8106_DukeRogers_Oct2021_SemiAnnualGWMR_FID1642225_20220204

OENUSE ONLW '',I 1 ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any Information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(1).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
consultant, facility owner):
Wood Environment & Infrastructure Solutions, Inc. (Consultant)
Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address:
Name: Anthony Kellogg Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC
Rogers Energy Complex
Power Road
Coal Combustion Products Landfill
L573Duke
resboro, North Carolina 28114
Ej
.0500
October 14, 2021
Phases I, 11, 111, and IV
Environmental Status: (Check all that apply)
Initial/Background Monitoring ❑X Detection Monitoring Assessment Monitoring Corrective Action
T e of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells Methane gas monitoring data
Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify)
X Leachate monitoring data
X Surface water monitoring data ❑ Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
)( Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Helen Corley Principal Hydrogeologist [phone]
Facility Representative Name(Print) Title (Area Code)Telephone Numbersl �ttt /jI
Digitally signed by Helen CorleyAffix NC Li@ µ!IP 7L�$l a Geologist Seal
Helen Corley Date: 2022.02.0413:47:39-0500' 1 �R �///�
Signature Date
�..•: r cni o a.T�N°°°°..
2801 Yorkmont Road, Suite 100, Charlotte, North Carolina 28208
Facility Representative Address
Engineering: F-1253, Geology: C-247
NC PE Firm License Number (if applicable effective May 1,
om,a.. amnno

wood.
Semiannual Groundwater Monitoring Report
Duke Energy Rogers Energy Complex
Rogers CCP Landfill, Phases I, II, III, and IV
Permit No. 8106
Prepared for:
Duke Energy Carolinas, LLC
Prepared by:
Wood Environment & Infrastructure Solutions, Inc.
2801 Yorkmont Road, Suite 100
Charlotte, North Carolina 28208
[phone]
February 3, 2022
Project No. 7812-20-0571.02
Copyright © 2022 by Wood Environment & Infrastructure Solutions, Inc.
All rights reserved.

February 3, 2022
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
Subject: Semiannual Groundwater Monitoring Report
Rogers Energy Complex
Rogers CCP Landfill, Phases I, II, III, and IV
Permit No. 8106
Wood Project 7812-20-0571.02
wood.
Wood Environment & Infrastructure Solutions, Inc.
2801 Yorkmont Road, Suite 100
Charlotte, North Carolina 28208
T:704-357-8600
www.woodpic.com
On behalf of Duke Energy Carolinas' CCP Landfill monitoring program, Wood Environment & Infrastructure
Solutions, Inc. (Wood) is pleased to submit this Semiannual Groundwater Monitoring Report for the Rogers
CCP Landfill located at the Duke Energy Rogers Energy Complex (formerly Cliffside Steam Station) in
Mooresboro, Rutherford County, North Carolina. Wood prepared this report based on information and data
provided by Duke Energy. Field sampling, laboratory analyses, and data validation were not performed or
overseen by Wood.
If you have questions regarding this submittal, please contact Ms. Helen Corley at [phone].
Sincerely,
Wood Environment & Infrastructure Solutions, Inc.
17
Anthony Kellogg
Senior 1 Project Manager
r
Morgan Snead
Staff Scientist
Attachments
*b-Vt- C6h
Helen P. Corley, LG, BCES
Principal Hydrogeologist
'Wood' is a trading name for John Wood Group PLC and its subsidiaries

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2027 Sampling Event
TABLE OF CONTENTS
Page
Tableof Contents............................................................................................................................................ii
SECTION 1
- BACKGROUND.......................................................................................................................................1
1.1
Site description..................................................................................................................................1
1.2
Hydrologic Setting............................................................................................................................2
1.3
Monitoring Program........................................................................................................................2
SECTION2
- METHODS................................................................................................................................................4
2.1
Sampling and Analysis Methods.................................................................................................4
2.1.1 Groundwater, Surface Water, and Leachate............................................................4
2.1.2 Supplemental Surface Water.........................................................................................5
SECTION3
— RESULTS...................................................................................................................................................6
3.1
Site Groundwater Flow....................................................................................................................6
3.2
Analytical Results...............................................................................................................................6
3.2.1 Groundwater........................................................................................................................6
3.2.2 Surface Water......................................................................................................................7
3.2.3 Leachate................................................................................................................................ 8
3.2.4 Quality Assurance / Quality Control...........................................................................8
FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3 Shallow Aquifer Water Table Map, October 2021
Figure 4 Bedrock Aquifer Potentiometric Surface, October 2021

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event
TABLES
Table 1
Well Construction Information
Table 2
Groundwater Flow Velocities
Table 3
Field Parameters
Table 4
Groundwater Field Results and Analytical Detections
Table 5
Field and Analytical Results that Equal or Exceed Groundwater Quality Standards
Table 6
Surface Water Field Results and Analytical Detections
Table 7
Leachate Field Results and Analytical Detections
APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
Appendix C Charts of Groundwater Elevation, pH, Chromium, Cobalt, Iron, Manganese, and
Vanadium over Time

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event wood.
SECTION 1 - BACKGROUND
1.1 SITE DESCRIPTION
The Rogers Energy Complex (formerly Cliffside Steam Station) is located at 573 Duke Power Road in
Mooresboro, Rutherford County, North Carolina. The station is owned and operated by Duke Energy
Carolinas, LLC (Duke Energy) and generates electricity by combustion of coal and natural gas. The Rogers
Coal Combustion Products (CCP) Landfill is located southwest of the Rogers Energy Complex and
northeast of the intersection of Old U.S. Highway 221A and Ballenger Road.
The landfill is permitted under the North Carolina Department of Environmental Quality (NCDEQ) Solid
Waste Permit No. 8106-INDUS-2009. The original landfill (Phases I and II) was constructed with an
engineered liner system and is permitted to receive the following materials: coal combustion residuals
(CCR) (such as fly ash, bottom ash, Flue Gas Desulfurization residue); waste coal; landfill leachate (used as
dust suppressant or in accordance with the vacuum waste section of the Operations Plan); sludges
(including, but not limited to, leachate basins, sediment and/or stormwater ponds, sumps, waste water
treatment, cooling towers, coal pile, and coal pile drainage features); stone (including, but not limited to,
limestone and ballast); water treatment system adsorption and filtration material; air emissions treatment
products; mill pulverizing residuals; conditioning agents introduced to CCR prior to entering the landfill
(including, but not limited to, lime kiln dust); vacuum truck waste (in accordance with Section 2.1.6.2 of the
Operations Plan); de minimis inert debris (including, but not limited to, filter bags, geotextiles, abrasive
blast material, etc.); soil; waste soil; comingled soil/CCR; de minimis petroleum impacted soil; sediments;
vegetation (in accordance with Section 2.1.6.3 of the Operations Plan); demolition waste from basin
closure activities (in accordance with Section 2.1.6.1 of the Operations Plan); and other waste streams
produced by electric generation facilities.
Phase I of the CCP Landfill has a footprint of approximately 23 acres while Phase II has a footprint of
approximately 15 acres. Waste was first placed into the landfill on October 24, 2010. Phases III and IV of
the landfill expand the existing landfill footprint to the east. The Permit to Operate includes an area of
16.9 acres for Phase III and 16.2 acres for Phase IV. Phases III and IV of the landfill include a liner system
that provides two geosynthetic barrier components (a 60-mil High Density Poly Ethylene geomembrane
and a geosynthetic clay liner) between waste and groundwater. On May 5, 2021, Duke Energy received
approval to operate Phase III and began placing waste in Phase III on July 6, 2021. On July 26, 2021, Duke
Energy received approval to operate Phase IV. No waste has been placed in Phase IV.
The location of the CCP Landfill in relation to the Rogers Energy Complex is shown on Figure 1.

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event \ A /w A
1.2 HYDROLOGIC SETTING
The site is in the Inner Piedmont Belt of the Piedmont Physiographic Province, near Cliffside, North
Carolina. The Piedmont Physiographic Province in North Carolina is characterized by gentle to steep, hilly
terrain with small quantities of alluvium. The Inner Piedmont is bounded on the northwest by the Brevard
Fault zone, on the southeast by the Kings Mountain Belt, and by the faults and shear zones that define the
central Piedmont structure.
As typical in the Piedmont region, groundwater is present within the residuum, saprolite, partially
weathered rock, and fractured bedrock beneath the CCP Landfill. In general, surface drainage from the
CCP Landfill site flows from the west to the north towards Duke Power Road, and to the south and east
towards Suck Creek. The highest elevations at the landfill site are along the western edge of the landfill.
Two streams are near the CCP Landfill. Suck Creek is located approximately 1,200 feet southeast of the
landfill and flows north to the Broad River. Surface waters draining to the Broad River are classified as WS-
IV per NC 15A NCAC Subchapter 02B. An unnamed tributary to the Broad River is located approximately
1,100 feet west of the landfill. Based on evaluation of local topography, shallow groundwater beneath the
landfill liner is expected to discharge to Suck Creek.
The landfill and surrounding topographic and physiographic features are shown on Figure 1 and Figure
2.
1.3 MONITORING PROGRAM
Environmental monitoring at the Rogers CCP Landfill is performed pursuant to the Water Quality
Monitoring Plan (WQMP) for the Rogers CCP Landfill'. As described in the WQMP, the monitoring
program consists of sampling and analyses of groundwater, surface water and leachate from the following
locations:
1 Water Quality Monitoring Plan (WQMP) for Rogers CCP Landfill. Prepared by Wood (March 11, 2019) and approved by NCDEQ (January 8, 2020).

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event
Monitoring Wells:
wood.
CCPMW-1 S
CCPMW-1 D
CCPMW-2S
CCPMW-2D
CCPMW-3S2
CCPMW-3D
CCPMW-4
CCPMW-5
CCPMW-6S
CCPMW-6D
CCPTW-2
CCPMW-7
CCPMW-8
CCPMW-10
CCPMW-11
Surface Water Sample Locations:
CCPSW-1 CCPSW-2 CCPSW-3
Leachate Sample Locations:
CCP-Leachate CCP-Leachate-34
A summary of monitoring well construction information is presented in Table 1. Sample locations for
groundwater, surface water, and leachate are shown on Figure 2.
Monitoring wells CCPMW-7, CCPMW-8, CCPMW-10, and CCPMW-11 are Phase III and IV landfill
expansion wells that were installed in July 2020 and were included in the routine sampling due to the
operation of the Phase III landfill.
Surface water sample CCPSW-1 is collected from Suck Creek at a location upstream of the landfill. Sample
CCPSW-2 is collected from Suck Creek in a location downgradient of the landfill and the leachate basin.
Sample CCPSW-3 is collected from a drainage swale that runs parallel to Old U.S. Highway 221A and flows
north towards the Broad River.
CCP-Leachate is an untreated leachate sample collected from the discharge pipe of the leachate basin. In
October 2021, an additional leachate sample (CCP-Leachate-34) was added to the sampling network
because Phases III and IV have a separate leachate port into the leachate basin from Phases I and II.
2 Monitoring well CCPMW-35 was not sampled during the October 2021 sampling event due to insufficient water volume for purging/sampling.

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event wood.
SECTION 2 - METHODS
2.1 SAMPLING AND ANALYSIS METHODS
Groundwater, surface water, and leachate sampling was performed by Pace Analytical Services personnel
(Pace Analytical Field Certification #5342) on October 14, 2021 in stated accordance with the North
Carolina Solid Waste Management Guidelines. Copies of the field sampling forms are included in
Appendix A. The parameters and constituents analyzed were selected in stated accordance with the
WQMP and guidance from the NCDEQ Division of Waste Management, Solid Waste Section. The samples
were analyzed by the Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248)
and analytical results were provided to Wood on November 19, 2021 by Duke Energy. The laboratory
reports and chain -of -custody forms are included in Appendix B.
Wood noted that supplemental analyses for alkalinity, calcium, magnesium, potassium, nitrate, and
sodium were performed, which are not required by the WQMP. These data are included in laboratory
analytical reports in Appendix B but not reported upon herein.
2.1.1 Groundwater, Surface Water, and Leachate
The groundwater, surface water, and leachate samples were analyzed using the following analytical
methods:
• Barium, boron, copper, iron, manganese, and zinc using Environmental Protection Agency (EPA)
Solid Waste (SW)-8463 Method 6010D;
• Antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, nickel, selenium, silver, thallium,
and vanadium using EPA SW-846 Method 6020B;
• Chloride, fluoride, nitrate as nitrogen, and sulfate using EPA SW-846 Method 9056A;
• Mercury using EPA SW-846 Method 7470A; and,
• Total dissolved solids using Standard Method (SM) 2540C.
3 EPA Hazardous Waste Test Methods (SW-846)
4

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event wood.
2.1.2 Supplemental Surface Water
In addition to the analyses listed above, surface water samples were also field -filtered using a 0.45-micron
in -line filter, and analyses of filtered samples were performed for the following constituents using the
following methodology:
• Zinc using EPA SW-846 Method 6010D; and,
• Cadmium, chromium, copper, lead, nickel, and silver using EPA SW-846 Method 6020B.
These analyses of filtered samples were performed to supplement analyses required by the WQMP.

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event wood.
SECTION 3 — RESULTS
3.1 Site Groundwater Flow
Groundwater elevation contours and flow directions in the vicinity of the CCP Landfill for the shallow and
bedrock aquifer wells are shown on Figures 3 and 4, respectively. These contours were developed using
the measured depths to water, prior to sample collection on October 14, 2021. The potentiometric surface
contour map (i.e., water table) for the shallow, unconfined aquifer indicates a direction of groundwater
flow mostly to the east and southeast toward Suck Creek. The calculated horizontal gradient ranges from
approximately 0.02 feet/foot in the north to 0.03 feet/foot in the south. The bedrock aquifer
potentiometric surface displays a similar direction of groundwater flow to the northeast, east and
southeast with a hydraulic gradient range from 0.02 to 0.03 feet/foot. The similarity of the shallow and
deep aquifer maps is indicative of hydraulic connectivity. Calculated groundwater flow velocities are
presented on Table 2.
Historical groundwater elevations have been charted on a hydrograph included in Appendix C. The
hydrograph indicates minimal seasonal fluctuations. The wells with the highest water elevations were
observed in the upgradient, western side of the landfill (CCPMW-1 S, CCPMW-1 D).
3.2 Analytical Results
Analytical results from the October 2021 monitoring event are presented in the following sections.
3.2.1 Groundwater
Laboratory results for groundwater samples were compared to the Title 15A NCAC Subchapter 02L
Standards (02L Standards) and Interim Maximum Allowable Concentrations (IMACs). Exceedances of the
02L Standard or IMAC were reported in one or more wells for the following constituents: pH, chromium,
cobalt, iron, manganese, and vanadium. A summary of field parameters recorded prior to sample
collection is presented in Table 3. Analytical detections for the current sampling event are presented in
Table 4.
Analytical results for the six parameters whose values are either outside of or above their respective
standards (pH, chromium, cobalt, iron manganese, and vanadium) and a comparison to historical data are
presented in Table S.
The values for pH were consistent within the range of historical readings, except for CCPMW-8, CCPMW-
10, and CCPMW-11. CCPMW-8 had a value less than its historical range. CCPMW-10 and CCPMW-11 had
values at the upper bound of their historical ranges. A chart of pH readings over time is included in

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event wood.
Appendix C. The 02L Standard defines an acceptable range for pH from 6.5 to 8.5 units. The chart shows
that most historic pH data consistently fall below the lower 02L Standard range, with two exceptions
above the range. The two wells with a history of pH values between 9 and 11 units, CCPMW-2D and
CCPMW-5, may have had well damage from grout intrusion to the well screen. CCPMW-2D and CCPMW-
5 were redeveloped in October 2021 ahead of the October 14, 2021 sampling event. The pH values
recorded at CCPMW-2D and CCPMW-5 for this sampling event were within the acceptable range.
Chromium concentrations exceeded the chromium 02L Standard of 10 pg/L in one well (CCPMW-5) and
the concentration in this well was within its historical range. A chart of chromium concentrations over time
for this well is included in Appendix C.
Cobalt concentrations exceeded the cobalt IMAC of 1 pg/L in three wells (CCPMW-1S, CCPMW-6S, and
CCPMW-8). The cobalt concentration in CCPMW-6S was within its historical range while the cobalt
concentrations in CCPMW-1S and CCPMW-8 were less than their historical ranges. A chart of cobalt
concentrations over time for these wells is included in Appendix C.
Iron concentrations exceeded the iron 02L Standard of 300 pg/L in one well (CCPMW-8) and the
concentration in this well was within its historical range. A chart of iron concentrations over time for this
well is included in Appendix C.
Manganese concentrations exceeded the manganese 02L Standard of 50 pg/L in one well (CCPMW-7) and
the concentration in this well was less than its historical range. A chart of manganese concentrations over
time for this well is included in Appendix C.
Vanadium concentrations exceeded the vanadium IMAC of 0.3 pg/L in seven wells (CCPMW-2S, CCPMW-
2D, CCPMW-5, CCPMW-6S, CCPMW-7, CCPMW-8, and CCPMW-11). The vanadium concentrations in
CCPMW-5 and CCPMW-8 were within their historical ranges, concentrations in CCPMW-2D and CCPMW-
6S were less than their respective historical ranges, and concentrations in CCPMW-2S, CCPMW-7, and
CCPMW-11 were greater than their respective historical ranges. A chart of vanadium concentrations over
time for these wells is included in Appendix C.
3.2.2 Surface Water
A summary of surface water analytical detections is presented in Table 6. A summary of field data
parameters recorded prior to surface water sample collection is presented in Table 3. Laboratory results
for the surface water samples are compared to Title 15A NCAC Subchapter 02B Standards (02B Standards)
for Class WS-IV surface water. Suck Creek discharges to the Broad River and is classified as Water Supply
IV (WS-IV) for waters used as a source of water supply for drinking. Federal primary and secondary MCLs
are shown in Table 6 for informational purposes only.

Duke Energy Carolinas, LLC I Semiannual Groundwater Monitoring Report
Rogers CCP Landfill
October 2021 Sampling Event wood.
Surface water standards for cadmium (dissolved), chromium (dissolved), copper (dissolved), lead
(dissolved), nickel (dissolved), silver (dissolved) and zinc (dissolved) were calculated using an average
carbonate/temporary hardness as alkalinity value for surface water for the October 2021 event (13.5 mg/1)
per NC 15A NCAC 02B Water Quality Standards for Surface Waters (https://deq.nc.gov/documents/nc-
stdstable-06102019). There were no exceedances of 02B Standards during the October 2021 sampling
event.
3.2.3 Leachate
A summary of field data parameters recorded prior to the leachate samples collection is presented in
Table 3. A summary of analytical detections is presented in Table 7. Leachate results are not compared to
02L or 02B Standards.
3.2.4 Quality Assurance / Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and analysis of
one field blank to evaluate if contamination was imparted to the samples by the sample container,
preservative, or other exogenous sources. The field blank was collected during surface water sampling and
analyzed for dissolved metals. Chloride, chromium (dissolved), and nitrate (as nitrogen) were reported at
an estimated concentration (J-flagged value) that exceeded the MDL in the field blank; however, the
concentration did not exceed the 02L Standard.
A duplicate sample was collected from well CCPMW-2S (identified as CLS_FD-1) at the same time and
from the same source as the CCPMW-2S sample to estimate sampling and laboratory analysis precision
by calculating relative percent differences (RPD). Two laboratory analytes (arsenic and copper) were
detected in either the parent or duplicate sample (at estimated concentrations below the reporting limit)
but were not detected in the other sample. Sixteen analytes were detected in both the parent and
duplicate samples, with RPD values ranging from zero (nitrate as nitrogen) to 129.41% (iron).
Select samples were diluted, as is normal laboratory practice, to bring samples within the calibrated range
of the analysis. Specifics regarding the samples that were diluted, including the dilution factor, are
included in the lab report. Additional QA/QC data, laboratory analyses, and chain -of -custody forms are
included in Appendix B.

wood.
FIGURES

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NOTE: C
1. LANDFILL BOUNDARIES, SAMPLE LOCATIONS AND TOPOGRAPHY PROVIDED BY DUKE ENERGY CAROLINAS
2. HYDROGRAPHY OBTAINED FROM THE NATIONAL HYDROGRAPHY DATASET AND DUKE ENERGY CAROLINAS �o° 800 a
3. SERVICE LAYER SOURCE: ESRI DIGITAL GLOBE, GEOEYE, EARTHSTA GEOGRAPHICS, USDA, USGS, AEROGRID, / 0 450 900 Feet
IGN AND THE GIS USER COMMUNITY`
4. GROUNDWATER ELEVATION MEASURED ON OCTOBER 14, 2021 ~�. �"'<%
a 70 p
LEGEND BEDROCK AQUIFER POTENTIOMETRIC SURFACE MAP
OCTOBER 2021
PROPERTY BOUNDARY STREAMS GROUNDWATER MONITORING WELL PHASE I AND II ROGERS ENERGY COMPLEX
LANDFILL LIMIT OF WASTE ROADS GROUNDWATER MONITORING WELL PHASE III AND IV CCP LANDFILL PHASE I, II, III AND IV DUKE
wood*-' LANDFILL REVIEW BOUNDARY RAILROADS GROUNDWATER CONTOURS (5 FEET) PERMIT NO.8106 ENERGY®
LANDFILL COMPLIANCE BOUNDARY INTERPRETED GROUNDWATER FLOW DIRECTION RUTHERFORD COUNTY, NORTH CAROLINA
TOPOGRAPHIC CONTOURS (2 FEET) PROJECT NO: FIGURE NO:
(801.38) GROUNDWATER ELEVATION (FEET) 7812200571.01 4
F:\AMEC_Projects\2020\7812-20-0418 Cliffside Rodgers\7812-20-0571\MXD\DeepContours.mxd, Prepared By: leanna.muroski, Checked by: MAS Date:1/31/22

wood.
TABLES

Table 1 - Well Construction Information
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Date Data Received from Duke:
19-Nov-21
Sample Date(s):
14-Oct-21
Well ID
Well Installation
Date
Latitude
Longitude
TOC
Elevation
(ft)
Ground
Surface
Elevation
(ft)
Well Stick -Up
Height Above
Ground Surface
(ft)
Depth to
Water
Below TOC
(ft)
Ground-
water
Elevation
(ft)
Total Well
Depth
(ft bgs)
Screened
Interval
(ft bgs)
Aquifer
Geology of
Screened
Interval
Well
Diameter
(in)
Casing
Type
CCPMW-1S
2/23/2010
35.20670
-81.77430
875.58
873.24
2.34
37.30
838.28
40.0
30.0 40.0
Shallow
PWR
2
PVC
CCPMW-1 D
2/24/2010
35.20671
-81.77430
875.89
873.33
2.56
38.12
837.77
54.0
49.0 54.0
Bedrock
Bedrock
2
PVC
CCPMW-2S
2/24/2010
35.20355
-81.77274
842.24
840.26
1.98
39.25
802.99
42.0
32.0 42.0
Shallow
Saprolite
2
PVC
CCPMW-2D
2/24/2010
35.20355
-81.77272
842.35
840.20
2.15
40.97
801.38
70.0
65.0 70.0
Bedrock
Bedrock
2
PVC
CCPMW-3S
6/27/2007
35.20341
-81.77102
811.56
809.30
2.26
14.71
796.85
14.0
9.0 14.0
Shallow
Saprolite
2
PVC
CCPMW-3D
7/16/2007
35.20341
-81.77100
811.74
810.47
1.27
18.23
793.51
31.0
26.0 31.0
Bedrock
Bedrock
2
PVC
CCPMW-4
10/26/201S
35.20893
-81.77482
845.95
843.29
1 2.66
28.89
817.06
65.0
50.0 65.0
Bedrock
Bedrock
2
PVC
CCPMW-5
10/23/2015
35.20993
-81.77285
858.63
855.87
2.76
43.54
815.09
72.5
62.5 72.5
Bedrock
Bedrock
2
PVC
CCPMW-6S
10/21/201S
35.20867
-81.77112
854.35
851.48
2.87
38.78
815.57
43.5
33.5 43.5
Shallow
Saprolite/PWR
2
PVC
CCPMW-6D
10/26/2015
35.20865
-81.77110
854.38
851.45
2.93
38.72
815.66
60.0
50.0 60.0
Bedrock
Bedrock
2
PVC
CCPMW-7
7/20/2020
35.20779
-81.769"
855.49
852.63
2.86
42.41
813.08
47.0
37.0 47.0
Shallow
Saprolite/PWR
2
PVC
CCPMW-8
7/6/2020
35.20372
-81.76946
831.52
828.24
3.28
44.57
786.95
45.0
35.0 45.0
Shallow
Saprolite/PWR
2
PVC
CCPMW-10
7/7/2020
35.20338
-81.76842
812.98
810.45
2.53
32.70
780.28
42.0
32.0 42.0
Shallow
Saprolite
2
PVC
CCPMW-11
7/1/2020
35.20381
-81.76675
803.32
800.24
3.08
21.34
781.98
30.0
20.0 30.0
Shallow
Saprolite/PWR
2
PVC
CCPTW-2
2/25/2010
35.20386
-81.77043
841.72
839.62
2.10
1 45.00
1 796.72
45.0
35.0 45.0
1 Shallow
PWR
2
PVC
Prepared by: MAS 11/29/2021
Notes: Checked by: ZJD 121212021
1. ft indicates feet
2. PWR indicates partially weathered rock
3. TOC indicates top of casing
4. in indicates inches nominal diameter
5. PVC indicates polyvinyl chloride
6. bgs indicates below ground surface
7. Elevations based on NAVD88 vertical datum; horizontal coordinates based on the NAD83 datum
8. Well information from well construction records, boring logs, Water Quality Monitoring Plan and previous reporting
9. According to Pace Analytical Field Data sheets, monitoring well CCPMW-3S was not sampled during the October 2021 sampling event due to insufficient water volume for purging/sampling.

Table 2 - Groundwater Flow Velocities
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Date Data Received from Duke:
19-Nov-21
Sample Date(s):
14-Oct-21
Aquifer
Hydraulic Gradient
(ft/ft)
Hydraulic
Conductivity
(ft/day)
Effective
Porosity
M
Groundwater Velocity
(ft/day)
Shallow (North)
0.02
1.02
20
0.09
Shallow (South)
0.03
1.02
20
0.14
Bedrock (North)
0.02
1.3
5
0.51
Bedrock (South)
0.03
1.3
5
0.74
Notes:
1. ft/ft indicates feet/foot
Prepared by: ZJD 12/13/2021
Checked by: NAH 12/13/2021
2. Hydraulic gradients are approximate. Groundwater flow direction beneath different landfill areas represented by flow
arrows on Figures 3 and 4 for October 14, 2021 measurements
3. Hydraulic conductivity values, average of PWR and Saprolite for Shallow Aquifer and average of Bedrock, presented is from
Permit to Construction Application, Phase 11 of the Cliffside CCP Landfill, February 2072
4. Effective porosity presented is from Permit to Construction Application, Phase 11 of the Cliffside CCP Landfill, February 2072

Table 3 - Field Parameters
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Date Data Received from Duke:
19-Nov-21
Sample Date(s):
14-Oct-21
Sample ID
Date
Well Depth
(ftbgs)
Depth to
Water
Below TOC
(ft)
Groundwater
Elevation
Appearance
Odor
Average
Pump
Rate
(mL/min)
Well
Volume
(gal)
EVAC
Volume
(mQ
Temperature
CQ
Specific
Conductance
(PS)
pH
(SU)
Turbidity
(NTU)
ORP
(mV-NHE)
DO
(mg/L)
CCPMW-1S
10/14/2021
40.00
37.30
838.28
Clear
None
60
0.84
2,100
21.1
26.0
5.1
1.0
87.4
6.7
CCPMW-1D
10/14/2021
54.00
38.12
837.77
Clear
None
120
3.07
2,400
18.9
48.9
5.4
0.4
119.6
6.0
CCPMW-2S
10/14/2021
42.00
39.25
802.99
Slightly Cloudy
None
100
0.82
2,000
20.8
55.8
5.2
8.2
193.2
6.3
CCPMW-2D
10/14/2021
70.00
40.97
801.38
1 Clear
None
80
5.19
37,600
18.8
121.4
8.4
0.5
108.0
3A
CCPMW-3S*
10/14/2021
14.00
14.71
796.85
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
CCPMW-3D
10/14/2021
31.00
18.23
793.51
Clear
None
100
2.80
3,500
21.2
82.1
5.3
0.2
190.0
5.2
CCPMW-4
10/14/2021
65.00
28.89
817.06
Clear
None
50
6A2
2,750
19.7
186.5
8.2
0.9
44.6
2.3
CCPMW-5
10/14/2021
72.50
43.54
815.09
Clear
None
80
5.19
2,050
29.9
167.8
8.1
1.0
49.3
4.1
CCPMW-6S
10/14/2021
43.50
38.78
815.57
Clear
None
80
1.31
15,200
19.4
56.7
5.0
7.0
149.4
6.8
CCPMW-6D
10/14/2021
60.00
38.72
815.66
Clear
None
120
3.96
3,000
23.3
50.9
5.3
0.1
175.7
7.2
CCPMW-7
10/14/2021
47.00
42A1
813.08
Clear
None
120
1.91
4,800
20.0
74.0
5.5
6A
135.8
6.0
CCPMW-8
10/14/2021
45.00
44.57
786.95
1 Clear
None
40
0.73
4,600
27.1
96.9
5.0
8.6
127.9
5.3
CCPMW-10
10/14/2021
42.00
32.70
780.28
Clear
None
120
6.98
2,400
21.4
44.0
5.1
1.7
201.6
5.0
CCPMW-11
10/14/2021
30.00
21.34
781.98
Clear
None
100
2.02
3,500
23.1
55.3
5.5
3.1
197.5
2.9
CCPTW-2
10/14/2021
45.00
45.00
796.72
Clear
None
60
NA
900
32.6
88.3
5.4
0.2
120.6
4.2
CCPSW-1
10/14/2021
NA
NA
NA
Clear
None
NA
NA
NA
17.7
253.0
7.3
5.8
68.3
7A
CCPSW-2
10/14/2021
NA
NA
NA
Clear
None
NA
NA
NA
18.6
59.8
6.3
6.0
118.0
5.5
CCPSW-3
10/14/2021
NA
NA
NA
Clear
None
NA
NA
NA
18.7
1 263.5
1 6.2
1 2.9
155.7
5.0
CCP-Leachate
10/14/2021
NA
NA
NA
Clear
None
NA
NA
NA
19.7
36,963
4.4
1 1.3
258.6
4.5
CCP-Leachate-34
10/14/2021
NA
NA
NA
Clear
None
NA
NA
NA
23.1
1,826
6.8
1 0.3
178.9
2.8
Prepared by: MAS 12/10/2021
Notes: Checked by: ZJD 12/13/2021
1. TOC indicates top of casinq
2. ft indicates feet
3. mL/min indicates milliliters per minute
4. qal indicates US gallons
5. EVAC indicates whether the water level in the well was drawn down to the level of the pump durinq purqinq and also the total amount purqed from well
6. °C indicates deqrees Celsius
7. µS indicates microsiemens
8. SU indicates standard units
9. NTU indicates nephelometric turbidity units
10. mV-NHE indicates millivolts -normal hydrogen electrode
11. bqs indicates below qround surface
12. Elevations based on NAVD88 vertical datum
13. NA indicates not applicable
14. Well information from well construction records, borinq logs, Duke Meta Data and previous reportinq
15. Field samplinq performed by Pace Analytical
16. *According to Pace Analytical Field Data sheets, monitoring well CCPMW-3S was not sampled during the October 2021 sampling event due to insufficient water volume for purging/sampling.

Table 4 - Groundwater Field Results and Analytical Detections
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Notes:
1. SWS ID is the Solid Waste Section Identification Number
2. SU indicates standard units
3. uS indicates microsiemen.
4. °C indicates dear... Celsius
5. u./L indicates micm.ram.... liter
6. MDL is the laboratory method detection limit the MDL values o..sented are for samples not diluted be the laboratory dunn. analysis
W ]. SW GPS is the Solid Waste Groundwater P—dion Standard
8. 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2013
9. IMAC is the Interim Maximum Allowable Concentrations. last u.dated June 30. 2021
10. MC L is the Federal Maximum Contaminant Level as found in 40 CFR. Subpart G. 4141.62
11. Federal orimare and secondary MCLs are provided for informational .u.00ses onv. The aoolicable—ter.ualit, standards are
the 15A NCAC 02L SUndard.
12.' Concentration listed is a secondary maximum contaminant level (SMCLI: SMCB are established by EPA in the National S.condary Drinkin. Water Re.ulation. as found in 40 CFR 4143.3
13. Concentrations in bold and himhlimhted indicate constituents that e.ual or exceed the res-dw, sandard
14. NE indicates not established
15. 11 indicates results are at concentations less than or equal m the Iaboratmv's MDL
16. J indicates estimated concentrations which are ...arer than the MDL but are less than the laboratorv', method reoortin. limit NRLI
1T NA indicates not analyzed or not applicable
18. Only compounds detected in one or more sample are shown
Prepared by: MAS 1 1292021
Checked bY. LD 1222021

Table 5 - Field and Analytical Results that Equal or Exceed Groundwater Quality Standards
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Date Data Received from Duke:
19-Nov-21
Sample Date(s):
14-Oct-21
Parameter
Sample ID
Result
Units
1SA NCAC
02L
Standard/
IMAC
Turbidity
(NTU)
Historical
Results
Significance
pH
CCPMW-1S
5.1
SU
6.5 - 8.5
1.0
4.39 - 5.58
pH is consistent with the range of historical readings at CCPMW-1S
CCPMW-1 D
5.4
0.4
4.8 - 9.71
pH is consistent with the range of historical readings at CCPMW-1 D
CCPMW-2S
5.2
8.2
5.04 - 6.37
pH is consistent with the range of historical readings at CCPMW-2S
CCPMW-3D
5.3
0.2
4.66 - 5.5
pH is consistent with the range of historical readings at CCPMW-3D
CCPMW-6S
5.0
7.0
4.71 - 5.86
pH is consistent with the range of historical readings at CCPMW-6S
CCPMW-6D
5.3
0.1
5.1 - 5.52
pH is consistent with the range of historical readings at CCPMW-6D
CCPMW-7
5.5
6.4
5.4 - 5.7
pH is consistent with the range of historical readings at CCPMW-7
CCPMW-8
5.0
8.6
5.1 - 5.2
pH is less than the limited historical readings at CCPMW-8
CCPMW-10
5.1
1.7
4.5 - 5.1
pH is at the upper bound of the limited range of historical readings at CCPMW-10
CCPMW-11
5.5
3.1
5.4 - 5.5
pH is at the upper bound of the limited range of historical readings at CCPMW-11
CCPTW-2
5.4
0.2
4.98 - 5.56
pH is consistent with the range of historical readings at CCPTW-2
Chromium CCPMW-5 12 pg/L 10 1.0 0.524 J - 21.8 Chromium is consistent with the range of historical concentrations at CCPMW-5
Cobalt
CCPMW-1S
1.55
pg/L
1
1.0
1.56 - 10.7
Cobalt is less than the range of historical concentrations at CCPMW-1S
CCPMW-6S
2.04
7.0
1.95 - 10.3
Cobalt is consistent with the range of historical concentrations at CCPMW-6S
CCPMW-8
1.69
8.6
1.86 - 5.86
Cobalt is less than the limited range of historical concentrations at CCPMW-8
Iron CCPMW-8 389 pg/L 300 8.6 27 - 628 Iron is consistent with the range of historical concentrations at CCPMW-8
Manganese CCPMW-7 73 pg/L 50 6.4 209 - 346 Manganese is less than the limitied range of historical concentrations at CCPMW-7
Vanadium
CCPMW-2S
0.67
pg/L
0.3
8.2
0.149 - 0.552
Vanadium is greater than the limited range of historical concentrations at CCPMW-2S
CCPMW-2D
4.06
0.5
4.56 - 9.3
Vanadium is less than the limited range of historical concentrations at CCPMW-2D
CCPMW-5
10.4
1.0
7.54 - 12.7
Vanadium is consistent with the limited range of historical concentrations at CCPMW-5
CCPMW-6S
0.368
7.0
0.448 - 0.488
Vanadium is less than the limited range of historical concentrations at CCPMW-6S
CCPMW-7
0.447
6.4
0.146 - 0.317
Vanadium is greater than the limited range of historical concentrations at CCPMW-7
CCPMW-8
0.763
8.6
<0.1 - 1.21
Vanadium is consistent with the limited range of historical concentrations at CCPMW-8
CCPMW-11
0.428
3.1
<0.1 - 0.146
Vanadium is greater than the limited range of historical concentrations at CCPMW-11
Notes: Prepared by: MAS 11/30/2021
1. SU indicates Standard Units; µg/L indicates micrograms per liter Checked by: ZJD 12/2/2021
2. 15A NCAC 2L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2013
3. IMAC is the Interim Maximum Allowable Concentrations, last updated June 30, 2021
4. NTU indicates Nephelometric Turbidity Units
5. Historical concentrations based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database and previous reporting
6. J indicates estimated concentrations which are qreater than the MDL but are less than the laboratory's method reportinq limit (MRL)

Table 6 - Surface Water Field Results and Analytical Detections
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Date Data Received from Duke:
19-Nov-21
Sample Date(s):
14-Oct-21
Parameter
Units
MDL
15A NCAC
02B
Standard
Federal
MCL
CCPSW-1
CCPSW-2
CCPSW-3
Field Blank
Field pH
SU
--
6.0-9.0
6.5 - 8.5*
7.3
6.3
6.2
NA
Specific Conductance
PS
--
NE
NE
253.0
59.8
263.5
NA
Temperature
°C
--
NE
NE
17.7
18.6
18.7
NA
Arsenic
pg/L
0.11
10
10
0.243 1
0.211 1
0.193 J
0.111 U
Barium
pg/L
2
1,000
2,000
21
22
19
2 U
Boron
pg/L
5
NE
NE
8 J
7 J
8 J
5 U
Chloride
pg/L
15
250,000
250,000*
4,000
4,100
5,400
201
Chromium
pg/L
0.185
NE
100
0.403 J
0.405 J
0.44 1
0.185 U
Chromium, dissolved
pg/L
0.185
14.38**
NE
0.373 1
0.38 1
0.415 1
0.228 1
Cobalt
pg/L
0.077
NE
NE
0.211 J
0.2 J
0.669 1
0.077 U
Copper
pg/L
1
NE
1,000*
1 U
1 U
1 U
1 U
Iron
pg/L
4
NE
300*
1,160
1,070
623
4 U
Lead
pg/L
0.037
NE
15
0.097 1
0.103 1
0.116 1
0.037 U
Manganese
pg/L
1
NE
50*
35
34
26
1 U
Mercury
pg/L
0.01
NE
2
0.01 1
0.01 U
0.01 U
0.01 U
Nickel
pg/L
0.256
25
NE
0.256 U
0.256 U
0.339 1
0.256 U
Nickel, dissolved
pg/L
0.256
9.56**
NE
0.256 U
0.256 U
0.322 J
0.256 U
Nitrate (as Nitrogen)
pg/L
2
10,000
10,000
440
430
20 J
10 1
Sulfate
pg/L
42.8
250,000
250,000*
990
1,500
1,700
42.8 U
Total Dissolved Solids
pg/L
25,000
502200
500,000*
45,000
48,000
48,000
NA
Thallium
pg/L
0.041
NE
2
0.057 1
0.044 1
0.064 J
0.041 U
Vanadium
p /L
0.114
NE
NE
0.325
0.4
0.372
0.114 U
Prepared by: MAS 11/30/2021
Notes: Checked by: Z1D 12/2/2021
1. SWS ID is the Solid Waste Section Identification Number
2. SU indicates standard units
3. uS indicates microsiemens
4. °C indicates deqrees Celsius
5. µq/L indicates micrograms per liter
6. MDL is the laboratory method detection limit; the MDL values presented are for samples not diluted by the
laboratory durinq analysis
7. Surface waters draininq to Broad River are classified as WS-IV, requlation 15A NCAC 02B provides water quality standards;
reference NC Surface Water Quality Standards Table, Updated: July 26, 2021
8. Concentrations in bold and hiqhliqhted indicate constituents that equal or exceed the respective standard
9. MCL is the Federal Maximum Contaminant Level as found in 40 CFR, Subpart G, §141.62
10. Federal primary and secondary MCLs are provided for informational purposes ony. The applicable water quality standards are
the 15A NCAC 02B Standards
11. * Concentration listed is a secondary maximum contaminant level (SMCL); SMCLs are established by EPA in the
National Secondary Drinkinq Water Requlations
12. NE indicates not established
13. U indicates results are at concentrations less than or equal to the laboratory's MDL
14.1 indicates estimated concentrations which are qreater than the MDL but are less than the laboratory's
method reportinq limit (MRL)
15. ** Standard is calculated usinq the average of the calculated total hardness for the surface water samples
from the October 2021 event (13.5 mg/p
16. NA indicates not analyzed or not applicable
17. Only compounds detected in one or more sample are shown

Table 7 - Leachate Field Results and Analytical Detections
Duke Energy Carolinas, LLC/Rogers Energy Complex
CCP Landfill, Phases I, II, III, and IV - Permit #8106
Date Data Received from Duke:
19-Nov-21
Sample Date(s):
14-Oct-21
Parameter
Units
MDL
CCP-Leachate
CCP-Leachate
34
Field pH
SU
--
4.4
6.8
Specific Conductance
µS
--
36,963
1,826
Temperature
°C
--
19.7
23.1
Antimony
ug/L
0.104
0.363 J
0.104 U
Arsenic
ug/L
0.111
9.33
0.164 J
Barium
ug/L
2
457
98
Beryllium
ug/L
0.249
0.456 J
0.249 U
Boron
ug/L
5
8,760
922
Cadmium
ug/L
0.032
1.96
0.393 J
Chloride
ug/L
15.4
15,000,000
48,000
Chromium
ug/L
0.185
1.43
0.252 J
Cobalt
ug/L
0.077
580
2.13
Iron
ug/L
4
1,450
42
Lead
ug/L
0.037
152
0.08 J
Manganese
ug/L
1
12,500
662
Nickel
ug/L
0.256
104
26.1
Nitrate as N
ug/L
2
4,000
2,600
Selenium
ug/L
0.193
92.6
3.18
Silver
ug/L
0.035
0.197 J
0.035 U
Sulfate
ug/L
42.8
980,000
960,000
Total Dissolved Solids
ug/L
25,000
37,700,000
1,670,000
Thallium
ug/L
0.041
9.24
0.184 J
Vanadium
ug/L
0.114
1.18
0.559
Zinc
u /L
4
147
5
Notes:
Prepared by: MAS 1211012021
Checked by: ZJD 12/13/2021
1. SWS ID is the Solid Waste Section Identification Number
2. SU indicates standard units
3. µS indicates microsiemens
4. °C indicates degrees Celsius
5. µg/L indicates micrograms per liter
6. MDL is the laboratory method detection limit; the MDL values presented are for samples
not diluted by the laboratory during analysis
7. U indicates results are at concentrations less than or equal to the laboratory's MDL
8. J indicates estimated concentrations which are greater than the MDL but are less than the
laboratory's method reporting limit (MRL)
9. Only compounds detected in one or more sample are shown

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Docunwnt Name: meld data Sheet
Pate Issued: March 8; 2019
Page:: 1 of Z—
�
-
I$5ui11 .h�lEtit�11I ._ Pack.' Huntersville Quality
Dtxuntent Plumber: F-CAWFLD-0Q]-rev.t73
Office
Field Data Sheet
CIient � eke E ✓� C r J, ti _ Location:�M 601e5 C Project #:
Name and Affiliation (SatrtpJer(s) M 1 �t Le- Field Data Sheet Review:
Name and Affiliation (Inspector): !y A
Date: Il o ~ 1 �{ � tl
We11 Information
Well ID:. Gc. Y M W - i s Well.Locke& (to/ 00 / Flushmount)
Well Diameter: '2 Coiistruction.. ('�V�'/SteeI/Stainless Steel;)
Total Well Depth.
.
Statie Water :t.evel: ft
Height of Water Column: 5,15 ft
Multi Factor*: 0, 1 C0 ["(Radius/12)2 x 3,14 x T 81
Casing `Volume: 0 • � galIons
Cal. 3 Volumes: 2, gallons
Pump :Intake: 4 D ft
LF cor,%e .4nre zaz
:By: (;.0 G.
Purge Information
Date PuaTged: I / l k :./ �- _Start : (7 D O Firdsiv. i o '3 5 PurgeRafe: 6 Ll�,ih
PurgingMethod:_�v.__ Total Volume Purged:....... oU (gaIlons./ l a/L)
5arnotina Information
Date Collected, 0 / 1 �/ ZJ Time Collected.,:_ i � �i 0-_
p
Sampling Equipment Used: lG nstrument ID: S I 1 `1 LO-1 / T1j S S L( I
Bottle Type Preservation Analysis Required
._-1-4 10EiKIzI
Y Lei+
Field Measurements/Observations
Sample Temp CC): ZI- ( Tinier 1 0 q_U_Turbidity{ntu): +i � D Time:
Diss Oxy (mg/ L)- (0--1Time: 1 0 H 0 Fe 2+ mg/ L: !JA Time. 0
Specific Cond. (uS): 2i.e ,V Time. �- ) \.I V_Res. Cl (mg//L (gg/I:) Inxte:
Sample pH. (s.u.)- 5-_1.--- .._Time- Odor:_ _.-- _,._._._._. Time:..._._1 � �._0_
ReDox (mV): 7 Time; D Appearance: C t e "-Time. ` ime. Q
ReDox (EH value):YSI ProPlus +200n V_ 197, 1 Other: — Time:
General/Weather Observations:
Sampler Signature
Stabilization Test
cloudy/rainy) Temp... —I 1 (°F) Wind 3 (mph)
e: (c) 2t
Time
Temp.
DissOxy,
spec.
Cond.
pH (s.u.)
Ciepox
Turbidity
Volume
remov-4
Water
Other
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°C
nt I.)
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Document Name:
Field Data Sheet
POCUnTent lssuedMarch $; 2019
Page 2of _Z
Document Nuniber:
Tssueing AutltO64t :
F-CARFi.l7-001 revAl
Pace Huntersville Quality Office
Client; . Nit t t E r g-.l q
Location; ......... M a0 re -S G 0"0.:. N C.
Project; CL S C_ CP LE ror,,e o� k Le Zy 2-1
Well I➢: G C C Mw — 15
Reviewed Date and By: l °' 14' I C-LG.
Stabilisation Test to 141131 W- -
INTall Diameter
'Xfultiplication Factor'
1
0.0403
1.525
0.1080
0.1630
3
0.367O
4
0,6530
6
1.4600
S
2.6100
Time
Purged
Temp.
(°C)
hiss (]xy.
{;mg/L)
Spec.
Cond,
(US)
pH (s.u.)
Re➢ox {mill}
Turbidity
(ntu)
Volume Removed
(gallons/ I L)
circle.one
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(Fr)
other
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Document Name: Field deta Sheet
Date Issued: March 8; 2t119
11!2eAn70ical
Page:. 1 of
Document Number: F-CAR-FLD-001-rev.Q3
Issuing Authority: face. HuMersville Quality
Office
Field Data Sheet
r� +\
CIient: _,? 5� Locatiort: M V e r SIC6 0 r s. Project #. � + 3'� � � �' � t, W►�L�.
Narrie and Affiliation (Sa:mpler(s) G �/M'Eg " pa Field Data Sheet Review: 2A
Name and Affiliation (Inspector).: Date: i a - t � _ L l By: M �L
Well Information . 10��(
Well ID: ° ` P V `w - I D Well Locked: Y / NO / Flushmount ).
Well Diameter:
2."
Total Weil Depth: 5 G q 5 ft
Static Water Level: 38' 1 a ft
Heigh of Water Colum.nj g' �3 ft
Construction: 6(P /Steei/Stainless Steel)
Multi Factor*: ������ ( (Radius/12)2 x3,Rx 7A8j
Casing Volume: 3 D gallons
Cal_ 3 Volumes: 2-I gallons
Pump Intake: S 5 ft
Pg a Information
Date Purged: ! O / _./ 2-1 Start: 1000 Finish: v Purge Rate:
Purging Method:_. (A0(44 l Total Volume -Purged- ayo u (ga.11ans/ nls L)
Sampling Information
Date Collected: I Q / Imo. �1 Time Collected: pm)
Sampling Equipment Used: �l �` `��l Instrument ID: f �/n -Trw-o 035:-'5r
Bottle Type
Preservation
Analysis Required
Field Measurements/Observations L
Sample Temp: (°C): ,_ Time: I v 2-5 Turbidity (ntu): G 7 _ _ Time: l v�
Diss Cxy (mg/L): lD • b Tune: ! �5 Fe 2+ mg/L:� Time: �"ZS
Specific Cond. (uS): '4�- 9 Time: z 5 Res, Cl (ing/L)/(µg/L): ~ -rinse: —�
Sample PH.. (sm.): Time: �S I- _
• � -._.___._..._. % Odar:_.....��'�
ReDox (mV): I �• Time., i U 2-5 Appearance: r°k Tzme:
ReDox (EH value):YSI Pr.oPiu.s +200rnV 3 / • other: Time:.
General/Weather Observations:
(su )cloudy/zanly) Temp. (°F) Wind o (mph)
Sampler Signature: _Date: / v / Y Z I _
Stabilization Test
Spec.
Volume
Time
Temp.
Diss Gxy.
Cond.
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
Pu.r ed
g
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I �6'AI�s7%�1lCai
I:)rxu meni Name: �ieid data Sheet.
[Hate Issued: March 8, 2019
[7cxument Number: F-CAR-Fi,.l7-0Q1-rev,Q3
Issuing Authority: Pace Huntersville Quality
Office
Field Data. Sheet
Client: Da
Name and Affiliation (Sampler(s):. 14 83LM PaQ C
Name and Affiliation (inspector): f1(_% A, ,
Well Information
Well ID: 4C P Mw-2-S
Well Diameter: -A i n
Total Well Depth.: 1`I.3 0 ft
Static Water Level: 3 4.2 5 ft
Height of Water Column: 5•0 ft
Well Locked: (( YES
#; GLS_CGP LF tGA?J;a,,e 0tt,2�1j
M Data Sheet Review:
Date: �„ •z.t�2t By:
/
Construction: (PVC/ teel/Stainjess Steel.)
Multi Factor*: Q lb [•(Radius/ 2)2 x 3: 14. x 7.481
Casing Volume-. O. 9 z gallons.
Cal. 3 Volumes:. Z . L( 7 gallons
Pump 2 ft
Pg a Information
Date Purged:- i `� ./ S 4 / ZI Start:—J0,4_5 Finish 1(O 5 Purge Rate: lflo Al5/,*,./I
Purging Method:_8 tad dbr PN M i, Total Volume Purged: Z000 (gallons nls/
Sa mvling .1 of o r ni a t io n
Date Collected: t Q Time Collected; am in)
Sampling Equipment Used: +Q (o.d dee- PLt .n P instrument iD: Y 4 L �6'I
A 13 P114/2 1-
Bottle 'Type Preservation Analysis Required
____.Dus<e LQr►P1 sn Ll�_....q............ ...
Field MeasurementglObservations
Sample Temp (°C): 10 1—Time:_1 tl°.....,...__Turbidity (ntu): g Time: I I1
aiss Oxy (mg/L): b • 3 7'lne: Fe 2+ mg/L; Time: �.
Specific: Con& (uS): 5 Time:. Res. Ct (mg/ L)/(gg/ L):- Time.
Sample p:El (s.�t,): 5 2.....__..., I.itne: Odor:—S 4n� _.._.._.____.. _Time:. k1 f o
R&DOX (mV): y ot,;-`z Tuzie: Appearance: 'Time: � —
ReDox (PH value):YSI..ProPlus +200mV 313. Z Other: Time: —�
General%WeatherObservations.'TOok lr r e � 9LxtI;Cs,e P1
Sampler Signature: Rye -1 {aY a.S _. Da
Stabilization Test
y/rainy) Temp.:7Z ff) Wind �3' 5 (mph)
/v/ iy /z
Spec..
Volume
Tune
Temp.
o
Diss Oxy.
Cond.
pH ('s.u.)
ReDox
Turbidity
removed
Water
Other
Purged.
(C)
(mg/L).
(us)(mV)
(ntu.)
(gallons/mis
level (ft)
L
+�5 e)
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b.9
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Document Name., hlclddat<ti-Sheet
I�Tte Issue& March B; 2019.
Page:: I Of
Ct'%ll)r3lflQr3�
Dmummt Number: F-CAWFl,WO.I-rav,a3
Issuing Authority face Huntersville Quality
Office
Name and Affiliation (Sam
Blame and Affiliation (Insp
Well Information
Well ID: CGERA - )�
Well Diameter: a I m
I_DD(f 5 Wfb Nii 1'irtijeet#:��
f i%lL� Field Data Sheet Review:
1.1) Iq I z 1
Date:
Well Lockett:
Construction:. 'PVC Steel/Stainless Steel)
Total Well Depth:� . ft Multi :Factor': U, (] [(Ra0iu5/12)2 x 3:1.4 x.7ABI
Static Water Level: qQ- 7 ft Casing Volume: -J, L`l gallons
Height of Water Column:3r 3 ft Cal, 3 Volumes: gallons
Pump Intake: 70,50 5l I ft
rrp [-anA'[ i `1 (�OMV( q1
R,� R
By, (�.C,v
Pur a Information y
Date Purged: .-N._ __/—L /� Start : .� � � Finish 315 P rge Rate: aD � 1' m
Purging Metho.el': AAp.r` RkQ Total Volume Purged: 37600 (gallons: znls L)
Sampling Information � I 1�
Date Collected. __/L/ r11 Thee Collected: 13aG (am m
Sam: ling.Eq.uipment Used: OLAAU PLOAP ID: �
Battle Type Preservation Analysis Required
Field MeasurementgDbservations t Sample Temp (°C): �5__,Time I. _Turbidity (ntu),. 0.6
J Time- 3aQ
Diss Oxy (mg/I..): 3, Tithe: I� Fe 2+ mg/L., ND Time:
Specific Cond. (uS): -�,q Time: ICJ oC0 Res. Cl. (mg/L) (pg/L): — Tune:.
Sample p:f-1 (s,u,): S r ._ Time, � 3 �0 Odor:
D
FeDox (mV); 1 V . d --- .WYu 4 Tithe: Appearance: C eM- Time: '), V
ReDox (R I value) :YSl..ProPlus.+20.0mV 3 , 0 _Other: Time:
General/Weather Observations:
soon cloudy/rainy) Temp. 2-.(°F) Wind -r.2- (mph)
Sampler Signature: �It _
Stabilization Test [,1
SI?ec.
Volume
Time
Purged
Temp.
o
(C)
Diss Oxy.
(ulg/L)
Cond.
pH (s.u.)
ReDox
(tnV)
Turbidity
(nku)
removed
(gattl.ons/ 1s
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level (ft)
Other
(US)
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Document Name.
Oocunient Issued: March £, 20'n
w a ekwlyfical
Field Data Sheet
f'age�af a
Document Number:
Issueing Authority:
t
F-CAR-FLD-olll.rev.M
Dace Hunteirsville Quality Office
Client: OtAke., ne
Location: !V core5boro s 1V C
Project: CILs_ CCIP LA14 iN romp kin =1
Well ID.- CL
Reviewed Date and By: �""H 1lt RIO
Stabilization Test 10 zI -Zr GcCY taiakl&b Nlo'
CN'eU Diameter
,iultiplscaiiort Factor"
1
6.0403 .
1.2
DAMS
1.625
0.1.060
2
0.1630
3.
. 0.3670
4
0.6530
b
1.4650
5
2.6100
Ni
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Docunitnt Name: Field data Sheet
Date Issued March 8 2019.
Pap: 1 of 7-
Document Number: F-CAWFLD-00.1-rev;03
Issuing Authority: PaceHuntersville (duality
Office
Field Data Sheet
Client: DW4c - » r Location: be
Narne and Akf 11iatio.n (Sampler(s): GM f6�d2
Narne and Affiliation (Inspector): N i A
Well Information
Well ID: U P A 91 - Co Well Locked:
Well Diameter: Z { r\ Construction:.
#: 4&-S 41 r Lf= lvewfF;crrLIe- 04t2O"I
Field Data Sheet Review:
Date
(0/m/al AGM
A�� .z(-�1 By: G4 61.
ES NO / Flushmount )
teel/Stairrless Steel)
Total Well Depth: �q-LA I _ft Multi 'Factor*: 0, 3 63 ("(Radius/12)2x'3A x 7,48]
Static Water Level: i ft Casing Volume: Z $ gallons
Height o.f Water Column: ft Cal. 3 Vol um es: gallons
Purap Intake: ^' 33 it
Purge Information
Date Purged: 10/I � /-'L_� Start: 11.1.3.5 FinisIt 1010 Purge Rate: loo,AO/I+F 1�
Purging.Method: B 1 o-d der- P �k M P Total Volume Purged: S o0 (gallon i�),)
Sampling Information.
Date Collected: i -o / t 1 / Time Collected: i 015
Sampling.Equipment Users: Q !a cf der Pa,- r Instrument ID:. _Y`j L 1061 ....+/ i P ✓ blLX
Bottle Type Preservation Analysis Required
lJul( (o 4anfe:.__.Ko�,<
Field Measurements/Observati.ons
Sample Temp ()C.): ' rime: ,•,,L .,I.S.w___Tuxb1dtty (ntu): 0 _ � Time: ! 4 f S
Diss Oxy (mg/L): ZS Time: Fe 2+ mg%L:N 1) 'I ime: l
Specific Cond. (uS): S 2 ` Tirne: Res. Cl. (mg/L)/(f%/L): "fine:.
Sample pH.
ReDax (mV): 190.0 Timer Appearance: 1 je,*.r 'rime,
ReDax (EH value):YSI ProPlus +200m.V 3 9 4:. a Other: Time:
General/Weather Observations
/rainy) Temp. 7 Z (OF) Wind D- S (mph)
Sampler Signature: Py o.n ey &4 _ Date: 1 / l rf // i........_......_......_�------
Stabilization Test
Spec.
Volume
Time
Temp.
o
Diss Oxy.
Cond.
pH (s.u.)
ReGox
Turbidity
remove
Water
Otlrer
Purged
(C)
(»gig/l_,)
(us)
(MV)
(ntu.)
(gallons/ tls/
level: (ft)
L
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Document Name:
Dmament issued; March 8, 2619
Field Wta Sheet
�
Paget of I
. ..� ..
Dkument Number:
{ssue(ng Authority-,
F-CA. R-FLD-00I.rev.U1
Pace Hunteesv.ille Quality Office
Client: i�utKe. ee ry., __
Location: r' °0 (d4 _bo_ no NC
Projects6Cf LI` oil
Well E0- L CP AAW - 3 ()
Reviewed hate and By:. I o/ b
Stabilization Test I u � zl I, 'z-( G� G
4Nrei.1 Diameter
Xfultxpb.eation Factor'
1
0,0408
1.2
.0.0918
1.623
0.10s0
2
0.16,30
0.3670
4
0.6330
6
1.4630
S
16100
Time
Purged
Temp.
n
(C)
Diss Oxy:
(mgf L)
Spec.
Cond.
(u5)
pH (s.u:)
ReDox (m.V)
Turbidity
(ntu)
Volume Re pu�ye
(gallonsIs )
circle.one
Water level
(ft)
Other
1047q
2o.aj
"7.Z-7
Z;OCD,
S7at,(
1
21.0
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t+4Di
Document Name: Field data Sheet
Date issued: March 8; 2(n9:
Page:: I of�
c�Analylical
Docununt. Number: F-CAR-FLD-001-rev.03
issuing Authority: Pace Huntersville Quality
Office
Field Data Sheet
NaMe and Affiliation (Sampler(s). NV-4 _" rCLC.0
Name. and Affiliation (Inspector):
Well Information
Well ID: �P MW"L_
Well Diameter:
Total Well Depth: ft
Static Water level; ft
Height of Water Column: Ift
Well Locked:
LL5 - (cP W (ompV-Ai
Project #: ! k C f r P4 1U(�
.Field Data Sheet Review:
Date:. I By: G' C c
E0 .��t - j :TC M
'Eq/ NO / Flushmount )
Construction ( >teel/Stainless Steel)
Multi Factor*; Q-1W3 [•(Radius/ I2)2 x s.t4 x 7A8]
Casing Volume: CD.L0- gallons
Cal. 3 Volumes: �<A. � 7 gzllor+s
Pump Intake: U(Q- ( '('- ft
Purse Information �'��, "
Date Purged- Q / e- � / ' A Start : � ~ Fi.nish:�� Purge Rate: �t'`t hfj
Purging Method:_, & r ijl-1 Total Volume Purged: ?1_752 (gallons/5/1')
Sampling Information
Date Collected: / �-4 / At Time Collected LW _ _- an /pin)
Sampling Equipment Used: r 5 y RA&f Instrument ID: ,i` CA b1 _
Bottle Type
Field Measurements/Observations
Preservation
Analysis Required
C0MVa (Q FCC a -
Sample Temp (°C):Time: Turbidity (ntu): .t'4 Time: `AD
Diss Oxy (mg/L): P �j Time: _�L� Fe 2+ mg/L: Time. its- Q
Specific Cond. (uS): � Time: MG Res. Cl (i71g/L)/(ug/L): Time:
Sample pH. (s.u,): - Time: Odor:
ReDox (mV): LI y A0 Time: �16-V) Appearance- CW> Y" Time: �4)_L3Q
ReDox (EH value):YSI ProPlus +200mV : �i-1, t7 Other: - Time: -
General/Weather
cloudy/rainy) Temp. !� (7) Wind 1-S (mph)
Sampler Signature
Stabilization Test
Spec.
Volume
Time
Temp.
Diss Ory.
Cond.
pH (s,u.)
ReDox
Turbidity
reproved
Water
Other
Purged
(°C)
(mg/I)
(uS)
(MV)
(ntu.)
(gallons/ /
level (ft)
5_ J
L
J cL,5
S;
VZ 29
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Docunient.Name:
Ocwwnent Issued: Mardi 8, 2019
A
Field Data Sheet
Page3f'
c7CL'/�T%jl c?f
Document Number:
[ssueing Authorityc
F-CAR-FLD-001.rev.03
Pace Huntersville Quality Office
Client' lw(o VgtA
Location: 11U1(1Z tOf3(D _I uc -
Project:
Well ID-, (KAUJ- A
Reviewed Date and By: /u - 2(, -41 �� G
Stabilization Test j(�.-al •-�( :SGM
i-VeR Diameter
'xfultiplication Factor*
,•1
o.0.�a
1.2
0.0918
1.625
0.1080
2
0,1636
0.3670
0.6530
6
1.4680
8
2.61G0
Time
Purged
Temp.
n
(C).
Disc Oxy.
(tng/L)
Spec.
Cond.
(us)
pH (s.u.)
ReDax (mVj
Turbidity
(:ntuj
Volume Removed
(gallons/ is L)
circle one
Water level
(ft)
Other
LZU, i
to
tci�
C;fL�
rz0:-1
6
Lillw
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�cBAr7F?lylrc�71 �
L7oeuntent Name: Field data Sheet
Date tssue& March B 2019.
T'a e:- 1 of l
Document Number: F-CAR-FLD-001-rev.03
Issubig Authority: Pace Huntersvilfe Quality
Office
Clien
Name and Affiliation (Sampler(s):_
Name and Affiliation (Inspector).:_
Well Information
Well ID: NW
Well Diameter: A Ik
Total Well Depth: �5; L ft
Static Water Level:_.. r�`' _ft
Height of Water Column: ;i,4gft
Field Data Sheet
VCZCV Pield Data Sheet Review:
Date: C C C'
f I ryryC � .. /4y
Well Locked: 6Y1,j / NO / Flushmount ).
Construction: O/Steet/Stainless
Steel)
Multi Factor- Q 1u3 r(RAdius/12)2 x 3:14 x 7.481
Casing Vtilu:me: 25,19 gallons
Cal. 3 Volumes: A5.5z- gallons
Pump Intake: 7�. CC — ft
Purge Information
Date Purged. 10 /_L /4— Start: \�Cb Finish, 'urge Rate:
Purging Method;,.— __- f2d . k l! --Total Volume Purged: (gal Ions./ /I )
Satnplutg Information
Date Collected:_ LOLA / Time Collected:__&�_..._ (am,(2!0
Sampling Equipment Used: cxx.1\Instrument ID:_
Bottle Type Preservation
Analysis Required
.—_�(j -... _.... ...........
Field MeasurementsZObservations
Sample Temp (°C): 461
Time; k—ba�� ___Turbidi.
ntu V ty (. ): I . , ...-_
Time:
Diss Oxy (mg/L): 9 •
Time. ��' �
Fe 2+ mgf L; _ Time: 1?lj 5
Specific Cond. (uS): �WIS
Time: �-
Res. Cl. (n-tg/L)/(wtg/L):�
rime:'
Sample pFl. (s.u.): '--...._..--.
Time: - 1�d5
Odor: .....— _ 1.--._.-. _
Tlrne:�?....—
ReDox (mV):._
Time: 1)45
Appearance:
'Time:
ReDox (EH vaILLe):YS.f ProPlus +20()n1.V 4-Lkq - 5 L
Other: __.
true:
General/Weather
Sampler Signature
Stabilization Test
/rainy) Temp.__!-,]_.('F) Windj-f; (mph)
Date:
Volume
Time
Purged
Temp.
Diss Oxy.
CondSpec.ReDox
pH (s.u.)
Turbidity
removed
Water
Other
g
C
(° )
�n L
( g/)
(US).
n1V
( )
ntu.
( )
(gallons/ t
(g /
level Et
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Document Name: Field data Sheet
Date Issued, March 8; M19
CBfIITc7dyifCttl ,
Page: I of _Z
iJi�cuntent Nuniber: F-CAR-FI..T1-0(}1-rev.03
Issuing Authority: Pace Huntersville Quality
CiEfiEe
Field Data Sheet
U ie c-
Name and Affiliation (Sainpler(s): MG--4 GLG r e
Name and Affiliation (Inspector): N A -
Well Information
Well ID: [ e P 1,, to �
Well Diameter:
Z"
Total Well Depth: 1� (P • 1 I ft
Static Water Level: S
Height of Water Column: B • () i ft
Well Locked:
Project #: LL.5
Data Sheet Review:
Date: / L7 ` 14' ZI
/ NO / Flushmount
Construction: (7/Stee(/Stainless Steel.)
Multi Factor' 0' 3[*(Radius/12)2x11.4x7,481
Casing volume: 31 gallons
Cal.3 Volumes; 3- `] 3 gallons
I'izmp Intake: � �
,, r L F cc ,,.�l G n[ ( Z b —1
By: GLG
Purge Information 11-L
Date Purged: Z 1 Start: I I Fialish: ( 3 -Z S Purge Rate: 80 /'+"Ln
.Purging Method:_ b 1 a d A-e- eu ,,,,,10 Total Volume .Purges[: � s �' U O (gallons 1 / L)
Sampling information
Date Collected:_ 1_0 ,/ 1 E / 2i I Time Collected 1 3 3._0 {ant/O)
Sampling Equipment Used: 81 4 ri � Pvm P Lnstrument ID:_ yS } 1 `7 Cog IT PW SSA 1
Bottle Type Preservation Analysis Required
_ ink Su['"iLt
Field Measurements/Observations
Sample Temp (°C): l " Time:
►. 3 3 c7
Turbidity (ntu): 7. O Time:
13 3 o
LDiss Oxy (mg/L): (o4S Time:
1 3 3 0
Fe 2+ mg/ L.: (`I Time:
1 3 30
Specific Cond. (uS): 5 (v,�l Time:
13 3 U
Res. C1 (nag/ L)/{itg/ G): 'Tune:
S"1 D
Sample pH (mt.): ,Time:
1330
Odor:_ _._.._._. No Time; ......
1 3_3_�
ReDox (mV): I c l` �{ Time:
j 3 3 U
Appearance: --­............C. (.-e 4 l 'rime:
1 330
.ReDox (EH value):YSI ProPlus +200m.V V1 `1
Other.: Time-
General/Weather Observations:
Sampler Signature
Stabilization Test
y/Yatxy) Temp._3__D_..(°F) Wind 3 (mph)
'-14-ZA
Time
Temp.
Dias Oxy.
Spec.
Cond.
pH (s,tr.)
ReDox
Turbidity
Volume
remove
Water
Other
Purged
a
(C)
(mg/ L)
(�
(znV)
(ntu)
(gallons/ V /
level (ft).
L
i Zco
23.o
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5,3
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--
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23.5
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Document Mum:
Do unient Issued: March 8, 2019.
r'�C kmlyfica _
Field Data Sheet
['age�f _
.'
m
Document Number:
lssueing Authority:
F-CAR Fi.D-001.rev.03
Pace Hunteusville Quality Office
Client: 1- C--- �S,
Location; . _ °y_re5 rul N C
Project:. CLS CC,P LE 2-OZI
Well Io: . LG rMui LOS
Reviewed Date and By:. 1 0— f 4 ` Z 1 CL61
Stabilization Test to `Aw W24
Well Diameter
Multiplication Factoe
1
0.0�8
L2
0:0913
1.623
0.1080
2
0.1630
3
0.3670
4
0.6330
6
1.4680
8
2.b100
Time
Purged
Temp.
(°C)
Diss Oxy.
t:mg/Lj
Spec.
Cond.
(us)
pH(s.u:)
ReDox imV
Turbidity
intu)
Volume Rpved
(gallons L)
circle one
Water level
t 1
Other
1'L25
Z3,8
510
51-0
i ,z
IIUA
z3"ll
Z400
3s%C6g
--
I Z30
21,5
5-2
5-1, 1
5, Z
28.y
ZSd o
-38, fig
--
1 '2. 3
ell
fir. 2
5'� ,�
5� 1
1 2 3• y
'Z -7
3 Z
-39.
r �+ e: Z k
1 Z'L D
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1. C)
5 u.3
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3 z. LQ
140,)
3 4 a g 3
—
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1,3
55.o
5.
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CDg.S
51.0Do
1 250
4<11
1.3
SSA
5• I
13214
'Zoo's
&Soi)
31.ao
1255
JVI
-7•1
5V.2
T-0
1 35, Z
t bl�o
2000
3 1,vZ
1300
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Dmament Name! field data Sheet
Date Issue& Mirth 8, 2(n9
e
rage: 1 of
Document Nvmbe: F-CAR-FLD=001-rev,(n
lssuiiig Authority: Pace Htuotersville Quality
Office
,�eAoatylical
r`
V 4-c
Name and Affiliation (Sam
Field Data Shee€
ation: ►VU 0 r 9
Me?, M & Ck
.Name and Affiliation (Inspector).::y`- 0 -
Well Information
Well ID: Cc l'`1 (o !�
Well Diameter:
Total Well Depth. D ft
Static Water Level: 3 O -r7 Z ft
Height of Water Column:A [ • Z$ ft
Well Locked:
n1C Project
ield Data Sheet Review:
[ o-14-Zr r,_, En
Date: to ICI x1 By: M P-4-
V NO / )~lushmount )
Construction: a/Steel/Stainless Steel)
Multi Factor*: 0, /1�3 '(Radius/12)2 x 3,14 x 7,481
Casing Volume: • to gallons
Cal, 3 VolumCS: 1 a gallons
Pump Intake: �O O • 5 ft
Purge Information f
Date Purged: / D / I / z. f Start. t' 1 Finish: Z�� purge Rate: / -Z "
Purging Method:_ �� Ot�wl Total Volume Purged: 3 o dy (gallons/ iC . L)
Sampling Information
Date Collected: I o I ZI Time Collected.-,---- (an16)
Sarapl:ing Equipment Users:Instrument ID: V 6-± A'D 2-P3 -7-10L-4036�5
Bottle Type
Field. Measurements/Observations
Preservation
Analysis Required
Sample Temp (°C):. J-3 . '3 Time: J Z ZS
Turbidity (ntu): •
Time:
Z],S
Diss Oxy (mg/L): 7. 2- Time.
lie 2+ mg/L: Af 3)
Specific Cond. (uS): '� ' Time: / 2 2 S
1Zes. CI (nig/L)/(µg/L):
Thne:
Sample pH (s,tr ): � 3....._.._._..__ Tirne:. I
Odor: _K-Icr
ReDox (mV): 115.7 Tfine: I zZS
/_...._.__..__
Appearance, Cj-ek(.
.Time:
ReDox (EH value):YSI ProPlus +200m.V 375
Other:
Time:
Ceneral/Weathe r Observa
s-u /cloudy/rainy) Temp,: -Z(,('F) Wind 2- (mph)
Sampler Signature: ,_,.Date:
Stabilization Test Q-
Spec'
Vo ut e
Time
Temp.
Diss Oxy.
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
?urged
(°C)
(mg/L)
� 5)
(mv)
(ntu)
(gallnn
level (ft)
L
----- -
1.7
5. 4
1( -SN
o, 1
(P
I
77
5r,7
5.q
Ilfl5•N
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5.3
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Document Name: Field data Sheet
Date Issued: March 8, 2014
CeliEaTy
1 of �
Document [Number: F-CAR-FLD-001-rev.03
-page..
Issuing Authority: Pace Huntersville Quality.
t
.
.
Office .
Meta uata Sheet
Clienf: PlrKe eta Location: lyWr¢5bc.►-�� IVG Project #: CLS CCP j."%4k11 CCWLPI Aar
Name and Affiliation (Sampler(s):_ Cam 6 [ Pact Field Data Sheet Review:
Name and Affiliation (Inspector): N t h Date: l o t i. B G`� f
Well Information ' ° ' Y
Well ID: CC PMW -'I
Well Diameter: 2."
Total Well Depth: 51.67 ft
Static Water Level: gL4A ' ft
Height of Water Column: SJOG ft
Well Locked: (QF / NO / Flushmount )
Construction; (/Steel/Stainless Steel)
Multi Factor*: 0.1(63 r(Radius/12)2 x 3.14 x -481.
Casing Volume: t. k 1 gallons
Cal. 3 Volumes: -4. 73 gallons
Pump Intake: YS.57 ft
Purge Information
Date Purged: 10 / 14 /?D24 Start: Oa35. Finish: ffia Purge Rate: _f NIL69rl
Purging Method; gloxkAsw- -Total Volume Purged: 4000 (gallons/ /L)
Sampling Information
Date Coliected: iG - /L/_2014 Time Collected: 102,0 (Rypm)
Sampling Equipment Used: �le.aclar Instruriient ID: YSJ-4l7t-S'TPW -US538
Bottle Type Preservation Analysis Required
Field MeasurementsjObservations
Sample Temp (oq, . 7n•o
Time: 10ZZG
Turbidity(ntu): (o-+i
Time: I lam
Diss Oxy (mg/L): (o.d
Time: IOZo
Fe 2+ mg/L: Nth
__Time:r GV
Specific Cond. (uS): 74.�0
Time: lam T&
Res. Cl (mg/L)/(µg/L): �Time:.
Sample pH (s.u.): S.S
Time: *o-716P
Odor: ND
Time: 1620
ReDox (mV): 13S-8
Time: 10LO
Appearance: f1e.r
Time: IbZo
ReDox (EH value):YSI ProPlus +24omV 335. 6
Other:
Time:
General/Weather Observations:_ .
__j:f(_sunn)/cloudy/rainy) Temp. 77 (°F) Wind 0-3 (mph)
Sampler Signature,
Stabilization Test
Spec.
Volume
Time
Purged
Temp.
Diss Oxy.
(mg/L)
PH (s.u.)
ReDox
Turbidity
removed
Water
level
Other
(°C)
bus)
(mV)
(ntu)
(gaRorts�/
(ft)
o9qa.
14.o
4.6
01.7
5.7
70•e
163.o
60
LIZ.gi
Dur
19.0
4.1
S1.7
15.7
71. a
11c4.0
17�
0g4K
jr z
5.0
80.3
S .7
70.5
10S . b
12Do
qq
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oggo
la. Z
5.3
'1g, a
5.t,.
bb.2.
(01. Z
ISOO
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111.1
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76.2
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510.7 1
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Docu ,limt Name;
Doclunont Issued- March H, 2019
(`tCeAnkilyf cal
s
f
Field Data Sheet
Page 2c)f -7,
Dockun nt Number
F-CAI-FLD-001..rev.03
Issueing Authority:
race Huntersville Quality Office
Client; _Duke C
Location: Moombaoro., me
Project; CLS C[.P U-UW11) &�
Well ID: CCPMW -77
Reviewed Date and By: / V "Zr , 2 I
Stabilization Test q,a 1d-va% hVW
ilzell Dianleter
Multiphcahoxx Factor"
1
0.0408
1.2
0.0.918
1.6.25
0.1080
2
0.1630
3
0.36f'0
4
0,6530
6
1.4650
$
2_6100
Time
Purged
Temp.
(°Cj
Diss Oxy.
imgllj
Spec,
Cond.
(US)
pH (s,u:)
ReDox (mV)
Turbidity
(nku}
Volume Removed
(gallonsA&L)
circle one
Water level
�j
Other
1000
14.4
io .0
75.6
5, b
168.7
L7. It
3000
1005
19.10
5.16
75.Z
5.S
119.3
13.4
3600
42.119
1010
1-1.`1
sr. g
14.9
5.5
1Y.4.0
7.`d
'izao
�12.yz1
--
1015
20. o
io. 0
74.1
s.s

Document Name: Field dat�t Sheet
Date Issued: Larch R 2©1.9
Pape;, 2 of �
r r3CL'�4Y7r71} fCBf
L]ucun�ent Number: F-EAR-FL.C1-adl-rev.0.3
Issuij Authority: Pace Hiuitersville Quality
r
Office
Name and A:ffillation
#:4x 00 / r--
Id Data Sheet Review:
Name and Affiliation (Inspector).: /1/_ /i ._._.-� iv- 'Z (I -� (
Date:
Well .Information w 0 41
Well lA Well Locked: NO / Flushrrtount ).
Well Diameter: Construction: (Steel%Stainless Steel)
Total Well Depth: H' `1Z)S Ft
Statzc Water Level: "t q ` 5- ' ft
Height of Water Column:V�/z_ft
Purge Information
Date Purged. 0 Z1
Multi Factor*:a - /d�7 [*(Radius/12)2 x 3:1-1 x 7,48]
Casing Volume: Q, -7,2.3 gallons
Cal. 3 Volumes: Z j 9 gallons
Pump Intake. ft
By -
Start, 1�)Q Finish: l i 3 i) Purge Rate:.���
Purguzg Method: o o Total Volume Purged: 6U� (gallons/&L)
Sampling Informati-an
Date Collected: 0 / ! `� / Z1 Time Collected: n /pm)
Sampling Equipment Used: r Instrument ID:e�f�
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (°C): _ 3--l1 ( Time:—i[ 3 5_—Turbidi.ty (ntu): R &. — Time:
Diss Oxy (mg/T )-. S� 3 Time. Fe 2+ mg/L: N & T me:
Specific Cond. (uS). 0 �� _ Time: Res. Cl (ing/L)/(Gtg/L): Time:
Sample pH. (s,u.); q�41'9 --- Time:----
lieDox (mV): ii�} F _ Time: Appearance: Cie 'Time;
ReDox (EH value):YSI ProPlus +200rttV 3 1-71` Other: /! ' Time:
General/Weather Observations:
Sampler Signature
Stabilization Test
/cloudy/rain) Tent ,[°F) Wind-�57(mph)
te:
S
V Q tmae
Time
Temp.
Diss Qxy.
Cond.pec.
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
Purged
o
( C)
Ong/L).
(US)
(znV)
(ntu)
(gal.l.ons/ zls
level (ft)
L
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Domnent Name.
Field Data.Sheet
Cx-,wnent Issued: March 8, 2019
Page Zo# Z
Document Number:
Issueing Authority:
I
F-CAR-Fl.D-001.rev.03
Pace Huntersville Quality Office
Client;
Location:
Project: L/- _CGS,..
Well JD-,
Reviewed Date and By: / L, __ Zl - ZJ G-tc,
Stabilization- Test 01 Ol /,YL NfzA'
INTell Diameter
Multiplication Factory
1
0.0408
1.2
0.0918
1.625
0.10&0
2
0.1630
3
0.3670
4
0.6330
6
1.4660
8
2.6100
Time
Purged
Temp.
n
(C)
Diss Oxy.
(,tug/C}
Spec.
Cond.
(us)
pH (s.u.)
ReDox (m1J):
Turbidity
(ntu)
Volume Removed
(gallons/aQl_)
circle one
Water level
( �
Other
iDSO
26�5
L4
�r5
S ► S'
3 5' L �,
O �i
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Document Name: Field. data Sheet
Date Issued: March 8, 2014
C@Avily6te
PaLe: 1of!
Document [Number: F-CAIi-FLD-001-rev.03
Issuing Authority: Pace Huntersviiie Quality.
J
i
Office .
Field Data Sheet
/410r 'ba'm VC Ptoject #: CCS aP Irw�lC411 c6mrtt'a-ner
Name and Affiliation (Sampler(s): CM.1 P4ca Field Data Sheet Review:
Name- and Affiliation (Inspector): ,4 Date: 1 Z i B 1 -c 6-
Well Information 1� �� �� y N
Well ID: PMw -1 U Well Locked: Y / NO / Flushmount) '
Well Diameter: V Construction: 46b/Steel/Stainless Steel)
Total Well Depth: 45• ft ft Multi Factor*:_ a•Ite3 r(Radius/12)2 x 3.14 x 7.48].
Static Water Level: 3Z.70 ft Casing Volume: Co-96 gallons.
Height of Water Column: !IZ-68 it Cal. 3 Volumes: -Zo.94 gallons
Pump Intake:_ _ f 2-- be, ft
Purge Information
Date Purged: 10 / tj /2024_ Start: IZ4S Finish: 1305. Purge Rate: r+G nr`n
Purging Method: PJAAAQ.r __ _ Totdi Volume'Purged: ViO0 (gallons/laL)
Samvlin$ Information
Date Collected:. j 6 / W U 21 Time Collected: 1310 (am/1
Sampling Equipment Used:_ Al"Jae Instrument ID: VSTU I7bS TEW 4 SS36
Bottle Type fteservatiG n Analysis Required
DwkA fbwtnlym%e& k-A
Field Measurements/Observations
SampleTexnp (°C): L �� .
Time:
i3tO
Turbidity (ntu): 1.7
Time:
1310
Digs Oxy (mg/L): 15.6
Time:
1316
Fe 2+ mg/L: wo
Time:
I3 to
Specific Cond. (US): �{i1.4 ,
Time:
13tm
Res. Cl (mg/L)/(ug/L):
�Time:.
Sample pH (s.u.): S i
Time:
13to
Odor: NA
Time:
1310
ReDox (mV): Zoe. b
Time:
.1316
Appearance: _ . Claw
-Time:
talc
ReDox (EH value):YSI ProPlus +200mV
3Q L fe
Other:
Time:
General/Weather Observations:.
(sunri cloudy/rainy) Temp._(°F) Wind o _3 (mph)
Sampler Signature: Date: 1 a/ IH ('ZP2..1
Stabilization Test
Spec'
Volume
Time
Temp.
Diss Oxy.
Cond.
pH (s.u.)
ReDox
Turbidity
. removed
Water
Other
Purged
(CC)
(mg/L)
(mV)
(ntu)
(gallons/o /
level (ft)
(us)
50
21.5
5.2
4't..0
G.1
I
9.2
(0a
32.So
la'
7A.S
5.1
44.0
S.1
190.1
$ .1
I>,
IZSS
Z1.K
5.0
43.9
%A
NIS.6
7.1
1200
U.iw
1300
21.3
41 1.43,,b
G.1 I
too .s
1.6
I6Qo
37-.e)o
-�
13 a5
21. e1
S'.o
tiY.O
5.1 1
W1.5
Z. 6
2,440
32 V.0

Document Name: Field data Sheet
Date Issued: March 8, 2019
a
Page: 1 of Z
C& k7l �1
Document IQumber: P-CAR-FLD-001-rev.03
Issuing Authority: face Huntersville Quality.
Office
Field Data Sheet
Clienf: Du Location: Macwes,
Name and Affiliation (Sampler(s): CM i eaact
Name and Affiliation (Inspector): A
Well Information
Well TD: CCPMW - I 1 Well Lacked:
Construction: kY�2-lSteel/Stainless Steel)
Well Diameter: V
Total Well Depth: 33-15 ft
Static Water Level: V.61 ft
Height of Water Column: 12._t11 ft
#: C1S cc P L 11 ce wtP11047ct
Data Sheet Review:
��•. z1.z�
Date: LO
/ NO / Flusbmount )
Multi Factor*: o • 1fo3 r(Radius/ 12)2 x 3.14 x 7.481
Casing Volume: 2- OZ gallons.
Cal. 3 Volumes: 10.610 gallons
Pump Intake: 31.25 1t
GC By. -
Purge Information
Date Purged; 16 / 14 /7,04_ Start: 112.&_ Finish. NS5 Purge Rate: 160r4 �n
Purging Method: g1r,,dds,r TotalVolvme'Purged: 3500 (gallons/eyL)
Sampling Information
Date Co1lecfed: IG ,I lH /2 Time Collected: 120a (am/0
Sampling Equipment Used:. 191eJAm- . _ _ Instrument ID: yST kl 1?b5 TPW 1553g
Bottle Type Preservatitin Analysis Required
-DuVa "If0tvx _ (k(:!'
Field Measur tnent Observations
Sample Temp (aq:
. 23.1
Time. 1246
Turbidity (ntu):
3.1
Timer
f2C
Diss Oxy (mg/L):
2-1
Time: 12CO .
Fe 2+ mg/L:
No
Time:
1200
Specific Cond. (us):
55.3
Time: _ J`I4a_
Res. Cl (mg/L)/(µg/L):
Time:.
Sample pH (s.u.):
5"•5
Time: i2db _Odor:
._ _
NS]
Tune:
1ZOM
ReDox (mV): ja?.
S
_Time: 1
Appearance;
C.1¢-
Time:
I?la
ReDox (EH value):YSI ProPlus +2OOmV
Other:
Time:
r
GeneraVWeather Observations:.
(Cu nr /cloudy/rainy) Temp. �g (OF) Wind a - 3 (mph)
Sampler Signature
Stabilization Test
Spec'
Volume
Time
Temp.Diss
Ox
Cond.
pH (s.u.)
ReDox
Turbidityremoved
Water
Other
Purged
(oC)
(mg/L)
(mV)
(ntu)
(gallons/ tQ/
level (ft)
(us)
1125.
[ 22.4
3.$
55.91
51:5
18b.1
t0.4
500
2.2.03
�-
D
22.4
3.8
SS.3
S.5
1661.3
1•.s
--
I.
1130
21.5 ,
3.9
57-5
S.S
161, .0
1. Z_L
1000
73. oa
-�
1115
U. 7
`3,3 1.SZ.L
5. S
i154..q
Z.Z.
1500
23.0-a
1110
2.1.-1
3.2
53.z
s.s
iga• 1
2.1
Zoa
23,60
r

Vocument Mime.,
Document J.sstivd March 8, 2019
Field DaW Sheet
f'ageZof Z
iICeAt WlYfi it
Document NUuiticn
[ssueiiigflutliciri#y:
i
F-C'ARFL.D-001,rev.03
Pace Huntersville Quality Office
Client: IN.,"
Location: i' or reshft C. QC_
Project: C[S CC II
Well ID: CGPMW-It
Reviewed Date and By: I u '2-1 G-C 6-
StabilizationTestLOOV)4_1 A'fZ/*-�`
Avell Diameter
;Iultiphcatioxt Factor"
1
0,0409
1,2.
0.0918
1.625
0.1080
2
0.1630
3
0.3670
4
0.6530
6
1 A680
8
2.6100
Time
Purged
Temp.
o
(C)
Diss Oxy:
(rng/L)
Spec.
Cond.
(us)
pH (s.u:)
ReDox (mV)
Turbidity
(ntu}
Volume Removed
(gallons/Q/�).
circle one
Water level
(ft}
Other
jftr5
22.16
13.6
54.16
S'.4-
IRk.0
3.1
2500
23.eo
�-
1150
2.2.W
3.0
SL-I.$
S.y
fCIS .s
3000
2-3-do
�-
1155
23.1
3.0
SS-3
5.4
197.4
W.1
3SQG
73.cc,

Document Name: 1=ield data Shcet
Date fixed: March a,, 2019
�_IwekkI44[caf
Page 1 of _
bctcumenC Number: F-CAR-FL.D-0Ot-rev.03
Issuing Authority: Dace Huntessville Quali ty
%
Office
Field Data Sheet
Location:i�
Name and Affiliation Field Data Sheet Review:
blame and Affiliation (Inspector): 111 t� -- ZI - z I
Da Ee:.
Well Information to c�y
Well ID: ez� Well Locked: Q E NO / F'lushmount )
WeJl Diameter: ZConstruction: 4E�12/Steel/Stainless Steel)
Total Well Depth: ! �_ ft
Static Water Level: 7d' ft
Height of Water Column: 7p z--ft
Multi Factor*: 62-1d �;' r(rtadius/12)2 x 3.14 x 7,481
Casing Volume: /_ gallons
Cal. 3 Volumes: mod- "� galIons
Pump Intake: rJ• Xf �/5-ft
By:
Purge Information /
Date Puxged:ZO / -c/ Start :Q Finish: t 3� 5 Pu:rge bate:
Purgvig Method:./'l Total Volume Pursed:
Sampling Information
Date Collected: �0 /z Time Collected: 1 �► (-. (am/
Sampling Equipment Used: 1� Instrument IDIII!
Bottle Type Preservation y�Analysis Required
Field Measurements/Observations
Sample Temp ()C):.-
- Z, � � __Time.
--.
Turbidity (ntu): Ci , Z_ Time:
hiss Oxy (mg/L).
` , Z'
Tune;
Fe 2+ mg/L: N Time:
Specific Cone. (u.S):
Time:
Res. Cl (nig/L)/(ug/L): --ftne:
Sample pFT (sat.):
-S�__.......-----Time:
Odor: .-.-.._._..---------- ---Time:
ReDox (mV): j
Z0y
Time:
Appearance: CIQy - I'irrte;
ReDox (EH valu.e).YSI ProPlus +200niV Z.ca a Wo
Other: �?�� „ _ Time:
General/Weather
Sampler Signature
Stabilization Test
�D't�
cloudy/rainy) Temp.
F) Wind �`�(mph)
Spey.
Volume
Time:
Temp.
u
Diss Oxy.
Cond.
pH (s.u.)
ReDox
Turbidity
removed
Water
Other
Purged
(C)
(Eng/L.)
(uS).
(tnV)
(tutu)
(gal.Tot.�s/�
level (ft)
L
ZSS
e
qli
St
1�4aA
.®ail
_5 3
�®
32
1 Y
03-
11r�w
1YV.'K
'0i
p©
c s
Z.13
y 1 2
S-'q
t20.-t
, 2
9 Off
'_ ,

—0-117
Document Nome: Field data Sheet
Late Issued: March 8, 2019
4C&.417r71yilCr71
Page:: 1 of
i3Ucument Number: F-CAR-FLD-0.01-rev.d3
Issuing Authority°.face klunterswillo Quality
`
E
Office.
Fie Id.Data Sheet
#: f✓t cam') &P60' v
Name and Affiliation (Sampler(s):S�j NAA-� � �4 ns,LJj,� Field Data Street Review:
Name and Affiliation (Inspector): isAA / u �f - � 1
Date: By:
WeII Information
WeI1.113: Lerd G W aunt).
Well Diameter: Co u ' eel)
Total. Well Depth: � ft Multi Factor*:r(Radius/12)2 x 3.14 x 7,48]
Static Water Level: ft Casing Volume. � gallons
Height of .Water Column: ft Cal. 3 Volumes: '~ gallons
Pump intake: ft
Purge Information,
Date Purged- / — / Start:, Finish: Purge ]late:
G-cC.
.purging Method, `�` Total Volume Purged: (gallons/oils/ L)
Sampling Information
Tate C olleeted:_IE3 /1A/ �. Time Colleetecl; 4�,36^"-_- ( nn /pm.)
Sampling Equipment Used:Instrument ID:_ Sfi30-'_7
Bottle Type Preservation Analysis Required
Field Measurentents Observe ions
Sample Temp: (°C): —Time: 05.31.'_ ._Turbidity (ntu)- 1.3 Time,........ IYA357
Diss pry {mg/L}: 4,�;_ Time 0 1� Fe 2+ mg/ C: Tune: Q�
Specific Cond. (uiS):36 , �16 Time: Res. Cl (mg/L)/(itg/L): �Time:
Sample pl-1. (s.u.)a !��Time: _ C1�3 Ddar:.N .....
R. eDox (mV): Time: 021 Appearance: C Time: Q`jri 1—
ReDux (EH value):YST. Pro.Plus +20.0mV. LA _Other: Time: __
General/Weather
cloudy/rainy)
Sampler Signature
Stabilization Test
Windy (mph)
Time
.Purged
Temp,
(C)
CC)
Diss Oxy.
(�ng/I.)
Spec.
Cond.
(us).
pH (s.u.)
ReDox.
(xttV)
Turbidity
(rttu)
Vo tttn.e
retn.oved
(gallons/nlls/
L)
Water
level {.ft)
Other

Document Name: Field data Sheet
Date Issued: March'.8} 2019
GeA7tx7-JjflfCt .
Page: 1 of
i7cxument (Vuml?er: F-CAR-rl..t7-0QZ-rev.Q
Issufltg Aoffiority: Pace HuntersvfIle'Qualfty
'
Office
Field Data Sheet
Client, Lncatiort:_. ,n��q,NC Project i ,oti
Nance and Affiliation (Samp'ler(sj:: n gAA -`� ta.u_ Antl�ec� � Field Data Sheet Review:
Eip Name and Affiliation (Ineetor)- 1j AJ
Date:.
Well Information to [a, IAA
Well ID: CCp- U-fCL(Ar- --
Well Diameter,
Total Well Depth: Ft
Static Water Level: ft
C ' ess ee
Multi Factor*: W. [;(Radius/12)2x 3.14 x 7,481
Cmmg`Volume: gallons
Yleight of .Water Column; ft Cal. 3 Volumes-, gallorts
Pump Intake: ft
Purge Information
Date Purged: /. " / -- Start ; Finish: Purge Date:
By: c C_
Purging Method Total Volume Purged: (gallons/oils1L)
lvc"z D�-Ur
Sampling Information
Date Coll.ectec{:_19__/1` /.._ Time Collected.:_19 S am(ptn)
Sampling Equipment Used: � }� Instrument 1D:,V 5T_ �o�l .t5 # O' [�� (pf-u C,<D 7�
Bottle Type
Field Measurentents/Observations
Preservation Analysis Required
Sample Temp (°C): —+Time:Q% Turbidity (ntu): Time: } o
Dist Oxy (mg/L): Time: ) o Fe 2+.rng/L: .. j] Time; 1 oc-�
Specific Conti. (us): Time:. c, C�- Res. Cl (nig/L)/(gg/L): Time:
Sample p.1 l (s.u.): L ._._.._._..... Time: l t' =—
ReDox (mV): 1`i `� • "i Time: 1 c, K< Appearance: CVO ( Time:
ReDox (EH value):YSI ProPlus f200n1V �'S� "� Other: Time: Y�
General/Weather Observations: N v 4 - - SVL,,e- ! a -U . �
( untt)/cloudy/rainy) 'Temp.(°F) Wind (mph)
Sampler Signature: _ _Date: -1 C1
Stabilization Test
Time
Purged
Temp,
CC)
Diss.Oxy.
(mg/ 1)
Spey'
{ S)
pH (s'tt')
Repox
(MV)
Turbidity
(ntu)
Volume
removed
(gallons/nals/
L
Water
level. (ft)
Other
3
g
ti
6,8
,�
l01 t�

C2Alir7n�liC l
=
Document Name: Field data Sheet
Date Issued: March 8; 2If19.
Page: 1 of
bocualent Number; F-CAR-rI..D-001-rev.bg
Authonit
Issuffi 6 y' Pace:Hunte"Aliile F„7uality
Office
Name and Affiliation
Field Data Sheet
h&0 p cS-e _ v 01 k ,
G-C'/M'tR - P,
Name and Affiliation (inspector): 1'k-�
Well Information
Well ID: < L 5- C w 1 \,Well Locked:
Total Well
Static Water Level:
Height of Water
Pure Information ~
Date Purged:
Start :
Coo 6�4rlbf
-ld Data Sheet Review:
Date- By:
(YES/ NO /
Lion: (PVC/Steel/Stainless Steel)
Multi Pactor�
Casing Volume:
Cal.3 Volumes:
( (Radius/12)2 x 3.14 x 7,481
gallons
Pump Intake: ft
PurgeRate.,
Purging Method:Total Volume.. Purged: Ilons/lilts/ L)
Sampling Information
Date Collected: 1 > / 19 / zl Time Collected:_11 -.._._ G./pm)
Sampling Equipment Used: !3'�! ci 13 Instrument 1D: ��•S� o z. 0 3 TPW 40 3 5.T
Bottle Type Preservation Analysis Required
_D c� __ j ,--- --------_--.-.-.-........
Field Measurentgnt .00bservations l
Sample Temp ()C):.-! �' Time: 09,Z-V_Tuzbidity (ntu): J ' Time: 0 9 2—G
Diss Oxy (mg/L): 7. [.( Time:
C) 92 0
Fe 2+ mg/L: x!-b
Time: -Y-) 9 z G
S ecific Cond. (us): 5 , U Time:
�Z-0
Res. Cl 111 L /L `
� Time: -__
Sample p.1-1. (s.u.)._._....._......-Time:
0 91U
Odor:. ,.V\�_.-_._...
lteDox (mV): Gf�(•'3 Time:
0 �''
Appearance: C[-&C V'
'Time: U �] 2-G
ReDox (EH value):YSI ProPlus +200in V � � � 3
Other: '~
Time: -�
General/Weather Observations:
Sampler Signature
Stabilization 'Pest
/cloudy/rainy) Temp...(°F) Wine b (mph)
ite: / I q ` a 1
Time
Purged
Temp,
°C
Diss Oxy:
111 I
Spec
Cond.
pH (s,u,)
ReDox
111V
Turbidity
11tu
Volume
removed
allons mis
L
Water
level (ft)
Other

jar
Uc� ument Name Field data Sheet
bate Issued: Mareh'8, 2II19
"".`
issuing Authority Pace Huntersville� Qiilc"L]tty.
T3geument IVunaber: E-CAR-FIB U01-cev:43
Office
Field Data Sheet:
C/{�...CCy� L1=Cc irnn�'14
Name and Affil€atim-i (Sampler(s)::3T76- AA - Qcc ,gr,aL,k� +.Field Data Sheet Review:
Name and Affiliation (Inspector):. r-' Date. ! J . 1-1
1 i! By:
3
WelI Information
Well ID: ZJ
Well Diameter:
Total Weil Depth: :ft
Static Water Level: � ft
Height of Water Column; ft
PuMe Information
Date Purged: — / = ./
C . ee teel)
Multi Factor'': ('(Rad1us/12)2x 3.14 x T481
Casing vblunle: gallons
Cal. 3 Volumes: gallons
Pump Intake: Ft
Start: " Finish: _ Purge Rate:
Purging Method: Tonal Volume Purged: (gallons/n-ls/L)
Sampling .lhiformation
Cate Collected. It—I1� '11 Time Collected:__bc! �....._ am pm)
Sampling, Equipment Used: Jnstrument ID: V ST........�...r�n� ��Q���� ONe,,� rf-j'i4-'30>1
Bottle Type Preservation Analysis Required
_
I -S& . m.e 1-c. [C
.Field Measurernents/Observations
Sample Temp C : , I g
p p{° ) ��.
Tune: `�._f �� _—_ Turbldit ntu : . C?
Y{. )
Time: O 1E 1 C
Disc Oxy (mg/L.):_12
Time: �n Fe 2+ mg/L: tV� Tune: a�1ti
Specific Cond. (uS): Sal •r$
Tune:._,, 1, t1 Res. Cl (ziig/L)/(ug/L): �f
Ti_Lne:
a e l o Odar: _ _. .._..._...:_ ' ...__
Time: _._._'Z�cA L�.__._.—
ReD.ox (mV);
Time: c A i a Appearance: Cteae'
'rime: +a lk 1.0
ReDox (EH value):YSI. ProPlus. f200rnV_ ?7�1 Other: i---
Time:
General/Weather Observations:
GPS �� n sus , 1 a . [ 1 `� %+ �� ° �S •,6
�'l.✓
cloudy/rainy)
Sampler Signature
Stabilization Test
Wind_� _ _(mph)
Time
Purged
Temp.
°C
Diss Oxy,
in L
Spec.
Cond.
pH (sx.)
ReDox
mV
Turbidity
tutu.
o ettt�e
removed
alloris mis
L
Water
level. ft
Other
1a

L�ncuntent Name: Field data Sheet
Date Issuer{: March 8, 2019'
17C,lllk7fyl�CR[ 6
Page:.1 of
Document Number: F-CAR-FLD-00b-rev,03
Issuing Authority Pace,Htuitersvill Quality
Office
Field. Data Sheet
Natne and Affiliation (Sampler(s) �Z� � -?c Lt AnaU .e-a..l
Name and Affiliation (Inspector):
Well Information
Well ID: A)
Well Diameter:
Total Well Depth: .� ft
Static Water Level: 1 ft
#: l. R1 to CC V LPC c,,Yp te, ,e_'),o�
Data. Sheet Review:
1� zf Z0
Date:l
O
NO / Flushm—ou nr
ee x: e9s teel)
Multi Factor*: r(Radius/12)2 x 3.14. x 7.481
Casing Volume: — gallons
Height of Water Column: _ ft Cal, 3 Volumes: r gallons
.Punip intake: ft
Purge Information
Date Purged: y Start: — Finish: Purge Rate:
. C_C C_
NDA
Purging Method:_ J Total Volume Purged, �. (gallons/ nis/ lw)
Sampling Information
Date Calleeted:. L) /1Lt/_jA : Time Collected: o ►K._._ O/pm)
SaznplittgEquipment Usedt Instrument ID- SM Rr-n�ri..rY+tc„z,}PtL,t� "3n3�
Bottle Type Preservation analysis Required.
Field Measurenients/Observations
Sample Temp (°C): iy ,Time:. f_C) �5 �_Turbidi.ty (ntu); 9 Time: i Q t
Diss Oxy (mg/L): 5 ,O Time: O t Fe 2+ mg/ L: 0 Time.,
Specific Cond. (uS): Time: t1 [ Res. CI (nag/t)/(gg/L): — Time:
Sample pH (s.u.): Time: i 4 f Odor:__
IZeDox (mV): 15` �� Tkie: 19 15 Appearance: C �,eltr Time: %C) 1
ReDox (E,H value):YS.I ProPlus +200mV Other: Time:
General/Weather Observations; L i ,j I N t-i r V/
cloudy/rainy) Temp _.(OF) Wine{ 0 (mph)
Sampler Signature
Stabilization Test
Time
I'ni�gerl.
Temp.
o
(C)
Diss Oxy.
(mg/1.)
Spec.
Cond.
(US)
pH (s.u,)
ReDox
(YnV)
Turbidity
(ntu)
Volume
removed
(gall'ons/mis/
L
Water
level. (ft)
Other
t� ,�
Li

f]ocun��nt Name:Meld data Sheet
Elate Issued; March 8, 20W
ftC�A(k7lytiC�7l
Pa 0:: l of:
Document Number F-CAR-E1..i�-001-rev,0,�
lssuiilg Authority. Pace Huntersville Quality
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Field Data Sheet
.A ^A -� i _ —
Name and Affiliation (Sampler(s): R m B Y`m PKO
Marne and Affiliation (Inspector),..rf 1A
Well Information
Well ID ( lr5-- r ts" I Well Locked:
Well Diameter: Construction:
Total Well Depth: ft
Static Water level: ft
Height of Water Column: — ft
Purge Information
Date
Project #: G LS GL p L F Go0"Pl: nn l e Q G�. 20 z/
!Id Data Sheet Review:
Date: jo-1l--Ii BY:
NO / F'lushmount ).
Steel.)
Multi Factor*: r(Radius%12)2 x 31.4 x 7,48)
Casing Volume: gallons
Cal, 3 Volumes: gallons
Pump Intake: ft
Start : ! FinisN Purge Rate: �~
Purging Method. .--1 Total Volume. Purged: (gallons/.nils'/L)
SaMling.Information
Date Collected: iirzte Collected:_ 1 I I IJ __._._- am/ . )
Sampling Equipment Used: 8 f0.1 air PLK-AT Instrument ID:__
Bottle Type Preservation Analysis Required
Field MeasurementsfObservations
Sample Temp (°C):
Diss Oxy (mg/L):
Specific Cond. (uS):
Sample pH (s,tt.): �__.._._...
Time:. ,...... _.............. —_Turbidity (ntu).
Time Fe 2+ mg/ L
Time:
Tin -Le:
L) Time:
ReDox (mV): Time- Appearance- I irate:
R value):YS1..Pro.Plus.+200mV Other: Time:
General/Weather Observations: F, Q' 1d d a li Lai Q ia-M'P re 4 r- CG F /A vd — 15
sunny cloudy/rainy) Ternp._.7 Z ff) Wind 0-5 (mph)
Sampler Signature: Date: Q I l LI % -21��
Stabilization Test
Purged
Temp. Tep.
Diss Qxy:
(nig/L)
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Card.
(uS).
pH (s.u.)
Repnx
(znV)
Turbidity
(ntu)
Volume
removed
(gallons/nfls/
Water

2cleAnab4ical'
Document Name: field data Sheet
Date [stied: March 8; 2M..
Page: 1 caf i
Document lrfuniber: F-CAR-I.1d7-00T-rev.03
fasubig Authority: Pace HwttersvilleQuality
'
Office
-"D kI<e-
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Name and Affil.iatio.n (Sampler(s):.
Name and Affiliation (Inspector): 0�
WeII Information
vor
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eld Data Sheet Review: Z 1
Date: tow .,. By: M
Well ID: C l S ell Locked: (YES / No / Flushrrtount )
Diameter: Cons ction: (PVC/Steel/Str h-dess Steel)
Total We the ft Multi Factor r(Radius/1a)2 x 3.14 x 7.481
Static Water Level: ft Casing Volume: gallons
Height of Water Column: ft Cal. 3 Volumes: gallons
Purge In€ormation
Date Purged:
Purging
Pump
Start : �—
Total Volume Purged:
Purge Rate
n71s/"id)
Sawn .lin In€ormation
Date Collected: f U /l � / Zl Time Collected:_0 �'fD ._ (Q/p1n)
Sampling Equipment Used- G,"6 Instrument ID: V 5-C 4'0 Z03 TPW -A0 3 $ S
14
Bottle Type Preservation Analysis Required
Sample Temp (°C): _ Tine:_ _Turbidity (ntu): Time:
Diss Oxy (mg/L): T1 ne. ............ Fe 2+ m�_,/ L: Time:
Specific Cond. (uS): Time:
Sample pH (s.u,):
[ZeDox (rnV): Time:
ReDox (EH value):YSI ProPlus +200mV_
General/Weather Observations: +S k
Odor:__
Appearance. -
Other:
cc PSw— I
L)/(gg/ L): °Time•
Time:
u cloudy/rainy) Temp. (Dy .(°F) Wind C) (mph)
Sampler Signature: Date: 1 "
Stabilization Test
Time
Purged
Temp.
CC)
ss Oxy.
Ong/ _.
Spec.
Cored.
pH (s.u.)
IieDox
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Turbidity
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Vo TCme
removed
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L
Water
level (ft)
Other

M
Document i anw— t ield data Sheet.
Date Issued March &; 2(]39
Page l of
ce�4ik71yllC. r
l7Ucunient NuntUer: F�CAR-CAR-0QL-rev.oj
Iss� big ALIthorily: Pace Htintenville Quality
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r
Office
ient.--VVj�, Q��gy
Name and. Affiliation (Samgler(s);
Name and Affiliation
Well Information
Well F
Well ID: C lV1VV ~-:�-s
Well Diameter:
Total Well Depth: C�• � I Ft
Static Water Level:Beiowft
Height of Water Co.lUMn' : ft
dooftsb f l C Pro)ect #: CU
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ko)1Vl21
Date:
to
Well Locked: OYES-y NO
Construction: PVC Steel/Staiffless Steel)
Multi Factor*: b. �63 ((RWius/12)2x3:14 x 7.481
Casing Volume: - gallor-is
Cal. 3 Volumes: gallons
Pump Intake:_ 141(D() ft
f►lf C�vnp�iar�c�.
By: tit C
Purge Information
Date Purged- I Q//� Start : `1 Finish: Purge Rate:
Purging Method-. AP -Total Volume Purged: --_� (ga:llons/.tn1s/L)
Saintnliniz hidorma Lion
Date Collected:=j- Time Co:l[ected:_ 7:=._ (am/pm)
Sampling,. Equipment Used: Instrument ID: _--w#602
Bottle Type Preservation Analysis Required
IUt
Field Measurements/Observations
Sample Temp (°C.): _
Tin-ke:­---.-.-.-.-.
-Turbidity. (ntu):
Time; _
Diss Oxy ('ng/L)-
Time:
Fe 2+ mg/ L:
artt :
Specific Coud.(US):
Time:.
Res..Cl 1;g/L}:
Time:
Sample pH.. (s.u.):-...-
ReDox (m.V):
Tune:
Appearance:
Time:
H value);YSI ProPlus +200n V
Other:
Tirae:
cloudy./rainy) Temp. �_�G WY�4�4#C L+iQ�r
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Sampler Signature
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a
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(MV)
Turbidity
(1 tu)
Volume
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0
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wood.
/e1»4►101KI1.1
Laboratory Report and Chain -of -Custody Forms

DUKE
Analytical Laboratory
4L, ' ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number:
J21090196
Project Name:
CLIFFSIDE - GW CCP LANDFILL
Task Code:
LF
Customer Name(s):
Ryan Czop, Bryan Moeller, Dee OBrien,Josh Stowe
Customer Address:
Cliffside Steam Station
573 Duke Power Rd
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Lab Contact:
Peggy Kendall Phone: [phone]
Report Authorized By:
pate: 10/29/2021
(Signature)
Peg Kendall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 82
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 82
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2021025386
CLIFFSIDE
14-Oct-21
10:40AM
GLG
CLS CCPMW-1S
2021025387
CLIFFSIDE
14-Oct-21
10:25AM
GLG
CLS CCPMW-1D
2021025388
CLIFFSIDE
14-Oct-21
11:10 AM
RMB
CLS CCPMW-2S
2021025389
CLIFFSIDE
14-Oct-21
1:20 PM
RMB
CLS CCPMW-2D
2021025391
CLIFFSIDE
14-Oct-21
10:15 AM
RMB
CLS CCPMW-3D
2021025392
CLIFFSIDE
14-Oct-21
10:40 AM
NRA
CLS CCPMW-4
2021025393
CLIFFSIDE
14-Oct-21
1:25 PM
NRA
CLS CCPMW-5
2021025394
CLIFFSIDE
14-Oct-21
1:30 PM
GLG
CLS CCPMW-6S
2021025395
CLIFFSIDE
14-Oct-21
12:25 PM
GLG
CLS CCPMW-6D
2021025396
CLIFFSIDE
14-Oct-21
10:20 AM
CTB
CLS CCPMW-7
2021025397
CLIFFSIDE
14-Oct-21
11:35 AM
BMS
CLS CCPMW-8
2021025398
CLIFFSIDE
14-Oct-21
1:10 PM
CTB
CLS CCPMW-10
2021025399
CLIFFSIDE
14-Oct-21
12:00 PM
CTB
CLS CCPMW-11
2021025400
CLIFFSIDE
14-Oct-21
1:10 PM
BMS
CLS CCPTW-2
2021025401
CLIFFSIDE
14-Oct-21
9:35 AM
JJZ
CLS CCP-Leachate
2021025402
CLIFFSIDE
14-Oct-21
9:20 AM
GLG
CLS CCPSW-1
2021025403
CLIFFSIDE
14-Oct-21
9:10 AM
JJZ
CLS CCPSW-2
2021025404
CLIFFSIDE
14-Oct-21
10:15 AM
JJZ
CLS CCPSW-3
2021025405
CLIFFSIDE
14-Oct-21
RMB
CLS FD-20211014-1
2021025406
CLIFFSIDE
14-Oct-21
9:40 AM
GLG
CLS FB-20211014-0940
2021027486
CLIFFSIDE
14-Oct-21
10:55 AM
JJZ
CLS CCP-LEACHATE-34
21 Total Samples

Page 3 of 82
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 10/29/2021

Certificate of Laboratory Analysis Page 4 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-1 S
Sample #: 2021025386
Collection Date: 10/14/2021
10:40 AM
Loc code: CLS CCPMW-1 S
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100235
Alkalinity (mg/L CaCO3)
1.85 J
mg/L
5
1.7
1 SM 2320B
10/15/2021 18:27
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.1
mg/L
0.1
0.0154
1 EPA 9056A
10/15/2021 13:08
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/15/2021 13:08
GHUTCHI
Nitrate
0.17
mg/L
0.1
0.0209
1 EPA 9056A
10/15/2021 13:08
GHUTCHI
Nitrate as N
0.04
mg-N/L
0.023
0.002
1 EPA 9056A
10/15/2021 13:08
GHUTCHI
Sulfate
0.18
mg/L
0.1
0.0428
1 EPA 9056A
10/15/2021 13:08
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1 EPA 7470A
10/21/2021 12:39
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Barium (Ba)
0.027
mg/L
0.005
0.002
1 SW 6010D
10/19/2021 13:41
DMFRANC
Boron (B)
0.006 J
mg/L
0.05
0.005
1 SW 6010D
10/19/2021 13:41
DMFRANC
Calcium (Ca)
0.157
mg/L
0.05
0.012
1 SW 6010D
10/19/2021 13:41
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 13:41
DMFRANC
Iron (Fe)
0.048
mg/L
0.01
0.004
1 SW 6010D
10/19/2021 13:41
DMFRANC
Magnesium (Mg)
0.793
mg/L
0.02
0.008
1 SW 6010D
10/19/2021 13:41
DMFRANC
Manganese (Mn)
0.018
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 13:41
DMFRANC
Potassium (K)
0.830
mg/L
0.1
0.031
1 SW 6010D
10/19/2021 13:41
DMFRANC
Sodium (Na)
1.42
mg/L
0.05
0.017
1 SW 6010D
10/19/2021 13:41
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/19/2021 13:41
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Chromium (Cr)
0.716 J
ug/L
1
0.185
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Cobalt (Co)
1.55
ug/L
1
0.077
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Lead (Pb)
0.055 J
ug/L
1
0.037
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Nickel (Ni)
0.684 J
ug/L
1
0.256
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Thallium (TI) Low Level
0.157 J
ug/L
0.2
0.041
1 SW 6020B
10/25/2021 18:00
CWSPEN3
Vanadium (V) Low Level
0.142 J
ug/L
0.3
0.114
1 SW 6020B
10/25/2021 18:00
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 5 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-1 D
Sample #: 2021025387
Collection Date: 10/14/2021
10:25 AM
Loc code: CLS CCPMW-1 D
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100235
Alkalinity (mg/L CaCO3)
4.88 J
mg/L
5
1.7
1 SM 2320B
10/15/2021 18:45
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
7.6
mg/L
0.1
0.0154
1 EPA 9056A
10/15/2021 14:10
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/15/2021 14:10
GHUTCHI
Nitrate
2.7
mg/L
0.1
0.0209
1 EPA 9056A
10/15/2021 14:10
GHUTCHI
Nitrate as N
0.61
mg-N/L
0.023
0.002
1 EPA 9056A
10/15/2021 14:10
GHUTCHI
Sulfate
1.6
mg/L
0.1
0.0428
1 EPA 9056A
10/15/2021 14:10
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1 EPA 7470A
10/21/2021 12:46
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Barium (Ba)
0.017
mg/L
0.005
0.002
1 SW 6010D
10/19/2021 13:54
DMFRANC
Boron (B)
0.007 J
mg/L
0.05
0.005
1 SW 6010D
10/19/2021 13:54
DMFRANC
Calcium (Ca)
2.54
mg/L
0.05
0.012
1 SW 6010D
10/19/2021 13:54
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 13:54
DMFRANC
Iron (Fe)
0.012
mg/L
0.01
0.004
1 SW 6010D
10/19/2021 13:54
DMFRANC
Magnesium (Mg)
1.46
mg/L
0.02
0.008
1 SW 6010D
10/19/2021 13:54
DMFRANC
Manganese (Mn)
0.008
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 13:54
DMFRANC
Potassium (K)
1.33
mg/L
0.1
0.031
1 SW 6010D
10/19/2021 13:54
DMFRANC
Sodium (Na)
2.70
mg/L
0.05
0.017
1 SW 6010D
10/19/2021 13:54
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/19/2021 13:54
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Chromium (Cr)
0.308 J
ug/L
1
0.185
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Cobalt (Co)
0.352 J
ug/L
1
0.077
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Nickel (Ni)
1.06
ug/L
1
0.256
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Thallium (TI) Low Level
0.063 J
ug/L
0.2
0.041
1 SW 6020B
10/25/2021 17:25
CWSPEN3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1 SW 6020B
10/25/2021 17:25
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 6 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-2S
Sample #: 2021025388
Collection Date: 10/14/2021
11:10 AM
Loc code: CLS CCPMW-2S
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100235
Alkalinity (mg/L CaCO3)
5.76
mg/L
5
1.7
1
SM 2320B
10/15/2021 18:51
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.2
mg/L
0.1
0.0154
1
EPA 9056A
10/15/2021 14:31
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/15/2021 14:31
GHUTCHI
Nitrate
4.5
mg/L
0.1
0.0209
1
EPA 9056A
10/15/2021 14:31
GHUTCHI
Nitrate as N
1.0
mg-N/L
0.023
0.002
1
EPA 9056A
10/15/2021 14:31
GHUTCHI
Sulfate
6.9
mg/L
0.1
0.0428
1
EPA 9056A
10/15/2021 14:31
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.04 J
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 12:48
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Barium (Ba)
0.033
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 13:58
DMFRANC
Boron (B)
0.01 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 13:58
DMFRANC
Calcium (Ca)
3.11
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 13:58
DMFRANC
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 13:58
DMFRANC
Iron (Fe)
0.228
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 13:58
DMFRANC
Magnesium (Mg)
2.17
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 13:58
DMFRANC
Manganese (Mn)
0.041
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 13:58
DMFRANC
Potassium (K)
2.02
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 13:58
DMFRANC
Sodium (Na)
1.71
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 13:58
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 13:58
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Arsenic (As)
0.115 J
ug/L
1
0.111
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Chromium (Cr)
4.19
ug/L
1
0.185
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Cobalt (Co)
0.658 J
ug/L
1
0.077
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Lead (Pb)
0.21 J
ug/L
1
0.037
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Nickel (Ni)
1.98
ug/L
1
0.256
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Selenium (Se)
0.56 J
ug/L
1
0.193
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Thallium (TI) Low Level
0.129 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 18:08
CWSPEN3
Vanadium (V) Low Level
0.670
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 18:08
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 7 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-2D
Sample #: 2021025389
Collection Date: 10/14/2021
01:20 PM
Loc code: CLS CCPMW-2D
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100235
Alkalinity (mg/L CaCO3)
39.7
mg/L
5
1.7
1 SM 2320B
10/15/2021 18:58
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
5.4
mg/L
0.1
0.0154
1 EPA 9056A
10/15/2021 14:51
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/15/2021 14:51
GHUTCHI
Nitrate
5.4
mg/L
0.1
0.0209
1 EPA 9056A
10/15/2021 14:51
GHUTCHI
Nitrate as N
1.2
mg-N/L
0.023
0.002
1 EPA 9056A
10/15/2021 14:51
GHUTCHI
Sulfate
4.9
mg/L
0.1
0.0428
1 EPA 9056A
10/15/2021 14:51
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1 EPA 7470A
10/21/2021 12:50
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Barium (Ba)
0.008
mg/L
0.005
0.002
1 SW 6010D
10/19/2021 14:03
DMFRANC
Boron (B)
0.005 U
mg/L
0.05
0.005
1 SW 6010D
10/19/2021 14:03
DMFRANC
Calcium (Ca)
15.7
mg/L
0.05
0.012
1 SW 6010D
10/19/2021 14:03
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 14:03
DMFRANC
Iron (Fe)
0.010
mg/L
0.01
0.004
1 SW 6010D
10/19/2021 14:03
DMFRANC
Magnesium (Mg)
0.821
mg/L
0.02
0.008
1 SW 6010D
10/19/2021 14:03
DMFRANC
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 14:03
DMFRANC
Potassium (K)
3.13
mg/L
0.1
0.031
1 SW 6010D
10/19/2021 14:03
DMFRANC
Sodium (Na)
5.36
mg/L
0.05
0.017
1 SW 6010D
10/19/2021 14:03
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/19/2021 14:03
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Arsenic (As)
0.547 J
ug/L
1
0.111
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Chromium (Cr)
1.10
ug/L
1
0.185
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Thallium (TI) Low Level
0.06 J
ug/L
0.2
0.041
1 SW 6020B
10/25/2021 18:17
CWSPEN3
Vanadium (V) Low Level
4.06
ug/L
0.3
0.114
1 SW 6020B
10/25/2021 18:17
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 8 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-3D
Sample #: 2021025391
Collection Date: 10/14/2021
10:15 AM
Loc code: CLS CCPMW-3D
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100235
Alkalinity (mg/L CaCO3)
5.90
mg/L
5
1.7
1 SM 2320B
10/15/2021 19:05
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
6.5
mg/L
0.1
0.0154
1 EPA 9056A
10/15/2021 15:32
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/15/2021 15:32
GHUTCHI
Nitrate
5.4
mg/L
0.1
0.0209
1 EPA 9056A
10/15/2021 15:32
GHUTCHI
Nitrate as N
1.2
mg-N/L
0.023
0.002
1 EPA 9056A
10/15/2021 15:32
GHUTCHI
Sulfate
14
mg/L
0.5
0.0428
5 EPA 9056A
10/15/2021 15:32
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1 EPA 7470A
10/21/2021 12:52
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Barium (Ba)
0.028
mg/L
0.005
0.002
1 SW 6010D
10/19/2021 14:07
DMFRANC
Boron (B)
0.025 J
mg/L
0.05
0.005
1 SW 6010D
10/19/2021 14:07
DMFRANC
Calcium (Ca)
7.55
mg/L
0.05
0.012
1 SW 6010D
10/19/2021 14:07
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 14:07
DMFRANC
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1 SW 6010D
10/19/2021 14:07
DMFRANC
Magnesium (Mg)
1.96
mg/L
0.02
0.008
1 SW 6010D
10/19/2021 14:07
DMFRANC
Manganese (Mn)
0.007
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 14:07
DMFRANC
Potassium (K)
1.63
mg/L
0.1
0.031
1 SW 6010D
10/19/2021 14:07
DMFRANC
Sodium (Na)
2.28
mg/L
0.05
0.017
1 SW 6010D
10/19/2021 14:07
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/19/2021 14:07
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Chromium (Cr)
1.19
ug/L
1
0.185
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Cobalt (Co)
0.097 J
ug/L
1
0.077
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Thallium (TI) Low Level
0.088 J
ug/L
0.2
0.041
1 SW 6020B
10/25/2021 18:25
CWSPEN3
Vanadium (V) Low Level
0.184 J
ug/L
0.3
0.114
1 SW 6020B
10/25/2021 18:25
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-4
Collection Date: 10/14/2021 10:40 AM Loc code: CLS CCPMW-4
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q21100235
Alkalinity (mg/L CaCO3) 76.1 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride 1.7
mg/L
0.1
0.0154 1
Fluoride 0.20
mg/L
0.1
0.0479 1
Nitrate 0.04 J
mg/L
0.1
0.0209 1
Nitrate as N 0.01 J
mg-N/L
0.023
0.002 1
Sulfate 11
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg) 0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Sample #: 2021025392
Matrix: GW RCRA
Page 9 of 82
Method Analysis Date/Time Analyst
SM 2320B 10/15/2021 19:11 EBATIAN
EPA
9056A
10/15/2021
16:14
GHUTCHI
EPA
9056A
10/15/2021
16:14
GHUTCHI
EPA
9056A
10/15/2021
16:14
GHUTCHI
EPA
9056A
10/15/2021
16:14
GHUTCHI
EPA
9056A
10/15/2021
16:14
GHUTCHI
EPA
7470A
10/21/2021
12:55
JAA5429
Barium (Ba)
0.008
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 14:20
DMFRANC
Boron (B)
0.01 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 14:20
DMFRANC
Calcium (Ca)
21.2
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 14:20
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:20
DMFRANC
Iron (Fe)
0.024
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 14:20
DMFRANC
Magnesium (Mg)
0.978
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 14:20
DMFRANC
Manganese (Mn)
0.009
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:20
DMFRANC
Potassium (K)
8.78
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 14:20
DMFRANC
Sodium (Na)
11.1
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 14:20
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 14:20
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Arsenic (As)
0.674 J
ug/L
1
0.111
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Chromium (Cr)
0.187 J
ug/L
1
0.185
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 18:34
CWSPEN3
Vanadium (V) Low Level
0.135 J
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 18:34
CWSPEN3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-5
Collection Date: 10/14/2021 01:25 PM Loc code: CLS CCPMW-5
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q21100235
Alkalinity (mg/L CaCO3) 36.3 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride 5.3
mg/L
0.1
0.0154 1
Fluoride 0.15
mg/L
0.1
0.0479 1
Nitrate 4.9
mg/L
0.1
0.0209 1
Nitrate as N 1.1
mg-N/L
0.023
0.002 1
Sulfate 19
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg) 0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Sample #: 2021025393
Matrix: GW RCRA
Page 10 of 82
Method Analysis Date/Time Analyst
SM 2320B 10/15/2021 19:19 EBATIAN
EPA
9056A
10/15/2021
16:55
GHUTCHI
EPA
9056A
10/15/2021
16:55
GHUTCHI
EPA
9056A
10/15/2021
16:55
GHUTCHI
EPA
9056A
10/15/2021
16:55
GHUTCHI
EPA
9056A
10/15/2021
16:55
GHUTCHI
EPA
7470A
10/21/2021
12:57
JAA5429
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 14:24
DMFRANC
Boron (B)
0.015 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 14:24
DMFRANC
Calcium (Ca)
12.5
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 14:24
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:24
DMFRANC
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 14:24
DMFRANC
Magnesium (Mg)
0.338
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 14:24
DMFRANC
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:24
DMFRANC
Potassium (K)
1.88
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 14:24
DMFRANC
Sodium (Na)
9.56
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 14:24
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 14:24
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.266 J
ug/L
1
0.104
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Arsenic (As)
2.30
ug/L
1
0.111
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Chromium (Cr)
12.0
ug/L
1
0.185
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 18:42
CWSPEN3
Vanadium (V) Low Level
10.4
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 18:42
CWSPEN3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-6S
Collection Date: 10/14/2021 01:30 PM Loc code: CLS CCPMW-6S
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q21100235
Alkalinity (mg/L CaCO3) 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride 5.3
mg/L
0.1
0.0154 1
Fluoride 0.0479 U
mg/L
0.1
0.0479 1
Nitrate 14
mg/L
0.5
0.0209 5
Nitrate as N 3.1
mg-N/L
0.023
0.002 1
Sulfate 1.7
mg/L
0.1
0.0428 1
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg) 0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Sample #: 2021025394
Matrix: GW RCRA
Page 11 of 82
Method Analysis Date/Time Analyst
SM 2320B 10/15/2021 19:34 EBATIAN
EPA
9056A
10/15/2021
17:36
GHUTCHI
EPA
9056A
10/15/2021
17:36
GHUTCHI
EPA
9056A
10/15/2021
17:36
GHUTCHI
EPA
9056A
10/15/2021
17:36
GHUTCHI
EPA
9056A
10/15/2021
17:36
GHUTCHI
EPA
7470A
10/21/2021
12:59
JAA5429
Barium (Ba)
0.045
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 14:28
DMFRANC
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 14:28
DMFRANC
Calcium (Ca)
1.54
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 14:28
DMFRANC
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:28
DMFRANC
Iron (Fe)
0.218
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 14:28
DMFRANC
Magnesium (Mg)
2.06
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 14:28
DMFRANC
Manganese (Mn)
0.049
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:28
DMFRANC
Potassium (K)
1.55
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 14:28
DMFRANC
Sodium (Na)
3.20
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 14:28
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 14:28
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Cadmium (Cd)
0.033 J
ug/L
1
0.032
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Chromium (Cr)
1.84
ug/L
1
0.185
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Cobalt (Co)
2.04
ug/L
1
0.077
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Lead (Pb)
0.155 J
ug/L
1
0.037
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Nickel (Ni)
2.28
ug/L
1
0.256
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Thallium (TI) Low Level
0.145 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 18:50
CWSPEN3
Vanadium (V) Low Level
0.368
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 18:50
CWSPEN3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 12 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-6D
Sample #: 2021025395
Collection Date: 10/14/2021
12:25 PM
Loc code: CLS CCPMW-6D
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100235
Alkalinity (mg/L CaCO3)
5.64
mg/L
5
1.7
1 SM 2320B
10/15/2021 19:39
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
5.2
mg/L
0.1
0.0154
1 EPA 9056A
10/15/2021 18:17
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/15/2021 18:17
GHUTCHI
Nitrate
11
mg/L
0.5
0.0209
5 EPA 9056A
10/15/2021 18:17
GHUTCHI
Nitrate as N
2.5
mg-N/L
0.023
0.002
1 EPA 9056A
10/15/2021 18:17
GHUTCHI
Sulfate
0.35
mg/L
0.1
0.0428
1 EPA 9056A
10/15/2021 18:17
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1 EPA 7470A
10/21/2021 13:01
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Barium (Ba)
0.035
mg/L
0.005
0.002
1 SW 6010D
10/19/2021 14:33
DMFRANC
Boron (B)
0.005 U
mg/L
0.05
0.005
1 SW 6010D
10/19/2021 14:33
DMFRANC
Calcium (Ca)
1.51
mg/L
0.05
0.012
1 SW 6010D
10/19/2021 14:33
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 14:33
DMFRANC
Iron (Fe)
0.006 J
mg/L
0.01
0.004
1 SW 6010D
10/19/2021 14:33
DMFRANC
Magnesium (Mg)
1.76
mg/L
0.02
0.008
1 SW 6010D
10/19/2021 14:33
DMFRANC
Manganese (Mn)
0.014
mg/L
0.005
0.001
1 SW 6010D
10/19/2021 14:33
DMFRANC
Potassium (K)
1.67
mg/L
0.1
0.031
1 SW 6010D
10/19/2021 14:33
DMFRANC
Sodium (Na)
3.28
mg/L
0.05
0.017
1 SW 6010D
10/19/2021 14:33
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/19/2021 14:33
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Chromium (Cr)
1.29
ug/L
1
0.185
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Cobalt (Co)
0.527 J
ug/L
1
0.077
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Nickel (Ni)
0.671 J
ug/L
1
0.256
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Thallium (TI) Low Level
0.082 J
ug/L
0.2
0.041
1 SW 6020B
10/25/2021 18:59
CWSPEN3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1 SW 6020B
10/25/2021 18:59
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-7
Collection Date: 10/14/2021 10:20 AM Loc code: CLS CCPMW-7
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q21100235
Alkalinity (mg/L CaCO3) 7.83 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride 10
mg/L
0.5
0.0154 5
Fluoride 0.0479 U
mg/L
0.1
0.0479 1
Nitrate 9.0
mg/L
0.1
0.0209 1
Nitrate as N 2.0
mg-N/L
0.023
0.002 1
Sulfate 0.55
mg/L
0.1
0.0428 1
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg) 0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q21100240
Sample #: 2021025396
Matrix: GW RCRA
Page 13 of 82
Method Analysis Date/Time Analyst
SM 2320B 10/15/2021 19:46 EBATIAN
EPA
9056A
10/15/2021
18:58
GHUTCHI
EPA
9056A
10/15/2021
18:58
GHUTCHI
EPA
9056A
10/15/2021
18:58
GHUTCHI
EPA
9056A
10/15/2021
18:58
GHUTCHI
EPA
9056A
10/15/2021
18:58
GHUTCHI
EPA
7470A
10/21/2021
13:04
JAA5429
Barium (Ba)
0.047
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 14:38
DMFRANC
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 14:38
DMFRANC
Calcium (Ca)
3.95
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 14:38
DMFRANC
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:38
DMFRANC
Iron (Fe)
0.170
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 14:38
DMFRANC
Magnesium (Mg)
1.97
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 14:38
DMFRANC
Manganese (Mn)
0.073
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:38
DMFRANC
Potassium (K)
2.54
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 14:38
DMFRANC
Sodium (Na)
4.38
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 14:38
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 14:38
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100244
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Cadmium (Cd)
0.033 J
ug/L
1
0.032
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Chromium (Cr)
0.982 J
ug/L
1
0.185
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Cobalt (Co)
0.837 J
ug/L
1
0.077
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Lead (Pb)
0.106 J
ug/L
1
0.037
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Nickel (Ni)
1.63
ug/L
1
0.256
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Thallium (TI) Low Level
0.081 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 19:07
CWSPEN3
Vanadium (V) Low Level
0.447
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 19:07
CWSPEN3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-8
Collection Date: 10/14/2021 11:35 AM Loc code: CLS CCPMW-8
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q21100239
Alkalinity (mg/L CaCO3) 2.18 J mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride 22
mg/L
0.5
0.0154 5
Fluoride 0.0479 U
mg/L
0.1
0.0479 1
Nitrate 3.8
mg/L
0.1
0.0209 1
Nitrate as N 0.86
mg-N/L
0.023
0.002 1
Sulfate 0.24
mg/L
0.1
0.0428 1
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg) 0.01 J
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Sample #: 2021025397
Matrix: GW RCRA
Page 14 of 82
Method Analysis Date/Time Analyst
SM 2320B 10/18/2021 14:36 EBATIAN
EPA
9056A
10/15/2021
20:40
GHUTCHI
EPA
9056A
10/15/2021
20:40
GHUTCHI
EPA
9056A
10/15/2021
20:40
GHUTCHI
EPA
9056A
10/15/2021
20:40
GHUTCHI
EPA
9056A
10/15/2021
20:40
GHUTCHI
EPA
7470A
10/21/2021
13:10
JAA5429
Barium (Ba)
0.075
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 14:51
DMFRANC
Boron (B)
0.006 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 14:51
DMFRANC
Calcium (Ca)
4.30
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 14:51
DMFRANC
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:51
DMFRANC
Iron (Fe)
0.389
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 14:51
DMFRANC
Magnesium (Mg)
3.84
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 14:51
DMFRANC
Manganese (Mn)
0.031
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 14:51
DMFRANC
Potassium (K)
2.44
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 14:51
DMFRANC
Sodium (Na)
2.94
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 14:51
DMFRANC
Zinc (Zn)
0.007
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 14:51
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.311 J
ug/L
1
0.104
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Chromium (Cr)
2.56
ug/L
1
0.185
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Cobalt (Co)
1.69
ug/L
1
0.077
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Lead (Pb)
0.19 J
ug/L
1
0.037
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Nickel (Ni)
3.46
ug/L
1
0.256
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Thallium (TI) Low Level
0.089 J
ug/L
0.2
0.041
1
SW 6020B
10/26/2021 13:50
CWSPEN3
Vanadium (V) Low Level
0.763
ug/L
0.3
0.114
1
SW 6020B
10/26/2021 13:50
CWSPEN3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 15 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-10
Sample #: 2021025398
Collection Date: 10/14/2021
01:10 PM
Loc code: CLS CCPMW-10
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
3.59 J
mg/L
5
1.7
1
SM 2320B
10/18/2021 14:48
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.9
mg/L
0.1
0.0154
1
EPA 9056A
10/15/2021 21:00
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/15/2021 21:00
GHUTCHI
Nitrate
6.4
mg/L
0.1
0.0209
1
EPA 9056A
10/15/2021 21:00
GHUTCHI
Nitrate as N
1.4
mg-N/L
0.023
0.002
1
EPA 9056A
10/15/2021 21:00
GHUTCHI
Sulfate
0.40
mg/L
0.1
0.0428
1
EPA 9056A
10/15/2021 21:00
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:17
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.045
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:04
DMFRANC
Boron (B)
0.007 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:04
DMFRANC
Calcium (Ca)
1.52
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:04
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:04
DMFRANC
Iron (Fe)
0.048
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:04
DMFRANC
Magnesium (Mg)
1.59
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:04
DMFRANC
Manganese (Mn)
0.015
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:04
DMFRANC
Potassium (K)
1.48
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:04
DMFRANC
Sodium (Na)
2.14
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:04
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:04
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Chromium (Cr)
1.06
ug/L
1
0.185
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Cobalt (Co)
0.915 J
ug/L
1
0.077
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Nickel (Ni)
0.496 J
ug/L
1
0.256
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Silver (Ag)
0.1 J
ug/L
1
0.035
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Thallium (TI) Low Level
0.108 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 18:15
CWSPEN3
Vanadium (V) Low Level
0.17 J
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 18:15
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 16 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPMW-11
Sample #: 2021025399
Collection Date: 10/14/2021 12:00 PM
Loc code: CLS CCPMW-11
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
8.21
mg/L
5
1.7
1
SM 2320B
10/18/2021 14:54
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.8
mg/L
0.1
0.0154
1
EPA 9056A
10/15/2021 21:21
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/15/2021 21:21
GHUTCHI
Nitrate
8.1
mg/L
0.1
0.0209
1
EPA 9056A
10/15/2021 21:21
GHUTCHI
Nitrate as N
1.8
mg-N/L
0.023
0.002
1
EPA 9056A
10/15/2021 21:21
GHUTCHI
Sulfate
1.1
mg/L
0.1
0.0428
1
EPA 9056A
10/15/2021 21:21
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:19
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.045
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:08
DMFRANC
Boron (B)
0.007 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:08
DMFRANC
Calcium (Ca)
2.43
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:08
DMFRANC
Copper (Cu)
0.007
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:08
DMFRANC
Iron (Fe)
0.220
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:08
DMFRANC
Magnesium (Mg)
1.43
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:08
DMFRANC
Manganese (Mn)
0.038
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:08
DMFRANC
Potassium (K)
4.07
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:08
DMFRANC
Sodium (Na)
3.22
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:08
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:08
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Chromium (Cr)
0.673 J
ug/L
1
0.185
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Cobalt (Co)
0.925 J
ug/L
1
0.077
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Lead (Pb)
0.281 J
ug/L
1
0.037
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Nickel (Ni)
1.16
ug/L
1
0.256
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Thallium (TI) Low Level
0.161 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 19:03
CWSPEN3
Vanadium (V) Low Level
0.428
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 19:03
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPTW-2
Collection Date: 10/14/2021 01:10 PM Loc code: CLS CCPTW-2
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q21100239
Alkalinity (mg/L CaCO3) 4.88 J mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride 8.7
mg/L
0.1
0.0154 1
Fluoride 0.0479 U
mg/L
0.1
0.0479 1
Nitrate 9.1
mg/L
0.1
0.0209 1
Nitrate as N 2.1
mg-N/L
0.023
0.002 1
Sulfate 10
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg) 0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Sample #: 2021025400
Matrix: GW RCRA
Page 17 of 82
Method Analysis Date/Time Analyst
SM 2320B 10/18/2021 15:00 EBATIAN
EPA
9056A
10/15/2021
22:02
GHUTCHI
EPA
9056A
10/15/2021
22:02
GHUTCHI
EPA
9056A
10/15/2021
22:02
GHUTCHI
EPA
9056A
10/15/2021
22:02
GHUTCHI
EPA
9056A
10/15/2021
22:02
GHUTCHI
EPA
7470A
10/21/2021
13:22
JAA5429
Barium (Ba)
0.037
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:13
DMFRANC
Boron (B)
0.012 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:13
DMFRANC
Calcium (Ca)
5.20
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:13
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:13
DMFRANC
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:13
DMFRANC
Magnesium (Mg)
3.51
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:13
DMFRANC
Manganese (Mn)
0.007
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:13
DMFRANC
Potassium (K)
1.67
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:13
DMFRANC
Sodium (Na)
2.29
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:13
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:13
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Chromium (Cr)
1.53
ug/L
1
0.185
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Cobalt (Co)
0.485 J
ug/L
1
0.077
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Nickel (Ni)
0.404 J
ug/L
1
0.256
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Selenium (Se)
0.247 J
ug/L
1
0.193
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Thallium (TI) Low Level
0.112 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 19:12
CWSPEN3
Vanadium (V) Low Level
0.115 J
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 19:12
CWSPEN3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 18 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCP-Leachate
Sample #: 2021025401
Collection Date: 10/14/2021 09:35 AM
Loc code: CLS CCP-Leachate
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
1.7 U
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:06
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
15000
mg/L
200
0.0154
2000
EPA 9056A
10/15/2021 22:43
GHUTCHI
Fluoride
0.0479 U
mg/L
20
0.0479
200
EPA 9056A
10/15/2021 22:43
GHUTCHI
Nitrate
18 J
mg/L
20
0.0209
200
EPA 9056A
10/15/2021 22:43
GHUTCHI
Nitrate as N
4.0
mg-N/L
0.023
0.002
1
EPA 9056A
10/15/2021 22:43
GHUTCHI
Sulfate
980
mg/L
20
0.0428
200
EPA 9056A
10/15/2021 22:43
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:24
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.457
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:17
DMFRANC
Boron (B)
8.76
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:17
DMFRANC
Calcium (Ca)
7870
mg/L
5
0.012
100
SW 6010D
10/19/2021 15:17
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:17
DMFRANC
Iron (Fe)
1.45
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:17
DMFRANC
Magnesium (Mg)
50.4
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:17
DMFRANC
Manganese (Mn)
12.5
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:17
DMFRANC
Potassium (K)
655
mg/L
5
0.031
50
SW 6010D
10/19/2021 15:17
DMFRANC
Sodium (Na)
405
mg/L
2.5
0.017
50
SW 6010D
10/19/2021 15:17
DMFRANC
Zinc (Zn)
0.147
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:17
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.363 J
ug/L
1
0.104
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Arsenic (As)
9.33
ug/L
1
0.111
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Beryllium (Be)
0.456 J
ug/L
1
0.249
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Cadmium (Cd)
1.96
ug/L
1
0.032
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Chromium (Cr)
1.43
ug/L
1
0.185
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Cobalt (Co)
580
ug/L
20
0.077
20
SW 6020B
10/26/2021 13:59
CWSPEN3
Lead (Pb)
152
ug/L
1
0.037
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Nickel (Ni)
104
ug/L
1
0.256
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Selenium (Se)
92.6
ug/L
1
0.193
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Silver (Ag)
0.197 J
ug/L
1
0.035
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Thallium (TI) Low Level
9.24
ug/L
0.2
0.041
1
SW 6020B
10/26/2021 13:59
CWSPEN3
Vanadium (V) Low Level
1.18
ug/L
0.3
0.114
1
SW 6020B
10/26/2021 13:59
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 19 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPSW-1
Sample #:
2021025402
Collection Date: 10/14/2021
09:20 AM
Loc code: CLS CCPSW-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
12.0
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:13
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.0
mg/L
0.1
0.0154
1
EPA 9056A
10/15/2021 23:04
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/15/2021 23:04
GHUTCHI
Nitrate
2.0
mg/L
0.1
0.0209
1
EPA 9056A
10/15/2021 23:04
GHUTCHI
Nitrate as N
0.44
mg-N/L
0.023
0.002
1
EPA 9056A
10/15/2021 23:04
GHUTCHI
Sulfate
0.99
mg/L
0.1
0.0428
1
EPA 9056A
10/15/2021 23:04
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:26
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q21100260
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/20/2021 17:11
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.021
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:30
DMFRANC
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:30
DMFRANC
Calcium (Ca)
2.70
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:30
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:30
DMFRANC
Iron (Fe)
1.16
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:30
DMFRANC
Magnesium (Mg)
1.37
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:30
DMFRANC
Manganese (Mn)
0.035
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:30
DMFRANC
Potassium (K)
2.07
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:30
DMFRANC
Sodium (Na)
2.75
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:30
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:30
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q21100265
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/26/2021 00:13
CWSPEN3
Chromium (Cr)
0.373 J
ug/L
1
0.185
1
SW 6020B
10/26/2021 00:13
CWSPEN3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/26/2021 00:13
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/26/2021 00:13
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/26/2021 00:13
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/26/2021 00:13
CWSPEN3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPSW-1
Collection Date: 10/14/2021 09:20 AM Loc code: CLS CCPSW-1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.243 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.403 J
ug/L
1
0.185
1
Cobalt (Co)
0.211 J
ug/L
1
0.077
1
Lead (Pb)
0.097 J
ug/L
1
0.037
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.057 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.325
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Sample #: 2021025402
Matrix: GW RCRA
Page 20 of 82
Method
Analysis Date/Time
Analyst
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
SW 6020B
10/25/2021 19:59
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 21 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPSW-2
Sample #:
2021025403
Collection Date: 10/14/2021
09:10 AM
Loc code: CLS CCPSW-2
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
12.6
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:19
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.1
mg/L
0.1
0.0154
1
EPA 9056A
10/15/2021 23:25
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/15/2021 23:25
GHUTCHI
Nitrate
1.9
mg/L
0.1
0.0209
1
EPA 9056A
10/15/2021 23:25
GHUTCHI
Nitrate as N
0.43
mg-N/L
0.023
0.002
1
EPA 9056A
10/15/2021 23:25
GHUTCHI
Sulfate
1.5
mg/L
0.1
0.0428
1
EPA 9056A
10/15/2021 23:25
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:28
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q21100260
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/20/2021 17:24
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.022
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:34
DMFRANC
Boron (B)
0.007 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:34
DMFRANC
Calcium (Ca)
2.86
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:34
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:34
DMFRANC
Iron (Fe)
1.07
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:34
DMFRANC
Magnesium (Mg)
1.41
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:34
DMFRANC
Manganese (Mn)
0.034
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:34
DMFRANC
Potassium (K)
2.01
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:34
DMFRANC
Sodium (Na)
2.72
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:34
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:34
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q21100265
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 23:45
CWSPEN3
Chromium (Cr)
0.38 J
ug/L
1
0.185
1
SW 6020B
10/25/2021 23:45
CWSPEN3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/25/2021 23:45
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/25/2021 23:45
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/25/2021 23:45
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 23:45
CWSPEN3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPSW-2
Collection Date: 10/14/2021 09:10 AM Loc code: CLS CCPSW-2
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.211 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.405 J
ug/L
1
0.185
1
Cobalt (Co)
0.2 J
ug/L
1
0.077
1
Lead (Pb)
0.103 J
ug/L
1
0.037
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.044 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.400
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Sample #: 2021025403
Matrix: GW RCRA
Page 22 of 82
Method
Analysis Date/Time
Analyst
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
SW 6020B
10/25/2021
20:09
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 23 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPSW-3
Sample #:
2021025404
Collection Date: 10/14/2021
10:15 AM
Loc code: CLS CCPSW-3
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
11.7
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:26
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
5.4
mg/L
0.1
0.0154
1
EPA 9056A
10/16/2021 02:09
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/16/2021 02:09
GHUTCHI
Nitrate
0.07 J
mg/L
0.1
0.0209
1
EPA 9056A
10/16/2021 02:09
GHUTCHI
Nitrate as N
0.02 J
mg-N/L
0.023
0.002
1
EPA 9056A
10/16/2021 02:09
GHUTCHI
Sulfate
1.7
mg/L
0.1
0.0428
1
EPA 9056A
10/16/2021 02:09
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:31
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q21100260
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/20/2021 17:37
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.019
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:38
DMFRANC
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:38
DMFRANC
Calcium (Ca)
3.17
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:38
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:38
DMFRANC
Iron (Fe)
0.623
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:38
DMFRANC
Magnesium (Mg)
1.76
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:38
DMFRANC
Manganese (Mn)
0.026
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:38
DMFRANC
Potassium (K)
1.61
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:38
DMFRANC
Sodium (Na)
2.21
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:38
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:38
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q21100265
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/26/2021 00:22
CWSPEN3
Chromium (Cr)
0.415 J
ug/L
1
0.185
1
SW 6020B
10/26/2021 00:22
CWSPEN3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/26/2021 00:22
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/26/2021 00:22
CWSPEN3
Nickel (Ni)
0.322 J
ug/L
1
0.256
1
SW 6020B
10/26/2021 00:22
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/26/2021 00:22
CWSPEN3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCPSW-3
Collection Date: 10/14/2021 10:15 AM Loc code: CLS CCPSW-3
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.193 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.44 J
ug/L
1
0.185
1
Cobalt (Co)
0.669 J
ug/L
1
0.077
1
Lead (Pb)
0.116 J
ug/L
1
0.037
1
Nickel (Ni)
0.339 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.064 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.372
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Sample #: 2021025404
Matrix: GW RCRA
Page 24 of 82
Method
Analysis Date/Time
Analyst
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
SW 6020B
10/25/2021
20:18
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 25 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS_FD-20211014-1 Duplicate
Sample #: 2021025405
Collection Date: 10/14/2021
Loc code:
CLS
FD
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
6.92
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:32
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
4.3
mg/L
0.1
0.0154
1
EPA 9056A
10/16/2021 00:06
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/16/2021 00:06
GHUTCHI
Nitrate
4.5
mg/L
0.1
0.0209
1
EPA 9056A
10/16/2021 00:06
GHUTCHI
Nitrate as N
1.0
mg-N/L
0.023
0.002
1
EPA 9056A
10/16/2021 00:06
GHUTCHI
Sulfate
7.0
mg/L
0.1
0.0428
1
EPA 9056A
10/16/2021 00:06
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.03 J
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:33
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.032
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:43
DMFRANC
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:43
DMFRANC
Calcium (Ca)
3.15
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:43
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:43
DMFRANC
Iron (Fe)
0.096
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:43
DMFRANC
Magnesium (Mg)
2.18
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:43
DMFRANC
Manganese (Mn)
0.038
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:43
DMFRANC
Potassium (K)
2.04
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:43
DMFRANC
Sodium (Na)
1.72
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:43
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:43
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Chromium (Cr)
3.88
ug/L
1
0.185
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Cobalt (Co)
0.483 J
ug/L
1
0.077
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Lead (Pb)
0.045 J
ug/L
1
0.037
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Nickel (Ni)
1.71
ug/L
1
0.256
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Selenium (Se)
0.625 J
ug/L
1
0.193
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Thallium (TI) Low Level
0.058 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 20:27
CWSPEN3
Vanadium (V) Low Level
0.371
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 20:27
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 26 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS FB-20211014-0940 Field Blank
Sample #:
2021025406
Collection Date: 10/14/2021 09:40 AM
Loc code: CLS QA
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
1.7 U
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:38
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
0.02 J
mg/L
0.1
0.0154
1
EPA 9056A
10/16/2021 00:26
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/16/2021 00:26
GHUTCHI
Nitrate
0.04 J
mg/L
0.1
0.0209
1
EPA 9056A
10/16/2021 00:26
GHUTCHI
Nitrate as N
0.01 J
mg-N/L
0.023
0.002
1
EPA 9056A
10/16/2021 00:26
GHUTCHI
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
10/16/2021 00:26
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:35
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q21100260
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/20/2021 17:41
DMFRANC
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:47
DMFRANC
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:47
DMFRANC
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 6010D
10/19/2021 15:47
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:47
DMFRANC
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:47
DMFRANC
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:47
DMFRANC
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:47
DMFRANC
Potassium (K)
0.033 J
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:47
DMFRANC
Sodium (Na)
0.026 J
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:47
DMFRANC
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:47
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q21100265
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/26/2021 00:32
CWSPEN3
Chromium (Cr)
0.228 J
ug/L
1
0.185
1
SW 6020B
10/26/2021 00:32
CWSPEN3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/26/2021 00:32
CWSPEN3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/26/2021 00:32
CWSPEN3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/26/2021 00:32
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/26/2021 00:32
CWSPEN3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS FB-20211014-0940 Field Blank
Collection Date: 10/14/2021 09:40 AM Loc code: CLS QA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Silver (Ag)
0.035 U
ug/L
1
0.035
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
Sample #: 2021025406
Matrix: GW RCRA
Page 27 of 82
Method
Analysis Date/Time
Analyst
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3
SW 6020B
10/25/2021
20:37
CWSPEN3

Certificate of Laboratory Analysis Page 28 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Site: CLS CCP-LEACHATE-34
Sample #: 2021027486
Collection Date: 10/14/2021 10:55 AM
Loc code:
CLS CCP-LEACHATE-34
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q21100239
Alkalinity (mg/L CaCO3)
187
mg/L
5
1.7
1
SM 2320B
10/18/2021 15:44
EBATIAN
(CaCO3)
INORGANIC IONS BY IC - Q21100218
Chloride
48
mg/L
2
0.0154
20
EPA 9056A
10/16/2021 08:34
GHUTCHI
Fluoride
0.0479 U
mg/L
2
0.0479
20
EPA 9056A
10/16/2021 08:34
GHUTCHI
Nitrate
12
mg/L
2
0.0209
20
EPA 9056A
10/16/2021 08:34
GHUTCHI
Nitrate as N
2.6
mg-N/L
0.023
0.002
1
EPA 9056A
10/16/2021 08:34
GHUTCHI
Sulfate
960
mg/L
20
0.0428
200
EPA 9056A
10/16/2021 08:34
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q21100281
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/21/2021 13:49
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q21100241
Barium (Ba)
0.098
mg/L
0.005
0.002
1
SW 6010D
10/19/2021 15:52
DMFRANC
Boron (B)
0.922
mg/L
0.05
0.005
1
SW 6010D
10/19/2021 15:52
DMFRANC
Calcium (Ca)
356
mg/L
1
0.012
20
SW 6010D
10/19/2021 15:52
DMFRANC
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:52
DMFRANC
Iron (Fe)
0.042
mg/L
0.01
0.004
1
SW 6010D
10/19/2021 15:52
DMFRANC
Magnesium (Mg)
59.1
mg/L
0.02
0.008
1
SW 6010D
10/19/2021 15:52
DMFRANC
Manganese (Mn)
0.662
mg/L
0.005
0.001
1
SW 6010D
10/19/2021 15:52
DMFRANC
Potassium (K)
19.3
mg/L
0.1
0.031
1
SW 6010D
10/19/2021 15:52
DMFRANC
Sodium (Na)
9.18
mg/L
0.05
0.017
1
SW 6010D
10/19/2021 15:52
DMFRANC
Zinc (Zn)
0.005
mg/L
0.005
0.004
1
SW 6010D
10/19/2021 15:52
DMFRANC
TOTAL RECOVERABLE METALS BY ICP-MS - Q21100245
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Arsenic (As)
0.164 J
ug/L
1
0.111
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Cadmium (Cd)
0.393 J
ug/L
1
0.032
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Chromium (Cr)
0.252 J
ug/L
1
0.185
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Cobalt (Co)
2.13
ug/L
1
0.077
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Lead (Pb)
0.08 J
ug/L
1
0.037
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Nickel (Ni)
26.1
ug/L
1
0.256
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Selenium (Se)
3.18
ug/L
1
0.193
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Thallium (TI) Low Level
0.184 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2021 20:46
CWSPEN3
Vanadium (V) Low Level
0.559
ug/L
0.3
0.114
1
SW 6020B
10/25/2021 20:46
CWSPEN3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 29 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Page 30 of 82
Level II QC Summary
Q21100235 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1 Parent Sample: J21090196 -- 2021025386
Parameter Measured Final Units Dil MDL RPD Qualifier
Alkalinity (mg/L CaCO3) 0 mg/L 1 1.7 200 R
(CaCO3)
LCS # 1
Parameter Measured Final Units Dil MDL S ike % Recovery LCL UCL
Alkalinity (mg/L CaCO3) 120 mg/L 1 1.7 124 96.4 85 115
(CaCO3)
Qualifiers:
R % RPD indeterminate due to low concentration in the parent sample.
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Page 31 of 82
Level II QC Summary
Q21100239 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1 Parent Sample: J21090196 -- 2021025397
Parameter Measured Final Units Dil MDL RPD Qualifier
Alkalinity (mg/L CaCO3) 2.13 mg/L 1 1.7 2.32
(CaCO3)
LCS # 1
Parameter Measured Final Units Dil MDL S ike % Recovery LCL UCL
Alkalinity (mg/L CaCO3) 120 mg/L 1 1.7 124 96.9 85 115
(CaCO3)
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100218 Dionex INORGANIC IONS BY IC
Blank # 1
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Page 32 of 82
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
5.01
5.01
mg/L
1
0.0154
5
100
90
110
Fluoride
4.88
4.88
mg/L
1
0.0479
5
97.6
90
110
Nitrate
4.95
4.95
mg/L
1
0.0209
5
98.9
90
110
Sulfate
5.45
5.45
mg/L
1
0.0428
5
109
90
110
Parent Sample:
J21090196 -- 2021025386
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Chloride
6.16
6.16
mg/L
1
0.0154
2
101
80
120
Fluoride
2.06
2.06
mg/L
1
0.0479
2
103
80
120
Nitrate
2.21
2.21
mg/L
1
0.0209
2
102
80
120
Sulfate
2.34
2.34
mg/L
1
0.0428
2
108
80
120
Parent Sample:
J21090196 -- 2021025386
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Chloride
6.19
6.19
mg/L
1
0.0154
2
102
80
120
1.48
Fluoride
2.09
2.09
mg/L
1
0.0479
2
104
80
120
1.5
Nitrate
2.24
2.24
mg/L
1
0.0209
2
104
80
120
1.56
Sulfate
2.37
2.37
mg/L
1
0.0428
2
110
80
120
1.47
Parent Sample:
J21090196 -- 2021025404
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
7.36
7.36
mg/L
1
0.0154
2
95.9
80
120
Fluoride
2.08
2.08
mg/L
1
0.0479
2
103
80
120
Nitrate
2.1
2.1
mg/L
1
0.0209
2
102
80
120
Sulfate
3.82
3.82
mg/L
1
0.0428
2
105
80
120
Parent Sample:
J21090196 -- 2021025404
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Chloride
7.39
7.39
mg/L
1
0.0154
2
97.2
80
120
1.35
Fluoride
2.11
2.11
mg/L
1
0.0479
2
105
80
120
1.44
Nitrate
2.17
2.17
mg/L
1
0.0209
2
105
80
120
3.09
Sulfate
3.85
3.85
mg/L
1
0.0428
2
106
80
120
1.42
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 33 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100281 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.013
-0.013
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.013
-0.013
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.012
-0.012
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.012
-0.012
ug/L
1
0.01
0.05
< MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.012
-0.012
ug/L
1
0.01
0.05
< MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.011
-0.011
ug/L
1
0.01
0.05
< MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.012
-0.012
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.96
1.96
ug/L
1
0.01
2
98.2 85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.99
1.99
ug/L
1
0.01
2
99.7 85
115
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
2.01
2.01
ug/L
1
0.01
2
100 85
115
MS # 1
Parent Sample: J21090196 -- 2021025386
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.08
1.08
ug/L
1
0.01
1
107 75
125

Certificate of Laboratory Analysis Page 34 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100281 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 1
Parent Sample:
J21090196 -- 2021025386
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
101
75 125 5.38
MS # 2
Parent Sample:
J21090196 -- 2021025397
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.12
1.12
ug/L
1
0.01
1
111
75 125
MSD # 2
Parent Sample:
J21090196 -- 2021025397
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.14
1.14
ug/L
1
0.01
1
113
75 125 2.41
MS # 3
Parent Sample:
J21090196 -- 2021027486
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
103
75 125
MSD # 3
Parent Sample:
J21090196 -- 2021027486
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
103
75 125 0.68
MS # 4
Parent Sample:
J21100251 -- 2021028268
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.869
0.869
ug/L
1
0.01
1
85.4
75 125
MSD # 4
Parent Sample:
J21100251 -- 2021028268
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.862
0.862
ug/L
1
0.01
1
84.7
75 125 0.823
MS # 5
Parent Sample:
J21100294 -- 2021028410
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.08
1.08
ug/L
1
0.01
1
105
75 125
MSD # 5
Parent Sample:
J21100294 -- 2021028410
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.07
1.07
ug/L
1
0.01
1
104
75 125 1.53
MS # 6
Parent Sample:
J21100294 -- 2021028420
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
104
75 125
MSD # 6
Parent Sample:
J21100294 -- 2021028420
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.11
1.11
ug/L
1
0.01
1
109
75 125 5.27

Certificate of Laboratory Analysis Page 35 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100260 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
-0.000487
-0.000487
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.16
5.16
mg/L
1
0.004
5
103
80
120
MS # 1
Parent Sample:
J21090196 -- 2021025402
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.18
5.18
mg/L
1
0.004
5
104
70
130
MSD # 1
Parent Sample:
J21090196 -- 2021025402
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.18
5.18
mg/L
1
0.004
5
104
70
130 0
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 36 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100240 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000307
-0.000307
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000662
0.000662
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
-0.000874
-0.000874
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
-0.000127
-0.000127
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.000342
0.000342
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
-0.000854
-0.000854
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000263
-0.000263
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.00975
-0.00975
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.0167
0.0167
mg/L
1
0.017
0.05
< MDL
Zinc (Zn)
0.000293
0.000293
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
4.98
4.98
mg/L
1
0.002
5
99.6
80
120
Boron (B)
4.86
4.86
mg/L
1
0.005
5
97.2
80
120
Calcium (Ca)
5.01
5.01
mg/L
1
0.012
5
100
80
120
Copper (Cu)
4.87
4.87
mg/L
1
0.001
5
97.4
80
120
Iron (Fe)
5.01
5.01
mg/L
1
0.004
5
100
80
120
Magnesium (Mg)
4.96
4.96
mg/L
1
0.008
5
99.3
80
120
Manganese (Mn)
5.01
5.01
mg/L
1
0.001
5
100
80
120
Potassium (K)
4.84
4.84
mg/L
1
0.031
5
96.8
80
120
Sodium (Na)
4.87
4.87
mg/L
1
0.017
5
97.4
80
120
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J21090196
-- 2021025386
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
5.03
5.03
mg/L
1
0.002
5
100
75
125
Boron (B)
4.88
4.88
mg/L
1
0.005
5
97.4
75
125
Calcium (Ca)
5.17
5.17
mg/L
1
0.012
5
100
75
125
Copper (Cu)
4.87
4.87
mg/L
1
0.001
5
97.5
75
125
Iron (Fe)
5.07
5.07
mg/L
1
0.004
5
100
75
125
Magnesium (Mg)
5.79
5.79
mg/L
1
0.008
5
99.9
75
125
Manganese (Mn)
5.04
5.04
mg/L
1
0.001
5
101
75
125
Potassium (K)
5.72
5.72
mg/L
1
0.031
5
97.9
75
125
Sodium (Na)
6.29
6.29
mg/L
1
0.017
5
97.3
75
125
Zinc (Zn)
5.07
5.07
mg/L
1
0.004
5
101
75
125
MSD # 1
Parent Sample:
J21090196
-- 2021025386
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
5.06
5.06
mg/L
1
0.002
5
101
75
125 0.555
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 37 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100240 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Boron (B)
4.91
4.91
mg/L
1
0.005
Calcium (Ca)
5.2
5.2
mg/L
1
0.012
Copper (Cu)
4.89
4.89
mg/L
1
0.001
Iron (Fe)
5.09
5.09
mg/L
1
0.004
Magnesium (Mg)
5.79
5.79
mg/L
1
0.008
Manganese (Mn)
5.07
5.07
mg/L
1
0.001
Potassium (K)
5.71
5.71
mg/L
1
0.031
Sodium (Na)
6.3
6.3
mg/L
1
0.017
Zinc (Zn)
5.09
5.09
mg/L
1
0.004
Parent Sample:
J21090196 -- 2021025386
Spike
% Recovery
LCL
UCL
RPD
5
98
75
125
0.552
5
101
75
125
0.424
5
97.8
75
125
0.307
5
101
75
125
0.551
5
99.8
75
125
0.0173
5
101
75
125
0.455
5
97.6
75
125
0.262
5
97.6
75
125
0.238
5
102
75
125
0.492
Qualifier

Certificate of Laboratory Analysis Page 38 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100241 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000315
-0.000315
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000954
0.000954
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
-0.000805
-0.000805
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000775
0.000775
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00339
0.00339
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
-0.00213
-0.00213
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
-0.000252
-0.000252
mg/L
1
0.001
0.005
< MDL
Potassium (K)
0.000194
0.000194
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.0105
0.0105
mg/L
1
0.017
0.05
< MDL
Zinc (Zn)
-0.0006
-0.0006
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
4.97
4.97
mg/L
1
0.002
5
99.4
80
120
Boron (B)
4.87
4.87
mg/L
1
0.005
5
97.5
80
120
Calcium (Ca)
5.03
5.03
mg/L
1
0.012
5
101
80
120
Copper (Cu)
4.87
4.87
mg/L
1
0.001
5
97.4
80
120
Iron (Fe)
5.03
5.03
mg/L
1
0.004
5
101
80
120
Magnesium (Mg)
5.01
5.01
mg/L
1
0.008
5
100
80
120
Manganese (Mn)
5.02
5.02
mg/L
1
0.001
5
100
80
120
Potassium (K)
4.89
4.89
mg/L
1
0.031
5
97.8
80
120
Sodium (Na)
4.86
4.86
mg/L
1
0.017
5
97.1
80
120
Zinc (Zn)
5.12
5.12
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J21090196
-- 2021025397
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
5.08
5.08
mg/L
1
0.002
5
100
75
125
Boron (B)
4.9
4.9
mg/L
1
0.005
5
97.9
75
125
Calcium (Ca)
9.35
9.35
mg/L
1
0.012
5
101
75
125
Copper (Cu)
4.85
4.85
mg/L
1
0.001
5
97
75
125
Iron (Fe)
5.41
5.41
mg/L
1
0.004
5
100
75
125
Magnesium (Mg)
8.84
8.84
mg/L
1
0.008
5
99.9
75
125
Manganese (Mn)
5.08
5.08
mg/L
1
0.001
5
101
75
125
Potassium (K)
7.29
7.29
mg/L
1
0.031
5
97.1
75
125
Sodium (Na)
7.79
7.79
mg/L
1
0.017
5
96.9
75
125
Zinc (Zn)
5.11
5.11
mg/L
1
0.004
5
102
75
125
MSD # 1
Parent Sample:
J21090196
-- 2021025397
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
5.08
5.08
mg/L
1
0.002
5
100
75
125 0.157
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 39 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100241 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Boron (B)
4.9
4.9
mg/L
1
0.005
Calcium (Ca)
9.38
9.38
mg/L
1
0.012
Copper (Cu)
4.86
4.86
mg/L
1
0.001
Iron (Fe)
5.43
5.43
mg/L
1
0.004
Magnesium (Mg)
8.88
8.88
mg/L
1
0.008
Manganese (Mn)
5.08
5.08
mg/L
1
0.001
Potassium (K)
7.35
7.35
mg/L
1
0.031
Sodium (Na)
7.81
7.81
mg/L
1
0.017
Zinc (Zn)
5.13
5.13
mg/L
1
0.004
Parent Sample:
J21090196 -- 2021025397
Spike
% Recovery
LCL
UCL
RPD
5
97.9
75
125
0.0204
5
102
75
125
0.374
5
97.2
75
125
0.185
5
101
75
125
0.461
5
101
75
125
0.519
5
101
75
125
0.0197
5
98.3
75
125
0.819
5
97.4
75
125
0.32
5
102
75
125
0.293
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100265 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Page 40 of 82
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Cadmium (Cd)
0.002
0.002
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.032
0.032
ug/L
1
0.185
1
< MDL
Copper (Cu)
-0.003
-0.003
ug/L
1
0.787
1
< MDL
Lead (Pb)
-0.041
-0.041
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.077
-0.077
ug/L
1
0.256
1
< MDL
Silver (Ag)
0.006
0.006
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Cadmium (Cd)
49.5
49.5
ug/L
1
0.032
50
99
80
120
Chromium (Cr)
51.1
51.1
ug/L
1
0.185
50
102
80
120
Copper (Cu)
48.6
48.6
ug/L
1
0.787
50
97.1
80
120
Lead (Pb)
51
51
ug/L
1
0.037
50
102
80
120
Nickel (Ni)
48.2
48.2
ug/L
1
0.256
50
96.3
80
120
Silver (Ag)
49.3
49.3
ug/L
1
0.035
50
98.5
80
120
Parent Sample:
J21090196 -- 2021025403
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Cadmium (Cd)
50
50
ug/L
1
0.032
50
100
75
125
Chromium (Cr)
51.3
51.3
ug/L
1
0.185
50
102
75
125
Copper (Cu)
48.4
48.4
ug/L
1
0.787
50
96.3
75
125
Lead (Pb)
50.7
50.7
ug/L
1
0.037
50
101
75
125
Nickel (Ni)
47.9
47.9
ug/L
1
0.256
50
95.7
75
125
Silver (Ag)
49.3
49.3
ug/L
1
0.035
50
98.7
75
125
Parent Sample:
J21090196 -- 2021025403
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Cadmium (Cd)
49.5
49.5
ug/L
1
0.032
50
99
75
125
1.07
Chromium (Cr)
51.5
51.5
ug/L
1
0.185
50
102
75
125
0.414
Copper (Cu)
48.5
48.5
ug/L
1
0.787
50
96.5
75
125
0.201
Lead (Pb)
51.1
51.1
ug/L
1
0.037
50
102
75
125
0.766
Nickel (Ni)
48
48
ug/L
1
0.256
50
95.8
75
125
0.104
Silver (Ag)
49.3
49.3
ug/L
1
0.035
50
98.6
75
125
0.0628
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 41 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100244 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.021
-0.021
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.011
-0.011
ug/L
1
0.111
1
< MDL
Beryllium (Be)
-0.011
-0.011
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0
0
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.044
0.044
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0
0
ug/L
1
0.077
1
< MDL
Lead (Pb)
-0.005
-0.005
ug/L
1
0.037
1
< MDL
Nickel (Ni)
0
0
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.052
-0.052
ug/L
1
0.193
1
< MDL
Silver (Ag)
0
0
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.016
0.016
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.067
0.067
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
49.5
49.5
ug/L
1
0.104
50
98.9
80
120
Arsenic (As)
49.1
49.1
ug/L
1
0.111
50
98.2
80
120
Beryllium (Be)
47.8
47.8
ug/L
1
0.249
50
95.7
80
120
Cadmium (Cd)
50.5
50.5
ug/L
1
0.032
50
101
80
120
Chromium (Cr)
50
50
ug/L
1
0.185
50
100
80
120
Cobalt (Co)
48.4
48.4
ug/L
1
0.077
50
96.8
80
120
Lead (Pb)
50.4
50.4
ug/L
1
0.037
50
101
80
120
Nickel (Ni)
49.4
49.4
ug/L
1
0.256
50
98.9
80
120
Selenium (Se)
49
49
ug/L
1
0.193
50
98
80
120
Silver (Ag)
49.4
49.4
ug/L
1
0.035
50
98.8
80
120
Thallium (TI) Low Level
47.2
47.2
ug/L
1
0.041
50
94.4
80
120
Vanadium (V) Low Level
49.5
49.5
ug/L
1
0.114
50
98.9
80
120
MS # 1
Parent Sample:
J21090196 -- 2021025387
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
51
51
ug/L
1
0.104
50
102
75
125
Arsenic (As)
49.4
49.4
ug/L
1
0.111
50
98.6
75
125
Beryllium (Be)
48.1
48.1
ug/L
1
0.249
50
96.2
75
125
Cadmium (Cd)
51.4
51.4
ug/L
1
0.032
50
103
75
125
Chromium (Cr)
51.5
51.5
ug/L
1
0.185
50
102
75
125
Cobalt (Co)
49.2
49.2
ug/L
1
0.077
50
97.6
75
125
Lead (Pb)
51.2
51.2
ug/L
1
0.037
50
102
75
125
Nickel (Ni)
51.3
51.3
ug/L
1
0.256
50
100
75
125
Selenium (Se)
47.7
47.7
ug/L
1
0.193
50
95.5
75
125
Silver (Ag)
49.8
49.8
ug/L
1
0.035
50
99.6
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 42 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100244 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter Measured Final Units
Thallium (TI) Low Level 46.5 46.5 ug/L
Vanadium (V) Low Level 51.4 51.4 ug/L
MSD # 1
Parameter
Measured
Final
Antimony (Sb)
49
49
Arsenic (As)
47.9
47.9
Beryllium (Be)
46.2
46.2
Cadmium (Cd)
49.1
49.1
Chromium (Cr)
49.4
49.4
Cobalt (Co)
47.6
47.6
Lead (Pb)
49.9
49.9
Nickel (Ni)
49.4
49.4
Selenium (Se)
47.5
47.5
Silver (Ag)
47.8
47.8
Thallium (TI) Low Level
45.2
45.2
Vanadium (V) Low Level
49.8
49.8
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Parent Sample:
J21090196 -- 2021025387
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
92.8
75
125
1
0.114
50
103
75
125
Parent Sample:
J21090196
-- 2021025387
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.104
50
98
75
125
3.86
1
0.111
50
95.7
75
125
2.94
1
0.249
50
92.3
75
125
4.08
1
0.032
50
98.2
75
125
4.47
1
0.185
50
98.3
75
125
4.12
1
0.077
50
94.4
75
125
3.32
1
0.037
50
99.8
75
125
2.5
1
0.256
50
96.6
75
125
3.91
1
0.193
50
95.1
75
125
0.399
1
0.035
50
95.6
75
125
4.05
1
0.041
50
90.2
75
125
2.9
1
0.114
50
99.5
75
125
3.07
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 43 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100245 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.045
0.045
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.003
-0.003
ug/L
1
0.111
1
< MDL
Beryllium (Be)
-0.022
-0.022
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.007
0.007
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.04
0.04
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.001
-0.001
ug/L
1
0.077
1
< MDL
Lead (Pb)
-0.034
-0.034
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.054
-0.054
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.01
-0.01
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.016
0.016
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.053
0.053
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
49.5
49.5
ug/L
1
0.104
50
98.9
80
120
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98.6
80
120
Beryllium (Be)
47.8
47.8
ug/L
1
0.249
50
95.7
80
120
Cadmium (Cd)
49.9
49.9
ug/L
1
0.032
50
99.9
80
120
Chromium (Cr)
50.4
50.4
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
50
50
ug/L
1
0.077
50
100
80
120
Lead (Pb)
50.9
50.9
ug/L
1
0.037
50
102
80
120
Nickel (Ni)
49.8
49.8
ug/L
1
0.256
50
99.6
80
120
Selenium (Se)
47.4
47.4
ug/L
1
0.193
50
94.7
80
120
Silver (Ag)
49.6
49.6
ug/L
1
0.035
50
99.1
80
120
Thallium (TI) Low Level
47.4
47.4
ug/L
1
0.041
50
94.7
80
120
Vanadium (V) Low Level
50.1
50.1
ug/L
1
0.114
50
100
80
120
MS # 1
Parent Sample:
J21090196 -- 2021025398
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.6
49.6
ug/L
1
0.104
50
99
75
125
Arsenic (As)
47.9
47.9
ug/L
1
0.111
50
95.8
75
125
Beryllium (Be)
48.1
48.1
ug/L
1
0.249
50
96
75
125
Cadmium (Cd)
50
50
ug/L
1
0.032
50
100
75
125
Chromium (Cr)
51.9
51.9
ug/L
1
0.185
50
102
75
125
Cobalt (Co)
49.5
49.5
ug/L
1
0.077
50
97.3
75
125
Lead (Pb)
50.6
50.6
ug/L
1
0.037
50
101
75
125
Nickel (Ni)
49.4
49.4
ug/L
1
0.256
50
97.7
75
125
Selenium (Se)
46.7
46.7
ug/L
1
0.193
50
93.4
75
125
Silver (Ag)
49.4
49.4
ug/L
1
0.035
50
98.7
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 44 of 82
This report shall not be reproduced, except in full.
Order # J21090196
Level II QC Summary
Q21100245 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter Measured Final Units
Thallium (TI) Low Level 46.1 46.1 ug/L
Vanadium (V) Low Level 51.6 51.6 ug/L
MSD # 1
Parameter
Measured
Final
Antimony (Sb)
49.8
49.8
Arsenic (As)
47.9
47.9
Beryllium (Be)
48.1
48.1
Cadmium (Cd)
50.2
50.2
Chromium (Cr)
52.2
52.2
Cobalt (Co)
49.9
49.9
Lead (Pb)
51
51
Nickel (Ni)
50.3
50.3
Selenium (Se)
47.1
47.1
Silver (Ag)
49.3
49.3
Thallium (TI) Low Level
46.2
46.2
Vanadium (V) Low Level
51.5
51.5
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Parent Sample:
J21090196 -- 2021025398
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
91.9
75
125
1
0.114
50
103
75
125
Parent Sample:
J21090196
-- 2021025398
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.104
50
99.6
75
125
0.528
1
0.111
50
95.7
75
125
0.111
1
0.249
50
95.9
75
125
0.0667
1
0.032
50
100
75
125
0.453
1
0.185
50
102
75
125
0.437
1
0.077
50
98
75
125
0.764
1
0.037
50
102
75
125
0.675
1
0.256
50
99.6
75
125
1.86
1
0.193
50
94.1
75
125
0.811
1
0.035
50
98.4
75
125
0.29
1
0.041
50
92.1
75
125
0.228
1
0.114
50
103
75
125
0.0467
Qualifier
Qualifier

lceAnalyircal
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October 22, 2021
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J21090196 CLS LF
Pace Project No.: 92567098
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on October 15, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/ 3)
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Project: J21090196 CLS LF
Pace Project No.: 92567098
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J21090196 CLS LF
Pace Project No.: 92567098
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92567098001
CCPMW-1S
Water
10/14/2110:40
10/15/2113:30
92567098002
CCPMW-1D
Water
10/14/2110:25
10/15/2113:30
92567098003
CCPMW-2S
Water
10/14/2111:10
10/15/2113:30
92567098004
CCPMW-2D
Water
10/14/2113:20
10/15/2113:30
92567098005
CCPMW-3D
Water
10/14/2110:15
10/15/2113:30
92567098006
CCPMW-4
Water
10/14/2110:40
10/15/2113:30
92567098007
CCPMW-5
Water
10/14/2113:25
10/15/2113:30
92567098008
CCPMW-6S
Water
10/14/2113:30
10/15/2113:30
92567098009
CCPMW-6D
Water
10/14/2112:25
10/15/2113:30
92567098010
CCPMW-7
Water
10/14/2110:20
10/15/2113:30
92567098011
CCPMW-8
Water
10/14/2111:35
10/15/2113:30
92567098012
CCPMW-10
Water
10/14/2113:10
10/15/2113:30
92567098013
CCPMW-11
Water
10/14/2112:00
10/15/2113:30
92567098014
CCPTW-2
Water
10/14/2113:10
10/15/2113:30
92567098015
CCP-LEACHATE
Water
10/14/2109:35
10/15/2113:30
92567098016
CCP-LEACHATE-34
Water
10/14/2110:55
10/15/2113:30
92567098017
CCPSW-1
Water
10/14/2109:20
10/15/2113:30
92567098018
CCPSW-2
Water
10/14/2109:10
10/15/2113:30
92567098019
CCPSW-3
Water
10/14/2110:15
10/15/2113:30
92567098020
CLS FD-20211014-1
Water
10/14/21 00:00
10/15/21 13:30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J21090196 CLS LF
92567098
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92567098001
CCPMW-1S
SM 2540C-2011
MJP
1
PASI-A
92567098002
CCPMW-1D
SM 2540C-2011
MJP
1
PASI-A
92567098003
CCPMW-2S
SM 2540C-2011
MJP
1
PASI-A
92567098004
CCPMW-2D
SM 2540C-2011
MJP
1
PASI-A
92567098005
CCPMW-3D
SM 2540C-2011
MJP
1
PASI-A
92567098006
CCPMW-4
SM 2540C-2011
MJP
1
PASI-A
92567098007
CCPMW-5
SM 2540C-2011
MJP
1
PASI-A
92567098008
CCPMW-6S
SM 2540C-2011
MJP
1
PASI-A
92567098009
CCPMW-6D
SM 2540C-2011
MJP
1
PASI-A
92567098010
CCPMW-7
SM 2540C-2011
MJP
1
PASI-A
92567098011
CCPMW-8
SM 2540C-2011
MJP
1
PASI-A
92567098012
CCPMW-10
SM 2540C-2011
MJP
1
PASI-A
92567098013
CCPMW-11
SM 2540C-2011
MJP
1
PASI-A
92567098014
CCPTW-2
SM 2540C-2011
MJP
1
PASI-A
92567098015
CCP-LEACHATE
SM 2540C-2011
MJP
1
PASI-A
92567098016
CCP-LEACHATE-34
SM 2540C-2011
MJP
1
PASI-A
92567098017
CCPSW-1
SM 2540C-2011
MJP
1
PASI-A
92567098018
CCPSW-2
SM 2540C-2011
MJP
1
PASI-A
92567098019
CCPSW-3
SM 2540C-2011
MJP
1
PASI-A
92567098020
CLS FD-20211014-1
SM 2540C-2011
MJP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J21090196 CLS LF
92567098
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92567098002
CCPMW-1 D
SM 2540C-2011
Total Dissolved Solids
53.0
mg/L
25.0
10/20/21 12:06
92567098003
CCPMW-2S
SM 2540C-2011
Total Dissolved Solids
48.0
mg/L
25.0
10/20/21 12:06
92567098004
CCPMW-2D
SM 2540C-2011
Total Dissolved Solids
100
mg/L
25.0
10/20/21 12:06
92567098005
CCPMW-3D
SM 2540C-2011
Total Dissolved Solids
65.0
mg/L
25.0
10/20/21 12:06
92567098006
CCPMW-4
SM 2540C-2011
Total Dissolved Solids
125
mg/L
25.0
10/20/21 12:06
92567098007
CCPMW-5
SM 2540C-2011
Total Dissolved Solids
88.0
mg/L
25.0
10/20/21 12:11
92567098008
CCPMW-6S
SM 2540C-2011
Total Dissolved Solids
47.0
mg/L
25.0
10/20/21 12:12
92567098009
CCPMW-6D
SM 2540C-2011
Total Dissolved Solids
43.0
mg/L
25.0
10/20/21 12:12
92567098010
CCPMW-7
SM 2540C-2011
Total Dissolved Solids
66.0
mg/L
25.0
10/20/21 12:12
92567098011
CCPMW-8
SM 2540C-2011
Total Dissolved Solids
70.0
mg/L
25.0
10/20/21 12:12
92567098012
CCPMW-10
SM 2540C-2011
Total Dissolved Solids
41.0
mg/L
25.0
10/20/21 12:12
92567098013
CCPMW-11
SM 2540C-2011
Total Dissolved Solids
48.0
mg/L
25.0
10/20/21 12:12
92567098014
CCPTW-2
SM 2540C-2011
Total Dissolved Solids
65.0
mg/L
25.0
10/20/21 12:12
92567098015
CCP-LEACHATE
SM 2540C-2011
Total Dissolved Solids
37700
mg/L
2500
10/20/21 12:12
92567098016
CCP-LEACHATE-34
SM 2540C-2011
Total Dissolved Solids
1670
mg/L
50.0
10/20/21 12:15
92567098017
CCPSW-1
SM 2540C-2011
Total Dissolved Solids
45.0
mg/L
25.0
10/20/21 12:15
92567098018
CCPSW-2
SM 2540C-2011
Total Dissolved Solids
48.0
mg/L
25.0
10/20/21 12:15
92567098019
CCPSW-3
SM 2540C-2011
Total Dissolved Solids
48.0
mg/L
25.0
10/20/21 12:15
REPORT OF LABORATORY ANALYSIS
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Project: J21090196 CLS LF
Pace Project No.: 92567098
Lab Sample ID
Method
92567098020
SM 2540C-2011
Client Sample ID
Parameters
CLS_FD-20211014-1
Total Dissolved Solids
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
46.0
mg/L
25.0
10/20/2112:15
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J21090196 CLS LF
Pace Project No.: 92567098
Method: SM 2540C-2011
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: October 22, 2021
General Information:
20 samples were analyzed for SM 254OC-2011 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-1S Lab ID: 92567098001 Collected: 10/14/21 10:40 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids ND mg/L 25.0 25.0 1 10/20/21 12:06
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-1D Lab ID: 92567098002 Collected: 10/14/21 10:25 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 53.0 mg/L 25.0 25.0 1 10/20/21 12:06
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-2S Lab ID: 92567098003 Collected: 10/14/21 11:10 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 48.0 mg/L 25.0 25.0 1 10/20/21 12:06
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-2D Lab ID: 92567098004 Collected: 10/14/21 13:20 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 100 mg/L 25.0 25.0 1 10/20/21 12:06
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-3D Lab ID: 92567098005 Collected: 10/14/21 10:15 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 65.0 mg/L 25.0 25.0 1 10/20/21 12:06
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-4 Lab ID: 92567098006 Collected: 10/14/21 10:40 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 125 mg/L 25.0 25.0 1 10/20/21 12:06
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-5 Lab ID: 92567098007 Collected: 10/14/21 13:25 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 88.0 mg/L 25.0 25.0 1 10/20/21 12:11
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-6S Lab ID: 92567098008 Collected: 10/14/21 13:30 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 47.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-6D Lab ID: 92567098009 Collected: 10/14/21 12:25 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 43.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 16 of 36

lceAnalyircal
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Pace Analytical Services, LLC
Og8wwbe. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-7 Lab ID: 92567098010 Collected: 10/14/21 10:20 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 66.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 36

lceAnalyircal
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Og8mwbe. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-8 Lab ID: 92567098011 Collected: 10/14/21 11:35 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 70.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 36

lceAnalyircal
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Og8mwbe. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-10 Lab ID: 92567098012 Collected: 10/14/21 13:10 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 41.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 36

lceAnalyircal
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Og8mwbe. Suite 100
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ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPMW-11 Lab ID: 92567098013 Collected: 10/14/21 12:00 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 48.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 36

lceAnalyircal
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Pace Analytical Services, LLC
Og8�t�ipwbe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPTW-2 Lab ID: 92567098014 Collected: 10/14/21 13:10 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 65.0 mg/L 25.0 25.0 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 36

lceAnalyircal
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Pace Analytical Services, LLC
Og8mwbe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCP-LEACHATE Lab ID: 92567098015 Collected: 10/14/21 09:35 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 37700 mg/L 2500 2500 1 10/20/21 12:12
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 36

lceAnalyircal
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Og8mwbe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCP-LEACHATE-34 Lab ID: 92567098016 Collected: 10/14/21 10:55 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 1670 mg/L 50.0 50.0 1 10/20/21 12:15
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 36

lceAnalyircal
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Pace Analytical Services, LLC
Og8mwbe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPSW-1 Lab ID: 92567098017 Collected: 10/14/21 09:20 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 45.0 mg/L 25.0 25.0 1 10/20/21 12:15
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 36

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
Og8mwbe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPSW-2 Lab ID: 92567098018 Collected: 10/14/21 09:10 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 48.0 mg/L 25.0 25.0 1 10/20/21 12:15
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 36

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
og8mwbe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CCPSW-3 Lab ID: 92567098019 Collected: 10/14/21 10:15 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 48.0 mg/L 25.0 25.0 1 10/20/21 12:15
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 36

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
Og8oywbe. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090196 CLS LF
Pace Project No.: 92567098
Sample: CLS_FD-20211014-1 Lab ID: 92567098020 Collected: 10/14/21 00:00 Received: 10/15/21 13:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 46.0 mg/L 25.0 25.0 1 10/20/21 12:15
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 36

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
Og8onfbe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J21090196 CLS LF
Pace Project No.: 92567098
QC Batch: 653998 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92567098001, 92567098002, 92567098003, 92567098004, 92567098005, 92567098006
METHOD BLANK: 3429181 Matrix: Water
Associated Lab Samples: 92567098001, 92567098002, 92567098003, 92567098004, 92567098005, 92567098006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 10/20/21 12:01
LABORATORY CONTROL SAMPLE: 3429182
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 251 258 103 90-110
SAMPLE DUPLICATE: 3429183
35670382001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 1380 1350 2 25
SAMPLE DUPLICATE: 3429184
35670316002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 612 606 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/22/2021 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 36

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
Og8oswbe. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J21090196 CLS LF
Pace Project No.: 92567098
QC Batch: 654002 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92567098007,92567098008,92567098009,92567098010,92567098011,92567098012,92567098013,
92567098014,92567098015,92567098016,92567098017,92567098018,92567098019,92567098020
METHOD BLANK: 3429193 Matrix: Water
Associated Lab Samples: 92567098007,92567098008,92567098009,92567098010,92567098011,92567098012,92567098013,
92567098014,92567098015,92567098016,92567098017,92567098018,92567098019,92567098020
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 10/20/21 12:11
LABORATORY CONTROL SAMPLE: 3429194
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 251 258 103 90-110
SAMPLE DUPLICATE: 3429195
92567098007 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 88.0 93.0 6 25
SAMPLE DUPLICATE: 3429196
92567098017 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 45.0 48.0 6 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/22/2021 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 36

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
Og8o4wbe. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J21090196 CLS LF
Pace Project No.: 92567098
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/22/2021 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 36

lceAnalyircal
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Pace Analytical Services, LLC
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�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J21090196 CLS LF
Pace Project No.: 92567098
Lab ID Sample ID QC Batch Method QC Batch
92567098001
CCPMW-1S
SM
2540C-2011
653998
92567098002
CCPMW-1D
SM
2540C-2011
653998
92567098003
CCPMW-2S
SM
2540C-2011
653998
92567098004
CCPMW-2D
SM
2540C-2011
653998
92567098005
CCPMW-3D
SM
2540C-2011
653998
92567098006
CCPMW-4
SM
2540C-2011
653998
92567098007
CCPMW-5
SM
2540C-2011
654002
92567098008
CCPMW-6S
SM
2540C-2011
654002
92567098009
CCPMW-6D
SM
2540C-2011
654002
92567098010
CCPMW-7
SM
2540C-2011
654002
92567098011
CCPMW-8
SM
2540C-2011
654002
92567098012
CCPMW-10
SM
2540C-2011
654002
92567098013
CCPMW-11
SM
2540C-2011
654002
92567098014
CCPTW-2
SM
2540C-2011
654002
92567098015
CCP-LEACHATE
SM
2540C-2011
654002
92567098016
CCP-LEACHATE-34
SM
2540C-2011
654002
92567098017
CCPSW-1
SM
2540C-2011
654002
92567098018
CCPSW-2
SM
2540C-2011
654002
92567098019
CCPSW-3
SM
2540C-2011
654002
92567098020
CLS FD-20211014-1
SM
2540C-2011
654002
Date: 10/22/2021 04:53 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 31 of 36

aceAnalytica!
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: October 28, RWe 76
Page 1 of 2
Document No.:
F-CAR-CS-033•Rev,07
Issuing Authority:
Pace Carolinas Quality Office
of 82
Laboratory receiving samples:
EssvilleDAtla Rta[—Kernersvillen
Sample Condition Upon Receipt Clie ame: W0 925fi7098
Project P.
Courier: ❑ ed Ea ❑UPS ❑USPS ❑Client 1111111IN 11111111111
Commercial DPace ❑Other; 01
Custody Seal Present? Des Seals Intact? Des [-]No 1 � r r
pate/lnftlals Person Examining {ontentstl 1 !
Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue Fr zen?
Thermometer: J 13 IJ/(51z! ©wet [_-]Blue[:)None❑yes ❑No N/A
© 1A Gibs In• _r'i-T ' —
ype a ce:
Correction Factor:
Cooler temp: L `� Add/Subtract (°C) Temp should be above freezing to VC
Cooler Temp Corrected ('9K ❑Samples out of temp criteria. Samples on ice, cooling process
rLJ� has begun
USDA Regulated Soil ( N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally,
nYes FINo includinrHawai}and Puertn Rirnl7 nYPs I—INn
Comments/discrepancy:
Chain of Custody Present?
ores
No
N/A
1.
Samples Arrived within Hold Time?
B'I;s
No
❑N/A
2.
Short Hold Time Analysis 1 <72 hr.)?
❑Yes
❑Na
N/A
3.
Rush Turn Around Time Requested?
❑Yes
[]No
❑N/A
4.
Sufficient Volume?
Q r;es
NO
N/A
5,
Correct Containers Used?
-Pace Containers Used?
©Yes
Fares
[-]NO
❑Np
❑N/A
N/A
6.
Containers Intact?
res
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
(-]Yes
ONO
N/A
a.
Sample Labels Match COC?
-Includes Date/Trme/ID/Analysis Matrix:
Wies
�/✓
❑No
❑N/A
9.
Headspace in VOA Vials (>S-6mm)?
Yes
❑NP
N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
❑No
On
❑N/A
N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
——°erson-con
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date:
Date:
Field OataRequired? ❑Yes ONO
Page 32 of 36

Document Name: Document Revised: October 28, 29ge 7 of 82
b Sample Condition Upon Recelpt(SCUR) Page 2 of 2
�.OceAnalytrcal Document No Issuing Authority:
F-CAR-CS-033-Reu.07 Pace Carolinas Quality Office
`Check mark top half of box if pH and/or dechlorination is Project WO# : 92567®98
�verified-and within. the acreptance range_fapLeservation PM: NMG Due Date: 10/22/21
samples. CLIENT: 92—Duke Emer
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottles
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adjusted added
IVpte.-vvnenever ui Cic u a uu�icyu.r o«^.g •..,. •..._. _...-- -- � _
Out of hold, Incorrect preservative, out of temp,lncorrect containers.
Page 33 of 36

Document Name:
edition Upon Rec,
Oacument No.:
'Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA,Caliform, TOC, 011 and Grease, ORO/3015 (water) DOC, LLHg
"Bottom half of box is to list number of bottles
Oacument Revised: October2a, 2020 Pie 78 of 82
it(SCElRj Page 2 of 2
Issuing Authority:
Pace Carolinas Quality office
Project I WO# : 925670g8
PM, NMG Due Date; 10/22/21
CLIENT: 82-puke Ener
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adjusted added
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-------------------
-- Note. Nhenew rthersis-3-drscrepancriffecnng-Narttr�aWinr�n:@Bance-,arnples�iepy-aFthis-fG m-w4bl a-iagtzr3 ��o h � finafl liNt�artiNcatioa]trice-il.��
Ovt"oFdord, irteoc�eg5� a vatsve; 3ut of emF, ficorrea �QaM ners_
Page 34 of 36
1

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
Page 79 of 82
Ouks Energy Analytical Laboratory i ....... ......... ._._„_----------- _._._._.__._._._AnslYllcal
' � DUKE Ya`�7a]]UGOW "m740) ! ,orderX J21O9O196
ENERGY Hab"e , N.c, famNs i V
pwla�ss24s �avvad a
Fu_jral ersso�e _ _ _ _ _
----._._.__._ _._------- _.... - 'Vendor
Projeetµams ROGERS CLIFFSIDE CCP ou°^e„^
LANDFILL PERMIT# B7.06 i _
'
Client RYAN CZDP, BRYAN MOELLER, jl.
PEE O'BRIEN, JOSH STOWE Pace
OAeraling Untl: L556 Procaes:KGRDWTR Account:
L
Proj-ch ACS560062 AclivilylD: Faclllty ID: CLS PO # 9,1 7R f 1 2
7 WT
Prargrmm l EOuts Task Ca de: CLS Sub -Program Task Code:
LCP rZF
Laboratory Uae Only._.__.___._.__._._�...._T..�_._._._i
Matrix WATER P e a �T NC_x_
Oat.yTme Sc—
SAMPLE PROGRAM
Gmund water NPDES _
!/ Onnking Water UST_��
RCRA Waato_
.�._..-�.. .�_. cooler TomP_,(C�._.._..._.._.._.._._.._..-,..„._.............................. _............
Filtration (0.45 um) b Unfiltered
Preservative ICE
Container Volume ml-
( I ~02 TISO 300
Container Type HOPE PET
j Page_7 a( 2
! DISTRIBUTION
ORIGINAL to LAB, COPY to CLIENT
_,.-.....,�____
1} Filtered
ICE
500
PET
Sample Description or ID
i SAMPLE ID
NUMBER
! !
Mete
Customer to
Tlms
L�
Ito
LJa'-a
campla[o all aAProprlalo nan•slradod�ron�. z w
as
CollscUon Iniermallon
ri
Printed Name SI atum 0
(Metals Prep -TRM)
11CP-EPA 0010OI Ba,
8, Ca, Cu. Fe, Mg, Mn,
K,Ne,2n(10)fHg
(EPA 141OA) 1(IMS•
EPA 60208) Sb, As,
Be, Cd, Cr, Co. Pb, Ni,
Se, Ag, TI(LL), V1LL)
12
CI, F,
NO3-N
140-Hr
Hold
Time),
SO4,
F _AL
(4.5)
TDS
c
v
a
.°
?! 2021�
2027387
CLS_CCPMW-1S
CLS_CCPMW-iD
tr�t4 ?tti1
IV j,�
�w r�s�
%
1
1
2021025388 :.
��
2021025309 j
1 2021025390 j
CLS_CCPMW-25
CLS_CCPMW-2D
GL6mQGPMW4&
J(J lr{ lei
1
J0 tt{ ��
11 ib
3
f2Mfl �1 M
Mfl �-(
r -TA 5
/�7
r LrG
x
x
x
-L
Z
1
1
,
1
1
20210 391
CLS CCPMW-3Q
CL5_CGPMW4
1043vL1
(y1f4,241
tV4Q
Rile
/%/
x
L
t
1
20211 0253
i 2021925393
CLS_CCPMW-5
ltl J'1 wm
3zsIVRA
x
1
1
+ 2021025394
.j
CLS _CCPMW 65
JU Jyju,Ll
33 0
(�L6
t 2021025395
L—�
CLS_CCPMW-60
{u I4 2-,
2021025396'
CL5_CCPMW-7
10j14 y.Ly
{pLID
LTQ
x
t
1
! 2021025397 i
CLS _CCPMW 8
IUjl4 2bLl
�� 3 5
S
"�
x
L
1
1
2021025398
2021025399
CLS_CCPMW-1p
{r41`{ 2-4
1310
LT13
x
L
1
1
CLS_CCPMW-1i
1011 "11
Iwo
(IT
%
2027025400
CLS
lu IK lutl
1310
QMS
x
>`
1
i 20210 1
CLSCCP-LEACHATE
(d iY iuLJ
17�f3�
S�� K/¢.4
x
(2021027486
CLS_CCP-LEAC14ATE-34
/Jsr
Z-T2-- HA6
I
0
i
j
Customer la al n 6 Ualo bs ow
TOTAL CONTAINERS
0
0
0
1 17
0
17
17
0
0
0
0
0
O
51
Rnllnqulehod By DatafTlme
�uc� !o(fYiwLc L 19V)
Ace. ptad By:
G
-
Datefnme
m
a
c
Requested Turnaround
Total 51
Relinquished By OstefTlma
Accepted B DmefTime
c
n a
21 Days
Reilnqu ad By OotefTlma
Accep ed B DatolT
SosllLoc Da Imo
^
a
m
E
q v
C
4
dr
E
14 Days X
-7 Days
'Other
Sssle ock Opened By D s I r
Regulatory Agency: NCDENR1DWm -SW Section STATE EDD I EOU1S REQUIRED !PERMIT >! 87-06
U
- Add. Cost Will Apply
2
0
to
M
0t
lT
M
D-

CHAIN OF CUSTODY RECORD A_ND ANREQUEST FORM
r■� DI r{[C DYkq Lnerpy lit Cal Laboratory • i -- �--W- "-'-'--'-'-'- _ Analytical Laboratory Va Only_._ ---DU
VI\L YW Cw1. MnOiA](nWldlna TM51 1(]fder it _._._._.�,. _.___._._. _._.— NC-X ._._._.-
ENERGY—11AW,N..ryxd MaVlt WATER aMw�a,aM.mrr.
xunur-)1 x.c. nova
pwyars-!zu I Lopped BY Dam S TlIn SC_
r
�._._.__! I d SAMPLE PROGRAM
aJgct Namq ROGERS_ CLIFFSIDE CCP Ground Walor X NPi]ES_
LANDFILL PERMIT# $1-06 ! I. Z - Drinking Welor UST
' Cgglnr To-me(CI RCRP. Wmiti
Ilent RYAN CZOP, BRYAN MOELLER,----•-_._.._.._ _._..,._..�_, __._,.-„_-._.
,_ O'HRIEN, JOSH STOWS Pace Filtration (0.45 um) 8 Unfiltered
ierating Unit: C556 Proc06vNGRDWTR Account:
.as r r Preservative ICE ICE
oJact: AC5560062 Activity ID: Facility ID: CLS 'ABRI ®® ■Y rif •-------
TEST SV+T Container Volume (mL)
opram l EQYIS Task Cods: CLS Sub-PropramRao-k Cgdq; t r 300 500
:PlLF J Container Type HOPE PEI PEr
SAMPLE to
NUMBER
2021025402
2021025403
i 2021� 0
I. 20210254o5
2021025406
i
i
i 1
i
i
I
I
I—�
i
Sample Description or ID
Customer ro complete eff epproprlo(a eon-sbeded Dross.
��
a
e d
ri
(MgtaFe Prop -TRM)
(ICP - EPA 6010O) Ba,
B, Ca, Cu, Fe, Mg, Mn,
K, Na, 2n 440)1 Hg
(EPA 1470A) l(IMS -
EPA 6020B) Sb, As,
Be, Cd, Cr, Ca, Pb, NI,
Cl. F.
NO3-N
[4$-Hr
Hold
Time),
SO4,
TOS
CollgcOgn lnfarmatlon
CLS_CCP5W-1
GLs_Ccpsw-2
cis ccpsw-s
CLS_FD-1
GLS_FB
Dalq
1O IN Z#LI
Iv�[4jt•.a1
i�(I4ftqu
f��14 Eval
Ioll`l wit
Time
( [}
U�iiv
�[7tS�
0140
Pdntgd Namq
G�(� r, EK
TY1- K,44
4.[4+4
GLG /`tER
SI atun
E
u
X
X
x
Se, Ag, VILL), V(LL)
1Z
Z
F_ALK
4.5X
,
L
1
t) q
U jgIZGLy
D.WTIm
TOTAL#CONTAINERS I I I g I g I 0 I 5
;0j
J r3 P.-, r i-( v'L-
f v 1 IZf f -� GI s
Regulatory Agency: NCO ENRIDWm - SW Section STATE EDO f EQUIS REQUIRED ! PERMIT # 81-06 , )) t >' +7 / 2 t
Page 80 of 82 m
O
Page _2_ of 2 M
DISTRIBUTION p)
ORIGINAL to LAB. COPY to CLIENT N
tw
a Filtered
HOPE
(Metals Prep - q
TRMI (iCP - `
EPA 60100)Zn
(1)1(IMS-EPA _
6020B)Cd, Cr, t°-n
Cu, Pb, NI, Ag
(6) u
w-1�I14
D 5 4 0 1 0 1 0 1 0 L 4
m
Requested Turnaround
c
" n 21 Days
m c
m�
a �
.: 14 Days X,
N �
O y
a '7 Days
E _
- y
4a
E
•Other
'Add. Cost Will Apply
U
To1el 18

"o�ia E;;:�gy.S.�.tyiic,i Labornory'
• IF' DUKE �. ��.��a�],Pr,�,
E .ER" I ]9 Np�n F�nY RC i
i+s.larsua
F •Irerl ilJsa]e
CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
----`•-----------•----"._._•___".__".-•--------•-----Anaynlcalia6maen------ Only-- -•-•---•---•--•-•-
i J21 D90196 Matrix WATER a per
SAMPLE PROGRAM
Page 81 of 82
RC_x_ E Page _ t_ of-2_
sc— DISTRIBUTION
' ORIGINAL to LAB. COPY to CLIENT
Project Rome - ROGERS CLIFFSIDE CCP ^�^�++^-- _! edor
LANDFILL PERMITS 81-06 ! `
Client RYAN C20P, BRYAN MOELLER, ` c°°Nrr'•=ETc-L-----
il.
DEE O'BRIEN, JOSH STOWE I pale Filtration (0-45 um)
Operating Unit: CS56 P---:NGRDWTR Account: I Project: AC5560062 Activity ID: Facility ID: CLS PO # 9171711 - - ' Container Volume Preservative
TEST [
Program 1 EqulS Teak Coda: CLS Sub-ProgranJTaak Code:
CCP I LF Container Type
Cusfcmer fo comprere all ePpmpna$o non-shatlad areas w
Semple DeSGrj¢tiOn Oi I❑
SAMPLE Callectfan Information
NUMBER I Tm
Dale Time Prinsed Name Si alum
Ground water 1f NPDE$
Dnnkirg water UST _
RCRA waste
•-•--••_.._.._.._.._.._.._.._.._.._.._.._.._._. .-_---_--_.,_.-__.._.__
d Unfiltered CrFiltered
i dly 'w ISO
300
Soo
HOPE
PET
PET
;Mepps prep - TRM]
j{CP - EPA 6ot0Dl Ba,
B, Ca, Cu. Fe, MB, Mn,
[EPA 7470A] f VMS-
EPA 60208] Sib. Ae,
9o. Cd, Cr, Co, Pb, Ni.
�� AB, T[LL], V[LL]
f2
Cl, F
NO3-N
148-Hr
Hold
Tlme},
SO4.
F_ALK
al5
TDS
■
2
U
12020266
CLS CCPMw-15
x
nh
1
20210253s7
CLS ccPIIW 1D�u
ZS
6L6 hER
x
1iz
i
,
4
E 2021025M i':
CLS CCPMW-25
1ot14 7W
tl�d
j��1$ :V^
A y
x
12021025389
CLS _CCPMW 21)
x
2021025390E
6LCr6C?B1W�S
x
f
t
j 2021025391
CLS CCPMW3D
{d�l k+Ll
lt]IS
e
M1itl�
pp
f+`rlpyt-�
x
7—
t
t
12027025392
CLS_CCPMW-4
Ibjlyr 1
LU40
N�
x
L
t
t
12021025393
CLS_CCPMW-5
LV/1417sel
13zsRA
x
2
t
t
2021025394
CLS_CCPMW-&5
r� iyj
y 33 ❑
GAG M E�
x
,
12021025395 !
CL5 CCPMW-SD
{L {4 jy
in's,
1kF—},
x
i• 2021025386':
CLS_CCPMW-7
ldIN kL{
toxa
LTa
x
2021025397 {
CL$ CCPMW-6
2021025398
2021025399 E
CLS_CCPMW-40
CLS_CCPMW-TT
l 14 lrsl
131�
TQ
x
x
i 2021025400
CLS_CCPTW-2
1310
x
12021025 0
CLS CCP-LEACHATE
fa +Y tatl
0y3r
ssZ- H,4f9
x
i Z0210�27486 ,
CLS_CCP-LEACHATE-34
lV114ML,
I p xr
n�—L H A 4
x
0
TOTAL P CONTAINERS
]It,
0
47
0
47
17
B
0
D
0
B
p
51
unomar to sign ate ow
Rehinqulahed By Del Yoe
� = P�y� 16N iV
accepted By: Oaterrime
G
m v
G
w
C
n .
E A
a
o
c�
Requested Tumhn around
21 Days
14 Days x
•7 Days
'Diner
Add. Cost Will Appiy
Total 54
Relinquished By DaleITime
Acwpted B Datw Time
�Inqudy DaleJTime
Ac p d B pat
3ea &"ke Oa ime
Beata oak Opened By D
Comments
Regulatory Agency: NCOENRIDWm - SW Section STATE EDD 1EQUIS REQUIRED 1 PERMIT g 81.0E

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 82 of 82
,,if DUKE
'' ENERGY.
' Cllant RYAN CZOP, BRYAN MOELLER,
i DEE O'BRIEN,JOSH STOWS
Page _ — o1-2
DISTRIBUTION
ORIGINAL to LAB. COPY to CLIENT

wood.
APPENDIX C
Charts of Groundwater Elevation, pH, Chromium, Cobalt, Iron, Manganese, and Vanadium over
Time

s
E:3.71;
CCPMW-1s
840
830
CCPMW-1 D
`� rrvi vv-vv
790
CCPMW-11
CCPMW-10
780
Iry ry
p� �� p� ��, p� �� p� Qt p� fit, p� �� p� �� p� ��, p� ��, p� �� p� �� c
O Q- O Q- O Q� O Q� O Q� O Q- O Q- O Q- O Q� O Q� O Q- O Q, O
wood.
Date Measured
T ,DUKE
ENERGY
GROUNDWATER ELEVATIONS OVER TIME
ROGERS ENERGY COMPLEX
CCP LANDFILL PHASE I, II, III AND IV
RUTHERFORD COUNTY, NORTH CAROLINA
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MDF Date: 12/13/2021
PROJECT NO: 7812200571

12
11
10
�i
8
2
Q
7
6
5
�rmvv -u
4
O°) NO N') <5 N1R 1 �1 �� N� 1�0 NO N\ \1 �`� ��' NI)
O�'�
O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q O Q Q O
Date Sampled
wood.
ED
VC 2L (Upper Limit
of Acceptable
Range)
CCPMW-5
l
NC 2L (Lower
Limit of
Acceptable
Range)
CCPMW-11
:CPMW-2S
pH OVER TIME
DUKE ROGERS ENERGY COMPLEX
CCP LANDFILL PHASE I, II, III AND IV
ENERGY® RUTHERFORD COUNTY, NORTH CAROLINA
PROJECT NO: 7812200571
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MAS Date: 12/21/2021

25
20
J
s
15
c
0
12
c
a�
c
0
V
E
CCPMW-5
0
10-----------------------------------------------------------------------------------------------------------------------------rNC2L
V
67
0
1\10
NO
N1
N1
N1b
N1b
�
No)
11 0
tiQ
�N
�N
P
Cl
�
P
�
P
L�
�
P
L�
�
Q�
P
!
�
�t
P
p�
�
wood.
Date Sampled
DUKE
r, ENERGY
CHROMIUM CONCENTRATIONS IN CCPMW-5 OVER TIME
ROGERS ENERGY COMPLEX
CCP LANDFILL PHASE I, II, III AND IV
RUTHERFORD COUNTY, NORTH CAROLINA
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MDF Date: 12/13/2021
PROJECT NO: 7812200571

11
CCPMW-1S
in
0
H.
7
4
3
2
E
JI
MAC
-----------_---------------------------------------------------------------------------------------------------
0
NO NA
c Q0 Qc fit, p� �� !� �� c �� c ��, p
O Q� O Q� O Q� O Q� O Q� O Q� O Q� O Q- O
Date Sampled
wood.
DUKE
r, ENERGY
COLBALT CONCENTRATIONS IN SELECT
WELLS OVER TIME
ROGERS ENERGY COMPLEX
CCP LANDFILL PHASE I, II, III AND IV
RUTHERFORD COUNTY, NORTH CAROLINA
PROJECT NO: 7812200571
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MDF Date: 12/13/2021

700
600
500
J
1
p
400
c
a�
v
c
O
v
c
0
—
300- - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
200
100
0
O
P
wood.
y0
O�� Pit CF
Date Sampled
IRON CONCENTRATIONS IN CCPMW-8 OVER TIME
ROGERS ENERGY COMPLEX
DUKE KE CCP LANDFILL PHASE I, II, III AND IV
t ENERGY® RUTHERFORD COUNTY, NORTH CAROLINA
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MDF Date: 12/13/2021
PROJECT NO: 7812200571

500 -
450 -
400 -
350
J
300
0
�a
L
250
0
V
0)
e1
N
c
200
c
►-1
150
0
MRA\A/ �
50_______________________________________________________________________________________________________
0
,LO ,LO
41,
Date Sampled
wood.
:DUKE
ENERGY
MANGANESE CONCENTRATIONS IN
CCPMW-7 OVER TIME
ROGERS ENERGY COMPLEX
CCP LANDFILL PHASE I, II, III AND IV
RUTHERFORD COUNTY, NORTH CAROLINA
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MDF Date: 1/31/2022
PROJECT NO: 7812200571

12
10
P
,-%-rIvi vv-.j
0
4
CCPMW-2S
2
IMAC
........................
------------------- CCPMW-6S
------------------------------------------------------------ r------------�
0
NIZ) NQ) N11\ N") N� N� N�') Nh NO NO N1 N1 Nob -1b
fit' fit' d ��' �� Q� fit' fit' fit' ��' �� ��'
P � P 4 P � P � P � P O P O P � P � P c
Date Sampled
wood.
takik DUKE
° ENERGY
CCPMW-2D
I- CCPMW-8
r- CCPMW-7
------�. ---ram- -
PMW-11
VANADIUM CONCENTRATIONS IN SELECT WELLS OVER TIME
ROGERS ENERGY COMPLEX
CCP LANDFILL PHASE I, II, III AND IV
RUTHERFORD COUNTY, NORTH CAROLINA
F:WMEC_Projects\2020\7812-20-0417\MXD\Template11x17.mxd, User: leanna.muroski; Checked by: MDF Date: 12/13/2021
PROJECT NO: 7812200571