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1202_Burke_EastBurke_MSWLF_Nov21GW_FID1646726_20220301
ENR USE ONLY: ❑Paper Report ❑Electronic Data -Email CD data loaded: Yes / No) Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 26 surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. Phone: (336) 323-0092 E-mail: vburbach@labellapc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Rhodiss Road November 1, 2022; Burke Co. - East Burke Landfill Rhodiss, NC 12-02 .0500 February 17, 2022 (resample) Environmental Status: (Check all that apply) [] Initial/Background Monitoring X❑ Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points. dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach. Ph.D., P.G. Sr. Technical Consultant (336) 323-0092 12-D Oak Branch Drive Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 a Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal SEAL 1349LID = MESS LaBeRa Powered by partnership. March 1, 2022 Jaclynne Drummond Compliance Hydrogeologist NC Department of Environmental Quality Division of Waste Management - Solid Waste Section 2090 US Highway 70, Swannanoa, NC 28778 Via Email: jaclynne.drummond@ncdenr.gov RE: Burke County, East Burke Landfill, Permit Number 12-02 November 2021 Semiannual Water Quality Monitoring Report Project No. 2212740 Dear Ms. Drummond: On behalf of Burke County, we are submitting the November 2021 Semiannual Water Quality Monitoring Report in electronic format, as well as a copy of the Environmental Monitoring Form and the laboratory EDDs for the East Burke Landfill, Permit # 12-02. This report completes the second semiannual compliance monitoring event of 2021 as required by the North Carolina Division of Waste Management, Solid Waste Section. If we can provide any additional information, please call me at (336) 323-0092. Respectfully submitted, LaBella Associates Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure cc: Mark Delehant, Burke County 12-D Oak Branch Drive I Greensboro, NC 27407 I p (336) 323-0092 www.LabeLLapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 4 BanxE � �rH CA Submitted by: LaBella Associates (Joyce Engineering) 12-D Oak Branch Drive Greensboro, NC 27407 (336) 323-0092 NC License No. C-0782 LaBeRa Powered by partnership. NOVEMBER 2021 SEMIANNUAL WATER QUALITY MONITORING REPORT EAST BURKE LANDFILL Permit No. 12-02 MARCH 2O22 PROJECT NO. 2212740 November 2021 Semiannual Water Quality Monitoring Report East Burke Landfill, Permit No. 12-02 Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................1 1.1 Site Information................................................................................................................1 1.2 Regulatory Status.............................................................................................................1 2.0 FACILITY MONITORING PROGRAM...................................................................................1 2.1 Groundwater Monitoring Program...................................................................................1 2.2 Surface Water Monitoring Program.................................................................................2 3.0 November 2021 SEMIANNUAL SAMPLING EVENT.........................................................2 3.1 Field Work.........................................................................................................................2 3.2 Laboratory Analysis and Quality Control..........................................................................3 4.0 HYDROGEOLOGY..............................................................................................................3 5.0 DATA ANALYSIS................................................................................................................4 5.1 Analytical Results and Comparison to Standards...........................................................5 5.1.1 Groundwater.............................................................................................................5 5.1.2 Surface Water..........................................................................................................5 6.0 CONCLUSIONS..................................................................................................................6 7.0 REFERENCES....................................................................................................................7 November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 November 2021 Semiannual Water Quality Monitoring Report East Burke Landfill, Permit No. 12-02 Burke County, North Carolina TABLE OF CONTENTS (CONTINUED) Tables Table 1 Groundwater Elevations (November 2021) Table 2 Hydraulic Gradients and Velocities (November 2021) Table 3 Detected Constituents (November 2021) Table 4 Exceedances of Standards (November 2021) Table 5 Field Parameters (November 2021) Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map (November 2021) Appendix Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Surface Water Constituents Table A2-4 Historical Groundwater Field Parameters Table A2-5 Historical Surface Water Field Parameters November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 1.0 INTRODUCTION 1.1 Site Information The East Burke Landfill, Permit No. 12-02, is located in Burke County, North Carolina as shown on Figure 1. The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1972 and 1988 and has been closed to the reception of waste since 1988. 1.2 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors' groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. In March 1995, the North Carolina Department of Environment and Natural Resources (NCDENR), now the Department of Environmental Quality (NCDEQ), requested that the facility perform additional site contamination investigation activities due to the quantified detections of organic constituents in the groundwater on site. In response to this request a Water Quality Assessment Plan for the East Burke Landfill was submitted to the Solid Waste Section (SWS) in September of 1995. Updates on Groundwater Assessment Activities were submitted to NCDENR SWS in June 2003 and August 2003. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the East Burke Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3, and AMW-1. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored for the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Monitoring Date Monitoring Total Depth Lithology of Well Installed Classification Program from TOC Screened Interval (feet) MW-1 Unknown Background .0600 50.55 Bedrock (Est.) MW-2 Unknown Compliance .0600 71.05 Bedrock (Est.) MW-3 Unknown Compliance .0600 32.50 Saprolite (Est.) AMW-1 4/01/ 2003 Compliance .0600 7.25 Saprolite November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 1 2.2 Surface Water Monitoring Program Surface water monitoring at the East Burke Landfill is completed in accordance with the monitoring requirements of Rule .0600 of NCSWMR. Surface water samples are collected semiannually and are analyzed for the NC Appendix I constituents plus 1,4-dioxane. The surface water monitoring network consists of two sampling points: SW-1 located upstream from the sediment pond, and SW-2 located downstream from MW-3 and AMW-1. The approximate locations of the sampling points are shown on Drawing 1. Surface water from the site flows to Rhodhiss Lake, just upstream of the dam. Rhodhiss Lake is Classified and Water Supply IV. Surface Point Classification Monitoring Program SW-1 SW-2 Compliance Compliance .0600 .0600 3.0 November 2021 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On November 1, 2021, personnel from LaBella Associates visited the East Burke Landfill to obtain water levels to the nearest 0.01 foot, purge and sample monitoring wells MW-1, MW-2, MW-3, and AMW-1, and sample surface monitoring point SW-2. Surface water monitoring point SW-1 was dry and was not sampled during the November 2021 event. Due to unusual detections of cobalt and vanadium, well AME-1 was resampled on February 17, 2022. Monitoring wells were purged and sampled using either disposable bailers or a 12-V submersible pump during the November 2021 sampling event. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site logbook prior to purging, after each purge volume, and during sampling. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers or the tubing for the 12-V submersible pump in the provided laboratory containers within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a laboratory -provided cooler. Copies of the field data logs are provided in Appendix 1. November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 2 Surface water from monitoring point SW-2 was collected directly from stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity and recorded in the field data log. Immediately after collection, the samples were placed on ice in a laboratory -provided cooler. Copies of the field data logs are presented in Appendix 1. 3.2 Laboratory Analysis and Quality Control Pace Analytical Services, Inc. of Huntersville, North Carolina received the groundwater and surface water samples on November 3, 2021, under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. The samples were received by the laboratory in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the East Burke Landfill, a Field Blank was collected by LaBella Associates personnel as part of the November 2021 sampling event. A Trip Blank was also prepared by the laboratory to accompany the volatile samples during shipment. The Field Blank was analyzed for the NC Appendix I list compounds and 1,4-dioxane while the Trip Blank was analyzed for NC Appendix I VOCs and 1,4-dioxane. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Correct analyte lists; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC2L (NC2L) Groundwater Standards, NC Interim Maximum Allowable Concentrations (IMACs), 15A NCAC213 (NC2B) Surface Water Standards, or NC In -Stream Target Values (ISTV); and • Detections that are above historical levels. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 3 Groundwater discharges into an unnamed tributary to Lake Rhodhiss, northeast of the landfill. A groundwater potentiometric surface map, developed from static water level data obtained on November 1, 2021, is presented as Drawing 1. Depth to groundwater was measured in the compliance monitoring wells at the site prior to sampling. The groundwater elevations were calculated relative to the surveyed measuring point (top of casing) for each monitoring well to ±0.01 ft. The groundwater elevations are summarized in Table 1 for the November 2021 sampling event. Historical groundwater elevations are summarized in Appendix 2, Table A2-1. Groundwater flow beneath the waste management unit is primarily to the northeast. Estimated horizontal groundwater gradients (i) from the November 2021 groundwater elevations are presented in Table 2. The horizontal gradient (i) calculated for the facility from the data was 0.0657. Linear groundwater flow velocities (V) was estimated using the following modified Darcy equation: V = Ki/ne, where: V = average linear velocity; K = hydraulic conductivity; i = horizontal hydraulic gradient; and ne = effective porosity. Hydraulic conductivity (K) was estimated at 3.28 feet/day based on slug tests from a nearby site (Johns River Landfill). An effective porosity (ne) of 20% was estimated based on typical values for piedmont aquifers. The estimated linear groundwater flow velocity under the facility is 393 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplified assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known preferred pathways or barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. 5.0 DATA ANALYSIS The laboratory results from the November 2021 sampling event were received on November 17, 2021, for all monitoring wells (MW-1, MW-2, MW-3, and AMW-1) and one surface water monitoring location (SW-2). All analytical results can be found in Appendix November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 4 1. Table 3 summarizes the constituents detected at concentrations above the MDL in all monitoring well and surface water samples for the November 2021 sampling event. Constituents confirmed in exceedance of the appropriate standards are summarized in Table 4. Field Parameters for the November 2021 sampling event are summarized in Table 5. 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Analytical results from monitoring wells were compared directly to the North Carolina Groundwater Standards found in 15A NCAC 02L.0202 (NC2L Standards) or the NC Interim Maximum Allowable Concentrations (IMACs) for constituents with no listed NC2L Standard. Note that estimated concentrations below the Method Reporting Limit (MRL) are not considered exceedances of the standard, even if the estimated value is higher than the standard. Constituents detected in groundwater samples during the November 2021 sampling event are listed in Table 3 and exceedances of the NC2L or IMAC are presented in Table 4. Historically detected constituents in groundwater can be found in Appendix 2, Table A2-2 and historical groundwater field parameters can be found in Appendix 2, Table A2-4. The inorganic constituents detected at quantified concentrations above the MRL during the November 2021 event include: arsenic (MW-2); barium (MW-1, MW-2, MW-3, AMW-1); cobalt (MW-1, MW-2, MW-3, AMW-1); nickel (MW-2, MW-3); thallium (MW-3), and vanadium (MW-1, MW-2, MW-3, AMW-1). The inorganic constituents detected at quantified concentrations in exceedance of their respective NC21- or IMAC include: arsenic (MW-2); cobalt (MW-1, MW-2, MW-3, AMW-1); thallium (MW-3); and vanadium (MW-1, MW-2, MW-3, AMW-1). Arsenic was detected in the associated method blank; therefore, the detection in MW-2 may have been due to laboratory contamination. The exceedances for cobalt and vanadium in AMW-1 were refuted by the November 17, 2022 resampling event results (see Table 3). The organic constituents detected at quantified concentrations above the MRL include: cis-1,2-dichloroethene (MW-2, MW-3, AMW-1); 1,4-dichlorobenzene (MW-2, MW-3, AMW-1); and 1,4-dioxane (MW-2, MW-3). The only organic constituent detected at a quantified concentration in exceedance of the NC21- or IMAC was 1,4-dioxane (MW-3). In general, these detections are consistent with historical data for the inorganic and organic constituents (Appendix 2, Table A2-2) except for the first exceedance of cobalt in AMW-1 since June 2009 and an increase of vanadium in all monitoring wells. 5.1.2 Surface Water Analytical results for surface water samples were compared directly to either the Water Supply, Freshwater Aquatic Life, or Fish Consumption Surface Water Standards November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 5 (whichever was lower) found in 15A NCAC .02B (NC2B Standards). For metals which have hardness -dependent NC2B Standards, the hardness of the sample collected was used to calculate the NC2B standard. For constituents which have NC2B standards for both chronic and acute exposure, the chronic exposure standard was used. For constituents with no NC213 standards, the results were compared to either the NC In - Stream Target Value (ISTV) or the EPA Nationally Recommended Water Quality Standard (NRWQS). Note that estimated concentrations below the MRL are not considered exceedances of the standard, even if the estimated value is greater than the standard. During the November 2021 sampling event, the constituents detected at quantified concentrations above the MRL include: barium (SW-2); cobalt (SW-2); nickel (SW-2); vanadium (SW-2); cis-1,2-dichloroethene (SW-2); and 1,4-dioxane (SW-2). The only constituents detected above the NC2B or ISTV were cobalt (SW-2) and 1,4-dioxane (SW-2). Historical surface water data can be found in Appendix 2, Table A2-3. Historical surface water field parameters can be found in Appendix 2, Table A2-5. 6.0 CONCLUSIONS Cobalt was detected in exceedance of the Groundwater Protection Standard in monitoring wells MW- 1, MW-2, MW-3, and AMW-1 during the November 2021 sampling event; however, the exceedance cobalt in AMW-1 was refuted by the November 2022 resampling event. Cobalt was also detected in surface water sample SW-1 in exceedance of the ISTV. Arsenic was detected in monitoring well MW-2 in exceedance of the NC2L; however, arsenic was also detected in the associated method blank; therefore, this could be due to laboratory contamination; however, it is consistent with historical results. Thallium was detected in exceedance in MW-3, and vanadium was in exceedance in all monitoring wells; however, the exceedance vanadium in AMW-1 was refuted by the November 2022 resampling event. 1,4-Dioxane was detected in exceedance of the NC21- in monitoring well MW-3 and in surface water sample SW-1 in exceedance of the ISTV. According to historical groundwater data, inorganic and organic constituents detected above the NC21- or IMAC in groundwater samples collected during the November 2021 sampling event are consistent with previous events except for the first exceedance of cobalt in AMW-1 since June 2009 and an increase of vanadium in all monitoring wells. The surface water exceedance for cobalt in SW-1 was consistent with historical data. Based on the results of this groundwater monitoring event, the groundwater monitoring network remains adequate to monitor groundwater at the site. The next semiannual sampling event is tentatively scheduled for May 2022. November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 6 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, P. 119 November 2021 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - East Burke Landfill, Permit No. 12-02 March 2022 7 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 Groundwater Elevations (October 2021) Hydraulic Gradients and Velocities (October 2021) Detected Constituents (October 2021) Exceedances of Standards (October 2021) Field Parameters (October 2021) TABLE 1: Groundwater Elevations (November 2021) Depth to Groundwater TOC Elevation Well Depth Location Groundwater Lithology Elevation (Ft AMSL) (Ft BTOC) (Ft-BTOC) (Ft-AMSL) MW-1 1147 37.55 Saprolite 50.58 1109.45 MW-2 1096.5 57.13 Saprolite 74.80 1039.37 MW-3 1039 10.68 Bedrock 32.65 1028.32 AMW-1 1021 4.91 Bedrock 7.30 1016.09 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level Water levels measured on November 1, 2021. Burke County- East Burke Landfill Permit No. 12-02 Labella Associates TABLE 2: Hydraulic Gradients and Velocities (November 2021) Date of Water Levels: November 1, 2021 HYDRAULIC LINEAR GRADIENT FLOW LINE GROUNDWATER HORIZONTAL EFFECTIVE FLOW CONDUCTIVITY VELOCITY CALCULATION LENGTH ELEVATION GRADIENT POROSITY DIRECTION K V SEGMENT (feet) (feet) i n e (feet/day) (feet/year) 1100 11 1,217 NE 0.0657 3.28 0.20 393 1020 Notes: The mean of K estimates from individual well slug tests from the Burke County John's River Facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln e ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Burke County- East Burke Landfill Permit No. 12-02 LaBella Associates TABLE 3: Detected Constituents (November 2021) SAMPLE ID PARAMETER RESULT METHOD MDL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater Arsenic 9.4 J EPA 6010D 4.7 10 10 NC 2L pg/L Barium 60.3 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 8.5 EPA 6010D 3.6 5 1 IMAC pg/L MW-1 Nickel 4.5 J EPA 6010D 3.5 5 100 NC 2L pg/L 11/1/2021 Thallium 0.095 J EPA 6020B 0.05 0.47 0.2 IMAC pg/L Vanadium 5.4 EPA 6010D 3.9 5 0.3 IMAC pg/L cis-1,2-Dichloroethene 0.56 J EPA 8260D 0.38 1 70 NC 2L pg/L Arsenic 19.7 B EPA 6010D 4.7 10 10 NC 2L pg/L Barium 39.1 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 58.7 EPA 6010D 3.6 5 1 IMAC pg/L Nickel 42.2 EPA 6010D 3.5 5 100 NC 2L pg/L Thallium 0.15 J EPA 6020B 0.05 0.47 0.2 IMAC pg/L Vanadium 22.2 EPA 6010D 3.9 5 0.3 IMAC pg/L MW 2 11/1/2021 1,4-Dichlorobenzene 3.7 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 2.6 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L Benzene 0.96 J EPA 8260D 0.34 1 1 NC 2L pg/L Chlorobenzene 0.33 J EPA 8260D 0.28 1 50 NC 2L pg/L cis-1,2-Dichloroethene 17.2 EPA 8260D 0.38 1 70 NC 2L pg/L Vinyl chloride 0.51 J EPA 8260D 0.39 1 0.03 NC 2L pg/L Antimony 3.6 J EPA 6010D 3 5 1 IMAC pg/L Barium 130 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 32.1 EPA 6010D 3.6 5 1 IMAC pg/L Nickel 12.7 EPA 6010D 3.5 5 100 NC 2L pg/L Thallium 1.1 EPA 6020E 0.05 0.47 0.2 IMAC pg/L Vanadium 19.2 EPA 6010D 3.9 5 0.3 IMAC pg/L MW-3 11/1/2021 1,1-Dichloroethane 0.47 J EPA 8260D 0.37 1 6 NC 2L pg/L 1,4-Dichlorobenzene 3.7 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 45.6 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L Benzene 0.64 J EPA 8260D 0.34 1 1 NC 2L pg/L Chlorobenzene 0.69 J EPA 8260D 0.28 1 50 NC 2L pg/L cis-1,2-Dichloroethene 10.8 EPA 8260D 0.38 1 70 NC 2L pg/L Barium 63.5 EPA 6010D 3.5 5 700 NC 2L pg/L Cadmium 0.49 J EPA 6010D 0.4 1 2 NC 2L pg/L Cobalt 6.6 EPA 6010D 3.6 5 1 IMAC pg/L AMW-1 Vanadium 13.1 EPA 6010D 3.9 5 0.3 IMAC pg/L 11/1/2021 1,4-Dichlorobenzene 1.9 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 1.4 J EPA 8260D Mod. 0.86 2 3 NC 2L pg/L cis-1,2-Dichloroethene 5.0 EPA 8260D 0.38 1 70 NC 2L pg/L AMW-1 Cobalt 3.8 J EPA 6010D 3.6 5 1 IMAC pg/L 2/17/2022 Resample Vanadium ND EPA 6010D 3.9 5 0.3 IMAC pg/L Surface Water Arsenic 6.9 JB EPA 6010D 4.7 10 36 NC213 pg/L Barium 53.6 EPA 6010D 3.5 5 21000 ISTV pg/L Cobalt 12.0 EPA 6010D 3.6 5 1.6 ISTV pg/L Nickel 5.5 EPA 6010D 3.5 5 16.10 NC2B* pg/L SW-2 Thallium 0.12 J EPA 6020E 0.05 0.47 2 ISTV pg/L 11/1/2021 Vanadium 10.8 EPA 6010D 3.9 5 ns ns pg/L 1,4-Dichlorobenzene 0.42 J EPA 8260D 0.33 1 100 ISTV pg/L 1,4-Dioxane (p-Dioxane) 16.5 EPA 8260D Mod. 0.86 2 0.35 ISTV pg/L cis-1,2-Dichloroethene 1.0 EPA 8260D 0.38 1 720 ISTV pg/L Notes: MDL= Method Detection Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 MRL = Method Reporting limit IMAC = Interim Maximum Allowable Concentration ND = Not detected above the MDL NC2B = NC Surface Water Standard from 15A NCAC 2B J = Estimated concentration below the MRL. NC2B* = Hardness -dependant NC2B B = Blank -Qualified (detected in field, trip, or method blank). ISTV = In -Stream Target Value Bold results are exceedances of the applicable standards. Burke Co. - East Burke Landfill LaBella Associates Permit # 12-02 TABLE 4: Exceedances of Standards (November 2021) SAMPLE ID PARAMETER RESULT METHOD MOIL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater Cobalt 8.5 EPA 6010D 3.6 5 1 IMAC ug/L M W-1 11/1/2021 Vanadium 5.4 EPA 6010D 3.9 5 0.3 IMAC pg/L Arsenic 19.7 B EPA 6010D 4.7 10 10 NC 2L pg/L MW-2 Cobalt 58.7 EPA 6010D 3.6 5 1 IMAC pg/L 11/1/2021 Vanadium 22.2 EPA 6010D 3.9 5 0.3 IMAC pg/L Cobalt 32.1 EPA 6010D 3.6 5 1 IMAC pg/L Thallium 1.1 EPA 6020E 0.05 0.47 0.2 IMAC pg/L MW-3 11/1/2021 Vanadium 19.2 EPA 6010D 3.9 5 0.3 IMAC pg/L 1,4-Dioxane (p-Dioxane) 45.6 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L Cobalt* 6.6 EPA 6010D 3.6 5 1 IMAC pg/L AMW-1 11/1/2021 Vanadium* 13.1 EPA 6010D 3.9 5 0.3 IMAC pg/L Surface Water SW-2 Cobalt 12 EPA 6010D 1 3.6 5 1.6 V pg/L 11/1/2021 1,4-Dioxane (p-Dioxane) 16.5 EPA 8260D Mod. 0.86 2 0.35 EV ug/L Notes: MDL= Method Detection Limit MRL = Method Reporting limit ND = Not detected above the MDL NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 IMAC = Interim Maximum Allowable Concentration NC213 = NC Surface Water Standard from 15A NCAC 2B J = Estimated concentration below the MRL. NC2B* = Hardness -dependant NC2B B = Blank -Qualified (detected in field, trip, or method blank). ISTV = In -Stream Target Value * Cobalt and vanadium exceedances in AMW-1 were refuted by the results of a resampling event - see Table 4. Burke Co. - East Burke Landfill La Bella Associates Permit # 12-02 TABLE 5: Field Parameters (November 2021) Parameter Units Collect Date GW Upgradient GW Downgradient Surface Water MW-1 MW-2 MW-3 AMW-1 SW-1 SW-2 pH S.U. 11/1/2021 5.14 5.81 4.43 5.77 -- 5.85 Temperature °C 11/1/2021 17.0 16.1 16.5 16.0 -- 13.8 Conductivity pS/cm 11/1/2021 119.9 304.1 355.4 183.7 -- 211.6 Dissolved Oxygen mg/L 11/1/2021 0.74 0.86 1.52 4.58 -- 7.04 Oxidation Reduction Potential mV 11/1/2021 104.8 27.5 105.9 62.7 -- 89.2 Turbidity NTU 11/1/2021 1.05 0.86 0.91 30.4 -- 5.98 Static Water Level Ft 11/1/2021 37.55 57.13 10.68 4.91 -- Well Depth Ft 11/1/2021 50.58 74.80 32.65 7.3 -- -- Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microsemens per cm NTU = Nephelometric Turbidity Units Ft = feet Burke County -East Burke LaBella Associates Permit No. 12-02 FIGURE Figure 1 Site Location Map '• ill: • •s ---SLAKE_ ,- W �:,�_ }• h. Raw, -- ' 1i '( [�� f Ijjj��`�>•— ` I +1 � �Rt,udhiss _�i ��� � ...: •'.. - ., AM EAST BURKE,- t� t Area r _ 1. PROPvF,RT.Y j� � � .i ice` � ! '! •rl•r..,.; -� :{' ,�.- "�irr .*�:.-'-�`. I rr /^ r•j `'� �`w r,�ticC :.✓ I;,. •i- �. 1 C„nunundy _ E'r' p7C7hlI'' S • 1\ I � IV_—''„ 3� I. • 4-! ..'• . >,t „ +"ter J `r `1 �� �:� r. g 6 •. S GRAPHIC SCAL �., •0 1000 2000 4000 (FEET) - ISSUED FOR: 0.3 LaBe«a GROUNDWATER MONITORING REPORT Powered by partnership, DRAWING NAME: DRAWN BY: DATE: PROJECT NO.: SITE LOCATION MAP RWH 02/27/19 2192621 2211 WEST MEADOWVIEW ROAD GREENSBORO, N.C. 27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: EAST BURKE LANDFILL Figure 1 labellapc.com © 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\DWge\D—I.q.—Current\BURKE\GW EVENT MAPS\, SITE LOCATION MAP EAST BURKE.dwg DRAWING Drawing 1 Groundwater Potentiometric Surface Map (October 2021) 1p60 \ / / —1080 MW-2 103 0i \ I 1016.09 / I 0 �� \ W-2 —\ % \ MW-3 I I I / 10f8 10 0 — o, \ J� �040 �09 I j Rtioo �yjss I IELD DETERMINED \ E OF WASTE (' 1 10b( M W1 r0� I �/0 O �� � �� 1 \ q0 1109.4�5 O �c99 0 ' f SR 2300 / I I I I / G P s / \ R �611 1 _ FRIENDSHIP METHODIST CHURCH LEGEND — 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING 20' TOPOGRAPHIC CONTOUR 1 020 — — GROUNDWATER SURFACE CONTOUR [FEET ABOVE MEAN SEA LEVEL (AMSL)] PROPERTY LINE GROUNDWATER FLOW PATHWAY USED TO CALCULATE HYDRAULIC GRADIENT EXISTING ROAD APPROXIMATE LIMITS OF WASTE CENTERLINE OF STREAM - MW-1 COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC ELEV WATER LEVEL ELEVATION (FEET AMSL) O SW-2 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION OSEGMENT USED FOR GRADIENT CALCULATION 1 FLOW PATH LENGTH 11 1,217 LF NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. 3. STATIC WATER LEVELS WERE MEASURED ON NOVEMBER 1, 2021. 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. GRAPHIC SCALE 0 150 300 600 (FEET) LaBeRa Powered by partnership. 2211 WEST MEADOWVIEW, SUITE 101 GREENSBORO, INC 2-07 (336) 323-0092 labellapc.com T T T L_ T T T L- 1 C 2021 LeBellzh—metes EAST BURKE LANDFILL BURKE COUNTY, NORTH CAROLINA N0: DATE'. DESCRIPTION: Revisions PROJECT NUMBER: 2212740.00 DRAWN W. RH REVIEWED BY: EW ISSUED FOR: GROUNDWATER REPORT DATE: 01/21/22 DRAWING NAME: PERMIT NO. 12-02 GROUNDWATER POTENTIOMETRIC SURFACE MAP NOVEMBER 1, 2021 DRAWING NUMBER: 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data LaBetLa DATE: 1,/f Powpie,- hy_pottnerahip GROUND WATER SAMPLING LOG Project Name: L Y-eCo— fA;4-60(-ke Project No. /Task No.: ;20- Pr?(/y/00 WeIIID: Mw--1 Well Location: Well Diameter: Sampler(s)j,.Wdgy, - S Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches 3' ` , bS feet S Q, 5-9 feet n 3 feet [DTB-DTW] �- gallons = g• J gallons = 2S. gallons 5---gallons Purged with: Bailer CPumo Other: Sampled with: Bailer P�umo� Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (us/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials D 105-9 16.E 5-.H q Ig6.q S jp 60,s qq. $ fA-) I 9.8� 1`4.0 Illo 16.E s•y? 1�2.� o.s'G�t�' I, +� �' �51 ��` 111 S I`�. o ►Y +19 .� G,� y IoLl.B I , v.S 4?�J Date of sample: �12J� Before Sampling Comments (weather conditions, odor, color, silt, etc.): "17 bAltvS Signature: ✓ Date: 10121 QA/QC Sign Off: Date: 11 - Z Q., LaBelLa DATE: I i/I 1:2 1 a-,rtner,hip GROUND WATER SAMPLING LOG / Project Name: Q0,(Ke Project No. /Task No.: Well ID: rmt Sampler(s): S- 0c qL+_, K AS S Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled wit[ Depth to Water before Sampling: 2 inches Sq - I `3 feet -4 y $b feet 1 '7' 6 feet [DTB-DTW] gallons 11'-!�>rallons = 3y gallons gallons feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials � d9ss 16. `I 6.02 �,� �, ate- 3y,3 ►`�► f� 11. S jet 16. -:3j- e3 i y .'� p .--3-F 36.q 33. f- OP 3 i 3�1 S 1n'*21 0.► 6.$6 o.8� Date of sample: 1 I 11P I Before Sampling -SC M "J Comments (weather conditions, odor, color, silt, etc.): s 0' s .ten n q `�- 60+4-� Signature: 'e_ Date: QA/QC Sign Off: Date: _ rIIq/ 2i DATE: � j 1:21 LaBetLa "Ov;eredby Paltnt,:.., : GROUND WATER SAMPLING LOG Project Name: �v�Y�e.Cc?. _ ���ke Project No./Task No.:as Well ID: mW _3 Sampler(s): f, �'nQO-.'i , F4os Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt Depth to Water before Sampling: 2 inches Ea . 66 feet 3a.6S feet 91, q 7� feet [DTB-DTW] _ ®lam gallons lq,, gallons _ `7/qQ, g gallons �?,9 gallons feet Gallons Time Temp (°C) pH Cond. (US/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials o, f, qq ��u, ilSs ffo.5 y,ga 3s�t. i 1 • I !a`�,s 0,T-6 `�a•� laoe 16.5- y,�►3 3s-s.H 1, lo$q a:ql � Date of sample: I /' 21 Before Sampling :5a(n (x_f_ Comments (weather conditions, odor, color, silt, etc.): �0+4t 5Z`S &;nAl-I Signature:- Date: % Iq Ili QA/QC Sign Off: f Date: f Z DATE: I I / ) J-2 LaBetta 7`oweiedbypartnership GROUND WATER SAMPLING LOG Project Name: N' eke. C . Boc-y e Project No. /Task No.: '.-I'D 1'2�yO ` o2 Well ID: � fnw' Sampler(s):q�� Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): ,�/ 2 inches -I ,ql feet •3 feet Q ' 3q feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 =J gallons Actual Amount Purged/Bailed: 0.2 gallons Purged with: ,� Pump Other: Sampled with: Bafle-E-1� Pump Other: Depth to Water before Sampling: '57, q feet Gallons Time Temp (°C) pH Cond. (us/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials Date of sample: Before Sampling Comments (weather conditions, odor, color, silt, etc.): S-0`S Z��_ FJ(2�12q() Signature: PI`" Date: fi1q/2 QA/QC Sign Off: Date: // -9 -21 LaBetta DATE: 11 /) 121 SURFACE WATER MONITORING LOG Project Name: 6'KYc �' r s{' �� Project/Task No.: Qal �' o Surface Point Sampler(s):_ Wngi��, K. Location: Field Parameters: Time of Sampling: pH: Temperature: (° C) Conductivity: (US/CM) Turbidity: (ntu) Dissolved Oxygen (mg/L) Oxidation -Reduction Potential (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): n J Summary/Sketch of Sampling Location Q Signature: � Date: X-2 QA/QC Sign 0 i Date: DATE:11/1 /QI LaBeLta SURFACE WATER MONITORING LOG Project Name: ke (0, — Cis}' &)Cke Project/Task No.: a a 1'2-"0 00 Surface Point ID: Sw'�2 Sampler(s):C-Priq� Location: Field Parameters: Time of Sampling: pH: Temperature: �� (0 C) Conductivity: (US/cm) Turbidity: ® s-q (ntu) Dissolved Oxygen (mg/L) Oxidation -Reduction Potential S 9• (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): Summary/Sketch of Sampling Location e i F16,J s� 6 �a� • S� Signature: 1��`�"� Date: QA/QC Sign Off: Date: - 2 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 17, 2021 Mr. Van Burbach Joyce Engineering -Greensboro 12-D Oak Branch Drive Greensboro, NC 27407 RE: Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on November 03, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Kandice Estes, Labella Associates Miguel Vazquez, Joyce Engineering Elina Wright, LaBella Associates, D.P.C. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 35 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Lab ID Sample ID Matrix Date Collected Date Received 92570492001 1202-MW1 Water 11/01/2111:15 11/03/21 08:25 92570492002 1202-MW2 Water 11/01/2110:21 11/03/21 08:25 92570492003 1202-MW3 Water 11/01/21 12:00 11/03/21 08:25 92570492004 1202-AMW1 Water 11/01/2112:30 11/03/21 08:25 92570492005 1202-SW2 Water 11/01/2112:27 11/03/21 08:25 92570492006 FIELD BLANK Water 11/01/21 12:40 11/03/21 08:25 92570492007 TRIP BLANK Water 11/01/21 00:00 11/03/21 08:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: BURKE CO - EAST BURKE LF 92570492 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92570492001 1202-MW1 EPA 601 OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570492002 1202-MW2 EPA 601 OD CBV 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570492003 1202-MW3 EPA 601 OD CBV 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570492004 1202-AMW1 EPA 601 OD CBV 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570492005 1202-SW2 EPA 601 OD CBV 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570492006 FIELD BLANK EPA 601 OD CBV 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570492007 TRIP BLANK EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Lab Sample ID Method Client Sample ID Parameters 92570492001 1202-MW1 EPA 601 OD Arsenic EPA 601 OD Barium EPA 601 OD Cobalt EPA 601 OD Nickel EPA 601 OD Vanadium EPA 6020B Thallium EPA 8260D cis-1,2-Dichloroethene 92570492002 1202-MW2 EPA 601 OD Arsenic EPA 601 OD Barium EPA 601 OD Cobalt EPA 601 OD Nickel EPA 601 OD Vanadium EPA 6020B Thallium EPA 8260D Benzene EPA 8260D Chlorobenzene EPA 8260D 1,4-Dichlorobenzene EPA 8260D cis-1,2-Dichloroethene EPA 8260D Vinyl chloride EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92570492003 1202-MW3 EPA 601 OD Antimony EPA 601 OD Barium EPA 601 OD Cobalt EPA 601 OD Nickel EPA 601 OD Vanadium EPA 6020B Thallium EPA 8260D Benzene EPA 8260D Chlorobenzene EPA 8260D 1,4-Dichlorobenzene EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92570492004 1202-AMW1 EPA 601 OD Barium EPA 601 OD Cadmium EPA 601 OD Cobalt EPA 601 OD Vanadium EPA 8260D 1,4-Dichlorobenzene EPA 8260D cis-1,2-Dichloroethene EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92570492005 1202-SW2 EPA 601 OD Arsenic EPA 601 OD Barium EPA 601 OD Cobalt SUMMARY OF DETECTION Result Units Report Limit Analyzed 9AJ ug/L 10.0 11/17/2107:21 60.3 ug/L 5.0 11/17/2107:21 8.5 ug/L 5.0 11/17/2107:21 4.5J ug/L 5.0 11/17/2107:21 5.4 ug/L 5.0 11/17/2107:21 0.095J ug/L 0.47 11/09/2100:03 0.56J ug/L 1.0 11/08/2117:04 19.7 ug/L 10.0 11/16/2106:05 B 39.1 ug/L 5.0 11/16/2106:05 58.7 ug/L 5.0 11/16/2106:05 42.2 ug/L 5.0 11/16/2106:05 22.2 ug/L 5.0 11/16/2106:05 0.151 ug/L 0.47 11/09/2100:07 0.96J ug/L 1.0 11/08/2117:21 0.33J ug/L 1.0 11/08/2117:21 3.7 ug/L 1.0 11/08/2117:21 17.2 ug/L 1.0 11/08/2117:21 0.51 J ug/L 1.0 11 /08/21 17:21 2.6 ug/L 2.0 11/04/2120:40 3.6J ug/L 5.0 11/16/2106:18 130 ug/L 5.0 11/16/2106:18 32.1 ug/L 5.0 11/16/2106:18 12.7 ug/L 5.0 11/16/2106:18 19.2 ug/L 5.0 11/16/2106:18 1.1 ug/L 0.47 11/09/2100:10 0.64J ug/L 1.0 11/08/2117:39 0.69J ug/L 1.0 11/08/2117:39 3.7 ug/L 1.0 11/08/2117:39 0.47J ug/L 1.0 11/08/2117:39 10.8 ug/L 1.0 11/08/2117:39 45.6 ug/L 2.0 11/04/2121:38 63.5 ug/L 5.0 11/16/2106:21 0.49J ug/L 1.0 11/16/2106:21 6.6 ug/L 5.0 11/16/2106:21 13.1 ug/L 5.0 11/16/2106:21 1.9 ug/L 1.0 11/08/2117:56 5.0 ug/L 1.0 11/08/2117:56 1AJ ug/L 2.0 11/04/2120:59 6.9J ug/L 10.0 11/16/2106:37 B 53.6 ug/L 5.0 11/16/2106:37 12.0 ug/L 5.0 11/16/2106:37 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: BURKE CO - EAST BURKE LF 92570492 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92570492005 1202-SW2 EPA 601OD Nickel 5.5 ug/L 5.0 11/16/2106:37 EPA 601OD Vanadium 10.8 ug/L 5.0 11/16/2106:37 EPA6020B Thallium 0.12J ug/L 0.47 11/09/2100:17 EPA8260D 1,4-Dichlorobenzene 0.42J ug/L 1.0 11/08/2115:54 EPA8260D cis-1,2-Dichloroethene 1.0 ug/L 1.0 11/08/2115:54 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 16.5 ug/L 2.0 11/04/21 21:18 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-MW1 Lab ID: 92570492001 Collected: 11/01/21 11:15 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:21 7440-36-0 Arsenic 9.4J ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:21 7440-38-2 Barium 60.3 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:21 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:21 7440-47-3 Cobalt 8.5 ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:21 7439-92-1 Nickel 4.5.1 ug/L 5.0 3.5 1 11/11/21 10:54 11/17/21 07:21 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:21 7440-22-4 Vanadium 5.4 ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.095J ug/L 0.47 0.050 1 11/08/2111:14 11/09/2100:03 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 17:04 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 17:04 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 17:04 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 17:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 17:04 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 17:04 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 17:04 74-83-9 IH 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 17:04 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 17:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 17:04 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 17:04 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 17:04 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 17:04 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 17:04 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 17:04 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 17:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 17:04 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 17:04 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 17:04 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 17:04 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 17:04 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 17:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 17:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 17:04 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-MW1 Lab ID: 92570492001 Collected: 11/01/21 11:15 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.56J ug/L 1.0 0.38 1 11/08/2117:04 156-59-2 ND ug/L 1.0 0.40 1 11/08/2117:04 156-60-5 ND ug/L 1.0 0.36 1 11/08/2117:04 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 17:04 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 17:04 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 17:04 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 17:04 591-78-6 ND ug/L 20.0 9.7 1 11/08/2117:04 74-88-4 ND ug/L 5.0 2.0 1 11/08/2117:04 75-09-2 ND ug/L 5.0 2.7 1 11/08/2117:04 108-10-1 ND ug/L 1.0 0.29 1 11/08/2117:04 100-42-5 ND ug/L 1.0 0.31 1 11/08/2117:04 630-20-6 ND ug/L 1.0 0.22 1 11/08/2117:04 79-34-5 ND ug/L 1.0 0.29 1 11/08/2117:04 127-18-4 ND ug/L 1.0 0.48 1 11/08/2117:04 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 17:04 71-55-6 ND ug/L 1.0 0.32 1 11/08/2117:04 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 17:04 79-01-6 ND ug/L 1.0 0.30 1 11/08/2117:04 75-69-4 ND ug/L 1.0 0.26 1 11/08/2117:04 96-18-4 ND ug/L 2.0 1.3 1 11/08/2117:04 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 17:04 75-01-4 ND ug/L 1.0 0.34 1 11/08/2117:04 1330-20-7 100 % 70-130 1 11/08/2117:04 460-00-4 108 % 70-130 1 11/08/2117:04 17060-07-0 101 % 70-130 1 11/08/2117:04 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2120:20 123-91-1 86 % 70-130 1 11/04/2120:20 17060-07-0 89 % 66-133 1 11/04/2120:20 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-MW2 Lab ID: 92570492002 Collected: 11/01/21 10:21 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/16/2106:05 7440-36-0 Arsenic 19.7 ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:05 7440-38-2 B Barium 39.1 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:05 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/16/2106:05 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/16/2106:05 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/16/2106:05 7440-47-3 Cobalt 58.7 ug/L 5.0 3.6 1 11/11/2110:54 11/16/2106:05 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/16/2106:05 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/16/2106:05 7439-92-1 Nickel 42.2 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:05 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:05 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/16/2106:05 7440-22-4 Vanadium 22.2 ug/L 5.0 3.9 1 11/11/2110:54 11/16/2106:05 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/16/2106:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.15J ug/L 0.47 0.050 1 11/08/2111:14 11/09/2100:07 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 17:21 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 17:21 107-13-1 Benzene 0.96J ug/L 1.0 0.34 1 11/08/21 17:21 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 17:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 17:21 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 17:21 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 17:21 74-83-9 IH 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 17:21 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 17:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 17:21 56-23-5 Chlorobenzene 0.33J ug/L 1.0 0.28 1 11/08/21 17:21 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 17:21 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 17:21 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 17:21 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 17:21 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 17:21 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 17:21 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 17:21 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 17:21 95-50-1 1,4-Dichlorobenzene 3.7 ug/L 1.0 0.33 1 11/08/21 17:21 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 17:21 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 17:21 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 17:21 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 17:21 75-35-4 Date: 11/17/2021 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-MW2 Lab ID: 92570492002 Collected: 11/01/21 10:21 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 17.2 ug/L 1.0 0.38 1 11/08/2117:21 156-59-2 ND ug/L 1.0 0.40 1 11/08/2117:21 156-60-5 ND ug/L 1.0 0.36 1 11/08/2117:21 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 17:21 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 17:21 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 17:21 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 17:21 591-78-6 ND ug/L 20.0 9.7 1 11/08/2117:21 74-88-4 ND ug/L 5.0 2.0 1 11/08/2117:21 75-09-2 ND ug/L 5.0 2.7 1 11/08/2117:21 108-10-1 ND ug/L 1.0 0.29 1 11/08/2117:21 100-42-5 ND ug/L 1.0 0.31 1 11/08/2117:21 630-20-6 ND ug/L 1.0 0.22 1 11/08/2117:21 79-34-5 ND ug/L 1.0 0.29 1 11/08/2117:21 127-18-4 ND ug/L 1.0 0.48 1 11/08/2117:21 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 17:21 71-55-6 ND ug/L 1.0 0.32 1 11/08/2117:21 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 17:21 79-01-6 ND ug/L 1.0 0.30 1 11/08/2117:21 75-69-4 ND ug/L 1.0 0.26 1 11/08/2117:21 96-18-4 ND ug/L 2.0 1.3 1 11/08/2117:21 108-05-4 0.511 ug/L 1.0 0.39 1 11 /08/21 17:21 75-01-4 ND ug/L 1.0 0.34 1 11/08/2117:21 1330-20-7 99 % 70-130 1 11/08/2117:21 460-00-4 107 % 70-130 1 11/08/2117:21 17060-07-0 101 % 70-130 1 11/08/2117:21 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 2.6 ug/L 2.0 0.86 1 11/04/2120:40 123-91-1 85 % 70-130 1 11/04/2120:40 17060-07-0 88 % 66-133 1 11/04/2120:40 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-MW3 Lab ID: 92570492003 Collected: 11/01/21 12:00 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony 3.6J ug/L 5.0 3.0 1 11/11/2110:54 11/16/2106:18 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:18 7440-38-2 Barium 130 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:18 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/16/2106:18 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/16/2106:18 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/16/2106:18 7440-47-3 Cobalt 32.1 ug/L 5.0 3.6 1 11/11/2110:54 11/16/2106:18 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/16/2106:18 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/16/2106:18 7439-92-1 Nickel 12.7 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:18 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:18 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/16/2106:18 7440-22-4 Vanadium 19.2 ug/L 5.0 3.9 1 11/11/2110:54 11/16/2106:18 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/16/2106:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 1.1 ug/L 0.47 0.050 1 11/08/2111:14 11/09/2100:10 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 17:39 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 17:39 107-13-1 Benzene 0.64J ug/L 1.0 0.34 1 11/08/21 17:39 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 17:39 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 17:39 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 17:39 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 17:39 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 17:39 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 17:39 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 17:39 56-23-5 Chlorobenzene 0.69J ug/L 1.0 0.28 1 11/08/21 17:39 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 17:39 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 17:39 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 17:39 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 17:39 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 17:39 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 17:39 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 17:39 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 17:39 95-50-1 1,4-Dichlorobenzene 3.7 ug/L 1.0 0.33 1 11/08/21 17:39 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 17:39 110-57-6 1,1-Dichloroethane 0.47J ug/L 1.0 0.37 1 11/08/21 17:39 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 17:39 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 17:39 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. IH v2 Page 11 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-MW3 Lab ID: 92570492003 Collected: 11/01/21 12:00 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 10.8 ug/L 1.0 0.38 1 11/08/2117:39 156-59-2 ND ug/L 1.0 0.40 1 11/08/2117:39 156-60-5 ND ug/L 1.0 0.36 1 11/08/2117:39 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 17:39 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 17:39 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 17:39 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 17:39 591-78-6 ND ug/L 20.0 9.7 1 11/08/2117:39 74-88-4 ND ug/L 5.0 2.0 1 11/08/2117:39 75-09-2 ND ug/L 5.0 2.7 1 11/08/2117:39 108-10-1 ND ug/L 1.0 0.29 1 11/08/2117:39 100-42-5 ND ug/L 1.0 0.31 1 11/08/2117:39 630-20-6 ND ug/L 1.0 0.22 1 11/08/2117:39 79-34-5 ND ug/L 1.0 0.29 1 11/08/2117:39 127-18-4 ND ug/L 1.0 0.48 1 11/08/2117:39 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 17:39 71-55-6 ND ug/L 1.0 0.32 1 11/08/2117:39 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 17:39 79-01-6 ND ug/L 1.0 0.30 1 11/08/2117:39 75-69-4 ND ug/L 1.0 0.26 1 11/08/2117:39 96-18-4 ND ug/L 2.0 1.3 1 11/08/2117:39 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 17:39 75-01-4 ND ug/L 1.0 0.34 1 11/08/2117:39 1330-20-7 98 % 70-130 1 11/08/2117:39 460-00-4 106 % 70-130 1 11/08/2117:39 17060-07-0 100 % 70-130 1 11/08/2117:39 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 45.6 ug/L 2.0 0.86 1 11/04/2121:38 123-91-1 81 % 70-130 1 11/04/2121:38 17060-07-0 86 % 66-133 1 11/04/2121:38 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-AMW1 Lab ID: 92570492004 Collected: 11/01/21 12:30 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/16/2106:21 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:21 7440-38-2 Barium 63.5 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/16/2106:21 7440-41-7 Cadmium 0.49J ug/L 1.0 0.40 1 11/11/2110:54 11/16/2106:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/16/2106:21 7440-47-3 Cobalt 6.6 ug/L 5.0 3.6 1 11/11/2110:54 11/16/2106:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/16/2106:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/16/2106:21 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:21 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/16/2106:21 7440-22-4 Vanadium 13.1 ug/L 5.0 3.9 1 11/11/2110:54 11/16/2106:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/16/2106:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/09/2100:14 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 17:56 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 17:56 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 17:56 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 17:56 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 17:56 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 17:56 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 17:56 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 17:56 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 17:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 17:56 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 17:56 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 17:56 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 17:56 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 17:56 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 17:56 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 17:56 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 17:56 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 17:56 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 17:56 95-50-1 1,4-Dichlorobenzene 1.9 ug/L 1.0 0.33 1 11/08/21 17:56 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 17:56 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 17:56 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 17:56 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 17:56 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. IH v2 Page 13 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-AMW1 Lab ID: 92570492004 Collected: 11/01/21 12:30 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 5.0 ug/L 1.0 0.38 1 11/08/2117:56 156-59-2 ND ug/L 1.0 0.40 1 11/08/2117:56 156-60-5 ND ug/L 1.0 0.36 1 11/08/2117:56 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 17:56 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 17:56 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 17:56 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 17:56 591-78-6 ND ug/L 20.0 9.7 1 11/08/2117:56 74-88-4 ND ug/L 5.0 2.0 1 11/08/2117:56 75-09-2 ND ug/L 5.0 2.7 1 11/08/2117:56 108-10-1 ND ug/L 1.0 0.29 1 11/08/2117:56 100-42-5 ND ug/L 1.0 0.31 1 11/08/2117:56 630-20-6 ND ug/L 1.0 0.22 1 11/08/2117:56 79-34-5 ND ug/L 1.0 0.29 1 11/08/2117:56 127-18-4 ND ug/L 1.0 0.48 1 11/08/2117:56 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 17:56 71-55-6 ND ug/L 1.0 0.32 1 11/08/2117:56 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 17:56 79-01-6 ND ug/L 1.0 0.30 1 11/08/2117:56 75-69-4 ND ug/L 1.0 0.26 1 11/08/2117:56 96-18-4 ND ug/L 2.0 1.3 1 11/08/2117:56 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 17:56 75-01-4 ND ug/L 1.0 0.34 1 11/08/2117:56 1330-20-7 99 % 70-130 1 11/08/2117:56 460-00-4 105 % 70-130 1 11/08/2117:56 17060-07-0 102 % 70-130 1 11/08/2117:56 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1AJ ug/L 2.0 0.86 1 11/04/2120:59 123-91-1 83 % 70-130 1 11/04/2120:59 17060-07-0 88 % 66-133 1 11/04/2120:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-SW2 Lab ID: 92570492005 Collected: 11/01/21 12:27 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/16/2106:37 7440-36-0 Arsenic 6.9.1 ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:37 7440-38-2 B Barium 53.6 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:37 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/16/2106:37 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/16/2106:37 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/16/2106:37 7440-47-3 Cobalt 12.0 ug/L 5.0 3.6 1 11/11/2110:54 11/16/2106:37 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/16/2106:37 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/16/2106:37 7439-92-1 Nickel 5.5 ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:37 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:37 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/16/2106:37 7440-22-4 Vanadium 10.8 ug/L 5.0 3.9 1 11/11/2110:54 11/16/2106:37 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/16/2106:37 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene Date: 11/17/2021 12:39 PM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.12J ug/L 0.47 0.050 1 11/08/2111:14 11/09/2100:17 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 11/08/2115:54 67-64-1 ND ug/L 10.0 1.8 1 11/08/2115:54 107-13-1 ND ug/L 1.0 0.34 1 11 /08/21 15:54 71-43-2 ND ug/L 1.0 0.47 1 11/08/2115:54 74-97-5 ND ug/L 1.0 0.31 1 11/08/2115:54 75-27-4 ND ug/L 1.0 0.34 1 11/08/2115:54 75-25-2 ND ug/L 2.0 1.7 1 11/08/2115:54 74-83-9 ND ug/L 5.0 4.0 1 11/08/2115:54 78-93-3 ND ug/L 2.0 0.73 1 11/08/2115:54 75-15-0 ND ug/L 1.0 0.33 1 11/08/2115:54 56-23-5 ND ug/L 1.0 0.28 1 11/08/2115:54 108-90-7 ND ug/L 1.0 0.65 1 11/08/2115:54 75-00-3 ND ug/L 1.0 0.43 1 11/08/2115:54 67-66-3 ND ug/L 1.0 0.54 1 11/08/2115:54 74-87-3 ND ug/L 2.0 0.34 1 11/08/2115:54 96-12-8 ND ug/L 1.0 0.36 1 11/08/2115:54 124-48-1 ND ug/L 1.0 0.27 1 11/08/2115:54 106-93-4 ND ug/L 1.0 0.39 1 11/08/2115:54 74-95-3 ND ug/L 1.0 0.34 1 11/08/2115:54 95-50-1 0.42J ug/L 1.0 0.33 1 11/08/2115:54 106-46-7 ND ug/L 1.0 0.56 1 11/08/2115:54 110-57-6 ND ug/L 1.0 0.37 1 11/08/2115:54 75-34-3 ND ug/L 1.0 0.32 1 11/08/2115:54 107-06-2 ND ug/L 1.0 0.35 1 11/08/2115:54 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IH v2 Page 15 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: 1202-SW2 Lab ID: 92570492005 Collected: 11/01/21 12:27 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.0 ug/L 1.0 0.38 1 11/08/2115:54 156-59-2 ND ug/L 1.0 0.40 1 11/08/2115:54 156-60-5 ND ug/L 1.0 0.36 1 11/08/2115:54 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 15:54 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 15:54 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 15:54 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 15:54 591-78-6 ND ug/L 20.0 9.7 1 11/08/2115:54 74-88-4 ND ug/L 5.0 2.0 1 11/08/2115:54 75-09-2 ND ug/L 5.0 2.7 1 11/08/2115:54 108-10-1 ND ug/L 1.0 0.29 1 11/08/2115:54 100-42-5 ND ug/L 1.0 0.31 1 11/08/2115:54 630-20-6 ND ug/L 1.0 0.22 1 11/08/2115:54 79-34-5 ND ug/L 1.0 0.29 1 11/08/2115:54 127-18-4 ND ug/L 1.0 0.48 1 11/08/2115:54 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 15:54 71-55-6 ND ug/L 1.0 0.32 1 11/08/2115:54 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 15:54 79-01-6 ND ug/L 1.0 0.30 1 11/08/2115:54 75-69-4 ND ug/L 1.0 0.26 1 11/08/2115:54 96-18-4 ND ug/L 2.0 1.3 1 11/08/2115:54 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 15:54 75-01-4 ND ug/L 1.0 0.34 1 11/08/2115:54 1330-20-7 99 % 70-130 1 11/08/2115:54 460-00-4 106 % 70-130 1 11/08/2115:54 17060-07-0 101 % 70-130 1 11/08/2115:54 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 16.5 ug/L 2.0 0.86 1 11/04/2121:18 123-91-1 85 % 70-130 1 11/04/2121:18 17060-07-0 88 % 66-133 1 11/04/2121:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: FIELD BLANK Lab ID: 92570492006 Collected: 11/01/21 12:40 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/16/2106:40 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:40 7440-38-2 Barium ND ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:40 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/16/2106:40 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/16/2106:40 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/16/2106:40 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/16/2106:40 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/16/2106:40 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/16/2106:40 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/16/2106:40 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/16/2106:40 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/16/2106:40 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/11/2110:54 11/16/2106:40 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/16/2106:40 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/09/2100:21 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 13:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 13:35 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 13:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 13:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 13:35 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 13:35 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 13:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 13:35 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 13:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 13:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 13:35 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 13:35 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 13:35 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 13:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 13:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 13:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 13:35 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 13:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 13:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 13:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 13:35 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 13:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 13:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 13:35 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. IH v2 Page 17 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: FIELD BLANK Lab ID: 92570492006 Collected: 11/01/21 12:40 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2113:35 156-59-2 ND ug/L 1.0 0.40 1 11/08/2113:35 156-60-5 ND ug/L 1.0 0.36 1 11/08/2113:35 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 13:35 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 13:35 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 13:35 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 13:35 591-78-6 ND ug/L 20.0 9.7 1 11/08/2113:35 74-88-4 ND ug/L 5.0 2.0 1 11/08/2113:35 75-09-2 ND ug/L 5.0 2.7 1 11/08/2113:35 108-10-1 ND ug/L 1.0 0.29 1 11/08/2113:35 100-42-5 ND ug/L 1.0 0.31 1 11/08/2113:35 630-20-6 ND ug/L 1.0 0.22 1 11/08/2113:35 79-34-5 ND ug/L 1.0 0.29 1 11/08/2113:35 127-18-4 ND ug/L 1.0 0.48 1 11/08/2113:35 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 13:35 71-55-6 ND ug/L 1.0 0.32 1 11/08/2113:35 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 13:35 79-01-6 ND ug/L 1.0 0.30 1 11/08/2113:35 75-69-4 ND ug/L 1.0 0.26 1 11/08/2113:35 96-18-4 ND ug/L 2.0 1.3 1 11/08/2113:35 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 13:35 75-01-4 ND ug/L 1.0 0.34 1 11/08/2113:35 1330-20-7 98 % 70-130 1 11/08/2113:35 460-00-4 105 % 70-130 1 11/08/2113:35 17060-07-0 101 % 70-130 1 11/08/2113:35 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2116:49 123-91-1 88 % 70-130 1 11/04/2116:49 17060-07-0 90 % 66-133 1 11/04/2116:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: TRIP BLANK Lab ID: 92570492007 Collected: 11/01/21 00:00 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 11/17/2021 12:39 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 11/08/2113:52 67-64-1 ND ug/L 10.0 1.8 1 11/08/2113:52 107-13-1 ND ug/L 1.0 0.34 1 11 /08/21 13:52 71-43-2 ND ug/L 1.0 0.47 1 11/08/2113:52 74-97-5 ND ug/L 1.0 0.31 1 11/08/2113:52 75-27-4 ND ug/L 1.0 0.34 1 11/08/2113:52 75-25-2 ND ug/L 2.0 1.7 1 11/08/2113:52 74-83-9 ND ug/L 5.0 4.0 1 11/08/2113:52 78-93-3 ND ug/L 2.0 0.73 1 11/08/2113:52 75-15-0 ND ug/L 1.0 0.33 1 11/08/2113:52 56-23-5 ND ug/L 1.0 0.28 1 11/08/2113:52 108-90-7 ND ug/L 1.0 0.65 1 11/08/2113:52 75-00-3 ND ug/L 1.0 0.43 1 11/08/2113:52 67-66-3 ND ug/L 1.0 0.54 1 11/08/2113:52 74-87-3 ND ug/L 2.0 0.34 1 11/08/2113:52 96-12-8 ND ug/L 1.0 0.36 1 11/08/2113:52 124-48-1 ND ug/L 1.0 0.27 1 11/08/2113:52 106-93-4 ND ug/L 1.0 0.39 1 11/08/2113:52 74-95-3 ND ug/L 1.0 0.34 1 11/08/2113:52 95-50-1 ND ug/L 1.0 0.33 1 11/08/2113:52 106-46-7 ND ug/L 1.0 0.56 1 11/08/2113:52 110-57-6 ND ug/L 1.0 0.37 1 11/08/2113:52 75-34-3 ND ug/L 1.0 0.32 1 11/08/2113:52 107-06-2 ND ug/L 1.0 0.35 1 11/08/2113:52 75-35-4 ND ug/L 1.0 0.38 1 11/08/2113:52 156-59-2 ND ug/L 1.0 0.40 1 11/08/2113:52 156-60-5 ND ug/L 1.0 0.36 1 11/08/2113:52 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 13:52 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 13:52 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 13:52 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 13:52 591-78-6 ND ug/L 20.0 9.7 1 11/08/2113:52 74-88-4 ND ug/L 5.0 2.0 1 11/08/2113:52 75-09-2 ND ug/L 5.0 2.7 1 11/08/2113:52 108-10-1 ND ug/L 1.0 0.29 1 11/08/2113:52 100-42-5 ND ug/L 1.0 0.31 1 11/08/2113:52 630-20-6 ND ug/L 1.0 0.22 1 11/08/2113:52 79-34-5 ND ug/L 1.0 0.29 1 11/08/2113:52 127-18-4 ND ug/L 1.0 0.48 1 11/08/2113:52 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 13:52 71-55-6 ND ug/L 1.0 0.32 1 11/08/2113:52 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 13:52 79-01-6 ND ug/L 1.0 0.30 1 11/08/2113:52 75-69-4 ND ug/L 1.0 0.26 1 11/08/2113:52 96-18-4 ND ug/L 2.0 1.3 1 11/08/2113:52 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IH v2 Page 19 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 Sample: TRIP BLANK Parameters Lab ID: 92570492007 Collected: Report Results Units Limit 11/01/21 00:00 MDL DF Received: 11/03/21 08:25 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 11/08/21 13:52 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 11/08/21 13:52 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 11/08/21 13:52 460-00-4 1,2-Dichloroethane-d4 (S) 105 % 70-130 1 11/08/21 13:52 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 11/08/21 13:52 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 11/04/21 17:08 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 11/04/21 17:08 17060-07-0 Toluene-d8 (S) 91 % 66-133 1 11/04/21 17:08 2037-26-5 Date: 11/17/2021 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 QC Batch: 659040 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92570492001 METHOD BLANK: 3454147 Associated Lab Samples: 92570492001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 11/17/2105:43 Arsenic ug/L ND 10.0 4.7 11/17/2105:43 Barium ug/L ND 5.0 3.5 11/17/2105:43 Beryllium ug/L ND 1.0 0.70 11/17/2105:43 Cadmium ug/L ND 1.0 0.40 11/17/2105:43 Chromium ug/L ND 5.0 3.7 11/17/2105:43 Cobalt ug/L ND 5.0 3.6 11/17/2105:43 Copper ug/L ND 5.0 4.3 11/17/2105:43 Lead ug/L ND 5.0 4.5 11/17/2105:43 Nickel ug/L ND 5.0 3.5 11/17/2105:43 Selenium ug/L ND 10.0 4.7 11/17/2105:43 Silver ug/L ND 5.0 2.5 11/17/2105:43 Vanadium ug/L ND 5.0 3.9 11/17/2105:43 Zinc ug/L ND 10.0 9.5 11/17/2105:43 LABORATORY CONTROL SAMPLE: Parameter 3454148 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 473 95 80-120 Arsenic ug/L 500 455 91 80-120 Barium ug/L 500 478 96 80-120 Beryllium ug/L 500 486 97 80-120 Cadmium ug/L 500 470 94 80-120 Chromium ug/L 500 464 93 80-120 Cobalt ug/L 500 459 92 80-120 Copper ug/L 500 474 95 80-120 Lead ug/L 500 475 95 80-120 Nickel ug/L 500 469 94 80-120 Selenium ug/L 500 459 92 80-120 Silver ug/L 250 230 92 80-120 Vanadium ug/L 500 466 93 80-120 Zinc ug/L 500 471 94 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: BURKE CO - EAST 92570492 BURKE LF MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3454149 3454150 MS MSD 92569908007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 352 347 70 69 75-125 1 20 M1 Arsenic ug/L ND 500 500 420 426 84 85 75-125 1 20 Barium ug/L 305 500 500 768 789 93 97 75-125 3 20 Beryllium ug/L 2.8 500 500 468 479 93 95 75-125 2 20 Cadmium ug/L 0.59J 500 500 458 455 92 91 75-125 1 20 Chromium ug/L 88.2 500 500 537 554 90 93 75-125 3 20 Cobalt ug/L 29.2 500 500 464 460 87 86 75-125 1 20 Copper ug/L 70.3 500 500 542 557 94 97 75-125 3 20 Lead ug/L 40.0 500 500 483 481 89 88 75-125 1 20 Nickel ug/L 51.2 500 500 494 492 89 88 75-125 0 20 Selenium ug/L ND 500 500 423 419 85 84 75-125 1 20 Silver ug/L ND 250 250 222 228 88 91 75-125 3 20 Vanadium ug/L 118 500 500 576 593 92 95 75-125 3 20 Zinc ug/L 169 500 500 629 626 92 91 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 QC Batch: 659042 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92570492002, 92570492003, 92570492004, 92570492005, 92570492006 METHOD BLANK: 3454152 Matrix: Water Associated Lab Samples: 92570492002, 92570492003, 92570492004, 92570492005, 92570492006 Blank Reporting Parameter Units Result Limit MDL Antimony ug/L ND 5.0 Arsenic ug/L 5.2J 10.0 Barium ug/L ND 5.0 Beryllium ug/L ND 1.0 Cadmium ug/L ND 1.0 Chromium ug/L ND 5.0 Cobalt ug/L ND 5.0 Copper ug/L ND 5.0 Lead ug/L ND 5.0 Nickel ug/L ND 5.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.0 Vanadium ug/L ND 5.0 Zinc ug/L ND 10.0 Analyzed 3.0 11 /16/21 05:58 4.7 11 /16/21 05:58 3.5 11 /16/21 05:58 0.70 11 /16/21 05:58 0.40 11 /16/21 05:58 3.7 11 /16/21 05:58 3.6 11 /16/21 05:58 4.3 11 /16/21 05:58 4.5 11 /16/21 05:58 3.5 11 /16/21 05:58 4.7 11 /16/21 05:58 2.5 11 /16/21 05:58 3.9 11 /16/21 05:58 9.5 11 /16/21 05:58 LABORATORY CONTROL SAMPLE: Parameter 3454153 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 472 94 80-120 Arsenic ug/L 500 468 94 80-120 Barium ug/L 500 479 96 80-120 Beryllium ug/L 500 488 98 80-120 Cadmium ug/L 500 478 96 80-120 Chromium ug/L 500 492 98 80-120 Cobalt ug/L 500 461 92 80-120 Copper ug/L 500 496 99 80-120 Lead ug/L 500 473 95 80-120 Nickel ug/L 500 479 96 80-120 Selenium ug/L 500 462 92 80-120 Silver ug/L 250 238 95 80-120 Vanadium ug/L 500 490 98 80-120 Zinc ug/L 500 467 93 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: BURKE CO - EAST 92570492 BURKE LF MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3454154 3454155 MS MSD 92570492002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 482 485 96 97 75-125 1 20 Arsenic ug/L 19.7 500 500 499 505 96 97 75-125 1 20 Barium ug/L 39.1 500 500 520 524 96 97 75-125 1 20 Beryllium ug/L ND 500 500 498 502 100 100 75-125 1 20 Cadmium ug/L ND 500 500 498 500 100 100 75-125 0 20 Chromium ug/L ND 500 500 500 512 100 102 75-125 2 20 Cobalt ug/L 58.7 500 500 519 523 92 93 75-125 1 20 Copper ug/L ND 500 500 500 507 100 101 75-125 1 20 Lead ug/L ND 500 500 485 487 97 97 75-125 0 20 Nickel ug/L 42.2 500 500 519 525 95 97 75-125 1 20 Selenium ug/L ND 500 500 511 512 102 102 75-125 0 20 Silver ug/L ND 250 250 241 243 96 97 75-125 1 20 Vanadium ug/L 22.2 500 500 519 528 99 101 75-125 2 20 Zinc ug/L ND 500 500 483 486 96 96 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 QC Batch: 658131 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006 METHOD BLANK: 3449622 Matrix: Water Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 11/08/2122:42 LABORATORY CONTROL SAMPLE: 3449623 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 24.8 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3449624 3449625 MS MSD 92570457002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 24.9 24.7 100 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 QC Batch: 657547 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006, 92570492007 METHOD BLANK: 3446849 Matrix: Water Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006, 92570492007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 11/08/21 13:00 1,1,1-Trichloroethane ug/L ND 1.0 0.33 11/08/21 13:00 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/08/21 13:00 1,1,2-Trichloroethane ug/L ND 1.0 0.32 11/08/21 13:00 1,1-Dichloroethane ug/L ND 1.0 0.37 11/08/21 13:00 1,1-Dichloroethene ug/L ND 1.0 0.35 11/08/21 13:00 1,2,3-Trichloropropane ug/L ND 1.0 0.26 11/08/21 13:00 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 11/08/21 13:00 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/08/21 13:00 1,2-Dichlorobenzene ug/L ND 1.0 0.34 11/08/21 13:00 1,2-Dichloroethane ug/L ND 1.0 0.32 11/08/21 13:00 1,2-Dichloropropane ug/L ND 1.0 0.36 11/08/21 13:00 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/08/21 13:00 2-Butanone (MEK) ug/L ND 5.0 4.0 11/08/21 13:00 2-Hexanone ug/L ND 5.0 0.48 11/08/21 13:00 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 11/08/21 13:00 Acetone ug/L ND 25.0 5.1 11/08/21 13:00 Acrylonitrile ug/L ND 10.0 1.8 11/08/21 13:00 Benzene ug/L ND 1.0 0.34 11/08/21 13:00 Bromochloromethane ug/L ND 1.0 0.47 11/08/21 13:00 Bromodichloromethane ug/L ND 1.0 0.31 11/08/21 13:00 Bromoform ug/L ND 1.0 0.34 11/08/21 13:00 Bromomethane ug/L ND 2.0 1.7 11/08/21 13:00 Carbon disulfide ug/L ND 2.0 0.73 11/08/21 13:00 Carbon tetrachloride ug/L ND 1.0 0.33 11/08/21 13:00 Chlorobenzene ug/L ND 1.0 0.28 11/08/21 13:00 Chloroethane ug/L ND 1.0 0.65 11/08/21 13:00 Chloroform ug/L ND 1.0 0.43 11/08/21 13:00 Chloromethane ug/L ND 1.0 0.54 11/08/21 13:00 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 11/08/21 13:00 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 11/08/21 13:00 Dibromochloromethane ug/L ND 1.0 0.36 11/08/21 13:00 Dibromomethane ug/L ND 1.0 0.39 11/08/21 13:00 Ethylbenzene ug/L ND 1.0 0.30 11/08/21 13:00 lodomethane ug/L ND 20.0 9.7 11/08/21 13:00 Methylene Chloride ug/L ND 5.0 2.0 11/08/21 13:00 Styrene ug/L ND 1.0 0.29 11/08/21 13:00 Tetrachloroethene ug/L ND 1.0 0.29 11/08/21 13:00 Toluene ug/L ND 1.0 0.48 11/08/21 13:00 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 11/08/21 13:00 IH v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 METHOD BLANK: 3446849 Matrix: Water Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006, 92570492007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 11/08/21 13:00 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 11/08/21 13:00 Trichloroethene ug/L ND 1.0 0.38 11/08/21 13:00 Trichlorofluoromethane ug/L ND 1.0 0.30 11/08/21 13:00 Vinyl acetate ug/L ND 2.0 1.3 11/08/21 13:00 Vinyl chloride ug/L ND 1.0 0.39 11/08/21 13:00 Xylene (Total) ug/L ND 1.0 0.34 11/08/21 13:00 1,2-Dichloroethane-d4 (S) % 106 70-130 11/08/21 13:00 4-Bromofluorobenzene (S) % 101 70-130 11/08/21 13:00 Toluene-d8 (S) % 101 70-130 11/08/21 13:00 LABORATORY CONTROL SAMPLE: Parameter 3446850 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 55.3 111 70-130 1,1,1-Trichloroethane ug/L 50 54.8 110 70-130 1,1,2,2-Tetrachloroethane ug/L 50 54.2 108 70-130 1,1,2-Trichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethene ug/L 50 53.2 106 70-132 1,2,3-Trichloropropane ug/L 50 59.2 118 70-130 1,2-Dibromo-3-chloropropane ug/L 50 56.4 113 70-132 1,2-Dibromoethane (EDB) ug/L 50 54.3 109 70-130 1,2-Dichlorobenzene ug/L 50 52.8 106 70-130 1,2-Dichloroethane ug/L 50 51.8 104 70-130 1,2-Dichloropropane ug/L 50 54.5 109 70-130 1,4-Dichlorobenzene ug/L 50 54.3 109 70-130 2-Butanone (MEK) ug/L 100 123 123 70-133 2-Hexanone ug/L 100 115 115 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 116 116 70-130 Acetone ug/L 100 108 108 70-144 Acrylonitrile ug/L 250 278 111 70-130 Benzene ug/L 50 52.8 106 70-130 Bromochloromethane ug/L 50 51.8 104 70-130 Bromodichloromethane ug/L 50 54.2 108 70-130 Bromoform ug/L 50 56.1 112 70-131 Bromomethane ug/L 50 73.4 147 30-177lH Carbon disulfide ug/L 50 55.2 110 70-133 Carbon tetrachloride ug/L 50 54.4 109 70-130 Chlorobenzene ug/L 50 53.8 108 70-130 Chloroethane ug/L 50 48.9 98 46-131 Chloroform ug/L 50 54.7 109 70-130 Chloromethane ug/L 50 51.2 102 49-130 v2 cis-1,2-Dichloroethene ug/L 50 52.9 106 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 LABORATORY CONTROL SAMPLE: Parameter 3446850 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 57.7 115 70-130 Dibromochloromethane ug/L 50 55.4 111 70-130 Dibromomethane ug/L 50 50.2 100 70-130 Ethylbenzene ug/L 50 55.1 110 70-130 lodomethane ug/L 100 111 111 47-140 Methylene Chloride ug/L 50 50.8 102 68-130 Styrene ug/L 50 56.2 112 70-130 Tetrachloroethene ug/L 50 52.7 105 70-130 Toluene ug/L 50 52.9 106 70-130 trans-1,2-Dichloroethene ug/L 50 53.6 107 70-130 trans- 1,3-Dichloropropene ug/L 50 56.7 113 70-130 trans-1,4-Dichloro-2-butene ug/L 50 59.2 118 25-200 Trichloroethene ug/L 50 53.6 107 70-130 Trichlorofluoromethane ug/L 50 50.8 102 61-130 Vinyl acetate ug/L 100 133 133 70-140 Vinyl chloride ug/L 50 54.1 108 59-142 Xylene (Total) ug/L 150 166 111 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3446851 MS 92570420003 Spike Parameter Units Result Conc. MSD Spike Conc. 3446852 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.0 22.4 115 112 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 23.5 23.1 118 116 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.5 21.5 113 108 70-131 5 30 1,1,2-Trichloroethane ug/L ND 20 20 22.5 22.4 112 112 70-136 1 30 1,1-Dichloroethane ug/L ND 20 20 22.8 22.5 114 112 70-147 1 30 1,1-Dichloroethene ug/L ND 20 20 23.0 22.4 115 112 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 21.5 20.9 107 104 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 21.9 21.7 110 108 69-136 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.6 21.7 113 109 70-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 22.4 22.1 112 111 70-133 1 30 1,2-Dichloroethane ug/L ND 20 20 21.9 21.3 109 107 67-138 2 30 1,2-Dichloropropane ug/L ND 20 20 22.7 22.8 114 114 70-138 0 30 1,4-Dichlorobenzene ug/L ND 20 20 22.5 22.2 112 111 70-133 1 30 2-Butanone (MEK) ug/L ND 40 40 46.2 44.1 115 110 61-147 4 30 2-Hexanone ug/L ND 40 40 42.2 40.4 105 101 67-139 4 30 4-Methyl-2-pentanone ug/L ND 40 40 42.1 41.1 105 103 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 43.2 42.1 108 105 55-159 3 30 Acrylonitrile ug/L ND 100 100 111 110 111 110 68-140 1 30 Benzene ug/L ND 20 20 22.5 22.1 112 111 67-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3446851 MS 92570420003 Spike Parameter Units Result Conc. MSD Spike Conc. 3446852 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 23.4 22.6 117 113 70-146 4 30 Bromodichloromethane ug/L ND 20 20 22.4 21.8 112 109 70-138 3 30 Bromoform ug/L ND 20 20 21.5 20.8 107 104 57-138 3 30 Bromomethane ug/L ND 20 20 22.5 22.9 113 115 10-200 2 30 Carbon disulfide ug/L ND 20 20 23.6 23.2 118 116 70-152 2 30 Carbon tetrachloride ug/L ND 20 20 22.9 23.1 115 115 70-147 1 30 Chlorobenzene ug/L ND 20 20 22.8 22.3 114 112 70-137 2 30 Chloroethane ug/L ND 20 20 25.0 25.3 125 126 51-166 1 30 Chloroform ug/L ND 20 20 24.2 23.4 121 117 70-144 3 30 Chloromethane ug/L ND 20 20 22.5 22.4 112 112 24-161 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 23.1 22.7 116 113 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.0 21.7 110 108 70-142 1 30 Dibromochloromethane ug/L ND 20 20 22.4 21.8 112 109 68-138 3 30 Dibromomethane ug/L ND 20 20 23.2 22.8 116 114 70-134 2 30 Ethylbenzene ug/L ND 20 20 22.6 22.1 113 110 68-143 3 30 lodomethane ug/L ND 40 40 43.6 45.5 109 114 20-161 4 30 Methylene Chloride ug/L ND 20 20 22.0 21.5 110 107 64-148 2 30 Styrene ug/L ND 20 20 15.4 15.6 77 78 70-136 1 30 Tetrachloroethene ug/L ND 20 20 22.5 22.1 112 111 70-139 2 30 Toluene ug/L ND 20 20 22.6 22.2 113 111 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.3 22.6 116 113 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.7 20.9 109 105 70-138 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 19.0 20.5 95 103 31-145 8 30 Trichloroethene ug/L ND 20 20 23.1 22.7 115 113 70-149 2 30 Trichlorofluoromethane ug/L ND 20 20 22.0 21.8 110 109 61-154 1 30 Vinyl acetate ug/L ND 40 40 37.9 37.6 95 94 48-156 1 30 Vinyl chloride ug/L ND 20 20 25.3 25.0 126 125 55-172 1 30 Xylene (Total) ug/L ND 60 60 67.5 66.4 112 111 66-145 2 30 1,2-Dichloroethane-d4 (S) % 93 96 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 99 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 QC Batch: 657653 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006, 92570492007 METHOD BLANK: 3447403 Matrix: Water Associated Lab Samples: 92570492001, 92570492002, 92570492003, 92570492004, 92570492005, 92570492006, 92570492007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/04/21 12:39 1,2-Dichloroethane-d4 (S) % 92 70-130 11/04/21 12:39 Toluene-d8 (S) % 92 66-133 11/04/21 12:39 LABORATORY CONTROL SAMPLE: 3447404 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.6 98 70-130 1,2-Dichloroethane-d4 (S) % 87 70-130 Toluene-d8 (S) % 90 66-133 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3447405 3447406 MS MSD 92570457004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 21.5 22.1 104 107 64-141 3 30 1,2-Dichloroethane-d4 (S) % 82 87 70-130 30 Toluene-d8 (S) % 86 88 66-133 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: BURKE CO - EAST BURKE LF Pace Project No.: 92570492 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:39 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 35 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: BURKE CO - EAST BURKE LF 92570492 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92570492001 1202-MW1 EPA 3010A 659040 EPA 6010D 659156 92570492002 1202-MW2 EPA 3010A 659042 EPA 6010D 659154 92570492003 1202-MW3 EPA 3010A 659042 EPA 6010D 659154 92570492004 1202-AMW1 EPA 3010A 659042 EPA 6010D 659154 92570492005 1202-SW2 EPA 3010A 659042 EPA 6010D 659154 92570492006 FIELD BLANK EPA 3010A 659042 EPA6010D 659154 92570492001 1202-MW1 EPA 3010A 658131 EPA 6020B 658209 92570492002 1202-MW2 EPA 3010A 658131 EPA 6020B 658209 92570492003 1202-MW3 EPA 3010A 658131 EPA 6020B 658209 92570492004 1202-AMW1 EPA 3010A 658131 EPA 6020B 658209 92570492005 1202-SW2 EPA 3010A 658131 EPA 6020B 658209 92570492006 FIELD BLANK EPA 3010A 658131 EPA 6020B 658209 92570492001 1202-MW1 EPA 8260D 657547 92570492002 1202-MW2 EPA 8260D 657547 92570492003 1202-MW3 EPA 8260D 657547 92570492004 1202-AMW1 EPA 8260D 657547 92570492005 1202-SW2 EPA 8260D 657547 92570492006 FIELD BLANK EPA 8260D 657547 92570492007 TRIP BLANK EPA 8260D 657547 92570492001 1202-MW1 EPA 8260D Mod. 657653 92570492002 1202-MW2 EPA 8260D Mod. 657653 92570492003 1202-MW3 EPA 8260D Mod. 657653 92570492004 1202-AMW1 EPA 8260D Mod. 657653 92570492005 1202-SW2 EPA 8260D Mod. 657653 92570492006 FIELD BLANK EPA 8260D Mod. 657653 92570492007 TRIP BLANK EPA 8260D Mod. 657653 Date: 11/17/2021 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 35 Document Name: Document Revised: October 28, 2020 - ace Anal ICBM- Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: ( F-CAR-CS-033-Rev,07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville M Raleigh❑ Mechanicsville[] Atianta❑ Kernersville❑ ConditionSample Client Name: WO# : 92570492 Proje( Courier: [:]Fed Ex ❑UPS ❑U5P5 ❑Clienk �� ��� ���' 11�' �I �I� ❑ Commercial dace ❑Other; 92570492 Custody Seal Present? ❑Yes 'QNo Seals Intact? ❑Yes J]JNo ll Date/In111alsPerson Examining Contents: b "' 4L Packing Material: dibble Wrap 613ubble Bags []None ❑ Other Biological Tissue Frozen? Thermometer: / / ❑Yes [-]NoaN/A �iRr..,n—in'�Z I Wet ❑Blue ❑None — Type Of ce: {n Correction Factor: Cooler Temp: - ` w Add/Subtract (*Cl Temp should be above freezing to 6•C ❑Samples out of temp criteria. Samples an ice, coo4ing process Cooler Temp Corrected ('Cl: has begun USDA Regulated Soil ('WN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, myes I—INo i—sudi—W.—H end o on M-17 r IV— 17-I1'1 Cam ments/Discrepanty: Chain of Custody Present? LY5Yes (_-]No ❑N/A 1. Samples Arrived within Hold Time? Egles ❑No ❑N/A 2. Short Hold Time Analysis J<72 hr.)? ❑Yes ONO N/A 3, Rush Turn Around Time Requested? ❑Yes NNo El N/A 4. Sufficient Volume? ❑Yes o ❑N/A 5. Correct Containers Used? -Pace Containers Used? (Yes es ❑No ❑No ❑N/A ❑N/A 6. Containers Intact? t Yes QNo N/A 7. Dissolved analysis: Samples Field filtered? ❑Yes No /A 8. Sample Labels Match COC? Includes Date/Time/ID/Analysis Matrix: 1 ,`} Yes W f ❑Na ❑N/A 9. Headspace in VOA Vials (>5-fimm)? QYcs ®No ❑N/A 10, Trip Blank Present? Trip Blank Custody Seals Present? J@Yes es '❑No ❑Na ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION ate/Time: Project Manager SCURF Review: Date: Project Manager SRF Review: Date: Field Data Required? Des ❑No Document Name: le Condition Upon Recell Document No.: F-CAR-05-0334(ev.07 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (waters DOC, LLHS "Bottom half of box is to list number of bottles Docui -nt Revised: October 28, 2020 t(SCUR) Page 2 of 2 issuing Authority: -. n,,,rty Office Proje,Q# 9 57049 PM : RhIlB � Due Dale CLIENT: 92—Joyce Eng 11/17/21 z W n V Z W V 2 41 e V a y v 7 U V V O O 2 10 d U ry A a D Z - � w z d � a 7 N V S 2 tr N V ._¢.. O T N 2 v H Z i Z E z V 4 Z 0rZ4 m z _ ¢ a m .r Y v _ Z Y a _ Q 2 a m ? w Cn M C � r 4 z a 2 p� ys o a _ z h c io y a 7 E! al m a E NMpp e G. m a E N FA 4. m o tY E vla N Q. m i a no R a O a m m a C N Zti m a m a E N * a m m 4 N U 4 a ca E 4. l7 3 a E 4 e=i U' a a E d ~0"G rl e=1 V' a E ¢ E N nrl W a a E Nm` M Q a E 4 Le' NE vi C7 a o N M M l7 a Q O� Y (n q O JE Q1 C7 a a O� OI U 7 ¢ O M l7 a u a a 0 > o, he W � a %n a yA `m N ~ N a LA a OE N a T m E a OE fl ¢ C v"+ NE G aN M Q O QE Q o ] X/ I 2 I j l4 3 j j 4 i 5 ! V 5 7 \\\N 8 4 lU 11 - 12 N\N pH Adjustment Log for Preserved Samples Sample iD Type of Preservative pH upon receipt Date preservation adjusted Time preservallon adjusted Amount of Preservative added Lot 4 —Not e:—Wheneverthere-is-a-discrepanc"ffecting-North-C-arolina- comp liance-samples; a-Capy-of-this-form-will-be-sent-to-the-North-Carolina-DEHNR.Certification-Office-si,e, — Out of hold, Incorrect preservative, out of temp, incorrect Containers. __ Paae 34 of 35 - 2/inalytrcal CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page: 1 Of 1 Company: La Bella Associates Report To: Van Burbach Attention: Lecia Jones Address: 12-D Oak Branch Dr copy To: Miguel Vazquez Company Name: La Bella Associates Greensboro, NC 27407 Address: 1604 Ownby Lane, Richmond, VA 23220 Regulatory Agency Email To: vburbach(d).labellapc.com Purchase Order No. 2212740.00.02 Pace Quote Reference Phone: (336) 323-0092 Fax Client Project ID, Burke Co. - East Burke LF Pace Project Manager: Angela Baioni State I Location Requested Due DaterFAT: 10 Da Default _ Conlamer Order Number: IlPace Profile #: i North Carolina Requ Analysis Flkemd YIN a Z mA.TRix CODE v COLLECTED z Preservatives _ - - Drinking Water DW U Water WT m U 'r o Waste Water Ww Pmduq P SAMPLE ID SoiVSolitl SL n �^ START END � U m m U p m ou o _ F One Character per box. wipe WP w W a = to o (A-7- 0-9 1. A r AR Other O7 O a w - z m Z � 7+ c a s U Sample Ids must be unique Ti:rue T5 U x r o C O c to a a x a ¢ a a s a a U o m O' N z S 0 L L C a¢ a a m v m w rn DATE TIME DATE TIME mry a= z 2 z z D z z / 1 1202-MW1 WT G I �! A]� j t X X X v 2 1202-MW2 WT G P �d16 X X X ✓✓Z 3 1202-MW3 WT G f 26r 16- x x x G :> 4 1202-AMW1 WT G ii 2 �30 i- X X x $ 1-29�SKr• WT G X X X 6 1202-SW2 WT G n I t irrL i„ X X X 7 8 Field Blank WT G J `^ 1 X x x 9 Trip Blank WT G y r •� (� X x 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFRUATION DATE TIME ACCEPTED BY I AFFILIATION BATE TIME SAMPLE CONDITIONS 62- SAMPLER NAME AND SIGNATURE m u PRINT Name of SAMPLER^J L Z m CL SIGNATURE of SAMPLE jj%T• l .: DATE Signed: 17 peg am 10 k [1, LaBetLa DATE: '�_A-7-41� P"Vef" tly pa r tri ery.hi P. GROUND WATER SAMPLING LOG Project Name: DULA14<_ — �f lYl kT roject No. /Task No.: Well ID: flmw—� Sampler(s): k,!/Zl1 o' Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt Depth to Water before Sampling: 2 inches q (o feet -7- 3 feet 'J - 341 feet [DTB-DTW] _ 0.3b gallons rtgo _ / gallons / ,-gallons gallons I U feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials l c2la, , ,q 3� C .l� Date of sample: Before Sampling: h�-- YJ� I I LI `�' f/ ��� )09. 2 33 �n J ,,�- K� Comments (weather conditions, odor, color, silt, etc.): M,(-, 1 Signature: QA/QC Sign Off: M Date: a _9'/4�_ Date: Z/z l iZZ leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 25, 2022 Mr. Van Burbach LaBella Associates, D.P.C. 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 RE: Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on February 18, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, LaBella Associates, DPC Kandice Estes, Labella Associates Miguel Vazquez, Joyce Engineering Elina Wright, LaBella Associates, D.P.C. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 North Carolina Certification #: 381 Florida DOH Certification #: E87315 South Carolina Certification #: 98011001 Georgia DW Inorganics Certification #: 812 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Lab ID Sample ID SAMPLE SUMMARY Matrix Date Collected Date Received 92589147001 1202-AMW1 Water 02/17/2215:08 02/18/2210:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92589147001 1202-AMW1 EPA6020B CW1 2 PASI-GA PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Lab Sample ID Method 92589147001 EPA 6020B SUMMARY OF DETECTION Client Sample ID Parameters Result Units Report Limit Analyzed Qualifiers 1202-AMW1 Cobalt 3.8J ug/L 5.0 02/24/2218:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Sample: 1202-AMW1 Lab ID: 92589147001 Collected: 02/17/22 15:08 Received: 02/18/22 10:52 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Cobalt 3.8J ug/L 5.0 0.39 1 02/24/2212:07 02/24/2218:24 7440-48-4 Vanadium ND ug/L 10.0 1.9 1 02/24/2212:07 02/24/2218:24 7440-62-2 Date: 02/25/2022 02:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 QC Batch: 680607 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92589147001 METHOD BLANK: 3560596 Matrix: Water Associated Lab Samples: 92589147001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cobalt ug/L ND 5.0 0.39 02/24/2217:42 Vanadium ug/L ND 10.0 1.9 02/24/2217:42 LABORATORY CONTROL SAMPLE: 3560597 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cobalt ug/L 100 103 103 80-120 Vanadium ug/L 100 107 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3560598 3560599 MS MSD 92587319001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cobalt ug/L ND 100 100 99.0 101 99 101 75-125 2 20 Vanadium ug/L ND 100 100 102 107 102 107 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/25/2022 02:50 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/25/2022 02:50 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co -East Burke LF Resampl Pace Project No.: 92589147 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92589147001 1202-AMW1 EPA 3005A 680607 EPA 6020B 680745 Date: 02/25/2022 02:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 12 Document Name: Document Revised:.November.15, 2021_ act3AnalPkal Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville [ Raleigh[] Mechanicsville(] Atlanta❑ Kernersville❑ SampleClient Name: Upon Receipt Project p W01t : 921.589147 Courier: OFed Ex ❑UPS ❑LISPS ❑ Commercial []Pace ❑Other: II II jl 92589/47 Custody Seal Present? ❑Yes No Seals Intact? ❑Yes Z Packing Material: VSubble Wrap ❑Bubble Bags ❑None Thermgme ® et [✓j IR Gun ID: Type of Ice: Correction Factor: Cooler Temp: Add/Subtract (T) Date/initials Person EMamining Contents: % L 2 ❑ ' Other []Blue []None Cooler-Ternp-Eorrected 1*01 USDA Regulated Soli ( NIA. ater sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? i❑Yes I❑No Biological Tissue rozen? []Yes [-]No N/A Temp should be above freezing to VC 05amples outof temp criteria. Samples on ice, cooling process Old samples originate from a foreign source (internationally, includineHawali and Puerto Rirnl? I—iYes MNn Comments/Discrepancy: Chain of Custody Present? 21Y4 [-]No ❑N/A 1. Samples Arrived within Hold Time? Yes ❑ Vo [-]N/A 2, Short Hold Time Analysts (c72 hr.)? CYes EfNX EIN/A 3. Rush Turn Around Time Requested? ❑Y s �No ❑N/A 4, Sufficient Volume? s ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? � hY S (-]No []No [:1 N/A ❑N/A b. Containers Intact? `Yes ❑N N/A 7. Dissolved analysis: Samples Field Filtered? ❑Y , o ❑N/A S. Sample Labels Match COC? -Includes Date/Time/l0/Anaiysis Matrix: ti Yes ❑No ❑N/A 1 Headspace in VOA Vials >5.5mm)? Yes Na /A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes []Yes ❑No []No_ M a/ . N a 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted, DatelTimet Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date: Date: Field Data Required? []Yes []No Page 10 of 12 Document Name: Oocument Revised: November 15, 2021 aGe�lllalyflCal . Sample Condition Upon Receipt (SCUR) Page 2 of 2 Document No.: Issuing Authority, F-CAR•CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project 9 verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 {water} DOC, LLHg "Bottom half of box Is to list number of bottles WN : 921.589147 PM: AMB Due Date: 03/04/22 CLIENT: 92-Joyce Eng U z x 1 ¢ Q N a a ¢ o 4 a" a z z z n M Z `! Z ?p _ N ¢ a 2 M ? 'o Y7 b N is = yg Z a ar a v aJ Z Z a S v W '� = ,� m N v N = L a z Z v w = C y ,n 2 2 In 0.1 d a y N a m 2 A a a a a O a = m y ? �o h G C C Z ID O N qqO b A Z j o C 7 Q c ry = 2 Z Z c U X Q ? N 'A j U U N '.+ v M 7 m 2 v a - a E U x z C 7 x 5c d a .M = d " a 8 m a E u�i 4 ¢ a a a+ y `m 3 E E 0. J _� G O. � Co i= Q N D} Q O N G to J J QJ N Q J £ J E E CL m E 4 E E E v Q m Q J J E E E E E a m E E of E E 'ryA O _ u1 L -V1 N = N N O G O O } � ti ��7 of vF C Y ei N in -I ,Nq N N rl 4- ,. 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Section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page : 1 Of 1 Company LaBella Associates Report To: l Estes Attention' Address. • 12-0 Oak Branch Drive Copy To, Company Name: Greensboro. NC 27407 Address Reoulatory A enc Email: Purchase Order# Pace Quote: Phone: i Fax Project Name- Burke Co, - East Burke LF Resample Pace Project Manager angels baioni pacelabs.com, State I Loca tion Requested Due Date. Project ft. Pace Profile * 21 B6 NC Requested Anal is Filtered YIN ¢ a z_ MATRIX CODE — COLLECTED Z Preservatives } Drinking Water DW water Wr 2U U O Waslowater WW Prod— P ° < z SAMPLE ID SOIvSohd SE mm $TART END V m W 1— m oil OL One Character per box. W.P. WIP w ul 1 a rr to Zr b g f Air AR D a w r m N L v Sample Ids must be unique a sure Ts Ja W ~ a ~ a ¢ a U o m c O N M z U T m w L 1ii L C Q o b m r� S6 i DATE TIME DATE TIME x 2 X z 7 O O 7 1 1202-AMW-1 WT �• {_/ Y X 2 3 4 5 6 7 8 , 9 10 11 i2 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAM LE CONDITIONS el SAMPLER NAME AND SIGNATURE C c ' PRINT Na f MP m m S[GNAT R a DAT�.�Si 'ed: u�i r a `m J Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Surface Water Constituents Table A2-4 Historical Groundwater Field Parameters Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Well ID: MW-1 MW-2 MW-3 AMW-1 TOC Elevation: 1147.00 1096.50 1039.00 1021.00 Well Depth (Ft): 50.55 71.05 32.50 7.30 05/18/15 1108.36 1032.09 1030.10 1016.35 12/07/15 1108.30 1030.95 1028.55 1016.55 05/02/16 1109.15 1037.00 1026.50 1016.69 12/12/16 1108.05 1036.20 1026.85 1016.35 06/26/17 1108.15 1042.85 1026.00 1016.30 12/14/17 1107.54 1031.67 1028.00 1016.45 05/16/18 1108.44 1030.65 1028.14 1016.35 12/03/18 1107.91 1034.32 1028.61 1016.55 05/06/19 1110.05 1042.03 1029.71 1016.92 11/04/19 1109.50 1040.83 1028.70 1016.45 05/05/20 1109.92 1041.46 1029.24 1016.71 11/09/20 1112.14 1041.10 1029.20 1016.60 05/03/21 1110.67 1043.58 1029.55 1017.21 11/01/21 1109.45 1039.37 1028.32 1016.09 Notes: All elevations are in feet above mean sea level. Well depths are in feet belwo top of casing. TOC Elevations are estimated from best available data. NM = Groundwater level not measured. Burke County - East Burke Landfill Permit No. 12-02 La Bella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Date INORGANICS Antimony 1-Nov-21 EPA 6010D 3.0 5.0 ND ND 3.6 J ND ND IMAC=1p L Arsenic 28-Apr-94 NR 1 ND 3.0 ND NI ND 2-May-00 NR 10 ND 15 J ND NI ND 8-Nov-00 NR 10 ND 18.0 ND NI ND 31-May-01 NR 10 ND 14 J ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 13.0 10 ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 24.0 15.0 ND NI ND 18-Nov-03 NR 10 ND 27.0 ND ND ND 4-May-04 NR 10 ND 23.0 ND ND ND 9-Nov-04 NR 10 ND 27.0 ND ND ND 25-May-05 NR 10 ND 22.0 ND ND ND 1-Nov-05 NR 10 ND 31.0 ND ND ND 23-May-06 NR 10 ND 32.8 ND ND ND 1-Nov-06 NR 10 ND 31.5 ND ND ND 29-May-07 NR 10 4.4 J 21.8 ND ND ND NC 2L = 50 pg/L (10/23/07) 27-Nov-07 NR 10 8.2 J 40.1 5.4 J ND ND 27-May-08 2.7 10.0 7.8 J 16.8 ND ND ND 4-Nov-08 2.7 10.0 8.4 B 18.5 B 4.2 B ND 4.8 J 1-Jun-09 2.7 10.0 33.5 Dry 5.1 J ND ND 19-Nov-09 2.7 10.0 19.1 16.3 ND ND ND NC 2L = 10 ug/L (01/01/10) 14-Jun-10 2.7 10.0 3.0 J 26.5 3.5 J ND ND 29-Nov-10 2.7 10.0 4.0 J 30.7 3.8 J ND ND 31-May-11 2.7 10.0 3.1 J 34.4 5.5 J ND ND 19-Dec-11 5.0 10.0 6.5 J 30.7 ND ND ND 30-May-12 5.0 10.0 5.3 J 22.0 ND ND ND 3-Dec-12 5.0 10.0 8.2 J 35.8 9.8 J ND ND 10-Jun-13 5.0 10.0 ND 14.0 ND ND ND 28-Oct-13 5.0 10.0 ND 34.0 ND ND ND 5-May-14 EPA 6010 5.0 10.0 ND 32.7 ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND 39.7 ND ND ND 18-May-15 EPA 6010 2.5 10.0 ND 30.4 3.5 J 3.2 J ND 7-Dec-15 EPA 6010 2.5 10.0 9.9 J 28.4 4.3 J ND ND 2-May-16 EPA 6010 2.5 10.0 ND 24.1 6.5 J ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND 26.3 5.4 J 3.8 J ND 26-Jun-17 EPA 6010 5.0 10.0 6.1 J 35.4 8.8 J 5.1 J ND 14-Dec-17 5.0 10.0 7.1 J 25.5 ND ND ND 14-May-18 EPA 6010 5.0 10.0 10.8 24.4 8.9 J ND ND 6-May-19 EPA 6010D 5.0 10.0 5 J 20.4 ND ND ND 5-Nov-19 EPA 6010D 5.0 10.0 ND 24.4 ND ND ND 6-May-20 EPA 6010D 4.7 10.0 ND 30.4 ND ND ND 9-Nov-20 EPA 6010D 4.7 10.0 7.5 J 40.2 ND ND ND 3-May-21 EPA 6010D 4.7 10.0 ND 1.9.8 ND ND ND 1-Nov-21 EPA 6010D 4.7 10.0 9.4 J 1.9.7 B ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 1 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Barium 28-Apr-94 NR 100 ND ND ND NI ND 2-May-00 NR 500 ND ND ND NI ND 8-Nov-00 NR 500 ND ND ND NI ND 31-May-01 NR 500 ND ND ND NI ND 6-Nov-01 NR 500 ND ND ND NI ND 21-May-02 NR 500 ND ND ND NI ND 13-Nov-02 NR 500 ND ND ND NI ND 13-May-03 NR 500 ND ND ND NI ND 18-Nov-03 NR 500 ND ND ND ND ND 4-May-04 NR 500 ND ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND ND 25-May-05 NR 500 ND ND ND ND ND 1-Nov-05 NR 500 ND ND ND ND ND 23-May-06 NR 500 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 100 74.6 J 70.6 J 109 60.4 J ND NC 2L = 2,000 pg/L (10/23/07) 27-Nov-07 NR 100 71.5 J 63.9 J 110 45.5 J 0.30 J 27-May-08 0.2 100 65.6 J 64.0 J 92.4 J 35.6 J 0.41 J 4-Nov-08 0.20 100 57.3 J 60.9 J 93.0 J 34.1 B 10.5 J 1-Jun-09 0.20 100 62.0 B Dry 81.8 J 32.3 B 15.2 J 19-Nov-09 0.20 100 57.7 B 149 90.5 B 30.1 B 19.8 J NC 2L = 700 pg/L (01/01/10) 14-Jun-10 0.20 100 66.3 J 85.9 J 101 60.2 J 0.58 J 29-Nov-10 0.20 100 67.2 J 76.7 J 111 46.6 J ND 31-May-11 0.20 100 67.0 J 66.8 J 96.2 J 41.7 J ND 19-Dec-11 5.0 100 86.3 J 81.3 J 103 39.5 J ND 30-May-12 5.0 100 70.7 J 61.2 J 92.7 J 39.4 J ND 3-Dec-12 5.0 100 65.2 J 54.2 J 111 27.7 J ND 10-Jun-13 5.0 100 69.8 J 125 93.9 J 25.6 B 13.7 J 28-Oct-13 5.0 100 66.4 J 101 71.5 J 45.5 J ND 5-May-14 EPA 6010 5.0 100 65.3 J 68.9 J 110 42.2 J ND 20-Oct-14 EPA 6010 5.0 100 62.1 J 56.5 J 116 47.6 J ND 18-May-15 EPA 6010 2.5 100 65.0 J 49.7 J 98.6 J 43.4 J ND 7-Dec-15 EPA 6010 2.5 100 74.5 J 63.0 J 114 38.7 J ND 2-May-16 EPA 6010 2.5 100 62.8 J 80.4 J 111 45.0 J ND 12-Dec-16 EPA 6010 2.5 100 65.3 J 48.4 J 119 47.8 J ND 26-Jun-17 EPA 6010 2.5 100 65.5 J 62.5 J 136 53.4 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 60.2 J 52.0 J 120 37.6 J ND 14-May-18 EPA 6010 2.5 100 63.3 J 49.2 J 124 42.6 J ND 6-May-19 EPA 6010D 2.5 5 56.3 40.6 113 50.8 ND 5-Nov-19 EPA 6010D 2.5 5 63.5 42.0 130 40.3 6-May-20 EPA 6010D 3.5 5 59.9 42.8 135 50.0 ND 9-Nov-20 EPA 6010D 3.5 5 59.0 37.5 135 51.6 ND 3-May-21 EPA 6010D 3.5 5 58.8 41.2 139 50.8 ND 1-Nov-21 EPA 6010D 3.5 5 60.3 39.1 130 63.5 ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 2 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Beryllium 19-Oct-99 NR 2 ND ND ND NI ND 2-May-00 NR 2 ND ND ND NI ND 8-Nov-00 NR 2 ND ND ND NI NA 31-May-01 NR 2 ND ND ND NI ND 6-Nov-01 NR 2 ND ND ND NI ND 21-May-02 NR 2 ND ND ND NI ND 13-Nov-02 NR 2 2.3 3.4 3.7 NI ND 13-May-03 NR 2 ND ND ND NI ND 18-Nov-03 NR 2 ND ND ND ND ND 4-May-04 NR 2 ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND 1-Nov-05 NR 2 ND ND ND ND ND 23-May-06 NR 2 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND GWPS = 4 Ng/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.1 1.0 0.11 J 0.11 J 0.26 J ND ND 4-Nov-08 0.10 1.0 0.12 J 0.29 J 0.24 J ND ND 1-Jun-09 0.10 1.0 ND Dry 0.17 J ND ND 19-Nov-09 0.10 1.0 ND 0.41 J 0.22 J ND ND 14-Jun-10 0.10 1.0 ND 0.18 J 0.15 J ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND 31-May-11 0.10 1.0 0.27 J 0.18 J 0.25 J ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND 10-Jun-13 1.0 1.0 ND ND ND ND ND 28-Oct-13 1.0 1.0 ND ND ND ND ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND 20-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND 18-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND 0.54 J ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 ND 0.5 J 0.57 J ND ND 14-Dec-17 EPA 6010 0.5 1.0 ND ND ND ND ND IMAC = 4 pg/L 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 ND ND ND ND ND 5-Nov-19 EPA 6010D 0.5 1.0 ND ND ND ND -- 6-May-20 EPA 6010D 0.7 1.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 0.7 1.0 ND ND ND ND ND 3-May-21 EPA 6010D 0.7 1.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 0.7 1.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 3 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Cadmium 28-Apr-94 NR 1 18.0 ND ND NI ND 2-May-00 NR 1 ND 1.0 J ND NI ND 8-Nov-00 NR 1 ND 2.0 ND NI ND 31-May-01 NR 1 ND 3.0 J 1.0 J NI ND 6-Nov-01 NR 1 ND 1.4 ND NI ND 21-May-02 NR 1 1.1 1.6 1.7 NI ND 13-Nov-02 NR 1 1.4 2.3 2.4 NI ND 13-May-03 NR 1 1.4 1.4 1.2 NI ND 18-Nov-03 NR 1 ND ND 1.7 ND ND 4-May-04 NR 1 ND ND 1.8 ND ND 9-Nov-04 NR 1 ND 2.6 1.6 ND ND 25-May-05 NR 1 ND ND ND ND ND 1-Nov-05 NR 1 ND ND ND ND ND 23-May-06 NR 1 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND NC 2L = 1.75 pg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.5 1.0 ND ND ND ND ND 4-Nov-08 0.50 1.0 ND ND ND ND ND 1-Jun-09 0.50 1.0 ND Dry ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND NC 2L = 2 pg/L (01/01/10) 14-Jun-10 0.50 1.0 ND ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 31-May-11 0.50 1.0 ND 0.55 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND 10-Jun-13 1.0 1.0 ND ND ND ND ND 28-Oct-13 1.0 1.0 ND ND ND ND ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND 20-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND 18-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 ND ND ND ND ND 5-Nov-19 EPA 6010D 0.5 1.0 ND ND ND ND -- 6-May-20 EPA 6010D 0.4 1.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 0.4 1.0 ND ND ND ND ND 3-May-21 EPA 6010D 0.4 1.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 0.4 1.0 ND ND ND 0.49 J ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 4 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 50 pg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 0.4 10.0 ND 0.66 B ND 1.0 B 0.85 J 4-Nov-08 0.40 10.0 0.68 J 1.4 J ND 1.4 J ND 1-Jun-09 0.40 10.0 ND Dry ND 1.3 J ND 19-Nov-09 0.40 10.0 ND 6.3 J ND ND 1.1 J NC 2L = 10 pg/L (01/01/10) 14-Jun-10 0.40 10.0 0.97 J 1.3 J ND 2.5 J ND 29-Nov-10 0.40 10.0 1.7 J ND ND 1.0 J ND 31-May-11 0.40 10.0 2.3 B 1.4 B 6.2 J 1.8 B 0.73 J 19-Dec-11 5.00 10.0 11.5 5.3 J ND 7.7 J ND 30-May-12 5.00 10.0 ND ND ND 7.9 J ND 3-Dec-12 5.00 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND ND 28-Oct-13 5.0 10.0 ND ND ND ND ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND 18-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 3.8 J 9.5 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 2.5 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND 3 J ND 26-Jun-17 EPA 6010 2.5 10.0 ND 3.6 J ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 ND ND ND 3.9 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND ND -- 6-May-20 EPA 6010D 3.7 5.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 3.7 5.0 ND ND ND ND ND 3-May-21 EPA 6010D 3.7 5.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 3.7 5.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 5 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Cobalt 28-Apr-94 NR 20 ND ND ND NI ND 2-May-00 NR 10 ND 54.0 ND NI ND 8-Nov-00 NR 10 ND 40.0 26.0 NI ND 31-May-01 NR 10 44.0 27.0 40.0 NI ND 6-Nov-01 NR 10 ND 22.0 41.0 NI ND 21-May-02 NR 10 18.0 19.0 51.0 NI NA 13-Nov-02 NR 10 10.0 19.0 48.0 NI ND 13-May-03 NR 10 67.0 44.0 47.0 NI ND 18-Nov-03 NR 10 29.0 120 45.0 ND ND 4-May-04 NR 10 21.0 110 35.0 ND ND 9-Nov-04 NR 10 22.0 110 36.0 ND ND 25-May-05 NR 10 23.0 120 32.0 ND ND 1-Nov-05 NR 10 17.0 120 34.0 ND ND 23-May-06 NR 10 14.6 116 31.3 ND ND 6-Nov-06 NR 10 14.8 104 32.0 ND ND 29-May-07 NR 10 17.3 79.0 30.1 2.9 J ND GWPS = 70 pg/L (10/23/07) 27-Nov-07 NR 10 11.6 84.4 32.2 3.0 J ND 27-May-08 0.6 10.0 8.9 J 8.1 J 16.5 ND ND 4-Nov-08 0.6 10.0 15.5 B 20.5 26.1 4.5 B 3.5 J 1-Jun-09 0.60 10.0 36.1 Dry 29.8 6.0 B 3.3 J 19-Nov-09 0.60 10.0 19.6 39.8 23.5 1.4 J ND 14-Jun-10 0.60 10.0 20.1 160 31.1 4.0 J ND GWPS = 1 pg/L (10/1/10) 29-Nov-10 0.60 10.0 10.2 156 37.7 5.4 J ND 31-May-11 0.60 10.0 12.2 111 27.1 ND ND 19-Dec-11 5.0 10.0 14.7 75.7 24.8 ND ND 30-May-12 5.0 10.0 23.5 78.4 26.2 ND ND 3-Dec-12 5.0 10.0 27.5 124 34.9 ND ND 10-Jun-13 5.0 10.0 19.5 58.9 29.8 ND ND 28-Oct-13 5.0 10.0 14.6 178 14.0 6.6 J ND 5-May-14 EPA 6010 5.0 10.0 9.7 J 115 24.8 ND ND 20-Oct-14 EPA 6010 5.0 10.0 8.6 J 144 25.3 ND ND 18-May-15 EPA 6010 2.5 10.0 10.3 95.3 23.5 ND ND 7-Dec-15 EPA 6010 2.5 10.0 16.3 88.6 26.1 ND ND 2-May-16 EPA 6010 2.5 10.0 10.4 128 25.6 ND ND 12-Dec-16 EPA 6010 2.5 10.0 9.3 J 94.0 24.1 ND ND 26-Jun-17 EPA 6010 2.5 10.0 13.9 110 26.3 ND ND 14-Dec-17 EPA 6010 2.5 10.0 15.8 102 24.3 ND ND IMAC = 1 pg/L 14-May-18 EPA 6010 2.5 10.0 17.9 84.7 21.0 ND ND 6-May-19 EPA 6010D 2.5 5.0 10.6 74.7 27.2 ND ND 5-Nov-19 EPA 6010D 2.5 5.0 10.5 74.1 28.9 3.0 J -- 6-May-20 EPA 6010D 3.6 5.0 8.8 89.0 31.6 ND ND 9-Nov-20 EPA 6010D 3.6 5.0 8.9 66.6 33.4 ND ND 3-May-21 EPA 6010D 3.6 5.0 7.3 56.8 35.6 ND ND 1-Nov-21 EPA 6010D 3.6 5.0 8.5 58.7 32.1 6.6 ND Resample > 17-Feb-22 EPA 6010D 3.9 5.0 NS NS NS 3.8 J -- Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 6 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Copper 28-Apr-94 NR 10 ND ND ND NI ND 2-May-00 NR 200 ND ND ND NI ND 8-Nov-00 NR 200 ND ND ND NI ND 31-May-01 NR 200 ND ND ND NI ND 6-Nov-01 NR 200 ND ND ND NI ND 21-May-02 NR 200 ND ND ND NI ND 13-Nov-02 NR 200 ND ND ND NI ND 13-May-03 NR 200 ND ND ND NI ND 18-Nov-03 NR 200 ND ND ND ND ND 4-May-04 NR 200 ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND 1-Nov-05 NR 200 ND ND ND ND ND 23-May-06 NR 200 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 1,000 pg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 0.3 10.0 ND 3.0 J ND ND ND 4-Nov-08 0.30 10.0 ND 2.2 B ND ND 0.94 J 1-Jun-09 0.30 10.0 0.36 J Dry ND ND ND 19-Nov-09 0.30 10.0 0.31 J 3.9 J ND ND ND 14-Jun-10 0.30 10.0 0.99 B 6.1 B ND ND 3.4 J 29-Nov-10 0.30 10.0 0.80 J 2.9 J ND ND ND 31-May-11 0.30 10.0 ND 0.63 J ND ND ND 19-Dec-11 5.0 10.0 5.2 J ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND 10.8 28-Oct-13 5.0 10.0 ND 11 ND ND ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND 18-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND 8.5 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 4.6 J ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 2.9 J ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND 3.0 J ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND 3.2 J ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND ND -- 6-May-20 EPA 6010D 4.3 5.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 4.3 5.0 ND ND ND ND ND 3-May-21 EPA 6010D 4.3 5.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 4.3 5.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 7 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Lead 28-Apr-94 NR 1 21.0 3.0 4.0 NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND 10.0 ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND 2.5 B 6.9 B 3.9 B 6.1 J NC 2L = 15 pg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 4 10.0 ND ND ND ND ND 4-Nov-08 4.0 10.0 ND ND ND ND ND 1-Jun-09 4.0 10.0 ND Dry ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND ND 14-Jun-10 4.0 10.0 ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND 19-Dec-11 5.0 10.0 6.2 J ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND ND 28-Oct-13 5.0 10.0 ND ND ND ND ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND 18-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND 6.6 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 ND 3.0 J ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND ND -- 6-May-20 EPA 6010D 4.5 5.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 4.5 5.0 ND ND ND ND ND 3-May-21 EPA 6010D 4.5 5.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 4.5 5.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 8 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Nickel 28-Apr-94 NR 50 ND ND ND NI ND 2-May-00 NR 50 ND ND ND NI ND 8-Nov-00 NR 50 ND ND ND NI ND 31-May-01 NR 50 ND ND ND NI ND 6-Nov-01 NR 50 ND ND ND NI ND 21-May-02 NR 50 60.0 ND ND NI ND 13-Nov-02 NR 50 ND ND ND NI ND 13-May-03 NR 50 ND ND ND NI ND 18-Nov-03 NR 50 ND 110 ND ND ND 4-May-04 NR 50 ND 99 ND ND ND 9-Nov-04 NR 50 ND 110 ND ND ND 25-May-05 NR 50 ND 100 ND ND ND 1-Nov-05 NR 50 ND 110 ND ND ND 23-May-06 NR 50 ND 103 ND ND ND 6-Nov-06 NR 50 ND 92.6 ND ND ND 29-May-07 NR 50 11.5 J 78.3 7.7 J ND ND NC 2L = 100 pg/L (10/23/07) 27-Nov-07 NR 50 7.7 J 66.4 7.2 J ND ND 27-May-08 1.7 50.0 12.1 J 24.3 J 7.4 J ND ND 4-Nov-08 1.7 50.0 16.5 J 19.2 J 9.1 B 2.2 B 2.2 J 1-Jun-09 1.7 50.0 14.9 J Dry 6.1 J ND ND 19-Nov-09 1.7 50.0 13.2 J 39.9 J 7.7 B ND 2.2 J 14-Jun-10 1.7 50.0 8.6 J 157 6.3 J ND ND 29-Nov-10 1.7 50.0 7.3 J 133 7.2 J ND ND 31-May-11 1.7 50.0 9.1 B 116 9.6 B ND 2.3 J 19-Dec-11 5.0 50.0 10.9 J 85.8 6.8 J ND ND 30-May-12 5.0 50.0 9.9 J 57.4 5.8 J ND ND 3-Dec-12 5.0 50.0 8.0 J 63.3 6.7 J ND ND 10-Jun-13 5.0 50.0 8.1 J 40.9 J 6.5 J ND ND 28-Oct-13 5.0 50.0 ND 161 ND ND ND 5-May-14 EPA 6010 5.0 50.0 ND 124 6.8 J ND ND 20-Oct-14 EPA 6010 5.0 50.0 ND 132 7.5 J ND ND 18-May-15 EPA 6010 2.5 50.0 5.1 J 88.2 7.9 J ND ND 7-Dec-15 EPA 6010 2.5 50.0 8.8 J 75.2 8.9 J ND ND 2-May-16 EPA 6010 2.5 50.0 5.6 J 122 8.4 J ND ND 12-Dec-16 EPA 6010 2.5 50.0 4.3 J 92.5 8.5 J ND ND 26-Jun-17 EPA 6010 2.5 50.0 6.0 J 98.8 8.2 J ND ND 14-Dec-17 EPA 6010 2.5 50.0 8.1 J 84.0 9.4 J ND ND 14-May-18 EPA 6010 2.5 50.0 7.2 J 64.3 6.2 J ND ND 6-May-19 EPA 6010D 2.5 5.0 5.5 62.0 9.7 ND ND 5-Nov-19 EPA 6010D 2.5 5.0 4.7 J 50.9 8.6 ND - 6-May-20 EPA 6010D 3.5 5.0 5.0 66.2 9.7 ND ND 9-Nov-20 EPA 6010D 3.5 5.0 4.5 J 49.6 11.5 ND ND 3-May-21 EPA 6010D 3.5 5.0 ND 39.4 11.6 ND ND 1-Nov-21 EPA 6010D 3.5 5.0 4.5 J 42.2 12.7 ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 9 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Selenium 19-Oct-99 NR 20 ND ND ND NI NA 2-May-00 NR 20 ND ND ND NI ND 8-Nov-00 NR 20 ND ND ND NI NA 31-May-01 NR 20 ND ND ND NI ND 6-Nov-01 NR 20 ND ND ND NI ND 21-May-02 NR 20 ND ND ND NI ND 13-Nov-02 NR 20 ND ND ND NI ND 1-Apr-03 NR 20 NA NA NA ND NA 13-May-03 NR 20 ND ND ND NA ND 18-Nov-03 NR 20 ND ND ND ND ND 4-May-04 NR 20 ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND 1-Nov-05 NR 20 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 50 pg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND 2.4 J 27-May-08 3.8 10.0 ND ND ND ND ND 4-Nov-08 3.8 10.0 ND 7.2 B 5.7 B ND 4.2 J 1-Jun-09 3.8 10.0 ND Dry 5.0 J ND ND 19-Nov-09 3.8 10.0 ND ND ND ND ND NC 2L = 20 pg/L (01/01/10) 14-Jun-10 3.8 10.0 ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND 10-Jun-13 10.0 10.0 ND ND ND ND ND 28-Oct-13 10.0 10.0 ND ND ND ND ND 5-May-14 EPA 6010 10.0 10.0 ND ND ND ND ND 20-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND 18-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 ND ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND ND -- 6-May-20 EPA 6O1OD 4.7 10.0 ND ND ND ND ND 9-Nov-20 EPA 6O1OD 4.7 10.0 ND ND ND ND ND 3-May-21 EPA 6O1OD 4.7 10.0 ND ND ND ND ND 1-Nov-21 EPA 6O1OD 4.7 10.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 10 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Silver 19-Oct-99 NR 10 ND ND ND NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI NA 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI 15.0 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 17.5 pg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 0.1 10.0 ND ND 0.30 B ND 0.14 J 4-Nov-08 0.10 10.0 0.19 B 0.31 B 0.76 B 0.18 B 0.20 J 1-Jun-09 0.10 10.0 0.18 J Dry 0.45 J ND ND 19-Nov-09 0.10 10.0 0.22 J 0.34 J 0.42 J 0.16 J ND NC 2L = 20 pg/L (01/01/10) 14-Jun-10 0.10 10.0 ND ND ND ND ND 29-Nov-10 0.10 10.0 ND ND ND ND ND 31-May-11 0.10 10.0 0.18 J 0.14 J ND 0.31 J ND 19-Dec-11 5.0 10.0 ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND ND 28-Oct-13 5.0 10.0 ND ND ND ND ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND 18-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND ND -- 6-May-20 EPA 6010D 2.5 5.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 2.5 5.0 ND ND ND ND ND 3-May-21 EPA 6010D 2.5 5.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 2.5 5.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 11 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Thallium 28-Apr-94 NR 1 ND ND ND NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND 12.0 ND ND 1-Nov-05 NR 10 ND 12.0 14.0 ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 5.5 0.167 J 0.525 J 0.625 J 0.053 J ND GWPS = 0.28 pg/L (10/23/07) 27-Nov-07 NR 5.5 0.422 J 0.475 J 0.593 J 0.073 J ND 27-May-08 3 5.5 ND ND ND ND ND 4-Nov-08 3.0 5.5 ND ND ND ND ND 1-Jun-09 3.0 5.5 ND Dry ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 14-Jun-10 3.0 5.5 3.8 J 5.3 J 4.1 J ND ND GWPS = 0.28 pg/L (10/1/10) 29-Nov-10 3.0 5.5 ND ND ND ND ND 31-May-11 3.0 5.5 ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND 3-Dec-12 5.4 5.5 7.6 ND ND ND ND 10-Jun-13 5.4 5.5 ND ND ND ND ND 28-Oct-13 5.4 5.5 ND ND ND ND ND 5-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND 20-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND 18-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 ND ND ND ND 5.5 J 26-Jun-17 EPA 6020B 5.0 5.5 0.083 J 0.57 J 1.4 J 0.034 J ND 14-Dec-17 EPA 6020B 0.03 0.10 0.10 0.54 1.4 0.04 J IMAC = 0.2 pg/L 14-May-18 EPA 6020 0.50 5.5 ND ND 1.2 J ND ND 6-May-19 EPA 6020B 0.06 0.1 0.13 0.42 0.91 0.17 ND 5-Nov-19 EPA 6020B 0.06 0.1 0.12 0.35 1.4 ND -- 6-May-20 EPA 6020B 0.06 0.1 0.12 0.30 1.2 0.13 ND 9-Nov-20 EPA 6020B 0.05 0.1 0.11 0.22 1.2 0.15 ND 3-May-21 EPA 6020B 0.05 1.0 0.10 J 0.15 J 0.79 J 0.15 J ND 1-Nov-21 EPA 6020B 0.05 0.47 0.095 J 0.15 J 1.1 ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 12 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Vanadium 28-Apr-94 NR 80 ND ND ND NI ND 2-May-00 NR 40 ND ND ND NI ND 8-Nov-00 NR 40 ND ND ND NI ND 31-May-01 NR 40 ND ND ND NI ND 6-Nov-01 NR 40 ND ND ND NI ND 21-May-02 NR 40 ND ND ND NI ND 13-Nov-02 NR 40 ND ND ND NI ND 13-May-03 NR 40 ND ND ND NI ND 18-Nov-03 NR 40 ND ND ND ND ND 4-May-04 NR 40 ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND 1-Nov-05 NR 40 ND ND ND ND ND 23-May-06 NR 40 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND GWPS = 3.5 pg/L (10/23/07) 27-Nov-07 NR 25 ND ND ND ND ND 27-May-08 0.2 25.0 0.90 B 4.5 J 1.0 B 0.93 B 0.22 J 4-Nov-08 0.20 25.0 1.4 B 4.5 J 0.62 B 1.4 B 0.85 J 1-Jun-09 0.20 25.0 0.99 B Dry 0.93 B 2.1 B 1.2 J 19-Nov-09 0.20 25.0 0.81 B 9.1 J 0.96 B 1.4 B 0.58 J 14-Jun-10 0.20 25.0 0.85 B 1.7 J 1.0 B 1.8 J 0.25 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 1.0 J ND ND ND ND 31-May-11 0.20 25.0 ND ND ND 1.4 J ND 19-Dec-11 5.0 25.0 12.1 J 6.9 J ND 6.7 J ND 30-May-12 5.0 25.0 ND ND ND 6.8 J ND 3-Dec-12 5.0 25.0 ND ND ND 6.9 J ND 10-Jun-13 5.0 25.0 ND ND ND ND ND 28-Oct-13 5.0 25.0 ND ND ND ND ND 5-May-14 EPA 6010 5.0 25.0 ND ND ND ND ND 20-Oct-14 EPA 6010 5.0 25.0 ND ND ND ND ND 18-May-15 EPA 6010 2.5 25.0 ND 7.8 J 3.6 J ND ND 7-Dec-15 EPA 6010 2.5 25.0 4.4 J 18.8 J 5.7 J 3.4 J ND 2-May-16 EPA 6010 2.5 25.0 ND ND ND 3.2 J ND 12-Dec-16 EPA 6010 2.5 25.0 ND ND ND 2.7 J ND 26-Jun-17 EPA 6010 2.5 25.0 ND 4.3 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 ND ND ND ND ND IMAC = 0.3 pg/L 14-May-18 EPA 6010 2.5 25.0 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND ND -- 6-May-20 EPA 6010D 3.9 5.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 3.9 5.0 ND 8.3 7.7 4.4 J ND 3-May-21 EPA 6010D 3.9 5.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 3.9 5.0 5.4 22.2 19.2 13.1 ND Resample > 17-Feb-22 EPA 6020B 1.9 10.0 NS NS NS ND -- Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 13 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Zinc 28-Apr-94 NR 10 ND ND ND NI ND 2-May-00 NR 50 ND ND ND NI ND 8-Nov-00 NR 50 ND ND ND NI ND 31-May-01 NR 50 ND ND ND NI ND 6-Nov-01 NR 50 ND ND ND NI ND 21-May-02 NR 50 ND ND ND NI ND 13-Nov-02 NR 50 ND ND ND NI ND 13-May-03 NR 50 ND ND ND NI ND 18-Nov-03 NR 50 ND ND ND ND ND 4-May-04 NR 50 ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND 1-Nov-05 NR 50 ND ND ND ND ND 23-May-06 NR 50 ND ND ND 76.9 ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 4.7 B 11.3 4.6 B 2.9 B 2.0 J NC 2L = 1,050 pg/L (10/23/07) 27-Nov-07 NR 10 9.1 J 9.5 J 7.3 J 1.6 J ND 27-May-08 0.4 10.0 2.6 J 8.6 B 6.4 B ND 4.8 J 4-Nov-08 0.40 10.0 3.3 B 5.4 B 0.77 B ND 8.9 J 1-Jun-09 0.40 10.0 8.7 B Dry 6.5 B 7.0 B 83.0 19-Nov-09 0.40 10.0 6.0 B 14.0 B 5.0 B 4.2 B 3.5 J NC 2L = 1,000 pg/L (01/01/10) 14-Jun-10 0.40 10.0 2.1 BB 17.4 B 20.1 B ND 10.1 29-Nov-10 0.40 10.0 1.9 J 13.0 1.8 J ND ND 31-May-11 0.40 10.0 6.5 B 20.5 B 6.8 B 4.3 B 13.7 19-Dec-11 10.0 10.0 21.3 17.0 ND 10.3 ND 30-May-12 10.0 10.0 ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND 10-Jun-13 10.0 10.0 ND ND ND ND 76.3 28-Oct-13 10.0 10.0 ND 21.4 ND ND ND 5-May-14 EPA 6010 10.0 10.0 ND 18.7 ND ND ND 20-Oct-14 EPA 6010 10.0 10.0 ND 13.4 ND ND ND 18-May-15 EPA 6010 5.0 10.0 ND 21.7 ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 7.8 B 16.7 B 6.3 B ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 5.4 J 17.0 5.3 J ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND 9.7 J 6.0 J 9.0 J ND 26-Jun-17 EPA 6010 5.0 10.0 ND 11.1 5.1 J 6.4 J ND 14-Dec-17 EPA 6010 5.0 10.0 5.6 J 10.8 6.6 J 9.9 J ND 14-May-18 EPA 6010 5.0 10.0 13 15.4 5.6 J ND ND 6-May-19 EPA 6010D 5.0 10.0 ND 8.0 J ND ND ND 5-Nov-19 EPA 6010D 5.0 10.0 ND 5.5 J ND ND -- 6-May-20 EPA 6010D 9.5 10.0 ND ND ND ND ND 9-Nov-20 EPA 6010D 9.5 10.0 ND ND ND ND ND 3-May-21 EPA 6010D 9.5 10.0 ND ND ND ND ND 1-Nov-21 EPA 6010D 9.5 10.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 14 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks ORGANICS Acetone 28-Apr-94 NR 100 ND ND ND NI ND 2-May-00 NR 100 ND ND ND NI ND 8-Nov-00 NR 100 ND ND ND NI ND 31-May-01 NR 100 ND ND ND NI ND 6-Nov-01 NR 100 ND ND ND NI ND 21-May-02 NR 100 ND ND ND NI ND 13-Nov-02 NR 100 ND ND ND NI ND 13-May-03 NR 100 210 ND ND NI ND 18-Nov-03 NR 100 ND ND ND ND ND 4-May-04 NR 100 ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND 25-May-05 NR 100 150 ND ND ND ND 1-Nov-05 NR 100 ND ND ND ND ND 23-May-06 NR 100 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND NC 2L = 700 pg/L (10/23/07) 27-Nov-07 NR 100 7.6 B 5.9 B 4.0 B 4.1 B 4.3 J 27-May-08 20 100 ND ND ND ND ND 4-Nov-08 20.0 100 ND ND ND ND ND 1-Jun-09 2.2 100 65.9 J Dry ND ND 3.2 J 19-Nov-09 2.2 100 ND 2.8 B 3.8 B 21.9 B 3.8 J NC 2L = 6,000 pg/L (01/01/10) 14-Jun-10 2.2 100 6.3 B 4.0 B ND ND 8.9 J 29-Nov-10 2.2 100 ND ND ND ND 2.3 J 31-May-11 2.2 100 3.0 B 4.0 B 4.0 B ND 3.9 J 19-Dec-11 2.2 100 ND ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND ND 3-Dec-12 10.0 100 ND ND ND ND ND 10-Jun-13 10.0 100 ND ND ND ND ND 28-Oct-13 10.0 100 ND 11.4 J ND ND ND 5-May-14 EPA 8260 10.0 100 ND ND ND ND ND 20-Oct-14 EPA 8260 10.0 100 ND ND ND ND ND 18-May-15 EPA 8260 10.0 100 ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 11.6 J 21.1 J 11 J 17.8 J 23 J 14-Dec-17 EPA 8260 10.0 100 ND ND N ND ND ND 14-May-18 EPA 8260 10.0 100 ND 10.5 J ND ND ND 6-May-19 EPA 8260D 8.2 25 ND ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 ND ND ND ND -- 6-May-20 EPA 8260D 6.2 25 ND ND ND ND ND 9-Nov-20 EPA 8260D 6.2 25 ND ND ND ND ND 3-May-21 EPA 8260D 5.1 25 ND ND ND ND ND 1-Nov-21 EPA 8260D 5.1 25 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 15 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Benzene 28-Apr-94 NR 5 ND 6.1 ND NI ND 2-May-00 NR 5 ND ND ND NI ND 8-Nov-00 NR 5 ND ND ND NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1.0 1.0 2.0 0.9 J ND ND NC 2L = 1 pg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.25 1.0 0.83 J 2.0 0.74 J ND ND 4-Nov-08 0.25 1.0 0.38 J 2.5 0.88 J ND ND 1-Jun-09 0.25 1.0 0.92 J Dry 0.74 J ND ND 19-Nov-09 0.25 1.0 ND ND ND 1.1 ND 14-Jun-10 0.25 1.0 0.62 J 2.3 0.81 J ND ND 29-Nov-10 0.25 1.0 ND 2.4 ND ND ND 31-May-11 0.25 1.0 0.62 J 2.1 0.75 J ND ND 19-Dec-11 0.25 1.0 0.68 J 1.7 0.75 J ND ND 30-May-12 0.25 1.0 0.81 J 1.6 0.68 J ND ND 3-Dec-12 0.25 1.0 0.87 J 1.3 0.67 J ND ND 10-Jun-13 0.25 1.0 0.79 J 2.0 0.75 J ND ND 28-Oct-13 0.25 1.0 ND 1.1 0.70 J ND ND 5-May-14 EPA 8260 0.25 1.0 0.38 J 1.6 0.78 J ND ND 20-Oct-14 EPA 8260 0.25 1.0 0.36 J 1.3 0.62 J ND ND 18-May-15 EPA 8260 0.25 1.0 ND 0.80 J 0.50 J ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 0.76 J ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.33 J 0.89 J 0.65 J ND ND 12-Dec-16 EPA 8260 0.25 1.0 0.3 J 1.2 0.62 J ND ND 26-Jun-17 EPA 8260 0.25 1.0 0.34 J 0.94 J 0.65 J ND ND 14-Dec-17 EPA 8260 0.25 1.0 0.44 J 0.65 J 0.56 J ND ND 14-May-18 EPA 8260 0.25 1.0 0.28 J 0.90 J 0.49 J ND ND 6-May-19 EPA 8260D 0.20 1.0 0.24 J 4.7 1.8 ND ND Resample > 24-Jul-19 EPA 8260D 0.15 1.0 - 0.95 J 0.63 J - -- 5-Nov-19 EPA 8260D 0.15 1.0 ND 1.2 0.59 J ND -- Resample > 23-Jan-20 EPA 8260D 0.15 1.0 - 1.1 - - - 6-May-20 EPA 8260D 0.15 1.0 ND 1.0 J 0.67 J ND ND 9-Nov-20 EPA 8260D 0.15 1.0 ND 1.1 0.68 J ND ND 3-May-21 EPA 8260D 0.34 1.0 ND 1.0 J 0.67 J ND ND 1-Nov-21 EPA 8260D 0.34 1.0 ND 0.96 J 0.64 J ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 16 of 28 TABLE A2-2: Historical Groundwater Constituents �An�ayte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks 2-Butanone (MEK) 19-Nov-09 0.96 100 ND ND ND 2.8 J ND NC 2L = 4,000 pg/L (01/01/10) 14-Jun-10 0.96 100 ND ND ND ND 1.6 J 29-Nov-10 0.96 100 ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND 19-Dec-11 0.96 100 ND ND ND ND ND 30-May-12 0.96 100 ND ND ND ND ND 3-Dec-12 0.96 100 ND ND ND ND ND 10-Jun-13 0.96 100 ND ND ND ND ND 28-Oct-13 0.96 100 ND ND ND ND ND 5-May-14 EPA 8260 0.96 100 ND ND ND ND ND 20-Oct-14 EPA 8260 0.96 100 ND ND ND ND ND 18-May-15 EPA 8260 0.96 100 ND ND ND ND ND 7-Dec-15 EPA 8260 0.96 100 ND ND ND ND ND 2-May-16 EPA 8260 0.96 100 ND ND ND ND ND 12-Dec-16 EPA 8260 0.96 100 ND ND ND ND ND 26-Jun-17 EPA 8260 0.96 100 ND ND ND ND ND 14-Dec-17 EPA 8260 0.96 100 ND ND ND ND ND 14-May-18 EPA 8260 0.96 100 ND ND ND ND ND 6-May-19 EPA 8260D 3.20 5 ND ND ND ND ND 5-Nov-19 EPA 8260D 3.30 5 ND ND ND ND -- 6-May-20 EPA 8260D 3.30 5 ND ND ND ND ND 9-Nov-20 EPA 8260D 3.30 5 ND ND ND ND ND 3-May-21 EPA 8260D 4.00 5 ND ND ND ND ND 1-Nov-21 EPA 8260D 4.00 5 ND ND ND ND ND Carbon Disulfide 12-May-99 NR 5 5.8 ND ND NI ND 19-Oct-99 NR 100 ND ND ND NI ND 2-May-00 NR 100 ND ND ND NI ND 8-Nov-00 NR 100 ND ND ND NI ND 31-May-01 NR 100 ND ND ND NI ND 6-Nov-01 NR 100 ND ND ND NI ND 21-May-02 NR 100 ND ND ND NI ND 13-Nov-02 NR 100 ND ND ND NI ND 13-May-03 NR 100 ND ND ND NI ND 18-Nov-03 NR 100 ND ND ND ND ND 4-May-04 NR 100 ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND 1-Nov-05 NR 100 ND ND ND ND ND 23-May-06 NR 100 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND NC 2L - 700 pWL (10/23/07) 27-Nov-07 NR 100 ND ND ND ND ND 27-May-08 1.2 100 ND ND ND ND ND 4-Nov-08 1.2 100 ND ND ND ND ND 1-Jun-09 1.2 100 ND Dry ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND 14-Jun-10 1.2 100 ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND 10-Jun-13 1.2 100 ND ND ND ND ND 28-Oct-13 1.2 100 ND ND ND ND ND 5-May-14 EPA 8260 1.2 100 ND ND ND ND ND 20-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND 18-May-15 EPA 8260 1.2 100 ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 ND ND ND ND ND 6-May-19 EPA 8260D 0.8 10 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.4 2 ND ND ND ND -- 6-May-20 EPA 8260D 0.4 2 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.4 2 ND ND ND ND ND 3-May-21 EPA 8260D 0.7 2 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.73 2 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 17 of 28 TABLE A2-2: Historical Groundwater Constituents Analyta Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Chlorobenzene 7NC= 29-May-07 NR 3 ND 0.73 J 0.76 J 0.24 J ND 50 pVL (10/23/07) 27-Nov-07 NR 3 ND ND ND ND ND 27-May-08 0.23 3.0 ND 0.57 J 0.58 J ND ND 4-Nov-08 0.23 3.0 ND 0.41 J 0.56 J ND ND 1-Jun-09 0.23 3.0 ND Dry 0.55 J ND ND 19-Nov-09 0.23 3.0 ND ND ND 0.23 J ND 14-Jun-10 0.23 3.0 ND 0.70 J 0.58 J ND ND 29-Nov-10 0.23 3.0 ND 0.84 J ND ND ND 31-May-11 0.23 3.0 ND 0.65 J 0.63 J ND ND 19-Dec-11 0.23 3.0 ND 0.59 J 0.65 J ND ND 30-May-12 0.23 3.0 ND 0.42 J 0.68 J ND ND 3-Dec-12 0.23 3.0 ND 0.32 J 0.60 J ND ND 10-Jun-13 0.23 3.0 ND 0.43 J 0.60 J ND ND 28-Oct-13 0.23 3.0 ND 0.50 J 0.64 J ND ND 5-May-14 EPA 8260 0.23 3.0 ND 0.73 J 0.72 J ND ND 20-Oct-14 EPA 8260 0.23 3.0 ND 0.67 J 0.70 J ND ND 18-May-15 EPA 8260 0.23 3.0 ND ND 0.77 J ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 0.42 J 0.58 J ND ND 2-May-16 EPA 8260 0.23 3.0 ND 0.54 J 0.84 J ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 0.46 J 0.67 J ND ND 26-Jun-17 EPA 8260 0.23 3.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 ND 0.37 J 0.73 J ND ND 14-May-18 EPA 8260 0.23 3.0 ND 0.26 J 0.72 J ND ND 6-May-19 EPA 8260D 0.53 1.0 ND 35.50 8.90 ND ND 5-Nov-19 EPA 8260D 0.23 1.0 ND 0.38 J 0.66 J ND - 6-May-20 EPA 8260D 0.23 1.0 ND 0.29 J 0.75 J ND ND 9-Nov-20 EPA 8260D 0.23 1.0 ND 0.42 J 0.75 J ND ND 3-May-21 EPA 8260D 0.28 1.0 ND 0.35 J 0.76 J ND ND 1-Nov-21 EPA 8260D 0.28 1.0 ND 0.33 J 0.69 J ND ND Chloromethane 1-Jun-09 0.11 1.0 ND Dry 0.21 J ND ND NC 2L = 2.6 pg/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND NC 2L = 3 ug/L (01/01/10) 14-Jun-10 0.11 1.0 ND ND ND ND 0.12 J 29-Nov-10 0.11 1.0 ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND 10-Jun-13 0.11 1.0 ND ND ND ND ND 28-Oct-13 0.11 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.11 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.11 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.39 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.39 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.54 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.54 1.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 18 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks ,2-Dichlorobenzene 7NC 28-Oct-13 5.00 30.0 ND ND ND 0.86 J ND L= 20 pVL (01/01/10) 5-May-14 EPA 8260 0.30 5.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.30 5.0 ND ND ND ND ND 18-May-15 EPA 8260 0.30 5.0 ND ND ND ND ND NC 2L = 20 pg/L (01/01/10) 7-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 ND 0.88 J ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.34 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.34 1.0 ND ND ND ND ND 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 7.1 ND NI ND 2-May-00 NR 5 ND 10.0 5.2 NI ND 8-Nov-00 NR 5 ND 9.9 5.9 NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND 8.2 6.4 NI ND 13-Nov-02 NR 5 ND 7.6 ND NI ND 13-May-03 NR 5 5.0 5.5 ND NI ND 18-Nov-03 NR 5 ND 5.4 5.4 ND ND 4-May-04 NR 5 ND 7.4 5.0 ND ND 9-Nov-04 NR 5 ND 7.4 5.1 ND ND 25-May-05 NR 5 ND 6.0 5.0 ND ND 1-Nov-05 NR 5 ND 8.0 5.0 ND ND 23-May-06 NR 5 ND 5.8 ND ND ND 6-Nov-06 NR 3 ND 6.7 5.5 ND ND 29-May-07 NR 1 3.6 8.1 6.5 2.2 ND NC 2L = 1.4 pg/L (10/23/07) 27-Nov-07 NR 1 2.7 7.2 5.5 ND ND 27-May-08 0.33 1.0 2.5 8.2 4.7 1.0 ND 4-Nov-08 0.33 1.0 1.2 6.3 4.8 0.94 J ND 1-Jun-09 0.33 1.0 3.4 Dry 4.6 1.2 ND 19-Nov-09 0.33 1.0 ND ND ND 3.7 ND NC 2L = 6 pg/L (01/01/10) 14-Jun-10 0.33 1.0 1.7 2.4 4.6 1.2 ND 29-Nov-10 0.33 1.0 0.97 J 4.2 5.3 1.4 ND 31-May-11 0.33 1.0 1.4 5.6 4.8 0.96 J ND 19-Dec-11 0.33 1.0 1.4 6.3 4.7 0.62 J ND 30-May-12 0.33 1.0 1.9 5.0 4.3 0.73 J ND 3-Dec-12 0.33 1.0 1.7 3.4 4.3 0.63 J ND 10-Jun-13 0.33 1.0 1.5 4.1 4.1 0.77 J ND 28-Oct-13 0.30 1.0 1.1 1.6 4.5 0.88 J ND 5-May-14 EPA 8260 0.33 1.0 0.89 J 4.7 4.7 0.78 J ND 20-Oct-14 EPA 8260 0.33 1.0 0.92 J 5.3 4.6 0.91 J ND 18-May-15 EPA 8260 0.33 1.0 1.2 5.1 4.6 0.68 J ND 7-Dec-15 EPA 8260 0.33 1.0 1.2 4.8 4.1 0.50 J ND 2-May-16 EPA 8260 0.33 1.0 1.1 2.7 4.4 0.65 J ND 12-Dec-16 EPA 8260 0.33 1.0 0.60 J 3.6 4.3 0.60 J ND 26-Jun-17 EPA 8260 0.33 1.0 ND 3.5 4.3 ND ND 14-Dec-17 EPA 8260 0.33 1.0 1.10 4.7 4.4 0.80 J ND 14-May-18 EPA 8260 0.33 1.0 1.20 2.9 3.6 0.63 J ND 6-May-19 EPA 8260D 0.58 1.0 0.74 J 14 4.9 ND ND 5-Nov-19 EPA 8260D 0.26 1.0 ND 3.6 3.9 0.73 J - 6-May-20 EPA 8260D 0.26 1.0 ND 2.7 4 0.40 J ND 9-Nov-20 EPA 8260D 0.26 1.0 0.37 J 4.1 4.2 0.34 J ND 3-May-21 EPA 8260D 0.33 1.0 0.38 J 3.7 3.6 ND ND 1-Nov-21 EPA 8260D 0.33 1.0 ND 3.7 3.7 1.9 ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 19 of 28 TABLE A2-2: Historical Groundwater Constituents lyte rlDichloroethane Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks 28-Apr-94 NR 5 ND 6.1 16.0 Ni ND 2-May-00 NR 5 ND ND 8.8 J NI ND 8-Nov-00 NR 5 ND ND 11.0 NI ND 31-May-01 NR 5 ND ND 8.4 NI ND 6-Nov-01 NR 5 ND ND 7.4 NI ND 21-May-02 NR 5 ND ND 11.0 NI ND 13-Nov-02 NR 5 ND ND 8.1 NI ND 13-May-03 NR 5 ND ND 6.0 NI ND 18-Nov-03 NR 5 ND ND 6.0 ND ND 4-May-04 NR 5 ND ND 5.2 ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND 5.0 ND ND 1-Nov-05 NR 5 ND ND 5.0 ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 5 1.9 J 2.3 J 5.1 4.0 J ND NC 2L = 70 pg/L (10/23/07) 27-Nov-07 NR 5.0 ND 0.58 J 2.7 J 1.2 J ND 27-May-08 0.32 5.0 0.36 J 0.71 J 2.8 J 1.1 J ND 4-Nov-08 0.32 5.0 0.34 J 0.79 J 3.4 J 0.88 J ND 1-Jun-09 0.32 5.0 0.35 J Dry 2.6 J 0.62 J ND 19-Nov-09 0.32 5.0 ND ND ND 0.32 J ND NC 2L = 6 pg/L (01/01/10) 14-Jun-10 0.32 5.0 0.32 J 0.41 J 2.3 J 1.5 J ND 29-Nov-10 0.32 5.0 ND ND 2.7 J ND ND 31-May-11 0.32 5.0 0.35 J 0.40 J 2.6 J 0.67 J ND 19-Dec-11 0.32 5.0 ND ND 2.2 J ND ND 30-May-12 0.32 5.0 ND ND 1.9 J ND ND 3-Dec-12 0.32 5.0 ND ND 1.7 J ND ND 10-Jun-13 0.32 5.0 ND ND 1.8 J ND ND 28-Oct-13 0.32 5.0 ND ND 1.5 J 0.42 J ND 5-May-14 EPA 8260 0.32 5.0 ND ND 1.6 J 0.57 J ND 20-Oct-14 EPA 8260 0.32 5.0 ND ND 1.3 J 0.46 J ND 18-May-15 EPA 8260 0.32 5.0 ND ND 0.87 J ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND ND 0.91 J ND ND 2-May-16 EPA 8260 0.32 5.0 ND ND 0.95 J ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND ND 0.97 J ND ND 26-Jun-17 EPA 8260 0.32 5.0 ND ND 0.97 J ND ND 14-Dec-17 EPA 8260 0.32 5.0 ND ND 0.89 J ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND 0.63 J ND ND 6-May-19 EPA 826OD 0.41 1.0 ND 0.46 J 5.8 ND ND 5-Nov-19 EPA 826OD 0.27 1.0 ND ND 0.66 J ND -- 6-May-20 EPA 826OD 0.27 1.0 ND ND 0.58 J ND ND 9-Nov-20 EPA 826OD 0.27 1.0 ND ND 0.53 J ND ND 3-May-21 EPA 826OD 0.37 1.0 ND ND ND ND ND 1-Nov-21 EPA826OD 0.37 1.0 ND ND 0.47 J ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 20 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks 2-Dichloroethane 7NC21 31-May-11 0.12 1.0 ND ND 0.12 J ND ND = 0.4 Ng/L (01/01/10) 19-Dec-11 0.12 1.0 ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND 10-Jun-13 0.12 1.0 ND ND ND ND ND 28-Oct-13 0.12 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.12 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.12 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.24 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.24 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.24 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.24 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.24 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.67 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.34 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.34 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.34 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.32 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.32 1.0 ND ND ND ND ND cis-1,2-Dichloroethene 28-Apr-94 NR 5 12.0 80.0 20.0 NI ND 2-May-00 NR 5 11.0 58.0 22.0 NI ND 8-Nov-00 NR 5 16.0 65.0 33.0 NI ND 31-May-01 NR 5 11.0 75.0 26.0 NI ND 6-Nov-01 NR 5 15.0 68.0 22.0 NI ND 21-May-02 NR 5 21.0 92.0 34.0 NI ND 13-Nov-02 NR 5 16.0 100 29.0 NI ND 1-Apr-03 NR 5 NA NA NA ND NA 13-May-03 NR 5 21.0 82.0 26.0 NA ND 1-Jul-03 NR 5 NA NA NA NA ND 18-Nov-03 NR 5 9.0 91.0 28.0 23.0 ND 4-May-04 NR 5 11.0 78.0 26.0 19.0 ND 9-Nov-04 NR 5 11.0 66.0 24.0 13.0 ND 25-May-05 NR 5 14.0 59.0 28.0 17.0 ND 1-Nov-05 NR 5 ND 26.0 11.0 7.0 ND 23-May-06 NR 5 ND 26.8 14.0 7.4 ND 1-Nov-06 NR 5 13.0 53.0 25.0 13.0 ND 29-May-07 NR 5 15.0 49.0 24.0 20.0 ND NC 2L = 70 pg/L (10/23/07) 27-Nov-07 NR 5 ND 43.0 20.0 7.7 ND 27-May-08 0.19 5.0 9.8 50.3 22.0 7.4 ND 4-Nov-08 0.19 5.0 5.1 61.4 27.9 4.2 J ND 1-Jun-09 0.19 5.0 12.1 Dry 21.1 2.7 J ND 19-Nov-09 0.19 5.0 ND ND ND 12.6 0.26 J 14-Jun-10 0.19 5.0 6.6 51.4 21.7 21.4 ND 29-Nov-10 0.19 5.0 4.4 J 56.5 23.0 11.6 ND 31-May-11 0.19 5.0 7.0 56.2 25.6 12.2 ND 19-Dec-11 0.19 5.0 6.8 41.1 20.9 1.7 J ND 30-May-12 0.19 5.0 8.8 40.1 19.6 1.3 J ND 3-Dec-12 0.19 5.0 7.3 30.0 18.7 0.58 J ND 10-Jun-13 0.19 5.0 7.0 43.0 20.4 0.61 J ND 28-Oct-13 0.19 5.0 4.4 J 23.6 18.4 4.7 J ND 5-May-14 EPA 8260 0.19 5.0 2.9 J 40.5 19.2 8.5 ND 20-Oct-14 EPA 8260 0.19 5.0 2.7 J 33.9 16.6 7.0 ND 18-May-15 EPA 8260 0.19 5.0 2.7 J 19.2 13.4 5.8 ND 7-Dec-15 EPA 8260 0.19 5.0 4.0 J 26.9 15.4 3.2 J ND 2-May-16 EPA 8260 0.19 5.0 2.1 J 17.2 13.8 7.1 ND 12-Dec-16 EPA 8260 0.19 5.0 2.1 J 31.2 16.9 5.2 ND 26-Jun-17 EPA 8260 0.19 5.0 2.3 J 24.0 14.7 4.9 J ND 14-Dec-17 EPA 8260 0.19 5.0 3.0 J 21.6 15.3 2.6 J ND 14-May-18 EPA 8260 0.19 5.0 1.9 J 18.9 10.6 3.6 J ND 6-May-19 EPA 8260D 0.66 1.0 1.6 ND 18 1.4 ND 5-Nov-19 EPA 8260D 0.29 1.0 0.86 J 29.6 12.8 2.3 - 6-May-20 EPA 8260D 0.29 1.0 0.75 J 17.6 12 2.6 ND 9-Nov-20 EPA 8260D 0.29 1.0 0.61 J 17.7 10.3 2.1 ND 3-May-21 EPA 8260D 0.38 1.0 0.77 J 17.3 10.1 2.0 ND 1-Nov-21 EPA 8260D 0.38 1.0 0.56 J 17.2 10.8 5 ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 21 of 28 TABLE A2-2: Historical Groundwater Constituents Analyta Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks -1;2-Dichloroethene 7NCr 29-May-07 NR 5 ND ND ND 0.4 J ND = 100Ng/L (10/23/07) 27-Nov-07 NR 5 ND ND ND ND ND 27-May-08 0.49 5.0 ND ND ND ND ND 4-Nov-08 0.49 5.0 ND ND ND ND ND 1-Jun-09 0.49 5.0 ND Dry ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 14-Jun-10 0.49 5.0 ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND 10-Jun-13 0.49 5.0 ND ND ND ND ND 28-Oct-13 0.49 5.0 ND ND ND ND ND 5-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND 18-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.46 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.25 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.25 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.25 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.40 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.40 1.0 ND ND ND ND ND Bromomethane 27-May-08 0.29 10.0 3.4 J ND ND ND ND NC 2L = NE pg/L (10/23/07) 4-Nov-08 0.29 10.0 ND ND ND ND ND 1-Jun-09 0.29 10.0 ND Dry ND ND ND 19-Nov-09 0.29 10.0 ND ND ND ND ND 14-Jun-10 0.29 10.0 ND ND ND ND ND GWPS - 10 pg/L (8/1/10) 29-Nov-10 0.29 10.0 ND ND ND ND ND 31-May-11 0.29 10.0 ND ND ND ND ND 19-Dec-11 0.29 10.0 ND ND ND ND ND 30-May-12 0.29 10.0 ND ND ND ND ND 3-Dec-12 0.29 10.0 ND ND ND ND ND 10-Jun-13 0.29 10.0 ND ND ND ND ND 28-Oct-13 0.29 10.0 ND ND ND ND ND 5-May-14 EPA 8260 0.29 10.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.29 10.0 ND ND ND ND ND 18-May-15 EPA 8260 0.29 10.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.29 10.0 ND ND ND ND ND 2-May-16 EPA 8260 0.29 10.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.29 10.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.29 10.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.29 10.0 ND ND ND ND ND IMAC = 10 pg/L 14-May-18 EPA 8260 0.29 10.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.95 2.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.95 2.0 ND ND ND ND ND 6-May-20 EPA 8260D 0.62 2.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.62 2.0 ND ND ND ND ND 3-May-21 EPA 8260D 1.70 2.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 1.70 2.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 22 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks -Dichloropropane 7NC 14-Jun-10 0.27 1.0 ND ND ND 0.32 J ND = 0.6 OWL (01/01/10) 29-Nov-10 0.27 1.0 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND 0.28 J ND ND 10-Jun-13 0.27 1.0 ND ND ND ND ND 28-Oct-13 0.27 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.27 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.27 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.27 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND 1.0 ND ND Resample > 24-Jul-19 EPA 8260D 0.60 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.19 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.19 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.36 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.36 1.0 ND ND ND ND ND Ethylbenzene 14-Jun-10 0.26 1.0 ND 0.35 J ND ND ND NC 2L = 600 pg/L (01/01/10) 29-Nov-10 0.30 1.0 ND ND ND ND ND 31-May-11 0.30 1.0 ND ND ND ND ND 19-Dec-11 0.30 1.0 ND ND ND ND ND 30-May-12 0.30 1.0 ND ND ND ND ND 3-Dec-12 0.30 1.0 ND ND ND ND ND 10-Jun-13 0.30 1.0 ND ND ND ND ND 28-Oct-13 0.30 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.30 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.30 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.30 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.45 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.26 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.26 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.30 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.30 1.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 23 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Styrene 1-Jun-09 0.26 1.0 2.0 Dry ND ND ND NC 2L = 100 pg/L (10/23/07) 19-Nov-09 0.26 1.0 ND ND ND ND ND NC 2L = 70 pVL (01/01/10) 14-Jun-10 0.26 1.0 ND ND ND ND ND 29-Nov-10 0.26 1.0 ND ND ND ND ND 31-May-11 0.26 1.0 ND ND ND ND ND 19-Dec-11 0.26 1.0 ND ND ND ND ND 30-May-12 0.26 1.0 ND ND ND ND ND 3-Dec-12 0.26 1.0 ND ND ND ND ND 10-Jun-13 0.26 1.0 ND ND ND ND ND 28-Oct-13 0.26 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.26 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.26 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.26 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.26 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.27 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.27 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.27 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.29 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.29 1.0 ND ND ND ND ND Methylene Chloride 28-Apr-94 NR 5 ND 5.8 7.8 NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND NC 2L = 4.6 pg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.97 2.0 ND ND ND ND 1.5 J 4-Nov-08 0.97 2.0 ND ND ND ND 2.8 1-Jun-09 0.97 2.0 ND Dry ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND NC 2L = 5 pg/L (01/01/10) 14-Jun-10 0.97 2.0 ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND ND 31-May-11 0.97 1.0 ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND 10-Jun-13 0.97 1.0 ND ND ND ND ND 28-Oct-13 0.97 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.97 1.0 ND ND ND ND 2.6 20-Oct-14 EPA 8260 0.97 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.97 1.0 ND ND ND ND 1.3 7-Dec-15 EPA 8260 0.97 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.97 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.97 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.97 1.0 ND ND ND ND 1.3 C 14-Dec-17 EPA 8260 0.97 1.0 ND ND ND ND 2.1 C9 14-May-18 EPA 8260 0.97 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 3.70 5.0 ND ND ND ND -- 6-May-20 EPA 8260D 3.70 5.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 3.70 5.0 ND ND ND ND ND 3-May-21 EPA 8260D 2.00 5.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 2.0 5.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 24 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Tetrachloroethene 28-Apr-94 NR 5.0 ND 14.0 6.2 NI ND (PCE) 6-Oct-94 NR 5.0 ND 13.0 10.0 NI ND 2-May-00 NR 5 ND ND ND NI ND 8-Nov-00 NR 5 ND ND ND NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 0.6 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 0.6 J 0.57 J 1.0 ND ND NC 2L = 0.7 pg/L (10/23/07) 27-Nov-07 NR 1 ND 0.43 J 0.67 J ND ND 27-May-08 0.46 1.0 0.53 J 0.54 J 0.60 J ND ND 4-Nov-08 0.46 1.0 0.48 J ND 0.58 J ND ND 1-Jun-09 0.46 1.0 0.49 J Dry 0.48 J ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND 14-Jun-10 0.46 1.0 0.53 J ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND ND 31-May-11 0.46 1.0 ND ND ND ND ND 19-Dec-11 0.46 1.0 ND ND 0.49 B ND 0.77 J 30-May-12 0.46 1.0 ND ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND ND 10-Jun-13 0.46 1.0 0.50 J ND ND ND ND 28-Oct-13 0.46 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.46 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.46 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.46 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 0.55 J ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 ND ND 11.3 ND ND Resample > 24-Jul-19 EPA 8260D 0.78 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.16 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.16 1.0 0.84 J ND 0.75 J ND ND 3-May-21 EPA 8260D 0.29 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.29 1.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 25 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Trichloroethene 28-Apr-94 NR 5 ND 9.9 7.2 NI ND (TCE) 6-Oct-94 NR 5 ND 10.0 7.6 NI ND 2-May-00 NR 5 ND ND ND NI ND 8-Nov-00 NR 5 ND ND 5.5 NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND 2.9 3.1 3.0 ND NC 2L = 2.8 pg/L (10/23/07) 27-Nov-07 NR 1 ND 1.5 1.7 ND ND 27-May-08 0.47 1.0 ND 1.5 1.6 0.56 J ND 4-Nov-08 0.47 1.0 ND 1.6 1.6 ND ND 1-Jun-09 0.47 1.0 ND Dry 1.4 ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND NC 2L = 3 pg/L (01/01/10) 14-Jun-10 0.47 1.0 ND 0.92 J 1.3 1.2 ND 29-Nov-10 0.47 1.0 ND 1.3 1.5 ND ND 31-May-11 0.47 1.0 ND 0.84 J 1.3 0.59 J ND 19-Dec-11 0.47 1.0 ND 0.87 J 1.3 ND ND 30-May-12 0.47 1.0 ND 0.61 J 1.1 ND ND 3-Dec-12 0.47 1.0 ND 0.68 J 1.0 ND ND 10-Jun-13 0.47 1.0 ND 1.8 1.1 ND ND 28-Oct-13 0.47 1.0 ND 0.50 J 0.86 J ND ND 5-May-14 EPA 8260 0.47 1.0 ND 0.85 J 0.92 J 0.57 J ND 20-Oct-14 EPA 8260 0.47 1.0 ND 0.69 J 0.81 J ND ND 18-May-15 EPA 8260 0.47 1.0 ND ND 0.66 J ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND 0.71 J ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND 0.55 J ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND 0.51 J 0.65 J ND ND 26-Jun-17 EPA 8260 0.47 1.0 ND ND 0.60 J ND ND 14-Dec-17 EPA 8260 0.47 1.0 ND ND 0.57 J ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 ND ND 6.0 ND ND 5-Nov-19 EPA 8260D 0.22 1.0 ND 0.60 J 0.59 J ND - 6-May-20 EPA 8260D 0.22 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.22 1.0 ND 0.53 J 0.47 J ND ND 3-May-21 EPA 8260D 0.38 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.38 1.0 ND ND ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 26 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Toluene 19-Nov-09 0.26 1.0 ND ND ND 0.49 J ND NC 2L = 6,000 pg/L (01/01/10) 14-Jun-10 0.26 1.0 1.1 ND ND ND ND 29-Nov-10 0.26 1.0 ND ND ND ND ND 31-May-11 0.26 1.0 ND ND ND ND ND 19-Dec-11 0.26 1.0 ND ND ND ND ND 30-May-12 0.26 1.0 ND ND ND ND ND 3-Dec-12 0.26 1.0 ND ND ND ND ND 10-Jun-13 0.26 1.0 ND ND ND ND ND 28-Oct-13 0.26 1.0 ND ND ND ND ND 5-May-14 EPA 8260 0.26 1.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.26 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.26 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND ND ND ND ND 2-May-16 EPA 8260 0.26 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.31 1.0 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.24 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.24 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.48 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.48 1.0 ND ND ND ND ND Vinyl Chloride 12-May-97 NR 5 ND ND 3.1 J NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 1.8 ND 1.3 2.0 ND NC 2L = 0.015 pg/L (10/23/07) 27-Nov-07 NR 1 0.75 J ND 0.69 J ND ND 27-May-08 0.62 1.0 1.3 ND 1.0 ND ND 4-Nov-08 0.62 1.0 0.67 J ND 1.0 ND ND 1-Jun-09 0.62 1.0 1.4 Dry 0.83 J ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.6 ND NC 2L = 0.03 pg/L (01/01/10) 14-Jun-10 0.62 1.0 1.3 ND 1.3 0.67 J ND 29-Nov-10 0.62 1.0 1.1 0.63 J 1.3 0.65 J ND 31-May-11 0.62 1.0 1.3 ND 1.0 0.81 J ND 19-Dec-11 0.62 1.0 1.2 ND 0.84 J ND ND 30-May-12 0.62 1.0 2.1 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND 10-Jun-13 0.62 1.0 1.4 ND 0.86 J ND ND 28-Oct-13 0.62 1.0 0.64 J ND ND ND ND 5-May-14 EPA 8260 0.62 1.0 0.65 J ND 0.76 J ND ND 20-Oct-14 EPA 8260 0.62 1.0 ND ND ND ND ND 18-May-15 EPA 8260 0.62 1.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 1 ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 ND ND 0.63 J ND ND 14-Dec-17 EPA 8260 0.62 1.0 0.69 J ND 0.71 J ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND 1.4 ND ND 5-Nov-19 EPA 8260D 0.24 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.24 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.24 1.0 ND 0.52 J ND ND ND 3-May-21 EPA 8260D 0.39 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.39 1.0 ND 0.51 J ND ND ND Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 27 of 28 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Method DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Date Xylene (Total) 7NC= 28-Apr-94 NR 5 5.1 15.0 ND NI ND 8-Nov-00 NR 5 ND ND ND NI ND 1-Oct-99 NR 5 ND 5.9 ND NI ND 530 pg/L (10/23/07) 2-May-00 NR 5 ND ND ND NI ND 31-May-01 NR 5 ND ND ND NI ND INC 2L = 500 pg/L (01/01/10) 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 4 ND 1.3 J ND ND ND 27-Nov-07 NR 5 ND 1.4 J ND ND ND 27-May-08 0.89 10.0 ND 1.5 J ND ND ND 4-Nov-08 0.66 10.0 ND 1.3 J ND ND ND INC 2L = 530 pg/L (10/23/07) 1-Jun-09 0.66 2.0 ND Dry ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND ND INC 2L = 500 pg/L (01/01/10) 14-Jun-10 0.66 2.0 ND 3.1 ND ND ND 29-Nov-10 0.66 2.0 ND 2.3 ND ND ND 31-May-11 0.66 2.0 ND 0.80 J ND ND ND 19-Dec-11 0.66 2.0 ND 0.89 J ND ND ND 30-May-12 0.66 2.0 ND ND ND ND ND 3-Dec-12 0.66 2.0 ND ND ND ND ND 10-Jun-13 0.66 5.0 ND ND ND ND ND 28-Oct-13 0.66 5.0 ND ND ND ND ND 5-May-14 EPA 8260 0.66 5.0 ND ND ND ND ND 20-Oct-14 EPA 8260 0.66 5.0 ND ND ND ND ND 18-May-15 EPA 8260 0.66 5.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 ND ND ND ND ND 6-May-19 EPA 8260D 1.50 2.0 ND 17.2 ND ND ND 5-Nov-19 EPA 8260D 0.63 1.0 ND ND ND ND -- 6-May-20 EPA 8260D 0.63 1.0 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.63 1.0 ND ND ND ND ND 3-May-21 EPA 8260D 0.34 1.0 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.34 1.0 ND ND ND ND ND 1,4-Dioxane (p-Dioxane) 6-May-19 EPA 8260D Mod. 1.2 2 ND 2.7 33.1 1.9 J ND INC 2L = 3 pg/L 5-Nov-19 EPA 8260D Mod. 1.2 2 ND 2.5 29.5 ND -- 6-May-20 EPA 8260D Mod. 1.2 2 ND 2.5 37.6 ND ND 9-Nov-20 EPA 8260D Mod. 1.2 2 ND 2.8 38.8 ND ND 3-May-21 EPA 8260D Mod. 0.86 2 ND 2.5 44.8 ND ND 1-Nov-21 EPA 8260D Mod. 0.86 2 ND 2.6 45.6 1.4 J ND Chloroethane 6-May-19 EPA 8260D 0.5 1 -- 1.7 ND -- ND NC 21 = 3000 pg/L 5-Nov-19 EPA 8260D 0.5 1 ND ND ND ND -- 6-May-20 EPA 8260D 0.5 1 ND ND ND ND ND 9-Nov-20 EPA 8260D 0.5 1 ND ND ND ND ND 3-May-21 EPA 8260D 0.7 1 ND ND ND ND ND 1-Nov-21 EPA 8260D 0.65 1 ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and Solid Waste Section Reporting Limit (SWSL) for December 2006 - 2017; INC PQL for 2018 - present). OIL = Laboratory detection limit NO = Not Detected at or above the RL (prior to Dec. 2006) or the OIL (after Dec. 2006). NA = No data available. NR = Not reported. NI = Not installed. NE = Not established. J = Estimated concentration less than the RL but greater than the DL. B = Blank -Qualified (Concentration suspected to reflect laboratory or field contamination). NC21- = North Carolina 2L Groundwater Standards (15A NCAC 2L). IMAC = INC Interim Maximum Allowable Concentration. Bold values are greater than the NC21- Standards or IMAC. Historical data between 1994-1999 available upon request Burke County- East Burke Landfill LaBelle Associates Permit No. 12-02 28 of 28 TABLE A2-3: Historical Surface Water Constituents Sample AMMO Collection EPA Method DL RL SW-1 SW-2 Blanks Date INORGANICS Antimony (Dissolved) 29-Jun-21 EPA 6010D 3 5 4.7 J ND P4 -- Arsenic 29-May-07 NR 10 Dry 2.3 1 ND 27-Nov-07 NR 10 Dry 2.8 1 ND NC 2B/EPA NC= 10 pg/L(03/28/08) 27-May-08 2.7 10.0 Dry ND ND 04-Nov-08 2.6 10.0 Dry ND 4.8 1 01-Jun-09 2.6 10.0 Dry ND ND 19-Nov-09 2.7 10.0 ND ND ND NC 2B= 10 pg/L(05/01/07) 14-1un-10 2.7 10.0 ND 3.3 1 ND 29-Nov-30 2.7 10.0 ND ND ND 31-May-11 2.7 10.0 ND ND ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03-Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND ND ND 28-0ct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-0ct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry 3.2 1 ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 5.0 10.0 Dry ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND 03-Dec-18 EPA 6010 5.0 10.0 ND ND ND 06-May-19 EPA 6010D 5.0 10.0 ND ND NO 05-Nov-19 EPA 6010D 5.0 10.0 ND ND - O6-May-20 EPA 6010D 4.7 10.0 ND ND - 09-Nov-20 EPA 6010D 4.7 10.0 ND 6.1 1 - 03-May-21 EPA 6010D 4.7 10.0 ND 5.5 1 - Resample-> 29-Jun-21 EPA 6010D 4.7 10.0 ND ND - 01-Nov-21 EPA 6010D 4.7 10.0 - 6.9 1,6 ND Arsenic (Dissolved) 29-Jun-21 EPA 6010D 4.7 10.0 9.7 ND P4 P, Barium Nov-97 NR 100 ND 1000 NA May-98 NR 100 ND ND ND Nov-98 NR 100 ND ND ND May-99 NR 5 18.0 19.0 ND Oct-99 NR 500 ND ND ND May-00 NR 500 ND ND ND Nov-00 NR 500 Dry ND ND May-01 NR 500 Dry ND ND Nov-01 NR 500 Dry ND ND May-02 NR 500 Dry ND ND Nov-02 NR 500 ND ND ND May-03 NR 500 ND ND ND Nov-03 NR 500 ND ND ND May-04 NR 500 Dry ND ND Nov-04 NR 500 ND ND ND May-05 NR 500 Dry ND ND Nov-05 NR 500 Dry ND ND 23-May-06 NR 500 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 100 Dry 44.1 1 ND 27-Nov-07 NR 100 Dry 46.5 1 0.30 J Nc 2B/EPA NC=1,00o ug/L(03/28/08) 27-May-O8 0.2 100 Dry 48.8 1 0.41 J 04-Nov-08 0.20 100 Dry 51.7 B 10.5 J O1-Jun-09 0.20 100 Dry 41.2 B 15.2 J 19-Nov-09 0.20 100 81.4 B 40.5 B 19.8 J NC 2B=1,000 pg/L(05/01/07) 14-Jun-10 0.20 100 111 39.8 J 0.58 J 29-Nov-10 0.20 100 94.7 1 39.2 1 ND 31-May-11 0.20 100 92.9 1 37.6 1 ND 19-Deo-11 5.0 100 Dry 38.2 1 ND 29-May-12 5.0 100 Dry 38.5 1 ND 03-Deo-12 5.0 100 Dry 43.0 1 ND 10-Jun-13 5.0 100 21.3 B 86.4 1 13.7 J 28-0ct-13 5.0 100 15.4 1 36.8 1 ND 05-May-14 EPA 6010 5.0 100 13.7 1 44.5 1 ND 20-0ct-14 EPA 6010 5.0 100 13.3 1 39.8 1 ND 18-Map15 EPA 6010 2.5 100 Dry 38.9 1 ND 07-Deo-15 EPA 6010 2.5 100 Dry 54.3 1 ND 02-May-16 EPA 6010 2.5 100 Dry 41.6 1 ND 12-D-16 EPA 6010 2.5 100 Dry 45.4 1 ND 26-Jun-17 EPA 6010 2.5 100 Dry 53.1 1 2.5 J 14-May-18 EPA 6010 2.5 100 23.2 1 41.9 1 ND 03-Deo-18 EPA 6010 2.5 5 39.1 49.3 ND 06-May-19 EPA 6010D 2.5 5 41.4 47.9 ND 05-Nov-19 EPA 6010D 2.5 5 80.9 67.6 - O6-May-20 EPA 6010D 3.5 5 61.4 95.3 - 09-Nov-20 EPA 6010D 3.5 5 119 50.0 - 03-Map21 EPA 6010D 3.5 5 142 63.1 - Resample-> 29-Jun-21 EPA 6010D 3.5 5 139 39.0 - 01-Nov-21 EPA 6010D 3.5 5 - 53.6 ND Barium (Dissolved) 29-Jun-21 EPA 6010D 3.5 5 96.1 P4 31.4 P4 Burke County - East Burke Landfill La Bella Associates Permit No. 12-02 1 of 11 TABLE A2-3: Historical Surface Water Constituents AnaVe Sample Collection Data EPA Method DL RL SW-1 SW-2 Blanka Beryllium Nov-02 NR 2 3.2 3.6 ND May-03 NR 2 ND ND ND Nov-03 NR 2 ND ND ND May-04 NR 2 Dry ND ND Nov-04 NR 2 ND ND ND May-05 NR 2 Dry ND ND Nov-05 NR 2 Dry ND ND 23Ma106 NR 2 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 1 Dry ND ND 27-Nov-07 NR 1 Dry ND ND Nc 23/EPA Nc-6.54g/L(03/28/os) 27-May-08 0.1 1.0 Dry ND ND 04-Nov-08 0.10 1.0 Dry ND ND 03-Jun-09 0.10 1.0 Dry ND ND 19-Nov-09 0.10 1.0 ND ND ND NC 2B=NE yg/L(05/01/07) 14-Jun-10 0.10 1.0 ND NO ND 29-Nov-10 0.10 1.0 ND ND ND 31-May-11 0.10 1.0 ND ND ND 19-Dec-11 1.0 1.0 Dry ND ND 29-May-12 1.0 1.0 Dry ND ND 03Dee-12 1.0 1.0 Dry ND ND 10-Jun-13 1.0 1.0 ND ND ND 28-0ct-13 1.0 1.0 ND ND ND 05-May-14 EPA 6010 1.0 1.0 ND ND ND 20-0ct-14 EPA 6010 1.0 1.0 ND ND ND 18-May-15 EPA 6010 0.5 1.0 Dry ND ND 07-Dec-15 EPA 6010 0.5 1.0 Dry ND ND 02-May-16 EPA 6010 0.5 1.0 Dry ND ND 12-Dec-16 EPA 6010 0.5 1.0 Dry ND ND 26-Jun-17 EPA 6010 0.5 1.0 Dry ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND 03Dee-18 EPA 6010 0.5 1.0 ND ND ND 06-May-19 EPA 6010D 0.5 1.0 ND 0.86 1 ND 05-Nov-19 EPA 6010D 0.2 1.0 ND 0.22 1 ND 06-May-20 EPA 6010D 0.7 1.0 ND ND - 09-Nov-20 EPA 6010D 0.7 1.0 ND ND - 03-May-21 EPA 6010D 0.7 1.0 1.2 ND - Resample-> 29-Jun-21 EPA 6010D 0.7 1.0 ND ND - 01-Nov-21 EPA 6010D 0.7 1.0 - ND ND Cadmium Oct-99 NR 1 ND 1.0 ND May-00 NR 1 ND ND ND Nov-00 NR 1 Dry ND ND May-01 NR 1 Dry ND ND Nov-01 NR 1 Dry ND ND May-02 NR 1 Dry 1.0 ND Nov-02 NR 1 1.2 1.5 ND May-03 NR 1 ND ND ND Nov-03 NR 1 ND ND ND May-04 NR 1 Dry ND ND Nov-04 NR 1 ND ND ND May-05 NR 1 Dry ND ND Nov-05 NR 1 Dry ND ND 23May-06 NR 1 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 1 Dry ND ND 27-Nov-07 NR 1 Dry ND ND NC 2B/EPA NC = 2 yg/L l03/28/06) 27-May-08 0.5 1.0 Dry ND ND 04-Nov-08 0.50 1.0 Dry ND ND 03-Jun-09 0.50 1.0 Dry ND ND 19-Nov-09 0.50 1.0 ND ND ND NC 2B=NE yg/L(05/01/07) 14-Jun-10 0.50 1.0 ND ND ND 29-Nov-30 0.50 1.0 ND ND ND 31-May-11 0.50 1.0 ND ND ND 19-Dec-11 1.0 1.0 Dry ND ND 29-May-12 1.0 1.0 Dry ND ND 03Dee-12 1.0 1.0 Dry ND ND 10-Jun-13 1.0 1.0 ND ND ND 28-0ct-13 1.0 1.0 ND ND ND 05-May-14 EPA 6010 1.0 1.0 ND ND ND 20-0ct-14 EPA 6010 1.0 1.0 ND ND ND 18-May-15 EPA 6010 0.5 1.0 Dry ND ND 07-Dec-15 EPA 6010 0.5 1.0 Dry ND ND 02-May-16 EPA 6010 0.5 1.0 Dry ND ND 12-Dec-16 EPA 6010 0.5 1.0 Dry ND ND 26-Jun-17 EPA 6010 0.5 1.0 Dry ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND 03Dee-18 EPA 6010 0.5 1.0 ND ND ND 06-May-19 EPA 6010D 0.5 1.0 ND 1.2 ND 05-Nov-19 EPA 6010D 0.5 1.0 ND ND ND 06-May-20 EPA 6010D 0.4 1.0 ND ND - 09-Nov-20 EPA 6010D 0.4 1.0 ND ND - 03-May-21 EPA 6010D 0.4 1.0 ND ND - Resample-> 29-Jun-21 EPA 6010D 0.4 1.0 0.43 1 ND - 01-Nov-21 EPA 6010D 0.4 1.0 - ND NO Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 2 of 11 TABLE A2-3: Historical Surface Water Constituents AnaVe Sample Collection Data EPA Method DL RL SW-1 SW-2 Blanka Chmmmm May-97 NR 1 2.0 1.0 ND Nov-97 NR 1 ND ND NA May-98 NR 1 ND ND ND Nov-98 NR 1 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 10 ND ND ND May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-01 NR 10 Dry ND ND Nov-01 NR 10 Dry ND ND May-02 NR 10 Dry ND ND Nov-02 NR 10 ND ND ND May-03 NR 10 ND ND ND Nov-03 NR 10 ND ND ND May-04 NR 10 Dry ND ND Nov-04 NR 10 ND ND ND May-05 NR 10 Dry ND ND Nov-05 NR 10 Dry ND ND 23May-06 NR 10 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 10 Dry ND ND 27-Nov-07 NR 10 Dry ND ND NC 2B/EPA NC = 50 yg/L(03/28/08) 27-May-08 0.4 10.0 Dry ND 0.85 J 04-Nov-08 0.40 10.0 Dry ND ND 03-Jun-09 0.40 10.0 Dry ND ND NC 2B/EPA NC = 20 yg/L(02/05/10) 19-Nov-09 0.40 10.0 0.48 B ND 1.1 J NC 2B= 20 pg/L(05/01/07) 14-Jun-10 0.40 10.0 7 1 0.42 1 ND 29-Nov-30 0.40 10.0 ND ND ND 31-May-11 0.40 10.0 1.2 B 1.2 B 0.73 1 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03Dee-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND 16.7 ND 28-0ct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-0ct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03Dee-18 EPA 6010 2.5 5.0 ND ND ND 06May-19 EPA 6010D 2.5 5.0 ND ND ND 05-Nov-19 EPA 6010D 2.5 5.0 2.8 1 ND ND 06May-20 EPA 6010D 3.7 5.0 ND ND - 09-Nov-20 EPA 6010D 3.7 5.0 ND ND - 03-May-21 EPA 6010D 3.7 5.0 39.8 13.8 - Resample-> 29-Jun-21 EPA 6010D 3.7 5.0 ND ND - 01-Nov-21 EPA 6010D 3.7 5.0 - ND ND Cobalt May-98 NR 1.0 ND 3.0 ND Nov-98 NR 1.0 ND ND ND May-99 NR 5.0 ND ND ND Oct-99 NR 10 ND ND ND May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-01 NR 10 Dry ND ND Nov-01 NR 10 Dry ND ND May-02 NR 10 Dry ND NA Nov-02 NR 10 ND ND ND May-03 NR 10 23.0 ND ND Nov-03 NR 10 34.0 10.0 ND May-04 NR 10 Dry 10.0 ND Nov-04 NR 10 16.0 12.0 ND May-05 NR 10 Dry ND ND Nov-05 NR 10 Dry 11.0 ND 23May-06 NR 10 Dry 12.4 ND 06-Nov-06 NR 10 17.5 ND ND 29-May-07 NR 10 Dry 10.7 ND 27-Nov-07 NR 10 Dry 10.4 ND NC 2B/EPA NC = 190 yg/L(03/28/08) 27-May-08 0.6 10.0 Dry 11.3 ND 05-Nov-08 0.60 10.0 Dry 14.9 B 3.5 1 03-Jun-09 0.60 10.0 Dry 15.0 B 3.3 1 NC 2B=NE pg/L(05/01/07) 19-Nov-09 0.60 10.0 ND 5.5 1 ND 14-Jun-10 0.60 10.0 64.4 11.0 ND 29-Nov-10 0.60 10.0 54.1 10.3 ND 31-May-11 0.60 10.0 23.6 8.1 1 ND 19-Dec-11 5.0 10.0 Dry 8.2 1 ND 29-May-12 5.0 10.0 Dry 8.9 1 ND 03Dee-12 5.0 10.0 Dry 11.7 ND 10-Jun-13 5.0 10.0 ND 18.2 ND 28-0ct-13 5.0 10.0 ND 11.4 ND 05-May-14 EPA 6010 5.0 10.0 ND 6.9 1 ND 20-0ct-14 EPA 6010 5.0 10.0 ND 8.2 1 ND 18-May-15 EPA 6010 2.5 10.0 Dry 8.5 1 ND 07-Dec-15 EPA 6010 2.5 10.0 Dry 6.2 1 ND 02-May-16 EPA 6010 2.5 10.0 Dry 6.3 1 ND 12-Dec-16 EPA 6010 2.5 10.0 Dry 9.2 1 ND 26-Jun-17 EPA 6010 2.5 10.0 Dry 10.0 1 ND 14-May-18 EPA 6010 2.5 10.0 ND 8.5 1 ND 03Dee-18 EPA 6010 2.5 5.0 2.7 1 7.4 ND ISTV = 3 pg/L 06-May-19 EPA 6010D 2.5 5.0 3.5 1 7.8 ND 05-Nov-19 EPA 6010D 2.5 5.0 8.8 8.4 ND Resample> 23-Jan-20 EPA 6010D 1.1 5.0 11.0 06May-20 EPA 6010D 3.6 5.0 9.3 10.6 - 09- Nov -20 EPA 6010D 3.6 5.0 13.1 9.1 - 03-May-21 EPA 6010D 3.6 5.0 15.0 7.3 - Resample-> 29- Jun -21 EPA 6010D 3.6 5.0 15.1 ND - 01- Nov -21 EPA 6010D 3.6 5.0 - 12 ND Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 3 of 11 TABLE A2-3: Historical Surface Water Constituents Sample AnaKe Collection Emb- EPA Method DL RL SW-1 Cobalt (Dissolved) 29-Jun-21 EPA 6010D 3.6 5.0 5.9 P4 ND P4 Copper May-97 NR 10 40.0 ND ND Nov-97 NR 10 ND ND ND May-98 NR 10 ND ND ND Nov-98 NR 10 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 200 ND ND ND May-00 NR 200 ND ND ND Nov-00 NR 200 Dry ND ND May-01 NR 200 Dry ND ND Nov-01 NR 200 Dry ND ND May-02 NR 200 Dry ND ND Nov-02 NR 200 ND ND ND May-03 NR 200 ND ND ND Nov-03 NR 200 ND ND ND May-04 NR 200 Dry ND ND Nov-04 NR 200 ND ND ND May-05 NR 200 Dry ND ND Nov-05 NR 200 Dry ND ND 23May-06 NR 200 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 10 Dry ND ND 27-Nov-07 NR 10 Dry ND ND NC 2B/EPA NC=7yg/L t03/28/M) 27-May-08 0.3 10.0 Dry ND ND 05-Nov-08 0.30 10.0 Dry ND 0.94 J 03-Jun-09 0.30 10.0 Dry ND ND 19-Nov-09 0.30 10.0 1.1 1 ND ND NC 2B=NE yg/L(05/01/07) 14-Jun-10 0.30 10.0 1.9 B ND 3.4 1 29-Nov-10 0.30 10.0 ND ND ND 31-May-11 0.30 10.0 0.47 1 ND ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03Dac-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND 7.7 B 10.8 28-0ct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-0ct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03Dec-18 EPA 6010 2.5 5.0 ND ND ND 0EMay-19 EPA 6010D 2.5 5.0 ND 2.8 1 ND 05-Nov-19 EPA 6010D 2.5 5.0 ND ND ND 06-May-20 EPA 6010D 4.3 5.0 ND ND - 09-Nov-20 EPA 6010D 4.3 5.0 ND ND - 03May-21 EPA 6010D 4.3 5.0 123 4.6 1 - Resample-> 29-Jun-21 EPA 6010D 4.3 5.0 ND ND 01-Nov-21 EPA 6010D 4.3 5.0 - ND ND Lead 29-May-07 NR 10 Dry 2.9 B 6.1 1 27-Nov-07 NR 10 Dry ND ND NC 2B/EPA NC= 25 yg/L(03/28/08) 27-May-08 4 10.0 Dry ND ND 04-Nov-08 4.0 10.0 Dry ND ND 01-Jun-09 4.0 10.0 Dry ND ND 19-Nov-09 4.0 10.0 ND ND ND NC 2B=NE u9/L(05/01/07) 14-Jun-10 4.0 10.0 ND ND ND 29-Nov-30 4.0 10.0 ND ND ND 31-May-11 4.0 10.0 ND ND ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND 8.7 1 ND 28-0ct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-0ct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03Dec-18 EPA 6010 2.5 5.0 ND ND ND 06-May-19 EPA 6010D 2.5 5.0 ND 2.7 1 ND 05-Nov-19 EPA 6010D 2.5 5.0 ND ND ND 06-May-20 EPA 6010D 4.5 5.0 ND ND - 09-Nov-20 EPA 6010D 4.5 5.0 ND ND - 03-May-21 EPA 6010D 4.5 5.0 14A 6.7 - Resample-> 29-Jun-21 EPA 6010D 4.5 5.0 ND 52 01-Nov-21 EPA 6010D 4.5 5.0 - ND NO Burke County - East Burke Landfill La Bella Associates Permit No. 12-02 4 of 11 TABLE A2-3: Historical Surface Water Constituents Sample Analyte Collection EPA Method DL RL SW-1 SW-2 Blanka Data Nickel May-97 NR 50 4500 140 ND Nov-97 NR 50 ND ND ND May-98 NR 50 ND ND ND Nov-98 NR 50 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 50 ND ND ND May-00 NR 50 ND ND ND Nov-00 NR 50 Dry ND ND May-01 NR 50 Dry ND ND Nov-01 NR 50 Dry ND ND May-02 NR 50 Dry ND ND Nov-02 NR 50 ND ND ND May-03 NR 50 ND ND ND Nov-03 NR 50 ND ND ND May-04 NR 50 Dry ND ND Nov-04 NR 50 ND ND ND May-05 NR 50 Dry ND ND Nov-05 NR 50 Dry ND ND 23May-06 NR 50 Dry ND ND 06-Nov-06 NR 50 ND ND ND 29-May-07 NR 50 Dry 3.7 1 ND 27-Nov-07 NR 50 Dry 4.3 1 ND INC 2B/EPA NC = 25 yg/L l03/28/08) 27-May-08 1.7 50.0 Dry 6.0 1 ND 04-Nov-08 1.7 50.0 Dry 7.9 B 2.2 1 03-Jun-09 1.7 50.0 Dry 4.7 1 ND 19-Nov-09 1.7 50.0 4.8 B 3.6 B 2.2 1 NC 2B= 25 pg/L(05/01/07) 14-Jun-10 1.7 50.0 14.1 1 3.3 1 ND 29-Nov-10 1.7 50.0 5.3 1 2.4 1 ND 31-May-11 1.7 50.0 7.6 B 5.2 B 2.3 1 19-Dec-11 5.0 50.0 Dry ND ND 29-May-12 5.0 50.0 Dry ND ND 03Dec-12 5.0 50.0 Dry ND ND 10-Jun-13 5.0 50.0 ND 12.8 1 ND 28-0ct-13 5.0 50.0 ND ND ND 05-May-14 EPA 6010 5.0 50.0 ND ND ND 20-0ct-14 EPA 6010 5.0 50.0 ND ND ND 18-May-15 EPA 6010 2.5 50.0 Dry 4.4 1 ND 07-Dec-15 EPA 6010 2.5 50.0 Dry 4.7 1 ND 02-May-16 EPA 6010 2.5 50.0 Dry 3.8 1 ND 12-Dec-16 EPA 6010 2.5 50.0 Dry 4.8 1 ND 26-Jun-17 EPA 6010 2.5 50.0 Dry 5.7 1 ND 14-May-18 EPA 6010 2.5 50.0 ND 5 1 ND 03Dec-18 EPA 6010 2.5 5.0 ND 4.3 1 ND 06May-19 EPA 6010D 2.5 5.0 2.9 1 4.7 1 ND 05- Nov -19 EPA 6010D 0.9 5.0 5.7 4.8 1 ND 06May-20 EPA 6010D 3.5 5.0 5.1 7.7 - 09-Nov-20 EPA 6010D 3.5 5.0 10.8 4.1 J - 03-May-21 EPA 6010D 3.5 5.0 21A 7.6 - Resample-> 29-Jun-21 EPA 6010D 3.5 5.0 10.5 ND - 01-Nov-21 EPA 6010D 3.5 5.0 - 5.5 ND Nickel(Dissolved) 29-Jun-21 EPA 6010D 3.5 5.0 323 P4 ND P4 Selenium 29-Jun-21 EPA 6010D 4.7 10.0 5.8 1 ND - 01-Nov-21 EPA 6010D 4.7 10.0 - ND ND Silver 27-May-08 0.1 10.0 Dry 0.11 B 0.14 J 04-Nov-08 0.10 10.0 Dry 0.41 B 0.20 J 03-Jun-09 0.10 10.0 Dry 0.12 1 ND 19-Nov-09 0.10 10.0 ND 0.14 1 ND NC 2B=NE ug/L(05/01/07) 14-Jun-10 0.10 10.0 ND ND ND 29-Nov-30 0.10 10.0 ND ND ND 31-May-11 0.10 10.0 1.0 1 0.68 1 ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND ND ND 28-0ct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-0ct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03Dec-18 EPA 6010 2.5 5.0 ND ND ND 06May-19 EPA 6010D 2.5 5.0 ND ND ND 05-Nov-19 EPA 6010D 2.5 5.0 ND ND ND 06May-20 EPA 6010D 2.5 5.0 ND ND - 09-Nov-20 EPA 6010D 2.5 5.0 ND ND - 03May-21 EPA 6010D 2.5 5.0 ND ND - Resample-> 29-Jun-21 EPA 6010D 2.5 5.0 ND ND - 01-Nov-21 EPA 6010D 2.5 5.0 - ND ND Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 5 of 11 TABLE A2-3: Historical Surface Water Constituents AnaVe Sample Collection Date EPA Method DL RL SW-1 SW-2 Blanks Thallium Nov-97 NR 1 ND 1.0 ND May-98 NR 1 ND ND ND Nov-98 NR 1 ND ND ND May-99 NR 2 ND ND ND Oct-99 NR 10 ND ND ND May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-01 NR 10 Dry ND ND Nov-01 NR 10 Dry ND ND May-02 NR 10 Dry ND ND Nov-02 NR 10 ND ND ND May-03 NR 10 ND ND ND Nov-03 NR 10 ND ND ND May-04 NR 10 Dry ND ND Nov-04 NR 10 ND ND ND May-05 NR 10 ND ND ND Nov-05 NR 10 Dry ND ND 23May-06 NR 10 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 5.5 Dry 0.168 1 ND 27-Nov-07 NR 5.5 Dry 0.136 1 ND NC 2B/EM NC- 0.24 V4/L(03/28/08) 27-May-08 3 5.5 Dry ND ND 04-Nov-08 3.0 5.5 Dry ND ND 01-Jun-09 3.0 5.5 Dry ND ND 19-Nov-09 3.0 5.5 ND ND ND NC 2B=NE yg/L(05/01/07) 14-Jun-10 3.0 5.5 3.0 1 NO ND 29-Nov-10 3.0 5.5 ND ND ND 31-May-11 3.0 5.5 ND ND ND 19-DeC-11 5.4 5.5 Dry ND ND 29-May-12 5.4 5.5 Dry ND ND 03Dac-12 5.4 5.5 Dry ND ND 10-Jun-13 5.4 5.5 ND ND ND 28-0Ct-13 5.4 5.5 ND ND ND 05-May-14 EPA 6010 5.4 5.5 ND ND ND 20-0ct-14 EPA 6010 5.4 5.5 ND ND ND 18-May-15 EPA 6010 5.0 5.5 Dry ND ND 07-Dec-15 EPA 6010 5.0 5.5 Dry ND ND 02-May-16 EPA 6010 5.0 5.5 Dry ND ND 12-Dec-16 EPA 6010 5.0 5.5 Dry ND 5.5 1 26-Jun-17 EPA 6020E 0.0 5.5 Dry 0.12 1 ND 14-May-18 EPA 6020 0.5 5.5 ND ND ND 03Dec-18 EPA 6020E 0.06 0.1 ND 0.11 ND 0EMay-19 EPA 6020E 0.06 0.1 0.072 1 0.10 ND 05-Nov-19 EPA 6020E 0.06 0.1 0.15 0.17 ND Resample> 23Jan-20 EPA 6020E 0.06 0.1 0.14 0.12 ND 0EMay-20 EPA 6020E 0.06 0.1 0.13 0.16 - 09-Nov-20 EPA 6020E 0.05 0.1 0.17 0.11 - 03-May-21 EPA 6020E 0.05 1 0.36 1 0.15 1 - Resample-> 29-Jun-21 EPA 6020E 0.05 0.47 0.16 1 ND - 01-Nov-21 EPA 6020E 0.05 0.47 - 0.12 1 ND Vanadium 01-Jun-09 0.20 25.0 Dry 0.24 B 1.2 1 NC 2B/EPA NC - NE V€/L(03/28/08) 19-Nov-09 0.20 25.0 0.33 B 0.30 B 0.58 J NC 2B=NE yg/L(05/01/07) 14-Jun-10 0.20 25.0 5.9 1 0.22 B 0.25 J 29-Nov-30 0.20 25.0 ND ND ND 31-May-11 0.20 25.0 ND ND ND 19-DeC-11 5.0 25.0 Dry ND ND 29-May-12 5.0 25.0 Dry ND ND 03Dec-12 5.0 25.0 Dry ND ND 10-Jun-13 5.0 25.0 ND 21.2 1 ND 28-0ct-13 5.0 25.0 ND ND ND 05-May-14 EPA 6010 5.0 25.0 ND ND ND 20-0ct-14 EPA 6010 5.0 25.0 ND ND ND 18-May-15 EPA 6010 2.5 25.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 25.0 Dry ND ND 02-May-16 EPA 6010 2.5 25.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 25.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 25.0 Dry ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND 03Dec-18 EPA 6010 2.5 5.0 ND ND ND 0EMay-19 EPA 6010D 2.5 5.0 ND ND ND 05-Nov-19 EPA 6010D 1.3 5.0 ND 1.4 1 ND 06-May-20 EPA 6010D 3.9 5.0 ND ND - 09-Nov-20 EPA 6010D 3.9 5.0 4.9 1 ND - 03-May-21 EPA 6010D 3.9 5.0 38.4 14.5 - Resample-> 29-Jun-21 EPA 6010D 3.9 5.0 ND ND - 01-Nov-21 EPA 6010D 3.9 5.0 - 10.8 ND Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 6 of 11 TABLE A2-3: Historical Surface Water Constituents Sample Anslyte Collection EPA Method DL RL SW-1 SW-2 Blanks Data Zlnc Oct NR 10 10.0 10.0 14.0 Jun-95 NR 10 ND ND 12.0 Oct-95 NR 10 NA 46.0 ND Oct-96 NR 10 ND ND NA May-97 NR 10 40.0 10.0 ND Nov-97 NR 10 ND ND NA May-98 NR 10 ND ND ND Nov-98 NR 10 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 50 ND ND ND May-00 NR 50 ND ND ND Nov-00 NR 50 Dry ND ND May-01 NR 50 Dry ND ND Nov-01 NR 50 Dry ND ND May-02 NR 50 Dry ND ND Nov-02 NR 50 ND ND ND May-03 NR 50 ND ND ND Nov-03 NR 50 ND ND ND May-04 NR 50 Dry ND ND Nov-04 NR 50 ND ND ND May-05 NR 50 Dry ND ND Nov-05 NR 50 Dry ND ND 23May-06 NR 50 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 10 Dry 1.2 B 2.0 1 27-Nov-07 NR 10 Dry ND ND NC 28/EPA NC = 50 pg/L l03/28/08) 27-May-08 0.4 10.0 Dry 2.3 B 4.8 1 04-Nov-08 0.40 10.0 Dry ND 8.9 1 03-Jun-09 0.40 10.0 Dry 8.2 B 83.0 19-Nov-09 0.40 10.0 9.1 B 31.9 3.5 1 NC 2B=NE pg/L(05/01/07) 14-Jun-10 0.40 10.0 18.0 B ND 10.1 29-Nov-10 0.40 10.0 8.3 1 0.44 1 ND 31-May-11 0.40 10.0 7.7 B 8.9 B 13.7 19-Dec-11 10.0 10.0 Dry ND ND 29-May-12 10.0 10.0 Dry ND ND 03Dee-12 10.0 10.0 Dry ND ND 10-Jun-13 10.0 10.0 ND 30.7 B 76.3 28-0ct-13 10.0 10.0 ND ND ND 05-May-14 EPA 6010 10.0 10.0 ND ND ND 20-0ct-14 EPA 6010 10.0 10.0 ND ND ND 18-May-15 EPA 6010 5.0 10.0 Dry ND ND 07-Dec-15 EPA 6010 5.0 10.0 Dry 5.5 B 7.2 1 02-May-16 EPA 6010 5.0 10.0 Dry ND ND 12-Dec-16 EPA 6010 5.0 10.0 Dry ND ND 26-Jun-17 EPA 6010 5.0 10.0 Dry ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND 03Dee-18 EPA 6010 5.0 10.0 ND ND ND 0EMay-19 EPA 6010D 5.0 10.0 ND ND ND 05-Nov-19 EPA 6010D 3.9 10.0 14.6 9.1 1 ND 06-May-20 EPA 6010D 9.5 10.0 ND ND - 09-Nov-20 EPA 6010D 9.5 10.0 ND ND - 03May-21 EPA 6010D 9.5 10.0 48.8 22.8 - Resample-> 29-Jun-21 EPA 6010D 9.5 10.0 ND ND - 01-Nov-21 EPA 6010D 9.5 10.0 - ND ND Organic Compounds Acetone 27-Nov-07 NR 100 Dry 4.4 B 4.3 J Ne 23/EPA NC= 2.000 yg/L(03/28/08) 27-May-08 20 100 Dry ND ND 04-Nov-08 20.0 100 Dry ND ND 01-Jun-09 20.0 100 Dry ND 3.2 1 19-Nov-09 2.2 100 ND ND 3.8 1 NC 2B=NE pg/L(05/01/07) 14-Jun-10 2.2 100 5.5 B ND 8.9 1 29-Nov-10 2.2 100 ND ND 2.3 1 31-May41 2.2 100 5.8 B 2.3 B 3.9 1 19-Deo-11 2.2 100 Dry ND 6.6 1 29-May42 2.2 100 Dry ND ND 03Deo-12 10.0 100.0 Dry ND ND 10-Jun-13 10.0 100.0 ND ND ND 28-0ct-13 10.0 100.0 ND ND ND 05-May44 EPA 8260 10.0 100.0 ND ND ND 20-0ct-14 EPA 8260 10.0 100.0 ND ND ND 18-May45 EPA 8260 10.0 100.0 Dry ND ND 07-Deo-15 EPA 8260 10.0 100.0 Dry ND ND 02-May46 EPA 8260 10.0 100.0 Dry ND ND 12-Deo-16 EPA 8260 10.0 100.0 Dry ND ND 26-Jun-17 EPA 8260 10.0 100.0 Dry 20.9 B 23.0 J 14-May48 EPA 8260 10.0 100.0 ND ND ND 03Deo-18 EPA 8260 10.0 25.0 ND ND ND 06-May49 EPA 8260D 8.2 25.0 ND ND ND 05-Nov-19 EPA 8260D 6.2 25.0 ND ND ND 06-Map20 EPA 8260D 6.2 25.0 ND ND - 09-Nov-20 EPA 8260D 6.2 25.0 ND ND - 03May-21 EPA 8260D 5.1 25.0 ND ND - 01-Nov-21 EPA 8260D 5.1 25.0 - ND ND Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 7 of 11 TABLE A2-3: Historical Surface Water Constituents Sample AnaVe Collection EPA Method DL RL SW-1 SW-2 Blanks Data Benzene 19- No, -09 0.25 1.0 3.6 0.76 1 ND Resample> 15 Feb-10 0.25 1.0 ND NS ND NC 213 = 1.19 pg/L (05/01,/07) 14-Jun-10 0.25 1.0 ND ND ND 29-Nov-30 0.25 1.0 ND ND ND 31-May-11 0.25 1.0 ND ND ND 19-Dec-11 0.25 1.0 Dry ND ND 29-May-12 0.25 1.0 Dry ND ND 03-Dec-12 0.25 1.0 Dry ND ND 10-Jun-13 0.25 1.0 ND ND ND 28-0ct-13 0.25 1.0 ND ND ND 05-May-14 EPA 8260 0.25 1.0 ND ND ND 20-0ct-14 EPA 8260 0.25 1.0 ND ND ND 18-May-15 EPA 8260 0.25 1.0 Dry ND ND 07-Dec-15 EPA 8260 0.25 1.0 Dry ND ND 02-May-16 EPA 8260 0.25 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.25 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.25 1.0 Dry ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND 03-Dec-18 EPA 8260 0.25 1.0 ND ND ND 06May-19 EPA 8260D 0.20 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.15 1.0 ND ND ND 06May-20 EPA 8260D 0.15 1.0 ND ND - 09-Nov-20 EPA 8260D 0.15 1.0 ND ND - 03-May-21 EPA 8260D 0.34 1.0 ND ND - 01-Nov-21 EPA 8260D 0.34 1.0 - ND ND Chlorobenzene 19-Nov-09 0.23 3.0 0.70 1 0.61 1 ND BC 2B/EPA NC- 130 yg/L(03/28/08) 14-Jun-10 0.23 3.0 ND ND ND NC 2B= 488 ug/L(05/01/07) 29-Nov-10 0.23 3.0 ND ND ND 31-May-11 0.23 3.0 ND ND ND 19-DeC-11 0.23 3.0 Dry ND ND 29-May-12 0.23 3.0 Dry ND ND 03-DBc-12 0.23 3.0 Dry ND ND 10-Jun-13 0.23 3.0 ND ND ND 28-0ct-13 0.23 3.0 ND ND ND 05-May-14 EPA 8260 0.23 3.0 ND ND ND 20-0ct-14 EPA 8260 0.23 3.0 ND ND ND 18-May-15 EPA 8260 0.23 3.0 Dry ND ND 07-Dec-15 EPA 8260 0.23 3.0 Dry ND ND 02-May-16 EPA 8260 0.23 3.0 Dry ND ND 12-Dec-16 EPA 8260 0.23 3.0 Dry ND ND 26Jun-17 EPA 8260 0.23 3.0 Dry ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND 03-Dec-18 EPA 8260 0.23 1.0 ND ND ND 06May-19 EPA 8260D 0.53 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.23 1.0 ND ND ND 06May-20 EPA 8260D 0.23 1.0 ND ND - 09-Nov-20 EPA 8260D 0.23 1.0 0.32 1 ND - 03-May-21 EPA 8260D 0.28 1.0 ND ND - 01-Nov-21 EPA 8260D 0.28 1.0 - ND ND 1,4-Dioxane(R-Dioxane) 03-Deo-18 EPA 8260E 1.90 2.0 6.2 1o.1 ND ISN = 0.35 pgL 06May-19 EPA 8260D Mod. 1.20 2.0 7.40 92 ND 05-Nov-19 EPA 8260D Mod. 1.20 2.0 12.60 12.3 ND 06May-20 EPA 8260D Mod. 1.20 2.0 12.60 189 - 09-Nov-20 EPA 8260D Mod. 1.20 2.0 34AO 12.9 - 03-May-21 EPA 8260D Mod. 0.86 2.0 4.30 3.7 - 01-Nov-21 EPA 8260D Mod. 0.86 2.0 - 16.5 ND 1,4-Dichlombenzene 29-May-07 NR 1 Dry 0.94 1 ND 27-Nov-07 NR 1 Dry ND ND NC 28/EPA NC- 63 yg/L(03/28/08) 27-May-08 0.33 1.0 Dry 0.64 1 ND 04-Nov-08 0.33 1.0 Dry 0.96 1 ND 01-Jun-09 0.33 1.0 Dry 0.76 1 ND 19-Nov-09 0.33 1.0 4.8 4.9 ND NC 2B= 488 Ug/L(05/01/07) 14-Jun-10 0.33 1.0 ND 0.63 1 ND 29-Nov-10 0.33 1.0 0.78 1 ND ND 31-May-11 0.33 1.0 ND 0.62 1 ND 19-Dec-11 0.33 1.0 Dry 0.68 1 ND 29-May-12 0.33 1.0 Dry 0.58 1 ND 03-Dec-12 0.33 1.0 Dry 0.51 1 ND 10-Jun-13 0.33 1.0 ND ND ND 28-0ct-13 0.33 1.0 ND 0.55 1 ND 05-May-14 EPA 8260 0.33 1.0 ND 0.55 1 ND 20-0ct-14 EPA 8260 0.33 1.0 ND 0.64 1 ND 18-May-15 EPA 8260 0.33 1.0 Dry 0.57 1 ND 07-Dec-15 EPA 6010 0.33 1.0 Dry 0.44 1 ND 02-May-16 EPA 8260 0.33 1.0 Dry 0.43 1 ND 12-Dec-16 EPA 8260 0.33 1.0 Dry 0.51 1 ND 26Jun-17 EPA 8260 0.33 1.0 Dry ND ND 14-May-18 EPA 8260 0.33 1.0 ND 0.44 1 ND 03-Dec-18 EPA 8260 0.33 1.0 ND ND ND 06May-19 EPA 8260D 0.58 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.26 1.0 ND 0.33 1 ND 06May-20 EPA 8260D 0.26 1.0 0.4 1 ND - 09-Nov-20 EPA 8260D 0.26 1.0 0.55 J 0.51 J - 03-May-21 EPA 8260D 0.33 1.0 ND ND - 01-Nov-21 EPA 8260D 0.33 1.0 - 0.42 J ND Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 8 of 11 TABLE A2-3: Historical Surface Water Constituents Amlybe Sample Collection Data EPA Method DL RL SW-1 SW-2 Blanka 1,1-Dichlomethane 29-May-07 NR 5 Dry 2.3 1 ND 27-Nov-07 NR 5.0 Dry 0.43 1 ND Kze/ern K-B.7oo IVLIo3/za/oe) 27-May-08 0.32 5.0 Dry 0.55 1 ND 04-Nov-08 0.32 5.0 Dry 1.2 1 ND 01-Jun-09 0.32 5.0 Dry 0.41 1 ND 19-Nov-09 0.32 5.0 0.65 1 2.4 1 ND NC 2B=NE yg/L(05/01/07) 14-Jun-10 0.32 5.0 ND 0.34 1 ND 29-Nov-10 0.32 5.0 ND ND ND 31-May-11 0.32 5.0 ND 0.42 1 ND 19-Dec-11 0.32 5.0 Dry 0.37 1 ND 29-May-12 0.32 5.0 Dry ND ND 03Dee-12 0.32 5.0 Dry ND ND 10-Jun-13 0.32 5.0 ND ND ND 28-0ct-13 0.32 5.0 ND ND ND 05-May-14 EPA 8260 0.32 5.0 ND ND ND 20-0ct-14 EPA 8260 0.32 5.0 ND ND ND 18-May-15 EPA 8260 0.32 5.0 Dry ND ND 07-Dec-15 EPA 8260 0.32 5.0 Dry ND ND 02-May-16 EPA 8260 0.32 5.0 Dry ND ND 12-Dec-16 EPA 8260 0.32 5.0 Dry ND ND 26-Jun-17 EPA 8260 0.32 5.0 Dry ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND ND 03Dee-18 EPA 8260 0.32 1.0 ND ND ND 06May-19 EPA 8260D 0.41 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.27 1.0 ND ND ND 06May-20 EPA 8260D 0.27 1.0 ND ND - 09-Nov-20 EPA 8260D 0.27 1.0 ND ND - 03May-21 EPA 8260D 0.37 1.0 ND ND - 01-Nov-21 EPA 8260D 0.37 1.0 - ND ND cis-1,2-Dichloroethene May-03 NR 5 ND 5.0 ND Jul-03 NR 5 Dry ND ND Nov-03 NR 5 ND ND ND May-04 NR 5 Dry ND ND Nov-04 NR 5 ND ND ND May-05 NR 5 Dry 5.0 ND Resample> Aug-05 NR 5 NS ND INS Nov-05 NR 5 Dry ND ND 23May-06 NR 5 Dry ND ND 01-Nov-06 NR 5 ND ND ND 29-May-07 NR 5 Dry 6.4 ND 27-Nov-07 NR 5 Dry 10.4 ND BC 2B/EPA NC-290 pVL(03/za/Ca) 27-May-08 0.19 5.0 Dry 4.2 1 ND 04-Nov-08 0.19 5.0 Dry 8.3 ND 01-Jun-09 0.19 5.0 Dry 3.9 1 ND 19-Nov-09 0.19 5.0 73.8 21.1 0.26 1 NC 2B=NE yg/L(05/01/07) 14-Jun-10 0.19 5.0 ND 3.2 1 ND 29-Nov-30 0.19 5.0 3.6 1 ND ND 31-May-11 0.19 5.0 ND 3.5 1 ND 19-Dec-11 0.19 5.0 Dry 3.4 1 ND 29-May-12 0.19 5.0 Dry 2.5 1 ND 03Dee-12 0.19 5.0 Dry 2.5 1 ND 10-Jun-13 0.19 5.0 ND ND ND 28-0ct-13 0.19 5.0 ND 2.3 1 ND 05-May-14 EPA 8260 0.19 5.0 ND 1.9 1 ND 20-0ct-14 EPA 8260 0.19 5.0 ND 2.2 1 ND 18-May-15 EPA 8260 0.19 5.0 Dry 1.8 1 ND 07-Dec-15 EPA 6010 0.19 5.0 Dry 1.4 1 ND 02-May-16 EPA 8260 0.19 5.0 Dry 1.0 1 ND 12-Dec-16 EPA 8260 0.19 5.0 Dry 1.9 1 ND 26Jun-17 EPA 8260 0.19 5.0 Dry 1.5 1 ND 14-May-18 EPA 8260 0.19 5.0 ND 1.1 1 ND 03Dee-18 EPA 8260 0.19 1.0 ND 0.97 1 ND 06May-19 EPA 8260D 0.66 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.29 1.0 ND 0.83 1 ND 06May-20 EPA 8260D 0.29 1.0 0.95 1 ND - 09-Nov-20 EPA 8260D 0.29 1.0 0.57 1 0.97 1 - 03-May-21 EPA 8260D 0.38 1.0 ND ND - 01-Nov-21 EPA 8260D 0.38 1.0 - 1 NO Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 9 of 11 TABLE A2-3: Historical Surface Water Constituents Sample Ani Collection EPA Method DL RL SW-1 Si Blank. Methylene Chloride May-97 NR 5 7.0 B ND 6.0 Nov-97 NR 5 ND ND NA May-98 NR 10 ND ND ND Nov-98 NR 5 ND ND ND May-99 NR 5 ND ND ND 0ct-99 NR 10 ND ND 21.0 May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-01 NR 10 Dry ND ND Nov-01 NR 10 Dry ND ND May-02 NR 10 Dry ND ND Nov-02 NR 10 ND ND ND May-03 NR 10 ND ND ND Nov-03 NR 10 ND ND ND May-04 NR 10 Dry ND ND Nov-04 NR 10 ND ND ND May-05 NR 10 Dry ND ND Nov-05 NR 10 Dry ND ND 23-May-06 NR 10 Dry ND ND 01-Nov-06 NR 10 ND ND ND 29-May-07 NR 1 Dry ND ND 27-Nov-07 NR 1 Dry ND ND No 23/Ern Nc-4.6 ug/L 103/28/oal 27-May-08 0.97 2.0 Dry ND 1.5 1 04-Nov-08 0.97 2.0 Dry ND 2.8 01-Jun-09 0.97 2.0 Dry ND ND 19-Nov-09 0.97 2.0 1.6 1 ND ND INC 2B=NE hi(05/01/07) 14-Jun-10 0.97 2.0 ND ND ND 29-Nov-30 0.97 1.0 ND ND ND 31-May-11 0.97 1.0 ND ND ND 19-Dec-11 0.97 1.0 Dry ND 3.3 29-May-12 0.97 1.0 Dry ND ND 03-Dec-12 0.97 1.0 Dry ND ND 10-Jun-13 0.97 1.0 ND ND ND 28-0ct-13 0.97 1.0 ND ND ND 05-May-14 EPA 8260 0.97 1.0 ND ND 2.6 20-01 EPA 8260 0.97 1.0 ND ND ND 18-May-15 EPA 8260 0.97 1.0 Dry ND 1.3 07-Dec-15 EPA 8260 0.97 1.0 Dry ND 4.8 02-May-16 EPA 8260 0.97 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.97 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.97 1.0 Dry ND 1.3 14-May-18 EPA 8260 0.97 1.0 ND ND ND 03-Dec-18 EPA 8260 0.97 1.0 ND ND ND 06May-19 EPA 8260D 0.50 1.0 ND ND ND 05-Nov-19 EPA 8260D 3.70 5.0 ND ND ND 06May-20 EPA 8260D 3.70 5.0 ND ND - 09-Nov-20 EPA 8260D 3.70 5.0 ND ND - 03-May-21 EPA 8260D 2.00 5.0 ND ND - 01-Nov-21 EPA 8260D 2.00 5.0 - ND ND Tetrachloroethene 19-Nov-09 0.46 1.0 1.5 ND ND Resample> 15-Feb-10 0.46 1.0 ND NS ND INC 2B= 0.07 pg/L(05/01/07) 14-Jun-10 0.46 1.0 ND ND ND 29-Nov-30 0.46 1.0 ND ND ND 31-May-11 0.46 1.0 ND ND ND 19-Dec-11 0.46 1.0 Dry ND 0.77 J 29-May-12 0.46 1.0 Dry ND ND 03-Dec-12 0.46 1.0 Dry ND ND 10-Jun-13 0.46 1.0 ND ND ND 28-0ct-13 0.46 1.0 ND ND ND 05-May-14 EPA 8260 0.46 1.0 ND ND ND 20-01 EPA 8260 0.46 1.0 ND ND ND 18-May-15 EPA 8260 0.46 1.0 Dry ND ND 07-Dec-15 EPA 6010 0.46 1.0 Dry 0.64 1 ND 02-May-16 EPA 8260 0.46 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.46 1.0 Dry ND ND 26Jun-17 EPA 8260 0.46 1.0 Dry ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND 03-Dec-18 EPA 8260 0.46 1.0 ND ND ND 06May-19 EPA 8260D 0.78 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.16 1.0 ND ND ND 06May-20 EPA 8260D 0.16 1.0 ND ND - 09-Nov-20 EPA 8260D 0.16 1.0 ND ND - 03-May-21 EPA 8260D 0.29 1.0 ND ND - 01-Nov-21 EPA 8260D 0.29 1.0 - ND ND Trichlomethene 19-Nov-09 0.47 1.0 3.6 1.4 ND Resample> 15-Feb-10 0.47 1.0 ND NS ND INC 2B=2.5 Pi (5/1/07) 14-Jun-10 0.47 1.0 ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 31-May-11 0.47 1.0 ND ND ND 19-Dec-11 0.47 1.0 Dry ND ND 29-May-12 0.47 1.0 Dry ND ND 03-Dec-12 0.47 1.0 Dry ND ND 10-Jun-13 0.47 1.0 ND ND ND 28-0ct-13 0.47 1.0 ND ND ND 05-May-14 EPA 8260 0.47 1.0 ND ND ND 20-01 EPA 8260 0.47 1.0 ND ND ND 18-May-15 EPA 8260 0.47 1.0 Dry ND ND 07-Dec-15 EPA 8260 0.47 1.0 Dry ND ND 02-May-16 EPA 8260 0.47 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.47 1.0 Dry ND ND 26Jun-17 EPA 8260 0.47 1.0 Dry ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND 03-Dec-18 EPA 8260 0.47 1.0 ND ND ND 06May-19 EPA 8260D 0.34 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.22 1.0 ND ND ND 06May-20 EPA 8260D 0.22 1.0 ND ND - 09-Nov-20 EPA 8260D 0.22 1.0 ND ND - 03-May-21 EPA 8260D 0.38 1.0 ND ND - 01-Nov-21 EPA 8260D 0.38 1.0 - ND ND Burke County - East Burke Landfill La Bella Associates Permit No. 12-02 10 of 11 TABLE A2-3: Historical Surface Water Constituents Sample Analyte Collection EPA Method DL RL SW-1 SW-2 Blanks Data Vinyl Chloride 19-Nov-09 0.62 1.0 ND 0.74 1 ND NC 2B=0.025 pg/L(05/OV07) 14 Jun-10 0.62 1.0 ND ND ND 29-Nov-10 0.62 1.0 ND ND ND 31-May-11 0.62 1.0 ND ND ND 19-Dec-11 0.62 1.0 Dry ND ND 29-May-12 0.62 1.0 Dry ND ND 03-Dec-12 0.62 1.0 Dry ND ND 16Jun-13 0.62 1.0 ND ND ND 28-0ct-13 0.62 1.0 ND ND ND 05-May-14 EPA 8260 0.62 1.0 ND ND ND 20-0ct-14 EPA 8260 0.62 1.0 ND ND ND 18-May-15 EPA 8260 0.62 1.0 Dry ND ND 07-Dec-15 EPA 8260 0.62 1.0 Dry ND ND 02-May-16 EPA 8260 0.62 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.62 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.62 1.0 Dry ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND 03-Dec-18 EPA 8260 0.62 1.0 ND ND ND 06May-19 EPA 8260D 0.60 1.0 ND ND ND 05-Nov-19 EPA 8260D 0.24 1.0 ND ND ND 06May-20 EPA 8260D 0.24 1.0 ND ND - 09-Nov-20 EPA 8260D 0.24 1.0 ND ND - 03-May-21 EPA 8260D 0.39 1.0 ND ND - 01-Nov-21 EPA 8260D 0.39 1.0 - ND ND Xylene (Total) 19-Nov-09 0.66 2.0 8.8 ND ND NC 2B=NE p9/L(05/01/07) 14-Jun-10 0.66 2.0 ND ND ND 29-Nov-10 0.66 2.0 ND ND ND 31-May-11 0.66 2.0 ND ND ND 19-Dec-11 0.66 2.0 Dry ND ND 29-May-12 0.66 2.0 Dry ND ND 03-Dec-12 0.66 5.0 Dry ND ND 10-Jun-13 0.66 5.0 ND ND ND 28-0ct-13 0.66 5.0 ND ND ND 05-May-14 EPA 8260 0.66 5.0 ND ND ND 20-0ct-14 EPA 8260 0.66 5.0 ND ND ND 18-May-15 EPA 8260 0.66 5.0 Dry ND ND 07-Dec-15 EPA 8260 0.66 5.0 Dry ND ND 02-May-16 EPA 8260 0.66 5.0 Dry ND ND 12-Dec-16 EPA 8260 0.66 5.0 Dry ND ND 26Jun-17 EPA 8260 0.66 5.0 Dry ND ND 14-May-18 EPA 8260 0.66 5.0 ND ND ND 03-Dec-18 EPA 8260 0.66 1.0 ND ND ND 06May-19 EPA 8260D 1.50 2.0 ND ND ND 05-Nov-19 EPA 8260D 0.63 1.0 ND ND ND 06May-20 EPA 8260D 0.63 1.0 ND ND - 09-Nov-20 EPA 8260D 0.63 1.0 ND ND - 03-May-21 EPA 8260D 0.34 1.0 ND ND - 01-Nov-21 EPA 8260D 0.34 1.0 - ND ND Chloroform 06May49 EPA 8260D 0.6 1 - 0.72 1 ND 05-Nov-19 EPA 8260D 2.3 5 ND ND ND 06May-20 EPA 8260D 2.3 5 ND ND - 09-Nov-20 EPA 8260D 2.3 5 ND ND - 03-May-21 EPA 8260D 1.6 5 ND ND - 01-Nov-21 EPA 8260D 0.43 1 - ND ND Notes; RL = Reporting Limit (Lab. Reporting Limit for September 1994- May 1999; NC PQLfor October1999-DecemWr2006; antl SWSL for December 2006- 2017; NC PQL for 201S-present). DL= Laboratory memcd detenton Ilmt. ND = Not Detected st or above the Iabclatory RL (prior to Dec. 2006) or the DL (after Dec. 2006). NS Not at NA = No tlata available. NR = Not reported. 1= Estimated concentration less than the RL but greaterthan the DL B=Biank-Qualified (Concentration suspected to reflect laboratory orfleltl contamination). NE = Not est- shed. Dry = Surtace water point was considered to W dry and no sample collected. Vdlues above the NC 2B are boll. Surface water is classIfed as Water Supply IV - Highly Developed, Primary Rea., Critical Area. Burke County - East Burke Landfill LaBelle Associates Permit No. 12-02 11 of 11 TABLE A2-4: Historical Groundwater Field Parameters Parameter Collection Date MW-1 MW-2 MW-3 AMW-1 Conductivity 10-Jun-13 123.0 275.0 299 149.1 (at 25°C) [mS/cm] 28-Oct-13 90.1 164.5 228.2 126.2 5-May-14 94.7 209.9 234.1 123.7 20-Oct-14 119.5 186.0 254 189 18-May-15 117.0 250.0 264 135 7-Dec-15 133.0 274.0 287 170 2-May-16 86.0 177.2 241 125.4 12-Dec-16 124.5 254.0 265 176.3 26-Jun-17 126.0 228.0 268 182.3 14-Dec-17 140.0 272.0 283 200 14-May-18 123.0 275.0 299 168 3-Dec-18 96.2 187.6 244.8 124.5 6-May-19 104.0 239.9 266.3 118.90 23-Jul-19* -- 454.7 464.7 - 4-Nov-19 101.2 275 270.5 111.10 5-May-20 105.7 278.1 299.8 117.20 9-Nov-20 91.2 245.5 267.8 101.50 3-May-21 86.7 285.7 242.3 78.3 1-Nov-21 119.9 304.1 355.4 183.7 pH [standard units] 10-Jun-13 5.97 5.88 5.75 5.64 28-Oct-13 5.18 5.4 5.53 5.85 5-May-14 5.53 5.53 5.61 5.61 20-Oct-14 4.69 5.39 5.49 6.85 18-May-15 5.05 5.55 5.39 6.09 7-Dec-15 5.22 5.57 5.46 6.29 2-May-16 4.79 5.08 5.15 5.55 12-Dec-16 5.46 5.84 5.6 5.94 26-Jun-17 5.51 5.24 5.18 5.61 14-Dec-17 5.54 5.87 5.73 5.95 14-May-18 5.97 5.88 5.75 6.19 3-Dec-18 5.57 5.7 6.03 5.38 6-May-19 5.56 5.84 5.58 5.73 23-Jul-19* -- 5.63 5.19 - 4-Nov-19 5.21 5.63 5.24 5.45 5-May-20 5.50 5.72 5.54 5.65 9-Nov-20 5.41 5.8 5.65 5.40 3-May-21 5.13 5.47 5.10 5.20 1-Nov-21 5.14 5.81 4.43 5.77 Oxidation Reduction Potential [mV] 6-May-19 96.9 69.6 176.0 146.1 23-Jul-19* -- 119.6 147.9 - 4-Nov-19 139.7 63.1 204.4 181.4 5-May-20 325.8 307.8 346.6 323.4 9-Nov-20 115.7 36.6 126.4 152.2 3-May-21 194.3 6.0 171.4 218.4 1-Nov-21 104.8 27.5 105.9 62.7 Dissolved Oxygen [mg/L] 6-May-19 1.29 2.31 1.35 3.28 23-Jul-19* -- 2.93 0.69 - 4-Nov-19 3.01 5.66 1.97 2.83 5-May-20 3.62 3.56 15.55 9.33 9-Nov-20 1.45 1.34 2.29 2.49 3-May-21 0.87 1.07 1.17 4.33 1-Nov-21 0.74 0.86 1.52 4.58 Burke County -East Burke LaBella Associates Permit No. 12-02 1 of 2 TABLE A2-4: Historical Groundwater Field Parameters Parameter Collection Date MW-1 MW-2 MW-3 AMW-1 Temperature [°C] 10-Jun-13 18.7 17.6 17.5 15.4 2 8-0 ct-13 16.8 15.9 16 15.1 5-May-14 18.1 17.9 15.7 13.6 2 0-0 ct-14 16.0 15.3 15.3 16.7 18-May-15 17.9 17.3 16.1 18 7-Dec-15 15.4 14.9 15.9 13.9 2-May-16 17.4 17.2 16.1 15.7 12-Dec-16 16.0 15.6 15.9 12.3 26-Jun-17 17.5 16.6 15.8 18.6 14-Dec-17 17.1 14.7 13.7 10.9 14-May-18 18.7 17.6 17.5 18.2 3-Dec-18 15.1 15.5 16.0 12.5 6-May-19 17.3 17.4 16.8 15.6 23-Jul-19* -- 18.6 16.7 - 4-Nov-19 17.7 17.2 15.6 15.5 5-May-20 16.6 16.9 15.8 15.2 9-Nov-20 17.3 16.8 16.8 16.5 3-May-21 17.4 16.8 16.2 14.5 1-Nov-21 17.0 16.1 16.5 16.0 Turbidity [NTU] 10-Jun-13 0.92 0.99 4.58 9.8 28-Oct-13 5.11 3.0 4.38 10.11 5-May-14 6.15 25.30 12.33 21.8 20-Oct-14 17.20 18.40 3.49 20.5 18-May-15 6.95 11.00 3.88 6.29 7-Dec-15 4.29 26.20 6.75 7.26 2-May-16 6.63 15.11 14.56 14.23 12-Dec-16 2.32 2.29 5.81 6.49 26-Jun-17 4.07 4.57 11.8 8.67 14-Dec-17 12.75 8.41 15.71 7.09 14-May-18 0.92 0.99 4.58 0.96 3-Dec-18 5.41 8.26 5.98 15.5 6-May-19 1.42 4.07 5.63 11.5 23-Jul-19* -- 3.20 4.41 - 4-Nov-19 1.87 10.23 3.87 2.69 5-May-20 6.28 18.54 2.23 18.32 9-Nov-20 0.83 1.45 2.17 4.87 3-May-21 1.35 1.77 2.25 10.0 1-Nov-21 1.05 0.86 0.91 30.4 NOTES: C` = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units mg/L = milligrams per liter *= resampling event - = data not available or not sampled. Burke County -East Burke LaBella Associates Permit No. 12-02 2 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 pH [S.U.] 10-Jun-13 6.45 6.78 28-Oct-13 6.31 6.09 5-May-14 6.29 5.5 20-Oct-14 5.84 6.97 18-May-15 - 6.07 7-Dec-15 6.1 2-May-16 5.38 12-Dec-16 6.22 26-Jun-17 - 5.04 14-Dec-17 6.32 5.9 14-May-18 7.43 6.48 3-Dec-18 6.55 6.16 6-May-19 6.26 6.12 4-Nov-19 5.96 5.76 5-May-20 6.61 6.37 9-Nov-20 6.5 6.11 3-May-21 5.47 5.19 Resample -> 29-Jun-21 4.73 4.66 1-Nov-21 - 5.85 Temperature [°C] 10-Jun-13 18.3 19.5 28-Oct-13 13.8 13.7 5-May-14 15.2 14.6 20-Oct-14 14 14.2 18-May-15 - 17.7 7-Dec-15 10.4 2-May-16 16.2 12-Dec-16 8.5 26-Jun-17 - 17.6 14-Dec-17 8.9 9.5 14-May-18 18.8 18.4 3-Dec-18 12.6 12 6-May-19 16.5 16.6 4-Nov-19 17.1 11.9 5-May-20 14.8 14.7 9-Nov-20 17.3 16.1 3-May-21 17.2 16.3 Resample ---> 29-Jun-21 20.3 18.8 1-Nov-21 - 13.8 Dissolved Oxygen [mg/L] 6-May-19 5.90 6.32 5-Nov-19 5.79 5.97 5-May-20 15.48 15.17 9-Nov-20 5.56 7.3 3-May-21 6.56 7.82 Resample -> 29-Jun-21 5.44 5.75 1-Nov-21 - 7.04 Oxidation Reduction Potential [mV] 6-May-19 145.3 155.3 5-Nov-19 217.8 217.8 5-May-20 344.1 350 9-Nov-20 - 125.2 3-May-21 146.3 211.4 Resample -> 29-Jun-21 126.4 170.1 1-Nov-21 - 89.2 Burke County - East Burke Landfill LaBella Associates Permit No. 12-02 1 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 Turbidity [NTU] 10-Jun-13 16.8 32.7 28-Oct-13 15.21 12.94 5-May-14 9.05 10.57 20-Oct-14 7.18 19.2 18-May-15 - 6.19 7-Dec-15 6.27 2-May-16 11.89 12-Dec-16 13.61 26-Jun-17 - 8.95 14-Dec-17 19.06 10.15 14-May-18 0 0 3-Dec-18 13.9 47.6 6-May-19 15.2 14.4 4-Nov-19 17.36 13.08 5-May-20 29.32 32.9 9-Nov-20 5.09 14.9 3-May-21 328 175 Resample -> 29-Jun-21 95.5 19.4 1-Nov-21 - 5.98 Conductivity 10-Jun-13 31.5 115.9 (at 25c) [mS/cm] 28-Oct-13 27.5 89.7 5-May-14 26.5 116.1 20-Oct-14 44.2 49.7 18-May-15 - 131 7-Dec-15 171 2-May-16 112.4 12-Dec-16 168.4 26-Jun-17 - 169.8 14-Dec-17 362 300 14-May-18 95 153 3-Dec-18 129 139 6-May-19 127.6 131.2 4-Nov-19 211.6 173.9 5-May-20 334.7 189.8 9-Nov-20 427.7 153.3 3-May-21 103.8 71.8 Resample ---> 29-Jun-21 - - 1-Nov-21 211.6 NOTES: °C= degrees Centigrade S.U.= Standard Units uS/cm= microSemens per centimeter my = millivolts NTU= Nephelometric Turbidity Units mg/L = miligrams per liter - = Dry/Could not sample Burke County - East Burke Landfill LaBella Associates Permit No. 12-02 2 of 2