 02/02/2215:49 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:49 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:49 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:49 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:49 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:49 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:49 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:49 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:49 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:49 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:49 7440-28-0 Vanadium 2.OJ ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:49 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:49 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 02:57 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 02:57 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 02:57 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 02:57 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 02:57 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 02:57 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 02:57 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 02:57 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 02:57 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 02:57 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 02:57 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 02:57 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 02:57 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 02:57 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-9 Lab ID: 92584821009 Collected: 01/26/22 08:31 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 97 % 70-130 99 % 70-130 104 % 70-130 1 01/29/22 02:57 96-12-8 1 01/29/22 02:57 124-48-1 1 01/29/22 02:57 106-93-4 1 01/29/22 02:57 74-95-3 1 01/29/22 02:57 95-50-1 1 01/29/22 02:57 106-46-7 1 01/29/22 02:57 110-57-6 1 01/29/22 02:57 75-34-3 1 01/29/22 02:57 107-06-2 1 01/29/22 02:57 75-35-4 1 01/29/22 02:57 156-59-2 1 01/29/22 02:57 156-60-5 1 01/29/22 02:57 78-87-5 1 01/29/22 02:57 10061-01-5 1 01/29/22 02:57 10061-02-6 1 01/29/22 02:57 100-41-4 1 01/29/22 02:57 591-78-6 1 01/29/22 02:57 74-88-4 1 01/29/22 02:57 75-09-2 1 01/29/22 02:57 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 02:57 100-42-5 01/29/22 02:57 630-20-6 01/29/22 02:57 79-34-5 01/29/22 02:57 127-18-4 01/29/22 02:57 108-88-3 01/29/22 02:57 71-55-6 01/29/22 02:57 79-00-5 01/29/22 02:57 79-01-6 01/29/22 02:57 75-69-4 01/29/22 02:57 96-18-4 01/29/22 02:57 108-05-4 01/29/22 02:57 75-01-4 01/29/22 02:57 1330-20-7 01/29/22 02:57 460-00-4 01/29/22 02:57 17060-07-0 01/29/22 02:57 2037-26-5 Page 28 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-10 Lab ID: 92584821010 Collected: 01/26/22 07:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 07:41 pH 6.54 Std. Units 1 01/26/22 07:41 Temperature 12.5 deg C 1 01/26/22 07:41 Static Water Level 76.46 feet 1 01/26/22 07:41 Specific Conductance 63.9 umhos/c 1 01/26/22 07:41 m Oxidation Potential 31.6 mV 1 01/26/22 07:41 Oxygen, Dissolved 5.15 mg/L 1 01/26/22 07:41 7782-44-7 Total Well Depth 88.21 feet 1 01/26/22 07:41 Turbidity 0.86 NTU 1 01/26/22 07:41 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2215:55 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:55 7440-38-2 Barium 25.1J ug/L 100 0.67 1 02/01/2210:55 02/02/2215:55 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2215:55 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2215:55 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2215:55 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2215:55 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2215:55 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2215:55 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2215:55 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2215:55 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2215:55 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2215:55 7440-28-0 Vanadium 3.3J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2215:55 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2215:55 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 03:15 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 03:15 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 03:15 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 03:15 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 03:15 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 03:15 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 03:15 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 03:15 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 03:15 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 03:15 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 03:15 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 03:15 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 03:15 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 03:15 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-10 Lab ID: 92584821010 Collected: 01/26/22 07:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 98 % 70-130 99 % 70-130 104 % 70-130 1 01/29/22 03:15 96-12-8 1 01/29/22 03:15 124-48-1 1 01/29/22 03:15 106-93-4 1 01/29/22 03:15 74-95-3 1 01/29/22 03:15 95-50-1 1 01/29/22 03:15 106-46-7 1 01/29/22 03:15 110-57-6 1 01/29/22 03:15 75-34-3 1 01/29/22 03:15 107-06-2 1 01/29/22 03:15 75-35-4 1 01/29/22 03:15 156-59-2 1 01/29/22 03:15 156-60-5 1 01/29/22 03:15 78-87-5 1 01/29/22 03:15 10061-01-5 1 01/29/22 03:15 10061-02-6 1 01/29/22 03:15 100-41-4 1 01/29/22 03:15 591-78-6 1 01/29/22 03:15 74-88-4 1 01/29/22 03:15 75-09-2 1 01/29/22 03:15 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 03:15 100-42-5 01/29/22 03:15 630-20-6 01/29/22 03:15 79-34-5 01/29/22 03:15 127-18-4 01/29/22 03:15 108-88-3 01/29/22 03:15 71-55-6 01/29/22 03:15 79-00-5 01/29/22 03:15 79-01-6 01/29/22 03:15 75-69-4 01/29/22 03:15 96-18-4 01/29/22 03:15 108-05-4 01/29/22 03:15 75-01-4 01/29/22 03:15 1330-20-7 01/29/22 03:15 460-00-4 01/29/22 03:15 17060-07-0 01/29/22 03:15 2037-26-5 Page 30 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-11 Lab ID: 92584821011 Collected: 01/26/22 06:48 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 06:48 pH 6.78 Std. Units 1 01/26/22 06:48 Temperature 11.3 deg C 1 01/26/22 06:48 Static Water Level 83.23 feet 1 01/26/22 06:48 Specific Conductance 71.1 umhos/c 1 01/26/22 06:48 m Oxidation Potential 18.6 mV 1 01/26/22 06:48 Oxygen, Dissolved 1.90 mg/L 1 01/26/22 06:48 7782-44-7 Total Well Depth 108.40 feet 1 01/26/22 06:48 Turbidity 0.46 NTU 1 01/26/22 06:48 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2216:01 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:01 7440-38-2 Barium 86.9J ug/L 100 0.67 1 02/01/2210:55 02/02/2216:01 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2216:01 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2216:01 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:01 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2216:01 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2216:01 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2216:01 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2216:01 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2216:01 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2216:01 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2216:01 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2216:01 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2216:01 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 05:41 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 05:41 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 05:41 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 05:41 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 05:41 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 05:41 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 05:41 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 05:41 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 05:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 05:41 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 05:41 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 05:41 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 05:41 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 05:41 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-MW-11 Lab ID: 92584821011 Collected: 01/26/22 06:48 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 13.0 0.34 ND ug/L 3.0 0.36 ND ug/L 2.0 0.27 ND ug/L 10.0 0.39 ND ug/L 5.0 0.34 ND ug/L 1.0 0.33 ND ug/L 100 0.56 ND ug/L 5.0 0.37 ND ug/L 1.0 0.32 ND ug/L 5.0 0.35 ND ug/L 5.0 0.38 ND ug/L 5.0 0.40 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.36 ND ug/L 1.0 0.30 ND ug/L 50.0 0.48 ND ug/L 20.0 9.7 ND ug/L 5.0 2.0 ND ug/L 100 2.7 ND ug/L 1.0 0.29 ND ug/L 5.0 0.31 ND ug/L 3.0 0.22 ND ug/L 1.0 0.29 ND ug/L 1.0 0.48 ND ug/L 1.0 0.33 ND ug/L 1.0 0.32 ND ug/L 1.0 0.38 ND ug/L 1.0 0.30 ND ug/L 1.0 0.26 ND ug/L 50.0 1.3 ND ug/L 1.0 0.39 ND ug/L 5.0 0.34 98 % 70-130 101 % 70-130 103 % 70-130 1 01/29/22 05:41 96-12-8 1 01/29/22 05:41 124-48-1 1 01/29/22 05:41 106-93-4 1 01/29/22 05:41 74-95-3 1 01/29/22 05:41 95-50-1 1 01/29/22 05:41 106-46-7 1 01/29/22 05:41 110-57-6 1 01/29/22 05:41 75-34-3 1 01/29/22 05:41 107-06-2 1 01/29/22 05:41 75-35-4 1 01/29/22 05:41 156-59-2 1 01/29/22 05:41 156-60-5 1 01/29/22 05:41 78-87-5 1 01/29/22 05:41 10061-01-5 1 01/29/22 05:41 10061-02-6 1 01/29/22 05:41 100-41-4 1 01/29/22 05:41 591-78-6 1 01/29/22 05:41 74-88-4 1 01/29/22 05:41 75-09-2 1 01/29/22 05:41 108-10-1 1 1 1 1 1 1 1 1 1 1 1 1 1 I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/29/22 05:41 100-42-5 01/29/22 05:41 630-20-6 01/29/22 05:41 79-34-5 01/29/22 05:41 127-18-4 01/29/22 05:41 108-88-3 01/29/22 05:41 71-55-6 01/29/22 05:41 79-00-5 01/29/22 05:41 79-01-6 01/29/22 05:41 75-69-4 01/29/22 05:41 96-18-4 01/29/22 05:41 108-05-4 01/29/22 05:41 75-01-4 01/29/22 05:41 1330-20-7 01/29/22 05:41 460-00-4 01/29/22 05:41 17060-07-0 01/29/22 05:41 2037-26-5 Page 32 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-Field Blank Lab ID: 92584821012 Collected: 01/25/22 13:50 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 2.OJ ug/L 6.0 0.78 1 02/01/2210:55 02/02/2216:25 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:25 7440-38-2 Barium ND ug/L 100 0.67 1 02/01/2210:55 02/02/2216:25 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2216:25 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2216:25 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:25 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/2210:55 02/02/2216:25 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2216:25 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2216:25 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2216:25 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2216:25 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2216:25 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2216:25 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/2216:25 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2216:25 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 01:07 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 01:07 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 01:07 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 01:07 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 01:07 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 01:07 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 01:07 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 01:07 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 01:07 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 01:07 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 01:07 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 01:07 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 01:07 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 01:07 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 01:07 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.36 1 01/29/22 01:07 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.27 1 01/29/22 01:07 106-93-4 Dibromomethane ND ug/L 10.0 0.39 1 01/29/22 01:07 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.34 1 01/29/22 01:07 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/29/22 01:07 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 0.56 1 01/29/22 01:07 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.37 1 01/29/22 01:07 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 01/29/22 01:07 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.35 1 01/29/22 01:07 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.38 1 01/29/22 01:07 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-Field Blank Lab ID: 92584821012 Collected: 01/25/22 13:50 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 0.40 1 01/29/22 01:07 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 01:07 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 01:07 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 01:07 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 01:07 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 01:07 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 01:07 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 01:07 75-09-2 ND ug/L 100 2.7 1 01/29/22 01:07 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 01:07 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 01:07 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 01:07 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 01:07 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 01:07 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 01:07 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 01:07 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 01:07 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 01:07 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 01:07 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 01:07 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 01:07 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 01:07 1330-20-7 98 % 70-130 1 01/29/22 01:07 460-00-4 102 % 70-130 1 01/29/22 01:07 17060-07-0 104 % 70-130 1 01/29/22 01:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW1 Lab ID: 92584821013 Collected: 01/25/22 13:58 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/25/22 13:58 pH 6.56 Std. Units 1 01/25/22 13:58 Temperature 11.1 deg C 1 01/25/22 13:58 Specific Conductance 79.2 umhos/c 1 01/25/22 13:58 m Oxidation Potential 20.2 mV 1 01/25/22 13:58 Oxygen, Dissolved 4.02 mg/L 1 01/25/22 13:58 7782-44-7 Turbidity 3.98 NTU 1 01/25/22 13:58 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2216:31 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:31 7440-38-2 Barium 25.6J ug/L 100 0.67 1 02/01/2210:55 02/02/2216:31 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2216:31 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2216:31 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:31 7440-47-3 Cobalt 1.1J ug/L 10.0 0.39 1 02/01/2210:55 02/02/2216:31 7440-48-4 Copper 6.4J ug/L 10.0 0.50 1 02/01/2210:55 02/02/2216:31 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2216:31 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2216:31 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2216:31 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2216:31 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2216:31 7440-28-0 Vanadium 2.8J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2216:31 7440-62-2 Zinc 10.1 ug/L 10.0 7.0 1 02/01/2210:55 02/02/2216:31 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 03:33 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 03:33 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 03:33 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 03:33 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 03:33 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 03:33 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 03:33 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 03:33 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 03:33 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 03:33 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 03:33 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 03:33 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 03:33 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 03:33 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 03:33 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW1 Lab ID: 92584821013 Collected: 01/25/22 13:58 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 01/29/22 03:33 124-48-1 ND ug/L 2.0 0.27 1 01/29/22 03:33 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 03:33 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 03:33 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 03:33 106-46-7 ND ug/L 100 0.56 1 01/29/22 03:33 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 03:33 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 03:33 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 03:33 75-35-4 ND ug/L 5.0 0.38 1 01/29/22 03:33 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 03:33 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 03:33 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 03:33 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 03:33 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 03:33 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 03:33 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 03:33 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 03:33 75-09-2 ND ug/L 100 2.7 1 01/29/22 03:33 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 03:33 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 03:33 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 03:33 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 03:33 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 03:33 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 03:33 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 03:33 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 03:33 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 03:33 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 03:33 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 03:33 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 03:33 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 03:33 1330-20-7 98 % 70-130 1 01/29/22 03:33 460-00-4 102 % 70-130 1 01/29/22 03:33 17060-07-0 105 % 70-130 1 01/29/22 03:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW2 Lab ID: 92584821014 Collected: 01/25/22 15:04 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/25/22 15:04 pH 6.66 Std. Units 1 01/25/22 15:04 Temperature 11.4 deg C 1 01/25/22 15:04 Specific Conductance 98.5 umhos/c 1 01/25/22 15:04 m Oxidation Potential 24.7 mV 1 01/25/22 15:04 Oxygen, Dissolved 3.92 mg/L 1 01/25/22 15:04 7782-44-7 Turbidity 3.26 NTU 1 01/25/22 15:04 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2216:37 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:37 7440-38-2 Barium 26.1J ug/L 100 0.67 1 02/01/2210:55 02/02/2216:37 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2216:37 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2216:37 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2216:37 7440-47-3 Cobalt 1.3J ug/L 10.0 0.39 1 02/01/2210:55 02/02/2216:37 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2216:37 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2216:37 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2216:37 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2216:37 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2216:37 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2216:37 7440-28-0 Vanadium 2.2J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2216:37 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2216:37 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 03:51 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 03:51 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 03:51 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 03:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 03:51 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 03:51 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 03:51 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 03:51 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 03:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 03:51 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 03:51 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 03:51 75-00-3 Chloroform ND ug/L 5.0 0.43 1 01/29/22 03:51 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 03:51 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 03:51 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW2 Lab ID: 92584821014 Collected: 01/25/22 15:04 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 01/29/22 03:51 124-48-1 ND ug/L 2.0 0.27 1 01/29/22 03:51 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 03:51 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 03:51 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 03:51 106-46-7 ND ug/L 100 0.56 1 01/29/22 03:51 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 03:51 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 03:51 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 03:51 75-35-4 ND ug/L 5.0 0.38 1 01/29/22 03:51 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 03:51 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 03:51 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 03:51 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 03:51 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 03:51 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 03:51 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 03:51 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 03:51 75-09-2 ND ug/L 100 2.7 1 01/29/22 03:51 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 03:51 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 03:51 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 03:51 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 03:51 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 03:51 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 03:51 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 03:51 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 03:51 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 03:51 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 03:51 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 03:51 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 03:51 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 03:51 1330-20-7 100 % 70-130 1 01/29/22 03:51 460-00-4 103 % 70-130 1 01/29/22 03:51 17060-07-0 102 % 70-130 1 01/29/22 03:51 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW3 Lab ID: 92584821015 Collected: 01/25/22 16:18 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Performed by pH Temperature Specific Conductance Oxidation Potential Turbidity 6020 MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane Date: 02/08/2022 03:27 PM Analytical Method: Pace Analytical Services - Charlotte ES&S 1 01/25/22 16:18 7.87 Std. Units 1 01/25/22 16:18 10.2 deg C 1 01/25/22 16:18 67.2 umhos/c 1 01/25/22 16:18 m -37.3 mV 1 01/25/22 16:18 2.92 NTU 1 01/25/22 16:18 Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/22 16:43 7440-36-0 ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/22 16:43 7440-38-2 21.4J ug/L 100 0.67 1 02/01 /22 10:55 02/02/22 16:43 7440-39-3 ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/22 16:43 7440-41-7 ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/22 16:43 7440-43-9 1.6J ug/L 10.0 1.1 1 02/01 /22 10:55 02/02/22 16:43 7440-47-3 0.45J ug/L 10.0 0.39 1 02/01 /22 10:55 02/02/22 16:43 7440-48-4 0.68J ug/L 10.0 0.50 1 02/01 /22 10:55 02/02/22 16:43 7440-50-8 ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/22 16:43 7439-92-1 ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/22 16:43 7440-02-0 ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/22 16:43 7782-49-2 ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/22 16:43 7440-22-4 ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/22 16:43 7440-28-0 2.1 J ug/L 25.0 1.9 1 02/01 /22 10:55 02/02/22 16:43 7440-62-2 ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/22 16:43 7440-66-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 01/29/22 04:10 67-64-1 ND ug/L 200 1.8 1 01/29/22 04:10 107-13-1 ND ug/L 1.0 0.34 1 01/29/22 04:10 71-43-2 ND ug/L 3.0 0.47 1 01/29/22 04:10 74-97-5 ND ug/L 1.0 0.31 1 01/29/22 04:10 75-27-4 ND ug/L 3.0 0.34 1 01/29/22 04:10 75-25-2 ND ug/L 10.0 1.7 1 01/29/22 04:10 74-83-9 ND ug/L 100 4.0 1 01/29/22 04:10 78-93-3 ND ug/L 100 0.73 1 01/29/22 04:10 75-15-0 ND ug/L 1.0 0.33 1 01/29/22 04:10 56-23-5 ND ug/L 3.0 0.28 1 01/29/22 04:10 108-90-7 ND ug/L 10.0 0.65 1 01/29/22 04:10 75-00-3 ND ug/L 5.0 0.43 1 01/29/22 04:10 67-66-3 ND ug/L 1.0 0.54 1 01/29/22 04:10 74-87-3 ND ug/L 13.0 0.34 1 01/29/22 04:10 96-12-8 ND ug/L 3.0 0.36 1 01/29/22 04:10 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW3 Lab ID: 92584821015 Collected: 01/25/22 16:18 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.27 1 01/29/22 04:10 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 04:10 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 04:10 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 04:10 106-46-7 ND ug/L 100 0.56 1 01/29/22 04:10 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 04:10 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 04:10 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 04:10 75-35-4 ND ug/L 5.0 0.38 1 01/29/22 04:10 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 04:10 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 04:10 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 04:10 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 04:10 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 04:10 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 04:10 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 04:10 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 04:10 75-09-2 ND ug/L 100 2.7 1 01/29/22 04:10 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 04:10 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 04:10 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 04:10 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 04:10 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 04:10 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 04:10 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 04:10 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 04:10 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 04:10 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 04:10 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 04:10 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 04:10 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 04:10 1330-20-7 96 % 70-130 1 01/29/22 04:10 460-00-4 105 % 70-130 1 01/29/22 04:10 17060-07-0 104 % 70-130 1 01/29/22 04:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW4 Lab ID: 92584821016 Collected: 01/25/22 15:52 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Performed by pH Temperature Specific Conductance Oxidation Potential Turbidity 6020 MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane Date: 02/08/2022 03:27 PM Analytical Method: Pace Analytical Services - Charlotte ES&S 1 01/25/22 15:52 7.65 Std. Units 1 01/25/22 15:52 10.0 deg C 1 01/25/22 15:52 69.8 umhos/c 1 01/25/22 15:52 m -25.7 mV 1 01/25/22 15:52 2.38 NTU 1 01/25/22 15:52 Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/22 17:09 7440-36-0 ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/22 17:09 7440-38-2 24.1 J ug/L 100 0.67 1 02/01 /22 10:55 02/02/22 17:09 7440-39-3 ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/22 17:09 7440-41-7 ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/22 17:09 7440-43-9 ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/22 17:09 7440-47-3 0.42J ug/L 10.0 0.39 1 02/01 /22 10:55 02/02/22 17:09 7440-48-4 0.59J ug/L 10.0 0.50 1 02/01 /22 10:55 02/02/22 17:09 7440-50-8 ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/22 17:09 7439-92-1 ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/22 17:09 7440-02-0 ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/22 17:09 7782-49-2 ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/22 17:09 7440-22-4 ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/22 17:09 7440-28-0 ND ug/L 25.0 1.9 1 02/01/2210:55 02/02/22 17:09 7440-62-2 ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/22 17:09 7440-66-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 01/29/22 04:28 67-64-1 ND ug/L 200 1.8 1 01/29/22 04:28 107-13-1 ND ug/L 1.0 0.34 1 01/29/22 04:28 71-43-2 ND ug/L 3.0 0.47 1 01/29/22 04:28 74-97-5 ND ug/L 1.0 0.31 1 01/29/22 04:28 75-27-4 ND ug/L 3.0 0.34 1 01/29/22 04:28 75-25-2 ND ug/L 10.0 1.7 1 01/29/22 04:28 74-83-9 ND ug/L 100 4.0 1 01/29/22 04:28 78-93-3 ND ug/L 100 0.73 1 01/29/22 04:28 75-15-0 ND ug/L 1.0 0.33 1 01/29/22 04:28 56-23-5 ND ug/L 3.0 0.28 1 01/29/22 04:28 108-90-7 ND ug/L 10.0 0.65 1 01/29/22 04:28 75-00-3 ND ug/L 5.0 0.43 1 01/29/22 04:28 67-66-3 ND ug/L 1.0 0.54 1 01/29/22 04:28 74-87-3 ND ug/L 13.0 0.34 1 01/29/22 04:28 96-12-8 ND ug/L 3.0 0.36 1 01/29/22 04:28 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW4 Lab ID: 92584821016 Collected: 01/25/22 15:52 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 0.27 1 01/29/22 04:28 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 04:28 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 04:28 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 04:28 106-46-7 ND ug/L 100 0.56 1 01/29/22 04:28 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 04:28 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 04:28 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 04:28 75-35-4 ND ug/L 5.0 0.38 1 01/29/22 04:28 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 04:28 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 04:28 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 04:28 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 04:28 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 04:28 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 04:28 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 04:28 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 04:28 75-09-2 ND ug/L 100 2.7 1 01/29/22 04:28 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 04:28 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 04:28 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 04:28 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 04:28 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 04:28 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 04:28 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 04:28 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 04:28 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 04:28 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 04:28 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 04:28 108-05-4 ND ug/L 1.0 0.39 1 01/29/22 04:28 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 04:28 1330-20-7 99 % 70-130 1 01/29/22 04:28 460-00-4 101 % 70-130 1 01/29/22 04:28 17060-07-0 103 % 70-130 1 01/29/22 04:28 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW5 Lab ID: 92584821017 Collected: 01/25/22 15:28 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/25/22 15:28 pH 7.35 Std. Units 1 01/25/22 15:28 Temperature 10.2 deg C 1 01/25/22 15:28 Specific Conductance 136.2 umhos/c 1 01/25/22 15:28 m Oxidation Potential -13.8 mV 1 01/25/22 15:28 Oxygen, Dissolved 3.60 mg/L 1 01/25/22 15:28 7782-44-7 Turbidity 5.49 NTU 1 01/25/22 15:28 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2217:15 7440-36-0 Arsenic 1.5J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2217:15 7440-38-2 Barium 25.2J ug/L 100 0.67 1 02/01/2210:55 02/02/2217:15 7440-39-3 Beryllium ND ug/L 1.0 0.054 1 02/01/2210:55 02/02/2217:15 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2217:15 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2217:15 7440-47-3 Cobalt 1.1J ug/L 10.0 0.39 1 02/01/2210:55 02/02/2217:15 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2217:15 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2217:15 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/2210:55 02/02/2217:15 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2217:15 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2217:15 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2217:15 7440-28-0 Vanadium 3.1J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2217:15 7440-62-2 Zinc 11.4 ug/L 10.0 7.0 1 02/01/2210:55 02/02/2217:15 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 09:42 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 09:42 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 09:42 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 09:42 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 09:42 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 09:42 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 09:42 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 09:42 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 09:42 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 09:42 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 09:42 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 09:42 75-00-3 IK Chloroform ND ug/L 5.0 0.43 1 01/29/22 09:42 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 09:42 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 09:42 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-SW5 Lab ID: 92584821017 Collected: 01/25/22 15:28 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 01/29/22 09:42 124-48-1 ND ug/L 2.0 0.27 1 01/29/22 09:42 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 09:42 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 09:42 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 09:42 106-46-7 ND ug/L 100 0.56 1 01/29/22 09:42 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 09:42 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 09:42 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 09:42 75-35-4 ND ug/L 5.0 0.38 1 01/29/22 09:42 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 09:42 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 09:42 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 09:42 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 09:42 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 09:42 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 09:42 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 09:42 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 09:42 75-09-2 ND ug/L 100 2.7 1 01/29/22 09:42 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 09:42 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 09:42 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 09:42 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 09:42 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 09:42 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 09:42 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 09:42 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 09:42 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 09:42 75-69-4 ND ug/L 1.0 0.26 1 01/29/22 09:42 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 09:42 108-05-4 IH ND ug/L 1.0 0.39 1 01/29/22 09:42 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 09:42 1330-20-7 98 % 70-130 1 01/29/22 09:42 460-00-4 103 % 70-130 1 01/29/22 09:42 17060-07-0 102 % 70-130 1 01/29/22 09:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-UD1 Lab ID: 92584821018 Collected: 01/25/22 14:45 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/25/22 14:45 pH 5.94 Std. Units 1 01/25/22 14:45 Temperature 18.1 deg C 1 01/25/22 14:45 Specific Conductance 252 umhos/c 1 01/25/22 14:45 m Oxidation Potential 63.1 mV 1 01/25/22 14:45 Oxygen, Dissolved 3.70 mg/L 1 01/25/22 14:45 7782-44-7 Turbidity 4.28 NTU 1 01/25/22 14:45 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2217:21 7440-36-0 Arsenic 2.1J ug/L 10.0 1.1 1 02/01/2210:55 02/02/2217:21 7440-38-2 Barium 68.1J ug/L 100 0.67 1 02/01/2210:55 02/02/2217:21 7440-39-3 Beryllium 0.074J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2217:21 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2217:21 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2217:21 7440-47-3 Cobalt 6.5J ug/L 10.0 0.39 1 02/01/2210:55 02/02/2217:21 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2217:21 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2217:21 7439-92-1 Nickel 1.4J ug/L 50.0 0.71 1 02/01/2210:55 02/02/2217:21 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2217:21 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2217:21 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2217:21 7440-28-0 Vanadium 4.3J ug/L 25.0 1.9 1 02/01/2210:55 02/02/2217:21 7440-62-2 Zinc 9.6J ug/L 10.0 7.0 1 02/01/2210:55 02/02/2217:21 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 10:00 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 10:00 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 10:00 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 10:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 10:00 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 10:00 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 10:00 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 10:00 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 10:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 10:00 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 10:00 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 10:00 75-00-3 IK Chloroform ND ug/L 5.0 0.43 1 01/29/22 10:00 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 10:00 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 10:00 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-UD1 Lab ID: 92584821018 Collected: 01/25/22 14:45 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 01/29/2210:00 124-48-1 ND ug/L 2.0 0.27 1 01 /29/22 10:00 106-93-4 ND ug/L 10.0 0.39 1 01 /29/22 10:00 74-95-3 ND ug/L 5.0 0.34 1 01/29/2210:00 95-50-1 ND ug/L 1.0 0.33 1 01/29/2210:00 106-46-7 ND ug/L 100 0.56 1 01/29/2210:00 110-57-6 ND ug/L 5.0 0.37 1 01/29/2210:00 75-34-3 ND ug/L 1.0 0.32 1 01 /29/22 10:00 107-06-2 ND ug/L 5.0 0.35 1 01/29/2210:00 75-35-4 ND ug/L 5.0 0.38 1 01/29/2210:00 156-59-2 ND ug/L 5.0 0.40 1 01/29/2210:00 156-60-5 ND ug/L 1.0 0.36 1 01/29/2210:00 78-87-5 ND ug/L 1.0 0.36 1 01 /29/22 10:00 10061-01-5 ND ug/L 1.0 0.36 1 01/29/2210:00 10061-02-6 ND ug/L 1.0 0.30 1 01/29/2210:00 100-41-4 ND ug/L 50.0 0.48 1 01 /29/22 10:00 591-78-6 ND ug/L 20.0 9.7 1 01 /29/22 10:00 74-88-4 ND ug/L 5.0 2.0 1 01 /29/22 10:00 75-09-2 ND ug/L 100 2.7 1 01/29/2210:00 108-10-1 ND ug/L 1.0 0.29 1 01 /29/22 10:00 100-42-5 ND ug/L 5.0 0.31 1 01 /29/22 10:00 630-20-6 ND ug/L 3.0 0.22 1 01 /29/22 10:00 79-34-5 ND ug/L 1.0 0.29 1 01/29/2210:00 127-18-4 ND ug/L 1.0 0.48 1 01 /29/22 10:00 108-88-3 ND ug/L 1.0 0.33 1 01 /29/22 10:00 71-55-6 ND ug/L 1.0 0.32 1 01 /29/22 10:00 79-00-5 ND ug/L 1.0 0.38 1 01 /29/22 10:00 79-01-6 ND ug/L 1.0 0.30 1 01 /29/22 10:00 75-69-4 ND ug/L 1.0 0.26 1 01/29/2210:00 96-18-4 ND ug/L 50.0 1.3 1 01/29/2210:00 108-05-4 IH ND ug/L 1.0 0.39 1 01 /29/22 10:00 75-01-4 ND ug/L 5.0 0.34 1 01 /29/22 10:00 1330-20-7 99 % 70-130 1 01/29/2210:00 460-00-4 102 % 70-130 1 01/29/2210:00 17060-07-0 102 % 70-130 1 01/29/2210:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-UD2 Lab ID: 92584821019 Collected: 01/25/22 14:24 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/25/22 14:24 pH 6.52 Std. Units 1 01/25/22 14:24 Temperature 10.6 deg C 1 01/25/22 14:24 Specific Conductance 182.6 umhos/c 1 01/25/22 14:24 m Oxidation Potential 44.6 mV 1 01/25/22 14:24 Oxygen, Dissolved 3.58 mg/L 1 01/25/22 14:24 7782-44-7 Turbidity 2.95 NTU 1 01/25/22 14:24 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/2210:55 02/02/2217:27 7440-36-0 Arsenic 2.OJ ug/L 10.0 1.1 1 02/01/2210:55 02/02/2217:27 7440-38-2 Barium 80.OJ ug/L 100 0.67 1 02/01/2210:55 02/02/2217:27 7440-39-3 Beryllium 0.085J ug/L 1.0 0.054 1 02/01/2210:55 02/02/2217:27 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 02/01/2210:55 02/02/2217:27 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/2210:55 02/02/2217:27 7440-47-3 Cobalt 7.9J ug/L 10.0 0.39 1 02/01/2210:55 02/02/2217:27 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/2210:55 02/02/2217:27 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/2210:55 02/02/2217:27 7439-92-1 Nickel 1.3J ug/L 50.0 0.71 1 02/01/2210:55 02/02/2217:27 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/2210:55 02/02/2217:27 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/2210:55 02/02/2217:27 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/2210:55 02/02/2217:27 7440-28-0 Vanadium 3.OJ ug/L 25.0 1.9 1 02/01/2210:55 02/02/2217:27 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/2210:55 02/02/2217:27 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 100 5.1 1 01/29/22 10:18 67-64-1 Acrylonitrile ND ug/L 200 1.8 1 01/29/22 10:18 107-13-1 Benzene ND ug/L 1.0 0.34 1 01/29/22 10:18 71-43-2 Bromochloromethane ND ug/L 3.0 0.47 1 01/29/22 10:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 01/29/22 10:18 75-27-4 Bromoform ND ug/L 3.0 0.34 1 01/29/22 10:18 75-25-2 Bromomethane ND ug/L 10.0 1.7 1 01/29/22 10:18 74-83-9 2-Butanone (MEK) ND ug/L 100 4.0 1 01/29/22 10:18 78-93-3 Carbon disulfide ND ug/L 100 0.73 1 01/29/22 10:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 01/29/22 10:18 56-23-5 Chlorobenzene ND ug/L 3.0 0.28 1 01/29/22 10:18 108-90-7 Chloroethane ND ug/L 10.0 0.65 1 01/29/22 10:18 75-00-3 IK Chloroform ND ug/L 5.0 0.43 1 01/29/22 10:18 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 01/29/22 10:18 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.34 1 01/29/22 10:18 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-UD2 Lab ID: 92584821019 Collected: 01/25/22 14:24 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 3.0 0.36 1 01/29/2210:18 124-48-1 ND ug/L 2.0 0.27 1 01 /29/22 10:18 106-93-4 ND ug/L 10.0 0.39 1 01 /29/22 10:18 74-95-3 ND ug/L 5.0 0.34 1 01/29/2210:18 95-50-1 ND ug/L 1.0 0.33 1 01/29/2210:18 106-46-7 ND ug/L 100 0.56 1 01/29/2210:18 110-57-6 ND ug/L 5.0 0.37 1 01/29/2210:18 75-34-3 ND ug/L 1.0 0.32 1 01 /29/22 10:18 107-06-2 ND ug/L 5.0 0.35 1 01/29/2210:18 75-35-4 ND ug/L 5.0 0.38 1 01/29/2210:18 156-59-2 ND ug/L 5.0 0.40 1 01/29/2210:18 156-60-5 ND ug/L 1.0 0.36 1 01/29/2210:18 78-87-5 ND ug/L 1.0 0.36 1 01 /29/22 10:18 10061-01-5 ND ug/L 1.0 0.36 1 01/29/2210:18 10061-02-6 ND ug/L 1.0 0.30 1 01/29/2210:18 100-41-4 ND ug/L 50.0 0.48 1 01 /29/22 10:18 591-78-6 ND ug/L 20.0 9.7 1 01 /29/22 10:18 74-88-4 ND ug/L 5.0 2.0 1 01 /29/22 10:18 75-09-2 ND ug/L 100 2.7 1 01/29/2210:18 108-10-1 ND ug/L 1.0 0.29 1 01 /29/22 10:18 100-42-5 ND ug/L 5.0 0.31 1 01 /29/22 10:18 630-20-6 ND ug/L 3.0 0.22 1 01 /29/22 10:18 79-34-5 ND ug/L 1.0 0.29 1 01/29/2210:18 127-18-4 ND ug/L 1.0 0.48 1 01 /29/22 10:18 108-88-3 ND ug/L 1.0 0.33 1 01 /29/22 10:18 71-55-6 ND ug/L 1.0 0.32 1 01 /29/22 10:18 79-00-5 ND ug/L 1.0 0.38 1 01 /29/22 10:18 79-01-6 ND ug/L 1.0 0.30 1 01 /29/22 10:18 75-69-4 ND ug/L 1.0 0.26 1 01/29/2210:18 96-18-4 ND ug/L 50.0 1.3 1 01/29/2210:18 108-05-4 IH ND ug/L 1.0 0.39 1 01 /29/22 10:18 75-01-4 ND ug/L 5.0 0.34 1 01 /29/22 10:18 1330-20-7 99 % 70-130 1 01/29/2210:18 460-00-4 103 % 70-130 1 01/29/2210:18 17060-07-0 102 % 70-130 1 01/29/2210:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-Trip Blank Lab ID: 92584821020 Collected: 01/25/22 13:54 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrach loroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Date: 02/08/2022 03:27 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 01/29/22 05:10 67-64-1 ND ug/L 200 1.8 1 01/29/22 05:10 107-13-1 ND ug/L 1.0 0.34 1 01/29/22 05:10 71-43-2 ND ug/L 3.0 0.47 1 01/29/22 05:10 74-97-5 ND ug/L 1.0 0.31 1 01/29/22 05:10 75-27-4 ND ug/L 3.0 0.34 1 01/29/22 05:10 75-25-2 ND ug/L 10.0 1.7 1 01/29/22 05:10 74-83-9 ND ug/L 100 4.0 1 01/29/22 05:10 78-93-3 ND ug/L 100 0.73 1 01/29/22 05:10 75-15-0 ND ug/L 1.0 0.33 1 01/29/22 05:10 56-23-5 ND ug/L 3.0 0.28 1 01/29/22 05:10 108-90-7 ND ug/L 10.0 0.65 1 01/29/22 05:10 75-00-3 ND ug/L 5.0 0.43 1 01/29/22 05:10 67-66-3 ND ug/L 1.0 0.54 1 01/29/22 05:10 74-87-3 ND ug/L 13.0 0.34 1 01/29/22 05:10 96-12-8 ND ug/L 3.0 0.36 1 01/29/22 05:10 124-48-1 ND ug/L 2.0 0.27 1 01/29/22 05:10 106-93-4 ND ug/L 10.0 0.39 1 01/29/22 05:10 74-95-3 ND ug/L 5.0 0.34 1 01/29/22 05:10 95-50-1 ND ug/L 1.0 0.33 1 01/29/22 05:10 106-46-7 ND ug/L 100 0.56 1 01/29/22 05:10 110-57-6 ND ug/L 5.0 0.37 1 01/29/22 05:10 75-34-3 ND ug/L 1.0 0.32 1 01/29/22 05:10 107-06-2 ND ug/L 5.0 0.35 1 01/29/22 05:10 75-35-4 ND ug/L 5.0 0.38 1 01/29/22 05:10 156-59-2 ND ug/L 5.0 0.40 1 01/29/22 05:10 156-60-5 ND ug/L 1.0 0.36 1 01/29/22 05:10 78-87-5 ND ug/L 1.0 0.36 1 01/29/22 05:10 10061-01-5 ND ug/L 1.0 0.36 1 01/29/22 05:10 10061-02-6 ND ug/L 1.0 0.30 1 01/29/22 05:10 100-41-4 ND ug/L 50.0 0.48 1 01/29/22 05:10 591-78-6 ND ug/L 20.0 9.7 1 01/29/22 05:10 74-88-4 ND ug/L 5.0 2.0 1 01/29/22 05:10 75-09-2 ND ug/L 100 2.7 1 01/29/22 05:10 108-10-1 ND ug/L 1.0 0.29 1 01/29/22 05:10 100-42-5 ND ug/L 5.0 0.31 1 01/29/22 05:10 630-20-6 ND ug/L 3.0 0.22 1 01/29/22 05:10 79-34-5 ND ug/L 1.0 0.29 1 01/29/22 05:10 127-18-4 ND ug/L 1.0 0.48 1 01/29/22 05:10 108-88-3 ND ug/L 1.0 0.33 1 01/29/22 05:10 71-55-6 ND ug/L 1.0 0.32 1 01/29/22 05:10 79-00-5 ND ug/L 1.0 0.38 1 01/29/22 05:10 79-01-6 ND ug/L 1.0 0.30 1 01/29/22 05:10 75-69-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IN Page 49 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Sample: 1403-Trip Blank Lab ID: 92584821020 Collected: 01/25/22 13:54 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/08/2022 03:27 PM ND ug/L 1.0 0.26 1 01/29/22 05:10 96-18-4 ND ug/L 50.0 1.3 1 01/29/22 05:10 108-05-4 IH ND ug/L 1.0 0.39 1 01/29/22 05:10 75-01-4 ND ug/L 5.0 0.34 1 01/29/22 05:10 1330-20-7 100 % 70-130 1 01/29/22 05:10 460-00-4 99 % 70-130 1 01/29/22 05:10 17060-07-0 102 % 70-130 1 01/29/22 05:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 QC Batch: 675175 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584821001, 92584821002, 92584821003, 92584821004, 92584821005, 92584821006, 92584821007, 92584821008,92584821009,92584821010,92584821011,92584821012,92584821013,92584821014, 92584821015,92584821016,92584821017,92584821018,92584821019 METHOD BLANK: 3533804 Matrix: Water Associated Lab Samples: 92584821001, 92584821002, 92584821003, 92584821004, 92584821005, 92584821006, 92584821007, 92584821008,92584821009,92584821010,92584821011,92584821012,92584821013,92584821014, 92584821015,92584821016,92584821017,92584821018,92584821019 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 02/02/2214:31 Arsenic ug/L ND 10.0 1.1 02/02/2214:31 Barium ug/L ND 100 0.67 02/02/2214:31 Beryllium ug/L ND 1.0 0.054 02/02/2214:31 Cadmium ug/L ND 1.0 0.11 02/02/2214:31 Chromium ug/L ND 10.0 1.1 02/02/2214:31 Cobalt ug/L ND 10.0 0.39 02/02/2214:31 Copper ug/L ND 10.0 0.50 02/02/2214:31 Lead ug/L ND 10.0 0.89 02/02/2214:31 Nickel ug/L ND 50.0 0.71 02/02/2214:31 Selenium ug/L ND 10.0 1.4 02/02/2214:31 Silver ug/L ND 10.0 0.44 02/02/2214:31 Thallium ug/L ND 5.5 0.18 02/02/2214:31 Vanadium ug/L ND 25.0 1.9 02/02/2214:31 Zinc ug/L ND 10.0 7.0 02/02/2214:31 LABORATORY CONTROL SAMPLE: Parameter 3533805 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 114 114 80-120 Arsenic ug/L 100 103 103 80-120 Barium ug/L 100 108 108 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 109 109 80-120 Chromium ug/L 100 112 112 80-120 Cobalt ug/L 100 108 108 80-120 Copper ug/L 100 108 108 80-120 Lead ug/L 100 107 107 80-120 Nickel ug/L 100 109 109 80-120 Selenium ug/L 100 101 101 80-120 Silver ug/L 100 108 108 80-120 Thallium ug/L 100 105 105 80-120 Vanadium ug/L 100 110 110 80-120 Zinc ug/L 100 109 109 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Semi-Annual 92584821 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533806 3533807 MS MSD 92584821011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 113 109 113 109 75-125 4 20 Arsenic ug/L ND 100 100 101 102 101 102 75-125 1 20 Barium ug/L 86.9J 100 100 186 179 100 92 75-125 4 20 Beryllium ug/L ND 100 100 106 108 106 108 75-125 2 20 Cadmium ug/L ND 100 100 104 103 104 103 75-125 1 20 Chromium ug/L ND 100 100 109 108 109 107 75-125 1 20 Cobalt ug/L ND 100 100 107 102 107 102 75-125 4 20 Copper ug/L ND 100 100 103 99.1 103 99 75-125 4 20 Lead ug/L ND 100 100 105 105 105 105 75-125 1 20 Nickel ug/L ND 100 100 105 103 104 102 75-125 2 20 Selenium ug/L ND 100 100 103 104 103 104 75-125 1 20 Silver ug/L ND 100 100 101 99.3 101 99 75-125 2 20 Thallium ug/L ND 100 100 103 99.0 103 99 75-125 4 20 Vanadium ug/L ND 100 100 108 106 108 106 75-125 3 20 Zinc ug/L ND 100 100 108 106 107 104 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 QC Batch: 674589 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584821001, 92584821002, 92584821003, 92584821004, 92584821005, 92584821006, 92584821007, 92584821008,92584821009,92584821010,92584821011,92584821012,92584821013,92584821014, 92584821015,92584821016 METHOD BLANK: 3530772 Matrix: Water Associated Lab Samples: 92584821001, 92584821002, 92584821003, 92584821004, 92584821005, 92584821006, 92584821007, 92584821008,92584821009,92584821010,92584821011,92584821012,92584821013,92584821014, 92584821015,92584821016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 01/29/22 00:31 1,1,1-Trichloroethane ug/L ND 1.0 0.33 01/29/22 00:31 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 01/29/22 00:31 1,1,2-Trichloroethane ug/L ND 1.0 0.32 01/29/22 00:31 1,1-Dichloroethane ug/L ND 5.0 0.37 01/29/22 00:31 1,1-Dichloroethene ug/L ND 5.0 0.35 01/29/22 00:31 1,2,3-Trichloropropane ug/L ND 1.0 0.26 01/29/22 00:31 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 01/29/22 00:31 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 01/29/22 00:31 1,2-Dichlorobenzene ug/L ND 5.0 0.34 01/29/22 00:31 1,2-Dichloroethane ug/L ND 1.0 0.32 01/29/22 00:31 1,2-Dichloropropane ug/L ND 1.0 0.36 01/29/22 00:31 1,4-Dichlorobenzene ug/L ND 1.0 0.33 01/29/22 00:31 2-Butanone (MEK) ug/L ND 100 4.0 01/29/22 00:31 2-Hexanone ug/L ND 50.0 0.48 01/29/22 00:31 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 01/29/22 00:31 Acetone ug/L ND 100 5.1 01/29/22 00:31 Acrylonitrile ug/L ND 200 1.8 01/29/22 00:31 Benzene ug/L ND 1.0 0.34 01/29/22 00:31 Bromochloromethane ug/L ND 3.0 0.47 01/29/22 00:31 Bromodichloromethane ug/L ND 1.0 0.31 01/29/22 00:31 Bromoform ug/L ND 3.0 0.34 01/29/22 00:31 Bromomethane ug/L ND 10.0 1.7 01/29/22 00:31 Carbon disulfide ug/L ND 100 0.73 01/29/22 00:31 Carbon tetrachloride ug/L ND 1.0 0.33 01/29/22 00:31 Chlorobenzene ug/L ND 3.0 0.28 01/29/22 00:31 Chloroethane ug/L ND 10.0 0.65 01/29/22 00:31 Chloroform ug/L ND 5.0 0.43 01/29/22 00:31 Chloromethane ug/L ND 1.0 0.54 01/29/22 00:31 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 01/29/22 00:31 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 01/29/22 00:31 Dibromochloromethane ug/L ND 3.0 0.36 01/29/22 00:31 Dibromomethane ug/L ND 10.0 0.39 01/29/22 00:31 Ethylbenzene ug/L ND 1.0 0.30 01/29/22 00:31 lodomethane ug/L ND 20.0 9.7 01/29/22 00:31 Methylene Chloride ug/L ND 5.0 2.0 01/29/22 00:31 Styrene ug/L ND 1.0 0.29 01/29/22 00:31 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 METHOD BLANK: 3530772 Matrix: Water Associated Lab Samples: 92584821001, 92584821002, 92584821003, 92584821004, 92584821005, 92584821006, 92584821007, 92584821008,92584821009,92584821010,92584821011,92584821012,92584821013,92584821014, 92584821015,92584821016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.29 01/29/22 00:31 Toluene ug/L ND 1.0 0.48 01/29/22 00:31 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 01/29/22 00:31 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 01/29/22 00:31 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 01/29/22 00:31 Trichloroethene ug/L ND 1.0 0.38 01/29/22 00:31 Trichlorofluoromethane ug/L ND 1.0 0.30 01/29/22 00:31 Vinyl acetate ug/L ND 50.0 1.3 01/29/22 00:31 Vinyl chloride ug/L ND 1.0 0.39 01/29/22 00:31 Xylene (Total) ug/L ND 5.0 0.34 01/29/22 00:31 1,2-Dichloroethane-d4 (S) % 101 70-130 01/29/22 00:31 4-Bromofluorobenzene (S) % 101 70-130 01/29/22 00:31 Toluene-d8 (S) % 103 70-130 01/29/22 00:31 LABORATORY CONTROL SAMPLE: 3530773 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.0 102 70-130 1,1,1-Trichloroethane ug/L 50 45.9 92 70-130 1,1,2,2-Tetrachloroethane ug/L 50 51.4 103 70-130 1,1,2-Trichloroethane ug/L 50 49.1 98 70-130 1,1-Dichloroethane ug/L 50 45.8 92 70-130 1,1-Dichloroethene ug/L 50 43.4 87 70-132 1,2,3-Trichloropropane ug/L 50 49.2 98 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.2 106 70-132 1,2-Dibromoethane (EDB) ug/L 50 48.4 97 70-130 1,2-Dichlorobenzene ug/L 50 47.4 95 70-130 1,2-Dichloroethane ug/L 50 47.0 94 70-130 1,2-Dichloropropane ug/L 50 48.7 97 70-130 1,4-Dichlorobenzene ug/L 50 47.7 95 70-130 2-Butanone (MEK) ug/L 100 105 105 70-133 2-Hexanone ug/L 100 102 102 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 103 103 70-130 Acetone ug/L 100 101 101 70-144 Acrylonitrile ug/L 250 282 113 70-130 Benzene ug/L 50 47.1 94 70-130 Bromochloromethane ug/L 50 50.7 101 70-130 Bromodichloromethane ug/L 50 49.2 98 70-130 Bromoform ug/L 50 51.9 104 70-131 Bromomethane ug/L 50 49.2 98 30-177 Carbon disulfide ug/L 50 44.7J 89 70-133 Carbon tetrachloride ug/L 50 47.7 95 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 LABORATORY CONTROL SAMPLE: Parameter 3530773 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Chlorobenzene ug/L 50 46.7 93 70-130 Chloroethane ug/L 50 50.6 101 46-131 Chloroform ug/L 50 46.0 92 70-130 Chloromethane ug/L 50 48.6 97 49-130 cis-1,2-Dichloroethene ug/L 50 47.0 94 70-130 cis-1,3-Dichloropropene ug/L 50 48.6 97 70-130 Dibromochloromethane ug/L 50 46.8 94 70-130 Dibromomethane ug/L 50 50.0 100 70-130 Ethylbenzene ug/L 50 46.6 93 70-130 lodomethane ug/L 100 82.4 82 47-140 Methylene Chloride ug/L 50 44.8 90 68-130 Styrene ug/L 50 49.4 99 70-130 Tetrachloroethene ug/L 50 47.0 94 70-130 Toluene ug/L 50 46.6 93 70-130 trans-1,2-Dichloroethene ug/L 50 43.0 86 70-130 trans- 1,3-Dichloropropene ug/L 50 50.2 100 70-130 trans-1,4-Dichloro-2-butene ug/L 50 58.3J 117 25-200 Trichloroethene ug/L 50 49.0 98 70-130 Trichlorofluoromethane ug/L 50 42.9 86 61-130 Vinyl acetate ug/L 100 105 105 70-140 Vinyl chloride ug/L 50 49.2 98 59-142 Xylene (Total) ug/L 150 142 95 70-130 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530774 MS 92584821011 Spike Parameter Units Result Conc. MSD Spike Conc. 3530775 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 25.8 23.3 129 116 70-135 11 30 1,1,1-Trichloroethane ug/L ND 20 20 26.6 22.9 133 115 70-148 15 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 24.3 22.7 122 113 70-131 7 30 1,1,2-Trichloroethane ug/L ND 20 20 24.6 22.2 123 111 70-136 10 30 1,1-Dichloroethane ug/L ND 20 20 24.2 22.8 121 114 70-147 6 30 1,1-Dichloroethene ug/L ND 20 20 25.4 23.1 127 116 70-158 10 30 1,2,3-Trichloropropane ug/L ND 20 20 24.3 22.3 122 112 67-137 9 30 1,2-Dibromo-3- ug/L ND 20 20 25.1 24.4 126 122 69-136 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 23.8 22.5 119 113 70-137 6 30 1,2-Dichlorobenzene ug/L ND 20 20 23.5 21.2 117 106 70-133 10 30 1,2-Dichloroethane ug/L ND 20 20 24.2 22.8 121 114 67-138 6 30 1,2-Dichloropropane ug/L ND 20 20 24.3 22.9 122 115 70-138 6 30 1,4-Dichlorobenzene ug/L ND 20 20 23.9 21.4 120 107 70-133 11 30 2-Butanone (MEK) ug/L ND 40 40 51.7J 49.OJ 129 122 61-147 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530774 3530775 MS MSD 92584821011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2-Hexanone ug/L ND 40 40 47.9J 45.OJ 120 113 67-139 6 30 4-Methyl-2-pentanone ug/L ND 40 40 46.7J 44.3J 117 111 67-136 5 30 (MIBK) Acetone ug/L ND 40 40 49AJ 48.7J 124 122 55-159 1 30 Acrylonitrile ug/L ND 100 100 116J 126J 116 126 68-140 8 30 Benzene ug/L ND 20 20 24.2 22.1 121 111 67-150 9 30 Bromochloromethane ug/L ND 20 20 26.0 23.5 130 118 70-146 10 30 Bromodichloromethane ug/L ND 20 20 24.7 23.2 124 116 70-138 6 30 Bromoform ug/L ND 20 20 24.3 24.2 121 121 57-138 0 30 Bromomethane ug/L ND 20 20 28.2 26.2 141 131 10-200 8 30 Carbon disulfide ug/L ND 20 20 23.6J 21 AJ 118 107 70-152 10 30 Carbon tetrachloride ug/L ND 20 20 26.2 23.1 131 116 70-147 12 30 Chlorobenzene ug/L ND 20 20 24.4 22.1 122 111 70-137 10 30 Chloroethane ug/L ND 20 20 31.7 28.5 158 143 51-166 10 30 Chloroform ug/L ND 20 20 25.3 22.7 126 114 70-144 11 30 Chloromethane ug/L ND 20 20 26.7 24.3 134 121 24-161 10 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.6 23.7 128 118 67-148 8 30 cis-1,3-Dichloropropene ug/L ND 20 20 24.1 23.0 121 115 70-142 5 30 Dibromochloromethane ug/L ND 20 20 22.8 22.5 114 112 68-138 2 30 Dibromomethane ug/L ND 20 20 24.5 23.1 123 116 70-134 6 30 Ethylbenzene ug/L ND 20 20 24.8 22.0 124 110 68-143 12 30 lodomethane ug/L ND 40 40 36.7 38.3 92 96 20-161 4 30 Methylene Chloride ug/L ND 20 20 24.3 22.4 121 112 64-148 8 30 Styrene ug/L ND 20 20 24.5 22.7 122 113 70-136 8 30 Tetrachloroethene ug/L ND 20 20 25.6 23.4 128 117 70-139 9 30 Toluene ug/L ND 20 20 23.5 21.9 118 110 47-157 7 30 trans-1,2-Dichloroethene ug/L ND 20 20 25.3 23.1 126 115 70-149 9 30 trans-1,3-Dichloropropene ug/L ND 20 20 24.5 22.7 123 114 70-138 8 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 24.8J 23.7J 124 118 31-145 5 30 Trichloroethene ug/L ND 20 20 24.7 23.5 123 117 70-149 5 30 Trichlorofluoromethane ug/L ND 20 20 26.0 22.7 130 114 61-154 13 30 Vinyl acetate ug/L ND 40 40 52.3 49.OJ 131 122 48-156 7 30 Vinyl chloride ug/L ND 20 20 28.4 25.2 142 126 55-172 12 30 Xylene (Total) ug/L ND 60 60 74.2 66.4 124 111 66-145 11 30 1,2-Dichloroethane-d4 (S) % 96 98 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 96 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 QC Batch: 674748 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584821017, 92584821018, 92584821019, 92584821020 METHOD BLANK: 3531774 Matrix: Water Associated Lab Samples: 92584821017, 92584821018, 92584821019, 92584821020 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 01/29/22 04:34 1,1,1-Trichloroethane ug/L ND 1.0 0.33 01/29/22 04:34 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 01/29/22 04:34 1,1,2-Trichloroethane ug/L ND 1.0 0.32 01/29/22 04:34 1,1-Dichloroethane ug/L ND 5.0 0.37 01/29/22 04:34 1,1-Dichloroethene ug/L ND 5.0 0.35 01/29/22 04:34 1,2,3-Trichloropropane ug/L ND 1.0 0.26 01/29/22 04:34 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 01/29/22 04:34 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 01/29/22 04:34 1,2-Dichlorobenzene ug/L ND 5.0 0.34 01/29/22 04:34 1,2-Dichloroethane ug/L ND 1.0 0.32 01/29/22 04:34 1,2-Dichloropropane ug/L ND 1.0 0.36 01/29/22 04:34 1,4-Dichlorobenzene ug/L ND 1.0 0.33 01/29/22 04:34 2-Butanone (MEK) ug/L ND 100 4.0 01/29/22 04:34 2-Hexanone ug/L ND 50.0 0.48 01/29/22 04:34 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 01/29/22 04:34 Acetone ug/L ND 100 5.1 01/29/22 04:34 Acrylonitrile ug/L ND 200 1.8 01/29/22 04:34 Benzene ug/L ND 1.0 0.34 01/29/22 04:34 Bromochloromethane ug/L ND 3.0 0.47 01/29/22 04:34 Bromodichloromethane ug/L ND 1.0 0.31 01/29/22 04:34 Bromoform ug/L ND 3.0 0.34 01/29/22 04:34 Bromomethane ug/L ND 10.0 1.7 01/29/22 04:34 Carbon disulfide ug/L ND 100 0.73 01/29/22 04:34 Carbon tetrachloride ug/L ND 1.0 0.33 01/29/22 04:34 Chlorobenzene ug/L ND 3.0 0.28 01/29/22 04:34 Chloroethane ug/L ND 10.0 0.65 01/29/22 04:34 Chloroform ug/L ND 5.0 0.43 01/29/22 04:34 Chloromethane ug/L ND 1.0 0.54 01/29/22 04:34 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 01/29/22 04:34 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 01/29/22 04:34 Dibromochloromethane ug/L ND 3.0 0.36 01/29/22 04:34 Dibromomethane ug/L ND 10.0 0.39 01/29/22 04:34 Ethylbenzene ug/L ND 1.0 0.30 01/29/22 04:34 lodomethane ug/L ND 20.0 9.7 01/29/22 04:34 Methylene Chloride ug/L ND 5.0 2.0 01/29/22 04:34 Styrene ug/L ND 1.0 0.29 01/29/22 04:34 Tetrachloroethene ug/L ND 1.0 0.29 01/29/22 04:34 Toluene ug/L ND 1.0 0.48 01/29/22 04:34 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 01/29/22 04:34 IK Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 METHOD BLANK: 3531774 Matrix: Water Associated Lab Samples: 92584821017, 92584821018, 92584821019, 92584821020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 01/29/22 04:34 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 01/29/22 04:34 Trichloroethene ug/L ND 1.0 0.38 01/29/22 04:34 Trichlorofluoromethane ug/L ND 1.0 0.30 01/29/22 04:34 Vinyl acetate ug/L ND 50.0 1.3 01/29/22 04:34 IH Vinyl chloride ug/L ND 1.0 0.39 01/29/22 04:34 Xylene (Total) ug/L ND 5.0 0.34 01/29/22 04:34 1,2-Dichloroethane-d4 (S) % 101 70-130 01/29/22 04:34 4-Bromofluorobenzene (S) % 100 70-130 01/29/22 04:34 Toluene-d8 (S) % 102 70-130 01/29/22 04:34 LABORATORY CONTROL SAMPLE: Parameter 3531775 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 47.8 96 70-130 1,1,1-Trichloroethane ug/L 50 47.2 94 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.1 94 70-130 1,1,2-Trichloroethane ug/L 50 47.0 94 70-130 1,1-Dichloroethane ug/L 50 48.5 97 70-130 1,1-Dichloroethene ug/L 50 52.8 106 70-132 1,2,3-Trichloropropane ug/L 50 45.5 91 70-130 1,2-Dibromo-3-chloropropane ug/L 50 48.5 97 70-132 1,2-Dibromoethane (EDB) ug/L 50 48.7 97 70-130 1,2-Dichlorobenzene ug/L 50 47.2 94 70-130 1,2-Dichloroethane ug/L 50 45.3 91 70-130 1,2-Dichloropropane ug/L 50 47.2 94 70-130 1,4-Dichlorobenzene ug/L 50 47.0 94 70-130 2-Butanone (MEK) ug/L 100 95.OJ 95 70-133 2-Hexanone ug/L 100 96.7 97 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 95.9J 96 70-130 Acetone ug/L 100 92.8J 93 70-144 Acrylonitrile ug/L 250 265 106 70-130 Benzene ug/L 50 47.7 95 70-130 Bromochloromethane ug/L 50 47.4 95 70-130 Bromodichloromethane ug/L 50 45.7 91 70-130 Bromoform ug/L 50 47.5 95 70-131 Bromomethane ug/L 50 47.3 95 30-177 Carbon disulfide ug/L 50 49.2J 98 70-133 Carbon tetrachloride ug/L 50 46.7 93 70-130 Chlorobenzene ug/L 50 46.8 94 70-130 Chloroethane ug/L 50 29.4 59 46-131 IK Chloroform ug/L 50 46.9 94 70-130 Chloromethane ug/L 50 44.8 90 49-130 cis-1,2-Dichloroethene ug/L 50 47.9 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 89 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 LABORATORY CONTROL SAMPLE: Parameter 3531775 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 49.2 98 70-130 Dibromochloromethane ug/L 50 48.8 98 70-130 Dibromomethane ug/L 50 44.7 89 70-130 Ethylbenzene ug/L 50 47.6 95 70-130 lodomethane ug/L 100 99.5 99 47-140 Methylene Chloride ug/L 50 47.6 95 68-130 Styrene ug/L 50 50.5 101 70-130 Tetrachloroethene ug/L 50 45.7 91 70-130 Toluene ug/L 50 46.1 92 70-130 trans-1,2-Dichloroethene ug/L 50 49.7 99 70-130 trans- 1,3-Dichloropropene ug/L 50 48.4 97 70-130 trans-1,4-Dichloro-2-butene ug/L 50 47.3J 95 25-200 Trichloroethene ug/L 50 46.3 93 70-130 Trichlorofluoromethane ug/L 50 42.2 84 61-130 Vinyl acetate ug/L 100 116 116 70-140 IH Vinyl chloride ug/L 50 45.8 92 59-142 Xylene (Total) ug/L 150 147 98 70-130 1,2-Dichloroethane-d4 (S) % 92 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3531776 MS 92584833001 Spike Parameter Units Result Conc. MSD Spike Conc. 3531777 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.1 22.7 111 114 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 23.3 23.9 117 120 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.7 22.2 108 111 70-131 2 30 1,1,2-Trichloroethane ug/L ND 20 20 22.4 23.2 112 116 70-136 4 30 1,1-Dichloroethane ug/L 0.94J 20 20 24.5 25.2 118 121 70-147 3 30 1,1-Dichloroethene ug/L ND 20 20 26.5 27.0 133 135 70-158 2 30 1,2,3-Trichloropropane ug/L ND 20 20 21.0 21.9 105 110 67-137 4 30 1,2-Dibromo-3- ug/L ND 20 20 21.4 23.2 107 116 69-136 8 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.8 22.9 109 115 70-137 5 30 1,2-Dichlorobenzene ug/L ND 20 20 22.3 22.9 112 115 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 21.8 22.4 109 112 67-138 3 30 1,2-Dichloropropane ug/L ND 20 20 22.6 23.5 113 117 70-138 4 30 1,4-Dichlorobenzene ug/L 0.54J 20 20 23.0 23.8 112 117 70-133 4 30 2-Butanone (MEK) ug/L ND 40 40 40.9J 43.1J 102 108 61-147 5 30 2-Hexanone ug/L ND 40 40 41.7J 44.8J 104 112 67-139 7 30 4-Methyl-2-pentanone ug/L ND 40 40 42.3J 43.8J 106 109 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 39.9J 40.8J 100 102 55-159 2 30 Acrylonitrile ug/L ND 100 100 108J 112J 108 112 68-140 3 30 Benzene ug/L 2.4 20 20 25.9 26.4 117 120 67-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 89 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3531776 MS 92584833001 Spike Parameter Units Result Conc. MSD Spike Conc. 3531777 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 22.2 23.0 111 115 70-146 3 30 Bromodichloromethane ug/L ND 20 20 22.1 22.8 110 114 70-138 3 30 Bromoform ug/L ND 20 20 21.4 22.0 107 110 57-138 3 30 Bromomethane ug/L ND 20 20 27.6 27.0 138 135 10-200 2 30 Carbon disulfide ug/L ND 20 20 24.6J 25AJ 123 127 70-152 3 30 v2 Carbon tetrachloride ug/L ND 20 20 23.5 24.3 118 121 70-147 3 30 Chlorobenzene ug/L ND 20 20 22.6 23.6 113 118 70-137 4 30 Chloroethane ug/L ND 20 20 20.9 21.0 105 105 51-166 0 30 IK Chloroform ug/L ND 20 20 22.5 23.0 113 115 70-144 2 30 Chloromethane ug/L ND 20 20 22.0 22.7 110 113 24-161 3 30 cis-1,2-Dichloroethene ug/L 3AJ 20 20 26.4 27.5 115 120 67-148 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.6 23.7 113 118 70-142 5 30 Dibromochloromethane ug/L ND 20 20 22.3 23.5 111 117 68-138 5 30 Dibromomethane ug/L ND 20 20 21.3 22.1 106 111 70-134 4 30 Ethylbenzene ug/L ND 20 20 23.5 24.2 118 121 68-143 3 30 lodomethane ug/L ND 40 40 38.5 44.5 96 111 20-161 15 30 Methylene Chloride ug/L ND 20 20 23.2 23.8 116 119 64-148 3 30 Styrene ug/L ND 20 20 24.1 24.8 121 124 70-136 3 30 Tetrachloroethene ug/L ND 20 20 22.8 23.7 114 118 70-139 4 30 Toluene ug/L ND 20 20 22.8 23.7 114 118 47-157 4 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.9 25.2 124 126 70-149 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.4 23.4 112 117 70-138 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 14.9J 15.9J 75 79 31-145 6 30 Trichloroethene ug/L ND 20 20 23.3 23.9 116 120 70-149 3 30 Tri ch lo rofl u oro m eth a n e ug/L ND 20 20 21.2 21.6 106 108 61-154 2 30 Vinyl acetate ug/L ND 40 40 48.7J 51.6 122 129 48-156 6 30 IH Vinyl chloride ug/L ND 20 20 23.2 23.9 116 119 55-172 3 30 Xylene (Total) ug/L 0.68J 60 60 73.4 75.6 121 125 66-145 3 30 1,2-Dichloroethane-d4 (S) % 99 99 70-130 4-Bromofluorobenzene (S) % 102 103 70-130 Toluene-d8 (S) % 99 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS CO Result confirmed by second analysis. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92584821001 1403-MW-1R2 676084 92584821002 1403-MW-3R2 676084 92584821003 1403-MW-4 676084 92584821005 1403-MW-5 676084 92584821006 1403-MW-6 676084 92584821007 1403-MW-7 676084 92584821008 1403-MW-8 676084 92584821009 1403-MW-9 676084 92584821010 1403-MW-10 676084 92584821011 1403-MW-11 676084 92584821013 1403-SW1 676084 92584821014 1403-SW2 676084 92584821015 1403-SW3 676084 92584821016 1403-SW4 676084 92584821017 1403-SW5 676084 92584821018 1403-U D1 676084 92584821019 1403-U D2 676084 92584821001 1403-MW-1R2 EPA 3005A 675175 EPA 6020B 675304 92584821002 1403-MW-3R2 EPA 3005A 675175 EPA 6020B 675304 92584821003 1403-MW-4 EPA 3005A 675175 EPA 6020B 675304 92584821004 1403-DUP@MW-4 EPA 3005A 675175 EPA 6020B 675304 92584821005 1403-MW-5 EPA 3005A 675175 EPA 6020B 675304 92584821006 1403-MW-6 EPA 3005A 675175 EPA 6020B 675304 92584821007 1403-MW-7 EPA 3005A 675175 EPA 6020B 675304 92584821008 1403-MW-8 EPA 3005A 675175 EPA 6020B 675304 92584821009 1403-MW-9 EPA 3005A 675175 EPA 6020B 675304 92584821010 1403-MW-10 EPA 3005A 675175 EPA 6020B 675304 92584821011 1403-MW-11 EPA 3005A 675175 EPA 6020B 675304 92584821012 1403-Field Blank EPA 3005A 675175 EPA 6020B 675304 92584821013 1403-SW1 EPA 3005A 675175 EPA 6020B 675304 92584821014 1403-SW2 EPA 3005A 675175 EPA 6020B 675304 92584821015 1403-SW3 EPA 3005A 675175 EPA 6020B 675304 92584821016 1403-SW4 EPA 3005A 675175 EPA 6020B 675304 92584821017 1403-SW5 EPA 3005A 675175 EPA 6020B 675304 92584821018 1403-U D1 EPA 3005A 675175 EPA 6020B 675304 92584821019 1403-U D2 EPA 3005A 675175 EPA 6020B 675304 92584821001 1403-MW-1R2 EPA 8260D 674589 92584821002 1403-MW-3R2 EPA 8260D 674589 92584821003 1403-MW-4 EPA 8260D 674589 92584821004 1403-DUP@MW-4 EPA 8260D 674589 92584821005 1403-MW-5 EPA 8260D 674589 92584821006 1403-MW-6 EPA 8260D 674589 92584821007 1403-MW-7 EPA 8260D 674589 92584821008 1403-MW-8 EPA 8260D 674589 92584821009 1403-MW-9 EPA 8260D 674589 92584821010 1403-MW-10 EPA 8260D 674589 92584821011 1403-MW-11 EPA 8260D 674589 92584821012 1403-Field Blank EPA 8260D 674589 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/08/2022 03:27 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 89 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF/Semi-Annual Pace Project No.: 92584821 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92584821013 1403-SW1 EPA 8260D 674589 92584821014 1403-SW2 EPA 8260D 674589 92584821015 1403-SW3 EPA 8260D 674589 92584821016 1403-SW4 EPA 8260D 674589 92584821017 1403-SW5 EPA 8260D 674748 92584821018 1403-UD1 EPA 8260D 674748 92584821019 1403-UD2 EPA 8260D 674748 92584821020 1403-Trip Blank EPA 8260D 674748 Date: 02/08/2022 03:27 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 63 of 89 � h f�'" Pace Analytical Services, Inc. m CHAIN OF CUSTODY RECORD 'J'�' 1'i0 TECHNOLOGY PARKWAY, PEACHTREE CORNERS, GA 30092 PAGE: 1 OF 2 � _ (770) 734-4200 : FAX (770) 734-4201 : www.pacelabs.com CLIENT NAME. REPUBLIC SERVICES OF NC L A PRESERVATION a P PLASTIC 1 - Hp, SeC V P .mu rfm I B - A - AMBER GLASS 2 - H=SO,, SVC CLIENT ADDRESS(PHONE NUMBERIFAX NUMBER: mm 1 3 G - CLEAR GLASS 3 - HNO3 *of G 8 V - VOA VIAL 4 - NOOK a-C C O 04 CD to 1 D S- STERILE b- NaOWZnAC, 56-C O - OTHER B - N8 SA' s6-C REPORT TO: STEVE J ETT CC: N m J 7 - SVC Wt *Mn T () ¢ F- N REQUESTED COMPLETION DATE: PO *: -MATRIX CODES: STANDARD TAT A I 0O � PROJECT NAMEISTATE: REPUBLIC - FOOTHILLS LF - NORTH CAROLINA -1403 N _ _ s DW - DRINKING WATER S- SOIL E R X X E R - WASTEWATER SL- SLUDGE VW - GROUNDWATER SO - SOLID PROJECT* S W 0 W SW- SURFACE WATER A- AIR ST - STORM WATER L- LIQUID C G DATE TIME MATRIX O M R A SAMPLE IDENTIFICATION I p- a a a W- WATER P- PRODUCT REMARKSIADDITIONAL INFORMATION CODE" p B Q Q -26 a GW X 1403 - MW -1 R2 5 X X 1 13'.41 GW Xj 1403 - MW - 3R2 5 X X 2 24-'a7- 12.47 GW X 1403 - MW - 4 5 X X 3 12141 GW X 1403-DUP MW - 4 5 X I X-1 1 14 _24-st 11-57 GW X 1403- MW-5 5 X X 5 1-2b-ZZ 1 -07 GW X1 1403 - MW - 6 5 X X 6 1-2` -?-Z. 10.17 GW X 1403 - MW - 7 5 X X 7 I_2i,-at 9:210 GW X 1403-MW-8 5 X X 8 1_2(. - ZZ $; 31 GW X 1403 - MW.- 9 5 X X 9 i_ 2i0 -zz 'l'•41 GW X 1403 - MW -10 5 X X 10 1•Z.6-7- G'.w GW X 1403-MW-11 5 X X 11 1-Zb -2Z (p .4 8 GW X 1403-MSIMSD@140-i1 5 X X 12 SAMPLED BY AND TITLE: DATEITIME: 1-7:55 QUISH D DATWIME: Chiodo - ES&S 1124/ZZ _ n u_17:s; RELINQUISHED BY: DAT IME: WO# : 92584821 UPS FED- EX YI/4: USPS COURIER CLIENT" ED BY: DATEITIME: kECE111 ECV07 —1. YNTVME-. ,rZ -. . 92584821 Gw�tody8": II9fCookn Coolsrl.D: Tem*relum: N0 NA Ye! Na NA Mln` Irnad i14kq hint P.n�en1 1ewoole Pace Analytical Services, Inc. m CHAIN OF CUSTODY RECORD 110 TECHNOLOGY PARKWAY, PEACHTREE CORNERS, GA 30092 PAGE: 2 OF 2 (770) 734-4200 : FAX (770) 734-4201 : www.pac:elabs.com LO f CLIENT NAME' REPUBLIC SERVICES OF NCANALYSIS REQUESTED L NTAINER P PRESERVATION a A P- PLASTIC 1- HCI, WC B A - AMBER GLASS 2 - H2SO4, 56-C .� V P CLIENT ADDRESSIPHONE NUMBERIFAX NUMBER: 1 3 G - CLEAR GLASS 3 - HNO3 * V - VOA VIAL 4. NaOH, 5B-C C O NI 00 U? S- STERILE 5- NaOHIZnAC. SB'C D O - OTHER B - Na2S2%, WC REPORT TO: SIEVE J ETT CC: N m J 7 - aft not frozen T V N REQUESTED COMPLETION DATE: PO #: STANDARD TAT A 0 w UM 'MATRIX CODES: PROJECT NAMEISTATE: REPUBLIC - FOOTHILLS LF - NORTH CAROLINA -1403 N ' DW- DRINKING WATER - SOIL E R X X .i= -WASTEWATER SL- SLUDGE A W- GROUNDWATER SD - SOLID PROJECT M g ❑ ❑ SW - SURFACE WATER A - AIR ST - STORM WATER L - LIQUID C G DATE TIME MATRIX 0 R A SAMPLE IDENTIFICATION a a d a W - WATER P- PRODUCT CODE' M p e Q Q REMARKSIADDITIONAL INFORMATION {^2S•ZZ IT S-o W X 1403-FIELD BLANK 5 X X 1.3 Z 13'. S S SW IXI 1403 - SW 1 5 X X 14 1- zs- zZ I s; o SW X1 1403 - SW 2 5 X X 15 -2a -2Z 11101. I t SW X 1403 - SW 3 51 X X 16 I-is-zz. IS:SZ SW X 1403-SW4 5 X X 17 Ir-z2 157; 2$ SW X 1403 - SW 5 5 X X 18 I-25'-2-7- {(!,4 SW X1 1403 - UD 1 5 X X1 119 I-Z.S'-zZ 14 t ILI SW X 1403 - LID 2 51 X X 20 l--Zs- 22- 13:SH W X 1403-TRIP BLANK 31 X 21 SAMPLED BY AND TITLE: DATEITIME: NQUISHED B DATEITIME: Bob Chiodo - ES&S t ZL Z2 — 17: SS e�C. 112(, 82 DATEITIM WO 92SRd82 RECEIVED BY: DATE/TIME: RELINQUISHED BY: FM: Mp Due Dale: 02/07/22 '1 P VIA-' D UPS FED -EX LISPS COURIER CLIEI CLIENT • GARepNC CocW IM ohmdrmd= low- T mpe ura. CuatodYSaal: # of Coabn►: Yea fVb Yes NO HAMln' I token f#RreaerA Document Name: Document Revised: November 15, 1 i Sample Condition Upon Receipt (SCURj i Page 1 of 2 �� Document No.: Issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office i Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville❑ Atlanta Kernersville❑ ConditionSample Client me: Upon Receipt / Project #: e I SL r�i ' (�, Courier:[Bred Ex ❑UPS ❑LISPS ©Client ❑ Commercial ❑Pace � /� her: Custody Seal Present? Yes ❑No Seals[ Intact? es []NO Packing Material: ❑Bubble Wrap Bubble Bags []None ❑ Other Thermometer: [--]wet []Blue R Gun ID: Type of Ice: Correction Factor: Gaoler Temp:L Add/Subtract ('Cj Cooler Temp Corrected ("C): USDA Regulated Soil (❑ N/A, Water sampl ni,l cmmnla< nrioinato in a nuarantine zone within the United States: CA. NY, or SC (check maps)? WO#:92584821 PM: MP Due Date: 02/07/22 CLIENT: GARePNC Date/initials Person Examining Contents: r�- Biological Tissue Froze ❑Yes []No ❑None Temp should be above freezing to 6°C ❑Samples out of temp criteria Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes ❑No Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Date/Time; Date: Project Manager SRF Review: Date: Page 66 of 89 Document Name: Document Revised: November 15, 2021 CECd� Sample Condition Upon Receipt (SOUR) Page 2 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO.8015 fwater) DOC, LLHg **Bottom half of box is to list number of bottles Project # I W0# : 92584821 PM: MP Due Date: 02/07/22 CLIENT: GRRepNC m d! C > u N d J E Ln N a d m w C! C > u N d J E o N M a. m a C7 C > u N 1 J E $ N N d m q v a+ N d CL C R a ry ._ �•M w r1 m v 2 O vt N u N S J E N V z a0 v m O z 2 u CL -J E o N Z s m R e7j W " Q Z u d J E an a d m n x 0 V d J E in eN•1 a a m N m !7 b 0 E ro �j 3 N 7 a `m ,i •� l7 4 i c V xCIO E ¢ w = .� s •• C7 4 z d d n C 7 a J E N T G 4 Y c LA O r4 x y E q `a = rl J� ., l7 ¢ v v 0 r4 2 E Q J E o N J� m l7 ¢ d E q E N m try a �+, t7 ¢ z ]VC q �! E a x m (� O z M O N VI i0 Z 0 > �' E q O� 0 > dW ` N W CL q d 7 E Qg 7 - m �7 > Q Z 0 O _ q E q 0. �7 O Y Ln fn N Y a N 1O s "r x 0 7 z �0 x 4 7 `� Y Q. N y .mr Y 7 ;, A m V in J E � N r N a w z M v N J E! O Ln N r fn a+ v 4n N a z ` Z a " a N 49 d q J J E E o a p N ,••� a m ¢ Z /9 2 _ V of E p N > } A > N N C `a C G Q E O Q > p 1 2 3 4 5 6 7 9 10 11 1 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot N Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i e. Out of hold, ncorrect preservative, out of temp, incorrect containers Page 67 of 89 Document Name: /-.,PSceareryural. Condition Upon Receil: Document No.: F-CAR-CS-033-Rev.08 *Check mark top half of box if pH and/or dechlorination is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles Document Revised: November 15, 2021 Page 2 of 2 Issuing Authority: carp Carolinas Quality Office WO#:92584821 PM° PP Due Dale: 02/07/22 CLIENT: GARepNC a u N m a J E N m $ u " A a J E N m /1 7 A a J E 4'f m Z roGl d C y d `a 1" m N S O = m a J E ,r, V-t m N v Q S �, W a J E o N m m Z W V N u .: m a J E u, N a m N A 2 Z u 'U A a J E ui ,Ny a m n _ �p V m r o E " `� i ra 3 Z w a E a d w1 H C N V d. _ m E Q `m c rl .=i Q Z N G m a E ¢ J E C N M Q v Y C 0 2 a E q w � 4 .`Ai Q N 2 V G = E ¢ J E E N m a i ? L Q J E N _ a r� e rA Q _ Q z v x ¢ O > J E a�i c = Z O Z d O 7 J E Q ii; > Q v Gr G c a ¢ O E m > ? d On x ¢ O 7 J E m o Q ? Y m .�_. .. 3e y a N m 4 > Z N « Y °' d w a > v > fp ?. S d d y 44 J E ,n eNq u~i JA �9 rZr S d Y 4n J E o N ry qA f/� $ v1 N ? m d J E E N ran m '? Z N G E q J E o O o a z J^ y .0 —u V1 J E N a H dy f' `+ E d J E ate+ o 1 2 3 4 Y X N\N \N 6 7 8 N '31 9 10 11 12 �S N NN I I I INN pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot R Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 68 of 89 SITE NAME: FOOTHILLS LF POINT ID: FIELD BLANK LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: DEIONIZED WATER INITIAL TER LEVEL (FT) ELEV., MEAS. PT. 117_%9 METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: LAB SAMPLE / PROJECT #: E S & S - B.CHIODO mim DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) NDFOS PUMP ( ) YES ( ) NO ( ) OTH ` ( ) 3 ( ) 4 6 ( ) OTHER WAS WELL RGED TO DRYNESS( )YES( ) NO WATER LEVEL E URGE (FT) FINISH • • - • pH (Std.Units). TURBIDITY - OWN slow, -a SAMPLING INFORMATION DATE/TIME / --2 '" Z- / 1 : 0 METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) GRUNDFOS PUMP ( ) YES ( ) OTHER ( ) NO TIME pH Std.Units TEMP. C CONDUCT. umhos/cm TURBIDITY NTU OTHER eh (mV) DISS.OXY. (PPM OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: tJ' COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1 Page 69 of 89 SITE NAME: FOOTHILLS LF POINT ID: LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE I PROJECT #: INITIALLEVEL (FT) 'VVER � ELEV., MEAS. PT. (M DATE METHOD OF EVACUATION: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): ff qjkl in E S & S - B.CHIODO W-1 TIME: START/FINISH EVACUA TION EQUIPMENT DEDICATED: .--5— GRUN S PUMP YES NO OTHER 3 4 6 OTHER WAS WELL PURGED '01 DRYNESS YES NO -T WATER LEVEL END PURGE( FINISH "Tin pH SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) - NA SAMPLING EQUIPMENT DEDICATED: GRUNDFOS PUMP YES OTHER NO TIME pH (Std.Units) TEMP. (C) CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER j eh (mV) DISS. OXY. (PPM) OTHER NA NA NA NA I NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: 5w "Ov SAMPLE CHARACTERISTICS: COMMENTS: VOA ONLY Page 70 0f SAMPLE COLLECTION NUMBER 89 SITE NAME: FOOTHILLS LF POINT ID: SW - 'I LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: EVACUATION INFO SURFACE WATER INITIAL WAR LEVEL (FEET) NA ELEVATION, MEAS.PT.( NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTIN ( ) YES ( ) NO PUMPING WELL ( )4 ( )6 ( )OTHER WAS WELL PURGED TO DRYN WATER LEVEL AFTER PURGE (FT.) FINISH ) YES ( ) NO TIME PURGE RATE m/htz CU L'AT4VE VOLUME TEMP. C PH Units SPEC. CONDUCT. umhos/cm) TURBIDITY (NTU) OTHER [eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME 1" ���-� / ��- WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME PH Std.Units SPEC. CONDUCT. TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER au�mhos/cm 1 +4 . , 0 2. NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: li ty" SAMPLE CHARACTERISTICS: COMMENTS: Page 71 of 89 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER INITIAL WATERQLEVEL (FEET) NA ELEVATION, MEAS7PT—(`MMSb�,_NA.. METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EyAgLATION STABILIZATION DATA POINT ID: UD-2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GfW (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: c 0 N T I N U.$ YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRY )YES ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpm/htz) CUMULATIVE VOLUME --T-Ef� (C) pH :::]�st� SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh fmV) I I NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) — NA WATERRA PUMP (X) DIP BOTTLE SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER I fill 2 4 (0 .57 + 14 NA GENERAL INFORMATION ® or" WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C A COMMENTS: Page 72 of 89 SAMPLE COLLECTION NUMBER 4/ SITE NAME: FOOTHILLS LF LOCATION: LENO|RNORTH CAROL|NA SAMPLE MATRIX: UNOERDRA|NVVATER INITIAL W-A-FERIEVEL (FEET) NA ELEVATION, MEAS.PT.(MSI-): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( \ WELL WIZARD ( S.S. BAILER ( \GRUNOFOSPUK8P WELL RISER DIAMETER UN.\: ( )2 ONE (1) RISER VOLUME (GAL) -------- TOTAL VOLUME EVACUATED /GAL TURBIDITY OFPURG|NGG:START EYACUATION STABILIZATION DATA POINT OD: UUD ~ I FIELD REPRESENTATIVE: ES&G-B.CH|DOO LAB SAMPLE/PROJECT#: NA DEPTH TOBOTTOM (FEET ELE\AA7|ON.G/VV (K8SL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: / )CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( )4 ( \O / ) OTHER_____ VVAG WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE/FT.) FINISH ( )NO PURGE RATE CtIMULATWE TEMP. pH SPEC. CONDUCT. TURBIDITY OTHER NA 0 NA NA NA SAMPLING INFORMATION WATER LEVEL PRIORTOSAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( \ WELL WIZARD ( > VV/TlERRAPUK8p (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA pH SPEC. CONDUCT. TEMP. TURBIDITY REDOX DISS. OXY. OTHER NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: _ SAMPLE CHARACTERISTICS: COMMENTS: SAMPLE COLLECTION NUMBER 57 Page 73m89 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL VVAT4;R-LEVEL (FEET) NA ELEVATION, MEAS. DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: SW-2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GfW (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: CONTINUO YES NO PUMPING WELL 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) CUMULA - VOLUME_ TEMP (C) PH -----4,5td. Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (m NA 0 NA NA F—r NA SAMPLING INFORMATION DATE/TIME /-23;7-22 / / 0 'v WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME PH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER /%, (0.(0(0 99-,5 / �, ? (o +2cl. -) 3,91 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: y SAMPLE CHARACTERISTICS: c L r-- A Jlz COMMENTS: SAMPLE COLLECTION NUMBER 4 Page 74 of 89 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WATERIEVFL (FEET) NA ELEVATION, MEAS.PT.(MSI-): NA DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACLULTION STABILIZATION DATA POINT ID: SW - 5 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: CONTINUOUS YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) CUMULATIVE' VOLUME____ Ttl%P--- _ (c) pH SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (mV) NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME /-�57-zz. / /.,57.'2fr WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER ITjo r7, 3 9- 13 (0. 10. 5-1419 -13.9 Y. (oO NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: sw Af N 55, SAMPLE CHARACTERISTICS: V-A t2 - 7-Atj COMMENTS: SAMPLE COLLECTION NUMBER 7 Page 75 of 89 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVASUATION INFORMATION INITIAL VEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVAQUATION STABILIZATION DATA POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GM (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOU ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( )OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( ) NO TIME PURGE RATE m/htz CUMUL V VOLUME TEMP. C pH .Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME I-?S-ZZ / 153�Z WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 15:yy ?, 5 1, g /0, .3 -2 r.? NA GENERAL INFORMATION a or WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: 4C UcAZ COMMENTS: Page 76 of 89 SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WATER-tEVEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: POINT ID: SW - 3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH PVC BAILER WELL WIZARD ) CONTINUOU'r S.S. BAILER GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): 2 4 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACtKT40.AL STABILIZATION DATA EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO 6 ( ) OTHER WAS WELL PURGED TO DRYNES WATER LEVEL AFTER PURGE (FT.) FINISH YES ( )NO TIME PURGE RATE (gpm/htz) CUMULATIVE VOLUME TEMP—, (C) pH S�td.Uni- SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (m NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME / - 2:57- Z Al'o 80 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std. U nits) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER 9, NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: Y14 SAMPLE CHARACTERISTICS: COMMENTS: Page 77 of 89 SAMPLE COLLECTION NUMBER 17 SITE NAME FOOTHILLS LF _ POINT ID: LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION • 1 1 INITIAL WATER LEVEL (FT): 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 22 DEPTH TO BOTTOM (FT): 1 0 .4 0 ELEV., MEAS. PT. (MSL): `� ° ELEVATION, G/W (MSL): / O DATE ��� �- TIME: START/FINISH 6 f 16 / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) , 0 TOTAL VOL. EVACUATED (GAL) • 0 0 TURBIDITY OF PURGINGS: START Ce.f, EVACUATION STABILIZATION DATA ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS( )YES(X)NO WATER LEVEL END PURGE (FT) • 3 FINISH C pH opt �l ffll-� I MET* ME wom Em SAMPLING INFORMATION DATE / TIME r 1 DEPTH TO GROUNDWATER (FT) -?• 2---? METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION �°' or WEATHER CONDITIONS AT TIME OF SAMPLING: J q 10 SAMPLE CHARACTERISTICS: C l� COMMENTS: APPENDIX I LIST M 511-1sb 'r A( SAMPLE COLLECTION NUMBER 1 0 + l ( Page 78 of 89 SITE NAME FOOTHILLS LF .O TT LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 1 5 • :s DATE I - )L(P- Z Z-- LAB SAMPLE / PROJECT #: E S & S - B.CHIODO am DEPTH TO BOTTOM (FT): ° 'z r ELEVATION, G/W (MSL): TIME: START/FINISH 17., d,q / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS .0o START C EVACUATION STABILIZATION DATA WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) qL FINISH C �F' pH NMI SAMPLING INFORMATION DATE/TIME I DEPTH TO GROUNDWATER (FT) • L� METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION (' OF WEATHER CONDITIONS AT TIME OF SAMPLING: , o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER Page 79 of 89 SITE NAME FOOTHILLS LF POINT ID: mw - 9 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): . I FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): ELEVATION, G/W (MSL): DATE 1-2(p- c Z- TIME: START/FINISH : 59 / METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) .RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: '2.0 0 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) Co 9. 2 s- START C FINISH C t-F. EVACUATION STABILIZATION DATA off ME ork AN = rpm ml, m pH MINOR SAMPLING INFORMATION DATE/TIME 1- 26- 2'Z- / , ) DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: scar SAMPLE CHARACTERISTICS: C VA X- COMMENTS: APPENDIX I LIST - Page 80 of 89 SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): 1 1 ELEVATION, G/W (MSL): 119 4 . 3 DATE TIME: START/FINISH . 54 / • .2(o METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO (X)2 ( )3 ( )4 ( )6 ( )OTHER • o o WAS WELL PURGED TO DRYNESS( )YES(X)NO ®® WATER LEVEL END PURGE (FT) 3 0. TURBIDITY OF PURGINGS: START FINISH'. EVACUATION STABILIZATION DATA SAMPLING INFORMATION DATE/TIME )~V0--ZZ / !' .2 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: S(A lljQ SAMPLE CHARACTERISTICS: cL� COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I Ll Page 81 of 89 SITE NAME FOOTHILLS LF POINT ID: MW-7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ m FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FT): 44 19. /-? ELEV., MEAS. PT. (MSQ: 1 0 . -') ELEVATION, G/W (MSL): lj� I. 1--> DATE 2Ap - Z7— TIME: START/FINISH 9: 4ts- METHOD OF EVACUATION: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: EVACUATION STABILIZATION DATA EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) 32.1 Z FINISH (f UEAlp- 0 P14— (Std.Units) ff -2 mem, SAMPLING INFORMATION DATE/TIME 1-26—Z-Z- / )().' 1-7 DEPTH TO GROUNDWATER (FT) 32./2 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION F WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C LrZAJZ- COMMENTS: APPENDIX I LIST Page 82 of 89 SAMPLE COLLECTION NUMBERIS SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ Ll 3 LO ELEV., MEAS. PT. (MSQ: ( S*' DATE ) - A, - -17- POINT ID: MW-6 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): .5-0--s-5 ELEVATION, G/W (MSQ: )33. (o � TIME: START/FINISH /0,'?S- / //;07 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 4 6 OTHER ONE (1) RISER VOLUME (GAL) 1.18 WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) ®2, oo WATER LEVEL END PURGE (FT) 30 TURBIDITY OF PURGINGS: START C FINISH C (ZAK EVACUATION STABILIZATION DATA PURGE RATITM (ML MIN) pH fflT.-TITS In SAMPLING INFORMATION DATE/TIME 1-26-ZL / I): 0r7 DEPTH TO GROUNDWATER (FT)/ 3. 30 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP OTHER NO GENERAL INFORMATION Qn OF WEATHER CONDITIONS AT TIME OF SAMPLING: 5a-4^jt4jd20 IV SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1(4 Page 83 of 89 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION e-� INITIAL WATER LEVEL (FT): q . P POINT ID: MW - 5 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): 5 1. ELEV., MEAS. PT. (MSL): 1 1 57. O - ELEVATION, G/W (MSL): 11 ' ?7. 70 DATE 1 26— 2 2- TIME: START/FINISH I ) : ;Z.5 / 0 , 5 7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.14 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) Z00 WATER LEVEL END PURGE (FT) Ll 7 1 TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA TURBIDITY SAMPLING INFORMATION DATE/TIME �® � �'�- / , DEPTH TO GROUNDWATER (FT) s-i METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: w f-j SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1 d Page 84 of 89 SITE NAME FOOTHILLS LF POINT ID: MW-4 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSQ: DATE 1- 2 � - 2,7- FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): ELEVATION, G/W (MSQ: TIME: START/FINISH METHOD OF EVACUATION: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP S.S. BAILER (X)QED WWPUMP ( ) OTHER NA /1-1211,17 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 3 ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS YES (X) NO qSo TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) 1. TURBIDITY OF PURGINGS: START FINISH O-Ur:-Ag EVACUATION STABILIZATION DATA PURGE RAT17m __�ML MIN) pH (Stc TURBIDITY SAMPLING INFORMATION DATE/TIME I-2t--27- / )2"LI-7 4- 12.:41 DEPTH TO GROUNDWATER (FT) ko METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION 01-Ic WEATHER CONDITIONS AT TIME OF SAMPLING: 5w tv r4 y I-' /o SAMPLE CHARACTERISTICS: IAR COMMENTS: APPENDIX I LIST bL4P --(-AO^J (*'V7 -j-/2-'ql) SAMPLE COLLECTION NUMBER I '?'+ 1 I Page 85 of 89 SITE NAME FOOTHILLS LF POINT ID: MW - 3R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL) DATE I— — LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA am ELEVATION, G/W (MSL): ( 1 , TIME: START/FINISH 1 3' I 0 / 1 "Y METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 5-.og WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) o?. 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START Cy ia- FINISH C EVACUATION STABILIZATION DATA pH TURBIDITY �Z�m SAMPLING INFORMATION DATE/TIME 1-26 ®Z 7- / DEPTH TO GROUNDWATER (FT) '1-'13 METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO. , GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �at n,►rJ SAMPLE CHARACTERISTICS: c t-F-Ap- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER Page 86 of 89 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): POINT ID: MW - 2R FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT#: DEPTH TO BOTTOM (FT) ffm ELEV., MEAS. PT. (MSL): 5 i ELEVATION, G/W (MSQ: DATE )-2�-ZZ TIME: START/FINISH 14; 0 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 ) 4 6 OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) 0.50 WATER LEVEL END PURGE (FT) 5-OdS TURBIDITY OF PURGINGS: START C k;EA� FINISH C L.FrAK EVACUATION STABILIZATION DATA Mj� PURGE RA'TESIMDMW�� (ML MIN) I pH Units) 0 0 I ml mu jimwwwp-jj SAMPLING INFORMATION DATE/TIME / mLll DEPTH TO GROUNDWATER (FT) 5-6), / g METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c LE^z COMMENTS: APPENDIX 11 LIST SAMPLE COLLECTION NUMBER R 1 Page 87 of 89 SITE NAME FOOTHILLS LF POINT ID: MW - 'I R2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): 30 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 0 DEPTH TO BOTTOM (FT): 419. ELEV., MEAS. PT. (MSL): ELEVATION, G/W (MSL): I'l -1 3 . -"- DATE ) -- 26 -+ 2 Z TIME: START/FINISH /5 ..2 O / 15" • 5 2- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 3, 37 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . 00 WATER LEVEL END PURGE (FT) -7,cl.5 TURBIDITY OF PURGINGS: START l ' FINISH c UE Z EVACUATION STABILIZATION DATA rpm TURBIDITY SAMPLING INFORMATION DATE / TIME / I • S 2- DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: pYo SAMPLE CHARACTERISTICS:' COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 0 Page 88 of 89 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE INITIALVVA-T€R,,,LEVEL (FEET) NA ELEVATION, MEAS.PT.(MSL., _ NA DATE METHOD OF EVACUATION: POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUO ( ) YES ( ) NO ( } S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYN ) YES ( )NCO TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA -•� ... • • f • •CONDUCT.-: • • OTHER - SAMPLING INFORMATION DATE / TIME I — 26 -AZ- / I V. WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) SAMPLE PORT ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER ?(;37 1. ,,(o 000 17.6 — 3. NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING:y SAMPLE CHARACTERISTICS: Ci, Amevz COMMENTS: Page 89 of 89 SAMPLE COLLECTION NUMBER lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 07, 2022 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, r J� Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 41 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 North Carolina Certification #: 381 Florida DOH Certification #: E87315 South Carolina Certification #: 98011001 Georgia DW Inorganics Certification #: 812 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Lab ID Sample ID Matrix Date Collected Date Received 92584833001 1403-MW-2R Water 01/26/2214:41 01/27/2210:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF/Semi-Annual 92584833 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92584833001 1403-MW-2R EPA 8081 B AMM 24 PAN EPA 8151 CCW 5 PAN EPA8011 HH 3 PASI-C EPA 8082A SEM 8 PASI-C EPA6020B CW1 16 PASI-GA EPA 7470A VB 1 PASI-GA EPA 8270E PKS 118 PASI-C EPA 8260D NSCQ 62 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A SM 4500-CN-E-2016 MMB 1 PASI-A PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Foothills LF/Semi-Annual 92584833 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584833001 1403-MW-2R Performed by ES&S 01/26/22 14:41 pH 5.74 Std. Units 01/26/22 14:41 Temperature 14.4 deg C 01/26/22 14:41 Static Water Level 50.18 feet 01/26/22 14:41 Specific Conductance 156.8 umhos/cm 01/26/22 14:41 Oxidation Potential 73.6 my 01/26/22 14:41 Oxygen, Dissolved 2.45 mg/L 01/26/22 14:41 Turbidity 0.58 NTU 01/26/22 14:41 EPA6020B Barium 307 ug/L 100 02/01/2213:57 EPA6020B Beryllium 0.16J ug/L 1.0 02/01/2213:57 EPA 6020B Cadmium 0.11 J ug/L 1.0 02/01/22 13:57 EPA8260D Benzene 2.4 ug/L 1.0 01/29/2210:36 EPA8260D 1,4-Dichlorobenzene 0.54J ug/L 1.0 01/29/2210:36 EPA8260D 1,1-Dichloroethane 0.94J ug/L 5.0 01/29/2210:36 EPA8260D cis-1,2-Dichloroethene 3AJ ug/L 5.0 01/29/2210:36 EPA8260D Xylene(Total) 0.68J ug/L 5.0 01/29/2210:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Performed by pH Temperature Static Water Level Specific Conductance Oxidation Potential Oxygen, Dissolved Turbidity Pesticides (GC) 8081 B Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) alpha -Chlordane gamma -Chlordane 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Surrogates Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Chlorinated Herb. (GC) 8151 2,4-D Dinoseb 2,4,5-T 2,4,5-TP (Silvex) Date: 02/07/2022 03:04 PM Analytical Method: Pace Analytical Services - Charlotte ES&S 1 01/26/22 14:41 5.74 Std. Units 1 01/26/22 14:41 14.4 deg C 1 01/26/22 14:41 50.18 feet 1 01/26/22 14:41 156.8 umhos/c 1 01/26/22 14:41 m 73.6 my 1 01/26/22 14:41 2.45 mg/L 1 01/26/22 14:41 7782-44-7 0.58 NTU 1 01/26/22 14:41 Analytical Method: EPA 8081 B Preparation Method: 3510C Pace National - Mt. Juliet ND ug/L 0.0500 0.0198 1 02/01/22 17:52 02/02/22 01:51 309-00-2 ND ug/L 0.0500 0.0172 1 02/01/22 17:52 02/02/22 01:51 319-84-6 ND ug/L 0.0500 0.0208 1 02/01/22 17:52 02/02/22 01:51 319-85-7 ND ug/L 0.0500 0.0150 1 02/01/22 17:52 02/02/22 01:51 319-86-8 ND ug/L 0.0500 0.0209 1 02/01/22 17:52 02/02/22 01:51 58-89-9 ND ug/L 5.00 0.0198 1 02/01/22 17:52 02/02/22 01:51 57-74-9 ND ug/L 0.0500 0.0149 1 02/01/22 17:52 02/02/22 01:51 5103-71-9 ND ug/L 0.0500 0.0137 1 02/01/22 17:52 02/02/22 01:51 5103-74-2 ND ug/L 0.0500 0.0177 1 02/01/22 17:52 02/02/22 01:51 72-54-8 ND ug/L 0.0500 0.0154 1 02/01/22 17:52 02/02/22 01:51 72-55-9 ND ug/L 0.0500 0.0198 1 02/01/22 17:52 02/02/22 01:51 50-29-3 ND ug/L 0.0500 0.0162 1 02/01/22 17:52 02/02/22 01:51 60-57-1 ND ug/L 0.0500 0.0160 1 02/01/22 17:52 02/02/22 01:51 959-98-8 ND ug/L 0.0500 0.0164 1 02/01/22 17:52 02/02/22 01:51 33213-65-9 ND ug/L 0.0500 0.0217 1 02/01/22 17:52 02/02/22 01:51 1031-07-8 ND ug/L 0.0500 0.0161 1 02/01/22 17:52 02/02/22 01:51 72-20-8 ND ug/L 0.0500 0.0237 1 02/01/22 17:52 02/02/22 01:51 7421-93-4 ND ug/L 0.0500 0.0219 1 02/01/22 17:52 02/02/22 01:51 53494-70-5 ND ug/L 0.0500 0.0148 1 02/01/22 17:52 02/02/22 01:51 76-44-8 ND ug/L 0.0500 0.0183 1 02/01/22 17:52 02/02/22 01:51 1024-57-3 ND ug/L 0.0500 0.0193 1 02/01/22 17:52 02/02/22 01:51 72-43-5 ND ug/L 0.500 0.168 1 02/01/22 17:52 02/02/22 01:51 8001-35-2 47.3 % 10.0- 1 02/01/22 17:52 02/02/22 01:51 2051-24-3 128 61.6 % 10.0- 1 02/01/22 17:52 02/02/22 01:51 877-09-8 127 Analytical Method: EPA8151 Preparation Method: 8151A Pace National - Mt. Juliet ND ug/L 2.00 0.547 1 02/01/22 08:03 02/07/22 08:12 94-75-7 ND ug/L 2.00 0.250 1 02/01/22 08:03 02/07/22 08:12 88-85-7 ND ug/L 2.00 0.258 1 02/01/22 08:03 02/07/22 08:12 93-76-5 ND ug/L 2.00 0.335 1 02/01/22 08:03 02/07/22 08:12 93-72-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. LO LO Page 6 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151 Analytical Method: EPA8151 Preparation Method: 8151A Pace National - Mt. Juliet Surrogates 2,4-DCAA (S) 72.0 % 14.0- 1 02/01/22 08:03 02/07/22 08:12 19719-28-9 158 8011 GCS EDB and DBCP Analytical Method: EPA 8011 Preparation Method: EPA 8011 Pace Analytical Services - Charlotte 1,2-Dibromo-3- ND ug/L 0.20 0.0026 1 02/03/2210:37 02/03/2212:59 96-12-8 chloropropane 1,2-Dibromoethane (EDB) ND ug/L 0.050 0.0075 1 02/03/22 10:37 02/03/22 12:59 106-93-4 Surrogates 1-Chloro-2-bromopropane 88 % 60-140 1 02/03/2210:37 02/03/2212:59 301-79-56 (S) 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 0.42 0.18 1 01/31/22 09:19 02/02/22 13:46 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.42 0.19 1 01/31/22 09:19 02/02/22 13:46 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.42 0.19 1 01/31/22 09:19 02/02/22 13:46 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.42 0.21 1 01/31/22 09:19 02/02/22 13:46 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.42 0.24 1 01/31/22 09:19 02/02/22 13:46 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.42 0.18 1 01/31/22 09:19 02/02/22 13:46 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.42 0.13 1 01/31/22 09:19 02/02/22 13:46 11096-82-5 Surrogates Decachlorobiphenyl (S) 98 % 10-181 1 01/31/22 09:19 02/02/22 13:46 2051-24-3 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 6.0 0.78 1 02/01/22 09:47 02/01/22 13:57 7440-36-0 Arsenic ND ug/L 10.0 1.1 1 02/01/22 09:47 02/01/22 13:57 7440-38-2 Barium 307 ug/L 100 0.67 1 02/01/22 09:47 02/01/22 13:57 7440-39-3 Beryllium 0.16J ug/L 1.0 0.054 1 02/01/22 09:47 02/01/22 13:57 7440-41-7 Cadmium 0.11J ug/L 1.0 0.11 1 02/01/22 09:47 02/01/22 13:57 7440-43-9 Chromium ND ug/L 10.0 1.1 1 02/01/22 09:47 02/01/22 13:57 7440-47-3 Cobalt ND ug/L 10.0 0.39 1 02/01/22 09:47 02/01/22 13:57 7440-48-4 Copper ND ug/L 10.0 0.50 1 02/01/22 09:47 02/01/22 13:57 7440-50-8 Lead ND ug/L 10.0 0.89 1 02/01/22 09:47 02/01/22 13:57 7439-92-1 Nickel ND ug/L 50.0 0.71 1 02/01/22 09:47 02/01/22 13:57 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/01/22 09:47 02/01/22 13:57 7782-49-2 Silver ND ug/L 10.0 0.44 1 02/01/22 09:47 02/01/22 13:57 7440-22-4 Thallium ND ug/L 5.5 0.18 1 02/01/22 09:47 02/01/22 13:57 7440-28-0 Tin ND ug/L 20.0 1.5 1 02/01/22 09:47 02/01/22 13:57 7440-31-5 Vanadium ND ug/L 25.0 1.9 1 02/01/22 09:47 02/01/22 13:57 7440-62-2 Zinc ND ug/L 10.0 7.0 1 02/01/22 09:47 02/01/22 13:57 7440-66-6 Date: 02/07/2022 03:04 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Peachtree Corners, GA Mercury ND ug/L 0.20 0.13 1 01/31/2215:00 02/01/2211:24 7439-97-6 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Acenaphthene ND ug/L 9.1 1.8 1 01/28/22 10:38 01/28/22 20:24 83-32-9 Acenaphthylene ND ug/L 9.1 1.8 1 01/28/22 10:38 01/28/22 20:24 208-96-8 Acetophenone ND ug/L 9.1 1.4 1 01/28/22 10:38 01/28/22 20:24 98-86-2 2-Acetylaminofluorene ND ug/L 9.1 3.7 1 01/28/22 10:38 01/28/22 20:24 53-96-3 4-Aminobiphenyl ND ug/L 9.1 4.3 1 01/28/22 10:38 01/28/22 20:24 92-67-1 Anthracene ND ug/L 9.1 2.1 1 01/28/22 10:38 01/28/22 20:24 120-12-7 Benzo(a)anthracene ND ug/L 9.1 2.4 1 01/28/22 10:38 01/28/22 20:24 56-55-3 Benzo(a)pyrene ND ug/L 9.1 2.5 1 01/28/22 10:38 01/28/22 20:24 50-32-8 Benzo(b)fluoranthene ND ug/L 9.1 2.4 1 01/28/22 10:38 01/28/22 20:24 205-99-2 Benzo(g,h,i)perylene ND ug/L 9.1 2.6 1 01/28/22 10:38 01/28/22 20:24 191-24-2 Benzo(k)fluoranthene ND ug/L 9.1 2.5 1 01/28/22 10:38 01/28/22 20:24 207-08-9 Benzoic Acid ND ug/L 45.5 3.1 1 01/28/22 10:38 01/28/22 20:24 65-85-0 Benzyl alcohol ND ug/L 18.2 2.6 1 01/28/22 10:38 01/28/22 20:24 100-51-6 4-Bromophenylphenyl ND ug/L 9.1 1.6 1 01/28/22 10:38 01/28/22 20:24 101-55-3 ether Butylbenzylphthalate ND ug/L 9.1 2.9 1 01/28/22 10:38 01/28/22 20:24 85-68-7 Carbazole ND ug/L 9.1 2.1 1 01/28/22 10:38 01/28/22 20:24 86-74-8 4-ChIoro-3-methyl phenol ND ug/L 9.1 3.0 1 01/28/22 10:38 01/28/22 20:24 59-50-7 4-Chloroaniline ND ug/L 18.2 3.3 1 01/28/22 10:38 01/28/22 20:24 106-47-8 Chlorobenzilate ND ug/L 9.1 3.4 1 01/28/22 10:38 01/28/22 20:24 510-15-6 bis(2- ND ug/L 9.1 1.7 1 01/28/22 10:38 01/28/22 20:24 111-91-1 Chloroethoxy)methane bis(2-Chloroethyl) ether ND ug/L 9.1 1.7 1 01/28/22 10:38 01/28/22 20:24 111-44-4 2-Chloronaphthalene ND ug/L 9.1 1.6 1 01/28/22 10:38 01/28/22 20:24 91-58-7 2-Chlorophenol ND ug/L 9.1 1.1 1 01/28/22 10:38 01/28/22 20:24 95-57-8 4-Chlorophenylphenyl ND ug/L 9.1 1.8 1 01/28/22 10:38 01/28/22 20:24 7005-72-3 ether Chrysene ND ug/L 9.1 2.5 1 01/28/22 10:38 01/28/22 20:24 218-01-9 Diallate ND ug/L 9.1 3.1 1 01/28/22 10:38 01/28/22 20:24 2303-16-4 Dibenz(a,h)anthracene ND ug/L 9.1 2.7 1 01/28/22 10:38 01/28/22 20:24 53-70-3 Dibenzofuran ND ug/L 9.1 1.9 1 01/28/22 10:38 01/28/22 20:24 132-64-9 1,2-Dichlorobenzene ND ug/L 9.1 1.6 1 01/28/22 10:38 01/28/22 20:24 95-50-1 1,3-Dichlorobenzene ND ug/L 9.1 1.5 1 01/28/22 10:38 01/28/22 20:24 541-73-1 1,4-Dichlorobenzene ND ug/L 9.1 1.5 1 01/28/22 10:38 01/28/22 20:24 106-46-7 3,3'-Dichlorobenzidine ND ug/L 18.2 7.4 1 01/28/22 10:38 01/28/22 20:24 91-94-1 2,4-Dichlorophenol ND ug/L 9.1 1.3 1 01/28/22 10:38 01/28/22 20:24 120-83-2 Diethylphthalate ND ug/L 9.1 1.9 1 01/28/22 10:38 01/28/22 20:24 84-66-2 Dimethoate ND ug/L 9.1 3.3 1 01/28/22 10:38 01/28/22 20:24 60-51-5 P- ND ug/L 4.5 2.2 1 01/28/22 10:38 01/28/22 20:24 60-11-7 IL Dimethylaminoazobenzen e REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 7,12- ND ug/L 9.1 2.7 1 01/28/22 10:38 01/28/22 20:24 57-97-6 Dimethylbenz(a)anthracen e 3,3'-Dimethylbenzidine ND ug/L 45.5 28.3 1 01/28/22 10:38 01/28/22 20:24 119-93-7 IH 2,4-Dimethylphenol ND ug/L 9.1 1.5 1 01/28/22 10:38 01/28/22 20:24 105-67-9 Dimethylphthalate ND ug/L 9.1 1.9 1 01/28/22 10:38 01/28/22 20:24 131-11-3 Di-n-butylphthalate ND ug/L 9.1 2.0 1 01/28/22 10:38 01/28/22 20:24 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 18.2 3.1 1 01/28/22 10:38 01/28/22 20:24 534-52-1 1,3-Dinitrobenzene ND ug/L 9.1 3.4 1 01/28/22 10:38 01/28/22 20:24 99-65-0 2,4-Dinitrophenol ND ug/L 45.5 23.6 1 01/28/22 10:38 01/28/22 20:24 51-28-5 v1 2,4-Dinitrotoluene ND ug/L 9.1 1.5 1 01/28/22 10:38 01/28/22 20:24 121-14-2 2,6-Dinitrotoluene ND ug/L 9.1 1.6 1 01/28/22 10:38 01/28/22 20:24 606-20-2 Di-n-octylphthalate ND ug/L 9.1 3.6 1 01/28/22 10:38 01/28/22 20:24 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/L 5.5 3.4 1 01/28/22 10:38 01/28/22 20:24 117-81-7 Ethyl methanesulfonate ND ug/L 18.2 2.7 1 01/28/22 10:38 01/28/22 20:24 62-50-0 Famphur ND ug/L 9.1 5.6 1 01/28/22 10:38 01/28/22 20:24 52-85-7 IH Fluoranthene ND ug/L 9.1 2.0 1 01/28/22 10:38 01/28/22 20:24 206-44-0 Fluorene ND ug/L 9.1 1.9 1 01/28/22 10:38 01/28/22 20:24 86-73-7 Hexachloro-1,3-butadiene ND ug/L 9.1 1.6 1 01/28/22 10:38 01/28/22 20:24 87-68-3 v1 Hexachlorobenzene ND ug/L 9.1 2.0 1 01/28/22 10:38 01/28/22 20:24 118-74-1 Hexachlorocyclopentadien ND ug/L 9.1 1.4 1 01/28/22 10:38 01/28/22 20:24 77-47-4 e Hexachloroethane ND ug/L 9.1 1.3 1 01/28/22 10:38 01/28/22 20:24 67-72-1 Hexachloropropene ND ug/L 9.1 6.4 1 01/28/22 10:38 01/28/22 20:24 1888-71-7 v1 Indeno(1,2,3-cd)pyrene ND ug/L 9.1 2.6 1 01/28/22 10:38 01/28/22 20:24 193-39-5 Isodrin ND ug/L 9.1 2.5 1 01/28/22 10:38 01/28/22 20:24 465-73-6 Isophorone ND ug/L 9.1 1.5 1 01/28/22 10:38 01/28/22 20:24 78-59-1 Isosafrole ND ug/L 9.1 2.3 1 01/28/22 10:38 01/28/22 20:24 120-58-1 Kepone ND ug/L 18.2 12.8 1 01/28/22 10:38 01/28/22 20:24 143-50-0 Methapyrilene ND ug/L 45.5 15.5 1 01/28/22 10:38 01/28/22 20:24 91-80-5 IH 3-Methylcholanthrene ND ug/L 9.1 5.3 1 01/28/22 10:38 01/28/22 20:24 56-49-5 Methyl methanesulfonate ND ug/L 4.5 2.8 1 01/28/22 10:38 01/28/22 20:24 66-27-3 2-Methylnaphthalene ND ug/L 9.1 1.7 1 01/28/22 10:38 01/28/22 20:24 91-57-6 Methyl parathion ND ug/L 9.1 3.4 1 01/28/22 10:38 01/28/22 20:24 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 9.1 1.7 1 01/28/22 10:38 01/28/22 20:24 95-48-7 3&4-Methyl phenol (m&p ND ug/L 9.1 1.1 1 01/28/22 10:38 01/28/22 20:24 15831-10-4 Cresol) 1-Naphthalenamine ND ug/L 4.5 3.7 1 01/28/22 10:38 01/28/22 20:24 134-32-7 2-Naphthalenamine ND ug/L 9.1 5.0 1 01/28/22 10:38 01/28/22 20:24 91-59-8 Naphthalene ND ug/L 9.1 1.9 1 01/28/22 10:38 01/28/22 20:24 91-20-3 1,4-Naphthoquinone ND ug/L 4.5 4.0 1 01/28/22 10:38 01/28/22 20:24 130-15-4 2-Nitroaniline ND ug/L 18.2 2.7 1 01/28/22 10:38 01/28/22 20:24 88-74-4 3-Nitroaniline ND ug/L 18.2 3.4 1 01/28/22 10:38 01/28/22 20:24 99-09-2 4-Nitroaniline ND ug/L 18.2 4.6 1 01/28/22 10:38 01/28/22 20:24 100-01-6 Nitrobenzene ND ug/L 9.1 1.7 1 01/28/22 10:38 01/28/22 20:24 98-95-3 2-Nitrophenol ND ug/L 9.1 1.3 1 01/28/22 10:38 01/28/22 20:24 88-75-5 Date: 02/07/2022 03:04 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270E APP9 RV 4-Nitrophenol 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitroso-di-n-butylamine N-Nitroso-di-n- propylamine N-Nitrosodiphenylamine N- Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine O,O,O- Tri ethyl phosphorothioate 2,2'-Oxybis(1- chloropropane) Parathion (Ethyl parathion) Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol p-Phenylenediamine Phorate Pronamide Pyrene Pyridine Safrole 1,2,4,5- Tetrachlorobenzene 2,3,4,6-Tetrachlorophenol Thionazin O-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 1,3,5-Trinitrobenzene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) Date: 02/07/2022 03:04 PM Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte ND ug/L 45.5 6.0 1 01/28/22 10:38 01/28/22 20:24 100-02-7 ND ug/L 9.1 3.5 1 01/28/22 10:38 01/28/22 20:24 99-55-8 ND ug/L 9.1 2.1 1 01/28/22 10:38 01/28/22 20:24 55-18-5 ND ug/L 9.1 1.7 1 01/28/22 10:38 01/28/22 20:24 62-75-9 ND ug/L 9.1 7.9 1 01/28/22 10:38 01/28/22 20:24 924-16-3 ND ug/L 9.1 1.2 1 01/28/22 10:38 01/28/22 20:24 621-64-7 ND ug/L 9.1 2.7 1 01/28/22 10:38 01/28/22 20:24 86-30-6 ND ug/L 9.1 6.8 1 01/28/22 10:38 01/28/22 20:24 10595-95-6 ND ug/L 9.1 3.9 1 01/28/22 10:38 01/28/22 20:24 59-89-2 ND ug/L 9.1 2.3 1 01/28/22 10:38 01/28/22 20:24 100-75-4 ND ug/L 9.1 2.8 1 01/28/22 10:38 01/28/22 20:24 930-55-2 ND ug/L 9.1 2.3 1 01/28/22 10:38 01/28/22 20:24 126-68-1 ND ug/L 9.1 1.0 1 01/28/22 10:38 01/28/22 20:24 108-60-1 ND ug/L 9.1 3.5 1 01/28/22 10:38 01/28/22 20:24 56-38-2 ND ug/L 9.1 3.1 1 01/28/22 10:38 01/28/22 20:24 608-93-5 ND ug/L 9.1 3.0 1 01/28/22 10:38 01/28/22 20:24 82-68-8 ND ug/L 18.2 3.4 1 01/28/22 10:38 01/28/22 20:24 87-86-5 ND ug/L 9.1 3.3 1 01/28/22 10:38 01/28/22 20:24 62-44-2 ND ug/L 9.1 1.8 1 01/28/22 10:38 01/28/22 20:24 85-01-8 ND ug/L 9.1 1.2 1 01/28/22 10:38 01/28/22 20:24 108-95-2 ND ug/L 9.1 9.1 1 01/28/22 10:38 01/28/22 20:24 106-50-3 ND ug/L 9.1 3.2 1 01/28/22 10:38 01/28/22 20:24 298-02-2 ND ug/L 9.1 2.8 1 01/28/22 10:38 01/28/22 20:24 23950-58-5 ND ug/L 9.1 2.0 1 01/28/22 10:38 01/28/22 20:24 129-00-0 ND ug/L 9.1 2.4 1 01/28/22 10:38 01/28/22 20:24 110-86-1 ND ug/L 9.1 2.1 1 01/28/22 10:38 01/28/22 20:24 94-59-7 ND ug/L 9.1 4.1 1 01/28/22 10:38 01/28/22 20:24 95-94-3 ND ug/L 9.1 1.4 1 01/28/22 10:38 01/28/22 20:24 58-90-2 ND ug/L 9.1 2.6 1 01/28/22 10:38 01/28/22 20:24 297-97-2 ND ug/L 9.1 2.4 1 01/28/22 10:38 01/28/22 20:24 95-53-4 ND ug/L 9.1 1.6 1 01/28/22 10:38 01/28/22 20:24 120-82-1 ND ug/L 9.1 1.3 1 01/28/22 10:38 01/28/22 20:24 95-95-4 ND ug/L 9.1 1.4 1 01/28/22 10:38 01/28/22 20:24 88-06-2 ND ug/L 9.1 5.0 1 01/28/22 10:38 01/28/22 20:24 99-35-4 114 % 10-144 1 01/28/22 10:38 01/28/22 20:24 4165-60-0 114 % 10-130 1 01/28/22 10:38 01/28/22 20:24 321-60-8 97 % 34-163 1 01/28/22 10:38 01/28/22 20:24 1718-51-0 46 % 10-130 1 01/28/22 10:38 01/28/22 20:24 13127-88-3 58 % 10-130 1 01/28/22 10:38 01/28/22 20:24 367-12-4 109 % 10-144 1 01/28/22 10:38 01/28/22 20:24 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 Page 10 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene Ethyl methacrylate 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate Date: 02/07/2022 03:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 100 5.1 1 01/29/2210:36 67-64-1 ND ug/L 50.0 24.8 1 01 /29/22 10:36 75-05-8 ND ug/L 50.0 8.5 1 01 /29/22 10:36 107-02-8 ND ug/L 200 1.8 1 01/29/2210:36 107-13-1 ND ug/L 10.0 0.50 1 01/29/2210:36 107-05-1 2.4 ug/L 1.0 0.34 1 01 /29/22 10:36 71-43-2 ND ug/L 3.0 0.47 1 01 /29/22 10:36 74-97-5 ND ug/L 1.0 0.31 1 01 /29/22 10:36 75-27-4 ND ug/L 3.0 0.34 1 01/29/2210:36 75-25-2 ND ug/L 10.0 1.7 1 01/29/2210:36 74-83-9 ND ug/L 100 4.0 1 01/29/2210:36 78-93-3 ND ug/L 100 0.73 1 01/29/2210:36 75-15-0 ND ug/L 1.0 0.33 1 01/29/2210:36 56-23-5 ND ug/L 3.0 0.28 1 01/29/2210:36 108-90-7 ND ug/L 10.0 0.65 1 01/29/2210:36 75-00-3 ND ug/L 5.0 0.43 1 01 /29/22 10:36 67-66-3 ND ug/L 1.0 0.54 1 01 /29/22 10:36 74-87-3 ND ug/L 10.0 1.6 1 01/29/2210:36 126-99-8 ND ug/L 3.0 0.36 1 01/29/2210:36 124-48-1 ND ug/L 10.0 0.39 1 01/29/2210:36 74-95-3 ND ug/L 5.0 0.34 1 01/29/2210:36 95-50-1 ND ug/L 1.0 0.34 1 01/29/2210:36 541-73-1 0.54J ug/L 1.0 0.33 1 01/29/2210:36 106-46-7 ND ug/L 100 0.56 1 01/29/2210:36 110-57-6 ND ug/L 1.0 0.35 1 01 /29/22 10:36 75-71-8 0.94J ug/L 5.0 0.37 1 01/29/2210:36 75-34-3 ND ug/L 1.0 0.32 1 01/29/2210:36 107-06-2 ND ug/L 5.0 0.35 1 01/29/2210:36 75-35-4 3.4J ug/L 5.0 0.38 1 01/29/2210:36 156-59-2 ND ug/L 5.0 0.40 1 01/29/2210:36 156-60-5 ND ug/L 1.0 0.36 1 01/29/2210:36 78-87-5 ND ug/L 1.0 0.28 1 01 /29/22 10:36 142-28-9 ND ug/L 1.0 0.39 1 01 /29/22 10:36 594-20-7 ND ug/L 1.0 0.43 1 01 /29/22 10:36 563-58-6 ND ug/L 1.0 0.36 1 01 /29/22 10:36 10061-01-5 ND ug/L 1.0 0.36 1 01 /29/22 10:36 10061-02-6 ND ug/L 1.0 0.30 1 01 /29/22 10:36 100-41-4 ND ug/L 10.0 0.28 1 01 /29/22 10:36 97-63-2 ND ug/L 50.0 0.48 1 01 /29/22 10:36 591-78-6 ND ug/L 20.0 9.7 1 01 /29/22 10:36 74-88-4 ND ug/L 100 52.3 1 01/29/2210:36 78-83-1 ND ug/L 10.0 4.2 1 01 /29/22 10:36 126-98-7 ND ug/L 5.0 2.0 1 01 /29/22 10:36 75-09-2 ND ug/L 10.0 0.32 1 01 /29/22 10:36 80-62-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IH,M1, v1 IK Page 11 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 Sample: 1403-MW-2R Lab ID: 92584833001 Collected: 01/26/22 14:41 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 4-Methyl-2-pentanone ND ug/L 100 2.7 1 01/29/22 10:36 108-10-1 (MIBK) Propionitrile ND ug/L 20.0 3.6 1 01/29/22 10:36 107-12-0 Styrene ND ug/L 1.0 0.29 1 01/29/22 10:36 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.31 1 01/29/22 10:36 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.22 1 01/29/22 10:36 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 01/29/22 10:36 127-18-4 Toluene ND ug/L 1.0 0.48 1 01/29/22 10:36 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 01/29/22 10:36 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 01/29/22 10:36 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 01/29/22 10:36 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 01/29/22 10:36 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 01/29/22 10:36 96-18-4 Vinyl acetate ND ug/L 50.0 1.3 1 01/29/22 10:36 108-05-4 IH Vinyl chloride ND ug/L 1.0 0.39 1 01/29/22 10:36 75-01-4 Xylene (Total) 0.68J ug/L 5.0 0.34 1 01/29/22 10:36 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 01/29/22 10:36 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 01/29/22 10:36 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 01/29/22 10:36 2037-26-5 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 50.0 1 01/28/22 03:58 18496-25-8 4500CNE Cyanide, Total Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016 Pace Analytical Services -Asheville Cyanide ND ug/L 8.0 6.0 1 02/01/2216:45 02/02/2219:46 57-12-5 M1 Date: 02/07/2022 03:04 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 1810843 Analysis Method: EPA 8081 B QC Batch Method: 3510C Analysis Description: Pesticides (GC) 8081 B Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92584833001 METHOD BLANK: R3755972-1 Associated Lab Samples: 92584833001 Parameter Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor Heptachlor epoxide Methoxychlor alpha -Chlordane gamma -Chlordane Chlordane (Technical) Toxaphene Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Matrix: Water Units Blank Result Reporting Limit MDL Analyzed ug/L ND 0.0500 0.0198 02/01 /22 22:50 ug/L ND 0.0500 0.0172 02/01 /22 22:50 ug/L ND 0.0500 0.0208 02/01 /22 22:50 ug/L ND 0.0500 0.0150 02/01 /22 22:50 ug/L ND 0.0500 0.0209 02/01 /22 22:50 ug/L ND 0.0500 0.0177 02/01 /22 22:50 ug/L ND 0.0500 0.0154 02/01 /22 22:50 ug/L ND 0.0500 0.0198 02/01 /22 22:50 ug/L ND 0.0500 0.0162 02/01 /22 22:50 ug/L ND 0.0500 0.0160 02/01 /22 22:50 ug/L ND 0.0500 0.0164 02/01 /22 22:50 ug/L ND 0.0500 0.0217 02/01 /22 22:50 ug/L ND 0.0500 0.0161 02/01 /22 22:50 ug/L ND 0.0500 0.0237 02/01 /22 22:50 ug/L ND 0.0500 0.0219 02/01 /22 22:50 ug/L ND 0.0500 0.0148 02/01 /22 22:50 ug/L ND 0.0500 0.0183 02/01 /22 22:50 ug/L ND 0.0500 0.0193 02/01 /22 22:50 ug/L ND 0.0500 0.0149 02/01 /22 22:50 ug/L ND 0.0500 0.0137 02/01 /22 22:50 ug/L ND 5.00 0.0198 02/01 /22 22:50 ug/L ND 0.500 0.168 02/01 /22 22:50 % 43.7 10.0-128 02/01 /22 22:50 % 56.5 10.0-127 02/01 /22 22:50 LABORATORY CONTROL SAMPLE: R3755972-2 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aldrin ug/L 1.00 0.639 63.9 22.0-124 alpha-BHC ug/L 1.00 0.721 72.1 54.0-130 beta-BHC ug/L 1.00 0.663 66.3 53.0-136 delta-BHC ug/L 1.00 0.723 72.3 54.0-133 gamma-BHC (Lindane) ug/L 1.00 0.657 65.7 55.0-129 4,4'-DDD ug/L 1.00 0.667 66.7 56.0-140 4,4'-DDE ug/L 1.00 0.629 62.9 52.0-128 4,4'-DDT ug/L 1.00 0.689 68.9 50.0-141 Dieldrin ug/L 1.00 0.668 66.8 59.0-133 Endosulfan I ug/L 1.00 0.661 66.1 57.0-131 Endosulfan II ug/L 1.00 0.669 66.9 58.0-133 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 LABORATORY CONTROL SAMPLE: Parameter R3755972-2 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Endosulfan sulfate ug/L 1.00 0.667 66.7 58.0-133 Endrin ug/L 1.00 0.627 62.7 57.0-134 Endrin aldehyde ug/L 1.00 0.635 63.5 53.0-129 Endrin ketone ug/L 1.00 0.732 73.2 60.0-145 Heptachlor ug/L 1.00 0.708 70.8 27.0-132 Heptachlor epoxide ug/L 1.00 0.674 67.4 57.0-130 Methoxychlor ug/L 1.00 0.687 68.7 54.0-155 alpha -Chlordane ug/L 1.00 0.640 64.0 70.0-130 LO gamma -Chlordane ug/L 1.00 0.665 66.5 70.0-130 LO Decachlorobiphenyl (S) % 44.0 10.0-128 Tetrachloro-m-xylene (S) % 55.0 10.0-127 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3755972-3 MS L1455986-01 Spike Parameter Units Result Conc. MSD Spike Conc. R3755972-4 MS MSD Result Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Aldrin ug/L ND 1.00 1.00 0.450 0.438 45.0 43.8 10.0-141 2.70 40 alpha-BHC ug/L ND 1.00 1.00 0.596 0.614 59.6 61.4 10.0-145 2.98 40 beta-BHC ug/L ND 1.00 1.00 0.577 0.564 57.7 56.4 14.0-146 2.28 35 delta-BHC ug/L ND 1.00 1.00 0.643 0.623 64.3 62.3 17.0-143 3.16 38 gamma-BHC (Lindane) ug/L ND 1.00 1.00 0.601 0.602 60.1 60.2 14.0-141 0.166 40 4,4'-DDD ug/L ND 1.00 1.00 0.480 0.465 48.0 46.5 10.0-160 3.17 38 4,4'-DDE ug/L ND 1.00 1.00 0.406 0.400 40.6 40.0 10.0-159 1.49 35 4,4'-DDT ug/L ND 1.00 1.00 0.475 0.446 47.5 44.6 10.0-160 6.30 38 Dieldrin ug/L ND 1.00 1.00 0.503 0.504 50.3 50.4 10.0-158 0.199 38 Endosulfan I ug/L 0.0176 1.00 1.00 0.463 0.513 44.5 49.5 10.0-153 10.2 36 Endosulfan II ug/L ND 1.00 1.00 0.534 0.524 53.4 52.4 10.0-159 1.89 39 Endosulfan sulfate ug/L ND 1.00 1.00 0.547 0.534 54.7 53.4 23.0-147 2.41 35 Endrin ug/L ND 1.00 1.00 0.461 0.488 46.1 48.8 10.0-160 5.69 39 Endrin aldehyde ug/L ND 1.00 1.00 0.498 0.542 49.8 54.2 10.0-148 8.46 38 Endrin ketone ug/L ND 1.00 1.00 0.584 0.574 58.4 57.4 10.0-160 1.73 40 Heptachlor ug/L ND 1.00 1.00 0.533 0.525 53.3 52.5 16.0-136 1.51 40 Heptachlor epoxide ug/L ND 1.00 1.00 0.515 0.509 51.5 50.9 10.0-160 1.17 36 Methoxychlor ug/L ND 1.00 1.00 0.556 0.535 55.6 53.5 10.0-160 3.85 34 alpha -Chlordane ug/L ND 1.00 1.00 0.433 0.445 43.3 44.5 70.0-130 2.73 20 ML gamma -Chlordane ug/L ND 1.00 1.00 0.464 0.461 46.4 46.1 70.0-130 0.649 20 ML Decachlorobiphenyl (S) % 33.5 20.8 10.0-128 Tetrachloro-m-xylene (S) % 42.5 42.8 10.0-127 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 1811080 Analysis Method: EPA 8151 QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92584833001 METHOD BLANK: R3757563-1 Matrix: Water Associated Lab Samples: 92584833001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 2,4-D ug/L ND 2.00 0.547 02/07/22 05:18 Dinoseb ug/L ND 2.00 0.250 02/07/22 05:18 2,4,5-T ug/L ND 2.00 0.258 02/07/22 05:18 2,4,5-TP (Silvex) ug/L ND 2.00 0.335 02/07/22 05:18 2,4-DCAA (S) % 74 14.0-158 02/07/22 05:18 LABORATORY CONTROL SAMPLE & LCSD: R3757563-2 R3757563-3 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 2,4-D ug/L 5.00 4.77 4.83 95.4 96.6 50.0-120 1.25 20 Dinoseb ug/L 5.00 4.17 4.38 83.4 87.6 36.0-134 4.91 20 2,4,5-T ug/L 5.00 4.54 4.62 90.8 92.4 54.0-120 1.75 20 2,4,5-TP (Silvex) ug/L 5.00 3.99 4.09 79.8 81.8 50.0-125 2.48 20 2,4-DCAA (S) % 78.0 81.2 14.0-158 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 675122 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584833001 METHOD BLANK: 3533656 Associated Lab Samples: 92584833001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 0.78 02/01/2213:34 Arsenic ug/L ND 10.0 1.1 02/01/2213:34 Barium ug/L ND 100 0.67 02/01/2213:34 Beryllium ug/L ND 1.0 0.054 02/01/2213:34 Cadmium ug/L ND 1.0 0.11 02/01/2213:34 Chromium ug/L ND 10.0 1.1 02/01/2213:34 Cobalt ug/L ND 10.0 0.39 02/01/2213:34 Copper ug/L ND 10.0 0.50 02/01/2213:34 Lead ug/L ND 10.0 0.89 02/01/2213:34 Nickel ug/L ND 50.0 0.71 02/01/2213:34 Selenium ug/L ND 10.0 1.4 02/01/2213:34 Silver ug/L ND 10.0 0.44 02/01/2213:34 Thallium ug/L ND 5.5 0.18 02/01/2213:34 Tin ug/L ND 20.0 1.5 02/01/2213:34 Vanadium ug/L ND 25.0 1.9 02/01/2213:34 Zinc ug/L ND 10.0 7.0 02/01/2213:34 LABORATORY CONTROL SAMPLE: Parameter 3533657 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 109 109 80-120 Arsenic ug/L 100 99.6 100 80-120 Barium ug/L 100 104 104 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 106 106 80-120 Chromium ug/L 100 105 105 80-120 Cobalt ug/L 100 105 105 80-120 Copper ug/L 100 102 102 80-120 Lead ug/L 100 102 102 80-120 Nickel ug/L 100 105 105 80-120 Selenium ug/L 100 99.9 100 80-120 Silver ug/L 100 104 104 80-120 Thallium ug/L 100 99.5 100 80-120 Tin ug/L 100 103 103 80-120 Vanadium ug/L 100 108 108 80-120 Zinc ug/L 100 97.4 97 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Semi-Annual 92584833 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533658 3533659 MS MSD 92585102002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 107 108 107 108 75-125 1 20 Arsenic ug/L ND 100 100 103 104 101 103 75-125 1 20 Barium ug/L 23.1 100 100 130 128 107 105 75-125 2 20 Beryllium ug/L ND 100 100 110 108 110 108 75-125 2 20 Cadmium ug/L ND 100 100 105 108 105 108 75-125 3 20 Chromium ug/L 47.0 100 100 154 159 107 112 75-125 3 20 Cobalt ug/L ND 100 100 105 109 105 109 75-125 3 20 Copper ug/L ND 100 100 102 103 102 103 75-125 1 20 Lead ug/L ND 100 100 97.0 98.9 97 99 75-125 2 20 Nickel ug/L ND 100 100 107 108 106 107 75-125 1 20 Selenium ug/L ND 100 100 101 102 100 102 75-125 1 20 Silver ug/L ND 100 100 99.7 104 100 104 75-125 4 20 Thallium ug/L ND 100 100 99.0 100 99 100 75-125 1 20 Tin ug/L ND 100 100 104 106 104 105 75-125 1 20 Vanadium ug/L ND 100 100 117 121 110 114 75-125 4 20 Zinc ug/L ND 100 100 101 102 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 674967 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584833001 METHOD BLANK: 3532893 Matrix: Water Associated Lab Samples: 92584833001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.13 02/01/2210:19 LABORATORY CONTROL SAMPLE: 3532894 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.3 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532895 3532896 MS MSD 92583907032 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.1 2.4 85 96 75-125 13 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 674748 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584833001 METHOD BLANK: 3531774 Associated Lab Samples: 92584833001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 01/29/22 04:34 1,1,1-Trichloroethane ug/L ND 1.0 0.33 01/29/22 04:34 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 01/29/22 04:34 1,1,2-Trichloroethane ug/L ND 1.0 0.32 01/29/22 04:34 1,1-Dichloroethane ug/L ND 5.0 0.37 01/29/22 04:34 1,1-Dichloroethene ug/L ND 5.0 0.35 01/29/22 04:34 1,1-Dichloropropene ug/L ND 1.0 0.43 01/29/22 04:34 1,2,3-Trichloropropane ug/L ND 1.0 0.26 01/29/22 04:34 1,2-Dichlorobenzene ug/L ND 5.0 0.34 01/29/22 04:34 1,2-Dichloroethane ug/L ND 1.0 0.32 01/29/22 04:34 1,2-Dichloropropane ug/L ND 1.0 0.36 01/29/22 04:34 1,3-Dichlorobenzene ug/L ND 1.0 0.34 01/29/22 04:34 1,3-Dichloropropane ug/L ND 1.0 0.28 01/29/22 04:34 1,4-Dichlorobenzene ug/L ND 1.0 0.33 01/29/22 04:34 2,2-Dichloropropane ug/L ND 1.0 0.39 01/29/22 04:34 2-Butanone (MEK) ug/L ND 100 4.0 01/29/22 04:34 2-Hexanone ug/L ND 50.0 0.48 01/29/22 04:34 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 01/29/22 04:34 Acetone ug/L ND 100 5.1 01/29/22 04:34 Acetonitrile ug/L ND 50.0 24.8 01/29/22 04:34 Acrolein ug/L ND 50.0 8.5 01/29/22 04:34 Acrylonitrile ug/L ND 200 1.8 01/29/22 04:34 Allyl chloride ug/L ND 10.0 0.50 01/29/22 04:34 Benzene ug/L ND 1.0 0.34 01/29/22 04:34 Bromochloromethane ug/L ND 3.0 0.47 01/29/22 04:34 Bromodichloromethane ug/L ND 1.0 0.31 01/29/22 04:34 Bromoform ug/L ND 3.0 0.34 01/29/22 04:34 Bromomethane ug/L ND 10.0 1.7 01/29/22 04:34 Carbon disulfide ug/L ND 100 0.73 01/29/22 04:34 Carbon tetrachloride ug/L ND 1.0 0.33 01/29/22 04:34 Chlorobenzene ug/L ND 3.0 0.28 01/29/22 04:34 Chloroethane ug/L ND 10.0 0.65 01/29/22 04:34 Chloroform ug/L ND 5.0 0.43 01/29/22 04:34 Chloromethane ug/L ND 1.0 0.54 01/29/22 04:34 Chloroprene ug/L ND 10.0 1.6 01/29/22 04:34 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 01/29/22 04:34 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 01/29/22 04:34 Dibromochloromethane ug/L ND 3.0 0.36 01/29/22 04:34 Dibromomethane ug/L ND 10.0 0.39 01/29/22 04:34 Dichlorodifluoromethane ug/L ND 1.0 0.35 01/29/22 04:34 Qualifiers IH,v1 I:/ Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 METHOD BLANK: 3531774 Associated Lab Samples: 92584833001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Ethyl methacrylate ug/L ND 10.0 0.28 01/29/22 04:34 Ethylbenzene ug/L ND 1.0 0.30 01/29/22 04:34 lodomethane ug/L ND 20.0 9.7 01/29/22 04:34 Isobutanol ug/L ND 100 52.3 01/29/22 04:34 Methacrylonitrile ug/L ND 10.0 4.2 01/29/22 04:34 Methyl methacrylate ug/L ND 10.0 0.32 01/29/22 04:34 Methylene Chloride ug/L ND 5.0 2.0 01/29/22 04:34 Propionitrile ug/L ND 20.0 3.6 01/29/22 04:34 Styrene ug/L ND 1.0 0.29 01/29/22 04:34 Tetrachloroethene ug/L ND 1.0 0.29 01/29/22 04:34 Toluene ug/L ND 1.0 0.48 01/29/22 04:34 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 01/29/22 04:34 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 01/29/22 04:34 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 01/29/22 04:34 Trichloroethene ug/L ND 1.0 0.38 01/29/22 04:34 Trichlorofluoromethane ug/L ND 1.0 0.30 01/29/22 04:34 Vinyl acetate ug/L ND 50.0 1.3 01/29/22 04:34 Vinyl chloride ug/L ND 1.0 0.39 01/29/22 04:34 Xylene (Total) ug/L ND 5.0 0.34 01/29/22 04:34 1,2-Dichloroethane-d4 (S) % 101 70-130 01/29/22 04:34 4-Bromofluorobenzene (S) % 100 70-130 01/29/22 04:34 Toluene-d8(S) % 102 70-130 01/29/22 04:34 LABORATORY CONTROL SAMPLE: Parameter 3531775 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 47.8 96 70-130 1,1,1-Trichloroethane ug/L 50 47.2 94 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.1 94 70-130 1,1,2-Trichloroethane ug/L 50 47.0 94 70-130 1,1-Dichloroethane ug/L 50 48.5 97 70-130 1,1-Dichloroethene ug/L 50 52.8 106 70-132 1,1-Dichloropropene ug/L 50 48.0 96 70-131 1,2,3-Trichloropropane ug/L 50 45.5 91 70-130 1,2-Dichlorobenzene ug/L 50 47.2 94 70-130 1,2-Dichloroethane ug/L 50 45.3 91 70-130 1,2-Dichloropropane ug/L 50 47.2 94 70-130 1,3-Dichlorobenzene ug/L 50 47.0 94 70-130 1,3-Dichloropropane ug/L 50 48.1 96 70-130 1,4-Dichlorobenzene ug/L 50 47.0 94 70-130 2,2-Dichloropropane ug/L 50 47.4 95 70-130 2-Butanone (MEK) ug/L 100 95.OJ 95 70-133 2-Hexanone ug/L 100 96.7 97 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 95.9J 96 70-130 Qualifiers IH Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 41 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 LABORATORY CONTROL SAMPLE: Parameter 3531775 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Acetone ug/L 100 92.8J 93 70-144 Acetonitrile ug/L 500 489 98 68-134 Acrolein ug/L 250 477 191 32-200IH,v1 Acrylonitrile ug/L 250 265 106 70-130 Allyl chloride ug/L 50 47.4 95 70-134 Benzene ug/L 50 47.7 95 70-130 Bromochloromethane ug/L 50 47.4 95 70-130 Bromodichloromethane ug/L 50 45.7 91 70-130 Bromoform ug/L 50 47.5 95 70-131 Bromomethane ug/L 50 47.3 95 30-177 Carbon disulfide ug/L 50 49.2J 98 70-133 Carbon tetrachloride ug/L 50 46.7 93 70-130 Chlorobenzene ug/L 50 46.8 94 70-130 Chloroethane ug/L 50 29.4 59 46-131 IK Chloroform ug/L 50 46.9 94 70-130 Chloromethane ug/L 50 44.8 90 49-130 Chloroprene ug/L 50 50.0 100 70-130 cis-1,2-Dichloroethene ug/L 50 47.9 96 70-130 cis-1,3-Dichloropropene ug/L 50 49.2 98 70-130 Dibromochloromethane ug/L 50 48.8 98 70-130 Dibromomethane ug/L 50 44.7 89 70-130 Dichlorodifluoromethane ug/L 50 42.9 86 52-134 Ethyl methacrylate ug/L 50 49.6 99 70-130 Ethylbenzene ug/L 50 47.6 95 70-130 lodomethane ug/L 100 99.5 99 47-140 Isobutanol ug/L 1000 957 96 62-136 Methacrylonitrile ug/L 500 490 98 70-130 Methyl methacrylate ug/L 50 48.2 96 70-130 Methylene Chloride ug/L 50 47.6 95 68-130 Propionitrile ug/L 500 482 96 70-130 Styrene ug/L 50 50.5 101 70-130 Tetrachloroethene ug/L 50 45.7 91 70-130 Toluene ug/L 50 46.1 92 70-130 trans-1,2-Dichloroethene ug/L 50 49.7 99 70-130 trans- 1,3-Dichloropropene ug/L 50 48.4 97 70-130 trans-1,4-Dichloro-2-butene ug/L 50 47.3J 95 25-200 Trichloroethene ug/L 50 46.3 93 70-130 Trichlorofluoromethane ug/L 50 42.2 84 61-130 Vinyl acetate ug/L 100 116 116 70-140 IH Vinyl chloride ug/L 50 45.8 92 59-142 Xylene (Total) ug/L 150 147 98 70-130 1,2-Dichloroethane-d4 (S) % 92 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3531776 3531777 MS MSD 92584833001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.1 22.7 111 114 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 23.3 23.9 117 120 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.7 22.2 108 111 70-131 2 30 1,1,2-Trichloroethane ug/L ND 20 20 22.4 23.2 112 116 70-136 4 30 1,1-Dichloroethane ug/L 0.94J 20 20 24.5 25.2 118 121 70-147 3 30 1,1-Dichloroethene ug/L ND 20 20 26.5 27.0 133 135 70-158 2 30 1,1-Dichloropropene ug/L ND 20 20 23.9 24.5 119 122 70-149 3 30 1,2,3-Trichloropropane ug/L ND 20 20 21.0 21.9 105 110 67-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 22.3 22.9 112 115 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 21.8 22.4 109 112 67-138 3 30 1,2-Dichloropropane ug/L ND 20 20 22.6 23.5 113 117 70-138 4 30 1,3-Dichlorobenzene ug/L ND 20 20 22.4 23.4 112 117 70-133 4 30 1,3-Dichloropropane ug/L ND 20 20 21.8 22.9 109 115 70-136 5 30 1,4-Dichlorobenzene ug/L 0.54J 20 20 23.0 23.8 112 117 70-133 4 30 2,2-Dichloropropane ug/L ND 20 20 25.0 25.6 125 128 52-155 2 30 2-Butanone (MEK) ug/L ND 40 40 40.9J 43.1J 102 108 61-147 5 30 2-Hexanone ug/L ND 40 40 41.7J 44.8J 104 112 67-139 7 30 4-Methyl-2-pentanone ug/L ND 40 40 42.3J 43.8J 106 109 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 39.9J 40.8J 100 102 55-159 2 30 Acetonitrile ug/L ND 200 200 212 224 106 112 66-145 6 30 Acrolein ug/L ND 100 100 198 205 198 205 10-200 4 30 IH,M1, v1 Acrylonitrile ug/L ND 100 100 1081 112J 108 112 68-140 3 30 AIIyl chloride ug/L ND 20 20 23.1 25.0 116 125 70-147 8 30 Benzene ug/L 2.4 20 20 25.9 26.4 117 120 67-150 2 30 Bromochloromethane ug/L ND 20 20 22.2 23.0 111 115 70-146 3 30 Bromodichloromethane ug/L ND 20 20 22.1 22.8 110 114 70-138 3 30 Bromoform ug/L ND 20 20 21.4 22.0 107 110 57-138 3 30 Bromomethane ug/L ND 20 20 27.6 27.0 138 135 10-200 2 30 Carbon disulfide ug/L ND 20 20 24.6J 25AJ 123 127 70-152 3 30 v2 Carbon tetrachloride ug/L ND 20 20 23.5 24.3 118 121 70-147 3 30 Chlorobenzene ug/L ND 20 20 22.6 23.6 113 118 70-137 4 30 Chloroethane ug/L ND 20 20 20.9 21.0 105 105 51-166 0 30 IK Chloroform ug/L ND 20 20 22.5 23.0 113 115 70-144 2 30 Chloromethane ug/L ND 20 20 22.0 22.7 110 113 24-161 3 30 Chloroprene ug/L ND 20 20 24.5 25.2 122 126 70-143 3 30 cis-1,2-Dichloroethene ug/L 3AJ 20 20 26.4 27.5 115 120 67-148 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.6 23.7 113 118 70-142 5 30 Dibromochloromethane ug/L ND 20 20 22.3 23.5 111 117 68-138 5 30 Dibromomethane ug/L ND 20 20 21.3 22.1 106 111 70-134 4 30 Dichlorodifluoromethane ug/L ND 20 20 21.9 22.3 110 111 43-155 2 30 Ethyl methacrylate ug/L ND 20 20 22.3 23.4 111 117 70-137 5 30 Ethylbenzene ug/L ND 20 20 23.5 24.2 118 121 68-143 3 30 Iodomethane ug/L ND 40 40 38.5 44.5 96 111 20-161 15 30 Isobutanol ug/L ND 400 400 388 411 97 103 44-145 6 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3531776 3531777 MS MSD 92584833001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Methacrylonitrile ug/L ND 200 200 213 223 106 111 67-139 5 30 Methyl methacrylate ug/L ND 20 20 21.4 22.7 107 113 70-130 6 30 Methylene Chloride ug/L ND 20 20 23.2 23.8 116 119 64-148 3 30 Propionitrile ug/L ND 200 200 212 217 106 109 70-138 3 30 Styrene ug/L ND 20 20 24.1 24.8 121 124 70-136 3 30 Tetrachloroethene ug/L ND 20 20 22.8 23.7 114 118 70-139 4 30 Toluene ug/L ND 20 20 22.8 23.7 114 118 47-157 4 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.9 25.2 124 126 70-149 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.4 23.4 112 117 70-138 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 14.9J 15.9J 75 79 31-145 6 30 Trichloroethene ug/L ND 20 20 23.3 23.9 116 120 70-149 3 30 Tri ch lo rofl u oro m eth a n e ug/L ND 20 20 21.2 21.6 106 108 61-154 2 30 Vinyl acetate ug/L ND 40 40 48.7J 51.6 122 129 48-156 6 30 IH Vinyl chloride ug/L ND 20 20 23.2 23.9 116 119 55-172 3 30 Xylene (Total) ug/L 0.68J 60 60 73.4 75.6 121 125 66-145 3 30 1,2-Dichloroethane-d4 (S) % 99 99 70-130 4-Bromofluorobenzene (S) % 102 103 70-130 Toluene-d8 (S) % 99 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 675726 Analysis Method: EPA 8011 QC Batch Method: EPA 8011 Analysis Description: GCS 8011 EDB DBCP Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584833001 METHOD BLANK: 3536638 Matrix: Water Associated Lab Samples: 92584833001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,2-Dibromo-3-chloropropane ug/L ND 0.20 0.0026 02/03/22 12:17 1,2-Dibromoethane (EDB) ug/L ND 0.050 0.0075 02/03/22 12:17 1-Chloro-2-bromopropane (S) % 92 60-140 02/03/22 12:17 LABORATORY CONTROL SAMPLE & LCSD: 3536639 3536640 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,2-Dibromo-3-chloropropane ug/L 0.25 0.26 0.191 104 75 60-140 32 20 R1 1,2-Dibromoethane (EDB) ug/L 0.25 0.22 0.20 88 80 60-140 9 20 1-Chloro-2-bromopropane (S) % 95 90 60-140 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3536642 3536643 MS MSD 92585193002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2-Dibromo-3- ug/L ND 0.24 0.24 0.20 0.20 83 82 60-140 2 20 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 0.24 0.24 0.20 0.21 83 85 60-140 1 20 1-Chloro-2-bromopropane % 94 95 60-140 (S) SAMPLE DUPLICATE: 3536641 92585193001 Dup Parameter Units Result Result 1,2-Dibromo-3-chloropropane ug/L ND ND 1,2-Dibromoethane (EDB) ug/L ND ND 1-Chloro-2-bromopropane (S) % 94 89 Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 674836 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584833001 METHOD BLANK: 3532152 Matrix: Water Associated Lab Samples: 92584833001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.21 02/02/22 13:21 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.23 02/02/22 13:21 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.23 02/02/22 13:21 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.25 02/02/22 13:21 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.29 02/02/22 13:21 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.21 02/02/22 13:21 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.16 02/02/22 13:21 Decachlorobiphenyl (S) % 131 10-181 02/02/22 13:21 LABORATORY CONTROL SAMPLE: 3532153 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 4.8 95 41-137 PCB-1260 (Aroclor 1260) ug/L 5 4.7 94 42-156 Decachlorobiphenyl (S) % 122 10-181 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532154 3532155 MS MSD 92585070002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 9.1 9.1 8.7 9.2 96 101 22-145 5 30 PCB-1260 (Aroclor 1260) ug/L ND 9.1 9.1 8.2 8.5 90 94 10-167 4 30 Decachlorobiphenyl (S) % 112 115 10-181 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 674451 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584833001 METHOD BLANK: 3530290 Associated Lab Samples: 92584833001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 4.5 01/28/22 15:16 1,2,4-Trichlorobenzene ug/L ND 10.0 1.7 01/28/22 15:16 1,2-Dichlorobenzene ug/L ND 10.0 1.8 01/28/22 15:16 1,3,5-Trinitrobenzene ug/L ND 10.0 5.5 01/28/22 15:16 1,3-Dichlorobenzene ug/L ND 10.0 1.6 01/28/22 15:16 1,3-Dinitrobenzene ug/L ND 10.0 3.8 01/28/22 15:16 1,4-Dichlorobenzene ug/L ND 10.0 1.7 01/28/22 15:16 1,4-Naphthoquinone ug/L ND 5.0 4.4 01/28/22 15:16 1-Naphthalenamine ug/L ND 5.0 4.1 01/28/22 15:16 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 1.2 01/28/22 15:16 2,3,4,6-Tetrachlorophenol ug/L ND 10.0 1.5 01/28/22 15:16 2,4,5-Trichlorophenol ug/L ND 10.0 1.4 01/28/22 15:16 2,4,6-Trichlorophenol ug/L ND 10.0 1.6 01/28/22 15:16 2,4-Dichlorophenol ug/L ND 10.0 1.4 01/28/22 15:16 2,4-Dimethylphenol ug/L ND 10.0 1.7 01/28/22 15:16 2,4-Dinitrophenol ug/L ND 50.0 26.0 01/28/22 15:16 2,4-Dinitrotoluene ug/L ND 10.0 1.6 01/28/22 15:16 2,6-Dinitrotoluene ug/L ND 10.0 1.7 01/28/22 15:16 2-Acetylaminofluorene ug/L ND 10.0 4.1 01/28/22 15:16 2-Chloronaphthalene ug/L ND 10.0 1.7 01/28/22 15:16 2-Chlorophenol ug/L ND 10.0 1.2 01/28/22 15:16 2-Methylnaphthalene ug/L ND 10.0 1.9 01/28/22 15:16 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.9 01/28/22 15:16 2-Naphthalenamine ug/L ND 10.0 5.4 01/28/22 15:16 2-Nitroaniline ug/L ND 20.0 3.0 01/28/22 15:16 2-Nitrophenol ug/L ND 10.0 1.4 01/28/22 15:16 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 1.2 01/28/22 15:16 3,3'-Dichlorobenzidine ug/L ND 20.0 8.1 01/28/22 15:16 3,3'-Dimethylbenzidine ug/L ND 50.0 31.1 01/28/22 15:16 3-Methylcholanthrene ug/L ND 10.0 5.8 01/28/22 15:16 3-Nitroaniline ug/L ND 20.0 3.8 01/28/22 15:16 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 3.4 01/28/22 15:16 4-Aminobiphenyl ug/L ND 10.0 4.7 01/28/22 15:16 4-Bromophenylphenyl ether ug/L ND 10.0 1.8 01/28/22 15:16 4-ChIoro-3-methyl phenol ug/L ND 10.0 3.3 01/28/22 15:16 4-Chloroaniline ug/L ND 20.0 3.6 01/28/22 15:16 4-Chlorophenylphenyl ether ug/L ND 10.0 2.0 01/28/22 15:16 4-Nitroaniline ug/L ND 20.0 5.1 01/28/22 15:16 4-Nitrophenol ug/L ND 50.0 6.6 01/28/22 15:16 5-Nitro-o-toluidine ug/L ND 10.0 3.8 01/28/22 15:16 v1 v1 v1 IH Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 METHOD BLANK: 3530290 Associated Lab Samples: 92584833001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 3.0 01/28/22 15:16 Acenaphthene ug/L ND 10.0 2.0 01/28/22 15:16 Acenaphthylene ug/L ND 10.0 2.0 01/28/22 15:16 Acetophenone ug/L ND 10.0 1.5 01/28/22 15:16 Anthracene ug/L ND 10.0 2.3 01/28/22 15:16 Benzo(a)anthracene ug/L ND 10.0 2.7 01/28/22 15:16 Benzo(a)pyrene ug/L ND 10.0 2.8 01/28/22 15:16 Benzo(b)fluoranthene ug/L ND 10.0 2.6 01/28/22 15:16 Benzo(g,h,i)perylene ug/L ND 10.0 2.8 01/28/22 15:16 Benzo(k)fluoranthene ug/L ND 10.0 2.7 01/28/22 15:16 Benzoic Acid ug/L ND 50.0 3.4 01/28/22 15:16 Benzyl alcohol ug/L ND 20.0 2.9 01/28/22 15:16 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.8 01/28/22 15:16 bis(2-Chloroethyl) ether ug/L ND 10.0 1.9 01/28/22 15:16 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 3.7 01/28/22 15:16 Butylbenzylphthalate ug/L ND 10.0 3.1 01/28/22 15:16 Carbazole ug/L ND 10.0 2.4 01/28/22 15:16 Chlorobenzilate ug/L ND 10.0 3.8 01/28/22 15:16 Chrysene ug/L ND 10.0 2.8 01/28/22 15:16 Di-n-butylphthalate ug/L ND 10.0 2.2 01/28/22 15:16 Di-n-octylphthalate ug/L ND 10.0 3.9 01/28/22 15:16 Diallate ug/L ND 10.0 3.4 01/28/22 15:16 Dibenz(a,h)anthracene ug/L ND 10.0 3.0 01/28/22 15:16 Dibenzofuran ug/L ND 10.0 2.1 01/28/22 15:16 Diethylphthalate ug/L ND 10.0 2.0 01/28/22 15:16 Dimethoate ug/L ND 10.0 3.7 01/28/22 15:16 Dimethylphthalate ug/L ND 10.0 2.1 01/28/22 15:16 Ethyl methanesulfonate ug/L ND 20.0 3.0 01/28/22 15:16 Famphur ug/L ND 10.0 6.1 01/28/22 15:16 Fluoranthene ug/L ND 10.0 2.2 01/28/22 15:16 Fluorene ug/L ND 10.0 2.1 01/28/22 15:16 Hexachloro-1,3-butadiene ug/L ND 10.0 1.8 01/28/22 15:16 Hexachlorobenzene ug/L ND 10.0 2.2 01/28/22 15:16 Hexachlorocyclopentadiene ug/L ND 10.0 1.6 01/28/22 15:16 Hexachloroethane ug/L ND 10.0 1.4 01/28/22 15:16 Hexachloropropene ug/L ND 10.0 7.0 01/28/22 15:16 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 2.9 01/28/22 15:16 Isodrin ug/L ND 10.0 2.8 01/28/22 15:16 Isophorone ug/L ND 10.0 1.7 01/28/22 15:16 Isosafrole ug/L ND 10.0 2.5 01/28/22 15:16 Kepone ug/L ND 20.0 14.1 01/28/22 15:16 Methapyrilene ug/L ND 50.0 17.0 01/28/22 15:16 Methyl methanesulfonate ug/L ND 5.0 3.1 01/28/22 15:16 Methyl parathion ug/L ND 10.0 3.7 01/28/22 15:16 N-Nitroso-di-n-butylamine ug/L ND 10.0 8.7 01/28/22 15:16 IH v1 v1 IH Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 METHOD BLANK: 3530290 Associated Lab Samples: 92584833001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 01/28/22 15:16 N-Nitrosodiethylamine ug/L ND 10.0 2.3 01/28/22 15:16 N-Nitrosodimethylamine ug/L ND 10.0 1.9 01/28/22 15:16 N-Nitrosodiphenylamine ug/L ND 10.0 3.0 01/28/22 15:16 N-Nitrosomethylethylamine ug/L ND 10.0 7.5 01/28/22 15:16 N-Nitrosomorpholine ug/L ND 10.0 4.2 01/28/22 15:16 N-Nitrosopiperidine ug/L ND 10.0 2.5 01/28/22 15:16 N-Nitrosopyrrolidine ug/L ND 10.0 3.1 01/28/22 15:16 Naphthalene ug/L ND 10.0 2.1 01/28/22 15:16 Nitrobenzene ug/L ND 10.0 1.9 01/28/22 15:16 O,O,O-Triethylphosphorothioate ug/L ND 10.0 2.6 01/28/22 15:16 O-Toluidine ug/L ND 10.0 2.6 01/28/22 15:16 P-Dimethylaminoazobenzene ug/L ND 5.0 2.4 01/28/22 15:16 p-Phenylenediamine ug/L ND 10.0 10.0 01/28/22 15:16 Parathion (Ethyl parathion) ug/L ND 10.0 3.9 01/28/22 15:16 Pentachlorobenzene ug/L ND 10.0 3.4 01/28/22 15:16 Pentachloronitrobenzene ug/L ND 10.0 3.3 01/28/22 15:16 Pentachlorophenol ug/L ND 20.0 3.8 01/28/22 15:16 Phenacetin ug/L ND 10.0 3.6 01/28/22 15:16 Phenanthrene ug/L ND 10.0 2.0 01/28/22 15:16 Phenol ug/L ND 10.0 1.4 01/28/22 15:16 Phorate ug/L ND 10.0 3.6 01/28/22 15:16 Pronamide ug/L ND 10.0 3.1 01/28/22 15:16 Pyrene ug/L ND 10.0 2.2 01/28/22 15:16 Pyridine ug/L ND 10.0 2.6 01/28/22 15:16 Safrole ug/L ND 10.0 2.3 01/28/22 15:16 Thionazin ug/L ND 10.0 2.9 01/28/22 15:16 2,4,6-Tribromophenol (S) % 104 10-144 01/28/22 15:16 2-Fluorobiphenyl (S) % 96 10-130 01/28/22 15:16 2-Fluorophenol (S) % 60 10-130 01/28/22 15:16 Nitrobenzene-d5 (S) % 89 10-144 01/28/22 15:16 Phenol-d6 (S) % 43 10-130 01/28/22 15:16 Terphenyl-d14 (S) % 97 34-163 01/28/22 15:16 v1 IL v1 v1 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 3530291 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4,5-Tetrachlorobenzene ug/L 50 35.2 70 17-130 1,2,4-Trichlorobenzene ug/L 50 30.2 60 18-130 1,2-Dichlorobenzene ug/L 50 26.6 53 20-130 1,3,5-Trinitrobenzene ug/L 50 52.8 106 44-200 v1 1,3-Dichlorobenzene ug/L 50 25.6 51 18-130 1,3-Dinitrobenzene ug/L 50 44.5 89 39-159 1,4-Dichlorobenzene ug/L 50 26.2 52 18-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 LABORATORY CONTROL SAMPLE: Parameter 3530291 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,4-Naphthoquinone ug/L 50 28.8 58 10-159 1-Naphthalenamine ug/L 50 32.5 65 10-130 2,2'-Oxybis(1-chloropropane) ug/L 50 38.4 77 28-130 2,3,4,6-Tetrachlorophenol ug/L 50 41.1 82 10-200 v1 2,4,5-Trichlorophenol ug/L 50 40.7 81 35-130 2,4,6-Trichlorophenol ug/L 50 39.8 80 31-130 2,4-Dichlorophenol ug/L 50 35.7 71 35-130 2,4-Dimethylphenol ug/L 50 34.1 68 34-130 2,4-Dinitrophenol ug/L 250 165 66 10-153 v1 2,4-Dinitrotoluene ug/L 50 40.0 80 37-136 2,6-Dinitrotoluene ug/L 50 41.5 83 33-136 2-Acetylaminofluorene ug/L 50 39.3 79 19-181 2-Chloronaphthalene ug/L 50 35.4 71 26-130 2-Chlorophenol ug/L 50 31.3 63 37-130 2-Methylnaphthalene ug/L 50 33.3 67 29-130 2-Methylphenol(o-Cresol) ug/L 50 31.3 63 35-130 2-Naphthalenamine ug/L 50 32.7 65 10-136 2-Nitroaniline ug/L 100 69.5 69 37-130 2-Nitrophenol ug/L 50 35.7 71 32-130 3&4-Methyl phenol (m&p Cresol) ug/L 50 32.0 64 34-130 3,3'-Dichlorobenzidine ug/L 100 77.1 77 34-136 3,3'-Dimethylbenzidine ug/L 100 85.2 85 10-200lH 3-Methylcholanthrene ug/L 50 43.3 87 39-190 3-Nitroaniline ug/L 100 74.7 75 37-138 4,6-Dinitro-2-methyl phenol ug/L 100 72.7 73 21-157 4-Aminobiphenyl ug/L 50 28.0 56 17-137 4-Bromophenylphenyl ether ug/L 50 39.3 79 38-130 4-Chloro-3-methylphenol ug/L 100 68.2 68 37-130 4-Chloroaniline ug/L 100 65.9 66 38-130 4-Chlorophenylphenyl ether ug/L 50 41.4 83 33-130 4-Nitroaniline ug/L 100 70.7 71 42-137 4-Nitrophenol ug/L 250 121 48 10-130 5-Nitro-o-toluidine ug/L 50 42.4 85 39-170 7,12-Dimethylbenz(a)anthracene ug/L 50 46.3 93 33-139 Acenaphthene ug/L 50 38.1 76 33-130 Acenaphthylene ug/L 50 37.5 75 35-130 Acetophenone ug/L 50 33.9 68 36-130 Anthracene ug/L 50 33.4 67 48-130 Benzo(a)anthracene ug/L 50 37.3 75 48-137 Benzo(a)pyrene ug/L 50 46.9 94 49-138 Benzo(b)fluoranthene ug/L 50 51.8 104 52-138 Benzo(g,h,i)perylene ug/L 50 49.3 99 48-140 Benzo(k)fluoranthene ug/L 50 48.6 97 48-139 Benzoic Acid ug/L 250 50.7 20 10-130 Benzyl alcohol ug/L 100 62.5 62 35-130 bis(2-Chloroethoxy)methane ug/L 50 35.1 70 34-130 bis(2-Chloroethyl) ether ug/L 50 35.8 72 36-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 41 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 LABORATORY CONTROL SAMPLE: Parameter 3530291 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers bis(2-Ethylhexyl)phthalate ug/L 50 33.7 67 32-165 Butylbenzylphthalate ug/L 50 35.8 72 34-161 Carbazole ug/L 50 33.8 68 47-130 Chlorobenzilate ug/L 50 35.1 70 43-176 Chrysene ug/L 50 37.2 74 47-131 Di-n-butylphthalate ug/L 50 33.9 68 39-144 Di-n-octylphthalate ug/L 50 35.4 71 30-170 Diallate ug/L 50 29.7 59 33-143 Dibenz(a,h)anthracene ug/L 50 48.6 97 49-138 Dibenzofuran ug/L 50 39.2 78 33-130 Diethylphthalate ug/L 50 38.4 77 38-131 Dimethoate ug/L 50 30.4 61 46-173 Dimethylphthalate ug/L 50 39.2 78 37-130 Ethyl methanesulfonate ug/L 50 33.5 67 33-133 Famphur ug/L 100 67.8 68 10-1301H Fluoranthene ug/L 50 38.4 77 46-137 Fluorene ug/L 50 39.7 79 37-130 Hexachloro-1,3-butadiene ug/L 50 29.3 59 11-130 v1 Hexachlorobenzene ug/L 50 38.0 76 38-130 Hexachlorocyclopentadiene ug/L 50 30.1 60 10-130 Hexachloroethane ug/L 50 22.8 46 14-130 Hexachloropropene ug/L 50 18.0 36 10-130 v1 Indeno(1,2,3-cd)pyrene ug/L 50 48.7 97 41-130 Isodrin ug/L 50 34.3 69 36-139 Isophorone ug/L 50 35.0 70 33-130 Isosafrole ug/L 50 35.9 72 22-130 Kepone ug/L 100 64.5 64 10-130 Methapyrilene ug/L 50 ND 18 10-1731H Methyl methanesulfonate ug/L 50 31.7 63 33-130 Methyl parathion ug/L 50 37.0 74 39-200 N-Nitroso-di-n-butylamine ug/L 50 29.6 59 22-130 N-Nitroso-di-n-propylamine ug/L 50 38.3 77 36-130 N-Nitrosodiethylamine ug/L 50 33.8 68 23-136 N-Nitrosodimethylamine ug/L 50 41.4 83 34-130 v1 N-Nitrosodiphenylamine ug/L 50 32.6 65 37-130 N-Nitrosomethylethylamine ug/L 50 39.9 80 18-137 N-Nitrosomorpholine ug/L 50 40.1 80 24-156 N-Nitrosopiperidine ug/L 50 35.5 71 25-142 N-Nitrosopyrrolidine ug/L 50 34.6 69 24-146 Naphthalene ug/L 50 30.3 61 30-130 Nitrobenzene ug/L 50 35.7 71 36-130 O,O,O-Triethylphosphorothioate ug/L 50 38.7 77 29-130 O-Toluidine ug/L 50 31.5 63 27-132 P-Dimethylaminoazobenzene ug/L 50 17.6 35 17-130IL p-Phenylenediamine ug/L ND Parathion (Ethyl parathion) ug/L 50 36.7 73 32-200 Pentachlorobenzene ug/L 50 40.9 82 27-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 41 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 LABORATORY CONTROL SAMPLE: Parameter 3530291 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Pentachloronitrobenzene ug/L 50 47.6 95 47-164 Pentachlorophenol ug/L 100 74.9 75 23-149 Phenacetin ug/L 50 34.4 69 44-181 Phenanthrene ug/L 50 35.0 70 44-130 Phenol ug/L 50 22.7 45 18-130 Phorate ug/L 50 43.3 87 18-183 v1 Pronamide ug/L 50 36.5 73 45-163 Pyrene ug/L 50 37.0 74 47-134 Pyridine ug/L 50 25.7 51 10-130 v1 Safrole ug/L 50 33.9 68 27-130 Thionazin ug/L 50 34.9 70 36-162 2,4,6-Tribromophenol (S) % 80 10-144 2-Fluorobiphenyl (S) % 74 10-130 2-Fluorophenol (S) % 49 10-130 Nitrobenzene-d5 (S) % 72 10-144 Phenol-d6 (S) % 39 10-130 Terphenyl-d14 (S) % 73 34-163 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530292 MS 92584838004 Spike Parameter Units Result Conc. MSD Spike Conc. 3530293 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 90.9 90.9 95.6 92.4 105 102 10-130 3 30 1,2,4-Trichlorobenzene ug/L ND 90.9 90.9 80.2 75.8 88 83 10-130 6 30 1,2-Dichlorobenzene ug/L ND 90.9 90.9 66.0 63.6 73 70 10-130 4 30 1,3,5-Trinitrobenzene ug/L ND 90.9 90.9 143 132 157 145 50-200 8 30 v1 1,3-Dichlorobenzene ug/L ND 90.9 90.9 62.4 60.1 69 66 10-130 4 30 1,3-Dinitrobenzene ug/L ND 90.9 90.9 115 105 127 115 43-161 9 30 1,4-Dichlorobenzene ug/L ND 90.9 90.9 66.1 61.9 73 68 10-130 6 30 1,4-Naphthoquinone ug/L ND 90.9 90.9 86.3 70.1 95 77 10-184 21 30 1-Naphthalenamine ug/L ND 90.9 90.9 90.1 76.5 99 84 10-130 16 30 2,2'-Oxybis(1- ug/L ND 90.9 90.9 93.6 88.6 103 97 12-142 5 30 chloropropane) 2,3,4,6-Tetrachlorophenol ug/L ND 90.9 90.9 103 95.1 114 105 10-198 8 30 v1 2,4,5-Trichlorophenol ug/L ND 90.9 90.9 104 99.0 114 109 10-143 5 30 2,4,6-Trichlorophenol ug/L ND 90.9 90.9 97.9 94.0 108 103 10-147 4 30 2,4-Dichlorophenol ug/L ND 90.9 90.9 88.3 86.7 97 95 10-138 2 30 2,4-Dimethylphenol ug/L ND 90.9 90.9 84.8 80.5 93 89 25-130 5 30 2,4-Dinitrophenol ug/L ND 455 455 440 467 97 103 10-165 6 30 v1 2,4-Dinitrotoluene ug/L ND 90.9 90.9 106 97.4 116 107 29-148 8 30 2,6-Dinitrotoluene ug/L ND 90.9 90.9 104 98.0 115 108 26-146 6 30 2-Acetylam inofl uorene ug/L ND 90.9 90.9 107 93.4 117 103 27-172 13 30 2-Chloronaphthalene ug/L ND 90.9 90.9 90.5 85.7 100 94 11-130 5 30 2-Chlorophenol ug/L ND 90.9 90.9 73.7 72.8 81 80 10-133 1 30 2-Methyl naphthalene ug/L ND 90.9 90.9 84.2 80.1 93 88 13-130 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530292 MS 92584838004 Spike Parameter Units Result Conc. MSD Spike Conc. 3530293 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 2-Methyl phenol(o-Cresol) ug/L ND 90.9 90.9 79.5 75.4 87 83 20-130 5 30 2-Naphthalenamine ug/L ND 90.9 90.9 57.7 65.7 63 72 10-135 13 30 2-Nitroaniline ug/L ND 182 182 185 170 102 93 24-136 8 30 2-Nitrophenol ug/L ND 90.9 90.9 83.0 84.2 91 93 10-153 2 30 3&4-Methylphenol(m&p ug/L ND 90.9 90.9 79.9 78.9 88 87 16-130 1 30 Cresol) 3,3'-Dichlorobenzidine ug/L ND 182 182 204 175 112 96 10-153 15 30 3,3'-Dimethylbenzidine ug/L ND 182 182 315 186 173 103 10-200 51 30 IH,R1 3-Methylcholanthrene ug/L ND 90.9 90.9 118 103 129 113 53-181 14 30 3-Nitroaniline ug/L ND 182 182 201 177 111 98 22-151 13 30 4,6-Dinitro-2-methylphenol ug/L ND 182 182 193 179 106 99 10-180 7 30 4-Aminobiphenyl ug/L ND 90.9 90.9 76.0 58.7 84 65 10-139 26 30 4-Bromophenylphenyl ether ug/L ND 90.9 90.9 97.0 88.2 107 97 25-130 10 30 4-Chloro-3-methylphenol ug/L ND 182 182 168 164 92 90 25-133 2 30 4-Chloroaniline ug/L ND 182 182 161 155 88 85 14-132 4 30 4-Chlorophenylphenyl ether ug/L ND 90.9 90.9 105 95.9 115 106 19-130 9 30 4-Nitroaniline ug/L ND 182 182 197 172 109 95 29-150 14 30 4-Nitrophenol ug/L ND 455 455 407 376 89 83 10-130 8 30 5-Nitro-o-toluidine ug/L ND 90.9 90.9 118 102 130 112 48-163 15 30 7,12- ug/L ND 90.9 90.9 121 110 134 121 40-140 10 30 Dimethylbenz(a)anthracene Acenaphthene ug/L ND 90.9 90.9 96.4 90.6 106 100 16-130 6 30 Acenaphthylene ug/L ND 90.9 90.9 96.0 89.8 106 99 15-137 7 30 Acetophenone ug/L ND 90.9 90.9 79.6 78.0 88 86 28-130 2 30 Anthracene ug/L ND 90.9 90.9 87.7 78.3 97 86 37-136 11 30 Benzo(a)anth race ne ug/L ND 90.9 90.9 100 87.7 110 96 40-145 13 30 Benzo(a)pyrene ug/L ND 90.9 90.9 126 111 139 123 41-146 12 30 Benzo(b)fluoranthene ug/L ND 90.9 90.9 139 124 153 137 39-151 11 30 M1 Benzo(g,h,i)perylene ug/L ND 90.9 90.9 135 118 149 130 40-147 14 30 M1 Benzo(k)fluoranthene ug/L ND 90.9 90.9 130 114 142 125 40-146 13 30 Benzoic Acid ug/L ND 455 455 160 212 35 47 10-130 28 30 Benzyl alcohol ug/L ND 182 182 154 149 85 82 25-130 4 30 bis(2- ug/L ND 90.9 90.9 86.5 83.1 95 91 23-130 4 30 Chloroethoxy)methane bis(2-Chloroethyl) ether ug/L ND 90.9 90.9 85.2 82.8 94 91 25-130 3 30 bis(2- Ethyl hexyl)phthalate ug/L ND 90.9 90.9 90.1 78.5 99 86 28-166 14 30 Butylbenzylphthalate ug/L ND 90.9 90.9 94.4 83.1 104 91 33-165 13 30 Carbazole ug/L ND 90.9 90.9 89.4 79.1 98 87 40-137 12 30 Chlorobenzilate ug/L ND 90.9 90.9 89.6 80.8 99 89 55-170 10 30 Chrysene ug/L ND 90.9 90.9 99.0 85.6 109 94 38-141 14 30 Di-n-butylphthalate ug/L ND 90.9 90.9 89.6 78.7 99 87 32-153 13 30 Di-n-octylphthalate ug/L ND 90.9 90.9 99.4 83.3 109 92 30-175 18 30 Diallate ug/L ND 90.9 90.9 78.1 69.7 86 77 39-141 11 30 Dibenz(a,h)anthracene ug/L ND 90.9 90.9 136 119 150 131 39-148 13 30 M1 Dibenzofuran ug/L ND 90.9 90.9 97.8 91.1 108 100 20-130 7 30 Diethylphthalate ug/L ND 90.9 90.9 99.2 89.1 109 98 28-142 11 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530292 MS 92584838004 Spike Parameter Units Result Conc. Dimethoate Dimethylphthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isodrin Isophorone Isosafrole Kepone Methapyrilene Methyl methanesulfonate Methyl parathion N-Nitroso-di-n-butylamine N-Nitroso-di-n-propylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine Naphthalene Nitrobenzene O,O,O- Triethylphosphorothioate O-Toluidine P- Dimethylaminoazobenzene p-Phenylenediamine Parathion (Ethyl parathion) Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol Phorate Pronamide Pyrene 3530293 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits ug/L ND 90.9 90.9 81.1 74.3 89 82 57-167 ug/L ND 90.9 90.9 99.7 90.4 110 99 26-136 ug/L ND 90.9 90.9 80.4 80.3 88 88 38-134 ug/L ND 182 182 128 131 70 72 10-130 ug/L ND 90.9 90.9 101 87.9 111 97 39-143 ug/L ND 90.9 90.9 101 93.1 112 102 24-132 ug/L ND 90.9 90.9 78.3 75.3 86 83 10-130 ug/L ND 90.9 90.9 94.6 86.3 104 95 29-130 ug/L ND 90.9 90.9 82.4 81.1 91 89 10-130 ug/L ND 90.9 90.9 57.1 54.9 63 60 10-130 ug/L ND 90.9 90.9 72.7 72.0 80 79 10-130 ug/L ND 90.9 90.9 133 117 146 129 39-148 ug/L ND 90.9 90.9 88.8 78.7 98 87 45-138 ug/L ND 90.9 90.9 86.3 84.1 95 92 23-130 ug/L ND 90.9 90.9 92.7 85.3 102 94 25-130 ug/L ND 182 182 109 138 60 76 10-130 ug/L ND 90.9 90.9 64AJ ND 71 27 10-181 ug/L ND 90.9 90.9 79.7 78.7 88 87 31-130 ug/L ND 90.9 90.9 94.6 87.4 104 96 53-197 ug/L ND 90.9 90.9 73.3 70.6 81 78 28-130 ug/L ND 90.9 90.9 87.7 85.7 96 94 25-130 ug/L ND 90.9 90.9 80.2 82.2 88 90 29-132 ug/L ND 90.9 90.9 111 109 122 120 22-130 ug/L ND 90.9 90.9 84.0 75.8 92 83 26-134 ug/L ND 90.9 90.9 101 91.8 111 101 24-133 ug/L ND 90.9 90.9 98.6 94.2 108 104 15-164 ug/L ND 90.9 90.9 84.7 81.0 93 89 29-141 ug/L ND 90.9 90.9 82.9 82.7 91 91 29-140 ug/L ND 90.9 90.9 77.8 74.0 86 81 14-130 ug/L ND 90.9 90.9 87.8 83.8 97 92 25-130 ug/L ND 90.9 90.9 88.5 88.0 97 97 30-130 Max RPD RPD Qual 9 30 10 30 0 30 2 30 IH 14 30 8 30 4 30 v1 9 30 2 30 4 30 1 30 v1 13 30 12 30 3 30 8 30 24 30 30 IH 1 30 8 30 4 30 2 30 2 30 1 30 v1 10 30 10 30 5 30 4 30 0 30 5 30 5 30 1 30 ug/L ND 90.9 90.9 78.6 74.6 86 82 27-130 5 30 ug/L ND 90.9 90.9 47.2 41.2 52 45 20-130 13 30 IL ug/L ND ND ND 30 ug/L ND 90.9 90.9 102 86.3 112 95 48-200 16 30 ug/L ND 90.9 90.9 103 96.5 113 106 23-130 6 30 ug/L ND 90.9 90.9 121 112 133 123 57-159 8 30 ug/L ND 182 182 190 171 104 94 10-175 10 30 ug/L ND 90.9 90.9 91.9 81.8 101 90 57-179 12 30 ug/L ND 90.9 90.9 90.9 80.9 100 89 36-133 12 30 ug/L ND 90.9 90.9 65.6 63.9 72 70 10-130 3 30 ug/L ND 90.9 90.9 115 103 127 114 21-192 11 30 v1 ug/L ND 90.9 90.9 95.4 84.3 105 93 55-162 12 30 ug/L ND 90.9 90.9 97.0 85.5 107 94 40-143 13 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530292 MS 92584838004 Spike Parameter Units Result Conc. MSD Spike Conc. 3530293 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual Pyridine ug/L ND 90.9 90.9 77.1 72.0 85 79 10-130 7 30 v1 Safrole ug/L ND 90.9 90.9 85.9 82.9 94 91 25-130 4 30 Thionazin ug/L ND 90.9 90.9 92.5 85.1 102 94 50-157 8 30 2,4,6-Tribromophenol (S) % 109 98 10-144 2-Fluorobiphenyl (S) % 97 91 10-130 2-Fluorophenol(S) % 68 69 10-130 Nitrobenzene-d5(S) % 94 92 10-144 Phenol-d6 (S) % 62 60 10-130 Terphenyl-d14 (S) % 101 91 34-163 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 674438 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584833001 METHOD BLANK: 3530256 Matrix: Water Associated Lab Samples: 92584833001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 01/28/22 03:56 LABORATORY CONTROL SAMPLE: 3530257 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 502 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530258 3530259 MS MSD 92584883001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 513 546 100 106 80-120 6 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530260 3530261 MS MSD 92584833001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 499 490 99 97 80-120 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 41 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 QC Batch: 675043 Analysis Method: SM 4500-CN-E-2016 QC Batch Method: SM 4500-CN-E-2016 Analysis Description: 450OCNE Cyanide, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584833001 METHOD BLANK: 3533363 Matrix: Water Associated Lab Samples: 92584833001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide ug/L ND 8.0 6.0 02/02/2219:45 LABORATORY CONTROL SAMPLE: 3533364 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cyanide ug/L 100 102 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533365 3533366 MS MSD 92584833001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L ND 100 100 73.8 78.5 72 77 80-120 6 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533367 3533368 MS MSD 92584285002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide ug/L ND 100 100 54.8 48.1 53 47 80-120 13 10 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 41 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Foothills LF/Semi-Annual Pace Project No.: 92584833 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased low. R1 RPD value was outside control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF/Semi-Annual 92584833 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92584833001 1403-MW-2R 676084 92584833001 1403-MW-2R 3510C 1810843 EPA 8081 B 1810843 92584833001 1403-MW-2R 8151A 1811080 EPA8151 1811080 92584833001 1403-MW-2R EPA 8011 675726 EPA 8011 675825 92584833001 1403-MW-2R EPA 3510C 674836 EPA 8082A 675532 92584833001 1403-MW-2R EPA 3005A 675122 EPA 6020B 675233 92584833001 1403-MW-2R EPA 7470A 674967 EPA 7470A 675135 92584833001 1403-MW-2R EPA 3510C 674451 EPA 8270E 674605 92584833001 1403-MW-2R EPA 8260D 674748 92584833001 1403-MW-2R SM 4500-S2D-2011 674438 92584833001 1403-MW-2R SM 4500-CN-E-2016 675043 SM 4500-CN-E-2016 675372 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 03:04 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 41 h,�, •](770) Pace Ana"cal Services, Inc. CHAIN OF CUSTODY RECORD Ce a l 110 TECHNOLOGY PARKWAY, PEACHTREE CORNERS, GA 30M PAGE: 1 OF 16 73"20U : FAX (770) 73"2U1 : Www.PaoelabS.com M - - - REPUBLIC SERVICES OF NC nl\1"kL r aJv rtiG1.4 ur—Q 1 CLr V P P P A I A I A V ^TM� .TENT ADDRESSIPHONE NUMBERIFAX NUMBER: 1 3 4 5 7 1 7 7 7 C (00 04 CO LO Go Mao N c�i CO :PORT TO: STEVE JETT CC: O N 1 N W W 00 o :QUESTED COMPLETION DATE: PO # T = C co STANDARD TAT A W "t CO)o W W C)� O OD O ODo V_ CO W J ;OJECT NAMEISTATE: I REPUBLIC - FOOTHILLS LF - NORTH CAROLINA -1403 e a LL ° m g O W 0 #: ;OJECT R U (0 (L a S 1 1 1 — eZI� Id.l 1 1 1 C G DATE TIME MATRIX CODE* 0 M R SAMPLE IDENTIFICATION I A a a In (Ln. a. a a P a a a¢ I a¢ a a I a 1W:4 GW X 1403 - MW - 2R 17 X i X I X1 X X X X X A P - PLASTIC 1 - MCI, Svc B A - AMBER GLASS 2 - H2SO4, a-C G - CLEAR GLASS 3 - HNO3 V - VOA VIAL 1 4 - NOON, 98°C 1 S - STERILE 5 - NsOHgjft 9S'C D O - OTHER S - N82SJ%. a-C 7 - WC not frozen N U 'MATRIX CODES: B DW - DRINKING WATER S - SOIL E M - WASTEWATER SL- SLUDGE RW - GROUNDWATER SD - SOLID SW - SURFACE WATER A -AIR ST - STORM WATER L - LIQUID W - WATER P - PRODUCT REMARKSIADDTTIONAL INFORMATION 1 Bob Chiodo - ES&S RECEIVED BY: DATErrIME: i RELINQUISHED BY: DATEITIME: WO#:92584833 71; nGvl.-" 6t&— . UPS FED -EX LISPS COURIER CLIEN- IIIIII �I II�III I �tl �II dQKkw; : CuModyB•il- ofCoolera CnddrlD; vbr No RA -Yes Msc biWct _ Oftim W flwmnt 92564833 Document Name: Document Revised: November 15, 2021 d,,'�,�; . Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document No.: Issuing Authority: celC� F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples:. Asheville ❑ Edell Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[:] Atlanta Kernersville❑ Sample Condition Client me:Upor Receipt Proj1 • 92584833 - -e- S� I* . G W0 Courier: ed Ex ❑UPS P1� MP Duo Dais: 02/07/22 ❑LISPS OC�ient ❑ Commercial ❑Pace / her: CLIENT'e'�� M ��r )A'�_ GAReIp�C — Custody Seal Present? ETYes []No Seals Intact? es ❑No Date/initials Person Examining Contents: f �,_'Z PackingMaterial: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue Froze Thermometer• Oyes [:]No A t R Gun Ill ❑Wet ❑Blue ❑None Type of Ice: Correction Factor: Cooler temp: Add/Subtract ('C) Temp should be above freezing to 6'C []Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): 7 has begun USDA Regulated Soil (❑ N/A, water sampl Did samples originate in a quarantine zone within the United States: CA, NY. or SC (check maps}? Did samples originate from a foreign source (internationally, ❑Yes []No including Hawaii and Puerto Rico)? []Yes []No Comments/Discrepancy: Chain of Custody Presents Ys ❑No []N/A 1, Samples Arrived within Hold Times es c [:Ill 2. _ Short Hold Time Analysis (<72 hr.l? ❑Yes No [-]N/A 3 _ Rush Turn Around Time Requested? ❑Yes No Ci N/A F 4. Sufficient Volume? Yes ❑No N/A 5. _ Correct Containers Used? es [--]No []N/A 6. -Pace Containers Used? Q�Yes ❑No ❑N/A Containers Intact? _ Yes No ❑N/A 7. Dissolved analysis: Samples Field Filtered? Yes []No Eyn/A B. Sample Labels Match COC? Ows ❑No ❑N/A 9 G_w -Includes Date/Time/ID/Anal is Matrix: 30 11. Heads ace in VOA Vials (>5-6mm)? ❑Yes N/A Trip Blank Present? ❑Yes ❑N/ Trip Blank Custody Seals Present? I�lYes IllflN/A COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOWTION Person contacted: Project Manager SCURF Review: Date/Time: Date: Field Data Required? ❑Yes ❑No Project Manager SRF Review: Date: Page 40 of 41 Document Name: Condition Upon Recei; Document No.: F-CAR-CS-033-Rev.08 "Check mark top half of box if pH and/or dechlorination is Project verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles Document Revised: November 15, 2021 Paae 2 of 2 Issuing Authority: Pace Carolinas Quality Office W0#:92584833 PM' IrIP DueDate: 02/07/22 CLIENT: GARepNC N ry Z N CL z N = Q ? W N fn Z } z •} 47 d d a V V = °b « ^ _ ILd d N V d N N V V V 2 `� C 5 Z = Z 2 +U�! ? Y +• N {� I \ Z 1 \ Z ti: O y is at z fY Ol CL 7 V (S 7 U G 7 V c = O Z S N Q N 2 O Z f6 V � ` a c V V 2 CL c W V O N = Q '^ 2 L E q J = z _ (� O N � M yL N v a C a O rn C '^ U� 2 a y V «' N N 2 z C fi c � R 9 c o A VI a c N ro CL J N m a J N ev a J Z A 1 m n J '', A a J V ... M a J U a J y c E d a E q N s E ¢ E ¢ J E q y E ¢ _ E o N 2 ¢ O Z q O 7 ¢ 4 7 M, S ¢ O 7 Y Q, N i+ Jc m y = :: = .°: N V '.. i J G! a E ¢ J = c N W E q LM o N g IA :: rl E E N E n ,Ny 3�_ d rl `m rl c N a �.y E N m fa O E 0 Y E g E E ° '° v E eJ E Ln N E Ln N E O E N E Y E r C d m M 6 m N d m .'-I 4 Com ��1 Q O. fZiYe�Y d Co 6 as a m t7 a .=1 C7 a fn V' a .Ni t7 41 M {7 a M l7 ¢ G=f lS o O~1 C7 } O� L7 y 0 l7 a d O a {7 N d V, N CLO. V, M m a 47 a V� of o 1Xv zN N\� N \N 3 4 5 6 7 11 9 10 11 I- 12 \�\M IN N\N I --- t I I I I I NN I 1-i pH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certifcation Off ce ( .e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 41 of 41 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 07, 2022 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF/Leachate Pace Project No.: 92584814 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 27, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Eden • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, r J� Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 30 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92584814 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 Virginia/VELAP Certification M 460025 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Foothills LF/Leachate Pace Project No.: 92584814 Lab ID Sample ID SAMPLE SUMMARY Matrix Date Collected Date Received 92584814001 1403-Leachate Water 01/26/22 16:35 01/27/22 10:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Foothills LF/Leachate Pace Project No.: 92584814 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92584814001 1403-Leachate EPA 350.1 Rev 2.0 1993 AMI 1 PASI-E EPA6020B CW1 15 PASI-GA EPA 7470A VB 1 PASI-GA SM 2540C-2015 ALW 1 PASI-GA SM 2540D-2015 BTS 1 PASI-GA SM 4500-H+B-2011 TBM 1 PASI-GA SM 521OB-2016 TBM 1 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C EPA 300.0 Rev 2.1 1993 CDC 3 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-E = Pace Analytical Services - Eden PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Foothills LF/Leachate Pace Project No.: 92584814 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92584814001 1403-Leachate EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia 1070000 ug/L 20000 01/31/22 14:59 Performed by ES&S 01/26/22 16:35 pH 7.86 Std. Units 01/26/22 16:35 Temperature 17.6 deg C 01/26/22 16:35 Specific Conductance 26,000 umhos/cm 01/26/22 16:35 Turbidity 22.80 NTU 01/26/22 16:35 EPA6020B Antimony 107J ug/L 150 02/01/2213:51 D3 EPA6020B Arsenic 213J ug/L 250 02/01/2213:51 D3 EPA6020B Barium 437J ug/L 2500 02/01/2213:51 D3 EPA6020B Chromium 378 ug/L 250 02/01/2213:51 EPA6020B Cobalt 33.2J ug/L 250 02/01/2213:51 D3 EPA6020B Copper 273 ug/L 250 02/01/2213:51 EPA6020B Nickel 172J ug/L 1250 02/01/2213:51 D3 EPA6020B Vanadium 97.2J ug/L 625 02/01/2213:51 D3 SM 2540C-2015 Total Dissolved Solids 4960000 ug/L 200000 02/02/22 17:22 SM 2540D-2015 Total Suspended Solids 11000 ug/L 5000 01/28/22 11:25 SM 4500-H+B-2011 pH at 25 Degrees C 7.9 Std. Units 0.10 01/28/22 13:14 H3 SM 521OB-2016 BOD, 5 day 302000 ug/L 2000 02/02/22 14:30 EPA 8260D Acetone 4830 ug/L 2000 02/02/22 06:05 EPA 8260D 2-Butanone (MEK) 2240 ug/L 2000 02/02/22 06:05 EPA 8260D Ethylbenzene 23.7 ug/L 20.0 02/02/22 06:05 EPA 8260D Toluene 19.6J ug/L 20.0 02/02/22 06:05 EPA 8260D Xylene (Total) 44.7J ug/L 100 02/02/22 06:05 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 143 ug/L 5.0 01/31/22 16:05 EPA 300.0 Rev 2.1 1993 Sulfate 21600 ug/L 20000 01 /27/22 23:32 EPA 351.2 Rev 2.0 1993 Nitrogen, Kjeldahl, Total 1290000 ug/L 50000 01/29/22 03:14 EPA 365.1 Rev 2.0 1993 Phosphorus 7730 ug/L 250 02/03/22 23:06 SM 5220D-2011 Chemical Oxygen Demand 2810000 ug/L 100000 02/04/22 23:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92584814 Sample: 1403-Leachate Lab ID: 92584814001 Collected: 01/26/22 16:35 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 1070000 ug/L 20000 5420 200 01/31/22 14:59 7664-41-7 Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by ES&S 1 01/26/22 16:35 pH 7.86 Std. Units 1 01/26/22 16:35 Temperature 17.6 deg C 1 01/26/22 16:35 Specific Conductance 26,000 umhos/c 1 01/26/22 16:35 m Turbidity 22.80 NTU 1 01/26/22 16:35 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 107J ug/L 150 19.5 5 02/01/22 09:47 02/01/22 13:51 7440-36-0 Arsenic 213J ug/L 250 28.3 5 02/01/22 09:47 02/01/22 13:51 7440-38-2 Barium 437J ug/L 2500 16.8 5 02/01/22 09:47 02/01/22 13:51 7440-39-3 Beryllium ND ug/L 25.0 1.3 5 02/01/22 09:47 02/01/22 13:51 7440-41-7 Cadmium ND ug/L 25.0 2.8 5 02/01/22 09:47 02/01/22 13:51 7440-43-9 Chromium 378 ug/L 250 27.4 5 02/01/22 09:47 02/01/22 13:51 7440-47-3 Cobalt 33.2J ug/L 250 9.9 5 02/01/22 09:47 02/01/22 13:51 7440-48-4 Copper 273 ug/L 250 12.6 5 02/01/22 09:47 02/01/22 13:51 7440-50-8 Lead ND ug/L 250 22.2 5 02/01/22 09:47 02/01/22 13:51 7439-92-1 Nickel 172J ug/L 1250 17.7 5 02/01/22 09:47 02/01/22 13:51 7440-02-0 Selenium ND ug/L 250 34.2 5 02/01/22 09:47 02/01/22 13:51 7782-49-2 Silver ND ug/L 250 10.9 5 02/01/22 09:47 02/01/22 13:51 7440-22-4 Thallium ND ug/L 138 4.5 5 02/01/22 09:47 02/01/22 13:51 7440-28-0 Vanadium 97.2J ug/L 625 46.5 5 02/01/22 09:47 02/01/22 13:51 7440-62-2 Zinc ND ug/L 250 174 5 02/01/22 09:47 02/01/22 13:51 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Peachtree Corners, GA Mercury ND ug/L 0.20 0.13 1 01/31/2215:00 02/01/2211:21 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services - Peachtree Corners, GA Total Dissolved Solids 4960000 ug/L 200000 200000 1 02/02/22 17:22 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Peachtree Corners, GA Total Suspended Solids 11000 ug/L 5000 5000 1 01/28/22 11:25 4500H+ pH, Electrometric ATL Analytical Method: SM 4500-H+B-2011 Pace Analytical Services - Peachtree Corners, GA pH at 25 Degrees C 7.9 Std. Units 0.10 0.10 1 01/28/22 13:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 H3 Page 6 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92584814 Sample: 1403-Leachate Lab ID: 92584814001 Collected: 01/26/22 16:35 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 5210B BOD, 5 day BOD, 5 day 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene Date: 02/07/2022 02:04 PM Analytical Method: SM 521OB-2016 Preparation Method: SM 521OB-2016 Pace Analytical Services - Peachtree Corners, GA 302000 ug/L 2000 2000 1 01/27/2217:10 02/02/2214:30 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 4830 ug/L 2000 102 20 02/02/22 06:05 67-64-1 ND ug/L 4000 37.0 20 02/02/22 06:05 107-13-1 ND ug/L 20.0 6.9 20 02/02/22 06:05 71-43-2 ND ug/L 60.0 9.4 20 02/02/22 06:05 74-97-5 ND ug/L 20.0 6.1 20 02/02/22 06:05 75-27-4 ND ug/L 60.0 6.8 20 02/02/22 06:05 75-25-2 ND ug/L 200 33.2 20 02/02/22 06:05 74-83-9 2240 ug/L 2000 79.2 20 02/02/22 06:05 78-93-3 ND ug/L 2000 14.6 20 02/02/22 06:05 75-15-0 ND ug/L 20.0 6.7 20 02/02/22 06:05 56-23-5 ND ug/L 60.0 5.7 20 02/02/22 06:05 108-90-7 ND ug/L 200 13.0 20 02/02/22 06:05 75-00-3 ND ug/L 100 8.6 20 02/02/22 06:05 67-66-3 ND ug/L 20.0 10.8 20 02/02/22 06:05 74-87-3 ND ug/L 260 6.8 20 02/02/22 06:05 96-12-8 v2 v2 ND ug/L 60.0 7.2 20 02/02/22 06:05 124-48-1 ND ug/L 40.0 5.4 20 02/02/22 06:05 106-93-4 ND ug/L 200 7.9 20 02/02/22 06:05 74-95-3 ND ug/L 100 6.8 20 02/02/22 06:05 95-50-1 ND ug/L 20.0 6.7 20 02/02/22 06:05 106-46-7 ND ug/L 2000 11.1 20 02/02/22 06:05 110-57-6 v1 ND ug/L 100 7.3 20 02/02/22 06:05 75-34-3 ND ug/L 20.0 6.4 20 02/02/22 06:05 107-06-2 ND ug/L 100 7.0 20 02/02/22 06:05 75-35-4 ND ug/L 100 7.7 20 02/02/22 06:05 156-59-2 ND ug/L 100 7.9 20 02/02/22 06:05 156-60-5 ND ug/L 20.0 7.1 20 02/02/22 06:05 78-87-5 ND ug/L 20.0 7.3 20 02/02/22 06:05 10061-01-5 ND ug/L 20.0 7.3 20 02/02/22 06:05 10061-02-6 23.7 ug/L 20.0 6.1 20 02/02/22 06:05 100-41-4 ND ug/L 1000 9.5 20 02/02/22 06:05 591-78-6 ND ug/L 400 194 20 02/02/22 06:05 74-88-4 ND ug/L 100 39.0 20 02/02/22 06:05 75-09-2 ND ug/L 2000 54.2 20 02/02/22 06:05 108-10-1 ND ug/L 20.0 5.8 20 02/02/22 06:05 100-42-5 ND ug/L 100 6.2 20 02/02/22 06:05 630-20-6 ND ug/L 60.0 4.5 20 02/02/22 06:05 79-34-5 ND ug/L 20.0 5.8 20 02/02/22 06:05 127-18-4 19.6J ug/L 20.0 9.7 20 02/02/22 06:05 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Foothills LF/Leachate Pace Project No.: 92584814 Sample: 1403-Leachate Lab ID: 92584814001 Collected: 01/26/22 16:35 Received: 01/27/22 10:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 300.0 IC anions 48hr Nitrate as N Nitrite as N Sulfate 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 365.1 Phosphorus, Total Phosphorus 5220D COD Chemical Oxygen Demand Date: 02/07/2022 02:04 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 20.0 6.6 20 02/02/22 06:05 71-55-6 ND ug/L 20.0 6.5 20 02/02/22 06:05 79-00-5 ND ug/L 20.0 7.7 20 02/02/22 06:05 79-01-6 ND ug/L 20.0 6.0 20 02/02/22 06:05 75-69-4 ND ug/L 20.0 5.2 20 02/02/22 06:05 96-18-4 ND ug/L 1000 26.2 20 02/02/22 06:05 108-05-4 ND ug/L 20.0 7.7 20 02/02/22 06:05 75-01-4 44.7J ug/L 100 6.8 20 02/02/22 06:05 1330-20-7 97 % 70-130 20 02/02/22 06:05 460-00-4 100 % 70-130 20 02/02/22 06:05 17060-07-0 97 % 70-130 20 02/02/22 06:05 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 143 ug/L 5.0 2.2 2.5 01 /31 /22 16:05 123-91-1 103 % 70-130 2.5 01/31/2216:05 17060-07-0 CO 99 % 66-133 2.5 01 /31 /22 16:05 2037-26-5 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville ND ug/L 2000 1200 20 01/27/22 23:32 14797-55-8 D3,M1 ND ug/L 2000 1000 20 01/27/22 23:32 14797-65-0 D3,M1 21600 ug/L 20000 10000 20 01/27/22 23:32 14808-79-8 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville 1290000 ug/L 50000 25000 100 01/28/22 16:41 01/29/22 03:14 7727-37-9 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville 7730 ug/L 250 125 5 02/03/22 18:26 02/03/22 23:06 7723-14-0 Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville 2810000 ug/L 100000 50000 1 02/04/22 03:26 02/04/22 23:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674901 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92584814001 METHOD BLANK: 3532541 Associated Lab Samples: 92584814001 Parameter Units Nitrogen, Ammonia ug/L LABORATORY CONTROL SAMPLE: 3532542 Parameter Units Nitrogen, Ammonia ug/L Matrix: Water Blank Reporting Result Limit ND 100 Spike LCS Conc. Result 5000 5170 MDL Analyzed Qualifiers 27.1 01/31/22 14:11 LCS % Rec % Rec Limits Qualifiers 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532543 3532544 MS MSD 92585132001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia ug/L 58.3 mg/L 5000 5000 69200 68400 218 202 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532545 3532546 MS MSD 92585135001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia ug/L 38.1 mg/L 5000 5000 44300 42300 126 86 90-110 5 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 675122 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584814001 METHOD BLANK: 3533656 Associated Lab Samples: 92584814001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 6.0 0.78 02/01/2213:34 Arsenic ug/L ND 10.0 1.1 02/01/2213:34 Barium ug/L ND 100 0.67 02/01/2213:34 Beryllium ug/L ND 1.0 0.054 02/01/2213:34 Cadmium ug/L ND 1.0 0.11 02/01/2213:34 Chromium ug/L ND 10.0 1.1 02/01/2213:34 Cobalt ug/L ND 10.0 0.39 02/01/2213:34 Copper ug/L ND 10.0 0.50 02/01/2213:34 Lead ug/L ND 10.0 0.89 02/01/2213:34 Nickel ug/L ND 50.0 0.71 02/01/2213:34 Selenium ug/L ND 10.0 1.4 02/01/2213:34 Silver ug/L ND 10.0 0.44 02/01/2213:34 Thallium ug/L ND 5.5 0.18 02/01/2213:34 Vanadium ug/L ND 25.0 1.9 02/01/2213:34 Zinc ug/L ND 10.0 7.0 02/01/2213:34 LABORATORY CONTROL SAMPLE: Parameter 3533657 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 109 109 80-120 Arsenic ug/L 100 99.6 100 80-120 Barium ug/L 100 104 104 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 106 106 80-120 Chromium ug/L 100 105 105 80-120 Cobalt ug/L 100 105 105 80-120 Copper ug/L 100 102 102 80-120 Lead ug/L 100 102 102 80-120 Nickel ug/L 100 105 105 80-120 Selenium ug/L 100 99.9 100 80-120 Silver ug/L 100 104 104 80-120 Thallium ug/L 100 99.5 100 80-120 Vanadium ug/L 100 108 108 80-120 Zinc ug/L 100 97.4 97 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Foothills LF/Leachate 92584814 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533658 3533659 MS MSD 92585102002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 107 108 107 108 75-125 1 20 Arsenic ug/L ND 100 100 103 104 101 103 75-125 1 20 Barium ug/L 23.1 100 100 130 128 107 105 75-125 2 20 Beryllium ug/L ND 100 100 110 108 110 108 75-125 2 20 Cadmium ug/L ND 100 100 105 108 105 108 75-125 3 20 Chromium ug/L 47.0 100 100 154 159 107 112 75-125 3 20 Cobalt ug/L ND 100 100 105 109 105 109 75-125 3 20 Copper ug/L ND 100 100 102 103 102 103 75-125 1 20 Lead ug/L ND 100 100 97.0 98.9 97 99 75-125 2 20 Nickel ug/L ND 100 100 107 108 106 107 75-125 1 20 Selenium ug/L ND 100 100 101 102 100 102 75-125 1 20 Silver ug/L ND 100 100 99.7 104 100 104 75-125 4 20 Thallium ug/L ND 100 100 99.0 100 99 100 75-125 1 20 Vanadium ug/L ND 100 100 117 121 110 114 75-125 4 20 Zinc ug/L ND 100 100 101 102 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674967 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584814001 METHOD BLANK: 3532893 Matrix: Water Associated Lab Samples: 92584814001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.13 02/01/2210:19 LABORATORY CONTROL SAMPLE: 3532894 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.3 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532895 3532896 MS MSD 92583907032 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.1 2.4 85 96 75-125 13 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 675522 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584814001 METHOD BLANK: 3535377 Associated Lab Samples: 92584814001 Parameter Units Total Dissolved Solids ug/L LABORATORY CONTROL SAMPLE: 3535378 Parameter Units Total Dissolved Solids ug/L SAMPLE DUPLICATE: 3535379 Parameter Units Total Dissolved Solids ug/L Matrix: Water Blank Reporting Result Limit MDL Analyzed Qualifiers ND 10000 10000 02/02/22 17:20 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 400000 382000 96 80-120 92583955021 Dup Max Result Result RPD RPD Qualifiers 290 mg/L 301000 4 25 SAMPLE DUPLICATE: 3535380 92584814001 Dup Parameter Units Result Result Total Dissolved Solids ug/L 4960000 4580000 Max RPD RPD Qualifiers 8 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674549 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584814001 METHOD BLANK: 3530601 Matrix: Water Associated Lab Samples: 92584814001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids ug/L ND 5000 5000 01/28/22 11:20 LABORATORY CONTROL SAMPLE: 3530602 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids ug/L 100000 98000 98 90-110 SAMPLE DUPLICATE: 3530603 92584753001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids ug/L <5.0 mg/L ND 25 SAMPLE DUPLICATE: 3530604 92584769001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids ug/L 7.8 mg/L 7400 5 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674545 Analysis Method: SM 4500-H+B-2011 QC Batch Method: SM 4500-H+B-2011 Analysis Description: 4500H+B pH ATL Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584814001 SAMPLE DUPLICATE: 3530593 92584891005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.6 8.6 0 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674407 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92584814001 METHOD BLANK: 3530161 Matrix: Water Associated Lab Samples: 92584814001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 02/02/22 13:41 B3 LABORATORY CONTROL SAMPLE: 3530162 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 186000 94 84.6-115 SAMPLE DUPLICATE: 3530164 92584769001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 4.7 mg/L 4320 9 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 675330 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584814001 METHOD BLANK: 3534535 Associated Lab Samples: 92584814001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.31 02/02/22 00:53 1,1,1-Trichloroethane ug/L ND 1.0 0.33 02/02/22 00:53 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.22 02/02/22 00:53 1,1,2-Trichloroethane ug/L ND 1.0 0.32 02/02/22 00:53 1,1-Dichloroethane ug/L ND 5.0 0.37 02/02/22 00:53 1,1-Dichloroethene ug/L ND 5.0 0.35 02/02/22 00:53 1,2,3-Trichloropropane ug/L ND 1.0 0.26 02/02/22 00:53 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.34 02/02/22 00:53 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.27 02/02/22 00:53 1,2-Dichlorobenzene ug/L ND 5.0 0.34 02/02/22 00:53 1,2-Dichloroethane ug/L ND 1.0 0.32 02/02/22 00:53 1,2-Dichloropropane ug/L ND 1.0 0.36 02/02/22 00:53 1,4-Dichlorobenzene ug/L ND 1.0 0.33 02/02/22 00:53 2-Butanone (MEK) ug/L ND 100 4.0 02/02/22 00:53 2-Hexanone ug/L ND 50.0 0.48 02/02/22 00:53 4-Methyl-2-pentanone (MIBK) ug/L ND 100 2.7 02/02/22 00:53 Acetone ug/L ND 100 5.1 02/02/22 00:53 Acrylonitrile ug/L ND 200 1.8 02/02/22 00:53 Benzene ug/L ND 1.0 0.34 02/02/22 00:53 Bromochloromethane ug/L ND 3.0 0.47 02/02/22 00:53 Bromodichloromethane ug/L ND 1.0 0.31 02/02/22 00:53 Bromoform ug/L ND 3.0 0.34 02/02/22 00:53 Bromomethane ug/L ND 10.0 1.7 02/02/22 00:53 Carbon disulfide ug/L ND 100 0.73 02/02/22 00:53 Carbon tetrachloride ug/L ND 1.0 0.33 02/02/22 00:53 Chlorobenzene ug/L ND 3.0 0.28 02/02/22 00:53 Chloroethane ug/L ND 10.0 0.65 02/02/22 00:53 v2 Chloroform ug/L ND 5.0 0.43 02/02/22 00:53 Chloromethane ug/L ND 1.0 0.54 02/02/22 00:53 v2 cis-1,2-Dichloroethene ug/L ND 5.0 0.38 02/02/22 00:53 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 02/02/22 00:53 Dibromochloromethane ug/L ND 3.0 0.36 02/02/22 00:53 Dibromomethane ug/L ND 10.0 0.39 02/02/22 00:53 Ethylbenzene ug/L ND 1.0 0.30 02/02/22 00:53 lodomethane ug/L ND 20.0 9.7 02/02/22 00:53 Methylene Chloride ug/L ND 5.0 2.0 02/02/22 00:53 Styrene ug/L ND 1.0 0.29 02/02/22 00:53 Tetrachloroethene ug/L ND 1.0 0.29 02/02/22 00:53 Toluene ug/L ND 1.0 0.48 02/02/22 00:53 trans-1,2-Dichloroethene ug/L ND 5.0 0.40 02/02/22 00:53 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 METHOD BLANK: 3534535 Associated Lab Samples: 92584814001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 02/02/22 00:53 trans-1,4-Dichloro-2-butene ug/L ND 100 0.56 02/02/22 00:53 v1 Trichloroethene ug/L ND 1.0 0.38 02/02/22 00:53 Trichlorofluoromethane ug/L ND 1.0 0.30 02/02/22 00:53 Vinyl acetate ug/L ND 50.0 1.3 02/02/22 00:53 Vinyl chloride ug/L ND 1.0 0.39 02/02/22 00:53 Xylene (Total) ug/L ND 5.0 0.34 02/02/22 00:53 1,2-Dichloroethane-d4 (S) % 100 70-130 02/02/22 00:53 4-Bromofluorobenzene (S) % 98 70-130 02/02/22 00:53 Toluene-d8 (S) % 99 70-130 02/02/22 00:53 LABORATORY CONTROL SAMPLE: Parameter 3534536 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.1 106 70-130 1,1,1-Trichloroethane ug/L 50 45.9 92 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.8 102 70-130 1,1,2-Trichloroethane ug/L 50 49.4 99 70-130 1,1-Dichloroethane ug/L 50 44.6 89 70-130 1,1-Dichloroethene ug/L 50 43.2 86 70-132 1,2,3-Trichloropropane ug/L 50 53.4 107 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.1 100 70-132 1,2-Dibromoethane (EDB) ug/L 50 50.9 102 70-130 1,2-Dichlorobenzene ug/L 50 52.1 104 70-130 1,2-Dichloroethane ug/L 50 45.2 90 70-130 1,2-Dichloropropane ug/L 50 48.3 97 70-130 1,4-Dichlorobenzene ug/L 50 52.7 105 70-130 2-Butanone (MEK) ug/L 100 91.2J 91 70-133 2-Hexanone ug/L 100 88.8 89 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 89.OJ 89 70-130 Acetone ug/L 100 82.5J 83 70-144 Acrylonitrile ug/L 250 233 93 70-130 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 46.9 94 70-130 Bromodichloromethane ug/L 50 48.1 96 70-130 Bromoform ug/L 50 50.9 102 70-131 Bromomethane ug/L 50 52.6 105 30-177 Carbon disulfide ug/L 50 45.6J 91 70-133 Carbon tetrachloride ug/L 50 50.7 101 70-130 Chlorobenzene ug/L 50 51.7 103 70-130 Chloroethane ug/L 50 40.1 80 46-131 v3 Chloroform ug/L 50 46.9 94 70-130 Chloromethane ug/L 50 39.8 80 49-130 v3 cis-1,2-Dichloroethene ug/L 50 45.4 91 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 30 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 LABORATORY CONTROL SAMPLE: Parameter 3534536 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 49.3 99 70-130 Dibromochloromethane ug/L 50 48.4 97 70-130 Dibromomethane ug/L 50 51.2 102 70-130 Ethylbenzene ug/L 50 50.6 101 70-130 lodomethane ug/L 100 83.2 83 47-140 Methylene Chloride ug/L 50 40.6 81 68-130 Styrene ug/L 50 52.5 105 70-130 Tetrachloroethene ug/L 50 51.6 103 70-130 Toluene ug/L 50 49.4 99 70-130 trans-1,2-Dichloroethene ug/L 50 44.6 89 70-130 trans- 1,3-Dichloropropene ug/L 50 48.6 97 70-130 trans-1,4-Dichloro-2-butene ug/L 50 68.6J 137 25-200 v1 Trichloroethene ug/L 50 52.3 105 70-130 Trichlorofluoromethane ug/L 50 42.0 84 61-130 Vinyl acetate ug/L 100 96.0 96 70-140 Vinyl chloride ug/L 50 44.9 90 59-142 Xylene (Total) ug/L 150 153 102 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3534537 MS 92585125003 Spike Parameter Units Result Conc. MSD Spike Conc. 3534538 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 24.1 24.1 121 120 70-135 0 30 v1 1,1,1-Trichloroethane ug/L ND 20 20 23.5 22.7 118 114 70-148 4 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.6 23.3 118 117 70-131 1 30 1,1,2-Trichloroethane ug/L ND 20 20 24.3 23.4 121 117 70-136 4 30 1,1-Dichloroethane ug/L ND 20 20 22.9 20.9 115 105 70-147 9 30 1,1-Dichloroethene ug/L ND 20 20 22.6 21.8 113 109 70-158 4 30 1,2,3-Trichloropropane ug/L ND 20 20 23.1 23.0 115 115 67-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 24.0 23.1 120 115 69-136 4 30 v1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.7 23.2 113 116 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 23.0 21.7 115 109 70-133 6 30 1,2-Dichloroethane ug/L ND 20 20 23.0 21.8 115 109 67-138 5 30 1,2-Dichloropropane ug/L ND 20 20 23.9 23.0 120 115 70-138 4 30 1,4-Dichlorobenzene ug/L ND 20 20 22.8 22.3 114 112 70-133 2 30 2-Butanone (MEK) ug/L ND 40 40 49.OJ 48.7J 122 122 61-147 1 30 2-Hexanone ug/L ND 40 40 47.1J 46.7J 118 117 67-139 1 30 4-Methyl-2-pentanone ug/L ND 40 40 46.8J 45.1J 117 113 67-136 4 30 (MIBK) Acetone ug/L ND 40 40 48.OJ 46.8J 120 117 55-159 3 30 Acrylonitrile ug/L ND 100 100 126J 120J 126 120 68-140 5 30 Benzene ug/L ND 20 20 23.0 22.0 115 110 67-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3534537 MS 92585125003 Spike Parameter Units Result Conc. MSD Spike Conc. 3534538 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 24.5 22.4 122 112 70-146 9 30 Bromodichloromethane ug/L ND 20 20 24.0 22.9 120 115 70-138 5 30 Bromoform ug/L ND 20 20 23.4 22.9 117 114 57-138 2 30 v1 Bromomethane ug/L ND 20 20 27.5 25.5 137 128 10-200 7 30 Carbon disulfide ug/L ND 20 20 20.2J 20.OJ 101 100 70-152 1 30 Carbon tetrachloride ug/L ND 20 20 24.4 23.4 122 117 70-147 4 30 Chlorobenzene ug/L ND 20 20 22.6 22.7 113 113 70-137 0 30 Chloroethane ug/L ND 20 20 27.7 26.4 138 132 51-166 5 30 Chloroform ug/L ND 20 20 23.2 21.4 116 107 70-144 8 30 Chloromethane ug/L ND 20 20 24.5 23.9 123 120 24-161 3 30 cis-1,2-Dichloroethene ug/L ND 20 20 22.9 22.3 114 112 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.9 22.3 120 112 70-142 7 30 Dibromochloromethane ug/L ND 20 20 21.6 22.0 108 110 68-138 2 30 Dibromomethane ug/L ND 20 20 25.1 23.8 125 119 70-134 5 30 Ethylbenzene ug/L ND 20 20 22.7 22.6 114 113 68-143 1 30 lodomethane ug/L ND 40 40 39.6 39.0 99 97 20-161 2 30 Methylene Chloride ug/L ND 20 20 22.0 21.5 110 108 64-148 2 30 Styrene ug/L ND 20 20 23.4 23.0 117 115 70-136 2 30 Tetrachloroethene ug/L ND 20 20 23.6 23.1 118 116 70-139 2 30 Toluene ug/L ND 20 20 23.1 22.1 115 110 47-157 4 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.6 21.6 108 108 70-149 0 30 trans-1,3-Dichloropropene ug/L ND 20 20 24.3 22.9 121 115 70-138 6 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 25.OJ 25.3J 125 126 31-145 1 30 v1 Trichloroethene ug/L ND 20 20 24.3 23.1 121 115 70-149 5 30 Trichlorofluoromethane ug/L ND 20 20 23.0 21.3 115 106 61-154 8 30 Vinyl acetate ug/L ND 40 40 47.9J 45.1J 120 113 48-156 6 30 Vinyl chloride ug/L ND 20 20 25.2 24.4 126 122 55-172 3 30 Xylene (Total) ug/L ND 60 60 68.8 68.7 115 114 66-145 0 30 1,2-Dichloroethane-d4 (S) % 93 93 70-130 4-Bromofluorobenzene (S) % 98 101 70-130 Toluene-d8 (S) % 98 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674978 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92584814001 METHOD BLANK: 3532959 Matrix: Water Associated Lab Samples: 92584814001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 01/31/22 14:10 1,2-Dichloroethane-d4 (S) % 102 70-130 01/31/22 14:10 Toluene-d8 (S) % 103 66-133 01/31/22 14:10 LABORATORY CONTROL SAMPLE: 3532960 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 20.3 101 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 Toluene-d8(S) % 102 66-133 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532961 3532962 MS MSD 92585113001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 249 100 100 382 367 133 118 64-141 4 30 1,2-Dichloroethane-d4 (S) % 111 111 70-130 30 Toluene-d8 (S) % 98 98 66-133 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674422 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584814001 METHOD BLANK: 3530217 Matrix: Water Associated Lab Samples: 92584814001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N ug/L ND 100 60.0 01/27/22 23:01 Nitrite as N ug/L ND 100 50.0 01/27/22 23:01 Sulfate ug/L ND 1000 500 01/27/22 23:01 LABORATORY CONTROL SAMPLE: 3530218 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 2500 2360 94 90-110 Nitrite as N ug/L 2500 2420 97 90-110 Sulfate ug/L 50000 48000 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530219 3530220 MS MSD 92584814001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L ND 2500 2500 1860J 1800J 74 72 90-110 10 D3,M1 Nitrite as N ug/L ND 2500 2500 ND ND 0 6 90-110 10 D3,M1 Sulfate ug/L 21600 50000 50000 69100 67000 95 91 90-110 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 674607 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584814001 METHOD BLANK: 3530821 Associated Lab Samples: 92584814001 Parameter Units Nitrogen, Kjeldahl, Total ug/L LABORATORY CONTROL SAMPLE: 3530822 Parameter Units Nitrogen, Kjeldahl, Total ug/L Matrix: Water Blank Reporting Result Limit ND 500 Spike LCS Conc. Result 10000 9460 MDL Analyzed Qualifiers 250 01/29/22 02:31 LCS % Rec % Rec Limits Qualifiers 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530823 3530824 MS MSD 92584735001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Kjeldahl, Total ug/L 0.90 mg/L 10000 10000 11700 11600 108 107 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530825 3530826 MS MSD 92584761001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Kjeldahl, Total ug/L 3.4 mg/L 10000 10000 14100 14700 108 113 90-110 4 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 675913 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584814001 METHOD BLANK: 3537828 Associated Lab Samples: 92584814001 Parameter Units Phosphorus ug/L LABORATORY CONTROL SAMPLE: 3537829 Parameter Units Phosphorus ug/L Matrix: Water Blank Reporting Result Limit ND 50.0 Spike LCS Conc. Result 2500 2570 MDL Analyzed Qualifiers 25.0 02/03/22 22:53 LCS % Rec % Rec Limits Qualifiers 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3537830 3537831 MS MSD 92582144001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 48.0 mg/L 2500 2500 53700 49900 228 75 90-110 7 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3537832 3537833 MS MSD 92582144002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 39.1 mg/L 2500 2500 41200 40700 85 63 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 30 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Foothills LF/Leachate Pace Project No.: 92584814 QC Batch: 675989 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584814001 METHOD BLANK: 3538247 Matrix: Water Associated Lab Samples: 92584814001 Blank Reporting Parameter Units Result Limit Chemical Oxygen Demand ug/L ND 25000 LABORATORY CONTROL SAMPLE: 3538248 Spike LCS Parameter Units Conc. Result Chemical Oxygen Demand ug/L 750000 763000 MDL Analyzed Qualifiers 12500 02/04/22 23:48 LCS % Rec % Rec Limits Qualifiers 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3538249 3538250 MS MSD 92584220001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 37.7 mg/L 100000 100000 138000 141000 101 103 90-110 2 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3538251 3538252 MS MSD 92584417002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 25.7 mg/L 100000 100000 134000 136000 108 110 90-110 2 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 30 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Foothills LF/Leachate Pace Project No.: 92584814 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L. CO Result confirmed by second analysis. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 02:04 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 30 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF/Leachate 92584814 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92584814001 1403-Leachate EPA 350.1 Rev 2.0 1993 674901 92584814001 1403-Leachate 92584814001 1403-Leachate EPA 3005A 675122 EPA 6020B 675233 92584814001 1403-Leachate EPA 7470A 674967 EPA 7470A 675135 92584814001 1403-Leachate SM 2540C-2015 675522 92584814001 1403-Leachate SM 2540D-2015 674549 92584814001 1403-Leachate SM 4500-H+B-2011 674545 92584814001 1403-Leachate SM 5210B-2016 674407 SM 5210B-2016 675557 92584814001 1403-Leachate EPA 8260D 675330 92584814001 1403-Leachate EPA 8260D Mod. 674978 92584814001 1403-Leachate EPA 300.0 Rev 2.1 1993 674422 92584814001 1403-Leachate EPA 351.2 Rev 2.0 1993 674607 EPA 351.2 Rev 2.0 1993 674771 92584814001 1403-Leachate EPA 365.1 Rev 2.0 1993 675913 EPA 365.1 Rev 2.0 1993 675971 92584814001 1403-Leachate SM 5220D-2011 675989 SM 5220D-2011 676215 Date: 02/07/2022 02:04 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 30 Pace Analytical Services, Inc. CHAIN OF CUSTODY RECORD t BA►>aOCal * 110 TECHNOLOGY PARKWAY, PEACHTREE CORNERS, GA 30092 PAGE: 1 OF I (770) 734-4200 : FAX (770) 734-4201 : www.pacelabs.com N REPUBLIC SERVICES OF NC ADDRESS/PHONE C :PORT TO: SIEVE JETT CC: O N :QUESTED COMPLETION DATE: PO S: T STANDARD TAT I A .OJECT NAMEISTATE: I REPUBLIC - FOOTHILLS LF - NORTH CAROLINA -1403 N E DATE 1 TIME 1-#A6_'�L21 Its,:35 Bob Chiodo - ES&S RECEIVED BY: R s C G MATRIX O R SAMPLE IDENTIFICATION I CODE' M A P 8 L X 1403 - LEACHATE 11 V P P P I P P P V A 1 3 7 2 7 2 7 1 B � t mW O D V O — 0 z w a -j a a 0 z Ill a (0 r- 0 Y H -cc O 0 W H- z h F- Co w O a Cl) i Q. LLI H 5 N °° } C113 z 0 o N D M E R a¢ m U z m co i X X X X X X X X 1 P - PLASTIC A - AMBER GLASS G - CLEAR GLASS V - VOA VIAL S - STERILE O - OTHER 1 - HCI, sft LL 2 - HrSO4, SO-C 3 - HNOs 4 - NaOH, s8-C 5 - NaOHIZnAc, arC 6 - Na,%O,, s6-C 7 - SeC not frozen )W - DRINKING WATER S - SOIL J - WASTEWATER SL - SLUDGE 'W - GROUNDWATER SD - SOLID iW - SURFACE WATER A- AIR ST - STORM WATER L - LIQUID W - WATER P - PRODUCT REMARKSIADDITIONAL INFORMATION 12b tt — 17: SS r tL-17,'SS 1ATEifIME: RELINQUISHED BY: DATElfIME: WO#:92584814 P SHIPPED VLA:II11II h lllllllllll III Vitt UPS FED=EX USPS COURIER CLIENT am pe um: Custody Seal: of cool" Coalw ID: 92584814 sr'• m"t# _ . B+o*en_ .. Nok Prasent # Document Name: Document Revised: November 15, 2021 • Sample Condition Upon Receipt (SCUR) I Page 1 of 2 Document No.- 7 Issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlanta Kernersville❑ ConditionSample Client me: Upon Receipt .''� ! S' fill • 6Project Courier: ed Ex ❑UPS CUSPS ©Client ❑ Commercial ❑Pace /� her: 1 Custody Seal Present? OYes ❑No Seals Intact? LdTes ❑No 11-11 Packing Material: El Bubble Wrap Bubble Bags [-]None�Wet%Slue Other Thermometer• R Gun ID: Type of Ice: ff Correction Factor: CoolerTemp: Add/Subtract VQ Cooler Temp Corrected (•C): 12 USDA Regulated Soil (❑ N/A, water sampl Did samples originate in a quarantine zone within the United States CA, NY. or SC (check maps? ❑Yes ❑No Chain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis (<72 hr.)? g Rush Turn Around Time Requested? fl Suffic ent Volume -A Correct Conta ners Used? -Pace Containers Used? Containers Intact? Dissolved analysis- Samples Field Filtered? Sample Labels Match COG? -Includes Date/Time/ID/Analysis Matrix Headspace in VOA Vials (>5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLLITION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: J` 1. 2. 3. 4. L.Lo ❑N/A 1 5. ❑No ❑N/A 1 6. 2T S ❑No ❑N/A 19. ❑Yes 11. go-# :92584814 1 P11- MP Due Date: 02/01/22 CLIENT: GARePNC Date/Initials Person Examining Contents: i �2 Biological Tissue Froze Cif ❑Yes []NoA r ❑None Temp should be above freezing to 6'C []Sam pies out of temp criteria. Samples on ice, cooling process has begun Did sampfes originate from a foreign source (internationally, including Hawaii and Puerto Rico)? ❑Yes []NO Lot ID of split containers: Date/Time: Date: Date: Field Data Required? []Yes []NO Page 29 of 30 Document Name: Condition Upon Receil Document No.: F-CAR-CS-033-Rev.08 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles Document Revised: November 15, 2021 Page 2 of 2 Issuing Authority: ' Paro rarnlinee r1, nhr„ nfs:.... Project ii W0# : 92584814 PH: MP Due Date: 02/07/22 CLIENT: GARepNC mW d d Q C V N m a J E N d m d d Q C a V y m a J E N > 6 m v d Q L O V a, �o a J E pp 1n N a m N V Q c V N d d rl 7 d m v Q O N ^' ev J E Ln N., Vt Op. . v M O Z = V •N n J E o N = d m z as d u ¢ Z U m J E N N 6 m p. = Q m m E ,N.y rja d m 7 N _R C? s t p C E 3 i 3 a N ` Q c y £ ¢ d !=Ln rl N l7 4 V = v = Q! E ¢ w .-I N 07 a w �% Q C O y = E a J E N to W a ti. 7 O n = d a Q u`, .y 14 0 a V V Q O & = N E J E N on o9 a IV d £ ¢ E ry eon G d_d lei 07 Q Z = ¢ O E q CI W O Z NO H R Z ¢ � J O~1 l7 7 z qwq L d = ¢ O 7 E R M +, y ¢ 2 O 2 ¢ O ? E q 0 07 O Z Ln ref O v+ z Y y a " .m... a O 9 a = d �' Y m N m Vr - ? N y J E � rL in N d � y . J E v01 N a H 0 N = Z V eNo J E eq !¢n d cc d Q C N d E J £ O o7 ¢ G o 16 c Vi O N � v1 7 z N e Q c N E ¢ Q a, t7 O 1 1 Z 3 4 5 6 7 8 9 is ]12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted 1 Time preservation }adiusted Amount of Preservative did d Lot N Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Lr_ Page 30 of 30 FOOTHILLS LANDFILL JAN UARY 26, 2022 .; : ''"J •. F . :�,' •; - y✓,l . `u'.q:,'�C eke„i�i, t� `•,�,.,i;� ' i"} "3^� 'Y `i'ti �.. 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A�''�"�' "L,�'�9"�w'cyv'v3tW - -.�� f� �. l'`y '�' � �. �a`� �',"�..:u�f ��� t�„-:».... „��� h� , 3 rc'��"Y,f,�3 .irS.�' '.�'� oQ%�4S�i.��".�r'�..��"vN 1t�i`'X�\"�atf��• £.?�s�^3'-•a ���.ik deA`�''�,'.'r�,y�f^.., P��i �%5,:��� �� - MW-1 R2 22.30 1516.22 1493.92 MW-2R 50.01 1253.36 1203.35 MW-3 54.00 1241.95 1187.95 MW-3R 59.34 1242.69 1183.35 MW-3R2 42.18 1240.83 1198.65 MW-4 41.69 1171.18 1129.49 MW-5 47.37 1175.07 1127.70 MW-6 43.16 1176.82 1133.66 MW-7 32.00 1183.13 1151.13 MW-8 30.80 1195.18 1164.38 MW-9 69.10 1290.79 1221.69 MW-10 76.32 1358.53 1282.21 MW-11 83.11 1401.71 1318.60 * FROM THE TOP OF RISER SITE NAME: FOOTHILLS LF POINT ID: FIELD BLANK LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: DEIONIZED WATER INITIAL TER LEVEL (FT) ELEV., MEAS. PT. 117_%9 METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: LAB SAMPLE / PROJECT #: E S & S - B.CHIODO mim DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) NDFOS PUMP ( ) YES ( ) NO ( ) OTH ` ( ) 3 ( ) 4 6 ( ) OTHER WAS WELL RGED TO DRYNESS( )YES( ) NO WATER LEVEL E URGE (FT) FINISH • • - • pH (Std.Units). TURBIDITY - SAMPLING INFORMATION DATE/TIME / --2 '" Z- / 1 : 0 METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) S.S. BAILER ( ) QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) NA SAMPLING EQUIPMENT DEDICATED: ( ) GRUNDFOS PUMP ( ) YES ( ) OTHER ( ) NO TIME pH Std.Units TEMP. C CONDUCT. umhos/cm TURBIDITY NTU OTHER eh (mV) DISS.OXY. (PPM OTHER NA NA NA NA NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: tJ' COMMENTS: APPENDIX I LIST GIN SAMPLE COLLECTION NUMBER 1 SITE NAME: FOOTHILLS LF POINT ID: TRIP BLANK LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: DEIONIZED WATER LAB SAMPLE I PROJECT #: NA LEVEL (FT) ELEV., MEAS. PT. DATE METHOD OF EVACUATION: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA GRUNt OTHER DEPTH TO BOTTOM (FT) ELEVATION, G/W (MSL): TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: PUMP ( ) YES ( ) NO 3 4 6 -�IOTHER WAS WELL PURGED RYNESS( )YES( )NO WATER LEVEL END PURGE FINISH "Tin M pH SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: PVC BAILER S.S. BAILER S.S. BAILER QED PUMP SAMPLING FIELD MEASUREMENT DATA DEPTH TO GROUNDWATER (FT) - NA SAMPLING EQUIPMENT DEDICATED: GRUNDFOS PUMP YES OTHER NO TIME pH (Std.Units) TEMP. (C) CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER j eh (mV) DISS. OXY. (PPM) OTHER NA NA NA NA I NA NA NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: COMMENTS: VOA ONLY SAMPLE COLLECTION NUMBER 2 SITE NAME: FOOTHILLS LF POINT ID: SW - 'I LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: EVACUATION INFO SURFACE WATER INITIAL WAR LEVEL (FEET) NA ELEVATION, MEAS.PT.( NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTIN ( ) YES ( ) NO PUMPING WELL ( )4 ( )6 ( )OTHER WAS WELL PURGED TO DRYN WATER LEVEL AFTER PURGE (FT.) FINISH ) YES ( ) NO TIME PURGE RATE m/htz CU L'AT4VE VOLUME TEMP. C PH Units SPEC. CONDUCT. umhos/cm) TURBIDITY (NTU) OTHER [eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME 1" ���-� / ��- WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME PH Std.Units SPEC. CONDUCT. TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER au�mhos/cm 1 +4 . , 0 2. NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: li ty" SAMPLE CHARACTERISTICS: COMMENTS: SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: UNDERDRAIN WATER INITIAL WATERQLEVEL (FEET) NA ELEVATION, MEAS7PT—(`MMSb�,_NA.. METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EyAgLATION STABILIZATION DATA POINT ID: UD-2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GfW (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: c 0 N T I N U.$ YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRY )YES ( )NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE (gpm/htz) CUMULATIVE VOLUME --T-Ef� (C) pH :::]�st� SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh fmV) I I NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME METHOD OF SAMPLING: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) — NA WATERRA PUMP (X) DIP BOTTLE SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER I fill 2 4 .57 + 14 NA GENERAL INFORMATION ® or" WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C A COMMENTS: SAMPLE COLLECTION NUMBER 4/ SITE NAME: FOOTHILLS LF LOCATION: LENO|RNORTH CAROL|NA SAMPLE MATRIX: UNOERDRA|NVVATER INITIAL W-A-FERIEVEL (FEET) NA ELEVATION, MEAS.PT.(MSI-): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( \ WELL WIZARD ( S.S. BAILER ( \GRUNOFOSPUK8P WELL RISER DIAMETER UN.\: ( )2 ONE (1) RISER VOLUME (GAL) -------- TOTAL VOLUME EVACUATED /GAL TURBIDITY OFPURG|NGG:START EYACUATION STABILIZATION DATA POINT OD: UUD ~ I FIELD REPRESENTATIVE: ES&G-B.CH|DOO LAB SAMPLE/PROJECT#: NA DEPTH TOBOTTOM (FEET ELE\AA7|ON.G/VV (K8SL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: / )CONTINUOUS ( ) YES ( ) NO PUMPING WELL ( )4 ( \O / ) OTHER_____ VVAG WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE/FT.) FINISH ( )NO PURGE RATE CtIMULATWE TEMP. pH SPEC. CONDUCT. TURBIDITY OTHER NA 0 NA NA NA SAMPLING INFORMATION WATER LEVEL PRIORTOSAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( \ WELL WIZARD ( > VV/TlERRAPUK8p (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA pH SPEC. CONDUCT. TEMP. TURBIDITY REDOX DISS. OXY. OTHER NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: _ SAMPLE CHARACTERISTICS: COMMENTS: SAMPLE COLLECTION NUMBER 57 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL VVAT4;R-LEVEL (FEET) NA ELEVATION, MEAS. DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACUATION STABILIZATION DATA POINT ID: SW-2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GfW (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: CONTINUO YES NO PUMPING WELL 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) CUMULA - VOLUME_ TEMP (C) PH -----4,5td. Units) SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (m NA 0 NA NA F—r NA SAMPLING INFORMATION DATE/TIME /-23;7-22 / / o 'v WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME PH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER /%, (0.(o('o 99-,5 / �, ? (o +2cl. -) 3,91 NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: y SAMPLE CHARACTERISTICS: c L r-- A COMMENTS: SAMPLE COLLECTION NUMBER 4 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WATERIEVFL (FEET) NA ELEVATION, MEAS.PT.(MSI-): NA DATE METHOD OF EVACUATION: PVC BAILER WELL WIZARD S.S. BAILER GRUNDFOS PUMP WELL RISER DIAMETER (IN.): 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS: START EVACLULTION STABILIZATION DATA POINT ID: SW - 5 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: CONTINUOUS YES NO PUMPING WELL ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH ( )NO TIME PURGE RATE (gpm/htz) CUMULATIVE' VOLUME____ Ttl%P--- _ (c) pH SPEC. CONDUCT. (umhos/cm) TURBIDITY (NTU) OTHER eh (mV) NA 0 NA NA NA SAMPLING INFORMATION DATE / TIME /-�57-zz. / /.,57.'2fr WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER WELL WIZARD WATERRA PUMP (X) YES S.S. BAILER GRUNDFOS PUMP (X) DIP BOTTLE NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.Units) SPEC. CONDUCT. (umhos/cm) TEMP. (C) TURBIDITY (NTU) REDOX eh (mV) DISS. OXY. (PPM) OTHER lfjo r7, 3 9- 13 (0. 10. 5-1419 -13.9 Y. (oO NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: sw Af N 55, SAMPLE CHARACTERISTICS: V-A t2 - 7-Atj COMMENTS: SAMPLE COLLECTION NUMBER 7 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER E TION INFORMATION INITIAL VEL (FEET) NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVALUATION STABILIZATION DATA POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE ! PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) CONTINUOU ( ) YES ( ) NO PUMPING WELL ( ) 4 ( ) 6 ( )OTHER WAS WELL PURGED TO DRYNESS WATER LEVEL AFTER PURGE (FT.) FINISH YES ( ) NO TIME PURGE RATE m/htz CUMU VOLUME TEMP. C pH .Units SPEC. CONDUCT. umhos/cm TURBIDITY NTU OTHER eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME I- Z S- Z Z / 15: S .Z WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH Std.Units SPEC. CONDUCT. umhhos/cm TEMP. C TURBIDITY NTU REDOX eh mV DISS.OXY. PPM OTHER IS:Sy 7. co 5' 6 , 0 /c 1 / 01 b o? . ?9 -2 5- % 5.30 NA GENERAL INFORMATION o t WEATHER CONDITIONS AT TIME OF SAMPLING: I.�rrnry, SS SAMPLE CHARACTERISTICS: COMMENTS: SAMPLE COLLECTION NUMBER 9 SITE NAME: FOOTHILLS LF POINT ID: SW-3 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER INITIAL WA NA ELEVATION, MEAS.PT.(MSL): NA DATE METHOD OF EVACUATION: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACth4�STABILIZATION DATA FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, GAN (MSL): NA TIME: START/FINISH / ( ) CONTINUOU: PUMPING WELL ( ) 4 ( ) 6 EVACUATION EQUIPMENT DEDICATED: ( ) YES ( ) NO ( ) OTHER WAS WELL PURGED TO DRYNES YES ( ) NO WATER LEVEL AFTER PURGE (FT.) FINISH TIME PURGE RATE m/htz CUMULATIVE VOLUME TE C pH Std.Uni SPEC. CONDUCT. umhos/cm) TURBIDITY OTHER I eh mV NA 0 NA NA NA SAMPLING INFORMATION DATE/TIME /-Z$'ZI Z / t,I8 METHOD OF SAMPLING: ( ) PVC BAILER ( ) WELL WIZARD ( ) S.S. BAILER ( ) GRUNDFOS PUMP SAMPLING FIELD MEASUREMENT DATA WATER LEVEL PRIOR TO SAMLING (FT.) ( ) WATERRA PUMP (X) DIP BOTTLE NA SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO TIME pH Std.Units SPEC. CONDUCT. umhos/cm TEMP. C 1,,?. TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER 1b; zo 7,91 G 9, 'z / d. a 9. 3 9, 3 S.H Z NA GENERAL INFORMATION y, �.S a,c WEATHER CONDITIONS AT TIME OF SAMPLING: ��+ �v �+ SAMPLE CHARACTERISTICS: C (f✓4� COMMENTS: SAMPLE COLLECTION NUMBER / SITE NAME FOOTHILLS LF _ POINT ID: LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION • 1 1 INITIAL WATER LEVEL (FT): 1 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 22 DEPTH TO BOTTOM (FT): 1 0 .4 0 ELEV., MEAS. PT. (MSL): `� ° ELEVATION, G/W (MSL): / O DATE ��� �- TIME: START/FINISH 6 f 16 / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ONE (1) RISER VOLUME (GAL) , 0 TOTAL VOL. EVACUATED (GAL) • o o TURBIDITY OF PURGINGS: START Ce.f, EVACUATION STABILIZATION DATA ( ) 4 ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS( )YES(X)NO WATER LEVEL END PURGE (FT) • 3 FINISH C pH opt �l ffll-� I MET* ME wom Em SAMPLING INFORMATION DATE / TIME r 1 DEPTH TO GROUNDWATER (FT) -?• 2---? METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION �°' or WEATHER CONDITIONS AT TIME OF SAMPLING: J q 10 SAMPLE CHARACTERISTICS: C l� COMMENTS: APPENDIX I LIST M 511-1sb —IAtFo SAMPLE COLLECTION NUMBER 10 + I ( SITE NAME FOOTHILLS LF .O TT LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL): 1 5 • :s DATE I - )L(P- Z Z-- LAB SAMPLE / PROJECT #: E S & S - B.CHIODO am DEPTH TO BOTTOM (FT): ° 'z r ELEVATION, G/W (MSL): TIME: START/FINISH 17., d'q / METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS 1,10 .00 START C EVACUATION STABILIZATION DATA WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) qL FINISH C �F' pH NMI SAMPLING INFORMATION DATE/TIME I DEPTH TO GROUNDWATER (FT) • L� METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION (' OF WEATHER CONDITIONS AT TIME OF SAMPLING: , o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: mw - 9 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): . I FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): ELEVATION, G/W (MSL): DATE 1-2(p- c Z- TIME: START/FINISH : 59 / METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) .RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: '2.0 0 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) Co 9. 2 s- START C FINISH C t-F. EVACUATION STABILIZATION DATA off ME ork AN = rpm ml, m pH MINOR SAMPLING INFORMATION DATE/TIME 1- 26- 2'Z- / , ) DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: scar ,mot SAMPLE CHARACTERISTICS: C VA X- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 13 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE / PROJECT #: NA EVACUATION INFORMATION INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT): ELEV., MEAS. PT. (MSL): 1 1 ELEVATION, G/W (MSL): 119 4 . 3 DATE TIME: START/FINISH . 54 / • .2(o METHOD OF EVACUATION: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO (X)2 ( )3 ( )4 ( )6 ( )OTHER • o o WAS WELL PURGED TO DRYNESS( )YES(X)NO ®® WATER LEVEL END PURGE (FT) 3 0. TURBIDITY OF PURGINGS: START FINISH'. EVACUATION STABILIZATION DATA SAMPLING INFORMATION DATE/TIME )~V0--ZZ / !' .2 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION 0 f= WEATHER CONDITIONS AT TIME OF SAMPLING: S(A lljQ SAMPLE CHARACTERISTICS: cL� COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 14 SITE NAME FOOTHILLS LF POINT ID: MW-7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ m FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT NA DEPTH TO BOTTOM (FT): 44 19. /-? ELEV., MEAS. PT. (MSQ: 1 0 . -') ELEVATION, G/W (MSL): lj� I. 1--> DATE 2Ap - Z7— TIME: START/FINISH 9: 4ts- METHOD OF EVACUATION: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 ( ) 4 ONE (1) RISER VOLUME (GAL) TOTAL VOL. EVACUATED (GAL) TURBIDITY OF PURGINGS: EVACUATION STABILIZATION DATA EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO ( ) 6 ( ) OTHER WAS WELL PURGED TO DRYNESS ( ) YES (X) NO WATER LEVEL END PURGE (FT) 32.1 Z FINISH (f LJEAP- 0 P14— (Std.Units) ff -2 mon, SAMPLING INFORMATION DATE/TIME 1-26—Z-Z- / )().' 1-7 DEPTH TO GROUNDWATER (FT) 32./2 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION F WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C LrZAJZ- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER IS SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ Ll 3 LO ELEV., MEAS. PT. (MSQ: ( S*' DATE ) - A, - -17- POINT ID: MW-6 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): .5-0--s-5 ELEVATION, G/W (MSQ: )33. (o � TIME: START/FINISH /0,'?S- / //;07 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 4 6 OTHER ONE (1) RISER VOLUME (GAL) 1.18 WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) ®2, oo WATER LEVEL END PURGE (FT) 30 TURBIDITY OF PURGINGS: START C FINISH C (ZAK EVACUATION STABILIZATION DATA PURGE RATITM (ML MIN) pH fflT.-TITS In SAMPLING INFORMATION DATE/TIME 1-26-ZL / I): or7 DEPTH TO GROUNDWATER (FT)/ 3. 30 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP OTHER NO GENERAL INFORMATION Qn OF WEATHER CONDITIONS AT TIME OF SAMPLING: 5a-4^jt4jd20 IV SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1(4 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION e-� INITIAL WATER LEVEL (FT): q . P POINT ID: MW - 5 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FT): 5 1. ELEV., MEAS. PT. (MSL): 1 1 57. O - ELEVATION, G/W (MSL): 11 ' ?7. 70 DATE 1 26— 2 2- TIME: START/FINISH I ) : ;Z.5 / 0 , 5 7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1.14 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) Zoo WATER LEVEL END PURGE (FT) Ll 7 1 TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA TURBIDITY SAMPLING INFORMATION DATE/TIME �® � �'�- / , DEPTH TO GROUNDWATER (FT) s-i METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: w f-j SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1 d SITE NAME FOOTHILLS LF POINT ID: MW-4 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT):_ ELEV., MEAS. PT. (MSQ: DATE 1- 2 � - 2,7- FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): ELEVATION, G/W (MSQ: TIME: START/FINISH METHOD OF EVACUATION: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP S.S. BAILER (X)QED WWPUMP ( ) OTHER NA /1-1211,17 EVACUATION EQUIPMENT DEDICATED: (X) YES ( ) NO WELL RISER DIAMETER (IN.): (X) 2 3 ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS YES (X) NO qSo TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) 1. TURBIDITY OF PURGINGS: START FINISH O-Ur:-Ag EVACUATION STABILIZATION DATA PURGE RAT17m __�ML MIN) pH (Stc TURBIDITY SAMPLING INFORMATION DATE/TIME I-2t--27- / )2"LI-7 4- 12.:41 DEPTH TO GROUNDWATER (FT) ko METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION 01-Ic WEATHER CONDITIONS AT TIME OF SAMPLING: 5w tv r4 y I-' /o SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX I LIST bL4P --(-AO^J (*'V7 -j-/2-'ql) SAMPLE COLLECTION NUMBER 19'+ 11 SITE NAME FOOTHILLS LF POINT ID: MW - 3R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV., MEAS. PT. (MSL) DATE I— — LAB SAMPLE / PROJECT #: DEPTH TO BOTTOM (FT): NA am ELEVATION, G/W (MSL): ( 1 , TIME: START/FINISH 1 3' I 0 / 1 "Y METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 5-.og WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) o?. 00 WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START Cy ia- FINISH C EVACUATION STABILIZATION DATA pH TURBIDITY �Z�m SAMPLING INFORMATION DATE/TIME 1-26 ®Z 7- / DEPTH TO GROUNDWATER (FT) '1-'13 METHOD OF SAMPLING: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER SAMPLING EQUIPMENT DEDICATED: (X) YES ( ) NO. , GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: �at n,►rJ SAMPLE CHARACTERISTICS: c t-F-Ap- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): POINT ID: MW - 2R FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE/ PROJECT#: DEPTH TO BOTTOM (FT) ffm ELEV., MEAS. PT. (MSL): 5 i ELEVATION, G/W (MSQ: DATE )-2�-ZZ TIME: START/FINISH 14; 0 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES NO S.S. BAILER (X)QED WWPUMP OTHER WELL RISER DIAMETER (IN.): (X) 2 3 ) 4 6 OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS YES (X) NO TOTAL VOL. EVACUATED (GAL) 0.50 WATER LEVEL END PURGE (FT) 5-OdS TURBIDITY OF PURGINGS: START C k;EA� FINISH C L.FrAK EVACUATION STABILIZATION DATA Mj� PURGE RA'TESIMDMW�� (ML MIN) I pH Units) 0 0 I ml mu jimwwwp-jj SAMPLING INFORMATION DATE/TIME / mLll DEPTH TO GROUNDWATER (FT) 5-6), / g METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER GRUNDFOS PUMP (X) YES S.S. BAILER (X)QED WWPUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: c LE^z COMMENTS: APPENDIX 11 LIST SAMPLE COLLECTION NUMBER R 1 SITE NAME FOOTHILLS LF POINT ID: MW - 'I R2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): 30 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: 0 DEPTH TO BOTTOM (FT): 419. ELEV., MEAS. PT. (MSL): ELEVATION, G/W (MSL): I'l -1 3 . -"- DATE ) -- 26 -+ 2 Z TIME: START/FINISH /5 ..2 O / 15" • 5 2- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) NO ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ) 3 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 3, 37 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) . 00 WATER LEVEL END PURGE (FT) -7,cl.5 TURBIDITY OF PURGINGS: START l ' FINISH c UE Z EVACUATION STABILIZATION DATA rpm TURBIDITY SAMPLING INFORMATION DATE / TIME / I • S 2- DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: pyo SAMPLE CHARACTERISTICS:' COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 0 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE INITIALVVA-T€R,,,LEVEL (FEET) NA ELEVATION, MEAS.PT.(MSL., _ NA DATE METHOD OF EVACUATION: POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE / PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W (MSL): NA TIME: START/FINISH / EVACUATION EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) CONTINUO ( ) YES ( ) NO ( } S.S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 ( ) 4 ( ) 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYN ) YES ( )NCO TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA -•� ... • • f • •CONDUCT.-: • • OTHER - SAMPLING INFORMATION DATE / TIME I — 26 -AZ- / I V. WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( ) WATERRA PUMP (X) YES ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) SAMPLE PORT ( ) NO SAMPLING FIELD MEASUREMENT DATA TIME pH (Std.0nits) SPEC. CONDUCT. umhos/cm TEMP. C TURBIDITY NTU REDOX eh (mV) DISS.OXY. (PPM OTHER ?(;37 1. ,,(o 000 17.6 — 3. NA NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING:y SAMPLE CHARACTERISTICS: Ci, Amavz COMMENTS: SAMPLE COLLECTION NUMBER 3