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1201_Burke_KirkseyDrive_MSWLF_Nov21GW_FID1646722_20220301
jD7ENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: ' NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information _ Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D.. P.G. E-mail: vburbach@labellapc.com Phone: (336)323-0092 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Burke Co. - Kirksey Dr. Landfill Kirksey Drive 12-01 .0500 November 1-2, 2021 Morganton, NC Environmental Status: (Check all that apply) Initial/Background Monitoring X� Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., P.G. Sr. Technical Consultant (336) 323-0092 12-D Oak Branch Dr., Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 !a Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal SEAL 1349 2 G9 G'F4LOG� �Q`; "'•�.yNESS LaBeLLa Powered by partnership. March 1, 2022 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Via Email: jaclynne.drummond@ncdenr.gov RE: November 2021 Semiannual Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2212740 Dear Ms. Drummond: Please find the attached November 2021 Semiannual Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the November 2021 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form and the EQuIS EDD. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide them upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates ro�51--tr� Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure cc: Mark Delehant, Burke County 12-D Oak Branch Drive I Greensboro, NC 27407 I p (336) 323-0092 www.LabeLLapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 4 eo$xg o W oe�,tizEOl �0�-1 c x �Tk CA Submitted by: LaBella Associates (Joyce Engineering) 12-D Oak Branch Drive Greensboro, NC 27407 (336) 323-00g2 NC License No. C-0782 LaBeRa Powered by partnership. NOVEMBER 2021 SEMIANNUAL WATER QUALITY MONITORING REPORT KIRKSEY DRIVE LANDFILL Permit No. 12-01 MARCH 2O22 PROJECT NO. 2212740 November 2021 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................1 1.1 Site Information................................................................................................................ 1 1.2 Site Geology........................................................................................................................ 1 1.3 Regulatory Status............................................................................................................... 2 2.0 FACILITY MONITORING PROGRAM...................................................................................2 2.1 Groundwater Monitoring Program.................................................................................... 2 2.2 Surface Water Monitoring Program.................................................................................. 2 3.0 May 2021 SEMIANNUAL SAMPLING EVENT...................................................................3 3.1 Field Work...........................................................................................................................3 3.2 Laboratory Analysis and Quality Control........................................................................... 4 4.0 HYDROGEOLOGY..............................................................................................................4 5.0 DATA ANALYSIS................................................................................................................6 5.1 Analytical Results and Comparison to Standards............................................................ 6 5.1.1 Groundwater............................................................................................................6 5.1.2 Surface Water..........................................................................................................6 7.0 REFERENCES....................................................................................................................7 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 November 2021 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 Groundwater Elevations (November 2021) Table 2 Hydraulic Gradients and Velocities (November 2021) Table 3 Detected Constituents (November 2021) Table 4 Exceedances of Standards (November 2021) Table 5 Field Parameters (November 2021) Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map (November 2021) Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 ii 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of Inner Piedmont Belt rocks were mostly sedimentary (greywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Well MW-1 was damaged and has not been able to be sampled since June 2017. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (feet) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points (SMP-1, SMP-2, and SMP-3) comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply WS-IV. All surface water monitoring points are monitored semiannually for the NC Appendix I list of constituents plus 1,4-dioxane. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 2 Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 November 2021 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On November 1-2, 2021, personnel from LaBella visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Monitoring well MW-1 is damaged and was not able to be monitored during this sampling event. This well should be evaluated for repair or replacement. Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the November 2021 monitoring event can be found in Table 1. Monitoring wells were purged using either disposable bailers or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site logbook and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field data logs are included in Appendix 1. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a cooler. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the November 2021 monitoring event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 3 reduction potential, and turbidity and recorded in the site logbook. Immediately after sample collection, the samples were placed on ice in a laboratory -provided cooler. Field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The November 2021 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory in good condition, properly preserved, at proper temperature, and within analysis hold times. The sampling data report was received from Pace Analytical Services on November 17, 2021. In addition to samples collected for compliance monitoring at the Kirksey Drive Landfill, a Field Blank was collected by LaBella personnel as part of the sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs only, and both were analyzed for 1,4-dioxane. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC2L), NC Interim Maximum Allowable Concentrations (IMACs), 15A NCAC 2B Surface Water Standards (NC2B), or NC In -stream Target Values (ISTV); and • Detections that are above historical levels. Review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and highly fractured/weathered metamorphic rock. Beneath the regolith is fractured metamorphic rock that is typically well connected to the regolith but has less porosity Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 and storativity. The fractured bedrock portion of the aquifer tends to be more heterogeneous and anisotropic than the regolith. Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in November 2021, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the November 2021 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.0386 to 0.0686, with an average of approximately 0.0503. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = Ki/ne. Where: V = average linear velocity; K = hydraulic conductivity; i = horizontal hydraulic gradient; and ne = effective porosity. The mean of hydraulic conductivities from slug -tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 231 to 410 feet/year, with an average flow velocity of approximately 301 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 5 5,0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the November 2021 monitoring event are listed in Table 3. Results with quantified concentrations above their respective NC21- or IMAC are presented in Table 4. Field parameter data from the November 2021 event are summarized in Table 5. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2), and historical groundwater field parameters can be found in Appendix 2 (Table A2-3). During the November 2021 monitoring event, the inorganic constituents detected at quantified concentrations above the MRL in the groundwater samples included: barium (MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, MW-6S); cobalt (MW-2, MW-3S); nickel (MW-2, MW-3D, MW-3S); silver (MW-2); and vanadium (MW-2, MW-3S, MW-4, MW-5). The inorganic constituents detected at quantified concentrations in exceedance of their respective NC21- or IMAC during the November 2021 sampling event include: barium (MW-2); cobalt (MW-2, MW-3S); and vanadium (MW-2, MW-3S, MW-4, MW-5). The organic constituents detected in groundwater monitoring wells at quantified concentrations above the MRL in the groundwater samples included: benzene (MW-2, MW-3D, MW-3S); chlorobenzene (MW-2, MW-3D, MW-3S); chloroethane (MW-3S); 1,1-dichloroethane (MW-3D); 1,2-dichlorobenzene (MW-2); 1,4-dichlorobenzene (MW-2, MW-3D, MW-3S); cis-1,2-dichlorethene (MW-3D, MW-4); 1,4-dioxane (MW-2, MW-31), MW-3S); ethylbenzene (MW-2); 4-methyl-2-pentanone (MW-2); tetra chloroethene (MW-3D); trichloroethene (MW-3D); toluene (MW-2); vinyl chloride (MW-3D); and xylene (MW-2, MW-3S). The organic constituents detected at quantified concentrations in exceedance of their respective NC21- or IMAC during the November 2021 sampling event include: benzene (MW-2, MW-31), MW-3S); 1,4-dichlorobenzene (MW-2, MW-3S); 1,4-dioxane (MW-2, MW-3D, MW-3S); tetra chloroethene (MW-3D); trichloroethene (MW-3D); and vinyl chloride (MW-31)). In general, these results are consistent with historical data for the site, except that vanadium in MW-2 and MW-3S increased significantly (Appendix 2, Table A2-2). 5.1.2 Surface Water Constituents detected in the surface water during the November 2021 monitoring event are presented in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A2-4), and historical surface water field parameters can be found in Appendix 2 (Table A2-5). Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 9 Barium was the only constituent detected at quantified concentrations above the MRL in any of the surface water samples during the November 2021 sampling event. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC213 Standards or ISTV for class WS-IV waters during this sampling event. 6.0 CONCLUSION The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for May 2022. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, p. 119 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2021 Semiannual Water Quality Monitoring Report March 2022 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 Groundwater Elevations (November 2021) Hydraulic Gradients and Velocities (November 2021) Detected Constituents (November 2021) Exceedances of Standards (November y 2021) Field Parameters (November 2021) TABLE 1: Groundwater Elevations (November 2021) Location TOC Elevation (Ft-AMSL) Depth to Groundwater (Ft-BTOC) Lithology Well Depth (Ft-BTOC) Groundwater Elevation (Ft-AMSL) MW-1 1119.82 --- Saprolite 35.65 --- MW-2 1077.23 26.21 Saprolite 45.70 1051.02 MW-3S 1022.76 6.29 Bedrock 26.69 1016.47 MW-31D 1021.90 0.00 Bedrock 78.40 1021.90 MW-4 1054.99 22.62 Saprolite 29.50 1032.37 MW-5 1137.43 36.14 Saprolite 49.80 1101.29 MW-6S 1065.00 10.25 Bedrock 25.00 1054.75 MW-6D 1065.00 12.0 Saprolite 60.00 1053.00 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level Water Levels measured November 1-2, 2021 --- = well damaged, not sampled. Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 TABLE 2: Hydraulic Gradients and Velocities (November 2021) Water Levels Measured: November 1-2, 2021 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION GROUNDWATER ELEVATION (feet) HORIZONTAL GRADIENT ► HYDRAULIC CONDUCTIVITY K (feet/day) EFFECTIVE POROSITY n LINEAR VELOCITY V (feet/year) 1100 11 1,167 E 0.0686 3.28E+00 0.20 410 1020 1090 12 1,296 SE 0.0386 3.28E+00 0.20 231 1040 AVERAGE: 0.05031 AVERAGE: 301 Notes: The mean of K estimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1) . Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: Detected Constituents (November 2021) SAMPLE ID PARAMETER RESULT METHOD MDL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater Barium 1550 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 116 EPA 6010D 3.6 5 1 IMAC pg/L Nickel 20.5 EPA 6010D 3.5 5 100 NC 2L pg/L Silver 5.6 EPA 6010D 2.5 5 20 NC 2L pg/L Vanadium 59.9 EPA 6010D 3.9 5 0.3 IMAC pg/L 1,1-Dichloroethane 0.49 J EPA 8260D 0.37 1 6 NC 2L pg/L 1,2-Dichlorobenzene 2.1 EPA 8260D 0.34 1 20 NC 2L pg/L MW-2 1,4-Dichlorobenzene 33.7 EPA 8260D 0.33 1 6 NC 2L pg/L 11/1/2021 1,4-Dioxane (p-Dioxane) 279 EPA 8260D Mod. 4.3 10 3 NC 2L pg/L 4-Methyl-2-pentanone (MIBK) 5.0 EPA 8260D 2.7 5 100 IMAC pg/L Benzene 8.9 EPA 8260D 0.34 1 1 NC 2L pg/L Chlorobenzene 24.5 EPA 8260D 0.28 1 50 NC 2L pg/L Ethylbenzene 10.7 EPA 8260D 0.3 1 600 NC 2L pg/L Toluene 1.0 EPA 8260D 0.48 1 600 NC 2L pg/L Xylene (Total) 18.2 EPA 8260D 0.34 1 500 NC 2L pg/L Barium 202 EPA 6010D 3.5 5 700 NC 2L pg/L Nickel 28.9 EPA 6010D 3.5 5 100 NC 2L pg/L 1,1-Dichloroethane 5.5 EPA 8260D 0.37 1 6 NC 2L pg/L 1,2-Dichloropropane 0.72 J EPA 8260D 0.36 1 0.6 NC 2L pg/L 1,4-Dichlorobenzene 3.9 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 95.7 EPA 8260D Mod. 1.7 4 3 NC 2L pg/L MW-3D 11/1/2021 Benzene 1.5 EPA 8260D 0.34 1 1 NC 2L pg/L Chlorobenzene 8.8 EPA 8260D 0.28 1 50 NC 2L pg/L cis-1,2-Dichloroethene 22.9 EPA 8260D 0.38 1 70 NC 2L pg/L Tetrachloroethene 7.7 EPA 8260D 0.29 1 0.7 NC 2L pg/L Trichloroethene 5.7 EPA 8260D 0.38 1 3 NC 2L pg/L Vinyl chloride 1.1 EPA 8260D 0.39 1 0.03 NC 2L pg/L Barium 467 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 12.4 EPA 6010D 3.6 5 1 IMAC pg/L Nickel 5.3 EPA 6010D 3.5 5 100 NC 2L pg/L Silver 2.6 J EPA 6010D 2.5 5 20 NC 2L pg/L Vanadium 23.3 EPA 6010D 3.9 5 0.3 IMAC pg/L 1,2-Dichlorobenzene 0.49 J EPA 8260D 0.34 1 20 NC 2L pg/L MW-3S 11/2/2021 1,4-Dichlorobenzene 9.0 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 34.1 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L Benzene 3.1 EPA 8260D 0.34 1 1 NC 2L pg/L Chlorobenzene 32.3 EPA 8260D 0.28 1 50 NC 2L pg/L Chloroethane 1.7 EPA 8260D 0.65 1 3,000 NC 2L pg/L Xylene (Total) 13.3 EPA 8260D 0.34 1 500 NC 2L pg/L Barium 110 EPA 6010D 3.5 5 700 NC 2L pg/L Chromium 4.3 J EPA 6010D 3.7 5 10 NC 2L pg/L Copper 4.5 J EPA 6010D 4.3 5 1,000 NC 2L pg/L MW-4 Vanadium 9.9 EPA 6010D 3.9 5 0.3 IMAC pg/L 11/2/2021 1,1-Dichloroethane 0.65 J EPA 8260D 0.37 1 6 NC 2L pg/L cis-1,2-Dichloroethene 5.6 EPA 8260D 0.38 1 70 NC 2L pg/L Tetrachloroethene 0.49 J EPA 8260D 0.29 1 0.7 NC 2L pg/L Barium 46.5 EPA 6010D 3.5 5 700 NC 2L pg/L MW-5 Thallium 0.15 J EPA 6020E 0.05 0.47 0.2 IMAC pg/L 11/2/2021 Vanadium 5.1 EPA 6010D 3.9 5 0.3 IMAC pg/L MW-6D Barium 13.5 EPA 6010D 3.5 5 700 NC 2L I1g/L 11/1/2021 Barium 26.2 EPA 6010D 3.5 5 700 NC 2L pg/L MW-6S Cadmium 0.65 J EPA 6010D 0.4 1 2 NC 2L pg/L 11/2/2021 Chloroform 0.88 J EPA 8260D 0.43 1 70 NC 2L pg/L Surface Water SW-1 Barium 30.5 EPA 6010D 3.5 5 21,000 ISTV pg/L 11/2/2021 Barium 31.8 EPA 6010D 3.5 5 21,000 ISTV pg/L SW-2 11/1/2021 1,4-Dioxane (p-Dioxane) 1.4 J EPA 8260D Mod. 0.86 2 0.35 ISTV pg/L SW-3 Barium 30.8 EPA 6010D 3.5 5 21,000 ISTV pg/L 11/1/2021 Notes: pg/L= micrograms per liter. MDL= Method Detection Limit MRL = Method Reporting Limit 1 = Estimated concentration below the MRL B = Blank -qualified data due to detections in trip, field, or method blanks. ND = Not detected above the MDL Bold = Quantified detections above the Standard NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) NC2B = INC Surface Water Standard from15A NCAC 2B (NC2B* =hardness -dependent standard) ISTV= INC In -Stream Target Values NRWQC = EPA's National Recommended Water Quality Criteria BKGD = Background Burke Co. - Kirksey Dr. Landfill La Bella Associates Permit # 12-01 TABLE 4: Exceedances of Standards (November 2021) SAMPLE ID PARAMETER RESULT METHOD I MDL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater Barium 1550 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 116 EPA 6010D 3.6 5 1 IMAC pg/L Vanadium 59.9 EPA 6010D 3.9 5 0.3 IMAC pg/L MW 2 11/1/2021 1,4-Dichlorobenzene 33.7 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 279 EPA 8260D Mod. 4.3 10 3 NC 2L pg/L Benzene 8.9 EPA 8260D 0.34 1 1 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 95.7 EPA 8260D Mod. 1.7 4 3 NC 2L pg/L Benzene 1.5 EPA 8260D 0.34 1 1 NC 2L pg/L MW-3D Tetrachloroethene 7.7 EPA 8260D 0.29 1 0.7 NC 2L pg/L 11/1/2021 Trichloroethene 5.7 EPA 8260D 0.38 1 3 NC 2L pg/L Vinyl chloride 1.1 EPA 8260D 0.39 1 0.03 NC 2L pg/L Cobalt 12.4 EPA 6010D 3.6 5 1 IMAC pg/L Vanadium 23.3 EPA 6010D 3.9 5 0.3 IMAC pg/L MW-3S 1,4-Dichlorobenzene 9.0 EPA 8260D 0.33 1 6 NC 2L pg/L 11/2/2021 1,4-Dioxane (p-Dioxane) 34.1 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L Benzene 3.1 EPA 8260D 0.34 1 1 NC 2L pg/L MW-4 Vanadium 9.9 EPA 6010D 3.9 5 0.3 IMAC pg/L 11/2/2021 MW-5 Vanadium 5.1 EPA 6010D 3.9 5 0.3 IMAC pg/L 11/2/2021 Notes: pgIL= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit J = Estimated concentration below the MRL B = Blank -qualified data due to detections in trip, field, or method blanks. ND = Not detected above the MDL NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) NC2B = NC Surface Water Standard from15A NCAC 213 (NC2B* = hardness -dependent standard) ISTV = NC In -Stream Target Values NRWQC = EPA's National Recommended Water Quality Criteria Burke Co. Kirksey Dr. Landfill Permit # 12-01 LaBella Associates TABLE 5: Field Parameters (November 2021) Parameter Units Sample Date GW Upgradient Groundwater Downgradient Surface Water MW-1 MW-2 MW-3S MW-311) MW-4 MW-5 MW-6S MW-61D SW-1 SW-2 SW-3 Well Depth Ft. 5/4/2021 NS 45.25 26.95 76.15 29.60 50.8 27.56 63.15 -- -- -- pH S.U. 5/4/2021 NS 5.14 6.12 5.05 5.77 5.89 5.85 5.96 7.32 6.86 6.22 Temperature oC 5/4/2021 NS 16.8 15.7 16.4 14.2 14.9 16.1 15.0 11.6 13.6 13.9 Conductivity PS/cm 5/4/2021 NS 3069 931 1002 112.6 25.6 75.9 122.7 115.4 100.0 112.0 Dissolved Oxygen mg/L 5/4/2021 NS 1.06 1.87 6.52 1.73 7.57 4.31 0.90 8.52 7.23 6.88 Oxidation Reduction Potential my 5/4/2021 NS -30.4 64.7 116.0 56.9 110.9 83.2 -43.1 -55.0 -17.1 -55.1 Turbidity NTU 5/4/2021 NS 6.93 33.7 1.55 65.5 150 18.6 2.23 6.37 6.19 5.72 Static Water Level Ft. 5/4/2021 NS 26.21 1 6.29 1 0.00 1 22.62 1 36.14 1 10.25 1 12.0 - - - Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units Ft = feet NS = Not sampled due to broken casing Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map ------ tj 16V 1000 CP APPROXIMATE LOCATION OF PROPERTY LINE i---------- rx X, IF lef' 44,0 .10410 ISSUED FOR: 03 LaBeRa GROUNDWATER MONITORING REPORT Powered by partnership. DRAWING NAME: DRAWN BY: DATE: PROJECT NO.: SITE LOCATION MAP RVVH 02/27/19 2192621 2211 WEST MEADOW'VIEW ROAD GREENSBORO, N.C. 27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: KIRKSEY DRIVE LANDFILL 1 labellapc.com (D 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\Pwgs\Drawhgs—ruint\8URKE\GW EVENT MAPS\, SITE LOCATION MAP KIRKSEY DRIVE 2020.4wg DRAWING Drawing 1 Groundwater Potentiometric Surface Map (November 2021) / l .191 SMP-1 — — — — — LIMITS OF WASTE / �' �/1000 / ''ji \ BMW 2 � 1051.02 ole SMP-2—102190 � j /`' SMP-3 O _ 000, 140 00i LIMITS OF WAST6+TY P) — q \ \ /11 / 1 2.3 �G I JN0000-0-1 O __--------- \ �\ �\ `Q0 0 / \\ // ��� GRAPHI�SCALE LEGEND 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING ROAD EXISTING 20' TOPOGRAPHIC CONTOUR 0 150 / 600 / / ■ (FEET) N(1TP:C APPROXIMATE LIMITS OF WASTE 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET 3. STATIC WATER LEVELS MEASURED ON NOVEMBER 1-2, 2021. GROUNDWATER SURFACE CONTOUR [FEET CENTERLINE OF STREAM GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION 1080 — — — — — ABOVE MEAN SEA LEVEL (AMSL)] COMPLIANCE WELL LOCATION AND 4. BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, - MW-5 IDENTIFICATION WITH STATIC WATER TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. PROPERTY LINE ELEV LEVEL ELEVATION (FEET AMSL) GROUNDWATER FLOW PATHWAY USED TO SURFACE MONITORING POINT LOCATION FLOW PATH LENGTH CALCULATE HYDRAULIC GRADIENT SW-2 AND IDENTIFICATION SEGMENT USED FOR GRADIENT CALCULATION 0 1,167 LF Z� O1,296 LF 2 0.3 LaBella Powered by partnership. 2211 WESTMEADOWVIEW, SUITE 101 GREENSBORO, NC 27407 (336) 323-0092 labellapc.com T T T L L F T L_ L J C 2021 LaBelle Associates KIRKSEY DRIVE LANDFILL BURKE COUNTY, NORTH CAROLINA NO. DATE'. DESCRIPTION. Revisions PROJECT NUMBER: 2212740.00 DRAWN BY: RH REVIEWED BY EW ISSUED FOR: GROUNDWATER REPORT DATE: 1/ 8/21 DRAWING NAME: PERMIT NO. 12-01 GROUNDWATER POTENTIOMETRIC SURFACE MAP NOVEMBER 1-2, 2021 DRAWING NUMBER: 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data Appendix 1 Field Logs and Laboratory Analytical Reports DATE: 11 /112 LaBe4a U <r 6Y.l.)6"- riri"'Jll ' GROUND WATER SAMPLING LOG Project Name: &X4 w, " �Icx2f, Project No. /Task No.: Well ID: �Sampler(s): Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches 06') 1 feet 157, a '37 feet 19,a`/ feet [DTB-DTW] = 3a ( gallons _ gallons gallons gallons Purged with: Bailer Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials U l 3a0S 1. 3s tg, -_2 f3 . 2 � 9.3 I5l N %6. 8 5. ICI 30_`l ). e 3v . y 6, Date of sample: 1111 Before Sampling sc,M iM(�-_e "ak Comments (weather conditions, odor, color, silt, etc.): sd s soon�LA "1_4 664 e-s Signature: Date: QA/QC Sign Off: Date: LaBetLa DATE: I I A— �/ 2/ wattnerni�- Ky GROUND WATER SAMPLING LOG Project Name: Ye CO. Project No. /Task No.: Well ID: 3 S Sampler(s): f I��u �, K • fS+5 , Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl' 2 inches G9 a I C, feet a6.955 feet �Wb. @� feet [DTB-DTW] 3,3 gallons = gallons I gallons gallons Depth to Water before Sampling: L-7 J b feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials CO iy� 1&.,? N.$- q8 ..15- final 0,-4-G _S2.6 11.3 6. iyS5- IT v 57,a7 9TS :�,q,� -s3. e 30.6 V0 Nss rl-3 ss�2 q71 2. 0-4- -S`.q a1,o PJ Date of sample: 11 -�21 Before Sampling 03Y6 bs, 6,1 `2 7S j .8` 6'y, 33r"� Comments (weather conditions, odor, color, silt, etc.): -7 baWt-s Signature: Date: / QA/QC Sign Off: Date: DATE: 11 b /2 LaBelLa Pots.+oral by .pastnt,_rahlp GROUND WATER SAMPLING LOG Project Name: Lcve (.v n cy5e,y br. Project No. /Task No.: Well ID: (^I `�� Sampler(s): f, Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches feet ' 5 feet feet [DTB-DTW] gallons --gallons r - _3\ gallons gallons Purged with: Bailer Pl ump� Other: Q v Sampled with: Bailer Gmpi� Other: U V _ Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials o Iq oo i6. y, s':� loot-1 0-IS T. i 1W 1 qoF- 16. �5- 3. S) 100q I.. l,,) fi6. 0 6- fGJ of b 0,r'5- f21.2 Q.°B' ; PU Date of sample: Before Sampling C(,I P 6-'� to Comments (weather conditions, odor, color, silt, etc.): Signature: Z,'av Date: 11/ (712% QA/QC Sign Off: Date: DATE: ®r- LaBelLa Flo,amereclb•y partnerhip GROUND WATER SAMPLING LOG Project Name: (tAe Co. A�ANacq b . Project No. /Task No.: 2-Q 1,2-qND(0� Well ID: ry) tiJ _Cl Sampler(s): ���n��� %• S Well Location: Well Diameter: 2 inches Initial Depth to Water (DTW): feet Depth to Bottom (DTB): feet Water Column Thickness (WCT): 9 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 l j = 1. 1 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 gallons Actual Amount Purged/Bailed: 1. % -S gallons Purged with: Bailer Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: 3�• feet Gallons Time Temp (°C) pH Cond. (us/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials Date of sample: �� /� '2lAli Before Sampling Comments (weather conditions, odor, color, silt, etc.): SSO ' S Sv (?/?Lf -=7 PCct-i-I, i clo voq Signature: _?/7 Date: QA/QC Sign Off: Date: C� Q_., LaBelLa DATE: 11 // %0? 11 /z/2/ Ro+jveOhy.pottnersnip GROUND WATER SAMPLING LOG Project Name: &c4 69K'r-ks�Project No. /Task No.: a Ala 7 7D k Q Well ID: I' )W— Sampler(s): f•Wrgk4-, K•ES�e_S Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches 36 • Iq feet Sb• � feet 1q ' 6c feet [DTB-DTW] Q• gallons _ gallons gallons 2 gallons Depth to Water before Sampling:feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials O jS�Z9 �6. -2 q�- a b 1331 Is. `� SA �2 2o. 6 `7-. 6 S Il o, 2 00C' 57 0 20.3 ( 1�`�. >two Date of sample: ( I/ ! Before Sampling 0-1j-0 14 ,q '5-,N 95-- 4; 1 *-.S 7 110'q /So Comments (weather conditions, odor, color, silt, etc.): 5s &Y) a'-1 -'�o (-4, Signature: . Date: 1 1 /g121 QA/QC Sign off: Date: 11- q - 21 n_ LaePua DATE: Powereid by partnership, GROUNDWATER SAMPLING LOG Project Name: [�X4 ��' ���cK$e'�' �" Project No. No.: Qa1a-7qo lu2 Well ID: � —�S Sampler(s): f•"k4-I k-CS41r-5 Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): nches l0. �2-S- feet �2q• .56 feet 0` 3 l feet [DTB-DTW] For 2" Well: WCT X 0.163 = �•`� gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = �'� gallons Actual Amount Purged/Bailed: c�. `) gallons Purged with: C6 Pump Other: Sampled with: Bailers Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials d 1636 16•5 512� u ,L1 7.yy � 6 16Nl 16.q y, -gs,S 3.qv qS, , oQ go. `i S.615 5-3. b / Date of sample: Before Sampling: �.�5" -��,� N• 3 � g�. 2 1$. � �i "� Comments (weather conditions, odor, color, silt, etc. Sb's -1100f►L1 ---? Sb`S PZ-<4kY r_laX),41- Signature: 7— (, QA/QC Sign Off: > e 0 173c� vDate: 1119121 Date: P LaB( Ua DATE: J 1 I GROUND WATER SAMPLING LOG Project Name: �);?i l Ga. KY !' • Project No. /Task No.: 102 Well ID: Sampler(s): K- ESkS . L • W�U 4- Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 2 inches 0 feet 15 feet '5-I. l �5- feet [DTB-DTW] _ 3 gallons gallons �•� 0,gIInn- Actual Amount Purged/Bailed: gallons Purged with: Bailer umrn Other: 12 Sampled with: Bailer um Other: I� V Depth to Water before Sampling: feet Gallons Time Temp pH Cond. Dis.02 ORP Turb. Initials (OC) (S.U.) (pS/cm) (mg/L) (mV) (NTU) 0 16t y /s-,q -f of jV. o 1. 6� --65. 0 )S Q 6.S7 l27.5- 0.-45 --�.TS Date of sample: Before Sampling: Comments (weather conditions, odor, color, silt, etc.): � Qa� bo44(e.,s , sV's ScVn �k- Signature: QA/QC Sign Off: Date: Date: P LaBella DATE: I I1�2/2) SURFACE WATER MONITORING LOG Project Name: �'Xk2 �, '—� ``"�"h �� Project/Task No.: 22 127No%- Surface Point ID: 3W — i Sampler(s): k • 2-TLeS Location: Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential .MfAi II . (0C) 5 • `� (US/cm) (ntu) (mg/L) —SS. 0 (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): Sb" s �2r-I C� io d✓1 7 Summary/Sketch of Sampling Location 2 Z Signature:Z' �✓�� QA/QC Sign 0ff: Date: I I / Gr .? I Date: n LaBeLla DATE: 1111 2 SURFACE WATER MONITORING LOG Project Name: Dike Co.- K,AkINY Project/Task No.:aa I a"79o/UQ Surface Point ID: 'S I", �a Sampler(s):fI ►q'k� k• BLS Location: Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential 6, ag 13. 6 (°C) Il�b- (US/CM) �• 1 (ntu) (mg/L) `��• (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): s S,o n Signature: ham/ QA/QC Sign Off: Summary/Sketch of Sampling Location PI W rw 3p /►'► w -3 Date: 111 g121 Date: ll- `7 - g� n LaBelta DATE: II/ IQ SURFACE WATER MONITORING LOG Project Name:K,(e (oIN-. Project/Task No.: Surface Point ID: SL,; ' Sampler(s): �• ��q'� �" , X• G�� Location: Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential 5-us 6.aa (0C) (US/cm) (ntu) 6`. $ (mg/L) —SS• ` (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): 5-6 Summary/Sketch of Sampling Location 0 F/©c-.D © e Signature: Date: QA/QC Sign Off• Date: leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 17, 2021 Mr. Van Burbach Joyce Engineering -Greensboro 12-D Oak Branch Drive Greensboro, NC 27407 RE: Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on November 03, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Kandice Estes, Labella Associates Miguel Vazquez, Joyce Engineering Elina Wright, LaBella Associates, D.P.C. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 52 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Lab ID Sample ID Matrix Date Collected Date Received 92570457001 1201-MW2 Water 11/01/2115:44 11/03/21 08:25 92570457002 1201-MW3S Water 11/02/21 08:56 11/03/21 08:25 92570457003 1201-MW3D Water 11/01/2114:27 11/03/21 08:25 92570457004 1201-MW4 Water 11/02/2109:18 11/03/21 08:25 92570457005 1201-MW5 Water 11/02/21 07:50 11/03/21 08:25 92570457006 1201-MW6S Water 11/02/2109:25 11/03/21 08:25 92570457007 1201-MW6D Water 11/01/2116:26 11/03/21 08:25 92570457008 1201-SW1 Water 11/02/21 09:07 11/03/21 08:25 92570457009 1201-SW2 Water 11/01/2115:15 11/03/21 08:25 92570457010 1201-SW3 Water 11/01/21 15:05 11/03/21 08:25 92570457011 1201-FILED BLANK Water 11/02/21 09:30 11/03/21 08:25 92570457012 1201-TRIP BLANK Water 11/01/21 00:00 11/03/21 08:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: BURKE CO. - KIRKSEY DRIVE 92570457 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92570457001 1201-MW2 EPA 601OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457002 1201-MW3S EPA 601OD CBV 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457003 1201-MW3D EPA 601OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457004 1201-MW4 EPA 601OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457005 1201-MW5 EPA 601OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457006 1201-MW6S EPA 601OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457007 1201-MW6D EPA 601OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457008 1201-SW1 EPA 601OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457009 1201-SW2 EPA 601OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457010 1201-SW3 EPA 601OD JOR 14 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457011 1201-FILED BLANK EPA 601OD JOR 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92570457012 1201-TRIP BLANK EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: BURKE CO. - KIRKSEY DRIVE 92570457 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92570457001 1201-MW2 EPA 601OD Barium 1550 ug/L 5.0 11/17/2106:58 EPA 601OD Cobalt 116 ug/L 5.0 11/17/2106:58 EPA 601OD Nickel 20.5 ug/L 5.0 11/17/2106:58 EPA 601OD Silver 5.6 ug/L 5.0 11/17/2106:58 EPA 601OD Vanadium 59.9 ug/L 5.0 11/17/2106:58 EPA8260D Benzene 8.9 ug/L 1.0 11/08/2116:29 EPA8260D Chlorobenzene 24.5 ug/L 1.0 11/08/2116:29 EPA8260D 1,2-Dichlorobenzene 2.1 ug/L 1.0 11/08/2116:29 EPA8260D 1,4-Dichlorobenzene 33.7 ug/L 1.0 11/08/2116:29 EPA8260D 1,1-Dichloroethane 0.49J ug/L 1.0 11/08/2116:29 EPA8260D Ethylbenzene 10.7 ug/L 1.0 11/08/2116:29 EPA8260D 4-Methyl-2-pentanone(MIBK) 5.0 ug/L 5.0 11/08/2116:29 EPA8260D Toluene 1.0 ug/L 1.0 11/08/2116:29 EPA8260D Xylene(Total) 18.2 ug/L 1.0 11/08/2116:29 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 279 ug/L 10.0 11/04/21 22:16 92570457002 1201-MW3S EPA 601OD Barium 467 ug/L 5.0 11/08/2100:53 EPA 601OD Cobalt 12.4 ug/L 5.0 11/08/2100:53 EPA 601OD Nickel 5.3 ug/L 5.0 11/08/2100:53 EPA 601OD Silver 2.6J ug/L 5.0 11/08/2100:53 EPA 601OD Vanadium 23.3 ug/L 5.0 11/08/2100:53 EPA8260D Benzene 3.1 ug/L 1.0 11/08/2116:37 EPA8260D Chlorobenzene 32.3 ug/L 1.0 11/08/2116:37 EPA8260D Chloroethane 1.7 ug/L 1.0 11/08/2116:37 EPA8260D 1,2-Dichlorobenzene 0.49J ug/L 1.0 11/08/2116:37 EPA8260D 1,4-Dichlorobenzene 9.0 ug/L 1.0 11/08/2116:37 EPA8260D Xylene(Total) 13.3 ug/L 1.0 11/08/2116:37 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 34.1 ug/L 2.0 11/04/21 21:57 92570457003 1201-MW3D EPA 601OD Barium 202 ug/L 5.0 11/05/2120:01 EPA 601OD Nickel 28.9 ug/L 5.0 11/05/2120:01 EPA8260D Benzene 1.5 ug/L 1.0 11/08/2116:47 EPA8260D Chlorobenzene 8.8 ug/L 1.0 11/08/2116:47 EPA8260D 1,4-Dichlorobenzene 3.9 ug/L 1.0 11/08/2116:47 EPA8260D 1,1-Dichloroethane 5.5 ug/L 1.0 11/08/2116:47 EPA8260D cis-1,2-Dichloroethene 22.9 ug/L 1.0 11/08/2116:47 EPA8260D 1,2-Dichloropropane 0.72J ug/L 1.0 11/08/2116:47 EPA8260D Tetrachloroethene 7.7 ug/L 1.0 11/08/2116:47 EPA8260D Trichloroethene 5.7 ug/L 1.0 11/08/2116:47 EPA8260D Vinyl chloride 1.1 ug/L 1.0 11/08/21 16:47 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 95.7 ug/L 4.0 11/04/21 23:07 92570457004 1201-MW4 EPA 601OD Barium 110 ug/L 5.0 11/17/2107:01 EPA 601OD Chromium 4.3J ug/L 5.0 11/17/2107:01 EPA 601OD Copper 4.5J ug/L 5.0 11/17/2107:01 EPA 601OD Vanadium 9.9 ug/L 5.0 11/17/2107:01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: BURKE CO. - KIRKSEY DRIVE 92570457 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92570457004 1201-MW4 EPA8260D 1,1-Dichloroethane 0.65J ug/L 1.0 11/08/2116:55 EPA8260D cis-1,2-Dichloroethene 5.6 ug/L 1.0 11/08/2116:55 EPA8260D Tetrachloroethene 0.49J ug/L 1.0 11/08/2116:55 92570457005 1201-MW5 EPA 601OD Barium 46.5 ug/L 5.0 11/17/2107:04 EPA 601OD Vanadium 5.1 ug/L 5.0 11/17/2107:04 EPA6020B Thallium 0.151 ug/L 0.47 11/08/2123:10 92570457006 1201-MW6S EPA 601OD Barium 26.2 ug/L 5.0 11/05/2120:11 EPA 601OD Cadmium 0.65J ug/L 1.0 11/05/2120:11 EPA8260D Chloroform 0.88J ug/L 1.0 11/08/2117:13 92570457007 1201-MW6D EPA 601OD Barium 13.5 ug/L 5.0 11/05/2120:14 92570457008 1201-SW1 EPA 601OD Barium 30.5 ug/L 5.0 11/17/2107:08 92570457009 1201-SW2 EPA 601OD Barium 31.8 ug/L 5.0 11/17/2107:11 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 1.4J ug/L 2.0 11/04/21 19:42 92570457010 1201-SW3 EPA 601OD Barium 30.8 ug/L 5.0 11/17/2107:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW2 Lab ID: 92570457001 Collected: 11/01/21 15:44 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2106:58 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2106:58 7440-38-2 Barium 1550 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2106:58 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2106:58 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2106:58 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2106:58 7440-47-3 Cobalt 116 ug/L 5.0 3.6 1 11/11/2110:54 11/17/2106:58 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2106:58 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2106:58 7439-92-1 Nickel 20.5 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2106:58 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2106:58 7782-49-2 Silver 5.6 ug/L 5.0 2.5 1 11/11/2110:54 11/17/2106:58 7440-22-4 Vanadium 59.9 ug/L 5.0 3.9 1 11/11/2110:54 11/17/2106:58 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2106:58 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2122:56 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 16:29 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 16:29 107-13-1 Benzene 8.9 ug/L 1.0 0.34 1 11/08/21 16:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 16:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 16:29 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 16:29 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 16:29 74-83-9 IH 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 16:29 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 16:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 16:29 56-23-5 Chlorobenzene 24.5 ug/L 1.0 0.28 1 11/08/21 16:29 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 16:29 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 16:29 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 16:29 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 16:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 16:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 16:29 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 16:29 74-95-3 1,2-Dichlorobenzene 2.1 ug/L 1.0 0.34 1 11/08/21 16:29 95-50-1 1,4-Dichlorobenzene 33.7 ug/L 1.0 0.33 1 11/08/21 16:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 16:29 110-57-6 1,1-Dichloroethane 0.49J ug/L 1.0 0.37 1 11/08/21 16:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 16:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 16:29 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW2 Lab ID: 92570457001 Collected: 11/01/21 15:44 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2116:29 156-59-2 ND ug/L 1.0 0.40 1 11/08/2116:29 156-60-5 ND ug/L 1.0 0.36 1 11/08/2116:29 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 16:29 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 16:29 10061-02-6 10.7 ug/L 1.0 0.30 1 11/08/2116:29 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 16:29 591-78-6 ND ug/L 20.0 9.7 1 11/08/2116:29 74-88-4 ND ug/L 5.0 2.0 1 11/08/2116:29 75-09-2 5.0 ug/L 5.0 2.7 1 11/08/2116:29 108-10-1 ND ug/L 1.0 0.29 1 11/08/2116:29 100-42-5 ND ug/L 1.0 0.31 1 11/08/2116:29 630-20-6 ND ug/L 1.0 0.22 1 11/08/2116:29 79-34-5 ND ug/L 1.0 0.29 1 11/08/2116:29 127-18-4 1.0 ug/L 1.0 0.48 1 11/08/2116:29 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 16:29 71-55-6 ND ug/L 1.0 0.32 1 11/08/2116:29 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 16:29 79-01-6 ND ug/L 1.0 0.30 1 11/08/2116:29 75-69-4 ND ug/L 1.0 0.26 1 11/08/2116:29 96-18-4 ND ug/L 2.0 1.3 1 11/08/2116:29 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 16:29 75-01-4 18.2 ug/L 1.0 0.34 1 11/08/2116:29 1330-20-7 100 % 70-130 1 11/08/2116:29 460-00-4 102 % 70-130 1 11/08/2116:29 17060-07-0 100 % 70-130 1 11/08/2116:29 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 279 ug/L 10.0 4.3 5 11/04/2122:16 123-91-1 86 % 70-130 5 11/04/2122:16 17060-07-0 87 % 66-133 5 11/04/2122:16 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW3S Lab ID: 92570457002 Collected: 11/02/21 08:56 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/04/2116:09 11/08/2100:53 7440-36-0 BC Arsenic ND ug/L 10.0 4.7 1 11/04/2116:09 11/08/2100:53 7440-38-2 Barium 467 ug/L 5.0 3.5 1 11/04/2116:09 11/08/2100:53 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/04/2116:09 11/08/2100:53 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/04/2116:09 11/08/2100:53 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/04/2116:09 11/08/2100:53 7440-47-3 Cobalt 12.4 ug/L 5.0 3.6 1 11/04/2116:09 11/08/2100:53 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/04/2116:09 11/08/2100:53 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/04/2116:09 11/08/2100:53 7439-92-1 Nickel 5.3 ug/L 5.0 3.5 1 11/04/2116:09 11/08/2100:53 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/04/2116:09 11/08/2100:53 7782-49-2 Silver 2.6J ug/L 5.0 2.5 1 11/04/2116:09 11/08/2100:53 7440-22-4 Vanadium 23.3 ug/L 5.0 3.9 1 11/04/2116:09 11/08/2100:53 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/04/2116:09 11/08/2100:53 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene Date: 11/17/2021 12:32 PM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:00 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 11/08/2116:37 67-64-1 ND ug/L 10.0 1.8 1 11/08/2116:37 107-13-1 3.1 ug/L 1.0 0.34 1 11/08/2116:37 71-43-2 ND ug/L 1.0 0.47 1 11/08/2116:37 74-97-5 ND ug/L 1.0 0.31 1 11/08/2116:37 75-27-4 ND ug/L 1.0 0.34 1 11/08/2116:37 75-25-2 ND ug/L 2.0 1.7 1 11/08/2116:37 74-83-9 ND ug/L 5.0 4.0 1 11/08/2116:37 78-93-3 ND ug/L 2.0 0.73 1 11/08/2116:37 75-15-0 ND ug/L 1.0 0.33 1 11/08/2116:37 56-23-5 32.3 ug/L 1.0 0.28 1 11/08/2116:37 108-90-7 1.7 ug/L 1.0 0.65 1 11/08/2116:37 75-00-3 ND ug/L 1.0 0.43 1 11/08/2116:37 67-66-3 ND ug/L 1.0 0.54 1 11/08/2116:37 74-87-3 ND ug/L 2.0 0.34 1 11/08/2116:37 96-12-8 ND ug/L 1.0 0.36 1 11/08/2116:37 124-48-1 ND ug/L 1.0 0.27 1 11/08/2116:37 106-93-4 ND ug/L 1.0 0.39 1 11/08/2116:37 74-95-3 0.49J ug/L 1.0 0.34 1 11/08/2116:37 95-50-1 9.0 ug/L 1.0 0.33 1 11/08/2116:37 106-46-7 ND ug/L 1.0 0.56 1 11/08/2116:37 110-57-6 ND ug/L 1.0 0.37 1 11/08/2116:37 75-34-3 ND ug/L 1.0 0.32 1 11/08/2116:37 107-06-2 ND ug/L 1.0 0.35 1 11/08/2116:37 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW3S Lab ID: 92570457002 Collected: 11/02/21 08:56 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2116:37 156-59-2 ND ug/L 1.0 0.40 1 11/08/2116:37 156-60-5 ND ug/L 1.0 0.36 1 11/08/2116:37 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 16:37 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 16:37 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 16:37 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 16:37 591-78-6 ND ug/L 20.0 9.7 1 11/08/2116:37 74-88-4 ND ug/L 5.0 2.0 1 11/08/2116:37 75-09-2 ND ug/L 5.0 2.7 1 11/08/2116:37 108-10-1 ND ug/L 1.0 0.29 1 11/08/2116:37 100-42-5 ND ug/L 1.0 0.31 1 11/08/2116:37 630-20-6 ND ug/L 1.0 0.22 1 11/08/2116:37 79-34-5 ND ug/L 1.0 0.29 1 11/08/2116:37 127-18-4 ND ug/L 1.0 0.48 1 11/08/2116:37 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 16:37 71-55-6 ND ug/L 1.0 0.32 1 11/08/2116:37 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 16:37 79-01-6 ND ug/L 1.0 0.30 1 11/08/2116:37 75-69-4 ND ug/L 1.0 0.26 1 11/08/2116:37 96-18-4 ND ug/L 2.0 1.3 1 11/08/2116:37 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 16:37 75-01-4 13.3 ug/L 1.0 0.34 1 11/08/2116:37 1330-20-7 97 % 70-130 1 11/08/2116:37 460-00-4 103 % 70-130 1 11/08/2116:37 17060-07-0 100 % 70-130 1 11/08/2116:37 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 34.1 ug/L 2.0 0.86 1 11/04/2121:57 123-91-1 86 % 70-130 1 11/04/2121:57 17060-07-0 89 % 66-133 1 11/04/2121:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW3D Lab ID: 92570457003 Collected: 11/01/21 14:27 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/04/2116:09 11/05/2120:01 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/04/2116:09 11/05/2120:01 7440-38-2 Barium 202 ug/L 5.0 3.5 1 11/04/2116:09 11/05/2120:01 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/04/2116:09 11/05/2120:01 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/04/2116:09 11/05/2120:01 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/04/2116:09 11/05/2120:01 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/04/2116:09 11/05/2120:01 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/04/2116:09 11/05/2120:01 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/04/2116:09 11/05/2120:01 7439-92-1 Nickel 28.9 ug/L 5.0 3.5 1 11/04/2116:09 11/05/2120:01 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/04/2116:09 11/05/2120:01 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/04/2116:09 11/05/2120:01 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/04/2116:09 11/05/2120:01 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/04/2116:09 11/05/2120:01 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:03 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 16:47 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 16:47 107-13-1 Benzene 1.5 ug/L 1.0 0.34 1 11/08/21 16:47 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 16:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 16:47 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 16:47 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 16:47 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 16:47 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 16:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 16:47 56-23-5 Chlorobenzene 8.8 ug/L 1.0 0.28 1 11/08/21 16:47 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 16:47 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 16:47 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 16:47 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 16:47 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 16:47 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 16:47 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 16:47 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 16:47 95-50-1 1,4-Dichlorobenzene 3.9 ug/L 1.0 0.33 1 11/08/21 16:47 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 16:47 110-57-6 1,1-Dichloroethane 5.5 ug/L 1.0 0.37 1 11/08/21 16:47 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 16:47 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 16:47 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. IH v2 Page 12 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW3D Lab ID: 92570457003 Collected: 11/01/21 14:27 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 22.9 ug/L 1.0 0.38 1 11/08/2116:47 156-59-2 ND ug/L 1.0 0.40 1 11/08/2116:47 156-60-5 0.72J ug/L 1.0 0.36 1 11/08/2116:47 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 16:47 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 16:47 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 16:47 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 16:47 591-78-6 ND ug/L 20.0 9.7 1 11/08/2116:47 74-88-4 ND ug/L 5.0 2.0 1 11/08/2116:47 75-09-2 ND ug/L 5.0 2.7 1 11/08/2116:47 108-10-1 ND ug/L 1.0 0.29 1 11/08/2116:47 100-42-5 ND ug/L 1.0 0.31 1 11/08/2116:47 630-20-6 ND ug/L 1.0 0.22 1 11/08/2116:47 79-34-5 7.7 ug/L 1.0 0.29 1 11/08/2116:47 127-18-4 ND ug/L 1.0 0.48 1 11/08/2116:47 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 16:47 71-55-6 ND ug/L 1.0 0.32 1 11/08/2116:47 79-00-5 5.7 ug/L 1.0 0.38 1 11/08/2116:47 79-01-6 ND ug/L 1.0 0.30 1 11/08/2116:47 75-69-4 ND ug/L 1.0 0.26 1 11/08/2116:47 96-18-4 ND ug/L 2.0 1.3 1 11/08/2116:47 108-05-4 1.1 ug/L 1.0 0.39 1 11/08/2116:47 75-01-4 ND ug/L 1.0 0.34 1 11/08/2116:47 1330-20-7 100 % 70-130 1 11/08/2116:47 460-00-4 106 % 70-130 1 11/08/2116:47 17060-07-0 100 % 70-130 1 11/08/2116:47 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 95.7 ug/L 4.0 1.7 2 11/04/2123:07 123-91-1 94 % 70-130 2 11/04/2123:07 17060-07-0 96 % 66-133 2 11/04/2123:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW4 Lab ID: 92570457004 Collected: 11/02/21 09:18 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:01 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:01 7440-38-2 Barium 110 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:01 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:01 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:01 7440-43-9 Chromium 4.3.1 ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:01 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:01 7440-48-4 Copper 4.5.1 ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:01 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:01 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:01 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:01 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:01 7440-22-4 Vanadium 9.9 ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:01 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:01 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:07 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 16:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 16:55 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 16:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 16:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 16:55 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 16:55 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 16:55 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 16:55 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 16:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 16:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 16:55 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 16:55 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 16:55 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 16:55 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 16:55 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 16:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 16:55 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 16:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 16:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 16:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 16:55 110-57-6 1,1-Dichloroethane 0.65J ug/L 1.0 0.37 1 11/08/21 16:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 16:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 16:55 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW4 Lab ID: 92570457004 Collected: 11/02/21 09:18 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 5.6 ug/L 1.0 0.38 1 11/08/2116:55 156-59-2 ND ug/L 1.0 0.40 1 11/08/2116:55 156-60-5 ND ug/L 1.0 0.36 1 11/08/2116:55 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 16:55 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 16:55 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 16:55 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 16:55 591-78-6 ND ug/L 20.0 9.7 1 11/08/2116:55 74-88-4 ND ug/L 5.0 2.0 1 11/08/2116:55 75-09-2 ND ug/L 5.0 2.7 1 11/08/2116:55 108-10-1 ND ug/L 1.0 0.29 1 11/08/2116:55 100-42-5 ND ug/L 1.0 0.31 1 11/08/2116:55 630-20-6 ND ug/L 1.0 0.22 1 11/08/2116:55 79-34-5 0.49J ug/L 1.0 0.29 1 11/08/2116:55 127-18-4 ND ug/L 1.0 0.48 1 11/08/2116:55 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 16:55 71-55-6 ND ug/L 1.0 0.32 1 11/08/2116:55 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 16:55 79-01-6 ND ug/L 1.0 0.30 1 11/08/2116:55 75-69-4 ND ug/L 1.0 0.26 1 11/08/2116:55 96-18-4 ND ug/L 2.0 1.3 1 11/08/2116:55 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 16:55 75-01-4 ND ug/L 1.0 0.34 1 11/08/2116:55 1330-20-7 98 % 70-130 1 11/08/2116:55 460-00-4 105 % 70-130 1 11/08/2116:55 17060-07-0 101 % 70-130 1 11/08/2116:55 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2118:06 123-91-1 88 % 70-130 1 11/04/2118:06 17060-07-0 90 % 66-133 1 11/04/2118:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW5 Lab ID: 92570457005 Collected: 11/02/21 07:50 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:04 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:04 7440-38-2 Barium 46.5 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:04 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:04 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:04 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:04 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:04 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:04 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:04 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:04 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:04 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:04 7440-22-4 Vanadium 5.1 ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:04 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:04 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.15J ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:10 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 14:30 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 14:30 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 14:30 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 14:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 14:30 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 14:30 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 14:30 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 14:30 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 14:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 14:30 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 14:30 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 14:30 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 14:30 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 14:30 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 14:30 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 14:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 14:30 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 14:30 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 14:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 14:30 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 14:30 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 14:30 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 14:30 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 14:30 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW5 Lab ID: 92570457005 Collected: 11/02/21 07:50 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2114:30 156-59-2 ND ug/L 1.0 0.40 1 11/08/2114:30 156-60-5 ND ug/L 1.0 0.36 1 11/08/2114:30 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 14:30 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 14:30 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 14:30 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 14:30 591-78-6 ND ug/L 20.0 9.7 1 11/08/2114:30 74-88-4 ND ug/L 5.0 2.0 1 11/08/2114:30 75-09-2 ND ug/L 5.0 2.7 1 11/08/2114:30 108-10-1 ND ug/L 1.0 0.29 1 11/08/2114:30 100-42-5 ND ug/L 1.0 0.31 1 11/08/2114:30 630-20-6 ND ug/L 1.0 0.22 1 11/08/2114:30 79-34-5 ND ug/L 1.0 0.29 1 11/08/2114:30 127-18-4 ND ug/L 1.0 0.48 1 11/08/2114:30 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 14:30 71-55-6 ND ug/L 1.0 0.32 1 11/08/2114:30 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 14:30 79-01-6 ND ug/L 1.0 0.30 1 11/08/2114:30 75-69-4 ND ug/L 1.0 0.26 1 11/08/2114:30 96-18-4 ND ug/L 2.0 1.3 1 11/08/2114:30 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 14:30 75-01-4 ND ug/L 1.0 0.34 1 11/08/2114:30 1330-20-7 98 % 70-130 1 11/08/2114:30 460-00-4 103 % 70-130 1 11/08/2114:30 17060-07-0 101 % 70-130 1 11/08/2114:30 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2118:25 123-91-1 86 % 70-130 1 11/04/2118:25 17060-07-0 89 % 66-133 1 11/04/2118:25 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW6S Lab ID: 92570457006 Collected: 11/02/21 09:25 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/04/2116:09 11/05/2120:11 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/04/2116:09 11/05/2120:11 7440-38-2 Barium 26.2 ug/L 5.0 3.5 1 11/04/2116:09 11/05/2120:11 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/04/2116:09 11/05/2120:11 7440-41-7 Cadmium 0.65.1 ug/L 1.0 0.40 1 11/04/2116:09 11/05/2120:11 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/04/2116:09 11/05/2120:11 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/04/2116:09 11/05/2120:11 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/04/2116:09 11/05/2120:11 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/04/2116:09 11/05/2120:11 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/04/2116:09 11/05/2120:11 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/04/2116:09 11/05/2120:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/04/2116:09 11/05/2120:11 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/04/2116:09 11/05/2120:11 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/04/2116:09 11/05/2120:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:14 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 17:13 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 17:13 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 17:13 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 17:13 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 17:13 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 17:13 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 17:13 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 17:13 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 17:13 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 17:13 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 17:13 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 17:13 75-00-3 Chloroform 0.88J ug/L 1.0 0.43 1 11/08/21 17:13 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 17:13 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 17:13 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 17:13 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 17:13 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 17:13 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 17:13 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 17:13 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 17:13 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 17:13 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 17:13 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 17:13 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW6S Lab ID: 92570457006 Collected: 11/02/21 09:25 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2117:13 156-59-2 ND ug/L 1.0 0.40 1 11/08/2117:13 156-60-5 ND ug/L 1.0 0.36 1 11/08/2117:13 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 17:13 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 17:13 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 17:13 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 17:13 591-78-6 ND ug/L 20.0 9.7 1 11/08/2117:13 74-88-4 ND ug/L 5.0 2.0 1 11/08/2117:13 75-09-2 ND ug/L 5.0 2.7 1 11/08/2117:13 108-10-1 ND ug/L 1.0 0.29 1 11/08/2117:13 100-42-5 ND ug/L 1.0 0.31 1 11/08/2117:13 630-20-6 ND ug/L 1.0 0.22 1 11/08/2117:13 79-34-5 ND ug/L 1.0 0.29 1 11/08/2117:13 127-18-4 ND ug/L 1.0 0.48 1 11/08/2117:13 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 17:13 71-55-6 ND ug/L 1.0 0.32 1 11/08/2117:13 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 17:13 79-01-6 ND ug/L 1.0 0.30 1 11/08/2117:13 75-69-4 ND ug/L 1.0 0.26 1 11/08/2117:13 96-18-4 ND ug/L 2.0 1.3 1 11/08/2117:13 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 17:13 75-01-4 ND ug/L 1.0 0.34 1 11/08/2117:13 1330-20-7 98 % 70-130 1 11/08/2117:13 460-00-4 105 % 70-130 1 11/08/2117:13 17060-07-0 101 % 70-130 1 11/08/2117:13 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2118:44 123-91-1 87 % 70-130 1 11/04/2118:44 17060-07-0 90 % 66-133 1 11/04/2118:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW6D Lab ID: 92570457007 Collected: 11/01/21 16:26 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/04/2116:09 11/05/2120:14 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/04/2116:09 11/05/2120:14 7440-38-2 Barium 13.5 ug/L 5.0 3.5 1 11/04/2116:09 11/05/2120:14 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/04/2116:09 11/05/2120:14 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/04/2116:09 11/05/2120:14 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/04/2116:09 11/05/2120:14 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/04/2116:09 11/05/2120:14 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/04/2116:09 11/05/2120:14 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/04/2116:09 11/05/2120:14 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/04/2116:09 11/05/2120:14 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/04/2116:09 11/05/2120:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/04/2116:09 11/05/2120:14 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/04/2116:09 11/05/2120:14 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/04/2116:09 11/05/2120:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:17 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 15:02 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 15:02 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 15:02 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 15:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 15:02 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 15:02 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 15:02 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 15:02 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 15:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 15:02 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 15:02 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 15:02 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 15:02 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 15:02 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 15:02 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 15:02 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 15:02 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 15:02 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 15:02 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 15:02 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 15:02 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 15:02 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 15:02 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 15:02 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. IH v1 Page 20 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-MW6D Lab ID: 92570457007 Collected: 11/01/21 16:26 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2115:02 156-59-2 ND ug/L 1.0 0.40 1 11/08/2115:02 156-60-5 ND ug/L 1.0 0.36 1 11/08/2115:02 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 15:02 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 15:02 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 15:02 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 15:02 591-78-6 ND ug/L 20.0 9.7 1 11/08/2115:02 74-88-4 ND ug/L 5.0 2.0 1 11/08/2115:02 75-09-2 ND ug/L 5.0 2.7 1 11/08/2115:02 108-10-1 ND ug/L 1.0 0.29 1 11/08/2115:02 100-42-5 ND ug/L 1.0 0.31 1 11/08/2115:02 630-20-6 ND ug/L 1.0 0.22 1 11/08/2115:02 79-34-5 ND ug/L 1.0 0.29 1 11/08/2115:02 127-18-4 ND ug/L 1.0 0.48 1 11/08/2115:02 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 15:02 71-55-6 ND ug/L 1.0 0.32 1 11/08/2115:02 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 15:02 79-01-6 ND ug/L 1.0 0.30 1 11/08/2115:02 75-69-4 ND ug/L 1.0 0.26 1 11/08/2115:02 96-18-4 ND ug/L 2.0 1.3 1 11/08/2115:02 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 15:02 75-01-4 ND ug/L 1.0 0.34 1 11/08/2115:02 1330-20-7 97 % 70-130 1 11/08/2115:02 460-00-4 105 % 70-130 1 11/08/2115:02 17060-07-0 100 % 70-130 1 11/08/2115:02 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2119:04 123-91-1 85 % 70-130 1 11/04/2119:04 17060-07-0 90 % 66-133 1 11/04/2119:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-SW1 Lab ID: 92570457008 Collected: 11/02/21 09:07 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:08 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:08 7440-38-2 Barium 30.5 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:08 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:08 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:08 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:08 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:08 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:08 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:08 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:08 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:08 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:08 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:08 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:21 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 14:48 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 14:48 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 14:48 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 14:48 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 14:48 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 14:48 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 14:48 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 14:48 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 14:48 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 14:48 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 14:48 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 14:48 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 14:48 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 14:48 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 14:48 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 14:48 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 14:48 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 14:48 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 14:48 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 14:48 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 14:48 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 14:48 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 14:48 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 14:48 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-SW1 Lab ID: 92570457008 Collected: 11/02/21 09:07 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2114:48 156-59-2 ND ug/L 1.0 0.40 1 11/08/2114:48 156-60-5 ND ug/L 1.0 0.36 1 11/08/2114:48 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 14:48 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 14:48 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 14:48 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 14:48 591-78-6 ND ug/L 20.0 9.7 1 11/08/2114:48 74-88-4 ND ug/L 5.0 2.0 1 11/08/2114:48 75-09-2 ND ug/L 5.0 2.7 1 11/08/2114:48 108-10-1 ND ug/L 1.0 0.29 1 11/08/2114:48 100-42-5 ND ug/L 1.0 0.31 1 11/08/2114:48 630-20-6 ND ug/L 1.0 0.22 1 11/08/2114:48 79-34-5 ND ug/L 1.0 0.29 1 11/08/2114:48 127-18-4 ND ug/L 1.0 0.48 1 11/08/2114:48 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 14:48 71-55-6 ND ug/L 1.0 0.32 1 11/08/2114:48 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 14:48 79-01-6 ND ug/L 1.0 0.30 1 11/08/2114:48 75-69-4 ND ug/L 1.0 0.26 1 11/08/2114:48 96-18-4 ND ug/L 2.0 1.3 1 11/08/2114:48 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 14:48 75-01-4 ND ug/L 1.0 0.34 1 11/08/2114:48 1330-20-7 96 % 70-130 1 11/08/2114:48 460-00-4 104 % 70-130 1 11/08/2114:48 17060-07-0 101 % 70-130 1 11/08/2114:48 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2119:23 123-91-1 88 % 70-130 1 11/04/2119:23 17060-07-0 90 % 66-133 1 11/04/2119:23 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-SW2 Lab ID: 92570457009 Collected: 11/01/21 15:15 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:11 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:11 7440-38-2 Barium 31.8 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:11 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:11 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:11 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:11 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:11 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:11 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:11 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:11 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:11 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:11 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:24 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 15:19 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 15:19 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 15:19 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 15:19 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 15:19 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 15:19 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 15:19 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 15:19 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 15:19 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 15:19 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 15:19 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 15:19 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 15:19 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 15:19 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 15:19 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 15:19 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 15:19 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 15:19 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 15:19 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 15:19 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 15:19 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 15:19 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 15:19 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 15:19 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. IH v2 Page 24 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-SW2 Lab ID: 92570457009 Collected: 11/01/21 15:15 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2115:19 156-59-2 ND ug/L 1.0 0.40 1 11/08/2115:19 156-60-5 ND ug/L 1.0 0.36 1 11/08/2115:19 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 15:19 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 15:19 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 15:19 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 15:19 591-78-6 ND ug/L 20.0 9.7 1 11/08/2115:19 74-88-4 ND ug/L 5.0 2.0 1 11/08/2115:19 75-09-2 ND ug/L 5.0 2.7 1 11/08/2115:19 108-10-1 ND ug/L 1.0 0.29 1 11/08/2115:19 100-42-5 ND ug/L 1.0 0.31 1 11/08/2115:19 630-20-6 ND ug/L 1.0 0.22 1 11/08/2115:19 79-34-5 ND ug/L 1.0 0.29 1 11/08/2115:19 127-18-4 ND ug/L 1.0 0.48 1 11/08/2115:19 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 15:19 71-55-6 ND ug/L 1.0 0.32 1 11/08/2115:19 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 15:19 79-01-6 ND ug/L 1.0 0.30 1 11/08/2115:19 75-69-4 ND ug/L 1.0 0.26 1 11/08/2115:19 96-18-4 ND ug/L 2.0 1.3 1 11/08/2115:19 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 15:19 75-01-4 ND ug/L 1.0 0.34 1 11/08/2115:19 1330-20-7 99 % 70-130 1 11/08/2115:19 460-00-4 108 % 70-130 1 11/08/2115:19 17060-07-0 101 % 70-130 1 11/08/2115:19 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1.4J ug/L 2.0 0.86 1 11/04/2119:42 123-91-1 85 % 70-130 1 11/04/2119:42 17060-07-0 89 % 66-133 1 11/04/2119:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-SW3 Lab ID: 92570457010 Collected: 11/01/21 15:05 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:14 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:14 7440-38-2 Barium 30.8 ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:14 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:14 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:14 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:14 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:14 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:14 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:14 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:14 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:14 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:14 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:35 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 15:37 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 15:37 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 15:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 15:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 15:37 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 15:37 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 15:37 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 15:37 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 15:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 15:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 15:37 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 15:37 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 15:37 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 15:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 15:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 15:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 15:37 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 15:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 15:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 15:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 15:37 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 15:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 15:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 15:37 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. IH v2 Page 26 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-SW3 Lab ID: 92570457010 Collected: 11/01/21 15:05 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2115:37 156-59-2 ND ug/L 1.0 0.40 1 11/08/2115:37 156-60-5 ND ug/L 1.0 0.36 1 11/08/2115:37 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 15:37 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 15:37 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 15:37 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 15:37 591-78-6 ND ug/L 20.0 9.7 1 11/08/2115:37 74-88-4 ND ug/L 5.0 2.0 1 11/08/2115:37 75-09-2 ND ug/L 5.0 2.7 1 11/08/2115:37 108-10-1 ND ug/L 1.0 0.29 1 11/08/2115:37 100-42-5 ND ug/L 1.0 0.31 1 11/08/2115:37 630-20-6 ND ug/L 1.0 0.22 1 11/08/2115:37 79-34-5 ND ug/L 1.0 0.29 1 11/08/2115:37 127-18-4 ND ug/L 1.0 0.48 1 11/08/2115:37 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 15:37 71-55-6 ND ug/L 1.0 0.32 1 11/08/2115:37 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 15:37 79-01-6 ND ug/L 1.0 0.30 1 11/08/2115:37 75-69-4 ND ug/L 1.0 0.26 1 11/08/2115:37 96-18-4 ND ug/L 2.0 1.3 1 11/08/2115:37 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 15:37 75-01-4 ND ug/L 1.0 0.34 1 11/08/2115:37 1330-20-7 100 % 70-130 1 11/08/2115:37 460-00-4 105 % 70-130 1 11/08/2115:37 17060-07-0 102 % 70-130 1 11/08/2115:37 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2120:01 123-91-1 88 % 70-130 1 11/04/2120:01 17060-07-0 89 % 66-133 1 11/04/2120:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-FILED BLANK Lab ID: 92570457011 Collected: 11/02/21 09:30 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 11/11/2110:54 11/17/2107:17 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:17 7440-38-2 Barium ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:17 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 11/11/2110:54 11/17/2107:17 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 11/11/2110:54 11/17/2107:17 7440-43-9 Chromium ND ug/L 5.0 3.7 1 11/11/2110:54 11/17/2107:17 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 11/11/2110:54 11/17/2107:17 7440-48-4 Copper ND ug/L 5.0 4.3 1 11/11/2110:54 11/17/2107:17 7440-50-8 Lead ND ug/L 5.0 4.5 1 11/11/2110:54 11/17/2107:17 7439-92-1 Nickel ND ug/L 5.0 3.5 1 11/11/2110:54 11/17/2107:17 7440-02-0 Selenium ND ug/L 10.0 4.7 1 11/11/2110:54 11/17/2107:17 7782-49-2 Silver ND ug/L 5.0 2.5 1 11/11/2110:54 11/17/2107:17 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 11/11/2110:54 11/17/2107:17 7440-62-2 Zinc ND ug/L 10.0 9.5 1 11/11/2110:54 11/17/2107:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 11/08/2111:14 11/08/2123:38 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/08/21 14:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/08/21 14:12 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/08/21 14:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/08/21 14:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/08/21 14:12 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/08/21 14:12 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/08/21 14:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/08/21 14:12 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 11/08/21 14:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/08/21 14:12 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/08/21 14:12 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/08/21 14:12 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/08/21 14:12 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/08/21 14:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/08/21 14:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/08/21 14:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/08/21 14:12 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/08/21 14:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/08/21 14:12 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/08/21 14:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/08/21 14:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/08/21 14:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/08/21 14:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/08/21 14:12 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-FILED BLANK Lab ID: 92570457011 Collected: 11/02/21 09:30 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 11/08/2114:12 156-59-2 ND ug/L 1.0 0.40 1 11/08/2114:12 156-60-5 ND ug/L 1.0 0.36 1 11/08/2114:12 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 14:12 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 14:12 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 14:12 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 14:12 591-78-6 ND ug/L 20.0 9.7 1 11/08/2114:12 74-88-4 ND ug/L 5.0 2.0 1 11/08/2114:12 75-09-2 ND ug/L 5.0 2.7 1 11/08/2114:12 108-10-1 ND ug/L 1.0 0.29 1 11/08/2114:12 100-42-5 ND ug/L 1.0 0.31 1 11/08/2114:12 630-20-6 ND ug/L 1.0 0.22 1 11/08/2114:12 79-34-5 ND ug/L 1.0 0.29 1 11/08/2114:12 127-18-4 ND ug/L 1.0 0.48 1 11/08/2114:12 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 14:12 71-55-6 ND ug/L 1.0 0.32 1 11/08/2114:12 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 14:12 79-01-6 ND ug/L 1.0 0.30 1 11/08/2114:12 75-69-4 ND ug/L 1.0 0.26 1 11/08/2114:12 96-18-4 ND ug/L 2.0 1.3 1 11/08/2114:12 108-05-4 ND ug/L 1.0 0.39 1 11 /08/21 14:12 75-01-4 ND ug/L 1.0 0.34 1 11/08/2114:12 1330-20-7 97 % 70-130 1 11/08/2114:12 460-00-4 103 % 70-130 1 11/08/2114:12 17060-07-0 100 % 70-130 1 11/08/2114:12 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 11/04/2116:10 123-91-1 90 % 70-130 1 11/04/2116:10 17060-07-0 91 % 66-133 1 11/04/2116:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-TRIP BLANK Lab ID: 92570457012 Collected: 11/01/21 00:00 Received: 11/03/21 08:25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 11/17/2021 12:32 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 11/08/2113:17 67-64-1 ND ug/L 10.0 1.8 1 11/08/2113:17 107-13-1 ND ug/L 1.0 0.34 1 11 /08/21 13:17 71-43-2 ND ug/L 1.0 0.47 1 11/08/2113:17 74-97-5 ND ug/L 1.0 0.31 1 11/08/2113:17 75-27-4 ND ug/L 1.0 0.34 1 11/08/2113:17 75-25-2 ND ug/L 2.0 1.7 1 11/08/2113:17 74-83-9 ND ug/L 5.0 4.0 1 11/08/2113:17 78-93-3 ND ug/L 2.0 0.73 1 11/08/2113:17 75-15-0 ND ug/L 1.0 0.33 1 11/08/2113:17 56-23-5 ND ug/L 1.0 0.28 1 11/08/2113:17 108-90-7 ND ug/L 1.0 0.65 1 11/08/2113:17 75-00-3 ND ug/L 1.0 0.43 1 11/08/2113:17 67-66-3 ND ug/L 1.0 0.54 1 11/08/2113:17 74-87-3 ND ug/L 2.0 0.34 1 11/08/2113:17 96-12-8 ND ug/L 1.0 0.36 1 11/08/2113:17 124-48-1 ND ug/L 1.0 0.27 1 11/08/2113:17 106-93-4 ND ug/L 1.0 0.39 1 11/08/2113:17 74-95-3 ND ug/L 1.0 0.34 1 11/08/2113:17 95-50-1 ND ug/L 1.0 0.33 1 11/08/2113:17 106-46-7 ND ug/L 1.0 0.56 1 11/08/2113:17 110-57-6 ND ug/L 1.0 0.37 1 11/08/2113:17 75-34-3 ND ug/L 1.0 0.32 1 11/08/2113:17 107-06-2 ND ug/L 1.0 0.35 1 11/08/2113:17 75-35-4 ND ug/L 1.0 0.38 1 11/08/2113:17 156-59-2 ND ug/L 1.0 0.40 1 11/08/2113:17 156-60-5 ND ug/L 1.0 0.36 1 11/08/2113:17 78-87-5 ND ug/L 1.0 0.36 1 11 /08/21 13:17 10061-01-5 ND ug/L 1.0 0.36 1 11 /08/21 13:17 10061-02-6 ND ug/L 1.0 0.30 1 11 /08/21 13:17 100-41-4 ND ug/L 5.0 0.48 1 11 /08/21 13:17 591-78-6 ND ug/L 20.0 9.7 1 11/08/2113:17 74-88-4 ND ug/L 5.0 2.0 1 11/08/2113:17 75-09-2 ND ug/L 5.0 2.7 1 11/08/2113:17 108-10-1 ND ug/L 1.0 0.29 1 11/08/2113:17 100-42-5 ND ug/L 1.0 0.31 1 11/08/2113:17 630-20-6 ND ug/L 1.0 0.22 1 11/08/2113:17 79-34-5 ND ug/L 1.0 0.29 1 11/08/2113:17 127-18-4 ND ug/L 1.0 0.48 1 11/08/2113:17 108-88-3 ND ug/L 1.0 0.33 1 11 /08/21 13:17 71-55-6 ND ug/L 1.0 0.32 1 11/08/2113:17 79-00-5 ND ug/L 1.0 0.38 1 11 /08/21 13:17 79-01-6 ND ug/L 1.0 0.30 1 11/08/2113:17 75-69-4 ND ug/L 1.0 0.26 1 11/08/2113:17 96-18-4 ND ug/L 2.0 1.3 1 11/08/2113:17 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IH v2 Page 30 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Sample: 1201-TRIP BLANK Parameters Lab ID: 92570457012 Collected: Report Results Units Limit 11/01/21 00:00 MDL DF Received: 11/03/21 08:25 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 11/08/21 13:17 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 11/08/21 13:17 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 11/08/21 13:17 460-00-4 1,2-Dichloroethane-d4 (S) 105 % 70-130 1 11/08/21 13:17 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 11/08/21 13:17 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 11/04/21 16:29 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 88 % 70-130 1 11/04/21 16:29 17060-07-0 Toluene-d8 (S) 91 % 66-133 1 11/04/21 16:29 2037-26-5 Date: 11/17/2021 12:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 657606 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92570457002, 92570457003, 92570457006, 92570457007 METHOD BLANK: 3447194 Matrix: Water Associated Lab Samples: 92570457002, 92570457003, 92570457006, 92570457007 Blank Reporting Parameter Units Result Limit Antimony ug/L ND 5.0 Arsenic ug/L ND 10.0 Barium ug/L ND 5.0 Beryllium ug/L ND 1.0 Cadmium ug/L ND 1.0 Chromium ug/L ND 5.0 Cobalt ug/L ND 5.0 Copper ug/L ND 5.0 Lead ug/L ND 5.0 Nickel ug/L ND 5.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.0 Vanadium ug/L ND 5.0 Zinc ug/L ND 10.0 MDL Analyzed 3.0 11 /05/21 19:02 4.7 11 /05/21 19:02 3.5 11 /05/21 19:02 0.70 11 /05/21 19:02 0.40 11 /05/21 19:02 3.7 11 /05/21 19:02 3.6 11 /05/21 19:02 4.3 11 /05/21 19:02 4.5 11 /05/21 19:02 3.5 11 /05/21 19:02 4.7 11 /05/21 19:02 2.5 11 /05/21 19:02 3.9 11 /05/21 19:02 9.5 11 /05/21 19:02 LABORATORY CONTROL SAMPLE: Parameter 3447195 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 480 96 80-120 Arsenic ug/L 500 472 94 80-120 Barium ug/L 500 474 95 80-120 Beryllium ug/L 500 485 97 80-120 Cadmium ug/L 500 492 98 80-120 Chromium ug/L 500 483 97 80-120 Cobalt ug/L 500 471 94 80-120 Copper ug/L 500 488 98 80-120 Lead ug/L 500 486 97 80-120 Nickel ug/L 500 494 99 80-120 Selenium ug/L 500 462 92 80-120 Silver ug/L 250 237 95 80-120 Vanadium ug/L 500 476 95 80-120 Zinc ug/L 500 484 97 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. Pace Project No.: 92570457 - KIRKSEY DRIVE MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3447196 3447197 MS MSD 92570483021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 519 500 104 100 75-125 4 20 Arsenic ug/L ND 500 500 518 498 104 100 75-125 4 20 Barium ug/L 99.7 500 500 610 584 102 97 75-125 4 20 Beryllium ug/L ND 500 500 515 495 103 99 75-125 4 20 Cadmium ug/L ND 500 500 530 510 106 102 75-125 4 20 Chromium ug/L 10.9 500 500 521 501 102 98 75-125 4 20 Cobalt ug/L ND 500 500 501 481 100 96 75-125 4 20 Copper ug/L 61.7 500 500 590 567 106 101 75-125 4 20 Lead ug/L ND 500 500 516 497 103 99 75-125 4 20 Nickel ug/L 5.9 500 500 528 504 104 100 75-125 5 20 Selenium ug/L ND 500 500 544 521 109 104 75-125 4 20 Silver ug/L ND 250 250 257 250 103 100 75-125 3 20 Vanadium ug/L 34.4 500 500 542 523 102 98 75-125 4 20 Zinc ug/L 19.5 500 500 542 520 105 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 659040 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92570457001, 92570457004, 92570457005, 92570457008, 92570457009, 92570457010, 92570457011 METHOD BLANK: 3454147 Matrix: Water Associated Lab Samples: 92570457001, 92570457004, 92570457005, 92570457008, 92570457009, 92570457010, 92570457011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 11/17/2105:43 Arsenic ug/L ND 10.0 4.7 11/17/2105:43 Barium ug/L ND 5.0 3.5 11/17/2105:43 Beryllium ug/L ND 1.0 0.70 11/17/2105:43 Cadmium ug/L ND 1.0 0.40 11/17/2105:43 Chromium ug/L ND 5.0 3.7 11/17/2105:43 Cobalt ug/L ND 5.0 3.6 11/17/2105:43 Copper ug/L ND 5.0 4.3 11/17/2105:43 Lead ug/L ND 5.0 4.5 11/17/2105:43 Nickel ug/L ND 5.0 3.5 11/17/2105:43 Selenium ug/L ND 10.0 4.7 11/17/2105:43 Silver ug/L ND 5.0 2.5 11/17/2105:43 Vanadium ug/L ND 5.0 3.9 11/17/2105:43 Zinc ug/L ND 10.0 9.5 11/17/2105:43 LABORATORY CONTROL SAMPLE: Parameter 3454148 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 473 95 80-120 Arsenic ug/L 500 455 91 80-120 Barium ug/L 500 478 96 80-120 Beryllium ug/L 500 486 97 80-120 Cadmium ug/L 500 470 94 80-120 Chromium ug/L 500 464 93 80-120 Cobalt ug/L 500 459 92 80-120 Copper ug/L 500 474 95 80-120 Lead ug/L 500 475 95 80-120 Nickel ug/L 500 469 94 80-120 Selenium ug/L 500 459 92 80-120 Silver ug/L 250 230 92 80-120 Vanadium ug/L 500 466 93 80-120 Zinc ug/L 500 471 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. Pace Project No.: 92570457 - KIRKSEY DRIVE MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3454149 3454150 MS MSD 92569908007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 352 347 70 69 75-125 1 20 M1 Arsenic ug/L ND 500 500 420 426 84 85 75-125 1 20 Barium ug/L 305 500 500 768 789 93 97 75-125 3 20 Beryllium ug/L 2.8 500 500 468 479 93 95 75-125 2 20 Cadmium ug/L 0.59J 500 500 458 455 92 91 75-125 1 20 Chromium ug/L 88.2 500 500 537 554 90 93 75-125 3 20 Cobalt ug/L 29.2 500 500 464 460 87 86 75-125 1 20 Copper ug/L 70.3 500 500 542 557 94 97 75-125 3 20 Lead ug/L 40.0 500 500 483 481 89 88 75-125 1 20 Nickel ug/L 51.2 500 500 494 492 89 88 75-125 0 20 Selenium ug/L ND 500 500 423 419 85 84 75-125 1 20 Silver ug/L ND 250 250 222 228 88 91 75-125 3 20 Vanadium ug/L 118 500 500 576 593 92 95 75-125 3 20 Zinc ug/L 169 500 500 629 626 92 91 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 658131 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92570457001, 92570457002, 92570457003, 92570457004, 92570457005, 92570457006, 92570457007, 92570457008,92570457009,92570457010,92570457011 METHOD BLANK: 3449622 Matrix: Water Associated Lab Samples: 92570457001, 92570457002, 92570457003, 92570457004, 92570457005, 92570457006, 92570457007, 92570457008,92570457009,92570457010,92570457011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 11/08/2122:42 LABORATORY CONTROL SAMPLE: 3449623 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 24.8 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3449624 3449625 MS MSD 92570457002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 24.9 24.7 100 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 657547 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92570457001, 92570457003, 92570457007, 92570457009, 92570457010, 92570457012 METHOD BLANK: 3446849 Matrix: Water Associated Lab Samples: 92570457001, 92570457003, 92570457007, 92570457009, 92570457010, 92570457012 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 11/08/21 13:00 1,1,1-Trichloroethane ug/L ND 1.0 0.33 11/08/21 13:00 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/08/21 13:00 1,1,2-Trichloroethane ug/L ND 1.0 0.32 11/08/21 13:00 1,1-Dichloroethane ug/L ND 1.0 0.37 11/08/21 13:00 1,1-Dichloroethene ug/L ND 1.0 0.35 11/08/21 13:00 1,2,3-Trichloropropane ug/L ND 1.0 0.26 11/08/21 13:00 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 11/08/21 13:00 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/08/21 13:00 1,2-Dichlorobenzene ug/L ND 1.0 0.34 11/08/21 13:00 1,2-Dichloroethane ug/L ND 1.0 0.32 11/08/21 13:00 1,2-Dichloropropane ug/L ND 1.0 0.36 11/08/21 13:00 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/08/21 13:00 2-Butanone (MEK) ug/L ND 5.0 4.0 11/08/21 13:00 2-Hexanone ug/L ND 5.0 0.48 11/08/21 13:00 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 11/08/21 13:00 Acetone ug/L ND 25.0 5.1 11/08/21 13:00 Acrylonitrile ug/L ND 10.0 1.8 11/08/21 13:00 Benzene ug/L ND 1.0 0.34 11/08/21 13:00 Bromochloromethane ug/L ND 1.0 0.47 11/08/21 13:00 Bromodichloromethane ug/L ND 1.0 0.31 11/08/21 13:00 Bromoform ug/L ND 1.0 0.34 11/08/21 13:00 Bromomethane ug/L ND 2.0 1.7 11/08/21 13:00 Carbon disulfide ug/L ND 2.0 0.73 11/08/21 13:00 Carbon tetrachloride ug/L ND 1.0 0.33 11/08/21 13:00 Chlorobenzene ug/L ND 1.0 0.28 11/08/21 13:00 Chloroethane ug/L ND 1.0 0.65 11/08/21 13:00 Chloroform ug/L ND 1.0 0.43 11/08/21 13:00 Chloromethane ug/L ND 1.0 0.54 11/08/21 13:00 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 11/08/21 13:00 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 11/08/21 13:00 Dibromochloromethane ug/L ND 1.0 0.36 11/08/21 13:00 Dibromomethane ug/L ND 1.0 0.39 11/08/21 13:00 Ethylbenzene ug/L ND 1.0 0.30 11/08/21 13:00 lodomethane ug/L ND 20.0 9.7 11/08/21 13:00 Methylene Chloride ug/L ND 5.0 2.0 11/08/21 13:00 Styrene ug/L ND 1.0 0.29 11/08/21 13:00 Tetrachloroethene ug/L ND 1.0 0.29 11/08/21 13:00 Toluene ug/L ND 1.0 0.48 11/08/21 13:00 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 11/08/21 13:00 IH v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 METHOD BLANK: 3446849 Matrix: Water Associated Lab Samples: 92570457001, 92570457003, 92570457007, 92570457009, 92570457010, 92570457012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 11/08/21 13:00 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 11/08/21 13:00 Trichloroethene ug/L ND 1.0 0.38 11/08/21 13:00 Trichlorofluoromethane ug/L ND 1.0 0.30 11/08/21 13:00 Vinyl acetate ug/L ND 2.0 1.3 11/08/21 13:00 Vinyl chloride ug/L ND 1.0 0.39 11/08/21 13:00 Xylene (Total) ug/L ND 1.0 0.34 11/08/21 13:00 1,2-Dichloroethane-d4 (S) % 106 70-130 11/08/21 13:00 4-Bromofluorobenzene (S) % 101 70-130 11/08/21 13:00 Toluene-d8 (S) % 101 70-130 11/08/21 13:00 LABORATORY CONTROL SAMPLE: Parameter 3446850 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 55.3 111 70-130 1,1,1-Trichloroethane ug/L 50 54.8 110 70-130 1,1,2,2-Tetrachloroethane ug/L 50 54.2 108 70-130 1,1,2-Trichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethene ug/L 50 53.2 106 70-132 1,2,3-Trichloropropane ug/L 50 59.2 118 70-130 1,2-Dibromo-3-chloropropane ug/L 50 56.4 113 70-132 1,2-Dibromoethane (EDB) ug/L 50 54.3 109 70-130 1,2-Dichlorobenzene ug/L 50 52.8 106 70-130 1,2-Dichloroethane ug/L 50 51.8 104 70-130 1,2-Dichloropropane ug/L 50 54.5 109 70-130 1,4-Dichlorobenzene ug/L 50 54.3 109 70-130 2-Butanone (MEK) ug/L 100 123 123 70-133 2-Hexanone ug/L 100 115 115 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 116 116 70-130 Acetone ug/L 100 108 108 70-144 Acrylonitrile ug/L 250 278 111 70-130 Benzene ug/L 50 52.8 106 70-130 Bromochloromethane ug/L 50 51.8 104 70-130 Bromodichloromethane ug/L 50 54.2 108 70-130 Bromoform ug/L 50 56.1 112 70-131 Bromomethane ug/L 50 73.4 147 30-1771H Carbon disulfide ug/L 50 55.2 110 70-133 Carbon tetrachloride ug/L 50 54.4 109 70-130 Chlorobenzene ug/L 50 53.8 108 70-130 Chloroethane ug/L 50 48.9 98 46-131 Chloroform ug/L 50 54.7 109 70-130 Chloromethane ug/L 50 51.2 102 49-130 v2 cis-1,2-Dichloroethene ug/L 50 52.9 106 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 LABORATORY CONTROL SAMPLE: Parameter 3446850 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 57.7 115 70-130 Dibromochloromethane ug/L 50 55.4 111 70-130 Dibromomethane ug/L 50 50.2 100 70-130 Ethylbenzene ug/L 50 55.1 110 70-130 lodomethane ug/L 100 111 111 47-140 Methylene Chloride ug/L 50 50.8 102 68-130 Styrene ug/L 50 56.2 112 70-130 Tetrachloroethene ug/L 50 52.7 105 70-130 Toluene ug/L 50 52.9 106 70-130 trans-1,2-Dichloroethene ug/L 50 53.6 107 70-130 trans- 1,3-Dichloropropene ug/L 50 56.7 113 70-130 trans-1,4-Dichloro-2-butene ug/L 50 59.2 118 25-200 Trichloroethene ug/L 50 53.6 107 70-130 Trichlorofluoromethane ug/L 50 50.8 102 61-130 Vinyl acetate ug/L 100 133 133 70-140 Vinyl chloride ug/L 50 54.1 108 59-142 Xylene (Total) ug/L 150 166 111 70-130 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3446851 MS 92570420003 Spike Parameter Units Result Conc. MSD Spike Conc. 3446852 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.0 22.4 115 112 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 23.5 23.1 118 116 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.5 21.5 113 108 70-131 5 30 1,1,2-Trichloroethane ug/L ND 20 20 22.5 22.4 112 112 70-136 1 30 1,1-Dichloroethane ug/L ND 20 20 22.8 22.5 114 112 70-147 1 30 1,1-Dichloroethene ug/L ND 20 20 23.0 22.4 115 112 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 21.5 20.9 107 104 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 21.9 21.7 110 108 69-136 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.6 21.7 113 109 70-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 22.4 22.1 112 111 70-133 1 30 1,2-Dichloroethane ug/L ND 20 20 21.9 21.3 109 107 67-138 2 30 1,2-Dichloropropane ug/L ND 20 20 22.7 22.8 114 114 70-138 0 30 1,4-Dichlorobenzene ug/L ND 20 20 22.5 22.2 112 111 70-133 1 30 2-Butanone (MEK) ug/L ND 40 40 46.2 44.1 115 110 61-147 4 30 2-Hexanone ug/L ND 40 40 42.2 40.4 105 101 67-139 4 30 4-Methyl-2-pentanone ug/L ND 40 40 42.1 41.1 105 103 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 43.2 42.1 108 105 55-159 3 30 Acrylonitrile ug/L ND 100 100 111 110 111 110 68-140 1 30 Benzene ug/L ND 20 20 22.5 22.1 112 111 67-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3446851 MS 92570420003 Spike Parameter Units Result Conc. MSD Spike Conc. 3446852 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 23.4 22.6 117 113 70-146 4 30 Bromodichloromethane ug/L ND 20 20 22.4 21.8 112 109 70-138 3 30 Bromoform ug/L ND 20 20 21.5 20.8 107 104 57-138 3 30 Bromomethane ug/L ND 20 20 22.5 22.9 113 115 10-200 2 30 Carbon disulfide ug/L ND 20 20 23.6 23.2 118 116 70-152 2 30 Carbon tetrachloride ug/L ND 20 20 22.9 23.1 115 115 70-147 1 30 Chlorobenzene ug/L ND 20 20 22.8 22.3 114 112 70-137 2 30 Chloroethane ug/L ND 20 20 25.0 25.3 125 126 51-166 1 30 Chloroform ug/L ND 20 20 24.2 23.4 121 117 70-144 3 30 Chloromethane ug/L ND 20 20 22.5 22.4 112 112 24-161 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 23.1 22.7 116 113 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.0 21.7 110 108 70-142 1 30 Dibromochloromethane ug/L ND 20 20 22.4 21.8 112 109 68-138 3 30 Dibromomethane ug/L ND 20 20 23.2 22.8 116 114 70-134 2 30 Ethylbenzene ug/L ND 20 20 22.6 22.1 113 110 68-143 3 30 lodomethane ug/L ND 40 40 43.6 45.5 109 114 20-161 4 30 Methylene Chloride ug/L ND 20 20 22.0 21.5 110 107 64-148 2 30 Styrene ug/L ND 20 20 15.4 15.6 77 78 70-136 1 30 Tetrachloroethene ug/L ND 20 20 22.5 22.1 112 111 70-139 2 30 Toluene ug/L ND 20 20 22.6 22.2 113 111 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.3 22.6 116 113 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.7 20.9 109 105 70-138 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 19.0 20.5 95 103 31-145 8 30 Trichloroethene ug/L ND 20 20 23.1 22.7 115 113 70-149 2 30 Trichlorofluoromethane ug/L ND 20 20 22.0 21.8 110 109 61-154 1 30 Vinyl acetate ug/L ND 40 40 37.9 37.6 95 94 48-156 1 30 Vinyl chloride ug/L ND 20 20 25.3 25.0 126 125 55-172 1 30 Xylene (Total) ug/L ND 60 60 67.5 66.4 112 111 66-145 2 30 1,2-Dichloroethane-d4 (S) % 93 96 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 99 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 657832 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92570457002, 92570457004, 92570457005, 92570457006, 92570457008, 92570457011 METHOD BLANK: 3448091 Matrix: Water Associated Lab Samples: 92570457002, 92570457004, 92570457005, 92570457006, 92570457008, 92570457011 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 11/08/21 13:18 1,1,1-Trichloroethane ug/L ND 1.0 0.33 11/08/21 13:18 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/08/21 13:18 1,1,2-Trichloroethane ug/L ND 1.0 0.32 11/08/21 13:18 1,1-Dichloroethane ug/L ND 1.0 0.37 11/08/21 13:18 1,1-Dichloroethene ug/L ND 1.0 0.35 11/08/21 13:18 1,2,3-Trichloropropane ug/L ND 1.0 0.26 11/08/21 13:18 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 11/08/21 13:18 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/08/21 13:18 1,2-Dichlorobenzene ug/L ND 1.0 0.34 11/08/21 13:18 1,2-Dichloroethane ug/L ND 1.0 0.32 11/08/21 13:18 1,2-Dichloropropane ug/L ND 1.0 0.36 11/08/21 13:18 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/08/21 13:18 2-Butanone (MEK) ug/L ND 5.0 4.0 11/08/21 13:18 2-Hexanone ug/L ND 5.0 0.48 11/08/21 13:18 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 11/08/21 13:18 Acetone ug/L ND 25.0 5.1 11/08/21 13:18 Acrylonitrile ug/L ND 10.0 1.8 11/08/21 13:18 Benzene ug/L ND 1.0 0.34 11/08/21 13:18 Bromochloromethane ug/L ND 1.0 0.47 11/08/21 13:18 Bromodichloromethane ug/L ND 1.0 0.31 11/08/21 13:18 Bromoform ug/L ND 1.0 0.34 11/08/21 13:18 Bromomethane ug/L ND 2.0 1.7 11/08/21 13:18 Carbon disulfide ug/L ND 2.0 0.73 11/08/21 13:18 Carbon tetrachloride ug/L ND 1.0 0.33 11/08/21 13:18 Chlorobenzene ug/L ND 1.0 0.28 11/08/21 13:18 Chloroethane ug/L ND 1.0 0.65 11/08/21 13:18 Chloroform ug/L ND 1.0 0.43 11/08/21 13:18 Chloromethane ug/L ND 1.0 0.54 11/08/21 13:18 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 11/08/21 13:18 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 11/08/21 13:18 Dibromochloromethane ug/L ND 1.0 0.36 11/08/21 13:18 Dibromomethane ug/L ND 1.0 0.39 11/08/21 13:18 Ethylbenzene ug/L ND 1.0 0.30 11/08/21 13:18 lodomethane ug/L ND 20.0 9.7 11/08/21 13:18 Methylene Chloride ug/L ND 5.0 2.0 11/08/21 13:18 Styrene ug/L ND 1.0 0.29 11/08/21 13:18 Tetrachloroethene ug/L ND 1.0 0.29 11/08/21 13:18 Toluene ug/L ND 1.0 0.48 11/08/21 13:18 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 11/08/21 13:18 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 METHOD BLANK: 3448091 Matrix: Water Associated Lab Samples: 92570457002, 92570457004, 92570457005, 92570457006, 92570457008, 92570457011 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 11/08/21 13:18 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 11/08/21 13:18 Trichloroethene ug/L ND 1.0 0.38 11/08/21 13:18 Trichlorofluoromethane ug/L ND 1.0 0.30 11/08/21 13:18 Vinyl acetate ug/L ND 2.0 1.3 11/08/21 13:18 Vinyl chloride ug/L ND 1.0 0.39 11/08/21 13:18 Xylene (Total) ug/L ND 1.0 0.34 11/08/21 13:18 1,2-Dichloroethane-d4 (S) % 103 70-130 11/08/21 13:18 4-Bromofluorobenzene (S) % 98 70-130 11/08/21 13:18 Toluene-d8 (S) % 100 70-130 11/08/21 13:18 LABORATORY CONTROL SAMPLE: Parameter 3448092 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.0 106 70-130 1,1,1-Trichloroethane ug/L 50 53.8 108 70-130 1,1,2,2-Tetrachloroethane ug/L 50 53.6 107 70-130 1,1,2-Trichloroethane ug/L 50 53.5 107 70-130 1,1-Dichloroethane ug/L 50 54.4 109 70-130 1,1-Dichloroethene ug/L 50 51.6 103 70-132 1,2,3-Trichloropropane ug/L 50 47.6 95 70-130 1,2-Dibromo-3-chloropropane ug/L 50 58.1 116 70-132 1,2-Dibromoethane (EDB) ug/L 50 53.7 107 70-130 1,2-Dichlorobenzene ug/L 50 53.9 108 70-130 1,2-Dichloroethane ug/L 50 50.4 101 70-130 1,2-Dichloropropane ug/L 50 54.6 109 70-130 1,4-Dichlorobenzene ug/L 50 54.4 109 70-130 2-Butanone (MEK) ug/L 100 109 109 70-133 2-Hexanone ug/L 100 103 103 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 102 102 70-130 Acetone ug/L 100 110 110 70-144 Acrylonitrile ug/L 250 274 110 70-130 Benzene ug/L 50 52.7 105 70-130 Bromochloromethane ug/L 50 56.3 113 70-130 Bromodichloromethane ug/L 50 53.3 107 70-130 Bromoform ug/L 50 56.2 112 70-131 Bromomethane ug/L 50 44.7 89 30-177 Carbon disulfide ug/L 50 58.7 117 70-133 Carbon tetrachloride ug/L 50 52.8 106 70-130 Chlorobenzene ug/L 50 53.3 107 70-130 Chloroethane ug/L 50 41.6 83 46-131 Chloroform ug/L 50 54.8 110 70-130 Chloromethane ug/L 50 55.8 112 49-130 cis-1,2-Dichloroethene ug/L 50 54.5 109 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 LABORATORY CONTROL SAMPLE: Parameter 3448092 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 54.1 108 70-130 Dibromochloromethane ug/L 50 55.4 111 70-130 Dibromomethane ug/L 50 54.0 108 70-130 Ethylbenzene ug/L 50 52.5 105 70-130 lodomethane ug/L 100 75.5 75 47-140 Methylene Chloride ug/L 50 52.5 105 68-130 Styrene ug/L 50 54.8 110 70-130 Tetrachloroethene ug/L 50 53.3 107 70-130 Toluene ug/L 50 52.8 106 70-130 trans-1,2-Dichloroethene ug/L 50 55.8 112 70-130 trans- 1,3-Dichloropropene ug/L 50 53.1 106 70-130 trans-1,4-Dichloro-2-butene ug/L 50 55.0 110 25-200 Trichloroethene ug/L 50 53.2 106 70-130 Trichlorofluoromethane ug/L 50 46.5 93 61-130 Vinyl acetate ug/L 100 111 111 70-140 Vinyl chloride ug/L 50 61.0 122 59-142 Xylene (Total) ug/L 150 160 107 70-130 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 99 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3448093 MS 92570457005 Spike Parameter Units Result Conc. MSD Spike Conc. 3448094 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.6 21.5 108 107 70-135 1 30 1,1,1-Trichloroethane ug/L ND 20 20 22.6 22.5 113 113 70-148 0 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.4 21.3 107 106 70-131 0 30 1,1,2-Trichloroethane ug/L ND 20 20 21.6 21.4 108 107 70-136 1 30 1,1-Dichloroethane ug/L ND 20 20 21.6 21.7 108 108 70-147 1 30 1,1-Dichloroethene ug/L ND 20 20 22.3 22.0 112 110 70-158 1 30 1,2,3-Trichloropropane ug/L ND 20 20 20.7 20.9 103 104 67-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 21.5 22.2 107 111 69-136 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.3 21.4 106 107 70-137 0 30 1,2-Dichlorobenzene ug/L ND 20 20 21.7 21.7 109 108 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 20.7 20.6 104 103 67-138 1 30 1,2-Dichloropropane ug/L ND 20 20 22.1 21.8 111 109 70-138 1 30 1,4-Dichlorobenzene ug/L ND 20 20 21.8 21.8 109 109 70-133 0 30 2-Butanone (MEK) ug/L ND 40 40 43.6 43.6 109 109 61-147 0 30 2-Hexanone ug/L ND 40 40 40.5 41.1 101 103 67-139 2 30 4-Methyl-2-pentanone ug/L ND 40 40 40.8 40.9 102 102 67-136 0 30 (MIBK) Acetone ug/L ND 40 40 41.5 41.7 104 104 55-159 0 30 Acrylonitrile ug/L ND 100 100 107 108 107 108 68-140 1 30 Benzene ug/L ND 20 20 21.8 21.6 109 108 67-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3448093 MS 92570457005 Spike Parameter Units Result Conc. MSD Spike Conc. 3448094 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 22.5 22.2 112 111 70-146 1 30 Bromodichloromethane ug/L ND 20 20 21.7 21.2 108 106 70-138 2 30 Bromoform ug/L ND 20 20 20.4 20.6 102 103 57-138 1 30 Bromomethane ug/L ND 20 20 23.2 22.6 116 113 10-200 3 30 Carbon disulfide ug/L ND 20 20 22.2 22.5 111 113 70-152 1 30 Carbon tetrachloride ug/L ND 20 20 23.0 22.4 115 112 70-147 3 30 Chlorobenzene ug/L ND 20 20 22.1 22.2 110 111 70-137 1 30 Chloroethane ug/L ND 20 20 25.5 25.3 128 126 51-166 1 30 Chloroform ug/L ND 20 20 23.2 23.2 116 116 70-144 0 30 Chloromethane ug/L ND 20 20 21.8 21.7 109 108 24-161 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 22.1 22.0 110 110 67-148 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.1 20.8 105 104 70-142 1 30 Dibromochloromethane ug/L ND 20 20 21.1 21.4 105 107 68-138 2 30 Dibromomethane ug/L ND 20 20 22.0 21.9 110 109 70-134 1 30 Ethylbenzene ug/L ND 20 20 21.6 21.8 108 109 68-143 1 30 lodomethane ug/L ND 40 40 41.0 41.9 102 105 20-161 2 30 Methylene Chloride ug/L ND 20 20 20.9 20.8 104 104 64-148 0 30 Styrene ug/L ND 20 20 21.9 22.0 109 110 70-136 0 30 Tetrachloroethene ug/L ND 20 20 21.6 21.6 108 108 70-139 0 30 Toluene ug/L ND 20 20 21.9 21.6 110 108 47-157 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.8 22.2 109 111 70-149 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.5 20.5 103 102 70-138 0 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 18.1 18.6 90 93 31-145 3 30 Trichloroethene ug/L ND 20 20 22.3 21.9 111 109 70-149 2 30 Trichlorofluoromethane ug/L ND 20 20 21.9 21.6 110 108 61-154 2 30 Vinyl acetate ug/L ND 40 40 42.1 42.3 105 106 48-156 1 30 Vinyl chloride ug/L ND 20 20 24.1 24.2 120 121 55-172 1 30 Xylene (Total) ug/L ND 60 60 65.7 66.1 110 110 66-145 1 30 1,2-Dichloroethane-d4 (S) % 92 93 70-130 4-Bromofluorobenzene (S) % 99 100 70-130 Toluene-d8 (S) % 100 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 657653 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92570457001, 92570457002, 92570457004, 92570457005, 92570457006, 92570457007, 92570457008, 92570457009,92570457010,92570457011,92570457012 METHOD BLANK: 3447403 Matrix: Water Associated Lab Samples: 92570457001, 92570457002, 92570457004, 92570457005, 92570457006, 92570457007, 92570457008, 92570457009,92570457010,92570457011,92570457012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/04/21 12:39 1,2-Dichloroethane-d4 (S) % 92 70-130 11/04/21 12:39 Toluene-d8 (S) % 92 66-133 11/04/21 12:39 LABORATORY CONTROL SAMPLE: 3447404 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 19.6 98 70-130 1,2-Dichloroethane-d4 (S) % 87 70-130 Toluene-d8 (S) % 90 66-133 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3447405 3447406 Parameter 1,4-Dioxane (p-Dioxane) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) MS 92570457004 Spike Units Result Conc. ug/L ND 20 MSD Spike MS MSD Conc. Result Result 20 21.5 22.1 MS MSD % Rec Max % Rec % Rec Limits RPD RPD Qual 104 107 64-141 3 30 82 87 70-130 30 86 88 66-133 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 QC Batch: 657670 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92570457003 METHOD BLANK: 3447511 Matrix: Water Associated Lab Samples: 92570457003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/04/21 13:54 1,2-Dichloroethane-d4 (S) % 99 70-130 11/04/21 13:54 Toluene-d8 (S) % 102 66-133 11/04/21 13:54 LABORATORY CONTROL SAMPLE: 3447512 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.5 98 70-130 1,2-Dichloroethane-d4 (S) % 91 70-130 Toluene-d8 (S) % 96 66-133 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3447513 3447514 MS MSD 92569911007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 20.0 19.6 100 98 64-141 2 30 1,2-Dichloroethane-d4 (S) % 92 97 70-130 30 Toluene-d8 (S) % 95 96 66-133 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: BURKE CO. - KIRKSEY 92570457 DRIVE Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92570457001 1201-MW2 EPA 3010A 659040 EPA6010D 659156 92570457002 1201-MW3S EPA 3010A 657606 EPA6010D 657691 92570457003 1201-MW3D EPA 3010A 657606 EPA6010D 657691 92570457004 1201-MW4 EPA 3010A 659040 EPA6010D 659156 92570457005 1201-MW5 EPA 3010A 659040 EPA6010D 659156 92570457006 1201-MW6S EPA 3010A 657606 EPA6010D 657691 92570457007 1201-MW6D EPA 3010A 657606 EPA6010D 657691 92570457008 1201-SW1 EPA 3010A 659040 EPA6010D 659156 92570457009 1201-SW2 EPA 3010A 659040 EPA6010D 659156 92570457010 1201-SW3 EPA 3010A 659040 EPA6010D 659156 92570457011 1201-FILED BLANK EPA 3010A 659040 EPA6010D 659156 92570457001 1201-MW2 EPA 3010A 658131 EPA 6020B 658209 92570457002 1201-MW3S EPA 3010A 658131 EPA 6020B 658209 92570457003 1201-MW3D EPA 3010A 658131 EPA 6020B 658209 92570457004 1201-MW4 EPA 3010A 658131 EPA 6020B 658209 92570457005 1201-MW5 EPA 3010A 658131 EPA 6020B 658209 92570457006 1201-MW6S EPA 3010A 658131 EPA 6020B 658209 92570457007 1201-MW6D EPA 3010A 658131 EPA 6020B 658209 92570457008 1201-SW1 EPA 3010A 658131 EPA 6020B 658209 92570457009 1201-SW2 EPA 3010A 658131 EPA 6020B 658209 92570457010 1201-SW3 EPA 3010A 658131 EPA 6020B 658209 92570457011 1201-FILED BLANK EPA 3010A 658131 EPA 6020B 658209 92570457001 1201-MW2 EPA 8260D 657547 92570457002 1201-MW3S EPA 8260D 657832 92570457003 1201-MW3D EPA 8260D 657547 92570457004 1201-MW4 EPA 8260D 657832 92570457005 1201-MW5 EPA 8260D 657832 92570457006 1201-MW6S EPA 8260D 657832 92570457007 1201-MW6D EPA 8260D 657547 92570457008 1201-SW1 EPA 8260D 657832 92570457009 1201-SW2 EPA 8260D 657547 92570457010 1201-SW3 EPA 8260D 657547 92570457011 1201-FILED BLANK EPA 8260D 657832 92570457012 1201-TRIP BLANK EPA 8260D 657547 92570457001 1201-MW2 EPA 8260D Mod. 657653 92570457002 1201-MW3S EPA 8260D Mod. 657653 92570457003 1201-MW3D EPA 8260D Mod. 657670 92570457004 1201-MW4 EPA 8260D Mod. 657653 92570457005 1201-MW5 EPA 8260D Mod. 657653 92570457006 1201-MW6S EPA 8260D Mod. 657653 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 52 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: BURKE CO. - KIRKSEY DRIVE Pace Project No.: 92570457 Lab ID Sample ID QC Batch Method QC Batch 92570457007 1201-MW6D EPA8260D Mod. 657653 92570457008 1201-SW1 EPA8260D Mod. 657653 92570457009 1201-SW2 EPA8260D Mod. 657653 92570457010 1201-SW3 EPA8260D Mod. 657653 92570457011 1201-FILED BLANK EPA8260D Mod. 657653 92570457012 1201-TRIP BLANK EPA 8260D Mod. 657653 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /17/2021 12:32 PM without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 49 of 52 Document Name: Document Revised: October 28, 2020 __ . ae6Analyfrcat Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033•Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersviile 0' Raleigh[] Mechanicsville❑ Atlanta[:) Kernersville❑ ConditionSample Client Name: // [ `-In#t .. 3 (dam J 5(/ a% Project 9: W V# : 9257045 Courier: ❑Fed fx ❑UPS ❑LISPS []Client ❑ Commercial []Pace ❑Other: I 11 111I 1111 92670457 Custody Seal Present? ❑Yes ❑] o seals Intact? ❑Yes ❑%0 1 Date/Initials Person Examining Contents:, 1 l ! �13-2—] Packing )Material: ❑Bubble Wrap dBubble Bags [-]None❑ Other Biological Tissue Frozen? f Thermometer: []Yes❑No ❑�A •r ;, �,- ❑Wet ❑Blue ❑None ype of ice: 7 Correction Factor: Cooler Temp: Add/Subtract ('Cl ,` Temp should be above freezing to VC ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected (•C): . �_ ) has begun USDA Regulated Sall (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally, Yes No Including Hawaii and Puerto Ricoh L.JYes L-,JNo Comments/Discrepancy: Chain of Custody Present? LJYes ONo N/A 1. Samples Arrived within Hold Time? [I -Yes ONO ❑NIA 2. Short Hold Time Analysis 1<72 hr.)? ❑Yes ❑tllo ❑NIA 3. Rush Turn Around Time Requested? Oyes [3 [_]N/A 4. Sufficient Volume? E3G QNo ❑N/A S. Correct Containers Used? -Pace Containers Used? 09es OY�es ❑N❑ ❑No ❑N/A ❑N/A 6. Containers Intact? Ids ONO ❑N/A 7• Dissolved analysis: Samples Field Filtered? ❑Yes []rfo ❑N/A g. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: QYes LV ❑No ❑N/A 9. Headspace in VOA vials (>5-6mml? 0yes No NIA 10, Trip Blank Present? Trip Blank Custody Seals Present? []Yes Ofes ONO [:]No ❑N/A ❑NIA 11, COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person Project Manager SCURF Review: te/Time: Lot ID of split containers: Date: Project Manager SRF Review: Date: Field Data Requlred? ❑Yes ❑No Document Name: Occurrent Revised: October 28, 2020 Sample Condition Upon Receipt(SCUR) Page 2 of 2 c?CBAnaVical Document No.; Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office *Check mark top half of box if pH and/or aecnlorinanon Is verified and within the acceptance range for preservation samples. Uceptions: VOA, Coliform, TOC, Oil and Grease, ORO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Project # 0# : 9Z57o45 r PM. RMB Due Date: 11/17/21 CLIENT: 92—Joyce Eng Z v a u Z ro m u Z v m u ¢ p U ry v ry T Z u O M a U M _ O m< [i m c7 a _ d a y y = 2 y n j V ry a = V O r� <^ Z R v n E a ? u m 2 LA ro 4 ? c 2 m A Z N m ,Cn Z Y j _ e_Aa u ro a z R w m ry z u a a d n v Z > o ? ra ro m c 0 'a m a m a E E a E a Ln a o a a 6 N E A a t a a E > > > > `m E Y' „, ,a E o E E a E E E E v v w E E E E E y 3 E o E E opE r {m� O N G a ti N N N N N " ry N .ti .H N C Y q q q y m .ti ,�11 N N y� N .� _ M ut VM a S h 3 a Y X N a O E a N am+ r...-r. VO LF .-I r-1 m .� m of 01 4i CI T Q l7 �/1 Ln N ^� a�i en rxn a a a t7 +7 C7 l7 l7 l7 l7 0 a a a U v� U u a a m a m a m a m a co m 0 3 a a a a a a o > n o > n yr ;A m a a o m 1 I �NN IT ✓ 3 4- 4-, ' 5 7 M Ek 0 Ek MEMEMEMMEMEM Boom on 0 nommonooklilLool MISSION MEN 00101 on M M M NONE ON Time preservailDn Amount of Preservative adjusted added Note: —Wheneverthere is-a-discrepancy-affecting-Narth-C-aroiina-compliance-samplesr-a-copy-of-this-Form-will-be-sent-tolhe-North Carolina-DEH Out of hold, Incorrect preservative, out o€temp, incorrect containers. ,�ace.4nalyrncar �� Section A Required Client Information: Company: LaBella Associates To: Fax SAMPLE ID One Character per box. IA Z, 0-91, -j Sample Ids must be unique W F 2 12o1-Mw2 3 1201-MW3S 4 1201-Mw3D 5 1201-MW4 6 1201-MW5 7 1201-Mw6S 8 1201-MWGD 9 1201-SW1 12 13 CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT, All relevant fields must be completed accurately. Section B Section C Required Project Information: Invoice Information: Page: 1 Of 1 Report To: Van Burbach Attention: Lecia Jones Copy To: Miguel Vazquez Company Name: LaBella Associates Address: 1604 Ownby Lane, Richmond,'JA 23220 Regulatory Agency Purchase Order No. 2212740.00.02 Pace Quote Reference: Client Project ID: Burke Co. - Klrksey Drive Pace Project Manager: Angela Baionl State 1 Location Container Order Number: Pace Profile #: North Carolina Re uested Analysis Filtered Y1 m d z MATRIX CODE COLLECTED z Preservatives Drinking Wetar DW water VJT u r westswater ww -a Product P } C7 Z } o NSond sOt �:y START END Wipe WP Air AR o Other OT OU m y, ro v c U Tlswe r5 x T11TETI1E ro O c a n o L a a a w DATE TIME rn *_? S z z o Z z ? ?S� {�c { S7 ADDITIONAL COMMENTS RELINQUISHED BY! AFFILIATION DATE TIME ACCEPTED BY ! AFFILIATION DATE TIME SAMPLE CONDITIONS "V31 4,h)) 3/:,Il /-N<_2 I IPLER NAME AND SIGNATURE PRINT Name of SAMPLER - I lull SIGNATURE of SAMPLER:.V i DATE Signed: O m Z C U _ rn s } } ❑ `m n m Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Location Background Downgradient MW-1 MW-2 MW-3S MW-3D MWA MW-5 MW-6S MW-61D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 2 7-May-08 1085.56 1049.5 7 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 4-Nov-19 1089.96 1051.23 1016.22 1022.76 1036.09 1101.77 1054.90 1053.09 6-May-20 - 1051.23 1017.08 1022.76 1036.09 1101.77 1055.25 1053.38 9-Nov-20 1051.08 1016.18 1022.76 1036.31 1102.20 1055.16 1053.30 4-May-21 1051.62 1016.35 1022.76 1037.38 1105.08 1055.35 1053.67 2-Nov-21 1051.02 1015.61 1022.76 1032.37 1101.29 1054.75 1053.00 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level All depths measured in feet below TOC. MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 damaged approx. June 2017 Burke County, Kirksey Drive Landfill Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-313 MW-4 MW-5 MW-6S If MW-6D Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 Ng/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 ug/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA6010 3.9 6.0 NS ND ND ND ND ND ND ND ND IMAC = 1 pg/L 4-Dec-18 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND 9-Nov-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 3.0 5.0 NS 3 J ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC21- = 50 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NCH = 10 ug/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA6010 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC21- = 2,000 Ng/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC21- = 700 Ng/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 NS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1,050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1,210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1,060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1,040 388 167 82.0 J 28.0 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 NS 1,470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 NS 1,240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 NS 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 NS 1,160 507 205 82.0 27.1 42.6 12.8 ND 6-May-19 EPA 6010D 2.5 5 NS 1,040 454 181 82.6 37.5 43.7 12.2 ND 5-Nov-19 EPA 6010D 2.5 5 NS 1,370 448 219 130 46.5 35.6 17.0 -- 6-May-20 EPA 6010D 3.5 5 NS 1,160 486 194 71.2 55.4 27.2 12.8 -- 9-Nov-20 EPA 6010D 3.5 5 NS 1,390 489 200 75.3 36.6 30.0 13.9 ND 4-May-21 EPA 6010D 3.5 5 NS 1,190 478 201 91.2 121 26.5 13.4 ND 2-Nov-21 EPA 6010D 3.5 5 NS 1,550 467 202 110 46.5 26.2 13.5 ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S If MW-6D Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.10 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA BOO 0.5 1.0 NS ND ND ND ND ND ND ND ND IMAC = 4 pWL (10/23/07) 4-Dec-18 EPA 6O1OD 0.5 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O1OD 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 0.2 1.0 NS ND ND ND ND 0.23 J ND ND -- 6-May-20 EPA 6O1OD 0.7 1.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6O1OD 0.7 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 0.7 1.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6O1OD 0.7 1.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL I MW-1 MW-2 MW-3S MW-3D MWM MW-5 9 MW-6S If MW-6D Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 1.75 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NCH = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA6010 0.5 1.0 NS 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 NS 2.0 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 6010D 0.4 1.0 NS ND 0.51 J ND ND ND ND ND -- 9-Nov-20 EPA 6010D 0.4 1.0 NS ND ND 0.62 J 0.58 J ND ND ND ND 4-May-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND 0.65 J ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL I MW-1 MW-2 MW-3S MW-31D MW-4 MW- MW-6S MW-6D Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NCH = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 2.5 10.0 NS 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 NS ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 NS 2.5 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 1.0 5.0 NS ND ND ND 5.9 1.8 J ND ND -- 6-May-20 EPA 6O1OD 3.7 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6O1OD 3.7 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 3.7 5.0 NS ND ND ND ND 8 ND ND ND 2-Nov-21 EPA 6O1OD 3.7 5.0 NS ND ND ND 4.3 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 Ng/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 Ng/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA6010 2.5 10.0 NS 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA6010 2.5 10.0 NS 114 11.0 ND ND ND ND ND ND 14-May-18 EPA6010 2.5 10.0 NS 102 20.2 ND ND ND 4.2 J ND ND IMAC = 1 ug/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 107 14.4 ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.1 5.0 NS 119 12.3 ND 1.6 J 1.3 J ND ND -- 6-May-20 EPA 6010D 3.6 5.0 NS 106 16.8 ND ND ND ND ND -- 9-Nov-20 EPA 6010D 3.6 5.0 NS 122 14.2 ND ND ND ND ND ND 4-May-21 EPA 6010D 3.6 5.0 NS 95.4 13.7 ND ND 8.7 ND ND ND 2-Nov-21 EPA 6010D 3.6 5.0 NS 116 12.4 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL JL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-6D Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC21- = 1,000 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND NS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 2.5 10.0 NS 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA BOO 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 8.3 5.8 3.2 J ND 3.1 J ND ND ND 5-Nov-19 EPA 6010D 2.1 5.0 NS 3.3 J ND ND 4.6 J ND ND ND -- 6-May-20 EPA 6010D 4.3 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6010D 4.3 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.3 5.0 NS ND ND ND ND 6.2 ND ND ND 2-Nov-21 EPA 6010D 4.3 5.0 NS ND ND ND 4.5 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC21- = 15 pg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 4.9 J 3.2 J ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.6 5.0 NS 5.2 2.0 J ND ND ND ND ND -- 6-May-20 EPA 6010D 4.5 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6010D 4.5 5.0 NS 9.3 ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.5 5.0 NS ND ND ND ND 10.4 ND ND ND 2-Nov-21 EPA 6010D 4.5 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method Dill RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC21- = 100 Ng/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND NS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA6010 2.5 50.0 NS 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA6010 2.5 50.0 NS 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA6010 2.5 50.0 NS 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 14.5 4.4 J 25.7 3.0 J ND ND ND ND 5-Nov-19 EPA 6010D 0.9 5.0 NS 16.8 3.3 J 28.7 2.4 J 1.0 J ND ND -- 6-May-20 EPA 6010D 3.5 5.0 NS 14.4 5.4 24.1 ND ND ND ND -- 9-Nov-20 EPA 6010D 3.5 5.0 NS 21.7 4.9 J 27.1 ND ND ND ND ND 4-May-21 EPA 6010D 3.5 5.0 NS 14.4 ND 26.9 ND 5.6 ND ND ND 2-Nov-21 EPA 6010D 3.5 5.0 NS 20.5 5.3 28.9 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC21- = 50 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC21- = 20 ug/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 6010D 4.7 10.0 NS 9.2 J ND ND ND 7.2 J ND ND -- 9-Nov-20 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC21- = 17.5 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NCH = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 2.5 5.0 NS 5.6 2.6 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 Ng/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 ug/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND {4.8) J ND ND 4.0 {ND) J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 6020B 0.0 5.5 NS ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 6020B 0.03 0.1 NS ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 NS ND ND ND ND ND ND ND ND IMAC = 0.2 ug/L (10/1/10) 4-Dec-18 EPA 6020B 0.06 0.1 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6020B 0.06 0.1 NS ND ND ND ND 0.087 J ND ND ND 5-Nov-19 EPA 6020B 0.06 0.1 NS ND ND 0.061 J 0.060 J 0.16 ND ND -- 6-May-20 EPA 6020B 0.12 0.2 NS ND ND ND ND 0.20 ND ND -- Resample -> 16-Jul-20 EPA 6020B 0.12 0.2 NS NS NS NS NS ND NS NS -- 9-Nov-20 EPA 6020B 0.05 0.1 NS ND ND ND ND 0.11 ND ND ND 4-May-21 EPA 6020B 0.05 1 NS ND ND ND 0.058 J 0.67 J ND ND ND 2-Nov-21 EPA 6020B 0.05 0.47 NS ND ND ND ND 0.15 J ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND NS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13.0 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 NS 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 NS 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 NS 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND IMAC = 0.3 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS ND 3.0 J ND 6.0 ND ND ND ND Resample --> 8-Feb-19 EPA 6010D 2.5 5.0 NS - - - ND -- -- -- 6-May-19 EPA 6010D 2.5 5.0 NS 4.1 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 NS 5.3 1.8 J ND 10.0 3.8 J ND ND -- Resample --> 23-Jan-20 EPA 6010D 1.3 5.0 NS 5.1 - - 2.3 J -- -- -- 6-May-20 EPA 6010D 3.9 5.0 NS ND ND ND ND 7.2 ND ND -- Resample--> 16-Jul-20 EPA 6010D 3.9 5.0 NS NS NS NS NS ND NS NS -- 9-Nov-20 EPA 6010D 3.9 5.0 NS - 9.5 ND ND ND ND ND ND Resample--> 27-Jan-21 EPA 6010D 3.9 5.0 NS - ND - - -- -- -- 4-May-21 EPA 6010D 3.9 5.0 NS 7.3 ND ND 7.9 19.4 ND ND ND 2-Nov-21 EPA 6010D 3.9 5.0 NS 59.9 23.3 ND 9.9 5.1 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NC21- = 1,050 pg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC21- = 1,000 pg/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 NS ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 NS ND 5.9 J ND ND 7.5 J ND 7.6 J ND 5-Nov-19 EPA 6O1OD 3.9 10.0 NS ND ND ND 15.4 7.5 J ND 7.0 J -- 6-May-20 EPA 6O1OD 9.5 10.0 NS ND ND ND ND 12.6 ND ND -- 9-Nov-20 EPA 6O1OD 9.5 10.0 NS ND 14.7 ND ND ND ND ND ND 4-May-21 EPA 6O1OD 9.5 10.0 NS ND ND ND 10.6 34.6 ND ND ND 2-Nov-21 EPA 6O1OD 9.5 10.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-6D Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC21- = 700 pg/L (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC21- = 6,000 pg/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 NS ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA8260 10.0 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 10.0 100 NS 484 ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 10.0 25 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 8.2 25 NS 299 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 NS 105 ND ND ND ND ND ND -- 6-May-20 EPA 8260D 6.2 25 NS 255 ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 6.2 25 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 25.6 125 NS 1160 m ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 5.1 25 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61D Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC21- = 1 pg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 NS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 NS 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 NS 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 NS 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260E 0.25 1.0 NS 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 NS 10.4 4.6 1.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 NS 8.3 3.4 1.3 ND ND ND ND 6-May-20 EPA 8260D 0.15 1.0 NS 9.6 3.7 1.4 ND ND ND ND 9-Nov-20 EPA 8260D 0.15 1.0 NS 10.4 3.5 1.4 ND ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 NS 9.7 3.6 1.6 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 NS 8.9 3.1 1.5 ND ND ND ND ND Burke County, Klrksey Drive Landfill Permit No. 12-01 Page 17 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC21- = 700 Ng/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 1.2 100 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 1.2 2 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.8 10 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 3.6 10 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.7 2 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA8260 0.23 3.0 NS 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA8260 0.23 3.0 NS 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA8260 0.23 3.0 NS 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA8260B 0.23 1.0 NS 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA 826OD 0.53 1.0 NS 26.6 36.4 8.7 ND ND ND ND ND 5-Nov-19 EPA 826OD 0.23 1.0 NS 22.5 32.7 7.5 ND ND 0.28 J ND -- 6-May-20 EPA 826OD 0.23 1.0 NS 26.7 32.3 8.2 ND ND ND ND -- 9-Nov-20 EPA 826OD 0.23 1.0 NS 24.7 32.7 8.0 ND ND ND ND ND 4-May-21 EPA 826OD 0.28 1.0 NS 22.1 35.9 8.7 ND ND ND ND ND 2-Nov-21 EPA 826OD 0.28 1.0 NS 24.5 32.3 8.8 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 2,800 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC21- = 3,000 Ng/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J NS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA8260 0.54 10.0 NS ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA8260 0.54 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.54 10.0 NS ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.54 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.52 1.0 NS ND 1.8 0.56 J ND ND ND ND ND 5-Nov-19 EPA 826OD 0.49 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 826OD 0.49 1.0 NS ND 1.6 ND ND ND ND ND -- 9-Nov-20 EPA 826OD 0.49 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 3.20 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 826OD 0.65 1.0 NS ND 1.7 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC21- = 70 Ng/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND INS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA8260 0.14 5.0 NS ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA8260 0.14 5.0 NS ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA8260 0.14 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.14 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 NS ND ND ND ND ND 0.67 J ND ND 5-Nov-19 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 7.80 25.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.43 1.0 NS ND ND ND ND ND 0.88 J ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL I MW-1 MW-2 MW-3S MW-31D j MW-4 MW-5 MW-6S MW-6D Blanks Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC21- = 2.6 Ng/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 Ng/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA8260 0.11 1.0 NS 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.11 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND 9-Nov-20 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.70 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.54 1.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL I MW-1 I MW-2 MW-3S MW-31D j MW-4 MW-5 MW-6S If MW-6D Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC21- = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NCH = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J NS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA8260 0.30 5.0 NS 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA8260 0.30 5.0 NS 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA8260 0.30 5.0 NS 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.30 1.0 NS 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 NS 2.4 0.88 J ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 NS 2.2 0.6 J ND ND ND ND ND -- 6-May-20 EPA 8260D 0.29 1.0 NS 2.2 0.64 J ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.29 1.0 NS 2.2 0.62 J ND ND ND ND ND ND 4-May-21 EPA 8260D 1.70 5.0 NS 1.7 J 0.66 J ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 NS 2.1 0.49 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61D Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC21- = 1.4 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 NS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 NS 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 NS 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 NS 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 8260E 0.33 1.0 NS 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 NS 47.3 14.6 4.8 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 NS 38.6 10.7 4.2 0.48 J ND ND ND 6-May-20 EPA 8260D 0.26 1.0 NS 39.0 10.7 4.1 ND ND ND ND 9-Nov-20 EPA 8260D 0.26 1.0 NS 37.7 10.9 3.9 ND ND ND ND ND 4-May-21 EPA 8260D 0.33 1.0 NS 38.4 10.4 3.9 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.33 1.0 NS 33.7 9 3.9 ND ND ND ND ND Burke County, Klrksey Drive Landfill Permit No. 12-01 Page 24 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC21- = 70 Ng/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J NS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 NS 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 NS 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 NS ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260E 0.32 1.0 NS 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA 8260D 0.41 1.0 NS 0.68 J ND 6.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.27 1.0 NS 0.57 J 0.43 J 4.7 1.5 ND ND ND 6-May-20 EPA 8260D 0.27 1.0 NS 0.61 J ND 4.8 0.48 J ND ND ND 9-Nov-20 EPA 8260D 0.27 1.0 NS ND ND 5.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.80 5.0 NS ND ND 5.8 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.37 1.0 NS 0.49 J ND 5.5 0.65 J ND ND ND ND Burke County, Klrksey Drive Landfill Permit No. 12-01 Page 25 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC21- = 0.4 Ng/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.24 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.67 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.34 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.34 1.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.34 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.32 1.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL I MW-1 I MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61D Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC21- = 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 2L = 350 Ng/L (04/01/2013) 11-Jun-13 0.56 5.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260E 0.56 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.72 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.70 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.35 1.0 NS ND ND ND ND ND ND ND ND Burke County, Klrksey Drive Landfill Permit No. 12-01 Page 27 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B Mod. 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND NC 21- = 3 pg/L 6-May-19 EPA 8260D Mod. 5.8 10 NS 218 57.0 128 2.4 ND ND ND ND 5-Nov-19 EPA 8260D Mod. 1.2 2 3.0 236 36.4 269 2.7 ND ND ND --- 6-May-20 EPA 8260D Mod. 5.8 10 NS 213 33.3 111 ND ND ND ND --- 9-Nov-20 EPA 8260D Mod. 1.2 2 NS 260 49.6 114 ND ND ND ND ND 4-May-21 EPA 8260D Mod. 0.9 2 NS 187 41.5 110 ND ND ND ND ND 2-Nov-21 EPA 8260D Mod. 0.9 2 NS 279 34.1 95.7 ND ND ND ND ND cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC21- = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J NS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA8260 0.19 5.0 NS 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA8260 0.19 5.0 NS 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA8260 0.19 5.0 NS ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA8260B 0.19 1.0 NS 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 NS ND ND 18.7 1.2 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 NS 0.33 J ND 14.6 J 8.0 ND ND ND -- 6-May-20 EPA 8260D 0.29 1.0 NS 0.41 J ND 16.4 2.6 ND ND ND -- 9-Nov-20 EPA 8260D 0.29 1.0 NS ND ND 21.2 3.5 ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 21.3 2.1 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 NS ND ND 22.9 5.6 ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC21- = 100 Ng/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J NS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.49 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.46 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.00 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.40 1.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NC21- = 0.51 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC21- = 0.6 Ng/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA8260 0.27 1.0 NS ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA8260B 0.27 1.0 NS ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 NS ND ND 0.87 J ND ND ND ND -- 6-May-20 EPA 8260D 0.19 1.0 NS ND ND 0.84 J ND ND ND ND -- 9-Nov-20 EPA 8260D 0.19 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 NS ND ND 0.63 J ND ND ND ND ND 2-Nov-21 EPA 8260D 0.36 1.0 NS ND ND 0.72 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC21- = 550 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NCH = 600 Ng/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 NS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.30 1.0 NS 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.30 1.0 NS 10.5 ND ND ND ND ND ND ND 14-May-18 EPA8260 0.30 1.0 NS 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.45 1.0 NS 24.1 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 NS 12.1 ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.26 1.0 NS 17.0 ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.26 1.0 NS 10.9 ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.30 1.0 NS 20.3 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS = 280 ug/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND IMAC = 40 Ng/L 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.46 50.0 NS 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.46 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.89 5.0 NS 8.0 ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.57 5.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 826OD 0.57 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 826OD 0.57 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 2.40 25.0 NS 6.4 J ND ND ND ND ND ND ND 2-Nov-21 EPA 826OD 0.48 5.0 - ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 I MW-6S MW-61) Blanks lodomethane 11-Jun-13 0.32 10.0 ND ND ND NS ND 7.4 J ND ND ND NC21- = NE Ng/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA826O 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA826O 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA826O 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA826O 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA826O 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA826O 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA826O 0.32 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.32 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA826OD 3.10 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA826OD 12.50 20.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 826OD 12.50 20.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 826OD 12.50 20.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 48.60 100.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 826OD 9.70 20.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI Ni 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 4.6 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC21- = 5 Ng/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.97 1.0 NS ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA8260 0.97 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.97 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.97 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.50 1.0 NS ND ND 0.63 J ND ND ND ND ND 5-Nov-19 EPA 826OD 3.70 5.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 826OD 3.70 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 826OD 3.70 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 9.80 25.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 826OD 2.00 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC21- = 4,200 Ng/L (10/23/07) 28-Nov-07 NR 100 18.0 J ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC21- = 4,000 Ng/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.96 100 NS 268 ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.96 5 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 3.20 5 NS 448 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 3.30 5 NS 14.8 ND ND ND ND ND ND -- 6-May-20 EPA 8260D 3.30 5 NS 222 ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 3.30 5 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 19.80 25 NS 1190 Ml ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 4.00 5 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND IMAC = 100 pg/L 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.33 100 NS 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.33 5 NS 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.86 5 NS 311 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 4.50 5 NS 11.2 ND ND ND ND ND ND -- 6-May-20 EPA 8260D 4.50 5 NS 187 ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 4.50 5 NS 7.0 ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.70 5 NS 616 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 2.70 5 NS 5 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI Ni ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC21- = 0.7 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND NS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA8260 0.46 1.0 NS ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA8260 0.46 1.0 NS ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA8260 0.46 1.0 NS ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA8260B 0.46 1.0 NS ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 NS ND ND 11.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 NS ND ND 6.5 1.8 ND ND ND -- 6-May-20 EPA 8260D 0.16 1.0 NS ND ND 8.1 0.69 J ND ND ND -- 9-Nov-20 EPA 8260D 0.16 1.0 NS ND ND 8.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.50 5.0 NS ND ND 8.7 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.29 1.0 NS ND ND 7.7 0.49 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC21- = 1,000 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NCH = 600 Ng/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 NS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND -- 2-May-16 EPA8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.26 1.0 NS 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA8260 0.26 1.0 NS 1.1 ND ND ND ND ND ND ND 14-May-18 EPA8260 0.26 1.0 NS 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.26 1.0 NS 0.91 J ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.31 1.0 NS 4.8 ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.24 1.0 NS 1.1 ND ND ND ND ND ND -- 6-May-20 EPA 826OD 0.24 1.0 NS 2.5 ND ND ND ND ND ND -- 9-Nov-20 EPA 826OD 0.24 1.0 NS 0.90 J ND ND ND ND ND ND ND 4-May-21 EPA 826OD 0.48 1.0 NS 6.80 ND ND ND ND ND ND ND 2-Nov-21 EPA 826OD 0.48 1.0 NS 1.00 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI Ni ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC21- = 2.8 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND NS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA8260 0.47 1.0 NS ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA8260 0.47 1.0 NS ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA8260 0.47 1.0 NS ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA8260B 0.47 1.0 NS ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 NS ND ND 5.9 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 NS ND ND 4.8 0.72 J ND ND ND -- 6-May-20 EPA 8260D 0.22 1.0 NS ND ND 5.0 ND ND ND ND -- 9-Nov-20 EPA 8260D 0.22 1.0 NS ND ND 5.4 ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 6.2 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 NS ND ND 5.7 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC21- = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC21- = 0.03 pg/L (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND NS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA8260 0.62 1.0 NS ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA8260 0.62 1.0 NS ND ND 1.1 ND ND ND ND ND 14-May-18 EPA8260 0.62 1.0 NS ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA8260B 0.62 1.0 NS ND ND 1.2 ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.4 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND 0.88 J ND ND ND ND -- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 1.1 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.39 1.0 NS ND ND 1.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyta Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC21- = 530 Ng/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NCH = 500 Ng/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 NS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA8260 0.66 5.0 NS 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA8260 0.66 5.0 NS 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA8260 0.66 5.0 NS 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.66 1.0 NS 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA 826OD 1.50 2.0 NS 55.8 17.7 ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.63 1.0 NS 22.3 14.3 ND ND ND ND ND -- 6-May-20 EPA 826OD 0.63 1.0 NS 34.0 15.1 ND ND ND ND ND -- 9-Nov-20 EPA 826OD 0.63 1.0 NS 20.8 15.0 ND ND ND ND ND ND 4-May-21 EPA 826OD 0.34 1.0 NS 51.5 9.5 ND ND ND ND ND ND 2-Nov-21 EPA 826OD 0.34 1.0 NS 18.2 13.3 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 42 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyze Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND NS ND ND ND ND ND IMAC = 1 Ng/L 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.58 2.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.29 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.59 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND -- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.32 1.0 NS ND ND ND ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 -May 1999; NC PQL for October 1999 -December 2006; and SWSL for December 2006 -present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. NA = No data available. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NR = Not reported. NC21_ = North Carolina Groundwater Standards from 15A NCAC 2L.0202. NI = Not installed. GWPS = Groundwater Protection Standards established by the SWS for constituents with no listed NC2L standard (no longer used). NE = Not established. IMAC = Interim Maximum Allowable Concentration. NS = Not sampled. Bold values are greater than the NC2L, GWPS, or IMAC. Dry= Insufficient water column to sample. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 42 of 42 Labelle Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Well Depth [ft] - 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25°C) 11-Jun-13 233.1 1168.0 847 - 56.9 14.2 62.8 74.1 [MS/CM] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 - 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 - 2185.0 920 875 99 25 97 114 14-May-18 - 1658.0 1117 923 131 22.2 118 59 4-Dec-18 - 1604.0 776 661 70 48 64.3 92.8 Resample-> 8-Feb-19 - - - - 55.9 - - - 6-May-19 - 1923 916 792 59.6 23.3 50.6 85.6 Resample-> 23-Jul-19 - - - 1454 - - - - 4-Nov-19 - 2225 831 853 92.1 18.3 59.3 90 6-May-20 - 2226 913 842 59 19.2 80.4 101.5 Resample--> 16-Jul-20 - - - - - 16.6 - - 9-Nov-20 - 2044 803 752 72.8 15.8 53.5 88.5 Resample--> 27-Jan-21 - 757 - -- - - - 4-May-21 - 1506.0 593 632.0 67.0 43.9 45.2 74.2 2-Nov-21 -- 3069 931 1002 112.6 25.6 75.9 122.7 pH 11-Jun-13 5.9 6.1 6.36 - 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 - 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 - 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 - 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample-> 8-Feb-19 - - - - 5.64 - - - 6-May-19 - 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample-> 23-Jul-19 - - - 6.00 - - - - 4-Nov-19 - 5.64 5.94 6.15 5.43 5.49 5.28 5.54 6-May-20 - 6 6.35 6.59 5.66 5.47 5.8 6.44 Resample--> 16-Jul-20 - - - - -- 5.55 - - 9-Nov-20 - 6.11 6.37 6.19 5.44 5.50 5.88 6.16 Resample-> 27-Jan-21 - - 6.65 - -- - - - 4-May-21 - 5.8 5.96 6.0 6.5 7.2 6.3 5.76 2-Nov-21 - 5.14 6.12 5.05 5.77 5.89 5.85 5.96 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 1 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Temperature 11-Jun-13 17.0 17.4 15.2 - 15.9 16.4 14 15.4 [ ° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 - 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 - 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 - 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 - 15.3 14.6 13.9 14 14 13.3 14.5 Resample-> 8-Feb-19 - - - - 15.2 - - - 6-May-19 - 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample-> 23-Jul-19 - - - 17.3 - - - - 4-Nov-19 - 15.1 13 16.4 14.7 15.3 16.4 16.4 6-May-20 - 16 16 16.7 14.6 16 13.3 14.2 Resample-> 16-Jul-20 - -- - - - 20.9 - - 9-Nov-20 - 17.0 17.4 16.6 15.9 16.2 17.5 15.1 Resample-> 27-Jan-21 -- 15.1 - - - - - 4-May-21 - 16.9 14.9 16.4 15.6 16.1 13.8 15.6 2-Nov-21 16.8 15.7 16.4 14.2 14.9 16.1 15.0 Dissolved Oxygen 6-May-19 - 0.92 3.59 1.09 5.18 5.73 5.44 2.13 [mg/L] 23-Jul-19 - - - 0.91 - - - - 4-Nov-19 - 1.63 1.85 4.39 3.99 4.36 3.55 2.89 6-May-20 - 5.06 4.71 5.14 6.7 1.85 5.74 4.33 Resample-> 16-Jul-20 - - - - - 7.37 - - 9-Nov-20 - 1.65 1.29 1.21 3.66 9.03 6.00 1.19 Resample-> 27-Jan-21 - 1.68 - - - - - 4-May-21 1.4 1.97 1.2 7.1 10.3 9.07 0.98 2-Nov-21 1.06 1.87 6.52 1.73 7.57 4.31 0.90 Oxidation Reduction Potential 6-May-19 - 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mV] 23-Jul-19 - -- - 210.5 - - - - 4-Nov-19 - 33.3 85.4 180.3 199 146.4 208.3 -81.6 6-May-20 - 218.2 272.5 323 192.5 300.9 192 201.5 Resample-> 16-Jul-20 - - - - - 282.3 - - 9-Nov-20 - 0.6 -24.7 1.4 199.9 202.3 230.1 63.1 Resample-> 27-Jan-21 - - -22.8 - - - - - 4-May-21 - 40.4 60.8 194.8 98.3 164.7 127.5 109.6 2-Nov-21 -30.4 64.7 116.0 56.9 110.9 83.2 -43.1 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 2 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Turbidity 11-Jun-13 27.4 4.50 3.65 - 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 - 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 - 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 - 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 - 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample-> 8-Feb-19 - - - - 7.96 - - - 6-May-19 - 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample-> 23-Jul-19 - - - 3.12 - - - - 4-Nov-19 - 4.79 9 3.01 35.17 41.15 8.49 30.39 6-May-20 - 8.25 8.12 12.17 97.58 356.5 79.08 3.74 Resample-> 16-Jul-20 - - - - - 13.23 - - 9-Nov-20 - 6.18 14.0 6.26 8.57 11.4 4.82 8.84 Resample-> 27-Jan-21 - - 8.5 - - - - - 4-May-21 - 8.7 8 4.0 30.1 91.6 20.4 5.25 2-Nov-21 6.93 33.7 1.55 65.5 150 18.6 2.23 Notes: °C= degrees Centigrade mg/L = milligrams per liter S.U.= Standard Units my = millivolts pS = microSemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 3 of 3 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC2B = 10 pg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 ND ND 5.2 J ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.7 10.0 ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.7 10.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2,000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10.0 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.50 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.20 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.80 J NC2B = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.30 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.70 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 EPA 6010 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 EPA 6010 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 EPA 6010 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 EPA 6010 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 EPA 6010 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 EPA 6010 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 EPA 6010 2.5 100 38.1 J 38.0 J 301 2.50 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 EPA 6010 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 EPA 6010D 2.5 5 33.1 32.0 267 ND 6-May-19 EPA 6010D 2.5 5 26.4 26.2 239 ND 5-Nov-19 EPA 6010D 2.5 5 34.5 35.9 34.8 --- 6-May-20 EPA 6010D 3.5 5 31.9 28.7 32.3 --- 9-Nov-20 EPA 6010D 3.5 5 34.0 33.7 32.0 ND 4-May-21 EPA 6010D 3.5 5 34.1 38.6 36.1 ND 2-Nov-21 EPA 6010D 3.5 5 30.5 31.8 30.8 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 pg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND Dry NA 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND NS ND 26-Jun-17 EPA 6010 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 ND ND ND ND 5-Nov-19 EPA 6010D 0.5 1.0 ND ND ND --- 6-May-20 EPA 6010D 0.4 1.0 ND ND ND --- 9-Nov-20 EPA 6010D 0.4 1.0 ND ND ND ND 4-May-21 EPA 6010D 0.4 1.0 ND ND ND ND 2-Nov-21 EPA 6010D 0.4 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.00 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J N D 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC2B = 20 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.3 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.3 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 2.8 J ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 4.4 J ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.7 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.7 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.7 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 3.7 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC2B = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 6 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND 9.6 J INS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 3.6 J ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 4.2 J ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.6 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.6 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.6 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 3.6 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC213 = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.4 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.0 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 4.3 5.0 ND ND ND 9-Nov-20 EPA 6010D 4.3 5.0 ND ND ND ND 4-May-21 EPA 6010D 4.3 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.3 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 4.1 J ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 4.5 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.5 5.0 ND ND ND ND 4-May-21 EPA 6010D 4.5 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 ND ND 4.6 B 2.2 J NC2B = 25 pg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 EPA 6010 5.0 50.0 ND ND 10.4 J ND 19-May-15 EPA 6010 2.5 50.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 50.0 ND ND 5.1 J ND 2-May-16 EPA 6010 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 EPA 6010 2.5 50.0 ND ND INS ND 26-Jun-17 EPA 6010 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 EPA 6010 2.5 50.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 5.9 ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 6.3 ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.5 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.5 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.5 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 3.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC213 = 5 pg/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND 6-May-20 EPA 6O1OD 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.7 10.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.7 10.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 4.7 10.0 ND ND ND ND Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC2B = 0.06 Ng/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 2.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 2.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 2.5 5.0 ND ND ND ND 2-Nov-21 EPA 6O1OD 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Thallium 4-Dec-18 EPA 6020B 0.1 0.1 ND ND 0.077 J - 6-May-19 EPA 6020B 0.1 0.1 ND ND 0.11 ND 5-Nov-19 EPA 6020B 0.1 0.1 ND ND ND 6-May-20 EPA 6020B 0.1 0.1 ND ND ND --- 9-Nov-20 EPA 6020B 0.1 0.1 ND ND ND ND 4-May-21 EPA 6020B 0.1 1.0 ND ND ND ND 2-Nov-21 EPA 6020B 0.1 0.5 ND ND ND ND Vanadium 19-Nov-03 NR 40.0 62.00 56.00 60.00 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NC213 = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 25.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 25.0 ND ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 EPA 6010 2.5 25.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 1.4 J 1.5 J 1.5 J --- 6-May-20 EPA 6010D 3.9 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.9 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.9 5.0 5.40 6.40 5.70 ND 2-Nov-21 EPA 6010D 3.9 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND 10.3 ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND 18.0 ND 19-May-15 EPA 6010 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 EPA 6010 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 EPA 6010 5.0 10.0 ND 8.0 J INS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND 7.4 J ND 6-May-19 EPA 6010D 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 9.5 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 9.5 10.0 ND ND ND ND 4-May-21 EPA 6010D 9.5 10.0 ND ND ND ND 2-Nov-21 EPA 6010D 9.5 10.0 ND ND ND ND Beryllium 5-Nov-19 EPA 6010D 0.2 1.0 ND 0.24 J ND --- 6-May-20 EPA 6010D 0.7 1.0 ND ND ND --- 9-Nov-20 EPA 6010D 0.7 1.0 ND ND ND ND 4-May-21 EPA 6010D 0.7 1.0 ND ND ND ND 2-Nov-21 EPA 6010D 0.7 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks ORGANICS Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND N D 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry N D 5-May-14 EPA 8260 10.0 100 ND ND 17.6 J ND 21-Oct-14 EPA 8260 10.0 100 ND ND ND ND 19-May-15 EPA 8260 10.0 100 ND ND Dry NA 7-Dec-15 EPA 8260 10.0 100 ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 ND ND NS ND 26-Jun-17 EPA 8260 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 EPA 8260 10.0 100 ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 ND ND ND ND 6-May-19 EPA 8260D 8.2 25 ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 ND ND ND --- 6-May-20 EPA 8260D 6.2 25 ND ND ND ND 9-Nov-20 EPA 8260D 6.2 25 ND ND ND ND 4-May-21 EPA 8260D 5.1 25 ND ND ND ND 2-Nov-21 EPA 8260D 5.1 25 ND ND ND ND Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 Ng/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.25 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.25 1.0 ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND ND 4-Dec-18 EPA8260B 0.25 1.0 ND ND ND ND 6-May-19 EPA8260D 0.20 1.0 ND ND ND ND 5-Nov-19 EPA8260D 0.15 1.0 ND ND ND --- 6-May-20 EPA8260D 0.15 1.0 ND ND ND ND 9-Nov-20 EPA8260D 0.15 1.0 ND ND ND ND 4-May-21 EPA8260D 0.34 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 EPA 8260 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 EPA 8260 0.29 10.0 ND ND 0.41 J ND 19-May-15 EPA 8260 0.29 10.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.29 10.0 ND ND ND ND 2-May-16 EPA 8260 0.29 10.0 ND ND ND ND 12-Dec-16 EPA 8260 0.29 10.0 ND ND NS ND 26-Jun-17 EPA 8260 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 EPA 8260 0.29 10.0 ND ND ND ND 4-Dec-18 EPA8260B 0.29 2.0 ND ND ND ND 6-May-19 EPA8260D 0.95 2.0 ND ND 1.5 J ND 5-Nov-19 EPA8260D 0.62 2.0 ND ND ND --- 6-May-20 EPA8260D 0.62 2.0 ND ND ND ND 9-Nov-20 EPA8260D 0.62 2.0 ND ND ND ND 4-May-21 EPA8260D 1.70 2.0 ND ND ND ND 2-Nov-21 EPA8260D 1.70 2.0 ND ND ND ND Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 ug/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J N D N D 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 EPA 8260 0.23 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.23 3.0 ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND ND NS ND 26-Jun-17 EPA 8260 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.23 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.23 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.23 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.23 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.28 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.28 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC213 = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.11 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 ND ND 0.19 J ND 19-May-15 EPA 8260 0.11 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.11 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.39 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.39 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.54 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.54 1.0 ND ND ND ND 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 ug/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.30 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 18 TABLE A2-4: Historical Surface Water Constituents Analyt Collection Date Method RL SW-1 SW-2 SW-3 Blanks 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 Ng/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 EPA8260 0.33 1.0 ND ND ND ND 21-Oct-14 EPA8260 0.33 1.0 ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 ND ND Dry NA 7-Dec-15 EPA8260 0.33 1.0 ND ND ND ND 2-May-16 EPA8260 0.33 1.0 ND ND ND ND 12-Dec-16 EPA8260 0.33 1.0 ND ND NS ND 26-Jun-17 EPA8260 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 EPA8260 0.33 1.0 ND ND ND ND 4-Dec-18 EPA8260B 0.33 1.0 ND ND ND ND 6-May-19 EPA8260D 0.58 1.0 ND ND ND ND 5-Nov-19 EPA8260D 0.26 1.0 ND ND ND --- 6-May-20 EPA8260D 0.26 1.0 ND ND ND ND 9-Nov-20 EPA8260D 0.26 1.0 ND ND ND ND 4-May-21 EPA8260D 0.33 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.33 1.0 ND ND ND ND 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NUB = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 EPA8260 0.32 5.0 ND ND ND ND 21-Oct-14 EPA8260 0.32 5.0 ND ND ND ND 19-May-15 EPA8260 0.32 5.0 ND ND Dry NA 7-Dec-15 EPA8260 0.32 5.0 ND ND ND ND 2-May-16 EPA8260 0.32 5.0 ND ND ND ND 12-Dec-16 EPA8260 0.32 5.0 ND ND NS ND 26-Jun-17 EPA8260 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 EPA8260 0.32 5.0 ND ND ND ND 4-Dec-18 EPA8260B 0.32 1.0 ND ND ND ND 6-May-19 EPA8260D 0.41 1.0 ND ND ND ND 5-Nov-19 EPA8260D 0.27 1.0 ND ND ND --- 6-May-20 EPA8260D 0.27 1.0 ND ND ND ND 9-Nov-20 EPA8260D 0.27 1.0 ND ND ND ND 4-May-21 EPA8260D 0.37 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.37 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 J NC213 = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.19 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.19 5.0 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 ND ND ND ND 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.27 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 ND ND ND ND 9-Nov-20 EPA8260D 0.19 1.0 ND ND ND ND 4-May-21 EPA8260D 0.36 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.36 1.0 ND ND ND ND 1,4-Dioxane(p-Dioxane) 4-Dec-18 EPA8260B 1.90 2.0 ND ND 10.5 ND 6-May-19 EPA8260D 1.20 2.0 ND ND 7.6 ND 5-Nov-19 EPA8260D 1.20 2.0 ND ND ND --- 6-May-20 EPA8260D 1.20 2.0 ND ND ND ND 9-Nov-20 EPA8260D 1.20 2.0 ND ND ND ND 4-May-21 EPA8260D 0.86 2.0 ND ND ND ND 2-Nov-21 EPA8260D 0.86 2.0 ND 1.40 J ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC213 = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.46 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 ND ND ND -- 6-May-20 EPA 8260D 0.16 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.16 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.29 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.29 1.0 ND ND ND ND Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.47 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 ND ND ND --- 6-May-20 EPA8260D 0.22 1.0 ND ND ND ND 9-Nov-20 EPA8260D 0.22 1.0 ND ND ND ND 4-May-21 EPA8260D 0.38 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.38 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS INS ND NC213 = 0.025 Ng/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 EPA8260 0.62 1.0 ND ND ND ND 21-Oct-14 EPA8260 0.62 1.0 ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND Dry NA 7-Dec-15 EPA8260 0.62 1.0 ND ND ND ND 2-May-16 EPA8260 0.62 1.0 ND ND ND ND 12-Dec-16 EPA8260 0.62 1.0 ND ND INS ND 26-Jun-17 EPA8260 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 EPA8260 0.62 1.0 ND ND ND ND 4-Dec-18 EPA8260B 0.62 1.0 ND ND ND ND 6-May-19 EPA8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 ND ND ND --- 6-May-20 EPA8260D 0.24 1.0 ND ND ND ND 9-Nov-20 EPA8260D 0.24 1.0 ND ND ND ND 4-May-21 EPA8260D 0.39 1.0 ND ND ND ND 2-Nov-21 EPA8260D 0.39 1.0 ND ND ND ND Hardness, Total (SM 23406) 6-May-20 EPA 6010D 131.00 662.0 25,300 22,600 25,100 Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; SWSL for December 2006 - 2017, and MRL 2017-present.). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC213 = 15A NCAC 2B Surface Water Standards. Dry = Surface water point was considered to be dry and no sample collected. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. Bold values are greater than the NC2B. NA = No data available. NR = Not reported. NS = Not sampled. NE = Not established. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 18 of 18 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25 °C) 11-Jun-13 54.4 63.2 655 [MS/CM] 29-Oct-13 78.2 67.8 - 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 - 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 - 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 4-Nov-19 78 92.4 80.9 6-May-20 77.0 76.8 76.8 9-Nov-20 68.4 69.6 74.5 4-May-21 61.1 54 79.8 2-Nov-21 115.4 100.0 112.0 pH 11-Jun-13 7.8 8.25 7.81 [S.U.] 29-Oct-13 7.2 6.85 - 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 - 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 - 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 6.60 6.98 7.92 4-Nov-19 6.60 6.78 6.63 6-May-20 7.5 7.43 7.43 9-Nov-20 6.32 7.09 7.18 4-May-21 6.93 6.62 6.76 2-Nov-21 7.32 6.86 6.22 Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 Page 1 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 2 0-0 ct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 - 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 4-Nov-19 10.07 10.6 10.7 6-May-20 14.4 17.2 17.2 9-Nov-20 16.2 17.1 17.1 4-May-21 16.2 16.2 16.5 2-Nov-21 11.6 13.6 13.9 Dissolved Oxygen 6-May-19 5.89 6.14 5.93 (mg/L) 4-Nov-19 7.23 6.56 7.27 6-May-20 5.2 4.89 4.89 9-Nov-20 7.86 7.82 6.65 4-May-21 9.35 8.79 7.62 2-Nov-21 8.52 7.23 6.88 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 (mV) 4-Nov-19 147.6 43.4 99.9 6-May-20 326.9 214 214 9-Nov-20 219.9 37.8 7.1 4-May-21 30.1 43.9 4.7 2-Nov-21 -55.0 -17.1 -55.1 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 - 5-May-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 - 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 - 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 4-Nov-19 11.6 10.4 10.0 6-May-20 15.6 15.6 15.6 9-Nov-20 7.5 9.13 9.24 4-May-21 47.4 77.90 47.40 2-Nov-21 6.37 6.19 5.72 Notes: °C= degrees Centigrade S.U.= Standard Units my = millivolts pS/cm = microSemens per centimeter NTU = Nephelometric Turbidity Units mg/L- milligrams per liter Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 Page 2 of 2