2019.10.31_CCO.p11.b_PFASCharacterizationQuarterlyReport2

CHARACTERIZATION OF PFAS IN
PROCESS AND NON-PROCESS
WASTEWATER AND STORMWATER
Quarterly Report #2
Prepared for
The Chemours Company FC, LLC
22828 NC-87
Fayetteville, NC 28306
Prepared by
Geosyntec Consultants of NC, P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
Geosyntec Project Number TR0795
October 31, 2019

TR0795 vi 31-October-19
“I certify that I am personally familiar with the information contained in this submittal,
including any and all supporting documents accompanying this report, and that the
material and information contained herein is, to the best of my knowledge and belief, true, accurate and complete.”
Adrienne Nemura, North Carolina Licensed Professional Engineer 038141
Geosyntec Consultants of NC, PC is licensed to practice engineering in North Carolina.
The certification number (Firm’s License Number) is C-3500.
Geosyntec Consultants of NC, PC is licensed to practice geology in North Carolina. The
certification number (Firm’s License Number) is C-295.

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Tables
TABLE 1PARAGRAPH 11(b) PROPOSED SAMPLE LOCATION SUMMARYChemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.Intake/ OutfallProcess waterNon-process wastewater Stormwater1Discharge point of excess river water (i.e., water drawn from the Cape Fear River, but not used as process water or NCCW) to characterize background levels of PFASTemporal Composite Intake2 Kuraray northern leased area stormwater dischargeTemporal Composite3 Chemours PPA area stormwater dischargeTemporal Composite4 Combined stormwater discharge from Kuraray northern leased area and Chemours PPA areaTemporal Composite5 Kuraray southern leased area stormwater Temporal Composite6A Kuraray southern leased area NCCW discharge - Vacuum CondenserGrab6B Kuraray southern leased area NCCW discharge - Resins AreaGrab7A Combined stormwater and NCCW discharge from western portion of the FacilityTemporal Composite7BCombined stormwater and NCCW discharge from western portion of the Facility and treated discharge from WWTPTemporal Composite8 Outfall 001 treated non-Chemours process wastewater discharge to open channel to Outfall 002 Temporal Composite9Chemours Monomers IXM NCCW and stormwater discharge including stormwater from Vinyl Ethers South and Vinyl Ethers NorthTemporal Composite10 Chemours Monomers IXM area stormwater dischargeTemporal Composite11 Stormwater discharge from portion of grassy field to north of decommissioned Chemours Teflon area Temporal Composite12 DuPont area southern drainage ditch stormwater discharge and NCCWTemporal Composite13 DuPont area northern drainage ditch stormwater discharge and NCCWTemporal Composite14 DuPont area southeast stormwater and NCCW discharge Temporal Composite15 Combined stormwater and NCCW discharge from eastern portion of the FacilityTemporal Composite16 Chemours Monomers IXM Area combined process wastewater Grab17A Chemours PPA Area waste acid trailerGrab17B Chemours PPA Area waste rinse water trailerGrab18 Kuraray process wastewater Grab19A DuPont process wastewater, Plant 1Grab19B DuPont process wastewater, Plant 2Grab20 Outfall 002 pipe to Cape Fear River upstream of sumpTemporal Composite Outfall21A Sediment Basin SouthGrab21B Sediment Basin NorthGrab22 WWTP combined influentGrab23A Kuraray northern leased area combined process wastewater and NCCW; manhole on Terra Cotta PipeGrab23B Kuraray laboratory process wastewaterGrab24A Chemours Monomers IXM Vinyl Ethers South NCCWGrab24B Chemours Monomers IXM Line 3 and Line 4 Extruder NCCWGrab24C Chemours Monomers IXM Water Return Header NCCWGrabNotesSample numbers refer to locations identified in Figure 2.Temporal composite samples to be integrated over 4 hours.IXM - ion exchange membraneNCCW - non-contact cooling waterPFAS - per- and polyfluoroalkyl substances PPA - polymer processing aid WWTP - Wastewater treatment plantSample NumberSample Location DescriptionSampling MethodSample CategoryOctober 2019
TABLE 2SUMMARY OF SAMPLES COLLECTEDChemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.Intake/ OutfallProcess waterNon-process wastewater StormwaterApril(Q2)June (Q2) August (Q3)October (Q4)December(Q4)February (Q1)April (Q2) June (Q2) August (Q3)1Discharge point of excess river water (i.e., water drawn from the Cape Fear River, but not used as process water or NCCW) to characterize background levels of PFASTemporal Composite Intake2 Kuraray northern leased area stormwater discharge Temporal Composite-- -- --3 Chemours PPA area stormwater discharge Temporal Composite-- -- --4 Combined stormwater discharge from Kuraray northern leased area and Chemours PPA area Temporal Composite-- -- --5 Kuraray southern leased area stormwater Temporal Composite-- -- --6A Kuraray southern leased area NCCW discharge - Vacuum CondenserGrab 6B Kuraray southern leased area NCCW discharge - Resins AreaGrab 7A Combined stormwater and NCCW discharge from western portion of the Facility Temporal Composite  7BCombined stormwater and NCCW discharge from western portion of the Facility and treated discharge from WWTPGrab/Temporal Composite*   8 Outfall 001 treated non-Chemours process wastewater discharge to open channel to Outfall 002 Temporal Composite  9Chemours Monomers IXM NCCW and stormwater discharge including stormwater from Vinyl Ethers South and Vinyl Ethers NorthTemporal Composite  10 Chemours Monomers IXM area stormwater discharge Temporal Composite--11 Stormwater discharge from portion of grassy field to north of decommissioned Chemours Teflon area Temporal Composite-- -- --12 DuPont area southern drainage ditch stormwater discharge and NCCWTemporal Composite-- --13 DuPont area northern drainage ditch stormwater discharge and NCCW Temporal Composite-- -- --14 DuPont area southeast stormwater and NCCW discharge Temporal Composite  15 Combined stormwater and NCCW discharge from eastern portion of the Facility Temporal Composite  16 Chemours Monomers IXM Area combined process wastewater Grab--17A Chemours PPA Area waste acid trailerGrab--17B Chemours PPA Area waste rinse water trailerGrab--18 Kuraray process wastewater Grab**19A DuPont process wastewater, Plant 1Grab 19B DuPont process wastewater, Plant 2Grab 20 Outfall 002 pipe to Cape Fear River upstream of sump Temporal Composite Outfall21A Sediment Basin SouthGrab  21B Sediment Basin NorthGrab-- -- --22 WWTP combined influentGrab  23A Kuraray northern leased area combined process wastewater and NCCW; manhole on Terra Cotta Pipe Grab **23B Kuraray laboratory process wastewaterGrab----24A Chemours Monomers IXM Vinyl Ethers South NCCWGrab 24B Chemours Monomers IXM Line 3 and Line 4 Extruder NCCWGrab 24C Chemours Monomers IXM Water Return Header NCCWGrabNotesSamples collected on 24 April 2019 (April 2019 event), 27 June 2019 & 28 June 2019 (June 2019 event), and 21 August 2019 & 22 August 2019 (August 2019 event).Sample numbers refer to locations identified in Figure 2.All temporal composite samples were integrated over 4 hoursLocations 2, 3, 4, 5, 11, 12, and 13 were not sampled in 2019 Quarter 2 (Q2) because they had insufficient water to collect a sample.Location 10 was not sampled during the June 2019 event because it had insufficient water to collect a sample.Location 21B was not sampled in Q2 or Quarter 3 (Q3) because this sediment pond was not in use at the time of sampling.Location 23B was added to the Sampling Plan after the April 2019 event. It was sampled during the June 2019 event was but was not sampled during the August 2019 event because it had insufficient water to collect a sample.Locations 2, 3, 4, 5, 11, and 13 were not sampled in Q3 because they had insufficient water to collect a sample.Location 17A was not sampled in Q3 because it was removed from the work plan.-- - sample not collected* - Location 7B was collected as a grab sample for the April and June 2019 events due to limited autosampler availability. This location was collected as a temporal composite sample for the August 2019 event and will continue to be collected in this manner for future sampling events.** - Locations 18 and 23A were collected as four grab samples over four hours during the August 2019 event to assess temporal variability at these locations.IXM - ion exchange membraneNCCW - non-contact cooling waterPFAS - per- and polyfluoroalkyl substances PPA - polymer processing aid WWTP - Wastewater treatment plantSample NumberSample Location DescriptionSampling MethodSample Collected20192020Sample CategoryOctober 2019
TABLE 3
PFAS AND ASSOCIATED ANALYTICAL METHODS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
HFPO-DA*Hexafluoropropylene oxide dimer acid 13252-13-6 C6HF11O3
PFMOAA Perfluoro-2-methoxyaceticacid 674-13-5 C3HF5O3
PFO2HxA Perfluoro(3,5-dioxahexanoic) acid 39492-88-1 C4HF7O4
PFO3OA Perfluoro(3,5,7-trioxaoctanoic) acid 39492-89-2 C5HF9O5
PFO4DA Perfluoro(3,5,7,9-tetraoxadecanoic) acid 39492-90-5 C6HF11O6
PFO5DA Perfluoro-3,5,7,9,11-pentaoxadodecanoic acid 39492-91-6 C7HF13O7
PMPA Perfluoromethoxypropyl carboxylic acid 13140-29-9 C4HF7O3
PEPA Perfluoroethoxypropyl carboxylic acid 267239-61-2 C5HF9O3
PFESA-BP1 Byproduct 1 29311-67-9 C7HF13O5S
PFESA-BP2 Byproduct 2 749836-20-2 C7H2F14O5S
Byproduct 4 Byproduct 4 N/A C7H2F12O6S
Byproduct 5 Byproduct 5 N/A C7H3F11O7S
Byproduct 6 Byproduct 6 N/A C6H2F12O4S
NVHOS Perfluoroethoxysulfonic acid 1132933-86-8 C4H2F8O4S
EVE Acid Perfluoroethoxypropionic acid 69087-46-3 C8HF13O4
Hydro-EVE Acid Perfluoroethoxsypropanoic acid 773804-62-9 C8H2F14O4
R-EVE R-EVE N/A C8H2F12O5
PES Perfluoroethoxyethanesulfonic acid 113507-82-7 C4HF9O4S
PFECA B Perfluoro-3,6-dioxaheptanoic acid 151772-58-6 C5HF9O4
PFECA-G Perfluoro-4-isopropoxybutanoic acid 801212-59-9 C12H9F9O3S
10:2 FTS 10:2-fluorotelomersulfonate acid 120226-60-0 C12H5F21O3
8:2 FTS 8:2 fluorotelomersulfonic acid 39108-34-4 C10H5F17O3S
4:2 FTS 4:2 fluorotelomersulfonic acid 757124-72-4 C6H5F9O3S
NEtPFOSAE 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 1691-99-2 C8F17SO2N(C2H5)CH2CH2OH
NMePFOSAE 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 24448-09-7 C8F17SO2N(CH3)CH2CH2OH
6:2 FTS 6:2 fluorotelomer sulfonate 27619-97-2 C8H5F13SO3
ADONA Ammonium 4,8-dioxa-3H-perfluorononanoate 958445-44-8 CF3O(CF2)3OCHFCF2COONH4
NaDONA Sodium 4,8-dioxa-3H-perfluorononanoate EVS1361 CF3O(CF2)3OCHFCF2COONa
NEtFOSAA N-ethyl perfluorooctane sulfonamidoacetic acid 2991-50-6 C8F17SO2N(C2H5)CH2COOH
NEtPFOSA N-ethylperfluoro-1-octanesulfonamide 4151-50-2 C8F17SO2NHCH2CH3
NMePFOSA N-methyl perfluoro-1-octanesulfonamide 31506-32-8 C8F17SO2NHCH3
NMeFOSAA N-methyl perfluorooctane sulfonamidoacetic acid 2355-31-9 C8F17SO2N(CH3)CH2COOH
PFBS Perfluorobutane sulfonic acid 375-73-5 C4HF9SO
PFBA Perfluorobutanoic acid 375-22-4 C4HF7O2
PFDS Perfluorodecane sulfonic acid 335-77-3 C10HF21O3S
PFDA Perfluorodecanoic acid 335-76-2 C10HF19O2
PFDOS Perfluorododecane sulfonic acid 79780-39-5 C12HF25O3S
PFDoA Perfluorododecanoic acid 307-55-1 C12HF23O2
PFHpS Perfluoroheptane sulfonic acid 375-92-8 C7HF15O3S
PFHpA Perfluoroheptanoic acid 375-85-9 C7HF13O2
PFHxDA Perfluorohexadecanoic acid 67905-19-5 C16HF31O2
PFHxS Perfluorohexane sulfonic acid 355-46-4 C6HF13SO3
PFHxA Perfluorohexanoic acid 307-24-4 C6HF11O2
PFNS Perfluorononanesulfonic acid 68259-12-1 C9HF19O3S
PFNA Perfluorononanoic acid 375-95-1 C9HF17O2
PFODA Perfluorooctadecanoic acid 16517-11-6 C18HF35O2
PFOSA Perfluorooctane sulfonamide 754-91-6 C8H2F17NO2S
PFPeS Perfluoropentane sulfonic acid 2706-91-4 C5HF11O3S
PFPeA Perfluoropentanoic acid 2706-90-3 C5HF9O2
PFTeA Perfluorotetradecanoic acid 376-06-7 C14HF27O2
PFTriA Perfluorotridecanoic acid 72629-94-8 C13HF25O2
PFUnA Perfluoroundecanoic acid 2058-94-8 C11HF21O2
PFOA Perfluorooctanoic acid 335-67-1 C8HF15O
PFOS Perfluorooctane sulfonic acid 1763-23-1 C8HF17SO3
F-53B Major F-53B Major 73606-19-6 C8HClF16O4S
F-53B Minor F-53B Minor 83329-89-9 C10HClF20O4S
Notes:
*Depending on the laboratory, HFPO-DA may also appear on the EPA Method 537 Mod analyte list
EPA - Environmental Protection Agency
PFAS - per- and polyfluoroalkyl substances
SOP - Standard Operating Procedure
CASN Chemical Formula
Table 3+ Lab SOP
Analytical Method Common Name Chemical Name
EPA Method 537
Mod
October 2019
TABLE 4A
ANALYTICAL RESULTS - JUNE 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID 1 6A 6B 7A 7B
Field Sample ID STW-LOC1-062819 STW-LOC-6A-062719 STW-LOC-6B-062719 STW-LOC7A-062819 STW-LOC7B-062719
Date Sampled 06/28/2019 06/27/2019 06/27/2019 06/28/2019 06/27/2019
Analytical Laboratory TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
QA/QC ----------
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)18 66 24 22 18
PFMOAA <5 <5 UJ <5 UJ <5 69
PFO2HxA 14 11 J 13 J 14 25
PFO3OA 2.5 <2 UJ <2 UJ 2.2 10
PFO4DA <2 <2 UJ <2 UJ <2 9.7
PFO5DA <2 <2 UJ <2 UJ <2 24
PMPA 23 23 J 23 J 22 21
PEPA <20 <20 UJ <20 UJ <20 <20
PFESA-BP1 <2 <2 UJ <2 UJ <2 <2
PFESA-BP2 <2 <2 UJ <2 UJ <2 120
Byproduct 4 2.8 J 7.9 J 13 J 3.4 J 73 J
Byproduct 5 <2 <2 UJ <2 UJ <2 490 J
Byproduct 6 <2 <2 UJ <2 UJ <2 2.2
NVHOS <2 <2 UJ <2 UJ <2 9.2
EVE Acid <2 <2 UJ <2 UJ <2 <2
Hydro-EVE Acid <2 <2 UJ <2 UJ <2 <2
R-EVE <2 4 J 5.8 J <2 3.7 J
PES <2 <2 UJ <2 UJ <2 <2
PFECA B <2 <2 UJ <2 UJ <2 <2
PFECA-G <2 <2 UJ <2 UJ <2 <2
Total Table 3+ Compounds*60 110 79 64 870
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate <2 <2 <2 <2 <2
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<20 <20 <20 <20 <20
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<20 <20 <20 <20 <20
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2 <60 <60 <2 <2
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <2 <110 <110 <2 <2
6:2 Fluorotelomer sulfonate <20 <20 <20 <20 <20
ADONA <2.1 <2.1 <2.1 <2.1 <2.1
NaDONA <2.1 <2.1 <2.1 <2.1 <2.1
N-ethyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20
N-ethylperfluoro-1-octanesulfonamide 2.7 <37 <37 <2 <2
N-methyl perfluoro-1-octanesulfonamide <2 <35 <35 <2 <2
N-methyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20
Perfluorobutane Sulfonic Acid 3.7 3.6 3.6 3.6 3.4
Perfluorobutanoic Acid 8.3 11 9.2 8.8 8.9
Perfluorodecane Sulfonic Acid <2 <2 <2 <2 <2
Perfluorodecanoic Acid <2 <2 <2 <2 <2
Perfluorododecane sulfonic acid (PFDoS)<2 <2 <2 <2 <2
Perfluorododecanoic Acid <2 <2 <2 <2 <2
Perfluoroheptane sulfonic acid (PFHpS)<2 <2 <2 <2 <2
Perfluoroheptanoic Acid 14 13 13 14 14
Perfluorohexadecanoic acid (PFHxDA)<2 <2 <2 <2 <2
Perfluorohexane Sulfonic Acid 5 5.3 5.6 5.2 5.4
Perfluorohexanoic Acid 21 22 20 20 21
Perfluorononanesulfonic acid <2 <2 <2 <2 <2
Perfluorononanoic Acid <2 <2 <2 <2 <2
Perfluorooctadecanoic acid <2 <2 <2 <2 <2
Perfluorooctane Sulfonamide <2 <2 <2 <2 <2
Perfluoropentane sulfonic acid (PFPeS)<2 <2 <2 <2 <2
Perfluoropentanoic Acid 17 18 17 19 18
Perfluorotetradecanoic Acid <2 <2 <2 <2 <2
Perfluorotridecanoic Acid <2 <2 <2 <2 <2
Perfluoroundecanoic Acid <2 <2 <2 <2 <2
PFOA 8.5 8.3 9.6 9.4 8.9
PFOS 11 14 16 15 15
Notes:
* - Total Table 3+ was calculated including J qualified data but
not non-detect data. The total Table 3+ sum is rounded to two
significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be accurate or
precise.
Page 1 of 6 October 2019
TABLE 4A
ANALYTICAL RESULTS - JUNE 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including J qualified data but
not non-detect data. The total Table 3+ sum is rounded to two
significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be accurate or
precise.
7B 8 9 14 15 16
STW-LOC7B-062719-D STW-LOC8-062819 STW-LOC9-062819 STW-LOC14-062819 STW-LOC15-062819 STW-LOC16-062819
06/27/2019 06/28/2019 06/28/2019 06/28/2019 06/28/2019 6/28/2019
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
Field Duplicate ----------
18 100 77 22 45 250,000 J
65 <21 <21 <5 12 350,000
25 360 20 15 16 310,000
10 200 5.9 2.5 3.2 33,000
10 210 <7.9 <2 <2 18,000
26 520 <3.4 <2 <2 11,000 J
19 <57 <57 22 25 520,000
<20 34 <20 <20 <20 270,000
2 37 2,300 <2 880 1,600,000
130 2,600 120 <2 41 270,000
71 J 760 110 <2 80 J 17,000,000 J
470 J 3,500 190 2.1 J 250 J 1,700,000
2.3 49 <2 <2 <2 4,400
9.8 190 61 <2 23 75,000
<2 <2.4 57 <2 22 580,000 J
<2 18 6.7 <2 3.6 120,000
<2 29 J 53 <2 33 J 4,100,000 J
<2 <4.6 <4.6 <2 <2 <460
<2 <6 <6 <2 <2 <600
<2 <4.1 <4.1 <2 <2 <410
860 8,600 3,000 64 1,400 27,000,000
<2 <2 <2 <2 <2 <18
<20 <20 <20 <20 <20 <180
<20 <20 <20 <20 <20 <480
<2 <6 <6 <2 <2 <600
<2 <11 <11 <2 <2 <1,100
<20 <20 <20 <20 <20 <180
<2.1 <2.1 <2.1 <2.1 <2.1 <18
<2.1 <2.1 <2.1 <2.1 <2.1 <18
<20 <20 <20 <20 <20 <180
<2 <3.7 <3.7 <2 3.1 <370
<2 <3.5 <3.5 <2 <2 <350
<20 <20 <20 <20 <20 <290
3.7 4.3 3.7 5.7 3.7 <18
8.7 18 9.2 13 9.4 100,000 J
<2 <2 <2 <2 <2 <30
<2 <2 <2 <2 <2 84
<2 <2 <2 <2 <2 <42
<2 <2 <2 <2 <2 <51
<2 <2 <2 <2 <2 <18
15 16 13 24 14 8,200
<2 <2 <2 <2 <2 <82
5.5 4.7 5.5 7.9 5.7 <16
21 25 21 36 22 2,900
<2 <2 <2 <2 <2 <15
<2 4.8 2 2.3 <2 3,100
<2 <2 <2 <2 <2 <43
<2 <2 <2 <2 <2 <32
<2 <2 <2 <2 <2 <28
17 22 19 28 18 29,000
<2 <2 <2 <2 <2 <27
<2 <2 <2 <2 <2 <120
<2 <2 <2 <2 <2 460
9.3 12 9.3 14 9.5 360
16 2.9 15 22 15 <50
Page 2 of 6 October 2019
TABLE 4A
ANALYTICAL RESULTS - JUNE 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including J qualified data but
not non-detect data. The total Table 3+ sum is rounded to two
significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be accurate or
precise.
17A 17B 18 19A
STW-LOC17A-062719 STW-LOC17B-062719 STW-LOC-18-062719 STW-LOC-19A-062719
6/27/2019 6/27/2019 06/27/2019 06/27/2019
TestAmerica TestAmerica TestAmerica TestAmerica
----
820,000,000 J 370,000,000 J 4.1 4.5 J
<210,000 UJ <85,000 UJ <5 UJ <5 UJ
<81,000 UJ <32,000 UJ 2.4 J 2.6 J
<58,000 UJ <23,000 UJ <2 UJ <2 UJ
<79,000 UJ <31,000 UJ <2 UJ <2 UJ
<34,000 UJ <13,000 UJ <2 UJ <2 UJ
<570,000 UJ <230,000 UJ <10 UJ <10 UJ
<47,000 UJ 63,000 J <20 UJ <20 UJ
<27,000 UJ <11,000 UJ <2 UJ <2 UJ
<30,000 UJ <12,000 UJ <2 UJ <2 UJ
<160,000 UJ <63,000 UJ <2 UJ <2 UJ
<58,000 UJ <23,000 UJ <2 UJ <2 UJ
<15,000 UJ <6,200 UJ <2 UJ <2 UJ
<54,000 UJ <21,000 UJ <2 UJ <2 UJ
<24,000 UJ <9,700 UJ <2 UJ <2 UJ
<28,000 UJ <11,000 UJ <2 UJ <2 UJ
<70,000 UJ <28,000 UJ <2 UJ <2 UJ
<46,000 UJ <18,000 UJ <2 UJ <2 UJ
<60,000 UJ <24,000 UJ <2 UJ <2 UJ
<41,000 UJ <16,000 UJ <2 UJ <2 UJ
820,000,000 370,000,000 6.5 7.1
<2,400,000 UJ <1,900 UJ <2 <2
<25,000,000 UJ <20,000 UJ <20 <20
<65,000,000 UJ <52,000 UJ <20 <20
<60,000 UJ <24,000 UJ <60 <60
<110,000 UJ <44,000 UJ <110 <110
<25,000,000 UJ <20,000 UJ <20 <20 UJ
<2,400,000 UJ <1,900 UJ <2.1 <2.1 UJ
<2,400,000 UJ <1,900 UJ <2.1 <2.1 UJ
<24,000,000 UJ <19,000 UJ <20 <20
60,000 J <15,000 UJ <37 <37
<35,000 UJ <14,000 UJ <35 <35
<39,000,000 UJ <31,000 UJ <20 <20
<2,500,000 UJ <2,000 UJ <2 <2
<4,400,000 UJ <3,500 UJ <3.3 2.4 J
<4,000,000 UJ <3,200 UJ <2 <2
<3,900,000 UJ 73,000 J <2 <2
<5,600,000 UJ <4,500 UJ <2 <2
<6,900,000 UJ <5,500 UJ <2 <2
<2,400,000 UJ <1,900 UJ <2 <2
<3,100,000 UJ 6,600 J 2.4 3.3 J
<11,000,000 UJ <8,900 UJ <2 UJ <2 UJ
4,000,000 J <1,700 UJ <2 <2
<7,300,000 UJ 6,700 J 3.5 6.1 J
<2,000,000 UJ <1,600 UJ <2 <2
<3,400,000 UJ 3,500 J <2 <2
<5,800,000 UJ <4,600 UJ <2 UJ <2 UJ
<4,400,000 UJ <3,500 UJ <2 <2
<3,800,000 UJ <3,000 UJ <2 <2
<6,100,000 UJ 28,000 J 3.6 5.3
<3,600,000 UJ <2,900 UJ <2 <2 UJ
<16,000,000 UJ <13,000 UJ <2 <2
<14,000,000 UJ <11,000 UJ <2 <2
<11,000,000 UJ 1,300,000 J <2 3.1 J
<6,800,000 UJ <5,400 UJ <2 <2
Page 3 of 6 October 2019
TABLE 4A
ANALYTICAL RESULTS - JUNE 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including J qualified data but
not non-detect data. The total Table 3+ sum is rounded to two
significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be accurate or
precise.
19B 20 21A 22 23A
STW-LOC-19B-062719 STW-LOC20-062819 STW-LOC-21A-062719 STW-LOC-22-062719 STW-LOC-23A-062719
06/27/2019 06/28/2019 06/27/2019 06/27/2019 06/27/2019
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
----------
9.6 50 40 130 J 170
<5 UJ 48 12 J 220 J 320
3.1 J 28 15 J 540 J 240
<2 UJ 9.3 2.9 J 27 J 87
<2 UJ 8.7 <2 UJ 32 J <79
<2 UJ 20 <2 UJ <6.7 UJ <34 UJ
<10 UJ 30 33 J 1,500 J 1,300
<20 UJ <20 <20 UJ 210 J 560
<2 UJ 260 9.7 J 180 J 17,000
21 J 110 2.2 J 150 J 740
<2 UJ 69 J 19 J 500 J 220
<2 UJ 390 J 11 J 13,000 J 2,900
<2 UJ 2 <2 UJ 23 J 19
<2 UJ 14 2.5 J 65 J <54
<2 UJ 7.3 <2 UJ <4.9 UJ 110
<2 UJ <2 <2 UJ <5.6 UJ 28
<2 UJ 12 J 4.1 J 54 J <70
<2 UJ <2 <2 UJ <9.2 UJ <46
<2 UJ <2 <2 UJ <12 UJ <60
<2 UJ <2 <2 UJ <8.2 UJ <41
34 1,100 150 17,000 24,000
<2 <2 <2 <2 <2
<20 <20 <20 <20 <20
<20 <20 <20 <20 <20
<60<2<60<60<60
<110 <2 <110 <110 <110
<20 <20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1 UJ <2.1
<2.1 <2.1 <2.1 <2.1 UJ <2.1
<20 <20 <20 <20 <20
<37<2<37<37<37
<35<2<35<35<35
<20 <20 <20 <20 <20
<2 3.8 4 3.4 3.8
3 8.8 9.8 37 J 70
<2 <2 <2 <2 <2
<2 <2 <2 2.4 2.8
<2 <2 <2 <2 <2
<2 <2 <2 <2 6.9
<2 <2 <2 <2 <2
415141214
<2 UJ <2 <2 <2 42
<2 5.8 6.2 5.6 5.8
6.8 23 23 21 J 24
<2 <2 <2 <2 <2
<2 <2 <2 2.3 2.9
<2 UJ <2 <2 <2 21
<2 <2 <2 <2 <2
<2 <2 <2 <2 <2
6 17 21 22 J 29
<2 <2 <2 <2 30
<2 <2 <2 <2 16
<2 <2 <2 <2 4.3
3.1 9.3 9.8 9.8 30
2.2 15 14 18 19
Page 4 of 6 October 2019
TABLE 4A
ANALYTICAL RESULTS - JUNE 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including J qualified data but
not non-detect data. The total Table 3+ sum is rounded to two
significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be accurate or
precise.
23B 24A 24A 24B 24C
STW-LOC-23B-062719 STW-LOC-24A-062719 STW-LOC-24A-062719-D STW-LOC24B-062719 STW-LOC24C-062719
06/27/2019 06/27/2019 06/27/2019 06/27/2019 06/27/2019
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
----Field Duplicate ----
3,200 26 26 10 16
160 J <5 UJ <5 UJ <5 <5
150 J 14 J 14 J 8.1 8.6
67 J 2.1 J 2.3 J <2 <2
61 J <2 UJ <2 UJ <2 <2
77 J <2 UJ <2 UJ <2 <2
19,000 J 26 J 30 J 17 14
8,500 J <20 UJ <20 UJ <20 <20
49 J <2 UJ 2.2 J 77 3.5
110 J <2 UJ <2.2 J 3.3 <2
580 J 9.6 J 4.4 J <2 13 J
450 J <2 UJ <2 UJ 11 J 5.3 J
4.5 J <2 UJ <2 UJ <2 <2
33 J <2 UJ 2 J <2 2
5.1 J <2 UJ <2 UJ <2 <2
21 J <2 UJ 4.4 J <2 <2
210 J 3.8 J 2.3 J <2 3.9 J
<9.2 UJ <2 UJ <2 UJ <2 <2
<12 UJ <2 UJ <2 UJ <2 <2
<8.2 UJ <2 UJ <2 UJ <2 <2
33,000 82 88 130 66
<3.5 <2 <2 <2 <2
<37 <20 <20 <20 <20
<20 <20 <20 <20 <20
<60 <60 <60 <2 <2
<110 <110 <110 <2 <2
20 J <20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20 <20
<37 <37 <37 2.9 2.3
<35 <35 <35 <2 <2
<20 <20 <20 <20 <20
2.5 3.5 3.4 3.5 3.8
580 9.7 9.4 9.6 8
<2 <2 <2 <2 <2
<2 <2 2.2 <2 <2
<2 <2 <2 <2 <2
<2 <2 <2 <2 <2
<2 <2 <2 <2 <2
10 13 13 13 13
<2 UJ <2 <2 <2 <2
<2 5.3 6 5 5.1
12 21 21 19 21
<2 <2 <2 <2 <2
2.5 <2 2.7 <2 <2
<2 UJ <2 <2 <2 <2
<2 <2 <2 <2 <2
<2 <2 <2 <2 <2
68 17 17 17 17
<2 UJ <2 <2 <2 <2
<2 <2 <2 <2 <2
<2 <2 <2 <2 <2
29 8.8 J 11 J 8.3 7.9
5 17 J 30 J 14 15
Page 5 of 6 October 2019
TABLE 4A
ANALYTICAL RESULTS - JUNE 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including J qualified data but
not non-detect data. The total Table 3+ sum is rounded to two
significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be accurate or
precise.
TBLK EQBLK EQBLK FBLK
STW-TBLK-1 STW-EQBLK-1 STW-EQBLK-2 STW-LOC-FBLK-1
06/28/2019 06/28/2019 06/27/2019 06/27/2019
TestAmerica TestAmerica TestAmerica TestAmerica
Trip Blank Equipment Blank Equipment Blank Field Blank
<4 <4 <4 <4
<5 <5 <5 <5
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<10 <10 <10 <10
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
ND ND ND ND
<2 <2 <2 <2
<20 <20 <20 <20
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
Page 6 of 6 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID 1 6A 6B 7A
Field Sample ID STW-LOC1-082219 STW-LOC6A-082119 STW-LOC6B-082119 STW-LOC7A-082219
Date Sampled 8/22/2019 8/21/2019 8/21/2019 8/22/2019
Analytical Laboratory TestAmerica TestAmerica TestAmerica TestAmerica
QA/QC--------
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)30 19 17 13
PFMOAA 25 <5 <5 6.7
PFO2HxA 21 12 11 9.4
PFO3OA 3.3 <2 <2 <2
PFO4DA <2<2<2<2
PFO5DA <2<2<2<2
PMPA 37 27 37 23
PEPA <20 <20 <20 <20
PFESA-BP1 <2 <2 <2 <2
PFESA-BP2 <2 <2 <2 <2
Byproduct 4 15 J <2 12 J 11 J
Byproduct 5 11 J 5.1 J 2.5 J 3.1 J
Byproduct 6 <2 <2 <2 <2
NVHOS 5.1 5.3 4.4 4.5
EVE Acid <2 <2 <2 <2
Hydro-EVE Acid <2 <2 <2 <2
R-EVE 4 J 3.9 3.2 J <2
PES <2<2<2<2
PFECA B <2<2<2<2
PFECA-G <2<2<2<2
Total Table 3+ Compounds*150 72 87 71
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate <2 <2 <2 <2
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<20 <20 <20 <20
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<20 <20 <20 <20
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2 <2 <2 <2
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <4 <4 <4 <4
6:2 Fluorotelomer sulfonate <20 <20 <20 <20
ADONA <2.1 <2.1 <2.1 <2.1
NaDONA <2.1 <2.1 <2.1 <2.1
N-ethyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20
N-ethylperfluoro-1-octanesulfonamide <2 <2 <2 <2
N-methyl perfluoro-1-octanesulfonamide <2 <2 <2 <2
N-methyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20
Perfluorobutane Sulfonic Acid 4 4.3 4.3 4.1
Perfluorobutanoic Acid 8.5 8.7 8.4 8.8
Perfluorodecane Sulfonic Acid <2 <2 <2 <2
Perfluorodecanoic Acid <2 <2 <2 <2
Perfluorododecane sulfonic acid (PFDoS)<2 <2 <2 <2
Perfluorododecanoic Acid <2 <2 <2 <2
Perfluoroheptane sulfonic acid (PFHpS)<2 <2 <2 <2
Perfluoroheptanoic Acid 20 21 20 20
Perfluorohexadecanoic acid (PFHxDA)<2 <2 <2 <2
Perfluorohexane Sulfonic Acid 5.6 6.5 5.8 6.1
Perfluorohexanoic Acid 26 27 27 26
Perfluorononanesulfonic acid <2 <2 <2 <2
Perfluorononanoic Acid <2 <2 <2 <2
Perfluorooctadecanoic acid <2 <2 <2 <2
Perfluorooctane Sulfonamide <2 <2 <2 <2
Perfluoropentane sulfonic acid (PFPeS)<2 <2 <2 <2
Perfluoropentanoic Acid 26 27 26 26
Perfluorotetradecanoic Acid <2 <2 <2 <2
Perfluorotridecanoic Acid <2 <2 <2 <2
Perfluoroundecanoic Acid <2 <2 <2 <2
PFOA 8.7 11 8.8 8.9
PFOS 12181515
F-53B Major <2<2<2<2
F-53B Minor <2 <2 <2 <2
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
Page 1 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
7B 8 9 10
STW-LOC7B-082219 STW-LOC8-082219 STW-LOC9-082219 STW-LOC10-082219
8/22/2019 8/22/2019 8/22/2019 8/22/2019
TestAmerica TestAmerica TestAmerica TestAmerica
--------
42 460 55 1,700
1,100 20,000 25 J 490 J
300 4,900 28 250
100 1,700 5.9 88
64 1,000 2.3 87
35 480 <2 42
45 160 48 180
<20 72 <20 63
6.9 58 86 380
180 1,700 8 510
110 J 340 81 J 870
1,100 J 4,600 160 J 730 J
4.1 43 <2 23
48 530 11 460
<2 <4.9 19 62
8.7 140 2.1 72
11 J 39 J 17 J 280 J
<2 <9.2 <2 <2
<2 <12 <2 <2
<2 <8.2 <2 <2
3,200 36,000 550 6,300
<2 <2 <2 <2
<20 <20 <20 <20
<20 <20 <20 <20
<2 <2 <2 <2
<4 <4 <4 <4
<20 <20 41 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
4 4.5 4.1 4.4
10 24 9.1 23
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
20 22 19 23
<2 <2 <2 <2
5.7 4.6 6.1 6
26 31 26 29
<2 <2 <2 <2
<2 3.2 <2 2.5
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
27 39 27 47
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
9.6 16 8.9 48
14 2.7 15 15
<2 <2 <2 <2
<2 <2 <2 <2
Page 2 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
12 14 15 18
STW-LOC12-082219 STW-LOC14-082219 STW-LOC15-082219 STW-LOC18-082119-1
8/22/2019 8/22/2019 8/22/2019 8/21/2019
TestAmerica TestAmerica TestAmerica TestAmerica
--------
17 14 43 7.1
<5 <5 12 <5
14 14 22 2.2
2.6 <2 5.3 <2
<2 <2 2.2 <2
<2 <2 <2 <2
26 33 38 <10 UJ
<20 <20 <20 <20
<2 <2 92 <2
<2 <2 8.2 <2
9.2 J 5 J 63 J 3.5 J
3 J <2 140 J <2
<2 <2 <2 <2
4.9 3.8 12 <2 UJ
<2 <2 22 <2
<2 <2 2.1 <2
3.5 J <2 15 J <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
80 70 480 13
<2 <2 <2 <2
<20 <20 <20 <20
<20 <20 <20 <20
<2 <2 <2 <2
<4 <4 <4 <4 UJ
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
6.5 4.2 4.1 <2
15 10 9.2 14 J
<2 <2 <2 <2
2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
33 21 20 5.1
<2 <2 <2 <2 UJ
8.5 6.1 5.9 <2
37 27 26 5.2
<2 <2 <2 <2
2.9 <2 <2 <2
<2 <2 <2 <2 UJ
<2 <2 <2 <2
<2 <2 <2 <2
37 27 28 3.7 J
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
16 10 9.4 2.8
22 15 16 <2
<2 <2 <2 <2
<2 <2 <2 <2
Page 3 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
18 18 18 19A
STW-LOC18-082119-2 STW-LOC18-082119-3 STW-LOC18-082119-4 STW-LOC19A-082119
8/21/2019 8/21/2019 8/21/2019 8/21/2019
TestAmerica TestAmerica TestAmerica TestAmerica
--------
11 7.6 120 18
<5 <5 <5 <5
4.4 3.8 20 5.1
<2 <2 5.1 <2
<2 <2 3.2 <2
<2 <2 <2 <2
18 21 64 J 21
<20 <20 26 <20
2 <2 54.5
<2 <2 6.4 <2
4.1 J 2.3 J 53 J <2 UJ
<2 <2 22 J <2
<2 <2 <2 <2
<2 4.4 6.4 <2
<2 <2 <2 <2
<2 <2 2.3 <2
2.1 J 3.2 J 26 J <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2 UJ
42 42 360 49
<2 <2 <2 <2
<20 <20 <20 <20
<20 <20 <20 <20
<2 <2 <2 <2
<4 <4 <4 UJ <4
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
<2 <2 <2 <2
7.1 J 7.9 12 J 2.9
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 2 <2 <2
<2 <2 <2 <2
9.2 8.9 6.3 5.1
<2 UJ <2 UJ <2 <2 UJ
2.6 2.5 <2 <2
11 12 7.6 6.8
<2 <2 <2 <2
<2 <2 <2 <2
<2 UJ <2 UJ <2 <2 UJ
<2 <2 <2 <2
<2 <2 <2 <2
11 11 7.3 7.1
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
5.4 5.1 4.2 3.7
6.4 7.6 4.1 2.4
<2 <2 <2 <2
<2 <2 <2 <2
Page 4 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
19B 20 20 21A
STW-LOC19B-082119 STW-LOC20-082219 STW-LOC20-082219-D STW-LOC21A-082119
8/21/2019 8/22/2019 8/22/2019 8/21/2019
TestAmerica TestAmerica TestAmerica TestAmerica
----Field Duplicate --
26 49 J 71 J 57
<5 650 J 630 9.5 J
5.3 210 J 210 13
<2 71 71 2.4
<2 44 46 <2
<2 19 22 2.2
26 39 46 53
<20 <20 <20 <20
53940 12
2.6 70 67 4.9
<2 63 J 74 J 31 J
<2 540 J 640 J 25 J
<2 <2 <2 <2
32828 33
<2 8.6 8.3 <2
<2 6.4 6.3 3.8
<2 11 J 12 J 34 J
<2 <2 <2 <2
<2 <2 <2 <2
<2 UJ <2 <2 <2
68 1,800 2,000 280
<2 <2 <2 <2
<20 <20 <20 <20
<20 <20 <20 <20
<2 <2 <2 <2
<4 <4 <4 <4
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
<2 4.2 4.2 4.5
4.6 10 10 12
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
7.9 20 20 23
<2 UJ <2 <2 <2
<2 5.9 6.3 6
11 26 27 29
<2 <2 <2 <2
<2 <2 <2 <2
<2 UJ <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
11 27 26 30
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
30 10 9.5 10
2.1 14 14 16
<2 <2 <2 <2
<2 <2 <2 <2
Page 5 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
22 23A 23A 23A
STW-LOC22-082119 STW-LOC23A-082119-1 STW-LOC23A-082119-2 STW-LOC23A-082119-3
8/21/2019 8/21/2019 8/21/2019 8/21/2019
TestAmerica TestAmerica TestAmerica TestAmerica
--------
140 11,000 25,000 15,000
36 J 1,200 1,300 1,600
45 J 280 350 390
5.5 73 110 110
6.5264846
3.8 J 11 22 19
20 J 82 120 <110
<20 33 54 45
47 4,500 12,000 12,000
54 210 570 520
59 J 190 400 350
770 J 3,800 7,400 7,000
<2 23.33.5
13 J 49 100 94
<2 52 150 130
3.9236152
7.5 J 16 25 27
<2 <2.3 <9.2 <9.2
<2 <3 <12 <12
<2 UJ <2 <8.2 <8.2
1,200 22,000 48,000 37,000
<2 <2 <2 <2
<20 <20 <20 <20
<20 <51 <50 <52
<2 <3 <12 <12
<4 <14 <13 <14
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <7.5 <7.5
<2 <2 <6.9 <6.9
<20 <30 <30 <31
<2 3.5 3.7 3.5
5.4 J 55 54 51
<2 <3.1 <3.1 <3.2
<2 <3 <3 <3.1
<2 <4.4 <4.3 <4.5
<2 <5.4 <5.3 <5.5
<2 <2 <2 <2
6.7242526
<2 <8.7 <8.6 <8.8
<2 6.2 6 6.1
6.9262624
<2 <2 <2 <2
<2 3.5 5.2 5
<2 <4.5 <4.4 <4.6
<2 <3.4 <3.4 <3.5
<2 <2.9 <2.9 <3
8313434
<2 <2.8 <2.8 <2.9
<2 <13 <13 <13
<2 <11 <11 <11
7.5 290 460 380
3.6233333
<2 <2.4 <2.3 <2.4
<2 <3.1 <3.1 <3.2
Page 6 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
23A 24A 24A 24B
STW-LOC23A-082119-4 STW-LOC24A-082119 STW-LOC24A-082119-D STW-LOC24B-082119
8/21/2019 8/21/2019 8/21/2019 8/21/2019
TestAmerica TestAmerica TestAmerica TestAmerica
----Field Duplicate --
12,000 16 17 8.9
1,200 11 12 <5
310 12 13 6.7
92 <2 2.1 <2
42 <2 <2 <2
21 J <2 <2 <2
<110 26 28 16
42 <20 <20 <20
12,000 <2 <2 <2
530 <2 <2 <2
350 9.7 J 11 J 5.3 J
7,000 4 J 4.2 J 2.4 J
3.1 <2 <2 <2
89 4.7 5.3 4.3
130 <2 <2 <2
52 <2 <2 <2
23 4.5 J 3.9 J 2.2 J
<9.2 <2 <2 <2
<12<2<2<2
<8.2 <2 <2 <2
34,000 88 97 46
<2 <2 <2 <2
<20 <20 <20 <20
<50 <20 <20 <20
<12<2<2<2
<13<4<4<4
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<7.5 <2 <2 <2
<6.9 <2 <2 <2
<30 <20 <20 <20
3.9 4.1 3.7 4.3
49 9.3 9 9.5
<3.1 <2 <2 <2
5.1 2.5 2 <2
<4.3 <2 <2 <2
<5.3 <2 <2 <2
<2 <2 <2 <2
23 19 18 21
<8.5 <2 <2 <2
6.5 6 5.8 5.8
27 26 26 25
<2 <2 <2 <2
4.8 2.7 2.1 <2
<4.4 <2 <2 <2
<3.3 <2 <2 <2
<2.9 <2 <2 <2
32 25 27 25
<2.8 <2 <2 <2
<12<2<2<2
<11<2<2<2
310 11 10 9.5
32 27 J 22 J 16
<2.3 <2 <2 <2
<3.1 <2 <2 <2
Page 7 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
24C TBLK z_EQBLK z_EQBLK
STW-LOC24C-082119 STW-TBLK-082219 STW-EB-01-082119 STW-EB-02-082119
8/21/2019 8/22/2019 8/21/2019 8/21/2019
TestAmerica TestAmerica TestAmerica TestAmerica
--Trip Blank Equipment Blank Equipment Blank
13 <2 <2 <2
<5 <5 <5 <5
7.6 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
23 <10 <10 <10
<20 <20 <20 <20
21 <2 <2 <2
3.3 <2 <2 <2
18 J <2 <2 <2
53 J <2 <2 <2
<2 <2 <2 <2
6.7 <2 <2 <2
2.1 <2 <2 <2
<2 <2 <2 <2
5.4 J <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
150 ND ND ND
<2 <2 <2 <2
<20 <20 <20 <20
<20 <20 <20 <20
<2 <2 <2 <2
<4 <4 <4 <4
<20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20
<2 <2 <2 <2
<2 <2 <2 <2
<20 <20 <20 <20
4.5 <2 <2 <2
8.4 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
22 <2 <2 <2
<2 <2 <2 <2
6.1 <2 <2 <2
27 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
26 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 2
9.8 <2 <2 <2
13 <2 <2 <2
<2 <2 <2 <2
<2 <2 <2 <2
Page 8 of 9 October 2019
TABLE 4B
ANALYTICAL RESULTS - AUGUST 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
F-53B Major
F-53B Minor
Notes:
* - Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
z_EQBLK z_FBLK
STW-EB-03-082119 STW-FB-082119
8/21/2019 8/21/2019
TestAmerica TestAmerica
Equipment Blank Field Blank
<2 <2
<5 <5
<2 <2
<2 <2
<2 <2
<2 <2
<10 <10
<20 <20
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
ND ND
<2 <2
<20 <20
<20 <20
<2 <2
<4 <4
<20 <20
<2.1 <2.1
<2.1 <2.1
<20 <20
<2 <2
<2 <2
<20 <20
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
<2 <2
Page 9 of 9 October 2019
TABLE 5A
TOTAL DAILY PRECIPITATION -
2019 QUARTER 2
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Date Total Precipitation
(inches)
4/1/2019 --
4/2/2019 1.0
4/3/2019 --
4/4/2019 --
4/5/2019 1.0
4/6/2019 --
4/7/2019 --
4/8/2019 --
4/9/2019 0.03
4/10/2019 --
4/11/2019 --
4/12/2019 1.1
4/13/2019 1.2
4/14/2019 0.23
4/15/2019 --
4/16/2019 --
4/17/2019 --
4/18/2019 --
4/19/2019 0.48
4/20/2019 --
4/21/2019 --
4/22/2019 --
4/23/2019 --
4/24/2019 --
4/25/2019 --
4/26/2019 0.05
4/27/2019 --
4/28/2019 --
4/29/2019 --
4/30/2019 --
5/1/2019 --
5/2/2019 --
5/3/2019 --
5/4/2019 0.16
5/5/2019 0.39
5/6/2019 --
5/7/2019 --
5/8/2019 --
5/9/2019 --
5/10/2019 --
5/11/2019 --
5/12/2019 0.13
5/13/2019 --
5/14/2019 --
5/15/2019 --
5/16/2019 --
5/17/2019 --
Page 1 of 2 October 2019
TABLE 5A
TOTAL DAILY PRECIPITATION -
2019 QUARTER 2
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Date Total Precipitation
(inches)
5/18/2019 --
5/19/2019 --
5/20/2019 0.24
5/21/2019 --
5/22/2019 --
5/23/2019 --
5/24/2019 --
5/25/2019 --
5/26/2019 --
5/27/2019 --
5/28/2019 --
5/29/2019 --
5/30/2019 --
5/31/2019 0.1
6/1/2019 --
6/2/2019 --
6/3/2019 --
6/4/2019 --
6/5/2019 0.8
6/6/2019 --
6/7/2019 --
6/8/2019 --
6/9/2019 2.2
6/10/2019 0.8
6/11/2019 0.1
6/12/2019 0.4
6/13/2019 --
6/14/2019 --
6/15/2019 --
6/16/2019 --
6/17/2019 --
6/18/2019 --
6/19/2019 --
6/20/2019 0.1
6/21/2019 --
6/22/2019 0.2
6/23/2019 --
6/24/2019 --
6/25/2019 --
6/26/2019 --
6/27/2019 --
6/28/2019 --
6/29/2019 --
6/30/2019 --
Notes:
-- - below USGS measurement threshold
Precipitation data obtained from USGS rain gauge at
W.O. Huske Dam.
72 hour period prior to sample collection date
Sample collection date
USGS - United States Geological Survey
Page 2 of 2 October 2019
TABLE 5B
TOTAL DAILY PRECIPITATION -
2019 QUARTER 3
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Date Total Precipitation
(inches)
7/1/2019 --
7/2/2019 0.03
7/3/2019 --
7/4/2019 1.72
7/5/2019 --
7/6/2019 --
7/7/2019 --
7/8/2019 0.43
7/9/2019 --
7/10/2019 0.01
7/11/2019 --
7/12/2019 0.15
7/13/2019 --
7/14/2019 --
7/15/2019 --
7/16/2019 --
7/17/2019 --
7/18/2019 --
7/19/2019 --
7/20/2019 --
7/21/2019 --
7/22/2019 --
7/23/2019 0.6
7/24/2019 --
7/25/2019 --
7/26/2019 --
7/27/2019 --
7/28/2019 --
7/29/2019 --
7/30/2019 --
7/31/2019 --
8/1/2019 0.25
8/2/2019 0.41
8/3/2019 0.01
8/4/2019 0.24
8/5/2019 --
8/6/2019 --
8/7/2019 --
8/8/2019 --
8/9/2019 --
8/10/2019 --
8/11/2019 --
8/12/2019 --
8/13/2019 --
8/14/2019 1.01
8/15/2019 0.01
Page 1 of 2 October 2019
TABLE 5B
TOTAL DAILY PRECIPITATION -
2019 QUARTER 3
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Date Total Precipitation
(inches)
8/16/2019 1.9
8/17/2019 0.74
8/18/2019 0.01
8/19/2019 --
8/20/2019 --
8/21/2019 0.06
8/22/2019 --
8/23/2019 0.16
8/24/2019 0.38
8/25/2019 0.01
8/26/2019 --
8/27/2019 --
8/28/2019 --
8/29/2019 --
8/30/2019 --
8/31/2019 --
9/1/2019 --
9/2/2019 0.04
9/3/2019 --
9/4/2019 0.1
9/5/2019 3.82
9/6/2019 0.1
9/7/2019 --
9/8/2019 --
9/9/2019 --
9/10/2019 --
9/11/2019 --
9/12/2019 --
9/13/2019 --
9/14/2019 --
9/15/2019 --
9/16/2019 --
9/17/2019 --
9/18/2019 --
9/19/2019 --
9/20/2019 --
9/21/2019 --
9/22/2019 --
9/23/2019 --
9/24/2019 --
9/25/2019 --
9/26/2019 --
9/27/2019 --
9/28/2019 --
9/29/2019 --
9/30/2019 --
Notes:
-- - below USGS measurement threshold
Precipitation data obtained from USGS rain gauge at
W.O. Huske Dam.
72 hour period prior to sample collection date
Sample collection date
USGS - United States Geological Survey
Page 2 of 2 October 2019
Figures
")
")
")
Willis Creek
Old Outfall 002Cape Fear RiverOutfall 002
W.O. Huske Dam
Site River Water Intake
NC Highway 87Seep A
Seep B
Seep C
Seep D
GBCTributary1GeorgiaBranchCreek
Site Location Map
Figure
1Raleigh
2,000 0 2,0001,000 Feet
³Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_SiteLocation.mxd; 10/22/2019October 2019
Legend
")Site Features
Site Boundary
Nearby Tributary
Observed Seep (Natural Drainage)
Site Drainage Network
Notes:1. The outline of the Cape Fear River shown on this figure is approximate (River outline based on compilation of open data sources fromArcGIS online service and North Carolina Department of Environmental Quality Online GIS - Major Hydro shapefile).2. Basemap sources: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS UserCommunity
Chemours Fayetteville Works, North Carolina
Areas at Site
Chemours Monomers IXM
Former DuPont PMDF Area
Wastewater Treatment Plant
Kuraray SentryGlas®Leased Area
Kuraray Trosifol®Leased Area
DuPont Polyvinyl FluorideLeased Area
Chemours PolymerProcessing Aid Area Power - Filtered andDemineralized WaterProductionKuraray Laboratory
")")
")
")
")
")
")")
")
")")
")@@@@@@Waste Water Treatment Plant Discharge
D u P o n t A r e aWoodLinedTrench
O p e n C h a n n e l t o O u t f a l l 0 0 2
C o o l i n g Wa t e r C h a n n e l Cape Fear
R
iver
21A
22
23A
16
17A
17B
18
19A
19B
23B
6A 6B
24B
24A24C
1
2 3
4
5
7A
8
910
11
12
13
14
15
20
7B
Paragraph 11(b) Sample Locations
Chemours Fayetteville Works, North Carolina
Figure
2Raleigh
500 0 500250 Feet
³Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_Paragraph11b_Sample_Locations.mxd Last Revised: 10/21/2019 Author: TIpOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Legend
!(Temporal Composite Sample
")Grab Sample
Sample Location Category
Intake
Stormwater
Discharge Areas
Wood Lined Trench
Cooling Water Channel
Open Channel to Outfall 002
Non-process wastewater
DuPont Area
Process wastewater
Outfall 002
Wastewater Treatment Plant Discharge
Other Connections
Terracotta Pipe and Piping Connected to Terracotta Pipe
Grouted Pipe Section
Pipe Connection to Facility
"
"
""
"@@@""
"
"
"@@@TR0795_Paragraph11b_Sample_Locations.ai
D u P o n t A r e aWoodLinedTrench
O p e n C h a n n e l t o O u t f a l l 0 0 2
C o o l i n g Wa t e r C h a n n e l
WastewaterTreatmentPlant Discharge Cape Fear
R
ive
r
21A
22
23A
18
19A19B
23B
6A 6B
24B
24A
24C
1
7A
8
9
14
15
20
7B
12
10
HFPO-DA, PFMOAA, and PMPA Concentrations -Locations that Reach Outfall 002
Chemours Fayetteville Works, North Carolina
Figure
3ARaleigh
500 0 500250 Feet
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_Stormwater_PFAS.mxd Last Revised: 2019-10-25 Author: SSomnarainOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Notes:
ng/L - nanograms per literJ - estimated valueUJ - estimated reporting limitDry - Insufficient water to collect sampleNS - not sampled; sample added to work plan after April sampling eventHFPO-DA - Hexafluoropropylene oxide dimer acidPFMOAA - Perfluoro-2-methoxyacetic acidPMPA - Perfluoromethoxypropyl carboxylic acid
1. See text for sample collection dates.2. All concentrations are in ng/L.3. Temporal composite samples collected over 4 hour interval.4. * - Samples collected in August 2019 at Locations 18 and 23A werecollected and analyzed as four individual grab samples collected over fourhours. Results presented here are the average result if the compound wasdetected in all four grab samples, otherwise, the result presented here isthe range of results observed. Individual results are provided in Table 4B.
Legend
Temporal Composite Sample
Grab Sample
Sample Location Category
Intake
Stormwater
Ditch Types
Wood Lined Trench
Cooling Water Channel
Open Channel to Outfall 002
Non-process wastewater
Process wastewater
Outfall 002
Other Connections
Pipe Connection to Facility
Terracotta Pipe and Piping Connected to Terracotta Pipe
Wastewater Treatment Plant Discharge
DuPont Area
Grouted Pipe Section
"
""
"@@@""
"
"
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HFPO-DA 14 10 8.9
PFMOAA ϭϭJ <5 <5
PMPA ϭϵ:17 16
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 16 J 26 16
PFMOAA ϳ͘ϱ:фϱh:11
PMPA Ϯϱ: Ϯϲ:26
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA NS 3,200 Dry
PFMOAA NS ϭϲϬ:Dry
PMPA NS 19,000 J Dry
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚΎ
HFPO-DA 270 170 16,000
PFMOAA 1,300 J 320 1,300
PMPA 700 J 1,300 <82 - 120
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 170 J 130 J 140
PFMOAA фϱh: ϮϮϬ:36 J
PMPA ϲϳ:ϭ͕ϱϬϬ:20 J
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 33 40 57
PFMOAA ϭϭ:ϭϮ:9.5 J
PMPA ϰϯ:ϯϯ:53
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 61 50 49
PFMOAA ϱϯJ 48 650 J
PMPA ϯϳ:30 39
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 22 9.6 26
PFMOAA <ϱh:<ϱh:<5
PMPA ϯϵ:<ϭϬh:26
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 30 J 4.5 J 18
PFMOAA <ϱh:<ϱh:<5
PMPA Ϯϳ:<ϭϬh:21
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚΎ
HFPO-DA 59 4.1 36
PFMOAA фϱh: фϱh:<5
PMPA ϰϰ:фϭϬh:<10 - 64
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 12 22 14
PFMOAA ϴJ <5 <5
PMPA ϭϱ:22 33
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 320 Dry 1,700
PFMOAA ϱϴJ Dry 490 J
PMPA 260 J Dry 180
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 14 18 30
PFMOAA ϳJ <5 25
PMPA Ϯϭ:23 37
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 29 77 55
PFMOAA ϴ͘ϴJ <21 25 J
PMPA Ϯϱ:<57 48
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 120 100 460
PFMOAA 1,200 J <21 20,000
PMPA <570 <57 160
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 21 18 42
PFMOAA ϱϭ:69 1,100
PMPA Ϯϯ:21 45
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 41 24 17
PFMOAA фϱh: фϱh:<5
PMPA Ϯϯ: Ϯϯ:37
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 13 66 19
PFMOAA фϱh:<ϱh:<5
PMPA Ϯϰ:Ϯϯ:27
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 14 22 13
PFMOAA ϴJ <5 6.7
PMPA Ϯϰ:22 23
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 19 16 13
PFMOAA ϭϭJ <5 <5
PMPA Ϯϴ:14 23
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA Dry Dry 17
PFMOAA Dry Dry <5
PMPA Dry Dry 26
Ɖƌŝů :ƵŶĞ ƵŐƵƐƚ
HFPO-DA 34 45 43
PFMOAA ϴ͘ϰJ 12 12
PMPA ϯϱ:25 38
D u P o n t A r e aWoodLinedTrench
O p e n C h a n n e l t o O u t f a l l 0 0 2
C o o l i n g Wa t e r C h a n n e l
WastewaterTreatmentPlant Discharge Cape Fea
r
R
iver
21A
22
23A
18
19A19B
23B
6A 6B
24B
24A
24C
1
7A
8
9
14
15
20
7B
12
10
Total Table 3+ Concentrations -Locations that Reach Outfall 002
Chemours Fayetteville Works, North Carolina
Figure
3BRaleigh
500 0 500250 Feet
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_Stormwater_PFAS_TotalTable3.mxd Last Revised: 2019-10-25 Author: SSomnarainOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Notes:
ng/L - nanograms per literDry - Insufficient water to collect sampleNS - not sampled - sample added to work plan after April sampling event
1. See text for sample collection dates.2. All concentrations are in ng/L.3. Temporal composite samples collected over 4 hour interval.4. * - Samples collected in August 2019 at Locations 18 and 23A werecollected and analyzed as four individual grab samples collected over fourhours. Results presented here are the range of results observed across allfour grab samples. Individual results are provided in Table 4B.
Legend
Temporal Composite Sample
Grab Sample
Sample Location Category
Intake
Stormwater
Ditch Types
Wood Lined Trench
Cooling Water Channel
Open Channel to Outfall 002
Non-process wastewater
DuPont Area
Process wastewater
Outfall 002
Wastewater Treatment Plant Discharge
Other Connections
Pipe Connection to Facility
Terracotta Pipe and Piping Connected to Terracotta Pipe
Grouted Pipe Section
"
""
"@@@""
"
"
"@@@/Data/PRJ/Projects/TR0795/Database and GIS/Illustrator/Wastewater and Stormwater Quarterly Report/Fig3BChemoursSampleLocations_WW_SW_TotalTable3_databoxes.aiTotal Table 3+Month
April 
June 00
August 550
Total Table 3+Month
April 2,900
June ,00
August 36,000
Total Table 3+Month
April 21
June 0
August 3,200
Total Table 3+Month
April 
June 6
August 71
Total Table 3+Month
April 
June 
August 
Total Table 3+Month
April 
June 
August 
Total Table 3+Month
April 3
June 
August 150
Total Table 3+Month
April 
June 10
August 45
Total Table 3+Month
April 
June 
August 88
Total Table 3+Month
April NS
June 33,000
August Dry
Total Table 3+Month
April 8,200
June 2,000
August*22,000 - 48,000
Total Table 3+Month
April 
June 
August 280
Total Table 3+Month
April 
June 7,00
August 1,200
Total Table 3+Month
April 
June 
August 1,800
Total Table 3+Month
April 
June 
August 68
Total Table 3+Month
April 
June 7.1
August 49
Total Table 3+Month
April 
June 6.5
August*13 - 360
Total Table 3+Month
April 26
June 1,00
August 480
Total Table 3+Month
April 
June 6
August 70
Total Table 3+Month
April Dry
June Dry
August 80
Total Table 3+Month
April 1,600
June Dry
August 6,300
Total Table 3+Month
April 
June 
August 150
D u P o n t A r e aWoodLinedTrench
O p e n C h a n n e l t o O u t f a l l 0 0 2
C o o l i n g Wa t e r C h a n n e l
WastewaterTreatmentPlant Discharge
16
17A
17B
HFPO-DA, PFMOAA, and PMPA Concentrations -Locations for Offsite Disposal
Chemours Fayetteville Works, North Carolina
Figure
3CRaleigh
500 0 500250 Feet
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_Loc_Offsite_16_17A_17B.mxd Last Revised: 2019-10-30 Author: SSomnarainOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Notes:
ng/L - nanograms per literJ - estimated valueUJ - estimated reporting limitHFPO-DA - Hexafluoropropylene oxide dimer acidPFMOAA - Perfluoro-2-methoxyacetic acidPMPA - Perfluoromethoxypropyl carboxylic acid
1. See text for sample collection dates.2. All concentrations are in ng/L.3. Location 16 is the location of the tanks holding process wastewater fromMonomers IXM.
Legend
Grab Sample
Sample Location Category
Process wastewater
Discharge Areas
Wood Lined Trench
Cooling Water Channel
Open Channel to Outfall 002
DuPont Area
Wastewater Treatment Plant Discharge
"
"/Data/PRJ/Projects/TR0795/Database and GIS/Illustrator/Wastewater and Stormwater Quarterly Report/Chemours_Sample_Loc_Osite_16_17A_17B_databoxes.aiƉƌŝů :ƵŶĞ
HFPO-DA 550,000,000 J 370,000,000 J
PFMOAA 1,770,000 J <85,000 UJ
PMPA <570,000 UJ <230,000 UJ
Ɖƌŝů :ƵŶĞ
HFPO-DA 860,000,000 J 820,000,000 J
PFMOAA <210,000 UJ <210,000 UJ
PMPA <570,000 UJ <570,000 UJ
Ɖƌŝů :ƵŶĞ
HFPO-DA 2,100,000 250,000 J
PFMOAA 170,000 J 35Ϭ,000
PMPA 5ϰϬ,000 J 5ϮϬ,000
Notes: Intake and Outfall 002 Concentrations - HFPO-DAChemours Fayetteville Works, North CarolinaAcronyms: ng / L: nanograms per literFigure4ARaleighOctober 2019Outfall 002 samples are 3.5 day composite samplesIntake samples are grab samples.1.0010.00100.001,000.0010,000.00100,000.00Concentration (ng/L)Outfall 002 External Lab AverageOutfall 002 External Lab DetectsOutfall 002 External Lab Non‐DetectsRiver Intake AverageRiver Intake DetectsRiver Intake Non‐Detects
Notes: Outfall 002 samples are 3.5 day composite samplesIntake samples are grab samples.Intake and Outfall 002 Concentrations - PFMOAAChemours Fayetteville Works, North CarolinaAcronyms: ng / L: nanograms per literFigure4BRaleighOctober 20191.0010.00100.001,000.0010,000.00100,000.00Concentration (ng/L)Outfall 002 External Lab AverageOutfall 002 External Lab DetectsOutfall 002 External Lab Non‐DetectsRiver Intake AverageRiver Intake DetectsRiver Intake Non‐Detects
Notes: Outfall 002 samples are 3.5 day composite samplesIntake samples are grab samples.Intake and Outfall 002 Concentrations - PMPAChemours Fayetteville Works, North CarolinaAcronyms: ng / L: nanograms per literFigure4CRaleighOctober 20191.0010.00100.001,000.0010,000.00100,000.00Concentration (ng/L)Outfall 002 External Lab AverageOutfall 002 External Lab DetectsOutfall 002 External Lab Non‐DetectsRiver Intake AverageRiver Intake DetectsRiver Intake Non‐Detects
Appendix A: Quarters 2 and 3 Supplemental
Sampling Activities
Geosyntec Consultants of NC, P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
31 October 2019
APPENDIX A:
QUARTERS 2 AND 3 SUPPLEMENTAL SAMPLING ACTIVITIES
The following supplemental sampling activities were conducted in Quarters 2 (April, May, June)
and 3 (July, August, September) in 2019.
Water and wastewater samples were collected from locations along the Terra Cotta pipe
upstream and downstream of the wastewater treatment plant (WWTP) to gather additional
data on PFAS concentrations in water that is processed at the WWTP before reaching
Outfall 002.
Supplemental Conveyance Network sampling (Cooling Water Channel and Open Channel
to Outfall 002) was completed to screen the sediments in the channel as a possible
secondary source of PFAS in Outfall 002. The samples were analyzed using a Table 3+
method for solids, which utilizes a solvent extraction process to quantify PFAS in the
sediment.
Supplemental dry weather water samples were collected along the Open Channel to Outfall
002 to evaluate if groundwater infiltration was affecting the variability of PFAS
concentrations in the Open Channel.
Results from the supplemental sampling activities were previously discussed in the Assessment of
HFPO-DA and PFMOAA in Outfall 002 Discharge and Evaluation of Potential Control Options
Report (Geosyntec, 2019c); however, some data from TestAmerica were pending at the time of
submission and data from the Chemours onsite laboratory in Fayetteville were presented in the
interim. All results discussed herein are from TestAmerica. Test America laboratory analytical
reports are provided in Appendix C.
Wastewater Treatment Plant Sampling
Wastewater samples were collected on July 16-18, 2019, from locations along the Terra Cotta pipe
upstream and downstream of the WWTP to gather additional data on PFAS in water that is
processed at the WWTP before reaching Outfall 002. Simultaneous 24-hour composite samples
were collected at Locations 1, 18, 22, 23A-1, 23A-2, and 23A (Figure A.1). A composite sample
31 October 2019 Page 2

was also collected at Location 8, approximately one hydraulic residence time (24 hours) after the
other locations. Sample locations are shown in Figure A.1 and PFAS results are provided in Table
A.1. The intent of this one-time sampling event was to further understandings of the inputs from
manufacturing areas to the WWTP. The findings of this sampling event are as follows:
 The water samples collected at Location 22 (the combined influent to the WWTP) reported
elevated HFPO-DA and PFMOAA concentrations (HFPO-DA: 790 ng/L, J qualified;
PFMOAA: 5,700 ng/L, J qualified), as well as elevated Byproduct 5 concentrations (58,000
ng/L, B qualified). This resulted in the highest reported Total Table 3+ concentration at
Location 22 (96,000 ng/L). The concentrations reported at Location 22 are not similar to
water samples collected and analyzed from upstream (Location 23A) or Outfall 001
(Location 8) sample locations. The autosampler at Location 22 became clogged with
sediment, roughly 8 hours into the sampling event. The interference of sediment in the
sampler makes it difficult to draw conclusions from this sampling event.
 HFPO-DA (12,000 ng/L, J qualified) was observed at Location 23A-1 (Kuraray
SentryGlas® process wastewater) and at Location 22 (790 ng/L, J qualified; the WWTP
combined influent). A lower concentration was observed at Location 8 (91 ng/L, Outfall
001).
 PFMOAA was observed at Location 23A (1,100 ng/L, combined Kuraray process water)
and at Location 22 (5,700 ng/L, J qualified, the WWTP combined influent). PFMOAA was
detected at 430 ng/L in Outfall 001 (Location 8).
 The elevated HFPO-DA observed in the sample collected from Location 23A-1 (12,000
ng/L, J qualified) does not appear to represent a significant source of mass loading to
downstream Location 23A where the HFPO-DA concentration was 120 ng/L, J qualified.
Elevated HFPO-DA and PFMOAA concentrations at Location 22 may be due to the autosampler
clogging with sediment; however, the magnitude of this interference cannot be evaluated without
further sampling. The WWTP sampling program will be repeated. Elevated PFAS concentrations
at Location 23A suggest that the remaining in use portions of the Terra Cotta pipe may continue
to be a minor source of PFAS to the WWTP. Kuraray and Chemours are planning to decommission
the remaining portion of the Terra Cotta pipe and replace it with an above ground pipe. After this
action is completed, future characterization will help assess the results of this action, and whether
additional sampling or characterization is needed.
31 October 2019 Page 3

Conveyance Network Sampling
Supplemental Cooling Water Channel and Open Channel to Outfall 002 sampling was completed
on July 3, 2019. The channels have sediments present in them at certain locations. Sediment
samples were collected as a screening level evaluation to understand the potential for sediments to
contribute to observed PFAS concentrations at Outfall 002 and to understand the potential benefit
of removing sediment from the conveyance network. The samples were analyzed using a newly
developed Table 3+ method for solids, which utilizes a solvent extraction to quantify PFAS in the
sediment. Composite samples were created from sediment grab samples. The locations of these
samples are show in Figure A.2 along with the total Table 3+ results for these samples. The PFAS
results are summarized in Table A.2.
The total Table 3+ concentrations varied among sediment sample locations between 24,000 and
3,200,000 ng/kg. The highest total Table 3+ concentrations were observed at Location C
(3,200,000 ng/kg), at the end of the cooling water channel before combining with the open channel
(Figure A.2). This result was made up entirely of byproduct PFESA-BP1. Due to the elevated
concentration of PFESA-BP1, dilution of the sample led to non-detects with elevated reporting
limits for other analytes. The sample collected at Location F, in the cooling water channel south
of Monomers IXM, had total Table 3+ concentration of 410,000 ng/kg, and was comprised of
PFESA-BP1 and PFESA-BP2. The primary and duplicate samples collected at Location G, in the
northwest corner of Monomers IXM, had lower total Table 3+ concentrations than the other
locations (44,000 and 24,000 ng/kg, respectively) but these samples included detects for several
PFAS. Nine PFAS were detected in the primary sample and seven PFAS were detected in the
duplicate sample, including HFPO-DA and PFMOAA in both samples. These results suggest that
sediments present in the Cooling Water Channel around the Monomers IXM Area contain PFAS
and may represent a source of PFAS that can contribute to concentrations at Outfall 002.
Based on these results, sediment removal from the Cooling Water Channel and Open Channel to
Outfall 002 was recommended as an action. During the October 2019 Plant Turn Around, sediment
was removed from the Cooling Water Channel in the Monomers IXM Area and from the Open
Channel to Outfall 002. Future characterization will help assess the results of this removal, and
whether additional sampling is needed.
Open Channel to Outfall 002 Sampling
Supplemental dry weather water samples were collected on May 30, 2019 along the Open Channel
to Outfall 002 to evaluate whether possible groundwater infiltration was affecting the variability
31 October 2019 Page 4

of PFAS in the Open Channel. The samples were collected from along the Open Channel to Outfall
002 after the last conveyance network tributary joins the channel (Figure A.3). Samples at
Locations 20B, 20C, and 20D were collected as spatial composite samples, where three grab
samples were collected from just below the water surface using a dip rod at three points along the
width of the open channel, then composited together in a stainless-steel vessel and poured into
HDPE bottles. Downstream of Location 20D and Location 20, the sample at Location 20E was
collected from within the sump at Outfall 002 as a grab sample using the autosampler at that
location.
Concentrations of HFPO-DA and PFMOAA in the supplemental outfall channel samples are
presented in Figure A.3. Sample results for all PFAS reported under Table 3+ Laboratory SOP and
EPA Method 537 Mod are provided in Table A.3.
HFPO-DA concentrations in samples collected along the Open Channel, upstream of Outfall 002
(Locations 20B, 20C, and 20D) were either non-detect (reporting limit of 86 ng/L) or were detected
between 89 ng/L and 130 ng/L. The sample collected at Location 20E, downstream of Outfall 002
in the sump, had detectable HFPO-DA at 110 ng/L.
The primary and duplicate samples at Location 20B, along with the samples at 20C, 20D, and 20E,
do not conclusively show a pattern in HFPO-DA concentrations upstream to downstream along
the Open Channel to Outfall 002. While the primary sample at Location 20B was not detected at
a reporting limit of 86 ng/L and Locations 20C and 20D showed a slight increase downstream, the
duplicate sample collected at Location 20B shows an HFPO-DA concentration higher than the
furthest downstream Location 20E. The range of values (non-detect at reporting limit of 86 ng/L
to 130 ng/L) are also within reasonable expectations of analytical variability.
Each of the supplemental outfall samples had elevated PFMOAA compared to results for Location
20 during April 2019, June 2019, and August 2019 events, ranging from 2,400 ng/L to 2,800 ng/L.
Similar to HFPO-DA, the PFMOAA concentrations at locations upstream of Outfall 002 did not
consistently show a pattern of being higher or lower than the PFMOAA reported at Location 20E,
downstream of Outfall 002. Several other PFAS were elevated in the supplemental outfall samples
that were non-detect or detected at much lower concentrations at Location 20 during the April
2019, June 2019, and August 2019 events. These observations are discussed in more detail in the
Observations of Elevated PFAS Concentrations at the Cape Fear River Intake and Outfall 002
Sample Locations in May and June 2019 (Geosyntec, 2019d).
31 October 2019 Page 5

Additional sampling may be recommended pending data from future bimonthly PFAS
characterization events. As discussed previously, sediment removal from the Open Channel to
Outfall 002 occurred during the October 2019 Plant Turn Around. Future characterization will
help assess the results of this action, and whether additional dry weather data is needed to further
understand what may be contributing to PFAS increases along the Open Channel portion of the
network to Outfall 002.
TABLE A.1
ANALYTICAL RESULTS - ADDITIONAL WASTEWATER
TREATMENT PLANT SAMPLES
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID 1 8 8
Field Sample ID WWTP-LOC1-071619 WWTP-LOC8-071819 WWTP-LOC8-071819-D
Date Sampled 7/16/2019 7/18/2019 7/18/2019
Analytical Laboratory TestAmerica TestAmerica TestAmerica
QA/QC ----Field Duplicate
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)14 J 91 110 J
PFMOAA 11 430 420
PFO2HxA 12 180 180
PFO3OA <2 89 85
PFO4DA <2 80 76
PFO5DA <2 170 160
PMPA 21 93 83
PEPA <20 50 J 31 J
PFESA-BP1 <2 26 25
PFESA-BP2 <2 2,200 2,100
Byproduct 4 14 J 340 360
Byproduct 5 6.3 J 2,800 J 2,800 J
Byproduct 6 <2 24 21
NVHOS 4 160 160
EVE Acid <2 <2 <2
Hydro-EVE Acid <2 98.2
R-EVE 3.7 J 31 30
PES <2 <2 <2
PFECA B <2 <2 <2
PFECA-G <2 <2 <2
Total Table 3+ Compounds* 38 2,900 2,900
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate <4.5 <4.5 <4.4
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) <2.7 <2.7 <2.7
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) <1.8 UJ <1.8 UJ <1.8
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2.7 UJ <2.7 UJ <2.7 UJ
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <2.7 UJ <2.7 UJ<2.7
6:2 Fluorotelomer sulfonate <4.5 <4.5 <4.4
DONA <1.8 <1.8 <1.8
N-ethyl perfluorooctane sulfonamidoacetic acid <2.7 <2.7 <2.7
N-ethylperfluoro-1-octanesulfonamide <4.5 UJ <4.5 UJ <4.4 UJ
N-methyl perfluoro-1-octanesulfonamide <2.7 UJ <2.7 UJ <2.7 UJ
N-methyl perfluorooctane sulfonamidoacetic acid <1.8 <1.8 <1.8
Perfluorobutane Sulfonic Acid 3.3 J 3.5 J 4 J
Perfluorobutanoic Acid 5.6 18 19
Perfluorodecane Sulfonic Acid <1.8 <1.8 <1.8
Perfluorodecanoic Acid <1.8 <1.8 <1.8
Perfluorododecane sulfonic acid (PFDoS)<2.7 <2.7 <2.7
Perfluorododecanoic Acid <1.8 <1.8 <1.8
Perfluoroheptane sulfonic acid (PFHpS)<1.8 <1.8 <1.8
Perfluoroheptanoic Acid 7.9 9.7 9.9
Perfluorohexadecanoic acid (PFHxDA)<2.7 <2.7 <2.7
Perfluorohexane Sulfonic Acid 5.8 4.6 4.2
Perfluorohexanoic Acid 13 16 17
Perfluorononanesulfonic acid <1.8 <1.8 <1.8
Perfluorononanoic Acid <1.8 2.6 2.6
Perfluorooctadecanoic acid <2.7 <2.7 <2.7
Perfluorooctane Sulfonamide <1.8 UJ <1.8 UJ <1.8
Perfluoropentane sulfonic acid (PFPeS)<1.8 <1.8 <1.8
Perfluoropentanoic Acid 14 23 25
Perfluorotetradecanoic Acid <1.8 UJ <1.8 UJ <1.8
Perfluorotridecanoic Acid <1.8 <1.8 <1.8
Perfluoroundecanoic Acid <1.8 <1.8 <1.8
PFOA 69 9.4
PFOS 11 2.3 2.6
Notes:
* - Total Table 3+ was calculated including B and J qualified
data but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
B - analyte detected in an associated blank
J - Analyte detected. Reported value may not be accurate or
preciseND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedureUJ – Analyte not detected. Reporting limit may not be accurate
or precise.
< - Analyte not detected above associated reporting limit.
Page 1 of 3 October 2019
TABLE A.1
ANALYTICAL RESULTS - ADDITIONAL WASTEWATER
TREATMENT PLANT SAMPLES
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including B and J qualified
data but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
B - analyte detected in an associated blank
J - Analyte detected. Reported value may not be accurate or
preciseND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedureUJ – Analyte not detected. Reporting limit may not be accurate
or precise.
< - Analyte not detected above associated reporting limit.
18 22 23
WWTP-LOC18-071619 WWTP-LOC22-071619 WWTP-LOC23-071619
7/16/2019 7/16/2019 7/16/2019
TestAmerica TestAmerica TestAmerica
------
43 J 790 J 120 J
<5 UJ 5,700 J 1,100
9.3 J 1,600 J 240
<2 UJ 1,200 J 78
<2 UJ 2,800 B 33
<2 UJ 3,100 B <2022 J 1,100 J <100
49 UJ <2,000 UJ <200
<2 UJ <200 UJ 8,000
<2 UJ 6,700 J 450
24 J 7,800 J 2709.4 J 58,000 B 4,600 J
<2 UJ <200 UJ <20
2.9 J 5,800 J 47
<2 UJ <200 UJ 79
<2 UJ 370 J 26
8.4 J 1,500 J <20
<2 UJ <200 UJ <20
<2 UJ <200 UJ <20
<2 UJ <200 UJ <20
120 96,000 4,700
<4.3 <490 <4.5 UJ
<2.6 <300 <2.7 UJ
<1.7 UJ <200 <1.8 UJ
<2.6 UJ <300 UJ 2.7 J
<2.6 UJ <300 <2.7 UJ
<4.3 <490 <4.5 UJ
<1.7 <200 <1.8 UJ
<2.6 <300 <2.7 UJ
<4.3 UJ <490 UJ <4.5 UJ
<2.6 <300 <2.7 UJ
<1.7 <200 2.6 J
<1.7 <200 3.2 J
18 J <490 110 J
<1.7 <200 <1.8 UJ
<1.7 <200 <1.8 UJ
<2.6 <300 <2.7 UJ
<1.7 <200 2.3 J
<1.7 <200 <1.8 UJ2.7 <200 9.2 J
<2.6 <300 4.6 J
1.8 <200 5.6 J
4.4 <200 15 J
<1.7 <200 <1.8 UJ
<1.7 <200 <1.8 UJ
<2.6 <300 <2.7 UJ
<1.7 UJ <200 <1.8 UJ
<1.7 <200 <1.8 UJ
7.3 <200 20 J
<1.7 UJ <200 7.2 J
<1.7 <200 4.9 J
<1.7 220 <1.8 UJ
3.1 <200 22 J
3.8 <200 13 J
Page 2 of 3 October 2019
TABLE A.1
ANALYTICAL RESULTS - ADDITIONAL WASTEWATER
TREATMENT PLANT SAMPLES
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:
* - Total Table 3+ was calculated including B and J qualified
data but not non-detect data. The total Table 3+ sum is rounded
to two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
B - analyte detected in an associated blank
J - Analyte detected. Reported value may not be accurate or
preciseND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedureUJ – Analyte not detected. Reporting limit may not be accurate
or precise.
< - Analyte not detected above associated reporting limit.
23A1 23A2 EB
WWTP-LOC23A1-071619 WWTP-LOC23A2-071619 WWTP-LOCEB-071819
7/16/2019 7/16/2019 7/18/2019
TestAmerica TestAmerica TestAmerica
----Equipment Blank
12,000 J 21 <2.7
33 12 <5
27 14 <2
4.6 <2 <2
3.6 <2 <2
2.9 <2 <211021<10
22 <20 <20
4.9 3.4 <2
15 <2 <2
190 13 <2
260 J 19 J <2
<2 <2 <2
63<2
<2 <2 <2
3.7 <2 <2
20 3.7 <2
<2 <2 <2
<2 <2 <2
<2 <2 <2
12,000 19 ND
<53 <4.1 <4.5
<32 <2.4 <2.7
<21 UJ <1.6 UJ <1.8 UJ
<32 UJ <2.4 UJ <2.7 UJ
<32 UJ <2.4 UJ <2.7 UJ
<53 <4.1 <4.5
<21 <1.6 <1.8
<32 <2.4 <2.7
<53 UJ <4.1 UJ <4.5 UJ
<32 <2.4 UJ <2.7
<21 <1.6 <1.8
<21 2.9 J <1.8
<53 6.2 <4.5
<21 <1.6 <1.8
<21 <1.6 <1.8
<32 <2.4 <2.7
<21 <1.6 <1.8
<21 <1.6 <1.8
<21 7.2 <1.8
<32 <2.4 <2.7
<21 5 <1.8
<21 11 <1.8
<21 <1.6 <1.8
<21 <1.6 <1.8
<32 <2.4 <2.7
<21 UJ <1.6 UJ <1.8 UJ
<21 <1.6 <1.8
98 12 <1.8
<21 UJ <1.6 UJ <1.8 UJ
<21 <1.6 <1.8
<21 <1.6 <1.8
460 6 <1.8
<21 9.3 <1.8
Page 3 of 3 October 2019
TABLE A.2ANALYTICAL RESULTS - COOLING WATER CHANNEL SEDIMENTSChemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.Location ID Location CLocation FLocation GLocation GFBLKField Sample IDSD-DNSS-C-070319 SD-DNSS-F-070319 SD-DNSS-G-070319 SD-DNSS-G-070319-D FB-SED-070319Date Sampled7/3/2019 7/3/2019 7/3/2019 7/3/2019 7/3/2019Analytical LaboratoryTestAmericaTestAmericaTestAmericaTestAmericaTestAmericaQA/QC------Field DuplicateField BlankTable 3+ Lab SOP (ng/kg)HFPO-DA<110,000 UJ<10,000 UJ3,200 J2,100 J--PFMOAA<280,000 UJ<23,000 UJ17,000 J8,300 J<5PFO2HxA<280,000 UJ<23,000 UJ5,400 J2,700 J<2PFO3OA<280,000 UJ<23,000 UJ4,500 J2,200 J<2PFO4DA<280,000 UJ<23,000 UJ4,900 J3,000 J<2PFO5DA<280,000 UJ<23,000 UJ<2,000 UJ2,300 J<2PMPA<280,000 UJ<23,000 UJ<2,000 UJ<1,900 UJ<10PEPA<280,000 UJ<23,000 UJ<2,000 UJ<1,900 UJ<20PFESA-BP13,200,000 J380,000 J2,700 J<1,900 UJ<2PFESA-BP2<280,000 UJ25,000 J3,600 J3,200 J<2Byproduct 4<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2Byproduct 5<110,000 UJ<9,300 UJ1,100 J<1,000 UJ<2Byproduct 6<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2NVHOS<110,000 UJ<9,300 UJ1,100 J<1,000 UJ<2EVE Acid<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2Hydro-EVE Acid<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2R-EVE<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2PES<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2PFECA B<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2PFECA-G<280,000 UJ<23,000 UJ<2,000 UJ<1,900 UJ<2Total Table 3+ Compounds*3,200,000410,00044,00024,000ND2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2N-ethylperfluoro-1-octanesulfonamide<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2N-methyl perfluoro-1-octanesulfonamide<110,000 UJ<9,300 UJ<1,000 UJ<1,000 UJ<2Notes:* - Total Table 3+ was calculated including J qualified data but not non-detect data. The total Table 3+ sum is rounded to two significant figures.Bold - Analyte detected above associated reporting limitND - No Table 3+ compounds were detected above their associated reporting limits.ng/kg - nanograms per kilogramQA/QC - Quality assurance/ quality controlSOP - standard operating procedure-- - Result not reported< - Analyte not detected above associated reporting limit. J - Analyte detected. Reported value may not be accurate or preciseUJ – Analyte not detected. Reporting limit may not be accurate or precise. Other PFAS (ng/kg)October 2019
TABLE A.3
ANALYTICAL RESULTS - ADDITIONAL OUTFALL 002 SAMPLES
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID 20B 20B 20C 20D
Field Sample ID FAY-SW-20B-053019 FAY-SW-DUP-053019 FAY-SW-20C-053019 FAY-SW-20D-053019
Date Sampled 05/30/2019 05/30/2019 05/30/2019 05/30/2019
Analytical Laboratory TestAmerica TestAmerica TestAmerica TestAmerica
QA/QC --Field Duplicate ----
Table 3+ Lab SOP (ng/L)
HFPO-DA <86 130 <86 89
PFMOAA 2,400 J 2,500 J 2,800 J 2,600 J
PFO2HxA 640 J 680 J 680 J 660 J
PFO3OA 300 J 320 J 340 J 320 J
PFO4DA 220 J 220 J 250 J 230 J
PFO5DA 140 J 140 J 160 J 150 J
PMPA <570 UJ <570 UJ 570 J <570 UJ
PEPA <47 UJ <47 UJ <47 UJ <47 UJ
PFESA-BP1 <27 UJ <27 UJ 36 J 32 J
PFESA-BP2 200 J 200 J 210 J 210 J
Byproduct 4 210 J 280 J 220 J 240 J
Byproduct 5 1,300 J 1,500 J 1,700 J 1,300 J
Byproduct 6 <15 UJ <15 UJ <15 UJ <15 UJ
NVHOS 110 J 110 J 140 J 110 J
EVE Acid <24 UJ <24 UJ <24 UJ <24 UJ
Hydro-EVE Acid <28 UJ <28 UJ <28 UJ <28 UJ
R-EVE <70 UJ 70 J <70 UJ <70 UJ
PES <46 UJ <46 UJ <46 UJ <46 UJ
PFECA B <60 UJ <60 UJ <60 UJ <60 UJ
PFECA-G <41 UJ <41 UJ <41 UJ <41 UJ
Total Table 3+ Compounds*5500 6200 7100 5900
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate --------1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)--------
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)--------
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <60 UJ <60 UJ <60 UJ <60 UJ
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <110 UJ <110 UJ <110 UJ <110 UJ
6:2 Fluorotelomer sulfonate --------
N-ethyl perfluorooctane sulfonamidoacetic acid --------
N-ethylperfluoro-1-octanesulfonamide <37 UJ <37 UJ <37 UJ <37 UJ
N-methyl perfluoro-1-octanesulfonamide <35 UJ <35 UJ <35 UJ <35 UJ
N-methyl perfluorooctane sulfonamidoacetic acid --------
Perfluorobutane Sulfonic Acid --------Perfluorobutanoic Acid --------
Perfluorodecane Sulfonic Acid --------
Perfluorodecanoic Acid --------
Perfluorododecane sulfonic acid (PFDoS)--------
Perfluorododecanoic Acid --------
Perfluoroheptane sulfonic acid (PFHpS)--------
Perfluoroheptanoic Acid --------
Perfluorohexadecanoic acid (PFHxDA)--------
Perfluorohexane Sulfonic Acid --------
Perfluorohexanoic Acid --------Perfluorononanesulfonic acid --------
Perfluorononanoic Acid --------
Perfluorooctadecanoic acid --------Perfluorooctane Sulfonamide --------
Perfluoropentane sulfonic acid (PFPeS)--------
Perfluoropentanoic Acid --------Perfluorotetradecanoic Acid --------
Perfluorotridecanoic Acid --------
Perfluoroundecanoic Acid --------PFOA --------
PFOS --------
Notes:* - Total Table 3+ was calculated including J qualified data but not
non-detect data. The total Table 3+ sum is rounded to two
significant figures.**Analyzed using EPA Method 537 Mod
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
J - Analyte detected. Reported value may not be accurate or precise
ng/L - nanograms per literQA/QC - Quality assurance/ quality control
SOP - standard operating procedure
UJ – Analyte not detected. Reporting limit may not be accurate or
precise
-- - No data reported
< - Analyte not detected above associated reporting limit.
Page 1 of 2 October 2019
TABLE A.3
ANALYTICAL RESULTS - ADDITIONAL OUTFALL 002 SAMPLES
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic AcidPerfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic AcidPerfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acidPerfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic AcidPerfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic AcidPFOA
PFOS
Notes:* - Total Table 3+ was calculated including J qualified data but not
non-detect data. The total Table 3+ sum is rounded to two
significant figures.**Analyzed using EPA Method 537 Mod
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
J - Analyte detected. Reported value may not be accurate or precise
ng/L - nanograms per literQA/QC - Quality assurance/ quality control
SOP - standard operating procedure
UJ – Analyte not detected. Reporting limit may not be accurate or
precise
-- - No data reported
< - Analyte not detected above associated reporting limit.
20E EQBLK FBLK
FAY-DSTW-OUTFALL002-053019 EB3-053019 FB7-053019
05/30/2019 05/30/2019 05/30/2019
TestAmerica TestAmerica TestAmerica
--Equipment Blank Field Blank
110 <86 <4.0**
2,500 J <210 UJ <210 UJ
640 J <81 UJ <81 UJ
320 J <58 UJ <58 UJ
220 J <79 UJ <79 UJ
140 J <34 UJ 37 J
640 J <570 UJ <570 UJ
<47 UJ <47 UJ <47 UJ
30 J <27 UJ <27 UJ
190 J <30 UJ <30 UJ
230 J <160 UJ <160 UJ
1,300 J <58 UJ <58 UJ
<15 UJ <15 UJ <15 UJ
100 J <54 UJ <54 UJ
<24 UJ <24 UJ <24 UJ
<28 UJ <28 UJ <28 UJ
<70 UJ <70 UJ <70 UJ
<46 UJ <46 UJ <46 UJ
<60 UJ <60 UJ <60 UJ
<41 UJ <41 UJ <41 UJ
6400 ND 37
----<2.0----<20
----<20
<60 UJ <60 UJ <60 UJ
<110 UJ <110 UJ <110 UJ
----<20
----<20
<37 UJ <37 UJ <37 UJ
<35 UJ <35 UJ <35 UJ
----<20
----<2.0----<2.0
----<2.0
----<2.0
----<2.0
----<2.0
----<2.0
----<2.0----<2.0
----<2.0
----<2.0----<2.0
----<2.0
----<2.0----<2.0
----<2.0
----<2.0----<2.0
----<2.0
----<2.0----<2.0
----<2.0
Page 2 of 2 October 2019
1
8
18
22*
23A
23A-1
23A-2
HFPO-DA and PFMOAA Concentrations from the Wastewater Treatment Plant Sampling Program
Chemours Fayetteville Works, North Carolina
Figure
A.1Raleigh
500 0 500250 Feet
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_WWTPreport_Sampling_PFAS.mxd Last Revised: 2019-10-25 Author: SSomnarainOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Notes:
ng/L - nanograms per literJ - estimated valueUJ - estimated reporting limitHFPO-DA - Hexafluoropropylene oxide dimer acidPFMOAA - Perfluoro-2-methoxyacetic acid
1. All concentrations are in ng/L.2. Samples collected on July 16, 2019 and July 18, 2019.3. Samples were collected as 24-hr composite samples.4. All samples were collected simultaneously except Location 8, which wascollected 1 hydraulic residence time (approximately 24 hours) after the otherlocations.5. Data reported here are from TestAmerica.6. * Due to a sediment blockage, sample was only collected over 8 hours.Results may potentially be influenced by presence of sediment.7. Aerial imagery provided by Esri basemaps (2017).
Sample Location Category
Intake
Process wastewater
Non-process wastewater
Legend
Pipe Connection to Facility
Terracotta Pipe and Piping Connected to Terracotta Pipe
Grouted Pipe Section
Temporal Composite Sample
Site Areas
Chemours Monomer IXM Area
Kuraray Trosifol® Manufacturing Operations
Kuraray Laboratory
Kuraray SentryGlas® Manufacturing Operations
Power - Filtered and Demineralized Water Production
Wastewater Treatment Plant
Fig A1.ChemoursSampleLocations_Wastewater_PFAS.aiHFPO-DA 14 J
PFMOAA 11
HFPO-DA 21
PFMOAA 12
HFPO-DA 91
PFMOAA 430
HFPO-DA 43 J
PFMOAA <5 UJ
HFPO-DA 790 J
PFMOAA 5,700 J
HFPO-DA 120 J
PFMOAA 1,100
HFPO-DA 12,000 J
PFMOAA 33
DuPont Area Cooling
Wa
te
r
Channe
l
Wood Lined
Trench
O pe n C ha n n e l t o O ut f al l 0 0 2 Cap
e

Fe
a
r
R
i
v
e
r
Location G44,000 / 24,000
Location F400,000
Location C200,000
Total Table 3+ Concentrations fromComposite Sediment Samples
Chemours Fayetteville Works, North Carolina
Figure
A.2Raleigh
500 0 500250 Feet
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_Composite_Sediment_Results.mxd Last Revised: 2019-10-28 Author: SSomnarainOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Notes:ng/kg - nanograms per kilogram1. All concentrations samples are in ng/kg.2. Both the results for the primary and duplicate samples arereported for Location G.3. Basemap source: Esri, DigitalGlobe, GeoEye, EarthstarGeographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN,and the GIS User Community
Legend
Composite Sediment Sample Location
Ditch Types
Wood Lined Trench
Wastewater Treatment Plant Discharge
Cooling Water Channel
Open Channel to Outfall 002
DuPont Area
D u P o n t A r e a
O p e n C h a n n e l t o O ut f a l l 0 0 2
WastewaterTreatmentPlant Discharge
20E20B
20C
20D
HFPO-DA and PFMOAA Concentrations – Additional Outfall 002 Samples - May 2019 Event
Chemours Fayetteville Works, North Carolina
Figure
A.3Raleigh
400 0 400200 Feet
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Wastewater and Stormwater Quarterly Report\TR0795_Outfall002Channel_Sampling_Results.mxd Last Revised: 2019-10-25 Author: SSomnarainOctober 2019
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Notes:
ng/L - nanograms per literJ - estimated value
1. All concentrations are in ng/L.2. Spatial composite samples collected as three grab samples alongchannel cross section then composited together.3. Samples collected May 30, 2019.4. Aerial imagery provided by Esri Basemaps (2017).
Legend
Grab Sample
Spatial Composite Sample
Sample Location Category
Non-process wastewater
Outfall 002
Stormwater
Process wastewater
Ditch Types
Wood Lined Trench
Cooling Water Channel
Open Channel to Outfall 002
DuPont Area
Wastewater Treatment Plant Discharge
"
HFPO-DA 89
PFMOAA 2,600 J
HFPO-DA 110
PFMOAA 2,500 J
HFPO-DA <86
PFMOAA 2,800 J
HFPO-DA <86
PFMOAA 2,400 J
130
2,500 J
DuplicatePrimary
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,&WKͲϰ͕ϮϬϬ
W&DK ϭϯϬ/Data/PRJ/Projects/TR0795/Database and GIS/Illustrator/Wastewater and Stormwater Quarterly Report/TR0795_AdditionalOutfallSamples_May2019.ai
Appendix B: Field Parameters
Geosyntec Consultants of NC, P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
31 October 2019
APPENDIX B: FIELD PARAMETERS
Field parameters recorded during the April, June, and August 2019 events are provided in Table
B.1 and Table B.2 for grab samples and temporal composite samples, respectively. Field
parameters were measured using a Horiba U-52 model. The water quality meter was calibrated at
the start of every sampling day, except for on August 21st, when the Turbidity meter could not be
calibrated due to lack of proper calibration solution.
For grab samples during the April, June, and August 2019 events, field parameters were measured
once prior to sampling using a flow through cell. For temporal composite samples during the April
2019 and August 2019 events, field parameters were measured twice using a flow through cell:
once during composite sampling (collected directly from the water stream), and once after
composite sampling (collected from the autosampler reservoir). For temporal composite samples
during the June 2019 event, field parameters were measured from the autosampler reservoir after
sampling.
Field parameter data from the April 2019 event were previously discussed in Characterization of
PFAS Concentration in Process and Non-Process Wastewater and Stormwater: Quarterly Report
#1 (Geosyntec, 2019b). Recorded field parameter data observed during the June and August 2019
events are generally in line with expectations for the sample locations, with the following
exceptions:
In June 2019, most locations had recorded pH between 6 and 9. Locations 18 and 22 had
pH greater than or equal to 10. Location 22, the combined influent to the wastewater
treatment plan (WWTP), had the highest measured pH at 11. Location 18, Kuraray process
wastewater flowing to the WWTP, had measured pH at 10. The treated effluent pH from
the WWTP at Location 8 was 6.9.
In August 2019, most locations had recorded pH between 6 and 9. Location 6, Kuraray
non-contact cooling water flowing to the WWTP, and Location 18, Kuraray process
wastewater flowing to the WWTP, each had measured pH at 10. The treated effluent pH
from the WWTP at location 8 was between 7.9 and 8.3.
31 October 2019 Page 2

 In August 2019, Location 23A, Kuraray SentryGlas® process water and non-contact
cooling water flowing to the WWTP, had the lowest measured pH at 4.7. The treated
effluent pH from the WWTP at Location 8 was between 7.9 and 8.3.
 In June 2019, Location 23B, Kuraray laboratory process wastewater flowing to the WWTP,
had dissolved oxygen (DO) measured at 0 mg/L. Other field parameter data for this location
were as expected; however, in general the DO measured for other grab sample locations
were also low (2 mg/L – 5 mg/L) compared to the other bimonthly sampling events (April:
6 mg/L – 11 mg/L, June: 3 mg/L – 9 mg/L). Additional field calibration data for DO will
be requested for the next sampling event to evaluate this further.
TABLE B.1GRAB SAMPLE FIELD PARAMETERS - QUARTERS 2 AND 3Chemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.AprilJuneAugustAprilJuneAugustAprilJuneAugust 6A7.97.88.32133340.0610.130.088 6B7.88.3102034330.0550.140.157BN/A7.9--N/A31--N/A0.25--16N/AN/AN/AN/AN/AN/AN/AN/AN/A17AN/AN/A--N/AN/A--N/AN/A--17BN/AN/AN/AN/AN/AN/AN/AN/AN/A186.210102336490.0740.870.67 19A6.47.37.33442260.0530.0680.002 19B7.28.06.62343340.160.110.60 21A7.86.98.32536330.0880.160.112211117.82741320.312.10N/A23A3.58.752235410.220.290.1423B--8.6Dry--31Dry--1.24Dry 24A9.87.98.12334300.0580.170.08 24B8.18.08.42331320.0880.170.11 24C8.58.78.22737330.0930.170.10Notes:-- - sample not collected°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltN/A - no data reportedNTU - nephelometric turbidity unitsORP - oxidation reduction potentialLocationpH Temperature (°C)Specific Conductivity (mS/cm)Page 1 of 2October 2019
TABLE B.1GRAB SAMPLE FIELD PARAMETERS - QUARTERS 2 AND 3Chemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C. 6A 6B7B1617A17B18 19A 19B 21A2223A23B 24A 24B 24CNotes:-- - sample not collected°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltN/A - no data reportedNTU - nephelometric turbidity unitsORP - oxidation reduction potentialLocationAprilJuneAugustAprilJuneAugustAprilJuneAugust*9.14.74.6380510270150009.14.94.4490290387000N/A4.3--N/A310--N/A0--N/AN/AN/AN/AN/AN/AN/AN/AN/AN/AN/A--N/AN/A--N/AN/A--N/AN/AN/AN/AN/AN/AN/AN/AN/A7.04.03.515018-463111.3776.92.98.7170330230630120190113.27.91702901205.90240105.34.2160390993.000.06.53.57.6-14-135711010.43108.72.03.7300801201.117.10--0.0Dry---230Dry--120Dry114.24.13302804306200114.54.4170290930.7006.54.25.41702801802.200Turbidity (NTU)Dissolved Oxygen (mg/L)ORP (mV)Page 2 of 2October 2019
TABLE B.2TEMPORAL COMPOSITE SAMPLE FIELD PARAMETERS - QUARTERS 2 AND 3 Chemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading18.07.6N/A6.48.48.12519N/A1331197A7.78.2N/A6.7N/A7.92122N/A10N/A177B--------N/A7.8--------N/A1788.18.2N/A6.98.37.92623N/A14371597.87.8N/A6.57.98.22722N/A103514107.58.2----8.58.02822----371312--------9.89.2--------3412148.98.1N/A7.39.59.12823N/A124211158.07.3N/A6.68.88.52922N/A133410208.87.4N/A7.08.37.92622N/A16349Notes:Initial reading collected at the start of sampling directly from the water stream.Final reading collected after sampling was complete, from autosampler reservoir.-- - sample not collected°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltN/A - no data reportedNTU - nephelometric turbidity unitsORP - oxidation reduction potentialpHTemperature (°C)LocationAprilJuneAugustJuneAugustAprilPage 1 of 3October 2019
TABLE B.2TEMPORAL COMPOSITE SAMPLE FIELD PARAMETERS - QUARTERS 2 AND 3 Chemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.17A7B891012141520Notes:Initial reading collected at the start of sampling directly from the water stream.Final reading collected after sampling was complete, from autosampler reservoir.-- - sample not collected°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltN/A - no data reportedNTU - nephelometric turbidity unitsORP - oxidation reduction potentialLocationInitial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading0.0640.053N/A0.120.0790.12167.2N/A6.65.55.40.0710.056N/A0.13N/A0.081114N/A5.5N/A7.4--------N/A0.13--------N/A6.71.70.95N/A1.81.630.928.17.3N/A5.05.97.40.0740.057N/A0.120.0780.0919.96.1N/A5.86.88.60.0970.069----0.0730.071266.9----6.78.7--------0.170.12--------9.75.70.160.09N/A0.230.170.091136.9N/A6.17.38.40.0270.061N/A0.130.160.075296.2N/A6.16.87.90.110.087N/A0.190.130.12127.1N/A5.28.28.3AugustSpecific Conductivity (mS/cm)Dissolved Oxygen (mg/L)AprilJuneAugustAprilJunePage 2 of 3October 2019
TABLE B.2TEMPORAL COMPOSITE SAMPLE FIELD PARAMETERS - QUARTERS 2 AND 3 Chemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC P.C.17A7B891012141520Notes:Initial reading collected at the start of sampling directly from the water stream.Final reading collected after sampling was complete, from autosampler reservoir.-- - sample not collected°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltN/A - no data reportedNTU - nephelometric turbidity unitsORP - oxidation reduction potentialLocationInitial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading Initial Reading Final Reading470200N/A37016023010057N/A8.59.08.6350100N/A320N/A2305558N/A4.0N/A7.3--------N/A220--------N/A9.532150N/A310180220242.7N/A11114.4240160N/A35025022010059N/A4.78.66.4230130----15023077310----2260--------76210--------2.14.545200N/A280992103.11.2N/A07.02.137220N/A35014023021048N/A7.48.06.843210N/A30014025023046N/A3.67.06.8Turbidity(NTU)AprilJuneAugustORP(mV)AprilJuneAugustPage 3 of 3October 2019
Appendix C: Re-issued Results from April
2019 Event
TABLE C
ANALYTICAL RESULTS - APRIL 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID 1 6A 6B 7A 7B
Field Sample ID DSTW-LOC1-042419 DSTW-LOC6A-042419 DSTW-LOC6B-042419 DSTW-LOC7A-042419 DSTW-LOC7B-042419
Date Sampled 04/24/2019 04/24/2019 04/24/2019 04/24/2019 04/24/2019
QA/QC ----------
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)14 13 41 14 21
PFMOAA 7 J <5 UJ <5 UJ 8 J 51 J
PFO2HxA 12 J 11 J 11 J 12 J 26 J
PFO3OA <2 UJ <2 UJ <2 UJ <2 UJ 6 J
PFO4DA <2 UJ <2 UJ <2 UJ <2 UJ 2.5 J
PFO5DA <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
PMPA 21 J 24 J 23 J 24 J 23 J
PEPA <20 UJ <20 UJ <20 UJ <20 UJ <20 UJ
PFESA-BP1 <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
PFESA-BP2 <2 UJ <2 UJ <2 UJ <2 UJ 7 J
Byproduct 4 11 J 8.1 J 11 J 5.3 J 19 J
Byproduct 5 3.2 J 4.3 J 3.6 J 4.2 J 53 J
Byproduct 6 <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
NVHOS <2 UJ <2 UJ <2 UJ <2 UJ 2.1 J
EVE Acid <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
Hydro-EVE Acid <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
R-EVE 6.4 J 2.6 J 6.6 J 3.9 J 4 J
PES <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
PFECA B <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
PFECA-G <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
Total Table 3+ Compounds*75 63 96 71 210
EPA Method 537 Mod (ng/L)
10:2 Fluorotelomer sulfonate <2.0 <2.0 <2.0 <2.0 <2.0
8:2 Fluorotelomersulfonic acid <20 <20 <20 <20 <20
4:2 Fluorotelomersulfonic acid <20 <20 <20 <20 <20
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <60 <60 <60 <60 900 J
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <110 <110 <110 <110 <110
6:2 Fluorotelomer sulfonate <20 <20 <20 <20 <20
ADONA <2.1 <2.1 <2.1 <2.1 <2.1
NaDONA <2.1 <2.1 <2.1 <2.1 <2.1
N-ethyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20
N-ethylperfluoro-1-octanesulfonamide <37 <37 UJ <37 UJ <37 <37 UJ
N-methyl perfluoro-1-octanesulfonamide <35 <35 UJ <35 UJ <35 <35
N-methyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20
Perfluorobutane Sulfonic Acid 2.3 2.4 2.3 2.3 2.3
Perfluorobutanoic Acid 7.1 7.6 7.1 7 5.2
Perfluorodecane Sulfonic Acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluorodecanoic Acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluorododecane sulfonic acid (PFDoS)<2.0 <2.0 <2.0 <2.0 <2.0
Perfluorododecanoic Acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluoroheptane sulfonic acid (PFHpS)<2.0 <2.0 <2.0 <2.0 <2.0
Perfluoroheptanoic Acid 7 7.4 7.4 7.4 7
Perfluorohexadecanoic acid (PFHxDA)<2.0 <2.0 <2.0 <2.0 <2.0
Perfluorohexane Sulfonic Acid 3.3 3.7 3.6 3.4 3.5
Perfluorohexanoic Acid 9.2 9.2 9.3 8.3 8.2
Perfluorononanesulfonic acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluorononanoic Acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluorooctadecanoic acid <2.0 <2.0 <2.0 2 <2.0
Perfluorooctane Sulfonamide <2.0 <2.0 <2.0 <2.0 <2.0
Perfluoropentane sulfonic acid (PFPeS)<2.0 <2.0 <2.0 <2.0 <2.0
Perfluoropentanoic Acid 7 7.4 7.2 6.5 7.2
Perfluorotetradecanoic Acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluorotridecanoic Acid <2.0 <2.0 <2.0 <2.0 <2.0
Perfluoroundecanoic Acid <2.0 <2.0 <2.0 <2.0 <2.0
PFOA 8.1 8.6 9.3 8.8 7.9
PFOS 12 14 14 14 14
Notes:*- Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded to
two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
Page 1 of 6 October 2019
TABLE C
ANALYTICAL RESULTS - APRIL 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
EPA Method 537 Mod (ng/L)
10:2 Fluorotelomer sulfonate
8:2 Fluorotelomersulfonic acid
4:2 Fluorotelomersulfonic acid
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:*- Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded to
two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
8 9 10 14 15
DSTW-LOC8-042419 DSTW-LOC9-042419 DSTW-LOC10-042419 DSTW-LOC14-042419 DSTW-LOC15-042419
04/24/2019 04/24/2019 04/24/2019 04/24/2019 04/24/2019
----------
120 29 320 12 34
1,200 J 8.8 J 58 J 67 J 8.4 J
480 17 J 88 J 10 J 17 J
150 4.5 J 24 J 2.1 J 4 J
<79 3.6 J 20 J <2 UJ 3.2 J
51 <2 UJ 9.1 J <2 UJ <2 UJ
<570 25 J 260 J 15 J 35 J
<47 <20 UJ 97 J <20 UJ <20 UJ
<27 28 J 78 J <2 UJ 22 J
240 3.4 J 19 J <2 UJ 4.3 J
<160 50 J 190 J 5.7 J 42 J
690 83 J 280 J 2.3 J 71 J
<15 <2 UJ <2 UJ <2 UJ <2 UJ
<54 2.8 J 14 J <2 UJ 3 J
<24 11 J 8.5 J <2 UJ 9.5 J
<28 <2 UJ 8.5 J <2 UJ <2 UJ
<70 7.5 J 150 J 3.2 J 10 J
<46 <2 UJ <2 UJ <2 UJ <2 UJ
<60 2.8 J <2 UJ <2 UJ <2 UJ
<41 <2 UJ <2 UJ <2 UJ <2 UJ
2,900 280 1,600 58 260
<2.0 <2.0 <2.0 <2.0 <2.0
<20 <20 <20 <20 <20
<20 <20 <20 <20 <20
<60 <60 <60 <60 <60
<110 <110 <110 <110 <110
<20 <20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20 <20
<37 <37 <37 <37 <37
<35 <35 <35 <35 <35
<20 <20 <20 <20 <20
2.4 2.2 2.1 <2.0 2.3
5.7 6.9 10 4.7 6.5
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
3.7 7.5 8.4 3.1 7.5
<2.0 <2.0 <2.0 <2.0 <2.0
3.1 3.3 3.5 3 3.5
4.9 9 9.3 4.4 7.9
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
4.2 8.6 17 3.8 8.2
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
8.2 8.9 10 5.8 8.5
<2.0 14 12 11 14
Page 2 of 6 October 2019
TABLE C
ANALYTICAL RESULTS - APRIL 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
EPA Method 537 Mod (ng/L)
10:2 Fluorotelomer sulfonate
8:2 Fluorotelomersulfonic acid
4:2 Fluorotelomersulfonic acid
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:*- Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded to
two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
16 17A 17B 18 19A
DSTW-LOC16-042419 DSTW-LOC17A-042419 DSTW-LOC17B-042419 DSTW-LOC18-042419 DSTW-LOC19A-042419
04/24/2019 04/24/2019 04/24/2019 04/24/2019 04/24/2019
----------
2,100,000 860,000,000 550,000,000 59 30 J
160,000 <210,000 1,770,000 <5 UJ < 5 UJ
133,000 <81,000 <81,000 21 J 4.8 J
44,000 <58,000 <58,000 3.1 J <2 UJ
<59,000 <79,000 <79,000 2 J <2 UJ
<25,000 <34,000 <34,000 <2 UJ <2 UJ
539,000 <570,000 <570,000 44 J 27 J
<35,000 110,000 47,000 <20 UJ <20 UJ
1,445,000 <27,000 <27,000 <2 UJ <2 UJ
248,000 <30,000 <30,000 3.2 J <2 UJ
2,410,000 <160,000 <160,000 11 J <2 UJ
330,000 <58,000 <58,000 13 J <2 UJ
54,000 <15,000 <15,000 <2 UJ <2 UJ
259,000 <54,000 <54,000 14 J <2 UJ
787,000 <24,000 <24,000 <2 UJ <2 UJ
95,000 <28,000 <28,000 <2 UJ <2 UJ
1,590,000 <70,000 <70,000 5.1 J <2 UJ
<34,000 <46,000 <46,000 <2 UJ <2 UJ
<45,000 <60,000 <60,000 <2 UJ <2 UJ
<31,000 <41,000 <41,000 <2 UJ <2 UJ
10,000,000 860,000,000 550,000,000 180 62
170 <2,400,000 <4,800 <2.0 <2.0
<480 <65,000,000 <130,000 <20 <20
<370 <25,000,000 <50,000 <20 <20
<45,000 <60,000 <60,000 <60 <60
<82,000 <110,000 <110,000 <110 <110
<370 <25,000,000 <50,000 <20 <20 UJ
<18 <2,400,000 <4,800 <2.1 <2.1 UJ
<18 <2,400,000 <4,800 <2.1 <2.1 UJ
<180 <24,000,000 <48,000 <20 <20
<28,000 <37,000 <37,000 <37 UJ <37 UJ
<26,000 <35,000 <35,000 <35 UJ <35 UJ
<290 <39,000,000 <78,000 <20 <20
<18 <2,500,000 <5,000 <2.0 <2.0 UJ
30,000 <4,400,000 <8,800 5.3 4.3 J
<29 <4,000,000 <8,000 <2.0 <2.0 UJ
240 <3,900,000 28,000 <2.0 <2.0 UJ
<41 <5,600,000 <11,000 <2.0 <2.0 UJ
<51 <6,900,000 <14,000 <2.0 <2.0 UJ
<18 <2,400,000 <4,800 <2.0 <2.0 UJ
13,000 <3,100,000 <6,300 3 <2.0 UJ
<82 <11,000,000 <22,000 <2.0 <2.0 UJ
<16 4,100,000 <4,300 2.1 <2.0 UJ
1,700 <7,300,000 <15,000 4.3 <2.0 UJ
<15 <2,000,000 <4,000 <2.0 <2.0 UJ
7,500 <3,400,000 <6,800 <2.0 <2.0 UJ
<42 <5,800,000 <12,000 <2.0 <2.0 UJ
<32 <4,400,000 <8,800 <2.0 <2.0 UJ
<28 <3,800,000 <7,500 <2.0 <2.0 UJ
53,000 <6,100,000 <12,000 3.7 2.6 J
<27 <3,600,000 <7,300 <2.0 <2.0 UJ
300 <16,000,000 <33,000 <2.0 <2.0 UJ
1,900 <14,000,000 <28,000 <2.0 <2.0 UJ
440 <11,000,000 1,800,000 6.7 2.6 J
<50 <6,800,000 <14,000 7.3 <2.0 UJ
Page 3 of 6 October 2019
TABLE C
ANALYTICAL RESULTS - APRIL 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
EPA Method 537 Mod (ng/L)
10:2 Fluorotelomer sulfonate
8:2 Fluorotelomersulfonic acid
4:2 Fluorotelomersulfonic acid
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:*- Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded to
two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
19B 20 20 21A 22
DSTW-LOC19B-042419 DSTW-LOC20-042419 DSTW-LOC20-042419-D DSTW-LOC21A-042419 DSTW-LOC22-042419
04/24/2019 04/24/2019 04/24/2019 04/24/2019 04/24/2019
----Blind Field Duplicate ----
22 61 63 33 170
<5 UJ 53 J 56 J 11 J <5 UJ
9.8 J 30 J 31 J 16 J <2 UJ
<2 UJ 6.9 J 6.7 J 2.9 J 3 J
<2 UJ 3.7 J 3.5 J 2 J 5.3 J
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
39 J 37 J 35 J 43 J 67 J
<20 UJ <20 UJ <20 UJ <20 UJ <20 UJ
<2 UJ 5.3 J 5.5 J 2.1 J 2 J
<2 UJ 7.8 J 7.9 J <2 UJ 18 J
6.5 J 28 J 27 J 4.2 J 160 J
3.5 J 68 J 68 J 4.1 J 170 J
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ 2.9 J 2.4 J <2 UJ 11 J
<2 UJ 2 J <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ 2.1 J
5.3 J 6.6 J 7.8 J 3.4 J 5.2 J
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
86 310 310 120 610
<2.0 <2.0 <2.0 <2.0 <2.0
<20 <20 <20 <20 <52
<20 <20 <20 <20 <20
<60 <60 <60 <60 <60
<110 <110 <110 <110 <110
<20 <20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20 <20
<37 UJ <37 <37 <37 UJ <37 UJ
<35 UJ <35 <35 <35 UJ <35 UJ
<20 <20 <20 <20 <31
<2.0 2.2 2.2 2 <2.0
4.4 6.5 5.9 5 <3.5 UJ
<2.0 <2.0 <2.0 <2.0 <3.2
<2.0 <2.0 <2.0 <2.0 <3.1
<2.0 <2.0 <2.0 <2.0 <4.5
<2.0 <2.0 <2.0 <2.0 <5.5
<2.0 <2.0 <2.0 <2.0 <2.0
2.2 7.1 7 3 7.1
<2.0 <2.0 <2.0 <2.0 <8.9
<2.0 3.5 3.5 3 4.5
3.4 7.8 7.7 4.4 <5.8
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.7
<2.0 <2.0 UJ <2.0 <2.0 <4.6
<2.0 <2.0 <2.0 <2.0 <3.5
<2.0 <2.0 <2.0 <2.0 <3.0
3.6 6.7 7.6 4.8 20
<2.0 <2.0 <2.0 <2.0 2.9
<2.0 <2.0 <2.0 <2.0 <13
<2.0 <2.0 <2.0 <2.0 <11
4.9 8.7 8.5 5.6 <8.5
3.2 13 13 9.1 <5.4
Page 4 of 6 October 2019
TABLE C
ANALYTICAL RESULTS - APRIL 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
EPA Method 537 Mod (ng/L)
10:2 Fluorotelomer sulfonate
8:2 Fluorotelomersulfonic acid
4:2 Fluorotelomersulfonic acid
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:*- Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded to
two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
23A 24A 24A 24B 24C
DSTW-LOC23A-042419 DSTW-LOC24A-042419 D DSTW-LOC24B-042419 DSTW-LOC24C-042419
04/24/2019 04/24/2019 04/24/2019 04/24/2019 04/24/2019
----Blind Field Duplicate ----
270 16 J 14 14 19
1,300 7.5 J <5 UJ 11 J 11 J
480 9.9 J 12 J 11 J 12 J
140 <2 UJ <2 UJ <2 UJ <2 UJ
<79 <2 UJ <2 UJ <2 UJ <2 UJ
<34 <2 UJ <2 UJ <2 UJ <2 UJ
700 25 J 26 J 19 J 28 J
<47 <20 UJ <20 UJ <20 UJ <20 UJ
2,700 <2 UJ <2 UJ <2 UJ 14 J
140 <2 UJ <2 UJ <2 UJ 2.1 J
180 3.6 J 5.4 J 5.1 J 39 J
2,200 2.7 J 3.1 J 4.3 J 51 J
<15 <2 UJ <2 UJ <2 UJ <2 UJ
<54 <2 UJ <2 UJ <2 UJ 4 J
65 <2 UJ <2 UJ <2 UJ 6.8 J
32 <2 UJ <2 UJ <2 UJ 3.7 J
<70 4 J 4.2 J 3.8 J 36 J
<46 <2 UJ <2 UJ <2 UJ <2 UJ
<60 <2 UJ <2 UJ <2 UJ <2 UJ
<41 < UJ <2 UJ <2 UJ <2 UJ
8,200 69 65 68 230
<2.0 <2.0 <2.0 <2.0 <2.0
<20 <20 <20 <20 <20
<20 <20 <20 <20 <20
<60 <60 <60 <60 <60
<110 <110 <110 <110 <110
<20 <20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20 <20
<37 <37 UJ <37 UJ <37 <37
<35 <35 UJ <35 UJ <35 <35
<20 <20 <20 <20 <20
<2.0 2.3 2.3 2.2 2
160 6.3 5.8 5.5 4.7
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <16 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
3.6 7 7.3 6 5.9
<2.0 <2.0 <2.0 <2.0 <2.0
2 3.9 3.8 3.3 3.4
6.6 8.5 8.8 8 7
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 2 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
13 7 6.7 6.2 6.4
<2.0 <5.9 <2.0 <2.0 <2.0
<2.0 <14 <2.0 <2.0 <2.0
<2.0 <2 <2.0 <2.0 <2.0
20 9.5 9.7 7.7 7.3
2.9 25 21 12 15
Page 5 of 6 October 2019
TABLE C
ANALYTICAL RESULTS - APRIL 2019 EVENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Field Sample ID
Date Sampled
QA/QC
Table 3+ Lab SOP (ng/L)
HFPO-DA (EPA Method 537 Mod)
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PFESA-BP1
PFESA-BP2
Byproduct 4
Byproduct 5
Byproduct 6
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ Compounds*
EPA Method 537 Mod (ng/L)
10:2 Fluorotelomer sulfonate
8:2 Fluorotelomersulfonic acid
4:2 Fluorotelomersulfonic acid
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
ADONA
NaDONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes:*- Total Table 3+ was calculated including J qualified data
but not non-detect data. The total Table 3+ sum is rounded to
two significant figures.
Bold - Analyte detected above associated reporting limit
EPA - Environmental Protection Agency
ND - No Table 3+ compounds were detected above their
associated reporting limits.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
J - Analyte detected. Reported value may not be accurate or
precise
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
EQBLK EQBLK EQBLK FBLK TBLK
DSTW-EB-01-042419 DSTW-EB-02-042419 DSTW-EB-03-042419 DSTW-FB-042419 DSTW-TB-042519
04/24/2019 04/24/2019 04/24/2019 04/24/2019 04/25/2019
Equipment Blank - Dip Equipment Blank - Equipment Blank - Field Blank Trip Blank
<4.0 <4.0 <4.0 <4.0 <4.0
<5 UJ <5 UJ <5 UJ <5 UJ <5 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<10 UJ <10 UJ <10 UJ <10 UJ <10 UJ
<20 UJ <20 UJ <20 UJ <20 UJ <20 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
ND ND ND ND ND
<2.0 <2.0 <2.0 <2.0 <2.0
<20 <20 <20 <20 <20
<20 <20 <20 <20 <20
820 J 850 J 780 J <60 <60
<110 <110 <110 <110 <110
<20 <20 <20 <20 <20
<2.1 <2.1 <2.1 <2.1 <2.1
<2.1 <2.1 <2.1 <2.1 <2.1
<20 <20 <20 <20 <20
<37 UJ <37 UJ <37 <37 <37
<35 <35 <35 <35 <35
<20 <20 <20 <20 <20
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0
Page 6 of 6 October 2019
Appendix D: Laboratory Reports and
DVM Workbooks
Laboratory Reports are provided on a USB
memory storage drive that was shipped with
the hard copies provided to NCDEQ
ADQM Data Review Narrative - FAY 2019 Dry Stormwater Samp update.doc 1 of 3
ADQM DATA REVIEW NARRATIVE

Site Chemours FAY – Fayetteville
Project 2019 Dry Stormwater Sampling (updated for completeness)
Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates April 24 - 25, 2019 Analytical Protocol

Laboratory Analytical Method Parameter(s)
TestAmerica - Sacramento 537 Modified PFAS1
TestAmerica - Sacramento Cl. Spec. Table 3 Compound SOP Table 3+ compounds

1 Perfluoroalkylsubstances, a list of 33 compounds including HFPO-DA. Sample Receipt
The following items are noted for this data set:

• All samples were received in satisfactory condition and within EPA temperature guidelines on
April 26, 2019, except for a waste acid sample (LOC17A) received on May 17, 2019.
• Some samples were reactivated outside the laboratory established hold time to allow reanalysis
by the low level Table 3+ method.
Data Review
The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process.
Overall the data is acceptable for use without qualification, except as noted below:

• Non-detect results for PPF Acid in one sample were qualified R and are considered to be
unusable due to very poor matrix spike (MS) relative percent recoveries (RPR). The lab revised reports to apply a Z qualifier for four Table 3+ compounds (DFSA, MMF, MTP, PPF Acid), indicating poor performance in the presence of matrix effects, including inconsistent sample
results. The data reviewer qualified these analytical results J as estimated, and non-detect results were qualified UJ indicating an estimated reporting limit, unless the DVM had already applied a B or R qualifier. Subsequently DFSA, MMF, MTP, and PPF Acid were dropped from the
method. These compounds were not reported for the waste acid sample.
• Professional judgement was used to overwrite R qualifiers, indicating an unusable result, that
were assigned by the DVM due to very poor matrix recoveries for PFMOAA and MTP in one sample. The qualifiers were updated to UJ, indicating an estimated reporting limit, because the
ADQM Data Review Narrative - FAY 2019 Dry Stormwater Samp update.doc 2 of 3
surrogate compound was a measurable labeled isotope compound, which is used for quantitation and provides a sample specific recovery correction of the sample results.
• Some of the analytical results have been qualified B, and may be biased high, or may be a false positive, because an associated field or equipment blank contained a comparable concentration.
• Several analytical results have been qualified J as estimated, and non-detect results qualified UJ indicating an estimated reporting limit, due to poor recovery of surrogate, laboratory blank spike, or matrix spike compounds; sample preparation and/or analysis which exceeded the laboratory
hold times; and poor laboratory blank spike, matrix spike, field duplicate or lab replicate precision. See the Data Verification Module (DVM) Narrative Report for which samples were
qualified, the specific reasons for qualification, and potential bias in reported results.
Attachments The DVM Narrative report is attached. The lab reports due to a large page count are stored on an
AECOM network shared drive and are available to be posted on external shared drives, or on a flash
drive.

ADQM Data Review Narrative - FAY 2019 Dry Stormwater Samp update.doc 3 of 3
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD
between these spikes
• Surrogate spike recoveries for organic analyses
• RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory
or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

DVM Narrative ReportAssociated MS and/or MSD analysis had relative percent recovery (RPR) values less than the data rejection level. The reported non-detect result isunusable.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC14-042419 04/24/2019 320-49620-8PPF Acid0.87 UG/LCl. Spec. Table 3Compound SOPRPFAS_DI_Prep0.38PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PPF Acid0.38 UG/LCl. Spec. Table 3Compound SOPRPFAS_DI_Prep0.38PQLPage 1 of 95
Contamination detected in equipment blank(s). Sample result does not differ significantly from the analyte concentration detected in the associatedequipment blank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC7B-042419 04/24/2019 320-49623-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.90 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.060PQLDSTW-LOC7B-042419 04/24/2019 320-49623-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.79 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.060PQLPage 2 of 95
Contamination detected in Field Blank(s). Sample result does not differ significantly from the analyte concentration detected in the associated fieldblank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC15-042419 04/24/2019 320-49620-9PPF Acid1.1 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PPF Acid1.1 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PPF Acid0.82 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PPF Acid0.72 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PPF Acid1.1 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PPF Acid0.93 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PPF Acid0.85 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PPF Acid0.88 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PPF Acid0.89 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PPF Acid0.96 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PPF Acid0.79 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PPF Acid0.56 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PPF Acid0.53 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PPF Acid0.59 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PPF Acid0.96 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PPF Acid0.82 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLPage 3 of 95
Contamination detected in Field Blank(s). Sample result does not differ significantly from the analyte concentration detected in the associated fieldblank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC9-042419 04/24/2019 320-49620-6PPF Acid0.82 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PPF Acid0.79 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.38PQLPage 4 of 95
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC22-042419 04/24/2019 320-49624-9Perfluorobutanoic Acid0.0035 UG/L537 ModifiedUJ3535_PFC0.0035PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFOS0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluoroundecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluoropentanesulfonic acid (PFPeS)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-66:2 Fluorotelomersulfonate0.020 ug/L537 ModifiedUJ3535_PFC0.020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorohexanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorododecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluorononanesulfonic acid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorotridecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6F-53B Major0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorooctaneSulfonamide0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluorododecanesulfonic acid (PFDoS)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6F-53B Minor0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6ADONA0.0021 UG/L537 ModifiedUJ3535_PFC0.0021PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6NaDONA0.0021 ug/L537 ModifiedUJ3535_PFC0.0021PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorodecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorodecaneSulfonic Acid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorohexaneSulfonic Acid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorobutaneSulfonic Acid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluoroheptanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluoroheptanesulfonic acid (PFHpS)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 5 of 95
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorononanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluorotetradecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 6 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC23A-042419 04/24/2019 320-49624-10 NVHOS0.054 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.054PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 NVHOS0.054 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.054PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO4DA0.079 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.079PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO4DA0.079 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.079PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLPage 7 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC16-042419 04/24/2019 320-49624-3MMF2700 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep2700PQLDSTW-LOC16-042419 04/24/2019 320-49624-3MMF2700 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep2700PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFECA B45 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep45PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFECA B45 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep45PQLDSTW-LOC16-042419 04/24/2019 320-49624-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol45 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep45PQLPage 8 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC16-042419 04/24/2019 320-49624-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol45 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep45PQLDSTW-LOC16-042419 04/24/2019 320-49624-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol82 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep82PQLDSTW-LOC16-042419 04/24/2019 320-49624-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol82 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep82PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PEPA35 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PEPA35 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO4DA59 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep59PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO4DA59 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep59PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO5DA25 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep25PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO5DA25 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep25PQLDSTW-LOC16-042419 04/24/2019 320-49624-3N-ethylperfluoro-1-octanesulfonamide28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLDSTW-LOC16-042419 04/24/2019 320-49624-3N-ethylperfluoro-1-octanesulfonamide28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFESA-BP127 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep27PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFESA-BP127 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep27PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1N-methyl perfluoro-1-octanesulfonamide35 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1N-methyl perfluoro-1-octanesulfonamide35 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO2HxA81 ug/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep81PQLPage 9 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO2HxA81 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep81PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO3OA58 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO3OA58 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO4DA79 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep79PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO4DA79 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep79PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO5DA34 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFO5DA34 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1N-ethylperfluoro-1-octanesulfonamide37 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep37PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1N-ethylperfluoro-1-octanesulfonamide37 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep37PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFMOAA210 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep210PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFMOAA210 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep210PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1EVE Acid24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1EVE Acid24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFESA-BP230 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep30PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFESA-BP230 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep30PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Hydro-EVE Acid28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLPage 10 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC17A-042419 04/24/2019 320-50472-1Hydro-EVE Acid28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFECA-G41 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep41PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFECA-G41 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep41PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1R-EVE70 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep70PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1R-EVE70 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep70PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Byproduct 4160 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep160PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Byproduct 4160 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep160PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Byproduct 558 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Byproduct 558 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Byproduct 615 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1Byproduct 615 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4NVHOS54 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep54PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4NVHOS54 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep54PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PES46 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep46PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PES46 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep46PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PMPA570 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep570PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PMPA570 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep570PQLPage 11 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC17B-042419 04/24/2019 320-49624-4MMF3600 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep3600PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4MMF3600 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep3600PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFECA B60 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFECA B60 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17B-042419 04/24/2019 320-49624-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol60 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17B-042419 04/24/2019 320-49624-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol60 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17B-042419 04/24/2019 320-49624-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep110PQLDSTW-LOC17B-042419 04/24/2019 320-49624-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep110PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PES34 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PES34 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLDSTW-LOC16-042419 04/24/2019 320-49624-3N-methyl perfluoro-1-octanesulfonamide26 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep26PQLDSTW-LOC16-042419 04/24/2019 320-49624-3N-methyl perfluoro-1-octanesulfonamide26 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep26PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFECA-G31 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep31PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFECA-G31 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep31PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFESA-BP127 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep27PQLPage 12 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC17B-042419 04/24/2019 320-49624-4PFESA-BP127 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep27PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4N-methyl perfluoro-1-octanesulfonamide35 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4N-methyl perfluoro-1-octanesulfonamide35 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO2HxA81 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep81PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO2HxA81 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep81PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO3OA58 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO3OA58 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO4DA79 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep79PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO4DA79 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep79PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO5DA34 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFO5DA34 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4N-ethylperfluoro-1-octanesulfonamide37 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep37PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4N-ethylperfluoro-1-octanesulfonamide37 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep37PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4EVE Acid24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4EVE Acid24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFESA-BP230 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep30PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFESA-BP230 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep30PQLPage 13 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC17B-042419 04/24/2019 320-49624-4Hydro-EVE Acid28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Hydro-EVE Acid28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFECA-G41 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep41PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFECA-G41 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep41PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4R-EVE70 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep70PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4R-EVE70 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep70PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Byproduct 4160 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep160PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Byproduct 4160 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep160PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Byproduct 558 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Byproduct 558 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Byproduct 615 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4Byproduct 615 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1NVHOS54 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep54PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1NVHOS54 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep54PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PES46 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep46PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PES46 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep46PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PMPA570 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep570PQLPage 14 of 95
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC17A-042419 04/24/2019 320-50472-1PMPA570 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep570PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFECA B60 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PFECA B60 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17A-042419 04/24/2019 320-50472-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol60 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17A-042419 04/24/2019 320-50472-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol60 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLDSTW-LOC17A-042419 04/24/2019 320-50472-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep110PQLDSTW-LOC17A-042419 04/24/2019 320-50472-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep110PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4DFSA3100 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep3100PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4DFSA3100 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep3100PQLPage 15 of 95
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC9-042419 04/24/2019 320-49620-6PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC9-042419 04/24/2019 320-49620-6MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC9-042419 04/24/2019 320-49620-6MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC8-042419 04/24/2019 320-49620-5PPF Acid0.38 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.38PQLDSTW-LOC8-042419 04/24/2019 320-49620-5PPF Acid0.38 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.38PQLDSTW-LOC8-042419 04/24/2019 320-49620-5MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC8-042419 04/24/2019 320-49620-5MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLPage 16 of 95
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24B-042419 04/24/2019 320-49620-1MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 MTP0.12 UG/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep0.12PQLPage 17 of 95
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC10-042419 04/24/2019 320-49620-7PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC10-042419 04/24/2019 320-49620-7MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC1-042419 04/24/2019 320-49620-3MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC1-042419 04/24/2019 320-49620-3MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC15-042419 04/24/2019 320-49620-9MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC15-042419 04/24/2019 320-49620-9MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-FB-042419 04/24/2019 320-49620-10 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-FB-042419 04/24/2019 320-49620-10 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC16-042419 04/24/2019 320-49624-3MTP91 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep91PQLPage 18 of 95
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC16-042419 04/24/2019 320-49624-3MTP91 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep91PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4MTP120 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep120PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4MTP120 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep120PQLDSTW-LOC18-042419 04/24/2019 320-49624-5MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLPage 19 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC6B-042419 04/24/2019 320-49624-2N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLPage 20 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC21A-042419 04/24/2019 320-49624-8R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC22-042419 04/24/2019 320-49624-9N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC22-042419 04/24/2019 320-49624-9N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC22-042419 04/24/2019 320-49624-9R-EVE0.070 UG/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep0.070PQLPage 21 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PPF Acid0.38 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.38PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PPF Acid0.38 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.38PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 DFSA3.1 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep3.1PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 DFSA3.1 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep3.1PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLPage 22 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 40.16 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.16PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 40.16 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.16PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLDSTW-LOC14-042419 04/24/2019 320-49620-8R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-LOC14-042419 04/24/2019 320-49620-8R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLDSTW-EB-01-042419 04/24/2019 320-49623-2N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-EB-01-042419 04/24/2019 320-49623-2N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-EB-02-042419 04/24/2019 320-49623-3N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-EB-02-042419 04/24/2019 320-49623-3N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC18-042419 04/24/2019 320-49624-5N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC18-042419 04/24/2019 320-49624-5N-methyl perfluoro-1-0.035 ug/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep0.035PQLPage 23 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsoctanesulfonamideSOPDSTW-LOC18-042419 04/24/2019 320-49624-5N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC18-042419 04/24/2019 320-49624-5N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 24 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC9-042419 04/24/2019 320-49620-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 25 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC7A-042419 04/24/2019 320-49620-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 26 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC7A-042419 04/24/2019 320-49620-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 27 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC7A-042419 04/24/2019 320-49620-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 28 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-TB-042519 04/25/2019 320-49623-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-TB-042519 04/25/2019 320-49623-5PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-TB-042519 04/25/2019 320-49623-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-TB-042519 04/25/2019 320-49623-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 29 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-TB-042519 04/25/2019 320-49623-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-TB-042519 04/25/2019 320-49623-5PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-TB-042519 04/25/2019 320-49623-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 30 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-TB-042519 04/25/2019 320-49623-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-TB-042519 04/25/2019 320-49623-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 31 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24B-042419 04/24/2019 320-49620-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 32 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24B-042419 04/24/2019 320-49620-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLPage 33 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC6A-042419 04/24/2019 320-49624-1PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 34 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC6B-042419 04/24/2019 320-49624-2NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 35 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC6B-042419 04/24/2019 320-49624-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 36 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC21A-042419 04/24/2019 320-49624-8PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 37 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC21A-042419 04/24/2019 320-49624-8PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 38 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC22-042419 04/24/2019 320-49624-9PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC22-042419 04/24/2019 320-49624-9EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 39 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24A-042419 04/24/2019 320-49624-11 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 40 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 41 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 42 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC10-042419 04/24/2019 320-49620-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 43 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC1-042419 04/24/2019 320-49620-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 44 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC14-042419 04/24/2019 320-49620-8PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 45 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC14-042419 04/24/2019 320-49620-8PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 46 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-01-042419 04/24/2019 320-49623-2PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-EB-01-042419 04/24/2019 320-49623-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 47 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-01-042419 04/24/2019 320-49623-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 48 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-02-042419 04/24/2019 320-49623-3PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-EB-02-042419 04/24/2019 320-49623-3EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 49 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-02-042419 04/24/2019 320-49623-3Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-02-042419 04/24/2019 320-49623-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 50 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-03-042419 04/24/2019 320-49623-4PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-EB-03-042419 04/24/2019 320-49623-4EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 51 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-03-042419 04/24/2019 320-49623-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-03-042419 04/24/2019 320-49623-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-FB-042419 04/24/2019 320-49620-10 PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 52 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-FB-042419 04/24/2019 320-49620-10 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO2HxA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-FB-042419 04/24/2019 320-49620-10 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 53 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-FB-042419 04/24/2019 320-49620-10 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-FB-042419 04/24/2019 320-49620-10 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 54 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-01-042419 04/24/2019 320-49623-2NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-EB-01-042419 04/24/2019 320-49623-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 55 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC15-042419 04/24/2019 320-49620-9Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC18-042419 04/24/2019 320-49624-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 56 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC18-042419 04/24/2019 320-49624-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 57 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 58 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19A-042419 04/24/2019 320-49624-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 59 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19B-042419 04/24/2019 320-49624-7PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 60 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC20-042419 04/24/2019 320-49620-11 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 61 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the data rejection level. The reporting limit may be bi-ased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC14-042419 04/24/2019 320-49620-8PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLDSTW-LOC14-042419 04/24/2019 320-49620-8MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLDSTW-LOC14-042419 04/24/2019 320-49620-8MTP0.12 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.12PQLPage 62 of 95
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may bebiased high.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC23A-042419 04/24/2019 320-49624-10 MMF7.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 MMF5.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLPage 63 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19B-042419 04/24/2019 320-49624-7MMF12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7MMF11.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6MMF17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC18-042419 04/24/2019 320-49624-5R-EVE0.0051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5R-EVE0.0046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Byproduct 40.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Byproduct 40.0096 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Byproduct 50.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5Byproduct 50.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5MMF15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC18-042419 04/24/2019 320-49624-5MMF13.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC14-042419 04/24/2019 320-49620-8R-EVE0.0032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8R-EVE0.0029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 40.0057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8Byproduct 40.0065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9R-EVE0.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 64 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC15-042419 04/24/2019 320-49620-9R-EVE0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Byproduct 40.042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Byproduct 40.043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Byproduct 50.071 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9Byproduct 50.074 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3R-EVE0.0064 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3R-EVE0.0062 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Byproduct 40.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Byproduct 50.0032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Byproduct 50.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7R-EVE0.15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Byproduct 40.19 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Byproduct 40.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Byproduct 50.28 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Byproduct 50.31 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 R-EVE0.0042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 R-EVE0.0044 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 65 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 50.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 50.0028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 R-EVE0.0040 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 R-EVE0.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 40.0036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Hfpo Dimer Acid0.016 UG/L537 ModifiedJ3535_PFC0.0040PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 50.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 50.0038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8R-EVE0.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8R-EVE0.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 40.0042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8Byproduct 40.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 R-EVE0.0066 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 R-EVE0.0070 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Byproduct 40.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Byproduct 40.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 66 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC20-042419 04/24/2019 320-49620-11 Byproduct 50.068 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 Byproduct 50.070 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8MMF19 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 R-EVE0.0078 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 R-EVE0.0068 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Byproduct 40.027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Byproduct 40.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Byproduct 50.068 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 Byproduct 50.057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2R-EVE0.0066 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2R-EVE0.0076 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Byproduct 40.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Byproduct 50.0036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Byproduct 50.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1R-EVE0.0026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1R-EVE0.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Byproduct 40.0081 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 67 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC6A-042419 04/24/2019 320-49624-1Byproduct 40.0075 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Byproduct 50.0043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1Byproduct 50.0037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2R-EVE0.036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2R-EVE0.036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Byproduct 40.039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Byproduct 40.039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Byproduct 50.051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Byproduct 50.051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1R-EVE0.0038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1R-EVE0.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Byproduct 40.0051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Byproduct 40.0055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Byproduct 50.0043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1Byproduct 50.0038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 50.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 68 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 50.0030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC8-042419 04/24/2019 320-49620-5DFSA8.8 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.1PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1R-EVE0.0040 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1R-EVE0.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Byproduct 40.019 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Byproduct 40.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Byproduct 50.053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1Byproduct 50.050 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4R-EVE0.0039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4R-EVE0.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Byproduct 40.0053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Byproduct 40.0052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Byproduct 50.0042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4Byproduct 50.0044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6R-EVE0.0075 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6R-EVE0.0068 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Byproduct 40.050 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 69 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC9-042419 04/24/2019 320-49620-6Byproduct 40.046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Byproduct 50.083 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6Byproduct 50.081 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 70 of 95
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 40.0054 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 Byproduct 40.0057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 MMF9.5 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 MMF8.8 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 Byproduct 40.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 MMF14.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLPage 71 of 95
High relative percent difference (RPD) observed between LCS and LCSD samples. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC14-042419 04/24/2019 320-49620-8MMF4.9 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC14-042419 04/24/2019 320-49620-8MMF4.9 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLPage 72 of 95
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19A-042419 04/24/2019 320-49624-6Perfluorobutanoic Acid0.0043 UG/L537 ModifiedJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFOA0.0026 UG/L537 ModifiedJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PerfluoropentanoicAcid0.0026 UG/L537 ModifiedJ3535_PFC0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6Hfpo Dimer Acid0.03 UG/L537 ModifiedJ3535_PFC0.0040PQLPage 73 of 95
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC20-042419 04/24/2019 320-49620-11 PMPA0.037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PMPA0.031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6MMF15.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PEPA180 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep47PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PEPA180.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep47PQLDSTW-LOC1-042419 04/24/2019 320-49620-3Byproduct 40.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PEPA0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.047PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PEPA0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.047PQLDSTW-LOC10-042419 04/24/2019 320-49620-7R-EVE0.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFMOAA0.058 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFMOAA0.066 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO2HxA0.0099 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8MMF15.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2MMF19.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC8-042419 04/24/2019 320-49620-5DFSA4.8 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.1PQLPage 74 of 95
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC8-042419 04/24/2019 320-49620-5PFMOAA1.5 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLPage 75 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC20-042419 04/24/2019 320-49620-11 PFESA-BP10.0053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFESA-BP10.0056 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO2HxA0.031 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO2HxA0.031 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO3OA0.0069 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO3OA0.0067 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO4DA0.0037 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFO4DA0.0034 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 NVHOS0.0029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 NVHOS0.0029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7R-EVE0.0053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7R-EVE0.0054 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Byproduct 40.0065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Byproduct 40.0063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Byproduct 50.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7Byproduct 50.0039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO2HxA0.0098 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 76 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19B-042419 04/24/2019 320-49624-7PFO2HxA0.010 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO2HxA0.0048 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PFO2HxA0.0047 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PMPA0.039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7PMPA0.042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PMPA0.027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6PMPA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFESA-BP20.0032 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFESA-BP20.0033 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO2HxA0.021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO2HxA0.021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO3OA0.0031 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO3OA0.0033 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PMPA0.044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC18-042419 04/24/2019 320-49624-5PMPA0.044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 77 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC18-042419 04/24/2019 320-49624-5NVHOS0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC18-042419 04/24/2019 320-49624-5NVHOS0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PMPA0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PMPA0.032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PMPA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PMPA0.020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO2HxA0.010 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO3OA0.0021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFO3OA0.0021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PMPA0.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PMPA0.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFMOAA0.0080 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC14-042419 04/24/2019 320-49620-8PFMOAA0.0081 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFESA-BP10.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 78 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC15-042419 04/24/2019 320-49620-9PFESA-BP10.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO2HxA0.017 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO2HxA0.017 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO3OA0.0040 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO3OA0.0040 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO4DA0.0032 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFO4DA0.0032 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9NVHOS0.0030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9NVHOS0.0030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9EVE Acid0.0095 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9EVE Acid0.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFESA-BP20.0043 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFESA-BP20.0044 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PMPA0.26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PMPA0.26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC10-042419 04/24/2019 320-49620-7NVHOS0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7NVHOS0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 79 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC1-042419 04/24/2019 320-49620-3PFMOAA0.0070 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC1-042419 04/24/2019 320-49620-3PFMOAA0.0073 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PEPA0.097 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PEPA0.10 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFESA-BP10.078 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFESA-BP10.076 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO2HxA0.088 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO2HxA0.090 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO3OA0.024 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO3OA0.024 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO4DA0.020 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO4DA0.021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO5DA0.0091 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFO5DA0.0097 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7EVE Acid0.0085 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7EVE Acid0.0087 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7PFESA-BP20.019 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 80 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC10-042419 04/24/2019 320-49620-7PFESA-BP20.019 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Hydro-EVE Acid0.0085 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC10-042419 04/24/2019 320-49620-7Hydro-EVE Acid0.0087 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PMPA0.019 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PMPA0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PMPA0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 PMPA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PMPA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PMPA0.029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 50.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 50.18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9R-EVE0.0052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9R-EVE0.0057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 40.16 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Byproduct 40.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 81 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC22-042419 04/24/2019 320-49624-9PFESA-BP20.018 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFESA-BP20.018 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Hydro-EVE Acid0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9Hydro-EVE Acid0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFESA-BP20.0079 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFESA-BP20.0078 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFESA-BP10.0055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFESA-BP10.0057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO2HxA0.030 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO2HxA0.030 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO3OA0.0067 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO3OA0.0065 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO4DA0.0035 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFO4DA0.0035 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 NVHOS0.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 82 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC20-042419 04/24/2019 320-49620-11 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFESA-BP20.0078 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFESA-BP20.0076 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO2HxA0.016 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO2HxA0.016 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO3OA0.0029 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO3OA0.0029 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PMPA0.043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PMPA0.042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PMPA0.035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PMPA0.036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PMPA0.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 83 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC6A-042419 04/24/2019 320-49624-1PMPA0.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1PMPA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFESA-BP10.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFESA-BP10.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2NVHOS0.0040 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2NVHOS0.0044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFMOAA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24B-042419 04/24/2019 320-49620-1PFMOAA0.0098 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PMPA0.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PMPA0.029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2EVE Acid0.0068 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2EVE Acid0.0067 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFESA-BP20.0021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 84 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC24C-042419 04/24/2019 320-49620-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Hydro-EVE Acid0.0037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2Hydro-EVE Acid0.0037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PMPA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC9-042419 04/24/2019 320-49620-6NVHOS0.0028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6NVHOS0.0028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFESA-BP20.0070 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFESA-BP20.0066 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PMPA0.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PMPA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFO2HxA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFMOAA0.0080 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC7A-042419 04/24/2019 320-49620-4PFMOAA0.0082 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLPage 85 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC7B-042419 04/24/2019 320-49623-1PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PMPA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1NVHOS0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1NVHOS0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO2HxA0.026 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO2HxA0.025 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO3OA0.0060 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO3OA0.0056 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO4DA0.0025 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFO4DA0.0025 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFESA-BP10.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFESA-BP10.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO2HxA0.017 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO2HxA0.017 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO3OA0.0045 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO3OA0.0046 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFO4DA0.0036 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 86 of 95
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC9-042419 04/24/2019 320-49620-6PFO4DA0.0035 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6EVE Acid0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6EVE Acid0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFESA-BP20.0034 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFESA-BP20.0033 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 87 of 95
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC17B-042419 04/24/2019 320-49624-4PFMOAA1800.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep210PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PFMOAA2000 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep210PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PEPA93.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep47PQLDSTW-LOC17A-042419 04/24/2019 320-50472-1PEPA110 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep47PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PPF Acid49000.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep380PQLDSTW-LOC17B-042419 04/24/2019 320-49624-4PPF Acid49000 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep380PQLDSTW-LOC16-042419 04/24/2019 320-49624-3R-EVE1600.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep53PQLDSTW-LOC16-042419 04/24/2019 320-49624-3R-EVE1700 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep53PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Byproduct 42400.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep120PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Byproduct 42500 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep120PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Byproduct 5330 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep44PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Byproduct 5360.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep44PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Byproduct 654 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep12PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Byproduct 655.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep12PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO2HxA130.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep61PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO2HxA140 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep61PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFO3OA53 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep44PQLPage 88 of 95
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC16-042419 04/24/2019 320-49624-3PFO3OA53.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep44PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PMPA540.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep430PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PMPA600 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep430PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PPF Acid350.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep280PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PPF Acid390 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep280PQLDSTW-LOC16-042419 04/24/2019 320-49624-3DFSA50000.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2300PQLDSTW-LOC16-042419 04/24/2019 320-49624-3DFSA56000 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2300PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFMOAA170 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep160PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFMOAA170.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep160PQLDSTW-LOC16-042419 04/24/2019 320-49624-3EVE Acid790.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep18PQLDSTW-LOC16-042419 04/24/2019 320-49624-3EVE Acid820 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep18PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFESA-BP2250.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep23PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFESA-BP2250 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep23PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Hydro-EVE Acid95 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep21PQLDSTW-LOC16-042419 04/24/2019 320-49624-3Hydro-EVE Acid99.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep21PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFESA-BP11400.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep20PQLDSTW-LOC16-042419 04/24/2019 320-49624-3PFESA-BP11500 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep20PQLPage 89 of 95
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC16-042419 04/24/2019 320-49624-3NVHOS260.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep40PQLDSTW-LOC16-042419 04/24/2019 320-49624-3NVHOS270 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep40PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO2HxA0.48 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO2HxA0.5 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO3OA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFO3OA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Byproduct 40.18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Byproduct 40.18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Byproduct 52.2 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Byproduct 52.1 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFMOAA1.3 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFMOAA1.3 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 EVE Acid0.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.024PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 EVE Acid0.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.024PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFESA-BP20.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFESA-BP20.13 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 Hydro-EVE Acid0.032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.028PQLPage 90 of 95
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC23A-042419 04/24/2019 320-49624-10 Hydro-EVE Acid0.03 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.028PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFESA-BP12.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PFESA-BP12.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PMPA0.70 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.57PQLDSTW-LOC23A-042419 04/24/2019 320-49624-10 PMPA0.59 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.57PQLPage 91 of 95
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC19B-042419 04/24/2019 320-49624-7MTP0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC19B-042419 04/24/2019 320-49624-7MTP0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6MTP0.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC19A-042419 04/24/2019 320-49624-6MTP0.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-FB-042419 04/24/2019 320-49620-10 PPF Acid0.72 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.38PQLDSTW-FB-042419 04/24/2019 320-49620-10 PPF Acid0.94 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.38PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 MTP0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC24A-042419-D 04/24/2019 320-49624-12 MTP0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC22-042419 04/24/2019 320-49624-9MTP0.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC22-042419 04/24/2019 320-49624-9MTP0.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1MTP0.20 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC6A-042419 04/24/2019 320-49624-1MTP0.22 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLDSTW-LOC8-042419 04/24/2019 320-49620-5PFMOAA1.2 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLPage 92 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-EB-01-042419 04/24/2019 320-49623-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.82 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.060PQLDSTW-EB-01-042419 04/24/2019 320-49623-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.82 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.060PQLDSTW-EB-03-042419 04/24/2019 320-49623-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.78 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.060PQLDSTW-EB-03-042419 04/24/2019 320-49623-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.86 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.060PQLDSTW-EB-02-042419 04/24/2019 320-49623-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.85 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.060PQLDSTW-EB-02-042419 04/24/2019 320-49623-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.82 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.060PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFMOAA0.0084 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC15-042419 04/24/2019 320-49620-9PFMOAA0.0092 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFMOAA0.0074 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 PFMOAA0.0062 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24A-042419 04/24/2019 320-49624-11 MMF15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PMPA0.067 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PMPA0.071 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLDSTW-LOC22-042419 04/24/2019 320-49624-9MMF7.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLPage 93 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsDSTW-LOC22-042419 04/24/2019 320-49624-9MMF6.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO3OA0.0030 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO3OA0.0031 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO4DA0.0053 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9PFO4DA0.0055 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9NVHOS0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC22-042419 04/24/2019 320-49624-9NVHOS0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFMOAA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC21A-042419 04/24/2019 320-49624-8PFMOAA0.010 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFMOAA0.053 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC20-042419 04/24/2019 320-49620-11 PFMOAA0.054 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFMOAA0.056 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC20-042419-D 04/24/2019 320-49620-12 PFMOAA0.051 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC6B-042419 04/24/2019 320-49624-2MMF15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep3.6PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFMOAA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC24C-042419 04/24/2019 320-49620-2PFMOAA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC7B-042419 04/24/2019 320-49623-1PFMOAA0.051 ug/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0050PQLPage 94 of 95
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Dry Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPDSTW-LOC7B-042419 04/24/2019 320-49623-1PFMOAA0.051 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFMOAA0.0088 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLDSTW-LOC9-042419 04/24/2019 320-49620-6PFMOAA0.0088 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLPage 95 of 95
ADQM Data Review Narrative - FAY Additional Outfall Samples.doc 1 of 2
ADQM DATA REVIEW NARRATIVE

Site Chemours FAY – Fayetteville
Project Additional Outfall Samples
Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates May 30, 2019 Analytical Protocol

Laboratory Analytical Method Parameter(s)
TestAmerica - Sacramento Cl. Spec. Table 3
Compound SOP
Table 3+ compounds

Sample Receipt
The following items are noted for this data set:

• All samples were received in satisfactory condition and within EPA temperature guidelines on June 1, 2019.
Data Review The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process.
Overall the data is acceptable for use without qualification, except as noted below:

• All of the Table 3+ analytical results have been qualified J as estimated, and non-detect results qualified UJ indicating an estimated reporting limit, due to analysis which exceeded the
laboratory established hold time. The result for Byproduct 5 in one sample was qualified J, and may be biased high, due to an MS RPR that exceeded criteria. See the Data Verification Module
(DVM) Narrative Report for which samples were qualified, the specific reasons for qualification,
and potential bias in reported results.
Attachments
The DVM Narrative report is attached. The lab report due to a large page count is stored on an AECOM
network shared drive and is available to be posted on external shared drives, or on a flash drive.

ADQM Data Review Narrative - FAY Additional Outfall Samples.doc 2 of 2
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD
between these spikes
• Surrogate spike recoveries for organic analyses
• RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory
or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

DVM Narrative ReportThe analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitEB3-05301905/30/2019 280-124597-5 NVHOS0.054 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.054PQLEB3-05301905/30/2019 280-124597-5 NVHOS0.054 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.054PQLEB3-05301905/30/2019 280-124597-5 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLEB3-05301905/30/2019 280-124597-5 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLEB3-05301905/30/2019 280-124597-5 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLEB3-05301905/30/2019 280-124597-5 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLEB3-05301905/30/2019 280-124597-5 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLEB3-05301905/30/2019 280-124597-5 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLEB3-05301905/30/2019 280-124597-5 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLEB3-05301905/30/2019 280-124597-5 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLEB3-05301905/30/2019 280-124597-5 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLEB3-05301905/30/2019 280-124597-5 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLEB3-05301905/30/2019 280-124597-5 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLEB3-05301905/30/2019 280-124597-5 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLPage 1 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitEB3-05301905/30/2019 280-124597-5 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLEB3-05301905/30/2019 280-124597-5 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLEB3-05301905/30/2019 280-124597-5 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLEB3-05301905/30/2019 280-124597-5 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLEB3-05301905/30/2019 280-124597-5 PFO2HxA0.081 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.081PQLEB3-05301905/30/2019 280-124597-5 PFO2HxA0.081 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.081PQLEB3-05301905/30/2019 280-124597-5 PFO3OA0.058 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLEB3-05301905/30/2019 280-124597-5 PFO3OA0.058 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLEB3-05301905/30/2019 280-124597-5 PFO4DA0.079 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.079PQLEB3-05301905/30/2019 280-124597-5 PFO4DA0.079 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.079PQLEB3-05301905/30/2019 280-124597-5 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLEB3-05301905/30/2019 280-124597-5 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLEB3-05301905/30/2019 280-124597-5 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLEB3-05301905/30/2019 280-124597-5 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLEB3-05301905/30/2019 280-124597-5 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLEB3-05301905/30/2019 280-124597-5 PFMOAA0.21 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.21PQLEB3-05301905/30/2019 280-124597-5 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLPage 2 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitEB3-05301905/30/2019 280-124597-5 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLEB3-05301905/30/2019 280-124597-5 PFESA-BP20.030 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.030PQLEB3-05301905/30/2019 280-124597-5 PFESA-BP20.030 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.030PQLEB3-05301905/30/2019 280-124597-5 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLEB3-05301905/30/2019 280-124597-5 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLEB3-05301905/30/2019 280-124597-5 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLEB3-05301905/30/2019 280-124597-5 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLEB3-05301905/30/2019 280-124597-5 Hfpo Dimer Acid (trial)0.086 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.086PQLEB3-05301905/30/2019 280-124597-5 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLEB3-05301905/30/2019 280-124597-5 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLEB3-05301905/30/2019 280-124597-5 Byproduct 40.16 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.16PQLEB3-05301905/30/2019 280-124597-5 Byproduct 40.16 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.16PQLEB3-05301905/30/2019 280-124597-5 Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLEB3-05301905/30/2019 280-124597-5 Byproduct 50.058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.058PQLEB3-05301905/30/2019 280-124597-5 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLEB3-05301905/30/2019 280-124597-5 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLPage 3 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLPage 4 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLPage 5 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20B-053019 05/30/2019 280-124597-2 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLPage 6 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20B-053019 05/30/2019 280-124597-2 Hfpo Dimer Acid (trial)0.086 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.086PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLPage 7 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20C-053019 05/30/2019 280-124597-1 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Hfpo Dimer Acid (trial)0.086 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.086PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLPage 8 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20D-053019 05/30/2019 280-124597-4 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLPage 9 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20D-053019 05/30/2019 280-124597-4 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Hfpo Dimer Acid (trial)0.086 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.086PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.070PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PES0.046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.046PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.57PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFECA B0.060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.060 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.060PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.11 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.11PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 2-(N-methyl perfluoro-1-0.11 ug/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep0.11PQLPage 10 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitoctanesulfonamido)-ethanolSOPFAY-SW-DUP-053019 05/30/2019 280-124597-7 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PEPA0.047 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.047PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 N-methyl perfluoro-1-octanesulfonamide0.035 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.035PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 N-ethylperfluoro-1-octanesulfonamide0.037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.037PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 EVE Acid0.024 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.024PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Hydro-EVE Acid0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLPage 11 of 19
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFECA-G0.041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.041PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Byproduct 60.015 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLPage 12 of 19
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Byproduct 51.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Byproduct 51.4 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLPage 13 of 19
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-DUP-053019 05/30/2019 280-124597-7 Hfpo Dimer Acid (trial)0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.086PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 R-EVE0.070 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.070PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 R-EVE0.087 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.070PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Byproduct 40.28 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Byproduct 40.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Byproduct 51.5 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 Byproduct 51.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFESA-BP20.20 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFESA-BP20.21 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFMOAA2.5 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFMOAA2.7 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 NVHOS0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 NVHOS0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFESA-BP20.21 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFESA-BP20.21 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO2HxA0.68 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO2HxA0.7 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLPage 14 of 19
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO3OA0.32 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO3OA0.33 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO4DA0.22 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO4DA0.24 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO5DA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-DUP-053019 05/30/2019 280-124597-7 PFO5DA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Byproduct 40.24 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Byproduct 40.26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Byproduct 51.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 Byproduct 51.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFMOAA2.6 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFMOAA2.7 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 NVHOS0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 NVHOS0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO2HxA0.66 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO2HxA0.66 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO3OA0.32 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLPage 15 of 19
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO3OA0.32 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO4DA0.23 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO4DA0.24 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO5DA0.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFO5DA0.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFESA-BP10.032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLFAY-SW-20D-053019 05/30/2019 280-124597-4 PFESA-BP10.036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Byproduct 40.22 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Byproduct 40.23 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Byproduct 51.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 Byproduct 51.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFESA-BP20.21 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFESA-BP20.2 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFMOAA2.8 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFMOAA2.8 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO2HxA0.68 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO2HxA0.67 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLPage 16 of 19
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO3OA0.34 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO3OA0.34 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO4DA0.25 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO4DA0.26 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO5DA0.16 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFO5DA0.16 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFESA-BP10.036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PFESA-BP10.04 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PMPA0.57 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.57PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 PMPA0.66 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.57PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 NVHOS0.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-20C-053019 05/30/2019 280-124597-1 NVHOS0.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Byproduct 40.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Byproduct 40.22 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Byproduct 51.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 Byproduct 51.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFESA-BP20.20 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLPage 17 of 19
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-SW-20B-053019 05/30/2019 280-124597-2 PFESA-BP20.19 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFMOAA2.4 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFMOAA2.4 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 NVHOS0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 NVHOS0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Byproduct 40.23 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Byproduct 40.28 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.16PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO2HxA0.64 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO2HxA0.66 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO3OA0.30 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO3OA0.29 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO4DA0.22 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO4DA0.23 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO5DA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-SW-20B-053019 05/30/2019 280-124597-2 PFO5DA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 Hfpo Dimer Acid (trial)0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.086PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFESA-BP20.19 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLPage 18 of 19
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidationValidation ReasonFayettevilleSite:SamplingAdditional Outfall SamplesAnalyticalMethodAnalyteDateSamplePQLValidationLab SamplePre-prepMDLResult TypField Sample IDPrepUnitFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFESA-BP20.2 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFMOAA2.5 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFMOAA2.6 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.21PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PMPA0.64 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.57PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PMPA0.67 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.57PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO2HxA0.64 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO2HxA0.62 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO3OA0.32 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO3OA0.3 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.058PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO4DA0.22 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO4DA0.21 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.079PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO5DA0.14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFO5DA0.13 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFESA-BP10.030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 PFESA-BP10.027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 NVHOS0.10 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLFAY-DSTW-OUTFALL002-05301905/30/2019 280-124597-3 NVHOS0.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.054PQLPage 19 of 19
ADQM Data Review Narrative - FAY 2019 Sediment Samp.doc 1 of 3
ADQM DATA REVIEW NARRATIVE

Site Chemours FAY – Fayetteville
Project 2019 Sediment Sampling
Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates April 29 - 30, 2019 July 2 - 3, 2019 August 9, 2019
Analytical Protocol

Laboratory Analytical Method Parameter(s)
TestAmerica - Sacramento 537 Modified PFAS1, total and SPLP
TestAmerica - Sacramento Cl. Spec. Table 3 Compound SOP Table 3+ compounds, total and SPLP
TestAmerica - Burlington ASTM D422-63 Grain Size
TestAmerica - Sacramento ASTM D2216-90 Percent Moisture
TestAmerica - Sacramento ASTM D2216-90 Percent Solids
1 Perfluoroalkylsubstances, a list of 33 compounds including HFPO-DA, or HFPO-DA alone.
Sample Receipt
The following items are noted for this data set:

• All samples were received in satisfactory condition and within EPA temperature guidelines on:
May 2, 2019 July 9. 2019
August 13, 2019

• The density results reported for soil samples do not represent the in-place density of the soil. The
soil was received in a disturbed state and was subsequently molded in the laboratory to an approximation of the field environment
Data Review The electronic data submitted for this project was reviewed via the Data Verification Module (DVM) process.
Overall the data is acceptable for use without qualification, except as noted below:
ADQM Data Review Narrative - FAY 2019 Sediment Samp.doc 2 of 3
• Non-detect results for R-EVE, Byproduct 4, and Byproduct 5 in some sediment samples were qualified R and should be considered to be unusable due to very poor matrix spike recoveries.
• Several analytical results have been qualified J as estimated, and non-detect results qualified UJ indicating an estimated reporting limit, due to poor recovery of a blank spike or matrix spike;
sample preparation which exceeded the laboratory established hold time; and poor field duplicate or lab replicate precision. See the Data Verification Module (DVM) Narrative Report for which samples were qualified, the specific reasons for qualification, and potential bias in reported
results.

Attachments
The DVM Narrative report is attached. The lab reports due to a large page count are stored on an AECOM network shared drive and are available to be posted on external shared drives, or on a flash
drive.
ADQM Data Review Narrative - FAY 2019 Sediment Samp.doc 3 of 3
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD
between these spikes
• Surrogate spike recoveries for organic analyses
• RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory
or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

DVM Narrative ReportAssociated MS and/or MSD analysis had relative percent recovery (RPR) values less than the data rejection level. The reported non-detect result isunusable.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3R-EVE1.2 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 51.2 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.2PQLPage 1 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the data rejection level. The reported non-detect result isunusable.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 41.2 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.2PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 41.0 UG/KGCl. Spec. Table 3CompoundRShake_Bath_14D1.0PQLPage 2 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the data rejection level. The reported non-detect result isunusable.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPRShake_Bath_14D1.0PQLPage 3 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-B-070219 07/02/2019 320-52074-2Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO3OA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO3OA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO4DA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO4DA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO5DA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO5DA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFMOAA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFMOAA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA-G1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA-G1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 4 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-A-070219 07/02/2019 320-52074-1R-EVE1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1R-EVE1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO2HxA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO2HxA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-SETP-01 04/29/2019 320-49863-2R-EVE1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1PFECA-G1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1PFECA-G1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-SETP-01 04/29/2019 320-49863-2N-ethylperfluoro-1-octanesulfonamide1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1PFECA B1.0 UG/KGCl. Spec. Table 3CompoundUJShake_Bath_14D1.0PQLPage 5 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPSD-DNSS-A-070219 07/02/2019 320-52076-3PFO5DA0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFECA-G1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFECA-G1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 6 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA-G1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA-G2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5NEtPFOSA (trial)1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6NEtPFOSA (trial)1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP21.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP21.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA-G1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA-G1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 7 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-D-070219 07/02/2019 320-52074-5PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO4DA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO4DA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO3OA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO3OA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFMOAA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFMOAA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 8 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6PEPA1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PEPA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PMPA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP11.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP12.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-E-070219 07/02/2019 320-52074-6N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO2HxA1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO2HxA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO4DA1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO4DA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLPage 9 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6PFO3OA1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO3OA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFMOAA1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFMOAA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-E-070219 07/02/2019 320-52074-6EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP21.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP22.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 10 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO5DA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO5DA2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFMOAA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFMOAA2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP21.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP22.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA-G1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA-G2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3NEtPFOSA (trial)1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4NEtPFOSA (trial)1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 11 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP11.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP12.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO2HxA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO2HxA2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO3OA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO3OA2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO4DA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO4DA2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 61.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 12 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-3Hydro-EVE Acid1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PEPA1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PEPA2.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.4PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP12.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP13.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3N-methyl perfluoro-1-octanesulfonamide1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO2HxA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO2HxA3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLPage 13 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA B1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PEPA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PEPA3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO3OA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO3OA3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO4DA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO4DA3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO5DA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO5DA3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFMOAA2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLPage 14 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-3PFMOAA3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3EVE Acid1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP22.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP23.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA-G2.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA-G3.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D3.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2NEtPFOSA (trial)1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3NVHOS1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PES1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.2PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP21.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP21.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 15 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-A-070219 07/02/2019 320-52074-1NVHOS1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1NVHOS1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA B1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA B1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1N-methyl perfluoro-1-octanesulfonamide1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1N-methyl perfluoro-1-octanesulfonamide1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PES1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PES1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1EVE Acid1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1EVE Acid1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLPage 16 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP24.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP24.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA-G4.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA-G4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1NEtPFOSA (trial)1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Hydro-EVE Acid1.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Hydro-EVE Acid1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 61.6 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 61.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 17 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-B-070219 07/02/2019 320-52074-2PEPA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PEPA1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP11.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP11.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSS-SGSS-B-070219 07/02/2019 320-52074-2N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA B1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PEPA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLPage 18 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-A-070219 07/02/2019 320-52076-3PEPA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3NVHOS1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PES1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PMPA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PMPA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-methyl perfluoro-1-octanesulfonamide1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO2HxA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO2HxA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO3OA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO3OA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO5DA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO5DA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-ethylperfluoro-1-octanesulfonamide1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-ethylperfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 19 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-A-070219 07/02/2019 320-52076-3PFMOAA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFMOAA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3EVE Acid1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Hydro-EVE Acid1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA-G2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA-G2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 61 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-C-070319 07/03/2019 320-52076-4NVHOS110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4NVHOS110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PES110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PES110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PMPA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PMPA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA B110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLPage 20 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA B110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PEPA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PEPA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-methyl perfluoro-1-octanesulfonamide110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-methyl perfluoro-1-octanesulfonamide110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO2HxA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO2HxA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO3OA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO3OA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO4DA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO4DA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLPage 21 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-C-070319 07/03/2019 320-52076-4PFO5DA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO5DA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-ethylperfluoro-1-octanesulfonamide110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-ethylperfluoro-1-octanesulfonamide110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFMOAA280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFMOAA270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4EVE Acid110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4EVE Acid110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO4DA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO4DA2.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Hfpo Dimer Acid (trial)1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3R-EVE1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 41 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP2280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP2270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLPage 22 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-C-070319 07/03/2019 320-52076-4Hydro-EVE Acid110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Hydro-EVE Acid110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA-G280 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA-G270 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4R-EVE110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4R-EVE110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-F-070319 07/03/2019 320-52076-7NVHOS9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7NVHOS9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PES9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PES9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PMPA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PMPA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA B9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA B9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLPage 23 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PEPA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PEPA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 4110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 4110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 5110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 5110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-methyl perfluoro-1-octanesulfonamide9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-methyl perfluoro-1-octanesulfonamide9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO2HxA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO2HxA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO3OA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO3OA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO4DA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO4DA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLPage 24 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7PFO5DA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO5DA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-ethylperfluoro-1-octanesulfonamide9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-ethylperfluoro-1-octanesulfonamide9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFMOAA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFMOAA23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7EVE Acid9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7EVE Acid9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Hydro-EVE Acid9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Hydro-EVE Acid9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA-G23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA-G23 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D23PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 6110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 6110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Hfpo Dimer Acid (trial)110 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D110PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Hfpo Dimer Acid (trial)9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7R-EVE9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLPage 25 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7R-EVE9.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 49.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 49.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 59.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 59.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 69.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 69.3 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D9.3PQLSD-DNSS-G-070319 07/03/2019 320-52076-5NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PEPA2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLPage 26 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5PEPA2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP12.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PMPA2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PMPA2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-ethylperfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-ethylperfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO5DA2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO5DA2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA-G2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLPage 27 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA-G2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 61.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6NVHOS1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PES1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PMPA1.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PMPA2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA B1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 28 of 81
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6PEPA1.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PEPA2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP11.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP12.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-methyl perfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-ethylperfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-ethylperfluoro-1-octanesulfonamide1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA-G1.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA-G2.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Hydro-EVE Acid1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 29 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5NEtPFOSA (trial)0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6NEtPFOSA (trial)0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 30 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 31 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3NEtPFOSA (trial)0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4NEtPFOSA (trial)0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 32 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 33 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2NEtPFOSA (trial)0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 34 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA B0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA B0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.011 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.011PQLSS-SGSS-A-070219 07/02/2019 320-52074-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.011 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.011PQLSS-SGSS-A-070219 07/02/2019 320-52074-1N-methyl perfluoro-1-octanesulfonamide0.0035 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0035PQLSS-SGSS-A-070219 07/02/2019 320-52074-1N-methyl perfluoro-1-octanesulfonamide0.0035 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0035PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PES0.0046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0046PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PES0.0046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0046PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA-G0.0041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0041PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFECA-G0.0041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0041PQLSS-SGSS-A-070219 07/02/2019 320-52074-1NEtPFOSA (trial)0.0037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0037PQLPage 35 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-B-070219 07/02/2019 320-52074-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Hfpo Dimer Acid (trial)1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2R-EVE1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Byproduct 41.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Byproduct 41.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Byproduct 51.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLPage 36 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-SETP-01 04/29/2019 320-49863-2Byproduct 51.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Byproduct 61.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Byproduct 61.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 37 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-A-070219 07/02/2019 320-52076-3N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLFAY-SED-River-01 04/30/2019 320-49863-3NVHOS1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3NVHOS1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PES1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PES1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PMPA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PMPA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFECA B1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PFECA B1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PEPA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLPage 38 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-River-01 04/30/2019 320-49863-3PEPA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFESA-BP12.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFESA-BP14.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3N-methyl perfluoro-1-octanesulfonamide1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3N-methyl perfluoro-1-octanesulfonamide1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO2HxA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO2HxA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO3OA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO3OA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO4DA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO4DA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO5DA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFO5DA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3N-ethylperfluoro-1-octanesulfonamide1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3N-ethylperfluoro-1-octanesulfonamide1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PFMOAA2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFMOAA4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLPage 39 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-River-01 04/30/2019 320-49863-3EVE Acid1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3EVE Acid1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PFESA-BP22.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFESA-BP24.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3Hydro-EVE Acid1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Hydro-EVE Acid1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3PFECA-G2.9 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3PFECA-G4.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.2PQLFAY-SED-River-01 04/30/2019 320-49863-3R-EVE1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3R-EVE1.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Byproduct 41.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Byproduct 41.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Byproduct 51.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Byproduct 51.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Byproduct 61.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-River-01 04/30/2019 320-49863-3Byproduct 61.7 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.7PQLFAY-SED-SETP-01 04/29/2019 320-49863-2NVHOS1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLPage 40 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-SETP-01 04/29/2019 320-49863-2NVHOS1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PES1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PES1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PMPA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PMPA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFECA B1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFECA B1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PEPA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PEPA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFESA-BP13.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFESA-BP14.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLPage 41 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-SETP-01 04/29/2019 320-49863-2N-methyl perfluoro-1-octanesulfonamide1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2N-methyl perfluoro-1-octanesulfonamide1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO2HxA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO2HxA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO3OA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO3OA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO4DA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO4DA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO5DA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFO5DA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2N-ethylperfluoro-1-octanesulfonamide1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFMOAA3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFMOAA4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2EVE Acid1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2EVE Acid1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFESA-BP23.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFESA-BP24.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLPage 42 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-SETP-01 04/29/2019 320-49863-2Hydro-EVE Acid1.2 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Hydro-EVE Acid1.8 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.8PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFECA-G3.1 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLFAY-SED-SETP-01 04/29/2019 320-49863-2PFECA-G4.4 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D4.4PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO5DA0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4NVHOS0.0054 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0054PQLSD-DNSS-C-070319 07/03/2019 320-52076-4NVHOS0.0054 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0054PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PES0.0046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0046PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PES0.0046 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0046PQLPage 43 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-C-070319 07/03/2019 320-52076-4PMPA0.057 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.057PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PMPA0.057 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.057PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA B0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA B0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0060 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0060PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.011 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.011PQLSD-DNSS-C-070319 07/03/2019 320-52076-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.011 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.011PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-methyl perfluoro-1-octanesulfonamide0.0035 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0035PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-methyl perfluoro-1-octanesulfonamide0.0035 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0035PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO2HxA0.0081 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0081PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO2HxA0.0081 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0081PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO3OA0.0058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0058PQLPage 44 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-C-070319 07/03/2019 320-52076-4PFO3OA0.0058 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0058PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO4DA0.0079 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0079PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO4DA0.0079 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0079PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO5DA0.0034 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0034PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFO5DA0.0034 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0034PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-ethylperfluoro-1-octanesulfonamide0.0037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0037PQLSD-DNSS-C-070319 07/03/2019 320-52076-4N-ethylperfluoro-1-octanesulfonamide0.0037 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0037PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFMOAA0.021 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.021PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFMOAA0.021 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.021PQLSD-DNSS-A-070219 07/02/2019 320-52076-3R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA-G0.0041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0041PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFECA-G0.0041 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0041PQLSD-DNSS-F-070319 07/03/2019 320-52076-7NVHOS0.0027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0027PQLSD-DNSS-F-070319 07/03/2019 320-52076-7NVHOS0.0027 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0027PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PES0.0023 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0023PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PES0.0023 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0023PQLPage 45 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7PMPA0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PMPA0.028 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.028PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA B0.0030 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0030PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA B0.0030 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0030PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0030 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0030PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0030 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0030PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0055 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0055PQLSD-DNSS-F-070319 07/03/2019 320-52076-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0055 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0055PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO3OA0.0029 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0029PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO4DA0.0039 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0039PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO4DA0.0039 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0039PQLPage 46 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7PFO5DA0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO5DA0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFMOAA0.011 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.011PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFMOAA0.011 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.011PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 47 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 48 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-methyl perfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6N-ethylperfluoro-1-octanesulfonamide0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 49 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 50 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the data rejection level. The reporting limit may be bi-ased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1R-EVE1.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1Byproduct 41.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1Byproduct 51.0 UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 51 of 81
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may bebiased high.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 50.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0029PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 50.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0029PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 50.39 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0058PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 50.4 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0058PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 50.084 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 50.08 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 55.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0058PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 55.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0058PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO5DA160 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO5DA150 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 50.072 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 50.069 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 50.082 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 50.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 50.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO5DA6.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.8PQLPage 52 of 81
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may bebiased high.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6PFO5DA6.8 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.2PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO5DA4.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO5DA4.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 50.0099 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 50.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 50.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 50.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 53 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5PFMOAA17 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO4DA4.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 40.0052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 40.0049 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 52.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Byproduct 52.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1PFMOAA20 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1A08/09/2019 320-53222-1PFMOAA19.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PEPA13 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PEPA13.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFO2HxA9.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFO2HxA9.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFMOAA21 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2PFMOAA20.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLBASIN-SEDIMENT-PILE-1B08/09/2019 320-53222-2Hfpo Dimer Acid9.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFB-SS-07031907/03/2019 320-52074-8Hfpo Dimer Acid0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 54 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-D-070219 07/02/2019 320-52074-5R-EVE0.042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5R-EVE0.044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 40.072 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Byproduct 40.075 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6R-EVE0.0073 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6R-EVE0.0078 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 55 of 81
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6Hfpo Dimer Acid (trial)2.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Hfpo Dimer Acid (trial)0.056 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP23.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP23.7 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFMOAA8.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFMOAA7.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFMOAA0.28 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFMOAA0.28 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO2HxA2.7 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO2HxA2.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO2HxA0.10 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO2HxA0.1 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO3OA2.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO3OA2.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO3OA0.077 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO3OA0.075 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO4DA3.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLPage 56 of 81
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO4DA3.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO4DA0.082 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO4DA0.081 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO5DA2.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO5DA2.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 40.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5R-EVE0.0055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5R-EVE0.0063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Hfpo Dimer Acid (trial)2.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Hfpo Dimer Acid (trial)0.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Hydro-EVE Acid0.0050 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Hydro-EVE Acid0.0051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO5DA0.027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP20.067 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP20.068 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFMOAA16.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLPage 57 of 81
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5PFMOAA0.37 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFMOAA0.38 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PMPA0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PMPA0.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO2HxA5.4 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO2HxA5.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO2HxA0.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO2HxA0.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO3OA4.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO3OA4.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO3OA0.098 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO3OA0.1 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO4DA4.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO4DA0.10 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO4DA0.1 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP10.0045 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP10.0046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 58 of 81
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5NVHOS0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319 07/03/2019 320-52076-5NVHOS0.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PMPA0.15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PMPA0.15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 50.087 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Percent Moisture14.1 %D2216-90J0.1PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Gravel0.0 %ASTM D422-63J0MDLSS-SGSS-C-070219 07/02/2019 320-52074-3Hfpo Dimer Acid (trial)0.090 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP20.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP20.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFMOAA0.034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFMOAA0.034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO5DA0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO4DA0.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO4DA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO3OA0.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO3OA0.0099 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 59 of 81
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219 07/02/2019 320-52074-3PEPA0.044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PEPA0.043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO2HxA0.057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO2HxA0.056 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP10.0095 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFESA-BP10.0094 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3R-EVE0.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3R-EVE0.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO3OA0.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO3OA0.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PMPA3.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PMPA4.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.4PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP10.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP10.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 40.036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Byproduct 40.034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Percent Moisture1.6 %D2216-90J0.1PQLPage 60 of 81
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219-D 07/02/2019 320-52074-4Gravel0.4 %ASTM D422-63J0MDLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Hfpo Dimer Acid (trial)2.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 40.057 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Byproduct 40.058 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 61 of 81
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP1380 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP1570.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D23PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP13200 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D270PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP15300.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D270PQLPage 62 of 81
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6Percent Moisture14.8 %D2216-90J0.1PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Percent Solids85.2 %D2216-90J0.1PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Percent Moisture19.2 %D2216-90J0.1PQLSD-DNSS-G-070319 07/03/2019 320-52076-5Percent Solids80.8 %D2216-90J0.1PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Percent Moisture18.7 %D2216-90J0.1PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Percent Solids81.3 %D2216-90J0.1PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Percent Moisture26.2 %D2216-90J0.1PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Percent Solids73.8 %D2216-90J0.1PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Percent Moisture31.4 %D2216-90J0.1PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Percent Solids68.6 %D2216-90J0.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Percent Moisture1 %D2216-90J0.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Percent Solids99.0 %D2216-90J0.1PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Percent Moisture1.9 %D2216-90J0.1PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Percent Solids98.1 %D2216-90J0.1PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Percent Solids85.9 %D2216-90J0.1PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Percent Solids98.4 %D2216-90J0.1PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Percent Moisture13.9 %D2216-90J0.1PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Percent Solids86.1 %D2216-90J0.1PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Percent Moisture1.6 %D2216-90J0.1PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Percent Solids98.4 %D2216-90J0.1PQLPage 63 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6R-EVE0.0048 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6R-EVE0.0047 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Hydro-EVE Acid0.0050 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Hydro-EVE Acid0.005 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP20.066 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP20.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO5DA0.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFO5DA0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP10.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PFESA-BP10.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PMPA0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6PMPA0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6NVHOS0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6NVHOS0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 40.019 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0079PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Byproduct 40.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0079PQLSD-DNSS-F-070319 07/03/2019 320-52076-7R-EVE0.0052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLPage 64 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-F-070319 07/03/2019 320-52076-7R-EVE0.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLSD-DNSS-F-070319 07/03/2019 320-52076-7Hfpo Dimer Acid (trial)0.037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0043PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Hfpo Dimer Acid (trial)0.074 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0086PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 60.0032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 60.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7EVE Acid0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7EVE Acid0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP20.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP20.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO2HxA0.0047 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0041PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFO2HxA0.0046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0041PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 40.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Byproduct 40.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP12.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP12.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4R-EVE0.0078 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0070PQLSD-DNSS-C-070319 07/03/2019 320-52076-4R-EVE0.0078 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0070PQLPage 65 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-C-070319 07/03/2019 320-52076-4Hydro-EVE Acid0.0072 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0028PQLSD-DNSS-C-070319 07/03/2019 320-52076-4Hydro-EVE Acid0.008 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0028PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP20.94 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0030PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP20.97 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0030PQLSD-DNSS-A-070219 07/02/2019 320-52076-3Hfpo Dimer Acid (trial)0.0083 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO4DA0.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO4DA0.0023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-C-070319 07/03/2019 320-52076-4EVE Acid0.29 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0024PQLSD-DNSS-C-070319 07/03/2019 320-52076-4EVE Acid0.29 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0024PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP15.8 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0027PQLSD-DNSS-C-070319 07/03/2019 320-52076-4PFESA-BP15.9 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0027PQLSD-DNSS-A-070219 07/02/2019 320-52076-3EVE Acid0.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3EVE Acid0.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP20.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP20.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFMOAA0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFMOAA0.01 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLPage 66 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-A-070219 07/02/2019 320-52076-3PFO3OA0.0026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO3OA0.0023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SED-River-01 04/30/2019 320-49863-3Hfpo Dimer Acid (trial)3.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.7PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO2HxA0.0043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFO2HxA0.0042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PMPA0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PMPA0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP10.062 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP10.061 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO2HxA0.18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO2HxA0.18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP10.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP10.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2NVHOS0.0044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2NVHOS0.0043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PEPA0.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PEPA0.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLPage 67 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-B-070219 07/02/2019 320-52074-2PMPA0.20 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PMPA0.20 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 60.0026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 60.0026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Hydro-EVE Acid0.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0028PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Hydro-EVE Acid0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0028PQLSS-SGSS-A-070219 07/02/2019 320-52074-1R-EVE0.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0070PQLSS-SGSS-A-070219 07/02/2019 320-52074-1R-EVE0.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0070PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 40.25 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 40.25 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Hfpo Dimer Acid (trial)1.5 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0086PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP20.074 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0030PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP20.073 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0030PQLSS-SGSS-A-070219 07/02/2019 320-52074-1EVE Acid0.0058 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0024PQLSS-SGSS-A-070219 07/02/2019 320-52074-1EVE Acid0.0061 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0024PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PMPA4.4 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.057PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PMPA4.4 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.057PQLPage 68 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-A-070219 07/02/2019 320-52074-1PFO2HxA1.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0081PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO2HxA1.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0081PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO3OA1.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0058PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO3OA1.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0058PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO4DA2.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0079PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO4DA2.2 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0079PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO5DA5.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0034PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO5DA5.2 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0034PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFMOAA0.34 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.021PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFMOAA0.35 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.021PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PEPA2.8 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PEPA2.8 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP10.26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0027PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP10.26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0027PQLSS-SGSS-A-070219 07/02/2019 320-52074-1NVHOS0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0054PQLSS-SGSS-A-070219 07/02/2019 320-52074-1NVHOS0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0054PQLSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 69 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319-D 07/03/2019 320-52076-6Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Hfpo Dimer Acid (trial)0.22 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP20.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFESA-BP20.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFMOAA0.19 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFMOAA0.19 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO5DA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO5DA0.020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO4DA0.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO4DA0.016 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO3OA0.032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PFO3OA0.030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Hydro-EVE Acid0.0038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Hydro-EVE Acid0.0038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 40.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Byproduct 40.016 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-B-070219 07/02/2019 320-52074-2R-EVE0.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 70 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-B-070219 07/02/2019 320-52074-2R-EVE0.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PEPA0.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PEPA0.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Hydro-EVE Acid0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4NVHOS0.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4NVHOS0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO4DA0.030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO4DA0.031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO2HxA0.086 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO2HxA0.085 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PMPA0.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PMPA0.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Hydro-EVE Acid0.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Hydro-EVE Acid0.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4Hfpo Dimer Acid (trial)0.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP20.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 71 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFESA-BP20.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4EVE Acid0.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4EVE Acid0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFMOAA0.049 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFMOAA0.049 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PEPA0.25 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PEPA0.25 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP10.053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP10.055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5NVHOS0.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5NVHOS0.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4R-EVE0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4R-EVE0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP20.055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP20.058 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFMOAA0.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFMOAA0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLPage 72 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6PFO3OA0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO3OA0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO4DA0.055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO4DA0.059 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO2HxA0.077 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO2HxA0.079 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP10.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFESA-BP10.019 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PMPA0.092 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PMPA0.094 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-E-070219 07/02/2019 320-52074-6NVHOS0.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6NVHOS0.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PEPA0.037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PEPA0.038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFMOAA0.066 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFMOAA0.066 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO3OA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 73 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-D-070219 07/02/2019 320-52074-5PFO3OA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO4DA0.030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO4DA0.031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO2HxA0.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO2HxA0.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PMPA0.69 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PMPA0.70 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Hfpo Dimer Acid (trial)0.24 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP20.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP20.024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5EVE Acid0.0026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5EVE Acid0.0027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Hydro-EVE Acid0.0049 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Hydro-EVE Acid0.0048 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Hydro-EVE Acid0.0088 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Hydro-EVE Acid0.0093 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Hfpo Dimer Acid (trial)0.094 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 74 of 81
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 40.016 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Byproduct 40.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 75 of 81
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsFAY-SED-SETP-01 04/29/2019 320-49863-2Percent Moisture44.1 %D2216-90J0.1PQLFAY-SED-SETP-01 04/29/2019 320-49863-2Percent Solids55.9 %D2216-90J0.1PQLFAY-SED-River-01 04/30/2019 320-49863-3Percent Moisture47.9 %D2216-90J0.1PQLFAY-SED-River-01 04/30/2019 320-49863-3Percent Solids52.1 %D2216-90J0.1PQLPage 76 of 81
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsEQB-0104/30/2019 320-49863-1MTP0.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLEQB-0104/30/2019 320-49863-1MTP0.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.12PQLPage 77 of 81
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5Byproduct 51.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFO5DA0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 42.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 42.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.7PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PFO5DA0.027 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO5DA0.037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-C-070219-D 07/02/2019 320-52074-4PFO5DA0.035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO5DA0.24 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-E-070219 07/02/2019 320-52074-6PFO5DA0.26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO5DA0.080 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO5DA0.080 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 78 of 81
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP23.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-G-070319 07/03/2019 320-52076-5PFESA-BP23.3 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.0PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP225 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D23PQLSD-DNSS-F-070319 07/03/2019 320-52076-7PFESA-BP225.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D23PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP24.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP23.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP18.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.3PQLSD-DNSS-A-070219 07/02/2019 320-52076-3PFESA-BP17.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.3PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PMPA2.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.7PQLSS-SGSS-B-070219 07/02/2019 320-52074-2PMPA2.4 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 545 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Byproduct 543 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1Hfpo Dimer Acid (trial)38 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.7PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PMPA110 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PMPA110 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO2HxA29 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO2HxA27 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLPage 79 of 81
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-A-070219 07/02/2019 320-52074-1PFO3OA23 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO3OA21 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO4DA54 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFO4DA52 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFMOAA8.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFMOAA7.4 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PEPA74 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PEPA71 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP15.7 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.1PQLSS-SGSS-A-070219 07/02/2019 320-52074-1PFESA-BP15.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D4.4PQLSS-SGSS-B-070219 07/02/2019 320-52074-2Hfpo Dimer Acid (trial)2.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PMPA4.2 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D2.2PQLSS-SGSS-C-070219 07/02/2019 320-52074-3PMPA4.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D3.0PQLSS-SGSS-C-070219 07/02/2019 320-52074-3Hfpo Dimer Acid (trial)2.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.2PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PEPA5.0 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PEPA4.9 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP11.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLPage 80 of 81
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Sediment SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSS-SGSS-D-070219 07/02/2019 320-52074-5PFESA-BP11.6 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO2HxA3.4 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PFO2HxA3.4 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PMPA14 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5PMPA14 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.6PQLSS-SGSS-D-070219 07/02/2019 320-52074-5Hfpo Dimer Acid (trial)5.5 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLSS-SGSS-E-070219 07/02/2019 320-52074-6Hfpo Dimer Acid (trial)2.1 UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLPage 81 of 81
ADQM Data Review Narrative - FAY 2019 Stormwater Samp update2.doc 1 of 3
ADQM DATA REVIEW NARRATIVE

Site Chemours FAY – Fayetteville
Project 2019 Stormwater Sampling (updated for completeness)
Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates June 27 - 28, 2019 August 21 – 22, 2019 September 6, 2019
Analytical Protocol

Laboratory Analytical Method Parameter(s)
TestAmerica - Sacramento 537 Modified PFAS1
TestAmerica - Sacramento Cl. Spec. Table 3
Compound SOP
Table 3+ compounds
TestAmerica - Denver 200.7/200.8 Select metals
TestAmerica - Denver 300.0 Select anions
TestAmerica - Denver 351.2 Total Kjeldahl Nitrogen
TestAmerica - Denver 353.2 Nitrate/Nitrite Nitrogen
TestAmerica - Denver 365.1 Phosphorus
TestAmerica - Denver 410.4 Chemical Oxygen Demand (COD)
TestAmerica - Denver 2540 D-1997 Total Suspended Solids
TestAmerica - Denver 5210 B-2001 Biochemical Oxygen Demand (BOD) - 5 Day
TestAmerica - Denver Calculation Nitrogen, total

1 Perfluoroalkylsubstances, a list of 33 or 37 compounds including HFPO-DA. Sample Receipt

The following items are noted for this data set:

• All samples were received in satisfactory condition and within EPA temperature guidelines on:
o July 2, 11, and 16, 2019
o August 23, 2019
o September 7, 2019
• Some samples were reactivated outside the laboratory established hold time to allow reanalysis
by the low level Table 3+ method.
ADQM Data Review Narrative - FAY 2019 Stormwater Samp update2.doc 2 of 3
Data Review
The electronic data submitted for this project was reviewed via the Data Verification Module (DVM) process.

Overall the data is acceptable for use without qualification, except as noted below:
• A result for phosphorous in field sample ID STW-LOC003-09061909 was qualified B and the reported result may be biased high, or a false positive, due to a comparable concentration found in
the associated method blank.
• Several analytical results have been qualified J as estimated, and non-detect results qualified UJ
indicating an estimated reporting limit, due to poor or very poor recovery of a surrogate or
laboratory blank spike; sample analysis which exceeded the laboratory hold time; and poor field duplicate or lab replicate precision. See the Data Verification Module (DVM) Narrative Report
for which samples were qualified, the specific reasons for qualification, and potential bias in
reported results.
Attachments
The DVM Narrative report is attached. The lab reports due to a large page count are stored on an
AECOM network shared drive and are available to be posted on external shared drives, or on a flash drive.
ADQM Data Review Narrative - FAY 2019 Stormwater Samp update2.doc 3 of 3
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD
between these spikes
• Surrogate spike recoveries for organic analyses
• RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory
or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

DVM Narrative ReportContamination detected in Method Blank(s). Sample result does not differ significantly from the analyte concentration detected in the associated methodblank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC003-090619 09/06/2019 280-128067-1 Phosphorus0.17 MG/L0.025365.1B0.050MDLPage 1 of 57
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC18-082119-1 08/21/2019 320-53640-5Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5N-methyl perfluoro-1-octanesulfonamide0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7N-methyl perfluoro-1-octanesulfonamide0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5ADONA0.0021 UG/L537 ModifiedUJ3535_PFC0.0021PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5NaDONA0.0021 ug/L537 ModifiedUJ3535_PFC0.0021PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-56:2 Fluorotelomersulfonate0.020 ug/L537 ModifiedUJ3535_PFC0.020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PerfluorotetradecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-062719 06/27/2019 320-51907-8ADONA0.0021 UG/L537 ModifiedUJ3535_PFC0.0021PQLSTW-LOC-22-062719 06/27/2019 320-51907-8NaDONA0.0021 ug/L537 ModifiedUJ3535_PFC0.0021PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PerfluorotetradecanoicAcid0.0020 UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC19A-082119 08/21/2019 320-53582-4Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC19A-082119 08/21/2019 320-53582-4Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC19B-082119 08/21/2019 320-53582-5Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC19B-082119 08/21/2019 320-53582-5Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 2 of 57
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC18-082119-4 08/21/2019 320-53640-8N-methyl perfluoro-1-octanesulfonamide0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 3 of 57
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17A-062719 06/27/2019 320-52169-1NVHOS54 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep54PQLSTW-LOC17A-062719 06/27/2019 320-52169-1NVHOS54 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep54PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PES46 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep46PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PES46 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep46PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PMPA570 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep570PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PMPA570 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep570PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFECA B60 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFECA B60 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLSTW-LOC17A-062719 06/27/2019 320-52169-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol60 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLSTW-LOC17A-062719 06/27/2019 320-52169-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol60 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep60PQLSTW-LOC17A-062719 06/27/2019 320-52169-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep110PQLSTW-LOC17A-062719 06/27/2019 320-52169-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol110 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep110PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PEPA47 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep47PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PEPA47 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep47PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFESA-BP127 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep27PQLPage 4 of 57
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17A-062719 06/27/2019 320-52169-1PFESA-BP127 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep27PQLSTW-LOC17A-062719 06/27/2019 320-52169-1N-methyl perfluoro-1-octanesulfonamide35 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLSTW-LOC17A-062719 06/27/2019 320-52169-1N-methyl perfluoro-1-octanesulfonamide35 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep35PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFMOAA210 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep210PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFMOAA210 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep210PQLSTW-LOC17A-062719 06/27/2019 320-52169-1EVE Acid24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLSTW-LOC17A-062719 06/27/2019 320-52169-1EVE Acid24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFESA-BP230 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep30PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFESA-BP230 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep30PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Hydro-EVE Acid28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Hydro-EVE Acid28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFECA-G41 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep41PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFECA-G41 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep41PQLSTW-LOC17A-062719 06/27/2019 320-52169-1R-EVE70 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep70PQLSTW-LOC17A-062719 06/27/2019 320-52169-1R-EVE70 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep70PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Byproduct 4160 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep160PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Byproduct 4160 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep160PQLPage 5 of 57
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17A-062719 06/27/2019 320-52169-1Byproduct 558 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Byproduct 558 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Byproduct 615 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Byproduct 615 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLSTW-LOC17B-062719 06/27/2019 320-52276-1NVHOS21 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep21PQLSTW-LOC17B-062719 06/27/2019 320-52276-1NVHOS21 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep21PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PES18 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep18PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PES18 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep18PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PMPA230 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep230PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PMPA230 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep230PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFECA B24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFECA B24 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLSTW-LOC17B-062719 06/27/2019 320-52276-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol24 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLSTW-LOC17B-062719 06/27/2019 320-52276-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol24 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep24PQLSTW-LOC17B-062719 06/27/2019 320-52276-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol44 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep44PQLSTW-LOC17B-062719 06/27/2019 320-52276-12-(N-methyl perfluoro-1-44 ug/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep44PQLPage 6 of 57
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsoctanesulfonamido)-ethanolSOPSTW-LOC17A-062719 06/27/2019 320-52169-1PFO2HxA81 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep81PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO2HxA81 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep81PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO3OA58 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO3OA58 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep58PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO4DA79 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep79PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO4DA79 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep79PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO5DA34 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFO5DA34 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep34PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFESA-BP111 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep11PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFESA-BP111 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep11PQLSTW-LOC17B-062719 06/27/2019 320-52276-1N-methyl perfluoro-1-octanesulfonamide14 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep14PQLSTW-LOC17B-062719 06/27/2019 320-52276-1N-methyl perfluoro-1-octanesulfonamide14 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep14PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO2HxA32 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep32PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO2HxA32 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep32PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO3OA23 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep23PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO3OA23 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep23PQLPage 7 of 57
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17B-062719 06/27/2019 320-52276-1PFO4DA31 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep31PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO4DA31 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep31PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO5DA13 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep13PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFO5DA13 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep13PQLSTW-LOC17B-062719 06/27/2019 320-52276-1N-ethylperfluoro-1-octanesulfonamide15 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLSTW-LOC17B-062719 06/27/2019 320-52276-1N-ethylperfluoro-1-octanesulfonamide15 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep15PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFMOAA85 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep85PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFMOAA85 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep85PQLSTW-LOC17B-062719 06/27/2019 320-52276-1EVE Acid9.7 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep9.7PQLSTW-LOC17B-062719 06/27/2019 320-52276-1EVE Acid9.7 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep9.7PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFESA-BP212 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep12PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFESA-BP212 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep12PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Hydro-EVE Acid11 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep11PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Hydro-EVE Acid11 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep11PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFECA-G16 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep16PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFECA-G16 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep16PQLSTW-LOC17B-062719 06/27/2019 320-52276-1R-EVE28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLPage 8 of 57
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17B-062719 06/27/2019 320-52276-1R-EVE28 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep28PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Byproduct 463 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep63PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Byproduct 463 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep63PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Byproduct 523 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep23PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Byproduct 523 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep23PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Byproduct 66.2 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep6.2PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Byproduct 66.2 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep6.2PQLPage 9 of 57
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-23A-062719 06/27/2019 320-51907-9PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-23A-062719 06/27/2019 320-51907-9PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLPage 10 of 57
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO5DA0.034 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.034PQLPage 11 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6A-062719 06/27/2019 320-51907-1PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 12 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-18-062719 06/27/2019 320-51907-4PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC19A-082119 08/21/2019 320-53582-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC19A-082119 08/21/2019 320-53582-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC19A-082119 08/21/2019 320-53582-4Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC19A-082119 08/21/2019 320-53582-4Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC19B-082119 08/21/2019 320-53582-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC19B-082119 08/21/2019 320-53582-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 13 of 57
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17A-062719 06/27/2019 320-52169-110:2 Fluorotelomersulfonate2400 ug/L537 ModifiedUJ3535_PFC2400PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluorooctadecanoicacid5800 ug/L537 ModifiedUJ3535_PFC5800PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFOS6800 UG/L537 ModifiedUJ3535_PFC6800PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluoroundecanoicAcid14000 UG/L537 ModifiedUJ3535_PFC14000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1N-methylperfluorooctanesulfonamidoacetic acid39000 UG/L537 ModifiedUJ3535_PFC39000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluoropentanoicAcid6100 UG/L537 ModifiedUJ3535_PFC6100PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluoropentanesulfonic acid (PFPeS)3800 ug/L537 ModifiedUJ3535_PFC3800PQLSTW-LOC17A-062719 06/27/2019 320-52169-16:2 Fluorotelomersulfonate25000 ug/L537 ModifiedUJ3535_PFC25000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1N-ethylperfluorooctanesulfonamidoacetic acid24000 UG/L537 ModifiedUJ3535_PFC24000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorohexanoicAcid7300 UG/L537 ModifiedUJ3535_PFC7300PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorododecanoicAcid6900 UG/L537 ModifiedUJ3535_PFC6900PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PFOA11000 UG/L537 ModifiedUJ3535_PFC11000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorodecanoicAcid3900 UG/L537 ModifiedUJ3535_PFC3900PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorodecaneSulfonic Acid4000 UG/L537 ModifiedUJ3535_PFC4000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluorohexadecanoicacid (PFHxDA)11000 ug/L537 ModifiedUJ3535_PFC11000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluorononanesulfonic acid2000 ug/L537 ModifiedUJ3535_PFC2000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorotridecanoicAcid16000 UG/L537 ModifiedUJ3535_PFC16000PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorooctaneSulfonamide4400 UG/L537 ModifiedUJ3535_PFC4400PQLSTW-LOC17A-062719 06/27/2019 320-52169-19Cl-PF3ONS3000 ug/L537 ModifiedUJ3535_PFC3000PQLSTW-LOC17A-062719 06/27/2019 320-52169-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)65000 ug/L537 ModifiedUJ3535_PFC65000PQLSTW-LOC17A-062719 06/27/2019 320-52169-111Cl-PF3OUdS4000 ug/L537 ModifiedUJ3535_PFC4000PQLPage 14 of 57
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluorododecanesulfonic acid (PFDoS)5600 ug/L537 ModifiedUJ3535_PFC5600PQLSTW-LOC17A-062719 06/27/2019 320-52169-1ADONA2400 UG/L537 ModifiedUJ3535_PFC2400PQLSTW-LOC17A-062719 06/27/2019 320-52169-1NaDONA2400 ug/L537 ModifiedUJ3535_PFC2400PQLSTW-LOC17B-062719 06/27/2019 320-52276-110:2 Fluorotelomersulfonate1.9 ug/L537 ModifiedUJ3535_PFC1.9PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluorooctadecanoicacid4.6 ug/L537 ModifiedUJ3535_PFC4.6PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFOS5.4 UG/L537 ModifiedUJ3535_PFC5.4PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluoroundecanoicAcid11 UG/L537 ModifiedUJ3535_PFC11PQLSTW-LOC17B-062719 06/27/2019 320-52276-1N-methylperfluorooctanesulfonamidoacetic acid31 UG/L537 ModifiedUJ3535_PFC31PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluorobutanoic Acid4400 UG/L537 ModifiedUJ3535_PFC4400PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorobutaneSulfonic Acid2500 UG/L537 ModifiedUJ3535_PFC2500PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluoroheptanoicAcid3100 UG/L537 ModifiedUJ3535_PFC3100PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Perfluoroheptanesulfonic acid (PFHpS)2400 ug/L537 ModifiedUJ3535_PFC2400PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorononanoicAcid3400 UG/L537 ModifiedUJ3535_PFC3400PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorotetradecanoicAcid3600 UG/L537 ModifiedUJ3535_PFC3600PQLSTW-LOC17A-062719 06/27/2019 320-52169-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)25000 ug/L537 ModifiedUJ3535_PFC25000PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluoropentanesulfonic acid (PFPeS)3.0 ug/L537 ModifiedUJ3535_PFC3.0PQLSTW-LOC17B-062719 06/27/2019 320-52276-16:2 Fluorotelomersulfonate20 ug/L537 ModifiedUJ3535_PFC20PQLSTW-LOC17B-062719 06/27/2019 320-52276-1N-ethylperfluorooctanesulfonamidoacetic acid19 UG/L537 ModifiedUJ3535_PFC19PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorododecanoicAcid5.5 UG/L537 ModifiedUJ3535_PFC5.5PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorodecaneSulfonic Acid3.2 UG/L537 ModifiedUJ3535_PFC3.2PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorohexaneSulfonic Acid1.7 UG/L537 ModifiedUJ3535_PFC1.7PQLPage 15 of 57
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluorobutanoic Acid3.5 UG/L537 ModifiedUJ3535_PFC3.5PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorobutaneSulfonic Acid2.0 UG/L537 ModifiedUJ3535_PFC2.0PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorotetradecanoicAcid2.9 UG/L537 ModifiedUJ3535_PFC2.9PQLSTW-LOC17B-062719 06/27/2019 320-52276-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)20 ug/L537 ModifiedUJ3535_PFC20PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluorohexadecanoicacid (PFHxDA)8.9 ug/L537 ModifiedUJ3535_PFC8.9PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluorononanesulfonic acid1.6 ug/L537 ModifiedUJ3535_PFC1.6PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorotridecanoicAcid13 UG/L537 ModifiedUJ3535_PFC13PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorooctaneSulfonamide3.5 UG/L537 ModifiedUJ3535_PFC3.5PQLSTW-LOC17B-062719 06/27/2019 320-52276-19Cl-PF3ONS2.4 ug/L537 ModifiedUJ3535_PFC2.4PQLSTW-LOC17B-062719 06/27/2019 320-52276-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)52 ug/L537 ModifiedUJ3535_PFC52PQLSTW-LOC17B-062719 06/27/2019 320-52276-111Cl-PF3OUdS3.2 ug/L537 ModifiedUJ3535_PFC3.2PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluorododecanesulfonic acid (PFDoS)4.5 ug/L537 ModifiedUJ3535_PFC4.5PQLSTW-LOC17B-062719 06/27/2019 320-52276-1ADONA1.9 UG/L537 ModifiedUJ3535_PFC1.9PQLSTW-LOC17B-062719 06/27/2019 320-52276-1NaDONA1.9 ug/L537 ModifiedUJ3535_PFC1.9PQLSTW-LOC17B-062719 06/27/2019 320-52276-1Perfluoroheptanesulfonic acid (PFHpS)1.9 ug/L537 ModifiedUJ3535_PFC1.9PQLPage 16 of 57
One or more surrogates had relative percent recovery (RPR) values less than the data rejection level. The reporting limit may be bi-ased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC18-082119-1 08/21/2019 320-53640-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040 ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6N-methyl perfluoro-1-octanesulfonamide0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Perfluorooctadecanoicacid0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Perfluorohexadecanoicacid (PFHxDA)0.0020 ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-82-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040 ug/L537 ModifiedUJ3535_PFC0.0040PQLPage 17 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6B-062719 06/27/2019 320-51907-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 18 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 19 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6A-062719 06/27/2019 320-51907-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 20 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6B-062719 06/27/2019 320-51907-2PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 21 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-18-062719 06/27/2019 320-51907-4PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-18-062719 06/27/2019 320-51907-4EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 22 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-18-062719 06/27/2019 320-51907-4Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 23 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-19A-062719 06/27/2019 320-51907-5Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 24 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-19B-062719 06/27/2019 320-51907-6PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PMPA0.010 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.010PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 25 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-19A-062719 06/27/2019 320-51907-5PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6R-EVE0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Byproduct 40.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 26 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-19B-062719 06/27/2019 320-51907-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 27 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-21A-062719 06/27/2019 320-51907-7EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFECA B0.012 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.012PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFECA B0.012 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.012PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PES0.0092 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0092PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PES0.0092 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0092PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO5DA0.0067 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0067PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO5DA0.0067 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0067PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Hydro-EVE Acid0.0056 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0056PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Hydro-EVE Acid0.0056 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0056PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFECA-G0.0082 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0082PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFECA-G0.0082 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0082PQLSTW-LOC-22-062719 06/27/2019 320-51907-8EVE Acid0.0049 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0049PQLSTW-LOC-22-062719 06/27/2019 320-51907-8EVE Acid0.0049 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0049PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFECA B0.012 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.012PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFECA B0.012 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.012PQLPage 28 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-23B-062719 06/27/2019 320-51907-10 PES0.0092 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0092PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PES0.0092 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0092PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFECA-G0.0082 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0082PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFECA-G0.0082 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0082PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 29 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-24A-062719 06/27/2019 320-51907-11 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Byproduct 50.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 30 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0050PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 31 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC18-082119-2 08/21/2019 320-53640-6R-EVE0.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6R-EVE0.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6Byproduct 40.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6Byproduct 40.0039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8R-EVE0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8R-EVE0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8Byproduct 40.053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8Byproduct 40.052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8Byproduct 50.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8Byproduct 50.022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-062819 06/28/2019 320-51902-13 R-EVE0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-062819 06/28/2019 320-51902-13 R-EVE0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-062819 06/28/2019 320-51902-13 Byproduct 40.069 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-062819 06/28/2019 320-51902-13 Byproduct 40.072 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-062819 06/28/2019 320-51902-13 Byproduct 50.39 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-062819 06/28/2019 320-51902-13 Byproduct 50.41 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 32 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC20-082219 08/22/2019 320-53582-20 R-EVE0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 R-EVE0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 Byproduct 40.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 Byproduct 40.069 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 Byproduct 50.54 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 Byproduct 50.59 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1R-EVE0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1R-EVE0.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1Byproduct 40.074 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1Byproduct 40.079 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1Byproduct 50.64 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1Byproduct 50.7 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC21A-082119 08/21/2019 320-53582-6R-EVE0.034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC21A-082119 08/21/2019 320-53582-6Byproduct 40.031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC21A-082119 08/21/2019 320-53582-6Byproduct 40.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC21A-082119 08/21/2019 320-53582-6Byproduct 50.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7R-EVE0.0075 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 33 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPSTW-LOC22-082119 08/21/2019 320-53582-7R-EVE0.0065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7Byproduct 40.059 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7Byproduct 40.059 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7Byproduct 50.77 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7Byproduct 50.76 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119 08/21/2019 320-53582-8R-EVE0.0045 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119 08/21/2019 320-53582-8Byproduct 40.0097 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119 08/21/2019 320-53582-8Byproduct 50.0040 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119 08/21/2019 320-53582-8Byproduct 50.0046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9R-EVE0.0039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9Byproduct 40.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9Byproduct 40.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9Byproduct 50.0042 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9Byproduct 50.0045 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-062719 06/27/2019 320-51902-1Byproduct 50.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-082119 08/21/2019 320-53582-10 R-EVE0.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 34 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC24B-082119 08/21/2019 320-53582-10 R-EVE0.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-082119 08/21/2019 320-53582-10 Byproduct 40.0053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-082119 08/21/2019 320-53582-10 Byproduct 50.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-082119 08/21/2019 320-53582-10 Byproduct 50.0024 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-062719 06/27/2019 320-51902-2R-EVE0.0039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-062719 06/27/2019 320-51902-2Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-062719 06/27/2019 320-51902-2Byproduct 50.0053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-082119 08/21/2019 320-53582-3R-EVE0.0054 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-082119 08/21/2019 320-53582-3Byproduct 40.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-082119 08/21/2019 320-53582-3Byproduct 40.016 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-082119 08/21/2019 320-53582-3Byproduct 50.053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-082119 08/21/2019 320-53582-3Byproduct 50.05 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6A-082119 08/21/2019 320-53582-1Byproduct 50.0051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6A-082119 08/21/2019 320-53582-1Byproduct 50.0061 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6B-082119 08/21/2019 320-53582-2R-EVE0.0032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6B-082119 08/21/2019 320-53582-2R-EVE0.0032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6B-082119 08/21/2019 320-53582-2Byproduct 40.012 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 35 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPSTW-LOC6B-082119 08/21/2019 320-53582-2Byproduct 50.0025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6B-082119 08/21/2019 320-53582-2Byproduct 50.0028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7A-062819 06/28/2019 320-51902-4Byproduct 40.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7A-062819 06/28/2019 320-51902-4Byproduct 40.0034 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7A-082219 08/22/2019 320-53582-12 Byproduct 40.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7A-082219 08/22/2019 320-53582-12 Byproduct 50.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7A-082219 08/22/2019 320-53582-12 Byproduct 50.0033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719 06/27/2019 320-51902-5R-EVE0.0037 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719 06/27/2019 320-51902-5Byproduct 40.073 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719 06/27/2019 320-51902-5Byproduct 40.067 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719 06/27/2019 320-51902-5Byproduct 50.49 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719 06/27/2019 320-51902-5Byproduct 50.44 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719-D 06/27/2019 320-51902-6Byproduct 40.071 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719-D 06/27/2019 320-51902-6Byproduct 40.067 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719-D 06/27/2019 320-51902-6Byproduct 50.47 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-062719-D 06/27/2019 320-51902-6Byproduct 50.45 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 36 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC7B-082219 08/22/2019 320-53582-13 R-EVE0.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-082219 08/22/2019 320-53582-13 Byproduct 40.11 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-082219 08/22/2019 320-53582-13 Byproduct 40.12 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC9-082219 08/22/2019 320-53582-15 R-EVE0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC9-082219 08/22/2019 320-53582-15 R-EVE0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC9-082219 08/22/2019 320-53582-15 Byproduct 40.081 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC9-082219 08/22/2019 320-53582-15 Byproduct 40.08 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC9-082219 08/22/2019 320-53582-15 Byproduct 50.16 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC9-082219 08/22/2019 320-53582-15 Byproduct 50.15 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 R-EVE0.0023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 R-EVE0.0025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 R-EVE0.0038 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 R-EVE0.0039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Byproduct 40.0096 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7R-EVE0.0041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7R-EVE0.0046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Byproduct 40.019 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 37 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPSTW-LOC-21A-062719 06/27/2019 320-51907-7Byproduct 40.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Byproduct 50.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7Byproduct 50.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7R-EVE0.0032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7R-EVE0.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7Byproduct 40.0023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-3 08/21/2019 320-53640-7Byproduct 40.0023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5Byproduct 40.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5Byproduct 40.0031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2R-EVE0.0058 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2R-EVE0.0050 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2Byproduct 40.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1R-EVE0.0040 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1R-EVE0.0036 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Byproduct 40.0079 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 38 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC1-062819 06/28/2019 320-51902-3Byproduct 40.0028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC1-082219 08/22/2019 320-53582-11 R-EVE0.0040 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC1-082219 08/22/2019 320-53582-11 R-EVE0.0048 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC1-082219 08/22/2019 320-53582-11 Byproduct 40.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC1-082219 08/22/2019 320-53582-11 Byproduct 50.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC1-082219 08/22/2019 320-53582-11 Byproduct 50.011 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC10-082219 08/22/2019 320-53582-16 PFMOAA0.49 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC10-082219 08/22/2019 320-53582-16 PFMOAA0.49 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC10-082219 08/22/2019 320-53582-16 R-EVE0.28 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC10-082219 08/22/2019 320-53582-16 R-EVE0.29 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC10-082219 08/22/2019 320-53582-16 Byproduct 50.73 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC10-082219 08/22/2019 320-53582-16 Byproduct 50.73 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC12-082219 08/22/2019 320-53582-17 R-EVE0.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC12-082219 08/22/2019 320-53582-17 R-EVE0.0026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC12-082219 08/22/2019 320-53582-17 Byproduct 40.0092 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC12-082219 08/22/2019 320-53582-17 Byproduct 40.01 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC12-082219 08/22/2019 320-53582-17 Byproduct 50.0030 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0020PQLPage 39 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPSTW-LOC12-082219 08/22/2019 320-53582-17 Byproduct 50.0035 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC14-062819 06/28/2019 320-51902-10 Byproduct 50.0021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC14-082219 08/22/2019 320-53582-18 Byproduct 40.0050 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC14-082219 08/22/2019 320-53582-18 Byproduct 40.0047 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-062819 06/28/2019 320-51902-11 R-EVE0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-062819 06/28/2019 320-51902-11 Byproduct 40.080 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-062819 06/28/2019 320-51902-11 Byproduct 40.072 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-062819 06/28/2019 320-51902-11 Byproduct 50.25 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-062819 06/28/2019 320-51902-11 Byproduct 50.23 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082119 08/21/2019 320-53641-2R-EVE0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082119 08/21/2019 320-53641-2R-EVE0.025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082119 08/21/2019 320-53641-2Byproduct 40.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082119 08/21/2019 320-53641-2Byproduct 40.13 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082119 08/21/2019 320-53641-2Byproduct 50.35 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082119 08/21/2019 320-53641-2Byproduct 50.34 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082219 08/22/2019 320-53582-19 R-EVE0.015 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 40 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC15-082219 08/22/2019 320-53582-19 R-EVE0.016 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082219 08/22/2019 320-53582-19 Byproduct 40.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082219 08/22/2019 320-53582-19 Byproduct 40.058 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082219 08/22/2019 320-53582-19 Byproduct 50.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-082219 08/22/2019 320-53582-19 Byproduct 50.14 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 41 of 57
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC20-082219 08/22/2019 320-53582-20 Hfpo Dimer Acid0.049 UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC20-082219-D 08/22/2019 320-53641-1Hfpo Dimer Acid0.071 UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC24A-082119 08/21/2019 320-53582-8PFOS0.027 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC24A-082119 08/21/2019 320-53582-8R-EVE0.0058 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9PFOS0.022 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC24A-082119-D 08/21/2019 320-53582-9R-EVE0.0029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Byproduct 40.0044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 Byproduct 40.0050 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFOS0.03 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFOS0.017 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 Byproduct 40.0093 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFOA0.0088 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFOA0.011 UG/L537 ModifiedJ3535_PFC0.0020PQLPage 42 of 57
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-23B-062719 06/27/2019 320-51907-10 6:2 Fluorotelomersulfonate0.02 ug/L537 ModifiedJ3535_PFC0.020PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Hfpo Dimer Acid0.13 UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PerfluorohexanoicAcid0.021 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PerfluorohexanoicAcid0.0061 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFOA0.0031 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Perfluorobutanoic Acid0.0024 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PerfluoroheptanoicAcid0.0033 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5Hfpo Dimer Acid0.0045 UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC18-082119-2 08/21/2019 320-53640-6Perfluorobutanoic Acid0.0071 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5PerfluoropentanoicAcid0.0037 UG/L537 ModifiedJ3535_PFC0.0020PQLPage 43 of 57
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC21A-082119 08/21/2019 320-53582-6PFMOAA0.0095 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC21A-082119 08/21/2019 320-53582-6PFMOAA0.0067 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC21A-082119 08/21/2019 320-53582-6R-EVE0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC21A-082119 08/21/2019 320-53582-6Byproduct 50.02 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7NVHOS0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC23A-082119-4 08/21/2019 320-53640-4PFO5DA0.021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0067PQLSTW-LOC23A-082119-4 08/21/2019 320-53640-4PFO5DA0.017 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0067PQLSTW-LOC24A-082119 08/21/2019 320-53582-8Byproduct 40.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-062719 06/27/2019 320-51902-1Byproduct 50.01 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24B-082119 08/21/2019 320-53582-10 Byproduct 40.0079 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-062719 06/27/2019 320-51902-2R-EVE0.0052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-062719 06/27/2019 320-51902-2Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-062719 06/27/2019 320-51902-2Byproduct 50.0053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC24C-082119 08/21/2019 320-53582-3R-EVE0.0044 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC6B-082119 08/21/2019 320-53582-2Byproduct 40.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7A-082219 08/22/2019 320-53582-12 Byproduct 40.01 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC7B-082219 08/22/2019 320-53582-13 R-EVE0.0091 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 44 of 57
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC8-062819 06/28/2019 320-51902-7R-EVE0.029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0070PQLSTW-LOC8-062819 06/28/2019 320-51902-7R-EVE0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0070PQLSTW-LOC8-082219 08/22/2019 320-53582-14 R-EVE0.039 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.014PQLSTW-LOC8-082219 08/22/2019 320-53582-14 R-EVE0.047 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.014PQLSTW-LOC9-082219 08/22/2019 320-53582-15 PFMOAA0.025 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC9-082219 08/22/2019 320-53582-15 PFMOAA0.022 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFESA-BP20.13 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFESA-BP20.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.030PQLSTW-LOC-22-062719 06/27/2019 320-51907-8NVHOS0.065 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.011PQLSTW-LOC-22-062719 06/27/2019 320-51907-8NVHOS0.077 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.011PQLSTW-LOC-16-062819 06/28/2019 320-51907-3PFO5DA14.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.34PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1Byproduct 40.0091 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC1-082219 08/22/2019 320-53582-11 Byproduct 40.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC15-062819 06/28/2019 320-51902-11 R-EVE0.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 45 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PMPA0.030 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PMPA0.028 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 NVHOS0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PMPA0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PMPA0.029 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO2HxA0.014 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO2HxA0.014 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO3OA0.0021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719 06/27/2019 320-51907-11 PFO3OA0.0022 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 R-EVE0.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.014PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 R-EVE0.19 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.014PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Byproduct 40.58 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.032PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Byproduct 40.56 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.032PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Byproduct 50.45 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Byproduct 50.44 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Byproduct 60.0045 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0031PQLPage 46 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-23B-062719 06/27/2019 320-51907-10 Byproduct 60.0043 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0031PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 EVE Acid0.0051 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0049PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 EVE Acid0.0052 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0049PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFESA-BP20.11 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0061PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFESA-BP20.11 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0061PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Hydro-EVE Acid0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0056PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 Hydro-EVE Acid0.020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0056PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PMPA19 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.11PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PMPA18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.11PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO2HxA0.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO2HxA0.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO3OA0.067 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO3OA0.064 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO4DA0.061 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO4DA0.061 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO5DA0.077 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0067PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO5DA0.071 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0067PQLPage 47 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFMOAA0.16 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.042PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFMOAA0.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.042PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PEPA8.5 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PEPA8.2 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFESA-BP10.049 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0053PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFESA-BP10.047 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0053PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 NVHOS0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.011PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 NVHOS0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.011PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFESA-BP20.15 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0061PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFESA-BP20.16 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0061PQLSTW-LOC-22-062719 06/27/2019 320-51907-8R-EVE0.054 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.014PQLSTW-LOC-22-062719 06/27/2019 320-51907-8R-EVE0.053 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.014PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Byproduct 40.50 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.032PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Byproduct 40.48 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.032PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Byproduct 513 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Byproduct 514 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Byproduct 60.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0031PQLPage 48 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-22-062719 06/27/2019 320-51907-8Byproduct 60.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0031PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFMOAA0.22 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.042PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFMOAA0.22 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.042PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PMPA1.5 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.11PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PMPA1.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.11PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PEPA0.21 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PEPA0.22 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFESA-BP10.18 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0053PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFESA-BP10.17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0053PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO2HxA0.54 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO2HxA0.58 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO3OA0.027 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO3OA0.027 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.012PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO4DA0.032 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-22-062719 06/27/2019 320-51907-8PFO4DA0.031 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.016PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFESA-BP20.0022 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFESA-BP20.0023 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 49 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-21A-062719 06/27/2019 320-51907-7PFESA-BP10.0097 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFESA-BP10.0095 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO2HxA0.015 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO2HxA0.015 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO3OA0.0029 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFO3OA0.0030 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PMPA0.033 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PMPA0.032 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO2HxA0.0026 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19A-062719 06/27/2019 320-51907-5PFO2HxA0.0028 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7NVHOS0.0025 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7NVHOS0.0023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFESA-BP20.021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFESA-BP20.021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO2HxA0.0031 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-062719 06/27/2019 320-51907-6PFO2HxA0.0030 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 50 of 57
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-6B-062719 06/27/2019 320-51907-2PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PFO2HxA0.011 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-6A-062719 06/27/2019 320-51907-1PMPA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFESA-BP10.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFESA-BP10.0022 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO2HxA0.014 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO2HxA0.014 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO3OA0.0023 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-062719-D 06/27/2019 320-51907-12 PFO3OA0.0024 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO2HxA0.013 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-062719 06/27/2019 320-51907-2PFO2HxA0.013 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 51 of 57
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17B-062719 06/27/2019 320-52276-1Hfpo Dimer Acid (trial) 370000.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep34PQLSTW-LOC17A-062719 06/27/2019 320-52169-1N-ethylperfluoro-1-octanesulfonamide60 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep37PQLSTW-LOC17A-062719 06/27/2019 320-52169-1N-ethylperfluoro-1-octanesulfonamide52.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep37PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PEPA63 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep19PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PEPA66.0 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep19PQLPage 52 of 57
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO5DA0.098 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLSTW-LOC-23B-062719 06/27/2019 320-51907-10 PFO5DA0.082 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.034PQLSTW-LOC-16-062819 06/28/2019 320-51907-3PFO5DA11 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.34PQLPage 53 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC20-082219 08/22/2019 320-53582-20 PFO2HxA0.21 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 PFO2HxA0.22 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC20-082219 08/22/2019 320-53582-20 PFMOAA0.65 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC20-082219 08/22/2019 320-53582-20 PFMOAA0.67 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC22-082119 08/21/2019 320-53582-7NVHOS0.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PMPA0.020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC22-082119 08/21/2019 320-53582-7PMPA0.019 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFO2HxA0.045 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFO2HxA0.045 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFO5DA0.0038 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFO5DA0.0041 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFMOAA0.036 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC22-082119 08/21/2019 320-53582-7PFMOAA0.036 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFMOAA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC-21A-062719 06/27/2019 320-51907-7PFMOAA0.012 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0050PQLSTW-LOC-18-062719 06/27/2019 320-51907-4PFO2HxA0.0024 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 54 of 57
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC-18-062719 06/27/2019 320-51907-4PFO2HxA0.0023 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8PMPA0.064 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC18-082119-4 08/21/2019 320-53640-8PMPA0.063 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 55 of 57
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorononanoicAcid3.5 UG/L537 ModifiedJ3535_PFC2.7PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluoroheptanoicAcid6.6 UG/L537 ModifiedJ3535_PFC2.5PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PFOA1300.0 UG/L537 ModifiedJ3535_PFC8.5PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorodecanoicAcid73.0 UG/L537 ModifiedJ3535_PFC3.1PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluorohexanoicAcid6.7 UG/L537 ModifiedJ3535_PFC5.8PQLSTW-LOC17B-062719 06/27/2019 320-52276-1PerfluoropentanoicAcid28.0 UG/L537 ModifiedJ3535_PFC4.9PQLSTW-LOC17A-062719 06/27/2019 320-52169-1PerfluorohexaneSulfonic Acid4000.0 UG/L537 ModifiedJ3535_PFC2100PQLSTW-LOC17A-062719 06/27/2019 320-52169-1Hfpo Dimer Acid820000.0 UG/L537 ModifiedJ3535_PFC19000PQLPage 56 of 57
One or more surrogates had relative percent recovery (RPR) values less than the data rejection level. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 Stormwater SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSTW-LOC18-082119-4 08/21/2019 320-53640-8Perfluorobutanoic Acid0.012 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC22-082119 08/21/2019 320-53582-7Perfluorobutanoic Acid0.0054 UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-062719 06/27/2019 320-51907-8Perfluorobutanoic Acid0.037 UG/L537 ModifiedJ3535_PFC0.0035PQLSTW-LOC18-082119-1 08/21/2019 320-53640-5Perfluorobutanoic Acid0.014 UG/L537 ModifiedJ3535_PFC0.0020PQLPage 57 of 57
ADQM Data Review Narrative - FAY 2019 WWTP 24 HOUR COMPOSITE.doc 1 of 3
ADQM DATA REVIEW NARRATIVE

Site Chemours FAY – Fayetteville
Project 2019 WWTP 24 HOUR COMPOSITE
Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates September 16, 2019 Analytical Protocol

Laboratory Analytical Method Parameter(s)
Eurofins Lancaster 537 Modified PFAS1
Eurofins Lancaster Cl. Spec. Table 3 Compound SOP Table 3+ compounds

1 Perfluoroalkylsubstances, a list of 36 compounds including HFPO-DA. Sample Receipt
The following items are noted for this data set:

• All samples were received in satisfactory condition and within EPA temperature guidelines on
September 18, 2019. Data Review The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process.
Overall the data is acceptable for use without qualification, except as noted below:

• Results for PFO4DA, PFO5DA, and Byproduct 5 in field sample ID WWTP-LOC22-071619 have been qualified B, and may be biased high, or may be false positives, because an associated
lab method blank contained a comparable concentration.
• Analytical results have been qualified J as estimated, and non-detect results qualified UJ
indicating an estimated reporting limit, due to poor recovery of surrogate, laboratory blank spike, or matrix spike compounds; sample preparation and/or analysis which exceeded the laboratory hold times; and poor field duplicate or lab replicate precision. See the Data Verification Module
(DVM) Narrative Report for which samples were qualified, the specific reasons for qualification, and potential bias in reported results.

ADQM Data Review Narrative - FAY 2019 WWTP 24 HOUR COMPOSITE.doc 2 of 3
Attachments
The DVM Narrative report is attached. The lab report due to a large page count is stored on an AECOM network shared drive and is available to be posted on external shared drives, or on a flash drive.
ADQM Data Review Narrative - FAY 2019 WWTP 24 HOUR COMPOSITE.doc 3 of 3
Data Verification Module (DVM)
The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD
between these spikes
• Surrogate spike recoveries for organic analyses
• RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.
Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory
or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank.
If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

DVM Narrative ReportContamination detected in Method Blank(s). Sample result does not differ significantly from the analyte concentration detected in the associated methodblank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC22-071619 07/16/2019 1107388PFO4DA2.8 ug/LCl. Spec. Table 3Compound SOPB0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFO4DA2.1 ug/LCl. Spec. Table 3Compound SOPB0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFO5DA3.1 ug/LCl. Spec. Table 3Compound SOPB0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFO5DA2.5 ug/LCl. Spec. Table 3Compound SOPB0.20PQLWWTP-LOC22-071619 07/16/2019 1107385Byproduct 559 UG/LCl. Spec. Table 3Compound SOPB2.0PQLPage 1 of 20
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC18-071619 07/16/2019 1107384PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFECA B0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJ0.020PQLWWTP-LOC18-071619 07/16/2019 1107384PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFESA-BP10.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381Byproduct 60.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PES0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFO3OA0.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJ0.0050PQLWWTP-LOC18-071619 07/16/2019 1107381PFMOAA0.0050 ug/LCl. Spec. Table 3Compound SOPUJ0.0050PQLPage 2 of 20
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC18-071619 07/16/2019 1107384EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFESA-BP20.0020 ug/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381Hydro-EVE Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFECA-G0.0020 UG/LCl. Spec. Table 3Compound SOPUJ0.0020PQLPage 3 of 20
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC18-071619 07/16/2019 1107381PerfluorotetradecanoicAcid0.0017 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0017PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluorooctadecanoicacid0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC23-071619 07/16/2019 11073892-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorooctaneSulfonamide0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 11073891H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389DONA0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23A1-071619 07/16/2019 11073932-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.032 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.032PQLWWTP-LOC23A1-071619 07/16/2019 11073932-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.032 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.032PQLWWTP-LOC23A1-071619 07/16/2019 1107393PerfluorotetradecanoicAcid0.021 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.021PQLWWTP-LOC23A1-071619 07/16/2019 1107393PerfluorooctaneSulfonamide0.021 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.021PQLWWTP-LOC23A1-071619 07/16/2019 11073939Cl-PF3ONS0.021 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.021PQLWWTP-LOC23A1-071619 07/16/2019 11073931H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.021 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.021PQLWWTP-LOC23A1-071619 07/16/2019 110739311Cl-PF3OUdS0.021 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.021PQLWWTP-LOC23A2-071619 07/16/2019 1107397PerfluorotetradecanoicAcid0.0016 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0016PQLWWTP-LOC23A2-071619 07/16/2019 1107397PerfluorooctaneSulfonamide0.0016 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0016PQLWWTP-LOC23A2-071619 07/16/2019 11073979Cl-PF3ONS0.0016 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0016PQLWWTP-LOC23A2-071619 07/16/2019 11073971H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0016 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0016PQLWWTP-LOC23A2-071619 07/16/2019 110739711Cl-PF3OUdS0.0016 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0016PQLPage 4 of 20
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC23A2-071619 07/16/2019 11073972-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0024 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0024PQLWWTP-LOC23A2-071619 07/16/2019 11073972-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0024 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0024PQLWWTP-LOC8-071819 07/18/2019 11074012-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC8-071819 07/18/2019 11074012-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC22-071619 07/16/2019 1107385N-ethylperfluoro-1-octanesulfonamide0.49 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.49PQLWWTP-LOC22-071619 07/16/2019 11073852-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.3 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.3PQLWWTP-LOC18-071619 07/16/2019 11073812-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0026 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0026PQLWWTP-LOC18-071619 07/16/2019 11073812-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0026 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0026PQLWWTP-LOC1-071619 07/16/2019 1107377PerfluorotetradecanoicAcid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC1-071619 07/16/2019 1107377PerfluorooctaneSulfonamide0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC1-071619 07/16/2019 11073779Cl-PF3ONS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC1-071619 07/16/2019 11073771H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC1-071619 07/16/2019 110737711Cl-PF3OUdS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC1-071619 07/16/2019 11073772-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC1-071619 07/16/2019 11073772-(N-methyl perfluoro-1-octanesulfonamido)-0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLPage 5 of 20
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsethanolWWTP-LOC18-071619 07/16/2019 1107381N-ethylperfluoro-1-octanesulfonamide0.0043 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0043PQLWWTP-LOC18-071619 07/16/2019 1107381PerfluorooctaneSulfonamide0.0017 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0017PQLWWTP-LOC18-071619 07/16/2019 11073819Cl-PF3ONS0.0017 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0017PQLWWTP-LOC18-071619 07/16/2019 11073811H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0017 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0017PQLWWTP-LOC18-071619 07/16/2019 110738111Cl-PF3OUdS0.0017 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0017PQLWWTP-LOC8-071819 07/18/2019 1107401PerfluorotetradecanoicAcid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC8-071819 07/18/2019 1107401PerfluorooctaneSulfonamide0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC8-071819 07/18/2019 11074019Cl-PF3ONS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC8-071819 07/18/2019 11074011H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC8-071819 07/18/2019 110740111Cl-PF3OUdS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC8-071819-D 07/18/2019 11074092-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOCEB-071819 07/18/2019 11074052-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOCEB-071819 07/18/2019 11074052-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOCEB-071819 07/18/2019 1107405PerfluorotetradecanoicAcid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOCEB-071819 07/18/2019 1107405N-ethylperfluoro-1-octanesulfonamide0.0045 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0045PQLWWTP-LOCEB-071819 07/18/2019 1107405PerfluorooctaneSulfonamide0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOCEB-071819 07/18/2019 11074059Cl-PF3ONS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOCEB-071819 07/18/2019 11074051H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLPage 6 of 20
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOCEB-071819 07/18/2019 110740511Cl-PF3OUdS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLPage 7 of 20
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC23-071619 07/16/2019 110738910:2 Fluorotelomersulfonate0.0045 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0045PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluoroundecanoicAcid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluoropentanesulfonic acid (PFPeS)0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 11073896:2 Fluorotelomersulfonate0.0045 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0045PQLWWTP-LOC23-071619 07/16/2019 1107389N-ethylperfluorooctanesulfonamidoacetic acid0.0027 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorodecanoicAcid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorodecaneSulfonic Acid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluoroheptanesulfonic acid (PFHpS)0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorononanoicAcid0.0018 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 11073891H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluorononanesulfonic acid0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 11073899Cl-PF3ONS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 110738911Cl-PF3OUdS0.0018 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluorododecanesulfonic acid (PFDoS)0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLPage 8 of 20
One or more surrogates had relative percent recovery (RPR) values less than the data rejection level. The reported result is unusable.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC23-071619 07/16/2019 1107389N-methyl perfluoro-1-octanesulfonamide0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC23-071619 07/16/2019 1107389N-ethylperfluoro-1-octanesulfonamide0.0045 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0045PQLWWTP-LOC23A1-071619 07/16/2019 1107393N-ethylperfluoro-1-octanesulfonamide0.053 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.053PQLWWTP-LOC23A2-071619 07/16/2019 1107397N-ethylperfluoro-1-octanesulfonamide0.0041 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0041PQLWWTP-LOC23A2-071619 07/16/2019 1107397N-methyl perfluoro-1-octanesulfonamide0.0024 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0024PQLWWTP-LOC1-071619 07/16/2019 1107377N-ethylperfluoro-1-octanesulfonamide0.0045 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0045PQLWWTP-LOC1-071619 07/16/2019 1107377N-methyl perfluoro-1-octanesulfonamide0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC8-071819 07/18/2019 1107401N-ethylperfluoro-1-octanesulfonamide0.0045 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0045PQLWWTP-LOC8-071819 07/18/2019 1107401N-methyl perfluoro-1-octanesulfonamide0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC8-071819-D 07/18/2019 1107409N-methyl perfluoro-1-octanesulfonamide0.0027 ug/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0027PQLWWTP-LOC8-071819-D 07/18/2019 1107409N-ethylperfluoro-1-octanesulfonamide0.0044 UG/LEPA 537 Rev.1.1 modifiedUJ537_Prep0.0044PQLPage 9 of 20
The analysis hold time for this sample was exceeded by a factor of 2. The reported non-detect result is unusable.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC22-071619 07/16/2019 1107388Byproduct 60.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385Byproduct 60.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFECA-G0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFECA-G0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388EVE Acid0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385EVE Acid0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFECA B0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFECA B0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PEPA2.0 UG/LCl. Spec. Table 3Compound SOPUJ2.0PQLWWTP-LOC22-071619 07/16/2019 1107385PEPA2.0 UG/LCl. Spec. Table 3Compound SOPUJ2.0PQLWWTP-LOC22-071619 07/16/2019 1107388PFESA-BP10.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFESA-BP10.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PES0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PES0.20 UG/LCl. Spec. Table 3Compound SOPUJ0.20PQLPage 10 of 20
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may bebiased high.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC8-071819-D 07/18/2019 1107412Byproduct 52.8 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC8-071819-D 07/18/2019 1107409Byproduct 52.6 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC8-071819 07/18/2019 1107404Byproduct 52.8 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC8-071819 07/18/2019 1107401Byproduct 52.8 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC1-071619 07/16/2019 1107380Byproduct 50.0063 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC1-071619 07/16/2019 1107377Byproduct 50.0060 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC23A2-071619 07/16/2019 1107400Byproduct 50.019 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC23A2-071619 07/16/2019 1107397Byproduct 50.020 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC23A1-071619 07/16/2019 1107396Byproduct 50.26 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC23A1-071619 07/16/2019 1107393Byproduct 50.27 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC23-071619 07/16/2019 1107392Byproduct 54.6 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC23-071619 07/16/2019 1107389Byproduct 54.3 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLPage 11 of 20
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC18-071619 07/16/2019 1107384R-EVE0.0084 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381R-EVE0.0074 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384Byproduct 40.024 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384Byproduct 50.0094 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381Byproduct 50.0088 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC1-071619 07/16/2019 1107380R-EVE0.0037 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC1-071619 07/16/2019 1107377R-EVE0.0041 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC1-071619 07/16/2019 1107380Byproduct 40.014 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLPage 12 of 20
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC8-071819-D 07/18/2019 1107412PEPA0.031 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC8-071819-D 07/18/2019 1107409PEPA0.022 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC8-071819 07/18/2019 1107404PEPA0.050 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLWWTP-LOC8-071819 07/18/2019 1107401PEPA0.053 UG/LCl. Spec. Table 3Compound SOPJ0.020PQLPage 13 of 20
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC1-071619 07/16/2019 1107377Hfpo Dimer Acid0.014 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0027PQLWWTP-LOC8-071819-D 07/18/2019 1107409PerfluorobutaneSulfonic Acid0.004 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC8-071819 07/18/2019 1107401PerfluorobutaneSulfonic Acid0.0035 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC8-071819-D 07/18/2019 1107409Hfpo Dimer Acid0.11 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0027PQLWWTP-LOC18-071619 07/16/2019 1107381Hfpo Dimer Acid0.043 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0026PQLWWTP-LOC1-071619 07/16/2019 1107377PerfluorobutaneSulfonic Acid0.0033 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC22-071619 07/16/2019 1107385Hfpo Dimer Acid0.79 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.3PQLWWTP-LOC18-071619 07/16/2019 1107381Perfluorobutanoic Acid0.018 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0043PQLWWTP-LOC23A2-071619 07/16/2019 1107397PerfluorobutaneSulfonic Acid0.0029 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0016PQLWWTP-LOC23A1-071619 07/16/2019 1107393Hfpo Dimer Acid12 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.32PQLPage 14 of 20
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC18-071619 07/16/2019 1107381Byproduct 40.018 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC1-071619 07/16/2019 1107377Byproduct 40.016 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLPage 15 of 20
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC22-071619 07/16/2019 1107388PMPA1.1 UG/LCl. Spec. Table 3Compound SOPJ1.0PQLWWTP-LOC22-071619 07/16/2019 1107385PMPA1.1 UG/LCl. Spec. Table 3Compound SOPJ1.0PQLWWTP-LOC22-071619 07/16/2019 1107388NVHOS5.8 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385NVHOS6.1 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFO2HxA1.6 ug/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFO2HxA1.7 ug/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFO3OA1.2 ug/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFO3OA1.1 ug/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFESA-BP26.7 ug/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385PFESA-BP26.5 ug/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388Hydro-EVE Acid0.37 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385Hydro-EVE Acid0.37 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388PFMOAA5.7 ug/LCl. Spec. Table 3Compound SOPJ0.50PQLWWTP-LOC22-071619 07/16/2019 1107385PFMOAA5.9 ug/LCl. Spec. Table 3Compound SOPJ0.50PQLWWTP-LOC22-071619 07/16/2019 1107388R-EVE1.5 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107385R-EVE1.5 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLWWTP-LOC22-071619 07/16/2019 1107388Byproduct 47.8 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLPage 16 of 20
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC22-071619 07/16/2019 1107385Byproduct 47.4 UG/LCl. Spec. Table 3Compound SOPJ0.20PQLPage 17 of 20
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC18-071619 07/16/2019 1107384PMPA0.022 UG/LCl. Spec. Table 3Compound SOPJ0.010PQLWWTP-LOC18-071619 07/16/2019 1107381PMPA0.027 UG/LCl. Spec. Table 3Compound SOPJ0.010PQLWWTP-LOC18-071619 07/16/2019 1107384NVHOS0.0029 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381NVHOS0.0033 UG/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107384PFO2HxA0.0093 ug/LCl. Spec. Table 3Compound SOPJ0.0020PQLWWTP-LOC18-071619 07/16/2019 1107381PFO2HxA0.0091 ug/LCl. Spec. Table 3Compound SOPJ0.0020PQLPage 18 of 20
Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC23-071619 07/16/2019 11073892-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0027 ug/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0027PQLPage 19 of 20
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:2019 WWTP 24 HOUR COMPOSITEAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsWWTP-LOC23-071619 07/16/2019 1107389PerfluorotridecanoicAcid0.0049 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluorohexadecanoicacid (PFHxDA)0.0046 ug/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0027PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorotetradecanoicAcid0.0072 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PFOA0.022 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorohexaneSulfonic Acid0.0056 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389Perfluorobutanoic Acid0.11 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0045PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorobutaneSulfonic Acid0.0032 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluoroheptanoicAcid0.0092 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorohexanoicAcid0.015 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluorododecanoicAcid0.0023 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PerfluoropentanoicAcid0.02 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389N-methylperfluorooctanesulfonamidoacetic acid0.0026 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389PFOS0.013 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0018PQLWWTP-LOC23-071619 07/16/2019 1107389Hfpo Dimer Acid0.12 UG/LEPA 537 Rev.1.1 modifiedJ537_Prep0.0027PQLPage 20 of 20