1119_DukeAsheville_Semiannual_WQM Report_FID1636968_20220119

(� DUKE
ENERGY
January 19, 2022
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
1646 Mail Service Center
Raleigh, North Carolina 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semiannual Water Quality Monitoring Report — September 2021
CCR Landfill
Permit No. 1119-INDUS-2020
Asheville Steam Electric Plant
Buncombe County, North Carolina
Dear Ms. Moutos:
526 South Church St.
Charlotte, NC 28202
Mailing Address
P.O. Box 1006
Mail Code EC 13K.
Charlotte, NC 28201-1006
717-982-0986
Duke Energy is providing the results of the September 2021 semiannual water quality monitoring for the Duke Energy
Progress Asheville CCR Landfill (1119-INDUS), located in Arden, Buncombe County, North Carolina.
Sampling was conducted on September 20 and 21, 2021 in accordance with the approved Water Quality Monitoirng Plan
(WQMP). The September 2021 monitoring event included samples from nine groundwater monitoring wells, two surface
water locations, one seep location, and one sample of composite leachate. Three surface water locations are
desiganated in the WQMP, however one location was dry during the event.
The groundwater analytical results are compared to the groundwater standards found in Title 15A NCAC 02L .0202 (02L
Standards). The surface water and seep analytical results are compared to the surface water standards found in Title
15A NCAC 02B .0211 (02B Standard) for Class C waters. Leachate analytical results are not compared to groundwater
or surface water quality standards.
Duke Energy personnel sample designated locations for groundwater, surface water, and leachate at the Asheville CCR
Landfill semiannually during March and September. The next water quality monitoring event for the CCR Landfill is
planned for March 2022 with a report of monitoring results to follow.
If you have any questions or concerns with this submittal, please do not hesitate to contact me at Ashley. HealvCa)duke-
energy.com or [phone].
Respectfully submitted,
J4144i
Ashley Healy, P.G.
Environmental Services
Attachments: Semiannual Water Quality Monitoring Report — September 2021 Sampling Event; SynTerra, January 2022
cc (via e-mail): Jordan Russ, NCDEQ
Sherri Stanley, NCDEQ
Ed Mussler, NCDEQ
Kelly Ferri, SynTerra
Craig Eady, SynTerra
Matt Pickett, Duke Energy
John Toepfer, Duke Energy
Dee O'Brien, Duke Energy
www.duke-energy.com Page 1 of 1

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Kelly Ferri Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit# (.0500 or.1600) October 20-24, 2006)
1119-INDUS-2020 1.0500 e tember 20-21, 2021
Duke Energy Progress
Asheville Steam Electric L46Duke Energy Lane
n, NC 28704Plant
CCR Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Craig D. Eady
Project Manager
Facility Representative Name (Print) Title
Signature
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
1 /19/2022
Date
[phone]
(Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
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NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

REPORT VERIFICATION
PROJECT: SEMIANNUAL GROUNDWATER MONITORING REPORT
SEPTEMBER 2021 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
CCR LANDFILL
PERMIT NO. 1119-INDUS-2020
TITLE: SEPTEMBER 2021 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the
intended application.
Prepared by: Date
Approved by: �� Date
Project Manager: Craig Ea�(�PC LGC!
1/19/2022
1/19/2022
Licensed Geologist Seal:
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SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

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Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
SEPTEMBER 2021 SAMPLING EVENT
CCR LANDFILL
(PERMIT NO. 1119-INDUS-2020)
ASHEVILLE STEAM ELECTRIC PLANT
46 DUKE ENERGY LANE
ARDENT NORTH CAROLINA 28704
JANUARY 2022
PREPARED FOR
r� DUDE
ENERGY.
PROGRESS
DUKE ENERGY PROGRESS, LLC
Crai D. Eady, L.G. # t99
enior Peer Revi wer
riap McGann
ei't Scientist
Kelly Ferri
Project Manager

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0
INTRODUCTION AND BACKGROUND..............................................................1-1
1.1
Site and Landfill Information..................................................................................1-1
1.2
Hydrogeologic Setting..............................................................................................1-1
1.3
Landfill Semi -Annual Monitoring Program.........................................................1-2
2.0
METHODS.....................................................................................................................
2-1
2.1
Sampling and Analysis Methods............................................................................2-1
2.2
Regulatory Criteria...................................................................................................2-1
2.3
Statement of Work....................................................................................................
2-2
3.0
RESULTS........................................................................................................................
3-1
3.1
Site Groundwater Flow............................................................................................
3-1
3.2
Historical Range Data...............................................................................................3-1
3.3
Analytical Results.....................................................................................................
3-2
3.4
Quality Assurance/Quality Control.......................................................................3-3
4.0
REFERENCES................................................................................................................
4-1
January 2022 Page i
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Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3a Water -level Map - Surficial and Transition Flow Zones - September 2021
Figure 3b Water -level Map - Bedrock Flow Zone - September 2021
LIST OF TABLES
Table 1 Well Construction Summary
Table 2 Groundwater, Surface Water, and Leachate Monitoring Parameters
Table 3 Groundwater Seepage Velocities
Table 4 Field Data Parameters
Table 5 Groundwater Field Results and Analytical Detections
Table 6 Field and Analytical Results that Equal or Exceed Groundwater Quality
Standards
Table 7 Surface Water Field Results and Analytical Detections
Table 8 Field and Analytical Results that Equal or Exceed Surface Water Quality
Standards
Table 9 Leachate Field Results and Analytical Detections
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
January 2022 Page H
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Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
LIST OF ACRONYMS
02L
Title 15A NCAC 02L .0202(g) Groundwater Quality Standards
02B
15A NCAC 02B .0200 Surface Water and Wetland standards
Asheville Plant
Asheville Steam Electric Plant
CCR
coal combustion residuals
Duke Energy
Duke Energy Progress, LLC
EDD
electronic data deliverable
IMAC
interim maximum allowable concentration
Landfill
Asheville CCR Landfill
MSE
mechanically stabilized earth
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
Site
Asheville Steam Electric Plant
SWLF
Solid Waste Landfill
SWS
Solid Waste Section
TDS
Total dissolved solids
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
January 2022 Page iii
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
1.0 INTRODUCTION AND BACKGROUND
This semiannual report pertains to the Duke Energy Progress, LLC (Duke Energy)
Asheville Steam Electric Plant (Asheville Plant, Site) Coal Combustion Residual (CCR)
Landfill (Landfill; Permit No. 1119-INDUS-2020) and documents the results of the
September 2021 Solid Waste Landfill (SWLF) groundwater, surface water and leachate
monitoring event.
1.1 Site and Landfill Information
Duke Energy owns and operates the Asheville Steam Electric Plant, located on
approximately 786 acres, addressed at 46 Duke Energy Lane in Arden, Buncombe
County, North Carolina. (Figure 1). The Asheville Plant began operations in 1964 with
construction of two coal-fired power generating units to generate electricity.
Throughout the period of coal-fired generation, CCR was managed and stored on -Site
in the 1964 and 1982 Ash Basins. The Asheville Plant ceased burning coal in January
2020 and replaced the coal-fired units with a natural gas combined cycle station for
electricity generation; thus, the facility no longer generates CCR. The 1982 Ash Basin
has been excavated, and excavation of the 1964 Ash Basin is ongoing.
Development and construction activities for the on -Site double -lined CCR Landfill
began in February 2020 and were completed in March 2021. The CCR Landfill was
constructed in an area previously developed as a laydown yard, located north of and
adjacent to the 1964 Ash Basin (Figure 1). The CCR Landfill was constructed to support
the (currently ongoing) last phase of ash excavation from the 1964 Ash Basin. The
Landfill received a Permit Approval to Operate from the North Carolina Department of
Environmental Quality (NCDEQ) on April 1, 2021, and initial placement of CCR
material in the Landfill occurred on the same day. The Landfill Operations Plan
(Geosyntec, 2021) and Landfill Permit outline a variety of landfill -approved wastes;
however, the primary waste disposed of in the Landfill is CCR (fly ash and bottom ash).
1.2 Hydrogeologic Setting
The Site hydrogeology is well understood from site assessments implemented under
the Coal Ash Management Act (CAMA). Groundwater occurs (and is discussed) in
terms of three "distinct" yet highly interconnected flow zones. The first and shallowest
groundwater —the surficial flow zone —occurs in the residual soil and/or the upper
section of saprolite. The residual soil and saprolite soil units thin to the west and
northwest of the Site resulting in a thin or absent surficial flow zone in these areas.
Beneath the shallow flow zone, the transition zone flow zone occurs in the lower
portions of the saprolite and partially weathered bedrock and is the most permeable
January 2022 Page 1-1
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
part of the Site hydrogeologic system. Bedrock underlies the transition zone and
comprises the least permeable flow zone of the Site hydrogeologic system, where
groundwater flow occurs predominantly along fractures, joints, and faults. As alluded
to earlier, groundwater is usually encountered in the surficial flow zone; however, as
the hydrogeologic units above the bedrock thin to the west and northwest, groundwater
is encountered only within lower hydrogeologic unit(s).
Groundwater flow direction at the Site is generally toward the west and northwest
toward several surface water features. One stream is located west of the landfill. A
wetland area and several streams, merging into one known as Powell Creek, are located
northwest of the landfill. The wetland area and streams act as groundwater discharge
zones downgradient of the landfill. Lake Julian also contributes flow to Powell Creek.
These surface waters have a 15A NCAC .02B Class C surface water classification. Flow
from these surface water features eventually reaches the French Broad River.
1.3 Landfill Semi -Annual Monitoring Program
The Water Quality Monitoring Plan (WQMP), Revision 2 (Geosyntec, 2019) for the CCR
Landfill was submitted to NCDEQ on October 31, 2019, and approved on February 7,
2020. The Landfill semi-annual monitoring program, described in detail in the WQMP,
is summarized in the following table with noted locations portrayed on Figure 2.
Analytical parametric coverage for the Landfill semi-annual groundwater monitoring
program is summarized in Table 2.
January 2022 Page 1-2
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
MEDIA
MONITORING WELLS
COMMENTS
OR SAMPLE LOCATIONS
Background
CB-9, CB-9SL, CB-9BR
Groundwater
LMW-1S, LMW-1B
See Table 1 Well Construction
Summary for monitoring well
Downgradient
LMW-2T, LMW-2B,
construction information.
Groundwater
LWM-3B, LMW-4B
Three (3) surface water
monitoring locations in two
streams located west and
LF-SW-1, LF-SW-2, LF-SW-3
north-northwest, adjacent,
and downgradient of the
Landfill (sampled if flow is
present during semi-annual
monitoring).
Surface Water
Drainpipe for groundwater
seepage from the northwest
portion of the Landfill's
DP-4
mechanically stabilized earth
(MSE) berm (sampled if flow is
present during semi-annual
monitoring).
Leachate sample, representing
leachate from the entire
landfill, collected from an in-
Leachate
LCS-1
line sampling point along the
forcemain conveying leachate
from the Landfill to the
Leachate Storage Tank.
Notes:
1. The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised to
differentiate between other Site monitoring program surface water locations.
2. The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sample
collection.
3. Two additional groundwater monitoring wells (LMW-1T and LMW-2S) were included as proposed monitoring
wells in the WQMP but were not installed. Monitoring well LMW-1T was proposed to be screened in the
transition zone; however, no transition zone was observed during drilling. Monitoring well LMW-2S was not
installed because the surficial aquifer was not present at the proposed location.
January 2022 Page 1-3
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling was performed by SynTerra
Corporation (SynTerra Field Certification #5591) and Duke Energy personnel on
September 20 and 21, 2021, in accordance with the North Carolina Solid Waste
Management Guidelines. Copies of the field sampling forms are included in
Appendix A. Duke Energy Analytical Laboratory (North Carolina Laboratory
Certification #248) and Pace Analytical Laboratory (North Carolina Laboratory
Certification #40) analyzed the reported parameters and constituents. The laboratory
report and chain -of -custody forms are included in Appendix B.
The samples were analyzed for the list of parameters and constituents outlined in the
WQMP and guidance from the NCDEQ Division of Waste Management, Solid Waste
Section. The monitoring parameters, along with the U.S. Environmental Protection
Agency (USEPA) Solid Waste (SW)-846 analytical methods, 02L standards, and IMACs
are present in Table 2.02B Class C standards are also presented in Table 2.
Groundwater and surface water samples were analyzed for the following constituents
using the EPA methods noted:
• Barium, beryllium, boron, copper, iron, manganese, nickel, and zinc using U.S.
Environmental Protection Agency (USEPA) Solid Waste (SW) Method 60101);
• Antimony, arsenic, cadmium, chromium, cobalt, lead, selenium, silver, thallium,
and vanadium using SW Method 6020B;
• Chloride, fluoride, nitrate, and sulfate using USEPA Method 9056A;
• Mercury using USEPA Method 7470A; and
• Total dissolved solids (TDS) using SM 2540C.
2.2 Regulatory Criteria
For evaluating the semi-annual monitoring data results, comparisons to the following
regulatory criteria are made in the tables and/or text throughout the remainder of the
report:
Regulatory Criteria -Groundwater
• Title 15A NCAC 02L .0202(g) Groundwater Quality Standards (02L)
• Interim Maximum Allowable Concentrations established under 15A NCAC 02L
0202 (IMAC)
January 2022 Page 2-1
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
• Solid Waste Groundwater Protection Standard
Regulatory Criteria -Surface Water
• 15A NCAC 02B .0200 Surface Water and Wetland standards (02B)
2.3 Statement of Work
SynTerra completed the following tasks:
• Collected groundwater, surface water, leachate, and seep samples on September
20 and 21, 2021. This task was completed with Duke personnel.
• Observed groundwater seepage through the drainpipe of the MSE and collected
a sample from DP-4.
• Measured depth -to -groundwater in each of the monitoring wells during the
September 2021 groundwater sampling event. Depth -to -water measurements in
monitoring wells were collected prior to purging and sample collection.
• Reviewed the laboratory analytical results pertaining to the parameters listed in
Table 2. The Electronic Data Deliverable (EDD) provided by Duke Energy was
adapted to conform to the format requirements of the NCDEQ EQUIS EDD
template.
• Compared groundwater analytical results to 02L, IMAC, and historical
concentration ranges. Surface water and seep results were compared with 02B
standards.
• Developed generalized groundwater surface contour maps using groundwater
elevation data supplied by Duke Energy.
• Calculated groundwater flow velocities based on groundwater elevations at
wells perpendicular to groundwater flow.
• Prepared and submitted this Semiannual Water Quality Monitoring Report to
Duke Energy.
January 2022 Page 2-2
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
3.0 RESULTS
3.1 Site Groundwater Flow
Generalized groundwater elevation contours and groundwater flow direction arrows in
the vicinity of the CCR Landfill are shown on Figure 3a for the surficial and transition
flow zones, and Figure 3b for the bedrock flow zone. These contours were developed
by calculating groundwater elevations in each monitoring well using the depth -to -
water -level measurements taken during the September 2021 monitoring event. In
addition, water -level measurements from nearby groundwater monitoring wells
included in other Site groundwater monitoring programs were used. Depth- to -water
measurements and calculated groundwater elevations are presented in Table 3.
Calculated groundwater flow velocities are presented in Table 4. Calculated
groundwater elevations based depth -to -water measurements gauged during the
September 2021 monitoring event indicate groundwater at the Landfill generally flows
to the west and northwest, consistent with historical Site observations.
3.2 Historical Range Data
Newly Installed Landfill Groundwater Monitoring Wells. The WQMP included
collecting four groundwater samples from each new Landfill monitoring well prior to
the Landfill becoming operational (baseline samples). The four baseline monitoring
events occurred between September 2020 and January 2021, with samples collected
from each well approximately once every 30 days. The baseline monitoring included
measuring groundwater field parameters, gauging depth -to -water in the wells, and
analysis of the collected groundwater samples for the list of parameters and
constituents outlined in the WQMP (same parameter list sampled and analyzed for in
the Landfill semi-annual monitoring program). The results of the four baseline
sampling events were submitted in the Groundwater Monitoring Report Baseline Sampling
Events #1 Through #4 — CCR Landfill (Baseline Report) (SynTerra, 2021). For each newly
installed monitoring well, historical ranges of constituent concentrations were
calculated using the analytical results from the four baseline monitoring events.
Existing Wells Incorporated into the Landfill Monitoring Program. Monitoring wells
CB-9, CB-9SL, and CB-9BR existed at the Site prior to Landfill development but are
incorporated into the Landfill monitoring program. These three wells were not sampled
during baseline sampling events for the newly installed wells. Rather, data from these
wells, collected as part of other regulatory sampling programs well in advance of
Landfill operations, was used to satisfy the initial baseline sampling requirements.
Historical concentration ranges for existing wells were established using all available
January 2022 Page 3-1
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
data collected prior to initiation of Landfill operations (November 2012 to January
2021).
3.3 Analytical Results
A summary of the groundwater, surface water, and leachate field data are presented in
Table 3. Table 5 through Table 9 summarize the analytical results and reference
comparisons discussed below. Sample locations are depicted on Figure 2.
Groundwater Results
Field and analytical results for the collected downgradient and background
groundwater samples are presented in Table 5. Groundwater analytical results are
compared with 02L standards or IMAC. Constituent concentrations equal to or greater
than their 02L standard or IMAC are noted in Table 5 by bold font. The laboratory
analytical reports are included as Appendix B. The following constituents were
detected at concentrations greater than or equal to their 02L standard or IMAC from
downgradient wells:
• pH - LMW-2T, LMW-2B, LMW-3B, and LMW-4B
• Cobalt - LMW-4B
• Iron - LMW-4B
• Manganese - LMW-3B and LMW-4B
• Sulfate - LMW-4B
• Total dissolved solids - LMW-413
• Vanadium - LMW-2T and LMW-2B
Note, there were several constituents detected at concentrations greater than (or less
than for pH) or equal to their 02L standard or IMAC from background wells, including:
• pH - CB-9, CB-9SL, CB-9BR, LMW-1S, and LMW-1B
• Iron - LMW-1S
• Manganese - CB-9BR and LMW-1S
• Vanadium - LMW-1S and LMW-1B
A summary of the downgradient groundwater field and analytical results that are equal
to or greater than applicable comparison criteria are presented in Table 6. The pH
measurements in monitoring wells LMW-2T and LMW-4B were less than their
January 2022 Page 3-2
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
historical concentration range minimums. However, the pH results were within
historical concentrations ranges of Landfill background monitoring wells (Table 6). All
other groundwater analytical results greater than their 02L standards/IMACs were
within their historical concentration ranges.
The groundwater concentrations in Table 5, which are identified as being equal to or
greater than the 02L standard/IMAC are attributable to natural variation. No
constituent concentrations greater than their applicable comparative criteria are
attributed to a release from the CCR Landfill.
Surface Water
Field and analytical results for surface water samples are presented in Table 7. The
sample locations are depicted shown on Figure 2. Analytical results for surface water
and seep samples are compared with applicable 02B Class C surface water standards.
Surface water sample LF-SW-1 was not sampled during the September 2021 sampling
event due to dry conditions. Mercury was reported at concentrations greater than the
02B standard at LF-SW-3 and DP-4, and turbidity was measured at a value greater than
the 02B standard at DP-4. Constituent concentrations greater than 02B standards are
noted in Table 7 by bold font.
A summary of surface water analytical results equal to or greater than applicable
comparison criteria is presented in Table 8. The September 2021 monitoring event is the
first sampling event for surface water locations associated with the Landfill. Additional
monitoring and data evaluation are required in order to determine a cause and
significance of concentrations equal to or greater than 02B standards.
Leachate
A leachate sample (LCS-1) was collected from the leachate collection discharge pipe on
the west side of the landfill. Analytical results are presented in Table 9. Leachate
analytical results are not compared to groundwater (02L or IMAC) or surface water
(02B) quality standards and are provided for informational purposes only.
3.4 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the
collection and analysis of two field blanks (one on each day of sampling) to evaluate if
contamination was imparted to the samples by the sample container, preservative, or
other exogenous sources. A field duplicate sample was also collected to estimate
sampling and laboratory precision. The field blanks had detections of mercury, nitrate,
nitrate as N, and vanadium at concentrations above the method detection limit.
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Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
Select samples were diluted, as is normal laboratory practice, to bring samples within
the calibrated range of the analysis. Specifics regarding the samples that were diluted,
including the dilution amount, are reported in the lab report. Additional QA/QC data,
laboratory analyses, and chain -of -custody forms are included in Appendix B.
January 2022 Page 3-4
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Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
4.0 REFERENCES
Geosyntec. (2019). Water Quality Monitoring Plan Revision 2, Asheville Steam Electric Plant
CCR Landfill, October 2019.
Geosyntec. (2021). Operations Plan, Asheville Steam Electric Plant, CCR Landfill (1119-
INDUS) Rev. 2, February 19, 2021.
SynTerra. (2021). Groundwater Monitoring Report Baseline Sampling Events #1 Through #4 —
CCR Landfill, Asheville Steam Electric Plant. April 2021.
January 2022 Page 4-1
Project: 00.0069.34.04

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
FIGURES
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snrro� N I , �• WASTE BOUNDARY
+N.xinram • . A,rfr r ,
l • ` ; DUKE ENERGY PROGRESS
` PROPERTY LINE
♦ % 4e �.
F�orr pt, • • ••, •
ASHEVILLE COMBINED -
7 CYCLE STATION
� 4�l
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE. -
2. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS. - -
3. USGS TOPOGRAPHIC MAP OBTAINED FROM ESRI ONLINE,• -
LAST UPDATED AUGUST 2021.
/s DUKE FIGURE 1
SITE LOCATION MAP
ENERGY BUNCOMBE SEMIANNUAL WATER QUALITY MONITORING REPORT
COUNTY wWsroN-saLEM
PROGRESS ASHEVILLE STEAM ELECTRIC PLANT
ASHEWLIE ARDEN, NORTH CAROLINA
7 CHARLOTTE
� DRAWN BY: B. MCGANN DATE: 12/08
/2021 GRAPHIC SCALE
REVISED BY: C. WYATT DATE: 01/18/2022 i,000 o i,000 z,000
synTerra CHECKED BY: K. FERRI DATE: 01/18/2022
APPROVED BY: B. MCGANN DATE: 01/18/2022 (IN FEET)
WWW.$ nterracor .com PROJECT MANAGER: K. FERRI

L
i� -a t
100.001
LMW-2B
i e
e
` LMW-1 B
LMW-1S
I LANDFILL LIMIT
' A WASTE
L tf gigue.
�i.,a-yard
~A
w ��ww
DUKE
ENERGY
r
PROGRESS DRAWN BY: B. MCGANN DATE: 01/21/2021
REVISED BY: C. WYATT DATE: 01/18/2022
CHECKED BY: K. FERRI DATE: 01/18/2022
DATE: 01/18/2022
APPROVED BY: B. MCGANN
• .� synTena PROJECT MANAGER: K. FERRI DATE: 01/18/2022
www.synterracorp.com
LEGEND
SURFACE WATER SAMPLE LOCATION
LEACHATE SAMPLE LOCATION
0 DRAINPIPE SEEP SAMPLE LOCATION
DOWNGRADIENT MONITORING WELL
BACKGROUND MONITORING WELL
LANDFILL LIMIT OF WASTE
LANDFILL REVIEW BOUNDARY
—• LANDFILL COMPLIANCE BOUNDARY
1110. STREAM (TWT)
WETLANDS (TWT)
NOTES:
1. THE WQMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
IDENTIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE
COLLECTION SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING
SAMPLE COLLECTION.
2. WQMP - WATER QUALITY MONITORING PLAN
3. ALL SAMPLE LOCATIONS AREAPPROXIMATE.
4. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USACE) ON MAY 19, 2016 - JURISDICTIONAL DETERMINATION
SAW 2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF
THE FEATURES.
5. ALL BOUNDARIES ARE APPROXIMATE.
6. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
7. LANDFILL AERIAL SURVEY AND TOPOGRAPHY COLLECTED ON NOVEMBER 30, 2021 BY
WASTE MANAGEMENT. ADDITIONAL AERIAL IMAGERY OBTAINED FROM GOOGLE EARTH
ON DECEMBER 15, 2021. IMAGE DATED JANUARY 28, 2021.
8. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIRS 3200 (NAD83).
LANDFILL REVIEW BOUNDP
(APPROXIMATELY 80' FROM
I LIMIT OF WASTE)
.11l�
GRAPHIC SCALE
75 0 75 150
(IN FEET)
FIGURE 2
SAMPLE LOCATIONS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
ARDEN, NORTH CAROLINA

I
L � _
I�
LMW-2T
2057.16
2 ti�
/ �� ♦ �,
�I
LMW-1 S .
2143.91 r� —
/
- y - ____ -- - - --------
-S,
------ ----
LEGEND
SURFACE WATER SAMPLE LOCATION
LEACHATE SAMPLE LOCATION
O DRAINPIPE SEEP SAMPLE LOCATION
DOWNGRADIENT MONITORING WELL
BACKGROUND MONITORING WELL
GROUNDWATER FLOW DIRECTION L_
—• INFERRED WATER ELEVATION CONTOUR (20' INTERVAL)
LANDFILL LIMIT OF WASTE
LANDFILL REVIEW BOUNDARY
---LANDFILL COMPLIANCE BOUNDARY
)0- STREAM (TWT)
WETLANDS (TWT)
TOPOGRAPHIC CONTOUR (10' INTERVAL)
NOTES
1. THE WQMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
IDENTIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE
COLLECTION SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING SAMPLE
COLLECTION..
2. * - MONITORING WELL PART OF ANOTHER REGULATORY SAMPLE PROGRAM AND USED
FOR GROUNDWATER ELEVATION DATA ONLY.
3. W.E. -WATER ELEVATION (APPROXIMATE).
4. WQMP - WATER QUALITY MONITORING PLAN
5. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
6. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USAGE) ON MAY 19, 2016 - JURISDICTIONAL DETERMINATION SAW
2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF THE
FEATURES.
7. ALL BOUNDARIES ARE APPROXIMATE.
LANDFILL LIMIT
OF WASTE 8. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
I 9. LANDFILLAERIAL SURVEYAND TOPOGRAPHY COLLECTED ON NOVEMBER 30, 2021 BY
_ WASTE MANAGEMENT. ADDITIONAL AERIAL IMAGERY OBTAINED FROM GOGGLE EARTH ON
�+ DECEMBER 15, 2021. IMAGE DATED JANUARY 28, 2021.
10. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
T COORDINATE SYSTEM RIPS 3200 (NAD83).
LANDFILL REVIEW BOUNDARY
I (APPROXIMATELY 80' FROM
LIMIT OF WASTE)
CB-9 I
2145.18 �.
'I
2170� —
/ LANDFILL COMPLIANCE
BOUNDARY (APPROXIMATELY
160' FROM LIMIT OF WASTE) ^
I
DUKE GRAPHIC SCALE FIGURE 3a
75 0 75 150
ENERGY WATER LEVEL MAP
(IN FEET) SURFICIAL AND TRANSITION FLOW ZONES
PROGRESS DRAWN Ely: R.KIEKHAEFER DATe01/21/2021 CCR LANDFILL - SEPTEMBER 2021
REVISED BY: C.DATE: 01/18/2022
CHECKED BY: K.. FERR FERRI DATE: 01/18/2022 SEMIANNUAL WATER QUALITY MONITORING REPORT
APPROVED BY: B.MCGANN DATE: 01/18/2022 ASHEVILLE STEAM ELECTRIC PLANT
symTerra PROJECT MANAGER: K. FERRI DATE: 01/112022
www.synterracorp.com ARDEN, NORTH CAROLINA

I,
LMW-2B �0
2057.57 e`
LMW-3B
2070.22
LMW-1 B,
2147.08 r
- ---- -
t- /--------
- MW-13BR* ...I
^~-~ 2124.43 ,
-fir � 1
LEGEND
■ SURFACE WATER SAMPLE LOCATION
LEACHATE SAMPLE LOCATION
O DRAINPIPE SEEP SAMPLE LOCATION
DOWNGRADIENT MONITORING WELL
BACKGROUND MONITORING WELL
GROUNDWATER FLOW DIRECTION
---• INFERRED WATER ELEVATION CONTOUR (20' INTERVAL)
LANDFILL LIMIT OF WASTE
LANDFILL REVIEW BOUNDARY
--• LANDFILL COMPLIANCE BOUNDARY
STREAM (TWT)
WETLANDS (TWT)
TOPOGRAPHIC CONTOUR (10' INTERVAL)
NOTES:
1. THE WQMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
IDENTIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE COLLECTION
SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING SAMPLE COLLECTION.
—'r
-
2. * - MONITORING WELL PART OF ANOTHER REGULATORY SAMPLE PROGRAM AND USED
FOR GROUNDWATER ELEVATION DATA ONLY.
3. W.E. - WATER ELEVATION (APPROXIMATE).
4. WQMP- WATER QUALITY MONITORING PLAN
---'�
5. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
6. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY CORPS
OF ENGINEERS (USAGE) ON MAY 19, 2016- JURISDICTIONAL DETERMINATION SAW
LANDFILL LIMIT
LANDFILL LIM�
TAYLOR WISEMAN AND TAYLOR(TWT) PERFORMED THE SURVEY OF THE
FEATURES.
FEATURES.
OF WASTE
7. ALL BOUNDARIES ARE APPROXIMATE.
8. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
9. LANDFILL AERIAL SURVEY AND TOPOGRAPHY COLLECTED ON NOVEMBER 30, 2021 BY
WASTE MANAGEMENT. ADDITIONAL AERIAL IMAGERY OBTAINED FROM GOOGLE EARTH ON
DECEMBER 15, 2021. IMAGE DATED JANUARY 28, 2021.
10. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM RIPS 3200 (NAD83).
sa
i
. LANDFILL REVIEW BOUNDARY
(APPROXIMATELY 80' FROM
LIMIT OF WASTE)
i" CB-9BR -- - -- ------
2131.71 _
u LANDFILL COMPLIANCE
so BOUNDARY (APPROXIMATELY
/ 160' FROM LIMIT OF WASTE)d
--�..2170.��� 10/I
I
P
DUKE
ENERGY
PROGRESS
CB-813R* r ` ,
2092.05 y sV/,nTerra
GRAPHIC SCALE
FIGURE 3b
75 0 75 150
WATER LEVEL MAP
(IN FEET)
BEDROCK FLOW ZONE
BY: R. KIEKHAEFER DATE:01/21/2021
CCR LANDFILL - SEPTEMBER 2021
D BY: C. WYATT DATE: 01/18/2022
SEMIANNUAL WATER QUALITY MONITORING REPORT
ED BY: K. FERRI DATE: 01/18/2022
OED BY: B. MCGANN DATE: 01/18/2022
ASHEVILLE STEAM ELECTRIC PLANT
;T MANAGER: K. FERRI DATE: 01/18/2022
ARDEN, NORTH CAROLINA
www.synterracorp.com

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
TABLES
410
synTerra
Science & Engineering Consultants

TABLE 1
WELL CONSTRUCTION SUMMARY
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Screened
Measuring
Ground
Groundwater
Depth to
Date
Diameter
Latitude
Longitude
Well Depth
Well ID
Flow Zone
Material
Interval
Point TOC
Surface
Elevation
Water
Installed
(Inches)
(degrees)
(degrees)
(Ft, BTOC)
(Ft, BGS)
(Ft, NAVD 88)
(Ft, NAVD 88)
(Ft NAVD 88)
(Ft BTOC)
CB-9*
10/8/2012
Surficial
PVC
2
35.4720450
-82.5467520
65.60
52-62
2182.08
2178.86
2145.18
36.90
CB-9BR*
4/21/2015
Bedrock
PVC
2
35.4720311
-82.5467707
97.85
83-93
2181.11
2178.15
2131.71
49.40
CB-9SL*
4/21/2015
Saprolite
PVC
2
35.4720577
-82.5467646
78.10
69-74
2181.42
2178.17
2145.47
35.95
LMW-1B*
9/11/2020
Bedrock
PVC
2
35.4732130
-82.5469693
103.20
91-101
2169.67
2169.53
2147.08
22.59
LMW-lS*
8/31/2020
Surficial
PVC
2
35.4731733
-82.5469538
66.60
55-65
2169.73
2169.58
2143.91
25.82
LMW-2B
9/11/2020
Bedrock
PVC
2
35.4740577
-82.5491559
110.30
100.5-110.5
2121.16
2120.84
2057.57
63.59
LMW-2T
9/11/2020
Transition
PVC
2
35.4741121
-82.5491312
87.00
76-86
2123.11
2123.20
2057.16
64.00
LMW-3B
9/11/2020
Bedrock
PVC
2
35.4734715
-82.5496049
45.30
33-43
2102.89
2102.80
2070.22
32.67
LMW-4B
9/11/2020
Bedrock
PVC
2
35.4729336
-82.5506071
49.25
39-49
2102.67
2102.57
2081.48
21.19
Notes•
* - Indicates background groundwater monitoring well.
Groundwater elevations are based on data collected during the September 2021 sampling event.
BGS - Below ground surface
BTOC - Below top of casing
CCR - Coal combustion residual
Ft - feet
NAD 83 - Horizontal coordinates based on the North American Datum of 1983.
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988.
NM - not measured
PVC - polyvinylchloride
TOC - Top of casing
Prepared by: JHC Checked by: KHF
Page 1of1

TABLE 2
GROUNDWATER, SURFACE WATER, AND LEACHATE
MONITORING PARAMETERS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Field Parameters
Analytical Methods
Units
15A NCAC
1
02L Standard
15A NCAC 02B
(Class C)
pH
Multi -Parameter Water Quality Meter
S.U.
6.5-8.5
6.0-9.0
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
NE
:529
Specific Conductance
Multi -Parameter Water Quality Meter
pmhos/cm
NE
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
NE
>_4
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
millivolts
NE
NE
Turbidity
Turbidimeter
NTU
NE
1550
Water Level
Water Level Meter
ft
NE
NE
Laboratory Parameters
Analytical Methods
Units
15A NCAC
i
02L Standard
15A NCAC 02B
2
(Class C)
Antimony
EPA 200.8/EPA 6020E
pg/L
1*
NE
Arsenic
EPA 200.8/EPA 6020B
pg/L
10
NE
Barium
EPA 200.7/EPA 6010D
pg/L
700
NE
Beryllium
EPA 200.7/EPA 6010D
pg/L
4*
NE
Boron
EPA 200.7/EPA 6010D
pg/L
700
NE
Cadmium
EPA 200.8/EPA 6020B
pg/L
2
NE
Chloride
EPA 300.0/EPA 9056A
mg/L
250
230
Chromium
EPA 200.8/EPA 6020B
pg/L
10
NE
Cobalt
EPA 200.8/EPA 6020B
pg/L
1*
NE
Copper
EPA 200.7/EPA 6010D
pg/L
1000
NE
Fluoride
EPA 300.0/EPA 9056A
mg/L
2
1.8
Iron
EPA 200.7/EPA 6010D
pg/L
300
NE
Lead
EPA 200.8/EPA 6020B
pg/L
15
NE
Manganese
EPA 200.7/EPA 6010D
pg/L
50
NE
Mercury
EPA 7470A
pg/L
1
0.012
Nickel
EPA 200.7/EPA 6010D
pg/L
100
NE
Nitrate
EPA 300.0/EPA 9056A
mg-N/L
10
NE
Selenium
EPA 200.8/EPA 6020B
pg/L
20
5
Silver
EPA 200.8/EPA 6020E
pg/L
20
NE
Sulfate
EPA 300.0/EPA 9056A
mg/L
250
NE
Thallium
EPA 200.8/EPA 6020E
pg/L
0.2*
NE
Total Dissolved Solids
SM 2540C
mg/L
500
NE
Vanadium
EPA 200.8/EPA 6020B
pg/L
0.3*
NE
Zinc
EPA 200.7/EPA 6010D
pg/L
1000
NE
Preparea by: KHr unecKea by: I( N
Notes:
1 - 15A NCAC 02L Standards for groundwater - North Carolina groundwater quality standards (effective April 1, 2013).
z 15A NCAC 02B Standards for Class C surface water - North Carolina surface water and wetland standards (effective November 1, 2
* - Interim Maximum Allowable Concentrations (IMAC) established under 15A NCAC 02L .0202.
Ng/L - micrograms per liter
pmhos/cm - micromhos per centimeter
EPA - US Environmental Protection Agency
ft- feet
mg/L - milligrams per liter
mV - millivolts
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
Page 1 of 1

TABLE 3
FIELD DATA PARAMETERS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Sample ID
Sample Date
Appearance
Odor
Purge Method
Average Pump
Rate
(mL/min)
Temp
(Deg C)
Specific
Conductance
(Nmhos/cm)
pH
(S.U.)
ORP
(mV)
Dissolved Oxygen
(mg/L)
Turbidity
(NTU)
Groundwater
Elevation
(Ft NAVD 88)
Depth to
Water
(Ft BTOC)
Groundwater Parameters
C13-9
09/21/2021
Clear
None
Low flow
180
17
32
4.5
392
2.87
1.5
2145.18
36.90
CB-9BR
09/21/2021
Clear
None
Low flow
300
17
94
5.7
348
0.61
1.3
2131.71
49.40
CB-9SL
09/21/2021
Clear
None
Low flow
80
18
54
5.2
361
3.41
0.9
2145.47
35.95
LMW-1B
09/21/2021
Clear
None
Low flow
220
16
115
6.0
322
0.94
2.0
2147.08
22.59
LMW-1S
09/21/2021
Clear
None
Low flow
280
16
65
5.3
373
1.52
8.9
2143.91
25.82
LMW-213
09/21/2021
Clear
None
Low flow
300
18
72
5.3
248
1.52
4.4
2057.57
63.59
LMW-2T
09/21/2021
Clear
None
Low flow
180
19
65
5.1
347
1.66
2.1
2057.16
64.00
LMW-313
09/20/2021
Clear
None
Low flow
120
17
306
6.2
330
2.54
4.0
2070.22
32.67
LMW-413
09/20/2021
Clear
None
Low flow
300
16
616
6.1
186
0.30
3.2
2081.48
21.19
Surface Water Parameters
LF-SW-2*
09/20/2021
clear
None
NA
NA
19
90
6.5
366
8.03
4.1
NA
NA
LF-SW-3*
09/20/2021
clear
None
NA
NA
21
61
6.6
409
8.04
2.8
NA
NA
DP-4
9/21/2021
Cloudy
None
NA
NA
24
1266
6.8
384
8.75
63.5
NA
NA
Leachate Collection Parameters
LCS-1**
1 09/21/2021
clear
None
NA
NA
17
1455
5.8
398
7.46
2.2
NA
NA
Notes:
Water level data collected September 20 & 21, 2021.
- The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised to differentiate between other Site monitoring program surface water locations.
** - The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sampling collection.
Surface water sample location LF-SW-1` was not sampled due to dry conditions.
pmhos/cm - micromhos per centimeter
BTOC - Below top of casing
Deg C - degrees Celsius
ft - feet
mg/L - milligrams per liter
mL/min - milliliters per minute
mV - millivolts
NA - not applicable
NAVD88 - North American Vertical Datum of 1988
NTU - nephelometric turbidity units
ORP - oxidation reduction potential
S.U. - standard units
WQMP - Water Quality Monitoring Plan
Prepared by: TAH Checked by: TCP
Page 1 of 1

kr_1a44E,I
GROUNDWATER SEEPAGE VELOCITIES
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Surficial and Transition Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Ah
Distance
Effective Porosity
Velocity
Elevation
Elevation
(ft/day)l
(ft)
(ft)
(Ft NAVD 88)
(Ft NAVD 88)
(ft/day)
CB-9SL to LMW-2T
2145.47
j 2057.16
j 0.26
j 88.31
j 1027
j 0.20
0.112
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Ah
Distance
Effective Porosity
Velocity
Elevation
Elevation
(ft/day)l
(ft)
(ft)
Z
(Ft NAVD 88)
(Ft NAVD 88)
(ft/day)
LMW-1B to LMW-2B
2147.08
2057.57
2.17
89.51
720
0.001
269.8
CB-9BR to LMW-3B
2131.71
2070.22
1.53
61.49
993
0.001
94.7
Prepared By: TAH Checked By: RSB
Notes:
1 - Values used are a calculated Geomean of hydraulic conductivities in paired wells. Hydraulic conductivity values are derived from slug test data presented in the
Groundwater Monitoring Well Installation Report (SynTerra, April 2021).
z - Value represents an estimate of the velocity of groundwater through bedrock fractures.
Groundwater elevations are based on water level data collected in September 2021.
Monitoring wells are not listed where groundwater contour information is unavailable to calculate velocity.
Hydraulic gradients and groundwater velocities are approximate.
Effective porosity taken from the Updated Groundwater Flow and Transport Modeling Report for Asheville Steam Electric Plant, Arden, NC - May 30, 2017.
ft - feet
ft/day - feet per day
NAVD 88 - North American Vertical Datum 1988
Page 1 of 1

TABLE 5
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Monitoring Wells
MDL
SW GWPS
15A NCAC 02L
Standard
CB-9
CB-9BR
CB-9SL
LMW-1B
LMW-1S
LMW-2B
LMW-2T
LMW-3B
LMW-4B
pH
320
S.U.
4.5
5.7
5.2
6.0
5.3
5.3
5.1
6.2
6.1
NE
6.5-8.5
Temperature
325
Deg C
17
17
18
16
16
18
19
17
16
NE
NE
Specific Conductance
323
pmhos/cm
32
94
54
115
65
72
65
306
616
NE
NE
Dissolved Oxygen
-
mg/L
2.87
0.61
3.41
0.94
1.52
1.52
1.66
2.54
0.30
NE
NE
Oxidation Reduction
Potential
336
mV
392
348
361
322
373
248
347
330
186
NE
NE
Eh
-
mV
597
553
566
527
578
453
552
535
391
NE
NE
Turbidity
330
NTUs
1.5
1.3
0.9
2.0
8.9
4.4
2.1
4.0
3.2
-
NE
NE
Antimony
13
pg/L
<1
<1
<1
<1
<1
0.127 j
<1
<1
<1
0.104
NE
1.
Arsenic
14
pg/L
<1
<1
<1
<1
<1
<1
<1
<1
0.353 j
0.111
NE
10
Barium
15
ug/L
27
25
40
26
42
43
34
38
20
2
NE
700
Beryllium
23
ug/L
<5
<5
<5
<5
<5
<5
<5
<5
<5
2
NE
4`
Boron
428
ug/L
<50
<50
<50
<50
<50
12j
25j
16j
56
5
NE
700
Cadmium
34
pg/L
<1
<1
<1
<1
<1
<1
0.062 j
<1
<1
0.032
NE
2
Chloride
301
mg/L
6.6
7.6
7.7
7.9
6.3
8
10
3.1
9.1
0.0154
NE
250
Chromium
51
pg/L
0.231 j
<1
0.559 j
0.225 j
0.488 j
0.716 j
<1
<1
<1
0.185
NE
10
Cobalt
53
ug/L
0.882 j
<1
<1
<1
1.25
0.096 j
0.755 j
0.702 j
53.3
0.077
NE
1`
Copper
54
pg/L
<5
<5
<5
<5
<5
<5
<5
4 j
<5
1
NE
1,000
Fluoride
312
mg/L
<0.1
0.05 j
<0.1
<0.1
<0.1
<0.1
<0.1
0.05 j
0.47 j
0.0479
NE
2
Iron
340
ug/L
79
69
8j
33 S1
481
127
63
80
19500
4
NE
300
Lead
131
pg/L
<1
<1
0.096 j
0.047 j
0.158 j
0.081 j
0.088 j
0.081 j
0.116 j
0.037
NE
15
Manganese
342
Ng/L
33
53
<5
3j
141
8
28
286
9170
1
NE
50
Mercury
132
pg/L
<0.05
<0.05
<0.05
0.04 j,S1
<0.05
<0.05
<0.05
0.03 j,S1
0.04 j,S1
0.01
NE
1
Nickel
152
pg/L
<5
<5
<5
<5
<5
<5
<5
4 j
20
1
NE
100
Nitrate (as N)
303
mg-N/L
0.24
0.05
0.2
0.03 S1
0.39
0.23
0.59
0.53
0.78
0.002
NE
10
Selenium
183
pg/L
<1
<1
<1
<1
<1
<1
<1
<1
<1
0.193
NE
20
Silver
184
pg/L
0.084 j
0.063 j
0.395 j
<1
0.047 j
0.104 j
<1
<1
0.041 j
0.035
NE
20
Sulfate
315
mg/L
0.1
1.5
0.26
0.3
0.33
3.2
4.8
94
250
0.0428
NE
250
Thallium
194
pg/L
0.069 j
<0.2
<0.2
<0.2
0.046 j
<0.2
<0.2
<0.2
<0.2
0.041
NE
0.2*
Total Dissolved Solids
311
mg/L
<25
81
53
86. S1
36
53
28
211
501
25
NE
500
Vanadium
209
ug/L
0.246 j,Sl
0.257 j,SI
0.285 j,S1
0.428 S1
0.541 S1
0.776 S1
0.356 S1
0.27 j
<0.3
0.114
NE
0.3*
Zinc
213
ug/L
8
<5
<5
<5
5
<5
<5
<5
<5
4
NE
1,000
Notes:
Bold concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH bold indicates a measurement less than or greater than the indicated range).
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2013 (Appendix I amended April 1, 2013).
CB-9/BR/SL and LMW-1B/S are background groundwater monitoring wells.
* Interim Maximum Allowable Concentration (IMAC).
Samples collected by SynTerra and Duke personnel on September 20 and 21, 2021.
A blank cell means there is no relevant information.
°C - degrees Celsius
I - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
mV - millivolts
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
NCAC - North Carolina Administrative Code
NE - not established
S.U. - standard units
Sl - Data review findings indicate result may be biased, however data is usable.
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
pmhos/cm - micromhos per centimeter
U - Analyte was analyzed for, but not detected above the MDL. MDL may be higher than value shown due to sample dilution by laboratory.
< - Concentration not detected at or greater than the adjusted reporting limit.
Prepared by KHF Checked by: TCP
Page 1 of 1

TABLE 6
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED GROUNDWATER QUALITY STANDARDS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Historical
Parameter
Sample ID
September 2021
Units
15A NCAC 02L
Concentration
Cause and Significance
Concentration
Standard
Range`
Natural variation, within historical
LMW-2B
5.3
S.U.
6.5 - 8.5
5.3 - 5.8
concentration range.
Natural variation, within historical
concentration ranges of background
LMW-2T
5.1
S.U.
6.5 - 8.5
5.3 - 5.6
monitoring wells (CB-9SL: 4.6 -
5.8)�.
pH
Natural variation, within historical
LMW-3B
6.2
S.U.
6.5 - 8.5
5.5 - 6.4
concentration range.
Natural variation, within historical
concentration ranges of background
LMW-4B
6.1
S.U.
6.5 - 8.5
6.4 - 6.6
monitoring wells (CB-9BR and LMW-
113: 4.9 - 6.5)^.
Cobalt
LMW-4B
53.3
pg/L
1
56.7 - 75.6
Natural variation, less than
historical concentration range.
Iron
LMW-4B
19,500
pg/L
300
20,800 - 27,400
Natural variation, less than
historical concentration range.
Natural variation, less than
LMW-3B
286
299 - 774
historical concentration range.
Manganese
ug/L
50
Natural variation, less than
LMW-4B
9,170
10,000 - 13,800
historical concentration range.
Sulfate
LMW-4B
250
mg/L
250
260 - 360
Natural variation, less than
historical concentration range.
Total Dissolved
LMW-4B
501
mg/L
500
499 - 696
Natural variation, within historical
Solids
concentration range.
LMW-2B
0.776 S1
ug/L
0.3
0.557 - 0.969
Natural variation, within historical
concentration range.
Vanadium
LMW-2T
0.356 S1
pg/L
0.3
0.192 - 1.81
Natural variation, within historical
concentration range.
Prepared by: BNM/KHF Checked by: RSB
Notes:
- Historical ranges for monitoring wells installed in 2020, are based on data from the four baseline monitoring events that occurred between September 2020 and
January 2021, prior to waste placement in the CCR Landfill.
^ - Historical concentration ranges for CB-9SL and CB-913R are based on all available data collected from November 2012 to January 2021, prior to
waste placement in the CCR Landfill.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2013.
pg/L - micrograms per liter
mg/L - milligrams per liter
S1 - Data review findings indicate result may be biased, however data is usable.
S.U. - standard units
Page 1 of 1

TABLE 7
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Surface Water Sample ID
MDL
15A NCAC 02B
(Class C)
(Class
LF-SW-2'
LF-SW-3'
DP-4
pH
320
S.U.
6.5
6.6
6.8
-
6.0-9.0
Temperature
325
Deg C
19
21
24
-
<_29
Specific Conductance
323
pmhos/cm
90
61
1,266
-
NE
Dissolved Oxygen
-
mg/L
8.03
8.04
8.75
-
>_4
Oxidation Reduction
Potential
336
mV
366
409
384
-
NE
Eh
-
mV
571
614
589
-
NE
Turbidity
330
NTUs
j 4.1
2.8
63.5
-
:550
Antimony
13
pg/L
<1
<1
<1
0.104
NE
Arsenic
14
pg/L
<1
<1
0.186 j
0.111
NE
Barium
15
pg/L
18
16
29
2
NE
Beryllium
23
pg/L
<5
<5
<5
2
NE
Boron
428
pg/L
22 j
22 j
<50
5
NE
Cadmium
34
pg/L
0.145 j
<1
<1
0.032
NE
Chloride
301
mg/L
8.7
9.8
3.8
0.0154
230
Chromium
51
pg/L
<1
<1
<1
0.185
NE
Cobalt
53
pg/L
0.398j
0.147j
1.63
0.077
NE
Copper
54
pg/L
<5
<5
<5
1
NE
Fluoride
312
mg/L
0.06 j
<0.1
0.29
0.0479
1.8
Iron
340
pg/L
413
135
667
4
NE
Lead
131
pg/L
0.054j
0.055j
0.09j
0.037
NE
Manganese
342
pg/L
278
17
261
1
NE
Mercury
132
pg/L
<0.05
0.09 S1
0.08 S1
0.01
0.012
Nickel
152
pg/L
<5
<5
<5
1
NE
Nitrate (as Nitrogen)
303
mg-N/L
0.08 S1
0.13
0.16
0.002
NE
Selenium
183
pg/L
<1
<1
<1
0.193
5
Silver
184
pg/L
<1
<1
<1
0.035
NE
Sulfate
315
mg/L
12
4.3
780
0.0428
NE
Thallium
194
pg/L
<0.2
<0.2
<0.2
0.041
NE
Total Dissolved Solids
311
mg/L
62
40
1,180
25
NE
Vanadium
209
pg/L
<0.3
0.257j
0.262j
0.114
NE
Zinc
213
pg/L
<5
<5
<5
4
NE
Prepared by: KHF Checked by: TCP JPC
Notes:
Bold concentrations are equal to or greater than the 15A NCAC 02B Standards for Class C surface waters (for pH, bold indicates a measurement less
than or greater than the indicated range).
' - The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised in order to differentiate between other Site
monitoring program surface water locations.
Z - 15A NCAC 02B Standards for Class C surface waters - North Carolina surface water and wetland standards (effective November 1, 2019).
Samples collected by SynTerra and Duke personnel on September 20, 2021.
Surface water sample location LF-SW-1' was not sampled due to dry conditions.
- - No relevant information.
< - Concentration not detected at or greater than the adjusted reporting limit.
°C - degrees Celsius
EPA - Environmental Protection Agency
J - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
MDL - Laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
NA - not analyzed
NE - not established
NTU - nephelometric turbidity unit
S1 - Data review findings indicate result may be biased, however data is usable.
S.U. - standard units
pmhos/cm - micromhos per centimeter
pg/L - micrograms per liter
mV - millivolts
SWS ID - Solid Waste Section Identification Number
WQMP - Water Quality Monitoring Plan
Page 1 of 1

TABLE 8
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED SURFACE WATER QUALITY STANDARDS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
September 2021
15A NCAC 02B
Historical
Parameter
Sample ID
Concentration
Units
Standard
Concentration
Cause and Significance
(Class C)
Range
Turbidity
DP-4
63.5
NTUs
50
NA
DP-4 has only been sampled one time, therefore cause and
significance cannot be determined.
LF-SW-3*
0.09
pg/L
0.012
NA
LF-SW-3 has only been sampled one time, therefore cause and
significance cannot be determined.
Mercury
DP-4
0.08
pg/L
0.012
NA
DP-4 has only been sampled one time, therefore cause and
significance cannot be determined.
Prepared by: KHF Checked by: BNM
Notes:
- The WQMP identifies the surface water sample as SW-3. Identification was revised in order to differentiate between other Site monitoring program surface water locations with the same IDs as those in
the WQMP.
15A NCAC 02B Standards for Class C surface waters - North Carolina surface water and wetland standards (effective November 1, 2019).
NA - not applicable
pg/L - micrograms per liter
NCAC - North Carolina Administrative Code
NTU - nephelometric turbidity unit
WQMP - Water Quality Monitoring Plan
Page 1 of 1

TABLE 9
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
CCR LANDFILL
SEMIANNUAL WATER QUALITY MONITORING REPORT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Leachate Collection Sample
MDL
LCS-1*
pH
320
S.U.
5.8
-
Specific Conductance
323
Nmhos/cm
1,455
-
Temperature
325
Deg C
17
-
Dissolved Oxygen
-
mg/L
7.46
-
Oxidation Reduction
Potential
336
mV
398
-
Eh
-
mV
603
-
Turbidity
330
NTUs
2.2
-
Antimony
13
Ng/L
1.87
0.104
Arsenic
14
pg/L
2.36
0.111
Barium
15
pg/L
53
2
Beryllium
23
pg/L
<5
2
Boron
428
Ng/L
9,650
5
Cadmium
34
pg/L
0.355 j
0.032
Chloride
301
mg/L
30
0.0154
Chromium
51
Ng/L
0.232 j
0.185
Cobalt
53
pg/L
0.715 j
0.077
Copper
54
Ng/L
<5
1
Fluoride
312
mg/L
1.1 j
0.0479
Iron
340
pg/L
25
4
Lead
131
pg/L
0.119j
0.037
Manganese
342
pg/L
1,600
1
Mercury
132
pg/L
<0.05
0.01
Nickel
152
pg/L
3 j
1
Nitrate (as N)
303
mg-N/L
0.22 j
0.002
Selenium
183
Ng/L
204
0.193
Silver
184
pg/L
<1
0.035
Sulfate
315
mg/L
740
0.0428
Thallium
194
pg/L
0.099 j
0.041
Total Dissolved Solids
311
mg/L
1,350
25
Vanadium
209
pg/L
1.72 S1
0.114
Zinc
213
pg/L
14
4
Prepared by: KHF Checked by: TCP
Notes:
Sample collected by SynTerra and Duke personnel on September 21, 2021.
Comparative criteria are not applied to leachate collection samples.
The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sampling collection.
A blank cell means there is no relevant information.
< - Concentration not detected at or greater than the adjusted reporting limit.
°C - degrees Celsius
I - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
MDL - Laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg N/L - milligrams nitrogen per liter
mV - millivolts
NE - not established
NTU - nephelometric turbidity unit
S1 - Data review findings indicate result may be biased, however data is usable.
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
Nmhos/cm - micromhos per centimeter
Ng/L - micrograms per liter
WQMP - Water Quality Monitoring Plan
Page 1 of 1

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
410
synTerra
Science & Engineering Consultants

CAMA CCR --Landfill NPDES DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG
Site: A4xtlk Well/SW ID: 94-1 Date: ?:Mzi
DUKE
ENERGY
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: (_)L- WEATHER: [-]SUNNY ❑PARTLY CLOUDY ❑OVERCAST EnRAIN SNOW AIR TEMP: 7V -F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL M 743 ?�
❑ OTHER: TURBIDIMETER TYPE? SERIAL M `,3!2
START PURGE TIME: SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH: - (ft) DEPTH TO WATER: (ft) MULT FACTOR 0.163 ('(radiuS112)2.3 14*748]
WELL DIAMETER: (in) HEIGHT OF WC: (h) WELL VOLUME: (gal)
WELL DEPTH: — (ft) TOTAL VOLUME PURGED: - (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( ]
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
A
a
Low Flaw Sampling Stabilization Criteria
D�� K$E� pH t 0.1 standard unit
- Speck Conductance i 50% In NSfem
• DO t 0 2 mg11
• Turbidity less than 10 NTUe
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
°
(C}
(x)
(mglL)
(x.xx)
(tr5lcm)
[x}
(Su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? []YES❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO rS THE LOCATION FIELD VEHICLE ACCESSIBLE? DYES ❑/ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%u? ❑ YES ❑NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1-12S Petroleum Earthy Musly Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Clwdy Turbid Redllion Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12117/201 S RDP

nCAMA ❑CCR [-- Landfill
Site: Ashevcl -
NPDES DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG
WeII/SW ID: SW-Z
Date: ,
� DUKE
ENERGY
El GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO [:]WELL DEVELOPMENT
FIELD STAFF: 6-7Z WEATHER: []SUNNY [:]PARTLYCLOUDY QOVERCAST []RAIN []SNOW AIR TEMP:—Zj •F
COMPANY: ❑` DUKE ENERGY FIELD METER TYPE/ SERIAL #: 7435J4
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 33"
START PURGE TIME: 1151 SAMPLE COLLECTION TIME: IZr)
PUMPITUBING INTAKE DEPTH: ^ 00 DEPTH TO WATER: — (n) MOLT FACTOR 0.163 ('(radius112)2'3 14'7.481
WELL DIAMETER: (in) HEIGHT OF WC: (h) WELL VOLUME: (gal)
WELL DEPTH: — 00 TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other { )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
a
IP„I c.�� tieG1 Low Flow Sampling Stabilization Criteria
• pH t 0 1 standard unit
• Speck Conductance t 50/6 In NS1cm
• DO t 0.2 mg/I.
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
CC)
(x)
(mg1L)
(x.xx)
(NSICm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
17.001
sty►
-
U
7•a
6%
C. fo
37T
4.9
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
8
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? EIYES [:]NO
1S A TURBIDITY METER DUPLICATE REQUIRED?
❑YES
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑YES V] NO
IS THE TURBIDITY METER DUPLICATE. TAKEN, WITHIN 15%?
❑ YES []NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
pie
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
pi.
Minor Strong
ADDITIONAL NOTES: APPEARANCE
46�`
Cloudy Turbid RediIron Film on Surface Sheen ins Flue
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
* LQLGK Version 1.0 Revised 12/17/201 B RDP

CAMA OCCR —Landfill 7,NPDES
DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG
Site: khzX& Well/SW ID: 5w-3 Date: %zv-zr
DUKE
ENERGY
DGROUNDWATER SAMPLE❑SURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 07, WEATHER: []SUNNY ❑PARTLYCLOUDY [)OVERCAST QRAIN FISNOW AIRTEMP: 7K -F
COMPANY: 0 DUKE ENERGY FIELD METER TYPEI SERIAL #: 76 71
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3321
START PURGE TIME: /lg SAMPLE COLLECTION TIME: 1321
PUMP/TUBING INTAKE DEPTH: — (h) DEPTH TO WATER: 01) MULT FACTOR "• 0.163 [yradtusJ12[2'314'7.48l
WELL DIAMETER: (in) HEIGHT OF WC: (fit WELL VOLUME: — (gal)
WELL DEPTH: 011) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( )
PURGE METHOD:
i
SAMPLING METHOD:
PUMP SETTING:
P
cr.,o Is�l r.�I Low Flow Sampling Stabilization Criteria
PH :k (1.1 standard unit
Specific Conductance = 5% in pSfcm
00 t 0 2 mgit
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
(rnUmin)
W
(gallons OR mL)
(x.xx)
(°C)
(x)
(mgll)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
1311
Shan
a zz
1j.dL_
C1
6.5Fr
-Ian
3.5,
1120
2(
a k
6 r
G i6 Z
'fo `t
fa 2-16
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? EYES NO
[:)NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
[]YES
8
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
15%?
❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
t( ne
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
I phe
Mir -or Strong
ADDITIONAL NOTES: APPEARANCE
le r
Cloudy Turbid Redliron Film on Surface Sheen 45� Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
i! CI'E6K Version 1.0 Revised 12/17/2018 RDP

CAMA CCR , Landfill NPDES DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG
Site: k wll►k Weil/SW ID: Lc5-1
Date: 1-2 j -zl
DUKE
ENERGY
GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: &P - WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST QRAIN SNOW AIR TEMP: 68 •F
COMPANY: 0 DUKE ENERGY FIELD METER. TYPE/ SERIAL M 76 5574
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3 3L`1
START PURGE TIME: 0647 SAMPLE COLLECTION TIME: 01550
PUMPITUBING INTAKE DEPTH: Ih) DEPTH TO WATER: IS) MULT FACTOR ": 0.163 ['(r0dius112)2'3 ia'7 aa]
WELL DIAMETER: — (in) HEIGHT OF WC: — (h) WELL VOLUME: — (ga )
WELL DEPTH: — (h) TOTAL VOLUME PURGED: ^' d sO (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
iP,,, Isal i.al Low Flow Sampling Stabilization Criteria
PH : 0 1 standard unit
• Specific Conductance : 5% in NS cm
• DO t 0 2 mg.+1
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mLlmin)
(x)
(gallons OR mL)
(x.xx)
VC)
(X)
(mg1L)
(x.xx)
(NSIcm)
W
(su)
(x.xx)
(mV)
(x)
(NTU)
(X.X)
48'I$
-
-
0.25
Is
19.111
1250
`i•86
166
-
0144
17
7•4t,
1455
5.76
1 39fs
Z. Z.
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
NO
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? A[:]NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑YES
LJ
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? [YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%?
[:]YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
496
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
t a
Minor Strong
ADDITIONAL NOTES: APPEARANCE
Oar
Cloudy Turbid Red/lion Film an Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

CAMA CCR ELandfll RNPDES ❑ DGW ASW LRB SPECIAL STUDY
Site: A56cwlte
FIELD SAMPLING LOG
Well/SW ID: bP-`I
•�� DUKE
ENERGY
Date: q-2-0 -z1
GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: LSL WEATHER: []SUNNY ❑PARTLY CLOUDY ❑OVERCAST QRAIN SNOW AIR TEMP: 72 •F
COMPANY: Q DUKE ENERGY FIELD METER TYPE! SERIAL #:. 763 74 _
❑ OTHER: TURBIDIMETER TYPE! SERIAL M 3314
START PURGE TIME: 1339 SAMPLE COLLECTION TIME: f 3 Ko
PUMP/TUBING INTAKE DEPTH: 00 DEPTH TO WATER: (tt) MULT FACTOR'' 0.163 ['(radius112)2'31a•7.a8j
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: — (gal)
WELL DEPTH: (f) TOTAL VOLUME PURGED: 0.05 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other { bFX0 )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
a
n
Low Flow Sampling Stabilization, Criteria
• pH t 0 1 standard unit
• Speck Conductance = 510 In NS.cm
• DO f 0 2 mg-1
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
{FT)
(x.xx)
(mLlmin)
{x)
(gallons OR mL)
{x.xx)
{"C}
{x)
(mglL)
(x.xx)
(NSlcm)
{x)
(su)
(x.xx)
(mv)
{xJ
(NTU)
(x.x)
133
-
o•a 5
-
2K
S.?S
1166
6.83
3V
6 3. 5
k'LkASt Ktl'EK TU THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES 21 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? /❑YES ❑NO
IS A TURBIDITY METER DUPLICATE REQUIRED? [-]YES J±j NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? /❑YES ® NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES [:]NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR I o9i H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH I&e Minor Strong
ADDITIONAL NOTES. APPEARANCE Clear Cl&y Turbid Redllron Film on Surface Sheen Fines C:9F
WELL TAG PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/201 S RDP

CAMA , CCR -Landfill NPDES DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG tom, DUKE
44- ENERGY
Site: As6&vNew Well/SW ID: ijW, 10 Date: y-zr-2t
GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO [:]WELL DEVELOPMENT
FIELD STAFF: 01- WEATHER: []SUNNY ❑PARTLY CLOUDY ❑OVERCAST QRAIN []SNOW AIR TEMP: 6S F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL #: 74 352k
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M M1
START PURGE TIME: _t5rt15 SAMPLE COLLECTION TIME: 093r>
PUMPITUBING INTAKE DEPTH: Q 6 DEPTH TO WATER: 21. 6 9 (n) MULT FACTOR 0.163 1'(radiUsJ12)2'3 14'7.4aj
WELL DIAMETER: Z. (in) HEIGHT OF WC: SO. 61 (h) WELL VOLUME: t3.1`t (gal)
WELL DEPTH: �b3, 2 (h) TOTAL VOLUME PURGED: I.35 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other { }
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
A
p
cam) 1S.Gl JIM) Low Flow Sampling Stabilization Criteria
l r pH f 0.1 standard unit
Speck Conductance t 5% in NSicm
• DO t 0.2 mgrt
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE V5
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUrnin)
{x}
(gallons OR mL)
(x.xx)
VC)
{x}
(mg/L)
(x.xx)
(NS/cm)
{x)
(su)
(x.xx)
(mV)
(x)
(NTU)
(x.x)
61117
W 23.
220
0.35
(
SAI
014 t 13
t .
06
a
2.3.10
22w
o.6b
!L
I -to
U5
447-
3co
I.o
41113
'Z3 to
VZO
.t5
tb
1.61
1114
4.11111
5.5
012
.IL7
Ztu
1.10
0.4L
1%_5
9
3Zo
1.7
6j2d
2 3. to
; Z0
l r T 35
Ito
o •9
Its
5.97
2
2-0
PLEASE REFER TO THE BACK OF TH15 5HEET IF THE CHANT ABOVE l5 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:)YES ~ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES — NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? DYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES [:]NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR 18.9e H2S Petroleum Earthy Musty Undetermined
�1,
ODOR STRENGTH vveMinor Strong
ADDITIONAL NOTES: APPEARANCE r&r Cloudy Turbid Redfiron Film on Surface Sheen Fines Floc
WELL_ TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 1211712018 RDP
to It

wV1
CAMA - CCR.. Landfill NPDES ]DGW❑ASW OLRB
SPECIAL STUDY
FIELD SAMPLING LOG
Site: 44wk Well/SW ID: i Ntw- )s Date: q-?,I-,zi
ifft, DUKE
ii� ` ENERGY
El GROUNDWATER SAMPLE❑SURFACE WATER SAMPLE❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
Gd
FIELD STAFF: ti WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST QRAIN []SNOW AIR TEMP: 19 'F
COMPANY: O DUKE ENERGY FIELD METER TYPE/ SERIAL M 7�t iK
❑ OTHER: TURBIDIMETER TYPEI SERIAL M _ 132011
START PURGE TIME: ~ r74SM SAMPLE COLLECTION TIME: -AOO
PUMPfTUBING INTAKE DEPTH: r15
00 DEPTH TO WATER: Z-541 M) MULT FACTOR ": 0.163 ['{radu5112}2'3 14'7,48[
WELL DIAMETER: 2•(7 (in) HEIGHT OF WC: 40•-111 Ut) WELL VOLUME: 6.45 (gal)
WELL DEPTH: _ ._GG • 60 (ft) TOTAL VOLUME PURGED: Z- 10 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
a
is) 466c) ism) Low Flow Samplincl_Stabilization Criteria
• pH f 0.1 standard unit
� � Speck Conductance ± 5% In NSlcm
IL DO 3 0.2 mglt
• Turbidity less than 10 NTUs.
TIME
WATER
LEVEL
FLOW,o
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/Cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
6154
140
p . 2
t {s
65
71
516 i
311
S.
0159
26.' o
Iq0 1"w
p. 0
t't
2.34
45
5•441
5417
14 7.
OR4
29. I N
12*0
1, sof 5
1.41
66
`
2
ZwL
W-u�.
2�•S
2�D
1.85
}.So
10
•372
U,C'
( 25
%
7-w
2.10
t It.
1,5ti
&S
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
NO
WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
[:]YES:
NO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? AYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
lie H2S
Petroleum Earhy Musty Undelermined
ODOR STRENGTH
4 cove Minor
Strong
ADDITIONAL NOTES: APPEARANCE
4ewr Cloudy
Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

FICAMA F--�CCR[--�Landfill F]NPDES [-�DGW❑ASW F--ILRB
SPECIAL STUDY
FIELD SAMPLING LOG
Site: OlyiI,CC Well/SW ID: LAV- 79 Date: R 21-21
•/ft, DUKE
t.r ENERGY
GROUNDWATER SAMPLE [—]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO [:]WELL DEVELOPMENT
FIELD STAFF: M— WEATHER: []SUNNY❑r PARTLY CLOUDY OVERCAST []RAIN []SNOW AIR TEMP:41 'F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL M 76753
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: '1 W3 )Zct
START PURGE TIME: IM SAMPLE COLLECTION TIME: llbS
PUMP/TUBING INTAKE DEPTH:_ _ 1" fill DEPTH TO WATER: 0-15 1 00 MULT FACTOR ": 0.163 [•iradius112)2.314•7.48l
WELL DIAMETER: 7�0 (in) HEIGHT OF WC: kb•Z t 00 WELL VOLUME: 7.0� (gat)
WELL DEPTH: ho-1 (0) TOTAL VOLUME PURGED: 2.00 (gal)
TYPE OF PUMP,
Bladder
Peristaltic
12 Volt
Grundfos
Other {
PURGE METHOD:
/
SAMPLING METHOD:
PUMP SETTING:
a
(psi) t.eC) (.ft) Low Flow Sampling Stabilization Criteria
• pH t 0.1 standard unit
• Speck Conductance f 50,6 In VS/cm
• DO f 0.2 mgll
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mLlmin)
(x)
(gallons OR mL)
(x.xx)
VC)
{x)
(mglL)
(x.xx)
(PS/cm)
{x)
(su)
(x.xx)
(mV)
{x)
(NTU)
(x.x)
(046
63.11
le0.46
11
& 23
791'
S b7
1 Z.
to S f
( 72 t
'Soo
046
t S3
4.51
7. 1
5-St
- 3141ll.!
1r5jl
1 63•?!
3LO
I.0
[ Gb
72
3.35
2.55
7.c
10 -7
43.111
3w
1.60
1%
I.S4
72
5
2'to
7.7
1100
.?!
3U0
2.0
l 8
I. 5 L
7 Z
%
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YE5E]
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑ YES
L-i
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ©YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
15%?
[:]YES ❑NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
a
Minor Strong
ADDITIONAL NOTES: APPEARANCE
leer
Cloudy Turbid RediIron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
VA11 Version 1.0 Revised 1211712018 RDP

CAMA r CCR � Landfill NPDES
DGW ASW LRB SPECIAL STUDY
Site: A-s w tk
FIELD SAMPLING LOG
WeII/SW ID: LMw - 27
Date: 44,[-si
.j•� DUKE
ENERGY
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO [—]WELL DEVELOPMENT
FIELD STAFF: 01- WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST DRAIN ❑SNOW AIR TEMP: 61 'F
COMPANY: [-j DUKE ENERGY FIELD METER TYPE/ SERIAL #: 74357(
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #:_'1)21
START PURGE TIME: 11l SAMPLE COLLECTION TIME: (f 10
PUMPITUBING INTAKE DEPTH: M s (n) DEPTH TO WATER: L9q• 06 (h) MOLT FACTOR *: 0,163 ['{radius112)2•314'7 as]
WELL DIAMETER: to (in) HEIGHT OF WC: 215.6 (fl) WELL VOLUME: `(.*S (gal)
WELL DEPTH: f1 (0) TOTAL VOLUME PURGED: (-W (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( }
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
a
1p.+1 cs�l c.�1 Low Flow Sampling Stabilization Criteria
• pH t 0 1 standard unit
• Specific Conductance t 5% In }tS!cm
• DO t 0.2 mg.l
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE 115
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x,xx)
(nnUmin)
(x)
(gallons OR ml-)
(x.xx)
CC)
(x)
(mg/L)
(x.xx)
(NSIcm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
ul'i
(71. z1)
Ito
O"w
70
z515
h 6 62L
1-0
(6-011
'.J.3
lbo
0.10
Li
2. tP
66
5 a
32z
Z. f
1110
*Z3
tiro
D, b
L'l
t• `�o
64
S. r?
311
Z.11
IIti3
6'L1
itu
a.sb
11
&b
.5•t5
'54
2.v
176
I$V
34 7
2.t
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
[3
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [EYES []NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑YES
[eNO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? AYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
15%?
[:)YES ❑NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
0e
1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
l&e
Minor Strong
ADDITIONAL NOTES: APPEARANCE
Dar
Cloudy Turbid Redllron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
/
/
All
Version 1.0 Revised 12/17/2018 RDP
4,'pU.%4C)%A

CAMA , CCRLandfill
NPDES DGW ASW LRB SPECIAL STUDY
Site: 44w.4
FIELD SAMPLING LOG
Well/SW ID: I-MW-36
Date: 9 ZO-Z1
%; DUKE
` w ENERGY
El GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE[:]LEACHATE SAMPLE 0WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 071 WEATHER: []SUNNY ❑PARTLY CLOUDY ❑OVERCAST QRAIN ❑SNOW AIR TEMP: 7Z -F
COMPANY: 0 DUKE ENERGY FIELD METER TYPE! SERIAL M-174;57Y
❑ OTHER: TURBIDI METER TYPE! SERIAL #: 3-t Y
START PURGE TIME: Niel SAMPLE COLLECTION TIME: Ogg, ( SOS
PUMPITUSING INTAKE DEPTH: 140 (ft) DEPTH TO WATER: •Ia (fit) MULT FACTOR -: 0.1631 (radus112)2 3.ta•zas}
WELL DIAMETER: 2• V (in) HEIGHT OF WC: I Z. 6 3 (h) WELL VOLUME: Z •0 is (gal)
WELL DEPTH: 1( 5.10 (ft) TOTAL VOLUME PURGED: 0•60 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
/
PUMP SETTING:
P
R
p
tit (,« (b«)
Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
• Specific Conductance ± 5% in VS/cm
• DO t 0.2 mgit
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUrnin)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(NSkm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
I
37.15,
1 oO !tom
G .r5
k
5- fe
3'-13
1.411
3ro
1L.L
IKS,
3 51
110
0.36
t16
2.67
3 2
27
31
d•Y
156U
"is-61
12v
6 .,IS
11
Z-54
311
G.24
3 7.b
110
0.60
306
•I
0
(6
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES " NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? 2YES❑NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? A ❑
YES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? [] YES ❑ NO DUPLICATE i (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR eie H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH tone Minor Strong
ADDITIONAL NOTES: APPEARANCE bear Cloudy Turbid Redfiron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
SAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

CAMA C�ECR r_ Landfill
NPDES DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG
Site: Asktmkc Well/SW ID: LMw-K6
Date: 9-Zv•2(
� � DUKE
T ENERGY
❑i GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: (11 L WEATHER: []SUNNY ❑PARTLY CLOUDY ❑OVERCAST QRAIN []SNOW AIR TEMP: 72 -F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL M 7655-1 'I
❑ OTHER: TURSIDIMETER TYPE/ SERIAL M -3im
START PURGE TIME: Mol SAMPLE COLLECTION TIME: lq'L5
PUMPITUBING INTAKE DEPTH: �� 00 DEPTH TO WATER: Z)• M (n) MULT FACTOR `: n 163 (trail+usn2}2 a.ta �.ae)
WELL DIAMETER: Z.o (in) HEIGHT OF WC: (h) WELL VOLUME: Y• 57 (gal)
WELL DEPTH: Kj2 (d) TOTAL VOLUME PURGED: (.86 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
,
PUMP SETTING:
a
o
(am) Low Flow Sampling Stabilization Criteria
• pH 10 1 standard unit
Specific Conductance i 5% In NSxm
• DO t 0.2 mgrl
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE �U"
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
("C)
(x)
(mg/L)
(x.xx)
(}1S/Cm)
)
(su)
(x.xx)
(MV)
(x)
(NTU)
(x.x)
taw>
2(.55
`try! o
0.60
16
0,3)
62
1
5:1fY
tit
KO
3W
(•05
I6
6.31
620
.rt
w
7.31
!KI$
25.45
1w
I. K5
(6
0.32
620
(,.Il
(&
Z•Xb
I�Z(
25.45
w
I. `DS
(6
0. 3o
6(z
4.rz
1,06
3.1(.
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? [?)YES [:1NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
❑YES
N
NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? AYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%?
❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
�
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
K01e
Minor Strong
ADDITIONAL NOTES: APPEARANCE
r&r
Cloudy Turbid RediIron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
r
�
:0 FLASH M0111NT Version 1.0 Revised 12/17/2018 RDP

nCAMA [2CCR Landfill ONPDES ❑ DGWC ASW LRB SPECIAL STUDY,
FIELD SAMPLING LOG
Site: 46;14. Well/SW ID: GB-1
Date: Vt1-zj
t� DUKE
ENERGY
GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: Ot— WEATHER: []SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST QRAIN QSNOW AIR TEMP: " 'F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL M 7 S5711
❑ OTHER: TURHIDIMETER TYPE/ SERIALM 312-1
START PURGE TIME: 12'10 SAMPLE COLLECTION TIME: 12 _
PUMP/TUBING INTAKE DEPTH: 7y r10 00 DEPTH TO WATER: 34-90 (fl) MULT FACTOR': 0,163 Igradiusr12?2.314•7481
WELL DIAMETER: I'D (in) HEIGHT OF WC: y0 • 00 WELL VOLUME: 6.52 (gal)
WELL DEPTH: X 20 (fl) TOTAL VOLUME PURGED: a•'ICU (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( }
PURGE METHOD:
/
SAMPLING METHOD:
/
PUMP SETTING:
a
(psi) (,mi) cal Low Flow Sampling Stabilization Criteria
pH t 0 1 standard unit
Specit'ic Conductance t 5% In 4lcm
• 00 t 0 2 mgrt
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
QRP
TURBIDITY
(FT)
(x.xx)
(mL/min)
{x)
(gallons OR mL)
(x.xx)
VC)
(x}
(mg/L)
(x.xx)
(PS/cm)
(x}
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
I21.17
3?. yo
I to
0.70
1 C6
II 1 &
32
q 70
5L7
L(q
24S
37.39
ISO
0,L10
17
?AILI
33
u•51
391
9I'2
2q
37.11
ISO
0,60
11
LES
33
k.uq
Z3
t'LSI
37.32
1
0
17
'7
31'
1.5
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES 2 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? []YES []NO
IS A TURBIDITY METER DUPLICATE REQUIRED? [:IYESLJNO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? AYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR (2>e 1-12S Petroleum Eanny Musty Undelermired
ODOR STRENGTH (±gie Minor Strong
ADDITIONAL NOTES: APPEARANCE `Ar Cloudy Turbid Red/iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/1712018 RDP

�CAMA ]CCR]Landfill �NPDES LI DGW❑ASW �LRI3 SPECIAL STUDY
DUKE
FIELD SAMPLING LOGI
ENERGY
Site: ilu- Well/SW ID: 66-1 W, Date: 9-Zl of
GROUNDWATER SAMPLE SURFACE WATER SAMPLE [:]LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G51,
COMPANY: 0 DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑PARTLY CLOUDY TOVERCAST QRAIN 12SNOW AIR TEMP: 72— -F
FIELD METER TYPE/ SERIAL #: 76357
TURBIDIMETER TYPE/ SERIAL #: 5521
START PURGE TIME: IVO SAMPLE COLLECTION TIME: J'ZZS
PUMP/TUBING INTAKE DEPTH: �TL 1%- 00 DEPTH TO WATER: H%KD (ft) MULT FACTOR "• 0,163I•(radfuen2)2'314•7.481
WELL DIAMETER: 2 D (in) HEIGHT OF WC: 4(ft) WELL VOLUME: 7. b 2 (gal)
WELL DEPTH: b• I Z 01) TOTAL VOLUME PURGED: 1.60 (gal)
TYPE OF PUMP:
Bladder I
Peristaltic
12 Volt
Grundfos
Other { )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
a
°
1peg (1ec) (aec)
Low Flow Sampling Stabilization Criteria
pH = 0.1 standard unit
Specific Conductance = 5% in 11Slcm
DO = 0 2 mgR
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
{FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mV)
(x)
(NTU)
(x.x)
j-41,
Q 74
3ro
0.2o
Z I
r S. ro
1 /
557
Sill
1.11.
12K
KR.-74
3017
o - 5-5
is
6.4't
43
5;.&V
3l4b
/.
IL(e
K'71j
LO
OAD
17
0.6to
1 13
S6e,
1 !�50
01
Pt2t
k4.14
30
1. 25
I'1
6.63
q3
5.7t�
3q-)
t. K
IZ7M
N°I.
-30D
>, by
(7
W
9'l
510
34
U
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES© NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?ZYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ]YES (❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE i (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR 9b H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH t&e Minor Strong
ADDITIONAL NOTES: APPEARANCE (&ar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/1712018 RDP

CAMA , CCR .,Landfill
Site: AshciAk
JNPDES 0 DGW ASW LRB SPECIAL STUDY
FIELD SAMPLING LOG
Well/SW ID: GB-45L
Date: 9-Z►-z
•DUKE
ENERGY
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: 01. WEATHER: []SUNNY ❑PARTLY CLOUDY ❑OVERCAST ❑RAIN []SNOW AIRTEMP: 70 -F
COMPANY: 0 DUKE ENERGY FIELD METER TYPE! SERIAL #: 76B74
❑ OTHER: TURBIDIMETER TYPE! SERIAL #:_ n2A
START PURGE TIME: 13 11 SAMPLE COLLECTION TIME: 1335
PUMPITUBING INTAKE DEPTH: S7.64 00 DEPTH TO WATER: 35•15 (tt) MOLT FACTOR 0.1631'(radm511212'3 14'7 481
WELL DIAMETER: 7.6 (in) HEIGHT OF WC: It.74 00 WELL VOLUME: y 6' (gal)
WELL DEPTH: by .0 {I1) TOTAL VOLUME PURGED: 6155 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
I
SAMPLING METHOD:
PUMP SETTING:
V
q
0
Low Flow Sampling Stabilization Criteria
(pef 1'ra[ pH t D.1 standard unit
flb ' N Speck Conductance t 5% in NSlcm
• DO 10 2 mglt
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
00
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
[FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
[°C)
(x)
(mg1L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
[x)
(NTU)
(x.x)
I S'15
.11
?0
0.55
It
3A &
53
5.16
3111-
i ••t
137 G
38.11
to
0.161
it
3 S'1
5 `f
5. r7
561f
1 •E
1329
Will
6. ?S
1`d
3.41
5,4
5.1(.
ul
I.o
I 37-
Will
8o
O S's
it
3.41
5,1b
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)?
❑ YES
"
NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? EYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED?
OYEStJNO
IS THE LOCATION FIELD VEHICLE ACCESSIBLE? QYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN
15%?
❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR
(lope
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH
I&e
Minor Strong
ADDITIONAL NOTES: APPEARANCE
I + r
Cloudy Turbid Redliron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 1211712018 RDP

CAMA , CCR _—Landfill NPDES DGW ASW LRB SPECIAL STUDY
DAILY CALIBRATION LOG -%� DUKE
Site: `Qs� uA-, Date: q-Zo-2 i ENERGY
FIELD PERSONNEL: L3Z
WEATHER: ❑SUNNY EIPARTLYCLOUDY J! OVERCAST J RAIN []SNOW TEMiPERATURE (APPROX): 6a1r
INSITU SERIALM 2,635711
2moci SERIAL t1: 332.9
Buffer Chart Meter
HH
Within ±
Lot Number
Expiration Temperature
pH Reading
Time: 1DtiS
0.1 su?
'C
I � '
su su
(Sul(Sul
7.00 sU
! 2uo3yg
02-ze-zi I- zu.Lty
7.,rL i 6.1?1
N
10.01 ------ s
Z602.3o
G2 -22-Z'1.. U. y b �I
a1- 31- 2L 2v�,{&
}}I
16.0 b 1 {v.D�
u-W I I..01N
N
4.01 SU
ZcK9l2
11-Check of 7.00 su as Live Reading
2co 3'd$
01-25s -Z.L i �ZC,..,,
� 00
Y N
j
Post Calibration- Date: 4-21-'Lt Time: 0605
Within ±
0.2 Su?
7.00 su Z0b3881 oZ'Za'ZZ I$.Nl 7.rrt. 7.01 m N
10.01 su 26OZ30 E OL-26-2.1 ti$ IJ(, [0.y6_ _ lo,03
V N
4.01 su 2094911 01-31-2L lfb•7.1- K-tV 3t4t 4i N
Time:
Standard Value: 1410 PS
Calibration Check of
221 ps as Live Reading
Post Calibration- Date. 5
tqiu Ns
ORP
Time: It&
KZq mV
' Post Calibration- Date.
s1Z,i mV
Lot Number
L t$2of.
golf qA
Gt ii Lo C-
Lot Number
1378
1378
Buffer �Mete�r- - j� Within i i
Expiration
Temperature (°C) Reading (Ns) 10%? 1
63.1-ZL ZTBIs lKo6l +a N
02-�-2'L Z2u+ 22b t$ N
03•I-2.1- I 1-6:10 f 140b.R ;� N
T
Buffer Adjusted
Meter
Within _
Expiration
Temperature
Value
Reading
za%?
(°C)
(mV)
(mV)
ol-3o.7oZ-L
*77.'7a
K361b
K3d•2 iV N
Time:
'l3
T Y� N
ot•3o- 2oz'L
27•��
Revised 12/18/2018 KKH

CAMA , CCR - Landfill NPQES DGW ASW LRB SPECIAL STUDY.
DAILY CALIBRATION LOG I DUKE
"�. ENERGY
Site: &aw k- Date: ��Zt-��
FIELD PERSONNEL:_CJ?- _
WEATHER: SUNNY _PARTLY CLOUDY CIOVERCAST RAIN ❑SNOW TEMPERATURE (APPRDX)_ 66V
INSITU SERIAL M 76757K
21000SERIAL#•- 33.21
PH
Time: ��
Lot Number
Expiration
`
Buffer
Temperature
°C
( )
Chart
pH
su
( �
Meter
Reading
su
( )
Within t
0.1 su?
7.00 Su I
2vc3$8
0Z-Z8-Z••L I
1$.t!!
I Too?
7-01
N
10.01 su I
Zboz.3b
o2-is-2'L
IS•oL
le.a6
i 1"3
N
4.01 su
eck of 7.00 su as Live Reading
ZbK q lZ
2oo3id8
01- 31- Z'L
OZ'2� _ZZ
i g .1A
!$_KY
1(,L0 13 $
74,1, j 7-(1t
1
N
N I
I—
9'tl-2i
Post Calibration- Date: Time: 1 YSS
_
Within T
0.2 SO
7.00 su T
10.01 Su
2003%3
2607-30
# o2-294% 23. q0 7 n 7.oi
I 02,-2S-21 Z3. 5t 10.00 10.02
a) N I
IN
4.01 su
2094 q 17.
01- 31-2'L
23. SN
l Y•W-
i(.o Z
N
Specific Conductivity
Buller _F_
Meter Within t
Time: 060
Lot Number
I Expiration '
Temperature (°C)
Reading (Ns) 10%?
Standard Value: 1410 Ns
I'i06.$ N
G l$2o(.
83-1 -2'L
lt5. 7o
Calibration Check of
Z Z5.5 00 N
27-1 ps as Live Reading
�Oii RA
o2- • 2•L
!$. 7'(
Post Calibration- Date: 1-'bt-IA
Time:Y [St+v
ILtID Nsi
GIILoc.
� 03.1-21L I
23.ia4
f lKil•t � N i
T FORP Buller T Adjusted Meter
Within t
Time: °
r050 Lot Number Expiration Temperature Value Reading 20%?
1 (°C) (mV) (mV)
474 mV 137$ � el - 30 • ZoZz 2'Ll $ 4 36.8 i j A>•L 8+ N
Post Calibration- Date: 9.,Lt - Tt Time: 15W
tjjq mV 1-578 1 ot•30- ZoLZ ' 431.°I 1 K31,.5 N
Revised 12/18/2018 KKH

Semiannual Water Quality Monitoring Report — September 2021 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
410
synTerra
Science & Engineering Consultants

Analytical Data Review Checklist
Station
State
Sample IDs
Asheville Steam Electric Plant
NC
DP-4, LMW-3B, LMW-4B, SW-2, SW-3
Laboratory Name(s):
Duke, Pace
MATRICES
Lab Report Number:
Sample Receipt Date
Analysis Complete Date
Sampling Date(s)
O GW
O SO/SE
J21090334
9/21/2021
10/5/2021
9/20/2021
o SW
References:
NATIONAL FUNCTIONAL GUIDELINES for Inorganic Superfund Methods Data Review (EPA 2017)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Specified Methods (EPA 9056, EPA 6010, EPA 6020, EPA 7470, EPA 903.1, and EPA 904.0)
Sample Receipt & Chain of Custody
Do the Sample IDs and Laboratory Analyses recorded on the Chain -of -Custody form match the Sample IDs and
Ed yes l] No
i)
Analyses listed in the Laboratory Package?
© YES 0 No
la Do the dates and times of sampling listed on the Chain -of -Custody match the laboratory report?
Is the Sample Temperature Upon Receipt at the laboratory recorded on the Chain -of -Custody form less than 6
© YES 0 No
2) degrees Celsius? If NO, then
❑ YES ❑ NO
2a Is the presence of Wet Ice noted in the cooler? OR
❑ YES ❑ NO
2b Were the samples collected less than two hours prior to receipt at the lab?
If so, the sample temperature at the time of collection should have been recorded on the Chain -of -Custody
form to compare to the sample temperature upon receipt at the lab to demonstrate that the samples were
iced down for cooling during transport.
o YES o No
3) Was the proper sample preservation checked and documented on the Chain -of -Custody form or Sample Receipt form?
Are there any Special Notes, Exceptions, or Anomalies listed either on the Chain -of -Custody form or on the Sample
❑ YES © No
4)
Receipt form?
Briefly describe:
❑ YES 10 NO
Was the transfer of Custody of the Samples properly documented and traceable through signature, date, and time by all
5)
persons who relinquished and/or received custody of the samples?
Cl YES Cl NO
6) Do the values for the field parameters listed on the COC match the values entered in the lab report?
N/A
Batch Quality Assurance/Quality Control (See attached List of Definitions)
7) Was the Holding Time for Analysis met for each parameter?
❑ YES o NO
N/A 7a Alkalinity, Bicarbonate, Carbonate: Analyzed within 14 days of collection
© YES ❑ NO
7b Bromide, Chloride, Fluoride, Sulfate: Analyzed within 28 days of collection
© YES ❑ NO
7c Nitrate -Nitrite: Analyzed within 28 days of collection
❑ YES 0 NO
N/A 7d Chromium VI: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
❑ YES ❑ NO
N/A 7e Mercury: Analyzed within 28 days of collection (preserved)
© YES 0 NO
7f Total and Dissolved Metals: Analyzed within 6 months of collection
O YES ❑ NO
7g TSS and TDS: Analyzed within 7 days of collection
❑ YES 0 NO
N/A 7h Oil and Grease: Analyzed within 28 days of collection
❑ YES o NO
8) Are there any Qualifiers assigned by the laboratory, such as a "J" flag?
11 YES 11 NO
8a If YES, are definitions provided?

Batch Quality Assurance/Quality Control (See attached List of Definitions)
❑ YES 0 NO
Laboratory Control Sample - were any parameters flagged by the lab as being outside the limits of control in the
9)
associated laboratory control sample?
❑ YES ❑ NO
9a If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑ YES ❑ NO
9b Were the same parameters detected in the samples?
0 YES 0 No 10)
Matrix Spike Sample - did the laboratory provide matrix spike results (MS/MSD)? If so, then:
0 YES 0 NO
10a Was the original sample spiked a project sample? If not, then stop here. If so, then:
❑ YES 0 No
Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike
10b
sample? If so, list in the summary section below.
0 YES ❑ No 11)
Laboratory Duplicate Sample - did the laboratory provide duplicate sample results? If so, then:
❑ YES 0 No
11a Was the sample analyzed as a laboratory duplicate a project sample? If not, then stop here. If so, then:
Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate
0 ves ❑ No
lib sample? If so, list in the summary section below.
Field Duplicate Sample - is the relative percent difference between the original and field sample results less than 35
O YES 0 NO 12)
percent?
N/A
Field/Equipment/Trip Blanks - were any parameters detected in the associated Field/Equipment/Trip Blanks? If yes,
0 ves 0 No 13)
please include in the summary section at the end of this form.
If yes, were any target analytes detected in the samples at a concentration less than ten times the
0 YES ❑ No
13a Field/Equipment/Trip Blank concentration?
0 YES o No 14)
Were initial and continuing calibration blank information within acceptable criteria per the lab report?
0 YES 0 No 15)
Method Blank - were any parameters detected in the Method Blank(s)?
0 YES 0 No
If yes, were any target analytes detected in the samples at a concentration less than ten times the method
15a
blank concentration?
If YES, please list in the summary section below.
❑ YES 0 NO 16)
Were any reporting limits for non -detect results greater than the screening criteria?
If YES, please list in the summary section below.
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up
action with the analytical lab or field personnel must be noted in the summary section at the end of this form before the data can be approved for use by technical
leads.
Summary (include any special notes, exceptions or anomalies listed in the case narrative or discovered as a result of data validation):
- Nitrate (0.02 mg/L), Nitrate as N (0.01 mg-N/L), and Mercury (0.03 ug/L) were detected in the Field Blank; Nitrate as N and Mercury were also
detected in the samples at concentrations less than 10x the blank concentrations.
Review Determination:
❑ USABLE 0 USABLE WITH REQUIRED ACTIONS ❑ UNUSABLE
RESOLVED
Signatures:
Date:
Technical Lead
�'j,L r`/r�
i Y� 1/12/2022
Data Quality Reviewer
REB 10/27/2021

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J21090334
Project Name: ASHEVILLE - ASHEVILLE STATE LF DETECTION MONITORING
Task Code: LF
Customer Name(s): B Allison ,B Moeller,J Stowe,D OBrien,Synterra
Customer Address: Asheville Steam Station
200 CP and L Drive
Arden,NC 28704
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: Pee, � Date:
(Signature)__ _ _
P endall
Program Comments:
1 /10/2022
REVISION
Page 1 of 35
Note: This is a revised report that supersedes the original dated 10-5-2021. At the request of the customer, the surface water
location IDs were changed.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
REVISION
Page 2 of 35
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2021026150
ASHEVILLE
20-Sep-21
12:11 PM
Connor Zahora
ASV_LF-SW-2
2021026151
ASHEVILLE
20-Sep-21
1:21 PM
Connor Zahora
ASV_LF-SW-3
2021026152
ASHEVILLE
20-Sep-21
1:40 PM
Connor Zahora
ASV—DP-4
2021026153
ASHEVILLE
20-Sep-21
2:25 PM
Connor Zahora
ASV_LMW-4B
2021026154
ASHEVILLE
20-Sep-21
3:05 PM
Connor Zahora
ASV_LMW-3B
2021026155
ASHEVILLE
20-Sep-21
3:45 PM
Connor Zahora
ASV_FB-20210920-1545
6 Total Samples

REVISION
Page 3 of 35
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 10/5/2021

REVISION
Certificate of Laboratory Analysis Page 4 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Site: ASV LF-SW-2
Sample #:
2021026150
Collection Date: 09/20/2021 12:11 PM
Loc code: ASV LF-SW-2
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090238
Chloride 8.7
mg/L
0.1
0.0154
1
EPA 9056A
09/21/2021 11:25
BGN9034
Fluoride 0.06 J
mg/L
0.1
0.0479
1
EPA 9056A
09/21/2021 11:25
BGN9034
Nitrate 0.37
mg/L
0.1
0.0209
1
EPA 9056A
09/21/2021 11:25
BGN9034
Nitrate as N 0.08
mg-N/L
0.023
0.002
1
EPA 9056A
09/21/2021 11:25
BGN9034
Sulfate 12
mg/L
0.2
0.0428
2
EPA 9056A
09/21/2021 11:25
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090323
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090269
0.01 1 EPA 7470A 09/23/2021 12:17 JAA5429
Barium (Ba)
0.018
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.022 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.413
mg/L
0.01
0.004
Manganese (Mn)
0.278
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090278
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.145 J
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.398 J
ug/L
1
Lead (Pb)
0.054 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.114 U
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
1 SW 6010D
09/22/2021 19:34
DMFRANC
0.104
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.111
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.032
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.185
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.077
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.037
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.193
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.035
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.041
1
SW 6020B
09/28/2021 16:33
CWSPEN3
0.114
1
SW 6020B
09/28/2021 16:33
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

REVISION
Certificate of Laboratory Analysis Page 5 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Site: ASV LF-SW-3
Sample #:
2021026151
Collection Date: 09/20/2021 01:21 PM
Loc code: ASV LF-SW-3
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090238
Chloride
9.8
mg/L
0.1
0.0154
1
EPA 9056A
09/21/2021 10:25
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/21/2021 10:25
BGN9034
Nitrate
0.56
mg/L
0.1
0.0209
1
EPA 9056A
09/21/2021 10:25
BGN9034
Nitrate as N
0.13
mg-N/L
0.023
0.002
1
EPA 9056A
09/21/2021 10:25
BGN9034
Sulfate
4.3
mg/L
0.1
0.0428
1
EPA 9056A
09/21/2021 10:25
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090323
Mercury (Hg) 0.09 ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090269
0.01 1 EPA 7470A 09/23/2021 12:19 JAA5429
Barium (Ba)
0.016
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.022 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.135
mg/L
0.01
0.004
Manganese (Mn)
0.017
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090278
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.147 J
ug/L
1
Lead (Pb)
0.055 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.257 J
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
1 SW 6010D
09/22/2021 19:46
DMFRANC
0.104
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.111
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.032
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.185
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.077
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.037
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.193
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.035
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.041
1
SW 6020B
09/28/2021 16:42
CWSPEN3
0.114
1
SW 6020B
09/28/2021 16:42
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

REVISION
Certificate of Laboratory Analysis Page 6 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Site: ASV DP-4
Sample #:
2021026152
Collection Date: 09/20/2021 01:40 PM
Loc code: ASV-DIP-4
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090238
Chloride 3.8
mg/L
0.1
0.0154
1
EPA 9056A
09/21/2021 09:25
BGN9034
Fluoride 0.29
mg/L
0.1
0.0479
1
EPA 9056A
09/21/2021 09:25
BGN9034
Nitrate 0.71
mg/L
0.1
0.0209
1
EPA 9056A
09/21/2021 09:25
BGN9034
Nitrate as N 0.16
mg-N/L
0.023
0.002
1
EPA 9056A
09/21/2021 09:25
BGN9034
Sulfate 780
mg/L
10
0.0428
100
EPA 9056A
09/21/2021 09:25
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090323
Mercury (Hg) 0.08 ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090269
0.01 1 EPA 7470A 09/23/2021 12:30 JAA5429
Barium (Ba)
0.029
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.667
mg/L
0.01
0.004
Manganese (Mn)
0.261
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090278
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.186 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
1.63
ug/L
1
Lead (Pb)
0.09 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.262 J
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
1 SW 6010D
09/22/2021 19:51
DMFRANC
0.104
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.111
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.032
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.185
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.077
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.037
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.193
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.035
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.041
1
SW 6020B
09/28/2021 16:50
CWSPEN3
0.114
1
SW 6020B
09/28/2021 16:50
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

REVISION
Certificate of Laboratory Analysis Page 7 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Site: ASV LMW-4B
Sample #:
2021026153
Collection Date: 09/20/2021 02:25 PM
Loc code: ASV LMW-4B
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090238
Chloride
9.1
mg/L
0.5
0.0154
5
EPA 9056A
09/21/2021 08:39
BGN9034
Fluoride
0.47 J
mg/L
0.5
0.0479
5
EPA 9056A
09/21/2021 08:39
BGN9034
Nitrate
3.4
mg/L
0.5
0.0209
5
EPA 9056A
09/21/2021 08:39
BGN9034
Nitrate as N
0.78
mg-N/L
0.115
0.002
5
EPA 9056A
09/21/2021 08:39
BGN9034
Sulfate
250
mg/L
5
0.0428
50
EPA 9056A
09/21/2021 08:39
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090323
Mercury (Hg) 0.04 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090269
0.01 1 EPA 7470A 09/23/2021 12:37 JAA5429
Barium (Ba)
0.020
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.056
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
19.5
mg/L
0.01
0.004
Manganese (Mn)
9.17
mg/L
0.005
0.001
Nickel (Ni)
0.020
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090278
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.353 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
53.3
ug/L
1
Lead (Pb)
0.116 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.041 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.114 U
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
1 SW 6010D
09/22/2021 19:55
DMFRANC
0.104
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.111
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.032
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.185
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.077
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.037
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.193
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.035
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.041
1
SW 6020B
09/28/2021 16:58
CWSPEN3
0.114
1
SW 6020B
09/28/2021 16:58
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

REVISION
Certificate of Laboratory Analysis Page 8 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Site: ASV LMW-3B
Sample #:
2021026154
Collection Date: 09/20/2021 03:05 PM
Loc code: ASV LMW-3B
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090238
Chloride 3.1
mg/L
0.1
0.0154
1
EPA 9056A
09/21/2021 10:55
BGN9034
Fluoride 0.05 J
mg/L
0.1
0.0479
1
EPA 9056A
09/21/2021 10:55
BGN9034
Nitrate 2.4
mg/L
0.1
0.0209
1
EPA 9056A
09/21/2021 10:55
BGN9034
Nitrate as N 0.53
mg-N/L
0.023
0.002
1
EPA 9056A
09/21/2021 10:55
BGN9034
Sulfate 94
mg/L
2
0.0428
20
EPA 9056A
09/21/2021 10:55
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090323
Mercury (Hg) 0.03 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090269
0.01 1 EPA 7470A 09/23/2021 12:39 JAA5429
Barium (Ba)
0.038
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.016 J
mg/L
0.05
0.005
Copper (Cu)
0.004 J
mg/L
0.005
0.001
Iron (Fe)
0.080
mg/L
0.01
0.004
Manganese (Mn)
0.286
mg/L
0.005
0.001
Nickel (Ni)
0.004 J
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090278
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.702 J
ug/L
1
Lead (Pb)
0.081 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.27 J
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
1 SW 6010D
09/22/2021 19:59
DMFRANC
0.104
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.111
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.032
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.185
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.077
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.037
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.193
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.035
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.041
1
SW 6020B
09/28/2021 17:07
CWSPEN3
0.114
1
SW 6020B
09/28/2021 17:07
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

REVISION
Certificate of Laboratory Analysis Page 9 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Site: ASV FB-20210920-1545 Field Blank Sample #: 2021026155
Collection Date: 09/20/2021 03:45 PM Loc code: ASV QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q21090238
Chloride 0.0154 U mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.02 J mg/L
Nitrate as N 0.01 J mg-N/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q21090323
Mercury (Hg) 0.03 J ug/L
TOTAL RECOVERABLE METALS BY ICP - Q21090269
Barium (Ba)
0.002 U
mg/L
Beryllium (Be)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.004 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Nickel (Ni)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090278
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.114 U
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/21/2021 08:24
BGN9034
0.1
0.0479
1
EPA 9056A
09/21/2021 08:24
BGN9034
0.1
0.0209
1
EPA 9056A
09/21/2021 08:24
BGN9034
0.023
0.002
1
EPA 9056A
09/21/2021 08:24
BGN9034
0.1
0.0428
1
EPA 9056A
09/21/2021 08:24
BGN9034
0.05
0.01
1
EPA 7470A
09/23/2021 12:41
JAA5429
0.005
0.002
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.005
0.002
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.05
0.005
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.005
0.001
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.01
0.004
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.005
0.001
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.005
0.001
1
SW 6010D
09/22/2021 20:04
DMFRANC
0.005
0.004
1
SW 6010D
09/22/2021 20:04
DMFRANC
1
0.104
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.111
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.032
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.185
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.077
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.037
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.193
1
SW 6020B
09/28/2021 17:15
CWSPEN3
1
0.035
1
SW 6020B
09/28/2021 17:15
CWSPEN3
0.2
0.041
1
SW 6020B
09/28/2021 17:15
CWSPEN3
0.3
0.114
1
SW 6020B
09/28/2021 17:15
CWSPEN3
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

REVISION
Certificate of Laboratory Analysis Page 10 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090238 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
1.97
1.97
mg/L
1
0.0154
2
98.4
90
110
Fluoride
2.01
2.01
mg/L
1
0.0479
2
101
90
110
Nitrate
1.99
1.99
mg/L
1
0.0209
2
99.3
90
110
Sulfate
1.86
1.86
mg/L
1
0.0428
2
93.3
90
110
MS # 1
Parent Sample:
J21090334 -- 2021026153
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
Chloride
3.8
19
mg/L
5
0.0154
10
98.9
80
120
Fluoride
2.09
10.5
mg/L
5
0.0479
10
100
80
120
Nitrate
2.67
13.4
mg/L
5
0.0209
10
99.4
80
120
Sulfate
6.9
345
mg/L
50
0.0428
100
97
80
120
MSD # 1
Parent Sample:
J21090334 -- 2021026153
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
3.8
19
mg/L
5
0.0154
10
98.6
80
120
0.304
Fluoride
2.09
10.4
mg/L
5
0.0479
10
99.7
80
120
0.28
Nitrate
2.67
13.3
mg/L
5
0.0209
10
99.1
80
120
0.252
Sulfate
6.87
344
mg/L
50
0.0428
100
95.5
80
120
1.49

Certificate of LaboratoryAnalysis REVISION
y Page 11 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090323 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.001
-0.001
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.002
0.002
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.002
0.002
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.001
-0.001
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery LCL UCL
Qualifier
Mercury (Hg)
1.85
1.85
ug/L
1
0.01
2
92.5 85 115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.83
1.83
ug/L
1
0.01
2
91.3
85 115
MS # 1
Parent Sample:
J21090306 -- 2021025966
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
102
75 125
MSD # 1
Parent Sample:
J21090306 -- 2021025966
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.998
0.998
ug/L
1
0.01
1
98.3
75 125 3.5
MS # 2
Parent Sample:
J21090306 -- 2021025976
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
99
75 125
MSD # 2
Parent Sample:
J21090306 -- 2021025976
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.972
0.972
ug/L
1
0.01
1
95
75 125 4.12
MS # 3
Parent Sample:
J21090334 -- 2021026152
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
95.2
75 125

Certificate of LaboratoryAnalysis REVISION
y Page 12 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090323 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 3 Parent Sample: J21090334 -- 2021026152
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Mercury (Hg) 1.03 1.03 ug/L 1 0.01 1 95.2 75 125 0

REVISION
Certificate of Laboratory Analysis Page 13 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090269 1CP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000262
-0.000262
mg/L
1
0.002
0.005
< MDL
Beryllium (Be)
0
0
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000798
0.000798
mg/L
1
0.005
0.05
< MDL
Copper (Cu)
0.000219
0.000219
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
-0.000051
-0.000051
mg/L
1
0.004
0.01
< MDL
Manganese (Mn)
-0.000354
-0.000354
mg/L
1
0.001
0.005
< MDL
Nickel (Ni)
-0.000069
-0.000069
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000222
-0.000222
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.97
4.97
mg/L
1
0.002
5
99.4
80
120
Beryllium (Be)
4.95
4.95
mg/L
1
0.002
5
99
80
120
Boron (B)
4.88
4.88
mg/L
1
0.005
5
97.5
80
120
Copper (Cu)
4.88
4.88
mg/L
1
0.001
5
97.6
80
120
Iron (Fe)
4.93
4.93
mg/L
1
0.004
5
98.6
80
120
Manganese (Mn)
4.9
4.9
mg/L
1
0.001
5
98
80
120
Nickel (Ni)
4.99
4.99
mg/L
1
0.001
5
99.7
80
120
Zinc (Zn)
4.98
4.98
mg/L
1
0.004
5
99.5
80
120
MS # 1
Parent Sample:
J21090266
-- 2021025721
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.01
5.01
mg/L
1
0.002
5
100
75
125
Beryllium (Be)
4.97
4.97
mg/L
1
0.002
5
99.5
75
125
Boron (B)
4.89
4.89
mg/L
1
0.005
5
97.7
75
125
Copper (Cu)
4.89
4.89
mg/L
1
0.001
5
97.8
75
125
Iron (Fe)
10.5
10.5
mg/L
1
0.004
5
96.2
75
125
Manganese (Mn)
5
5
mg/L
1
0.001
5
98.2
75
125
Nickel (Ni)
4.97
4.97
mg/L
1
0.001
5
99.4
75
125
Zinc (Zn)
4.97
4.97
mg/L
1
0.004
5
99.2
75
125
MSD # 1
Parent Sample:
J21090266
-- 2021025721
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5
5
mg/L
1
0.002
5
99.6
75
125
0.38
Beryllium (Be)
4.93
4.93
mg/L
1
0.002
5
98.7
75
125
0.836
Boron (B)
4.85
4.85
mg/L
1
0.005
5
96.8
75
125
0.882
Copper (Cu)
4.85
4.85
mg/L
1
0.001
5
97.1
75
125
0.719
Iron (Fe)
10.4
10.4
mg/L
1
0.004
5
95.6
75
125
0.287
Manganese (Mn)
4.98
4.98
mg/L
1
0.001
5
97.8
75
125
0.441
Nickel (Ni)
4.95
4.95
mg/L
1
0.001
5
99
75
125
0.464
Qualifier
Qualifier
Qualifier
Qualifier

REVISION
Certificate of Laboratory Analysis Page 14 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090269 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J21090266 -- 2021025721
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.94 4.94 mg/L 1 0.004 5 98.6 75 125 0.565

REVISION
Certificate of Laboratory Analysis Page 15 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090278 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.056
-0.056
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.004
-0.004
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0
0
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.058
-0.058
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.005
-0.005
ug/L
1
0.077
1
< MDL
Lead (Pb)
-0.004
-0.004
ug/L
1
0.037
1
< MDL
Selenium (Se)
-0.288
-0.288
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.001
0.001
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.014
-0.014
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.012
0.012
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
49.7
49.7
ug/L
1
0.104
50
99.4
80
120
Arsenic (As)
51.2
51.2
ug/L
1
0.111
50
102
80
120
Cadmium (Cd)
50.8
50.8
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
50.1
50.1
ug/L
1
0.185
50
100
80
120
Cobalt (Co)
50.3
50.3
ug/L
1
0.077
50
101
80
120
Lead (Pb)
50.7
50.7
ug/L
1
0.037
50
101
80
120
Selenium (Se)
49.8
49.8
ug/L
1
0.193
50
99.5
80
120
Silver (Ag)
50.3
50.3
ug/L
1
0.035
50
101
80
120
Thallium (TI) Low Level
48.1
48.1
ug/L
1
0.041
50
96.2
80
120
Vanadium (V) Low Level
50.2
50.2
ug/L
1
0.114
50
100
80
120
MS # 1
Parent Sample:
J21090266 -- 2021025722
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
49.7
49.7
ug/L
1
0.104
50
99.4
75
125
Arsenic (As)
50.8
50.8
ug/L
1
0.111
50
102
75
125
Cadmium (Cd)
50.8
50.8
ug/L
1
0.032
50
102
75
125
Chromium (Cr)
50.7
50.7
ug/L
1
0.185
50
101
75
125
Cobalt (Co)
50.1
50.1
ug/L
1
0.077
50
100
75
125
Lead (Pb)
50.8
50.8
ug/L
1
0.037
50
101
75
125
Selenium (Se)
49.7
49.7
ug/L
1
0.193
50
99.4
75
125
Silver (Ag)
51
51
ug/L
1
0.035
50
102
75
125
Thallium (TI) Low Level
47.7
47.7
ug/L
1
0.041
50
95.4
75
125
Vanadium (V) Low Level
50.4
50.4
ug/L
1
0.114
50
101
75
125
MSD # 1
Parent Sample:
J21090266 -- 2021025722
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Antimony (Sb)
49.3
49.3
ug/L
1
0.104
50
98.7
75
125 0.775
Qualifier
Qualifier
Qualifier
Qualifier

REVISION
Certificate of Laboratory Analysis Page 16 of 35
This report shall not be reproduced, except in full.
Order # J21090334
Level II QC Summary
Q21090278 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Arsenic (As)
50.7
50.7
ug/L
1
0.111
Cadmium (Cd)
50.5
50.5
ug/L
1
0.032
Chromium (Cr)
50.7
50.7
ug/L
1
0.185
Cobalt (Co)
50.2
50.2
ug/L
1
0.077
Lead (Pb)
50.6
50.6
ug/L
1
0.037
Selenium (Se)
49.6
49.6
ug/L
1
0.193
Silver (Ag)
50.5
50.5
ug/L
1
0.035
Thallium (TI) Low Level
45.3
45.3
ug/L
1
0.041
Vanadium (V) Low Level
50.5
50.5
ug/L
1
0.114
Parent Sample:
J21090266 -- 2021025722
Spike
% Recovery
LCL
UCL
RPD
50
101
75
125
0.225
50
101
75
125
0.596
50
101
75
125
0.0593
50
100
75
125
0.128
50
101
75
125
0.383
50
99.1
75
125
0.226
50
101
75
125
0.949
50
90.5
75
125
5.26
50
101
75
125
0.127
Qualifier

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January 06, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J21090334 ASV LF
Pace Project No.: 92562485
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on September 21, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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CERTIFICATIONS
Project: J21090334 ASV LF
Pace Project No.: 92562485
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 17

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SAMPLE SUMMARY
Project: J21090334 ASV LF
Pace Project No.: 92562485
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92562485001
LF-SW-2
Water
09/20/2112:11
09/21/2114:38
92562485002
LF-SW-3
Water
09/20/21 13:21
09/21/21 14:38
92562485003
DP-4
Water
09/20/2113:40
09/21/2114:38
92562485004
LMW-413
Water
09/20/2114:25
09/21/2114:38
92562485005
LMW-313
Water
09/20/2115:05
09/21/2114:38
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 3 of 17

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SAMPLE ANALYTE COUNT
Project: J21090334 ASV LF
Pace Project No.: 92562485
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92562485001 LF-SW-2
SM 2540C-2011
ZMC
1
PASI-A
92562485002 LF-SW-3
SM 2540C-2011
ZMC
1
PASI-A
92562485003 DP-4
SM 2540C-2011
ZMC
1
PASI-A
92562485004 LMW-413
SM 2540C-2011
ZMC
1
PASI-A
92562485005 LMW-313
SM 2540C-2011
ZMC
1
PASI-A
PASI-A = Pace Analytical Services -Asheville
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J21090334 ASV LF
92562485
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92562485001
LF-SW-2
SM 2540C-2011
Total Dissolved Solids
62.0
mg/L
25.0
09/22/21 18:12
92562485002
LF-SW-3
SM 2540C-2011
Total Dissolved Solids
40.0
mg/L
25.0
09/22/21 18:12
92562485003
DP-4
SM 2540C-2011
Total Dissolved Solids
1180
mg/L
50.0
09/22/21 18:12
92562485004
LMW-4B
SM 2540C-2011
Total Dissolved Solids
501
mg/L
25.0
09/22/21 18:12
92562485005
LMW-3B
SM 2540C-2011
Total Dissolved Solids
211
mg/L
25.0
09/22/21 18:12
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 17

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PROJECT NARRATIVE
Project: J21090334 ASV LF
Pace Project No.: 92562485
Method: SM 2540C-2011
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: January 06, 2022
General Information:
5 samples were analyzed for SM 2540C-2011 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 17

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ANALYTICAL RESULTS
Project: J21090334 ASV LF
Pace Project No.: 92562485
Sample: LF-SW-2 Lab ID: 92562485001 Collected: 09/20/21 12:11 Received: 09/21/21 14:38 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 62.0 mg/L 25.0 25.0 1 09/22/21 18:12
Date: 01/06/2022 02:18 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 7 of 17

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ANALYTICAL RESULTS
Project: J21090334 ASV LF
Pace Project No.: 92562485
Sample: LF-SW-3 Lab ID: 92562485002 Collected: 09/20/21 13:21 Received: 09/21/21 14:38 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 40.0 mg/L 25.0 25.0 1 09/22/21 18:12
Date: 01/06/2022 02:18 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 8 of 17

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ANALYTICAL RESULTS
Project: J21090334 ASV LF
Pace Project No.: 92562485
Sample: DP-4 Lab ID: 92562485003 Collected: 09/20/21 13:40 Received: 09/21/21 14:38 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 1180 mg/L 50.0 50.0 1 09/22/21 18:12
Date: 01/06/2022 02:18 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 9 of 17

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ANALYTICAL RESULTS
Project: J21090334 ASV LF
Pace Project No.: 92562485
Sample: LMW-413 Lab ID: 92562485004 Collected: 09/20/21 14:25 Received: 09/21/21 14:38 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 501 mg/L 25.0 25.0 1 09/22/21 18:12
Date: 01/06/2022 02:18 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 17

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ANALYTICAL RESULTS
Project: J21090334 ASV LF
Pace Project No.: 92562485
Sample: LMW-313 Lab ID: 92562485005 Collected: 09/20/21 15:05 Received: 09/21/21 14:38 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 211 mg/L 25.0 25.0 1 09/22/21 18:12
Date: 01/06/2022 02:18 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 11 of 17

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QUALITY CONTROL DATA
Project: J21090334 ASV LF
Pace Project No.: 92562485
QC Batch: 648811 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92562485001, 92562485002, 92562485003, 92562485004, 92562485005
METHOD BLANK: 3403021 Matrix: Water
Associated Lab Samples: 92562485001, 92562485002, 92562485003, 92562485004, 92562485005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 09/22/21 18:10
LABORATORY CONTROL SAMPLE: 3403022
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 246 98 90-110
SAMPLE DUPLICATE: 3403023
92562052016 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 439 437 0 25
SAMPLE DUPLICATE: 3403024
92562104006 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 812 798 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /06/2022 02:18 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 17

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QUALIFIERS
Project: J21090334 ASV LF
Pace Project No.: 92562485
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /06/2022 02:18 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 17

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J21090334 ASV LF
Pace Project No.: 92562485
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92562485001
LF-SW-2
SM 2540C-2011
648811
92562485002
LF-SW-3
SM 2540C-2011
648811
92562485003
DP-4
SM 2540C-2011
648811
92562485004
LMW-4B
SM 2540C-2011
648811
92562485005
LMW-3B
SM 2540C-2011
648811
Date: 01/06/2022 02:18 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 14 of 17

REVISION
1 of 35
Document Name:
Document Revised: October 28, 202
_ aceAnal real �
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.07
Pace Carolinas Quality Off -ice
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville 0 Raleigh❑ Mechanicsville[] Atlanta❑ KernersvilleF
Sample Condition Client Name: _ WO# : 92562455
' 4-t� _ - Project g:
Courier: ❑Fed Ex ❑UPS QU5P5 ❑Client ���� I1����� 111�� ■��
❑ Commercial [ Pace ❑Other:
g2BB248
Custody Seal Present? Dyes QNo Seals Intact? ❑Yes []No
Date/tnitlals Person Examining Contents
Packing Material: ❑Bubble Wrap ❑Hubble Bags ®None ❑ Other Biological Tissue Frozen?
❑Yes []No '❑N%A
Thermometer: Type oce: OWet []Blue ❑None
i
Correction Factor -
Cooler Temp: � • Add/Subtract (°C) Ir + Temp should be above freezing to b°C
[_]Samples out of temp criteria. Samples an ice, coaling process
Cooler Ternp Corrected {°C): ; ?� has begun
USDA Regulated Soil ([] N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate From a foreign source (internationally,
nYes I)N❑ including Hawaii and Puerto Rico)? [)Yes FIN0
Comments/Discrepancy:
Chain of Custody Present?
Yes
ONO
El N/A
1.
Samples Arrived within Hold Time?
UYes
ONO
❑N/A
2.
Short Hold Time Analysis 02 hr.)?
❑Yes
[No
❑NIA
3.
Rush Turn Around Time Requested?
❑Yes
�No
❑N/A
4.
Sufficient Volume?
Yes
ONO
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
oYes
Yes
ONO
❑NO
❑N/A
[:]NIA
6.
Containers Intact?
r,
.QYes
ONO
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
ENO
❑N/A
8.
Sample labels Match COC?
-includesOate/Time/ID/Analysis Matrix:
`DYes
❑No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes
ONO
[]N/A
10.
Trip Blank Present?
Trip Blank Custody Seais Present?
❑Yes
OYes
ONO
ONO
'QN/A
[161A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOT
Person -contacted:
Prolect Manager SCURF Review:
Date-ff ime:
Lot ID of split containers:
ProlesLManagetr-SRF-Resriew: —
--
Date:
Field Data Required? []Yes ❑No
Page 15 of 17

REVISION
Page 32 of 35
*Check mark top half of box if pH and/or dechlorination is Project #
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Cofiform, TOC, Oil and Grease, DRO/8015 (water) ❑OC, LLHg
**Bottom half of box is to list number of bottles
Document Name: Document Revised: October 28, 2020
5ampie Condition Upon Recelpt(SCUR) Page 2 of 2
ceAnalytical. Document No.: Issuing Authority:
F-CMCS-0334ev.07 Pace Carolinas Quality Office
WQ#:92562485
PM: NMG Due Date: 09/28/21
CLIENT: 92-Duke Ener
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pH Adjustment Log for Preserved Samples
Sample IQ
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
Amount of Preservative
Lpt N
adjusted
added
hote:�Nheneverthere-ira-disUepancy-attecting�orCn-�-artfnna-C�mp�ianse"sampies; a-��py+�w��n-�w.��rw��r:,�,r�,i-tw++�e-�vucEn"�eru�ure-��a�.�c.rf�u�6ar��,.wx�br-{�•c.
"" -Out vriioid,�r coiTect'oreserva'trve; o6t cf temp; incorrect tonrainem' -' -
Page 16 of 17

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM REVISION
_.ouk. Enaegr Analyllcal L'atioulcry i -'- -'-'- --'-'- ---'- --'- - -' - -'- - --'-'- -'-'-' • Anal licat Laboralc "Us Only'-'-'-'- - -'-'- Page 33 of 35 1--
.f DUKE Xr.X.d.raGOal lR/dXyIrMI ; ,Orderp 9rG Matrie WATER NC x Page _7.."of _i
ENERGY. 1111.011W N.L. M1 .C, (/ ..w.ow+arr-
fMXwXVW. n. L'. mail � -�.Y �'" DISTRIBUTION O
t�Le9a.d a7.•,, Dal. I Th.. SAMPLE PROGRAM ORSG HAL to LAB, COPY to CL HNT
fa.:{rat ar>•wx Gmum Water X_ NPOES— "
{ ProJacl Nama ASHEYILLE STATE LF DETECTION PP.n. Re 'Y•"d^r Onnking Walm _ UST
E[ W7=2'1
MONITORING .._.._.._.._.._.._.._.._.._.,_.,_.._,CtiYasle._.._.._.._.._.._.._.._.._.._..r
Client BRYSOH ALLISON. BRYAN MOELLER. DEE 1 _
I O'BRIEN, JOSH STOWE, CONNOR ZAHORA 'Pace Filtration t0.45 um) I Unfiltered d FlHered
Operating Unit: AEW Proeoss:NGROWTR Account F'
09172712
j Preservative I.E XEE
i Propet AAE000315Activity 10: Facility ID:ASv - -"-" - "- Container Volume (mL) 500 300 500
TEST SIATL
ProgramlEqul4 Task CRde:ASV LF Sub•Programrraak Cad.; Container Type PET PET HOPE
{¢ Metals Pnp•60100
- - ANIONS by TRM• Ba, Be, B. Cu.
CUSIM" 10 e0mP left all a - 9056A: CI, F- F. Mn, Ni, Zn
Sample Description or ID PProPrfaNaon•rhadadanal v it TOS NO3.H-I4&H+ 60201811MS:5b,As, U
r SAMPLE ID _ CmlNction Inlannatlon HoldTin+el" Cd, Cr. Co. Pb. Se, m
NUMBER OalaTTeme _ Printed Hamre s Slgnaluu n Ste_ AandNH LT 7i0AI
.26,Z1� f��rp A5V_ 5"V-2 V70.11 " 12I I UwAr02 ZAHuO �i_ �� X I _ t t 1 0
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STATE 'DO REQUIRED.- EQUIS REQUIRED
910-111. 151is Cc#vnRJlL Z 114011LA
TOTAL#CONTAINERS I - D T C
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Total
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a
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6 2
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•7 Days
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c
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V

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM REVISION
Dub En.rgy An,lyllcal Laboralcry A na lylical Laboralary Uw Only - - " " - - ---"---- - - -�-�-Rage 34 Of 3rJ
.f DUKE N.X.)Mt1i, l IIXJdXylwll ; ,Orderp 9rG Matrix WATER Nc x Page _1.."of _I
ENERGY. 1111f14R-.rrryRd (/ a.w.o-w+.r -
fMX..011W N.L. r..rl DISTRIBUTION
Im.I „yl,u �Le9a.d a7.•X, Dal. I Th.. SAMPLE PROGRAM ORSG,NAL to LAB, COPY to CLIENT
fa.:Lral ar�wx ' ' d(.y� p�L//u �yD Gmud Water X_ NPOES—
{ Pro .cl Nam. ASHEVILLE STATE LF DETECTION Plwn.. 'V.rrd.r
E[ 1 Onnking Walm _ UST
MONITORING ._.._.._.._....... .-..--.-..-. RCRA Waste._.._.._.._.._.._.._.._.._.._..r
Client BRYSON ALLISON. BRYAN MOELLER. DEE 1 _
I O'BRIEN, JOSH STOWE, CONNOR ZAHORA 'Pace Filtration tO.45 um) I Unfiltered d FlHered
OwMing Unit: AEO0 Proeoss:NGROWTR Account F'
P9# 9172712 j Preservative ICE XEE
Prepct AA£000315 !TEST 10: Facility ID:ASv - -"-" - "- Container Volume ImL) 500 300 500
TEST SIATL
Program 1 Equl4 Tuk C.de:ASV LF 5ub•ProgranYiaak Cad.: Container Type PET PET HOPE
{¢ Metal, Prep•60100
- - ANIONS by 7RM• Ba, Be, B. Cu.
-EkCustoms do earn left all a - 9056A: CI, F" F, Mn, Ni, Zn
Sample Description or ID P PYroPrfaf. aon•rhad d,ns v �' ' TOS HO1H-I4&H+ 602p81MS: 5b, As, cmi
r SAMPLE ID _ C.INction Inlannatlon Hold Tin+el" Cd, Cr. Co. Pb. Se, m
NUMBER 0.1.TTima _ Printed Hamre . Slgnaluu n Ste_ Aandg.TNH 7 7i0A)
.26,Z�� f�ki �rp ASV_ S-2 9-?0.21 " allCuNNp2 ZAHvreii X I _ t t I 0
A5V- 5w-3 — I��I Coro+vwt 741.400
6!s'2 ASV- V-4 _ _ 1340 C&vtw rz 2AI{UtA L I 0
GlS3 ASV- LAkW -40 I42S CnHnult 24140A _" I I T n
�Y ; ASv _ Lnnw - 3 $ ISuS c►�- www
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By Date/Tim
-`57— atalrlm{�.jj
DatRrrir..
STATE 'DO REQUIRED.- EQUIS REQUIRED
910-111. 15lis Cc#vnRJs-•ZA►+oaP'
TOTAL#CONTAINERS I - D T C
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-
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Total
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6 2
e
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e 3
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n m
•7 Days
E a
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�a
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c
Other
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V

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM REVISION
Dub En.rgy An,lyllcal Laboralcry A na lylical Laboralary Uw Only - - " " - - ---"---- - - -�-�-Rage 3S Of 3rJ
.f DUKE N.X.)Mt1i, l IIXJdXylwll ; ,Orderp 9rG Matrix WATER Nc x Page _1.."of _I
ENERGY. 1111f14R-.rrryRd (/ a.w.o-w+.r -
fMX..011W N.L. r..rl DISTRIBUTION
Im.I „yl,u �Le9a.d a7.•X, Dal. I Th.. SAMPLE PROGRAM ORSG,NAL to LAB, COPY to CLIENT
fa.:Lral ar�wx ' ' d(.y� p�L//u �yD Gmud Water X_ NPOES—
{ Pro .cl Nam. ASHEVILLE STATE LF DETECTION Plwn.. 'V.rrd.r
E[ 1 Onnking Walm _ UST
MONITORING ._.._.._.._....... .-..--.-..-. RCRA Waste._.._.._.._.._.._.._.._.._.._..r
Client BRYSON ALLISON. BRYAN MOELLER. DEE 1 _
I O'BRIEN, JOSH STOWE, CONNOR ZAHORA 'Pace Filtration tO.45 um) I Unfiltered d FlHered
OwMing Unit: AEO0 Proeoss:NGROWTR Account F'
P9# 9172712 j Preservative ICE XEE
Prepct AA£000315 !TEST 10: Facility ID:ASv - -"-" - "- Container Volume ImL) 500 300 500
TEST SIATL
Program 1 Equl4 Tuk C.de:ASV LF 5ub•ProgranYiaak Cad.: Container Type PET PET HOPE
{¢ Metal, Prep•60100
- - ANIONS by 7RM• Ba, Be, B. Cu.
-EkCustoms do earn left all a - 9056A: CI, F" F, Mn, Ni, Zn
Sample Description or ID P PYroPrfaf. aon•rhad d,ns v �' ' TOS HO1H-I4&H+ 602p81MS: 5b, As, cmi
r SAMPLE ID _ C.INction Inlannatlon Hold Tin+el" Cd, Cr. Co. Pb. Se, m
NUMBER 0.1.TTima _ Printed Hamre . Slgnaluu n Ste_ Aandg.TNH 7 7i0A)
.26,Z�� f�ki �rp ASV_ S-2 9-?0.21 " allCuNNp2 ZAHvreii X I _ t t I 0
A5V- 5w-3 — I��I Coro+vwt 741.400
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�Y ; ASv _ Lnnw - 3 $ ISuS c►�- www
X
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By Date/Tim
-`57— atalrlm{�.jj
DatRrrir..
STATE 'DO REQUIRED.- EQUIS REQUIRED
910-111. 15lis Cc#vnRJs-•ZA►+oaP'
TOTAL#CONTAINERS I - D T C
Accepted
Accep77bd !/ D,telTlnre
Accapted fly;
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r
A
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0
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0
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0
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-
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0
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tX 0
0 0 0
c
Requested Turnaround
Total
0
a
21 Days
6 2
e
14 Days
e 3
C
n m
•7 Days
E a
_ m
�a
m
c
Other
'•
-Add Cost Will Apply
V

Analytical Data Review Checklist
Station
State
Sample IDs
Asheville Steam Electric Plant
NC
CB-9, 9BR, 9SL; LCS-1; LMW-1B, 1S, 213, 2T
Laboratory Name(s):
Duke, Pace
MATRICES
Lab Report Number:
Sample Receipt Date
Analysis Complete Date
Sampling Date(s)
O GW
O SO/SE
J21090369
9/22/2021
10/6/2021
9/21/2021
❑ SW
References:
NATIONAL FUNCTIONAL GUIDELINES for Inorganic Superfund Methods Data Review (EPA 2017)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Specified Methods (EPA 9056, EPA 6010, EPA 6020, EPA 7470, EPA 903.1, and EPA 904.0)
Sample Receipt & Chain of Custody
Do the Sample IDs and Laboratory Analyses recorded on the Chain -of -Custody form match the Sample IDs and
Ed yes l] No
i)
Analyses listed in the Laboratory Package?
© YES 0 No
la Do the dates and times of sampling listed on the Chain -of -Custody match the laboratory report?
Is the Sample Temperature Upon Receipt at the laboratory recorded on the Chain -of -Custody form less than 6
© YES 0 No
2) degrees Celsius? If NO, then
❑ YES ❑ NO
2a Is the presence of Wet Ice noted in the cooler? OR
❑ YES ❑ NO
2b Were the samples collected less than two hours prior to receipt at the lab?
If so, the sample temperature at the time of collection should have been recorded on the Chain -of -Custody
form to compare to the sample temperature upon receipt at the lab to demonstrate that the samples were
iced down for cooling during transport.
o YES o No
3) Was the proper sample preservation checked and documented on the Chain -of -Custody form or Sample Receipt form?
Are there any Special Notes, Exceptions, or Anomalies listed either on the Chain -of -Custody form or on the Sample
❑ YES ©No
4)
Receipt form?
Briefly describe:
❑ YES 10 NO
Was the transfer of Custody of the Samples properly documented and traceable through signature, date, and time by all
5)
persons who relinquished and/or received custody of the samples?
Cl YES Cl NO
6) Do the values for the field parameters listed on the COC match the values entered in the lab report?
N/A
Batch Quality Assurance/Quality Control (See attached List of Definitions)
7) Was the Holding Time for Analysis met for each parameter?
❑ YES o NO
N/A 7a Alkalinity, Bicarbonate, Carbonate: Analyzed within 14 days of collection
© YES ❑ NO
7b Bromide, Chloride, Fluoride, Sulfate: Analyzed within 28 days of collection
© YES ❑ NO
7c Nitrate -Nitrite: Analyzed within 28 days of collection
0 YES 0 NO
N/A 7d Chromium VI: Analyzed within 24 hours (unpreserved) / 28 days (preserved) of collection
o YES ❑ NO
7e Mercury: Analyzed within 28 days of collection (preserved)
© YES 0 NO
7f Total and Dissolved Metals: Analyzed within 6 months of collection
O YES ❑ NO
7g TSS and TDS: Analyzed within 7 days of collection
❑ YES 0 NO
N/A 7h Oil and Grease: Analyzed within 28 days of collection
❑ YES o NO
8) Are there any Qualifiers assigned by the laboratory, such as a "J" flag?
11 YES 11 NO
8a If YES, are definitions provided?

Batch Quality Assurance/Quality Control (See attached List of Definitions)
❑ YES 0 NO
Laboratory Control Sample - were any parameters flagged by the lab as being outside the limits of control in the
9)
associated laboratory control sample?
❑ YES ❑ NO
9a If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑ YES ❑ NO
9b Were the same parameters detected in the samples?
0 YES 0 No 10)
Matrix Spike Sample - did the laboratory provide matrix spike results (MS/MSD)? If so, then:
0 YES 0 NO
10a Was the original sample spiked a project sample? If not, then stop here. If so, then:
❑ YES 0 No
Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike
10b
sample? If so, list in the summary section below.
0 YES ❑ No 11)
Laboratory Duplicate Sample - did the laboratory provide duplicate sample results? If so, then:
0 YES ❑ No
11a Was the sample analyzed as a laboratory duplicate a project sample? If not, then stop here. If so, then:
Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate
❑ ves 0 No
llb sample? If so, list in the summary section below.
Field Duplicate Sample - is the relative percent difference between the original and field sample results less than 35
O YES 0 NO 12)
percent?
Field/Equipment/Trip Blanks - were any parameters detected in the associated Field/Equipment/Trip Blanks? If yes,
0 ves 0 No 13)
please include in the summary section at the end of this form.
If yes, were any target analytes detected in the samples at a concentration less than ten times the
0 YES ❑ No
13a Field/Equipment/Trip Blank concentration?
0 YES o No 14)
Were initial and continuing calibration blank information within acceptable criteria per the lab report?
0 YES 0 No 15)
Method Blank - were any parameters detected in the Method Blank(s)?
0 YES 0 No
If yes, were any target analytes detected in the samples at a concentration less than ten times the method
15a
blank concentration?
If YES, please list in the summary section below.
❑ YES 0 NO 16)
Were any reporting limits for non -detect results greater than the screening criteria?
If YES, please list in the summary section below.
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up
action with the analytical lab or field personnel must be noted in the summary section at the end of this form before the data can be approved for use by technical
leads.
Summary (include any special notes, exceptions or anomalies listed in the case narrative or discovered as a result of data validation):
- The RPD between LMW-1B and the field duplicate is greater than 35% for Nitrate as N (0.03/0.02 mg-N/L), Mercury (0.04/0.06 ug/L), Iron
(0.033/0.072 mg/L), Vanadium
(0.428/0.627 ug/L), and TDS (86/ND mg/L).
- Vanadium (0.175 ug/L) was detected in the Field Blank; Vanadium was also detected in the samples at concentrations less than lox the blank
concentration.
Review Determination:
I] USABLE 0 USABLE WITH REQUIRED ACTIONS ❑ UNUSABLE
RESOLVED
Signatures:
Date:
Technical Lead
4 1/12/2022
Data Quality Reviewer
REB 10/27/2021

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J21090369
Project Name: ASHEVILLE - ASHEVILLE STATE LF DETECTION MONITORING
Task Code: LF
Customer Name(s): B Allison ,B Moeller, J Stowe,D Obrien,C Zahora
Customer Address: Asheville Steam Station
200 CP and L Drive
Arden,NC 28704
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: & f Y pate; 10/6/2021
(Signature)plef�l ,,�L.�
Pe y ndall
Program Comments:
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 43
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 43
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2021026374
ASHEVILLE
21-Sep-21
8:50 AM
Connor Zahora
ASV_LCS-1
2021026375
ASHEVILLE
21-Sep-21
9:30 AM
Connor Zahora
ASV_LMW-1 B
2021026376
ASHEVILLE
21-Sep-21
10:30AM
Connor Zahora
ASV_LMW-1S
2021026377
ASHEVILLE
21-Sep-21
11:05 AM
Connor Zahora
ASV_LMW-2B
2021026378
ASHEVILLE
21-Sep-21
11:30AM
Connor Zahora
ASV_LMW-2T
2021026379
ASHEVILLE
21-Sep-21
12:25 PM
Connor Zahora
ASV_CB-9BR
2021026380
ASHEVILLE
21-Sep-21
12:55 PM
Connor Zahora
ASV—CB-9
2021026381
ASHEVILLE
21-Sep-21
1:35 PM
Connor Zahora
ASV_C13-9SL
2021026382
ASHEVILLE
21-Sep-21
Connor Zahora
ASV_FD-20210921-1
2021026383
ASHEVILLE
21-Sep-21
2:00 PM
Connor Zahora
ASV_FB-20210921-1400
10 Total Samples

Page 3 of 43
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 10/6/2021

Certificate of Laboratory Analysis Page 4 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV LCS-1
Sample #:
2021026374
Collection Date: 09/21/2021 08:50 AM
Loc code: ASV LCS-1
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride 30
mg/L
2
0.0154
20
EPA 9056A
09/22/2021 09:34
BGN9034
Fluoride 1.1 J
mg/L
2
0.0479
20
EPA 9056A
09/22/2021 09:34
BGN9034
Nitrate 0.96 J
mg/L
2
0.0209
20
EPA 9056A
09/22/2021 09:34
BGN9034
Nitrate as N 0.22 J
mg-N/L
0.46
0.002
20
EPA 9056A
09/22/2021 09:34
BGN9034
Sulfate 740
mg/L
20
0.0428
200
EPA 9056A
09/22/2021 09:34
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:22 JAA5429
Barium (Ba)
0.053
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
9.65
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.025
mg/L
0.01
0.004
Manganese (Mn)
1.60
mg/L
0.005
0.001
Nickel (Ni)
0.003 J
mg/L
0.005
0.001
Zinc (Zn)
0.014
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
1.87
ug/L
1
Arsenic (As)
2.36
ug/L
1
Cadmium (Cd)
0.355 J
ug/L
1
Chromium (Cr)
0.232 J
ug/L
1
Cobalt (Co)
0.715 J
ug/L
1
Lead (Pb)
0.119 J
ug/L
1
Selenium (Se)
204
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.099 J
ug/L
0.2
Vanadium (V) Low Level
1.72
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
1 SW 6010D
09/23/2021 17:21
DMFRANC
0.104
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.111
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.032
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.185
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.077
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.037
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.193
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.035
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.041
1
SW 6020B
09/24/2021 22:59
CWSPEN3
0.114
1
SW 6020B
09/24/2021 22:59
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 5 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV LMW-1 B
Sample #:
2021026375
Collection Date: 09/21/2021 09:30 AM
Loc code: ASV LMW-lB
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride
7.9
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 10:19
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 10:19
BGN9034
Nitrate
0.14
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 10:19
BGN9034
Nitrate as N
0.03
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 10:19
BGN9034
Sulfate
0.30
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 10:19
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.04 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:24 JAA5429
Barium (Ba)
0.026
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.033
mg/L
0.01
0.004
Manganese (Mn)
0.003 J
mg/L
0.005
0.001
Nickel (Ni)
0.001 J
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.225 J
ug/L
1
Cobalt (Co)
0.077 U
ug/L
1
Lead (Pb)
0.047 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.428
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
1 SW 6010D
09/24/2021 09:12
DMFRANC
0.104
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.111
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.032
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.185
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.077
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.037
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.193
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.035
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.041
1
SW 6020B
09/24/2021 21:53
CWSPEN3
0.114
1
SW 6020B
09/24/2021 21:53
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 6 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV LMW-lS
Sample #:
2021026376
Collection Date: 09/21/2021 10:30 AM
Loc code: ASV LMW-lS
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride
6.3
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 08:49
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 08:49
BGN9034
Nitrate
1.7
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 08:49
BGN9034
Nitrate as N
0.39
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 08:49
BGN9034
Sulfate
0.32
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 08:49
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:27 JAA5429
Barium (Ba)
0.042
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.481
mg/L
0.01
0.004
Manganese (Mn)
0.141
mg/L
0.005
0.001
Nickel (Ni)
0.001 J
mg/L
0.005
0.001
Zinc (Zn)
0.005 J
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.488 J
ug/L
1
Cobalt (Co)
1.25
ug/L
1
Lead (Pb)
0.158 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.047 J
ug/L
1
Thallium (TI) Low Level
0.046 J
ug/L
0.2
Vanadium (V) Low Level
0.541
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
1 SW 6010D
09/23/2021 17:52
DMFRANC
0.104
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.111
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.032
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.185
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.077
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.037
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.193
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.035
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.041
1
SW 6020B
09/24/2021 23:08
CWSPEN3
0.114
1
SW 6020B
09/24/2021 23:08
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 7 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV LMW-2B
Sample #:
2021026377
Collection Date: 09/21/2021 11:05 AM
Loc code: ASV LMW-2B
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride
8.0
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 10:49
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 10:49
BGN9034
Nitrate
1.00
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 10:49
BGN9034
Nitrate as N
0.23
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 10:49
BGN9034
Sulfate
3.2
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 10:49
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:29 JAA5429
Barium (Ba)
0.043
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.012 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.127
mg/L
0.01
0.004
Manganese (Mn)
0.008
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.127 J
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.716 J
ug/L
1
Cobalt (Co)
0.096 J
ug/L
1
Lead (Pb)
0.081 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.104 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.776
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
1 SW 6010D
09/23/2021 17:56
DMFRANC
0.104
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.111
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.032
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.185
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.077
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.037
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.193
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.035
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.041
1
SW 6020B
09/25/2021 00:15
CWSPEN3
0.114
1
SW 6020B
09/25/2021 00:15
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 8 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV LMW-2T
Sample #:
2021026378
Collection Date: 09/21/2021 11:30 AM
Loc code: ASV LMW-2T
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride
10
mg/L
0.5
0.0154
5
EPA 9056A
09/22/2021 11:50
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 11:50
BGN9034
Nitrate
2.6
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 11:50
BGN9034
Nitrate as N
0.59
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 11:50
BGN9034
Sulfate
4.9
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 11:50
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:31 JAA5429
Barium (Ba)
0.035
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.025 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.063
mg/L
0.01
0.004
Manganese (Mn)
0.028
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.062 J
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.755 J
ug/L
1
Lead (Pb)
0.088 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.356
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
1 SW 6010D
09/23/2021 18:00
DMFRANC
0.104
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.111
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.032
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.185
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.077
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.037
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.193
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.035
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.041
1
SW 6020B
09/25/2021 00:24
CWSPEN3
0.114
1
SW 6020B
09/25/2021 00:24
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 9 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV CB-9BR
Sample #:
2021026379
Collection Date: 09/21/2021 12:25 PM
Loc code: ASV CB-9BR
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride 7.6
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 11:05
BGN9034
Fluoride 0.05 J
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 11:05
BGN9034
Nitrate 0.21
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 11:05
BGN9034
Nitrate as N 0.05
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 11:05
BGN9034
Sulfate 1.5
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 11:05
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:33 JAA5429
Barium (Ba)
0.025
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.069
mg/L
0.01
0.004
Manganese (Mn)
0.053
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.077 U
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.063 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.257 J
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
1 SW 6010D
09/23/2021 18:05
DMFRANC
0.104
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.111
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.032
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.185
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.077
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.037
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.193
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.035
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.041
1
SW 6020B
09/25/2021 00:34
CWSPEN3
0.114
1
SW 6020B
09/25/2021 00:34
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 10of43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV CB-9
Sample #:
2021026380
Collection Date: 09/21/2021 12:55 PM
Loc code: ASV-CB-9
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride 6.6
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 11:20
BGN9034
Fluoride 0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 11:20
BGN9034
Nitrate 1.0
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 11:20
BGN9034
Nitrate as N 0.24
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 11:20
BGN9034
Sulfate 0.1 J
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 11:20
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:35 JAA5429
Barium (Ba)
0.027
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.079
mg/L
0.01
0.004
Manganese (Mn)
0.033
mg/L
0.005
0.001
Nickel (Ni)
0.001 J
mg/L
0.005
0.001
Zinc (Zn)
0.008
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.231 J
ug/L
1
Cobalt (Co)
0.882 J
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.084 J
ug/L
1
Thallium (TI) Low Level
0.069 J
ug/L
0.2
Vanadium (V) Low Level
0.246 J
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
1 SW 6010D
09/23/2021 18:09
DMFRANC
0.104
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.111
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.032
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.185
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.077
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.037
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.193
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.035
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.041
1
SW 6020B
09/25/2021 00:43
CWSPEN3
0.114
1
SW 6020B
09/25/2021 00:43
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 11 of43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV CB-9SL
Sample #:
2021026381
Collection Date: 09/21/2021
01:35 PM
Loc code: ASV CB-9SL
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride
7.7
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 11:35
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 11:35
BGN9034
Nitrate
0.89
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 11:35
BGN9034
Nitrate as N
0.20
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 11:35
BGN9034
Sulfate
0.26
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 11:35
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:38 JAA5429
Barium (Ba)
0.040
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.008 J
mg/L
0.01
0.004
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.559 J
ug/L
1
Cobalt (Co)
0.077 U
ug/L
1
Lead (Pb)
0.096 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.395 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.285 J
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
1 SW 6010D
09/23/2021 18:22
DMFRANC
0.104
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.111
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.032
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.185
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.077
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.037
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.193
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.035
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.041
1
SW 6020B
09/25/2021 00:52
CWSPEN3
0.114
1
SW 6020B
09/25/2021 00:52
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 12 of43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV_FD
-20210921-1 Duplicate
Sample #:
2021026382
Collection Date: 09/21/2021
Loc code: ASV FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q21090266
Chloride
7.9
mg/L
0.1
0.0154
1
EPA 9056A
09/22/2021 10:34
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/22/2021 10:34
BGN9034
Nitrate
0.1 J
mg/L
0.1
0.0209
1
EPA 9056A
09/22/2021 10:34
BGN9034
Nitrate as N
0.02 J
mg-N/L
0.023
0.002
1
EPA 9056A
09/22/2021 10:34
BGN9034
Sulfate
0.30
mg/L
0.1
0.0428
1
EPA 9056A
09/22/2021 10:34
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.06 ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q21090307
0.01 1 EPA 7470A 09/28/2021 12:40 JAA5429
Barium (Ba)
0.026
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.072
mg/L
0.01
0.004
Manganese (Mn)
0.005 J
mg/L
0.005
0.001
Nickel (Ni)
0.002 J
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.281 J
ug/L
1
Cobalt (Co)
0.104 J
ug/L
1
Lead (Pb)
0.056 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.627
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
1 SW 6010D
09/23/2021 18:26
DMFRANC
0.104
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.111
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.032
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.185
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.077
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.037
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.193
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.035
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.041
1
SW 6020B
09/25/2021 01:02
CWSPEN3
0.114
1
SW 6020B
09/25/2021 01:02
CWSPEN3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 13of43
This report shall not be reproduced, except in full.
Order # J21090369
Site: ASV FB-20210921-1400 Field Blank Sample #: 2021026383
Collection Date: 09/21/2021 02:00 PM Loc code: ASV QA Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
INORGANIC IONS BY IC - Q21090266
Chloride 0.0154 U mg/L
Fluoride 0.0479 U mg/L
Nitrate 0.0209 U mg/L
Nitrate as N 0.002 U mg-N/L
Sulfate 0.0428 U mg/L
MERCURY (COLD VAPOR) IN WATER - Q21090403
Mercury (Hg) 0.01 U ug/L
TOTAL RECOVERABLE METALS BY ICP - Q21090307
Barium (Ba)
0.002 U
mg/L
Beryllium (Be)
0.002 U
mg/L
Boron (B)
0.005 U
mg/L
Copper (Cu)
0.001 U
mg/L
Iron (Fe)
0.004 U
mg/L
Manganese (Mn)
0.001 U
mg/L
Nickel (Ni)
0.001 U
mg/L
Zinc (Zn)
0.004 U
mg/L
TOTAL RECOVERABLE METALS BY ICP-MS - Q21090315
Antimony (Sb)
0.104 U
ug/L
Arsenic (As)
0.111 U
ug/L
Cadmium (Cd)
0.032 U
ug/L
Chromium (Cr)
0.185 U
ug/L
Cobalt (Co)
0.077 U
ug/L
Lead (Pb)
0.037 U
ug/L
Selenium (Se)
0.193 U
ug/L
Silver (Ag)
0.035 U
ug/L
Thallium (TI) Low Level
0.041 U
ug/L
Vanadium (V) Low Level
0.175 J
ug/L
Method Analysis Date/Time Analyst
0.1
0.0154
1
EPA 9056A
09/22/2021 08:34
BGN9034
0.1
0.0479
1
EPA 9056A
09/22/2021 08:34
BGN9034
0.1
0.0209
1
EPA 9056A
09/22/2021 08:34
BGN9034
0.023
0.002
1
EPA 9056A
09/22/2021 08:34
BGN9034
0.1
0.0428
1
EPA 9056A
09/22/2021 08:34
BGN9034
0.05
0.01
1
EPA 7470A
09/28/2021 12:51
JAA5429
0.005
0.002
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.005
0.002
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.05
0.005
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.005
0.001
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.01
0.004
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.005
0.001
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.005
0.001
1
SW 6010D
09/23/2021 18:30
DMFRANC
0.005
0.004
1
SW 6010D
09/23/2021 18:30
DMFRANC
1
0.104
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.111
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.032
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.185
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.077
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.037
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.193
1
SW 6020B
09/25/2021 01:11
CWSPEN3
1
0.035
1
SW 6020B
09/25/2021 01:11
CWSPEN3
0.2
0.041
1
SW 6020B
09/25/2021 01:11
CWSPEN3
0.3
0.114
1
SW 6020B
09/25/2021 01:11
CWSPEN3
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 14of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090266 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
1.98
1.98
mg/L
1
0.0154
2
99
90
110
Fluoride
2.02
2.02
mg/L
1
0.0479
2
101
90
110
Nitrate
2
2
mg/L
1
0.0209
2
99.8
90
110
Sulfate
1.87
1.87
mg/L
1
0.0428
2
93.6
90
110
MS # 1
Parent Sample:
J21090369 -- 2021026376
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
Chloride
8.26
8.26
mg/L
1
0.0154
2
98.3
80
120
Fluoride
2.04
2.04
mg/L
1
0.0479
2
101
80
120
Nitrate
3.74
3.74
mg/L
1
0.0209
2
101
80
120
Sulfate
2.36
2.36
mg/L
1
0.0428
2
102
80
120
MSD # 1
Parent Sample:
J21090369 -- 2021026376
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
8.23
8.23
mg/L
1
0.0154
2
96.9
80
120
1.49
Fluoride
2.03
2.03
mg/L
1
0.0479
2
99.7
80
120
0.849
Nitrate
3.72
3.72
mg/L
1
0.0209
2
99.5
80
120
1.05
Sulfate
2.35
2.35
mg/L
1
0.0428
2
101
80
120
0.641

Certificate of Laboratory Analysis Page 15of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090403 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.022
-0.022
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.021
-0.021
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.019
-0.019
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.02
-0.02
ug/L
1
0.01
0.05
< MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.021
-0.021
ug/L
1
0.01
0.05
< MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.019
-0.019
ug/L
1
0.01
0.05
< MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.021
-0.021
ug/L
1
0.01
0.05
< MDL
Blank # 8
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.021
-0.021
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.82
1.82
ug/L
1
0.01
2
91.3
85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.82
1.82
ug/L
1
0.01
2
91.2
85
115
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
1.78
1.78
ug/L
1
0.01
2
89.3
85
115

Certificate of Laboratory Analysis Page 16 of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090403 HG 7470 MERCURY (COLD VAPOR) IN WATER
LCS # 4
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.81
1.81
ug/L
1
0.01
2
90.7
85 115
MS # 1
Parent Sample:
J21090266 -- 2021025695
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
105
75 125
MSD # 1
Parent Sample:
J21090266 -- 2021025695
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.986
0.986
ug/L
1
0.01
1
98.6
75 125 6.38
MS # 2
Parent Sample:
J21090266 -- 2021025705
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
105
75 125
MSD # 2
Parent Sample:
J21090266 -- 2021025705
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
102
75 125 3
MS # 3
Parent Sample:
J21090266 -- 2021025715
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
101
75 125
MSD # 3
Parent Sample:
J21090266 -- 2021025715
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
101
75 125 0.197
MS # 4
Parent Sample:
J21090266 -- 2021025725
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.99
0.99
ug/L
1
0.01
1
99
75 125
MSD # 4
Parent Sample:
J21090266 -- 2021025725
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.985
0.985
ug/L
1
0.01
1
98.5
75 125 0.506
MS # 5
Parent Sample:
J21090337 -- 2021026178
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.995
0.995
ug/L
1
0.01
1
99.5
75 125
MSD # 5
Parent Sample:
J21090337 -- 2021026178
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.993
0.993
ug/L
1
0.01
1
99.3
75 125 0.201

Certificate of Laboratory Analysis Page 17 of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090403 HG 7470 MERCURY (COLD VAPOR) IN WATER
MS # 6
MSD # 6
MS # 7
MSD # 7
Parameter Measured Final
Mercury (Hg) 1.01 1.01
Parameter Measured Final
Mercury (Hg) 1.01 1.01
Parameter Measured Final
Mercury (Hg) 0.991 0.991
Parameter Measured Final
Mercury (Hg) 0.974 0.974
Parent Sample:
J21090337 -- 2021026188
Units
Dil
MDL
Spike
% Recovery
LCL UCL
ug/L
1
0.01
1
101
75 125
Parent Sample:
J21090337 -- 2021026188
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
ug/L
1
0.01
1
101
75 125 0.197
Parent Sample:
J21090369 -- 2021026383
Units
Dil
MDL
Spike
% Recovery
LCL UCL
ug/L
1
0.01
1
99.1
75 125
Parent Sample:
J21090369 -- 2021026383
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
ug/L
1
0.01
1
97.4
75 125 1.73
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 18of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090307 1CP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000335
-0.000335
mg/L
1
0.002
0.005
< MDL
Beryllium (Be)
0
0
mg/L
1
0.002
0.005
< MDL
Boron (B)
-0.000804
-0.000804
mg/L
1
0.005
0.05
< MDL
Copper (Cu)
0.00042
0.00042
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
-0.000144
-0.000144
mg/L
1
0.004
0.01
< MDL
Manganese (Mn)
-0.00039
-0.00039
mg/L
1
0.001
0.005
< MDL
Nickel (Ni)
-0.000266
-0.000266
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000424
-0.000424
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
4.96
4.96
mg/L
1
0.002
5
99.1
80
120
Beryllium (Be)
4.98
4.98
mg/L
1
0.002
5
99.6
80
120
Boron (B)
4.83
4.83
mg/L
1
0.005
5
96.7
80
120
Copper (Cu)
4.89
4.89
mg/L
1
0.001
5
97.8
80
120
Iron (Fe)
4.93
4.93
mg/L
1
0.004
5
98.5
80
120
Manganese (Mn)
4.96
4.96
mg/L
1
0.001
5
99.1
80
120
Nickel (Ni)
4.99
4.99
mg/L
1
0.001
5
99.7
80
120
Zinc (Zn)
5.02
5.02
mg/L
1
0.004
5
100
80
120
MS # 1
Parent Sample:
J21090369
-- 2021026374
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.04
5.04
mg/L
1
0.002
5
99.7
75
125
Beryllium (Be)
4.91
4.91
mg/L
1
0.002
5
98.2
75
125
Boron (B)
14.5
14.5
mg/L
1
0.005
5
98
75
125
Copper (Cu)
4.87
4.87
mg/L
1
0.001
5
97.4
75
125
Iron (Fe)
4.93
4.93
mg/L
1
0.004
5
98.2
75
125
Manganese (Mn)
6.5
6.5
mg/L
1
0.001
5
97.9
75
125
Nickel (Ni)
4.75
4.75
mg/L
1
0.001
5
95
75
125
Zinc (Zn)
4.84
4.84
mg/L
1
0.004
5
96.5
75
125
MSD # 1
Parent Sample:
J21090369
-- 2021026374
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.04
5.04
mg/L
1
0.002
5
99.8
75
125
0.119
Beryllium (Be)
4.89
4.89
mg/L
1
0.002
5
97.9
75
125
0.335
Boron (B)
14.5
14.5
mg/L
1
0.005
5
97.7
75
125
0.11
Copper (Cu)
4.9
4.9
mg/L
1
0.001
5
98
75
125
0.594
Iron (Fe)
4.96
4.96
mg/L
1
0.004
5
98.6
75
125
0.425
Manganese (Mn)
6.48
6.48
mg/L
1
0.001
5
97.6
75
125
0.247
Nickel (Ni)
4.76
4.76
mg/L
1
0.001
5
95.2
75
125
0.252
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 19of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090307 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J21090369 -- 2021026374
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.83 4.83 mg/L 1 0.004 5 96.3 75 125 0.207

Certificate of Laboratory Analysis Page 20 of 43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.008
-0.008
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.005
-0.005
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.001
0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.043
-0.043
ug/L
1
0.185
1
< MDL
Cobalt (Co)
-0.004
-0.004
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.008
0.008
ug/L
1
0.037
1
< MDL
Selenium (Se)
-0.146
-0.146
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.002
0.002
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.001
-0.001
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.026
0.026
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
46.7
46.7
ug/L
1
0.104
50
93.4
80
120
Arsenic (As)
47.7
47.7
ug/L
1
0.111
50
95.4
80
120
Cadmium (Cd)
47.4
47.4
ug/L
1
0.032
50
94.8
80
120
Chromium (Cr)
47.6
47.6
ug/L
1
0.185
50
95.2
80
120
Cobalt (Co)
47.1
47.1
ug/L
1
0.077
50
94.2
80
120
Lead (Pb)
48.1
48.1
ug/L
1
0.037
50
96.2
80
120
Selenium (Se)
47.9
47.9
ug/L
1
0.193
50
95.9
80
120
Silver (Ag)
49.3
49.3
ug/L
1
0.035
50
98.6
80
120
Thallium (TI) Low Level
48.1
48.1
ug/L
1
0.041
50
96.2
80
120
Vanadium (V) Low Level
47.3
47.3
ug/L
1
0.114
50
94.5
80
120
MS # 1
Parent Sample:
J21090369 -- 2021026375
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
46.4
46.4
ug/L
1
0.104
50
92.7
75
125
Arsenic (As)
47.1
47.1
ug/L
1
0.111
50
94.1
75
125
Cadmium (Cd)
47.4
47.4
ug/L
1
0.032
50
94.8
75
125
Chromium (Cr)
47.1
47.1
ug/L
1
0.185
50
93.7
75
125
Cobalt (Co)
45.9
45.9
ug/L
1
0.077
50
91.8
75
125
Lead (Pb)
47.6
47.6
ug/L
1
0.037
50
95
75
125
Selenium (Se)
47.7
47.7
ug/L
1
0.193
50
95.5
75
125
Silver (Ag)
48.4
48.4
ug/L
1
0.035
50
96.7
75
125
Thallium (TI) Low Level
46.8
46.8
ug/L
1
0.041
50
93.5
75
125
Vanadium (V) Low Level
47.6
47.6
ug/L
1
0.114
50
94.4
75
125
MSD # 1
Parent Sample:
J21090369 -- 2021026375
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Antimony (Sb)
47.3
47.3
ug/L
1
0.104
50
94.7
75
125 2.12
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page21 of43
This report shall not be reproduced, except in full.
Order # J21090369
Level II QC Summary
Q21090315 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Arsenic (As)
47.3
47.3
ug/L
1
0.111
Cadmium (Cd)
47.5
47.5
ug/L
1
0.032
Chromium (Cr)
47.4
47.4
ug/L
1
0.185
Cobalt (Co)
46.6
46.6
ug/L
1
0.077
Lead (Pb)
47.9
47.9
ug/L
1
0.037
Selenium (Se)
48.3
48.3
ug/L
1
0.193
Silver (Ag)
49
49
ug/L
1
0.035
Thallium (TI) Low Level
47.9
47.9
ug/L
1
0.041
Vanadium (V) Low Level
47.9
47.9
ug/L
1
0.114
Parent Sample:
J21090369 -- 2021026375
Spike
% Recovery
LCL
UCL
RPD
50
94.6
75
125
0.492
50
95
75
125
0.173
50
94.4
75
125
0.714
50
93.1
75
125
1.43
50
95.7
75
125
0.717
50
96.6
75
125
1.18
50
98
75
125
1.32
50
95.7
75
125
2.38
50
95
75
125
0.659
Qualifier

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1098 tl929601e. Suite 100
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September 28, 2021
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J21090369 ASV LF
Pace Project No.: 92562787
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on September 22, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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Project: J21090369 ASV LF
Pace Project No.: 92562787
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J21090369 ASV LF
Pace Project No.: 92562787
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92562787001
LCS-1
Water
09/21/2108:50
09/22/21 14:30
92562787002
LMW-1B
Water
09/21/2109:30
09/22/21 14:30
92562787003
LMW-1S
Water
09/21/2110:30
09/22/21 14:30
92562787004
LMW-213
Water
09/21/2111:05
09/22/21 14:30
92562787005
LMW-2T
Water
09/21/21 11:30
09/22/21 14:30
92562787006
C13-913R
Water
09/21/2112:25
09/22/21 14:30
92562787007
C13-9
Water
09/21/2112:55
09/22/21 14:30
92562787008
C13-9SL
Water
09/21/2113:35
09/22/21 14:30
92562787009
ASV FD-20210921-1
Water
09/21/21 00:00
09/22/21 14:30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 3 of 21

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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J21090369 ASV LF
92562787
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92562787001
LCS-1
SM 2540C-2011
ZMC
1
PASI-A
92562787002
LMW-1B
SM 2540C-2011
ZMC
1
PASI-A
92562787003
LMW-1S
SM 2540C-2011
ZMC
1
PASI-A
92562787004
LMW-213
SM 2540C-2011
ZMC
1
PASI-A
92562787005
LMW-2T
SM 2540C-2011
ZMC
1
PASI-A
92562787006
C13-913R
SM 2540C-2011
ZMC
1
PASI-A
92562787007
C13-9
SM 2540C-2011
ZMC
1
PASI-A
92562787008
C13-9SL
SM 2540C-2011
ZMC
1
PASI-A
92562787009
ASV FD-20210921-1
SM 2540C-2011
ZMC
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J21090369 ASV LF
92562787
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92562787001
LCS-1
SM 2540C-2011
Total Dissolved Solids
1350
mg/L
50.0
09/23/21 17:59
92562787002
LMW-1B
SM 2540C-2011
Total Dissolved Solids
86.0
mg/L
25.0
09/23/21 17:59
92562787003
LMWA S
SM 2540C-2011
Total Dissolved Solids
36.0
mg/L
25.0
09/23/21 17:59
92562787004
LMW-26
SM 2540C-2011
Total Dissolved Solids
53.0
mg/L
25.0
09/23/21 17:59
92562787005
LMW-2T
SM 2540C-2011
Total Dissolved Solids
28.0
mg/L
25.0
09/23/21 17:59
92562787006
C13-96R
SM 2540C-2011
Total Dissolved Solids
81.0
mg/L
25.0
09/23/21 18:01
92562787008
CB-9SL
SM 2540C-2011
Total Dissolved Solids
53.0
mg/L
25.0
09/23/21 18:01
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J21090369 ASV LF
Pace Project No.: 92562787
Method: SM 2540C-2011
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: September 28, 2021
General Information:
9 samples were analyzed for SM 2540C-2011 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: LCS-1 Lab ID: 92562787001 Collected: 09/21/21 08:50 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 1350 mg/L 50.0 50.0 1 09/23/21 17:59
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: LMW-113 Lab ID: 92562787002 Collected: 09/21/21 09:30 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 86.0 mg/L 25.0 25.0 1 09/23/21 17:59
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: LMW-1S Lab ID: 92562787003 Collected: 09/21/21 10:30 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 36.0 mg/L 25.0 25.0 1 09/23/21 17:59
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: LMW-213 Lab ID: 92562787004 Collected: 09/21/21 11:05 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 53.0 mg/L 25.0 25.0 1 09/23/21 17:59
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: LMW-2T Lab ID: 92562787005 Collected: 09/21/21 11:30 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 28.0 mg/L 25.0 25.0 1 09/23/21 17:59
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: C13-913R Lab ID: 92562787006 Collected: 09/21/21 12:25 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 81.0 mg/L 25.0 25.0 1 09/23/21 18:01
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 21

leAnalyiical
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098�lS49601e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: C13-9 Lab ID: 92562787007 Collected: 09/21/21 12:55 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids ND mg/L 25.0 25.0 1 09/23/21 18:01
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 21

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098� ipoW601e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: C13-9SL Lab ID: 92562787008 Collected: 09/21/21 13:35 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids 53.0 mg/L 25.0 25.0 1 09/23/21 18:01
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 21

leAnalyiical
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Pace Analytical Services, LLC
098� i�W601e. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J21090369 ASV LF
Pace Project No.: 92562787
Sample: ASV_FD-20210921-1 Lab ID: 92562787009 Collected: 09/21/21 00:00 Received: 09/22/21 14:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids ND mg/L 25.0 25.0 1 09/23/21 18:01
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 21

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[phone]
QUALITY CONTROL DATA
Project: J21090369 ASV LF
Pace Project No.: 92562787
QC Batch: 649098 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92562787001, 92562787002, 92562787003, 92562787004, 92562787005, 92562787006, 92562787007,
92562787008,92562787009
METHOD BLANK: 3404746 Matrix: Water
Associated Lab Samples: 92562787001, 92562787002, 92562787003, 92562787004, 92562787005, 92562787006, 92562787007,
92562787008,92562787009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 09/23/21 17:54
LABORATORY CONTROL SAMPLE:
3404747
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
244 97
90-110
SAMPLE DUPLICATE: 3404748
92562663001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
2510
2550
2 25
SAMPLE DUPLICATE: 3404749
92562787002
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
86.0
85.0
1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/28/2021 03:25 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 21

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098� �gW601e. Suite 100
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[phone]
QUALIFIERS
Project: J21090369 ASV LF
Pace Project No.: 92562787
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/28/2021 03:25 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 21

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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J21090369 ASV LF
Pace Project No.: 92562787
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92562787001
LCS-1
SM
2540C-2011
649098
92562787002
LMW-1 B
SM
2540C-2011
649098
92562787003
LMW-1S
SM
2540C-2011
649098
92562787004
LMW-2B
SM
2540C-2011
649098
92562787005
LMW-2T
SM
2540C-2011
649098
92562787006
CB-9BR
SM
2540C-2011
649098
92562787007
CB-9
SM
2540C-2011
649098
92562787008
CB-9SL
SM
2540C-2011
649098
92562787009
ASV FD-20210921-1
SM
2540C-2011
649098
Date: 09/28/2021 03:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 18 of 21

Document Name: Document Revised: October 28, 2 of 43
Sample Condition Upon Receipt(SCUR) Page 1 of 2
acaAnalylrcal Document No.: Issuing Authority:
F-CAR-CS-033-Rev,07 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ HuntersvilleN Raleigh[] Mechanicsvlll 7 Atlanta) Worne— MI-F-1
ConditionSample Client Name!: W0# : 92562787
Upon ReceiptProject N:
Courier: ❑Fe�&�P 5 ❑u5P5 ❑Client
❑ Commercial 2pace ❑Other; 92362787
Custody Seal Present? j[:ks ❑No Seals Intact? ❑Yes ❑No
Date/tnitlals Person Examining Contents: , 24
Packing Material: ❑Bubble Wrap ❑Elubble Bags one
❑ Other Biological Tissue Frozen?
Thermometer: []Yes []No ❑N/A
ype o re: et []Blue ❑None
Correction Factor:
Cooler Temp; Add/Subtract VC) Temp should be above freezing to VC
I ❑Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected ('C): has begun
USDA Regulated Soil (❑ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples orlgfnate From a foreign source linrernationafly,
Yes o includingbiawau and Puerto RicMl? []Yes Dee
Chain of Custody Present?
s
❑No
❑N/A
1.
Samples Arrived within Hold Time?
Yes
❑NC
❑N/A
2.
Short Hold Time Analysis k02 hr.)?
Dyes
ONG
❑N/A
3.
Rush Turn Around Time Requested?
[--]Yes
ao
❑N/A
4.
Sufficient Volume?
es
❑No
❑N/A
5.
Correct Containers Used?
,Yes
[]No
❑N/A
6.
-Pace Containers Used?
Oyes
o
[]N/A
Containers Intact?
_P�es
No
❑N/A
7.
Dissolved analysis; Samples Field Filtered?
❑Yes
[]No
A
B.
Sample Labels Match COC7
i 3r�
❑No
❑H/A
9.
-Includes Date/Tlme/ID/Analysis Matrix:
Headspace in VOA Vials {>5-6mm)?
ClYes
❑No
2KIA
10.
Trip Blank Present?
❑Yes
❑No
N/A
11.
Trip Blank Custody Seals Present?
Dyes
❑No
[24/A
COMMENTS/SAMPLE DISCREPANCY
Lot ID of splitcontainers:
CLIENT NOTIFICATION/RESOLUTION
Field Data Re4ulred? ❑Yes [:)No
Person -cunt -acted DateMme:
Project Manager SCURF Review: Date:
Project Manager SRF Review: date.
Page 19 of 21

Page 41 of 43
Oocument Name:
b Sample Condition Upon Res
Document No-:
`Check mark top half of box if pH and/or de.chlorination is Project #
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/SO]S (water) DOC, LLHg
"Bottom half of box is to list number of bottles
Document Revised: October 28, 2020
Page 2 of 2
Issuing Authority:
Pace Carolinas Qualitv office
W0#:92562787
PM: NMG Due Date: 09/29/21
CLIENT: 92-Duke Ener
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pH Adjustment Log for Preserved Samples
Sample fP
Type of Preservadve
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot q
k
M1ioie:-Wheneverther�is-a-dis[repan[y-affectingNortlr�-aralina• -0rnplianee-iarnples; asopy-.3F-Fn15-Form-w+t�a�52n[-dowhe-Nact•hEar4llna-DEJiNfi_Gerti%6atipn-Ofil6e-(l.e,
of hdrd,incorFed terng, incorrect containers:
Page 20 of 21

n�ka! i er Anal CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 42 of 43
(DUKE 0Y wl�al�.Ar;e;afnry-„ - - ---------- - - ----- -- - - --- --- -
Mul c,4r Ncosgz to„u.grh� ,aril I I Order #
Ankf [ic:d Laboraeo Vae Onl -
-• naa¢ Ha4x• herry Ntl N
ENERGY uxr.vllle. H r. i¢a,a S,Zt� Sd �4y Matrix WATER - o
.., ,,,.. n,�oM.n,.n 1, m n... Page i - of -I. ,
Pwler�-sz�s = ; �uuod By I DISTRIBUTION N
o¢m R Ty+. sc
- L _ -,- -._.tM:LrF±l9nanu 47/ j Ur cT.�•. SAMPLE PROGRAM -__ -- - -... f ORIGINAL to LAB. COPY to CUNT
P+aluei Nama ASHEVlLLf STATE LF DETECTION pl�.nu Hn iVonrinrZ % L/ a"U Giournl WotS R_ - MONITORING NPDES _ r
_ Client BRYSON ALLISON, BRYAN MOELLER. DEE �•.. i! iJrinklnq Wafm UST
—t codt?rr Tani o c RCRA Wasie .
O'BRIEN, JOSH 574WE, CONNOR ZAHpRA N
OPgraun0 Vnd: AE00 Prgcess:NGROWTR .Account I'-l" Fr•' JS
.45 uml 13 .Unfiltered
" b Filtered
Project: AAE000315 Acbvdy ID: Facility ID:ASV r. ,fir+��-,.rvative iCE ice
Program! EO-IS Task Codn:ASV Lr TEST SFTE
Sob-PrgOra frank Cods: 1 72 7 1 2 e (mL) S00 300
500
r Type PET PET HDPE
- ANIONS by Mgtale Pr¢P-6010D
TRMt Ba, a. B, Cu,
_ Sample Description or 10 Cnctam«r ro comprePo olr approprHro non -rho w 9aseA: CI. F.c j TOS N Fa, Mn, Nl. Zn
5AMPLE 14 p3-N�148-Hr 60206 WS: Sh, As.oNUMBER Codachen INermallana Hord 71ms , 7 Cd, Cr. Co, Pb, Sn,--"--I - jhte T1mr Pnnled Name504 Ag. TgLLj, V1LLj,,26jf�Z '�V_�GC�— and H 7470ASV/ JCfINHI�+(.2Riipgjl 7s~ A5v_ l Mw - I Y -074 A5V_ LPAVJILL
x 4)-V7, A5v_ BMW -2_'_+ )79.it5V — I',. x Alov,
43gt; AS'v_ C6 SL
G � AV2oZIp921- IW�
Duplicate
Field Blank
Ely DahhlTimn
STATE EDD REQUIRED ! EQUFS REQUIRED
t-21-21 — �onr�wi:L7Aaro
1-'21-21 (Kto Ppnrrvu2 _Z4k40&A
Arcgj tw By: ---
arPlgd By;
Accnp!«d By: ~
Soa_l_-011Lock Op-n.d By
C
TOTAL 0 CONTAINERS
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I
I ,
I 0 �
0 0 0 0 B 0 0 0- D 0 0 0 0 0
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DatglTlmx
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Requested Turnaround
Total
T
21 Days.—
_b C
4 V
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14 Days _ _ __ _
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'7 Days---
p
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_
Add. Cost Will Apply

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
-g-A-' '---- - -
Duk. Energy Analplcat Labor+tort Ana ical LaberalO Use On " " - - - - - - - -- - -"Page 43 Of 43
DUKE M.e cad. uddw iu-od e.INrr
tu»n.e...r«raa , ;Order0 S2 C :Matrb; WATER ,„- _, x Page-1-of 1
ENERGY t ••M•. n P n•te ^�Q_�G_7 - DISTRIBUTION
Pral.cl Name ASH EVILLE STATE LF DETECTION =�� r•.
MONITORING
Client BRVSON ALLISON, BRYAN MOELLER, DEE
O'BRIEN, JOSH STOWE, CONNOR YAHORA
OPSMUng Unit: AEOO IProc•ss:NGRDWFR Account:
Pro(act: AAE000315 l4ctivity to: Facility ID:ASV
'TEST SIATE
Program r EcuiS Task Codr.ASV LF Sub-PtogramlT.sk Coda:
r _SAMPLE
I Sample Description or ID
r
10
NUMBER r
.Zd1/Ip2.4 3 2,(i
ASv- LCS - t
G 373--
AW_ L1Aw - i 5
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A5V- LMW-15
4377;
A5u—LMVJ-2
— 43.7$;
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437 t :
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:Legged Br pap a T' • SAMPLE PROGRAM i ORIii1NAL tO LAB COPY to CL-ENT
F,72II I 625b Ground Water X NPOES
;v.nd.r Onnkny Wale: UST
RCRA Waste
P4Y`Filtration (0.45 um) - 0 Unfiltered
ace II Filtered
Preservative ICE ICE
I Container Volume (mt} 500 300 500
I} s
Container Type PET PET HOPE I
Customer to CMPlel. -U OPPrOPrfar. non-shadod areal
collecitun Inla matlen
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IDS
ANIONS by
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NO2•N (4a�Nr
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Fe, Mn, Ni. Z.
60208IMS: Sb, Aa,
i
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+
504
Ag, TIjLLI, VfLLI,
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and 6r 747OA
o
TOTAL a CONTAINERS r 4 0 0 e 1- 0 DD-'- e��- it yf
Requested Turnaround Totslj e
21 Days
O IAcupbd By: i ifirat�urfime Sf a a p�
F
a 14 Days
0410alm,r Sealed/Lock Opened BY OaUlTlme C a -
�Z� •7 Days
m
STATE -DO REQUIRED 1 EQUIS REQUIRED o 'Other _
n I ' Add Cost 4V.n Apply
.Prod By: