1302_Cabarrus_MSWLF_Units2&3_Nov21GW_FID1636808_20220119

Cabarrus County Sanitary
Landfill -Units 2 and 3
Semi -Annual Sampling Report
Facility Permit # 1302-MSWLF-
CDLF-1998
(November 2021 Sampling Event)
1792 �
u
Prepared January 2022

pENR USE MIYY op -par Report DEloolmnic Data- Email CD (data baded: Yes / No) Doc/Event#
C DENR Environmental Monitoring
Division of Waste Management- Solid Waste Reoortina Form
Notiee: This form and any information attached to it are •Public Remade as defined in NO General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 1326).
Instructions:
• Prepare one form for each individually monitored unit.
• Pieass type or print agibly.
• Attach a notification table with values that attain or exceed NO 2L groundwater standards or NO 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. normally occurring, oft -site source, pre-existing
condition, etc.).
Attach a rrotification table of any groundwater or surface water values that equal a exceed the reporting limits.
• Attach a notification table of any methane gas values Nat attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 136 .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable ro: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NO 276991646.
Solid Waste Monitorina Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner)
Consultant -CDM Smith
Confect for questions about data formatting. Include data preparees more, telephone number and E•amil address:
Name: Mathew F. Colon Phone: [phone]
Email: cobnemfCalcdmsmilh.com
NO Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address. Facility Permit N (.0500 or.1600) October 20-24, 2006)
a tl 3�s County Landrgl Units 2
1ConirnQ North PotatoRoad
28025
1302-MSWLF-
.0500 and .1600
November 15-19, 2021
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring Q Detection Monitoring © Assessment Monitoring Q Come.live Action
T�Other(specify)of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells © Methane gas monitoring data
Groundwater monitoring data from private water supply wells X❑ Commove action data (specify) MNA Data
Leachate monitoring data
x Surface water monitoring data ❑
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notificetion of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NO 2L groundwater standard, NO 2B surface water standard or NO Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the beat of my knowledge, the information reported and statements made on this data submittal and attachments are free and comeet
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. 1 am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Mathew F. Colon Consultant [phone]
Facil' res ta' NamelPrint) Title (Area Code) Telephone NuM. gF'
C•�
Affix NO Ur,°4' x gist Seal
1/19/2022 iC. % x�
Signature Date c`_o
5400 Glenwood Avenue, Suite 400, Raleigh, North Carolina 27612
Facility Representative Address
F6412
NO PE Finn License Number if applicable effective May 1, 2009)
Revised
812009

Smith
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
fax: [phone]
January 19, 2022
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: November 2021 Semi -Annual Sampling Report
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Dear Ms. Drummond:
CDM Smith Inc. (CDM Smith), on behalf of Cabarrus County, is submitting an electronic copy of the
November 2021 semi-annual sampling event report. This letter report presents the results of the
recently completed sampling at Units 2 and 3 of the Cabarrus County Landfill and constitutes the second
semi-annual sampling event for 2021.
The approved groundwater monitoring network consists of the following wells: MW-1, -3, -3 Deep, -A,
-B, -C, -D, -E Rep, -E Deep, -F, -G, -H, -H Deep, -I, -J, -K, -L, -L Deep, -M, -X, CD-4 Rep, assessment wells
AMW-1s, -1d, -2s, and -2d, and background wells CD -Is and CD-1d. Surface water sample locations
include SW-1 and -2, which also monitor the Unit 1 Landfill. Assessment wells AMW-1s, -1d, -2s, and -2d
were added to the groundwater monitoring network in October 2009 as part of the Corrective Action
Plan (CAP) implementation. CD-4 Rep was installed in January 2009 as part of the proposed Phase I C&D
Landfill expansion. Assessment wells CD-4, -5, and -6 were added to the groundwater monitoring
network in September 2006 during the Phase I C&D Landfill expansion. Assessment wells CD-4 and -5
were abandoned in July 2010 in preparation of the Phase 2 C&D Landfill expansion. Assessment well
CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Field activities,
sampling and landfill gas screening results, and an evaluation of corrective action activities are discussed
below.
Field Activities
Groundwater samples from Units 2 and 3 of the Cabarrus County Landfill were collected on November
15-19, 2021, except for monitoring wells MW-3 Deep, -L Deep, and -M, which are sampled annually in
the spring. Surface water sample locations SW-1 and -2 were dry during the November 2021 sampling
event. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory
Of
WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES

Smith
Ms. Jaclynne Drummond
January 19, 2022
Page 2
decontaminated TeflonTm bailers. Monitoring well and surface water locations for Units 2 and 3 are
provided on Figure 1. Construction details for each monitoring well are summarized in Table 1.
Groundwater elevations were measured at each well on November 15, 2021, prior to sampling and are
presented in Table 2. These groundwater elevations were used to construct potentiometric contours for
this sampling event and are presented on Figure 1. The groundwater elevations and potentiometric
contours were used to estimate groundwater velocities at each well, which are presented in Table 3.
After depth to groundwater was measured, three well volumes of water were removed from each well
prior to sampling to provide fresh formation water within the well water column. Low -flow sampling
techniques were used to purge and sample wells used to monitor natural attenuation. Each well volume
was measured for pH, conductivity, turbidity, temperature, dissolved oxygen (DO), and oxidation-
reduction potential (ORP) using a YSI-556 multi -parameter water quality meter and a HANNA HI 98703
turbidity meter. Wells with elevated turbidity were allowed to settle prior to sampling. The water quality
parameters at the time of sampling are presented in Table 4.
Sampling Results
Pace Analytical Services, Inc., located in West Columbia, South Carolina, analyzed the groundwater and
surface water samples for North Carolina Appendix I volatile organic compounds (VOCs) and metals. In a
letter dated May 28, 2019, the Solid Waste Section (SWS) requested that all groundwater and surface
water samples collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On July 1, 2019,
the SWS approved the removal of 1,4-dioxane from the sampling program for all wells, with the
exceptions of MW-1, -B, -E Rep, -E Deep, -F, -G, -H, -M, -X, SW-1 and -2, due to two consecutive non -
detect events (May 2019 and November 2019). Samples were collected from the wells requiring the
1,4-dioxane analysis during the November 2021 sampling event. Samples results are provided below.
Additional groundwater samples were collected from the background well CD-1s; monitoring wells
MW-A, -E Rep, -E Deep, -L, and -3; and assessment wells AMW-1s, -1d, -2s, and -2d to evaluate the
effectiveness of natural attenuation and the Phase II injection event and are discussed in the Corrective
Action Evaluation section of this letter report. Samples were analyzed for monitored natural attenuation
parameters (i.e., alkalinity, biochemical oxygen demand, chemical oxygen demand (COD), chloride,
dissolved hydrogen, dissolved gases (i.e., methane, ethane, ethene, carbon dioxide), volatile fatty acids
(i.e., acetic, butyric, lactic, propionic, and pyruvic), ferrous iron, nitrate, sulfate, sulfide, and total organic
carbon). Note that ferrous iron was analyzed in the field using a Hach® test kit due to the short hold
time of 15 minutes.
The analytical results were reported to the laboratory specific method detection limit (MDL) and are
quantifiable at or below the method reporting limit (MRL). All monitoring wells for Units 2 and 3 with
detections of analytes above the MDL but below the MRL were qualified as estimated or "J" flags. In
samples collected from MW-A, a detection of methane had an "H" flag, indicating that the analyte was
analyzed outside of hold time. In MW-C, -D, -E Rep, -E Deep, and -G, detections of chloroethane also had
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Ms. Jaclynne Drummond
January 19, 2022
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"H" flags. Detections of methane had "D" flags in samples collected from MW-A and -E Deep, indicating
that the analyte was analyzed at a dilution greater than one. In MW-E Rep, -E Deep, and -G, detections
of barium also had "D" flags. Additionally, in MW-E Deep, detections of chloride and nitrate also had "D"
flags. In samples collected from MW-1, -X, and CD-4 Rep, detections of copper had "B" flags, indicating
that the analyte was detected in the method blank.
The following list indicates the analytes detected above the MRL at each sampling location. No "J" flag
or general chemistry detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202
(NC 2L) Groundwater Standard or Interim Maximum Allowable Concentration (IMAC). A complete
summary of all detected and estimated concentrations from the May 2011 through the November 2021
sampling events is presented in Table 5. Laboratory data reports are provided in Appendix A.
CD-1s (Background)
Metals: Barium, Zinc
Volatile Organic Compounds: None Detected
CD-1d (Background)
Metals: Barium
Volatile Organic Compounds: None Detected
CD-4 Rep
Metals: Barium, Cobalt, Vanadium
Volatile Organic Compounds: 1,1-Dichloroethane
AMW-Is
Metals: Antimony, Barium Beryllium
Volatile Organic Compounds: None Detected
AMW-1 d
Metals: Antimony, Barium, Cobalt, Nickel
Volatile Organic Compounds: Benzene, Chloroethane, 1,1-Dichloroethane, cis-1,2-Dichloroethene,
Vinyl Chloride
AMW-2s
Metals: Barium, Beryllium
Volatile Organic Compounds: 1,1-Dichloroethane, cis-1,2-Dichloroethene, Tetrachloroethene (PCE),
Trichloroethene (TCE)
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Ms. Jaclynne Drummond
January 19, 2022
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AMW-2d
Metals: Barium
Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane, 1,1-Dichloroethene,
cis- 1,2-Dichloroethene, PCE, TCE
MW-1
Metals: Barium, Cobalt, Nickel
Volatile Organic Compounds: 1,1-Dichloroethane, cis-1,2-Dichloroethene, 1,4-Dioxane
MW-3
Metals: Barium, Zinc
Volatile Organic Compounds: 1,1-Dichloroethane, 1,2-Dichloroethene, cis-1,2-Dichloroethene, PCE,
TCE, Trichlorofluoromethane
MW-3 Deep
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
MW-A
Metals: Barium Cobalt, Nickel
Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene,
1,1-Dichloethane, cis-1,2-Dichloroethene, 1,2-Dichloropropane,
Methylene Chloride, PCE, TCE, Vinyl Chloride
MW-8
Metals: Barium, Cobalt
Volatile Organic Compounds: 1,4-Dioxane
MW-C
Metals: Barium, Cobalt, Nickel
Volatile Organic Compounds: Benzene, Chloroethane, 1,4-Dichlorobenzene, 1,1-Dichloroethane,
cis-1,2-Dichloroethene, Vinyl Chloride
MW-D
Metals: Barium, Cobalt, Nickel
Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene, cis- 1,2-Dichloroethene,
TCE, Vinyl Chloride
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Ms. Jaclynne Drummond
January 19, 2022
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MW-E Rep
Metals: Barium, Cobalt, Nickel
Volatile Organic Compounds: Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene,
1,1-Dichloroethane, 1,2-Dichloroethane, cis-1,2-Dichloroethene,
1,2-Dichloropropane, 1,4-Dioxane, Vinyl Chloride
MW-E Deep
Metals: Arsenic, Barium, Cobalt, Lead, Nickel
Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene,
1,1-Dichloroethane, cis-1,2-Dichloroethene, 1,2-Dichloropropane,
1,4-Dioxane, Vinyl Chloride
MW-F
Metals: Barium, Nickel
Volatile Organic Compounds: 1,4-Dioxane
MW-G
Metals: Arsenic, Barium, Cobalt, Nickel, Selenium
Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene,
1,1-Dichloroethane, 1,4-Dioxane, Vinyl Chloride
MW-H
Metals: Barium
Volatile Organic Compounds: None Detected
MW-H Deep
Metals: Barium
Volatile Organic Compounds: None Detected
MW-1
Metals: Barium
Volatile Organic Compounds: 1,1-Dichloeothane, cis-1,2-Dichloroethene, PCE, TCE
MW-J
Metals: Barium
Volatile Organic Compounds: None Detected
MW-K
Metals: Barium
Volatile Organic Compounds: None Detected
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Ms. Jaclynne Drummond
January 19, 2022
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MW-L
Metals: Barium
Volatile Organic Compounds: None Detected
MW-L Deep
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
MW-M
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
MW-X
Metals: Antimony, Barium
Volatile Organic Compounds: None Detected
SW-1
Metals: Dry
Volatile Organic Compounds: Dry
SW-2
Metals: Dry
Volatile Organic Compounds: Dry
"J" flags were not included in the previous list, but several locations had "J" flag detections that
exceeded the standards. These constituents along with their location are listed below.
Antimony: MW-E Deep
Cobalt: MW-F
Vanadium: CD-1s, -1d, AMW-1s, MW-I, -K, and -L
1,2-Dichloroethane: MW-A
A trip and equipment blank, and a duplicate sample were analyzed for quality control. No analytes were
detected in the trip blank above the MDLs. An estimated detection of chromium and a detection of
copper with a "B" flag were detected in the equipment blank below their respective NC 2L Groundwater
Standards. The duplicate sample, identified as Dup, was collected from MW-H Deep, and had similar
analyte concentrations as those detected in MW-H Deep, except for an estimated detection of nickel in
the parent sample below its NC 2L Groundwater Standard.
Metals detected above the standards are likely natural occurring based on concentrations in the
background monitoring wells or are from elevated turbidity at the time of sample collection. Table 6
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Ms. Jaclynne Drummond
January 19, 2022
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presents a summary of all analytes detected during the November 2021 sampling event that exceeded
the NC 2L Groundwater Standards or IMACs.
Corrective Action Evaluation
In December 2008, CDM Smith, on behalf of the County, submitted an Assessment of Corrective
Measures Report to the SWS for the closed landfill Units 2 and 3 in accordance with North Carolina Solid
Waste Management Rule 15 NCAC 13B .1635. Monitored natural attenuation and institutional controls
paired with in situ remediation by enhanced bioremediation was selected as the remedy to address
groundwater contamination by select VOCs at the facility. In situ remediation efforts were to be focused
on the bedrock contamination near monitoring wells MW-E Rep and -E Deep. Groundwater
contamination in the area of MW-E Deep is caused by migration of leachate from the closed landfill
Units 2 and 3 downward into the shallow fractured bedrock, thereby allowing low-level VOCs to migrate
into this area prior to being attenuated below NC 2L Groundwater Standards.
Following approval of the CAP in September 2009 and the Phase I injection permit, six injection wells
were installed upgradient of the MW-E cluster in October 2009 as shown on Figure 2. A 3% solution of
potable water and EOS® 450, which is an emulsion of soybean oil and water, was injected
simultaneously into the injection wells from November 2-6, 2009. A total of 38,100 gallons of the
solution were injected with each well receiving approximately 6,350 gallons.
The initial injection of EOS®450 successfully degraded PCE and TCE to daughter products in the injection
area and neither compound has been detected above the NC 2L Groundwater Standards in MW-E Deep
since the Phase I injection in November 2009. It was assumed that the EOS® 450 would be viable for a
period of 3 to 5 years. However, samples collected from the MW-E cluster and wells downgradient of
the injection area during the November 2013 sampling event showed that groundwater contaminant
concentrations had increased and levels exceeding the applicable NC 2L Groundwater Standards had
been detected in monitoring wells near the property line. Due to the increasing downgradient
contaminant concentrations and NC 2L Groundwater Standard exceedances near the property line, the
groundwater conditions were re-evaluated in accordance with the CAP and a Phase 11 injection was
implemented.
In order to assess the biological conditions in the injection area prior to initiating the Phase II injection,
groundwater samples were collected from MW-E Rep, -E Deep, AMW-1s, -1d, -2s, and -2d in January
2014 and analyzed for Deholococcoides spp (DHC), the bacteria responsible for degrading the
chlorinated ethene species of VOCs. The specific genes of the bacteria that promote dechlorination were
also analyzed. Analytical results for the DHC analyses are summarized in Table 7 and show that a
sufficient population exists at monitoring wells MW-E, -E Deep, and assessment monitoring well
AMW-2s for reductive dechlorination by enhanced anaerobic bioremediation. DHC was detected at low
concentrations in assessment monitoring wells AMW-1d and -2d and was not detected at AMW-1s. The
absence of DHC at AMW-1s is likely associated with relatively low VOC concentrations.
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Ms. Jaclynne Drummond
January 19, 2022
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Following approval of the injection permit in January 2014, the Phase II injection was completed from
February 10-18, 2014, using potable water and a 10% solution of 60% SRS®-FR large droplet emulsified
vegetable oil substrate. SRS®-FR is specifically designed for use in fractured bedrock environments and
is a mixture of 60% emulsified vegetable oil, 20% water, 5-15% of proprietary emulsifiers and nutrients,
and 5% sodium lactate. The nutrient component of SRS®-FR further enhances the microbial population
growth. A total of 9,966 gallons of the solution were injected during the Phase II event with each well
receiving approximately 1,661 gallons.
To monitor the progress of the Phase II injection and the geochemical and biological response of the
aquifer, groundwater samples were collected quarterly from monitoring wells MW-E Rep and -E Deep
and assessment wells AMW-1s, -1d, -2s, and -2d. The first and third quarterly sampling events were
completed in conjunction with the May and November 2014 semi-annual sampling events respectively.
The second quarterly sampling event was completed in August 2014 and the fourth quarterly sampling
event was completed in March 2015. A 15-month post -injection sampling event was completed in May
2015.
Water quality measurements of pH, temperature, ORP, DO, conductivity, turbidity, and ferrous iron
were collected during each sampling event. In addition, the quarterly samples were submitted to an
analytical laboratory for analysis of nitrate, sulfate, alkalinity, chloride, COD, VOCs, dissolved gasses, and
metabolic acids. North Carolina Appendix I metals were collected during events that corresponded with
the semi-annual sampling program.
Additional samples were collected during the fourth quarterly sampling event (March 2015) from
monitoring wells MW-E Rep and -E Deep and assessment wells AMW-1s, -1d, -2s, and -2d and analyzed
for DHC to assess the biological conditions in the injection area after initiating the Phase II injection. A
sufficient population of DHC existed at assessment monitoring well AMW-1d for reductive
dechlorination by enhanced anaerobic bioremediation and DHC was detected at low concentrations in
monitoring well MW-E Deep. Detections of DHC in AMW-1d indicated a healthy population of DHC in
the primary bedrock treatment zone surrounding the injection wells. DHC detections in MW-E Deep was
an indication that active treatment in bedrock was also occurring downgradient. DHC was not detected
at MW-E Rep, AMW-1s, -2s, or -2d and was likely due to reduced VOC concentrations from upgradient
treatment. Analytical results for the DHC analyses are summarized in Table 7.
On September 28, 2015, a report summarizing the results of the Phase II injection was submitted to the
SWS. The report stated that the Phase II injection of emulsified vegetable oil replenished the carbon
source and complete reductive dechlorination is occurring at MW-E, -E Deep, and AMW-1d. The
presence of DHC populations and functional genes in MW-E Deep and AMW-1d demonstrate that the
treatment process can achieve complete chlorinated VOC degradation as long as a sufficient carbon
donor is present.
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Ms. Jaclynne Drummond
January 19, 2022
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As part of the semi-annual monitoring program, additional groundwater samples were collected from
the background well CD-1s; monitoring wells MW-A, -E Rep, -E Deep, -L, and -3; and assessment wells
AMW-1s, -1d, -2s, and -2d. Samples were analyzed for monitored natural attenuation parameters. These
additional samples were collected to evaluate natural attenuation and the effectiveness of the Phase II
injection as part of the CAP. A complete summary of the geochemical results is provided in Table 5.
Contaminant concentration trends for MW-A, -3, -E Rep, -E Deep, AMW-1s, -1d, -2s, and -2d were
evaluated to determine the effectiveness of natural attenuation and the Phase II injection. Figures 3
through 10 present total VOC contaminant concentration data for each well. An isoconcentration
contour map with data from the November 2021 sampling event is provided on Figure 11.
The total VOC trend analysis for MW-A is presented on Figure 3. Total VOC concentrations increased in
MW-A between June 1995 and April 2003 and show a decreasing trend from April 2003 to November
2021.
Figure 4 presents the total VOC trend analysis for MW-3. Total VOC concentrations show an increasing
trend. 1,1-Dichloroethane, PCE, and TCE are the only analytes that have been detected in MW-3 above
the NC 2L Groundwater Standards. The geochemical data indicates aerobic conditions at MW-3. VOC
concentrations in MW-3 Deep have never been detected above the standards.
The total VOC trend analyses for MW-E Rep and -E Deep are presented on Figures 5 and 6, respectively.
Total VOC concentrations in MW-E Rep and -E Deep have decreased since the November 2009 Phase I
injection. PCE and TCE have not been detected above the NC 2L Groundwater Standards in MW-E Deep
since the Phase I injection and have not been detected above the MDL since August 2010. Delivery of
the carbon substrate (i.e., SRS®-FR) during the Phase II injection was effective based on the increase in
COD at MW-E Deep. Historical geochemical data shows reducing conditions exist at the MW-E cluster
based on low DO and high methane concentrations. ORP has fluctuated since the November 2016
sampling event. The increase in metabolic acids and ferrous iron at MW-E Deep also indicates that a
reducing subsurface environment exists. A geochemically reducing environment is favorable for
anaerobic reductive dechlorination.
Figures 7 and 8 present the total VOC trend analyses for assessment wells AMW-1s and -1d,
respectively. Total VOC concentrations in AMW-1s show an increasing trend from November 2010 to
May 2013 but show a decreasing trend from May 2013 to November 2021. VOCs have not been
detected above the MDL in AMW-1s since the September 2020 sampling event. Total VOC
concentrations in AMW-1d show a decreasing trend from the initial sampling in October 2009 to
November 2019 but have fluctuated since the November 2019 sampling event. Historical data shows
reducing conditions existed at AMW-1d but DO and ORP have fluctuated since the November 2017
sampling event. The concentration of vinyl chloride generally increased from the Phase II injection to
November 2017 while TCE concentrations decreased, indicating anaerobic reductive dechlorination is
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Ms. Jaclynne Drummond
January 19, 2022
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occurring as vinyl chloride is a daughter product of TCE. However, from November 2017 to September
2020, TCE concentrations increased, and the concentration of vinyl chloride decreased. The results of
the March and November 2021 sampling event show that TCE was not detected above the standard and
the concentration of vinyl chloride increased.
The total VOC trend analyses for AMW-2s and -2d are presented on Figures 9 and 10, respectively. Total
VOC concentrations at AMW-2s show an increasing trend between the initial sampling event in October
2009 and November 2014 and have fluctuated since the November 2014 sampling event, but generally
show a decreasing trend. Total VOC concentrations show an increasing trend at AMW-2d from
November 2010 to November 2017 but have fluctuated since then. The AMW-2 cluster is located
farthest downgradient of the injection area and the shallow well is screened in partially weathered rock.
Geochemical results indicate an aerobic subsurface environment.
Landfill Gas Monitoring
The approved landfill gas monitoring network consists of monitoring wells MGW-1 through -16. Site
structures that are monitored on the property include the scale house, maintenance shop, electricity
building, and recycling facility. Quarterly landfill gas monitoring of the facility was completed on
September 13 and November 30, 2021, using a GEM 5000+ landfill gas analyzer. No methane or
hydrogen sulfide was detected in any monitoring wells or site structures during either monitoring event.
Copies of the quarterly landfill gas monitoring results and equipment calibration data have been placed
in the landfill operating record and are provided in Appendix B.
Recommendations
Units 2 and 3 of the Cabarrus County Landfill are unlined and are the source of VOC concentrations that
are above the NC 2L Groundwater Standards or IMACs in downgradient monitoring wells. The injection
remedy successfully reduced the contaminant concentrations in bedrock monitoring well MW-E Deep
and developed a primary VOC treatment zone in the vicinity of the injection wells and MW-E Rep.
Downgradient VOC concentrations in bedrock and saprolite should continue to decrease due to reduced
VOC concentrations in the primary treatment zone. Additional injections will be necessary in the future
once all electron donors have been consumed and complete dechlorination stalls.
The County will continue with the semi-annual assessment monitoring program. In addition to sampling
for Appendix I VOCs, including 1,4-dioxane, and metals, and the Appendix II constituent,
bis(2-ethylhexyl) phthalate (sampled at CD-1s, -1d, MW-C, -E Deep, -H, -I, and AMW-2d during the spring
sampling event), samples collected from CD-1s, MW-A, -E Rep, -E Deep, -L, -3, AMW-1s, -1d, -2s, and -2d
will continue to be analyzed for natural attenuation parameters during the semi-annual sampling
events. Future analytical results will be monitored to evaluate if another injection will be needed. The
next sampling event will be completed in the spring of 2022.
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Ms. Jaclynne Drummond
January 19, 2022
Page 11
If you have any questions or require further explanation, do not hesitate to call me at [phone] or
by email at [e-mail].
Very truly yours,
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: Kevin Grant, Cabarrus County
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Table 1
Monitoring Well Construction Summary
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
DepthMonitoring Well Insta ation Geology of Total Facility Permit Number 1 11 Latitude Longitude Screened ..
Code Date Interval (feet BTOC) 6-inch Screen Filter Seal (inches)
1302-MSWLF-CDLF-1998 CD-1s 8/7/2006 35.47788 80.52334 Saprolite 29.53 18.0-28.0 16.0-28.0 14.0-16.0 2.0
(background well)
1302-MSWLF-CDLF-1998
CD-1d
(background well)
7/21/2004
35.47788
80.52340
PWR
52.15
40.0-50.0
38.0-50.0
36.0-38.0
2.0
1302-MSWLF-CDLF-1998
AMW-1s
10/6/2009
35.46915
80.52225
PWR
67.57
50.0-65.0
48.0-65.0
46.0-48.0
2.0
1302-MSWLF-CDLF-1998
AMW-ld
10/8/2009
35.46914
80.52227
Bedrock
96.93
0-78.0
84.0-94.0
82.0-94.0
80.0-82.0
2.0
1302-MSWLF-CDLF-1998
AMW-2s
10/6/2009
35.46829
80.52232
PWR
39.90
--
22.0-37.0
20.0-37.0
18.0-20.0
2.0
1302-MSWLF-CDLF-1998
AMW-2d
10/8/2009
35.46831
80.52233
Bedrock
63.55
0-51.0
55.0-60.0
53.0-60.0
51.0-53.0
2.0
1302-MSWLF-CDLF-1998
CD-4 Rep
1/15/2009
35.47656
80.52210
Saprolite
19.41
--
6.0-16.0
4.0-16.0
2.0-4.0
2.0
1302-MSWLF-CDLF-1998
MW-1
1990s
35.47355
80.52105
Saprolite/PWR
29.93
18.0-28.0
16.0-28.0
14.0-16.0
2.0
1302-MSWLF-CDLF-1998
MW-3
2/17/1992
35.46794
80.52120
Saprolite/PWR
35.10
--
19.0-34.0
17.0-34.0
15.0-17.0
2.0
1302-MSWLF-CDLF-1998
MW-3 deep
6/3/2003
35.46785
80.52133
Bedrock
93.76
0-44.0
75.0-90.0
71.0-75.0
68.0-71.0
2.0
1302-MSWLF-CDLF-1998
MW-9
1990s
35.47706
80.51740
Saprolite/PWR
51.15
--
39.0-49.0
37.0-49.0
35.0-37.0
2.0
1302-MSWLF-CDLF-1998
MW-A
9/16/1994
35.47289
80.52524
Saprolite/PWR
50.42
33.0-48.0
31.0-49.9
29.0-31.0
2.0
1302-MSWLF-CDLF-1998
MW-B
9/16/1994
35.47165
80.52081
Saprolite/PWR
15.22
2.5-12.5
2.0-13.0
1.0-2.0
2.0
1302-MSWLF-CDLF-1998
MW-C
9/16/1994
35.47042
80.52556
Saprolite/PWR
18.50
2.5-15.0
2.0-15.0
1.0-2.0
2.0
1302-MSWLF-CDLF-1998
MW-D
9/16/1994
35.47021
80.52394
Saprolite/PWR
30.15
18.0-28.0
16.0-28.0
14.0-16.0
2.0
1302-MSWLF-CDLF-1998
MW-E Rep
4/9/1996
35.46983
80.52212
PWR/Bedrock
45.65
28.0-43.0
25.0-45.0
23.0-25.0
2.0
1302-MSWLF-CDLF-1998
MW-E deep
9/2/1999
35.46974
80.52220
Bedrock
59.57
41.0-56.0
39.0-56.0
37.0-39.0
2.0
1302-MSWLF-CDLF-1998
MW-F
9/15/1994
35.47050
80.52040
Saprolite/PWR
20.08
3.0-18.0
1.5-18.0
0.5-1.5
2.0
1302-MSWLF-CDLF-1998
MW-G
9/15/1994
35.47290
80.52121
Saprolite/PWR
20.25
3.0-18.0
1.5-18.0
0.5-1.5
2.0
1302-MSWLF-CDLF-1998
MW-H
9/3/1999
35.46861
80.52310
Saprolite/PWR
32.70
19.5-29.5
17.5-29.5
15.5-17.5
2.0
1302-MSWLF-CDLF-1998
MW-H deep
9/2/1999
35.46851
80.52317
Bedrock
59.67
41.0-56.0
39.0-56.0
37.0-39.0
2.0
1302-MSWLF-CDLF-1998
MW-1
9/3/1999
35.46928
80.52076
Saprolite/PWR
65.18
47.0-62.0
45.0-62.0
43.0-45.0
2.0
1302-MSWLF-CDLF-1998
MW-J
9/3/1999
35.47403
80.52647
Saprolite/PWR
34.90
29.0-32.0
28.0-32.0
25.0-28.0
2.0
1302-MSWLF-CDLF-1998
MW-K
9/3/1999
35.46978
80.52467
Saprolite/PWR
36.08
18.0-33.0
16.0-33.0
14.0-16.0
2.0
1302-MSWLF-CDLF-1998
MW-L
9/2/1999
35.46771
80.52168
Saprolite/PWR
26.90
14.0-24.0
12.0-24.0
10.0-12.0
2.0
02-MSWLF-CDLF-1998
MW-Ldeep
6/3/2003
35.46778
80.52168
Bedrock
65.20
0-48.0
53.0-63.0
50.0-63.0
47.0-50.0
2.0
02-MSWLF-CDLF-1998
L13
MW-M
6/2/2003
35.46743
80.52026
PWR
39.80
21.0-36.0
18.0-36.0
16.0-18.0
2.0
02-MSWLF-CDLF-1998
MW-X
12/1/1993
35.47225
80.52664
Saprolite/PWR
31.79
20.0-30.0
18.0-30.0
16.0-18.0
2.0
Notes:
1. BTOC - Below Top of Casing
2. bgs - Below Ground Surface
3. PWR - Partially Weathered Rock
Smith Page 1 of 1 January 2022

Table 2
Groundwater Elevations
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Facility Permit
Number
Sampling Event
Monitoring Well Code
MW-1
Top of Casing Elevation
(AMSQ
701.37
F
689.08
I
689.35
===
689.82
688.87
Groundwater
690.81
Elevation
689.03
(AMSQ
689.32
690.73
689.22
688.97
688.94
MW-3
670.37
652.20
651.67
654.06
652.48
654.70
654.34
656.75
652.60
655.97
654.26
657.31
MW-3 deep
668.33
655.15
NS
656.74
NS
657.43
NS
659.63
NS
658.99
657.48
660.27
MW-9
780.25
736.07
734.92
735.84
NS
NS
NS
NS
NS
NS
NS
NS
MW-A
746.80
703.02
702.39
703.59
703.09
702.45
703.45
705.01
702.49
703.28
702.60
704.73
MW-8
681.66
679.04
679.56
678.34
677.44
679.71
678.96
678.96
675.25
679.06
678.86
678.89
MW-C
694.98
686.66
683.43
684.58
682.88
690.12
683.78
688.55
682.14
688.33
682.70
688.74
MW-D
720.28
692.88
691.48
693.12
691.60
692.15
692.58
696.21
692.98
692.78
691.53
694.50
MW-E Rep
712.58
679.94
679.07
682.38
NS
680.25
682.53
685.83
682.49
683.00
680.93
684.97
MW-E deep
705.70
669.66
668.80
671.10
669.31
670.05
672.21
675.55
672.75
672.71
670.65
674.67
MW-F
681.06
672.27
672.60
671.61
667.86
673.91
671.41
672.51
668.38
672.66
671.66
672.46
MW-G
695.19
685.79
686.40
685.46
685.72
686.74
685.69
685.78
685.11
685.68
685.68
685.62
MW-H
699.23
670.19
669.25
671.30
669.74
670.32
672.62
675.66
672.74
672.67
671.03
674.90
MW-H deep
699.17
669.30
668.54
670.81
669.32
669.72
672.17
675.17
672.33
672.32
670.62
674.52
- 1302
MW-1
709.30
661.43
660.65
662.40
660.82
662.70
662.90
665.83
662.00
664.00
662.17
665.50
CDLF-1998
-1998
MW-J
728.47
698.68
697.11
698.49
696.45
698.77
698.02
700.14
696.55
699.10
696.77
699.52
MW-K
702.91
679.22
676.91
679.73
676.51
679.51
679.09
682.24
677.86
680.25
676.84
681.21
MW-L
669.54
653.13
651.96
654.24
652.71
655.24
654.74
657.83
654.03
656.54
654.39
657.90
MW-L deep
672.51
654.62
NS
655.81
NS
656.74
NS
659.35
NS
658.15
656.14
659.50
MW-M
668.49
647.85
NS
648.19
NS
649.98
NS
650.69
NS
649.52
648.01
649.94
MW-X
710.28
697.62
700.80
697.38
695.25
699.28
696.54
698.95
695.53
698.02
696.14
698.64
CD -is (background well)
755.00
730.81
729.60
730.65
728.94
729.28
730.20
731.82
730.20
730.42
728.55
731.10
CD-1d(background well)
757.40
730.49
729.46
730.96
728.75
729.09
730.00
731.54
729.95
730.20
728.33
730.89
CD-4 Rep
739.15
NS
727.71
728.74
727.35
730.70
728.69
730.69
727.97
729.45
728.68
730.45
CD-6
741.40
707.71
706.81
707.55
706.10
706.02
704.04
710.20
709.30
707.64
706.65
708.75
AMW-Is
725.30
670.87
670.00
672.32
670.00
671.30
673.57
676.79
674.05
674.06
672.00
676.07
AMW-1d
725.80
670.58
669.77
672.03
670.34
671.05
673.31
676.62
673.02
673.85
671.73
675.85
AMW-2s
694.50
668.16
667.10
669.38
667.78
671.47
670.43
673.40
670.29
671.07
669.09
672.97
AMW-2d
694.50
668.49
667.68
669.90
668.32
669.12
671.05
673.95
670.70
671.60
669.65
673.53
Notes:
1. AMSL - Above Mean Sea Level
2. NS - Not Sampled
3. The November 2012 sampling event was the first event that
CD-1s/CD-1d replaced MW-9 as the background monitoring wells.
4. MW-9 was removed from the monitoring program in November 2012.
5. MW-E Rep was not sampled during the Novemver 2012
sampling event due to laboratory oversight.
6. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D
Landfill expansion.
Smith Page 1 of 2 January 2022

Table 2
Groundwater Elevations
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Facility Permit
Number
Sampling Event
Monitoring Well Code
MW-1
Top of Casing Elevation
(AMSQ
701.37
688.76
689.10
688.48
688.76
Groundwater
689.90
Elevation
689.49
(AMSQ
689.32
689.50
689.38
689.34
688.90
MW-3
670.37
655.78
657.56
655.20
656.52
659.53
658.47
655.49
657.93
657.49
659.52
655.67
MW-3 deep
668.33
659.10
661.06
658.68
660.09
660.36
660.70
657.83
659.88
659.66
662.05
658.27
MW-9
780.25
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
MW-A
746.80
704.39
703.58
703.50
702.71
703.45
707.23
706.60
707.17
707.06
709.50
708.06
MW-8
681.66
678.77
679.21
676.88
678.38
679.68
679.20
679.09
679.35
679.18
679.26
678.99
MW-C
694.98
683.29
689.03
682.63
683.75
690.09
682.94
683.70
687.16
685.43
688.80
684.23
MW-D
720.28
693.39
693.40
692.14
691.86
695.70
697.52
695.28
697.33
696.64
700.18
696.95
MW-E Rep
712.58
683.18
682.85
678.66
682.76
683.49
688.28
684.95
687.49
686.55
687.78
685.46
MW-E deep
705.70
672.88
672.51
675.20
672.38
673.22
677.97
674.68
676.69
676.27
674.75
675.19
MW-F
681.06
670.61
672.84
669.57
671.73
674.33
672.97
671.84
672.76
672.87
672.86
671.51
MW-G
695.19
685.65
685.82
685.37
685.50
686.41
685.96
685.89
685.98
685.86
686.13
685.41
MW-H
699.23
673.29
672.50
671.87
671.92
672.52
671.88
675.01
676.86
676.70
678.80
675.79
MW-H deep
699.17
672.96
672.16
671.66
671.85
672.22
677.41
674.71
676.56
676.22
678.47
675.40
1302-MSWLF-
MW-1
709.30
663.72
665.28
662.95
664.52
665.01
667.47
663.96
666.42
665.85
668.35
664.47
CDLF-1998
MW-J
728.47
698.05
699.37
697.55
698.15
700.16
700.85
699.42
700.94
700.83
702.03
698.45
MW-K
702.91
678.35
680.15
677.33
678.94
680.58
683.30
679.61
682.86
682.20
685.21
681.31
MW-L
669.54
655.72
657.89
655.10
655.62
658.22
659.66
655.92
659.18
658.18
660.82
656.24
MW-L deep
672.51
657.51
660.49
656.95
658.43
660.66
661.16
657.73
660.93
659.90
662.40
658.13
MW-M
668.49
648.79
650.25
648.36
649.12
651.25
650.93
648.49
649.83
649.69
651.48
647.99
MW-X
710.28
696.83
698.46
695.93
696.67
700.50
697.07
698.30
699.85
700.62
702.53
699.69
CD -is (background well)
755.00
729.77
730.00
728.89
730.00
730.05
726.89
731.53
733.46
733.75
735.38
733.80
CD-1d(background well)
757.40
729.57
729.82
728.67
729.57
729.88
730.51
731.32
733.22
733.48
735.15
733.60
CD-4 Rep
739.15
728.90
730.38
728.00
729.24
731.83
728.50
729.50
730.74
730.52
731.93
729.58
CD-6
741.40
708.44
AMW-1s
725.30
674.31
673.89
671.16
673.75
674.20
679.25
677.01
678.00
677.59
680.19
676.56
AMW-1d
725.80
674.09
673.67
672.91
672.60
674.05
679.12
675.80
677.82
677.33
680.09
676.32
AMW-2s
694.50
671.18
671.15
670.19
670.72
671.41
675.55
672.69
674.80
674.43
676.42
673.20
AMW-2d
694.50
671.82
1 671.60
670.74
1 671.20
671.72
676.32
1 674.40
675.40
675.00
677.21
1 673.95
Notes:
1. AMSL - Above Mean Sea Level
2. NS - Not Sampled
3. The November 2012 sampling event was the first event that
CD-1s/CD-1d replaced MW-9 as the background monitoring wells.
4. MW-9 was removed from the monitoring program in November 2012.
5. MW-E Rep was not sampled during the Novemver 2012
sampling event due to laboratory oversight.
6. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D
Landfill expansion.
Smith Page 2 of 2 January 2022

Table 3
Summary of Groundwater Velocities
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Facility Permit
Number
Monitoring Well Code
MW-A
Gradient
0.0157
Average Linear
Velocity
feet/day
6.12E+00
Gradient
0.0162
Average Linear
Velocity
feet/day
6.31E+00
Gradient
0.0164
Average Linear
Velocity
feet/day
6.40E+00
Gradient
0.0181
Average Linear
Velocity
feet/day
7.06E+00
Gradient
0.0143
Average Linear
Velocity
feet/day
5.56E+00
Gradient
0.0165
Average Linear
Velocity
feet/day
6.43E+00
Gradient
0.0154
r,
Average LI ... r
Velocity
fect/day
6.02E+00
Cr.die.,
0.0169
,.
AveVrage Linear
cloc ity
feet/day
6.59E+00
MW-B
0.0171
1.27E+00
0.0163
1.20E+00
0.0180
1.33E+00
0.0183
1.35E+00
0.0162
1.20E+00
0.0175
1.29E+00
0.0186
1.37E+00
0.0195
1.44E+00
MW-C
0.0182
3.98E+00
0.0211
4.61E+00
0.0211
4.62E+00
0.0225
4.91E+00
0.0137
3.00E+00
0.0219
4.78E+00
0.0183
4.00E+00
0.0226
4.95E+00
MW-D
0.0097
3.42E+00
0.0104
3.68E+00
0.0100
3.53E+00
0.0109
3.88E+00
0.0098
3.47E+00
0.0104
3.67E+00
0.0084
2.97E+00
0.0091
3.21E+00
MW-E Rep
0.0154
5.36E+01
0.0155
5.42E+01
0.0141
4.93E+01
0.0148
5.16E+01
0.0139
4.86E+01
0.0128
4.46E+01
0.0133
4.65E+01
1302-MSWLF-
CDLF-1998
MW-F
0.0181
1.65E+00
0.0175
1.60E+00
0.0188
1.72E+00
0.0207
1.89E+00
0.0168
1.53E+00
0.0188
1.72E+00
0.0191
1.74E+00
0.0201
1.83E+00
MW-G
0.0265
2.92E+00
0.0255
2.82E+00
0.0265
2.93E+00
0.0227
2.51E+00
0.0224
2.47E+00
0.0234
2.59E+00
0.0242
2.68E+00
0.0237
2.62E+00
MW-1
0.0276
6.05E+00
0.0268
5.87E+00
0.0271
5.92E+00
0.0236
5.16E+00
0.0226
4.95E+00
0.0242
5.30E+00
0.0250
5.47E+00
0.0232
5.08E+00
MW-9
0.0185
4.05E+00
0.0187
4.08E+00
0.0190
4.16E+00
CD-1s
0.0196
2.35E-02
0.0163
1.96E-02
0.0183
2.20E-02
0.0177
2.13E-02
0.0185
2.23E-02
(background well)
Notes:
1. Blanks indicate no data.
2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells.
4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F.
5. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells.
6. MW-9 was removed from the monitoring program in November 2012.
7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight.
Smith Page 1 of 3 January 2022

Table 3
Summary of Groundwater Velocities
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Facility Permit
Number
-ell Cecil
MW-A
Gradient
0.0151
Average Lil­
Velocity
fect/day
5.88E+00
Gradient
0.0165
Average Lin...
Velocity
fect/d.y
6.42E+00
Gradient
0.0156
Average Lin...
Velocity
feet/day
6.09E+00
Gradient
0.0172
Average Linear
Velocity
feet/day
6.73E+00
Gradient
0.0150
Average Linear
Velocity
feet/day
5.86E+00
Gradient
0.0180
Average Lin-,
Velocity
feet/day
7.01E+00
Gradient
0.0161
r:
Li ... r
Velocity
fect/day
6.26E+00
MW-B
0.0173
1.28E+00
0.0170
1.25E+00
0.0185
1.36E+00
0.0183
1.35E+00
0.0174
1.29E+00
0.0191
1.41E+00
0.0174
1.28E+00
MW-C
0.0166
3.63E+00
0.0221
4.84E+00
0.0178
3.89E+00
0.0234
5.13E+00
0.0162
3.54E+00
0.0233
5.09E+00
0.0211
4.61E+00
MW-D
0.0100
3.54E+00
0.0105
3.73E+00
0.0097
3.45E+00
0.0105
3.71E+00
0.0097
3.43E+00
0.0109
3.86E+00
0.0103
3.66E+00
MW-E Rep
0.0135
4.71E+01
0.0144
5.03E+01
0.0132
4.59E+01
0.0141
4.93E+01
0.0138
4.82E+01
0.0166
5.79E+01
0.0133
4.63E+01
1302-MSWLF-
CDLF-1998
MW-F
0.0180
1.64E+00
0.0182
1.66E+00
0.0190
1.73E+00
0.0199
1.81E+00
0.0181
1.65E+00
0.0200
1.82E+00
0.0182
1.66E+00
MW-G
0.0235
2.60E+00
0.0226
2.49E+00
0.0239
2.64E+00
0.0232
2.56E+00
0.0233
2.57E+00
0.0240
2.65E+00
0.0234
2.59E+00
MW-1
0.0242
5.30E+00
0.0233
5.09E+00
0.0248
5.43E+00
0.0241
5.28E+00
0.0241
5.26E+00
0.0244
5.34E+00
0.0243
5.31E+00
MW-9
CD-1s
0.0173
2.07E-02
0.0181
2.17E-02
0.0178
2.14E-02
0.0189
2.26E-02
0.0172
2.06E-02
0.0195
2.34E-02
0.0180
2.16E-02
(background well)
Notes:
1. Blanks indicate no data.
2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells.
4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F.
5. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells.
6. MW-9 was removed from the monitoring program in November 2012.
Smith Page 2 of 3 January 2022

Table 3
Summary of Groundwater Velocities
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Facility Permit
Number
-ell Code
MW-A
Gradient
0.0139
Average Lil­
Velocity
5.43E+00
Gradient
0.0178
Average Lin...
Velocity
6.95E+00
Gradient
0.0182
Average Lin...
Velocity
7.08E+00
Gradient
0.0170
Average Linear
Velocity
6.62E+00
Gradient
0.0175
Average Linear
Velocity
6.84E+00
Gradient
0.0179
Average Linear
Velocity
6.98E+00
Gradient
0.0193
-e,,,, Li ... r
Velocity
7.53E+00
MW-B
0.0170
1.25E+00
0.0200
1.48E+00
0.0197
1.45E+00
0.0199
1.47E+00
0.0199
1.47E+00
0.0216
1.60E+00
0.0212
1.56E+00
MW-C
0.0148
3.25E+00
0.0270
5.91E+00
0.0254
5.57E+00
0.0222
4.86E+00
0.0240
5.26E+00
0.0230
5.03E+00
0.0271
5.92E+00
MW-D
0.0074
2.61E+00
0.0092
3.28E+00
0.0108
3.82E+00
0.0094
3.32E+00
0.0099
3.52E+00
0.0089
3.14E+00
0.0111
3.93E+00
MW-E Rep
0.0133
4.64E+01
0.0126
4.40E+01
0.0144
5.03E+01
0.0131
4.57E+01
0.0137
4.76E+01
0.0145
5.05E+01
0.0154
5.38E+01
1302-MSWLF-
CDLF-1998
MW-F
0.0171
1.56E+00
0.0202
1.84E+00
0.0204
1.86E+00
0.0202
1.85E+00
0.0201
1.83E+00
0.0216
1.97E+00
0.0218
1.99E+00
MW-G
0.0230
2.54E+00
0.0215
2.38E+00
0.0240
2.65E+00
0.0249
2.74E+00
0.0251
2.77E+00
0.0258
2.85E+00
0.0254
2.80E+00
MW-1
0.0236
5.17E+00
0.0220
4.81E+00
0.0248
5.43E+00
0.0257
5.63E+00
0.0259
5.68E+00
0.0269
5.90E+00
0.0263
5.75E+00
MW-9
CD-1s
0.0163
1.95E-02
0.0189
2.26E-02
0.0197
2.37E-02
0.0190
2.29E-02
0.0195
2.34E-02
0.0200
2.40E-02
0.0209
2.51E-02
(background well)
Notes:
1. Blanks indicate no data.
2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells.
4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F.
5. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells.
6. MW-9 was removed from the monitoring program in November 2012.
Smith Page 3 of 3 January 2022

Table 4
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
CD-ls (background well)
5.58 158 16.0
5.96 191 87
5.65
120
•17.5
3.83
182
59
5.86
111 16.3
1.51 181 10
6.06
116
13.8
15.50
139 7
6.02 104 •15.1 1.96
206 5
CD-ld (background well)
5.55 171 16.2
8.22 191 280
5.80
132
17.9
2.70
171
84
6.27
121 17.3
1.41 150 73
6.16
125
16.4
9.53
140 5
6.06 117 16.9 1.11
242 27
CD-4 Rep
NS NS NS
NS NS NS
5.84
284
17.9
1.40
145
18
6.37
390 15.4
0.00 156 13
6.47
207
15.6
0.00
-1 2
5.54 256 13.7 0.62
29 30
CD-6
5.55 257 16.8
3.19 130 55
5.49
269
16.4
4.19
183
13
5.76
208 18.4
0.78 202 7
6.03
221
16.2
0.00
71 1
5.75 223 16.9 0.60
166 11
AMW-15
5.23 225 21.9
1.22 176 10
6.36
237
17.8
0.17
12
7
5.67
292 27.4
0.02 121 9
5.89
230
15.5
3.81
44 5
5.56 256 16.4 0.34
523 1
AMW-ld
6.09 569 22.0
0.01 89 4
7.60
638
17.3
0.00
-112
3
6.00
651 24.1
0.24 95 8
6.47
573
14.5
7.00
169 5
6.20 755 17.9 0.46
-53 2
AMW-2s
5.65 135 17.8
2.10 128 36
7.72
148
17.0
2.47
-30
10
5.74
171 18.6
0.42 195 29
6.16
149
15.0
5.36
38 5
5.60 157 16.7 0.88
153 9
AMW-2d
6.24 241 19.1
0.75 107 3
6.96
167
13.9
1.07
-29
3
5.78
195 17.4
0.00 195 4
6.37
183
15.0
3.47
149 1
5.83 192 17.1 0.36
126 0
MW-1
6.03 1,870 16.6
2.96 -77 78
6.01
1,570
16.3
2.44
139
4
6.37
1,794 16.1
0.00 -22 2
6.57
1,480
15.4
0.00
31 9
6.19 1,817 15.0 0.77
43 1
MW-3
5.57 127 18.1
2.60 164 27
6.01
174
17.8
4.05
198
32
5.73
155 19.5
2.76 113 9
6.19
160
15.8
12.31
73 8
5.76 149 16.0 1.88
188 40
MW-3 deep
7.09 469 18.3
3.98 81 242
NS
NS
NS
NS
NS
NS
7.93
329 17.1
0.39 21 191
NS
NS
NS
NS
NS NS
7.76 348 16.4 0.39
-153 2
MW-9
6.08 90 18.9
3.45 139 4
5.91
107
18.9
4.70
212
0
6.05
106 19.1
1.82 127 3
NS
NS
NS
NS
NS NS
NS NS NS NS
NS NS
MW-A
5.01 292 17.3
1.08 113 4
5.47
324
17.9
0.06
205
1
5.47
411 17.1
0.00 103 3
5.47
371
14.7
2.66
140 2
5.42 309 16.5 0.25
-34 0
1302-MSWLF-
MW-B
6.45 1,350 14.2
3.70 -116 25
6.26
1,070
15.8
2.39
-78
5
6.70
1,097 14.8
0.00 -49 7
6.87
958
15.2
0.00
-82 10
6.44 1,037 13.1 1.09
-88 1
CDLF-1998
MW-C
5.37 152 13.8
5.23 136 54
5.79
394
16.9
4.01
130
12
5.89
200 18.3
0.83 -16 46
5.93
187
15.2
0.00
28 4
5.35 100 13.2 1.06
104 43
MW-D
5.36 610 16.7
3.14 87 135
5.26
501
16.5
1.99
79
4
5.36
460 16.9
0.00 79 4
5.66
467
15.6
0.00
90 8
5.48 462 16.7 0.26
60 9
MW-E Rep
5.73 586 17.7
0.01 34 9
5.69
659
19.0
0.00
-115
4
5.96
785 19.3
0.00 13 6
DRY
DRY
DRY
DRY
DRY DRY
6.17 991 16.8 0.47
-81 0
MW-E deep
6.40 738 15.9
0 -51 7
6.54
823
18.7
0.00
-67
3
6.50
842 21.1
2.51 -76 9
6.50
822
16.5
1.70
78 >800
6.51 803 18.1 0.51
-80 3
MW-F
6.35 1,120 14.3
2.43 -139 10
6.40
979
16.9
1.53
-95
4
6.30
826 16.2
0.00 -57 7
6.81
1,050
15.4
0.00
-92 12
6.30 745 13.7 0.64
-89 3
MW-G
6.11 1,110 16.5
5.79 -99 29
5.91
917
17.4
2.85
-61
2
6.21
861 14.1
0.00 -63 3
6.51
997
16.1
0.00
-84 2
6.10 930 14.0 0.49
-98 0
MW-H
5.29 230 14.5
9.03 197 212
5.82
176
14.9
6.13
193
7
5.20
145 15.0
3.90 74 13
6.45
171
14.6
0.00
-22 2
5.79 149 15.7 1.77
60 9
MW-H deep
5.53 369 15.1
5.97 192 43
5.83
263
15.1
6.91
186
6
5.74
270 14.6
0.96 35 11
6.40
251
16.1
6.27
17 1
6.13 255 16.0 1.23
130 2
MW-I
5.46 99 16.2
3.44 164 10
5.67
113
15.8
4.67
114
3
5.92
109 17.9
2.58 147 3
6.14
116
14.4
0.00
84 8
5.74 112 15.3 0.21
159 1
MW-J
6.25 341 16.2
4.62 156 86
5.78
343
16.9
6.14
111
1
6.49
247 16.1
1.09 21 4
6.57
251
14.1
0.00
125 1
6.40 236 15.5 1.45
223 14
MW-K
5.47 269 15.6
4.74 153 38
5.09
311
16.4
4.32
47
8
5.75
200 15.8
1.90 143 8
6.00
235
14.8
0.00
103 9
5.72 207 15.2 0.66
175 1
MW-L
5.38 91 14.3
2.31 206 4
5.66
106
16.4
2.59
222
3
5.44
112 16.4
0.04 214 5
6.70
227
14.9
3.03
3 5
5.30 96 15.1 1.09
188 8
MW-L deep
6.65 368 18.7
3.49 103 18
NS
NS
NS
NS
NS
NS
6.20
279 18.5
0.87 75 14
NS
NS
NS
NS
NS NS
6.02 208 17.1 1.49
133 2
MW-M
5.53 301 14.4
6.58 194 26
NS
NS
NS
NS
NS
NS
6.09
221 15.4
1.47 91 59
NS
NS
NS
NS
NS NS
6.34 297 15.3 1.51
54 1
MW-X
5.93 338 15.3
4.29 174 51
6.01
260
16.6
6.51
33
20
5.13
241 14.9
0.91 69 4
6.37
253
14.3
0.00
145 1
6.15 222 14.6 1.20
117 2
1302-MSWLF-
SW-1
6.14 685 10.5
6.58 78 18
6.14
424
16.8
6.01
170
2
DRY
DRY DRY
DRY DRY DRY
DRY
DRY
DRY
DRY
DRY DRY
7.02 466 16.0 4.10
-17 15
CDLF-1998
SW-2
5.05 667.00 9.67
6.06 121 196
DRY
DRY
DRY
DRY
DRY
DRY
6.36
455 22.3
2.49 114 13
DRY
DRY
DRY
DRY
DRY DRY
7.10 333 15.5 4.416
-7 6
Notes:
1. NS - Not Sampled
2. its/cm- Microsiemens per centimeter
3. mg/L- milligrams per liter
4. ORP - Oxidation -Reduction Potential
5. Turb. - Turbidity; NTUs - Nephelometric Turbidity Units
6. mvs - millivolts
7. DO - Dissolved Oxygen
8. S.U. - Standard Units
9. Temp. - Temperature; Deg. C - Degrees Celsius
10. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells.
11. MW-9 was removed from the monitoring program in November 2012.
12. M W-3 deep, -L deep, -and -Mare sampled annually during the spring event.
13. M W-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight.
Smith Page 1 of 5 January 2022

Table 4
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
CD-1s (background well)
6.06 100
13.0
1.74
348
42
6.15
119
•15.9
0.02
353
9
6.10 129
15.1 6.06
135 2
6.00
115
15.5
3.99 281
7
5.73 132 15.0
3.84
519 3
CD -Id (background well)
6.03 119
14.5
1.71
320
32
6.21
134
19.2
4.56
293
9
6.18 139
16.5 4.68
109 14
5.97
123
16.4
4.84 186
13
5.81 136 14.5
6.96
507 7
CD-4 Rep
6.14 177
16.9
1.20
-45
26
6.10
259
13.3
2.19
-7
3
6.15 126
15.9 2.69
58 7
6.29
495
13.5
2.75 70.4
4
6.06 231 16.4
3.19
31.2 3
CD-6
6.15 994
17.1
1.24
-17
60
5.84
217
17.7
2.86
137
4
5.77 253
16.4 3.35
45 67
5.79
372
17.4
2.04 142
5
5.90 244 16.3
3.92
111 >800
AMW-15
5.72 249
17.9
1.05
149
9
5.83
251
16.8
0.02
400
10
5.72 251
17.5 3.25
132 8
4.58
243
14.9
2.00 592
6
5.80 443 16.0
2.68
253 3
AMW-Id
6.08 727
19.6
1.40
-23
9
6.04
650
20.1
2.05
-28
604
6.13 643
18.0 1.36
-68 29
5.94
518
15.9
1.78 -52
16
6.11 1,004 15.8
2.55
-42 5
AMW-2s
5.69 159
17.7
1.51
75
9
5.76
178
18.8
2.08
114
6
5.77 182
15.2 3.48
121 6
5.07
160
14.2
3.50 562
6
5.92 173 16.2
4.19
187 3
AMW-2d
6.26 203
18.5
1.40
138
1
6.30
231
16.9
3.88
95
1
6.26 252
16.0 4.19
104 1
5.77
230
15.2
2.51 391
1
6.36 260 17.2
3.90
158 2
MW-1
6.30 1,381
15.7
1.99
144
22
6.36
1,361
15.0
2.84
37
3
6.34 1,511
15.4 2.59
-37 0
6.29
2,379
14.9
2.69 -19
6
6.31 1,743 15.5
1.94
21 7
MW-3
5.87 160
17.0
1.99
301
40
6.05
180
18.5
0.04
150
8
5.97 202
16.3 5.94
466 4
5.42
166
17.6
2.29 260
14
6.20 178 19.5
3.85
166 3
MW-3 deep
NS NS
NS
NS
NS
NS
7.75
385
16.5
4.04
-65
4
NS NS
NS NS
NS NS
7.49
368
20.5
1.50 -198
4
7.63 387 19.5
1.67
-165 3
MW-9
NS NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS NS
NS NS
NS NS
NS
NS
NS
NS NS
NS
NS NS NS
NS
NS NS
MW-A
5.40 333
15.3
1.89
291
1
5.42
432
16.9
0.04
-17
1
5.47 451
16.4 1.70
45 2
4.78
390
15.6
2.34 27
2
5.30 402 15.5
1.41
29 3
1302-MSWLF-
MW-B
6.33 817
16.4
1.35
-67
15
6.66
1,033
12.6
2.58
-67
10
6.62 922
16.6 3.00
-101 1
6.70
1,485
13.0
3.03 -68
9
6.00 833 16.9
3.91
-51 6
CDLF-1998
MW-C
5.90 206
16.7
1.31
233
72
5.64
108
12.3
2.23
44
4
6.02 428
16.0 2.58
47 3
5.94
162
12.9
3.89 -181
8
5.21 186 16.7
1.73
153 37
MW-D
5.66 490
16.1
1.04
295
51
5.85
705
17.2
1.85
-17
2
5.71 471
15.7 3.39
35 4
5.86
745
16.8
3.66 15
3
5.19 520 16.5
2.60
85 14
MW-E Rep
6.11 959
16.5
1.64
-40
3
5.99
831
19.0
0.07
-24
2
6.25 1,180
17.6 1.62
-54 3
6.04
1,095
17.3
3.61 -38
9
6.10 1,076 16.2
1.25
-36 3
MW-E deep
6.35 836
17.1
1.21
-82
3
5.60
1,042
20.2
0.09
-41
800
6.34 1,198
18.0 1.09
-82 13
6.41
1,027
18.4
0.88 -100
15
6.44 979 16.2
1.21
-71 5
MW-F
6.52 877
15.8
1.47
-100
10
6.57
726
13.8
2.74
-81
5
6.46 919
15.4 2.18
-104 6
6.51
1,270
13.9
3.58 -58
3
6.61 1,134 15.5
2.71
-136 3
MW-G
6.15 1,430
16.7
1.60
-83
23
6.27
1,542
13.7
2.29
-106
8
6.30 1,794
16.3 1.97
-124 14
6.31
2,445
13.9
2.66 -78
6
6.32 1,372 16.8
2.28
-135 0
MW-H
6.04 160
15.2
2.04
335
96
5.92
161
14.5
2.39
230
19
5.92 199
14.2 3.70
466 11
5.51
174
15.0
2.71 136-5
10
5.15 203 15.3
0.81
168 43
MW-H deep
6.14 259
15.1
2.75
332
15
6.25
269
15.4
2.10
260
4
6.24 317
14.3 3.81
427 4
6.12
285
15.4
1.62 137
4
5.72 280 15.3
0.64
146 4
5.97 116
15.1
1.61
311
1
5.95
118
15.3
2.59
84
3
6.11 133
14.4 4.12
199 3
5.64
134
15.3
2.82 132
3
5.13 128 15.2
0.76
104 3
MW-J
6.42 242
14.7
1.64
346
37
6.39
259
15.8
2.05
36
5
6.53 245
14.2 3.75
155 14
6.54
402
14.9
3.13 137
7
6.48 274 14.3
0.38
210 7
MW-K
5.79 199
15.2
1.40
266
33
5.81
202
16.0
2.88
96
6
5.83 229
14.6 2.65
187 10
5.56
239
14.9
1.50 95
5
4.93 253 15.2
3.43
167 6
LMW-1
MW-L
5.54 106
14.6
1.39
258
68
5.80
99
16.6
2.12
379
4
5.78 122
16.4 4.03
59 3
5.29
97
17.5
4.15 131
3
5.92 93 18.5
3.80
89 4
MW-L deep
NS NS
NS
NS
NS
NS
6.88
201
17.5
2.70
380
3
NS NS
NS NS
NS NS
6.61
341
17.5
4.79 190
3
5.49 395 15.8
0.80
155 2
MW-M
NS NS
NS
NS
NS
NS
6.31
271
15.3
2.45
211
4
NS NS
NS NS
NS NS
6.31
334
15.4
1.49 116
4
5.67 334 15.7
0.49
151 10
MW-X
6.25 236
15.4
1.45
348
36
6.28
216
15.2
2.07
106
21
6.31 228
14.5 4.53
131 2
6.19
341
13.5
3.23 140
4
5.03 234 15.3
2.53
342 3
1302-MSWLF-
SW -1
6.16 560
11.0
2.12
341
11
7.24
502
24.6
0.07
-26
22
DRY DRY
DRY DRY
DRY DRY
DRY
DRY
DRY
DRY DRY
DRY
6.83 840 16.0
1.04
-54 0
CDLF-1998
SW-2
DRY DRY
DRY
DRY
DRY
DRY
7.50
604
25.4
4.48
3
8
6.50 325
10.4 -69.80
2 43
6.89
520
24.7
2.19 4
7
5.55 788 15.4
1.34
1 158 1 7
Notes:
1. NS - Not Sampled
2. ps/cm- Microsiemens per centimeter
3. mg/L- milligrams per liter
4. ORP - Oxidation -Reduction Potential
5. Turb. - Turbidity; NTUs - Nephelometric Turbidity Units
6. mVs - millivolts
7. DO - Dissolved Oxygen
8. S.U. - Standard Units
9. Temp. -Temperature; Deg. C - Degrees Celsius
10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced MW-9 as the background monitoring wells.
11. MW-9 was removed from the monitoring program in November 2012.
12. M W-3 deep, -L deep, -and -Mare sampled annually during the spring event.
Smith Page 2 of 5 January 2022

Table 4
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Sampling
Event:
No. 42
No. 43
No. 44 No. 45
CD-1s (background well)
5.91
103 15.7
3.45 245
4 5.05
113
16.1
4.49
360
6
5.32 117 15.7
1.69 274.6 8 5.35
121
16.1 1.87
57.7 8.09 6.2
110
31.5
3.8
124.1
5
CD -Id (background well)
6.06
115 15.8
4.50 210
20 5.34
124
15.9
3.10
330
8
5.46 129 14.3
1.51 257.2 4 5.64
132
17.3 2.85
36.9 2.89 6.2
117
18.3
2.9
54.2
11
CD-4 Rep
6.90
242 14.2
2.68 -54
28 5.28
209
17.0
1.35
79
3
5.65 211 14.3
5.00 29.0 9 5.94
156
15.9 1.31
218.4 5.19 6.0
156
16.3
4.5
50.7
153
CD-6
6.20
271 16.9
1.50 -48
23 5.62
292
16.9
1.38
-4
29
-- -- --
-- -- -- --
--
-- --
-- -- --
--
--
--
--
--
AMW-1s
6.07
224 16.5
3.77 222
8 5.02
297
18.8
1.65
377
6
5.46 258 15.7
1.54 148.6 0 5.17
198
16.7 2.39
226.6 0.87 5.8
218
18.0
0.5
566.1
2
AMW-Id
6.13
477 18.1
1.51 -28
4 5.00
583
13.3
1.73
199
8
5.92 496 17.9
1.59 -6.7 4 5.94
454
23.2 3.51
158.9 4.24 6.0
429
20.4
3.2
21.3
109
AMW-2s
5.78
154 15.8
3.22 51
7 4.92
164
16.4
3.38
235
8
5.79 172 18.9
1.55 48.2 4 4.40
159
17.2 4.42
280.1 4.39 5.8
154
22.4
2.2
162.6
4
AMW-2d
6.04
229 15.9
2.69 88
1 5.52
356
16.5
2.15
346
4
5.98 264 18.5
1.47 37.0 0 5.17
258
15.5 3.20
151.0 3.79 5.9
244
22.9
0.6
13.9
2
MW-1
8.05
1,515 15.4
3.48 94
4 6.13
1,812
16.2
1.03
34
8
5.49 1,545 15.7
3.44 53.2 7 6.28
1,533
15.0 2.44
210.9 10.0 6.4
1,385
15.2
3.4
75.4
47
MW-3
6.04
167 16.5
3.18 101
1 5.52
246
20.6
3.50
439
5
5.61 179 17.9
1.75 229.6 1 5.86
172
17.3 1.60
325.4 1.36 6.0
166
22.3
3.7
130.6
2
MW-3 deep
7.48
362 15.6
2.26 -130
0 NS
NS
NS
NS
NS
NS
6.60 381 17.2
4.03 95.7 4 7.68
360
17.3 2.29
67 0.20 7.6
341
24.1
0.4
109.8
2
MW-9
NS
NS NS
NS NS
NS NS
NS
NS
NS
NS
NS
NS NS NS
NS NS NS NS
NS
NS NS
NS NS NS
NS
NS
NS
NS
NS
MW-A
5.48
394 16.1
1.27 -55
1 4.77
412
16.5
1.65
205
4
5.23 412 15.6
1.31 140.9 3 5.06
423
16.8 3.21
70.1 4.42 5.6
373
21.2
0.4
63.5
1
1302-MSWLF-
MW-B
8.32
976 14.0
3.73 53
17 6.44
1,085
17.5
2.11
-79
9
5.53 991 14.2
4.71 -18.3 22 6.53
904
16.1 1.94
-74.6 57.0 6.6
701
18.5
3.4
-18.7
31
CDLF-1998
MW-C
6.50
126 14.0
3.48 -78
6 5.52
243
17.4
2.58
49
7
5.40 103 14.0
4.92 34.6 8 5.55
145
15.7 3.71
320.5 9.17 5.7
109
15.0
5.4
64.2
225
MW-D
7.26
617 16.3
1.23 -84
4 5.43
627
16.5
1.51
69
6
5.98 824 16.9
5.10 10.0 9 5.73
530
15.0 2.33
201.5 21.0 5.9
490
17.2
2.9
62.9
23
MW-E Rep
6.27
1,088 17.1
1.40 -59
1 5.59
1,139
17.6
3.79
48
5
6.31 1,117 18.1
1.35 -50.7 8 6.33
1,116
18.0 2.48
65.1 4.25 6.4
999
23.7
1.3
-26.2
11
MW-E deep
6.63
1,017 17.5
3.08 -95
9 5.89
959
18.1
2.30
-39
8
6.34 929 18.1
1.65 -78.5 9 5.59
890
17.5 2.45
151.8 8.61 6.5
857
29.0
0.4
-83.5
5
MW-F
8.12
796 14.4
2.65 -47
6 6.25
1,141
16.6
1.23
-71
6
5.23 911 14.6
3.59 -16.3 5 6.38
934
15.0 2.03
-82.3 20.0 6.5
526
14.9
3.4
-69.3
20
MW-G
7.96
1,671 15.0
2.40 49
12 6.07
2,320
17.6
1.09
-80
1
5.32 1,733 15.5
3.78 -60.0 13 6.17
1,760
16.2 3.20
-85.7 48.0 6.3
1,035
15.9
2.60
-38.7
49
MW-H
6.06
162 14.2
5.40 204
38 5.53
211
15.3
1.63
118
59
4.50 174 14.9
4.17 124.6 43 5.80
162
13.9 1.57
272.2 15.0 6.2
159
14.8
5.3
46.8
49
MW-H deep
6.82
272 14.9
4.99 145
18 5.91
337
15.0
2.21
105
16
5.47 276 15.8
4.80 66.7 7 6.12
264
13.7 1.52
332.9 3.17 6.5
267
15.2
3.0
47.0
28
MW-I
6.86
127 15.0
4.49 164
7 5.65
164
15.0
1.35
68
9
4.56 136 15.7
5.05 119.1 7 5.79
126
13.7 1.15
251.2 7.00 6.3
155
15.5
3.9
26.1
29
MW-J
6.92
265 14.8
4.20 28
58 6.05
311
14.8
2.65
21
36
6.47 254 14.8
4.87 111.6 18 6.41
256
13.6 2.66
428.9 28.0 6.2
243
15.9
3.0
104.2
97
MW-K
7.03
208 15.0
4.34 21
14 5.47
2831
15.4
1.89
149
21
4.53 215 15.4
5.03 123.1 8 5.72
218
14.2 1.30
327.3 11.0 6.0
192
15.8
4.6
61.8
27
MW-L
5.80
95 14.2
3.66 192
2 5.11
146
18.1
3.49
486
5
4.97 100 17.8
1.70 128.9 3 5.65
104
15.8 1.61
360.8 2.07 5.9
95
18.8
1.2
141.2
4
MW-L deep
6.82
209 15.0
3.88 149
2 NS
NS
NS
NS
NS
NS
6.17 223 16.5
1.58 72.4 0 6.54
211
15.7 2.63
211 0.61 6.7
207
24.0
0.3
146.7
3
MW-M
7.97
320 15.3
4.02 -3
8 NS
NS
NS
NS
NS
NS
6.24 304 16.0
5.29 55.4 4 6.30
305
14.7 2.46
326 14.0 6.6
286
16.1
3.1
91.5
18
MW-X
7.19
210 13.9
3.98 20
6 5.94
275
DRY
15.3
1.62
78
2
6.39 202 14.3
5.19 82.2 6 6.18
207
14.1 1.45
466.4 5.88 6.4
195
15.0
4.0
102.1
20
1302-MSWLF-
SW-1
6.99
342 15.4
4.99 360.3
>800 DRY
DRY
DRY
DRY
DRY
6.73 508 21.1
5.13 11.0 4 DRY
DRY
DRV DRY
DRY DRY
DRY
CDLF-1998
SW-2
6.80
241 15.6
3.51 181
590 DRY
DRY
DRY
DRY
DRY
DRY
5.86 528 20.1
5.23 36.7 7 DRY
DRY
DRY DRY
DRY DRY 7.5
306
1 21.1
4.1
1 70.2
1 50
Notes:
1. NS - Not Sampled
2. ps/cm- Microsiemens per centimeter
3. mg/L- milligrams per liter
4. ORP - Oxidation -Reduction Potential
5. Turb. - Turbidity; NTUs - Nephelometric Turbidity Units
6. mVs - millivolts
7. DO -Dissolved Oxygen
8. S.U. - Standard Units
9. Temp. -Temperature; Deg. C- Degrees Celsius
10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced MW-9 as the background monitoring wells.
11. MW-9 was removed from the monitoring program in November 2012.
12. M W-3 deep, -L deep, -and -M are sampled annually during the spring event.
13. (--) CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion.
Smith Page 3 of 5 January 2022

Table 4
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Sampling Event:
No. 48 No. 49 No. 50
1111!CD
11111111
-is (background well)
6.3
130
16.7
5.6
38.6 9
5.26 116
15.0
1.82
242.4
7
5.65
100 15.8 1.49 197.0 3 6.1
122 20.3
4.3 -32.4 9
CD-ld (background well)
6.1
116
15.8
3.6
25.1 30
5.67 114
18.3
1.61
183.2
9
5.88
102 16.0 1.84 190.7 2 6.2
118 20.4
2.4 31.5 3
CD-4 Rep
CD-4
6.0
139
12.5
5.3
4&9 101
5.98 191
14.7
2.46
4&4
10
5.18
111 15.3 1.34 88.3 2 6.0
229 14.7
5.2 -26.1 43
CD-6
__
5.9
219
14.5
0.7
510.5 0
5.23 205
15.5
1.80
90.3
2
6.10
112 17.1 0.84 228.1 2 5.8
211 20.2
0.8 92.4 4
AMW-1d
6.0
412
14.6
0.5
1.8 10
5.56 372
17.9
1.71
91.1
9
6.70
227 17.8 1.04 173.0 1 5.9
378 19.6
2.5 -43.2 9
AMW-2s
5.8
144
13.7
2.9
101.3 2
5.24 154
16.2
1.74
201.1
7
5.60
128 15.0 1.06 1972.3 5.8
145 17.1
2.2 24.1 3
AMW-2d
6.0
274
13.2
0.9
65.3 0
6.08 256
20.2
2.55
165.2
9
6.10
216 15.3 1.44 198.1 4 6.0
260 16.7
0.5 -22.9 1
MW-1
6.4
1,355
12.4
2.0
224.6 7
6.51 140
15.9
1.52
22.4
5
6.02
1,396 14.5 1.27 105.3 13 6.3
1,157 14.9
1.9 -35.8 5
MW-3
6.0
178
15.3
2.8
48.8 8
5.47 170
15.2
1.81
114.5
6
5.79
156 18.4 1.22 208.6 2 5.9
178 17.9
3.1 -16.5 0
MW-3 deep
NS
NS
NS
NS
NS NS
6.98 343
16.0
1.76
17.9
8
NS
NS NS NS NS NS 7.5
339 18.2
0.5 -45 3
MW-9
NS
NS
NS
NS
NS NS
NS NS
NS
NS
NS
NS
NS
NS NS NS NS NS NS
NS NS
NS NS NS
MW-A
5.7
372
9.3
0.6
32.4 1
5.27 449
13.7
1.91
76.7
2
5.6
353 16.9 1.56 54.4 2 5.6
380 16.3
0.2 -47.8 4
1302-MSWLF-
MW-B
6.7
795
9.3
1.3
-64.8 18
6.67 784
16.0
1.05
-64.5
5
6.25
687 15.7 2.53 -4.1 6 6.7
694 14.4
3.1 -36.5 34
CDLF-1998
MW-C
5.8
102
12.3
4.8
162.6 11
5.74 98
15.0
1.37
104.3
3
5.85
657 15.7 0.90 38.5 29 5.5
87 14.7
7.0 64.2 11
MW-D
6.2
858
15.1
1.1
35.4 1
5.92 620
13.8
1.93
36.4
3
5.44
582 14.6 1.29 77.3 6 6.1
637 15.6
4.4 -29.3 3
MW-E Rep
6.2
1,012
13.4
0.3
-16.1 4
6.05 984
17.3
1.68
-1.9
2
6.58
969 18.1 0.77 26.5 3 6.3
1,153 18.3
0.5 -25.2 1
MW-E deep
6.3
1,031
11.6
0.4
-56.2 4
6.29 1,123
16.4
1.88
-30.9
9
NA
NA NA NA NA NA 6.3
1,201 18.3
0.6 -21.8 4
MW-F
6.1
481
11.6
2.5
ll.0 4
6.57 478
14.3
1.55
-69.4
5
6.14
886 14.5 1.31 -17.9 4 6.6
820 14.4
6.6 _33.7 4
MW-G
6.1
586
11.3
2.10
-2.8 15
6.39 1,576
15.0
2.28
-82.9
8
6.02
1,596 15.4 1.81 -24.9 29 6.3
1,266 14.7
1.2 -33.1 31
MW-H
6.5
242
14.7
9.9
-2.6 10
6.23 161
15.0
4.74
118.5
5
5.18
153 13.4 1.35 122.1 20 5.9
145 15.0
3.6 76.2 84
MW-H deep
6.2
165
14.1
5.8
-8.3 173
6.47 261
16.2
2.75
95.2
6
5.61
254 13.4 1.51 114.6 1 6.6
237 15.6
7.5 77.9 8
MW-I
6.1
143
14.8
4.5
-2.9 11
6.15 130
15.8
5.96
115.9
6
5.78
131 13.3 1.69 91.4 15 6.1
125 16.0
7.1 80.0 7
MW-J
6.6
241
14.1
3.3
143.7 67
5.68 245
16.1
2.45
154.5
9
5.89
249 13.4 1.37 84.4 27 6.8
243 14.6
5.4 -25.4 38
MW-K
6.0
173
15.1
3.9
129.8 5
6.06 181
15.9
2.45
140.0
4
5.30
217 13.9 1.25 111.1 7 6.1
173 14.6
5.3 -32.0 22
MW-L
5.8
86
12.5
2.7
100.4 3
5.12 91
14.4
1.87
142.9
7
5.57
85 16.2 1.54 240.6 2 5.8
91 15.1
2.0 -15.8 2
MW-L deep
NS
NS
NS
NS
NS NS
6.10 203
13.7
1.90
160.7
5
NS
NS NS NS NS NS 6.9
209 15.5
4.6 -9.6 0
MW-M
NS
NS
NS
NS
NS NS
6.53 287
15.7
2.84
324.7
2
NS
NS NS NS NS NS 6.5
246 15.5
4.0 30.8 37
MW-X
6.3
185
13.6
3.2
167.5 1
6.28 181
14.7
1.33
137.0
4
5.75
186 13.8 1.49 67.1 1 6.3
179 16.0
4.1 75.2 9
Surface Water
Sample Locations
7.17 357
18.9
4.06
120.1
11
5.33
293 12.5 1.26 126.0 7 7.4
400 16.6
5.9 -18.0 13
1302-MSWLF-
SW-1
7.6
336
6.2
10.1
-73.4 18
CDLF-1998
SW-2
7.2
267
6.4
9.8
2 1. 1 19
6.74 473
19.8
5.07
174.1
9
5.83
302 10.9 1.23 121.7 2 7.0
374 17.2
5.1 66.9 109
Notes.
1. NS - Not Sampled
2. ps/cm- Microsiemens per centimeter
3. mg/L- milligrams per liter
4. ORP - Oxidation -Reduction Potential
5. Turb. - Turbidity; NTUs - Nephelometric Turbidity Units
6. mVs
- millivolts
7. DO - Dissolved Oxygen
8. S.U. - Standard Units
9. Temp. - Temperature; Deg. C - Degrees Celsius
10. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells.
11. MW-9 was removed from the monitoring program in November 2012.
12. M W-3 deep, -L deep, -and -M are sampled annually during the spring event.
13. (--) CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion.
14. NA - Not available. The field sheet for MW-E deep was lost by field personnel during the November 2019 sampling event.
Smith Page 4 of 5 January 2022

Table 4
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Sampling Event:
CD-1s (background well)
5.8 125
17.1
6.00
50.1
9
6.10
137
14.1 3.98
-91.2 10 6.11
136 16.3
3.95
73.6 28
CD -Id (background well)
6.0 120
17.1
4.18
70.4
10
6.04
119
14.1 5.04
-68.8 9 6.42
110 15.9
3.37
67.9 33
CD-4 Rep
6.1 202
18.3
0.51
-40.1
12
6.12
262
11.3 0.80
-202.7 31 6.35
158 16.9
1.49
12.7 9
CD_6
AMW-15
5.6 195
16.3
0.42
61.3
7
5.71
191
13.9 0.67
-168.0 12 5.85
153 16.5
0.93
89.4 20
AMW-Id
5.8 396
16.5
0.30
27.9
39
5.74
382
14.1 1.06
-164.2 6 6.15
382 17.5
0.41
44.5 17
AMW-2s
5.7 151
16.2
2.97
60.3
7
5.71
149
14.0 2.86
-176.4 4 5.88
133 16.1
2.41
78.0 10
AMW-2d
5.8 269
16.5
0.37
12.7
8
5.90
277
14.2 0.41
-93.0 4 6.10
236 16.4
0.66
56.1 4
MW-1
6.3 1,411
16.5
0.23
24.9
8
6.28
1,411
13.8 0.79
-160.0 10 6.70
1,159 16.3
2.02
-1.6 9
MW-3
5.7 189
17.0
4.75
30.8
9
5.84
180
13.7 3.65
-61.2 7 6.11
223 16.2
2.37
75.3 39
MW-3 deep
NS NS
NS
NS
NS
NS
6.89
351
13.7 1.22
-162.0 9 NS
NS NS
NS
NS NS
MW-9
NS NS
NS
NS
NS
NS
NS
NS
NS NS
NS NS NS
NS NS
NS
NS NS
MW-A
5.4 384
16.8
0.59
-18.4
7
5.51
378
14.1 0.62
-184.1 9 5.98
367 16.9
0.58
17.3 17
1302-MSWLF-
CDLF-1998
MW-B
MW-C
MW-D
6.5 861
5.8 354
5.8 665
18.8
18.6
16.9
0.22
0.31
0.32
-59.0
11.7
17.9
13
9
8
6.61
5.71
6.07
722
107
640
13.5 1.14
12.8 2.41
13.0 3.57
-167.8 10 6.68
-162.7 43 6.11
-183.1 9 6.01
676 16.1
370 17.1
526 17.0
0.45
0.74
0.41
-4.3 16
2.7 31
24.0 9
MW-E Rep
6.2 152
17.8
0.29
-0.8
9
6.27
361
14.1 0.40
-119.2 9 6.48
1,053 18.0
0.34
29.2 31
MW-E deep
6.3 1,158
17.9
0.27
-36.8
10
6.22
1,221
13.9 0.91
-152.1 14 6.65
907 18.2
0.40
-33.1 46
MW-F
6.3 1,077
16.3
0.56
-56.9
8
6.48
421
13.7 4.21
-143.0 10 6.63
1,022 16.1
0.75
-21.0 11
MW-G
6.2 1,684
18.1
0.29
_84.5
14
6.23
1,486
13.8 0.71
-114.2 9 6.72
1,490 16.5
2.31
-43.2 10
MW-H
5.6 142
18.0
4.10
59.5
13
5.71
144
13.6 3.57
-194.7 9 5.84
137 15.7
1.90
82.9 19
MW-H deep
5.9 239
15.7
2.15
55.3
13
5.91
244
13.8 3.71
-123.7 7 6.09
211 15.0
1.57
73.0 5
MW-I
5.8 122
16.0
7.38
56.5
9
6.02
127
13.6 7.68
-160.0 7 5.98
95 15.3
6.18
82.8 10
MW-J
6.4 263
15.1
4.61
39.7
10
6.51
257
12.1 5.01
-202.1 7 6.71
262 17.1
1.21
44.1 5
MW-K
5.6 182
16.2
2.84
57.0
12
5.46
190
128 2.17
-211.1 9 582
190 162
698
78.4 5
MW-L
5.6 93
16.6
2.79
50.4
14
5.62
96
14.1 262
91.2 8 5.95
-582
94 15.7
3.15
75.4 46
MW-L deep
NS NS
NS
NS
NS
NS
637
211
13.8 3.12
7 NS
NS NS
NS
NS NS
iviNS
NS
NS
NS
NS
NS
6.47
271
13.7 3.04
-95.1 4 NS
NS NS
NS
NS NS
MW-%
6.0 186
16.3
0.41
78.2
5
5.81
159
12.1 2.11
-161.5 8 6.38
170 16.2
0.80
59.0 4
Surface Water
Sample Locations
31.7
32
7.22
347
11.2 7.91
-117.8 25 NS
NS NS
NS
NS NS
1302-MSWLF-
SW-1
7.3 174
10.43
23.7
CDLF-1998
SW-2
7.6 130
17.1
9.91
29.6
27
7.19
232
11.5 8.81
-126.0 38 NS
NS NS
NS
NS NS
Notes:
1. NS - Not Sampled
2. ps/cm- Microsiemens per centimeter
3. mg/L- milligrams per liter
4. ORP - Oxidation -Reduction Potential
5. Turb. - Turbidity; NTUs - Nephelometric Turbidity Units
6. mVs - millivolts
7. DO - Dissolved Oxygen
8. S.U. - Standard Units
9. Temp. - Temperature; Deg. C - Degrees Celsius
10. The November 2012 sampling event was the first event that CD-Is/CD-Id replaced MW-9 as the background monitoring wells.
11. MW-9 was removed from the monitoring program in November 2012.
12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event.
13. (--) CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion.
14. SW-1 and -2 were dry during the November 2021 sampling event.
Smith Page 5 of 5 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
,,,
15
100
,,,
CD-1s
3-May-11
81.41
0.191
5.45JB
4.23J
16.0
2.321
5.931
0.141
20.61
26.5
CD-ls
8-Nov-11
59.71
0.25JB
4.461
2.67J
12.4
1.91
4.411
0.08J
11.21
18.2
CD-1s
7-May-12
45.51
3.301
1.191
8.751
1.12J
3.011
12.71
12.6E
CD-15
28-Nov-12
63.81
0.111
5.651
3.05J
11.6
1.431
4.661
17.11
16.9
CD-1s
7-May-13
0.94J
2.4JB
35.61
0.881
0.67J
4.041
0.391
1.781
0. 13J
6.061
5.08J
CD-1s
5-Nov-13
46.81
0.12J
3.591
1.63J
10.2
1.351
3.501
18.41B
15.413
CD-1s
6-May-14
28.81
4.14JB
1.481
0.111
1.031
0.311
3.401
2.98JB
CD-1s
4-Nov-14
28.71
0.131
1.31.1
0.06J
1.04J
0.11J
2.571B
1.581
CD-1s
5-May-15
1.63J
29.5JB
1.331
0.15J
1.17J
2.401
2.75JB
CD-1s
27-Oct-15
28.41
0.80J
0.391
0.75J
0.12J
1.21.1
4.19CN,J 0.151
4.101
3.3613-01)
1302-MSWLF-
CD-1s
17-May-16
29.31
0.941
0.991
0.121
1.011
4.701
1.931
CDLF-1998
CD-1s
1-Nov-16
30.51
1.23.1
1.36.1
0.28.1
1.35.1
4.301
CD-1s
9-May-17
34.31
1.17J
1.261
0.201
0.971
6.691
1.821
CD-1s
31-Oct-17
0.521
36.31
1.81.1
0.541
2.87.1
0.37.1
1.41.1
6.911
4.001
CD-1s
11-Jun-18
29.51
5.71
4.01
CD-1s
17-Dec-18
26.71
0.601
3.6.1
15.0.1
7.0.1
9.51
CD-1s
7-May-19
29.8
1.31
7.01
5.11
CD-1s
5-Nov-19
31.9
1.01
1.8J13
0.0701
0.73J
S.O1
7.318
CD-1s
18-May-20
0.46J
34.5
2.21
0.921
0.231
1.41
6.41
6.91
CD-1s
23-Sep-20
34
1.31
1.5.1
4.91
4.21
CD-1s
17-Mar-21
42
1.31
4.1.1
5.81
CD-1s
17-Nov-21
34
4.0.1
34
CD-1d
3-May-11
2.44J
231
2.03
16.7
18.6
112
14.0
22.31
0.111
101
103
CD-1d
8-Nov-11
74.51
0.511
4.081
4.271
27
2.841
5.681
24.61
26.3
CD-1d
7-May-12
72.41
0.581
3.911
4.67J
25
2.811
5.581
26
27.9E
CD-1d
28-Nov-12
0.331
37.71
0.071
2.381
0.941
12.6
1.14J
2.50J
8.901
13
CD-1d
8-May-13
0.881
1.02JB
31.21
0.07J
0.781
4.51
0.491
1.921
6.18J
13.1
CD-1d
5-Nov-13
35J
0.861
4.34.1
1.13J
1.90J
17.11B
10.813
CD -Id
6-May-14
1.14J
37.81
0.07J
0.05J
3.22JB
1.161
7.341
0.811
2.741
0.121
6.161
9.41JB
CD-1d
4-Nov-14
43.11
0.16J
0.111
2.251
9.09J
0.87.1
2.88.1
10.21B
10.7
CD-1d
S-May-15
34.5JB
0.84J
3.631
0.391
1.421
5.181
3.68JB
CD-1d
27-Oct-15
0.42J
42.3.1
0.13J
1.871
2.151
S.181
0.97J
2.491
4.37CN,J
0.061
10.91
14.08-01
1302-MSWLF-
CD -Id
17-May-16
81.31
0.46J
4.861
7.42J
26.0
3.131
7.111
2.111
0.071
29.3
29.7
CDLF-1998
CD-1d
1-Nov-16
32.6.1
1.191
0.771
2.82J
0.33J
1.24J
7.961
4.29J
CD -Id
9-May-17
33.91
1.271
0.521
1.811
6.921
1.091
6.951
3.12J
CD-1d
31-Oct-17
29.5.1
0.681
0.611
0.111
0.641
5.831
1.24J
CD -Id
12-Jun-18
32.41
2.51
1.01
6.91
3.2J
CD-1d
17-Dec-18
31.9.1
9.31
2.31
0.411
3.01
6.81
4.11
CD -Id
7-May-19
30.7
1.4.1
7.41
2.9J
CD-1d
5-Nov-19
0.48J
30.1
1.91
1.11B
0. 13J
1.81
4.71
8.21B
CD -Id
18-May-20
29.1
0.64J
0.33.1
5.6.1
2.0J
CD-1d
22-Sep-20
0.67J
38
1.91
8.6
0.991
4.21
8.8
36
CD-1d
16-Mar-21
27
4.8.1
3.1J
CD-1d
17-Nov-21
33
2.41
0.421
1.51
6.01
5.81
CD-4 Rep
3-May-11
206
0.9J13
17.6
0.62J
8.39.1
2.721E
CD-4 Rep (dup)
3-May-11
0.21J
206
17.9
0.681
8.981
0.17J
2.85J
CD-4 Rep
8-Nov-11
0.14J
191
0.93J
18.2
1.00J
8.86.1
9.44J
CD-4 Rep
9-May-12
184
1.691
18.1
1.701
11.31
3.031
16.1B
CD-4 Rep
29-Nov-12
172
13.7
0.62J
7.03J
2.84J
2.141E
CD-4 Rep
10-May-13
75.51
0.51
2.711
7.87J
1.941
11.2J
11.11
10.3
CD-4 Rep
7-Nov-13
1.36J
60.4J
0.35J
0.07J
0.77.1
5.311
1.83.1
5.11.1
0. 13J
32
4.40JB
CD-4 Rep
7-May-14
62.41
0.31J
0.05J
3.25JB
5.021
1.701
6.52J
22.21
2.971B
CD-4 Rep
5-Nov-14
70.0J
0.31J
2.59J
1.46.1
4.29.1
14.8JB
6.851
CD-4 Rep
6-May-15
58.4.1
0.39J
1.13J
5.941
1.901
0.53J
4.72J
14.01
2.99.1
CD-4 Rep
28-Oct-15
0.79J
57.9.1
0.32J
2.181
5.861
8.951
1.26.1
30.7J
4.14CN,J
13.9J
8.34E-01,J
1302-MSWLF-
CDLF-1998
CD-4 Rep
18-May-16
1.091
56.21
0.46J
1.241
7.31J
1.021
0.661
5.431
18.01
3.70J
CD-4 Rep
2-Nov-16
46.3.1
0.27J
1.351
1.591
1.18J
0.901
4.18.1
1.111
18.11
8.81J
CD-4 Rep
9-May-17
53.81
0.46J
0.951
5.911
1.721
0.521
4.381
10.51
3.731
CD-4 Rep
31-Oct-17
45.0.1
0.181
0.971
0.82J
0.581
0.451
2.75.1
1.881
7.68J
2.76J
CD-4 Rep
6-Jun-18
52.91
0.41J
3.41
0.741
3.31
13.3J
4.01
CD-4 Rep
19-Dec-18
1.11
50.9J
0.96J
4.61
5.51
2.61
2.9.1
7.01
1.41
15.51
11.6
CD-4 Rep
8-May-19
45.9
0.38J
2.31
7.0
1.41
1.1
5.8
6.21
13.7
CD-4 Rep
7-Nov-19
1.41
31.5
0.40J
1.81
1.31
1.41B
0.83.1
3.81
21.0
9.5JB
CD-4 Rep
20-May-20
1.3J6
70.9
0.48J
0.981
6.6
0.771
0.571
5.1
11.6
12.5
CD-4 Rep
23-Sep-20
56
0.52
2.21
3.11
1.51
1.4
5.6
11
7.3J
CD-4 Rep
18-Mar-21
1.91
43
0.83
5.8
6.7
2.31
7.4
26
10
CD-4 Rep
17-Nov-21
66
0.28J
6.0
1.4B1
0.61J
4.41
11
3.21
CDWI
Page 1 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
1302-MSWLF-
CDLF-1998
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
CD-6
12 E
4-May-11 66.61 0.42J
9-Nov-11 59.61 0.26J
9-May-12 57.81 0.20J
29-Nov-12 50.81 0.131
30-May-13 61.41 0.36J
7-Nov-13 0.57J 3.771 298 0.14J
7-May-14 38.51 0.101
5-Nov-14 120 0.881
6-May-15 47.41 0.20J
28-Oct-15 4.971 215 2.03
18-May-16 1.92J 62.21 0.21
2-Nov-16 1.891 63.71 0.331
,,, 15 100 ,,,
6.741 4.081 4.61 2.011 5.341 0.11 24.71 14
4.711 2.621 7.891 1.311 5.221 15.81 9.621
4.201 2.081 3.631 1.211 4.481 17.21 17.76
2.251 1.801 1.861 0.731 3.731 12.31 6.61JB
5.891 3.02J 4.121 1.431 4.771 20.41 13.8
18.3 36.9 2.131 11.71 1.07J 14.61 6.88JB
3.42JB 1.041 0.071 2.301 4.391 2.40JB
7.641 8.021 8.021 3.831 9.04J 0.14J 50.613 25.7
1.60J 1.841 2.771 0.811 3.291 10.51 5.401
32.3 19.5 25.6 26.1 21.61 8.64.1 4.05CN,1 0.371 107 73.913-01
3.461 13.2 2.571 1.581 8.701 1.011 12.61 7.941
6.181 13.3 3.121 2.871 9.121 1.291 17.31 10.1
AMW-1s
3-May-11
104
0.92J
1.4113
0.311
2.081
0.51
3.591
0.081
8.118
AMW-1s
8-Nov-11
105
0.901
1.431
0.461
1.941
0.441
3.671
0.101
8.471
AMW-1s
7-May-12
103
0.86J
2.391
1.871
0.221
3.871
2.98J
8.49JB
AMW-1s
28-Nov-12
0.191
97.41
0.831
0.781
0.781
0.11J
3.31.1
2.411
4.791
AMW-1s
8-May-13
101
0.87J
1.981
0.091
4.051
2.241
6.13J
AMW-1s
6-Nov-13
981
0.911
0.221
2.91.1
0.32.1
4.06J
16.71B
6.701B
AMW-1s
7-May-14
93.01
0.95J
2.44JB
0.281
2.271
0.471
3.911
1.39J
6.35JB
AMW-1s
5-Nov-14
89.21
1.06
0.501
3.37.1
0.78.1
4.15.1
4.011B
7.601
AMW-1s
7-May-15
87.61
0.97J
3.781
0.311
2.721
0.681
5.861
3.311
6.511
AMW-1s
29-Oct-15
82.51
0.781
1.03J
0.71.1
0.19J
4.03J
3.18CN,J
4.221
9.8213-01)
1302-MSWLF-
AMW-1s
18-May-16
0.27J
0.82J
85.41
1.03
1.431
0.381
2.471
0.921
4.161
5.181
7.431
CDLF-1998
AMW-1s
2-Nov-16
71.71
0.561
0.551
3.191
5.781
AMW-1s
30-May-17
92.41
0.71
0.611
0.361
3.911
2.601
5.451
AMW-1s
1-Nov-17
68.21
0.661
0.891
0.541
0.14J
2.711
3.341
6.371
AMW-1s
8-Jun-18
91.91
0.77J
5.21
3.91
4.4.1
17.7
AMW-1s
19-Dec-18
86.41
0.891
3.91
3.11
5.91
AMW-1s
8-May-19
80.9
0.70
3.61
2.4.1
6.51
AMW-1s
6-Nov-19
1.61
60.5
0.65
0.421
4.1113
2.41
9.71
9.6113
AMW-1s
18-May-20
0.55J
78.9
0.78
0.661
0.261
6.8
4.6.1
8.31
AMW-1s
23-Sep-20
72
0.91
4.01
2.11
0.601
6.5
3.21
8.6.1
AMW-1s
17-Mar-21
1.01
34
0.28J
1.41
15
AMW-1s
17-Nov-21
2.0
34
0.41
1.41
1.51
0.371
1.41
3.21
9.6.1
AMW-1d
3-May-11
0.24J
129
0.12J
4.67J
2.081
0.251
9.161
0.191
9.17JB
AMW-1d
8-Nov-11
0.181
140
0.07J
0.941
5.781
1.641
0.211
10.21
0.251
7J
AMW-1d
7-May-12
0.29J
135
5.20J
2.171
0.271
9.171
2.691
8.98JB
AMW-1d
28-Nov-12
0.41J
106
0.14J
1.381B
3.27J
2.261
0.521
6.211
5.50J
AMW-1d
8-May-13
1.05JB
133
4.53J
1.631
0.251
7.811
3.081
AMW-1d
6-Nov-13
133
1.881
4.31J
1.771
0.451
7.451
20.51B
4.30JB
AMW-1d
7-May-14
143
0.50J
0.05J
L 11.48
5.48J
4.901
3.011
9.841
5.891
27.913
AMW-1d
5-Nov-14
1.46J
168
0.69J
0.05J
4.491
6.70J
6.531
4.141
11.81
13.8JB
20.8
AMW-1d
7-May-15
133
0.40J
4.081
5.511
3.581
2.141
9.831
5.471
10.3
AMW-1d
29-Oct-15
1.41J
123
0.18J
3.021
5.321
1.061
0.931
8.61J
3.57CN,J
4.001
6.7913-01,1
1302-MSWLF-
AMW-1d
18-May-16
1.011
131
0.191
2.091
6.06J
1.521
0.841
9.031
2.521
6.841
CDLF-1998
AMW-1d
3-Nov-16
128
0.17J
2.201
6.09J
1.12J
0.811
9.30J
6.65.1
AMW-1d
30-May-17
0.62B-01,J
131
0.12J
1.301
5.501
0.661
0.491
8.071
1.391
5.111
AMW-1d
1-Nov-17
0.85J
128
0.14J
0.931
6.07J
1.391
0.451
9.601
5.491
AMW-1d
8-Jun-18
1.21
153
0.26J
2.91
7.31
2.01
1.41
12.41
4.21
14.2
AMW-1d
19-Dec-18
0.71J
127
0.16J
6.61
0.311
10.11
2.21
5.01
AMW-1d
8-May-19
167
0.14J
6.3
9.8
6.1J
AMW-1d
6-Nov-19
1.51
60.4
0.65
0.451
0.38113
0.0771
2.31
9.21
26.513
AMW-1d
18-May-20
1.2.1
112
0.15J
0.881
6.5
0.55J
0.24.1
10.3
4.3.1
8.41
AMW-1d
23-Sep-20
4.7
210
1.4
29
12
16
9.2
28
4.81
0. 16J
29
60
AMW-1d
17-Mar-21
41
0.45
AMW-1d
17-Nov-21
110
0.16J
1.51
5.7
1.51
0.741
12
7.61
CDWI
Page 2 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
12 E
,,, 15 100 ,,,
AMW-2s
3-May-11
52.11 0.92J
2.49JB 1.101 1.411 2.21 2.541 7.171 6.47JB
AMW-2s
8-Nov-11
42.31 0.50J
1.361 0.291 0.821 2.191 1.361 5.081
AMW-2s
8-May-12
42.81 0.45J
1.481 0.231 2.851 0.661 1.471 3.771 5.92JB
AMW-2s
29-Nov-12
45.31 0.48J
1.021 0.231 0.62J 0.32J 1.19J 1.411
AMW-2s
9-May-13
42.61 0.57J
1.111 0.521 1.061 0.631 1.951 3.091 3.631
AMW-2s
6-Nov-13
40.11 0.54J
0.271 0.641 0.421 1.481 16.8JB 3.51JB
AMW-2s
7-May-14
43.71 0.56J
2.16JB 0.301 0.871 0.351 1.411 1.96JB
AMW-2s
5-Nov-14
46.01 0.691
0.441 1.011 0.591 1.881 2.841
AMW-2s
6-May-15
2.72J 43.41 O.S3J
1.071 0.391 1.461 2.071 2.371
AMW-2s
28-Oct-15
1.021 50.61 0.881
1.561 0.751 0.501 1.231 1.961 6.12CN,J 6.231 6.14B-01,J
1302-MSWLF-
AMW-2s(dup)
28-Oct-15
1.001 51.11 0.85J
1.791 0.871 0.571 1.341 2.101 3.34CN,J 7.011 7.018-01,1
CDLF-1998
AMW-2s
17-May-16
45.81 0.691
1.15J 0.651 0.481 0.711 1.631 0.101 4.511 3.931
AMW-2s
1-Nov-16
46.51 0.71
1.601 0.581 0.571 0.741 1.811 5.171
AMW-2s
10-May-17
0.62B-01,1 42.71 0.471
0.951 0.17J 1.021 3.581 1.62.1
AMW-2s
1-Nov-17
43.61 0.54J
0.881 0.531 0.261 1.17J 3.64J 3.211
AMW-2s
8-Jun-18
45.91 0.471
1.41 3.7.1 3.01
AMW-2s
20-Dec-18
39.01 0.39J
9.81 3.71 5.81
AMW-2s
7-May-19
44.1 0.55
1.61 1.41 4.31 3.41
AMW-2s
6-Nov-19
1.21 40.2 0.42J
0.751 0.3318 0.0911 0.881 9.81 150
AMW-2s
19-May-20
40.6 0.391
0.781 0.211 0.871 1.5J 3.1J
AMW-2s
23-Sep-20
43 0.71
0.661 1.51 4.11 3.61
AMW-2s
17-Mar-21
J 86
1.51 2.11 12
AMW-2s
17-Nov-21
37 0.49
AMW-2d
3-May-11
55.21
2.861B
0.831
1.031
AMW-2d
8-Nov-11
47.51
1.081
0.121
0.771
1.231
AMW-2d
8-May-12
78.21
1.261
3.201
0.331
1.221
2.791
10.513
AMW-2d
28-Nov-12
69.1J
0.881
2.341
0.391
2.561
4.761
AMW-2d
9-May-13
54.71
1.751
0.061
1.421
4.031
2.41
AMW-2d
6-Nov-13
71.11
2.431
2.691
18.51E
7.86JB
AMW-2d
7-May-14
57.01
0.101
2.081B
0.841
1.241
0.76JB
AMW-2d
S-Nov-14
60.41
0.07J
1.251
2.331
1.091E
5.041
AMW-2d
6-May-15
1.28J
67.41
0.851
1.671
AMW-2d
28-Oct-15
0.25J
63.91
0.451
0.14J
1.501
2.79CN,J
2.651
7.418-01,J
1302-MSWLF-
AMW-2d
17-May-16
64.51
0.13J
1.371
1.071
1.381
CDLF-1998
AMW-2d
2-Nov-16
67.71
0.101
0.661
1.901
5.021
AMW-2d
10-May-17
0.65B-01,J
70.11
0.14J
3.631
0.241
1.321
4.531
AMW-2d
2-Nov-17
74.21
0.16J
1.481
2.001
AMW-2d
8-Jun-18
75.71
0.17J
2.1J
3.11J
3.11
AMW-2d
20-Dec-18
75.31
0.20J
0.581
4.11
AMW-2d
7-May-19
74.6
0.18J
2.71
2.71
3.31
11.6
AMW-2d
6-Nov-19
0.75J
2.31
73.2
0.101
1.11
1.8113
0.211
2.81
8.6J
108
AMW-2d
19-May-20
72.4
0.20J
0.381
0.281
0.0691
1.61
2.61
AMW-2d
23-Sep-20
0.981
68
1.61
0.441
1.91
14
AMW-2d
17-Mar-21
120
2.51
4.9J
2.01
0.881
13
20
6.8
AMW-2d
16-Nov-21
67
0.181
1.91
8.71
MW-1
4-May-11
0.46J
5.081
360
0.91
0.091
9.051
19.7
11.8
4.591
20.81
2.391
0.091
35.7
40.4
MW-1
9-Nov-11
2.22J
187
0.52J
16.8
6.671
0.641
37.71
3.351
3.711
MW-1
9-May-12
201
0.16J
0.06J
2.261
17.8
17.0
3.61J
42.41
6.901
12.21
13.913
MW-1
28-Nov-12
153
1.01
0.751
12.6
5.541
0.751
29.91
5.751
4.861
3.551
MW-1
10-May-13
172
0.12J
0.26J
0.871
15.9
9.481
0.3J
35.11
8.861
8.671
MW-1
6-Nov-13
127
0.31J
11.5
8.661
1.12J
28J
5.891
11.91E
2.641E
MW-1
7-May-14
1.991
120
0.06J
0.28J
10.3
10.2
0.28J
28.21
5.611
0.101
6.991
1.93J
MW-1(dup)
7-May-14
119
0.05J
0.31J
10.5
10.2
0.291
28.01
5.701
6.161
1.911
MW-1
4-Nov-14
2.27J
126
0.05J
0.44J
12.5
9.071
0.951
31.1J
2.401
5.471B
1.72J
MW-1
5-May-15
0.81
128
0.17J
11.6
7.741
0.231
29.91
2.991
3.77J
1.88J
MW-1
28-Oct-15
144
0.36J
1.521
14.4
8.261
1.151
33.31
4.32CN,J
3.631
4.248-01,1
MW-1
19-May-16
144
0.34J
0.511
12.8
12.0
0.281
29.41
2.591
1.991
1302-MSWLF-
MW-1
2-Nov-16
143
0.39J
13.7
8.641
0.631
30.41
3.02J
CDLF-1998
MW-1
30-May-17
150
0.17J
0.511
12.5
6.821
0.321
29.41
3.291
2.051
MW-1
31-Oct-17
132
0.43J
0.761
12.4
7.781
0.781
29.01
3.15J
3.051
MW-1
7-Jun-18
0.91
1.21
146
0.21J
13.1
7.81
0.481
29.61
4.2J
MW-1(dup)
7-Jun-18
0.87J
148
0.34J
13.6
8.31
0.551
31.31
7.01
MW-1
19-Dec-18
136
0.68J
12.2
6.31
0.681
30.01
2.61
3.01
MW-1
9-May-19
0.46J
133
12.7
3.11
0.131
28.9
1.51
2.51
MW-1(dup)
9-May-19
135
12.3
2.71
0.121
27.8
2.51
MW-1
6-Nov-19
135
3.8
12.9J,D3
20.O1,B,D3
1.2
30.4D3
3.61,03
MW-1(dup)
6-Nov-19
146
4.2D3
13.1J,D3
19.51,13,D3
1.3
31.5D3
8.71,13,D3
MW-1
20-May-20
0.73JB
111
0.37J
0.571
9.5
8.9
0.411
24.1
3.2.1
3.71
MW-1
25-Sep-20
120
0.24J
1.41
8.2
5.7
1.2
25
3.01
4.41
11
MW-1
18-Mar-21
150
0.14J
12
3.31
2.0
31
2.5.1
3.61
2.51
MW-1
18-Nov-21
100
0.16J
7.4
2.9131
0.931
25
3.91
Smth Page 3 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
,,,
15
100
,,,
MW-3
4-May-11
36.21
0.32J
4.19JB
1.561
1.641
1.14J
2.341
0.111
6.8J
7.681
MW-3
9-Nov-11
35.21
0.25J
2.561
1.221
1.601
11
2.031
8.11
MW-3(dup)
9-Nov-11
37.11
0.24JB
2.301
1.201
1.551
1.011
2.001
6.291
MW-3
8-May-12
30.11
2.071
0.64J
1.691
0.791
2.231
3.761
7.631B
MW-3
28-Nov-12
28.61
2.301
0.32J
0.841
0.431
1.201
3.54J
1.981
MW-3
9-May-13
37.91
0.51J
3.281
1.53J
1.811
2.211
2.361
6.151
8.11
MW-3
7-Nov-13
0.50J
37.91
0.47J
0.09J
3.931
1.781
3.551
4.171
4.471
24.7J
82B
MW-3
8-May-14
56.21
0.701
3.321
2.45J
3.081
3.281
3.541
8.621
36.6
MW-3
6-Nov-14
30.81
0.05J
1.14JB
0.40J
1.03J
0.42.1
1.56.1
3.85J
3.57JB
MW-3
6-May-15
0.811
55.41
0.711
4.141B
2.59J
3.171
3.691
4.361
0.07J
11.31
15.3
1302-MSWLF-
MW-3
28-Oct-15
25.01
1.231
0.25J
0.83.1
4.17CN,J
3.12J
5.438-01,1
CDLF-1998
MW-3
18-May-16
1.461
0.351
0.991
3.48J
2.101
MW-3
2-Nov-16
27.41
1.601
0.25J
1.00J
2.361
MW-3
11-May-17
32.01
0.131
2.001
0.631
0.551
1.291
3.651
2.931
MW-3
1-Nov-17
27.61
1.451
0.07J
0.89.1
2.40J
MW-3
7-Jun-18
0.631
28.01
0.0511
1.31
2.41
3.51
MW-3
19-Dec-18
31.11
0.14J
1.81
0.31J
1.0.1
2.71
2.31
MW-3
8-May-19
32.5
0.0741
1.61
2.7.1
2.31
MW-3
6-Nov-19
1.41
30.9
0.12J
0.21J
1.51
0.4418
0.34J
0.96.1
10.1
7.51B
MW-3
19-May-20
0.57J
31.4
1.21
0.701
4.61
4.21
MW-3
23-Sep-20
34
0.35J
1.61
1.1
1.3.1
3.51
4.91
MW-3
17-Mar-21
34
1.51
MW-3
17-Nov-21
30
34
MW-3 Deep
5-May-11
L 2.47J
3.11J
195
1.73
1.24
26
14
55.4
0. 17J
0.55J
77.3
81
MW-3 Deep
9-May-12
0.35J
38.31
0.93J
2.12.1
1.71JB
MW-3 Deep
10-May-13
0.411
37.71
0.12J
0.091
2.181B
0.131
1.321
0.17J
2.491
2.571
MW-3 Deep
8-May-14
40.81
0.13J
4.30J
1.59.1
0.98.1
2.78.1
5.441
MW-3 Deep
6-May-15
0.261
2.161
44.01
0.131
0.291
1.901
1.721
2.471
33.2
1302-MSWLF-
MW-3 Deep
28-Oct-15
1.02J
42.21
0.70J
0.50J
0.64.1
0.57.1
3.00CN,J
5.878-01,1
CDLF-1998
MW-3 Deep
19-May-16
1.501
43.01
0.691
0.611
0.401
0.581
2.371
3.261
MW-3 Deep
11-May-17
0.76J
0.71J
44.1.1
0.55.1
0.80J
0.43.1
0.68.1
2.061
MW-3 Deep
7-Jun-18
0.811
50.31
3.6.1
MW-3 Deep
8-May-19
0.71
56.9
5.71
MW-3 Deep
19-May-20
1.4JB
52.6
0.441
0.621
0.101
0.641
1.7.1
5.3.1
MW-3 Deep
19-Mar-21
57
1.4.1
12
1302-MSWLF-
MW-9
3-May-11
11.81
1.44JB
0.271
3.871
0.611
5.871
4.621B
CDLF-1998
MW-9
9-Nov-11
9.87.1
1.73.1
0.161
2.04J
0.54.1
4.771
MW-9
9-May-12
13.71
1.331
0.341
5.651
0.091
0.801
8.371
6.191B
MW-A
3-May-11
40J
0.15J
1.38JB
3.48J
0.87.1
12.5.1
3.86JB
MW-A
9-Nov-11
0.36JB
44.21
0.13J
1.811
0.761
9.321
2.821
MW-A
9-May-12
42.4.1
0.101
1.14J
8.20J
0.91.1
15.5.1
4.53JB
MW-A
27-Nov-12
0.36JB
45.61
0.13J
0.971
2.86J
1.17J
11.61
1.861
2.631
MW-A
7-May-13
43.7.1
0.14J
0.64.1
1.48J
1.48.1
0.07J
9.14.1
1.09J
2.311
MW-A
5-Nov-13
43.41
1.651
2.05J
0.761
9.931
20.31B
3.37JB
MW-A
6-May-14
44.2.1
0.14J
3.73JB
8.881
0.84J
16.6.1
1.15J
2.10JB
MW-A
4-Nov-14
45.11
0.20J
6.14J
0.941
18.71
1.411
1.87.1
MW-A
S-May-15
46.9.1
0.15J
3.44J
0.84.1
13.4.1
1.41J
1.821
MW-A
27-Oct-15
0.26J
47.21
0.14J
3.15J
1.181
0.17J
12.91
2.25CN,1
2.14J
5.2313-01,J
1302-MSWLF-
MW-A
17-May-16
0.35J
1.011
44.3.1
0.17J
9.54J
0.48.1
19.8.1
2.401
1.641
CDLF-1998
MW-A
1-Nov-16
48.61
0.17J
7.25J
19.2J
3.85.1
MW-A
9-May-17
0.45B-01,J
48.9.1
0.16J
4.69J
0.40J
14.7.1
1.801
MW-A
31-Oct-17
50.91
0.15J
4.83J
0.271
15.11
1.971
MW-A
7-Jun-18
52.8.1
0.14J
4.61
2.7.1
29.8.1
22.0
MW-A
20-Dec-18
52.31
0.0901
5.5J
16.81
2.91
MW-A
9-May-19
56.0
0.191
11.2
25.2
1.51
31.9
6.01
MW-A
5-Nov-19
50.8
0.17J
13.0
0.83113
0.0661
22.0
8.21E
MW-A
19-May-20
47.8
0.16J
10.5
0.451
19.8
4.61
MW-A
23-Sep-20
47
0.15J
1.91
7.0
2.61
0.251
18
17
MW-A
17-Mar-21
64
0.40
40
1.61
32
9.71
MW-A
16-Nov-21
46
0.22J
15
18
CDWI
Page 4 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
,,,
15
100
,,,
MW-B
4-May-11
2.35J
269
0.28J
3.78JB
18
3.451
1.361
11.31
3.18J
0.14J
9.951
MW-B
9-Nov-11
2.59J
249
0.06J
8.75J
1.511
0.701
8.911
3.54.1
0.131
3.61
MW-B
9-May-12
191
8.68J
0.891
0.091
6.351
15.96
MW-B
29-Nov-12
5.88J
268
23.5
1.081
0.201
9.101
2.29.1
3.581
MW-B
30-May-13
2.55J
197
9.39J
1.11
0.291
6.41
2.891
10.7
MW-B
6-Nov-13
2.02J
225
11.7
0.971
0.231
6.721
1.49.1
3.77JB
MW-B
8-May-14
2.73J
236
0.081
11.5
1.251
0.551
8.801
1.48J
5.81J
3.141
MW-B
4-Nov-14
6.041
226
0.061
21.0
1.12J
0.18J
12.1.1
2.751
2.62JB
1.521
MW-B
5-May-15
0.30J
1.501
160
8.501
1.251
0.341
7.051
2.251
1.971
MW-B
29-Oct-15
2.611
171
0.521
16.5
0.531
0.311
5.451
2.39CN,J 0.071
7.3913-01)
1302-MSWLF-
MW-B
19-May-16
0.30B-01,J
2.16J
225
1.051
11.7
0.811
0.391
6.531
0.061
W.64J
3.54J
CDLF-1998
MW-B
3-Nov-16
2.431
196
13.5
0.241
6.841
2.71J
MW-B
30-May-17
1.73B-01,J
258
0.581
9.201
0.451
0.351
5.541
0.061
3.15J
2.03J
MW-B
31-Oct-17
3.551
256
0.771
14.9
0.291
0.091
7.281
2.08J
MW-B
6-Jun-18
4.81
251
0.191
2.31
15.8
2.11
0.971
7.81
0.151
04.9.1
6.3J
MW-B
19-Dec-18
0.781
172
0.0711
9.61
0.361
5.51
15.1
MW-B
9-May-19
0.38J
175
7.3
0.271
0.301
5.5
2.51
MW-B
6-Nov-19
207
8.51,D3
0.29113
5.61,D3
MW-B
20-May-20
0.72JB
158
0.68J
8.4
0.471
0.381
4.81
1.11
4.21
MW-B
25-Sep-20
2.0
230
0.161
1.31
11
0.681
6.9
3.71
6.11
MW-B
18-Mar-21
1.61
230
12
0.291
6.8
1.41
MW-B
18-Nov-21
150
8.2
4.41
MW-C
4-May-11
42.31
0.44J
0.07J
7.321
S.63J
2.581
1.451
4.141
0.081
7.261
9.971
MW-C
9-Nov-11
15.51
0.151
0.101
0.621
3.431
1.061
0.431
4.191
8.621
MW-C
9-May-12
43.51
0.41
7.451
17
3.941
2.301
6.851
10.41
22.2E
MW-C
29-Nov-12
35.81
0.131
2.751
9.051
1.17J
0.711
3.941
4.87J
8.071
MW-C
9-May-13
19.71
0.24J
2.961
0.75J
1.361
0.81
1.771
3.481
10.1
MW-C
6-Nov-13
31.71
0.261
3.771
9.54J
1.791
0.821
3.741
23.5JB
18.813
MW-C
7-May-14
19.61
0.17J
2.98JB
3.201
0.791
0.261
1.651
3.08JB
MW-C
5-Nov-14
47.21
0.101
0.571
1.681
4.20J
1.301
0.291
4.741
2.11JB
3.061
MW-C
6-May-15
20.41
0.30J
2.381
2.26J
1.661
0.911
2.341
3.531
3.431
MW-C
29-Oct-15
1.42J
47.91
0.68J
11.6
7.47J
4.521
3.04J
9.281
1.151
3.79CN,J
0.101
19.4J
14.413-01
1302-MSWLF-
MW-C
18-May-16
21.41
0.21J
0.711
1.78J
0.471
0.251
1.691
4.111
2.011
CDLF-1998
MW-C
2-Nov-16
2.161
34.01
0.181
1.301
10.3
0.551
0.33J
3.791
3.511
MW-C
9-May-17
22.51
0.14J
1.081
0.431
0.301
1.18J
1.941
1.361
MW-C
1-Nov-17
0.601
31.91
0.33J
4.971
7.83J
1.381
1.20J
3.921
8.39J
5.701
MW-C
7-Jun-18
2.01
52.51
0.811
16.5
8.2J
4.11
4.01
8.81
1.51
25.8
17.7
MW-C
19-Dec-18
22.0J
0.14J
0.11J
0.971
0.331
1.21
3.01
MW-C
30-May-19
19.6
0.16J
IMW
1.3J
3.11
0.181
9.7
1.71
4.51
MW-C
6-Nov-19
79.5
0.20J
3.41,D3
7.81,D3
1.6J,B,D3
0.91J
8.21,D3
8.3J,D3
9.5J,B,D3
MW-C
19-May-20
14.8
0.25J
1.21
2.1J
0.841
0.311
1.31
1.71
3.11
MW-C
22-Sep-20
51
3.1J
0.41J
3.41
3.21
5.81
MW-C
18-Mar-21
21
0.34J
2.41
3.1J
0.771
1.71
6.4
4.71
MW-C
18-Nov-21
58
9.7
6.8
MW-D
4-May-11
193
0.81J
0.12J
11.7
30.2
5.281
30.41
0.25J
41.7
37.3
MW-D
9-Nov-11
0.361B
118
0.25J
8.021
3.05J
8.5J
1.47J
15.31
0.07J
5.68J
12.1
MW-D
9-May-12
124
31
8.97J
3.941
0.611
15.71
SAD
9.331E
MW-D
28-Nov-12
0.981
1.83J
117
0.11J
0.06J
2.311
3.01J
3.631
0.61J
13.81
12.1J
5.111B
MW-D
9-May-13
140
0.21J
0.08J
6.41
6.72J
7.781
0.941
17.31
25.8
10.8
MW-D
6-Nov-13
194
0.86J
0.25J
12.8
35.5
7.32J
27J
105B
37.9B
MW-D
7-May-14
169
0.21J
3.74JB
19.0
1.16J
20.71
8.021
1.43JB
MW-D
5-Nov-14
121
0.11J
0.06J
1.62J
7.61J
3.411
0.72J
18.31
0.95JB
7.001
MW-D
S-May-15
1.79J
164
14.2
1.061
21.71
4.511
1.621
MW-D
29-Oct-15
0.30J
5.11J
199
0.74J
0.12J
10.4
32.7
6.25J
37.0J
5.921
3.91CN,1
0.371
50.7
48.513-01
MW-D
18-May-16
1.65J
157
0.111
0.851
17.0
0.921
0.191
21.01
3.92J
1.721
1302-MSWLF-
MW-D
3-Nov-16
134
0.091
8.75J
0.851
0.211
19.91
3.641
CDLF-1998
MW-D
9-May-17
0.94B-01,J
242
0.07J
0.561
18.8
0.421
0.091
24.31
8.27J
5.681
MW-D
1-Nov-17
1.23J
151
0.30J
9.171
6.69J
7.621
1.601
20.41
1.871
0.06J
12.8J
14.5
MW-D
7-Jun-18
1.21
139
0.111
1.71
3.4J
1.41
0.361
15.71
6.81
15.8
MW-D
19-Dec-18
214
0.11J
18.6
14.81
14.0J
MW-D
30-May-19
140
0.22J
0.641
12.1
0.471
18.1
18.7
6.31
MW-D
6-Nov-19
210
0.15J
16.3J,D3
2.S1,B,D3
0.50113
27.0
4.3J,D3
8.11,13,D3
MW-D
20-May-20
206
0.11
13.2
0.0471
23.4
12.3
3.91
MW-D
24-Sep-20
220
0.23J
13
1.31
0.361
27
3.0.1
MW-D(dup)
24-Sep-20
210
13
1.31
0.281
25
2.61
MW-D
18-Mar-21
160
0.15J
2.71
34
2.41
0.481
20
3.0.1
MW-D
18-Nov-21
1.61
280
17
32
CDWI
Page 5 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
12 E
,,, 15 100
,,,
MW-E Rep
4-May-11
262 0.57J
1.18JB 12.4 1.091 0.621 15.11
6.41
MW-E Rep
8-Nov-11
267 0.41J
9.28J 0.831 13.21 0.071
2.881
MW-E Rep
8-May-12
303 0.31J
12.6 0.851 0.321 15.21
1.721 10.36
MW-E Rep
8-May-13
286 0.34J
8.29J 1.081 0.081 14J 0.891
3.711
MW-E Rep
5-Nov-13
294
15.5 0.841 0.221 15.81
14JB 6.38JB
MW-E Rep
6-May-14
342 0.44J
16.8 1.451 0.671 15.91
7.581 6.46JB
MW-E Rep
4-Nov-14
326 0.21J
8.39J 0.891 0.281 15.91 1.57J
2.991E 4.311
MW-E Rep
5-May-15
348 0.301
7.481 1.02J 0.62.1 14.5.1 1.441
12.21 4.461
MW-E Rep
27-Oct-15
0.911 294 0.26J
1.12J 10.2 0.391 12.31 2.07CN,J
4.848-01,1
1302-MSWLF- MW-E Rep
18-May-16
1.111 365 0.271
12.0 0.32J 12.9.1
2.311 2.991
CDLF-1998 MW-E Rep
1-Nov-16
297 0.15J
5.44J 0.171 11.41
5.131
MW-E Rep
9-May-17
0.71B-01,J 353 0.201
7.58J 0.13J 12.1.1
1.431 3.401
MW-E Rep
31-Oct-17
0.86J 344 0.22J
6.81 0.341 12.21
4.451 3.711
MW-E Rep
11-Jun-18
0.661 350 0.231
9.11 13.1.1
4.61
MW-E Rep
20-Dec-18
321 0.11J
7.11 13.11
MW-E Rep
7-May-19
0.571 344 0.231
7.4 11.7
3.41
MW-E Rep
5-Nov-19
0.28J 319 0.17J
5.6 0.3218 0.111 13.6
34.2E
MW-E Rep
21-May-20
339 0.121
3.21 14.6
1.21 2.71
MW-E Rep
23-Sep-20
360 0.27J
7.3 0.611 15
2.6.1 6.51
MW-E Rep
17-Mar-21
0.661 350
13 0.341 12
5.51
MW-E Rep
17-Nov-21
340 0.24J
5.5 0.431 13
3.81
MW-E Deep
4-May-11
2.961
2,
0.251
0.181
1.14JB
66.4
3.111
20
30.8J
57.9
MW-E Deep
8-Nov-11
3.66J
2,280
0.16J
0.22J
54.2
1.381
16.4
26J
43.5
MW-E Deep
8-May-12
2.511
2,210
0.531
0.361
50.1
31.6
94
24.9.1
7.651
60.913
MW-E Deep
28-Nov-12
0.71J
3.86J
1,820
0.84J
1.99
4.561
39.6
22.3
213
26.11
0.181
9.201
67.2
MW-E Deep
8-May-13
4.561B
1,730
0.341
0.711
37.9
4.71
74.5
201
43
MW-E Deep
6-Nov-13
1.091
2,240
0.19J
0.32J
39.7
2.341
39.3
20.51
16JB
41.2E
MW-E Deep
6-May-14
2.691
2,080
0.601
0.441
63.4
6.291
60.9
32.71
2.491
32.213
MW-E Deep
4-Nov-14
3.29J
2,000
0.31J
0.47J
43.6
6.411
55.6
20.41
3.751E
30.0
MW-E Deep
5-May-15
2.421
2,040
0.251
0.191
34.4
2.701
22.2
17.31
0.871
2.541
19.3
MW-E Deep
27-Oct-15
2.55J
1,900
0.28J
0.21
34.3
4.341
38.2
14.21
2.81CN,J
2.971
24.38-01
1302-MSWLF-
MW-E Deep
18-May-16
3.54J
2,150
0.48J
0.67J
0.931
37.0
8.731
76.4
16.01
1.071
8.52J
30.6
CDLF-1998
MW-E Deep
1-Nov-16
2.41
1,960
0.22J
0.18J
34.5
2.341
18.5
14.61
19.3
MW-E Deep
9-May-17
1.68B-01,J
2,010
0.23J
32.9
0.591
3.961
14.51
8.051
MW-E Deep
1-Nov-17
1.65J
2,100
0.26J
0.461
32.3
1.631
9.691
15.21
0.061
1.311
8.011
MW-E Deep
11-Jun-18
2.11
2,310
0.21J
33.5
2.1J
13.91
4.81
MW-E Deep
20-Dec-18
1.31
2,640
0.26J
1.61
39.1
6.71
21.21
5.2J
MW-E Deep
8-May-19
2.11
2,910
0.37J
42.1
2.9
24.9
5.41
MW-E Deep
5-Nov-19
2.01
2,670
0.28J
38.3
0.8116
8.9
20.6
11.0E
MW-E Deep
21-May-20
2.6JB
4,120
0.40J
0.231
0.46J
40.5
1.31
18.9
29.4
13.0
MW-E Deep
23-Sep-20
3.3
2,800
0.72
2.0
2.3J
34
22
230
24
1.31
1
46
MW-E Deep
17-Mar-21
1.01
2.1
2,600
32
2.61
6.1
18
21
MW-E Deep
17-Nov-21
1.7J
2.5
2,300
0.21J
0.16J
34
2.31
18
18
8.51
MW-F
4-May-11
136
0.14J
0.751B
1.29J
0.911
3.151
2.241
MW-F
9-Nov-11
0.17J
5.42J
219
0.06J
10.6
1.061
4.441
1.57J
MW-F
9-May-12
3.19J
242
8.35J
1.271
3.331
0.921
2.851
2.341B
MW-F
29-Nov-12
283
0.15J
1.861
8.50J
1.071
0.591
5.001
1.52J
3.761
4.461
MW-F
10-May-13
1.17J
154
0.21J
1.631B
SAW
1.561
0.151
2.78J
21
0. 12J
4.861
MW-F
6-Nov-13
2.01J
255
11.2
0.821
0.191
3.451
0.83J
12.71E
2.431E
MW-F
8-May-14
5.17J
213
0.16J
10.4
0.971
0.54J
4.881
1.041
6.84J
1.771
MW-F
4-Nov-14
2.92J
262
0.21
11.3
0.801
0.451
5.511
3.091
1.251
MW-F
5-May-15
0.31J
2.29J
129
0.11J
1.39J
0.731
0.101
4.571
1.851
MW-F
28-Oct-15
5.94J
262
0.451
13.0
0.791
0.14J
4.801
1.92CN,J
3.676-01,1
1302-MSWLF-
MW-F
18-May-16
3.40J
214
9.621
3.841
CDLF-1998
MW-F
3-Nov-16
231
0.14J
7.64J
4.631
MW-F
11-May-17
0.87B-01,J
190
0.12J
4.101
0.081
5.001
MW-F
31-Oct-17
0.80J
363
13.4
4.311
1.331
MW-F
6-Jun-18
2.41
149
0.48J
3.11
3.6J
1.81
7.11
6.41
MW-F
19-Dec-18
0.81J
103
0.101
1.31
5.81
MW-F (dup)
19-Dec-18
1.01
107
0.10J
1.3J
6.11
MW-F
9-May-19
2.41
188
7.2
6.6
4.5
8.91
MW-F
6-Nov-19
28.0
0.19113
MW-F
20-May-20
2.OJB
231
0.088J
0.391
8.4
0.631
0.161
6.7
5.91
MW-F
25-Sep-20
3.4
300
0.86
2.21
5.8
1.51
1.2
14
1.4.1
4.91
MW-F
18-Mar-21
6.2
320
0.191
14
10
MW-F
18-Nov-21
240
2.OJ
12
1.5.1
CDWI
Page 6 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
,,, 15 100 ,,,
MW-G
4-May-11 148 0.08J 0.19J
1.07JB 14.6 12.6 1.151 32.51 8.16J 4.01J
MW-G
9-Nov-11 0.14J 2.75J 420 0.12J
4.99J 0.87JB 3.171 2.791 2.511
MW-G
9-May-12 4.45J 302
2.19J 0.861 4.401 1.41J 4.25J 13.7E
MW-G
29-Nov-12 2.01 385 0.15J
2.14J 0.961 0.12J 3.691 3.03J 2.79J 2.86J
MW-G
30-May-13 354 0.181
5.08J 1.191 0.14J 2.431 1.51J 2.11J 5.14J
MW-G
6-Nov-13 5.44J 346
3.09J 0.81.1 0.09J 4.81.1 2.751 12.4JB 2.491B
MW-G
8-May-14 4.42J 373 0.20J
6.69J 1.311 0.271 5.001 2.951 7.99J 4.081
MW-G
4-Nov-14 480 0.261
7.021 2.571 0.611 9.321 2.961 0.171 10.6JB 6.721
MW-G
5-May-15 2.131 340 0.18J
5.62J 2.301 0.371 5.291 4.791 4.851 4.161
MW-G
28-Oct-15 4.45J 387 0.14J
1.231 5.011 0.741 0.19J 4.881 2.09CN,1 2.76J 3.6913-01,1
1302-MSWLF-
MW-G
19-May-16 3.19J 412 0.15J
1.311 6.07J 0.891 0.261 5.071 4.72J 4.621
CDLF-1998
MW-G(dup)
19-May-16 0.31B-01,J 3.511 417 0.111
1.051 5.37J 0.091 3.641 2.55J 2.081
MW-G
3-Nov-16 6.65J 418 0.091
1.231 3.67J 1.001 5.361 5.041
MW-G
11-May-17 0.46J 2.211 448 0.351
2.751 7.45J 2.821 1.14J 5.531 1.721 0.091 13.2J 10.5
MW-G
1-Nov-17 5.91 488 0.101
0.951 5.961 0.091 5.391 2.411 2.661
MW-G
6-Jun-18 5.21 448 0.0911
6.3J 4.51 2.21
MW-G
19-Dec-18 1.41 331 0.20J
6.11 2.51 3.11 3.81
MW-G
9-May-19 2.41 464 0.131
0.791 14.6 0.431 0.111 10.9 0.0611 0.74J 3.81
MW-G
6-Nov-19 2.41,D3 451
7.41,D3 0.1318 10.41,D3 8.4J,B,D3
MW-G
20-May-20 4.01B 377 0.0881
1.61 14.4 0.261 0.491 9.2 2.21 3.31
MW-G
25-Sep-20 5.8 MM 0.17J
1.91 18 1.41 0.561 18 9.2 6.8 5.91
MW-G
18-Mar-21 4.3 340
28 0.261 30 4.21 3.61 2.71
MW-G
18-Nov-21 5.3 320D
18 26 17
MW-H
5-May-11
62.21
0.311
9.051
2.05J
6.941
1.681
6.891
0.081
9.851
16.9
MW-H
9-Nov-11
0.14J
32.61
0.11
2.691
0.71J
2.931
0.591
2.831
7.371
MW-H
9-May-12
44.91
0.131
3.581
0.891
4.231
1.17J
3.171
5.79J
12.113
MW-H
29-Nov-12
37.81
1.681
0.251
1.621
0.291
1.13J
2.891
5.651
MW-H
9-May-13
27.91
1.941
0.211
1.331
0.221
1.11
2.68J
5.451
MW-H
7-Nov-13
72J
0.38J
4.941
6.391
2.651
5.961
15.4J
16.4E
MW-H
8-May-14
67.01
0.471
3.481
6.341
2.121
4.491
9.00J
14.2
MW-H
6-Nov-14
49.81
0.17J
2.04JB
0.951
3.671
0.951
2.971
5.331
7.55JB
MW-H
5-May-15
1.20J
52.51
0.20J
0.50JB
0.891
4.341
1.27J
2.941
4.63J
7.651
MW-H
29-Oct-15
1.85J
78.11
0.48J
8.221
2.56J
8.561
2.511
7.191
2.571
4.20CN,J
0.091
14.71
22.98-01
1302-MSWLF-
MW-H
19-May-16
1.24J
52.31
0.25J
4.011
1.161
3.621
1.26J
3.27J
1.521
8.62J
9.431
CDLF-1998
MW-H
3-Nov-16
67.81
0.31
5.811
1.961
5.861
1.781
5.591
2.871
10.71
15.7
MW-H
11-May-17
0.85J
64.81
0.28J
6.821
1.83J
4.761
1.68J
6.28J
2.391
0.091
10.2J
12.5
MW-H
1-Nov-17
0.62J
59.51
0.21
4.101
1.20J
4.291
1.291
3.511
3.111
8.681
9.691
MW-H
7-Jun-18
1.21
56.61
0.26J
3.81
1.2J
4.71
1.3J
3.21
8.11
9.61
MW-H
19-Dec-18
1.11
74.71
0.51
7.81
2.6J
9.81
2.81
6.61
1.81
15.01
17.9
MW-H
9-May-19
32.7
0.13J
1.31
0.471
2.91
0.481
2.81
4.71
7.31
MW-H
6-Nov-19
65.3
0.32J
5.5
1.81
5.813
1.6
6.8
0.0601
12.2
19.5E
MW-H
19-May-20
0.52J
62.1
0.35J
6.0
2.3J
5.4
2.2
6.7
0.0751
10.7
18.3
MW-H
24-Sep-20
1.31
59
0.42
6.2
2.4J
5.4
1.8
6.7
1.61
10
16
MW-H
18-Mar-21
35
1.61
0.261
1.61
2.51
2.61
MW-H
17-Nov-21
30
1.81
MW-H Deep
5-May-11
57.51
0.22J
4.33JB
0.82J
4.351
1.571
2.651
7.23J
7.84.1
MW-H Deep
9-Nov-11
29.21
0.05J
1.17J
0.711
2.071
0.451
1.621
2.551
MW-H Deep
9-May-12
0.74J
49.61
0.181
3.411
0.951
5.671
1.421
2.91J
7.53J
13.2B
MW-H Deep
28-Nov-12
52.41
1.281
1.591
0.961
2.44J
2.621
MW-H Deep
9-May-13
0.83J
43J
0.471
2.21
0.221
1.45J
6.98J
MW-H Deep (dup)
9-May-13
0.24J
44.11
1.051
0.191
1.721
0.221
1.41
3.34J
13.3
MW-H Deep
7-Nov-13
40.91
0.281
1.851
0.23J
1.39J
12.1J
5.29JB
MW-H Deep
8-May-14
55.01
0.101
0.321
2.031
0.371
1.631
3.891
MW-H Deep
6-Nov-14
49.91
0.08J
1.33JB
1.451
0.191
2.001
4.18J
9.25JB
MW-H Deep (dup)
6-Nov-14
49.41
1.54JB
0.501
1.741
0.271
1.931
6.32JB
MW-H Deep
5-May-15
1.84J
44.41
0.291
2.691
0.381
1.971
2.00J
2.001
MW-H Deep (dup)
5-May-15
1.421
39.81
0.11
1.081
0.311
2.881
0.371
2.261
3.231
1302-MSWLF-
MW-H Deep
29-Oct-15
45.91
0.641
1.49113
0.231
1.571
3.82CN,J
4.80J
3.0613-01,1
CDLF-1998
MW-H Deep
19-May-16
1.10B-01,1
55.91
0.12J
0.871
2.361
0.451
1.331
0.101
SAW
2.271
MW-H Deep
3-Nov-16
54.71
1.14J
0.251
0.891
MW-H Deep
11-May-17
50.51
0.761
1.341
0.441
1.231
3.84J
7.301
MW-H Deep
1-Nov-17
53.01
0.381
0.821
0.181
0.801
4.12J
1.831
MW-H Deep
7-Jun-18
0.79J
61.91
0.066J
1.41
0.281
5.01
2.2J
MW-H Deep
19-Dec-18
47.41
0.0591
0.291
3.41
MW-H Deep
9-May-19
42.0
0.521
1.11
0.171
0.831
4.41
3.21
MW-H Deep
6-Nov-19
49.9
0.971
1.6JB
0.30113
1.71
5.81
37.513
MW-H Deep
19-May-20
1.51
35.4
4.91
0.881
0.121
2.91
1.11
5.21
MW-H Deep
24-Sep-20
1.21
42
3.21
1.71
0.271
1.71
11
MW-H Deep
18-Mar-21
43
MW-H Deep
15-Nov-21
42
1.41
MW-H Deep (dup)
15-Nov-21
44
Smith Page 7 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
,,,
15
100
,,,
MW-1
4-May-11
26.31
0.16J
4.87JB
0.291
0.941
0.441
2.441
4.151
3.141
MW-I
9-Nov-11
0.30JB
12J
0.12JB
0.661
0.11J
0.811
1.241
0.281
3.361
MW-1
9-May-12
0.25J
17.61
0.31
1.801
0.201
1.651
0.271
3.011
3.531
11.56
MW-1 (dup)
9-May-12
16.21
0.31J
1.711
1.111
0.231
2.391
8.56JB
MW-1
28-Nov-12
0.30J
14.31
0.731
0.441
0.941
2.491
1.05JB
MW-1
10-May-13
0.49J
17.81
0.22J
0.07J
1.38JB
0.34.1
0.791
0.311
1.321
3.391
MW-1
7-Nov-13
14.21
0.12J
0.211
0.591
0.201
1.411
6.831
2.61JB
MW-1
7-May-14
13.91
0.131
3.441B
0.771
0.191
1.311
1.311
1.531B
MW-1
5-Nov-14
20.71
0.16J
0.05J
0.821
0.261
0.901
0.311
1.561
2.551E
1.70J
MW-1
5-May-15
0.501
15.41
0.171
1.811
1.711
0.331
1.851
1.861
1302-MSWLF-
MW-1
29-Oct-15
21.11
0.21J
1.101
0.621
0.281
1.571
4.40CN,J 4.711
4.328-01,1
CDLF-1998
MW-1
19-May-16
0.37B-01,J
20.71
0.201
1.071
0.331
1.751
3.091
2.421
MW-1
3-Nov-16
24.21
0.29J
0.07J
1.301
0.551
0.841
1.431
3.581
MW-1
11-May-17
26.31
0.231
0.081
1.251
0.551
0.791
1.481
3.641
2.451
MW-1
31-Oct-17
23.41
0.21
1.301
0.391
0.511
1.211
3.951
3.01J
MW-1
7-Jun-18
24.41
0.181
0.351
1.01
3.11
2.61
MW-1
18-Dec-18
31.01
0.21
0.15J
2.31
0.641
1.61
3.91
4.61
MW-1
9-May-19
17.8
0.181
1.21
0.241
1.21
4.9.1
3.31
MW-1
6-Nov-19
22.7
0.26J
1.71
0.5918
0.781
1.91
9.1.1
8.4.113
MW-1
19-May-20
1.51B
13.3
0.131
0.131
M
1.01
0.201
7.4
4.7.1
7.41
MW-1
23-Sep-20
45
0.29J
4.71
1.71
0.991
5.7
7.0
7.OJ
MW-1
19-Mar-21
16
0.151
2.81
2.81
3.71
MW-1
15-Nov-21
26
0.20J
2.21
0.501
1.71
4.4.1
MW-J
4-May-11
38.41
0.311
6.141
2.OIJ
31
2.41
5.471
0.081
13J
11.2
MW-1
9-Nov-11
0.16JB
35.31
1.551
0.44J
1.261
0.2718
5.841
0. 12J
5.981
M W-1
9-May-12
15.21
1.641
0.381
1.411
0.521
2.761
3.351
15B
MW-1
29-Nov-12
16.41
1.391
0.301
2.541
0.301
1.201
3.931
4.891
MW-1
8-May-13
10.61
0.861
0.311
1.16J
0.271
1.381
4.811
2.71
MW-1
6-Nov-13
17.81
0.791
1.431
0.911
2.281
21.41E
4.73JB
MW-1
7-May-14
31.61
3.021B
0.521
1.411
0.831
2.031
3.401
4.24JB
MW-1
4-Nov-14
27.41
0.17J
1.451
1.24J
2.001
1.16J
3.541
9.S8J6
6.38JB
MW-1
6-May-15
10.71
1.381
0.511
2.001
0.63J
2.481
3.511
3.36.1
MW-1
28-Oct-15
11.01
0.58B-01,J
0.45J
1.641
0.381
2.061
3.59CN,J
2.471
5.911
1302-MSWLF-
MW-1
18-May-16
0.961
28.21
0.25J
3.111
1.40J
1.621
1.991
3.551
0.901
12.01
6.861
CDLF-1998
MW-1
2-Nov-16
32.21
0.28J
4.861
2.51J
2.381
2.741
5.691
1.66J
14.9J
11.0
MW-1
9-May-17
18.81
0.11J
1.661
0.731
0.971
1.02J
2.041
6.181
4.41J
MW-1
1-Nov-17
18.71
0.11
2.591
0.921
0.981
1.241
2.211
8.18J
6.221
MW-1
7-Jun-18
1.21
37.81
0.35J
5.6J
2.9M
2.51
3.31
6.01
19.11
14.6
MW-1
19-Dec-18
16.71
0.14J
2.11
0.911
1.31
2.51
7.2.1
6.9J
MW-1
10-May-19
0.481
19.0
0.11J
1.6J
0.701
0.821
0.931
1.61
7.41
6.31
MW-1
6-Nov-19
14.9
0.076J
2.51
0.651
0.9216
0.871
2.71
8.91
14.2E
MW-1
20-May-20
1.31B
15.6
0.082J
1.2J
0.481
0.631
0.831
1.21
6.11
7.51
MW-1
24-Sep-20
21
2.01
1.2
2.51
7.0
10
M W-1
18-Mar-21
10
3.41
M W-1
18-Nov-21
16
2.51
MW-K
4-May-11
25.21
0.26J
6.521
1.57J
2.251
1.531
3.651
111
7.961
MW-K
9-Nov-11
17.71
0.14JB
2.511
0.73J
3.671
0.731
2.071
0.071
4.961
4.091
MW-K
9-May-12
35.21
0.22J
7.591
2.981
3.66J
1.92J
6.061
13.81
20.113
MW-K
28-Nov-12
16.11
1.351
0.28J
0.741
0.281
1.421
2.531
4.44JB
MW-K
8-May-13
1.02JB
17J
0.15J
1.911
0.71J
1.33J
0.69J
2.241
6.051
5.281
MW-K
6-Nov-13
13.91
2.681
0.761
1.261
0.431
1.941
23JB
4.68JB
MW-K
7-May-14
17.51
0.12J
4.27JB
0.491
1.30J
0.70J
1.831
3.491
2.461B
MW-K
5-Nov-14
13.31
0.13J
1.211
0.531
1.201
0.431
1.971
3.821E
3.191
MW-K
5-May-15
1.16)
1.42J
15.31
0.14J
0.491
1.991
0.71J
2.541
4.661
2.951
MW-K
29-Oct-15
0.351
26.21
0.191
2.54B-01,J
1.16J
2.411
1.041
4.171
2.87CN,J
6.18J
5.601
MW-K
18-May-16
1.43J
17.81
0.16J
3.251
0.891
1.031
0.831
2.281
1.181
8.68J
5.35)
1302-MSWLF-
MW-K
2-Nov-16
17.81
0.16J
2.601
0.871
0.941
0.721
2.041
1.78J
4.01J
CDLF-1998
MW-K(dup)
2-Nov-16
4.051
1.311
0.631
0.181
1.17J
1.081
2.18J
MW-K
9-May-17
0.47B-01,J
13.91
0.101
1.901
0.471
0.621
0.411
1.591
4.41J
1.92J
MW-K
1-Nov-17
0.82J
20.21
0.16J
3.281
1.031
0.871
2.201
8.121
4.57J
MW-K
7-Jun-18
0.94J
0.88J
13.81
0.11
2.21
0.591
1.31
6.2.1
2.2.1
MW-K
19-Dec-18
15.71
0.31J
0.12J
2.01
0.491
1.11
0.221
4.01
2.61
MW-K
10-May-19
15.8
0.089J
1.81
1.01
0.231
1.21
5.11
3.71
MW-K
6-Nov-19
0.65J
20.1
0.17J
3.41
1.11
1.1JB
0.871
2.41
13.1
9.0JB
MW-K
20-May-20
1.6JB
22.1
0.17J
3.81
1.1J
0.891
1.1
2.41
9.2.1
9.81
MW-K
24-Sep-20
35
0.26J
4.81
2.0J
1.51
1.3
4.41
8.9
8.71
MW-K
18-Mar-21
30
1.51
0.311
1.51
MW-K(dup)
18-Mar-21
31
1.91
0.271
1.31
2.51
MW-K
18-Nov-21
41
2.21
4.11
Smth Page 8 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
MW-L
4-May-11
45.7J
2.67JB
0.351
0.7J
0.2J
1.64J
3.961
MW-L
9-Nov-11
0.191
40.9J
0.06J
1.64J
0.41J
0.93J
0.37J
1.49J
3.72J
MW-L
9-May-12
43.8J
1.20J
0.52J
0.09J
1.27J
1.931
2.16JB
MW-L
28-Nov-12
0.82J
23.0J
1.74J
0.32J
0.39J
2.21J
6.471
3.751
MW-L
9-May-13
1.24JB
43.5J
1.12J
0.49J
0.83J
0.22J
1.95J
2.9J
3.29J
MW-L
7-Nov-13
49.2J
0.191
0.88J
1.20J
2.49J
0.85J
3.62J
11.81
11.5B
MW-L
8-May-14
43.7J
0.07J
0.67J
0.14J
1.28J
1.951
MW-L
5-Nov-14
38.6J
0.76J
0.14J
1.32J
2.441
2.281B
MW-L
6-May-15
40J
0.81J
0.16J
1.27J
2.23J
MW-L
28-Oct-15
33.5J
1.051
0.291
1.07J
4.04CN,J
2.871
6.06B-01-1
1302-MSWLF-
MW-L
19-May-16
38.4J
0.88J
1.011
2.231
1.481
CDLF-1998
MW-L
2-Nov-16
35.2J
1.001
1.04J
2.461
MW-L
30-May-17
0.56B-01,J
33.3J
1.011
0.49J
0.111
0.951
2.341
2.801
MW-L
1-Nov-17
33.9J
1.23J
1.30J
0.12J
0.85J
1.461
1.871
MW-L
7-Jun-18
32.71
2.71
60.9
MW-L
19-Dec-18
34.41
0.0791
MW-L
8-May-19
41.0
2.9J
MW-L
7-Nov-19
3.61B
35.3
1.3J
0.37J
0.15JB
0.76J
7.61E
7.31E
MW-L
21-May-20
36.9
0.901
0.25J
0.951
4.2J
MW-L
23-Sep-20
42
1.4J
3.3J
0.74J
3.0J
3.9J
18
MW-L
17-Mar-21
49
1.81
0.351
2.11
3.9J
3.3J
MW-L
17-Nov-21
40
1.6J
0.45J
2.2J
4.81
6.91
MW-L Deep
4-May-11
0.44J
56.81
0.34J
14.7
2.861
3.62J
3.39J
13.6J
15.21
12.7
MW-L Deep
9-May-12
0.621
23J
2.03J
0.831
1.60J
0.68J
3.14J
8.531
7.991B
MW-L Deep
30-May-13
0.41J
19.21
0.241
1.891
0.271
1.63J
2.081
21.8
MW-L Deep
8-May-14
27.9J
1.34JB
0.111
1.32J
6.06J
MW-L Deep
6-May-15
0.36J
23.11
0.901
1.241
1.501
2.451
45.1
1302-MSWLF-
MW-L Deep
29-Oct-15
0.581
23.0J
0.47B-01,J
1.23J
0.091
1.62J
3.73CN,J
81.1
CDLF-1998
MW-L Deep
19-May-16
0.46J
30.81
0.441
1.871
0.171
1.271
4.591
116
MW-L Deep
10-May-17
1.101
0.93B-01,J
34.41
0.081
0.42J
0.66J
0.14J
1.27J
4.731
128
MW-L Deep (dup)
30-May-17
1.04J
0.91E-01,J
33.91
0.07J
0.401
0.821
0.151
1.281
4.701
123
MW-L Deep
7-Jun-18
32.1J
1.4J
2.41
352
MW-L Deep
8-May-19
0.901
34.3
1.81
3.6J
396
MW-L Deep
21-May-20
0.95J
32.3
0.34J
1.51
2.61
429
MW-L Deep
19-Mar-21
1.11
35
1.41
490
MW-M
5-May-11
0.921
64.2J
0.56J
2.681
2.641
15.6
4.83J
5.84J
0. 14J
18.21
15.2
MW-M
9-May-12
40.31
0.26J
2.461
1.38J
8.561
3.071
3.801
11.81
15.2B
MW-M
10-May-13
34.9J
0.16J
1.44JB
0.691
2.21J
0.51
1.68J
2.21
MW-M
8-May-14
37.11
0.101
0.801
0.301
2.001
0.631
1.911
2.421
MW-M
5-May-15
1.93J
39.41
0.881
2.02J
0.511
2.18J
4.071
1.71J
1302-MSWLF-
MW-M
29-Oct-15
38.91
0.101
1.56B-01,1
0.391
2.101
0.621
2.101
3.09CN,J
1.781
4.961
CDLF-1998
MW-M
18-May-16
0.92J
38.8J
0.60J
0.461
1.60J
0.581
1.47J
6.84J
1.54J
MW-M
9-May-17
40.41
0.081
0.651
1.501
0.571
1.18J
4.651
1.981
MW-M
7-Jun-18
37.9J
0.31J
0.99J
4.0J
MW-M
30-May-19
49.1
1.71
0.0971
0.901
5.11
1.81
MW-M
19-May-20
1.3JB
36.7
0.14J
0.911
0.75J
2.7J
0.78J
1.91
8.31
5.51
MW-M
19-Mar-21
53
2.31
0.711
1.41
4.6J
2.61
CDWI
Page 9 of 31 January 2022

Table 5a
Detected Groundwater Constituents - Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Notes:
1. All units are in micrograms per liter (parts per billion).
2.' - Interim Maximum Allowable Concentration (IMAC)
3. Monitoring wells MW-3 Deep, -L Deep, -and -M are sampled annually during the spring event.
4. (dup) - Duplicate
S. Assessment Wells CD-4, CD-5, and CD-6 were installed in September 2006. CD-4 and -5 were abandoned in July 2010. CD-6 was abandoned in February 2017.
6. Assessment Wells AMW-1s, -1d, -2s, and -2d were installed in October 2009.
7. M W-9 was removed from the monitoring program in November 2012. CD-1s/CD-1d replaced M W-9 as the background monitoring wells.
8. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight.
9.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit.
10. 8/8-01- Indicates constituent was detected in the batch blank above the method detection limit.
11. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid used.
12. D3 - The sample was diluted due to matrix interference.
Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 21.) Groundwater Standard or IMAC
- Indicates the result is below the detection limit or not analyzed.
Smth Page 10 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smth Page 11 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smth Page 12 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smith Page 13 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smth Page 14 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smith Page 15 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
1302-MSWLF-
CDLF-1998
MW-3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW.3 Deep
MW-3 Deep
MW-3 Deep
4.May-11
8-May-12
30-May-13
8.May-14
6-May-15
28-Och15
19-May-16
11-May-17
7-Jun-18
8-May-19
19-May-20
19-Mar-21
10.01
0.5J
Il
0.4J
1.2J
1.4J
1.2J
1.01
1.4J
1.1
0.63J
0.81
1
1
1
0.41
0.6J
0.41
0.41
0.41
0.41
1302-MSWLF-
MW-9
3-May-11
0.81
CDLF-1998
MW.9
9-Nov-11
1.1
MW-9
9-May-12
1.4
MW.A
3-May-11
7.4
11
4.7J
12
14
2.2
110
0.41
2.2
0.81
3.9
3.1J
3.2
0.71
MW-A
9-Nov-11
9.2
1.41
6.5J
16
18
2.9
120
0.6J
2.4
2
6.5
5.2
3.8
11
MW.A
9-May-12
8.9
1.11
6.51
17
26
3.8
0.51
110
0.4J
2
0.91
6.5
2.6J
0.5J
4.5
0.2J
1.1
MW-A
27-Nov-12
9.3
1.6J
6.9J
15
25
3.9
0.61
130
0.5J
2.2
0.4J
0.5J
4.7
1.7J
0.41
4.4
0.81
MW.A
7-May-13
9.1
1.3J
5.1J
22
23
3
0.41
120
0.5J
2.4
0.6J
0.8J
6.2
0.3J
8.0
4.3
MW-A
5-Nov-13
11
1.41
5.7J
0.4J
25
22
4.1
130
1.4
6.2
6.0
3.8
1.0
MW.A
6-May-14
11
1.3J
5.61
0.31
28
18
3.6
0.21
120
0.4J
2.1
0.7J
4.6
5.3
0.41
5.8
3.3
1.0
MW-A
4-Nov-14
9.5
1.6J
5.6J
0.3J
31
21
2.6
130
0.5J
0.41
1.1
5.7
2.0J
4.5
1.01
MW.A
5-May-15
9.3
1.41
5.0J
0.3J
24
16
2.5
110
0.5J
2.1
0.8J
0.8J
5.6
0.41
5.3
3.6
0.61
MW-A
27-Oc[-15
9.1
1.41
5.41
28
15
2.3
110
0.7J
0.8J
5.9
0.3J
4.41
3.4
0.71
1302-MSWLF-
MW-A
17-May-16
9.7
1.5J
31
15
1.3
120
2.2
1.1
1.4
4.8
0.6J
5.2
3.7
0.81
CDLF-1998
MW-A
1-Nov-16
11
1.61
5.71
36
17
1.6
140
0.5J
2.6
0.7J
1.4
5.7
4.7J
3.8
0.91
MW.A
9-May-17
9.5
1.4J
4.5J
30
13
1.0
120
0.5J
1.9
0.8J
1.6
4.8
0.41
4.8J
3.1
0.71
MW-A
31-Oc[-17
12
1.41
4.41
35
15
1.7
140
2.4
0.91
2.6
5.3
IL-3.7
MW.A
7-Jun-18
8.3
4.5J
0.91J
2.9J
16.6
10.8
100
0.661
1.5
1.5
2.8
MW.A
20-Dec-18
11.0
1.41
4.2J
20.3
13.3
1.7
133
0.521
2.1
3.1
2.6J
2.8
MW-A
9-May-19
9.7J
5.7
1.3
2.7
36.0
12.7
1.7
86.2
0.49J
2.4
0.49J
2.5
2.3
3.8
2.9
0.77J
MW-A
5-Nov-19
5.9
1.3
4.3
35.7
12.6
1.4
87.4
2.2
Jx)
0.901
2.6
.4
0.92J
MW-A
19-May-20
5.4
9.0
1.1
68.2
1.5
0.69J
2.0
2.2
1.5
MW-A
23-Sep-20
7.4
0.85
3.4
17
30
1.0
76
1.6
0.64
1.5
2.7
2.9
2.6
2.2
MW-A
17-Mar-21
11
4.5
1.2
4.2
25
12
86
0.41J
1.8
jet
0.64
1.3
2.3
3.6
3.7
1.6
MW-A
16-Nov-21
7.0
1
1.0
4.0
1
22
1 11
0.40J
89
0.49J
1.7
0.65
2.7
0.40J
3.9
2.4
Smth Page 16 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smith Page 17 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
MW-D
3-May-11
5.5
3.21
1.9
1.91
37
0.71
1.6J
5.5
0.81
MW-D
8-Nov-11
5.7
3.21
2.9
1.81
57
0.41
0.7J
0.91
1.5J
3.9
0.91
MW-D
8-May-12
7
0.31
2.71
6.2
1.3J
56
1
11
1.71
5.3
0.81
MW-D
27-Nov-12
6.5
0.31
1.31
6.4
1.3J
54
1.5
0.7J
0.2J
5.3
4.0
0.6J
MW-D
8-May-13
6.9
0.4J
1.6J
9.4
1.2J
56
0.81
2.2
2.7J
5.9
0.71
MW-D
5-Nov-13
7.2
0.5J
1.8J
9.3
1.01
57
0.81
1.81
4.6
0.91
MW-D
6-May-14
5.1
0.4J
1.1J
7.8
0.7J
39
3.3J
3.9
0.6J
MW-D
4-Nov-14
6.9
0.5J
0.9J
30
0.91
53
0.2J
0.4J
1.5J
4.6
0.61
MW-D
5-May-15
5.9
0.6J
7.3
0.51
38
0.2J
1.81
3.3
0.51
MW-D
28-Och15
5.3
0.91
8.1
0.5J
37
1.5J
2.7
0.61
MW-D
17-May-16
5.0
0.7J
9.9
39
1.71
2.8
1302-MSWLF-
MW-D
2-Nov-16
6.5
0.8J
1.3J
12
0.5J
48
3.2J
2.6
1.1
CDLF-1998
MW-D
9-May-17
5.1
0.91
9.8
35
2.5
0.81
MW-D
1-Nov-17
5.9
0.81
1.5J
30
0.4J
41
3.9J
2.3
MW-D
7-Jun-18
5.4
0.93J
10.1
36.0
0.62J
2.6
MW-D
19-Dec-18
2.7
0.72J
0.69J
10.9
0.41J
30.5
1.6
0.801
MW-D
9-May-19
4.2
1.0
1.1
9.1
23.4
1.3
0.67J
MW-D
5-Nov-19
5.3
1.1
0.75J
9.4
26.3
.)
1.0
0.911
MW-D
20-May-20
2.3
0.60J
6.4
12.8
0.901
0.63J
MW-D
24-Sep-20
4.2
0.80
0.70
5.3
12
_.)
0.41J
0.90
1.9
MW-D)dup)
24-Sep-20
4.1
0.74
0.68
4.8
11
0.41J
0.86
2.0
MW-D
18-Mar-21
2.8
0.48J
0.49J
2.9
3.1
1.4
MW-D
18-Nov-21
4.2
0.69
0.46HJ
3.8
7.4
0.67
1.8
MW-E Rep
4-May-11
6
2.5J
4.5J
14
20
11
7
0.91
11
6.3
MW-E Rep
8-Nov-11
3.3
0.7J
2.1J
4.2J
11
20
0.81
54
0.81
1.1
2.2
5
MW-E Rep
8-May-12
2.5
2.4J
5.7J
13
23
1.1
47
0.91
1.1
0.4J
0.3J
1.8
6.6
MW-E Rep
8-May-13
1.3
2.78J
3.7J
14
19
0.71
21
0.7J
1.2
0.51
4.4
MW-E Rep
5-Nov-13
2.3
3.2
3.7J
16
19
1.2
41
0.7J
1.0
7.6
MW-E Rep
6-May-14
2.9
3.2
2.9J
16
14
1.0
53
0.7J
1.0
0.2J
1.4
9.3
MW-E Rep
4-Nov-14
1.5
4.1
3.6J
18
15
1.1
43
0.7J
1.0
7.5
MW-E Rep
5-May-15
3.4J
0.8J
3.1
4.21
0.3J
15
8.8
1.01
25
0.4J
1.1
0.51
3.8
MW-E Rep
27-OCt-15
1.0
3.9
5.11
0.3J
15
9.0
1.1
27
0.4J
0.61
4.3
1302-MSWLF-
MW-E Rep
18-May-16
0.81
2.3J
7.61
8.2
0.91
12
0.91
3.2
CDLF-1998
MW-E Rep
1-Nov-16
0.61
3.2
8.01
15
11
1.1
18
0.5J
4.5
MW-E Rep
9-May-17
0.7J
3.0
6.21
14
5.9
0.7J
18
0.5J
0.8J
3.5
MW-E Rep
31-OCt-17
0.61
3.1
8.21
15
5
1.2
21
0.81
4.4
MW-E Rep
11-Jun-18
0.73J
2.8J
6.51
10.0
2.5J
16.7
0.70J
2.9
MW-E Rep
20-Dec-18
0.661
3.8
6.31
12.3
2.6J
22.1
0.531
0.81J
2.0
3.6
MW-E Rep
7-May-19
0.76J
4.2
5.3
16.9
2.8
28.3
0.701
0.63J
2.5
4.0
MW-E Rep
5-Nov-19
0.52J
3.6
5.4
15.4
1.8
1.1
21.6
0.541
0.78J
2.7H3
4.6
MW-E Rep
21-May-20
0.36J
5.6
1.3
0.911
17.1
0.62J
3.1
3.5
MW-E Rep
23-Sep-20
0.49J
2.4
3.5
6.9
1.8
0.85
17
0.431
0.64
3.9
MW-E Rep
17-Mar-21
0.60
1.7
1.0
1.2
0.68
9.7
2.8
MW-E Reo
17-Nov-21
0.46J
2.4
4.7H
8.2
1.3
0.80
11
0.43J
0.72
3.8
2.7
Smith Page 18 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smth Page 19 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smith Page 20 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smith Page 21 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Smith Page 22 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
o
Z.
North Carolina
o
ZL Groundwater
or IMAC
MW-L
4-May-11
rrr ,,, 40 rr r rrr r r . r 0.4 r 0.6 rr
r
rr rr rr
,,, 0.03
MW-L
9-Nov-11
MW-L
9-May-12
MW-L
28-Nov-12
1.01 1.11
1.2
2.5
2.4
MW-L
9-May-13
MW-L
7-Nov-13
MW-L
8-May-14
MW-L
5-Nov-14
MW-L
6-May-15
MW-L
28-Oct-15
1302-MSWLF-
MW-L
19-May-16
CDLF-1998
MW-L
2-Nov-16
MW-L
30-May-17
MW-L
I-Nov-17
0.81 0.4J
1.0
MW-L
7-Jun-18
0.561
MW-L
19-Dec-18
MW-L
8-May-19
MW-L
7-Nov-19
0.911 .)
MW-L
21-May-20
MW-L
23-Sep-20
_.)
MW-L
17-Mar-21
MW-L
17-Nov-21
0.481
MW-L Deep
4-May-11
1.41
1.2J
0.7J
13
3.7
1.6
MW-L Deep
8-May-12
5.8
0.41
0.6J
0.4J
1.4
1.2
0.6J
MW-L Deep
9-May-13
1.21
1.8J
0.91
16
5.1
1.5
MW-L Deep
8-May-14
0.4J
0.51
0.8J
2.2
1.7
0.4J
MW-L Deep
6-May-15
5.6
0.51
0.6J
0.4J
3.5
1.8
0.6J
MW-L Deep
29-0c1:45
4.6J
0.6J
2.2
1.5
0.51
1302-MSWLF-
MW-L Deep
19-May-16
3.2J
2.0
0.91
CDLF-1998
MW-L Deep
10-May-17
3.8J
2.1
1.0
MW-L Deep (dup)
10-May-17
3.7J
1.7
1.1
MW-L Deep
7-Jun-18
0.97J
5.3
1.0
0.38J
5.4
MW-L Deep
8-May-19
3.3
1.0
0.65J
MW-L Deep
21-May-20
5.0
2.9
MW-L Deep
19-Mar-21
4.8
1.6
0.93
0.61
MW-M
4-May-11
0.4J
MW-M
8-May-12
0.91
0.3J
MW-M
9-May-13
1.11
0.S1
MW-M
8-May-14
1.11
MW-M
5-May-15
1.01
0.4J
1302-MSWLF-
MW-M
28-Oct-15
0.91
CDLF-1998
MW.M
17-May-16
0.81
MW.M
9-May-17
0.61
MW.M
7-Jun-18
0.641
0.531
MW-M
9-May-19
1.2
2.2
0.38J
MW-M
19-May-20
0.481
MW-M
19-Mar-21
1.5
0.51
Smith Page 23 of 31 January 2022

Table 5b
Detected Groundwater Constituents - Volatile Organic Compounds
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
Notes:
1. All units are in micrograms per liter (parts per billion).
2. Monitoring wells MW-3 Deep, -L Deep, -and -M are sampled annually during the spring event.
3. (dup) - Duplicate
4. Assessment Wells CD-4, CD-5, and CD-6 were installed in September 2006. CD-4 and -5 were abandoned in July 2010. CD-6 was abandoned in February 2017.
5. Assessment Wells AMW-1s, -1d, -2s, and -2d were installed in October 2009.
6. MW-9 was removed from the monitoring program in November 2012. CD-1s/CD-1d replaced MW-9 as the background monitoring wells.
7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight.
B. —- 1,4-Dioxane was removed from the sampling program for CD -IS, -1d, -4 Rep, MW-3, -3 deep, -A, -C, -D, -H deep, -I, -1, -K, A, -L deep, AMW-1s, -1d, -2s, and -2d due to two consecutive non -detect events.
9. * - Interim Maximum Allowable Concentration (IMAC)
10. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit.
11. B - Indicates constituent was detected in the batch blank above the method detection limit.
12. H3 - The sample was received or analysis was requested beyond the method holding time.
13. M1- The matrix spike recovery exceeded quality control limits. The value was accepted based on laboratory control sample recovery.
14. RI -The relative percent difference value was outside control limits.
15. L- Laboratory control spike/laboratory control spike detection failure.
Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) Groundwater Standard or IMAC
- Indicates the result is below the detection limit.
Smith Page 24 of 31 January 2022

Table 3c
Detected Surface Water Constituents - Volatile Organic Compounds and Metals
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
NC 2B or In -Stream
Aquatic Life or Fish
Target Value
Consumption
SW-1
Freshwater
Standard
9-Nov-11
-.10, L"e, 000(s
94.01
.-S",
­11 NI NIS
0.771 2.601 0.231 5.321 1.741
DRY
DRY
SW-1
9-May-12
DRY
DRY
SW
28-Nov-12
82.11
0.06J
3.79J 2.01J
0.16J
6.301
2.OS1
4.931
SW-1
10-May-13
SW
5-Nov-13
1.061
139
9.52I 1.75J
0.0"
8.511
2.851
0.121
2.01
0.31
SW-1
S-May-14
1.80J
146
0.371
4.6361
31.7 6.341
3.58
9.791
2.831
14.41
34.3
DRY
DRV
SW
3-Nov-14
DRY
DRY
SW-1
S-May-15
0.89J
69.21
1.011
1.72J
5.091
4.39J
2.93CN,1
2.371
SW
29-0ct-15
1302-MSWLF-CDLF-
1998
SW-1
SW-1
19-May-16
1-Nov-16
3.521
157
1.44
31.2
15.6
25.1
14.8
17.21
5.393
0.08J
65.2
64.0
DRY
DRY
66.6J 3.69J 2.04J 1.04J 0.07J 5.921
SW-1
10-May-17
DRY
DRY
SW-1
31-Oct-17
DRY
DRY
SW
7-Jun-18
0.70J
57.6J
0.052J
1.81
2.01
0.341
4.41
3.21
4.91
4.4
2.1
SW
18-Dec-18
SW-1
9-May-19
66.9
0.76J
1.31
0.16J
5.1
1.31
3.91E
8.7
SW
6-Nov-19
59.1
0.38J
S.OB
0.064JB
2.91
0.0581
6.51E
5.9
SW
19-May-20
65.4
0.711
1.91
1.51
0.211
4.SJ
3.]J
9.9
SW
25-Sep-20
49
0.241
4.51
1.91
7.2
2.4
4.51
8.6
13
1.21
SW-1
19-Mar-21
61
2.9J
1.71
4.3J
1.3
7.4
3.5J
19
DRY
DRY
SW-1
17-Nov-21
SW
9-Nov-11
DRY
DRY
65.31 1.06J 0.88J 1.68J 0.851 3.33J 1.33J
SW
9-May-12
DRY
DRY
SW
28-Nov-12
0.97J 78.9J 0.63J 2.53J 2.20J 0.80 6.36J 3.02J 6.05J
SW
10-May-13
DRY
DRY
SW
5-Nov-13
1.451
137
O.OSJ
3.291
3.65J
1.52B1
6.991
3.68J
7.11I
24.5
SW-2
6-May-14
SW
3-Nov-14
1.881
67.01
12.7
0.571
0.05J
1.421
1.081
5.15E-01,1
6.01
1.8
SW
5-May-15
73.2B-01,1
3.16J
1.211
6.341
3.401
1.361
SW
29-0ct-15
1.681
81.11
0.101
0.691
3.641
0.951
4.601
6,1W
3.28CN,1
1.93J
5.48J
1302-MSWLF-CDLF-
1998
SW-2
SW-2
19-May-16
1-Nov-16
2.35J
89.01
0.94J
12.2
7.211
31.9
8.731
8.331
3.401
32.7
35.0
DRY
DRY
94.71 2.221 0.89J 0.311 I 4.81J
SW-2
10-May-17
DRY
DRY
SW-2
31-Oct-17
0.991
42.9J
1.41 0.37J 2.51
SW-2
7-Jun-18
SW-2
18-Dec-18
0.63J
71.8J
0.111
1.91
1.81
1.91 3.11
4.3J
3.61
2.5
1.8
SW-2
10-May-19
83.8
2.3J
1.7J 5.1
2.8JB
7.3
SW-2
6-Nov-19
0.621
83.9
0.66J
0.35J
3.3JM 0.221E 2.71
1.3J
7.11B
3.8
SW-2
19-May-20
0.69J
100
0.23J
3.SJ
3.21
4.11 5.4
1.7J
8.61
10.2
6.7
SW-2
25-Sep-20
2.7
91
0.77
25
4.81
18 8.8
2.7J
33
34
SW-2
19-Mar-21
37
0.30J
2.6J
9. 2.41
7.1
5.2I
DRY
DRY
SW-2
17-Nov-21
Notes:
1. All units are in micrograms per liter (parts per billion).
2. NS - No Standard
3. l'I - A Standard for total chromium has not been established. The value provided is for chromium (III).
4. lal - North Carolina 15A NCAC 02B (NC 2B) Fish Consumption Standard
S. lsI - North Carolina In -Stream Target Value Freshwater Aquatic Life Standard
6. lei _NC
2B Freshwater Aquatic Life Standard
7. or - North Carolina In -Stream Target Value Fish Consumption Standard
8. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
9. B -The analyte concentration detected in the method blank was greater than the method detection limit.
10. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid.
Concentration exceeds the NC 2B or In -Stream Target Value Freshwater Aquatic Life or Fish Consumption Standard for Class C Waters - July 2021
- Indicates the result is below the detection limit.
Smith 25 of 31 January 2022

Table Sd
Geochemical Constituents in Groundwater
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facilty Permit Number 1302-MSWLF-CDLF-1998
0.1 <0.15 0.65 37 50 <0.5 <6 1.3 0.161 0.091)
o
1302-MSWLF-
MW-9
3-May-11
3.45
139
<0.010
0.004
1.7
0.088
<0.05
0.14
0.411
<0.6
3.1
CDLF-1998
MW-9
9-Nov-11
4.70
212
0.062
0.078
3.5
<0.07
<0.05
0.033
<0.05 <0.15 1.4 53 35 <2 11 1.3 0.9JH 0.094J
0.26J
<1
0.4B
MW-9
9-Ma -12
1.82
127
0.11
0.012
6.7
0.038
<0.05
0.086
<0.05 <0.15 2.8 41 36 <0.002 <10 1.6 <0.2H 0.1801
<5
<0.2
0.484
CD -Is
3-May_11
__
__
__
__
__
__
__
__
__
__
__
__
47
__
__
3.6
__
__
1.2J
CD -Is
8-Nov-11
__
__
__
__
__
__
__
__
__
__
__
__
40
__
__
4
__
__
1.11
CD-1s
7-May_12
__
__
__
__
__
__
__
__
__
__
__
__
46
__
__
3.9
CD-1s
27-Nov-12
15.56
139
<0.025
0.019
1.1
<0.07
0.029
<0.10
<0.05
<0.15
0.94
54
39
<2
<10
4.1
0
0.06J
<5
<0.2
<1
CD-1s
7-May-13
1.96
206
0.21
0.14
3.8
<0.07
<0.05
0.055
<0.05
<0.15
0.82
30
42
<2
0.64
4
0.22
0.066J
<5
<0.2
<1
CD-1s
5-Nov-13
1.74
348
0.0033
0.0037
0.33
0.034
0.056
0.20
<0.05
<0.15
0.74
15
30
<2
<10
3.8
2.42
0.082J
<5
<0.2
<1
CD-1s
6-May-14
0.02
353
0.0032
0.010
3.4
0.037
<0.05
<0.10
<0.05
<0.15
0.94
54
42
<2
<10
3.8
0
0.077J
<5
<0.2
1.07
CD-1s
4-Nov-14
6.06
135
0.0061
0.011
1.8
0.041
<0.05
0.037
0.052
<0.15
1.7
62
41
<2
<10
3.9
0
0.065J
<5
<0.2
<1
CD-1s
5-May-15
3.99
281
0.0034
0.016
0.060
0.081
<0.05
0.019
<0.05
0.034
26
42
38
<2
<10
3.8
0
0.120J
<5
<0.2
3.48
CD-1s
27-Oct-15
3.84
519
<0.10
0.012
0.12
0.036
0.0094
<0.20
0.0024
<0.10
40
61
43
<2
30.6
3.8
0
0.130J
<5
<0.2
<1
1302-MSWLF-
CD-1s
17-May-16
3.45
245
<0.10
<0.10
0.048
0.020
<0.10
0.011
<0.10
<0.10
22
46
43
<2
<10
3.7
0
0.079J
1
<0.2
<1
CDLF-1998
CD-1s
1-Nov-16
4.49
360.2
0.0031
0.0099
0.84
0.038
0.0076
0.0090
<0.10
<0.10
3.1
60
46
<2
26.5
4.2
0
0.067J,H-02
<5
<0.2
<1
CD-1s
9-May-17
1.69
274.6
0.0035
0.0026
0.50
0.035
<0.10
<0.20
<0.10
<0.10
7.8
48
49
<2
<10
3.6
0
0.076J
1.3J
<0.2
<1
CD -Is
31-Oct-17
1.87
58
<0.10
<0.10
0.18J
<0.10
<0.10
<0.20
<0.10
<0.10
14
58
50
<2
14.6
4.2
0
0.066
1.01
<0.2
<1
CD-1s
11-Jun-18
3.8
124.1
0.036J
0.031J
15.00
0.031J
<0.10
0.021J
<0.10
<0.10
6.4
44
49
<2
<10
3.89
0
0.0820
0.904J
<0.2
<1
CD -Is
17-Dec-18
5.6
38.6
<0.10
<0.10
3.50
<0.30
<0.30
<0.20
<0.30
<0.30
420
46
46
<2
<10
3.72
0
0.146
0.993J
<0.2
<1
CD-1s
7-May-19
5.26
242.4
<0.0050
<0.0040
0.053J
0.032J
<0.011
<0.043
<0.0040
<0.0050
2.5
50
43
<2
<10
2.93
0
0.359
12.6
<0.2
<1
CD -Is
5-Nov-19
1.49
197.0
<0.0050
<0.0040
0.18J
0.15
<0.011
0.091J
<0.0040
<0.0050
28
61
43
<2
<50
3.75
0
0.134H1
2.16J
<0.2
<1.0
CD -Is
18-May-20
4.3
-32.4
<1.00
<1.00
<2.00
<0.18
<0.089
<0.13
<0.065
<0.021
-(")
166
49.1
<2
<10
4.57
0
0.254
4.28
<0.1
0.616J
CD-1s
23-Sep-20
6.0
50.1
<10
<10
5.9J
0.55
<0.058
<0.053
0.053J
<0.060
0.73J
96
51
<2.0
<20
5.5
0
0.21
2.5
<0.10
<1.0
CD -Is
17-Mar-21
3.98
-91.2
<10
<10
2.5BJ
--
--
--
--
--
0.99J
27
53
<2.0
<20
1.0
0
0.42E
4.8
<1.0
<1.0
CD-1s
17-Nov-21
3.95
73.6
<2.5
<2.5
<2.5
3.0
<0.058
0.78
<0.053
<0.060
0.85J
150
50
<0.18
<20
9.4
0
0.32
1.1
<1
0.62J
Mid
3-May_11
__
__
__
__
__
__
__
__
__
__
__
__
57
__
__
2.6
__
__
3J
CD-1d
8-Nov-11
__
__
__
__
__
__
__
__
__
__
__
__
30
__
__
2.9
__
__
3J
Mid
7-May_12
__
__
__
__
__
__
__
__
__
__
__
__
50
__
__
2.8
__
__
<5
CD-1d
27-Nov-12
9.53
140
--
--
--
--
--
--
--
--
--
--
46
--
--
3
0
0.07J
<5
--
--
Mid
7-May-13
1.11
242
0.015
0.015
0.31
0.021
<0.05
0.06
<0.05
<0.15
0.61
40
52
4
6.05
3
0.56
0.069J
<5
<0.2
1.42
CD-1d
5-Nov-13
1.71
320.1
--
--
--
--
--
--
--
--
--
--
42
--
--
3
--
--
<5
--
--
CD-1d
6-May-14
4.56
293
--
--
--
--
--
--
--
--
--
--
46
--
--
2.9
--
0.077J
<5
--
--
CD-1d
4-Nov-14
4.68
108.7
--
--
--
--
--
--
--
--
--
--
43
--
--
3.1
0
--
<5
--
--
CD-1d
5-May-15
4.84
186
--
--
--
--
--
--
--
--
--
--
44
--
--
2.9
0
0.0861
<5
--
--
CD-1d
27-Oct-15
4.10
507
--
--
--
--
--
--
--
--
--
--
46
--
--
2.9
0
--
<5
--
--
1302-MSWLF-
CD-1d
17-May-16
4.50
210
--
--
--
--
--
--
--
--
--
--
96
--
--
18.0
0
<0.05
14
--
--
CDLF-1998
CD-1d
1-Nov-16
3.10
330
--
--
--
--
--
--
--
--
--
--
52
--
--
3.4
0
--
<5
--
--
CD-1d
9-May-30
1.51
257.2
--
--
--
--
--
--
--
--
--
--
53
--
--
2.8
0
--
3.71
--
--
CD-1d
31-Oct-17
2.85
37
--
--
--
--
--
--
--
--
--
--
52
--
--
3.3
0
0.079J
3.3J
-
--
CD-1d
12-Jun-18
2.9
54.2
--
--
--
--
--
--
--
--
--
--
51
--
--
3.2
0
--
3.33J
--
--
CD-1d
17-Dec-18
3.6
25.1
--
--
--
--
--
--
--
--
--
--
53
--
--
3.11
0
--
3.36J
-
--
Mid
7-May-19
1.61
183.2
--
--
--
--
--
--
--
--
--
--
52
--
--
2.84
0
0.0808
3.14J
--
--
CD-1
5-Nov-19
1.84
190.7
--
--
--
--
--
--
--
--
--
--
48
--
--
3.14
0
--
3.07J
-
--
Mid
18-May-20
2.4
31.5
--
--
--
--
--
--
--
--
--
--
54.3
--
--
2.45
0
--
2.63
--
--
Mid
22-Sep-20
4.18
70.4
--
--
--
--
--
--
--
-
--
--
53
--
--
3.1
0
--
2.0
-
--
CD-1d
16-Mar-21
5.04
-68.8
--
--
--
--
--
--
--
--
--
--
53
--
--
3.1
0
--
2.5
--
--
CD-1d
17-Nov-21
3.37
67.9
--
--
--
--
--
--
--
--
--
--
51
--
--
3.3
0
--
2.6
--
--
CDM
Smith Page 26 of 31 January 2022

Table Sd
Geochemical Constituents in Groundwater
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facilty Permit Number 1302-MSWLF-CDLF-1998
AMW-1s
3-May-11
1.22
176
0.007
0.004
810
0.57
<0.05
0.13
0.63
<0.15
1
250
114
<0.5
<6
3.2
0.131
<0.006
0.36J
<0.6M03B
AMW-1s
8-Nov-11
0.17
12
0.031
0.068
1,100
<0.07
<0.05
0.08
<0.05
<0.15
1.1
320
95
3
9
3.1
<0.2
<0.05
0.26J
<1
AMW-1s
7-May-12
0.02
121
0.043
0.047
1,300
0.061
<0.05
0.089
<0.05
<0.15
82
300
105
<0.002
<10
3.2
<O.2H
<0.004
<0.18
<0.2
AMW-1s
28-Nov-12
3.81
44
0.064
0.031
1,000
<0.07
<0.05
<0.10
<0.05
<0.15
1.1
280
92
<2
<10
3.1
0.3
<0.05
<5
<0.2AMW-1s
8-May-13
0.34
523
0.11
0.054
1,600
0.029
<0.05
0.073
<0.05
<0.15
0.69
260
87
<2
14.4
3.5
0.11
<0.05
<5
<0.2AMW-1s
6-Nov-13
1.05
149
0.11
<0.025
1,400
0.041
0.061
0.15
0.015
<0.15
0.85
270
107
<2
<10
3.6
0.34
<0.05
<5
<0.2AMW-1s
7-May-14
0.02
400
0.095
<0.025
1,200
0.054
<0.05
0.026
0.036
<0.15
0.86
280
105
<2
<10
3.4
0
<0.05
<5
<0.2AMW-1s
5-Nov-14
3.25
132.2
0.15
0.015
1,000
0.055
<0.05
0.031
0.053
<0.15
1.7
280
120
<2
<10
3.7
0
<0.05
<5
<0.2
AMW-1s
7-May-15
2.00
592
0.2
0.0073
1,600
<0.07
<0.05
0.031
<0.05
<0.15
12
310
96
<2
<10
3.5
0
<0.5
<5
<0.2
<1
AMW-1s
29-0ct-15
2.68
253
0.21
0.0064
1,100
0.028
0.0052
0.0094
0.0022
<0.10
8.2
300
10.5
<2
<10
3.7
0
<0.05
0.22J
<0.2
<1
1302-MSWLF-
AMW-1s
18-May-16
3.77
222
0.17
<0.30
1,000
0.015
<0.30
0.0072
<0.30
<0.30
1.5
210
85
<2
<10
3.8
0
<0.05
<5
<0.2
1.44
CDLF-1998
AMW-1s
2-Nov-16
1.65
377.2
0.13
0.0064
820
0.044
<0.10
0.0092
<0.10
<0.10
6
270
100
<2
23.6
3.3
0
<0.05
<5
<0.2
<1
AMW-1s
30-May-17
1.54
148.6
0.25
0.0046
1,400
0.062
<0.30
<0.20
<0.30
<0.30
2.0
280
121
<2
25.1
4.2
0
<0.05
0.231
<0.2
<1
AMW-1s
1-Nov-17
2.39
227
O.097J
0.O3OJ
600
<0.10
<0.10
<0.20
<0.10
<0.10
3.1
200
93
<2
<10
3.5
0
<0.05
0.42J
<0.2
<1
AMW-1s
8-Jun-18
0.5
566.1
0.14
<0.30
1,200
0.O38J
<0.30
<0.20
<0.30
<0.30
5.4
280
383
<2
<10
2.99
0
<0.0500
<0.5
<0.2
<1
AMW-1s
19-Dec-18
0.7
510.5
0.24
<0.30
1,600
<0.30
<0.10
<0.20
<0.30
<0.10
5.6
260
115
2.28
<10
3.57
0
O.O36OJ
0.2911
<0.2
<1
AMW-1s
8-May-19
1.80
90.3
0.21
<0.0040
1,300
<0.025
<0.0070
<0.048
<0.0020
<0.0050
1.6
230
92
<2
<10
3.92
0
0.137
O.336J
<0.2
<1
AMW-1s
6-Nov-19
0.94
228.1
<0.10
<0.10
130
<0.10
<0.10
<0.20
<0.10
<0.10
1.4
170
67
<2
<50
3.32
0
0.145
O.346J
<0.2
<1.0
AMW-1s
18-May-20
0.8
92.4
<1.00
<1.00
321
<0.18
<0.089
<0.13
<0.065
<0.021
-Os'
515
105
<2
5.54J
3.01
0
<0.0100
<0.5
<0.0500
22.2
AMW-1s
23-Sep-20
0.42
61.3
<10
<10
790
0.481
<0.058
<0.053
O.054J
<0.060
O.77J
160
95
<4.0
<20
3.1
0
O.O14J
<1.0
<0.10
<1.0
AMW-1s
18-Mar-21
0.67
-168.0
<10
<10
23
O.3OJ
<0.058
<0.053
<0.053
<0.060
-'20)
68
51
<2.0
<20
2.1
0
O.O32B
<1.0
1.3
1.0
AMW-1s
17-Nov-21
0.93
89.4
<2.5
<2.5
7.3J
2.4
<0.058
0.44J
<0.053
<0.060
2.0J
170
50
4.5p)
<20
2.5
0
0.23
0.39J
<1
O.86J
AMW-1d
3-May-11
0.01
89
0.059
0.71
1,100
0.11
<0.05
<0.1
0.29
<0.15
0.89
170
295
1.8
<6
7.3
O.14J
<0.006
31J
3
1.3
AMW-Id
8-Nov-11
0.00
-112
0.18
1.4
2,900
0.23
<0.05
0.2
<0.05
<0.15
0.89
280
320
4
19
6.8
1
<0.05
27J
<1
4.6
AMW-1d
7-May-12
0.24
95
0.17
1.7
2,500
0.097
<0.05
0.11
<0.05
<0.15
480
270
230
6
<10
6.6
1.91H
0.0O6J
151
<0.2
4.11
AMW-Id
28-Nov-12
7.00
169
0.15
1.8
2,000
1.9
<0.05
<0.10
0.039
<0.15
0.511
240
265
4
30.2
6.4
1.8
<0.05
9.2J
0.434J
3.02
AMW-1d
8-May-13
0.46
-53
0.32
1.6
3,800
0.054
<0.05
0.089
0.028
<0.15
1
300
375
4
8.99
7.1
3.3
<0.05
12J
<0.2
4.95
AMW-Id
6-Nov-13
1.40
-22.7
0.28
1.1
3,400
0.033
0.066
0.12
<0.05
<0.15
0.96
290
315
<2
19.7
5.6
2.91
<0.05
6.4J
<0.2
3.4
AMW-1d
7-May-14
2.05
-28
0.32
0.82
3,700
0.082
<0.05
0.047
0.032
<0.15
1.3
330
230
2
<10
5.6
5
<0.05
<5
<0.2
2.16
AMW-1d
5-Nov-14
1.36
-67.7
0.33
1.3
3,000
0.34
<0.05
0.042
0.077
<0.15
2.0
320
375
2
44.9
5.4
4.0
<0.05
<5
0.241J
2.15
AMW-1d
7-May-15
1.78
-52
0.5
2.2
3,400
0.15
<0.05
0.014
<0.05
0.035
7.3
320
230
2
35.2
5.4
2.0
<0.5
<5
<0.2
3.41
AMW-1d
29-Oct-15
2.55
-42
0.79
4.0
4,000
0.27
0.0061
0.011
0.0050
<0.10
8.2
330
255
90)
<10
5.5
2.5
<0.05
<5
<0.2
2.67
1302-MSWLF-
AMW-1d
18-May-16
1.51
-28
2
2.2
3,700
0.021
<0.10
<0.20
<0.30
<0.30
1.8
300
225
<2
13.2
5.9
3.0
<0.05
<5
<0.2
2.93
CDLF-1998
AMW-1d
3-Nov-16
1.73
199.2
2.2
3.4
3,900
0.045
<0.10
0.0083
<0.10
<0.10
19.0
350
215
30
41.6
5.9
2.0
<0.05
<5
<0.2
3.42
AMW-1d
30-May-17
1.59
-6.7
3.9
2.2
3,700
0.047
<0.30
<0.20
<0.30
<0.30
2.5
280
225
30
29.6
6.1
7.0
<0.05
O.065J
<0.2
2.27
AMW-1d
1-Nov-17
3.51
159
3.6
1.6
4,000
<0.10
<0.10
<0.20
<0.10
<0.10
2.9
280
230
<2
20.0
6.3
3.0
<0.05
0.471
<0.2
2.64
AMW-1d
8-Jun-18
3.2
21.3
1.3
0.75
1,900
0.O43J
<0.10
<0.20
<0.30
<0.30
1.7
260
223
<2
<10
5.26
0
<0.0500
O.579J
<0.2
1.02
AMW-1d
19-Dec-18
0.5
1.8
2.6
1.5
3,500
<0.10
<0.10
<0.20
<0.10
<0.10
11
360
202
<2
<10
7.18
6.0
0.01701
0.5731
<0.2
1.02
AMW-1d
8-May-19
1.71
91.1
1.4
0.73
2,700
0.O38J
<0.0070
<0.048
0.O065J
<0.0050
1.3
300
145
2.12
<10
7.15
2.0
O.O22OJ
0.480J
<0.2
1.04
AMW-1d
6-Nov-19
1.04
173.0
<0.10
<0.10
190
<0.10
<0.10
<0.20
<0.10
<0.10
1.6
190
80
<2
<50
3.39
0
0.152
<0.2
0.314J
<1.0
AMW-1d
18-May-20
2.5
-43.2
<1.00
<1.00
700
<0.18
<0.089
<0.13
<0.065
<0.021
-his)
704
197
2.69
<5
5.95
5.5
<0.0100
<0.5
<0.0500
0.9281
AMW-1d
23-Sep-20
0.30
27.9
<10
<10
2,700
2.2J
<0.29
<0.26
<0.26
<0.30
O.82J
270
200
4.7,7
<20
6.4
2
O.O52HJ
<1.0
<0.20
<1.0
AMW-1d
17-Mar-21
1.06
-164.2
<10
2.7J
990
O.33J
<0.058
<0.053
<0.053
<0.060
_(2°)
380
200
<2.0
<20
6.4
2.5
O.O42BHJ
0.39J
1.1
1.1
AMW-1d
17-Nov-21
0.41
44.5
2.5J
<2.5
1,600
4.9
<0.058
0.71
<0.053
<0.060
1.31
590
190
3.7(21)
<20
6.6
2.5
0.0094J
0.25J
<1
1.2
CDM
Smith Page 27 of 31 January 2022

Table Sd
Geochemical Constituents in Groundwater
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facilty Permit Number 1302-MSWLF-CDLF-1998
0.063 <0.15 1.2 130 77 <0.5 20 3.2 <0.07 0.086
AMW-2s
3-May-11
2.10
128
0.003
0.014
0.240
0.098
10.05
0.12
0.2J
<0.6
1.2
AMW-2s
8-Nov-11
2.47
-30
0.016
0.076
4
<0.07
<0.05
0.092
<0.05 <0.15 0.68 170 70 11 10 3.2 0.2JH 0.1J
0.097J
<1
0.6B
AMW-2s
8-May-12
0.42
195
0.014
0.022
0.34
0.042
<0.05
0.53
<0.05 <0.15 9.7 170 70 1.29 <10 3.4 <0.2H 0.12J
<5
<0.2
0.418
AMW-2s
29-Nov-12
5.36
38
<0.025
0.026
0.86
<0.07
0.025
<0.10
<0.05 <0.15 0.41J 170 8 <2 <10 3.3 <0.2H 0.111
<5
<0.2
<1
AMW-2s
9-May-13
0.88
153
0.008
0.022
4.30
0.047
<0.05
0.11
<0.05 <0.15 0.87 160 46 4 13.5 3.5 0.43 0.13J
<5
<0.2
1.52
AMW-2s
6-Nov-13
1.51
75.1
0.0045
<0.025
0.58
0.020
0.068
0.10
<0.05 <0.15 0.94 140 63 <2 15.8 3.5 0.55 0.16J
<5
<0.2
12.3
AMW-2s
7-May-14
2.08
114
0.022
0.0081
0.31
0.062
0.033
0.032
0.032 <0.15 25 180 60.6 <2 <10 3.6 0 0.16J
<5
<0.2
1.07
AMW-2s
5-Nov-14
3.48
120.5
0.0054
0.014
0.20
0.036
<0.05
<0.10
0.048 0.046 1.4 180 95 <2 <10 3.6 0 0.17J
<5
<0.2
<1
AMW-2s
6-May-15
3.50
562
0.0044
0.020
1.10
<0.07
<0.05
0.013
<0.05 <0.15 52.0 180 53 <2 <10 3.5 0 0.22J
<5
<0.2
1.05
AMW-2s
28-0ct-15
4.19
187
0.0048
0.056
0.26
0.026
0.0050
0.0087
0.0016 <0.10 8.0 160 64 <2 <10 3.7 0 0.24J
<5
<0.2
1.15
1302-MSWLF-
AMW-2s
17-May-16
3.22
51
<0.10
0.012
4.60
0.017
<0.30
<0.20
<0.30 <0.10 1.9 180 65 <2 <10 3.4 0 0.29J
<5
<0.2
<1
CDLF-1998
AMW-2s
1-Nov-16
3.38
235.1
0.0087
0.014
3.80
0.027
0.0073
0.0077
<0.10 <0.10 2.9 200 69 <2 25.8 3.7 0 0.31J,H-02
<5
<0.2
1.02
AMW-2s
10-May-17
1.55
48.2
0.078
0.018
0.82
0.019
<0.30
0.019
<0.30 <0.10 7.3 160 720 <2 14 3.5 0.5 0.41J
0.33J
<0.2
<1
AMW-2s
1-Nov-17
4.42
280
0.0095J
0.0181
0.50J
<0.10
<0.10
<0.20
<0.10 <0.10 8.5 150 74.0 <2 10 3.6 0 0.43
0.38
<0.2
<1
AMW-2s
8-Jun-18
2.2
162.2
0.14
0.066J
1.2
0.028J
<0.30
<0.20
<0.30 <0.10 2.9 150 257 <2 <10 2.79 0 0.362
<0.5
<0.2
<1
AMW-2s
20-Dec-18
2.9
101.3
<0.30
<0.30
<0.50
<0.30
<0.10
<0.20
<0.30 <0.10 12 160 71 <2 <10 3.22 0 0.452
0.797J
<0.2
1.31
AMW-2s
7-May-19
1.74
201.1
0.070J
0.36
17
0.036J
0.00781
<0.048
<0.0020 <0.0050 1.5 190 79 <2 <10 2.78 0 0.342
0.306J
<0.2
<1
AMW-2s
6-Nov-19
1.06
197.2
<0.10
<0.10
<0.50
<0.10
<0.10
<0.20
<0.10 <0.10 1.0 160 71 <2 <50 3.35 0 0.45
0.549J
<0.2
<1.0
AMW-2s
19-May-20
2.2
24.1
<1.00
<1.00
<2.00
<0.18
<0.089
<0.13
<0.065 <0.021 -0s) 356 71.6 <2 <5 2.62 0 0.408
<0.5
<0.0500
0.759J
AMW-2s
23-Sep-20
2.97
60.3
<10
<10
6.41
0.50
<0.058
<0.053
<0.053 <0.060 0.86J 120 74 <2.0 <20 2.8 0 0.30
<1.0
<0.10
<1.0
AMW-2s
17-Ma,21
2.86
-176.4
<10
<10
3.11
--
--
--
-- -- 0.99J 320 72 <2.0 <20 320 0 0.25B
<1.0
<1.0
<1.0
AMW-2s
17-Nov-21
2.41
78.0
1 <2.5
1 <2.5
<2.5
2.2
<0.058
0.51
<0.053 <0.060 1.OJ 320 66 <0.0018 <20 3 0 0.36
<0.25
<1
<1.0
AMW-2d
3-May-11
0.75
107
0.005
0.037
0.41
0.052
<0.05
0.12
0.066
<0.15
0.86
44
129
<0.5
<6
3.1
0.081
0.017J
4.3J
<0.6
0.8
AMW-2d
8-Nov-11
1.07
-29
0.03
0.19
7.10
<0.07
<0.05
0.032
<0.05
<0.15
1.4
96
75
<2
7
2.9
<0.2H
0.0111
3.5J
<1
0.7B
AMW-2d
8-May-12
0.00
195
0.053
0.073
1
0.037
<0.05
0.087
<0.05
<0.15
31
98
80
<0.002
<10
3
<0.2H
<0.05
<5
<0.2
0.932
AMW-2d
28-Nov-12
3.47
149
0.10
0.69
30
0.99
<0.05
<0.10
0.030
<0.15
0.68
110
79
<2
13.5
3.2
0.3
<0.05
<5
<0.2
<1
AMW-2d
9-May-13
0.36
126
0.013
0.049
1.1
0.1
<0.05
0.08
<0.05
<0.15
1.5
110
65
1.48
11.7
3
0.06
<0.05
<5
<0.2
<1
AMW-2d
6-Nov-13
1.40
137.7
0.0072
0.048
0.48
0.027
0.061
0.12
<0.05
<0.15
0.65
68
85
20.4
<10
3.1
0.16
0.181
<5
<0.2
<1
AMW-2d
7-May-14
3.88
95
0.0068
0.021
0.36
0.073
<0.05
0.033
0.030
<0.15
18
170
78.8
<2
<10
3.2
0.5
<0.05
<5
<0.2
<1
AMW-2d
5-Nov-14
4.19
103.5
0.016
0.016
0.27
0.04
<0.05
0.016
0.048
<0.15
1.3
100
130
<2
<10
3.3
0
<0.05
<5
<0.2
<1
AMW-2d
6-May-15
2.51
391
0.011
0.035
0.97
<0.07
<0.05
<0.1
<0.05
<0.15
23.0
200
90
<2
<10
3.4
0
<0.5
<5
<0.2
<1
AMW-2d
28-Oct-15
3.90
158
0.013
0.039
0.20
0.030
0.0075
0.0051
0.0024
<0.10
9.0
120
98
<2
<10
3.3
0
<0.05
<5
<0.2
<3
1302-MSWLF-
AMW-2d
17-May-16
2.69
88
0.023
0.012
0.49
0.036
<0.10
<0.20
<0.10
<0.10
1.0
160
110
<2
<10
3.5
0
<0.05
<5
<0.2
<1
CDLF-1998
AMW-2d
2-Nov-16
2.15
345.8
0.015
0.2
2.00
0.020
<0.10
0.075
<0.10
<0.10
2.3
230
110
<2
31.2
4.2
0
<0.05
<5
<0.2
<1
AMW-2d
10-May-17
1.47
37.0
0.080
0.29
6.9
0.020
<0.10
0.013
<0.10
<0.10
7.7
200
121
<2
<10
3.7
0
<0.05
0.32J
<0.2
<1
AMW-2d
2-Nov-17
3.20
151.0
0.020J
0.27
9.2
0.021J
<0.10
<0.20
<0.10
<0.10
2.9
190
131
<2
<10
3.9
0
<0.05
0.521
<0.2
<1
AMW-2d
8-tun-18
0.6
13.9
0.0141
0.28
12.0
0.046J
<0.10
<0.20
<0.10
<0.10
3.2
200
374
<2
<10
2.86
0
<0.0500
<0.5
<0.2
<1
AMW-2d
20-Dec-18
0.9
65.3
<0.30
<0.30
72
<0.30
<0.10
<0.20
<0.30
<0.30
16
240
137
<2
<10
3.4
1.5
<0.050
0.819J
0.272
<1
AMW-2d
7-May-19
2.55
165.2
0.0371
0.050J
0.25J
<0.025
<0.0070
<0.048
<0.0020
<0.0050
1.7
150
132
<2
<10
3.59
0
<0.050
0.618J
<0.2
1.04
AMW-2d
6-Nov-19
1.44
198.1
<0.10
<0.10
0.79
<0.10
<0.10
<0.20
<0.10
<0.10
2.7
97
142
<2
<50
3.63
0
0.0710
0.635J
<0.2
0.84J
AMW-2d
19-May-20
0.5
-22.9
<1.00
<1.00
43.9
<0.18
<0.089
<0.13
<0.065
<0.021
-("'
530
140
<2
<5
2.82
1.0
<0.0100
0.508J
<0.0500
0.742J
AMW-2d
23-Sep-20
0.37
12.7
<10
<10
21
0.56
<0.058
<0.053
<0.053
<0.060
0.58J
140
130
<4.0
<20
3.2
0
0.023
<1.0
<0.10
<1.0
AMW-2d
17- Ma, -21
0.41
-93.0
<10
<30
7.11
0.31J
<0.058
<0.053
<0.053
<0.060
1.2J
260
140
<2.0
<20
3.3
0
0.046B
0.26J
<3.0
<3.0
AMW-2d
16-Nov-21
0.66
56.1
<2.5
<2.5
410
3.9
<0.058
0.48J
<0.053
<0.060
1.4J
420
130
<0.18
<20
3.4
0
<0.0050
0.37J
<1
<3.0
Smith Page 28 of 31 January 2022

Table Sd
Geochemical Constituents in Groundwater
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facilty Permit Number 1302-MSWLF-CDLF-1998
Units
Mg/1 M.4,4 I
0.094 <0.15 1.1 69 69 <0.5 <6 2.8 0.181 0.022J
i
MW-3
4-May-11
Mg/1
2.60
MV01tS
164
Vg11
0.003
[AgIl
0.006
Vg11
0.5
Mg/1
0.24
Mg/1
0.098
Mg/1
0.19
0.25J
nng/1
<0.6rO.3O3
MW-3
9-Nov-11
4.05
198
0.04
0.059
1.6
<0.07
<0.05
0.043
<0.05 <0.15 0.8 120 65 <2 <10 2.9 O.18JH 0.0191
0.15J
<1
MW-3
8-May-12
2.76
113
<0.025
0.021
0.14
0.072
<0.05
0.13
<0.05 <0.15 1.5 100 60 <0.002 <10 3.6 0.3H <0.05
<5
<0.2
MW-3
28-Nov-12
12.31
73
0.044
0.022
0.83
<0.07
<0.05
<0.10
<0.05 <0.15 1.1 120 91 <2 <10 3.2 <0.2H <0.05
<5
<0.2MW-3
9-May-13
1.88
188
0.018
0.0079
0.40
0.025
<0.05
0.082
<0.05 <0.15 1.6 82 52 <2 10.1 3.1 1.11 <0.05
<5
<0.2MW-3
7-Nov43
1.99
301.1
0.0035
0.0075
0.34
0.049
<0.05
0.22
0.015 <0.15 1.4 110 69 26 28.1 3.4 0.83 <0.05
<5
<0.2
MW-3
8-May-14
0.04
150
0.0062
0.030
0.16
0.080
<0.05
0.053
0.034 <0.15 1.1 140 63.6 6 <10 3.2 0 <0.05
<5
<0.2
MW-3
6-Nov-14
5.94
465.6
0.0040
0.015
0.30
0.045
<0.05
0.040
0.048 <0.15 1.6 140 61 <2 <10 3.3 0 <0.05
<5
<0.2
<1
MW-3
6-May-15
2.29
260
0.0085J
0.016
0.18
<0.07
<0.05
0.014
<0.05 <0.15 14 140 65 <2 76.2 3.4 0 <O.5
<5
<0.2
1.43
MW-3
28-0ct-15
3.85
166
0.23
0.022
0.20
0.026
0.0058
<0.20
0.0016 <0.10 11 130 69 <2 <10 3.4 0 <0.05
<5
<0.2
<1
1302-MSWLF-
MW-3
18-May-16
3.18
101
<0.30
<0.30
0.87
0.015
<0.30
0.0092
<0.30 <0.30 9.6 120 75 <2 <10 3.7 0 <0.05
<5
<0.2
1.32
CDLF-1998
MW-3
2-Nov-16
3.50
438.8
0.020
0.021
0.72
0.031
<0.10
0.0082
<0.10 <0.10 1.9 130 60 <2 14.9 4.1 0 <0.05
<5
<0.2
<1
MW-3
11-May-17
1.75
229.6
0.0045
0.0087
0.33
0.052
<.030
0.0095
0.022 <0.30 9.1 140 78 <2 <10 3.9 0 <0.05
0.6J
<0.2
<1
MW-3
1-Nov-17
1.60
325
0.011J
0.022J
0.64
<0.10
<0.10
<0.20
<0.10 <0.10 2.4 120 80 <2 <10 4.2 0 <0.05
0.22J
<0.2
<1
MW-3
7-Jun-18
3.7
130.6
<0.30
0.017J
0.35J
0.034J
<0.30
<0.20
<0.30 <0.30 3.9 110 79 2.31 <10 3.89 0 0.0180J
0.137J
<0.2
<1
MW-3
19-Dec-18
2.8
48.8
<0.30
<0.30
<0.20
<0.30
<0.10
<0.20
<0.30 <0.10 9.5 160 89 <2 <10 3.34 0 27.OJ
0.222J
0.381
<1
MW-3
8-May-19
1.81
114.5
0.070J
0.015J
0.13J
0.027J
<0.0070
<0.048
0.0063J <0.0050 1.1 160 77 <2 <10 3.92 0.5 0.0250J
0.239J
<0.2
<1
MW-3
6-Nov-19
1.22
208.6
<0.10
<0.10
<0.50
<0.10
<0.10
<0.20
<0.10 <0.10 1.4 120 82 <2 <50 5.1 0 0.172
0.25J
<0.2
<1.0
MW-3
19-May-20
3.1
-16.5
<1.00
<1.00
<2.00
<0.18
<0.089
<0.13
<0.065 <0.021 -") 390 89.6 <2 <5 4.42 0 <0.0100
<0.5
<0.0500
<0.5
MW-3
23-Sep-20
4.8
30.8
<10
<10
3.7J
0.53
<0.058
<0.053
0.051 <0.060 0.58J 130 94 <2.0 <20 4.7 0 0.0151
<1.0
<O.10
<1.0
MW-3
17-Mar-21
3.65
-61.2
<10
<10
3.2J
--
--
--
-- -- 0.93J 330 93 <2.0 <20 4.9 0 <0.020
<1.0
<1.0
<1.0
MW-3
17-Nov-21
2.37
75.3
<2.5
<2.5
<2.5
2.3
<0.058
0.56
<0.053 <0.060 2.4 220 91 <0.18 <20 6.6 0 0.0074J
<1
<1
<1.0
MW-A
3-May-11
1.08
113
0.018
<0.010
3,600
0.085
0.12
0.13
0.063
<0.15
1.3
470
134
6
7
11
0.14J
<0.006
4.5J
<0.6
7.6
MW-A
9-Nov-11
0.06
205
0.084
0.057
9,300
<0.07
<0.05
0.22
<0.05
<0.15
1.3
610
115
2
<10
11
0.6H
<0.05
4.3J
<1
2.6
MW-A
9-May-12
0.00
103
0.11
0.027
8,000
0.16
<0.05
0.11
0.02
<0.15
3.2
560
146
6
<10
14
2.22H
<0.05
<5
<0.2
0.364
MW-A
27-Nov-12
2.66
140
0.073
0.018
9,000
<0.07
<0.05
0.043
<0.05
0.071
4
530
127
8
13.3
19
0.60
<0.05
<5
0.228J
2.52
MW-A
7-May-13
0.25
-34
0.11
0.033
7,500
0.03
<0.05
0.07
<0.05
<0.15
0.54J
470
131
5
5.15
16
0.28
<0.05
<5
<0.2
2.62
MW-A
5-Nov-13
1.89
290.8
0.051
<0.025
8,000
0.028
0.044
0.11
<0.05
<0.15
0.84
530
128
6
<10
20
0.60
<0.05
3J
<0.2
2.53
MW-A
6-May-14
0.04
-17
0.048
<0.025
11,000
0.21
0.077
0.026
0.050
<0.15
0.90
580
131
4
<10
29
2
<0.05
3.5J
0.232J
3.1
MW-A
4-Nov-14
1.70
45
0.082
0.019
10,000
0.038
<0.05
<0.1
0.048
<0.15
4.8
640
111
2
<10
32
1
<0.05
4.4J
<0.2
2.32
MW-A
5-May-15
2.34
26
0.080J
0.015
10,000
<0.07
<0.05
0.027
<0.05
<0.15
14.0
580
117
4
<10
28
1
<0.05
5.91
<0.2
3.15
MW-A
27-Oct-15
1.41
29
0.084
0.011
9,900
0.032
0.0066
0.013
0.0033
<0.10
7.2
600
123
11
<10
25
0.5
<0.05
7.4J
<0.2
4.18
1302-MSWLF-
MW-A
17-May-16
1.27
-55
0.094
<0.10
11,000
0.21
0.084
0.0075
<0.10
<0.10
1.3
540
85
6
<10
18
1.0
<0.05
131
<0.2
3.68
CDLF-1998
MW-A
1-Nov-16
1.65
205
0.087
0.015
9,500
0.040
<0.10
<0.20
<0.10
<0.10
1.8
640
129
120)
33.8
27
1.5
<0.05
191
<0.2
3.28
MW-A
9-May-17
1.31
140.9
0.084
0.0087
8,300
0.088
0.0095
0.0078
0.0090
<0.30
8.0
530
143
14
42.9
27
1.0
<0.05
17J
<0.2
3.22
MW-A
31-Oct-17
3.21
70
0.085J
0.0065J
9,300
<0.20
<0.10
<0.20
<0.10
<0.10
1.9
450
132
13
35.2
27
0.5
<0.05
24
<0.2
3.22
MW-A
7-Jun-18
0.4
635
<0.10
0.011
6,100
0.026J
<0.10
0.050J
<0.30
<0.30
73
480
136
<2
<10
24.1
1.5
0.01001
15.5
<0.2
20.5
MW-A
20-Dec-18
0.6
32.4
<0.30
<0.10
7,600
0.22
<0.10
<0.20
<0.10
<0.10
110
600
135
8.06
<10
2.39
3.5
0.01901
1.24
2.03
2.09
MW-A
9-May-19
1.91
76.7
0.038J
0.014J
5,100
1.0
<0.011
<0.043
0.019J
<0.0050
1.3
290
109
6.96
<10
26.9
3.5
0.0230J
31.5
0.652
4.38
MW-A
5-Nov-19
1.56
54.4
0.068J
0.020J
10,000
0.24
<0.011
0.052J
0.012J
<0.0050
1.3
600
135
20
<50
25.6
2.0
0.2H1
21.4
<0.2
2.9
MW-A
19-May-20
0.2
-47.8
<1.00
<1.00
2,760
<0.18
<0.089
<0.13
<0.065
<0.021
J"i
1,010
126
6.83
9.25J
22.3
3.0
<0.0100
29.2
<0.0500
2.73
MW-A
23-Sep-20
0.4
-18.4
<10
<10
10,000
0.51
<0.058
<0.053
<0.053
<0.060
0.72J
320
140
13,7
<20
21
2.5
<0.020
18
<O.10
2.2
MW-A
17-Mar-21
0.62
-184.1
<10
<10
12,000
0.72
0.059J
<0.053
<0.053
<0.060
-12"
250
96
5.6
<20
22
2.5
0.044BHJ
18
<3.0
3.7
MW-A
16-Nov-21
0.58
17.3
<13
<13
12,000H
2.9
<0.058
0.35J
<0.053
<0.060
1.7J
1,300
140
3(s'ii)
<20
20
2.0
<0.0050
11
<1
2.6
CDM
Smith Page 29 of 31 January 2022

Table Sd
Geochemical Constituents in Groundwater
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facilty Permit Number 1302-MSWLF-CDLF-1998
10
0.18
1.4
410
MW-E Rep
4-May-11
0.01
34
0.37
0.38
5,000
0.22
0.086
0.13
0.092
261
5
13
30
10.O7H
<0.006
13J
<0.6
4.2
MW-E Rep
8-Nov-11
0.00
-115
4.9
0.36
4,300
<0.07
<0.05
0.21
<0.05
<0.15
1.4
460
275
5
34
32
5.89H
<0.05
111
<1
4
MW-E Rep
8-May-12
0.00
13
4.6
0.33
2,200
0.048
<0.05
0.086
<0.05
<0.15
2.1
430
285
4
<10
30
8.22H
<0.05
8.11
<0.2
0.317
MW-E Rep
8-May-13
0.47
-81
6.6
0.5
1,600
0.048
<0.05
0.072
<0.05
<0.15
O.56J
350
405
2
16.9
52
3.3
<0.05
<5
<0.2
4.89
MW-E Rep
5-Nov-13
1.64
-39.8
4.2
0.36
1,700
0.038
0.058
0.11
<0.05
<0.15
0.81
330
320
4.09
24.6
31
2.77
<0.05
51
<0.2
4.18
MW-E Rep
6-May-14
0.07
-24
2.6
0.27
2,400
0.095
0.091
0.15
0.048
<0.15
0.97
400
285
3
<10
28
5
<0.05
8.5J
<0.2
4.08
MW-E Rep
4-Nov-14
1.62
-54
3.7
0.56
2,800
0.038
<0.05
0.051
<0.05
<0.15
1.4
430
610
3
<10
45
3.5
<0.05
111
<0.2
4.44
MW-E Rep
5-May-15
3.61
-38
3.4
0.47
1,700
<0.07
<0.05
0.036
<0.05
0.044
13
340
415
4
11
48
2.5
<0.05
111
<0.2
6.14
MW-E Rep
27-Oct-15
1.25
-36
4.1
0.73
2,300
0.038
0.0062
0.011
0.0026
<0.10
7.3
380
365
5
<10
48
2.0
<0.05
8.3J
<0.2
4.82
MW-E Rep
18-May-16
1.40
-59
3.3
0.63
680
0.21
1
<0.20
0.021
0.014
1
250
425
3
<10
55
0.5
<0.05
6J
<0.2
4.49
1302-MSWLF-
MW-E Rep
1-Nov-16
3.79
48.1
4.8
0.73
660
0.035
<0.30
0.0060
<0.30
0.012
2.3
370
475
<2
33.4
50
3.0
<0.05
78J
<0.2
5.06
CDLF-1998
MW-E Rep
9-May-17
1.35
-50.7
3.2
0.55
730
0.077
<0.10
<0.20
<0.10
0.010
2.6
340
457
2
38
65
4.5
<0.05
6.41
<0.2
4.38
MW-E Rep
31-Oct-17
2.48
65
4.0
0.58
600
0.O2OJ
<0.30
<0.20
<0.30
<0.10
3.8
280
484
<2
32
54
2.5
<0.05
6.6
<0.2
4.46
MW-E Rep
11-Jun-18
1.3
-26.2
2.1
0.44
420
0.0581
<0.10
O.026J
<0.10
<0.10
120
280
462
6
<10
56.4
4.5
<0.0050
5.87
<0.2
3.33
MW-E Rep
20-Dec-18
0.3
-16.1
2.9
0.63
830
<0.30
<0.30
<0.20
<0.30
<0.10
13
380
495
3.59
<10
49
6.0
O.O17OJ
6.81
<0.2
3.78
MW-E Rep
7-May-19
1.68
-1.9
3.0
0.60
930
0.O35J
<0.0070
<0.048
<0.0020
O.014J
1.7
420
510
<2
<10
46.6
4.25
<0.050
7.12
<0.2
3.65
MW-E Rep
5-Nov-19
0.77
26.5
2.5
0.68
460
0.O35J
<0.011
<0.043
<0.0040
<0.0050
1.1
400
489
<2
<50
54.6
2.5
O.O53OB
6.75
<0.2
4.0
MW-E Rep
21-May-20
0.5
-25.2
<1.00
<1.00
42.2
1.1
<0.089
0.26
<0.065
<0.021
-""
531
627
<2
13.3
54.2
2.5
<0.010
7.88
<0.050
4.35
MW-E Rep
23-Sep-20
0.29
-0.8
<10
<10
580
O.96J
<0.12
<0.11
<0.11
<0.12
O.76J
620
530
<2.0
<20
39
3.5
<0.020
4.4
<0.10
3.2
MW-E Rep
17-Mar-21
0.40
-119.2
<10
<10
400
2.9J
<0.58
<0.53
<0.53
<0.60
-(30)
510
460
2.8
22
34
0
O.O45BHJ
3.1
<1.0
3.9
MW-E Rep
17-Nov-21
0.34
29.2
2.7J
<2.5
210
1.9
O.41J
0.92
<0.053
<0.060
1.1J
900
540
<0.18
<20
69
3.0
<0.0050
4.3
<1
4.6
MW-E Deep
4-May-11
0.00
-51
3.3
0.14
6,900
4.3
0.13
<0.1
0.25
<0.15
2.3
100
401
7
37
27
2.7
<0.006
O.096J
<0.6
5.4
MW-E Deep
8-Nov-11
0.00
-67
30
0.29
19,000
2.2
0.021
0.076
<0.05
<0.15
2
160
345
16
33
26
2.2
O.0O7J
<5
<3
2.9
MW-E Deep
8-May-12
2.51
-76
7.5
0.11
14,000
0.84
<0.05
0.10
0.024
<0.15
3.3
160
305
24
22.6
27
4.O3H
<0.05
<5
<0.2
0.207
MW-E Deep
27-Nov-12
1.70
78
9.8
0.14
16,000
0.19
<0.05
0.034
<0.05
0.11
1.1
160
255
10
39.2
28
7H
<0.05
<5
<0.2
1.37
MW-E Deep
8-May-13
0.51
-80
13
0.13
16,000
0.25
<0.05
0.066
0.028
<0.15
0.99
140
370
5
26.4
28
3.3
<0.05
<5
<0.2
2.3
MW-E Deep
6-Nov-13
1.21
-82.2
13
0.18
15,000
0.11
<0.05
0.16
<0.05
<0.15
1.5
170
345
5.97
23.1
31
3.3
<0.05
<5
<0.2
2.51
MW-E Deep
6-May-14
0.09
-41
4.6
0.13
19,000
120
20
<1
100
4.0
1.3
480
320
1,580
2,410
20
5.5
<0.05
<5
<0.2
432
MW-E Deep
4-Nov-14
1.09
-82.3
2.8
0.056
22,000
52
2.3
0.046
5.4
0.21
6.7
310
625
208
355
30
1.5
<0.05
<5
<0.2
41.6
MW-E Deep
5-May-15
0.88
-100
9
0.059
22,000
7.1
0.092
0.019
0.12
0.042
17
220
410
47
59.2
35
1
<0.50
<5
<2
8.26
MW-E Deep
27-Oct-15
1.20
-71
8.1
<0.50
26,000
2.4
0.085
<0.20
0.026
<0.30
8.7
170
415
36
22.4
34
3.0
0.13J
<5
<0.2
4.52
1302-MSWLF-
MW-E Deep
18-May-16
3.08
-95
3.9
0.021
16,000
2.8
0.2
<0.20
0.064
0.012
2.3
130
<1
28
63.8
37
3.0
<0.05
<5
<0.2
6.34
CDLF-1998
MW-E Deep
1-Nov-16
2.30
-39
12
0.063
29,000
0.12
<0.30
<0.20
<0.30
<0.30
2.7
210
415
62.5
44
2.0
<0.5
<5
<0.2
3.16
MW-E Deep
9-May-17
1.65
-78.5
8.2
0.067
21,000
0.073
<0.10
<0.20
<0.10
0.0099
3.6
190
395
26
70.7
49
5.0
O.SJ
0.151
<0.2
3.39
MW-E Deep
1-Nov-17
2.45
152
6.8
0.0481
17,000
0.18
<0.10
<0.20
<0.10
<0.10
2.1
170
407
8
60.6
53
3.0
<0.05
O.071J
<0.2
5.22
MW-E Deep
11-Jun-18
0.4
-84
5.5
0.O47J
13,000
0.O89J
<0.10
<0.20
0.00981
<0.10
2.0
160
398
25.4
16.9
49.2
5.5
<0.0050
<0.0170
<0.2
2.37
MW-E Deep
20-Dec-18
0.4
-56.2
6.6
0.10
11,000
<0.30
<0.10
<0.20
<0.30
<0.30
7.7
320
451
7.59
303
5.62
6.0
O.O17OJ
<5
<0.2
5.34
MW-E Deep
8-May-19
1.88
-30.9
5.3
0.O76J
10,000
0.O82J
<0.0070
<0.048
<0.0020
0.0221
2.7
360
468
129
<10
66.2
6.0
O.O21OJ
0.09201
<0.2
8.1
MW-E Deep
5-Nov-19
NA
NA
8.2
0.O54J
14,000
0.O64J
<0.011
<0.043
<0.0040
0.00731
2.1
280
492
2.33""
58.7
70.2
NA
0.O13OJ,H1
0.09701
<0.2
5.4
MW-E Deep
21-May-20
0.6
-21.8
2.11
<1.00
2,960
1.4
<0.089
0.73
<0.065
<0.021
-die)
15.1
522
3.1
31.8
79.4
4.5
0.01081
<0.5
<0.050
9.37
MW-E Deep
23-Sep-20
0.27
-36.8
16
<10
12,000
2.4J
<0.29
<0.26
<0.26
<0.30
O.74J
580
480
21,7
23
78
7.0
<0.020
<5.0
<0.10
6.3
MW-E Deep
17-Mar-21
0.91
-152.1
<50
<50
6,300
3.0J
<0.58
<0.53
<0.53
<0.60
_(20)
430
440
6.9
36
65
0
O.O47BHJ
<5.0
<1.0
7.8
MW-E Deep
17-Nov-21
0.40
-33.1
5.1J
<2.5
9,600
2.1
0.131
1.2
<0.053
<0.060
1.8J
640
420
8.3'11)
<20
58
4.5
0.39
1 <1.3
I <1
4.7
CDM
Smith Page 30 of 31 January 2022

Table Sid
Geochemical Constituents in Groundwater
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facilty Permit Number 1302-MSWLF-CDLF-1998
MW-L
4-May-11
2.31
206
<0.01
0.003
0.3
0.22
0.11
0.32
0.097
<0.15
0.7
72
44
<0.5
<6
2.2
0.161
0.13J
1.81
<0.6rO.342
MW-L
9-Nov-11
2.59
222
<0.025
0.066
0.3
<0.07
0.019
0.16
<0.05
<0.15
1.4
83
30
<2
101
2.6
<O.2H
0.O96J
1.81
<1
MW-L
9-May-12
0.04
214
<0.025
0.014
0.69
0.049
<0.05
0.11
<0.05
<0.15
1.1
98
37
<0.002
<10
2.6
<O.2H
0.0961
<5
<0.2
MW-L
28-Nov-12
3.03
3
0.22
0.037
2.8
<0.07
0.033
0.066
<0.05
<0.15
O.43J
72
90
<2
<10
2.7
<O.2H
0.O52J
<5
<0.2MW-L
9-May-13
1.09
188
<0.025
0.024
0.55
0.024
<0.05
0.085
<0.05
<0.15
1.2
79
28
1.91
2.22
2.7
0
0.061
<5
<0.2MW-L
7-Nov-13
1.39
258.1
<0.025
<0.025
0.059
0.034
<0.05
0.12
<0.05
<0.15
0.78
90
35
2
<10
2.8
0.61
O.O65J
<5
<0.2
MW-L
8-May-14
2.12
379
0.0030
0.0038
0.042
0.063
<0.05
0.033
0.034
<0.15
0.79
100
34.3
<2
<10
2.8
0.5
0.0611
<5
<0.2MW-L
5-Nov-14
4.03
59.2
0.0037
0.014
0.63
0.042
<0.05
0.058
0.049
<0.15
1.3
100
31
<2
<10
3.1
0
O.O81J
2.81
<0.2
MW-L
6-May-15
4.15
131
0.005
0.016
0.055
<0.07
<0.05
0.014
<0.05
<0.15
26
100
31
<2
11
2.7
0
<0.5
1.91
<0.2
<1
MW-L
28-Oct-15
3.80
89
0.0058
0.019
0.077
0.029
0.0081
<0.20
0.0022
<0.10
8.9
94
39
<2
<10
3
0
O.O54J
1.5J
<0.2
<1
1302-MSWLF-
MW-L
19-May-16
3.66
192
<0.30
<0.30
0.031
0.012
<0.30
0.0063
<0.30
<0.30
0.63
98
35
<2
30
2.8
0
<0.05
1.4J
<0.2
<10
CDLF-1998
MW-L
2-Nov-16
3.49
486
0.028
0.013
0.8
0.029
0.0079
0.0062
<0.10
<0.10
1.7
87
40
<2
12.9
3.2
0
O.O85J
<5
<0.2
<1
MW-L
30-May-17
1.40
128.9
0.046
0.011
0.24
0.021
<0.30
0.030
<0.30
<0.30
2.3
89
41
<2
<10
3
0
<0.05
0.951
<0.2
<1
MW-L
1-Nov-17
1.61
361
0.00981
0.O16J
0.25J
0.O23J
<0.10
<0.20
<0.10
<0.10
2.3
89
45
<2
<10
3.2
0
0.085
1.81
<0.2
<1
MW-L
7-Jun-18
1.2
141.2
0.0111
0.O17J
0.23J
0.O44J
<0.30
<0.20
<0.30
<0.30
13
94
34
<2
<10
2.94
0
0.0840
O.984J
<0.2
<1
MW-L
19-Dec-18
2.7
100.4
<0.10
<0.10
0.93
<0.10
<0.10
<0.20
<0.10
<0.10
13
95
41
<2
<10
2.95
0
0.0770
O.988J
<0.2
<1
MW-L
8-May-19
1.87
142.9
<0.0050
<0.0040
O.057J
0.O44J
<0.0070
<0.048
<0.0020
<0.0050
1.6
77
36
<2
<10
2.68
0
0.0840
1.48J
<0.2
<1
MW-L
7-Nov-19
1.54
240.6
<0.10
<0.10
<0.50
<0.10
<0.10
<0.20
<0.10
<0.10
1.2
79
40
<2
<50
3.3
0
O.2681-11
2.15J
<0.2
4.2
MW-L
21-May-20
2.0
-15.8
<1.00
<1.00
<2.00
<0.18
<0.089
<0.13
<0.065
<0.021
-Its)
164
40.6
<2
<5
2.5
0
0.0595
1
<0.050
1.12
MW-L
23-Sep-20
2.79
50.4
<10
<10
5.81
O.5OJ
<0.058
<0.053
<0.053
<0.060
O.8OJ
82
58
<2.0
<20
2.6
0
O.O16J
0.76J
<0.050
<3.0
MW-L
17-Mar-21
2.62
-91.2
<10
<10
<10
--
--
--
--
--
1.4J
150
42
<2.0
<20
2.5
0
O.O6OB
0.951
<1.0
<1.0
MW-L
17-Nov-21
3.1-1
71.4
<2.5
<2.5
3.01
2.2
<0.058
0.94
<0.053
1 <0.060
2.5
27
43
<0.18 1
<20
1 2.9
1 0
0.066
1 1
1 <1
<3.0
Notes:
1. Blank cells indicate parameter was below the detection limit.
2. (--) - Not Analyzed
3. Assessment wells AMW-1s, -1d, 2s, and 2d were installed in October 2009.
4. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit.
5. Is1 _ BOD-1,1 Flag - Indicates the dilutions selected for the BOD analysis based on screening COD values did not meet the oxygen depletion criteria of at least 2 mg/L dissolved oxygen depletion.
The result is reported as an estimated value or non -detect at the elevated reporting limit.
6. H, H-02, H3 - Sample was analyzed outside the U.S. Environmental Protection Agency recommended holding time.
7. B - Indicates constituent was detected in the method blank.
8. Iel- BOD-3 Flag- Lab control recovery was outside control limits biased low. Samples could not be reanalyzed due to holding time requirements. Sample values are reported as estimated values with possible low bias.
9. Isl - BOD-4 Flag - Lab control recovery was outside control limits biased high. Samples are reported as estimated with possible high bias.
10. I10)- R6 Flag - The relative percent difference between valid sample dilutions exceeded 30 percent.
11. I")-7 Flag - The seed correction factor was above the method range.
12. mg/I - milligrams per liter/µg/I - micrograms per liter/mVolts - millivolts/N m - nanomoles
13. H I BA - Hydroxyisobutyric Acid
14. Alkalinity, chloride, ferrous iron, sulfate, and total dissolved solids were added to the sampling program in May 2010 for CD-1s and CD-1d.
15. The November 2012 sampling event was the first event that CD-is/CD-ld replaced M W-9 as the background monitoring wells.
16. MW-9 was removed from the monitoring program in November 2012.
17. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight.
18. NA - Not available. The field sheet for MW-E deep was lost by field personnel during the November 2019 sampling event.
19. Its) - Samples were not analyzed for dissolved hydrogen during the May 2020 sampling event due to laboratory error.
20. (20) - Samples were not analyzed for dissolved hydrogen during the March 2021 sampling event due to equipment malfuction.
CDM
Smith Page 31 of 31 January 2022

Table 6
Constituents Detected Above Standards
November 2021 Semi -Annual Sampling Event
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
STANDARDFACILITY PERMIT MONITORING PARAMETERS EXCEEDING NORTH CAROLINA 2L OR IMAC .. .
NUMBER WELL ASSESSMENT MONITORING - NOVEMBER 2021 WELL ASSESSMENT MONITORING - NOVEMBER 2021
1302-MSWLF-
MW-9 Not Sampled MW-D Cobalt*, Benzene, Vinyl Chloride
CDLF-1998
1302-MSWLF-
CD-1s
Cobalt*, 1,4-Dichlorobenzene, 1,2-Dichloroethane,
Vanadium*
MW-E Rep
CDLF-1998
(background well)
1,2-Dichloropropane, 1,4-Dioxane, Vinyl Chloride
1302-MSWLF-
CD-1d
Antimony*, Barium, Cobalt, Lead, 1,4-Dichlorobenzene,
Antimony*, Vanadium*
MW-E deep
CDLF-1998
(background well)
1,2-Dichloropropane, 1,4-Dioxane, Vinyl Chloride
1302-MSWLF
CD-4 Rep
Cobalt*, Vanadium*
MW-F
Cobalt*, 1,4-Dioxane
CDLF-1998
1302-MSWLF
AMW-ls
Antimony*, Vanadium*
MW-G
Cobalt*, 1,4-Dioxane, Vinyl Chloride
CDLF-1998
1302-MSWLF-
AMW-1d
Antimony*, Cobalt*, Benzene, 1,1-Dichloroethane, Vinyl Chloride
MW-H
None Detected
CDLF-1998
1302-MSWLF-
AMW-2s
Tetrachloroethene
MW-H deep
None Detected
CDLF-1998
1302-MSWLF-
AMW-2d
Benzene, 1,1-Dichloroethane, Tetrachloroethene, Trichloroethene
MW-1
Vanadium*, Tetrachloroethene
CDLF-1998
1302-MSWLF-
MW-1
Cobalt*, 1,4-Dioxane
MWA
None Detected
CDLF-1998
1302-MSWLF-
MW-3
1,1-Dichloroethane, Tetrachloroethene, Trichloroethene
MW-K
Vanadium*
CDLF-1998
1302-MSWLF-
MW-3 deep
Not Sampled
MW-L
Vanadium*
CDLF-1998
Cobalt*, Benzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane,
1302-MSW LF-
MW-A
1,2-Dichloroethane, cis-1,2-Dichloroethene, 1,2-Dichloropropane,
MW-L deep
Not Sampled
CDLF-1998
Tetrachloroethene, Trichloroethene, Vinyl Chloride
1302-MSWLF-
MW-B
Cobalt*, 1,4-Dioxane
MW-M
Not Sampled
CDLF-1998
1302-MSWLF-
MW-C
Cobalt*, Vinyl Chloride
MW-X
Antimony*
CDLF-1998
Notes:
1. Monitoring wells MW-3 deep, -L deep, -and -M are sampled annually during the spring event.
2. * - Constituents exceed the Interim Maximum Allowable Concentration (IMAC)
3. Bold - J Flag - Indicates the analytical result is an estimated concentration between the method detection limit and the method reporting limit.
4. The November 2012 sampling event was the first event that CD-1s and -1d replaced MW-9 as the background monitoring wells. MW-9 was removed from the monitoring program in November 2012.
Smith Page 1 of 1 January 2022

Table 7
DHC Sampling Summary
Cabarrus County Landfill Units 2 and 3
Facility Permit Number 1302-MSWLF-CDLF-1998
MW-E Rep 9-Jan-14 1,958 + 1.37E+06 + 1.81E+05 9.48E+05 + 8.02E+04 0.00E+00 + 0.00E+00 5.46E+02 + 1.02E+02
MW-E Rep 4-Mar-15 328 + 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00
MW-E deep
9-Jan-14
3,524
+
1.38E+07 + 2.23E+06
7.85E+05 + 1.10E+05
0.00E+00 + 0.00E+00
2.84E+06 + 4.53E+05
M W-E deep
4-Mar-15
6,848
+
5.20E+03 ± 6.72E+02
9.00E+03 ± 8.24E+01
0.00E+00 ± 0.00E+00
7.06E+02 ± 1.28E02
AMW-1s
9-Jan-14
8,214
+
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
AMW-1s
4-Mar-15
538
+
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
AMW-1d
9-Jan-14
2,648
+
3.53E+03 + 3.17E+03
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
AMW-1d
4-Mar-15
1,716
+
1.03E+06 ± 1.12E+05
6.18E06 ± 2.89+05
0.00E+00 ± 0.00E+00
3.13E+04 ± 2.79+03
AMW-2s
9-Jan-14
1,917
+
3.09E+05 + 5.12E+04
1.24E+06 + 2.26E+05
9.61E+04 + 1.86E+04
5.66E+04 + 1.12E+04
AMW-2s
4-Mar-15
1,564
+
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
AMW-2d
9-Jan-14
1,320
+
8.81E+03 + 3.15E+02
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
0.00E+00 + 0.00E+00
AMW-2d
4-Mar-15
108
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
0.00E+00 ± 0.00E+00
Notes:
1. PCR - Polymearse chain reaction
2. DHC - Dehalococcoides spp
3. * - A "+" inidicates that amplication of bacteria was successful. "-" indicates that ampification was not successful.
4. ng/L - Nanogram per liter
5. copy/L - Copy per liter
Indicates the result is between the laboratory method detection limit and the reporting limit.
Smt� Page 1 of 1 January 2022

H
.s
w + E
MGW-15
i
MGW-1 /f
o CD-1s .
733.80 MGW-14 -
SW-3 \� ,CD -id
733.60
20\ C&D I .!•Y
�� }•
�J 721.17 Landfill CD-4 Rep
729.58
I.
707.0.�'
CD-9
MI:G.•
�W -1.
3
CD
°F''"Unit2705.4aMW-17\J10 MGW-12 Unit
MW-J MW-1 MW 8A
698.45 688.90W 10 708.09
�690.68 %
mw'MGW-11
MGW-16 693.86
-5-A MW-G MW
06 685.41 680.62
MW Unit 3 , 678.99/ MW-11 e0 " Borrow Area
99.69 MGW-3 — IMW-E Rep
690�� MW-D 1 \685.46; SW-1 675.78 MGW-10
\ 696.95 MW-E deep /
675.19 .y _
67
0
684.23 681..31\ // / 6711..51 MGW-8 MGW-9
680 AMW-1d 664.47 —660
MGW-4 676.32 /
MW-H AMW-1s SW-2
675.79 '673.95 MGW-7
MW-H deep 675.40 AMW-2s 650
MW-3
673.20
670 655.67
AMW-2d MW-M
676.56 6y0 MW-L 0 647.99
656.2465 MW-3 deep MGW-6
MW-L deep 658.27
658.13
MGW-5
Scale in Feet
0 S00 1000
Map Data Source: 2019 Aerial Photograph, Cabarrus County, North Carolina one Map.
NxHgkllvl
Groundwater Monitoring Well
Surface Water Sample Location
♦ Landfill Gas Well Location
Potentiometric Contour
680 — (dashed where inferred)
Contour Interval = 10 Feet

Legend
Regoldh Monitoring Well
Bedrock Monitoring Well
Injection Well
Notes
1. The Injection weft w stalled using ai -rmary citing
mothers an October 59in, 2009.
2. The injection wells are spaced approximately 30 feet aped
perpendicular to groundwater flow and have a radius of
Influence of approximately 15 feet.
3. The surface area of the injection well netwed Is
approximately SA00 real,
0. The Phase I injection event was completed on November
2-6, 2009.
5. The Phase II Njection event was compound an February
10-1 B, 2014.
Nap Nato Suume: Febwary M15 Aerial Photograph, Cabanas County, North Carolina Onehfap.
Figure 2: Injection Area Overview
Scale (feet) Closed Landfill Units 2 and 3
cp Cabarrus County, North Carolina
Smith 0 100 200

Figure 3
450
EM
350
300
aA
V
u 250
O
ai 200
U
G1
GJ
0 150
H
100
50
0
CDM
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
M W-A
-zT LnLn��.Dr-r-,WwMM00C*,J M n�-zT LnLn�.ok.0r-r-,WWMM00�ic-4cjmm���n�nQok r-r- oW MM00��
Q1Q1Q�QlQ1Q1Ql61 01 00000000000000000000 rIrrI rI rI rI fV(VfVcV
O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O
Date
Note: Only detections above laboratory method detection limits are represented in the figure. Figure 3 (MW-A)

70
50
10
0
Figure 4
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
MW-3
00 m M m 0 0 rl r-i N N M m;t t u1 L 1 w w r� r� 00 oo m m O 0 r-I r i N N m m;t L n L) w w ^r� 00 00 m m O O r i r-I
Q1MQlM00000000000000000000r-Irlr-irINN NN
O O M O M O M O O M O M O M O O M O M O M O O M O M O M O M O M O M O M O M O M O M O
�zz:Ez2z:Ezz2iz2z:Ezz2z:Ez:Ezz 2 z :E z 2 z :E z :2 z :E z 2i z 2 z 2 z :2 z
Date
Note: Only detections above laboratory method detection limits are represented in the figure. Figure 4 (MW-3)

Figure 5
200
160
140
3 120
V
0100
80
a�
1� 60
H
.W
ME
0
CDM
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
MW-E Rep
�LnLn�Dk.0r-r oW w M M 0 0 1rJrjcnm�-zt LnLn�Dk.or-r-,WWMM001r,4c imm�-zT LnLnI-o�.Dr-r oW W MM00�I �i
6141p1a1�61Q�Q1�61Q�00000pO0000000000000 �.���.� ��� �.��.� ��� �NNNN
O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O m O
Date
Note: Only detections above laboratory method detection limits are represented in the figure. Figure 5 (MW-E Rep)

Figure 6
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
MW-E deep
.e]
Phase I Emulsified Oil Injection —
November 2009
160
140
120
100
O
1W
Phase II Injection —
February 2014
--O—Tota I VOC
--*--PCE
0 TCE
0 DCE
VC
H Q
40
vsio 0 QQQQ
20 � 4 ❑ — -
5�
Q LA Q
mOo- -jNNmmzt -tt LnLn,o�.or-r,wxmmoo NNmm mLn,otor- r�xwmmoo
Ql O O O O O O O O O O O O O O O O O O O O
O O O O O O O O O O O O O O O O O O O O O O O
2iz�z�z�z�z�z�z�z�z�z�z�z
Date
CDM
SmithNote: Only detections above laboratory method detection limits are represented in the figure. Figure 6 (MW-E deep)

Figure 7
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
AMW-1s
70
Phase I Emulsified Oil Injection — Phase II Injection —
November 2009 :February 2014
M
50
O 20
12
10
a
rn o o N m M IZT Ln 00 00 rn o o
o ry 1-I -I r- rl r - r-I c-I I r- r- r�
Q 2i O o Li Ln Q z Q p o Li cn Q Z
Date
CDM
SmithNote: Only detections above laboratory method detection limits are represented in the figure. Figure 7 (AMW-1s)

Figure 8
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
AMW-1d
120
Phase I Emulsified Oil Injection — Phase II Injection —
November 2009 February 2014
100
tw 80
u
O
CU 60
4-0
U
a)
N
f�
C 40
H
20
rn o o r-1 r-1 N m cn T IZT Ln 00 00 rn o o
o r I -I -I r-I ry 1-I -I r- 1 l r- r-I c-I I r- r-
Q 2i O o U- Ln Q z Q p o U- cn Q Z
Date
CD
SmithNote: Only detections above laboratory method detection limits are represented in the figure. Figure 8 (AMW-1d)

35
30
25
tw
v 20
u
O
a,
�15
a�
a�
G
010
H
5
rilim
Figure 9
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
AMW-2s
Phase I Emulsified Oil Injection —
November 2009
R
Phase II Injection —
February 2014
rn o o rH N m rn T Ln 00 00 o o
o -i4 �
p N N N
U0 U U za o � V) a a o o LL V) a zi
Date
CIDM
SmithNote: Only detections above laboratory method detection limits are represented in the figure. Figure 9 (AMW-2s)

70
.E
ttw 50
U
0
> 40
a�
U
a 30
0
M
4-0
~ 20
10
0 '
o
O
rH
a
O
�
Figure 10
Total Detected Volatile Organic Compounds
Cabarrus County Landfill Units 2 and 3
AMW-2d
c-I N M M Izt T* Ln l0
I I I I I I I I
U Q L > C C
a) cn Q O co
z
Date
00
00
M
O
Note: Only detections above laboratory method detection limits are represented in the figure
O rH r-I
N
I I I
N O
N Q z
Figure 10 (AMW-2d)

N
w+ E
S
CD-1s CD-1d�."A
ND NDI
C&D
Landfill
L'CD-4R'ep
2.10
000(
10
' - 50
---100
1,
MND Unit 2 100 101
MW-1
63.45
146.64
MW-A 130 93 1 `
MW-X � � � • ____ `
NO
i — — _ MW-B `
19.00
Unit 3 Sw-1
MW C
22.37 MW-F
102 Injection Area 29.00
- - - _ � MW-E Rep i
� 36.51 �
MND MW-E deep ,
ND 31 35
MW-H AMW-17APMW-1
MW-I
ND ND
5.17
MW-H deep
d
ND
25.40 ;
Source: 2019 Aerial Photograph, Cabarrus County, North Carolina OneMap.
Urfit 1
SW-2
MW-3
38.82
MW-3 deep
NS
MW-M
NS
try,
f
Borrow Area
LEGEND
Groundwater Monitoring Well
Surface Water Sample Location
Total Volatile Organic
10 _ Compound Concentration Contour
(values in pg/L)
(dashed where inferred)

Appendix A

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: Cabarrus County 2021-2022
Project Number: Unit 2
Lot Number:WK17018
Date Completed:12/14/2021
12/30/2021 10:41 PM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�4 aecRFo���A16
TNI /
AM Amflvue Acm^rmm Fvu rj
('
4eOfFAi�
ACC R E OI TEO
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 152

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: WK17018
Report Revision 12/3012021:
Per client request, this report has been revised to combine the 2 analytical runs for VOA samples
WK17018-010 (MW-E REP) and WK17018-011 (MW-E deep). Only Chloroethane has been reported from
Run 2. All other sample results are as reported in the original PDF report. This report supersedes and
replaces any prior reports issued under this lot number.
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this
Case Narrative. The sample receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current
approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality
Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the
Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of
accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon,
Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal Coliform SM 9221 C
E-2006 & SM 9222D-2006, Strontium SW-846 601 OD, VOC SM 6200 B-2011, Drinking Water: VOC (excluding BTEX,
MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid Chemical Material: TOC Walkley-Black.
VOA 8260D
Due to the large number of spiked analytes, there is a high probability that one or more analytes will recover outside
acceptance limits. The laboratory's SOP allows for 10% of analytes to recover marginally outside criteria. The
following analytes recovered marginally outside LCS/LCSD criteria: trans- 1,4-dichloro-2-butene @ 63%. Associated
samples: WK17018-010 (MW-E REP), WK17018-011 (MW-E deep) and WK17018-012 (AMW-1s)
The laboratory control sample (LCS) for analytical batch 23641 exceeded acceptance criteria for the following
analytes: acetone. These analytes were biased high and were not detected in the associated samples: WK17018-
010 (MW-E REP), WK17018-011 (MW-E deep), and WK17018-012 (AMW-1s).
The laboratory control sample (LCS) for analytical batch 23569 exceeded acceptance criteria for the following
analytes: ,2-Butanone and 2-Hexanone. These analytes were biased high and were not detected in the samples
affected: WK17018-015 (MW-H) , WK17018-016 (MW-L), WK17018-017 (MW-3), and WK17018-019 (TRIP BLANK).
Trans 1, 4-Dichloro-2-butene failed readback associated with the calibration (ICAL) of the instrument used in this
sequence. The compound passes using linear fit but the readback fails extremely high at 343% drift. Since the
compound is detected in the LOQ associated with this sequence and samples are non -detect, the data has been
reported for the following samples: WK17018-015 (MW-H) , WK17018-016 (MW-L), WK17018-017 (MW-3), and
WK17018-019 (TRIP BLANK).
Reanalysis of the following samples was performed outside of the analytical holding time for Chloroethane due to
high failure in the CCV: WK17018-010 (MW-E REP) and WK17018-011 (MW-E deep).
1,4-dioxane SIM 8260D
The following samples were analyzed using unpreserved sample vials due to analyst error: WK17018-014 (AMW-2s),
WK17018-016 (MW-L), and WK17018-017 (MW-3). The unpreserved vials were analyzed within hold time, therefore
data will be reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 2 of 152

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Sample WK17018-004 (MW-A) required a dilution which was performed outside of the analytical holding time. Both
analytical runs have been reported.
Nitrate-N 9056A
The following samples were diluted due to the nature of the sample matrix: WK17018-004 (MW-A), WK17018-005
(AMW-2d), and WK17018-010 (MW-E REP). The LOQ has been elevated to reflect the dilution. The reanalysis for
samples WK17018-004 (MW-A) and WK17018-010 (MW-E REP) was performed outside of the analytical holding
time. These samples were reanalyzed outside holding due to matrix interference during initial analysis. Both sets of
data have been reported.
The MS/MSD for batch 22958 and parent sample WK17018-004 (MW-A), recovered outside the lower control limit.
The associated LCS passed acceptance criteria.
COD
The MSD for batch 23842 and parent sample WK17018-005 (AMW-2d), recovered marginally outside the lower
control limit. The associated LCS and MS passed acceptance criteria.
BOD
The seed correction factor for samples WK17018-004 (MW-A) and WK17018-005 (AMW-2d) was above the method
range of 0.6 to 1.0. SCF = 1.1
The seed correction factor for the samples listed below was above the method range of 0.6 to 1.0. SCF = 1.6
WK17018-010 (MW-E REP)
WK17018-011 (MW-E deep)
WK17018-012 (AMW-1s)
WK17018-013 (AMW-1d)
WK17018-014 (AMW-2s)
WK17018-016 (MW-L)
WK17018-017 (MW-3)
The results of the three GGA check samples associated with the batch are as follows: 157.6 mg/L, 168.6 mg/L, and
173.6 mg/L. The resulting average BOD for the three bottles, after correcting for dilution and seed is 166.6 mg/L
which is lower than the method required range of 198±30.5 mg/L. The data for the associated samples (WK17018-
004 (MW-A) and WK17018-005 (AMW-2d)) has been flagged accordingly.
Alkalinity
Analytical batch 23834 does not have duplicate reported. A duplicate was analyzed during the analysis; however,
due to instrument error, a majority of the samples did not have reportable data. The sample (WK17018-005 (AMW-
2d) that was analyzed in duplicate was one of the samples affected. Results have been uploaded for the reportable
samples in the batch.
If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 3 of 152

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: WK17018
Project Name: Cabarrus County 2021-2022
Project Number: Unit 2
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-H deep
Aqueous
11/15/2021 1400
11/17/2021
002
DUP
Aqueous
11/15/20210800
11/17/2021
003
MW-1
Aqueous
11/15/20211440
11/17/2021
004
MW-A
Aqueous
11/16/20210945
11/17/2021
005
AMW-2d
Aqueous
11/16/20211150
11/17/2021
006
MW-E deep
Aqueous
11/16/2021 1300
11/17/2021
007
AMW-1 deep
Aqueous
11/16/2021 1415
11/17/2021
008
AMW-1s
Aqueous
11/16/20211450
11/17/2021
009
TRIP BLANK
Aqueous
11/16/2021
11/17/2021
010
MW-E REP
Aqueous
11/17/2021 0900
11/18/2021
011
MW-E deep
Aqueous
11/17/2021 0945
11/18/2021
012
AMW-1s
Aqueous
11/17/20211020
11/18/2021
013
AMW-1d
Aqueous
11/17/20211040
11/18/2021
014
AMW-2s
Aqueous
11/17/20211130
11/18/2021
015
MW-H
Aqueous
11/17/20211200
11/18/2021
016
MW-L
Aqueous
11/17/20211245
11/18/2021
017
MW-3
Aqueous
11/17/20211330
11/18/2021
018
CD-4 REP
Aqueous
11/17/2021 1510
019
TRIP BLANK
Aqueous
11/17/2021
11/18/2021
020
AMW-2s
Aqueous
11/17/20211120
11/18/2021
(20 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 152

PACE ANALYTICAL SERVICES, LLC
Detection Summary
CDM Smith
Lot Number: WK17018
Project Name: Cabarrus County 2021-2022
Project Number: Unit 2
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
001
MW-H deep
Aqueous
Barium
6020B
42
ug/L
11
001
MW-H deep
Aqueous
Nickel
6020B
1.4
J
ug/L
11
002
DUP
Aqueous
Barium
6020B
44
ug/L
14
003
MW-1
Aqueous
1,1-Dichloroethane
8260D
2.1
ug/L
15
003
MW-1
Aqueous
cis- 1,2-Dichloroethene
8260D
1.1
ug/L
15
003
MW-1
Aqueous
Tetrachloroethene
8260D
1.3
ug/L
15
003
MW-1
Aqueous
Trichloroethene
8260D
0.67
ug/L
15
003
MW-1
Aqueous
Barium
6020B
26
ug/L
17
003
MW-1
Aqueous
Beryllium
6020B
0.20
J
ug/L
17
003
MW-1
Aqueous
Chromium
6020B
2.2
J
ug/L
17
003
MW-1
Aqueous
Lead
6020B
0.50
J
ug/L
17
003
MW-1
Aqueous
Nickel
6020B
1.7
J
ug/L
17
003
MW-1
Aqueous
Vanadium
6020B
4.4
J
ug/L
17
004
MW-A
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
140
mg CaCO3/L
18
004
MW-A
Aqueous
BOD, 5 day
SM 5210B-
3.0
17
mg/L
18
004
MW-A
Aqueous
Chloride
9056A
20
mg/L
18
004
MW-A
Aqueous
CO2 (calculation)
SM 4500-CO2
1300
mg/L
18
004
MW-A
Aqueous
Sulfate
9056A
11
mg/L
18
004
MW-A
Aqueous
Benzene
8260D
7.0
ug/L
19
004
MW-A
Aqueous
Chlorobenzene
8260D
1.0
ug/L
19
004
MW-A
Aqueous
Chloroethane
8260D
4.0
ug/L
19
004
MW-A
Aqueous
1,4-Dichlorobenzene
8260D
22
ug/L
19
004
MW-A
Aqueous
1,1-Dichloroethane
8260D
11
ug/L
19
004
MW-A
Aqueous
1,2-Dichloroethane
8260D
0.40
J
ug/L
19
004
MW-A
Aqueous
cis- 1,2-Dichloroethene
8260D
89
ug/L
19
004
MW-A
Aqueous
trans- 1,2-Dichloroethene
8260D
0.49
J
ug/L
19
004
MW-A
Aqueous
1,2-Dichloropropane
8260D
1.7
ug/L
19
004
MW-A
Aqueous
Methylene chloride
8260D
0.65
ug/L
19
004
MW-A
Aqueous
Tetrachloroethene
8260D
2.7
ug/L
19
004
MW-A
Aqueous
Trichloroethene
8260D
3.9
ug/L
19
004
MW-A
Aqueous
Vinyl chloride
8260D
2.4
ug/L
20
004
MW-A
Aqueous
Xylenes (total)
8260D
0.40
J
ug/L
20
004
MW-A
Aqueous
Methane
RSK - 175
12000
HD
ug/L
22
004
MW-A
Aqueous
Barium
6020B
46
ug/L
23
004
MW-A
Aqueous
Beryllium
6020B
0.22
J
ug/L
23
004
MW-A
Aqueous
Cobalt
6020B
15
ug/L
23
004
MW-A
Aqueous
Nickel
6020B
18
ug/L
23
005
AMW-2d
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
130
mg CaCO3/L
24
005
AMW-2d
Aqueous
Chloride
9056A
3.4
mg/L
24
005
AMW-2d
Aqueous
CO2 (calculation)
SM 4500-CO2
420
mg/L
24
005
AMW-2d
Aqueous
Sulfate
9056A
0.37
J
mg/L
24
005
AMW-2d
Aqueous
Benzene
8260D
1.2
ug/L
25
005
AMW-2d
Aqueous
Chloroethane
8260D
0.44
J
ug/L
25
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Page 5 of 152

Detection Summary (Continued)
Lot Number: WK17018
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
005
AMW-2d
Aqueous
1,4-Dichlorobenzene
8260D
1.4
ug/L
25
005
AMW-2d
Aqueous
1,1-Dichloroethane
8260D
21
ug/L
25
005
AMW-2d
Aqueous
1,1-Dichloroethene
8260D
1.4
ug/L
25
005
AMW-2d
Aqueous
cis- 1,2-Dichloroethene
8260D
21
ug/L
25
005
AMW-2d
Aqueous
Methylene chloride
8260D
0.46
J
ug/L
25
005
AMW-2d
Aqueous
Tetrachloroethene
8260D
2.9
ug/L
25
005
AMW-2d
Aqueous
Trichloroethene
8260D
6.3
ug/L
25
005
AMW-2d
Aqueous
Xylenes (total)
8260D
0.50
J
ug/L
26
005
AMW-2d
Aqueous
Methane
RSK - 175
410
ug/L
27
005
AMW-2d
Aqueous
Barium
6020B
67
ug/L
28
005
AMW-2d
Aqueous
Beryllium
6020B
0.18
J
ug/L
28
005
AMW-2d
Aqueous
Nickel
6020B
1.9
J
ug/L
28
005
AMW-2d
Aqueous
Zinc
6020B
8.7
J
ug/L
28
010
MW-E REP
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
540
mg CaCO3/1-
31
010
MW-E REP
Aqueous
Chloride
9056A
69
mg/L
31
010
MW-E REP
Aqueous
CO2 (calculation)
SM 4500-CO2
900
mg/L
31
010
MW-E REP
Aqueous
Sulfate
9056A
4.3
mg/L
31
010
MW-E REP
Aqueous
Benzene
8260D
0.46
J
ug/L
32
010
MW-E REP
Aqueous
Chlorobenzene
8260D
2.4
ug/L
32
010
MW-E REP
Aqueous
Chloroethane
8260D
4.7
H
ug/L
32
010
MW-E REP
Aqueous
1,4-Dichlorobenzene
8260D
8.2
ug/L
32
010
MW-E REP
Aqueous
1,1-Dichloroethane
8260D
1.3
ug/L
32
010
MW-E REP
Aqueous
1,2-Dichloroethane
8260D
0.80
ug/L
32
010
MW-E REP
Aqueous
cis- 1,2-Dichloroethene
8260D
11
ug/L
32
010
MW-E REP
Aqueous
trans- 1,2-Dichloroethene
8260D
0.43
J
ug/L
32
010
MW-E REP
Aqueous
1,2-Dichloropropane
8260D
0.72
ug/L
32
010
MW-E REP
Aqueous
Vinyl chloride
8260D
2.7
ug/L
33
010
MW-E REP
Aqueous
1,4-Dioxane
8260D (SIM)
3.8
ug/L
34
010
MW-E REP
Aqueous
Ethane
RSK - 175
2.7
J
ug/L
35
010
MW-E REP
Aqueous
Methane
RSK - 175
210
ug/L
35
010
MW-E REP
Aqueous
Barium
6020B
340
D
ug/L
36
010
MW-E REP
Aqueous
Beryllium
6020B
0.24
J
ug/L
36
010
MW-E REP
Aqueous
Cobalt
6020B
5.5
ug/L
36
010
MW-E REP
Aqueous
Lead
6020B
0.43
J
ug/L
36
010
MW-E REP
Aqueous
Nickel
6020B
13
ug/L
36
010
MW-E REP
Aqueous
Zinc
6020B
3.8
J
ug/L
36
011
MW-E deep
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
420
mg CaCO3/1-
37
011
MW-E deep
Aqueous
BOD, 5 day
SM 521013-
8.3
7
mg/L
37
011
MW-E deep
Aqueous
Chloride
9056A
58
D
mg/L
37
011
MW-E deep
Aqueous
CO2 (calculation)
SM 4500-CO2
640
mg/L
37
011
MW-E deep
Aqueous
Nitrate - N
9056A
0.39
D
mg/L
37
011
MW-E deep
Aqueous
Benzene
8260D
0.74
ug/L
38
011
MW-E deep
Aqueous
Chlorobenzene
8260D
1.4
ug/L
38
011
MW-E deep
Aqueous
Chloroethane
8260D
11
H
ug/L
38
011
MW-E deep
Aqueous
1,4-Dichlorobenzene
8260D
7.6
ug/L
38
011
MW-E deep
Aqueous
1,1-Dichloroethane
8260D
0.74
ug/L
38
011
MW-E deep
Aqueous
1,2-Dichloroethane
8260D
0.91
ug/L
38
011
MW-E deep
Aqueous
cis- 1,2-Dichloroethene
8260D
0.99
ug/L
38
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Page 6 of 152

Detection Summary (Continued)
Lot Number: WK17018
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
011
MW-E deep
Aqueous
1,2-Dichloropropane
8260D
0.77
ug/L
38
011
MW-E deep
Aqueous
Vinyl chloride
8260D
0.61
ug/L
39
011
MW-E deep
Aqueous
Xylenes (total)
8260D
0.50
J
ug/L
39
011
MW-E deep
Aqueous
1,4-Dioxane
8260D (SIM)
7.0
ug/L
40
011
MW-E deep
Aqueous
Ethane
RSK - 175
5.1
J
ug/L
41
011
MW-E deep
Aqueous
Methane
RSK - 175
9600
D
ug/L
41
011
MW-E deep
Aqueous
Antimony
6020B
1.7
J
ug/L
42
011
MW-E deep
Aqueous
Arsenic
6020B
2.5
ug/L
42
011
MW-E deep
Aqueous
Barium
6020B
2300
D
ug/L
42
011
MW-E deep
Aqueous
Beryllium
6020B
0.21
J
ug/L
42
011
MW-E deep
Aqueous
Cadmium
6020B
0.16
J
ug/L
42
011
MW-E deep
Aqueous
Cobalt
6020B
34
ug/L
42
011
MW-E deep
Aqueous
Copper
6020B
2.3
J
ug/L
42
011
MW-E deep
Aqueous
Lead
6020B
18
ug/L
42
011
MW-E deep
Aqueous
Nickel
6020B
18
ug/L
42
011
MW-E deep
Aqueous
Zinc
6020B
8.5
J
ug/L
42
012
AMW-1s
Aqueous
Alkalinity @ pH 4.5 su
SM 232013-
50
mg CaCO3/-
43
012
AMW-1s
Aqueous
BOD, 5 day
SM 5210B-
4.5
7
mg/L
43
012
AMW-1s
Aqueous
Chloride
9056A
2.5
mg/L
43
012
AMW-1s
Aqueous
CO2 (calculation)
SM 4500-CO2
170
mg/L
43
012
AMW-1s
Aqueous
Nitrate - N
9056A
0.23
mg/L
43
012
AMW-1s
Aqueous
Sulfate
9056A
0.39
J
mg/L
43
012
AMW-1s
Aqueous
Methane
RSK - 175
7.3
J
ug/L
47
012
AMW-1s
Aqueous
Antimony
6020B
2.0
ug/L
48
012
AMW-1s
Aqueous
Barium
6020B
34
ug/L
48
012
AMW-1s
Aqueous
Beryllium
6020B
0.41
ug/L
48
012
AMW-1s
Aqueous
Chromium
6020B
1.4
J
ug/L
48
012
AMW-1s
Aqueous
Copper
6020B
1.5
J
ug/L
48
012
AMW-1s
Aqueous
Lead
6020B
0.37
J
ug/L
48
012
AMW-1s
Aqueous
Nickel
6020B
1.4
J
ug/L
48
012
AMW-1s
Aqueous
Vanadium
6020B
3.2
J
ug/L
48
012
AMW-1s
Aqueous
Zinc
6020B
9.6
J
ug/L
48
013
AMW-1d
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
190
mg CaCO3/L
49
013
AMW-1d
Aqueous
BOD, 5 day
SM 521013-
3.7
7
mg/L
49
013
AMW-1d
Aqueous
Chloride
9056A
6.6
mg/L
49
013
AMW-1d
Aqueous
CO2 (calculation)
SM 4500-CO2
590
mg/L
49
013
AMW-1d
Aqueous
Nitrate - N
9056A
0.0094
J
mg/L
49
013
AMW-1d
Aqueous
Sulfate
9056A
0.25
J
mg/L
49
013
AMW-1d
Aqueous
Benzene
8260D
1.1
ug/L
50
013
AMW-1d
Aqueous
Chloroethane
8260D
1.2
ug/L
50
013
AMW-1d
Aqueous
1,1-Dichloroethane
8260D
14
ug/L
50
013
AMW-1d
Aqueous
cis- 1,2-Dichloroethene
8260D
2.5
ug/L
50
013
AMW-1d
Aqueous
Trichloroethene
8260D
0.40
J
ug/L
50
013
AMW-1d
Aqueous
Vinyl chloride
8260D
6.2
ug/L
51
013
AMW-1d
Aqueous
Ethane
RSK - 175
2.5
J
ug/L
53
013
AMW-1d
Aqueous
Methane
RSK - 175
1600
ug/L
53
013
AMW-1d
Aqueous
Antimony
6020B
5.8
ug/L
54
013
AMW-1d
Aqueous
Barium
6020B
110
ug/L
54
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Page 7 of 152

Detection Summary (Continued)
Lot Number: WK17018
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
013
AMW-1d
Aqueous
Beryllium
6020B
0.16
J
ug/L
54
013
AMW-1d
Aqueous
Chromium
6020B
1.5
J
ug/L
54
013
AMW-1d
Aqueous
Cobalt
6020B
5.7
ug/L
54
013
AMW-1d
Aqueous
Copper
6020B
1.5
J
ug/L
54
013
AMW-1d
Aqueous
Lead
6020B
0.74
J
ug/L
54
013
AMW-1d
Aqueous
Nickel
6020B
12
ug/L
54
013
AMW-1d
Aqueous
Zinc
6020B
7.6
J
ug/L
54
014
AMW-2s
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
66
mg CaCO3/1-
55
014
AMW-2s
Aqueous
Chloride
9056A
3.0
mg/L
55
014
AMW-2s
Aqueous
CO2 (calculation)
SM 4500-CO2
320
mg/L
55
014
AMW-2s
Aqueous
Nitrate - N
9056A
0.36
mg/L
55
014
AMW-2s
Aqueous
1,1-Dichloroethane
8260D
3.7
ug/L
56
014
AMW-2s
Aqueous
cis- 1,2-Dichloroethene
8260D
3.1
ug/L
56
014
AMW-2s
Aqueous
Tetrachloroethene
8260D
0.94
ug/L
56
014
AMW-2s
Aqueous
Trichloroethene
8260D
0.81
ug/L
56
014
AMW-2s
Aqueous
Barium
6020B
37
ug/L
60
014
AMW-2s
Aqueous
Beryllium
6020B
0.49
ug/L
60
015
MW-H
Aqueous
Barium
6020B
30
ug/L
64
015
MW-H
Aqueous
Nickel
6020B
1.8
J
ug/L
64
016
MW-L
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
43
mg CaCO3/L
65
016
MW-L
Aqueous
Chloride
9056A
2.9
mg/L
65
016
MW-L
Aqueous
CO2 (calculation)
SM 4500-CO2
270
mg/L
65
016
MW-L
Aqueous
Nitrate - N
9056A
0.066
mg/L
65
016
MW-L
Aqueous
Sulfate
9056A
1.0
mg/L
65
016
MW-L
Aqueous
Tetrachloroethene
8260D
0.48
J
ug/L
66
016
MW-L
Aqueous
Methane
RSK - 175
3.0
J
ug/L
68
016
MW-L
Aqueous
Barium
6020B
40
ug/L
69
016
MW-L
Aqueous
Chromium
6020B
1.6
J
ug/L
69
016
MW-L
Aqueous
Lead
6020B
0.45
J
ug/L
69
016
MW-L
Aqueous
Nickel
6020B
2.2
J
ug/L
69
016
MW-L
Aqueous
Vanadium
6020B
4.8
J
ug/L
69
016
MW-L
Aqueous
Zinc
6020B
6.9
J ug/L
69
017
MW-3
Aqueous
Alkalinity @ pH 4.5 su
SM 2320B-
91
mg CaCO3/L
70
017
MW-3
Aqueous
Chloride
9056A
6.6
mg/L
70
017
MW-3
Aqueous
CO2 (calculation)
SM 4500-CO2
220
mg/L
70
017
MW-3
Aqueous
Nitrate - N
9056A
0.0074
J mg/L
70
017
MW-3
Aqueous
1,1-Dichloroethane
8260D
17
ug/L
71
017
MW-3
Aqueous
1,1-Dichloroethene
8260D
1.2
ug/L
71
017
MW-3
Aqueous
cis- 1,2-Dichloroethene
8260D
8.1
ug/L
71
017
MW-3
Aqueous
Tetrachloroethene
8260D
7.4
ug/L
71
017
MW-3
Aqueous
Trichloroethene
8260D
4.5
ug/L
71
017
MW-3
Aqueous
Trichlorofluoromethane
8260D
0.62
ug/L
71
017
MW-3
Aqueous
Barium
6020B
30
ug/L
74
017
MW-3
Aqueous
Zinc
6020B
34
ug/L
74
(183
detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 8 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-001
Description: MW-H deep Matrix: Aqueous
Date Sampled:11/15/2021 1400 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/20/20211347 BWS
23231
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-001
Description: MW-H deep Matrix: Aqueous
Date Sampled:11/15/2021 1400 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/20/20211347 BWS 23231
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
109 70-130
118 70-130
112 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-001
Description: MW-H deep Matrix: Aqueous
Date Sampled:11/15/2021 1400 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2257 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
42
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-002
Description: DUP Matrix: Aqueous
Date Sampled:11/15/2021 0800 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/20/20211412 BWS
23231
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-002
Description: DUP Matrix: Aqueous
Date Sampled:11/15/2021 0800 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/20/20211412 BWS 23231
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
104 70-130
118 70-130
109 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-002
Description: DUP Matrix: Aqueous
Date Sampled:11/15/2021 0800 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2305 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
44
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-003
Description: MW-1 Matrix: Aqueous
Date Sampled:11/15/2021 1440 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/20/20211437 BWS
23231
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
2.1
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
1.1
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
1.3
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.67
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-003
Description: MW-1 Matrix: Aqueous
Date Sampled:11/15/2021 1440 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/20/20211437 BWS 23231
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
108 70-130
121 70-130
112 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-003
Description: MW-1 Matrix: Aqueous
Date Sampled:11/15/2021 1440 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2312 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
26
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.20
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.2
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.50
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.7
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.4
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-004
Description: MW-A Matrix: Aqueous
Date Sampled:11/16/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
11/30/2021 1916 AAB
24107
1
(BOD, 5 day) SM 521OB-2011
1
11/22/2021 1745 GAH
11/17/2021 1911 22694
1
(Chloride) 9056A
1
11/17/2021 1932 AMR
22960
1
(CO2 (calcula) SM 4500-CO2 D
1
11/30/2021 1916 AAB
1
(COD) SM 5220D-2011
1
11/27/2021 2054 DAK
23842
1
(Nitrate - N) 9056A
1
11/17/2021 1932 AMR
22958
2
(Nitrate - N) 9056A
5
11/25/2021 0136 AMR
23912
1
(Sulfate) 9056A
1
11/17/2021 1932 AMR
22955
1
(Sulfide) SM 4500-S2 F-2011
1
11/20/2021 1727 SJL
23209
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
140
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521 OB-2011
3.0
17
2.0
0.18
mg/L
1
Chloride
9056A
20
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
1300
27
27
mg/L
1
COD
SM 5220D-2011
20
U
20
20
mg/L
1
Sulfate
9056A
11
1.0
0.25
mg/L
1
Nitrate - N
9056A
0.020
US
0.020
0.0050
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L
1
Nitrate - N
9056A
0.10
UH
0.10
0.025
mg/L
2
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-004
Description: MW-A Matrix: Aqueous
Date Sampled:11/16/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/20/20211501 BWS
23231
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
7.0
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
1.0
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
4.0
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
22
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
11
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.40
J
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
89
0.50
0.40
ug/L
1
trans-1,2-Dichloroethene
156-60-5
8260D
0.49
J
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
1.7
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.65
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
2.7
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
3.9
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-004
Description: MW-A Matrix: Aqueous
Date Sampled:11/16/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/20/20211501 BWS 23231
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
2.4
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
0.40 J
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
116 70-130
121 70-130
113 70-130
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-004
Description: MW-A Matrix: Aqueous
Date Sampled:11/16/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
RSK - 175
1
11/23/2021 1227 TML
23440
2
RSK - 175
5
12/10/2021 1208 TML
25173
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 2500 E 10 2.5 ug/L 1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-004
Description: MW-A Matrix: Aqueous
Date Sampled:11/16/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
RSK - 175
1
11/23/2021 1227 TML
23440
2
RSK - 175
5
12/10/2021 1208 TML
25173
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 50 UH 50 13 ug/L 2
Ethene 74-85-1 RSK - 175 50 UH 50 13 ug/L 2
Methane 74-82-8 RSK - 175 12000 HD 50 13 ug/L 2
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-004
Description: MW-A Matrix: Aqueous
Date Sampled:11/16/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2319 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
46
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.22
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
15
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
18
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-005
Description: AMW-2d Matrix: Aqueous
Date Sampled:11/16/2021 1150 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
11/27/2021 1523 AAB
23834
1
(BOD, 5 day) SM 521OB-2011
1
11/22/2021 1748 GAH
11/17/2021 1918 22694
1
(Chloride) 9056A
1
11/17/2021 2029 AMR
22960
1
(CO2 (calcula) SM 4500-CO2 D
1
11/27/2021 1523 AAB
1
(COD) SM 5220D-2011
1
11/27/2021 2055 DAK
23842
1
(Nitrate - N) 9056A
1
11/17/2021 2029 AMR
22958
1
(Sulfate) 9056A
1
11/17/2021 2029 AMR
22955
1
(Sulfide) SM 4500-S2 F-2011
1
11/20/2021 1727 SJL
23209
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su
BOD, 5 day
Chloride
CO2 (calculation)
COD
Nitrate - N
Sulfate
Sulfide
SM 2320B-2011
130
20
20
mg CaCO3/L 1
SM 521OB-2011
2.0
U17
2.0
0.18
mg/L 1
9056A
3.4
1.0
0.25
mg/L 1
124-38-9 SM 4500-CO2 D
420
27
27
mg/L 1
SM 5220D-2011
20
US
20
20
mg/L 1
9056A
0.020
U
0.020
0.0050
mg/L 1
9056A
0.37
J
1.0
0.25
mg/L 1
18496-25-8 SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L 1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-005
Description: AMW-2d Matrix: Aqueous
Date Sampled:11/16/2021 1150 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/20/20211526 BWS
23231
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
1.2
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.44
J
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.4
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
21
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
1.4
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
21
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.46
J
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
2.9
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
6.3
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-005
Description: AMW-2d Matrix: Aqueous
Date Sampled:11/16/2021 1150 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/20/20211526 BWS 23231
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
0.50
J
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
105 70-130
123 70-130
111 70-130
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-005
Description: AMW-2d Matrix: Aqueous
Date Sampled:11/16/2021 1150 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/23/2021 1248 TML 23440
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 410 10 2.5 ug/L 1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-005
Description: AMW-2d Matrix: Aqueous
Date Sampled:11/16/2021 1150 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2327 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
67
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.18
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.9
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
8.7
J
10
2.5
ug/L
1
Footnote(s): 1-G:G Lower than valid range 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-009
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:11/16/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/20/20211257 BWS
23231
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-009
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:11/16/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /17/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/20/20211257 BWS 23231
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
102 70-130
117 70-130
107 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-010
Description: MW-E REP Matrix: Aqueous
Date Sampled:11/17/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
11/30/2021 2102 AAB
24107
1
(BOD, 5 day) SM 521OB-2011
1
11/23/2021 2215 GAH
11/18/2021 2314 23023
1
(Chloride) 9056A
1
11/19/2021 0006 AMR
23178
1
(CO2 (calcula) SM 4500-CO2 D
1
11/30/2021 2102 AAB
1
(COD) SM 5220D-2011
1
11/27/2021 2056 DAK
23842
1
(Nitrate - N) 9056A
1
11/19/2021 0006 AMR
23179
2
(Nitrate - N) 9056A
5
11/25/2021 0155 AMR
23912
1
(Sulfate) 9056A
1
11/19/2021 0006 AMR
23177
1
(Sulfide) SM 4500-S2 F-2011
1
11/20/2021 1727 SJL
23209
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
540
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521 OB-2011
2.0
U7
2.0
0.18
mg/L
1
Chloride
9056A
69
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9
SM 4500-CC2 D
900
27
27
mg/L
1
COD
SM 5220D-2011
20
U
20
20
mg/L
1
Sulfate
9056A
4.3
1.0
0.25
mg/L
1
Nitrate - N
9056A
0.020
U
0.020
0.0050
mg/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L
1
Nitrate - N
9056A
0.10
UH
0.10
0.025
mg/L
2
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-010
Description: MW-E REP Matrix: Aqueous
Date Sampled:11/17/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20211848
BWS
23641
2 5030B 8260D
1 12/09/20211500 JM1
25097
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.46
J
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
2.4
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
4.7
H
0.50
0.40
ug/L
2
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UL
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
8.2
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.3
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.80
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
11
0.50
0.40
ug/L
1
trans-1,2-Dichloroethene
156-60-5
8260D
0.43
J
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.72
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-010
Description: MW-E REP Matrix: Aqueous
Date Sampled:11/17/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/24/20211848 BWS
23641
2
5030B
8260D 1
12/09/20211500 JM1
25097
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
2.7
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130 H 86 70-130
118 70-130 H 98 70-130
106 70-130 H 91 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-010
Description: MW-E REP Matrix: Aqueous
Date Sampled:11/17/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0331 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.8 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
86 40-170
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-010
Description: MW-E REP Matrix: Aqueous
Date Sampled:11/17/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 0911 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 2.7 J 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 210 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-010
Description: MW-E REP Matrix: Aqueous
Date Sampled:11/17/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2334 BPK
6020B 10 11/24/2021 1119 BPK
Prep Date Batch
11/22/2021 0054 23281
11/22/2021 0054 23281
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
340 D
50
13
ug/L
2
Beryllium
7440-41-7 6020B
0.24 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
5.5
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1 6020B
0.43 J
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
13
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
3.8 J
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-011
Description: MW-E deep Matrix: Aqueous
Date Sampled:11/17/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 11/30/2021 2110 AAB
24107
1
(BOD, 5 day) SM 521OB-2011
1 11/23/2021 2215 GAH
11/18/2021
2314
23023
1
(Chloride) 9056A
5 11/19/2021 0025 AMR
23178
1
(CO2 (calcula) SM 4500-CO2 D
1 11/30/2021 2110 AAB
1
(COD) SM 5220D-2011
1 11/27/2021 2056 DAK
23842
1
(Nitrate - N) 9056A
5 11/19/2021 0025 AMR
23179
1
(Sulfate) 9056A
5 11/19/2021 0025 AMR
23177
1
(Sulfide) SM 4500-S2 F-2011
1 11/20/2021 1727 SJL
23209
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
420
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521 OB-2011
8.3
7
2.0
0.18
mg/L
1
Chloride
9056A
58
D
5.0
1.3
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
640
27
27
mg/L
1
COD
SM 5220D-2011
20
U
20
20
mg/L
1
Nitrate - N
9056A
0.39
D
0.10
0.025
mg/L
1
Sulfate
9056A
5.0
U
5.0
1.3
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-011
Description: MW-E deep Matrix: Aqueous
Date Sampled:11/17/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20211912
BWS
23641
2 5030B 8260D
1 12/09/20211524 JM1
25097
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.74
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
1.4
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
11
H
0.50
0.40
ug/L
2
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UL
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
7.6
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.74
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.91
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
0.99
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.77
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-011
Description: MW-E deep Matrix: Aqueous
Date Sampled:11/17/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/24/20211912 BWS
23641
2
5030B
8260D 1
12/09/20211524 JM1
25097
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.61
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
0.50
J
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
Footnote(s): 7-SCF Out of range
86 70-130 H 86 70-130
116 70-130 H 95 70-130
105 70-130 H 95 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-011
Description: MW-E deep Matrix: Aqueous
Date Sampled:11/17/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0355 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 7.0 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-011
Description: MW-E deep Matrix: Aqueous
Date Sampled:11/17/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
RSK - 175
1
11/30/2021 0922 TML
24004
2
RSK - 175
10
12/01/2021 0912 TML
24123
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 5.1 J 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 9600 D 100 25 ug/L 2
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-011
Description: MW-E deep Matrix: Aqueous
Date Sampled:11/17/2021 0945 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/23/2021 2341 BPK
6020B 100 11/24/2021 1126 BPK
Prep Date Batch
11/22/2021 0054 23281
11/22/2021 0054 23281
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
1.7 J
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
2.5
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
2300 D
500
130
ug/L
2
Beryllium
7440-41-7 6020B
0.21 J
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
0.16 J
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
34
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
2.3 J
5.0
1.3
ug/L
1
Lead
7439-92-1 6020B
18
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
18
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
8.5 J
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-012
Description: AMW-1s Matrix: Aqueous
Date Sampled:11/17/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 11/30/2021 2115 AAB
24107
1
(BOD, 5 day) SM 521OB-2011
1 11/23/2021 2220 GAH
11/18/2021
2322 23023
1
(Chloride) 9056A
1 11/19/2021 0044 AMR
23178
1
(CO2 (calcula) SM 4500-CO2 D
1 11/30/2021 2115 AAB
1
(COD) SM 5220D-2011
1 11/27/2021 2056 DAK
23842
1
(Nitrate - N) 9056A
1 11/19/2021 0044 AMR
23179
1
(Sulfate) 9056A
1 11/19/2021 0044 AMR
23177
1
(Sulfide) SM 4500-S2 F-2011
1 11/20/2021 1727 SJL
23209
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
50
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521 OB-2011
4.5
7
2.0
0.18
mg/L
1
Chloride
9056A
2.5
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
170
27
27
mg/L
1
COD
SM 5220D-2011
20
U
20
20
mg/L
1
Nitrate - N
9056A
0.23
0.020
0.0050
mg/L
1
Sulfate
9056A
0.39
J
1.0
0.25
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-012
Description: AMW-1s Matrix: Aqueous
Date Sampled:11/17/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20211937 BWS
23641
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UL
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-012
Description: AMW-1s Matrix: Aqueous
Date Sampled:11/17/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20211937 BWS 23641
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
90 70-130
120 70-130
106 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-012
Description: AMW-1s Matrix: Aqueous
Date Sampled:11/17/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0419 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-012
Description: AMW-1s Matrix: Aqueous
Date Sampled:11/17/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 0932 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 7.3 J 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-012
Description: AMW-1s Matrix: Aqueous
Date Sampled:11/17/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/24/2021 0004 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
34
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.41
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
1.4
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.5
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.37
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.2
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
9.6
J
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-013
Description: AMW-1d Matrix: Aqueous
Date Sampled:11/17/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
11/30/2021 2128 AAB
24111
1
(BOD, 5 day) SM 521OB-2011
1
11/23/2021 2223 GAH
11/18/2021 2329 23023
1
(Chloride) 9056A
1
11/19/2021 0103 AMR
23178
1
(CO2 (calcula) SM 4500-CO2 D
1
11/30/2021 2128 AAB
1
(COD) SM 5220D-2011
1
11/27/2021 2057 DAK
23842
1
(Nitrate - N) 9056A
1
11/19/2021 0103 AMR
23179
1
(Sulfate) 9056A
1
11/19/2021 0103 AMR
23177
1
(Sulfide) SM 4500-S2 F-2011
1
11/20/2021 1727 SJL
23209
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su
BOD, 5 day
Chloride
CO2 (calculation)
COD
Nitrate - N
Sulfate
Sulfide
Footnote(s): 7-SCF Out of range
SM 2320B-2011
190
20
20
mg CaCO3/L 1
SM 521OB-2011
3.7
7
2.0
0.18
mg/L 1
9056A
6.6
1.0
0.25
mg/L 1
124-38-9 SM 4500-CO2 D
590
27
27
mg/L 1
SM 5220D-2011
20
U
20
20
mg/L 1
9056A
0.0094
J
0.020
0.0050
mg/L 1
9056A
0.25
J
1.0
0.25
mg/L 1
18496-25-8 SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-013
Description: AMW-1d Matrix: Aqueous
Date Sampled:11/17/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210705 JWO
23570
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
1.1
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
1.2
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
14
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
2.5
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.40
J
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-013
Description: AMW-1d Matrix: Aqueous
Date Sampled:11/17/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210705 JWO 23570
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
6.2
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
90 70-130
117 70-130
102 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-013
Description: AMW-1d Matrix: Aqueous
Date Sampled:11/17/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0444 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-013
Description: AMW-1d Matrix: Aqueous
Date Sampled:11/17/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 0942 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 2.5 J 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 1600 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-013
Description: AMW-1d Matrix: Aqueous
Date Sampled:11/17/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/24/2021 0011 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
5.8
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
110
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.16
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
1.5
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.7
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.5
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.74
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
12
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
7.6
J
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-014
Description: AMW-2s Matrix: Aqueous
Date Sampled:11/17/2021 1130 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 11/30/2021 2132 AAB
24111
1
(BOD, 5 day) SM 521OB-2011
1 11/23/2021 2225 GAH
11/18/2021
2334 23023
1
(Chloride) 9056A
1 11/19/2021 0159 AMR
23185
1
(CO2 (calcula) SM 4500-CO2 D
1 11/30/2021 2132 AAB
1
(COD) SM 5220D-2011
1 11/27/2021 2057 DAK
23842
1
(Nitrate - N) 9056A
1 11/19/2021 0159 AMR
23188
1
(Sulfate) 9056A
1 11/19/2021 0159 AMR
23182
1
(Sulfide) SM 4500-S2 F-2011
1 11/20/2021 1727 SJL
23209
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
66
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521 OB-2011
2.0
U7
2.0
0.18
mg/L
1
Chloride
9056A
3.0
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
320
27
27
mg/L
1
COD
SM 5220D-2011
20
U
20
20
mg/L
1
Nitrate - N
9056A
0.36
0.020
0.0050
mg/L
1
Sulfate
9056A
1.0
U
1.0
0.25
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 55 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-014
Description: AMW-2s Matrix: Aqueous
Date Sampled:11/17/2021 1130 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210730 JWO
23570
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
3.7
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
3.1
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.94
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.81
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-014
Description: AMW-2s Matrix: Aqueous
Date Sampled:11/17/2021 1130 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210730 JWO 23570
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130
117 70-130
104 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 57 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-014
Description: AMW-2s Matrix: Aqueous
Date Sampled:11/17/2021 1130 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0508 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 58 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-014
Description: AMW-2s Matrix: Aqueous
Date Sampled:11/17/2021 1130 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 0952 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 10 U 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 59 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-014
Description: AMW-2s Matrix: Aqueous
Date Sampled:11/17/2021 1130 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/24/2021 0018 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
37
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.49
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 60 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-015
Description: MW-H Matrix: Aqueous
Date Sampled:11/17/2021 1200 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210301 JWO
23569
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
UL
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 61 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-015
Description: MW-H Matrix: Aqueous
Date Sampled:11/17/2021 1200 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210301 JWO 23569
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
99 70-130
110 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 62 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-015
Description: MW-H Matrix: Aqueous
Date Sampled:11/17/2021 1200 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0533 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 63 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-015
Description: MW-H Matrix: Aqueous
Date Sampled:11/17/2021 1200 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/24/2021 0026 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
30
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.8
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 64 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-016
Description: MW-L Matrix: Aqueous
Date Sampled:11/17/2021 1245 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1 11/30/2021 2145 AAB
24111
1
(BOD, 5 day) SM 521OB-2011
1 11/23/2021 2228 GAH
11/18/2021 2340 23023
1
(Chloride) 9056A
1 11/19/2021 0218 AMR
23185
1
(CO2 (calcula) SM 4500-CO2 D
1 11/30/2021 2145 AAB
1
(COD) SM 5220D-2011
1 11/27/2021 2057 DAK
23842
1
(Nitrate - N) 9056A
1 11/19/2021 0218 AMR
23188
1
(Sulfate) 9056A
1 11/19/2021 0218 AMR
23182
1
(Sulfide) SM 4500-S2 F-2011
1 11/20/2021 1727 SJL
23209
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
43
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521 OB-2011
2.0 U7
2.0
0.18
mg/L
1
Chloride
9056A
2.9
1.0
0.25
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2 D
270
27
27
mg/L
1
COD
SM 5220D-2011
20 U
20
20
mg/L
1
Nitrate - N
9056A
0.066
0.020
0.0050
mg/L
1
Sulfate
9056A
1.0
1.0
0.25
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-2
1.0 U
1.0
1.0
mg/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 65 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-016
Description: MW-L Matrix: Aqueous
Date Sampled:11/17/2021 1245 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/2021 0324 JWO
23569
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
UL
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.48
J
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 66 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-016
Description: MW-L Matrix: Aqueous
Date Sampled:11/17/2021 1245 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/2021 0324 JWO 23569
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
101 70-130
110 70-130
103 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 67 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-016
Description: MW-L Matrix: Aqueous
Date Sampled:11/17/2021 1245 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 1002 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 3.0 J 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 68 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-016
Description: MW-L Matrix: Aqueous
Date Sampled:11/17/2021 1245 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/24/2021 0033 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
40
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
1.6
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.45
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.2
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.8
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
6.9
J
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 69 of 152

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK17018-017
Description: MW-3 Matrix: Aqueous
Date Sampled:11/17/2021 1330 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
11/30/2021 2151 AAB
24111
1
(BOD, 5 day) SM 521OB-2011
1
11/23/2021 2229 GAH
11/18/2021 2343 23023
1
(Chloride) 9056A
1
11/19/2021 0237 AMR
23185
1
(CO2 (calcula) SM 4500-CO2 D
1
11/30/2021 2151 AAB
1
(COD) SM 5220D-2011
1
11/27/2021 2057 DAK
23842
1
(Nitrate - N) 9056A
1
11/19/2021 0237 AMR
23188
1
(Sulfate) 9056A
1
11/19/2021 0237 AMR
23182
1
(Sulfide) SM 4500-S2 F-2011
1
11/20/2021 1727 SJL
23209
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su
BOD, 5 day
Chloride
CO2 (calculation)
COD
Nitrate - N
Sulfate
Sulfide
Footnote(s): 7-SCF Out of range
SM 2320B-2011
91
20
20
mg CaCO3/L 1
SM 521OB-2011
2.0
U7
2.0
0.18
mg/L 1
9056A
6.6
1.0
0.25
mg/L 1
124-38-9 SM 4500-CO2 D
220
27
27
mg/L 1
SM 5220D-2011
20
U
20
20
mg/L 1
9056A
0.0074
J
0.020
0.0050
mg/L 1
9056A
1.0
U
1.0
0.25
mg/L 1
18496-25-8 SM 4500-S2 F-2
1.0
U
1.0
1.0
mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 70 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-017
Description: MW-3 Matrix: Aqueous
Date Sampled:11/17/2021 1330 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/2021 0347 JWO
23569
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
17
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
1.2
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
8.1
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
UL
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
7.4
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
4.5
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.62
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 71 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-017
Description: MW-3 Matrix: Aqueous
Date Sampled:11/17/2021 1330 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/2021 0347 JWO 23569
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
100 70-130
110 70-130
102 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 72 of 152

Dissolved Gases
Client:CDM Smith Laboratory ID:WK17018-017
Description: MW-3 Matrix: Aqueous
Date Sampled:11/17/2021 1330 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 1015 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 10 U 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 73 of 152

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK17018-017
Description: MW-3 Matrix: Aqueous
Date Sampled:11/17/2021 1330 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/24/2021 0040 BPK
Prep Date Batch
11/22/2021 0054 23281
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
30
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
34
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 74 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-019
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210214 JWO
23569
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
UL
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 75 of 152

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK17018-019
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210214 JWO 23569
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
98 70-130
109 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
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Page 76 of 152

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK17018-019
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/19/2021 0646 JWO 23060
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
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Page 77 of 152

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 78 of 152

Inorganic non-metals - BOD Blank and GGA
Matrix: Aqueous
Batch: 22694 SCF: 1.6
Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0
Result
Avg. Result
Sample ID
Depl
Avg. Depl (mg/L)
(mg/L) Q
Limit
Prep Date
Analysis Date
WQ22694-041 (Blank)
0.08
1
0.2
11/17/2021 1803
11/22/2021 1653
WQ22694-141 (Blank)
0.04
1
0.2
11/17/2021 1803
11/22/2021 1652
WQ22694-241 (Blank)
0.05
0.06
1
0.2
11/17/2021 1803
11/22/2021 1653
WQ22694-035 (GGA)
157.6
17
167.5-228.5
11/17/2021 1810
11/22/2021 1658
WQ22694-135 (GGA)
168.6
17
167.5-228.5
11/17/2021 1810
11/22/2021 1657
WQ22694-235 (GGA)
173.6
166.6 17
167.5-228.5
11/17/2021 1810
11/22/2021 1659
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 79 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ22955-001 Matrix: Aqueous
Batch: 22955
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.25 mg/L 11/17/2021 0904
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 80 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ22955-002 Matrix: Aqueous
Batch: 22955
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 21 1 104 80-120 11/17/2021 0948
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 81 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MS
Sample ID: WK17018-OO4MS Matrix: Aqueous
Batch: 22955
Analytical Method: 9056A
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 11 10 21 1 93 80-120 11/17/2021 1951
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 82 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MSD
Sample ID: WK17018-OO4MD Matrix: Aqueous
Batch: 22955
Analytical Method: 9056A
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfate 11 10 20 1 91 0.85 80-120 20 11/17/2021 2010
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 83 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ22958-001 Matrix: Aqueous
Batch: 22958
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/17/2021 0904
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 84 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ22958-002 Matrix: Aqueous
Batch: 22958
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.84 1 105 80-120 11/17/2021 0948
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 85 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MS
Sample ID: WK17018-004MS Matrix: Aqueous
Batch: 22958
Analytical Method: 9056A
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.0 0.40 0.13 N 1 33 80-120 11/17/2021 1951
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 86 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MSD
Sample ID: WK17018-004MD Matrix: Aqueous
Batch: 22958
Analytical Method: 9056A
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Nitrate - N 0.0 0.40 0.034 N,+ 1 8.6 120 80-120 20 11/17/2021 2010
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 87 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ22960-001 Matrix: Aqueous
Batch: 22960
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.25 mg/L 11/17/2021 0904
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 88 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ22960-002 Matrix: Aqueous
Batch: 22960
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 21 1 106 80-120 11/17/2021 0948
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 89 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MS
Sample ID: WK17018-OO4MS Matrix: Aqueous
Batch: 22960
Analytical Method: 9056A
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 10 30 1 103 80-120 11/17/2021 1951
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 90 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MSD
Sample ID: WK17018-OO4MD Matrix: Aqueous
Batch: 22960
Analytical Method: 9056A
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Chloride 20 10 30 1 102 0.12 80-120 20 11/17/2021 2010
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 91 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - BOD Blank and GGA
Matrix: Aqueous
Batch: 23023 SCF: 1.1
Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0
Result
Avg. Result
Sample ID
Depl
Avg. Depl (mg/L)
(mg/L) Q
Limit
Prep Date
Analysis Date
WQ23023-041 (Blank)
0.06
0.2
11/18/2021 2300
11/23/2021 2207
WQ23023-141 (Blank)
0.08
0.2
11/18/2021 2300
11/23/2021 2206
WQ23023-241 (Blank)
0.13
0.09
0.2
11/18/2021 2300
11/23/2021 2207
WQ23023-035 (GGA)
194.5
7
167.5-228.5
11/18/2021 2308
11/23/2021 2211
WQ23023-135 (GGA)
165.5
71
167.5-228.5
11/18/2021 2308
11/23/2021 2211
WQ23023-235 (GGA)
153
171 71
167.5-228.5
11/18/2021 2308
11/23/2021 2211
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 92 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23177-001 Matrix: Aqueous
Batch: 23177
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.25 mg/L 11/18/2021 1554
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 93 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23177-002 Matrix: Aqueous
Batch: 23177
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 22 1 108 80-120 11/18/2021 1632
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 94 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23178-001 Matrix: Aqueous
Batch: 23178
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.25 mg/L 11/18/2021 1554
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 95 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23178-002 Matrix: Aqueous
Batch: 23178
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 21 1 107 80-120 11/18/2021 1632
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 96 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23179-001 Matrix: Aqueous
Batch: 23179
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/18/2021 1554
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 97 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23179-002 Matrix: Aqueous
Batch: 23179
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.87 1 109 80-120 11/18/2021 1632
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 98 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23182-001 Matrix: Aqueous
Batch: 23182
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.25 mg/L 11/18/2021 2328
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 99 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23182-002 Matrix: Aqueous
Batch: 23182
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 21 1 106 80-120 11/19/2021 0141
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 100 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23185-001 Matrix: Aqueous
Batch: 23185
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.25 mg/L 11/18/2021 2328
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 101 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23185-002 Matrix: Aqueous
Batch: 23185
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 21 1 106 80-120 11/19/2021 0141
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 102 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23188-001 Matrix: Aqueous
Batch: 23188
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/18/2021 2328
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 103 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23188-002 Matrix: Aqueous
Batch: 23188
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.84 1 105 80-120 11/19/2021 0141
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 104 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23209-001 Matrix: Aqueous
Batch: 23209
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide 1.0 U 1 1.0 1.0 mg/L 11/20/2021 1727
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 105 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23209-002 Matrix: Aqueous
Batch: 23209
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 10 9.2 1 92 80-120 11/20/2021 1727
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 106 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23834-002 Matrix: Aqueous
Batch:23834
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 96 1 96 90-110 11/27/2021 1433
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 107 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23842-001 Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
COD 20 U 1 20 20 mg/L 11/27/2021 2052
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 108 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23842-002 Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 40 41 1 102 95-105 11/27/2021 2053
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 109 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MS
Sample ID: WK17018-005MS Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 0.0 40 44 1 109 90-110 11/27/2021 2055
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 110 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MSD
Sample ID: WK17018-005MD Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
COD 0.0 40 35 N,+ 1 86 23 90-110 20 11/27/2021 2055
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 111 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - MB
Sample ID: WQ23912-001 Matrix: Aqueous
Batch: 23912
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/24/2021 1858
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 112 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ23912-002 Matrix: Aqueous
Batch: 23912
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.83 1 103 80-120 11/24/2021 1936
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 113 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ24107-002 Matrix: Aqueous
Batch: 24107
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 98 1 98 90-110 11/30/2021 1910
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 114 of 152
QC Data for Lot Number: WK17018

Inorganic non-metals - LCS
Sample ID: WQ24111-002 Matrix: Aqueous
Batch:24111
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 100 1 102 90-110 11/30/2021 2122
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 115 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: WQ23060-001 Matrix: Aqueous
Batch:23060 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 11/18/2021 2157
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
86 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 116 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: WQ23060-002 Matrix: Aqueous
Batch:23060 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 54 1 107 70-130 11/18/2021 2033
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
103 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 117 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23231-001 Matrix: Aqueous
Batch: 23231 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/20/2021 1159
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/20/2021 1159
Benzene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/20/2021 1159
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
11/20/2021 1159
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/20/2021 1159
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
2-Hexanone
10
U
1
10
2.0
ug/L
11/20/2021 1159
Methacrylonitrile
5.0
U
1
5.0
2.0
ug/L
11/20/2021 1159
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/20/2021 1159
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/20/2021 1159
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Styrene
0.50
U
1
0.50
0.41
ug/L
11/20/2021 1159
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Toluene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 118 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23231-001 Matrix: Aqueous
Batch:23231 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/20/2021 1159
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/20/2021 1159
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/20/2021 1159
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 105 70-130
1,2-Dichloroethane-d4 111 70-130
Toluene-d8 107 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 119 of 152

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23231-002 Matrix: Aqueous
Batch: 23231 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
78
1
78
60-140
11/20/2021 1100
Acrylonitrile
100
110
1
109
70-130
11/20/2021 1100
Benzene
50
55
1
109
70-130
11/20/2021 1100
Bromochloromethane
50
52
1
103
70-130
11/20/2021 1100
Bromodichloromethane
50
54
1
108
70-130
11/20/2021 1100
Bromoform
50
50
1
99
70-130
11/20/2021 1100
Bromomethane (Methyl bromide)
50
50
1
100
70-130
11/20/2021 1100
2-Butanone (MEK)
100
98
1
98
70-130
11/20/2021 1100
Carbon disulfide
50
51
1
102
70-130
11/20/2021 1100
Carbon tetrachloride
50
55
1
110
70-130
11/20/2021 1100
Chlorobenzene
50
52
1
104
70-130
11/20/2021 1100
Chloroethane
50
54
1
109
70-130
11/20/2021 1100
Chloroform
50
53
1
106
70-130
11/20/2021 1100
Chloromethane (Methyl chloride)
50
56
1
112
60-140
11/20/2021 1100
1,2-Dibromo-3-chloropropane (DBCP)
50
53
1
105
70-130
11/20/2021 1100
Dibromochloromethane
50
53
1
105
70-130
11/20/2021 1100
1,2-Dibromoethane (EDB)
50
53
1
105
70-130
11/20/2021 1100
Dibromomethane (Methylene bromide)
50
50
1
101
70-130
11/20/2021 1100
trans- 1,4-Dichloro-2-butene
50
45
1
91
70-130
11/20/2021 1100
1,2-Dichlorobenzene
50
52
1
104
70-130
11/20/2021 1100
1,4-Dichlorobenzene
50
50
1
100
70-130
11/20/2021 1100
1,1-Dichloroethane
50
56
1
113
70-130
11/20/2021 1100
1,2-Dichloroethane
50
55
1
109
70-130
11/20/2021 1100
1,1-Dichloroethene
50
55
1
109
70-130
11/20/2021 1100
cis- 1,2-Dichloroethene
50
54
1
109
70-130
11/20/2021 1100
trans- 1,2-Dichloroethene
50
54
1
108
70-130
11/20/2021 1100
1,2-Dichloropropane
50
55
1
110
70-130
11/20/2021 1100
cis- 1,3-Dichloropropene
50
50
1
100
70-130
11/20/2021 1100
trans- 1,3-Dichloropropene
50
48
1
96
70-130
11/20/2021 1100
Ethylbenzene
50
57
1
114
70-130
11/20/2021 1100
2-Hexanone
100
110
1
109
70-130
11/20/2021 1100
Methacrylonitrile
250
280
1
112
70-130
11/20/2021 1100
Methyl iodide (lodomethane)
50
51
1
101
70-130
11/20/2021 1100
4-Methyl-2-pentanone
100
120
1
115
70-130
11/20/2021 1100
Methylene chloride
50
49
1
98
70-130
11/20/2021 1100
Styrene
50
52
1
103
70-130
11/20/2021 1100
1,1,1,2-Tetrachloroethane
50
53
1
105
70-130
11/20/2021 1100
1,1,2,2-Tetrachloroethane
50
52
1
104
70-130
11/20/2021 1100
Tetrachloroethene
50
53
1
106
70-130
11/20/2021 1100
Toluene
50
58
1
115
70-130
11/20/2021 1100
1,1,1-Trichloroethane
50
57
1
113
70-130
11/20/2021 1100
1,1,2-Trichloroethane
50
51
1
102
70-130
11/20/2021 1100
Trichloroethene
50
52
1
104
70-130
11/20/2021 1100
Trichlorofluoromethane
50
55
1
111
70-130
11/20/2021 1100
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 120 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23231-002
Matrix: Aqueous
Batch:23231
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
50
1
101
70-130
11/20/2021 1100
Vinyl acetate
50
53
1
106
60-140
11/20/2021 1100
Vinyl chloride
50
57
1
114
70-130
11/20/2021 1100
Xylenes (total)
100
110
1
110
70-130
11/20/2021 1100
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 106 70-130
1,2-Dichloroethane-d4 102 70-130
Toluene-d8 103 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 121 of 152

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23569-001 Matrix: Aqueous
Batch: 23569 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/23/2021 2339
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/23/2021 2339
Benzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/23/2021 2339
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
11/23/2021 2339
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
2-Hexanone
10
U
1
10
2.0
ug/L
11/23/2021 2339
Methacrylonitrile
5.0
U
1
5.0
2.0
ug/L
11/23/2021 2339
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/23/2021 2339
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/23/2021 2339
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Styrene
0.50
U
1
0.50
0.41
ug/L
11/23/2021 2339
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Toluene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 122 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23569-001 Matrix: Aqueous
Batch: 23569 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/23/2021 2339
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/23/2021 2339
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 103 70-130
1,2-Dichloroethane-d4 112 70-130
Toluene-d8 94 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 123 of 152

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23569-002 Matrix: Aqueous
Batch: 23569 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Acetone
100
180
N
1
177
60-140
11/23/2021 2103
Acrylonitrile
100
120
1
117
70-130
11/23/2021 2103
Benzene
50
50
1
101
70-130
11/23/2021 2103
Bromochloromethane
50
50
1
101
70-130
11/23/2021 2103
Bromodichloromethane
50
55
1
110
70-130
11/23/2021 2103
Bromoform
50
45
1
90
70-130
11/23/2021 2103
Bromomethane (Methyl bromide)
50
42
1
84
70-130
11/23/2021 2103
2-Butanone (MEK)
100
140
N
1
143
70-130
11/23/2021 2103
Carbon disulfide
50
54
1
107
70-130
11/23/2021 2103
Carbon tetrachloride
50
59
1
117
70-130
11/23/2021 2103
Chlorobenzene
50
49
1
99
70-130
11/23/2021 2103
Chloroethane
50
41
1
81
70-130
11/23/2021 2103
Chloroform
50
53
1
106
70-130
11/23/2021 2103
Chloromethane (Methyl chloride)
50
48
1
96
60-140
11/23/2021 2103
1,2-Dibromo-3-chloropropane (DBCP)
50
59
1
117
70-130
11/23/2021 2103
Dibromochloromethane
50
55
1
110
70-130
11/23/2021 2103
1,2-Dibromoethane (EDB)
50
51
1
103
70-130
11/23/2021 2103
Dibromomethane (Methylene bromide)
50
52
1
104
70-130
11/23/2021 2103
trans- 1,4-Dichloro-2-butene
50
63
1
126
70-130
11/23/2021 2103
1,2-Dichlorobenzene
50
49
1
97
70-130
11/23/2021 2103
1,4-Dichlorobenzene
50
48
1
95
70-130
11/23/2021 2103
1,1-Dichloroethane
50
55
1
110
70-130
11/23/2021 2103
1,2-Dichloroethane
50
53
1
106
70-130
11/23/2021 2103
1,1-Dichloroethene
50
54
1
107
70-130
11/23/2021 2103
cis- 1,2-Dichloroethene
50
50
1
101
70-130
11/23/2021 2103
trans- 1,2-Dichloroethene
50
52
1
105
70-130
11/23/2021 2103
1,2-Dichloropropane
50
53
1
106
70-130
11/23/2021 2103
cis- 1,3-Dichloropropene
50
57
1
114
70-130
11/23/2021 2103
trans- 1,3-Dichloropropene
50
49
1
98
70-130
11/23/2021 2103
Ethylbenzene
50
50
1
101
70-130
11/23/2021 2103
2-Hexanone
100
140
N
1
138
70-130
11/23/2021 2103
Methacrylonitrile
250
280
1
112
70-130
11/23/2021 2103
Methyl iodide (lodomethane)
50
45
1
89
70-130
11/23/2021 2103
4-Methyl-2-pentanone
100
120
1
122
70-130
11/23/2021 2103
Methylene chloride
50
48
1
96
70-130
11/23/2021 2103
Styrene
50
53
1
106
70-130
11/23/2021 2103
1,1,1,2-Tetrachloroethane
50
52
1
103
70-130
11/23/2021 2103
1,1,2,2-Tetrachloroethane
50
57
1
113
70-130
11/23/2021 2103
Tetrachloroethene
50
49
1
97
70-130
11/23/2021 2103
Toluene
50
51
1
103
70-130
11/23/2021 2103
1,1,1-Trichloroethane
50
56
1
111
70-130
11/23/2021 2103
1,1,2-Trichloroethane
50
49
1
97
70-130
11/23/2021 2103
Trichloroethene
50
49
1
97
70-130
11/23/2021 2103
Trichlorofluoromethane
50
51
1
103
70-130
11/23/2021 2103
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 124 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23569-002
Matrix: Aqueous
Batch: 23569
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
56
1
112
70-130
11/23/2021 2103
Vinyl acetate
50
50
1
101
60-140
11/23/2021 2103
Vinyl chloride
50
54
1
108
70-130
11/23/2021 2103
Xylenes (total)
100
100
1
101
70-130
11/23/2021 2103
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 97 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 125 of 152

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23570-001 Matrix: Aqueous
Batch: 23570 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/23/2021 2248
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/23/2021 2248
Benzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/23/2021 2248
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
11/23/2021 2248
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2248
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
2-Hexanone
10
U
1
10
2.0
ug/L
11/23/2021 2248
Methacrylonitrile
5.0
U
1
5.0
2.0
ug/L
11/23/2021 2248
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/23/2021 2248
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/23/2021 2248
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Styrene
0.50
U
1
0.50
0.41
ug/L
11/23/2021 2248
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Toluene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 126 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23570-001 Matrix: Aqueous
Batch:23570 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/23/2021 2248
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2248
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/23/2021 2248
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 90 70-130
1,2-Dichloroethane-d4 115 70-130
Toluene-d8 103 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 127 of 152

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23570-002 Matrix: Aqueous
Batch: 23570 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
140
1
139
60-140
11/23/2021 2055
Acrylonitrile
100
130
1
129
70-130
11/23/2021 2055
Benzene
50
51
1
101
70-130
11/23/2021 2055
Bromochloromethane
50
51
1
103
70-130
11/23/2021 2055
Bromodichloromethane
50
45
1
90
70-130
11/23/2021 2055
Bromoform
50
39
1
78
70-130
11/23/2021 2055
Bromomethane (Methyl bromide)
50
52
1
104
70-130
11/23/2021 2055
2-Butanone (MEK)
100
120
1
120
70-130
11/23/2021 2055
Carbon disulfide
50
55
1
111
70-130
11/23/2021 2055
Carbon tetrachloride
50
48
1
96
70-130
11/23/2021 2055
Chlorobenzene
50
46
1
92
70-130
11/23/2021 2055
Chloroethane
50
57
1
114
70-130
11/23/2021 2055
Chloroform
50
52
1
103
70-130
11/23/2021 2055
Chloromethane (Methyl chloride)
50
53
1
105
60-140
11/23/2021 2055
1,2-Dibromo-3-chloropropane (DBCP)
50
42
1
84
70-130
11/23/2021 2055
Dibromochloromethane
50
42
1
83
70-130
11/23/2021 2055
1,2-Dibromoethane (EDB)
50
44
1
88
70-130
11/23/2021 2055
Dibromomethane (Methylene bromide)
50
48
1
96
70-130
11/23/2021 2055
trans- 1,4-Dichloro-2-butene
50
41
1
82
70-130
11/23/2021 2055
1,2-Dichlorobenzene
50
46
1
92
70-130
11/23/2021 2055
1,4-Dichlorobenzene
50
45
1
91
70-130
11/23/2021 2055
1,1-Dichloroethane
50
55
1
110
70-130
11/23/2021 2055
1,2-Dichloroethane
50
46
1
93
70-130
11/23/2021 2055
1,1-Dichloroethene
50
55
1
110
70-130
11/23/2021 2055
cis- 1,2-Dichloroethene
50
53
1
105
70-130
11/23/2021 2055
trans- 1,2-Dichloroethene
50
51
1
102
70-130
11/23/2021 2055
1,2-Dichloropropane
50
50
1
99
70-130
11/23/2021 2055
cis- 1,3-Dichloropropene
50
47
1
94
70-130
11/23/2021 2055
trans- 1,3-Dichloropropene
50
45
1
90
70-130
11/23/2021 2055
Ethylbenzene
50
45
1
91
70-130
11/23/2021 2055
2-Hexanone
100
98
1
98
70-130
11/23/2021 2055
Methacrylonitrile
250
290
1
114
70-130
11/23/2021 2055
Methyl iodide (lodomethane)
50
52
1
104
70-130
11/23/2021 2055
4-Methyl-2-pentanone
100
96
1
96
70-130
11/23/2021 2055
Methylene chloride
50
60
1
120
70-130
11/23/2021 2055
Styrene
50
45
1
90
70-130
11/23/2021 2055
1,1,1,2-Tetrachloroethane
50
44
1
88
70-130
11/23/2021 2055
1,1,2,2-Tetrachloroethane
50
48
1
97
70-130
11/23/2021 2055
Tetrachloroethene
50
44
1
88
70-130
11/23/2021 2055
Toluene
50
47
1
93
70-130
11/23/2021 2055
1,1,1-Trichloroethane
50
49
1
98
70-130
11/23/2021 2055
1,1,2-Trichloroethane
50
45
1
90
70-130
11/23/2021 2055
Trichloroethene
50
45
1
90
70-130
11/23/2021 2055
Trichlorofluoromethane
50
50
1
100
70-130
11/23/2021 2055
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 128 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23570-002
Matrix: Aqueous
Batch:23570
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
45
1 91
70-130
11/23/2021 2055
Vinyl acetate
50
49
1 98
60-140
11/23/2021 2055
Vinyl chloride
50
53
1 106
70-130
11/23/2021 2055
Xylenes (total)
100
91
1 91
70-130
11/23/2021 2055
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 90 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 129 of 152

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23641-001 Matrix: Aqueous
Batch: 23641 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/24/2021 1034
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/24/2021 1034
Benzene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/24/2021 1034
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
11/24/2021 1034
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/24/2021 1034
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
2-Hexanone
10
U
1
10
2.0
ug/L
11/24/2021 1034
Methacrylonitrile
5.0
U
1
5.0
2.0
ug/L
11/24/2021 1034
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/24/2021 1034
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/24/2021 1034
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Styrene
0.50
U
1
0.50
0.41
ug/L
11/24/2021 1034
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Toluene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 130 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23641-001 Matrix: Aqueous
Batch:23641 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/24/2021 1034
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/24/2021 1034
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/24/2021 1034
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 86 70-130
1,2-Dichloroethane-d4 113 70-130
Toluene-d8 104 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 131 of 152

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23641-002
Matrix: Aqueous
Batch: 23641
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
140
N 1
144
60-140
11/24/2021 0933
Acrylonitrile
100
110
1
109
70-130
11/24/2021 0933
Benzene
50
55
1
109
70-130
11/24/2021 0933
Bromochloromethane
50
53
1
105
70-130
11/24/2021 0933
Bromodichloromethane
50
50
1
100
70-130
11/24/2021 0933
Bromoform
50
43
1
85
70-130
11/24/2021 0933
Bromomethane (Methyl bromide)
50
55
1
ill
70-130
11/24/2021 0933
2-Butanone (MEK)
100
130
1
130
70-130
11/24/2021 0933
Carbon disulfide
50
58
1
117
70-130
11/24/2021 0933
Carbon tetrachloride
50
52
1
103
70-130
11/24/2021 0933
Chlorobenzene
50
49
1
98
70-130
11/24/2021 0933
Chloroethane
50
64
1
128
70-130
11/24/2021 0933
Chloroform
50
55
1
111
70-130
11/24/2021 0933
Chloromethane (Methyl chloride)
50
55
1
109
60-140
11/24/2021 0933
1,2-Dibromo-3-chloropropane (DBCP)
50
43
1
87
70-130
11/24/2021 0933
Dibromochloromethane
50
47
1
94
70-130
11/24/2021 0933
1,2-Dibromoethane (EDB)
50
47
1
94
70-130
11/24/2021 0933
Dibromomethane (Methylene bromide)
50
52
1
104
70-130
11/24/2021 0933
trans- 1,4-Dichloro-2-butene
50
31
N 1
63
70-130
11/24/2021 0933
1,2-Dichlorobenzene
50
48
1
96
70-130
11/24/2021 0933
1,4-Dichlorobenzene
50
47
1
94
70-130
11/24/2021 0933
1,1-Dichloroethane
50
58
1
116
70-130
11/24/2021 0933
1,2-Dichloroethane
50
49
1
99
70-130
11/24/2021 0933
1,1-Dichloroethene
50
58
1
115
70-130
11/24/2021 0933
cis- 1,2-Dichloroethene
50
54
1
107
70-130
11/24/2021 0933
trans- 1,2-Dichloroethene
50
54
1
108
70-130
11/24/2021 0933
1,2-Dichloropropane
50
54
1
108
70-130
11/24/2021 0933
cis- 1,3-Dichloropropene
50
49
1
99
70-130
11/24/2021 0933
trans- 1,3-Dichloropropene
50
47
1
94
70-130
11/24/2021 0933
Ethylbenzene
50
47
1
95
70-130
11/24/2021 0933
2-Hexanone
100
100
1
101
70-130
11/24/2021 0933
Methacrylonitrile
250
280
1
112
70-130
11/24/2021 0933
Methyl iodide (lodomethane)
50
54
1
107
70-130
11/24/2021 0933
4-Methyl-2-pentanone
100
95
1
95
70-130
11/24/2021 0933
Methylene chloride
50
62
1
125
70-130
11/24/2021 0933
Styrene
50
48
1
96
70-130
11/24/2021 0933
1,1,1,2-Tetrachloroethane
50
49
1
97
70-130
11/24/2021 0933
1,1,2,2-Tetrachloroethane
50
51
1
101
70-130
11/24/2021 0933
Tetrachloroethene
50
47
1
94
70-130
11/24/2021 0933
Toluene
50
49
1
98
70-130
11/24/2021 0933
1,1,1-Trichloroethane
50
52
1
104
70-130
11/24/2021 0933
1,1,2-Trichloroethane
50
48
1
97
70-130
11/24/2021 0933
Trichloroethene
50
48
1
97
70-130
11/24/2021 0933
Trichlorofluoromethane
50
56
1
112
70-130
11/24/2021 0933
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 132 of 152
QC Data for Lot Number: WK17018

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23641-002
Matrix: Aqueous
Batch:23641
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
47
1 93
70-130
11/24/2021 0933
Vinyl acetate
50
46
1 91
60-140
11/24/2021 0933
Vinyl chloride
50
55
1 109
70-130
11/24/2021 0933
Xylenes (total)
100
95
1 95
70-130
11/24/2021 0933
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 101 70-130
Toluene-d8 101 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 133 of 152

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ25097-001 Matrix: Aqueous
Batch: 25097 Prep Method: 5030E
Analytical Method: 8260D
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloroethane 0.50 U 1 0.50 0.40 ug/L 12/09/2021 1033
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 85 70-130
1,2-Dichloroethane-d4 92 70-130
Toluene-d8 95 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 134 of 152

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ25097-002
Matrix: Aqueous
Batch: 25097
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
Chloroethane
50
46
1 92 70-130 12/09/2021 0919
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 88 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK17018
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 135 of 152

Dissolved Gases - MB
Sample ID: WQ23440-001 Matrix: Aqueous
Batch:23440
Analytical Method: RSK - 175
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Ethane
10
U
1
10
2.5
ug/L
11/23/2021 0902
Ethene
10
U
1
10
2.5
ug/L
11/23/2021 0902
Methane
10
U
1
10
2.5
ug/L
11/23/2021 0902
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 136 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - LCS
Sample ID: WQ23440-002 Matrix: Aqueous
Batch:23440
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Ethane
280
340
1
120
70-130
11/23/2021 0841
Ethene
260
310
1
119
70-130
11/23/2021 0841
Methane
150
170
1
115
70-130
11/23/2021 0841
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 137 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - MB
Sample ID: WQ24004-001 Matrix: Aqueous
Batch:24004
Analytical Method: RSK - 175
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Ethane
10
U
1
10
2.5
ug/L
11/30/2021 0859
Ethene
10
U
1
10
2.5
ug/L
11/30/2021 0859
Methane
10
U
1
10
2.5
ug/L
11/30/2021 0859
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 138 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - LCS
Sample ID: WQ24004-002 Matrix: Aqueous
Batch:24004
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Ethane
280
310
1
108
70-130
11/30/2021 0826
Ethene
260
270
1
103
70-130
11/30/2021 0826
Methane
150
160
1
109
70-130
11/30/2021 0826
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 139 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - LCSD
Sample ID: WQ24004-003 Matrix: Aqueous
Batch:24004
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
% RPD
Limit
Limit
Analysis Date
Ethane
280
300
1 107
1.3
70-130
30
11/30/2021 0836
Ethene
260
270
1 102
0.87
70-130
30
11/30/2021 0836
Methane
150
160
1 107
1.5
70-130
30
11/30/2021 0836
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 140 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - MB
Sample ID: WQ24123-001 Matrix: Aqueous
Batch: 24123
Analytical Method: RSK - 175
Parameter Result Q Dil LOQ DL Units Analysis Date
Methane 10 U 1 10 2.5 ug/L 12/01/2021 0846
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 141 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - LCS
Sample ID: WQ24123-002 Matrix: Aqueous
Batch: 24123
Analytical Method: RSK - 175
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 120 1 82 70-130 12/01/2021 0833
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 142 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - MB
Sample ID: WQ25173-001 Matrix: Aqueous
Batch: 25173
Analytical Method: RSK - 175
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Ethane
10
U
1
10
2.5
ug/L
12/10/2021 0908
Ethene
10
U
1
10
2.5
ug/L
12/10/2021 0908
Methane
10
U
1
10
2.5
ug/L
12/10/2021 0908
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 143 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - LCS
Sample ID: WQ25173-002 Matrix: Aqueous
Batch: 25173
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Ethane
550
620
1
111
70-130
12/10/2021 0840
Ethene
520
580
1
112
70-130
12/10/2021 0840
Methane
300
320
1
109
70-130
12/10/2021 0840
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 144 of 152
QC Data for Lot Number: WK17018

Dissolved Gases - LCSD
Sample ID: WQ25173-003
Matrix: Aqueous
Batch: 25173
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L) Q
Dil % Rec % RPD
Limit
Limit
Analysis Date
Ethane
550
620
1 112 0.30
70-130
30
12/10/2021 0854
Ethene
520
580
1 112 0.12
70-130
30
12/10/2021 0854
Methane
300
320
1 108 0.46
70-130
30
12/10/2021 0854
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 145 of 152
QC Data for Lot Number: WK17018

ICP-MS Metals - MB
Sample ID: WQ23281-001 Matrix: Aqueous
Batch: 23281 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/22/2021 0054
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
11/23/2021 1719
Arsenic
2.0
U
1
2.0
1.3
ug/L
11/23/2021 1719
Barium
5.0
U
1
5.0
1.3
ug/L
11/23/2021 1719
Beryllium
0.40
U
1
0.40
0.15
ug/L
11/23/2021 1719
Cadmium
0.50
U
1
0.50
0.13
ug/L
11/23/2021 1719
Chromium
5.0
U
1
5.0
1.3
ug/L
11/23/2021 1719
Cobalt
5.0
U
1
5.0
1.3
ug/L
11/23/2021 1719
Copper
5.0
U
1
5.0
1.3
ug/L
11/23/2021 1719
Lead
1.0
U
1
1.0
0.25
ug/L
11/23/2021 1719
Nickel
5.0
U
1
5.0
1.3
ug/L
11/23/2021 1719
Selenium
5.0
U
1
5.0
1.3
ug/L
11/23/2021 1719
Silver
1.0
U
1
1.0
0.25
ug/L
11/23/2021 1719
Thallium
0.50
U
1
0.50
0.15
ug/L
11/23/2021 1719
Vanadium
5.0
U
1
5.0
2.5
ug/L
11/23/2021 1719
Zinc
10
U
1
10
2.5
ug/L
11/23/2021 1719
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 146 of 152
QC Data for Lot Number: WK17018

ICP-MS Metals - LCS
Sample ID: WQ23281-002 Matrix: Aqueous
Batch: 23281 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/22/2021 0054
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
93
1
93
80-120
11/23/2021 1726
Arsenic
100
86
1
86
80-120
11/23/2021 1726
Barium
100
96
1
96
80-120
11/23/2021 1726
Beryllium
100
93
1
93
80-120
11/23/2021 1726
Cadmium
100
93
1
93
80-120
11/23/2021 1726
Chromium
100
100
1
103
80-120
11/23/2021 1726
Cobalt
100
100
1
101
80-120
11/23/2021 1726
Copper
100
110
1
109
80-120
11/23/2021 1726
Lead
100
110
1
106
80-120
11/23/2021 1726
Nickel
100
110
1
106
80-120
11/23/2021 1726
Selenium
100
80
1
80
80-120
11/23/2021 1726
Silver
100
95
1
95
80-120
11/23/2021 1726
Thallium
100
100
1
105
80-120
11/23/2021 1726
Vanadium
100
100
1
101
80-120
11/23/2021 1726
Zinc
100
85
1
85
80-120
11/23/2021 1726
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 147 of 152
QC Data for Lot Number: WK17018

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 148 of 152

PACE ANALYTICAL SERVICES, LLC
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Page 149 of 152

PACE ANALYTICAL SERVICES, LLC
Sarre Recegrt Checklist (SRC) [ME0d18G1S) Ri2wised-9f 29}2020
fiCTf IssuirLSAvthority, farce ENV - WCOL F3g2 1 4�t 1
Sample Receipt Cheeklist (SR C
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h,e; tl ofrwc¢ipl.
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1, Were cusloft seals pmm. tan ih,. Coolrr7
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2. lfcustody walls were prosent, wern th2y intact and wdjntltien?
H :;trjp IL)= 21-932 _ C.lilorineStrip Q; NA. Tasttd by_7ALF.
Otigina: rempe,ature Upon rebeipt l Dedved (Corrected) terrrperuturo upon m _aeipt %Sf—,lid $nap -Cup ID=
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PM was Notificd by, plione f email ; frme-to-;ace (cireIc ions).
RSA
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4. Is the 00M=.er€sal couri er g packing slip attached to this form?
Yes
No.
5. Nero prcper cLstcdy proct:TWTS 71inquishedij ecei lo4 b11gwcd?
6, VL M Sample IDs I[sled fan dw COC?
d Yes
No
Ve Yes
7- Wum stamplc 1Ds li4'ed on al l sample oantairim?
S. Was Collecdoll dale & Lime lisw { Un the mc" j
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R. Vdas collecdDil. daie & Lime :stud on all rartnle containers'?
0 Yts
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10. 1)id a'J cuTiainer rabal iltforntatian (ID, dale, umc) eve wit,I 1hr. C.00?
Yes
11, Were bests t,3 Mtn performcd listed on the C',OM —
Ll Vo
CS
ONo
I2. Did al ,urE1P1Q3 arrive °n [he Prowl' osmtainers far each tart and/or in geed cona;lit[oil
(tlyhrnkr.;I, lids Oar, etv-)?
t TO
13, �Fk15 adequate sample vo fume available'?
hTa
14. Were a[I SW31Ples rxeived within 3,S the holding tense ar 4E hours, whichever COmca first'?
� No
l Wcrc any sam Ies Containers Missir f}eaM(W (dre[c cii0 sam les Rio# listed {oi C7f7C?
El Yes CNn
16- For VOA and RSK-175 swpla;s, were bubbles prescut >"pea-sixn" (1/410T GJrm
❑RAL m in di
in ary oftho VQAvials"
Yes NG
NIA 17, W4re A t DRClhnelal4.1n-,r7ierr1 stun 1 YS rcxieijrcd at a pr I of ; 2?
LJ Yes; No
_ AlA 18. Were all gart; do samples rwel vW at a p!� 7 12 and sul fldr samp[ex rrLcived 8t a 'aH > 9?
[� Y ❑— o
WNA l.. we*e 31 app ieub:c 1*1H• (I' hjce pan idfVphcrta 2.5-1I6083 (< 0,5m2/L) -;am pies - o
ruidual el' brine?
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ONAZQ ' Were cFe l rcmarksifequeslh {i-c. requested d.i[ulions, hfl$,'NISD degi, ]ati0'I5, etc,,,)
c"rectly 11 arabr:riM Frarn rtite C_OC into Ilia catnMAL scud Dn in 1.1 [SAS;'
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21. %VaS the QUIOLC number li€red on the container If yes, Quoie i
5atnple Prt�cr+'ta#ian ([�f�st lee c:urtrplcted for atsy snrr��rin(s) iiacal'l+e�tly preserved or witf h��d;p�,)
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R barcode ]n1 rls applied by t7�;G L]ata' I U M202 L
Comm cnts:
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 150 of 152

PACE ANALYTICAL SERVICES, LLC
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Page 151 of 152

PACE ANALYTICAL SERVICES, LLC
Sam piles Receipt Checkl lst 1511G) [M E01}18C-151 AeVISed:9 f 29f 202❑
G �• ' l rssu ing Authority; Pace ENV - WCOL Page l of l
Sample Receipt Checklist (SRC)
Client, 01M Guider Ins =ted b •,`date: JM-T r, I I. Ixr I}�l 'i K17o1S
Mva n-1 La f rwL! ipL: PLuc Climt U11's 1' edLx C2h&'.
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(unbrrrk", Ws on. Lta}7
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13. Was adequaw r;Lunpl r volmnc avaiLible?
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Yes
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ENA
19.WeFe all appliLmblL'XW1'KN,`oyamde.'p[Lenoli625.IiblM.; (< 0.5mgrL)samples, free,of
residual chlvrinv.?
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20' Were client m„Hrks,"t�aests (i.e. 1txlurstrd tlilutiom, MS,MSD deFfgnarionw, etc,,,)
eorn,Ldly Ira%ufibc,i from the C:OC intq dt4 oL=ncrrt soctian in ijN4S?
Yesj
Z No
21, Wto th. quotc number lislmd on Lhn-c(mtainer ILtbeP [f Yea, gLu
Snmple Pri ase rvatinn ([ldujL by uomplotcd for airy €ample(fi) inc4rTw dy preserved or w illi liugriSpucc,)
.Smnplc(s) NA wcm received incorrectly }n'csci-ved and were aLljuyL4d tLCLaLdingly
in samplo rccaiving wirb wL ol''c.irv1-u une; H2S0 4, J IN03, [ IC',1, NhOA using SR t 7kA
Time of prwscr'vatiOn NI_. IF more th;Ln one pr-.servative i3 Iheeded, plcasc noto in the cornmenl-�, below.
5ampla(s) P:4 Ware rt3Ceivad 1vlLli b41}blcs -{6 mil AL d[anleLer.
Sarnplcs(j) x^ v eTe received with TRC > 0,5 mg L (if TiL19 is Ro ) and were
jusial =,or&ngly in aample receiving with sodium lhiosulfatc (Na,S,O}) wish Shoal}' 11); NI
SR barcode label. applied b-, i4ilx [)ate -
Corn meniv. { ,,.:F ' C D- V Rp?
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Page 152 of 152

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: Cabarrus County 2021-2022
Project Number: Background
Lot Number:WK18006
Date Completed:12/13/2021
12/27/2021 2:52 AM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�4 aecRFo���A4W-
TNI /
AM Amflvue Acm^rmm Fvu rj
('
4eOfFAi�
ACC R E OI TEO
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 61

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: WK18006
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
VOA 8260D
Reanalysis of sample WK18006-003 (Trip Blank) was performed outside of the analytical holding time for
cis- 1,2-Dichloroethene due to carryover.
BOD
The seed correction factor for sample WK18006-001 (CD-1 s) was above the method range of 0.6 to 1.0.
SCF = 1.6
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
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Page 2 of 61

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: WK18006
Project Name: Cabarrus County 2021-2022
Project Number: Background
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
CD-1s
Aqueous
11/17/20211425
11/18/2021
002
CD-1d
Aqueous
11/17/20211445
11/18/2021
003
Trip Blank
Aqueous
11/17/2021
11/18/2021
(3 samples)
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Page 3 of 61

PACE ANALYTICAL SERVICES, LLC
Detection Summary
CDM Smith
Lot Number: WK18006
Project Name: Cabarrus County 2021-2022
Project Number: Background
Sample Sample ID
Matrix
Parameter Method
Result
Q
Units
Page
001
CD-1s
Aqueous
Alkalinity @ pH 4.5 su SM 232013-
50
mg CaCO3/L
5
001
CD-1s
Aqueous
Chloride 9056A
9400
ug/L
5
001
CD-1s
Aqueous
CO2 (calculation) SM 4500-CO2
150000
ug/L
5
001
CD-1s
Aqueous
Nitrate - N 9056A
320
ug/L
5
001
CD-1s
Aqueous
Sulfate 9056A
1100
ug/L
5
001
CD-1s
Aqueous
TDS SM 2540C-
130000
ug/L
5
001
CD-1s
Aqueous
Barium 6020B
34
ug/L
10
001
CD-1s
Aqueous
Iron 6020B
100
ug/L
10
001
CD-1s
Aqueous
Manganese 6020B
11
ug/L
10
001
CD-1s
Aqueous
Vanadium 6020B
4.0
J
ug/L
10
001
CD-1s
Aqueous
Zinc 6020B
34
ug/L
10
002
CD-1d
Aqueous
Alkalinity @ pH 4.5 su SM 232013-
51
mg CaCO3/L
11
002
CD-1d
Aqueous
Chloride 9056A
3300
ug/L
11
002
CD-1d
Aqueous
Sulfate 9056A
2600
ug/L
11
002
CD-1d
Aqueous
TDS SM 2540C-
110000
ug/L
11
002
CD-1d
Aqueous
Antimony 6020B
1.4
J
ug/L
15
002
CD-1d
Aqueous
Barium 6020B
33
ug/L
15
002
CD-1d
Aqueous
Copper 6020B
2.4
J
ug/L
15
002
CD-1d
Aqueous
Iron 6020B
740
ug/L
15
002
CD-1d
Aqueous
Lead 6020B
0.42
J
ug/L
15
002
CD-1d
Aqueous
Manganese 6020B
32
ug/L
15
002
CD-1d
Aqueous
Nickel 6020B
1.5
J
ug/L
15
002
CD-1d
Aqueous
Vanadium 6020B
6.0
ug/L
15
002
CD-1d
Aqueous
Zinc 6020B
5.8
J
ug/L
15
(24 detections)
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Page 4 of 61

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK18006-001
Description: CD-1s Matrix: Aqueous
Date Sampled:11/17/2021 1425 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(Alkalinity @) SM 2320B-2011
1
11/30/2021 2157 AAB
24111
1
(BOD, 5 day) SM 521OB-2011
1
11/23/2021 2233 GAH
11/18/2021 2354 23023
1
(Chloride) 9056A
1
11/19/2021 0334 AMR
23185
1
(CO2 (calcula) SM 4500-CO2 D
1
11/30/2021 2157 AAB
1
(COD) SM 5220D-2011
1
11/27/2021 2058 DAK
23842
1
(Nitrate - N) 9056A
1
11/19/2021 0334 AMR
23188
1
(Sulfate) 9056A
1
11/19/2021 0334 AMR
23182
1
(Sulfide) SM 4500-S2 F-2011
1
11/23/2021 1541 SJL
23434
1
(TDS) SM 2540C-2011
1
11/23/2021 1845 CVR
23546
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Alkalinity @ pH 4.5 su
SM 2320B-2011
50
20
20
mg CaCO3/L
1
BOD, 5 day
SM 521OB-2011
ND 7
2000
180
ug/L
1
Chloride
9056A
9400
1000
250
ug/L
1
CO2 (calculation)
124-38-9
SM 4500-CO2 D
150000
27000
27000
ug/L
1
COD
SM 5220D-2011
ND
20000
20000
ug/L
1
Nitrate - N
9056A
320
20
5.0
ug/L
1
Sulfate
9056A
1100
1000
250
ug/L
1
Sulfide
18496-25-8
SM 4500-S2 F-2
ND
1000
1000
ug/L
1
TDS
SM 2540C-2011
130000
25000
25000
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-001
Description: CD-1s Matrix: Aqueous
Date Sampled:11/17/2021 1425 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210616 JWO
23570
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
0.50
0.40
ug/L
1
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
1
Toluene
108-88-3
8260D
ND
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
0.50
0.40
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-001
Description: CD-1s Matrix: Aqueous
Date Sampled:11/17/2021 1425 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210616 JWO 23570
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
ND
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
ND
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
ND
1.0
0.40
ug/L
1
Run Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
91 70-130
1,2-Dichloroethane-d4
118 70-130
Toluene-d8
105 70-130
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 61

Dissolved Gases
Client:CDM Smith Laboratory ID:WK18006-001
Description: CD-1s Matrix: Aqueous
Date Sampled:11/17/2021 1425 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/30/2021 1024 TML 24004
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane
Ethene
Methane
74-84-0 RSK - 175 ND 10 2.5 ug/L 1
74-85-1 RSK - 175 ND 10 2.5 ug/L 1
74-82-8 RSK - 175 ND 10 2.5 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 61

CVAA
Client:CDM Smith Laboratory ID:WK18006-001
Description: CD-1s Matrix: Aqueous
Date Sampled:11/17/2021 1425 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/29/2021 2109 CMS2 11/29/2021 1521 23876
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A ND 0.20 0.091 ug/L 1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 61

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK18006-001
Description: CD-1s Matrix: Aqueous
Date Sampled:11/17/2021 1425 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/27/2021 1016 BPK
Prep Date Batch
11/26/2021 0315 23450
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
34
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
ND
5.0
1.3
ug/L
1
Iron
7439-89-6
6020B
100
50
13
ug/L
1
Lead
7439-92-1
6020B
ND
1.0
0.25
ug/L
1
Manganese
7439-96-5
6020B
11
5.0
1.3
ug/L
1
Nickel
7440-02-0
6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.0 J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
34
10
2.5
ug/L
1
Footnote(s): 7-SCF Out of range
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 61

Inorganic non-metals
Client:CDM Smith Laboratory ID:WK18006-002
Description: CD-1d Matrix: Aqueous
Date Sampled:11/17/2021 1445 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
(Alkalinity @) SM 2320B-2011
1
11/30/2021 2209 AAB
24111
1
(Chloride) 9056A
1
11/25/2021 0407 AMR
23910
1
(Sulfate) 9056A
1
11/25/2021 0407 AMR
23908
1
(TDS) SM 2540C-2011
1
11/23/2021 1845 CVR
23546
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Alkalinity @ pH 4.5 su
Chloride
Sulfate
TDS
SM 2320B-2011
51
20
20
mg CaCO3/L 1
9056A
3300
1000
250
ug/L 1
9056A
2600
1000
250
ug/L 1
SM 254OC-2011
110000
25000
25000
ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-002
Description: CD-1d Matrix: Aqueous
Date Sampled:11/17/2021 1445 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210641 JWO
23570
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
0.50
0.40
ug/L
1
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
1
Toluene
108-88-3
8260D
ND
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-002
Description: CD-1d Matrix: Aqueous
Date Sampled:11/17/2021 1445 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210641 JWO 23570
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
ND
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
ND
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
ND
1.0
0.40
ug/L
1
Run Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
91 70-130
1,2-Dichloroethane-d4
118 70-130
Toluene-d8
106 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 61

CVAA
Client:CDM Smith Laboratory ID:WK18006-002
Description: CD-1d Matrix: Aqueous
Date Sampled:11/17/2021 1445 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/29/2021 2112 CMS2 11/29/2021 1521 23876
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A ND 0.20 0.091 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 61

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK18006-002
Description: CD-1d Matrix: Aqueous
Date Sampled:11/17/2021 1445 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/27/2021 1053 BPK
Prep Date Batch
11/26/2021 0315 23450
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
1.4
J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
33
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.4
J
5.0
1.3
ug/L
1
Iron
7439-89-6
6020B
740
50
13
ug/L
1
Lead
7439-92-1
6020B
0.42
J
1.0
0.25
ug/L
1
Manganese
7439-96-5
6020B
32
5.0
1.3
ug/L
1
Nickel
7440-02-0
6020B
1.5
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
6.0
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
5.8
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-003
Description: Trip Blank Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/2021
0323 JWO
23570
2 5030B 8260D
1 12/08/2021 1622 CAW
24944
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
ND
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
ND
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
ND
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
ND
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
ND
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
ND
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
ND
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
ND
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
ND
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
ND
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
ND
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
ND
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
ND
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
ND
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
0.63
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
ND
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
ND
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
ND
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
0.50
0.40
ug/L
1
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
1
Toluene
108-88-3
8260D
ND
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-003
Description: Trip Blank Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/24/2021 0323 JWO
23570
2
5030B
8260D 1
12/08/2021 1622 CAW
24944
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichloroethene
79-01-6
8260D
ND
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
ND
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
ND
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130 H 106 70-130
116 70-130 H 100 70-130
105 70-130 H 109 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-003
Description: Trip Blank Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/2021
0323 JWO
23570
2 5030B 8260D
1 12/08/2021 1622 CAW
24944
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
ND
H
10
4.0
ug/L
2
Acrylonitrile
107-13-1
8260D
ND
H
5.0
0.80
ug/L
2
Benzene
71-43-2
8260D
ND
H
0.50
0.40
ug/L
2
Bromochloromethane
74-97-5
8260D
ND
H
0.50
0.40
ug/L
2
Bromodichloromethane
75-27-4
8260D
ND
H
0.50
0.40
ug/L
2
Bromoform
75-25-2
8260D
ND
H
0.50
0.40
ug/L
2
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
H
0.50
0.40
ug/L
2
2-Butanone (MEK)
78-93-3
8260D
ND
H
10
2.0
ug/L
2
Carbon disulfide
75-15-0
8260D
ND
H
0.50
0.40
ug/L
2
Carbon tetrachloride
56-23-5
8260D
ND
H
0.50
0.40
ug/L
2
Chlorobenzene
108-90-7
8260D
ND
H
0.50
0.40
ug/L
2
Chloroethane
75-00-3
8260D
ND
H
0.50
0.40
ug/L
2
Chloroform
67-66-3
8260D
ND
H
0.50
0.40
ug/L
2
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
H
0.50
0.40
ug/L
2
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
H
0.50
0.40
ug/L
2
Dibromochloromethane
124-48-1
8260D
ND
H
0.50
0.40
ug/L
2
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
H
0.50
0.40
ug/L
2
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
H
0.50
0.40
ug/L
2
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
H
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
ND
H
0.50
0.40
ug/L
2
1,4-Dichlorobenzene
106-46-7
8260D
ND
H
0.50
0.40
ug/L
2
1,1-Dichloroethane
75-34-3
8260D
ND
H
0.50
0.40
ug/L
2
1,2-Dichloroethane
107-06-2
8260D
ND
H
0.50
0.40
ug/L
2
1,1-Dichloroethene
75-35-4
8260D
ND
H
0.50
0.40
ug/L
2
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
H
0.50
0.40
ug/L
2
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
H
0.50
0.40
ug/L
2
1,2-Dichloropropane
78-87-5
8260D
ND
H
0.50
0.40
ug/L
2
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
H
0.50
0.40
ug/L
2
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
H
0.50
0.40
ug/L
2
Ethylbenzene
100-41-4
8260D
ND
H
0.50
0.40
ug/L
2
2-Hexanone
591-78-6
8260D
ND
H
10
2.0
ug/L
2
Methacrylonitrile
126-98-7
8260D
ND
H
5.0
2.0
ug/L
2
Methyl iodide (lodomethane)
74-88-4
8260D
ND
H
5.0
0.40
ug/L
2
4-Methyl-2-pentanone
108-10-1
8260D
ND
H
10
2.0
ug/L
2
Methylene chloride
75-09-2
8260D
ND
H
0.50
0.40
ug/L
2
Styrene
100-42-5
8260D
ND
H
0.50
0.41
ug/L
2
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
H
0.50
0.40
ug/L
2
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
H
0.50
0.40
ug/L
2
Tetrachloroethene
127-18-4
8260D
ND
H
0.50
0.40
ug/L
2
Tetrahydrofuran
109-99-9
8260D
ND
H
5.0
1.0
ug/L
2
Toluene
108-88-3
8260D
ND
H
0.50
0.40
ug/L
2
1,1,1-Trichloroethane
71-55-6
8260D
ND
H
0.50
0.40
ug/L
2
1,1,2-Trichloroethane
79-00-5
8260D
ND
H
0.50
0.40
ug/L
2
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 61

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK18006-003
Description: Trip Blank Matrix: Aqueous
Date Sampled:11/17/2021 Project Name: Cabarrus County 2021-2022
Date Received: 11 /18/2021 Project Number: Background
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/24/2021 0323 JWO
23570
2
5030B
8260D 1
12/08/2021 1622 CAW
24944
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichloroethene
79-01-6
8260D
ND
H
0.50
0.40
ug/L
2
Trichlorofluoromethane
75-69-4
8260D
ND
H
0.50
0.40
ug/L
2
1,2,3-Trichloropropane
96-18-4
8260D
ND
H
0.50
0.40
ug/L
2
Vinyl acetate
108-05-4
8260D
ND
H
5.0
1.2
ug/L
2
Vinyl chloride
75-01-4
8260D
ND
H
0.50
0.40
ug/L
2
Xylenes (total)
1330-20-7
8260D
ND
H
1.0
0.40
ug/L
2
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130 H 106 70-130
116 70-130 H 100 70-130
105 70-130 H 109 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 61

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK18006
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 61

Inorganic non-metals - BOD Blank and GGA
Matrix: Aqueous
Batch: 23023 SCF: 1.6
Analytical Method: SM 521 OB-2011 SCF Range: 0.6 - 1.0
Result Avg. Result
Sample ID
(ug/L) (ug/L)
(ug/L) (rng/L)
Q
Limit
Prep Date
Analysis Date
WQ23023-041 (Blank)
60.0000
0.2
11/18/2021 2300
11/23/2021 2207
WQ23023-141 (Blank)
80.0000
0.2
11/18/2021 2300
11/23/2021 2206
WQ23023-241 (Blank)
130.000(90.0000
0.2
11/18/2021 2300
11/23/2021 2207
WQ23023-035 (GGA)
194500.0000
7
167.5-228.5
11/18/2021 2308
11/23/2021 2211
WQ23023-135 (GGA)
165500.0000
71
167.5-228.5
11/18/2021 2308
11/23/2021 2211
WQ23023-235 (GGA)
153000.00001
71
167.5-228.5
11/18/2021 2308
11/23/2021 2211
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23182-001 Matrix: Aqueous
Batch: 23182
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate ND 1 1000 250 ug/L 11/18/2021 2328
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23182-002 Matrix: Aqueous
Batch: 23182
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Sulfate 20000 21000 1 106 80-120 11/19/2021 0141
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23185-001 Matrix: Aqueous
Batch: 23185
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride ND 1 1000 250 ug/L 11/18/2021 2328
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23185-002 Matrix: Aqueous
Batch: 23185
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Chloride 20000 21000 1 106 80-120 11/19/2021 0141
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23188-001 Matrix: Aqueous
Batch: 23188
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N ND 1 20 5.0 ug/L 11/18/2021 2328
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23188-002 Matrix: Aqueous
Batch: 23188
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 800 840 1 105 80-120 11/19/2021 0141
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23434-001 Matrix: Aqueous
Batch:23434
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide ND 1 1000 1000 ug/L 11/23/2021 1541
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23434-002 Matrix: Aqueous
Batch:23434
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Sulfide 10000 9000 1 90 80-120 11/23/2021 1541
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23546-001 Matrix: Aqueous
Batch: 23546
Analytical Method: SM 2540C-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
TDS ND 1 25000 25000 ug/L 11/23/2021 1845
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23546-002 Matrix: Aqueous
Batch: 23546
Analytical Method: SM 2540C-2011
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
TDS 1500000 1600000 1 107 90-110 11/23/2021 1845
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23842-001 Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
COD ND 1 20000 20000 ug/L 11/27/2021 2052
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23842-002 Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
COD 40000 41000 1 102 95-105 11/27/2021 2053
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MS
Sample ID: WK1 8006-001 MS Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec
Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
COD ND 40000 38000 1 96 90-110 11/27/2021 2058
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MSD
Sample ID: WK18006-001MD Matrix: Aqueous
Batch:23842
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result %Rec % RPD
Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
COD ND 40000 36000 1 90 6.3 90-110 20 11/27/2021 2058
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23908-001 Matrix: Aqueous
Batch: 23908
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate ND 1 1000 250 ug/L 11/24/2021 1858
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23908-002 Matrix: Aqueous
Batch: 23908
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Sulfate 20000 21000 1 103 80-120 11/24/2021 1936
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - MB
Sample ID: WQ23910-001 Matrix: Aqueous
Batch: 23910
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride ND 1 1000 250 ug/L 11/24/2021 1858
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ23910-002 Matrix: Aqueous
Batch: 23910
Analytical Method: 9056A
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Chloride 20000 21000 1 105 80-120 11/24/2021 1936
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - LCS
Sample ID: WQ24111-002 Matrix: Aqueous
Batch:24111
Analytical Method: SM 2320B-2011
Spike
Amount Result %Rec
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % Rec Limit Analysis Date
Alkalinity @ pH 4.5 su 100 100 1 102 90-110 11/30/2021 2122
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 61
QC Data for Lot Number: WK18006

Inorganic non-metals - Duplicate
Sample ID: WK1 8006-001 DU Matrix: Aqueous
Batch:24111
Analytical Method: SM 2320B-2011
Sample
Amount Result %RPD
Parameter (mg CaCO3/L) (mg CaCO3/L) Q Dil % RPD Limit Analysis Date
Alkalinity @ pH 4.5 su 50 50 1 1.1 20 11/30/2021 2204
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 61
QC Data for Lot Number: WK18006

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23570-001 Matrix: Aqueous
Batch: 23570 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
10
4.0
ug/L
11/23/2021 2248
Acrylonitrile
ND
1
5.0
0.80
ug/L
11/23/2021 2248
Benzene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Bromochloromethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Bromodichloromethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Bromoform
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Bromomethane (Methyl bromide)
ND
1
0.50
0.40
ug/L
11/23/2021 2248
2-Butanone (MEK)
ND
1
10
2.0
ug/L
11/23/2021 2248
Carbon disulfide
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Carbon tetrachloride
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Chlorobenzene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Chloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Chloroform
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Chloromethane (Methyl chloride)
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Dibromochloromethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dibromoethane (EDB)
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Dibromomethane (Methylene bromide)
ND
1
0.50
0.40
ug/L
11/23/2021 2248
trans- 1,4-Dichloro-2-butene
ND
1
2.0
0.40
ug/L
11/23/2021 2248
1,2-Dichlorobenzene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,4-Dichlorobenzene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,1-Dichloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dichloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,1-Dichloroethene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
cis- 1,2-Dichloroethene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
trans- 1,2-Dichloroethene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,2-Dichloropropane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
cis- 1,3-Dichloropropene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
trans- 1,3-Dichloropropene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Ethylbenzene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
2-Hexanone
ND
1
10
2.0
ug/L
11/23/2021 2248
Methacrylonitrile
ND
1
5.0
2.0
ug/L
11/23/2021 2248
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
11/23/2021 2248
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
11/23/2021 2248
Methylene chloride
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Styrene
ND
1
0.50
0.41
ug/L
11/23/2021 2248
1,1,1,2-Tetrachloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,1,2,2-Tetrachloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Tetrachloroethene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Tetrahydrofuran
ND
1
5.0
1.0
ug/L
11/23/2021 2248
Toluene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,1,1-Trichloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,1,2-Trichloroethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Trichloroethene
ND
1
0.50
0.40
ug/L
11/23/2021 2248
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 61
QC Data for Lot Number: WK18006

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23570-001 Matrix: Aqueous
Batch:23570 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q Dil
LOQ
DL
Units
Analysis Date
Trichlorofluoromethane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
1,2,3-Trichloropropane
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Vinyl acetate
ND
1
5.0
1.2
ug/L
11/23/2021 2248
Vinyl chloride
ND
1
0.50
0.40
ug/L
11/23/2021 2248
Xylenes (total)
ND
1
1.0
0.40
ug/L
11/23/2021 2248
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 90 70-130
1,2-Dichloroethane-d4 115 70-130
Toluene-d8 103 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK18006
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 61

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23570-002 Matrix: Aqueous
Batch: 23570 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
140
1
139
60-140
11/23/2021 2055
Acrylonitrile
100
130
1
129
70-130
11/23/2021 2055
Benzene
50
51
1
101
70-130
11/23/2021 2055
Bromochloromethane
50
51
1
103
70-130
11/23/2021 2055
Bromodichloromethane
50
45
1
90
70-130
11/23/2021 2055
Bromoform
50
39
1
78
70-130
11/23/2021 2055
Bromomethane (Methyl bromide)
50
52
1
104
70-130
11/23/2021 2055
2-Butanone (MEK)
100
120
1
120
70-130
11/23/2021 2055
Carbon disulfide
50
55
1
111
70-130
11/23/2021 2055
Carbon tetrachloride
50
48
1
96
70-130
11/23/2021 2055
Chlorobenzene
50
46
1
92
70-130
11/23/2021 2055
Chloroethane
50
57
1
114
70-130
11/23/2021 2055
Chloroform
50
52
1
103
70-130
11/23/2021 2055
Chloromethane (Methyl chloride)
50
53
1
105
60-140
11/23/2021 2055
1,2-Dibromo-3-chloropropane (DBCP)
50
42
1
84
70-130
11/23/2021 2055
Dibromochloromethane
50
42
1
83
70-130
11/23/2021 2055
1,2-Dibromoethane (EDB)
50
44
1
88
70-130
11/23/2021 2055
Dibromomethane (Methylene bromide)
50
48
1
96
70-130
11/23/2021 2055
trans- 1,4-Dichloro-2-butene
50
41
1
82
70-130
11/23/2021 2055
1,2-Dichlorobenzene
50
46
1
92
70-130
11/23/2021 2055
1,4-Dichlorobenzene
50
45
1
91
70-130
11/23/2021 2055
1,1-Dichloroethane
50
55
1
110
70-130
11/23/2021 2055
1,2-Dichloroethane
50
46
1
93
70-130
11/23/2021 2055
1,1-Dichloroethene
50
55
1
110
70-130
11/23/2021 2055
cis- 1,2-Dichloroethene
50
53
1
105
70-130
11/23/2021 2055
trans- 1,2-Dichloroethene
50
51
1
102
70-130
11/23/2021 2055
1,2-Dichloropropane
50
50
1
99
70-130
11/23/2021 2055
cis- 1,3-Dichloropropene
50
47
1
94
70-130
11/23/2021 2055
trans- 1,3-Dichloropropene
50
45
1
90
70-130
11/23/2021 2055
Ethylbenzene
50
45
1
91
70-130
11/23/2021 2055
2-Hexanone
100
98
1
98
70-130
11/23/2021 2055
Methacrylonitrile
250
290
1
114
70-130
11/23/2021 2055
Methyl iodide (lodomethane)
50
52
1
104
70-130
11/23/2021 2055
4-Methyl-2-pentanone
100
96
1
96
70-130
11/23/2021 2055
Methylene chloride
50
60
1
120
70-130
11/23/2021 2055
Styrene
50
45
1
90
70-130
11/23/2021 2055
1,1,1,2-Tetrachloroethane
50
44
1
88
70-130
11/23/2021 2055
1,1,2,2-Tetrachloroethane
50
48
1
97
70-130
11/23/2021 2055
Tetrachloroethene
50
44
1
88
70-130
11/23/2021 2055
Tetrahydrofuran
50
55
1
111
70-130
11/23/2021 2055
Toluene
50
47
1
93
70-130
11/23/2021 2055
1,1,1-Trichloroethane
50
49
1
98
70-130
11/23/2021 2055
1,1,2-Trichloroethane
50
45
1
90
70-130
11/23/2021 2055
Trichloroethene
50
45
1
90
70-130
11/23/2021 2055
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 61
QC Data for Lot Number: WK18006

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23570-002
Matrix: Aqueous
Batch:23570
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
Trichlorofluoromethane
50
50
1
100
70-130
11/23/2021 2055
1,2,3-Trichloropropane
50
45
1
91
70-130
11/23/2021 2055
Vinyl acetate
50
49
1
98
60-140
11/23/2021 2055
Vinyl chloride
50
53
1
106
70-130
11/23/2021 2055
Xylenes (total)
100
91
1
91
70-130
11/23/2021 2055
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 90 70-130
1,2-Dichloroethane-d4 99 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK18006
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 61

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ24944-001 Matrix: Aqueous
Batch: 24944 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
10
4.0
ug/L
12/08/2021 1105
Acrylonitrile
ND
1
5.0
0.80
ug/L
12/08/2021 1105
Benzene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Bromochloromethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Bromodichloromethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Bromoform
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Bromomethane (Methyl bromide)
ND
1
0.50
0.40
ug/L
12/08/2021 1105
2-Butanone (MEK)
ND
1
10
2.0
ug/L
12/08/2021 1105
Carbon disulfide
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Carbon tetrachloride
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Chlorobenzene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Chloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Chloroform
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Chloromethane (Methyl chloride)
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Dibromochloromethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,2-Dibromoethane (EDB)
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Dibromomethane (Methylene bromide)
ND
1
0.50
0.40
ug/L
12/08/2021 1105
trans- 1,4-Dichloro-2-butene
ND
1
2.0
0.40
ug/L
12/08/2021 1105
1,2-Dichlorobenzene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,4-Dichlorobenzene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,1-Dichloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,2-Dichloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,1-Dichloroethene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
cis- 1,2-Dichloroethene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
trans- 1,2-Dichloroethene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,2-Dichloropropane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
cis- 1,3-Dichloropropene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
trans- 1,3-Dichloropropene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Ethylbenzene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
2-Hexanone
ND
1
10
2.0
ug/L
12/08/2021 1105
Methacrylonitrile
ND
1
5.0
2.0
ug/L
12/08/2021 1105
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
12/08/2021 1105
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
12/08/2021 1105
Methylene chloride
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Styrene
ND
1
0.50
0.41
ug/L
12/08/2021 1105
1,1,1,2-Tetrachloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,1,2,2-Tetrachloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Tetrachloroethene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Tetrahydrofuran
ND
1
5.0
1.0
ug/L
12/08/2021 1105
Toluene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,1,1-Trichloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,1,2-Trichloroethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Trichloroethene
ND
1
0.50
0.40
ug/L
12/08/2021 1105
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 61
QC Data for Lot Number: WK18006

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ24944-001 Matrix: Aqueous
Batch:24944 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q Dil
LOQ
DL
Units
Analysis Date
Trichlorofluoromethane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
1,2,3-Trichloropropane
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Vinyl acetate
ND
1
5.0
1.2
ug/L
12/08/2021 1105
Vinyl chloride
ND
1
0.50
0.40
ug/L
12/08/2021 1105
Xylenes (total)
ND
1
1.0
0.40
ug/L
12/08/2021 1105
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 106 70-130
1,2-Dichloroethane-d4 101 70-130
Toluene-d8 106 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK18006
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 61

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ24944-002 Matrix: Aqueous
Batch: 24944 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
130
1
134
60-140
12/08/2021 1002
Acrylonitrile
100
100
1
101
70-130
12/08/2021 1002
Benzene
50
47
1
94
70-130
12/08/2021 1002
Bromochloromethane
50
46
1
93
70-130
12/08/2021 1002
Bromodichloromethane
50
47
1
94
70-130
12/08/2021 1002
Bromoform
50
51
1
102
70-130
12/08/2021 1002
Bromomethane (Methyl bromide)
50
46
1
93
70-130
12/08/2021 1002
2-Butanone (MEK)
100
99
1
99
70-130
12/08/2021 1002
Carbon disulfide
50
43
1
86
70-130
12/08/2021 1002
Carbon tetrachloride
50
46
1
92
70-130
12/08/2021 1002
Chlorobenzene
50
47
1
95
70-130
12/08/2021 1002
Chloroethane
50
43
1
86
70-130
12/08/2021 1002
Chloroform
50
44
1
88
70-130
12/08/2021 1002
Chloromethane (Methyl chloride)
50
45
1
90
60-140
12/08/2021 1002
1,2-Dibromo-3-chloropropane (DBCP)
50
50
1
101
70-130
12/08/2021 1002
Dibromochloromethane
50
50
1
99
70-130
12/08/2021 1002
1,2-Dibromoethane (EDB)
50
50
1
99
70-130
12/08/2021 1002
Dibromomethane (Methylene bromide)
50
46
1
93
70-130
12/08/2021 1002
trans- 1,4-Dichloro-2-butene
50
44
1
88
70-130
12/08/2021 1002
1,2-Dichlorobenzene
50
48
1
97
70-130
12/08/2021 1002
1,4-Dichlorobenzene
50
46
1
92
70-130
12/08/2021 1002
1,1-Dichloroethane
50
44
1
88
70-130
12/08/2021 1002
1,2-Dichloroethane
50
46
1
91
70-130
12/08/2021 1002
1,1-Dichloroethene
50
43
1
85
70-130
12/08/2021 1002
cis- 1,2-Dichloroethene
50
45
1
91
70-130
12/08/2021 1002
trans- 1,2-Dichloroethene
50
44
1
88
70-130
12/08/2021 1002
1,2-Dichloropropane
50
45
1
90
70-130
12/08/2021 1002
cis- 1,3-Dichloropropene
50
50
1
99
70-130
12/08/2021 1002
trans- 1,3-Dichloropropene
50
51
1
103
70-130
12/08/2021 1002
Ethylbenzene
50
50
1
100
70-130
12/08/2021 1002
2-Hexanone
100
95
1
95
70-130
12/08/2021 1002
Methacrylonitrile
250
240
1
95
70-130
12/08/2021 1002
Methyl iodide (lodomethane)
50
44
1
87
70-130
12/08/2021 1002
4-Methyl-2-pentanone
100
97
1
97
70-130
12/08/2021 1002
Methylene chloride
50
42
1
84
70-130
12/08/2021 1002
Styrene
50
52
1
105
70-130
12/08/2021 1002
1,1,1,2-Tetrachloroethane
50
50
1
100
70-130
12/08/2021 1002
1,1,2,2-Tetrachloroethane
50
47
1
95
70-130
12/08/2021 1002
Tetrachloroethene
50
49
1
99
70-130
12/08/2021 1002
Tetrahydrofuran
50
43
1
86
70-130
12/08/2021 1002
Toluene
50
49
1
98
70-130
12/08/2021 1002
1,1,1-Trichloroethane
50
45
1
89
70-130
12/08/2021 1002
1,1,2-Trichloroethane
50
47
1
94
70-130
12/08/2021 1002
Trichloroethene
50
47
1
94
70-130
12/08/2021 1002
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 61
QC Data for Lot Number: WK18006

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ24944-002
Matrix: Aqueous
Batch:24944
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
Trichlorofluoromethane
50
42
1
85
70-130
12/08/2021 1002
1,2,3-Trichloropropane
50
49
1
99
70-130
12/08/2021 1002
Vinyl acetate
50
52
1
105
60-140
12/08/2021 1002
Vinyl chloride
50
46
1
92
70-130
12/08/2021 1002
Xylenes (total)
100
100
1
101
70-130
12/08/2021 1002
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 92 70-130
1,2-Dichloroethane-d4 85 70-130
Toluene-d8 90 70-130
LOQ = Limit of Quantitation ND = Not detected at or above the DL N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK18006
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 61

Dissolved Gases - MB
Sample ID: WQ24004-001 Matrix: Aqueous
Batch:24004
Analytical Method: RSK - 175
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Ethane
ND
1
10
2.5
ug/L
11/30/2021 0859
Ethene
ND
1
10
2.5
ug/L
11/30/2021 0859
Methane
ND
1
10
2.5
ug/L
11/30/2021 0859
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 61
QC Data for Lot Number: WK18006

Dissolved Gases - LCS
Sample ID: WQ24004-002 Matrix: Aqueous
Batch:24004
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Ethane
280
310
1
108
70-130
11/30/2021 0826
Ethene
260
270
1
103
70-130
11/30/2021 0826
Methane
150
160
1
109
70-130
11/30/2021 0826
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 61
QC Data for Lot Number: WK18006

Dissolved Gases - LCSD
Sample ID: WQ24004-003 Matrix: Aqueous
Batch:24004
Analytical Method: RSK - 175
Spike
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
% RPD
Limit
Limit
Analysis Date
Ethane
280
300
1 107
1.3
70-130
30
11/30/2021 0836
Ethene
260
270
1 102
0.87
70-130
30
11/30/2021 0836
Methane
150
160
1 107
1.5
70-130
30
11/30/2021 0836
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 61
QC Data for Lot Number: WK18006

ICP-MS Metals - MB
Sample ID: WQ23450-001 Matrix: Aqueous
Batch: 23450 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/26/2021 0315
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
ND
1
2.0
0.50
ug/L
11/27/2021 1002
Arsenic
ND
1
2.0
1.3
ug/L
11/27/2021 1002
Barium
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Beryllium
ND
1
0.40
0.15
ug/L
11/27/2021 1002
Cadmium
ND
1
0.50
0.13
ug/L
11/27/2021 1002
Chromium
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Cobalt
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Copper
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Iron
ND
1
50
13
ug/L
11/27/2021 1002
Lead
ND
1
1.0
0.25
ug/L
11/27/2021 1002
Manganese
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Nickel
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Selenium
ND
1
5.0
1.3
ug/L
11/27/2021 1002
Silver
ND
1
1.0
0.25
ug/L
11/27/2021 1002
Thallium
ND
1
0.50
0.15
ug/L
11/27/2021 1002
Vanadium
ND
1
5.0
2.5
ug/L
11/27/2021 1002
Zinc
ND
1
10
2.5
ug/L
11/27/2021 1002
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 61
QC Data for Lot Number: WK18006

ICP-MS Metals - LCS
Sample ID: WQ23450-002 Matrix: Aqueous
Batch: 23450 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/26/2021 0315
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
93
1
93
80-120
11/27/2021 1009
Arsenic
100
100
1
100
80-120
11/27/2021 1009
Barium
100
97
1
97
80-120
11/27/2021 1009
Beryllium
100
99
1
99
80-120
11/27/2021 1009
Cadmium
100
96
1
96
80-120
11/27/2021 1009
Chromium
100
100
1
104
80-120
11/27/2021 1009
Cobalt
100
110
1
110
80-120
11/27/2021 1009
Copper
100
100
1
104
80-120
11/27/2021 1009
Iron
1000
1100
1
109
80-120
11/27/2021 1009
Lead
100
110
1
106
80-120
11/27/2021 1009
Manganese
100
100
1
104
80-120
11/27/2021 1009
Nickel
100
110
1
110
80-120
11/27/2021 1009
Selenium
100
85
1
85
80-120
11/27/2021 1009
Silver
100
100
1
100
80-120
11/27/2021 1009
Thallium
100
110
1
105
80-120
11/27/2021 1009
Vanadium
100
100
1
103
80-120
11/27/2021 1009
Zinc
100
90
1
90
80-120
11/27/2021 1009
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 61
QC Data for Lot Number: WK18006

ICP-MS Metals - MS
Sample ID: WK1 8006-001 MS
Matrix: Aqueous
Batch: 23450
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
11/26/2021
0315
Sample
Spike
Amount
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Antimony
ND
100
95
1
95
75-125
11/27/2021 1024
Arsenic
ND
100
100
1
102
75-125
11/27/2021 1024
Barium
34
100
130
1
96
75-125
11/27/2021 1024
Beryllium
ND
100
100
1
104
75-125
11/27/2021 1024
Cadmium
ND
100
99
1
99
75-125
11/27/2021 1024
Chromium
ND
100
100
1
102
75-125
11/27/2021 1024
Cobalt
ND
100
110
1
107
75-125
11/27/2021 1024
Copper
ND
100
110
1
105
75-125
11/27/2021 1024
Iron
100
1000
1200
1
106
75-125
11/27/2021 1024
Lead
ND
100
100
1
102
75-125
11/27/2021 1024
Manganese
11
100
110
1
101
75-125
11/27/2021 1024
Nickel
ND
100
110
1
107
75-125
11/27/2021 1024
Selenium
ND
100
93
1
93
75-125
11/27/2021 1024
Silver
ND
100
98
1
98
75-125
11/27/2021 1024
Thallium
ND
100
100
1
101
75-125
11/27/2021 1024
Vanadium
4.0
100
110
1
102
75-125
11/27/2021 1024
Zinc
34
100
130
1
97
75-125
11/27/2021 1024
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 55 of 61
QC Data for Lot Number: WK18006

ICP-MS Metals - MSD
Sample ID: WK18006-001MID
Matrix: Aqueous
Batch: 23450
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
11/26/2021 0315
Sample
Spike
Amount
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec % RPD
Limit
Limit
Analysis Date
Antimony
ND
100
96
1
96
0.28
75-125
20
11/27/2021 1031
Arsenic
ND
100
100
1
103
0.83
75-125
20
11/27/2021 1031
Barium
34
100
130
1
98
1.9
75-125
20
11/27/2021 1031
Beryllium
ND
100
110
1
105
1.4
75-125
20
11/27/2021 1031
Cadmium
ND
100
99
1
99
0.80
75-125
20
11/27/2021 1031
Chromium
ND
100
100
1
103
1.0
75-125
20
11/27/2021 1031
Cobalt
ND
100
110
1
109
1.2
75-125
20
11/27/2021 1031
Copper
ND
100
100
1
105
0.55
75-125
20
11/27/2021 1031
Iron
100
1000
1200
1
108
1.6
75-125
20
11/27/2021 1031
Lead
ND
100
100
1
104
1.4
75-125
20
11/27/2021 1031
Manganese
11
100
110
1
101
0.38
75-125
20
11/27/2021 1031
Nickel
ND
100
110
1
108
0.40
75-125
20
11/27/2021 1031
Selenium
ND
100
93
1
93
0.15
75-125
20
11/27/2021 1031
Silver
ND
100
99
1
99
0.85
75-125
20
11/27/2021 1031
Thallium
ND
100
100
1
103
2.7
75-125
20
11/27/2021 1031
Vanadium
4.0
100
110
1
102
0.71
75-125
20
11/27/2021 1031
Zinc
34
100
130
1
97
0.30
75-125
20
11/27/2021 1031
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 61
QC Data for Lot Number: WK18006

CVAA -MB
Sample ID: WQ23876-001 Matrix: Aqueous
Batch:23876 Prep Method:
Analytical Method: 7470A Prep Date: 11/29/2021 1521
Parameter Result Q Dil LOQ DL Units Analysis Date
Mercury ND 1 0.20 0.091 ug/L 11/29/2021 2016
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 57 of 61
QC Data for Lot Number: WK18006

CVAA - LCS
Sample ID: WQ23876-002 Matrix: Aqueous
Batch:23876 Prep Method:
Analytical Method: 7470A Prep Date: 11/29/2021 1521
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Mercury 2.0 1.9 1 94 80-120 11/29/2021 2018
LOQ = Limit of Quantitation
DL = Detection Limit
ND = Not detected at or above the DL
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 58 of 61
QC Data for Lot Number: WK18006

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 59 of 61

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 60 of 61

PACE ANALYTICAL SERVICES, LLC
5w"iles Receipt Checklist ISRC) (MEGOLI5[ :mj P.ev1sed:9;291-020
IssuingAuthority: Pate LNV- WOOL Rage L of 1
Sample receipt Cheeklist (SRC)
Client= CrjNt $1pftli CDVICr itlmPUL;W i byJchllc: a� z I i I+tRanzl mot #. WK130D6
Means al raccipl= d E'cc Clietrt 17 4.1a5 PedGx O[aor; — — -
Yes
NoI
] - W urc tatstt d) seal., prrxnl. i Hn the r:Dolee'
Yes
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J DNA
'2- T f' wT- w.nim present, wei-e th . I ntcct omd u i i brok -n''
j[T Strip ID: 21,052 Ularine Sir-l} ID: NA 'Peened by rui,7
06411a' 1Crnr&.ra14tr4 IIP091 receipt,' Derived (Ctxrreutcri) uainperuwN tlpan rtiGeipt %Snlid Snap-CALp [ID: --
:0 j3.6 cC NA )NA AC 1IA f NA oC, NA /NA vC
M abod: MT fflpeMli�rt Blbrk QkEainst Elaattcs IR Own ID; ' IROun Cunwtiun Factor: 6 °C:
Method of coolant: ❑ 1Wat kv. Cl [cc lurks ❑ Dry IceLj Nnne
Q Yes
No
❑NA
3, If temperature of 8iy taolc.I• oxceaeded 6.OaT=, WaS llh*Ct L1�n r Notificd'f
lrhl was hntified by, phoneiemail f face-ro-face(cilrle onc).
+' ': CB
No
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4, 13 the commercial courier's backing blip arMcLied io tllis '-cn-jo?
,f Yes
ND
i. Wnm lvopercustody I]rD--edu-tN (m]iru,luhh<Afrcc:ived) fal[owed?
1", es
ND
6, cm sample Ills Iiu2d an the COC?
Ym
Nu
7, Wcro sampie IDSs listed orr all surr[plo cimIHinorR
,f Yt%. Hq
8, W&; collw6on dare & little ]{sod on thn COC?
❑ des
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9, RYAS collockon date & time iistad Dn a]I sampie nontai Icrs' _
1CI. Did all Crntainrl- lFibel'.rformatlon (ID, {laic, agrre With the COC?
1 I- Were lrs4s -,u be pt formed listed on the QOC?
Yes
❑ No
J Ye}
Na
❑*� Yc3
❑ Na
11 Did alJ sampi&a arKvt In thtc proper mitailler; for rf,+.I[ [L; t 1rnL4'rr in good coud'tion
(unbrokrrn, lids on,
I3. Was Adequate tarnpl= w31[[me available?
'❑ YC.31
Ll No
_
'ems
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14, Wei: all Wm pica rcccivcd with in'A the wmIdingtimo w49hours, whichevero[uiies lir:0
Yes
Ld No
JS, Wc:eany salnp:ea Container; missiLieexcess{Cilete one) seunplus N[rt lister an COC7
16, For VOA and )ASK--75 88rn].let wurr bubb.Vs pres+enI >'pea size, (K"or 6min In ilarnAcr)
ut ally orthw VOA vials?
[Yes
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❑NA
Ryy�r`�`:
No
J=No
NAt
]7, %V,.m all DRO?rneMiVntrtricat samples irceived at n H al;< 27
! NA I
I S. W.-re all cy, nidr Samples recei v.d at a 13R > 12 r,nd sui l'ide. Efal . Ins re--eived ai a pH > 9?
19- Vkrareall rY rlicahk1 Nl-i3ril�NiiyarudelpherblL'625,II606,3 <- ,Srt ) sar[iples free pf
vezid a1 dtlorine7
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20. Wr... client l'crrtarLvTNuaetr (f.e- reg-jestod tiiluIms, M� IW D a tgiaL)nx
wrrcatly traiseribed Wara the COC Into the comment Sect:kr.I in ENS?
2 1 - l k w the quote, numbsr listed on the costa=nor lahcl? Tf yvr,, c74latc 8
�"s
No
-Sample Preservaiien (Must bc cmnpleted for any sa ple(s} ircornectly pr€ 1^red ar t�til}4 hcadspn�c,}
3enrple(s) "A _ were rc=ivcd ilioorraaly prc%en d and were adjuste3
ill sar+pio raGaivi ng with u mL of circle om 1`12304, HNQ3, HCI, NaOl I using SR # NA
Timo of presavatioul hA if more (ban one preservativa is r.eerlerr, pEcme note in the minmeels below.
ISample(&) NA - wereroc,eivcd with bubbles>6 mat in diamcicr.
—
SArnpj(DS(S) NA _ were r elycd Mth 'iRC: > G.S mtJ, (IC 919 is N[+) aitd vw'ere
jusmd sscardingly =ri bamplo rcociviiig with sod iwil IhlomulratL: (NstaA eyfva
R bmc[rdr laUtils aWlted by. ,I I# 32 Dam. I trl8+'ml.
colllitle[515;
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 61 of 61

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: Cabarrus County 2021-2022
Project Number: Unit 2
Lot Number:WK19034
Date Completed:12/09/2021
12/30/2021 10:24 PM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�4 aecRFo���A16
TNI /
AM Amflvue Acm^rmm Fvu rj
('
4eOfFAi�
ACC R E OI TEO
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 62

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: WK19034
Report Revision 12/30/2021:
Per client request, this report has been revised to combine the 2 analytical runs for VOA samples
WK19034-002 (MW-G), WK19034-005 (MW-D), and WK19034-007 (MW-C). Only Chloroethane has
been reported from Run 2. All other sample results are as reported in the original PDF report.
This report supersedes and replaces any prior reports issued under this lot number.
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
VOA 8260D
The laboratory control sample (LCS) for analytical batch 23569 exceeded acceptance criteria for the
following analytes: Acetone 2-Butanone and 2-Hexanone. These analytes were biased high and were not
detected in the associated sample: WK19034-011 (CD4 Rep).
Trans 1, 4-Dichloro-2-butene fails read back associated with the calibration (ICAL) of the instrument used
in this sequence. The compound passes using linear fit, but the read back fails extremely high at 343%
drift. Since the compound is detected in the LOQ associated with this sequence and samples are non -
detect for analyte, the data has been reported for the following sample: WK19034-011 (CD4 Rep)
The laboratory control sample (LCS) for analytical batch 23728 exceeded acceptance criteria for the
following analytes: Acetone and acrylonitrile. These analytes were biased high and were not detected in
the associated samples: WK19034-001 (MW-1), WK19034-002 (MW-G), WK19034-003 (MW-B),
WK19034-004 (MW-F) , WK19034-005 (MW-D), WK19034-006 (MW-K), WK19034-007 (MW-C),
WK19034-008 (MW-J), WK19034-009 (MW-X), and WK19034-010 (EQ-BLANK-2).
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 2 of 62

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Reanalysis of the following samples was performed outside of the analytical holding time: WK19034-002
(MW-G), WK19034-005 (MW-D), and WK19034-007 (MW-C). The samples needed reanalysis for
Chloroethane due to high CCV failure associated with run 1.
Metals 6020B
The method blank associated with batch 23456 had Copper detected at a concentration that was above
the DL but below half the LOQ. All samples associated with this method blank that have detections for
Copper have been flagged with a "B".
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 3 of 62

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: WK19034
Project Name: Cabarrus County 2021-2022
Project Number: Unit 2
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-1
Aqueous
11/18/20210830
11/19/2021
002
MW-G
Aqueous
11/18/20210845
11/19/2021
003
MW-B
Aqueous
11/18/20210900
11/19/2021
004
MW-F
Aqueous
11/18/20210930
11/19/2021
005
MW-D
Aqueous
11/18/20210950
11/19/2021
006
MW-K
Aqueous
11/18/20211005
11/19/2021
007
MW-C
Aqueous
11/18/20211020
11/19/2021
008
MW-J
Aqueous
11/18/20211040
11/19/2021
009
MW-X
Aqueous
11/18/20211055
11/19/2021
010
EQ-BLANK-2
Aqueous
11/18/20211520
11/19/2021
011
CD4 Rep
Aqueous
11/17/2021 1510
11/19/2021
(11 samples)
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 62

PACE ANALYTICAL SERVICES, LLC
Detection Summary
CDM Smith
Lot Number: WK19034
Project Name: Cabarrus County 2021-2022
Project Number: Unit 2
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
001
MW-1
Aqueous
1,1-Dichloroethane
8260D
2.9
ug/L
7
001
MW-1
Aqueous
cis- 1,2-Dichloroethene
8260D
1.1
ug/L
7
001
MW-1
Aqueous
Trichloroethene
8260D
0.45
J
ug/L
7
001
MW-1
Aqueous
1,4-Dioxane
8260D (SIM)
59
ug/L
9
001
MW-1
Aqueous
Barium
6020B
100
ug/L
10
001
MW-1
Aqueous
Cadmium
6020B
0.16
J
ug/L
10
001
MW-1
Aqueous
Cobalt
6020B
7.4
ug/L
10
001
MW-1
Aqueous
Copper
6020B
2.9
BJ
ug/L
10
001
MW-1
Aqueous
Lead
6020B
0.93
J
ug/L
10
001
MW-1
Aqueous
Nickel
6020B
25
ug/L
10
001
MW-1
Aqueous
Selenium
6020B
3.9
J
ug/L
10
002
MW-G
Aqueous
Benzene
8260D
0.61
ug/L
11
002
MW-G
Aqueous
Chlorobenzene
8260D
4.0
ug/L
11
002
MW-G
Aqueous
Chloroethane
8260D
0.88
H
ug/L
11
002
MW-G
Aqueous
1,4-Dichlorobenzene
8260D
2.5
ug/L
11
002
MW-G
Aqueous
1,1-Dichloroethane
8260D
1.9
ug/L
11
002
MW-G
Aqueous
1,2-Dichloropropane
8260D
0.46
J
ug/L
11
002
MW-G
Aqueous
Vinyl chloride
8260D
0.58
ug/L
12
002
MW-G
Aqueous
1,4-Dioxane
8260D (SIM)
120
ug/L
13
002
MW-G
Aqueous
Arsenic
6020B
5.3
ug/L
14
002
MW-G
Aqueous
Barium
6020B
320
D
ug/L
14
002
MW-G
Aqueous
Cobalt
6020B
18
ug/L
14
002
MW-G
Aqueous
Nickel
6020B
26
ug/L
14
002
MW-G
Aqueous
Selenium
6020B
17
ug/L
14
003
MW-B
Aqueous
1,4-Dioxane
8260D (SIM)
19
ug/L
17
003
MW-B
Aqueous
Barium
6020B
150
ug/L
18
003
MW-B
Aqueous
Cobalt
6020B
8.2
ug/L
18
003
MW-B
Aqueous
Nickel
6020B
4.4
J
ug/L
18
004
MW-F
Aqueous
1,4-Dioxane
8260D (SIM)
29
ug/L
21
004
MW-F
Aqueous
Barium
6020B
240
ug/L
22
004
MW-F
Aqueous
Cobalt
6020B
2.0
J
ug/L
22
004
MW-F
Aqueous
Nickel
6020B
12
ug/L
22
004
MW-F
Aqueous
Selenium
6020B
1.5
J
ug/L
22
005
MW-D
Aqueous
Benzene
8260D
4.2
ug/L
23
005
MW-D
Aqueous
Chlorobenzene
8260D
0.69
ug/L
23
005
MW-D
Aqueous
Chloroethane
8260D
0.46
HJ
ug/L
23
005
MW-D
Aqueous
1,4-Dichlorobenzene
8260D
3.8
ug/L
23
005
MW-D
Aqueous
cis- 1,2-Dichloroethene
8260D
7.4
ug/L
23
005
MW-D
Aqueous
Trichloroethene
8260D
0.67
ug/L
23
005
MW-D
Aqueous
Vinyl chloride
8260D
1.8
ug/L
24
005
MW-D
Aqueous
Arsenic
6020B
1.6
J
ug/L
25
005
MW-D
Aqueous
Barium
6020B
280
ug/L
25
005
MW-D
Aqueous
Cobalt
6020B
17
ug/L
25
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 62

Detection Summary (Continued)
Lot Number: WK19034
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
005
MW-D
Aqueous
Nickel
6020B
32
ug/L
25
006
MW-K
Aqueous
Barium
6020B
41
ug/L
28
006
MW-K
Aqueous
Nickel
6020B
2.2
J
ug/L
28
006
MW-K
Aqueous
Vanadium
6020B
4.1
J
ug/L
28
007
MW-C
Aqueous
Benzene
8260D
0.60
ug/L
29
007
MW-C
Aqueous
Chlorobenzene
8260D
0.45
J
ug/L
29
007
MW-C
Aqueous
Chloroethane
8260D
0.72
H
ug/L
29
007
MW-C
Aqueous
1,4-Dichlorobenzene
8260D
2.5
ug/L
29
007
MW-C
Aqueous
1,1-Dichloroethane
8260D
2.9
ug/L
29
007
MW-C
Aqueous
cis- 1,2-Dichloroethene
8260D
13
ug/L
29
007
MW-C
Aqueous
Vinyl chloride
8260D
2.2
ug/L
30
007
MW-C
Aqueous
Barium
6020B
58
ug/L
31
007
MW-C
Aqueous
Cobalt
6020B
9.7
ug/L
31
007
MW-C
Aqueous
Nickel
6020B
6.8
ug/L
31
008
MW-J
Aqueous
Barium
6020B
16
ug/L
34
008
MW-J
Aqueous
Zinc
6020B
2.5
J
ug/L
34
009
MW-X
Aqueous
Antimony
6020B
2.9
ug/L
38
009
MW-X
Aqueous
Barium
6020B
29
ug/L
38
009
MW-X
Aqueous
Copper
6020B
1.6
BJ
ug/L
38
009
MW-X
Aqueous
Lead
6020B
0.56
J
ug/L
38
009
MW-X
Aqueous
Nickel
6020B
2.9
J
ug/L
38
009
MW-X
Aqueous
Zinc
6020B
3.5
J
ug/L
38
010
EQ-BLANK-2
Aqueous
Chromium
6020B
2.1
J
ug/L
41
010
EQ-BLANK-2
Aqueous
Copper
6020B
7.0
B
ug/L
41
011
CD4 Rep
Aqueous
1,1-Dichloroethane
8260D
2.1
ug/L
42
011
CD4 Rep
Aqueous
Barium
6020B
66
ug/L
44
011
CD4 Rep
Aqueous
Beryllium
6020B
0.28
J
ug/L
44
011
CD4 Rep
Aqueous
Cobalt
6020B
6.0
ug/L
44
011
CD4 Rep
Aqueous
Copper
6020B
1.4
BJ
ug/L
44
011
CD4 Rep
Aqueous
Lead
6020B
0.61
J
ug/L
44
011
CD4 Rep
Aqueous
Nickel
6020B
4.4
J
ug/L
44
011
CD4 Rep
Aqueous
Vanadium
6020B
11
ug/L
44
011
CD4 Rep
Aqueous
Zinc
6020B
3.2
J
ug/L
44
(76 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-001
Description: MW-1 Matrix: Aqueous
Date Sampled:11/18/2021 0830 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/20210110 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
2.9
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
1.1
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.45
J
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-001
Description: MW-1 Matrix: Aqueous
Date Sampled:11/18/2021 0830 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/20210110 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130
118 70-130
104 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 8 of 62

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK19034-001
Description: MW-1 Matrix: Aqueous
Date Sampled:11/18/2021 0830 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/24/2021 1953 CAW 23671
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 59 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-001
Description: MW-1 Matrix: Aqueous
Date Sampled:11/18/2021 0830 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0434 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
100
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.16
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
7.4
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.9
BJ
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.93
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
25
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
3.9
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-002
Description: MW-G Matrix: Aqueous
Date Sampled:11/18/2021 0845 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/2021
0134 JWO
23728
2 5030B 8260D
1 12/07/2021 1713 CAW
24794
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.61
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
4.0
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.88
H
0.50
0.40
ug/L
2
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
2.5
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.9
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.46
J
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-002
Description: MW-G Matrix: Aqueous
Date Sampled:11/18/2021 0845 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/25/2021 0134 JWO
23728
2
5030B
8260D 1
12/07/2021 1713 CAW
24794
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.58
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130 H 103 70-130
119 70-130 H 103 70-130
106 70-130 H 107 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 62

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK19034-002
Description: MW-G Matrix: Aqueous
Date Sampled:11/18/2021 0845 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/24/2021 2017 CAW 23671
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 120 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
86 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-002
Description: MW-G Matrix: Aqueous
Date Sampled:11/18/2021 0845 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0442 BPK
6020B 10 11/30/2021 1112 BPK
Prep Date Batch
11/29/2021 0356 23456
11/29/2021 0356 23456
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
5.3
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
320 D
50
13
ug/L
2
Beryllium
7440-41-7 6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
18
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
5.0 U
5.0
1.3
ug/L
1
Lead
7439-92-1 6020B
1.0 U
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
26
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
17
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
10 U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-003
Description: MW-B Matrix: Aqueous
Date Sampled:11/18/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/20210159 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-003
Description: MW-B Matrix: Aqueous
Date Sampled:11/18/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/20210159 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
87 70-130
120 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 62

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK19034-003
Description: MW-B Matrix: Aqueous
Date Sampled:11/18/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/24/2021 2042 CAW 23671
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 19 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
88 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-003
Description: MW-B Matrix: Aqueous
Date Sampled:11/18/2021 0900 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0449 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
150
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
8.2
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
4.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-004
Description: MW-F Matrix: Aqueous
Date Sampled:11/18/2021 0930 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/2021 0224 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-004
Description: MW-F Matrix: Aqueous
Date Sampled:11/18/2021 0930 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/2021 0224 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130
117 70-130
104 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 62

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK19034-004
Description: MW-F Matrix: Aqueous
Date Sampled:11/18/2021 0930 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/24/2021 2106 CAW 23671
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 29 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-004
Description: MW-F Matrix: Aqueous
Date Sampled:11/18/2021 0930 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0457 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
240
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
2.0
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
12
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
1.5
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-005
Description: MW-D Matrix: Aqueous
Date Sampled:11/18/2021 0950 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/2021
0248 JWO
23728
2 5030B 8260D
1 12/07/2021 1736 CAW
24794
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
4.2
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.69
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.46
HJ
0.50
0.40
ug/L
2
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
3.8
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
7.4
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.67
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-005
Description: MW-D Matrix: Aqueous
Date Sampled:11/18/2021 0950 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/25/2021 0248 JWO
23728
2
5030B
8260D 1
12/07/2021 1736 CAW
24794
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
1.8
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
92 70-130 H 102 70-130
120 70-130 H 99 70-130
105 70-130 H 106 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-005
Description: MW-D Matrix: Aqueous
Date Sampled:11/18/2021 0950 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0504 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
1.6
J
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
280
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
17
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
32
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-006
Description: MW-K Matrix: Aqueous
Date Sampled:11/18/2021 1005 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/2021 0313 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-006
Description: MW-K Matrix: Aqueous
Date Sampled:11/18/2021 1005 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/2021 0313 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
91 70-130
123 70-130
105 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-006
Description: MW-K Matrix: Aqueous
Date Sampled:11/18/2021 1005 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0511 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
41
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.2
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.1
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-007
Description: MW-C Matrix: Aqueous
Date Sampled:11/18/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/2021
0337 JWO
23728
2 5030B 8260D
1 12/07/2021 1759 CAW
24794
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.60
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.45
J
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.72
H
0.50
0.40
ug/L
2
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
2.5
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
2.9
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
13
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-007
Description: MW-C Matrix: Aqueous
Date Sampled:11/18/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/25/2021 0337 JWO
23728
2
5030B
8260D 1
12/07/2021 1759 CAW
24794
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
2.2
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
89 70-130 H 103 70-130
119 70-130 H 102 70-130
106 70-130 H 107 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-007
Description: MW-C Matrix: Aqueous
Date Sampled:11/18/2021 1020 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0519 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
58
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
9.7
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
6.8
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-008
Description: MW-J Matrix: Aqueous
Date Sampled:11/18/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/20210402 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-008
Description: MW-J Matrix: Aqueous
Date Sampled:11/18/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/20210402 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
92 70-130
120 70-130
106 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-008
Description: MW-J Matrix: Aqueous
Date Sampled:11/18/2021 1040 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0541 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
16
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
2.5
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-009
Description: MW-X Matrix: Aqueous
Date Sampled:11/18/2021 1055 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/20210426 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-009
Description: MW-X Matrix: Aqueous
Date Sampled:11/18/2021 1055 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/20210426 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
86 70-130
118 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 62

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WK19034-009
Description: MW-X Matrix: Aqueous
Date Sampled:11/18/2021 1055 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/24/2021 2131 CAW 23671
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
87 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-009
Description: MW-X Matrix: Aqueous
Date Sampled:11/18/2021 1055 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0548 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.9
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
29
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.6
BJ
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.56
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.9
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
3.5
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-010
Description: EQ-BLANK-2 Matrix: Aqueous
Date Sampled:11/18/2021 1520 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/25/20210045 JWO
23728
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
UL
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-010
Description: EQ-BLANK-2 Matrix: Aqueous
Date Sampled:11/18/2021 1520 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/25/20210045 JWO 23728
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
85 70-130
119 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-010
Description: EQ-BLANK-2 Matrix: Aqueous
Date Sampled:11/18/2021 1520 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0555 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
5.0
U
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.1
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
7.0
B
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-011
Description: CD4 Rep Matrix: Aqueous
Date Sampled:11/17/2021 1510 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/24/20210410 JWO
23569
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
UL
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
UL
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
2.1
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
UL
10
2.0
ug/L
1
Methacrylonitrile
126-98-7
8260D
5.0
U
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 62

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WK19034-011
Description: CD4 Rep Matrix: Aqueous
Date Sampled:11/17/2021 1510 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/24/20210410 JWO 23569
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
98 70-130
110 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 62

ICP-MS Metals
Client:CDM Smith Laboratory ID:WK19034-011
Description: CD4 Rep Matrix: Aqueous
Date Sampled:11/17/2021 1510 Project Name: Cabarrus County 2021-2022
Date Received: 11 /19/2021 Project Number: Unit 2
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/30/2021 0603 BPK
Prep Date Batch
11/29/2021 0356 23456
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
66
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.28
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
6.0
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.4
BJ
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.61
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
4.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
11
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
3.2
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 62

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 62

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23569-001 Matrix: Aqueous
Batch: 23569 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/23/2021 2339
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/23/2021 2339
Benzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/23/2021 2339
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
11/23/2021 2339
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/23/2021 2339
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
2-Hexanone
10
U
1
10
2.0
ug/L
11/23/2021 2339
Methacrylonitrile
5.0
U
1
5.0
2.0
ug/L
11/23/2021 2339
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/23/2021 2339
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/23/2021 2339
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Styrene
0.50
U
1
0.50
0.41
ug/L
11/23/2021 2339
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Toluene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 62
QC Data for Lot Number: WK19034

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23569-001 Matrix: Aqueous
Batch: 23569 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/23/2021 2339
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/23/2021 2339
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/23/2021 2339
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 103 70-130
1,2-Dichloroethane-d4 112 70-130
Toluene-d8 94 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 62

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23569-002 Matrix: Aqueous
Batch: 23569 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Acetone
100
180
N
1
177
60-140
11/23/2021 2103
Acrylonitrile
100
120
1
117
70-130
11/23/2021 2103
Benzene
50
50
1
101
70-130
11/23/2021 2103
Bromochloromethane
50
50
1
101
70-130
11/23/2021 2103
Bromodichloromethane
50
55
1
110
70-130
11/23/2021 2103
Bromoform
50
45
1
90
70-130
11/23/2021 2103
Bromomethane (Methyl bromide)
50
42
1
84
70-130
11/23/2021 2103
2-Butanone (MEK)
100
140
N
1
143
70-130
11/23/2021 2103
Carbon disulfide
50
54
1
107
70-130
11/23/2021 2103
Carbon tetrachloride
50
59
1
117
70-130
11/23/2021 2103
Chlorobenzene
50
49
1
99
70-130
11/23/2021 2103
Chloroethane
50
41
1
81
70-130
11/23/2021 2103
Chloroform
50
53
1
106
70-130
11/23/2021 2103
Chloromethane (Methyl chloride)
50
48
1
96
60-140
11/23/2021 2103
1,2-Dibromo-3-chloropropane (DBCP)
50
59
1
117
70-130
11/23/2021 2103
Dibromochloromethane
50
55
1
110
70-130
11/23/2021 2103
1,2-Dibromoethane (EDB)
50
51
1
103
70-130
11/23/2021 2103
Dibromomethane (Methylene bromide)
50
52
1
104
70-130
11/23/2021 2103
trans- 1,4-Dichloro-2-butene
50
63
1
126
70-130
11/23/2021 2103
1,2-Dichlorobenzene
50
49
1
97
70-130
11/23/2021 2103
1,4-Dichlorobenzene
50
48
1
95
70-130
11/23/2021 2103
1,1-Dichloroethane
50
55
1
110
70-130
11/23/2021 2103
1,2-Dichloroethane
50
53
1
106
70-130
11/23/2021 2103
1,1-Dichloroethene
50
54
1
107
70-130
11/23/2021 2103
cis- 1,2-Dichloroethene
50
50
1
101
70-130
11/23/2021 2103
trans- 1,2-Dichloroethene
50
52
1
105
70-130
11/23/2021 2103
1,2-Dichloropropane
50
53
1
106
70-130
11/23/2021 2103
cis- 1,3-Dichloropropene
50
57
1
114
70-130
11/23/2021 2103
trans- 1,3-Dichloropropene
50
49
1
98
70-130
11/23/2021 2103
Ethylbenzene
50
50
1
101
70-130
11/23/2021 2103
2-Hexanone
100
140
N
1
138
70-130
11/23/2021 2103
Methacrylonitrile
250
280
1
112
70-130
11/23/2021 2103
Methyl iodide (lodomethane)
50
45
1
89
70-130
11/23/2021 2103
4-Methyl-2-pentanone
100
120
1
122
70-130
11/23/2021 2103
Methylene chloride
50
48
1
96
70-130
11/23/2021 2103
Styrene
50
53
1
106
70-130
11/23/2021 2103
1,1,1,2-Tetrachloroethane
50
52
1
103
70-130
11/23/2021 2103
1,1,2,2-Tetrachloroethane
50
57
1
113
70-130
11/23/2021 2103
Tetrachloroethene
50
49
1
97
70-130
11/23/2021 2103
Toluene
50
51
1
103
70-130
11/23/2021 2103
1,1,1-Trichloroethane
50
56
1
111
70-130
11/23/2021 2103
1,1,2-Trichloroethane
50
49
1
97
70-130
11/23/2021 2103
Trichloroethene
50
49
1
97
70-130
11/23/2021 2103
Trichlorofluoromethane
50
51
1
103
70-130
11/23/2021 2103
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 48 of 62
QC Data for Lot Number: WK19034

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23569-002
Matrix: Aqueous
Batch: 23569
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
56
1
112
70-130
11/23/2021 2103
Vinyl acetate
50
50
1
101
60-140
11/23/2021 2103
Vinyl chloride
50
54
1
108
70-130
11/23/2021 2103
Xylenes (total)
100
100
1
101
70-130
11/23/2021 2103
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 97 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 62

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: WQ23671-001 Matrix: Aqueous
Batch:23671 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 11/24/2021 1259
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
87 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 50 of 62
QC Data for Lot Number: WK19034

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: WQ23671-002 Matrix: Aqueous
Batch:23671 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 52 1 105 70-130 11/24/2021 1157
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
109 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 51 of 62
QC Data for Lot Number: WK19034

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23728-001 Matrix: Aqueous
Batch: 23728 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/24/2021 2235
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/24/2021 2235
Benzene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/24/2021 2235
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
trans- 1,4-Dichloro-2-butene
2.0
u
1
2.0
0.40
ug/L
11/24/2021 2235
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/24/2021 2235
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
2-Hexanone
10
U
1
10
2.0
ug/L
11/24/2021 2235
Methacrylonitrile
5.0
U
1
5.0
2.0
ug/L
11/24/2021 2235
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/24/2021 2235
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/24/2021 2235
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Styrene
0.50
U
1
0.50
0.41
ug/L
11/24/2021 2235
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Toluene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 52 of 62
QC Data for Lot Number: WK19034

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23728-001 Matrix: Aqueous
Batch:23728 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/24/2021 2235
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/24/2021 2235
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/24/2021 2235
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 89 70-130
1,2-Dichloroethane-d4 118 70-130
Toluene-d8 103 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 53 of 62

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23728-002 Matrix: Aqueous
Batch:23728 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
150
N 1
146
60-140
11/24/2021 2130
Acrylonitrile
100
130
N 1
133
70-130
11/24/2021 2130
Benzene
50
54
1
108
70-130
11/24/2021 2130
Bromochloromethane
50
54
1
109
70-130
11/24/2021 2130
Bromodichloromethane
50
49
1
98
70-130
11/24/2021 2130
Bromoform
50
42
1
85
70-130
11/24/2021 2130
Bromomethane (Methyl bromide)
50
54
1
109
70-130
11/24/2021 2130
2-Butanone (MEK)
100
120
1
123
70-130
11/24/2021 2130
Carbon disulfide
50
58
1
115
70-130
11/24/2021 2130
Carbon tetrachloride
50
50
1
100
70-130
11/24/2021 2130
Chlorobenzene
50
48
1
95
70-130
11/24/2021 2130
Chloroethane
50
64
1
129
70-130
11/24/2021 2130
Chloroform
50
55
1
110
70-130
11/24/2021 2130
Chloromethane (Methyl chloride)
50
54
1
108
60-140
11/24/2021 2130
1,2-Dibromo-3-chloropropane (DBCP)
50
45
1
91
70-130
11/24/2021 2130
Dibromochloromethane
50
46
1
93
70-130
11/24/2021 2130
1,2-Dibromoethane (EDB)
50
47
1
93
70-130
11/24/2021 2130
Dibromomethane (Methylene bromide)
50
52
1
103
70-130
11/24/2021 2130
trans- 1,4-Dichloro-2-butene
50
36
1
73
70-130
11/24/2021 2130
1,2-Dichlorobenzene
50
47
1
95
70-130
11/24/2021 2130
1,4-Dichlorobenzene
50
46
1
92
70-130
11/24/2021 2130
1,1-Dichloroethane
50
58
1
116
70-130
11/24/2021 2130
1,2-Dichloroethane
50
50
1
99
70-130
11/24/2021 2130
1,1-Dichloroethene
50
56
1
112
70-130
11/24/2021 2130
cis- 1,2-Dichloroethene
50
53
1
107
70-130
11/24/2021 2130
trans- 1,2-Dichloroethene
50
53
1
105
70-130
11/24/2021 2130
1,2-Dichloropropane
50
54
1
108
70-130
11/24/2021 2130
cis- 1,3-Dichloropropene
50
48
1
97
70-130
11/24/2021 2130
trans- 1,3-Dichloropropene
50
46
1
92
70-130
11/24/2021 2130
Ethylbenzene
50
46
1
92
70-130
11/24/2021 2130
2-Hexanone
100
98
1
98
70-130
11/24/2021 2130
Methacrylonitrile
250
290
1
117
70-130
11/24/2021 2130
Methyl iodide (lodomethane)
50
52
1
103
70-130
11/24/2021 2130
4-Methyl-2-pentanone
100
95
1
95
70-130
11/24/2021 2130
Methylene chloride
50
64
1
127
70-130
11/24/2021 2130
Styrene
50
47
1
94
70-130
11/24/2021 2130
1,1,1,2-Tetrachloroethane
50
48
1
97
70-130
11/24/2021 2130
1,1,2,2-Tetrachloroethane
50
51
1
102
70-130
11/24/2021 2130
Tetrachloroethene
50
45
1
91
70-130
11/24/2021 2130
Toluene
50
48
1
96
70-130
11/24/2021 2130
1,1,1-Trichloroethane
50
51
1
102
70-130
11/24/2021 2130
1,1,2-Trichloroethane
50
49
1
97
70-130
11/24/2021 2130
Trichloroethene
50
47
1
93
70-130
11/24/2021 2130
Trichlorofluoromethane
50
55
1
111
70-130
11/24/2021 2130
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 54 of 62
QC Data for Lot Number: WK19034

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23728-002
Matrix: Aqueous
Batch:23728
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
47
1
93
70-130
11/24/2021 2130
Vinyl acetate
50
44
1
89
60-140
11/24/2021 2130
Vinyl chloride
50
55
1
109
70-130
11/24/2021 2130
Xylenes (total)
100
91
1
91
70-130
11/24/2021 2130
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 91 70-130
1,2-Dichloroethane-d4 103 70-130
Toluene-d8 98 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 55 of 62

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ24794-001 Matrix: Aqueous
Batch:24794 Prep Method: 5030E
Analytical Method: 8260D
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloroethane 0.50 U 1 0.50 0.40 ug/L 12/07/2021 1133
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 103 70-130
1,2-Dichloroethane-d4 102 70-130
Toluene-d8 105 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 56 of 62

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ24794-002
Matrix: Aqueous
Batch:24794
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
Chloroethane
50
46
1 92 70-130 12/07/2021 1025
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 98 70-130
1,2-Dichloroethane-d4 91 70-130
Toluene-d8 96 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WK19034
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 57 of 62

ICP-MS Metals - MB
Sample ID: WQ23456-001 Matrix: Aqueous
Batch: 23456 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/29/2021 0356
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
11/30/2021 0244
Arsenic
2.0
U
1
2.0
1.3
ug/L
11/30/2021 0244
Barium
5.0
U
1
5.0
1.3
ug/L
11/30/2021 0244
Beryllium
0.40
U
1
0.40
0.15
ug/L
11/30/2021 0244
Cadmium
0.50
U
1
0.50
0.13
ug/L
11/30/2021 0244
Chromium
5.0
U
1
5.0
1.3
ug/L
11/30/2021 0244
Cobalt
5.0
U
1
5.0
1.3
ug/L
11/30/2021 0244
Copper
1.7
J
1
5.0
1.3
ug/L
11/30/2021 0244
Lead
1.0
U
1
1.0
0.25
ug/L
11/30/2021 0244
Nickel
5.0
U
1
5.0
1.3
ug/L
11/30/2021 0244
Selenium
5.0
U
1
5.0
1.3
ug/L
11/30/2021 0244
Silver
1.0
U
1
1.0
0.25
ug/L
11/30/2021 0244
Thallium
0.50
U
1
0.50
0.15
ug/L
11/30/2021 0244
Vanadium
5.0
U
1
5.0
2.5
ug/L
11/30/2021 0244
Zinc
10
U
1
10
2.5
ug/L
11/30/2021 0244
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 58 of 62
QC Data for Lot Number: WK19034

ICP-MS Metals - LCS
Sample ID: WQ23456-002 Matrix: Aqueous
Batch: 23456 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/29/2021 0356
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
95
1
95
80-120
11/30/2021 0251
Arsenic
100
100
1
102
80-120
11/30/2021 0251
Barium
100
96
1
96
80-120
11/30/2021 0251
Beryllium
100
100
1
102
80-120
11/30/2021 0251
Cadmium
100
98
1
98
80-120
11/30/2021 0251
Chromium
100
110
1
107
80-120
11/30/2021 0251
Cobalt
100
110
1
108
80-120
11/30/2021 0251
Copper
100
110
1
109
80-120
11/30/2021 0251
Lead
100
100
1
103
80-120
11/30/2021 0251
Nickel
100
110
1
111
80-120
11/30/2021 0251
Selenium
100
92
1
92
80-120
11/30/2021 0251
Silver
100
110
1
110
80-120
11/30/2021 0251
Thallium
100
100
1
102
80-120
11/30/2021 0251
Vanadium
100
100
1
104
80-120
11/30/2021 0251
Zinc
100
94
1
94
80-120
11/30/2021 0251
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 59 of 62
QC Data for Lot Number: WK19034

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 60 of 62

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 61 of 62

PACE ANALYTICAL SERVICES, LLC
Sar"pl0-s Receipt Checklist (SRC) {MCC01SC-15) eviscd:9{29/.2MD
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1 5tr:p TT} ^ mil• £ -L C'Florilie Strip ID: rL^ lcstcd by.:
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Aethod: ❑TemperalI;rr Rlanl< ❑A gninst i3ottles 1R Gull Ta: { T1t {?LILT L'cni cation 1 actr}1" {I °
C-,Lhq[i Qf tfaultmL: 21 W,;ticc ❑ [oe Packs ❑ Da Tun ❑ Noll;
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❑No
S_ Were pmper cuMMIYproccdures (rrlincl-AsheLL-Teceived) f4,llukccd?
ee
No
6_ Were Ramplr Ms 1ictcd an the COUI
. Yes
❑ N{7
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10. T}id 0 containcr JabcJ intorlrlation (ID, dale, iirne) ngmo with the COC?
Q'Yus
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12. Die all 5fm plcs arYJ}v in the pmper-;:onlaineix fcu �%h TCS ndr`or in pod Curulil-itrn
(Irnt"kcn, lids on. etc.)?
Us
No
13. W-a,e ru. Nuiw sample volunle available?
s
LJ No
14, l -4ro:ell samples roccived within "-� the hi)l ing tuna rn:49 L-omrs, v Mdieve: Unit,. ,ir4l?
in.LlVo
❑NA
5.' t!m an ss,n,plt5 C•6ntahlers noirelr. m w) 5umplcs Not Ji3tcd an CPC?
❑Yes
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6. Par VDA and R9%-1'i s�ml ,a5, wire u lespreser[L-•"Ecru-sir> "{t "cu d:71m rn dialnet8r',
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No
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17,-Wr'call DRClrmeMlsAn1trientsa,naltnires;eivr,;J aapJHof<2?
Ya3
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18_ Were all Cva[uidt� sampl4s .mwivcd at a pH > 12 and sulfide {amplrs rcc;ivq,j at a pH > 9?
Yt�
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1_ _ Were a applicable h�T=,'7[Ohlrr y rnidw`pbcnflL+G25.1+606.3 (<0.5m�.;T.) xmnpItR -r :c o
re.31dw.] chturjUC?
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`rl_ Were client remiirrl«+reyuct~ta (i c, requested diludDrrs_ M&MSr) &signations, vroc,,,1
correctly Iranr;Lxibrd from the C:oC hita the cu[tlmruL,;K-,vLicin ill LN- 52
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21 _ Was ttie Lui W number listed on the conrainer label? Tf vrs, Cluotc 4
Sample Yreservation lA4us7 beCOr[�p1rLe�1 fur wuiy'sxm lc{s) intourccth pre erred nr k+ilhhrs,,lsl,acc,i
Sample(s) nl .. _. Were reutnive[i incurrccilvpiwcrvcdalldwel,e adjumed xwrdinghy
in sample teteiving wit.:. Nri mL of circle aue: H21SO4, NR03, HCI, Napa using Sit'' VA
TiInr of Frenerya:J.iirn NA if rkom than ane premrvad,.-6 is nerdn;l, plcasc I10te hl the CUllllr[elAN hcluu..
sm1ple(s) irk were received wish h[[bHos =.G mm in diamecer.
Sarr[plcs(x) `a^ ._ - _ were rrce veil witli JRC = 0_5 mejL (Tf .! 14 is 11rj ) aak[ WQTZ
mlj„xte[1 mum,ling y in sample u7ceiv:r:g w1rh s0611.11 il[:M U1 FU(O (N4i.25y03) with Skaly [D:
SR barcode labels apptic[[ 1: -: Late: +
fA=unl4: `,z,4, {.d G►sl(4,,143 iI Gl7 nr„ d7J S }r1 yf7_ frs-� i.r �i 13 ;
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 62 of 62

aceAnalytical®
www.pacolaibs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
December 07, 2021
Cathy Dover
Pace West Columbia
106 Vantage Point Drive
West Columbia, SC 29172
RE: Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Dear Cathy Dover:
Enclosed are the analytical results for sample(s) received by the laboratory on November 30, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
[phone]
Project Manager
Enclosures
cc: Blaire Gagne, Pace Analytical West Columbia
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 20

aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92574913001
MW-A
Water
11/16/2109:45
11/30/21 14:45
92574913002
AMW-2d
Water
11/16/2111:50
11/30/21 14:45
92574913003
MW-E REP
Water
11/17/21 09:00
11/30/21 14:45
92574913004
MW-E deep
Water
11/17/21 09:45
11/30/21 14:45
92574913005
AMW-1s
Water
11/17/2110:20
11/30/21 14:45
92574913006
AMW-1d
Water
11/17/2110:40
11/30/21 14:45
92574913007
AMW-2s
Water
11/17/2111:30
11/30/21 14:45
92574913008
MW-L
Water
11/17/2112:45
11/30/21 14:45
92574913009
MW-3
Water
11/17/2113:30
11/30/21 14:45
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
WK17018 Cabarrus County
92574913
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92574913001
MW-A
SM 5310B-2014
MDW
1
PASI-A
92574913002
AMW-2d
SM 5310E-2014
MDW
1
PASI-A
92574913003
MW-E REP
SM 5310B-2014
MDW
1
PASI-A
92574913004
MW-E deep
SM 5310B-2014
MDW
1
PASI-A
92574913005
AMW-1s
SM 5310E-2014
MDW
1
PASI-A
92574913006
AMW-1d
SM 5310E-2014
MDW
1
PASI-A
92574913007
AMW-2s
SM 5310E-2014
MDW
1
PASI-A
92574913008
MW-L
SM 5310B-2014
MDW
1
PASI-A
92574913009
MW-3
SM 5310B-2014
MDW
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 20

aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Method: SM 531OB-2014
Description: 5310B TOC
Client: Pace West Columbia (Shealy)
Date: December 07, 2021
General Information:
9 samples were analyzed for SM 531 OB-2014 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 663579
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92574368001,92574368002
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 3476122)
• Total Organic Carbon
• MS (Lab ID: 3476124)
• Total Organic Carbon
• MSD (Lab ID: 3476123)
• Total Organic Carbon
• MSD (Lab ID: 3476125)
• Total Organic Carbon
Additional Comments:
Batch accepted based on laboratory control sample (LCS) recovery.
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 20

aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: MW-A Lab ID: 92574913001 Collected: 11/16/21 09:45 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 2.6 mg/L 1.0 0.50 1 12/04/21 00:04 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 20

aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: AMW-2d Lab ID: 92574913002 Collected: 11/16/21 11:50 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 0.50 1 12/04/21 00:23 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 20

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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: MW-E REP Lab ID: 92574913003 Collected: 11/17/21 09:00 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 4.6 mg/L 1.0 0.50 1 12/04/21 00:41 7440-44-0
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: MW-E deep Lab ID: 92574913004 Collected: 11/17/21 09:45 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 4.7 mg/L 1.0 0.50 1 12/04/21 00:58 7440-44-0
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: AMW-1s Lab ID: 92574913005 Collected: 11/17/21 10:20 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 0.86J mg/L 1.0 0.50 1 12/04/21 10:32 7440-44-0
Date: 12/07/2021 02:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 20

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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: AMW-1d Lab ID: 92574913006 Collected: 11/17/21 10:40 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 1.2 mg/L 1.0 0.50 1 12/04/21 10:50 7440-44-0
Date: 12/07/2021 02:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 20

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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: AMW-2s Lab ID: 92574913007 Collected: 11/17/21 11:30 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 0.50 1 12/04/21 11:07 7440-44-0
Date: 12/07/2021 02:03 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 12 of 20

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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: MW-L Lab ID: 92574913008 Collected: 11/17/21 12:45 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 0.50 1 12/04/21 11:27 7440-44-0
Date: 12/07/2021 02:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 20

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ANALYTICAL RESULTS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Sample: MW-3 Lab ID: 92574913009 Collected: 11/17/21 13:30 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 0.50 1 12/04/21 11:42 7440-44-0
Date: 12/07/2021 02:03 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 14 of 20

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QUALITY CONTROL DATA
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
QC Batch: 663579 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92574913001, 92574913002, 92574913003, 92574913004, 92574913005, 92574913006, 92574913007,
92574913008,92574913009
METHOD BLANK: 3476120 Matrix: Water
Associated Lab Samples: 92574913001, 92574913002, 92574913003, 92574913004, 92574913005, 92574913006, 92574913007,
92574913008,92574913009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 0.50 12/03/21 18:48
LABORATORY CONTROL SAMPLE: 3476121
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 26.1 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3476122 3476123
MS MSD
92574368001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 773 25 25 895 855 490 330 90-110 5 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3476124 3476125
MS MSD
92574368002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 343 25 25 361 358 72 61 90-110 1 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 20

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QUALIFIERS
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: WK17018 Cabarrus County
Pace Project No.: 92574913
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92574913001
MW-A
SM
5310B-2014
663579
92574913002
AMW-2d
SM
5310E-2014
663579
92574913003
MW-E REP
SM
5310B-2014
663579
92574913004
MW-E deep
SM
5310B-2014
663579
92574913005
AMW-1s
SM
5310E-2014
663579
92574913006
AMW-1d
SM
5310E-2014
663579
92574913007
AMW-2s
SM
5310E-2014
663579
92574913008
MW-L
SM
5310B-2014
663579
92574913009
MW-3
SM
5310B-2014
663579
Date: 12/07/2021 02:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 17 of 20

Docum (!ntName! 06tument REvisad: f7ctobar 2$1 2Q20
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Fhwrrrorneter: _ l
❑Yes LING ONJA
[] lRGun.1 i i �Q�WaT Qalue E]Ha4s Type of ice:
tic Corretrion Fartnr:
Cooler TempAddJSubtraa('Cj• Tam pshoDid be above freezing to VC
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my.e MPdA. inrliirfnvHRW211 And Pc>nrtn Rlco11 r1Ye5 nlgo
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COMMEMTS/SAMPLE DISCREPANCY
Lot to of s litcontain?rs:
CLIENT NOTIFICATIDN/RB$DLUn0N
Person contacted: Date/time:
Project Manager SCURF Review:
Prolect Manager SRF Review:
Date;
Date:
Ffald Data Requirod? ❑Yes DrYQ
Page 18 of 20

E7ccurge nt Nam e:
Condttlon Upon Ree
Dacurrrertt No.:
w Check mark top half of box if pN and%r4e�.hlorinatlon, is
verified and within the,acceptance range forpre5ervatlon
samples.
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[7utaF hold, incarrectpraserMlve, out of temp, IncorrectcontafAers.-
Page 19 of 20

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Page 20 of 20

aceAnalytical®
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
December 07, 2021
Cathy Dover
Pace West Columbia
106 Vantage Point Drive
West Columbia, SC 29172
RE: Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Dear Cathy Dover:
Enclosed are the analytical results for sample(s) received by the laboratory on November 30, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
[phone]
Project Manager
Enclosures
cc: Blaire Gagne, Pace Analytical West Columbia
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 1 of 12

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Huntersville, NC 28078
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CERTIFICATIONS
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Lab ID Sample ID Matrix Date Collected Date Received
92574917001 CD-1s Water 11/17/2114:25 11/30/2114:45
REPORT OF LABORATORY ANALYSIS
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Lab ID Sample ID
92574917001 CD-1s
PASI-A = Pace Analytical Services - Asheville
SAMPLE ANALYTE COUNT
Method
SM 5310B-2014
REPORT OF LABORATORY ANALYSIS
Analytes
Analysts Reported
MDW
Laboratory
PAS I -A
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Page 4 of 12

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[phone]
PROJECT NARRATIVE
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Method: SM 531OB-2014
Description: 5310B TOC
Client: Pace West Columbia (Shealy)
Date: December 07, 2021
General Information:
1 sample was analyzed for SM 531 OB-2014 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 663579
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92574368001,92574368002
M1: Matrix spike recovery exceeded QC limits.
• MS (Lab ID: 3476122)
• Total Organic Carbon
• MS (Lab ID: 3476124)
• Total Organic Carbon
• MSD (Lab ID: 3476123)
• Total Organic Carbon
• MSD (Lab ID: 3476125)
• Total Organic Carbon
Additional Comments:
Batch accepted based on laboratory control sample (LCS) recovery.
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 5 of 12

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ANALYTICAL RESULTS
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Sample: CD-1s Lab ID: 92574917001 Collected: 11/17/21 14:25 Received: 11/30/21 14:45 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 0.62J mg/L 1.0 0.50 1 12/04/21 11:59 7440-44-0
REPORT OF LABORATORY ANALYSIS
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Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 12

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9800 Kincey Ave. Suite 100
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[phone]
QUALITY CONTROL DATA
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
QC Batch: 663579 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92574917001
METHOD BLANK: 3476120
Associated Lab Samples: 92574917001
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 3476121
Parameter Units
Total Organic Carbon mg/L
Matrix: Water
Blank Reporting
Result Limit
ND 1.0
Spike LCS
Conc. Result
25 26.1
MDL Analyzed Qualifiers
0.50 12/03/21 18:48
LCS % Rec
% Rec Limits Qualifiers
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3476122 3476123
MS MSD
92574368001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 773 25 25 895 855 490 330 90-110 5 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3476124 3476125
MS MSD
92574368002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 343 25 25 361 358 72 61 90-110 1 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 12

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12

aceAnalytical®
www.pacolaibs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: WK18006 Cabarrus County
Pace Project No.: 92574917
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92574917001 CD-1s SM 5310E-2014 663579
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2021 02:03 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 12

DoeumentName:
Document Revised: CCtober 28, 2p20
a
dC8i4fla «r
Sample Condition Upon Recel t SCUR
Pa e 1 of 2
Doc umentNv,:
I3sUingRuthorlty;
P.CAR-CS•033-RCY.B7
Pace carp! lnas �uallt Ofn[e
Laboratory receiving samples;
Asheville Eden❑ Greertwood ❑ Huntersville ❑ Ralelgli❑ Mechanicsville❑ Atlanta❑ HertTersville❑
Sample Condition CflenMirne; WC)# 4.92574917
upon Receipt � Project I Pro
..Iv�;u
Courier: —OFed6Jt Ql1P5 D—U5P5 ..._ _ ❑Client
[]Commercial ]Pace ❑others 92574917
Custody Seat Present? wfYes ❑N0 Seals 111l0ct? ?Yes ONO
Ualejinl[}als Person rxartt[nlrig Contertts:��
Patiring-Muerlal' ❑Ruisble Wrap []Bubble Flags None ❑ Other Ginlogiral Tissuekozen?
Thermometer: Oyes []NoON/A
❑ IR Gun 1P- ^" Wet ❑O1�e ❑Nu(e
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Yes
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6Yes ©No
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Yes
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7,
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)ZYes
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Trip lilartk CuAtody Sears Present?
Yet
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COMMENTSI5AMPLE DISCREPANCY Field Data Required? []YeS ❑ho
Lo..t $I) of split containers:
CLIENT NOTrfICAT IDNJRVSOLUTiON
Pwwrt contacted;
❑ate/11nto:
Project Manager SCURF RBViewr Dater
Project Manager SELF Ruvlew:
Page 10 of 12

pacutnent Name. document Revlsrd:-'7c{ohar Z9, 2020.
5aniple Cund3tIQn Uport Recei t(kVR) page 2 of l
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*Check mark top hair of tiox it pH ancilor-3Ktllorination is
verifled and wlthln the acceptante range for preservatlon
samples.
Exceptions, V0A, Co I Iform, TOC, 0 ff vd Grease, 090/8015 [water).DOC, LUIC
**aottor i half of- box .ls to list nun1ber of bottles
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(� aceAna/ytical W
LELAP CERTIFICATE NUMBER: 01955
DOD-ELAP ACCREDITATION NUMBER: 74960
ANALYTICAL RESULTS
•:I
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 12/14/2021
Report Y 231113090
�1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III
Project WK17018 Cabarrus County
Samples Collected 11/16/21 - 11/17/21
Deliver To Additional Recipients
Cathy Dover NONE
Pace Analytical Services South Carolina
106 Vantage Point Drive
West Columbia, SC 29172
[phone]
L*--
FJLA
1XMINg
DOD ELAF
Pace Gulf Coast Report#: 221113090 Page 1 of 17

Report#: 221113090
ace k k+ytUh
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub -Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re -analysis
CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non -compliant QC Result (See Q Flag Application Report)
" Indicates a non -compliant or not applicable QC recovery or RPD — see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk -based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis — when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results
contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.
Authorized Signature
Pace Gulf Coast Report 221113090
Pace Gulf Coast Report#: 221113090 Page 2 of 17

Report#: 221113090
aceAr�alYl�+l
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Certifications
Certification
Certification Number
DOD ELAP
74960
Alabama
01955
Arkansas
88-0655
Colorado
01955
Delaware
01955
Florida
E87854
Georgia
01955
Hawaii
01955
Idaho
01955
Illinois
200048
Indiana
01955
Kansas
E-10354
Kentucky
95
Louisiana
01955
Maryland
01955
Massachusetts
01955
Michigan
01955
Mississippi
01955
Missouri
01955
Montana
N/A
Nebraska
01955
New Mexico
01955
North Carolina
618
North Dakota
R-195
Oklahoma
9403
South Carolina
73006001
South Dakota
01955
Tennessee
01955
Texas
T104704178
Vermont
01955
Virginia
460215
Washington
C929
USDA Soil Permit
P330-16-00234
Pace Gulf Coast Report#: 221113090 Page 3 of 17

Report#: 221113090
ace k k+ytUh
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Case Narrative
Client: Pace Analytical Services South Carolina Report: 221113090
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
PROJECT MANAGER COMMENTS
Project Manager Comments - All of the samples for Hydrogen analysis were received either on the day the holding time expired or
within 1 day of the expiration. All analyses were completed as quickly as possible. (Ruth Welsh(Do Not 12/01/2021 11:40)
VOLATILES GAS CHROMATOGRAPHY
In the AM20_B analysis for analytical batch 728491 , all samples were analyzed outside hold time due to failing CCVs in the initial
analytical batch.
Pace Gulf Coast Report#: 221113090 Page 4 of 17

ace k k+ytUh
Report#: 221113090
Project ID: WK17018 Cabarrus County
Report Date:
12/14/2021
Sample Summary
Lab ID
Client ID
Matrix
Collect Date
Receive Date
22111309001
MW-A
Water
11/16/21 09:45
11/30/21 11:03
22111309002
AMW-2d
Water
11/16/2111:50
11/30/21 11:03
22111309003
MW-E REP
Water
11/17/21 09:00
11/30/21 11:03
22111309004
MW-E deep
Water
11/17/21 09:45
11/30/21 11:03
22111309005
AMW-1s
Water
11/17/2110:20
11/30/21 11:03
22111309006
AMW-1d
Water
11/17/2110:40
11/30/21 11:03
22111309007
AMW-2s
Water
11/17/2111:30
11/30/21 11:03
22111309008
MW-L
Water
11/17/2112:45
11/30/21 11:03
22111309009
MW-3
Water
11/17/2113:30
11/30/21 11:03
22111309010
MW-A (1-12)
Bubble Strip
11/16/21 09:45
11/30/21 11:03
22111309011
AMW-2d (1-12)
Bubble Strip
11/16/21 11:50
11/30/21 11:03
22111309012
MW-E deep (1-12)
Bubble Strip
11/16/21 13:00
11/30/21 11:03
22111309013
AMW-1 deep (1-12)
Bubble Strip
11/16/21 14:15
11/30/21 11:03
22111309014
AMW-1s (1-12)
Bubble Strip
11/16/21 14:50
11/30/21 11:03
22111309015
MW-E REP (1-12)
Bubble Strip
11/17/21 09:00
11/30/21 11:03
22111309016
MW-L (1-12)
Bubble Strip
11/17/21 12:45
11/30/21 11:03
22111309017
MW-3 (1-12)
Bubble Strip
11/17/21 13:30
11/30/21 11:03
22111309018
AMW-2s (1-12)
Bubble Strip
11/17/21 11:20
11/30/21 11:03
Pace Gulf Coast Report#: 221113090 Page 5 of 17

k
Report#:
221113090
ace k+ytUh
Project ID:
WK17018 Cabarrus County
Report Date: 12/14/2021
Detect Summary
Results and Detection
Limits are adjusted for dilution and
moisture when applicable
AM23G
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22111309001
MW-A
Acetic Acid
mg/L
2.9
1
NA
22111309001
MW-A
Lactic Acid
mg/L
0.35J
1
NA
22111309002
AMW-2d
Acetic Acid
mg/L
3.9
1
NA
22111309002
AMW-2d
Lactic Acid
mg/L
0.48J
1
NA
22111309003
MW-E REP
Acetic Acid
mg/L
1.9
1
NA
22111309003
MW-E REP
Butyric Acid
mg/L
0.41J
1
NA
22111309003
MW-E REP
Lactic Acid
mg/L
0.92
1
NA
22111309004
MW-E deep
Acetic Acid
mg/L
2.1
1
NA
22111309004
MW-E deep
Butyric Acid
mg/L
0.13J
1
NA
22111309004
MW-E deep
Lactic Acid
mg/L
1.2
1
NA
22111309005
AMW-1s
Acetic Acid
mg/L
2.4
1
NA
22111309005
AMW-1 s
Lactic Acid
mg/L
0.44J
1
NA
22111309006
AMW-1 d
Acetic Acid
mg/L
4.9
1
NA
22111309006
AMW-1 d
Lactic Acid
mg/L
0.71
1
NA
22111309007
AMW-2s
Acetic Acid
mg/L
2.2
1
NA
22111309007
AMW-2s
Lactic Acid
mg/L
0.51
1
NA
22111309008
MW-L
Acetic Acid
mg/L
2.2
1
NA
22111309008
MW-L
Lactic Acid
mg/L
0.84
1
NA
22111309009
MW-3
Acetic Acid
mg/L
2.3
1
NA
22111309009
MW-3
Lactic Acid
mg/L
0.56
1
NA
AM20GAX
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22111309010
MW-A (H2)
Hydrogen
nM
1.7J
2
NA
22111309011
AMW-2d (H2)
Hydrogen
nM
II AJ
2
NA
22111309012
MW-E deep (H2)
Hydrogen
nM
1.8J
2
NA
22111309013
AMW-1 deep (H2)
Hydrogen
nM
1.3J
2
NA
22111309014
AMW-1s (H2)
Hydrogen
nM
2.OJ
2
NA
22111309015
MW-E REP (H2)
Hydrogen
nM
1.1J
1
NA
22111309016
MW-L (H2)
Hydrogen
nM
2.5
1
NA
22111309017
MW-3 (H2)
Hydrogen
nM
2.4
1
NA
22111309018
AMW-2s (H2)
Hydrogen
nM
1.01
1
NA
Pace Gulf Coast Report#: 221113090 Page 6 of 17

Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Sample Results
Collect Date 11/16/2021 09:45 Lab ID 22111309001
MW-A Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/06/2122:04 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
2.9
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.35J
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
AMW-2d Collect Date 11/16/2021 11:50 Lab ID 22111309002
Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/06/2122:39 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
3.9
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.48J
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 11/17/2021 09:00 Lab ID 22111309003
MW-E REP Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/06/2123:13 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
1.9
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.41J
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.92
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Pace Gulf Coast Report#: 221113090 Page 7 of 17

Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Sample Results
Collect Date 11/17/2021 09:45 Lab ID 22111309004
MW-E deep Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/06/2123:48 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
2.1
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.13J
0.058
0.50
mg/L
50-21-5
Lactic Acid
1.2
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 11/17/2021 10:20 Lab ID 22111309005
AMW-1$ Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/07/2101:32 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
2.4
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.44J
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 11/17/2021 10:40 Lab ID 22111309006
AMW-1 d Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/07/2102:07 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
4.9
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.71
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Pace Gulf Coast Report#: 221113090 Page 8 of 17

Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Sample Results
AMW-2s Collect Date 11/17/2021 11:30 Lab ID 22111309007
Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/07/2102:41 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
2.2
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.51
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 11/17/2021 12:45 Lab ID 22111309008
MW-L Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/07/2103:16 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
2.2
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.84
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 11/17/2021 13:30 Lab ID 22111309009
MW�3 Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/07/2103:50 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
2.3
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.56
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Pace Gulf Coast Report#: 221113090 Page 9 of 17

--] Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Sample Results
Collect Date 11/16/2021 09:45 Lab ID 22111309010
MW-A (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
*Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 12/03/2116:29 728491 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
1.7J
0.98
3.8
nM
Collect Date 11/16/2021 11:50 Lab ID 22111309011
AMW-2d (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
*Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 12/03/2116:41 728491 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
1.4J
0.98
3.8
nM
Collect Date 11/16/2021 13:00 Lab ID 22111309012
MW-E deep (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
*Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 12/03/2116:53 728491 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
1.81
0.98
3.8
nM
Collect Date 11/16/2021 14:15 Lab ID 22111309013
AMW-1 deep (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
*Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 12/03/2117:06 728491 CWB NA
CAS# Parameter
1333-74-0 Hydrogen
Result
DL
LOQ
Units
1.3J
0.98
3.8
nM
Pace Gulf Coast Report#: 221113090
Page 10 of 17

--] Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Sample Results
Collect Date 11/16/2021 14:50 Lab ID 22111309014
AMW-1 s (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
*Results And limits are adjusted for dilution.
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 2 12/03/2117:18 728491 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
2.0,1
0.98
3.8
nM
Collect Date 11/17/2021 09:00 Lab ID 22111309015
MW-E REP (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/01/2117:05 728281 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
1.11
0.49
1.9
nM
Collect Date 11/17/2021 12:45 Lab ID 22111309016
MW-L (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/01/2117:17 728281 CWB NA
CAS#
Parameter
Result
DL
LOQ
Units
1333-74-0
Hydrogen
2.5
0.49
1.9
nM
Collect Date 11/17/2021 13:30 Lab ID 22111309017
MW-3 (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
AM20GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/01/2117:30 728281 CWB NA
CAS# Parameter
1333-74-0 Hydrogen
Result
DL
LOQ
Units
2.4
0.49
1.9
nM
Pace Gulf Coast Report#: 221113090
Page 11 of 17

Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
Sample Results
Collect Date 11/17/2021 11:20 Lab ID 22111309018
AMW-2s (Fi2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
) GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/01/2117:42 728281 CWB NA
CAS# Parameter
1333-74-0 Hydrogen
Result DL LOQ
1.01 0.49 1.9
Units
nM
Pace Gulf Coast Report#: 221113090
Page 12 of 17

Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
General Chemistry QC Summary
Analytical Batch
Client ID
MB728648
LCS728648
LCSD728648
728648
Lab ID
2281737
2281738
2281739
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
12/07/21 00:57
12/07/21
00:23
12/07/21 07:18
Matrix
Water
Water
Water
AM23G
Units
mg/L
Spike
I Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Acetic Acid
64-19-7
0.12U
0.12
2.0
1.8
90
70 - 130
2.0
1.9
94
5
20
Butyric Acid
107-92-6
0.058U
0.058
2.0
1.6
81
70 - 130
2.0
1.9
97
18
20
Lactic Acid
50-21-5
0.053U
0.053
2.0
2.0
103
70 - 130
2.0
2.0
99
4
20
Propionic Acid
79-09-4
0.053U
0.053
2.0
1.8
93
70 - 130
2.0
1.9
94
1
20
Pyruvic Acid
127-17-3
0.060U
0.060
2.0
2.1
105
70 - 130
2.0
2.2
110
5
20
Pace Gulf Coast Report#: 221113090 Page 13 of 17

Report#: 221113090
Project ID: WK17018 Cabarrus County Report Date: 12/14/2021
General Chromatography QC Summary
Analytical Batch Client ID
MB728281
LCS728281
LCSD728281
728281 Lab ID
2279957
2279958
2279959
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
12/01/21 14:26
12/01/21 14:00
12/01/21 14:13
Matrix
Bubble Strip
Bubble Strip
Bubble Strip
AM20GAX
Units
nM
Spike
Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Hydrogen 1333-74-0
0.49U
1 0.491
121
11
1 94
1 70 - 130
1 121
11
193
1 1
1 20
Analytical Batch Client ID
MB728491
LCS728491
LCSD728491
728491 Lab ID
2280896
2280897
2280898
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
12/03/21 15:40
12/03/21 15:15
12/03/21 15:28
Matrix
Bubble Strip
Bubble Strip
Bubble Strip
AM20GAX
Units
nM
Spike
Result
%R
I
Control
Spike
Result
%R
RPD
RPD
Result
DLI
Added
Limits%R
1 Added
Limit
Hydrogen 1333-74-0
0.49U
1 0.491
121
9.6
181
1 70 - 130
1 121
9.6181
1 1
1 20
Pace Gulf Coast Report#: 221113090 Page 14 of 17

aceAnalytical Chars of Custody
Record
Client ID: Shealy Envir - Pace Anatylicar Services South Carolina
Pace Analytical Services, LLC. SDG: 221113090
106 Vantage Point drive PM: RWe
West Columbia, South Carolina 29172
Telephone No. (803] 791-9700 Fax No. (803) 791-a I I I
www.pacelabs.com
Glierr9
Report to Contact
Telephone No.l E-mail
Quote No -
Pace Analylical Services -West Columbia
Catherine S- Dover
[e-mail]
Address
Sampler's Signature
Analysis (Attach
list
if more space
is needed)
Page
106 Vantage Point Drive
x
1 of 2
City
Stale
Zip Code
Lot fl Bar Code
West Columbia
SC
29172
— Printed Name
�
a1
M
(lab use only)
Project Name
Cabarrus County 2021.2022
2
Project Number
P•o- No-
Matrix
No of Containers by
unit 2
�^Q
cn Y
Preservative T e
Q
a
o
Sample 101 DescrtplIon
Collection
Collection
Time
H
v
7
o
6
8
3
co
p
z
=
Y
m
Y
Remarks 1 Cooler I.D.
tConlatners for each sample may he combined on ❑na Tina}
Date{s)
(military)
r°n
7
r
N
x
a
z
0
m
N
a
a
j
0
MW-A
11/16/2021
0945
G
X
1
2
X
X
WK17018-004
AMW-2d
11/16/2021
1150
G
X
1
2
X
X
WK17018-005
MW-E deep
11/16/2021
1300
G
X
1
X
WK17018-006
AMW-1 deep
11/16/2021
1415
G
X
1
X
WK17018-007
AMW-1s
11/16/2021
145o
G
X
1
X
WK17018-008
MW-E REP
11/17/2021
090o
G
X
1
2
X
X
WK17018-010
MW-E deep
11/17/2021
0945
G
X
2
X
WK17018-011
AMW-1s
11/17/2021
102o
G
X
2
X
WK17018-012
AMW-1d
11/17/2021
1040
G
X
2
X
WK17018-013
AMW-2s
11/17/2021
1130
G
X
2
X
WK17018-014
Turn Around Time Required (Prior lab apprgval required for expedited TAT)
Sample Disposal
Possible Hazard Identification [List any known hazards in the remarks)
QC Requirements
0 Standard ❑ Rush (Please Specify) 7-10 business days
❑ Return to CIlent Disposal by Lab
❑fug-yazamvus ❑ riammahla ❑ sh7n t r ram ❑ Sos prodded ❑ unknown
1. Relinquished by
DaJr
Time
1: Received by
Dale
Time
T. Relinquished by
11e30_a
T
e
2. Received by
Date
T' e�
� �
��I
T. Relinquished by
Dale
Time
3- Received by
Date
Time
4. Relinquished by
Dale
Time
4. Laboratory Received by
Date
Time
Note: All samples are retained for four weeks from
LAB USE ONLY Receipt Te
Temp. Blank
receipt unless other arrangements are made
Received on ice (Check] ❑ Y ❑ N ❑Ice Pack ° C
❑ Y 1 ❑N
1 uo :5H W 1CII 1
Pace Gulf Coast Report#: 221113090 Page 15 of 17

aceAnalWical" Chain of Custody
Record
Pace Analytical Services, LLC.
106 Vantage Paint Drive
West Columbia, South Carolina 29172
Telephone No. (803)l 791 -9 700 Fax Nc. (803) 791--11 r
www.pacelabs.com
Client ID: Shealy Emir - Pace Analytical Services Soul Carolina
� ` a'� IIIIIII IIIIIIII IIIIIIIIII III
C4ient
Pace Analytical Services -West Columbia
Report So Contact
Catherine S- Dover
Telephone No, 1 E-mail
calhy.dover*pacelabs.com
Quote No -
Address
106 Vantage Point Drive
Sampler's Signature
x
Printed Name
Analysis [Attach list
it more space
is needed]
Page
2 of 2
City
West Columbia
Stale
ISO
Zip code
129172
¢
=
2
i
m
w
ul
Lot # Bar Code
{lab use only)
Project Name
Cabarrus County 2021-2022
Project Number
Unit 2
P D• No-
A
n
U
Matrix
No of Containers by
Preservative Type
Sample ID 1 Description
(Can[ainars far each sarnpW way be canbined an ana llna)
Colleclion
Dales)
Collection
Time
(military)
.1
a
p
o
U7
o
v m
Z
¢
2
a
c
a
Q
rn
cV
z
0
Z
=
U
X
D
a
G
¢
cc
Remarks! Cooler I.D.
MW-L
11/17/2021
1245
C,
I X
1
2
X
X
WK17018-016
MW-3
11/17/2021
1330
G
X
1
2
X
X
WK17018-017
AMW-2s
11/17/2021
1120
G
X
1
X
WK17018-020
r�
level 2 with excel +
NCDEQ EQUIS
Turn Around Time Required (prior lab approval required for expedited TAT)
❑� Standard ❑ Rush (Please Specify) 7-10 business days
Sample Disposal
❑ Return to Client 0 Disposal by Lab
Possible Hazard Identification [List any known hazards in the remarks]
❑ Non-HaiafdnU5 ❑ Flammable ❑ Skln irnranl ❑ SOS pm -tided ❑ Unkrmwn
QC Requirements
METHOD REQ. QC
1- Relinquished by
Date
it zu n.l
Time
f�it�
1. Received by
Date
Time
2. Relinquished by
Date
11
Tim[
����ee,,
2 eceived by_ �n. `�
ale
Tyrte
.06
3. Relinquished by
Date
Time
3- Received by
Date
Time
4. Relinquished by
Date
Time
4- Labaralory Received by
Date
Time
Note: All samples are retained for four weeks from
receipt unless other arrangements are made
LAB USE ONLY
Received on Ice (Check) ❑ Y ❑ N ❑ Ice Pack
Receipt Temp.
° C
Temp. Blank
❑ Y 1 ❑N
Pace Gulf Coast Report#: 221113090 Page 16 of 17

/.5navivfica' SAMPLE RECEIVING CHECKLIST IINIIIII�II9II III
SAMPLE DELIVERY GROUP
221113090
CHECKLIST
YES
NO
Client PM RWe
Transport Method
Samples received with proper thermal preservation?
*❑
❑
Shealy Envir - Pace Analytical
FEDDC
Services South Carolina
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including samplelDs, collect times, and sampler)?
*❑
*❑
❑
❑
Profile Number
Received By
288352
Fbberts, George S.
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
0
0
❑
❑
Line Item(s)
Receive Date(s)
1 - VFA
11/30/21
2- hydrogen
Preservative added to any containers?
❑
0
If received, was headspace for VOC water containers < 6mm?
0
❑
Samples collected in containers provided by Pace Gulf Coast?
0
❑
COOLERS
DISCREPANCIES
LAB PRESERVATIONS
Airbill Thermometer ID: E34
Temp °C
None
None
166334661931
0.5
NOTES
Revision 1.6
Page 1 of 1
Pace Gulf Coast Report#: 221113090
Page 17 of 17

aceAnalytical
LELAP CERTIFICATE NUMBER: 01955
DOD-ELAP ACCREDITATION NUMBER: 74960
ANALYTICAL RESULTS
•:I
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 12/14/2021
Report Y231113091
�1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i �1��i III
Project WK18006 Cabarrus Cty
Samples Collected 11/17/21
Deliver To Additional Recipients
Cathy Dover NONE
Pace Analytical Services South Carolina
106 Vantage Point Drive
West Columbia, SC 29172
[phone]
PJLA
'resting
WD tithe
Pace Gulf Coast Report#: 221113091 Page 1 of 11

Report#: 221113091
ace k k+ytUh
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub -Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re -analysis
CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non -compliant QC Result (See Q Flag Application Report)
" Indicates a non -compliant or not applicable QC recovery or RPD — see narrative
E Organics - The result is estimated because it exceeded the instrument calibration range
E Metals - % diference for the serial dilution is > 10%
L Reporting Limits adjusted to meet risk -based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis — when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples
reported. The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results
contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if
applicable.
Authorized Signature
Pace Gulf Coast Report 221113091
Pace Gulf Coast Report#: 221113091 Page 2 of 11

Report#: 221113091
aceAr�alYl�+l
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
Certifications
Certification
Certification Number
DOD ELAP
74960
Alabama
01955
Arkansas
88-0655
Colorado
01955
Delaware
01955
Florida
E87854
Georgia
01955
Hawaii
01955
Idaho
01955
Illinois
200048
Indiana
01955
Kansas
E-10354
Kentucky
95
Louisiana
01955
Maryland
01955
Massachusetts
01955
Michigan
01955
Mississippi
01955
Missouri
01955
Montana
N/A
Nebraska
01955
New Mexico
01955
North Carolina
618
North Dakota
R-195
Oklahoma
9403
South Carolina
73006001
South Dakota
01955
Tennessee
01955
Texas
T104704178
Vermont
01955
Virginia
460215
Washington
C929
USDA Soil Permit
P330-16-00234
Pace Gulf Coast Report#: 221113091 Page 3 of 11

Report#: 221113091
ace k k+ytUh
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
Case Narrative
Client: Pace Analytical Services South Carolina Report: 221113091
Pace Analytical Gulf Coast received and analyzed the sample(s) listed
on the Report Sample Summary page of this report. Receipt of the sample(s) is documented
by the attached chain of custody. This applies only to the sample(s) listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
PROJECT MANAGER COMMENTS
Project Manager Comments - The sample was received the day before the holding time for Hydrogen expired. The analysis was
completed as quickly as possible. (Ruth Welsh(Do Not 12/01/2021 10:34)
Pace Gulf Coast Report#: 221113091 Page 4 of 11

PaceA;U44Uh'
Report#: 221113091
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
Sample Summary
Lab ID Client ID Matrix Collect Date Receive Date
22111309101 CD-1s Water 11/17/2114:25 11/30/2111:03
22111309102 CD-1s (1-12) Bubble Strip 11/17/21 14:25 11/30/21 11:03
Pace Gulf Coast Report#: 221113091 Page 5 of 11

ace k k+ytUh
Report#: 221113091
Project ID: WK18006 Cabarrus Cty
Report Date:
12/14/2021
Results and Detection Limits
Detect Summary
are adjusted for dilution and moisture when applicable
AM23G
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22111309101
22111309101
CD-1 s
CD-1s
Acetic Acid
Lactic Acid
mg/L
mg/L
3.0
0.78
1
1
NA
NA
AM20GAX
Lab ID
Client ID
Parameter
Units
Result
Dil.
%Moist
22111309102
CD-1s (H2)
Hydrogen
nM
0.85J
1
NA
Pace Gulf Coast Report#: 221113091 Page 6 of 11

Report#: 221113091
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
Sample Results
CD-1 s Collect Date 11/17/2021 14:25 Lab ID 22111309101
Receive Date 11/30/2021 11:03 Matrix Water
G
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/07/2104:25 728648 SLL2 NA
CAS#
Parameter
Result
DL
LOQ
Units
64-19-7
Acetic Acid
3.0
0.12
0.50
mg/L
107-92-6
Butyric Acid
0.058U
0.058
0.50
mg/L
50-21-5
Lactic Acid
0.78
0.053
0.50
mg/L
79-09-4
Propionic Acid
0.053U
0.053
0.50
mg/L
127-17-3
Pyruvic Acid
0.060U
0.060
0.50
mg/L
Collect Date 11/17/2021 14:25 Lab ID 22111309102
CD-1 s (H2) Receive Date 11/30/2021 11:03 Matrix Bubble Strip
GAX
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
NA NA NA 1 12/01/2117:54 728281 CWB NA
CAS# Parameter
1333-74-0 Hydrogen
Result
DL
LOQ
Units
0.85J
0.49
1.9
nM
Pace Gulf Coast Report#: 221113091
Page 7 of 11

Report#: 221113091
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
General Chemistry QC Summary
Analytical Batch
Client ID
MB728648
LCS728648
LCSD728648
728648
Lab ID
2281737
2281738
2281739
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
12/07/21 00:57
12/07/21
00:23
12/07/21 07:18
Matrix
Water
Water
Water
AM23G
Units
mg/L
Spike
I Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Acetic Acid
64-19-7
0.12U
0.12
2.0
1.8
90
70 - 130
2.0
1.9
94
5
20
Butyric Acid
107-92-6
0.058U
0.058
2.0
1.6
81
70 - 130
2.0
1.9
97
18
20
Lactic Acid
50-21-5
0.053U
0.053
2.0
2.0
103
70 - 130
2.0
2.0
99
4
20
Propionic Acid
79-09-4
0.053U
0.053
2.0
1.8
93
70 - 130
2.0
1.9
94
1
20
Pyruvic Acid
127-17-3
0.060U
0.060
2.0
2.1
105
70 - 130
2.0
2.2
110
5
20
Pace Gulf Coast Report#: 221113091 Page 8 of 11

Report#: 221113091
Project ID: WK18006 Cabarrus Cty Report Date: 12/14/2021
General Chromatography QC Summary
Analytical Batch Client ID
MB728281
LCS728281
LCSD728281
728281 Lab ID
2279957
2279958
2279959
Sample Type
MB
LCS
LCSD
Prep Date
NA
NA
NA
Analysis Date
12/01/21 14:26
12/01/21 14:00
12/01/21 14:13
Matrix
Bubble Strip
Bubble Strip
Bubble Strip
AM20GAX
Units
nM
Spike
Result
%R
Control
Spike
Result
%R
RPD
RPD
Result
DL
Added
Limits%R
Added
Limit
Hydrogen 1333-74-0
0.49U
1 0.491
121
11
1 94
1 70 - 130
1 121
11
193
1 1
1 20
Pace Gulf Coast Report#: 221113091 Page 9 of 11

Client ID: Shealy Envlr - Pace Analylical Servl ms South Carolina
Pace Analytical Services, LLC. SDG: 221113091
aceAnalytieal
Chain of Custody
1 W Vantage Paint Drive PM: RWe
West Columbia, South Carolina 29172
--
Record Telephone
No. 4B03j 791-9700 Fax No. (8O3) 791-z7
www. acelabs.com
Cfiant
Report to Contact
Telephone No. 1 E-mail
I Quote No.
Pace Analytical Services -West Columbia
Galherlrle S. Dover
Cathy-dover0pacelabs.com
Samplers Signature
Analysis (Attach list it more space is needed)
Page
Address
1 of 1
106 Vantage Paint Drive
Lot It Bar Code
City State Zip Code
X
[lab use only]
West COlumbIa SC 29172
Printed Name
c
Project Name
m
rn
O
Cabarru s Co unly 2021-2622
Project Number
P ° No.Matrix
No of Containers by
Background
n
Preservative T e
Sam le ID 1 Description
p
Collection `� E v o
Collection c�
Time o o
0 M x x o
O j O Lo ¢ rn
a U1 ¢
Remarks 1 Cooler I.p.
{Conlainom for each sample may be combined on one line)
a
Date(s) (military) (] ¢
T N M m N
N S Z 0 L ❑
CD-1s
11/17/2021 1425 G x
1 2 X x -
Wl(18606001
OVA- L
t
level 2 with excel +
NCDEQ EQUIS
Turn Armnd Time Required (Prior lab approval required for expedited ed TAT) Sample Disposal
Possibla Hazard Idaril ification [List any known hazards in the remarks}
QC Requirements
El Standard ❑ Rush (Please Specily)
7.10 business days ❑ Return to Client
Disposal by Lab ❑ Non -Hazardous ❑ Flammable ❑ Skin lr*anl ❑ 809 provlded ❑ unknown
method re rd CC
1. Relinquished by
Date
Time I. Received by Dale
Time
a�Li
all/I,t
oo
2. Relinquished by
to
T�rrre P- Received qy Date
i -�
T e
--o
3- Relinquished by
Date
Time 3. Received by Date
Time
A. Relinquished by
Date
Time G. Laboratory Received by Date
Time
Note: All samples are
retained for four weeks from
LAB USE ONLY Receipt Temp.
o
Temp, Blank
El 1 ❑N
receipt unless ether arran ements are made
Received on Ice {Check) ❑ Y ❑ N ❑ Ice Pack C
t� tag
Pace Gulf Coast Report#: 221113091 Page 10 of 11

/.5navivfica' SAMPLE RECEIVING CHECKLIST IINIIIIYII9II III
SAMPLE DELIVERY GROUP
221113091
CHECKLIST
YES
NO
Client PM RWe
Transport Method
Samples received with proper thermal preservation?
*❑
❑
Shealy Envir - Pace Analytical
FEDDC
Services South Carolina
Radioactivity is <1600 cpm? If no, record cpm value in notes section.
COC relinquished and complete (including samplelDs, collect times, and sampler)?
*❑
*❑
❑
❑
Profile Number
Received By
288352
Fbberts, George S.
All containers received in good condition and within hold time?
All sample labels and containers received match the chain of custody?
0
0
❑
❑
Line Item(s)
Receive Date(s)
1 - VFA
11/30/21
2- hydrogen
Preservative added to any containers?
❑
0
If received, was headspace for VOC water containers < 6mm?
0
❑
Samples collected in containers provided by Pace Gulf Coast?
0
❑
COOLERS
DISCREPANCIES
LAB PRESERVATIONS
Airbill Thermometer ID: E34
Temp °C
None
None
166334661961
0.5
NOTES
Revision 1.6
Page 1 of 1
Pace Gulf Coast Report#: 221113091
Page 11 of 11

Appendix B

NC Division of Waste Management - Solid Waste Section
Landfill Gas Monitoring Data Form
Notice: This /him and nm ie fiu nmlion pNrrcfr rf to it erne "Pablic Records"as elyined in NC General Statute 133-1. Is such, these doc•uwews arc
available for in.sy)ection and erammavem br anY person neon request (NC General Statnte 132-6)
Facility Name: q 4d
Sampling bate: I ! I I NC Landfill Rule
Sample Collector Name & Position:
Gas Meter Type & Serial Number:_, t" em, 9,110 r ��
Field Calibration Date & Time:
Field Calibration Gas Type (15/15 oil 35/50
Permit Number: —G
or. 1600):
Gas Meter Calibration Date:
eld Calibration Gas Canister Expiration Date:
Gas Meter Pump Rate:
J c�
Ambient Air Temperature: / arametnic Pressure (in. or mm Hg): A�leather Conditions: ",Ajh — F],f
Instructions: Under "Location or LFG ell", list monitorin well"# or describe monitoring location (e.g., inside field office).
,._ .
Attach a test location ma or draMn . Report methane readings as both % LEL and % CH4 by volume.
Convert % CTI4 (by volitn e) to % LEL as follows: % methane (by volume)/20 = % LEL.
*Hydrogen Sulfide (1-12S gas monitoring rnav be required for Construction & Demolition Landfills (CDLFs). See
individual permit conclitidr s and/or Facility LFG monitoring plan.
Location or
Sample
Time
LFG Wcll ID
Tube
Purge
Time of
Day
Pumpe
(sec)
Initial
% LEL
Stabilized
% LEL
% CH4
(volume)
"j O2
(volume)
%CO2
(volume)
% 112S*
(volume)
6
E
l
C)
o
©
1. 3
o
v
w%7fL
o
j
o
o
,6
o
a
o
�Q��
a
,�
O
��
D
6ri✓
0,5
5 eC
t r
r5
v
6 l7
Vad�-ecLI eo 0 C-' lo,6 O,(P
NOTE. If needed, altacb additional data forms to i ctnde additional LFG monitoring data locations• or thefac•iliw
ACTION LG VGLS: Methane: >1.25'%1a volume (inside structures) AND >5% by volume (at facility boundary)
Hydrogen Sulfide: > .'% by volume (inside structures) AND >4% by volume (at facility boundary)
Certification
To the best of my knowledge, the
are true and correct. I am aware
or certification includinLy the nos!
NOTES
ormation reported and statements made on this data submittal and attachments
It there are significant penalties for making any false statement, representation,
lity of a fine and imprisonment.
TIT.L C
Revised — March 6, 2017

NC Dfivision of Waste Management - Solid Waste Section
Landfill Gas Monitoring Data Form
Notice: This form and cum it jot oration aNat•b •d la a ar'c "Public Records" as defined in NC General Slaltne 132-1 As such, Nrese docmncuts arc
available for inspection and e.retmtna. ran hY an1- person rnpon request (NC General Slatnte 132-6)
Facility
Sampling
Sample Collector Name & Position:
Gas Meter Type & Serial Number:
Field Calibration Date & Time:
Field Calibration Gas Type (15/15 os 35/50):
Gas Meter Pump Rate:
Ambient Air
Permit Number:
C Landfill Rule (.0500 or.] 600):
Gas Meter Calibration Date:
Calibration Gas Canister Expiration Dale_
Pressure (in. or mm Hg): Weather Conditions:
Instructions: Under "Location or LFG ell", list monitoring well # or describe monitoring location (e.g., inside field office).
Attach a test location ma or drawin . Report methane readings as both % LEL and % CH4 by volume.
Convert % CH4 (by volur? e) to % LEL as follows: % methane (by volume)/20 = % LEL.
*Hydrogen Sulfide (H25'A, gas monitoring Ingi, be required for Construction & Demolition Landfills (CDLFs). See
individual permit corditir ?s and/or Facility LFG moniloring plan.
Location or
LPG Wc11 ID
S ample
Tube
Purge
Time of
Day
Time
Pumped
(sec)
Initial
% LEL
Stabilized
% LEL
% C144
(volume)
% O2
(volume)
% CO2
(volume)
% 112S'
(vulume)
NOTES
di&VL/qec-
(0
o
/0
D
0,
Gu
Tr U
C) o
'e
D
0
0- G
o
(QeSG�
o
3
b
^/, 3
0.3
b
�' �
(eo
t
o
0
0
/,2
v .3
o
:qq
a
!.
a (?C
d
°1
0
I
NOTE: 1f needed, allach additional data forms to i elide additional LFG monitoring data locations/or the facilitp.
ACTION LEVELS: Methane: >1.25'% b volume (inside structures) AND >5'%, by volume (at facility boundary)
Hydrogen Sulfide: `%, by volume (inside structures) AND >4% by volume (at facility boundary)
Certification
To the best of my knowledge, the
are true and correct. I am aware
or certification including the pas:
SIGNATURE
rmation reported and statements made on this data submittal and attachments
there are significant penalties for making any false statement, representation,
ty of a fine and imprisonment.
TITLE
Revised — March 6, 2017

INSTRUMENT CALIBRATION REPORT
Pine Environmental Services LLC
3901 Coconut Palm Dr. Stc 107
Tampa, FL 33619
Direct: 813-620-1001
Pine Environmental Services, Inc.
Instrument ID 23223
Description GEM 5000
Calibrated 9/9/2021 10:02:02AM
Manufacturer
CES Landtec
State Certified
Model Number
GEM 5000
Status Pass
Serial Number/ Lot
G500544
Temp °C 24
Number
Location
Florida
Humidity % 50
Department
Calibration Specifications
Group # 1
Range Ace %
0.0000
Group Name Methane
Reading Ace %
3.0000
Stated Accy Pct of Reading
Plus/Minus
0.00
Nom In Val / In Val In Type Out Val
Out Type
Fnd As
Lft As
Dev%
Pass/Fail
50.00 / 50.00 %Volume 50.00
%Volume
50.90
50.00
0.00%
Pass
Group # 2
Range Ace %
0.0000
Group Name Carbon Dioxide
Reading Ace %
3.0000
Stated Accy Pct of Reading
Plus/Minus
0.00
Nom In Val / In Val In Type Out Val
Out Type
Fnd As
LftAs
Dev%
Pass/Fail
35.00 / 35.00 %Volume 35.00
%Volume
36.00
35.00
0.00%
Pass
Group # 3
Range Ace %
0.0000
Group Name Oxygen
Reading Ace %
3.0000
Stated Accy Pct of Reading
Plus/Minus
0.00
Nam In Val / In Val In Type Out Val
Out Type
Fnd As
Lft As
Dev%
Pass/Fail
4.00/4.00 % 4.00
%
4.00
4.00
0.00%
Pass
Group # 4
Range Ace %
0.0000
Group Name CARBON MONOXIDE
Reading Ace %
3.0000
Stated Accy Pct of Reading
Plus/Minus
0.00
Nom In Val / In Val In Type Out Val
Out Type
Fnd As
Lft As
Dev%
Pass/Fail
50.00 / 50.00 PPM 50.00
PPM
50.90
50.00
0.00%
Pass
Group # 5
Range Ace %
0.0000
Group Name HYDROGEN SULFIDE
Reading Ace %
3.0000
Stated Accy Pct of Reading
Plus/Minus
0.00
Nom In Val / In Val In Type Out Val
OutType
Fnd As
Lft As
Dev%
Pass/Fail
10.00 / 10.00 PPM 10.00
PPM
12.00
10.00
0.00%
Pass
Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663
www.pine-environmental.com

INSTRUMENT CALIBRATION REPORT
Pine Environmental Services LLC
3901 Coconut Palm Dr. Ste 107
Tampa, FL 33619
Direct: 813-620-1001
Pine Environmental Services, Inc.
Instrument ID 23223
Description GEM 5000
Calibrated 9/9/2021 10:02:02AM
Test Instruments Used During the Calibration
(As Of Cal Entry Date)
Serial Number /
Next Cal Date /
Test Standard 1D
Description
Manufacturer
Model Number Lot Number
Last Cal Date/ Expiration Date
Opened Date
50% CH4-35%
AB 50 CH4/35 CO2
American Gas
GP12116 0218FC22
3/l/2015 9/28/2021
CO2
Group
AB 1000 CO2
AB 1000 CO2 50 1-12S
Airgas
GAQ-408BST-1 GAQ-408BST-
11/21/2020
50 1-12S
LOTGAQ408BSTI
1
LOTGAQ408BS
T1
Notes about this calibration
Calibration Result Calibration Successful
Who Calibrated Danny Moore
All instruments are calibrated by Pine Environmental Services LLC according to the manufacturer's
specifications, but it is the customer's responsibility to calibrate and maintain this unit in accordance with the
manufacturer's specifications and/or the customer's own specific needs.
Notify Pine Environmental Services LLC of any defect within 24 hours of receipt of equipment
Please call 800-301-9663 for Technical Assistance
Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663
www.pine-environmental.com

NCD
Notice: This fhrnn unrl un y it fornuttion
availahle for inspection and ei
Facility N
sion of Waste Management - Solid Waste Section
Landfill Gas Monitoring Data Form
to it are "Public Records" as defined in NC General Statute 132-1..Is such, th"e doclllnellls aa'e
v h , any person upon request (NC General Stuhlte 132-6)
t Number: / f-0-�2
I
Sampling Date: � _ 9 � A�NNC Landfill Rule (.0500 or.1600):
Sample Collector Name & Position: 0+i�ali �''r d rf�J SCjc.lprtY���r
Qp0 J
Gas Meter Type & Serial Number: �e^ 7 � Gas Meter Calibration Date:
Field Calibration Date & Time:
Field Calibration Gas Type (15/15 ti f 35/50):
Gas Meter Pump Rate;
Ambient Air Temperature: u
Field Calibration Gas Canister Expiration Date:
Pressure (in. or mm Hg): Weather Conditions: -)-ee /t//
Instructions: Under "Location or LFG ell", list monitoring well # or describe monitoring location (e.g., inside field office).
Attach a test location map or drawing. Report methane readings as both % LEL and % CHa by volume.
Convert % CtI4 (by volun e) to % LEL as follows: % methane (by volume)/20 = % LEL.
*Hydrogen Sulfide (HZS gas monitoring ntah be required for Construction & Demolition Landfills (CDLFs). See
individual permis it conditi and/or Facility LFG monitoring plan.
Location or
LFG Location
WelI
Sample
Tube
Purge
Time of
Day
Time
Pumpe
Initial
% LEL
Stabilized
% LEL
% Cli4
(volume)
"� 02
(volume))
% CO2
(volume)
% 112S*
(volume)
NOTES
50¢ 46
pb
/(see)
(1N
e� 6
Qr
"D
a� 7
d,
o
W(
ba5gc
3 =/3�
(��
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d./
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Pofee-
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o,
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(a
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o
(0 Ix
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Q
�o
.r ,
�
o
O
h, S
6° 3
o
t°c
A' o
t7
(7
a
p
I
NOTE. If needed, altach additional data forms to i chile additional LFG monitoring data locations for the facility.
ACTION LEVELS: Methane: >1.25'%l b volume (inside structures) AND >5% by volume (at facility boundary)
Hydrogen Sulfide: � %. by volume (inside structures) AND > 1% by volume (at facility boundary)
Certification
To the best of my knowledge, the
are true and correct. I am aware
or certification includint= thrL�s!
rmation reported and statements made on this data submittal and attachments
there are significant penalties for making any false statement, representation,
ly of a fine and imprisonment.
TITLE
Revised — March 6, 2017

NC D Ision of Waste Management - Solid Waste Section
Landfill Gas Monitoring Data Form
Notice: This li+rm and nn,t i+fornxNiun etaercl+ d to it are 'Public• Records"as atgined in NC General57atute 132-1. ,Is sne•h, these docmnenls are
mailable %nr• in.cpec•lion and stet+++Tarr inu ht� arm per.rnn rgton request (NC General Sh+h+le 133-(>)
Facility N
Sampling Date:
Sample Collector Name & Position:
Gas Meter Type & Serial Number:
Field Calibration Date & Time:
Field Calibration Gas Type (15115 all 35/50):
Gas Meter Pump Rate:
Ambient Air Temperature. -
Permit Number:
C Landfill Rule (.0500 or.1600):
Gas Meter Calibration Date:
d Calibration Gas Canister Expiration Date -
is Pressure (in. or mm Hg): Weather Conditions:
Instructions: Under "Location or LFG ell", list monitoring well # or describe monitoring location (e.g., inside field office).
Attach a test location mar or drawing. Report methane readings as both % LEL and % CH4 by volume.
Convert % CT14 (by solun e) to % LEL as follows: % methane (by volume)/20 = % LEL.
*Hydrogen: Sulfide (112S gas monitoring may be required for Construction & Demolition Landfills (CDLFs). See
individual permit candific Pt.v and/or Facility LFG monitoring plan.
Location or
LFG Well ID
S ample
Tube
Purge
b
Time of
Da Y
Time
Pumpec
(see)
sec
Initial
% LEL
Stabilized
% LEL
% CH4
(volume)
% O2
volume
(Volume)
% CO2
(volume)
)
% H2S*
(volume)
)
NOTES
oij"Rk
/a`55
6
c
0
iv
o+a
�J
ec
7
to ec-1
Q
0
o-)fc
9- /S
o
/ 0
0,0
b
f
v ec
9-4)5,
9zi
O
o.7
U,
NOTE: If needed, attach additional data forms to i elude additional LFG monitoring data locations%r thefirc•ilih,.
ACTION LEVELS: Methane: >1.25'% ii volume (inside structures) AND >5'Y" by volume (at facility boundary)
Hydrogen Sulfide: > :"/o by volume (inside structures) AND >4% by volume (at facility boundary)
Certification
To the best of my knowledge, the
are true and correct. I am aware
or,Fertifica Lion including the pos!
TURE
rmation reported and statements made on this data submittal and attachments
there are significant penalties for making any false statement, representation,
ty of a fine and imprisonment.
TITLE
Revised — March 6, 2017

INSTRUMENT CALIBRATION REPORT
Pine Environmental Services LLC
11669 Lilburn Park Rd.
St. Louis, MO 63146
Office: 314.344.1079
Pine Environmental Services, Inc.
Instrument ID
43637
Description
GEM 5000
Calibrated
11/29/2021 1:34:55PM
Manufacturer
CES Landtec
State Certified
Model Number
GEM5000
Status Pass
Serial Number/ Lot
G505247
Temp °C 22
Number
Location
St. Louis
Humidity % 16
Department
Calibration Specifications
Group # 1 Range Acc % 0.0000
Group Name Methane Reading Acc % 3.0000
Stated Accy Pct of Reading Plus/Minus 0.0
Nom In Val / In Val In Type Out Val Out Type Fnd As Lft As
50.0 / 50.0 %Volume 50.0 %Volumc 50.0 50.0
Group # 2
Group Name Carbon Dioxide
Stated Accy Pct of Reading
Nom In Val I In Val In Type Out Val
35.0/35.0 %Volume 35.0
Group # 3
Group Name Oxygen
Stated Accy Pct of Reading
Nom In Val / In Val In Type Out Val
20.9/20.9 %Volume 20.9
Group # 4
Group Name Hydrogen Sulfide
Stated Accy Pct of Reading
Nom In Val / In Val In Type Out Val
1000 / 1000 PPM 1000
Out Type
%Volume
Range Acc %
0.0000
Reading Acc %
3.0000
Plus/Minus
0.0
Fnd As
Lft As
35.0
35.0
Range Acc %
0.0000
Reading Acc %
3.0000
Plus/Minus
0.0
Out Type Fnd As
Lft As
%Volume 20.9
20.9
Out Type
PPM
Range Acc %
0.0000
Reading Acc %
3.0000
Plus/Minus
0
Fnd As
Lft As
980
1,000
Dev% Pass/Fail
0.00% Pass
Dev% Pass/Fail
0.00% Pass
Dev% Pass/Fail
0.00% Pass
Dev% Pass/Fail
0.00% Pass
Group # 5 Range Acc % 0.0000
Group Name CO Reading Acc % 3.0000
Stated Accy Pct of Reading Plus/Minus 0
Nom In Val / In Val In Type Out Val Out Type Fnd As Lft As Dev% Pass/Fail
50150 PPM 50 PPM 47 50 0.00% Pass
Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663
www.pine-environmental.com

INSTRUMENT CALIBRATION REPORT
Pine Environmental Services LLC
11669 Lilburn Park Rd.
St. Louis, MO 63146
Office: 314.344.1079
Pine Environmental Services, Inc.
Instrument ID 43637
Description GEM 5000
Calibrated 11/29/2021 1:34:55PM
Test Instruments Used During the Calibration
(As Of Cal Entry _Date}
Serial Number /
Next Cal Date /
'rest Standard ID
Description Manufacturer
Model Number Lot Number
Last Cal Date/ Expiration Date
Opened Date
NC 50 35
NC 50 CH4/35 CO2 Gasco
GP 12126 - 31803 CBJ-399-1
2/8/2023
CBJ-399-1
NC CO
CARBON Pine
BBH-408BST-
1000/1-12S50
MONOXIDE/HYDRO
1
GEN SULFIDE
Notes about this calibration
Calibration Result Calibration Successful
Who Calibrated Danny Moore
All instruments are calibrated by Pine Environmental Services LLC according to the manufacturer's
specifications, but it is the customer's responsibility to calibrate and maintain this unit in accordance with the
manufacturer's specifications and/or the customer's own specific needs.
Notify Pine Environmental Services LLC of any defect within 24 hours of receipt of equipment
Please call 800-301-9663 for Technical Assistance
Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663
www.pine-enviromnental.com