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3404_Forsyth_Kernersville_MSWLF_CAER_FID1656891_20220319
Electronic DocJEvent #: NC DENR ' ' Environments! Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records' as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit Please type or print legibly. Attach a notification table with values that attain or exceed NG 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility(NCAC 13B A629 (4)(8)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to Compliance Unit, NCDENR-DWM. Sand Waste Section, 1645 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of @ra ty submitting data (laboratory, consultant, facility owner): WithersRavenel, Inc. Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address: Name: Mark Brown, LG, PG, RSM E-mail: mbrown(Dwithersuavenel.com Phone: 919.469,3340 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Faclltty Permit # (.0500 or. 1600) October 20-24, 2006} Town of Kemersville Landfill Freeman Road 34-04 .0560 July 20, 2021 Kemersville, NC 27284 Environmental Status: (Check all that apply) InitiallBackground Monitoring 0 Detection Monitoring Assessment Monitoring Q Corrective Action T of data sufmmitted: (Check ail that apply) Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑X Corrective action data (specify) Corrective Action Evaluation Report Leachate monitoring data Other(specify) X Surface water monitoring data Notification attached? eNo. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Q Yes, a nobficabon of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant panaltles for making any false statement, representation, or certification Ineluding the possibility of a fine and imprisonment Mark Brown, LG, PG, RSM Senior Geologist 919-608.4562 Facili es Ntative Name (Print) Title (Area Cade) Telephone Number March 19, 2022 Affix NC Ucensedl Professional Geologist Seai Signature 424 Galli re Dairy Road, Suite C, Greensboro, NC 27409 Facility Representative Address C-082 NC PE Firm License Number (if applicable effective May 1, 2409) Revised &2009 Date NSARptf. �; WithersRavenel Our People. Your Success. March 19, 2022 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management -Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: Corrective Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.48 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached Corrective Action Evaluation Report (CAER) for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the July 2021 semiannual sampling report and historic data from the CAER Report submitted by Joyce Engineering in October 2016. Also attached is the North Carolina Environmental Monitoring Reporting Form for the July 2021 monitoring event. Please contact Butch Lawter at blawter@withersravenel.com with comments, questions, or requests. Sincerely WithersRavenel Mark Brown, LG, PG, RSM Senior Geologist Attachment C: Brad Beeson -Town of Kernersville, Solid Waste Superintendent 424 Gallimore Dairy Road, Suite C I Greensboro, NC 27409 t: 336.605.3009 1 f: 919.467.6008 1 www.withersravenel.com I License No. C-0832 Asheville I Cary I Charlotte I Greensboro I Pittsboro I Raleigh I Southern Pines I Wilmington 40 WithersRavenel NO Our people. Your Success. CORRECTIVE ACTION EVALUATION REPORT Town of Kernersville Landfill NCDEQ SWS Permit # 34-04 EXECUTIVE SUMMARY On behalf of the Town of Kernersville, North Carolina, WithersRavenel (WR) prepared this Corrective Action Evaluation Report (CAER) for the Town of Kernersville Landfill. The Kernersville Landfill is regulated under §.0500 of the North Carolina Solid Waste Management Rules (NCSWMR). This CAER has been prepared in accordance with those rules. In a letter dated July 16, 2013, the North Carolina Department of Environment and Natural Resource, now doing business as the North Carolina Department of Environmental Quality (NCDEQ), in response to the Groundwater Protection Standard (GPS) exceedances of volatile organic compounds (VOCs) in groundwater monitoring wells at the facility, called for the Town to select a remedy and submit a Corrective Action Application In July 2014, the Town submitted the Corrective Action Application, selecting Monitored Natural Attenuation (MNA) plus Phytoremediation as the remedy. The remedy was approved by NCDEQ-Solid Waste Section (Section) in a letter dated July 23, 2014. The Town submitted a Corrective Action Plan (CAP) in October 2014 and the Section approved the CAP in a letter dated November 4, 2014. At the request of the Section, the Town's environmental consultant at the time, Joyce Engineering (JOYCE), submitted a Corrective Action Evaluation Report (CAER) in October 2016 in accordance with the Section's Guidelines for Corrective Action Evaluation Reports. In their Conclusions and Recommendations, JOYCE recommended removing several of the MNA parameters from the parameter list for the site and reducing the frequency of MNA monitoring to twice per CAER period, during the two semiannual events immediately prior to the next, and subsequent, CAERs. In a response letter (DIN27098) to the Town dated December 6, 2016, the Section approved the request to remove cis-1,2-dicholorethylene from the COC list. However, the request to modify the MNA monitoring frequency for the requested MNA parameters was not approved but changed to continually monitoring them semi-annually (both sampling events) every three years. In their report, Joyce concluded that: • MNA plus phytoremediation remained an appropriate and effective remedy and no changes to the CAP were recommended at the time. • MNA plus phytoremediation remained an appropriate and effective remedy and no contingency remedies were recommended at the time. • There was no evidence that the contaminant plume had impacted the surface water in the creek or that the plume had migrated off site. • The current COC plume was reported as stable and concentrations of most COCs appeared to be decreasing; and • There was no need to impose land use restrictions on the landfill or adjoining property at the time. Executive Summary -Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 WithersRavenel March 2022 Page i of ii 40 WithersRavenel ki0 Our people. Your Success. This report presents the second CAER for the facility and includes historical data and comments recommendations previously reported by JOYCE, and subsequent sampling events conducted by WR between September 2017 and July 2021 (referred to in this report as the "recent sampling period"). Unless modified by the Section, subsequent CAERs will be submitted approximately every five years. Since October 2016, several of the constituents of concern (COCs) for the facility listed in the initial CAER have not been detected during the semi-annual water quality sampling events. The current list of COCs include the following VOCs: benzene, 1,1- dichloroethane (1,1-DCA), 1,2- dichlorethane (1,2-DCA), 1,2-dichloropropane (1,2-DCP), and vinyl chloride (VC). During the July 2021 groundwater sampling event low concentrations of four volatile organic compounds (VOCs) in addition to VC were identified in the groundwater sample from MW-2R. These included benzene (3.07 ug/L), 1,1 dichloroethane (1,1 DCA 9.24 ug/L), 1,2 dichloroethane (1,2 DCA 0.520 ug/L), and 1,2 dichloropropane (1,2 DCP 3.64 ug/L). Measurement of dissolved oxygen in the groundwater from MW-2R at the time of sampling was approximately 2.85 mg/L, which indicates the presence of aerobic conditions. Because benzene and vinyl chloride are known to be amenable to aerobic biodegradation, the EPA BIOSCREEN Natural Attenuation Decision Support System model was used to predict future concentrations of the four VOCs downgradient of MW-2R at a time ten years from the present. Due to the relatively low concentrations of VOCs in the July 2021 sample from MW-2R, and the slow rate of groundwater flow at the site, the BIOSCREEN runs predict that even under no degradation conditions, detectable concentrations of the VOCs should not be present in groundwater 25 to 50 feet downgradient of MW-2R within a ten-year period. Future monitoring of VOC concentrations in samples from MW-2R and within surface water samples from location SW-3, which is immediately downgradient of MW-2R can be used to evaluate the validity of the BIOSCREEN model predictions. This CAER presents plume maps and trend charts for each of the COCs. There is no evidence that the plume is expanding horizontally or vertically, and constituent concentrations are generally decreasing. TWR concludes that the current remedy is sufficient for remediating the groundwater at the Kernersville Landfill facility and recommends no changes to the CAP or the active remedy at this time. Executive Summary -Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page ii of ii WithersRavenel . ,4 Our People. Your Success. CORRECTIVE ACTION EVALUATION REPORT March 2022 Town of Kernersville Closed Landfill 9900 Freeman Road Kernersville, Forsyth County, North Carolina NCDEQ Permit ID #: 34-04 Prepared for: Town of Kernersville Public Works Department PO Box 728 Kernersville, North Carolina 27285 Prepared By. WithersRavenel, Inc. 424 Gallimore Dairy Road, Suite C Greensboro, North Carolina 27409 WR Project #: 06140180.39 March 19, 2022 Mati Maltba Environmental Technician I DG Mark MG PU, RSM Senior Geologist .. 4. Our People. Your Success. TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................................................ 1 1.1 Site Background.............................................................................................................. 1 1.2 Aquifer Characteristics.................................................................................................. 4 1.2.1 Groundwater Flow................................................................................................. 4 1.2.2 Vertical Gradient........................................................................................................... 5 1.3 Contamination Distribution.......................................................................................... 5 1.4 Site Conceptual Model.................................................................................................. 7 1.4.2 Site Hydrogeology................................................................................................. 7 1.5 Regulatory Status........................................................................................................... 8 2.0 CORRECTIVE ACTION SUMMARY............................................................................... 9 2.1 Physical and Chemical Changes in Aquifer Conditions .......................................... 9 2.2 Physical and Chemical Changes in Plume Characteristics...................................10 2.3 Refining the Site Conceptual Model.........................................................................10 2.4 Evaluation of the Impact of Corrective Actions.....................................................11 2.4.1 Contamination Levels..........................................................................................11 2.4.2 Evaluation of MNA Parameters........................................................................11 2.4.3 MNA Matrix Evaluation......................................................................................16 2.4.4 Evaluation of Phytoremediation.......................................................................16 2.4.5 Impacts on Hydraulic Gradients........................................................................16 2.4.6 Contaminant Removal Efficiencies and Mass of Contaminants Removed 17 2.5 Migration of the Contaminant Plume.......................................................................18 2.5.1 Status of Impacts at the Compliance Boundary............................................18 2.5.2 Off -Site Migration Concerns.............................................................................18 3.0 CONCLUSIONS AND RECOMMENDATIONS..........................................................19 QualityControl..........................................................................................................................20 3.2 Assessment of MNA Indicator Parameters.............................................................20 3.3 Modifications Needed to Selected Remedy...........................................................20 3.4 Contingency Plan.........................................................................................................21 3.5 Land Use Restrictions..................................................................................................21 4.0 REFERENCES....................................................................................................................22 Page i of iii ... to Our People. Your Success. Figures Figure 1 General Location Map Figure 2 Water Quality Sampling Locations Map Figure 3A Potentiometric Map January 2021 Figure 3B Potentiometric Map July 2021 Figure 4 Groundwater 2L/GWP Exceedances July 2021 Figure 5 Benzene Isoconcentration Map Figure 6 Cadmium Isoconcentration Map Figure 7 Chromium Isoconcentration Map Figure 8 1,1-Dichloroethane Isoconcentration Map Figure 9 1,2-Dicholorethane Isoconcentration Map Figure 10 1,2-Dicholorpropane Isoconcentration Map Figure 11 Thallium Isoconcentration Map Figure 12 Vinyl Chloride Isoconcentration Map Figure 13 Total VOCs Isoconcentration Map Figure 14 Benzene Concentrations vs Time Figure 15 Cadmium Concentrations vs Time Figure 16 Chromium Concentrations vs Time Figure 17 1,1-Dichloroethane Concentrations vs Time Figure 18 1,2-Dichloroethane Concentrations vs Time Figure 19 1,2-Dichloropropane Concentrations vs Time Figure 20 Thallium Concentrations vs Time Figure 21 Vinyl Chloride Concentrations vs Time Figure 22 Total VOC Concentrations vs Time Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents Table 7 EPA Biodegradation Screening Matrix Appendices Appendix I Laboratory Analytical Reports and Field Notes Appendix 11 BIOSCREEN Modeling Appendix III Historical Summary Tables (reproduced from JOYCE Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Page ii of iii .. 4. Our People. Your Success. ACRONYMS 2B Standards North Carolina Surface Water Standards listed in 15A NCAC 2B 2L Standards North Carolina Groundwater Quality Standards listed in 15A NCAC 2L ACM Assessment of Corrective Measures AOC Area of Concern BOD Biological Oxygen Demand BTEX Benzene, Toluene, Ethylbenzene and Xylenes CAP Corrective Action Plan CAER Corrective Action Evaluation Report COC Contaminant of Concern COD Chemical Oxygen Demand DL Detection Limit DO Dissolved Oxygen EPA United States Environmental Protection Agency GPS Groundwater Protection Standards (per 15A NCAC 13B.1634.g) GWPS SWS Groundwater Protection Standards HASP Health and Safety Plan JOYCE Joyce Engineering, Inc. LFG Landfill Gas LEL Lower Explosive Limit MNA Monitored Natural Attenuation MSW Municipal Solid Waste MW Monitoring Well NCAC North Carolina Administrative Code NCDENR North Carolina Department of Environment and Natural Resources NCDEQ North Carolina Department of Environmental Quality NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600) ND Not detected ORP Oxidation Reduction Potential OSHA Occupational Health and Safety Association QL Quantitation Limit QRA Quantitative Risk Assessment RA Risk Assessment RL Reporting Limit SVOC Semi -Volatile Organic Compound SWQS Surface Water Quality Standards SWS NCDEQ Division of Waste Management, Solid Waste Section SWSL North Carolina Solid Waste Section Reporting Limits TOC Total Organic Carbon VOC Volatile Organic Compound WQMP Water Quality Monitoring Plan WR WithersRavenel Page iii of iii ... to Our People. Your Success. 1.0 INTRODUCTION On behalf of the Town of Kernersville, WithersRavenel (WR) has prepared this Corrective Action Evaluation Report (CAER) for the Town of Kernersville Landfill Facility (facility). This CAER has been prepared in accordance with 15A NCAC 1313.1636 of the North Carolina Solid Waste Management Rules (NCSWMR) and in response to Groundwater Protection Standard (GPS) exceedances of several volatile organic compounds (VOCs) detected in groundwater monitoring wells at the facility. 1.1 Site Background The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres which straddle Forsyth and Guilford Counties, NC, approximately 10 miles north of the Town of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5-minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina Quadrangle (Quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM), Solid Waste Section (Section) on May 15, 1985, and a Letter of Closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. The Town of Kernersville Landfill is currently monitoring groundwater in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules (NCSWMR) for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. The current groundwater compliance monitoring network includes six monitoring wells, comprised of one upgradient well and five downgradient wells. There is relatively limited historical geological data available for the Kernersville landfill. Neither WR nor the previous consultant (Joyce Engineering (JOYCE) could locate drilling records or boring logs for wells on the property through a review of both the Town of Kernersville records and NCDEQ records. Existing monitoring well MW-6 serves as the background well for the facility. Monitoring well MW-6 replaced MW-1 as the facility's background well due to infrequent opportunities to sample the well because of low well volumes or the well-being dry; however, MW-6 has also been dry during the last several sampling events. Downgradient monitoring wells MW-2, MW- 3S, MW-3D, MW-4, and MW-5 are monitored as part of the compliance network for the facility. MW-1 is monitored for water levels only, as conditions permit. Monitoring well construction details are summarized in Table 1, and the well locations are shown on Figure 2 These wells are summarized below, along with their current monitoring program status. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 1 of 23 %0 10 Our People. Your Success. Monitoring Well Classification Monitoring Program Total Depth from TOC (feet) MW-1 Former Background Water Levels Only 34.69 MW-2 Compliance/MNA Detection(.0500)/CAP 13.18 MW-3S Compliance/MNA Detection(.0500)/CAP 24.00 MW-3D Compliance/MNA Detection(.0500)/CAP 56.96 MW-4 Compliance/MNA Detection(.0500)/CAP 14.40 MW-5 Compliance Detection (.0500) 11.36 MW-6 Background/MNA Detection(.0500)/CAP 20.46 I UC = I op of casing. CAN = Corrective Action Plan. Groundwater samples are collected semiannually during the second and fourth quarters and analyzed for constituents listed in the NC Solid Waste Section Environmental Monitoring Appendix I/Appendix II list (in reference to 40 CFR Part 258 Appendix I and Appendix II). As a condition of the CAP, monitoring wells MW-2, MW-3S, MW-3D, MW-4 and MW-6 are also monitored for Monitored Natural Attenuation (MNA) laboratory constituents, including nitrate, sulfate, chloride, alkalinity, total organic carbon, methane, ethane, ethene, volatile fatty acids, dissolved hydrogen, biological oxygen demand, and chemical oxygen demand, as well as several MNA field parameters, during both semiannual sampling events. Based on the presence of constituents detected at concentrations above the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the "21- Standards") that could potentially be crossing the facility boundary, the North Carolina Department of Environment and Natural Resources (NCDENR) requested that Kernersville submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to NCDENR on May 13, 2013. JOYCE, in their Report, concluded that, based on site hydrogeology, it is unlikely that the site impacts reported above the 2L Standards are crossing the property boundary. In a July 16, 2013, response to the Groundwater Assessment Report, NCDENR determined that the detection of VOCs at concentrations that exceeded the 2L Standards constituted a violation of Section regulations. As required by NCDENR, JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town of Kernersville Landfill in October 2014. NCDENR approved the Corrective Action Plan in a letter dated November 4, 2014. It should be noted that NCDENR is currently operating as the North Carolina Department of Environmental Quality (NCDEQ). At the request of the Section, JOYCE submitted a Corrective Action Evaluation Report (CAER) in October 2016 in accordance with the Section's Guidelines for Corrective Action Evaluation Reports. In their Conclusions and Recommendations, JOYCE concluded and recommended the following: • Cis-1,2-dichloroethylene had not been detected in exceedance of its GPS in any monitoring well since November 2012, and the concentrations of cis-1,2- dichloroethylene appear to be stable or decreasing in all wells. JOYCE recommended that cis-1,2-dichloroethylene be removed from the facility's COC list. No other changes to the COC list were recommended at that time. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 2 of 23 %10 4 go Our People. Your Success. Several of the extended MNA parameters listed in the MNA listing demonstrated limited usefulness in evaluating natural attenuation at this site. JOYCE recommended and requested that BOD and COD be removed from the MNA analytical requirements for this facility. JOYCE also recommended and requested reducing the frequency of MNA monitoring to twice per CAER period, during the two semiannual events immediately prior to the next, and subsequent, CAERs for the following MNA parameters: • Methane, ethane, and ethene • Dissolved CO2 • Volatile Fatty Acids • Ferrous Iron Wee+) In a response letter (DIN27098) to the Town dated December 6, 2016, the Section approved the request to remove cis-1,2-dicholorethylene from the COC list. However, the request to modify the MNA monitoring frequency for the above -listed MNA parameters was not approved but changed to continually monitoring them semi-annually (both sampling events) every three years. JOYCE concluded that MNA plus phytoremediation remained an appropriate and effective remedy and no changes to the CAP were recommended at the time. • JOYCE concluded that MNA plus phytoremediation remained an appropriate and effective remedy and no contingency remedies were recommended at the time. JOYCE concluded that there was no evidence that the contaminant plume had impacted the surface water in the creek or that the plume had migrated off site. The current COC plume was reported as stable and concentrations of most COCs appeared to be decreasing. JOYCE concluded that there was no need to impose land use restrictions on the landfill or adjoining property at the time. This report presents the second CAER for the facility and includes historical data and comments previously reported by JOYCE, and subsequent sampling events conducted by WR between September 2017 and July 2021(referred to in this report as the "recent sampling period"). Unless modified by the Section, subsequent CAERs will be submitted approximately every five years. Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Page 3 of 23 WithersRavenel March 2022 .. ,. Our People. Your Success. 1.2 Aquifer Characteristics The Town of Kernersville Landfill is located in the Piedmont Physiographic Province (Piedmont) of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian -to -Permian age, which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well-connected. Groundwater at the site has historically been reported flowing generally to the southwest. JOYCE conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft. • An effective porosity value (n) of 30 percent was estimated. • Hydraulic conductivity (K) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. As reported by JOYCE and confirmed by WR, the water table under the area of investigation is typically encountered in the unconfined aquifer that is located mostly in saprolite but is believed to grade into highly fractured bedrock with depth. Groundwater in the saprolite feeds the fractures in the bedrock and is discharged into creeks south and southwest of the landfill. Groundwater flow at deeper levels within the fracture bedrock is controlled by fracture orientation and connectivity. This unconfined aquifer is pervasive across the site and the water table generally mimics the surface topography. Historically, depth to groundwater at the site has ranged from approximately 2-5 feet below ground surface (BGS) on the downgradient (southwest) side of the site, to approximately 28- 33 feet BGS near the northeast corner of the landfill. During the recent sampling period, groundwater elevation has ranged from approximately 790 feet above mean sea level (MSL) on the upgradient side of the site to approximately 751 feet MSL on the down gradient side of the site. Historically, groundwater appears to flow from the northeast to the southwest. Historical groundwater elevation data for the facility are presented in Table 2. The groundwater elevations and flow direction based on the July 2021 water level data are illustrated on Figure 3B Potentiometric Map July 2021. 1.2.1 Groundwater Flow Aquifer hydraulic properties and groundwater flow velocity calculations are included in Table 3. The horizontal gradient for the flow path illustrated on Figure 3 was 0.0316 ft/ft. This value is consistent with previous estimates. The linear groundwater flow velocities were computed using the modified Darcy equation of V = Ki/ne, where: V = average linear velocity (feet/day); K = hydraulic conductivity (feet/day); i = horizontal hydraulic gradient; and ne = effective porosity. Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Page 4 of 23 WithersRavenel March 2022 %0 %io Our People. Your Success. The hydraulic conductivity (K =1.73 feet/day) from slug -tests conducted by JOYCE in April 2013 was used in this calculation. The effective porosity (ne = 30%) was estimated based on typical values for saprolite in the North Carolina Piedmont. Although the regolith and bedrock are hydraulically connected, the effective porosity generally decreases with depth into the underlying fractured bedrock. The calculated linear groundwater velocity (V) is estimated to be approximately 65 feet/year. As reported by JOYCE, because of the conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplified assumptions of a homogeneous and isotropic aquifer. Actual velocities may vary significantly in the heterogeneous, anisotropic conditions believed to exist at this site. 1.2.2 Vertical Gradient Monitoring wells MW-3S and MW-3D represent a nested pair of wells with different screened intervals. The estimated vertical gradient based on the water levels measured during the July 2021 sampling event is calculated below. As tabulated below, the calculated upward gradient is -2.12 feet/foot between these two wells, indicating a moderately weak upward component to groundwater flow. Since these wells are located near the creek southwest of the landfill, these data support the contention that the creek is a groundwater discharge feature. Well ID Ground TOC Screened Interval Elevation Groundwater Vertical Surface (Ft MSL) (Ft MSL) Elevation Gradient Elevation (Ft MSL) (Ft) (Ft MSL) Top Bottom Midpoint MW-3S 761.98 764.57 748.0 738.0 743.0 751.14 -2.12 MW-3D 762.02 764.56 725.1 705.1 715.1 753.26 Ft-AMSL = Feet above mean sea level. TOC = Top of PVC well casing. 1.3 Contamination Distribution Based on the data reported during the July 2021 groundwater sampling event, there appears to be one VOC plume and associated AOC continuing at the facility. The AOC is located hydraulically downgradient of the waste disposal area in the vicinity of MW-2, MW-3S, MW- 3D, and MW-4. The groundwater surface contours illustrated on Figure 313 indicate that groundwater flow is generally from the northeast to the southeast towards the creek, which is an unnamed tributary to East Belews Creek. This is consistent with historical data and the observed plume. The creek, which flows toward the northwest, is believed to be a groundwater discharge feature and therefore should exert some hydraulic control over the migration of the VOC plume. During the recent sampling period, there have been few Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 5 of 23 ... aiv Our People. Your Success. quantified detections of VOCs in the surface water and no exceedances to the Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of North Carolina listed in 15A NCAC 2B (the "2B Standards"). Since 2017, several VOCs have been detected at concentrations that exceed their respective 2L Standards or the NC Solid Waste Section Groundwater Protection Standards (GWPS - established for constituents without a currently defined 2L Standard). The constituents of concern (COCs) for the facility include the VOCs that have been detected in exceedance of the 2L Standards in one or more downgradient well during the recent sampling period. These COCs include: • Benzene, • 1,1-dichloroethane (1,1-DCA) • 1,2-dichloroethane (1,2-DCA) • 1,2-dichloropropane (1,2-DCP), and • Vinyl chloride. Monitoring wells impacted by VOCs include MW-2, MW-3S, MW-3D and MW-4, which are located southwest of the waste unit approximately 130 feet to 450 feet from the western boundary of the facility. Table 4 and Table 5 present summaries of NC Appendix I and II organic and inorganic constituents that have been detected above the 2L Standards or the GWPS. Complete historical data for detected constituents in groundwater and surface water are presented in Appendix III. The laboratory analytical reports and field data logs have been submitted in the corresponding Semiannual Water Quality Monitoring Reports (WQMRs) for the facility. The laboratory reports and field data logs for the July 2021 sampling event are presented in the July 2021 Water Quality Monitoring Report (Permit #34-04), which was submitted in January 2022. Five VOCs have been detected at concentrations greater than the regulatory Groundwater Protection Standard (GPS) as defined in NCSWMR §.1634 in the recent sampling period. For the COCs, the GPSs are the 2L Standards. During the recent sampling event, benzene exceeded its 2L Standard (1.0 µg/L) in MW-2; 1,1-dichloroethane was detected above its 2L Standard (6.0 (µg/L) in MW-2R; 1,2-dichloroethane was detected above its 2L Standard ( 0.4 µg/L) in MW- 2R, MW-3S and MW-3D; 1,2-dichloropropane was detected above its 2L Standard (0.6 µg/L) in MW-2R and MW-3D; and vinyl chloride was detected above its 2L Standard (0.03 µg/L) in MW- 2R, MW-3S, MW-3D, and MW-4. Table 4 presents the historical data for these constituents. Figures 5-13 present isoconcentration maps for the individual COC plumes and for total VOCs using the July 2021 sample event data. Based on the lack of detections of any COCs in the surface water samples SW-1, SW-2 and SW-3, immediately downgradient of the impacted monitoring wells, the plume appears to be limited and contained within the facility boundary. As previously discussed, nested wells MW-3S and MW-3D, which are located adjacent to the creek, exhibit a moderately weak upward hydraulic gradient, indicating that the creek is a groundwater discharge feature. The deep -screened well MW-3D has higher concentrations Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 6 of 23 %0 %io Our People. Your Success. of VOCs than the shallower MW-3S, indicating that the vertical extent of the total VOC plume is not delineated. Figures 14-22 present plots of the COCs and total VOCs versus time in all monitoring wells where they have been detected (MW-2R, MW-3S, MW-3D, and MW-4). The concentrations of most of the COCs in most wells show downward or stable trends. A review of Figure 22 appears to show a downward trend in total VOCs in all of the wells. The trends indicate that the geometric distribution of the plume and the concentrations in the plume are generally stable or decreasing. In addition to the VOCs, there have been isolated occurrences of inorganic constituents (metals) detected above the 2L Standard or the GWPs in both upgradient and downgradient monitoring wells at the site; however, in the last five years the only metals detected at concentrations above the referenced standards include cadmium and chromium in MW-3S, and chromium and lead in MW-5. MW-5 is located on the east side of the landfill, in a cross - gradient location relative to waste and is unlikely to have been impacted by the landfill. The metals' exceedances do not appear to coincide with the VOC plume; therefore, they do not appear to be related to a release from the landfill. The metals are believed to represent naturally occurring variations in groundwater chemistry due to the site geology; therefore, they are not considered COCs. The historic exceedances of inorganic constituents are summarized in Table 4. 1.4 Site Conceptual Model 1.4.1 Site Geology The Town of Kernersville Landfill is located in the Piedmont Physiographic Province (Piedmont) of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian to Permian age which are part of the Charlotte Belt Geologic Unit. A geologic map of the area has been included as Figure 2 (Espenshade, et al, 1975). The geologic map shows that rock underlying the site is primarily characterized as quartz monzonite and granodiorite, typically containing large microcline phenocrysts as well as biotite, muscovite, epidote, and hornblende. It is generally nonfoliated and may contain thin layers of mafic rock. Just south of the site is an area mapped as a mafic intrusive body, mainly composed of gneissic metagabbro and metadiorite. The geologic map does not illustrate any diabase dikes mapped near the site location. There is relatively limited historical geological data available for the Kernersville landfill. Neither JOYCE nor WR could locate drilling records or boring logs for wells on the property through a review of both the Town of Kernersville records and NCDEQ records. In 2012, JOYCE installed a number of gas probes at the site and boring records were prepared for those probe installations. In most cases, the borings for the gas probes encountered uniform red clayey sands that appeared saprolitic. Depths of borings for the probes ranged from approximately eight feet to approximately 34 ft-BGS. Bedrock was not encountered in any of those borings. 1.4.2 Site Hydrogeology The uppermost aquifer is unconfined and includes both saprolite and the uppermost fractured bedrock, which are well connected and act as a single aquifer. Typically in the Piedmont, the Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 7 of 23 %0 %io Our People. Your Success. saprolite grades into weathered bedrock which grades into fractured competent bedrock, resulting in an aquifer in which porosity and permeability decrease significantly with depth. Groundwater can occur in substantial volumes where soils and saprolite are very thick; but typically, groundwater is found in minimal volumes in bedrock, primarily restricted to fractures. Groundwater in the saprolite feeds the fractures in the bedrock and is discharged into creeks south and southwest of the landfill. Although the regolith and bedrock are hydraulically connected, the effective porosity generally decreases with depth into the underlying fractured bedrock. Groundwater flow at deeper levels within the fractured bedrock is controlled by fracture orientation and connectivity. This unconfined aquifer is pervasive across the site. Historical water level data are presented in Table 3. A groundwater potentiometric surface map based on water levels obtained during the July 2021 sampling event is presented on Figure .3B The water table beneath the facility generally mimics the surface topography, ranging in depth from approximately three to 30 ft-BGS. Groundwater flow is to the southwest, and discharges to the creek located south and southwest of the landfill. The creek forms a hydrologic divide, so that groundwater from the site is not expected to migrate beyond it. The calculated linear groundwater velocity was approximately 65 feet/year (see Section 1.2 for a more detailed discussion). However, our review of the calculations indicated an estimated linear velocity of approximately 0.3 ft/yr., significantly less than previously calculated. Migration of groundwater contaminants are expected to follow the general groundwater flow paths shown on Figure 3B. The unnamed tributary present along the south and southwestern border of the waste unit, downgradient of the plume, is a groundwater discharge feature and, therefore, a hydrologic divide that should prevent migration of the plume beyond it. There are currently no known preferred pathways that could significantly affect plume migration or the effectiveness of the groundwater/surface water monitoring network to monitoring plume migration. 1.5 Regulatory Status The Kernersville Landfill is regulated under §.0500 of the NCSWMR and is monitored in accordance with the requirements of §.0600 of the NCSWMR. On November 1, 2012, the Town of Kernersville received notification from NCDEQ that because detected groundwater impacts at the site could potentially be crossing the property boundary, the Town needed to submit a Phased Groundwater Assessment Plan and complete the described groundwater assessment. In January 2013, JOYCE, on behalf of the Town, submitted a Groundwater Assessment Plan, which was approved by DEQ on February 14, 2013. In May 2013, JOYCE submitted a Groundwater Assessment Report for the facility. In a letter dated July 16, 2013, DEQ approved the Groundwater Assessment Report and called for the Town to select a remedy and submit a Corrective Action Application within 1 year of the date of that letter. In July 2014, on behalf of the Town, JOYCE submitted the Corrective Action Application selecting Monitored Natural Attenuation (MNA) plus Phytoremediation as the remedy. The remedy was approved by DEQ in a letter dated July 23, 2014. As required by NCDEQ, JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town of Kernersville Landfill in October 2014. NCDEQ approved the CAP in a letter dated November 4, 2014. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 8 of 23 .. ,. Our People. Your Success. 2.0 CORRECTIVE ACTION SUMMARY 2.1 Physical and Chemical Changes in Aquifer Conditions The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background monitoring well MW-1 was replaced (by monitoring well MW-6) due to slow recharge in the well, low well volumes, or being dry during sampling events. Downgradient monitoring wells MW-2R, MW-3S, MW-3D, MW-4, and MW-5R are monitored for the Appendix I list of constituents as part of the compliance network for the facility. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2R, MW-3S, MW-3D, MW-4 and MW-6 are analyzed for the Appendix I list of constituents and for the following Monitored Natural Attenuation (MNA) constituents: • Nitrate, sulfate, chloride, sulfide, alkalinity, and • Total organic carbon (TOC); Sample analyses are then compared to the 2L Standards, IMACs or GWPs, where appropriate. Data obtained from the July 2021 semiannual sampling event, including groundwater elevation and flow, groundwater field parameters, MNA parameters, and constituent concentrations have been evaluated with regard to the physical and chemical conditions in the uppermost aquifer at the site. Table 6 presents the recent and historical MNA data for the facility. The laboratory analytical reports for the MNA data have been submitted in the corresponding semiannual WQMRs for the facility. The laboratory report for the July 2021 MNA data are presented in the July 2021 Water Quality Monitoring Report (Permit # 34-04), which was submitted in January 2022. Temperature, pH, conductivity, ORP, turbidity, dissolved oxygen, dissolved carbon dioxide, and ferrous iron fluctuate within normal ranges for groundwater in saprolite of the Piedmont physiographic province. Conductivity, ORP, alkalinity and chloride concentrations are significantly higher and sulfate concentrations are lower in the vicinity of the plume than in the upgradient well. These differences are attributed to the presence of the plume and the natural attenuation process. Although some MNA parameters have fluctuated or had sporadic results, there appear to be no systematic differences in groundwater chemistry during the sampling period. Additionally, there appears to be no significant change or variation in groundwater elevation and flow or constituent concentrations since the CAP was implemented. These data indicate no significant changes in the physical or chemical characteristics of the aquifer during the recent sampling period. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 9 of 23 %0 10 Our People. Your Success. 2.2 Physical and Chemical Changes in Plume Characteristics Surface water at the landfill is monitored semi-annually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Water Designation SW-1 SW-2 SW-3 Classification Upstream/Compliance Compliance Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semiannual monitoring events. Analytical results are compared to the 2B Standards. Table 5 presents the historical data for the COCs detected during the recent sampling period. Figures 5-13 present isoconcentration maps for the individual COC plumes and for total VOCs using the July 2021 sample event data. Based on the lack of detections of any COCs in the surface water samples the plume appears to be limited and contained within the facility boundary. There is no evidence of the plume either increasing or decreasing in horizontal or vertical extent since the CAP was prepared in 2014. Figures 14-22 present plots of the COCs and total VOCs concentrations versus time in monitoring well MW-2R, MW-3S, MW31D, and MW-4. The concentrations of most of the COCs in most wells show downward or stable trends. Vinyl chloride concentrations show slightly decreasing trends in MW-3S, MW-31D, and MW-4, and appear to have stabilized over the recent sampling period in MW-2R. A review of Figure 22 appears to show a downward trend of total VOCs in all of the wells. The trends indicate that the geometric distribution of the plume and the concentrations in the plume are generally stable or decreasing. These data indicate that there have been no significant changes in the chemical or physical characteristics of the contaminant plume since 2016. 2.3 Refining the Site Conceptual Model Any new information that comes to the attention of the facility, either from the data collected on site or other sources, which impact the site conceptual model will be reported and evaluated. This includes data on site or regional geology, hydrogeology, or other aspects of the site conceptual model. The site conceptual model will be refined in response to the new information as needed and appropriate. The landfill is bound to the south and southwest by an unnamed tributary of East Belews Creek, and to the east by a drainage feature that flows south into the unnamed tributary. The unnamed tributary flows to a confluence with East Belews Creek more than 2000 feet northwest of the facility property. Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Page 10 of 23 WithersRavenel March 2022 %% Our People. Your Success. Historically, three surface water points [SW-1 (upstream), SW-2 (downstream), and SW-3 (midpoint)] have been sampled semiannually in conjunction with the groundwater sampling at the facility. Historical surface water sampling data indicate that groundwater discharge into the creek has not impacted the surface water; therefore, the surface water does not constitute a sensitive receptor pathway risk. If the plume migrated to impact the surface water, dilution would likely reduce the concentrations to below detectable levels with a short distance downstream. Flora and fauna on or above the ground surface are at minimal risk, because there have been no confirmed detections of the COCs in the downstream surface water samples. Organisms suspected to be living in the subsurface at the site are at potential risk; however, soil microorganisms are known to use the organic acids and by-products of the degradation process of the groundwater plumes as a food source; therefore, the potential risk to the environment from the impacted groundwater is considered to be low. JOYCE conducted tree surveys in June 2015 and April 2016 and no evidence of distressed vegetation or obvious impacts to wildlife were observed because of exposure to the contaminant plume. During the recent sampling period, WR personnel also did not note any significant evidence of distressed vegetation or obvious impacts to wildlife potentially exposed to the contaminant plume. In 2019, in response to site inspection comments by Section Environmental Senior Specialist, Ms. Susan Heim, the Town re -graded the landfill surface to promote more efficient surface run-off. At the same time, the Town also re -graded the southwestern side slope of the landfill removing volunteer trees and undergrowth which had gown up on the slopes over the last five years. As noted above, the VOC plume remains relatively unchanged, and there is no data indicating a need to modify the site conceptual model at this time. WR plans to conduct a new tree survey in Summer 2022. 2.4 Evaluation of the Impact of Corrective Actions 2.4.1 Contamination Levels Figures 14-22 present plots of the COCs and total VOCs concentrations versus time in monitoring well MW-2R, MW-3S, MW3D, and MW-4. The concentrations of most of the COCs in most wells show downward or stable trends. Vinyl chloride concentrations show slightly decreasing trends in MW-3S, MW-3D, and MW-4, and appear to have stabilized over the recent sampling period in MW-2R. A review of Figure 22 appears to show a downward trend of total VOCs in all of the wells. The trends indicate that the geometric distribution of the plume and the concentrations in the plume are generally stable or decreasing. These data indicate that there have been no significant changes in the chemical or physical characteristics of the contaminant plume since 2016. 2.4.2 Evaluation of MNA Parameters In accordance with the CAP for the facility, MNA baseline sampling was initiated with the November 2014 sampling event; therefore, the June 2016 sampling event was the fourth and final baseline sampling event for MNA. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 11 of 23 %0 10 Our People. Your Success. The MNA performance parameters provide insight into the microbial and biogeochemical reactions and processes that are occurring within the subsurface. In accordance with the CAP, the baseline sampling has included the following MNA performance parameters. Some of these parameters will be analyzed in the field at the time of sampling while others will be collected for laboratory analysis, as indicated in parentheses below. Nitrate pH (field) Sulfate Temperature (field) Sulfide Conductivity (field) Methane Turbidity (field) Ethene, Ethane ORP (field) TOC Ferrous Iron (field) Alkalinity Dissolved CO2 (field) Chloride Dissolved Oxygen (field) Dissolved Hydrogen BOD Volatile Fatty Acids COD As reported above in Section 1.1 Site Background, JOYCE submitted a Corrective Action Evaluation Report (CAER) in October 2016 in accordance with the Section's Guidelines for Corrective Action Evaluation Reports. In their Conclusions and Recommendations, JOYCE recommended that 1,2-dichloroethylene, BOD and COD be removed from the MNA analytical requirements for this facility. JOYCE also requested reducing the frequency of MNA monitoring to twice per CAER period, during the two semiannual events immediately prior to the next, and subsequent, CAERs for the following MNA parameters: • Methane, ethane, and ethene • Dissolved CO2 • Volatile Fatty Acids • Ferrous Iron (Fe2+) In a response letter (DIN27098) to the Town dated December 6, 2016, the Section approved the request to remove cis-1,2-dicholorethylene from the COC list. However, the request to modify the MNA monitoring frequency for the above -listed MNA parameters was not approved but changed to continually monitoring them semi-annually (both sampling events) every three years. Table 6 presents a summary of MNA parameter results during the recent sampling period (September 2017 through July 2021). Typical definitions of Standard MNA Parameters are presented below: Temperature of groundwater is used to help assess the representativeness of water samples, and to correct temperature sensitive parameters/measuring devices. Microorganisms are active over a wide temperature range, although some may become more active with increasing temperature. Temperature measurements for groundwater samples during the recent sampling period have fluctuated between 8.4 °C and 22.4'C. Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Page 12 of 23 WithersRavenel March 2022 ... to Our People. Your Success. • pH is an indication of the suitability of environment to support wide range of microbial species. Activity tends to be reduced outside of pH range of 5 to 9, and anaerobic microorganisms are typically more sensitive to pH extremes. pH is also used to help assess the representativeness of the water sample taken during purging of wells. All pH measurements of groundwater at the site during the recent sampling period have been between 3.2 and 7.0. • Conductivity of groundwater is a measure of its ability to conduct electricity. The standard unit of conductivity is micro -Siemens per centimeter (µS/cm). Conductivity measurements are used in environmental applications as a way of measuring the ionic content in water. Conductivity in downgradient wells have ranged from 0.03 to 397.1 µS/cm. These values are, on average, significantly higher than the 0.035 µS/cm to 0.05 µS/cm observed in the background well, MW-6, during the recent sampling events. This is an indication on increased ionic content in the vicinity of the plume. • Oxidation -Reduction Potential (ORP) also referred at as redox potential or Eh, measures whether the environment is reducing or oxidizing. Ranges from 0 to +500 mV indicate oxidizing (aerobic) environments, and ranges from -500 mV to 0 indicate reducing (anaerobic) environments. The ORP measurements have fluctuated between -44.1 and 257.0 mV in downgradient wells and have been generally lower than the 47.8 mV observed in MW-6 in July 2021. The ORP data indicate a weakly aerobic environment in the plume, but less aerobic than the upgradient environment. Biological activity associated with natural attenuation is expected to reduce the ORP, so these data indicate ongoing biodegradation. • Dissolved Oxygen (DO)_is an indicator of aerobic versus anaerobic environments. The availability of oxygen is essential for aerobic microbes to metabolize organic contaminants, but DO > 5 mg/L is detrimental to the ability of anaerobic microbes to metabolize organic contaminants. Groundwater from downgradient wells showed fluctuations in DO concentrations over time, ranging from 0.23 to 14.3 mg/L; however, the DO concentrations were generally lower than the 2.38 mg/I observed in MW-6 in July 2021. The key observation is that there is sufficient oxygen in the plume area to facilitate biodegradation of constituents like benzene which require an anaerobic environment, but not too much oxygen to shut down anaerobic biodegradation required for most chlorinated VOCs. The decreased DO in the plume indicates ongoing aerobic biodegradation. • Chloride is an ultimate daughter product of reductive dehalogenation and is usually an indicator of anaerobic degradation of chlorinated hydrocarbons; however, chloride production has been documented to occur also in association with biodegradation of benzene. Chloride concentrations within the plume have consistently been an order of magnitude greater than in background well MW-6 (1.5 mg/L in July 2021), with concentrations ranging from 9.65 to 36.5 mg/L during this recent sampling period. This is a strong indication that natural attenuation is occurring. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 13 of 23 %10 4 go Our People. Your Success. • Nitrate and Sulfate compounds can be used as electron acceptors by reducing bacteria. Changes in concentrations may provide evidence of biological activity. At high concentrations, they may interfere with reductive pathways. In general, one would expect concentrations of nitrate and sulfate to decrease if active biodegradation is occurring. Concentrations of sulfate have been consistently lower in the wells within the plume than in the upgradient well, ranging from 97.5-10.4 µg/L. Concentrations of nitrate have generally been slightly lower in the wells within the plume than in the upgradient well, ranging from below the detection limit to 69.0 µg/L. Extended MNA Parameters have also been recorded periodically at this site. Typical definitions of specific Extended MNA Parameters are presented below: • Dissolved Hydrogen (DH) concentrations in anaerobic environments can be correlated with types of anaerobic activities. DH may be the limiting factor for complete dechlorination of chlorinated hydrocarbons. A concentration greater than 1 nM in considered necessary for effective reductive dehalogenation. Concentrations of DH have little impact on the aerobic degradation, such is expected for benzene. In general, the measured DH concentrations have ranged between 5.4-8.7 nM in most wells. The primary conclusion is that there is sufficient hydrogen to support anaerobic dehalogenation of chlorinated VOCs. • Sulfide presence may provide evidence of sulfate reduction; however, it may not be detected even if sulfate -reducing bacteria are active because it can react with various oxygenated chemical species and metals. Sulfide readings during the recent sampling period ranged from 7.0-148 µg/L. • Alkalinity level increase may be indicative of carbon dioxide production and mineralization of organic compounds. Alkalinity has ranged from 123 to 194 mg/I in the wells within the plume, compared to only 9.96 mg/L in the upgradient well MW-6 in July 2021. This is a strong sign that natural attenuation is occurring. • Total Organic Carbon (TOC) in significant concentrations indicates the availability of general growth substrates for microorganisms. One would expect TOC to also be higher inside the plume than outside of it. The TOC concentrations inside the plume have ranged from 0.50-5.170 mg/L, with significant fluctuations. The TOC concentrations in MW-6 ranged from 1.0 to 2.450 mg/L in July 2021. These data imply that there is less organic matter in the plume area than is considered conducive to sustain biological activity. • BTEX (the sum of benzene, toluene, ethylbenzene, and xylenes) in significant concentrations indicate the availability of general growth substrates for microorganisms. There have been no detections of toluene, ethylbenzene, or xylenes in any well during the recent sampling period, so the BTEX is simply the benzene concentration, which has ranged from BDL to 4.7 µg/L. This is lower than the concentrations considered conducive to sustain biological activity. An anomalous concentration of 9.0 µg/L was recorded in MW-1, upgradient of the landfill cell, in January 2021. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 14 of 23 ... aiv Our People. Your Success. • Biological Oxygen Demand (BOD) is based on the activities of bacteria and aerobic microorganisms which feed on organic matter in presence of oxygen. The result of a BOD test indicates the amount of water -dissolved oxygen (mg/L) consumed by microbes. In general, the higher the BOD, the higher the amount of pollution in the test sample. Typical values for pristine rivers will have BOD below 1 mg/L. Moderately polluted rivers may have a BOD value in the range of 2.0 to 8.0 mg/L. The BOD value in the background well, MW-6, was below the detection limit (<2.0 mg/L) during the recent sampling period. In MW-2, the BOD values ranged from 7.7 mg/L in September 2017 to <2.0 mg/L as the recent sampling period progressed to 2021. The BOD values in MW- 3S, MW-3D and MW-4 have consistently been <2.0 mg/L. The higher values indicate heightened biological activity within the plume, which implies significant biodegradation of the BOD is occurring; however, these results have not been consistent. • Chemical Oxygen Demand (COD) tells how much oxygen is needed to fully oxidize compounds containing carbon, hydrogen or both. As an indicator of the amount of organic pollutants found in groundwater, COD indicates the mass of oxygen consumed per liter (mg/Q. The COD was typically less than the laboratory method detection limit (also referred to as Non -Detect (ND)) in MW-6 and has been ND in most of the samples from within the plume throughout the recent sampling period; however, there have been a few higher detections (36.0 mg/L in MW-3S and 38.0 mg/L in MW-3D in July 2018). The higher values indicate heightened biological activity within the plume, which implies significant biodegradation of the COD occurs periodically. As mentioned above, the Section gave relief to analyzing certain MNA constituents in 2016. Subsequent communications between the Section (Ms. Drummond) and WR (Ms. Laura Elliott) re-established the relief until January 2022. Therefore, MNA constituents listed below were analyzed in January 2019, July 2019, and January 2020, but were not analyzed in July 2020 and both sampling events conducted in 2021. • Dissolved Methane, Ethane, Ethene in groundwater can provide evidence of dechlorination of chlorinated hydrocarbons; however, methane may also indicate activity of methanogenic bacteria. Methane produced by methanogenic bacteria decomposing organic waste is common and expected in an MSW landfill. Dissolved methane has been detected in MW-2R with a relatively high concentration of 8.18 mg/L in January 2019, and a high reading in MW-3D (9.34 mg/L) in July 2018 at lower concentrations (0.1-0.5 mg/I) in MW-3S, MW-3D, and MW-4. Methane was detected in MW-6 in July 2019 (27.2 mg/Q. The higher methane in MW-2R probably indicates impact by landfill gas. Low but detectable concentrations of ethane and ethene have been detected in the plume area sporadically, but most have been ND. 2+ • Ferrous Iron Fe )(the soluble reduced form of iron) is a nutrient and indicated the activity 2+ 2+ of iron reducing bacteria. Fe is used as electron acceptor. Fe has been detected one Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 15 of 23 ... ioOur People. Your Success. time in MW-6 (3.16 mg/L) in July 2019. During the same sampling event, 5.21 mg/L was detected in MW-2R, 4.88 mg/L was detected in MW-3S and 9.99 mg/L was detected in MW-4. 2.4.3 MNA Matrix Evaluation The MNA parameter data were evaluated in general accordance with the United States Environmental Protection Agency's (EPA's) Technical Protocol Manual (EPA, 1998) to determine whether the conditions are conducive to, or whether there is evidence for, anaerobic degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to hereafter as the Biodegradation Screening Matrix. According to this manual, a score of • <5 Indicates that there is inadequate evidence for anaerobic natural attenuation, • 6-14 Indicates that there is limited evidence for anaerobic natural attenuation, • 15-20 Indicates that there is adequate evidence for anaerobic natural attenuation, and • >20 Indicates that there is strong evidence that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the July 2021 sampling event for downgradient wells within the contaminant plume, compared where appropriate to the background well (MW-6). Where target parameters were not analyzed/recorded during the July 2021 sampling event, due to relief given by the Section, the score was based on the last time the target parameter was analyzed/recorded. The Biodegradation Screening Matrix is presented in Table 7 of this report. The total points conservatively awarded for the July 2021 sampling event was 18, which indicates that there is adequate evidence for anaerobic natural attenuation. 2.4.4 Evaluation of Phytoremediation WR did not conduct phytoremediation assessment during the recent sampling period. An assessment will be conducted beginning in early 2022 sampling event and extending through the next five-year sampling period. In their 2016 CAER Report, JOYCE concluded that "the presence of wetlands downgradient of the plume is expected to enhance phytoremediation at this site, and no changes or augmentation to the phytoremediation remedy are needed at this time." 2.4.5 Impacts on Hydraulic Gradients Based on historic groundwater elevations at this site, the average hydraulic gradient is 0.0316 ft/ft toward the southwest, with an estimated horizontal flow velocity of approximately 65 feet per year. The most recent estimate of hydraulic gradients and groundwater flow velocities are provided in Table 3 of this report and are discussed in Section 1.2.1. There is currently no pumping or injection associated with the corrective action at this facility; Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 16 of 23 .. ,. Our People. Your Success. therefore, there is no impact on hydraulic gradients. 2.4.6 Contaminant Removal Efficiencies and Mass of Contaminants Removed The CAP specifies that the EPA's BIOCHLOR Natural Attenuation Decision Support System (Version 2.2) will be used as a screening model to evaluate MNA at the Town of Kernersville Landfill facility. BIOCHLOR is an easy -to -use screening model which simulates remediation by natural attenuation of dissolved solvents at chlorinated solvent release sites (USEPA, 2002). BIOCHLOR includes three different model types: • Solute transport without decay; • Solute transport with biotransformation modeled as a sequential first -order decay process; and • Solute transport with biotransformation modeled as a sequential first -order decay process with two different reaction zones (i.e., each zone has a different set of rate coefficient values). The software, programmed in the Microsoft Excel spreadsheet environment and based on the Domenico analytical solute transport model, has the ability to simulate one-dimensional advection, three-dimensional dispersion, linear adsorption, and biotransformation via reductive dechlorination (the dominant biotransformation process at most chlorinated solvent sites). Reductive dechlorination is assumed to occur under anaerobic conditions and dissolved solvent degradation is assumed to follow a sequential first -order decay process. Previously, JOYCE conducted BIOCHLOR modeling for the Town of Kernersville Landfill for the chlorinated ethenes (PCE, TCE, DCE, & VC) based on the June 2016 concentrations in MW-2R for a simulated 10 years of biodegradation. The results of the JOYCE modeling efforts are summarized below. Constituent Mass Removed % Biotransformed Chang e in Tetrachloroethene (PCE) 0.043 Kg 70.9% 98.0% Trichloroethene (TCE) 0.198 Kg 63.3% 96.6% Dichloroethene (DCE) 1.424 Kg 55.1% 90.7% Vinyl Chloride (VC) -1.065 Kg -380% -375.8% Analytical results for the groundwater sample obtained from MW-2R for WR in July 2021 did not identify the detectable presence of PCE, TCE or DCE, which implies that these chlorinated ethenes have been removed from the groundwater by reductive dichlorination over the past five years. The vinyl chloride concentration at location MW-2R in June 2021 (4.02 ug/L) is slightly lower than that detected in June 2016 (4.60 ug/L). Its continued presence in groundwater at this location appears to be related to the disappearance of the precursor chlorinated ethenes having been transformed into VC through reductive dichlorination. Due to the absence of PCE, TCE and DCE within the sample from MW-2R further modeling using BIOCHLOR was not Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Page 17 of 23 WithersRavenel March 2022 %0 10 Our People. Your Success. conducted. During the July 2021 groundwater sampling event low concentrations of four VOCs in addition to VC were identified in the groundwater sample from MW-2R. These included benzene (3.07 ug/L), 1,1 dichloroethane (1,1 DCA 9.24 ug/L), 1,2 dichloroethane (1,2 DCA 0.520 ug/L), and 1,2 dichloropropane (1,2 DCP 3.64 ug/L). Measurement of dissolved oxygen in the groundwater from MW-2R at the time of sampling was approximately 2.85 mg/L, which indicates the presence of aerobic conditions. Because benzene and vinyl chloride are known to be amenable to aerobic biodegradation, the EPA BIOSCREEN Natural Attenuation Decision Support System model was used to predict future concentrations of the four VOCs downgradient of MW-2R at a time ten years from the present. Copies of the BIOSCREEN input and output pages for each of the five VOCs detected in the groundwater sample from MW-2R are provided in Appendix II. Under no degradation conditions, the model assumes constant contaminant source concentrations, which are the concentrations of the VOCs detected in MW-2R in July 2021. BIOSCREEN also utilizes the Domenico analytical solute transport model and simulates one-dimensional advection and dispersion in runs with an assumed constant source either with or without biodegradation. Due to the relatively low concentrations of VOCs in the July 2021 sample from MW-2R, and the slow rate of groundwater flow at the site, the BIOSCREEN runs predict that even under no degradation conditions, detectable concentrations of the VOCs should not be present in groundwater 25 to 50 feet downgradient of MW-2R within a ten-year period. Future monitoring of VOC concentrations in samples from MW-2R and within surface water samples from location SW-3, which is immediately downgradient of MW-2R can be used to evaluate the validity of the BIOSCREEN model predictions. 2.5 Migration of the Contaminant Plume 2.5.1 Status of Impacts at the Compliance Boundary No quantified detections of VOCs have been recorded in the surface water samples collected from the monitoring point SW-3, which is immediately downgradient of MW-2, nor in the upstream or downstream surface water samples (SW-1 and SW-2, respectively). Since this creek is believed to be a groundwater discharge feature, this indicates that the plume in the uppermost aquifer has not migrated beyond the creek, nor has it migrated beyond the facility boundary west of the plume. Since there are GPS exceedances in the deep well, MW-3D, the vertical extent of the plume is not fully delineated; therefore, it is possible that the plume extends into the fractured bedrock. Groundwater flow in fractured bedrock is less predictable than in the unconsolidated regolith and saprolite, therefore, we cannot determine whether or not the plume may have migrated farther at depth in the bedrock fractures. 2.5.2 Off -Site Migration Concerns The nearest property boundary to the plume is located approximately 135 feet west of MW- 4; however, the direction of groundwater flow and therefore, plume migration is to the Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 18 of 23 %% Our People. Your Success. southwest, and the creek lies between MW-4 and the property boundary in this direction. However, the highest concentration of VOCs during the recent sampling period were detected in MW-2r, also located adjacent to the property boundary and creek. The COCs with 2L Standard exceedances in MW-4 were benzene; 1,1-dichloroethane; 1,2-dichloroethane; 1,2- dichloropropane, and vinyl chloride. During the recent sampling period, none of these COCs were detected in the surface water sample collected from SW-3 which is near the property boundary southwest of MW-2R. Furthermore, there were not any quantified detections of VOCs in the other surface water sampling points located adjacent to the property boundary. This supports the contention that the plume has not migrated off site. As discussed above, WR cannot determine if the plume may have migrated farther at depth in the fractured bedrock; however, since there are no receptors for the bedrock aquifer, there is no significant risk. Since there is no evidence that the plume is expanding, there is no reason to expect the plume to migrate off site in the foreseeable future. 3.0 CONCLUSIONS AND RECOMMENDATIONS On January 13, 2021, WithersRavenel (WR) personnel mobilized to the facility to purge and sample monitoring wells MW-1, MW-2R MW-3S, MW-3D, MW-4, MW-5R, and MW-6 and sample surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01-foot. Due to the lack of water encountered within the well, monitoring well MW-1 was measured for static water level only. Table 2 presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top -of -well casing elevations reported by JOYCE in their 2015 reports. For comparison purposes, the most recent sampling event (January 2021) data are illustrated on some of the figures. Figure 3A illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the January 2021 sampling event. Figure 3B illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2021 sampling event. As shown on these figures and in recent sampling events, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of East Belews Creek. Table 3 presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR between 2016 and 2021. The monitoring wells were purged and sampled using either disposable bailers or submersible pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity, were recorded in the site -specific sampling forms after purging and before sampling. Groundwater Sampling Methods Groundwater samples from each monitoring well were collected directly from a submersible pump or decanted from disposable bailers into the laboratory -prepared and -provided containers immediately after purging. Samples were then placed into laboratory -provided coolers, chilled on ice to approximately 4°C, and delivered to a State of North Carolina -certified laboratory (Pace Laboratories) under standard Chain -of -Custody (COC) protocol. Field data logs are provided in Appendix I. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 19 of 23 ... to Our People. Your Success. Surface Water Sampling Methods Surface water samples were collected either directly into laboratory -provided, non -preserved sample containers, or by decanting the sample from a non -preserved 1-Liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. When used, care was taken to not overfill the preserved sample containers (which could lead to preservative loss) and avoid sample -induced turbidity. Samples were collected initially from the downstream sample location (previously designated SW-2 by others), and in sequence upstream, SW-3 and then SW-1 to reduce potential turbidity in the samples (Figure 2). After sample collection, the samples were placed in a laboratory -provided cooler, chilled on ice to approximately 4°C, and submitted to Pace Laboratories under standard COC protocol. Quality Control One Field Blank was collected by WR personnel as part of the January 2021 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Field Blank was analyzed for the Appendix I list of constituents only, while the Trip Blank was analyzed for VOCs only. 3.2 Assessment of MNA Indicator Parameters Based on the efficacy of the indicator parameters discussed, WR recommends they be continued to be assessed during the semiannual sampling events and reported accordingly in future CAER reports. 3.3 Modifications Needed to Selected Remedv Natural attenuation and phytoremediation will not prevent further releases of COCs from the waste unit; however, natural attenuation and phytoremediation appear to be occurring beneath the facility at a rate sufficient to keep up with migration of the plume. Evaluation of indicator parameter data and historical observations of the plume indicate that biodegradation is occurring beneath the facility at a rate that will prevent migration of contaminants beyond the property line and will reduce concentrations of constituents -of - concern within the delineated plume with time. An evaluation of the risks posed to human health and the environment suggests that there is low risk due to the fact that groundwater contamination is contained within the facility property boundary, the adjoining property downgradient of the plume is undeveloped land, and there are no known human receptors. We conclude that MNA plus phytoremediation remains an appropriate and effective remedy for the Town of Kernersville Landfill. No changes to the CAP are recommended. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 20 of 23 ... to Our People. Your Success. 3.4 Contingency Plan The CAP included a contingency plan in the event that MNA plus phytoremediation is shown to be ineffective at controlling migration of the contaminant plume. The contingency plan includes implementation of one of two contingency remedies: 1. Control of landfill gas through installation of passive or active gas vents or an intercept trench; or 2. Installation of a reactive barrier trench to intercept and filter the shallow groundwater plume. At this time, MNA plus phytoremediation remains an appropriate and effective remedy for the Town of Kernersville Landfill. No contingency remedies are recommended. 3.5 Land Use Restrictions Groundwater beneath the landfill property appears to have been impacted by leachate that originates from the unlined landfill and/or by the migration of landfill gas as evidenced by the fact that several VOCs have been detected in downgradient wells in exceedance of their respective GPS. There is no evidence that the contaminant plume has impacted the surface water in the creek or that the plume has migrated off site. The current COC plume is stable and concentrations of most COCs appear to be decreasing. Based on the data presented and discussed in this CAER, there is no need to impose land use restrictions on the landfill or adjoining property at this time. Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 21 of 23 ... to Our People. Your Success. 4.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semiannual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semiannual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, Division of Waste Management, Solid Waste Section, 2016 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling. -----, Corrective Active Evaluation Report (CAER), Closed Town of Kernersville MSW Landfill, Correspondence DIN 27098 from Ms. Jaclynn Drummond, Compliance Hydrogeologist to Mr. Doran Maltba, Town of Kernersville Public Services Director, December 6, 2016. -----, Facility Compliance Inspection Report, Ms. Susan Heim, Environmental Senior Specialist, August 13, 2019. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. United States Environmental Protection Agency (USEPA), Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance, July 1992. -----, Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater. Office of Research and Development, EPA/600/R-98/128, September 1998. -----, BIOCHLOR Natural Attenuation Decision Support System, Version 2.2, User's Manual. (Carol E. Aziz, Charles J. Newell, and James R. Gonzales.), March 2002. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina. WithersRavenel, Inc., 2017 Annual Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, April 2, 2018. -----, 2018 Annual Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34- 04, April 16, 2019 -----, July 2019 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, October 7, 2019 Correction Action Evaluation Report WithersRavenel Town of Kernersville Landfill, Permit No. 34-04 March 2022 Page 22 of 23 499 Our People. Your Success. -----, January 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, March 6, 2020. -----, July 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, September 2, 2020. -----, January 2021 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, May 17, 2021. -----, July 2021 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, January 28, 2022. Correction Action Evaluation Report Town of Kernersville Landfill, Permit No. 34-04 Page 23 of 23 WithersRavenel March 2022 FIGURES -_ - - - $�0 850 DUM DARY a f SMOKE HOLLOW Rp C) IL GRAPHIC SCALE ch = 1000 )900 -.: TOWN OF KERNERSVILLE DRAWN BY: SCALE: FIGURE NO.: W i t h e rs Ra ve n e l CLOSED LANDFILL - PERMIT #34-04 MGM 1"=1000 ' 1 1/ GOODWILL CHURCH ROAD Engineers I Planners I Surveyors KERNERSVILLE, GUILFORD/FORSYTH COUNTY NC APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drivel Cary, NC 275111 t: 919.469.3340 1 license #: F-1479 I www.withersravenel.com GENERAL LOCATION MAP SMB 01/24/2022 06140180.48 W! 14X1+4HM,140110.M-7W-3-DM8 landlpl S-1— Fn 201R\EmYo\GD\27t1A1.2iBoMmoo_IGnwrMM L dMA— J-- 24, 21M - M711111L Yql F FM qti RO A D SW-21 '0 MWW-31D MW-4 A MW-3S MW-2R SW-3 � C SW-1 MW-5 MW-6 GOODWILL CHURCH ROAD LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: -- 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 110 300 6110 1 inch = 300 ft. ;! C—N BY SCALE FIGURE NO, WithersRavenel TOWNOFKERNERSVILLECLOSED LANDFILL -PERMIT #34-04 MGM 1-300' Engineers I Planners I Surveyors GOODWILL CHURCH ROAD WATER QUALITY SAMPLE LOCATIONS MAP KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA PROVED BY: DA E: PROJE NO.: m.Ic ,Ncnsui1 ESMB O3/24/2022 06140180.48 jr - ti,f-� a ! GOODWILLCHU RCIi ROR❑ LEG EN C q FACILITY 13OUNDARY d�b 179031] D -- WASTE DISPOSAL BOUN ARY M W-6 s GROUNDWATER MONITORING WELL M W-1 [7758D])A �+ P 17aive} GROUNDWATER SURFACE ELEVATION ~1 rye N GROUNDWATER SURFACE LLEVATIUN yes CONTOUR r6p 1 1 l ESTIMATED GROUNDWATER FLOW 'ST f DIRECTION MW-4 NIyyS 1 NOTES: 754.82j {753.38} M t4W-2R ' MW-5 - �. - - '.t • �•".i 1.a 2014 AERIAL 097NNED FROM {759,811 1769.571 FORSYTH COUNlY GIG OERAWMENT' $ N 2.) PARCEL INFORMATION UEdTNNED FROM GLHLFM AND FORSYrH COUN-+' dS DEPAVIVENY"a. GRAPHIC SCALE l 4+lh-2fOp It irvFmlY 5fM1 i:xp :: WithersRauenel TOWN OF KERNERSVILLE CLOSED LANDFILL -PERMIT #34-04 POTENTIOMETRICMAP LRE >•-700' 3A GOODWILL CHURCH ROAD t.,If „ m_ Engineers Planners Surveyors KERNERSVILLE. FORSYTH COUNTY, .NORTH CAROLINA OANIIARY 2021) sere ninsnesi 06iaa=aa3! F FM qti RO A D MW-6 (790— {Jir (DRV\ N v 775 \ 770 765 0 760 753.26) j 5510 M(� D MW-4 4"`P (754.52) M 3S (751.14) W-2R $ MW-5 N , (759.65) (769.54) rn GOODWILL CHURCH ROAD LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION N OTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY CIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY CIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. ;!WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL -PERMIT #34-04 POTENTIOMETRIC MAP DP MGM 1"=300' FIGure3B Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (JULY 2021) PRO KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA B BY: DATE: P06i4 1 m.ic,rv,Ncnssu1.sas.aev.aaaoi u�mY a:P-aani,w,.,.mmers,,.e".m"m SMB 03/24/2022 06140180.48 F FM q� R 0 M W-35 Jul-21 2Ls (ug/L) CADMIUM 7.95 2 CHROMIUM 15.4 10 _ THALLIUM VINYL CHLORIDE 4.57 0.2 av 1.13 MW -1 1 Jul-21 I2Ls(ug/L) CHROMIUM 12.1 1� ViW[ CFILQR b 9-6, 0-03 SW-2 -,,o MW-4 M W-3D I Jul-21 2Ls [ug/L) 1.2-❑ICHLOROETHANE 0.571 0.4 0-01CHLOROPROPANE VINYL CHLORIDE 0.9771 5_,741 0.6 0,03 MW-2R SW-3 Q , 0 SW-1 MW-6 v wur0 f MW-1 Jul 21 }' NOTSAMPLED - DRY WELL MW-5 GOODWILL CHURCH ROAD ALL COF�IPF i! 11NE)` F6ELCiW _LSTANDARDS MVV-.,K Juh41 1LSlug(L) CHROMIUM 11.3 10 LEAD 99.5 is MW-2R Jul-21 2Ls (ug/L) BENZENE 3A7 1 1.1-DICHLOROETHANE 9.24 6 1.2-DICHLOROE- HANE 0.520 0: ; 1.2-DICHLOROPROPANE 3.64 0I6 VINYL CHLORIDE 4.02 0.03 ;! WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL -PERMIT #34-04 Engineers I Planners I Surveyors GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA m.1c ,NcI III IIII s.aevaaao Ili —I, a� 1-1411 www.nn�r•.e"ei �" LEGEND FACILITY BOUNDARY -- WASTE DISPOSAL BOUNDARY 0 SHALLOW MONITORING WELL ® DEEP MONITORING WELL p SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) ONLY ANALYTICAL RESULTS THAT EXCEEDED THE 2L STANDARD ARE ILLUSTRATED. 4.) FOR WELLS FROM WHICH DUPLICATE SAMPLES WERE COLLECTED, THE HIGHEST DEFECTED CONCENTRATION OF EACH CONTAMINANT IS SHOWN. GROUNDWATER 2L STANDARD/GWP EXCEEDANCES MAP GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. N BY oRMGM SCALE1"=300' uREn4 PROVED BY. DATE: PROIECTNO.: SMB 01/24/2022 06140180A8 F� qti R O A h4. SW-2 (BDL) MW-4 (BDL) (BDL) MW-3D \ I -4 ' MW-3S (3.07) (BDL) \ MW-2111 SW-3 (BDL) q BDL AA z - r 3: a .. �k. F �, GOODWILL CHURCH ROAD kint 4` I S• i MW-6 ti- (BDL) I MW-1 (NS) - 'I t ti+ kR i 3 �! MW-5 (BDL) LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION 11 NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) BENZENE 2L STANDARD 1.0 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 BENZENE ISOCONCENTRATION MAP - JULY MGM 1"=300' 5 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD 2021 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA APPROVED BY: DATEPROJECT NO.: : 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.withersravenel.— SM B 01/24/2022 06140180.48 Ik\14\74-0110\14018MB—MJ4_S—M! I.-M SwNoM F1'E 20R2\Emftk LmdHLdn— Fdruav ffi 21M — MMNX rM F� qti SW-2 (BDL) IN (BDL) i MW-3D MW-4 2.0 (BDL) MW-3S (BDL) (7.95) MW-2 SW-3 (BDL) BDL 0 SW-1 (BDL) Z. LN _ .� •� ` ` s - `f- .� .� � �€'_ ter. GOODWILL CHURCH ROAD kint 4` I S• i MW-6 ti- (BDL) I i GT t •-. _far n •i" >ti�. 1. � ,� - tYer LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) CADMIUM 2L STANDARD 2 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 MGM 1"=300' 6 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD CADMIUM ISOCONCENTRATION MAP APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.withersravenek— SM B 01/24/2022 06140180.48 Fk\14\74-0110\14018MB-MJ4-S—M! L-M SwNoM F1'E 20R2\Emftk LmdHLdn- Fdruav ffi 21M - MMNX rM F� qti Z. -__ - --- - _ - - -i „ _ ,y _ `k �'• mot" �� )r s _ .� •� ` ` s - `f- .� .� � �€'_ ter. GOODWILL CHURCH ROAD kint 4` I S• i — MW-1 (NS) SW-2 (BDL) MW-3D •. f \� (BDL) MW-4 (15.6). (12.1) MW-3S MW-2111 - 10 � MW-51/ SW-3 (2.15) (11.3) (BDL) BDL LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) CHROMIUM 2L STANDARD 10 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 CHROMIUM ISOCONCENTRATION MAP - MGM 1"=300' 7 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD JULY 2021 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA APPROVED BY: DATEPROJECT NO.: : 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.wither—,enek— SM B 01/24/2022 06140180.48 Ik\14\74-0110\14018MB-MJ4-S—M! L-M SwNoM FW 20R2\Emftk LmdHLdn- Fdruav ffi 21M - MMNX rM F� qti Z. `k �' • mot" �� s _ .� •� ` ` s - `f- .� .� � �€'_ ter. GOODWILL CHURCH ROAD 4` I S• i • s i L!`% MW-6 ti- (BDL) I _ MW-1 (1.26) i {; SW-2 \ MW-3D f (BDL) i MW-4 1 (1.15)--,'MW-3S (0.451) MW-2111 MW-5 (9.24) (BDL) SW-3 6.0 F (BDL) BDL �P t Zi i GT t •-. _darn •4a i��. 1. � ,.� _ Lu LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) 1,1—DICHLOROETHANE 2L STANDARD 6 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 1,1-DICHLOROETHANE ISOCONCENTRATION MGM 1"=300' 8 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD MAP - JULY 2021 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.with—ravenel.com SM B 01/24/2022 06140180.48 Ik\14\74-0110\14018MB-70/4-ImM! L-M SwW— F1'E 20n\ iR*Dk LmdHLdn— Fdruav ffi 21M — W117BA WIM F� qti SW-2 (BDL) IN Z. `k �'• mot" �� )r s GOODWILL CHURCH ROAD 4• I S• i • s i L!`% MW-6 ti- (BDL) I MW-1 (NS) t r 1 Y 'IMF t (0.571) MW-3D MW-4 (BDL) W-3S (0.272) MW-2R MW-5 x' (0.520) 0 4 (BDL) SW-3 (BDL) BDL 0 SW-1 (BDL) 11111111111�-VIOPL V r4fLL s; �P i Rb�`• i , r, LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) 1,2—DICHLOROETHANE 2L STANDARD 0.4 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 1,2-DICHLOROETHANE ISOCONCENTRATION MGM 1"=300' 9 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD MAP - JULY 2021 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.with—ravenel.com SM B 01/24/2022 06140180.48 Ik\14\74-0110\14018MB-70/4-ImM! L-M SwW— F1'E 20n\ iR*Dk LmdHLdn— Fdruav ffi 21M — W117BA WIM F� qti (0.977) SW-2 MW-3D (BDL) i MW-4 (0.286) MW-3S (0.394) MW-2111 SW-3 (3.64) (BDL) 0.6 BDL 0 SW-1 (BDL) Z. `k �'• mot" �� )r s GOODWILL CHURCH ROAD kint 4` I S• i 'lJ MW-1 (NS) �Y ti+ kR f MW-5 (BDL) . • s i L!`% MW-6 ti- (BDL) I Njw" LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) 1,2—DICHLOROPROPANE 2L STANDARD 0.6 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 1,2-DICHLOROPROPANE MGM 1"=300 ' 10 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD ISOCONCENTRATION MAP - JULY 2021 APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.withersravenek— SM B 01/24/2022 06140180.48 Ik\14\74-0110\14018MB—MJ4—S—M! L-M SwNoM F1'E 20R2\Emftk LmdHLdn— Fid— ffi 21M — MMNX rM F� qti SW-2 (BDL) IN Z. `k �'• mot" �� )r s _ .� •� ` ` s - `f- .� .� � �€'_ ter. GOODWILL CHURCH ROAD 4` I S• i -, r ., �v� l -. •.�. �P _ y' may,, • s i L!`% MW-6 ti- (BDL) I MW-1 (NS) �# 'IMF (BDL) MW-3D +' MW-4 ____0.2 W-3S� -• '. (BDL) (4.57) MW-2R MW-5 Q (BDL) (BDL) SW-3 F - (BDL) BDL 0 SW-1 (BDL) t I LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) THALLIUM 2L STANDARD 0.2 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 THALLIUM ISOCONCENTRATION MAP - JULY MGM 1"=300 ' 11 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD 2021 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA APPROVED BY: DATEPROJECT NO.: : 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #: F-1479 I www.wither5ravenel.com SM B 01/24/2022 06140180.48 Ik\14\74-0110\14018MB-70/4_ImM! L-M SwWo F1'E 20n\ iR*Dk LmdHLdn— Fdruav ffi 21M — W117BA rM - _ ,� ,y - LN {,` `' GOODWILL CHURCH ROAD !r 4` I S• i /V IQ O :�"� _ _ , ■ _ _ _ ^'t" `fie i MW-6 Sw-2 (BDL) MW-1 (NS) �Y r 1 s . •� 4� t (5J4) �\ MW-3DY MW-4�' .t (9.62)\MW-3S (1.13) MW-2111 0.03 MW-5 SW-3 (4.02) BDL (BDL) (BDL) (BDL) �l �.L tYer V" LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) VINYL CHLORIDE 2L STANDARD 0.03 UG/L 4.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 5.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: I SCALE: FIGURE NO.: / �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 VINYL CHLORIDE ISOCONCENTRATION MAP MGM 1"=300 ' 12 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD - JULY 2021 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drive I Cary, NC 275111 C 919.469.3340 I license W: F-1479 I wes-with—ravenelkom SM B 01/24/2022 06140180.48 Ik\14\74-0110\140l8MB-70/4_I..M! L-M SwNs F1'E 20R2\BR*o\ Lmd1IIl FId— ffi 21M — WL7BA WM F� qti \ (7.288) SW-2 \ MW-3D (BDL) \ MW-4 (9.62) MW-3' (1.13) SW-3 (BDL) MW-2R (20.49) Z. LN _ .� •� ` ` s - `f- .� .� � �€'_ ter. GOODWILL CHURCH ROAD 4• I S• i 01-� '` Wit` r.'- - t 1 \ +W2' i LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) BDL = BELOW LABORATORY METHOD DETECTION LIMITS 4.) NS = NOT SAMPLED (DRY) GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. / LE: �0- Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 TOTAL VOLATILE ORGANIC COMPOUNDS FIGURE NO.: DRAWN BY: MGM 1SCALE: 13 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (VOCs) ISOCONCENTRATION MAP - JULY APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 2021 115 MacKenan Drive Cary, NC 27511 t: 919.469.3340 license #: F-1479 www.withersraveneLcom SM B 01/24/2022 06140180.48 Fk\14\74-0110\14018MB-MJ4_S—M! I.-M SwNoM F1'E 20R2\Em*Dk LmdHLdn- Fdruav ffi 21M - MMNX rM BENZENE MIXIZ17 9.00 8.00 VA4141 -::r 6.00 on 5.00 J N E 4.00 3.00 2.00 1.00 WIN f MW-1 MW-2R • lD N CO N N 0 N N Ln W N O N O N O NJ NJ N O N O N O NJ O O IR 00 FR lO F-� O N N IliV 00 lD O F-` 1 ` DATE Benzene concentration versus sample date graph. All points on graph are at concentrations higher than the benzene 2L Standard of 1 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel CADMIUM 9.00 8.00 7.00 6.00 J b 5.00 J N 4.00 w 2.00 1.00 WIN l0 lD N 00 W N 0 N Ln N N O NJ N O NJ O N O N O NJ FR 00 IR lO F-� O N V 00 lD O DATE BMW-1 t MW-3S NJUj W O \ \ N N O O N N N N Cadmium concentration versus sample date graph. All points on graph are at concentrations higher than the cadmium 2L Standard of 2 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel *■ C • 1I 1I 45.0 B1ixi7 35.0 011t, J own 25.0 H J v) 20.0 W 15.0 10.0 5.0 MW-3s t MW-4 BMW-5 I 0.0 l0 l0 NJ 00 N W N 0 N N Ln W N O N O N O NJ N N O N O N O NJ O O F� 00 IR lD O N N N �I 00 lO O 11 DATE Chromium concentration versus sample date graph. All points on graph are at concentrations higher than the chromium 2L Standard of 10 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel 18.0 16.0 14.0 12.0 J 10.0 6.0 4.0 2.0 M 1,1-DICHLOROETHANE f MW-2R 00 hn N Uj NJ NJ N Ln W ON O O O O O O F� 00 I—` lO I—` O N N N V 00 lO O N N DATE 1,1-Dichloroethane concentration versus sample date graph. All points on graph are at concentrations higher than the 1,1-dichloroethane 2L Standard of 1 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel 1,2-DICHLOROETHANE 3 2.5 2 J tin 7 1.5 J Z) V) W Cf 1 0.5 tMW-1 f MW-2R �— M W-3S MW-3D 0 l0 O F-� l0 ) N 00 00 N LU \ N \ N \ N Ln \ LU \ \ Nj O� Ili O1 NJ O Ili Nj NJ O O O N O O O F-+ 00 F-` lD 1- O N N N A 00 lD O 1 DATE 1,2-Dichloroethane concentration versus sample date graph. All points on graph are at concentrations higher than the 1,2-dichloroethane 2L Standard of 0.4 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel 1,2-DICHLOROPROPANE tMW-1 f MW-2R 5.00 4.50 4.00 3.50 3.00 \ / on Y 2.50 J V) N W = 2.00 1.50 1.00 0.50 00 Ln Uj N NJ NJ\ N ON O O O O O O F� 00 kD N N N �I 00 lO O DATE 1,2-Dichloropropane concentration versus sample date graph. All points on graph are at concentrations higher than the 1,2-dichloropropane 2L Standard of 0.6 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel THALLIUM fMW-3S t MW-4 alft 4.50 4.00 41411 -::r 3.00 on 2.50 J Ln N E 2.00 1.50 1.00 0.50 l0 lD N 00 N W N 0 N N Ln W N O N O N O NJ NJ N O N O N O NJ O O IR 00 IR lO F-� O N N IliV 00 lD O F-` 1 ` DATE Thallium concentration versus sample date graph. All points on graph are at concentrations higher than the thallium 2L Standard of 0.2 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel VINYL CHLORIDE 20 18 16 14 12 on I H 10 J D N w 8 Of 4 `a f MW-1 MW-2R t MW-3S f MW-3D t M W-4 0 ' O o LU l0 CD l0 N 00 Ln LU N \ N \ N \ N \ \ \ O O� PQ O O1 NJ O ON O O O F-+ 00 1. lD 1- O N N N �I 00 lD O 1 F-� DATE Vinyl chloride concentration versus sample date graph. All points on graph are at concentrations higher than the vinyl chloride 2L Standard of 0.03 µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel 35.00 30.00 25.00 J o;0 20.00 7 H J Ln 15.00 w 10.00 5.00 0.00 LU W N O F-+ v F-� N O 00 00 V CD O N O 00 TOTAL VOCs DATE N A N O LO lD F-� 00 N O N O BMW-1 MW-2R f MW-3S f MW-3D BMW-4 tMW-5 V N O N O N N Total volatile organic compounds (VOCs) versus sample date graph. Result values calculated for each sample date equals the sum of VOC concentrations for benzene, 1,1-dichloroethane, 1,2-dichloroethane, 1,1-dichloropropane, and vinyl chloride in µg/L. Town of Kernersville Landfill Permit # 34.04 WithersRavenel TABLES TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft-bTOC) Screen Interval (ft-bTOC) Total Depth (ft-bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 2 6.36 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 2 10.46 10.46 - 20.46 20.46 804.87 Notes: 1) ft-bTOC = Feet below top of casing 2) MSL = Mean sea level Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring 3) Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 1/13/2021 7/20/2021 GROUNDWATER GROUNDWATER SCREENED TOP OF CASING DEPTH DEPTH WELL ID INTERVAL ELEVATION SURFACE SURFACE (ft-bTOC) (feet above MSL) WATER ELEVATION WATER ELEVATION (fbTOC) (fbTOC) (feet above MSL) (feet above MSL) MW-1 24.96 - 34.96 806.42 30.62 775.80 DRY DRY MW-2R 3.18 - 13.18 762.19 2.38 759.81 2.54 759.65 MW-3S 14.00 - 24.00 764.57 12.89 751.68 13.43 751.14 MW-3D 36.96 - 56.96 764.56 11.23 753.33 11.30 753.26 MW-4 4.40 - 14.40 760.26 5.44 754.82 5.74 754.52 MW-5 6.36 - 11.36 773.32 3.75 769.57 3.78 769.54 MW-6 10.46 - 20.46 804.87 14.56 790.31 14.26 790.61 Notes: 1) All measurements are in feet. 2) Elevation data is measured in feet above Mean Sea Level (MSL). 3) Depth to water measured in feet below top of casing (ft-bTOC) "Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality 4) Monitoring Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feel)_ Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-1 806.42 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 9/13/2017 DRY DRY 7/10/2018 DRY DRY 1/9/2019 DRY DRY 7/24/2019 DRY DRY 1/8/2020 DRY DRY 7/15/2020 DRY DRY 1/13/2021 30.62 775.80 7/20/2021 DRY DRY MW-2R 762.19 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 9/13/2017 4.22 757.97 7/10/2018 4.41 757.78 1/9/2019 2.84 759.35 7/24/2019 3.40 758.79 1/8/2020 3.17 759.02 7/15/2020 3.02 759.17 1/13/2021 2.38 759.81 7/20/2021 2.54 759.65 MW-3S 764.57 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 9/13/2017 14.29 750.28 7/10/2018 15.00 749.57 1/10/2019 12.50 752.07 7/24/2019 13.96 750.61 1/8/2020 13.23 751.34 7/15/2020 13.47 751.10 1/13/2021 12.89 751.68 7/20/2021 13.43 751.14 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 1 of 3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feel)_ Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-3D 764.56 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29/2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 9/13/2017 12.96 751.60 7/10/2018 15.00 749.56 1/10/2019 11.25 753.31 7/24/2019 11.86 752.70 1/8/2020 11.68 752.88 7/15/2020 11.94 752.62 1/13/2021 11.23 753.33 7/20/2021 11.30 753.26 MW-4 760.26 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 9/13/2017 7.33 752.93 7/10/2018 7.00 753.26 1/9/2019 5.24 755.02 7/24/2019 5.89 754.37 1/8/2020 5.71 754.55 7/15/2020 6.04 754.22 1/13/2021 5.44 754.82 7/20/2021 5.74 754.52 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 2of3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feel)_ Date Depth to ) Groundwater Elevation (feet) MW-5 773.32 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 9/14/2017 5.48 767.84 7/10/2018 NM NM 1/10/2019 10.50 762.82 7/24/2019 4.03 769.29 1/8/2020 3.54 769.78 7/15/2020 4.75 768.57 1/13/2021 3.75 769.57 7/20/2021 3.78 769.54 MW-6 804.87 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 9/14/2017 20.64 784.23 7/10/2018 DRY DRY 1/9/2019 17.49 787.38 7/24/2019 16.51 788.36 1/8/2020 17.19 787.68 7/15/2020 15.97 788.90 1/13/2021 14.56 790.31 7/20/2021 14.26 790.61 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 3of3 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 6010 Contaminant Of Concern o Q H Q E 7 m ? >, m E -O V E E 0 V N 0 V v C. 0 V M J Y V Z 2 C V1 W ] 0 > - L F M U C iV CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result I Qum LiMmit I Qual Result Qual Result Qual Result Qual Result Qual Result Quail Result Qual 9/13/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 NOT SAMPLED (DRY WELL) MW-1 7/24/2019 NOT SAMPLED (DRY WELL) 1/8/2020 NOT SAMPLED (DRY WELL) 7/15/2020 NOT SAMPLED (DRY WELL) 1/13/2021 4.43 J BDL 214 1.59 J 3.12 2.63 J 69.5 23.4 B BDL 2.63 J 8.85 J BDL BDL 6.25 J 795 7/20/2021 NOT SAMPLED (DRY WELL) 9/13/2017 <3.9 <5 247 <0.5 <0.5 <2.5 2.3 <2.5 <2.5 <2.5 <5 <2.5 <0.02 <2.5 <5 1/9/2018 <3.9 <5 281 <0.5 <0.5 <2.5 NA <2.5 <2.5 <2.5 <5 <2.5 NA <2.5 <5 7/10/2018 <3.9 <5.0 255 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 3.0 J 6.4 1 1/9/2019 <3.9 <5.0 251 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 3.2 J <5.0 MW-2R 7/24/2019 <10.0 <10.0 245 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.0 <10.0 <20.0 10.2 1 1/8/2020 0.70 J 0.51 J 222 0.40 J 0.31 J 0.73 J NA 1.09 0.56 1 <1 <1 0.13 1 NA 2.31 16.8 7/15/2020 <10.0 <10.0 234 <2.00 <2.00 <10.0 1.11 J <10.0 <6.00 <10.0 <10.0 <5.0 <10.0 <20.0 19.4 1 1/13/2021 5.04 J BDL 210 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 BDL I BDL 1 253 0.333 J 0.504 J 2.15 J 3.95 1 BDL 3.25 1 1 BDL BDL BDL I BDL 6.89 J 7.27 J 9/13/2017 <3.9 <5 45.5 <0.5 3.8 41.3 0.24 1 27.5 1 <2.5 35 <5 <2.5 <0.02 40 157 1/9/2018 <3.9 <5 158 <0.5 2.5 7.1 NA 15.6 <2.5 35 <5 <2.5 NA 30.3 318 7/10/2018 <3.9 <5.0 138 <.50 1.1 5.9 NA 9.2 <2.5 3.6 J <5.0 <2.5 NA 22.1 154 1/10/2019 <3.9 <5.0 115 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA <2.5 10.4 MW-3S 7/24/2019 <10.0 <10.0 208 <2.00 2.94 4.69 J 9.6 J 16.9 6.12 5.37 1 <10.0 <5.0 <10.0 51.8 592 1/8/2020 0.63 J 0.17 J 107 <1 <1 1.75 NA 3.3 <1 2.38 <1 0.12 1 NA 1.19 33.2 7/15/2020 <10.0 <10.0 121 <2.00 <2.00 <10.0 8.10 1 <10.0 <6.00 3.82 J <10.0 <5.0 <10.0 <20.0 37.9 J 1/13/2021 BDL BDL 152 0.466 J 3.820 2.2 J 9.14 J 15.2 B BDL 4.78 1 BDL BDL BDL 15.8 J 229 7/20/2021 4.40 J BDL 1 236 1 1 0.88 J 7.95 15.6 15.5 44.7 12.5 8.10 J BDL BDL 4.57 B J 76.8 619 9/13/2017 <3.9 <5 155 <0.5 <0.5 <2.5 7.5 1 <2.5 1 <2.5 <2.5 <5 <2.5 <0.02 <2.5 <5 1/9/2018 <3.9 <5 40.2 <0.5 <0.5 <2.5 NA <2.5 <2.5 <2.5 <5 <2.5 NA <2.5 <5 7/10/2018 <3.9 <5.0 42.4 <.50 0.55 <2.5 NA 3.6 1 <2.5 <2.5 <5.0 <2.5 NA 3.0 J 5.1 1 1/10/2019 <3.9 <5.0 40.6 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 3.3 1 <5.0 MW-3D 7/24/2019 <10.0 <10.0 44 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.0 <10.0 7.44 1 <50 1/8/2020 0.57 J 0.11 J 40.1 <1 <1 0.61 J NA 2.19 <1 0.52 J <1 0.10 1 NA 2.61 17.4 7/15/2020 <10.0 <10.0 45.9 <2.00 <2.00 <10.0 <10.0 <10.0 <6.00 <10.0 <10.0 <5.0 <10.0 <20.0 26.3 1 1/13/2021 BDL BDL 44.6 BDL BDL BDL I BDL 3.96 B J BDL BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL 38.0 BDL BDL BDL BDL BDL 3.43 1 I BDL BDL BDL BDL 1 6.52 J I BDL 7/15/2020 <10.0 <10.0 45.1 <2.00 <2.00 <10.0 <10.0 <10.0 1 <6.00 <10.0 <10.0 <5.0 <10.0 <20.0 19.6 1 DUP(MW-3D) 1/13/2021 BDL BDL 45.9 BDL BDL BDL BDL 4.77 J BDL BDL BDL BDL BDL BDL BDL 7/20/2021 5.65 J BDL 49.2 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7.49 1 BDL 9/13/2017 <3.9 <5 88.5 <0.5 <0.5 <2.5 1.6 <2.5 <2.5 <2.5 <5 <2.5 <0.02 <2.5 <5 1/9/2018 <3.9 <5 92.6 <0.5 <0.5 <2.5 NA 7.8 <2.5 <2.5 <5 <2.5 NA 5.8 <5 7/10/2018 <3.9 <5.0 86.4 <.50 <.50 <2.5 NA 2.6 J <2.5 <2.5 <5.0 <2.5 NA <2.5 6.9 1 1/9/2019 <3.9 <5.0 91.8 <.50 <.50 4.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 7.0 9.6 1 MW-4 7/24/2019 <10.0 <10.0 92.7 <2.00 <2.00 1.42 J I <10.0 <10.0 <5.00 <10.0 I <10.0 <5.0 <10.0 <20.0 5.93 1 1/8/2020 1.59 0.19 J 80.4 <1 I <1 2.01 NA 1.53 0.64 1 2.11 1 <1 0.21 J I NA 3.0 11.20 7/15/2020 <10.0 <10.0 94.2 <2.00 0.63 J <10.0 1.82 1 I <10.0 1 <6.00 4.06 J <10.0 <5.0 4.66 1 <20.0 22.6 1 1/13/2021 BDL BDL 99.9 1 0.656 J BDL 7.01 J 2.48 J 4.68 J BDL 2.74 1 BDL BDL BDL BDL 8.49 1 7/20/2021 BDL BDL 127 BDL 0.580 J 12.1 3.50 1 6.32 1 5.96 1 3.84 J BDL BDL BDL 17.2 1 20.1 1 9/14/2017 <3.9 <5 87.4 <0.5 <0.5 <2.5 11.3 <2.5 5.7 <2.5 <5 <2.5 <0.02 7.1 12.2 1/9/2018 <3.9 <5 100 <0.5 <0.5 <2.5 NA 22 21.5 <2.5 <5 <2.5 NA 36.6 78.3 7/10/2018 <3.9 <5.0 69.3 <.50 <.50 <2.5 NA 17.0 3.3 1 <2.5 <5.0 <2.5 NA 9.5 67.8 1/9/2019 <3.9 <5.0 37 <.50 <.50 <2.5 NA <2.5 3.3 <2.5 <5.0 <2.5 NA 2.6 J 17 MW-5 7/24/2019 <10.0 <10.0 108 <2.00 <2.00 <10.0 7.24 J 11 23.5 <10.0 <10.0 <5.0 <10.0 12.9 J 45.3 1 1/8/2020 1.01 1.02 39.9 <1 0.20 J 1.94 NA 1 5.3 3.5 0.90 J 1.53 0.27 J NA 5.18 27.7 7/15/2020 <10.0 6.92 J 231 2.26 <2.00 5.81 1 17.4 1 22.9 78.9 4.99 J <10.0 <5.0 <10.0 91.3 114 1/13/2021 BDL BDL 145 1.81 J BDL 9.54 J 15.9 33.0 50.0 3.89 1 BDL BDL BDL 61.1 141 7/20/2021 2LStandard/GWP(µg"I 11.8 BDL 10 268 2.93 1.05 1 11.3 33.9 35.9 99.5 1 6.56 J BDL 20 BDL BDL 0.23 110 0_3a 327 1,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers B= The sample analyte is found in the associated blank. J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit Page 1 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA6010 Contaminant Of Concern o Q H Q £ 7 m ? >, m 2 E V E C V N V v C. V M J -Y Z C Ln y In = F f6 i N CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 W Dd Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual It Qual Result Qual Result Qual ult Qual Qual Result Qual Result Qual 9/14/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 <3.9 <5.0 77.6 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA <2.5 <5.0 MW-6 7/24/2019 <10.0 <10.0 51.3 <2.00 <2.00 <10.0 <10.0 <10.0 1.9 J <10.0 <10.0 <5.0 <10.0 9.14 J <50 1/8/2020 3.05 1.1 71.8 <1 0.20 J 1.82 NA 1.43 3.08 0.39 J 1.9 0.81 J NA 4.37 30.7 7/15/2020 <10.0 <10.0 84.4 <2.00 <2.00 <10.0 0.999 J <10.0 7.57 <10.0 <10.0 <5.0 <10.0 <20.0 18.3 J 1/13/2021 6.62 J BDL 67.0 BDL BDL 1.61 J BDL BDL BDL BDL BDL BDL BDL BDL 12.7 J 7/20/2021 BDL BDL 50.3 BDL BDL 1.99 J 1.12 1 BDL 5.68 J BDL BDL BDL BDL 6.69 J 7.56 J 9/14/2017 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1/9/2018 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 7/10/2018 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1/9/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trip Blank 7/24/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1/8/2020 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 7/15/2020 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 1/13/2021 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 7/20/2021 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 9/14/2017 <3.9 <5 <2.5 <0.5 <0.5 <2.5 <0.01 <2.5 <2.5 <2.5 <5 <2.5 <0.02 <2.5 13.3 1/9/2018 <3.9 <5 <2.5 <0.5 <0.5 <2.5 NA <2.5 <2.5 <2.5 <5 <2.5 NA <2.5 13.3 Field Blank 7/10/2018 <3.9 1 1 <5.0 <2.5 1 <.50 1 <.50 1 <2.5 NA 11 <2.5 <2.5 1 <2.5 11 <5.0 11 <2.5 1 1 NA <2.5 <5.0 1/9/2019 < <5 25 < <.50 <120 <2.05 <5205 <1%0 .05 NA0 <02.050 <5.0 74/ <10 <2.00 <<1205 .0 0 < <50 <.0 <.0 <5 <10 <2/2019 <50 1/8/2020 <10.0 I I <10.0 <2.5 1 1 <2.00 1 <2.00 <10.0 <10.01 1 <10.0 <5.00 1 <10.0 <10.0 <5.0 <10.0 I <20.00 <50 2LStandard/GWP (µg/L) 131 10 700 1 43 2 30 131 1,000 15 100 20 20 0.23 0.33 1,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers B= The sample analyte is found in the associated blank. J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit Page 2 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 Contaminant Of Concern N v Q C O L Q O 4)0 c N m O y £ O L U E O m v c L � o L V '6 O E O m E w O E O m c L E O E O m Y f C O C m N w H W 7 m ° n O CO a R W 9 L u r CO a R c C W J] O o L w R L W O 0 L E w O 0 L CAS # 67-64-1 1 107-13-1 1 71-43-2 1 74-97-5 1 75-27-4 1 75-25-2 1 74-83-9 1 78-93-3 1 135-98-8 1 75-15-0 1 56-23-5 1 108-90-7 1 75-00-3 1 67-66-3 W esult Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result I Qual I Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/13/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 NOT SAMPLED (DRY WELL) MW-1 7/24/2019 NOT SAMPLED (DRY WELL) 1/8/2020 NOT SAMPLED (DRY WELL) 7/15/2020 NOT SAMPLED (DRY WELL) 1/13/2021 32.5 J BDL 9.00 NA BDL BDL BDL I I BDL 1 0.137 J NA BDL 0.252 J BDL BDL 7/20/2021 NOT SAMPLED (DRY WELL) 9/13/2017 <10 <1.9 4.2 <0.18 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 4.7 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 7/10/2018 <10 <1.9 4.2 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 <.14 1/9/2019 <10 <1.9 3.5 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 <.14 MW-2R 7/24/2019 <50 <10 3.43 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/8/2020 5.72 J <10 2.53 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 7/15/2020 <50 <10 3.81 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/13/2021 BDL BDL 3.23 NA BDL BDL BDL BDL BDL NA BDL 0.124 J BDL BDL 7/20/2021 BDL BDL 3.07 NA NA BDL BDL BDL BDL NA BDL 0.155 J BDL BDL 9/13/2017 <10 <1.9 <0.25 <0.18 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 1.3 <0.54 <0.14 7/10/2018 10.2 J <1.9 0.34 J <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 1.2 0.89 J <.14 1/10/2019 23 J <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 <.14 MW-3S 7/24/2019 10.8 J <10 0.365 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 1.16 0.705 J <5.00 1/8/2020 <50 <10 0.24 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 0.88 0.68 J <5.00 7/15/2020 <50 <10 0.366 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 1.82 <5.00 <5.00 1/13/2021 161 BDL 0.328 J NA BDL BDL BDL BDL BDL NA BDL 1.34 J 0.451 J BDL 7/20/2021 34.9 J I BDL 0.284 J NA NA BDL BDL BDL BDL NA BDL 1.55 0.41 J BDL 9/13/2017 <10 <1.9 <0.25 <0.18 <0.18 <0.26 1 1 <0.29 1 <0.96 <1.2 1 <1.2 1 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 7/10/2018 <10 <1.9 0.41 J <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 0.34 J <.54 <.14 1/10/2019 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 0.35 <.54 <.14 MW-3D 7/24/2019 <50 <10 0.575 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 0.441 J 0.797 J <5.00 1/8/2020 9.16 J <10 0.43 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 0.35 J 0.78 J <5.00 7/15/2020 <50 <10 0.708 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 1.16 <5.00 <5.00 1/13/2021 BDL BDL 0.571 J NA BDL I BDL BDL BDL BDL NA BDL 0.597 J 0.427 J I BDL 7/20/2021 BDL I BDL 0.451 J NA NA BDL BDL BDL BDL NA BDL 0.583 J 0.362 J BDL 7/15/2020 <50 <10 0.69 J <1.00 <1.00 <1.00 1 1 <5.00 1 <10.0 <1.2 <1.2 <1.00 1.08 <5.00 <5.00 DUP(MW-3D) 1 1/13/2021 BDL BDL 0.607 J NA BDL BDL BDL BDL BDL NA BDL 0.596 J 0.481 J BDL 7/20/2021 BDL BDL 0.472 1 NA NA BDL BDL BDL BDL NA BDL 0.566 J 0.334 J BDL 9/13/2017 <10 <1.9 <0.25 <0.18 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 7/10/2018 <10 <1.9 0.33 J <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 <.14 1/9/2019 <10 <1.9 <.25 <.17 1 <.18 <.26 <.29 <.96 <1.2 <1.2 1 <.25 <.23 <.54 <.14 MW-4 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 0.875 J <5.00 1/8/2020 4.56 1 J I <10 0.19 J <1.00 <1.00 I <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 0.62 J <5.00 7/15/2020 <50 <10 1 0.402 J <1.00 <1.00 <1.00 1 <5.00 I <10.0 <1.2 <1.2 <1.00 0.198 J <5.00 <5.00 1/13/2021 BDL BDL 0.379 J NA BDL BDL BDL BDL BDL NA BDL 0.144 J 0.739 J BDL 7/20/2021 BDL BDL 0.384 J NA NA BDL BDL BDL BDL NA BDL 0.163 J 0.606 J BDL 9/14/2017 <10 <1.9 <0.25 <0.18 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 7/10/2018 11.3 J <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 < 54 <.14 1/9/2019 <10 <1.9 <.25 <.17 1 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 1 <.14 MW-5 7/24/2019 1 <50 <10 <1.00 I <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/8/2020 <50 1 1 <10 I <1.00 <1.00 <1.00 <1.00 1 <5.00 <10.0 <1.2 <1.2 1 <1.00 <1.00 <5.00 <5.00 7/15/2020 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/13/2021 BDL BDL BDL NA BDL BDL BDL BDL BDL NA BDL BDL BDL BDL 7/20/2021 BDL I I BDL I I BDL NA NA BDL BDL I I BDL BDL NA BDL BDL BDL BDL 2L Standard/GWP (µg/L) 6.000 1 1r NE 1 0.6 ° 0.6 M 4 1 1W 10 a 1 41000 70 0 3,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit Page 3 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 Contaminant Of Concern c y £ v c t � o c Y f w H ° w s L c u w `o s E L c c 6 E t V E O c _a -O r W aL+ w O y O E O E O E O E 3 m CO CO O o O 0 O 0 v L c O O a a Q Q m m m m m N V V V V V CAS # 67-64-1 107-13-1 71-43-2 74-97-5 75-27-4 75-25-2 74-83-9 78-93-3 135-98-8 75-15-0 56-23-5 108 90-7 75- 00-3 67-66-3 W esult Qual Result Qual ult I Qual I Result I Qual I Result I Qual I Result Qual I Result I Qual I Result I Qual I Res.L_L2tal,dJJJWEJftJ Result I Qual I Result I Qual I Result Qual IA&FULL2± 9/14/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 <.14 MW-6 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/8/2020 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 7/15/2020 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/13/2021 BDL BDL BDL NA BDL BDL BDL BDL BDL NA BDL BDL BDL BDL 7/20/2021 BDL BDL BDL NA NA BDL BDL BDL BDL NA BDL BDL BDL BDL 9/14/2017 <10 <1.9 <0.25 <0.18 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 1 <1.2 <1.2 <0.25 1 <0.23 <0.54 1 <0.14 7/10/2018 <10 I <1.9 1 <,25 1 <.17 1 <.18 1 <.26 <.29 <36 <1.2 1 <1.2 <,25 <.23 <.54 <,14 1/9/2019 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <,25 <,23 <,54 <.14 Trip Blank 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/8/2020 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <3.00 <1.00 <5.00 <5.00 7/15/2020 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <50.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/13/2021 BDL BDL BDL NA BDL BDL BDL BDL BDL NA BDL BDL BDL BDL 7/20/2021 BDL BDL BDL NA NA BDL BDL BDL BDL NA BDL BDL BDL BDL 9/14/2017 <10 <1.9 <0.25 <0.18 <0.18 <0.26 <0.29 <0.96 <1.2 <1.2 <0.25 <0.23 <0.54 <0.14 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 1 <1.2 <1.2 1 1 <0.25 1 <0.23 <0.54 <0.14 Field Blank 7/10/2018 1 <10 1 1 <1.9 1 1 <.25 1 1 <,17 1 <,18 <,26 <.29 <,96 <1.2 <1.2 <,25 <.23 <.54 <,14 1/9/2019 <SO <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <1.2 <.25 <.23 <.54 <,14 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.2 <1.00 <1.00 <5.00 <5.00 1/8/2020 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <12 <1.2 <1.00 <1.00 <5.00 <5.00 2L Standard/GWP (µg/L) 1 6,000 1 NE I 1 0.6 ° 1 0.6 1 4 1 103 1 4,000 70 1 0 700 0.3 50 3,000 70 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit Page 4 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 Contaminant Of Concern W c @ yE p c L c a o CL O L u M O O = 0 N C L y O O L O E O .0 m C y W O E O :2 0 N r L W O E O .0 O W y O O L u 0 N W W y O O :E u 0 V W c � O O L ey v i C L W O O :E u 0 ei C L N O O :E u 0 N C L W O O :E u 0 ei W c L O L u N r n � c W L O O L u N ri u i CAS # 74-87-3 96-12-8 124 48-1 106193-4 74-95-3 95-50-1 106 46-7 110 57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result I Qual ult Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/13/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 NOT SAMPLED (DRY WELL) MW-1 7/24/2019 NOT SAMPLED (DRY WELL) 1/8/2020 NOT SAMPLED (DRY WELL) 7/15/2020 NOT SAMPLED (DRY WELL) 1/13/2021 BDL BDL NA BDL BDL 0.293 J 1 15.9 1 1 NA 1.15 2.42 BDL 112 0.448 J 7/20/2021 NOT SAMPLED (DRY WELL) 9/13/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 4.3 <1.0 L1 16.5 <0.24 <0.56 36 1.2 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 4.8 <1.0 16.5 <0.24 <0.56 39.8 1.2 7/10/2018 <.11 <2.0 <.21 <.27 <.21 <.30 4.3 <1.0 14.5 0.83 J <.56 34.3 1.1 1/9/2019 <.11 <2.0 <.21 <.27 <.21 <.30 3.9 <1.0 12.5 <.24 <.56 28.4 <.49 MW-2R 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 4.04 1.03 12.5 <1.00 <1.00 28.7 1.03 1/8/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 2.58 <1 8.35 0.40 J <1.00 19.4 0.59 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 0.189 J 4.88 1.03 12.0 0.622 J <1.00 32.5 1.02 1/13/2021 BDL BDL NA BDL BDL 0.136 J 4.22 NA 9.98 0.526 J BDL 27.1 0.815 J 7/20/2021 BDL BDL BDL BDL BDL 0.215 J 4.81 NA 9.24 111 0.520 J I BDL C3 26.2 0.85 J 9/13/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 1.5 <1.0 I Ll <0.32 <0.24 <0.56 5.6 <0.49 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 1.8 <1.0 <0.32 <0.24 <0.56 4.5 <0.49 7/10/2018 <.11 <2.0 <.21 <.27 <.21 <.30 1.6 <1.0 0.74 J 0.54 J <.56 4.7 <.49 1/10/2019 <.11 <2.0 <.21 <.27 <.21 <.30 1.5 <1.0 0.61 J <.24 <.56 2.5 <.49 MW-35 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 1.56 <1.0 0.831 J <1.00 <1.00 3.81 <1.00 1/8/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 1.0 <1.0 0.41 J 0.17 J <1.00 1.97 <1.00 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 1.65 <1.0 0.528 J 0.259 J <1.00 2.52 <1.00 1/13/2021 BDL BDL NA BDL BDL BDL 1.55 NA 0.429 J 0.23 J BDL 1.35 BDL 7/20/2021 BDL BDL BDL BDL BDL 0.116 J BDL NA 0.451 J 0.272 J BDL C3 0.984 J BDL 9/13/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 2.6 <1.0 I Ll 1.8 <0.24 <0.56 <0.19 <0.49 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 3.8 <1.0 2.3 <0.24 <0.56 37.2 <0.49 7/10/2018 <.11 <2.0 <.21 <.27 <.21 <.30 3.5 <1.0 1.8 0.78 J <.56 17.3 1 1 <.49 1/10/2019 <.11 <2.0 <.21 <.27 <.21 <.30 3.3 <1.0 <.32 <.24 <.56 24.7 <.49 MW-31D 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 3.95 <1.0 2.05 0.696 J <1.00 23.4 <1.00 1/8/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 2.69 <1.0 1.29 0.49 J <1.00 13.7 <1.00 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 0.151 J 4.77 <1.0 1.76 0.711 J <1.00 16.5 <1.00 1/13/2021 BDL BDL NA BDL BDL 0.117 J 4.43 NA 1.51 0.589 J BDL 11.5 BDL 7/20/2021 BDL BDL BDL BDL BDL 0.174 J 5.00 NA 1.26 0.571 J I BDL C3 8.81 BDL 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 0.143 J 4.61 <1.0 1 1.7 0.712 J <1.00 15.8 <1.00 DUP(MW-3D) 1/13/2021 BDL BDL NA BDL BDL BDL 4.56 NA 1.56 0.656 J BDL 11.8 BDL 7/20/2021 BDL BDL BDL BDL BDL 0.168 J 4.87 NA 1.19 0.53 J BDL C3 7.58 BDL 9/13/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 2.2 <1.0 Ll 1.9 <0.24 <0.56 16.5 <0.49 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 2.1 <1.0 1.7 <0.24 <0.56 15.3 <0.49 7/10/2018 <.11 <2.0 <.21 <.27 <.21 <.30 2.2 <1.0 1.7 0.33 J <.56 15.8 <.49 1/9/2019 <.11 <2.0 <.21 <.27 <.21 <.30 1.8 <1.0 <.32 <.24 <.56 14.1 <.49 MW-4 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 2.12 <1.0 1.41 <1.00 <1.00 13.3 <1.00 1/8/2020 0.210 J 1 <5.00 1 <1.00 I <1.00 <1.00 <1.00 1.2 <1.0 0.83 1 1 <1.00 I <1.00 7.99 <1.00 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 6.117 J 2.46 1 <1.0 1.39 <1.00 <1.00 15.9 <1.00 1/13/2021 BDL BDL NA BDL BDL BDL 2.21 NA 1.39 0.106 J BDL 16 BDL 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA 1.15 BDL BDL C3 14.4 BDL 9/14/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 L1 <0.32 <0.24 <0.56 <0.19 <0.49 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 7/10/2018 <.11 <2.0 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 0.25 J <.56 <.19 <.49 1/9/2019 <.11 <2.0 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 MW-5 7/24/2019 <2.5 <5.00 1 <1.00 <1.00 <1.00 <1.00 I I <1.00 <1.0 I <1.00 <1.00 I <1.00 <1.00 <1.00 1/8/2020 <2.5 1 <5.00 1 <1.00 I <1.00 <1.00 <1.00 <1.00 <1.0 I <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 I <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 BDL BDL NA BDL BDL BDL BDL NA BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA BDL BDL BDL I C3 BDL BDL 11 2LStandard/GWP(µg/L) 3 0.04 0.4 0.4 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit C3= The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method senseitivity check is acceptable. L1= Analyte recovery in the laboratory control samples was above QC limits. Results for this analyte in associated samples may be biased high. Page 5 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 c a o m W c W W CL C W c W c L O L W W L L y C W W O C C C O Contaminant Of Concern W U M o y r y W O L L L L O L c @ o 2 W 0 r a 0 a o u w o w 0 w o o r u E O L E O W o o o `o o u p = O E :2 O E L u :E u H :E u :E u :E u N N ri c o O 9 O o o o o 0 �4 L N .0 N .0 N V i ey N ey n i 74 87-3 96-12-8 124 48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 We Qual Result Qual Result Qual It Qual RMEMillillial I Result Qual Result I Qual ult Qual R Qual Result I Qual Result Qual Jildib.1t Qual Result Qual 9/14/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 <.11 <2.0 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 MW-6 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 BDL BDL NA BDL BDL BDL BDL NA BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL 9/14/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 L1 <0.32 <0.24 <0.56 <0.19 <0.49 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 7/10/2018 <.11 1 2.0 <.21 <,27 <,21 <.30 1 <.33 <1.0 <.32 <,24 <,56 1 <.19 <,49 1/9/2019 <.11 <2.0 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 Trip Blank 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <2.5 <5.00 <3.00 <1.00 <1.00 <1.00 <1.00 <1.0 <3.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 BDL BDL NA BDL BDL BDL BDL NA BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL 9/14/2017 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 Ll <0.32 <0.24 <0.56 <0.19 <0.49 1/9/2018 <0.11 <2.0 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 Field Blank 7/10/2018 <.11 <2.0 <.21 <,27 <,21 <,30 <.33 <1.0 <.32 <,24 <,56 <.19 <,49 1/9/2019 <.11 <2.0 1 1 <.21 1 1 <,27 <,21 <.30 <.33 <1.0 <.32 <,24 <.56 <.19 <.49 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 2LStandard/GWP (µg/L) 0.04 0.4 0.02 70' 20 b 1 NE 6 0.4 350 70 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL lesultExceeds elow Laboratory Detection Limit NAot Analyzed by Method Shown Resultesult Exceeds Laboratory Detection Limit Result 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit C3= The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method senseitivity check is acceptable. L1= Analyte recovery in the laboratory control samples was above QC limits. Results for this analyte in associated samples may be biased high. Page 6 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 Contaminant Of Concern W R a 2 O. O tV H y C O O a ° O u rj v� •U y O. O CL 2 y N L d " w O G O. O n W C W T L W O N W S N N L W C -O w C G Oa W w y0„ G p '� C W L C > L W i Y m ? C C .2 r C N L W L Lu m W T L W C W L L Z C W rn c L O `o r u W N '+ ,-f ri c L O `o r u W N N ri rl W L C u i W F W 3 O F CAS # 78-87-5 10061-01-5 10061-02-6 108-20-3 100-41-4 591-78-6 74-88-4 98-82-8 99-87-6 75- 99-2 108-10-1 1634-04-4 91-20-3 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result I Qual I Result Qual Result I Qual I Result I Qual I Result I Qual I Result I Qual I Result I Qual I Result I Qual I Result I Qual I Result I Qual 9/13/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 NOT SAMPLED (DRY WELL) MW-1 7/24/2019 NOT SAMPLED (DRY WELL) 1/8/2020 NOT SAMPLED (DRY WELL) 7/15/2020 NOT SAMPLED (DRY WELL) 1/13/2021 2.55 NA BDL 0.28 J BDL NA NA 0,363 J 0.264 1 J I BDL I I BDL 1.6 3.42 J BDL BDL BDL 0.736 J 0.391 J 7/20/2021 NOT SAMPLED (DRY WELL) 9/13/2017 4.0 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 1/9/2018 4.1 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 7/10/2018 4.2 <.13 <26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <26 <.33 <.40 0.71 J <26 1/9/2019 <.27 <.13 <26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <26 <.33 <.40 <.46 <.26 MW-2R 7/24/2019 4.22 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 0.641 J <1.00 1/8/2020 2.69 <1.00 <1.00 NA <1.00 0.190 J 0.280 J <5.00 NA <5.00 <10.0 NA NA 0.180 J <1.00 <1.00 0.230 J <1.00 7/15/2020 4.46 <1.00 <1.00 0.269 J <1.00 NA NA 0.216 J NA <5.00 <10.0 0.34 NA <1.00 <1.00 <1.00 0.507 J <1.00 1/13/2021 3.76 NA BDL 0.234 J BDL NA NA 0.272 J BDL BDL BDL 0.323 J BDL BDL BDL BDL 0.313 J BDL 7/20/2021 3.64 BDL BDL 0.241 J BDL NA NA 0.421 J BDL BDL BDL 0.313 J BDL BDL BDL BDL BDL BDL 9/13/2017 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 1/9/2018 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 7/10/2018 0.39 J <.13 <.26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 <.26 1/10/2019 <.27 <.13 <26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 <.26 MW-3S 7/24/2019 0.508 J <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 0.290 J <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 0.168 J NA <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 0.295 J NA BDL BDL BDL NA NA BDL BDL BDL BDL 0.162 J BDL BDL BDL BDL BDL BDL 7/20/2021 0.394 J BDL BDL BDL BDL NA NA BDL BDL BDL BDL 0.187 J BDL BDL BDL BDL BDL BDL 9/13/2017 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 1/9/2018 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 7/10/2018 0.88 J <.13 <26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <26 <.33 <.40 <.46 <26 1/10/2019 <.27 <.13 <26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 <.26 MW-3D 7/24/2019 1.24 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 0.80 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 1.11 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 0.350 J NA <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 1.02 NA BDL BDL BDL NA NA BDL BDL BDL BDL 0.351 J BDL BDL BDL BDL BDL BDL 7/20/2021 0.977 J BDL BDL BDL BDL NA NA BDL BDL BDL BDL 0.36 J BDL BDL BDL BDL BDL BDL 7/15/2020 1.09 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 0.384 J NA <1.00 <1.00 <1.00 <1.00 <1.00 DUP(MW-3D) 1/13/2021 1.00 J NA BDL BDL BDL NA NA BDL BDL BDL BDL 0.337 J BDL BDL BDL BDL BDL BDL 7/20/2021 0.959 J BDL BDL BDL BDL NA NA BDL BDL BDL BDL 0.303 J BDL BDL BDL BDL BDL BDL 9/13/2017 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 1/9/2018 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 7/10/2018 0.38 J <.13 <.26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 <.26 1/9/2019 0.38 J <.13 <26 NA 1 <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <26 <.33 <.40 <.46 <.26 MW-4 7/24/2019 0.328 J <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 0.200 J <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 1 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 0.224 J NA <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 0.281 J NA BDL BDL BDL NA NA BDL BDL BDL BDL 0.236 J BDL BDL BDL BDL BDL BDL 7/20/2021 0.286 J BDL BDL BDL BDL NA NA 0.118 J BDL BDL BDL 0.243 J BDL BDL BDL BDL BDL 9/14/2017 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 1/9/2018 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 7/10/2018 <.27 <.13 <.26 NA 1.5 <.46 <.32 <.97 NA <.97 <.33 NA NA 1.1 <.33 <.40 <.46 1/9/2019 <.27 <.13 <26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 7/24/2019 <1.00 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 JBD 1/S/2020 <1.00 <1.00<1.00A <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 <1.00 NA <1.00 <1.00 <1.00 <1.00 1/13/2021 BDL NA BDL BDL BDL NA NA BDLBDL BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL BDL 0.139 J NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2LStandard/GWP(µg/L) 0.6 0.4 0.4 70 600 403 NE 70 NE 5 1003 20 b 70 13 0.2 0.7 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers 1= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit C9= Common Laboratory Contaminant Page 7 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 Y m y y ? c c W C O O. O d C L L L R O CL 2 " W 06 C LuCL O O W Contaminant Of Concern 222 CL O yL y W J L L L CLO O O W W C r L O. m u u u C L C N W C W W W LO Ci C C O W C C L L W N CL O W tC6 W EO p > L W T L L C W N N V rj n T L 2 -O Oa '� W W r ri N ri i W 7 O H U w N CL Z CAS # 78-87-5 10061-01-5 10061-02-6 108-20-3 100-41-4 591-78-6 74-88-4 98 82-8 99-87-6 75- 99-2 108 10-1 1632-04-4 91-20-3 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 Well ID Qual Result Qual Result Qual Result Qual Result Ift, I an Qual Result Qual Result Qual Result I Qual Result Result Qual Result Qual R Qual Result Qual Qual Qual Result Qual 9/14/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 <.27 <.13 <.26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 <.26 MW-6 7/24/2019 <1.00 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <1.00 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 <1.00 NA <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 BDL NA BDL BDL 0.217 J NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1.8 7/20/2021 BDL BDL BDL BDL 1.02 NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7.10 9/14/2017 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 1/9/2018 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 7/10/2018 <.27 <,13 <.26 1 NA <.30 1 <.46 <.32 <,97 NA I <,97 <.33 NA NA <,26 11 <.33 <.40 1 <.46 <.26 1/9/2019 <.27 <.13 <.26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA 1 <.26 <.33 <.40 <.46 <.26 Trip Blank 7/24/2019 <1.00 <1.00 <1.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <3.00 <3.00 <3.00 NA <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 NA NA <1.00 NA <5.00 <10.0 <1.00 NA <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 BDL NA BDL BDL BDL NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL BDL BDL NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 9/14/2017 <0.27 <0.13 <0.26 NA <0.3 <0.46 <0.32 <0.97 NA <0.97 <0.33 NA NA <0.26 <0.33 <0.4 <0.46 <0.26 1/9/2018 <0.27 <0.13 1 <0.26 NA 1 1 <0.3 1 1 <0.46 <0.32 1 <0.97 1 1 NA <0.97 1 1 <0.33 1 1 NA NA <0.26 1 <0.33 1 1 <0.4 1 1 <0.46 <0.26 Field Blank 7/10/2018 <.27 <.13 <.26 NA <.30 <.46 <.32 <.97 NA <.97 <.33 NA NA <.26 <.33 <.40 <.46 <.26 142 <.27 < <126 NA <.30 <46 <132 .6 C9 NA 1.6 C9 <.33 < 3 <1.030 <1400 <1460 7/2019 <.0 <.0 00/9/ < 1/8/2020 1 <1.00 <1.00 1 <1.00 NA I <1.00 <1.00 <1.00 <5.00 NA <5.00 <10.0 NA NA <1.00 <1.00 <1.00 2LStandard/GWPLgg/L) I k6 1 0.4 1 0.4 70 600 4(3 NE 70 NE 5 1003 20 6 1 70 1 13 1 0.2 0.7 600 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result d Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit C9= Common Laboratory Contaminant Page 8 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 W C W C C C C C C Contaminant Of Concern 6 aL- O 6 aL- O C O L E O O O C O L T L L T L L T L N W O L u O L u L o c L u E E E t0 y o R F F F O O F F F F u W rl N L u L u CM CM ul C rl rl F F -1 rl rl rl i i X CAS # 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 95-63-6 526-73-8 108-67-8 108-05-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/13/2017 NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 NOT SAMPLED (DRY WELL) MW-1 7/24/2019 NOT SAMPLED (DRY WELL) 1/8/2020 NOT SAMPLED (DRY WELL) 7/15/2020 NOT SAMPLED (DRY WELL) 1/13/2021 BDL BDL 1.01 BDL BDL 1 1.93 1 1 0.192 J 2.91 NA 3.57 4.34 7/20/2021 NOT SAMPLED (DRY WELL) 9/13/2017 <0.48 <0.29 3.7 <0.2 <0.41 NA <0.41 NA <0.35 5.2 <0.66 1/9/2018 <0.48 <0.29 2.8 <0.2 <0.41 NA <0.41 NA <0.35 6.4 <0.66 7/10/2018 <.48 <.29 2.9 <.20 <.41 NA <.41 NA <.35 4.6 <.66 1/9/2019 <.48 <.29 2.2 <.20 <.41 NA <.41 NA <.35 4.2 <.66 MW-2R 7/24/2019 <1.00 <1.00 2.76 <5.00 <2.50 NA <2.50 NA <1.00 4.51 <3.00 1/8/2020 <1.00 <1.00 1.55 <5.00 <2.50 NA <2.50 NA <1.00 3.65 <3.00 7/15/2020 <1.00 <1.00 2.09 <5.00 <2.50 NA 0.141 J NA NA 4.17 <3.00 1/13/2021 BDL BDL 1.46 BDL BDL BDL 0.138 J BDL NA 3.77 BDL 7/20/2021 BDL BDL 1 1 0.700 J 0.160 C3 J I BDL BDL BDL BDL NA 4.02 C3 BDL 9/13/2017 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 2.5 <0.66 1/9/2018 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 2.7 <0.66 7/10/2018 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 2.8 <.66 1/10/2019 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 2.6 <.66 MW-3S 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 3.29 <3.00 1/8/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <1.00 NA NA 1.85 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL I NA 1.51 BDL 7/20/2021 BDL BDL I BDL BDL C3 BDL BDL BDL BDL NA 1.13 C3 BDL 9/13/2017 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 17.3 <0.66 1/9/2018 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 12.7 <0.66 7/10/2018 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 13.0 <.66 1/10/2019 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 12.6 <.66 MW-3D 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 13.6 <3.00 1/8/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 9.70 <3.00 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <1.00 NA NA 10.2 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL I NA 8.48 BDL 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 5.74 C3 0.390 J 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <1.00 NA NA <1.00 DUP(MW-3D) 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL NA 8.81 BDL 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 5.7 C3 0.936 J 9/13/2017 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 14.5 <0.66 1/9/2018 <0.48 <0.29 <0.47 1 <0.2 <0.41 NA 1 <0.41 NA 1 <0.35 13.9 <0.66 7/10/2018 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 14.0 <.66 1/9/2019 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 10.9 <.66 MW-4 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 12.3 <3.00 1/8/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 7.7 <3.00 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <1.00 NA NA 10.4 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL NA 11.6 BDL 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 9.62 C3 BDL 9/14/2017 <0.48 <0.29 <0.47 <0.2 <0.41 1 NA <0.41 NA 1 <0.35 <0.62 <0.66 1/9/2018 <0.48 <0.29 <0.47 1 1 <0.2 <0.41 NA <0.41 NA <0.35 <0.62 <0.66 7/10/2018 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 <.62 <.66 1/9/2019 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 <.62 1 <.66 MW-5 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 1/8/2020 <1.00 <.00 <5.0 <2.500 NA <1.00 <1.00 <3.00 <1.00 00 <1.00 <500 <7/15/2020 2.50 NA <1.00 NA A <1.00 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL NA BDL BDL 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA BDL C3 BDL 21- Standard/(iWP Wg/L) I ZOO 1 0.6' 11 E41JU UU 88' 1 5UU Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit BDL Below Laboratory Detection Limit C3 = The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. NA Not Analyzed by Method Shown Method senseitivity check is acceptable. Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Page 9 of 10 TABLE 4 GROUNDWATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 W C 6 aL- W C 6 aL- L E C R O C C L C L C L Contaminant Of Concern O O C O O T T T O O O L O L L L O W L u L u o 0 L u E E E t0 y O 0 F F F O O F F F F u W rl N L u L u Ch Ch ul C lu N N N N S S ri ri It It .4 1 .-i .-i > > X CAS # 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 95-63-6 526-73-8 108-67-8 108-05-4 75-01-4 1330-20-7 Well Date Collected 9/14/2017 Qual Result Qual It Qual R I R Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual NOT SAMPLED (DRY WELL) 1/9/2018 NOT SAMPLED (DRY WELL) 7/10/2018 NOT SAMPLED (DRY WELL) 1/9/2019 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 <.62 <.66 MW-6 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 1/8/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 7/15/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <1.00 NA NA <1.00 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL NA BDL BDL 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA BDL C3 BDL 9/14/2017 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 <0.62 <0.66 1/9/2018 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 <0.62 <0.66 7/10/2018 <.48 <.29 1 1 <,47 1 <,20 1 <.41 1 NA <,41 NA <.35 <.62 <.66 1/9/2019 <.48 <.29 <.47 <.20 <.41 NA <.41 NA <.35 <.62 <.66 Trip Blank 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 1/8/2020 <5.00 <5.00 <5.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 7/15/2020 <5.00 <5.00 <5.00 <5.00 <2.50 NA <1.00 NA NA <1.00 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL NA BDL BDL 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA BDL C3 BDL 9/14/2017 <0.48 <0.29 <0.47 <0.2 <0.41 NA <0.41 NA <0.35 <0.62 <0.66 1/9/2018 <0.48 <0.29 <0.47 <0.2 1 <0.41 1 NA <0.41 NA 1 <0.35 <0.62 1 <0.66 Field Blank 7/10/2018 <.48 <.29 1 1 <,47 1 1 <,20 <.41 1 NA I <,41 1 NA <,35 1 <.62 <,66 1/9/2019 <.48 <.29 <,47 <,20 <.41 NA <,41 NA <,35 <.62 <,66 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 1/8/2020 <1.00 <1.00 <1.00 <5.00 <2.50 NA <2.50 NA <1.00 <1.00 <3.00 2LStandard/GWP (µg/L) 200 0.63 1 3 2,000 0.005 400 NE 400 88' 0.03 500 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit BDL Below Laboratory Detection Limit C3 = The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. NA Not Analyzed by Method Shown Method senseitivity check is acceptable. Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Page 10 of 10 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 6010 EPA 6010 Contaminant Of Concern T C O E Q u Q 3 m _ m EE U E o U ++ U a U u Z E N ; in £ H E c 1 N CAS # 7440-36-0 1 7440-38-2 1 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 1 7440-28-0 1 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/14/2017 <3.9 <5 36.4 <0.5 <0.5 <2.5 0.7 <2.5 <2.5 <2.5 <5 <2.5 <0.02 <2.5 <5 1/9/2018 <3.9 <5 30.6 <0.5 <0.5 <2.5 NA <2.5 <2.5 <2.5 <5 <2.5 NA <2.5 <5 7/10/2018 <3.9 <5.0 33.7 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA <2.5 <5.0 1/9/2019 <3.9 <5.0 30.9 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 4.0 J <5.0 SW-1 7/24/2019 <10.0 <10.0 36.9 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.00 <10.0 8.02 J <50 1/8/2020 1.05 0.23 J 26.7 <1 <1 2.15 <10.0 1.89 0.72 J 1.3 0.37 J 0.13 J NA 4.44 10.3 7/15/2020 <10.0 <10.0 44.2 <2.00 <2.00 <10.0 1.45 J <10.0 5.68 J <10.0 <10.0 <5.00 <10.0 <20.0 19.7 J 1/13/2021 BDL BDL 30.4 BDL BDL 2.02 J 1.07 J BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 4.31 J BDL 36.60 BDL BDL 1.71 J BDL BDL 3.02 J BDL BDL BDL BDL BDL BDL 9/14/2017 <3.9 <5 37.0 <0.5 <0.5 <2.5 0.7 <2.5 <2.5 <2.5 <5 <2.5 <0.02 <2.5 <5 1/9/2018 <3.9 <5 36.2 <0.5 <0.5 <2.5 NA <2.5 <2.5 <2.5 <5 <2.5 NA <2.5 <5 7/10/2018 <3.9 <5.0 34.0 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA <2.5 <5.0 1/9/2019 <3.9 <5.0 33.7 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 4.4 J <5.0 SW-2 7/24/2019 <10.0 <10.0 1 38.4 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.00 <10.0 5.97 J <50 1/8/2020 0.83 J 0.250 J 29.1 <1 <1 2.22 NA 2.84 0.650 J 0.730 J <1 0.100 J NA 4.43 11.9 7/15/2020 <10.0 <10.0 38.7 <2.00 <2.00 <10.0 0.974 J <10.0 <6.00 <10.0 <10.0 <5.00 <10.0 <20.0 15.8 J 1/13/2021 BDL BDL 33.0 BDL BDL 1.87 J 1.15 J BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL 41.10 BDL BDL 1.690 J 1.44 J BDL BDL BDL BDL BDL BDL BDL BDL 9/14/2017 <3.9 <5 36.7 <0.5 <0.5 <2.5 0.63 <2.5 <2.5 <2.5 <5 <2.5 <0.02 <2.5 <5 1/9/2018 <3.9 <5 30.5 <0.5 <0.5 <2.5 NA <2.5 <2.5 <2.5 <5 <2.5 NA <2.5 <5 7/10/2018 <3.9 <5.0 38.5 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA <2.5 <5.0 1/9/2019 <3.9 <5.0 30.1 <.50 <.50 <2.5 NA <2.5 <2.5 <2.5 <5.0 <2.5 NA 3.9 J <5.0 SW-3 7/24/2019 <10.0 <10.0 38.7 <2.00 <2.00 <10.0 <10.0 <10.0 2.24 J <10.0 <10.0 <5.00 <10.0 6.81 J <50 1/8/2020 0.65 J 0.21 J 28.2 <1 <1 2.09 NA 2.01 0.68 J 0.740 J <1 <1 NA 4.38 16.5 7/15/2020 <10.0 <10.0 35.4 <2.00 <2.00 <10.0 <10.0 <10.0 3.16 J <10.0 <10.0 <5.00 <10.0 <20.0 15.0 J 1/13/2021 BDL BDL 30.6 BDL BDL BDL 1.23 J BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL 38.4 BDL BDL BDL 0.866 J BDL BDL BDL BDL BDL BDL 6.86 J BDL 2B Standard (µg/L) NET 150 NE 0.155 245 NE 2.75 0.545 165 5 0.06 NE NE 365 Notes: All results provided in µg/L (micrograms per liter) or parts per billion 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NE = 2B Standard not established 2B standard at 25mg/L hardness BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 1 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 0614180.48 Analytical Method EPA 8260 v c a 0 v c a Contaminant Of Concern ° E o a, LU °1 ° w E o c s w u i c N y M O N = 0 0 O O O 0 �° 0 0 O O O O c E E E E -0 - O O O O 0 v U U (D 2 2 o 2 m @ L L L L N Q Q m m m m m N U U U U U U ai CAS # 67-64 1 1 107-13-1 1 71-43 2 1 74-97 5 1 75-27 4 1 75-25 2 1 74-83 9 1 78-93 3 1 75-15 0 1 56-23 5 1 108-90-7 1 75-00-3 67-66-3 74-87-3 96-12-8 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/14/2017 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 1 <0.25 <0.23 1 <0.54 <0.14 <0.11 <2.0 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 7/10/2018 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <.25 <.23 <.54 <.14 <.11 <2.0 1/9/2019 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <.25 <.23 <.54 <.14 <.11 <2.0 SW-1 7/24/2019 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 1/8/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 7/15/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 1/13/2021 BDL BDL BDL NA BDL BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL NA BDL C3 BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 9/14/2017 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 7/10/2018 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <.25 <.23 <.54 <.14 <.11 <2.0 1/9/2019 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <.25 <.23 <.54 <.14 <.11 <2.0 SW-2 7/24/2019 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 1/8/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 7/15/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 1/13/2021 BDL BDL BDL NA BDL BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL NA BDL C3 BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 9/14/2017 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 1/9/2018 <10 <1.9 <0.25 <0.17 <0.18 <0.26 <0.29 <0.96 <1.2 <0.25 <0.23 <0.54 <0.14 <0.11 <2.0 7/10/2018 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <.25 <.23 <.54 <.14 <.11 <2.0 1/9/2019 <10 <1.9 <.25 <.17 <.18 <.26 <.29 <.96 <1.2 <.25 <.23 <.54 <.14 <.11 <2.0 SW-3 7/24/2019 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 1/8/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 7/15/2020 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 1/13/2021 BDL BDL BDL NA BDL BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 7/20/2021 BDL BDL BDL NA BDL C3 BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 213 Standard (µg/L) NE NE 51 NE NE NE NE NE NE NE NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 4) NE = 2B Standard not established BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard Qualifiers C3= The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method senseitivity check is acceptable. Page 2 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 0614180.48 Analytical Method EPA 8260 Contaminant Of Concern = y £ cc s u O E 0 .2 o W O (p L E O N eti c r- a, £ O E 0 O GJ N N c .0 0 O L u 0 N -4 GJ N N c .0 0 O L u 0 V c � O L ° 0 ? ti in i c s v 0 O L u 0 e-i e4 c s a 0 O L u 0 N -4 c s y v o O L u 0 e-i ++ y o `O u_ 0 N vt u aL+ O i c O N r in i N ra p, o a 0 O L u N -4 CL O a o O u_ 0 ut U y 0 O L c Cl r in i Y w w N c N T aL+ W CAS # 124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/14/2017 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 L1 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 726 <0.3 1/9/2018 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 7/10/2018 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 <.27 <.13 <.26 <.30 1/9/2019 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 <.27 <.13 <.26 <.30 SW-1 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 NA BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL BDL BDL BDL BDL 9/14/2017 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 L1 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 1/9/2018 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 7/10/2018 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 <.27 <.13 <.26 <.30 1/9/2019 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 <.27 <.13 <.26 <.30 SW-2 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 -1.00 <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 0.164 J <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 NA BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL BDL BDL BDL BDL 9/14/2017 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 L1 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 1/9/2018 <0.21 <0.27 <0.21 <0.3 <0.33 <1.0 1 <0.32 <0.24 <0.56 <0.19 <0.49 <0.27 <0.13 <0.26 <0.3 7/10/2018 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 0.28 J <.49 <.27 <.13 <.26 <.30 1/9/2019 <.21 <.27 <.21 <.30 <.33 <1.0 <.32 <.24 <.56 <.19 <.49 <.27 <.13 <.26 <.30 SW-3 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 1/8/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 7/15/2020 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 1/13/2021 NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7/20/2021 NA BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL BDL r BDL BDL BDL 213 Standard (µg/L) NE NE 11 NE NE NE NE NE NE NE NE NE NE ONE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 4) NE = 2B Standard not established Qualifiers C3= The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method senseitivity check is acceptable. J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. BDL Below Laboratory Detection Limit L1= Analyte recovery in the laboratory control samples was above QC limits. Results for this analyte in associated samples may be biased high. NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard Page 3 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 0614180.48 g v w 41 L L C f6 N O C O O Wm N +L+ O. +m+ O O O aL+ ate+ N O Contaminant Of Concern s a�i u u c C v y a co ` v t 'i O OL LN 'i YyR U p ~ f6 GyJ N T L a+ y C ~ N ~ N y N C 1- i H O O H f6 L U N N O at+ N >V H N i j e� N L L M T T N N u) ' -i I.- H a-i -i > > X CAS # 591-78-6 74-88-4 75-09-2 1 108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 108-05-4 75-01-4 1330-20-7 Well ID I Date Collected Result I Qual Result I Qual Result I Qual I Result I Qual Result I Qual I Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual Result I Qual I Result JA 9/14/2017 <0.46 <0.32 1 <0.97 1 <0.33 1 <0.26 1 <0.33 1 <0.4 1 <0.46 1 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 1/9/2018 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 7/10/2018 <.46 <.32 <.97 <.33 <.26 <.33 <.40 <.46 <.26 <.48 <.29 <.47 <.20 <.41 <.35 <.62 <.66 1/9/2019 <.46 <.32 <.97 <.33 <.26 <.33 <.40 <.46 <.26 <.48 <.29 <.47 <.20 <.41 <.35 <.62 <.66 SW-1 7/24/2019 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 1/8/2020 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 7/15/2020 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL 7/20/2021 NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL C3 BDL NA BDL BDL 9/14/2017 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 1/9/2018 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 7/10/2018 <.46 <.32 <.97 <.33 <.26 <.33 <.40 <.46 <.26 <.48 <.29 <.47 <.20 <.41 <.35 <.62 <.66 1/9/2019 <.46 <.32 <.97 <.33 <.26 <.33 <.40 <.46 <.26 <.48 <.29 <.47 <.20 <.41 <.35 <.62 <.66 SW-2 7/24/2019 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 1/8/2020 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 7/15/2020 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL 7/20/2021 NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL C3 BDL NA BDL BDL 9/14/2017 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 1/9/2018 <0.46 <0.32 <0.97 <0.33 <0.26 <0.33 <0.4 <0.46 <0.26 <0.48 <0.29 <0.47 <0.2 <0.41 <0.35 <0.62 <0.66 7/10/2018 <.46 <.32 <.97 <.33 <.26 <.33 <.40 <.46 <.26 <.48 <.29 <.47 <.20 <.41 <.35 <.62 <.66 1/9/2019 <.46 <.32 <.97 <.33 <.26 <.33 <.40 1 <.46 1 <.26 <.48 1 <.29 1 <.47 <.20 <.41 <.35 <.62 <.66 SW-3 7/24/2019 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 1/8/2020 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 7/15/2020 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL NA NA BDL BDL 7/20/2021 NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL C3 BDL NA BDL BDL I� 213 Standard (µg/L) I ]L NE 1 NE I NE' I j NE I i NE I NE I M4 1 3.3 11 ' NE 30 ' NE NE NE ' 2.4 NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 4) NE = 2B Standard not established BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard ualifiers C3= The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method senseitivity check is acceptable. Page 4 of 4 TABLE 6 SUMMARY OF MNA CONSTITUENTS TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 300.0 EPA 353.2 RSK 175 SM 2320B SM 3500-Fe B SM 4500-CI-E SM 4500-S2D SM 5210B SM 5220D AM20GAX SM 5310B Contaminant Of Concern y a v i Z c 0 OA �= Z W m aL Lu N N r w w m aL+ w co U F _ �C Q 7 o LL L 0 .6 `0 L U y LA C R p c T 0 •� �., 2 C) 00 m c? R X u_ _ C) s0 U V bo °tea = 0 0 U C O R U 00 I - CAS # 14808-79 8 NA 74-84 0 74-85 1 74-82 8 NA NA 16887-00-6 18496-25-8 NA NA AM20GAX 7440-44-0 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual 9/13/2017 <500 94.8 <0.87 <0.77 2440 146,000 <500 H1,N2 10,200 <100 7,710 <12,500 <10 1,320 7/10/2018 <500 86.4 <10 <10 7570 143,000 <500 N2, H6 10,700 <100 <2000 L2, B2 12,500 NA 524 J 1/9/2019 <500 <10 <10 <10 8180 148,000 <500 N2, H3 11,700 <50 2,640 H2 12,700 J NA 1,050 MW-2R 7/24/2019 <5,000 80.0 J <13 <13 3700 129,000 521 T8 9,650 <50 <2,000 K1, K6 <10,000 NA 1,380 B 1/8/2020 <10,000 54.0 1 <0.10 <0.10 2800 123,000 1 0 1 14,000 <50 <2,000 <5,000 7.3 <1,000 7/15/2020 <5,000 59.1 J NA NA NA 132,000 NA 11,400 J <50 NA NA NA 813 B, J 1/13/2021 812 J 63.1 J NA NA NA 135,000 NA 9,560 BDL NA NA NA 983 7/20/2021 986 J BDL NA NA NA 141,000 NA 10,500 BDL NA NA NA 1,170 B 9/13/2017 1,330 <10 <0.87 <0.77 56.4 170,000 <500 H1,N2 30,300 148 3,210 <12,500 <10 5,170 7/11/2018 572 J <10 <10 <10 429 155,000 <500 N2, H6 35,100 <100 <2000 L2 38,000 NA 3,500 1/10/2019 596 J <10 <10 <10 351 163,000 <500 N2, H3 30,900 59.9 J <2000 <12,500 NA 2,260 MW-3S 7/24/2019 <5,000 <100 1 <13 <13 207 152,000 488 T8 31,300 <50 1 <2,000 K1, K6 10,200 NA 1,870 B 1/8/2020 <10,000 <50 1 2.30 0.130 190 147,000 1 500 1 35,000 <50 <2,000 <5,000 8.7 2,070 7/15/2020 <5,000 <100 NA NA NA 159,000 NA 34,900 <50 J6 NA NA NA 2,020 B 1/13/2021 949 J BDL NA NA NA 152,000 NA 34,600 BDL NA NA NA 3,590 7/20/2021 938 J BDL NA NA NA 167,000 NA 36,500 BDL NA NA NA 3,020 B 9/13/2017 <500 M1 <10 <0.87 <0.77 90 176,000 <500 H1,N2 18,300 <100 <2000 <12,500 <10 <500 7/11/2018 <500 <10 <10 I <10 9340 167,000 <500 N2, H6 20,000 <100 <2000 36,000 NA 1,830 1/10/2019 705 J <10 <10 <10 M1 1030 M1 173,000 <500 N2, H3 18,900 <50 1 <2000 <12,500 NA 989 J MW-3D 7/24/2019 97.5 J <100 <13 <13 590 156,000 35.0 J, T8 18,700 <50 1 <2,000 K1, K6I <10,000 NA 1,370 B 1/8/2020 <10,000 <50 1 2.40 1A0 320 154,000 0 1 20,500 <50 <2,000 <5,000 5.6 1,030 7/15/2020 <5,000 <100 NA NA NA 164,000 NA 21,900 <50 NA NA NA 1,010 B 1/13/2021 960 J BDL NA NA NA 164,000 NA 23,600 BDL NA NA NA 1,160 B 7/20/2021 858 J BDL NA NA NA 178,000 NA 27,000 BDL NA NA NA 1,460 B 9/13/2017 <500 <10 <0.87 <0.77 315 194,000 <500 H1,N2 16,700 <100 3,360 <12,500 <10 2,070 7/10/2018 <500 <10 <10 <10 1070 183,000 590 N2, H6 18,300 <100 <2000 L2, B2 12,500 M1, R1 NA 2,070 1/9/2019 <500 <10 <10 <10 969 192,000 <500 N2, H3 17,400 <50 <2000 H2 <12,500 NA 1,070 MW-4 7/24/2019 <5,000 58.1 J <13 <13 345 170,000 999 T8 17,500 <50 1 1 <2,000 K1, K <10,000 NA 1,400 B 1/8/2020 <10,000 <50 <0.10 1A0 240 166,000 500 18,500 <50 <2,000 <5,000 5.8 <1,000 7/15/2020 <5,000 <100 NA NA NA 177,000 NA 19,100 <50 NA NA NA 854 B, J 1/13/2021 728 J BDL NA NA NA 169,000 NA 21,300 BDL NA NA NA 1,230 B P1 7/20/2021 662 J BDL NA NA NA 189,000 NA 24,000 BDL NA NA NA 1,250 B 9/14/2017 NOT SAMPLED (DRY WELL) 1/9/2019 7,310 <10 <10 <10 <10 5,480 <500 N2, H3 897 J <50 M1 <2000 H2 <12,500 NA 1,140 7/24/2019 4,070 J <100 <13 <13 27.2 17,300 J 3160 T8 1,950 7.00 J <2,000 K1, K <10,000 NA 1,370 B MW-6 1/8/2020 10,400 69.0 <0.10 <0.10 <0.50 5,820 0 4,000 <50 <2,000 <5,000 5.4 <1,000 7/15/2020 3,670 J <100 NA NA NA 11,700 J NA 1,700 <50 NA NA NA 2,450 B 1/13/2021 5,390 66.1 J NA NA NA 16,300 NA 1,360 BDL NA NA NA 1,360 B P1 7/20/2021 5130 BDL NA NA NA 9 960 J NA 1550 BDL NA NA NA 2 280 B 2L Standard/GWP (µ /L) 250,000 10,000 NE NE E 00 250,000 NE NE NE NE Notes: All results provided in µg/L (micrograms per liter) or parts per billion 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L Interim Maximum Allowable Concentration (IMAC) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established NE = 2L Standard or GWP not established. A detection is considered an exceedance. Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers B= The sample analyte is found in the associated blank. B2= Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the diluation using the most amount of sample. C9= Common Laboratory Contaminant H2= Extraction or preparation conducted outside of the EPA method holding time. H3= Sample was received or analysis requested beyond the recognized method holding time. H6= Analysis initiated outside of the 15 minute EPA required holding time. J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit J6= The sample matrix interfered with the ability to make any accurate determinations; spike value was low K1= The sample dilutions set-up for the BOD-CBOD analysis did not meet the oxygen depletion criteria of at least 2mg/L. Reported result is an estimated value. K6= Glucose/glutamic acid BOD/CBOD was below method acceptance criteria. L2= Analyte recovery in the laboratory control sample was below QC limits. Results for this analyte in assocated samples may be biased low. M1= Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample recovery. N2= The lab does not hold TNI accreditation for this parameter. P1= RPD value not applicable for sampline concentrations less than 5 time the reporting limit R1= RPD value was outside control limits. T8= Sample(s) received past/too close to holding time expiration. Page 1 OF 1 TABLE 7 BIODEGRADATION SCREENING MATRIX Town of Kernersville Closed Landfill Permit #34-04 Parameter Concentration in Plume Interpretation Possible Points Points Awarded Oxygen* < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 > 5 mg/L Not tolerated, vinyl chloride may be oxidized aerobically -3 0 Nitrate* < 1 mg/L At higher concentrations may compete with reductive pathway 2 2 1 Iron II (Ferrous Iron)* ( 7/24/19) > 1 mg/L Reductive pathway possible; vinyl chloride may be oxidized under Fe (III) - reducing conditions 3 0 Sulfate* < 20 mg/I At higher concentrations may compete with reductive pathway 2 2 Sulfide* > 1 mg/L Reductive pathway possible 3 3 Methane* (11/8/2020) < 0.5 mg/L Vinyl chloride oxidizes 0 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride accumulates 3 3 Oxidation Reduction Potential < 50 mV Reductive pathway possible 1 0 <-100 mV Reductive pathway likely 2 0 pH* 5 < pH < 9 Optimal range for reductive pathway 0 0 5 > ph > 9 Outside optimal range for reductive pathway -2 0 TOC > 20 mg/L Carbon and enegy source; drives dechlorination; can be natural or anthro o enic 2 0 Temperature* > 20'C lAt T> 200C, biochemical process is accelerated 1 0 Carbon Dioxide (CO2) (NA) > 2x background Ultimate oxidative daughter product 1 0 Alkalinity > 2x background Results from interaction between CO2 and aquifer minerals 1 1 Chloride* > 2x background Daugher product of organic chlorine 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 < 1 nM Vinyl chloride oxidizes 0 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more complex compounds; carbon and energy source 2 0 BTEX* > 0.1 mg/L Carbon and enegy source; drives dechlorination 2 0 Tetrachloroethane (PCE) --- Material released 0 0 Trichloroethane (TCE) --- Material released 0 0 Daughter product of PCE 2 0 Dichloroethene (DCE)* --- Material released 0 0 Daughter product of TCE 2 0 Dichloroethene, cis-1,2 --- Material released 0 0 Daughter product of trichloroethene 2 0 Vinyl Chloride* --- Material released 0 0 Daughter product of DCE 2 0 1,1,1-Trichloroethane (TCA)* --- Material released 0 0 1,1-Dichloroethane (DCA) --- Material released 0 0 Daughter product of TCA 2 0 Chloroethane* --- Daughter product of dichloroethane or vinyl chloride under reducing conditions 2 0 Ethene/Ethane (11/8/2020) > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 2 > 0.1 mg/L 3 0 Chloroform --- Material released 0 0 Daughter product of carbon tetrachloride 2 0 Dichloromethane (Methylene Chloride) --- Material released 0 0 Daughter product of chloroform 1 2 0 Total Points Awarded: 18 mg/L = miligrams per Liter * Required analysis mV = millivolts Analyte not sampled in July 2021 sampling event due to relief from SWS. nM = Nanometer Score is based on last sample analyzed during "recent sampling period" as C = Celcius indicated by (1 date) beside parameter listing. NA = Not analyzed BTEX = Sum of benzene, toluene, ethylbenzene and total xylenes This screening matrix is prepared in general accordance with the USEPA's Table 2.3 Analytical Parameters and Weighted far Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evidence of Natural Attentuation < 5 Inadequate 6-14 Limited 15-19 Adequate >20 Strong Pagel of 1 APPENDIX I Laboratory Analytical Reports and Field Notes a 6 aceAnalytical ANALYTICAL REPORT August 03, 2021 Withers & Ravenel Eng. - Standard Sample Delivery Group: L1380832 Samples Received: 07/21/2021 Project Number: 06140180.39 Description: Kernersville Landfill Report To: Laura Elliott 115 MacKenan Drive Cary, NC 27511 Entire Report Reviewed By Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and 16 ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. 0 M FC FSS [Cn] u FC E FAI FC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 1 of 51 TABLE OF CONTENTS Cp: Cover Page Tc: Table of Contents Ss: Sample Summary 3 Cn: Case Narrative 6 Sr: Sample Results 7 MW-5 L1380832-01 7 MW-2R L1380832-02 9 MW-3S L1380832-03 12 MW-3D L1380832-04 15 DUPLICATE L1380832-05 18 MW-4 L1380832-06 20 MW-6 L1380832-07 23 SW-1 L1380832-08 26 SW-2 L1380832-09 28 SW-3 L1380832-10 30 TRIP BLANK L1380832-11 32 TRIP BLANK L1380832-12 34 Qc: Quality Control Summary 36 Wet Chemistry by Method 2320 B-2011 36 Wet Chemistry by Method 4500S2 D-2011 37 Wet Chemistry by Method 9056A 38 Wet Chemistry by Method 9060A 40 Metals (ICP) by Method 6010D 41 Volatile Organic Compounds (GC/MS) by Method 8260D 43 GI: Glossary of Terms 48 Al: Accreditations & Locations 49 Sc: Sample Chain of Custody 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 2 of 51 MW-5 L1380832-01 GW Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D MW-2R L1380832-02 GW SAMPLE SUMMARY Collected by Laura Elliott Batch WG1712545 WG1710319 WG1716050 Collected date/time Received date/time 07/20/2110:20 07/21/2108:30 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/28/2121:23 07/30/2101:19 CCE Mt. Juliet, TN 1 07/22/2118:55 07/22/2118:55 ACG Mt. Juliet, TN 1 08/02/2121:26 08/02/2121:26 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2111:23 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/2107:19 07/25/2107:19 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:44 07/22/2110:44 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/2120:55 07/21/2120:55 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/2121:33 07/21/2121:33 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:21 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2119:14 07/22/2119:14 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2121:44 08/02/2121:44 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3S L1380832-03 GW Laura Elliott 07/20/2110:25 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/21 07:26 07/25/21 07:26 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:44 07/22/2110:44 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/21 21:44 07/21/21 21:44 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/21 21:51 07/21/21 21:51 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:24 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2119:33 07/22/2119:33 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2122:59 08/02/2122:59 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3D L1380832-04 GW Laura Elliott 07/20/2110:40 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/2107:34 07/25/2107:34 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:45 07/22/2110:45 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/2122:17 07/21/2122:17 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/2122:05 07/21/2122:05 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:27 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2119:52 07/22/2119:52 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2123:18 08/02/2123:18 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time DUPLICATE L1380832-05 GW Laura Elliott 07/20/2109:25 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:35 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2120:11 07/22/2120:11 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2123:37 08/02/2123:37 ACG Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 3 of 51 FP1 FTC 4 Cn FSr rqC F, FAI FSC MW-4 L1380832-06 GW Method Wet Chemistry by Method 2320 B-2011 Wet Chemistry by Method 4500S2 D-2011 Wet Chemistry by Method 9056A Wet Chemistry by Method 9060A Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D MW-6 L1380832-07 GW SAMPLE SUMMARY Collected by Laura Elliott Batch WG1711035 WG1709392 WG1709100 WG1709178 WG1712545 WG1710319 WG1716050 Collected date/time Received date/time 07/20/2111:55 07/21/2108:30 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/25/2107:37 07/25/2107:37 ARD Mt. Juliet, TN 1 07/22/2110:45 07/22/2110:45 SAC Mt. Juliet, TN 1 07/21/2122:50 07/21/2122:50 MCG Mt. Juliet, TN 1 07/21/2122:19 07/21/2122:19 MJA Mt. Juliet, TN 1 07/28/2121:23 07/30/2101:37 CCE Mt. Juliet, TN 1 07/22/2120:29 07/22/2120:29 ACG Mt. Juliet, TN 1 08/02/2123:56 08/02/2123:56 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2109:20 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/2107:41 07/25/2107:41 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:45 07/22/2110:45 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/2123:06 07/21/2123:06 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/2122:34 07/21/2122:34 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:40 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2120:48 07/22/2120:48 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/03/2100:15 08/03/2100:15 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time SW-1 L1380832-08 GW Laura Elliott 07/20/2112:10 07/21/2108:30 Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D SW-2 L1380832-09 GW Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D SW-3 L1380832-10 GW Batch WG1712545 WG1710319 WG1716050 Batch WG1712545 WG1710319 WG1716050 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/28/2121:23 07/30/2101:43 CCE Mt. Juliet, TN 1 07/22/21 21:07 07/22/21 21:07 ACG Mt. Juliet, TN 1 08/03/2100:34 08/03/2100:34 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2112:00 07/21/2108:30 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/28/2121:23 07/30/2101:45 CCE Mt. Juliet, TN 1 07/22/2121:26 07/22/2121:26 ACG Mt. Juliet, TN 1 08/03/2100:52 08/03/2100:52 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2112:05 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:48 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2121:45 07/22/2121:45 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/03/2101:11 08/03/2101:11 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time TRIP BLANK L1380832-11 GW Laura Elliott 07/20/2100:00 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2118:17 07/22/2118:17 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2120:48 08/02/2120:48 ACG Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 4 of 51 FP1 FTC M rCn] FSr RC F, FAI FSC TRIP BLANK L1380832-12 GW Method Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D SAMPLE SUMMARY Collected by Laura Elliott Collected date/time Received date/time 07/20/2100:00 07/21/2108:30 Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1710319 1 07/22/2118:36 07/22/2118:36 ACG Mt. Juliet, TN WG1716050 1 08/02/2121:07 08/02/2121:07 ACG Mt. Juliet, TN FP1 FTC M rCn] Fr RC F, FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1380832 08/03/21 15:48 5 of 51 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Heather J Wagner Project Manager FP FC FSS Fr RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 6 of 51 MW-5 Collected date/time: 07/20/21 10:20 SAMPLE RESULTS - 01 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 11.8 4.30 10.0 1 07/30/202101:19 WG1712545 Arsenic U 4.40 10.0 1 07/30/202101:19 WG1712545 Barium 268 0.736 5.00 1 07/30/202101:19 WG1712545 Beryllium 2.93 0.330 2.00 1 07/30/202101:19 WG1712545 Cadmium 1.05 J 0.479 2.00 1 07/30/202101:19 WG1712545 Chromium 11.3 1.40 10.0 1 07/30/202101:19 WG1712545 Cobalt 33.9 0.840 10.0 1 07/30/202101:19 WG1712545 Copper 35.9 3.68 10.0 1 07/30/202101:19 WG1712545 Lead 99.5 2.99 6.00 1 07/30/202101:19 WG1712545 Nickel 6.56 J 1.61 10.0 1 07/30/202101:19 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:19 WG1712545 Silver U 1.54 5.00 1 07/30/202101:19 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:19 WG1712545 Vanadium 110 4.99 20.0 1 07/30/202101:19 WG1712545 Zinc 327 6.52 50.0 1 07/30/202101:19 WG1712545 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time U 11.3 50.0 1 07/22/202118:55 U C3 2.54 50.0 1 07/22/202118:55 U 0.671 10.0 1 07/22/202118:55 U 0.0941 1.00 1 07/22/202118:55 U 0.118 1.00 1 07/22/202118:55 U 0.136 1.00 1 08/02/202121:26 U 0.129 1.00 1 07/22/202118:55 U 0.605 5.00 1 07/22/202118:55 U 0.157 1.00 1 07/22/202118:55 U 0.125 1.00 1 07/22/202118:55 U 0.127 1.00 1 07/22/202118:55 U 0.128 1.00 1 07/22/202118:55 U 0.116 1.00 1 07/22/202118:55 U 0.140 1.00 1 07/22/202118:55 U 0.192 5.00 1 07/22/202118:55 U 0.111 5.00 1 07/22/202118:55 U 0.960 2.50 1 07/22/202118:55 U 0.106 1.00 1 07/22/202118:55 U 0.114 1.00 1 07/22/202118:55 U 0.276 5.00 1 07/22/202118:55 U 0.126 1.00 1 07/22/202118:55 U 0.122 1.00 1 07/22/202118:55 U 0.107 1.00 1 07/22/202118:55 U 0.110 1.00 1 07/22/202118:55 U 0.120 1.00 1 07/22/202118:55 U 0.374 5.00 1 07/22/202118:55 U 0.100 1.00 1 07/22/202118:55 U 0.0819 1.00 1 07/22/202118:55 U C3 0.188 1.00 1 07/22/202118:55 U 0.126 1.00 1 07/22/202118:55 U 0.149 1.00 1 07/22/202118:55 U 0.149 1.00 1 07/22/202118:55 U 0.142 1.00 1 07/22/202118:55 U 0.110 1.00 1 07/22/202118:55 U 0.111 1.00 1 07/22/202118:55 U 0.118 1.00 1 07/22/202118:55 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 7 of 51 MW-5 SAMPLE RESULTS - 01 Collected date/time: 07/20/21 10:20 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene 0.139 J 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U C3 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 109 80.0-120 (S) Toluene-d8 93.4 80.0-120 (S) 4-Bromof/uorobenzene 95.3 77.0-126 (S) 4-Bromof/uorobenzene 107 77.0-126 (S)1,2-Dich/oroethane-d4 106 70.0-130 (S)1,2-Dlch/oroethane-d4 125 70.0-130 Dilution Analysis date / time Batch 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 07/22/202118:55 WG1710319 08/02/202121.26 WG1716050 07/22/202118:55 WG1710319 08/02/202121.26 WG1716050 07/22/202118:55 WG1710319 08/02/202121.26 WG1716050 FP1 FTc FSS 4 Cn RC F FAI FSC ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 8 of 51 MW-2R SAMPLE RESULTS - 02 Collected date/time: 07/20/21 11:23 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 141000 8450 Sample Narrative: L1380832-02 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:19 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:44 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 10500 379 1000 1 07/21/202120:55 WG1709100 Nitrate U 48.0 100 1 07/21/202120:55 WG1709100 Sulfate 986 J 594 5000 1 07/21/202120:55 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 1170 B 102 Metals (ICP) by Method 6010D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I 1000 RDL Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 253 0.736 5.00 Beryllium 0.333 J 0.330 2.00 Cadmium 0.504 J 0.479 2.00 Chromium 2.15 J 1.40 10.0 Cobalt 3.95 J 0.840 10.0 Copper U 3.68 10.0 Lead 3.25 J 2.99 6.00 Nickel U 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 6.89 J 4.99 20.0 Zinc 7.27 J 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene 3.07 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 C3 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.39 Dilution Analysis Batch date / time 1 07/21/202121:33 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 Dilution Analysis date / time Batch 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 08/02/202121:44 WG1716050 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 9 of 51 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC MW-2R SAMPLE RESULTS - 02 Collected date/time: 07/20/21 11:23 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I sec -Butyl benzene U 0.125 1.00 tert-Butylbenzene U 0.127 1.00 Carbon tetrachloride U 0.128 1.00 Chlorobenzene 0.155 J 0.116 1.00 Chlorodibromomethane U 0.140 1.00 Chloroethane U 0.192 5.00 Chloroform U 0.111 5.00 Chloromethane U 0.960 2.50 2-Chlorotoluene U 0.106 1.00 4-Chlorotoluene U 0.114 1.00 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1,2-Dibromoethane U 0.126 1.00 Dibromomethane U 0.122 1.00 1,2-Dichlorobenzene 0.215 J 0.107 1.00 1,3-Dichlorobenzene U 0.110 1.00 1,4-Dichlorobenzene 4.81 0.120 1.00 Dichlorodifluoromethane U 0.374 5.00 1,1-Dichloroethane 9.24 0.100 1.00 1,2-Dichloroethane 0.520 J 0.0819 1.00 1,1-Dichloroethene U C3 0.188 1.00 cis-1,2-Dichloroethene 26.2 0.126 1.00 trans-1,2-Dichloroethene 0.850 J 0.149 1.00 1,2-Dichloropropane 3.64 0.149 1.00 1,1-Dichloropropene U 0.142 1.00 1,3-Dichloropropane U 0.110 1.00 cis-1,3-Dichloropropene U 0.111 1.00 trans-1,3-Dichloropropene U 0.118 1.00 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether 0.241 J_ 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene 0.421 J 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether 0.313 J_ 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene 0.700 J 0.190 1.00 Trichlorofluoromethane 0.160 C3 J 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride 4.02 C3 0.234 1.00 Dilution Analysis Batch date / time 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 10 of 51 MW-2R SAMPLE RESULTS - 02 Collected date/time: 07/20/21 11:23 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/22/202119:14 WG1710319 (S) Toluene-d8 108 80.0-120 07/22/202119:14 WG1710319 (S) Toluene-d8 94.9 80.0-120 08/02/202121.44 WG1716050 (S) 4-Bromofluorobenzene 101 77.0-126 07/22/202119:14 WG1710319 (S) 4-Bromofluorobenzene 102 77.0-126 08/02/202121.44 WG1716050 (S)1,2-Dich/oroethone-d4 104 70.0-130 07/22/202119:14 WG1710319 (S) 1,2-Dich/oroethone-d4 111 70.0-130 08/02/202121.44 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 11 of 51 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/20/21 10:25 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 167000 8450 Sample Narrative: L1380832-03 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:26 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:44 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 36500 379 1000 1 07/21/202121:44 WG1709100 Nitrate U 48.0 100 1 07/21/202121:44 WG1709100 Sulfate 938 J 594 5000 1 07/21/202121:44 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 3020 B 102 1000 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Antimony 4.40 J 4.30 10.0 Arsenic U 4.40 10.0 Barium 236 0.736 5.00 Beryllium 0.880 J 0.330 2.00 Cadmium 7.95 0.479 2.00 Chromium 15.6 1.40 10.0 Cobalt 15.5 0.840 10.0 Copper 44.7 3.68 10.0 Lead 12.5 2.99 6.00 Nickel 8.10 J 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium 4.57 B J 4.31 10.0 Vanadium 76.8 4.99 20.0 Zinc 619 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone 34.9 J 11.3 50.0 Acrolein U C3 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.284 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 07/21/202121:51 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC Dilution Analysis date / time Batch 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 08/02/202122:59 WG1716050 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 12 of 51 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/20/21 10:25 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202119:33 WG1710319 tert-Butylbenzene U 0.127 1.00 1 07/22/202119:33 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202119:33 WG1710319 Chlorobenzene 1.55 0.116 1.00 1 07/22/202119:33 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202119:33 WG1710319 Chloroethane 0.410 1_ 0.192 5.00 1 07/22/202119:33 WG1710319 Chloroform U 0.111 5.00 1 07/22/202119:33 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202119:33 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202119:33 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202119:33 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202119:33 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202119:33 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202119:33 WG1710319 1,2-Dichlorobenzene 0.116 J 0.107 1.00 1 07/22/202119:33 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202119:33 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202119:33 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202119:33 WG1710319 1,1-Dichloroethane 0.451 J 0.100 1.00 1 07/22/202119:33 WG1710319 1,2-Dichloroethane 0.272 J 0.0819 1.00 1 07/22/202119:33 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202119:33 WG1710319 cis-1,2-Dichloroethene 0.984 J 0.126 1.00 1 07/22/202119:33 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202119:33 WG1710319 1,2-Dichloropropane 0.394 J 0.149 1.00 1 07/22/202119:33 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202119:33 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202119:33 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202119:33 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202119:33 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202119:33 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202119:33 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202119:33 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202119:33 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202119:33 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202119:33 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202119:33 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202119:33 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202119:33 WG1710319 Methyl tert-butyl ether 0.187 J_ 0.101 1.00 1 07/22/202119:33 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202119:33 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202119:33 WG1710319 Styrene U 0.118 1.00 1 07/22/202119:33 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202119:33 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202119:33 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202119:33 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202119:33 WG1710319 Toluene U 0.278 1.00 1 07/22/202119:33 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202119:33 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202119:33 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202119:33 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202119:33 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202119:33 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202119:33 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202119:33 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202119:33 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202119:33 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202119:33 WG1710319 Vinyl chloride 1.13 C3 0.234 1.00 1 07/22/202119:33 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 13 of 51 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/20/21 10:25 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I Dilution Analysis date / time Xylenes, Total U 0.174 3.00 1 07/22/202119:33 (S) Toluene-d8 107 80.0-120 07/22/202119:33 (S) Toluene-d8 94.9 80.0-120 08702/202122.59 (S) 4-Bromofluorobenzene 98.3 77.0-126 07/22/202119:33 (S) 4-Bromofluorobenzene 102 77.0-126 08702/202122.59 (S)1,2-Dich/oroethone-d4 107 70.0-130 07/22/202119:33 (S)1,2-Dich/oroethane-d4 111 70.0-130 08702/202122.59 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 Batch WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC DATE/TIME: PAGE: 08/03/2115:48 14 of 51 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/20/21 10:40 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 178000 8450 Sample Narrative: L1380832-04 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:34 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:45 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 27000 379 1000 1 07/21/202122:17 WG1709100 Nitrate U 48.0 100 1 07/21/202122:17 WG1709100 Sulfate 858 J 594 5000 1 07/21/202122:17 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 1460 B 102 1000 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 38.0 0.736 5.00 Beryllium U 0.330 2.00 Cadmium U 0.479 2.00 Chromium U 1.40 10.0 Cobalt U 0.840 10.0 Copper U 3.68 10.0 Lead 3.43 J 2.99 6.00 Nickel U 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 6.52 J 4.99 20.0 Zinc U 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein U C3 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.451 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 07/21/202122:05 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 Dilution Analysis Batch date / time 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 08/02/202123:18 WG1716050 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 15 of 51 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/20/21 10:40 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202119:52 WG1710319 tert-Butylbenzene U 0.127 1.00 1 07/22/202119:52 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202119:52 WG1710319 Chlorobenzene 0.583 J 0.116 1.00 1 07/22/202119:52 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202119:52 WG1710319 Chloroethane 0.362 1_ 0.192 5.00 1 07/22/202119:52 WG1710319 Chloroform U 0.111 5.00 1 07/22/202119:52 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202119:52 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202119:52 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202119:52 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202119:52 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202119:52 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202119:52 WG1710319 1,2-Dichlorobenzene 0.174 J 0.107 1.00 1 07/22/202119:52 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202119:52 WG1710319 1,4-Dichlorobenzene 5.00 0.120 1.00 1 07/22/202119:52 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202119:52 WG1710319 1,1-Dichloroethane 1.26 0.100 1.00 1 07/22/202119:52 WG1710319 1,2-Dichloroethane 0.571 J 0.0819 1.00 1 07/22/202119:52 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202119:52 WG1710319 cis-1,2-Dichloroethene 8.81 0.126 1.00 1 07/22/202119:52 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202119:52 WG1710319 1,2-Dichloropropane 0.977 J_ 0.149 1.00 1 07/22/202119:52 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202119:52 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202119:52 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202119:52 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202119:52 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202119:52 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202119:52 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202119:52 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202119:52 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202119:52 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202119:52 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202119:52 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202119:52 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202119:52 WG1710319 Methyl tert-butyl ether 0.360 J_ 0.101 1.00 1 07/22/202119:52 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202119:52 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202119:52 WG1710319 Styrene U 0.118 1.00 1 07/22/202119:52 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202119:52 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202119:52 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202119:52 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202119:52 WG1710319 Toluene U 0.278 1.00 1 07/22/202119:52 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202119:52 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202119:52 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202119:52 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202119:52 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202119:52 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202119:52 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202119:52 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202119:52 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202119:52 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202119:52 WG1710319 Vinyl chloride 5.74 C3 0.234 1.00 1 07/22/202119:52 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 16 of 51 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/20/21 10:40 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I Dilution Analysis date / time Xylenes, Total 0.390 J_ 0.174 3.00 1 07/22/202119:52 (S) Toluene-d8 107 80.0-120 07/22/202119:52 (S) Toluene-d8 95.9 80.0-120 08702/202123:18 (S) 4-Bromofluorobenzene 98.5 77.0-126 07/22/202119:52 (S) 4-Bromofluorobenzene 102 77.0-126 08702/202123:18 (S)1,2-Dich/oroethone-d4 107 70.0-130 07/22/202119:52 (S)1,2-Dich/oroethane-d4 108 70.0-130 08702/202123:18 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 Batch WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC DATE/TIME: PAGE: 08/03/21 15:48 17 of 51 DUPLICATE Collected date/time: 07/20/21 09:25 SAMPLE RESULTS - 05 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 5.65 J 4.30 10.0 1 07/30/202101:35 WG1712545 Arsenic U 4.40 10.0 1 07/30/202101:35 WG1712545 Barium 49.2 0.736 5.00 1 07/30/202101:35 WG1712545 Beryllium U 0.330 2.00 1 07/30/202101:35 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:35 WG1712545 Chromium U 1.40 10.0 1 07/30/202101:35 WG1712545 Cobalt U 0.840 10.0 1 07/30/202101:35 WG1712545 Copper U 3.68 10.0 1 07/30/202101:35 WG1712545 Lead U 2.99 6.00 1 07/30/202101:35 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:35 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:35 WG1712545 Silver U 1.54 5.00 1 07/30/202101:35 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:35 WG1712545 Vanadium 7.49 J 4.99 20.0 1 07/30/202101:35 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:35 WG1712545 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time U 11.3 50.0 1 07/22/202120:11 U C3 2.54 50.0 1 07/22/202120:11 U 0.671 10.0 1 07/22/202120:11 0.472 J 0.0941 1.00 1 07/22/202120:11 U 0.118 1.00 1 07/22/202120:11 U 0.136 1.00 1 08/02/202123:37 U 0.129 1.00 1 07/22/202120:11 U 0.605 5.00 1 07/22/202120:11 U 0.157 1.00 1 07/22/202120:11 U 0.125 1.00 1 07/22/202120:11 U 0.127 1.00 1 07/22/202120:11 U 0.128 1.00 1 07/22/202120:11 0.566 J 0.116 1.00 1 07/22/202120:11 U 0.140 1.00 1 07/22/202120:11 0.334 J 0.192 5.00 1 07/22/202120:11 U 0.111 5.00 1 07/22/202120:11 U 0.960 2.50 1 07/22/202120:11 U 0.106 1.00 1 07/22/202120:11 U 0.114 1.00 1 07/22/202120:11 U 0.276 5.00 1 07/22/202120:11 U 0.126 1.00 1 07/22/202120:11 U 0.122 1.00 1 07/22/202120:11 0.168 J 0.107 1.00 1 07/22/202120:11 U 0.110 1.00 1 07/22/202120:11 4.87 0.120 1.00 1 07/22/202120:11 U 0.374 5.00 1 07/22/202120:11 1.19 0.100 1.00 1 07/22/202120:11 0.530 J 0.0819 1.00 1 07/22/202120:11 U C3 0.188 1.00 1 07/22/202120:11 7.58 0.126 1.00 1 07/22/202120:11 U 0.149 1.00 1 07/22/202120:11 0.959 J 0.149 1.00 1 07/22/202120:11 U 0.142 1.00 1 07/22/202120:11 U 0.110 1.00 1 07/22/202120:11 U 0.111 1.00 1 07/22/202120:11 U 0.118 1.00 1 07/22/202120:11 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 18 of 51 DUPLICATE SAMPLE RESULTS - 05 Collected date/time: 07/20/21 09:25 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether 0.303 J_ 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride 5.73 C3 0.234 1.00 Xylenes, Total 0.936 J 0.174 3.00 (S) Toluene-d8 113 80.0-120 (S) Toluene-d8 95.1 80.0-120 (S) 4-Bromof/uorobenzene 92.1 77.0-126 (S) 4-Bromof/uorobenzene 104 77.0-126 (S) 1,2-Dich/oroethane-d4 104 70.0-130 (S)1,2-Dlch/oroethane-d4 113 70.0-130 Dilution Analysis date / time 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 08/02/202123:37 07/22/202120:11 08/02/202123:37 07/22/202120:11 08/02/202123:37 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC I q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 19 of 51 ------------ MW-4 SAMPLE RESULTS - 06 Collected date/time: 07/20/21 11:55 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 189000 8450 Sample Narrative: L1380832-06 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:37 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:45 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 24000 379 1000 1 07/21/202122:50 WG1709100 Nitrate U 48.0 100 1 07/21/202122:50 WG1709100 Sulfate 662 J 594 5000 1 07/21/202122:50 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 1250 B 102 Metals (ICP) by Method 6010D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I 1000 RDL Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 127 0.736 5.00 Beryllium U 0.330 2.00 Cadmium 0.580 J 0.479 2.00 Chromium 12.1 1.40 10.0 Cobalt 3.50 J 0.840 10.0 Copper 6.32 J 3.68 10.0 Lead 5.96 J 2.99 6.00 Nickel 3.84 J 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 17.2 J 4.99 20.0 Zinc 20.1 J 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene 0.384 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 C3 2.54 50.0 0.671 10.0 J 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.39 Dilution Analysis Batch date / time 1 07/21/202122:19 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 Dilution Analysis Batch date / time 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 08/02/202123:56 WG1716050 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 20 of 51 MW-4 SAMPLE RESULTS - 06 Collected date/time: 07/20/21 11:55 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202120:29 WG1710319 tert-Butylbenzene U 0.127 1.00 1 07/22/202120:29 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202120:29 WG1710319 Chlorobenzene 0.163 J 0.116 1.00 1 07/22/202120:29 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202120:29 WG1710319 Chloroethane 0.606 1_ 0.192 5.00 1 07/22/202120:29 WG1710319 Chloroform U 0.111 5.00 1 07/22/202120:29 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202120:29 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202120:29 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202120:29 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202120:29 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202120:29 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202120:29 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202120:29 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202120:29 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202120:29 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202120:29 WG1710319 1,1-Dichloroethane 1.15 0.100 1.00 1 07/22/202120:29 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202120:29 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202120:29 WG1710319 cis-1,2-Dichloroethene 14.4 0.126 1.00 1 07/22/202120:29 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202120:29 WG1710319 1,2-Dichloropropane 0.286 J_ 0.149 1.00 1 07/22/202120:29 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202120:29 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202120:29 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202120:29 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202120:29 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202120:29 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202120:29 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202120:29 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202120:29 WG1710319 Isopropylbenzene 0.118 J 0.105 1.00 1 07/22/202120:29 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202120:29 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202120:29 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202120:29 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202120:29 WG1710319 Methyl tert-butyl ether 0.243 J_ 0.101 1.00 1 07/22/202120:29 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202120:29 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202120:29 WG1710319 Styrene U 0.118 1.00 1 07/22/202120:29 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202120:29 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202120:29 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202120:29 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202120:29 WG1710319 Toluene U 0.278 1.00 1 07/22/202120:29 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202120:29 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202120:29 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202120:29 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202120:29 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202120:29 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202120:29 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202120:29 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202120:29 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202120:29 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202120:29 WG1710319 Vinyl chloride 9.62 C3 0.234 1.00 1 07/22/202120:29 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 21 of 51 MW-4 SAMPLE RESULTS - 06 Collected date/time: 07/20/21 11:55 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/22/202120:29 WG1710319 (S) Toluene-d8 108 80.0-120 07/22/202120:29 WG1710319 (S) Toluene-d8 94.3 80.0-120 08/02/202123:56 WG1716050 (S) 4-Bromofluorobenzene 99.4 77.0-126 07/22/202120.29 WG1710319 (S) 4-Bromofluorobenzene 100 77.0-126 08/02/202123:56 WG1716050 (S) 1,2-Dich/oroethone-d4 107 70.0-130 07/22/202120.29 WG1710319 (S) 1,2-Dich/oroethone-d4 109 70.0-130 08/02/202123:56 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 22 of 51 ------------ MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/20/21 09:20 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 9960 J 8450 Sample Narrative: L1380832-07 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:41 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:45 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 1550 379 1000 1 07/21/202123:06 WG1709100 Nitrate U 48.0 100 1 07/21/202123:06 WG1709100 Sulfate 5130 594 5000 1 07/21/202123:06 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 2280 B 102 Metals (ICP) by Method 6010D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I 1000 RDL Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 50.3 0.736 5.00 Beryllium U 0.330 2.00 Cadmium U 0.479 2.00 Chromium 1.99 J 1.40 10.0 Cobalt 1.12 J 0.840 10.0 Copper U 3.68 10.0 Lead 5.68 J 2.99 6.00 Nickel U 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 6.69 J 4.99 20.0 Zinc 7.56 J 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 C3 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.39 Dilution Analysis Batch date / time 1 07/21/202122:34 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 Dilution Analysis Batch date / time 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 08/03/202100:15 WG1716050 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 23 of 51 MW-6 SAMPLE Collected date/time: 07/20/21 09:20 Volatile Organic Compounds (GC/MS) by Method 8260D RESULTS - 07 L1380832 Result Qualifier MDL RDL Dilution Analysis Batch FP1 Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202120:48 WG1710319 FTc tert-Butylbenzene U 0.127 1.00 1 07/22/202120:48 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202120:48 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202120:48 WG1710319 FSS Chlorodibromomethane U 0.140 1.00 1 07/22/202120:48 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202120:48 WG1710319 4 Cn Chloroform U 0.111 5.00 1 07/22/202120:48 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202120:48 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202120:48 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202120:48 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202120:48 WG1710319 RC 1,2-Dibromoethane U 0.126 1.00 1 07/22/202120:48 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202120:48 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202120:48 WG1710319 GI 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202120:48 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202120:48 WG1710319 FAI Dichlorodifluoromethane U 0.374 5.00 1 07/22/202120:48 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202120:48 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202120:48 WG1710319 FSC 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202120:48 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202120:48 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202120:48 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202120:48 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202120:48 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202120:48 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202120:48 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202120:48 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202120:48 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202120:48 WG1710319 Ethylbenzene 1.02 0.137 1.00 1 07/22/202120:48 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202120:48 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202120:48 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202120:48 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202120:48 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202120:48 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202120:48 WG1710319 Methyl tert-butyl ether U 0.101 1.00 1 07/22/202120:48 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202120:48 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202120:48 WG1710319 Styrene U 0.118 1.00 1 07/22/202120:48 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202120:48 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202120:48 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202120:48 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202120:48 WG1710319 Toluene 7.10 0.278 1.00 1 07/22/202120:48 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202120:48 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202120:48 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202120:48 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202120:48 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202120:48 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202120:48 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202120:48 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202120:48 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202120:48 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202120:48 WG1710319 Vinyl chloride U C3 0.234 1.00 1 07/22/202120:48 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 24 of 51 MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/20/21 09:20 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/22/202120:48 WG1710319 (S) Toluene-d8 107 80.0-120 07/22/202120.48 WG1710319 (S) Toluene-d8 94.5 80.0-120 08703/202100.15 WG1716050 (S) 4-Bromofluorobenzene 99.4 77.0-126 07/22/202120.48 WG1710319 (S) 4-Bromofluorobenzene 101 77.0-126 08703/202100.15 WG1716050 (S) 1,2-Dich/oroethone-d4 107 70.0-130 07/22/202120.48 WG1710319 (S)1,2-Dich/oroethone-d4 115 70.0-130 08703/202100.15 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 25 of 51 SW-1 SAMPLE RESULTS - 08 Collected date/time: 07/20/21 12:10 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Cp Analyte ug/I ug/I ug/I date / time Antimony 4.31 J 4.30 10.0 1 07/30/202101:43 WG1712545 F Arsenic U 4.40 10.0 1 07/30/202101:43 WG1712545 Barium 36.6 0.736 5.00 1 07/30/202101:43 WG1712545 3 SS Beryllium U 0.330 2.00 1 07/30/202101:43 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:43 WG1712545 Chromium 1.71 J 1.40 10.0 1 07/30/202101:43 WG1712545 4 Cfl Cobalt U 0.840 10.0 1 07/30/202101:43 WG1712545 Copper U 3.68 10.0 1 07/30/202101:43 WG1712545 Lead 3.02 J 2.99 6.00 1 07/30/202101:43 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:43 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:43 WG1712545 6 QC Silver U 1.54 5.00 1 07/30/202101:43 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:43 WG1712545 7G1 Vanadium U 4.99 20.0 1 07/30/202101:43 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:43 WG1712545 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/22/202121:07 WG1710319 Acrolein U C3 2.54 50.0 1 07/22/202121:07 WG1710319 Acrylonitrile U 0.671 10.0 1 07/22/202121:07 WG1710319 Benzene U 0.0941 1.00 1 07/22/202121:07 WG1710319 Bromobenzene U 0.118 1.00 1 07/22/202121:07 WG1710319 Bromodichloromethane U 0.136 1.00 1 08/03/202100:34 WG1716050 Bromoform U 0.129 1.00 1 07/22/202121:07 WG1710319 Bromomethane U 0.605 5.00 1 07/22/202121:07 WG1710319 n-Butylbenzene U 0.157 1.00 1 07/22/202121:07 WG1710319 sec -Butyl benzene U 0.125 1.00 1 07/22/202121:07 WG1710319 ter[-Butylbenzene U 0.127 1.00 1 07/22/202121:07 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202121:07 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202121:07 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202121:07 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202121:07 WG1710319 Chloroform U 0.111 5.00 1 07/22/202121:07 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202121:07 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202121:07 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202121:07 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202121:07 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202121:07 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202121:07 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202121:07 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202121:07 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202121:07 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202121:07 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202121:07 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202121:07 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202121:07 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202121:07 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202121:07 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202121:07 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202121:07 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202121:07 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202121:07 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202121:07 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 26 of 51 SW-1 SAMPLE RESULTS - 08 Collected date/time: 07/20/21 12:10 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U C3 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 114 80.0-120 (S) Toluene-d8 95.5 80.0-120 (S) 4-Bromof/uorobenzene 92.4 77.0-126 (S) 4-Bromof/uorobenzene 103 77.0-126 (S) 1,2-Dich/oroethane-d4 101 70.0-130 (S)1,2-Dlch/oroethane-d4 122 70.0-130 Dilution Analysis Batch date / time 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 07/22/202121:07 WG1710319 08103120210034 WG1716050 07/22/202121:07 WG1710319 08103120210034 WG1716050 07/22/202121:07 WG1710319 08103120210034 WG1716050 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 27 of 51 SW-2 SAMPLE RESULTS - 09 Collected date/time: 07/20/21 12:00 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Cp Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/30/202101:45 WG1712545 F Arsenic U 4.40 10.0 1 07/30/202101:45 WG1712545 Barium 41.1 0.736 5.00 1 07/30/202101:45 WG1712545 3 SS Beryllium U 0.330 2.00 1 07/30/202101:45 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:45 WG1712545 Chromium 1.69 J 1.40 10.0 1 07/30/202101:45 WG1712545 4 Cfl Cobalt 1.44 J 0.840 10.0 1 07/30/202101:45 WG1712545 Copper U 3.68 10.0 1 07/30/202101:45 WG1712545 Lead U 2.99 6.00 1 07/30/202101:45 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:45 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:45 WG1712545 6 QC Silver U 1.54 5.00 1 07/30/202101:45 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:45 WG1712545 7G1 Vanadium U 4.99 20.0 1 07/30/202101:45 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:45 WG1712545 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/22/202121:26 WG1710319 Acrolein U C3 2.54 50.0 1 07/22/202121:26 WG1710319 Acrylonitrile U 0.671 10.0 1 07/22/202121:26 WG1710319 Benzene U 0.0941 1.00 1 07/22/202121:26 WG1710319 Bromobenzene U 0.118 1.00 1 07/22/202121:26 WG1710319 Bromodichloromethane U 0.136 1.00 1 08/03/202100:52 WG1716050 Bromoform U 0.129 1.00 1 07/22/202121:26 WG1710319 Bromomethane U 0.605 5.00 1 07/22/202121:26 WG1710319 n-Butylbenzene U 0.157 1.00 1 07/22/202121:26 WG1710319 sec -Butyl benzene U 0.125 1.00 1 07/22/202121:26 WG1710319 ter[-Butylbenzene U 0.127 1.00 1 07/22/202121:26 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202121:26 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202121:26 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202121:26 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202121:26 WG1710319 Chloroform U 0.111 5.00 1 07/22/202121:26 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202121:26 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202121:26 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202121:26 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202121:26 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202121:26 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202121:26 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202121:26 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202121:26 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202121:26 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202121:26 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202121:26 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202121:26 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202121:26 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202121:26 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202121:26 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202121:26 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202121:26 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202121:26 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202121:26 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202121:26 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 28 of 51 SW-2 SAMPLE RESULTS - 09 Collected date/time: 07/20/21 12:00 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 2,2-Dichloropropane U 0.161 1.00 1 07/22/202121:26 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202121:26 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202121:26 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202121:26 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202121:26 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202121:26 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202121:26 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202121:26 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202121:26 WG1710319 Methyl tert-butyl ether U 0.101 1.00 1 07/22/202121:26 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202121:26 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202121:26 WG1710319 Styrene U 0.118 1.00 1 07/22/202121:26 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202121:26 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202121:26 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202121:26 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202121:26 WG1710319 Toluene U 0.278 1.00 1 07/22/202121:26 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202121:26 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202121:26 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202121:26 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202121:26 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202121:26 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202121:26 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202121:26 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202121:26 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202121:26 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202121:26 WG1710319 Vinyl chloride U C3 0.234 1.00 1 07/22/202121:26 WG1710319 Xylenes, Total U 0.174 3.00 1 07/22/202121:26 WG1710319 (S) Toluene-d8 109 80.0-120 07/22/202121:26 WG1710319 (S) Toluene-d8 93.9 80.0-120 08/03/202100.52 WG1716050 (S) 4-Bromof/uorobenzene 96.4 77.0-126 07/22/202121:26 WG1710319 (S) 4-Bromof/uorobenzene 102 77.0-126 08/03/202100.52 WG1716050 (S 1,2-Dich/oroethane-d4 104 70.0-130 07/22/202121:26 WG1710319 (S)1,2-Dlch/oroethone-d4 125 70.0-130 08/03/202100.52 WG1716050 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 29 of 51 SW-3 SAMPLE RESULTS - 10 Collected date/time: 07/20/21 12:05 L1380832 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/30/202101:48 WG1712545 F Arsenic U 4.40 10.0 1 07/30/202101:48 WG1712545 Barium 38.4 0.736 5.00 1 07/30/202101:48 WG1712545 3 SS Beryllium U 0.330 2.00 1 07/30/202101:48 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:48 WG1712545 Chromium U 1.40 10.0 1 07/30/202101:48 WG1712545 4 Cfl Cobalt 0.866 J 0.840 10.0 1 07/30/202101:48 WG1712545 Copper U 3.68 10.0 1 07/30/202101:48 WG1712545 Lead U 2.99 6.00 1 07/30/202101:48 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:48 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:48 WG1712545 6 QC Silver U 1.54 5.00 1 07/30/202101:48 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:48 WG1712545 7G1 Vanadium 6.86 J 4.99 20.0 1 07/30/202101:48 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:48 WG1712545 Al r Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/22/202121:45 WG1710319 Acrolein U C3 2.54 50.0 1 07/22/202121:45 WG1710319 Acrylonitrile U 0.671 10.0 1 07/22/202121:45 WG1710319 Benzene U 0.0941 1.00 1 07/22/202121:45 WG1710319 Bromobenzene U 0.118 1.00 1 07/22/202121:45 WG1710319 Bromodichloromethane U 0.136 1.00 1 08/03/202101:11 WG1716050 Bromoform U 0.129 1.00 1 07/22/202121:45 WG1710319 Bromomethane U 0.605 5.00 1 07/22/202121:45 WG1710319 n-Butylbenzene U 0.157 1.00 1 07/22/202121:45 WG1710319 sec -Butyl benzene U 0.125 1.00 1 07/22/202121:45 WG1710319 ter[-Butylbenzene U 0.127 1.00 1 07/22/202121:45 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202121:45 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202121:45 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202121:45 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202121:45 WG1710319 Chloroform U 0.111 5.00 1 07/22/202121:45 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202121:45 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202121:45 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202121:45 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202121:45 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202121:45 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202121:45 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202121:45 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202121:45 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202121:45 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202121:45 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202121:45 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202121:45 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202121:45 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202121:45 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202121:45 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202121:45 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202121:45 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202121:45 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202121:45 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202121:45 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 30 of 51 SW-3 SAMPLE RESULTS - 10 Collected date/time: 07/20/21 12:05 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U C3 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 109 80.0-120 (S) Toluene-d8 96.0 80.0-120 (S) 4-Bromof/uorobenzene 97.2 77.0-126 (S) 4-Bromof/uorobenzene 104 77.0-126 (S)1,2-Dich/oroethane-d4 105 70.0-130 (S) 1,2-Dlch/oroethane-d4 121 70.0-130 Dilution Analysis date / time 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121.45 081031202101:11 07/22/202121.45 081031202101:11 07/22/202121.45 081031202101:11 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC I q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 31 of 51 TRIP BLANK Collected date/time: 07/20/21 00:00 SAMPLE RESULTS - 11 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene Result ug/I U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 11.3 50.0 1 07/22/202118:17 WG1710319 C3 2.54 50.0 1 07/22/202118:17 WG1710319 0.671 10.0 1 07/22/202118:17 WG1710319 0.0941 1.00 1 07/22/202118:17 WG1710319 0.118 1.00 1 07/22/202118:17 WG1710319 0.136 1.00 1 08/02/202120:48 WG1716050 0.129 1.00 1 07/22/202118:17 WG1710319 0.605 5.00 1 07/22/202118:17 WG1710319 0.157 1.00 1 07/22/202118:17 WG1710319 0.125 1.00 1 07/22/202118:17 WG1710319 0.127 1.00 1 07/22/202118:17 WG1710319 0.128 1.00 1 07/22/202118:17 WG1710319 0.116 1.00 1 07/22/202118:17 WG1710319 0.140 1.00 1 07/22/202118:17 WG1710319 0.192 5.00 1 07/22/202118:17 WG1710319 0.111 5.00 1 07/22/202118:17 WG1710319 0.960 2.50 1 07/22/202118:17 WG1710319 0.106 1.00 1 07/22/202118:17 WG1710319 0.114 1.00 1 07/22/202118:17 WG1710319 0.276 5.00 1 07/22/202118:17 WG1710319 0.126 1.00 1 07/22/202118:17 WG1710319 0.122 1.00 1 07/22/202118:17 WG1710319 0.107 1.00 1 07/22/202118:17 WG1710319 0.110 1.00 1 07/22/202118:17 WG1710319 0.120 1.00 1 07/22/202118:17 WG1710319 0.374 5.00 1 07/22/202118:17 WG1710319 0.100 1.00 1 07/22/202118:17 WG1710319 0.0819 1.00 1 07/22/202118:17 WG1710319 C3 0.188 1.00 1 07/22/202118:17 WG1710319 0.126 1.00 1 07/22/202118:17 WG1710319 0.149 1.00 1 07/22/202118:17 WG1710319 0.149 1.00 1 07/22/202118:17 WG1710319 0.142 1.00 1 07/22/202118:17 WG1710319 0.110 1.00 1 07/22/202118:17 WG1710319 0.111 1.00 1 07/22/202118:17 WG1710319 0.118 1.00 1 07/22/202118:17 WG1710319 0.161 1.00 1 07/22/202118:17 WG1710319 0.105 1.00 1 07/22/202118:17 WG1710319 0.137 1.00 1 07/22/202118:17 WG1710319 0.337 1.00 1 07/22/202118:17 WG1710319 0.105 1.00 1 07/22/202118:17 WG1710319 0.120 1.00 1 07/22/202118:17 WG1710319 1.19 10.0 1 07/22/202118:17 WG1710319 0.430 5.00 1 07/22/202118:17 WG1710319 0.478 10.0 1 07/22/202118:17 WG1710319 0.101 1.00 1 07/22/202118:17 WG1710319 1.00 5.00 1 07/22/202118:17 WG1710319 0.0993 1.00 1 07/22/202118:17 WG1710319 0.118 1.00 1 07/22/202118:17 WG1710319 0.147 1.00 1 07/22/202118:17 WG1710319 0.133 1.00 1 07/22/202118:17 WG1710319 C3 0.180 1.00 1 07/22/202118:17 WG1710319 0.300 1.00 1 07/22/202118:17 WG1710319 0.278 1.00 1 07/22/202118:17 WG1710319 0.230 1.00 1 07/22/202118:17 WG1710319 0.481 1.00 1 07/22/202118:17 WG1710319 FP1 FTc FSS 4 Cn Rc F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 32 of 51 TRIP BLANK SAMPLE RESULTS - 11 Collected date/time: 07/20/21 00:00 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202118:17 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202118:17 Trichloroethene U 0.190 1.00 1 07/22/202118:17 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202118:17 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202118:17 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202118:17 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202118:17 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202118:17 Vinyl chloride U C3 0.234 1.00 1 07/22/202118:17 Xylenes, Total U 0.174 3.00 1 07/22/202118:17 (S Toluene-d8 110 80.0-120 071221202118:17 (S) Toluene-d8 96.3 80.0-120 08/02/202120.48 (S 4-Bromofluorobenzene 96.6 77.0-126 07/22/202118:17 (S) 4-Bromofluorobenzene 102 77.0-126 08/02/202120.48 (S)1,2-Dich/oroethone-d4 107 70.0-130 07/22/202118:17 (S)1,2-Dich/oroethone-d4 112 70.0-130 08/02/202120.48 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC F FAI FSC DATE/TIME: PAGE: 08/03/21 15:48 33 of 51 TRIP BLANK Collected date/time: 07/20/21 00:00 SAMPLE RESULTS - 12 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene Result ug/I U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 11.3 50.0 1 07/22/202118:36 WG1710319 C3 2.54 50.0 1 07/22/202118:36 WG1710319 0.671 10.0 1 07/22/202118:36 WG1710319 0.0941 1.00 1 07/22/202118:36 WG1710319 0.118 1.00 1 07/22/202118:36 WG1710319 0.136 1.00 1 08/02/202121:07 WG1716050 0.129 1.00 1 07/22/202118:36 WG1710319 0.605 5.00 1 07/22/202118:36 WG1710319 0.157 1.00 1 07/22/202118:36 WG1710319 0.125 1.00 1 07/22/202118:36 WG1710319 0.127 1.00 1 07/22/202118:36 WG1710319 0.128 1.00 1 07/22/202118:36 WG1710319 0.116 1.00 1 07/22/202118:36 WG1710319 0.140 1.00 1 07/22/202118:36 WG1710319 0.192 5.00 1 07/22/202118:36 WG1710319 0.111 5.00 1 07/22/202118:36 WG1710319 0.960 2.50 1 07/22/202118:36 WG1710319 0.106 1.00 1 07/22/202118:36 WG1710319 0.114 1.00 1 07/22/202118:36 WG1710319 0.276 5.00 1 07/22/202118:36 WG1710319 0.126 1.00 1 07/22/202118:36 WG1710319 0.122 1.00 1 07/22/202118:36 WG1710319 0.107 1.00 1 07/22/202118:36 WG1710319 0.110 1.00 1 07/22/202118:36 WG1710319 0.120 1.00 1 07/22/202118:36 WG1710319 0.374 5.00 1 07/22/202118:36 WG1710319 0.100 1.00 1 07/22/202118:36 WG1710319 0.0819 1.00 1 07/22/202118:36 WG1710319 C3 0.188 1.00 1 07/22/202118:36 WG1710319 0.126 1.00 1 07/22/202118:36 WG1710319 0.149 1.00 1 07/22/202118:36 WG1710319 0.149 1.00 1 07/22/202118:36 WG1710319 0.142 1.00 1 07/22/202118:36 WG1710319 0.110 1.00 1 07/22/202118:36 WG1710319 0.111 1.00 1 07/22/202118:36 WG1710319 0.118 1.00 1 07/22/202118:36 WG1710319 0.161 1.00 1 07/22/202118:36 WG1710319 0.105 1.00 1 07/22/202118:36 WG1710319 0.137 1.00 1 07/22/202118:36 WG1710319 0.337 1.00 1 07/22/202118:36 WG1710319 0.105 1.00 1 07/22/202118:36 WG1710319 0.120 1.00 1 07/22/202118:36 WG1710319 1.19 10.0 1 07/22/202118:36 WG1710319 0.430 5.00 1 07/22/202118:36 WG1710319 0.478 10.0 1 07/22/202118:36 WG1710319 0.101 1.00 1 07/22/202118:36 WG1710319 1.00 5.00 1 07/22/202118:36 WG1710319 0.0993 1.00 1 07/22/202118:36 WG1710319 0.118 1.00 1 07/22/202118:36 WG1710319 0.147 1.00 1 07/22/202118:36 WG1710319 0.133 1.00 1 07/22/202118:36 WG1710319 C3 0.180 1.00 1 07/22/202118:36 WG1710319 0.300 1.00 1 07/22/202118:36 WG1710319 0.278 1.00 1 07/22/202118:36 WG1710319 0.230 1.00 1 07/22/202118:36 WG1710319 0.481 1.00 1 07/22/202118:36 WG1710319 FP1 FTc FSS 4 Cn Rc I q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 34 of 51 TRIP BLANK SAMPLE RESULTS - 12 Collected date/time: 07/20/21 00:00 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202118:36 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202118:36 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202118:36 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202118:36 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202118:36 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202118:36 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202118:36 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202118:36 WG1710319 Vinyl chloride U C3 0.234 1.00 1 07/22/202118:36 WG1710319 Xylenes, Total U 0.174 3.00 1 07/22/202118:36 WG1710319 (S) Toluene-d8 109 80.0-120 07/22/202118:36 WG1710319 (S) Toluene-d8 96.4 80.0-120 08/02/202121.07 WG1716050 (S) 4-Bromofluorobenzene 97.6 77.0-126 07/22/202118:36 WG1710319 (S) 4-Bromofluorobenzene 102 77.0-126 08/02/202121.07 WG1716050 (S) 1,2-Dich/oroethone-d4 104 70.0-130 07/22/202118:36 WG1710319 (S) 1,2-Dich/oroethane-d4 101 70.0-130 08/02/202121.07 WG1716050 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 35 of 51 WG1711035 QUALITY CONTROL SUMMARY Wet Chemistry by Method 2320 B-2011 L1380832-02,03,04,06,07 Method Blank (MB) (MB) R3683563-1 07/25/21 06:54 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Alkalinity U 8450 20000 Sample Narrative: BLANK: Endpoint pH 4.5 L1380832-02 Original Sample (OS) • Duplicate (DUP) (OS) L1380832-02 07/25/21 07:19 • (DUP) R3683563-3 07/25/21 07:23 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 141000 143000 1 1.48 20 Sample Narrative: OS: Endpoint pH 4.5 Headspace DUP: Endpoint pH 4.5 L1380832-07 Original Sample (OS) • Duplicate (DUP) (OS) L1380832-07 07/25/21 07:41 • (DUP) R3683563-6 07/25/21 07:43 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 9960 10600 1 6.11 J 20 Sample Narrative: OS: Endpoint pH 4.5 Headspace DUP: Endpoint pH 4.5 Laboratory Control Sample (LCS) (LCS) R3683563-5 07/25/21 07:30 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Alkalinity 100000 102000 102 90.0-110 Sample Narrative: LCS: Endpoint pH 4.5 FP1 Fc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 36 of 51 WG1709392 Wet Chemistry by Method 450052 D-2011 Method Blank (MB) (MB) R3682599-1 07/22/21 10:43 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Sulfide U 25.0 MB RDL ug/1 50.0 L1380832-02 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1380832-02,03,04,06,07 (OS) L1380832-02 07/22/21 10:44 • (DUP) R3682599-3 07/22/21 10:44 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 L1380832-07 Original Sample (OS) • Duplicate (DUP) (OS) L1380832-07 07/22/21 10:45 • (DUP) R3682599-4 07/22/21 10:46 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3682599-2 07/22/21 10:43 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Sulfide 500 574 115 Rec. Limits LCS Qualifier 85.0-115 L1380984-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1380984-01 07/22/21 10:46 • (MS) R3682599-5 07/22/21 10:46 • (MSD) R3682599-6 07/22/21 10:46 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Sulfide 1000 U 1070 1120 107 112 1 80.0-120 4.66 RPD Limits 20 — I Cp Fc FSS 4 Cn FSr _ �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 37 of 51 WG1709100 Wet Chemistry by Method 9056A Method Blank (MB) (MB) R3682724-1 07/21/21 15:05 MB Result MB Qualifier MB MDL Analyte ug/I ug/1 Chloride U 379 Nitrate U 48.0 Sulfate U 594 L1380824-01 Original Sample (OS) • Duplicate (DUP) MB RDL ug/I 1000 100 5000 (OS) L1380824-01 07/21/21 16:16 • (DUP) R3682724-3 07/21/21 16:32 Original Result DUP Result Dilution DUP RPD Analyte ug/I ug/1 % Chloride 3190 3150 1 1.19 Nitrate 780 773 1 0.889 Sulfate 5980 5950 1 0.540 L1380862-01 Original Sample (OS) • Duplicate (DUP) (OS) L1380862-01 07/21/21 23:39 • (DUP) R3682724-6 07/21/21 23:56 Original Result DUP Result Dilution DUP RPD Analyte ug/I ug/1 % Chloride 50200 50200 1 0.102 Nitrate 4090 4120 1 0.729 Sulfate 870 859 1 0.000 Laboratory Control Sample (LCS) QUALITY CONTROL SUMMARY L1380832-02,03,04,06,07 DUP Qualifier DUP RPD Limits 15 15 15 DUP Qualifier DUP RPD Limits 15 15 15 (LCS) R3682724-2 07/21/21 15:22 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/1 % % Chloride 40000 39300 98.3 80.0-120 Nitrate 8000 8020 100 80.0-120 Sulfate 40000 39400 98.5 80.0-120 FP1 Fc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 38 of 51 WG1709100 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9056A L1380832-02,03,04,06,07 L138O824-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1380824-01 07/21/21 16:16 • (MS) R3682724-4 07/21/21 16:49 • (MSD) R3682724-5 07/21/21 17:05 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Chloride 50000 3190 53400 54800 100 103 1 80.0-120 2.46 Nitrate 5000 780 5860 6010 102 105 1 80.0-120 2.48 Sulfate 50000 5980 56000 57300 100 103 1 80.0-120 2.33 L1380862-01 Original Sample (OS) • Matrix Spike (MS) (OS) L1380862-01 07/21/21 23:39 • (MS) R3682724-7 07/22/21 00:12 Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier Analyte ug/I ug/I ug/I % % Chloride 50000 50200 99200 98.1 1 80.0-120 Nitrate 5000 4090 9290 104 1 80.0-120 Sulfate 50000 870 50600 99.4 1 80.0-120 RPD Limits o� 15 15 15 FP1 FC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 39 of 51 WG1709178 Wet Chemistry by Method 9060A Method Blank (MB) (MB) R3682558-2 07/21/2114:51 MB Result MB Qualifier MB MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 430 J 102 MB ROL ug/I 1000 L1380862-04 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1380832-02,03,04,06,07 (OS) L1380862-04 07/22/21 00:18 • (DUP) R3682558-8 07/22/21 00:32 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC (Total Organic Carbon) 1560 1700 1 8.45 20 Laboratory Control Sample (LCS) (LCS) R3682558-1 07/21/21 14:38 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % TOC (Total Organic Carbon) 75000 74500 99.3 85.0-115 L1380760-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1380760-02 07/21/21 20:08 • (MS) R3682558-6 07/21/21 20:35 • (MSD) R3682558-7 07/21/21 20:57 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC (Total Organic Carbon) 50000 1570 51800 48900 100 94.7 1 80.0-120 5.62 RPD Limits 20 — I Cp Fc FS-S 4 Cn rs—r _ �GI rAl FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 40 of 51 WG1712545 Metals (ICP) by Method 6010D QUALITY CONTROL SUMMARY L1380832-01,02,03,04,05,06,07,08,09,10 Method Blank (MB) (MB) R3685749-1 07/30/21 01:03 MB Result Analyte ug/I Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc U U U U U U U U U U U U 4.43 U U MB Qualifier J Laboratory Control Sample (LCS) MB MDL ug/I 4.30 4.40 0.736 0.330 0.479 1.40 0.840 3.68 2.99 1.61 7.35 1.54 4.31 4.99 6.52 MB RDL ug/I 10.0 10.0 5.00 2.00 2.00 10.0 10.0 10.0 6.00 10.0 10.0 5.00 10.0 20.0 50.0 (LCS) R3685749-2 07/30/21 01:06 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Antimony 1000 988 98.8 80.0-120 Arsenic 1000 948 94.8 80.0-120 Barium 1000 1030 103 80.0-120 Beryllium 1000 972 97.2 80.0-120 Cadmium 1000 955 95.5 80.0-120 Chromium 1000 957 95.7 80.0-120 Cobalt 1000 987 98.7 80.0-120 Copper 1000 980 98.0 80.0-120 Lead 1000 980 98.0 80.0-120 Nickel 1000 970 97.0 80.0-120 Selenium 1000 966 96.6 80.0-120 Silver 200 171 85.6 80.0-120 Thallium 1000 947 94.7 80.0-120 Vanadium 1000 992 99.2 80.0-120 Zinc 1000 990 99.0 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 41 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC WG1712545 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1380832-01,02,03,04,05,06,07,08,09,10 L1381181-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1381181-04 07/30/21 01:09 • (MS) R3685749-4 07/30/21 01:14 • (MSD) R3685749-5 07/30/21 01:16 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Antimony 1000 U 1010 1030 101 103 1 75.0-125 1.62 20 Arsenic 1000 U 985 990 98.5 99.0 1 75.0-125 0.492 20 Barium 1000 69.8 1090 1100 102 103 1 75.0-125 0.572 20 Beryllium 1000 U 977 981 97.7 98.1 1 75.0-125 0.346 20 Cadmium 1000 U 974 979 97.4 97.9 1 75.0-125 0.531 20 Chromium 1000 U 955 964 95.5 96.4 1 75.0-125 1.00 20 Cobalt 1000 1.74 1000 1010 100 101 1 75.0-125 0.748 20 Copper 1000 U 982 991 98.2 99.1 1 75.0-125 0.848 20 Lead 1000 U 992 1000 99.2 100 1 75.0-125 0.987 20 Nickel 1000 3.59 985 995 98.2 99.1 1 75.0-125 0.973 20 Selenium 1000 U 1010 1010 101 101 1 75.0-125 0.102 20 Silver 200 U 173 174 86.7 86.9 1 75.0-125 0.200 20 Thallium 1000 U 948 951 94.8 95.1 1 75.0-125 0.346 20 Vanadium 1000 U 994 1000 99.4 100 1 75.0-125 1.08 20 Zinc 1000 U 992 1000 99.2 100 1 75.0-125 0.846 20 FP1 Fc FSS 4 Cn FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 42 of 51 WG1710319 Volatile Organic Compounds (GC/MS) by Method 8260D QUALITY CONTROL SUMMARY L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3686791-3 07/22/21 12:14 MB Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U tert-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U MB Qualifier MB MDL MB RDL ug/I ug/I 11.3 50.0 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.129 1.00 0.605 5.00 0.157 1.00 0.125 1.00 0.127 1.00 0.128 1.00 0.116 1.00 0.140 1.00 0.192 5.00 0.111 5.00 0.960 2.50 0.106 1.00 0.114 1.00 0.276 5.00 0.126 1.00 0.122 1.00 0.107 1.00 0.110 1.00 0.120 1.00 0.374 5.00 0.100 1.00 0.0819 1.00 0.188 1.00 0.126 1.00 0.149 1.00 0.149 1.00 0.142 1.00 0.110 1.00 0.111 1.00 0.118 1.00 0.161 1.00 0.105 1.00 0.137 1.00 0.337 1.00 0.105 1.00 FP1 FC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1380832 08/03/21 15:48 43 of 51 WG1710319 Volatile Organic Compounds (GC/MS) by Method 8260D QUALITY CONTROL SUMMARY L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3686791-3 07/22/21 12:14 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1,2,3-Trichlorobe nzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,3-Trimethyl benzene U 0.104 1.00 1,2,4-Trimethylbenzene U 0.322 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 110 80.0-120 (S) 4-Bromofluorobenzene 96.9 77.0-126 (S)1,2-Dich/oroethone-d4 104 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3686791-1 07/22/21 11:17 • (LCSD) R3686791-2 07/22/21 11:36 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Acetone 25.0 38.9 36.1 156 144 19.0-160 7.47 27 Acrolein 25.0 9.30 9.26 37.2 37.0 10.0-160 0.431 26 Acrylonitrile 25.0 30.0 27.5 120 110 55.0-149 8.70 20 Benzene 5.00 4.31 4.30 86.2 86.0 70.0-123 0.232 20 Bromobenzene 5.00 5.02 5.05 100 101 73.0-121 0.596 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/21 15:48 44 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC WG1710319 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3686791-1 07/22/21 11:17 • (LCSD) R3686791-2 07/22/21 11:36 Spike Amount LCS Result LCSD Result Analyte ug/I ug/I ug/I Bromoform 5.00 4.64 4.49 Bromomethane 5.00 4.73 4.71 n-Butylbenzene 5.00 5.27 5.46 sec -Butyl benzene 5.00 5.19 5.40 tert-Butylbenzene 5.00 5.18 5.39 Carbon tetrachloride 5.00 4.49 4.47 Chlorobenzene 5.00 5.14 5.20 Chlorodibromomethane 5.00 4.93 4.83 Chloroethane 5.00 4.14 4.29 Chloroform 5.00 4.13 4.22 Chloromethane 5.00 4.26 4.61 2-Chlorotoluene 5.00 5.30 5.40 4-Chlorotoluene 5.00 5.40 5.55 1,2-Dibromo-3-Chloropropane 5.00 5.69 5.41 1,2-Dibromoethane 5.00 5.23 5.20 Dibromomethane 5.00 4.74 4.73 1,2-Dichlorobenzene 5.00 5.43 5.41 1,3-Dichlorobenzene 5.00 5.15 5.31 1,4-Dichlorobenzene 5.00 5.35 5.35 Dichlorodifluoromethane 5.00 4.04 4.13 1,1-Dichloroethane 5.00 4.29 4.29 1,2-Dichloroethane 5.00 4.53 4.53 1,1-Dichloroethene 5.00 3.94 4.02 cis-1,2-Dichloroethene 5.00 4.40 4.37 trans-1,2-Dichloroethene 5.00 4.28 4.34 1,2-Dichloropropane 5.00 4.31 4.38 1,1-Dichloropropene 5.00 4.38 4.48 1,3-Dichloropropane 5.00 5.07 5.06 cis-1,3-Dichloropropene 5.00 4.22 4.36 trans-1,3-Dichloropropene 5.00 4.94 4.93 2,2-Dichloropropane 5.00 4.54 4.45 Di -isopropyl ether 5.00 4.51 4.50 Ethylbenzene 5.00 4.92 5.11 Hexachloro-1,3-butadiene 5.00 5.11 5.09 Isopropylbenzene 5.00 4.96 5.00 p-Isopropyltoluene 5.00 5.17 5.28 2-Butanone (MEK) 25.0 28.3 27.8 Methylene Chloride 5.00 4.87 4.74 4-Methyl-2-pentanone (MIBK) 25.0 28.3 27.6 Methyl tert-butyl ether 5.00 4.39 4.35 ACCOUNT: Withers & Ravenel Eng. - Standard LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits 92.8 89.8 68.0-132 3.29 20 94.6 94.2 10.0-160 0.424 25 105 109 73.0-125 3.54 20 104 108 75.0-125 3.97 20 104 108 76.0-124 3.97 20 89.8 89.4 68.0-126 0.446 20 103 104 80.0-121 1.16 20 98.6 96.6 77.0-125 2.05 20 82.8 85.8 47.0-150 3.56 20 82.6 84.4 73.0-120 2.16 20 85.2 92.2 41.0-142 7.89 20 106 108 76.0-123 1.87 20 108 111 75.0-122 2.74 20 114 108 58.0-134 5.05 20 105 104 80.0-122 0.575 20 94.8 94.6 80.0-120 0.211 20 109 108 79.0-121 0.369 20 103 106 79.0-120 3.06 20 107 107 79.0-120 0.000 20 80.8 82.6 51.0-149 2.20 20 85.8 85.8 70.0-126 0.000 20 90.6 90.6 70.0-128 0.000 20 78.8 80.4 71.0-124 2.01 20 88.0 87.4 73.0-120 0.684 20 85.6 86.8 73.0-120 1.39 20 86.2 87.6 77.0-125 1.61 20 87.6 89.6 74.0-126 2.26 20 101 101 80.0-120 0.197 20 84.4 87.2 80.0-123 3.26 20 98.8 98.6 78.0-124 0.203 20 90.8 89.0 58.0-130 2.00 20 90.2 90.0 58.0-138 0.222 20 98.4 102 79.0-123 3.79 20 102 102 54.0-138 0.392 20 99.2 100 76.0-127 0.803 20 103 106 76.0-125 2.11 20 113 111 44.0-160 1.78 20 97.4 94.8 67.0-120 2.71 20 113 110 68.0-142 2.50 20 87.8 87.0 68.0-125 0.915 20 PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1380832 08/03/21 15:48 45 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC WG1710319 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3686791-1 07/22/21 11:17 • (LCSD) R3686791-2 07/22/21 11:36 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Naphthalene 5.00 5.38 5.30 108 106 54.0-135 1.50 20 n-Propylbenzene 5.00 5.34 5.56 107 ill 77.0-124 4.04 20 Styrene 5.00 5.07 5.02 101 100 73.0-130 0.991 20 1,1,1,2-Tetrachloroethane 5.00 5.09 4.98 102 99.6 75.0-125 2.18 20 1,1,2,2-Tetrachloroethane 5.00 5.94 5.87 119 117 65.0-130 1.19 20 Tetrachloroethene 5.00 4.73 4.87 94.6 97.4 72.0-132 2.92 20 Toluene 5.00 4.87 5.00 97.4 100 79.0-120 2.63 20 1,1,2-Trichlorotrifluoroethane 5.00 3.91 3.96 78.2 79.2 69.0-132 1.27 20 1,2,3-Trichlorobenzene 5.00 4.79 4.90 95.8 98.0 50.0-138 2.27 20 1,2,4-Trichlorobenzene 5.00 5.25 5.40 105 108 57.0-137 2.82 20 1,1,1-Trichloroethane 5.00 4.52 4.56 90.4 91.2 73.0-124 0.881 20 1,1,2-Trichloroethane 5.00 5.15 5.16 103 103 80.0-120 0.194 20 Trichloroethene 5.00 4.32 4.35 86.4 87.0 78.0-124 0.692 20 Trichlorofluoromethane 5.00 3.73 3.93 74.6 78.6 59.0-147 5.22 20 1,2,3-Trichloropropane 5.00 5.49 5.35 110 107 73.0-130 2.58 20 1,2,3-Trimethyl benzene 5.00 5.27 5.30 105 106 77.0-120 0.568 20 1,2,4-Trimethylbenzene 5.00 5.16 5.29 103 106 76.0-121 2.49 20 1,3,5-Trimethyl benzene 5.00 5.24 5.32 105 106 76.0-122 1.52 20 Vinyl chloride 5.00 3.91 4.11 78.2 82.2 67.0-131 4.99 20 Xylenes, Total 15.0 15.3 14.6 102 97.3 79.0-123 4.68 20 (S) Toluene-d8 108 109 80.0-120 (S) 4-Bromofluorobenzene 97.9 97.4 77.0-126 (S)1,2-Dich/oroethane-d4 106 104 70.0-130 FP1 FC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 46 of 51 WG1716050 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3687142-3 08/02/21 10:58 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/1 ug/I Bromodichloromethane U 0.136 1.00 (S) Toluene-d8 96.1 80.0-120 (S) 4-Bromofluorobenzene 104 77.0-126 (S)1,2-Dich/oroethane-d4 113 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3687142-1 08/02/21 10:02 • (LCSD) R3687142-2 08/02/21 10:21 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I Ug/l ug/1 % % % % % Bromodichloromethane 5.00 5.70 5.89 114 118 75.0-120 3.28 20 (S) Toluene-d8 94.1 93.9 80.0-120 (S)4-Bromofluorobenzene 109 106 77.0-126 (S)1,2-Dich/oroethane-d4 117 119 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 47 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) U Analyte Dilution Limits Original Sample Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. FP1 FTC FSS 4 Cn FSr Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be FQC detected in all environmental media. Not detected at the Reporting Limit (or MDL where applicable). The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the rA laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal I9 for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or SC duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description B The same analyte is found in the associated blank. C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. J The identification of the analyte is acceptable; the reported value is an estimate. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 48 of 51 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolinas 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhodelsland LA000356 Kentucky16 KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' ° 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas' LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A21-A A21-A — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A21-A — ISO 17025 s 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks 'Aquatic Toxicity ° Chemical/Microbiological 'Mold 6 Wastewater n/a Accreditation not applicable Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. FP1 FTc FSS 4 Cn FSr Rc I ql FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 49 of 51 Company Name/Address: Billing Information: Withers & Ravenel Eng. - Standard Accounts Payable 115 MacKenan Drive 115 MacKenan Drive Cary, NC 27511 Cary, NC 27511 Pres ChkI \:l I 1'\ I ii-_Q1 Hepor[ to: Email To Ielliott@withersravenel.com `Laura Elliott Project Description: Gty/State Please Cir c \6 Kernersville landfill Collected: PT MT C Client Project # Lab Project # Phone: 919 469 3340 06140180.39 WITHRAVS-KERNERSVILL Collected by {print]: Site/Facility 10 # P.C. tf 06140180.40--S3 Coll: ed to (signatu e) + Rush? 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Received b : (Signal rel fletties Received: 7em P:od 3 C If preservation required by Login: Date/Time Re i uished : ) • Z- • li! • lr Relinquished by (Signature) Date: Time: Rece' `+b by; Signature Dae� `� Timetr Hold: Condition: Company Name/Address: Billing Information: A ialvsis / Container Pr nervative Chain of Custody Page !�ol _ 'J Withers & Ravenel Eng. - Standard Tres Accounts Payable 115 MacKenan Drive Chk ; aeeAnalytical 115 MacKenan Drive Cary, NC 27511 Cary, NC 27511 12065 Lebanon Rd Mounl lhh.t. 7N 37122 Report to: Email To, Ielliott@withersravenel,com a o s.bmlu'.9 a -Pt. v.. 11,"' N" °r.USmdy Laura Elliott w q .Ke.a ackn .1,dg,.n1 modbf rh. P h and Co"i.om fo," aP h7�: ffi,fo P... hb,. ,m h,M./poistandard- Project Description' City/State t Please Cird Kernersville Landfill Collected: PT MT CT €T d «m Pd rrt ❑ _ N + I SDG # 17�rj�32 Client Project p Lab Project A Phone:919-469-3340 06140190.39 WITHRAVS-KERNERSVILI. Z = E G Table a w IL p Ln ry ° Z Col ected by (print): it ID # P.O. x Acctnum: WITHRAVS i 06140180.4iF11 z 0 u u p � n C Q S w T Tempiate:T170822 Collect b si nature Y{ g Quote if Rush? [Loh MUST Be Notified] Q v7 r t z E d ❑ Q Prelogin: P860832 t" Same Day _ Five Day -- Its Needed Next Day _ S Day (Rad Only) DateT'LU4 uQ1 PM: 87 - He ther 1 Wagner Im ci tely . / _ Two Day _ 10 Day (Rad Only) No. a. fV E U O PB' Packed cn Ice N _ Y Y Three Day S of O L 2 o Shippe Via: e[iEX Ground Sample ID Comp/Grab Matrix ` Depth Date Time ntrs J V N Remarks Sampi' x ;14 enlyi a a G w > GW rr 2124nr4 x x —1 U Cv GW 2.. Z r � 5 "rYl TT GW GW 3 X X X GW 3 X X X GW i 3 X X X GW 3 x X x r _ _ F 1 "Matrix:Remarks: Sample Receipt Checklist SS -Soil AIR -Air F- filter pH Temp COC Seal Present/Intact: _N11 1% _N GW -Groundwater B- Bloassay COC Signed/Accurate:,N Flow Other Bottles arrive intact: � N WW - WasteWater Correct bottles used:N DW -Drinking Water Sufficient volume sent: %Y _N re Samples med via: OT -Other edFx Courier Tracking q If able UPS y F T VOA Zero HPadapazeaoe: � N Relin shed by (Sign ure Date, Time. Receiv by ISignatu e} Trip Blannk eceived: e)/ No Preservation Correct/Checked: _N - PAD Screen <O,S mRlitr: LY —N / MeoH �� TOR R in i ed y (Signature) Dat4 k Time Rene ved bq (Signature) Terrpo3 °C Bottles Received: If preservation required by Login: Date/Time •L- l� 1• I Relinquished by : {Signature} Date. Time Recei for la by: {Sign to Time: Date]]: Hold: Conditi! f y } L� L -6 1\./ NCF /V Page 1 of 1 r P s:rle Your Success Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MWJLZR- Site Name Kernersville Closed Landfill Dater 7/20/2021 Well Depth Depth to Water 1.5� Well Diameter 2" Casing Material PVC Screen Length 5 Well Water Volume Sampling Crew S. Powell. Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity Other Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time 8260 VOCs HCL 40 ml VOAs glass 14 Days None 1 Liter glass 7 Days 6010 Metals Nitric Acid 250 ml plastic 180 Days 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Calculation 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2"well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft= 4" well [well depth-0epth to water] x 0.653 alal lift. x 3 = 1.959/ft = \A) - 2.54 - , it X-3 t 5.1 \ 5 N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID Mwlmft air Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 24 Depth to Water I LY j Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew !, L. Parsons _ Pump Type bailer Tubing Type Intake set at j'3 • t13 Weather Conditions _ -:74- _� �y Notes (eg. odororcolor) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity � um Uther Narameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days vvcn vuturrl@ t-aicuiavon 1 well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of i Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-3D Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 57 Depth to Water_,' Well Diameter 2" Casing Material PVC Screen Length 20 Well Water Volume Sampling Crew_ 51� L. Parsons Pump Type _ Grundfos Tubing Type poly _ Intake set at Weather Conditions Q — % Clelu ne,e Notes (eg, odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (from TOC] Gals. m /L °C Slcm) (standard mV NTU © ?-,&3 eg,,?qj7ZO Other Parameters Sampled at to Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days NOTE: DUPLICATE SAMPLE vverl volume La[culat[on 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-4 Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 14 Depth to Water r'%�� Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Parsons Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 1, iila=ii�:T.i1rC�Ifl ■ =�E'y[.Tii1)t - ■ . ■ =1�1 ��=��j Other Parameters Sampled at 1155 Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Other Parameters Sampled at 1155 Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Galculation 1 " well [well depth -depth to wafer] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 galleons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s No Page 1 of 1 NO Our People, Your Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-t.Z Site Name Kernersville Closed Landfill Date 7120/20211 Well Depth 4 Depth to Water ` 9J Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Parsons Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals.) rn 1L) {`'G} (pSicrrl) (standard) ImV NTU ►0'1pLA-1b O(j) SO.5 .170 (017 i, I Other Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Galculation 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft._ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-6 Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 20 Depth to Water 11 11 ~t�.'Z Well Diameter 2' Casing Material PVC Screen Length —A 10 Well Water Volume 0. Sampling Crew S. PQwe//, L Parsons Pump Type bailer Tubing Type Intake set at. Weather Conditions �� _ �� ��,, �1 � Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity Uther Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC None 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days well volume Lalcu[atlon 1" well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] X 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallonstft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s KMUUAZ191PAI II BIOSCREEN Modeling Data BIOSCREEN Natural Attenuation Decision Support System Air Force Center for Environmental Excellence Version 1.4 1. HYDROGEOLOGY Seepage Velocity* or Hydraulic Conductivity Hydraulic Gradient Porosity 2. DISPERSION Longitudinal Dispersivity* Transverse Dispersivity* Vertical Dispersivity* or Estimated Plume Length 3. ADSORPTION Retardation Factor* or Soil Bulk Density Partition Coefficient FractionOrganicCarbon Vs K i n 0.3 (ft/yr) (cm/sec) (ft/ft) (-) nr 1.2E-06 0.05 0.2 alpha x 4.8 (ft) alpha y 0.5 (ft) alpha z 0.0 (ft) T or Lp 60 (ft) R 3.2 (-) T or rho 1.6 (k9/1) Koc 150 (L/kg) foc 1.8E-3 ( ) 4. BIODEGRADATION 1 st Order Decay Coeff* lambda or Solute Half -Life t-half or Instantaneous Reaction Model Delta Oxygen* DO Delta Nitrate* NO3 Observed Ferrous Iron* Fe2+ Delta Sulfate* SO4 Observed Methane* CH4 6.9E-1 (per yr) Tnr 1.00 (year) 2.85 (mg/L) 0 (mg/L) 5 (mg/L) 0.98 (mg/L) 0 (mg/L) 5. GENERAL Modeled Area Length* Modeled Area Width* Simulation Time* Kernersville III - UU[14GII Run Name 200 (ft) t4 L 700 (ft) W 10 (yr) 1 Data Input Instructions: 115 1. Enter value directiv.... or T or 2. Calculate by fillinq in grev 0.02 cells below. (To restore formulas, hit button below). Variable* Data used directly in model. m Value calculated by model. (Don't enter anv data). 6. SOURCE DATA Source Thickness in Sat.Zone* 15 (ft) Vertical Plane Source: Look at Plume Cross -Section Source Zones: and Input Concentrations &Widths Wirlfh* (ffl I none (mn/l 1* I for Zones 1, 2, and 3 150 0.0001 150 0.001 50 0.0031 Source Halflife (see Hel (yr) Inst. React.%i__1st Order Soluble Massl infinite (Kg) In Source NAPL, Soil 7. FIELD DATA FOR COMPARISON Concentration (mg/L) Dist. from Source (ft) 003 8. CHOOSE TYPE OF OUTPUT TO SEE: 0 View of Plume Looking Down Observed Centerline Concentrations at Monitoring Wells If No Data Leave Blank or Enter "0" RUN RUN ARRAY CENTERLINE View Output View Output r Help Recalculate This r r Paste Example Dataset Restore Formulas for Vs, TYPE OF MODEL L_ No Degradation 0.003 1st Order Decay 0.003 Inst. Reactionj 0.003 Field Data from Site 1, 0.003 0.004 0.003 c 0.003 - 0.002 0 0.002 U 0.001 0.001 0.000 DISSOLVED HYDROCARBON CONCENTRATION ALONG PLUME CENTERLINE (mg/L at Z--0) Distance from Source (ft) MbL 801bL7 100 0.000 J&20&7 140 160 0.000 0.000 `180jajj 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.001 1st Order Decay '211110-o-Instantaneous Reaction fNo Degradation H Field Data from Site 0 Time: 10 Years ❑ El 100 150 Distance From Source (ft) Return to 200 Recalculate This Transverse Distance ft) 0 350 0.000 0.000 DISSOLVED HYDROCARBON CONCENTRATIONS IN PLUME (mg/L at �0) Distance from Source ft) 80 100 120 180 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 200 0.000 � Model to Display. No Degradation 175 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 , 0 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -175 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 , 1st Order Decay -350 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 1 0.000 1 0.000 Instantaneous MASS FLUX (mg/day) 7 3.5E-2 1.4E-11 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 Time: 0 Year 1s Target Level: 0.005 mg/L Displayed Model: ion No Degradat 0 E c 0 c a� C O A 0.004 0.003 0.003 0.002 0.002 0.001 0.001 0.00( Plot All DaLa Plot Data > Target (ft) 1 4U 160 180 Plume and Source Masses (Order -of -Magnitude Accuracy) Plume Mass if No Biodegradation Can't Calc. (Kg) - Actual Plume Mass Can't Calc. (Kg) = Plume Mass Removed by Biodeg(Kg) Change in Electron Acceptor/Byproduct Masses: Nitrate Iron ll Sulfate Methane na na na na (Ka) Contam. Mass in Source (t=0 Years) infinite (Kg) Contam. Mass in Source Now (t=10Years) Infinite I(Kg) Current Volume of Groundwater in Plume Can't Calc. (ac-ft) Flowrate of Water Through Source Zone Can't Calc. (ac-ft/yr) Mass HELP . Recalculate BIOSCREEN Natural Attenuation Decision Support System Air Force Center for Environmental Excellence Version 1.4 1. HYDROGEOLOGY Seepage Velocity* or Hydraulic Conductivity Hydraulic Gradient Porosity 2. DISPERSION Longitudinal Dispersivity* Transverse Dispersivity* Vertical Dispersivity* or Estimated Plume Length 3. ADSORPTION Retardation Factor* or Soil Bulk Density Partition Coefficient FractionOrganicCarbon Vs K i n 0.3 (ft/yr) (cm/sec) (ft/ft) (-) nr 1.2E-06 0.05 0.2 alpha x 4.8 (ft) alpha y 0.5 (ft) alpha z 0.0 (ft) T or Lp 60 (ft) R 1.5 (-) T or rho 1.6 (k9/1) Koc 32 (L/kg) foc 1.8E-3 ( ) 4. BIODEGRADATION 1 st Order Decay Coeff* lambda or Solute Half -Life t-half or Instantaneous Reaction Model Delta Oxygen* DO Delta Nitrate* NO3 Observed Ferrous Iron* Fe2+ Delta Sulfate* SO4 Observed Methane* CH4 6.9E-1 (per yr) Tnr 1.00 (year) 2.85 (mg/L) 0 (mg/L) 5 (mg/L) 0.98 (mg/L) 0 (mg/L) 5. GENERAL Modeled Area Length* Modeled Area Width* Simulation Time* Kernersville Run Name 200 (ft) t4 L 700 (ft) W 10 (yr) 1 Data Input Instructions: 115 1 1. Enter value directiv.... or t or 2. Calculate by fillinq in grev 0.02 cells below. (To restore formulas, hit button below). Variable* Data used directly in model. m Value calculated by model. (Don't enter anv data). 6. SOURCE DATA Source Thickness in Sat.Zone* 15 (ft) Vertical Plane Source: Look at Plume Cross -Section Source Zones: and Input Concentrations &Widths Wirlfh* (ffl I none (mn/l 1* I for Zones 1, 2, and 3 150 0.0001 150 0.001 50 0.0092 Source Halflife (see Hel (yr) Inst. React.%i__1st Order Soluble Massl infinite (Kg) In Source NAPL, Soil 7. FIELD DATA FOR COMPARISON Concentration (mg/L) Dist. from Source (ft) 009 8. CHOOSE TYPE OF OUTPUT TO SEE: 0 View of Plume Looking Down Observed Centerline Concentrations at Monitoring Wells If No Data Leave Blank or Enter "0" RUN RUN ARRAY CENTERLINE View Output View Output r Help Recalculate This r r Paste Example Dataset Restore Formulas for Vs, TYPE OF MODEL L_ No Degradation 0.009 1st Order Decay 0.009 Inst. Reactionj 0.009 Field Data from Site 1, 0.009 0.010 0.008 0 r a 0.006 0.004 0 U 0.002 0.000 DISSOLVED HYDROCARBON CONCENTRATION ALONG PLUME CENTERLINE (mg/L at Z--0) Distance from Source (ft) MbL 801bL7 100 0.000 J&20&7 140 160 0.000 0.000 `180jajj 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 0.003 0.001 1st Order Decay Instantaneous Reaction fNo Degradation H Field Data from Site 0 Time: 10 Years ❑ ❑ ❑ 100 150 Distance From Source (ft) Return to 200 Recalculate This Transverse DISSOLVED HYDROCARBON CONCENTRATIONS IN PLUME (mg/L at Z--0) Distance (ft) Distance from Source (ft) 350 175 0 -175 -350 MASS FLUX (mg/day) Time: 10 Years 0.010 0.009 J 0.008 0 0.007 c 0.006 0.005 w 0.004 c v 0.003 C C 0.002 U 0.001 0.00( Plot All DaLa Plot Data > Target (ft) Target Level: 0.005 mg/L -14U 160 J 180 Displayed Model: No Degradation Model to Display. - No Degradation 1 1 st Order Decay Instantaneous Plume and Source Masses (Order -of -Magnitude Accuracy) Plume Mass if No Biodegradation Can't Calc. (Kg) - Actual Plume Mass Can't Calc. (Kg) = Plume Mass Removed by Biodeg(Kg) Change in Electron Acceptor/Byproduct Masses: Nitrate Iron ll Sulfate Methane na na na na (Ka) Contam. Mass in Source (t=0 Years)j infinite (Kg) Contam. Mass in Source Now (t=10Years)j Infinite I (Kg) Current Volume of Groundwater in Plume Can't Calc. (ac-ft) Flowrate of Water Through Source Zone Can't Calc. (ac-ft/yr) Mass HELP . Recalculate BIOSCREEN Natural Attenuation Decision Support System Air Force Center for Environmental Excellence Version 1.4 1. HYDROGEOLOGY Seepage Velocity* or Hydraulic Conductivity Hydraulic Gradient Porosity 2. DISPERSION Longitudinal Dispersivity* Transverse Dispersivity* Vertical Dispersivity* or Estimated Plume Length 3. ADSORPTION Retardation Factor* or Soil Bulk Density Partition Coefficient FractionOrganicCarbon Vs K i n 0.3 (ft/yr) (cm/sec) (ft/ft) (-) nr 1.2E-06 0.05 0.2 alpha x 4.8 (ft) alpha y 0.5 (ft) alpha z 0.0 (ft) T or Lp 60 (ft) R 1.6 (-) T or rho 1.6 (k9/1) Koc 40 (L/kg) foc 1.8E-3 ( ) 4. BIODEGRADATION 1 st Order Decay Coeff* lambda or Solute Half -Life t-half or Instantaneous Reaction Model Delta Oxygen* DO Delta Nitrate* NO3 Observed Ferrous Iron* Fe2+ Delta Sulfate* SO4 Observed Methane* CH4 6.9E-1 (per yr) Tnr 1.00 (year) 2.85 (mg/L) 0 (mg/L) 5 (mg/L) 0.98 (mg/L) 0 (mg/L) 5. GENERAL Modeled Area Length* Modeled Area Width* Simulation Time* Kernersville III - I.L ✓lam/ Run Name 200 (ft) t4 L 700 (ft) W 10 (yr) 1 Data Input Instructions: 115 1 1. Enter value directiv.... or t or 2. Calculate by fillinq in grev 0.02 cells below. (To restore formulas, hit button below). Variable* Data used directly in model. m Value calculated by model. (Don't enter anv data). 6. SOURCE DATA Source Thickness in Sat.Zone* 15 (ft) Vertical Plane Source: Look at Plume Cross -Section Source Zones: and Input Concentrations &Widths Wirith* (ffl I none (mn/l 1* I for Zones 1, 2, and 3 150 0.0001 150 0.0002 50 0.00052 Source Halflife (see Help): (yr) Inst. React.%i__1st Order Soluble Massl infinite (Kg) In Source NAPL, Soil 7. FIELD DATA FOR COMPARISON Concentration (mg/L) Dist. from Source (ft) 001 8. CHOOSE TYPE OF OUTPUT TO SEE: 0 View of Plume Looking Down Observed Centerline Concentrations at Monitoring Wells If No Data Leave Blank or Enter "0" RUN RUN ARRAY CENTERLINE View Output View Output r Help Recalculate This r r Paste Example Dataset Restore Formulas for Vs, TYPE OF MODEL L_ No Degradation 0.001 1st Order Decay 0.001 Inst. Reactionj 0.001 Field Data from Site 1, 0.001 0.001 0.001 0.000 .. 0.000 c 0.000 U 0.000 - 0.000 DISSOLVED HYDROCARBON CONCENTRATION ALONG PLUME CENTERLINE (mg/L at Z--0) Distance from Source (ft) 80 100 0.000 A&20&7 140 160 0.000 0.000 `180jajj 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1st Order Decay '211110-o-Instantaneous Reaction fNo Degradation H Field Data from Site 0 50 100 150 200 Distance From Source (ft) Time: 10 Years Return to Recalculate This Transverse DISSOLVED HYDROCARBON CONCENTRATIONS IN PLUME (mg/L at Z--0) Distance (ft) Distance from Source (ft) 350 175 0 -175 -350 MASS FLUX (mg/day) Time: 10 Years 0.010 0.009 J 0.008 0 0.007 c 0.006 0.005 w 0.004 c v 0.003 C C 0.002 U 0.001 0.00( Plot All DaLa Plot Data > Target (ft) Target Level: 0.005 mg/L -14U 160 J 180 Displayed Model: No Degradation Model to Display. - No Degradation 1 1 st Order Decay Instantaneous Plume and Source Masses (Order -of -Magnitude Accuracy) Plume Mass if No Biodegradation Can't Calc. (Kg) - Actual Plume Mass Can't Calc. (Kg) = Plume Mass Removed by Biodeg(Kg) Change in Electron Acceptor/Byproduct Masses: Nitrate Iron ll Sulfate Methane na na na na (Ka) Contam. Mass in Source (t=0 Years)j infinite (Kg) Contam. Mass in Source Now (t=10Years)j Infinite I (Kg) Current Volume of Groundwater in Plume Can't Calc. (ac-ft) Flowrate of Water Through Source Zone Can't Calc. (ac-ft/yr) Mass HELP . Recalculate BIOSCREEN Natural Attenuation Decision Support System Air Force Center for Environmental Excellence Version 1.4 1. HYDROGEOLOGY Seepage Velocity* or Hydraulic Conductivity Hydraulic Gradient Porosity 2. DISPERSION Longitudinal Dispersivity* Transverse Dispersivity* Vertical Dispersivity* or Estimated Plume Length 3. ADSORPTION Retardation Factor* or Soil Bulk Density Partition Coefficient FractionOrganicCarbon Vs K i n 0.3 (ft/yr) (cm/sec) (ft/ft) (-) nr 1.2E-06 0.05 0.2 alpha x 4.8 (ft) alpha y 0.5 (ft) alpha z 0.0 (ft) T or Lp 60 (ft) R 1.9 (-) T or rho 1.6 (k9/1) Koc 61 (L/kg) foc 1.8E-3 ( ) 4. BIODEGRADATION 1 st Order Decay Coeff* lambda or Solute Half -Life t-half or Instantaneous Reaction Model Delta Oxygen* DO Delta Nitrate* NO3 Observed Ferrous Iron* Fe2+ Delta Sulfate* SO4 Observed Methane* CH4 6.9E-1 (per yr) Tnr 1.00 (year) 2.85 (mg/L) 0 (mg/L) 5 (mg/L) 0.98 (mg/L) 0 (mg/L) 5. GENERAL Modeled Area Length* Modeled Area Width* Simulation Time* Kernersville III - I.L ✓l ! Run Name 200 (ft) t4 L 700 (ft) W 10 (yr) 1 Data Input Instructions: 115 1 1. Enter value directiv.... or t or 2. Calculate by fillinq in grev 0.02 cells below. (To restore formulas, hit button below). Variable* Data used directly in model. m Value calculated by model. (Don't enter anv data). 6. SOURCE DATA Source Thickness in Sat.Zone* 15 (ft) Vertical Plane Source: Look at Plume Cross -Section Source Zones: and Input Concentrations &Widths Wirith* (ffl I none (mn/l 1* I for Zones 1, 2, and 3 150 0.001 150 0.002 50 0.00364 Source Halflife (see Hel (yr) Inst. React.%i__1st Order Soluble Massl infinite (Kg) In Source NAPL, Soil 7. FIELD DATA FOR COMPARISON Concentration (mg/L) Dist. from Source (ft) 004 8. CHOOSE TYPE OF OUTPUT TO SEE: 0 View of Plume Looking Down Observed Centerline Concentrations at Monitoring Wells If No Data Leave Blank or Enter "0" RUN RUN ARRAY CENTERLINE View Output View Output r Help Recalculate This r r Paste Example Dataset Restore Formulas for Vs, DISSOLVED HYDROCARBON CONCENTRATION ALONG PLUME CENTERLINE (mg/L at Z_-0) Distance from Source (ft) 0.000 0.000 0.000 80& 0.000 100 0.000 Ak20A 140 0.000 160 0.000 180 0.000 0.000 TYPE OF MODEL No Degradation 0.004 0.000 1st Order Decay 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Inst. Reacti 0.004 0.000 0.000 0.000 0.000 Field Data from Site 0.004 0.002 0.001 1st Order Decay '91111i-*-Instantaneous Reaction fNo Degradation N Field Data from Site 0.004 0.004 9 0.003 0 -� 0.003 0.002 0.002 U 0.001 0.001 0.000 ❑ 10 0 0 ❑ ❑ 0 50 100 150 200 Distance From Source (ft) Time: Calculate 10 Years Animation Return to Recalculate This Transverse DISSOLVED HYDROCARBON CONCENTRATIONS IN PLUME (mg/L at Z--0) Distance (ft) Distance from Source (ft) 350 175 0 -175 -350 MASS FLUX (mg/day) Time: 10 Years 0.004 0.004 J 0.003 a7 0.003 c O 0.002 0.002 a� 0.001 O U 0.001 0.00( Plot All DaLa Plot Data > Target (ft) Target Level: 0.005 mg/L -14U 160 J 180 Displayed Model: No Degradation Model to Display. - No Degradation 1 1 st Order Decay Instantaneous Plume and Source Masses (Order -of -Magnitude Accuracy) Plume Mass if No Biodegradation Can't Calc. (Kg) - Actual Plume Mass Can't Calc. (Kg) = Plume Mass Removed by Biodeg(Kg) Change in Electron Acceptor/Byproduct Masses: Nitrate Iron ll Sulfate Methane na na na na (Ka) Contam. Mass in Source (t=0 Years) infinite (Kg) Contam. Mass in Source Now (t=10Years)j Infinite (Kg) Current Volume of Groundwater in Plume Can't Calc. (ac-ft) Flowrate of Water Through Source Zone Can't Calc. (ac-ft/yr) Mass HELP . Recalculate BIOSCREEN Natural Attenuation Decision Support System Air Force Center for Environmental Excellence Version 1.4 1. HYDROGEOLOGY Seepage Velocity* or Hydraulic Conductivity Hydraulic Gradient Porosity 2. DISPERSION Longitudinal Dispersivity* Transverse Dispersivity* Vertical Dispersivity* or Estimated Plume Length 3. ADSORPTION Retardation Factor* or Soil Bulk Density Partition Coefficient FractionOrganicCarbon Vs K i n 0.3 (ft/yr) (cm/sec) (ft/ft) (-) nr 1.2E-06 0.05 0.2 alpha x 4.8 (ft) alpha y 0.5 (ft) alpha z 0.0 (ft) T or Lp 60 (ft) R 1.4 (-) T or rho 1.6 (k9/1) Koc 30 (L/kg) foc 1.8E-3 ( ) 4. BIODEGRADATION 1 st Order Decay Coeff* lambda or Solute Half -Life t-half or Instantaneous Reaction Model Delta Oxygen* DO Delta Nitrate* NO3 Observed Ferrous Iron* Fe2+ Delta Sulfate* SO4 Observed Methane* CH4 6.9E-1 (per yr) Tnr 1.00 (year) 2.85 (mg/L) 0 (mg/L) 5 (mg/L) 0.98 (mg/L) 0 (mg/L) 5. GENERAL Modeled Area Length* Modeled Area Width* Simulation Time* Kernersville III - VIIIVI l ! Run Name 200 (ft) t4 L 700 (ft) W 10 (yr) 1 luara rnpur rnsrrucrrons: 115 1. Enter value directiv.... or T or 2. Calculate by fillinq in grev 0.02 cells below. (To restore formulas, hit button below). Variable* Data used directly in model. m Value calculated by model. (Don't enter anv data). 6. SOURCE DATA Source Thickness in Sat.Zone* 15 (ft) Vertical Plane Source: Look at Plume Cross -Section Source Zones: and Input Concentrations &Widths Wirlfh* (ffl I none (mn/l 1* I for Zones 1, 2, and 3 150 0.0001 150 0.001 50 0.00402 Source Halflife (see Help): (yr) Inst. React.%i__1st Order Soluble Massl infinite (Kg) In Source NAPL, Soil 7. FIELD DATA FOR COMPARISON Concentration (mg/L) Dist. from Source (ft) 004 8. CHOOSE TYPE OF OUTPUT TO SEE: 0 View of Plume Looking Down Observed Centerline Concentrations at Monitoring Wells If No Data Leave Blank or Enter "0" RUN RUN ARRAY CENTERLINE View Output View Output r Help Recalculate This r r Paste Example Dataset Restore Formulas for Vs, TYPE OF MODEL L_ No Degradation 0.004 1st Order Decay 0.004 Inst. Reacti 0.004 Field Data from Site 1 0.004 0.005 0.004 0.004 0.003 .. -6b 0.003 0.002 c 0.002 U 0.001 - 0.001 - 0.000 DISSOLVED HYDROCARBON CONCENTRATION ALONG PLUME CENTERLINE (mg/L at Z--0) Distance from Source (ft) MbL 801bL7 100 0.000 J&20&7 140 160 0.000 0.000 `180jajj 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.001 1st Order Decay 'Mq��Instantaneous Reaction fNo Degradation H Field Data from Site n Time: 10 Years -T- -O 1 ❑ ❑ 100 150 Distance From Source (ft) Return to 200 Recalculate This Transverse Distance ft) 0 350 0.000 0.000 DISSOLVED HYDROCARBON CONCENTRATIONS IN PLUME (mg/L at �0) Distance from Source ft) 80 100 120 180 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 200 0.000 � Model to Display. No Degradation 175 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 , 0 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 -175 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 , 1st Order Decay -350 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 1 0.000 1 0.000 Instantaneous MASS FLUX (mg/day) 7 3.8E-2 2.9E-6 3.6E-18 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 0.0E+0 Time: 10 Years Target Level: 0.005 mg/L Displayed Model: No Degradation 0.005 0.004 J 0.004 E 0.003 C 0.003 L 0.002 0.002 O 0.001 U 0.001 0.00( Plot All DaLa Plot Data > Target (ft) 1 4U 160 180 Plume and Source Masses (Order -of -Magnitude Accuracy) Plume Mass if No Biodegradation Can't Calc. (Kg) - Actual Plume Mass Can't Calc. (Kg) = Plume Mass Removed by Biodeg(Kg) Change in Electron Acceptor/Byproduct Masses: Nitrate Iron ll Sulfate Methane na na na na (Ka) Contam. Mass in Source (t=0 Years) infinite (Kg) Contam. Mass in Source Now (t=10Years) Infinite I(Kg) Current Volume of Groundwater in Plume Can't Calc. (ac-ft) Flowrate of Water Through Source Zone Can't Calc. (ac-ft/yr) Mass HELP . Recalculate APPENDIX III Historical Summary Tables TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Background Downgradient Well ID: MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 TOC Elevation: 806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth: 34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY WELL NUMBER CASING DIAMETER inches WELL ELEVATIONS TOTAL DEPTH SCREENED INTERVAL* LITHOLOGY OF SCREENED INTERVAL* GROUND SURFACE T.O.C. B.G.S. feet B.T.O.C. feet DEPTH B.G.S. ELEV. M.S.L. feet above M.S.L. from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 L 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S. Below Ground Surface M.S.L. Mean Sea Level B.T.O.C. Below Top of Casing T.O.C. Top of Casing * = Due to limited information this data is assumed based on field conditions Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY November 2014 GRADIENT FLOW LINE GROUND- HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW WATER GRADIENT, CONDUCTIVITY POROSITY VELOCITY, CALCULATION LENGTH DIRECTION ELEV. i K n V SEGMENT (feet) feet ft/ft ft/da ft/da l i 851 SW 0.04 1.73 0.30 0.20 785 Notes: 1. Hydraulic conductivities ("K") was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 --- ND 5.4 B ND ND 4.5 B --- 1.4 J GWPS = 1.4 µg/L (10/23/07) O1-Jun-10 1.2 6.0 --- ND ND ND ND ND --- 3.9 J GAPS = 1 µg/L (8/1/10) 29-Dec-10 2.6 6.0 --- ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 6.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 --- --- ND ND ND ND --- ND 09-May-13 5.0 6.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 6.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 6.0 --- ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 --- --- ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10) O1-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 --- --- 1.43 B 1.42 B 0.87 B 1.04 B --- 1.0 1 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 --- 74.1 J 496 178 18.2 J 89.0 J --- 3.6 J NC 2L = 700 µg/L (1/11/10) 01-Jun-10 1.1 100 --- 58.1 J 326 187 22.2 J 94.9 J --- 2.0 J 29-Dec-10 0.20 100 --- 46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 --- 77.7 1 370 128 41.2 J 98.4 J 113 ND O1-Nov-11 5.0 100 --- 125 413 132 41.7 J 111 72.1 J ND O1-May-12 5.0 100 --- 78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 --- --- 369 127 41.0 B 98.7 J --- 12.2 J 09-May-13 5.0 100 --- 78.6 J 307 112 40.0 J 85.6 J --- ND 07-Nov-13 5.0 100 --- --- 302 113 38.0 J 89.6 J --- ND 05-Jun-14 5.0 100 --- 60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 --- --- 301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 --- ND 0.5 J ND ND ND --- ND GWPS = 4 µg/L (10/23/07) OI-Jun-10 0.2 1.0 --- 0.6 J 0.7 J ND ND ND --- ND 29-Dec-10 0.10 1.0 --- ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 --- --- 0.34 J ND ND 0.099 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 --- ND 0.5 J 5.6 ND ND --- ND NC 2L = 2 µg/L (1/11/10) 01-Jun-10 0.2 1.0 --- 2.9 1.0 B 5.3 0.4 B 0.4 B --- 0.4 J 29-Dec-10 0.50 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 --- --- 0.15 J ND ND 0.043 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 --- ND 2.7 J 9.7 J ND 3.1 J --- ND NC 2L = 10 µg/L (1/11/10) 01-Jun-10 0.7 10.0 --- 3.5 J 1.6 J 12.4 1.2 J 3.2 J --- ND 29-Dec-10 0.40 10.0 --- 0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 10.0 --- ND ND ND ND 10.3 ND ND O1-May-12 5.0 10.0 --- ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 --- --- 0.71 J 0.12 B 0.094 B 7.31 J --- 0.099 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 --- ND 6.4 J 11.2 ND 1.8 J --- ND GAPS = 70 µg/L (10/23/07) 01-Jun-10 0.7 10.0 --- 1.8 J 2.5 J 8.5 J ND 1.7 J --- ND GAPS = 1 µg/L (10/1/10) 29-Dec-10 0.60 10.0 --- ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 --- ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 --- --- 1.98 J 3.89 J 0.43 B 2.02 J --- 0.24 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 --- ND ND 10.6 ND 1.5 J --- ND NC 2L = 1,000 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 12.2 B 3.3 B 33.2 3.9 B 6.8 B --- 4.8 .I 29-Dec-10 0.30 10.0 --- ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 --- 3.56 B 0.54 B 0.98 B 1.83 B --- 1.23 1 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 --- ND ND 10.2 ND ND --- ND NC 2L = 15 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 9.1 B 8.2 B 8.7 B 3.0 B 3.9 B --- 3.2 .I 29-Dec-10 4.0 10.0 --- ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 --- 5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 --- --- 1.00 B 0.091 B 0.066 B 1.12 B --- 0.58 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 --- ND ND 8.1 1 1.8 J 1.6 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.6 50.0 --- ND ND 6.0 1 ND 0.9 1 --- ND 29-Dec-10 1.7 50.0 --- ND ND ND ND ND 2.0 B 3.1 1 29-Jun-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 50.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 --- --- 0.73 B 1.19 B 0.65 B 5.57 J --- 0.84 1 09-May-13 5.0 50.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 50.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 50.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 --- --- ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 --- ND ND 8.4 J ND ND --- ND NC 2L = 20 µg/L (1/11/10) 01-Jun-10 6.3 10.0 --- ND ND 6.3 J ND ND --- ND 29-Dec-10 3.8 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 10.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 --- --- 0.16 J 0.38 J 0.20 J 0.25 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 --- --- ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 --- ND 1.7 B 2.2 B ND ND --- 1.9 J NC 2L = 20 µg/L (1/11/10) 01-Jun-10 1.1 10.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.10 10.0 --- ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 --- 0.18 J ND ND 0.078 J --- ND 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 --- ND ND ND ND ND --- 3.7 J GWPS = 0.28 µg/L (10/23/07) 01-Jun-10 2.7 5.5 --- ND ND ND ND ND --- ND GWPS = 0.2 µg/L (10/1/10) 29-Dec-10 3.0 5.5 --- ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-May-12 5.4 5.5 --- ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 --- --- 0.16 J ND ND 0.76 J --- ND 09-May-13 5.4 5.5 --- ND ND ND ND ND --- ND 07-Nov-13 5.4 5.5 --- --- ND ND ND ND --- ND 05-Jun-14 5.4 5.5 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 --- --- ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 --- ND 1.4 J 37.4 1.5 J 4.3 J --- ND GWPS = 3.5 µg/L (10/23/07) 01-Jun-10 0.4 25.0 --- 1.2 J 3.4 J 84.2 1.4 J 4.8 J --- ND GWPS = 0.3 µg/L (10/1/10) 29-Dec-10 0.20 25.0 --- 1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 --- ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 --- 7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 --- ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 --- --- 2.48 J 2.02 J 2.35 J 4.55 J --- ND 09-May-13 5.0 25.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 25.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 25.0 --- ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 --- --- ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 --- ND 10.1 B 204 15.9 B 24.8 B --- 5.8 .I NC 2L = 1,000 µg/L (1/11/10) 01-Jun-10 2.7 10.0 --- 16.2 13.5 415 8.5 J 22.2 --- ND 29-Dec-10 0.40 10.0 --- 12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 --- ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 --- 16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 --- ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 --- --- 8.61 J 5.20 J 3.98 J 4.65 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- 13.8 10.4 ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 --- --- ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 --- ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10) 01-Nov-11 2.2 100 --- ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 --- ND ND ND ND ND ND ND 07-Nov-12 0.193 100 --- --- ND ND ND ND --- ND 09-May-13 10.0 100 --- ND ND ND ND ND --- 12.0 J 07-Nov-13 10.0 100 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 100 --- ND ND ND ND ND ND ND 20-Nov-14 10.0 100 --- --- ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 --- ND 8.4 0.3 J 0.4 J 0.3 J --- ND NC 2L = 1 µg/L (10/23/07) 01-Jun-10 0.1 1.0 -- ND 2.9 ND ND ND --- ND 29-Dec-10 0.25 1.0 --- ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 --- ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 --- ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 --- ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 --- --- 8.63 0.430 J 0.504 J 0.478 J --- ND 09-May-13 0.25 1.0 --- ND 5.2 0.27 J 0.32 J 0.30 J --- ND 07-Nov-13 0.25 1.0 --- --- 6.9 0.33 J 0.38 J 0.39 J --- ND 05-Jun-14 0.25 1.0 --- ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 --- --- 6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 --- ND ND 0.37 B ND ND --- 0.37 J NC 2L = µg/L 4 (10/23/07) 07-Nov-13 0.26 3.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 3.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 --- --- ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 --- ND 0.5 J 0.6 J ND ND --- ND NC 2L = 50 µg/L (10/23/07) 01-Jun-10 0.1 3.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.23 3.0 --- ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 --- ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 --- ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 --- ND 10.42) J 0.94 B 0.38 B ND ND 0.30 {ND} J 07-Nov-12 0.083 3.00 --- --- 0.468 J 1.30 J 0.476 J ND --- ND 09-May-13 0.23 3.0 --- ND 0.27 J 0.72 J 0.27 J ND --- ND 07-Nov-13 0.23 3.0 --- --- 0.42 J 0.97 J 0.38 J ND --- ND 05-Jun-14 0.23 3.0 --- ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 --- ND ND 0.5 J 0.5 J ND --- 0.1 J NC 2L = 3,000 µg/L (1/11/10) 01-Jun-10 0.1 10.0 --- ND ND 0.4 J ND ND --- ND 29-Dec-10 0.54 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 --- ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 --- ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 --- --- ND ND ND ND --- ND 09-May-13 0.54 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.54 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.54 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 --- --- ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 --- ND 3.8 2.2 2.3 3.1 --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.2 0.9 J ND 1.2 --- ND 29-Dec-10 0.33 1.0 --- ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 --- ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 --- ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 --- ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 --- 5.12 2.93 4.08 3.64 --- ND 09-May-13 0.33 1.0 --- ND 3.6 2.0 3.1 2.3 --- ND 07-Nov-13 0.33 1.0 --- --- 5.4 2.5 4.2 3.2 --- ND 05-Jun-14 0.33 1.0 --- ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 --- --- 4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 --- ND 22.8 1.9 J 4.0 J 2.4 J --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.2 5.0 --- ND 11.0 1.1 J ND 1.2 J --- ND 29-Dec-10 0.32 5.0 --- ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 --- ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 --- ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 --- ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 --- --- 28.1 2.06 J 4.08 J ND --- ND 09-May-13 0.32 5.0 --- ND 18.7 1.4 J 3.0 J 1.6 J --- ND 07-Nov-13 0.32 5.0 --- --- 26.6 1.7 J 4.2 J 2.2 J --- ND 05-Jun-14 0.32 5.0 --- ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 --- --- 21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 --- ND 1.2 0.7 J 1.2 ND --- ND NC 2L = 0.4 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.12 1.0 --- ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 --- ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 --- ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 --- ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.12 1.0 --- ND 0.50 J 0.49 J 0.81 J ND --- ND 07-Nov-13 0.12 1.0 --- --- 0.93 J 0.66 J 1.3 ND --- ND 05-Jun-14 0.12 1.0 --- ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 --- --- 0.68 J 0.47 J 0.81 J ND ND ND 1,1-Dichloroethylene 30-Dec-09 0.1 5.0 --- ND 0.4 J ND ND ND --- ND NC 2L = 7 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.56 5.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-May-12 0.56 5.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 --- --- ND ND ND ND --- ND NC 2L = 350 µg/L (04/01/2013) 09-May-13 0.56 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.56 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.56 5.0 --- ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 --- ND ND ND ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 68.2 11.0 51.0 21.8 --- ND NC 2L = 70 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 23.0 7.6 ND 10.2 --- ND 29-Dec-10 0.19 5.0 --- ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 --- ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 --- ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 --- ND {48.7} 14.2 59.5 22.1 ND 0.21 {ND} J 07-Nov-12 0.103 5.00 --- 59.7 13.6 71.3 26.4 --- ND 09-May-13 0.19 5.0 --- ND 39.9 10.9 49.7 17.4 --- ND 07-Nov-13 0.19 5.0 --- 53.9 10.7 67.1 21.8 --- ND 05-Jun-14 0.19 5.0 --- ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 --- 44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 1.4 J ND 0.2 J 0.2 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 0.6 J ND ND ND --- ND 29-Dec-10 0.49 5.0 --- ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 --- ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 --- ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 --- --- 1.59 J ND ND ND --- ND 09-May-13 0.49 5.0 --- ND 1.1 J ND ND ND --- ND 07-Nov-13 0.49 5.0 --- --- 1.6 J ND ND ND --- ND 05-Jun-14 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 --- --- 1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 --- ND 5.7 0.6 J 1.1 0.7 J --- ND NC 2L = 0.6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.9 ND ND ND --- ND 29-Dec-10 0.27 1.0 --- ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 --- ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 --- ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 --- ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 --- 4.93 ND 1.66 ND --- ND 09-May-13 0.27 1.0 --- ND 3.3 0.51 J 0.96 J 0.45 J --- ND 07-Nov-13 0.27 1.0 --- --- 4.4 0.63 J 1.3 0.57 J --- ND 05-Jun-14 0.27 1.0 --- ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 --- --- 4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 --- ND ND ND 0.4 J ND --- ND NC 2L = 600 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.30 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.30 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.30 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.30 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.30 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 --- --- ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 --- ND 1.2 ND ND ND --- ND NC 2L = 0.7 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- ND 1.4 ND ND ND --- ND 29-Dec-10 0.46 1.0 --- ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 --- ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 --- ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 --- ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 --- --- 2.52 ND ND ND --- ND 09-May-13 0.46 1.0 --- ND 1.9 ND ND ND --- ND 07-Nov-13 0.46 1.0 --- --- 1.8 ND ND ND --- ND 05-Jun-14 0.46 1.0 --- ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 --- --- 1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 --- ND ND ND ND ND 0.76 J ND NC 2L= 600 µg/L (1/11/10) 01-Nov-11 0.26 1.0 -- ND ND ND ND ND ND ND 01-May-12 0.26 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.26 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.26 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 --- --- ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 --- ND 8.0 ND ND 0.2 J --- ND NC 2L = 3 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 6.4 ND ND ND --- ND 29-Dec-10 0.47 1.0 --- ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 --- ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 --- ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 --- ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 --- 9.97 ND ND ND --- ND 09-May-13 0.47 1.0 --- ND 8.4 ND ND ND --- ND 07-Nov-13 0.47 1.0 --- 8.0 ND ND ND --- ND 05-Jun-14 0.47 1.0 --- ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 --- 5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 --- ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10) 01-Nov-11 0.20 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.20 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.20 1.0 --- ND 0.66 J ND ND ND --- ND 07-Nov-13 0.20 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.20 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Analyte Sample Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 --- ND 4.0 2.8 4.1 26.2 --- ND NC 2L = 0.03 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 2.2 3.0 ND 26.7 --- ND 29-Dec-10 0.62 1.0 --- ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 --- ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 --- ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 --- ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 --- --- 7.94 2.73 6.99 29.9 --- ND 09-May-13 0.62 1.0 --- ND 2.8 1.9 4.2 18.6 --- ND 07-Nov-13 0.62 1.0 --- --- 6.3 2.1 6.0 21.9 --- ND 05-Jun-14 0.62 1.0 --- ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 --- --- 5.2 2.1 5.3 16.2 ND ND Xylene (Total) 30-Dec-09 0.3 4.0 --- ND ND ND 3.5 J ND --- ND NC 2L = 500 µg/L (1/11/10) 01-Jun-10 0.3 4.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.66 2.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-May-12 0.66 2.0 --- ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 --- --- ND ND ND ND --- ND 09-May-13 0.66 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.66 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.66 5.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07) 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07) 01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07) 01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 .1 ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07) 01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07) 01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07) 09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 020 25.0 0.67 B 0.37 B 0.62 B 0.26 1 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07) 01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07) 01-Nov-11 2.2 100 ND ND ND 14.6 J 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 1 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND) J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 --- 4600 J 148000 147000 160000 186000 (ug/L) Nov-14 1000.0 5000 --- --- 159000 151000 159000 181000 Sulfate Jun-14 2000 250000 --- 6500 J ND ND ND ND (ug/L) Nov-14 1000 250000 --- --- 1760 J 1730 J 1870 J 1560 1 Nitrogen, Nitrate Jun-14 20.0 1000 --- 72 1 56 J ND ND ND (ug/L) Nov-14 10.0 1000 --- --- 45 J ND ND ND Methane Jun-14 3.3 6.6 --- --- 5530 254 242 515 (ug/L) Nov-14 3.3 6.6 --- --- 4980 159 182 186 Chloride Jun-14 1000 1000 --- 2220 11200 25900 16800 15600 (ug/L) Nov-14 500 1000 --- --- 17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 --- 3100 10600 8300 1500 8200 (ug/L) Nov-14 500 1000 --- --- 2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 --- --- 1.5 1.2 120 3.5 (nM) Nov-14 0.13 0.6 --- --- 2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 --- ND ND ND ND ND (ug/L) Nov-14 2000 2000 --- --- 4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 --- N D ND ND ND ND (ug/L) Nov-14 12500 25000 --- --- ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP points Points Awarded without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >200 C At T > 200C biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product I 1 I 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine I 2 I 2 I 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination I 2 0 I 0 Tetrachloroethene (PCE) --- Material released 0 0 0 Trichloroethene (TCE) --- Material released 0 0 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE) --- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2, --- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC) --- Material released 0 0 0 --- Daughter product of DCE 1 2 2 0 1, 1, 1 -Trichloroethane (TCA) --- Material released 1 0 0 0 1, 1 -Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC) --- Material released 0 0 0 (Methylene Chloride) 1 Daughter product of chloroform 2 0 0 Based on data collected in November 2014. Total Points Awarded : 23 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evid. of Nat. Atten. < 5 inadequate 6-14 limited 15-19 adequate > 20 strong Town of Kernersville Joyce Engineering