1117_Buncombe_GARAA Q1 2022_SWSampling_FID1664076_20220408

DENR USE ONLY []Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition,
etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Craig Eady Phone: [phone]
E-mail: ceady(a)svnterracoro.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
January 24, 2022
Duke Energy Progress Greater January 27, 2022
Asheville Regional Airport 1 Terminal Drive #1 1117-STRUC-2020 .0500
Authority Fletcher, North Carolina
Structural Fills — Areas 1, 3, & 4
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
® No. No groundwater or surface water standards were exceeded.
Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on
this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting
or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Craig D. Eady Project Manager
[phone]
Facility Representative Name (Print) Title
(Area Code) Telephone Number
3/30/2022
Affix NC Licensed/ Professional Geologist Seal
Signature Date
A C) ��+y{{f�! f
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148 River Street, Suite 220, Greenville, SC 29601
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Facility Representative Address
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C-1478 / North Carolina Geological Corporation Number C-387';�:�
NC PE Firm License Number (if applicable effective May 1, 2009)
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Revised 6/2009

REPORT VERIFICATION
PROJECT: QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
STRUCTURAL FILLS — AREAS 1, 3, & 4
PERMIT NO. 1117-STRUC-2020
TITLE: QUARTERLY WATER QUALITY MONITORING REPORT
This document has been reviewed for accuracy and quality commensurate with the
intended application.
Prepared by:
Approved by:
Project Manager: Craig Eady, NC LG
Date: 3/30/2022
Date: 3/30/2022
Licensed Geologist Seal:
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1599
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

Science & Engineering Consultants
synterracorp.com
QUARTERLY WATER QUALITY
MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
STRUCTURAL FILLS —AREAS 1, 3, & 4
PERMIT NO. 1117-STRUC-2020
61 TERMINAL DRIVE #1
FLETCHER, NORTH CAROLINA
APRIL 2022
PREPARED FOR
DUKE
ENERGY
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DUKE ENERGY PROGRESS, LLC
Kathryn W. Webb
Senior Peer Review
' Kelly Ferri
CA/�O�i� Project Manager
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Quarterly Water Quality Monitoring Report —January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
TABLE OF CONTENTS
PAGE
1.0 BACKGROUND..........................................................................................................1-1
2.0 MONITORING NETWORK.......................................................................................... 2-1
2.1 Groundwater................................................................................................................2-1
2.2 Surface Water..............................................................................................................2-1
2.3 Fill Material Pore Water...............................................................................................2-2
3.0 SAMPLING ANALYSIS AND METHODS....................................................................... 3-1
3.1 Groundwater................................................................................................................3-1
3.2 Surface Water.............................................................................................................. 3-1
4.0 STATEMENT OF WORK............................................................................................. 4-1
5.0 FILL AREA 1 RESULTS................................................................................................ 5-1
5.1 Groundwater Flow.......................................................................................................5-1
5.2 Groundwater Analytical Results.................................................................................. 5-1
5.3 Surface Water Analytical Results................................................................................. 5-1
5.4 Piezometer Pore Water Levels..................................................................................... 5-2
6.0 FILL AREA 3 RESULTS................................................................................................ 6-1
6.1 Groundwater Flow.......................................................................................................6-1
6.2 Groundwater Analytical Results.................................................................................. 6-1
7.0 FILL AREA 4 RESULTS................................................................................................ 7-1
7.1 Groundwater Flow.......................................................................................................7-1
7.2 Groundwater Analytical Results.................................................................................. 7-1
8.0 REFERENCES.............................................................................................................8-1
ril 2022 Page i
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report —January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
LIST OF FIGURES
Figure 1 USGS Site Location Map
Figure 2 Groundwater Sample Location Map (Structural Fills - Areas 1, 3, & 4)
Figure 3 Surface Water Sample Location Map (Structural Fill - Area 1)
Figure 4 Pore Water Piezometer Location Map (Structural Fill - Area 1)
LIST OF TABLES
Table 1 Monitoring Well Construction Information
Table 2 Surface Water Field and Analytical Results
Table 3 Field and Analytical Results that Equal or Exceed Surface Water Quality
Standards
Table 4 Pore Water Piezometer Water Levels
LIST OF APPENDICES
Appendix A
Appendix B
Surface Water Sampling Logs
Surface Water Laboratory Analytical Reports
ril 2022
Page ii
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
LIST OF ACRONYMS AND ABBREVIATIONS
02B
15A NCAC 02B .0200 surface water standards
CCP
coal combustion products
DWM
Division of Waste Management
Duke Energy
Duke Energy Progress, LLC
EDD
Electronic Data Deliverable
GARAA
Greater Asheville Regional Airport Authority
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
NOAA
National Oceanic and Atmospheric Administration
NTU
nephelometric turbidity units
ORP
oxygen reduction potential
Site
Greater Asheville Regional Airport Authority
SW
Solid Waste
SWS
Solid Waste Section
TDS
total dissolved solids
TOC
total organic carbon
TSS
total suspended solids
USEPA
U.S. Environmental Protection Agency
WQMRP
Water Quality Monitoring and Reporting Plan
ril 2022 Page Hi
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
1.0 BACKGROUND
The Greater Asheville Regional Airport Authority (GARAA or Site) is located in Fletcher,
Buncombe County, North Carolina, approximately 13 miles south of Asheville, North Carolina
(Figure 1). Three separate structural fill areas (Areas 1, 3, and 4) were constructed at the Site
from the beneficial reuse of coal combustion products (CCP) material. That material was
sourced from the nearby Asheville Steam Electric Plant, owned and operated by Duke Energy
Progress, LLC (Duke Energy).
A Water Quality Monitoring and Reporting Plan (WQMRP) (SynTerra, 2020) pertaining to the
structural fills was submitted to the North Carolina Department of Environmental Quality
(NCDEQ) Division of Waste Management (DWM) — Solid Waste Section (SWS) in December
2020. The WQMRP established procedures for monitoring groundwater in the surficial flow
zone (saprolite and partially weathered rock) beneath Areas 1, 3, and 4, and surface waters
adjacent to structural fill Area 1, during operational and post -closure periods. Such procedures
are established to satisfy requirements of North Carolina Administrative Code (NCAC) Title 15A
NCAC 13B .0504(1)(g)(iv). Subsequent to approval of the WQMRP, NCDEQ SWS issued water
quality monitoring and reporting permit number 1117-STRUC-2020 on December 14, 2020.
This Quarterly Water Quality Monitoring Report, prepared to satisfy reporting requirements of
permit No. 1117-STRUC-2020, provides a summary of January 2022, Site surface water quality
sampling activities and results.
March 2022 Page 1-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report - January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
2.0 MONITORING NETWORK
2.1 Groundwater
Monitoring well locations of the three fill areas are provided in Figure 2 and monitoring well
construction details are presented in Table 1. Boring logs and well abandonment records are
included in the WQMRP and have been provided to NCDEQ SWS. A brief description of the
monitoring network for each fill area is provided below:
Area 1
The existing groundwater -quality monitoring network for Area 1 consists of two (2) background
wells and six (6) review boundary wells (Figure 2). Four of the monitoring wells (MW-1A-A1,
MW-2A-Al, MW-4A-Al, and MW-5-Al) were installed in 2009.The remaining four monitoring
wells (MW-6-Al, MW-7-Al, MW-8-Al, and MW-9-Al) were installed in 2018. Wells MW-4A-A1
and MW-9-Al, located upgradient of Area 1, serve as background wells. The remaining wells
were installed either side -gradient or downgradient from Area 1 at the approximate review
boundary (Figure 2). One additional well (MW-1-Al), located north and downgradient of Area 1
beyond the review boundary, is designated to be used only for water -level measurements, as
per the WQMRP.
Area 3
The existing groundwater -quality monitoring well network for Area 3 consists of seven (7)
downgradient review boundary wells (MW-1-A3, MW-2-A3, MW-3-A3, MW-4-A3, MW-5-A3,
MW-6-A3, and MW-7-A3) (Figure 2). The monitoring wells were installed in December 2013.
Area 4
The existing groundwater -quality monitoring well network for Area 4 consists of one (1)
background well and six (6) downgradient review boundary wells (Figure 2). Wells MW-2-A4
and MW-5-A4 were installed in 2009, wells MW-6-A4 and MW-7-A4 were installed in 2010, and
the remaining three wells (MW-1A-A4, MW-5D-A4, and MW-9-A4) were installed in 2012. The
top of casing for well MW-9-A4 was extended vertically in September 2014 to accommodate
final surface grade of the GARAA taxiway project. Well MW-1A-A4 was initially installed
upgradient of Area 4 as a background well but was abandoned due to the taxiway project. A
replacement background well, MW-IAR-A4, was installed in September 2015 (Figure 2).
MW-1A-A4 was properly abandoned in October 2015.
2.2 Surface Water
The eight (8) surface water sample locations designated for Area 1 include SW-2-Al, SW-3-Al,
SW-4B-Al, SW-4C-Al, SW-5-Al, SW-6-Al, SW-8-Al, and SW-9-Al (Figure 3). SW-2-Al, located
near the southern portion of Area 1, serves as a background surface water monitoring location.
SW-3-Al, located north of Area 1, is the farthest downgradient surface water sample location
and receives flow from the remaining Area 1 surface water locations.
ril 2022 Paee 2-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
2.3 Fill Material Pore Water
Nine piezometers installed within the Area 1 Structural Fill are used to monitor pore water
within the fill material (Figure 4). Six piezometers (PZ-1, PZ-2, PZ-3, PZ-4, PZ-5, and PZ-6) were
installed in November 2017, and three piezometers (PZ-2S, PZ-31D, and PZ-7) were installed in
August 2018. Those piezometers are designated to be used for water level only measurements,
as per the WQMRP.
ril 2022 Page 2-2
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
3.0 SAMPLING ANALYSIS AND METHODS
3.1 Groundwater
Groundwater samples are collected semiannually in April and November, as per the WQMRP,
and were not collected during the 1st quarter 2022.
3.2 Surface Water
Surface water sampling of Area 1 was conducted in accordance with the Internal Technical
Guidance: Evaluating Impact to Surface Water from Discharging Groundwater Plumes (NCDEQ,
October 2017). To comply with Section 3.2(a) of the WQMRP, SynTerra collected the 1" quarter
2022 surface water samples at each location over a 96-hour period on January 24 and January
27, 2022 (Site Investigation Sampling Options, NCDEQ, July 2018 email), using a frequency that
enables a comparison to applicable 15A North Carolina Administrative Code (NCAC) 02B .0200
(02B) surface water standards. Surface water downgradient of Area 1 flows northward towards
the French Broad River and is not classified. The French Broad River has a Class B surface water
classification in the vicinity of the airport. Therefore, analytical results for surface water
collected at Area 1 are compared with 02B Class B surface water standards.
Surface water samples were collected at each location during low or base flow conditions.
According to review of the U.S. Department of Commerce National Oceanic and Atmospheric
Administration (NOAA) record of climatological observations for the Asheville Airport Weather
Station (USW00003812), precipitation was recorded on January 28, 2022 (0.03 inches) and
January 29, 2022 (0.01 inches). Surface water samples were not collected from locations where
dry or stagnant conditions, insufficient flow, or other observed conditions, which would
preclude the ability to collect a valid, representative sample. Field parameters [i.e., pH,
temperature, dissolved oxygen, specific conductance, oxidation reduction potential (ORP), and
turbidity] were measured and recorded prior to collection of surface water samples. Copies of
surface water field sampling logs are included in Appendix A.
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) analyzed
surface water samples for total and dissolved phase metals, alkalinity, chloride, sulfate, cations,
anions, and other parameters, including total dissolved solids (TDS), total organic carbon (TOC)
and total suspended solids (TSS). Surface water analytical laboratory reports, including
analytical methods and constituent detection limits, and chain -of -custody forms are provided in
Appendix B.
ril 2022 Page 3-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
4.0 STATEMENT OF WORK
The following tasks occurred during the first quarter (January) 2022:
• SynTerra collected the January 2022 surface water samples at each location over a 96-
hour period.
• Measured depth -to -pore water in each of the piezometers positioned within Area 1
during the January 2022 sampling event.
• Conducted a review of laboratory surface water analytical results for samples listed
above.
• Reviewed the laboratory analytical results pertaining to the parameters listed in the
WQMRP. The Electronic Data Deliverable (EDD) provided by Duke Energy was adapted
to conform to the format requirements of the NCDEQ EQUIS EDD template.
• Prepared and submitted this quarterly Water Quality Monitoring Report to Duke Energy.
ril 2022 Page 4-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
5.0 FILL AREA 1 RESULTS
5.1 Groundwater Flow
Not applicable during this reporting period.
5.2 Groundwater Analytical Results
Not applicable during this reporting period.
5.3 Surface Water Analytical Results
Total and dissolved field parameters and analytical results from the January 2022 quarterly
surface water sampling event are summarized in Table 2. Surface water analytical results are
compared with applicable 02B Class B surface water standards and USEPA National
Recommended Water Quality Criteria (NRWQC) for Aquatic Life and Human Health (Table 2). As
stated by the USEPA, NRWQC standards do not constitute regulations, nor do they impose a
legally binding requirement. Therefore, comparisons with those criteria are for information
purposes only. A summary of the surface water field and analytical results that are equal to or
greater than the 02B standards and a preliminary analysis of the cause and significance of the
exceedances are presented in Table 3.
Review of the January 2022 surface water sampling data indicate that several constituent
concentrations are greater than (or less than for dissolved oxygen and pH) applicable 02B
standards for Class B surface waters at two surface water locations located within the Area 1
compliance boundary. Those constituents and locations include:
• Arsenic (dissolved) — SW-8-Al
• Dissolved oxygen - SW-4C-A1 and SW-8-Al
• pH — SW-4C-A1
• Turbidity— SW-8-Al
Upon further review of the constituents listed above, January 2022 concentrations of dissolved
oxygen in SW-4C-A1 were within the range of background concentrations for the Site. Analytical
results outside the range of background concentrations for the Site and a preliminary analysis
of the cause and significant of the exceedance are presented in Table 3.
Please note that flow at SW-8-Al was sufficient to sample. However, due to low flow
conditions, turbidity results were greater than 02B standards and DO results were less than the
02B minimum for surface water.
In the vicinity of Area 1, surface water flows north and is conveyed downgradient to surface
water location SW-3-Al, beyond the compliance boundary and near the northern property
boundary (Figure 3). The combined surface water flow at SW-3-Al is conveyed toward the
French Broad River. Due to the downgradient location of SW-3-Al and the combined flow from
ril 2022 Paee 5-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
Area 1 surface water, evaluation of SW-3-Al data is representative of the overall surface water
quality downgradient of Area 1 prior to migrating off -Site and potentially discharging into a
classified body of water (French Broad River). Review of January 2022 surface water sampling
data (Table 2) indicates that surface water at SW-3-Al is within applicable 02B standards for
Class B surface waters including turbidity. Fluctuations in turbidity concentrations appear to be
a result of low flow surface water conditions, rather than effects from the Area 1 Structural Fill.
5.4 Piezometer Pore Water Levels
Pore water level data were collected manually from five piezometers (PZ-1, PZ-4, PZ-5, PZ-6,
and PZ-7) in the Area 1 Structural Fill (Figure 4) on January 24, 2022, and are summarized in
Table 4. The remaining piezometers (PZ-2, PZ-2S, PZ-3, and PZ-3D) have pressure transducers
installed that log water levels continuously. Data from those transducers are downloaded
quarterly by others and submitted to NCDEQ SWS separately from this report.
ril 2022 Page 5-2
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
6.0 FILL AREA 3 RESULTS
6.1 Groundwater Flow
Not applicable during this reporting period.
6.2 Groundwater Analytical Results
Not applicable during this reporting period.
ril 2022 Page 6-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
7.0 FILL AREA 4 RESULTS
7.1 Groundwater Flow
Not applicable during this reporting period.
7.2 Groundwater Analytical Results
Not applicable during this reporting period.
ril 2022 Page 7-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
8.0 REFERENCES
NCDEQ. (2017). Internal Technical Guidance: Evaluating Impact to Surface Water from
Discharging Groundwater Plume. N.C. Division of Water Resources. Raleigh, N.C.: N.C.
Department of Environmental Quality. Retrieved March 4, 2021, from
https:Hfiles.nc.gov/ncdeq/Sampling%20of%20SW%20for%2002L%20171031%2OFINAL_
O.pdf
SynTerra. (2020). Water Quality Monitoring and Reporting Plan — Structural Fills Areas 1, 3, & 4
- Greater Asheville Regional Airport Authority. November 2020.
ril 2022 Page 8-1
Project: 00.0059.50.02

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
FIGURES
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USGS SITE LOCATION MAP
STRUCTURAL FILLS -AREAS 1, 3, & 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA
DRAWN BY: C. WYATT DATE: 01/26/2021 GRAPHIC SCALE
REVISED BY: R. KIEKHAEFER DATE: 03/14/2022 1,000 0 1,o0C
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FIGURE 1
USGS SITE LOCATION MAP
STRUCTURAL FILLS -AREAS 1, 3, & 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA
DRAWN BY: C. WYATT DATE: 01/26/2021 GRAPHIC SCALE
REVISED BY: R. KIEKHAEFER DATE: 03/14/2022 1,000 0 1,o0C
CHECKED BY: K. FERRI DATE: 03/14/2022
APPROVED BY: K. FERRI DATE: 03/14/2022
PROJECT MANAGER: K. FERRI IIN FEET)

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CHECKED BY: K. FERRI DATE: 03/14/2022
APPROVED BY: K. FERRI DATE: 03/14/2022
PROJECT MANAGER: K. FERRI
FIGURE 2
GROUNDWATER SAMPLE LOCATION MAP
STRUCTURAL FILLS -AREAS 1, 3, & 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

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www.synterracorp.com
PROPERTY BOUNDARY
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. LOCATION OF WELL MW-1-Al TAKEN FROM GEOSYNTEC DRAWING ("INSTRUMENTATION AND
MONITORING WELL LOCATIONS", MAY 2020). OTHER WELL LOCATIONS, COAL COMBUSTION
PRODUCTS LIMITS, REVIEW BOUNDARYAND COMPLIANCE BOUNDARYTAKEN FROM S&ME
DRAWING ( "GROUNDWATER FLOW MAP STRUCTURAL FILL", DECEMBER 12, 2010).
3. AERIAL PHOTOGRAPH OBTAINED FROM NC ONE MAP GEOSPATIAL PORTAL AT
http:lldata.nconemap.comlgeoportal/catalog/raster/download.page ON OCTOBER 7, 2020. AERIAL
COLLECTED ON JANUARY 1, 2019.
4. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIPS 3200 (NAD83).
FIGURE 3
SURFACE WATER SAMPLE LOCATION MAP
STRUCTURAL FILL - AREA I
QUARTERLY WATER QUALITY MONITORING RERPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

HEADWALL
♦
,
EXISTING WETLANDS
3
1
1
1
Y
1
u' CONCRETE HEADWALL
' PZ-5
' 1
15" RCP 1
,
WIF
1 PZ-3 D
� 1
1 , �
� 1
PZ-1 1
' 1
LOCKED GATE ,
1 ,
_ � 1
1 ,
\ 60" RC
PZ-4 \
- 0�01
FENCE �
1 ♦
1 AOCESS ROAD 1 /
, 1 I ♦
I 1 �
i
PZ Z PIEZOMETER - PORE WATER LEVEL ONLY
- - • COAL COMBUSTION PRODUCT LIMITS
REVIEW BOUNDARY
COMPLIANCE BOUNDARY
�- PROPERTY BOUNDARY
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARY AND COMPLIANCE BOUNDARY
TAKEN FROM S&ME DRAWING ( "GROUNDWATER FLOW MAP STRUCTURAL FILL", DECEMBER 12,
2010).
3. AERIAL PHOTOGRAPH OBTAINED FROM NC ONE MAP GEOSPATIAL PORTAL AT
http://data.nconemap.com/geoportal/catalog/raster/download.page ON OCTOBER 7, 2020. AERIAL
COLLECTED ON JANUARY 1, 2019.
4. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINASTATE PLANE
COORDINATE SYSTEM RIPS 3200 (NAD83).
GRAPHIC SCALE
120 0
120 240
symTerra
(IN FEET)
DRAWN BY: R. KIEKHAEFER
REVISED BY: R. KIEKHAEFER
B APPROVED BY: FFERRI
PROJECT MANAGER: K. FERRI
DATE: 08/27/2020
DATE: 03/14/2022
DATE: 03/14/2022
DUKE
ENERGY
PROGRESS
........._.._._....___.._
____
FIGURE 4
PORE WATER PIEZOMETER LOCATION MAP
STRUCTURAL FILL - AREA I
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
TABLES
L7
symTerra
Science & Engineering Consultants

TABLE 1
MONITORING WELL CONSTRUCTION INFORMATION
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well Name
Date
Installed
Casing Diameter
(inches)
inches
(NAD 83)
(NAVD 88)
Total Depth of Well
b s
(g)
Length of Screen
(feet)
feet
Screened Interval
Lithology of Screened Interval
Northing
Easting
Ground Elevation
Top Of Casing
Elevation
from
to
MW-1-Al
01/04/2008
6.5
636742.78
945061.99
2,096.50
2098.94
23
15
2,089
2,074
Saprolite
MW-1A-Al
10/6/2009
2
636559.68
944943.83
2,097.7
2,100.40
20
15
2,093
2,078
Saprolite
MW-2A-Al
10/6/2009
2
636617.12
945291.16
2,099.9
2,102.71
15
10
21095
2,085
Saprolite
MW-4A-Al
10/7/2009
2
635188.59
944975.13
2,149.1
2,151.55
45
15
2,119
2,104
Saprolite/PWR
MW-5-Al
10/7/2009
2
636320.32
944677.45
2,152.0
2,153.86
57
15
2,110
2,095
Saprolite
MW-6-Al
8/14/2018
2
636581.93
945096.41
2,102.8
2,103.13
20
10
2,093
2,083
Saprolite
MW-7-Al
8/14/2018
2
636504.84
945718.42
2,123.3
2,123.62
20
10
2,113
2,103
Saprolite
MW-8-Al
8/14/2018
2
636237.93
945850.91
2,142.3
2,142.59
25
10
2,127
2,117
Saprolite
MW-9-Al
8/14/2018
2
635681.19
946058.68
2,163.2
2,163.53
31.5
10
21142
2,132
Saprolite
MW-1-A3
11/25/2013
2
634037.84
943846.89
2,159.5
2,162.42
57.5
15
2,117
2,102
PWR
MW-2-A3
12/11/2013
2
634848.88
943520.52
2,144.6
2,147.13
62.9
15
2,097
2,082
Saprolite/PWR
MW-3-A3
12/2/2013
2
635548.38
943337.34
2,138.0
2,140.98
64.7
15
2,088
2,073
Saprolite/PWR
MW-4-A3
12/13/2013
2
636014.40
943105.17
2,115.4
2,117.64
33.7
10
2,092
2,082
Saprolite/PWR
MW-5-A3
12/3/2013
2
636531.67
943234.27
2,120.6
2,123.16
62.4
15
2,073
2,058
Saprolite/PWR
MW-6-A3
12/4/2013
2
636734.52
943257.50
2,127.8
2,130.44
66.7
15
2,076
2,061
Saprolite/PWR
MW-7-A3
12/2/2013
2
637022.38
943192.53
2,119.0
2,121.54
67.5
15
2,067
2,052
Saprolite/PWR
MW-1AR-A4
9/18/2015
2
631447.90
944679.90
2,131.2
2,133.72
60.2
10
2,081
2,071
PWR
MW-2-A4
12/8/2009
2
629920.28
944436.90
2,074.6
2,076.56
30
20
2,065
2,045
Saprolite
MW-5-A4
12/8/2009
2
629395.45
944832.59
2,066.3
2,068.31
25
15
2,056
2,041
Saprolite
MW-5D-A4
4/2/2012
2
629386.39
944842.05
2,067.1
2,071.47
71.5
10
2,006
1,996
PWR
MW-6-A4
7/2/2010
2
628967.08
945202.85
2,071.0
2,074.01
30
15
2,056
2,041
Saprolite
MW-7-A4
7/2/2010
2
628489.87
945512.01
2,068.4
2,071.37
30
15
2,053
2,038
Saprolite
MW-9-A4
3/29/2012
2
627830.32
945932.12
2,065.0
2,069.01
104.9
10
1,972
1,962
PWR
Notes:
* - Monitoring well used for water level measurements only.
NAD 83 - North American Datum of 1983
NAVD 88 - North American Vertical Datum of 1988
bgs - below ground surface
PWR - partially weathered rock
Information on this table provided by Duke Energy Progress, LLC
Prepared by: KHF Checked by: GAB
Page 1 of 1

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLECTHER, NC
Analytical Parameter
FIELD PARAMETERS
WATER QUALITY PARAMETERS
pH
Temperature
Specific
Conductance
Dissolved
Oxygen`
Oxidation
Reduction
Potential
Eh
Turbidity'
y
Flow
Alkalinity
Bicarbonate
Alkalinity
Carbonate Alkalinity
Total Hardness
Sulfide
Total Organic
Carbon
Total Suspended
Solids
TOT
TOT
TOT
TOT
TOT
TOT
TOT
Reporting Units
S.U.
Deg C
µmhos/cm
mg/L
mV
mV
NTUs
GPM
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
15A NCAC 02B (Class B)
6.0-9.0
<29c
NE
-4
NE
NE
NE
NE
NE
>_20"
NE
NE
NE
NE
NE
NE
USEPA NRWQC (Aquatic Life and Human Health)`
Location ID
Associated
Water Body
Latitude
Longitude
Associated Unit
Sample
Media
Location With Respect
Sour
to Source
Sample
Collection
Procedure
Type
Samplele
Sample
Collection Date
Analytical Results
Analytical
Result
Value Used
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
SW-02-Al
French Broad River
35.44394511
-82.54166313
Asheville Airport - Areal
Water
Background
Grab
Stream
1/24/2022
6.4
14
107
7.12
36
241
4.7
NM
39.2
39.2
21
39.2
<5
25.8
<0.1
1.7
<1.0
SW-2-Al(2)'French
Broad River
35.44394511
-82.54166313
Asheville Airport - Areal
Water
Background
Grab
Stream
1/24/2022
6.4
13
104
6.45
41
246
5.2
NM
12.3
12.3
12.3
<5
24.8
<0.1
1.9
<1.0
SW-2-AS
French Broad River
35.44394511
-82.54166313
Asheville Airport - Areal
Water
Background
Grab
Stream
1/27/2022
6.8
11
114
6.80
32
237
3.7
NM
12.5
12.5
12.5
<5
28.5
<0.1
1.6
<1.0
SW-3-Al
French Broad River
35.4481500
-82.542735
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/24/2022
6.4
9
122
11.09
57
262
3.7
NM
27.3
27.3
27
27.3
<5
37.4
<0.1
1.8
1.2
SW-3-Al (2)'
French Broad River
35.4481500
-82.542735
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/24/2022
6.6
9
121
9.25
60
265
1.8
NM
27.2
27.2
27.2
<5
38
<0.1
2
<1.0
SW-3-Al
French Broad River
35.4481500
-82.542735
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/27/2022
6.1
8
112
9.00
96
301
2.9
NM
25
25
25
<5
37.3
<0.1
1.7
<1.0
SW-4B-Al
French Broad River
35.44718433
-82.54317444
Asheville Airport -Area 1
Water
Downgradient
Grab
Stream
1/24/2022
6.2
9
93
4.90
56
261
4.3
NM
27
27
27
27
<5
34.1
<0.1
1.8
4.6
SW-4B-Al (2)s
French Broad River
35.44718433
-82.54317444
Asheville Airport - Area 1
Water
Downgradient
Grab
Stream
1/24/2022
6.1
10
92
4.75
57
262
1.7
NM
27
27
27
<5
34
<0.1
2
2.6
SW-4B-Al
French Broad River
35.44718433
-82.54317444
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/27/2022
6.2
8
87
5.66
50
255
3.4
NM
26.6
26.6
26.6
<5
33.1
<0.1
1.5
3
SW-4C-Al
French Broad River
NM
NM
Asheville Airport -Area 1
Water
Downgradient
Grab
Stream
1/24/2022
5.8
12
82
3.45
64
269
35.4
NM
22.5
22.5
23
22.5
<,
27.9
<0.1
1.9
7.4
SW-4C-Al
French Broad River
NM
NM
Asheville Airport -Areal
Water
Downgradient
Grab
Stream
1/24/2022
5.8
10.4
77
3.62
62
267
15.1
NM
22.8
22.8
22.8
<5
28.5
<0.1
1.9
3
SW-4C-Al
French Broad River
NM
NM
Asheville Airport -Areal
Water
Downgradient
Grab
Stream
1/27/2022
5.7
7.3
72.3
3.68
73.9
279
4.67
NM
22.6
22.6
22.6
<5
27.6
<0.1
l.6
1
SW-5-Al
French Broad River
35.44747192
-82.54287644
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/24/2022
6.7
3
245
5.27
34
239
6.6
NM
73.3
73.3
75
73.3
<5
84
<0.1
3.6
28.2
SW-S-AS (2)s
French Broad River
35.44747192
-82.54287644
Asheville Airport - Area 1
Water
Downgradient
Grab
Stream
1/24/2022
6.8
3
245
4.67
22
227
6.7
NM
73.1
73.1
73.1
<5
81.1
<0.1
3.2
55.6
SW-S-Al
French Broad River
35.44747192
-82.54287644
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/27/2022
6.1
4
253
10.84
57
262
5.0
NM
78A
78.4
78.4
<5
88
<0.1
3.1
23.1
SW-6-Al
French Broad River
35.44793865
-82.54304911
Asheville Airport - Area 1
Water
Downgradient
Grab
Stream
1/24/2022
6.3
8
100
7.84
22
227
11.8
NM
15.4
15.4
15
15.4
<5
21.9
<0.1
3.5
25.2
SW-6-AS (2)s
French Broad River
35.44793865
-82.54304911
Asheville Airport - Area 1
Water
Downgradient
Grab
Stream
1/24/2022
6.1
8
104
7.69
34
239
7.4
NM
16.3
16.3
16.3
<5
21
<0.1
3.6
11
SW-6-Al
French Broad River
35.44793865
-82.54304911
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/27/2022
7.5
6
102
7.36
-70
135
40.9
NM
13.1
13.1
13.1
<5
21.4
<0.1
3.2
20
SW-8-Al
French Broad River
35.44713874
-82.54266769
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/24/2022
7.2
9
833
4.38
-39
166
216
NM
440
440
440
440
<5
445
<0.1
3.7
49.6
SW-8-Al
French Broad River
35.44713874
-82.54266769
Asheville Airport -Area 1
Water
Downgradient
Grab
Stream
1/24/2022
7.2
11
837
3.11
-67
138
50.4
NM
439
439
439
<5
444
<0.1
3.5
37.2
SW-8-Al
French Broad River
35.44713874
-82.54266769
Asheville Airport -Areal
Water
Downgradient
Grab
Stream
1/27/2022
6.7
7.1
741
1.78
-39
166
296
NM
442
442
442
<5
464
<0.1
3.2
52.6
SW-9-Al
French Broad River
35.44717207
-82.54312023
Asheville Airport -Areal
Water
Downgradient
Grab
Stream
1/24/2022
7.2
6
171
10.88
53
258
2.7
NM
20.2
20.2
32
20.2
<5
35.1
<0.1
1.7
<1.0
SW-9-Al (2)'
French Broad River
35.44717207
-82.54312023
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/24/2022
7.1
6
170
9.52
51
256
1.4
NM
25.1
25.1
25.1
<5
38
<0.1
1.8
<1.0
SW-9-Al
French Broad River
35.44717207
-82.54312023
Asheville Airport - Areal
Water
Downgradient
Grab
Stream
1/27/2022
6.5
6
154
9.85
50
255
4.5
NM
51
51
511
<5
64.7
<0.1
1.7
3.8
Notes:
- North Carolina 1SA NCAC 028 .0211 non -hardness dependent criteria for Class B Surface Waters.
0 - North Carolina 1SA NCAC 028 .0211 hardness dependent criteria for Class 8 Surface Waters.
- USEPA NRWQC for Civic or CCC Aquatic Life and Human Health
0 - North Carolina In -Stream Target Values for Surface Waters. Established per language in 15A NCAC 02B .0202 and .0208.
0 - Merged cells with fill indicate an average value that is compared to the non -hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 - Merged cells with fill indicate an average value that is compared to the hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 - Merged cells with fill indicate an average value that is compared to the acute or chronic criteria compared to USEPA NRWQC for Aquatic Life and Human Health.
Bold values indicate concentration is greater than the comparison criteria.
Surface water sample location SW-2-Al is an approved background monitoring location.
1) 15A NCAC 02B .0101 Class B = freshwaters protected for primary recreation which includes swimming on a frequent or organized basis and all Class C uses.
2) USEPA NRWQC Aquatic Life and Human Health =Aquatic Life and Human Health criteria applicable to alkalinity, aluminum, antimony, iron, and manganese.
3) SynTerra is not NC certified for these parameters. Data collected for information purposes only.
4) Dissolved oxygen values presented are instantaneous values.
5) Designates the same sample location sampled later on the same date within one hour for comparison to acute criteria. See "Acute" definition below.
6) Asheville Airport - Area 1 is located in the mountain and upper piedmont region.
7) Calculated hardness dependent metal standards represent most conservative value. Standards are calculated using 25 mg/L hardness, regardless if actual instream hardness values are greater than 25 mg/L.
8) Total Cr(VI) values are presented as dissolved Cr (VI), as hexavalent chromium is assumed to be in an aqueous (dissolved) phase.
9) Chromium speciation is not performed for trivalent chromium (Cr(III)). Trivalent values are derived by subtracting hexavalent chromium values from dissolved chromium values.
Where a dissolved chromium value is less than the detection limit ("<"), it is considered a whole number for purposes of deriving a trivalent chromium value.
10) Toxic Substance Level.
11) Criterion Continuous Concentration (chronic) of 20 mg/L is a minimum value except where alkalinity is naturally lower, in which case the criterion cannot be lower than 25% of the natural level.
12) USEPA criteria for aluminum (December 2018) - criteria based on waters with a pH = 6.5 S.U, DOC = 1 mg/L, and Hardness = 25 mg/L.
<- concentration not detected at or above the adjusted reporting limit.
greater than or equal to
less than or equal to
- In -stream target value represents total chronic concentration.
' Per DEC. NPDES DMR reporting guidance, values below the Practical Quantitation Limit are treated as zero for averaging purposes.
Acute - "Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour."
Reference 1SA NCAC 02B .0211(11) (e)
Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or
as a 96-hour average" Reference 15A NCAC 02B .0211(11) (e)
Deg C - Degrees Celsius
DIS - Inorganic dissolved concentration (with filter size 0.45µ)
GPM - gallons per minute
j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MI - Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable.
mg/L - milligrams per liter
mV - millivolts
NA - not applicable
NE - not established
NM - not measured
NRWQC- National Recommended Water Quality Criteria
NTUs - Nephelometric Turbidity Units
S.U. - Standard Unit
TOT - Inorganic total concentration
USEPA - United States Environmental Protection Agency
USEPA NRWQC Criterion Maximum Concentration (CMC). Evaluated using an average of two or more samples collected within one hour.
USEPA NRWQC Criterion Continuous Concentration (CCC). Evaluated using averages of a minimum of four samples taken on consecutive days, or as a 96-hour average.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Page 1 of 5

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLECTHER, NC
Analytical Parameter
INORGANIC PARAMETERS (TOTAL CONCENTRATION AND DISSOLVED CONCENTRATION)
Aluminum
Aluminum
Antimony
Antimony
Arsenic
Arsenic
Barium
Barium
Beryllium
Beryllium
Boron
Boron
Cadmium
TOT
Dis
TOT
Dis
TOT
Dis
TOT
Dis
TOT
DIS
TOT
Dis
TOT
Reporting Units
µg/L
pg/L
µg/L
µg/L
µg/L
pg/L
µg/L
pg/L
µg/L
µg/L
µg/L
µg/L
µB/L
15A NCAC 02B (Class Br)
NE
NE
3101z
160"
NE
NE
10
NE
NE
340
150
21000
NE
NE
NE
NE
65
6.5
7301"
NE
NE
USEPA NRWQC (Aquatic Life and Human Health)'
Location ID
Sample Collection Date
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic Mean
Analytical Result
Analytical Result
Analytical Result
SW-02-Al
1/24/2022
72
72
71
52t
12
<1
<1
< 1
< 1
0*
0*
o*
53
49
<1
<1
0*
0*
0*
6j
<50
0.034j
SW-2-AS (2)'
1/24/2022
70
70
<1
<1
<1
<1
0*
51
48
<1
<1
0*
<50
<50
<0.1
SW-2-A3
1/27/2022
14
14
NA
<1
<1
< 1
< 1
0*
NA
60
60
<1
<1
0*NA
6j
7i
0.034i
SW-3-A1
1/24/2022
138
138
85
62
<1
<1
< 1
< 1
0*43
0*0*SW-3-A1(2)'
0*
39
<1
<1
0*48j
W
44j
<0.1
1/24/2022
31
31
<1
0.414j
<1
<1
0*
43
40
<1
<1
0*
47j
42j
<0.1
SW-3-Al
1/27/2022
17
17
NA
<1
<3
<1
<1
0*
NA
43
42
<1
<1
0*
NA
43j
43j
<0.1
SW-4B-Al
1/24/2022
118
118
140
109
<10
<1
<1
< 1
< 1
0*
0*
0*
24
22
<1
<1
0*
W
W
129
121
<0.1
SW-4B-AI(2)s
1/24/2022
162
162
<10
<1
<1
< 1
< 1
0*
24
22
<1
<1
0*
129
122
<0.1
SW-4B-AI
1/27/2022
47
47
NA
<10
<1
<1
0.206j
< 1
0*
NA
24
23
<1
<1
0*
NA
117
118
<0.1
SW-4C-Al
1/24/2022
198
198
132
105
3i
<1
<0.5
< 1
< 1
0*
0*
W
25
22
<1
<1
0*
0*
0*
105
98
<0.1
SW-4C-A1
1/24/2022
66
66
5j
<1
<1
< 1
< 1
0*
25
22
<1
<1
0*
107
99
<0.1
SW-4C-Al_
1/27/2022
51
51
NA
4j
<1
<1
<1
<1
0*
NA
24
24
<1
<1
0*
NA
97
97
<0.1
SW-5-Al
1/24/2022
95
95
74
62
14
<1
<1
0.923j
0.461j
0*
0*
0*
96
80
<1
<1
0*
0*
0*
147
136
<0.1
SW-5-Al(2)'
1/24/2022
53
53
14
<1
<1
0.704i
0.483i
0*
90
80
<1
<1
0*
146
137
<0.1
SW-5-Al
1/27/2022
39
39
NA
12
<1
<1
0.596j
0.539j
0*
NA
89
88
<1
<1
0*
NA
154
156
<0.1
SW-6-Al
1/24/2022
294
294
196
150
6j
<1
<1
0.498j
0.212j
0*
0*
0*
23
19
<1
<1
0*
0*
0*
14j
llj
<0.1
SW-6-Al (2)'
1/24/2022
97
97
6i
<1
<1
0.352j
0.223i
0*
21
19
<1
<1
0*
13j
l0j
<0.1
SW-6-Al
1/27/2022
58
58
NA
4i
<1
<1
0.327i
0.159j
0*
NA
24
23
<1
1
0*
NA
12j
13i
<0.1
SW-8-Al
1/24/2022
465
465
321
240
20
<1
<0.5
607
292
292
287
295
304
233
<1
<1
0*
0*
0*
990
928
<0.1
SW-8-Al
1/24/2022
177
177
19
<1
<1
437
281
281
275
237
<1
<1
0*
990
949
<0.1
SW-8-Al
1/27/2022
77
77
NA
16
<1
465
312
312
274
254
<1
<1
0*
NA
985
991
<0.1
SW-9-Al
1/24/2022
19
19
19
Sa
4j
<1
<1
1.5
< 1
0*
0*
0*
52
48
<1
<1
0*
0*
W
22j
23j
<0.1
SW-9-Al (2)'
1/24/2022
18
18
5j
<1
<1
0.293i
0.196i
0*
51
52
<1
<1
0*
34j
37j
<0.1
SW-9-Al
1/27/2022
113
113
NA
4j
<1
<1
1.99
< 1
0*
NA
47
45
<1
<1
0*
NA
136
135
<0.1
Notes:
0 -North Carolina 1SA NCAC 028 .0211 non -hardness dependent criteria for Class B Surface Waters.
0 -North Carolina 1SA NCAC 028 .0211 hardness dependent criteria for Class a Surface Waters.
EM - USEPA NRWQC for CMC or CCC Aquatic Life and Human Health
E-M -North Carolina In -Stream Target Values for Surface Waters. Established per language in 15A NCAC 02B .0202 and .0208.
0 -Merged cells with fill indicate an average value that is compared to the non -hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 -Merged cells with fill indicate an average value that is compared to the hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 -Merged cells with fill indicate an average value that is compared to the acute or chronic criteria compared to USEPA NRWQC for Aquatic Life and Human Health.
Bold values indicate concentration is greater than the comparison criteria.
Surface water sample location SW-2-Al is an approved background monitoring location.
1) 15A NCAC 02B .0101 Class B = freshwaters protected for primary recreation which includes swimming on a frequent or organized basis and all Class C uses.
2) USEPA NRWQC Aquatic Life and Human Health =Aquatic Life and Human Health criteria applicable to alkalinity, aluminum, antimony, iron, and manganese.
3) Syn7erra is not NC certified for these parameters. Data collected for information purposes only.
4) Dissolved oxygen values presented are instantaneous values.
5) Designates the same sample location sampled later on the same date within one hour for comparison to acute criteria. See "Acute" definition below.
6) Asheville Airport - Area 1 is located in the mountain and upper piedmont region.
7) Calculated hardness dependent metal standards represent most conservative value. Standards are calculated using 25 mg/L hardness, regardless if actual instream hardness values are greater than 25 mg/L.
8) Total Cr(VI) values are presented as dissolved Cr (VI), as hexavalent chromium is assumed to be in an aqueous (dissolved) phase.
9) Chromium speciation is not performed for trivalent chromium (Cr(III)). Trivalent values are derived by subtracting hexavalent chromium values from dissolved chromium values.
Where a dissolved chromium value is less than the detection limit ("<"), it is considered a whole number for purposes of deriving a trivalent chromium value.
10) Toxic Substance Level.
11) Criterion Continuous Concentration (chronic) of 20 mg/L is a minimum value except where alkalinity is naturally lower, in which case the criterion cannot be lower than 25% of the natural level.
12) USEPA criteria for aluminum (December 2018) - criteria based on waters with a pH = 6.5 S.U, DOC = 1 mg/L, and Hardness = 25 mg/L.
<- concentration not detected at or above the adjusted reporting limit.
greater than or equal to
less than or equal to
- In -stream target value represents total chronic concentration.
* Per DEQ NPDES DMR reporting guidance, values below the Practical Quantitation Limit are treated as zero for averaging purposes.
Acute -Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour."
Reference 15A NCAC 02B .0211(11) (e)
Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or
as a 96-hour average" Reference 15A NCAC 028 .0211 (11) (e)
Deg C - Degrees Celsius
CIS - Inorganic dissolved concentration (with filter size 0.45µ)
GPM - gallons per minute
j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MI - Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable.
mg/L - milligrams per liter
TV - millivolts
NA - not applicable
NE - not established
NM - not measured
NRWQC - National Recommended Water Quality Criteria
NTUs - Nephelometric Turbidity Units
S.U. -Standard Unit
TOT- Inorganic total concentration
USEPA - United States Environmental Protection Agency
USEPA NRWQC Criterion Maximum Concentration (CMC). Evaluated using an average of two or more samples collected within one hour.
USEPA NRWQC Criterion Continuous Concentration (CCC). Evaluated using averages of a minimum of four samples taken on consecutive days, or as a 96-hour average.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Page 2 of 5

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLECTHER, NC
Analytical Parameter
INORGANIC PARAMETERS (TOTAL CONCENTRATION AND DISSOLVED CONCENTRATION) (Continued)
Cadmium
Calcium
Chloride
Chromium
Chromium
Chromium (III)'
Chromium (VI)a
Cobalt
Cobalt
Copper
Copper
Fluoride
DIS
TOT
TOT
TOT
DIS
DIS
TOT
TOT
Dis
TOT
DIS
TOT
Reporting Units
µg/L
mg/L
mg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg L
mg/L
15A NCAC 0213 (Class B')
NE
NE
0.82'
0.15,
NE
230"
NE
NE
NE
NE
183'
23.8'
NE
NE
16
11
1.6"
NE
NE
NE
NE
3,64'
2,74'
1.8
USEPA NRWQC (Aquatic Life and Human Health)'
Location ID
Sample Collection Date
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
SW-02-Al
1/24/2022
<0.1
0*
0*
0*
6.03
16
0.3661
0.217i
0.154
0.154
0.14
0.16
0.063
0.063
0.07
0.08
0.377j
0.373j
0.842j
<2
0*
0*
1*
<0.1
SW-2-Al (2)'
1/24/2022
<0.1
0*
5.8
16
0.375i
0.196i
0.123
0.123
0.073
0.073
0.371i
0.365i
<2
<2
0*
<0.1
SW-2-Al
1/27/2022
<0.1
0*
NA
6.54
18
0.357i
0.302j
0.21
0.21
NA
0.092
0.092
NA
0.436i
0.407i
<2
<2
0*
NA
<0.1
SW-3-Al
1/24/2022
<0.1
0*
o*
0*
9.06
15
0.362i
<1
0.955
0.955
0.95
0.69
0.045
0.045
0.05
0.05
0.736i
0.649j
<2
<2
0*
0*
0*
<0.1
SW-3-Al (2)'
1/24/2022
<0.1
0*
9.22
15
0.261j
<1
0.942
0.942
0.058
0.058
0.666i
0.668j
<2
<2
0*
<0.1
SW-3-Al
1/27/2022
<0.1
0*
NA
8.94
14
<1
0.218j
0.16
0.16
NA
0.058
0.058
NA
0.569i
0.58j
<2
<2
0*
NA
<0.1
SW-4B-A1
1/24/2022
<0.1
0*
o*
0*
7.43
3
0.237j
<1
<1
0*
0*
0*
<0.025
0*
0*
0*
0.655i
0.57j
<2
<2
0*
0*
0*
<0.1
SW-4B-A1(2)'
1/24/2022
<0.1
0*
7.42
3
0.266j
<1
<1
0*
<0.025
0*
0.594,
0.568j
<2
<2
0*
<0.1
SW-4B-A1
1/27/2022
<0.1
W
NA
7.11
2.7
<1
<1
<1
0*
NA
<0.025
0*
NA
0.753i
0.679j
<2
<2
0*
NA
<0.1
SW-4C-A1
1/24/2022
<0.1
0*
0*
0*
5.84
2.3
0.37j
0.2i
0.122
0.122
0.51
0.42
0.078
0.078
0.09
0.10
0.879i
0.698j
<2
<2
0*
0*
0*
<0.1
SW-4C-A1
1/24/2022
<0.1
0*
6
2.4
0.274j
<1
0.907
0.907
0.093
0.093
0.712i
0.643j
<2
<2
0*
<0.1
SW-4C-A1
1/27/2022
<0.1
0*
NA
5.73
2.1
0.224j
0.338j
0.218
0.218
NA
0.12
0.12
NA
0.606i
0.576j
26.6
<2
0*
NA
<0.1
SW-5-Al
1/24/2022
<0.1
0*
0*
0*E473
23.6
18
<1
<1
<1
0*
0*
0*
<0.025
0*
0*
0*
3.68
3.73
<2
<2
0*
0*
0*
0.081
SW-S-Al(2)'
1/24/2022
<0.1
0*
18
0.193j
<1
<1
0*
<0.025
0*
3.58
3.67
<2
<2
0*
0.081
SW-5-Al
1/27/2022
<0.1
0*
NA
19
<1
0.2551
<1
0*
NA
<0.025
0*
NA
3.17
3.08
<2
<2
0*
NA
0.081
SW-6-Al
1/24/2022
<0.1
0*
0*
0*
9.2
0.317j
<1
<3
0*
0*
0*
<0.025
0*
0*
0*
2.47
2.45
0.805i
<2
0*
0*
0*
<0.1
SW-6-Al (2)'
1/24/2022
<0.1
0*
9.2
0.222j
<1
<1
0*
<0.025
0*
2.3
2.37
<2
<2
0*
<0.1
SW-6-AI
1/27/2022
<0.1
0*
NA
SO
<1
0.229j
<1
0*
NA
<0.025
0*
NA
2.9
2.86
<2
<2
0*
NA
<0.1
SW-8-Al
1/24/2022
<0.1
0*
0*
0*
136
3.6
0.273j
<1
<1
0*
0*
0*
<0.025
0*
0*
0*
7.18
7.33
<2
<2
0*
0*
0*
0.6
SW-8-Al
1/24/2022
<0.1
0*
136
3.6
<1
<1
<1
0*
<0.025
0*
6.9
6.97
<2
<2
0*
0.65
SW-8-Al
1/27/2022
<0.1
0*
NA
142
3.4
<1
0.193j
<1
0*
NA
<0.025
0*
NA
7.18
7.02
<2
<2
0*
NA
0.58
SW-9-Al
1/24/2022
<0.1
0*
o*
0*
8.31
18
< 1
< 1
0.962
0.962
0.96
0.96
0.038
0.038
0.04
0.04
0.845 j
0.854 j
< 2
< 2
0*
0*
o*<0.1SW-9-Al
< 0.1
SW-9-AS (2)'
1/24/2022
<0.1
0*
��8
l8
0.196j
<1
0.964
0.964
0.036
0.036
0976j
0.936j
<2
<2
0*
1/27/2022
<0.1
0*
NA
12
<1
0.243j
<1
0*
NA
<0.025
0*
NA
2.21
2.24
<2
<2
0*
NA
0.1 777
Notes:
0 -North Carolina 1SA NCAC 028 .0211 non -hardness dependent criteria for Class B Surface Waters.
0 -North Carolina 1SA NCAC 028 .0211 hardness dependent criteria for Class a Surface Waters.
EM - USEPA NRWQC for CMC or CCC Aquatic Life and Human Health
E-M -North Carolina In -Stream Target Values for Surface Waters. Established per language in 15A NCAC 02B .0202 and .0208.
0 -Merged cells with fill indicate an average value that is compared to the non -hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 -Merged cells with fill indicate an average value that is compared to the hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 -Merged cells with fill indicate an average value that is compared to the acute or chronic criteria compared to USEPA NRWQC for Aquatic Life and Human Health.
Bold values indicate concentration is greater than the comparison criteria.
Surface water sample location SW-2-Al is an approved background monitoring location.
1) 15A NCAC 02B .0101 Class B = freshwaters protected for primary recreation which includes swimming on a frequent or organized basis and all Class C uses.
2) USEPA NRWQC Aquatic Life and Human Health =Aquatic Life and Human Health criteria applicable to alkalinity, aluminum, antimony, iron, and manganese.
3) Syn7erra is not NC certified for these parameters. Data collected for information purposes only.
4) Dissolved oxygen values presented are instantaneous values.
5) Designates the same sample location sampled later on the same date within one hour for comparison to acute criteria. See "Acute" definition below.
6) Asheville Airport - Area 1 is located in the mountain and upper piedmont region.
7) Calculated hardness dependent metal standards represent most conservative value. Standards are calculated using 25 mg/L hardness, regardless if actual instream hardness values are greater than 25 mg/L.
8) Total Cr(VI) values are presented as dissolved Cr (VI), as hexavalent chromium is assumed to be in an aqueous (dissolved) phase.
9) Chromium speciation is not performed for trivalent chromium (Cr(III)). Trivalent values are derived by subtracting hexavalent chromium values from dissolved chromium values.
Where a dissolved chromium value is less than the detection limit ("<"), it is considered a whole number for purposes of deriving a trivalent chromium value.
10) Toxic Substance Level.
11) Criterion Continuous Concentration (chronic) of 20 mg/L is a minimum value except where alkalinity is naturally lower, in which case the criterion cannot be lower than 25% of the natural level.
12) USEPA criteria for aluminum (December 2018) - criteria based on waters with a pH = 6.5 S.U, DOC = 1 mg/L, and Hardness = 25 mg/L.
<- concentration not detected at or above the adjusted reporting limit.
greater than or equal to
less than or equal to
- In -stream target value represents total chronic concentration.
* Per DEC. NPDES DMR reporting guidance, values below the Practical Quantitation Limit are treated as zero for averaging purposes.
Acute - "Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour."
Reference 1SA NCAC 02B .0211(11) (a)
Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or
as a 96-hour average" Reference 15A NCAC 02B .0211(11) (e)
Deg C - Degrees Celsius
DIS - Inorganic dissolved concentration (with filter size 0.45µ)
GPM - gallons per minute
j - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
M1- Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable.
mg/L - milligrams per liter
mV - millivolts
NA- not applicable
NE - not established
NM - not measured
NRWQC - National Recommended Water Quality Criteria
NTUs - Nephelometric Turbidity Units
S.U. - Standard Unit
TOT - Inorganic total concentration
USEPA - United States Environmental Protection Agency
USEPA NRWQC Criterion Maximum Concentration (CMC). Evaluated using an average of two or more samples collected within one hour.
USEPA NRWQC Criterion Continuous Concentration (CCC). Evaluated using averages of a minimum of four samples taken on consecutive days, or as a 96-hour average.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Page 3 of 5

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLECTHER, NC
Analytical Parameter
INORGANIC PARAMETERS (TOTAL CONCENTRATION AND DISSOLVED CONCENTRATION) (Continued)
Iron
Iron
Lead
Lead
Magnesium
Manganese
Manganese
Mercury
Mercury
Methane
Molybdenum
Molybdenum
Nickel
Nickel
TOT
Dis
TOT
DIS
TOT
TOT
Dis
TOT
Dis
TOT
TOT
Dis
TOT
DIS
Reporting Units
µg/L
µg/L
µg/L
µg/L
mg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
µg/L
L
15A NCAC 02B (Class Bi)
NE
NE
NE
NE
NE
13.88'
0.54'
NE
100
NE
NE
NE
NE
0.012
NE
NE
2000
NE
NE
NE
NE
144.9'
16.1'
NE
NE
7,1
USEPA NRWQC (Aquatic Life and Human Health)'
Location ID
Sample Collection Date
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute
Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic
Mean
SW-02-Al
1/24/2022
1060
1060
1,029
991
804
0.443
0.051j
0'
0*
0*
2.6
179
177
0.00243
0.00243
0.00258
00.002
0.0012
22.3
< 1
< 1
1.73
0.344j
0'
0'
0*
SW-2-Al (2)'
1/24/2022
998
998
764
0.416
<0.2
0'
2.5
173
171
0.00273
0.0027
0.00143
28.6
<1
<1
0.725j
0.3251
0'
SW-2-Al
1/27/2022
916
916
NA
844
0.216
<0.2
0'
NA
2.96
198
200
0.00128
0.00128
NA
0.000707
20.3
<1
<1
0.322j
<1
0'
NA
SW-3-Al
1/24/2022
686
686
404
404
141
0.33
<0.2
0'
0*
0*
3.59
278
258
0.00173
0.00173
0.00134
0.001
0.000767
10.7
0.183j
<1
0.426j
0.375j
0'
0'
0*
SW-3-Al (2)'
1/24/2022
273
273
149
0.189j
<0.2
0'
3.62
267
258
0.000948
0.000948
0.000811
<10.0
<1
<1
0.38j
0.376j
0'
SW-3-Al
1/27/2022
252
252
NA
191
0.196j
<0.2
0'
NA
3.64
225
225
0.00081
0.00081
NA
0.000862
21.6
<1
<1
0.36j
0.3471
0'
NA
SW-4B-A1
1/24/2022
943
943
781
854
394
0.184j
<0.2
0'
0*
o*
3.77
217
197
0.000636
0.000636
0.00101
0.001
<0.0005
38
<1
<1
<1
<1
0'
0'
0'
SW-4B-A1(2)s
1/24/2022
618
618
396
0.197J
<0.2
0'
3.76
203
196
0.00139
0.00139
<0.0005
36.4
<1
<1
<1
<1
0'
SW-4B-A1
1/27/2022
1,000
1,000
NA
440
0.164j
<0.2
0'
NA
3.72
251
237
<0.0005
0'
NA
<0.0005
38.5
<1
<1
<1
<1
0'
NA
SW-4C-A1
1/24/2022
1080
1080
NA
649
186
0.251
<0.2
0'
0'
0*
3.22
286
257
0.00106
0.00106
0.00087
0.001
<0.0005
56.3
< 1
< 1
0.317 j
0.3011
0'
0'
0'
SW-4C-A1
1/24/2022
473
473
NA
185
0.1731
<0.2
0'
3.28
273
256
0.000685
0.000685
0'
<0.0005
49.4
<1
<1
0.2721
0.2721
0'
SW-4C-A1
1/27/2022
395
395
NA
168
0.191j
<0.2
0'
NA
3.23
235
228
<0.0005
NA
0.000581
54.8
<1
<1
2.3
0.284j
0'
NA
SW-5-Al
1/24/2022
17,800
17,800
16,400
15,567
11,800
0.1731
<0.2
0'
0*
0*
6.11
2,670
2,450
0.00127
0.00127
0.00125
0.001
0.000632
1,980
2.41
1.92
<1
<1
0'
0.70
0.46
SW-S-Al(2)'
1/24/2022
15,000
15,000
11,700
0.2
<0.2
0'
5.9
2,540
2,440
0.00123
0.00123
<0.0005
1,930
2.1
1.88
<1
1.39
1.39
SW-S-Al
1/27/2022
13,900
13,900
NA
13,100
0.135j
<0.2
0'
NA
6.59
2,460
2,450
0.000726
0.000726
NA
0.000975
1,420
1.91
1.89
<1
<1
0'
NA
SW-6-Al
1/24/2022
8,380
8,380
7,140
6,483
3,470
0.29
<0.2
0'
0*
W
2.33
528
501
0.00125
0.00125
0.00210
0.002
<0.0005
464
<1
<1
0.4021
<1
0'
0'
0*
SW-6-Al (2)'
1/24/2022
5,900
5,900
3,720
0.197J
<0.2
0'
2.24
512
491
0.00294
0.00294
0.00105
581
<1
<1
0.268j
0.2871
0'
SW-6-AS
1/27/2022
5,170
5,170
NA
3,010
0.156j
<0.2
0'
NA
L42
570
550
0.000514
0.000514
NA
0.000716
486
<1
<1
0.311j
0.2651
0'
NA
SW-8-Al
1/24/2022
29,900
29,900
NA
25,800
16,500
0.318
<0.2
0'
0'
0*
25.3
5,100
4860
0.0025
0.0025
0.00231
0.002
0.000907
9,570
57.9
60.3
0.4311
0.2631
0'
0'
0*
SW-8-Al
1/24/2022
23,300
23,300
NA
16,900
0.238
<0.2
0'
25.3
5,050
4950
0.00212
0.00212
0'
0.00178
10,500
56.5
57.5
0.305j
0.26j
0'
SW-8-Al
1/27/2022
24,200
24,200
18,100
0.148j
<0.2
0'
NA
26.4
5,050
5040
<0.0005
1 NA
<0.0005
14,100
59.7
59.6
<1
<1
0*
NA
SW-9-Al
1/24/2022
434
434
422
584
259
0.166j
<0.2
0'
0'
0*
3.48
353
358
0.0023
0.0023
0.00228
1 0.002
0.00203
39.0
0.339j
< 1
0.418j
0.475j
0'
0.00
0.40
SW-9-Al (2)'
1/24/2022
410
410
269
0.159j
<0.2
0'
3.79
391
402
0.00225
0.00225
0.00256
31.4
0.213j
0.209j
0.47j
0.57j
0'
SW-9-Al
1/27/2022
908
908
NA
192
0.171j
<0.2
0'
NA
6.75
755
738
0.000627
0.000627
NA
0.000667
19.7
0.795j
0.672j
1.22
1.2
1.2
NA
Notes:
0 - North Carolina 1SA NCAC 028 .0211 non -hardness dependent criteria for Class B Surface Waters.
0 - North Carolina 1SA NCAC 028 .0211 hardness dependent criteria for Class a Surface Waters.
E - USEPA NRWQC for CMC or CCC Aquatic Life and Human Health
E-M - North Carolina In -Stream Target Values for Surface Waters. Established per language in 15A NCAC 02B .0202 and .0208.
0 - Merged cells with fill indicate an average value that is compared to the non -hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 - Merged cells with fill indicate an average value that is compared to the hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 - Merged cells with fill indicate an average value that is compared to the acute or chronic criteria compared to USEPA NRWQC for Aquatic Life and Human Health.
Bold values indicate concentration is greater than the comparison criteria.
Surface water sample location SW-2-Al is an approved background monitoring location.
1) 15A NCAC 02B .0101 Class B = freshwaters protected for primary recreation which includes swimming on a frequent or organized basis and all Class C uses.
2) USEPA NRWQC Aquatic Life and Human Health =Aquatic Life and Human Health criteria applicable to alkalinity, aluminum, antimony, iron, and manganese.
3) Syn7erra is not NC certified for these parameters. Data collected for information purposes only.
4) Dissolved oxygen values presented are instantaneous values.
5) Designates the same sample location sampled later on the same date within one hour for comparison to acute criteria. See "Acute" definition below.
6) Asheville Airport - Area 1 is located in the mountain and upper piedmont region.
7) Calculated hardness dependent metal standards represent most conservative value. Standards are calculated using 25 mg/L hardness, regardless if actual instream hardness values are greater than 25 mg/L.
8) Total Cr(VI) values are presented as dissolved Cr (VI), as hexavalent chromium is assumed to be in an aqueous (dissolved) phase.
9) Chromium speciation is not performed for trivalent chromium (Cr(III)). Trivalent values are derived by subtracting hexavalent chromium values from dissolved chromium values.
Where a dissolved chromium value is less than the detection limit ("<"), it is considered a whole number for purposes of deriving a trivalent chromium value.
10) Toxic Substance Level.
11) Criterion Continuous Concentration (chronic) of 20 mg/L is a minimum value except where alkalinity is naturally lower, in which case the criterion cannot be lower than 25% of the natural level.
12) USEPA criteria for aluminum (December 2018) - criteria based on waters with a pH = 6.5 S.U, DOC = 1 mg/L, and Hardness = 25 mg/L.
<- concentration not detected at or above the adjusted reporting limit.
greater than or equal to
less than or equal to
- In -stream target value represents total chronic concentration.
*Per DEQ NPDES DMR reporting guidance, values below the Practical Quantitation Limit are treated as zero for averaging purposes.
Acute -Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour."
Reference 15A NCAC 02B .0211(11) (e)
Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or
as a 96-hour average" Reference 15A NCAC 028 .0211 (11) (e)
Deg C - Degrees Celsius
DIS - Inorganic dissolved concentration (with filter size 0.45µ)
GPM - gallons per minute
1- Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MI - Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable.
mg/L- milligrams per liter
TV - millivolts
NA - not applicable
NE - not established
NM - not measured
NRWQC - National Recommended Water Quality Criteria
NTUs - Nephelometric Turbidity Units
S.U. -Standard Unit
TOT - Inorganic total concentration
USEPA - United States Environmental Protection Agency
USEPA NRWQC Criterion Maximum Concentration (CIVIC). Evaluated using an average of two or more samples collected within one hour.
USEPA NRWQC Criterion Continuous Concentration (CCC). Evaluated using averages of a minimum of four samples taken on consecutive days, or as a 96-hour average.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Page 4 of 5

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLECTHER, NC
Analytical Parameter
INORGANIC PARAMETERS (TOTAL CONCENTRATION AND DISSOLVED CONCENTRATION) (Continued)
Nitrate+Nitrite
Potassium
Selenium
Selenium
Silver
Silver
Sodium
Strontium
Strontium
Sulfate
Thallium
Thallium
Total Dissolved
Solids
Vanadium
Vanadium
Zinc
Zinc
TOT
TOT
TOT
Dis
TOT
DIS
TOT
TOT
Dis
TOT
TOT
Dis
TOT
TOT
Dis
TOT
DIS
Reporting Units
mg/L
mg/L
µg/L
µg/L
µg/L
99/1.
mg/L
µg/L
µg/L
mg/L
µg/L
pg/L
mg/L
pg/L
µg/L
pg/L
pg/L
15A NCAC 02B (Class B)
NE
NE
NE
NE
NE
5
NE
NE
NE
NE
0.3'
0.06'
NE
40000
NE
NE
2
NE
NE
NE
NE
NE
NE
NE
36.f
36.5'
USEPA NRWQC (Aquatic Life and Human Health)'
Location ID
Sample Collection Date
Analytical Result
Analytical Result
Analytical Result
Value
Used
Acute
Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Value
Used
Acute
Mean
Chronic
Mean
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Analytical Result
Value Used
Acute Mean
Chronic
Mean
SW-02-Al
1/24/2022
2
1.43
< 1
0*
0*
0*
< 1
< 0.2
< 0.2
0*
0*
0*
7.43
55
51
1.2
0.07 j
0.07 j
65
0.169 j
0.147 j
9
5
5
2.5
3.7
SW-2-Al (2)'
1/24/2022
2
1.39
<1
0*
<1
<0.2
<0.2
0*
7.21
53
50
1.2
0.041i
0.064j
65
0.131j
0.132j
<5
4j
0*
SW-2-AS
1/27/2022
2.5
1.51
<1
0*
NA
<1
<0.2
<0.2
0*
NA
7.7
63
63
1.1
0.085j
0.072j
87
<0.3
<0.3
6
6
6
NA
SW-3-Al
1/24/2022
1.1
1.6
0.465i
0*
0*
0*
0.435i
<0.2
<0.2
0*
0*
a*
6.69
95
89
4
0.045j
0.167i
78
0.192i
<0.3
6
<5
0*
0.0
0.0
SW-3-Al (2)'
1/24/2022
1.1
1.6
0.421j
0*
0.482j
<0.2
<0.2
0*
6.84
97
89
4
0.087J
0.106i
81
<0.3
<0.3
4j
<5
0*
SW-3-Al
1/27/2022
1.2
1.54
0.457i
0*
NA
0.517i
<0.2
<0.2
0*
NA
6.09
95
95
3.2
0.046j
<0.2
78
<0.3
<0.3
6
6
0*
NA
SW-4B-A1
1/24/2022
0.31
1.19
2.28
2.28
2.26
2.24
2.15
<0.2
<0.2
0*
0*
a*
2.71
64
58
10
<0.2
0.073i
59
<0.3
<0.3
<5
<5
0*
0.0
0.0
SW-4B-A1(2)s
1/24/2022
0.3
1.18
2.23
2.23
2.18
<0.2
<0.2
0*
2.7
63
59
10
<0.2
0.058j
59
0.126i
<0.3
<5
<S
0*
SW-4B-A1
1/27/2022
0.33
1.11
2.22
2.22
NA
2.03
<0.2
<0.2
0*
NA
2.64
62
62
8.3
<0.2
<0.2
48
<0.3
<0.3
<5
<5
0*
NA
SW-4C-A1
1/24/2022
0.53
1.1
3.22
3.22
3.19
3.25
3.37
3.22
<0.2
<0.2
0*
0*
0*
2.45
53
48
7.6
<0.2
0.0431
41
0.195j
<0.3
4j
<5
0*
0.0
0.0
SW-4C-A1
1/24/2022
0.53
1.08
3.16
3.16
<0.2
<0.2
0*
2.49
54
49
7.8
<0.2
0.0431
50
<0.3
<0.3
<5
<5
0*
SW-4C-A1
1/27/2022
0.56
1.03
3.38
3.38
NA
3.49
<0.2
<0.2
0*
NA
2.4
53
53
6.5
<0.2
<0.2
55
<0.3
<0.3
5j
<5
0*
NA
SW-5-Al
1/24/2022
0.14
2.37
<1
0*
0*
0*
<1
<0.2
<0.2
0*
0*
0*
5.98
376
333
6.3
<0.2
<0.2
136
<0.3
<0.3
6
<S
0*
o*
0*
SW-S-Al(2)'
1/24/2022
0.13
2.28
<1
0*
<1
<0.2
<0.2
0*
5.76
362
330
6.3
<0.2
<0.2
139
<0.3
<0.3
7
<S
0*
SW-S-Al
1/27/2022
0.091
2.3
<1
0*
NA
<1
<0.2
<0.2
0*
NA
6.4
389
389
4.7
<0.2
<0.2
128
<0.3
<0.3
4j
5j
0*
NA
SW-6-Al
1/24/2022
<0.040
1.95
<1
0*
0*
0*
<1
<0.2
<0.2
0*
0*
0*
3.01
31
28
3.5
0.0871
0.117i
52
0.319
<0.3
<5
<5
0*
0*
0*
SW-6-Al (2)'
1/24/2022
<0.040
1.93
<1
0*
<1
<0.2
<0.2
0*
2.94
29
26
3.5
0.042j
0.083j
54
0.124j
<0.3
<5
<S
0*
SW-6-AS
1/27/2022
<0.040
1.92
<1
0*
NA
<1
<0.2
<0.2
0*
NA
3.45
32
32
3
<0.2
<0.2
45
<0.3
<0.3
<5
<S
0*
NA
SW-8-Al
1/24/2022
0.093 M1
4.41
<1
0*
0*
0*
<1
<0.2
<0.2
0*
0*
0*
6.18
2380
2190
21
<0.2
0.056i
492
0.705
0.17j
<5
<5
0*
0.0
0.0
SW-8-Al
1/24/2022
0.092
4.39
<1
0*
<1
<0.2
<0.2
0*
6.2
2380
2200
21
<0.2
<0.2
476
0.352
0.16j
<5
<5
0*
SW-8-Al
1/27/2022
<0.040
4.34
<1
0*
NA
<1
<0.2
<0.2
0*
NA
6.15
2480
2480
19
<0.2
<0.2
476
0.285j
0.199j
<5
<5
0*
NA
SW-9-Al
1/24/2022
2
1.61
<1
0*
0*
0*
<1
<0.2
<0.2
0*
0*
0*
8.39
75
71
2.9
<0.2
0.0441
81
<0.3
<0.3
<5
<5
0*
0.0
0.0
SW-9-Al (2)'
1/24/2022
2
1.62
<1
0*
<1
<0.2
<0.2
0*
8.04
85
91
3.7
<0.2
0.044J
81
<0.3
<0.3
<5
<S
0*
SW-9-Al
1/27/2022
0.13
1.79
0.247j
o*
0.285j
<0.2
<0.2
0*
NA
5.22
168
165
8.7
<0.2
<0.2
103
<0.3
<0.3
4j
4j
0*
NA
Notes:
0 - North Carolina 1SA NCAC 028 .0211 non -hardness dependent criteria for Class B Surface Waters.
0 - North Carolina 1SA NCAC 028 .0211 hardness dependent criteria for Class 8 Surface Waters.
E - USEPA NRWQC for CMC or CCC Aquatic Life and Human Health
E-M - North Carolina In -Stream Target Values for Surface Waters. Established per language in 15A NCAC 02B .0202 and .0208.
0 - Merged cells with fill indicate an average value that is compared to the non -hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 - Merged cells with fill indicate an average value that is compared to the hardness dependent acute or chronic 15A NCAC 02B .0211 criteria.
0 - Merged cells with fill indicate an average value that is compared to the acute or chronic criteria compared to USEPA NRWQC for Aquatic Life and Human Health.
Bold values indicate concentration is greater than the comparison criteria.
Surface water sample location SW-2-Al is an approved background monitoring location.
1) 15A NCAC 02B .0101 Class B = freshwaters protected for primary recreation which includes swimming on a frequent or organized basis and all Class C uses.
2) USEPA NRWQC Aquatic Life and Human Health =Aquatic Life and Human Health criteria applicable to alkalinity, aluminum, antimony, iron, and manganese.
3) SynTerra is not NC certified for these parameters. Data collected for information purposes only.
4) Dissolved oxygen values presented are instantaneous values.
5) Designates the same sample location sampled later on the same date within one hour for comparison to acute criteria. See "Acute" definition below.
6) Asheville Airport - Area 1 is located in the mountain and upper piedmont region.
7) Calculated hardness dependent metal standards represent most conservative value. Standards are calculated using 25 mg/L hardness, regardless if actual instream hardness values are greater than 25 mg/L.
8) Total Cr(VI) values are presented as dissolved Cr (VI), as hexavalent chromium is assumed to be in an aqueous (dissolved) phase.
9) Chromium speciation is not performed for trivalent chromium (Cr(III)). Trivalent values are derived by subtracting hexavalent chromium values from dissolved chromium values.
Where a dissolved chromium value is less than the detection limit ("<"), it is considered a whole number for purposes of deriving a trivalent chromium value.
10) Toxic Substance Level.
11) Criterion Continuous Concentration (chronic) of 20 mg/L is a minimum value except where alkalinity is naturally lower, in which case the criterion cannot be lower than 25% of the natural level.
12) USEPA criteria for aluminum (December 2018) - criteria based on waters with a pH = 6.5 S.U, DOC = 1 mg/L, and Hardness = 25 mg/L.
<- concentration not detected at or above the adjusted reporting limit.
greater than or equal to
less than or equal to
- In -stream target value represents total chronic concentration.
*Per DEQ NPDES DMR reporting guidance, values below the Practical Qua mitation Limit are treated as zero for averaging purposes.
Acute - "Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour."
Reference 1SA NCAC 02B .0211(11) (e)
Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or
as a 96-hour average" Reference 15A NCAC 02B .0211(11) (e)
Deg C - Degrees Celsius
DIS - Inorganic dissolved concentration (with filter size 0.45µ)
GPM - gallons per minute
i - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
M1- Matrix spike recovery was high: the associated Laboratory Control Spike (LCS) was acceptable.
mg/L - milligrams per liter
mV - millivolts
NA- not applicable
NE - not established
NM - not measured
NRWQC - National Recommended Water Quality Criteria
NTUs - Nephelometric Turbidity Units
S.U. - Standard Unit
TOT - Inorganic total concentration
USEPA - United States Environmental Protection Agency
USEPA NRWQC Criterion Maximum Concentration (CMC). Evaluated using an average of two or more samples collected within one hour.
USEPA NRWQC Criterion Continuous Concentration (CCC). Evaluated using averages of a minimum of four samples taken on consecutive days, or as a 96-hour average.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
Created by: RHJ Checked by: KCS
Page 5 of 5

TABLE 3
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED SURFACE WATER QUALITY STANDARDS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Site
Parameter
Sample ID
Result
Units
15A NCAC 02B
Background
Cause and Significance
Standard
Concentration
Range
Pre-existing condition - consistent with historical results. Downgradient surface water location
Arsenic (dissolved)
SW-8-Al
29S (chronic)
µg/L
1S0 (chronic)
<0.1- 0.17
SW-3-Al, representative of overall surface water quality, is less than the 02B standard for
dissolved arsenic.
SW-4C-Al
3.45
Within Site background concentration range - naturally occurring
Dissolved Oxygen*
mg/L
4 (minimum)
3.25 - 10.01
Low flow conditions potentially contribute to decreased DO. Downgradient surface water
SW-8-Al
1.78
location SW-3-Al, representative of overall surface water quality, is greater than 02B
minimum for DO.
Low DO potentially contribute to decreased pH. Downgradient surface water location SW-3-
PH*
SW-4C-Al
5.7
S.U.
6.0 - 9.0
6.0 - 6.8
Al, representative of overall surface water quality, is within the 02B standard range for pH.
High turbidity due to low flow conditions. Downgradient surface water location SW-3-Al,
Turbidity*
SW-8-Al
296
NTU
50
0.6 - 34.1
representative of overall surface water quality, is less than the 02B standard for turbidity.
Notes:
15A NCAC 02B .0200 (02B) Standard refers to Class B Surface Water Standards as found in 15A NCAC 02B .0200 Surface Water Quality Standards, last amended on November 1, 2019.
Chronic - "Compliance with chronic instream metals standards shall only be evaluated using averages of a minimum of four samples taken on consecutive days, or
as a 96-hour average" Reference 15A NCAC 02B .0211 (11) (e)
* Results represent greatest (or least for dissolved oxygen and pH) analytical value of three samples collected over a 96 hour period in January 2022.
Background ranges are based on data from approved background surface water monitoring location SW-2-Al through January 2022.
µg/L- micrograms per liter
mg/L- milligrams per liter
NTU - nephelometric turbidity units
S.U. - standard units
Prepared by: KHF Checked by: TAH
Page 1 of 1

TABLE 4
PORE WATER PIEZOMETER WATER LEVELS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2022 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well ID
Associated Unit
Date
Depth to Water
(Ft-BTOC)
PZ-1
Area 1
01/24/2022
29.16
PZ-2
Area 1
01/24/2022
TM
PZ-2S
Area 1
01/24/2022
TM
PZ-3
Area 1
01/24/2022
TM
PZ-3D
Area 1
01/24/2022
TM
PZ-4
Area 1
01/24/2022
23.79
PZ-5
Area 1
01/24/2022
6.90
PZ-6
Area 1
01/24/2022
4.55
PZ-7
Area 1
01/24/2022
24.39
Prepared by: TAH Checked by: KHF
Notes:
ft - feet
BTOC - Below top of casing
TM - Transducer measurement - Monitoring wells have pressure transducers installed that record water levels continuously. Depth -to -pore
water is not measure manually.
Page 1 of 1

Quarterly Water Quality Monitoring Report — January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX A
SURFACE WATER SAMPLING LOGS
L7
symTerra
Science & Engineering Consultants

SURFACE WATER SAMPLING LOG
tip
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No.
Duke - 59.50.06
LOCATION:
Asheville Airport
FIELD PERSONNEL:
RHJ/GSD
WEATHER:
0 SUNNY 0 OVERCAST 0 RAIN 0 COOL 0 WARM
MULTI METER TYPE/S#:
YSI
TURBITIDY METER TYPE/S#
HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-24-22
gA ) � I . SAMPLE TIME: iq:5,5
TEMPERATURE
PH
CONDUCTANCE I DO ORP
TURBIDITY
READING
........
TIME ..............
(Whole # ' .
Celsius)
.... . ......
. . . ...........
(X.XX su)
(Whole #
(Whole # Wcm) (X.XX mg/L) MV)
.
COLOR
(X.X NTU)
lq3:5 J3, 6
SK
....... ......... ........ ........
J02
. . .. ... ... ............. .
% a ' 36 3
... .... .... .
ILI, 70
NUMBER OF CDNTATNM N U MR ER OF CONTAINERS
oel
6 61 Ile
CONSTITUENTS SAMPLED 01. 0- co
U
0 CONSTITUENTS SAMPLED 0 - I
U U-
E E- E E E E1 Ej E E-
in OF 0i
0 0 of 0- 0
.............................. ... . .....
L
. ....................... ............ . ........... ........... ............. . ---
4 ... . . ... ...
T
. . ............i.
COMMENTS:
P:kDuke Energy PrDgress.10200 FIELD PAPERWORKA2B-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone]. [phone] fax
www.synTerracorp.com
CLIENT/PROJECT N0. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-24-22
—,0Cjj SAMPLE TIME: /q 50
TEMPERATURE pH € CONDUCTANCE DO - ORP TURBIDITY
i
READING TIME COLOR
�_......
(Whole # ° •T'(Whole # .. Y ... ..
Celsius) (X.XX su) (Whole # µ5/cm) (X.XX mg/L) mV) X NTU)
.......
COMMENTS: —
ROuke Energy Progress.1026100 FIELD PAPERWORM213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
10
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER:
MULTI METER TYPE/S#: YSI
❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
SL - 3 *./
SAMPLE DATE: 1-24-22
SAMPLE TIME: P 3
TEMPERATURE
pH CONDUCTANCE DO
ORP TURBIDITY
READING TIME ............
(Whole # °
......... Celsius
.................... ........
h ._....., �.
COLOR
mole # (X.X NTU)
mv)'
(X.XX su) (Whole # µS/cm) (X.XX mg/L)
... ........... ......
'
_.:_:::.::..::.
NUMBER
OF
CONTAINERS
NUMBER
of
CONTAINERS
J
J
Ji
m
�
�
W
� i J J•
�
� �
W
CONSTITUENTS SAMPLED 0i.
0_
0
a
:E
J
J
m
CONSTITUENTS SAMPLED o 0 0
a
J
J J
u
u u
Q
i Ej
E'
E
E
E
E
J
E E E
E
E E
J
t ui:
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o:
in o o
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m
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m
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N
V
1f1
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m-
N Ill O
N om.
........................... ....�.......
.................................................. . .....
.... .:.....
O
7
N
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1n: O
N' m
•y
�'
_
...................
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORKI2B-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
,tip
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] - [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: 0 SUNNY 0 OVERCAST 0 RAIN 0 COOL 0 WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH2100Q
SAMPLE ID:
SAMPLE DATE: 1-24-22
SAMPLE TIME: Oq-5
TEMPERATURE
PH CONDUCTANCE
DO ORP
TURBIDITY
READING TIME
.F.
(Wholei'�
(X.XX 5u) (Whole # gS/cm)
. . .... ... ... ... . V�ol)e .. 11
(X.XX mg/L)
(X.X NTU)
COLOR
....................... . . .............
V
- — - — ----------------------------------
6.L
...... . ..... ....... ....
Z
NUMBER
OF
CONTA
I N E RS NUMBER OF CONTAINERS
CONSTITUENTS SAMPLED
0-
a
0
:E
CONSTITUENTS SAMPLED = a
.......
E
0
E
0
0
>
0
-C
E
U U L.z
E; E. E.. E-
0[ o - M- 01 0-
M! 0.uE10 01
. . ........................................... . .. . .............. J
OE
01 0
. ..
Ja
.. ....
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. . ................ . . ...........
........
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.. . ........
..
........ .
............
... . . ....... . ...... . —
.
.... . ......
... .
.. . ............... . ..................... .....
COMMENTS:
P:kDuke Energy Progress. 102600 FIELD PAPERWORM213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
100
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
SAMPLE DATE: 1-24-22
SAMPLE TIME: 1015
TEMPERATURE
READING TIME .:....._. ._...._._........_
ola # °
Celsius)
pH = CONDUCTANCE
�,
(X.XX su ) (Whole # µ em)
DO ORP ? TURBIDITY
.�..�...,_I..,..,..,�, - 3 COLOR
I
(X.XX mg/L) l (Whole i (X.X NTU)
l mV) 3-
_........ ........
NUMBER
OF
CONTAINERS
NUMBCONTAINERS.............
OF
w
_ aJ
SAMPLED O! aJN
s
CONSTITUENTS SAMPLED O
aCONSTITUENTS
JJ
O
u4]
u4]
u41I
I-
WQJ
JE
noo
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EE
o
u
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o[
O
N
i
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o
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o
7>JE
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= el
0O
.... ....... :.....
....
i
I
_
................
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.-...)
3
3
1_
I
1
-
I
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORQB-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
141P
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] - [phone] fax
vvww.synTerracorp.corn
CLIENT/PROJECT No. Duke - 59.50-06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: E] SUNNY 0 OVERCAST El RAIN 0 COOL 0 WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH2100Q
SAMPLE ID:
SAMPLE DATE: 1-24-22
SAMPLE TIME:
TEMPERATURE
PH
CONDUCTANCE
DO
ORP
TURBIDITY
READING . .. .. ....
TIME
(Whole #' :.
(X.XX su)
(Whole # I.&crn)
(X.)O( mg/L)
(Whole #
COLOR
(X.X NTU)
Celsius) 1.
MV)
6,/3
I
CONSTITUENTS SAMPLED
a
E
,n
a
E
0.
r.
ER
0
E
0
0.
Of
0
0.
CONTAINERS
E
N
-
U
E E
SAMPLED
CONSTITUENTS S
NUMBER
OF CONTAINERS
1
. ......
E
0
. ........
E
0
0
E
0
. . ..
U
E
..
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0
......... .
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.......
.......
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T
COMMENTS:
P:kDuke Energy Progress. 10200 FIELD PAPERWORM2131-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
tip
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] - [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: El SUNNY 0 OVERCAST 0 RAIN 0 COOL 0 WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/Sff HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-24-22
()W - qCA1 # L SAMPLE TIME: /0 q-5
TEMPERATURE PH CONDUCTANCE DO ORP T TURBIDITY
READING TIME . .... .
COLOR
(Whole
9
(X.XX su) (Whole (Whole # pVcm) (X.XX mg/L) (X.X NTU)
Celsius)MV)
........ ..... . .. ....
L ......... .. NUMBER
- -
OF
...
NUWRER
OF
iNERS
-
. ...
CONSTITUENTS SAMPLED 0 o
0
0
:E
CONSTITUENTS S AMPLED
0
0 0
>
U
<-
E
Ui U. .
E
E
E
E. E-V
-
E
El El
-gi
-
E- E E.
0
0
14l
0 0
0-
0 0
0
z i
... . ............ ...... . . . ..........
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j
......... . ................. .
. .. .
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. . . .......
. . . ....................
. .... . .. . . ....... . .........
.............. . . . ......
. .....
.............
.......... .
... . ... . . . ...
..
J.
. ........ ....... ............... — -------------
I 1
COMMENTS:
P:\Duke Energy Progress.1026100 FIELD PAPERWORK\213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�7
s�nTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
SAMPLE DATE: 1-24-22
SAMPLE TIME: / 0 S
TEMPERATURE
pH
CONDUCTANCE
DOTP
TURBIDITY
..............................
READING € TIME '.
#°
..........-........
....(Whole
COLOR
Celsius)
(X'
o e µ cm
(Wh I # 5/ )
(X XX mg/L)
X.X -
( NTU)
..................... _..............-i — ......—.--..._.. ............................... ...................,r.,:�,s�
- _ ....�
CONSTITUENTS SAMPLED
.. .. .. ..
........... ._.._. _._._..L.-.
...... ...
.......tea
O
E
N
... „i:
3
.. NUMBER.OF
o
J_
E;
-
-
!
o a"
JI j-
E;. E
i 0
0 F O
- ...
.,.........
CONTAINERS
f
a
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�n
N
..
u
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O
I!1
.....
€
�I m J
CONSTITUENTS SAMPLED o
u a a
E J E
a10
O V u1
OI '•I N
N,
-
...... ..................._........._.._...... ........ _..
€
'E
_
NUMBER
o
E
O
Ifl
N
o
E
O
O
Ill
OF
a
O
V
CONTAINERS
J
E
v1
N
J
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O
YI-
-N��
J
O'
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J
O.
...
_
E
COMMENTS:
P:IDuke Energy Progress. 1 026\00 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�11
synTerm
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: 0 SUNNY 0 OVERCAST 0 RAIN 0 COOL 0 WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH2100Q
SAMPLE ID: SAMPLE DATE: 1-24-22
-Sw, !SAI I SAMPLE TIME:
TEMPERATURE
pH CONDUCTANCE
DO
ORP
TURBIDITY
READING TIME
�ole#
. ... ..... .....
(Wholei
. .... . _41 COLOR
Celsius�
(X.XX su) (Whole 9 Wcm)
(X.XX mg/L)
— '
T
. M V) .......
(X.X NTU)
................. . ........................... . . . ...
b, 9,9 it:
_5 j
CONSTITUENTS SAMPLED
NUMBER
I d 0
OF
CONTAINERS
...
.........
CONSTITUENTS SAMPLED
NUMBER
IJ�
0
2
OF
0
CONTAINERS
:E
E E
E
E
0
E
0
E E E
Int0 0
v
0-
E
E
E
...............
. ........................
-7t"
..................
..................
. . .......... .
.
I
... . .. . ... . . . ...... . ..... ........
-
COMMENTS:
P:\Duke Energy Progress. 1 026\00 FIELD PAPERWORK128-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
141P
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] .[phone]fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 0
SAMPLE ID: SAMPLE DATE: 1-24-22
So _ SPI 4--2, SAMPLE TIME: / g, S
TEMPERATURE FF pH CONDUCTANCE DO ORP - TURBIDITY F
READING _ TIME ....... ._.......... ...... _... ... ..........T COLOR
€ (Whole # ° (X.XX su) ! (Whole # µStcm)l (X.)X mg/L) oYe p ], X.X NTU)
...... ... �,_...
3
...............,.,.,
NU
ER OF
CONTAINULS
-
_
NUMBER
P
-
OF
CONTAINERS . _.......
CONSTITUENTS SAMPLED
u
o f CONSTITUENTS SAMPLED
Oa
p
a
}�.....�
p
a
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K
�2
u u: U.
E.,
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1
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COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORM26-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT N0.
Duke - 59.50.06
LOCATION:
Asheville Airport
FIELD PERSONNEL:
RHJ/GSD
WEATHER:
❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#:
YSI
TURBITIDY METER TYPE/S#
HACH 2100 Q
SAMPLE ID:
SAMPLE DATE: 1-24-22
SAMPLE TIME: / 3 3 0
TEMPERATURE E pH
E CONDUCTANCE
DO
ORP
TURBIDITY
READING
TIME ;d ole # ° ..,....;_
( Cels€us (X.XX su)
)
---....
(Whole # µVcm)
.. ........................ ---..........
(X.XX mg/L)
.�..:..................
(Whole
COLOR
(X.X NTU)
1
133�
,3I
/00,3
N11MBER OF CONTAINERS NUMBER OF CONTAINERS
-.. ��. W
mi Lai. J" 0 W W W W
CONSTITUENTS SAMPLED o O o€ a: E: -- -- J O O a m
a J J �_ <i u; u a= CONSTITUENTS SAMPLED a J J u u u
E€ E: E€ E- EI E E E E E E
-1 o= oI E€ � o€ o:! a m o o E n o o a
N€ Ifl= O, O€ N; ut` O' N ill O O
— ............................... .........................:.i.i...i. " .. �-i � .. ... .i
-..-.........i.......... . - ... .. ............ ............. -f i-.i _ _. _ .........
.:.:. ... ..- (� ..r` ... ...
.....
COMMENTS:
P:IDuke Energy Progress. 1 026\00 FIELD PAPERWORKI213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�7
symTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT N0. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 0
SAMPLE ID: SAMPLE DATE: 1-24-22
S - 6AI # �2, SAMPLE TIME: 1345
TEMPERATURE
pH
E CONDUCTANCE
DO
ORP
TURBIDITY
READING " TIME
-
(Whole N ° _
-.,...,...,.
......
................
(Whole
COLOR
.....
Celsius) E
(X.XX su)
J/
(Whole µ5/cm)
..
(X.XX mg/L) . _
.. mV) .
(X.X NTU)
! _
NUMBER OF CONTAINERS NUMBER OF CONTAINERS
J0a 0aJ 0aJ O> am --1 a CONSTITUENTS SAMPLED OCONSTiTUENTSSAMPLED w
UF UU U U wmf
a
E E E E' • EI E- E_ -�€ E E E E E E J
u. u+ 0 o : o;. o€ m o o E
N In O 0-` N:'- in' O[ 0= N ut N
N IR eE -- N= u1_ _ N 0 0 V N= Ill
F
.i-.:............:i.......i.-.j ... ... - �. ........ ..
.................... .... ... ... - ... ... -_ - - .................
-.. ...,f I
....-.-.._..�
..............
- ................
i-H ............ I .......... i
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORKI213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
10
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-24-22
W _ QAI 41 SAMPLE TIME: I g
TEMPERATURE 1'
pH
CONDUCTANCE
DO
ORP
TURBIDITY
READING
TIME -- --
-----
-•-
—•—•-• COLOR
(Whole # µS/cm)
W
(X.XX mg/L)
(Whole #
(X.X NTU)
(Whole # ° X.XX su
- lsius ( )
_.,..................
33 =
,�fS
- 59
_
�....... ...
SIG
NUMBER OF. CONTAINERS NUMBER OF CONTAINERS
......,.. � ....i ......�..... ��•,-r-....��, : Tom........ ............... ........
;TJ
oJ oCONSTiTUENTSSAMPLED OCONSTITUENTS SAMPLED �
Q_ u11 U F a a a O u u u f
J: J >]
E 'E' 00- N N EII E 1E — E E E - J
in o o o E u+ o 0
O[ ' O N ut O �
.. .................... �...�._•--_.-.-� _-- .
..._ _ ...
�._._.._. j . . . ......... .. .. _i� ,�. .
P.....i _ .. _ ...
COMMENTS:
ROuke Energy PrDgress.1026100 FIELD PAPERWORKI213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�7
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone]. [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
SAMPLE DATE: 1-24-22
SAMPLE TIME: — ,+ a y
TEMPERATURE
pH
CONDUCTANCE
DO
ORP
TURBIDITY
READING TIME
( Mole IV
"' F
(Whole #
„W,.•••••••-••••••••••
COLOR
_........ ... ........ ���0
Celsius
(X.XX su)
(Whole # µS/cm)
(X.XX mg/L)
(X.X NTU)
-
.._.:.......,.
,
NUMBER OF CONTAINERS - NUMBER W CONTAINERS
CONSTITUENTS SAMPLED a_ as O' < u u f CONSTITUENTS SAMPLED 0- a'j—E
u
Ei E E`i E E EE EEoo
O
..............
......�...F{�.�.............................................-.....:....i..�.i:..........................Iw....................� .. .......
................... . .. . . . .. . .. ......
COMMENTS:
ROuke Energy Progress.1026100 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1
synTerra
146 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-24-22
SAMPLE TIME:
��
TEMPERATURE
PHCONDUCTANCE = DO
ORP
TURBIDITY
READING TIME 1-..........................................................
(Whole # °
WW
COLOR
(le #
Who
(X.XX su) (X.XX mg/L)
µCelsius) =
mV)
(X.X NTU)E
NUMBER
OF
CONTA
NUMBER
OF
CONTAINER'S
CONSTITUENTS SAMPLED A.
o
O
o[ a
m
CONSTITUENTS
a
a;
SAMPLED
0-
0.
Jl
J�
J
E
E
E
E
E
E
E
J
E;
E;:
E
E
E
E
J
u+
N
o
Ifl
N
o
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Y
N
o
Ill
N
o
1
O
0
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o!.
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o
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O
u+
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ul
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...... ..
.,
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':
....... ..
................ .-._.....
..
7
::
1
..-.. ..., -
.................. ....
.::
..
_
..................... .__.._._.._
............. .....,............
...........
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORKI213-21- Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
JW - yW 1 2�
SAMPLE DATE: 1-24-22
SAMPLE TIME: 1'O W
i '( TEMPERATURE
pH CONDUCTANCE DO ORP
TURBIDITY
READING ; TIME le o
(
1�_,.,:.......... _'...... ... _
.......
COLOR
(Whole #
Celsius
(X.XX su) (Whole # µS/cm) (X.XXsmg/L)
(X.X NTU)
NUMBER
_
..,.
OF CONTAINERS
f
NUMBER
,r�.,-.-,,....W-.
.
OF
CONTAINERS
CONSTITUENTS SAMPLED O€: 0=
a,
0=
a'
>
J
W
J
u
m
f. _
J
CONSTITUENTS SAMPLED O
a
Or
a-
O-
d= Os
U'
u
u
E
E' E
E"
E E
E
E
a
E
E
EI E
E
E
E
in o
o
in
o
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o
O
u+
N
o
N
o
Yet Y
u+
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o
N
o
�
t7
. ......... ....... �,_-
I
COMMENTS:
ROuke Energy Progress.1026100 FIELD PAPERWORM213-21- Surface water Sample Log.doo

Instrument Calibration Log
01 SynTerra Corporation
����� 148 River Street, Suite 220
Greenville, South Carolina 29601
NC Field Parameter Certification No. 5591
Instrument ID: YSI Professional Plus
Serial �: i Date:
Analyst: U1 Location: Sy
pH Initial Calibration (standard units)
Reference Method: SW846 9040C
Cal. Time Cal. Buffer Cal. Buffer Cal Buffer Check Buffer Measured
Value
U"? (101 4.0 17.0 10.0
V I buffer checks are to be within ± 0.1 pH units of the standards true value
4 Buffer Reference;, 6 10 Buffer Reference:--qL�--
7 Buffer Reference: Check Buffer Reference:
Mid -Day
End -of -Day � / 1500
Calibration Check standard units
Check Buffer True Value *Check Buffer Measured Value
7.0
7.0
Other
"pH buffer checks are to be within ± 0.1 pH units of the standards true value
Check Buffer Reference: Action Required:
Specific Conductance (umhos/cm)
R_ eference Method: SW846_ 9050A
Time I Calibration Standard True Value Verification standard Measured Value
Initial Cal 0 11,3 l 1409 1 �(C�
Mid -Day
End -of -Day ' 5 00 1
"Verification standard ± 110 percent of the standards true value
Calibration Standard Reference: �d-�
Action Required:
1409
1409
Verification Standard Reference: --
�7
Dissolved
Reference Method:
Oxygen (mg/L)
SM 4500
O G-2001
Time
Temp
BarometricT�tadi�nFa
ter
DO at
Theoretical
°C
Pressure (mm
Temperature
DO
H
m
/L
m /L
Initial* Q �
//m
YJ�
/_
r! I , `0
Mid -Day
End -of-
Da ��7 5
�Oj r
7QC%
%i
p
c
�r7U
q
C/o l
*Initial meter calibration
Pressure
Theoretical DO = DO from "Dissolved
Oxygen
Meter Calibration V--rifcation"
Table at ambient
temp X Correction
Factor at Barometric
Theoretical DO and Meter DO
reading within
+ 05 mg/I, if not tecalibrate
meter.
Action Required:
P:Ouke Energy Progress.1026100 FIELD PAPERWORnCalibration Forms NC Instrument Calibration Forth Rev? Prof Plus-doc

SURFACE WATER SAMPLING LOG
ti
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID: SAMPLE DATE
SAMPLE TIME
1-27-22
13`0
TEMPERATURE ' pH CONDUCTANCE DO ORP
TURBIDITY
READING
TIME
(Whole # ° (Whole#
COLOR
su) (Whole# µ5/cm) (X.XX mg/L)
Cli
(X.X NTU)(X.XX
_.. ...................
r0. i
...... ..
NUMBER
OF
CO
AINEAS
NUMBER
OF
CONTAINERS
rE
�
4
J"
CONSTITUENTS SAMPLED
o
o
a
J'. J
m
E'
CONSTITUENTS SAMPLED -: O' aaa
E_
E
E
E
E E
J
a
E E
I;
E
Ei
- N:
o€
Y1:
o
O
o
u+.t
N;
of o
111 o
U
ui� o o
N c O
o
in
N
o€ a
Ilf 1. O O
..._ ...........
,::
�..o-•,..��
....._
............. _" � J
........� ..
iT............. .....,..,........... C ...
- - _
.. ..
..
1
................._
COMMENTS: —
P:IDuke Energy Progress.1026100 FIELD PAPERWORQB-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT N0. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 210O G
SAMPLE ID: SAMPLE DATE: 1-27-22
5b') _ 5-A/ SAMPLE TIME: /I r.S
TEMPERATURE
pH
CONDUCTANCE
DO
ORP TURBIDITY
READING TIME
(Whole # °
Celsius)
........— ....
(X.XX su)
.......
(Whole # µS/cm)
(X.XX m L
�)
COLOR
( Whole #
(X.X NTU)
—...........:.......... ��........
/
my
--........ . _........
CONSTITUENTS SAMPLED
NanE
NUMB.
W
OO
E
IJoR
.ER OF.CONTAiHERS
..._.
Jo E>_a <_
E
z
u
o
u
_
o
O.
wa
CONSTITUENTS SAMPLED
li
1 Ja
E
NUMBER.
Oaa
E
O
E
o
OF CONTAINERS
1f
>ONJuil= YuaJl, m
E Ej aJuE -
of _
o; po V
. --.............. ,.............-.
N
Ill 7!� �
N
Ifl•
N
Ifl-
7� NI Vt
-T-H­_
4-4
77.
€ ��
...
I 1
77
Ir-
........,.
. -..�...........- ...............
t
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�10`
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] • [phone] fax
www.synTerracarp.com
CLIENT/PROJECT N0. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-27-22
Svc- qtS -Al SAMPLE TIME: 10-15
TEMPERATURE
pH
CONDUCTANCE
DO ORP
TURBIDITY
READING _ TIME .
(Whole # °
............ .... _ ......... i.....: Celsius
................---...._...........
... ._._.,.........-......`�
(X su
... .. XX )
.._...........�
(Whole - cm)
µ5/
_ .... ..-..
(Whole A
(X.XX m )
g/L
my
�..
X N
(X. TU)
COLOR
1 i o 5 /.
(a , 17 1
er6
...
3, 3�
J
HNUMBER
J[
OF
CONTAINERS
CONSTITUENTS SAMPLED
O;
r O- Oi a
E
a
u_
u
m' CONSTITUENTS SAMPLED O• a€
a' a- a Oi
J
u
J
u
J
u
f
E
€ N€
�-
E: E;
o!: o! E
ull O� O
N( IRj R
E
m
N
oI
in;
N=
o'
O€
if1
Qi
E; Ei E-
in; o o E
N= ut� G O
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E
a,
N
E
o
in
N
E
o
O
ul
J
j
i
................
. ............... . .
I
_
. ....... . .......
- I
COMMENTS:
ROuke Energy Progress.1026100 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
Op
symTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] • [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
SAMPLE DATE: 1-27-22
SAMPLE TIME: Ir,5
TEMPERATURE pH CONDUCTANCE € DO ORP TURBIDITY
READING TIME COLOR
.......- ---- . ....... .. ............ _
(Whole # ° ole #
(X.XX su) (Whole # µS/cm) ? (X.XX mg/L) (X.X NTU)
Celsius) mV)
................................................. — .. _
n........_—....I... .._.......�..._._.. ...
NUMBER OF CONTAINERS ! NUMBER OF CONTAINERS
JOaE JNOOae1 i a`€
�OJa 3OCONSTITUENTS SAMPLED a1 t € f ivawn :uuu
ia >E Ei EEEEJ EE Eaw awuE
J
oo;m o o! a Ei o oN 0=O NuO1n O-u:N i.N flOama
.............. ......... _. -
........ ............................... =
3
I
. .......................... +�_Y. . .
_____........... -- .............. _
4�11
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�7
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
f)li— S-Al
SAMPLE DATE: 1-27-22
SAMPLE TIME: /1 C 5
TEMPERATURE pH CONDUCTANCE DO ORP TURBIDITY
READING TIME — ...................... _ COLOR
(Whole # °
(%.XX su) . _ (Whole # µS/cm) (X.XX mg/L) (Whole # (X.X NTU)
........... .................Celsius) ....... ....... ,_, r. mV
— )
...........
��rs 3 �� 2 �,53 ; �fl,SLJ �( I:.2—
NUMKI10F
CONTAINERS
NUMBER
OF
CONTAINERS
,.....y
.....1. _.,
...........
SAMPLED
aOCONSTITUENTS
aJ
CONSTITUENTS SAMPLED j a
`0u
JIi
u; =
>_;
am
Ei
E
E E E
-g
E
E
E
J
..............
ui;
N;
-.
o!� o�
Y1;s
N
or
os NL o o
o-- It1 o
-- ............ ....... _
-....... .. -
E
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N
o
in
o
O
E
............... _,.
W��..r..:.....:�: ....._.........�
..
-•.....
-
........ . ..
.... -T
COMMENTS:
P:1Duke Energy Progress.1026100 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
141P
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
(8('4) 421-9999 • [phone] fax
www.synTerracorp.com
CLIENT/PROJECT No. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: ❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH 2100 Q
SAMPLE ID:
SAMPLE DATE: 1-27-22
SAMPLE TIME: /A3D
TEMPERATURE
pH
` CONDUCTANCE
DO
- ORP TURBIDITY
-
READING
TIME . ...................
• (Whole # ° =
..................... —
(X.XX su)
-
(Whole # µS/cm)
"j4�''
(X.XX mg/L
'i
(X.X NTU)
COLOR
..Celsius))
--.........,...........
..
.^,..,..� .::. .._..—�,r
L my�
'
i
5
Is7
��
o
'� 36
} �G�� �_
COMMENTS:
ROuke Energy PrDgress.1026100 FIELD PAPERWORKI2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�1
synTerm
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO. Duke - 59.50.06
LOCATION: Asheville Airport
FIELD PERSONNEL: RHJ/GSD
WEATHER: 0 SUNNY 0 OVERCAST 0 RAIN 0 COOL 0 WARM
MULTI METER TYPE/S#: YSI
TURBITIDY METER TYPE/S# HACH2100Q
SAMPLE ID: SAMPLE DATE: 1-27-22
— g--,V SAMPLE TIME: JA15
TEMPERATURE pH CONDUCTANCE 00 ORP TURBIDITY
... ............. READING TIME ....................... . . . COLOR
(Whole #
(Whole N
(X.XX su) (Whole # RS/cm) (X.XX mg/L) (X.X NTU)
Celsius) V L4 MV)
....... ............. .... ........ . .. .. ......... . . .... ........... .. ... .. . . .........
01 7 i.1
NUMBER OF CORTAINM
NUMBER OF CONTAINERS.
. . . ............ ........... .. ...
fW_
2
o� ce
-I T4e-
CONSTITUENTS SAMPLED0
0, Or a U CONSTITUENTS SA
u u u ul
E.T
3 -9 -9; E'
in -9 E E E E!
> E >
ce
kMPLED
o o
o o
o m ol of
o- o o . . .... . ....... . . . .............................. .. o
. . . ........................
....... . ...... . . ......... . . . ...... ....... — . . . . . . ........................ . . ............ .. . ........
. . ................ --- — — ------ ....... . ...
COMMENTS:
P:kDuke Energy Progress. 10200 FIELD PAPERWORKX2B-2L Surface water Sample Log.doc

SURFACE WATER SAMPLING LOG
1�7
synTerra
148 River Street, Suite 220
Greenville, South Carolina 29601
[phone] . [phone] fax
www.synTerracorp.com
CLIENT/PROJECT NO.
Duke - 59.50.06
LOCATION:
Asheville Airport
FIELD PERSONNEL:
RHJ/GSD
WEATHER:
❑ SUNNY ❑ OVERCAST ❑ RAIN ❑ COOL ❑ WARM
MULTI METER TYPE/S#:
YSI
TURBITIDY METER TYPE/S#
HACH 2100 Q
SAMPLE ID: SAMPLE DATE: 1-27-22
5 C� fj j SAMPLE TIME:
TEMPERATURE :I pH . i CONDUCTANCE DO ORP TURBIDITY
READING TIME W _._m ... ,. ... — ........................... COLOR
(Whole # " Whole #
(X.XX su) (Whole # µS/cm) s (X.XX mg/L) ( (X.X NTU)
Celsius) my1
NUMBER OF CONTAINERS
..... . . _rNJUUMBER
R OF C.OQNTAIQNEl: RS
..... —: ...... .... .................
daCONSTITUENTS SAMPLED Ji : OO ` a .. J<lUQ
Q...
Wm V Q
E E E— E E. E; J' E E E — E E= E J
E If1 O O E If1 O O N 0 O �"
N[ u1t O O N Ifli Oi O OF vt= O..0
N: 1e1:
-.t .i..... .... _ .... .. _.. ................ ._ ...
. ....................... _...... I-- _ ........
_..-..-.. ...... ......_ .
F.
COMMENTS:
P:IDuke Energy Progress.1026100 FIELD PAPERWORM B-2L Surface water Sample Log.doc

L�
synTerra
Instrument ID: YSI Professional Plus
Serial #:
Analyst:
Instrument Calibration Log
SynTerra Corporation
148 River Street, Suite 220
Greenville, South Carolina 29601
NC Field Parameter Certification No. 5591
Date: i- l-1'7'Z
Location: AilvAle
pH Initial Calibration (standard units)
Reference Method: SW846 9040C
Cal. Time
Cal. Buffer
Cal. Buffer
Cal Buffer
Check Buffer Measured
Value 1
4.0
7.0
10.0
%, Cr7_
*pH buffer checks are to be within ± 0.1 pH units of the standards true value
4 Buffer Reference: qo`_i
7 Buffer Reference: 1-7 7
10 Buffer Reference: q / +c
Check Buffer Reference:
off Calibration Check (standard unitsl
Time
Check Buffer True Value
*Check Buffer Measured Value
Mid -Day
7.0
End -of -Day
7.0
C,
Other
'pH butter checks are to be within ± 0.1 pH units of the standards true value
Check Buffer Reference: Action Required:
Specific Conductance (umhos/cm)
Time
Reference Method: SW846 9050A
Verification standard Measured Value
Calibration Standard True Value
Initial Cal
�1���;
1409
yo
Mid -Day
1409
End -of -Day
1409
3
'Verification standard ± 10 percent of the standards true value
Calibration Standard Reference: Z/ Z c Verification Standard Reference: q 2
Action Required:
Dissolved Oxygen (mg/L)
Reference Method: SM 4500 0 G-2001
Time
Temp
Barometric
Meter DO
Correction
DO at
Theoretical -
°C
Pressure (mm
Reading
Factor
Temperature
DO
H
m L
m /L
m /L
Initial*
z.r L
12, I t
ICI
4a
Mid -Day
-of-
5
-:7j
G, 9Z/
I //1
Dad
-mxlua meter cauoranon
Theoretical DO = DO from "Dissolved Oxygen Meter Calibration Verification" Table at ambient temp X Correction Factor at Barometric Pressure
Theoretical DO and Meter DO reading within + 0.5 mg/l, if not recalibrate meter
Action Required:
P:1Duke Energy Progress. 1 026\00 FIELD PAPERWORKICalibration FormslNC Instrument Calibration Form Rev7 Prof Plus.doc

Quarterly Water Quality Monitoring Report —January 2022 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX B
SURFACE WATER LABORATORY ANALYTICAL REPORTS
L7
synTerra
Science & Engineering Consultants

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J22010361
Project Name: ASHEVILLE AIRPORT - 2L-2B SURFACE WATER SAMPLING
Task Code: 21_213
Customer Name(s): John Toepfer,B Moeller,J Stowe, DOBrien,Synterra
Customer Address: Asheville Airport
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: pate: 2/15/2022
(Signature)
Pegg endall
Program Comments:
This is a revised report that supersedes the original. The PACE solids data was omitted from the report.
REVISION
Page 1 of 151
Note: The samples associated with PACE analyses were taken directly to the vendor laboratory after sample collection.
QC Note:
SW-8-Al (1250) and SW-6-Al (1345) NO3NO2 MS/MSD recoveries fell below the QC limits. The blank and LCS were within the
control limits. SW-8-Al sample result should be considered an estimate. SW-6-Al was non -detect.
Iron was detected in the filter blank at a concentration of 0.023 mg/L.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
REVISION
Page 2 of 151
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2022001821
Asheville Airport
24-Jan-22
2:35 PM
Richard Jacobs
ASA_SW-2-A1
2022001822
Asheville Airport
24-Jan-22
2:50 PM
Richard Jacobs
ASA_SW-2-A1
2022001823
Asheville Airport
24-Jan-22
11:35 AM
Richard Jacobs
ASA_SW-3-A1
2022001824
Asheville Airport
24-Jan-22
11:45 AM
Richard Jacobs
ASA_SW-3-A1
2022001825
Asheville Airport
24-Jan-22
10:15 AM
Richard Jacobs
ASA_SW-413-A1
2022001826
Asheville Airport
24-Jan-22
10:25 AM
Richard Jacobs
ASA_SW-413-A1
2022001827
Asheville Airport
24-Jan-22
10:45 AM
Richard Jacobs
ASA_SW-4C-A1
2022001828
Asheville Airport
24-Jan-22
10:55 AM
Richard Jacobs
ASA_SW-4C-A1
2022001829
Asheville Airport
24-Jan-22
12:15 PM
Richard Jacobs
ASA_SW-5-A1
2022001830
Asheville Airport
24-Jan-22
12:30 PM
Richard Jacobs
ASA_SW-5-A1
2022001831
Asheville Airport
24-Jan-22
1:30 PM
Richard Jacobs
ASA_SW-6-A1
2022001832
Asheville Airport
24-Jan-22
1:45 PM
Richard Jacobs
ASA_SW-6-A1
2022001833
Asheville Airport
24-Jan-22
12:50 PM
Richard Jacobs
ASA_SW-8-A1
2022001834
Asheville Airport
24-Jan-22
1:10 PM
Richard Jacobs
ASA_SW-8-A1
2022001835
Asheville Airport
24-Jan-22
2:05 PM
Richard Jacobs
ASA_FtB-20220124-1405
2022001836
Asheville Airport
24-Jan-22
9:45 AM
Richard Jacobs
ASA_SW-9-A1
2022001837
Asheville Airport
24-Jan-22
10:00 AM
Richard Jacobs
ASA_SW-9-A1
2022001983
Asheville Airport
24-Jan-22
2:05 PM
Richard Jacobs
ASA_FB-20220124-1405
18 Total Samples

REVISION
Page 3 of 151
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 2/15/2022

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-2-A1
Collection Date: 01/24/2022 02:35 PM Loc code: ASA SW-2-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 39.2 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 39.2 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
Sample #: 2022001821
Matrix: GW WW
REVISION
Page 4 of 151
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 19:37 EBATIAN
1 SM 2320E-2011 01/26/2022 19:37 EBATIAN
1 SM 2320B-2011 01/26/2022 19:37 EBATIAN
Chloride
16
mg/L
0.5
0.0154 5
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
1.2
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.012
mg/L
0.01
0.003
Barium (Ba)
0.049
mg/L
0.005
0.002
Boron (B)
< 0.05
mg/L
0.05
0.005
Iron (Fe)
0.804
mg/L
0.01
0.004
Manganese (Mn)
0.177
mg/L
0.005
0.001
Strontium (Sr)
0.051
mg/L
0.005
0.001
Zinc (Zn)
0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.072
mg/L
0.01
0.003
Barium (Ba)
0.053
mg/L
0.005
0.002
Boron (B)
0.006
mg/L
J 0.05
0.005
Calcium (Ca)
6.03
mg/L
0.05
0.012
Iron (Fe)
1.06
mg/L
0.01
0.004
Magnesium (Mg)
2.60
mg/L
0.02
0.008
Manganese (Mn)
0.179
mg/L
0.005
0.001
Potassium (K)
1.43
mg/L
0.1
0.031
Sodium (Na)
7.43
mg/L
0.05
0.017
Strontium (Sr)
0.055
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
25.8
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.009
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022 18:53
BGN9034
EPA
300.0
01/26/2022 18:53
BGN9034
EPA
300.0
01/26/2022 18:53
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/03/2022 15:56
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC
1 EPA 200.7
02/04/2022 13:22
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-2-A1
Collection Date: 01/24/2022 02:35 PM Loc code: ASA SW-2-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.217
ug/L
J
1
0.185
1
Cobalt (Co)
0.373
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.051
ug/L
J
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.344
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.07
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.147
ug/L
J
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
0.034
ug/L
J
0.1
0.032
1
Chromium (Cr)
0.366
ug/L
J
1
0.185
1
Cobalt (Co)
0.377
ug/L
J
1
0.077
1
Copper(Cu)
0.842
ug/L
J
2
0.787
1
Lead (Pb) Low Level
0.443
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
1.73
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.07
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.169
ug/L
J
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2022001821
Matrix: GW WW
REVISION
Page 5 of 151
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/02/2022 19:34
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
EPA 200.8
02/03/2022 13:24
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-2-A1
Collection Date: 01/24/2022 02:35 PM Loc code: ASA SW-2-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 6 of 151
Sample #: 2022001821
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.7 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202212:10 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-2-A1
Collection Date: 01/24/2022 02:50 PM Loc code: ASA SW-2-A1
Analyte Result Units Qualifiers RDL MDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22010397
Alkalinity, Bicarbonate 12.3 mg/L 5 1.7
Alkalinity, Carbonate < 5 mg/L 5 1.7
Total Alkalinity as CaCO3 12.3 mg/L 5 1.7
(CaCO3)
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC - Q22010358
Chloride
16
mg/L
0.5
0.0154
Fluoride
< 0.1
mg/L
0.1
0.0479
Sulfate
1.2
mg/L
0.1
0.0428
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
MERCURY 1631 - DISSOLVED
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22010407
Aluminum (AI)
0.012
mg/L
0.01
0.003
Barium (Ba)
0.048
mg/L
0.005
0.002
Boron (B)
< 0.05
mg/L
0.05
0.005
Iron (Fe)
0.764
mg/L
0.01
0.004
Manganese (Mn)
0.171
mg/L
0.005
0.001
Strontium (Sr)
0.050
mg/L
0.005
0.001
Zinc (Zn)
0.004
mg/L J
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.070
mg/L
0.01
0.003
Barium (Ba)
0.051
mg/L
0.005
0.002
Boron (B)
< 0.05
mg/L
0.05
0.005
Calcium (Ca)
5.80
mg/L
0.05
0.012
Iron (Fe)
0.998
mg/L
0.01
0.004
Magnesium (Mg)
2.50
mg/L
0.02
0.008
Manganese (Mn)
0.173
mg/L
0.005
0.001
Potassium (K)
1.39
mg/L
0.1
0.031
Sodium (Na)
7.21
mg/L
0.05
0.017
Strontium (Sr)
0.053
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
24.8
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Sample #: 2022001822
Matrix: GW WW
REVISION
Page 7 of 151
DF
Method
Analysis Date/Time
Analyst
1
SM 2320B4d
01/27/2022 14:17
EBATIAN
1
SM 2320B4d
01/27/2022 14:17
EBATIAN
1
SM 2320B4d
01/27/2022 14:17
EBATIAN
Vendor Method V_PACE
5 EPA 300.0
01/26/2022 19:13
BGN9034
1 EPA 300.0
01/26/2022 19:13
BGN9034
1 EPA 300.0
01/26/2022 19:13
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/03/2022 16:00
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC
1 EPA 200.7
02/04/2022 14:18
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-2-A1
Collection Date: 01/24/2022 02:50 PM Loc code: ASA SW-2-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.196
ug/L
J
1
0.185
1
Cobalt (Co)
0.365
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.325
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.064
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.132
ug/L
J
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.375
ug/L
J
1
0.185
1
Cobalt (Co)
0.371
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.416
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.725
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.041
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.131
ug/L
J
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2022001822
Matrix: GW WW
REVISION
Page 8 of 151
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/02/2022 21:36
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
EPA 200.8
02/03/2022 13:33
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-2-A1
Collection Date: 01/24/2022 02:50 PM Loc code: ASA SW-2-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 9 of 151
Sample #: 2022001822
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.9 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202212:48 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-3-A1
Collection Date: 01/24/2022 11:35 AM Loc code: ASA SW-3-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 27.3 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 27.3 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 10 of 151
Sample #: 2022001823
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 19:43 EBATIAN
1 SM 2320E-2011 01/26/2022 19:43 EBATIAN
1 SM 2320B-2011 01/26/2022 19:43 EBATIAN
Chloride
15
mg/L
0.5
0.0154 5
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
4.0
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
0.039
mg/L
0.005
0.002
Boron (B)
0.044
mg/L
J 0.05
0.005
Iron (Fe)
0.141
mg/L
0.01
0.004
Manganese (Mn)
0.258
mg/L
0.005
0.001
Strontium (Sr)
0.089
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.138
mg/L
0.01
0.003
Barium (Ba)
0.043
mg/L
0.005
0.002
Boron (B)
0.048
mg/L
J 0.05
0.005
Calcium (Ca)
9.06
mg/L
0.05
0.012
Iron (Fe)
0.686
mg/L
0.01
0.004
Magnesium (Mg)
3.59
mg/L
0.02
0.008
Manganese (Mn)
0.278
mg/L
0.005
0.001
Potassium (K)
1.60
mg/L
0.1
0.031
Sodium (Na)
6.69
mg/L
0.05
0.017
Strontium (Sr)
0.095
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
37.4
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.006
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022 19:34
BGN9034
EPA
300.0
01/26/2022 19:34
BGN9034
EPA
300.0
01/26/2022 19:34
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/03/2022 15:47
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC
1 EPA 200.7
02/04/2022 13:35
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-3-A1
Collection Date: 01/24/2022 11:35 AM Loc code: ASA SW-3-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
0.649
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.375
ug/L
J
1
0.256
1
Selenium (Se)
0.435
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.167
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.362
ug/L
J
1
0.185
1
Cobalt (Co)
0.736
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.330
ug/L
0.2
0.037
1
Molybdenum (Mo)
0.183
ug/L
J
1
0.18
1
Nickel (Ni)
0.426
ug/L
J
1
0.256
1
Selenium (Se)
0.465
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.045
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.192
ug/L
J
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 11 of 151
Sample #: 2022001823
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/02/2022 20:02
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
EPA 200.8
02/03/2022 12:46
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-3-A1
Collection Date: 01/24/2022 11:35 AM Loc code: ASA SW-3-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 12 of 151
Sample #: 2022001823
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.8 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202213:06 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-3-A1
Collection Date: 01/24/2022 11:45 AM Loc code: ASA SW-3-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 27.2 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 27.2 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 13 of 151
Sample #: 2022001824
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 19:47 EBATIAN
1 SM 2320E-2011 01/26/2022 19:47 EBATIAN
1 SM 2320B-2011 01/26/2022 19:47 EBATIAN
Chloride
15
mg/L
0.5
0.0154 5
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
4.0
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
0.040
mg/L
0.005
0.002
Boron (B)
0.042
mg/L
J 0.05
0.005
Iron (Fe)
0.149
mg/L
0.01
0.004
Manganese (Mn)
0.258
mg/L
0.005
0.001
Strontium (Sr)
0.089
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.031
mg/L
0.01
0.003
Barium (Ba)
0.043
mg/L
0.005
0.002
Boron (B)
0.047
mg/L
J 0.05
0.005
Calcium (Ca)
9.22
mg/L
0.05
0.012
Iron (Fe)
0.273
mg/L
0.01
0.004
Magnesium (Mg)
3.62
mg/L
0.02
0.008
Manganese (Mn)
0.267
mg/L
0.005
0.001
Potassium (K)
1.60
mg/L
0.1
0.031
Sodium (Na)
6.84
mg/L
0.05
0.017
Strontium (Sr)
0.097
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
38.0
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.004
mg/L
1 0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022 19:55
BGN9034
EPA
300.0
01/26/2022 19:55
BGN9034
EPA
300.0
01/26/2022 19:55
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/08/2022 11:18
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC
1 EPA 200.7
02/04/2022 13:39
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-3-A1
Collection Date: 01/24/2022 11:45 AM Loc code: ASA SW-3-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
0.414
ug/L
J
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
0.668
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.376
ug/L
J
1
0.256
1
Selenium (Se)
0.482
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.106
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.261
ug/L
J
1
0.185
1
Cobalt (Co)
0.666
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.189
ug/L
J
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.38
ug/L
J
1
0.256
1
Selenium (Se)
0.421
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.087
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 14 of 151
Sample #: 2022001824
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/02/2022 20:11
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
EPA 200.8
02/03/2022 15:17
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-3-A1
Collection Date: 01/24/2022 11:45 AM Loc code: ASA SW-3-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 15 of 151
Sample #: 2022001824
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 2.0 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202213:24 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4B-A1
Collection Date: 01/24/2022 10:15 AM Loc code: ASA SW-4B-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 27.0 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 27.0 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 16 of 151
Sample #: 2022001825
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 19:50 EBATIAN
1 SM 2320E-2011 01/26/2022 19:50 EBATIAN
1 SM 2320B-2011 01/26/2022 19:50 EBATIAN
Chloride
3.0
mg/L
0.1
0.0154 1
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
10
mg/L
0.5
0.0428 5
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
0.022
mg/L
0.005
0.002
Boron (B)
0.121
mg/L
0.05
0.005
Iron (Fe)
0.394
mg/L
0.01
0.004
Manganese (Mn)
0.197
mg/L
0.005
0.001
Strontium (Sr)
0.058
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.118
mg/L
0.01
0.003
Barium (Ba)
0.024
mg/L
0.005
0.002
Boron (B)
0.129
mg/L
0.05
0.005
Calcium (Ca)
7.43
mg/L
0.05
0.012
Iron (Fe)
0.943
mg/L
0.01
0.004
Magnesium (Mg)
3.77
mg/L
0.02
0.008
Manganese (Mn)
0.217
mg/L
0.005
0.001
Potassium (K)
1.19
mg/L
0.1
0.031
Sodium (Na)
2.71
mg/L
0.05
0.017
Strontium (Sr)
0.064
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
34.1
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Vendor Method V_PACE
EPA 300.0
01/26/2022 20:16
BGN9034
EPA 300.0
01/26/2022 20:16
BGN9034
EPA 300.0
01/26/2022 20:16
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/03/2022 16:05
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC
1 EPA 200.7
02/04/2022 13:44
DMFRANC

REVISION
Certificate of Laboratory Analysis Page 17 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4B-A1
Sample #: 2022001825
Collection Date: 01/24/2022
10:15 AM
Loc code: ASA SW-4B-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Cobalt (Co)
0.57
ug/L J
1
0.077
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Selenium (Se)
2.15
ug/L
1
0.193
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Thallium (TI) Low Level
0.073
ug/L J
0.2
0.041
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/02/2022 20:21
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Chromium (Cr)
0.237
ug/L J
1
0.185
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Cobalt (Co)
0.655
ug/L J
1
0.077
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Lead (Pb) Low Level
0.184
ug/L J
0.2
0.037
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Selenium (Se)
2.28
ug/L
1
0.193
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/03/2022 13:43
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4B-A1
Collection Date: 01/24/2022 10:15 AM Loc code: ASA SW-4B-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 18 of 151
Sample #: 2022001825
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.8 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202213:42 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4B-A1
Collection Date: 01/24/2022 10:25 AM Loc code: ASA SW-4B-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 27.0 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 27.0 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 19 of 151
Sample #: 2022001826
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 19:53 EBATIAN
1 SM 2320E-2011 01/26/2022 19:53 EBATIAN
1 SM 2320B-2011 01/26/2022 19:53 EBATIAN
Chloride
3.0
mg/L
0.1
0.0154 1
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
10
mg/L
0.5
0.0428 5
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
0.022
mg/L
0.005
0.002
Boron (B)
0.122
mg/L
0.05
0.005
Iron (Fe)
0.396
mg/L
0.01
0.004
Manganese (Mn)
0.196
mg/L
0.005
0.001
Strontium (Sr)
0.059
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.162
mg/L
0.01
0.003
Barium (Ba)
0.024
mg/L
0.005
0.002
Boron (B)
0.129
mg/L
0.05
0.005
Calcium (Ca)
7.42
mg/L
0.05
0.012
Iron (Fe)
0.618
mg/L
0.01
0.004
Magnesium (Mg)
3.76
mg/L
0.02
0.008
Manganese (Mn)
0.203
mg/L
0.005
0.001
Potassium (K)
1.18
mg/L
0.1
0.031
Sodium (Na)
2.70
mg/L
0.05
0.017
Strontium (Sr)
0.063
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
34.0
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022 20:36
BGN9034
EPA
300.0
01/26/2022 20:36
BGN9034
EPA
300.0
01/26/2022 20:36
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/03/2022 16:09
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC
1 EPA 200.7
02/04/2022 13:48
DMFRANC

REVISION
Certificate of Laboratory Analysis Page 20 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4B-A1
Sample #: 2022001826
Collection Date: 01/24/2022
10:25 AM
Loc code: ASA SW-4B-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Cobalt (Co)
0.568
ug/L J
1
0.077
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Selenium (Se)
2.18
ug/L
1
0.193
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Thallium (TI) Low Level
0.058
ug/L J
0.2
0.041
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/02/2022 20:30
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Chromium (Cr)
0.266
ug/L J
1
0.185
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Cobalt (Co)
0.594
ug/L J
1
0.077
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Lead (Pb) Low Level
0.197
ug/L J
0.2
0.037
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Selenium (Se)
2.23
ug/L
1
0.193
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Vanadium (V) Low Level
0.126
ug/L J
0.3
0.114
1
EPA 200.8
02/03/2022 13:52
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4B-A1
Collection Date: 01/24/2022 10:25 AM Loc code: ASA SW-4B-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 21 of 151
Sample #: 2022001826
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 2.0 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202214:01 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4C-A1
Collection Date: 01/24/2022 10:45 AM Loc code: ASA SW-4C-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 22.5 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 22.5 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 22 of 151
Sample #: 2022001827
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 19:57 EBATIAN
1 SM 2320E-2011 01/26/2022 19:57 EBATIAN
1 SM 2320B-2011 01/26/2022 19:57 EBATIAN
Chloride
2.3
mg/L
0.1
0.0154 1
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
7.6
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.003
mg/L
J 0.01
0.003
Barium (Ba)
0.022
mg/L
0.005
0.002
Boron (B)
0.098
mg/L
0.05
0.005
Iron (Fe)
0.186
mg/L
0.01
0.004
Manganese (Mn)
0.257
mg/L
0.005
0.001
Strontium (Sr)
0.048
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.198
mg/L
0.01
0.003
Barium (Ba)
0.025
mg/L
0.005
0.002
Boron (B)
0.105
mg/L
0.05
0.005
Calcium (Ca)
5.84
mg/L
0.05
0.012
Iron (Fe)
1.08
mg/L
0.01
0.004
Magnesium (Mg)
3.22
mg/L
0.02
0.008
Manganese (Mn)
0.286
mg/L
0.005
0.001
Potassium (K)
1.10
mg/L
0.1
0.031
Sodium (Na)
2.45
mg/L
0.05
0.017
Strontium (Sr)
0.053
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
27.9
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.004
mg/L
1 0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022 14:26
BGN9034
EPA
300.0
01/26/2022 14:26
BGN9034
EPA
300.0
01/26/2022 14:26
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/08/2022 11:17
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC
1 EPA 200.7
02/04/2022 13:52
DMFRANC

REVISION
Certificate of Laboratory Analysis Page 23 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4C-A1
Sample #: 2022001827
Collection Date: 01/24/2022
10:45 AM
Loc code: ASA SW-4C-A1
Matrix: GW WW
Analyte
Result
Units
Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Chromium (Cr)
0.2
ug/L
J
1
0.185
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Cobalt (Co)
0.698
ug/L
J
1
0.077
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Nickel (Ni)
0.301
ug/L
J
1
0.256
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Selenium (Se)
3.37
ug/L
1
0.193
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Thallium (TI) Low Level
0.043
ug/L
J
0.2
0.041
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/02/2022 20:40
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Chromium (Cr)
0.37
ug/L
J
1
0.185
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Cobalt (Co)
0.879
ug/L
J
1
0.077
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Lead (Pb) Low Level
0.251
ug/L
0.2
0.037
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Nickel (Ni)
0.317
ug/L
J
1
0.256
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Selenium (Se)
3.22
ug/L
1
0.193
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Vanadium (V) Low Level
0.195
ug/L
J
0.3
0.114
1
EPA 200.8
02/03/2022 14:01
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4C-A1
Collection Date: 01/24/2022 10:45 AM Loc code: ASA SW-4C-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 24 of 151
Sample #: 2022001827
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.9 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202214:19 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4C-A1
Collection Date: 01/24/2022 10:55 AM Loc code: ASA SW-4C-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 22.8 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 22.8 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 25 of 151
Sample #: 2022001828
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 20:00 EBATIAN
1 SM 2320E-2011 01/26/2022 20:00 EBATIAN
1 SM 2320B-2011 01/26/2022 20:00 EBATIAN
Chloride
2.4
mg/L
0.1
0.0154 1
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
7.8
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.005
mg/L
J 0.01
0.003
Barium (Ba)
0.022
mg/L
0.005
0.002
Boron (B)
0.099
mg/L
0.05
0.005
Iron (Fe)
0.185
mg/L
0.01
0.004
Manganese (Mn)
0.256
mg/L
0.005
0.001
Strontium (Sr)
0.049
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.066
mg/L
0.01
0.003
Barium (Ba)
0.025
mg/L
0.005
0.002
Boron (B)
0.107
mg/L
0.05
0.005
Calcium (Ca)
6.00
mg/L
0.05
0.012
Iron (Fe)
0.473
mg/L
0.01
0.004
Magnesium (Mg)
3.28
mg/L
0.02
0.008
Manganese (Mn)
0.273
mg/L
0.005
0.001
Potassium (K)
1.08
mg/L
0.1
0.031
Sodium (Na)
2.49
mg/L
0.05
0.017
Strontium (Sr)
0.054
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
28.5
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022 18:32
BGN9034
EPA
300.0
01/26/2022 18:32
BGN9034
EPA
300.0
01/26/2022 18:32
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/03/2022 16:18
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC
1 EPA 200.7
02/04/2022 13:57
DMFRANC

REVISION
Certificate of Laboratory Analysis Page 26 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4C-A1
Sample #: 2022001828
Collection Date: 01/24/2022
10:55 AM
Loc code: ASA SW-4C-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Cobalt (Co)
0.643
ug/L J
1
0.077
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Nickel (Ni)
0.272
ug/L J
1
0.256
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Selenium (Se)
3.22
ug/L
1
0.193
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Thallium (TI) Low Level
0.043
ug/L J
0.2
0.041
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/02/2022 20:49
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Chromium (Cr)
0.274
ug/L J
1
0.185
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Cobalt (Co)
0.712
ug/L J
1
0.077
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Lead (Pb) Low Level
0.173
ug/L J
0.2
0.037
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Nickel (Ni)
0.272
ug/L J
1
0.256
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Selenium (Se)
3.16
ug/L
1
0.193
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/03/2022 14:11
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-4C-A1
Collection Date: 01/24/2022 10:55 AM Loc code: ASA SW-4C-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 27 of 151
Sample #: 2022001828
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.9 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202214:37 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-5-A1
Collection Date: 01/24/2022 12:15 PM Loc code: ASA SW-5-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 73.3 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 73.3 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 28 of 151
Sample #: 2022001829
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 20:03 EBATIAN
1 SM 2320E-2011 01/26/2022 20:03 EBATIAN
1 SM 2320B-2011 01/26/2022 20:03 EBATIAN
Chloride
18
mg/L
0.5
0.0154 5
Fluoride
0.08
mg/L
J 0.1
0.0479 1
Sulfate
6.3
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.014
mg/L
0.01
0.003
Barium (Ba)
0.080
mg/L
0.005
0.002
Boron (B)
0.136
mg/L
0.05
0.005
Iron (Fe)
11.8
mg/L
0.01
0.004
Manganese (Mn)
2.45
mg/L
0.005
0.001
Strontium (Sr)
0.333
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.095
mg/L
0.01
0.003
Barium (Ba)
0.096
mg/L
0.005
0.002
Boron (B)
0.147
mg/L
0.05
0.005
Calcium (Ca)
23.6
mg/L
0.05
0.012
Iron (Fe)
17.8
mg/L
0.01
0.004
Magnesium (Mg)
6.11
mg/L
0.02
0.008
Manganese (Mn)
2.67
mg/L
0.005
0.001
Potassium (K)
2.37
mg/L
0.1
0.031
Sodium (Na)
5.98
mg/L
0.05
0.017
Strontium (Sr)
0.376
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
84.0
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.006
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/26/2022
20:57
BGN9034
EPA
300.0
01/26/2022
20:57
BGN9034
EPA
300.0
01/26/2022
20:57
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/03/2022 16:35
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC
1 EPA 200.7
02/04/2022 14:01
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-5-A1
Collection Date: 01/24/2022 12:15 PM Loc code: ASA SW-5-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.461
ug/L J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
3.73
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
1.92
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.923
ug/L J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
3.68
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.173
ug/L J
0.2
0.037
1
Molybdenum (Mo)
2.41
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 29 of 151
Sample #: 2022001829
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/02/2022 20:58
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
EPA 200.8
02/03/2022 14:20
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-5-A1
Collection Date: 01/24/2022 12:15 PM Loc code: ASA SW-5-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 30 of 151
Sample #: 2022001829
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.6 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202214:55 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-5-A1
Collection Date: 01/24/2022 12:30 PM Loc code: ASA SW-5-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 73.1 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 73.1 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 31 of 151
Sample #: 2022001830
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 20:07 EBATIAN
1 SM 2320E-2011 01/26/2022 20:07 EBATIAN
1 SM 2320B-2011 01/26/2022 20:07 EBATIAN
Chloride
18
mg/L
0.5
0.0154 5
Fluoride
0.08
mg/L
J 0.1
0.0479 1
Sulfate
6.3
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.014
mg/L
0.01
0.003
Barium (Ba)
0.080
mg/L
0.005
0.002
Boron (B)
0.137
mg/L
0.05
0.005
Iron (Fe)
11.7
mg/L
0.01
0.004
Manganese (Mn)
2.44
mg/L
0.005
0.001
Strontium (Sr)
0.330
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.053
mg/L
0.01
0.003
Barium (Ba)
0.090
mg/L
0.005
0.002
Boron (B)
0.146
mg/L
0.05
0.005
Calcium (Ca)
22.8
mg/L
0.05
0.012
Iron (Fe)
15.0
mg/L
0.01
0.004
Magnesium (Mg)
5.90
mg/L
0.02
0.008
Manganese (Mn)
2.54
mg/L
0.005
0.001
Potassium (K)
2.28
mg/L
0.1
0.031
Sodium (Na)
5.76
mg/L
0.05
0.017
Strontium (Sr)
0.362
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
81.1
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.007
mg/L
0.005
0.004
Vendor Method V_PACE
EPA 300.0
01/26/2022 21:18
BGN9034
EPA 300.0
01/26/2022 21:18
BGN9034
EPA 300.0
01/26/2022 21:18
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/03/2022 16:48
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC
1 EPA 200.7
02/04/2022 14:31
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-5-A1
Collection Date: 01/24/2022 12:30 PM Loc code: ASA SW-5-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.483
ug/L J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
3.67
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
1.88
ug/L
1
0.18
1
Nickel (Ni)
1.39
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.704
ug/L J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.193
ug/L J
1
0.185
1
Cobalt (Co)
3.58
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.2
ug/L J
0.2
0.037
1
Molybdenum (Mo)
2.10
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 32 of 151
Sample #: 2022001830
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 11:41
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
EPA 200.8
02/03/2022 14:29
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-5-A1
Collection Date: 01/24/2022 12:30 PM Loc code: ASA SW-5-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 33 of 151
Sample #: 2022001830
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.2 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202215:14 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-6-A1
Collection Date: 01/24/2022 01:30 PM Loc code: ASA SW-6-A1
Analyte Result Units Qualifiers RDL MDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22010397
Alkalinity, Bicarbonate 15.4 mg/L 5 1.7
Alkalinity, Carbonate < 5 mg/L 5 1.7
Total Alkalinity as CaCO3 15.4 mg/L 5 1.7
(CaCO3)
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC - Q22010358
Chloride
9.2
mg/L
0.5
0.0154
Fluoride
< 0.1
mg/L
0.1
0.0479
Sulfate
3.5
mg/L
0.1
0.0428
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
MERCURY 1631 - DISSOLVED
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22010407
Aluminum (AI)
0.006
mg/L J
0.01
0.003
Barium (Ba)
0.019
mg/L
0.005
0.002
Boron (B)
0.011
mg/L J
0.05
0.005
Iron (Fe)
3.47
mg/L
0.01
0.004
Manganese (Mn)
0.501
mg/L
0.005
0.001
Strontium (Sr)
0.028
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.294
mg/L
0.01
0.003
Barium (Ba)
0.023
mg/L
0.005
0.002
Boron (B)
0.014
mg/L J
0.05
0.005
Calcium (Ca)
4.91
mg/L
0.05
0.012
Iron (Fe)
8.38
mg/L
0.01
0.004
Magnesium (Mg)
2.33
mg/L
0.02
0.008
Manganese (Mn)
0.528
mg/L
0.005
0.001
Potassium (K)
1.95
mg/L
0.1
0.031
Sodium (Na)
3.01
mg/L
0.05
0.017
Strontium (Sr)
0.031
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
21.9
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
REVISION
Page 34 of 151
Sample #: 2022001831
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
SM 2320B4d
01/27/2022 14:41
EBATIAN
1
SM 2320B4d
01/27/2022 14:41
EBATIAN
1
SM 2320B4d
01/27/2022 14:41
EBATIAN
Vendor Method V_PACE
5 EPA 300.0
01/26/2022 22:39
BGN9034
1 EPA 300.0
01/26/2022 22:39
BGN9034
1 EPA 300.0
01/26/2022 22:39
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/03/2022 16:52
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC
1 EPA 200.7
02/04/2022 14:35
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-6-A1
Collection Date: 01/24/2022 01:30 PM Loc code: ASA SW-6-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.212
ug/L
J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
2.45
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.117
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.498
ug/L
J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.317
ug/L
J
1
0.185
1
Cobalt (Co)
2.47
ug/L
1
0.077
1
Copper (Cu)
0.805
ug/L
J
2
0.787
1
Lead (Pb) Low Level
0.290
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.402
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.087
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.319
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 35 of 151
Sample #: 2022001831
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/02/2022 22:14
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
EPA 200.8
02/03/2022 15:54
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-6-A1
Collection Date: 01/24/2022 01:30 PM Loc code: ASA SW-6-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 36 of 151
Sample #: 2022001831
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.5 mg/L 1 0.055 10 SM5310C/EPA9060A 01/28/2022 22:50 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-6-A1
Collection Date: 01/24/2022 01:45 PM Loc code: ASA SW-6-A1
Analyte Result Units Qualifiers RDL MDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22010397
Alkalinity, Bicarbonate 16.3 mg/L 5 1.7
Alkalinity, Carbonate < 5 mg/L 5 1.7
Total Alkalinity as CaCO3 16.3 mg/L 5 1.7
(CaCO3)
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC - Q22010358
Chloride
9.2
mg/L
0.5
0.0154
Fluoride
< 0.1
mg/L
0.1
0.0479
Sulfate
3.5
mg/L
0.1
0.0428
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
MERCURY 1631 - DISSOLVED
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22010407
Aluminum (AI)
0.006
mg/L J
0.01
0.003
Barium (Ba)
0.019
mg/L
0.005
0.002
Boron (B)
0.01
mg/L J
0.05
0.005
Iron (Fe)
3.72
mg/L
0.01
0.004
Manganese (Mn)
0.491
mg/L
0.005
0.001
Strontium (Sr)
0.026
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.097
mg/L
0.01
0.003
Barium (Ba)
0.021
mg/L
0.005
0.002
Boron (B)
0.013
mg/L J
0.05
0.005
Calcium (Ca)
4.73
mg/L
0.05
0.012
Iron (Fe)
5.90
mg/L
0.01
0.004
Magnesium (Mg)
2.24
mg/L
0.02
0.008
Manganese (Mn)
0.512
mg/L
0.005
0.001
Potassium (K)
1.93
mg/L
0.1
0.031
Sodium (Na)
2.94
mg/L
0.05
0.017
Strontium (Sr)
0.029
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
21.0
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
REVISION
Page 37 of 151
Sample #: 2022001832
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
SM 2320B4d
01/27/2022 14:48
EBATIAN
1
SM 2320B4d
01/27/2022 14:48
EBATIAN
1
SM 2320B4d
01/27/2022 14:48
EBATIAN
Vendor Method V_PACE
5 EPA 300.0
01/27/2022 01:23
BGN9034
1 EPA 300.0
01/27/2022 01:23
BGN9034
1 EPA 300.0
01/27/2022 01:23
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/03/2022 16:56
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC
1 EPA 200.7
02/04/2022 14:40
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-6-A1
Collection Date: 01/24/2022 01:45 PM Loc code: ASA SW-6-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.223
ug/L
J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
2.37
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.287
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.083
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
0.352
ug/L
J
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.222
ug/L
J
1
0.185
1
Cobalt (Co)
2.30
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.197
ug/L
J
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.268
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.042
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
0.124
ug/L
J
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 38 of 151
Sample #: 2022001832
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/02/2022 22:23
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
EPA 200.8
02/03/2022 16:04
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-6-A1
Collection Date: 01/24/2022 01:45 PM Loc code: ASA SW-6-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 39 of 151
Sample #: 2022001832
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.6 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202216:48 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-8-A1
Collection Date: 01/24/2022 12:50 PM Loc code: ASA SW-8-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
REVISION
Page 40 of 151
Sample #: 2022001833
Matrix: GW WW
Method Analysis Date/Time Analyst
Total Alkalinity as CaCO3
440
mg/L
5
1.7
1
SM 2320B-2011
01/26/2022 20:22
EBATIAN
(CaCO3)
Alkalinity, Carbonate
< 5
mg/L
5
1.7
1
SM 2320B-2011
01/26/2022 20:22
EBATIAN
Alkalinity, Bicarbonate
440
mg/L
5
1.7
1
SM 2320B-2011
01/26/2022 20:22
EBATIAN
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22010358
Chloride
3.6
mg/L
0.5
0.0154
5
EPA 300.0
01/27/2022 01:44
BGN9034
Fluoride
0.60
mg/L
0.1
0.0479
1
EPA 300.0
01/27/2022 01:44
BGN9034
Sulfate
21
mg/L
0.5
0.0428
5
EPA 300.0
01/27/2022 01:44
BGN9034
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
MERCURY 1631 - DISSOLVED - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.020
mg/L
0.01
0.003
1
EPA 200.7
02/03/2022 17:01
DMFRANC
Barium (Ba)
0.233
mg/L
0.005
0.002
1
EPA 200.7
02/03/2022 17:01
DMFRANC
Boron (B)
0.928
mg/L
0.05
0.005
1
EPA 200.7
02/03/2022 17:01
DMFRANC
Iron (Fe)
16.5
mg/L
0.01
0.004
1
EPA 200.7
02/03/2022 17:01
DMFRANC
Manganese (Mn)
4.86
mg/L
0.005
0.001
1
EPA 200.7
02/03/2022 17:01
DMFRANC
Strontium (Sr)
2.19
mg/L
0.005
0.001
1
EPA 200.7
02/03/2022 17:01
DMFRANC
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
1
EPA 200.7
02/03/2022 17:01
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.465
mg/L
0.01
0.003
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Barium (Ba)
0.304
mg/L
0.005
0.002
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Boron (B)
0.990
mg/L
0.05
0.005
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Calcium (Ca)
136
mg/L
1
0.012
20
EPA 200.7
02/04/2022 14:44
DMFRANC
Iron (Fe)
29.9
mg/L
0.01
0.004
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Magnesium (Mg)
25.3
mg/L
0.02
0.008
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Manganese (Mn)
5.10
mg/L
0.005
0.001
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Potassium (K)
4.41
mg/L
0.1
0.031
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Sodium (Na)
6.18
mg/L
0.05
0.017
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Strontium (Sr)
2.38
mg/L
0.005
0.001
1
EPA 200.7
02/04/2022 14:44
DMFRANC
Total Hardness (Ca and Mg)
445
mg/L
0.066
1
EPA 200.7
02/04/2022 14:44
DMFRANC
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
1
EPA 200.7
02/04/2022 14:44
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-8-A1
Collection Date: 01/24/2022 12:50 PM Loc code: ASA SW-8-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
292
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
7.33
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
60.3
ug/L
1
0.18
1
Nickel (Ni)
0.263
ug/L J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.056
ug/L J
0.2
0.041
1
Vanadium (V) Low Level
0.17
ug/L J
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
607
ug/L
20
0.111
20
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.273
ug/L J
1
0.185
1
Cobalt (Co)
7.18
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.318
ug/L
0.2
0.037
1
Molybdenum (Mo)
57.9
ug/L
1
0.18
1
Nickel (Ni)
0.431
ug/L J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.705
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 41 of 151
Sample #: 2022001833
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/02/2022 22:32
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
EPA 200.8
02/07/2022 11:50
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-8-A1
Collection Date: 01/24/2022 12:50 PM Loc code: ASA SW-8-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 42 of 151
Sample #: 2022001833
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.7 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202217:06 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-8-A1
Collection Date: 01/24/2022 01:10 PM Loc code: ASA SW-8-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
REVISION
Page 43 of 151
Sample #: 2022001834
Matrix: GW WW
Method Analysis Date/Time Analyst
Total Alkalinity as CaCO3
439
mg/L
5
1.7
1
SM 2320B-2011
01/26/2022 20:27
EBATIAN
(CaCO3)
Alkalinity, Carbonate
< 5
mg/L
5
1.7
1
SM 2320B-2011
01/26/2022 20:27
EBATIAN
Alkalinity, Bicarbonate
439
mg/L
5
1.7
1
SM 2320B-2011
01/26/2022 20:27
EBATIAN
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22010358
Chloride
3.6
mg/L
0.5
0.0154
5
EPA 300.0
01/27/2022 02:05
BGN9034
Fluoride
0.65
mg/L
0.1
0.0479
1
EPA 300.0
01/27/2022 02:05
BGN9034
Sulfate
21
mg/L
0.5
0.0428
5
EPA 300.0
01/27/2022 02:05
BGN9034
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
MERCURY 1631 - DISSOLVED - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.019
mg/L
0.01
0.003
1
EPA 200.7
02/03/2022 17:05
DMFRANC
Barium (Ba)
0.237
mg/L
0.005
0.002
1
EPA 200.7
02/03/2022 17:05
DMFRANC
Boron (B)
0.949
mg/L
0.05
0.005
1
EPA 200.7
02/03/2022 17:05
DMFRANC
Iron (Fe)
16.9
mg/L
0.01
0.004
1
EPA 200.7
02/03/2022 17:05
DMFRANC
Manganese (Mn)
4.95
mg/L
0.005
0.001
1
EPA 200.7
02/03/2022 17:05
DMFRANC
Strontium (Sr)
2.20
mg/L
0.005
0.001
1
EPA 200.7
02/03/2022 17:05
DMFRANC
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
1
EPA 200.7
02/03/2022 17:05
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.177
mg/L
0.01
0.003
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Barium (Ba)
0.275
mg/L
0.005
0.002
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Boron (B)
0.990
mg/L
0.05
0.005
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Calcium (Ca)
136
mg/L
1
0.012
20
EPA 200.7
02/04/2022 14:48
DMFRANC
Iron (Fe)
23.3
mg/L
0.01
0.004
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Magnesium (Mg)
25.3
mg/L
0.02
0.008
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Manganese (Mn)
5.05
mg/L
0.005
0.001
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Potassium (K)
4.39
mg/L
0.1
0.031
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Sodium (Na)
6.20
mg/L
0.05
0.017
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Strontium (Sr)
2.38
mg/L
0.005
0.001
1
EPA 200.7
02/04/2022 14:48
DMFRANC
Total Hardness (Ca and Mg)
444
mg/L
0.066
1
EPA 200.7
02/04/2022 14:48
DMFRANC
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
1
EPA 200.7
02/04/2022 14:48
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-8-A1
Collection Date: 01/24/2022 01:10 PM Loc code: ASA SW-8-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
281
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
6.97
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
57.5
ug/L
1
0.18
1
Nickel (Ni)
0.26
ug/L J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.16
ug/L J
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
437
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
6.90
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.238
ug/L
0.2
0.037
1
Molybdenum (Mo)
56.5
ug/L
1
0.18
1
Nickel (Ni)
0.305
ug/L J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.352
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 44 of 151
Sample #: 2022001834
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/02/2022 22:42
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
EPA 200.8
02/03/2022 16:23
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-8-A1
Collection Date: 01/24/2022 01:10 PM Loc code: ASA SW-8-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 45 of 151
Sample #: 2022001834
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.5 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202217:24 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA FtB-20220124-1405 Filter Blank
Collection Date: 01/24/2022 02:05 PM Loc code: ASA FtB
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
< 0.005
mg/L
0.005
0.002
Boron (B)
< 0.05
mg/L
0.05
0.005
Iron (Fe)
0.023
mg/L
0.01
0.004
Manganese (Mn)
< 0.005
mg/L
0.005
0.001
Strontium (Sr)
< 0.005
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
Arsenic (As)
< 1
ug/L
1
0.111
Beryllium (Be)
< 1
ug/L
1
0.249
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
Chromium (Cr)
< 1
ug/L
1
0.185
Cobalt (Co)
< 1
ug/L
1
0.077
Copper (Cu)
< 2
ug/L
2
0.787
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
Molybdenum (Mo)
< 1
ug/L
1
0.18
Nickel (Ni)
< 1
ug/L
1
0.256
Selenium (Se)
< 1
ug/L
1
0.193
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
REVISION
Page 46 of 151
Sample #:
2022001835
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1
EPA 200.7
02/03/2022 17:10
DMFRANC
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3
1 EPA 200.8
02/02/2022 22:51
CWSPEN3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-9-A1
Collection Date: 01/24/2022 09:45 AM Loc code: ASA SW-9-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 20.2 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 20.2 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 47 of 151
Sample #: 2022001836
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 20:32 EBATIAN
1 SM 2320E-2011 01/26/2022 20:32 EBATIAN
1 SM 2320B-2011 01/26/2022 20:32 EBATIAN
Chloride
18
mg/L
0.5
0.0154 5
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
2.9
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.004
mg/L
J 0.01
0.003
Barium (Ba)
0.048
mg/L
0.005
0.002
Boron (B)
0.023
mg/L
J 0.05
0.005
Iron (Fe)
0.259
mg/L
0.01
0.004
Manganese (Mn)
0.358
mg/L
0.005
0.001
Strontium (Sr)
0.071
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.019
mg/L
0.01
0.003
Barium (Ba)
0.052
mg/L
0.005
0.002
Boron (B)
0.022
mg/L
J 0.05
0.005
Calcium (Ca)
8.31
mg/L
0.05
0.012
Iron (Fe)
0.434
mg/L
0.01
0.004
Magnesium (Mg)
3.48
mg/L
0.02
0.008
Manganese (Mn)
0.353
mg/L
0.005
0.001
Potassium (K)
1.61
mg/L
0.1
0.031
Sodium (Na)
8.39
mg/L
0.05
0.017
Strontium (Sr)
0.075
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
35.1
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/27/2022 02:26
BGN9034
EPA
300.0
01/27/2022 02:26
BGN9034
EPA
300.0
01/27/2022 02:26
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/03/2022 17:14
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC
1 EPA 200.7
02/04/2022 14:53
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-9-A1
Collection Date: 01/24/2022 09:45 AM Loc code: ASA SW-9-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
0.854
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.475
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.044
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
1.50
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
0.845
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.166
ug/L
J
0.2
0.037
1
Molybdenum (Mo)
0.339
ug/L
J
1
0.18
1
Nickel (Ni)
0.418
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
REVISION
Page 48 of 151
Sample #: 2022001836
Matrix: GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/02/2022 23:01
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
EPA 200.8
02/03/2022 16:32
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-9-A1
Collection Date: 01/24/2022 09:45 AM Loc code: ASA SW-9-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 49 of 151
Sample #: 2022001836
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.7 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202217:42 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-9-A1
Collection Date: 01/24/2022 10:00 AM Loc code: ASA SW-9-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010381
Total Alkalinity as CaCO3 25.1 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 25.1 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22010358
REVISION
Page 50 of 151
Sample #: 2022001837
Matrix: GW WW
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/26/2022 20:35 EBATIAN
1 SM 2320E-2011 01/26/2022 20:35 EBATIAN
1 SM 2320B-2011 01/26/2022 20:35 EBATIAN
Chloride
18
mg/L
0.5
0.0154 5
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
3.7
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010407
Aluminum (AI)
0.005
mg/L
J 0.01
0.003
Barium (Ba)
0.052
mg/L
0.005
0.002
Boron (B)
0.037
mg/L
J 0.05
0.005
Iron (Fe)
0.269
mg/L
0.01
0.004
Manganese (Mn)
0.402
mg/L
0.005
0.001
Strontium (Sr)
0.091
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010409
Aluminum (AI)
0.018
mg/L
0.01
0.003
Barium (Ba)
0.051
mg/L
0.005
0.002
Boron (B)
0.034
mg/L
J 0.05
0.005
Calcium (Ca)
8.97
mg/L
0.05
0.012
Iron (Fe)
0.410
mg/L
0.01
0.004
Magnesium (Mg)
3.79
mg/L
0.02
0.008
Manganese (Mn)
0.391
mg/L
0.005
0.001
Potassium (K)
1.62
mg/L
0.1
0.031
Sodium (Na)
8.04
mg/L
0.05
0.017
Strontium (Sr)
0.085
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
38.0
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
01/27/2022 02:46
BGN9034
EPA
300.0
01/27/2022 02:46
BGN9034
EPA
300.0
01/27/2022 02:46
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 11:55
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC
1 EPA 200.7
02/04/2022 14:58
DMFRANC

REVISION
Certificate of Laboratory Analysis Page 51 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-9-A1
Sample #: 2022001837
Collection Date: 01/24/2022 10:00 AM
Loc code: ASA
SW-9-A1
Matrix: GW WW
Analyte
Result
Units
Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010413
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Arsenic (As)
0.196
ug/L
J
1
0.111
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Cobalt (Co)
0.936
ug/L
J
1
0.077
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Molybdenum (Mo)
0.209
ug/L
J
1
0.18
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Nickel (Ni)
0.57
ug/L
J
1
0.256
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Selenium (Se)
< 1
ug/L
1
0.193
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Thallium (TI) Low Level
0.044
ug/L
J
0.2
0.041
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/02/2022 23:10
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010415
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Arsenic (As)
0.293
ug/L
J
1
0.111
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Chromium (Cr)
0.196
ug/L
J
1
0.185
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Cobalt (Co)
0.976
ug/L
J
1
0.077
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Lead (Pb) Low Level
0.159
ug/L
J
0.2
0.037
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Molybdenum (Mo)
0.213
ug/L
J
1
0.18
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Nickel (Ni)
0.47
ug/L
J
1
0.256
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Selenium (Se)
< 1
ug/L
1
0.193
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/03/2022 16:41
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA SW-9-A1
Collection Date: 01/24/2022 10:00 AM Loc code: ASA SW-9-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010398
REVISION
Page 52 of 151
Sample #: 2022001837
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.8 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/27/202218:00 EBATIAN

REVISION
Certificate of Laboratory Analysis Page 53 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Site: ASA FB-20220124-1405 Field Blank Sample #: 2022001983
Collection Date: 01/24/2022 02:05 PM Loc code: ASA FB Matrix: GW WW
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

REVISION
Certificate of Laboratory Analysis Page 54 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010381 ALK_CarbBicarb TOTAL ALKALINITY
Duplicate # 1
Parameter Measured
Final
Alkalinity, Bicarbonate
137
Alkalinity, Carbonate
0
Total Alkalinity as
137
CaCO3
Duplicate # 2
Parameter Measured
Final
Alkalinity, Bicarbonate
151
Alkalinity, Carbonate
0
Total Alkalinity as
151
CaCO3
LCS # 1
Parameter Measured Final
Total Alkalinity as 93.8
CaCO3
LCS # 2
Parameter Measured Final
Total Alkalinity as 93
CaCO3
Parent Sample: J22010352 -- 2022001774
Units: Dil RPD Qualifier
mg/L 1 0.211
mg/L 1 0
mg/L 1 0.211
Parent Sample: J22010352 -- 2022001776
Units: Dil RPD Qualifier
mg/L 1 1.21
mg/L 1 0
mg/L 1 1.21
Units: Dil Spike % Recovery LCL UCL Qualifier
mg/L 1 95.5 98.2 85 115
Units: Dil Spike % Recovery LCL UCL Qualifier
mg/L 1 95.5 97.4 85 115

REVISION
Certificate of Laboratory Analysis Page 55 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010397 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample: J22010361 -- 2022001822
Parameter Measured
Final
Units:
Dil
RPD Qualifier
Alkalinity, Bicarbonate
12.4
mg/L
1
0.972
Alkalinity, Carbonate
0
mg/L
1
0
Total Alkalinity as
12.4
mg/L
1
0.972
CaCO3
LCS # 1
Parameter Measured
Final
Units:
Dil
Spike % Recovery LCL UCL Qualifier
Total Alkalinity as
47.2
mg/L
1
50.9 92.7 85 115
CaCO3
(CaCO3)

REVISION
Certificate of Laboratory Analysis Page 56 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010358 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.1
< 1/2 RDL
Fluoride
0
0
mg/L
1
0.1
< 1/2 RDL
Sulfate
0
0
mg/L
1
0.1
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Chloride
2.03
2.03
mg/L
1
2
102 90
110
Fluoride
2.06
2.06
mg/L
1
2
103 90
110
Sulfate
1.94
1.94
mg/L
1
2
96.8 90
110
MS # 1
Parent Sample:
J22010361
-- 2022001827
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Chloride
4.34
4.34
mg/L
1
2
100 80
120
Fluoride
2.1
2.1
mg/L
1
2
104 80
120
Sulfate
9.48
9.48
mg/L
1
2
92 80
120
MSD # 1
Parent Sample:
J22010361
-- 2022001827
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Chloride
4.31
4.31
mg/L
1
2
99.2 80
120
1.3
Fluoride
2.06
2.06
mg/L
1
2
103 80
120
1.74
Sulfate
9.44
9.44
mg/L
1
2
89.7 80
120
2.53
MS # 2
Parent Sample:
J22010361
-- 2022001831
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Chloride
3.87
19.3
mg/L
5
10
102 80
120
Fluoride
2.05
2.05
mg/L
1
2
102 80
120
Sulfate
5.5
5.5
mg/L
1
2
98.6 80
120
MSD # 2
Parent Sample:
J22010361
-- 2022001831
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
Chloride
3.86
19.3
mg/L
5
10
101 80
120
0.247
Fluoride
2.05
2.05
mg/L
1
2
102 80
120
0.0492
Sulfate
5.47
5.47
mg/L
1
2
96.9 80
120
1.74
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

REVISION
Certificate of Laboratory Analysis Page 57 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010407 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Aluminum (AI)
0.000323
0.000323
mg/L
1
0.01
< 1/2 RDL
Barium (Ba)
-0.000197
-0.000197
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.00106
-0.00106
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
-0.00106
-0.00106
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000097
-0.000097
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
-0.000263
-0.000263
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000736
-0.000736
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Aluminum (AI)
4.81
4.81
mg/L
1
5
96.1
85
115
Barium (Ba)
4.61
4.61
mg/L
1
5
92.2
85
115
Boron (B)
4.58
4.58
mg/L
1
5
91.6
85
115
Iron (Fe)
4.63
4.63
mg/L
1
5
92.5
85
115
Manganese (Mn)
4.63
4.63
mg/L
1
5
92.7
85
115
Strontium (Sr)
4.44
4.44
mg/L
1
5
88.8
85
115
Zinc (Zn)
4.58
4.58
mg/L
1
5
91.5
85
115
MS # 1
Parent Sample:
J22010361 -- 2022001823
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Aluminum (AI)
5
5
mg/L
1
5
100
70
130
Barium (Ba)
4.86
4.86
mg/L
1
5
96.3
70
130
Boron (B)
4.83
4.83
mg/L
1
5
95.7
70
130
Iron (Fe)
4.95
4.95
mg/L
1
5
96.2
70
130
Manganese (Mn)
5.08
5.08
mg/L
1
5
96.4
70
130
Strontium (Sr)
4.75
4.75
mg/L
1
5
93.1
70
130
Zinc (Zn)
4.73
4.73
mg/L
1
5
94.6
70
130
MS # 2
Parent Sample:
J22010361 -- 2022001824
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Aluminum (AI)
4.98
4.98
mg/L
1
5
99.6
70
130
Barium (Ba)
4.81
4.81
mg/L
1
5
95.4
70
130
Boron (B)
4.78
4.78
mg/L
1
5
94.8
70
130
Iron (Fe)
4.91
4.91
mg/L
1
5
95.3
70
130
Manganese (Mn)
5.06
5.06
mg/L
1
5
96
70
130
Strontium (Sr)
4.68
4.68
mg/L
1
5
91.9
70
130
Zinc (Zn)
4.7
4.7
mg/L
1
5
94
70
130
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

REVISION
Certificate of Laboratory Analysis Page 58 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010409 1CP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Aluminum (AI)
0.000395
0.000395
mg/L
1
0.01
< 1/2 RDL
Barium (Ba)
-0.000277
-0.000277
mg/L
1
0.005
< 1/2 RDL
Boron (B)
0.000569
0.000569
mg/L
1
0.05
< 1/2 RDL
Calcium (Ca)
-0.00154
-0.00154
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
0.00121
0.00121
mg/L
1
0.01
< 1/2 RDL
Magnesium (Mg)
0.00159
0.00159
mg/L
1
0.02
< 1/2 RDL
Manganese (Mn)
-0.000091
-0.000091
mg/L
1
0.005
< 1/2 RDL
Potassium (K)
0.000152
0.000152
mg/L
1
0.1
< 1/2 RDL
Sodium (Na)
0.0119
0.0119
mg/L
1
0.05
< 1/2 RDL
Strontium (Sr)
-0.000237
-0.000237
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000667
-0.000667
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.02
5.02
mg/L
1
5
100
85
115
Barium (Ba)
5.13
5.13
mg/L
1
5
103
85
115
Boron (B)
4.96
4.96
mg/L
1
5
99.1
85
115
Calcium (Ca)
4.96
4.96
mg/L
1
5
99.2
85
115
Iron (Fe)
4.96
4.96
mg/L
1
5
99.1
85
115
Magnesium (Mg)
4.83
4.83
mg/L
1
5
96.6
85
115
Manganese (Mn)
4.95
4.95
mg/L
1
5
99
85
115
Potassium (K)
5.01
5.01
mg/L
1
5
100
85
115
Sodium (Na)
5.01
5.01
mg/L
1
5
100
85
115
Strontium (Sr)
5.03
5.03
mg/L
1
5
101
85
115
Zinc (Zn)
4.88
4.88
mg/L
1
5
97.6
85
115
MS # 1
Parent Sample:
J22010361 -- 2022001821
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.1
5.1
mg/L
1
5
101
70
130
Barium (Ba)
5.22
5.22
mg/L
1
5
103
70
130
Boron (B)
4.98
4.98
mg/L
1
5
99.5
70
130
Calcium (Ca)
11.1
11.1
mg/L
1
5
100
70
130
Iron (Fe)
6.02
6.02
mg/L
1
5
99.1
70
130
Magnesium (Mg)
7.43
7.43
mg/L
1
5
96.6
70
130
Manganese (Mn)
5.14
5.14
mg/L
1
5
99.3
70
130
Potassium (K)
6.49
6.49
mg/L
1
5
101
70
130
Sodium (Na)
12.5
12.5
mg/L
1
5
102
70
130
Strontium (Sr)
5.08
5.08
mg/L
1
5
100
70
130
Zinc (Zn)
4.88
4.88
mg/L
1
5
97.5
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010409 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (AI)
5.1
5.1
mg/L
1
5
Barium (Ba)
5.21
5.21
mg/L
1
5
Boron (B)
4.99
4.99
mg/L
1
5
Calcium (Ca)
11.1
11.1
mg/L
1
5
Iron (Fe)
6.03
6.03
mg/L
1
5
Magnesium (Mg)
7.47
7.47
mg/L
1
5
Manganese (Mn)
5.14
5.14
mg/L
1
5
Potassium (K)
6.5
6.5
mg/L
1
5
Sodium (Na)
12.6
12.6
mg/L
1
5
Strontium (Sr)
5.1
5.1
mg/L
1
5
Zinc (Zn)
4.9
4.9
mg/L
1
5
MS # 2
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (AI)
5.09
5.09
mg/L
1
5
Barium (Ba)
5.19
5.19
mg/L
1
5
Boron (B)
4.97
4.97
mg/L
1
5
Calcium (Ca)
10.9
10.9
mg/L
1
5
Iron (Fe)
5.96
5.96
mg/L
1
5
Magnesium (Mg)
7.33
7.33
mg/L
1
5
Manganese (Mn)
5.1
5.1
mg/L
1
5
Potassium (K)
6.45
6.45
mg/L
1
5
Sodium (Na)
12.4
12.4
mg/L
1
5
Strontium (Sr)
5.1
5.1
mg/L
1
5
Zinc (Zn)
4.82
4.82
mg/L
1
5
MSD # 2
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (AI)
5.06
5.06
mg/L
1
5
Barium (Ba)
5.16
5.16
mg/L
1
5
Boron (B)
4.93
4.93
mg/L
1
5
Calcium (Ca)
10.8
10.8
mg/L
1
5
Iron (Fe)
5.92
5.92
mg/L
1
5
Magnesium (Mg)
7.25
7.25
mg/L
1
5
Manganese (Mn)
5.06
5.06
mg/L
1
5
Potassium (K)
6.41
6.41
mg/L
1
5
Sodium (Na)
12.3
12.3
mg/L
1
5
Strontium (Sr)
5.07
5.07
mg/L
1
5
Zinc (Zn)
4.8
4.8
mg/L
1
5
REVISION
Page 59 of 151
Parent Sample: J22010361 -- 2022001821
% Recovery
LCL
UCL
RPD Qualifier
101
70
130
0
103
70
130
0.249
99.7
70
130
0.16
100
70
130
0.0362
99.3
70
130
0.166
97.5
70
130
0.564
99.3
70
130
0.0194
101
70
130
0.154
103
70
130
0.143
101
70
130
0.432
97.7
70
130
0.286
Parent Sample: J22010361 -- 2022001822
% Recovery
LCL
UCL Qualifier
100
70
130
103
70
130
99.2
70
130
102
70
130
99.2
70
130
96.4
70
130
98.5
70
130
101
70
130
104
70
130
101
70
130
96.3
70
130
Parent Sample: J22010361 -- 2022001822
% Recovery
LCL
UCL
RPD Qualifier
99.8
70
130
0.611
102
70
130
0.637
98.6
70
130
0.667
101
70
130
0.672
98.5
70
130
0.572
94.8
70
130
1.13
97.8
70
130
0.728
100
70
130
0.669
102
70
130
0.591
100
70
130
0.747
95.9
70
130
0.374

REVISION
Certificate of Laboratory Analysis Page 60 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010409 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

REVISION
Certificate of Laboratory Analysis Page 61 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010413 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Antimony (Sb)
-0.011
-0.011
ug/L
1
1
< 1/2 RDL
Arsenic (As)
0.002
0.002
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
-0.028
-0.028
ug/L
1
1
< 1/2 RDL
Cadmium (Cd) Low Level
-0.011
-0.011
ug/L
1
0.1
< 1/2 RDL
Chromium (Cr)
-0.06
-0.06
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
-0.011
-0.011
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.051
-0.051
ug/L
1
2
< 1/2 RDL
Lead (Pb) Low Level
-0.027
-0.027
ug/L
1
0.2
< 1/2 RDL
Molybdenum (Mo)
-0.025
-0.025
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
0.008
0.008
ug/L
1
1
< 1/2 RDL
Selenium (Se)
-0.009
-0.009
ug/L
1
1
< 1/2 RDL
Silver (Ag) Low Level
0.004
0.004
ug/L
1
0.2
< 1/2 RDL
Thallium (TI) Low Level
0.036
0.036
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.071
0.071
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
52.1
52.1
ug/L
1
50
104
85
115
Arsenic (As)
52.7
52.7
ug/L
1
50
105
85
115
Beryllium (Be)
52.3
52.3
ug/L
1
50
105
85
115
Cadmium (Cd) Low Level
52.1
52.1
ug/L
1
50
104
85
115
Chromium (Cr)
51.9
51.9
ug/L
1
50
104
85
115
Cobalt (Co)
53.2
53.2
ug/L
1
50
106
85
115
Copper (Cu)
52.5
52.5
ug/L
1
50
105
85
115
Lead (Pb) Low Level
52.2
52.2
ug/L
1
50
104
85
115
Molybdenum (Mo)
52.3
52.3
ug/L
1
50
105
85
115
Nickel (Ni)
53.1
53.1
ug/L
1
50
106
85
115
Selenium (Se)
50.5
50.5
ug/L
1
50
101
85
115
Silver (Ag) Low Level
52.9
52.9
ug/L
1
50
106
85
115
Thallium (TI) Low Level
50
50
ug/L
1
50
100
85
115
Vanadium (V) Low Level
51.8
51.8
ug/L
1
50
104
85
115
MS # 1
Parent Sample:
J22010361 -- 2022001821
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
51.8
51.8
ug/L
1
50
104
70
130
Arsenic (As)
52.3
52.3
ug/L
1
50
104
70
130
Beryllium (Be)
52.2
52.2
ug/L
1
50
104
70
130
Cadmium (Cd) Low Level
52.1
52.1
ug/L
1
50
104
70
130
Chromium (Cr)
52.2
52.2
ug/L
1
50
104
70
130
Cobalt (Co)
51.9
51.9
ug/L
1
50
103
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010413 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MS # 1
Parameter
Measured
Final
Units:
Dil
Spike
Copper (Cu)
51.7
51.7
ug/L
1
50
Lead (Pb) Low Level
51.9
51.9
ug/L
1
50
Molybdenum (Mo)
52.1
52.1
ug/L
1
50
Nickel (Ni)
52.1
52.1
ug/L
1
50
Selenium (Se)
50
50
ug/L
1
50
Silver (Ag) Low Level
52
52
ug/L
1
50
Thallium (TI) Low Level
45.8
45.8
ug/L
1
50
Vanadium (V) Low Level
52.4
52.4
ug/L
1
50
MS # 2
Parameter
Measured
Final
Units:
Dil
Spike
Antimony (Sb)
51.7
51.7
ug/L
1
50
Arsenic (As)
51.6
51.6
ug/L
1
50
Beryllium (Be)
52
52
ug/L
1
50
Cadmium (Cd) Low Level
51.5
51.5
ug/L
1
50
Chromium (Cr)
52.4
52.4
ug/L
1
50
Cobalt (Co)
50.6
50.6
ug/L
1
50
Copper (Cu)
50.5
50.5
ug/L
1
50
Lead (Pb) Low Level
51.8
51.8
ug/L
1
50
Molybdenum (Mo)
51.4
51.4
ug/L
1
50
Nickel (Ni)
51
51
ug/L
1
50
Selenium (Se)
49.5
49.5
ug/L
1
50
Silver (Ag) Low Level
51.7
51.7
ug/L
1
50
Thallium (TI) Low Level
44
44
ug/L
1
50
Vanadium (V) Low Level
52.7
52.7
ug/L
1
50
Qualifiers:
REVISION
Page 62 of 151
Parent Sample: J22010361 -- 2022001821
% Recovery
LCL
UCL Qualifier
103
70
130
104
70
130
104
70
130
104
70
130
100
70
130
104
70
130
91.4
70
130
104
70
130
Parent Sample: J22010361 -- 2022001822
% Recovery
LCL
UCL Qualifier
103
70
130
103
70
130
104
70
130
103
70
130
104
70
130
101
70
130
100
70
130
104
70
130
103
70
130
101
70
130
98.9
70
130
103
70
130
87.9
70
130
105
70
130
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

REVISION
Certificate of Laboratory Analysis Page 63 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010415 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Antimony (Sb)
-0.014
-0.014
ug/L
1
1
< 1/2 RDL
Arsenic (As)
0.012
0.012
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
-0.003
-0.003
ug/L
1
1
< 1/2 RDL
Cadmium (Cd) Low Level
-0.003
-0.003
ug/L
1
0.1
< 1/2 RDL
Chromium (Cr)
0.032
0.032
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
0.01
0.01
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.006
-0.006
ug/L
1
2
< 1/2 RDL
Lead (Pb) Low Level
0.015
0.015
ug/L
1
0.2
< 1/2 RDL
Molybdenum (Mo)
0.015
0.015
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
0.004
0.004
ug/L
1
1
< 1/2 RDL
Selenium (Se)
-0.03
-0.03
ug/L
1
1
< 1/2 RDL
Silver (Ag) Low Level
0.005
0.005
ug/L
1
0.2
< 1/2 RDL
Thallium (TI) Low Level
0.002
0.002
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.001
0.001
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
49
49
ug/L
1
50
98.1
85
115
Arsenic (As)
49.5
49.5
ug/L
1
50
99
85
115
Beryllium (Be)
48.4
48.4
ug/L
1
50
96.9
85
115
Cadmium (Cd) Low Level
49.6
49.6
ug/L
1
50
99.2
85
115
Chromium (Cr)
49.1
49.1
ug/L
1
50
98.3
85
115
Cobalt (Co)
49.1
49.1
ug/L
1
50
98.3
85
115
Copper (Cu)
48.5
48.5
ug/L
1
50
97.1
85
115
Lead (Pb) Low Level
49.8
49.8
ug/L
1
50
99.6
85
115
Molybdenum (Mo)
49
49
ug/L
1
50
98.1
85
115
Nickel (Ni)
49.2
49.2
ug/L
1
50
98.5
85
115
Selenium (Se)
49.8
49.8
ug/L
1
50
99.6
85
115
Silver (Ag) Low Level
49.5
49.5
ug/L
1
50
98.9
85
115
Thallium (TI) Low Level
48.3
48.3
ug/L
1
50
96.7
85
115
Vanadium (V) Low Level
49.2
49.2
ug/L
1
50
98.3
85
115
MS # 1
Parent Sample:
J22010361 -- 2022001823
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
49.2
49.2
ug/L
1
50
98.3
70
130
Arsenic (As)
48.7
48.7
ug/L
1
50
97.3
70
130
Beryllium (Be)
49
49
ug/L
1
50
98
70
130
Cadmium (Cd) Low Level
48.7
48.7
ug/L
1
50
97.4
70
130
Chromium (Cr)
48.6
48.6
ug/L
1
50
96.6
70
130
Cobalt (Co)
48
48
ug/L
1
50
94.6
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010415 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
REVISION
Page 64 of 151
MS # 1
Parent Sample:
J22010361 -- 2022001823
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Copper (Cu)
47.7
47.7
ug/L
1
50
94.8
70
130
Lead (Pb) Low Level
49.5
49.5
ug/L
1
50
98.4
70
130
Molybdenum (Mo)
48.3
48.3
ug/L
1
50
96.3
70
130
Nickel (Ni)
48.4
48.4
ug/L
1
50
95.9
70
130
Selenium (Se)
50.6
50.6
ug/L
1
50
100
70
130
Silver (Ag) Low Level
48.5
48.5
ug/L
1
50
97
70
130
Thallium (TI) Low Level
47.3
47.3
ug/L
1
50
94.6
70
130
Vanadium (V) Low Level
49.5
49.5
ug/L
1
50
98.6
70
130
MSD # 1
Parent Sample:
J22010361
-- 2022001823
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Antimony (Sb)
50.1
50.1
ug/L
1
50
100
70
130
1.83
Arsenic (As)
50.1
50.1
ug/L
1
50
100
70
130
2.73
Beryllium (Be)
48.4
48.4
ug/L
1
50
96.8
70
130
1.22
Cadmium (Cd) Low Level
49.8
49.8
ug/L
1
50
99.6
70
130
2.22
Chromium (Cr)
49.5
49.5
ug/L
1
50
98.3
70
130
1.83
Cobalt (Co)
49.6
49.6
ug/L
1
50
97.8
70
130
3.32
Copper (Cu)
48.8
48.8
ug/L
1
50
97.1
70
130
2.38
Lead (Pb) Low Level
50.9
50.9
ug/L
1
50
101
70
130
2.86
Molybdenum (Mo)
49.7
49.7
ug/L
1
50
99.1
70
130
2.89
Nickel (Ni)
49.3
49.3
ug/L
1
50
97.8
70
130
1.93
Selenium (Se)
49.8
49.8
ug/L
1
50
98.6
70
130
1.6
Silver (Ag) Low Level
49.5
49.5
ug/L
1
50
99.1
70
130
2.11
Thallium (TI) Low Level
49.2
49.2
ug/L
1
50
98.3
70
130
3.85
Vanadium (V) Low Level
51
51
ug/L
1
50
102
70
130
2.95
MS # 2
Parent Sample:
J22010361
-- 2022001824
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Antimony (Sb)
49.3
49.3
ug/L
1
50
98.5
70
130
Arsenic (As)
49
49
ug/L
1
50
98
70
130
Beryllium (Be)
47.6
47.6
ug/L
1
50
95.2
70
130
Cadmium (Cd) Low Level
49.1
49.1
ug/L
1
50
98.1
70
130
Chromium (Cr)
49.3
49.3
ug/L
1
50
98.1
70
130
Cobalt (Co)
48.3
48.3
ug/L
1
50
95.2
70
130
Copper (Cu)
47.5
47.5
ug/L
1
50
94.8
70
130
Lead (Pb) Low Level
49.8
49.8
ug/L
1
50
99.3
70
130
Molybdenum (Mo)
48.7
48.7
ug/L
1
50
97.1
70
130
Nickel (Ni)
48.1
48.1
ug/L
1
50
95.5
70
130
Selenium (Se)
49.4
49.4
ug/L
1
50
98
70
130
Silver (Ag) Low Level
48.6
48.6
ug/L
1
50
97.2
70
130

REVISION
Certificate of Laboratory Analysis Page 65 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010415 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 2
Parent Sample:
J22010361 -- 2022001824
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Thallium (TI) Low Level
47.9
47.9
ug/L
1
50
95.7
70
130
Vanadium (V) Low Level
50.2
50.2
ug/L
1
50
100
70
130
MSD # 2
Parent Sample:
J22010361
-- 2022001824
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD Qualifier
Antimony (Sb)
50.8
50.8
ug/L
1
50
101
70
130
2.96
Arsenic (As)
49.3
49.3
ug/L
1
50
98.6
70
130
0.635
Beryllium (Be)
48.1
48.1
ug/L
1
50
96.2
70
130
1.11
Cadmium (Cd) Low Level
49.6
49.6
ug/L
1
50
99.2
70
130
1.07
Chromium (Cr)
49.8
49.8
ug/L
1
50
99.1
70
130
1.01
Cobalt (Co)
48.6
48.6
ug/L
1
50
96
70
130
0.776
Copper(Cu)
48
48
ug/L
1
50
95.7
70
130
1.01
Lead (Pb) Low Level
50.8
50.8
ug/L
1
50
101
70
130
1.89
Molybdenum (Mo)
49.4
49.4
ug/L
1
50
98.5
70
130
1.37
Nickel (Ni)
48.9
48.9
ug/L
1
50
97
70
130
1.53
Selenium (Se)
50.1
50.1
ug/L
1
50
99.3
70
130
1.34
Silver (Ag) Low Level
49.2
49.2
ug/L
1
50
98.4
70
130
1.16
Thallium (TI) Low Level
48.8
48.8
ug/L
1
50
97.5
70
130
1.89
Vanadium (V) Low Level
50.9
50.9
ug/L
1
50
102
70
130
1.27
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

REVISION
Certificate of Laboratory Analysis Page 66 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010398 Total Carbon Total Carbon
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.004
0.004
mg/L
1
0.1
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.018
0.018
mg/L
1
0.1
< 1/2 RDL
Blank # 3
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.02
0.02
mg/L
1
0.1
< 1/2 RDL
Blank # 4
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.04
0.04
mg/L
1
0.1
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
TOC
2.58
2.58
mg/L
1
2.71
95.3 85
115
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
TOC
2.6
2.6
mg/L
1
2.71
95.9 85
115
LCS # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
TOC
2.64
2.64
mg/L
1
2.71
97.5 85
115
LCS # 4
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
TOC
2.64
2.64
mg/L
1
2.71
97.6 85
115
MS # 1
Parent Sample:
J22010361
-- 2022001821
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
TOC
3.61
3.61
mg/L
1
2
93.7 80
120
MSD # 1
Parent Sample:
J22010361
-- 2022001821
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
TOC
3.65
3.65
mg/L
1
2
96 80
120
2.43
MS # 2
Parent Sample:
J22010361
-- 2022001831
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
TOC
2.28
22.8
mg/L
10
2
966 80
120
M4
MSD # 2
Parent Sample:
J22010361
-- 2022001831
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD Qualifier
TOC
2.28
22.8
mg/L
10
2
966 80
120
0.0518 M4

Certificate of LaboratoryAnalysis REVISION
y Page 67 of 151
This report shall not be reproduced, except in full.
Order # J22010361
Level II QC Summary
Q22010398 Total Carbon Total Carbon
MS # 3
Parent Sample:
J22010390 -- 2022001990
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL Qualifier
TOC
1.71
1.71
mg/L
1
2
57.6 80
120 M
MSD # 3
Parent Sample:
J22010390 -- 2022001990
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL RPD Qualifier
TOC
1.69
1.69
mg/L
1
2
56.8 80
120 1.49 M
MS # 4
Parent Sample:
J22010392 -- 2022001999
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL Qualifier
TOC
2.72
2.72
mg/L
1
2
100 80
120
MSD # 4
Parent Sample:
J22010392 -- 2022001999
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL RPD Qualifier
TOC
2.77
2.77
mg/L
1
2
102 80
120 2.18
Qualifiers:
M Matrix Spike and/or Matrix Spike Duplicate recovery was outside of the control limits. The associated
Laboratory Control Spike (LCS) recovery was acceptable.
M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate
to the spike level. The associated Laboratory Control Spike recovery was acceptable.

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Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: 21--213 SW J22010361
Pace Project No.: 92584118
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 24, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��K— ���
Tyler Forney for
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92584118001
SW-2-Al
Water
01/24/22 14:35
01/24/22 16:10
92584118002
SW-2-Al
Water
01/24/2214:50
01/24/22 16:10
92584118003
SW-3-Al
Water
01/24/2211:35
01/24/22 16:10
92584118004
SW-3-Al
Water
01/24/2211:45
01/24/22 16:10
92584118005
SW-413-A1
Water
01/24/2210:15
01/24/22 16:10
92584118006
SW-413-A1
Water
01/24/2210:25
01/24/22 16:10
92584118007
SW-4C-A1
Water
01/24/2210:45
01/24/22 16:10
92584118008
SW-4C-A1
Water
01/24/2210:55
01/24/22 16:10
92584118009
SW-5-Al
Water
01/24/2212:15
01/24/22 16:10
92584118010
SW-5-Al
Water
01/24/2212:30
01/24/22 16:10
92584118011
SW-6-Al
Water
01/24/2213:30
01/24/22 16:10
92584118012
SW-6-Al
Water
01/24/2213:45
01/24/22 16:10
92584118013
SW-8-Al
Water
01/24/2212:50
01/24/22 16:10
92584118014
SW-8-Al
Water
01/24/2213:10
01/24/22 16:10
92584118015
SW-9-Al
Water
01/24/22 09:45
01/24/22 16:10
92584118016
SW-9-Al
Water
01/24/2210:00
01/24/22 16:10
92584118017
ASA FB-20220124-1405
Water
01/24/22 14:05
01/24/22 16:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
2L-2B SW J22010361
92584118
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92584118001
SW-2-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118002
SW-2-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118003
SW-3-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118004
SW-3-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118005
SW-413-A1
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118006
SW-413-A1
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118007
SW-4C-Al
RSK 175 Modified
MAD
1
PASI-C
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118008
SW-4C-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118009
SW-5-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118010
SW-5-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118011
SW-6-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118012
SW-6-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118013
SW-8-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118014
SW-8-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118015
SW-9-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118016
SW-9-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584118017
ASA FB-20220124-1405
EPA 1631E
NMP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Lab Sample ID Client Sample ID
Method Parameters
92584118001
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118002
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118003
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118004
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118005
RSK 175 Modified
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584118006
RSK 175 Modified
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584118007
RSK 175 Modified
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118008
RSK 175 Modified
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118009
RSK 175 Modified
SW-2-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-2-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-3-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-3-Al
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-4B-Al
Methane
Mercury
Nitrogen, NO2 plus NO3
SW-46-Al
Methane
Mercury
Nitrogen, NO2 plus NO3
SW-4C-Al
Methane
Mercury
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-4C-Al
Methane
Mercury
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-5-Al
Methane
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
22.3
ug/L
10.0
01 /25/22 16:58
2.43
ng/L
0.50
01 /28/22 15:08
1.20
ng/L
0.50
01 /27/22 14:01
0.063
ug/L
0.025
01 /26/22 14:16
2.0
mg/L
0.040
01 /27/22 13:19
28.6
ug/L
10.0
01 /25/22 17:29
2.73
ng/L
0.50
01 /28/22 15:32
1.43
ng/L
0.50
01 /27/22 14:24
0.073
ug/L
0.025
01 /26/22 16:27
2.0
mg/L
0.040
01 /27/22 13:20
10.7
ug/L
10.0
01 /25/22 17:44
1.73
ng/L
0.50
01 /28/22 15:40
0.767
ng/L
0.50
01 /27/22 14:32
0.045
ug/L
0.025
01 /26/22 16:43
1.1
mg/L
0.040
01 /27/22 13:22
0.948
ng/L
0.50
01 /28/22 15:47
0.811
ng/L
0.50
01 /27/22 14:40
0.058
ug/L
0.025
01 /26/22 17:00
1.1
mg/L
0.040
01 /27/22 13:23
38.0
ug/L
10.0
01 /25/22 18:15
0.636
ng/L
0.50
01 /28/22 15:55
0.31
mg/L
0.040
01 /27/22 13:24
36.4
ug/L
10.0
01 /25/22 18:30
1.39
ng/L
0.50
01 /28/22 16:03
0.30
mg/L
0.040
01 /27/22 13:27
56.3
ug/L
10.0
01 /25/22 18:45
1.06
ng/L
0.50
01 /28/22 16:18
0.078
ug/L
0.025
01 /26/22 17:49
0.53
mg/L
0.040
01 /27/22 13:28
49.4
ug/L
10.0
01 /25/22 20:17
0.685
ng/L
0.50
01 /28/22 16:26
0.093
ug/L
0.025
01 /26/22 18:05
0.53
mg/L
0.040
01 /27/22 13:29
1980
ug/L 10.0 01 /25/22 19:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Lab Sample ID Client Sample ID
Method Parameters
92584118009
EPA 1631 E
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584118010
RSK 175 Modified
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584118011
RSK 175 Modified
EPA 1631 E
92584118012
RSK 175 Modified
EPA 1631 E
EPA 1631 E
92584118013
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584118014
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584118015
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584118016
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
SW-5-Al
Mercury
Mercury, Dissolved
Nitrogen, NO2 plus NO3
SW-5-Al
Methane
Mercury
Nitrogen, NO2 plus NO3
SW-6-Al
Methane
Mercury
SW-6-Al
Methane
Mercury
Mercury, Dissolved
SW-8-Al
Methane
Mercury
Mercury, Dissolved
Nitrogen, NO2 plus NO3
SW-8-Al
Methane
Mercury
Mercury, Dissolved
Nitrogen, NO2 plus NO3
SW-9-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-9-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
1.27
ng/L
0.50
01 /28/22 16:34
0.632
ng/L
0.50
01 /27/22 15:19
0.14
mg/L
0.040
01 /27/22 13:31
1930
ug/L
10.0
01 /25/22 20:47
1.23
ng/L
0.50
01 /28/22 16:42
0.13
mg/L
0.040
01 /27/22 13:32
464
ug/L
10.0
01 /25/22 21:02
1.25
ng/L
0.50
01 /28/22 16:50
581
ug/L
10.0
01 /25/22 21:18
2.94
ng/L
0.50
01 /28/22 17:13
1.05
ng/L
0.50
01 /27/22 16:13
9570
ug/L
10.0
01 /25/22 21:33
2.50
ng/L
0.50
01 /28/22 17:21
0.907
ng/L
0.50
01 /27/22 16:21
0.093
mg/L
0.040
01 /27/22 13:42 M 1
10500
ug/L
10.0
01 /25/22 21:48
2.12
ng/L
0.50
01 /28/22 17:29
1.78
ng/L
0.50
01 /27/22 16:28
0.092
mg/L
0.040
01 /27/22 13:45
39.0
ug/L
10.0
01 /25/22 22:04
2.30
ng/L
0.50
01 /28/22 17:36
2.03
ng/L
0.50
01 /27/22 16:36
0.038
ug/L
0.025
01 /26/22 21:54
2.0
mg/L
0.040
01 /27/22 13:46
31.4
ug/L
10.0
01 /25/22 22:19
2.25
ng/L
0.50
01 /28/22 17:44
2.56
ng/L
0.50
01 /27/22 16:44
0.036
ug/L
0.025
01 /26/22 22:11
2.0
mg/L
0.040
01 /27/22 13:47
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Method: RSK 175 Modified
Description: RSK 175 Headspace
Client: Duke Energy
Date: January 31, 2022
General Information:
16 samples were analyzed for RSK 175 Modified by Pace Analytical Services Charlotte. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Method: EPA 1631 E
Description: 1631 E Mercury,Low Level
Client: Duke Energy
Date: January 31, 2022
General Information:
17 samples were analyzed for EPA 1631 E by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 1631 E with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Method: EPA 1631 E
Description: 1631 E Mercury,LL Lab Filtered
Client: Duke Energy
Date: January 31, 2022
General Information:
16 samples were analyzed for EPA 1631 E by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 1631 E with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Method: SM 4500-S2D-2011
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: January 31, 2022
General Information:
16 samples were analyzed for SM 4500-S2D-2011 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 673561
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92583914002,92583914009
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3525673)
• Sulfide
• MSD (Lab ID: 3525674)
• Sulfide
QC Batch: 673862
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92584186002,92584186004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3527135)
• Sulfide
R1: RPD value was outside control limits.
• MSD (Lab ID: 3527136)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Method: EPA 218.7 Rev 1.0 2011
Description: 218.7 Chromium, Hexavalent
Client: Duke Energy
Date: January 31, 2022
General Information:
16 samples were analyzed for EPA 218.7 Rev 1.0 2011 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Method: EPA 353.2 Rev 2.0 1993
Description: 353.2 Nitrogen, NO2/NO3 pres.
Client: Duke Energy
Date: January 31, 2022
General Information:
16 samples were analyzed for EPA 353.2 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 674175
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92584118012,92584118013
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 3528590)
• Nitrogen, NO2 plus NO3
• MS (Lab ID: 3528592)
• Nitrogen, NO2 plus NO3
• MSD (Lab ID: 3528591)
• Nitrogen, NO2 plus NO3
• MSD (Lab ID: 3528593)
• Nitrogen, NO2 plus NO3
Additional Comments:
Batch accepted based on laboratory control sample (LCS) recovery.
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-2-Al Lab ID: 92584118001 Collected: 01/24/22 14:35 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
22.3 ug/L 10.0
1
01/25/2216:58 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.43 ng/L 0.50
1 01/27/2214:48
01/28/2215:08 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.20 ng/L 0.50
1 01/25/2213:10
01/27/2214:01 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:30 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.063 ug/L 0.025
1
01/26/2214:16 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
2.0 mg/L 0.040
1
01/27/2213:19
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-2-Al Lab ID: 92584118002 Collected: 01/24/22 14:50 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
28.6 ug/L 10.0
1
01/25/2217:29 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.73 ng/L 0.50
1 01/27/2214:48
01/28/2215:32 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.43 ng/L 0.50
1 01/25/2213:10
01/27/2214:24 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:30 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.073 ug/L 0.025
1
01/26/2216:27 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
2.0 mg/L 0.040
1
01/27/2213:20
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-3-Al Lab ID: 92584118003 Collected: 01/24/22 11:35 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
10.7 ug/L 10.0
1
01/25/2217:44 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.73 ng/L 0.50
1 01/27/2214:48
01/28/2215:40 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.767 ng/L 0.50
1 01/25/2213:10
01/27/2214:32 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:31 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.045 ug/L 0.025
1
01/26/2216:43 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
1.1 mg/L 0.040
1
01/27/2213:22
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-3-Al Lab ID: 92584118004 Collected: 01/24/22 11:45 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
ND ug/L 10.0
1
01/25/2217:59 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.948 ng/L 0.50
1 01/27/2214:48
01/28/2215:47 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.811 ng/L 0.50
1 01/25/2213:10
01/27/2214:40 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:32 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.058 ug/L 0.025
1
01/26/2217:00 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
1.1 mg/L 0.040
1
01/27/2213:23
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-413-A1 Lab ID: 92584118005 Collected: 01/24/22 10:15 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
38.0 ug/L 10.0
1
01/25/2218:15 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.636 ng/L 0.50
1 01/27/2214:48
01/28/2215:55 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/25/2213:10
01/27/2214:47 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:32 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/2217:16 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.31 mg/L 0.040
1
01/27/2213:24
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-413-A1 Lab ID: 92584118006 Collected: 01/24/22 10:25 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
36.4 ug/L 10.0
1
01/25/2218:30 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.39 ng/L 0.50
1 01/27/2214:48
01/28/2216:03 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/25/2213:10
01/27/2214:55 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:33 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/2217:32 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.30 mg/L 0.040
1
01/27/2213:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-4C-A1 Lab ID: 92584118007 Collected: 01/24/22 10:45 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
56.3 ug/L 10.0
1
01/25/2218:45 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.06 ng/L 0.50
1 01/27/2214:48
01/28/2216:18 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/25/2213:10
01/27/2215:03 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:33 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.078 ug/L 0.025
1
01/26/2217:49 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.53 mg/L 0.040
1
01/27/2213:28
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
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Huntersville, NC 28078
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-4C-A1 Lab ID: 92584118008 Collected: 01/24/22 10:55 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
49.4 ug/L 10.0
1
01/25/22 20:17 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.685 ng/L 0.50
1 01/27/2214:48
01/28/2216:26 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/25/2213:10
01/27/2215:11 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:34 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.093 ug/L 0.025
1
01/26/2218:05 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.53 mg/L 0.040
1
01/27/2213:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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leAnalyiical
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Pace Ag ig6$prvices, LLC
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-5-Al Lab ID: 92584118009 Collected: 01/24/22 12:15 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
1980 ug/L 10.0
1
01/25/2219:00 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.27 ng/L 0.50
1 01/27/2214:48
01/28/2216:34 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.632 ng/L 0.50
1 01/25/2213:10
01/27/2215:19 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/25/22 05:34 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/2218:21 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.14 mg/L 0.040
1
01/27/2213:31
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 23 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-5-Al Lab ID: 92584118010 Collected: 01/24/22 12:30 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
1930 ug/L 10.0
1
01/25/22 20:47 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.23 ng/L 0.50
1 01/27/2214:48
01/28/2216:42 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/25/2213:10
01/27/2215:42 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:27 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/2218:38 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.13 mg/L 0.040
1
01/27/2213:32
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
P36906irwy IIo``��e. Suite 100
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-6-Al Lab ID: 92584118011 Collected: 01/24/22 13:30 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
464 ug/L 10.0
1
01/25/22 21:02 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.25 ng/L 0.50
1 01/27/2214:48
01/28/2216:50 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/25/2213:10
01/27/2215:50 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:27 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/22 20:16 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.040
1
01/27/2213:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
P36906irwy IIo``��e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-6-Al Lab ID: 92584118012 Collected: 01/24/22 13:45 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
581 ug/L 10.0
1
01/25/22 21:18 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.94 ng/L 0.50
1 01/27/2214:48
01/28/2217:13 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.05 ng/L 0.50
1 01/25/2213:10
01/27/2216:13 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:28 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/22 21:05 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.040
1
01/27/2213:36 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 49

leAnalyiical
www.pacelabs.com
Pace Ag ig6$prvices, LLC
�J
P3B9C4irwY IIo``��e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-8-Al Lab ID: 92584118013 Collected: 01/24/22 12:50 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
9570 ug/L 10.0
1
01/25/22 21:33 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.50 ng/L 0.50
1 01/27/2214:48
01/28/2217:21 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.907 ng/L 0.50
1 01/25/2213:10
01/27/2216:21 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:28 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/22 21:21 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.093 mg/L 0.040
1
01/27/2213:42 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
�J
P3B90rwY IIo``��e. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-8-Al Lab ID: 92584118014 Collected: 01/24/22 13:10 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
10500 ug/L 10.0
1
01/25/22 21:48 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.12 ng/L 0.50
1 01/27/2214:48
01/28/2217:29 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.78 ng/L 0.50
1 01/25/2213:10
01/27/2216:28 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:29 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/26/22 21:38 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.092 mg/L 0.040
1
01/27/2213:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
Pdagvirwy IIo``��e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-9-Al Lab ID: 92584118015 Collected: 01/24/22 09:45 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
39.0 ug/L 10.0
1
01/25/22 22:04 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.30 ng/L 0.50
1 01/27/2214:48
01/28/2217:36 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.03 ng/L 0.50
1 01/25/2213:10
01/27/2216:36 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:29 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.038 ug/L 0.025
1
01/26/22 21:54 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
2.0 mg/L 0.040
1
01/27/2213:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 29 of 49

leAnalyiical
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Pace Ag ig6$prvices, LLC
Pdago irwy IIo``��e. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: SW-9-Al Lab ID: 92584118016 Collected: 01/24/22 10:00 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S21) Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 01/31/2022 03:40 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
31.4 ug/L 10.0
1
01/25/22 22:19 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.25 ng/L 0.50
1 01/27/2214:48
01/28/2217:44 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
2.56 ng/L 0.50
1 01/25/2213:10
01/27/2216:44 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
01/26/22 03:30 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.036 ug/L 0.025
1
01/26/22 22:11 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
2.0 mg/L 0.040
1
01/27/2213:47
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 30 of 49

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Pace Ap igf6$prvices, LLC
Pdagvirwy IIo``��e. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Sample: ASA_FB-20220124-1405 Lab ID: 92584118017 Collected: 01/24/22 14:05 Received: 01/24/22 16:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
Mercury ND ng/L 0.50 1 01/27/2214:48 01/28/2214:53 7439-97-6
Date: 01/31/2022 03:40 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 673785 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
METHOD BLANK: 3526765 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Methane ug/L ND 10.0 01/25/2215:57
LABORATORY CONTROL SAMPLE: 3526766
Parameter Units
Methane ug/L
MATRIX SPIKE SAMPLE: 3528103
Parameter Units
Methane ug/L
Spike LCS LCS
Conc. Result % Rec
396 344 87
92584118002 Spike MS
Result Conc. Result
28.6 396 418
SAMPLE DUPLICATE: 3528102
92584118001 Dup
Parameter Units Result Result
Methane ug/L 22.3 21.8
SAMPLE DUPLICATE: 3528104
92584118008 Dup
Parameter Units Result Result
Methane ug/L 49.4 53.5
% Rec
Limits Qualifiers
70-130
MS % Rec
% Rec Limits Qualifiers
98 70-130
Max
RPD RPD Qualifiers
2 20
Max
RPD RPD Qualifiers
8 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2022 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 49

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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 674322 Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016,92584118017
METHOD BLANK: 3529354 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016,92584118017
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/28/2214:37
METHOD BLANK: 3529355 Matrix: Water
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016,92584118017
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/28/2215:01
METHOD BLANK: 3529356 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016,92584118017
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/28/2217:52
LABORATORY CONTROL SAMPLE: 3529357
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ng/L 5 5.02 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3529358 3529359
MS MSD
92584118001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ng/L 2.43 25 25 28.5 27.9 104 102 71-125 2 24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2022 03:40 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3529360 3529361
MS MSD
92584118002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ng/L 2.73 25 25 27.1 27.2 97 98 71-125 0 24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 673715 Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E Analysis Description: 1631E Mercury, Dissolved Low Level
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
METHOD BLANK: 3526449 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury, Dissolved ng/L ND 0.50 01/27/22 13:45
METHOD BLANK: 3526450 Matrix: Water
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury, Dissolved ng/L ND 0.50 01/27/22 15:26
METHOD BLANK: 3526451 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury, Dissolved ng/L ND 0.50 01/27/22 16:52
LABORATORY CONTROL SAMPLE: 3526452
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury, Dissolved ng/L 5 4.82 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3526453 3526454
MS MSD
92584118001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury, Dissolved ng/L 1.20 25 25 26.2 25.8 100 98 71-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3526455 3526456
MS MSD
92584118002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury, Dissolved ng/L 1.43 25 25 29.4 29.6 112 113 71-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 673561 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009
METHOD BLANK: 3525669 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/25/22 05:19
LABORATORY CONTROL SAMPLE: 3525670
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L 0.5 0.52 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3525671 3525672
MS MSD
92583914002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.55 0.56 110 112 80-120 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3525673 3525674
MS MSD
92583914009 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.35 0.36 70 73 80-120 3 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 673862 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118010,92584118011,92584118012,92584118013,92584118014,92584118015,92584118016
METHOD BLANK: 3527133 Matrix: Water
Associated Lab Samples: 92584118010,92584118011,92584118012,92584118013,92584118014,92584118015,92584118016
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 01/26/22 03:21
LABORATORY CONTROL SAMPLE: 3527134
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L 0.5 0.51 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527135 3527136
MS MSD
92584186004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.40 0.45 73 85 80-120 14 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527137 3527138
MS MSD
92584186002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.53 0.53 102 103 80-120 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 673898 Analysis Method: EPA 218.7 Rev 1.0 2011
QC Batch Method: EPA 218.7 Rev 1.0 2011 Analysis Description: 218.7 Chromium, Hexavalent
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
METHOD BLANK: 3527200 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011,92584118012,92584118013,92584118014,
92584118015,92584118016
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.025 01/26/22 13:44
LABORATORY CONTROL SAMPLE: 3527201
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L 0.1 0.11 114 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527202 3527203
MS MSD
92584118001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 0.063 0.1 0.1 0.16 0.16 94 101 90-110 4 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527204 3527205
MS MSD
92584118011 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND 0.1 0.1 0.095 0.10 95 100 90-110 5 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2022 03:40 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 674174 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118001,92584118002,92584118003,92584118004,92584118005,92584118006,92584118007,
92584118008,92584118009,92584118010,92584118011
METHOD BLANK: 3528582 Matrix: Water
Associated Lab Samples: 92584118001, 92584118002, 92584118003, 92584118004, 92584118005, 92584118006, 92584118007,
92584118008,92584118009,92584118010,92584118011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L ND 0.040 01/27/22 12:59
LABORATORY CONTROL SAMPLE: 3528583
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.4 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3528586 3528587
MS MSD
92583548001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 11.9 2.5 2.5 14.2 14.2 92 90 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3528938 3528939
MS MSD
92583577004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.60 2.5 2.5 3.0 3.0 95 95 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2022 03:40 PM without the written consent of Pace Analytical Services, LLC.
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[phone]
QUALITY CONTROL DATA
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
QC Batch: 674175 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584118012, 92584118013, 92584118014, 92584118015, 92584118016
METHOD BLANK: 3528588
Matrix:
Water
Associated Lab Samples: 92584118012, 92584118013,
92584118014, 92584118015, 92584118016
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, NO2 plus NO3
mg/L
ND
0.040
01/27/22 13:34
LABORATORY CONTROL SAMPLE:
3528589
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, NO2 plus NO3
mg/L
2.5
2.4
98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3528590 3528591
MS MSD
92584118012 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.2 2.2 87 87 90-110 0 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3528592 3528593
MS MSD
92584118013 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.093 2.5 2.5 2.0 2.0 77 77 90-110 0 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92584118001
SW-2-Al
RSK 175
Modified
673785
92584118002
SW-2-Al
RSK 175
Modified
673785
92584118003
SW-3-Al
RSK 175
Modified
673785
92584118004
SW-3-Al
RSK 175
Modified
673785
92584118005
SW-4B-A1
RSK 175
Modified
673785
92584118006
SW-4B-A1
RSK 175
Modified
673785
92584118007
SW-4C-Al
RSK 175
Modified
673785
92584118008
SW-4C-Al
RSK 175
Modified
673785
92584118009
SW-5-Al
RSK 175
Modified
673785
92584118010
SW-5-Al
RSK 175
Modified
673785
92584118011
SW-6-Al
RSK 175
Modified
673785
92584118012
SW-6-Al
RSK 175
Modified
673785
92584118013
SW-8-Al
RSK 175
Modified
673785
92584118014
SW-8-Al
RSK 175
Modified
673785
92584118015
SW-9-Al
RSK 175
Modified
673785
92584118016
SW-9-Al
RSK 175
Modified
673785
92584118001
SW-2-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118002
SW-2-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118003
SW-3-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118004
SW-3-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118005
SW-4B-A1
EPA 1631 E
674322
EPA 1631 E
674615
92584118006
SW-4B-A1
EPA 1631 E
674322
EPA 1631 E
674615
92584118007
SW-4C-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118008
SW-4C-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118009
SW-5-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118010
SW-5-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118011
SW-6-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118012
SW-6-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118013
SW-8-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118014
SW-8-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118015
SW-9-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118016
SW-9-Al
EPA 1631 E
674322
EPA 1631 E
674615
92584118017
ASA FB-20220124-1405
EPA 1631 E
674322
EPA 1631 E
674615
92584118001
SW-2-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118002
SW-2-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118003
SW-3-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118004
SW-3-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118005
SW-4B-A1
EPA 1631 E
673715
EPA 1631 E
673911
92584118006
SW-4B-A1
EPA 1631 E
673715
EPA 1631 E
673911
92584118007
SW-4C-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118008
SW-4C-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118009
SW-5-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118010
SW-5-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118011
SW-6-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118012
SW-6-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118013
SW-8-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118014
SW-8-Al
EPA 1631 E
673715
EPA 1631 E
673911
92584118015
SW-9-Al
EPA 1631 E
673715
EPA 1631 E
673911
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 2L-2B SW J22010361
Pace Project No.: 92584118
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92584118016
SW-9-Al
EPA 1631 E
673715 EPA 1631 E 673911
92584118001
SW-2-Al
SM 4500-S2D-2011
673561
92584118002
SW-2-Al
SM 4500-S2D-2011
673561
92584118003
SW-3-Al
SM 4500-S2D-2011
673561
92584118004
SW-3-Al
SM 4500-S2D-2011
673561
92584118005
SW-4B-A1
SM 4500-S2D-2011
673561
92584118006
SW-4B-A1
SM 4500-S2D-2011
673561
92584118007
SW-4C-Al
SM 4500-S2D-2011
673561
92584118008
SW-4C-Al
SM 4500-S2D-2011
673561
92584118009
SW-5-Al
SM 4500-S2D-2011
673561
92584118010
SW-5-Al
SM 4500-S2D-2011
673862
92584118011
SW-6-Al
SM 4500-S2D-2011
673862
92584118012
SW-6-Al
SM 4500-S2D-2011
673862
92584118013
SW-8-Al
SM 4500-S2D-2011
673862
92584118014
SW-8-Al
SM 4500-S2D-2011
673862
92584118015
SW-9-Al
SM 4500-S2D-2011
673862
92584118016
SW-9-Al
SM 4500-S2D-2011
673862
92584118001
SW-2-Al
EPA 218.7
Rev 1.0 2011
673898
92584118002
SW-2-Al
EPA 218.7
Rev 1.0 2011
673898
92584118003
SW-3-Al
EPA 218.7
Rev 1.0 2011
673898
92584118004
SW-3-Al
EPA 218.7
Rev 1.0 2011
673898
92584118005
SW-4B-A1
EPA 218.7
Rev 1.0 2011
673898
92584118006
SW-4B-A1
EPA 218.7
Rev 1.0 2011
673898
92584118007
SW-4C-Al
EPA 218.7
Rev 1.0 2011
673898
92584118008
SW-4C-Al
EPA 218.7
Rev 1.0 2011
673898
92584118009
SW-5-Al
EPA 218.7
Rev 1.0 2011
673898
92584118010
SW-5-Al
EPA 218.7
Rev 1.0 2011
673898
92584118011
SW-6-Al
EPA 218.7
Rev 1.0 2011
673898
92584118012
SW-6-Al
EPA 218.7
Rev 1.0 2011
673898
92584118013
SW-8-Al
EPA 218.7
Rev 1.0 2011
673898
92584118014
SW-8-Al
EPA 218.7
Rev 1.0 2011
673898
92584118015
SW-9-Al
EPA 218.7
Rev 1.0 2011
673898
92584118016
SW-9-Al
EPA 218.7
Rev 1.0 2011
673898
92584118001
SW-2-Al
EPA 353.2
Rev 2.0 1993
674174
92584118002
SW-2-Al
EPA 353.2
Rev 2.0 1993
674174
92584118003
SW-3-Al
EPA 353.2
Rev 2.0 1993
674174
92584118004
SW-3-Al
EPA 353.2
Rev 2.0 1993
674174
92584118005
SW-4B-A1
EPA 353.2
Rev 2.0 1993
674174
92584118006
SW-4B-A1
EPA 353.2
Rev 2.0 1993
674174
92584118007
SW-4C-Al
EPA 353.2
Rev 2.0 1993
674174
92584118008
SW-4C-Al
EPA 353.2
Rev 2.0 1993
674174
92584118009
SW-5-Al
EPA 353.2
Rev 2.0 1993
674174
92584118010
SW-5-Al
EPA 353.2
Rev 2.0 1993
674174
92584118011
SW-6-Al
EPA 353.2
Rev 2.0 1993
674174
92584118012
SW-6-Al
EPA 353.2
Rev 2.0 1993
674175
92584118013
SW-8-Al
EPA 353.2
Rev 2.0 1993
674175
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2022 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 49

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 21--213 SW J22010361
Pace Project No.: 92584118
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
92584118014
SW-8-Al
EPA 353.2 Rev 2.0 1993
674175
92584118015
SW-9-Al
EPA 353.2 Rev 2.0 1993
674175
92584118016
SW-9-Al
EPA 353.2 Rev 2.0 1993
674175
Date: 01/31/2022 03:40 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 45 of 49

REVISION
Page 113 of 151
Laboratory racelving samples:
Ash evllleP Eden[] Greenwood ❑ Huntersville D WOOD Mechanicsville[] Atlanta.[] Kernersville❑
GlientName: Protect#:Wp# : 92584118
• �
Courier: ❑Fed Ex ❑UP5 ❑LISPS Client 1111111111111111111111
[]cam-mercial ❑€pace ❑other:
92584118
Custody Seal Present? []Yes 00 Seals Intact? []Yes [�No /
Date/Initials Person Examining Contents
packing 11/faterialt ❑Subbie-Wrap 4ubbre Bags []None ❑ Other 9lologicalTi5sue frozen?
Ther--m n6t r: QYes []No 7NIA
IRGun 1p: Fype of �%�j ( Ice!,�Wc[ [�&rue ❑None
—1-"--�
f/] Correction Factor:
Cooler 7es np: — Rdci/Subtract ('C4 7efnp s uid be above freezing to 6'C
/ �/ 5a mples cut of ternp crlterla. Samples on ice, coaling process
Cooler {'Cj: / �� 'C� as begun
LJSDA Regulated Soil (0 ,�i/A, water sample)
cmd samples orlainate Xa quarantine tone WkNn the United States: CA, NY,,or SC (dieck lnapsl? Did samples orfglnate from a foreign source linternatlonally,
mync 1 INCI fnrlilr{fna.Haw it an ri'Pirarin RI-0 MY— fiNn'
Comm ents/ Discrepancy:
ent?
:hair[ of Custojwit�h�l,.n
es
UND
❑NIA
1.
Samizles ArriveHold Time?
Yes
❑No
©N/AShort
Hold Time Ansijls (02 hr.)?
❑Yes
oft
[]NIA
3.
Rush Turn Around Tim Re uested?
❑Yes
Fla
❑NJA
4.
Sufficient Volume?
Yes
❑N.
❑N/A
S..
corrpetContalners Used?
-Pace CoritalneM Used?
4*1
k1YES
[:IN*
❑N❑
❑N/A
ON/a,
G.
ColitainersIntact?
oVeS
LINO
❑N/A
7.
pfssotved anafysls: 5arr lea field riitered7
Yes
Zrqo
[].i/A
8.
SarnpreLabelsiVatch CDC? ZYes
-In6udesrlate/T1Fn00/Analysis tvlatrlx:, A
❑Na
[]NIA
9.
Heads pace In V0AV/ als(s5•Smm)?
Yes-
No
El
10.
Trip Biank Present?
Trip 61ank Custody Seals Present?
©Yes
[]Yes _
0,4o
RjNo
[)N/A
[)NIA
11.
COMMENTS/SAMPLE DISCREPANCY Field Data Sequired? ❑Yes ©No
Lot ID of split containers:
CLIENT NOrtIfICATIDNIRESGLUT rON
Person contacted:
DateMrne:
Project Manager SCURF Review;
Date:
Project Manager SRC Review: bate: Page 46 of 49

REVISION
Page 114 of 151
bocurment Name;
bocum4�nt Revlied: Noverrtber151 zpri_
Sample Condltfon upon Receipt (SLUR)
Page 2 of Z
Document Na.:
rssuing Authority:
ceAnaly�reaf
F•CAR-CS•Q33-iteV.t}8
Pace Carolinas Quality 001ce
`fhea k murk top half of box if pH and/or dech(r dhation Is project g
verlfTed and within the acceptance range for preservation
sarr�pl es:
Eecepticnns. VOA, C-oliform, TOC, Clfi and 3rease, ORa/8015 (water) 06C,. LLHg
`*Bot-torn half of box Is to list number of bottles
rWO#:92584118
Due Date: 01/31/22
92—Duke Ener
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PH Adjustment
Log for preserved Samples
sample 11)
Type of Preservative
p!1 up on receipt
Date preservatlon adjusted
Time presergtlon
adjusted
Amount of Preservative
added
Lot ff
Note: Whenaver there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to thr North Carolina OEHNR Cerlifiratlun Office ri.e.
out of hold, incof-re6t preservative, out of temo, IncorrQct containers.
Page 47 of 49

REVISION
Page 115 of 151
Document Harm;: Document Reylsed: Ngvember 15, 2021.
tditton Upon Resel t ($CUR) Page Zof, 2
f eument Nb.: issuing Authority:
CAR-CS-03-RAv48 Pace Ca roll rtas Qua lily Office
'Eheck mark top half of box if pH and/or dechtotihattan is Piojectfl�O� . 925841 � 8
verified and within the acceptance range for preservatton
same[ es:
htept10ns: VOA, Collf arm, TEX, Oil and crease, pRt1/9p15 (water) ROC, L.LHg
`'3ot-torn half of box Is to fist number of bottles
PM: NMG Due Date: 01/31/22
CLIENT: 92—Duke Ener
y
¢
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sample iO
Type of Preservative
ph upon recerpt
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tirne preservation
adjuster!
Amount of Preservative
added
Let #
Nate: whenever there is a discrepanty atteenng North cerouna compliance samp�es, a copy or tnls rorm will oe sent romp ryarcn Laruuna ucn,yn L@raziGa[Ipn caste ii.e.
put of hold, incorrect preservative, act of temp, incorrect containers.
Page 48 of 49

REVISION
DUKE Duke Energy Analylicat Labaratnry
•' LJ rda rae. Meaeu Ie,�.X�nc�,asr
P ENERGY,. �""" M"""R"
N�eta}0 X. C, urra
pY) n:.af+b
6EE 0`13MEN, JOSH STOVJV- SYNfERRA -.
Opetatierg Unit AE00 Pnacwes: BENVWS Aecaunt
Project: Actwity ID: FaciRly Ip; ASA
`-IJWPLE Iq i
Sample Desedption or ID
i NUMBER i
Asa
ASAy
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AASA
AA
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PACE
CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Cuatornorto rorirplera a!t ypprvpn°afo nPnaJradad ■
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brinkin0 Water_ LIST
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b
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k:Z uoc M014E
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Container Volume (010
40 250 250 250 250 ..
Container Type
CLAD PET GLASS HDPE HOVE
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Page 116 of 151 v
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Add Cost Will Apply

leAnalyiical
www.pacelabs.com
Pace ,pfy igf6$prvices, LLC
Padgomwey IIo``��e. Suite 100
Huntersville, NC 28078
[phone]
February 03, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J22010361 ASA 21L213
Pace Project No.: 92584367
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 25, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 33

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[phone]
CERTIFICATIONS
Project: J22010361 ASA 21-213
Pace Project No.: 92584367
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 33

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SAMPLE SUMMARY
Project: J22010361 ASA 2L2B
Pace Project No.: 92584367
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92584367001
SW-2-Al
Water
01/24/22 14:35
01/25/22 14:55
92584367002
SW-2-Al
Water
01/24/22 14:50
01/25/22 14:55
92584367003
SW-3-Al
Water
01/24/2211:35
01/25/22 14:55
92584367004
SW-3-Al
Water
01/24/2211:45
01/25/22 14:55
92584367005
SW-413-A1
Water
01/24/2210:15
01/25/22 14:55
92584367006
SW-413-A1
Water
01/24/2210:25
01/25/22 14:55
92584367007
SW-4C-A1
Water
01/24/2210:45
01/25/22 14:55
92584367008
SW-4C-A1
Water
01/24/2210:55
01/25/22 14:55
92584367009
SW-5-Al
Water
01/24/2212:15
01/25/22 14:55
92584367010
SW-5-Al
Water
01/24/22 12:30
01/25/22 14:55
92584367011
SW-6-Al
Water
01/24/22 13:30
01/25/22 14:55
92584367012
SW-6-Al
Water
01/24/2213:45
01/25/22 14:55
92584367013
SW-8-Al
Water
01/24/22 12:50
01/25/22 14:55
92584367014
SW-8-Al
Water
01/24/2213:10
01/25/22 14:55
92584367015
SW-9-Al
Water
01/24/22 09:45
01/25/22 14:55
92584367016
SW-9-Al
Water
01/24/22 10:00
01/25/22 14:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 33

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[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J22010361 ASA 21-213
92584367
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92584367001
SW-2-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367002
SW-2-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367003
SW-3-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367004
SW-3-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367005
SW-413-A1
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367006
SW-413-A1
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367007
SW-4C-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367008
SW-4C-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367009
SW-5-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367010
SW-5-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367011
SW-6-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367012
SW-6-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367013
SW-8-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367014
SW-8-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367015
SW-9-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
92584367016
SW-9-Al
SM 2540C-2015
ZMC
1
PASI-A
SM 2540D-2011
MAB2
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 33

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[phone]
Project: J22010361 ASA 21-213
Pace Project No.: 92584367
Lab Sample ID
Method
Client Sample ID
Parameters
92584367001
SW-2-Al
SM 2540C-2015
Total Dissolved Solids
92584367002
SW-2-Al
SM 2540C-2015
Total Dissolved Solids
92584367003
SW-3-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367004
SW-3-Al
SM 2540C-2015
Total Dissolved Solids
92584367005
SW-46-All
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367006
SW-46-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367007
SW-4C-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367008
SW-4C-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367009
SW-5-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367010
SW-5-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367011
SW-6-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367012
SW-6-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367013
SW-8-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92584367014
SW-8-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
65.0
mg/L
25.0
01 /26/22 15:25
65.0
mg/L
25.0
01 /26/22 15:25
78.0
mg/L
25.0
01 /26/22 15:25
1.2
mg/L
1.0
01 /29/22 12:10
81.0
mg/L
25.0
01 /26/22 15:25
59.0
mg/L
25.0
01 /26/22 15:25
4.6
mg/L
1.0
01 /29/22 12:10
59.0
mg/L
25.0
01 /26/22 15:25
2.6
mg/L
1.0
01 /29/22 12:10
41.0
mg/L
25.0
01 /26/22 15:25
7.4
mg/L
1.0
01 /29/22 12:10
50.0
mg/L
25.0
01 /26/22 15:25
3.0
mg/L
1.0
01 /29/22 12:11
136
mg/L
25.0
01 /26/22 15:25
28.2
mg/L
2.0
01 /29/22 12:11
139
mg/L
25.0
01 /27/22 15:28
55.6
mg/L
4.0
01 /29/22 12:11
52.0
mg/L
25.0
01 /27/22 15:28
25.2
mg/L
4.0
01 /29/22 12:11
54.0
mg/L
25.0
01 /27/22 15:28
11.0
mg/L
2.0
01 /29/22 12:12
492
mg/L
50.0
01 /27/22 15:30
49.6
mg/L
4.0
01 /29/22 12:12
476
mg/L
50.0
01 /27/22 15:30
37.2
mg/L
4.0
01 /29/22 12:12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qualifiers
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SUMMARY OF DETECTION
Project: J22010361 ASA 21-213
Pace Project No.: 92584367
Lab Sample ID Client Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
92584367015 SW-9-Al
SM 2540C-2015 Total Dissolved Solids 81.0 mg/L 25.0 01/27/22 15:30
92584367016 SW-9-Al
SM 2540C-2015 Total Dissolved Solids 81.0 mg/L 25.0 01/27/22 15:30
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Method: SM 2540C-2015
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: February 03, 2022
General Information:
16 samples were analyzed for SM 2540C-2015 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Method: SM 2540D-2011
Description: 2540D TSS, Low -Level
Client: Duke Energy
Date: February 03, 2022
General Information:
16 samples were analyzed for SM 2540D-2011 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-2-Al
Parameters
Lab ID: 92584367001 Collected:
Report
Results Units Limit
01/24/22 14:35
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
65.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
01/29/22 12:09
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-2-Al
Parameters
Lab ID: 92584367002 Collected:
Report
Results Units Limit
01/24/22 14:50
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
65.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
01/29/22 12:09
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-3-Al
Parameters
Lab ID: 92584367003 Collected:
Report
Results Units Limit
01/24/22 11:35
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
78.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
1.2 mg/L 1.0
1.0 1
01/29/22 12:10
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-3-Al
Parameters
Lab ID: 92584367004 Collected:
Report
Results Units Limit
01/24/22 11:45
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
81.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
01/29/22 12:10
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-413-A1
Parameters
Lab ID: 92584367005 Collected:
Report
Results Units Limit
01/24/22 10:15
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
59.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
4.6 mg/L 1.0
1.0 1
01/29/22 12:10
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-413-A1
Parameters
Lab ID: 92584367006 Collected:
Report
Results Units Limit
01/24/22 10:25
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
59.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
2.6 mg/L 1.0
1.0 1
01/29/22 12:10
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-4C-Al
Parameters
Lab ID: 92584367007 Collected:
Report
Results Units Limit
01/24/22 10:45
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
41.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
7.4 mg/L 1.0
1.0 1
01/29/22 12:10
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-4C-Al
Parameters
Lab ID: 92584367008 Collected:
Report
Results Units Limit
01/24/22 10:55
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
50.0 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
3.0 mg/L 1.0
1.0 1
01/29/22 12:11
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-5-Al
Parameters
Lab ID: 92584367009 Collected:
Report
Results Units Limit
01/24/22 12:15
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
136 mg/L 25.0
25.0 1
01/26/22 15:25
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
28.2 mg/L 2.0
2.0 1
01/29/22 12:11
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-5-Al
Parameters
Lab ID: 92584367010 Collected:
Report
Results Units Limit
01/24/22 12:30
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
139 mg/L 25.0
25.0 1
01/27/22 15:28
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
55.6 mg/L 4.0
4.0 1
01/29/22 12:11
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-6-Al
Parameters
Lab ID: 92584367011 Collected:
Report
Results Units Limit
01/24/22 13:30
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
52.0 mg/L 25.0
25.0 1
01/27/22 15:28
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
25.2 mg/L 4.0
4.0 1
01/29/22 12:11
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-6-Al
Parameters
Lab ID: 92584367012 Collected:
Report
Results Units Limit
01/24/22 13:45
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
54.0 mg/L 25.0
25.0 1
01/27/22 15:28
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
11.0 mg/L 2.0
2.0 1
01/29/22 12:12
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-8-Al
Parameters
Lab ID: 92584367013 Collected:
Report
Results Units Limit
01/24/22 12:50
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
492 mg/L 50.0
50.0 1
01/27/22 15:30
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
49.6 mg/L 4.0
4.0 1
01/29/22 12:12
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-8-Al
Parameters
Lab ID: 92584367014 Collected:
Report
Results Units Limit
01/24/22 13:10
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
476 mg/L 50.0
50.0 1
01/27/22 15:30
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
37.2 mg/L 4.0
4.0 1
01/29/22 12:12
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-9-Al
Parameters
Lab ID: 92584367015 Collected:
Report
Results Units Limit
01/24/22 09:45
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
81.0 mg/L 25.0
25.0 1
01/27/22 15:30
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
01/29/22 12:13
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
Sample: SW-9-Al
Parameters
Lab ID: 92584367016 Collected:
Report
Results Units Limit
01/24/22 10:00
MDL DF
Received: 01/25/22 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
81.0 mg/L 25.0
25.0 1
01/27/22 15:30
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
01/29/22 12:13
Date: 02/03/2022 11:23 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
QC Batch: 673845 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584367001, 92584367002, 92584367003, 92584367004, 92584367005, 92584367006, 92584367007,
92584367008,92584367009
METHOD BLANK: 3527092 Matrix: Water
Associated Lab Samples: 92584367001, 92584367002, 92584367003, 92584367004, 92584367005, 92584367006, 92584367007,
92584367008,92584367009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 01/26/22 15:23
LABORATORY CONTROL SAMPLE:
3527093
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
236 94
90-110
SAMPLE DUPLICATE: 3527094
92584200019
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
2700
2480
8 25
SAMPLE DUPLICATE: 3527095
92584212001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
8690
8830
2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2022 11:23 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 33

leAnalyiical
www.pacelabs.com
Pace ,pfy igf6$prvices, LLC
PadgoM� Y IIO``��e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
QC Batch: 674137 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584367010, 92584367011, 92584367012, 92584367013, 92584367014, 92584367015, 92584367016
METHOD BLANK: 3528505
Matrix:
Water
Associated Lab Samples: 92584367010, 92584367011,
92584367012, 92584367013, 92584367014, 92584367015, 92584367016
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
25.0 01/27/22 15:28
LABORATORY CONTROL SAMPLE:
3528506
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
260 104
90-110
SAMPLE DUPLICATE: 3528507
92584367010 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 139 137 1 25
SAMPLE DUPLICATE: 3528508
92584401004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 1800 1830 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2022 11:23 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 33

leAnalyiical
www.pacelabs.com
Pace ,pfy igf6$prvices, LLC
PadgoM� Y IIO``��e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
QC Batch: 674788 Analysis Method: SM 2540D-2011
QC Batch Method: SM 2540D-2011 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584367001, 92584367002, 92584367003, 92584367004, 92584367005, 92584367006, 92584367007,
92584367008,92584367009,92584367010,92584367011,92584367012,92584367013,92584367014,
92584367015,92584367016
METHOD BLANK: 3531948 Matrix: Water
Associated Lab Samples: 92584367001, 92584367002, 92584367003, 92584367004, 92584367005, 92584367006, 92584367007,
92584367008,92584367009,92584367010,92584367011,92584367012,92584367013,92584367014,
92584367015,92584367016
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Suspended Solids mg/L ND 1.0 1.0 01/29/22 12:08
LABORATORY CONTROL SAMPLE: 3531949
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Suspended Solids mg/L 250 244 98 90-110
SAMPLE DUPLICATE: 3531977
92584320002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Suspended Solids mg/L 320 306 4 10
SAMPLE DUPLICATE: 3531978
92584908004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Suspended Solids mg/L 980 967 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2022 11:23 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 33

leAnalyiical
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Pace ,pfy igf6$prvices, LLC
Pa880P4Wr6fY IIO``��e. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J22010361 ASA 21_213
Pace Project No.: 92584367
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2022 11:23 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 33

leAnalyiical
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Pace ,pfy igf6$prvices, LLC
PadgOP4�WeY IIO``��e. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J22010361 ASA 2L2B
Pace Project No.: 92584367
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92584367001
SW-2-Al
SM
2540C-2015
673845
92584367002
SW-2-Al
SM
2540C-2015
673845
92584367003
SW-3-Al
SM
2540C-2015
673845
92584367004
SW-3-Al
SM
2540C-2015
673845
92584367005
SW-4B-A1
SM
2540C-2015
673845
92584367006
SW-4B-A1
SM
2540C-2015
673845
92584367007
SW-4C-Al
SM
2540C-2015
673845
92584367008
SW-4C-Al
SM
2540C-2015
673845
92584367009
SW-5-Al
SM
2540C-2015
673845
92584367010
SW-5-Al
SM
2540C-2015
674137
92584367011
SW-6-Al
SM
2540C-2015
674137
92584367012
SW-6-Al
SM
2540C-2015
674137
92584367013
SW-8-Al
SM
2540C-2015
674137
92584367014
SW-8-Al
SM
2540C-2015
674137
92584367015
SW-9-Al
SM
2540C-2015
674137
92584367016
SW-9-Al
SM
2540C-2015
674137
92584367001
SW-2-Al
SM
2540D-2011
674788
92584367002
SW-2-Al
SM
2540D-2011
674788
92584367003
SW-3-Al
SM
2540D-2011
674788
92584367004
SW-3-Al
SM
2540D-2011
674788
92584367005
SW-4B-A1
SM
2540D-2011
674788
92584367006
SW-4B-A1
SM
2540D-2011
674788
92584367007
SW-4C-Al
SM
2540D-2011
674788
92584367008
SW-4C-Al
SM
2540D-2011
674788
92584367009
SW-5-Al
SM
2540D-2011
674788
92584367010
SW-5-Al
SM
2540D-2011
674788
92584367011
SW-6-Al
SM
2540D-2011
674788
92584367012
SW-6-Al
SM
2540D-2011
674788
92584367013
SW-8-Al
SM
2540D-2011
674788
92584367014
SW-8-Al
SM
2540D-2011
674788
92584367015
SW-9-Al
SM
2540D-2011
674788
92584367016
SW-9-Al
SM
2540D-2011
674788
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2022 11:23 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 33

REVISION
151
Document Name:
Document Revised: November 1 , 2021
n
acaAr�afytical
Sample Condition Upon Receipt (SCUR)
Pagel of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.08
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
ConditionSample Client fume:
Upon Receipt D U. _ if, Project P:wo# 9258436
t:a Pace x ❑UPS EIUSPS❑Other: []Client III 1111111111111111111
❑ commercial
Custody Seal Present? ❑Yes E3JNo Seals Intact? ❑Yes Q o 92584367 _
Date/Initials Person Examining Contents: 1 `Z 15 ` Z mp
Packing Material: ❑Bubble Wrap ❑Bubble Bags [None ❑ Other Biological Tissue Frozen?
Thermometer: det ❑Blue ❑None ❑Yes []No ON/A
0111 Gun ID: �i2�Q(aL
Type of Ice:
Correction factor:
Cooler Temp: -� �' Add/Subtract (•C) U Temp should be above freezing to 6•C
Eoaler-Temp-Carrected �` >_ �l :7 ❑Samgples ari of temp criteria. Samples on ice, cooling process
uri
USDA Regulated Soil 1 N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source lintemationally,
Iri
I IYPS I 1Nn inrlirdlno mawan and 0—m 51Irn1) r_lvae mpdN
Comments Olscrepan :
Chain of Cuslody Present?
[%es
❑No
[]N/A
1.
Samples Arrived within Hold Time?
Dues
[]No
❑NIA
2.
Shart Hold Time Analysis 1<72 hr.)?
❑Yes
ElNo
N/A
3.
Rush Turn Around Time Requested?
Elves
EfNo
❑N/A
4.
Sufficient Volume?
[yes
No
N/A
5.
Correct Containers Used?
Pace Containers Used?
Qves
Yes
❑No
No
❑N/A
❑N/A
6.
Containers Intact?
aes
No
NIA
7.
Oissorved analysis: Samples Feld Filtered?
Oyes
QNo
N/A
9.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrik:
`` ©Yes
L r
❑No
❑N/A
9.
Headspace in VOA Vials >5-6mm)?
MYes
QNo
EDNIA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
byes
❑No
ON.
[26//A
N/A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager5RF Review:
Date/Time;
Lot ID of split containers:
Date:
Date:
Field Data Required? ❑yes ❑No
Page 30 of 33

REVISION
Document Name: Document Revised: November �9Qp o 151
5ample Condition Upon Recelpt ISCUR) Page 2 of 2
acEAnalytical Document No., Issuing Authority:
F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is Project # WO# : 92584367
verified and within the acceptance range for preservation
samples.
PM: NMG Due Date: 02/01/22
�'
Exteptlons: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) {IOC, LLHg A CLIENT: 92—Duke Eno,
)` "Bottom half of box is to list number of battles 11 ,) L
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pH Adjustment Log for Preserved Samples
Sample In
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot fs
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Cerl4icatlon Office (I.e,
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 31 of 33

n
8C9Aaafyfica -
Document Name:
Sample Condition Upon Receipt iSCURi
Document Revised: November �,SS e0 $
Page 2 of 2 g
Document No.:
Issuing Authority:
F-CAR•C5•033-Rev.09
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DR0/8015 [water} DOC, LLHg
**Bottom half of box is to list number of bottles
310N
f 151
Project# WO# : 92584367
PM: NMG Due Date: 02/01/22
L'
CLIENT: 92-Duke Ener
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon reselpt
Date preservation adjusted
Time preservatlon
Amount of Preservative
Lot 4
adjusted
added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy Of this form will be sent to the North Carellna OEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 32 of 33

Duke Energy Analytical Laboratory
r'rfte, DUKE M.II Co . MGCOM te411d ft 1401)
]]]aH.e..rlr' ENERGY, N, " 2l0
ra
Irwt ns-.z.t
Project Name - 2L-2B SURFACE WATER Phan. Ne:
ij SAMPLING—_
- Client JOHN TOEPFER,BRYAN MOELLER,
s DEE O'BRIEN, JOSH STOWE, SYNTERRA
OPorating Unit: AEaO Process: 8eNVWS Account:
u Proles= Activity 10: Facility 10: ASA
Program i' EQuiS Task Cede: ASA12L213 Sub-0rogramlTask Code:
Sample Description or ID
SAMPLE to
NUMBER
ASA. Sr.,-
nquished By
-aka; W2,_
3- SA I mo.
+gn n e eow
pntelTime
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CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
+- - - - --•---------- - - - - - - - - - - .- - - - - - - -------- - - - - - - - - - - - --._._..---------•-•------------- - - -----------------------------
k AnalYtIcall Laboratory Use Only'
!Order # 0- ell a Matrix WATER NC x +
i LogGdd BY
i I k'% SAMPLE PROGRAM +
--- Ground Water_X_ NPDES_
lVendrw Drinking Water_ UST I
!GoakrT P I51..............................
RCRA Waste
PO+ Pace - -i- - - - - ----....-.- - ._.._..- - - --._.._.. - - --._.._.._.._.._..- -
i
I PO M 917271 Filtration (0.45um) !1 UnfiltBred
I! Preservative ME icE .mis
.._.._.._.._.._.._.._.._ Ice
Container Volume (.L)
2000
300
250
Soo
Container Type
PET
PET
HOPE
HOPE
Cnstanlnr to canipinfo AH app,uprMte non-shndnd nrnes,
4
U
0
%
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REVISION
Page 149 of 151 M
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Page _1_ of _2_ M
DISTRIBUTION M
ORIGINAL to LAB. COPY 10 CLIEth
to
221� 2 AUIC
41 Filtered
250
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By' OatelFime
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Requested Turnaround
TotalE-s
By' DatWTkme
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DaterTime
,0 C
21 Days
NOTE: EOUIS Eno NEEDED
ELEMENTS by ICP_MS(TRM): S, As, Be, Cd_LL, Cr, Co, Cu, P6 LL, Mo, NI, Se, Ag_LL, TILL, V_LL
ELEMENTS by ICP(TRM): Al. Ba, B. Ca, Fa, Mg, Mn, K, Na, Sr, Zn, Total Hardness
DISSOLVED METALS: All Metals: ICP_DIS_TRM (excluding Ca, Mg, K, Na), IMS_DIS TRM
5S 14 Days
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CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
REVISION
yc\'
! Duke Energy Anal ical Laborato --1r-------'-------•--------------•-•---•---•-•---•--------- - - --- --• - --•------------- ------•---•-------•---•-•-•-•-•--.
` 9Y Y< rY i Analytical LaboratoryUse Only
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L)

CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM REVISION
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DISSOLVED METALS: All Metals: ICP ;DIS_TRM (excluding Ca, Mg, K, Na), IMS DIS TRM tJ

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J22010450
Project Name: ASHEVILLE AIRPORT - 2L-2B SURFACE WATER SAMPLING
Task Code: 21_213
Customer Name(s): John Toepfer, B Moeller, Josh Stowe, Synterra
Customer Address: Asheville Airport
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: pate: 2/15/2022
(Signature)
lwe
Program Comments:
Page 1 of 96
Note: The samples associated with the PACE analyses were taken directly to the vendor laboratory after sample collection.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 96
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2022002305
Asheville Airport
27-Jan-22
1:10 PM
Richard Jacobs
ASA_SW-2-A1
2022002306
Asheville Airport
27-Jan-22
11:25 AM
Richard Jacobs
ASA_SW-3-A1
2022002307
Asheville Airport
27-Jan-22
11:55 AM
Richard Jacobs
ASA_SW-5-A1
2022002308
Asheville Airport
27-Jan-22
12:30 PM
Richard Jacobs
ASA_SW-6-A1
2022002309
Asheville Airport
27-Jan-22
12:15 PM
Richard Jacobs
ASA_SW-8-A1
2022002310
Asheville Airport
27-Jan-22
10:30 AM
Richard Jacobs
ASA_SW-9-A1
2022002311
Asheville Airport
27-Jan-22
10:45 AM
Richard Jacobs
ASA_SW-413-A1
2022002312
Asheville Airport
27-Jan-22
11:15 AM
Richard Jacobs
ASA_SW-4C-A1
2022002313
Asheville Airport
27-Jan-22
12:45 PM
Richard Jacobs
ASA_FtB-20220127-1245
2022002324
Asheville Airport
27-Jan-22
12:50 PM
Richard Jacobs
ASA_FB-20220127-1250
10 Total Samples

Page 3 of 96
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 2/15/2022

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-2-A1
Collection Date: 01/27/2022 01:10 PM Loc code: ASA SW-2-A1
Analyte Result Units Qualifiers RDL MDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22010489
Alkalinity, Bicarbonate 12.5 mg/L 5 1.7
Alkalinity, Carbonate < 5 mg/L 5 1.7
Total Alkalinity as CaCO3 12.5 mg/L 5 1.7
(CaCO3)
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC - Q22020001
Chloride
18
mg/L
0.5
0.0154
Fluoride
< 0.1
mg/L
0.1
0.0479
Sulfate
1.1
mg/L
0.1
0.0428
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
MERCURY 1631 - DISSOLVED
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22010469
Aluminum (AI)
0.011
mg/L
0.01
0.003
Barium (Ba)
0.060
mg/L
0.005
0.002
Boron (B)
0.007
mg/L J
0.05
0.005
Iron (Fe)
0.844
mg/L
0.01
0.004
Manganese (Mn)
0.200
mg/L
0.005
0.001
Strontium (Sr)
0.063
mg/L
0.005
0.001
Zinc (Zn)
0.006
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.014
mg/L
0.01
0.003
Barium (Ba)
0.060
mg/L
0.005
0.002
Boron (B)
0.006
mg/L J
0.05
0.005
Calcium (Ca)
6.54
mg/L
0.05
0.012
Iron (Fe)
0.916
mg/L
0.01
0.004
Magnesium (Mg)
2.96
mg/L
0.02
0.008
Manganese (Mn)
0.198
mg/L
0.005
0.001
Potassium (K)
1.51
mg/L
0.1
0.031
Sodium (Na)
7.70
mg/L
0.05
0.017
Strontium (Sr)
0.063
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
28.5
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.006
mg/L
0.005
0.004
Sample #: 2022002305
Matrix: GW WW
Page 4 of 96
DF
Method
Analysis Date/Time
Analyst
1
SM 2320B4d
01/31/2022 12:00
Ebatian
1
SM 2320B4d
01/31/2022 12:00
Ebatian
1
SM 2320B4d
01/31/2022 12:00
Ebatian
Vendor Method V_PACE
5 EPA
300.0
02/01/2022 10:56
BGN9034
1 EPA
300.0
02/01/2022 10:56
BGN9034
1 EPA
300.0
02/01/2022 10:56
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 10:22
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC
1 EPA 200.7
02/10/2022 11:23
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-2-A1
Collection Date: 01/27/2022 01:10 PM Loc code: ASA SW-2-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.302
ug/L
J
1
0.185
1
Cobalt (Co)
0.407
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.072
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
0.034
ug/L
J
0.1
0.032
1
Chromium (Cr)
0.357
ug/L
J
1
0.185
1
Cobalt (Co)
0.436
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.216
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.322
ug/L
J
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.085
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2022002305
Matrix: GW WW
Page 5 of 96
Method
Analysis Date/Time
Analyst
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 17:35
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
EPA 200.8
02/08/2022 15:47
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-2-A1
Collection Date: 01/27/2022 01:10 PM Loc code: ASA SW-2-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 6 of 96
Sample #: 2022002305
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.6 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/202219:03 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-3-A1
Collection Date: 01/27/2022 11:25 AM Loc code: ASA SW-3-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010460
Total Alkalinity as CaCO3 25.0 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 25.0 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22020001
Sample #: 2022002306
Matrix: GW WW
Page 7 of 96
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/31/2022 15:16 EBATIAN
1 SM 2320E-2011 01/31/2022 15:16 EBATIAN
1 SM 2320B-2011 01/31/2022 15:16 EBATIAN
Chloride
14
mg/L
0.5
0.0154 5
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
3.2
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
0.042
mg/L
0.005
0.002
Boron (B)
0.043
mg/L
J 0.05
0.005
Iron (Fe)
0.191
mg/L
0.01
0.004
Manganese (Mn)
0.225
mg/L
0.005
0.001
Strontium (Sr)
0.095
mg/L
0.005
0.001
Zinc (Zn)
0.006
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.017
mg/L
0.01
0.003
Barium (Ba)
0.043
mg/L
0.005
0.002
Boron (B)
0.043
mg/L
J 0.05
0.005
Calcium (Ca)
8.94
mg/L
0.05
0.012
Iron (Fe)
0.252
mg/L
0.01
0.004
Magnesium (Mg)
3.64
mg/L
0.02
0.008
Manganese (Mn)
0.225
mg/L
0.005
0.001
Potassium (K)
1.54
mg/L
0.1
0.031
Sodium (Na)
6.09
mg/L
0.05
0.017
Strontium (Sr)
0.095
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
37.3
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.006
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
02/01/2022 11:11
BGN9034
EPA
300.0
02/01/2022 11:11
BGN9034
EPA
300.0
02/01/2022 11:11
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 10:31
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC
1 EPA 200.7
02/10/2022 11:36
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-3-A1
Collection Date: 01/27/2022 11:25 AM Loc code: ASA SW-3-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.218
ug/L
J
1
0.185
1
Cobalt (Co)
0.58
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.347
ug/L
J
1
0.256
1
Selenium (Se)
0.517
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
0.569
ug/L
J
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.196
ug/L
J
0.2
0.037
1
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
Nickel (Ni)
0.36
ug/L
J
1
0.256
1
Selenium (Se)
0.457
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
0.046
ug/L
J
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2022002306
Matrix: GW WW
Page 8 of 96
Method
Analysis Date/Time
Analyst
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 17:10
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
EPA 200.8
02/08/2022 15:09
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-3-A1
Collection Date: 01/27/2022 11:25 AM Loc code: ASA SW-3-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 9 of 96
Sample #: 2022002306
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.7 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/202219:59 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-5-A1
Collection Date: 01/27/2022 11:55 AM Loc code: ASA SW-5-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010460
Total Alkalinity as CaCO3 78.4 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 78.4 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22020001
Sample #: 2022002307
Matrix: GW WW
Page 10 of 96
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/31/2022 15:19 EBATIAN
1 SM 2320E-2011 01/31/2022 15:19 EBATIAN
1 SM 2320B-2011 01/31/2022 15:19 EBATIAN
Chloride
19
mg/L
0.5
0.0154 5
Fluoride
0.08
mg/L
J 0.1
0.0479 1
Sulfate
4.7
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
0.012
mg/L
0.01
0.003
Barium (Ba)
0.088
mg/L
0.005
0.002
Boron (B)
0.156
mg/L
0.05
0.005
Iron (Fe)
13.1
mg/L
0.01
0.004
Manganese (Mn)
2.45
mg/L
0.005
0.001
Strontium (Sr)
0.389
mg/L
0.005
0.001
Zinc (Zn)
0.005
mg/L
J 0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.039
mg/L
0.01
0.003
Barium (Ba)
0.089
mg/L
0.005
0.002
Boron (B)
0.154
mg/L
0.05
0.005
Calcium (Ca)
24.4
mg/L
0.05
0.012
Iron (Fe)
13.9
mg/L
0.01
0.004
Magnesium (Mg)
6.59
mg/L
0.02
0.008
Manganese (Mn)
2.46
mg/L
0.005
0.001
Potassium (K)
2.30
mg/L
0.1
0.031
Sodium (Na)
6.40
mg/L
0.05
0.017
Strontium (Sr)
0.389
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
88.0
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.004
mg/L
1 0.005
0.004
Vendor Method V_PACE
EPA
300.0
02/01/2022 11:26
BGN9034
EPA
300.0
02/01/2022 11:26
BGN9034
EPA
300.0
02/01/2022 11:26
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 10:35
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC
1 EPA 200.7
02/10/2022 11:40
DMFRANC

Certificate of Laboratory Analysis Page 11 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-5-A1
Sample #: 2022002307
Collection Date: 01/27/2022 11:55 AM
Loc code: ASA
SW-5-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Arsenic (As)
0.539
ug/L J
1
0.111
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Chromium (Cr)
0.255
ug/L J
1
0.185
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Cobalt (Co)
3.08
ug/L
1
0.077
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Molybdenum (Mo)
1.89
ug/L
1
0.18
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Selenium (Se)
< 1
ug/L
1
0.193
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 17:44
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Arsenic (As)
0.596
ug/L J
1
0.111
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Cobalt (Co)
3.17
ug/L
1
0.077
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Lead (Pb) Low Level
0.135
ug/L J
0.2
0.037
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Molybdenum (Mo)
1.91
ug/L
1
0.18
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Selenium (Se)
< 1
ug/L
1
0.193
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 15:56
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-5-A1
Collection Date: 01/27/2022 11:55 AM Loc code: ASA SW-5-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 12 of 96
Sample #: 2022002307
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.1 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/2022 20:36 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-6-A1
Collection Date: 01/27/2022 12:30 PM Loc code: ASA SW-6-A1
Analyte Result Units Qualifiers RDL MDL
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22010489
Alkalinity, Bicarbonate 13.1 mg/L 5 1.7
Alkalinity, Carbonate < 5 mg/L 5 1.7
Total Alkalinity as CaCO3 13.1 mg/L 5 1.7
(CaCO3)
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
INORGANIC IONS BY IC - Q22020001
Chloride
10
mg/L
0.2
0.0154
Fluoride
< 0.1
mg/L
0.1
0.0479
Sulfate
3.0
mg/L
0.1
0.0428
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
MERCURY 1631 - DISSOLVED
- (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q22010469
Aluminum (AI)
0.004
mg/L J
0.01
0.003
Barium (Ba)
0.023
mg/L
0.005
0.002
Boron (B)
0.013
mg/L J
0.05
0.005
Iron (Fe)
3.01
mg/L
0.01
0.004
Manganese (Mn)
0.550
mg/L
0.005
0.001
Strontium (Sr)
0.032
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.058
mg/L
0.01
0.003
Barium (Ba)
0.024
mg/L
0.005
0.002
Boron (B)
0.012
mg/L J
0.05
0.005
Calcium (Ca)
4.57
mg/L
0.05
0.012
Iron (Fe)
5.17
mg/L
0.01
0.004
Magnesium (Mg)
2.42
mg/L
0.02
0.008
Manganese (Mn)
0.570
mg/L
0.005
0.001
Potassium (K)
1.92
mg/L
0.1
0.031
Sodium (Na)
3.45
mg/L
0.05
0.017
Strontium (Sr)
0.032
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
21.4
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Sample #: 2022002308
Matrix: GW WW
Page 13 of 96
DF
Method
Analysis Date/Time
Analyst
1
SM 2320B4d
01/31/2022 12:00
Ebatian
1
SM 2320B4d
01/31/2022 12:00
Ebatian
1
SM 2320B4d
01/31/2022 12:00
Ebatian
Vendor Method V_PACE
2 EPA
300.0
02/01/2022 11:41
BGN9034
1 EPA
300.0
02/01/2022 11:41
BGN9034
1 EPA
300.0
02/01/2022 11:41
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 10:40
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC
1 EPA 200.7
02/10/2022 11:45
DMFRANC

Certificate of Laboratory Analysis Page 14 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-6-A1
Sample #: 2022002308
Collection Date: 01/27/2022 12:30 PM
Loc code: ASA
SW-6-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Arsenic (As)
0.159
ug/L J
1
0.111
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Chromium (Cr)
0.229
ug/L J
1
0.185
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Cobalt (Co)
2.86
ug/L
1
0.077
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Nickel (Ni)
0.265
ug/L J
1
0.256
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Selenium (Se)
< 1
ug/L
1
0.193
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 17:52
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Arsenic (As)
0.327
ug/L J
1
0.111
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Cobalt (Co)
2.90
ug/L
1
0.077
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Lead (Pb) Low Level
0.156
ug/L J
0.2
0.037
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Nickel (Ni)
0.311
ug/L J
1
0.256
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Selenium (Se)
< 1
ug/L
1
0.193
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 16:05
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-6-A1
Collection Date: 01/27/2022 12:30 PM Loc code: ASA SW-6-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 15 of 96
Sample #: 2022002308
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.2 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/2022 20:55 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-8-A1
Collection Date: 01/27/2022 12:15 PM Loc code: ASA SW-8-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010460
Sample #: 2022002309
Matrix: GW WW
Page 16 of 96
Method Analysis Date/Time Analyst
Total Alkalinity as CaCO3
442
mg/L
5
1.7
1
SM 2320B-2011
01/31/2022 15:26
EBATIAN
(CaCO3)
Alkalinity, Carbonate
< 5
mg/L
5
1.7
1
SM 2320B-2011
01/31/2022 15:26
EBATIAN
Alkalinity, Bicarbonate
442
mg/L
5
1.7
1
SM 2320B-2011
01/31/2022 15:26
EBATIAN
NITRITE + NITRATE (COLORIMETRIC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
INORGANIC IONS BY IC - Q22020001
Chloride
3.4
mg/L
0.5
0.0154
5
EPA 300.0
02/01/2022 11:57
BGN9034
Fluoride
0.58
mg/L
0.1
0.0479
1
EPA 300.0
02/01/2022 11:57
BGN9034
Sulfate
19
mg/L
0.5
0.0428
5
EPA 300.0
02/01/2022 11:57
BGN9034
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
MERCURY 1631 - DISSOLVED - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
0.016
mg/L
0.01
0.003
1
EPA 200.7
02/10/2022 10:44
DMFRANC
Barium (Ba)
0.254
mg/L
0.005
0.002
1
EPA 200.7
02/10/2022 10:44
DMFRANC
Boron (B)
0.991
mg/L
0.05
0.005
1
EPA 200.7
02/10/2022 10:44
DMFRANC
Iron (Fe)
18.1
mg/L
0.01
0.004
1
EPA 200.7
02/10/2022 10:44
DMFRANC
Manganese (Mn)
5.04
mg/L
0.005
0.001
1
EPA 200.7
02/10/2022 10:44
DMFRANC
Strontium (Sr)
2.48
mg/L
0.005
0.001
1
EPA 200.7
02/10/2022 10:44
DMFRANC
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
1
EPA 200.7
02/10/2022 10:44
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.077
mg/L
0.01
0.003
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Barium (Ba)
0.274
mg/L
0.005
0.002
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Boron (B)
0.985
mg/L
0.05
0.005
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Calcium (Ca)
142
mg/L
1
0.012
20
EPA 200.7
02/10/2022 11:49
DMFRANC
Iron (Fe)
24.2
mg/L
0.01
0.004
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Magnesium (Mg)
26.4
mg/L
0.02
0.008
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Manganese (Mn)
5.05
mg/L
0.005
0.001
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Potassium (K)
4.34
mg/L
0.1
0.031
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Sodium (Na)
6.15
mg/L
0.05
0.017
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Strontium (Sr)
2.48
mg/L
0.005
0.001
1
EPA 200.7
02/10/2022 11:49
DMFRANC
Total Hardness (Ca and Mg)
464
mg/L
0.066
1
EPA 200.7
02/10/2022 11:49
DMFRANC
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
1
EPA 200.7
02/10/2022 11:49
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-8-A1
Collection Date: 01/27/2022 12:15 PM Loc code: ASA SW-8-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
312
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.193
ug/L J
1
0.185
1
Cobalt (Co)
7.02
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
59.6
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.199
ug/L J
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
465
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
7.18
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.148
ug/L J
0.2
0.037
1
Molybdenum (Mo)
59.7
ug/L
1
0.18
1
Nickel (Ni)
< 1
ug/L
1
0.256
1
Selenium (Se)
< 1
ug/L
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.285
ug/L J
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2022002309
Matrix: GW WW
Page 17 of 96
Method
Analysis Date/Time
Analyst
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 18:00
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
EPA 200.8
02/08/2022 16:15
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-8-A1
Collection Date: 01/27/2022 12:15 PM Loc code: ASA SW-8-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 18 of 96
Sample #: 2022002309
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 3.2 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/2022 21:13 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-9-A1
Collection Date: 01/27/2022 10:30 AM Loc code: ASA SW-9-A1
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010460
Total Alkalinity as CaCO3 51.0 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 51.0 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22020001
Sample #: 2022002310
Matrix: GW WW
Page 19 of 96
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/31/2022 15:30 EBATIAN
1 SM 2320E-2011 01/31/2022 15:30 EBATIAN
1 SM 2320B-2011 01/31/2022 15:30 EBATIAN
Chloride
12
mg/L
0.5
0.0154 5
Fluoride
0.10
mg/L
0.1
0.0479 1
Sulfate
8.7
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
0.004
mg/L
J 0.01
0.003
Barium (Ba)
0.045
mg/L
0.005
0.002
Boron (B)
0.135
mg/L
0.05
0.005
Iron (Fe)
0.192
mg/L
0.01
0.004
Manganese (Mn)
0.738
mg/L
0.005
0.001
Strontium (Sr)
0.165
mg/L
0.005
0.001
Zinc (Zn)
0.004
mg/L
J 0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.113
mg/L
0.01
0.003
Barium (Ba)
0.047
mg/L
0.005
0.002
Boron (B)
0.136
mg/L
0.05
0.005
Calcium (Ca)
14.8
mg/L
0.05
0.012
Iron (Fe)
0.908
mg/L
0.01
0.004
Magnesium (Mg)
6.75
mg/L
0.02
0.008
Manganese (Mn)
0.755
mg/L
0.005
0.001
Potassium (K)
1.79
mg/L
0.1
0.031
Sodium (Na)
5.22
mg/L
0.05
0.017
Strontium (Sr)
0.168
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
64.7
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.004
mg/L
1 0.005
0.004
Vendor Method V_PACE
EPA
300.0
02/01/2022 12:12
BGN9034
EPA
300.0
02/01/2022 12:12
BGN9034
EPA
300.0
02/01/2022 12:12
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 10:48
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC
1 EPA 200.7
02/10/2022 11:54
DMFRANC

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-9-A1
Collection Date: 01/27/2022 10:30 AM Loc code: ASA SW-9-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
- Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
< 1
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
0.243
ug/L
J
1
0.185
1
Cobalt (Co)
2.24
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
Molybdenum (Mo)
0.672
ug/L
J
1
0.18
1
Nickel (Ni)
1.20
ug/L
1
0.256
1
Selenium (Se)
0.285
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
Arsenic (As)
1.99
ug/L
1
0.111
1
Beryllium (Be)
< 1
ug/L
1
0.249
1
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
Chromium (Cr)
< 1
ug/L
1
0.185
1
Cobalt (Co)
2.21
ug/L
1
0.077
1
Copper (Cu)
< 2
ug/L
2
0.787
1
Lead (Pb) Low Level
0.171
ug/L
J
0.2
0.037
1
Molybdenum (Mo)
0.795
ug/L
J
1
0.18
1
Nickel (Ni)
1.22
ug/L
1
0.256
1
Selenium (Se)
0.247
ug/L
J
1
0.193
1
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
Miscellaneous Tests by a Vendor
Laboratory
- (Analysis Performed
by
Pace Laboratories)
Vendor Parameter
Complete
METALS ANALYSIS BY VENDOR LAB - (Analvsis
Performed by Pace
Laboratories)
Vendor Parameter Complete
METHANE - (Analysis Performed by Pace Laboratories
Vendor Parameter Complete
Sample #: 2022002310
Matrix: GW WW
Page 20 of 96
Method
Analysis Date/Time
Analyst
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 18:09
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
EPA 200.8
02/08/2022 16:24
CWSPEN3
Vendor Method
V_PACE
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-9-A1
Collection Date: 01/27/2022 10:30 AM Loc code: ASA SW-9-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 21 of 96
Sample #: 2022002310
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.7 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/2022 21:31 EBATIAN

Certificate of Laboratory Analysis Page 22 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-4B-A1 Sample #: 2022002311
Collection Date: 01/27/2022 10:45 AM Loc code: ASA SW-4B-A1 Matrix: GW WW
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010460
Total Alkalinity as CaCO3 26.6 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 26.6 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22020001
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/31/2022 15:34 EBATIAN
1 SM 2320E-2011 01/31/2022 15:34 EBATIAN
1 SM 2320B-2011 01/31/2022 15:34 EBATIAN
Chloride
2.7
mg/L
0.1
0.0154 1
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
8.3
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
0.023
mg/L
0.005
0.002
Boron (B)
0.118
mg/L
0.05
0.005
Iron (Fe)
0.440
mg/L
0.01
0.004
Manganese (Mn)
0.237
mg/L
0.005
0.001
Strontium (Sr)
0.062
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.047
mg/L
0.01
0.003
Barium (Ba)
0.024
mg/L
0.005
0.002
Boron (B)
0.117
mg/L
0.05
0.005
Calcium (Ca)
7.11
mg/L
0.05
0.012
Iron (Fe)
1.00
mg/L
0.01
0.004
Magnesium (Mg)
3.72
mg/L
0.02
0.008
Manganese (Mn)
0.251
mg/L
0.005
0.001
Potassium (K)
1.11
mg/L
0.1
0.031
Sodium (Na)
2.64
mg/L
0.05
0.017
Strontium (Sr)
0.062
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
33.1
mg/L
0.066
(CaCO3)
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
Vendor Method V_PACE
EPA
300.0
02/01/2022 10:25
BGN9034
EPA
300.0
02/01/2022 10:25
BGN9034
EPA
300.0
02/01/2022 10:25
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 10:53
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC
1 EPA 200.7
02/10/2022 11:58
DMFRANC

Certificate of Laboratory Analysis Page 23 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-4B-A1
Sample #: 2022002311
Collection Date: 01/27/2022
10:45 AM
Loc code: ASA SW-4B-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Cobalt (Co)
0.679
ug/L J
1
0.077
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Selenium (Se)
2.03
ug/L
1
0.193
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 18:17
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Arsenic (As)
0.206
ug/L J
1
0.111
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Chromium (Cr)
< 1
ug/L
1
0.185
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Cobalt (Co)
0.753
ug/L J
1
0.077
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Lead (Pb) Low Level
0.164
ug/L J
0.2
0.037
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Nickel (Ni)
< 1
ug/L
1
0.256
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Selenium (Se)
2.22
ug/L
1
0.193
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 16:33
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-4B-A1
Collection Date: 01/27/2022 10:45 AM Loc code: ASA SW-4B-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 24 of 96
Sample #: 2022002311
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.5 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/2022 21:49 EBATIAN

Certificate of Laboratory Analysis Page 25 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-4C-A1 Sample #: 2022002312
Collection Date: 01/27/2022 11:15 AM Loc code: ASA SW-4C-A1 Matrix: GW WW
Analyte Result Units Qualifiers RDL MDL DF
TOTAL ALKALINITY - Q22010460
Total Alkalinity as CaCO3 22.6 mg/L 5 1.7
(CaCO3)
Alkalinity, Carbonate < 5 mg/L 5 1.7
Alkalinity, Bicarbonate 22.6 mg/L 5 1.7
NITRITE + NITRATE (COLORIMETRIC) - (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete
INORGANIC IONS BY IC - Q22020001
Method Analysis Date/Time Analyst
1 SM 2320E-2011 01/31/2022 15:38 EBATIAN
1 SM 2320E-2011 01/31/2022 15:38 EBATIAN
1 SM 2320B-2011 01/31/2022 15:38 EBATIAN
Chloride
2.1
mg/L
0.1
0.0154 1
Fluoride
< 0.1
mg/L
0.1
0.0479 1
Sulfate
6.5
mg/L
0.1
0.0428 1
MERCURY IN WATER - (Analvsis Performed by Pace Laboratories
Vendor Parameter Complete
MERCURY 1631 - DISSOLVED - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
0.004
mg/L
J 0.01
0.003
Barium (Ba)
0.024
mg/L
0.005
0.002
Boron (B)
0.097
mg/L
0.05
0.005
Iron (Fe)
0.168
mg/L
0.01
0.004
Manganese (Mn)
0.228
mg/L
0.005
0.001
Strontium (Sr)
0.053
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP - Q22010473
Aluminum (AI)
0.051
mg/L
0.01
0.003
Barium (Ba)
0.024
mg/L
0.005
0.002
Boron (B)
0.097
mg/L
0.05
0.005
Calcium (Ca)
5.73
mg/L
0.05
0.012
Iron (Fe)
0.395
mg/L
0.01
0.004
Magnesium (Mg)
3.23
mg/L
0.02
0.008
Manganese (Mn)
0.235
mg/L
0.005
0.001
Potassium (K)
1.03
mg/L
0.1
0.031
Sodium (Na)
2.40
mg/L
0.05
0.017
Strontium (Sr)
0.053
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
27.6
mg/L
0.066
(CaCO3)
Zinc (Zn)
0.005
mg/L
1 0.005
0.004
Vendor Method V_PACE
EPA
300.0
02/01/2022 10:40
BGN9034
EPA
300.0
02/01/2022 10:40
BGN9034
EPA
300.0
02/01/2022 10:40
BGN9034
Vendor Method V_PACE
Vendor Method V_PACE
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 10:57
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC
1 EPA 200.7
02/10/2022 12:02
DMFRANC

Certificate of Laboratory Analysis Page 26 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-4C-A1
Sample #: 2022002312
Collection Date: 01/27/2022
11:15 AM
Loc code: ASA SW-4C-A1
Matrix: GW WW
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Chromium (Cr)
0.338
ug/L J
1
0.185
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Cobalt (Co)
0.576
ug/L J
1
0.077
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Copper (Cu)
< 2
ug/L
2
0.787
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Nickel (Ni)
0.284
ug/L J
1
0.256
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Selenium (Se)
3.49
ug/L
1
0.193
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 18:25
CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS - Q22010481
Antimony (Sb)
< 1
ug/L
1
0.104
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Arsenic (As)
< 1
ug/L
1
0.111
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Beryllium (Be)
< 1
ug/L
1
0.249
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Chromium (Cr)
0.224
ug/L J
1
0.185
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Cobalt (Co)
0.606
ug/L J
1
0.077
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Copper (Cu)
26.6
ug/L
2
0.787
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Lead (Pb) Low Level
0.191
ug/L J
0.2
0.037
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Molybdenum (Mo)
< 1
ug/L
1
0.18
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Nickel (Ni)
2.30
ug/L
1
0.256
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Selenium (Se)
3.38
ug/L
1
0.193
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
1
EPA 200.8
02/08/2022 16:43
CWSPEN3
Miscellaneous Tests by a Vendor Laboratory
- (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA SW-4C-A1
Collection Date: 01/27/2022 11:15 AM Loc code: ASA SW-4C-A1
Analyte Result Units Qualifiers RDL MDL DF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Total Carbon - Q22010484
Page 27 of 96
Sample #: 2022002312
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
TOC 1.6 mg/L 0.1 0.055 1 SM5310C/EPA9060A 01/31/2022 22:07 EBATIAN

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA FtB-20220127-1245 Filter Blank
Collection Date: 01/27/2022 12:45 PM Loc code: ASA FtB
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22010469
Aluminum (AI)
< 0.01
mg/L
0.01
0.003
Barium (Ba)
< 0.005
mg/L
0.005
0.002
Boron (B)
< 0.05
mg/L
0.05
0.005
Iron (Fe)
0.008
mg/L
J 0.01
0.004
Manganese (Mn)
< 0.005
mg/L
0.005
0.001
Strontium (Sr)
< 0.005
mg/L
0.005
0.001
Zinc (Zn)
< 0.005
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22010478
Antimony (Sb)
< 1
ug/L
1
0.104
Arsenic (As)
< 1
ug/L
1
0.111
Beryllium (Be)
< 1
ug/L
1
0.249
Cadmium (Cd) Low Level
< 0.1
ug/L
0.1
0.032
Chromium (Cr)
0.242
ug/L
J 1
0.185
Cobalt (Co)
< 1
ug/L
1
0.077
Copper (Cu)
< 2
ug/L
2
0.787
Lead (Pb) Low Level
< 0.2
ug/L
0.2
0.037
Molybdenum (Mo)
< 1
ug/L
1
0.18
Nickel (Ni)
< 1
ug/L
1
0.256
Selenium (Se)
< 1
ug/L
1
0.193
Silver (Ag) Low Level
< 0.2
ug/L
0.2
0.035
Thallium (TI) Low Level
< 0.2
ug/L
0.2
0.041
Vanadium (V) Low Level
< 0.3
ug/L
0.3
0.114
Page 28 of 96
Sample #:
2022002313
Matrix:
GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1
EPA 200.7
02/10/2022 11:02
DMFRANC
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3
1 EPA 200.8
02/08/2022 18:34
CWSPEN3

Certificate of Laboratory Analysis Page 29 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Site: ASA FB-20220127-1250 Field Blank Sample #: 2022002324
Collection Date: 01/27/2022 12:50 PM Loc code: ASA FB Matrix: GW WW
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
MERCURY IN WATER - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 30 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010460 ALK_CarbBicarb TOTAL ALKALINITY
Duplicate # 1
Parameter Measured
Final
Alkalinity, Bicarbonate
104
Alkalinity, Carbonate
0
Total Alkalinity as
104
CaCO3
LCS # 1
Parameter Measured Final
Total Alkalinity as 93
CaCO3
Parent Sample: J22010436 -- 2022002263
Units: Dil RPD Qualifier
mg/L 1 2
mg/L 1 0
mg/L 1 2
Units: Dil Spike % Recovery LCL UCL Qualifier
mg/L 1 95.5 97.4 85 115

Certificate of Laboratory Analysis Page 31 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010489 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample: J22010436 -- 2022002265
Parameter Measured
Final
Units:
Dil
RPD Qualifier
Alkalinity, Bicarbonate
14.8
mg/L
1
4.86
Alkalinity, Carbonate
0
mg/L
1
0
Total Alkalinity as
14.8
mg/L
1
4.86
CaCO3
LCS # 1
Parameter Measured
Final
Units:
Dil
Spike % Recovery LCL UCL Qualifier
Total Alkalinity as
92.8
mg/L
1
95.5 97.2 85 115
CaCO3
(CaCO3)

Certificate of Laboratory Analysis Page 32 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22020001 Dionex INORGANIC IONS BY IC
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.1
< 1/2 RDL
Fluoride
0
0
mg/L
1
0.1
< 1/2 RDL
Sulfate
0.001
0.001
mg/L
1
0.1
< 1/2 RDL
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Chloride
1.91
1.91
mg/L
1
2
95.5 90
110
Fluoride
1.96
1.96
mg/L
1
2
98 90
110
Sulfate
1.83
1.83
mg/L
1
2
91.6 90
110
Parent Sample:
J21120178 -- 2021032941
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Chloride
8.19
40.9
mg/L
5
10
95.9 80
120
Fluoride
1.98
9.92
mg/L
5
10
98.2 80
120
Sulfate
5.99
30
mg/L
5
10
96.2 80
120
Parent Sample:
J21120178 -- 2021032941
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
RPD
Qualifier
Chloride
8.17
40.9
mg/L
5
10
95.1 80
120
0.869
Fluoride
1.97
9.84
mg/L
5
10
97.5 80
120
0.746
Sulfate
5.99
29.9
mg/L
5
10
95.8 80
120
0.396
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

Certificate of Laboratory Analysis Page 33 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010469 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Aluminum (AI)
0.000578
0.000578
mg/L
1
0.01
< 1/2 RDL
Barium (Ba)
-0.000066
-0.000066
mg/L
1
0.005
< 1/2 RDL
Boron (B)
0.00306
0.00306
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
0.00243
0.00243
mg/L
1
0.01
< 1/2 RDL
Manganese (Mn)
-0.000107
-0.000107
mg/L
1
0.005
< 1/2 RDL
Strontium (Sr)
-0.000049
-0.000049
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
0.000845
0.000845
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.11
5.11
mg/L
1
5
102
85
115
Barium (Ba)
5.11
5.11
mg/L
1
5
102
85
115
Boron (B)
4.93
4.93
mg/L
1
5
98.6
85
115
Iron (Fe)
5.03
5.03
mg/L
1
5
101
85
115
Manganese (Mn)
5.01
5.01
mg/L
1
5
100
85
115
Strontium (Sr)
5.03
5.03
mg/L
1
5
101
85
115
Zinc (Zn)
5.06
5.06
mg/L
1
5
101
85
115
MS # 1
Parent Sample:
J22010450 -- 2022002305
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.16
5.16
mg/L
1
5
103
70
130
Barium (Ba)
5.18
5.18
mg/L
1
5
102
70
130
Boron (B)
4.99
4.99
mg/L
1
5
99.7
70
130
Iron (Fe)
5.87
5.87
mg/L
1
5
100
70
130
Manganese (Mn)
5.22
5.22
mg/L
1
5
100
70
130
Strontium (Sr)
5.12
5.12
mg/L
1
5
101
70
130
Zinc (Zn)
5.06
5.06
mg/L
1
5
101
70
130
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

Certificate of Laboratory Analysis Page 34 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010473 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Aluminum (AI)
0.000638
0.000638
mg/L
1
0.01
< 1/2 RDL
Barium (Ba)
-0.000039
-0.000039
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.000214
-0.000214
mg/L
1
0.05
< 1/2 RDL
Calcium (Ca)
0.000355
0.000355
mg/L
1
0.05
< 1/2 RDL
Iron (Fe)
0.00139
0.00139
mg/L
1
0.01
< 1/2 RDL
Magnesium (Mg)
-0.00164
-0.00164
mg/L
1
0.02
< 1/2 RDL
Manganese (Mn)
0.000028
0.000028
mg/L
1
0.005
< 1/2 RDL
Potassium (K)
-0.00525
-0.00525
mg/L
1
0.1
< 1/2 RDL
Sodium (Na)
-0.0118
-0.0118
mg/L
1
0.05
< 1/2 RDL
Strontium (Sr)
0.000006
0.000006
mg/L
1
0.005
< 1/2 RDL
Zinc (Zn)
-0.000623
-0.000623
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.13
5.13
mg/L
1
5
103
85
115
Barium (Ba)
5.09
5.09
mg/L
1
5
102
85
115
Boron (B)
4.95
4.95
mg/L
1
5
98.9
85
115
Calcium (Ca)
5
5
mg/L
1
5
99.9
85
115
Iron (Fe)
5.02
5.02
mg/L
1
5
100
85
115
Magnesium (Mg)
4.96
4.96
mg/L
1
5
99.2
85
115
Manganese (Mn)
5.01
5.01
mg/L
1
5
100
85
115
Potassium (K)
5
5
mg/L
1
5
100
85
115
Sodium (Na)
4.95
4.95
mg/L
1
5
99.1
85
115
Strontium (Sr)
5
5
mg/L
1
5
99.9
85
115
Zinc (Zn)
5.04
5.04
mg/L
1
5
101
85
115
MS # 1
Parent Sample:
J22010450 -- 2022002305
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.11
5.11
mg/L
1
5
102
70
130
Barium (Ba)
5.13
5.13
mg/L
1
5
101
70
130
Boron (B)
4.93
4.93
mg/L
1
5
98.4
70
130
Calcium (Ca)
11.7
11.7
mg/L
1
5
103
70
130
Iron (Fe)
5.92
5.92
mg/L
1
5
100
70
130
Magnesium (Mg)
7.96
7.96
mg/L
1
5
100
70
130
Manganese (Mn)
5.18
5.18
mg/L
1
5
99.6
70
130
Potassium (K)
6.5
6.5
mg/L
1
5
99.8
70
130
Sodium (Na)
12.8
12.8
mg/L
1
5
102
70
130
Strontium (Sr)
5.02
5.02
mg/L
1
5
99.1
70
130
Zinc (Zn)
5
5
mg/L
1
5
99.9
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010473 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Aluminum (AI)
5.15
5.15
mg/L
1
5
Barium (Ba)
5.16
5.16
mg/L
1
5
Boron (B)
4.93
4.93
mg/L
1
5
Calcium (Ca)
11.6
11.6
mg/L
1
5
Iron (Fe)
5.94
5.94
mg/L
1
5
Magnesium (Mg)
7.95
7.95
mg/L
1
5
Manganese (Mn)
5.21
5.21
mg/L
1
5
Potassium (K)
6.52
6.52
mg/L
1
5
Sodium (Na)
12.7
12.7
mg/L
1
5
Strontium (Sr)
5.05
5.05
mg/L
1
5
Zinc (Zn)
5.05
5.05
mg/L
1
5
Page 35 of 96
Parent Sample: J22010450 -- 2022002305
% Recovery
LCL
UCL
RPD Qualifier
103
70
130
0.799
102
70
130
0.525
98.4
70
130
0.0203
102
70
130
0.335
100
70
130
0.371
99.7
70
130
0.201
100
70
130
0.654
100
70
130
0.2
101
70
130
0.611
99.7
70
130
0.636
101
70
130
0.995
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

Certificate of Laboratory Analysis Page 36 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010478 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Antimony (Sb)
-0.036
-0.036
ug/L
1
1
< 1/2 RDL
Arsenic (As)
0.003
0.003
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
0.043
0.043
ug/L
1
1
< 1/2 RDL
Cadmium (Cd) Low Level
-0.001
-0.001
ug/L
1
0.1
< 1/2 RDL
Chromium (Cr)
0.092
0.092
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
0.007
0.007
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.149
-0.149
ug/L
1
2
< 1/2 RDL
Lead (Pb) Low Level
-0.002
-0.002
ug/L
1
0.2
< 1/2 RDL
Molybdenum (Mo)
0.006
0.006
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
-0.009
-0.009
ug/L
1
1
< 1/2 RDL
Selenium (Se)
-0.012
-0.012
ug/L
1
1
< 1/2 RDL
Silver (Ag) Low Level
0.004
0.004
ug/L
1
0.2
< 1/2 RDL
Thallium (TI) Low Level
-0.008
-0.008
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
0.025
0.025
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
49.8
49.8
ug/L
1
50
99.6
85
115
Arsenic (As)
51
51
ug/L
1
50
102
85
115
Beryllium (Be)
48.8
48.8
ug/L
1
50
97.7
85
115
Cadmium (Cd) Low Level
50.6
50.6
ug/L
1
50
101
85
115
Chromium (Cr)
49.7
49.7
ug/L
1
50
99.5
85
115
Cobalt (Co)
50.9
50.9
ug/L
1
50
102
85
115
Copper (Cu)
50.8
50.8
ug/L
1
50
102
85
115
Lead (Pb) Low Level
50.6
50.6
ug/L
1
50
101
85
115
Molybdenum (Mo)
51
51
ug/L
1
50
102
85
115
Nickel (Ni)
51.5
51.5
ug/L
1
50
103
85
115
Selenium (Se)
47.8
47.8
ug/L
1
50
95.5
85
115
Silver (Ag) Low Level
51.4
51.4
ug/L
1
50
103
85
115
Thallium (TI) Low Level
48.6
48.6
ug/L
1
50
97.3
85
115
Vanadium (V) Low Level
49.3
49.3
ug/L
1
50
98.7
85
115
NIS # 1
Parent Sample:
J22010450 -- 2022002306
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
51.1
51.1
ug/L
1
50
102
70
130
Arsenic (As)
51.7
51.7
ug/L
1
50
103
70
130
Beryllium (Be)
50.5
50.5
ug/L
1
50
101
70
130
Cadmium (Cd) Low Level
51.1
51.1
ug/L
1
50
102
70
130
Chromium (Cr)
49.8
49.8
ug/L
1
50
99.1
70
130
Cobalt (Co)
51.3
51.3
ug/L
1
50
102
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010478 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MS # 1
Parameter
Measured
Final
Units:
Dil
Spike
Copper (Cu)
50.8
50.8
ug/L
1
50
Lead (Pb) Low Level
50.5
50.5
ug/L
1
50
Molybdenum (Mo)
51.6
51.6
ug/L
1
50
Nickel (Ni)
51.8
51.8
ug/L
1
50
Selenium (Se)
48.2
48.2
ug/L
1
50
Silver (Ag) Low Level
50.9
50.9
ug/L
1
50
Thallium (TI) Low Level
46.8
46.8
ug/L
1
50
Vanadium (V) Low Level
49.6
49.6
ug/L
1
50
Page 37 of 96
Parent Sample: J22010450 -- 2022002306
% Recovery
LCL
UCL Qualifier
102
70
130
101
70
130
103
70
130
103
70
130
95.4
70
130
102
70
130
93.5
70
130
99.2
70
130
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

Certificate of Laboratory Analysis Page 38 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010481 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Antimony (Sb)
-0.029
-0.029
ug/L
1
1
< 1/2 RDL
Arsenic (As)
-0.017
-0.017
ug/L
1
1
< 1/2 RDL
Beryllium (Be)
-0.024
-0.024
ug/L
1
1
< 1/2 RDL
Cadmium (Cd) Low Level
-0.013
-0.013
ug/L
1
0.1
< 1/2 RDL
Chromium (Cr)
-0.11
-0.11
ug/L
1
1
< 1/2 RDL
Cobalt (Co)
-0.014
-0.014
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.076
-0.076
ug/L
1
2
< 1/2 RDL
Lead (Pb) Low Level
-0.023
-0.023
ug/L
1
0.2
< 1/2 RDL
Molybdenum (Mo)
-0.014
-0.014
ug/L
1
1
< 1/2 RDL
Nickel (Ni)
-0.038
-0.038
ug/L
1
1
< 1/2 RDL
Selenium (Se)
-0.028
-0.028
ug/L
1
1
< 1/2 RDL
Silver (Ag) Low Level
0.006
0.006
ug/L
1
0.2
< 1/2 RDL
Thallium (TI) Low Level
0.036
0.036
ug/L
1
0.2
< 1/2 RDL
Vanadium (V) Low Level
-0.02
-0.02
ug/L
1
0.3
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
50.6
50.6
ug/L
1
50
101
85
115
Arsenic (As)
50.6
50.6
ug/L
1
50
101
85
115
Beryllium (Be)
48.1
48.1
ug/L
1
50
96.3
85
115
Cadmium (Cd) Low Level
51.4
51.4
ug/L
1
50
103
85
115
Chromium (Cr)
51.9
51.9
ug/L
1
50
104
85
115
Cobalt (Co)
51.1
51.1
ug/L
1
50
102
85
115
Copper(Cu)
51
51
ug/L
1
50
102
85
115
Lead (Pb) Low Level
51.5
51.5
ug/L
1
50
103
85
115
Molybdenum (Mo)
50.7
50.7
ug/L
1
50
101
85
115
Nickel (Ni)
51.2
51.2
ug/L
1
50
102
85
115
Selenium (Se)
48.4
48.4
ug/L
1
50
96.9
85
115
Silver (Ag) Low Level
50.1
50.1
ug/L
1
50
100
85
115
Thallium (TI) Low Level
49.3
49.3
ug/L
1
50
98.7
85
115
Vanadium (V) Low Level
51.7
51.7
ug/L
1
50
103
85
115
MS # 1
Parent Sample:
J22010450 -- 2022002306
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
51.3
51.3
ug/L
1
50
103
70
130
Arsenic (As)
51
51
ug/L
1
50
102
70
130
Beryllium (Be)
48.5
48.5
ug/L
1
50
97
70
130
Cadmium (Cd) Low Level
51.8
51.8
ug/L
1
50
104
70
130
Chromium (Cr)
52.5
52.5
ug/L
1
50
105
70
130
Cobalt (Co)
50.9
50.9
ug/L
1
50
101
70
130

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010481 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units:
Dil
Spike
Copper (Cu)
50.6
50.6
ug/L
1
50
Lead (Pb) Low Level
51.8
51.8
ug/L
1
50
Molybdenum (Mo)
51.3
51.3
ug/L
1
50
Nickel (Ni)
51.7
51.7
ug/L
1
50
Selenium (Se)
48.9
48.9
ug/L
1
50
Silver (Ag) Low Level
49.3
49.3
ug/L
1
50
Thallium (TI) Low Level
48.4
48.4
ug/L
1
50
Vanadium (V) Low Level
52.4
52.4
ug/L
1
50
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Antimony (Sb)
50.9
50.9
ug/L
1
50
Arsenic (As)
50.4
50.4
ug/L
1
50
Beryllium (Be)
49.2
49.2
ug/L
1
50
Cadmium (Cd) Low Level
50.8
50.8
ug/L
1
50
Chromium (Cr)
51.6
51.6
ug/L
1
50
Cobalt (Co)
50.1
50.1
ug/L
1
50
Copper (Cu)
49.6
49.6
ug/L
1
50
Lead (Pb) Low Level
51.2
51.2
ug/L
1
50
Molybdenum (Mo)
50.5
50.5
ug/L
1
50
Nickel (Ni)
50.2
50.2
ug/L
1
50
Selenium (Se)
48.4
48.4
ug/L
1
50
Silver (Ag) Low Level
48.9
48.9
ug/L
1
50
Thallium (TI) Low Level
48.8
48.8
ug/L
1
50
Vanadium (V) Low Level
51.8
51.8
ug/L
1
50
Qualifiers:
Page 39 of 96
Parent Sample: J22010450 -- 2022002306
% Recovery
LCL
UCL Qualifier
101
70
130
103
70
130
102
70
130
103
70
130
97
70
130
98.5
70
130
96.7
70
130
105
70
130
Parent Sample: J22010450 -- 2022002306
% Recovery
LCL
UCL
RPD Qualifier
102
70
130
0.788
101
70
130
1.26
98.4
70
130
1.46
102
70
130
1.96
103
70
130
1.87
99
70
130
1.76
98.9
70
130
2.04
102
70
130
1.19
101
70
130
1.56
99.7
70
130
2.99
96
70
130
1.06
97.7
70
130
0.799
97.5
70
130
0.838
103
70
130
1.32
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an

Certificate of Laboratory Analysis Page 40 of 96
This report shall not be reproduced, except in full.
Order # J22010450
Level II QC Summary
Q22010484 Total Carbon Total Carbon
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.022
0.022
mg/L
1
0.1
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TOC
0.022
0.022
mg/L
1
0.1
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL Qualifier
TOC
2.59
2.59
mg/L
1
2.71
95.5 85
115
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL Qualifier
TOC
2.6
2.6
mg/L
1
2.71
96.1 85
115
MS # 1
Parent Sample:
J22010436 -- 2022002263
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL Qualifier
TOC
3.11
3.11
mg/L
1
2
98 80
120
MSD # 1
Parent Sample:
J22010436 -- 2022002263
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL RPD Qualifier
TOC
3.18
3.18
mg/L
1
2
101 80
120 3.21
MS # 2
Parent Sample:
J22010450 -- 2022002306
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL Qualifier
TOC
3.66
3.66
mg/L
1
2
101 80
120
MSD # 2
Parent Sample:
J22010450 -- 2022002306
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL RPD Qualifier
TOC
3.65
3.65
mg/L
1
2
100 80
120 0.349

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February 08, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J22010450 ASA 21L213
Pace Project No.: 92585123
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 28, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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CERTIFICATIONS
Project: J22010450 ASA 21-213
Pace Project No.: 92585123
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J22010450 ASA 2L2B
Pace Project No.: 92585123
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92585123001
SW-2-Al
Water
01 /27/22 13:10
01 /28/22 14:10
92585123002
SW-3-Al
Water
01/27/2211:25
01/28/2214:10
92585123003
SW-5-Al
Water
01/27/2211:55
01/28/2214:10
92585123004
SW-6-Al
Water
01/27/2212:30
01/28/2214:10
92585123005
SW-8-Al
Water
01/27/2212:15
01/28/2214:10
92585123006
SW-9-Al
Water
01/27/2210:30
01/28/2214:10
92585123007
SW-413-A1
Water
01/27/2210:45
01/28/2214:10
92585123008
SW-4C-A1
Water
01/27/2211:15
01/28/2214:10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J22010450 ASA 21-213
92585123
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92585123001
SW-2-Al
SM 2540C-2015
MA132
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123002
SW-3-Al
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123003
SW-5-Al
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123004
SW-6-Al
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123005
SW-8-Al
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123006
SW-9-Al
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123007
SW-413-A1
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
92585123008
SW-4C-Al
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2011
ZMC
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
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Project: J22010450 ASA 21-213
Pace Project No.: 92585123
Lab Sample ID
Method
Client Sample ID
Parameters
92585123001
SW-2-Al
SM 2540C-2015
Total Dissolved Solids
92585123002
SW-3-Al
SM 2540C-2015
Total Dissolved Solids
92585123003
SW-5-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92585123004
SW-6-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92585123005
SW-8-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92585123006
SW-9-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92585123007
SW-413-A1
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
92585123008
SW-4C-Al
SM 2540C-2015
Total Dissolved Solids
SM 2540D-2011
Total Suspended Solids
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
87.0
mg/L
25.0
02/01/2211:29
78.0
mg/L
25.0
02/01/2211:29
128
mg/L
25.0
02/01/2211:29
23.1
mg/L
2.8
02/01/2215:38
45.0
mg/L
25.0
02/01/2211:29
20.0
mg/L
2.7
02/01/2215:38
476
mg/L
50.0
02/01/2211:29
52.6
mg/L
2.0
02/01/2215:38
103
mg/L
25.0
02/01/2211:29
3.8
mg/L
1.0
02/01/2215:39
48.0
mg/L
25.0
02/01/2211:29
3.0
mg/L
1.0
02/01/2215:40
55.0
mg/L
25.0
02/01/2211:29
1.0
mg/L
1.0
02/01/2215:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qualifiers
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PROJECT NARRATIVE
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Method: SM 2540C-2015
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: February 08, 2022
General Information:
8 samples were analyzed for SM 2540C-2015 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 22

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PROJECT NARRATIVE
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Method: SM 2540D-2011
Description: 2540D TSS, Low -Level
Client: Duke Energy
Date: February 08, 2022
General Information:
8 samples were analyzed for SM 2540D-2011 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-2-Al
Parameters
Lab ID: 92585123001 Collected:
Report
Results Units Limit
01/27/22 13:10
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
87.0 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
02/01/22 15:37
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-3-Al
Parameters
Lab ID: 92585123002 Collected:
Report
Results Units Limit
01/27/22 11:25
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
78.0 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 1.0
1.0 1
02/01/22 15:37
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-5-Al
Parameters
Lab ID: 92585123003 Collected:
Report
Results Units Limit
01/27/22 11:55
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
128 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 254OD-2011
Pace Analytical Services -Asheville
Total Suspended Solids
23.1 mg/L 2.8
2.8 1
02/01/22 15:38
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-6-Al
Parameters
Lab ID: 92585123004 Collected:
Report
Results Units Limit
01/27/22 12:30
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
45.0 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
20.0 mg/L 2.7
2.7 1
02/01/22 15:38
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-8-Al
Parameters
Lab ID: 92585123005 Collected:
Report
Results Units Limit
01/27/22 12:15
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
476 mg/L 50.0
50.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
52.6 mg/L 2.0
2.0 1
02/01/22 15:38
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 22

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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-9-Al
Parameters
Lab ID: 92585123006 Collected:
Report
Results Units Limit
01/27/22 10:30
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
103 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
3.8 mg/L 1.0
1.0 1
02/01/22 15:39
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 22

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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-413-A1
Parameters
Lab ID: 92585123007 Collected:
Report
Results Units Limit
01/27/22 10:45
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
48.0 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
3.0 mg/L 1.0
1.0 1
02/01/22 15:40
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 22

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ANALYTICAL RESULTS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
Sample: SW-4C-Al
Parameters
Lab ID: 92585123008 Collected:
Report
Results Units Limit
01/27/22 11:15
MDL DF
Received: 01/28/22 14:10 Matrix: Water
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
55.0 mg/L 25.0
25.0 1
02/01/22 11:29
2540D TSS, Low -Level
Analytical Method: SM 2540D-2011
Pace Analytical Services -Asheville
Total Suspended Solids
1.0 mg/L 1.0
1.0 1
02/01/22 15:40
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 22

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QUALITY CONTROL DATA
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
QC Batch: 675086 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92585123001, 92585123002, 92585123003, 92585123004, 92585123005, 92585123006, 92585123007,
92585123008
METHOD BLANK: 3533521 Matrix: Water
Associated Lab Samples: 92585123001, 92585123002, 92585123003, 92585123004, 92585123005, 92585123006, 92585123007,
92585123008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 02/01/22 11:29
LABORATORY CONTROL SAMPLE:
3533522
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 3533523
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 3533524
Parameter
Units
Total Dissolved Solids
mg/L
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 250 100 90-110
92585119008 Dup Max
Result Result RPD RPD Qualifiers
694 688 1 25
92585145002 Dup Max
Result Result RPD RPD Qualifiers
74.0 75.0 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/08/2022 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 22

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QUALITY CONTROL DATA
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
QC Batch: 675210 Analysis Method: SM 2540D-2011
QC Batch Method: SM 2540D-2011 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92585123001, 92585123002, 92585123003, 92585123004, 92585123005, 92585123006, 92585123007,
92585123008
METHOD BLANK: 3533950 Matrix: Water
Associated Lab Samples: 92585123001, 92585123002, 92585123003, 92585123004, 92585123005, 92585123006, 92585123007,
92585123008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Suspended Solids mg/L ND 1.0 1.0 02/01/22 15:36
LABORATORY CONTROL SAMPLE:
3533951
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Suspended Solids
mg/L
251
244 97
90-110
SAMPLE DUPLICATE: 3534426
92585064001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Suspended Solids
mg/L
ND
ND
10
SAMPLE DUPLICATE: 3534427
92585123005
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Suspended Solids
mg/L
52.6
50.0
5 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/08/2022 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 22

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QUALIFIERS
Project: J22010450 ASA 21_213
Pace Project No.: 92585123
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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Date: 02/08/2022 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 22

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J22010450 ASA 2L2B
Pace Project No.: 92585123
Lab ID Sample ID QC Batch Method QC Batch
92585123001
SW-2-Al
SM
2540C-2015
675086
92585123002
SW-3-Al
SM
2540C-2015
675086
92585123003
SW-5-Al
SM
2540C-2015
675086
92585123004
SW-6-Al
SM
2540C-2015
675086
92585123005
SW-8-Al
SM
2540C-2015
675086
92585123006
SW-9-Al
SM
2540C-2015
675086
92585123007
SW-4B-A1
SM
2540C-2015
675086
92585123008
SW-4C-Al
SM
2540C-2015
675086
92585123001
SW-2-Al
SM
2540D-2011
675210
92585123002
SW-3-Al
SM
2540D-2011
675210
92585123003
SW-5-Al
SM
2540D-2011
675210
92585123004
SW-6-Al
SM
2540D-2011
675210
92585123005
SW-8-Al
SM
2540D-2011
675210
92585123006
SW-9-Al
SM
2540D-2011
675210
92585123007
SW-4B-A1
SM
2540D-2011
675210
92585123008
SW-4C-Al
SM
2540D-2011
675210
Date: 02/08/2022 01:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 19 of 22

Document Name:
Document Revised: November 15,
+
aceAalyfrcal
Sample Condition Upon Recelpt (SCUR
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.08
Pace Carolinas quality Office
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersvilleo/ Raleigh❑
Courier:
❑ Commercial
__ _Custody Seal Present?--
)f 96
Mechanicsville[] Atlanta❑ Kernersville❑
,,. WO#:92585123
iuu5123immuiim
Date/Inhiais Person Examining Contents: ` 1 1? J gZ
Packing Material: ❑Bubble Wrap ❑Bubble Bags lone ❑' Other Biological Tissue Fr P.
Thermometer ❑Yes ❑No /A
R Gun ID:t []Blue❑Nave
Type of Ice:
U A) [arrectlon Factor.
Cooler Temp: J • ��:L- Add/Subtract i°C1 _i Temp should be above freezing to 6°C
[:]Samples out of temp criteria. Samples on ice, cooling process
olerFempfarrected#'Cj. 1v as Ngdn
USDA Regulated Sall { `�J'A, water sample)
Did {sa Imples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Old samples originate from a foreign source [internationally,
p
1 IY25 FINe u.... I; -A e....- a ­ 1 I`r..__ M..
Cl ent Name:
Proj
4
EX
P5 sps ❑Client
❑Other:
❑Yes --- to-Sealslntatt? ❑Yes
Comments/Discrepancy:
Chain of Custody Present?
es
❑No
❑N/A
1.
Samples Arrived within Hold Time?
a Y
[]No
[]N/A
2.
Short Hold Time Analysis (c72 hr.)?
OYes
V4
DNIA
3.
Rush turn Around Time Requested?
Elves
JD4
❑N/A
4.
Sufficient Volumes
es
❑No
_]N/A
S.
Correct Containers Used?
-Pace Containers Used?
es
M r:
❑n}o
®No
[_-]N/A
❑N/A
6.
Containers Intact?
es
[-]No
N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Y s
[]No
NJN/A
S.
Sample Labels Match C00
-Includes Date/Time/ID/Ana[ysis Matrik:
es
V�r
[-]NO
❑N/A
9.
ace in VOA Vials (a5.6mmi?
Elves[]NoQi/A
10.
reads
ip Blank Present?
Blank Custody Seals Present?
[:]Yes
[]Yes
❑No
[]No
/Aip
%A
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted,
Date/Time;
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Field Data Required? Elves ❑No
Page 20 of 22

e,
dceAnalytical
DOCUment Name:
Sample Condition Upon Recelpt (SCUR)
Document Revised: November 15,120§la 6
Page 2 of Z
Document No.:
Issuing Authority:
F-CAR-CS-033•Rev.08
Pace Carolinas Quality Office
*Check marls top half of box If pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, CcUorm, TOC, Oil and Grease, DRO/8015 {water) DOC, LLHg
**Bottom half of box is to list number of bottles
Project #WO# : 92585123
of 96
PM: NMG Due Date: 02/04/22
CLIENT: 92-Duke Ener
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Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot 4
adjusted added
Note: whenever here is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina D£HNR Cenification office il.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 21 of 22

Auk► Energy Analytical Laboratory
DUKE i
Mau cm. MGo3ta laoenmr 1r031 I !Older#
ENERGY. ,°y° R•a�• r¢rry Rd ! I
Hu¢,n...ul¢, H. c. seore !
I7W1 e13 3241 II.D�ed�
__ „a: lee {16.60)e i i
roject Name 2L-28 SURFACE WATER^^
SAMPLING
Ilent JOHN TOEPFER,BRYAN MOELLER, !PO
EE O'BRIEN, JOSH STOWE, SYNTERRA i
u Preeeaa; BENVYVS Account:
Activity kk): Facllfty In: ASA
Code: ASA12L20 I Sub-ProgramlTask Code:
Sample Description or ID
Sw^�, 1
CHAIN OF CUSTODY RECORD AND ANALYSIS -- REQUEST FORM
_._ _._._.._-_- _ -----._._._,_.-._-_,_.-.----------
---
Analytic lto use only
._._._._._._.
ii� �, J�1 ��1 aMatrix WATER
e al�
Pace r--.._..- --- C•.r_. p.
Filtration (0.45 um, PO # 9172712
I
I Preservative
Container Volume (mL)
Container Type
5
Customer to camplafo all approPNara non -shaded areas.
Collection Informatton Tno
Time Prin Name Sl nal re
l % IO AP' e n r. �S
I
NC X_
sc=
SAMPLE PROGRAM
Ground Waler_X_ NPDLS_
Drinking Water_ UST
RCRA waste
a3 Unfittered
ICE
ICE
H2SO4,
Ice
2000
300
250
500
PET
PET
HOPE
HOPE
X m
Cr
< Q
_
H
4 U
V m
w w
V] 63
J m
r w
LL: X
Cl
w
U U
�!1
I
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01
Page 62 of 96 N
O
Page _1_ of 2_
DISTRIBUTION N
ORIGINAL to LAB, COPY to CLIENT
Cu
a
3122l2021 DUKE TESTS
u
Filtered
HNo3
250
ROPE
w
w
w �
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1
0
!
TOTAL!! CONTAINERS 0 i 1 1
0 7
0 �00 0 0
0 5
sta r to a a bclow
Dalal'Ti� ma�
Acuptad By: ;'. DatelTinw
,0 -� //5 L•-»-.
u
Ruquested Turnaround
Total 5
Y 0019fItrle
Accepted By:
E
/
21 Days
p• Q
�1
I /fir
to Days
Y OaWTinw 1
Accepted By: 1 UateMme
L v
Oataffime
SaakMlLgck Opened BYvatenThial
'7 Days
E a
NOTE: EQUIS EDO NEEDED
ELEMENTS by ICP_M$(TRM); Sb, As, Be, Cd LL, Cr, Co, Cu, Pb_LL, Mo, Ni, So, Ag_LL, TILL, V_LL
m`
a
"Other
ELEMENTS by ICP(TRM): Al, Ba, e, Ca, Fe, Mg, Mn, K, No, Sr, Zn, Total Hardness
a
• Add. Cost Will Apply
DISSOLVED METALS: At1 Metals: ICP DIS TRM (excl g C M , K, Na), IMS_DIS TRM 0

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[phone]
February 07, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: 21--213 SW J22010450
Pace Project No.: 92584955
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 27, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D � a -,-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 33

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[phone]
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 33

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SAMPLE SUMMARY
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92584955001
SW-2-Al
Water
01/27/22 13:10
01/27/22 14:20
92584955002
SW-3-Al
Water
01/27/2211:25
01/27/22 14:20
92584955003
SW-5-Al
Water
01/27/2211:55
01/27/22 14:20
92584955004
SW-6-Al
Water
01/27/22 12:30
01/27/22 14:20
92584955005
SW-8-Al
Water
01/27/2212:15
01/27/22 14:20
92584955006
SW-9-Al
Water
01/27/22 10:30
01/27/22 14:20
92584955007
SW-413-A1
Water
01/27/2210:45
01/27/22 14:20
92584955008
SW-4C-A1
Water
01/27/2211:15
01/27/22 14:20
92584955009
ASA FB-20220127-1250
Water
01/27/22 12:50
01/27/22 14:20
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 3 of 33

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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
2L-2B SW J22010450
92584955
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92584955001
SW-2-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955002
SW-3-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955003
SW-5-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955004
SW-6-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955005
SW-8-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955006
SW-9-Al
RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955007
SW-413-A1
RSK 175 Modified
MAD
1
PASI-C
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955008 SW-4C-Al RSK 175 Modified
MAD
1
PASI-C
EPA 1631E
NMP
1
PASI-A
EPA 1631E
NMP
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 218.7 Rev 1.0 2011
CDC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
92584955009 ASA FB-20220127-1250 EPA 1631E
NMP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Lab Sample ID Client Sample ID
Method Parameters
92584955001
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584955002
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
92584955003
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584955004
RSK 175 Modified
EPA 1631 E
EPA 1631 E
92584955005
RSK 175 Modified
92584955006
RSK 175 Modified
EPA 1631 E
EPA 1631 E
EPA 353.2 Rev 2.0 1993
92584955007
RSK 175 Modified
EPA 353.2 Rev 2.0 1993
92584955008
RSK 175 Modified
EPA 1631 E
EPA 218.7 Rev 1.0 2011
EPA 353.2 Rev 2.0 1993
SW-2-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-3-Al
Methane
Mercury
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SW-5-Al
Methane
Mercury
Mercury, Dissolved
Nitrogen, NO2 plus NO3
SW-6-Al
Methane
Mercury
Mercury, Dissolved
SW-8-Al
Methane
SW-9-Al
Methane
Mercury
Mercury, Dissolved
Nitrogen, NO2 plus NO3
SW-46-Al
Methane
Nitrogen, NO2 plus NO3
SW-4C-Al
Methane
Mercury, Dissolved
Chromium, Hexavalent
Nitrogen, NO2 plus NO3
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
20.3
ug/L
10.0
01 /31 /22 15:21
1.28
ng/L
0.50
02/02/2213:56
0.707
ng/L
0.50
02/03/2214:21
0.092
ug/L
0.025
01 /30/22 03:39
2.5
mg/L
0.040
01/31/2214:31
21.6
ug/L
10.0
01 /31 /22 15:36
0.810
ng/L
0.50
02/02/2214:19
0.862
ng/L
0.50
02/03/2214:44
0.058
ug/L
0.025
01 /30/22 03:55
1.2
mg/L
0.040
01/31/2214:32
1420
ug/L
10.0
01 /31 /22 15:51
0.726
ng/L
0.50
02/02/2214:27
0.975
ng/L
0.50
02/03/2214:52
0.091
mg/L
0.040
01/31/2214:34
486
ug/L
10.0
01 /31 /22 16:07
0.514
ng/L
0.50
02/02/2214:35
0.716
ng/L
0.50
02/03/2215:00
14100
ug/L
10.0
01 /31 /22 16:22
19.7
ug/L
10.0
01 /31 /22 16:37
0.627
ng/L
0.50
02/02/2214:50
0.667
ng/L
0.50
02/03/2215:23
0.13
mg/L
0.040
01/31/2214:39
38.5
ug/L
10.0
01 /31 /22 16:52
0.33
mg/L
0.040
01/31/2214:40
54.8
ug/L
10.0
01 /31 /22 17:07
0.581
ng/L
0.50
02/03/2215:39
0.12
ug/L
0.025
01 /30/22 07:27
0.56
mg/L
0.040
01/31/2214:41
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Method: RSK 175 Modified
Description: RSK 175 Headspace
Client: Duke Energy
Date: February 07, 2022
General Information:
8 samples were analyzed for RSK 175 Modified by Pace Analytical Services Charlotte. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Method: EPA 1631 E
Description: 1631 E Mercury,Low Level
Client: Duke Energy
Date: February 07, 2022
General Information:
9 samples were analyzed for EPA 1631 E by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 1631 E with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Method: EPA 1631 E
Description: 1631 E Mercury,LL Lab Filtered
Client: Duke Energy
Date: February 07, 2022
General Information:
8 samples were analyzed for EPA 1631 E by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 1631 E with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Method: SM 4500-S2D-2011
Description: 4500S2D Sulfide Water
Client: Duke Energy
Date: February 07, 2022
General Information:
8 samples were analyzed for SM 4500-S2D-2011 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Method: EPA 218.7 Rev 1.0 2011
Description: 218.7 Chromium, Hexavalent
Client: Duke Energy
Date: February 07, 2022
General Information:
8 samples were analyzed for EPA 218.7 Rev 1.0 2011 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Method: EPA 353.2 Rev 2.0 1993
Description: 353.2 Nitrogen, NO2/NO3 pres.
Client: Duke Energy
Date: February 07, 2022
General Information:
8 samples were analyzed for EPA 353.2 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-2-Al Lab ID: 92584955001 Collected: 01/27/22 13:10 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
20.3 ug/L 10.0
1
01/31/22 15:21 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
1.28 ng/L 0.50
1 02/01/2214:30
02/02/2213:56 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.707 ng/L 0.50
1 01/29/2213:51
02/03/2214:21 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:53 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.092 ug/L 0.025
1
01/30/22 03:39 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
2.5 mg/L 0.040
1
01/31/2214:31
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-3-Al Lab ID: 92584955002 Collected: 01/27/22 11:25 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
21.6 ug/L 10.0
1
01/31/2215:36 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.810 ng/L 0.50
1 02/01/2214:30
02/02/2214:19 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.862 ng/L 0.50
1 01/29/2213:51
02/03/2214:44 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:53 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.058 ug/L 0.025
1
01/30/22 03:55 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
1.2 mg/L 0.040
1
01/31/2214:32
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-5-Al Lab ID: 92584955003 Collected: 01/27/22 11:55 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
1420 ug/L 10.0
1
01/31/2215:51 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.726 ng/L 0.50
1 02/01/2214:30
02/02/2214:27 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.975 ng/L 0.50
1 01/29/2213:51
02/03/2214:52 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:53 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/30/22 04:11 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.091 mg/L 0.040
1
01/31/2214:34
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-6-Al Lab ID: 92584955004 Collected: 01/27/22 12:30 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
486 ug/L 10.0
1
01/31/2216:07 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.514 ng/L 0.50
1 02/01/2214:30
02/02/2214:35 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.716 ng/L 0.50
1 01/29/2213:51
02/03/2215:00 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:54 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/30/22 04:28 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.040
1
01/31/2214:35
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-8-Al Lab ID: 92584955005 Collected: 01/27/22 12:15 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
14100 ug/L 10.0
1
01/31/2216:22 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 02/01/2214:30
02/02/2214:43 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/29/2213:51
02/03/2215:16 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:54 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/30/22 04:44 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.040
1
01/31/2214:38
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-9-Al Lab ID: 92584955006 Collected: 01/27/22 10:30 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
19.7 ug/L 10.0
1
01/31/2216:37 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.627 ng/L 0.50
1 02/01/2214:30
02/02/2214:50 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.667 ng/L 0.50
1 01/29/2213:51
02/03/2215:23 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:55 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/30/22 05:33 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.13 mg/L 0.040
1
01/31/2214:39
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-413-A1 Lab ID: 92584955007 Collected: 01/27/22 10:45 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
38.5 ug/L 10.0
1
01/31/22 16:52 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 02/01/2214:30
02/02/2214:58 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 01/29/2213:51
02/03/2215:31 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:55 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
ND ug/L 0.025
1
01/30/22 07:11 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.33 mg/L 0.040
1
01/31/2214:40
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: SW-4C-A1 Lab ID: 92584955008 Collected: 01/27/22 11:15 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Methane
1631E Mercury,Low Level
Mercury
1631E Mercury,LL Lab Filtered
Mercury, Dissolved
4500S213 Sulfide Water
Sulfide
218.7 Chromium, Hexavalent
Chromium, Hexavalent
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
Date: 02/07/2022 01:02 PM
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
54.8 ug/L 10.0
1
01/31/2217:07 74-82-8
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
ND ng/L 0.50
1 02/01/2214:30
02/02/2215:06 7439-97-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
0.581 ng/L 0.50
1 01/29/2213:51
02/03/2215:39 7439-97-6
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND mg/L 0.10
1
02/01/22 02:56 18496-25-8
Analytical Method: EPA 218.7 Rev 1.0 2011
Pace Analytical Services -Asheville
0.12 ug/L 0.025
1
01/30/22 07:27 18540-29-9
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.56 mg/L 0.040
1
01/31/2214:41
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Sample: ASA_FB-20220127-1250 Lab ID: 92584955009 Collected: 01/27/22 12:50 Received: 01/27/22 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services -Asheville
Mercury ND ng/L 0.50 1 02/01/2214:30 02/02/2213:33 7439-97-6
Date: 02/07/2022 01:02 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
QC Batch: 674984 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
METHOD BLANK: 3532989 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Methane ug/L ND 10.0 01/31/2217:23
LABORATORY CONTROL SAMPLE: 3532990
Parameter Units
Methane ug/L
MATRIX SPIKE SAMPLE: 3536513
Parameter Units
Methane ug/L
SAMPLE DUPLICATE: 3536512
Parameter Units
Methane ug/L
Spike LCS LCS
Conc. Result % Rec
396 360 91
% Rec
Limits Qualifiers
70-130
92584941002 Spike MS MS
Result Conc. Result % Rec
2300 396 2620 79
% Rec
Limits Qualifiers
70-130
92584941001 Dup Max
Result Result RPD RPD Qualifiers
330 326 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
QC Batch: 675264 Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury,Low Level
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008,92584955009
METHOD BLANK: 3534137 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008,92584955009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 02/02/2213:16
METHOD BLANK: 3534138 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008,92584955009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 02/02/2213:40
METHOD BLANK: 3534139 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008,92584955009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 02/02/2215:14
LABORATORY CONTROL SAMPLE: 3534140
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ng/L 5 4.30 86 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3534141 3534142
MS MSD
92584955001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ng/L 1.28 25 25 24.3 25.1 92 95 71-125 3 24
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2022 01:02 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
QC Batch: 674825
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E
Analysis Description: 1631E Mercury, Dissolved Low Level
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
METHOD BLANK: 3532109
Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury, Dissolved ng/L
ND 0.50 02/03/22 14:06
METHOD BLANK: 3532110
Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury, Dissolved ng/L
ND 0.50 02/03/22 15:08
METHOD BLANK: 3532111
Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury, Dissolved ng/L
ND 0.50 02/03/22 15:47
LABORATORY CONTROL SAMPLE: 3532112
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury, Dissolved ng/L
5 4.97 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532113 3532114
MS MSD
92584955001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury, Dissolved ng/L 0.707 25 25 24.6 24.1 96 94 71-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2022 01:02 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
QC Batch: 675094 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
METHOD BLANK: 3533554 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 02/01/22 02:45
LABORATORY CONTROL SAMPLE: 3533555
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L 0.5 0.50 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533556 3533557
MS MSD
92585003003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.53 0.53 105 105 80-120 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533558 3533559
MS MSD
92585003002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide mg/L ND 0.5 0.5 0.54 0.53 106 105 80-120 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2022 01:02 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
QC Batch: 674473 Analysis Method: EPA 218.7 Rev 1.0 2011
QC Batch Method: EPA 218.7 Rev 1.0 2011 Analysis Description: 218.7 Chromium, Hexavalent
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
METHOD BLANK: 3530358 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L ND 0.025 01/29/22 23:01
LABORATORY CONTROL SAMPLE: 3530359
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L 0.1 0.097 97 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530360 3530361
MS MSD
92584914015 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND 0.1 0.1 0.099 0.099 99 99 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530362 3530363
MS MSD
92584955005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND 0.1 0.1 0.093 0.097 93 97 90-110 4 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2022 01:02 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
QC Batch: 674841 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
METHOD BLANK: 3532172 Matrix: Water
Associated Lab Samples: 92584955001, 92584955002, 92584955003, 92584955004, 92584955005, 92584955006, 92584955007,
92584955008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L ND 0.040 01/31/22 14:18
LABORATORY CONTROL SAMPLE: 3532173
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532174 3532175
MS MSD
92582927035 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.50 2.5 2.5 3.0 2.9 98 98 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532176 3532177
MS MSD
92582927036 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.16 2.5 2.5 2.6 2.6 98 98 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2022 01:02 PM without the written consent of Pace Analytical Services, LLC.
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QUALIFIERS
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 2L-2B SW J22010450
Pace Project No.: 92584955
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92584955001
SW-2-Al
RSK 175
Modified
674984
92584955002
SW-3-Al
RSK 175
Modified
674984
92584955003
SW-5-Al
RSK 175
Modified
674984
92584955004
SW-6-Al
RSK 175
Modified
674984
92584955005
SW-8-Al
RSK 175
Modified
674984
92584955006
SW-9-Al
RSK 175
Modified
674984
92584955007
SW-4B-A1
RSK 175
Modified
674984
92584955008
SW-4C-Al
RSK 175
Modified
674984
92584955001
SW-2-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955002
SW-3-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955003
SW-5-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955004
SW-6-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955005
SW-8-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955006
SW-9-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955007
SW-4B-A1
EPA 1631 E
675264
EPA 1631 E
675526
92584955008
SW-4C-Al
EPA 1631 E
675264
EPA 1631 E
675526
92584955009
ASA FB-20220127-1250
EPA 1631 E
675264
EPA 1631 E
675526
92584955001
SW-2-Al
EPA 1631 E
674825
EPA 1631 E
674826
92584955002
SW-3-Al
EPA 1631 E
674825
EPA 1631 E
674826
92584955003
SW-5-Al
EPA 1631 E
674825
EPA 1631 E
674826
92584955004
SW-6-Al
EPA 1631 E
674825
EPA 1631 E
674826
92584955005
SW-8-Al
EPA 1631 E
674825
EPA 1631 E
674826
92584955006
SW-9-Al
EPA 1631 E
674825
EPA 1631 E
674826
92584955007
SW-4B-A1
EPA 1631 E
674825
EPA 1631 E
674826
92584955008
SW-4C-Al
EPA 1631E
674825
EPA 1631E
674826
92584955001
SW-2-Al
SM 4500-S2D-2011
675094
92584955002
SW-3-Al
SM 4500-S2D-2011
675094
92584955003
SW-5-Al
SM 4500-S2D-2011
675094
92584955004
SW-6-Al
SM 4500-S2D-2011
675094
92584955005
SW-8-Al
SM 4500-S2D-2011
675094
92584955006
SW-9-Al
SM 4500-S2D-2011
675094
92584955007
SW-4B-A1
SM 4500-S2D-2011
675094
92584955008
SW-4C-Al
SM 4500-S2D-2011
675094
92584955001
SW-2-Al
EPA 218.7 Rev 1.0 2011
674473
92584955002
SW-3-Al
EPA 218.7 Rev 1.0 2011
674473
92584955003
SW-5-Al
EPA 218.7 Rev 1.0 2011
674473
92584955004
SW-6-Al
EPA 218.7 Rev 1.0 2011
674473
92584955005
SW-8-Al
EPA 218.7 Rev 1.0 2011
674473
92584955006
SW-9-Al
EPA 218.7 Rev 1.0 2011
674473
92584955007
SW-4B-A1
EPA 218.7 Rev 1.0 2011
674473
92584955008
SW-4C-Al
EPA 218.7 Rev 1.0 2011
674473
92584955001
SW-2-Al
EPA 353.2 Rev 2.0 1993
674841
92584955002
SW-3-Al
EPA 353.2 Rev 2.0 1993
674841
92584955003
SW-5-Al
EPA 353.2 Rev 2.0 1993
674841
92584955004
SW-6-Al
EPA 353.2 Rev 2.0 1993
674841
92584955005
SW-8-Al
EPA 353.2 Rev 2.0 1993
674841
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/07/2022 01:02 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 33

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
og8�I i2c6r�e. Suite 100
�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 21--213 SW J22010450
Pace Project No.: 92584955
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
92584955006
SW-9-Al
EPA 353.2 Rev 2.0 1993
674841
92584955007
SW-4B-A1
EPA 353.2 Rev 2.0 1993
674841
92584955008
SW-4C-Al
EPA 353.2 Rev 2.0 1993
674841
Date: 02/07/2022 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 30 of 33

Page 93 of 96
Document Name: Document Revised: November 15, 2021
Y /_*,;81Ce Afk?iyhC � Sample Condition Upon Receipt (SOUR) Page ! of 2
DocurnentNo.: Issuing Authority:
_— - -- F-CAR-CS-033•Rev.08 Pace Carolinas Quality Office
Laboratory rec w tngsamples:
Asheville LZI Edens Greenwood n Huntersvilie []
Raleighr j Mechan(csville❑ Atlanta❑ Kernersville[]
G nt Name:
� ��
WO#: 92554955��
'.'LiLt�irj'i � =2Clie-
�Si� v
Project
#:
Gautier: L]fe (JUPS []LISPS---
— !lent
IIlI!lIIIlIIIlI�!
❑ Co fil I flerc id I []Pace ❑other._//�
925 935
� Custody seal Present? ye5 ❑No Seals Intact? LAYcs
FIN.
Date/Initials Person Examining Contents:.�_•�_1_Z7
Packfnp Material: L]Rubble Wrap LJRubbfe Bags [-IN
El Other
Biological Tissue Frozen? II
Therrttometer: T �r
2
❑
(]yes ❑No P/A
[Blue None
EltR Cron I[)-�]�Q- (� Type of Ice:
Correction Factor:
Cooler Temp: Ll a=C - Add/Subtract (T)
Temp should be above freezing to G'C
Cooler T'ervip Corrected (3 �jkl5 •E�-
05arnpins out Of lemn Criteria. Santpies on ice, cooling process
Ira; br,;un
USDA RegUlMed Soil (H N/A, water sample)
Did sam pits originate in a Quarantine done within this Unitd States. CA, NY, or SC (dteck maps)?
Did sarnptes originate from a foreign soance jiaternationally,
❑Yes ❑No
fnduding Ilawaii and Puerto Ricoi? []yes ❑No
Comfit ants/Discrepancy:
Chaain of custody Present?
5anlples Arrived within Hold Time?
Short Hold Time Analysis (,;72 hr.)?
Rush Turn Around Time Requested;
Sufficient Volume? - --
CorrrctContainers Used?
-Pace Containers Used?
Containers Irstaaa?
Dissolved analysis_ Samples Field riltered?
5arrrple Wbeis klatch CDC?
025
OYrs
[]No
❑Nn
❑N/A
❑NJr1
1.
2.
�_x_...A_ ❑Yes
VNo
❑NIA
_
3.
[- o
❑NIA
d.—_ --_
,,❑.�Y//e5
C]Na
(I NIA
5.
dyes
--- J��es
❑No
[]N0
❑NIA
❑N/,1
_
6.
es
❑Na
❑N/A
7.
❑yes
ONO
0%ol-
19.
$.
13'y'e
❑No
❑,%1M
-includes t7ateJ3ime/IU/Analysis Ma[rix:-___ Vtil [
4ead5pace rn VOA Vials (as-emmj? _ ❑Yes 126 ❑N/A
f TriFr t3lank sresent7 111 --------- ❑Yes- OVa ❑w/,1 Trip 6lartk Custody Seals Present? ( ]yes- ❑N. L).</.n
CUMivtENTS/5AlVIPif DISCREPANCY
CIIF. _,1IFICA1taN/H115011.1naN - - --- '-----�-- -
Personcontacted: - t IP[Timt
Lot ID of inlit containers:
Field Data Required? ❑Yes ❑No
Project Manager SCURF Review: �- _ __- - - Date:
Project Manager 5RF Review: Date:
Page 31 of 33

Page 94 of 96
27wnalyfic,44
Document Nance:
Sample Condition Upon Recef,
Document No.:
r-CAR-CS-433_Rev.07
*Cfieck mark top half of box if pH and/or deehlorination is
verified and within the acceptance range for preservation
samples,
Exceptfo,ts: VOA, Coliform, TOC, Oil and Grease, C)RO/8015 (water) DOC, Wig
**Bottom half of box is to list number of bottles
Document Nevisecl: October 28, 2020
rferttul I Page 2 of 2 ---
issuing Authority:
Pace Carolinas Quality office
Project # Wp# : 92584955
PM: NMG Due Date: 02/03/22
CLIENT: 92-Duke Ener
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sarlu�te In , Typo of Preservative pti upon rereipt once preservauon adjusted Tintea IJsted t1ar1 - ^ Attiaunt a(decdservative I Lot tl
Note: Whenever there fs a discrepancy affecting North Cargllna colapllancn ,amples, a cnµy of this fors,t+,ill ba semi to the North Carolina DENNH CerliFicallgR office, (i.e.
()U1 of hold, incorrect preservative, out of temp, Incorrect containers -
Page 32 of 33

Dukw Energy Analytical La boratcry
-� DUKE I MM CaauaGo] Le.aaa7w3l
" "Fk,,ENERGY N.C. UU
Treq 61y.52
*00t Name 2L-213 SURFACE WATER
SAMPLLIky I-
EE 179RIEN, JOSH STOW-NTERRAR -
Para4-ng Uni4 AEOO Pwcaos•8 E IN+WVS Account•,
_�_.lAclivity ID: T Facility 1i7: ASA
regnm } Eouis Took Cads; ASA W.2B Sub-PrognmrTwsk Code:
Sample Description or ID
SAMPLE ID
i
NUMBER
ASA
n1 !
ASA
_a
ASA
c
ASA
i I
I
i
ASA
.i
ASA_
ASA
S ✓'=
ASA;.':
ASA
•.
ASA
i
ASA
ASA
ASA
ii-
-
-.
ASA
'
ASA EB
CHAIN OF CUSTODY R
-------------
PACE
'ORD AND ANALYSIS REQUEST FORM
Page 95 of 96 M
•
_.-� '
use on(-•-...---•-•-•---------._._._._._._-APIA._.�._._-------•-•------>
eel Laboraio
O
Matrix WATER
a•4,r
NC x
SC
+ Page _2_of 2 M
'• DISTRIBUTION M
. .......
.___r0ated Tarn
--�
SAMPLE PROGRAM
i ORIGINAL to LAB. COPY to CLIENT
_�__.-._._.,_.......-._...._..,...._._.... _.,_,
._. _.. _- I, Ground Wate7_X_ NPDES_
co
Drinking Water UST
d..
pL}._.._...:.._.....----.._.._.._..
RCRA Wane-�_......_.._......._
3/22(2021 PACE TESTS
.... :--
Filtration (0.45 uml
u
Unfiltered
b
Filtered
t Preservative
ICE
NONE w
H2504•ICE
Container Volume (mL)
AO
250
250 250
250
Container Type
CUSS
PET
GLASS
HOPE
HOPE
J'
T
csu mo, to cwrtoleta alf appropriate aon hadad area& O 1'
w .-. W IIJ ~ 2 m W W °
-.........--'-- __ Collecturn Infotmotion i s Y¢ a a
m IL j Z Q
-- �r,d
Date Time Printed Name Si natu etl f >' tq YI x ? U ? Z ?
J'cIJr•u .J li hS,• LC �'�' o
-A_ 2 0
-- --- -I �-, - 2, 0
3
0
....._ .......
ASA�FB-
i
RclinAwahed� Oaterrme14-
A,°cepte6 Bq:
Rclinqu+shea By Daternine AbGepted By: -
Sealil—ked By --- DaLerTime--^��--SealedfLQtk cd By
NOTE: EQUIS EDD NEEDED
w
t
I
TOTAL x CONTAINERS
............... Datrmmw
Doteltime
Q
1 0 0 0 0 0 0 j a I s
Requested Turnaround
21 Days
14 Days
-7 Days
-other
' Add. Cost Will Apply
Total E

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
M
_._I I............................................................................................................................. ._._._._._._._._._._._._._._._._._._.-
!� DUKE Duke Energy Analytical Laboratory I Analytical LaboratoryUse Only—
Mell Code MG03A2 Matrix WATER NC_)L !
7405) I !Order #).:I
Page of 2
/ (Buddlna
1nter MiQ, ' !
�d 1i
Sempbe orlpined,p
From
sD_ !
_1_
DISTRIBUTION
N.C.Feryad
ENERGY. Hanle(704) , 2807e i
Time
ORIGINAL LAB, COPY CLIENT
5- iLoggsd ey
pa) 57s-saes
! !
Data a
/�
✓
SAMPLE
PROGRAM
!
to to
_-_-_-_•_,-,_,-,_,_--,--_•_•_,_,_• Fu:—vy)e75aoae._
Project Name 2L-2B SURFACE WATER Phone No: ivar'""
_ _ _
Ground
Water
Drinking Water
_X_
_
NPDES_
UST
21D
PLIN
Client JOHN TOEPFER,BRYAN MOELLER, !Po
Pace
_ _ _ _ _._ cooler Te .ip�C1._.._..
.._.. _.._.._.._.._.._RCRA
Waste_
_.._ _ .._.._.
DEE O'BRIEN, JOSH STOWE, SYNTERRA
�i }� 7
O # 9171712 1 7' 2
Filtration (0.45 um)
b
Unfiltered
b ed
Operating Unit: AE00 Process: BENVWS Account: I
■
i Preservative
ICE
H2soa,
ICE
.an.we
Project: Activity ID: Facility ID: A-
Container Volume (mL)
300
250
500
t
Program /EQuIS Task Code: ASAl2L28 Sub-ProgramlTask Code:
Container Type
r
PET
HDPE
HDPE
0
In
y
a s
O U
a
Customer to complete all appropriate non -shaded areas. i y rc
o U
0 m
p
In
—
In
c
Sample Description or ID
m
a
J 3
O a
a
I.._.._.._.._.._.._..,
i SAMPLE ID I
Collection Information
(n
w<
W w
O
N w w
o
i NUMBER i Date
Tims Pri d Name
SI na ra o
U U
F
y
0 f m
E•
�QAV
ASA_ ^ -A
°
ASA
°
�>
Ask s W- A I •
I/55
/
i
/
I
0
! !
ASA )J -
°
ASA_ W - -'A I
1Jr
/
°
a�- 1 d
ASA CjLJ-�%`
i/ O
I
/
%
I
0
ASA - -A)
1C1q5
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/y!
ASA_ LA -N "_1
0
ASA
0
i
ASA
o
ASA_
o
1 �
ASA
0
ASA_
o
ASA_
°
ASA_EB
4
13 1
ASA FtB
—
ri
o
i
°
! !
i I
TOTAL M CONTAINERS
0
1
1
1
0
1
0
0
0
0
0
1
0
5
Rslinquis DatdTima
Accepted By: DatelTime
y
'v
'0 -0
Requested Turnaround
21 Days
linquished By batelTime
Accepted By: - � / Date rime /
c
a m
.. E
14 Days ji / Ifr—
Relinquished By Dateffirre
Accepted By: /) / DatelTime
m
SeallLocked By Data/rims
saaladlLoek Opened By DatelTime
o.
'a
'7 Days
E
•- d
d a
Comments NOTE: EQUIS EDO NEEDED
ELEMENTS by ICP_MS(TRM): Sb, As, Be, Cd_LL, Cr, Co, Cu, Pb LL, Mo, N!, Se, Ag_LL, TILL, V_LL
o
'Other
ELEMENTS by ICP(TRM): Al, Be, B, Ca, Fe, Mg, Mn, K, Na, Sr, Zn, Total Hardness
*Add. Cost Will Apply
DISSOLVED METALS: All Metals: ICP DIS_TRM (excluding Ca, Mg, K, Na), IMS_DIS_TRM
v
Total