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3405_Forsyth_RJReynolds_RuralHall_Indus_Oct21GW_FID1642707_20220214
Groundwater &Surface Water Monitoring Semi- RlReynolds Annual Summary Report — October 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina February 2022 Project No.: 0588865 r The business of sustainability E RM ERM FRN Inc. Telephone: +1 704 541 8345 Summit Avenue F+1 704 624 7928 NC 28203 www.erm.com February 14, 2022 North Carolina Department of Environmental Quality Division of Waste Management 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Attention: Ms. Jaclynne Drummond jaclynne.drummond@ncdenr.gov Via Email Subject: Groundwater and Surface Water Monitoring Summary Report— October 2021 Permit #34-05 - Edwards Road Landfill Edwards Road Rural Hall, Forsyth County, North Carolina Dear Ms. Drummond: On behalf of R.J. Reynolds Tobacco Company, ERM NC, Inc. (ERM) is submitting the summary report for the October 2021 groundwater and surface water monitoring event associated with the subject property. As outlined in Section 5.0 of the report, ERM is requesting NCDEQ authorization to modify the Sampling and Analysis Plan for the subject Site by transitioning to annual monitoring and discontinuing analyses for barium, cadmium and lead. If acceptable, please provide written authorization to modify the Sampling and Analysis Plan. Please contact Mr. Scott Snow of R.J. Reynolds Tobacco Company at 336-741-2236 or me if you have any questions or comments. Sincerely, Alan M rtin, P.G. Project Manager Attachments: Environmental Monitoring Reporting Form Groundwater and Surface Water Monitoring Summary Report cc: Mr. Scott Snow - R.J. Reynolds Tobacco Company Mr. Max Hopkins - R.J. Reynolds Tobacco Company Mr. Brian Wilson - ERM Mr. Dave Wasiela - ERM DENR USE ONL�Y:t ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): ERM NC, Inc. (consultant) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Alan D. Martin E-mail: alan.martin@erm.com Phone:704-541-8345 Facility name: Facility Address: Facility Permit # NC Landfill Rule: Actual sampling dates (e.g., (.0500 or. 1600) October 20-24, 2006) R.J. Reynolds Industrial Landfill Edwards Road (S.R. 1903) 34-05 0.0503 October 20-21, 2021 Rural Hall, Forsyth County Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑ Assessment Monitoring ❑X Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Alan D. Martin, PG Project Manager 704-541-8345 Facility Represe i e Name (Print) Title February 14, Signature ERM NC, Inc. - 300 Summit Avenue, Suite 330, Charlotte, NC 28203 Facility Representative Address )Telephone Number G�QO[ Is Affix NC Licensed/ Professional Geologist Seal dos* G d ora Z : ►ih = _ NC Professional Geologic Corporation # C-470 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Signature Page February 14, 2022 Groundwater & Surface Water Monitoring Semi -Annual Summary Report — October 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Alan Marti , PG Principal Geologist ERM NC, Inc. 300 West Summit Avenue, Suite 330 Charlotte, North Carolina 28203 Phone: +1-704-541-8345 © Copyright 2022 by ERM Worldwide Group Ltd and / or its affiliates ("ERM"). All rights reserved. No part of this work may be reproduced or transmitted in any form, or by any means, without the prior written permission of ERM Brian Wilson, PG Partner in Charge www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 14, 2022 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING CONTENTS SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina CONTENTS 1. INTRODUCTION................................................................................................................................1 2. HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY.............................................1 3. SUMMARY OF MONITORING PROGRAM.......................................................................................1 4. DESCRIPTION OF WATER QUALITY CONDITIONS......................................................................3 4.1 Site Hydrogeology................................................................................................................................3 4.2 Groundwater.........................................................................................................................................4 4.3 Surface Water.......................................................................................................................................5 5. PRELIMINARY ANALYSIS................................................................................................................6 6. REFERENCES...................................................................................................................................7 List of Figures Figure1 Site Location Plan.......................................................................................................................... 9 Figure2 Site Plan.........................................................................................................................................9 Figure 3 Groundwater Flow Directions........................................................................................................9 Figure 4 Groundwater Sampling Results — October 2021........................................................................... 9 Figure 5 Surface Water Sampling Results — October 2021.........................................................................9 Figure 6 Sulfate Isocontour Map - Groundwater..........................................................................................9 Figure 7 Hydrogeologic Conceptual Model..................................................................................................9 Figure 8 Sulfate Trends - Groundwater....................................................................................................... 9 Figure 9 Sulfate Trends — Surface Water.................................................................................................... 9 List of Tables Table 1 Monitoring Well Construction Details..............................................................................................9 Table 2 Groundwater Elevations..................................................................................................................9 Table 3 Groundwater and Surface Water Sampling Event Summary Data ................................................. 9 Table 4 Groundwater Field Parameters.......................................................................................................9 APPENDIX A HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY ANALYTICAL DATA APPENDIX B LABORATORY DATA SHEETS APPENDIX C GROUNDWATER SAMPLING LOGS www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page i 2021-10 Edwards Rd LF Rural Hall GW Repon.docx GROUNDWATER & SURFACE WATER MONITORING INTRODUCTION SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 1. INTRODUCTION In accordance with the February 4, 2014 Corrective Action Plan (CAP; ERM NC, Inc.) and the Industrial Solid Waste Landfill Facility Permit No. 34-05-indus-1986 as amended through August 12, 2011, this report presents the results of the October 2021 groundwater and surface water sampling event conducted at the closed Edwards Road Landfill previously operated by R.J. Reynolds Tobacco Company. The closed landfill is located northeast of the jurisdictional boundaries of Rural Hall, Forsyth County, North Carolina (the "Site"). The location of the Site, along with topographic map coverage of the vicinity, are shown on Figure 1. Historical monitoring data indicate the occurrence of certain inorganic compounds in excess of the North Carolina Groundwater Standards (15A NCAC 2L) and Surface Water Standards (15A NCAC 213) within portions of the landfill extents. A Corrective Action Plan (ERM, 2014) prepared with the objectives of restoring groundwater quality beyond the compliance boundary, mitigating unacceptable impacts to the adjacent surface waters, and reducing the overall groundwater impacts at the facility was approved by the North Carolina Department of Environmental Quality (NCDEQ, formerly known as Department of Environment and Natural Resources) on February 19, 2014. The approved remedy includes source area contaminant control via the previous installation of the synthetic liner (cap) over the limits of waste, plus drainage improvements (completed in 2012) to minimize rainfall infiltration, leachate generation and discharge of constituents to groundwater, to allow intrinsic remediation of affected groundwater. Groundwater and surface water monitoring has been conducted semi-annually at the Site since 2012, following completion of the synthetic cap installation and drainage improvements. 2. HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY Groundwater and surface water quality monitoring has been conducted in the vicinity of the Edwards Road Landfill since 1989 in accordance with the conditions of Permit Number 34-05 and subsequent to the closure of the landfill, in accordance with the approved Post Closure Monitoring Plan (2003, Shield Engineering, Inc.). An updated water quality monitoring plan presented in the February 2014 CAP (ERM) was approved by NCDEQ on February 19, 2014 and is summarized in Section 3. Figure 2 depicts the locations of the groundwater monitoring wells and surface water sampling locations. Table 1 presents a summary of available well construction details. Historical laboratory analytical results for available groundwater and surface water samples are summarized in Appendix A. 3. SUMMARY OF MONITORING PROGRAM Routine groundwater and surface water monitoring activities were conducted on October 20-21, 2021 and are summarized in the following table: www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 1 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Samplinq and Analvses Plan SUMMARY OF MONITORING PROGRAM Analytic I Parameters Sample Metals a Total Dissolved Sulfate Field / Solids Location I.D. (EPA 6020B(EPA 300 .0) Parameters b 7074 SM 2540C Groundwater: W-1 ✓ ✓ ✓ ✓ W-2 Dry, no sample collected W-3 ✓ ✓ ✓ ✓ W-313 ✓ ✓ ✓ ✓ W-5 -- -- W-6 ✓ ✓ ✓ ✓ W-7 ✓ ✓ ✓ ✓ W-8 ✓ ✓ ✓ ✓ W-9 ✓ ✓ ✓ ✓ PW-1 ✓ ✓ ✓ ✓ PZ-1 c,a Dry, no sample collected PZ-2 c,e Dry, no sample collected PZ-3 c,e Dry, no sample collected PZ-4 c,e Dry, no sample collected PZ-5 Dry, no sample collected PZ-6 d -- -- -- -- PZ-7 d -- -- -- -- PZ-8 d -- -- -- -- PZ-9 d -- -- -- -- PZ-10 d -- -- -- -- Subtotal 8 8 8 8 Surface Water: SS-01 ✓ ✓ ✓ ✓ SS-01+150 d -- -- -- -- SS-01+550 d -- -- -- -- SS-01 +850 d -- -- -- -- SS-02 ✓ ✓ ✓ ✓ SS-10 -- -- -- -- SS-15 -- -- -- SS-20 ✓ ✓ ✓ ✓ SS-25 ✓ ✓ ✓ ✓ SS-30 ✓ ✓ ✓ ✓ SS-40 ✓ ✓ ✓ ✓ SS-50 ✓ ✓ ✓ Insufficient water SS-60 ✓ ✓ ✓ ✓ SS-70 ✓ ✓ ✓ ✓ SS-80 ✓ ✓ ✓ ✓ SS-90 ✓ ✓ ✓ ✓ Subtotal 11 11 11 10 TOTAL 19 19 19 18 2 Aluminum, barium, cadmium, chromium (total), iron, lead, manganese and selenium. Field parameters include temperature, pH, specific conductivity, turbidity, dissolved oxygen, and oxidation-reduction potential. PZ-1, PZ-2, PZ-3, PZ-4 and PZ-5 were dry during the October 2021 sampling event. Temporary point not included in routine sampling. e Analysis for all metals in PZ samples discontinued per NCDWM authorization dated 71912020. The groundwater and surface water monitoring activities were performed in general accordance with the techniques presented in the February 2014 CAP. Depth -to -water measurements and groundwater www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 2 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING DESCRIPTION OF WATER QUALITY CONDITIONS SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina elevations for available monitoring wells from the October 2021 sampling event are presented in Table 2. Groundwater flow directions are presented on Figure 3. Groundwater and surface water analytical data from the October 2021 sampling event are presented in Table 3. Field data measurements are provided in Table 4. Historical analytical data for both groundwater and surface water samples collected from the Site are presented in Appendix A. Laboratory data sheets for the October 2021 sampling event are presented in Appendix B. Copies of the sample logs are provided in Appendix C. Groundwater and surface water sample analytical results from the October 2021 sampling event are presented on Figures 4 and 5, respectively. Figure 6 depicts the isoconcentration contours of sulfates in groundwater at the site and Figure 7 presents a hydrogeologic conceptual site model and cross-section. Sulfate concentrations in groundwater and surface water over time are presented graphically on Figures 8 and 9, respectively. 4. DESCRIPTION OF WATER QUALITY CONDITIONS The following sections highlight key findings from the analytical results. 4.1 Site Hydrogeology The Site geology consists of fractured bedrock (gneiss and schist) overlain by partially weathered rock and a mantle of residual soils near the surface. The depth to bedrock beneath the Site generally ranges from 10 to 50 feet below ground surface (bgs). The shallowest occurrence of groundwater beneath the ground surface of the Site is within the fractured bedrock zone. In the lower ground surface elevations of the Site near the streams, groundwater is present within the partially weathered rock overlying hard bedrock (transition zone). Shallow groundwater beneath the Site migrates either along the top of bedrock or along the permeable zones within the shallow fractured bedrock zone and discharges into nearby creeks, namely Leak Creek and its tributaries. The regional groundwater flow regime within the lower portion of the deep bedrock aquifer is northeastward toward the nearest regional drainage feature, Town Fork Creek. The depth to groundwater in the transition zone overlying bedrock ranges from the ground surface at the creeks to approximately 13 feet bgs in shallow monitoring wells. The depth to water in the bedrock aquifer ranges from artesian conditions to approximately 110 feet bgs. Using recent depth -to -water measurements, Site groundwater elevations and hydraulic gradients for the Site were calculated as summarized below. Horizontal Hydraulic Gradient - Saprolite/Partially Weathered Rock (PWR) October 20, 2021 Well Reference Depth to Head Head Distance Hydraulic Designation Elevation Water Elevation Change Change Gradient ft MSL ft ft (ft) ft ft/ft W-1 822.68 16.21 806.47 Leak Creek a 780.0 0 780 26.47 180 0.147 W-3 804.43 4.86 799.57 Leak Creek a 785.5 0 785.5 14.07 80 0.176 Average Hydraulic Gradient 0.161 a Leak Creek bed elevation represents groundwater discharge line Based on the October 2021 hydraulic gradients, the groundwater flow rate (seepage velocity) in the saprolite/PWR aquifer zone was calculated as summarized below. www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 3 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Groundwater Seepage velocity Calculation = Ki/ne DESCRIPTION OF WATER QUALITY CONDITIONS where: K = hydraulic conductivity 0.080 ft/day (estimated) i = horizontal hydraulic gradient 0.161 ft/ft (measured) ne = effective porosity 0.25 estimated Groundwater Seepage Velocity (Saprolite/PWR) = _ (0.08) ( 0.161) / (0.25) = 5.17 x 10-2 ft/day or 19 ft/year The widely spaced locations of the bedrock monitoring wells at the Site do not allow for calculation of the hydraulic gradient and groundwater flow rate of the bedrock aquifer. 4.2 Groundwater During the October 2021 groundwater sampling event, eight monitoring wells were sampled utilizing a low -flow, low -volume sample collection technique. Piezometers PZ-1, PZ-2, PZ-3, PZ-4 and PZ-5 were dry during the sampling event; therefore, no samples were collected. Presently, samples from groundwater monitoring wells at the Site contain concentrations of sulfates, total dissolved solids, and four metals above the applicable North Carolina groundwater standards (NC 2L standard). Sulfate, the primary constituent related to the landfill, was detected in two groundwater samples in excess of the NC 2L standard. Iron was detected in three of the eight groundwater monitoring well samples in excess of the NC 2L standard. Manganese was detected in three of the eight groundwater monitoring well samples in excess of the NC 2L standard. Total chromium was detected in two groundwater monitoring well samples each in excess of the NC 2L standard. Selenium was detected in the W-1 groundwater sample above the NC 2L standard. The elevated concentrations of iron, chromium and manganese in groundwater samples from the Site monitoring wells are likely attributable to their natural occurrence in groundwater as indicated by historical sample results from onsite background monitoring wells (W-6 and former W-4). Dissolved solids were detected in two of the groundwater monitoring well samples in excess of the NC 2L standard. Consistent with the historical monitoring results, no elevated concentrations of sulfates, metals or total dissolved solids were detected in the groundwater sample collected from off -site monitoring well W-9, located to the southeast and side gradient of the landfill. As noted in Section 1, installation of the synthetic cap and construction of drainage improvements over the limits of waste were completed in September 2012. The October 2021 groundwater samples were collected approximately nine years after the cap installation. As graphically depicted in Figure 8, sulfate concentrations in groundwater samples collected from both the shallow and deep aquifer zones at the Site since the implementation of the corrective action in 2012 continue to exhibit overall decreasing or stable trends. The October 2021 monitoring results indicate that only two monitoring well locations contain groundwater with sulfate concentrations above the NC 2L standard: W-01, screened in the shallow saprolite aquifer zone, and PW-01, screened across the shallow and bedrock aquifer zone. Prior to the 2012 cap installation, sulfate concentrations exceeded the NC 2L standard in groundwater at five monitoring well locations and the inactive water supply well PW-1. The decrease in plume extent over time and the sustained trend of decreasing sulfate concentrations at the Site show that the corrective action has been effective for remediating both the lateral extent of affected groundwater in the shallow saprolite/partially weathered rock aquifer zone and the vertical extent of affected groundwater in the deeper bedrock aquifer zone. www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 4 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING DESCRIPTION OF WATER QUALITY CONDITIONS SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 4.3 Surface Water A total of 11 surface water samples were collected during the October 2021 sampling event. The October 2021 surface water monitoring results indicate there are no surface water quality impacts directly attributable to the landfill. Concentrations of sulfates and total dissolved solids in all of the samples collected during the October 2021 sampling event were below the applicable North Carolina surface water standards (NC 213 standards). Iron, manganese and lead were present above the applicable NC 2B standards in the SS-50 surface water sample collected upgradient of the landfill. Iron, manganese and lead concentrations in the remaining samples were below the applicable NC 2B standards. No selenium or chromium were reported in the surface water samples. Overall, October 2021 surface water quality results confirm that the corrective actions at the Site have been effective for the remediation of surface water at the Site. Compared to upstream surface water quality, there have been four confirmed on -site exceedances of surface water quality standards in the streams since 2014. There have been no exceedances of surface water quality standards downstream of the landfill (SS-40, SS-80 or SS-90) since installation of the synthetic landfill cap in 2012. www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 5 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING PRELIMINARY ANALYSIS SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 5. PRELIMINARY ANALYSIS The October 2021 monitoring results demonstrate: ■ Sulfate, total dissolved solids, iron, manganese, selenium and total chromium in groundwater samples exceed the NC 2L standards. The elevated concentrations of iron, manganese, and total chromium in groundwater are likely attributable to their natural occurrence in groundwater. ■ Overall, the groundwater quality data indicate that the concentration trends and area of affected groundwater have been stabilized or reduced at the Site. Using sulfate as a primary indicator of landfill -related impacts, the sulfate concentrations in groundwater, both shallow and deep, continue to show sustained decreasing trends since completion of the landfill cap installation in September 2012. ■ No elevated concentrations of sulfates, metals or total dissolved solids have been detected in the groundwater sample collected from off -site monitoring well W-9, located to the southeast and hydraulically side gradient of the landfill. ■ Consistent with the historical monitoring results, concentrations of sulfates and total dissolved solids in all 11 surface water samples did not exceed the applicable NC 2B standards. There have been no exceedances of surface water quality standards downstream of the landfill since the installation of the synthetic landfill cap in 2012. Iron, manganese and lead concentrations above the applicable NC 2B standards were reported the SS-50 surface water sample upgradient of the landfill. The presence of these metals in the upgradient sample is likely attributable to suspended sediment created during the sampling process due to low -flow conditions in the creek during sampling. Iron and manganese concentrations were below the NC 2B standards in all remaining surface water samples. Chromium and selenium were not detected in the remaining surface water samples. ■ The October 2021 samples were collected approximately nine years after implementation of the corrective action in 2012 and the monitoring results confirm continued improvement of groundwater and surface water quality at the Site. The water quality improvements indicate that the cap installation and the drainage improvements at the landfill are effective remedial measures. A transition to annual groundwater and surface water monitoring is recommended based on the continued water quality improvements at the Site. In addition, discontinuation of analyses for barium, cadmium and lead in groundwater and surface water samples is recommended due to their absence or infrequent detections at concentrations consistently below the applicable NC 2L or 213 standards. An updated Sampling and Analysis Plan incorporating these recommended changes is presented below. Annual Sampling and Analyses Plan Sample Metals a Location I.D. (EPA 602013/ 7074) Groundwater: W-1 ✓ W-2 ✓ W-3 ✓ W-3B ✓ W-5 W-6 ✓ W-7 ✓ W-8 ✓ W-9 ✓ PW-1 ✓ Analytical Parameters Sulfate Total Dissolved (EPA 300.0) Solids (SM 2540C) Field Parameters b www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 6 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina PRELIMINARY ANALYSIS Analytic I Parameters Sample Metals a Total Dissolved / Sulfate Solids Location I.D. (EPA 6020B(EPA 300 .0) Field b Parameters 7074) (SM 2540C) PZ-1 ° -- ✓ ✓ -- PZ-2 c -- ✓ ✓ -- PZ-3 c -- ✓ ✓ -- PZ-4 c -- ✓ ✓ -- PZ-5 -- ✓ ✓ -- PZ-6 d -- -- -- -- PZ-7 d -- -- -- -- PZ-8 d -- -- -- -- PZ-9 d -- -- -- -- PZ-10 d -- -- -- -- Subtotal 9 14 14 9 Surface Water: SS-01 ✓ ✓ ✓ ✓ SS-01+150 d -- -- -- -- SS-01+550 d -- -- -- -- SS-01+850 d -- -- -- -- SS-02 ✓ ✓ ✓ ✓ SS-10 -- -- -- SS-20 ✓ ✓ ✓ ✓ SS-25 ✓ ✓ ✓ ✓ SS-30 ✓ ✓ ✓ ✓ SS-40 ✓ ✓ ✓ ✓ SS-50 ✓ ✓ ✓ ✓ SS-60 ✓ ✓ ✓ ✓ SS-70 ✓ ✓ ✓ ✓ SS-80 ✓ ✓ ✓ ✓ SS-90 ✓ ✓ ✓ ✓ Subtotal 11 11 11 11 TOTAL 20 25 25 20 'Aluminum, chromium (total), iron, manganese and selenium. b Field parameters include temperature, pH, specific conductivity, turbidity, dissolved oxygen, and oxidation-reduction potential. Analysis for all metals in PZ samples discontinued per NCDWM authorization dated 71912020. d Temporary point not included in routine sampling. The revised schedule for proposed annual monitoring activities is summarized below. Target Activity Completion Date Conduct Annual Water Quality Monitoring Event September 2022 Submit Water Quality Monitoring Summary Report to NCDEQ December 2022 ERM respectfully requests NCDEQ concurrence with the reduced monitoring frequency and the modified Sampling and Analysis Plan which are supported by a review of the nine years of Site monitoring data since completion of the synthetic cap installation. If acceptable, please provide written acceptance of these changes. www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 7 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING REFERENCES SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina 6. REFERENCES Date Title Source 1986-05-29 Solid Waste Permit No. 34-05 issued to R.J. Reynolds Tobacco Company NCDENR 1999-10-19 R. J. Reynolds Tobacco Company Ash Landfill Transition Plan Geo-Environ mental Consultants, Inc. 2000-01-25 Work Plan for Upgrading Groundwater Monitoring, Phase 11 Ash Fill Area Geo-Environ mental Consultants, Inc. 2000-03-13 Upgrade of Groundwater Monitoring Program, Phase 11 Ash Fill Area Shield Environmental Associates, Inc. 2001-01-02 Modifications to Transition Plan, Permit #34-05 Shield Environmental Associates, Inc. 2003-12-23 Post Closure Cover Maintenance Plan, Permit #34-05 Shield Environmental Associates, Inc. 2009-04-17 Compliance Order with Administrative Penalty, Facility #34-05 NCDENR 2009-07-17 Preliminary Site Assessment Work Plan, Facility #34-05 ERM 2009-10-29 Summary Report — Preliminary Site Assessment, Facility #34-05 ERM 2010-11-15 Letter correspondence to NCDENR DWM regarding Off -Site Well ERM Locations, Facility #34-05 2011-03-10 Summary Report — Phase 11 Site Assessment ERM 2011-06-14 Proposed Closure Modification - Edwards Road Landfill, Permit No. 34-05 ERM 2011-08-12 Regulatory approval Letter Of Closure Modification, Permit No. 34-05 NCDENR 2012-04-30 Summary Report — Groundwater Modelling for Site Assessment ERM 2012-09-21 Construction Quality Assurance for Closure Modification, Permit No. 34- ERM 05 2012-10-09 Letter correspondence to NCDENR regarding Groundwater Modelling & ERM Water Quality Monitoring, Facility #34-05 2012-11-07 Groundwater Corrective Action Permit Modification Application ERM 2013-10-01 Groundwater Corrective Action Application and Revised Groundwater ERM Modelling Scenarios 2013-10-10 Regulatory approval of Groundwater Corrective Action Application NCDENR 2013-10-11 Regulatory approval of Construction Quality Assurance for Closure NCDENR Modification, Permit No. 34-05 2014-02-04 Corrective Action Plan, Permit No. 34-05 ERM 2014-02-19 Regulatory approval of Corrective Action Plan NCDENR Various Groundwater and Surface Water Monitoring Summary Reports — 2010- ERM present www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 8 2021-10 Edwards Rd LF Rural Hall GW Report.docx GROUNDWATER & SURFACE WATER MONITORING SEMI-ANNUAL SUMMARY REPORT — OCTOBER 2021 Edwards Road Landfill — Permit # 34-05 Rural Hall, Forsyth County, North Carolina Figures Figure 1 Site Location Plan Figure 2 Site Plan Figure 3 Groundwater Flow Directions Figure 4 Groundwater Sampling Results — October 2021 Figure 5 Surface Water Sampling Results — October 2021 Figure 6 Sulfate Isocontour Map - Groundwater Figure 7 Hydrogeologic Conceptual Model Figure 8 Sulfate Trends - Groundwater Figure 9 Sulfate Trends — Surface Water Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Elevations Table 3 Groundwater and Surface Water Sampling Event Summary Data Table 4 Groundwater Field Parameters REFERENCES www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 Page 9 2021-10 Edwards Rd LF Rural Hall GW Report.docx u LI if Y. VOrA 2 n obti'•. _• J� �y�. �i�l� �� y-y ` 1. �• .6 -� - � '- ��_ , `�` ��`,(�, � �-�-��,,,, o � .�`Y��: tea, --� ::.._ �6 �,�. �:�i��' 4_�'' 17 l="� ~='�_,.--�:-:•�` y 3 0 2,000 - Feet I' y Legend Figure 1 Compliance Boundary ±_ _� Limits of Permit Site Location Map U Edwards Road Landfill Permit #34-05 LD R.J. Reynolds Tobacco Co. i ERM NC, Inc. ERM www.erm.com 1:24,000 1 inch = 2,000 feet Rural Hall, North Carolina Source: Copyright:© 2013 National Geographic Society, i-cubed Coordinate System: NAD 1983 StatePlane North Carolina FIPS 3200 Feet 11, 11 L' I - .; . 900 o SS-50 E r- ^ E / B-9 R. J. W-4 W-6 O SS-10 A" : R. J. Reynolds �'' 1 , B-8 SS-80 300 PZ-3 0 Johnston SS 170 �� PZ-4 /J 4 v_SSV '-75 ♦ ` S �ilo Z-5 -60 , PZ-1 Si'�� ��' .dam . I� :. s; is? w-z 4 �., � t f W 1C� /I W-14 0_6, rm 10 SS-25 ZA .k W-3' j SS-95 f W-3B O� SS-01 +1 _'0 SS-001� Phipps W-9 O F I Ken Stewart SS-30 Stewart Sprinkle '�PZ-2 /7 SS-40 Phipps Ken Stewart Dave Stewart Don Stewart Mozelle Stewart N — - — t_. . SS-90 �L.. 2. del j huh (r F u I. I 1 H •.,11 Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well Payne O Abandoned Monitor Well z� Piezometer Z Soil Boring/Piezometer 11ii Soil Boring y Surface Water j As -Built Landfill Contours (20') Compliance Boundary Limits of Permit Streams Parcels Freeman s• Payne a; Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on Frierson available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 SS-15 r 1:4,320 1 inch = 360 feet r7eedom 9p0 BaptisOF s 0 180 360 540 - Church -- i Feet j Source: NCOneMaD Data Services (Imaaerv. Darcels). Forsvth Countv GIS Data Download (Streets. buildings) Sources: Esri. HERE. Garmin. IntermaD. increment P Coro.. GEBCO. USGS. FAO. NPS. NRCAN. GeoBase, IGN, Kadaster NL Ordnance Survev, Esri JaDan. METI. Esri China (Nona Kona). (c) ODen StreetMaD contributors. and the GIS User Community iWagner Figure 2 Site Area Map Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d www.erm.com ERM gate System: NAD 1983 StatePlane North Carolina RIPS 3200 Feet Beck goo R. J. Reynolds 1p00 Boyd 1:4,320 I 1 inch = 360 feet 0 180 360 540 Feet W-4 W-6 (880.27) .- Or J 8p0 Johnston � PZ-3 � 0 W8 (811.65) PZ-4- / PZ-2 -► (838.55) PZ-5 too0 Al Y R • - (809.72)I O pp� � PW� IW-1 , R. J. I� 1(853.77) (806:47) ,/' Guthrie Reynolds 000 i W-3 f (799.57) O' `W-3B ' � I Sprinkle -• •' - rI`l Phipps / ❑ 40 W-9 (800.95) - O Phipps Ken Stewart Ken Stewart Don Stewart Hawks Freedom Dave Stewart Don Stewart Mozelle Baptist Stewart Church 1�1 I Freedom O 9po Baptist Church Payne Freeman Payne Wagner 0, m� co D; U Kleitchens Q ❑ ❑ o x�_. Volta huh Rtiral Hill Legend O Saprolite/PWR Monitor Well O Bedrock Monitor Well o Piezometer Streams As -Built Landfill Contours (20') Compliance Boundary Limits of Permit Parcels Regional groundwater flow Local shallow groundwater flow Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 4. Regional and Local Shallow Groundwater Flow based on groundwater modeling (ERM, 2012) 5. Water Levels measured 20 October 2021. Figure 3 Groundwater Flow Direction Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d www.erm.com ERM j Source: NCOneMao Data Services (Imaaerv. oarcelsl. Forsvth Countv GIs Data Download (Streets. buildinasl Sources: Esri, HERE, Garmin. Intermao. increment P Coro.. GEBCO. USGS. FAO. NPS. NRCAN. GeoBase, IGN, Kadaster NL. Ordnance Survev, Esri Jaoan. METL Esri China (Nona Konal. (cl ODen StreetMao contributors, and the GIs User Community Y s L. -- •)' - p ; L•� yer _ .:.' r. lfi. �•a .fir:. - o. W-08 : SCRN-45.00-65.00 r < ;: a . r i �:� _��•-- ' •i ' W-8-WG-20211020 10/20/2021 ':.. _. .¢.� -y1' �• "�k 1 Aluminum 400 ` 1� 1 rrx rr� q / ;7% 11J b. J r / W-07:SCRN-42.00-341.00 Barium 150 _ .: .`' F Ui II Hall . �- ,`•y Cadmium <0.5 -� _ W-7-WG-20211021 10I21I2021 -' Aluminum 140+ ', Chromium 12 •�iX, �: F .. , r k ,a. s _ Iron 680- - -.,a ' •:Y . t yap _ Legend ^. t •� ♦ _ Barium 130 k•� Lead < 1.0 F.,. 1r;. ':`?1;` a:•i•iy_ ^ w g q. :k.. ` Cadmium <o.s g =; O Saprolite/PWR Monitor Well �q _ � Manganese 15 ' y >>• " -f'+.;�• I�'• Chromium <„ �•.�+.�R. Selenium <5.0 �� •tiy,•' _ Iron 870 Sulfate 19,000 O Bedrock Monitor Well Lead a, '' • fl i ° o f _ Man anese < t2g � � ? � �. FI Dissolved Solids, Total yzf' Selenium <5.0 SS-80 +a Abandoned Monitor Well }/� Sulfate 12,00o P. SS-90 ' F .,. ■:' Piezometer ' r r' ii _. _ Dissolved Solids, Total 130,000 0 . • I _ � "� `t ¢ 0 Soil Boring/ Piezometer SS-70 PZ-4 PZ-2 ,•;} �:: a�•" . :.�. __ e.d Soil Boring SS-75 g PZ-5 ` SS-40 :.e ,. 4 Surface Water .`..._'� PW-01 : SCRN-21.50-405.00 O SS-60 4 ' ;.•. PW-1-WG-20211020 10/20I2021 _ - + _ ` r - Sulfate 670,000 _ r- Streams �" t r SS-65 , w, PZ 1 0 As -Built Landfill Contours 20' L d-,x�,w Dissolved Solids, Total 1,600,000 waif �'rSS-35' jj i SS-02 CiCompliance Boundary Y � •�Y •'r A' '�' O ". ".�! - V-��.'' •J� +�. }: -ice' � � i� SS-01+850 a y` ♦ �/ B-4 SS-50 { O B-5 _ ~ _S 95 { W-06:SCRN-170.00-200.00 •.,+;' B-9 B g SS-01+150 Limits of Permit Parcels r - Notes 1. 120 - Result exceeds applicable standards. 2. Limits of landfill are approximate based on available historic data. 3. Streams estimated based on NC Floodplain Mapping Program, 2008 B-10 -t s� "'±�^+"'i','; i 4. All concentrations in micrograms per liter W-6-WG-20211021 10/21/2021 - Aluminum 320 �t[1 - i` . af-• . < SS-01 °`- T _ a U /L 'nJLJ_`' W-03 : SCRN-7.00-17.00 ( g � 5 4' • Barium st �e^ r " --=` `°'r 5. Metals analyses in iezometer samples r j^ B-12 r / W-3-WG-20211020 10I20I2021 _ _ y P P z Cadmium <o.s = + ` -_ 44-'' f discontinued in September 2020 q a Aluminum <40.0 .q P Chromium 10 " ; j Barium 34 6. PZ-01, PZ-03, & PZ-04 were dry Iron 540"I. y,. I : Cadmium <0.5 7. PZ-05 has been destroyed ° Lead < 1.0 B-1 SS-20 .1 SS-25 .. y -t Chromium < 5.0 5 Manganese 16 _ / ��^^>> �, /' r' :.Q • - Y '_f •' Iron < 50.0 Selenium < t .Y%-',- _ .jl'?• 8 � 5.0 �r � • �•a.r ..S-�. � 4 j �. :�• Lead <1.0 Sulfate 10,000 ' +r - 'S - *• - - - SS-307 Manganese 120 # o Dissolved Solids, Total 260,000 - i? x . B-14 • •O • / R _ +�y.�, Selenium < 5.0 o . r J. ti . •� '� Sulfate ' %,.. 120,000 S Dissolved Solids, Total 370,000 Y . ' g. SS-10 W-09: SCRN-229.00-259.00 ^F: • �� � _ �} "'y+=:�•- W-9-WG-20211020 10I20I2021 a r, jI Y••.lY.''-..{. •9 Aluminum 85 `i '•I NYC - Barium 130 SS-15 - Cadmium < 0.5 p _ �:� "• - Chromium <5.0 Q y - Iron < 50.0 Lead < 1.0 Manganese < 5.0 a o•-Y . f Selenium <5.0 ''�r� • IP � �r Sulfate 12,000 n e 3CRN-10.00-20.00 W-1-W G-20211021 10/21 /2021 Aluminum 41 Barium 22 Cadmium < 0.5 Chromium < 5.0 Iron 290 Lead < 1.0 Manganese 3,600 Selenium 22 Sulfate 1,10Q000 Dissolved Solids, Total 2,200,000 Cz Figure 4 ,::• ; :- Groundwater Sampling Results - October 2021 of Y d'S Edwards Road Landfill Permit #34-05 .°° R.J. Reynolds Tobacco Co. II = ,. •' "" ' ` m Rural Hall, North Carolina Q 1:7,200 1 inch - 61J0 feet s 0 300 600 900 ERM NC, Inc. i Feet a o www.erm.com ERM Source: NCOneMaD Data Services (Imaeerv. Darcelsl. Forsvth Countv GIS Data Download (Streets. buildinasl Sources: Esri. HERE, Garmin. IntermaD. increment P Coro.. GEBCO. USGS. FAO. NPS. NRCAN. GeoBase. IGN, Kadaster NL Ordnance Survev, Esri JaDan. METL Esri China (Hone Konal. (cl ODenStreetMaD contributors. and the GIS User Communitv Coordinate Svstern: NAD 1983 StatePlane North Carolina RIPS 3200 Feet NC 2L Groundwater Standard Aluminum (ug/L) 3,500 Barium (ug/L) 700 Cadmium (ug/L) 2 Chromium (ug/L) 10 Iron (ug/L) 300 Lead (ug/L) 15 Manganese (ug/L) 50 Selenium (ug/L) 20 Sulfate (ug/L) 250,000 Dissolved Solids, Total (ug/L) 500,000 W-03B : SCRN-190.00-210.00 W-3 B-W G-20211020 10/20/2021 Aluminum < 40.0 Barium 50 Cadmium < 0.5 Chromium < 5.0 Iron 210 Lead < 1.0 Manganese Selenium 78 < 5.0 Sulfate 14,000 Dissolved Solids, Total 230,000 • � y �1 �'[ � r`l N � �'��� '.1.._ .. :w;:. •tom � � �� .�.. _ .. ea �3 '° , ^'. Cis � ti SS 60 SS-70 SS-80 �� *;: ; is SS-60-WS-20211021 10/21/2021 F + • .i,'z � •�r � SS-70-WS-20211021 1012112021 F '� SS-80-WS-20211021 10I21I2021 ,.,•. y' .r %:: • SS-90 U .: Aluminum 80`: SS-90-WS-20211021 10I21I2021 ' LuC S�"f11.-t,i Aluminum 61r� �.. Aluminum 85°'• - ` ;:� Aluminum 53 �$` { Barium 64 x.. Barium 73 Barium 76 Barium 65 Rural Hall Cadmium <0.5 - Cadmium <0.5 Cadmium <0.5'1 _ Cadmium <0.5 _ - Chromium < 5.0 Chromium < 5.0 Chromium < 5.0 • Chromium < 5.0 Iron 210 Iron 170 Iron 200 Iron 140 Legend '-` Lead < 1.0 _ Lead < 1.0 �• Lead < 1.0J _ - Lead < 1.0 . Manganese 11 Manganese 7.5 Manganese 15 Manganese 5.4 O Saprolite/PWR Monitor Well a Selenium < 5.0 Selenium < 5.0 Selenium < 5.0 Selenium < 5.0 c L Sulfate 13,000 Sulfate 53,000 Sulfate 6Q000 Sulfate 29,000 O Bedrock Monitor Well Dissolved Solids, Total 92,000 Dissolved Solids, Total 230,000 t' Solids, Total d Dissolved 240,000 Dissolved Solids, Total 140,000 - D e ' SS-80 Q'� g`, O Abandoned Monitor Well ss 50ss' PZ_3• ,x;"MOW Piezometer SS-50-WS-20211021 10/21/2021 SS-90 .,. J Aluminum 1,300 moo' - yy� - y o o 0 Soil Boring/Piezometer Barium 170 _0° _ SS-70 PZ-4 PZ-2 Cadmium < 0.5 oilO ed Soil Boring u Chromium < 5.0 - #� W-7 PZ-5 ♦ SS775 40 SS-40 y � :.i g Surface Water s' 4 Iron 25,000 O SS-60 � Lead 6.5 _ 55-40-ws-20211021 10I21I2021 o • Aluminum 83 ! �, Streams uManganese 710 ss-65 _ , Piz-1 , b o _ Barium 74 L Selenium <5.0 �, ` SS-35 Cadmium <0.5As-Built Landfill Contours (20') £ ' Sulfate 1100.0 Chromium <s.o ��Compliance Boundary n " L Dissolved Solids, Total 72000.0 jSS-02 Iron 200 Y I oW_2, Lead <1.0 Limits of Permit E _ Manganese 8.5 y .� _ •�£:C --'i �"-•'-=-t-+ '+� Selenium < 5.0 ' Parcels W-1 5 �PW-V7-7 �OSS-01+850 ri' Sulfate 50,000 N Y�i O n Dissolved Solids, Total 230,000 B 4 { x ' .� ' Notes SS-20 SS-50 W-4 W 6 B 5 SS-02 � 1. 120 - Result exceeds applicable standards. '.� SS-20-WS-20211021 10I21I2021 - SS;01+550 - O SS-02-WS-20211021 10/21/2021 2. Limits of landfill are approximate based on Aluminum 170 Aluminum 77 !' !- .:4 , available historic data. " Barium 38 \ W-3 "1 '_ .� . ���L ., _. Barium 7s �'i�i�'3;' 3. Streams estimated based on NC Floodplain Cadmium < 0.5 B-9. B-10 B-8 O SS-95 Cadmium < 0.5 i �7�� Mapping Program, 2008 K Chromium < 5.0 B 7 W 3B SS-01+150 Chromium < 5.0 4. All concentrations in micrograms per liter Iron 480 7 - - _ Iron 200 'n Ito.. (ug/L) '.? Lead < 1.0 13-12 _ _ Lead < 1.0 zManganese 27 - - � �-' A �;',�-• Manganese 7.7 Selenium < 5.0 jr 1 ;- rT = Sulfate 9,200 _ �! W ` Selenium < 5.0 f«; Dissolved Solids, Total 82,000 W-4 W-6 B-11 SS-25�• u ♦ 4i Sulfate 5Q000 fi°? SS-20 �• i y W-9 1e�� Y Y r- �- t::• , , Dissolved Solids, Total 220,000 o o W-5 SS-30 _ ;Sf o. y'' n . - .. •�• •;- - i B-14 r' •• s :nr i '�4 F .£' .. ��� SS01 t N p NC 2B Surface Water Standard Aluminum (ug/L) 8,000 Barium (ug/L) 21,000 Cadmium (ug/L) 0.3 Chromium (ug/L) 50.1 Iron (ug/L) 1,000 Lead (ug/L) 1.49 Manganese (ug/L) 100 Selenium (ug/L) 5 Sulfate (ug/L) 250,000 Dissolved Solids, Total (ug/L) 500,000 y - SS-10 X- ; SS-25 4, -? SS-25-WS-20211021 •- ' Aluminum Barium „• r.Y�S_j. ....r4, .. .•.yi '�' ., Cadmium �•';' Chromium Iron _ Lead 10I21I2121 120 37 : 0.5 <5.0^ 360 <1.0r� • I r..-'_ �, , a G? SS-30.. SS-30-WS-20211021 Aluminum Barium Cadmium Chromium Iron Lead 10/21/2021 140 60 <0.5 < 5.0 430 < 1.0 n - +� " �• .! - k CI J _ - --01-WS-20211021 SS Aluminum Barium Cadmium Chromium Iron Lead Manganese Selenium Sulfate Dissolved Solids, Total _ 10/21/2021 73 ' Z 1j A _,;� •i. c s•:'r_ �i..r �- "'•--�_":• _ - `,ti;: r:` :^ :-..� .� - , C/ S! ' •I�' - �A��,I 7 s -8• �_ . - Figure 5 Surface Water Sampling Results - October 2021 Edwards Road Landfill Permit #34-05 <0.5 <5.0 210 <1.0 6.3 <5.0 4Q000 200,000' Manganese 12 _ Manganese 20 ` Selenium < 5.0 -' Selenium <5.6 .�Q R.J. Reynolds Tobacco Co. m Sulfate 46 000 �.' f � y. •: Sulfate 9,000 E' ' Dissolved Solids, Total 83 000 Dissolved Solids, Total 220,000 Rural Halle North Carolina �' 1:7,200 a 1 inch = f00 feet N 1;. u f ❑ '. .. - .... E' s 0 300 600 900 ° ERM NC, Inc. i Feet O a :.. p o ERM www.erm.com 1Source: NCOneMap Data Services (Imagery, parcels), Forsyth County GIS Data Download (Streets, buildings) NCDOT GIS Unit Coordinate System: NAD 1983 StatePlane North Carolina RIPS 3200 Feet :es: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO, USGS, FAO, NIPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance Survey, Esri Japan, METI, Esri China (Hong Kong), (c) OpenStreetMap contributors, and the GIS User Community Sulfate Concentrations - Most Recent n Monitorinq Wells Piezometers Date Sulfate u IL P W-01 10/20/2021 670,000 W-01 10/21/2021 1,100, 000 W-03 10/20/2021 120,000 W-03B 10/20/2021 14,000 W-06 10/21/2021 10,000 W-07 10/21/2021 12,000 W-08 10/20/2021 19,000 W-09 10/20/2021 12,000 Date Sulfate u IL PZ-01 03/07/2016 110,000 PZ-02 09/23/2020 24,000 PZ-04 04/01/2020 37,000 PZ-05 04/06/2021 19,000 NC Groundwater & Surface Water Standard = 250,000 ug/L Previous sample collected from PZ-03 = 18,000 ug/L. See tables and appendices for additional results. o� 00 + 1 .,r 1,4{ U), % 4 - Lu - &,SS-50 (1,100) ' . > R. J. Reynolds Surface Water Date Sulfate u IL SS-01 10/21/2021 40,000 SS-02 10/21/2021 50,000 SS-20 10/21/2021 9,200 SS-25 10/21/2021 9,000 SS-30 10/21/2021 48,000 SS-35 09/08/2015 170,000 SS-40 10/21/2021 50,000 SS-50 10/21/2021 1,100 SS-60 10/21/2021 13,000 SS-65 09/08/2015 44,000 SS-70 10/21/2021 53,000 SS-75 09/08/2015 41,000 SS-80 10/21/2021 60,000 SS-90 10/21/2021 29,000 SS-95 02/24/2020 160,000 I Lel El oA_ o l000 Boyd Z ' 000 900 \ � y •{; Johnston L a''r� �SS-80 (60,000) i SS-90 (29,000 Q W-08 (19,000) SS-40 . ¢ (50,000(125000) 4SS-60 - ' ■ (135000) ��� ■ , �; Payne �► y � jli; SS-02 �. (505000) T ° -- �� - R. J. ` ^-r e W-01 / Guthrie SM.ii � _.t . 4 - Reynolds y 0PW-01 Q(1,100,000) (670,000) �00� O W-06 ��oSprinkle (10,000) P r W-03 ' (1201000),W-03B - • d , 'y' (14,000) Freeman 1 SS-01 , Phipps . F (40,000) was �SS-20 4SS-25 O W-09 . (9,200) (9,000) (12,000) `Phipps''' O SS-30 Ken Stewart J 0 �(48,000)-� Ken Stewart Don` A Don StewartAstewart �`Mozelle -----DaveStewart Hawks Stewart\ . Freedom . 006 , Baptist Church Freedom Baptist Church Friergon I � N N �!� ea ISO X �I r U� Ruiai Hall Legend ! Q Saprolite/PWR Monitor Well ';. Q Bedrock Monitor Well O Abandoned Monitor Well Piezometer 0 Soil Boring/Piezometer 4 Surface Water Water Supply Well Streams As -Built Landfill Contours (20') compliance Boundary _ "Limits of Permit 0 Parcels Sulfate Isoconcentration Contours > 250,000 ug/L > 750,000 ug/L Notes 1. Contour interval is 20-ft. 2. Limits of landfill are approximate based on ;g 71, .#J+ available historic data. 3. Streams estimated based on NC Floodplain Kitchens Mapping Program, 2008 .+ 4. 120 - Result exceeds applicable standards. 5. All concentrations in micrograms per liter (ug/L) X i000 O • �' a RU N 1:7,200 1 inch & 0 feet m sao+ �� NqQ� • 1. W 0 300 600 soo ir, NTpN Rc Feet-:wc O .. 6 . - 9°0 Source: NCOneMaD Data Services (Imaaerv. Darcels). Forsvth Countv CIS Data Download (Streets. buildings) Sources: Esri. HERE. Garmin. IntermaD. increment P Coro- GEBCO. USGS. FAO. NPS. NRCAN. GeoBase. IGN. Kadaster NL. Ordnance Survev. Esri Jaoan. METL Esri China (Hong Kona). (c) ODen StreetMaD contributors. and the CIS User Communitv Figure 6 Sulfate Isocontour Map Groundwater Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina ERM NC, Inc. �d www.erm.com ERM A 1000 950 900 850 800 750 700 a� W 650 600 550 500 450 400 0 Svnthetic Cap Installation 125 250 375 500 625 750 875 1000 1125 1250 1375 1500 1625 1750 1875 2000 2125 2250 2375 2500 2625 2750 2875 3000 N r 1-J - i r— W8 \ Ass 170 PZA O PZ 2 pOSssno ~J W1 ss-75 OW ssBU PZ-5 ♦� /\ ss Sj, PZ-1( ^r J t 1 j ss 35 ss-02 V w`, — w-2 i PW-1 W., SS01+850 W J W 6 O - r w • ss-o1s50 1 W_3 ' , , ss.95 W.3B B$ 55-01+,50 , y� 55-01 Q i B-,2+ref25'4 *own ss-20 / W 9 � f} � O IL1f 0 325 650 I` A' \ Feet w-s ss 30; _,sin_ -k O Saprolite/PWR Monitor Well O Bedrock Monitor Well A, Piezometer 0 Soil Boring/ Piezometer 51 Soil Boring 4 Surface Water Regional Groundwater Flow OwCompliance Boundary Limits of Permit Sulfate Concentrations - Most Recent Monitoring Wells Piezometers Date Sulfate (ug/L) PW-01 10/20/2021 670,000 W-01 10/21/2021 1,100,000 W-03 1 10/20/2021 120,000 W-03B 10/20/2021 14,000 W-06 10/21/2021 10,000 W-07 10/21/2021 12,000 W-08 10/20/2021 19,000 W-09 10/20/2021 12,000 Date Sulfate (ug/L) PZ-01 03/07/2016 110,000 PZ-02 09/23/2020 24,000 PZ-04 04/01/2020 37,000 PZ-05 04/06/2021 19,000 NC Groundwater & Surface Water Standard = 250,000 ug/L. Previous sample collected from PZ-03 = 18,000 ug/L. See tables and appendices for additional results. Surface Water Date Sulfate (ug/L) SS-01 10/21/2021 40,000 SS-02 10/21/2021 50 000 SS-20 10/21/2021 9,200 SS-25 10/21/2021 9,000 SS-30 10/21/2021 48,000 SS-35 09/08/2015 170,000 SS-40 10/21/2021 50,000 SS-50 10/21/2021 1 100 SS-60 10/21/2021 13,000 SS-65 09/08/2015 44,000 SS-70 10/21/2021 53,000 SS-75 09108/2015 41000 SS-80 10/21/2021 60 000 SS-90 10/21/2021 29 000 SS-95 0212412020 160 000 A' Local Groundwater 1000 Flow Local Perched 950 _ -� Water Flow Bedrock Fracture 900 Water Level Well Details ' 850 Casing 800 Screen Subsurface Details 750 L Landfill 700 Confining Unit Sap rolite 650 Bedrock Bedrock 600 = 550 = 500 450 - 400 Notes: 1. ? - Estimated /Assumed 2. Vertical Exaggeration = 2:1 4. 1 inch = 250 feet 3. 120 - Result exceeds applicable standards. 4. All concentrations in micrograms per liter (ug/L) Figure 7 Hydrogeologic Conceptual Model Edwards Road Landfill Permit #34-05 R.J. Reynolds Tobacco Co. Rural Hall, North Carolina Environmental Resources Management www.erm.com ERM vstem: NAD 1983 StatePlane North Carolina FIPS 3200 Feet ug/L MONITORING WELL W-1 AMSL 4,500,000 815 SAPROLITE AQUIFER Synthetic cap 4,000,000 installed 3Q2012 814 3,500,000 813 812 3,000,000 811 2,500,000 810 2,000,000 809 1,500,000 808 1,000,000 807 500,000 806 0 805 ^°e°°°o 141ft U91L MONITORING WELL W-36 AMSL 1,200,000 1,000,000 800,000 600,000 400,000 200,000 0 a� 05 0`' o� o° ^5 �`' N" 11 �° ryo tio no yo tio ryo �o yo If, "9& MONITORING WELL W-8 350,000 300,000 250,000 200,000 150,000 100,000 50,000 0 �O 810 809 808 807 806 805 804 803 802 801 ug/L MONITORING WELL W-2 AMSL ug/L MONITORING WELL W-3 AMSL 4,000,000 V Synthetic cap 818 1,600,000 � SAPROLITE / PWR AQUIFER Synthetic 805 cap 3,500,000 + . ,installed 3Q2012 816 1,400,000 installed 3Q2012 804 814 803 3,000,000 1,200,000 812 802 2,500,000 1,000,000 810 801 2,000,000 800,000 808 800 1,500,000 600,000 806 799 1,000,000 400,000 804 798 500,000 802 200,000 797 0 800 0 796 '`0j°0 °°o ° °°!x °�o °°0 °,�o °,�`L °^P °,�0 °,�0 °ryo °�`L °°o °°`L �o'oP ^9°`L ^°9� ���6 ��°o NO �o'� ��°0 ^�C0 � BACKGROUND MONITORING WELL W-4 & W-6 AMSL ft "� MONITORING WELL W-7 ft AMSL 800,000 888 Synthetic cap - 250,000 700,000 installed 3Q2012 886 200,000 600,000 884 500,000 882 150,000 400,000 880 300,000 100,000 878 200,000 50,000 100,000 876 841 840 839 838 837 836 835 834 833 0 874 0 1 832 ^h ° o �° �° �9 ,yo tio no ryo ,yo tio ,yo ryo ryo tio tioti "WL MONITORING WELL W-9 350,000 SAPROLITF AQUIFFR 300,000 Synthetic cap installed 3Q2012 250,000 200,000 150,000 100,000 50,000 0 10 �O �O T �O ry0 If, LEGEND NC21- GW STD NC213 SW STD Sulfates 250,000 ug/L 250,000 ug/L ❑ Total Dissolved Solids 500,000 ug/L 500,000 ug/L Groundwater Table Elevation (above Mean Sea Level) fl AMSL 812 810 808 806 804 802 800 798 ft AMSL "� MONITORING WELL PW-1 ft AMSL 810 3,500,000 BEDROCK AQUIFER 866 808 3,000,000 Synthetic cap installed 3Q2012 _ 864 862 806 2,500,000 mi mm 860 804 2,000,000 858 802 1,500,000 856 800 1,000,000 854 798 500,000 852 796 0�q 850 _p sp ' 0 Nt^ N1b No °Q11 °^° °0 ug/L SURFACE WATER SS-01 1,400,000 1,200,000 1,000,000 800,000 600,000 400,000 200,000 0 000°j 900^Ory 909b 0y 06079000000'�Ory O^�Ob Oy 00 O'�000°j r�0,.'�r�`L ^"u r�D, ,`5^6 ^'�,�O ,�9 ry0 r1,'�r� �O ^9 ,�0 ^O ^O ^9 ^O ^O ^9 ^9 ^9 ^O ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ug/L SURFACE WATER SS-30 400,000 350,000 300,000 250,000 200,000 150,000 100,000 50,000 0 O00 OHO Off^ O^`L O�'h Orb O�5 Or�O O�'1 O^0 Or�O OHO O��. Or1`L ry ry ry ry ry ry ry ry ry ry ry ry ry ry ug/L 250,000 200,000 150,000 100,000 50,000 0 SURFACE WATER SS-70 Synthetic cap installed 3Q2012 � Y ug/L SURFACE WATER SS-02 1,000,000 900,000 800,000 700,000 600,000 500,000 400,000 300,000 200,000 100,000 0 �900 �o9ry ^9 ^oa�O �000 ry000 ry00ry ry0� ry006 ry00a ry0^O ryo^ry ryo^� ryo^0 ryo^e ryoryo ryoryry ug/L SURFACE WATER SS-40 800,000 Synthetic cap 700,000 installed 3Q2012 600,000 500,000 400,000 300,000 -- \ V / 200,000 100,000 0 ry0 ry0 ry0 ry0 ry0 ry0 ,y0 ry0 ry0 ry0 ry0 ry0�' ry0�' ry0� ug/L 300,000 250,000 200,000 150,000 100,000 50,000 oe o ^ry ry0 ry0 ry0 ry0 �o K�� 11 ry0 ,y0 ry0 ry0 ry0 �ro e o ,y0 ry0 ry0�' ry0�' ry ,y0�' LEGEND NC21- GW STD NC213 SW STD Sulfates 250,000 ug/L 250,000 ug/L 0 Total Dissolved Solids 500,000 ug/L 500,000 ug/L 0 000 OHO Off^ ONry ONO ON" OHO OHO O^'` 0N0 O-�i OHO Off'^ O�`L ry ry ry ry ry ry ry ry ry ry ry ry ry ry SURFACE WATER SS-80 ug/L SURFACE WATER SS-25 180,000 160,000 Synthetic installed cap 3Q2012 140,000 120,000 100,000 80,000 60,000 40,000 20,000 0 yo ryo ryo ryo ^6 N �O ^O ry0 ryN ryo ryry ryo ryo ryo yo ryo ryo ryo yo ryo ug/L SURFACE WATER SS-60 800,000 Synthetic cap 700,000 installed 3Q2012 600,000 500,000 400,000 - 300,000 - 200,000 � 100,000 0 ry0 ry0 ,y0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ry0 ug/L SURFACE WATER SS-90 600,000 Synthetic cap 500,000 installed 3Q2012 400,000 300,000 200,000 100,000 0 ,,N �ry �� � �h �6 o �9 0 ry0 ry0 ry0 � ry0 ry0 ry0 10 ,LO^_p ry0�' TABLE 1 MONITOR WELL CONSTRUCTION DETAILS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 1 Depth to Outer Ground TOC Ground- Boring Casing Screened Geologic Well Install Elevation Elevation water (ft Depth Depth Interval Zone ID Date Latitude Longitude (ft MSL) (ft MSL) BTOC) (ft BGL) (ft BGL) (ft BGL) Screened Comments 405 Former supply well, pump removed (8/09): 6 inch dia. gals. casing; Construction details per (son Clayton Well Drilling log and video inspection by ERM (8/09 & 4/10); Open rock to 405 ft, Total PW-1 5/26/87 36.2499455' -80.2779362' 920.51 920.66 65.49 21.5 21.5-405 Bedrock well yield 25 gpm with no other obvious water -bearing zones below 103 ft (Clayton). Silted in to bottom at 326) NA 10-20 326 ft (video). W-1 10/13/87 36.2500121' -80.2757441° 819.69 822.68 15.18 20.5 Saprolite 2 inch dia. PVC, Well replaced 11/93, DWM permit -required sample location W-2 12/6/89 36.2504070' -80.2753700' 824.21 827.30 17.01 17 NA 7-17 Sap/PWR 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs MW-1A, RH-MW-002) W-3 12/7/89 36.2486237' -80.2761346' 802.00 804.43 4.20 17 NA 7-17 Sap/PWR 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs W-3A, W-2A, RH-MW-003) W-3B 5/14/04 36.2485693' -80.2761875' 801.23 804.32 Artesian 210 Unknown 190-210 Bedrock 2 inch dia. PVC, DWM permit -required sample location, Artesian well W-4 6/8/93 36.24693455° " -80.28491769° � NE NE 24 NA NA 138-188 Bedrock 2 inch dia. PVC, damaged, abandoned 8127103, former background well, replaced with W-6in 2003. W-5 5/17/93 36.24629033°' -80.27862892° " NE NE NM 13-23.5 Bedrock 2 inch dia PVC, Phase 3 permanent MW 2 inch dia. PVC, DWM permit -required sample location, (alternate IDs MW-6), current W-6 8/22/03 36.2490276' -80.2819968° 977.93 980.71 99.51 200 NA 170-200 Bedrock background well, replaced W-4 as background well in 2003 W-7 12/15/10 36.2517944' -80.2798058' 929.51 931.58 95.23 341 NA 42-341 Bedrock 6 inch dia. open -rock hole, 6" galavanized casing to 42 ft bgs, TOC value for 6" casing W-8 12/14/10 36.2524760' -80.2744895' 859.39 861.67 58.22 129 NA 45-65 PWR 2 inch dia. PVC W-9 12/13/10 36.2469581 ° -80.2750675' 909.35 911.38 110.50 259 NA 229-259 Bedrock 2 inch dia. PVC, Ken Stewart's pasture, B-9 5/20/93 NM 23 NA 2 inch dia PVC, Phase 3 temporary piezometer, no protective well box around well 36.24819778' " -80.28420462° " NE NE 18-22.5 Saprolite B-10 5/19/93 36.24815194' ' -80.28243419° " NM NA 9-13.5 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, not located October 2009 B-11 5/20/93 36.24695712' " -80.28385595° " NE NE NM 54 NA 48-53 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, no protective well box around well B-12 5/19/93 36.24765518' " -80.28079913' " NE NE NM 8.5 NA 3.5-8 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, no protective well box around well B-14 5/20/93 36.2461299° ` -80.28188639° " NE NE NM 54 NA 48-53 Saprolite 2 inch dia PVC, Phase 3 temporary piezometer, no protective well box around well PZ-1 3/15/16 36.25134616' " -80.2740505° " NE NE NM 1.5 NA 1.0 - 1.5 Alluvium 1 inch dia PVC temporary piezometer. Originally installed 12/2010. Replaced 3/2016 PZ-2 12/15/10 36.25229952' " -80.27330537' " NE NE NM 4.0 NA 3.0 - 4.0 Alluvium 1 inch dia PVC temporary piezometer PZ-3 12/15/10 36.25292715' " -80.27477259' " NE NE NM 1.5 NA 0.5 - 1.5 Alluvium 1 inch dia PVC temporary piezometer PZ-4 12/16/10 36.25225065' " -80.27644449' " NE NE NM 5.0 NA 4.2 - 5.0 Alluvium 1 inch dia PVC temporary piezometer PZ-5 12/16/10 36.25178958' " -80.27767072' " NE NE NM 5.0 NA 3.0 - 5.0 Alluvium 1 inch dia PVC temporary piezometer NE - Not Established BGL - Below ground level MSL - above mean sea level BTOC - Below top of casing NM - Not Measured PWR = Partially Weathered Rock - Estimated value Survey data by Lawrence Associates, P.A., January 4, 2010, January 4, 2011 & February 28, 2011 RJR71Tables RJRT Ash LF.xlsxl f. Well Construction TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 3 Monitor Well ID PW-01 W-01 W-02 W-03 W-03B W-05 W-06 TOC Elevation 920.7 822.7 827.3 804.4 804.3 980.7 Start Screen Depth 21.5 10 7 7 190 13 170 End Screen Depth 405 20 17 17 210 23.5 200 Geologic Unit Bedrock Saprolite Saprolite/PWR Saprolite/PWR Bedrock - Artesian Bedrock Bedrock Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 11.59 811.09 13.32 813.98 7.54 796.89 Artesian 99.00 881.71 2007-04-27 10.88 811.80 13.96 813.34 6.98 797.45 Artesian 94.48 886.23 2007-11-19 13.29 809.39 16.08 811.22 7.78 796.65 Artesian 105.00 875.71 2008-04-30 12.84 809.84 14.68 812.62 7.04 797.39 Artesian 99.29 881.42 2009-04-30 -- 13.23 809.45 15.18 812.12 7.12 797.31 Artesian 98.28 882.43 2009-10-12 72.00 848.66 14.53 808.15 17.50 809.80 7.63 796.80 -1.22 805.54 10.08 99.64 881.07 2010-04-19 67.00 853.66 10.75 811.93 14.16 813.14 6.37 798.06 -1.05 805.37 8.38 98.29 882.42 2010-10-11 12.04 810.64 15.85 811.45 6.99 797.44 -0.89 805.21 9.73 98.93 881.78 2011-01-05 11.97 810.71 13.53 813.77 6.88 797.55 -0.98 805.30 9.67 98.92 881.79 2011-02-28 65.30 855.36 11.66 811.02 14.57 812.73 6.65 797.78 -1.37 805.69 9.50 99.01 881.70 2011-04-20 64.75 855.91 10.92 811.76 14.05 813.25 6.25 798.18 -1.63 805.95 7.85 98.42 882.29 2011-10-17 12.55 810.13 15.18 812.12 7.24 797.19 -1.36 805.68 99.41 881.30 2012-02-06 64.96 855.70 11.97 810.71 13.52 813.78 6.52 797.91 Artesian 99.22 881.49 2012-03-16 11.95 810.73 15.45 811.85 6.64 797.79 Artesian 99.05 881.66 2012-09-24 66.03 854.63 11.93 810.75 15.36 811.94 4.87 799.56 Artesian 99.63 881.08 2013-04-17 65.80 854.86 11.98 810.70 14.03 813.27 4.51 799.92 Artesian 99.04 881.67 2013-09-10 66.75 853.91 13.01 809.67 15.75 811.55 3.45 800.98 Artesian 98.86 881.85 2014-04-07 56.15 864.51 11.74 810.94 16.76 810.54 3.29 801.14 Artesian 98.23 882.48 2014-09-03 67.28 853.38 14.37 808.31 16.65 810.65 3.29 801.14 Artesian 98.93 881.78 2015-04-02 64.75 855.91 13.29 809.39 13.93 813.37 3.78 800.65 Artesian 99.45 881.26 2015-09-08 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 2015-09-10 65.49 855.17 15.18 807.50 17.01 810.29 4.20 800.23 Artesian 99.51 881.20 2016-03-08 62.75 857.91 12.42 810.26 13.32 813.98 2.80 801.63 Artesian 98.62 882.09 2016-09-06 67.21 853.45 14.92 807.76 16.68 810.62 3.31 801.12 Artesian 98.90 881.81 2017-03-27 65.34 855.32 15.50 807.18 15.33 811.97 3.89 800.54 Artesian 99.10 881.61 2017-09-25 65.50 855.16 16.02 806.66 16.89 810.41 3.32 801.11 Artesian 99.68 881.03 2018-03-05 66.00 854.66 16.10 806.58 11.90 815.40 4.45 799.98 Artesian 99.94 880.77 2018-09-12 65.44 855.22 15.88 806.80 16.95 810.35 4.24 800.19 Artesian 100.05 880.66 2019-03-19 61.00 859.66 11.20 811.48 6.23 821.07 1.88 802.55 0.00 804.32 2019-03-20 -- -- -- -- -- -- -- -- -- -- 98.59 882.12 2019-09-03 65.50 855.16 15.05 807.63 16.23 811.07 3.19 801.24 0.00 804.32 99.46 881.25 2020-02-13 67.61 853.05 10.31 812.37 5.03 822.27 2.98 801.45 0.21 804.11 93.41 887.30 2020-02-24 66.70 853.96 12.81 809.87 6.13 821.17 3.38 801.05 0.20 804.12 99.13 881.58 2020-03-04 66.82 853.84 12.29 810.39 6.29 821.01 3.43 801.00 0.21 804.11 99.14 881.57 2020-03-31 66.38 854.28 13.28 809.40 13.23 814.07 3.43 801.00 1.05 803.27 99.00 881.71 2020-09-22 67.42 853.24 15.02 807.66 15.38 811.92 3.81 800.62 0.50 803.82 100.05 880.66 2021-04-05 63.90 856.76 11.65 811.03 9.64 817.66 2.35 802.08 0.20 804.12 99.60 881.11 2021-10-20 66.89 853.77 16.21 806.47 17.58 809.72 4.86 799.57 100.44 880.27 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 3 Monitor Well ID W-07 W-08 W-09 B-09 B-12 PZ-06 PZ-07 TOC Elevation 931.6 861.7 911.4 834.3 833.7 Start Screen Depth 42 45 229 18 3.5 1.5 1.5 End Screen Depth 341 65 259 22.5 8 3.5 4.5 Geologic Unit Bedrock PWR Bedrock Saprolite Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 -- -- -- -- -- -- -- -- -- -- 2007-04-27 -- -- -- -- -- -- -- -- -- -- 2007-11-19 -- -- -- -- -- -- -- -- -- -- 2008-04-30 -- -- -- -- -- -- -- -- -- -- 2009-04-30 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 20.40 10.26 -- -- -- -- -- -- -- -- 18.78 6.18 -- -- -- -- -- -- -- - 21.63 9.40 -- -- 2011-01-05 94.73 836.85 52.67 809.00 110.47 800.91 22.05 9.05 2011-02-28 94.59 836.99 53.45 808.22 112.03 799.35 22.63 -- 2011-04-20 94.20 837.38 53.54 808.13 110.03 801.35 21.45 5.46 2011-10-17 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 2012-02-06 94.71 836.87 54.74 806.93 109.84 801.54 2012-03-16 -- -- -- -- -- -- -- -- -- -- -- -- -- 2012-09-24 96.05 835.53 55.47 806.20 110.26 801.12 2013-04-17 95.80 835.78 57.40 804.27 108.62 802.76 2013-09-10 94.71 836.87 54.20 807.47 110.23 801.15 2014-04-07 95.26 836.32 54.01 807.66 110.86 800.52 2014-09-03 94.90 836.68 52.78 808.89 110.68 800.70 2015-04-02 94.52 837.06 56.22 805.45 110.50 800.88 2015-09-08 -- -- 58.22 803.45 110.50 800.88 2015-09-10 95.23 836.35 -- -- -- -- 2016-03-08 93.95 837.63 59.01 802.66 110.06 801.32 2016-09-06 94.05 837.53 53.19 808.48 110.11 801.27 2017-03-27 94.41 837.17 56.00 805.67 109.90 801.48 2017-09-25 95.01 836.57 56.96 804.71 109.30 802.08 2018-03-05 94.60 836.98 60.60 801.07 110.30 801.08 2018-09-12 94.83 836.75 61.60 800.07 110.33 801.05 2019-03-19 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 2019-03-20 92.07 839.51 58.35 803.32 110.06 801.32 2019-09-03 92.98 838.60 52.28 809.39 109.54 801.84 2020-02-13 91.72 839.86 53.37 808.30 -- -- Dry Dry 2020-02-24 92.25 839.33 53.45 808.22 D -- D -- 2020-03-04 92.23 839.35 53.49 808.18 -- -- 8.87 825.40 9.69 824.01 2020-03-31 91.81 1 839.77 52.99 808.68 110.00 801.38 8.84 825.43 9.39 824.31 2020-09-22 92.60 838.98 51.12 810.55 100.00 811.38 -- -- -- 2021-04-05 89.00 842.58 49.22 812.45 100.00 811.38 2021-10-20 93.03 838.55 50.02 811.65 110.43 800.95 TABLE 2 GROUNDWATER ELEVATIONS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Monitor Well ID TOC Elevation Start Screen Depth End Screen Depth Geologic Unit PZ-08 PZ-09 PZ-10 830.7 834.6 839.9 2 1.5 1 5 4.5 4 Fill Soil/Saprolite Fill Soil/Saprolite Fill Soil/Saprolite Date Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) Depth to Water (ft BTOC) Groundwater Elev (ft MSL) 2006-10-19 2007-04-27 2007-11-19 2008-04-30 2009-04-30 2009-10-12 2010-04-19 2010-10-11 2011-01-05 2011-02-28 2011-04-20 2011-10-17 2012-02-06 2012-03-16 2012-09-24 2013-04-17 2013-09-10 2014-04-07 2014-09-03 2015-04-02 2015-09-08 2015-09-10 2016-03-08 2016-09-06 2017-03-27 2017-09-25 2018-03-05 2018-09-12 2019-03-19 2019-03-20 2019-09-03 2020-02-13 Dry Dry D -- 2020-02-24 Dry Dry 9.25 830.64 2020-03-04 Dry Dry 8.64 831.25 2020-03-31 Dry Dry 8.70 831.19 2020-09-22 2021-04-OS 2021-10-20 Notes: NE = Not Established MSL = above mean sea level BTOC = Below Top of Casing PWR = Partially Weathered Rock BGL - Below ground level Artesian condition - Value represents water level above permanent TOC. Measured via temporary standpipe installed on permanent casing. Page 3 of 3 TABLE 3 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA 1 of 1 N Sample Sample Date m to Location/ID E E _ d E c E ' _ m > d m > E E -0 O C M C N w N R 3 Q m U L) N J O 5 0) fq N a H NC 2L Groundwater Standard 3,500 700 2 10 300 15 50 20 250,000 500,000 NC 2B Surface Water Standard 8,000 21,000 0.3 50.1 1,000 1.49 100 5 250,000 500,000 Groundwater Monitoring Wells PW-01 10/20/2021 670,000 1,600,000 W-01 10/21/2021 41 22 < 0.5 < 5 290 < 1 3,600 22 1,100,000 2,200,000 W-03 10/20/2021 < 40 34 < 0.5 < 5 < 50 < 1 120 < 5 120,000 370,000 W-03B 10/20/2021 < 40 50 < 0.5 < 5 210 < 1 78 < 5 14,000 230,000 W-06 10/21/2021 320 61 < 0.5 10 540 < 1 16 < 5 10,000 260,000 W-07 10/21/2021 140 130 < 0.5 < 5 870 < 1 29 < 5 12,000 130,000 W-08 10/20/2021 400 150 < 0.5 12 680 < 1 15 < 5 19,000 96,000 W-09 10/20/2021 85 130 < 0.5 < 5 < 50 < 1 < 5 < 5 12,000 240,000 Surface Water SS-01 10/21/2021 84 73 < 0.5 < 5 210 < 1 6.3 < 5 40,000 200,000 SS-02 10/21/2021 77 S 76 < 0.5 < 5 200 < 1 7.7 < 5 50,000 220,000 SS-20 10/21/2021 170 38 < 0.5 < 5 480 < 1 27 < 5 9,200 82,000 SS-25 10/21/2021 120 37 < 0.5 < 5 360 < 1 12 < 5 9,000 83,000 SS-30 10/21/2021 140 60 < 0.5 < 5 430 < 1 20 < 5 48,000 220,000 SS-40 10/21/2021 83 74 < 0.5 < 5 200 < 1 8.5 < 5 50,000 230,000 SS-50 10/21/2021 1,300 170 < 0.5 < 5 25,000 6.5 710 < 5 1,100 72,000 SS-60 10/21/2021 61 64 < 0.5 < 5 210 < 1 11 < 5 13,000 92,000 SS-70 10/21/2021 80 73 < 0.5 < 5 170 < 1 7.5 < 5 53,000 230,000 SS-80 10/21/2021 85 76 < 0.5 < 5 200 < 1 15 < 5 60,000 240,000 SS-90 10/21/2021 53 65 < 0.5 < 5 140 < 1 5.4 < 5 29,000 140,000 Notes: All concentrations in micrograms per liter (pg/L) unless otherwise noted. NE - Not established No freshwater aquatic life standard established for barium, manganese, sulfate, and dissolved solids. Water Supply criteria presented. Bold with gray background indicates exceedance of applicable NC Groundwater or Surface Water Standard TABLE 4 GROUNDWATER AND SURFACE WATER FIELD PARAMETER RESULTS EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA E C o ` w � Sample m y °' w d> K O Location/ID Sample Date U j z a E R N L •� w O 16 N Z. •� > y E a y H° L) H O ao y o f NC 2L Groundwater Standard 6.5-8.5 NE NE NE NE NE NC 213 Surface Water Standard 1 6.0-9.0 NE NE NE NE NE Groundwater Monitoring Wells PW-01 10/20/2021 6.4 16.4 2020 0 36 0.71 W-01 10/21/2021 6.6 17.8 2.73 1.6 175 0.04 W-03 10/20/2021 6.0 17.4 614 0.6 322 0.25 W-03B 10/20/2021 7.6 17.1 369 0.4 -18 0 W-06 10/21/2021 9.8 15.8 434 10.2 22 1.32 W-07 10/21 /2021 6.3 15.9 186 8.5 206 4.12 W-08 10/20/2021 5.6 20.2 122 82.5 218 5.04 W-09 10/20/2021 11.1 18.0 7.39 0 -132 1 Surface Water SS-01 10/21/2021 7.8 15.5 338 215 212 6.02 SS-02 10/21/2021 7.8 14.5 358 7 191 7.5 SS-20 10/21/2021 7.6 16.4 127 600 181 7.35 SS-25 10/21/2021 7.5 15.7 129 17.1 177 6.64 SS-30 10/21/2021 7.9 15.4 431 44.7 183 6.2 SS-40 10/21/2021 7.8 15.0 364 3.2 193 6.72 SS-60 10/21/2021 7.6 14.5 150 0 198 6.6 SS-70 10/21/2021 7.8 14.6 364 20.2 200 6.3 SS-80 10/21/2021 7.8 14.3 413 3.1 196 6.52 SS-90 10/21/2021 7.6 14.3 235 0 208 6.12 Notes: SU - standard units uS/cm - microSiemens per centimeter NTUs - Nephelometric Turbidity Units my - millivolts mg/L - milligrams per liter NE - Not established No freshwater aquatic life standard established for barium, manganese, sulfate, and dissolved solids. Water Supply criteria presented. Bold with gray background indicates exceedance of applicable NC Groundwater or Surface Water Standard 1 of 1 APPENDIX A HISTORICAL GROUNDWATER AND SURFACE WATER QUALITY ANALYTICAL DATA www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 2021-10 Edwards Rd LF Rural Hall GW Report.docx APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 11 Sample P Location Date m a O _O z U E _ E 3 Q n Q L m E M U U .co C O U O = N J m 7 E d co co O N z y a z w w co c y G _ O H co = Om aco O H U C- N L m y? a1 0M d H E ` co v w _ O. O N U z �, _E j H _ o V c w r m x G O 0- d O v, N E C] NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-01 4/29/1988 -- 8,030 235 8 16 17,400 1,100 31 -- 130,000 156,000 2,240 5.9 -- -- -- -- -- W-01 7/13/1989 - -- 100 -- -- -- 5 -- -- -- -- -- -- -- - -- -- W-01 9/24/1990 - 5,620 189 8,900 150 59 - 13,500 185,000 13,000 6.27 19.3 195 - - - W-01 10/24/1991 - 161 346 150 97 23.9 - 126,000 303,000 12,000 6.24 20.3 425 - - - W-01 3/26/1992 - 2,850 736 833 1,830 0.32 21.9 38 -- 123,000 482,000 14,000 6.62 9.3 682 - - - W-01 9/30/1992 - -- 120 -- 310 32 -- 292,000 798,000 5,000 5.87 17.8 1,153 -- - - W-01 3/31/1993 - 364 137 1,130 2,230 13.2 33 -- 486,000 1,169,000 33,000 5.49 16.1 1,587 - - - W-01 9/17/1993 - 28,600 697 3.8 44 59,700 13 3,490 5.1 195 - 565,000 1,643,000 6,000 5.93 18 2,310 -- - - W-01 3/30/1994 - 5,320 545 20 18,800 8 505 6 107 -- 633,000 1,680,000 -- 5.63 15.2 1,250 -- - - W-01 9/30/1994 1,810 22 9,960 4,470 13 19 -- 758,000 2,420,000 123,000 6.02 18.1 3,010 - W-01 3/31/1995 - 24,000 1,250 26 53,900 11 1,580 12 115 -- 797,000 2,140,000 -- 5.89 15.8 2,820 - - - W-01 9/29/1995 - 7,650 367 4 24 18,800 10 4,020 12 -- -- 464,000 2,780,000 4,040 4.49 16.2 3,720 - - - W-01 3/20/1996 - 149,000 960 50 200 220 -- 63 11,400 695 -- 2,320,000 2,670,000 8,750 6.48 15 3,060 - - - W-01 9/27/1996 - 7,110 22,600 7 2,300 51 -- 1,320,000 2,970,000 3,810 6.09 19 3,350 - - - W-01 3/29/1997 - 2,990 -- 16 2,340 72 -- 1,360,000 2,860,000 6,870 6.01 14 1,890 -- - - W-01 9/17/1997 - 2,940 3 12,900 6 3,680 33 136 - 1,300,000 3,110,000 5,290 6.3 17 3,540 -- - - W-01 3/27/1998 - 2,400 7,830 2,340 16 -- 1,060,000 3,040,000 3,640 6.49 19.6 627 - -- -- W-01 9/30/1998 - 2,350 5,180 15 2,710 21 - 1,030,000 3,210,000 17,500 6.2 20 1,250 - 6.36 20.8 W-01 9/30/1998 - 1,250 4,980 2,720 30 - 1,040,000 3,320,000 9,250 -- -- -- - -- -- W-01 3/31/1999 - 1,820 4,690 10 2,450 15 -- 1,830,000 3,230,000 8,820 5.6 17 1,610 - - -- W-01 (FD) 3/31/1999 - 1,170 4,200 2,560 18 -- 1,920,000 3,230,000 3,730 -- -- -- - - - W-01 9/29/1999 - 1,650 4,780 8 2,790 31 -- 2,060 3,440,000 3,730 5.71 19 1,980 - - - W-01 3/16/2000 - 1,820 3,360 6 2,840 31 -- 1,390,000 3,330,000 3,930 -- -- -- -- - - W-01 9/15/2000 979 3,200 8 2,930 22 -- 1,540,000 3,480,000 13,300 5.82 18 1,040 -- - - W-01 3/23/2001 - 226 1,860 10 3,180 - 1,260,000 3,320,000 6,130 6.2 17 1,090 -- - - W-01 10/4/2001 - 728 2 3,140 9 2,890 37 -- 1,420,000 3,380,000 31,000 8 21 3,300 -- - - W-01 3/28/2002 - 1,010 20 3,600 8 3,270 - 48 -- 1,220,000 3,310,000 3,430 6.04 15 1,090 -- - - W-01 (FD) 3/28/2002 - 5,450 3,580 - -- 1,050,000 2,920,000 3,430 6.04 15 1,090 -- - - W-01 10/3/2002 8,960 2 14,000 8 3,910 51 -- 1,330,000 3,210,000 3,190 6.33 18 1,280 - - - W-01 3/25/2003 - 1,420 2,770 7 3,540 25 -- 1,130,000 3,310,000 3,210 6.43 19 910 -- - - W-01 10/2/2003 - 402 414 2,330 5 3,840 - 1,350,000 3,470,000 3,520 5.94 20 3,210 -- - - W-01 4/28/2004 - 1,440 6,890 12 3,920 -- 1,350,000 3,580,000 5,130 -- 15.1 3,670 -- - - W-01 10/26/2004 - 7,450 21 20,100 10 4,800 - 1,310,000 3,630,000 3,100 - -- 3,510 - W-01 4/27/2005 - 697 2 3,990 10 4,080 -- 1,820,000 3,601,000 3,450 - -- 3,610 - W-01 10/20/2005 - 9,030 283 18,400 15 3,920 104 -- 790,000 3,520,000 52,000 - - 2,370 - - - W-01 10/19/2006 - 214 926 6 4,160 56 -- 1,790,000 3,310,000 3,740 - - 2,120 - - - W-01 4/27/2007 - 787 1,250 3,550 -- 1,300,000 3,390,000 6,350 - - 4,510 - - - W-01 11/19/2007 - 186 778 4,080 -- 1,950,000 3,430,000 3,950 - - 3,460 - - - W-01 4/30/2008 - 291 536 3,870 -- 1,920,000 3,410,000 2,990 - - 3,590 - - - W-01 (FD) 4/30/2008 - 349 698 3,910 -- 1,860,000 3,380,000 2,850 - - 3,600 - - - W-01 10/29/2008 - 25.8 0.32 427 4.9 3,990 - 1,640,000 3,310,000 4,950 - - 3,840 - - - W-01 4/30/2009 - 30.5 3.44 4.9 599 13.1 4,560 1.44 -- 1,890,000 3,370,000 6,060 - - 3,860 - -- - W-01 10/12/2009 - 98 J 2.9 J 22 J 1 2 J 1.1 410 4,000 0.5 J 280 1,500,000 3,100,000 -- 6.1 14.93 4,620 14 87 3.32 W-01 4/20/2010 - 3,500 130 12 6,000 4,200 -- 1,500,000 3,100,000 56,500 6.1 16.5 11,800 57.9 119 W-01 10/11/2010 - 63 J 6.7 27 0.9 J 300 1.3 J 5,000 33 1.3 J 12 780 1,400,000 3,100,000 -- 6.12 20.43 2,990 110 147 W-01 4/22/2011 - 470 6.8 43 15 2,900 4,800 30 530 1,300,000 3,000,000 3,400 6.15 13.13 2,780 406 150 0.58 W-01 10/17/20111 1,550 66.2 51.7 2,640 4,400 1,150,000 2,620,000 25,700 6.67 20.14 3,740 73 130 0.64 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 11 Sample P Location Date 0)m a E .�+ fV n O O z U E E O Q t� r- N L Q 'i @ 00 E _7 E 'O M U O L L U L O Q O U C O M y J a' C u L a1 E 3 d d to d > to V O N z y R L �= z d '� 7 cn c y 0 �_ w .- O O H fn = O w L O M H U co 2 a N L m y d ` E d 0 H E ` 0) v w .2 3 O. O N U z �, y 3 H _ o C> c r+ f m 1C O O CL d O v°, N NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-01 3/16/2012 -- 24.4 4,480 6.8 270 1,190,000 3,860,000 21,700 6.24 18.19 3,547 0.8 43.5 0.48 W-01 9/24/2012 - 279 32.2 494 4,580 450 1,500,000 2,890,000 -- 6.54 19.62 3,750 9.6 312 W-01 4/18/2013 - 501 35.2 692 4,590 357 1,380,000 2,610,000 23,500 6.3 17.49 3,354 8.03 -441.5 0.32 W-01 9/10/2013 - 117 34 290 4,920 -- 1,370,000 2,900,000 27,600 6.19 22.49 3,067 7.29 49.4 0.29 W-01 4/7/2014 156 - 24.8 - 360 4,750 - - - -- 1,160,000 2,850,000 32,300 6.22 11.9 3,406 7.87 374.4 1.46 W-01 9/4/2014 - - 5.9 297 4,600 - 61.2 - - -- 1,450,000 2,950,000 -- 6.15 19.97 2,940 6.1 83.7 0.75 W-01 (FD) 4/1/2015 - 126 - 21 -- 300 4,540 - 53.7 - - -- 1,210,000 2,710,000 -- -- -- -- -- -- -- W-01 4/3/2015 - 212 - 24.5 -- 500 5.3 4,510 - 50.4 - - -- 1,260,000 241,000 - 6.37 17.91 2,676 5.09 76.9 0.66 W-01 (FD) 4/3/2015 - 126 - 21 -- 300 4,540 - 53.7 - - -- 1,210,000 2,710,000 -- 6.37 17.91 2,676 5.09 76.9 0.66 W-01 9/10/2015 - 330 J - 38 1 J 0.88 J -- 850 4,900 - - - -- 1,200,000 2,700,000 E 6.37 22.97 3,220 0 225 1.13 W-01 3/8/2016 - -- 37 0.24 -- 2,000 5,300 - 28 - - -- 1,200,000 2,600,000 -- 6.35 20.5 3,176 8.29 63.1 0.38 W-01 9/8/2016 - -- 22 0.38 -- 1,400 4,800 - - - - 1,100,000 2,500,000 - 6.8 22.3 2,905 1.8 -1.5 0.8 W-01 3/29/2017 - 280 -- 39 -- 1,900 5,100 - 4.1 J - - -- 1,200,000 2,600,000 E 6.38 18.7 3,060 9.7 142.5 0.34 W-01 9/27/2017 - 190 B -- 32 -- 860 5,200 - - - -- 1,200,000 2,700,000 -- 6.44 22.9 3,020 5.6 139 0 W-01 3/6/2018 - 930 -- 56 1.8 J -- 7,200 2.4 4,700 - 5.6 - - -- 1,200,000 2,600,000 -- 6.59 12.7 3,182 28 260 0.38 W-01 9/12/2018 - - 26 - 920 5,200 - - - -- 1,200,000 2,700,000 -- 6.19 23.8 2,949 2.53 74.5 0.6 W-01 3/19/2019 - - 20 -- 1,300 3,100 - 11 - - -- 940,000 2,200,000 - 6.31 14.9 2,740 1.39 -109.6 0.67 W-01 9/3/2019 180 - 24 -- 340 3,800 - 14 - - -- 970,000 2,200,000 -- 6.11 20.8 2,553 5.63 -1.2 0.26 W-01 3/31/2020 - 180 - 29 -- 450 4,000 - 18 - - -- 970,000 2,200,000 -- 6.35 14.4 2,635 6.01 45.4 0.3 W-01 9/24/2020 - 73 - 24 -- 950 3,700 - 26 - - -- 1,000,000 2,400,000 - 6.62 16.5 2,517 4.56 -61.8 0.62 W-01 4/5/2021 400 S - 31 - 1,200 3,600 S 17 S - - -- 770,000 1,600,000 F 6.56 23.77 25,800 0 220 0.4 W-01 10/21/2021 - 41 -- 22 -- 290 3,600 -- 22 - - -- 1,100,000 2,200,000 -- 6.59 17.79 2.73 1.6 175 0.04 W-02 1 /16/1990 - -- 210 -- -- -- 0.2 - -- -- -- -- 6.1 -- -- -- -- -- W-02 9/24/1990 - 850 219 8.3 1,400 9,900 - - 41,000 533,000 14,000 6.17 16.7 717 - - - W-02 10/24/1991 - 169 82 9,300 7.4 16,500 - -- 1,150,000 1,937,000 15,000 5.97 18.7 2,080 - - - W-02 3/26/1992 - 2,790 3.4 38,400 16 -- - -- 1,860,000 2,611,000 12,000 5.83 13.8 2,880 -- - - W-02 9/30/1992 - -- -- 21,300 -- -- 1,320,000 2,525,000 6,000 6.06 17.9 2,670 -- - - W-02 3/31/1993 - 417 177 1,280 7.6 53 40 -- 600,000 948,000 2,000 5.64 15.2 167 - - - W-02 9/17/1993 - 5,650 508 3.8 79 34,700 12 22,300 62 -- 1,570,000 3,350,000 12,000 6.41 20.8 4,030 - - - W-02 3/30/1994 - 18,700 2,770 3 76 50,900 34 2,400 25 -- 200,000 555,000 -- 5.72 16 1,640 -- - - W-02 9/30/1994 - 21,400 942 37 58 362 13 3,710 88 -- 415,000 969,000 15,900 6.23 18.3 1,440 -- - - W-02 3/31/1995 - 45,000 1,710 78 58 5,050 28 3,660 172 - 155,000 460,000 -- 6.24 13.7 930 -- - - W-02 9/29/1995 - 109,000 3,950 30 209 142 206,000 68 3,750 5 292 -- 379,000 944,000 7,370 5.58 16.4 1,345 -- - - W-02 3/30/1996 - 66,500 1,250 12 105 78 96,600 44 3,610 183 -- 12,600 127,000 4,680 5.61 14 316 -- - - W-02 9/27/1996 - 89,100 1,510 8.8 150,000 15 3,060 98 -- -- 373,000 9,220 7.04 21 840 -- - - W-02 3/29/1997 - 64,400 1,100 20 102 72 98,000 47 2,500 150 -- 1,010,000 2,020,000 10,800 6.44 14 1,300 -- - - W-02 9/17/1997 - 56,500 1,620 13 87 88 99,900 35 20,200 201 - 1,410,000 3,600,000 11,300 6.6 17 3,780 - - - W-02 3/27/1998 - 10,900 584 26,000 6,160 -- 116,000 1,130,000 6,340 6.83 19.9 743 -- - - W-02 9/30/1998 - 15,400 518 39 34 28,800 22 15,000 60 -- 762,000 3,380,000 15,700 6.4 21 753 W-02 3/31/1999 - 2,380 852 45 35 47,000 21 6,920 73 -- 26,300 262,000 1,410 6.2 18 126 W-02 9/29/1999 - 9,700 296 36 26,900 9 203 -- 293,000 458,000 15,300 6.19 20 182 - - - W-02 3/16/2000 - 12,700 434 28 25 19,400 2,160 28 -- 281,000 642,000 7,360 -- -- -- - - - W-02 9/15/2000 - 5,490 508 1,600 7 1,140 -- 93,400 374,000 1,890 6.63 19 170 - - - W-02 3/23/2001 - 2,600 4,740 6 234 37 -- 26,300 173,000 6,820 6.5 18 270 - - - W-02 3/28/2002 - 17,900 47 46 45,300 16 3,030 - 88 -- 23,400 219,000 11,900 6.72 14 140 - - - W-02 10/3/2002 -1 -- -- -- I -- I -- -- I -- -- -- - - - - - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 3 of 11 Sample P Location Date 0)m a E .�+ V co O O z U E E Q t� N L Q f6 00 E _7 f6 U L L U L Q O U C O = R y J C L d E 3 m d to to ci O N z L = z d 4 3 co c 0 w •- O O H co = O O M H U 2 C. N L m d d 0 H E ` co v w .2 3 C. O N U z y 3 H _ o V r+ f 1C O O 0- d O N C] NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-02 3/25/2003 -- 6,070 264 8,420 115 25 -- 14,400 118,000 5,290 6.11 18 140 -- -- -- W-02 10/2/2003 - 4,630 277 10,900 8 11,100 -- 1,270,000 3,380,000 7,780 6.11 20 3,020 -- -- -- W-02 4/28/2004 - 3,600 11,000 6 2,630 36 - 233,000 634,000 8,130 -- 14.4 1,460 -- - - W-02 10/26/2004 - 30,200 2,140 9 112 83 65,600 21 5,080 144 -- 11710,000 3,800,000 7,220 - -- 3,690 -- - - W-02 4/27/2005 - 2,750 6 9,150 8 8,950 26 -- 1,260,000 2,868,000 13,800 - -- 3,170 -- - - W-02 10/20/2005 - 9,380 377 2 20 203 26,200 9 6,800 116 -- 1,510,000 1,700,000 22,000 - - 1,110 -- - - W-02 10/19/2006 - 3,630 8,080 6 1,900 44 -- 749,000 1,210,000 8,990 - - 1,050 -- - - W-02 4/27/2007 - 46,500 451 2 0 55,900 -- -- 46 -- 1,570,000 2,800,000 9,010 - - 1,880 - - - W-02 11/19/2007 - 5,750 12,000 8 3,030 -- 1,330,000 1,310,000 9,710 - - 1,330 - - - W-02 4/30/2008 - 4,450 5 334 72 -- 246,000 330,000 7,260 -- - 609 -- -- -- W-02 4/30/2009 - 5,170 268 13.9 11.3 12,500 11.8 441 37.5 -- 10,400 157,000 7,570 -- -- 93.7 -- -- -- W-02 10/15/2009 - 30,000 13 1,600 4.8 110 67 200,000 36 3,400 42 410 - -- -- -- 6.37 15.88 900 30 -145 1.21 W-02 4/20/2010 - 430 180 490 2,400 -- 830,000 1,900,000 48,800 8.02 13.81 1,880 411 15 5.88 W-02 10/11/2010 - 2,300 2.4 J 240 0.68 J 8.7 11 J 6,600 1.7 J 2,300 11 -- 210 660,000 1,400,000 -- 6.33 17.02 1,340 712 46 3.99 W-02 4/22/2011 - 170 2.3 150 1.8 2,100 4,000 14 33 760,000 1,700,000 8,600 -- -- -- -- -- -- W-02 10/17/2011 - 2,180 113 6.1 2,710 4,020 5.8 365,000 842,000 18,700 -- -- -- -- -- -- W-02 3/16/2012 - 2,540 122 6.1 3,270 45.4 30,000 153,000 7,700 6.52 16.14 1,144 8.4 -8.6 5.75 W-02 9/24/2012 - 2,020 119 3,910 2,870 430 276,000 2,030,000 -- -- -- -- -- -- -- W-02 4/18/2013 - 192 339 182 425 56,800 149,000 5,000 -- -- -- -- -- -- W-02 4/18/2013 - -- - -- - - -- -- - -- - - - - -- -- -- -- 6.48 16.73 261 -- 97.2 7.37 W-02 9/10/2013 - 451 315 676 21 -- 44,600 135,000 10,200 -- -- -- -- -- -- W-02 4/7/2014 - 1,800 -- 291 - 2,450 18.8 - - - -- 37,000 7,600 5.79 10.79 247 54.9 252 4.81 W-02 9/4/2014 - 5,930 -- 183 6.3 - 7,950 163 - - - -- 39,000 182,000 -- 5.53 20.05 168 28.2 126.4 3.08 W-02 4/3/2015 - 114 -- 255 -- 148 - - - -- 43,900 134,000 -- 7.62 16.31 256 8.74 19.8 6.94 W-02 9/10/2015 - 6,800 -- 220 9.5 J -- 8,800 93 - - - - 18,000 190,000 B - 5.29 22.4 155 30 272 1.38 W-02 3/8/2016 - 860 -- 280 -- 1,300 29 - - - -- 41,000 130,000 -- 5.68 21.2 193.1 29.7 136.2 5.59 W-02 9/8/2016 - 1,900 -- 190 -- 3,200 31 - - - -- 14,000 230,000 -- 6.6 17.15 116 -- 101 1.91 W-02 3/29/2017 - 140 -- 220 -- 200 2.5 J - - - -- 46,000 100,000 B -- 7.01 15.2 294.3 5.76 206.2 6.94 W-02 9/27/2017 - -- - -- - - - -- - -- - -- - - -- -- -- - 5.55 21.15 114 22 176 0 W-02 3/6/2018 - 100 - 230 -- 150 7.4 - 1.3 J - - -- 47,000 130,000 - 6.21 10.6 185 7.47 220 3.7 W-02 9/12/2018 - 380 - 170 -- 530 6.5 - - - -- 24,000 99,000 - 5.68 19.7 184 27.6 120.7 2.16 W-02 3/19/2019 - 230 -- 150 -- 320 11 - - - -- 28,000 94,000 - 5.29 10.9 125.7 9.39 142.3 0.69 W-02 9/3/2019 - 5,100 -- 170 -- 4,800 29 - - - -- 18,000 160,000 - 5.13 22.3 122 -- 53 -- W-02 3/31/2020 - 970 -- 150 -- 1,100 20 - - - -- 22,000 82,000 - 5.52 13.1 100.7 19.4 83.9 2.57 W-02 (FD) 3/31/2020 - 990 -- 150 -- 1,300 20 - - - -- 22,000 76,000 - -- -- -- -- -- -- W-02 9/24/2020 - 2,600 -- 190 -- 4,300 370 - - - -- 19,000 130,000 - 5.59 17 127.2 10.4 -35.1 2.41 W-02 4/5/2021 - 120 -- 120 -- 92 83 - - -- 14,000 75,000 - 6.88 18.25 990 52.7 163 1.48 W-03 1/16/1990 - -- 300 -- -- -- - -- -- -- -- 7 -- -- -- -- -- W-03 9/6/1990 - -- 8,990 20 810 -- -- 330 -- 0.5 5.9 - -- -- -- -- 6.7 -- -- - - - W-03 9/21/1990 - 2,170 134 8.1 2,000 80 -- 8,500 174,000 12,000 6.52 16.2 238 - - - W-03 10/23/1991 - 213 149 240 330 116 - 214,000 12,000 6.7 19.7 207 - - - W-03 3/25/1992 - 119 -- 22,500 136,000 10,000 6.12 13.1 307 - - - W-03 9/29/1992 - 670 120 580 410 0.3 -- 20,000 189,000 1,000 5.86 17.1 223 - - - W-03 3/31/1993 - 1,170 180 2,300 55 -- 14,900 163,000 2,000 5.53 15.7 207 - - - W-03 9/17/1993 - 9,460 444 2.8 71 20,700 10 173 106 -- 12,000 207,000 2,000 6.23 18.3 282 - - - W-03 3/30/19941 1 4,420 1 1 259 1 1 24 1 10,700 1 150 1 264 1 107 -- 17,000 180,000 5.74 1 15.9 180 - - - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 4 of 11 Sample P Location Date m a co O z L) E 3 Q Q G m E 6 U U L) = J m E to to O N z y a �= z w w O cn c y G O O H fn = aco_E OlC O fC 1--0 2 C. N L m y? a1 d 0 I--N E ` (n v w V_ = O O U z �, j H _ o V c wC r d x G O a d O N N 01 o NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-03 9/30/1994 -- 25,400 485 26 67 32,000 17 526 86 -- 193,000 26,100 6.28 18 202 -- -- -- W-03 3/31/1995 - 31,300 466 27 55 36,400 25 430 186 -- 133,000 206,000 6.64 12.7 220 - -- -- W-03 9/29/1995 - 55,400 813 7 51 122 70,100 42 1,020 183 -- 139,000 302,000 1,320 5.42 15.4 245 - - - W-03 3/30/1996 - 17,100 436 2 20 46 25,900 19 409 100 -- 19,500 217,000 3,410 5.61 13 285 - - - W-03 9/27/1996 - 11,200 257 16,400 15 235 94 -- 59,800 215,000 1,100 7.81 18 243 - - - W-03 3/29/1997 - 16,400 347 3 43 23,000 13 384 51 -- 21,100 223,000 7,860 6.57 12 153 - - - W-03 9/17/1997 - 32,200 478 4 27 67 40,200 24 590 280 -- 88,900 262,000 1,290 6.9 16 366 - - - W-03 3/27/1998 - 12,200 491 21,300 604 -- 19,100 248,000 1,260 6.06 19.9 542 - - - W-03 9/30/1998 - 4,150 5,690 151 39 -- 5,050 238,000 1,340 6.8 20 276 - - - W-03 3/31/1999 - 2,380 3,930 126 73 -- 26,300 262,000 1,410 6.2 18 126 - - - W-03 9/29/1999 - 2,130 4,230 90 -- 27,300 272,000 1,710 6.77 19 315 - - - W-03 3/16/2000 - 11,700 356 35 15,700 7 334 16 36 -- 17,800 193,000 2,630 -- -- -- - - - W-03 9/15/2000 - 6,590 323 26 9,900 11 309 17 -- 20,900 187,000 1,530 6.69 18 390 - - - W-03 3/23/2001 - 828 1,020 9 45 23 -- 27,400 175,000 1,560 6.7 17 310 - - - W-03 10/4/2001 - 3,640 6,020 8 221 13 - 24,700 186,000 3,200 6.13 17 200 - - - W-03 3/28/2002 - 1,720 2,820 100 - -- 38,500 203,000 1,450 6.71 14 470 - - - W-03 3/28/2002 - 2,370 2,820 100 17 - 25,600 177,000 -- -- 238 - - - W-03 10/3/2002 - 8,770 387 22 16,400 450 35 -- 58,200 231,000 1,020 8.12 19 210 - - - W-03 3/25/2003 - 15,300 362 26 23,800 8 622 45 -- 42,600 194,000 6.19 19 210 - - - W-03 10/2/2003 - 2,460 646 4,080 212 -- 28,300 199,000 6.67 17 243 - - - W-03 4/28/2004 - 1,490 2,820 80 13 -- 1,350,000 171,000 -- 14.6 225 - - - W-03 10/26/2004 - 2,370 3,490 129 17 -- 25,600 177,000 -- -- 238 - - - W-03 4/27/2005 - 874 1,580 66 16 40 -- 34,400 192,000 740 - -- 277 - - - W-03 10/20/2005 - 3,500 252 107 4,230 72 30 71 -- 44,000 218,000 18,000 - - 317 - - - W-03 10/19/2006 - 553 277 1,020 37 48 -- 70,400 237,000 690 - - 330 - - - W-03 4/27/2007 - 262 708 -- -- 89,400 251,000 1,510 - - 388 - - - W-03 11/19/2007 - 124 263 156 65 -- 53,000 293,000 860 - - 403 - - - W-03 11/19/2007 - 139 254 158 12 65 -- 64,200 278,000 880 - - 402 - - - W-03 4/30/2008 - 261 148 94 -- 91,000 331,000 760 - - 470 - - - W-03 10/29/2008 - 274 0.33 10.6 216 3.3 124 0.1 95.5 5.15 -- 96,000 360,000 1,040 - - 571 - - - W-03 4/30/2009 - 442 368 638 8.5 61.6 154 68.2 -- 199,000 399,000 940 -- - 603 - -- -- W-03 (FD) 4/30/2009 - 571 268 2.5 332 7.1 30.8 153 32.4 -- 203,000 389,000 1,070 -- -- 617 -- -- -- W-03 10/12/2009 - 26 J 2.7 J 160 0.9 J 16 J 0.08 J 150 740 140,000 430,000 -- 5.88 15.2 -- 8.6 121 2.82 W-03 4/20/2010 - 870 280 940 49 100 -- 100,000 380,000 9,000 5.96 12.52 644 23.2 264 3.74 W-03 10/11/2010 - 110 1.3 J 21 J 1.6 J 77 20 790 89,000 310,000 -- 5.89 18.03 497 6.7 256 1.39 W-03 4/21/2011 - 2.1 140 210 6.7 100 850 120,000 330,000 1,000 5.8 13.07 399 299 3.68 W-03 10/18/2011 - 380 195 262 22.1 102 1,100 360,000 413,000 7,700 6.85 17.47 764 6.3 128 1.76 W-03 3/16/2012 - 97.5 101 10.2 112 5.8 1,700 220,000 1,070,000 7,800 5.51 14.27 755 1.4 125.8 2.36 W-03 9/24/2012 - 87.4 49.1 51.9 1,000 418,000 719,000 -- 5.81 17.76 1,110 1.6 521 W-03 4/18/2013 - 56.2 75.7 29.6 844 401,000 852,000 10,600 5.74 13.98 1,146 1.11 -443.1 0.54 W-03 9/10/2013 - 45.8 98.4 20 -- 447,000 852,000 9,290 5.88 18.91 959 1.13 221.7 0.44 W-03 4/7/2014 - - 39.8 - 88.4 - 20.4 - - -- 338,000 796,000 10,100 5.85 10.71 1,109 0.71 537.7 2.39 W-03 9/3/2014 - - 34 - 135 - 23.4 - - -- 364,000 895,000 -- 5.73 20.62 1,049 2.78 501.6 0.74 W-03 4/2/2015 - - 32.8 - 155 - 25 - - - 449,000 932,000 -- 6.06 15.68 960 2.11 327.6 1.48 W-03 9/9/2015 - - 38 - 280 - 11 J - - -- 530,000 1,000,000 E 5.92 26.15 1,410 0 485 1.02 W-03 3/8/20161 30 1 1 1- 190 1 1 170 1 12 - - -- 320,000 750,000 -- 4.98 13.1 1,018 0.62 550 1.5 W-03 9/8/2016 - - 29 - 300 320 - 2.7 - - -- 360,000 840,000 -- 6.36 20.8 1,048 0.46 88.2 1 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 5 of 11 Sample P Location Date 0)m a O _O z U E _ E 3 n L0 E E U L- U .co C O U O N J 3 E d co L co O N z y a z � w cn c y _ O co = aco Oca O I-- U C. N L m y a1 d0M I-- E ` cn v w ;G _ OO N U z �, _ o C> c w r G m a d O v, N 01 o NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-03 3/29/2017 -- 15 J -- 43 -- 310 290 -- -- -- -- 410,000 880,000 B -- 6.32 15.1 1,218 2.22 180.2 0.79 W-03 9/26/2017 - 13 BJ -- 32 -- 190 320 - -- -- -- 390,000 860,000 -- 6.29 23.28 1,080 2.9 371 0 W-03 3/6/2018 - - 35 - 130 590 - 8.8 - - -- 520,000 1,100,000 -- 6.7 11 149 0.61 481 0.7 W-03 (FD) 3/6/2018 - - 34 - 140 550 - 7.6 - - - 530,000 1,100,000 -- -- -- -- -- -- -- W-03 9/12/2018 - - 26 - 170 510 - - - -- 400,000 900,000 -- 6.17 20.2 1,131 0.64 195.6 3.2 W-03 3/19/2019 - - 28 - 230 180 - 7.4 - - -- 250,000 600,000 - 6.24 13.5 858 2.04 291 1.77 W-03 9/3/2019 - - 27 - 110 - 5.4 - - -- 200,000 500,000 - 5.96 20.9 680 0.16 177 1.11 W-03 3/31/2020 - - 26 - 170 - 9.8 - - -- 190,000 510,000 - 6.17 12.8 712 0.37 3,819.1 0.89 W-03 9/24/2020 - - 29 - 100 120 - 10 - - -- 150,000 460,000 - 6.24 16.3 648 0.35 129.3 0.7 W-03 4/5/2021 - - 28 - 55 32 6.7 - - -- 110,000 360,000 - 6.51 22.74 5,130 0 318 0.88 W-03 10/20/2021 - - 34 -- 120 - - -- -- 120,000 370,000 -- 6 17.4 614 0.6 322 0.25 W-03B 10/26/2004 - 2,330 3,170 157 24 -- 174,000 545,000 2,710 -- -- 862 -- -- -- W-03B 4/27/2005 - 203 2 1,830 15 907 41 36 -- 590,000 840,000 10,100 - - 1,180 - - - W-03B 10/20/2005 - 3,630 29 4,290 5 68 75 -- 146,000 627,000 30,000 - - 550 - - - W-03B 10/19/2006 - 135 950 5 811 42 -- 318,000 750,000 5,240 - - 739 - - - W-03B 4/27/2007 - 238 901 1,280 -- 475,000 1,050,000 2,570 - - 1,240 - - - W-03B 11/19/2007 - 1,170 1,270 -- 582,000 101,000 22,600 - - 1,310 - - - W-03B 4/30/2008 - 505 1,010 -- 570,000 955,000 1,180 - - 1,270 - - - W-03B 10/29/2008 - 48 4.9 1,950 946 0.07 10.5 -- 305,000 760,000 830 -- -- 1,080 -- -- - W-03B 4/30/2009 - 42.6 490 10.5 999 9.7 1.5 8.7 - 185,000 827,000 5,560 -- -- 1,150 -- -- -- W-03B 10/12/2009 - 39 J 3.6 J 43 J 0.9 J 330 880 250,000 780,000 -- 7.17 14.64 -- 14.4 -42 3.4 W-03B 4/20/2010 - 49 500 970 -- 280,000 770,000 11,200 6.75 17.46 2,320 108 -51 0.23 W-03B 10/11/2010 - 2.4 J 45 0.95 J 500 980 9.9 6 J 140 J 300,000 830,000 -- 6.66 17.49 1,010 41.3 -25 W-03B 4/21/2011 - 2.5 51 970 1,200 12 85 370,000 890,000 1,100 6.63 15.39 956 -72 0.48 W-03B 10/18/2011 - 52 606 1,320 460,000 1,090,000 9,700 9.49 15.03 1,750 9.4 -86 W-03B (FD) 10/18/2011 - 50.9 587 1,280 408,000 1,050,000 8,000 9.49 15.03 1,750 9.4 -86 W-03B 3/16/2012 - 48.5 472 1,560 47.6 559,000 533,000 9,800 6.7 14.5 1,474 2.9 -35 0.79 W-03B 9/24/2012 - 45.1 537 1,340 27.1 422,000 1,050,000 -- 7.14 16.04 1,650 3.6 -26 W-03B 4/18/2013 - 40.3 397 743 248,000 623,000 16,800 6.64 14.86 961 0 -71 0.47 W-03B 9/10/2013 - 43.2 258 448 -- 120,000 421,000 6,580 7.23 19.33 1,380 9.2 -43 W-03B 4/7/2014 - - 46.6 - 772 540 - - - -- 123,000 396,000 49,000 6.86 16.07 987 0 -92 0.38 W-03B 9/3/2014 - - 48.4 - 321 452 - 12.5 - - -- 18,100 403,000 -- 6.85 16.21 988 1.4 -87 2.01 W-03B 4/2/2015 - - 47.8 -- 3,070 520 - - - -- 79,400 415,000 -- 7.21 15.95 500 8.5 122.7 0.74 W-03B 9/9/2015 - - 42 -- 170 570 - - - -- 110,000 390,000 B -- 6.69 27.24 670 0 -7 0.96 W-03B 3/8/2016 - - 50 - 680 440 - 2.3 - - -- 73,000 390,000 -- 7.28 13 596.4 6.02 62 0.23 W-03B 9/8/2016 - - 45 - 340 380 - - - -- 71,000 380,000 -- 7.3 21.35 538 0.44 62 0.7 W-03B (FD) 9/8/2016 - - 46 - 350 380 - 1.1 - - -- 74,000 370,000 -- -- -- -- -- -- -- W-03B 3/29/2017 - 8.9 J -- 44 - 400 440 - - - -- 110,000 410,000 B -- 7.28 13.7 687 0.58 156.6 0.52 W-03B (FD) 3/29/20171 8.2 J -- 46 - 400 470 - - - -- 110,000 360,000 B -- -- -- -- -- -- -- W-03B 9/26/2017 - 19 BJ -- 55 - 820 310 - - - -- 65,000 370,000 -- 7.22 20.23 453 2.7 28 0 W-03B 3/6/2018 - - 45 - 210 330 - - - -- 100,000 440,000 - 8 10 652 0.1 -28 0.55 W-03B 9/12/2018 - - 47 - 240 230 - - - -- 61,000 340,000 - -- 23 504 0.18 -36 0.65 W-03B 3/19/2019 - - 47 - 650 48 - - - -- 39,000 290,000 - 7.18 10.7 459.9 3.63 71.3 3.17 W-03B 9/3/2019 - - 42 - 35 - - - -- 24,000 260,000 - 7.15 19.1 385 0.39 -11.5 0.59 W-03B 3/31/20201 59 1 87 1 23,000 240,000 - 7.53 12.8 400.3 0.2 24.9 0.44 W-03B 9/24/20201 54 - 350 1 1 120 1 19,000 1 260,000 - 7.57 16 391.9 0.73 185.3 0.23 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 6 of 11 Sample P Location Date 0)m a O _O z U E _ E 3 n L0 E E U L- U .co C O U O N J 3 E d co L co O N z y a z � w cn c y _ O cN = aco Oca O I-- U C. N L m y a1 d0M I-- E ` co v w ;G _ 0O N U z �, _ o V c w r G m a d O v, w a1 o NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-03B 4/5/2021 -- -- 56 -- 130 72 -- -- -- 16,000 250,000 -- 7.98 20.27 3,130 0 -23 2.91 W-03B 10/20/2021 - -- 50 -- 210 78 -- -- -- -- 14,000 230,000 -- 7.58 17.09 369 0.4 -18 0 W-04 4/4/1995 - 9,720 15,600 7 564 58 - 7,880 231,000 136,000 6.07 19 234 - - - W-04 9/17/1997 - 4,420 2 10,000 6 406 190 -- 8,860 212,000 3,190 7.5 18 366 - - - W-04 3/27/1998 - 3,410 6,250 -- 44 -- 7,120 226,000 2,690 6.72 19.2 390 - - - W-04 9/30/1998 - 219 1,610 299 -- 6,420 200,000 7,260 5.9 21 322 - - - W-04 3/31/1999 - 637 2,150 285 -- 5,710 202,000 8,530 6.5 16 279 - - - W-04 9/29/1999 - 127 1,440 5 271 24 - 207,000 2,850 6.38 18 315 - - - W-04 3/16/2000 - 1,470 298 -- 191,000 6,050 -- -- -- - - - W-04 9/15/2000 - 165 1,090 252 -- 5,300 241,000 15,500 6.22 17 310 - - - W-04 3/23/2001 - 2,750 4 9,910 16 447 28 - 6,530 219,000 5,990 6.4 16 240 - - - W-04 10/4/2001 - 204 915 7 229 -- 186,000 7,800 6.28 20 300 - - - W-04 3/28/2002 - 1,460 212 - -- 5,160 196,000 1,680 6.18 14 190 - - - W-04 10/3/2002 - 1,130 237 29 -- 5,080 202,000 4,070 6.11 19 280 - - - W-04 3/25/2003 - 976 212 -- 6,050 185,000 1,610 6.17 16 260 - - - W-06 10/2/2003 - 1,920 268 24 3,220 154 440 -- 95,000 466,000 34,000 7.25 19 661 W-06 4/28/2004 - 1,160 30 26 917 7 37 149 -- 370,000 692,000 139,000 -- 14.7 937 - - - W-06 10/26/2004 - 790 89 32 259 12 87 -- 116,000 630,000 79,200 - -- 917 - - - W-06 4/27/2005 - 389 5 56 -- 87,500 565,000 13,200 - - 932 - - - W-06 10/20/2005 - 40 355.7 60 -- 35,400 553,000 27,000 - - 939 - - - W-06 10/19/2006 - 529 77 12 66 -- 46,400 471,000 29,300 - - 655 - - - W-06 4/27/2007 - 2,660 29 2,790 106 168 - 29,500 442,000 8,840 - - 776 - - - W-06 11/19/2007 - 627 711 24 38 -- 11,200 431,000 8,980 - - 694 - - - W-06 4/30/2008 - 37 -- 392,000 5,610 - - 615 - - - W-06 10/29/2008 - 235 35.8 0.41 6.8 268 9.3 67 -- 393,000 4,130 - - 724 - - - W-06 (FD) 10/29/2008 - 222 293 1 2.7 460 4.9 84.6 0.16 101 -- 98,800 384,000 860 -- - 574 -- -- - W-06 4/30/2009 - 139 36.6 7 33.1 2.9 1.5 8.1 33.2 - 10,500 463,000 10,300 -- - 807 -- -- - W-06 10/12/2009 - 140 2.3 J 28 5.5 4.3 J 44 J 1.7 J 0.2 17,000 J 380,000 -- 10.55 18.86 1,020 33.1 -243 0.16 W-06 4/20/2010 - 1,700 59 400 14 3,200 87 69 -- 16,000 450,000 9,100 10.74 18.92 930 209 -227 0.03 W-06 10/11/2010 - 320 37 420 19 J 2,800 56 -- 120 J 13,000 410,000 -- 10.57 17.7 816 35.7 -250 W-06 4/22/2011 - 260 1.2 33 190 7 1,000 1.3 28 1.1 17 21 16,000 410,000 3,800 11.07 13.85 562 9.6 -189 1.01 W-06 10/17/2011 - 421 26.9 60.9 89 311 6.8 60.1 11,000 414,000 6,100 -- -- -- -- -- -- W-06 10/18/2011 - 421 26.9 60.9 89 311 6.8 60.1 -- 11,000 414,000 6,100 12.24 18.13 1,040 8.6 -313 0.37 W-06 3/16/2012 - 221 44.7 8.5 83 10.1 11,400 499,000 5,200 11.16 17.26 845 1.9 -234 0.38 W-06 9/26/2012 - 202 37.3 23.6 162 14.1 12,200 317,000 -- 11.44 16.32 667 8.9 -21 W-06 4/19/2013 - 517 41.1 18.3 277 6.4 21.2 12,200 334,000 4,920 -- -- -- -- -- -- W-06 4/19/2013 - -- - -- 18.3 277 6.4 21.2 - 12,200 334,000 4,900 10.44 15.8 620 8.6 -450.5 0.4 W-06 9/11/2013 - 312 46.9 21.7 397 7.7 19.4 - 12,100 335,000 4,390 10.63 17.85 506 6.87 82.6 0.71 W-06 4/9/2014 - 154 - 42.2 6.9 - 141 - - -- -- 12,400 304,000 4,700 10.85 15.07 634 4.23 -43.1 1.23 W-06 9/5/2014 - - 33.7 - - - - - 11,800 337,000 -- 10.81 15.7 637 3.87 -37.4 1.19 W-06 4/2/2015 - - 35.4 9.4 - 72.6 - - - -- 11,700 314,000 -- 10.26 16.31 555 2.62 -142.1 2.74 W-06 9/8/2015 - 570 - 37 110 - 900 23 - - - -- 11,000 280,000 - 10.22 21.3 496 22.7 -59 1.95 W-06 3/9/2016 - - 35 18 - 230 - - - -- 12,000 270,000 - 10.08 16.4 464.5 7.29 -80.9 0.48 W-06 9/6/2016 - 62 - 37 - 110 - - - -- 9,900 260,000 - 10.1 16.4 754 2 -106 0.7 W-06 3/28/2017 - 530 - 76 36 - 990 0.5 J 17 - - - -- 10,000 220,000 - 9.75 15.5 437.1 9.85 -67.2 0.59 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 7 of 11 Sample P Location Date 0)m a .r f�6 V d co _ O O z U E C _ E 3 Q .� a� i Q 7 L M m E O E M U L U y C. C O U O y J f6 C 7 i N E d d co L co O N z y y = z �; w 7 co c y p y R O O H co = O a m O M H U co 2 C- N L m y y y a1 d 0 H E ` 0) v w w 3 _ O. O N U z �, :a j H _ o V c w r m 1C O O 0- d O v, N E C] NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-06 9/27/2017 -- 220 B -- 41 14 -- 220 0.58 J 6.5 -- -- -- -- 11,000 270,000 -- 9.86 16.8 360 4.48 82 1.26 W-06 3/6/2018 - 100 -- 39 32 -- 620 9.4 - -- -- -- 11,000 260,000 - 9.56 11.86 0.399 11.4 -29 1.5 W-06 9/13/2018 - 2,100 -- 200 42 -- 2,900 1.6 330 - - - - 57,000 270,000 - 9.9 18.2 475 7.38 124 0.67 W-06 3/20/2019 - - 42 5.5 - 100 - - - - 10,000 270,000 - 9.51 15.6 435.2 3.18 80.7 0.68 W-06 9/4/2019 - 100 - 38 - 100 - - - -- 12,000 270,000 - 9.01 19.7 398 -- -109.5 0.37 W-06 4/3/2020 - 180 - 43 7.2 - 190 5.6 - - - -- 10,000 250,000 - 9.4 15.6 397 7.36 -56.6 0.42 W-06 9/24/2020 - 120 - 40 7.8 230 - - - -- 9,000 290,000 - 9.29 15.6 386.7 6.13 -76.9 0.75 W-06 4/5/2021 - 240 - 51 18 - 490 8.4 - - -- 9,000 S 270,000 9.65 17.38 372 1.8 16 4.83 W-06 10/21/2021 - 320 - 61 10 - 540 16 - - - -- 10,000 260,000 - 9.75 15.75 434 10.2 22 1.32 W-07 1/6/2011 -- 110 -- 200 120 - - - -- 9,300 200,000 -- 7.1 15.4 298 5.2 83 2 W-07 4/21/2011 - 92 80 520 160 44 6,600 190,000 7.26 15.24 301 12 0.62 W-07 9/25/2012 318 77.3 628 173 6,200 206,000 -- 8.09 15.07 403 18.2 46 W-07 4/18/2013 403 140 6 1,460 146 10,200 173,000 29,000 6.89 15.68 271 17.1 -448.1 1.7 W-07 9/11/2013 - 257 112 950 124 -- 8,100 3,310 7.43 16.19 271 7.7 4.3 0.87 W-07 4/9/2014 - 427 - 131 -- 1,830 97.1 - - - -- 11,200 181,000 3,500 6.79 15.55 265 21.3 119.1 2.87 W-07 9/5/2014 - 797 - 81.1 -- 1,580 189 - - - -- 6,400 220,000 -- 7.5 15.93 289 8.08 10.3 1.35 W-07 4/2/2015 - 402 - 136 -- 1,970 69.6 - - - -- 10,800 169,000 -- 7.5 15.87 284 9.37 6.3 2.19 W-07 9/9/2015 - 380 J - 78 28 -- 1,600 150 - - - -- 5,700 170,000 B -- 6.73 18.73 349 5.9 23 4.64 W-07 3/9/2016 - 800 - 140 16 - 3,800 100 - - -- 11,000 110,000 -- 6.98 14.1 283.5 40.4 114.9 1.87 W-07 9/6/2016 - 260 - 130 -- 1,800 53 - - -- 9,800 89,000 - 7.1 16.8 206 20.5 89 3.1 W-07 3/28/2017 - 500 - 130 28 -- 3,600 0.93 J 110 - - - -- 8,900 160,000 B -- 6.92 15.3 280.2 42.9 12.3 1.9 W-07 9/27/2017 - 2,200 B -- 100 11 -- 4,400 0.99 J 800 - - - -- 5,400 160,000 B -- 7.53 16.32 281 9.24 50 0.5 W-07 (FD) 9/27/2017 - 200 B -- 71 4.1 J - 1,100 0.67 J 93 - - - -- 5,400 230,000 -- 7.53 16.32 281 9.24 50 0.5 W-07 3/5/2018 - 240 - 73 7.9 -- 1,600 0.43 220 - - - -- 5,600 210,000 - 7.25 13.82 341 29.4 16 1.22 W-07 3/6/2018 - 240 - 73 7.9 -- 1,600 0.43 J 220 - - - -- 5,600 210,000 - -- -- -- -- -- -- W-07 9/12/2018 - 310 - 81 9.6 -- 2,800 190 - - - -- 6,300 210,000 - 7.3 17.7 327 56.3 32.4 0.74 W-07 9/12/2018 - 310 - 81 9.6 -- 2,800 190 - - - -- 6,300 210,000 - -- -- -- -- -- -- W-07 3/20/2019 - 96 - 100 -- 1,400 29 - - -- 11,000 180,000 - 6.5 15.7 267 21.3 134.7 2.28 W-07 (FD) 3/20/2019 - 140 - 110 -- 1,600 32 - - -- 11,000 180,000 - 6.5 15.7 267 21.3 134.7 2.28 W-07 9/4/2019 - 280 - 78 -- 1,800 150 - - - -- 6,000 220,000 - 6.75 15.4 322 26.1 -73.3 0.27 W-07 4/2/2020 - 130 - 75 6.1 -- 1,200 72 - - - -- 5,400 190,000 - 7.34 13.8 339.2 31.1 0.5 0.36 W-07 9/24/2020 - 99 - 130 5.9 -- 1,500 37 - - - -- 11,000 180,000 - 6.97 15.1 208.1 17.6 -81.6 4.21 W-07 4/5/2021 - 1,900 -- 100 22 -- 5,300 99 - - -- 11,000 140,000 - 6.41 17.08 166 29.4 323 7.19 W-07 10/21/2021 - 140 -- 130 -- 870 29 - - - -- 12,000 130,000 -- 6.33 15.9 186 8.5 206 4.12 W-08 1/6/2011 - -- -- 330 0.12 -- 2,900 65 - - -- -- 73,000 210,000 -- 7.47 14.8 300 49.6 182 7.88 W-08 4/20/2011 - 390 1.2 180 940 20 8.9 240 68,000 240,000 1,100 5.68 15.1 391 133 203 7.06 W-08 9/26/2012 - 643 166 25.2 7.7 777 63.6 151 250 86,800 242,000 -- 6.08 20.48 382 6.2 158 5.86 W-08 4/18/2013 - 5,940 465 86.4 85.6 9,760 220 122 292 95,000 247,000 5,160 5.83 19.45 330 9.6 -428 5.3 W-08 9/10/2013 - 1,180 407 41.7 40 1,900 37.1 67.1 -- 101,000 244,000 5,600 5.69 21.81 310 9.3 95.3 6.02 W-08 4/9/2014 - 1,670 - 147 7.5 -- 2,940 86.5 - - -- -- 98,800 263,000 4,900 5.58 18.13 371 11.91 195.4 5.87 W-08 9/3/2014 - 318 - 136 -- 463 23 - 13.4 - -- -- 114,000 300,000 -- 5.37 14.79 329 8.4 154.3 5.91 W-08 4/2/2015 - 873 -- 206 42.7 -- 1,410 26.9 - 11.5 - - - 62,700 219,000 -- 5.93 21.58 340 39.9 68.4 4.64 W-08 9/9/2015 - 840 -- 160 84 -- 1,200 180 - - - - 96,000 240,000 B -- 5.8 31.23 322 35.6 125 3.55 W-08 3/9/20161 2,700 -- 290 310 -- 4,800 1.9 290 - 6.4 - - - 65,000 230,000 -- 6.19 15.6 332 87 84.8 5.24 W-08 9/7/20161 1 1,900 1 1 280 7.9 1 4,100 60 - 4 - - - 64,000 200,000 - 6.3 20.1 240 9.6 98 6.5 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 8 of 11 Sample P Location Date d O. O U f% O 0 0 z U E O E 3 Q C.> a0i i Q O C f0 00 _7 E O f0 U E O i t U i O Q O L) C O i N J m N C C >+ i O a E N N to d to V O N z N f6 ca = z JT 7 to > 0 _N _ f9 ._ O O to V c _cc f6 O � cU _ 2 a tp N y a� fLC fp O` Gl N d I-- S E ` (n �, r V V U-0 Q O to L) H z r j 0 o w U O> w E O R C O m K O 0- � O X O N u0i J y 01 ❑ NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE W-08 3/28/2017 - 1,700 -- 380 99 -- 3,300 1 58 -- 6.7 -- -- -- 66,000 170,000 B - 5.73 19.9 275.2 21.5 177 5.74 W-08 9/26/2017 - 2,600 B -- 290 51 - 2,500 2.5 120 - 6.4 - - - 53,000 210,000 - 6.02 16.32 211 33.1 128 7.91 W-08 3/5/2018 - 560 -- 150 20 - 1,100 0.56 J 67 - 4 J - - - 56,000 190,000 - 5.66 18.95 221 41 203 18.32 W-08 9/12/2018 - 62 - 36 12 - 230 - - - - 11,000 260,000 - 6.94 18.5 394 91.3 119 5.87 W-08 3/20/2019 - 450 - 240 20 - 730 17 - - - -- 17,000 130,000 - 5.39 12.7 127.8 20.6 157.8 6.89 W-08 9/4/2019 - 270 - 300 - 370 11 - - - -- 61,000 180,000 - 5.13 16.3 205.7 9.8 61.6 6.47 W-08 4/2/2020 - 64 - 150 5.1 - 97 - - - - 69,000 170,000 - 5.57 18.3 239 4.9 118.1 6.78 W-08 9/24/2020 - 940 - 180 13 - 1,100 18 - - - -- 37,000 140,000 - 7.68 15.5 165.9 16.8 47.8 6.7 W-08 4/5/2021 - 2,000 - 210 75 - 2,600 43 16 - - - 16,000 150,000 - 5.94 19.89 157 94.9 242 4.54 W-08 10/20/2021 - 400 - 150 12 - 680 15 - - - -- 19,000 96,000 - 5.64 20.18 122 82.5 218 5.04 W-09 1/5/2011 - -- - 27 - 440 32 - - - - 16,000 150,000 - 8.39 15.9 274 119 22 W-09 1/5/2011 - -- - 27 - 440 32 - - - -- 16,000 150,000 - 8.39 15.9 274 119 22 W-09 4/20/2011 - 83 39 170 23 42 10,000 130,000 8.83 16.78 286 121 -10 0.45 W-09 9/26/2012 - 116 102 10 108 10.1 8,800 149,000 -- 10.98 16.25 350 7.9 12 ^ n� W-09 4/19/2013 - 281 115 8.5 157 8 9,270 155,000 2,400 9.62 16.48 286 9.7 -455 0.22 W-09 9/10/2013 - 114 94 68.6 -- 9,100 169,000 2,410 10.45 16.52 272 3.97 -73.4 0.27 W-09 4/9/2014 - - 54.8 - - - - -- 11,100 204,000 3,100 9.44 14.36 257 4.7 -421 0.18 W-09 9/4/2014 - 134 - 60.2 - 222 7.3 - - - -- 11,100 212,000 -- 9.74 19.92 303 11.2 32.8 3.54 W-09 4/3/2015 - -- 113 - - - - -- 9,100 279,000 -- 11.66 16.84 982 3.57 -184.4 0.7 W-09 9/8/2015 - 1101 -- 100 3.7 J - 41 J 1.4 J - - - -- 9,100 280,000 - 11.77 19.18 856 7 -177 1.67 W-09 3/8/2016 - 90 -- 89 - 83 - - - -- 10,000 290,000 - 12.22 16.9 888 3.16 -166.7 0.35 W-09 9/6/2016 - 74 -- 97 - 39 - - - -- 8,400 260,000 - 11.8 16.6 754 2 -106 0.7 W-09 3/28/2017 - 99 -- 100 11 - 81 1.3 J - - - -- 9,300 260,000 - 11.61 17.6 862 2.68 47.9 0.22 W-09 9/26/2017 - 140 B -- 100 5.9 - 96 0.41 J 2 J - - - - 11,000 230,000 - 11.59 16.95 655 1.85 -147.2 0.94 W-09 3/6/2018 61 - 110 3.8 J - 51 - - - -- 11,000 270,000 - 11.36 11.6 690 3.7 -36 2.03 W-09 9/11/2018 - - 130 - - - - -- 11,000 190,000 - 10.78 17.2 487 0.82 90.7 0.33 W-09 3/20/2019 - - 110 - - - - -- 12,000 270,000 - 11.34 17.9 798 1.51 -230.1 0.31 W-09 9/4/2019 - 130 - - - - -- 13,000 180,000 - 9.59 17 292.4 0.5 -139.4 0.15 W-09 4/2/2020 - 42 - 170 - - - - -- 12,000 230,000 - 11.37 18.1 758 0.87 -400 0.19 W-09 9/23/2020 - - 140 - - - - -- 11,000 190,000 - 11.18 17.7 472.9 0.61 -138.2 0.44 W-09 4/6/2021 - 120 - 120 7 - 200 - - -- 11,000 260,000 -- 11.57 18.01 676 0 -84 0.51 W-09 10/20/2021 - 85 - 130 -- - - - -- 12,000 240,000 -- 11.07 18.02 7.39 0 -132 1 PW-01 4/29/1988 - 152 59 8 57 57 314 576 -- 37,000 500,000 1,280 6.9 -- -- -- -- -- PW-01 7/13/1989 - -- 100 -- -- -- -- -- -- -- -- -- -- -- - - - PW-01 9/6/1990 - -- 90 -- -- 9.9 -- -- - -- -- -- 6.8 -- -- - - - PW-01 10/23/1991 - 130 0 620 1,230 3,310 - 460,000 850,000 8,000 6.41 15.1 1,247 -- -- -- PW-01 8/10/2009 - -- - 35 - 4,800 1,800 - - -- - 680,000 -- -- 6.98 15.3 2,860 32.1 13 PW-01 5/13/2010 - 46 6,800 2,500 5,100 -- 1,000,000 2,100,000 - 6.68 16.47 2,580 215 -54 13.5 PW-01 5/13/2010 - -- - -- - - - -- -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- PW-01 5/14/2010 - 44 6,300 9.4 2,400 21,000 - 940,000 2,100,000 -- 6.76 16.09 2,570 166 -50 13.2 PW-01 5/14/2010 - 34 2,900 2,000 560 - 800,000 1,900,000 -- 6.76 15.03 2,430 217 -20 14.9 PW-01 4/21/2011 - 280 11 46 4,400 3,000 54 920,000 2,000,000 2,100 6.2 16.58 2,250 24 0.6 PW-01 9/26/2012 - 1,060 52.2 4,280 2,780 13.5 450 1,190,000 2,980,000 -- 6.8 15.91 2,890 8.7 2 1' PW-01 4/18/2013 - 1,080 55.4 3,830 2,700 10.1 626 1,080,000 1,940,000 14,200 6.2 16.23 2,401 3.03 -453.1 0.6 PW-01 9/10/2013 - 1,010 52.4 5,680 2,990 18.8 - 1,150,000 2,240,000 20,500 6.21 1 17.72 2,191 5.24 44.1 0.4 APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 9 of 11 Sample P Location Date 0)m a E .�+2 fV n O O z U E E O Q U aCi N L Q 'i @ 00 E _7 E '0 M U O L i U L C C. O U C O M y J a' C u L d E 7 d d to d � to V C N z y R L �= z d '� Cn c y 0 �_ w .- O O H co = O M W L O M H U N` 2 C- N L m y d E °' Q O H : E ` co v w 0 w 7 0 d C C. O co U z �, a. L 3 H _ o V c r+ f. m ..+ X O O a d O v°, 0) N E NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE PW-01 4/7/2014 -- 628 -- 48.9 -- 4,780 3,130 -- -- -- -- 914,000 1,980,000 16,600 6.23 15.34 2,689 3.2 40.7 0.83 PW-01 9/5/2014 - 1,370 -- 32.3 8.4 -- 6,160 3,080 - 49.9 -- -- -- 1,010,000 2,260,000 -- 6.14 16.72 2,552 5.69 -16.2 3.93 PW-01 4/2/2015 - 195 -- 45 -- 435 595 - 62.3 - - -- 1,010,000 187,000 - 5.98 21.63 241 6.6 332 4.59 PW-01 9/9/2015 410 - 54 0.8 J 8.3 J - 5,000 3,400 - - - -- 990,000 2,100,000 E 6.34 26.1 2,220 0 1 0.49 PW-01 3/8/2016 - 420 - 51 8.8 -- 5,000 3,500 - - - -- 940,000 2,100,000 -- 6.39 14.3 2,524 3.12 39.2 0.4 PW-01 9/6/2016 250 - 42 0.12 -- 5,300 3,300 - 2.5 - - -- 840,000 1,900,000 -- 6.7 17.9 2,080 1.6 -2 0.8 PW-01 3/28/2017 - 61 - 39 19 -- 4,200 3,300 - 3.8 J - - -- 840,000 1,900,000 E 6.38 15.8 2,342 3.39 42.3 0.31 PW-01 9/26/2017 - 180 B -- 48 5.3 -- 4,700 1.3 3,600 - - - - 780,000 1,900,000 - 6.36 16.82 1,880 1 14.3 0.48 PW-01 3/6/2018 870 - 48 3.8 J -- 6,500 0.85 J 3,100 - 3.6 J - - -- 760,000 1,800,000 -- 6.09 13.55 2,420 39.1 98 1.01 PW-01 9/13/2018 - 160 - 37 -- 4,500 3,100 - - - -- 750,000 1,700,000 -- 6.43 15.5 1,709 9.76 74.4 0.26 PW-01 (FD) 9/13/2018 - 150 - 37 -- 4,500 3,300 - - - -- 770,000 1,700,000 - 6.43 15.5 1,709 9.76 74.4 0.26 PW-01 3/19/2019 - 430 - 38 -- 5,300 2,700 - 7.8 - - -- 670,000 1,500,000 -- 6.41 14.7 1,984 5.73 3.2 0.49 PW-01 9/4/2019 - 330 - 35 -- 3,000 3,000 - 20 - - -- 750,000 1,700,000 - 5.8 15.6 1,963 3.82 -56.1 0.17 PW-01 (FD) 9/4/2019 - 170 - 35 -- 3,300 3,100 - - - -- 740,000 1,700,000 -- -- -- -- -- -- -- PW-01 4/2/2020 - 250 - 36 -- 3,300 2,700 - 21 - - -- 830,000 1,700,000 -- 6.39 15.2 2,088 4.14 -1.6 0.25 PW-01 9/24/2020 - 360 - 56 9.6 -- 1,000 190 - 19 - - - 330,000 730,000 - 6.04 15.4 954 6.09 214.4 3.75 PW-01 4/5/2021 - 620 - 47 7.9 -- 8,900 2.2 2,500 15 - - -- 620,000 1,500,000 -- 6.59 17.85 1,880 58.9 85 0.43 PW-01 10/20/2021 - -- - -- - -- -- -- -- -- - -- - - -- 670,000 1,600,000 -- 6.44 16.4 2,020 0 36 0.71 PZ-01 1/4/2011 - -- - 81 -- 1,600 78 - - - -- 98,000 180,000 -- -- -- -- -- -- -- PZ-01 4/20/2011 - 1,600 63 1.9 2,700 1.6 110 110 30,000 100,000 4,200 PZ-01 9/25/2012 - 99.7 138 119 1,900 319,000 806,000 -- - - - - - - PZ-01 4/17/2013 - 182 64.3 200 55.6 240 95,500 217,000 4,960 PZ-01 9/10/2013 - 82.7 72.1 17.8 -- 179,000 485,000 6,530 - - - - - -- PZ-01 4/6/2014 - -- 56.7 - 148 28.3 - - - - 98,900 1,430,000 5,000 - - - - - -- PZ-01 9/3/2014 - 52,800 - 778 280 -- 69,200 27 3,130 - - - -- 162,000 503,000 -- -- -- -- -- -- -- PZ-01 4/1/2015 - - 60.1 -- 87 11.4 - - - -- 91,900 290,000 -- 8.13 16.48 509 2.19 17.4 7.51 PZ-01 9/8/2015 - -- -- -- - -- -- -- -- -- - - -- -- -- -- -- -- -- -- -- -- -- -- PZ-01 3/7/2016 - 72,000 -- 1,100 220 -- 110,000 58 2,800 - - - - 110,000 260,000 - - -- - -- - -- PZ-01 9/7/2016 - -- -- -- - -- -- -- -- -- - - -- -- -- -- -- -- -- -- -- -- - -- PZ-01 3/27/2017 - -- - - - - - -- -- - - - -- -- -- -- -- -- -- -- -- - - - PZ-01 9/25/2017 - - - - - - - -- -- - - - -- -- -- -- -- -- -- -- -- - - - PZ-01 3/5/2018 - - - - - - - -- - - - - -- -- -- -- -- -- -- -- -- - - - PZ-01 9/11/2018 - - - -- - - - -- - - - - -- -- -- -- -- -- -- -- -- - - - PZ-02 1/4/2011 - -- -- 120 - 770 410 - - - -- 180,000 360,000 - - - - - - - PZ-02 4/20/2011 - 4,200 99 6.9 2.7 7,400 3.4 410 0.14 100 82,000 250,000 6,700 - - - - - - PZ-02 9/25/2012 - 113 106 38.9 2,000 306,000 767,000 -- - - - - - - PZ-02 4/17/2013 - 222 63.7 247 28.4 180 98,200 197,000 4,630 - - - - - - PZ-02 9/10/2013 - 83.9 83.8 13.8 -- 169,000 455,000 6,250 - - - - - - PZ-02 4/6/2014 - 114 -- 54 -- 180 12 - - - -- 93,800 255,000 4,000 - - - - - - PZ-02 9/4/2014 - 4,250 -- 122 5.7 -- 7,330 464 - - - - 159,000 511,000 -- -- -- -- -- -- -- PZ-02 4/1/2015 - -- 58.4 -- 159 9.7 -- - - - 82,200 267,000 -- 8.15 15.93 466 3.17 18.7 8.05 PZ-02 9/8/2015 - 41,000 -- 560 9.5 66 -- 85,000 30 9,600 -- - - - 97,000 340,000 - -- -- -- -- -- -- PZ-02 3/7/2016 - 49,000 -- 810 3.4 69 -- 110,000 34 16,000 -- - - - 38,000 140,000 - - -- - - - - PZ-02 9/7/2016 - 1,900 -- 230 1.3 -- 19,000 8.5 4,500 -- - - - 59,000 240,000 - - - - - - - PZ-02 3/27/2017 - 11,000 -- 270 7.5 20 -- 33,000 8.1 6,400 -- - - - 63,000 210,000 B -- - - - - - - APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 10 of 11 Sample Location .: — • i. 1 • 1 111 11 .11 111 1 111 • : .: ' 1 • 1:� 1 1 1 ���®� 1 1 1 � : 1 1 �-��� 111 :1 111 ������� 1�Nwxff1 •®��®-��-��-��� 111 1 111 ���� • 1 • ® '® 1 ' 1 1� .• 1 1 1 ����� 1 1 1 1 � 1 1 ����� 111 •1 111 ������� ------------------------- 1 111 1 1 • � 1 1 1 � 11 ��� 1 1 1 � I I �-��� : 111 ' • 111 ������� 1 1 : ------------------------- 1' 1 •� .1 111 � 11 � 11 � .1 111 ® 111 �-��� 111 •1 111 ������� ------------------------- 1 1 ' 1 � 1 1 -�-�� 1 1 1 ®�-®-� • 1 : 111 1 111 111 ������ APPENDIX Al GROUNDWATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 11 of 11 E _ o ` N co V d Sample P m Z c = L m v w z W E O Location Date m a E E E y y y? �, c .r d C _ E E E E y O. 7 i aJ w; G_ y O a co m w _ �_ w r co _ 3 a� L O C i d w R _ m a1 d m v, O O Z L) Q >n Q R m M U L U O U O = y -i a1 d co co O N = Z 7 co O O H co O M H U 2 a 0 H O. O co U j H 1C p O 0- N E NC 2L Ground Water Standard NE 3,500 10 700 2 10 1,000 300 15 50 1 20 20 1,000 10,000 250,000 500,000 NE 6.5-8.5 NE NE NE NE NE PZ-05 4/6/2014 -- -- 66 -- 128 -- -- -- -- 115,000 270,000 3,500 -- -- -- -- -- -- PZ-05 9/4/2014 - 143 -- 129 -- 877 567 -- 12.9 -- -- -- 306,000 765,000 -- -- -- -- -- -- -- PZ-05 4/1/2015 - 494 -- 83.4 -- 769 82.3 -- - - - 153,000 339,000 - 7.04 10.53 516 1.06 34 7.17 PZ-05 9/8/2015 - -- -- -- -- -- -- -- -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- PZ-05 3/7/2016 - 41,000 -- 2,500 52 -- 1,300,000 27 32,000 -- - - -- 63,000 150,000 - - - - - - - PZ-05 9/7/2016 - 740 -- 58 0.27 -- 6,800 120 -- - - -- 28,000 110,000 - -- - - - - -- PZ-05 3/27/2017 - 10,000 -- 510 5.8 30 -- 300,000 5.8 1,100 - - - -- 150,000 -- -- -- -- -- -- PZ-05 9/25/2017 - 6,000 B -- 380 0.93 11 - 250,000 2.7 880 - - - -- 210,000 450,000 - 6.86 18.75 581 1,268 46 2.52 PZ-05 3/5/2018 - 630 -- 370 1.6 3.2 J -- 230,000 1.6 2,000 - 2.5 J - - -- 140,000 340,000 - 6.96 11.01 447 -- 149 11.89 PZ-05 9/11/2018 - 8,000 -- 410 8 17 -- 170,000 3.7 5,300 - - - -- 140,000 360,000 - -- -- -- -- -- -- PZ-05 3/19/2019 - 2,000 -- 55 3.2 -- 3,400 37 - - - -- 55,000 160,000 - 5.78 8 210.6 120 173.5 4.39 PZ-05 9/3/2019 - 270 -- 75 7.6 -- 1,100 470 - - - - 170,000 400,000 - -- -- -- - -- -- PZ-05 4/1/2020 - 11,000 -- 180 8.1 17 -- 51,000 4.7 770 - - - - 35,000 150,000 - -- -- -- - -- -- PZ-05 4/6/2021 - -- -- -- -- -- -- -- -- -- - - - - - 19,000 110,000 - -- - - - - - Notes: All concentrations in micrograms per liter (ug/L) unless otherwise noted SU - standard units uS/cm - microSiemens per centimeter NTUs - Nephelometric Turbidity Units my - millivolts mg/L - milligrams per liter NE - Not established -- - Not sampled B - Detected in the method blank J - Estimated result < LOQ and > DL Bold with gray background indicates exceedance of NC Groundwater Standard Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). NSA - Location inaccessible; no sample collected NSB - Obstruction in well; no sample collected NSC - Well dry; no sample collected NSD - Insufficient volume; no sample collected NSE - Well damaged; no sample collected NSF - Pump broken; no sample collected NSG - Surface water location dry; no sample collected APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 1 of 10 Sample Location Date = a E i I a E •L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -i Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O � O y a 0 R O C s fL6 � •E m O l6 O f- cn 2 a y >y y L r R d O- E tlJ d d c) > V O U .2 V V y O- N U) Z w 7 0 V Q: E O :� +r R c MR r X O O a C N O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-01 4/29/1988 118 8 86 15 220 64,000 220,000 2,810 6.8 -- -- -- -- -- SS-01 7/13/1989 -- 100 -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-01 9/6/1990 -- 64 -- -- -- -- -- -- -- -- -- 7.9 -- -- -- -- -- SS-01 9/21/1990 140 4.8 200 520 40,000 352,000 12,000 7.18 11.6 490 -- -- -- SS-01 10/23/1991 109 150 108,000 248,000 12,000 7.9 17.2 381 -- -- -- SS-01 3/25/1992 4,150 3.4 5,000 15.8 64 250 9,400 185,000 14,000 5.8 11.3 126 - -- -- SS-01 9/29/1992 160 85 190 84,000 241,000 2,000 5.73 13.8 356 -- -- -- SS-01 3/31/1993 400 77 29 1,340 70,400 127,000 2,000 5.89 13 207 -- -- -- SS-01 9/17/1993 240 598 28 450 77,400 251,000 3,000 7.07 20.9 360 -- -- -- SS-01 3/30/1994 220 873 30 250 30,600 108,000 5,000 5.88 14 380 -- -- -- SS-01 9/30/1994 1,300 1,690 6 84 430 64,800 255,000 30,000 7.05 19.1 332 -- -- -- SS-01 3/31/1995 3,580 2,440 106 246 190 48,900 211,000 7.75 13.9 290 -- -- -- SS-01 9/29/1995 200 358 7 38 500 70,000 264,000 3,740 5.16 13.9 458 -- -- -- SS-01 3/30/1996 279 547 14 185 31,300 129,000 1,790 6.68 11 193 -- -- -- SS-01 9/27/1996 125 300 5 21 95 290 56,100 225,000 2,360 7.65 19 336 -- -- -- SS-01 3/29/1997 307 552 16 13 225 30,000 138,000 3,040 7.63 16 94 -- -- -- SS-01 9/17/1997 476 835 40 169 625 47,400 224,000 1,670 7.9 19 319 -- -- -- SS-01 3/27/1998 190 685 12 61 680 38,700 163,000 5,230 7.64 18.6 473 -- -- -- SS-01 9/30/1998 126 540 6 33 300 28,000 177,000 4,090 7.2 18 322 -- -- -- SS-01 3/31/1999 239 332 44 120 63,200 191,000 2,490 7.1 16 247 -- -- -- SS-01 9/29/1999 1,530 3,330 5 88 90 23,200 143,000 8,810 7.83 16 308 -- -- -- SS-01 3/16/2000 117 1,940 922 199 50,900 202,000 3,780 -- -- -- -- -- -- SS-01 9/15/2000 327 166 38 160 26,100 157,000 5,080 7.32 19 410 -- -- -- SS-01 3/23/2001 158 10 26,100 113,000 2,810 6.9 16 150 -- -- -- SS-01 10/4/2001 116 29 300 99,000 343,000 5,300 7.39 19 440 -- -- -- SS-01 3/28/2002 201 10 -- 27 320 41,900 177,000 3,180 7.03 11 400 -- -- -- SS-01 10/3/2002 317 767 52 750 73,300 300,000 3,070 -- 19 330 -- -- -- SS-01 3/25/2003 673 607 24 115 31,600 119,000 2,080 6.87 18 440 -- -- -- SS-01 10/2/2003 705 72 446 29,400 181,000 2,380 6.33 15 249 -- -- -- SS-01 4/28/2004 179 80 374 70,400 176,000 2,060 -- 11.7 281 -- -- -- SS-01 10/26/2004 145 132 36 209 58,800 217,000 2,620 -- -- 397 -- -- -- SS-01 4/27/2005 105 11 149 41,400 174,000 2,150 -- -- 294 -- -- -- SS-01 10/20/2005 347 84 453 15 55 288 47,600 213,000 9,500 -- -- 232 -- -- -- SS-01 10/19/2006 937 1,630 130 22 226 59,200 168,000 2,970 -- -- 423 -- -- -- SS-01 4/27/2007 446 1,240 18 188 27,400 128,000 3,600 -- -- 209 -- -- -- SS-01 11/19/2007 104 11 117 61,500 243,000 3,540 -- -- 371 -- -- -- SS-01 4/30/2008 170 242 21 238 56,300 171,000 2,690 -- -- 260 -- -- -- SS-01 10/29/2008 56.4 0.3 3 20.6 6 0.05 50.9 229 76,300 254,000 2,870 -- -- 392 -- -- -- SS-01 4/30/2009 64.8 77.8 5.4 8.3 9.9 15.9 302 52,300 211,000 4,470 -- -- 325 -- -- -- SS-01 8/26/2009 -- -- 72 -- 160 14 -- -- -- -- 45,000 -- -- 8.1 22 1,490 10 94 9.05 SS-01 10/12/2009 89 J 2.7 J 63 0.8 J 1.1 J 86 7.3 J 370 49,000 240,000 -- 7.83 13.1 2,380 8.9 160 12.7 SS-01 4/19/2010 190 64 240 12 400 33,000 190,000 4,900 8.12 11.97 557 63.1 199 10.68 SS-01 10/11/2010 52 J 1.1 J 71 1.6 J 160 16 J 36 640 40,000 240,000 -- 7.8 16.54 455 8 107 12.77 SS-01 4/20/2011 62 66 280 13 300 30,000 140,000 3,400 7.59 17.98 270 4 211 9.71 SS-01 10/18/2011 153 76.7 190 9.6 250 39,200 210,000 5,700 7.54 16.94 289 8.3 236 9.56 SS-01 3/16/20121 170 82.5 1 1 238 11 37,400 221,000 4,800 7.8 15.73 359 2.46 -27 11.3 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 2 of 10 Sample Location Date = a E i a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -j Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s _� .O m O l6 O cn 2 a y L L r R d O- E tlJ d d c) O U .2 V V y O- N U) Z w 7 0 Q: E O :� +r R c MR r X O O a C O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1A9 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-01 9/24/2012 147 94.1 146 10.2 450 47,700 257,000 -- 7.71 15.68 589 21.3 153 8.65 SS-01 4/17/2013 366 73.5 492 12.4 141 29,000 131,000 4,410 8.03 20.89 297 4.9 76.3 6.87 SS-01 9/9/2013 179 87.1 240 18.1 470 41,700 203,000 7,210 8.36 20.64 347 5.4 -173 9.4 SS-01 4/6/2014 -- 62.2 -- 137 60.6 -- -- - -- 70,000 224,000 4,100 7.93 9.59 381 5.1 142.2 11.65 SS-01 9/3/2014 122 -- 82.6 -- 264 64.7 -- -- -- -- 93,400 339,000 -- 7.99 21.12 396 8.01 47.4 7.32 SS-01 4/1/2015 146 -- 72.2 -- 291 58.6 -- -- -- -- 69,100 216,000 -- 7.75 17.09 552 3.1 39.6 9.74 SS-01 9/9/2015 7,600 -- 190 11 -- 12,000 6.2 J 660 -- -- -- -- 93,000 280,000 B -- -- -- -- -- -- -- SS-01 3/8/2016 240 -- 63 -- 350 20 -- -- -- -- 29,000 93,000 -- 8.88 9.1 439.5 -- 98.1 12.3 SS-01 9/7/2016 71 -- 67 -- 220 6.3 -- -- -- -- 35,000 200,000 -- -- -- -- -- -- -- SS-01 9/7/2016 57 -- 72 -- 210 5.2 -- -- -- -- 32,000 210,000 -- 8.6 21.9 298 3.6 49 8.1 SS-01 3/27/2017 160 -- 61 -- 1,400 800 -- 3.6 J -- -- -- 460,000 1,000,000 E 7.58 16.95 1.31 -- 68 10.6 SS-01 5/8/2017 590 B -- 57 -- 660 6.8 -- -- -- -- 23,000 150,000 -- -- -- -- -- -- -- SS-01 9/25/2017 130 B -- 84 -- 250 8.6 -- -- - -- 40,000 240,000 -- 8.03 20.21 322 3.33 61 8.23 SS-01 3/5/2018 55 -- 69 -- 140 9.2 -- -- -- -- 38,000 190,000 -- 8.06 11.11 289 3.2 186 10.28 SS-01 9/11/2018 150 -- 84 -- 470 22 -- -- -- -- 36,000 1,200,000 -- 8.07 21.8 380 6.07 101 5.84 SS-01 3/18/2019 230 -- 51 -- 590 7.4 -- -- -- -- 20,000 150,000 -- 7.72 11.7 211.8 9.98 212.9 13.45 SS-01 9/4/2019 250 -- 77 -- 380 11 -- -- -- -- 32,000 200,000 -- 8.11 19.6 292.7 12.4 -28.6 6.39 SS-01 2/17/2020 3,100 -- 64 -- 3,400 1.2 26 -- -- -- -- 23,000 150,000 -- 7.79 1 10.38 219 34.9 216 9.58 SS-01 2/24/2020 1,200 -- 63 -- 1,600 16 -- -- -- -- 25,000 170,000 -- 8.64 7.74 233 16.2 192 10.95 SS-01 4/1/2020 490 -- 59 -- 690 8.6 -- -- -- -- 26,000 150,000 -- 8.53 11.7 224.9 34.2 49.5 8.58 SS-01 9/23/2020 1,000 -- 82 -- 1,400 25 -- -- -- -- 31,000 200,000 -- 7.72 15.5 316.2 34.2 16.7 7.06 SS-01 4/6/2021 2,800 -- 66 -- 3,300 1.1 24 -- -- -- 20,000 170,000 -- 8.07 12.95 185 52 268 9.72 SS-01 10/21/2021 84 -- 73 -- 210 6.3 -- -- -- -- 40,000 200,000 -- 7.76 15.5 338 215 212 6.02 SS-01+150 2/17/2020 2,700 -- 61 -- 3,400 1.2 24 -- -- -- -- 21,000 150,000 -- 7.84 10.42 208 33.1 232 9.76 SS-01+150 2/24/2020 1,500 -- 67 -- 1,700 49 -- -- -- -- 34,000 180,000 -- 8.16 7.77 198 17.8 209 12.08 SS-01+550 2/17/2020 2,400 -- 60 -- 2,700 1 32 -- -- -- -- 26,000 160,000 -- 7.71 10.19 207 26.4 234 10.26 SS-01+550 2/24/2020 1,300 -- 65 -- 1,400 33 -- -- -- -- 33,000 170,000 -- 8.32 7.9 256 13.2 205 10.26 SS-01+850 2/17/2020 2,500 -- 59 -- 2,700 36 -- -- -- -- 29,000 160,000 -- 7.69 10.01 221 25.2 243 9.42 SS-01+850 2/24/2020 1,100 -- 66 -- 1,300 27 -- -- -- -- 33,000 180,000 -- 8.18 7.94 249 13.9 207 12.28 SS-02 9/21/1990 130 94 4.6 100 -- 1,140 47,000 141,000 15,000 7.52 14.6 607 -- -- -- SS-02 10/23/1991 -- 170 820 711 80 1,020 490,000 806,000 10,000 7.82 18 1,280 -- -- -- SS-02 3/26/1992 7,650 2.1 8,070 12.9 130 250 13,100 149,000 12,000 6.04 11.5 111 -- -- -- SS-02 9/30/1992 330 -- -- 7.3 550 183,000 474,000 3,000 6.07 15.1 778 -- -- -- SS-02 3/31/1993 208 675 327 350 70,400 185,000 4,000 5.81 14.1 341 -- -- -- SS-02 9/17/1993 470 1,270 722 2,300 154,000 523,000 4,000 7.48 22.2 754 -- -- -- SS-02 3/30/1994 220 32 1,120 117 165 320 40,000 143,000 -- 5.99 14A 692 -- -- -- SS-02 9/30/1994 120 28 470 356 24 325 135,000 397,000 37,900 7.39 18.6 573 -- -- -- SS-02 3/31/1995 165 526 332 41 750 102,000 342,000 -- 7.87 14.5 496 -- -- -- SS-02 9/29/1995 406 1,020 6 598 1,030 155,000 505,000 2,680 5.6 13.5 1,095 -- -- -- SS-02 3/30/1996 426 787 250 190 30,600 198,000 2,990 6.53 12 282 -- -- -- SS-02 9/27/1996 61 227 10 262 47 750 147,000 409,000 3,190 7.59 20 613 -- -- -- SS-02 3/29/1997 209 644 246 10 450 72,800 255,000 2,470 7.83 16 224 -- -- -- APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 3 of 10 Sample Location Date = a E i I a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -i Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s .O m O l6 O f- cn 2 a y L L r R d CL E tlJ d d c) V O U .2 V V y CL N U) Z w 7 0 V Q: E O :� +r R c MR r X O O a C d O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-02 9/17/1997 165 428 6 333 153 2,210 160,000 562,000 2,430 7.8 18 826 -- -- -- SS-02 3/27/1998 220 960 363 32 550 94,200 324,000 3,960 7.75 17.5 724 -- -- -- SS-02 9/30/1998 100 595 351 1,550 89,200 444,000 6,850 7.4 19 368 -- -- -- SS-02 3/31/1999 129 947 587 1,550 204,000 420,000 3,260 7.4 17 340 -- -- -- SS-02 9/29/1999 1,380 3,030 147 21 160 45,700 173,000 8,100 7.62 17 623 -- -- -- SS-02 3/16/2000 960 464 1,180 175,000 500,000 3,750 -- -- -- -- -- -- SS-02 9/15/2000 283 225 416 1,240 170,000 439,000 6,580 7.44 20 640 -- -- -- SS-02 3/23/2001 108 260 7 135 34 103 71,900 224,000 3,080 6.6 16 170 -- -- -- SS-02 10/4/2001 166 746 8 910 6,320 421,000 1,250,000 27,000 7.21 19 680 -- -- -- SS-02 3/28/2002 121 502 206 -- 320 127,000 405,500 2,970 7.39 11 510 -- -- -- SS-02 10/3/2002 220 494 549 1,110 266,000 517,000 4,280 5.84 18 130 -- -- -- SS-02 3/25/2003 1,570 1,280 6 264 24 162 90,300 234,000 1,910 6.03 18 1,260 -- -- -- SS-02 (FD) 3/25/2003 1,750 1,320 265 24 194 94,600 235,000 2,000 6.03 18 1,260 -- -- -- SS-02 10/2/2003 1,010 546 610 115,000 395,000 2,500 6.51 14 556 -- -- -- SS-02 4/28/2004 109 400 417 608 220,000 394,000 2,260 -- 12.7 623 -- -- -- SS-02 10/26/2004 216 839 582 2,000 276,000 554,000 3,060 -- -- 807 -- -- -- SS-02 4/27/2005 356 272 648 37,600 460,000 2,480 -- -- 737 -- -- -- SS-02 10/20/2005 72 1,120 330 48 546 240,000 571,000 3,400 -- -- 419 -- -- -- SS-02 10/19/2006 530 1,060 534 32 299 204,000 422,000 3,490 -- -- 550 -- -- -- SS-02 4/27/2007 389 811 488 333 439,000 303,000 4,420 -- -- 511 -- -- -- SS-02 11/19/2007 136 308 23 258 300,000 647,000 3,540 -- -- 908 -- -- -- SS-02 4/30/2008 278 254 46 285 159,000 371,000 2,740 -- -- 569 -- -- -- SS-02 10/29/2008 56.3 0.24 128 318 14.2 407 342,000 708,000 3,430 -- -- 1,070 -- -- -- SS-02 4/30/2009 60.8 89.4 222 19.2 499 201,000 518,000 3,390 -- -- 821 -- -- -- SS-02 8/26/2009 -- -- 71 -- 110 220 -- -- -- -- 310,000 -- -- 7.78 21.55 2,120 6.4 101 6.38 SS-02 10/12/2009 43 J 5.1 J 60 0.8 J 45 J 48 320 210,000 510,000 -- 7.8 13.29 3,360 8.7 123 12.95 SS-02 4/19/2010 64 260 260 420 150,000 390,000 6,300 7.61 10.57 632 60.1 181 10.21 SS-02 10/11/2010 1.1 J 69 1.4 J 270 310 8.9 6.4 J 1,200 250,000 660,000 -- 7.62 15.24 999 -- 113 8.29 SS-02 4/20/2011 63 270 150 4 630 120,000 360,000 3,000 7.55 18.62 602 4.2 241 9.7 SS-02 10/18/2011 74.9 181 266 470 202,000 582,000 7,300 7.36 17.63 536 4.6 248 9.7 SS-02 3/16/2012 71.8 171 65.8 1,600 152,000 614,000 6,300 7.55 15.36 781 3.4 14.5 11.52 SS-02 9/25/2012 97.6 236 301 1,600 400,000 858,000 -- 8.46 16.16 1,420 9.7 181 9.08 SS-02 4/17/2013 194 71.4 242 110 214 79,100 207,000 5,030 8.14 20.8 382 4.7 79.6 7.97 SS-02 9/10/2013 83 135 102 1,160 167,000 493,000 6,290 8.03 19.79 657 8.2 99.8 7.11 SS-02 4/6/2014 133 -- 56.4 -- 194 21.2 -- -- -- -- 87,000 277,000 5,000 8.88 13.98 445 7.52 138.1 12.13 SS-02 9/3/2014 -- 83.7 -- 68.6 11.1 -- -- -- -- 158,000 526,000 -- 8.14 23.42 733 2.45 61.3 5.09 SS-02 4/1/2015 -- 59 -- 96.1 16.7 -- -- -- -- 92,200 297,000 -- 8.13 15.03 508 1.81 9.6 8.13 SS-02 9/8/2015 260 J -- 100 1.1 J -- 450 70 -- -- -- -- 160,000 460,000 -- -- -- -- -- -- -- SS-02 3/8/2016 150 -- 65 -- 260 36 -- 1.7 -- -- -- 61,000 180,000 -- 8.41 8.5 368.4 -- 227.1 11.32 SS-02 9/7/2016 150 -- 81 -- 490 44 -- -- -- -- 86,000 300,000 -- 8.5 21.8 452 4.6 89 8.4 SS-02 3/27/2017 65 -- 74 -- 210 11 -- -- -- -- 68,000 250,000 B -- 7.2 16.14 403 1.8 169 9.62 SS-02 9/25/2017 86 B -- 88 -- 200 43 -- -- -- -- 88,000 310,000 -- 7.95 19.7 458 1.18 183.9 8.41 SS-02 3/5/2018 37 J -- 69 -- 160 27 -- -- -- -- 92,000 300,000 -- 7.99 9.93 457 4.6 179 11.75 SS-02 9/11/2018 -- 83 -- 250 52 -- -- -- -- 89,000 320,000 -- 7.86 22.1 533 4.8 110 5.12 SS-02 3/18/2019 150 -- 47 -- 530 23 -- -- -- -- 34,000 170,000 -- 6.89 10.7 249.7_+ 7.68 175.3 12.34 SS-02 9/3/2019 150 -- 80 -- 240 30 -- -- -- -- 60,000 250,000 -- 7.43 22.6 375.8 8.62 -15.4 6.3 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 4 of 10 Sample Location Date = a E i a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -j Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s _� .O m O l6 O cn 2 a y L L r R d CL E tlJ d d c) O U .2 V V y CL N U) Z w 7 0 Q: E O :� +r R c MR r X O O a C O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-02 2/17/2020 1,900 -- 60 -- 2,400 34 -- -- -- -- 30,000 160,000 -- 7.64 9.95 216 24.8 265 9.28 SS-02 2/24/2020 1,100 -- 68 -- 1,300 40 -- -- -- -- 42,000 190,000 -- 7.99 8.12 294 21.4 208 11.96 SS-02 4/1/2020 450 -- 47 -- 580 18 -- -- -- -- 38,000 150,000 -- 9.13 12.4 245.4 13.5 42.7 9.13 SS-02 (FD) 4/1/2020 400 -- 46 -- 600 18 -- -- -- -- 38,000 160,000 -- -- -- -- -- -- -- SS-02 9/23/2020 1,200 -- 74 -- 1,400 39 -- -- -- -- 49,000 230,000 -- 7.99 15.6 371.9 28.4 9 7.32 SS-02 4/6/2021 2,000 -- 58 82 -- 2,900 25 -- -- -- 26,000 170,000 -- 8.12 14.28 200 30.2 290 10.1 SS-02 10/21/2021 77 S -- 76 -- 200 7.7 -- -- -- -- 50,000 220,000 -- 7.76 14.53 358 7 191 7.5 SS-10 8/11/2009 -- -- 65 -- 12,000 400 -- -- -- -- 11,000 -- -- 7.13 20.63 1,890 42.9 -40 3.38 SS-15 8/11/2009 -- -- 52 -- 900 35 -- -- -- -- 7,500 -- -- 7.84 20.7 1,840 52.5 114 9.65 SS-20 8/11/2009 -- -- 58 -- 800 46 -- -- -- -- 8,200 -- -- 8.35 23.85 1,112 27.3 58 7.63 SS-20 4/21/2011 190 54 550 17 100 4,800 96,000 1,900 7.66 14.64 87 14.2 128 9.4 SS-20 9/24/2012 378 51.4 1,580 51.1 3,600 89,000 -- 7.3 15.55 146 10.3 159 8.55 SS-20 4/17/2013 788 56 1,050 19.8 5,590 55,000 2,760 7.53 19.76 283 7.2 158 8.7 SS-20 9/9/2013 456 60.3 1,170 48.4 274 3,610 78,000 2,280 7.37 21.69 97 9.7 24.2 8.37 SS-20 4/6/2014 126 -- 54.2 -- 269 6 -- -- -- -- 5,200 68,000 1,900 8.05 9.56 212 14.4 134.7 10.32 SS-20 9/3/2014 818 -- 73.7 -- 2,450 71.4 -- -- -- -- 3,600 97,000 -- 7.35 20.59 100 20.9 -12.5 5.33 SS-20 4/1/2015 2,320 -- 105 -- 4,840 99.1 -- -- -- -- 5,000 66,000 -- 7.72 14.85 103 7.26 7.2 7.59 SS-20 9/9/2015 4,700 -- 130 5.8 J -- 7,600 170 -- -- -- -- 3,900 90,000 B -- -- -- -- -- -- -- SS-20 3/8/2016 470 -- 53 -- 450 8.9 -- -- -- -- 4,300 65,000 -- 7.91 12.1 73.5 -- 113.9 8.72 SS-20 9/7/2016 310 -- 59 -- 1,100 36 -- -- -- -- 1,600 89,000 -- 7.6 19.4 80 3.2 59 8.4 SS-20 3/27/2017 2,400 -- 120 -- 4,700 1 A 280 -- -- -- -- 3,100 62,000 B -- 7.49 16.29 179 9.7 97.8 8.97 SS-20 9/25/2017 3,200 B -- 110 4.6 J -- 5,500 1.6 140 -- -- -- -- 2,900 69,000 -- 6.87 20.41 84 16.1 -22.3 6.04 SS-20 3/5/2018 120 -- 57 -- 420 23 -- -- -- -- 4,100 80,000 -- 7.62 10.77 74 7 201 9.63 SS-20 9/11/2018 370 -- 67 -- 1,600 85 -- -- -- -- 3,300 75,000 -- 7.56 21.3 116.5 24.3 70 5.11 SS-20 3/18/2019 550 -- 54 -- 680 8.1 -- -- -- -- 4,300 84,000 -- 7.48 10.5 70.3 13.2 219.4 8.86 SS-20 9/3/2019 3,700 -- 110 -- 5,300 2 130 -- -- -- -- 3,100 94,000 -- 6.03 20.7 101.4 23.9 16.8 6.56 SS-20 2/17/2020 2,200 -- 51 -- 2,500 1 19 -- -- -- -- 8,700 79,000 -- 7.53 9,000 86 23 227 8.96 SS-20 2/24/2020 1,400 -- 49 -- 1,800 16 -- -- -- -- 8,800 86,000 -- 8.56 7.1 97 15.8 190 9.83 SS-20 4/1/2020 1,800 -- 47 -- 1,600 13 -- -- -- -- 9,300 76,000 -- 6.59 11.8 88.1 23.4 73.1 9.41 SS-20 9/23/2020 4,800 -- 59 -- 6,000 2 88 -- -- -- -- 8,000 120,000 -- 6.88 15.7 128.9 85.6 1,280 7.3 SS-20 4/6/2021 2,300 -- 45 -- 2,600 42 -- -- -- 4,300 90,000 -- 8.04 17.09 53 37.7 264 7.67 SS-20 10/21/2021 170 -- 38 -- 480 27 -- -- -- -- 9,200 82,000 -- 7.58 16.35 127 600 181 7.35 SS-25 8/11/2009 -- -- 60 -- 590 53 -- -- -- -- 28,000 -- -- 8.35 22.07 1,830 32.1 75 7.57 SS-25 4/21/2011 150 50 470 8.2 40 5,000 100,000 1,900 7.59 14.79 89 15.5 128 9.66 SS-25 9/24/2012 508 52.2 1,580 103 22 39,800 156,000 -- 7.19 15.94 257 13.6 145 8.44 SS-25 4/17/2013 820 54.9 1,170 32.6 5,810 62,000 2,940 7.49 19.64 336 6.8 163 8.9 SS-25 9/9/2013 345 54.3 809 23.8 60.9 3,650 82,000 2,590 7.39 20.34 134 5.9 23.7 8.26 SS-25 4/6/2014 310 -- 51.1 -- 555 13.8 -- -- -- -- 5,500 75,000 2,000 7.12 9.64 83 11.9 86.6 10.42 SS-25 9/3/2014 2,000 -- 83.3 -- 3,880 79.3 -- -- -- -- 3,400 100,000 -- 7.41 21.37 92 32.1 -11.9 5.63 SS-25 4/1/2015 292 -- 53.4 -- 649 10.6 -- -- -- -- 5,200 74,000 -- 7.14 14.95 89 9.45 16.3 5.93 SS-25 9/9/2015 660 -- 63 -- 1,500 58 -- -- -- -- 3,700 85,000 B -- -- -- -- -- -- -- SS-25 3/8/2016 1,700 -- 92 -- 2,500 1.8 90 -- -- -- -- 4,700 83,000 -- 8.29 12.8 72.9 -- 63 11.8 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 5 of 10 Sample Location Date = a E i a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -j Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s _� .O m O l6 O cn 2 a y L L r R d O- E tlJ d d c) O U .2 V V y CL N U) Z w 7 0 Q: E O :� +r R c MR r X O O a C O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-25 9/7/2016 1,400 -- 77 -- 3,200 81 -- -- -- -- 1,700 86,000 -- 8 19.7 64 2.9 43 8.2 SS-25 3/27/2017 390 -- 62 -- 590 9.4 -- -- -- -- 3,100 73,000 B -- 7.55 16.72 121 7.4 101 8.02 SS-25 9/25/2017 780 B -- 56 1.6 J -- 1,200 0.29 J 27 -- -- -- -- 2,500 74,000 -- 7.13 19.99 88 11.5 15.3 6.9 SS-25 3/5/2018 210 -- 47 -- 400 15 -- -- -- -- 4,200 78,000 -- 7.77 11.44 78 13.5 191 8.84 SS-25 9/11/2018 270 -- 53 -- 1,100 32 -- -- -- -- 2,600 88,000 -- 7.19 21.4 122.7 18.3 82.8 5.04 SS-25 3/18/2019 610 -- 51 -- 700 5.5 -- -- -- -- 4,400 69,000 -- 7.84 10.3 70.3 14.4 226.5 8.44 SS-25 9/3/2019 1,700 -- 70 -- 2,700 45 -- -- -- -- 3,200 100,000 -- 6.2 21.2 99.8 60.12 8.9 6.02 SS-25 2/17/2020 2,800 -- 55 -- 3,600 1.5 25 -- -- -- -- 8,500 81,000 -- 7.5 9.62 79 33.5 251 8.82 SS-25 2/24/2020 1,300 -- 46 -- 1,500 9.8 -- -- -- -- 8,700 93,000 -- 8.42 7.3 86 24.9 199 10.2 SS-25 4/1/2020 1,700 -- 48 -- 1,500 9.5 -- -- -- -- 9,200 70,000 -- 6.85 11.7 88.7 20.8 71 9.8 SS-25 9/23/2020 4,400 -- 58 -- 4,900 1.8 60 -- -- -- -- 8,300 110,000 -- 6.81 15.6 125 91 1,157 7.46 SS-25 4/6/2021 2,600 -- 48 -- 2,800 26 -- -- -- 8,000 90,000 -- 8.58 12.62 78 59.2 199 9.6 SS-25 10/21/2021 120 -- 37 -- 360 12 -- -- -- -- 9,000 83,000 -- 7.52 15.71 129 17.1 177 6.64 SS-30 8/11/2009 -- -- 72 -- 150 25 -- -- -- -- 95,000 -- -- 8.53 22.82 5,250 21.7 57 8.1 SS-30 1/5/2011 -- -- 77 -- 330 130 -- -- -- -- 63,000 370,000 -- 8.63 3.9 388 6.9 132 10.43 SS-30 4/20/2011 67 220 8.9 330 27,000 160,000 2,800 7.35 17.87 283 3.9 238 9.47 SS-30 9/24/2012 163 88 175 19.8 280 84,700 312,000 -- 7.76 15.38 567 14.9 152 8.77 SS-30 4/17/2013 352 76.4 455 13.2 194 31,000 144,000 18,200 7.82 21.06 268 8.7 62.1 6.24 SS-30 9/9/2013 158 86.2 237 18.6 498 45,600 220,000 4,990 8.06 20.44 318 4.59 17.9 7.13 SS-30 4/6/2014 -- 61.6 -- 159 -- - -- -- 33,200 170,000 4,000 7.97 9.47 270 5.52 159.3 16.21 SS-30 9/3/2014 145 -- 84.3 -- 277 16.4 -- - -- -- 43,600 253,000 -- 8.41 21.41 308 11 16.6 6.96 SS-30 4/1/2015 173 -- 67.1 -- 291 11.2 -- - -- -- 43,200 191,000 -- 7.92 16.48 348 6.3 6.2 7.66 SS-30 9/9/2015 -- 86 -- 110 5.8 J -- -- -- -- 98,000 280,000 B -- -- -- -- -- -- -- SS-30 3/8/2016 870 -- 67 -- 1,000 32 -- - -- -- 31,000 150,000 -- 8.49 9.3 275 -- 164.2 12.04 SS-30 9/7/2016 470 -- 70 -- 970 44 -- -- -- -- 48,000 270,000 -- 8.5 21.6 357 2.8 48 8.5 SS-30 3/27/2017 160 -- 70 -- 370 10 -- -- -- -- 41,000 200,000 B -- 7.76 16.05 343 2.8 114 10.33 SS-30 9/25/2017 200 B -- 91 -- 360 11 -- -- -- -- 41,000 220,000 -- 7.89 20.88 335 3.76 66.3 7.84 SS-30 3/5/2018 66 -- 64 -- 180 9.8 -- -- -- -- 51,000 240,000 -- 7.96 16.99 357 9.7 197 10.97 SS-30 9/11/2018 130 -- 71 -- 480 26 -- -- -- -- 52,000 260,000 -- 8.1 21.3 442 10.2 106 6.1 SS-30 3/18/2019 360 -- 54 -- 880 19 -- -- -- -- 24,000 150,000 -- 7.89 11.5 238.7 13 216.7 10.14 SS-30 9/4/2019 350 -- 86 -- 570 14 -- -- -- -- 34,000 220,000 -- 7.99 19.5 301.4 14.4 -28.6 6.39 SS-30 2/17/2020 3,200 -- 64 -- 3,600 1.5 62 -- -- -- -- 27,000 200,000 -- 7.59 10.08 240 9.65 259 9.85 SS-30 2/24/2020 1,800 -- 66 -- 2,500 65 -- -- -- -- 32,000 210,000 -- 8.45 7.58 269 24.2 202 10.23 SS-30 4/1/2020 1,300 -- 59 -- 1,800 18 -- -- -- -- 31,000 160,000 -- 7.36 11.8 261.9 24.1 63.3 10.12 SS-30 9/23/2020 3,800 -- 81 -- 4,300 1.4 56 -- -- -- -- 37,000 220,000 -- 7.48 15.5 339.8 61.1 18.2 7.46 SS-30 4/6/2021 3,800 -- 65 6.1 -- 4,100 1.4 32 -- -- -- 25,000 200,000 -- 8.09 12.89 217 64 252 9.56 SS-30 10/21/2021 140 -- 60 -- 430 20 -- -- -- -- 48,000 220,000 -- 7.85 15.39 431 44.7 183 6.2 SS-35 9/8/2015 -- 100 -- 72 J 28 -- -- -- -- 170,000 470,000 -- -- -- -- -- -- -- SS-40 8/26/2009 -- -- 91 -- 80 22 -- -- -- -- 300,000 -- -- 7.82 21.33 2,050 7.1 89 7.89 SS-40 4/20/2011 57 59 330 59 0.25 2.1 810 110,000 270,000 2,900 7.3 17.54 494 4.6 223 10.23 SS-40 9/25/2012 112 139 39 2,000 297,000 755,000 -- 8 14.75 1,260 9.8 174 9.28 SS-40 4/17/2013 221 60.7 294 25.7 179 73,200 195,000 4,980 8.23 19.9 329 4.9 68.9 6.94 SS-40 9/10/20131 89.6 92.5 15.5 20.4 1,440 165,000 450,000 6,230 1 7.92 19.75 610 5.7 87.8 1 8.43 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 6 of 10 Sample Location Date = a E i I a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -i Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s _� .O m O l6 O f- cn 2 a y L L r R d O- E tlJ d d c) O U .2 V V y O- N U) Z w 7 0 Q: E O :� +r R c MR r X O O a C O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-40 4/6/2014 -- 53.2 - 185 11.5 -- -- - -- 81,600 256,000 16,200 9.18 13.95 397 8.31 138.7 11.39 SS-40 9/3/2014 -- 86.5 -- 58.1 9.5 -- -- -- -- 152,000 473,000 -- 8.06 23.72 689 2.45 69.4 4.91 SS-40 4/1/2015 -- 58.5 -- 154 10.8 -- -- -- -- 84,200 264,000 -- 8.01 18.32 469 4.19 13.5 8.25 SS-40 9/8/2015 210 J -- 110 -- 370 48 -- -- -- -- 160,000 440,000 -- -- -- -- -- -- -- SS-40 3/8/2016 220 -- 62 -- 310 12 -- -- -- -- 57,000 180,000 -- 8.41 8.9 332.7 -- 238.2 13.44 SS-40 9/7/2016 540 -- 94 -- 1,300 100 -- -- -- -- 78,000 290,000 -- 8.2 21 427 3.2 121 7.7 SS-40 3/27/2017 91 -- 67 -- 240 7.9 -- -- -- -- 65,000 230,000 B -- 7.98 16.88 357 1.8 154 111.1 SS-40 9/25/2017 100 B -- 85 -- 210 17 -- -- -- -- 80,000 280,000 -- 8.07 19.85 425 3.24 121 8.57 SS-40 3/5/2018 45 -- 64 -- 130 5.8 -- -- -- -- 84,000 290,000 -- 8.19 9.79 417 2.6 190 11.82 SS-40 9/11/2018 -- 79 -- 210 14 -- -- -- -- 78,000 300,000 -- 7.73 22 498 5.03 99.5 4.91 SS-40 3/18/2019 160 -- 47 -- 480 9.3 -- -- -- -- 32,000 150,000 -- 7.44 10.4 230.8 7.92 175.8 12.25 SS-40 9/3/2019 75 -- 77 -- 190 10 -- -- -- -- 51,000 230,000 -- 7.04 21.9 336.2 4.27 -1.4 5.58 SS-40 2/17/2020 2,600 -- 60 -- 3,000 1 29 -- -- -- -- 27,000 150,000 -- 7.67 8.96 200 11.13 248 11.18 SS-40 2/24/2020 1,200 -- 66 -- 1,300 17 -- -- -- -- 37,000 190,000 -- 7.85 7.52 268 10.3 207 13.79 SS-40 4/1/2020 280 -- 48 -- 400 9 -- -- -- -- 24,000 110,000 -- 8.65 11.9 192.4 10.9 29.2 9.97 SS-40 9/23/2020 550 -- 73 -- 740 22 -- -- -- -- 42,000 230,000 -- 8.1 15.2 296.6 22.4 2.5 7.01 SS-40 4/6/2021 2,100 -- 57 -- 2,000 14 -- -- -- 23,000 170,000 -- 8.1 13.76 181 26.1 286 8.11 SS-40 10/21/2021 83 -- 74 -- 200 8.5 -- -- -- -- 50,000 230,000 -- 7.8 14.95 364 3.2 193 6.72 SS-50 8/11/2009 -- -- 29 -- 2,900 180 -- -- -- -- 5,600 -- -- 7.79 25.4 1,180 32 -21 8.52 SS-50 4/21/2011 120 36 1,100 85 130 3,700 71,000 2,000 6.91 14.66 85 16.3 92 9.88 SS-50 9/25/2012 410 41.9 1,640 110 140 72,000 -- 8.65 17.58 161 9.6 16 8.76 SS-50 4/17/2013 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 9/9/2013 -- -- -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 4/6/2014 -- -- -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 9/3/2014 -- -- -- -- - -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 4/1/2015 886 -- 49.4 -- 4,620 168 -- -- -- -- 2,900 63,000 -- 7 13.5 90 18.8 -6.3 13.7 SS-50 9/9/2015 160,000 -- 2,900 1.6 J 250 -- 850,000 100 16,000 -- -- -- -- 640 J 75,000 B -- -- -- -- -- -- -- SS-50 3/8/2016 930 -- 46 -- 1,700 46 -- -- -- -- -- -- -- 7.89 12.5 71.9 -- 111.8 9.84 SS-50 9/7/2016 410 -- 49 -- 2,900 180 -- -- -- -- 99,000 -- 8 22.8 121 3.6 50 6.9 SS-50 3/27/2017 230 -- 46 -- 650 13 -- -- -- -- 1,600 130,000 -- 6.46 18.32 9 47.4 195 11.54 SS-50 9/25/2017 960 B -- 52 2.1 J -- 2,200 0.56 J 93 -- -- -- -- 1,300 23,000 -- 6.86 20.27 84 14.7 13.2 7.71 SS-50 3/5/2018 86 -- 40 -- 530 22 -- -- -- -- 2,900 68,000 -- 7.38 11.41 74 14.8 213 11.87 SS-50 9/11/2018 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- SS-50 3/18/2019 240 -- 40 -- 740 25 -- -- -- -- 3,700 72,000 -- 7.45 9.7 73 11.8 145.8 8.69 SS-50 9/3/2019 1,400 -- 54 -- 3,000 93 -- -- -- -- 1,400 78,000 -- 5.22 22 104.2 24.8 6.8 6.85 SS-50 4/1/2020 660 -- 47 -- 2,300 96 -- -- -- -- 2,800 74,000 -- 7.6 12.4 74.3 31.5 22.1 9.81 SS-50 9/23/2020 820 -- 58 -- 4,400 1.1 180 -- -- -- -- 1,200 71,000 -- 7.25 15.1 68.3 28 1,470 8.03 SS-50 4/6/2021 1,700 -- 47 14 -- 2,200 35 -- -- -- 3,700 69,000 -- 7.63 15.84 63 47.4 290 9.42 SS-50 10/21/2021 1,300 -- 170 -- 25,000 6.5 710 -- -- -- -- 1,100 72,000 -- -- -- -- -- -- -- SS-60 8/26/2009 -- -- 140 -- 280 980 -- -- -- -- 350,000 -- -- 7.06 20.34 4,040 65.9 10 6.69 SS-60 4/21/2011 68 61 240 11 4.1 120 130,000 270,000 2,700 7.15 15.9 446 14.3 177 8.89 SS-60 9/25/2012 120 75.9 312 85 58,100 191,000 -- 8.43 12.53 337 11.7 179 8.75 SS-60 4/17/2013 534 63.4 667 43.8 164,000 274,000 4,170 7.8 20.15 380 8.6 70.6 1 10.79 SS-60 9/10/20131 103 120 116 75.5 2,120 275,000 663,000 6,150 7.47 20.97 423 8.4 87.6 8.17 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 7 of 10 Sample Location Date = a E i a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -j Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s _� .O m O l6 O f- cn 2 a y L L r R d CL E tlJ d d c) O U .2 V V y CL N U) Z w 7 0 Q: E O :� +r R c MR r X O O a C O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-60 4/6/2014 154 -- 64.9 -- 175 5.7 -- -- -- -- 119,000 234,000 3,300 7.59 13.63 421 5.94 186.4 12.81 SS-60 9/4/2014 -- 127 -- 709 537 -- 16.8 -- -- -- 290,000 717,000 -- 7.13 20.84 845 7.26 -3.4 4.53 SS-60 4/1/2015 1,320 -- 93 -- 2,140 69.5 -- -- -- -- 159,000 359,000 -- 7.07 9.72 538 18.8 1.56 6.6 SS-60 9/8/2015 190 J -- 57 -- 410 33 -- -- -- -- 13,000 110,000 -- -- -- -- -- -- -- SS-60 3/8/2016 510 -- 68 -- 410 8.6 -- 3 -- -- -- 120,000 270,000 -- 7.83 9.3 375.2 -- 252.1 10.62 SS-60 9/7/2016 780 -- 130 -- 2,400 160 -- -- -- -- 250,000 490,000 -- 7.5 20.1 666 4.7 39 6.5 SS-60 3/27/2017 4,500 -- 160 5.5 -- 7,800 2.7 190 -- 1.5 J -- -- -- 190,000 410,000 B -- 7.08 14.69 4 297 194 7.03 SS-60 9/25/2017 34 BJ -- 130 -- 260 89 -- -- -- -- 270,000 570,000 -- 7.31 18.92 763 1.16 54 3.31 SS-60 3/5/2018 140 -- 93 -- 280 19 -- -- -- -- 170,000 370,000 -- 7.13 10.08 522 44.7 156 12.41 SS-60 9/11/2018 -- 120 -- 810 330 -- -- -- -- 240,000 620,000 -- 7.33 21.5 916 4.97 76.3 2.06 SS-60 3/18/2019 560 -- 41 -- 750 7.9 -- -- -- -- 13,000 78,000 -- 7.19 11.2 90.7 12.6 213 12.51 SS-60 4/1/2020 650 -- 54 -- 690 7.3 -- -- -- -- 62,000 160,000 -- 7.4 11.4 231.7 13.7 78.9 7.91 SS-60 9/23/2020 200 -- 53 -- 490 25 -- -- -- -- 9,300 110,000 -- 8.55 15.5 119.3 6.12 -8.8 6.86 SS-60 4/6/2021 1,500 -- 53 -- 1,200 7.8 -- -- -- 37,000 140,000 -- 7.84 13.04 153 7.5 294 8.09 SS-60 10/21/2021 61 -- 64 -- 210 11 -- -- -- -- 13,000 92,000 -- 7.61 14.47 150 0 198 6.6 SS-65 9/8/2015 780 -- 80 1.3 J -- 1,300 96 -- -- -- -- 44,000 150,000 -- -- -- -- -- -- -- SS-70 8/26/2009 -- -- 120 -- 1,100 250 -- -- -- -- 65,000 -- -- 6.94 20.55 2,520 6.8 91 6.44 SS-70 4/21/2011 160 50 380 5.8 0.12 53 23,000 92,000 2,300 6.99 16.39 138 8.3 189 10.27 SS-70 9/25/2012 120 82.4 303 58.7 61,300 203,000 -- 8.15 12.58 367 10.1 143 8.34 SS-70 4/17/2013 694 51.3 986 13.4 24,100 89,000 3,330 7.98 19.28 129 7.3 60.9 7.67 SS-70 9/10/2013 135 58.8 299 13.6 1,390 28,600 123,000 3,510 7.89 20.87 419 7.6 85.3 8.07 SS-70 4/6/2014 374 -- 47.7 -- 479 5.3 -- -- -- -- 21,000 86,000 2,300 7.5 13.28 125 8.3 165 9.85 SS-70 9/4/2014 -- 79.9 -- 305 71.1 -- -- -- -- 35,000 146,000 -- 7.7 21.04 217 3.68 22.3 7.26 SS-70 4/1/2015 147 -- 55.1 -- 282 8.4 -- -- -- -- 27,300 93,000 -- 7.36 11.13 159 1.56 5.01 8.21 SS-70 9/8/2015 95 J -- 71 -- 260 27 -- -- -- -- 33,000 160,000 -- -- -- -- -- -- -- SS-70 3/8/2016 640 -- 47 -- 540 5.7 -- -- -- -- 18,000 90,000 -- 8.17 10 112.5 -- 244.2 11.35 SS-70 9/7/2016 160 -- 52 -- 470 18 -- -- -- -- 1,600 81,000 -- 7.5 19.9 93 5.3 26 7.6 SS-70 3/27/2017 170 -- 56 -- 270 4.2 J -- -- -- -- 21,000 93,000 B -- 7.5 16.52 722 6.2 170 7.92 SS-70 9/25/2017 350 B -- 62 1.3 J -- 530 28 -- -- -- -- 11,000 74,000 -- 7.53 19.21 122 7.69 158.8 7.14 SS-70 3/5/2018 78 -- 44 -- 150 7.2 -- -- -- -- 20,000 91,000 -- 7.32 10.96 120 1.4 197 7.9 SS-70 9/11/2018 86 -- 60 -- 480 31 -- -- -- -- 8,000 97,000 -- 7.67 21.4 152 4.94 111 5.3 SS-70 3/18/2019 360 -- 45 -- 500 5.7 -- -- -- -- 14,000 83,000 -- 7.5 11 96 10.2 209.7 10.53 SS-70 9/3/2019 91 -- 55 -- 410 27 -- -- -- -- 16,000 110,000 -- 6.72 22 137.7 4.27 2.3 5.14 SS-70 4/1/2020 630 -- 43 -- 840 14 -- -- -- -- 12,000 77,000 -- 7.21 11.9 86.7 14.4 62.9 9.74 SS-70 9/23/2020 170 -- 57 -- 350 12 -- -- -- -- 12,000 96,000 -- 8.21 15.7 75.4 5.61 12.8 8.31 SS-70 4/6/2021 1,400 -- 48 -- 1,300 8.3 -- -- -- 9,500 89,000 -- 7.87 13.58 76 6.3 290 7.95 SS-70 10/21/2021 80 -- 73 -- 170 7.5 -- -- -- -- 53,000 230,000 -- 7.81 14.6 364 20.2 200 6.3 SS-75 9/8/2015 -- 78 -- 230 26 -- 9.9 J -- -- -- 41,000 170,000 -- -- -- -- -- -- -- SS-80 8/26/2009 -- -- 120 -- 250 25 -- -- -- -- 82,000 -- -- 7.13 20.63 5,190 5.8 100 8.34 SS-80 4/21/2011 110 56 310 99 27,000 120,000 2,100 6.8 15.52 161 6.8 92 10.61 SS-80 9/25/2012 192 87 263 15.9 74,600 270,000 -- 8.53 11.69 399 4.8 205 9.08 SS-80 4/17/2013 643 52.5 921 7.5 27,600 88,000 3,170 7.43 20.14 139 7.6 70.8 7.14 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 8 of 10 Sample Location Date = a E i I a E 'L m m E -O m I c) O L s L) y CL Q O L) i O L O d I -i Gs N C m a V L d a G1 d U) d in 0 O N Z N y L :' z m m w 7 U) pl O O y a 0 R O C s _� .O m O l6 O f- cn 2 a y L L r R d O- E tlJ d d c) O U .2 V V y O- N U) Z w 7 0 Q: E O :� +r R c MR r X O O a C O > O J 0 y G NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1A9 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE SS-80 9/10/2013 110 71.5 211 8.3 265 47,600 152,000 3,430 7.67 21.64 417 6.9 87.9 7.92 SS-80 4/6/2014 180 -- 53.7 -- 328 -- - -- -- 17,500 84,000 2,400 7.39 13.87 106 8.7 136.2 11.78 SS-80 9/4/2014 149 -- 81.1 -- 436 16.8 -- -- -- -- 30,100 155,000 -- 8.09 21.23 245 11.3 17.5 6.98 SS-80 4/1/2015 246 -- 58.1 -- 382 7.1 -- -- -- -- 25,500 89,000 -- 7.88 12.8 162 4.37 4.37 9.57 SS-80 9/8/2015 -- 84 -- 180 14 J -- -- -- -- 41,000 170,000 -- -- -- -- -- -- -- SS-80 3/8/2016 640 -- 54 -- 530 6.4 -- -- -- -- 24,000 110,000 -- 8.45 8.8 124.3 -- 236.8 11.32 SS-80 9/7/2016 140 -- 63 -- 430 9.7 -- -- -- -- 13,000 110,000 -- 7.7 21 98 2.7 53 8.2 SS-80 3/27/2017 100 -- 62 -- 200 2.5 J -- -- -- -- 21,000 110,000 B -- 7.97 16.04 156 1.7 165 8.96 SS-80 9/25/2017 98 B -- 71 -- 250 6.8 -- -- -- -- 21,000 110,000 -- 7.68 18.95 158 2.97 146.5 8.89 SS-80 3/5/2018 74 -- 51 -- 190 10 -- -- -- -- 21,000 96,000 -- 7.57 10.92 127 0.9 185 15.18 SS-80 9/11/2018 490 -- 73 -- 1,200 34 -- -- -- -- 16,000 110,000 -- 8.19 21 191 5.55 109 5.72 SS-80 3/18/2019 400 -- 45 -- 560 -- -- -- -- 13,000 90,000 -- 7.64 9.9 96.8 9.89 196.2 9.74 SS-80 9/3/2019 240 -- 67 -- 500 9.9 -- -- -- -- 13,000 130,000 -- 6.65 21.7 142.6 6.32 8.1 5.64 SS-80 4/1/2020 510 -- 50 -- 680 5.8 -- -- -- -- 10,000 76,000 -- 7.24 11.7 87.3 13.3 83A 10.86 SS-80 9/23/2020 470 -- 65 -- 840 17 -- -- -- -- 10,000 120,000 -- 8.04 15.1 123.3 9.46 19.1 9.02 SS-80 4/6/2021 1,100 -- 56 -- 1,200 6.8 -- -- -- 11,000 100,000 -- 7.88 12.8 81 8.9 288 9.26 SS-80 10/21/2021 85 -- 76 -- 200 15 -- -- -- -- 60,000 240,000 -- 7.81 14.27 413 3.1 196 6.52 SS-90 1/4/2011 -- -- 44 -- 1,200 16 -- -- -- -- 26,000 97,000 -- 8.42 3 390 4.2 152 10.55 SS-90 1/4/2011 -- -- 44 -- 1,200 16 -- -- -- -- 26,000 97,000 -- 8.42 3 390 4.2 152 10.55 SS-90 4/20/2011 83 57 330 21 2.1 330 56,000 130,000 2,600 6.69 16.92 292 4.6 293 11.68 SS-90 9/25/2012 121 115 212 30.4 980 202,000 511,000 -- 8.14 11.93 840 12.1 207 8.96 SS-90 4/17/2013 491 56 709 17.4 34.9 38,900 127,000 3,690 7.94 19.71 203 6.9 66 7.59 SS-90 9/10/2013 148 86.6 265 32.4 642 121,000 283,000 4,920 7.86 22.19 429 7.9 91.6 7.26 SS-90 4/6/2014 154 -- 48.5 -- 274 9.4 -- -- -- -- 45,300 151,000 3,300 8.87 15.09 255 5.62 120.9 15.44 SS-90 9/3/2014 -- 90.8 -- 77.5 16 -- -- -- -- 94,500 357,000 -- 7.48 23.51 518 5.56 65.3 6.43 SS-90 4/1/2015 125 -- 58 -- 189 9 -- -- -- -- 51,400 166,000 -- 8.81 11.35 318 5.95 5.95 9.92 SS-90 9/8/2015 290 J -- 100 1 J -- 530 80 -- -- -- -- 110,000 340,000 -- -- -- -- -- -- -- SS-90 3/8/2016 390 -- 58 -- 470 11 -- -- -- -- 33,000 110,000 -- 8.35 8.5 210.3 -- 239.3 13.08 SS-90 9/7/2016 40 -- 73 -- 230 17 -- -- -- -- 49,000 200,000 -- 8 20.8 2,886 1.8 48 9 SS-90 3/27/2017 160 -- 62 -- 340 12 -- -- -- -- 40,000 100,000 B -- 8.2 16.52 256 1.9 152 11.09 SS-90 9/25/2017 72 B -- 79 -- 160 10 -- -- -- -- 48,000 200,000 -- 7.88 19.1 284 1.47 153.2 8.7 SS-90 3/5/2018 51 -- 54 -- 120 5.8 -- -- -- -- 48,000 170,000 -- 7.78 9.59 262 2.2 192 10.09 SS-90 9/11/2018 54 -- 72 -- 280 15 -- -- -- -- 46,000 210,000 -- 8.66 21.2 387 4.95 114 6.8 SS-90 3/18/2019 140 -- 45 -- 340 7.4 -- -- -- -- 20,000 110,000 -- 7.54 9.8 150.9 8.02 170.9 12.29 SS-90 9/3/2019 71 -- 69 -- 230 8.2 -- -- -- -- 31,000 160,000 -- 6.59 22.2 229.1 12.9 12.9 6.44 SS-90 2/17/2020 1,900 -- 49 -- 1,900 11 -- -- -- -- 17,000 120,000 -- 7.52 8.37 129 12.8 234 11.43 SS-90 2/24/2020 780 -- 52 -- 850 8.6 -- -- -- -- 22,000 130,000 -- 8.1 7.44 162 5.3 198 16.19 SS-90 4/1/2020 200 -- 47 -- 300 8.3 -- -- -- -- 22,000 110,000 -- 8.68 11.3 154.5 10.7 59.2 12.61 SS-90 9/23/2020 200 -- 64 -- 400 17 -- -- -- -- 24,000 140,000 -- 8.45 14.8 208.8 10.7 40.8 9.74 SS-90 4/6/2021 1,400 -- 55 -- 1,500 12 -- -- -- 14,000 110,000 -- 8.04 12.21 118 12 271 9.71 SS-90 10/21/2021 53 -- 65 -- 140 5.4 -- -- -- -- 29,000 140,000 -- 7.61 14.25 235 0 208 6.12 SS-95 2/17/2020 360 -- 62 -- 660 330 -- -- -- -- 94,000 270,000 -- 7.34 9.51 378 8.2 165 8.55 SS-95 2/24/2020 140 -- 66 -- 650 540 -- 5.1 -- -- -- 160,000 390,000 -- 8.08 7.51 599 18.5 200 10.12 APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 9 of 10 Sample Location Date E E Q V .i N i Q E i f6 m E f6 c� E 2 .E t c� O O O U O i d J N M a 01 c m Z �+ 7 i d Z C N d cn L in U C N z w +' = z r w 7 cn O � O y N 0 f0 O H G fL6 C) O L O f4 O H m O. i y r >d y N M O E y N d H U > V O U U_ w E V V y Q fn cn -ti 7 H 0 V E c _ O l6 .r = l6 C 8 r x O O a C N O > O J N N o f NC 2B Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 15000 1.49 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE MW-001 9/30/1994 2,580 16 44 23,200 6,490 35 2,950 7875000 25230,000 258,000 7.39 22.5 3,140 -- - - MW-001 3/31/1995 660 5,150 2,360 155 8,880 794,000 2,540,000 459,000 7.8 17.5 3,680 - - - MW-001 9/29/1995 156 5,240 8 4,880 1,030 801,000 2,660,000 4,950 5.41 14.8 4,220 - - - MW-001 3/30/1996 112 10 2 5,020 5,400 2,080 -- 2,340,000 6,650 7.18 15 3,050 - - MW-001 9/27/1996 167 < 10 -- 9 4,530 66 1,700 1,010,000 2,700,000 4,040 7.32 23 1,510 - - MW-001 3/17/1997 164 10 3,660 5,400 55 608 1,160,000 3,000,000 6,430 7.2 22 3,660 - - - MW-001 3/29/1997 97 - 10 6,180 5,460 10 1,290 1,050,000 2,460,000 4,310 7.5 22 1,770 - - - MW-001 3/27/1998 < 1( 10 11,400 5,900 21 290 942,000 2,780,000 4,430 7.19 23.4 1,419 - - MW-001 9/30/1998 274 < 10 -- 4,940 -- 666,000 2,700,000 15,400 7.6 20 1,200 - - MW-001 3/31/1999 < 10 7,550 6 4,450 600 1,560,000 2,930,000 7,920 7.3 18 1,021 - - - MW-001 9/29/1999 877 < 10 6,770 862 80 3,360 330,000 715,000 13,300 7.08 18 2,930 -- - - MW-001 3/16/2000 410 < 10 72,000 4,540 1,090 948,000 2,610,000 10,600 -- -- -- - - - MW-001 9/15/2000 ' 100 < 10 2,020 3,480 6,270 894,000 2,470,000 5,210 6.57 19 980 - - -- MW-001 3/23/2001 144 < 10 4 35,900 12 4,070 ; 20 480 926,000 2,630,000 5,850 6.5 17 480 - - - MW-001 (FD) 3/23/2001 ; 100 < 10 6,900 7 4,190 ; 20 350 939,000 2,640,000 7,520 6.5 17 480 - - - MW-001 10/4/2001 204 < 10 915 7 229 ; 20 < 0.05 186,000 7,800 6.28 20 300 - - - MW-001 3/28/2002 < 100 < 10 5,100 3,660 - 280 1,000,000 3,010,000 3,770 6.44 12 1,080 - - - MW-001 10/3/2002 < 100 < 10 2 27 1,520 3,340 1,820 1,030,000 2,940,000 4,940 6.67 18 370 - - -- MW-001 (FD) 10/3/2002 '00 < 10 2 24 1,580 3,330 1,780 1,040,000 2,860,000 5,120 5.67 18 370 - - -- MW-001 3/25/2003 100 < 10 6,690 6 3,560 25 406 846,000 2,530,000 3,720 6.62 17 330 - - -- MW-001 10/2/2003 100 < 10 11,300 7 3,880 42 174 916,000 2,710,000 3,920 5.59 15 3,050 - - -- MW-001 (FD) 10/2/2003 00 < 10 11,400 6 3,880 958,000 2,690,000 3,900 5.59 15 3,170 - - -- MW-001 4/28/2004 < 100 < 10 11,100 6 6,080 1,460,000 2,550,000 5,360 -- 17.3 2,860 -- - - MW-001 10/26/2004 < 100 < 10 5,250 4,550 287 1,190,000 2,950,000 3,640 - -- 3,480 -- - - MW-001 4/27/2005 < 10 2 7,630 7 5,730 1,100,000 2,550,000 4,710 - - 2,870 -- - - MW-001 10/20/2005 1,630 < 10 4 28 103,000 6 4,880 57 428 403,000 3,010,000 89,000 -- - 529 -- -- - MW-001 10/19/2006 172 < 10 2 347 27,400 3,600 27 139 1,320,000 2,850,000 4,370 - - 2,000 -- -- - MW-001 4/27/2007 < 10 5,360 2,380 287 1,380,000 2,750,000 4,010 - - 4,830 -- -- - MW-001 11/19/2007 42 < 2 48,200 3,280 25 5 1,560,000 3,060,000 3,820 - - 3,300 -- - - MW-001 4/30/2008 100 < 10 9,680 2,990 22 155 1,100,000 2,910,000 3,380 - - 4,880 -- - - MW-001 10/29/2008 < 100 < 10 68.7 4,840 3.5 2,880 188,000 3,060,000 3,510 - - 4,200 -- - - MW-001 4/30/2009 < 100 < 10 77.4 1.8 3.6 4,080 4.4 3,100 264 37,700 2,904,000 3,940 -- -- 4,070 -- - - MW-003 9/30/1994 1,770 113 3,370 2,200 96 200 159,000 415,000 20,100 6.89 19.6 519 -- - - MW-003 3/31/1995 -- 4,860 5,980 32 100 294,000 625,000 -- 7.56 13.6 896 - - - MW-003 9/29/1995 11640 3,420 7 2,940 104 463 314,000 740,000 3,740 4.89 14 1,040 - - - MW-003 3/30/1996 11,400 2 23,300 9 3,160 126 130 222,000 552,000 3,830 7.18 12 750 -- - - MW-003 9/27/1996 110 1,010 7 2,360 30 160 283,000 737,000 6,730 7.6 20 974 -- - - MW-003 3/29/1997 238 1,930 3,050 13 20 180 809,000 807,000 4,170 7.76 16 590 - - - MW-003 9/17/1997 169 1U 715 5 3,060 6 212 330 562,000 1,290,000 5,290 7.7 19 1,650 -- - - MW-003 3/27/1998 270 10 2,500 3,370 13 41 250 -- 929,000 6,980 7.2 20 1,214 -- - - MW-003 9/30/1998 353 10 1,380 -- 17 780 367,000 1,280,000 10,100 6.9 19 920 -- - - MW-003 3/31/1999 ' 100 < 10 4,830 5,550 190 482,000 842,000 7,580 7.1 16 592 - - - MW-003 9/29/1999 677 < 10 1,940 894 100 258,000 413,000 8,140 7.65 19 741 -- - - MW-003 9/15/2000 224 < 10 2,380 2,800 160 550,000 1,260,000 8,580 7.06 21 680 - - - MW-003 3/23/2001 < 10 3,690 10 2,250 30 230 530,000 1,230,000 5,720 6.6 17 640 - - - APPENDIX A2 SURFACE WATER ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Page 10 of 10 pl C y O � s >y > 0 V C fL6 y V N Gs Z O � •E L O Z W E O N E N U) a r R U .2 w O > =E E E E O y CL O 0) V d y m m 0 O cn d O- V V :� +r R c MR O J i •L IC -O IC L s Q O i O d C M L d G1 d 0 O L :' w 7 R O l6 O 2 E tlJ d d y O- N 7 r X O 0 y Sample Location Date a a m c� c� 0 L I -j a a U) in N Z U) f- a 0 U) O 0. G NC 213 Surface Water Standard 8,000 10 21,000 0.3 50.1 5.79 1,000 1A9 100 0.012 5 1.34 76.01 10,000 250,000 500,000 NE 6.0-9.0 NE NE 50 NE NE MW-003 10/4/2001 4,240 6 3,650 80 592,000 1,440,000 30,000 7 20 600 -- -- -- MW-003 3/28/2002 5,620 2,180 -- 110 682,000 1,590,000 5,360 6.37 13 680 -- - -- MW-003 10/3/2002 2 6,510 5,290 932,000 1,900,000 8,510 6.22 19 150 -- -- -- MW-003 3/25/2003 3,280 6,170 8 4,290 78 88 784,000 1,520,000 1,340 6.36 18 110 -- - -- MW-003 10/2/2003 634 5,950 8 6,750 50 174 765,000 1,420,000 3,970 6.12 14 1,460 -- -- -- MW-003 4/28/2004 152 8,370 6,720 224 1,040,000 1,810,000 3,890 -- 12.1 2,030 -- -- -- MW-003 10/26/2004 554 5 16,300 4,220 36 289 1,070,000 2,140,000 5,160 -- -- 2,150 -- -- - MW-003 4/27/2005 2 4,470 6,110 246 1,075,000 2,090,000 4,050 -- -- 2,320 -- -- - MW-003 10/20/2005 5 27 7,900 5,870 44 279 1,300,000 2,090,000 30,000 -- -- 1,060 -- -- - MW-003 10/19/2006 1,460 6,040 4,550 21 281 1,170,000 1,920,000 4,200 -- -- 1,370 -- -- -- MW-003 4/27/2007 8,330 4,190 290 1,130,000 2,130,000 3,830 -- -- 2,230 -- -- -- MW-003 11/19/2007 8,200 6,000 64 1,680,000 2,550,000 4,590 -- -- 2,710 -- -- -- MW-003 4/30/2008 3,360 3,800 37 297 2,090,000 2,110,000 3,560 -- -- 2,290 -- -- -- MW-003 10/29/2008 59.3 2,880 2.3 4,360 171 988,000 2,360,000 3,480 -- -- 2,740 -- -- -- MW-003 4/30/2009 53.2 4,620 7.2 4,960 14.6 337 261,000 2,460,000 4,110 -- -- 2,930 -- -- -- Notes: All concentrations in micrograms per liter (ug/L) unless otherwise noted SU - standard units uS/cm - microSiemens per centimeter NTUs - Nephelometric Turbidity Units my - millivolts mg/L - milligrams per liter NE - Not established -- - Not sampled B - Detected in the method blank J - Estimated result < LOQ and > DL Bold with gray background indicates exceedance of NC Surface Water Standard Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). NSA - Location inaccessible; no sample collected NSB - Obstruction in well; no sample collected NSC - Well dry; no sample collected NSD - Insufficient volume; no sample collected NSE - Well damaged; no sample collected NSF - Pump broken; no sample collected NSG - Surface water location dry; no sample collected APPENDIX A3 QA/QC ANALYTICAL RESULTS SUMMARY EDWARDS ROAD LANDFILL - PERMIT 34-05 RURAL HALL, NORTH CAROLINA Analyte E c E 3 Q d Q E R m E 3 A U E o L U y a O U c O y J (D m R R 2 a) 2 E ac N N > - (n u a N Z w y Z d ° U) a 0 rn � > p w G 'E H � U u rn O m H NC 2L Groundwater 3.5 0.01 0.7 0.002 0.01 1 0.3 0.015 0.05 0.001 0.02 0.02 1 10 250 500 NE Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Field Blank 9/30/1998 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/31 /1999 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.19 < 5 < 5 2.18 9/15/2000 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/23/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.006 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 < 1 10/412001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.006 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.3 < 5 15 < 2 3/28/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 -- < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 < 1 10/312002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 1 3/25/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.198 < 5 < 5 < 1 10/2/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 4/28/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 1 10/26/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.151 < 5 10 2.18 4/27/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 12 1.79 10/20/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.101 < 5 < 5 < 0.5 10/19/2006 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/27/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 11 /19/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/30/2008 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.336 < 5 < 5 < 0.5 10/29/2008 < 0.1 < 0.01 0.0031 < 0.001 < 0.01 < 0.01 < 0.05 < 0.01 < 0.01 0.00002 < 0.01 0.0022 0.01 < 0.05 < 10 < 5 < 0.5 4/30/2009 < 0.1 < 0.01 0.0077 < 0.001 < 0.01 < 0.01 < 0.05 0.0045 0.008 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 90 < 0.5 Trip Blank 9/30/1998 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/31 /1999 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.22 < 5 15 < 1 9/15/2000 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 1 3/23/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.03 10/4/2001 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.4 < 5 12 1 2 3/28/2002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 -- < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.03 10/312002 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 3/25/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 0.197 < 5 7 < 1 10/2/2003 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 7 < 1 4/28/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 16 < 1 10/26/2004 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.61 < 0.01 < 0.02 < 0.05 < 5 8 1.29 4/27/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 14 1.76 10/20/2005 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 6 < 0.5 10/19/2006 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/27/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 11/19/2007 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 4/30/2008 < 0.1 < 0.01 < 0.25 < 0.002 < 0.02 < 0.02 < 0.1 < 0.005 < 0.01 < 0.0002 < 0.01 < 0.01 < 0.02 < 0.05 < 5 < 5 < 0.5 10/29/2008 < 0.1 < 0.01 0.0046 < 0.001 < 0.01 < 0.01 < 0.05 < 0.01 < 0.01 0.00001 < 0.01 < 0.01 < 0.01 < 0.05 < 10 < 5 < 0.5 4/30/2009 < 0.1 < 0.01 0.0086 0.0003 < 0.01 < 0.01 < 0.05 < 0.01 0.0071 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 85 < 0.5 9/8/2016 < 0.1 < 0.01 0.0086 0.0003 < 0.01 < 0.01 < 0.05 < 0.01 0.0071 < 0.0002 < 0.01 < 0.01 < 0.01 < 0.05 < 10 85 < 0.5 Notes: All concentrations in milligrams per liter (mg/L) unless otherwise noted NE - Not established -- - Not sampled Bold with gray background indicates exceedance of NC Groundwater Standard Analysis for arsenic, copper, mercury, silver, zinc, nitrates & TOC discontinued in 2014 per Corrective Action Plan (ERM, 2/2014). Page 1 of 1 APPENDIX B LABORATORY DATA SHEETS www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 2021-10 Edwards Rd LF Rural Hall GW Report.docx aceAnalytical Report of Analysis ERM INC, Inc. 300 West Summit Avenue Suite 330 Charlotte, NC 28203 Attention: Alan Martin Project Name: RJRT Project Number: 0588865 Lot Number:WJ26005 Date Completed:11/11/2021 11/11/2021 3:59 PM Approved and released by: Project Manager I: Hannah K. Lucas The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel: 803-791-9700 Fax:803-791-9111 www.pacelabs.com PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative ERM INC, Inc. Lot Number: WJ26005 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ('Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 601 OD, VOC SM 6200 B-2011, Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid Chemical Material: TOC Walkley-Black. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Inorganic non-metals Sample -001 had yielded a high residual mass for TDS in the initial analysis. The sample was analyzed outside of the 7-day holding time and the detections were confirmed. The initial results have been reported. Metals The matrix spike/matrix spike duplicate (MS/MSD) associated with sample 20286 had aluminum recovered outside of the acceptance limits. The laboratory control sample (LCS) was recovered within the required acceptance limits; therefore, this likely demonstrates a matrix effect. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Dnve West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 x pacelabs.com Page 1 of 66 Page 2 of 66 PACE ANALYTICAL SERVICES, LLC Sample Summary ERM INC, Inc. Lot Number: WJ26005 Sample Number Sample ID Matrix Date Sampled Date Received 001 W-1-WG-20211021 Aqueous 10/21/2021 1540 10/26/2021 002 W-3-WG-20211020 Aqueous 10/20/2021 1640 10/26/2021 003 W-3B-WG-20211020 Aqueous 10/20/2021 1540 10/26/2021 004 W-6-WG-20211021 Aqueous 10/21/2021 1050 10/26/2021 005 W-7-WG-20211021 Aqueous 10/21/2021 1215 10/26/2021 006 W-8-WG-20211020 Aqueous 10/20/2021 1530 10/26/2021 007 W-9-WG-20211020 Aqueous 10/20/2021 1420 10/26/2021 008 PW-1-WG-20211020 Aqueous 10/20/2021 1645 10/26/2021 009 SS-01-WS-20211021 Aqueous 10/21/2021 1655 10/26/2021 010 SS-02-WS-20211021 Aqueous 10/21/2021 1400 10/26/2021 011 SS-20-WS-20211021 Aqueous 10/21/2021 1525 10/26/2021 012 SS-25-WS-20211021 Aqueous 10/21/2021 1535 10/26/2021 013 SS-30-WS-20211021 Aqueous 10/21/2021 1545 10/26/2021 014 SS-40-WS-20211021 Aqueous 10/21/2021 1410 10/26/2021 015 SS-50-WS-20211021 Aqueous 10/21/2021 1630 10/26/2021 016 SS-60-WS-20211021 Aqueous 10/21/2021 1600 10/26/2021 017 SS-70-WS-20211021 Aqueous 10/21/2021 1430 10/26/2021 018 SS-80-WS-20211021 Aqueous 10/21/2021 1420 10/26/2021 019 SS-90-WS-20211021 Aqueous 10/21/2021 1015 10/26/2021 (19 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 3 of 66 PACE ANALYTICAL SERVICES, LLC Detection Summary ERM INC, Inc. Lot Number: WJ26005 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 W-1-WG-20211021 Aqueous Sulfate 300.0 1100 mg/L 7 001 W-1-WG-20211021 Aqueous TDS SM 2540C- 2200 mg/L 7 001 W-1-WG-20211021 Aqueous Aluminum 6020B 41 ug/L 8 001 W-1-WG-20211021 Aqueous Barium 6020B 22 ug/L 8 001 W-1-WG-20211021 Aqueous Iron 6020E 290 ug/L 8 001 W-1-WG-20211021 Aqueous Manganese 6020B 3600 ug/L 8 001 W-1-WG-20211021 Aqueous Selenium 6020B 22 ug/L 8 002 W-3-WG-20211020 Aqueous Sulfate 300.0 120 mg/L 9 002 W-3-WG-20211020 Aqueous TDS SM 2540C- 370 mg/L 9 002 W-3-WG-20211020 Aqueous Barium 6020B 34 ug/L 10 002 W-3-WG-20211020 Aqueous Manganese 6020B 120 ug/L 10 003 W-3B-WG-20211020 Aqueous Sulfate 300.0 14 mg/L 11 003 W-3B-WG-20211020 Aqueous TDS SM 2540C- 230 mg/L 11 003 W-3B-WG-20211020 Aqueous Barium 6020B 50 ug/L 12 003 W-3B-WG-20211020 Aqueous Iron 6020E 210 ug/L 12 003 W-3B-WG-20211020 Aqueous Manganese 6020E 78 ug/L 12 004 W-6-WG-20211021 Aqueous Sulfate 300.0 10 mg/L 13 004 W-6-WG-20211021 Aqueous TDS SM 2540C- 260 mg/L 13 004 W-6-WG-20211021 Aqueous Aluminum 6020E 320 ug/L 14 004 W-6-WG-20211021 Aqueous Barium 6020B 61 ug/L 14 004 W-6-WG-20211021 Aqueous Chromium 6020E 10 ug/L 14 004 W-6-WG-20211021 Aqueous Iron 6020E 540 ug/L 14 004 W-6-WG-20211021 Aqueous Manganese 6020E 16 ug/L 14 005 W-7-WG-20211021 Aqueous Sulfate 300.0 12 mg/L 15 005 W-7-WG-20211021 Aqueous TDS SM 2540C- 130 mg/L 15 005 W-7-WG-20211021 Aqueous Aluminum 6020E 140 ug/L 16 005 W-7-WG-20211021 Aqueous Barium 6020E 130 ug/L 16 005 W-7-WG-20211021 Aqueous Iron 6020E 870 ug/L 16 005 W-7-WG-20211021 Aqueous Manganese 6020B 29 ug/L 16 006 W-8-WG-20211020 Aqueous Sulfate 300.0 19 mg/L 17 006 W-8-WG-20211020 Aqueous TDS SM 2540C- 96 mg/L 17 006 W-8-WG-20211020 Aqueous Aluminum 6020E 400 ug/L 18 006 W-8-WG-20211020 Aqueous Barium 6020E 150 ug/L 18 006 W-8-WG-20211020 Aqueous Chromium 6020E 12 ug/L 18 006 W-8-WG-20211020 Aqueous Iron 6020E 680 ug/L 18 006 W-8-WG-20211020 Aqueous Manganese 6020E 15 ug/L 18 007 W-9-WG-20211020 Aqueous Sulfate 300.0 12 mg/L 19 007 W-9-WG-20211020 Aqueous TDS SM 2540C- 240 mg/L 19 007 W-9-WG-20211020 Aqueous Aluminum 6020E 85 ug/L 20 007 W-9-WG-20211020 Aqueous Barium 6020B 130 ug/L 20 008 PW-1-WG-20211020 Aqueous Sulfate 300.0 670 mg/L 21 008 PW-1-WG-20211020 Aqueous TDS SM 2540C- 1600 mg/L 21 009 SS-01-WS-20211021 Aqueous Sulfate 300.0 40 mg/L 22 009 SS-01-WS-20211021 Aqueous TDS SM 2540C- 200 mg/L 22 009 SS-01-WS-20211021 Aqueous Aluminum 6020E 84 ug/L 23 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 4 of 66 Detection Summary (Continued) Lot Number: WJ26005 Sample Sample ID Matrix Parameter Method Result Q Units Page 009 SS-01-WS-20211021 Aqueous Barium 6020E 73 ug/L 23 009 SS-01-WS-20211021 Aqueous Iron 6020B 210 ug/L 23 009 SS-01-WS-20211021 Aqueous Manganese 6020B 6.3 ug/L 23 010 SS-02-WS-20211021 Aqueous Sulfate 300.0 50 mg/L 24 010 SS-02-WS-20211021 Aqueous TDS SM 2540C- 220 mg/L 24 010 SS-02-WS-20211021 Aqueous Aluminum 6020B 77 S ug/L 25 010 SS-02-WS-20211021 Aqueous Barium 6020B 76 ug/L 25 010 SS-02-WS-20211021 Aqueous Iron 6020B 200 ug/L 25 010 SS-02-WS-20211021 Aqueous Manganese 6020E 7.7 ug/L 25 011 SS-20-WS-20211021 Aqueous Sulfate 300.0 9.2 mg/L 26 011 SS-20-WS-20211021 Aqueous TDS SM 2540C- 82 mg/L 26 011 SS-20-WS-20211021 Aqueous Aluminum 6020B 170 ug/L 27 011 SS-20-WS-20211021 Aqueous Barium 6020B 38 ug/L 27 011 SS-20-WS-20211021 Aqueous Iron 6020E 480 ug/L 27 011 SS-20-WS-20211021 Aqueous Manganese 6020E 27 ug/L 27 012 SS-25-WS-20211021 Aqueous Sulfate 300.0 9.0 mg/L 28 012 SS-25-WS-20211021 Aqueous TDS SM 2540C- 83 mg/L 28 012 SS-25-WS-20211021 Aqueous Aluminum 6020B 120 ug/L 29 012 SS-25-WS-20211021 Aqueous Barium 6020B 37 ug/L 29 012 SS-25-WS-20211021 Aqueous Iron 6020E 360 ug/L 29 012 SS-25-WS-20211021 Aqueous Manganese 6020B 12 ug/L 29 013 SS-30-WS-20211021 Aqueous Sulfate 300.0 48 mg/L 30 013 SS-30-WS-20211021 Aqueous TDS SM 2540C- 220 mg/L 30 013 SS-30-WS-20211021 Aqueous Aluminum 6020B 140 ug/L 31 013 SS-30-WS-20211021 Aqueous Barium 6020E 60 ug/L 31 013 SS-30-WS-20211021 Aqueous Iron 6020E 430 ug/L 31 013 SS-30-WS-20211021 Aqueous Manganese 6020E 20 ug/L 31 014 SS-40-WS-20211021 Aqueous Sulfate 300.0 50 mg/L 32 014 SS-40-WS-20211021 Aqueous TDS SM 2540C- 230 mg/L 32 014 SS-40-WS-20211021 Aqueous Aluminum 6020E 83 ug/L 33 014 SS-40-WS-20211021 Aqueous Barium 6020B 74 ug/L 33 014 SS-40-WS-20211021 Aqueous Iron 6020B 200 ug/L 33 014 SS-40-WS-20211021 Aqueous Manganese 6020E 8.5 ug/L 33 015 SS-50-WS-20211021 Aqueous Sulfate 300.0 1.1 mg/L 34 015 SS-50-WS-20211021 Aqueous TDS SM 2540C- 72 mg/L 34 015 SS-50-WS-20211021 Aqueous Aluminum 6020E 1300 ug/L 35 015 SS-50-WS-20211021 Aqueous Barium 6020B 170 ug/L 35 015 SS-50-WS-20211021 Aqueous Iron 6020E 25000 ug/L 35 015 SS-50-WS-20211021 Aqueous Lead 6020E 6.5 ug/L 35 015 SS-50-WS-20211021 Aqueous Manganese 6020B 710 ug/L 35 016 SS-60-WS-20211021 Aqueous Sulfate 300.0 13 mg/L 36 016 SS-60-WS-20211021 Aqueous TDS SM 2540C- 92 mg/L 36 016 SS-60-WS-20211021 Aqueous Aluminum 6020B 61 ug/L 37 016 SS-60-WS-20211021 Aqueous Barium 6020B 64 ug/L 37 016 SS-60-WS-20211021 Aqueous Iron 6020B 210 ug/L 37 016 SS-60-WS-20211021 Aqueous Manganese 6020B 11 ug/L 37 017 SS-70-WS-20211021 Aqueous Sulfate 300.0 53 mg/L 38 017 SS-70-WS-20211021 Aqueous TDS SM 2540C- 230 mg/L 38 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 5 of 66 Detection Summary (Continued) Lot Number: WJ26005 Sample Sample ID Matrix Parameter Method Result Q Units Page 017 SS-70-WS-20211021 Aqueous Aluminum 6020E 80 ug/L 39 017 SS-70-WS-20211021 Aqueous Barium 6020B 73 ug/L 39 017 SS-70-WS-20211021 Aqueous Iron 6020E 170 ug/L 39 017 SS-70-WS-20211021 Aqueous Manganese 6020E 7.5 ug/L 39 018 SS-80-WS-20211021 Aqueous Sulfate 300.0 60 mg/L 40 018 SS-80-WS-20211021 Aqueous TDS SM 2540C- 240 mg/L 40 018 SS-80-WS-20211021 Aqueous Aluminum 6020B 85 ug/L 41 018 SS-80-WS-20211021 Aqueous Barium 6020B 76 ug/L 41 018 SS-80-WS-20211021 Aqueous Iron 60208 200 ug/L 41 018 SS-80-WS-20211021 Aqueous Manganese 6020E 15 ug/L 41 019 SS-90-WS-20211021 Aqueous Sulfate 300.0 29 mg/L 42 019 SS-90-WS-20211021 Aqueous TDS SM 2540C- 140 mg/L 42 019 SS-90-WS-20211021 Aqueous Aluminum 6020E 53 ug/L 43 019 SS-90-WS-20211021 Aqueous Barium 6020E 65 ug/L 43 019 SS-90-WS-20211021 Aqueous Iron 6020E 140 ug/L 43 019 SS-90-WS-20211021 Aqueous Manganese 6020B 5.4 ug/L 43 (109 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 6 of 66 Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: WJ26005-001 Description: W-1-WG-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1540 )ate Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate) 300.0 10 10/27/2021 1755 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 1100 10 or lL 1 TDS SM 254OC-2011 2200 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND= Not detected at or above the LOQ N=Re ,a, is out of cntena P=The RPD be —en hen GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: WJ26005-001 Description: W-1-WG-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1540 )ate Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/02/2021 2149 BNW 10/28/2021 0133 20286 2 3005A 6020E 100 11/03/2021 2037 BPK 10/28/2021 0133 20286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 41 40 ug/L 1 Barium 7440-39-3 6020B 22 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439.89.6 6020E 290 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 3600 500 ug/L 2 Selenium 7782.49.2 6020E 22 5.0 ug/L 1 Q = sumogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration range L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of crom, P=The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 66 Page 8 of 66 Q = surtogate failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-002 Description: W-3-WG-20211020 Matrix: Aqueous Date Sampled:l 0/20/2021 1640 Date Received: 10/26/2021 ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-002 Description: W-3-WG-20211020 Matrix: Aqueous Date Sampled:10/20/2021 1640 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate)300.0 1 10/27/20211814 AMR 20471 1 3005A 6020B 1 11/02/20212157 BNW 10/28/2021 0133 20286 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Parameter Number Method Result Q LOQ Units Run Aluminum Sulfate 300.0 120 1.0 mg/L 1 Barium TDS SM 254OC-2011 370 25 ni 1 Cadmium Chromium Iron Lead Manganese Selenium LOO =Limit of Ouantionion B = Detected in the method blank E = Quantitation of compound exceeded the calif aoan ange ND= Not detected at or above the LOQ N=Re ,a, is out of cnt,na P=The RPD be—,n twa GC columns exceed, 40% H = Out of holding tlme W = Reported on wet weight boats Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 66 CAS Analytical Number Method Result Q LOQ Units Run 7429-90-5 6020B ND 40 ug/L 1 7440-39-3 6020E 34 5.0 ug/L 1 7440-43-9 6020E ND 0.50 ug/L 1 7440-47-3 6020B ND 5.0 ug/L 1 7439-89-6 6020B ND 50 ug/L 1 7439-92-1 6020B ND 1.0 ug/L 1 7439-96-5 6020E 120 5.0 ug/L 1 7782-49-2 6020B ND 5.0 ug/L 1 O = Sunapte failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration ange L=LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlen, P=The RPD In—... twa GC calumny exceed, 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 10 of66 O = SURogate failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-003 Description: W-3B-WG-20211020 Matrix: Aqueous Date Sampled:l 0/20/2021 1540 Date Received: 10/26/2021 ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-003 Description: W-3B-WG-20211020 Matrix: Aqueous Date Sampled:10/20/2021 1540 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate)300.0 1 10/27/20211833 AMR 20471 1 3005A 6020B 1 11/02/20212205 BNW 10/28/2021 0133 20286 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Parameter Number Method Result Q LOQ Units Run Aluminum Sulfate 300.0 14 1.0 mg/L 1 Barium TDS SM 254OC-2011 230 25 mg/L 1 Cadmium Chromium Iron Lead Manganese Selenium LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange ND= Not detected at or above the LOQ N=Re .,, is out of crilaria P=The RPD be —en twa GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of66 CAS Analytical Number Method Result Q LOQ Units Run 7429-90-5 6020B ND 40 ug/L 1 7440-39-3 6020B 50 5.0 ug/L 1 7440-43-9 6020B ND 0.50 ug/L 1 7440-47-3 6020B ND 5.0 ug/L 1 7439-89-6 6020E 210 50 ug/L 1 7439-92-1 6020B ND 1.0 ug/L 1 7439-96-5 6020B 78 5.0 ug/L 1 7782-49-2 6020B ND 5.0 ug/L 1 Q = Sunapte failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration range L=LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P=The RPD be —en twa GC calumna exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 12 of 66 Q = SURogate failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-004 Description: W-6-WG-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1050 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/27/2021 1930 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 10 1.0 nr lL 1 TDS SM 254OC-2011 260 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of wmp.und exceeded the calibalion ange ND= Not detected at or above the LOQ N=Re .,, is out of cntena P=The RPD be —en hen GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of66 ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-004 Description: W-6-WG-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1050 Date Received: 10126/2021 Run Prep Method 1 3005A Analytical Method Dilution Analysis Dale Analyst 6020B 1 11/02/2021 2213 BNW Prep Date Batch 10/28/2021 0133 20286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 320 40 ug/L 1 Barium 7440-39-3 6020B 61 5.0 ug/L 1 Cadmium 7440-43-9 6020B NO 0.50 ug/L 1 Chromium 7440-47-3 6020B 10 5.0 ug/L 1 Iron 7439-89-6 6020B 540 50 ug/L 1 Lead 7439-92-1 6020B NO 1.0 ug/L 1 Manganese 7439-96-5 6020B 16 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 0 = Sumpte failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of crom, P=The RPD In—... two GC columneexceeit, 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight baste Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of66 0 = Sunmgate failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-005 Description: W-7-WG-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1215 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/27/2021 1949 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 12 1.0 nr lL 1 TDS SM 254OC-2011 130 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calilx000n ange ND= Not detected at or above the LOQ N=Re .,, is out of cntena P=The RPD be —en hen GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of66 ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-005 Description: W-7-WG-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1215 Date Received: 10/26/2021 Run Prep Method 1 3005A Analytical Method Dilution Analysis Dale Analyst 6020B 1 11/02/2021 2221 BNW Prep Date Batch 10/28/2021 0133 20286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 140 40 ug/L 1 Barium 7440-39-3 6020B 130 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020E 870 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020B 29 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 0 = Sumpte failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of crom, P=The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 16 of66 0=Sumxg failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-006 Description: W-8-WG-20211020 Matrix: Aqueous Date Sampled:l 0/20/2021 1530 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/27/2021 2046 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 19 1.0 nr lL 1 TDS SM 254OC-2011 96 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of wmp.und exceeded the calibalion ange ND= Not detected at or above the LOQ N=Re .,, is out of cntena P=The RPD be —en hen GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of66 ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: WJ26005-006 Description: W-8-WG-20211020 Matrix: Aqueous Date Sampled:10/20/2021 1530 Date Received: 10126/2021 Run Prep Method 1 3005A Analytical Method Dilution Analysis Dale Analyst 6020B 1 11/02/2021 2228 BNW Prep Date Batch 10/28/2021 0133 20286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 400 40 ug/L 1 Barium 7440-39-3 6020B 150 5.0 ug/L 1 Cadmium 7440-43-9 6020B NO 0.50 ug/L 1 Chromium 7440-47-3 6020B 12 5.0 ug/L 1 Iron 7439-89-6 6020B 680 50 ug/L 1 Lead 7439-92-1 6020B NO 1.0 ug/L 1 Manganese 7439-96-5 6020B 15 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 0 = Sumpte failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of crom, P=The RPD In—... two GC columneexceeit, 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight baste Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of66 0 = Sunmgate failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-007 Description: W-9-WG-20211020 Matrix: Aqueous Date Sampled:l 0/20/2021 1420 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/27/2021 2105 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 12 1.0 nr lL 1 TDS SM 254OC-2011 240 25 mg/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND= Not detected at or above the LOQ N=Re .,, is out of cntena P=The RPD be —en hen GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of66 ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-007 Description: W-9-WG-20211020 Matrix: Aqueous Date Sampled:10/20/2021 1420 Date Received: 10/26/2021 Run Prep Method 1 3005A Analytical Method Dilution Analysis Dale Analyst 6020B 1 11/02/2021 2236 BNW Prep Date Batch 10/28/2021 0133 20286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 85 40 ug/L 1 Barium 7440-39-3 6020B 130 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020B ND 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020B ND 5.0 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 ug/L 1 0 = Sumpte failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of ..pound exceeded the calibration range L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of crom, P=The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 20 of 66 0=Sumxg failure L = LCSILCSD failure S = MSIMSD failure Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: WJ26005-008 Description: PW-1-WG-20211020 Matrix: Aqueous Date Sampled:l 0/20/2021 1645 )ate Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 2 (Sulfate) 300.0 5 10/28/2021 2231 AMR 20617 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 670 5.0 thi 2 TDS SM 254OC-2011 1600 25 mg/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of wmpountl exceeded the calibration range ND= Not detected at or above the LOQ N=Re .,, is out of cnlena P=The RPD behv lwa GC wlumns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Inorganic non-metals Client: ERM NC, Inc. Laboratory ID: WJ26005-009 Description: SS-01-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1555 late Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 (Sulfate) 300.0 1 10/27/2021 2142 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run Sulfate 300.0 40 1.0 thi 1 TDS SM 254OC-2011 200 25 mg/L 1 Q = Sumogate failure LOO = Limit of Quantitation B = Detected in the meOod blank E = Quantitation of wmpountl exceeded the calibration range L=LCSILCSD failure ND= Not detected at or above the LOQ N=Re ,, is out of cnlena P=The RPD behv two GC wlumns exceeds 40% S = MSIMSD fallure H = Out of holding tlme W = Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of66 Page 22 of66 Q = S-ogate failure L = LCSILCSD failure S = MSIMSD fallure ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-009 Description: SS-01-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1555 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-010 Description: SS-02-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1400 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/02/20212300 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/27/20212201 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 84 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 73 5.0 ug/L 1 Sulfate 300.0 50 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 220 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 210 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 6.3 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en two GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 23 of66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 24 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-010 Description: SS-02-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1400 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-011 Description: SS-20-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1525 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/02/20212308 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/27/20212220 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 77 S 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 76 5.0 ug/L 1 Sulfate 300.0 9.2 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 82 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 200 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 7.7 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalion ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en lea GC columns exceeds 40% H = Out of holding Mn. W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 25 of66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding Mn. W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 26 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-011 Description: SS-20-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1525 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-012 Description: SS-25-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1535 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/02/20212347 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/27/20212239 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 170 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 38 5.0 ug/L 1 Sulfate 300.0 9.0 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 83 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 480 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 27 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en two GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 27 of 66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 28 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-012 Description: SS-25-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1535 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-013 Description: SS-30-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1545 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/02/20212355 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/27/20212258 AMR 20471 1 (TDS) SM 2540C-2011 1 10/27/2021 1934 MOM 20411 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 120 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 37 5.0 ug/L 1 Sulfate 300.0 48 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 220 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 360 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 12 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en two GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 29 of 66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 30 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-013 Description: SS-30-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1545 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-014 Description: SS-40-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1410 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/03/20210003 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/27/20212317 AMR 20471 1 (TDS) SM 2540C-2011 1 10/28/2021 2041 MOM 20541 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 140 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 60 5.0 ug/L 1 Sulfate 300.0 50 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 230 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 430 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 20 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en two GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 31 of 66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 32 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-014 Description: SS-40-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1410 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-015 Description: SS-50-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1630 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/03/20210010 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/27/20212336 AMR 20471 1 (TDS) SM 2540C-2011 1 10/28/2021 2041 MOM 20541 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 83 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 74 5.0 ug/L 1 Sulfate 300.0 1.1 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 72 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 200 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 8.5 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en two GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 33 of66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 34 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-015 Description: SS-50-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1630 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-016 Description: SS-60-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1600 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/03/20210034 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/28/20210033 AMR 20471 1 (TDS) SM 2540C-2011 1 10/28/2021 2041 MOM 20541 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 1300 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 170 5.0 ug/L 1 Sulfate 300.0 13 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 92 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89-6 6020B 25000 50 ug/L 1 Lead 7439-92-1 6020B 6.5 1.0 ug/L 1 Manganese 7439-96-5 6020B 710 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibalion ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en two GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 35 of66 0 = SURogate failure LOO =Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L=LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 36 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-016 Description: SS-60-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1600 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-017 Description: SS-70-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1430 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/03/20210042 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/28/20210052 AMR 20471 1 (TDS) SM 2540C-2011 1 10/28/2021 2041 MOM 20541 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 61 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 64 5.0 ug/L 1 Sulfate 300.0 53 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 230 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 210 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 11 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibcoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of criteria P=The RPD be —en lea GC columns exceeds 40% H = Oct of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 37 of 66 0 = SURogate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L= LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Oct of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 38 of 66 0 = SURogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-017 Description: SS-70-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1430 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-018 Description: SS-80-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1420 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 11/03/20210050 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/28/20210111 AMR 20471 1 (TDS) SM 2540C-2011 1 10/28/2021 2041 MOM 20541 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 80 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 73 5.0 ug/L 1 Sulfate 300.0 60 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 240 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 170 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 7.5 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en lea GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 39 of 66 0 = Su -gate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L=LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 40 of 66 0 = SuRogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM INC, Inc. Laboratory ID: WJ26005-018 Description: SS-80-WS-20211021 Matrix: Aqueous Date Sampled:l 0/21/2021 1420 Date Received: 10/26/2021 Inorganic non-metals Client: ERM INC, Inc. Laboratory ID: WJ26005-019 Description: SS-90-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1015 Date Received: 10/26/2021 Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch Run Prep Method Analytical Method Dilution Analysis Dale Analyst Prep Date Batch 1 3005A 6020B 1 11/03/20210058 BNW 10/28/2021 0133 20286 1 (Sulfate)300.0 1 10/28/20210207 AMR 20471 1 (TDS) SM 2540C-2011 1 10/28/2021 2041 MOM 20541 CAS Analytical Parameter Number Method Result Q LOQ Units Run CAS Analytical Aluminum 7429-90-5 6020B 85 40 ug/L 1 Parameter Number Method Result Q LOQ Units Run Barium 7440-39-3 6020B 76 5.0 ug/L 1 Sulfate 300.0 29 1.0 mg/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 TDS SM 254OC-2011 140 25 mg/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 200 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 15 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibnoi on ange ND= Not delected at or above the LOQ N=R—.,, is out of cntena P=The RPD be —en lea GC columns exceeds 40% H = Out of holding tlme W = Reported on wet weight basic Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 41 of 66 0 = Su -gate failure LOO = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration ange L=LCSILCSD failure ND= Not detected at or above the LOQ N= Recovery is out of cnlena P= The RPD be —en two GC columns exceeds 40% S=MSIMSD failure H= Out of holding tlme W= Reported on wet weight basis Pace Analytical Services. LLC (/ormerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelab—nn Page 42 of 66 0 = SuRogate failure L = LCSILCSD failure S = MSIMSD fallua ICP-MS Metals Client: ERM NC, Inc. Laboratory ID: WJ26005-019 Description: SS-90-WS-20211021 Matrix: Aqueous Date Sampled:10/21/2021 1015 )ate Received: 10/26/2021 Run Prep Method 1 3005A Analytical Method Dilution Analysis Dale Analyst 6020B 1 11/03/2021 0105 BNW Prep Date Batch 10/28/2021 0133 20286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6020B 53 40 ug/L 1 Barium 7440-39-3 6020B 65 5.0 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 ug/L 1 Iron 7439-89.6 6020B 140 50 ug/L 1 Lead 7439-92-1 6020B ND 1.0 ug/L 1 Manganese 7439-96-5 6020E 5.4 5.0 ug/L 1 Selenium 7782-49-2 6020E ND 5.0 ug/L 1 LOO =Limit of Quantitation B = Detected in the method blank E = Qui ntitation of wmp.und exceeded the calibretion range 0 = Su -gate failure ND= Not detected at or above the LOQ N=R--r, is out cf crilaria P=The RPD beh— lwa DC calumny exceeds 40% L=LCSILCSD failure H = Out of holding Mr. W = Reported on wet weight basis S = MSIMSD failure Pace Analytical Services. LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of66 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 66 Inorganic non-metals - MB Sample ID: WQ20411-001 Matrix: Aqueous Batch:20411 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: WQ20411-002 Matrix: Aqueous Batch:20411 Analytical Method: SM 2540C-2011 Spike Amount Result %Rec Units Analysis Date Parameter (mg/L) (mg/L) Q Dif % Rae Limit Analysis Date mg/L 10/27/2021 1934 TDS 1500 1500 1 100 90-110 10/27/2021 1934 LOQ = Limit of Q... tilation ND = Not delecled al or shave the LOQ N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie aul of —n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 45 of 66 LOQ = unit of Qu.ntilation ND = Not delecled a[ or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 46 .1766 Inorganic non-metals - Duplicate Sample ID: W,J26005-012DU Matrix: Aqueous Batch:20411 Analvtical Method: SM 2540C-2011 Sample Amount Result %RPD Parameter (mg/L) (hil Q Dil % RPD Limit Analysis Date TDS 83 90 1 8.1 20 10/27/20211934 LOQ = Limit of Quantilation ND = Not delecled al or shave the Lou N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cnlen. += RPD ie out of —n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Inorganic non-metals - Duplicate Sample ID: W,J26005-013DU Matrix: Aqueous Batch:20411 Analvtical Method: SM 2540C-2011 Sample Amount Result %RPD Parameter (mg/L) (ni Q Dil % RPD Limit Analysis Date TDS 220 230 1 5.4 20 10/27/20211934 LOQ = Limit of Qu.ntilation ND = Not delecled al or above the Lou N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cnlen. += RPD ie out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 47 of 66 Page 48 .1766 Inorganic non-metals - MB Sample ID: WQ20471-001 Matrix: Aqueous Batch:20471 Analytical Method: 300.0 Parameter Result Q Dil LOQ Sulfate ND 1 1.0 Inorganic non-metals - LCS Sample ID: WQ20471-002 Matrix: Aqueous Batch:20471 Analytical Method: 300.0 Spike Amount Result %Rec Units Analysis Date Parameter (mg/L) (.;,IL) Q Dil % Rae Limit Analysis Date mg/L 10/27/2021 1640 Sulfate 20 20 1 100 90-110 10/27/2021 1717 LOQ = Limit of Quantilation ND = Not delecled at or shave the LOQ N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie aul of —n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 49 of 66 LOQ = Limit of Qu.ntilation ND = Not delecled a[ or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 50 of 66 Inorganic non-metals - MS Sample ID: WJ26005-003MS Matrix: Aqueous Batch: 20471 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 14 10 24 1 97 90-110 10/27/20211852 LOQ = Limit of Quantilation ND = Not delecled at or shave the Lee N = Recovery is out of cnleria P = The RPD between two GC columns exceeds 40% = RSD is out of cnlen. +=RPD is aul oft n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 -pacelabs.com Inorganic non-metals - MSD Sample ID: WJ26005-003MD Matrix: Aqueous Batch: 20471 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 14 10 24 1 97 0.013 90-110 20 10/27/2021 1911 LOQ = Limit of Qu.ntilation ND = Not dslecled at or above the Lee N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of cnlen. += RPD is out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Page 51 .1766 Page 52 .1766 Inorganic non-metals - MS Sample ID: WJ26005-018MS Matrix: Aqueous Batch: 20471 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 60 10 69 1 96 90-110 10/28/2021 0130 LOQ = Limit of Quantilation ND = Not delecled at or shave the Lee N = Recovery is out of cnleria P = The RPD between two GC columns exceeds 40% = RSD is out of cnlen. +=RPD is aul oft n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 -pacelabs.com Inorganic non-metals - MSD Sample ID: WJ26005-018MD Matrix: Aqueous Batch: 20471 Analytical Method: 300.0 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 60 10 69 1 96 0.082 90-110 20 10/28/2021 0149 LOQ = Limit of Qu.ntilation ND = Not dslecled at or above the Lee N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of cnlen. += RPD is out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Page 53 .1766 Page 54 .1766 Inorganic non-metals - MB Sample ID: WQ20541-001 Matrix: Aqueous Batch:20541 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ TDS ND 1 25 Inorganic non-metals - LCS Sample ID: WQ20541-002 Matrix: Aqueous Batch:20541 Analytical Method: SM 2540C-2011 Spike Amount Result %Rec Units Analysis Date Parameter (mg/L) (mg/L) Q Dif % Rae Limit Analysis Date mg/L 10/28/2021 2041 TDS 1500 1500 1 101 90-110 10/28/2021 2041 LOQ = Limit of Qu.ntilation ND = Not delecled al or shave the LOQ N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie aul of —n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 55 o1766 LOQ = unit of Qu.ntilation ND = Not delecled al or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 56 .1766 Inorganic non-metals - MB Sample ID: WQ20617-001 Matrix: Aqueous Batch:20617 Analytical Method: 300.0 Parameter Result Q Dil LOQ Sulfate ND 1 1.0 Inorganic non-metals - LCS Sample ID: WQ20617-002 Matrix: Aqueous Batch:20617 Analytical Method: 300.0 Spike Amount Result %Rec Units Analysis Date Parameter (mg/L) (.;,IL) Q Dil % Rae Limit Analysis Date mg/L 10/28/2021 1825 Sulfate 20 20 1 101 90-110 10/28/2021 1902 LOQ = Limit of Quantilation ND = Not delecled at or shave the LOQ N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie aul of —n. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 57 of 66 LOQ = Limit of Qu.ntilation ND = Not delecled a[ or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% = RSD ie out of cntena += RPD ie out of triter. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 58 of 66 ICP-MS Metals - MB ICP-MS Metals - LCS Sample ID: WQ20286-001 Batch:20286 Analytical Method: 6020E Matrix: Aqueous Prep Method: 3005A Prep Date: 10/28/2021 0133 Sample ID: WQ20286-002 Batch:20286 Analytical Method: 6020E Matrix: Aqueous Prep Method: 3005A Prep Date: 10/28/2021 0133 Spike Amount Result %Rec Parameter Result Q Dil LOQ Units Analysis Date Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Aluminum ND 1 40 ug/L 11/01/2021 1640 Aluminum 100 99 1 99 80-120 11/01/2021 1648 Barium ND 1 5.0 ug/L 11/01/2021 1640 Barium 100 97 1 97 80-120 11/01/2021 1648 Cadmium ND 1 0.50 ug/L 11/01/2021 1640 Cadmium 100 97 1 97 80-120 11/01/2021 1648 Chromium ND 1 5.0 ug/L 11/01/2021 1640 Chromium 100 97 1 97 80-120 11/01/2021 1648 Iron ND 1 50 ug/L 11/01/2021 1640 Iron 1000 1000 1 100 80-120 11/01/2021 1648 Lead ND 1 1.0 ug/L 11/02/2021 1105 Lead 100 99 1 99 80-120 11/02/2021 1113 Manganese ND 1 5.0 ug/L 11/01/2021 1640 Manganese 100 96 1 96 80-120 11/01/2021 1648 Selenium ND 1 5.0 ug/L 11/01/2021 1640 Selenium 100 86 1 86 80-120 11/01/2021 1648 LOQ = Limit of Quantitation ND = Not detected at or abave the Lou N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD is out of totem +=RPD ie aut ofc ne Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 59 of 66 LOQ = Limit of Quentitation ND = Not detected at or above the LOQ N = Recovery ie out of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of totem += RPD ie out of criten. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111—pacelabs.com Page 60 .1766 ICP-MS Metals - MS Sample ID: WJ26005-01OMS Matrix: Aqueous Batch:20286 Prep Method: 3005A Analytical Method: 6020E Prep Date: 10/28/2021 0133 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Aluminum 77 100 280 N 1 204 75-125 11/02/2021 2316 Barium 76 100 170 1 98 75-125 11/02/2021 2316 Cadmium ND 100 95 1 95 75-125 11/02/2021 2316 Chromium ND 100 98 1 98 75-125 11/02/2021 2316 Iron 200 1000 1200 1 97 75-125 11/02/2021 2316 Lead ND 100 100 1 101 75-125 11/02/2021 2316 Manganese 7.7 100 100 1 97 75-125 11/02/2021 2316 Selenium ND 100 96 1 96 75-125 11/02/2021 2316 LOQ = Limit of Quantilation ND = Not delecled at or abave the Lou N = Recovery is out of cnteria P = The RPD between two GC columns exceeds 40% = RSD is out of cmen. +=RPD ie aul ofc ne Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com ICP-MS Metals - MSD Sample ID: WJ26005-01OMD Matrix: Aqueous Batch:20286 Prep Method: 3005A Analytical Method: 6020E Prep Date: 10/28/2021 0133 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 77 100 510 N,+ 1 433 58 75-125 20 11/02/2021 2323 Barium 76 100 170 1 98 0.14 75-125 20 11/02/2021 2323 Cadmium ND 100 94 1 94 1.5 75-125 20 11/02/2021 2323 Chromium ND 100 97 1 97 1.8 75-125 20 11/02/2021 2323 Iron 200 1000 1300 1 108 9.2 75-125 20 11/02/2021 2323 Lead ND 100 98 1 98 3.3 75-125 20 11/02/2021 2323 Manganese 7.7 100 100 1 96 0.51 75-125 20 11/02/2021 2323 Selenium ND 100 93 1 93 3.3 75-125 20 11/02/2021 2323 LOQ = Limit of Quentilation ND = Not delecled at or above the Lou N = Recovery is - of criteria P = The RPD between two GC columns exceeds 40% = RSD is out of.mena += RPD ie out of.riten. Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 —pacelabs.com Page 61 .1766 Page 62 .1766 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Page 63 of 66 PACE ANALYTICAL SERVICES, LLC CD Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111-pacelabs.com Page 64 of66 PACE ANALYTICAL SERVICES, LLC PACE ANALYTICAL SERVICES, LLC v-1 117 r-r r` N .4 E z z II Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 wvrx.pacelabs.com Page 65 o1766 Samples Receipt Lhe wlm ISaCI IMEOULSGI5) Revised19�29j202u eAla7yrecN Issuing Autltritg; Pace ENV-WCOLPage loft Sample Reeel pt Checklist (SRC) ? Client: Ell" L'onkr hlsp aed 'date: JRGd i !nl+1,2021 LaI N: WJ26UDE Means of w7c : PD..: heal VIa$ PpdE.. Pdter: Yea f No I, Ware—MuLy ..Is pies — an rlieC 1,1 Yes Nu NA 7. if "3tpdy seals were jn> i 1, werz t6hey intact laid unbrokcnY H Ship ]De 21-1M allorine Strip ill: NA Tes'.ed by a ua OriEinal assnpe:,tare -poll raneipt 1 D-ivcd (Corre.:md) tcmpemture upon receipt. %So[id SnaKup in N, 4.5 ,4-1 oC MA INA -C NA DNA aC NA INA T Mc[hod: �] IYmpalnaile Blank 0 ains! Rattles IR Gun ID: 5 IR Gun Ccrrectioa Racine o yr ur Laulani: L+J W 51 Ice L1 Ice Pa ks LJ DIV Teo LJ Neuma Yea ❑ Nn QN,q 3. If tern P.."toe of grry cooler ernleeded 6.0"C, was P:njecr Maaager Notincd? PM was Notified hy; phone lemai- I face-ta face (c'vcie oste), El Yea NO1 W NA 4. Is die wrnmcrcial cnnrler'sFacl mg ahp attached to ibis r—n7 Ayes IN 5, LVei+e proper nssmdy precedures (rclinquishedrrecelved) Falluwcrl7 FYea No 6. Wale -Pic IDS listed on the CDC? J Ycs No 7Wenesample ID.s listed un all snlnp:c aontainels? z Ycs No B, wag collection date & tlmo Ii't d on the l7CH:? Ye: No 9. Wm onLid(M. date & Lun, listed on all sample containers? f Ycs NO ] 0. Did el[ crmfamer label mfonnalion (1D, date, the WC? f Yea No I L Were [csis to he perfbrmed lisp[ oo the COC d Yea L_jm 12• Did all ,maples 8MVE In the pmperc minersdlor in emit conditirm (unbroken, lids on, eLc-)? _ im Yw Nn 13. Was adell ak sam Ie volume available? Yes No 14. Were all Samples—iyed wihri.14the hnldinurs, whichever comes t[rs(,+Yes Flo IS. Wereairy samples contain missin cess leg Not listed on COC? ❑Yes El No ❑f NA 16-Rm VOA 4w My-175 samples, were: bu hb les presort >"pe;r,-siMx ( nor d orm in diansetr) _ to wY of he VDA ri i:57 Yes No NA i7. Wete all f7RpiaretaLs.hsun•ieu simples remivcd ar a ll of ¢ 27 Yrs No f NA 18. %'e,n all cyanide samples received at a Fr> 12 and srifide samples rece ved at a pH 5 9? ❑Ycs ❑No DNn 19. Weee AI app icablc �1-!'Kltilcyamtlelphe110 25-II608.3 (t [1--.mggarnples Tree d residual :hlor:ne? ❑S, ❑Na I ?]A ❑ 2d- lVcs'e olien; [Cmarkslregnests(i e. requested d ilutivns, iWww D desi ) gnat101s, corn from the COC min Ehc oommenl section in t,1M5? Yes J Ne _ Eh_4a�uarihui 23, eras dre note number Lis Led on The container labcf? If vas. Clnnre k impie r"Servatioi [Masi be eompleied Far ally senp[e(s) iccorrectly pros-c—d or with heedVac,_ mp1e(y) Nn War; received mcoirecrly �raselved end were adjasted uccvrding]y sample receiving with NA ml, ol`oircle one: H2SO4, HP'03, "Cl, 111a01 rasing SR 4 vA me nF prestrvada, NA . ITT more .6one preservative is needed, plenae hole in the coavnents halpW, mple(s) TM•� were repclvcd wilh bubbles 7 G mm in diameter', inpl¢5(5} r•^ here received with'1RC p,5 ntgli. [iF#19 i5 no }and wcm U&I,ud atxordirgiy in sampe3 receiving wide sodium thiosu Bare (4a132Cy} ar ith Shealy TV; NA harcodc labels applied by: "C-1 Dam. lwanrzu2l mmalrls. MISSING: TR-i- 7-2r2i 1➢21 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 ot'66 APPENDIX C GROUNDWATER SAMPLING LOGS www.erm.com Version: 1.0 Project No.: 0588865 Client: R.J. Reynolds Tobacco Co. February 2022 2021-10 Edwards Rd LF Rural Hall GW Report.docx p" om vm nn.{ WL)glnG (min tihdnl WWI $0MOd Nwo urn iFll l uld ❑uplil {III InLwm (fl) PW-01 495 21.5405 W-01 ,'7.,1 41 10-20 W-02 W-02WL1-a020XXXX .7•5 17 7-17 W-03 W03 YG,2020XXXX L1, 8 E+ 17 7-17 %03B W-WB-WG-2020XXXX flrtfjSC 0i 21D 190-210 W-06 W66.WG-202OXXXX Oil. 4if 20C 170,200 W-07 W.07•WG 202MXX '1 � , O'; 3di 42-a41 j W-OS W48,WG 202MXX $C.1; 2 129 45 55 W,09 I&MING-2028Xxxx IW .`t',3 259 229-25D PZ•01 P1..01-WG,2020xxxx f V I x PZ•02 P2.02-WC,2020xxxx -fall x 30-4.0 PZ-03 px-w-m-2C2flxxxx I.1t x 0.5•1.5 j PZ•04 PZ-04-M-30eAMY 14M x 4s6.0 PZ•05 PZ-05-W -=20xxxx f• 13 x 3.0 LA — os WATER MATRIX SAMPLING, f' VELD PA TA FORM C R M STfa Name., RIM 1,dwafda Road Landfill dab #11,68889b Sampl4 Ty1•h-`: riIICId Of1P hn3{¢Y1r4¢I PT, Surf2Ca Water, Potabla WSW; other; Same!eld: un1c: It} C I L S:drlpling Personnel: Andrew H. erhaw U. _ Woothor Conditions: un P CI , MOLCq, nuGl; 0111dr Time1 ❑i S Wall Typez Fluuh Suttees Com v9un d �l Ial. Welt Tar peesonf: r Nu Well Lacked: Ala Lock PramV d rao Wall IC into. on Ta PT(. Ho Well Bol19d: Yee.No f Woll CD ' Mii"J Nn Welt Cap Cendillon; non RrAm, odlet Wvll Pgd Corydlklan= Cmcluq Fd kce. 4pner Andlllonal Conlmanml Wall Locallon: Grua A Irht Commit. Woadw olllur To(m1 0vpth of Well IT.0.I, Zp Screen Length; ) 15, 20 kdtwlhof na try to water u,T.WI' IL, d I Well Diametor: d, d. a bnd,r,e lb - Fluid PAOMstsra measured with! Ila Vj9,q Typd: PV Stour Dille Purgo Raia: r,,jd (o mUnlln __ $amplln 6a vi96 Pu�Wlell Mallxooll, r3rundlo6. anller, PnG, alllrr' 7Uhln Rea! i-dybaglone Pum Intake ft below M.P.}; tri Meamurfng Point: C610f: 'ro(, nlhvr! Odor' Y-, H. 7irrle do Voldthe PurERed Tarh9 °C PYI atd unllo spG uSkm lie rr !I. ORP my Tura NTU CaMME111 [ swina 2alldll Cmerim! 1 uIF r ?it 0.1 d�nl 8`h 109F +9 nl'J 1a%' or r5 or7 JDT �6-IL L_ IQ p 7A mil" r .:'y f•} UraS 1}"j 3`l .a t}�j�Ql sgm,,Inn Dales Tlme; I0I1,+_I1,1 r _1T qo $ggplea Collda(ed; AauhmLn ReauAts d: p eeervatlye: Hold Tima tdayaf: I& m nnt5 14pc;y 1f 7bSl SuUpn �5 ' s✓ t�w �.......rx.pea,,.w..a �� r.,da.na,.nnn�a er°�,K.u..wn,.,a,nu,. nw m.r»,.ana.,n,. n1,a.n pi . or.um,°�.n.n,wxaali m,rf,w,r rxrr wwulw nwuiin,rw r +q mu an,a•..i, n,..1 �. e�M`.nm. era�ir Mr Nue.PrN„w�e M�'rr�,.n n`+Wlflelwx �nwa,m h.Y.drneiva WA TER MATRIX SAMPVNG WATER MA TRJX SAMAI.7NG FIELD DATA FORM �R FIELD DATA FORM R SitnNamw RJRTEdwWd,$R0gdLandfill J4hM;U5868Q4 Sample Type: Clrclo ones n for OPT, Surface Water, Potablo WSW; nthorl :ialn le ID: Date: 1012 +' 7 SampllnidPcrv;-n l: and MIu11ooM. INedrhar CLlntl}lltlYls: 4„unn Padl r0n4dr, Clgl Rn4c 01hm rime: Weft eI 11140:4-4-Com dlvn, d J rn Watt Tag Present: Yea, Well Looked: Mo Lock Proeent: K. Well 10 Info. on Tap; Yee, Well Boiled: Yex,ria, WWI C.a (a Na Woll Cary Gondltiosl: ao : Re lace, Darer. Well Pad Condition; Croke, RepleCO. Clt-: Wall 1. llen' )MIML Comfule Ww4. r11hn: Acidlllons[ Commontw Total Popth of W011 IT-.P--j: 11 Po lh toWaer�4.TW7'4 - scrum LangW (5}, �C, h 14. u bmathtlWhLo,C+' uY: Wull PWmd-%r; ramoten m;wircd Flold Po— With; xlu(c7 aR Casing Type: 44,0 alher, PL:tga Rite: JV ! 170 fdLNrih sampling baviee: '.'L't ld Mu . Grumw HXbr, FOk, Oil— ruhi-I Tyf— I'mywgii o I'i ic,llulih, {II I,,:I—VTI Nfodyurinp PLairw Color' gl}re1 Odor: Vn9 N. I lnly. min W'Jdme Pgr etl DTW: Not) Temp Pc pH old npu SPC u510m 00 JrmL— GRP my Turb N'TL Commomiw Smbalmli- Crtlxlox jga4kxifij (see Hole bo w. Ib A *1- g1 xrll �c A +!- 10% If. ldmv •F 10%, e a .� •. 1 15 r7ti d.d' S 311 >a •zzf a D r, 0-ti •'t IT'10 1- n tj is; 131 f, 7o f.0 S-3r fI.t"3 01 " +~Grl kC I t� 17.57 6 ors 604 d sG iBc J.7 o 'e J i, x5 1 73 {In f, 630 f" 30 u `lu 17..mot UI Abf r+.Li t'YS qf,.. 4 5'.1 07.-Z 4,tttt Gttl M1.cy It6 'D.Vi Kj� �.Y;] tlu 17:.r c5 6 nn 6 Y9,li }LL F,.g Drlldal aRaftilaaw Tans. IV /10%i ( r W/0 y@mitl90 Co1Nagleti; Anq&P12Agj�Lq eel psmulft, U91d 71ing-WWI' La, pgr1 atg jf yi-1 iuLWrr/TQ'� Slfo Ndpte, RJRT gdworda RbAd LandNl ,1eh $:osease4 Sample Type' Chita One IMenil4r , PPT, Surface Water, Potable WSW; athnrl Sem Io ID: drm u - t Lr} C i, Date: ICf tt?/ t t S111mpi 12R;w. MetndWM, WdatllarCondlllorta; uAn, PartrrGo4d, Clo , Ray,; 01hur Time: tgfo Waif e: I"lush Sulfaca Ced albn, tkd Com Walf T.9 Present: Yda, Well Leckudi Ydf. LOCk Present; Y , MD Well ID Info. 4n Tag; Yau, Well Boiled; Yee'ARW Wall Cap: yea, Nd Well CitCondltion: , Ropiaaa, olher Wall Pad COndifl8ry; GMg Wd. Ro kC Cesar Well Lodatloo: Aqphpl. Car -me. ftcdc. r&w.. Addlllonul Comments: Te1e1 odpm of Weu [T.4.]: LLU seraen Langtn: 5. m. IN, Mdl-apidr: Pd th to Water D-7.W : i1 Aw-rKlAti Wall 41Pmalor C1. t, % p Inchad-Ll lsi: Ffald Peramaters medpltrad With: f k�It,E- Cueing Type: CpV 13w'o nlhen Ptirgo Rem: .160 nLAnbl Sampling Device: C, ParGwi kiurLwrYn, srlmdinu. 9oilm. P06, i lbw Tobin Type: Pm ih tuna moodurIng Point: 70C pillar: Pump Intake ri below 221:_jgj < Color Odor: vad, No Time: min Volume Pur ed OTW, lest Tomp pH etd unite SpC u&L- co m L ❑RP mV Turb NTU Commmda; stnb,Mradun Cdva? wipn.j Inge note G414NI, *f- 3% •,L Li unit *+- A *r im If. 10m11 J. lgy" 16 1 17 I lI 66 R p6 0- Zt7 y, u r 11 dx 17,56 is 47 t-AU - i$ tl t5 glmkUmnu mt nnm a rw [417 0 �.amvier-��1les�ad: �oahl�[rltt�; t. Swtrnrr, ft3 rYj'Te45 IS NO PWib'FZ HRi�31mg [c195kj 1� h I � rlmui IfylpYl IA • PawlsnnYLINRI Y.Ym d1YMf tiY PIPrr,Yxxa AM MPxwfb �, inr,mndn{Xm,mr, m,r e. "rlYumx,v..P1 h41r. {n PvIM n...,r�rPX blr,llow V �V Yea Yw P✓•tlrY MYtM�Aa,Hwr hwWYnWnIPxPI IM1d nor X IY41Ay on ulr x.Y luxwr rA. ddxY,lYn „I,d.In,d w,14ri TM1dlrullMWiu,lrn MMYM4.4r aY WxAMradaawTl xr 1111M PxN MI wile Y1M11 WFNY aI,IWfea.rW IaA4',Yrier�lk,,,Ab MlYr xrN 01 x, 161iir MYee M#r11{wY,MXXIx•WVMW4Yh YIPraYN1YMiMU14•L'ill pt-T'YIrW,Yew11W,W1IY III aAr PIYPIN']7PPl PYYjlPl lellu WaJNNU II Mr•IIIYNIxrYr III•MPhY dYrP „Y µi�T, WATER MATRIX SAMPLING 11 11`I`I WATER MATRIX SAMPLING FIERA AA TA FORM ` y.� � x FIELD DATA FORM E R* � SUa Nyma; RJRT Cdeeania Aoad Landoll .Icli: AM .116aft5 SalnpteTypm Clrclo urlV a 1R0r W6B pPT, Surfirdu Wuter, Pafeble WSW; other] SAm le ID. s - X� LWf• - Pate,, Sampling Psrsannal: Andrew:11 ethew woutha_r7C�a'p�d4lkons bun Pertl Cloudy, Coudy, PnM; 4tllsr_- __ _� _ -. _ — Mill Typir Pluulr Surleca Co0hpkml[nl wellLacked: Ye * Lock Prusmnl: !.ti' No r fdn Woll ID Info. on Tag: Yna% No Well Balled: Yee VA Well Pad C2—dlHpn; SWq, Add0lendi el Well Cp ; rnr. Now _ _ +nPFupincn, _.I her', kef — Well Cap CondlUbn: Wall Lade Lion- d oad) Rsyl"der 0m61 loe PHAI, rt.Meln. wooda, OIIhfT Total l7npth of Wall IT, n.j; Total Screen Length; 6, 10. t5. 24 IeotoFlMr. Depth to WAtor LP.UN : nk . , Wall Diameter: ., a. 6 1-11 wll,nr Fluid Pa remetere MIMI urep Ith: CasingT o; Sleel rnh- Purge Rofv+n ml-nln Sampling Device; Pademlllc, Monuen, runaroA Solknr. P139, :Jrrer: Tuohy Typv; + '•M Messudn Point: TOC ulhaf: . PL11,1p lnt:lhu eft holow M.P.:, Color, Odor: Yee, l llnu Jr111, Volume Pu ed DTW: lee[ Toltip plf JSW unlls spC a';' DO [m IL ORP mV Turh Tll Cbrnmbnln; Stdi'61 11" Crm,rid? nor,nn Iree Mole IM%Ayln •f. 31A •1- C.T unk H- 0% 'P '0% IF 10,AV W ibw 44 r r J U ). S. -- 1]ttrJal Samplingplil�7 Ts� � J 1] grgp Ile ayj; +!nslr tLRtttluaelntl. Preservallye: bRUm 4git; Lab'. Nwu III r}n W rMAlr1 Menn nopn d wl uxr Mrrpuyq rrvlrrryWq w irrxrrn,nrainp IF,raIM.rW h MnN,4 M xw wn W un al eh+ nllW�enrar+lnw 1 -Ip Mannwarrnaa Ir1«.xxL ry- md mwan�o� M.ml to umm,�al ae kr. r.rrnV 66Y 4 aarn/w,arxwe b InrA MwJaun r— M I y Wye M Sim Name, fURT Edwards Rood Landjpl Job 0.0;1r bl) SgmpldTVPa; Clfalt ante ,oa-o;i -PT, surmea water, potable WSW, otharj Law Sampling Perennnet: gadraw)A hlalhevr weatherCondttlona: 61OW Pen Cloudy, Claud, Form. Dllldr Well Type: Fpleh Su-ru, C:mm Ifo-n, el W411 Ta PYeriUM: o NO Wall Locked: /Ye»- Nv PrOO&MV No Wall 1. rnia, a7 Ta o' No _LOO WO!641ted: Yna, a Wol! CaClI Iw Wsll Ca Contlltldn: Renloro, 41nor; Wdll PAP Ce5pahlen; Cep-Jled, Fk loan, alh r Well Leratlon• m Psphml, Cuntrutu, Weeds, olhnr Addltlonal Comments: Toter Depth of W0 17.0.j: Screen Longtht a. 1� 15, 20 d ` fam-ullmr: — fl0 n le deter D.'r.w : "Iwell ye/ DlHrnator 2,no—pill- . •--_—_._—.—_ Flottl Perantatare mseaured With: Caaln Ty a: PVC, nlhPr Purge Rate: rnt ingn 8a'VIn9 Ds'JI cell Pedelullle, 10—on, nun d , Buller. FDB, VNr TuOin r a: nn PAaosuruT Polml TOC utnur. PumpIntakal i wM.P.: Color, oa Odor; Yea, a Time; min volume Pd ed OTW; Owl TbrnP florid pF+ units &PC LlSlum 00 m A:L ORO mV Turo NTU Comments: StnegIhnNan Gllualw Ilea (-0 n4m +J. J% I. 0.1 veil +i. 3% Ir 19% +1 10 mV •1. 10%, ]_ 77 (7 — U fZtlEdttlsSamallnn ❑nte A Tllrc: �{1^AWa�al _r Z)17 _ .�aIBPlaILS�lIa¢�rl, LulelvaleRaal�bsloe:. Preenrvallva L{��3�Ld�Ys1: Lam IkW L Illm.—nrrun—.IaYI,wMN,M•.11, AMIr YYIeM1Y rIW �'OIIIInMM•rWii1�,y„n elY nnx�Ilia, r1.r««.nY,r d«xx„xnenx� le- •YMIMn xraM, Ma1M,a I NII+n W IN�+I MAM��Igr N1MWaRnAx HI rwl Mi WhM bi,M w W Men IMI� P 1 4 p al ll Wley IniY M M4nA`al r.,ar..xry Ir w4i n'•Mr'ru+new„ , n to i, � WATjffJ4 MATRIX SAMPLING t.. l WATER MATRIX SAMPLING II FIFI-D DATA FORM ERR FIELD DATA FORM ERM silo lVYrne: RJRT Edwards Road Landllll Jelb q:17 ugdyi UrnplcType: Clydeene lRonilar WeW OPT, SurlaceWater. PotahloWSW; other) Sampling Personnel: Andruw F�.'14Akher M Weather Condltlonc Bunn Pahl c-I , cloud, vale; Omer Time: )ej Wo1I Typv:- FN_rh burtnpl t:n,n noon, apgr u cold ep well Ta PreeenL• a' No _ Well LPCkdi: R Na Lock PFAAArIt: dti AMr Well fO Info, on Tag: Nu Noll Balled; VII, No, Wall Ce m` No Well Ca Condition, e , Llawaa, Oamr Woil Pad Condklon: crw:x«t. RnpVou'1,. Ol11EI. Well Location• OrAe MIYWIq caOW491). Weeeb. 031a1. Addlllonal Cummenta; I olaI popth of Walt (T.P-): Go h to water A.T�W :111 _-•--- - $preen Length, Wetl PlAmei4 5, A 15 jo A, 5, a reetnlne,: Ineh-e 11 r Field Paramatars mcllrpurlld with: Calling Typo: 80101 eel., Purgo Rrrtu:.w ;.._ mUmb sampling bovine: Auo1 WWy M m-n, V& qWellw, Ppfl, b",: fukin9 TYAe' Pah'nln�uxer PLI.P Inteko (h below M.P.1L Maaaurin Ralnt: Cdor. Tar- Odor other Y.. Time. I Volume Purged 0TW1 fe L Tamp 'C PH glWLII l�J Spo uSlcm GO m ORP mV Turh N711 Comments: SloGulumlan cmerie W.III two note CohWl, .1. A +1. 01urtll +f. �m +F 16% '1. 16mV +1. lorfl CJ 4 5 C1 t •tar O U 51,03 ! r a p Le ful— QM4 „¢gmdllnabaie871rne. Jr%%�d,11 +wl 1 13) 6 %1w1"—CAt=L Anellm Hweetetl'. Praeatvauvrl &JILL III.wnlmwr. Yprnnkw,ne u'lrn, puy„ym u,xeini rxYrru.ul'Fnn,q wll..lwy u,.uw ux �wx'Y „nn.w M.whr.M'w.w,.hr,nulud b.l dIo,.,laYiwM..YnYnYw dY. Fnx,l M,rrnwrinwnl p hIU.1 Ml+h.l mA relit. .0 N Sil-Namd: RJHY FdWurda ROnd L. nrlill At-005NaM, Samplo Type; OTT IPonio eMter Wa OPT. SurfRee Water, Pmable WSW; other) Sample Ib: W - 1 , Uri. Ev III sampling POt00nLia1: Mi1fleW M. Weather Condlunna: sun , Port r:laud . MI UP: Olin? TIIne: � Weir Typai Flush Sur4Lw Cwnplallw, o u Con !nl Well Tog Present: , tdn Well Locked: die Lack Proson o No wen Ib Ins, on TB uh, No Well Bolmd: rre, Well Ca ruk. No wen Ca CondlAlan! Wolsw, Oeler Wall Pad CondltlOn: CrRlkatl, SoplActl. 011lm', Wall I.adnllon;'m x AePIUYIl. Co-rlerelo, Wtkha, r7}ka� Addltlonal Comments Total PrpIP tl( WWI LIP-): Z r o�pthrewater o.T_W:i� ' 1la_6_ S_tr@dn I I-ulh: W9IIMIIn 414r: '.I. 10, Ib, 70 g.? foh0.otllrtr: 4, a. 0 IodineoIhhr. FI_c10 Paremotom Inteaurad wlth: puma Cosing Type; , &pal &I'd, Pdtgo Rate; NIYit,7 mLhSln $ampling De Ylee: Pene191r6 MdlYlael pruedle 9111". PU13. 17nler. T intaType: rdyot[nnnr. PLht115 Ilnnke (rl L06W M.P.pI L °'t`i hAoaxuringPafnC L`dlor: TOC other. 6dcr v-, Nq 'I'Inle mill Voiudw Fur 9tl L)Tw: Poet lamp pH Id un 1s SpC watern NJ m OAP mV Turh NTU Commenfa: SI161kmhan C111.w I nllonn (Ike Min 11,Aw? +} 3t 11. QT LNI ./. ..% r/. lots 0. 10mv .Il. 109:1 Iv,Yla` a � ll �lr; e.1c5 i14 w.r1 t iT• IG c — i.,,st� la 2 U It[%.#G l�,i,+• l•9'• -`14 # .11 1" . � (, . its -• [�rs3 �-_-_-� is 5•u �!, , i � 7d c,C� III U li Iop oz o _ OHlclal SampJlflg ISBte tk TImB: 1.6rz��Y I �1 H zQ Hold Time tutml: L2 3i1!2Le4931I Amh ula Reaueslett: p(esa IY.@, Etpulgle Now �1 SVrPA Tf/TDS ArrV(F M4r'Fi4j 14 III a n.V e.wrw xYpM1 r YK1r111>M urdl.M.7lYlilr�p MY umrml Y'Ww uww,grYvYl Mer Yl�r,nhlhrnhlYn{en IM WYh�lrr, (!I. i'y,InM u11nN hr rM w Inw mwl rxnl emw¢ul.n mNeamAnMY In r.YlM.mx,n lnwrl leM Yw au'I.1 epult 14.yblYlr lY tlel„rY 11 Niw�/IY YIMII VnMwwl MYn0l wll,m r7, WATER MATRIX SAMPLING FIELD DATA FORM 4a ERM She Namo: RSRT GQWArdl, landrlll .Irrh d:p598t19$ Sample Type: Clmle ant- • IMonnar pyep, OPT, sllr(dae Wntar, Potshla WSW; wiln r) Dsta_ SampRnS Pomonnel; WorittroY t;oPtlplorte_ r+Ylrhr cwuor. cw11nV, R11nr olenrne�-, Imo= Wall lype,: lu h sv(L,u 4 tie 91id1 Lie Corn don Well TagPrasent Yuy Nn Wall Cooked: Yeo, c4gy._ Cook Present: Vq., Wall ID Info. on Tag, Yod, No Wall adtod: YO&ANIn Well Ca : l No Well Gap Condltlon: Rsa1a Rlher• Well Pod condnn; ltlC . deed. qs , oiW AddltionComments; ual Well LorMi_nn; 13mee. Aeplvil onorelo J WOW$ Cray Te1G{ Doptll of Well (T.D.jtTO Depth toter D.T.W i I" .a 8craan Lonpl l r: Wall Dlarnater: R, 19. % 8e j a 2, 4, s ara6dhdn l.ldlde.ds,nr. Field Parameters measured with: CasingTy r'Y4. CNO dher P4rna Rate: e-l' ML&A . Samprillg Davias: I'edWaVile. MarmnGn. rlpf�,glarrPu,, Pno, olh.1- Tuhln T e: I Iq nr T Msa9nrlrt P01111: TOG alhd(, I.—. 7um Intake ft slaw M.P.Ii n Color: r..v Odon o Time: min Volume Pbr ed PTw' feel Temp Ci pry utd UN10 SpC 15f rl 6o tin 1L ORP mV Turb NTV Comm9ns: 9lrhallashnn Crwie llanal Ianu main hul.w}i .1. 3% •1. d.land n;. 3% Ati 10% tN lalov 1.11 7R76y iJ U I., O rYktC21' �r. G.3-7 G +� , C6 t7Hlcel6nn11414:1�R$1LRli �/,�RI %�T� e�aB]gJk$ c�Jg.rtpp; pfyehn lc Reaueeted; Ii@.441Y@4L� [jold T1m$,(daye); Imo: ttalae 1 )m tlnPih,nY�.nxul xa�leRnxlNrix,'L'�XYexn„ny.Ayn,ynisx nnulriaMixpllxx O,niMu.rwingr. Iny++hmlwn pa.rre rwl ca,rrrgw, r�uAx,.�.MY m ,.Ia rtr.arAni 1. r,.x wn. w.m.,al.rlt.»n vend I.. h.lo,.,.a.Yr,. rc r .ho.iu �o.r �rPsylq WATER MATRIX SAMPLING FIELD VATA FORM W! ERM Slra Nam., ItJRT 5dwotd1 Gaud Lnrrdpl Job NiO5RtWW5 Sample Typo: Drcla one -(Monitor WRIT. PP , &UNaI'a wale Pntehla WSW; athar)_ ._ --- SaM�ID] Dato 8-_mLH2 Pot Onhal: draw lhew WghtllhrCpneitiona_ rn JNd 16l dy, oudy, Rkh' OHM TIMo: WaIL� a: Musheur1wd Coln Iloe 9ilckup Glyd,6,9dn Well L,vckad: Yea, No Look Proswm Ym, Iry WpHTo Pneeantf Yoc, No Wpll ID into, an Tag: Yce, Nd — Well Bolted: Yue. Nb, WA Walt Cap: 705, Nn _ Well Pad Cbndlllon: 13o_a_dCmO d._ Rl zy loon. 0ihm Addltlanel Commense: Wetl Cap Condition: i➢euo, Rndaee, 411erL _ Well Loaatlon: gium- Aepaon, .cnnorwn, Wn'd � Al ... To1Hl Oe�th at WAIT (TP.]: _._.. Screen Lrtnyth: S, 19, 15, 29 fuel-alhen Depth to Water. D,T. : al Well Dlemeter. 2, A. 8, 8 _ Inewd-dinet Field Parameters meASUNti Wilh: 0aalug TYA4: w%. SI041 atllbr. Pur1�4 RI1t0' muiYri 9nmpnng DoVice: nix O.RC, rnonxuorl. & ldf... ndlh. Poe. D111W Tuhln T a: fnrynlnylmnc klmp lhtyku (11 Htlow M.p,f: MsasuringPolnl: -TAG Cc)or: Odor: afhac YCr, Ne TVrrler, mllj_. Volume l'ur atl 1)7W: loetf (are Furl. bckr.), Tana C I'll sldunHa $PC 04krn co W1410 DRP mv Turb NTt) Cprr; rorilt S atnlheulwn Crrww' alnnb) rl- 37^ u. cAsill .1. 3% •e. 1R% 10mv 1w _3p 55— ' -td d,Lf 0 f - tU 76 U. 55 �tv5- Q i� {7. 5 , 1 —Ild 7 11 e. f j d GU-GuS- L 1.f Qp�al T!mrl; _Le)jL 29 1- Sumales GQll�led:. Any In RequaeW : PTea{31 M YE ,HpIC SammLQuYkh Lola: &AU: (r1 lL,yr YnAWM iIAM to hol,rn Yl rxrl ix Yi.An Yr•,MO.W gxMlAlyl.nlN�Y M.I W+RIP,y IRA IRI I�IATAIA.�M'nrM1r MY 7nI,nR rn 0ic4ulor 4lnrY I.YYJri11PrY IM•�,� IVrYHxRM nuyilx•xYr rslrw«6vrytlr•n lnrnr4n lx Nlr rM1rhnl.n,Y Ar lrl n.rrltlfexlAla WMryIAn PYwnyrylMYxq,nIR+RPMIYYIry�lnn Yry, z C 3 cr ERM has over 160 offices across the following countries and territories worldwide Argentina The Netherlands ERM's Charlotte, NC Office Australia New Zealand ERM NC, Inc. Belgium Norway 300 West Summit Avenue, Suite 330 Brazil Panama Charlotte, North Carolina 28203 Canada Peru Chile Poland T: 704-541-8345 China Portugal F: 704-624-7928 Colombia Puerto Rico France Romania www.erm.com Germany Russia Hong Kong Singapore India South Africa Indonesia South Korea Ireland Spain Italy Sweden Japan Switzerland Kazakhstan Taiwan Kenya Thailand Malaysia UAE Mexico UK Mozambique US Myanmar Vietnam -3c The business of sustainability ERM