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HomeMy WebLinkAbout9203_Wake_Feltonsville_MSWLF_Oct21GW_FID1636860_20220119Closed Feltonsville Landfill Facility Permit No. 9203- MSWLF-1980 Semi -Annual Sampling Report (October 2021 Sampling Event) Wake County Report Prepared January 2022 WAKE COUNTY NORTH CAROLI NA ENR USE ONLY: I I LIPaper Report ❑Electronic Data - Email CD data loaded: Yes I No Doc/Event #: NC ❑ENR i IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are T_ available for inspection and examination by any person upon request (NC General Statute 132-6), Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturaily occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporling limits. Attach a notification table of any methane gas vaivas that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 138 .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Sand Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Consultant - CDM Smith Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address.: Name: Mathew F. Colone Phone: 1919} 325-3500 E-mail: colonemf(utcdms-mith.com_ - NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Wake County - Closed 6000 Old Smithfield Road 9203-MSWLF- .0500 and .1600 October 18-21, 2021 Feltonsville Landfill Apex, North Carolina 27539 1980 Environmental Status: (Check all that apply) ❑ InitiaVSackground Monitoring ^_j Defection Monitoring ❑ Assessment Monitoring ❑X Corrective Action TTe of data submitted: (Check all that apply) x Groundwater monitoring data from monitoring wells Methane monitoring data - EVO injection performed March 2013 gas - Performance monitoring Groundwater monitoring data from private water supply wells ❑X Corrective action data (specify) - MNA data Leachate monitoring data Other{specify} x Surface water monitoring data Notification attached? No. No groundwater or surface water standards were exceeded. x Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 28 surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the hest of my knowledge, the information repotted and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Mathew F. Colone Consultant 919 325-3500 Facii' epr sent e a e [Print] Title (Area Code) Telephone Number 1 /19/2022 Affix NC nsedl Pr e ` ealcgist Seal - 1`-` Signature Date ^, 5400 Glenwood %venue, Suite 40_0, Raleigh -, _North Carolina 27612 Facility Representative Address F-0412 ,ss NC PE Finn License Number (if applicable effective May 1, 2009) s Revised 612009 2 �� smith 5400 Glenwood Ave, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 January 19, 2022 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: October 2021 Semi -Annual Groundwater Sampling Report Closed Feltonsville Landfill - Wake County Facility Permit No. 9203-MSWLF-1980 Dear Ms. Drummond: CDM Smith Inc., on behalf of Wake County, is submitting an electronic copy of the October 2021 semi- annual sampling event report. This letter report presents the results of the semi-annual sampling event that was recently completed at the Closed Feltonsville Landfill (Site) and constitutes the second semi- annual sampling event for 2021. The current groundwater monitoring network consists of the following wells: MW-2, -4, -6, -8, -9, -10, -11, -12, -13, -14, -15, -16, -17, -18, -19, -20, -21, -22, -23, -24, -25, -26, -27, -28, and -29, and surface water sampling locations SW-1, -2, and -3. Monitoring wells MW-2, -6, -8, -9, -10, -11, -12, -13, -14, -15, -16, -17, -18, -19, -20, -28, and -29 monitor the Site. The remaining wells (i.e., MW-4, -21, -22, -23, -24, -25, -26, and -27) monitor the old cells located in the back of the property. Field activities, sampling results for all wells and surface water locations, an evaluation of the groundwater corrective action effectiveness, and recommendations are discussed below. Field Activities Groundwater and surface water samples were collected from the Site on October 18-21, 2021, except for SW-2, which was dry during this sampling event. Monitoring well and surface water sample locations are shown on Figure 1. Construction details for each monitoring well are summarized in Table 1. Samples were collected from the monitoring wells by use of a peristaltic pump or disposable, laboratory decontaminated bailer. Groundwater elevations were measured at each well prior to sampling on October 18, 2021, using an electronic water level indicator with an accuracy of 0.01 feet and are presented in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are shown on Figure 1. The groundwater elevations and potentiometric contours were also used to estimate groundwater velocities at each well as presented in Table 2. 0 WATER + ENVIRONMENT+ TRANSPORTATION+ ENERGY + FACILITIES smith Ms. Jaclynne Drummond January 19, 2022 Page 2 After depth to groundwater was determined, a minimum of three well volumes of water were removed from each well prior to sampling to provide fresh formation water within the well water column. Each well volume was measured in the field for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-reduction potential using a YSI-556 multi -parameter water quality meter and a HANNA HI 98703 turbidity meter. Wells that had elevated turbidity (i.e., greater than 10 Nephelometric Turbidity Units (NTUs)) were allowed to stabilize prior to sample collection. The water quality parameters at the time of sampling are provided in Table 3. Alternate Source Demonstration Analytical data was collected from the Site's background monitoring well, MW-2, on a quarterly basis from January 2018 to April 2020 to determine if the metals exceeding the NCAC 02L .0202 (NC 2L) Groundwater Standards or Interim Maximum Allowable Concentrations (IMACs) were due to naturally occurring background concentrations or a release from the landfill. Based on statistical analysis, historical detections of metals above their respective NC 2L Groundwater Standards or IMACs were determined to be indicative of naturally occurring background concentrations instead of a release from the landfill. Future metal detections will be evaluated, and an Alternate Source Demonstration will be submitted to the North Carolina Department of Environmental Quality's Solid Waste Section (SWS) if there are constant detections of metals exceeding their NC 2L Groundwater Standards or IMACs. Sampling Results Groundwater and surface water samples were analyzed by Pace Analytical Services, LLC, located in West Columbia, South Carolina, for the North Carolina Appendix I volatile organic compounds (VOCs) plus dichlorodifluoromethane and Appendix I metals plus mercury. Additional samples were collected from select monitoring wells to evaluate natural attenuation and the effectiveness of the corrective action. Results of the additional sampling and an evaluation of natural attenuation are discussed in the next section of this report. In a letter dated May 29, 2018, the SWS stated that all groundwater and surface water samples collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On June 26, 2019, the SWS approved the removal of 1,4-dioxane from the sampling program for all monitoring wells and surface water locations, with the exceptions of MW-6, -9, -10, -11, -12, -13, -14, -15, -17, -18, -24, -25, -26, -27, and -29, because of two non -detect events (November 2018 and April 2019). Samples were collected from the monitoring wells requiring the 1,4-dioxane analysis during the October 2021 semi-annual sampling event and analyzed for 1,4-dioxane. Sample results are provided below. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the laboratory limit of quantitation (LOQ). All monitoring wells for the Site had detections of analytes above the MDL but below the LOQ that were qualified as estimated or "J" flags. 0 smith Ms. Jaclynne Drummond January 19, 2022 Page 3 In samples collected from MW-2, a detection of chloride had a "D" flag, indicating that the sample was run at a dilution greater than one. In MW-9, detections of methane also had "D" flags. Additionally, detections of barium in samples collected from MW-6, -9, -10, -13, -22, and -25 had "D" flags. In samples collected from MW-9 and -10, detections of biochemical oxygen (BOD) demand had "7" flags, indicating that the seed correction factor was out of range. BOD also had "1" flags in samples collected from MW-9 and -10, indicating that result should be used for estimation purposes. In samples collected from MW-13, a detection of nitrate had "B," "H," and "D" flags. A "B" flag indicates that the analyte was detected in the method blank, and an "H" flag indicates that the analyte was analyzed outside of its hold time. In samples collected from MW-8, a detection of sodium had an "S" flag, indicating a matrix spike/matrix spike duplicate failure during analysis. MW-10 and -19 also had detections of sodium with "D" flags. The following list indicates the analytes detected above the LOQ at each sampling location. No "J" flag detections are provided. Underlined groundwater analytes exceeded the NC 2L Groundwater Standard or IMAC. Underlined surface water analytes exceeded the 15A NCAC 02B or North Carolina In -Stream Target Value Surface Water Quality Standard for Class C Waters (NC 2B Surface Water Standards). A complete summary of all detected and estimated concentrations for the November 2011 through the October 2021 sampling events is provided in Table 4. Laboratory data reports are provided in Appendix A. MW-2 (Background) Metals: Barium Volatile Organic Compounds: Chloroform M W-4 Metals: Barium Volatile Organic Compounds: Dichlorofluoromethane, 1,1-Dichloroethane, cis-1,2-Dichloroethene MW-6 Metals: Arsenic, Barium, Cobalt, Nickel Volatile Organic Compounds: Chlorobenzene, Chloroethane, 1,1-Dichloroethane, cis-1,2-Dichloethene, 1,4-Dioxane MW-8 Inorganics: Barium, Nickel, Sodium, Vanadium, Total Dissolved Solids (TDS) Volatile Organic Compounds: Dichlorofluoromethane, 1,1-Dichloroethane, Trichlorofluoromethane co smith Ms. Jaclynne Drummond January 19, 2022 Page 4 MW-9 Inorganics: Arsenic, Barium, Cadmium, Cobalt, Copper, Lead, Nickel, Sodium, Zinc, TDS Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene, 1,1-Dichloroethane, 1,4-Dioxane MW-10 Inorganics: Arsenic, Barium, Cobalt, Nickel, Sodium, TDS Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene, 1,1-Dichloroethane, 1,4-Dioxane, Vinyl Chloride MW-11 Metals: Barium Volatile Organic Compounds: None Detected MW-12 Metals: Arsenic, Barium Volatile Organic Compounds: 1,4-Dioxane MW-13 Metals: Barium, Cobalt, Mercury, Nickel, Zinc Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane MW-14 Metals: Barium, Chromium, Mercury, Nickel Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane MW-15 Metals: Barium, Nickel Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane MW-16 Metals: Arsenic, Barium, Nickel Volatile Organic Compounds: Benzene, Chloroethane, Dichlorofluoromethane, 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Tetrachloroethene, Trichloroethene MW-17 Metals: Arsenic, Barium, Cobalt, Nickel Volatile Organic Compounds: Chloroethane, 1,1-Dichloroethane, cis-1,2-Dichloroethene, 1,4-Dioxane co smith Ms. Jaclynne Drummond January 19, 2022 Page 5 MW-18 Metals: Arsenic, Barium, Nickel Volatile Organic Compounds: 1,4-Dioxane MW-19 Inorganics: Barium, Sodium, Vanadium, TDS Volatile Organic Compounds: None Detected MW-20 Metals: Arsenic, Barium, Vanadium Volatile Organic Compounds: None Detected MW-21 Metals: Arsenic, Barium Volatile Organic Compounds: None Detected M W-22 Metals: Arsenic, Barium, Cobalt Volatile Organic Compounds: None Detected MW-23 Metals: Arsenic, Barium, Cobalt Volatile Organic Compounds: None Detected M W-24 Metals: Arsenic, Barium Volatile Organic Compounds: 1,4-Dioxane MW-25 Metals: Arsenic, Barium, Nickel Volatile Organic Compounds: Chloromethane, 1,1-Dichloroethane, 1,4-Dioxane MW-26 Metals: Barium, Copper, Lead, Vanadium, Zinc Volatile Organic Compounds: IA-Dioxane MW-27 Metals: Arsenic, Barium Volatile Organic Compounds: Dichlorofluoromethane, 1,1-Dichloroethane, 1,1-Dichloroethene, 1,4-Dioxane, Tetrachloroethene co smith Ms. Jaclynne Drummond January 19, 2022 Page 6 MW-28 Metals: Barium Volatile Organic Compounds: Chloroform MW-29 Inorganics: Arsenic, Barium, Copper, Lead, Nickel, Sodium, Vanadium, Zinc, TDS Volatile Organic Compounds: Chloroethane, 1,1-Dichloroethane SW-1 Metals: Barium Volatile Organic Compounds: None Detected SW-2 Metals: Dry Volatile Organic Compounds: Dry SW-3 Metals: Barium Volatile Organic Compounds: None Detected "J" flags were not included in the previous list, but several sampling locations had "J" flag detections that exceeded the standards. The "J" flag constituents above the standards along with their location are listed below: Cobalt: MW-11, -14, -15, -16, -18, -24, -25, -26, -27, and -29 Mercury: SW-1 and -3 Vanadium: MW-2, -4, -9, -18, and -24 Vinyl Chloride: MW-6 An equipment and two trip blanks were analyzed for quality control. A duplicate sample was also collected for quality control. The equipment and trip blanks had no detections above the MDLs. The duplicate sample, labeled DUP, was collected from MW-16, and had similar concentrations as MW-16. Table 5 presents a summary of all parameters detected during the October 2021 sampling event that exceeded the NC 2L Groundwater Standards, IMACs, or NC 2B Surface Water Standards. Pesticides, herbicides, and polychlorinated biphenyls have not been sampled for since April 2011 and the last detections above the standards were in May 2010. Historical data is available upon request. Additional metals samples were collected from monitoring wells MW-4, -9, -11, -18, -21, -22, -25, -26, and -29 during the October 2021 sampling event for the laboratory to filter and analyze due to elevated turbidity (i.e., greater than 10 NTUs) at the time samples were collected. Total metals that exceeded the co smith Ms. Jaclynne Drummond January 19, 2022 Page 7 NC 2L Groundwater Standards or IMACs from these wells were analyzed for dissolved metals to determine if turbidity was a contributing factor to total reported metals. Below is a summary of the dissolved metals exceedances. Wells with a "*' qualifier had a "J" flag detection for that analyte. Barium: MW-9 and -25 Cobalt: MW-9, -11*, -22, -25*, -26*, and -29* Vanadium: MW-26 Dissolved metal sample results are provided in Table 4 and the laboratory data report is provided in Appendix A. Based on qualitative and quantitative evaluation of current and historic groundwater sampling data, the NC 2L Groundwater Standard or IMAC metal exceedances from the October 2021 sampling event were determined to be indicative of naturally occurring background concentrations as opposed to a release from the landfill. Monitored Natural Attenuation Sampling Additional groundwater samples were collected from the background well, MW-2, and downgradient monitoring wells MW-8, -9, -10, -12, -13, and -14. The samples were analyzed for alkalinity, BOD, chemical oxygen demand (COD), carbon dioxide, chloride, dissolved hydrogen, dissolved gasses (i.e., methane, ethane, ethene), volatile fatty acids (i.e., acetic, butyric, lactic, propionic, and pyruvic), nitrate, sulfate, sulfide, and total organic carbon. Ferrous iron was also analyzed using a HACH test field kit due to the short hold time (i.e., 15 minutes). These additional samples were collected to monitor for natural attenuation as part of the approved corrective action program as required by SWS guidelines. Additional samples were also collected from wells MW-19 and -29, which are located downgradient of the injection area, to monitor the effectiveness of the injection. Samples collected from MW-8, -9, -10, -19, and -29 were also analyzed for sodium and TDS. Sampling results are provided in Table 6 and trend figures of total detected VOCs for select wells are presented on Figures 2-10. Corrective Action via In situ Bioremediation Injection In accordance with the Corrective Action Plan that was approved by the SWS in a letter dated December 1, 2011, two in situ bioremediation injections have been completed. Phase I consisted of injecting sodium lactate into five injection wells upgradient of monitoring wells MW-8, -9, and -10 on June 18-21, 2012. A total of 1,268 gallons of a 10 percent sodium lactate solution were injected resulting in each well receiving approximately 254 gallons of the sodium lactate solution. Phase I post -injection samples were collected 1, 2, and 5 months after injection. During each sampling event, samples from MW-8, -9, -10, -19, and -29 were analyzed for the following field measurements: pH, temperature, oxidation-reduction potential, dissolved oxygen, conductivity, turbidity, nitrate, sulfate, ferrous iron, carbon dioxide, and alkalinity along with laboratory analyses of chlorides, COD, VOCs, dissolved gases, sodium, and TDS. Volatile fatty acids were also collected during the 1-month post -injection sampling event. Additionally, samples were collected from MW-8, -9, and -10 and 0 smith Ms. Jaclynne Drummond January 19, 2022 Page 8 analyzed for bacterial population size and functional gene presence during the baseline and 5-month post -injection sampling events. Analytical results for each sampling event are summarized in Tables 4 and 6. Analytical results post -sodium lactate injection for MW-8, -9, and -10 indicated that bioremediation was occurring with no VOCs detected above NC 2L Groundwater Standards in MW-8 or -10, except for 1,1-dichloroethane detected in samples collected from MW-10 in July 2012. MW-9 had detections of 1,1-dichloroethane, tetrachloroethene, trichloroethene, and vinyl chloride above NC 2L Groundwater Standards, but contaminant concentrations were decreasing. DNA analyses revealed healthy populations of bacteria (Deholococcoides sp) in MW-9 and -10 that continued to reduce contaminant concentrations. Bacterial populations in MW-8 decreased as a result of little to no VOCs being detected during the post -injection sampling. The Phase I injection of sodium lactate successfully caused degradation of trichloroethene and tetrachloroethene to daughter products using enhanced anaerobic bioremediation in the injection area. Although the Phase I injection reduced contaminant concentrations, a second injection was needed to supply a longer lasting source of electron donors. Biodegradation can be sustained for as long as sufficient concentrations of substrate remain in the groundwater. For this reason, emulsified vegetable oil was utilized in the Phase 2 injection as it is a slow -release compound, and therefore should release organic carbon into the groundwater for three to five years, depending on site conditions. During the Phase 2 injection on March 25-27, 2013, a 10 percent emulsified vegetable oil solution was injected into the injection wells. Injection at each well consisted of approximately 220 gallons of water containing approximately 22 gallons of the emulsified vegetable oil product. The emulsified vegetable oil product consisted of 60 percent emulsified vegetable oil and 4 percent sodium lactate by weight, which resulted in a total injection volume of 1,100 gallons of water and 110 gallons of emulsified vegetable oil product. Post -injection samples were collected 1, 4, 7, 10, and 12 months after injection. The April 2014 monitoring event concluded the post -injection monitoring. Analyses for each sampling event were similar to the Phase I events except that DNA analyses to determine bacterial population size and functional gene presence were only done during the April 2014 sampling event. No VOCs have been detected above the standards in MW-8 since the November 2011 semi-annual sampling event, except for the April 2019 sampling event. Samples collected from MW-8 in April 2019 had detections of 1,1-dichloroethane and tetrachloroethene above their respective NC 2L Groundwater Standards. 1,4-Dioxane was detected above its NC 2L Groundwater Standard in samples collected from MW-9 during the October 2021 sampling event. Benzene has been detected slightly above the standard since May 2015, except for the November 2015, April 2016, and October 2021 sampling events, and was Co smith Ms. Jaclynne Drummond January 19, 2022 Page 9 either reported as an estimated concentration below the standard or was not detected from September 1994 to October 2014. 1,1-Dichloroethane has historically been detected above the standard, except during the September 2019 and October 2020 and 2021 sampling events. 1,4-Dioxane was detected above the NC 2L Standard (3 parts per billion (ppb)) at 6.3 ppb and has been detected at similar concentrations above the standard since being added to the sampling program in the fall of 2018. Total VOC concentrations have fluctuated since the March 2013 injection. In MW-10, benzene, 1,1-dichloroethane, 1,4-dioxane, and vinyl chloride were detected above their respective NC 2L Groundwater Standards. The concentration of 1,1-dichloroethane has fluctuated but shows a decreasing trend since the May 2015 sampling event. Concentrations of benzene have historically fluctuated at MW-10. As expected, the concentration of vinyl chloride has fluctuated following the Phase 2 injection and has shown a decreasing trend since the May 2015 semi-annual sampling event. No VOCs were detected above the MDLs in samples collected from MW-19 during the October 2021 sampling event. Historically, VOCs have never been detected above the standards in monitoring well M W-19. MW-29, located at the compliance boundary, has not had any chlorinated ethenes detected above the NC 2L Groundwater Standards since November 2012. Chloroethane, 1,1-dichloroethane and an estimated detection of 1,4-dioxane were detected in samples collected from MW-29 during the October 2021 sampling event below their respective NC 2L Groundwater Standards. Concentrations of 1,1-dichloroethane have decreased following the injection events. 1,1-Dichloroethane has been detected below the NC 2L Groundwater Standard since the January 2014 post -injection sampling event except for the October 2014 semi-annual sampling event (7.2 ppb) when it was detected slightly above the NC 2L Groundwater Standard (6 ppb). Dechlorination of chlorinated ethenes from tetrachloroethene to ethene is ongoing. Chlorinated ethene concentrations in MW-9 and -10 remain below the NC 2L Groundwater Standards. The geochemical data will continue to be evaluated to determine if conditions for reductive dechlorination remain present. Subsequent monitoring events will be evaluated to identify any trends. Recommendations Wake County will continue with the semi-annual assessment monitoring program. All wells will continue to be sampled for Appendix I VOCs plus dichlorodifluoromethane and Appendix I metals plus mercury. The concentration of 1,4-dioxane will continue to be monitored in MW-6, -9, -10, -11, -12, -13, -14, -15, -17, -18, -24, -25, -26, -27, and -29. Samples collected from MW-2, -8, -9, -10, -12, -13, -14, -19, and -29 will also be analyzed for natural attenuation parameters. The next semi-annual sampling event will be completed in the spring of 2022. co smith Ms. Jaclynne Drummond January 19, 2022 Page 10 If you have any questions or require further explanation, do not hesitate to call me at 919-325-3500. Very truly yours, %;a ILLtlf- Mathew F. Colone, P.G. CDM Smith Inc. cc: John Roberson, WCSWM Elliott Cornell, WCSWM 0 Table 1 Monitoring Well Construction Summary and Groundwater Elevations October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 Facility Permit Number 9203-MSW LF-1980 Monitoring Well Code M W-2 Installation . 1994 35.68420 78.84301 of Interval Bedrock Total �- pth (feet BTOC) 60.0 Screened Interval (feet BTOC) 50.0 - 60.0 Sea I I nterval (feet BTOC) 48.0 - 50.0 Top of Casing Elevation (feet AMSL) 366.03 DepthGeology Groundwater (feet BTOC) 30.17 Elevation (feet AMSQ 335.86 Well Diameter (inches) 2.0 9203-MSWLF-1980 MW-4 1994 35.68161 78.86000 Regolith 36.0 26.0 - 36.0 24.0 - 26.0 310.80 24.69 286.11 2.0 9203-MSWLF-1980 MW-6 1994 35.68380 78.84769 Bedrock 33.5 23.5 - 33.5 21.5 - 23.5 319.71 18.50 301.21 2.0 9203-MSWLF-1980 MW-8 1994 35.68394 78.85367 Regolith 45.7 35.7 - 45.7 33.7 - 35.7 287.72 11.98 275.74 2.0 9203-MSWLF-1980 MW-9 1994 35.68402 78.85362 Bedrock 37.2 27.2 - 37.2 25.2 - 27.2 285.83 10.81 275.02 2.0 9203-MSWLF-1980 MW-10 1994 35.68406 78.85358 Regolith 22.5 12.5 - 22.5 10.5 - 12.5 287.10 11.46 275.64 2.0 9203-MSWLF-1980 MW-11 1994 35.68314 78.85380 Regolith 23.8 13.8 - 23.8 10.8 - 13.8 282.80 6.73 276.07 2.0 9203-MSWLF-1980 MW-12 1994 35.68018 78.84787 Regolith 21.8 11.8 - 21.8 9.8 - 11.8 306.52 9.09 297.43 2.0 9203-MSWLF-1980 MW-13 1994 35.68013 78.84987 Regolith 23.3 13.3 - 23.3 11.3 - 13.3 305.93 14.75 291.18 2.0 9203-MSWLF-1980 MW-14 1994 35.68010 78.84994 Bedrock 39.8 29.8 - 39.8 27.8 - 29.8 305.29 14.05 291.24 2.0 9203-MSWLF-1980 MW-15 1994 35.68012 78.84990 Saprolite 41.0 31.0 - 41.0 29.0 - 31.0 305.64 14.47 291.17 2.0 9203-MSWLF-1980 MW-16 1994 35.68070 78.85300 Regolith 45.0 35.0 - 45.0 33.0 - 35.0 315.30 29.01 286.29 2.0 9203-MSWLF-1980 MW-17 1994 35.68141 78.85434 Regolith 28.5 18.5 - 28.5 16.5 - 18.5 291.58 15.87 275.71 2.0 9203-MSWLF-1980 MW-18 1994 35.68389 78.85087 Regolith 26.5 16.5 - 26.5 14.5 - 16.5 300.82 13.82 287.00 2.0 9203-MSWLF-1980 MW-19 6/10/1999 35.68405 78.85366 Bedrock 68.0 58.0 - 68.0 56.0 - 58.0 286.17 11.88 274.29 2.0 9203-MSWLF-1980 MW-20 6/10/1999 35.68456 78.85302 Regolith 28.5 13.5 - 28.5 11.5 - 13.5 285.80 10.42 275.38 2.0 9203-MSWLF-1980 MW-21 6/10/19991 35.68229 78.86262 Regolith 31.0 16.0 - 31.0 14.0 - 16.0 339.25 18.73 320.52 2.0 9203-MSWLF-1980 MW-22 6/10/19991 35.67984 78.86062 Regolith 28.5 13.5 - 28.5 11.5 - 13.5 299.39 17.55 281.84 2.0 9203-MSWLF-1980 MW-23 6/10/1999 35.68029 78.85884 Regolith 27.7 12.7 - 27.7 10.7 - 12.7 286.83 15.15 271.68 2.0 9203-MSWLF-1980 MW-24 6/10/1999 35.68179 78.85827 Regolith 31.0 16.0 - 31.0 14.0 - 16.0 295.04 12.25 282.79 2.0 9203-MSWLF-1980 MW-25 6/10/1999 35.68267 78.85769 Regolith 30.6 15.6 - 30.6 13.6 - 15.6 295.87 15.89 279.98 2.0 9203-MSWLF-1980 MW-26 6/9/1999 35.67795 78.85668 Regolith 20.0 7.0 - 20.0 5.0 - 7.0 282.95 5.95 277.00 2.0 9203-MSWLF-1980 MW-27 6/9/1999 35.67585 78.85661 Regolith 31.5 16.5 - 31.5 14.5 - 16.5 297.31 16.94 280.37 2.0 9203-MSWLF-1980 MW-28 6/10/1999 35.68378 78.84759 Bedrock 71.0 61.0 - 71.0 59.0 - 61.0 319.70 23.19 296.51 2.0 9203-MSWLF-1980 MW-29 2/21/20111 35.68420 1 78.85379 1 Regolith 25.3 15.3 - 25.3 13.3 - 15.3 1 284.76 1 9.69 1 275.07 1 2.0 Notes: 1. Groundwater elevations were measured on October 18, 2021. 2. AMSL - Above Mean Sea Level 3. BTOC - Below Top of Casing 4. Latitude and longitude are in decimal degrees (World Geodetic System 1983). Smith Page 1 of 1 January 2022 Table 2 Summary of Calculated Groundwater Flow Velocities October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 Facility Permit Number 9203-MSWLF-1980 Hydraulic Average Linear Velocity Code Conductivity Gradient Effective Porosity Monitoring Well .. MW-2 0.42 0.018 0.13 5.94E-02 9203-MSWLF-1980 MW-6 0.42 0.024 0.05 2.04E-01 9203-MSWLF-1980 MW-8 2.63 0.019 0.13 3.78E-01 9203-MSWLF-1980 MW-9 0.33 0.019 0.05 1.25E-01 9203-MSWLF-1980 MW-10 0.52 0.019 0.13 7.57E-02 9203-MSWLF-1980 MW-11 0.42 0.018 0.13 5.93E-02 9203-MSWLF-1980 MW-12 0.42 0.019 0.25 3.13E-02 9203-MSWLF-1980 MW-13 1.24 0.014 0.05 3.56E-01 9203-MSWLF-1980 MW-14 0.26 0.017 0.05 9.10E-02 9203-MSWLF-1980 MW-15 2.00 0.018 0.18 1.95E-01 9203-MSWLF-1980 MW-16 0.42 0.015 0.05 1.28E-01 9203-MSWLF-1980 MW-17 0.42 0.017 0.13 5.47E-02 9203-MSWLF-1980 MW-18 6.43 0.021 0.08 1.65E+00 9203-MSWLF-1980 MW-19 1.84 0.019 1 0.13 1 2.71E-01 Notes. 1. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 2. The gradient and linear velocity values shown for MW-2 are based on the average of all the listed wells. Smith Page 1 of 1 January 2022 Table 3 Water Quality Parameters October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 Facility Permit Number 9203-MSWLF-1980 Monitoring Well ..- MW-2 Water Quality Measurements pH Conduc ivity Temperature Turbidity..ORP 7.31 4,162 17.0 8 7.23 75.4 9203-MSWLF-1980 MW-4 6.82 279 18.1 59 8.86 119.7 9203-MSWLF-1980 MW-6 6.75 2,037 18.2 8 0.32 37.8 9203-MSWLF-1980 MW-8 6.95 219 15.5 2 0.22 56.6 9203-MSWLF-1980 MW-9 6.87 668 15.9 47 0.37 -24.7 9203-MSWLF-1980 MW-10 6.56 932 18.2 10 0.71 -26.1 9203-MSWLF-1980 MW-11 6.32 496 17.5 32 1.51 -30.6 9203-MSWLF-1980 MW-12 7.31 974 18.6 10 0.13 2.3 9203-MSWLF-1980 MW-13 5.92 318 18.5 8 0.46 111.2 9203-MSWLF-1980 MW-14 6.07 544 16.2 0 0.20 112.3 9203-MSWLF-1980 MW-15 6.24 698 16.5 6 0.38 99.6 9203-MSWLF-1980 MW-16 6.13 283 18.6 1 0.50 14.9 9203-MSWLF-1980 MW-17 6.40 733 17.4 7 0.53 24.9 9203-MSWLF-1980 MW-18 7.03 1,370 19.5 176 1.69 47.8 9203-MSWLF-1980 MW-19 7.96 323 15.7 1 0.33 14.7 9203-MSWLF-1980 MW-20 8.03 362 16.5 10 1.87 86.2 9203-MSWLF-1980 MW-21 5.93 152 18.2 61 6.21 106.7 9203-MSWLF-1980 MW-22 6.55 927 16.9 87 1.25 -37.5 9203-MSWLF-1980 MW-23 6.10 1,603 17.2 7 1.79 18.0 9203-MSWLF-1980 MW-24 5.84 1,873 18.0 10 1.16 82.6 9203-MSWLF-1980 MW-25 6.65 2,022 18.0 79 4.95 71.7 9203-MSWLF-1980 MW-26 5.03 526 18.7 272 5.40 46.0 9203-MSWLF-1980 MW-27 6.73 857 18.6 9 0.58 -42.4 9203-MSWLF-1980 MW-28 7.08 957 18.0 9 1.00 36.1 9203-MSWLF-1980 Surface Water Sample 9203-MSWLF-1980 MW-29 Location SW-1 6.55 8.25 269 148 16.7 86 0.21 13.0 12 9.18 -38.3 2.4 9203-MSWLF-1980 SW-2 DRY 9203-MSWLF-1980 SW-3 7.64 144 13.0 6 8.28 81.2 Notes: 1. Water quality measurements were collected on October 18-21, 2021. 2. SW - Surface Water 3. ORP - Oxidation -Reduction Potential (mV - millivolt) 4. DO - Dissolved Oxygen (mg/L - milligrams per liter) 5. S.U. - Standard Units 6. NTUs - Nephelometric Turbidity Units 7. µS/cm - Microsiemens per centimeter 8. Turbidity measurements recorded at the time of sample collection. smith Page 1 of 1 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW-2 4-Apr-12 159 18.3 -- -- MW-2 6-Nov-12 0.5631 401 2.391 2.241 1.971 -- 8.831 -- MW-2 15-May-13 801 0.21 0.071 0.51 -- 34 -- MW-2 6-Nov-13 210 1.01 0.21 21 0.41 11 -- 51B -- MW-2 9-Apr-14 150 0.3J 0.101 21 0.2J 0.041 0.71 21 -- 14J 5113 -- MW-2 28-0ct-14 2J 360 0.1.1 0.21 21 0.02J 2J 21 - 0.07J 4JB -- MW-2 5-May-15 0.71 190 O.L 11 0.041 11 - 3JB -- MW-2 19-Nov-15 0.51 650 2.141 61 0.06J 3J 21 - 10 -- MW-2 26-Apr-16 250 -- 20 -- MW-2 17-Nov-16 0.40J 370 0.161 1.51E 1.8J 1.OJ 0.36J -- 6.4JB 4.2J -- MW-2 27-Apr-17 2.11 160 0.97J 0.28J 2.81 9.41 -- 9.6J -- MW-2 26-Sep-17 170 0.831 - 14J -- MW-2 16-Jan-18 200 0.76) 0.251 1.51 -- 8.7J -- MW-2 28-Mar-18 130 - 8.11 4.OJ -- MW-2 31-Aug-18 170 - 7.9J 3.11 -- MW-2(dissolved) 31-Aug-18 -- -- -- -- -- -- -- -- -- - - - - - - 7.8 - -- MW-2 28-Nov-18 180 -- 7.8J 4.31 -- MW-2 26-Feb-19 120 -- 9.6J 5.4J -- MW-2 2-May-19 170 2.51 1.71 4.51 2.41 1.51 -- 13J 14B -- MW-2 2-Jul-19 IS 610 0.91 0.21J 25 240 31 3.1J 0.32.1 -- 57 160E -- MW-2 (dissolved) 2-Jul-19 -- -- -- -- -- -- -- -- -- -- -- -- -- MW-2(dup) 2-Jul-19 13 1,700 3.1 0.99 17 993 1,300 4.7J 1.6J -- 0.34J 130 610E -- MW-2(dup, dissolved) 2-Jul-19 -- -- -- -- -- -- -- -- -- -- MW-2 26-Sep-19 140 0.30J 2.1J -- 9.3 4.3J -- MW-2 22-Jan-20 140 2.21 -- 8.9 -- MW-2 15-Apr-20 120 5.4 - 11 -- MW-2 22-Oct-20 270D 0.181 2.41 0.431 4.71 -- 6.2 4.11 -- MW-2 14-Apr-21 140 0.29J 5.6 - 9.7 -- MW-2 21-Oct-21 380 3.OJ 0.70J 1.81 0.271 6.91 3.01 MW-4 8-Nov-11 45.61 2.27J 4.15JB -- 6.85J 17.8 -- MW-4 4-Apr-12 0.911 38.81 -- 3.841 -- MW-4 6-Nov-12 57.41 2.85J 1.621 2.581 2.871 3.48J -- 7.65J 11.1 -- MW-4 15-May-13 21 50J 0.051 21 1.01 21 21 21 -- 5JB -- MW-4 6-Nov-13 4J 901 0.11 61 41 11 41 91 - 121 27 -- MW-4 9-Apr-14 21 401 11 0.31 1.OJ 0.51 0.021 1.01 - 61 7JB -- MW-4 28-0ct-14 21 70J 0.081 4JB 21 41 31 51 - 0.091 51 168 -- MW-4 5-May-15 41 801 0.11 0.11 51 21 81 M 41 - 51 13B -- MW-4 19-Nov-15 2J 40J 0.11 21 0.6J 11 11 0.111 2J - 61 -- MW-4 26-Apr-16 50J 11 0.41 11 - -- MW-4 16-Nov-16 1.7J 48J 0.12J 0.090J 2.81 0.791 2.71 2.OJ 2.5J - 7.31 7.6J -- MW-4 28-Apr-17 33J - 5.61 3.61 -- MW-4 26-Sep-17 0.921 2.4J 56J 0.231 4.41 0.921 2.81 2.51 3.5J - 111 10 -- MW-4(dissolved) 26-Sep-17 -- -- -- -- -- -- -- -- -- -- -- -- -- - - 4.OJ -- -- MW-4 28-Mar-18 3.4J 68J 0.18J 6.71 4.11 2.81 4.6J -- 9.51 11 -- MW-4(dissolved) 28-Mar-18 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- MW-4 28-Nov-18 1.4J 42J 2.21 0.721 2.41 -- 3.61 2.5J -- MW-4(dissolved) 28-Nov-18 -- -- -- -- -- -- -- -- -- -- -- -- -- -- - 2.6J -- -- MW-4 2-May-19 1.3J 40J 2.31 0.54.1 -- 3.5J 4.08J -- MW-4(dissolved) 2_May_19 MW-4 24-Sep-19 1.3J 44 3.11 0.791 1.61 -- 4.7J 6.8BJ -- MW-4 14-Apr-20 1.91 50 3.21 1.31 0.921 1.3J -- 5.3 -- MW-4 21-Oct-20 1.4J 34 0.271 - 3.61 2.6J -- MW-4 13-Apr-21 1.31 44 0.211 2.21 0.74J - 4.0Jj 3.91 -- MW4(dissolved) 13-Apr-21 -- -- -- -- -- -- -- -- -- -- -- -- -- MW-4 19-Oct-21 1.31 35 1.31 0.49J - 3.01 4.11 -- MW4(dissolved) 19-Oct-21 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -I -- -- MW-6 4-Apr-12 0.254J 248 6.791 1.49J 2.521 2.181 -- 15.81 7.07J -- MW-6 6-Nov-12 509 6.42J 1.161 1.911 2.60J -- 16.2J 18.4 -- MW-6 15-May-13 0.61 280 0.81 71 11 27J 2.1 -- 91B -- MW-6 6-Nov-13 450 0.31 0.21 21 11 0.02J 191 2.1 -- 6JB -- MW-6 9-Apr-14 11 470 0.81 0.31 10 21 0.041 31J 3.1 -- 101 27B -- MW-6 28-Oct-14 0.91 530 0.41 61 21 0.03J 26J 2.1 -- 91B -- MW-6 5-May-15 11 570 0.51 0.41 51 3J 0.06J 25J 21 -- 13JB -- MW-6 18-Nov-15 0.5J 660 0.21 21 31 41 0.71 20J L -- 11 -- MW-6 (dup) 18-Nov-15 11 620 0.06J 0.21 3J 31 M 0.81 0.03J 20J 11 -- 12 -- MW-6 27-Apr-16 0.3J 1J 610 0.071 0.31 21B MB 41 0.81 21J L -- 13 -- MW-6 16-Nov-16 0.251 0.91J 570 0.621 0.861 3.91 25J 1.21 0.33J - 2.71 5.9J -- MW-6 27-Apr-17 620D 0.671 4.31 191 1.81 - 3.61 25 -- M MW-6 27-Sep-17 0.681 1,OOOD 0.171 1.41 3.2J 231 - 4.41 6.31 -- MW-6 (dup) 27-Sep-17 1,OOO1) 3.31 24J -- 3.8J 7.1J -- MW-6 28-Mar-18 850 0.561 18 3.71 29J - 11 -- MW-6 (dissolved) 28-Mar-18 -- -- 760 -- -- -- 16 -- -- -- -- -- -- -- -- -- -- -- MW-6 (dup) 28-Mar-18 820 0.531 18 3.31 28J -- 30 -- MW-6 dup (dissolved) 28-Mar-18 -- -- g00 -- -- -- 18 -- -- -- -- -- -- -- -- -- -- -- MW-6 28-Nov-18 850 0.70J 14 3.41 191 -- 8.5J -- MW-6 (dissolved) 28-Nov-18 -- -- B00 -- -- -- 10 -- -- -- -- -- -- -- -- -- -- -- MW-6 2-May-19 1.31 800 0.281 13 2.11 23J -- 1113 -- MW-6 (dissolved) 2-May-19 -- -- 820 -- -- -- 13 -- -- -- -- -- -- -- -- -- -- -- MW-6 26-Sep-19 580D 2.31 18 -- 4.4J -- MW-6 15-Apr-20 1,200D 0.451 9.0 3.51 30 3.51 -- 6.61 -- MW-6 21-Oct-20 1,OOO1) 0.72 8.3 4.3J 32 2.41 -- 14 -- MW-6 14-Apr-21 0.921 920 0.391 1.61 11 3.61 28 2.41 -- 7.21 -- MW-6 21-Oct-21 3.0 970D 0.151 1.61 12 2.5J 38 8.91 Smith Page 1 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW8 4-Apr- 0.5741 4JI 4J 1 -- MW-8 4-Jun-12 1 I I31--. -- -- -- -- I3.-0 I I I 8,2--90 -- -- - 200,000 -- 778 19-Jul-12 -- -- -- -- -- - - -- -- -- -- -- -- 10,100 -- - 240,000 VW-8 16-Aug-12 __ __ __ __ __ ._ ._ __ __ __ __ __ __ 8600 __ __ __ 170,000 VW-8 6-Nov-12 104 18.7 5.601 13.2 52.3 10,000 5.201 110,000 15-May-13 0.91 31 110 0.21 0.41 115 0.51 24J 9,520 12B 212,000 VW-8 23 61 MW-8 31-Jul-13 -- -- -- -- -- - - -- -- -- -- -- -- 9,150 -- -- -- 248,000 MW-8 6-Nov-13 0.31 150 61 21 61 24J 7,900 2JB 189,000 MW-8 16-Jan-14 -- -- -- -- -- - - -- -- -- -- -- -- 8,280 -- -- -- 212,000 VW-8 30-Apr-14 0.61 0.51 130 0.31 7J 31 81 0.21 0.051 34J 8,830 14B 212,000 MW-8 29-Oct-14 0.51 160 0.21 31 41 51 0.31 53 7,800 10B 181,000 VW-8 7-May-15 0.61 140 0.21 91 21 91 0.31 0.1121 29J 7,900 51 196,000 MW-8 19-Nov-15 0.7J 190 0.61 61 7J 61 0.31 102 11 I51 4J 178,000 VW-8 26-Apr-16 11 200 30 91 0.71 0.031 67 9,150 51 196,000 MW-8 16-Nov-16 0.521 160 6.9J 0.681 73 6,000 5.81 180,000 VW-8 28-Apr-17 0.67J 120 3.21 3.91 4.61 0.271 30J 6,400 14J 3.91 210,000 MW-8 27-Sep-17 130 2.61 12 2.81 6,800 24J 2.8J 190,0001-1 42J MW-8 28-Mar-18 0.67J 110 0.231 7.21 4.51 2.01 7,000 161 3.41 170,000 MW-8 27-Nov-18 160 23 12 9.11 0.49J 95 7,100 Ill 4.9J 190,000 MW-8 1-May-19 210 13 19 6.31 0.381 84 22,000 5.01 4.381 160,000 MW-8 25-Sep-19 120 0.191 6.4 4.71 1.81 57 6,300 13 5.08J 160,000 MW-8 14-Apr-20 0.711 110 0.131 7.8 5.1 1.91 0.30J 30 8,100 12 160,000 MW-8 21-Oct-20 110 5.4 1.61 1.3J 34 7,100 7.9 75 200,000 MW-8 13-Apr-21 160 3.61 9.7 1.51 70 15,000 220,000 W M-8 20-Oct-21 90 3.41 23 6,8005 7.5 170,000 MW-9 7-Nov-11 147 0.136) 3.18J 1.281 2.821E -- 3.16J 35.9 -- MW-9 4-Apr-12 191 0.3551 10.1 3.121 12 2.581 11 6J -- 7.481 20.2 -- MW-9 (dup) 4-Apr-12 180 0.2931 8.31J 3.381 9.981 10.21 -- 6.06J 31.1 -- MW-9 4-Jun-12 -- -- -- -- - - - -- -- -- -- -- -- 11,400 - - -- 280,000 -- MW-9 19-Jul-12 -- IN -- -- -- -- -- -- -- -- 0 -- -- -- 39,600 - - - 1,100,000 MW-9 16-Aug-12 -- -- -- -- -- -- -- -- -- -- -- -- -- 28,500 - -- -- 650,000 MW-9 6-Nov-12 0.446J 0 0.5461 16.2 23. 125 8.161 144 4.1SJ 45,100 17.41 36 970,000 i 15-May-13 61 57 41 MW-9 1,320 0.21 51 25 0.08J 65 2J 30,200 41 15B 473,000 MW-9(dup) 15-May-13 OM 7J 1,260 0.2J 31 24 57 41 0.071 63 21 - 12B -- -- MW-9 31-Jul-13 -- -- -- -- -- -- -- -- -- -- -- -- -- 30,800 -- -- 463,000 MW-9 6-Nov-13 81 1,200 0.41 0.11 71 21 65 71 0.081 47J 31 23,600 0.11 27 431,000 -- MW-9 16-Jan-14 -- -- -- -- -- -- -- -- -- -- -- -- -- 21,g00 -- -- 427,000 MW-9 10-Apr-14 81 1,D60 0.11 0.11 11 19 39 41 0.07J 31J 21 21,300 11B 417,000 MW-9(dup) 10-Apr-14 0.31 30 1,050 0.11 0.31 L 19 SO 41 0.061 321 21 -- 17B -- MW-9 29-Oct-14 61 820 0.11 0.21 2JB 14 29 51 0.11 32J 21,300 13B 375,000 MW-9(dup) 29-Oct-14 6J 820 0.11 0.21 11B 14 30 51 0.041 32J -- 10B -- MW-9 7-May-15 7J 1,000 0.3J 41 16 29 81 0.04J 33J 19,800 15 389,000 MW-9 20-Nov-15 6J 810 0.061 0.81 12 18 71 0.101 25J 2J 31 383,000 MW-9 27-Apr-16 61 930 0.11 0.4JB 13 11 61 24J 11 21,200 4J 403,000 MW-9 16-Nov-16 6.8J 2,100 0.0611 0.931 14 10 7.4J 0.0361 28J 19,000 4.01 370,000 MW-9 27-Apr-17 5.11 950D 0.181 1.41 12 14 8.31 0.041J 32J 21,000 3.31 5.5J 420,000 MW-9 27-Sep-17 6.11 900 30 5.71 3.01 24J 20,000 4.01 380,000 0.621 MW-9 29-Mar-18 4.9J 850 1.61 12 11 7.41 27J 22,000 4.0J 450,000 MW-9(dissolved) 29-Mar-18 -- -- 780 -- -- -- 12 -- -- -- -- -- -- -- -- -- -- -- MW-9 28-Nov-18 3.11 1,100 14 7.21 6.01 31J 17,000 2.5J 470,000 MW-9(dissolved) 28-Nov-18 -- -- 2,100 -- -- -- 13 -- -- -- -- -- -- -- -- -- -- -- MW-9 2-May-19 4.6J 1,400 0.141 25 7.21 4.6J 57 32,000 4.71 9.71 -- MW-9(dissolved) 2-May-19 -- -- 2,400 -- -- -- 25 -- -- -- -- -- -- -- -- -- MW-9 26-Sep-19 4.7 1,300D 14 6.3 4.2 33 25,000 3.11 3.9J 490,000 MW-9(dissolved) 26-Sep-19 -- -- 1,000D -- -- -- 14 -- -- -- -- -- -- -- -- -- -- MW-9 14-Apr-20 4.8 1,400D 18 4.61 2.6 41 31,000D 4.71 3.01 540,000 MW-9 22-Oct-20 4 1,100D 13 4.01 1.8 28 26,000 620,000 MW-9 14-Apr-21 0.561 3.2 1,600 23 16 1.6 48 22,000 3.31 4.31 560,000 MW-9 21-Oct-21 3.8 900D 0.71 1.6J 9.3 5.4 1.7 22 26,D00 3.21 10 400,000 MW-9(dissolved) 21-Oct-21 -- -- 770 -- -- -- -- -- -- - - - -- -- -- -- Smith Page 2 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW-10 7-Nov-11 8.75J 476 0.1411 4.521 1.641 3.721E 18.71 -- 3.30J 9.39J -- MW-10 4-Apr-12 10.2 596 4.971 47AJ - - MW-10 4-Jun-12 -- -- -- -- -- -- -- -- -- -- -- -- -- 58,100 -- 630,000 MW-10 19-Jul-12 __ __ __ __ __ __ __ __ ######### MW-10 1fAug-12 - -._########MW-30 �#5#9#5##0#0#0#� 6-Nov-12 34.2 2,050 294 67.6 42.5 152 34.7 0.349 107 7.641 ,111 195 2,800,000 MW-30(dup) 6-Nov-12 28.5 32 2,.0 1,140 3.31 2.9 76.1 46.1 190 41 46 154 42.8 28 0.306 0. 19J 113 77 8.23J 2J - 127 231 - 253000 0.3J 84 269 1,100,000 MW-10 15-May-13 MW-10 31-Jul-13 -- -- -- -- -- -- - -- -- -- -- -- -- 121:000 - - -- 680,000 MW-10 6-Nov-13 21 880 0.81 0.11 10 31 45 81 0.06J 39J 3J 128,000 0.08J 31 55 794,000 MW-10 (dup) 6-Nov-13 22 1,040 1.6 0.41 20 37 75 16 0.101 501 4J - 0.11 57 114 -- MW-10 16-Jan-14 -- - - -- - -- - -- -- -- -- -- - 69,600 - -- -- 460,000 MW-30 30-Apr-14 16 310 0.081 11 14 21 0.41 0.071 14J 50,400 7JB 393,000 MW-10 26-Oct-14 13 720 0.21 31 21 12 31 0.11 23J 2J 86,300 24 670,000 MW-30 7-May-15 23 700 0.11 21 29 310.6) 0.021 36J 3J 77,800 61 756,000 MW-10 20-Nov-15 25 730 0.11 31 21 71 0.91 0.05J 32J 31 6J 680,000 MW-10 27-Apr-16 0.31 34 850 0.11 0.51E 24 21 0.21 30J 2J 93,400 21 832,000 MW-10 16-Nov-16 20 930 1.21 17 1.21 25J 65,000 1.61 1.9J 760,000 MW-30 27-Apr-17 23 350 0.141 11 3.51 0.401 13J 40,000 2.3J Z8J 350,000 MW-10 27-Sep-17 0.591 8.01 520 7.61 0.771 9.6J 34,000 2.3J 380,000 MW-10 29-Mar-18 0.73J 6.11 480 0.231 2.81 35 6.51 1.11 38J 54,000 5.01 66 470,000 MW-30 (dissolved) 29-Mar-18 -- - - - -- -- 33 -- -- -- -- -- - - - - - MW-10 28-Nov-18 28 770 2.91 42 4.21 1.11 49J 55,000 4. 30 590, MW-30(dissolved) 28-Nov-18 -- 29 600 - -- -- 36 -- -- -- -- -- - - - - - MW-30 2-May-19 26 1,100 1.41 44 1.61 61 1.31 110,000 4.61 6.91 670, MW-10 26-Sep-19 12 700D 16 1.91 0.38J 22 49,OOOD SAJ 500, MW-30(dissolved) 26-Sep-19 -- 4.9 640D -- -- -- 16 -- -- -- -- -- -- -- - -- -- -- MW-10 14-Apr-20 31 1,000D 34 47 1.81 94,OOOD 2.9J 910,000 MW-10 22-Oct-20 0.681 16 980D 1.51 15 1.41 0.391 35 99,000D 3.11 980,000 MW-10 14-Apr-21 14 940 24 37 1.51 75,000 2.5J 750,000 MW40 20-Oct-21 15 830D 13 1.41 25 69,OOO1) 660,000 MW-11 8-Nov-11 83.8J 1.081 - 1.641 14.7 - MW-11 4-Apr-12 84.31 - -- MW-11 6-Nov-12 93.21 2.521 - 13.2 -- MW-11 15-May-13 0.61 70J 0.5J 21 0.81 2J - 3JB -- MW-11 6-Nov-13 0.81 70J 31 0.91 2J - 41B -- MW-11 10-Apr-14 11 70J 0.7J 0.5J 11 0.3J 0.04J 2J - 81B -- MW-11 29 Oct-14 0.61 70J 0.41B 0.91 11 0.21 2J - 51 -- MW-11 6-May-15 21 110 0.051 11 81 21 0.5J 0.02J 4J - 7JB -- MW-11 20-Nov-15 11 70J 0.05J 0.21 0.51 51 21 0.2J 3J 11 - 13 -- MW-11 27-Apr-16 11 110 91 0.81 3J - 41 -- MW-11 16-Nov-16 0.60J 911 2.41 0.77J 2.6J - 1.41 3.5J -- MW-11 28-Apr-17 96J 3.9J 1.51 - 2.31 9.81 -- MW-11 28-Sep-17 92J 1.81 - 1.51 3.01 -- MW-11 29-Mar-18 87J 3.11 2.4J - 3.11 -- MW-11 28-Nov-18 1.6J 100 5.91 2.9J -- 6.8J -- MW-11 2-May-19 2.91 170 0.181 1.5J 6.01 2.41 1.21 6.9J M 15B -- MW-11(dissolved) 2-May-19 -- -- -- -- -- -- 5.1 -- -- -- -- -- -- -- -- - MW-11 26-Sep-19 150 2.9J 4.1J -- 3.91 -- MW-11 15-Apr-20 85 4.81 2.OJ -- -- MW-11 22-Oct-20 2.1 120 5.4 6.3 -- -- MW-11 14-Apr-21 1.81 110 6.3 0.471 3.6J - 3.6J -- MW-11(dissolved) 14-Apr-21 -- -- -- -- -- -- 6.0 -- -- -- -- -- -- -- -- -- -- -- MW-11 21-Oct-21 80 2.81 1.91 -- 3.4J -- MW-11(dissolved) 21-Oct-21 -- -- -- -- -- -- 2.51 -- -- -- -- -- -- -- -- - -- -- MW-12 8-Nov-11 3.93J 115 3.02JB -- 6.15.1 -- MW-12 3-Apr-12 182 1.281 -- -- MW-12 5-Nov-12 123 -- -- MW-12 15-May-13 21 170 0.91 0.11 0.31 2J -- -- MW-12 6-Nov-13 4J 140 0.51 0.21 21 11 -- -- MW-12 10-Apr-14 21 230 0.91 0.21 0.6J 0.04J 2J - 4JB -- MW-12 28 Oct-14 2J 130 0.91E 0.11 0.51 11 - 218 -- MW-12 6-May-15 2J 290 0.41 0.1.1 0.51 0.05J 3J - 3JB -- MW-12 20-Nov-15 6J 200 0.31 0.. 11 2.1 - -- MW-12 27-Apr-16 5J 330 0.08J 31 M M U 5J 11 - 6J -- MW-12 17-Nov-16 5.1J 140 0.671E 1.41 - -- MW-12 27-Apr-17 3.91 260 0.821 0.049J 4.2J 5.9J - -- MW-12 (dup) 27-Apr-17 3.9J 250 3.91 3.91 - -- MW-12 28-Sep-17 0.851 3.8J 130 1.31 - -- MW-12 29-Mar-18 7.8J 89J - -- MW-12 28-Nov-18 5.31 220 2.1J - -- MW-12 2-May-19 5.2J 290 1.81 0.34J 4.31 2.01 - 7.81 -- MW-12(dissolved) 2-May-19 -- -- -- -- -- -- -- -- -- -- -- -- - -- - -- MW-12 26-Sep-19 6.3 200 2.21 - 27 3.31 -- MW-12 15-Apr-20 3.5 240 2.81 3.OJ - 5.0 100 -- MW-12 22-Oct-20 3.9 180 2.31 1.31 - 3.81 -- MW-12 14-Apr-21 3.3 250 0.26J 3.11 5.2 - -- MW-12 21-Oct-21 2.8 170 1.71 Smith Page 3 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o o MW-13 31-Mar-11 576 2.301 11.3 3.331B 0.273 44.91 3.481 -- 60.9 -- MW-13 8-Nov-11 4.701 906 0.1301 1.21 3.08J 16.8 5.291 53.2 -- 243 -- MW-13 3-Apr-12 4.411 960 2.481 17.0 4.64J 0.384 53.4 -- 88.1 -- MW-13 5-Nov-12 757 0.633J 1.131 10.4 8.361 0.487 46.2J -- 234 -- MW-13 16-May-13 21 550 0.11 0.61 0.5191 13 0.4J 0.35 36J -- 103 -- MW-13 7-Nov-13 0.9J 480 0.08J 0.21 71 418 0.151 33J -- 36 -- MW-13 30-Apr-14 21 590 0.11 0.61 0.31 10.0 18 0.79 35J -- 144 -- MW-13 28-Oct-14 2J 460 0.11 1.7 M 13 0.21 0.21 30J -- 0.061 265 -- MW-13 6-May-15 21 610 0.11 0.81 0.2110 17 0.39 39J -- 98 -- MW-13 20-Nov-15 1J Soo 0.11 0.31 0.31 81 13 0.50 32J 3.1 -- 48 -- MW-13 27-Apr-16 31 620 0.11 0.21 0.31E 91 13 0.61 0.51 35J -- 58 -- MW-13 17-Nov-16 1.2J Soo 0.181 6.4J 4.718 0.20J 0.36 31J 0.171 -- 41 -- MW-13 28-Apr-17 2.61 380 0.16) 5.71 5.51 0.36 24J 4.81 -- 38 -- MW-13 28-Sep-17 0.621 2.11 1101 0.161 8.61 2.71 0.43 35J -- 44 -- MW-13 29-Mar-18 1.51 490 0.331 6.71 7.91 0.351 0.56 29J -- 47 -- MW-13(dissolved) 29-Mar-18 -- -- -- -- -- -- 6.51 -- -- -- -- - - - -- - -- MW-13 28-Nov-18 200 0.381 LM 3.81 0.37 13 -- 20 -- MW-13 29-Apr-19 1.3J 450 0.191 7.31 5.71 0.40 26J -- 33 -- MW-13 (du 29-Apr-19 1.41 490 0.171 7.9J 5.8.1 0.37 27J -- 36 -- MW-13 26-Sep-19 440D 0.351 6.7 9.2 34 -- 51 -- MW-13 15-Apr-20 1.41 650D 0.86 9.0 10 0.36) 35 -- 15 91 -- MW-13 (dissolved) 15-Apr-20 -- -- - -- -- - 9.1 -- -- 0.57 -- - - - - 13 -- -- MW-13 22-Oct-20 2.4 560D 0.151 12 5.3 0.30J 0.22 32 -- 36 -- MW-13 14-Apr-21 2.5 700 13 4.81 0.141 33 - 36 -- MW-13 20-Oct-21 430D 4.6.1 0.41 27 39 MW-14 7-Nov-11 0.5281 5.60J 26.61 1.911 -- 5.77J 5.42.1 -- MW-14 3-Apr-12 0.4461 178 3.651 8.281 - 3.09J -- MW-14 5-Nov-12 0.2991 60.0J 3.59J - 2.09J -- MW-14 16-May-13 0.71 70J 1.8 11 51 0.021 51 - 5.1 -- 0.61 MW-14 7-Nov-13 0.61 1001 2.1 0.91E 51 - 81 71B -- MW-14 10-Apr-14 0.91 901 0.81 11 51 0.21 0.091 91 - 151 56.0 -- 0.51 MW-14 208 Oct-14 0.31 140 0.11 0.41B 11 51 - 21B -- MW-14 6-May-15 0.71 0.81 140 0.11 11 71 0.181 111 -- 6113 -- MW-14(dup) 6-May-15 1. 90 0.21 1JB 12 0.08J 6J -- 61 -- MW-14 20-Nov-15 0.91 150 0.71 0.71 41 0.081 51 11 -- 4J -- MW-14 27-Apr-16 0.4J 0.51 240 3JB 11 0.12J 181 -- -- 0.76) MW-14 17-Nov-16 0.72J 0.93J 210 0.171 2.71 2.61E 0.17J 0.80 16J 0.20J - 4. 3.6J -- MW-14 28-Apr-17 1.11 120 5.51 0.43 4.6J 1.6J -- 5.51 5.01 -- MW-14 28-Sep-17 0.841 140 0.381 1.41 1.91 0.13J 12J -- 4.91 5.3J -- MW-14 29-Mar-18 0.65J 120 1.41 0.41 5.1J -- 2.9J 160 -- MW-14 27-Nov-18 0.83J 260 0.331 11 2.51 3.61 0.36J IS 24J - 7.41 3.7J -- MW-14(dup) 27-Nov-18 1.0J 250 0.631 30 2.91 6.61 0.50J 3.3H 24J - 7.81 5.81 -- MW-14 29-Apr-19 0.811 250 0.341 4.8J 2.11 4.51 1.6 211 - 5.61 5.51 -- MW-14 25-Sep-19 3.5 160 0.341 2.7.1 1.71 4.61 11.2. 0.38 18 - 3.0J 16B -- MW-14 15-Apr-20 1.71 170 0.271 1.91 0. 16J 15 1.3J - 19 -- MW-14 (dup) 15-Apr-20 1.81 180 0.281 2.01 2.01 0.191 15 - 14 -- MW-14 22-0ct-20 210 5.2 0.39 19 1.41 -- 2.71 -- MW-14 13- Apr -21 190 0.251 2.91 1.31 0.151 17 1.51 -- 2.61 6.1J -- MW-14 20-Oct-21 190 6.0 0.30 18 1.61 MW-15 8-Nov-11 118 0.700J 1.09J 16.5J -- 2.31J -- MW-15 5-Apr-12 1.011 117 5.951 18.7J - -- MW-15 7-Nov-12 1.201 133 18.3J - 5M.1 -- MW-15 16-May-13 1.3J 140 0.51 11 14 0.31 0.07J 21J - -- MW-15 7-Nov-13 220 0.05J 0.11 21 518 0.111 34J -- -- MW-15 8-Apr-14 0.81 160 1 0.51 41 0.3J 0.08J 23J 21 -- 7JB -- MW-15 27-Oct-14 1.61 180 0.41 0.2JB 21 0.21 25J -- 4113 -- MW-15 5-May-15 1.01 0.81 210 0.41 0.81 17 0.21 0.08J 28J -- 5JB -- MW-15 18-Nov-15 0.41 180 0.71 0.31 21 0.31 0.03J 27J 1.1 -- 51 -- MW-15 27-Apr-16 280 0.071 0.21 51 71 0.81 0.21 32J -- 6J -- MW-15 17-Nov-16 0.80J 0.361 190 0.491 2.0J 0.711 3.918 0.211 0.11J 30J 0.33.1 -- 1.81 7.0J -- MW-15 28-Apr-17 190 0.271 5.51 0.12J 23J 3.9J -- 2.71 5.6J -- MW-15 28-Sep-17 240 0.481 3.01 4.41 0.311 0.31 30J - 4.8J 4.6J -- MW-15 29-Mar-18 250 0.361 6.1.1 4.91 0.49J 0.23 28J - 5.31 5.OJ -- 3. MW-15 28-Nov-18 0.53J 190 0.60J 2.51 1.71 26J - 5.01 -- MW-15 29-Apr-19 220 0.321 1.4J 2.91 27J - 3.1J -- MW-15 24-Sep-19 220 1.0 1.51 4.2J 3.21 0.271 0.0931 24 -- 11B -- MW-15 15-Apr-20 220 0.291 I1 13 -- 3.2J -- MW-15 22-Oct-20 240 0.7 11 1.81 13 -- 4.51 -- MW-15 13-Apr-21 240 0.391 10 1.81 0.401 13 - 6.1J -- MW-15 20-Oct-21 180 2.41 25 1.3J Smith Page 4 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW-11 9-Nov-11 18.9 348 0.1231 6.121 5.691 4-915.311 -- 7.05J 13.8 -- MW-16 5-Apr-12 0.267J 14.6 433 4.111 5.20J 9.34J 2.681 -- -- MW-16 7-Nov-12 12.1 436 2.64J 6.13J 3.981 7.561 -- 5.46) -- MW-16 14-May-13 14 350 11 61 31 0.81 91 -- 3JB -- MW-16 5-Nov-13 16 260 11 51 110.3J 41 2.1 -- 7113 -- MW-16 8-Apr-14 13 300 0.31 51 11 0.31 0.02J 7J 2.1 -- 5J 6JB -- MW-16 27-Oct-14 20J 330 0.11 0.21B 51 11 0.41 71 -- 5113 -- MW-16 5-May-15 13 290 11 51 31 0.71 0.03J 7J 2.1 -- 5JB -- MW-16 3-Nov-15 12 300 0.41 51 118 0.41 71 -- 4J -- MW-16 27-Apr-16 12 330 0.71 41 0.51 81 11 -- 4J -- MW-16 16-Nov-16 14 280 0.341 0.731 4.41 1.51 0.73J 6.51 0.20.1 -- 6.51 -- MW-16 27-Apr-17 13 230 2.01 1.0J 0.281 3.9J -- 3.11 -- MW-16 26-5ep-17 12 320 4.21 1.31 7.11 -- 4.7J -- MW-16 29-Mar-18 14 250 1.81 4.81 6.7J -- 3.3J -- MW-16 28-Nov-18 19 170 4.41 6.61 -- 2.51 2.6J -- MW-16 2-May-19 12 210 0.131 3.81 4.11 0.49J 6.3J - 5.8B1 -- MW-16 24-5ep-19 21 170 0.16) 2.31 4.71 2.0J 0.79J 5.6 -- 2.5J 9.3BJ -- MW-16 dup 24-Sep-19 21 230 0.221 2.0J 4.9J 1.51 0.62J 8.3 - 3.21 9.86J -- MW-16 15-Apr-20 19 160 0.291 5.2 8.5 - 8.7 3.01 -- MW-16 21-Oct-20 15 200 1.4 4.4J 6.4 - 5.8J -- MW-16 14-Apr-21 13 180 0.55 3.71 5.6 - 5.2 -- MW-16 19-Oct-21 12 220 4.51 6.9 - 2.7J -- MW-16 dup 19-Oct-21 12 220 4.11 6.6 4.51 MW-17 9-Nov-11 13.3 190 0.1831 8.34J 1.121 6.55J 7.49J 8.80J -- 10.6J 27.5 -- MW-17 5-Apr-12 5.59J 105 1.701 2.00J 3.221 5.181 - 2.421 -- MW-17 7-Nov-12 0.226J 3.57J 156 1.93J 2.151 1.781 3.231 4.981 - 3.121 7.491 -- MW-17 14-May-13 101 120 0.081 0.11 21 21 31 21 51 -- 6113 -- MW-17 6-Nov-13 12 120 0.91 31 21 0.6J 3J - 22 -- MW-17 30-Apr-14 81 70J 0.31 11 31 21 0.71 0.041 31 -- 9JB -- MW-17 28-Oct-14 &1 140 0.04J 2JB M 31 21 0.02J 6J - 11 -- MW-17 5-May-15 11 140 0.21 0.11 51 61 71 31 91 - M 24 -- MW-17 19-Nov-15 14 ISO 0.091 0.11 21 71 31 21 101 11 - 30.1 -- MW-17 26-Apr-16 11 110 0.21 21 41 31 11 71 - 91 -- MW-17 17-Nov-16 0.221 12 120 0.211 1.818 0.30J 6.3J 0.201 - 3.71 3.5J -- MW-17 28-Apr-17 8.91 100 1.51 0.50J 2.9J 2.1J - 2.81 5.71 -- MW-17 26-Sep-17 9.5J 150 1.61 1.51 0.711 5.4J - 5.01 4.3J -- MW-17(dissolved) 26-5ep-17 -- -- -- -- -- -- -- -- -- -- -- -- -- - - 2.41 -- -- MW-17 29-Mar-18 0.53J 23 280 0.71J 0.431 25 14 33 15 31J -- 71 82 -- MW-17(dissolved) 29-Mar-18 -- 14 -- -- -- -- -- -- -- -- -- - 44 -- -- MW-17 28-Nov-18 6.2J 93J 0.60J 2.81 1.91 5.01 -- 111 3.3J -- MW-17 2-May-19 30 160 0.301 7.81 5.51 11 5.7J 13J -- 16J 30B -- MW-17(dissolved) 2-May-19 -- 7.2 -- -- -- -- -- -- -- -- -- -- -- - 21 -- MW-17 26-5ep-19 0.73J 9.4 120 0.241 1.51 4.01 -- 19 4.01 -- MW-17 15-Apr-20 5.6 76 4.1J - 3.0.1 -- MW-17 22-Oct-20 4.7 110 0.481 1.81 2.91 6.6 - 9.5 -- MW-17 14-Apr-21 5.5 91 0.30J 1.31 0.29J 6.2 - 6.6 -- MW-17 19-Oct-21 15 130 5.8 8.8 MW-18 8-Nov-11 104 1.33J 1.301 2.53JB 8.051 -- 2.09J 8.83.1 -- MW-18 4-Apr-12 89.51 1.44J 9.94J - -- MW-18 6-Nov-12 104 12.1J - 5M.1 -- MW-18 15-May-13 21 901 0.31 11 11 0.3J 13J - -- MW-18 6-Nov-13 4J 120 0.2J 41 41 61 21 0.02J 181 2J - 24 -- MW-18 10-Apr-14 2J 80J 0.51 11 21 0.03J 151 - 6JB -- MW-18 28Oct-14 2J 801 31 11 14J - 3J -- MW-18 5-May-15 21 901 0.31 11 21 15J - 4JB -- MW-18 19-Nov-15 2J 901 0.41 31 11 16J iJ - 4J -- MW-18 26-Apr-16 11 901 0.41 21 151 - 41 -- MW-18 16-Nov-16 2.3J 100 0.111 0.93J 2.21 0.471 16J 1.2J - 2.31 7.1J -- MW-18 27-Apr-17 3.21 110 0.- 3.21 5.61 1.91 0.0341 23J 3.7J - 6.91 16 -- MW-18 26-Sep-17 2.41 110 0.171 2.61 4.21 1.11 181 - M14 -- MW-18(dissolved) 26-5ep-17 -- -- -- -- -- -- -- -- -- -- -- -- - -- -- 5.91 -- -- MW-18 28-Mar-18 1.3J 981 1.91 17J -- -- MW-18 28-Nov-18 1.4J 100 1.6J 181 - -- MW-18 2-May-19 1.81 100 1.51 2.0J 0.361 7.81 -- 5.3B1 -- MW-18(dissolved) 2-May-19 -- -- -- -- -- -- -- -- -- - -- - - - -- - -- MW-SS 26-5ep-19 1.3J 100 2.51 14 -- 3.11 3.51 -- MW-18 15-Apr-20 110 2.81 17 2.9J - -- MW-18 21-Oct-20 1.7J 97 0.171 2.71 16 1.61 -- -- MW-18 14-Apr-21 4.8 100 0.28J 9.1 12 4.4 17 2.9J -- 40 -- MW-18(dissolved) 14-Apr-21 -- -- -- -- -- -- -- -- -- -- -- - -- -- -- -- MW-18 21-Oct-21 2.0 110 1.41 4.91 0.74J 21 -- 6.1J -- MW-18(dissolved) 21-Oct-21 -- -- -- -- -- -- -- -- -- - - - -- -- - -- Smith Page 5 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW-19 9-Nov-11 0.7011 4.521 169 0.4311 1.951 2.11J 0.1661 - - Pr- - 6.081 MW-19 4-Jun-12 -- -- -- -- -- -- -- -- 44,700 -- -- 230,000 MW-19 19-Jul-12 -- -- -- -- -- -- -- -- -- -- -- 40,100 -- -- -- 2410. -- -- MW-19 16-Aug-12 -- -- -- -- -- -- -- -- -- -- -- -- -- 42,500 -- -- - 110,000 MW-19 7-14ov-12 181 0.1491 4.97J 3.09J 6.141 34,8001 21.2 130.000 16-May-13 1J 180 1 21 21 0.41 51 MW-19 37,100 5J 220,000 MW-19 31-Jul-13 -- -- -- -- -- -- -- -- -- -- -- -- -- 40,500 -- -- - 242,000 MW-19 7-Nov-13 2J 170 0.51 0.11 118 1J 36,800 418 222,000 MW-19 16-Jan-14 -- -- -- -- -- -- -- -- -- -- -- -- -- 40,900 -- -- -- 232,000 MW-19 9-Apr-14 1.01 3J ISO 0.41 21 FM 71 0.41 0.04J 12J 10,200 10B 154,000 MW-19 29-Oct-14 4.11 21 150 0.91 21B 81 41 0.3J 101 14,900 9JB 170,000 MW-19 7-May-15 3.2J 2J 220 0.09J 0.21 31 18 14 0.31 0.03J 25J 7,900 27 150,000 MW-19 20-Nov-15 1.3J 21 150 0.081 0.3J 3J 51 5J 0.4J 101 11 81 134,000 MW-19 26-Apr-11 0.31 11 160 0.06J 21 51 19 0.21 151 7,900 81 120,000 MW-19 (dup) 26-Apr-16 0.4J 11 160 0.071 O.lJ 2J 51 20 0.2J 151 81 MW-19 16-Nov-16 0.581 2.1J 180 0.13J 3.OJ 31 6.OJ 0.471 16J 7,600 7.2J 160,000 MW-19 27-Apr-17 170 1.61 2.5J 6.01 0.34J 0.0481 9.51 18,000 6.21 170,000 MW-19 27-Sep-17 1.7J 170 1.51 200,000 MW-19 28-Mar-18 160 3.31 3.4J 0.49J 7.81 16,000 7.41 160,000 MW-19 27-Nov-18 1.7J 200 2.31 1.71 3.11 26,000 4.. 170,000 MW-19 1-May-19 1.61 210 4.3J 1.91 2.3J 1.1J 7.91 32,000 7.31 6.481 170,000 MW-19 25-Sep-19 2.6 230 0.221 3.81 4.W 2.71 0.26J 8.7 26,000 7.1 9.08J 210,000 MW-19 14-Apr-20 220 0.96 2.01 3.31 2.4J 1 11 11,000 3.2J 240 160,000 MW-19 21-Oct-20 1.91 180 1.81 0.66J 2.7J 37,000 6.5 2.7J 230,000 MW-19 13-Apr-21 200 0.16) 1.81 1.31 4.21 3.IJ 3.11 190,000 MW-19 20-Oct-21 1.6J 160 34,0000 5.6 210,000 MW-20 9-Nov-11 6.55J 290 0.3711 24.2 14.1 16.6 14.4 23.11 - 29.5 78.5 -- MW-20 5-Apr-12 0.722J 4.37J 162 4.66J 1.57J 4.30J 2.52J 4.25J - 6.281 9.311 -- MW-20 7-Nov-12 218 12.6 3.41J 5.42J 5.181 9.291 - 11.51 24.7 -- MW-20 14-May-13 0.3J 3J 190 0.11 31 M 14 31 91 - 51 19B -- MW-20 5-Nov-13 0.3J 4J 240 0.21 0.11 10 71 11 51 13J - oMi I81 47 -- MW-20 9-Apr-14 0.51 2J 160 0.3J 3J 21 568 21 0.03J 51 - 14J 51 -- MW-20 28-Oct-14 61 450 0.31 0.2J 7J 61 46 3J 0.091 101 - 45 137 -- MW-20 5-May-15 0.61 4J 220 0.2J 71 51 14 31 91 - Ill 38 -- MW-20 19-Nov-15 0.. 31 210 0.11 61 41 91 3J 81 - 81 26 -- MW-20 27-Apr-16 0.2J 4J 240 0.2J A51 81 41 91 - Il 28 -- MW-20 17-Nov-16 0.25J 3.71 290 0.521 0.181 12 8.41 19B 7.5J 181 0.201 - 21J 56 -- MW-20 27-Apr-17 2.OJ 110 0.821 1.6J - 3.91 -- MW-20 27-Sep-17 0.821 2.31 110 0.69J - 9.91 -- MW-20 29-Mar-18 2.4J 120 - 3.41 -- MW-20 28-Nov-18 2.51 120 - 4.7J -- MW-20 2-May-19 2.3J 130 1.91 0.26J 3.9J - 4.51 5.2BJ -- MW-20(dissolved) 2_May_19 __ __ __ __ __ __ __ __ __ __ __ __ __ __ -- 3.SJ MW-20 26-Sep-19 2.3 110 -- 4.61 3.4J -- MW-20 15-Apr-20 0.581 2.3 120 -- 4.21 -- MW-20 21-Oct-20 2.5 110 -- 4.21 -- MW-20 14-Apr-21 2.1 130 -- 4.7J -- MW-20(dup) 14-Apr-21 2.1 110 -- 4.51 -- MW-20 19-Oct-21 2.0 120 1.4J 6.4 3.61 MW-21 8-Nov-11 16.1 135 0.2951 12.7 7.881 13.1 11.88 13.21 -- 22.41 48.7 -- MW-21 4-Apr-12 6.23J 58.11 1.85J 2.481 4.35J 3.081 3.781 -- 6.781 11.7 -- MW-21 6-Nov-12 3.19J 76.41 3.52J 2.141 4.731 4.37J 3.13J -- 9.45J 18.3 -- MW-21 15-May-13 41 70J 0.081 2J 2J 4J 2) 31 -- 51 9JB -- MW-21 6-Nov-13 2J 60J 0.06J 21 11 318 11 2J -- 61 AB -- MW-21 9-Apr-14 61 220 OM 7J 51 11 51 0.041 101 -- 37 89 -- MW-21 28-Oct-14 3J 60J 0.04J 2JB 11 31 21 2J -- 41 71 -- MW-21 5-May-15 51 100 0.21 61 3J 81 4J 71 -- 13J 25 -- MW-21 19-Nov-15 2J 40J 0.05J 0.21 11 11 31 11 2J -- 31 71 -- MW-21 26-Apr-16 21 60J 0.051 11 11 2J I) 21 -- 61 -- MW-21 16-Nov-16 2.3J 561 0.0731 2.71 2.31 5.0J 2.4J 4.31 -- 6.31 13 -- MW-21 28-Apr-17 8.3J 0.811 -- 3.2J -- MW-21 26-Sep-17 4.3J 65J 0.291 5.91 3.91 8.61 3.6J 9.11 -- Ili 27 -- MW-21(dissolved) 26-Sep-17 -- -- -- -- -- -- -- -- -- -- -- -- -- - 4.71 - -- MW-21 28-Mar-18 3.6J 48J 4.71 5.1.1 1.9.1 3.21 -- 7.1J 10 -- MW-21(dissolved) 28-Mar-18 -- -- -- -- -- -- -- -- -- -- -- -- -- -- - -- MW-21 28-Nov-18 24J 1.4J 0.49J -- 5.31 -- MW-21 2-May-19 3.OJ 55J 5.51 5.1.1 4.01 3.91 -- 9.21 13B -- MW-21(dissolved) 2-May-19 -- -- -- -- -- -- -- -- -- -- -- MW-21 24-Sep-19 4.3 58 6.4 8.6 4.1 8.6 -- 8.4 27B -- MW-21(dissolved) 24-Sep-19 -- -- -- -- -- -- -- -- -- -- -- MW-21 14-Apr-20 0.63J 3.2 32 3.1.1 1.51 0.99J 1.61 -- -- MW-21(dissolved) 14-Apr-20 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- - -- MW-21 21-Oct-20 3.0 30 2.1.1 0.59J 1.61 -- 3.01 -- MW-21 13-Apr-21 2.3 37 3.7J 3.2.1 1.7 3.11 -- 8.71 -- MW-21(dissolved) 13-Apr-21 -- -- -- -- -- -- -- -- -- - - - - - - - -- MW-21 19-Oct-21 2.2 1 26 0.38J 3.11 Smith Page 6 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW-22 8-Nov-11 4.301 173 1.441 2.211B -- 1.821 14.6 -- MW-22 4-Apr-12 4.66J 159 2.171 2.411 2.381 2.79J - 3.14J 8.59J -- M MW-22 6-Nov-12 4.701 184 2.41J -- 1.47J 7.72J -- MW-22 15-May-13 3J 200 0.11 0.71 41 41 71 21 0.04J 7J - 19B -- MW-22 6-Nov-13 31 160 0.21 0.91 31 318 0.3J 0.061 31 -- 4113 -- MW-22 9-Apr-14 21 240 0.21 11 21 31 0.61 0.05J 4J - 9JB -- MW-22 28-Oct-14 31 250 0.11 0.5J 41B 71 7J 21 0.111 71 - 36 -- MW-22 5-May-15 4J 240 0.051 11 6J 31 0.6J 0.06J 51 - 7JB -- MW-22 19-Nov-15 41 240 0.091 21 71 51 11 0.031 61 11 - 11 -- MW-22 26-Apr-16 51 240 0.81 51 21 0.81 0.03J 51 - 91 -- MW-22 16-Nov-16 6.31 250 0.0841 4.61 1.11 0.24J 3.41 - 1.51 5.21 -- MW-22(dup) 16-Nov-16 6.3J 250 0.0581 4.61 1.21 0.26J 3.5J - 1.81 4.8J -- MW-22 28-Apr-17 5.61 240 4.31 1.9J 0.54J 1.61 5.11 -- 4.31 4.91 -- MW-22 26-Sep-17 6.3J 260 4.1J 2.01 0.371 3.3J -- 3.71 6.2J -- MW-22 (dissolved) 26-Sep-17 -- -- -- -- -- -- 3.61 -- -- -- -- -- -- -- -- 3.31 -- -- MW-22 28-Mar-18 9.01 310 2.21 6.2J 2.11 0.751 4.5J -- 7.9J -- MW-22(dissolved) 28-Mar-18 -- -- -- -- -- -- 5.21 -- -- -- -- -- -- -- -- -- -- -- MW-22 28-Nov-18 12 360 7.1J 4.0J -- 3.2J -- MW-22(dissolved) 28-Nov-18 -- 9.3 -- -- -- -- 6.6 -- -- -- -- -- -- -- -- -- - -- MW-22 2-May-19 19 440 1.4J 8.1J 1.51 0.43J 4.9J -- 6.7131 -- MW-22(dissolved) 2-10ay-19 -- 3.4 -- -- -- -- 7.2 -- -- -- -- -- -- -- - -- - -- MW-22 24-Sep-19 12 370 6.7 3.4J -- 5.4BJ -- MW-22 14-Apr-20 16 430 7.1 3.31 4.71 -- 4.11 -- MW-22 (dissolved) 14-Apr-20 - 7.6 - -- - -- 7.1 -- - - -- -- -- - - - - -- MW-22 21-Oct-20 12 410D 6.8 2.71 2.31 - 2.71 -- MW-22 13-Apr-21 14 480 4.4J 7.8 2.81 1.1 6.0 9.3J -- MW-22(dissolved) 13-Apr-21 -- 5.3 -- -- -- -- 6.8 -- -- -- -- MW-22 19-Oct-21 14 420D 7.4 0.43.1MW-22 (dissolved) 19-Oct-21 -- 8.6 I- -- - - -- -- MW-23 8-Nov-11 4.391 203 1.681 3.78JB -- 3.381 -- MW-23 4-Apr-12 201 1.031 2.76J 7.63J MW-23 5-Nov-12 MW-23 15-May-13 MW-23 5-Nov-13 No Samples Collected - Well was Dry MW-23 8-Apr-14 MW-23 27-Oct-14 2J 270 0.31 0.31 0.91 0.021 21 -- 4JB -- MW-23 5-May-15 MW-23 19-Nov-15 10 830 0.061 31 71 51 21 91 11 -- 20 -- MW-23 26-Apr-16 260 11 0.051 -- 12 -- MW-23 16-Nov-16 0.43J 3.2J 310 0.271 6.7J 0.981 6.01 0.211 -- 4.2J -- MW-23 28-Apr-17 2.31 210 2.41 0.78) 0.0411 7.81 -- 6.M 15 -- MW-23 26-Sep-17 0.76J 5.2J 440 1.11 3.4J -- 3.91 3.11 -- MW-23(dissolved) 26-Sep-17 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- MW-23 28-Mar-18 5.3J 370 1.71 0.371 2.2J -- 3.01 -- MW-23(dissolved) 28-Mar-18 -- -- -- -- -- -- 1.41 -- -- -- -- -- -- -- -- -- -- -- MW-23 28-Nov-18 1.81 310 1.51 -- 5.71 20 -- MW-23 2-May-19 1.31 280 2.11 2.91 -- 3.11 -- MW-23 24-Sep-19 5.9 440 5.0 4.51 -- 4.2BJ -- MW-23 14-Apr-20 330 0.14J 1.41 1.61 5.5 -- 6.091 -- MW-23 21-Oct-20 1.7J 270 0.421 3.91 1.71 2.7J 1.9J -- 6.4 8.2J -- MW-23(dup) 21-Oct-20 1.11 2.3 280 0.55 1.31 3.81 2.4J 0.71J 3.71 2.31 - 12.0 5.51 -- MW-23 13-Apr-21 1.4J 200 0.161 1.91 2.1J 2.2J - 3.51 -- MW-23 19-Oct-21 7.1 330 9.2 3.81 MW-24 9-Nov-11 20.1 402 0.1011 8.94J 12.6 1.671 7.001 0.237 24.4J -- 8.52J 23.8 -- MW-24 5-Apr-12 0.297J 27.2 599 0.439J 16.8 19.5 19.9 11.2 0.708 34.31 2.771 - 31.7 64.3 -- MW-24 7-Nov-12 15.2 415 7.431 11.7 3.441 3.751 0.192J 24.7J 2.24J - 9.921 26.2 -- MW-24 16-May-13 15 570 0.61 0.3J 21 24 41 15 0.171 45J -- 0.101 43 132 -- MW-24 6-Nov-13 15 360 0.11 31 12 4111 21 0.04J 26J 2.1 -- 14B -- MW-24 8-Apr-14 91 550 0.61 0.4J 25 23 31 18 0.26 46J -- 0.05J 219 -- MW-24 27-Oct-14 31 430 0.21 81 14 915.1 0.121 301 -- 49 -- MW-24 5-May-15 4J 160 0.7J 41 11 0.2J 111 -- 11JB -- MW-24 19-Nov-15 6J 200 0.05J 0.41 11 51 31 0.91 0.02J 15J 11 -- 9J -- MW-24 25-Apr-16 71 140 31 21 4J 11 101 -- 18 -- MW-24 15-Nov-16 0.371 7.8JD 370 0.811 0.541D 20D 19D 36 21 0.20 0.401 -- 0.0841 96 -- MW-24 27-Apr-17 17 330 6.51 0.84J 0.26J 25J 7.3J -- 3.7J -- MW-24 26-Sep-17 0.501 12 310 1.31 5.91 1.51 0.531 21J -- 8.51 -- MW-24 (dissolved) 26-Sep-17 -- 7.8J -- -- -- -- 4.21 -- -- -- -- - - - - - -- MW-24 28-Mar-18 9.31 260 1.31 7.01 191 - 4.81 -- MW-24(dissolved) 28-Mar-18 -- - -- -- -- -- 6.71 -- -- -- -- -- - - - -- - -- MW-24 28-Nov-18 IjM 310 0.191 4.81 8.61 5.41 3.8J 22J 2.4J - 26 -- MW-24 (dissolved) 28-Nov-18 -- 2.0 -- -- -- -- 3.51 -- -- -- -- - - - - - -- MW-24 2-May-19 6.6J 130 0.151 3.21 3.81 3.11 1.71 11J - 208 -- MW-24 (dissolved) 2-May-19 -- -- -- -- -- - 2.71 -- -- -- -- - - - - - -- MW-24 24-Sep-19 7.9 250 6.8 1.71 19 - - 9.2 11B -- MW-24 (dissolved) 24-Sep-19 -- -- -- -- -- - 5.5 -- -- -- -- -- -- - - 3.81 - -- MW-24 14-Apr-20 3.5 130 10 2.41 - 2.51 3.81 -- MW-24 22-0ct-20 2.1 49 0.221 2.11 0.56J 3.21 - 2.6J 3.9J -- MW-24 13-Apr-21 1.9J 29 1.5J 1.31 0.72J 1.51 - 4.21 4.41 -- MW-24 19-Oct-21 7.5 46 4.5J 0.42J 1.71 4.41 3.4J Smith Page 7 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o o MW-25 31-Mar-11 0.8571 836 1.171 4.621 8.851 -- 2.511 9.05J -- MW-25 8-Nov-11 3.59J 903 3.491 1.331 2.62JB 6.03J -- 8.201 18.3 -- MW-25 4-Apr-12 894 1.201 4.531 -- 1.92J -- MW-25 6-Nov-12 963 4.55J -- 5.231 5.511 -- MW-25 15-May-13 21 900 0.21 0.41 0.81 11 0.31 81 -- -- MW-25 6-Nov-13 2J 820 0.4J 0.7J 1JB 81 21 -- -- MW-25 9-Apr-14 21 830 0.41 0.71 L 0.31 81 31 -- 111 9JB -- 0.6J MW-25 28-Oct-14 21 780 0.41 0.71 81 2.1 -- 3J -- MW-25 5-May-15 21 820 0.3J 0.7J III0.041 81 -- 3JB -- MW-25 19-Nov-15 11 890 0.41 0.81 2J 91 11 -- 4J -- MW-25 26-Apr-16 830 0.71 81 -- -- MW-25 16-Nov-16 1.61 860 0.39J 1.21 7.8J 1.2J 0.321 - 2.0J 3.9J -- MW-25 27-Apr-17 2.01 890D 1.3J 13J 4.81 -- 1.71 5.51 -- MW-25 26-Sep-17 3.8J 1,0001) 0.26J 0.381 7.01 9.7J 3.6J 17J - 111 31 -- MW-25(dissolved) 26-Sep-17 -- -- 870 -- -- -- -- -- -- -- -- -- -- -- 3.L -- -- MW-25 28-Mar-18 2.01 960 0.401 111 -- 2.8J -- MW-25(dissolved) 28-Mar-18 -- -- 880 -- -- -- -- -- -- -- -- -- -- -- -- -- - -- MW-25 28-Nov-18 930 0.611 12J - 21 -- MW-25(dissolved) 28-Nov-18 -- -- 940 -- -- -- -- -- -- -- -- -- -- -- -- -- - -- MW-25 2-May-19 1.7J 900 0.441 1.31 12J 2.5J - 3.2131 -- MW-25(dissolved) 2-May-19 -- -- 930 -- -- -- -- -- -- -- -- -- -- -- -- -- - -- MW-25 24-Sep-19 1.51 890 0.54 12 - 4.3BJ -- MW-25(dissolved) 24-5eP-19 -- -- 960D -- -- -- -- -- -- -- -- -- -- -- -- -- - -- MW-25 14-Apr-20 930 0.441 11 -- 2.8J -- MW-25 22-Oct-20 1.41 830D 0.82 1.31 11 2.6J -- -- MW-25 13-Apr-21 1.7J 740D 0.231 7.5 2.3J -- 2.9J -- MW-25 19-Oct-21 2.2 770D 0.17J 1.61 4.51 2.3J 0.781 13 2.5J -- 7.8J -- MW-25 dissolved 19-Oct-21 -- -- 750 - -- -- 3.01 -- I -- I -- -- I -- I -- - - - -- -- MW-26 8-Nov-11 3.211 230 1.66 1.751 34.0 3.041E 16.31 -- 2.58J 52.5 -- MW-26 4-Apr-12 364 2.12 1.78 60.2 4.531 23.5J - 30.4 -- MW-26 6-Nov-12 357 1.98 47.9 1.85J 21.21 - 46.9 -- MW-26 IS-May-13 0.51 340 1.9 0.41 0.41 55 L 0.31 21J - 25 -- MW-26 6-Nov-13 51 400 1.8 0.41 40 17 10J 0.041 31J - 0.071 29 72 -- M 0.6J MW-26 9-Apr-14 330 1.6 0.41 56 2J 0.31 0.03J 20J - 51 30B -- MW-26 28-Oct-14 11 350 1.8 0.3J 0.41B 50 L 0.3J 0.04J 111 -- 25 -- MW-26 5-May-15 11 300 1.6 0.3J 2J47 3J 0.51 0.051 111 2J -- 26 -- MW-26 19-Nov-15 0.61 180 1.4 0.31 11 32 41 0.71 0.0. 131 11 -- 27 -- MW-26 26-Apr-16 180 1.1 2J 29 2J OM 0.03J 101 -- 36 -- MW-26 16-Nov-16 0.57J 170 1.2 0.21J 1.3J 25 2.91 0.81) 0.046J 9.7J 0.96J -- 16 -- MW-26 28-Apr-17 1.51 111 0.66J 0.13J 14 2.3J 1.4J 0.028J 6.9J 5.0J -- 17 -- MW-26 26-Sep-17 2.71 190 1.2 1.3 8.7J 26 9.3J 4.11 111 -- 35 -- MW-26(dissolved) 26-Sep-17 -- -- -- -- -- -- 22 -- -- -- -- -- -- -- -- -- MW-26 28-Mar-18 140 1.1 0.16) 1.41 21 1.81 0.291 8.51 -- 21 -- MW-26(dissolved) 28-Mar-18 -- -- -- -- -- -- 20 -- -- -- -- -- -- -- -- -- -- -- MW-26 28-Nov-18 190 0.831 0.161 26 1.81 111 -- 23 -- MW-26 2-May-19 220 0.79J 0.24J 34 2.71 0.27J 13J 2.3J -- 25B -- MW-26 24-Sep-19 200 1.3 0.25J 1.81 27 2.5J 0.82J 11 -- 21B -- MW-26 14-Apr-20 130 0.57 0.21J 16 2.41 6.9 3.1J -- 42 -- MW-26 21-Oct-20 70 0.63 0.50 9.9 2.2J 0.51J 4.61 -- 60 -- MW-26 14-Apr-21 1.4J 96 0.45 0.32J 3.01 30 4.5J 1.9 6.3 1.7J -- 43M 70 -- MW-26(dissolved) 14-Apr-21 -- -- -- -- -- -- 11 -- -- -- -- -- -- - - - -- MW-26 19-0ct-21 1.81 30 0.39J 0.27J 1.6J 4.01 7.9 1.3 3.8J - 5.7 35 -- MW-26(dissolved) 19-Oct-21 -- -- I -- -- I -- I -- 3.91 -- I -- I -- -- I -- I -- - - 6.2 -- -- MW-27 8-Nov-11 9.70J 128 0.159J 6.51J 4.231 5.94J 7.64JB 0.286 7.06J - 9.221 27.7 -- MW-27 4-Apr-12 4.27J 110 2.3W - 1.46J 5.25J -- MW-27 6-Nov-12 139 1.21J 1.471 1.71J 1.98J 2.02J - 13.3J 8.97J -- MW-27 15-May-13 21 110 11 0.41 11 - -- MW-27 6-Nov-13 4J 150 0.11 4J W 81 3J 0.091 81 - 111 25 -- MW-27 9-Apr-14 31 120 0.L 21 2J 0.6J 0.12J 2J - 71 81B -- MW-27 28-Oct-14 2J 140 0.71 0.3J 11 - 2J 2J -- MW-27 5-May-15 81 150 0.41 0.05J 2J - 31B -- MW-27 19-Nov-15 3J 130 0.4J 11 L - 4J -- MW-27 26-Apr-16 18 160 0.02J 4J - 10 -- MW-27 16-Nov-16 0.23J 2.4J 120 0.0491 0.38J 1.8J 0.48J 0.0401 1.61 - 151 4.11 -- MW-27 28-Apr-17 0.531 2.11 120 1.91 0.781 0.054J 1.5J - 211 5.5J -- MW-27 26-Sep-17 6.1J 470 0.541 0.34J 33 15 0.29 33J - 67 85 -- MW-27 (dissolved) 26-Sep-17 -- -- -- -- -- -- - -- - - - - 1.5.1 - -- MW-27 28-Mar-18 110 - 4.4J -- MW-27(dissolved) 28-Mar-18 -- -- -- -- -- -- -- -- -- - - - - - - -- MW-27 28-Nov-18 1.5J 951 - 7.5J -- MW-27 30-Apr-19 220 0.13J 9.2J 16 6.31 111 - 111 111 - 3 MW-27 24-Sep-19 2.3 100 - 8.1 3.681 -- MW-27 14-Apr-20 2.7 100 1.41 - - MW-27 21-Oct-20 4.5 130 2.6J - -- MW-27 14-Apr-21 8.0 100 .71 1.4J - - M W-27 19-Oct-21 2.9 130 Smith Page 8 of 18 January 2022 Table 4a Detected Groundwater Constituents - Inorganics October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 o o MW-28 9-Nov-11 18.8 464 0.791J 47.1 25.5 30.3 11.1 34.01 -- 85.6 180 -- MW-28 5-Apr-12 2.961 233 14.0 7.61J 12.6 5.461 11.2J - 30.2 51.4 -- MW-28 6-Nov-12 24.4 620 0.359J 21.7 11.0 19.7 9.091 17.01 2.191 -- 62.3 90.4 -- MW-28 15-May-13 33 3040 1.7 0.5J 67 52 65 32 0.04J 67 - 0.3J 291 683 -- MW-28 6-Nov-13 51 300 0.41 0.2J 15 12 16 6J 15J 21 -- 53 94 -- MW-28 9-Apr-14 11 160 0.3J 21 11 144 0.6J 0.04J 3J - 14J 31 -- 6J MW-28 28-Oct-14 0.81 150 31B 11 91 0.5J 31 - 30 -- MW-28 5-May-15 11 270 0.8J 0.51 11 2J - 3113 -- MW-28 19-Nov-15 21 190 0.11 61 12 L 51 L - 23J 21 -- = 0.4J MW-28 26-Apr-16 5J 300 - -- MW-28 16-Nov-16 0.381 0.581 180 0.081J 0.971 1.7J 1.61 -- 5.3J 2.81 -- MW-28 27-Apr-17 2.4J 230 0.36J 11 3.61 111 -- 24J 43 -- MW-28 27-5ep-17 0.65J 7.21 370 1.0 0.60J 39 12 28J -- 0.13J 75 120 -- MW-28 (dissolved) 27-Sep-17 -- -- -- -- - -- -- - -- -- -- -- - 8.01 -- MW-28 28-Mar-18 7.21 470 1.4 0.49J 60 16 43J -- 0.191 81 220 -- MW-28 (dissolved) 28-Mar-18 -- -- -- -- - -- - -- -- -- -- - 2.5J -- -- MW-28 28-Nov-18 2.01 170 0.191 5.71 1.71 .1 -- 111 20 -- MW-28(dissolved) 28-Nov-18 -- -- -- -- -- -- -- -- -- -- -- - - 4.2J -- -- MW-28 2-May-19 250 0.14J 1.51 -- 2.6J 3.9B1 -- MW-28(dissolved) 2-May-19 -- -- -- -- -- -- -- -- -- -- -- -- MW-28 26-Sep-19 180 -- 3.2J 3.71 -- MW-28 15-Apr-20 150 0.151 1.3J 1.6J -- 4.8J 2.8J -- MW-28(dissolved) 15-Apr-20 -- -- -- -- -- -- -- -- -- -- -- -- -- -- - 3.81 -- -- MW-28 21-0ct-20 1.7J 180 0.20J 0.191 3.71 5.7 1.6 4.1J -- 16 29 -- MW-28(dissolved) 21-Oct-20 -- -- -- -- -- -- -- -- -- -- -- -- -- - 6.8 -- -- MW-28 14-Apr-21 280 0.24J 1AJ - -- MW-28 21-Oct-21 0,651 260 0.31J 1.41 1.9J 0.45J 2.61 9.91 MW-29 9-Nov-11 142 0.1731 2.53J 2.63J 2.501 3.42J -- 2.961 8.54J -- MW-29 (dup) 9-Nov-11 154 0.233J 4.471 3.01J 3.091 3.35J 4.951 -- 3.951 16.5 -- MW-29 5-Apr-12 827 4.23 42.2 28.1 116 57.2 -- 0.245J 28.7 186 -- -- MW-29 4-Jun-12 -- -- -- -- -- -- -- -- -- -- -- -- 9,800 -- -- -- 190,000 MW-29 19-Jul-12 -- 12,900 260,0MW-29 -- -- -- -- - 16-Aug-12 -- -- -- L - - - - -- -- -- -- 135 -- - - 160,000 MW-29 7-Nov-12 375 231.2 16.9 12.2 21.1 31AJ 13,400 0.136J 23.91 132 220,000 MW-29 16-May-13 28.6 2.3 140 100 1610 193 0.29 200J 5,600 0.81 575 101 2300 316,000 MW-29 31-Jul-13 -- -- -- -- -- -- -- -- -- -- - -- -- 20,000 -- -- -- 309,000 MW-29 7-Nov-13 7J 2330 25 2.4 150 100 360 176 0.29 2901 21 21700 0.81 707 847 312,000 MW-29 16-Jan-14 -- -- -- -- -- -- -- -- -- -- - -- -- 13,600 - -- -- 129,000 MW-29 9-Apr-14 71 630 0.81 68 32 71 33 0. 16J 55 12,300 0.3J 124 168 268,000 MW-29 29-Oct-14 41 330 1.5 0.51 20 31 31 18 0.091 21J 13,900 0.11 47 74 228,000 MW-29 6-May-15 71 470 2.3 0.3J 35 19 50 20 0.061 37J 12,100 X 53 104 202,000 MW-29 20-Nov-15 2J 250 1.1 1.4 14 71 20 17 0.071 151 0.11 41 87 160,000 MW-29 27-Apr-16 350 1.5 0.2J 19 11 25 21 20J 11,000 0.11 46 70 176,000 MW-29 17-Nov-16 0.381 3.81 450 2.9 0.37J 26 17 58B 27 0.083J 34J 0.391 10,000 0.12J 28 110 130,000 MW-29 27-Apr-17 83J 0.401 5.5J 2.S1 8.2J 5.81 0.0321 7.41 9,100 111 19 180,000 MW-29 27-Sep-17 2.61 991 1.61 4.01 0.85J 0.361 5.81 11,000 4.81 6AJ 10,000 MW-29 29-Mar-18 1.41 150 0.871 0.131 19 5.81 21 9.81 15J 9,600 46 410,000 MW-29(dissolved) 29-Mar-18 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- MW-29 28-Nov-18 64J 6.51 1.91 5.61 2.21 7.41 7,900 4A1 11 130,000 MW-29(dissolved) 28-Nov-18 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- MW-29 2-May-19 3.31 130 0.161 5.31 11 4.1J 1.9J 14J 13,000 SAJ 13 MW-29(dissolved) 2-May-19 -- -- -- -- -- -- 7.5 -- -- -- -- -- -- -- -- -- MW-29 26-Sep-19 2.5 130 1.61 5.7 1.7J 0.64J 9.1 14,000 -- 6.61 180,000 MW-29(dissolved) 26-Sep-19 -- -- -- -- -- -- 5.9 -- -- -- -- -- -- -- -- -- MW-29 15-Apr-20 89 0.441 2.61 1.81 3.3J 0.861 9.7 14,000 8.01 180,000 MW-29(dissolved) 15-Apr-20 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- MW-29 22-Oct-20 1.91 87 0.151 2.61I2.9J 1.3 9.0 11,000 3.11 14 190,000 MW-29(dissolved) 22-Oct-20 -- -- -- -- -- -- MW-29 14-Apr-21 78 0.331 4.7J 4AJ 2.3 8.1 12,000 5.8 30 140,000 MW-29(dissolved) 14-Apr-21 -- -- -- -- -- -- MW-29 21-Oct-21 2.1 130 0.221 0.26) 3.61 6.4 2.5 9.6 14,000 5.8 15 140,000 MW-29(dissolved) 21-Oct-21 -- -- -- -- -- -- -- I -- I -- I -- -- -- -- I - I I -- I -- Notes: 1. All units are in micrograms per liter (parts per billion). 2.' - Interim Maximum Allowable Concentration (IMAC) 3. dup -Duplicate Sample 4. J - Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the laboratory limit of quantitation. 5. B -The amount in the prep blank is greater than the method detection limit. 6. D - The analyte was run at dilution. 7. H - The anaylte was analyzed outside of hold time due to laboratory error. 8. S - Matrix spike/matrix spike duplicate failure. 9. - Not analyzed 11. NE -Standard Not Established 11. Dissolved metals samples were collected to evaluate the influence of turbidity on total metal concentrations. Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or IMAC - Indicates the result is below the detection limit - A sodium lactate injection was performed near MW-8, -9, and -10 on June 18-21, 2012. - An emulsified vegetable oil injection was performed near MW-8, -9, and -10 on March 25-27, 2013. Smith Page 9 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-2 MW-2 8-Nov-11 4-Apr-12 J.6 0.651 MW-2 6-Nov-12 ID MW-2 15-May-13 MW-2 6-Nov-13 1.J1 MW-2 9-Apr-14 5.11 1.31 MW-2 28-Oct-14 1.91 MW-2 5-May-15 1W 2.JJ 0.39J MW-2 19-Nov-15 9.1 MW-2 2&Apr-16 2.3J MW-2 1]-Nov-16 3.11 MW-2 27-Apr-17 1.2J MW-2 26-Sep-17 1.W MW-2 2&Mar-I8 0.66J MW-2 28-Nov-18 0.91 MW-2 2-May-19 MW-2 26-Sep-19 2.1 1.]J MW-2 15-Apr-20 0." MW-2 22-Oct-20 1.4 MW-2 14-Apr-21 MW-2 21-Oct-21 0.86 MW-4 &Nov-11 2.01 MW-4 4-Apr-12 0.511 0.451 1.91 MW-4 &Nov-12 2.21 MW-4 1&May-13 0.52 1.21 1.91 0.321 MW-4 &Nov-13 2.11 MW-4 9-Apr-14 0.631 0.65J 2.21 0.261 MW-4 28-Oct-14 0.431 2.41 0.431 MW-4 5-May-15 0.64J 0.511 3.51 MW-4 19-Nov-15 0.561 0.321 3.11 0.241 0.441 MW-4 2&Apr-16 0.5W 3.81 MW-4 16-Nov-16 0.521 0.6W 3.11 0.641 0.40 MW-4 2&Apr-17 0.]4J 0.]3J 4.21 0.571 0.54J MW-4 26-Sep-17 0.421 3.91 Z 2&Mar-18 0.4W 3.41 0.411 MW-4 28-Nov-18 0.52 3.8 0.4W 0.62 0AW MW-4 2-May-19 0.441 0.50 0.95 5.0 0.59 0.52 MW-4 24-Sep-19 0.4]1 0.4W 5.1 0.55 - 0.451 MW-4 14-Apr-20 0.481 0.97 5.1 0.62 - 0.52 MW-4 21-0ct-20 0.461 0.74 4.6 0.57 - MW-4 13-Apr-21 0.461 0.93 5.J 0.68 - MW-4 19-0ct-21 0.95 0.53 MW-6 9-Nov-11 1.11 MW-6 4-Apr-12 1.41 MW-6 &Nov-12 1.81 MW-6 15-May-13 0.931 0.911 2.11 0.]]J 5.6 5.4 0.241 MW-6 &Nov-13 3.01 MW-6 9-Apr-14 TU 0.6W 0.]41 4.11 0.31J 5.4 4.11 MW-6 28-Oct-14 0.2W 0.941 3.21 0.42J 3.61 2.01 MW-6 5-May-15 0.]]1 1.21 2.61 . 4.51 1.51 MW-6 18-Nov-15 0.74J 0.361 0.351 5.01 1.11 MW-6(dup) 18-Nov-IS 0.6M 0.37J 0.321 4.81 1.11 MW-6 27-Apr-16 0.401 O.JOJ M 0.94J MW-6 I6-Nov-16 0.4JJ 1.51 1.]J 0.501 5.4 1.81 G. MW-6 2J-Apr-1] l.JJ 0.911 0.5W 5.4 O.JJJ MW-6 2]-Sep-I] 0.9W 0.69J 3.91 0.421 MW-6(dup) 2]-5ep-1] 0.931 0.J01 3.81 0.5]J MW-6 28 Mar 18 6.2 3.SI 1.5 5.9 4.71 0.831 MW-6(dup) 28-Mar-18 1.1 5.9 3.]1 1.5 5.7 4.51 0.J91 MW-6 28-Nov-18 1.2 4.2 3.5 1.3 5.3 4.0 11 MW-6 2-May-19 1.1 3.4 2.9 1.1 4.8 3.8 13 6.9 2.1 MW-6 26-5ep-19 0.60 0.61 2.4 1.9 12 I.JI MW-6 15-Apr-20 1.1 6.2 2.9 1.2 4.8 6.2 20 ].5 0.79 MW-6 21-Oct-20 6.6 3.3 1.4B 4.0 10 27 8.8 1.4 MW-6 14-Apr-21 0.80 3.5 1.6 0.60 2.7 2.3 18 7.3 0.991 MW-6 21-Oct-21 1.5 1.1 2.3 1.8 M 2.31 OA51 MW-8 J-Nov-11 0.5. MW-8 4-Apr-12 3.31 4.31 0.J2J 2.71 0.461 0.381 0.331 0.551 0.801 3.6 MW-8 19-M-12 ].61 MW-8 1&Aug-12 MW-8 &Nov-12 0.4L 0.601 MW-8 15-May-13 0.81J 0.47J MW-8 31-M-13 0.891 O.J]J 0.261 MW-8 &Nov-13 MW-8 164 -14 0.571 0.3W MW-8 10-Apr-14 ].41 0.2W 0.97J MW-8 29-0ct-14 0.59J 0.521 0.311 0.201 MW-8 7-May-15 11J O.J21 0.401 0.9W 0.3W MW-8 19-Nov-15 0.391 0.751 0.671 0.341 0.22) MW-8 2&Apr-16 1.51 0.59J MW-8 16-Nov-16 2.71 2.71 1.41 0.4W 0.681 MW-8 2&Apr-I] 1.2J 0.6W IM MW-8 2]-5ep-1] O.J21 0.631 MW-8 28-Mar-18 MW-8 27-Nov-18 0.86 1 0.431 MW-8 1-May-19 1.1 2.5 1.8 0.45J 1.2 0.84 1.3 MW-8 25-5ep-19 0.51 - 0.61 MW-8 14-Apr-20 0.69 - MW-8 21-0ct-20 3.1 2.0 0.80 - 1.1 MW-8 13-Apr-21 1.461 1.7 5.0 1.1 - 0.50 MW-8 20-0ct-21 2.0 1.9 0.491 0.69 Smith Page 10 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 I 16.30 I I MW 91du P� 4-APr-12 0.421 3.61 46 3.31 4.11 0.]41 4.9 0.471 4.0 6A 0.941 0.541 2.8J 0.491 0.46 12 0.441 MW 9 16--Aug 120 i6 6.01 41 1.21 3.91 2 MW-9 6-Nov-12 250 0.501 37J 6.1J 2.11 32 1.41 3.61 0.871 5 0.61 018E 0.90 281 21 2.81 2.21 MW-9 15-May-13 0.40 21 1.421 0.631 0.761 MW-9(dup) 15-May-13 0.9W 2W 16 1.41 20 2.51 2.21 0.591 0.711 MW-9 31-1u1-13 0.]51 22 3.11 1.91 0.851 MW-9 6-Nov-13 321 0.731 4.21 19 1.51 1.71 1.471 1.5 4.91 MW-9 16-1an-14 241 0.571 19 0.741 1.61 0.551 4.1 0.561 MW-9 10.Apr-14 131 0.7D 20 0.661 17 0.171 2.31 1.21 0.51) 2.6 1.9 MW-9 (du 10.Apr-14 231 0.601 21 0.591 16 2.41 1.21 2.2 1.4 MW-9 29-Oct-14 6.41 0.661 15 0.47J 11 1.41 0.63J 0.411 0.98) MW-9(dup) 29-Oct-14 8.91 0.631 16 0.471 0.43J 10 1.31 0.661 0.041 1.091 1.7 MW-9 7-May-15 1.1 16 1 19 1.61 2.01 1.3 0.911 MW-9 20-Nov-15 0.861 15 0.74J 0.6D 11 1.01 0.521 DA31 1.51 0.331 0.891 0.471 MW-9 27-Apr-16 0.961 14 0.74J 14 0.601 0.511B 0.411 0.]81 0.531 MW-9 16-Nov-16 1.3 12 0.77J 0.44J 7.4 2M 0.731 MW-9 27-Apr-17 1.1 13 0.97J 12 0.67J 2.W 0.401 MW-9 27-Sep47 1.1 14 0.891 6.9 1.]1 0."1 MW-9 29-Mar-18 2.2 11 0.881 8.7 0.47J 1.W MW-9 28-Nov-18 1.7 0.55 13 1.4 9.5 0.54 0.611 MW-9 1-May-19 2.3 1.6 16 2.2 13 0.67 8.7 1.51 MW-9 26-Sep-19 1.2 0.87 15 1.4 4.7 6.8 1.51 MW-9 14-Apr-20 1.6 1.2 13 1.8 6.9 8.2 1"1 MW-9 22-0c[-20 1.6 1.3 17 1.8 4.0 8.3 MW-9 14-Apr-21 2.8 1.3 14 1.9 9.5 8.8 1.]1 MW-9 20-0ct-21 0.89 0.82 10 1.1 0.81 6.3 MW-10 4-Apr-12 6AJ 4.9 0.351 2.5 0.551 54 2.81 0.381 1.6 0.811 1.4J 0.531 0.511 1.11 MW-30 19-1ul-12 840 220 8.51 30 MW-10 16-Aug-12 5800 1,100 MW-10 6-Nov-12 780D 330D 21D 4.21D MW-10(dup) 6-Nov-12 700D 310D 21D 3 91D 1.91 MW-10 15-May-13 530.0 8]1 24 0.5W 0.331 1.31 1.]1 0.361 4.6 MW-10 31-Jul-13 2.9 18 0.631 D401 0.781 0.481 0.251 20 MW-10 6-Nov-13 2.1 21 1.2 3.01 2.5 MW-10 6-Nov-13 1.6 1B 0.931 2 41 2.6 MW-10 16-1an-14 6.61 2.6 17 1.5 12 1.31 1.1 0.691 0.761 1.4 1.1 MW-10 10 Apr 8.01 2.8 0.311 16 1.7 20 0.221 1.11 1.4 1.31 0.92) 2.5 4.2 MW-10 29-Oct-14 1.4 0.251 18 1.6 9.0 0.43J 0.271 0.481 0.661 0.391 MW40 7-May-15 6.6 0-T 23 3.6 68.0 OAM 1.91 0.361 2 2.W 2.91 2.331 0.2]1 4.5 MW-10 20-Nov-15 17J 4.1 1.M 17 0.651 4.0 46 OAN 0.94J 0.221 1.5 1.1 2.W 0.80 ID 0.34J 2.9 MW-10 27-Apr-16 17J 5.6 0.771 27 4.3 44 0.481 0.951 0.941B 2.9 MW-10 16-Nov-16 2.31 4.7 0.]Il 16 3.7 0.421 31 0.631 0.701 0.431 0.671 0.491 0.501 MW-10 27-Apr-17 ].11 1.4 0.401 9.61 2.8 23 0AW 2.2 MW-SO 27-Sep47 1.2 8.51 1.3 1.5 MW-10 29-Mar-18 1.7 DAU 9.11 1.9 17 MW-10 28-Nov18 4.3 1.7 13 4.2 29 0.59 1.3 0.76 2.0 2.1 MW-10 1-May-19 3.61 4.2 3.0 17 4.2 27 0." 0.91 0.441 0.86 6.0 0.93) 1.6 MW-10 26-Sep-19 1.6 1.0 1.2 1.7 12 a.4 0.421 0.82 MW-10 14-Apr-20 4.41 3.4 2.4 12 3.8 21 0.451 28 0.56 7.5 1.] MW-10 22-Oct-20 4.W 4.5 3.4 15 5.0 36 0A71 0.73 25 0.63 2.71 2.8 MW-10 14-Apr-21 34 3.3 60 1.] 14 2.8 25 27 3.31 0.62 3.71 0.56) 1.6 MW-10 20-Oct-21 5.2J 2.0 1.9 9.1 2.5 16 MW-11 4-Apr-12 MW-11 6-No 12 MW-11 15-May-13 MW-11 6-No 13 MW-11 10.Apr-14 MW-11 29-0ct-14 MW-11 6-May-15 0.55J 0.40J MW-11 20-Nov-15 0.57J MW-11 27-Apr-16 7.31 MW-11 I6-Nov-16 MW-11 2B-Apr-17 MW-11 28-Sep-17 MW-11 19-Mar-18 MW-11 28-Nov-18 MW-11 2-May-19 0.50 1.0 2M 1.01 MW-11 26-Sep-19 0.71 1.W 2.31 MW-11 15-Apr-20 MW-11 22-0ct-20 MW-11 14-Apr-21 8.W 3.51 MW-11 21-00-21 1.51 MW-12 3-Apr-12 MW-12 5-N_12 MW-12 15-May-13 MW-12 6-Nov-13 MW-12 10.Apr-14 MW-12 28-00-14 MW-12 6-May-15 0.331 MW-12 20-Nov-15 7.81 0.821 MW-12 27-Apr-16 MW-12 17-Nov-16 MW-12 27-Apr-17 MW-12(dup) 27-Apr-17 0.43J MW-12 28-5ep-17 MW-12 29-Mar-18 MW-12 27-Nov-18 MW-12 1-May-19 0.83 IS MW-12 26-5ep-19 12 1.01 MW-12 14-Apr-20 IS 1.2J MW-12 22-Oct-20 11 MW-12 14Apr-21 I6 MW-12 20-Oc[-21 4.7 Smith Page 11 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-13 8-Nov-11 2.1 15.0 2.0 1.91 MW-13 3-Apr-12 34 1].0 3.0 2.31 MW-13 5-Nov-12 1.6 13.0 2.5 0.52 1.41 MW-13 16-May-13 1.5 18 0.521 3.2 2.41 MW-13 7-Nov-13 1.4 12 0.73J 1.]I MW-13 10.Apr-14 1.9 12 2.4 2.11 MW-13 28-Oct-14 1.4 13 2.1 1.31 MW-13 6-May-15 2 13 2.7 2.31 0.281 0.2M MW-13 20-Nov-15 2.2 9.0 0.63J 1.9 1.41 0.321 MW-13 27-Apr-16 1.4 12 2.6 1.41 MW-13 17-Nov-16 0.941 8.3 2.0 0461 0.9W MW-13 28-Apr-17 1.3 11 2.2 1.01 MW-13 28-Sep-1] 1.3 10 2.4 1.21 MW-13 29-Ma 18 0.821 7.7 1.4 0.641 MW-13 27-Nov-18 0.71 6.6 1.1 0.47J 2.W MW-13 29-Apr-19 0.74 6.8 0.50 1.4 0.63 2.M MW-13 29-Apr-19 0.76 6.9 1.3 0.61 MW-13 26-Sep-19 0.70 6.5 1.0 0.66 6.4 MW-13 15-Apr-20 0.64 5.8 1.1 0.53 4.4 MW-13 22-0c-20 0.67 5.7 1.2 2.11 MW-13 14-Apr-21 0.62 4.6 0.80 2.91 MW-13 20-0ct-21 0.53 4.9 1.1 5.3 MW-14 7-Nov-11 251 MW-14 3-4r-12 0.3M 0.63J 1.21 MW-14 5-Nov-12 0.47J MW-14 16-May-13 0.4W MW-14 7-Nov-13 MW-14 10-Apr-14 0.23J MW-14 28-Oct-14 0.471 0.41J 0.59J 0.191 MW-14 6-May-IS 0.40J 0.2W 0.611 MW-14)dop) 6-May-15 111 0.37J 0.67J MW-14 20-Nov-15 8.21 0." 0.951 1.2 0.71J 1.11 0.531 0.221 MW-14 27-Apr-16 0.]51 3.3 1.2 1.41 0.611 MW-14 17-Nov-16 0.651 3.1 0.97J 0.45J 0.981 MW-14 28-Apr-17 0.8W 0.43J 0.621 MW-14 28-Sep-0 2.21 1.21 0.501 0.621 MW-14 29-Mar-18 1.11 MW-14 2]-Nov-18 0.71 5.4 1.2 0.401 0.91 0.50 9.9 MW-14 )dup) 27-Nov-18 0.83 5.6 1.2 0.93 0.51 9.9 MW-14 29-Apr-19 0.86 6.7 0.401 1.2 0.87 0.55 8.7 1.3) MW-14 25-5ep-19 1.1 8.3 MW-14 15-Apr-20 2.1 0.40J 7.7 MW-14)dop) 15-Apr-20 1.9 0.401 8.4 MW-14 22-Oct-20 ON 12 1.1 7.1 MW-14 13-Apr-21 0.401 3.3 0.4W 8.0 MW-14 20-Oct-21 0.67 7.0 0.82 6.2 MW-15 8-Nov-11 0.85J MW-15 5-Apr-12 0.59J MW-15 7-Nov-12 0.451 0.4W 0.97J MW-15 16-May-13 0.351 0.691 MW-15 7-Nov-13 1.01 MW-15 8-Apr-14 0.851 0.581 0.651 MW-15 27-Oct-14 1.11 0.68J 0.96J MW-15 5-May-15 0.47 3.1 0.581 1 0.6W 0.47J MW-15 18-Nov-15 0.M IX0.87J 1.31 0.54J 0.221 MW-15 27-Apr-16 0.341 5.3 1.5 1.2J 0.5W MW-15 17-Nov-16 1.71 0.74J 0.74J MW-15 28 Apr-17 3.2 0.92J 0.5W 0.611 MW-15 28-Sep-1] 3.4 0.92J 0.911 MW-15 29-Mar-18 2.W 0.73J 0.57J MW-15 28-Nov-18 0.69 0.58 MW-15 29-Apr-11 2.6 0.48J 5.4 MW-15 24-5ep-19 3.7 0.57 0.4W 6.7 MW-15 15-Apr-20 4.1 0.79 3.7 MW-15 22-0c-20 4.6 0.93 4.2 MW-15 13-Apr-21 3.3 0.76 4.3 MW-15 20-0ct-21 0.86 30 1.2 045J 7.7 MW-16 4Nov-11 1.3 2.31 5.1 4.31 0.931 MW-16 5-Apr-12 211 1.4 0.531 1.91 1.]1 56 2.91 2.0 MW-16 7-Nov-12 341 1.5 0.5. 3.11 3.6J 6.8 3.31 5.5 0.351 MW-16 14-May-13 1.3 0.611 2.41 5.21 7.1 3.31 5.8 MW-16 5-Nov-13 1.2 2.51 6.5 3.51 2.9 MW-16 8-Apr-14 2.2 0.401 3.51 3.31 8.3 0.191 3.61 0.921 4.9 MW-16 2]-Oct-14 0.991 0.351 2.7J 2.51 6.2 0.811 2.71 3.] MW-16 5-May-15 1.2 0.361 0.4W 2.51 7.3 3.51 1.51 3.5 0.36J MW-16 3-Nov-15 1.0 1.01 1.91 6.5 0.17J 2.81 3.9 0.3W MW-16 27-Apr-16 1.0 0.391 1.31 0.261 ].0 3.31 2.0 0.491 MW-16 16-Nov-16 1.2 0.991 2.91 6.1 2.81 0.451 3.4 0.431 MW-16 27-Apr-1] 0.911 1.3 1.61 6.2 3.81 1.7 MW-16 26-5ep-1] 0.981 1.41 0.941 5.5 2.61 2.1 MW-16 29-Mar-18 1.3 1.]1 2.01 4.01 0.551 2.9 MW-16 28-Nov-18 1 2.1 5.9 3.7 2.6 MW-16 2-May-19 0.89 1.4 3.0 5.4 2.7 0.51 MW-16 24-5ep-19 0.64 0.60 2.0 4.8 2.2 - 0.63 1.8 MW-16&p 24-5ep-19 0.67 0.67 2.3 4.9 2.1 - 0.72 2.0 MW-16 15-Apr-20 6.5J 0.51 0." 4.0 4.7 1.6 - 1.0 1.8 MW-16 21-0ct-20 0.461 0.471 2.4 4.3 1.5 - 0.66 1.4 MW-16 14-Apr-21 0.421 2.2 3.4 1.2 - 1.0 MW-16 19-Oct-21 0.51 0.50 4.6 4.3 1.5 MW-16dp 19-Oct-21 0.52 0.49 1.6 4.4 1.5 0.67 1.] Smith Page 12 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-17 9-Nov-11 5.61 11 281 MW-1] 5-Apr-12 2.91 19 2.31 0.49J MW-17 7-Nov-12 3.61 18 2.J1 0.43J MW-1] 14-May-13 2.11 14 2.11 MW-17 6-Nov-13 10 1.31 MW-1] 10-Apr-14 6.71 1.51 10 1.31 MW-17 28-Ott-14 5.31 ii 2.11 1.411 MW-1] 5-May-15 191 101 0.851 14 2.01 0.411 MW-1] 19-N--15 7.9J 0.841 0.9W 16 0.311 2.71 0.241 0, MW-17 26-Apr-16 0.33J 10 1.41 MW-17 17-Nov-16 2.7J 2.41 9.8 1.41 MW-17 28-Apr-17 1.81 12 1.41 MW-17 26-Sep-1] 3.21 7.1 1.21 MW-17 29-Mar-18 1.M 6.2 0.97J MW-17 28-Nov-18 9.3 1.4 14 MW-1] 2-May-19 1.8 ].] 1.1 13 MW-17 26-Sep-19 1.1 7.3 0.82 15 MW-1] 15-Apr-20 4.5 21 MW-1] 22-Oct-20 0.94 041J 7.0 0.75 25 MW-1] 14-Apr-31 0.481 3.9 m MW-1] 19-Oct-21 1.2 5.5 0.64 28 MW-18 8-Nov-11 MW-18 4-Apr-12 MW-18 6-Nov-12 MW-18 15-May-13 MW-18 6-Nov-13 MW-18 10-Apr-14 MW-18 28-0ct-14 MW-18 5-May-15 7.1J 0.52J MW-18 19-Nov-15 7.31 0.291 MW-18 26-Apr-16 MW-18 16-Nov-16 MW-18 27-Apr-17 MW-18 26-Sep-17 MW-18 28-Mar-18 MW-18 28-Nov-18 10 MW-18 2-May-19 0.47J 0.69 2.8J MW-18 26-Sep-19 1.5 2.01 MW-18 15-Apr-20 9.4 1.7) MW-18 21-0ct-20 10 2.31 MW-18 14-Apr-21 1.1 3.2 MW-18 21-0ct-21 12 2.71 MW-19 9-No 11 MW-19 5-Apr-12 1.01 194.1-12 4.OJ MW-19 MW-19 16-Aug-12 MW-19 7-Nov-12 16-May-13 230 MW19 Z19 31-h1-13 MW-19 ]-Nov-13 MW-19 16-1an-14 MW-19 9-Apr-14 MW-19 29-Oct-14 MW-19 7-May-15 12J MW-19 20-Nov-15 MW-19 26-Apr-16 0.331 MW-19)dup) 26-Apr-16 MW-19 16-Nov-16 0.44J 0.691 MW-19 27-Apr-17 0.54J MW-19 27-Sep-17 MW-19 28-Mar-18 MW-19 27-Nov-18 MW-19 1-May-19 MW-19 25-Sep-19 - MW-19 14-Apr-20 -- MW-19 21-0d-20 - MW-19 13-Apr-21 0.51 -- MW-19 20-0d-21 MW-20 9-No 11 MW-20 5-Apr-12 MW-20 ]-Nov-12 MW-20 14-May-13 MW-20 5-Nov-13 MW-20 9-Apr-14 9.3J 0.531 MW-20 28-0ct-14 MW-20 5-May-15 8.7J 0.101 MW-20 19-Nov-15 0.251 MW-20 27-Apr-16 MW-20 17-Nov-16 MW-20 27-Apr-17 2.41 MW-20 17-5ep-17 MW-20 29-Mar-18 MW-20 28-Nov-18 MW-20 2-May-19 0.45J MW-20 26-5ep-19 - MW-20 15-Apr-20 - 0.46) MW-20 21-0ct-20 - MW-20 14Apr-21 - MW-20)dup) 14-Apr-21 - MW-20 19-Oct-21 7.O1 Smith Page 13 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-21 8-Nov-11 MW-21 4-Apr-12 MW-21 6-Nov-12 MW-21 15-May-13 MW-21 6-Nov-13 MW-21 9-Apr-14 MW-21 28-Oct-14 MW-21 5-May-15 0.641 MW-21 19-Nov-15 MW-21 2&Apr-16 MW-21 16-Nov-16 MW-21 2&Apr-1] MW-21 26-Sep4] MW-21 2&Mar-18 MW-21 21-Nov-18 MW-21 2-May-19 0.43J MW-21 24-Sep-19 -- MW-21 14-Apr-20 - MW-21 21-Oct-20 - MW-21 13-Apr-21 - MW-21 19-Oct-21 MW-22 &Nov-12 MW-22 15-May-13 MW-22 &Nov-13 MW-22 9-Apr-14 MW-22 28-0ct-14 MW-22 5-May-15 0.911 MW-22 19-Nov-15 MW-22 2&Apr-16 MW-22 16-Nov-16 MW-22)dup) 16-Nov-16 MW-22 2&Apr-1] MW-22 26-Sep-17 MW-22 2&Mar-18 MW-22 28-Nov-18 MW-22 2-May-19 0.431 MW-22 24-Sep-19 -- MW-22 14-Apr-20 - MW-22 21-Oct-20 -- MW-22 13-Apr-21 - MW-22 19-Oct-21 41 MW-23 9 Nov-11 MW-23 4-Apr-12 MW-23 5Nov-12 MW-23 15-May-13 MW-23 5Nov-13 NO Sample Collected -Well was Dry MW-23 10-Apr-14 MW-23 2]-Oct-14 MW-23 5-May-15 0.]11 MW-23 19-Nov-15 231 0.831 MW-23 26-Apr-16 6.01 MW-23 I6-Nov-16 351 0.401 MW-23 28-Apr-17 111 MW-23 26-Sep-17 4.31 MW-23 28-Mar-18 3.11 MW-23 28-Nov-18 MW-23 2-May-19 2.41 MW-23 24-Sep-19 8.31 - MW-23 14-Apr-20 -- MW-23 21-0ct-20 - MW-23)dop) 21-Oct-20 - MW-23 13-Apr-21 - MW-23 I 19-Oct-21 MW-24 9-Nov-11 3.3 10 3:1 3.5 9.9 1.31 MW-24 5-Apr-12 3.0 8.5 3.01 3.5 8.6 1.01 0.481 MW-24 ]-Nov-12 3.2 9.5 3.2J 3.2 9.0 MW-24 1&May-13 2.9 ].9 1 3.2 7.8 0.311 1.11 0.62) 0.42) MW-24 6-Nov-13 2.5 6.4 3.2J 2.6 8.8 1.11 MW-24 8-Apr-14 1.4 3.6 2.21 1.] 5.3 0.64J 1.201 MW-24 2]-Oct-14 2.6 6.6 2.91 2.3 1.21 0.431 0.331 MW-24 5-May-15 1.1 2.11 0.4W 1.1 4.61 0.6U 1.W 0.251 MW-24 19-Nov-15 12J 1.4 3.6 1.3 5.0 0.7Ol 0.271 0.231 MW-24 25-Apr-16 7.6J 0.25J 2.01 0.541 MW-24 IS-Nov-16 1.0 2.01 0.86J 0.841 3.01 MW-24 2]-Apr-1] 1.31 MW-24 26-Sep-1] 1.31 2.7 6.3 3.31 2.6 (B 0.941 MW-24 2&Mar-18 1.9 5.2 2.21 1.9 4.11 0.6W MW-24 28-Nov-18 0.94 1.8 2.] 88 MW-24 2-May-19 2.0 3.9 3.2 1.6 5.6 0.91 220 2.6) MW-24 24-Sep-19 1.8 1 2.9 1.67 5.8 0.94 180D 4.0) MW-24 14-Apr-20 1.2 2.1 1.8 0.99 3.5 89 2.11 MW-24 22-00-20 O86 19 MW-24 13-Apr-21 SA MW-24 19-Oct-21 ].1 Smith Page 14 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-25 8-Nov-11 1.41 "1 MW-25 4-APr-12 0.651 2.91 4.41 MW-25 6-Nov-12 0.781 2.31 3.91 MW-25 15-May-13 0.831 2.31 L21 4.01 MW-25 &Nov-13 0.871 3.21 MW-25 9-Apr-14 0.801 2.71 3.11 MW-25 28-Oct-14 0.871 4.31 2.61 MW-25 5-May-15 1.4 2.L 0.77J 3.71 1.0 MW-25 19-Nov-15 17J 1.2 2.71 0.37) MW-25 2&Apr-16 12J 1.2 2.91 MW-25 16-Nov-16 0.801 1.71 0.47J 2.61 MW-25 27-Apr-17 1.41 2.61 MW-25 26-Sep-17 I, 2.01 MW-25 2&Mar-I8 1.5 2.91 2.21 MW-25 28-Nov-18 0.76 1.6 52 MW-25 2-May-19 1.5 3.4 2.0 42 MW-25 24-Sep-19 1.] 3.1 0.481 2.1 45 MW-25 14-Apr-20 1.4 2.8 1.8 47 MW-25 22-Oct-20 0.65 2.4 1.5 40 MW-25 13-Apr-21 1.1 1.3 27 MW-25 19-Oct-21 0.94 1.2 31 MW-26 &Nov-11 1.4 0.911 MW-26 4-Apr-12 1.6 0.661 1.L 1.41 0.491 MW-26 &Nov-12 1.4 0.471 0.831 1.11 0.601 MW-26 1&May-13 0.881 0.141 0.32J 0.57J MW-26 &Nov-13 0.821 MW-26 9-Apr-14 1.5 0.69J 0.33J 1.41 0.6W 0.871 MW-26 28-0ct-14 1.5 0.871 1.91 0.37J 0.97J 0.501 MW-26 5-May-15 161 2.4 0.771 0.841 1.01 0.50J 1.61 0.211 MW-26 19-Nov-15 14J 1.3 IM 0.42J 0.711 0.39J 0.321 MW-26 2&Apr-16 9.6J 2.4 1.51 0.621 0.70J MW-26 16-Nov-16 3.7J 2.4 3.3 2.01 1.9 0.841 0.411 1.31 MW-26 2&Apr-17 2.1 3.3 2.61 1.9 0.95J 0.671 MW-26 26-Sep-17 3.6J 2.3 3.2 2.31 2.3 1.11 0.461 0.SM MW-26 2&Mar-18 1.8 2.41 1.51 1.6 0.801 MW-26 28-Nov-18 2.4J 1.8 1.9 1.4 1.1 MW-26 2-May-19 3.0J 2.4 2.7 2.0 1.9 1.2 0.51 210D 27 0.43) MW-26 24-Sep-19 4.51 1.6 1.6 1.3 1.1 0.84 0.421 IBOD 23 MW-26 14-Apr-20 9.6J 0.90 1.5 1.3 1.1 0.49J 220 17 MW-26 21-0ct-20 8.3J 0.72 1.1 0.91 0.70 7] 13 MW-26 14-Apr-21 5.21 0.78 0.91 0.54 74 18 MW-26 19-0ct-21 20 3.31 MW-27 &Nov-11 1.71 4.41 1.21 0.981 MW-27 4-Apr-12 0.45J 3.01 5.8 1.31 1.3 MW-2] &Nov-12 0.461 1.41 5.4 1.31 1.1 MW-27 1&May-13 0.5J 2.91 5.5 2.51 0.321 1.41 MW-2] &Nov-13 5.01 6.1 MW-27 9-Apr-14 0.42J 2.3J 5.7 0.67J 0.331 MW-2] 28-Oct-14 0.431 2.01 6.1 1.41 0.261 1.21 MW-27 5-May-15 9.31 0.5M 0.501 2.8J 8.6 1.21 0.381 1.61 MW-2] 19-Nov-15 O.SL 3.31 ].8 1.21 0.401 0.271 0.651 0.371 1.0 MW-27 2&Apr-16 0.44J I.6 1.31 0.371 0.671 0.881 MW-27 16-Nov-16 7.8 1.51 OAM 0.66) MW-27 2&Apr-17 2.71 4.2J 9.4 1.81 0.411 0 11 0.601 MW-27 26-Sep-17 2.71 6.6 8.3 1.41 0.551 MW-27 2&Mar-18 7.0 1.01 0.551 0.821 MW-27 28-Nov-18 4.3 7.2 1.3 8.8 0.68 1.1 MW-27 30-Apr-19 4.01 0.79 8.3 1.1 8.3 0.491 3.31 MW-27 24-Sep-19 0.451 4.5 8.6 1.5 0.44J 15 0.62 5.2 0.401 0.99 MW-27 1LApr-20 4.8 8.7 1.5 0.421 11 0.66 3.21 1.1 MW-27 21-0c -20 5.1 9.1 1.4 1.411 11 0.62 3.6) 0.441 0.66 MW-27 SLApr-21 3.9 8.6 1.3 11 0.431 3.41 0.65 MW-27 19-Oct-21 3.1 9.1 1.4 0.40J a0.. 3.81 0.441 MW-28 4Nov-11 MW-28 5-Apr-12 MW-28 &Nov-12 MW-28 15-May-13 MW-28 &Nov-13 MW-28 9-APr-14 4.1J MW-28 28-0ct-14 1.21 MW-28 5-May-15 6.91 8.2 0.44J MW-28 19-Nov-15 1.81 MW-28 2&Apr-16 1.81 0.431 MW-28 16-Nov-16 0.78J MW-28 27-Apr-17 0.531 MW-28 27-5ep-17 MW-28 2&Mar-18 MW-28 28-Nov-18 MW-28 2-May-19 0.411 3.5 MW-28 26-5ep-19 2.1 - MW-28 15-Apr-20 MW-28 21-0ct-20 0.82 - MW-28 14-Apr-21 4.5 - MW-28 21-Oct-21 2.6 Smith Page 15 of 18 January 2022 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 M W-29uP) O1 J M 5 APr-12 1.51 1 12 0.541 1.L 0.801 0.681 0.581 4.61 0.451 01.3 0.491 MW 29 J9Nov-122 1.41 0.681 IB 12 0.451 2.61 0.]61� 0.51 MW-29 1GMay-13 121 0.211 1.4J 0.491 111 0.161 MW-29 31-Jul-13 0.261 B.81 ] 0.]81 2.5J 1.5 MW-29 J-Nov-13 0.2w 3.4J 3.01 0.681 MW-29 164an-14 6.3J 0.211 MW-29 9-Apr-14 5.91 0.891 MW-29 29-0ct-14 7.2 L21 0.361 0.331 MW-29 6-May-15 9AJ 0.54J 1.J1 1.51 MW-29 20-Nov-15 MW-29 27-Apr-16 1.01 MW-29 17-Nov-16 0.781 2.11 MW-29 27-Apr-17 5.51 MW-29 2]-Sep-1] O.94J 5.5 0.621 MW-29 29-Mar-18 MW-29 28-Nov-18 1 I.51 MW-29 1-May-19 4.11 3.JD MW-29 26-Sep-19 1.3 4.1 1.41 MW-29 14-Apr-20 0.99 2.6 1.91 MW-29 22-0ct-20 1.3 0.51 3.0 MW-29 14-Apr-21 0.]2 2.2 2.41 MW-29 20-0ct-21 1.1 3.2 1.9J N.- 1. All units are in micrograms per liter (parts per billion). 2. • - Interim Maximum Allowable Concentration (IMAC) 3. NS - No Standard 4, dup - Duplicate Sample 5. J -Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the laboratory limit of quantitation. 6. B -The amount in the prep blank is greater than the method detection limit. J. D -The an,Iyte was run at dilution. 8. (--) - Not Analyzed. I,MDioxane was removed from the sampling program for all wells on June 26, 2019, with the exreptions of M W-6, -9, -10, -11, -12, -13, -14, -I5, -IJ, -19, -24, -25, -26, -27, and -29, due to two ronsecutive non- defect events. Concentration exceeds the ISA NCAC 02L.0202 (North Carolina 2L) or IMAC. - Indicates the result is below the detection limit -A sodium lactate injection was performed near M W-8, -9, and -10 on June 18-21, 2012. - An em ulsifled vegetable oil injection was performed near M W-8, -9, and -10 on March 25-27, 2013. Smith Page 16 of 18 January 2022 Smith Table 4c Detected Surface Water Constituents - Metals and Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 NC 2B or In -Stream Target Value Consumption SW-1 Standard 8-Nov-11 43.31 0.1111 2.901 5.101 4.981 SW-1 4-Apr-12 57.11 3.18JB 1.841 SW-1 6-Nov-12 39.41 SW-1 14-May-13 60J 0.061 0.41 0.91 11 .7J 0.81 51B SW-1 S-Nov-13 0.91 50J 0.61 0.71 4JB SW-1 9-Apr-14 40J 0.91 0.41 21 .6J 0.81 51 71B 8.11 SW-1 28-Oct-14 40J 0.41E 0.41 0.61 0.61 SW-1 5-May-15 40J 0.41 1J 0.2J 0.71 318 0.73J SW-1 19-Nov-15 21 70J 0.21 31 31 2J 1J 13J 16 SW-1 26-Apr-16 0.71 40J 0.31 1J 0.31 0.61 31 SW-1 16-Nov-16 0.241 0.731 56J 0.281 1.21 1.11 1.91 SW-1 28-Apr-17 40J 1.61 0.451 3.31 3.31 SW-1 26-Sep-17 DRY SW-1 29-Mar-18 451 1.31 3.9.1 0.311 4.11 SW-1 28-Nov-18 48J 1.3J 0.25J 3.4.1 SW-1 30-Apr-19 421 1.61 0.40J SW-1 24-Sep-19 DRY SW-1 13-Apr-20 51 2.01 2.11 0.451 3.31 SW-1 22-Oct-20 46 SW-1 14-Apr-21 43 6.21 SW-1 21-Oct-21 38 0.141 SW-2 8-Nov-11 3.631 55.81 0.1651 3.421 6.801 12.3 SW-2 4-Apr-12 69.4J 2.66113 2.04J S.7SJ SW-2 6-Nov-12 3.371 76.91 2.301 9.181 SW-2 14-May-13 11 801 0.1J 1.1 21 21 2.1 2J 3J 106 0.211 SW-2 5-Nov-13 60J 0.11 11 0.61 3.113 0.81 11 71 11B SW-2 8-Apr-14 0.61 50J 11 0.6J 21 11 0.81 61 11B SW-2 27-Oct-14 30J 0.3113 0.21 11 0.31 51 SW-2 5-May-15 60J 0.21 11 0.81 0.31 0.71 25 0.61 SW-2 18-Nov-15 0.21 701 I 0.04J 0.81 0.51 1 11 0.31 0.71 11 13 SW-2 25-Apr-16 DRY SW-2 17-Nov-16 0.341 1.51 1 130 0.201 0.0521 3.51 1.81 5.41B 4.21 2.81 8.91 23 2.81 SW-2 28-Apr-17 66J 1 1 I 1.5J 1.0J 1.5J 4.01 6.81 SW-2 26-Sep-17 DRY SW-2 29-Mar-18 DRY SW-2 28-Nov-18 50J 0.37J 6.21 SW-2 30-Apr-19 DRY SW-2 24-Sep-19 DRY SW-2 13-Apr-20 56 1.91 4.11 1.5 1.31 4.71 13 SW-2 21-Oct-20 64 1.5J 3.31 SW-2 14-Apr-21 110 2.61 1.7J 0.611 1.41 1.3J 21 SW-2 21-Oct-21 DRY Page 17 of 18 January 2022 Table 4c Detected Surface Water Constituents - Metals and Volatile Organic Compounds October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 NC 2B or In -Stream Target Value Consumption SW-3 Standard 8-Nov-11 3.991 52.21 0.141J 2.361 8.011 7.551 SW-3 4-Apr-12 46.71 SW-3 6-Nov-12 41.51 1.621 SW-3 15-May-13 0.61 40J 0.31 0.81 0.2J 0.51 218 SW-3 5-Nov-13 0.61 40J 0.61 0.41 2113 0.4J 1J 31 616 SW-3 8-Apr-14 50J 0.051 11 0.71 21 11 11 61 10B SW-3 27-Oct-14 40J 0.41E 0.51 0.71 0.2J 0.71 216 SW-3 5-May-15 0.81 40J 0.31 0.51 11 0.31 0.71 418 0.94J SW-3 18-Nov-15 50J 0.41 0.61 11 0.21 0.81 1 SW-3 26-Apr-16 40J 0.31 0.41 11 0.41 0.71 41B SW-3 16-Nov-16 0.451 38J 0.93.1 0.191 0.77J 2.01 SW-3 28-Apr-17 41J 0.161 1.61 3.61 4.6J 2.41 SW-3 26-Sep-17 DRY SW-3 28-Mar-18 47J 1.31 1.91 0.44J 5.21 SW-3 28-Nov-18 511 1.3J 0.25J 3.21 SW-3 30-Apr-19 1.51 6.11 170 0.171 7.51 6.41 6.81 6.5J 6.91 1, 38 8.11 0.46J SW-3 24-Sep-19 DRY SW-3 13-Apr-20 2.2 87 1.5J 2.9J 2.0J 1.4 2.3J 4.0.1 12 SW-3 21-Oct-20 1.71 5.1 270D 0.98 19 7.6 17 19 9.7 1.91 0.161 43 SW-3 14-Apr-21 4.6 190 0.55 13 10 1s 12 12 3.5J 31 SW-3 21-Oct-21 37 0.121 Notes: 1. All units are in micrograms per liter (parts per billion). 2. (2) - A Standard for total chromium has not been established. The value provided is for chromium (111). 3. NS - No Standard 4. (4) - North Carolina 15A NCAC 02B (NC 28) Fish Consumption Standard 5. I51- North Carolina In -Stream Target Value Freshwater Aquatic Life Standard 6. (6) - NC 2B Freshwater Aquatic Life Standard 7. Ill - North Carolina In -Stream Target Value Fish Consumption Standard 8.1- Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the laboratory limit of quantitation. 9. B - The amount in the prep blank is greater than the method detection limit. Concentration exceeds the NC 2B or In -Stream Target Value Freshwater Aquatic Life or Fish Consumption Standard for Class C Waters -July 2021 Indicates the result is below the detection limit Smith Page 18 of 18 January 2022 Table 5 Constituents Detected Above Standards October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 Facility Permit Number 9203-MSWLF-1980 Monitoring Well Code MW-2 October Interim Maximum Allowable Concentration Vanadium* 9203-MSWLF-1980 MW-4 Vanadium*, 1,1-Dichloroethane 9203-MSWLF-1980 MW-6 Barium, Cobalt*, 1-4-Dioxane, Vinyl Chloride 9203-MSWLF-1980 MW-8 Vanadium* 9203-MSWLF-1980 MW-9 Barium, Cobalt*, Sodium, Vanadium*, 1,4-Dioxane 9203-MSWLF-1980 MW-10 Arsenic, Barium, Cobalt, Sodium, Total Dissolved Solids, Benzene, 1,1-Dichloroethane, 1,4-Dioxane, Vinyl Chloride 9203-MSWLF-1980 MW-11 Cobalt* 9203-MSWLF-1980 MW-12 1,4-Dioxane 9203-MSWLF-1980 MW-13 Cobalt*, 1,4-Dioxane 9203-MSWLF-1980 MW-14 Cobalt*, 1,4-Dioxane 9203-MSWLF-1980 MW-15 Cobalt*, 1,4-Dioxane 9203-MSWLF-1980 MW-16 Arsenic, Cobalt*, Tetra chloroethene 9203-MSWLF-1980 MW-17 Arsenic, Cobalt*, 1,4-Dioxane 9203-MSWLF-1980 MW-18 Cobalt*, Vanadium*, 1,4-Dioxane 9203-MSWLF-1980 MW-19 Sodium, Vanadium* 9203-MSWLF-1980 MW-20 Vanadium* 9203-MSWLF-1980 MW-21 None Detected 9203-MSWLF-1980 MW-22 Arsenic, Cobalt* 9203-MSWLF-1980 MW-23 Cobalt* 9203-MSWLF-1980 MW-24 Cobalt*, Vanadium*, 1,4-Dioxane 9203-MSWLF-1980 MW-25 Barium, Cobalt*, 1,4-Dioxane 9203-MSWLF-1980 MW-26 Cobalt*, Vanadium*, 1,4-Dioxane 9203-MSWLF-1980 MW-27 Cobalt*, 1,1-Dichloroethane, 1,4-Dioxane 9203-MSWLF-1980 MW-28 None Detected 9203-MSWLF-1980 MW-29 Cobalt*, Vanadium* Notes: 1. Bold - "J" flag 2. (*) - Interim Maximum Allowable Concentration 3. TDS - Total Dissolved Solids smith Page 1 of 1 January 2022 Table 6 Geochemical Data October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-2 8-Nov-11 298.0 9.11 6.63 <2 100 0.969 <1 <2.3 1,200BD O.87J 19J <0.01 7.4 260D 27.3 0.040 0.98 <0.024 <0.062 <0.057 <0.061 -- MW-2 4-Apr-12 211.8 6.73 8.20 <2 67 <0.72 <1 <2.3 450BD 0.471 33JB <0.01 2.1 150D 8.7 0.052 <0.04 <0.024 <0.062 <0.057 <0.061 -- MW-2 6-Nov-12 41.4 6.85 6.12 <2 180 <0.43 <0.2 <0.54 1,200BD O.SSJ 23J <0.01 6.4 230D 29.3 <0.046 <0.031 <0.031 <0.095 <0.063 <0.010 -- MW-2 15-May-13 109.7 7.02 6.94 <4 22 <0.3 <0.061 <0.069 462 0.14J 35.2J <0.4 2.6 152 5.2 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 6-Nov-13 21.2 7.46 8.19 <4 46 0.34 <0.061 <0.069 834 0.54J 32.5J <0.4 2.7 215 12 1.1* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 9-Apr-14 124.1 6.76 7.71 <2 52 <0.3 <0.061 <0.069 589 0.221 32.5J <0.4 5.1 162 8 0.0* 1.40 <1.0 <0.50 <0.50 <0.25 -- MW-2 28-Oct-14 59.3 6.63 6.08 <4 430 <0.3 <0.061 <0.069 1,040 0.47J 26.4J <0.4 5.7 232 13.0 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 5-May-15 69.1 6.75 6.01 <2 25 <0.3 <0.061 <0.069 785 0.91 30.9J <0.4 4.3 175 6.0 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 19-Nov-15 130.2 6.89 6.60 <2.0 169 <0.30 <0.061 <0.069 1,480 O.SI 17.7J <0.4 12.5 274 19 0.0* <0.50 <1.0 <0.50 <0.50 <0.020 -- MW-2 26-Apr-16 93.0 7.31 7.50 <2.0 42 <0.30 <0.061 <0.069 756 0.241 26.1J <0.4 7.1 180 8.3 0.0* <0.50 <1.0 <0.50 <0.50 <0.020 -- MW-2 17-Nov-16 82.6 7.32 7.65 <12 29 <10 <10 <10 1,100D 0.45J 24J -- 6.4 200 190 0.0* <1.0 <1.0 <2.0 <1.0 <1.0 -- MW-2 27-Apr-17 154.9 6.91 6.72 <2.0 20 2.8B <10 <10 730D 0.201D 14JD <1.0 4.7 170 160 0.0* <1.0 <1.0 <2.0 <1.0 <1.0 -- MW-2 26-Sep-17 162.0 7.65 4.30 <2.0 16 3.0 <10 <10 640D 0.26J 281 <1.0 4.1 190 170 0.0* <1.0 <1.0 <2.0 <1.0 <3.0 -- MW-2 28-Mar-18 193.6 7.08 5.84 <2.0 8.5 <10 <10 <10 570D <0.020 34 <1.0 3.4 160 150 0.0* <1.0 <1.0 <2.0 <1.0 <1.0 -- MW-2 28-Nov-18 69.3 7.06 10.18 2.011) 68 <10 <10 <10 730 0.26 31 <1.0 4.6 190 170 0.0* 1.7 <1.0 <2.0 <1.0 <1.0 -- MW-2 2-May-19 95.7 6.99 8.83 2.9 23 <10 <10 <10 540D 0.081 33 <1.0 2.4 170 180 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 -- MW-2 26-Sep-19 49.5 7.08 7.52 <2.0 <20 -- -- -- 690D 0.16HJD 30D <1.0 4.4 180 180 0.0* 2.1 <1.0 <2.0 1.2 <1.0 -- MW-2 15-Apr-20 130.0 7.50 10.87 <2.0 <20 2.5J <10 <10 580D 0.03 33 <1.0 2.7 160 150 0.0* <1.0 <1.0 <2.0 <1.0 <1.0 -- MW-2 22-Oct-20 53.8 7.16 6.85 2.5(13,14) 25 2.5J <10 <10 820D 0.54D 20JD <0.10 5.1 210 200 0.0* 7.9J <1.0 <2.0 <1.0 <1.0 -- MW-2 14-Apr-21 97.2 7.08 7.24 <2.0 235 5.01 <10 <10 660D 0.039 32 <1.0 3.5 180 -- 0.0* 2.81 <0.58 <0.53 <0.53 <0.60 -- MW-2 21-Oct-21 75.4 7.31 7.23 1 <2.0 29 1 2.6J <10 <10 130D 0,39 29 1.6 5.2 210 200 0.0* 21 <0.O18 17 1.4 0.55 -- MW-8 7-Nov-11 161.7 6.08 2.09 <2 <10 4.5 <1 <2.3 4.1B 0.33J 2.4J <0.01 <0.28 120 62.2 0.033 1.1 <0.024 0.19 0.28 <0.061 1.0 MW-8 4-Apr-12 167.8 6.59 1.65 <2 <10 1,4300, <1 <2.3 4.7B 0.27J 2.2JB <0.01 0.54 120 90.5 0.056 <0.04 <0.024 0.082 <0.057 <0.061 7.5 <-- Mw_■ <0-31 0.-- 2-- MW S 16-Aug 12 -56.1 5.85 0.59 <2 17 26.7 <0.2 <0.54 4.1 0.3* 1* - 190* 186* 1 6* -- =_ MW-8 6-Nov-12 -63.4 6.31 0.93 <2 17 96.5D <0.2 <0.54 5.3B 0.7* 2.40J <0.01 1.6 150 40.6 1.0* 0.56 <0.031 <0.095 0.37 <0.010 4.5 MW-8 15-May-13 -59.4 5.12 1.43 34.7 20 110.0 0.17 0.35 5.55 <0.03 0.63 <0.4 3.8 155 22 3.5* 3.0 <1.0 <0.50 0.961 <0.25 64 MW-8 31-4-13 -33.8 7.12 0.96 -- 30 3,000 1.6 1.4 4.85 <0.03 0.52 -- -- 191 15 2.8* 23.0 <1.0 <0.50 <0.50 <0.25 -- MW-S 6-Nov-13 -81.4 7.27 0.81 <2 <16 600 <0.061 0.17 4.15 <0.03 0.51 <0.4 0.5 152 17 1.2* <0.50 <1.0 <0.50 <0.50 <0.25 1.6 MW-8 16-Jan-14 -94.8 7.09 0.49 -- <16 1,400 0.14 0.10 4.37 <0.03 0.48J -- -- 168 18 0.8* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-S 10-Apr-14 -77.7 7.08 1.53 47.2 <16 200 <0.061 <0.069 4.9 0.15J 0.7J <0.4 1.9 154 12 0.0* 1.9 <1.0 <0.50 <0.50 <0.25 1.6 MW-8 29-Oct-14 -76.4 5.90 0.78 <4 <5 110 <0.061 0.10 5.10 <0.03 1.1 <0.4 0.4 138 23 0.5* <0.50 <1.0 <0.50 <0.50 <0.25 1.6 MW-8 7-May-15 -78.3 6.57 0.89 16.5 <16 210 <0.061 <0.069 5.70 <0.03 4.2B <0.4 1.0 165 9.6 3.0* <0.50 <1.0 <0.50 <0.50 <0.25 18.0 MW-8 19-Nov-15 -7.9 6.18 2.79 3.1 <16 32 0.23 <0.069 5.3 0.091 1.4 <0.4 0.5 120 19 0.5* <0.50 <1.0 <0.50 <0.50 <0.020 12 MW-S 26-Apr-16 -40.8 7.13 1.45 <2.0 14J 890 0.31 <0.069 5.2 0.06J 1.3 <0.4 0.6 141 12 3.0* <0.50 <1.0 <0.50 <0.50 <0.020 2.8 MW-8 16-Nov-16 -1.7 7.18 1.69 <2.0 <10 270B <10 <10 9.0 0.0072J 0.23J 1.6 0.71 130 150 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 7.3 MW-S 28-Apr-17 -6.7 6.42 1.38 <2.0 <10 64B <10 <10 7.3 0.042J <1.0 <1.0 120 0.741 110 1.5* <0.10 <0.10 <0.20 <0.10 <0.10 13 MW-8 27-Sep-17 71.0 7.27 1.34 <2.0 <10 21 <10 <10 5.8 0.15J 1.2J <1.0 <1.0 120 110 2.5* <0.10 <0.10 <0.20 <0.10 <0.10 4.4 MW-S 28-Mar-18 6.1 6.91 0.05 <2.0 <10 69 <10 <10 5.4 0.16E 1.0 <1.0 <3.0 110 100 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 2.5 MW-8 27-Nov-18 19.9 7.32 0.27 2.9 <20 2,300 <40 79 7.1 <0.020 0.64J <1.0 <1.0 160 160 1.0* 0.15 <0.10 <0.20 <0.10 <0.10 7.8 MW-8 1-May-19 18.6 5.90 0.26 <2.0 <20 5,600D <10 <10 7.2 0.066 0.69J <1.0 <1.0 260 140 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 2.2 MW-8 25-Sep-19 7.3 6.73 1.92 <2.0 <20 49BJD <100 <100 5.7 0.16H 0.67J <1.0 <1.0 120 220 0.0* 0.16 <0.10 <0.20 0.11 <0.10 1.4 MW-S 14-Apr-20 41.3 7.11 0.62 <2.0 <20 110 3.2J <10 6.2 0.180 <1.0 <1.0 <1.0 120 110 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 1.8 MW-8 21-Oct-20 94.8 6.24 0.45 <2.0 <20 33B <10 <10 7.9 0.12 0.63J <0.10 <1.0 120 130 0.0* 0.46J <0.10 <0.20 <0.10 <0.10 0.88J MW-8 13-Apr-21 -35.3 6.75 0.19 <2.0 <20 1,300B <10 <10 8.6 0.046JD 0.40J <1.0 1.3 230 270 0.5* 0.29J <0.055 <0.053 <0.053 <0.060 0.731 MW-8 20-Oct-21 56.6 6.95 0.22 <2.0 <20 46 <10 <10 6.0 0.14 0.49J <1.0 <1.0 120 140 0.5* 0.29J <0.058 0.098J <0.053 <0.060 5.0 Smith Page 1 of 5 January 2022 Table 6 Geochemical Data October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-9 7-Nov-11 1.1 6.11 1.21 <2 <10 174D <1 <2.3 9.9B 0.12J 2.9J <0.01 0.43 200D 315D 0.10 1.4 <0.024 0.34 0.27 <0.061 1.6 MW-9 4-Apr-12 148.8 6.41 2.71 <2 29 310D <1 <2.3 12B 0.0611 2.81B <0.01 0.80 210D 342D 0.21 <0.04 <0.024 <0.062 0.12 <0.061 8.2 19-Jul-12 9.8* 76 MW-9 -99.8 6.40 0.18 <2 690 602D <0.2 <0.54 17 0* 6* -- -- 506* 440* 230 110 22 <0.01 -- MW-9 16-Aug-12 -112.9 6.31 0.58 <2 440 5,330D 1.24 2.34 15 1.51* 9* -- -- 408* 368* 10.0* -- -- -- -- -- -- MW-9 6-Nov-12 -109.6 6.36 1.06 >73 930 6,190D 1.04 2.26 23B 2.1J* 2.30J <0.01 310D 650D 88.1 3.8* 230 180 <0.095 120 <0.01 39 MW-9 15-May-13 -71.4 5.72 1.27 198 961 4,400 2.2 1.7 36.8 <0.03 0.58J <1.6 163 312 71 7.8* 71 8 <0.50 17 <0.25 11 MW-9 31-Jul-13 -55.2 6.49 1.21 -- 156 6,200 0.58 0.16 32.1 <0.03 0.57J -- -- 367 220 11.3* 30 2.9 <0.50 9.3 <0.25 -- MW-9 6-Nov-13 -52.2 6.49 0.89 58.7 125 8,600 0.96 0.40 27.7 <0.03 0.53J <0.4 32.3 348 120 9.5* 54 <1.0 <0.50 3.6 <0.25 9.8 MW-9 16-Jan-14 -128.5 6.40 0.28 -- 63 5,100 0.27 <0.069 24.2 <0.03 0.53J -- -- 388 210 3.0* 6.8 <1.0 <0.50 <0.50 <0.25 -- MW-9 10-Apr-14 -29.1 6.63 0.93 51.7 88 12,000 1.10 0.31 25.4 <0.03 0.5J <0.4 16.8 325 110 3.5* 32.0 <1.0 <0.50 <0.50 <0.25 4.0 MW-9 29-Oct-14 -90.3 5.40 1.39 25.3 72 9,700 1.1 0.21 25.9 0.091 0.8J <0.4 15.1 308 79 2.0* 21 <1.0 <0.50 <0.50 <0.25 -- MW-9 7-May-15 -81.7 6.34 1.13 18.1 29 11,000 2.2 0.60 28.9 <0.03 0.8B1 <0.4 8.7 374 62 1.0* 10 <1.0 <0.50 <0.50 <0.25 7.8 MW-9 20-Nov-15 -51.4 6.18 1.97 9.5 24 6,400 0.93 <0.069 27.9 <0.03 0.6J <1.6 7.2 349 62 4.0* 7.0 <1.0 <0.50 <0.50 <0.020 16 MW-9 27-Apr-16 -47.4 6.86 0.96 14.0 32 6,000 1.1 0.2 31.1 <0.04 0.5J <0.8 7.1 325 72 3.0* 8.4 <1.0 <0.50 <0.50 <0.020 5.1 MW-9 16-Nov-16 -48.3 7.08 1.91 23 33 11,000BD <10 <10 36 0.0064J <1.0 1.0J 7.4 310 400 3.0* 7.1DB <0.10 <0.20 0.14 <0.10 9.7 MW-9 27-Apr-17 -17.9 6.62 1.38 17 21 11,000BD <100 <100 42D 0.0251 <1.0 <1.0 6.1 320 360 2.0* 2.7 <0.10 <0.20 <0.10 <0.10 2.6 MW-9 27-Sep-17 -42.0 7.35 1.56 25 20 8,000D 11 <10 42 0.54J <1.0 <1.0 6.8 350 310 4.0* 5.9 <0.10 <0.20 <0.10 <0.10 4.4 MW-9 29-Mar-18 -74.8 6.70 0.43 21 17 9,500D 13 <10 52 <0.020 3.1 <1.0 6.7 340 330 1.5* 2.4 <0.10 <0.20 0.13 <0.10 2.0 MW-9 28-Nov-18 -61.5 6.91 0.27 22"" 57 22,000 5.1 <10 64 <0.020 <1.0 <1.0 7.3 400 410 1.5* 1.4 <0.10 <0.20 <0.10 <0.10 5.3 MW-9 1-May-19 1.8 5.84 0.07 19 30 13,000D 9.3J <10 75 <0.020 0.46J <1.0 10 470 1,300 3.0* 1.9 <0.10 <0.20 <0.10 <0.10 1.3 MW-9 26-Sep-19 -69.5 6.68 0.94 16 21 16,000BD <100 <100 70 <0.020 <1.0 <1.0 6.9 400 550 2.5* 0.8 <0.10 <0.20 0.14 <0.10 1.2 MW-9 14-Apr-20 -55.6 7.49 1.42 12 33 11,000D 11 <10 81 <0.020 0.34J <1.0 7.6 410 490 2.5* 0.2 <0.10 <0.20 <0.10 <0.10 1.4 MW-9 22-Oct-20 59.9 6.38 0.55 14"'""' 24 13,000D 8.8J <10 76 <0.020 <1.0 <0.10 7.8 390 450 2.5* 0.54 <0.10 <0.20 <0.10 <0.10 0.551 MW-9 14-Apr-21 -61.5 6.39 0.12 5.0 31 5,800D <10 <10 84 <0.10 0.52J <1.0 9.2 430 610 2.0* 1.9J <0.29 <0.26 <0.26 <0.30 1.01 MW-9 20-Oct-21 1 -24.7 16.37, 0.37 17.5(14,15) <20 1 7,000D 3.8J I <10 1 53 1 <0.020 1 <1.0 I <1.0 1 4.6 1 330 1 340 1 1.5* 1 0.27J 1 <0.058 0.41J <0.053 <0.060 7.0 MW-10 7-Nov-11 -76.5 5.82 1.29 <2 38 2,540D <1 <2.3 77B 0.052J 5.9J <0.01 8.9 250D 509D 1.1 <0.40 <0.024 <0.062 5.3 <0.061 0.92 MW-10 4-Apr-12 84.8 6.05 1.18 4.5 80 6,540D <1 <2.3 1 130BD 0.069J 11JB 0.17J 13 1 270D I 653D 1 5.3 <0.04 <0.024 <0.062 8.8 <0.061 3.5 1800 10 19-Ju1-12 -96.7 5.93 0.63 <2 13,000 1,590D <0.2 4.89 150 51* 901* -- -- 1,650* 2,080* 30* 1500 2000 220 4.2 -- 10 LMw_ 16-Aug-12 -54.6 5.85 0.36 <2 13,000 1,470D <0.2 1.76 140 4J* 301* -- -- 1,860* 2,140* 36* -- -- -- -- -- SO 6-Nov-12 -48.6 5.74 1.15 >220 2,100 16,200D <0.2 <0.54 67B 4.61* 61J* <0.01 660D 1,800 442 12* 210 45 <0.095 630D 0.43 4.2 MW-10 15-May-13 -54.9 5.65 1.28 195 1,250 4,200 0.22 0.13 63.1 0.03J 0.56J 1.0J 597 729 340 17.2* 120 33 1.1 86 <0.25 11 MW-10 31-Jul-13 -94.7 6.39 2.08 -- 265 5,300 0.098 0.11 108 <0.03 0.77J -- -- 487 350 48.2* 3.4 4.0 <0.50 <0.50 0.26 -- MW-10 6-Nov-13 -59.4 6.69 1.94 19.1 118 6,500 0.25 <0.069 77.6 0.15J 0.54J <0.4 30.6 662 300 8.2* 4.4 <1.0 <0.50 <0.50 <0.25 3.4 MW-10 16-Jan-14 -114.4 6.16 0.31 -- 116 6,800 <0.061 0.08 81.4 <0.03 1.95J -- -- 308 400 1.75* <0.50 <1.0 <0.50 <0.50 0.41 -- MW-10 10-Apr-14 -38.5 6.15 2.19 12.7 59 7,600 0.13 0.260 78.9 <0.03 3.6J 0.4J 14.7 226 400 2.5* <0.50 <1.0 <0.50 <0.50 <0.25 1.0 MW-10 29-Oct-14 -90.0 5.35 0.92 12.8 104 5,400 0.43 <0.069 93.7 0.08J 1.6J <0.4 16.8 505 240 2.5* 1.0 <1.0 1.0 <0.50 0.29 1.40 MW-30 7-May-15 -67.7 5.79 1.19 5.9 78 2,300 0.27 0.32 180.0 <0.03 7.3JB <0.4 22.6 421 290 3.0* <0.50 <1.0 <0.50 <0.50 0.61 1.90 MW-10 20-Nov-15 -29.5 6.01 3.61 4.4 105 840 <0.061 <0.069 144 <0.3 91 <0.4 24.2 457 210 3.0* 1.1 <1.0 <0.50 <0.50 <0.020 13 MW-10 27-Apr-16 -36.5 6.20 2.07 6.8 97 710 <0.061 <0.069 207 <0.04 13.21 <0.4 23.5 444 240 5.5* 0.5 <1.0 <0.50 <0.50 1.0 2.8 MW-10 16-Nov-16 -30.6 6.54 1.16 12 93 4,000BD <10 <10 190D <0.10 3.6JD 0.72J 21 390 1,000 6.5* <1.0 <1.0 <2.0 <1.0 <1.0 5.8 MW-10 27-Apr-17 -14.5 5.73 1.73 4.3 39 2,900B <10 <10 64D 0.0071J 5.01 <1.0 30 200 440 4.5* <0.10 <0.10 <0.20 <0.10 <0.10 3.5 MW-10 27-Sep-17 -18.0 7.13 1.96 6.2 17 3,200 <10 <10 60 0.54J 0.30J <1.0 4.9 310 270 2.5* <0.10 <0.10 <0.20 <0.10 <0.10 3.7 MW-10 29-Mar-18 27.0 5.89 1.78 4.2 42 2,200 <10 <10 85 <0.020 53 <1.0 14 210 320 5.0* <0.10 <0.10 <0.20 <0.20 <0.10 1.4 MW-10 28-Nov-18 -11.1 6.18 0.38 12(") 130 5,600 <10 <10 140 0.021 10 <1.0 24 370 560 4.5* 0.32 <0.10 <0.20 0.12 <0.10 5.8 MW-10 1-May-19 27.7 5.56 0.23 9.4 79 5,400D <10 <10 160 <0.020 11 <1.0 23 440 1,500 4.5* 0.12 0.31 <0.20 <0.10 <0.10 <1.0 MW-10 26-Sep-19 -19.2 6.45 0.78 6.3 45 5,900BD <100 <100 83 8.7E 2.5 <1.0 8.0 400 690 3.5* 0.31 <0.10 <0.20 0.14 <0.10 1.0 MW-10 14-Apr-20 -54.3 6.94 0.43 7.2 83 3,600D <10 <10 230D <0.020 19 <1.0 26.0 410 860 4.0* <0.10 0.42 <0.20 <0.10 <0.10 1.4 MW-10 22-Oct-20 62.6 5.95 0.81 9,3"3j4) 89 4,400D <10 <10 220D <0.020 13 <0.10 30 550 840 6.5* 4.3J <0.10 3.1J <0.10 <0.10 <1.0 MW-10 14-Apr-21 -31.7 5.87 0.14 11 330 2,800 <10 <10 190 <0.10 12 1.0 29 430 870 4.0* 2.81 0.601 <0.53 <0.53 <0.60 1.5J MW-10 20-Oct-21 -26.1 6.56 0.71 2.5(",") 74 1,800 <10 <10 120 <0.020 10 <1.0 15 420 510 3.5* 3.3J <0.58 <0.53 <0.53 <0.60 1.3J Smith Page 2 of 5 January 2022 Table 6 Geochemical Data October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-12 31-Mar-11 130.6 6.62 ox 1.49 <2 28 14.4 <1.5 12 <1.6 290 <0.025 14J <0.01 7.1 700 196 <0.037 11.0 1.10 <0.44 <0.18 <0.14 2.3 MW-12 8-Nov-11 -42.9 6.98 1.94 <2 23 45.1 <1 <2.3 160BD <0.025 12J <0.01 2.4 280D 69.9 <0.030 0.67 <0.024 <0.062 0.56 <0.061 0.88 MW-12 3-Apr-12 148.5 6.86 2.23 <2 34 20.2 <1 <2.3 240BD 0.045J 12JB <0.01 3.4 540D 177D 0.049 <0.04 <0.024 <0.062 0.87 <0.061 6.9 MW-12 5-Nov-12 -65.4 7.09 1.14 <2 17 26.7 <0.2 <0.54 150BD <0.025 111 <0.01 2.2 240D 66.7 <0.031 <0.031 <0.031 <0.095 0.24 <0.010 5.1 MW-12 15-May-13 1.7 6.25 1.75 <4 <16 6.9 <0.061 <0.069 223 0.18J 10.71 <0.4 4.6 523 110 0.0* <0.50 1.51 <0.50 <0.50 <0.25 0.74 MW-12 6-Nov-13 -19.7 7.09 1.25 <2 <16 13 <0.061 <0.069 179 <0.03 11.4J <0.4 2.8 351 60 1.0* <0.50 <1.0 <0.50 <0.50 <0.25 0.99 MW-12 10-Apr-14 14.9 6.99 3.33 <2 19 3.8 <0.061 <0.069 258 0.17J AM <0.4 5 651 140 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 0.89 MW-12 28-Oct-14 -42.4 5.81 0.91 <4 21 10.0 <0.061 <0.069 184 <0.03 13.3J <0.4 2.0 401 42 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 0.74 MW-12 6-May-15 4.1 6.73 1.18 <2 19 22.0 <0.061 <0.069 245 <0.03 18.6J <0.4 5.5 736 120 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 2.60 MW-12 20-Nov-15 -23.2 6.68 6.11 <2.0 <16 3.6 <0.061 <0.069 169 <0.2 7.6J <1.6 3.3 288 24 0.5* 2.4 <1.0 <0.50 <0.50 <0.020 29 MW-12 27-Apr-16 -44.0 7.02 6.36 <2.0 32 7.3 <0.061 <0.069 238 <0.08 21.0J 0.8J 6.4 699 96 1.0* <0.50 <1.0 0.56J <0.50 <0.020 2.5 MW-12 17-Nov-16 -39.5 7.29 1.36 <12 9.6 17B <10 <10 180D <0.10 13JD -- 2.5 330 340 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 4.7 MW-12 27-Apr-17 1.2 6.45 1.43 <2.0 15 21B <10 <10 220D <0.040 16JD <1.0 5.2 610 600 0.5* <1.0 <1.0 <2.0 <1.0 <1.0 3.3 MW-12 28-Sep-17 2.0 7.70 1.83 <2.0 9.0 21 <10 <10 170 <0.020 12J <1.0 2.3 310 270 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 3.3 MW-12 29-Mar-18 -58.1 7.16 1.75 <2.0 <10 <10 <10 <10 170 <0.020 9.7 <1.0 2.0 280 260 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 1.5 MW-12 27-Nov-18 -87.1 7.41 1.16 <2.0 <20 99 <10 <10 190 <0.020 4.6 1.1 2.7 390 360 0.5* 0.26 <0.10 <0.20 <0.10 <0.10 7.2 MW-12 1-May-19 27.6 6.29 0.18 <2.0 21 22 <10 <10 270D <0.020 34 <1.0 6.4 740 940 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 1.1 MW-12 26-Sep-19 -30.5 6.93 0.94 <2.0 <20 24B <10 <10 210D <0.020 12 <1.0 3.9 470 500 0.5* 0.45 <0.10 <0.20 0.17 <0.10 1.5 MW-12 15-Apr-20 -12.1 6.58 0.37 <2.0 <20 18 <10 <10 220D 9.0E 14 <1.0 5.0 600 560 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 1.8 MW-12 22-Oct-20 58.0 6.94 0.68 <2.0 <20 26B <10 <10 190 <0.020 9.6 <0.10 3.7 450 450 0.0* 4.01 <0.10 <0.20 <0.10 <0.10 <1.0 MW-12 14-Apr-21 -28.3 6.65 0.24 <2.0 <20 21 <10 <10 240D 0.045JD 24 <1.0 6.3 710 730 0.5* 2.51 <0.58 <0.53 <0.53 <0.60 1.7J MW-12 20-Oct-21 2.3 7.31 0.13 <2.0 <20 19 <10 <10 160 <0.020 12 1.1 1.8 300 290 0.5* 3.7J <0.58 6.2 <0.53 <0.60 1.6J MW-13 20-May-10 74.4 6.14 1.69 <2 5 597 <0.4 <0.4 58 <0.025 41 <0.031 3.8 200 348 0.509 <0.083 <0.16 2.4 0.56 <0.14 1.2 MW-13 2-Nov-10 89.8 6.02 0.98 <2 20 418 <1.5 <1.6 63 <0.025 4.9J <0.01 4.8 220 365 0.13 <0.083 <0.16 <0.44 <0.18 <0.14 5.6 MW-13 31-Mar-11 99.9 5.70 1.58 <2 19 1,300 <1.5 <1.6 61 <0.025 5.5J <0.01 5.9 210 498 0.44 <0.083 <0.16 <0.44 <0.18 <0.14 2.2 MW-13 8-Nov-11 -20.4 5.76 3.81 <2 38 3,150D <1 <2.3 49B 0.170J 7.2J <0.01 8.6 250D 737D 0.16 0.72 <0.024 <0.062 <0.057 <0.061 0.96 MW-13 3-Apr-12 200.9 5.93 1.28 <2 48 2,260D <1 <2.3 45B 0.050.1 8.7JB <0.01 6.0 250D 559D 0.47 <0.04 <0.024 <0.062 <0.057 <0.061 7.0 MW-13 5-Nov-12 50.7 5.84 1.07 <2 28 1,050D <0.2 <0.54 61B <0.025 6.80J <0.01 4.9 230D 993D <0.046 <0.031 <0.031 2.70 0.23 <0.010 5.7 MW-13 16-May-13 48.3 5.73 1.41 <4 27 410 <0.061 <0.069 48.4 0.14J 7.25J <0.4 5.8 237 450 0.7* <0.5 <1.0 <0.50 <0.50 <0.25 0.61 MW-13 7-Nov-13 35.2 5.92 1.24 <2 <16 190 <0.061 <0.069 66.0 0.18.1 5.12J <0.4 3.3 253 550 0.2* <0.5 <1.0 <0.50 <0.50 <0.25 1.0 MW-13 10-Apr-14 90.4 5.94 2.64 <2 30 430 <0.061 <0.069 35.6 0.29J 71 <0.4 7.1 178 -- 0.5* <0.5 <1.0 <0.50 <0.50 <0.25 2.0 MW-13 28-Oct-14 70.5 5.17 0.74 <4 33 150 <0.061 <0.069 47.9 0.14.1 8.51 <0.4 5.3 263 350 0.0* <0.5 <1.0 <0.50 <0.50 <0.25 1 MW-13 6-May-15 42.5 5.10 1.09 <2 <16 270 <0.061 <0.069 39.3 0.12J 9.2JB <0.4 6.7 197 300 0.0* <0.5 <1.0 <0.50 <0.50 <0.25 6 MW-13 20-Nov-15 119.4 5.49 6.40 <2.0 <16 100 <0.061 <0.069 32.7 0.37.1 6.3J <0.4 7.5 162 190 0.5* <0.50 <1.0 <0.50 <0.50 <0.020 22 MW-13 27-Apr-16 107.5 5.76 4.24 <2.0 20 68 <0.061 <0.069 44.0 <0.04 8.8J <0.4 5.7 200 240 0.5* <0.50 <1.0 <0.50 <0.50 <0.020 2.8 MW-13 17-Nov-16 92.7 6.20 1.72 <2.0 16 190B <10 <10 49D 0.12J 8.11 -- 4.5 190 410 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 40 MW-13 28-Apr-17 115.4 5.43 1.61 <2.0 16 170E <10 <10 29 0.0911 9.11 <1.0 5.5 190 420 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 2.3 MW-13 28-Sep-17 143.0 6.34 3.06 <2.0 14 270 <10 <10 54 0.010.1 7.0J <1.0 5.2 180 160 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 3.8 MW-13 29-Mar-18 127.6 5.71 1.95 <2.0 <10 130 <10 <10 38 <0.020 15.0 <1.0 4.5 210 270 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 2.7 MW-13 27-Nov-18 2.2 5.99 2.17 <2.0 <20 270 <10 <10 30 0.11 7.7 <1.0 5.1 170 270 0.5* 0.15 <0.10 <0.20 <0.10 <0.10 6.9 MW-13 29-Apr-19 198.2 4.45 1.14 <2.0 <20 120 <10 <10 35 0.083 8.3 <1.0 5.6 200 490 0.0* 0.10 <0.10 <0.20 <0.10 <0.10 1.3 MW-13 26-Sep-19 65.7 5.89 2.58 <2.0 <20 73B <10 <10 53 7.8 7.0 <1.0 4.2 220 610 0.0* 0.24 <0.10 <0.20 0.13 <0.10 2.3 MW-13 15-Apr-20 173.0 6.36 0.48 <2.0 <20 36 <10 <10 39 <0.020 8.2 <1.0 4.0 190 300 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 9.1 MW-13 22-Oct-20 86.2 5.38 3.49 <2.0 <20 120B <10 <10 38 0.061HJD 6.0 <0.10 5.0 140 310 0.0* 0.44J <0.10 <0.20 <0.10 <0.10 0.62) MW-13 14-Apr-21 163.0 5.14 0.74 <2.0 <20 85 <10 <10 37 <0.10 5.8 <1.0 5.0 140 380 0.0* 0.281 <0.058 <0.053 <0.053 <0.060 3.2 MW-13 I 20-Oct-21 111.2 5.92 0.46 <2.0 <20 130 <10 <10 48 0.027BHJD 6.7 1 <1.0 1 3.8 1 170 1 350 1 0.0* 1 0.401 1 <0.058 0.71 <0.053 <0.060 1.3J Smith Page 3 of 5 January 2022 Table 6 Geochemical Data October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-14 30-Mar-11 108.1 6.69 2.25 <2 <10 0.57 <1.5 <1.6 6.7 0.76.1 4.1J <0.01 0.6 83 20.6 <0.037 <0.083 <0.16 <0.44 <0.15 <0.14 4.5 MW-14 7-Nov-11 18.2 6.78 1.06 6.7 25 299D <1 <2.3 11B 0.0361 4.8J 0.0651 5.5 70 <1.3 0.040 1.5 <0.024 0.0691 <0.057 <0.061 0.95 MW-14 3-Apr-12 174.2 6.57 1.04 <2 19 282D <1 <2.3 62B <0.025 3.9JB <0.01 1.8 220D 170D 0.042 <0.04 <0.024 <0.062 0.19 <0.061 9.1 MW-14 5-Nov-12 -78.2 6.40 1.78 4 39 838D <0.2 1.19 55B <0.025 4.6J 0.20J 8.1 120D 13.8 <0.046 <0.031 <0.031 2.30 1.30 <0.010 6.1 MW-14 16-May-13 30.6 6.18 1.11 2.9 <16 7.6 <0.061 <0.069 38.5 <0.03 4.22J <0.4 3.3 140 52 0.8* <0.50 <1.0 <0.50 <0.50 <0.25 5.1 MW-14 7-Nov-13 12.2 6.64 1.55 <4 <16 8.3 <0.061 <0.069 23.4 <0.03 3.09J <0.4 0.7 173 93 0.0* <0.5 <1.0 <0.50 <0.50 <0.25 1.4 MW-14 10-Apr-14 36.8 6.47 2.25 <2 <16 23.0 <0.061 <0.069 25.7 0.16J 3.9J <0.4 1.6 158 -- 0.0* <0.5 <1.0 <0.50 <0.50 <0.25 2.8 MW-14 28-Oct-14 -7.1 5.64 0.77 5.2 <16 790 0.23 1.0 65.1 <0.03 1.8J 0.6JB 4.8 225 56 0.5* <0.5 <1.0 <0.50 <0.50 <0.25 1.1 MW-14 6-May-15 -27.6 6.22 0.91 <2 <16 17 <0.061 <0.069 68.3 0.08.1 3.6JB <0.4 3.1 214 23 0.5* <0.5 <1.0 <0.50 <0.50 <0.25 4.6 MW-14 20-Nov-15 86.5 5.28 4.49 9.6 <16 730 0.14 0.52 77.7 <0.03 2.6J 0.7J 7.2 212 53 0.5* 1.0 <1.0 <0.50 <0.50 <0.020 31 MW-14 27-Apr-16 43.6 6.27 1.61 <2.0 <12 130 <0.061 <0.069 87.7 <0.04 4.5J 0.4J 2.4 245 49 0.5* <0.50 <1.0 <0.50 <0.50 <0.020 23 MW-14 17-Nov-16 52.0 6.55 1.16 <2.0 8.3 390B <10 <10 76D <0.020 5.6J -- 1.6 230 310 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 7.5 MW-14 28-Apr-17 53.7 5.95 1.55 3.4 8.4 30B <10 <10 45 0.019.1 3.4J <1.0 2.8 180 180 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 3.7 MW-14 28-Sep-17 152.0 6.50 1.84 2.2 16 220 <10 <10 51 0.0631 1.4J 0.76J 3.1 180 160 0.5* <0.10 0.12 <0.20 <0.10 <0.10 3.9 MW-14 29-Mar-18 146.7 6.00 0.16 <2.0 <10 26 <10 <10 40 <0.020 3.7 0.84J 1.8 170 160 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 6.3 MW-14 27-Nov-18 143.1 5.95 0.19 2.3 <20 800E <10 <10 100 <0.020 1.9 1.0 2.7 220 350 0.5* 0.12 <0.10 <0.20 <0.10 <0.10 7.9 MW-14 29-Apr-19 152.4 4.64 0.07 <30 <20 690 <10 <10 98 <0.020 2.2 <1.0 2.3 230 890 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 1.4 MW-14 25-Sep-19 106.0 5.99 0.75 <2.0 <20 25B <10 <10 82 <0.020 2.7 <1.0 2.4 200 240 0.0* 0.27 <0.10 <0.20 0.14 <0.10 <1.0 MW-14 14-Apr-20 133.8 5.76 0.31 <2.0 <20 9.11 <10 <10 82 <0.020 4.1 <1.0 2.8 190 190 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 2 MW-14 22-Oct-20 66.3 5.66 0.78 <2.0 <20 350B <10 <10 90 <0.020 2.1 <0.10 2.3 180 350 0.5* 0.56 <0.10 <0.20 <0.10 <0.10 0.571 MW-14 13-Apr-21 208.0 5.63 0.04 <2.0 <20 50B <10 <10 87 <0.10 2.8 <1.0 3.6 180 240 0.0* 0.281 <O.OSS <0.053 <0.056 <0.060 2.3 MW-14 20-Oct-21 112.3 6.07 0.20 <2.0 <20 280 <10 <10 79 <0.020 3.6 <1.0 1.9 180 340 1 0.5* 0.361 <0.058 0.141 <0.053 <0.060 2.3 MW-19 5-Apr-12 203.3 7.12 1.15 <3 -- -- ----- MW-9 19-u-12 -64.2 7.1 0.28 -- <1 <0.43 0.2 <0.554 15 0.2J 21* 541140: 108 0.4* <0.031 <0.031 00.0--2-- tW63 2J 16-Aug-12 -18.4 6.80 7 1 I 37JMW-19 I 2J* I I 1 2 -- - 6-Nov-12 -21.5 6.71 1.41 17 7.27 <0.2 1.96 13 4.1J* 11J* _ 170* 10* 0.4*MW-19 - -- MW-19 16-May-13 2.4 6.60 1.08 189 320 33 0.58 0.41 17 <0.03 0.79J 1.71 17.6 148 45 0.4* 15 2.4 <0.50 4.9 <0.25 -- MW-19 31-4-13 -107.8 6.81 1.21 -- 29 1,200 0.30 0.69 21.4 <0.03 1.83J -- -- 161 23 1.3* 17 <1.0 <0.50 1.1 <0.25 -- MW-19 7-Nov-13 -32.8 7.65 1.19 <2 <16 1,200 1.1 0.084 19.7 0.17.1 2.99J <0.4 0.2 157 110 0.5* <0.5 <1.0 <0.50 <0.50 <0.25 -- MW-19 16-Jan-14 -141.9 7.54 0.36 -- <16 64 <0.061 <0.069 21.2 <0.03 3.18J -- -- 162 6.9 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-19 9-Apr-14 -74.8 7.19 1.24 <2 29 1,800 0.14 0.093 4.6 <0.03 4.9J -- -- 128 76 0.0* 1.1 <1.0 <0.50 <0.50 <0.25 -- MW-19 29-Oct-14 -31.2 6.63 1.31 <4 19 730 0.55 1.60 8.9 <0.03 4.3J 0.4JB 1.5 124 54 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-19 7-May-15 -22.4 7.21 1.38 3.9 <16 95 <0.061 <0.069 4.1 0.091 7.0JB <0.4 1.6 106 46 0.0* <0.50 <1.0 <0.50 <0.50 <0.25 18.0 MW-19 20-Nov-15 194.9 7.51 1.50 <2.0 <16 24 <0.061 <0.069 5.8 <0.03 5.0J <0.4 1.8 87.5 55 1.5* <0.50 <1.0 <0.50 <0.50 <0.020 12 MW-19 26-Apr-16 21.1 7.69 1.94 <2.0 15 12 <0.061 <0.069 8.5 0.05.1 6.7J <0.4 1.5 83.5 62 1.5* <0.50 <1.0 <0.50 <0.50 <0.020 260 MW-19 16-Nov-16 -34.7 7.68 1.43 <2.0 13 460B <10 <10 9.6 0.0083J 5.4J <1.0 2.2 95 140 3.5* <0.10 <0.10 <0.20 <0.10 <0.10 7.3 MW-19 27-Apr-17 1.4 7.25 1.47 <2.0 <10 7.6B <10 <10 11 0.015.1 4.4J <1.0 1.6 120 140 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 38 MW-19 27-Sep-17 -69.0 8.21 1.74 <2.0 <10 20 <10 <10 16 0.059.1 2.9J <1.0 <1.0 160 140 1.0* <0.10 <0.10 <0.20 <0.10 <0.10 5.1 MW-19 28-Mar-18 -2.8 7.54 0.47 <2.0 <10 <10 <10 <10 13 0.024B 6.1 <1.0 1.1 96 98 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 2.7 MW-19 27-Nov-18 -34.9 7.83 0.44 <2.0 <20 48 <10 <10 16 0.040 4.2 <1.0 1.6 140 160 0.0* 0.16 <0.10 <0.20 <0.10 <0.10 5.8 MW-19 1-May-19 97.9 5.52 0.44 <2.0 <20 <10 <10 <10 13 0.059 5.3 <1.0 <1.0 190 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 1.1 MW-19 25-Sep-19 -18.7 7.62 1.07 <2.0 <20 38B <10 <10 19 0.026H 5.0 <1.0 <1.0 150 200 0.0* 0.21 <0.10 <0.20 0.14 <0.10 1.2 MW-19 14-Apr-20 182.8 7.64 0.69 <2.0 <20 6.9J <10 <10 20 0.0181 6.6 <1.0 <1.0 110 130 0.0* <0.10 <0.10 <0.20 <0.10 <0.10 1.8 MW-19 21-Oct-20 60.0 7.34 0.59 <2.0 <20 9.4BJ <10 <10 22 0.054 2.9 <0.10 <1.0 150 140 0.0* 0.43J <0.10 0.060J <0.10 <0.10 0.78J MW-19 13-Apr-21 21.7 7.30 0.41 <2.0 <20 37B <10 <10 19 0.060JD 5.7 <1.0 <3.0 140 190 0.0* 0.251 <0.055 <0.053 <0.053 <0.060 1.5J MW-19 20-Oct-21 14.7 7.96 0.33 <2.0 <20 3.9J <10 <10 22 0.0067J 3.2 <1.0 <1.0 160 150 0.0* 0.28J <0.058 0.91 <0.053 <0.060 1.4J Smith Page 4 of 5 January 2022 Table 6 Geochemical Data October 2021 Semi -Annual Sampling Event Feltonsville Landfill - Wake County Permit Number 9203-MSWLF-1980 MW-29 MW-29 5-Apr-12 19-Jul-12 1 113.4 -102.8 16.541 6.46 ox 0.831 0.18 -- 1 360 27 1 221D 464D I <3 <0.2 12 1 <2.3 <0.54 1 106 15 I 1.9J* 0.8J* I 6.01* 8J* I-- -- -- 1 84* 220* 268* 292* 5.8* 4.2* -- 4.5 -- -- -- -- -- -- <0.031 <0.095 1.80 <0.010 MW-29 16-Aug-12 -6.4 6.57 0.48 -- 17 219D <0.2 <0.54 14 2.6J* 41* -- -- 162* 204* 2.2* -- -- -- -- -- -- MW-29 6-Nov-12 1.6 6.42 1.47 -- 37 59.8 <0.2 <0.54 13 9.2J* 141* - -- 208* 288* 2.4* -- -- -- -- -- -- MW-29 16-May-13 -1.4 5.49 0.98 154 620 300 <0.061 0.41 11.1 <0.03 1.45J 8.OJ 33.8 220 110 10.2* 48 1.81 <0.50 21 <0.25 -- MW-29 31-Jul-13 -54.2 6.40 1.85 -- 81 3,000 0.41 0.34 14.0 <0.03 0.73J -- -- 242 140 11.7* 26 <1.0 <0.50 9.1 <0.25 -- MW-29 7-Nov-13 -42.4 6.74 1.21 5.7 55 4,300 0.064 0.071 17.6 <0.03 1.18J 0.9J 15 301 6.6 9.8* 3 <1.0 <0.50 <0.50 <0.25 -- MW-29 16-Jan-14 -119.2 5.65 0.47 -- 99 2,400 <0.061 <0.069 5.23 <0.03 7.67J -- -- 49.1 50 1.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-29 9-Apr-14 -23.7 5.63 0.89 13.4 86 4,500 0.098 0.098J 6.30 <0.03 4.4J -- -- 107 79 1.0* <0.50 <1.0 <0.50 <0.50 <0.25 -- MW-29 29-Oct-14 -95.6 6.38 0.41 <70 54 2,700 <0.061 <0.069 11.80 <0.03 2.5J 0.8JB 18.6 173 57 1.0* <0.50 <1.0 <0.50 <0.50 <0.25 1.0 MW-29 7-May-15 -39.1 5.72 1.88 5.6 48 120 <0.061 <0.069 8.1 <0.03 4.OJB <0.4 8 94 56 0.5* <0.50 <1.0 <0.50 <0.50 <0.25 1.8 MW-29 20-Nov-15 76.7 5.49 2.71 2.1 74 2 <0.061 <0.069 7.0 <0.03 5.0J 1.6J 14.4 34.3 32 3.0* <0.50 <1.0 <0.50 <0.50 <0.020 13 MW-29 27-Apr-16 -45.9 6.07 1.94 2.5 54 58 <0.061 <0.069 8.3 <0.04 2.3J <0.8 11.7 58.6 65 2.5* <0.50 <1.0 <0.50 <0.50 <0.020 2.6 MW-29 17-Nov-16 -21.6 6.70 2.02 <2.0 16 260B <10 <10 9.3 0.12JD 1.91 <1.0 4.0 81 140 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 7.5 MW-29 27-Apr-17 5.0 5.59 2.13 2.7 72 7.68 <10 <10 6.5 0.0111 2.OJ 0.80J 18 36 73 2.5* <0.10 <0.10 <0.20 <0.10 <0.10 2.2 MW-29 27-Sep-17 -10.0 7.14 1.39 <2.0 14 230 <10 <10 14 0.041J 2.4J <1.0 3.4 130 120 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 3.4 MW-29 29-Mar-18 115.6 6.06 0.18 <2.0 39 <10 <10 <10 13 0.0111 7.2 <1.0 8.4 33 43 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 1.7 MW-29 28-Nov-18 37.7 6.30 0.26 <2.0 22 4.1J <10 <10 13 <0.020 4.3 <1.0 6.7 59 56 2.5* 0.24 <0.10 <0.20 <0.10 <0.10 7.2 MW-29 1-May-19 61.6 5.02 0.51 2.2 37 300 <10 <10 24 <0.020 3.8 <1.0 9.7 120 470 2.0* <0.10 <0.10 <0.20 <0.10 <0.10 1.2 MW-29 26-Sep-19 -22.2 6.58 0.76 <2.0 <20 72B <10 <10 23 <0.020 3.9 <1.0 3.8 140 250 0.0* 0.30 <0.10 <0.20 0 <0.10 1.4 MW-29 14-Apr-20 80.6 6.08 0.63 <2.0 <20 84 <10 <10 29 0.021 5.4 <1.0 6.4 64 88 0.5* <0.10 <0.10 <0.20 <0.10 <0.10 1.6 MW-29 22-Oct-20 60.9 5.82 1.05 <2.0 <20 130B <10 <10 22 0.018.1 2.9 <0.10 6.4 83 150 1.5* 4.3J <0.10 <0.20 <0.10 <0.10 0.57J MW-29 14-Apr-21 18.0 5.48 0.23 <2.0 <20 66 <10 <10 24 0.012.1 4.3 <1.0 5.6 57 150 0.5* 0.52J <0.12 <0.11 <0.11 <0.12 1.2J MW-29 20-Oct-21 -38.3 6.55 0.21 <2.0 <20 150 <10 <10 18 <0.020 2.8 <1.0 4.6 130 1 160 1.0* 0.29J <0.058 0.58 1 <0.053 <0.060 1.4J Notes: 1. All units are in milligrams per liter (parts per million), unless otherwise noted. 2. µg/L- micrograms per liter 3. mV - millivolt 4. nM - nanomoles per liter 5. * - Field analysis performed using a HACH kit. 6. -- Not analyzed 7. J -The analytical result is an estimated concentration between the laboratory method detection limit and the laboratory limit of quantitation. 8. D -The sample was analyzed at dilution. 9. B -The analyte was detected in the associated method blank. 10. E-Quantitation of compound exceeded the calibration range. 11. I" i - "4" Flag - The 4-blank depletion was greater than 0.20 milligrams per liter. 12. H - The analyte was analyzed out of holding time. 13. - "2" Flag - The G-G was higher than average. 14. I14i - "7" Flag - The seed correction factor was out of range. 15. - "1" Flag - The G-G was lower than the valid range. 16. S - Matrix spike/matrix spike duplicate failure A sodium lactate injection was performed near M W-8, -9, and -10 on June 18-21, 2012. -An emulsified vegetable oil injection was performed near MW-8, -9, and -10 on March 25-27, 2013. Smith Page 5 of 5 January 2022 w ry m�O 1 / 1 � l / / I / r / M W-25 279.98 M W -24 MW-4 282.79 286.11 / / b MW-23 .. 271.68 .•-MW-22 281.84 1 • ri MW-26 277.00 a 1 SW-3 � N SW-1 MW-29 MW-20 275.07 275.38.,, MW 8 MW 9 MW-18 275 74275 02 287.00 MW-19 MW-10 270.29 275.64 Injection Area MW-11 276.071 /�yrg.� MW-17 /// o/M.w m� S5` 275.71 fi / a / ze MW-27 280.37 1. Groundwater elevations were measured on October 18, 2021. 2. Potendometric contours are derivedfrom previous site investigations anda�(usted based on the recent groundwater elevations. Nep Doti Source; August 2017 Aerial Photograph, Wake County, North Carolina OneMdp. 4 \ Matti 3 D famed Dike Location from Geophysical Data Width 1 feetl0epth 30 reef I o \ 1=® \1 MW-6 301.21 i 1 I MW-28 1 296.51- I 1 1 Felton�sville Closed landfill � l I / 1 1 1 / 1 MW-13 / 291.18 -- �—` 1 MW-15 291.17 MW-12 MW-14 297.43 291.24 r, LEGEND 't \ MW2 � t 335.86 Ar.9D Groundwater Monitoring Well 2/6 75 Groundwater Elevation Surface Water Sample Location 290 — Potentiometric Contour (dashed where inferred) M W-8 Total Detected VOCs 160 140 120 : 100 a a 60 40 pr7 IC C!R c� 00 01 OA cab CO 00 00 Oy O'L (Z'5 (Z'5 cp Pit ,ate cps Pit ,�� Op� ��� Pic ,ate cps ,�� Pit 41` Op� Pit ,ate Op� ��� Pic ,ate 6` ,�� Pic ,a� Op� Pit ,ate Oo� Pic ,ate 0` Date Note: Acetone was omitted as it is a common laboratory contaminant. Figure 2 October 2021 Semi -Annual Sampling Event Smith Feltonsville Landfill — Wake County M W-9 Total Detected VOCs 180 160 140 120 CL Q. `0 100 a, 80 M r` 40 20 Ell I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Ln I i--I I N I In I W o I I I 10 0 N 0 I N 0 0 I N I N ,N 1 0 I J I I U I I c l Q I Q I c '++ I E I 06 I I I O to 0 co I a` I 1 E 1 I I — sZ I , I c _ c I E I N v O I — I + I O � I E I v I c LJ I E I X O 1 L1 I O m ate+ C I Vl I O I C I C I I O , I � I � I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I Off` O� OHO 01 O)A Ob 00 00 Q0 Q' x O'ti O'5 O� O� O� O� 00 01 Ob 00 00 y0 yy y'l y'l y'� ��` y� �O �O ti1 ti� ti0 ti0 ,LO ,tiy ,Ly cps ,�� Pic ,;� cp ,�� Pit ,ate cps ,�� Pic ,ate cps ��� Pic ,ate Op,�� Pic ,ate O`� ,�� Pit ,ate cps ,J� Pic ,ate C`, ��� Pic ,ate cp ,�� Pic ,�� o` Date Note: Acetone was omitted as it is a common laboratory contaminant. Figure 3 October 2021 Semi -Annual Sampling Event Smith Feltonsville Landfill — Wake County M W-10 Total Detected VOCs RM 500 400 2 Q. 1Z U O v 300 v v 12 200 100 A :.0 I I "1 I I r-I 1r4 I ry I m I Ir4 100 I pN 1 00 U I> I NO I U 1 p 06 I J I 1 1 1 I I I I •++ I p , co 1 •y, I E 1 bA 1 0 I I I I I I U I I I I 4! I N I ? I I i I O I C I I O I I E I N I Q I v I 1 I a 1 O_ 1 E I I I I I I I p I uai I I C I- 1 O 1 C N I I I 1 I 1 U I� 2 '- I I O I I I I 1 I I 1 E 1 v I C I I I I I I I LJ I E I p 1 Q I x I X O I I I I m I O I I 1 I I I I I I I m Ii7i I I I I I ,+�+ I I l/1 I `� O _ I I I 1 I 1 0 I I I I I I a I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 1 1 00.< I I I I I I I I I I I I I I I I I I I I I I 1 I 1 I I I I I I 1 I I I I I I I 1 I 1 I I I I I Q I I I I I I I I I I I I I I I I I I I I C� °�� °��° O1 Oil 0 C� 00 Q0 O,' O'1, (Z S O'5 O� O� Q0 OHO O'� Q) 00 O� y0 yy y'1, y, y'S y0yh y� y(o y'� y'b yob ti� ,LO cps ��� Pit ,�� cps� cps� cps cps Pit' it ,ate O�� ,�� P�� ,ate cps� C`_ ��� P�� ,�� 6! Date Note: Acetone was omitted as it is a common laboratory contaminant. � DMth Figure 4 October 2021 Semi -Annual Sampling Event Feltonsville Landfill — Wake County M W-12 Total Detected VOCs PW W 16 14 2 a 12 �i co 8 M. 4 2 Lei ci �� fir° °1 oi1 00 C(� 0, 00 O'y 0'L O', (�5 OR O� Or° OHO 01 Q%b (Z� OP 1y ,:y 1y1 1y 1 1` 1y 1�1 1� 1� ti1 ti00 ti� 1� _L, ,tiy 1ti' Oc� cps ,� Pit ,ate OG� ,� Pit ,ate cps ,� Pic ,ate O`er ,� Pit ,ao cps ,� Pit ,ate OG� ,� Pit ,ate O�! ,� P ,ate Opp Date Note: Acetone was omitted as it is a common Iaboratorvcontaminant. Figure 5 October 2021 Semi -Annual Sampling Event Smith Feltonsville Landfill — Wake County M W-13 Total Detected VOCs 30 25 20 10 5 O� °�� 0O� 01 �� Ooi 00 00 Oy O'ti O� O� O� O� 00 00 0A 04' O� O� y0 yy y'L y'l �' yR yh y� ti tit y(b y4' ti� LO ,tiy ,Ly cps Pic , cps Pit ,ate cps ,�� Pic ,ate cps ��� Pic ,ate cps P� ,ate cps P�� ,ate cps ,J� Pic ,ate Op Date Note: Acetone was omitted as it is a common Iaboratory contaminant. Figure 6 October 2021 Semi -Annual Sampling Event Smith Feltonsville Landfill — Wake County M W-14 Total Detected VOCs 25 all 2 a 15 �i 5 Lei c� O� 0 O� C1 C�, C0 0, 00 O'y OL (', (�5 OR O� Or° OHO 01 O' (Z i e y0 ,y ^" y,' , y ti� tih ti� -1 ti� ti� ti0 -L, do ,� P ,�� O`er ,� Pic ,ate cps ,�� Pit ,ate dG ,� Pit ,ate do ,� Pic ,ate O`er 4 Pit ,ate cps ,� Pit' it ,ate dG ,� Pit ,ate d!! ,� P ,al- O`_ Date Note: Acetone was omitted as it is a common Iaboratorvcontaminant. Figure 7 October 2021 Semi -Annual Sampling Event Smith Feltonsville Landfill — Wake County MW-15 Total Detected VOCs 25 20 a 15 5 ri7 0� oir° oil 01 04' Ci 00 00 O'y &, 03 O',5 O� O� Or° Or° ) Orb Oo5 00 y0 y, y'L y`L y'� y� ti� ti� ti0 y1 y4' y4' 'y0 LO titi 'Ly O`er QQ� ,ate Cam- �\ Pit �a� O� �" QQ� �a� O� " QQc �,, " Op� ��� Q�j �a� Op ��� Pit ,ate Op Pit �a� Oo� QQ� �a� OG� Date Note:Acetonewas omitted as itis a common laboratory contaminant. � DMth Figure 8 October 2021 Semi -Annual Sampling Event Feltonsville Landfill — Wake County MW-16 Total Detected VOCs 30 25 W a a U O 15 a, 4, aj M ra 10 5 ri7 Oh co oi\ 01 04' Ci 00 00 O'y &, 03 O',5 O� O� OHO OHO 01 O� 00 00 y0 yy y'L y`L y'� y� ti� ti� ti0 y1 y4' y4' 'y0 LO titi 'Ly O`er QQ� ,ate Cam- �\ Pit �a� O� �" QQ� �a� O� " QQc �,, " Op� ��� Q�j �a� Op ��� Pit ,ate Op Pit �a� O�� QQ� �a� OG� Date Note: Acetone was omitted as it is a common Iaboratorycontaminant. � DMth Figure 9 October 2021 Semi -Annual Sampling Event Feltonsville Landfill — Wake County M W-29 Total Detected VOCs j2 35 30 25 10 5 a I I I I Ib I I I 10 N I I I I I I I I E I I I I I on 10 I I I I d I I I I qp I I I I I I I a I >_ I I I I I I I A I N I I 1 I I ate-+ I I I 1 0 I I I I I N c I ra I I 1 x O I I I I I I i I I I 10 O I I I I O I I N I I ri I I I 'O I _0 Q 1 o I I I 1 I I I I I Q I I I .+., I I I p I N C I (V 1 C I 0) I E 1 I I 1 I J I C I E I O_ I I I I 0 I E r I .21 O I O I I I I Nam+ I N ( I � I I I > O I I O I I I OV I N Of m l O I m 1 I I I I I (D I J I in I C I I in I C I I I I NN NN IX ti<-) tih tiII) ti(0 ti(0 tib NA NA NA ti(b ti% ti� ti� ti� tiC �O �O �O C `, � o �� C `, � ,ice CP. 1< lip CP- le��� O`'C. ��� ��� C `' <C e ��� Cp' <:0 'S � � Cp° "< � CP < � �� CP Date Note: Acetone was omitted as it is a common laboratory contaminant. Figure 10 October 2021 Semi -Annual Sampling Event Smith Feltonsville Landfill — Wake County Appendix A Analytical Data aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Feltonsville Landfill Lot Number:WJ21026 Date Completed:11/20/2021 11 /21 /2021 9:24 PM Approved and released by: Project Manager II: Cathy S. Dover =w�4 aecRFo���A16 TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 257 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: WJ21026 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid Chemical Material: TOC Walkley-Black. Metals 6020B The MSD for batch 19783 and parent sample WJ21026-001 (MW-8), recovered outside the upper control limit. The associated LCS and MS passed acceptance criteria. Nitrate The following samples were diluted due to the nature of the sample matrix: WJ21026-002 (MW-9), WJ21026-003 (MW-10), WJ21026-006 (MW-13), WJ21026-009 (MW-12). The LOQ has been elevated to reflect the dilution. Reanalysis of the following samples was performed outside of the analytical holding time: WJ21026-002 (MW-9), WJ21026-003 (MW-10), WJ21026-006 (MW-13) and WJ21026-009 (MW-12). These samples were reanalyzed outside of holding time due to matrix interference during initial analysis. Both runs have been reported. The method blank for analytical batch 20146 contained nitrate greater than the acceptance criteria. The associated samples, WJ21026-006 (MW-13) and WJ21026-009 (MW-12), did not contain detections for the target analyte greater than the LOQ; therefore, re -analysis of samples was not performed. The data has been reported. BOD The results of the three GGA check samples associated with the batch are as follows: 125.9 mg/L, 137.4 mg/L, and 141.9 mg/L. The resulting average BOD for the three bottles, after correcting for dilution and seed is 135.1 mg/L which is lower than the method required range of 198±30.5 mg/L. The affected data Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 257 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 for samples WJ21026-001 (MW-8), WJ21026-002 (MW-9) and WJ21026-003 (MW-10) has been flagged with a "1" qualifier accordingly. The seed correction factor was above the method range of 0.6 to 1.0. SCF = 1.3. Samples WJ21026- 001 (MW-8), WJ21026-002 (MW-9) and WJ21026-003 (MW-10) are flagged with a "7" flag accordingly. The results of the three GGA check samples associated with the batch are as follows: 162 mg/L, 158 mg/L, and 118.5 mg/L. The resulting average BOD for the three bottles, after correcting for dilution and seed is 146.2 mg/L which is lower than the method required range of 198±30.5 mg/L. The affected data for sample WJ21026-030 (MW-2) has been flagged with a "1" qualifier accordingly. The seed correction factor was above the method range of 0.6 to 1.0. SCF = 1.4. Sample WJ21026-030 (MW-2) is flagged with a 7" flag accordingly. The results of the three GGA check samples associated with the batch are as follows: 114.5 mg/L, 125.5 mg/L, and 129 mg/L. The resulting average BOD for the three bottles, after correcting for dilution and seed is 123.0 mg/L which is lower than the method required range of 198±30.5 mg/L. The affected data for samples WJ21026-004 (MW-19), WJ21026-005 (MW-29), WJ21026-006 (MW-13), WJ21026-008 (MW-14) and WJ21026-009 (MW-12) has been flagged with a "1" accordingly. The seed correction factor was above the method range of 0.6 to 1.0. SCF = 1.3. Samples WJ21026-004 (MW-19), WJ21026-005 (MW-29), WJ21026-006 (MW-13), WJ21026-008 (MW-14) and WJ21026-009 (MW-12) has been flagged with a "7" accordingly. COD The MS/MSD for batch 21218 and parent sample WJ21026-002 (MW-9), recovered outside the upper control limit. The associated LCS passed acceptance criteria. Sulfide The MS/MSD for batch 21218 and parent sample WJ21026-002 (MW-9), recovered marginally outside the lower control limit. The associated LCS passed acceptance criteria. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 3 of 257 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: WJ21026 Project Name: Feltonsville Landfill Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-8 Aqueous 10/20/20210900 10/21/2021 002 MW-9 Aqueous 10/20/20210930 10/21/2021 003 MW-10 Aqueous 10/20/20211000 10/21/2021 004 MW-19 Aqueous 10/20/20211030 10/21/2021 005 MW-29 Aqueous 10/20/20211100 10/21/2021 006 MW-13 Aqueous 10/20/20211330 10/21/2021 007 MW-15 Aqueous 10/20/20211400 10/21/2021 008 MW-14 Aqueous 10/20/20211430 10/21/2021 009 MW-12 Aqueous 10/20/20211530 10/21/2021 010 Trip Blank Aqueous 10/20/2021 10/21/2021 011 MW-20 Aqueous 10/19/20211250 10/21/2021 012 MW-17 Aqueous 10/19/20211400 10/21/2021 013 MW-16 Aqueous 10/19/20211440 10/21/2021 014 MW-21 Aqueous 10/19/20211500 10/21/2021 015 MW-4 Aqueous 10/19/20211520 10/21/2021 016 MW-25 Aqueous 10/19/20211535 10/21/2021 017 MW-22 Aqueous 10/19/20211600 10/21/2021 018 MW-26 Aqueous 10/19/20211620 10/21/2021 019 MW-27 Aqueous 10/19/20211630 10/21/2021 020 DUP Aqueous 10/19/20210800 10/21/2021 021 MW-28 Aqueous 10/21/20210845 10/22/2021 022 MW-6 Aqueous 10/21/20210900 10/22/2021 023 MW-18 Aqueous 10/21/20210910 10/22/2021 024 MW-11 Aqueous 10/21/20210930 10/22/2021 025 MW-9 Aqueous 10/21/20210945 10/22/2021 026 MW-29 Aqueous 10/21/20210950 10/22/2021 027 SW-1 Aqueous 10/21/20211010 10/22/2021 028 SW-3 Aqueous 10/21/20211050 10/22/2021 029 MW-12 Aqueous 10/21/20211150 10/22/2021 030 MW-2 Aqueous 10/21/20211220 10/22/2021 031 MW-13 Aqueous 10/21/20211115 10/22/2021 032 MW-14 Aqueous 10/21/20211130 10/22/2021 033 MW-12 Aqueous 10/21/20211150 10/22/2021 034 MW-24 Aqueous 10/21/20211545 10/22/2021 035 MW-23 Aqueous 10/19/20211610 10/22/2021 036 Trip Blank Aqueous 10/19/2021 10/22/2021 037 Equipment Blank Aqueous 10/21/2021 1345 10/22/2021 (37 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-001 Description: MW-8 Matrix: Aqueous Date Sampled:10/20/2021 0900 Project Name: Feltonsville Landfill Date Received: 10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1904 AAB 21062 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 1801 GAH 10/21/2021 1939 19595 1 (Chloride) 300.0 1 10/21/2021 2216 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1904 AAB 1 (COD) SM 5220D-2011 1 11/04/2021 0152 DAK 21218 1 (Nitrate - N) 300.0 1 10/21/2021 2216 AMR 19838 1 (Sulfate) 300.0 1 10/21/2021 2216 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 1 (TDS) SM 2540C-2011 1 10/26/2021 1927 MOM 20249 1 (TOC) SM 531OC-2011 1 11/05/2021 0222 MSG 21537 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 120 20 20 mg CaCO3/L 1 BOD, 5 day SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 Chloride 300.0 6.0 1.0 0.25 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CO2 D 140 27 27 mg/L 1 COD SM 5220D-2011 20 U 20 20 mg/L 1 Nitrate - N 300.0 0.14 0.020 0.0050 mg/L 1 Sulfate 300.0 0.49 J 1.0 0.25 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 1.0 US 1.0 1.0 mg/L 1 TDS SM 2540C-2011 170 25 25 mg/L 1 TOC SM 531OC-2011 1.0 U 1.0 1.0 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-001 Description: MW-8 Matrix: Aqueous Date Sampled:10/20/2021 0900 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0223 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 2.0 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.9 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.49 J 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-001 Description: MW-8 Matrix: Aqueous Date Sampled:10/20/2021 0900 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0223 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.69 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 91 70-130 98 70-130 97 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-001 Description: MW-8 Matrix: Aqueous Date Sampled:10/20/2021 0900 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/26/2021 1349 TML 20109 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 46 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-001 Description: MW-8 Matrix: Aqueous Date Sampled:10/20/2021 0900 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1014 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-001 Description: MW-8 Matrix: Aqueous Date Sampled:10/20/2021 0900 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211421 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 90 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 23 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Sodium 7440-23-5 6020B 6800 S 400 150 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 7.5 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-002 Description: MW-9 Matrix: Aqueous Date Sampled:10/20/2021 0930 Project Name: Feltonsville Landfill Date Received: 10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1912 AAB 21062 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 1803 GAH 10/21/2021 1942 19595 1 (Chloride) 300.0 1 10/21/2021 2235 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1912 AAB 1 (COD) SM 5220D-2011 1 11/04/2021 0153 DAK 21218 1 (Nitrate - N) 300.0 1 10/21/2021 2235 AMR 19838 2 (Nitrate - N) 300.0 5 10/23/2021 0054 AMR 19998 1 (Sulfate) 300.0 1 10/21/2021 2235 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 1 (TDS) SM 2540C-2011 1 10/26/2021 1927 MOM 20249 1 (TOC) SM 531OC-2011 1 11/05/2021 0302 MSG 21537 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 330 20 20 mg CaCO3/L 1 BOD, 5 day SM 521 OB-2011 7.5 17 2.0 0.18 mg/L 1 Chloride 300.0 53 1.0 0.25 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CO2 D 340 27 27 mg/L 1 COD SM 5220D-2011 20 US 20 20 mg/L 1 Sulfate 300.0 1.0 U 1.0 0.25 mg/L 1 Nitrate - N 300.0 0.020 U 0.020 0.0050 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 1.0 U 1.0 1.0 mg/L 1 Nitrate - N 300.0 0.10 UH 0.10 0.025 mg/L 2 TDS SM 254OC-2011 400 25 25 mg/L 1 TOC SM 531OC-2011 4.6 1.0 1.0 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-002 Description: MW-9 Matrix: Aqueous Date Sampled:10/20/2021 0930 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0247 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.89 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.82 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 10 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.1 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.81 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-002 Description: MW-9 Matrix: Aqueous Date Sampled:10/20/2021 0930 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0247 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 106 70-130 100 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-002 Description: MW-9 Matrix: Aqueous Date Sampled:10/20/2021 0930 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/23/2021 2300 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.3 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-002 Description: MW-9 Matrix: Aqueous Date Sampled:10/20/2021 0930 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/26/2021 1405 TML 20109 2 RSK - 175 10 10/29/2021 0957 TML 20568 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 3.8 J 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 7000 D 100 25 ug/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received: 10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1920 AAB 21062 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 1807 GAH 10/21/2021 1945 19595 1 (Chloride) 300.0 1 10/21/2021 2254 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1920 AAB 1 (COD) SM 5220D-2011 1 11/04/2021 0134 DAK 21217 1 (Nitrate - N) 300.0 1 10/21/2021 2254 AMR 19838 2 (Nitrate - N) 300.0 5 10/23/2021 0113 AMR 19998 1 (Sulfate) 300.0 1 10/21/2021 2254 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 1 (TDS) SM 2540C-2011 1 10/26/2021 1927 MOM 20249 2 (TOC) SM 531OC-2011 1 11/17/2021 2140 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 420 20 20 mg CaCO3/L 1 BOD, 5 day SM 521 OB-2011 2.5 17 2.0 0.18 mg/L 1 Chloride 300.0 120 1.0 0.25 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CO2 D 510 27 27 mg/L 1 COD SM 5220D-2011 74 20 20 mg/L 1 Sulfate 300.0 10 1.0 0.25 mg/L 1 Nitrate - N 300.0 0.020 U 0.020 0.0050 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 1.0 U 1.0 1.0 mg/L 1 Nitrate - N 300.0 0.10 UH 0.10 0.025 mg/L 2 TDS SM 2540C-2011 660 25 25 mg/L 1 TOC SM 531OC-2011 15 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0312 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 5.2 J 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 2.0 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.9 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 9.1 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 2.5 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 17 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0312 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.88 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 106 70-130 101 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/23/2021 2325 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 16 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/26/2021 1423 TML 20109 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 1800 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1022 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-003 Description: MW-10 Matrix: Aqueous Date Sampled:10/20/2021 1000 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A 2 3005A 3 3005A Analytical Method 6020B 6020B 6020B Dilution Analysis Date Analyst 1 11/02/20211516 BNW 10 11/03/20210113 BNW 10 11/03/20212124 BPK Prep Date Batch 10/25/20210332 19783 10/25/20210332 19783 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 15 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 830 D 50 13 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 13 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.4 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 25 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Sodium 7440-23-5 6020B 69000 D 4000 1500 ug/L 3 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-004 Description: MW-19 Matrix: Aqueous Date Sampled:10/20/2021 1030 Project Name: Feltonsville Landfill Date Received: 10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1935 AAB 21063 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 2319 GAH 10/21/2021 2301 19737 1 (Chloride) 300.0 1 10/21/2021 2313 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1935 AAB 1 (COD) SM 5220D-2011 1 11/04/2021 0153 DAK 21218 1 (Nitrate - N) 300.0 1 10/21/2021 2313 AMR 19838 1 (Sulfate) 300.0 1 10/21/2021 2313 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 1 (TDS) SM 2540C-2011 1 10/26/2021 1927 MOM 20249 2 (TOC) SM 531OC-2011 1 11/17/2021 2153 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su BOD, 5 day Chloride CO2 (calculation) COD Nitrate - N Sulfate Sulfide TDS TOC SM 2320B-2011 160 20 20 mg CaCO3/L 1 SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 300.0 22 1.0 0.25 mg/L 1 124-38-9 SM 4500-CO2 D 150 27 27 mg/L 1 SM 5220D-2011 20 U 20 20 mg/L 1 300.0 0.0067 J 0.020 0.0050 mg/L 1 300.0 3.2 1.0 0.25 mg/L 1 18496-25-8 SM 4500-S2 F-2 1.0 U 1.0 1.0 mg/L 1 SM 2540C-2011 210 25 25 mg/L 1 SM 531OC-2011 1.0 U 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-004 Description: MW-19 Matrix: Aqueous Date Sampled:10/20/2021 1030 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0337 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 24 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-004 Description: MW-19 Matrix: Aqueous Date Sampled:10/20/2021 1030 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0337 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 100 70-130 99 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 25 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-004 Description: MW-19 Matrix: Aqueous Date Sampled:10/20/2021 1030 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/26/2021 1439 TML 20109 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 3.9 J 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 26 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-004 Description: MW-19 Matrix: Aqueous Date Sampled:10/20/2021 1030 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1025 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 27 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-004 Description: MW-19 Matrix: Aqueous Date Sampled:10/20/2021 1030 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211523 BNW 6020B 10 11/03/20212132 BPK Prep Date Batch 10/25/20210332 19783 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 1.6 J 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 160 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Sodium 7440-23-5 6020B 34000 D 4000 1500 ug/L 2 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.6 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 28 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-005 Description: MW-29 Matrix: Aqueous Date Sampled:10/20/2021 1100 Project Name: Feltonsville Landfill Date Received: 10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1942 AAB 21063 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 2323 GAH 10/21/2021 2307 19737 1 (Chloride) 300.0 1 10/21/2021 2331 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1942 AAB 1 (COD) SM 5220D-2011 1 11/04/2021 0154 DAK 21218 1 (Nitrate - N) 300.0 1 10/21/2021 2331 AMR 19838 1 (Sulfate) 300.0 1 10/21/2021 2331 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 1 (TDS) SM 2540C-2011 1 10/26/2021 1927 MOM 20249 2 (TOC) SM 531OC-2011 1 11/17/2021 2207 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su BOD, 5 day Chloride CO2 (calculation) COD Nitrate - N Sulfate Sulfide TDS TOC SM 2320B-2011 130 20 20 mg CaCO3/L 1 SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 300.0 18 1.0 0.25 mg/L 1 124-38-9 SM 4500-CO2 D 160 27 27 mg/L 1 SM 5220D-2011 20 U 20 20 mg/L 1 300.0 0.020 U 0.020 0.0050 mg/L 1 300.0 2.8 1.0 0.25 mg/L 1 18496-25-8 SM 4500-S2 F-2 1.0 U 1.0 1.0 mg/L 1 SM 2540C-2011 140 25 25 mg/L 1 SM 531OC-2011 4.6 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 29 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-005 Description: MW-29 Matrix: Aqueous Date Sampled:10/20/2021 1100 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0402 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.1 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 3.2 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 30 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-005 Description: MW-29 Matrix: Aqueous Date Sampled:10/20/2021 1100 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0402 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 108 70-130 102 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 31 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-005 Description: MW-29 Matrix: Aqueous Date Sampled:10/20/2021 1100 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/23/2021 2349 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.9 J 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 32 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-005 Description: MW-29 Matrix: Aqueous Date Sampled:10/20/2021 1100 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/26/2021 1455 TML 20109 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 150 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 33 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received: 10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1949 AAB 21063 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 2324 GAH 10/21/2021 2310 19737 1 (Chloride) 300.0 1 10/21/2021 2350 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1949 AAB 1 (COD) SM 5220D-2011 1 11/04/2021 0154 DAK 21218 1 (Nitrate - N) 300.0 1 10/21/2021 2350 AMR 19838 2 (Nitrate - N) 300.0 5 10/25/2021 1758 AMR 20146 1 (Sulfate) 300.0 1 10/21/2021 2350 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 2 (TOC) SM 531OC-2011 1 11/17/2021 2220 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 170 20 20 mg CaCO3/L 1 BOD, 5 day SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 Chloride 300.0 48 1.0 0.25 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CO2 D 350 27 27 mg/L 1 COD SM 5220D-2011 20 U 20 20 mg/L 1 Sulfate 300.0 6.7 1.0 0.25 mg/L 1 Nitrate - N 300.0 0.020 U 0.020 0.0050 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 1.0 U 1.0 1.0 mg/L 1 Nitrate - N 300.0 0.027 BHJD 0.10 0.025 mg/L 2 TOC SM 531OC-2011 3.8 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 34 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/20210427 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.53 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 4.9 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.1 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 35 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/20210427 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 105 70-130 103 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 36 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0014 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 5.3 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 37 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/29/2021 1024 TML 20568 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 130 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 38 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1027 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00041 0.00020 0.000091 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 39 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-006 Description: MW-13 Matrix: Aqueous Date Sampled:10/20/2021 1330 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211231 BNW 6020B 10 11/02/20212054 BNW Prep Date Batch 10/25/20210332 19783 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 430 D 50 13 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 6.5 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.6 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 27 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 39 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 40 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-007 Description: MW-15 Matrix: Aqueous Date Sampled:10/20/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0452 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.86 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 10 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 1.2 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.45 J 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 41 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-007 Description: MW-15 Matrix: Aqueous Date Sampled:10/20/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0452 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 107 70-130 106 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 42 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-007 Description: MW-15 Matrix: Aqueous Date Sampled:10/20/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0038 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 7.7 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 43 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-007 Description: MW-15 Matrix: Aqueous Date Sampled:10/20/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1030 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 44 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-007 Description: MW-15 Matrix: Aqueous Date Sampled:10/20/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211239 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 180 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.4 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 25 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.3 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 45 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 1955 AAB 21063 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 2326 GAH 10/21/2021 2314 19737 1 (Chloride) 300.0 1 10/22/2021 0009 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 1955 AAB 1 (COD) SM 5220D-2011 1 11/06/2021 1942 DAK 21412 1 (Nitrate - N) 300.0 1 10/22/2021 0009 AMR 19838 1 (Sulfate) 300.0 1 10/22/2021 0009 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/26/2021 1518 SJL 20113 2 (TOC) SM 531OC-2011 1 11/17/2021 2233 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 180 20 20 mg CaCO3/L 1 BOD, 5 day SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 Chloride 300.0 79 1.0 0.25 mg/L 1 CO2 (calculation) 124-38-9 SM 4500-CC2 D 340 27 27 mg/L 1 COD SM 5220D-2011 20 U 20 20 mg/L 1 Nitrate - N 300.0 0.020 U 0.020 0.0050 mg/L 1 Sulfate 300.0 3.6 1.0 0.25 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 1.0 U 1.0 1.0 mg/L 1 TOC SM 531OC-2011 1.9 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 46 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0517 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.67 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 7.0 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.82 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 47 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0517 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 91 70-130 105 70-130 99 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 48 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0102 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 6.2 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 89 40-170 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 49 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/29/2021 1039 TML 20568 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 280 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 50 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1033 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00030 0.00020 0.000091 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 51 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-008 Description: MW-14 Matrix: Aqueous Date Sampled:10/20/2021 1430 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211247 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 190 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 6.0 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 1.4 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 18 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.6 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 52 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-009 Description: MW-12 Matrix: Aqueous Date Sampled:10/20/2021 1530 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 2002 AAB 21063 1 (BOD, 5 day) SM 521OB-2011 1 10/26/2021 2329 GAH 10/21/2021 2320 19737 1 (Chloride) 300.0 1 10/22/2021 0028 AMR 19839 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 2002 AAB 1 (COD) SM 5220D-2011 1 11/06/2021 1942 DAK 21412 1 (Nitrate - N) 300.0 1 10/22/2021 0028 AMR 19838 2 (Nitrate - N) 300.0 5 10/25/2021 1817 AMR 20146 1 (Sulfate) 300.0 1 10/22/2021 0028 AMR 19840 1 (Sulfide) SM 4500-S2 F-2011 1 10/27/2021 1128 SJL 20296 2 (TOC) SM 531OC-2011 1 11/17/2021 2246 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su BOD, 5 day Chloride CO2 (calculation) COD Sulfate Nitrate - N Sulfide Nitrate - N TOC SM 2320B-2011 300 20 20 mg CaCO3/L 1 SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 300.0 160 1.0 0.25 mg/L 1 124-38-9 SM 4500-CO2 D 290 27 27 mg/L 1 SM 5220D-2011 20 U 20 20 mg/L 1 300.0 12 1.0 0.25 mg/L 1 300.0 0.020 U 0.020 0.0050 mg/L 1 18496-25-8 SM 4500-S2 F-2 1.1 1.0 1.0 mg/L 1 300.0 0.10 UH 0.10 0.025 mg/L 2 SM 531OC-2011 1.8 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 53 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-009 Description: MW-12 Matrix: Aqueous Date Sampled:10/20/2021 1530 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0542 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 54 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-009 Description: MW-12 Matrix: Aqueous Date Sampled:10/20/2021 1530 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0542 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 102 70-130 98 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 55 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-009 Description: MW-12 Matrix: Aqueous Date Sampled:10/20/2021 1530 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0127 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 4.7 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 56 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-009 Description: MW-12 Matrix: Aqueous Date Sampled:10/20/2021 1530 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/29/2021 1055 TML 20568 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 19 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 57 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-010 Description: Trip Blank Matrix: Aqueous Date Sampled:10/20/2021 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0108 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 58 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-010 Description: Trip Blank Matrix: Aqueous Date Sampled:10/20/2021 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 0108 JWO 20267 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 104 70-130 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 59 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-010 Description: Trip Blank Matrix: Aqueous Date Sampled:10/20/2021 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/23/2021 2122 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 60 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-011 Description: MW-20 Matrix: Aqueous Date Sampled:10/19/2021 1250 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211148 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 7.0 J 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 61 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-011 Description: MW-20 Matrix: Aqueous Date Sampled:10/19/2021 1250 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211148 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 96 70-130 104 70-130 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 62 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-011 Description: MW-20 Matrix: Aqueous Date Sampled:10/19/2021 1250 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1035 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 63 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-011 Description: MW-20 Matrix: Aqueous Date Sampled:10/19/2021 1250 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211255 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 120 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 6.4 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.6 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 64 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-012 Description: MW-17 Matrix: Aqueous Date Sampled:10/19/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211214 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.2 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 5.5 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.64 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 65 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-012 Description: MW-17 Matrix: Aqueous Date Sampled:10/19/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211214 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 95 70-130 103 70-130 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 66 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-012 Description: MW-17 Matrix: Aqueous Date Sampled:10/19/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0151 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 28 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 67 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-012 Description: MW-17 Matrix: Aqueous Date Sampled:10/19/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1043 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 68 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-012 Description: MW-17 Matrix: Aqueous Date Sampled:10/19/2021 1400 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211318 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 15 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.8 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 8.8 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 69 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-013 Description: MW-16 Matrix: Aqueous Date Sampled:10/19/2021 1440 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211240 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.51 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 1.6 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 4.3 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.5 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.70 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 70 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-013 Description: MW-16 Matrix: Aqueous Date Sampled:10/19/2021 1440 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211240 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 1.7 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 97 70-130 105 70-130 101 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 71 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-013 Description: MW-16 Matrix: Aqueous Date Sampled:10/19/2021 1440 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1046 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 72 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-013 Description: MW-16 Matrix: Aqueous Date Sampled:10/19/2021 1440 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211326 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 12 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 220 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 6.9 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 2.7 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 73 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-014 Description: MW-21 Matrix: Aqueous Date Sampled:10/19/2021 1500 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211305 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 74 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-014 Description: MW-21 Matrix: Aqueous Date Sampled:10/19/2021 1500 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211305 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 94 70-130 102 70-130 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 75 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-014 Description: MW-21 Matrix: Aqueous Date Sampled:10/19/2021 1500 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1049 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 76 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-014 Description: MW-21 Matrix: Aqueous Date Sampled:10/19/2021 1500 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211334 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.2 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 26 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.38 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 77 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-015 Description: MW-4 Matrix: Aqueous Date Sampled:10/19/2021 1520 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211331 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.95 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 6.3 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.53 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 78 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-015 Description: MW-4 Matrix: Aqueous Date Sampled:10/19/2021 1520 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211331 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 96 70-130 103 70-130 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 79 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-015 Description: MW-4 Matrix: Aqueous Date Sampled:10/19/2021 1520 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1051 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 80 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-015 Description: MW-4 Matrix: Aqueous Date Sampled:10/19/2021 1520 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211342 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 1.3 J 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 35 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.3 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.49 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.0 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 81 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-016 Description: MW-25 Matrix: Aqueous Date Sampled:10/19/2021 1535 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211356 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.94 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 1.2 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 82 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-016 Description: MW-25 Matrix: Aqueous Date Sampled:10/19/2021 1535 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211356 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 103 70-130 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 83 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-016 Description: MW-25 Matrix: Aqueous Date Sampled:10/19/2021 1535 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0216 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 31 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 84 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-016 Description: MW-25 Matrix: Aqueous Date Sampled:10/19/2021 1535 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1054 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 85 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-016 Description: MW-25 Matrix: Aqueous Date Sampled:10/19/2021 1535 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211349 BNW 6020B 10 11/02/20212102 BNW Prep Date Batch 10/25/20210332 19783 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.2 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 770 D 50 13 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.17 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.3 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.78 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 13 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.5 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 7.8 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 86 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-017 Description: MW-22 Matrix: Aqueous Date Sampled:10/19/2021 1600 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211422 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 87 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-017 Description: MW-22 Matrix: Aqueous Date Sampled:10/19/2021 1600 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211422 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 100 70-130 106 70-130 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 88 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-017 Description: MW-22 Matrix: Aqueous Date Sampled:10/19/2021 1600 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1057 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 89 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-017 Description: MW-22 Matrix: Aqueous Date Sampled:10/19/2021 1600 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211357 BNW 6020B 10 11/03/20212140 BPK Prep Date Batch 10/25/20210332 19783 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 14 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 420 D 50 13 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 7.4 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.43 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.0 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 2.9 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 90 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-018 Description: MW-26 Matrix: Aqueous Date Sampled:10/19/2021 1620 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211448 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 3.3 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 91 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-018 Description: MW-26 Matrix: Aqueous Date Sampled:10/19/2021 1620 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211448 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 104 70-130 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 92 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-018 Description: MW-26 Matrix: Aqueous Date Sampled:10/19/2021 1620 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0241 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 20 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 90 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 93 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-018 Description: MW-26 Matrix: Aqueous Date Sampled:10/19/2021 1620 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1100 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 94 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-018 Description: MW-26 Matrix: Aqueous Date Sampled:10/19/2021 1620 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211405 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 1.8 J 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 30 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.39 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.27 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.0 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 7.9 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.3 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.7 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 35 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 95 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-019 Description: MW-27 Matrix: Aqueous Date Sampled:10/19/2021 1630 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211513 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 3.1 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 9.1 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 1.4 0.50 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 0.40 J 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.63 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 3.8 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 96 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-019 Description: MW-27 Matrix: Aqueous Date Sampled:10/19/2021 1630 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211513 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.44 J 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 104 70-130 103 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 97 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-019 Description: MW-27 Matrix: Aqueous Date Sampled:10/19/2021 1630 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0305 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 13 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 92 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 98 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-019 Description: MW-27 Matrix: Aqueous Date Sampled:10/19/2021 1630 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1102 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 99 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-019 Description: MW-27 Matrix: Aqueous Date Sampled:10/19/2021 1630 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/02/20211413 BNW Prep Date Batch 10/25/20210332 19783 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.9 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.0 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 100 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-020 Description: DUP Matrix: Aqueous Date Sampled:10/19/2021 0800 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211539 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.52 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.49 J 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 1.6 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 4.4 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.5 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.67 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 101 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-020 Description: DUP Matrix: Aqueous Date Sampled:10/19/2021 0800 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/26/20211539 BWS 20164 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 1.7 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 92 70-130 104 70-130 101 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 102 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-020 Description: DUP Matrix: Aqueous Date Sampled:10/19/2021 0800 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1105 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 103 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-020 Description: DUP Matrix: Aqueous Date Sampled:10/19/2021 0800 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211144 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 12 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 220 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.1 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 6.6 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 4.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 104 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-021 Description: MW-28 Matrix: Aqueous Date Sampled:10/21/2021 0845 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1550 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 2.6 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 105 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-021 Description: MW-28 Matrix: Aqueous Date Sampled:10/21/2021 0845 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1550 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 106 70-130 102 70-130 101 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 106 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-021 Description: MW-28 Matrix: Aqueous Date Sampled:10/21/2021 0845 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1108 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 107 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-021 Description: MW-28 Matrix: Aqueous Date Sampled:10/21/2021 0845 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211146 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 0.65 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 260 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.31 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.9 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.45 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 2.6 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 9.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 108 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-022 Description: MW-6 Matrix: Aqueous Date Sampled:10/21/2021 0900 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1614 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 1.5 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 1.1 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 2.3 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis-1,2-Dichloroethene 156-59-2 8260D 1.8 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 2.3 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 109 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-022 Description: MW-6 Matrix: Aqueous Date Sampled:10/21/2021 0900 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1614 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.45 J 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 99 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 110 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-022 Description: MW-6 Matrix: Aqueous Date Sampled:10/21/2021 0900 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0330 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 18 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 87 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 111 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-022 Description: MW-6 Matrix: Aqueous Date Sampled:10/21/2021 0900 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1116 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 112 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-022 Description: MW-6 Matrix: Aqueous Date Sampled:10/21/2021 0900 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211148 BNW 6020B 5 11/05/20211445 BNW Prep Date Batch 10/27/20210900 19969 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 3.0 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 970 D 25 6.3 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.15 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 12 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.5 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 38 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 8.9 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 113 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-023 Description: MW-18 Matrix: Aqueous Date Sampled:10/21/2021 0910 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1637 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 2.7 J 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 114 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-023 Description: MW-18 Matrix: Aqueous Date Sampled:10/21/2021 0910 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1637 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 103 70-130 101 70-130 100 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 115 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-023 Description: MW-18 Matrix: Aqueous Date Sampled:10/21/2021 0910 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0354 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 12 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 86 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 116 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-023 Description: MW-18 Matrix: Aqueous Date Sampled:10/21/2021 0910 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1118 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 117 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-023 Description: MW-18 Matrix: Aqueous Date Sampled:10/21/2021 0910 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211150 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 110 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.4 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 4.9 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.74 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 21 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 4.1 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 6.1 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 118 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-024 Description: MW-11 Matrix: Aqueous Date Sampled:10/21/2021 0930 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1700 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 119 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-024 Description: MW-11 Matrix: Aqueous Date Sampled:10/21/2021 0930 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1700 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 106 70-130 101 70-130 101 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 120 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-024 Description: MW-11 Matrix: Aqueous Date Sampled:10/21/2021 0930 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0419 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 1.5 J 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 121 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-024 Description: MW-11 Matrix: Aqueous Date Sampled:10/21/2021 0930 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1121 JA132 10/26/2021 0718 19981 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 122 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-024 Description: MW-11 Matrix: Aqueous Date Sampled:10/21/2021 0930 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211152 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 80 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 2.8 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.9 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 123 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-025 Description: MW-9 Matrix: Aqueous Date Sampled:10/21/2021 0945 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1129 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 124 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-025 Description: MW-9 Matrix: Aqueous Date Sampled:10/21/2021 0945 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A 2 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211154 BNW 6020B 5 11/05/20211447 BNW Prep Date Batch 10/27/20210900 19969 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 3.8 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 900 D 25 6.3 ug/L 2 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.71 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 9.3 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.4 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.7 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 22 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Sodium 7440-23-5 6020B 26000 400 150 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 3.2 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 125 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-026 Description: MW-29 Matrix: Aqueous Date Sampled:10/21/2021 0950 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1132 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 126 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-026 Description: MW-29 Matrix: Aqueous Date Sampled:10/21/2021 0950 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211156 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.1 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 130 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.22 J 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.26 J 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 3.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.3 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 6.4 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 2.5 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 9.6 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Sodium 7440-23-5 6020B 14000 400 150 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.8 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 15 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 127 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-027 Description: SW-1 Matrix: Aqueous Date Sampled:10/21/2021 1010 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1723 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 128 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-027 Description: SW-1 Matrix: Aqueous Date Sampled:10/21/2021 1010 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1723 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 101 70-130 100 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 129 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-027 Description: SW-1 Matrix: Aqueous Date Sampled:10/21/2021 1010 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1140 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00014 J 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 130 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-027 Description: SW-1 Matrix: Aqueous Date Sampled:10/21/2021 1010 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211158 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 38 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 131 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-028 Description: SW-3 Matrix: Aqueous Date Sampled:10/21/2021 1050 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1746 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 132 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-028 Description: SW-3 Matrix: Aqueous Date Sampled:10/21/2021 1050 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1746 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 97 70-130 100 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 133 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-028 Description: SW-3 Matrix: Aqueous Date Sampled:10/21/2021 1050 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1148 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00012 J 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 134 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-028 Description: SW-3 Matrix: Aqueous Date Sampled:10/21/2021 1050 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211200 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 37 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 135 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-029 Description: MW-12 Matrix: Aqueous Date Sampled:10/21/2021 1150 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1151 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 136 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-029 Description: MW-12 Matrix: Aqueous Date Sampled:10/21/2021 1150 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211206 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.8 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 170 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 137 of 257 Inorganic non-metals Client:CDM Smith Laboratory ID:WJ21026-030 Description: MW-2 Matrix: Aqueous Date Sampled:10/21/2021 1220 Project Name: Feltonsville Landfill Date Received: 10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity @) SM 2320B-2011 1 11/02/2021 2010 AAB 21063 1 (BOD, 5 day) SM 521OB-2011 1 10/27/2021 1653 GAH 10/22/2021 2048 19764 2 (Chloride) 300.0 10 10/25/2021 1836 AMR 20142 1 (CO2 (calcula) SM 4500-CO2 D 1 11/02/2021 2010 AAB 1 (COD) SM 5220D-2011 1 11/06/2021 1942 DAK 21412 1 (Nitrate - N) 300.0 1 10/22/2021 1729 AMR 20024 1 (Sulfate) 300.0 1 10/22/2021 1729 AMR 20021 1 (Sulfide) SM 4500-S2 F-2011 1 10/27/2021 1128 SJL 20296 2 (TOC) SM 531OC-2011 1 11/17/2021 2300 AAB 22865 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity @ pH 4.5 su SM 2320B-2011 210 20 20 mg CaCO3/L 1 BOD, 5 day SM 521OB-2011 2.0 U17 2.0 0.18 mg/L 1 Chloride 300.0 930 D 10 2.5 mg/L 2 CO2 (calculation) 124-38-9 SM 4500-CO2 D 200 27 27 mg/L 1 COD SM 5220D-2011 29 20 20 mg/L 1 Nitrate - N 300.0 0.36 0.020 0.0050 mg/L 1 Sulfate 300.0 29 1.0 0.25 mg/L 1 Sulfide 18496-25-8 SM 4500-S2 F-2 1.6 1.0 1.0 mg/L 1 TOC SM 531OC-2011 5.2 1.0 1.0 mg/L 2 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 138 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-030 Description: MW-2 Matrix: Aqueous Date Sampled:10/21/2021 1220 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1810 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.86 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 139 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-030 Description: MW-2 Matrix: Aqueous Date Sampled:10/21/2021 1220 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1810 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 99 70-130 99 70-130 97 70-130 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 140 of 257 Dissolved Gases Client:CDM Smith Laboratory ID:WJ21026-030 Description: MW-2 Matrix: Aqueous Date Sampled:10/21/2021 1220 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 10/29/2021 1115 TML 20568 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1 Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1 Methane 74-82-8 RSK - 175 2.6 J 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 141 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-030 Description: MW-2 Matrix: Aqueous Date Sampled:10/21/2021 1220 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1153 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 142 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-030 Description: MW-2 Matrix: Aqueous Date Sampled:10/21/2021 1220 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211209 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 380 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 3.0 J 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.70 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 1.8 J 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 0.27 J 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 6.9 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.0 J 10 2.5 ug/L 1 Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 143 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-034 Description: MW-24 Matrix: Aqueous Date Sampled:10/21/2021 1545 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1833 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 144 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-034 Description: MW-24 Matrix: Aqueous Date Sampled:10/21/2021 1545 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/2021 1833 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 100 70-130 99 70-130 97 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 145 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-034 Description: MW-24 Matrix: Aqueous Date Sampled:10/21/2021 1545 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/24/2021 0443 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 7.1 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 91 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 146 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-034 Description: MW-24 Matrix: Aqueous Date Sampled:10/21/2021 1545 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1156 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 147 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-034 Description: MW-24 Matrix: Aqueous Date Sampled:10/21/2021 1545 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211211 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 7.5 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 46 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 4.5 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 0.42 J 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 1.7 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 4.4 J 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 3.4 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 148 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-035 Description: MW-23 Matrix: Aqueous Date Sampled:10/19/2021 1610 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/25/20211753 TML 20045 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 149 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-035 Description: MW-23 Matrix: Aqueous Date Sampled:10/19/2021 1610 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/25/20211753 TML 20045 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 107 70-130 104 70-130 102 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 150 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-035 Description: MW-23 Matrix: Aqueous Date Sampled:10/19/2021 1610 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1159 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 151 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-035 Description: MW-23 Matrix: Aqueous Date Sampled:10/19/2021 1610 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211213 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 7.1 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 330 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 9.2 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 3.8 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 152 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-036 Description: Trip Blank Matrix: Aqueous Date Sampled:10/19/2021 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/25/20211404 TML 20045 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 153 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-036 Description: Trip Blank Matrix: Aqueous Date Sampled:10/19/2021 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/25/20211404 TML 20045 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 103 70-130 100 70-130 99 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 154 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-036 Description: Trip Blank Matrix: Aqueous Date Sampled:10/19/2021 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/23/2021 2146 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 155 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-037 Description: Equipment Blank Matrix: Aqueous Date Sampled:10/21/2021 1345 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/20211221 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D 10 U 10 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D 5.0 U 5.0 0.80 ug/L 1 Benzene 71-43-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D 0.50 U 0.50 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D 0.50 U 0.50 0.40 ug/L 1 Bromoform 75-25-2 8260D 0.50 U 0.50 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D 0.50 U 0.50 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D 10 U 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 0.50 U 0.50 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D 0.50 U 0.50 0.40 ug/L 1 Chlorobenzene 108-90-7 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroethane 75-00-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloroform 67-66-3 8260D 0.50 U 0.50 0.40 ug/L 1 Chloromethane (Methyl chloride) 74-87-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromochloromethane 124-48-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dibromoethane (EDB) 106-93-4 8260D 0.50 U 0.50 0.40 ug/L 1 Dibromomethane (Methylene bromide) 74-95-3 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,4-Dichloro-2-butene 110-57-6 8260D 2.0 U 2.0 0.40 ug/L 1 1,2-Dichlorobenzene 95-50-1 8260D 0.50 U 0.50 0.40 ug/L 1 1,4-Dichlorobenzene 106-46-7 8260D 0.50 U 0.50 0.40 ug/L 1 Dichlorodifluoromethane 75-71-8 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethane 75-34-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloroethane 107-06-2 8260D 0.50 U 0.50 0.40 ug/L 1 1,1-Dichloroethene 75-35-4 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,2-Dichloroethene 156-59-2 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,2-Dichloroethene 156-60-5 8260D 0.50 U 0.50 0.40 ug/L 1 1,2-Dichloropropane 78-87-5 8260D 0.50 U 0.50 0.40 ug/L 1 cis- 1,3-Dichloropropene 10061-01-5 8260D 0.50 U 0.50 0.40 ug/L 1 trans- 1,3-Dichloropropene 10061-02-6 8260D 0.50 U 0.50 0.40 ug/L 1 Ethylbenzene 100-41-4 8260D 0.50 U 0.50 0.40 ug/L 1 2-Hexanone 591-78-6 8260D 10 U 10 2.0 ug/L 1 Methacrylonitrile 126-98-7 8260D 5.0 U 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D 5.0 U 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D 10 U 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D 0.50 U 0.50 0.40 ug/L 1 Styrene 100-42-5 8260D 0.50 U 0.50 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D 5.0 U 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D 0.50 U 0.50 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D 0.50 U 0.50 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 156 of 257 Volatile Organic Compounds by GC/MS Client:CDM Smith Laboratory ID:WJ21026-037 Description: Equipment Blank Matrix: Aqueous Date Sampled:10/21/2021 1345 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 10/27/20211221 CAW 20342 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Trichloroethene 79-01-6 8260D 0.50 U 0.50 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D 0.50 U 0.50 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D 0.50 U 0.50 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D 5.0 U 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D 0.50 U 0.50 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D 1.0 U 1.0 0.40 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8 98 70-130 99 70-130 98 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 157 of 257 Volatile Organic Compounds by GC/MS (SIM) Client:CDM Smith Laboratory ID:WJ21026-037 Description: Equipment Blank Matrix: Aqueous Date Sampled:10/21/2021 1345 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 10/23/2021 2211 BBW 19945 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1 Run Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 90 40-170 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 158 of 257 CVAA Client:CDM Smith Laboratory ID:WJ21026-037 Description: Equipment Blank Matrix: Aqueous Date Sampled:10/21/2021 1345 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 10/26/2021 1201 JA132 10/26/2021 0718 19985 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 159 of 257 ICP-MS Metals Client:CDM Smith Laboratory ID:WJ21026-037 Description: Equipment Blank Matrix: Aqueous Date Sampled:10/21/2021 1345 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method 1 3005A Analytical Method Dilution Analysis Date Analyst 6020B 1 11/04/20211215 BNW Prep Date Batch 10/27/20210900 19969 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Antimony 7440-36-0 6020B 2.0 U 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 2.0 U 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 5.0 U 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B 0.40 U 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B 0.50 U 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 5.0 U 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 5.0 U 5.0 1.3 ug/L 1 Lead 7439-92-1 6020B 1.0 U 1.0 0.25 ug/L 1 Nickel 7440-02-0 6020B 5.0 U 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B 5.0 U 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B 1.0 U 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B 0.50 U 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 Zinc 7440-66-6 6020B 10 U 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 160 of 257 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 161 of 257 Inorganic non-metals - BOD Blank and GGA Matrix: Aqueous Batch: 19595 SCF: 1.4 Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0 Result Avg. Result Sample ID Depl Avg. Depl (mg/L) (mg/L) Q Limit Prep Date Analysis Date WQ19595-041 (Blank) -0.03 1 0.2 10/21/2021 1753 10/26/2021 1624 WQ19595-141 (Blank) 0.08 1 0.2 10/21/2021 1753 10/26/2021 1624 WQ19595-241 (Blank) -0.01 0.01 1 0.2 10/21/2021 1753 10/26/2021 1624 WQ19595-035 (GGA) 125.9 17 167.5-228.5 10/21/2021 1801 10/26/2021 1628 WQ19595-135 (GGA) 137.4 17 167.5-228.5 10/21/2021 1801 10/26/2021 1628 WQ19595-235 (GGA) 141.9 135.1 17 167.5-228.5 10/21/2021 1801 10/26/2021 1629 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 162 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - BOD Blank and GGA Matrix: Aqueous Batch: 19737 SCF: 1.3 Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0 Result Avg. Result Sample ID Depl Avg. Depl (mg/L) (mg/L) Q Limit Prep Date Analysis Date WQ19737-041 (Blank) -0.1 1 0.2 10/21/2021 2236 10/26/2021 2302 WQ19737-141 (Blank) 0.02 1 0.2 10/21/2021 2236 10/26/2021 2302 WQ19737-241 (Blank) 0.07 0 1 0.2 10/21/2021 2237 10/26/2021 2303 WQ19737-035 (GGA) 114.5 17 167.5-228.5 10/21/2021 2244 10/26/2021 2306 WQ19737-135 (GGA) 125.5 17 167.5-228.5 10/21/2021 2244 10/26/2021 2306 WQ19737-235 (GGA) 129 123 17 167.5-228.5 10/21/2021 2244 10/26/2021 2307 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 163 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - BOD Blank and GGA Matrix: Aqueous Batch: 19764 SCF: 1.3 Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0 Result Avg. Result Sample ID Depl Avg. Depl (mg/L) (mg/L) Q Limit Prep Date Analysis Date WQ19764-041 (Blank) 0.06 1 0.2 10/22/2021 1943 10/27/2021 1605 WQ19764-141 (Blank) 0.09 1 0.2 10/22/2021 1943 10/27/2021 1605 WQ19764-241 (Blank) 0.06 0.07 1 0.2 10/22/2021 1943 10/27/2021 1605 WQ19764-035 (GGA) 162 17 167.5-228.5 10/22/2021 1950 10/27/2021 1610 WQ19764-135 (GGA) 158 17 167.5-228.5 10/22/2021 1950 10/27/2021 1611 WQ19764-235 (GGA) 118.5 146.2 17 167.5-228.5 10/22/2021 1950 10/27/2021 1610 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 164 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ19838-001 Matrix: Aqueous Batch: 19838 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 10/21/2021 2119 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 165 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ19838-002 Matrix: Aqueous Batch: 19838 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.83 1 103 90-110 10/21/2021 2138 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 166 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCSD Sample ID: WQ19838-003 Matrix: Aqueous Batch: 19838 Analytical Method: 300.0 Spike Amount Result %Rec % RPD Parameter (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Nitrate - N 0.80 0.83 1 103 0.17 90-110 20 10/21/2021 2157 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 167 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ19839-001 Matrix: Aqueous Batch: 19839 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Chloride 1.0 U 1 1.0 0.25 mg/L 10/21/2021 2119 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 168 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ19839-002 Matrix: Aqueous Batch: 19839 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 21 1 104 90-110 10/21/2021 2138 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 169 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCSD Sample ID: WQ19839-003 Matrix: Aqueous Batch: 19839 Analytical Method: 300.0 Spike Amount Result %Rec % RPD Parameter (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 20 21 1 104 0.14 90-110 20 10/21/2021 2157 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 170 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ19840-001 Matrix: Aqueous Batch: 19840 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate 1.0 U 1 1.0 0.25 mg/L 10/21/2021 2119 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 171 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ19840-002 Matrix: Aqueous Batch: 19840 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 102 90-110 10/21/2021 2138 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 172 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCSD Sample ID: WQ19840-003 Matrix: Aqueous Batch: 19840 Analytical Method: 300.0 Spike Amount Result %Rec % RPD Parameter (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate 20 20 1 101 0.43 90-110 20 10/21/2021 2157 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 173 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ19998-001 Matrix: Aqueous Batch: 19998 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 10/22/2021 1527 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 174 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ19998-002 Matrix: Aqueous Batch: 19998 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.83 1 103 90-110 10/22/2021 1605 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 175 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20021-001 Matrix: Aqueous Batch:20021 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate 1.0 U 1 1.0 0.25 mg/L 10/22/2021 1633 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 176 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20021-002 Matrix: Aqueous Batch:20021 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 20 1 101 90-110 10/22/2021 1711 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 177 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20024-001 Matrix: Aqueous Batch:20024 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 10/22/2021 1633 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 178 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20024-002 Matrix: Aqueous Batch:20024 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.75 1 93 90-110 10/22/2021 1711 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 179 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20113-001 Matrix: Aqueous Batch: 20113 Analytical Method: SM 4500-S2 F-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Sulfide 1.0 U 1 1.0 1.0 mg/L 10/26/2021 1518 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 180 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20113-002 Matrix: Aqueous Batch: 20113 Analytical Method: SM 4500-S2 F-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfide 10 9.1 1 91 80-120 10/26/2021 1518 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 181 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MS Sample ID: WJ21026-001MS Matrix: Aqueous Batch: 20113 Analytical Method: SM 4500-S2 F-2011 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfide 0.0 10 6.4 N 1 64 70-130 10/26/2021 1518 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 182 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MSD Sample ID: WJ21026-001MD Matrix: Aqueous Batch: 20113 Analytical Method: SM 4500-S2 F-2011 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfide 0.0 10 6.6 N 1 66 2.3 70-130 20 10/26/2021 1518 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 183 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20142-001 Matrix: Aqueous Batch: 20142 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Chloride 1.0 U 1 1.0 0.25 mg/L 10/25/2021 1546 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 184 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20142-002 Matrix: Aqueous Batch: 20142 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 21 1 103 90-110 10/25/2021 1624 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 185 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20146-001 Matrix: Aqueous Batch: 20146 Analytical Method: 300.0 Parameter Result Q Dil LOQ DL Units Analysis Date Nitrate - N 0.0062 J 1 0.020 0.0050 mg/L 10/25/2021 1546 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 186 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20146-002 Matrix: Aqueous Batch: 20146 Analytical Method: 300.0 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Nitrate - N 0.80 0.83 1 103 90-110 10/25/2021 1624 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 187 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20249-001 Matrix: Aqueous Batch: 20249 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TDS 25 U 1 25 25 mg/L 10/26/2021 1927 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 188 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20249-002 Matrix: Aqueous Batch: 20249 Analytical Method: SM 2540C-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 1500 1500 1 100 90-110 10/26/2021 1927 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 189 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ20296-001 Matrix: Aqueous Batch: 20296 Analytical Method: SM 4500-S2 F-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Sulfide 1.0 U 1 1.0 1.0 mg/L 10/27/2021 1128 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 190 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ20296-002 Matrix: Aqueous Batch: 20296 Analytical Method: SM 4500-S2 F-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfide 10 9.1 1 91 80-120 10/27/2021 1128 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 191 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ21062-002 Matrix: Aqueous Batch: 21062 Analytical Method: SM 2320B-2011 Spike Amount Result %Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 96 1 96 90-110 11/02/2021 1624 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 192 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ21063-002 Matrix: Aqueous Batch: 21063 Analytical Method: SM 2320B-2011 Spike Amount Result %Rec Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date Alkalinity @ pH 4.5 su 100 99 1 99 90-110 11/02/2021 1927 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 193 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ21217-001 Matrix: Aqueous Batch: 21217 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD 20 U 1 20 20 mg/L 11/04/2021 0131 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 194 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ21217-002 Matrix: Aqueous Batch: 21217 Analytical Method: SM 5220D-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 400 390 1 98 95-105 11/04/2021 0131 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 195 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MS Sample ID: WJ21026-003MS Matrix: Aqueous Batch: 21217 Analytical Method: SM 5220D-2011 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 74 400 480 1 102 90-110 11/04/2021 0135 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 196 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MSD Sample ID: WJ21026-003MD Matrix: Aqueous Batch: 21217 Analytical Method: SM 5220D-2011 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date COD 74 400 470 1 98 2.9 90-110 20 11/04/2021 0135 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 197 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ21218-001 Matrix: Aqueous Batch: 21218 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD 20 U 1 20 20 mg/L 11/04/2021 0145 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 198 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ21218-002 Matrix: Aqueous Batch: 21218 Analytical Method: SM 5220D-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 40 42 1 105 95-105 11/04/2021 0145 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 199 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MS Sample ID: WJ21026-002MS Matrix: Aqueous Batch: 21218 Analytical Method: SM 5220D-2011 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 0.0 40 53 N 1 134 90-110 11/04/2021 0153 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 200 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MSD Sample ID: WJ21026-002MD Matrix: Aqueous Batch: 21218 Analytical Method: SM 5220D-2011 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date COD 0.0 40 49 N 1 122 9.3 90-110 20 11/04/2021 0153 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 201 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ21412-001 Matrix: Aqueous Batch: 21412 Analytical Method: SM 5220D-2011 Parameter Result Q Dil LOQ DL Units Analysis Date COD 20 U 1 20 20 mg/L 11/06/2021 1938 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 202 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ21412-002 Matrix: Aqueous Batch: 21412 Analytical Method: SM 5220D-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date COD 40 41 1 101 95-105 11 /06/2021 1941 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 203 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ21537-001 Matrix: Aqueous Batch: 21537 Analytical Method: SM 531 OC-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TOC 1.0 U 1 1.0 1.0 mg/L 11/04/2021 2041 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 204 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ21537-002 Matrix: Aqueous Batch: 21537 Analytical Method: SM 531 OC-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 20 19 1 96 90-110 11/04/2021 2054 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 205 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MS Sample ID: WJ21026-001MS Matrix: Aqueous Batch: 21537 Analytical Method: SM 531 OC-2011 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 0.0 20 19 1 94 70-130 11/05/2021 0236 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 206 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MSD Sample ID: WJ21026-001MD Matrix: Aqueous Batch: 21537 Analytical Method: SM 531 OC-2011 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date TOC 0.0 20 18 1 92 1.5 70-130 20 11/05/2021 0249 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 207 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - MB Sample ID: WQ22865-001 Matrix: Aqueous Batch: 22865 Analytical Method: SM 531 OC-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TOC 1.0 U 1 1.0 1.0 mg/L 11/17/2021 2114 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 208 of 257 QC Data for Lot Number: WJ21026 Inorganic non-metals - LCS Sample ID: WQ22865-002 Matrix: Aqueous Batch: 22865 Analytical Method: SM 531 OC-2011 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TOC 20 20 1 99 90-110 11/17/2021 2127 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 209 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: WQ19945-001 Matrix: Aqueous Batch: 19945 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 10/23/2021 2018 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 92 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 210 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: WQ19945-002 Matrix: Aqueous Batch: 19945 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 49 1 98 70-130 10/23/2021 1834 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 96 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 211 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS (SIM) - MS Sample ID: WJ21026-002MS Matrix: Aqueous Batch: 19945 Prep Method: 5030E Analytical Method: 8260D (SIM) Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 6.3 50 54 1 96 70-130 10/24/2021 0532 Surrogate 1,2-Dichloroethane-d4 LOQ = Limit of Quantitation DL = Detection Limit Acceptance Q % Rec Limit 101 40-170 U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 212 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20045-001 Matrix: Aqueous Batch: 20045 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 10/25/2021 1230 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 10/25/2021 1230 Benzene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Bromoform 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 10/25/2021 1230 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Chloroethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Chloroform 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 10/25/2021 1230 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 Dichlorodifluoromethane 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 10/25/2021 1230 1,2-Dichloroethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 2-Hexanone 10 U 1 10 2.0 ug/L 10/25/2021 1230 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 10/25/2021 1230 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 10/25/2021 1230 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 10/25/2021 1230 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Styrene 0.50 U 1 0.50 0.41 ug/L 10/25/2021 1230 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Tetrahydrofuran 5.0 U 1 5.0 1.0 ug/L 10/25/2021 1230 Toluene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 213 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20045-001 Matrix: Aqueous Batch:20045 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Trichloroethene 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 10/25/2021 1230 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 10/25/2021 1230 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 10/25/2021 1230 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 96 70-130 1,2-Dichloroethane-d4 99 70-130 Toluene-d8 97 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 214 of 257 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20045-002 Matrix: Aqueous Batch: 20045 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 110 1 106 60-140 10/25/2021 1129 Acrylonitrile 100 100 1 100 70-130 10/25/2021 1129 Benzene 50 49 1 98 70-130 10/25/2021 1129 Bromochloromethane 50 49 1 97 70-130 10/25/2021 1129 Bromodichloromethane 50 52 1 103 70-130 10/25/2021 1129 Bromoform 50 56 1 111 70-130 10/25/2021 1129 Bromomethane (Methyl bromide) 50 53 1 105 70-130 10/25/2021 1129 2-Butanone (MEK) 100 110 1 112 70-130 10/25/2021 1129 Carbon disulfide 50 54 1 109 70-130 10/25/2021 1129 Carbon tetrachloride 50 55 1 111 70-130 10/25/2021 1129 Chlorobenzene 50 48 1 96 70-130 10/25/2021 1129 Chloroethane 50 57 1 115 70-130 10/25/2021 1129 Chloroform 50 50 1 99 70-130 10/25/2021 1129 Chloromethane (Methyl chloride) 50 56 1 112 60-140 10/25/2021 1129 1,2-Dibromo-3-chloropropane (DBCP) 50 55 1 109 70-130 10/25/2021 1129 Dibromochloromethane 50 54 1 108 70-130 10/25/2021 1129 1,2-Dibromoethane (EDB) 50 50 1 101 70-130 10/25/2021 1129 Dibromomethane (Methylene bromide) 50 49 1 99 70-130 10/25/2021 1129 trans- 1,4-Dichloro-2-butene 50 43 1 85 70-130 10/25/2021 1129 1,2-Dichlorobenzene 50 47 1 94 70-130 10/25/2021 1129 1,4-Dichlorobenzene 50 47 1 93 70-130 10/25/2021 1129 Dichlorodifluoromethane 50 69 1 139 60-140 10/25/2021 1129 1,1-Dichloroethane 50 49 1 99 70-130 10/25/2021 1129 1,2-Dichloroethane 50 49 1 97 70-130 10/25/2021 1129 1,1-Dichloroethene 50 56 1 111 70-130 10/25/2021 1129 cis- 1,2-Dichloroethene 50 50 1 100 70-130 10/25/2021 1129 trans- 1,2-Dichloroethene 50 52 1 103 70-130 10/25/2021 1129 1,2-Dichloropropane 50 49 1 97 70-130 10/25/2021 1129 cis- 1,3-Dichloropropene 50 52 1 104 70-130 10/25/2021 1129 trans- 1,3-Dichloropropene 50 53 1 106 70-130 10/25/2021 1129 Ethylbenzene 50 49 1 99 70-130 10/25/2021 1129 2-Hexanone 100 100 1 104 70-130 10/25/2021 1129 Methacrylonitrile 250 250 1 101 70-130 10/25/2021 1129 Methyl iodide (lodomethane) 50 53 1 106 70-130 10/25/2021 1129 4-Methyl-2-pentanone 100 100 1 100 70-130 10/25/2021 1129 Methylene chloride 50 51 1 101 70-130 10/25/2021 1129 Styrene 50 51 1 103 70-130 10/25/2021 1129 1,1,1,2-Tetrachloroethane 50 51 1 102 70-130 10/25/2021 1129 1,1,2,2-Tetrachloroethane 50 49 1 98 70-130 10/25/2021 1129 Tetrachloroethene 50 50 1 101 70-130 10/25/2021 1129 Tetrahydrofuran 50 51 1 101 70-130 10/25/2021 1129 Toluene 50 48 1 96 70-130 10/25/2021 1129 1,1,1-Trichloroethane 50 53 1 105 70-130 10/25/2021 1129 1,1,2-Trichloroethane 50 49 1 97 70-130 10/25/2021 1129 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 215 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20045-002 Matrix: Aqueous Batch:20045 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 50 50 1 100 70-130 10/25/2021 1129 Trichlorofluoromethane 50 64 1 127 70-130 10/25/2021 1129 1,2,3-Trichloropropane 50 48 1 96 70-130 10/25/2021 1129 Vinyl acetate 50 55 1 109 60-140 10/25/2021 1129 Vinyl chloride 50 61 1 123 70-130 10/25/2021 1129 Xylenes (total) 100 99 1 99 70-130 10/25/2021 1129 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 100 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 216 of 257 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20164-001 Matrix: Aqueous Batch: 20164 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 10/26/2021 1024 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 10/26/2021 1024 Benzene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Bromoform 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 10/26/2021 1024 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Chloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Chloroform 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 10/26/2021 1024 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 Dichlorodifluoromethane 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 10/26/2021 1024 1,2-Dichloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 2-Hexanone 10 U 1 10 2.0 ug/L 10/26/2021 1024 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 10/26/2021 1024 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 10/26/2021 1024 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 10/26/2021 1024 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Styrene 0.50 U 1 0.50 0.41 ug/L 10/26/2021 1024 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Tetrahydrofuran 5.0 U 1 5.0 1.0 ug/L 10/26/2021 1024 Toluene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 217 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20164-001 Matrix: Aqueous Batch:20164 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Trichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 10/26/2021 1024 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 10/26/2021 1024 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 10/26/2021 1024 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 101 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 218 of 257 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20164-002 Matrix: Aqueous Batch: 20164 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 120 1 123 60-140 10/26/2021 0923 Acrylonitrile 100 100 1 102 70-130 10/26/2021 0923 Benzene 50 48 1 96 70-130 10/26/2021 0923 Bromochloromethane 50 51 1 101 70-130 10/26/2021 0923 Bromodichloromethane 50 49 1 98 70-130 10/26/2021 0923 Bromoform 50 52 1 104 70-130 10/26/2021 0923 Bromomethane (Methyl bromide) 50 60 1 119 70-130 10/26/2021 0923 2-Butanone (MEK) 100 110 1 106 70-130 10/26/2021 0923 Carbon disulfide 50 50 1 100 70-130 10/26/2021 0923 Carbon tetrachloride 50 50 1 101 70-130 10/26/2021 0923 Chlorobenzene 50 48 1 96 70-130 10/26/2021 0923 Chloroethane 50 49 1 97 70-130 10/26/2021 0923 Chloroform 50 50 1 100 70-130 10/26/2021 0923 Chloromethane (Methyl chloride) 50 49 1 97 60-140 10/26/2021 0923 1,2-Dibromo-3-chloropropane (DBCP) 50 46 1 91 70-130 10/26/2021 0923 Dibromochloromethane 50 51 1 102 70-130 10/26/2021 0923 1,2-Dibromoethane (EDB) 50 49 1 97 70-130 10/26/2021 0923 Dibromomethane (Methylene bromide) 50 49 1 98 70-130 10/26/2021 0923 trans- 1,4-Dichloro-2-butene 50 54 1 108 70-130 10/26/2021 0923 1,2-Dichlorobenzene 50 49 1 99 70-130 10/26/2021 0923 1,4-Dichlorobenzene 50 48 1 97 70-130 10/26/2021 0923 Dichlorodifluoromethane 50 53 1 107 60-140 10/26/2021 0923 1,1-Dichloroethane 50 50 1 100 70-130 10/26/2021 0923 1,2-Dichloroethane 50 49 1 97 70-130 10/26/2021 0923 1,1-Dichloroethene 50 51 1 102 70-130 10/26/2021 0923 cis- 1,2-Dichloroethene 50 50 1 100 70-130 10/26/2021 0923 trans- 1,2-Dichloroethene 50 50 1 99 70-130 10/26/2021 0923 1,2-Dichloropropane 50 49 1 98 70-130 10/26/2021 0923 cis- 1,3-Dichloropropene 50 51 1 101 70-130 10/26/2021 0923 trans- 1,3-Dichloropropene 50 49 1 99 70-130 10/26/2021 0923 Ethylbenzene 50 48 1 97 70-130 10/26/2021 0923 2-Hexanone 100 96 1 96 70-130 10/26/2021 0923 Methacrylonitrile 250 250 1 100 70-130 10/26/2021 0923 Methyl iodide (lodomethane) 50 52 1 104 70-130 10/26/2021 0923 4-Methyl-2-pentanone 100 99 1 99 70-130 10/26/2021 0923 Methylene chloride 50 50 1 99 70-130 10/26/2021 0923 Styrene 50 51 1 102 70-130 10/26/2021 0923 1,1,1,2-Tetrachloroethane 50 50 1 101 70-130 10/26/2021 0923 1,1,2,2-Tetrachloroethane 50 49 1 97 70-130 10/26/2021 0923 Tetrachloroethene 50 47 1 95 70-130 10/26/2021 0923 Tetrahydrofuran 50 48 1 97 70-130 10/26/2021 0923 Toluene 50 47 1 93 70-130 10/26/2021 0923 1,1,1-Trichloroethane 50 50 1 101 70-130 10/26/2021 0923 1,1,2-Trichloroethane 50 46 1 92 70-130 10/26/2021 0923 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 219 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20164-002 Matrix: Aqueous Batch:20164 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 50 48 1 96 70-130 10/26/2021 0923 Trichlorofluoromethane 50 50 1 101 70-130 10/26/2021 0923 1,2,3-Trichloropropane 50 46 1 93 70-130 10/26/2021 0923 Vinyl acetate 50 53 1 105 60-140 10/26/2021 0923 Vinyl chloride 50 50 1 100 70-130 10/26/2021 0923 Xylenes (total) 100 98 1 98 70-130 10/26/2021 0923 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 94 70-130 1,2-Dichloroethane-d4 94 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 220 of 257 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20267-001 Matrix: Aqueous Batch: 20267 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 10/26/2021 2229 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 10/26/2021 2229 Benzene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Bromoform 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 10/26/2021 2229 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Chloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Chloroform 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 10/26/2021 2229 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 Dichlorodifluoromethane 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 10/26/2021 2229 1,2-Dichloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 2-Hexanone 10 U 1 10 2.0 ug/L 10/26/2021 2229 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 10/26/2021 2229 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 10/26/2021 2229 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 10/26/2021 2229 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Styrene 0.50 U 1 0.50 0.41 ug/L 10/26/2021 2229 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Tetrahydrofuran 5.0 U 1 5.0 1.0 ug/L 10/26/2021 2229 Toluene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 221 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20267-001 Matrix: Aqueous Batch:20267 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Trichloroethene 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 10/26/2021 2229 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 10/26/2021 2229 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 10/26/2021 2229 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 97 70-130 1,2-Dichloroethane-d4 106 70-130 Toluene-d8 102 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 222 of 257 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20267-002 Matrix: Aqueous Batch: 20267 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 94 1 94 60-140 10/26/2021 2126 Acrylonitrile 100 91 1 91 70-130 10/26/2021 2126 Benzene 50 48 1 95 70-130 10/26/2021 2126 Bromochloromethane 50 48 1 95 70-130 10/26/2021 2126 Bromodichloromethane 50 50 1 100 70-130 10/26/2021 2126 Bromoform 50 51 1 102 70-130 10/26/2021 2126 Bromomethane (Methyl bromide) 50 51 1 102 70-130 10/26/2021 2126 2-Butanone (MEK) 100 97 1 97 70-130 10/26/2021 2126 Carbon disulfide 50 50 1 101 70-130 10/26/2021 2126 Carbon tetrachloride 50 49 1 99 70-130 10/26/2021 2126 Chlorobenzene 50 48 1 95 70-130 10/26/2021 2126 Chloroethane 50 48 1 97 70-130 10/26/2021 2126 Chloroform 50 47 1 94 70-130 10/26/2021 2126 Chloromethane (Methyl chloride) 50 49 1 98 60-140 10/26/2021 2126 1,2-Dibromo-3-chloropropane (DBCP) 50 49 1 97 70-130 10/26/2021 2126 Dibromochloromethane 50 51 1 102 70-130 10/26/2021 2126 1,2-Dibromoethane (EDB) 50 49 1 99 70-130 10/26/2021 2126 Dibromomethane (Methylene bromide) 50 47 1 94 70-130 10/26/2021 2126 trans- 1,4-Dichloro-2-butene 50 48 1 96 70-130 10/26/2021 2126 1,2-Dichlorobenzene 50 49 1 98 70-130 10/26/2021 2126 1,4-Dichlorobenzene 50 46 1 91 70-130 10/26/2021 2126 Dichlorodifluoromethane 50 59 1 118 60-140 10/26/2021 2126 1,1-Dichloroethane 50 48 1 96 70-130 10/26/2021 2126 1,2-Dichloroethane 50 49 1 97 70-130 10/26/2021 2126 1,1-Dichloroethene 50 49 1 97 70-130 10/26/2021 2126 cis- 1,2-Dichloroethene 50 47 1 94 70-130 10/26/2021 2126 trans- 1,2-Dichloroethene 50 48 1 96 70-130 10/26/2021 2126 1,2-Dichloropropane 50 50 1 99 70-130 10/26/2021 2126 cis- 1,3-Dichloropropene 50 54 1 107 70-130 10/26/2021 2126 trans- 1,3-Dichloropropene 50 47 1 95 70-130 10/26/2021 2126 Ethylbenzene 50 49 1 97 70-130 10/26/2021 2126 2-Hexanone 100 100 1 100 70-130 10/26/2021 2126 Methacrylonitrile 250 250 1 101 70-130 10/26/2021 2126 Methyl iodide (lodomethane) 50 49 1 98 70-130 10/26/2021 2126 4-Methyl-2-pentanone 100 100 1 104 70-130 10/26/2021 2126 Methylene chloride 50 52 1 103 70-130 10/26/2021 2126 Styrene 50 53 1 106 70-130 10/26/2021 2126 1,1,1,2-Tetrachloroethane 50 50 1 99 70-130 10/26/2021 2126 1,1,2,2-Tetrachloroethane 50 47 1 94 70-130 10/26/2021 2126 Tetrachloroethene 50 47 1 93 70-130 10/26/2021 2126 Tetrahydrofuran 50 48 1 95 70-130 10/26/2021 2126 Toluene 50 49 1 97 70-130 10/26/2021 2126 1,1,1-Trichloroethane 50 49 1 98 70-130 10/26/2021 2126 1,1,2-Trichloroethane 50 48 1 96 70-130 10/26/2021 2126 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 223 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20267-002 Matrix: Aqueous Batch:20267 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 50 47 1 93 70-130 10/26/2021 2126 Trichlorofluoromethane 50 51 1 101 70-130 10/26/2021 2126 1,2,3-Trichloropropane 50 46 1 92 70-130 10/26/2021 2126 Vinyl acetate 50 47 1 93 60-140 10/26/2021 2126 Vinyl chloride 50 51 1 102 70-130 10/26/2021 2126 Xylenes (total) 100 100 1 101 70-130 10/26/2021 2126 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 84 70-130 1,2-Dichloroethane-d4 86 70-130 Toluene-d8 87 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 224 of 257 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20342-001 Matrix: Aqueous Batch: 20342 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone 10 U 1 10 4.0 ug/L 10/27/2021 1111 Acrylonitrile 5.0 U 1 5.0 0.80 ug/L 10/27/2021 1111 Benzene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Bromochloromethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Bromodichloromethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Bromoform 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Bromomethane (Methyl bromide) 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 2-Butanone (MEK) 10 U 1 10 2.0 ug/L 10/27/2021 1111 Carbon disulfide 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Carbon tetrachloride 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Chlorobenzene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Chloroethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Chloroform 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Chloromethane (Methyl chloride) 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,2-Dibromo-3-chloropropane (DBCP) 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Dibromochloromethane 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 1,2-Dibromoethane (EDB) 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 Dibromomethane (Methylene bromide) 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 trans- 1,4-Dichloro-2-butene 2.0 u 1 2.0 0.40 ug/L 10/27/2021 1111 1,2-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 1,4-Dichlorobenzene 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 Dichlorodifluoromethane 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 1,1-Dichloroethane 0.50 u 1 0.50 0.40 ug/L 10/27/2021 1111 1,2-Dichloroethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,1-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 cis- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 trans- 1,2-Dichloroethene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,2-Dichloropropane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 cis- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 trans- 1,3-Dichloropropene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Ethylbenzene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 2-Hexanone 10 U 1 10 2.0 ug/L 10/27/2021 1111 Methacrylonitrile 5.0 U 1 5.0 2.0 ug/L 10/27/2021 1111 Methyl iodide (lodomethane) 5.0 U 1 5.0 0.40 ug/L 10/27/2021 1111 4-Methyl-2-pentanone 10 U 1 10 2.0 ug/L 10/27/2021 1111 Methylene chloride 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Styrene 0.50 U 1 0.50 0.41 ug/L 10/27/2021 1111 1,1,1,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,1,2,2-Tetrachloroethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Tetrachloroethene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Tetrahydrofuran 5.0 U 1 5.0 1.0 ug/L 10/27/2021 1111 Toluene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,1,1-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,1,2-Trichloroethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 225 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - MB Sample ID: WQ20342-001 Matrix: Aqueous Batch:20342 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Trichloroethene 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Trichlorofluoromethane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 1,2,3-Trichloropropane 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Vinyl acetate 5.0 U 1 5.0 1.2 ug/L 10/27/2021 1111 Vinyl chloride 0.50 U 1 0.50 0.40 ug/L 10/27/2021 1111 Xylenes (total) 1.0 U 1 1.0 0.40 ug/L 10/27/2021 1111 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 97 70-130 Toluene-d8 99 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 226 of 257 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20342-002 Matrix: Aqueous Batch: 20342 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 84 1 84 60-140 10/27/2021 1011 Acrylonitrile 100 100 1 103 70-130 10/27/2021 1011 Benzene 50 50 1 100 70-130 10/27/2021 1011 Bromochloromethane 50 49 1 98 70-130 10/27/2021 1011 Bromodichloromethane 50 50 1 101 70-130 10/27/2021 1011 Bromoform 50 51 1 102 70-130 10/27/2021 1011 Bromomethane (Methyl bromide) 50 48 1 95 70-130 10/27/2021 1011 2-Butanone (MEK) 100 110 1 106 70-130 10/27/2021 1011 Carbon disulfide 50 53 1 105 70-130 10/27/2021 1011 Carbon tetrachloride 50 51 1 101 70-130 10/27/2021 1011 Chlorobenzene 50 49 1 98 70-130 10/27/2021 1011 Chloroethane 50 51 1 102 70-130 10/27/2021 1011 Chloroform 50 50 1 99 70-130 10/27/2021 1011 Chloromethane (Methyl chloride) 50 48 1 97 60-140 10/27/2021 1011 1,2-Dibromo-3-chloropropane (DBCP) 50 53 1 106 70-130 10/27/2021 1011 Dibromochloromethane 50 51 1 103 70-130 10/27/2021 1011 1,2-Dibromoethane (EDB) 50 51 1 102 70-130 10/27/2021 1011 Dibromomethane (Methylene bromide) 50 50 1 100 70-130 10/27/2021 1011 trans- 1,4-Dichloro-2-butene 50 55 1 110 70-130 10/27/2021 1011 1,2-Dichlorobenzene 50 50 1 100 70-130 10/27/2021 1011 1,4-Dichlorobenzene 50 50 1 99 70-130 10/27/2021 1011 Dichlorodifluoromethane 50 52 1 103 60-140 10/27/2021 1011 1,1-Dichloroethane 50 50 1 99 70-130 10/27/2021 1011 1,2-Dichloroethane 50 49 1 99 70-130 10/27/2021 1011 1,1-Dichloroethene 50 54 1 108 70-130 10/27/2021 1011 cis- 1,2-Dichloroethene 50 50 1 101 70-130 10/27/2021 1011 trans- 1,2-Dichloroethene 50 52 1 105 70-130 10/27/2021 1011 1,2-Dichloropropane 50 49 1 98 70-130 10/27/2021 1011 cis- 1,3-Dichloropropene 50 52 1 104 70-130 10/27/2021 1011 trans- 1,3-Dichloropropene 50 52 1 105 70-130 10/27/2021 1011 Ethylbenzene 50 50 1 100 70-130 10/27/2021 1011 2-Hexanone 100 100 1 105 70-130 10/27/2021 1011 Methacrylonitrile 250 250 1 100 70-130 10/27/2021 1011 Methyl iodide (lodomethane) 50 56 1 111 70-130 10/27/2021 1011 4-Methyl-2-pentanone 100 99 1 99 70-130 10/27/2021 1011 Methylene chloride 50 52 1 104 70-130 10/27/2021 1011 Styrene 50 52 1 105 70-130 10/27/2021 1011 1,1,1,2-Tetrachloroethane 50 51 1 101 70-130 10/27/2021 1011 1,1,2,2-Tetrachloroethane 50 52 1 104 70-130 10/27/2021 1011 Tetrachloroethene 50 50 1 101 70-130 10/27/2021 1011 Tetrahydrofuran 50 51 1 103 70-130 10/27/2021 1011 Toluene 50 49 1 99 70-130 10/27/2021 1011 1,1,1-Trichloroethane 50 50 1 100 70-130 10/27/2021 1011 1,1,2-Trichloroethane 50 49 1 98 70-130 10/27/2021 1011 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 227 of 257 QC Data for Lot Number: WJ21026 Volatile Organic Compounds by GC/MS - LCS Sample ID: WQ20342-002 Matrix: Aqueous Batch:20342 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Trichloroethene 50 50 1 101 70-130 10/27/2021 1011 Trichlorofluoromethane 50 51 1 102 70-130 10/27/2021 1011 1,2,3-Trichloropropane 50 51 1 102 70-130 10/27/2021 1011 Vinyl acetate 50 54 1 109 60-140 10/27/2021 1011 Vinyl chloride 50 51 1 101 70-130 10/27/2021 1011 Xylenes (total) 100 100 1 100 70-130 10/27/2021 1011 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 99 70-130 1,2-Dichloroethane-d4 95 70-130 Toluene-d8 93 70-130 LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 % = RSD is out of criteria + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21026 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 228 of 257 Dissolved Gases - MB Sample ID: WQ20109-001 Matrix: Aqueous Batch: 20109 Analytical Method: RSK - 175 Parameter Result Q Dil LOQ DL Units Analysis Date Ethane 10 U 1 10 2.5 ug/L 10/26/2021 0851 Ethene 10 U 1 10 2.5 ug/L 10/26/2021 0851 Methane 10 U 1 10 2.5 ug/L 10/26/2021 0851 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 229 of 257 QC Data for Lot Number: WJ21026 Dissolved Gases - LCS Sample ID: WQ20109-002 Matrix: Aqueous Batch: 20109 Analytical Method: RSK - 175 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Ethane 550 560 1 101 70-130 10/26/2021 0824 Ethene 520 520 1 101 70-130 10/26/2021 0824 Methane 300 290 1 97 70-130 10/26/2021 0824 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 230 of 257 QC Data for Lot Number: WJ21026 Dissolved Gases - LCSD Sample ID: WQ20109-003 Matrix: Aqueous Batch: 20109 Analytical Method: RSK - 175 Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Ethane 550 550 1 99 1.6 70-130 30 10/26/2021 0838 Ethene 520 520 1 100 1.3 70-130 30 10/26/2021 0838 Methane 300 280 1 96 0.20 70-130 30 10/26/2021 0838 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 231 of 257 QC Data for Lot Number: WJ21026 Dissolved Gases - MB Sample ID: WQ20568-001 Matrix: Aqueous Batch: 20568 Analytical Method: RSK - 175 Parameter Result Q Dil LOQ DL Units Analysis Date Ethane 10 U 1 10 2.5 ug/L 10/29/2021 0924 Ethene 10 U 1 10 2.5 ug/L 10/29/2021 0924 Methane 10 U 1 10 2.5 ug/L 10/29/2021 0924 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 232 of 257 QC Data for Lot Number: WJ21026 Dissolved Gases - LCS Sample ID: WQ20568-002 Matrix: Aqueous Batch: 20568 Analytical Method: RSK - 175 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Ethane 550 520 1 94 70-130 10/29/2021 0841 Ethene 520 490 1 95 70-130 10/29/2021 0841 Methane 300 260 1 88 70-130 10/29/2021 0841 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 233 of 257 QC Data for Lot Number: WJ21026 Dissolved Gases - LCSD Sample ID: WQ20568-003 Matrix: Aqueous Batch: 20568 Analytical Method: RSK - 175 Spike Amount Result %Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Ethane 550 520 1 95 0.29 70-130 30 10/29/2021 0910 Ethene 520 490 1 95 0.088 70-130 30 10/29/2021 0910 Methane 300 260 1 87 1.0 70-130 30 10/29/2021 0910 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 234 of 257 QC Data for Lot Number: WJ21026 ICP-MS Metals - MB Sample ID: WQ19783-001 Matrix: Aqueous Batch: 19783 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/25/2021 0332 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 2.0 U 1 2.0 0.50 ug/L 11/02/2021 1144 Arsenic 2.0 U 1 2.0 1.3 ug/L 11/02/2021 1144 Barium 5.0 U 1 5.0 1.3 ug/L 11/02/2021 1144 Beryllium 0.40 U 1 0.40 0.15 ug/L 11/02/2021 1144 Cadmium 0.50 U 1 0.50 0.13 ug/L 11/02/2021 1144 Chromium 5.0 U 1 5.0 1.3 ug/L 11/02/2021 1144 Cobalt 5.0 U 1 5.0 1.3 ug/L 11/02/2021 1144 Copper 5.0 U 1 5.0 1.3 ug/L 11/02/2021 1144 Lead 1.0 U 1 1.0 0.25 ug/L 11/02/2021 1144 Nickel 5.0 U 1 5.0 1.3 ug/L 11/02/2021 1144 Selenium 5.0 U 1 5.0 1.3 ug/L 11/02/2021 1144 Silver 1.0 U 1 1.0 0.25 ug/L 11/02/2021 1144 Sodium 400 U 1 400 150 ug/L 11/02/2021 1144 Thallium 0.50 U 1 0.50 0.15 ug/L 11/02/2021 1144 Vanadium 5.0 U 1 5.0 2.5 ug/L 11/02/2021 1144 Zinc 10 U 1 10 2.5 ug/L 11/02/2021 1144 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 235 of 257 QC Data for Lot Number: WJ21026 ICP-MS Metals - LCS Sample ID: WQ19783-002 Matrix: Aqueous Batch: 19783 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/25/2021 0332 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 100 1 102 80-120 11/02/2021 1152 Arsenic 100 98 1 98 80-120 11/02/2021 1152 Barium 100 97 1 97 80-120 11/02/2021 1152 Beryllium 100 98 1 98 80-120 11/02/2021 1152 Cadmium 100 99 1 99 80-120 11/02/2021 1152 Chromium 100 110 1 107 80-120 11/02/2021 1152 Cobalt 100 110 1 110 80-120 11/02/2021 1152 Copper 100 110 1 115 80-120 11/02/2021 1152 Lead 100 99 1 99 80-120 11/02/2021 1152 Nickel 100 110 1 112 80-120 11/02/2021 1152 Selenium 100 85 1 85 80-120 11/02/2021 1152 Silver 100 110 1 107 80-120 11/02/2021 1152 Sodium 1000 990 1 99 80-120 11/02/2021 1152 Thallium 100 110 1 107 80-120 11/02/2021 1152 Vanadium 100 100 1 101 80-120 11/02/2021 1152 Zinc 100 100 1 101 80-120 11/02/2021 1152 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 236 of 257 QC Data for Lot Number: WJ21026 ICP-MS Metals - MS Sample ID: WJ21026-001MS Matrix: Aqueous Batch: 19783 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/25/2021 0332 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 0.0 100 100 1 102 75-125 11/02/2021 1444 Arsenic 0.0 100 100 1 102 75-125 11/02/2021 1444 Barium 90 100 190 1 98 75-125 11/02/2021 1444 Beryllium 0.0 100 100 1 101 75-125 11/02/2021 1444 Cadmium 0.0 100 100 1 102 75-125 11/02/2021 1444 Chromium 3.4 100 110 1 103 75-125 11/02/2021 1444 Cobalt 0.0 100 100 1 103 75-125 11/02/2021 1444 Copper 0.0 100 110 1 108 75-125 11/02/2021 1444 Lead 0.0 100 100 1 101 75-125 11/02/2021 1444 Nickel 23 100 130 1 103 75-125 11/02/2021 1444 Selenium 0.0 100 95 1 95 75-125 11/02/2021 1444 Silver 0.0 100 100 1 100 75-125 11/02/2021 1444 Sodium 6800 1000 7700 1 93 75-125 11/02/2021 1444 Thallium 0.0 100 100 1 101 75-125 11/02/2021 1444 Vanadium 7.5 100 110 1 98 75-125 11/02/2021 1444 Zinc 0.0 100 100 1 102 75-125 11/02/2021 1444 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 237 of 257 QC Data for Lot Number: WJ21026 ICP-MS Metals - MSD Sample ID: WJ21026-001MD Matrix: Aqueous Batch: 19783 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/25/2021 0332 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Antimony 0.0 100 100 1 100 2.0 75-125 20 11/02/2021 1452 Arsenic 0.0 100 100 1 101 0.55 75-125 20 11/02/2021 1452 Barium 90 100 190 1 97 0.23 75-125 20 11/02/2021 1452 Beryllium 0.0 100 100 1 101 0.51 75-125 20 11/02/2021 1452 Cadmium 0.0 100 100 1 100 1.6 75-125 20 11/02/2021 1452 Chromium 3.4 100 110 1 103 0.26 75-125 20 11/02/2021 1452 Cobalt 0.0 100 100 1 103 0.26 75-125 20 11/02/2021 1452 Copper 0.0 100 110 1 108 0.16 75-125 20 11/02/2021 1452 Lead 0.0 100 100 1 100 1.1 75-125 20 11/02/2021 1452 Nickel 23 100 130 1 104 0.88 75-125 20 11/02/2021 1452 Selenium 0.0 100 94 1 94 0.64 75-125 20 11/02/2021 1452 Silver 0.0 100 99 1 99 0.94 75-125 20 11/02/2021 1452 Sodium 6800 1000 8200 N 1 136 5.4 75-125 20 11/02/2021 1452 Thallium 0.0 100 100 1 101 0.91 75-125 20 11/02/2021 1452 Vanadium 7.5 100 110 1 99 0.88 75-125 20 11/02/2021 1452 Zinc 0.0 100 100 1 101 0.91 75-125 20 11/02/2021 1452 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 238 of 257 QC Data for Lot Number: WJ21026 ICP-MS Metals - MB Sample ID: WQ19969-001 Matrix: Aqueous Batch: 19969 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/27/2021 0900 Parameter Result Q Dil LOQ DL Units Analysis Date Antimony 2.0 U 1 2.0 0.50 ug/L 11/04/2021 1136 Arsenic 2.0 U 1 2.0 1.3 ug/L 11/04/2021 1136 Barium 5.0 U 1 5.0 1.3 ug/L 11/04/2021 1136 Beryllium 0.40 U 1 0.40 0.15 ug/L 11/04/2021 1136 Cadmium 0.50 U 1 0.50 0.13 ug/L 11/04/2021 1136 Chromium 5.0 U 1 5.0 1.3 ug/L 11/04/2021 1136 Cobalt 5.0 U 1 5.0 1.3 ug/L 11/04/2021 1136 Copper 5.0 U 1 5.0 1.3 ug/L 11/04/2021 1136 Lead 1.0 U 1 1.0 0.25 ug/L 11/04/2021 1136 Nickel 5.0 U 1 5.0 1.3 ug/L 11/04/2021 1136 Selenium 5.0 U 1 5.0 1.3 ug/L 11/04/2021 1136 Silver 1.0 U 1 1.0 0.25 ug/L 11/04/2021 1136 Sodium 400 U 1 400 150 ug/L 11/04/2021 1136 Thallium 0.50 U 1 0.50 0.15 ug/L 11/04/2021 1136 Vanadium 5.0 U 1 5.0 2.5 ug/L 11/04/2021 1136 Zinc 10 U 1 10 2.5 ug/L 11/04/2021 1136 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 239 of 257 QC Data for Lot Number: WJ21026 ICP-MS Metals - LCS Sample ID: WQ19969-002 Matrix: Aqueous Batch: 19969 Prep Method: 3005A Analytical Method: 6020B Prep Date: 10/27/2021 0900 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Antimony 100 99 1 99 80-120 11/04/2021 1142 Arsenic 100 100 1 102 80-120 11/04/2021 1142 Barium 100 98 1 98 80-120 11/04/2021 1142 Beryllium 100 100 1 102 80-120 11/04/2021 1142 Cadmium 100 100 1 102 80-120 11/04/2021 1142 Chromium 100 100 1 101 80-120 11/04/2021 1142 Cobalt 100 100 1 100 80-120 11/04/2021 1142 Copper 100 110 1 106 80-120 11/04/2021 1142 Lead 100 100 1 101 80-120 11/04/2021 1142 Nickel 100 110 1 105 80-120 11/04/2021 1142 Selenium 100 100 1 103 80-120 11/04/2021 1142 Silver 100 96 1 96 80-120 11/04/2021 1142 Sodium 1000 1000 1 103 80-120 11/04/2021 1142 Thallium 100 94 1 94 80-120 11/04/2021 1142 Vanadium 100 99 1 99 80-120 11/04/2021 1142 Zinc 100 100 1 103 80-120 11/04/2021 1142 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 240 of 257 QC Data for Lot Number: WJ21026 CVAA -MB Sample ID: WQ19981-001 Matrix: Aqueous Batch: 19981 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury 0.00020 U 1 0.00020 0.000091 mg/L 10/26/2021 1003 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 241 of 257 QC Data for Lot Number: WJ21026 CVAA - LCS Sample ID: WQ19981-002 Matrix: Aqueous Batch: 19981 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0020 1 99 80-120 10/26/2021 1011 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 242 of 257 QC Data for Lot Number: WJ21026 CVAA - MS Sample ID: WJ21026-001MS Matrix: Aqueous Batch: 19981 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0 0.0020 0.0020 1 100 80-120 10/26/2021 1017 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 243 of 257 QC Data for Lot Number: WJ21026 CVAA - MSD Sample ID: WJ21026-001MD Matrix: Aqueous Batch: 19981 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury 0.0 0.0020 0.0020 1 98 2.0 80-120 20 10/26/2021 1019 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 244 of 257 QC Data for Lot Number: WJ21026 CVAA -MB Sample ID: WQ19985-001 Matrix: Aqueous Batch: 19985 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury 0.00020 U 1 0.00020 0.000091 mg/L 10/26/2021 1124 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 245 of 257 QC Data for Lot Number: WJ21026 CVAA - LCS Sample ID: WQ19985-002 Matrix: Aqueous Batch: 19985 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Spike Amount Result %Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0020 1 98 80-120 10/26/2021 1126 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 246 of 257 QC Data for Lot Number: WJ21026 CVAA - MS Sample ID: WJ21026-026MS Matrix: Aqueous Batch: 19985 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Sample Spike Amount Amount Result %Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0 0.0020 0.0020 1 99 80-120 10/26/2021 1135 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 247 of 257 QC Data for Lot Number: WJ21026 CVAA - MSD Sample ID: WJ21026-026MD Matrix: Aqueous Batch: 19985 Prep Method: Analytical Method: 7470A Prep Date: 10/26/2021 0718 Sample Spike Amount Amount Result %Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury 0.0 0.0020 0.0019 1 93 6.4 80-120 20 10/26/2021 1137 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 248 of 257 QC Data for Lot Number: WJ21026 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 249 of 257 PACE ANALYTICAL SERVICES, LLC 11, �. Y '� w � i "yt � -- _ — OI � �' it C 7 ' 4'. L]� H F m u m..1 .y.* U. �. • ..., s•. r L 11 � �--�,. .. �Y y�+..{�{ T.: .yr��r-:11.. 1tY}l �'% ✓yV���`�-+I'1}1:.�"J{j VY '.: ... ti. pv 5��l 6 -.tihrYOiSf _�y l; . _ 1 c f k a' 0 Or pp y u A 7 G 1hh .4 F 43 LS r tf 0i i~ I n � F v T L - u f'. S1 4t g n Jim a �— Ca Q �� 6 : — T -71 13 r tM1 k I O 17 0 C or C a v a Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 250 of 257 PACE ANALYTICAL SERVICES, LLC SaMp lea ReceipL Checklist (5RC) (MEdd18G15) RevNed:5129l?2020 /41 �Ice Afk7!}+IICal Issuing.4uthorlty: Pare E14V- VUCOl page _ of 1 a niple receipt C heddist (sRQ C',Ilenl' CE" Cooler lnzipccLed by datc: Jr(Fr2 f 1002irP 1 Txit k vG']P IG6 Means of rooei t. Pa oe list UPS rK1Ex Other: Yes -No 1 , Were custody seals Ixcsrnt cm the coolY0 Yes NOI Z NA '2, IFG115tOt[v SCAIg were resaiita wane flicy ir[[ac[ tu]d ;irbrokm? pl-1 S�rEp ID, !E-U; . C]Flor'no SkrLp la; 21.114 — Tagmd by, YR62 C}rlg[rkaT tcmporamvo upon Vecei.01- I Derived (Corrrctr:d) tcmperature Apon receipt ' Satid Strap -Cup III: MA 3.22 1 3.2 aC 2-6 12.5 Df�, '-4 rZA wt;_: 14A 114A DC+--- h4elhod;�cmTrerzmreMalik [D&,,!aio5tPottJc:.s% [ROuutID.- $ IRGun Gomeclian Factor- � °C Iierhor, afcoolarq 0 Wl Ir:r ❑ ice l iwL ❑ Ury Ice Mine 3.' Tterrrertt-im i5 any c aale_- ea.eeeded 6-011 , waq Pmject Mwta cr Nodlied7 [' x'as Notified by, phone Jemailf Lee-u�fzu-c (circleunc) VLs 'No lA 4, Is the owur ke:r,:ial to L11is FOrrn? J Yes o 17NO S- Were prdpr•r ausrody proceduivzs (eel inquishedin=ivcd) 'oiIwATd? J Yes 6- Worz surnplo IDs listed on the CDC? yes 10 Ttia 7- Wore sarrlple lfDs listed oii all snmple contaiDuns' _ 17,/1 Yes I Lj Nn 9. Was ixJ I octior dace& time Ii—swd on ftt OD ? 9, WasaallECI On dame& tiine.ligled rin all wtaplecontainers? -- 2—Vjytzj LIND , Yos 'eYrg No —7—FN—u 10, I7id all container label inC4wmatico (II). date, Time ",, qLr lh tile COCA i 11. WOW tests Lb be o[rFo-r d hsGcd on the COC? - _— Yes ❑ lq0 12 Dad all ssniplas Fa -rive. in the proper cwn Lainers fnr osc.7 Dcst and/or m gocd con,diticm 0inhni9krtn, lids oily etc.)? — Yeg LJ No 13, WIM a&quata sample volume avoi [t,bia? Eti Nal 14, Weh'n AIL mrn F4es -x-ceived with in 'A the bolding time or 49 Fours, Yi.71t31irvcr eornr5 FimV — ❑ No 1:5- were any sarnplas "-ntaincm rnLssitiWexCe.58 (Gir6-- Ono) ram pir,:5 Nor listed all COO? ❑ Yes 0 No QNA 16. For VOA and RSK-1" 5 samples, wore lnlbbles proseat x"pea-sike: ('>~"k3r 6mm is diameter) 1-1 Ruy of the VOA wals'? d Yes Nn TEA 17- Wrre rill DR.<]lmeta[ wlj-iert sevnpLe,. r--�eivcd at a p� of < 2'1 d Yes Na l A 18. Were al[ kyanide samples rereivrd at a pl.[ ? 12 and sl [1tid sam ]e L CCCi; Cd at a pH 91? ❑ DNA 19. l�'cr4. R applicable N11;1T1�N1-cyanidVp l ong 5.1 L08,3 (< 0,5m f4tiQ sarnplcs Free of residual chlorine? ❑Yes ❑7Jo 0N.� 20. Were client. remarks mgaests (Le. regnesied d:l:rtiuri�i, MS!M9D des [gnadoas, etc...} correctly trlinc�Lrihrd from klle COC iota the ownrnrnt section in JMI V El Vet If No 2 ;, Was the 'Jpbp num bcr ligt--d ai i_iC Co-ntainc.r kilw-l? Tf yrr,, fe..4 — 5awplt: Pro 3smatioa (MList b,- r irnjilewd fir any samp.tv(5) ircc,rectly pieserved or wi[[L Tit rldspaee,) Sampk(s) _ � _ were reaeivad inewrrertly preserved slid were adjusLed accordingly in sample receiving with PA: mL oft ircle one: 112SC.ia, HNO3, KC-, N90H tlsing SR 4 txA Tin1e of ptt sefVgiiun NA ! if mam &Arr sine pi raativ'c is naeded, please utita in tW caiffmcnljj'au[uw. Samples) A" wertrnr.aivedwit[ibobbles >6min Ind iimeLer- SanlpleA(A) NA wePrirxc[v-dwRhTRC:>b-51r�7.(ff�1915nojandwere iadliu€.terl acew lingly in sample rer6ytnn wi[h su]ium Illiumrilratc (Na,%O,) with 5he2�y ID: NA „— — SR balrade lsbeis applied by: a 3 Dane aor2iratra[ — -- Comments, i Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 251 of 257 PACE ANALYTICAL SERVICES, LLC . .:.T• ?i. i is ti � 3 .. r 0.0.. p y V N'... I I m:y. i :.4 .4 .. ! 77 1'.4 M ..:. .. _ d l u i` 43 L t _ L. 19 G F7 P I a yh 10 n Z m kv C 4t _ hr s- Lr- _ .r_ a Cs R 5 J «- W k 1 {I m a R rl T hi ., 1+ ri y x .z f a �y � L� S. U Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 253 of 257 R L PACE ANALYTICAL SERVICES, LLC - '.0'� :p' 9 #+?�rLS''rr�' 6u': °:dal'i M`isf.'+':ftsA*{htd :'.:1Iva 9 _ ME � n T C b+ 3 a c x � L'3 g 1 T a 'A ' yam' Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 254 of 257 NA Y H �I s �: Ip N E in .: � �-[ c r l Y PACE ANALYTICAL SERVICES, LLC 14. PE .:; arL n J. :. ca.,..': -H �J ... .• y •• j' a rz E 4K J v} �� 5 rim I CL - Q'..•:.::. �"�� Z. :. L s yi U r i f 4Ci1 All i. Ap v CL i t C13Y E u x cZ A t � � � � F �3 fir` � � .' •��� Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 255 of 257 PACE ANALYTICAL SERVICES, LLC +}Y�ra1 Samples Hel 1pt Checklist (SRC) IMEOOiSt-is) ReVISed;912912020 acs,dr� IssuingAu<hc,rlty; Pace ENV -WOOL Page Iaf 1 Sample Receipt Checklist {SRC} C1i'mt; 1 1m SrrM Cuolar Inspected N ,'date: Ki MV / ICt21iZf.21 �o- Ir. WJ2J026 W 4 Nql ofreceip ,, Lj Ptuo C;Jierl LJ UPS PudEx i IO�ltcr: yes' bil I l_ Wore cusNrly wi lx presnit or] !he cooler? Yes No J Yti l 2. J custody raai5 were 3l'Emi'r, were tl' ry intact and urmbrokcn7 H Str: P P ID: 1-BSx �s# _ _ Chlorine Strip rD; _ � Tested by, w1a1�'rr Qrrginal terltparature upon rcocipt ! Dil (CvmvLcdj temperature S65#lid upor- receipt ' Snap -Cup_ TD- 3.3 13.3 cC -2.6. 124 D(- KA r-NA NA r-NA Met])ad; RjTempeaaWr7 Blank L3;, i,1st klaules IR CiLin ID: 4 1R f',un Correction F-Ljctar: Mdh(vi of cools ❑ W-2 Ice ❑ ic4 ]'acka 11 l iv loe ❑ l*fone -- ❑ YvL, C Nn CENA I •iif ltrnwature Df any cookw;;xoceded 6.0"l was R jed MNruNotified? - TM was Notified b4: phone 1 cm�:I ! fac to-Fsace (eirr:l:: ivre), I 'des t�'o � 1 A- 4. Is OQ camrnemial courier's pecking slip atiachotd to this Ful l d yc* =T fj 5. Wcm prrpm7 custody prucedures (relirgtrislted}t eyed, thRowed? No 6, Vem ss =plc 01, IiSW or. The COC7 Yes ONO 1, Vell sarnpde IDs lislLd on all sampla containers'? d yes No 8- Wil u Em—licm date & lame JsWd -rti the COC? Yes No. 9, W93 Gollcs#ion date & tkne listed era nll sarmle cnnlamer�? 10 Yes ❑ No 10. Did al k;ortauier, labu-i informaClrrn 013, date, 6mcj r it -he COC,? `4s Nor ! I _: Werc 11:25rs to be performe>t[ I it trxi on :heCOC'? ,{ El Na l2. Did all samples arrive in the prr, +et cant shiers for each test andJpr in goad ccndiria�l (unbroken, lids oty etc.)? YC5 AID '3. W&i aeequa*- sampie vol kimc available? .. Yes Na 14_ Were all swuplc9 mzzeiwed vw�ithin Vl l_ln ; luin time or48 ho-trs` tivhivheverc •t ics firsr.? cs 4 15. VmxC s�iy s2rr Ales contai3se, n: i.kgir7 _ e:rc (circle one) .satnples Not 1istiA on CDC? Dyes [�], ND �AlA I6. For VGA attd RSK-I ,5 rugvlple:, war I� press:utt}„Ix trsize" (Y+"nr 6r,ru in dialkjcicr) m an oflw VOA vials? Yes lrJnLJNA I7_ WcN all DRO4metcLsfrmulric l: saiup'es received al a pH Df < x? * 'eS �_ A'A it Were all cyanide seunpl3.,; received al pH > 12 and sultl4e samptGR nBll at a pH > 9? ❑Yes � h ro,QNl1 14.. ere all 2ipplicabJe Ti l4_,l lcyarriri�lp envll bi}B,3 { 0.5mglLj sdtnples ee Of I , � 0_ Were client rerna4:81 ezz ic, m ueste,I diludcLis, 751MSDdeSi — I�I'r'as ❑NO Lrt NA ( gwrioiis,etc-..j CQIMCIIY transeribe>til from Ilre COC i:tr,3 the c4,mineru sediurt in LIM$? Y Nol 121. OUHs the uotC nurnber lured on the corot;tincr iaLt;l7 Ify95, QLIGU� seniple Preservation (Mus± bn complmbad for art} samplo(s} intxxrectly 1�reser+�erl or �itEt neadspaae.) samt,I�{s) u i we i� received incorrectly preserved and wire adjusmntt;icconditig;y ri ymrmple receiving with mL Of 6rolw one; 142SO4, HNO3, PICI, NaOH usiig SR Y I'irne of pl.a-vatnn NA li mare dlan one presel if needed, please role iu J1e jonrr_nents below - NA wcm received with habblm �-6 T1im its diameter. iautpl :(s) 19? v,=receivedwita 1-ftC>C-5m 1L{!f#1 isrtu}End were ,djusred wl ordingly in samplohmmiving wn R Jiurm: (Na2S O,) wvith Sheah_1 I13: NA R barcodll libel applittii by. !'�kW _Dale: IDC�r31ti I [ ommcrits; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 256 of 257 aceAnalytical Report of Analysis CDM Smith 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 Attention: Mathew Colone Project Name: Feltonsville Landfill Lot Number:WJ21031 Date Completed:12/16/2021 12/17/2021 12:05 AM Approved and released by: Project Manager II: Cathy S. Dover =w�4 aecRFo���A4W- TNI / AM Amflvue Acm^rmm Fvu rj (' 4eOfFAi� ACC R E OI TEO TESTINGL aORlTOAY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 23 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative CDM Smith Lot Number: WJ21031 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid Chemical Material: TOC Walkley-Black. If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 whw.pacelabs.com Page 2 of 23 PACE ANALYTICAL SERVICES, LLC Sample Summary CDM Smith Lot Number: WJ21031 Project Name: Feltonsville Landfill Project Number: Sample Number Sample ID Matrix Date Sampled Date Received 001 MW-21 Aqueous 10/19/20211500 10/21/2021 002 MW-4 Aqueous 10/19/20211520 10/21/2021 003 MW-25 Aqueous 10/19/20211535 10/21/2021 004 MW-22 Aqueous 10/19/20211600 10/21/2021 005 MW-26 Aqueous 10/19/20211620 10/21/2021 006 MW-18 Aqueous 10/21/20210910 10/22/2021 007 MW-11 Aqueous 10/21/20210930 10/22/2021 008 MW-9 Aqueous 10/21/20210945 10/22/2021 009 MW-29 Aqueous 10/21/20210950 10/22/2021 (9 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-001 Description: MW-21 Matrix: Aqueous Date Sampled:10/19/2021 1500 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1507 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-002 Description: MW-4 Matrix: Aqueous Date Sampled:10/19/2021 1520 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1530 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Vanadium 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-003 Description: MW-25 Matrix: Aqueous Date Sampled:10/19/2021 1535 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1533 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Barium 7440-39-3 Dissolved Cobalt 7440-48-4 6020B 750 5.0 1.3 ug/L 1 6020B 3.0 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-004 Description: MW-22 Matrix: Aqueous Date Sampled:10/19/2021 1600 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1537 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B 8.6 Dissolved Cobalt 7440-48-4 6020B 6.7 2.0 1.3 ug/L 1 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-005 Description: MW-26 Matrix: Aqueous Date Sampled:10/19/2021 1620 Project Name: Feltonsville Landfill Date Received:10/21/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1540 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Cobalt 7440-48-4 Dissolved Vanadium 7440-62-2 6020B 3.9 J 5.0 1.3 ug/L 1 6020B 6.2 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-006 Description: MW-18 Matrix: Aqueous Date Sampled:10/21/2021 0910 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1543 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Cobalt 7440-48-4 Dissolved Vanadium 7440-62-2 6020B 5.0 U 5.0 1.3 ug/L 1 6020B 5.0 U 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-007 Description: MW-11 Matrix: Aqueous Date Sampled:10/21/2021 0930 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1546 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Cobalt 7440-48-4 6020B 2.5 J 5.0 1.3 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-008 Description: MW-9 Matrix: Aqueous Date Sampled:10/21/2021 0945 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1550 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Barium Dissolved Cobalt Dissolved Vanadium 7440-39-3 6020B 770 5.0 1.3 ug/L 1 7440-48-4 6020B 8.0 5.0 1.3 ug/L 1 7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 23 ICP-MS Client:CDM Smith Laboratory ID:WJ21031-009 Description: MW-29 Matrix: Aqueous Date Sampled:10/21/2021 0950 Project Name: Feltonsville Landfill Date Received:10/22/2021 Project Number: Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 12/15/2021 1559 BNW 12/14/2021 1008 25471 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Cobalt 7440-48-4 Dissolved Vanadium 7440-62-2 6020B 2.5 J 5.0 1.3 ug/L 1 6020B 5.0 U 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 23 QC Summary Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ21031 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 23 ICP-MS - MB Sample ID: WQ25471-001 Matrix: Aqueous Batch: 25471 Prep Method: 3005A Analytical Method: 6020B Prep Date: 12/14/2021 1008 Parameter Result Q Dil LOQ DL Units Analysis Date Dissolved Arsenic 2.0 U 1 2.0 1.3 ug/L 12/15/2021 1501 Dissolved Barium 5.0 U 1 5.0 1.3 ug/L 12/15/2021 1501 Dissolved Cobalt 5.0 U 1 5.0 1.3 ug/L 12/15/2021 1501 Dissolved Vanadium 5.0 U 1 5.0 2.5 ug/L 12/15/2021 1501 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 23 QC Data for Lot Number: WJ21031 ICP-MS - LCS Sample ID: WQ25471-002 Matrix: Aqueous Batch: 25471 Prep Method: 3005A Analytical Method: 6020B Prep Date: 12/14/2021 1008 Spike Amount Result %Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Dissolved Arsenic 100 99 1 99 80-120 12/15/2021 1504 Dissolved Barium 100 98 1 98 80-120 12/15/2021 1504 Dissolved Cobalt 100 99 1 99 80-120 12/15/2021 1504 Dissolved Vanadium 100 100 1 104 80-120 12/15/2021 1504 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 23 QC Data for Lot Number: WJ21031 ICP-MS - MS Sample ID: WJ21031-001MS Matrix: Aqueous Batch: 25471 Prep Method: 3005A Analytical Method: 6020B Prep Date: 12/14/2021 1008 Sample Spike Amount Amount Result %Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Dissolved Vanadium 0.0 100 110 1 106 75-125 12/15/2021 1511 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 23 QC Data for Lot Number: WJ21031 ICP-MS - MSD Sample ID: WJ21031-001MD Matrix: Aqueous Batch: 25471 Prep Method: 3005A Analytical Method: 6020B Prep Date: 12/14/2021 1008 Sample Spike Amount Amount Result %Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Dissolved Vanadium 0.0 100 110 1 105 0.89 75-125 20 12/15/2021 1520 LOQ = Limit of Quantitation DL = Detection Limit U = Not detected at or above the LOD J = Estimated result < LOQ and > DL = RSD is out of criteria N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % + = RPD is out of criteria Note: Calculations are performed before rounding to avoid round -off errors in calculated results Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 17 of 23 QC Data for Lot Number: WJ21031 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 18 of 23 PACE ANALYTICAL SERVICES, LLC El kr'u -d _ y! L.- - EL L a a 'y L7 .7 « 0. LI ik. �. I Sig n. . p. {l...I. 1pId wi i ..' 'T G.14 .ti V45.L dGl ::...µ .•. .0.:'''.:.... . rq Z � .rt + — L paps F C5 m i' • ' T. �d 13 S � � to ? }• �r m sv r rs rr~ m es yT l it �!" 4ZY F•' L € A c 7 o' a re, w j L 9 n 'I r II X. 4•,i u q Y t ti J h � �� lI 1 it ¢ Fro Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 19 of 23 PACE ANALYTICAL SERVICES, LLC I''L I a... . ,III 4! e..4. G' q '25 H+JJp U 'tv LJ a� I' E di ..6+....17 f+tj is O 3 LT O 4 0 171 t427 [ V {� w r J i"I iy tx r'ti n 43 LS ti CJ W � p w rl 71 2 fi I i 5 a { m 7,,s Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 20 of 23 ISIII W -5� m hF Y F T N O I .m• 9 0 t' srJ 5 5. LL C R- PACE ANALYTICAL SERVICES, LLC 5.,mpLe-; Re�r.Pt Checklist (SRQ (MElll}1Wf tra) RCVI!Md'9{29,r2v20 f�s Area+} Ica Issu ing A117ha rity_ Para L:MV - WCOL Page 1 a F 1 Sample Receipt Checklist (SRQ Client: CL�v Srnirb C'.r)illtr Inspected lxu!datc: 1 DRW I IOED2021 Lack WaID26 to -v13�1 Mears ofree-eipt: J'are f'licni 1iPS , FtdFx Ll 0111N e'er; o ' i, %Vem custody seals pmsent art the oaolz.r? --- _. Yesl FiNold N,A 12. Ifcustad j seals tswru pwSznt, urcr,' they intact and unbroken? pH Strip 1D: ChlorineSIrip 1b: 2I-4 # -- �CStCS� Q :11L11'-W-. - riginal tKupemture upon rc4ciFt / DCJV(d (Ccr OcW) temperature upon receipt %SDiid Snap -Cup il); 3.3 13.3 aC 2.6 12.6 .rc Nis. iNA me NA OA ac Method, E( Temperature Blarsk Q4 nst J3ottles lit Clan lid: i R Guri CAA redian Pautw-: � r1G Method C' coolant= ❑, wet ice , Packs L Dry toe 0 Nol}r~ ❑PCs ©ltio 0 1,d - 6f Icm�crsdrrc aFsul} ccro[er exceeded 6_b°C etas Project Mar_age). NotEied? FLM was NLuLiIa:d "3y: 1�InarW 1 crikail "' face -La -race (circle one). -- Yes No hilt d_ €s the uommegvial courier's parking slip act -whorl to this farm"? --- — `rFcs No 5. %Vcre amper custndy pracedures (TCiinquishtxllrCCLAv-4) followed? toes No 6_ Were sample ills :isted on I:le COO _ 7_ Were sariple IDs Jisted on all saln le} containers? Yts No OYes Flo R_ :1Yaa collection dare & timc listed an the COC? © Yes i�D 9, 'Wn collectiou dare & time listed wi all sample cantai,mr;` _ I[}_ Did *II container label intonnation (6,d36Ltimc) agrccwith fhr.COO a Yes ❑ND ,� Yes Nu 11, Were testa tir he Pe­raalArd IiS(Cd u11 tine COIC2 12, INd sJI narnP:eg surnc in Lhc pTuprr curtl.ain=rs fur c--ch test and?vr in good condition (u41m,Dkan, lids oo, etc_]? 0 YeS LJN6 ,+ Yes No 13, WLtsaduqualc samplowlurao available? V Yes LiNco 14. Were ail samples received within A the hpldi-w lime. or 48 hours, whichever conies firs#'.' 15. Vlcrc Arty 9adrl kC run#intro rnis,l igjexcess (circle ore) samples Not listed an CM I es No �❑ 'cs n No ❑1 A lb, Fir VOA rind P,$K-175 samples, were bubbles presem ~�`paa-sire" (Y 'ou' Gr1rn in d]amcter) in ttriy of the VOA vials? _ 17. Were 3J1 DRLWmetakinutrknt sumplcs rc 6vcri at sk p14 vF<2? _ 21 YcLs N NA J Yc� No NA 1 S- Were ail c yaride samples received of a pH �- J 2 and a0Hidn wrnplm raceivud Lt a pH> 9? T 19. crc all appllc s 'H cywnl pkreno]fG?5,1�6083 ( 4.5tnerL) sarnp+lPs °eeo residual chloriaer' 20; Were c�etj, fem rk&5 ,-�quesrs (Le, IequC:tcd eilutions. MgAfSD dLgi liaLinns, etz.--� uarrOotly tranwrined frorn the COC Into the Commeat section In LAMS r j(Cy 1\1 71. Was thr r f�lr, niinl:cr Iixictl ini Lhe L:anlailkCr Lbd? If V-S. Ouoto A Sample Preservation (Must be CUM-Jlitcd fur LLnw �;Llu3pl r(s) ui cai=ectly preserved or with headspace,) Samplo(5) vl ....... I — were received iTic"rrrrtly preterv'ed Arid wu a adjusted 2ccordhigly in sarnplo rreciving with t mL of a Me odle: H2.$04, HNO3. HC:, MOE using, SR 4 tw,� Timc ofprescryation NA i If more Mwi one prem,.ralive is needed, please note in the cwtnent; below, Sam1+1n4s)11A were rcncivcd ivkh bubble8>6mm In diaiwetex_ SaMP1CSO) 1la _ wcau FLNWived wkli TRC> 0.5 1njVL (1f-419 is wo) and we&. adjusted nco* Jingly b sarpp�e - ceiviiig with sodium thiosu:fnic (Na2SzC3) willl �tea[y ID: rA SR barcode labels appli!d byl KDRW Date: JW11:0a: CANnnlCntS: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 21 of 23 PACE ANALYTICAL SERVICES, LLC t :..� :. ri T. .:4 tl - C 4 y .. .. .. Jl.•41 Cn r L L m j. lit 73 - C _ 'Al v A. L IMNI°� Al 'L F aj J jt c Ilj�t,l } ] ' .2 4 +.yk� E � LLI Y1I �V � Q a — a � � A a f lit I I rk � A J � 1 �I fyl rh Al may+ Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 22 of 23 x PACE ANALYTICAL SERVICES, LLC sarn*!,F1'46ptChecklist(SRC)(MEOMSC-15) l euisPd:9{29/2ND i Rrrtdl}?F 2+ Issuing .a„thorlty: Pace ENV - tilS CCL Page 1 of I Sample Receipt C'he-chltst (SP ) Client: CDMSr, vm C:uataeTn.Rlwrt,-d bvilatc: IRG2 r 1MM D2l Loth: wldCOdl M Free Lient UPS Pedf.SX Ott E I - V v'e Custody .;eels presert CM thr, cooler? Ll ti AD JF: usteri seats vi ere suit, 'Ne+e the in -,tt and wbrakcn7 pH S tr ipk T> 1; ='-s� CFiJ trine Strip ID: OrV"MI t�MPera1UM upartMceiptf Dorrived(Carractedj 1fr[tpeaature upon retelpt 28 `-+ 2.$ T NA � iw]A nC •14A i It Mietly [` Qr� 3-eswdl by: 1(r-z fa5olid Snar C.up ID: KA vmt r rattrre ]3lririk L—Mga=t Botties IR Gun ID: I R atn Cumc fom l� actor. 0 a(' WECIkod of eoolarlL 21 Wet leo © lee P+30ks L] le8 NUne C) Yes F] NO ❑{ NA 3• If tcrrrpentore OFfilty +rooJer &N(.ceded 6.0'C, was Prvjcct t�larl;tgcr Norl ri ed'� PM was �lg*fed l]y: phone J emaiI i face-Lu-face (ci-rle ottet- Yes l�lo Nit 4. Is the cotn erkial courier's paai ng sl ip iLwt, hed to th is farm ° qSL �Cea jV,VJ Na Ye s LJ No Yes W No IJ Yes ED'No ZI' NA Yes 11lri NA yQs . N,1 TI—NA ❑yes EIAla ONA El Yrs ❑T:u QNA S, Were prapr•r eustod prCCedures (i-kgliNuishcd,'neceiVg#) fallQFwcd7' 6. Wore salnpir IN Jist-ud on rile COC? "— ;. Wwra!jampte 11A lisredot1ail saanple coru$irrer-4? . WaL5 CD[]eotio� dute&- tirttrs [j&wri orr IbE'CQC? 9. 'Nag U41-1[ectivrt date Rc limp, listed on all sar?,lrle, Containers? 10. EAd all container label infotznatir,rl (ID, dale, iim'_) Ogee tvi(h the COO? I''. Were ! io perfrsrnled Ji3#p,d on the COC 12- ri;c all swrpiea =- ive in like puoper �Ontaii1, r3 I'vr oath flog[ Sndr'or irl good conditiolk (unbrukm. lids cka, m.)7 II Was adegmire saMP1E! volurIq availalrlu`? !d. We: 911 sw.rrip[rs 1'CCeivcd wit:1:1- V; the hOldirlg tuna ur48 hnur% w. FOlcvcr "'Osfirst? 15- Were arlw sallnpleS ContaJ, lt!M M iSSigl J!MCess (eircle One) 83mptes 1Nat lister{ ou co(C? _6. For VOA jT..Id RSK-173 samples, were bubbles present s "FUr-size" (ii"or 6mm in diunzicr) in Any cr= th a VOA via 1-.,? ] 7- V1 all DRDimetalelLtricnt ssmpics reerivad at 1 p`,y p{k 27 18- Wcro al Cyanide samrp.cs received at a �alnd su'L idc sam1 Ir.6 reueivecl ftta pH 97 M V4'e le all app Ica E NH3H�r ]-Q 4(nlderpheiloJG�5.1 608.3 (� O.� rnglL�5a,nples r x rrsidi al Ch1011i le? . Wrre Aent (i.c..rcquestcd dilrrti[Ezw [+ISIM b desi +rtatiolts,ct0,-.1 c3aoyectly trakt �bcd Iron' Th4 CDC' imo tik� ovmment sedior- in Lirw]s{2 1, Was thunto nrnnber- ristct t~n [etc o ilaincr lahf'l ;+ If es, Ql [ore # tnple Presetvatioa t'Mkrst be c, mplaLed COT ar}• Sarip[e(s) inrotrec_ly praservaxr or ++'i(h headspar, .) IL_wererece�volincaL-rz!Gdy prmcrv2d and wcrc adj-asted acwrdrnp MM:1lG receivin,- with NA mL of Circle ant: T�12SO4, HNO3, H(}l, N1tOH using SR * 10L rio of Irry r yat1411 HA. If more thwi aw preser-adve =s needed, picas[! narc in lih- Wry rnan l s lr 1pw. Szrnp]e(s) NA WUO reGrived W1111 bobbins >6 MrA in diarnazi. Salnples(s) a _ wcrc received •,V i fir T-RC > 0.5 mp q, (If fl 19 i s no ) and we —iv .AQUstcd actOrr il:gly in sample-, receiving wirh 9od;om d)I-MUUJfate (l`IM2%01) with Shealy la= t` SR bQMode labeJaappIind by: JRC2 i' J, lcr2lr2 [ 4ArR171rr1rJ: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 23 of 23 (� aceAna/ytical W LELAP CERTIFICATE NUMBER: 01955 DOD-ELAP ACCREDITATION NUMBER: 74960 ANALYTICAL RESULTS •:I Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 11/23/2021 Report Y 231303030 �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III Project WJ21026 Feltonsville Landfill Samples Collected 10/20/21 - 10/21/21 Deliver To Additional Recipients Cathy Dover NONE Pace Analytical Services South Carolina 106 Vantage Point Drive West Columbia, SC 29172 (803)791-9700 L*-- FJLA 1XMINg DOD ELAF Pace Gulf Coast Report#: 221103034 Page 1 of 18 Report#: 221103034 ace k k+ytUh Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) " Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 221103034 Pace Gulf Coast Report#: 221103034 Page 2 of 18 Report#: 221103034 aceAr�alYl�+l Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Certifications Certification Certification Number DOD ELAP 74960 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pace Gulf Coast Report#: 221103034 Page 3 of 18 Report#: 221103034 ace k k+ytUh Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Case Narrative Client: Pace Analytical Services South Carolina Report: 221103034 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. COC ANOMALIES COC Anomalies\Changes - Three samples for hydrogen were initially received but were not listed on the COC. The PM provided an additional COC for these samples since Hydrogen analysis is required. (Ruth Welsh(Do Not 11/02/2021 15:38) VOLATILES GAS CHROMATOGRAPHY In the AM20GAX Hydrogen analysis, samples 22110303410 (MW-8 (1-12) and 22110303411 (MW-9 (1-12)) were analyzed outside holding time. The samples were originally analyzed within holding time but were not reportable due to CCV failures. GENERAL CHEMISTRY In the AM23G VFA analysis, all samples were analyzed outside holding time. MISCELLANEOUS Sample 22110303415 (MW-13 (1-12)) was received but was not listed on the chain of custody. The client was contacted and authorized proceeding with analysis. Sample 22110303416 (MW-14 (1-12)) was received but was not listed on the chain of custody. The client was contacted and authorized proceeding with analysis. Sample 22110303417 (MW-12 (1-12)) was received but was not listed on the chain of custody. The client was contacted and authorized proceeding with analysis. Pace Gulf Coast Report#: 221103034 Page 4 of 18 ace k k+ytUh Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Summary Lab ID Client ID Matrix Collect Date Receive Date 22110303401 MW-8 Water 10/20/2109:00 10/29/21 10:58 22110303402 MW-9 Water 10/20/2109:30 10/29/21 10:58 22110303403 MW-10 Water 10/20/2110:00 10/29/21 10:58 22110303404 MW-19 Water 10/20/2110:30 10/29/21 10:58 22110303405 MW-29 Water 10/20/2111:00 10/29/21 10:58 22110303406 MW-13 Water 10/20/2113:30 10/29/21 10:58 22110303407 MW-14 Water 10/20/2114:30 10/29/21 10:58 22110303408 MW-12 Water 10/20/2115:30 10/29/21 10:58 22110303409 MW-2 Water 10/21/2112:20 10/29/21 10:58 22110303410 MW-8 (1-12) Bubble Strip 10/20/21 09:00 10/29/21 10:58 22110303411 MW-9 (1-12) Bubble Strip 10/20/21 09:30 10/29/21 10:58 22110303412 MW-10 (1-12) Bubble Strip 10/20/21 10:00 10/29/21 10:58 22110303413 MW-19 (1-12) Bubble Strip 10/20/21 10:30 10/29/21 10:58 22110303414 MW-29 (1-12) Bubble Strip 10/20/21 11:00 10/29/21 10:58 22110303415 MW-13 (1-12) Bubble Strip 10/21/21 11:15 10/29/21 10:58 22110303416 MW-14 (1-12) Bubble Strip 10/21/21 11:30 10/29/21 10:58 22110303417 MW-12 (1-12) Bubble Strip 10/21/21 11:50 10/29/21 10:58 Pace Gulf Coast Report#: 221103034 Page 5 of 18 k Report#: 221103034 ace k+ytUh Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable AM23G Lab ID Client ID Parameter Units Result Dil. %Moist 22110303401 MW-8 Acetic Acid mg/L 0.29J 1 NA 22110303401 MW-8 Formic Acid mg/L 5.2 1 NA 22110303401 MW-8 Hexanoic Acid mg/L 0.101 1 NA 22110303401 MW-8 Lactic Acid mg/L 0.098J 1 NA 22110303402 MW-9 Acetic Acid mg/L 0.27J 1 NA 22110303402 MW-9 Formic Acid mg/L 5.2 1 NA 22110303402 MW-9 Hexanoic Acid mg/L 0.14J 1 NA 22110303402 MW-9 Lactic Acid mg/L 0.41 J 1 NA 22110303403 MW-10 Acetic Acid mg/L 3.3J 10 NA 22110303403 MW-10 Formic Acid mg/L 51 10 NA 22110303404 MW-19 Acetic Acid mg/L 0.28J 1 NA 22110303404 MW-19 Formic Acid mg/L 5.3 1 NA 22110303404 MW-19 Hexanoic Acid mg/L 0.14J 1 NA 22110303404 MW-19 Lactic Acid mg/L 0.91 1 NA 22110303405 MW-29 Acetic Acid mg/L 0.29J 1 NA 22110303405 MW-29 Formic Acid mg/L 5.6 1 NA 22110303405 MW-29 Hexanoic Acid mg/L 0.12J 1 NA 22110303405 MW-29 Lactic Acid mg/L 0.58 1 NA 22110303406 MW-13 Acetic Acid mg/L 0.40J 1 NA 22110303406 MW-13 Formic Acid mg/L 5.4 1 NA 22110303406 MW-13 Hexanoic Acid mg/L 0.18J 1 NA 22110303406 MW-13 Lactic Acid mg/L 0.71 1 NA 22110303407 MW-14 Acetic Acid mg/L 0.36J 1 NA 22110303407 MW-14 Formic Acid mg/L 5.4 1 NA 22110303407 MW-14 Hexanoic Acid mg/L 0.15J 1 NA 22110303407 MW-14 Lactic Acid mg/L 0.14J 1 NA 22110303408 MW-12 Acetic Acid mg/L 3.7J 10 NA 22110303408 MW-12 Formic Acid mg/L 52 10 NA 22110303408 MW-12 Lactic Acid mg/L 6.2 10 NA 22110303409 MW-2 Acetic Acid mg/L 21 10 NA 22110303409 MW-2 Formic Acid mg/L 5.4 1 NA 22110303409 MW-2 Hexanoic Acid mg/L 0.13J 1 NA 22110303409 MW-2 Lactic Acid mg/L 17 10 NA 22110303409 MW-2 Propionic Acid mg/L 1.4 1 NA 22110303409 MW-2 Pyruvic Acid mg/L 0.55 1 NA AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22110303410 MW-8 (H2) Hydrogen nM 5.0 2 NA Pace Gulf Coast Report#: 221103034 Page 6 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Detect Summary (Continued) Results and Detection Limits are adjusted for dilution and moisture when applicable AM20GAX Lab ID Client ID Parameter Units Result Dil. %Moist 22110303411 MW-9 (H2) Hydrogen nM 7.0 2 NA 22110303412 MW-10 (H2) Hydrogen nM 1.3J 1 NA 22110303413 MW-19 (H2) Hydrogen nM 1 AJ 1 NA 22110303414 MW-29 (H2) Hydrogen nM 1 AJ 1 NA 22110303415 MW-13 (H2) Hydrogen nM 1.3J 1 NA 22110303416 MW-14 (H2) Hydrogen nM 2.3 1 NA 22110303417 MW-12 (H2) Hydrogen nM 1.6J 1 NA Pace Gulf Coast Report#: 221103034 Page 7 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Results MW-8 Collect Date 10/20/2021 09:00 Lab ID 22110303401 Receive Date 10/29/2021 10:58 Matrix Water 13G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2111:53 726862 SLL2 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.29J 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.0581.1 0.058 0.50 mg/L 64-18-6 Formic Acid 5.2 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.101 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.098J 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.0561.1 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.0531J 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L MW-9 Collect Date 10/20/2021 09:30 Lab ID 22110303402 Receive Date 10/29/2021 10:58 Matrix Water 13G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2112:28 726862 SLL2 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.27J 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 5.2 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.14J 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.41J 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.053U 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L Collect Date 10/20/2021 10:00 Lab ID 22110303403 MW-1 O Receive Date 10/29/2021 10:58 Matrix Water AM23G *Results And limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 11/18/2113:02 726862 SLL2 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 3.3J 1.2 5.0 mg/L 107-92-6 Butyric Acid 0.581.1 0.58 5.0 mg/L 64-18-6 Formic Acid 51 0.55 5.0 mg/L 142-62-1 Hexanoic Acid 0.581.1 0.58 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.561.1 0.56 5.0 mg/L Pace Gulf Coast Report#: 221103034 Page 8 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Results MW-1 O Collect Date 10/20/2021 10:00 Lab ID 22110303403 Receive Date 10/29/2021 10:58 Matrix Water AM23G (Continued) "Results And limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 11/18/2113:02 726862 SLL2 CAS# Parameter Result DL LOQ Units 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 50-21-5 Lactic Acid 0.531.1 0.53 5.0 mg/L 109-52-4 Pentanoic Acid 0.561J 0.56 5.0 mg/L 79-09-4 Propionic Acid 0.531J 0.53 5.0 mg/L 127-17-3 Pyruvic Acid 0.601.1 0.60 5.0 mg/L MW-19 Collect Date 10/20/2021 10:30 Lab ID 22110303404 Receive Date 10/29/2021 10:58 Matrix Water ?3G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2113:37 726862 SLL2 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.28J 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 5.3 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.14J 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.91 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.053U 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L MW-29 Collect Date 10/20/2021 11:00 Lab ID 22110303405 7 Receive Date 10/29/2021 10:58 Matrix Water 13G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2114:11 726862 SLL2 CAS# Parameter 64-19-7 Acetic Acid 107-92-6 Butyric Acid 64-18-6 Formic Acid 142-62-1 Hexanoic Acid 646-07-1 i-Hexanoic Acid 503-74-2 i-Pentanoic Acid 50-21-5 Lactic Acid 109-52-4 Pentanoic Acid 79-09-4 Propionic Acid Result DL LOQ Units 0.29J 0.12 0.50 mg/L 0.058U 0.058 0.50 mg/L 5.6 0.055 0.50 mg/L 0.12J 0.058 0.50 mg/L 0.056U 0.056 0.50 mg/L 0.061 U 0.061 0.50 mg/L 0.58 0.053 0.50 mg/L 0.056U 0.056 0.50 mg/L 0.053U 0.053 0.50 mg/L Pace Gulf Coast Report#: 221103034 Page 9 of 18 �7 r..._.,,,N1ka< Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Results MW-29 Collect Date 10/20/2021 11:00 Lab ID 22110303405 Receive Date 10/29/2021 10:58 Matrix Water ?3G (Continued) Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2114:11 726862 SLL2 CAS# Parameter Result DL LOQ Units 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L MW-1 3 Collect Date 10/20/2021 13:30 Lab ID 22110303406 Receive Date 10/29/2021 10:58 Matrix Water 13G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2114:46 726862 SLL2 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.40J 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 5.4 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.18J 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.71 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.053U 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L MW-14 Collect Date 10/20/2021 14:30 Lab ID 22110303407 Receive Date 10/29/2021 10:58 Matrix Water ?3G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/18/2115:21 726862 SLL2 CAS# Parameter 64-19-7 Acetic Acid 107-92-6 Butyric Acid 64-18-6 Formic Acid 142-62-1 Hexanoic Acid 646-07-1 i-Hexanoic Acid 503-74-2 i-Pentanoic Acid 50-21-5 Lactic Acid 109-52-4 Pentanoic Acid 79-09-4 Propionic Acid 127-17-3 Pyruvic Acid Result DL LOQ Units 0.36J 0.12 0.50 mg/L 0.058U 0.058 0.50 mg/L 5.4 0.055 0.50 mg/L 0.151 0.058 0.50 mg/L 0.056U 0.056 0.50 mg/L 0.061 U 0.061 0.50 mg/L 0.14J 0.053 0.50 mg/L 0.056U 0.056 0.50 mg/L 0.053U 0.053 0.50 mg/L 0.060U 0.060 0.50 mg/L Pace Gulf Coast Report#: 221103034 Page 10 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Results MW-12 Collect Date 10/20/2021 15:30 Lab ID 22110303408 Receive Date 10/29/2021 10:58 Matrix Water AM23G *Results And limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 11/18/2115:55 726862 SLL2 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 3.7J 1.2 5.0 mg/L 107-92-6 Butyric Acid 0.581.1 0.58 5.0 mg/L 64-18-6 Formic Acid 52 0.55 5.0 mg/L 142-62-1 Hexanoic Acid 0.581J 0.58 5.0 mg/L 646-07-1 i-Hexanoic Acid 0.56U 0.56 5.0 mg/L 503-74-2 i-Pentanoic Acid 0.61 U 0.61 5.0 mg/L 50-21-5 Lactic Acid 6.2 0.53 5.0 mg/L 109-52-4 Pentanoic Acid 0.561.1 0.56 5.0 mg/L 79-09-4 Propionic Acid 0.531J 0.53 5.0 mg/L 127-17-3 Pyruvic Acid 0.60U 0.60 5.0 mg/L Collect Date 10/21/2021 12:20 Lab ID 22110303409 MW-2 Receive Date 10/29/2021 10:58 Matrix Water 13G Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/19/2111:12 727035 SLL2 CAS# Parameter Result DL LOQ Units 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 5.4 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.13J 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.0561J 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 1.4 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.55 0.060 0.50 mg/L AM23G *Results And limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 10 11/19/2119:13 727354 SLL2 CAS# Parameter 64-19-7 Acetic Acid 50-21-5 Lactic Acid Result DL LOQ Units 21 1.2 5.0 mg/L 17 0.53 5.0 mg/L Pace Gulf Coast Report#: 221103034 Page 11 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Results Collect Date 10/20/2021 09:00 Lab ID 22110303410 MW-� (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip AM20GAX *Results And limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 2 11/08/2110:06 726054 AWE CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 5.0 0.98 3.8 nM Collect Date 10/20/2021 09:30 Lab ID 22110303411 MW-9 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip AM20GAX "Results And limits are adjusted for dilution. Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 2 11/08/2110:18 726054 AWE CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 7.0 0.98 3.8 nM Collect Date 10/20/2021 10:00 Lab ID 22110303412 MW-10 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/03/2110:37 725460 AWE CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 1.3J 0.49 1.9 nM Collect Date 10/20/2021 10:30 Lab ID 22110303413 MW-19 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/03/2110:40 725460 AWE CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 1.4J 0.49 1.9 n M Pace Gulf Coast Report#: 221103034 Page 12 of 18 ..-] Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 Sample Results Collect Date 10/20/2021 11:00 Lab ID 22110303414 MW-29 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/03/2110:53 725460 AWE CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 1.4.1 0.49 1.9 nM Collect Date 10/21/2021 11:15 Lab ID 22110303415 MW-13 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/03/2111:06 725460 AWE CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 1.3J 0.49 1.9 nM Collect Date 10/21/2021 11:30 Lab ID 22110303416 MW-14 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/03/2111:19 725460 AWE CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 2.3 0.49 1.9 nM Collect Date 10/21/2021 11:50 Lab ID 22110303417 MW-12 (H2) Receive Date 10/29/2021 10:58 Matrix Bubble Strip GAX Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture NA NA NA 1 11/03/2111:32 725460 AWE CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 1.6,1 0.49 1.9 nM Pace Gulf Coast Report#: 221103034 Page 13 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 General Chemistry QC Summary Analytical Batch Client ID MB726862 LCS726862 LCSD726862 726862 Lab ID 2273096 2273097 2273098 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 11/17/21 17:16 11/17/21 16:42 11/18/21 10:09 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Acetic Acid 64-19-7 0.12U 0.12 2.0 2.2 108 70 - 130 2.0 2.2 112 4 20 Butyric Acid 107-92-6 0.058U 0.058 2.0 2.5 124 70 - 130 2.0 2.4 122 2 20 Formic Acid 64-18-6 0.055U 0.055 2.0 2.2 108 70 - 130 2.0 2.1 106 2 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.4 119 70 - 130 2.0 2.2 108 9 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.4 120 70 - 130 2.0 2.4 120 0 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.0 100 70 - 130 2.0 2.0 101 1 20 Lactic Acid 50-21-5 0.053U 0.053 2.0 2.3 115 70 - 130 2.0 2.4 120 5 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.1 106 70 - 130 2.0 1.9 97 9 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.3 115 70 - 130 2.0 2.4 121 5 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 2.3 114 70 - 130 2.0 2.2 112 2 20 Analytical Batch Client ID MB727035 LCS727035 LCSD727035 727035 Lab ID 2274006 2274007 2274008 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 11/19/21 05:26 11/19/21 04:52 11/19/21 11:47 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Butyric Acid 107-92-6 0.058U 0.058 2.0 2.4 118 70 - 130 2.0 2.2 109 8 20 Formic Acid 64-18-6 0.055U 0.055 2.0 2.0 98 70 - 130 2.0 1.9 94 3 20 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 2.0 99 70 - 130 2.0 1.8 93 7 20 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.2 112 70 - 130 2.0 2.2 112 1 20 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.2 108 70 - 130 2.0 2.2 111 2 20 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 2.0 102 70 - 130 2.0 2.0 101 1 20 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.2 109 70 - 130 2.0 2.2 112 2 20 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 2.2 112 70 - 130 2.0 2.3 116 4 20 Analytical Batch Client ID MB727354 LCS727354 LCSD727354 727354 Lab ID 2276151 2276152 2276153 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 11/19/21 18:04 11/19/21 17:29 11/19/21 19:48 Matrix Water Water Water AM23G Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Acetic Acid 64-19-7 0.12U 0.12 2.0 2.0 102 70 - 130 2.0 2.1 105 3 20 Lactic Acid 50-21-5 0.053U 0.053 2.0 2.2 110 70 - 130 2.0 2.2 108 2 20 Pace Gulf Coast Report#: 221103034 Page 14 of 18 Report#: 221103034 Project ID: WJ21026 Feltonsville Landfill Report Date: 11/23/2021 General Chromatography QC Summary Analytical Batch Client ID MB725460 LCS725460 LCSD725460 725460 Lab ID 2265033 2265034 2265035 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 11/03/21 09:59 11/03/21 09:33 11/03/21 09:45 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Hydrogen 1333-74-0 0.49U 0.49 12 15 126 70 - 130 12 14 119 5 20 Analytical Batch Client ID MB726054 LCS726054 LCSD726054 726054 Lab ID 2268514 2268515 2268516 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 11/08/21 09:53 11/08/21 09:29 11/08/21 09:41 Matrix Bubble Strip Bubble Strip Bubble Strip AM20GAX Units nM Spike Result %R Control Spike Result %R RPD RPD Result DLI Added Limits%R 1 Added Limit Hydrogen 1333-74-0 0.49U 1 0.491 121 13 11071 70 - 130 1 121 1311121 4 1 20 Pace Gulf Coast Report#: 221103034 Page 15 of 18 clie11t IQ: Shealy Envir - Paco Anafytical Services south Carolina Pace Analytical Services, LLC. sac: 221103034 Chain of Custody 106 Vantage Point drive ��aneAnalXical Record West Columbia, South Carolina 29172 PM. RWe Telephone No. (803) 791-9700 Fax No. (803) 791 www.kacelabs.com Client Report to Contact Telephone No. 1 E-mail ouote No. Pace Analytical services -West Columbia Calherina S. Dover cathy-dover0pacelabs.cvm Address Sampler's Signature Analysis (Attach list it more space is needed) Page 106 Vantage Point Drive City Stale Zip Code x 1 of 1 Lot p Bar Code West Columbia 8C 29172 Printed Name (lab use only) Project Name Eeltonsville Landfill Project Number P.D. ND. No of Containers by Matrix Preservative Type P � a` `7 y Sample ID! Description Collection Collection = o m "' z Y Y {Con[almm Ior each sample may he combined on one line) Date(s) Time cJ rp q N O -Z o Remarks 1 Cooler I.D. {military} ¢ ¢ _ ]>lot MW-8 10/20/2021 0900 G X X X X X WJ21026-001 MW-g 10/20/2021 0930 G X X X X X a WJ21026-002 MW-10 10/20/2021 f000 G X X X X X 3 WJ21026.003 MW-19 10/20/2021 1030 G X X X X X VVJ21026-004 MW-29 10/20/2021 1100 G X X X X X WJ21026-005 j MW 13 10/20/2021 1330 G X X X [A WJ21026-006 MW-14 10/20/2021 1430 G X X X 7 WJ21026-008 MW-12 10/20/2021 1530 G X X X WJ21026-009 MW-2 10/21/2021 1220 G X X X WJ21026-030 TWO Around Tima Required (Prior lab approval required for expedited TAT) sample Dlsposal Passible Hazard Identification (List any known hazards in the remarks) QG Requirements ❑ Standard ❑ Rush (P ease specify) 7.10 8USINESS DAYS ❑ Relurn to Client Disposal by Lab ❑ Non Hazardous ❑ Flammable ❑ S tin lr rani � SDS prov dad ❑ V d wwn r 12J1- Ralinquished by Date Time 0� 1. Received by Date Time 2. Relinquished by f Dal Timp 2. Racei by ate Tim L�, 3. Relinquished by Date Time 3, Received Date Time 4. Relinquished by Date Time 4. Laboratory Received by Date Time Note: All samples are retained for four weeks from LAB USE ONLY Receipt Temp, Temp. Blank race€ t unless other arran ements are made Received on Ice (Check) ❑ Y 0 N ❑ Ice Pack o C ❑ Y 1 ❑N l��3 3�4� G7f�U Pace Gulf Coast Report#: 221103034 Page 16 of 18 ��anqAnalytical" Pace Analytical Services, LLC. Chain of Custody 106 Vantage Point Drive Record West Columbia, South Carolina 29172 Telephone No. (803) 791-9700 Fax No. (803) 791-9111 www.pacelabs.com Number Client Pace Analytical Services -West Columbia Report to Contact Catherine S. Dover Telephone No. / E-mail cathy.dover@pacelabs.com Quote No. Address 106 Vantage Point Drive Samplers Signature x Printed Name Analysis (Attach list if more space is needed) Page 1 of 1 City West Columbia State ISC Zip Code 29172 Q UL o = Lot # Bar Code (lab use only) Project Name Feltonsville Landfill Project Number P.O. No. o �? o U Matrix No of Containers by Preservative Type Sample ID / Description (Containers for each sample may be combined on one line) Collection Date(S) Collection Time (military) N o ¢ o (n c o Z Q C O N _ r = = = Om Z Y co 0 Y m Remarks /Cooler I.D. MW-12 10/21/2021 1150 G X X X WJ21026-033 MW-13 10/21/2021 1115 G X X X WJ21026-031 MW-14 10/21/2021 1130 G X X X WJ21026-032 Turn Around Time Required (Prior lab approval required for expedited TAT) ❑J Standard ❑ Rush (Please Specify) 7-10 BUSINESS DAYS Sample Disposal ❑ Return to Client ❑� Disposal by Lab Possible Hazard Identification (List any known hazards in the remarks) ❑ Non -Hazardous ❑ Flammable ❑ Skin Irritant ❑ SIDS provided ❑ Unknown QC Requirements 1. Relinquished by Date Time 1. Received by Date Time 2. Relinquished by Date Time 2. Received by Date Time 3. Relinquished by Date Time 3. Received by Date Time 4. Relinquished by Date Time 4. Laboratory Received by Date Time Note: All samples are retained for four weeks from receipt unless other arrangements are made LAB USE ONLY Received on Ice (Check) ❑ Y ❑ IN ❑ Ice Pack Receipt Temp. ° C Temp. Blank ❑ Y / ❑ N Pace Gulf Coast Report#: 221103034 Page 17 of 18 /.5navivfica' SAMPLE RECEIVING CHECKLIST IIIII�IIIII III SAMPLE DELIVERY GROUP 221103034 CHECKLIST YES NO Client PM RWe Transport Method Samples received with proper thermal preservation? *❑ ❑ Shealy Envir - Pace Analytical FEDDC Services South Carolina Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? *❑ *❑ ❑ ❑ Profile Number Received By 290722 N/bOune, DDdie K All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? *❑ ❑ ❑ I❑ Line Item(s) Receive Date(s) 1 - V FAs 10/29/21 2- Hydrogen Preservative added to any containers? ❑ sd If received, was headspace for VOC water containers < 6mm? *❑ ❑ Samples collected in containers provided by Pace Gulf Coast? 0 ❑ COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Thermometer ID: E34 Temp °C Broken Container (Container B - Unassigned): None 22110303404 - MNL19 166334660760 2.3 Extra Sarrple - Not Listed on OOC 22110303415 - NW13 (H2) 22110303416 - WV-14 (Fi2) 22110303417- MNL12 (Fi2) NOTES Revision 1.6 Page 1 of 1 Pace Gulf Coast Report#: 221103034 Page 18 of 18