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HomeMy WebLinkAbout3404_Forsyth_Kernersville_MSWLF_July2021GW_FID1638305_20220125onic Data - Email CD (data loaded: Yes / No) Doc/Event *- DENR Division of Waste Mana ement - Solid Waste Environmental Monitoring 9 Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Complianoe Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultard, facility owner): WithersRavenel, Inc. Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address: Name: Laura Robertson Elliott, PG Phone: 919.238.0422 (p)1919.451.9710 (c) E-mail: lelliott@vAthersmver*l.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Town of Kemersville Landfill Freeman Road 34-D1 .0500 July 20, 2021 Kemersville, NC 27284 Environmental Status: (Check all that apply) Initial/Background Monitoring X❑ Detection Monitoring Assessment Monitoring ❑ Corrective Action T of data submitted: (Check all that apply) X Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data ❑ X Surface water monitorin4 data Other(specify) Notification attached? HNo. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the hest of my knowledge, the Informadon reported and statements made on this data submittal and attachments are true and correct Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statemertt, representation, or certification Including the possibility of a fine and Imprisonment Mark Brown, LG, PG, RSM Senior Geologist 919.608.4582 Factl�ytBepresen 've Name (Print) Title (Area Code) Telephone Number January 25, 2021 Affix NC Licensed/ Professional Geologist Seal Signature I Date 424 GallimAre Dairy Road, Suite C. Greensboro, NC 27409 Facility Representative Address C•082 NC PE Firm License Number (f applicable effective May 1, 2009) Revised 6/2W9 ,a.01111r/b1"_ '. Our People. Your Success. January 25, 2022 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management -Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: July 2021 Water Quality Monitoring Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.48 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached July 2021 Water Quality Monitoring Report for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report, appendices for the July 2021 sampling event, and historic data from the semiannual sampling event performed January 2021. Also attached is the North Carolina Environmental Monitoring Reporting Form for the July 2021 monitoring event. Please contact me at mbrown@withersravenel.com or Laura Elliott at lelliott@withersravenel.com with comments, questions, or requests. Sincerely WithersRavenel Mark Brown, LG, PG, RSM Senior Geologist Attachment C: Brad Beeson -Town of Kernersville, Solid Waste Superintendent 424 Gallimore Dairy Road, Suite C I Greensboro, NC 27409 t: 336.605.3009 1 f: 919.467.6008 1 www.withersravenel.com I License No. C-0832 Asheville I Cary I Greensboro I Pittsboro I Raleigh I Wilmington 1\/ � WithersRavenel Our People. Your Success. JULY 2021 WATER QUALITY MONITORING REPORT Town of Kernersville Closed Landfill 9900 Freeman Road Kernersville, Forsyth County, North Carolina NCDEQ Permit ID #: 34-04 Prepared for: Town of Kernersville Public Works Department PO Box 728 Kernersville, North Carolina 27285 Prepared By: WithersRavenel, Inc. 424 Gallimore Dairy Road, Suite C Greensboro, North Carolina 27409 WR Project #: 06140180.39 January 25, 2022 ) -"vet 't (OJO-p- Mati Maltba Environmental Technician I CARD/ r� NNSS,��V_AY' i JCSA �ti� v' SE1171, L � ,- 10 o�oo IIAIl1�w � �k Mark Brown, LG, PG, RSM Senior Geologist Our People. Your Success. TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................................................................. 1 1.1 Site Information............................................................................................................................... 1 1.2 Site Geology and Hydrogeology.................................................................................................. 1 1.3 Regulatory Status............................................................................................................................ 1 2.0 FACILITY MONITORING PROGRAM............................................................................................. 2 2.1 Groundwater Monitoring Program.............................................................................................. 2 2.2 Surface Water Monitoring Program............................................................................................ 2 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT .............................................. 3 3.1 Field Services.................................................................................................................................... 3 3.2 Quality Control................................................................................................................................ 4 4.0 ANALYTICAL RESULTS...................................................................................................................... 4 4.1 Groundwater....................................................................................................................................4 4.2 Surface Water.................................................................................................................................. 5 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION ............................................ 5 5.1 MNA Parameters............................................................................................................................. 5 6.0 FINDINGS.............................................................................................................................................6 7.0 REFERENCES....................................................................................................................................... 6 Page i of ii r■ . ■ Our People. Your Success. Figures Figure 1 General Location Map Figure 2 Monitoring Well Location Map Figure 3A Potentiometric Map July 2021 Figure 3B Potentiometric Map July 2020 Figure 4 Groundwater 2L/GWP Exceedances Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents Appendices Appendix I Laboratory Analytical Reports and Field Notes Appendix II Historical Summary Tables (reproduced from Joyce Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Page ii of ii r■ . ■ Our People. Your Success. 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the Town of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5-minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina Quadrangle (Quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM), Solid Waste Section (Section) on May 15, 1985, and a Letter of Closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont Physiographic Province of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian -to -Permian age, which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well-connected. Groundwater at the site has historically been reported flowing generally to the southwest. Joyce Engineering (JOYCE) conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft. • An effective porosity value (n) of 30 percent was estimated. • Hydraulic conductivity (K) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. 1.3 Regulatory Status The Town of Kernersville (Town) is currently monitoring groundwater at the landfill in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. Samples are analyzed for all constituents listed in 40 CFR Part 258, Appendix I Constituents for Detection Monitoring ("Appendix I") and compared to the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the "2L Standards"); or, when a 2L Standard is not established, the Section's Groundwater Protection Standards (GWPs) or Interim Maximum Allowable Concentrations (IMACs). July 2021 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.39 January 2022 Page 1 of 7 r■ . ■ Our People. Your Success. Based on the presence of targeted Appendix I constituents detected at concentrations above the referenced standards that could potentially be crossing the facility boundary, the Section requested that the Town submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to the Section on May 13, 2013, and concluded that, based on site hydrogeology, it would be very unlikely that the site impacts at concentrations above their respective standards would cross the property boundaries. In a July 16, 2013 response to information presented in the Groundwater Assessment Report, the Section determined that, despite the conclusions presented in JOYCE's Groundwater Assessment Report, the detection of volatile organic compounds (VOCs) at concentrations that exceeded the referenced standards beyond the compliance boundary of the site constituted a violation of Section regulations. JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town in July 2014, which the Section approved on November 4, 2014. Note that the NCDENR is now doing business as the North Carolina Department of Environmental Quality (NCDEQ). 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background monitoring well MW-1 was replaced (by monitoring well MW-6) due to slow recharge in the well, low well volumes, or being dry during sampling events. Downgradient monitoring wells MW-2R, MW-3S, MW-3D, MW-4, and MW-5R are monitored for the Appendix I list of constituents as part of the compliance network for the facility. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2R, MW-3S, MW-3D, MW-4 and MW-6 are also periodically monitored for the following Monitored Natural Attenuation (MNA) constituents: • Nitrate, sulfate, chloride, sulfide, alkalinity, and • Total organic carbon (TOC); Groundwater samples collected semiannually are analyzed for the Appendix I list of constituents and periodically for the above -referenced MNA parameters. Sample analyses are then compared to the 2L Standards or IMACs or GWPs, where appropriate. 2.2 Surface Water Monitoring Program Surface water at the landfill is monitored semi-annually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. These surface water monitoring points are summarized below, along with their current monitoring program status. July 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 January 2022 Page 2 of 7 r■ . ■ Our People. Your Success. Surface Water Designation Classification SW-1 Upstream/Compliance SW-2 Compliance SW-3 Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semiannual monitoring events. Analytical results are compared to the Classifications and Water Quality Standards Applicable to Surface Waters of NC as listed in 15A NCAC 2B (2B Standards). 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT 3.1 Field Services On July 20, 2021, WithersRavenel (WR) personnel mobilized to the facility to purge and sample monitoring wells MW-1, MW-2R MW-3S, MW-3D, MW-4, MW-5R, and MW-6 and sample surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01- foot. Due to the lack of water encountered within the well, monitoring well MW-1 was measured for static water level only. Table 2, Groundwater Surface Elevations presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top -of -well casing elevations reported by JOYCE in their 2015 reports. For comparison purposes, the most recent sampling event (January 2021) data are illustrated on some of the figures. Figure 3A, Potentiometric Map (July 2021) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2021 sampling event. Figure 313, Potentiometric Map (January 2021) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the January 2021 sampling event. As shown on these figures and in recent sampling events, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of East Belews Creek. Table 3, Historical Groundwater Elevations presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR between 2016 and 2021. The monitoring wells were purged and sampled using either disposable bailers or submersible pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity, were recorded in the site -specific sampling forms after purging and before sampling. Groundwater Sampling Methods Groundwater samples from each monitoring well were collected directly from a submersible pump or decanted from disposable bailers into the laboratory -prepared and -provided containers immediately after purging. Samples were then placed into laboratory -provided coolers, chilled on ice to approximately 4°C, and delivered to a State of North Carolina -certified laboratory (Pace Laboratories) under standard Chain -of -Custody (COC) protocol. Field data logs are provided in the Appendix to this report. July 2021 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.39 January 2022 Page 3 of 7 r■ . ■ Our People. Your Success. Surface Water Sampling Methods Surface water samples were collected either directly into laboratory -provided, non -preserved sample containers, or by decanting the sample from a non -preserved 1-Liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. When used, care was taken to not overfill the preserved sample containers (which could lead to preservative loss) and avoid sample -induced turbidity. Samples were collected initially from the downstream sample location (previously designated SW-2 by others), and in sequence upstream, SW-3 and then SW-1 to reduce potential turbidity in the samples (Figure 2). After sample collection, the samples were placed in a laboratory -provided cooler, chilled on ice to approximately 4°C, and submitted to Pace Laboratories under standard COC protocol. 3.2 Quality Control One Field Blank was collected by WR personnel as part of the July 2021 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Field Blank was analyzed for the Appendix I list of constituents only, while the Trip Blank was analyzed for VOCs only. 4.0 ANALYTICAL RESULTS 4.1 Groundwater Groundwater samples were analyzed for the Appendix I list and the modified list of MNA constituents and compared to the respective 2L Standards or GWPs where appropriate. As shown on Table 4, Groundwater Analytical Results, the following organic and/or inorganic constituents were detected in groundwater samples during the July 2021 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations detected above the 2L Standard or GWPs are illustrated in bold font. Constituent Referenced Standard Compliance Wells (2L/GWP) MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6 Benzene 1.0 Dry - Not Sampled 3.07 0.284 0.451 0.384 BDL BDL 1,1-Dichloroethane 6.0 9.24 0.451 1.26 1.15 BDL BDL 1,2-Dichloroethane 0.4 0.520 0.272 0.571 BDL BDL BDL 1,2-Dichloropropane 0.6 3.64 0.394 0.977 0.286 BDL BDL Vinyl chloride 0.03 4.02 1.13 5.74 9.62 BDL BDL Cadmium 2 0.504 7.95 BDL 0.580 1.05 BDL Chromium 10 2.15 15.6 BDL BDL 11.3 1.99 Lead 15 3.25 12.5 3.43 5.96 99.5 BDL Thallium 0.3 BDL 4.57 BDL BDL BDL BDL Notes: BDL Below Laboratory Method Detection Limit Result Result Exceeds 2L Standard or GWP July 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 January 2022 Page 4 of 7 r■ . ■ Our People. Your Success. Figure 4, Groundwater Standard Exceedances Map illustrates exceedances to the referenced standards at the monitoring well locations. In general, the organic and inorganic results are consistent with historical data. Historical groundwater data, laboratory quality assurance/quality control information and the chain -of -custody records are included in the Appendix. 4.2 Surface Water Surface water samples were analyzed for the Appendix I list only. No analytes were detected at concentrations above the 2B Standards in surface water samples collected during the July 2021 sampling event. The results were consistent with historical data. Surface water data can be found in Table 5, Surface Water Analytical Results. The results, as reported by the laboratory, historical surface water data, the laboratory quality/assurance/quality control information, and the chain -of -custody records are included in the Appendix. 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION 5.1 MNA Parameters According to previous reports, in accordance with the facility CAP, MNA baseline sampling was initiated during the November 2014 sampling event and finished during the November 2015 sampling event. During those events, the full list of MNA parameters (shown below) were measured in samples collected from monitoring wells MW-2, MW-3S, MW-3D, and MW-4. MNA field (geochemical) parameters included: • Temperature • pH • Specific conductance • Oxidation-reduction potential (ORP) Turbidity; and Dissolved oxygen. Laboratory parameters included: • Biological Oxygen Demand (BOD) • Chemical Oxygen Demand (COD) • Dissolved hydrogen • Nitrate • Sulfate • Chloride • Alkalinity as CaCO3 • Sulfide • Total Organic Carbon (TOC) • Ethane, ethene, and methane; and • Volatile fatty acids. In correspondence with the Section in June 2020, the Section indicated that MNA sampling would not be required until after preparation and submittal of a new Corrective Action Evaluation Report in July 2021. As such, the full list of MNA parameters were not analyzed during the July 2021 sampling event. MNA parameters analyzed during the July 2021 sampling event are presented on Table 6, Summary of MNA Constituents, and included: • Alkalinity as CaCO3 • Chloride • Nitrogen, Nitrate • Sulfate July 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 January 2022 Page 5 of 7 r■ . ■ Our People. Your Success. • Sulfide, and • Total Organic Carbon (TOC) Laboratory reports and field data forms are included in the Appendix. Analysis of the full list of MNA parameters will begin again in January and July 2022. 6.0 FINDINGS Target analytes detected above their respective 2L Standards and/or GWPs in groundwater samples collected during the July 2021 sampling event appear to generally be consistent with previous events, including: • Benzene detected in MW-2R • 1,1-dichloroethane detected in MW-2R • 1,2-dichloroethane detected in MW-2R and MW-3D • 1,2-dichloropropane detected in MW-2R and MW-31D • Vinyl chloride detected in MW-2R, MW-3D, MW-3S, and MW-4 • Cadmium detected in MW-3S • Chromium detected in MW-3S, MW-4 and MW-5 • Lead detected in MW-5; and • Thallium detected in MW-3S No target analytes were detected in the surface water samples at concentrations above their respective 2B Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for February 2022. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Drummond, Jaclynne. "Re: Closed Town of Kernersville MSW Landfill - WQ Parameter Clarification 06140180.33" Message to Laura Elliott, June 29, 2020. E-mail. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semiannual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semiannual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, 2016 Solid Waste Section July 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 January 2022 Page 6 of 7 r■ . ■ Our People. Your Success. Guidelines for Groundwater, Soil and Surface Water Sampling. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. Technical Protocol for Evaluation Natural Attenuation of Chlorinated Solvents in Groundwater, EPA/600/R-98/128, September 1998. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina WithersRavenel, Inc., 2017 Annual Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, April 2, 2018. -----, 2018 Annual Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, April 16, 2019 -----, July 2019 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34- 04, October 7, 2019 -----, January 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, March 6, 2020. -----, July 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34- 04, September 2, 2020. ----, January 2021 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, May 7, 2021 July 2021 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.39 January 2022 Page 7 of 7 FIGURES % 0 bum) z 'A g50- N------ 0 WILL- 0 IV X Z - it x" 8, /* i : h A, "J. "N V. 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PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 MGM 1"=300' 2 1/ Engineers I Planners I Surveyors GOODWILL CHURCH ROAD WATER QUALITY SAMPLE LOCATIONS MAP APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive Cary, NC 275111 t: 919.469.3340 I license #: F-1479 I www.withersravenel—, SM B 01/24/2022 06140180.48 11 Ik\14\14-0110\14011OA!—TOM�mM! lady BrNs M I .M ft— J — 2C = — W117BA Yql F FM qti RO A D { MW-6 (790.61) MW-1 \ {i (DRY\ N v 775 \ 770 265 0 760 753.26) j 5510 M(� D MW-4 0 (754.52) M 3S (7s1.1a) W-2R $ MW-S Vy NbO (759.65) (769.54) P GOODWILL CHURCH ROAD LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY a GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION GROUNDWATER SURFACE ELEVATION / CONTOUR / ESTIMATED SNTIMAT GROUNDWATER FLOW NOTES: •^ 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY CIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY CIS DEPARTMENTS. GRAPHIC SCALE 0 110 300 6110 1 inch = 300 ft. N BY SCALE O. ;! WithersRavenel TOWN OFKERNERSVILLECLOSED LANDFILL - PERMIT #34-04 POTENTIOMETRIC MAP DR MGM 1-300' FIGURE EN3A Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (DULY 2021) KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA PROVED BY: DATE: PROIEQ NO.: m.ic,rv,Rcnssu,sas.aes.aaaoi n�u a:r-aazs nw,.,mm.rs,,.e�ei Qom SMB O3/24/2022 06140180.48 J?a A D ■■ W i t h e rs Raue n e l TOWN OF KERN ERSVILLE CLOSED LANDFILL - PERMIT #34-04 .. Engineers I Planners I Surveyors GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MaclC[nan Dmrc I Cary, NC 275I1 It 919A6933401 Ilansc t. L 0832 GOODWILL CHURCH ROAD LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION II N OTES: PDTENTIDMETRIC MAP (JANUARY 2021) I0,14i1h0110\I401W—%-am &* L-AM S-*— nT GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFOR❑ AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: LRE 1"=300 3A APPROVED BY: DATE: PROJECT NO.: SN1B 04/15/2021 06140180.39 6y—Vw—� '—ME . W 10. 2M — BLOIL IAIZ R O .e MW-4 Jul-29 CHROMIUM 12 VINYL CHLORIDE 9.� MW-3D Jul-21 2Ls (ug/L) 1,2-DICHLOROETHANE 0.571 0.4 1,2-DICHLOROPROPANE 0.977 0.6 VINYL CHLORIDE 5.74 0.03 GOODWILL CHURCH ROAD MW-2R Jul-21 2Ls (ug/L) BENZENE 3.07 1 1,1-DICHLOROETHANE 9.24 6 1,2-DICHLOROETHANE 0.520 0.4 1,2-DICHLOROPROPANE 3.64 0.6 VINYL CHLORIDE 4.02 0.03 a LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY $ SHALLOW MONITORING WELL ® DEEP MONITORING WELL Q SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) ONLY ANALYTICAL RESULTS THAT EXCEEDED THE 2L STANDARD ARE ILLUSTRATED. 4.) FOR WELLS FROM WHICH DUPLICATE SAMPLES WERE COLLECTED, THE HIGHEST DETECTED CONCENTRATION OF EACH CONTAMINANT IS SHOWN. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. MGM SCALE: ��/ W i th a rs Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL —PERMIT #34-04 DRE.FIGURE NO.: GROUNDWATER 2L STANDARD/GWP EXCEEDANCES 300' 4 1Engineers I Planners I Surveyors GOODWILL CHURCH ROAD MAP APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drive Cary, NC 27511 t: 919.469.3340 license #: F-1479 www.withersravenel.com KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA SM B 01/24/2022 06140180.48 Ik\14\14-0110\140la0A6-T0M-SmM! lady BwNs M 20n\E.*.\GID\20Q1A1.7-&—.—K--A% IadM.ft - J.— 2C 21M - WLTM Yql TABLES TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft-bTOC) Screen Interval (ft-bTOC) Total Depth (ft-bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 1 2 6.36 1 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 1 2 10.46 1 10.46 - 20.46 20.46 804.87 Notes: 1) ft-bTOC = Feet below top of casing 2) MSL = Mean sea level Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring 3) Report of 2014; Joyce Engineering; March 10, 2015. 1 of 15 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 7/20/2021 GROUNDWATER SCREENED TOP OF CASING DEPTH WELL ID INTERVAL ELEVATION SURFACE (ft-bTOC) (feet above MSL) WATERR ELEVATION (ft-bTOC) (feet above MSL) MW-1 24.96 - 34.96 806.42 DRY -- MW-2R 3.18 - 13.18 762.19 2.54 759.65 MW-3S 14.00 - 24.00 764.57 13.43 751.14 MW-3D 36.96 - 56.96 764.56 11.30 753.26 MW-4 4.40 - 14.40 1 760.26 5.74 1 754.52 MW-5 6.36 - 11.36 773.32 3.78 769.54 MW-6 10.46 - 20.46 804.87 14.26 790.61 Notes: 1) All measurements are in feet. 2) Elevation data is measured in feet above Mean Sea Level (MSL). 3) Depth to water measured in feet below top of casing (ft-bTOC) 4) "Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. 2of15 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-1 806.42 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 9/13/2017 DRY DRY 7/10/2018 DRY DRY 1/9/2019 DRY DRY 7/24/2019 DRY DRY 1/8/2020 DRY DRY 7/15/2020 DRY DRY 1/13/2021 30.62 775.80 7/20/2021 DRY DRY MW-2R 762.19 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 9/13/2017 4.22 757.97 7/10/2018 4.41 757.78 1/9/2019 2.84 759.35 7/24/2019 3.40 758.79 1/8/2020 3.17 759.02 7/15/2020 3.02 759.17 1/13/2021 2.38 759.81 7/20/2021 2.54 759.65 MW-3S 764.57 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 9/13/2017 14.29 750.28 7/10/2018 15.00 749.57 1/10/2019 12.50 752.07 7/24/2019 13.96 750.61 1/8/2020 13.23 751.34 7/15/2020 13.47 751.10 1/13/2021 12.89 751.68 7/20/2021 1 13.43 1 751.14 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 3of15 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-3D 764.56 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29/2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 9/13/2017 12.96 751.60 7/10/2018 15.00 749.56 1/10/2019 11.25 753.31 7/24/2019 11.86 752.70 1/8/2020 11.68 752.88 7/15/2020 11.94 752.62 1/13/2021 11.23 753.33 7/20/2021 11.30 753.26 MW-4 760.26 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 9/13/2017 7.33 752.93 7/10/2018 7.00 753.26 1/9/2019 5.24 755.02 7/24/2019 5.89 754.37 1/8/2020 5.71 754.55 7/15/2020 6.04 754.22 1/13/2021 5.44 754.82 7/20/2021 5.74 754.52 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 4of15 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-5 773.32 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 9/14/2017 5.48 767.84 7/10/2018 NM NM 1/10/2019 10.50 762.82 7/24/2019 4.03 769.29 1/8/2020 3.54 769.78 7/15/2020 4.75 768.57 1/13/2021 3.75 769.57 7/20/2021 3.78 769.54 MW-6 804.87 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 9/14/2017 20.64 784.23 7/10/2018 DRY DRY 1/9/2019 17.49 787.38 7/24/2019 16.51 788.36 1/8/2020 17.19 787.68 7/15/2020 15.97 788.90 1/13/2021 14.56 790.31 7/20/2021 14.26 790.61 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 5of15 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 6010 Contaminant Of Concern O Q u Q m E m E 2 M U E '� L U +,, U Q U -J V Z _� cn V) E (6 H F O i > N CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 7/20/2021 DRY - NOT SAMPLED MW-2R 7/20/2021 BDL BDL 253 0.333 J 0.504 J 2.15 J 3.95 J BDL 3.25 J BDL BDL BDL BDL 6.89 J 7.27 J MW-3S 7/20/2021 4.40 J BDL 236 0.880 J 7.95 15.6 15.5 44.7 12.5 8.10 J BDL BDL 4.57 B J 76.8 619 MW-3D 7/20/2021 BDL BDL 38.0 BDL BDL BDL BDL BDL 3.43 J BDL BDL BDL BDL 6.52 J BDL Duplicate (MW-3D) 7/20/2021 5.65 J BDL 49.2 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7.49 J BDL MW-4 7/20/2021 BDL BDL 127 BDL 0.580 J 12.1 3.50 J 6.32 J 5.96 J 3.84 J BDL BDL BDL 17.2 J 20.1 J MW-5R 7/20/2021 11.8 BDL 268 2.93 1.05 J 11.3 33.9 35.9 99.5 6.56 J BDL BDL BDL 110 327 MW-6 7/20/2021 BDL BDL 50.3 BDL BDL 1.99 1 1.12 1 BDL 5.68 1 BDL BDL BDL BDL 6.69 1 7.56 1 Trip Blank 7/20/2021 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2L Standard/GWP (µg/L) 13 10 700 43 2 10 13 1,000 1 15 100 20 20 0.2 0.33 1,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. NA Not Analyzed by Method Shown Qualifiers BDL Below Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds Laboratory Detection Limit J The identification of the analyte is acceptable; the reported value is an estimate. Result Result Exceeds 2L Standard or GWP Page 6 of 15 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 a� s o Contaminant Of Concern 0 °v M s a� 0 0 N 0 0 0 0 m 0 0 0 0 0 + N O O O O O m O O O a m m m m m N 0 U U U U -aQ U CAS # 67-64-1 107-13-1 71-43-2 74-97-5 75-27-4 75-25-2 74-83-9 78-93-3 135-98-8 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/20/2021 DRY - NOT SAMPLED MW-2R 7/20/2021 BDL BDL - NA NA BDL BDL BDL BDL NA BDL 0.155 J BDL BDL MW-3S 7/20/2021 34.9 J BDL 0.284 J NA NA BDL BDL BDL BDL NA BDL 1.55 0.410 J BDL MW-3D 7/20/2021 BDL BDL 0.451 J NA NA BDL BDL BDL BDL NA BDL 0.583 J 0.362 J BDL Duplicate (MW-3D) 7/20/2021 BDL BDL 0.472 J NA NA BDL BDL BDL BDL NA BDL 0.566 J 0.334 J BDL MW-4 7/20/2021 BDL BDL 0.384 J NA NA BDL BDL BDL BDL NA BDL 0.163 J 0.606 J BDL MW-5R 7/20/2021 BDL BDL BDL NA NA BDL BDL BDL BDL NA BDL BDL BDL BDL MW-6 7/20/2021 BDL BDL BDL NA NA BDL BDL BDL BDL NA BDL BDL BDL BDL Trip Blank 7/20/2021 BDL BDL BDL NA NA BDL BDL BDL BDL NA BDL BDL BDL BDL 2L Standard/GWP (µg/L) 6,000 NE 1 0.6 4 0.6 4 100 4,000 70 700 0.3 50 3,000 70 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J The identification of the analyte is acceptable; the reported value is an estimate. Page 7 of 15 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 r Analytical Method EPA 8260 C � a 0 oLL1 O C C -9 N c t s 4-0 N N 0 O O aJ O Contaminant Of Concern y E fCC S C C C W O fa t f6 L (D L O O Cn 0 s 0 s y O O Q O O O u Q O u O E O 0 O 0 0 u u u u u o �_ E -0 ri L O 0 0 0 0 0 0 0 L N N -2 N cc N c U ri r-P r-i r-P ri r-i r-i 'u CAS # 74-87-3 96-12-8 124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 7/20/2021 DRY - NOT SAMPLED MW-2R 7/20/2021 BDL BDL BDL BDL BDL 0.215 J 4.81 NA 9.24 0.520 J BDL C3 26.2 0.850 J MW-3S 7/20/2021 BDL BDL BDL BDL BDL 0.116 J BDL NA 0.451 J 0.272 J BDL C3 0.984 J BDL MW-3D 7/20/2021 BDL BDL BDL BDL BDL 0.174 J 5.00 NA 1.26 0.571 J BDL C3 8.81 BDL Duplicate (MW-3D) 7/20/2021 BDL BDL BDL BDL BDL 0.168 J 4.87 NA 1.19 0.530 J BDL C3 7.58 BDL MW-4 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA 1.15 BDL BDL C3 14.4 BDL MW-5R 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL MW-6 7/20/2021 BDL BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL Trip Blank 1 7/20/2021 1 BDL BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL 2L Standard/GWP (µg/L) 1 3 0.04 0.4 0.02 70 20 6 NE 6 0.4 7 70 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J The identification of the analyte is acceptable; the reported value is an estimate. C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. Page 8 of 15 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 m c ? c = c L a o a O a� LJO �Q. Oa� O O0 O O Contaminant Of Concern L- ° � t 4-1 � a N o a m u uo O C ca O CV a� a� O t Q M C o t + � CL 0 C O a� X 0 +�+ � C N N u N R 2 -0 c I �, N N W W ri ri a o 11 iJ 4-0 W Q. Z N r-i 1-- CAS # 78-87-5 10061-01-5 10061-02-6 108-20-3 100-41-4 591-78-6 74-88-4 98-82-8 99-87 6 75-09-2 108-10-1 1634-04-4 91-20-3 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 Well ID Date Collected Result Qual Result Qual Result Qual I Result Qual I Result l Qual l Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 7/20/2021 DRY - NOT SAMPLED MW-2R 7/20/2021 3.64 BDL BDL 0.241 J BDL NA NA 0.421 J BDL BDL BDL 0.313 J BDL BDL BDL BDL BDL BDL MW-3S 7/20/2021 0.394 J BDL BDL BDL BDL NA NA BDL BDL BDL BDL 0.187 J BDL BDL BDL BDL BDL BDL MW-3D 7/20/2021 0.977 J BDL BDL BDL BDL NA NA BDL BDL BDL BDL 0.360 J BDL BDL BDL BDL BDL BDL Duplicate (MW-3D) 7/20/2021 0.959 J BDL BDL BDL BDL NA NA BDL BDL BDL BDL 0.303 J BDL BDL BDL BDL BDL BDL MW-4 7/20/2021 0.286 J BDL BDL BDL BDL NA NA 0.118 J BDL BDL BDL 0.243 J BDL BDL BDL BDL BDL BDL MW-5R 7/20/2021 BDL BDL BDL BDL 0.139 J NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL MW-6 7/20/2021 BDL BDL BDL BDL 1.02 NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 7.10 Trip Blank 7/20/2021 BDL BDL BDL BDL BDL NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2L Standard/GWP (µg/L) 0.6 0.4 0.4 1 70 600 1 40 1 NE 70 1 NE 5 100 1 20 6 70 1 0.2 1 0.7 600 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J The identification of the analyte is acceptable; the reported value is an estimate. Page 9 of 15 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 S N N N L t O O N O O Contaminant Of Concern 0 o c E o a o 0 o t ° a a a °+J' o Z 'i 'i 'i 'i 'i 'i H H O H H H H U M t U N N t _O s CM M N 7, y N N N C1 > > X CAS # 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 95-63-6 526-73-8 108-67-8 108-05-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 7/20/2021 DRY - NOT SAMPLED MW-2R 7/20/2021 BDL BDL 0.700 J 0.160 C3 J BDL BDL BDL BDL NA 1 4.02 C31 BDL MW-3S 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 1.13 C3 BDL MW-31D 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 5.74 C3 0.390 J Duplicate (MW-3D) 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 5.73 C3 0.936 J MW-4 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA 9.62 C3 BDL MW-5R 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA BDL C3 BDL MW-6 7/20/2021 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA BDL C3 BDL Trip Blank 7/20/2021 1 BDL BDL BDL BDL C3 BDL BDL BDL BDL NA BDL C3 BDL 2L Standard/GWP (µg/L) 1 200 0.6 3 2,000 0.005 400 NE 400 88 0.03 500 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2L Standard or GWP Qualifiers J The identification of the analyte is acceptable; the reported value is an estimate. C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. Page 10 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 6010 Contaminant Of Concern c E E E E E E `—' .� E 2 •E Q- a •E a� = ca ++ $n 'L S� M o i -0 a M V Q% > (6 C u N a a m m u u u u � z N N H > CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/20/2021 4.31 J BDL 36.6 BDL BDL 1.71 J BDL BDL 3.02 J BDL BDL BDL BDL BDL BDL SW-2 7/20/2021 BDL BDL 41.1 BDL BDL 1.69 J 1.44 J BDL BDL BDL BDL BDL BDL BDL BDL SW-3 7/20/2021 BDL BDL 38.4 BDL BDL BDL 0.866 J BDL BDL BDL BDL BDL BDL 6.86 J BDL 213 Standard /L NE 10 1,000 65.0 0.82* 183.07* NE 3.64* 13.88* 144.92* 5 0.3* NE NE 36.2* Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. * Hardness -Dependent 15A NCAC 02B Water Quality Standard, Calculated with default in -stream hardness of 25 mg/L Qualifiers NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard The identification of the analyte is acceptable; the reported value is an estimate. Page 11 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 6010 EPA 8260 c ca Q. O O Q' N c O Contaminant Of Concern O E O c "' °' � t O a- 'n M O O u cc c O O E C ? oICE o '-� Op N O O O E O c M O O ,� O E o E E E E -0 -0 O O O o ca r— u U = O O O O O m M co t t t t N > N Q Q m m M m m N U U U U U U ri CAS # 7440-62-2 7440-66-6 67-64-1 107-13-1 71-43-2 74-97-5 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 96-12-8 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/20/2021 BDL BDL BDL BDL BDL NA NA BDL BDL BDL NA BDL BDL BDL BDL BDL BDL SW-2 7/20/2021 BDL BDL BDL BDL BDL NA NA BDL BDL BDL NA BDL BDL BDL BDL BDL BDL SW-3 7/20/2021 BDL I BDL BDL BDL BDL NA NA BDL BDL BDL NA BDL BDL BDL BDL BDL BDL 213 Standard /L NE 36 NE NE 1.19 NE NE NE NE NE NE 0.254 488 NE NE NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard Page 12 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 c � c O a _ ° v ° i o a) c c `I W W a) t a� c a ° a i 'n aJ 0 O M 0)N N 0 C C C +� o 0 f6 o i o 0 Contaminant Of Concern ° J c W O OO u0 y Q O O Q O uOC O i O O O t L t s s N t C] (') N C E u2 E u u r, u u u ri u r.i W 0 0 0 0 N N N co N v� ca N v� co LU +L+ rl r-I r-I u +L.+ rl +`+ W CAS # 96-12-8 124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/20/2021 BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL BDL BDL BDL BDL SW-2 7/20/2021 BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL BDL BDL BDL BDL SW-3 7/20/2021 BDL BDL BDL BDL BDL BDL NA BDL BDL BDL C3 BDL BDL I BDL BDL BDL BDL 213 Standard L /L NE NE NE NE 488 488 NE NE NE NE NE NE NE NE NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard Qualifiers C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. Page 13 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JULY 2021) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 8260 1 m O c UO O o o W o Contaminant Of Concern ° t s s o o c o o ^ °' O L Q U UM OU N c+o 0 N o 0 u u O 0 U a p o H X N +s+ C N N u H H O O H U O 2 p -O +�+ O i r-I C i N U U M O O CO r-i r-i W 0 r-i r-i . . C�j C c (V G N r-I r-i F- F- r-I r-I 1 � r-I i i X CAS # 591-78-6 74-88-4 75-09-2 108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 108-05-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/20/2021 NA NA BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL C3 BDL NA BDL C3 BDL SW-2 7/20/2021 NA NA BDL I BDL BDL I BDL BDL BLD BDL BDL BDL BDL BDL C3 BDL NA BDL C3 BDL SW-3 7/20/2021 NA NA I BDL I BDL BDL I BDL BDL BLD BDL BDL BDL BDL BDL I C3 BDL NA BDL C3 BDL 213 Standard /L NE NE NE NE NE NE NE 0.7 11 NE NE 2.5 NE NE NE 0.025 NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown BDL Below Laboratory Detection Limit Result Result Exceeds Laboratory Detection Limit Result Result Exceeds 2B Standard Qualifiers C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. Page 14 of 15 TABLE 6 SUMMARY OF MNA CONSTITUENTS (JULY 2021) TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.48 Analytical Method EPA 300.0 EPA 353.2 SM 2320B SM 4500-CI-E SM 4500-S2D SM 5310B U Contaminant Of Concern r M Cn -0 u, to O r- Y+ U 0 `��U to ZZ QHU U to t—O U CAS # 14808-79-8 NA NA 16887-00-6 18496-25-8 7440-44-0 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-2R 7/20/2021 986 J BDL 141,000 10,500 BDL 1,170 B MW-3S 7/20/2021 938 J BDL 167,000 36,500 BDL 3,020 B MW-3D 7/20/2021 858 J BDL 178,000 27,000 BDL 1,460 B MW-4 7/20/2021 662 J BDL 189,000 24,000 BDL 1,250 B MW-6 7/20/2021 5,130 BDL 9,960 J 1,550 BDL 2,280 B 2L Standard/GWP (µg/L) 250,000 10,000 NE 250,000 NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 4) NE = Not Established 5) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL Below Laboratory Detection Limit Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2L Standard or GWP J The identification of the analyte is acceptable; the reported value is an estimate. APPENDIX I Laboratory Analytical Reports and Field Notes aceAnalytical ANALYTICAL REPORT August 03, 2021 Withers & Ravenel Eng. - Standard Sample Delivery Group: L1380832 Samples Received: 07/21/2021 Project Number: 06140180.39 Description: Kernersville Landfill Report To: Laura Elliott 115 MacKenan Drive Cary, NC 27511 Entire Report Reviewed By: 4�41 Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 1 of 51 TABLE OF CONTENTS Cp: Cover Page Tc: Table of Contents Ss: Sample Summary 3 Cn: Case Narrative 6 Sr: Sample Results 7 MW-5 L1380832-01 7 MW-2R L1380832-02 9 MW-3S L1380832-03 12 MW-3D L1380832-04 15 DUPLICATE L1380832-05 18 MW-4 L1380832-06 20 MW-6 L1380832-07 23 SW-1 L1380832-08 26 SW-2 L1380832-09 28 SW-3 L1380832-10 30 TRIP BLANK L1380832-11 32 TRIP BLANK L1380832-12 34 Qc: Quality Control Summary 36 Wet Chemistry by Method 2320 B-2011 36 Wet Chemistry by Method 4500S2 D-2011 37 Wet Chemistry by Method 9056A 38 Wet Chemistry by Method 9060A 40 Metals (ICP) by Method 6010D 41 Volatile Organic Compounds (GC/MS) by Method 8260D 43 GI: Glossary of Terms 48 Al: Accreditations & Locations 49 Sc: Sample Chain of Custody 50 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 2 of 51 MW-5 L1380832-01 GW Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D MW-2R L1380832-02 GW SAMPLE SUMMARY Collected by Laura Elliott Batch WG1712545 WG1710319 WG1716050 Collected date/time Received date/time 07/20/2110:20 07/21/2108:30 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/28/2121:23 07/30/2101:19 CCE Mt. Juliet, TN 1 07/22/2118:55 07/22/2118:55 ACG Mt. Juliet, TN 1 08/02/2121:26 08/02/2121:26 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2111:23 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/2107:19 07/25/2107:19 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:44 07/22/2110:44 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/2120:55 07/21/2120:55 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/2121:33 07/21/2121:33 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:21 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2119:14 07/22/2119:14 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2121:44 08/02/2121:44 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3S L1380832-03 GW Laura Elliott 07/20/2110:25 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/21 07:26 07/25/21 07:26 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:44 07/22/2110:44 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/21 21:44 07/21/21 21:44 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/21 21:51 07/21/21 21:51 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:24 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2119:33 07/22/2119:33 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2122:59 08/02/2122:59 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3D L1380832-04 GW Laura Elliott 07/20/2110:40 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/2107:34 07/25/2107:34 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:45 07/22/2110:45 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/2122:17 07/21/2122:17 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/2122:05 07/21/2122:05 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:27 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2119:52 07/22/2119:52 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2123:18 08/02/2123:18 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time DUPLICATE L1380832-05 GW Laura Elliott 07/20/2109:25 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:35 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2120:11 07/22/2120:11 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2123:37 08/02/2123:37 ACG Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 3 of 51 FP1 FTC 4 Cn FSr rqC F, FAI FSC MW-4 L1380832-06 GW Method Wet Chemistry by Method 2320 B-2011 Wet Chemistry by Method 4500S2 D-2011 Wet Chemistry by Method 9056A Wet Chemistry by Method 9060A Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D MW-6 L1380832-07 GW SAMPLE SUMMARY Collected by Laura Elliott Batch WG1711035 WG1709392 WG1709100 WG1709178 WG1712545 WG1710319 WG1716050 Collected date/time Received date/time 07/20/2111:55 07/21/2108:30 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/25/2107:37 07/25/2107:37 ARD Mt. Juliet, TN 1 07/22/2110:45 07/22/2110:45 SAC Mt. Juliet, TN 1 07/21/2122:50 07/21/2122:50 MCG Mt. Juliet, TN 1 07/21/2122:19 07/21/2122:19 MJA Mt. Juliet, TN 1 07/28/2121:23 07/30/2101:37 CCE Mt. Juliet, TN 1 07/22/2120:29 07/22/2120:29 ACG Mt. Juliet, TN 1 08/02/2123:56 08/02/2123:56 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2109:20 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1711035 1 07/25/2107:41 07/25/2107:41 ARD Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1709392 1 07/22/2110:45 07/22/2110:45 SAC Mt. Juliet, TN Wet Chemistry by Method 9056A WG1709100 1 07/21/2123:06 07/21/2123:06 MCG Mt. Juliet, TN Wet Chemistry by Method 9060A WG1709178 1 07/21/2122:34 07/21/2122:34 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:40 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2120:48 07/22/2120:48 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/03/2100:15 08/03/2100:15 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time SW-1 L1380832-08 GW Laura Elliott 07/20/2112:10 07/21/2108:30 Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D SW-2 L1380832-09 GW Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D SW-3 L1380832-10 GW Batch WG1712545 WG1710319 WG1716050 Batch WG1712545 WG1710319 WG1716050 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/28/2121:23 07/30/2101:43 CCE Mt. Juliet, TN 1 07/22/21 21:07 07/22/21 21:07 ACG Mt. Juliet, TN 1 08/03/2100:34 08/03/2100:34 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2112:00 07/21/2108:30 Dilution Preparation Analysis Analyst Location date/time date/time 1 07/28/2121:23 07/30/2101:45 CCE Mt. Juliet, TN 1 07/22/2121:26 07/22/2121:26 ACG Mt. Juliet, TN 1 08/03/2100:52 08/03/2100:52 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 07/20/2112:05 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1712545 1 07/28/2121:23 07/30/2101:48 CCE Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2121:45 07/22/2121:45 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/03/2101:11 08/03/2101:11 ACG Mt. Juliet, TN Collected by Collected date/time Received date/time TRIP BLANK L1380832-11 GW Laura Elliott 07/20/2100:00 07/21/2108:30 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1710319 1 07/22/2118:17 07/22/2118:17 ACG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1716050 1 08/02/2120:48 08/02/2120:48 ACG Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 4 of 51 FP1 FTC M rCn] FSr RC F, FAI FSC TRIP BLANK L1380832-12 GW Method Volatile Organic Compounds (GC/MS) by Method 8260D Volatile Organic Compounds (GC/MS) by Method 8260D SAMPLE SUMMARY Collected by Laura Elliott Collected date/time Received date/time 07/20/2100:00 07/21/2108:30 Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1710319 1 07/22/2118:36 07/22/2118:36 ACG Mt. Juliet, TN WG1716050 1 08/02/2121:07 08/02/2121:07 ACG Mt. Juliet, TN FP1 FTC M rCn] Fr RC F, FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1380832 08/03/21 15:48 5 of 51 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Heather J Wagner Project Manager FP FC FSS Fr RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 6 of 51 MW-5 Collected date/time: 07/20/21 10:20 SAMPLE RESULTS - 01 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 11.8 4.30 10.0 1 07/30/202101:19 WG1712545 Arsenic U 4.40 10.0 1 07/30/202101:19 WG1712545 Barium 268 0.736 5.00 1 07/30/202101:19 WG1712545 Beryllium 2.93 0.330 2.00 1 07/30/202101:19 WG1712545 Cadmium 1.05 J 0.479 2.00 1 07/30/202101:19 WG1712545 Chromium 11.3 1.40 10.0 1 07/30/202101:19 WG1712545 Cobalt 33.9 0.840 10.0 1 07/30/202101:19 WG1712545 Copper 35.9 3.68 10.0 1 07/30/202101:19 WG1712545 Lead 99.5 2.99 6.00 1 07/30/202101:19 WG1712545 Nickel 6.56 J 1.61 10.0 1 07/30/202101:19 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:19 WG1712545 Silver U 1.54 5.00 1 07/30/202101:19 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:19 WG1712545 Vanadium 110 4.99 20.0 1 07/30/202101:19 WG1712545 Zinc 327 6.52 50.0 1 07/30/202101:19 WG1712545 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time U 11.3 50.0 1 07/22/202118:55 U C3 2.54 50.0 1 07/22/202118:55 U 0.671 10.0 1 07/22/202118:55 U 0.0941 1.00 1 07/22/202118:55 U 0.118 1.00 1 07/22/202118:55 U 0.136 1.00 1 08/02/202121:26 U 0.129 1.00 1 07/22/202118:55 U 0.605 5.00 1 07/22/202118:55 U 0.157 1.00 1 07/22/202118:55 U 0.125 1.00 1 07/22/202118:55 U 0.127 1.00 1 07/22/202118:55 U 0.128 1.00 1 07/22/202118:55 U 0.116 1.00 1 07/22/202118:55 U 0.140 1.00 1 07/22/202118:55 U 0.192 5.00 1 07/22/202118:55 U 0.111 5.00 1 07/22/202118:55 U 0.960 2.50 1 07/22/202118:55 U 0.106 1.00 1 07/22/202118:55 U 0.114 1.00 1 07/22/202118:55 U 0.276 5.00 1 07/22/202118:55 U 0.126 1.00 1 07/22/202118:55 U 0.122 1.00 1 07/22/202118:55 U 0.107 1.00 1 07/22/202118:55 U 0.110 1.00 1 07/22/202118:55 U 0.120 1.00 1 07/22/202118:55 U 0.374 5.00 1 07/22/202118:55 U 0.100 1.00 1 07/22/202118:55 U 0.0819 1.00 1 07/22/202118:55 U C3 0.188 1.00 1 07/22/202118:55 U 0.126 1.00 1 07/22/202118:55 U 0.149 1.00 1 07/22/202118:55 U 0.149 1.00 1 07/22/202118:55 U 0.142 1.00 1 07/22/202118:55 U 0.110 1.00 1 07/22/202118:55 U 0.111 1.00 1 07/22/202118:55 U 0.118 1.00 1 07/22/202118:55 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 7 of 51 MW-5 SAMPLE RESULTS - 01 Collected date/time: 07/20/21 10:20 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene 0.139 J 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U C3 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 109 80.0-120 (S) Toluene-d8 93.4 80.0-120 (S) 4-Bromof/uorobenzene 95.3 77.0-126 (S) 4-Bromof/uorobenzene 107 77.0-126 (S)1,2-Dich/oroethane-d4 106 70.0-130 (S)1,2-Dlch/oroethane-d4 125 70.0-130 Dilution Analysis date / time Batch 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 1 07/22/202118:55 WG1710319 07/22/202118:55 WG1710319 08/02/202121.26 WG1716050 07/22/202118:55 WG1710319 08/02/202121.26 WG1716050 07/22/202118:55 WG1710319 08/02/202121.26 WG1716050 FP1 FTc FSS 4 Cn RC F FAI FSC ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 8 of 51 MW-2R SAMPLE RESULTS - 02 Collected date/time: 07/20/21 11:23 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 141000 8450 Sample Narrative: L1380832-02 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:19 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:44 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 10500 379 1000 1 07/21/202120:55 WG1709100 Nitrate U 48.0 100 1 07/21/202120:55 WG1709100 Sulfate 986 J 594 5000 1 07/21/202120:55 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 1170 B 102 Metals (ICP) by Method 6010D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I 1000 RDL Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 253 0.736 5.00 Beryllium 0.333 J 0.330 2.00 Cadmium 0.504 J 0.479 2.00 Chromium 2.15 J 1.40 10.0 Cobalt 3.95 J 0.840 10.0 Copper U 3.68 10.0 Lead 3.25 J 2.99 6.00 Nickel U 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 6.89 J 4.99 20.0 Zinc 7.27 J 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene 3.07 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 C3 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.39 Dilution Analysis Batch date / time 1 07/21/202121:33 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 1 07/30/202101:21 WG1712545 Dilution Analysis date / time Batch 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 08/02/202121:44 WG1716050 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 9 of 51 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC MW-2R SAMPLE RESULTS - 02 Collected date/time: 07/20/21 11:23 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I sec -Butyl benzene U 0.125 1.00 tert-Butylbenzene U 0.127 1.00 Carbon tetrachloride U 0.128 1.00 Chlorobenzene 0.155 J 0.116 1.00 Chlorodibromomethane U 0.140 1.00 Chloroethane U 0.192 5.00 Chloroform U 0.111 5.00 Chloromethane U 0.960 2.50 2-Chlorotoluene U 0.106 1.00 4-Chlorotoluene U 0.114 1.00 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1,2-Dibromoethane U 0.126 1.00 Dibromomethane U 0.122 1.00 1,2-Dichlorobenzene 0.215 J 0.107 1.00 1,3-Dichlorobenzene U 0.110 1.00 1,4-Dichlorobenzene 4.81 0.120 1.00 Dichlorodifluoromethane U 0.374 5.00 1,1-Dichloroethane 9.24 0.100 1.00 1,2-Dichloroethane 0.520 J 0.0819 1.00 1,1-Dichloroethene U C3 0.188 1.00 cis-1,2-Dichloroethene 26.2 0.126 1.00 trans-1,2-Dichloroethene 0.850 J 0.149 1.00 1,2-Dichloropropane 3.64 0.149 1.00 1,1-Dichloropropene U 0.142 1.00 1,3-Dichloropropane U 0.110 1.00 cis-1,3-Dichloropropene U 0.111 1.00 trans-1,3-Dichloropropene U 0.118 1.00 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether 0.241 J_ 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene 0.421 J 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether 0.313 J_ 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene 0.700 J 0.190 1.00 Trichlorofluoromethane 0.160 C3 J 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride 4.02 C3 0.234 1.00 Dilution Analysis Batch date / time 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 1 07/22/202119:14 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 10 of 51 MW-2R SAMPLE RESULTS - 02 Collected date/time: 07/20/21 11:23 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/22/202119:14 WG1710319 (S) Toluene-d8 108 80.0-120 07/22/202119:14 WG1710319 (S) Toluene-d8 94.9 80.0-120 08/02/202121.44 WG1716050 (S) 4-Bromofluorobenzene 101 77.0-126 07/22/202119:14 WG1710319 (S) 4-Bromofluorobenzene 102 77.0-126 08/02/202121.44 WG1716050 (S)1,2-Dich/oroethone-d4 104 70.0-130 07/22/202119:14 WG1710319 (S) 1,2-Dich/oroethone-d4 111 70.0-130 08/02/202121.44 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 11 of 51 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/20/21 10:25 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 167000 8450 Sample Narrative: L1380832-03 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:26 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:44 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 36500 379 1000 1 07/21/202121:44 WG1709100 Nitrate U 48.0 100 1 07/21/202121:44 WG1709100 Sulfate 938 J 594 5000 1 07/21/202121:44 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 3020 B 102 1000 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Antimony 4.40 J 4.30 10.0 Arsenic U 4.40 10.0 Barium 236 0.736 5.00 Beryllium 0.880 J 0.330 2.00 Cadmium 7.95 0.479 2.00 Chromium 15.6 1.40 10.0 Cobalt 15.5 0.840 10.0 Copper 44.7 3.68 10.0 Lead 12.5 2.99 6.00 Nickel 8.10 J 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium 4.57 B J 4.31 10.0 Vanadium 76.8 4.99 20.0 Zinc 619 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone 34.9 J 11.3 50.0 Acrolein U C3 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.284 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 07/21/202121:51 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 1 07/30/202101:24 WG1712545 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC Dilution Analysis date / time Batch 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 08/02/202122:59 WG1716050 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 1 07/22/202119:33 WG1710319 SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 12 of 51 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/20/21 10:25 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202119:33 WG1710319 tert-Butylbenzene U 0.127 1.00 1 07/22/202119:33 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202119:33 WG1710319 Chlorobenzene 1.55 0.116 1.00 1 07/22/202119:33 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202119:33 WG1710319 Chloroethane 0.410 1_ 0.192 5.00 1 07/22/202119:33 WG1710319 Chloroform U 0.111 5.00 1 07/22/202119:33 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202119:33 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202119:33 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202119:33 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202119:33 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202119:33 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202119:33 WG1710319 1,2-Dichlorobenzene 0.116 J 0.107 1.00 1 07/22/202119:33 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202119:33 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202119:33 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202119:33 WG1710319 1,1-Dichloroethane 0.451 J 0.100 1.00 1 07/22/202119:33 WG1710319 1,2-Dichloroethane 0.272 J 0.0819 1.00 1 07/22/202119:33 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202119:33 WG1710319 cis-1,2-Dichloroethene 0.984 J 0.126 1.00 1 07/22/202119:33 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202119:33 WG1710319 1,2-Dichloropropane 0.394 J 0.149 1.00 1 07/22/202119:33 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202119:33 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202119:33 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202119:33 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202119:33 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202119:33 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202119:33 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202119:33 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202119:33 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202119:33 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202119:33 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202119:33 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202119:33 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202119:33 WG1710319 Methyl tert-butyl ether 0.187 J_ 0.101 1.00 1 07/22/202119:33 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202119:33 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202119:33 WG1710319 Styrene U 0.118 1.00 1 07/22/202119:33 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202119:33 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202119:33 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202119:33 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202119:33 WG1710319 Toluene U 0.278 1.00 1 07/22/202119:33 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202119:33 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202119:33 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202119:33 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202119:33 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202119:33 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202119:33 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202119:33 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202119:33 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202119:33 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202119:33 WG1710319 Vinyl chloride 1.13 C3 0.234 1.00 1 07/22/202119:33 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 13 of 51 MW-3S SAMPLE RESULTS - 03 Collected date/time: 07/20/21 10:25 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I Dilution Analysis date / time Xylenes, Total U 0.174 3.00 1 07/22/202119:33 (S) Toluene-d8 107 80.0-120 07/22/202119:33 (S) Toluene-d8 94.9 80.0-120 08702/202122.59 (S) 4-Bromofluorobenzene 98.3 77.0-126 07/22/202119:33 (S) 4-Bromofluorobenzene 102 77.0-126 08702/202122.59 (S)1,2-Dich/oroethone-d4 107 70.0-130 07/22/202119:33 (S)1,2-Dich/oroethane-d4 111 70.0-130 08702/202122.59 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 Batch WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC DATE/TIME: PAGE: 08/03/2115:48 14 of 51 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/20/21 10:40 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 178000 8450 Sample Narrative: L1380832-04 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:34 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:45 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 27000 379 1000 1 07/21/202122:17 WG1709100 Nitrate U 48.0 100 1 07/21/202122:17 WG1709100 Sulfate 858 J 594 5000 1 07/21/202122:17 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 1460 B 102 1000 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 38.0 0.736 5.00 Beryllium U 0.330 2.00 Cadmium U 0.479 2.00 Chromium U 1.40 10.0 Cobalt U 0.840 10.0 Copper U 3.68 10.0 Lead 3.43 J 2.99 6.00 Nickel U 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 6.52 J 4.99 20.0 Zinc U 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein U C3 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.451 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane U 0.136 1.00 Bromoform U 0.129 1.00 Bromomethane U 0.605 5.00 n-Butylbenzene U 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 07/21/202122:05 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 1 07/30/202101:27 WG1712545 Dilution Analysis Batch date / time 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 08/02/202123:18 WG1716050 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 1 07/22/202119:52 WG1710319 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 15 of 51 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/20/21 10:40 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202119:52 WG1710319 tert-Butylbenzene U 0.127 1.00 1 07/22/202119:52 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202119:52 WG1710319 Chlorobenzene 0.583 J 0.116 1.00 1 07/22/202119:52 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202119:52 WG1710319 Chloroethane 0.362 1_ 0.192 5.00 1 07/22/202119:52 WG1710319 Chloroform U 0.111 5.00 1 07/22/202119:52 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202119:52 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202119:52 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202119:52 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202119:52 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202119:52 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202119:52 WG1710319 1,2-Dichlorobenzene 0.174 J 0.107 1.00 1 07/22/202119:52 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202119:52 WG1710319 1,4-Dichlorobenzene 5.00 0.120 1.00 1 07/22/202119:52 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202119:52 WG1710319 1,1-Dichloroethane 1.26 0.100 1.00 1 07/22/202119:52 WG1710319 1,2-Dichloroethane 0.571 J 0.0819 1.00 1 07/22/202119:52 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202119:52 WG1710319 cis-1,2-Dichloroethene 8.81 0.126 1.00 1 07/22/202119:52 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202119:52 WG1710319 1,2-Dichloropropane 0.977 J_ 0.149 1.00 1 07/22/202119:52 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202119:52 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202119:52 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202119:52 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202119:52 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202119:52 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202119:52 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202119:52 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202119:52 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202119:52 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202119:52 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202119:52 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202119:52 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202119:52 WG1710319 Methyl tert-butyl ether 0.360 J_ 0.101 1.00 1 07/22/202119:52 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202119:52 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202119:52 WG1710319 Styrene U 0.118 1.00 1 07/22/202119:52 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202119:52 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202119:52 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202119:52 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202119:52 WG1710319 Toluene U 0.278 1.00 1 07/22/202119:52 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202119:52 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202119:52 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202119:52 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202119:52 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202119:52 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202119:52 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202119:52 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202119:52 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202119:52 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202119:52 WG1710319 Vinyl chloride 5.74 C3 0.234 1.00 1 07/22/202119:52 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 16 of 51 MW-3D SAMPLE RESULTS - 04 Collected date/time: 07/20/21 10:40 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I Dilution Analysis date / time Xylenes, Total 0.390 J_ 0.174 3.00 1 07/22/202119:52 (S) Toluene-d8 107 80.0-120 07/22/202119:52 (S) Toluene-d8 95.9 80.0-120 08702/202123:18 (S) 4-Bromofluorobenzene 98.5 77.0-126 07/22/202119:52 (S) 4-Bromofluorobenzene 102 77.0-126 08702/202123:18 (S)1,2-Dich/oroethone-d4 107 70.0-130 07/22/202119:52 (S)1,2-Dich/oroethane-d4 108 70.0-130 08702/202123:18 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 Batch WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC DATE/TIME: PAGE: 08/03/21 15:48 17 of 51 DUPLICATE Collected date/time: 07/20/21 09:25 SAMPLE RESULTS - 05 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 5.65 J 4.30 10.0 1 07/30/202101:35 WG1712545 Arsenic U 4.40 10.0 1 07/30/202101:35 WG1712545 Barium 49.2 0.736 5.00 1 07/30/202101:35 WG1712545 Beryllium U 0.330 2.00 1 07/30/202101:35 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:35 WG1712545 Chromium U 1.40 10.0 1 07/30/202101:35 WG1712545 Cobalt U 0.840 10.0 1 07/30/202101:35 WG1712545 Copper U 3.68 10.0 1 07/30/202101:35 WG1712545 Lead U 2.99 6.00 1 07/30/202101:35 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:35 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:35 WG1712545 Silver U 1.54 5.00 1 07/30/202101:35 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:35 WG1712545 Vanadium 7.49 J 4.99 20.0 1 07/30/202101:35 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:35 WG1712545 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time U 11.3 50.0 1 07/22/202120:11 U C3 2.54 50.0 1 07/22/202120:11 U 0.671 10.0 1 07/22/202120:11 0.472 J 0.0941 1.00 1 07/22/202120:11 U 0.118 1.00 1 07/22/202120:11 U 0.136 1.00 1 08/02/202123:37 U 0.129 1.00 1 07/22/202120:11 U 0.605 5.00 1 07/22/202120:11 U 0.157 1.00 1 07/22/202120:11 U 0.125 1.00 1 07/22/202120:11 U 0.127 1.00 1 07/22/202120:11 U 0.128 1.00 1 07/22/202120:11 0.566 J 0.116 1.00 1 07/22/202120:11 U 0.140 1.00 1 07/22/202120:11 0.334 J 0.192 5.00 1 07/22/202120:11 U 0.111 5.00 1 07/22/202120:11 U 0.960 2.50 1 07/22/202120:11 U 0.106 1.00 1 07/22/202120:11 U 0.114 1.00 1 07/22/202120:11 U 0.276 5.00 1 07/22/202120:11 U 0.126 1.00 1 07/22/202120:11 U 0.122 1.00 1 07/22/202120:11 0.168 J 0.107 1.00 1 07/22/202120:11 U 0.110 1.00 1 07/22/202120:11 4.87 0.120 1.00 1 07/22/202120:11 U 0.374 5.00 1 07/22/202120:11 1.19 0.100 1.00 1 07/22/202120:11 0.530 J 0.0819 1.00 1 07/22/202120:11 U C3 0.188 1.00 1 07/22/202120:11 7.58 0.126 1.00 1 07/22/202120:11 U 0.149 1.00 1 07/22/202120:11 0.959 J 0.149 1.00 1 07/22/202120:11 U 0.142 1.00 1 07/22/202120:11 U 0.110 1.00 1 07/22/202120:11 U 0.111 1.00 1 07/22/202120:11 U 0.118 1.00 1 07/22/202120:11 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 18 of 51 DUPLICATE SAMPLE RESULTS - 05 Collected date/time: 07/20/21 09:25 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether 0.303 J_ 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride 5.73 C3 0.234 1.00 Xylenes, Total 0.936 J 0.174 3.00 (S) Toluene-d8 113 80.0-120 (S) Toluene-d8 95.1 80.0-120 (S) 4-Bromof/uorobenzene 92.1 77.0-126 (S) 4-Bromof/uorobenzene 104 77.0-126 (S) 1,2-Dich/oroethane-d4 104 70.0-130 (S)1,2-Dlch/oroethane-d4 113 70.0-130 Dilution Analysis date / time 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 07/22/202120:11 08/02/202123:37 07/22/202120:11 08/02/202123:37 07/22/202120:11 08/02/202123:37 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC I q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 19 of 51 ------------ MW-4 SAMPLE RESULTS - 06 Collected date/time: 07/20/21 11:55 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 189000 8450 Sample Narrative: L1380832-06 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:37 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:45 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 24000 379 1000 1 07/21/202122:50 WG1709100 Nitrate U 48.0 100 1 07/21/202122:50 WG1709100 Sulfate 662 J 594 5000 1 07/21/202122:50 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 1250 B 102 Metals (ICP) by Method 6010D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I 1000 RDL Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 127 0.736 5.00 Beryllium U 0.330 2.00 Cadmium 0.580 J 0.479 2.00 Chromium 12.1 1.40 10.0 Cobalt 3.50 J 0.840 10.0 Copper 6.32 J 3.68 10.0 Lead 5.96 J 2.99 6.00 Nickel 3.84 J 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 17.2 J 4.99 20.0 Zinc 20.1 J 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene 0.384 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 C3 2.54 50.0 0.671 10.0 J 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.39 Dilution Analysis Batch date / time 1 07/21/202122:19 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 1 07/30/202101:37 WG1712545 Dilution Analysis Batch date / time 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 08/02/202123:56 WG1716050 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 1 07/22/202120:29 WG1710319 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 20 of 51 MW-4 SAMPLE RESULTS - 06 Collected date/time: 07/20/21 11:55 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202120:29 WG1710319 tert-Butylbenzene U 0.127 1.00 1 07/22/202120:29 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202120:29 WG1710319 Chlorobenzene 0.163 J 0.116 1.00 1 07/22/202120:29 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202120:29 WG1710319 Chloroethane 0.606 1_ 0.192 5.00 1 07/22/202120:29 WG1710319 Chloroform U 0.111 5.00 1 07/22/202120:29 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202120:29 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202120:29 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202120:29 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202120:29 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202120:29 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202120:29 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202120:29 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202120:29 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202120:29 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202120:29 WG1710319 1,1-Dichloroethane 1.15 0.100 1.00 1 07/22/202120:29 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202120:29 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202120:29 WG1710319 cis-1,2-Dichloroethene 14.4 0.126 1.00 1 07/22/202120:29 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202120:29 WG1710319 1,2-Dichloropropane 0.286 J_ 0.149 1.00 1 07/22/202120:29 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202120:29 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202120:29 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202120:29 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202120:29 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202120:29 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202120:29 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202120:29 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202120:29 WG1710319 Isopropylbenzene 0.118 J 0.105 1.00 1 07/22/202120:29 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202120:29 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202120:29 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202120:29 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202120:29 WG1710319 Methyl tert-butyl ether 0.243 J_ 0.101 1.00 1 07/22/202120:29 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202120:29 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202120:29 WG1710319 Styrene U 0.118 1.00 1 07/22/202120:29 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202120:29 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202120:29 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202120:29 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202120:29 WG1710319 Toluene U 0.278 1.00 1 07/22/202120:29 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202120:29 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202120:29 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202120:29 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202120:29 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202120:29 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202120:29 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202120:29 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202120:29 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202120:29 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202120:29 WG1710319 Vinyl chloride 9.62 C3 0.234 1.00 1 07/22/202120:29 WG1710319 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 21 of 51 MW-4 SAMPLE RESULTS - 06 Collected date/time: 07/20/21 11:55 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/22/202120:29 WG1710319 (S) Toluene-d8 108 80.0-120 07/22/202120:29 WG1710319 (S) Toluene-d8 94.3 80.0-120 08/02/202123:56 WG1716050 (S) 4-Bromofluorobenzene 99.4 77.0-126 07/22/202120.29 WG1710319 (S) 4-Bromofluorobenzene 100 77.0-126 08/02/202123:56 WG1716050 (S) 1,2-Dich/oroethone-d4 107 70.0-130 07/22/202120.29 WG1710319 (S) 1,2-Dich/oroethone-d4 109 70.0-130 08/02/202123:56 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 22 of 51 ------------ MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/20/21 09:20 L1380832 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 9960 J 8450 Sample Narrative: L1380832-07 WG1711035: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL Analyte ug/I ug/I Sulfide U 25.0 Wet Chemistry by Method 9056A RDL Dilution Analysis Batch ug/I date / time 20000 1 07/25/202107:41 WG1711035 RDL Dilution Analysis Batch ug/I date / time 50.0 1 07/22/202110:45 WG1709392 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 1550 379 1000 1 07/21/202123:06 WG1709100 Nitrate U 48.0 100 1 07/21/202123:06 WG1709100 Sulfate 5130 594 5000 1 07/21/202123:06 WG1709100 Wet Chemistry by Method 9060A Result Qualifier MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 2280 B 102 Metals (ICP) by Method 6010D Result Qualifier MDL Analyte ug/I ug/I RDL ug/I 1000 RDL Antimony U 4.30 10.0 Arsenic U 4.40 10.0 Barium 50.3 0.736 5.00 Beryllium U 0.330 2.00 Cadmium U 0.479 2.00 Chromium 1.99 J 1.40 10.0 Cobalt 1.12 J 0.840 10.0 Copper U 3.68 10.0 Lead 5.68 J 2.99 6.00 Nickel U 1.61 10.0 Selenium U 7.35 10.0 Silver U 1.54 5.00 Thallium U 4.31 10.0 Vanadium 6.69 J 4.99 20.0 Zinc 7.56 J 6.52 50.0 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL ug/I ug/I 11.3 50.0 C3 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 PROJECT: 06140180.39 Dilution Analysis Batch date / time 1 07/21/202122:34 WG1709178 Dilution Analysis Batch date / time 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 1 07/30/202101:40 WG1712545 Dilution Analysis Batch date / time 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 08/03/202100:15 WG1716050 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 1 07/22/202120:48 WG1710319 FP1 FTc FSS 4 Cn RC 7G1 FAI FSC SDG: DATE/TIME: PAGE: L1380832 08/03/21 15:48 23 of 51 MW-6 SAMPLE Collected date/time: 07/20/21 09:20 Volatile Organic Compounds (GC/MS) by Method 8260D RESULTS - 07 L1380832 Result Qualifier MDL RDL Dilution Analysis Batch FP1 Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 07/22/202120:48 WG1710319 FTc tert-Butylbenzene U 0.127 1.00 1 07/22/202120:48 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202120:48 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202120:48 WG1710319 FSS Chlorodibromomethane U 0.140 1.00 1 07/22/202120:48 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202120:48 WG1710319 4 Cn Chloroform U 0.111 5.00 1 07/22/202120:48 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202120:48 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202120:48 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202120:48 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202120:48 WG1710319 RC 1,2-Dibromoethane U 0.126 1.00 1 07/22/202120:48 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202120:48 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202120:48 WG1710319 GI 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202120:48 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202120:48 WG1710319 FAI Dichlorodifluoromethane U 0.374 5.00 1 07/22/202120:48 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202120:48 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202120:48 WG1710319 FSC 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202120:48 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202120:48 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202120:48 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202120:48 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202120:48 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202120:48 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202120:48 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202120:48 WG1710319 2,2-Dichloropropane U 0.161 1.00 1 07/22/202120:48 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202120:48 WG1710319 Ethylbenzene 1.02 0.137 1.00 1 07/22/202120:48 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202120:48 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202120:48 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202120:48 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202120:48 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202120:48 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202120:48 WG1710319 Methyl tert-butyl ether U 0.101 1.00 1 07/22/202120:48 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202120:48 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202120:48 WG1710319 Styrene U 0.118 1.00 1 07/22/202120:48 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202120:48 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202120:48 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202120:48 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202120:48 WG1710319 Toluene 7.10 0.278 1.00 1 07/22/202120:48 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202120:48 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202120:48 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202120:48 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202120:48 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202120:48 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202120:48 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202120:48 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202120:48 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202120:48 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202120:48 WG1710319 Vinyl chloride U C3 0.234 1.00 1 07/22/202120:48 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 24 of 51 MW-6 SAMPLE RESULTS - 07 Collected date/time: 07/20/21 09:20 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result Qualifier MDL ug/I ug/I RDL ug/I Dilution Analysis date / time Batch Xylenes, Total U 0.174 3.00 1 07/22/202120:48 WG1710319 (S) Toluene-d8 107 80.0-120 07/22/202120.48 WG1710319 (S) Toluene-d8 94.5 80.0-120 08703/202100.15 WG1716050 (S) 4-Bromofluorobenzene 99.4 77.0-126 07/22/202120.48 WG1710319 (S) 4-Bromofluorobenzene 101 77.0-126 08703/202100.15 WG1716050 (S) 1,2-Dich/oroethone-d4 107 70.0-130 07/22/202120.48 WG1710319 (S)1,2-Dich/oroethone-d4 115 70.0-130 08703/202100.15 WG1716050 FP1 FTc FSS 4 Cn RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 25 of 51 SW-1 SAMPLE RESULTS - 08 Collected date/time: 07/20/21 12:10 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Cp Analyte ug/I ug/I ug/I date / time Antimony 4.31 J 4.30 10.0 1 07/30/202101:43 WG1712545 F Arsenic U 4.40 10.0 1 07/30/202101:43 WG1712545 Barium 36.6 0.736 5.00 1 07/30/202101:43 WG1712545 3 SS Beryllium U 0.330 2.00 1 07/30/202101:43 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:43 WG1712545 Chromium 1.71 J 1.40 10.0 1 07/30/202101:43 WG1712545 4 Cfl Cobalt U 0.840 10.0 1 07/30/202101:43 WG1712545 Copper U 3.68 10.0 1 07/30/202101:43 WG1712545 Lead 3.02 J 2.99 6.00 1 07/30/202101:43 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:43 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:43 WG1712545 6 QC Silver U 1.54 5.00 1 07/30/202101:43 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:43 WG1712545 7G1 Vanadium U 4.99 20.0 1 07/30/202101:43 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:43 WG1712545 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/22/202121:07 WG1710319 Acrolein U C3 2.54 50.0 1 07/22/202121:07 WG1710319 Acrylonitrile U 0.671 10.0 1 07/22/202121:07 WG1710319 Benzene U 0.0941 1.00 1 07/22/202121:07 WG1710319 Bromobenzene U 0.118 1.00 1 07/22/202121:07 WG1710319 Bromodichloromethane U 0.136 1.00 1 08/03/202100:34 WG1716050 Bromoform U 0.129 1.00 1 07/22/202121:07 WG1710319 Bromomethane U 0.605 5.00 1 07/22/202121:07 WG1710319 n-Butylbenzene U 0.157 1.00 1 07/22/202121:07 WG1710319 sec -Butyl benzene U 0.125 1.00 1 07/22/202121:07 WG1710319 ter[-Butylbenzene U 0.127 1.00 1 07/22/202121:07 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202121:07 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202121:07 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202121:07 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202121:07 WG1710319 Chloroform U 0.111 5.00 1 07/22/202121:07 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202121:07 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202121:07 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202121:07 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202121:07 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202121:07 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202121:07 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202121:07 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202121:07 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202121:07 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202121:07 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202121:07 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202121:07 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202121:07 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202121:07 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202121:07 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202121:07 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202121:07 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202121:07 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202121:07 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202121:07 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 26 of 51 SW-1 SAMPLE RESULTS - 08 Collected date/time: 07/20/21 12:10 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U C3 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 114 80.0-120 (S) Toluene-d8 95.5 80.0-120 (S) 4-Bromof/uorobenzene 92.4 77.0-126 (S) 4-Bromof/uorobenzene 103 77.0-126 (S) 1,2-Dich/oroethane-d4 101 70.0-130 (S)1,2-Dlch/oroethane-d4 122 70.0-130 Dilution Analysis Batch date / time 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 1 07/22/202121:07 WG1710319 07/22/202121:07 WG1710319 08103120210034 WG1716050 07/22/202121:07 WG1710319 08103120210034 WG1716050 07/22/202121:07 WG1710319 08103120210034 WG1716050 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 27 of 51 SW-2 SAMPLE RESULTS - 09 Collected date/time: 07/20/21 12:00 L1380832 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Cp Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/30/202101:45 WG1712545 F Arsenic U 4.40 10.0 1 07/30/202101:45 WG1712545 Barium 41.1 0.736 5.00 1 07/30/202101:45 WG1712545 3 SS Beryllium U 0.330 2.00 1 07/30/202101:45 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:45 WG1712545 Chromium 1.69 J 1.40 10.0 1 07/30/202101:45 WG1712545 4 Cfl Cobalt 1.44 J 0.840 10.0 1 07/30/202101:45 WG1712545 Copper U 3.68 10.0 1 07/30/202101:45 WG1712545 Lead U 2.99 6.00 1 07/30/202101:45 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:45 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:45 WG1712545 6 QC Silver U 1.54 5.00 1 07/30/202101:45 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:45 WG1712545 7G1 Vanadium U 4.99 20.0 1 07/30/202101:45 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:45 WG1712545 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/22/202121:26 WG1710319 Acrolein U C3 2.54 50.0 1 07/22/202121:26 WG1710319 Acrylonitrile U 0.671 10.0 1 07/22/202121:26 WG1710319 Benzene U 0.0941 1.00 1 07/22/202121:26 WG1710319 Bromobenzene U 0.118 1.00 1 07/22/202121:26 WG1710319 Bromodichloromethane U 0.136 1.00 1 08/03/202100:52 WG1716050 Bromoform U 0.129 1.00 1 07/22/202121:26 WG1710319 Bromomethane U 0.605 5.00 1 07/22/202121:26 WG1710319 n-Butylbenzene U 0.157 1.00 1 07/22/202121:26 WG1710319 sec -Butyl benzene U 0.125 1.00 1 07/22/202121:26 WG1710319 ter[-Butylbenzene U 0.127 1.00 1 07/22/202121:26 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202121:26 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202121:26 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202121:26 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202121:26 WG1710319 Chloroform U 0.111 5.00 1 07/22/202121:26 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202121:26 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202121:26 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202121:26 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202121:26 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202121:26 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202121:26 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202121:26 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202121:26 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202121:26 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202121:26 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202121:26 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202121:26 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202121:26 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202121:26 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202121:26 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202121:26 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202121:26 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202121:26 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202121:26 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202121:26 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 28 of 51 SW-2 SAMPLE RESULTS - 09 Collected date/time: 07/20/21 12:00 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 2,2-Dichloropropane U 0.161 1.00 1 07/22/202121:26 WG1710319 Di -isopropyl ether U 0.105 1.00 1 07/22/202121:26 WG1710319 Ethylbenzene U 0.137 1.00 1 07/22/202121:26 WG1710319 Hexachloro-1,3-butadiene U 0.337 1.00 1 07/22/202121:26 WG1710319 Isopropylbenzene U 0.105 1.00 1 07/22/202121:26 WG1710319 p-Isopropyltoluene U 0.120 1.00 1 07/22/202121:26 WG1710319 2-Butanone (MEK) U 1.19 10.0 1 07/22/202121:26 WG1710319 Methylene Chloride U 0.430 5.00 1 07/22/202121:26 WG1710319 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 07/22/202121:26 WG1710319 Methyl tert-butyl ether U 0.101 1.00 1 07/22/202121:26 WG1710319 Naphthalene U 1.00 5.00 1 07/22/202121:26 WG1710319 n-Propylbenzene U 0.0993 1.00 1 07/22/202121:26 WG1710319 Styrene U 0.118 1.00 1 07/22/202121:26 WG1710319 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 07/22/202121:26 WG1710319 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 07/22/202121:26 WG1710319 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 1 07/22/202121:26 WG1710319 Tetrachloroethene U 0.300 1.00 1 07/22/202121:26 WG1710319 Toluene U 0.278 1.00 1 07/22/202121:26 WG1710319 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/22/202121:26 WG1710319 1,2,4-Trichlorobenzene U 0.481 1.00 1 07/22/202121:26 WG1710319 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202121:26 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202121:26 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202121:26 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202121:26 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202121:26 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202121:26 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202121:26 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202121:26 WG1710319 Vinyl chloride U C3 0.234 1.00 1 07/22/202121:26 WG1710319 Xylenes, Total U 0.174 3.00 1 07/22/202121:26 WG1710319 (S) Toluene-d8 109 80.0-120 07/22/202121:26 WG1710319 (S) Toluene-d8 93.9 80.0-120 08/03/202100.52 WG1716050 (S) 4-Bromof/uorobenzene 96.4 77.0-126 07/22/202121:26 WG1710319 (S) 4-Bromof/uorobenzene 102 77.0-126 08/03/202100.52 WG1716050 (S 1,2-Dich/oroethane-d4 104 70.0-130 07/22/202121:26 WG1710319 (S)1,2-Dlch/oroethone-d4 125 70.0-130 08/03/202100.52 WG1716050 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 29 of 51 SW-3 SAMPLE RESULTS - 10 Collected date/time: 07/20/21 12:05 L1380832 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 07/30/202101:48 WG1712545 F Arsenic U 4.40 10.0 1 07/30/202101:48 WG1712545 Barium 38.4 0.736 5.00 1 07/30/202101:48 WG1712545 3 SS Beryllium U 0.330 2.00 1 07/30/202101:48 WG1712545 Cadmium U 0.479 2.00 1 07/30/202101:48 WG1712545 Chromium U 1.40 10.0 1 07/30/202101:48 WG1712545 4 Cfl Cobalt 0.866 J 0.840 10.0 1 07/30/202101:48 WG1712545 Copper U 3.68 10.0 1 07/30/202101:48 WG1712545 Lead U 2.99 6.00 1 07/30/202101:48 WG1712545 Nickel U 1.61 10.0 1 07/30/202101:48 WG1712545 Selenium U 7.35 10.0 1 07/30/202101:48 WG1712545 6 QC Silver U 1.54 5.00 1 07/30/202101:48 WG1712545 Thallium U 4.31 10.0 1 07/30/202101:48 WG1712545 7G1 Vanadium 6.86 J 4.99 20.0 1 07/30/202101:48 WG1712545 Zinc U 6.52 50.0 1 07/30/202101:48 WG1712545 Al r Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 07/22/202121:45 WG1710319 Acrolein U C3 2.54 50.0 1 07/22/202121:45 WG1710319 Acrylonitrile U 0.671 10.0 1 07/22/202121:45 WG1710319 Benzene U 0.0941 1.00 1 07/22/202121:45 WG1710319 Bromobenzene U 0.118 1.00 1 07/22/202121:45 WG1710319 Bromodichloromethane U 0.136 1.00 1 08/03/202101:11 WG1716050 Bromoform U 0.129 1.00 1 07/22/202121:45 WG1710319 Bromomethane U 0.605 5.00 1 07/22/202121:45 WG1710319 n-Butylbenzene U 0.157 1.00 1 07/22/202121:45 WG1710319 sec -Butyl benzene U 0.125 1.00 1 07/22/202121:45 WG1710319 ter[-Butylbenzene U 0.127 1.00 1 07/22/202121:45 WG1710319 Carbon tetrachloride U 0.128 1.00 1 07/22/202121:45 WG1710319 Chlorobenzene U 0.116 1.00 1 07/22/202121:45 WG1710319 Chlorodibromomethane U 0.140 1.00 1 07/22/202121:45 WG1710319 Chloroethane U 0.192 5.00 1 07/22/202121:45 WG1710319 Chloroform U 0.111 5.00 1 07/22/202121:45 WG1710319 Chloromethane U 0.960 2.50 1 07/22/202121:45 WG1710319 2-Chlorotoluene U 0.106 1.00 1 07/22/202121:45 WG1710319 4-Chlorotoluene U 0.114 1.00 1 07/22/202121:45 WG1710319 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 07/22/202121:45 WG1710319 1,2-Dibromoethane U 0.126 1.00 1 07/22/202121:45 WG1710319 Dibromomethane U 0.122 1.00 1 07/22/202121:45 WG1710319 1,2-Dichlorobenzene U 0.107 1.00 1 07/22/202121:45 WG1710319 1,3-Dichlorobenzene U 0.110 1.00 1 07/22/202121:45 WG1710319 1,4-Dichlorobenzene U 0.120 1.00 1 07/22/202121:45 WG1710319 Dichlorodifluoromethane U 0.374 5.00 1 07/22/202121:45 WG1710319 1,1-Dichloroethane U 0.100 1.00 1 07/22/202121:45 WG1710319 1,2-Dichloroethane U 0.0819 1.00 1 07/22/202121:45 WG1710319 1,1-Dichloroethene U C3 0.188 1.00 1 07/22/202121:45 WG1710319 cis-1,2-Dichloroethene U 0.126 1.00 1 07/22/202121:45 WG1710319 trans-1,2-Dichloroethene U 0.149 1.00 1 07/22/202121:45 WG1710319 1,2-Dichloropropane U 0.149 1.00 1 07/22/202121:45 WG1710319 1,1-Dichloropropene U 0.142 1.00 1 07/22/202121:45 WG1710319 1,3-Dichloropropane U 0.110 1.00 1 07/22/202121:45 WG1710319 cis-1,3-Dichloropropene U 0.111 1.00 1 07/22/202121:45 WG1710319 trans-1,3-Dichloropropene U 0.118 1.00 1 07/22/202121:45 WG1710319 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 30 of 51 SW-3 SAMPLE RESULTS - 10 Collected date/time: 07/20/21 12:05 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I 2,2-Dichloropropane U 0.161 1.00 Di -isopropyl ether U 0.105 1.00 Ethylbenzene U 0.137 1.00 Hexachloro-1,3-butadiene U 0.337 1.00 Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 1,1,2-Trichlorotrifluoroethane U C3 0.180 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U C3 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,4-Trimethylbenzene U 0.322 1.00 1,2,3-Trimethyl benzene U 0.104 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U C3 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 109 80.0-120 (S) Toluene-d8 96.0 80.0-120 (S) 4-Bromof/uorobenzene 97.2 77.0-126 (S) 4-Bromof/uorobenzene 104 77.0-126 (S)1,2-Dich/oroethane-d4 105 70.0-130 (S) 1,2-Dlch/oroethane-d4 121 70.0-130 Dilution Analysis date / time 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121:45 07/22/202121.45 081031202101:11 07/22/202121.45 081031202101:11 07/22/202121.45 081031202101:11 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC I q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 31 of 51 TRIP BLANK Collected date/time: 07/20/21 00:00 SAMPLE RESULTS - 11 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene Result ug/I U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 11.3 50.0 1 07/22/202118:17 WG1710319 C3 2.54 50.0 1 07/22/202118:17 WG1710319 0.671 10.0 1 07/22/202118:17 WG1710319 0.0941 1.00 1 07/22/202118:17 WG1710319 0.118 1.00 1 07/22/202118:17 WG1710319 0.136 1.00 1 08/02/202120:48 WG1716050 0.129 1.00 1 07/22/202118:17 WG1710319 0.605 5.00 1 07/22/202118:17 WG1710319 0.157 1.00 1 07/22/202118:17 WG1710319 0.125 1.00 1 07/22/202118:17 WG1710319 0.127 1.00 1 07/22/202118:17 WG1710319 0.128 1.00 1 07/22/202118:17 WG1710319 0.116 1.00 1 07/22/202118:17 WG1710319 0.140 1.00 1 07/22/202118:17 WG1710319 0.192 5.00 1 07/22/202118:17 WG1710319 0.111 5.00 1 07/22/202118:17 WG1710319 0.960 2.50 1 07/22/202118:17 WG1710319 0.106 1.00 1 07/22/202118:17 WG1710319 0.114 1.00 1 07/22/202118:17 WG1710319 0.276 5.00 1 07/22/202118:17 WG1710319 0.126 1.00 1 07/22/202118:17 WG1710319 0.122 1.00 1 07/22/202118:17 WG1710319 0.107 1.00 1 07/22/202118:17 WG1710319 0.110 1.00 1 07/22/202118:17 WG1710319 0.120 1.00 1 07/22/202118:17 WG1710319 0.374 5.00 1 07/22/202118:17 WG1710319 0.100 1.00 1 07/22/202118:17 WG1710319 0.0819 1.00 1 07/22/202118:17 WG1710319 C3 0.188 1.00 1 07/22/202118:17 WG1710319 0.126 1.00 1 07/22/202118:17 WG1710319 0.149 1.00 1 07/22/202118:17 WG1710319 0.149 1.00 1 07/22/202118:17 WG1710319 0.142 1.00 1 07/22/202118:17 WG1710319 0.110 1.00 1 07/22/202118:17 WG1710319 0.111 1.00 1 07/22/202118:17 WG1710319 0.118 1.00 1 07/22/202118:17 WG1710319 0.161 1.00 1 07/22/202118:17 WG1710319 0.105 1.00 1 07/22/202118:17 WG1710319 0.137 1.00 1 07/22/202118:17 WG1710319 0.337 1.00 1 07/22/202118:17 WG1710319 0.105 1.00 1 07/22/202118:17 WG1710319 0.120 1.00 1 07/22/202118:17 WG1710319 1.19 10.0 1 07/22/202118:17 WG1710319 0.430 5.00 1 07/22/202118:17 WG1710319 0.478 10.0 1 07/22/202118:17 WG1710319 0.101 1.00 1 07/22/202118:17 WG1710319 1.00 5.00 1 07/22/202118:17 WG1710319 0.0993 1.00 1 07/22/202118:17 WG1710319 0.118 1.00 1 07/22/202118:17 WG1710319 0.147 1.00 1 07/22/202118:17 WG1710319 0.133 1.00 1 07/22/202118:17 WG1710319 C3 0.180 1.00 1 07/22/202118:17 WG1710319 0.300 1.00 1 07/22/202118:17 WG1710319 0.278 1.00 1 07/22/202118:17 WG1710319 0.230 1.00 1 07/22/202118:17 WG1710319 0.481 1.00 1 07/22/202118:17 WG1710319 FP1 FTc FSS 4 Cn Rc F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 32 of 51 TRIP BLANK SAMPLE RESULTS - 11 Collected date/time: 07/20/21 00:00 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202118:17 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202118:17 Trichloroethene U 0.190 1.00 1 07/22/202118:17 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202118:17 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202118:17 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202118:17 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202118:17 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202118:17 Vinyl chloride U C3 0.234 1.00 1 07/22/202118:17 Xylenes, Total U 0.174 3.00 1 07/22/202118:17 (S Toluene-d8 110 80.0-120 071221202118:17 (S) Toluene-d8 96.3 80.0-120 08/02/202120.48 (S 4-Bromofluorobenzene 96.6 77.0-126 07/22/202118:17 (S) 4-Bromofluorobenzene 102 77.0-126 08/02/202120.48 (S)1,2-Dich/oroethone-d4 107 70.0-130 07/22/202118:17 (S)1,2-Dich/oroethone-d4 112 70.0-130 08/02/202120.48 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 Batch WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1710319 WG1716050 WG1710319 WG1716050 WG1710319 WG1716050 FP1 FTc FSS 4 Cn RC F FAI FSC DATE/TIME: PAGE: 08/03/21 15:48 33 of 51 TRIP BLANK Collected date/time: 07/20/21 00:00 SAMPLE RESULTS - 12 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene Result ug/I U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 11.3 50.0 1 07/22/202118:36 WG1710319 C3 2.54 50.0 1 07/22/202118:36 WG1710319 0.671 10.0 1 07/22/202118:36 WG1710319 0.0941 1.00 1 07/22/202118:36 WG1710319 0.118 1.00 1 07/22/202118:36 WG1710319 0.136 1.00 1 08/02/202121:07 WG1716050 0.129 1.00 1 07/22/202118:36 WG1710319 0.605 5.00 1 07/22/202118:36 WG1710319 0.157 1.00 1 07/22/202118:36 WG1710319 0.125 1.00 1 07/22/202118:36 WG1710319 0.127 1.00 1 07/22/202118:36 WG1710319 0.128 1.00 1 07/22/202118:36 WG1710319 0.116 1.00 1 07/22/202118:36 WG1710319 0.140 1.00 1 07/22/202118:36 WG1710319 0.192 5.00 1 07/22/202118:36 WG1710319 0.111 5.00 1 07/22/202118:36 WG1710319 0.960 2.50 1 07/22/202118:36 WG1710319 0.106 1.00 1 07/22/202118:36 WG1710319 0.114 1.00 1 07/22/202118:36 WG1710319 0.276 5.00 1 07/22/202118:36 WG1710319 0.126 1.00 1 07/22/202118:36 WG1710319 0.122 1.00 1 07/22/202118:36 WG1710319 0.107 1.00 1 07/22/202118:36 WG1710319 0.110 1.00 1 07/22/202118:36 WG1710319 0.120 1.00 1 07/22/202118:36 WG1710319 0.374 5.00 1 07/22/202118:36 WG1710319 0.100 1.00 1 07/22/202118:36 WG1710319 0.0819 1.00 1 07/22/202118:36 WG1710319 C3 0.188 1.00 1 07/22/202118:36 WG1710319 0.126 1.00 1 07/22/202118:36 WG1710319 0.149 1.00 1 07/22/202118:36 WG1710319 0.149 1.00 1 07/22/202118:36 WG1710319 0.142 1.00 1 07/22/202118:36 WG1710319 0.110 1.00 1 07/22/202118:36 WG1710319 0.111 1.00 1 07/22/202118:36 WG1710319 0.118 1.00 1 07/22/202118:36 WG1710319 0.161 1.00 1 07/22/202118:36 WG1710319 0.105 1.00 1 07/22/202118:36 WG1710319 0.137 1.00 1 07/22/202118:36 WG1710319 0.337 1.00 1 07/22/202118:36 WG1710319 0.105 1.00 1 07/22/202118:36 WG1710319 0.120 1.00 1 07/22/202118:36 WG1710319 1.19 10.0 1 07/22/202118:36 WG1710319 0.430 5.00 1 07/22/202118:36 WG1710319 0.478 10.0 1 07/22/202118:36 WG1710319 0.101 1.00 1 07/22/202118:36 WG1710319 1.00 5.00 1 07/22/202118:36 WG1710319 0.0993 1.00 1 07/22/202118:36 WG1710319 0.118 1.00 1 07/22/202118:36 WG1710319 0.147 1.00 1 07/22/202118:36 WG1710319 0.133 1.00 1 07/22/202118:36 WG1710319 C3 0.180 1.00 1 07/22/202118:36 WG1710319 0.300 1.00 1 07/22/202118:36 WG1710319 0.278 1.00 1 07/22/202118:36 WG1710319 0.230 1.00 1 07/22/202118:36 WG1710319 0.481 1.00 1 07/22/202118:36 WG1710319 FP1 FTc FSS 4 Cn Rc I q, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 34 of 51 TRIP BLANK SAMPLE RESULTS - 12 Collected date/time: 07/20/21 00:00 L1380832 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.149 1.00 1 07/22/202118:36 WG1710319 1,1,2-Trichloroethane U 0.158 1.00 1 07/22/202118:36 WG1710319 Trichloroethene U 0.190 1.00 1 07/22/202118:36 WG1710319 Trichlorofluoromethane U C3 0.160 5.00 1 07/22/202118:36 WG1710319 1,2,3-Trichloropropane U 0.237 2.50 1 07/22/202118:36 WG1710319 1,2,4-Trimethylbenzene U 0.322 1.00 1 07/22/202118:36 WG1710319 1,2,3-Trimethyl benzene U 0.104 1.00 1 07/22/202118:36 WG1710319 1,3,5-Trimethyl benzene U 0.104 1.00 1 07/22/202118:36 WG1710319 Vinyl chloride U C3 0.234 1.00 1 07/22/202118:36 WG1710319 Xylenes, Total U 0.174 3.00 1 07/22/202118:36 WG1710319 (S) Toluene-d8 109 80.0-120 07/22/202118:36 WG1710319 (S) Toluene-d8 96.4 80.0-120 08/02/202121.07 WG1716050 (S) 4-Bromofluorobenzene 97.6 77.0-126 07/22/202118:36 WG1710319 (S) 4-Bromofluorobenzene 102 77.0-126 08/02/202121.07 WG1716050 (S) 1,2-Dich/oroethone-d4 104 70.0-130 07/22/202118:36 WG1710319 (S) 1,2-Dich/oroethane-d4 101 70.0-130 08/02/202121.07 WG1716050 FP1 FTc FSS 4 Cn RC I ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 35 of 51 WG1711035 QUALITY CONTROL SUMMARY Wet Chemistry by Method 2320 B-2011 L1380832-02,03,04,06,07 Method Blank (MB) (MB) R3683563-1 07/25/21 06:54 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Alkalinity U 8450 20000 Sample Narrative: BLANK: Endpoint pH 4.5 L1380832-02 Original Sample (OS) • Duplicate (DUP) (OS) L1380832-02 07/25/21 07:19 • (DUP) R3683563-3 07/25/21 07:23 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 141000 143000 1 1.48 20 Sample Narrative: OS: Endpoint pH 4.5 Headspace DUP: Endpoint pH 4.5 L1380832-07 Original Sample (OS) • Duplicate (DUP) (OS) L1380832-07 07/25/21 07:41 • (DUP) R3683563-6 07/25/21 07:43 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 9960 10600 1 6.11 J 20 Sample Narrative: OS: Endpoint pH 4.5 Headspace DUP: Endpoint pH 4.5 Laboratory Control Sample (LCS) (LCS) R3683563-5 07/25/21 07:30 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Alkalinity 100000 102000 102 90.0-110 Sample Narrative: LCS: Endpoint pH 4.5 FP1 Fc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 36 of 51 WG1709392 Wet Chemistry by Method 450052 D-2011 Method Blank (MB) (MB) R3682599-1 07/22/21 10:43 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Sulfide U 25.0 MB RDL ug/1 50.0 L1380832-02 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1380832-02,03,04,06,07 (OS) L1380832-02 07/22/21 10:44 • (DUP) R3682599-3 07/22/21 10:44 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 L1380832-07 Original Sample (OS) • Duplicate (DUP) (OS) L1380832-07 07/22/21 10:45 • (DUP) R3682599-4 07/22/21 10:46 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3682599-2 07/22/21 10:43 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Sulfide 500 574 115 Rec. Limits LCS Qualifier 85.0-115 L1380984-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1380984-01 07/22/21 10:46 • (MS) R3682599-5 07/22/21 10:46 • (MSD) R3682599-6 07/22/21 10:46 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Sulfide 1000 U 1070 1120 107 112 1 80.0-120 4.66 RPD Limits 20 — I Cp Fc FSS 4 Cn FSr _ �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 37 of 51 WG1709100 Wet Chemistry by Method 9056A Method Blank (MB) (MB) R3682724-1 07/21/21 15:05 MB Result MB Qualifier MB MDL Analyte ug/I ug/1 Chloride U 379 Nitrate U 48.0 Sulfate U 594 L1380824-01 Original Sample (OS) • Duplicate (DUP) MB RDL ug/I 1000 100 5000 (OS) L1380824-01 07/21/21 16:16 • (DUP) R3682724-3 07/21/21 16:32 Original Result DUP Result Dilution DUP RPD Analyte ug/I ug/1 % Chloride 3190 3150 1 1.19 Nitrate 780 773 1 0.889 Sulfate 5980 5950 1 0.540 L1380862-01 Original Sample (OS) • Duplicate (DUP) (OS) L1380862-01 07/21/21 23:39 • (DUP) R3682724-6 07/21/21 23:56 Original Result DUP Result Dilution DUP RPD Analyte ug/I ug/1 % Chloride 50200 50200 1 0.102 Nitrate 4090 4120 1 0.729 Sulfate 870 859 1 0.000 Laboratory Control Sample (LCS) QUALITY CONTROL SUMMARY L1380832-02,03,04,06,07 DUP Qualifier DUP RPD Limits 15 15 15 DUP Qualifier DUP RPD Limits 15 15 15 (LCS) R3682724-2 07/21/21 15:22 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/1 % % Chloride 40000 39300 98.3 80.0-120 Nitrate 8000 8020 100 80.0-120 Sulfate 40000 39400 98.5 80.0-120 FP1 Fc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 38 of 51 WG1709100 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9056A L1380832-02,03,04,06,07 L138O824-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1380824-01 07/21/21 16:16 • (MS) R3682724-4 07/21/21 16:49 • (MSD) R3682724-5 07/21/21 17:05 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Chloride 50000 3190 53400 54800 100 103 1 80.0-120 2.46 Nitrate 5000 780 5860 6010 102 105 1 80.0-120 2.48 Sulfate 50000 5980 56000 57300 100 103 1 80.0-120 2.33 L1380862-01 Original Sample (OS) • Matrix Spike (MS) (OS) L1380862-01 07/21/21 23:39 • (MS) R3682724-7 07/22/21 00:12 Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier Analyte ug/I ug/I ug/I % % Chloride 50000 50200 99200 98.1 1 80.0-120 Nitrate 5000 4090 9290 104 1 80.0-120 Sulfate 50000 870 50600 99.4 1 80.0-120 RPD Limits o� 15 15 15 FP1 FC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 39 of 51 WG1709178 Wet Chemistry by Method 9060A Method Blank (MB) (MB) R3682558-2 07/21/2114:51 MB Result MB Qualifier MB MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 430 J 102 MB ROL ug/I 1000 L1380862-04 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1380832-02,03,04,06,07 (OS) L1380862-04 07/22/21 00:18 • (DUP) R3682558-8 07/22/21 00:32 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC (Total Organic Carbon) 1560 1700 1 8.45 20 Laboratory Control Sample (LCS) (LCS) R3682558-1 07/21/21 14:38 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % TOC (Total Organic Carbon) 75000 74500 99.3 85.0-115 L1380760-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1380760-02 07/21/21 20:08 • (MS) R3682558-6 07/21/21 20:35 • (MSD) R3682558-7 07/21/21 20:57 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC (Total Organic Carbon) 50000 1570 51800 48900 100 94.7 1 80.0-120 5.62 RPD Limits 20 — I Cp Fc FS-S 4 Cn rs—r _ �GI rAl FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 40 of 51 WG1712545 Metals (ICP) by Method 6010D QUALITY CONTROL SUMMARY L1380832-01,02,03,04,05,06,07,08,09,10 Method Blank (MB) (MB) R3685749-1 07/30/21 01:03 MB Result Analyte ug/I Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc U U U U U U U U U U U U 4.43 U U MB Qualifier J Laboratory Control Sample (LCS) MB MDL ug/I 4.30 4.40 0.736 0.330 0.479 1.40 0.840 3.68 2.99 1.61 7.35 1.54 4.31 4.99 6.52 MB RDL ug/I 10.0 10.0 5.00 2.00 2.00 10.0 10.0 10.0 6.00 10.0 10.0 5.00 10.0 20.0 50.0 (LCS) R3685749-2 07/30/21 01:06 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Antimony 1000 988 98.8 80.0-120 Arsenic 1000 948 94.8 80.0-120 Barium 1000 1030 103 80.0-120 Beryllium 1000 972 97.2 80.0-120 Cadmium 1000 955 95.5 80.0-120 Chromium 1000 957 95.7 80.0-120 Cobalt 1000 987 98.7 80.0-120 Copper 1000 980 98.0 80.0-120 Lead 1000 980 98.0 80.0-120 Nickel 1000 970 97.0 80.0-120 Selenium 1000 966 96.6 80.0-120 Silver 200 171 85.6 80.0-120 Thallium 1000 947 94.7 80.0-120 Vanadium 1000 992 99.2 80.0-120 Zinc 1000 990 99.0 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 41 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC WG1712545 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1380832-01,02,03,04,05,06,07,08,09,10 L1381181-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1381181-04 07/30/21 01:09 • (MS) R3685749-4 07/30/21 01:14 • (MSD) R3685749-5 07/30/21 01:16 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Antimony 1000 U 1010 1030 101 103 1 75.0-125 1.62 20 Arsenic 1000 U 985 990 98.5 99.0 1 75.0-125 0.492 20 Barium 1000 69.8 1090 1100 102 103 1 75.0-125 0.572 20 Beryllium 1000 U 977 981 97.7 98.1 1 75.0-125 0.346 20 Cadmium 1000 U 974 979 97.4 97.9 1 75.0-125 0.531 20 Chromium 1000 U 955 964 95.5 96.4 1 75.0-125 1.00 20 Cobalt 1000 1.74 1000 1010 100 101 1 75.0-125 0.748 20 Copper 1000 U 982 991 98.2 99.1 1 75.0-125 0.848 20 Lead 1000 U 992 1000 99.2 100 1 75.0-125 0.987 20 Nickel 1000 3.59 985 995 98.2 99.1 1 75.0-125 0.973 20 Selenium 1000 U 1010 1010 101 101 1 75.0-125 0.102 20 Silver 200 U 173 174 86.7 86.9 1 75.0-125 0.200 20 Thallium 1000 U 948 951 94.8 95.1 1 75.0-125 0.346 20 Vanadium 1000 U 994 1000 99.4 100 1 75.0-125 1.08 20 Zinc 1000 U 992 1000 99.2 100 1 75.0-125 0.846 20 FP1 Fc FSS 4 Cn FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 42 of 51 WG1710319 Volatile Organic Compounds (GC/MS) by Method 8260D QUALITY CONTROL SUMMARY L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3686791-3 07/22/21 12:14 MB Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U tert-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U MB Qualifier MB MDL MB RDL ug/I ug/I 11.3 50.0 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.129 1.00 0.605 5.00 0.157 1.00 0.125 1.00 0.127 1.00 0.128 1.00 0.116 1.00 0.140 1.00 0.192 5.00 0.111 5.00 0.960 2.50 0.106 1.00 0.114 1.00 0.276 5.00 0.126 1.00 0.122 1.00 0.107 1.00 0.110 1.00 0.120 1.00 0.374 5.00 0.100 1.00 0.0819 1.00 0.188 1.00 0.126 1.00 0.149 1.00 0.149 1.00 0.142 1.00 0.110 1.00 0.111 1.00 0.118 1.00 0.161 1.00 0.105 1.00 0.137 1.00 0.337 1.00 0.105 1.00 FP1 FC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1380832 08/03/21 15:48 43 of 51 WG1710319 Volatile Organic Compounds (GC/MS) by Method 8260D QUALITY CONTROL SUMMARY L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3686791-3 07/22/21 12:14 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1,2,3-Trichlorobe nzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,3-Trimethyl benzene U 0.104 1.00 1,2,4-Trimethylbenzene U 0.322 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 110 80.0-120 (S) 4-Bromofluorobenzene 96.9 77.0-126 (S)1,2-Dich/oroethone-d4 104 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3686791-1 07/22/21 11:17 • (LCSD) R3686791-2 07/22/21 11:36 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Acetone 25.0 38.9 36.1 156 144 19.0-160 7.47 27 Acrolein 25.0 9.30 9.26 37.2 37.0 10.0-160 0.431 26 Acrylonitrile 25.0 30.0 27.5 120 110 55.0-149 8.70 20 Benzene 5.00 4.31 4.30 86.2 86.0 70.0-123 0.232 20 Bromobenzene 5.00 5.02 5.05 100 101 73.0-121 0.596 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/21 15:48 44 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC WG1710319 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3686791-1 07/22/21 11:17 • (LCSD) R3686791-2 07/22/21 11:36 Spike Amount LCS Result LCSD Result Analyte ug/I ug/I ug/I Bromoform 5.00 4.64 4.49 Bromomethane 5.00 4.73 4.71 n-Butylbenzene 5.00 5.27 5.46 sec -Butyl benzene 5.00 5.19 5.40 tert-Butylbenzene 5.00 5.18 5.39 Carbon tetrachloride 5.00 4.49 4.47 Chlorobenzene 5.00 5.14 5.20 Chlorodibromomethane 5.00 4.93 4.83 Chloroethane 5.00 4.14 4.29 Chloroform 5.00 4.13 4.22 Chloromethane 5.00 4.26 4.61 2-Chlorotoluene 5.00 5.30 5.40 4-Chlorotoluene 5.00 5.40 5.55 1,2-Dibromo-3-Chloropropane 5.00 5.69 5.41 1,2-Dibromoethane 5.00 5.23 5.20 Dibromomethane 5.00 4.74 4.73 1,2-Dichlorobenzene 5.00 5.43 5.41 1,3-Dichlorobenzene 5.00 5.15 5.31 1,4-Dichlorobenzene 5.00 5.35 5.35 Dichlorodifluoromethane 5.00 4.04 4.13 1,1-Dichloroethane 5.00 4.29 4.29 1,2-Dichloroethane 5.00 4.53 4.53 1,1-Dichloroethene 5.00 3.94 4.02 cis-1,2-Dichloroethene 5.00 4.40 4.37 trans-1,2-Dichloroethene 5.00 4.28 4.34 1,2-Dichloropropane 5.00 4.31 4.38 1,1-Dichloropropene 5.00 4.38 4.48 1,3-Dichloropropane 5.00 5.07 5.06 cis-1,3-Dichloropropene 5.00 4.22 4.36 trans-1,3-Dichloropropene 5.00 4.94 4.93 2,2-Dichloropropane 5.00 4.54 4.45 Di -isopropyl ether 5.00 4.51 4.50 Ethylbenzene 5.00 4.92 5.11 Hexachloro-1,3-butadiene 5.00 5.11 5.09 Isopropylbenzene 5.00 4.96 5.00 p-Isopropyltoluene 5.00 5.17 5.28 2-Butanone (MEK) 25.0 28.3 27.8 Methylene Chloride 5.00 4.87 4.74 4-Methyl-2-pentanone (MIBK) 25.0 28.3 27.6 Methyl tert-butyl ether 5.00 4.39 4.35 ACCOUNT: Withers & Ravenel Eng. - Standard LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits 92.8 89.8 68.0-132 3.29 20 94.6 94.2 10.0-160 0.424 25 105 109 73.0-125 3.54 20 104 108 75.0-125 3.97 20 104 108 76.0-124 3.97 20 89.8 89.4 68.0-126 0.446 20 103 104 80.0-121 1.16 20 98.6 96.6 77.0-125 2.05 20 82.8 85.8 47.0-150 3.56 20 82.6 84.4 73.0-120 2.16 20 85.2 92.2 41.0-142 7.89 20 106 108 76.0-123 1.87 20 108 111 75.0-122 2.74 20 114 108 58.0-134 5.05 20 105 104 80.0-122 0.575 20 94.8 94.6 80.0-120 0.211 20 109 108 79.0-121 0.369 20 103 106 79.0-120 3.06 20 107 107 79.0-120 0.000 20 80.8 82.6 51.0-149 2.20 20 85.8 85.8 70.0-126 0.000 20 90.6 90.6 70.0-128 0.000 20 78.8 80.4 71.0-124 2.01 20 88.0 87.4 73.0-120 0.684 20 85.6 86.8 73.0-120 1.39 20 86.2 87.6 77.0-125 1.61 20 87.6 89.6 74.0-126 2.26 20 101 101 80.0-120 0.197 20 84.4 87.2 80.0-123 3.26 20 98.8 98.6 78.0-124 0.203 20 90.8 89.0 58.0-130 2.00 20 90.2 90.0 58.0-138 0.222 20 98.4 102 79.0-123 3.79 20 102 102 54.0-138 0.392 20 99.2 100 76.0-127 0.803 20 103 106 76.0-125 2.11 20 113 111 44.0-160 1.78 20 97.4 94.8 67.0-120 2.71 20 113 110 68.0-142 2.50 20 87.8 87.0 68.0-125 0.915 20 PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1380832 08/03/21 15:48 45 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC WG1710319 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3686791-1 07/22/21 11:17 • (LCSD) R3686791-2 07/22/21 11:36 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Naphthalene 5.00 5.38 5.30 108 106 54.0-135 1.50 20 n-Propylbenzene 5.00 5.34 5.56 107 ill 77.0-124 4.04 20 Styrene 5.00 5.07 5.02 101 100 73.0-130 0.991 20 1,1,1,2-Tetrachloroethane 5.00 5.09 4.98 102 99.6 75.0-125 2.18 20 1,1,2,2-Tetrachloroethane 5.00 5.94 5.87 119 117 65.0-130 1.19 20 Tetrachloroethene 5.00 4.73 4.87 94.6 97.4 72.0-132 2.92 20 Toluene 5.00 4.87 5.00 97.4 100 79.0-120 2.63 20 1,1,2-Trichlorotrifluoroethane 5.00 3.91 3.96 78.2 79.2 69.0-132 1.27 20 1,2,3-Trichlorobenzene 5.00 4.79 4.90 95.8 98.0 50.0-138 2.27 20 1,2,4-Trichlorobenzene 5.00 5.25 5.40 105 108 57.0-137 2.82 20 1,1,1-Trichloroethane 5.00 4.52 4.56 90.4 91.2 73.0-124 0.881 20 1,1,2-Trichloroethane 5.00 5.15 5.16 103 103 80.0-120 0.194 20 Trichloroethene 5.00 4.32 4.35 86.4 87.0 78.0-124 0.692 20 Trichlorofluoromethane 5.00 3.73 3.93 74.6 78.6 59.0-147 5.22 20 1,2,3-Trichloropropane 5.00 5.49 5.35 110 107 73.0-130 2.58 20 1,2,3-Trimethyl benzene 5.00 5.27 5.30 105 106 77.0-120 0.568 20 1,2,4-Trimethylbenzene 5.00 5.16 5.29 103 106 76.0-121 2.49 20 1,3,5-Trimethyl benzene 5.00 5.24 5.32 105 106 76.0-122 1.52 20 Vinyl chloride 5.00 3.91 4.11 78.2 82.2 67.0-131 4.99 20 Xylenes, Total 15.0 15.3 14.6 102 97.3 79.0-123 4.68 20 (S) Toluene-d8 108 109 80.0-120 (S) 4-Bromofluorobenzene 97.9 97.4 77.0-126 (S)1,2-Dich/oroethane-d4 106 104 70.0-130 FP1 FC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 46 of 51 WG1716050 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1380832-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3687142-3 08/02/21 10:58 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/1 ug/I Bromodichloromethane U 0.136 1.00 (S) Toluene-d8 96.1 80.0-120 (S) 4-Bromofluorobenzene 104 77.0-126 (S)1,2-Dich/oroethane-d4 113 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3687142-1 08/02/21 10:02 • (LCSD) R3687142-2 08/02/21 10:21 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I Ug/l ug/1 % % % % % Bromodichloromethane 5.00 5.70 5.89 114 118 75.0-120 3.28 20 (S) Toluene-d8 94.1 93.9 80.0-120 (S)4-Bromofluorobenzene 109 106 77.0-126 (S)1,2-Dich/oroethane-d4 117 119 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 47 of 51 FP1 FC FSS 4 Cn FSr �GI FAI FSC GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) U Analyte Dilution Limits Original Sample Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. FP1 FTC FSS 4 Cn FSr Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be FQC detected in all environmental media. Not detected at the Reporting Limit (or MDL where applicable). The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the rA laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal I9 for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or SC duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description B The same analyte is found in the associated blank. C3 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low. Method sensitivity check is acceptable. J The identification of the analyte is acceptable; the reported value is an estimate. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1380832 08/03/2115:48 48 of 51 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolinas 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhodelsland LA000356 Kentucky16 KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' ° 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas' LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A21-A A21-A — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A21-A — ISO 17025 s 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks 'Aquatic Toxicity ° Chemical/Microbiological 'Mold 6 Wastewater n/a Accreditation not applicable Not all certifications held by the laboratory are applicable to the results reported in the attached report. 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Email To: lelliott@withersravenel.com hake mm. v..I.—m Laura Elliott Z w U ,d7ain.,r—al mr.mm/n�er.lm.-,mm.e- •m,.aer City/State Please Grr Project Description: Kemersville landfill Collected: ( PT MT C ET m z 0 = N + SDG # nn Q Client Project # Lab Project # Phone: 919-469-3340 06140180.39 WITHRAVS-KERNERSVILL = of a F074 w � to Table # y = mJ 0 Q Z U V Acctnum: WITHRAVS Collected by (print): Site/Facility ID P.O.# 06140180.�9 E 11�ry Z � E E _ = Template:T170822 Prelogim P860832 Colle ed by (signatu a Rush? (Lab MUST Be Notified) Quote # same Day _ Five Day CN 2 ai 'O o LeI In = Q E PM: 87 . 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X �cG . t /PG W iz, 1 X X „ti7 Wrn , e iW ( O 4 X X I ,1s--1 W DO]4XXMatrix: Sample Receipt c ,. :: st emarks: PH Temp COD seal Present/Intact: _NP �Y _N __ SS -Soil AIR -Air F-Filter CDC Signed/Accurate: � N GW-Groundwater B- Bioassay Flow Other Bottles arrive intact:'_N -Wastewater Correct bottles used: �Y/_N DW- Drinking Water rjlf„% n o7{10' Samples rejurned via: Tracking# VCJ �% OZ`?3 /J(/O Sufficient volume sent: _R _N If Applicable N OT - Other Fed Ex VOA Zero Headspace: �Y_ _UPS _Courier Pr`servation Correct/Checked: /i N BAD Screen <0.5 mR/hr: �' _N by:ISign lure) Date- Time: Receive y:(Signature) Trip Blank eceived: V No P R in fished MeoH BR Date - Time: Received 6 : (Signal re) Temp:.B3 C Battles Rersived: I( preservation required by login: Date/Time Re i .shed by:ISi re) Relinquished by (Signature) Date: Time: Rece' r`ab by; ignature Date Time: x 5U Hold: Condition: L� O Company Name/Address. Billing Information: Ana vsis / Container Re ervativoChain of Custody Page 1.0f ^� Withers & Ravenel Eng. - Standard Pries Accounts Payable 115 MacKenan Drive O,k �aceAnalyfical' 115 MacKenan Drive Cary, NC 27511 Cary, NC 27511 xxass t.mnan na wounu.r�n.+x vxxx Report to: Email To lelliott@withersravenel.com Laura Elliott a Z w uo.ai,m.omm.m,rm,+u.m,e- mbm mni.. am.m.m of.mar +.e oW�.aem. .•e... rounr. on Project Description'. City/State t Please Circl /T Kernersville Landfill Collected: PT MT CT d C fel O ❑ _ N HE -7 SDG # / �4'rIP3Z Client Project # Lab Project # Phone: 919-469-3340 06140180.39 WITHRAVS-KERNERSVILL = o = O Table # a p ul Z Col ected by an ntl: Site/Facility ID # P.O. # Acctnum: WITHRAVS S 06140180.491" 3' _ 0 v u ni E = Template:T170822 Collect by (signature : Rush? (Lab MUST Be Notified) Quote # O Q a d Z 0 ❑ Q Prelogin: P860832 —Same Day —Five Day N _ _Next Day _5 Day Iliad Only) Date sults Needed Y U1 PM: 87 -He ther J Wagner Im simply , / _ Two Day _ 10 Day Iliad Or No. N rN CD O Packed on Ice N _ Y Y _Three Day $ 2 of _ Shippe via: ed EXGround -ntrs Sample 10 Comp/Grab Matrix' Depth Date Time O Y j Remarks Samp:eYNG rn Q 1n OV r > only) ( Q _QW •--2___ .a GW G Z 4 X X �Ib fi 4VL1�__, GW 2' Z' i S X --4 GW %i -^ (2- GW 3 X X X GW 3 X X X GW 3 X X X Gw x x x _ I I ,I a Matrix:Remarks: Sample Receipt Checklist^ SS -Soil AIR -Air F- Filter pH Temp COC Seal Present/Intact: _NP <r N GW- Groundwater B- Bioassay COC Signed/Accurate: _N WW- WasteWater Flow Other Bottles arrive intact: N Correct trestles used: 1 N DW -Drinking Water Samples reylrned via: OT Other Tracking# Sufficient volume sent: /Y _N if - UPS ✓FedEx Courier — _ _ ace:Applicable VOA Zero Headapace: Preservation Correct/Checked: _ N Relin 'shed by: (Sign ure Date. Time: Receiv by (Signatu e) Trip Blank_Received: e / No / MeoH Z BAD Screen <0.5 mR/hr. ZY _N TBR R in i ed By .-(Signature) Dat '. Time: Recevied by: (Signature) Bottles Received: Tem{f,{J3 �� If reservation required b in: Date ime p q y Login: Relinquished by : (Signature) Date: Time: Recei for la by: (iign to DateTime: Hold: Conditi/p_a,�� 77: '' L( CD a �V11 NCF /Iwn/ �: Page 1 of 1 Our P,.;cle. Yc Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MWS _ Site Name Kernersville Closed Landfill Date _ 7/20/2021 Well Depth Depth to Water 1.5� Well Diameter 2" Casing Material PVC Screen Length 5 Well Water Volume Sampling Crew S. Powell. Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m /L °C Slcm standard mV NTU A Other Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at .Analysis Preservative Bottle ware Number of Bottles Hold Time 8260 VOCs HCL 40 ml VOAs glass 14 Days None 1 Liter glass 7 Days 6010 Metals Nitric Acid 250 ml plastic 180 Days 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Calculation 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2"well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft= 4" well [well depth-0epth to water] x 0.653 al lc lon^s/ft. x 3 = 1.959/ft = \ A) - 2.54 -1 , vil X-3 t 5.1 \ 5 N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW s Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 24 Depth to Water 3, j Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew F o !, L. Parsons Pump Type bailer Tubing Type Intake set at j'3 • t13 Weather Conditions _ f� j_W; _ Notes (eg. odor or color) ] Time Water Level Volume Purged DO Temp EC pH ORP Turbidity iO 1i Uther Narameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days vvcn vuturrl@ t-aicuiavon 1 well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-3D Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 57 Depth to Waterer Well Diameter 2" Casing Material PVC Screen Length 20 Well Water Volume Sampling Crew_ Sfh L. Parsons Pump Type Grundfos Tubing Type poly _ Intake set at Weather Conditions Notes (eg. odor or color) G/ Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m IL °C Slcm) (standard mV NTU Other Parameters Sampled at to Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Other Parameters Sampled at to Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days NOTE: DUPLICATE SAMPLE vven volume La[culat[on 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-4 Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 14 Depth to Water 15.11`14 Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Parsons Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity M) CEO Other Parameters Sampled at 11515 Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Galculation 1 " well [well depth -depth to wafer] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth-cepth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-45 Site Name Kernersville Closed Landfill Date 7/20/2021 Well Depth 4 Depth to Water `3 9 Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Parsons Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from, TOC) Gals. m /L °C pS/cm standard ImV NTU ►0'10 tb Wci� 01-1 2v. 5 ,IUD Co.7 t, %.-3 Other Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Galculation 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft._ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 40 Job Number 6140180.39 Groundwater Sampling Form State ID NA Well ID MW-6 Site Name Kernersville Closed Landfill 1 1 4Date 7/20/2021 Well Depth 20 Depth to Water —A � ' Well Diameter 2' Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew 5. Pawed, �. Parsons Pump Type bailer Tubing Type Intake set at�Z--/1 Weather Conditions - r9 - vct �/ Notes (eg. odor or color) C.Iejf Time Water Level Volume Purged DO Temp EC pH ORP Turbidity Uther Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC None 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days well volume Lalcu[atlon 1" well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] X 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s APPENDIX II Historical Summary Tables (2009-2014) TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Background Downgradient Well ID: MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 TOC Elevation: 806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth: 34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY WELL NUMBER CASING DIAMETER inches WELL ELEVATIONS TOTAL DEPTH SCREENED INTERVAL* LITHOLOGY OF SCREENED INTERVAL* GROUND SURFACE T.O.C. B.G.S. feet B.T.O.C. feet DEPTH B.G.S. ELEV. M.S.L. feet above M.S.L. from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S. Below Ground Surface M.S.L. Mean Sea Level B.T.O.C. Below Top of Casing T.O.C. Top of Casing * = Due to limited information this data is assumed based on field conditions Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY November 2014 GRADIENT FLOW LINE GROUND- HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW WATER GRADIENT, CONDUCTIVITY POROSITY VELOCITY, CALCULATION LENGTH DIRECTION ELEV. i K n V SEGMENT (feet) feet ft/ft ft/da ft/da l i 851 SW 0.04 1.73 0.30 0.20 785 Notes: 1. Hydraulic conductivities ("K") was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 --- ND 5.4 B ND ND 4.5 B --- 1.4 J GWPS = 1.4 µg/L (10/23/07) 01-Jun-10 1.2 6.0 --- ND ND ND ND ND --- 3.9 1 GAPS = 1 µg/L (8/1/10) 29-Dec-10 2.6 6.0 --- ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 6.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 --- --- ND ND ND ND --- ND 09-May-13 5.0 6.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 6.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 6.0 --- ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 --- --- ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10) O1-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 --- --- 1.43 B 1.42 B 0.87 B 1.04 B --- 1.0 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 --- 74.1 J 496 178 18.2 J 89.0 J --- 3.6 J NC 2L = 700 µg/L (1/11/10) 01-Jun-10 1.1 100 --- 58.1 J 326 187 22.2 J 94.9 J --- 2.0 J 29-Dec-10 0.20 100 --- 46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 --- 77.7 J 370 128 41.2 J 98.4 J 113 ND O1-Nov-11 5.0 100 --- 125 413 132 41.7 J 111 72.1 J ND O1-May-12 5.0 100 --- 78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 --- --- 369 127 41.0 B 98.7 J --- 12.2 J 09-May-13 5.0 100 --- 78.6 J 307 112 40.0 J 85.6 J --- ND 07-Nov-13 5.0 100 --- --- 302 113 38.0 J 89.6 J --- ND 05-Jun-14 5.0 100 --- 60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 --- --- 301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 --- ND 0.5 J ND ND ND --- ND GWPS = 4 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- 0.6 1 0.7 J ND ND ND --- ND 29-Dec-10 0.10 1.0 --- ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 --- --- 0.34 J ND ND 0.099 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 --- ND 0.5 J 5.6 ND ND --- ND NC 2L = 2 µg/L (1/11/10) 01-Jun-10 0.2 1.0 -- 2.9 1.0 B 5.3 0.4 B 0.4 B --- 0.4 J 29-Dec-10 0.50 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 --- --- 0.15 J ND ND 0.043 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 --- ND 2.7 J 9.7 J ND 3.1 J --- ND NC 2L = 10 µg/L (1/11/10) 01-Jun-10 0.7 10.0 --- 3.5 J 1.6 J 12.4 1.2 J 3.2 J --- ND 29-Dec-10 0.40 10.0 --- 0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 10.0 --- ND ND ND ND 10.3 ND ND O1-May-12 5.0 10.0 --- ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 --- --- 0.71 J 0.12 B 0.094 B 7.31 J --- 0.099 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 --- ND 6.4 J 11.2 ND 1.8 J --- ND GAPS = 70 µg/L (10/23/07) 01-Jun-10 0.7 10.0 --- 1.8 J 2.5 J 8.5 J ND 1.7 J --- ND GAPS = 1 µg/L (10/1/10) 29-Dec-10 0.60 10.0 --- ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 --- ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 --- --- 1.98 J 3.89 J 0.43 B 2.02 J --- 0.24 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 --- ND ND 10.6 ND 1.5 J --- ND NC 2L = 1,000 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 12.2 B 3.3 B 33.2 3.9 B 6.8 B --- 4.8 .1 29-Dec-10 0.30 10.0 --- ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 --- 3.56 B 0.54 B 0.98 B 1.83 B --- 1.23 1 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 --- ND ND 10.2 ND ND --- ND NC 2L = 15 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 9.1 B 8.2 B 8.7 B 3.0 B 3.9 B --- 3.2 .I 29-Dec-10 4.0 10.0 --- ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 --- 5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 --- --- 1.00 B 0.091 B 0.066 B 1.12 B --- 0.58 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 --- ND ND 8.1 1 1.8 J 1.6 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.6 50.0 --- ND ND 6.0 J ND 0.9 J --- ND 29-Dec-10 1.7 50.0 --- ND ND ND ND ND 2.0 B 3.1 1 29-Jun-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 50.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 --- --- 0.73 B 1.19 B 0.65 B 5.57 J --- 0.84 1 09-May-13 5.0 50.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 50.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 50.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 --- --- ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 --- ND ND 8.4 J ND ND --- ND NC 2L = 20 µg/L (1/11/10) 01-Jun-10 6.3 10.0 --- ND ND 6.3 J ND ND --- ND 29-Dec-10 3.8 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 10.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 --- --- 0.16 J 0.38 J 0.20 J 0.25 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 --- --- ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 --- ND 1.7 B 2.2 B ND ND --- 1.9 J NC 2L = 20 µg/L (1/11/10) 01-Jun-10 1.1 10.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.10 10.0 --- ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 --- 0.18 J ND ND 0.078 J --- ND 09-May-13 5.0 10.0 --- NI) ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- NI) ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 --- ND ND ND ND ND --- 3.7 1 GWPS = 0.28 µg/L (10/23/07) 01-Jun-10 2.7 5.5 --- ND ND ND ND ND --- ND GWPS = 0.2 µg/L (10/1/10) 29-Dec-10 3.0 5.5 --- ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-May-12 5.4 5.5 --- ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 --- --- 0.16 J ND ND 0.76 J --- ND 09-May-13 5.4 5.5 --- ND ND ND ND ND --- ND 07-Nov-13 5.4 5.5 --- --- ND ND ND ND --- ND 05-Jun-14 5.4 5.5 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 --- --- ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 --- ND 1.4 J 37.4 1.5 J 4.3 J --- ND GWPS = 3.5 µg/L (10/23/07) 01-Jun-10 0.4 25.0 --- 1.2 J 3.4 J 84.2 1.4 J 4.8 J --- ND GWPS = 0.3 µg/L (10/1/10) 29-Dec-10 0.20 25.0 --- 1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 1 29-Jun-11 5.0 25.0 --- ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 --- 7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 --- ND ND ND ND 7.2 J 7.6 1 ND 07-Nov-12 0.085 25.0 --- --- 2.48 J 2.02 J 2.35 J 4.55 J --- ND 09-May-13 5.0 25.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 25.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 25.0 --- ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 --- --- ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 --- ND 10.1 B 204 15.9 B 24.8 B --- 5.8 .I NC 2L = 1,000 µg/L (1/11/10) 01-Jun-10 2.7 10.0 --- 16.2 13.5 415 8.5 J 22.2 --- ND 29-Dec-10 0.40 10.0 --- 12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 --- ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 --- 16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 --- ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 --- --- 8.61 J 5.20 J 3.98 J 4.65 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- 13.8 10.4 ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 --- --- ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 --- ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 1 NC 2L = 6,000 µg/L (1/11/10) 01-Nov-11 2.2 100 --- ND ND ND ND ND ND 14.6 1 01-May-12 2.2 100 --- ND ND ND ND ND ND ND 07-Nov-12 0.193 100 --- --- ND ND ND ND --- ND 09-May-13 10.0 100 --- ND ND ND ND ND --- 12.0 1 07-Nov-13 10.0 100 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 100 --- ND ND ND ND ND ND ND 20-Nov-14 10.0 100 --- ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 --- ND 8.4 0.3 J 0.4 J 0.3 J --- ND NC 2L = 1 µg/L (10/23/07) 01-Jun-10 0.1 1.0 -- ND 2.9 ND ND ND --- ND 29-Dec-10 0.25 1.0 --- ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 --- ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 --- ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 --- ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 --- --- 8.63 0.430 J 0.504 J 0.478 J --- ND 09-May-13 0.25 1.0 --- ND 5.2 0.27 J 0.32 J 0.30 J --- ND 07-Nov-13 0.25 1.0 --- --- 6.9 0.33 J 0.38 J 0.39 J --- ND 05-Jun-14 0.25 1.0 --- ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 --- --- 6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 --- ND ND 0.37 B ND ND --- 0.37 J NC 2L = µg/L 4 (10/23/07) 07-Nov-13 0.26 3.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 3.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 --- --- ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 --- ND 0.5 J 0.6 J ND ND --- ND NC 2L = 50 µg/L (10/23/07) 01-Jun-10 0.1 3.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.23 3.0 --- ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 --- ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 --- ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 --- ND {0.42} J 0.94 B 0.38 B ND ND 0.30 {ND} .I 07-Nov-12 0.083 3.00 --- --- 0.468 J 1.30 J 0.476 J ND --- ND 09-May-13 0.23 3.0 --- ND 0.27 J 0.72 J 0.27 J ND --- ND 07-Nov-13 0.23 3.0 --- --- 0.42 J 0.97 J 0.38 J ND --- ND 05-Jun-14 0.23 3.0 --- ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 --- ND ND 0.5 J 0.5 J ND --- 0.1 J NC 2L = 3,000 µg/L (1/11/10) 01-Jun-10 0.1 10.0 --- ND ND 0.4 J ND ND --- ND 29-Dec-10 0.54 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 --- ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 --- ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 --- --- ND ND ND ND --- ND 09-May-13 0.54 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.54 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.54 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 --- --- ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 --- ND 3.8 2.2 2.3 3.1 --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.2 0.9 J ND 1.2 --- ND 29-Dec-10 0.33 1.0 --- ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 --- ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 --- ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 --- ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 --- 5.12 2.93 4.08 3.64 --- ND 09-May-13 0.33 1.0 --- ND 3.6 2.0 3.1 2.3 --- ND 07-Nov-13 0.33 1.0 --- --- 5.4 2.5 4.2 3.2 --- ND 05-Jun-14 0.33 1.0 --- ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 --- --- 4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 --- ND 22.8 1.9 J 4.0 J 2.4 J --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.2 5.0 --- ND 11.0 1.1 J ND 1.2 J --- ND 29-Dec-10 0.32 5.0 --- ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 --- ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 --- ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 --- ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 --- --- 28.1 2.06 J 4.08 J ND --- ND 09-May-13 0.32 5.0 --- ND 18.7 1.4 J 3.0 J 1.6 J --- ND 07-Nov-13 0.32 5.0 --- --- 26.6 1.7 J 4.2 J 2.2 J --- ND 05-Jun-14 0.32 5.0 --- ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 --- --- 21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 --- ND 1.2 0.7 J 1.2 ND --- ND NC 2L = 0.4 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.12 1.0 --- ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 --- ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 --- ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 --- ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.12 1.0 --- ND 0.50 J 0.49 J 0.81 J ND --- ND 07-Nov-13 0.12 1.0 --- --- 0.93 J 0.66 J 1.3 ND --- ND 05-Jun-14 0.12 1.0 --- ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 --- --- 0.68 J 0.47 J 0.81 J ND ND ND 1,1-Dichloroethylene 30-Dec-09 0.1 5.0 --- ND 0.4 J ND ND ND --- ND NC 2L = 7 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.56 5.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-May-12 0.56 5.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 --- --- ND ND ND ND --- ND NC 2L = 350 µg/L (04/01/2013) 09-May-13 0.56 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.56 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.56 5.0 --- ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 --- ND ND ND ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 68.2 11.0 51.0 21.8 --- ND NC 2L = 70 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 23.0 7.6 ND 10.2 --- ND 29-Dec-10 0.19 5.0 --- ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 --- ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 --- ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 --- ND {48.7{ 14.2 59.5 22.1 ND 0.21 {ND} J 07-Nov-12 0.103 5.00 --- 59.7 13.6 71.3 26.4 --- ND 09-May-13 0.19 5.0 --- ND 39.9 10.9 49.7 17.4 --- ND 07-Nov-13 0.19 5.0 --- 53.9 10.7 67.1 21.8 --- ND 05-Jun-14 0.19 5.0 --- ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 --- 44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 1.4 J ND 0.2 J 0.2 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 0.6 J ND ND ND --- ND 29-Dec-10 0.49 5.0 --- ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 --- ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 --- ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 --- --- 1.59 J ND ND ND --- ND 09-May-13 0.49 5.0 --- ND 1.1 J ND ND ND --- ND 07-Nov-13 0.49 5.0 --- --- 1.6 J ND ND ND --- ND 05-Jun-14 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 --- --- 1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 --- ND 5.7 0.6 J 1.1 0.7 J --- ND NC 2L = 0.6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.9 ND ND ND --- ND 29-Dec-10 0.27 1.0 --- ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 --- ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 --- ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 --- ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 --- 4.93 ND 1.66 ND --- ND 09-May-13 0.27 1.0 --- ND 3.3 0.51 J 0.96 J 0.45 J --- ND 07-Nov-13 0.27 1.0 --- --- 4.4 0.63 J 1.3 0.57 J --- ND 05-Jun-14 0.27 1.0 --- ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 --- --- 4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 --- ND ND ND 0.4 J ND --- ND NC 2L = 600 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.30 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.30 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.30 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.30 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.30 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 --- --- ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 --- ND 1.2 ND ND ND --- ND NC 2L = 0.7 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- ND 1.4 ND ND ND --- ND 29-Dec-10 0.46 1.0 --- ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 --- ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 --- ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 --- ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 --- --- 2.52 ND ND ND --- ND 09-May-13 0.46 1.0 --- ND 1.9 ND ND ND --- ND 07-Nov-13 0.46 1.0 --- --- 1.8 ND ND ND --- ND 05-Jun-14 0.46 1.0 --- ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 --- --- 1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 --- ND ND ND ND ND 0.76 J ND NC 2L= 600 µg/L (1/11/10) 01-Nov-11 0.26 1.0 -- ND ND ND ND ND ND ND 01-May-12 0.26 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.26 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.26 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 --- --- ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 --- ND 8.0 ND ND 0.2 J --- ND NC 2L = 3 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 6.4 ND ND ND --- ND 29-Dec-10 0.47 1.0 --- ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 --- ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 --- ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 --- ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 --- 9.97 ND ND ND --- ND 09-May-13 0.47 1.0 --- ND 8.4 ND ND ND --- ND 07-Nov-13 0.47 1.0 --- 8.0 ND ND ND --- ND 05-Jun-14 0.47 1.0 --- ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 --- --- 5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 --- ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10) 01-Nov-11 0.20 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.20 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.20 1.0 --- ND 0.66 J ND ND ND --- ND 07-Nov-13 0.20 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.20 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Analyte Sample Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 --- ND 4.0 2.8 4.1 26.2 --- ND NC 2L = 0.03 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 2.2 3.0 ND 26.7 --- ND 29-Dec-10 0.62 1.0 --- ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 --- ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 --- ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 --- ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 --- --- 7.94 2.73 6.99 29.9 --- ND 09-May-13 0.62 1.0 --- ND 2.8 1.9 4.2 18.6 --- ND 07-Nov-13 0.62 1.0 --- --- 6.3 2.1 6.0 21.9 --- ND 05-Jun-14 0.62 1.0 --- ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 --- --- 5.2 2.1 5.3 16.2 ND ND Xylene (Total) 30-Dec-09 0.3 4.0 --- ND ND ND 3.5 J ND --- ND NC 2L= 500 µg/L (1/11/10) 01-Jun-10 0.3 4.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.66 2.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-May-12 0.66 2.0 --- ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 --- --- ND ND ND ND --- ND 09-May-13 0.66 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.66 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.66 5.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07) 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 02 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07) 01-Jun-10 02 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07) 01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 .1 ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07) 01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07) 01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07) 09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 020 25.0 0.67 B 0.37 B 0.62 B 0.26 1 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07) O1-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND O 1-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07) 01-Nov-11 2.2 100 ND ND ND 14.6 J O1-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 1 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) O1-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND) J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 --- 4600 J 148000 147000 160000 186000 (ug/L) Nov-14 1000.0 5000 --- --- 159000 151000 159000 181000 Sulfate Jun-14 2000 250000 --- 6500 J ND ND ND ND (ug/L) Nov-14 1000 250000 --- --- 1760 J 1730 J 1870 J 1560 J Nitrogen, Nitrate Jun-14 20.0 1000 --- 72 J 56 J ND ND ND (ug/L) Nov-14 10.0 1000 --- --- 45 J ND ND ND Methane Jun-14 3.3 6.6 --- --- 5530 254 242 515 (ug/L) Nov-14 3.3 6.6 --- --- 4980 159 182 186 Chloride Jun-14 1000 1000 --- 2220 11200 25900 16800 15600 (ug/L) Nov-14 500 1000 --- --- 17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 --- 3100 10600 8300 1500 8200 (ug/L) Nov-14 500 1000 --- --- 2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 --- --- 1.5 1.2 120 3.5 (nM) Nov-14 0.13 0.6 --- --- 2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 --- ND ND ND ND ND (ug/L) Nov-14 2000 2000 --- --- 4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 --- N D ND ND ND ND (ug/L) Nov-14 12500 25000 --- --- ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP points Points Awarded without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 1 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 I 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >200 C At T > 200C biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product I 1 I 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine I 2 I 2 I 2 Hydrogen > 1 nM Reductive pathway possible 3 1 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination I 2 0 I 0 Tetrachloroethene (PCE) --- Material released 0 0 0 Trichloroethene (TCE) --- Material released 0 0 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE) --- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2, --- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC) --- Material released 0 0 0 --- Daughter product of DCE 2 2 0 1, 1, 1 -Trichloroethane (TCA) --- Material released 1 0 0 0 1,1-Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC) --- Material released 0 0 0 (Methylene Chloride) --- Daughter product of chloroform 2 0 1 0 Based on data collected in November 2014. Total Points Awarded : 23 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evid. of Nat. Atten. < 5 inadequate 6-14 limited 15-19 adequate > 20 strong Town of Kernersville Joyce Engineering