2021.09.28_CCO.p11d_FINAL_P11(d)_Semi-Annual_Report

CHARACTERIZATION OF PFAS IN
PROCESS AND NON-PROCESS
WASTEWATER AND STORMWATER
Ongoing Sampling – 2021 Quarters 1 and 2
Semi-Annual Report

Prepared for
The Chemours Company FC, LLC
22828 NC-87
Fayetteville, NC 28306

Prepared by
Geosyntec Consultants of NC, P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
Geosyntec Project Number TR0807E

September 28, 2021
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TABLE OF CONTENTS
1. INTRODUCTION ................................................................................................ 1
2. BACKGROUND .................................................................................................. 2
2.1 Paragraph 11(c) Reporting Background ...................................................... 2
2.2 Site and Conveyance Network Background ................................................ 3
2.2.1 Locations and Location Categories ................................................. 4
2.3 Paragraph 11(c) Conclusions and Recommendations ................................. 5
2.4 Summary of Recent Site Work to Mitigate PFAS Contributions to Outfall
002 7
3. SEMI-ANNUAL REPORT OBJECTIVES .......................................................... 7
4. PARAGRAPH 11(D) METHODS AND SCOPE ................................................ 8
4.1 Sample Locations ........................................................................................ 8
4.2 Field Methods .............................................................................................. 9
4.2.1 General Field Methods .................................................................... 9
4.2.2 Grab Sampling Methods ................................................................. 9
4.2.3 Temporal Composite Sampling Methods ..................................... 10
4.2.4 Wet Event Sampling Methods ...................................................... 10
4.3 Laboratory Methods .................................................................................. 10
5. ASSESSMENT OF PARAGRAPH 11(D) ONGOING SAMPLING ................ 11
5.1 Presentation of Results Table 3+ 17 Compounds ...................................... 11
5.2 Results - First Semiannual Period (2021 Quarters 1 and 2) ...................... 12
5.2.1 Data Quality .................................................................................. 13
5.2.2 Field Parameter Data ..................................................................... 13
5.3 Conveyance Network PFAS Data Observations ....................................... 14
6. SUMMARY AND RECOMMENDATIONS .................................................... 16
7. REFERENCES ................................................................................................... 18

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LIST OF TABLES
Table 1: Paragraph 11(d) Sample Location Summary
Table 2: PFAS and Associated Analytical Methods
Table 3: Total Daily Precipitation – 2021 Quarters 1 and 2

LIST OF FIGURES
Figure 1: Site Location Map
Figure 2: Paragraph 11(d) Sample Locations – Prior to Stormwater Treatment System and
Terracotta Pipe Activities
Figure 3: Paragraph 11(d) Sample Locations – After Stormwater Treatment System and
Terracotta Pipe Activities
Figure 4A: Total Table 3+ Concentrations – Non-Chemours Process Wastewater
Figure 4B: Total Table 3+ Concentrations – Non-Contact Cooling Water
Figure 4C: Total Table 3+ Concentrations – Stormwater
Figure 4D: Total Table 3+ Concentrations – Stormwater-Non-Contact Cooling Water
Figure 4E: Total Table 3+ Concentrations – Wastewater Treatment Plant
Figure 4F: Total Table 3+ Concentrations – Combined Flows to Outfall 002
Figure 5A: Distribution of Table 3+ Concentrations – All Locations
Figure 5B: Distribution of Total EPA Method 537 Mod Concentrations – All Locations
Figure 6: Proposed Paragraph 11(d) Sample Locations

LIST OF APPENDICES
Appendix A: Analytical Results – Paragraph 11(d) Sampling Events
Appendix B: Field Parameters
Appendix C: Laboratory Reports and Data Review Narrative Whitebooks

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ACRONYMS AND ABBREVIATIONS
CO Addendum Addendum to Consent Order Paragraph 12
DEQ The North Carolina Department of Environmental Quality
DVM Data Verification Module
EIM Environmental Information Management
EPA Environmental Protection Agency
EPA 537M EPA Method 537 Mod
HDPE high-density polyethylene
Hydrolyzed PSDA 2-fluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-tetrafluoro
sulfoethoxy)propoxy]-acetic acid
IXM ion exchange materials
mV millivolts
NCCW non-contact cooling water
ng/L nanograms per liter
NTU nephelometric turbidity unit
ORP oxidation reduction potential
PFAS per- and polyfluoroalkyl substances
PPA Polymer Processing Aid
QA/QC quality assurance/ quality control
R-EVE 4-(2-carboxy-1,1,2,2-tetrafluoroethoxy)-2,2,3,3,4,5,5,5-
octafluoro-pentanoic acid
R-PSDA 2,2,3,3,4,5,5,5-octafluoro-4-(1,1,2,2-tetrafluoro-2-
sulfoethoxy)-pentanoic acid
RPD relative percent difference
SOP Standard Operating Procedure
SWTS Stormwater Treatment System
WWTP Wastewater treatment plant
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1. INTRODUCTION
This report was prepared by Geosyntec Consultants of NC, P.C. (Geosyntec) for The
Chemours Company FC, LLC (Chemours) as the first semiannual report for Ongoing
Sampling of the concentrations of per- and polyfluoroalkyl substances (“PFAS”) in
process wastewater, non-process wastewater, and stormwater at the Chemours
Fayetteville Works, North Carolina site (the Facility, Figure 1). This is the first
semiannual report addressing paragraph 11(d) of the Consent Order amongst Chemours,
the North Carolina Department of Environmental Quality (DEQ), and Cape Fear River
Watch, entered into court on February 25, 2019.
This semiannual report is a continuation of bimonthly sampling and quarterly reporting
conducted under paragraph 11(c) of the Consent Order, which was an 18-month Initial
Characterization of PFAS concentrations in the process wastewater, non-process
wastewater, and stormwater at the Facility that is discharged through Outfall 002. At the
culmination of the 18-month paragraph 11(c) Initial Characterization period, a final report
summarized the findings of the paragraph 11(c) sampling events and provided
recommendations for transitioning to paragraph 11(d), Ongoing Sampling. An addendum
to the final report was submitted on May 28, 2021 to report bimonthly samples collected
in October 2020 and November 2020. Chemours is awaiting comment from DEQ
regarding these recommendations. As such, recent sampling conducted under the
Ongoing Sampling program was consistent with sampling conducted during the Initial
Characterization period.
This semiannual report summarizes the findings for the first three (3) paragraph 11(d)
sampling events during 2021 Quarters 1 and 2 and provides further support for
implementing the recommendations proposed at the conclusion of the paragraph 11(c)
Initial Characterization period. The remainder of this document is organized as follows:
 Section 2 – Background: this section describes the Facility, the conveyance
network which transmits flow to Outfall 002, locations sampled and location
categories, and conclusions from the paragraph 11(c) Initial Characterization
period;
 Section 3 – Semi-Annual Report Objectives: this section describes the
objectives of this report;
 Section 4 – Paragraph 11(d) Methods and Scope: this section describes the
methods employed for sample collection and analysis for 2021 Quarters 1 and 2;
 Section 5 – Assessment of Paragraph 11(d) Ongoing Sampling: this section
describes PFAS concentrations trends and observations in investigative samples
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over the first semiannual period in context with paragraph 11(c) observations
(2021 Quarters 1 and 2);
 Section 6 – Summary and Recommendations: this section summarizes the
observations of results from the first semiannual period and recommended
changes to the sampling plan for ongoing sampling activities pursuant to
paragraph 11(d) of the executed Consent Order; and
 Section 7 – References: this section lists the documents referenced in the report.
2. BACKGROUND
This section provides a summary of past paragraph 11(c) quarterly reports, an overview
of how the Facility uses water, the types of water present at the site, how this water flows
to the Facility’s discharge point at Outfall 002, how the locations sampled as part of
paragraph 11(c) and paragraph 11(d) are grouped for interpretation, and an overview of
recent site work conducted to mitigate PFAS contributions to Outfall 002.
2.1 Paragraph 11(c) Reporting Background
Chemours submitted the PFAS Characterization Sampling Plan (the Sampling Plan) to
DEQ on May 6, 2019 (Geosyntec, 2019a) and received written approval to implement the
program from DEQ on June 19, 2019. Past quarterly reports for the Initial
Characterization Period have summarized the activities conducted during the previous
quarter, reported observed trends in context to previous bimonthly sampling events, and
provided recommendations to implement during the next quarter. A summary of the
bimonthly sampling events and supplemental investigations included in past quarterly
reports for the Initial Characterization period are provided in the table below.
Quarterly
Report
No.
Date
Submitted Activities Summarized Reference
1 July 31,
2019
April 2019 and June 2019 bimonthly
sampling events collected in 2019 Quarter 2
Geosyntec,
2019b
2 October
31, 2019
August 2019 bimonthly sampling event
collected in 2019 Quarter 3 and
supplemental investigations completed in
2019 Quarters 2 and 3
Geosyntec,
2019c
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Quarterly
Report
No.
Date
Submitted Activities Summarized Reference
3 January
31, 2020
October 2019 and December 2019
bimonthly sampling events collected in 2019
Quarter 4
Geosyntec,
2020a
4 April 30,
2020
January 2020 bimonthly sampling event
collected in 2020 Quarter 1
Geosyntec,
2020b
5 July 31,
2021
April 2020 and May/June 2020 bimonthly
sampling events collected in 2020 Quarter 2
Geosyntec,
2020c
6 (Final) December
18, 2021
Overall conclusions and recommendations
from the paragraph 11(c) Initial
Characterization period; August 2020
bimonthly sampling event collected in 2020
Quarter 3
Geosyntec,
2020d
Addendum
1
May 28,
2021
October 2020 and November 2020
bimonthly sampling events collected in 2020
Quarter 4 – these bimonthly events were
collected after Initial Characterization
period and prior to the beginning of Ongoing
Sampling
Geosyntec,
2021a
2.2 Site and Conveyance Network Background
Chemours and the two Faytetteville Works site tenants, Kuraray and DuPont, currently
operate five manufacturing areas on the site along with two other areas servicing
manufacturing activities. These areas are shown in Figure 1 and listed below:
 Chemours Monomers/Ion Exchange Materials (Monomers/IXM);
 Chemours Polymer Processing Aid (PPA) Area;
 Kuraray Trosifol® Leased Area;
 Kuraray SentryGlas® Leased Area;
 DuPont Polyvinylfluoride Leased Area;
 Wastewater treatment plant (WWTP); and
 Power Area at the Facility (produces filtered water and demineralized water).
These various areas both use and produce water which flow through the site conveyance
network to Outfall 002. The site conveyance network waters are comprised of three (3)
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water types and five (5) primary flow pathways as they combine at Outfall 002. The water
types and flow pathways at the Facility are listed below:
Water Types
1. Process wastewater (Note: Chemours process wastewaters are presently disposed
of offsite while tenant [Kuraray and DuPont] process wastewaters are treated at
the onsite WWTP prior to discharge);
2. Non-Process Wastewater (Note: Non-Process Wastewater is also commonly
called non-contact cooling water [NCCW] or steam condensate); and
3. Stormwater.
Flow Pathways
1. Monomers/IXM Conveyance Network (formerly Cooling Water Channel, see
Section 2.4), which transmits NCCW and stormwater from the Chemours
Monomers/IXM area;
2. Wood Lined Trench, which transmits NCCW from Kuraray areas and stormwater
from Kuraray and limited areas in the Chemours PPA area;
3. Wastewater Treatment Plant Discharge, which transmits treated waters from the
WWTP;
4. DuPont Area Ditches, which transmit NCCW and stormwater from DuPont; and
5. Open Channel to Outfall 002, which combines the above flows and transmits and
discharges them through Outfall 002.
2.2.1 Locations and Location Categories
Sample locations have been grouped into seven location categories developed to facilitate
analysis and interpretation of data collected during this program. The location categories
were developed based on locations having either (a) a common type of water (e.g.,
NCCW), or (b) a common spatial and flow path relationship (e.g., WWTP related
locations). The seven categories are listed and briefly described below:
Location Category Description
Intake River Water at Facility Represents background PFAS concentrations
Non-Chemours Process Wastewater Locations representing process wastewater from
Kuraray and DuPont
Non-Contact Cooling Water Locations representing NCCW from Kuraray
and Chemours
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Location Category Description
Stormwater Locations containing only stormwater from
throughout the Facility
Stormwater-Non-Contact Cooling
Water
Locations representing commingled stormwater
and NCCW
Wastewater Treatment Plant Locations representing the WWTP influent and
effluent and the Terracotta pipe, which prior to
November 2017 transmitted Chemours process
wastewater to the WWTP and was fully
decommissioned in April 2021
Combined Flows to Outfall 002 Locations representing stormwater, NCCW, and
process wastewater from the combined flow
pathways at the Facility in the Open Channel to
Outfall 002

2.3 Paragraph 11(c) Conclusions and Recommendations
Chemours collected samples pursuant to the Sampling Plan for nine (9) bimonthly
sampling events during the 18-month Initial Characterization period from April 2019 to
September 2020. Samples were analyzed for EPA Method 537 Mod (EPA 537M) and
Table 3+ Method PFAS. Summarized findings and recommendations from the Initial
Characterization are listed below.
Summary of Findings
The following conclusions were drawn based on the samples collected during the Initial
Characterization period:
 The intake river water at the facility (Location 1) contains PFAS before this water
is used at the Facility. PFAS detected at Location 1 represent the background level
of PFAS at other sampling locations.
 Across all locations, EPA 537M PFAS were not statistically different or higher
than intake data with the exception of one location (23A) on the Terracotta pipe
which was decommissioned as of April 21, 2021.
 Non-Chemours process wastewater locations (Locations 18, 19A, 19B, and 23B)
and NCCW only locations (Locations 6A, 6B, 24A, 24B, and 24C) generally had
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low PFAS concentrations, similar to or less than those observed at the intake river
water at the Facility.
 The primary sources of total Table 3+ PFAS concentrations to Outfall 002 were
(1) locations comprising both stormwater and non-process wastewater from the
Monomers/IXM area, (2) stormwater-only locations, and (3) the WWTP effluent,
including PFAS loadings from the Terracotta pipe (now decommissioned), which
prior to November 2017 transmitted Chemours process water to the WWTP.
The degree of PFAS contributions from the sources outlined in the last bullet above are
expected to be reduced through recent site actions as summarized in Section 2.4.
Summary of Recommendations from Paragraph 11(c) Initial Characterization
Based on the findings from the paragraph 11(c) Initial Characterization, the following
recommendations were made to the sampling program transitions to Ongoing Sampling
in paragraph 11(d):
 Continue analyzing EPA 537M at the intake river water at Location 1 and
Location 20 only;
 Upon completion of the Monomers/IXM stormwater treatment system by June
30, 20211, replace Locations 9, 10, 10A, 24A, 24B, and 24C with one new sample
location representing the combined NCCW (Location 9A);
 Replace locations representing inputs to the WWTP (Locations 6A, 6B, 18, 19A,
19B, 23A, 23B) with ongoing sampling of the WWTP influent (Location 22); and
 Replace stormwater-only Locations 2, 3, 4, and 5 with ongoing sampling of
downstream Location 7A.
Chemours submitted these recommendations to DEQ as a part of the Final Quarterly
Report (Geosyntec 2020d) on December 18, 2021 and requested approval from DEQ to
perform the Ongoing Sampling in accordance with these recommendations by January 8,
2021; DEQ has not yet approved this request. Therefore, recent sampling conducted
under the Ongoing Sampling program was consistent with sampling conducted during the
Initial Characterization period. A follow-up technical discussion between Chemours and
DEQ took place in June 2021 to further clarify the recommendations and request approval
for future sampling events. With submittal of this report, Chemours requests approval

1 The Monomers/IXM stormwater treatment system was operational as of June 30, 2021 and
is currently being monitored in accordance with the Stormwater Treatment System Sampling
Plan (Geosyntec, 2021b).
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from DEQ to perform the Ongoing Sampling in accordance with these recommendations
by October 31, 2021.
2.4 Summary of Recent Site Work to Mitigate PFAS Contributions to Outfall
002
The degree of PFAS contributions from the primary sources identified during the Initial
Characterization Period have been or are being mitigated through on-going actions,
specifically:
 Continued use of the Thermal Oxidizer and other air emissions controls at the
Facility reduces aerial emissions of PFAS. This mitigates future PFAS loading to
surfaces and subsequent stormwater concentrations;
 Sediment is removed annually from onsite conveyance channels. Removal of
sediment prevents the potential transfer of PFAS compounds from the sediment
and soils in the overlying water of Outfall 002;
 The Terracotta pipe, which prior to November 2017 conveyed Chemours PFAS
manufacturing process water, was fully decommissioned in April 2021, reducing
PFAS contributions to the WWTP2; and
 Pursuant to paragraph 4(a) of the Addendum to Consent Order Paragraph 12 (CO
Addendum), a Stormwater Treatment System (SWTS) has been installed and was
operational as of June 30, 2021. The SWTS treats stormwater flows from the
Monomers/IXM Area, up to the 1-inch design storm. This is reducing PFAS
contributions from the Monomers/IXM Area to Outfall 002. Influent and effluent
stormwater is being monitored as a part of the SWTS Sampling Plan (Geosyntec,
2021).
3. SEMI-ANNUAL REPORT OBJECTIVES
This semiannual report summarizes the data from three bimonthly Ongoing Sampling
events that have been collected to characterize PFAS in non-process wastewater, process
wastewater, and stormwater at the Facility. Objectives of the first semi-annual report are
to:
1) Evaluate trends and observations at each location / location category in context
with conclusions drawn from the Initial Characterization Period, and

2 Kuraray process wastewater lines to the WWTP were also reconfigured due to the
decommissioning of the Terracotta pipe, eliminating some sampling locations from the
Sampling Plan (Geosyntec, 2019a)
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2) Review the recommendations made for the Ongoing Sampling program based on
findings from the Initial Characterization period and confirm the results from the
first semiannual period of Ongoing Sampling continue to support those
recommendations.
4. PARAGRAPH 11(D) METHODS AND SCOPE
This section describes the methods implemented for the first semiannual Ongoing
Sampling period including locations sampled, field methods implemented, and laboratory
methods used.
Samples were collected during wet weather on February 18 and 19, 2021 (the February
2021 event); during dry weather on April 26 and 29, 2021 and May 4 and 7, 2021 (the
April/May 2021 event); and during dry weather on June 18, 2021 (the June 2021 event).
This sampling was conducted as outlined in the Sampling Plan (Geosyntec, 2019a), with
adjustments made based on recommendations in prior reports (Geosyntec 2019a, 2019b,
2019c, 2020a, 2020b, and 2020c). The April/May 2021 event was collected over multiple
days due to construction activities including the replacement of the Terracotta pipe and
installation of the SWTS infrastructure. Recommendations made in the Final Quarterly
Report (Geosyntec, 2020d) are awaiting approval from DEQ; however, some changes
were required due to recent site work as discussed in Section 2.4. These changes are
summarized in Section 4.1.
4.1 Sample Locations
Locations sampled are described in Table 1 and shown in Figures 2 and 3. Figures 2 and
3 display the sample locations prior to and after SWTS and Terracotta pipe activities
described in Section 2.4, respectively.
The number of samples collected during the first semi-annual period were thirty (30) in
the wet February 2021 event, twenty-four (24) in the dry April/May 2021 event, and
twenty-one (21) in the dry June 2021 event sampling. Table 1 provides a summary of the
sample locations collected during each event. Samples were not able to be collected from
some locations because they were dry during the sampling event or because recent site
work prohibited sample collection or eliminated the sample locations. Additionally, some
sample locations were added to characterize locations that were no longer accessible due
to recent site work. A summary of the reasoning for samples that were not able collected
or added to the program is listed below:
 Locations 2, 3, 4, 5, 10, 11, and 13 were not sampled during the April/May 2021
and June 2021 events because they were dry.
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 Locations 9 and 10A were not sampled during the June 2021 event due to
construction related to the separation of stormwater and NCCW in the
Monomers/IXM area.
 Locations 23A (Terracotta pipe) and 23B (Kuraray laboratory process
wastewater) were not sampled after the February 2021 event because the
Terracotta pipe was decommissioned on April 21, 2021. The new sample location
representing Location 23B is Location 23C-2.
 Locations 23C-1, 23C-2, and 23C-3 were added to the sampling program as they
came into services after the decommissioning of the Terracotta pipe.
4.2 Field Methods
Field methods used during the Ongoing Sampling period are consistent with methods
documented in previous quarterly reports. The following sub-sections summarize these
field methods.
4.2.1 General Field Methods
Equipment was inspected by the field program supervisor, decontaminated, and
calibrated daily prior to use in the field, according to the manufacturer’s
recommendations. Field parameters (e.g., pH, temperature, turbidity) were measured
with a water quality meter prior to sample collection for grab samples, and for temporal
composite samples, once during composite sampling (collected directly from the water
stream), and once after composite sampling (collected from the autosampler reservoir).
A field notebook and location-specific field forms were used to record information
regarding additional items such as quality assurance/ quality control (QA/QC), sample
identifications, color, odor, and other field observations.
Field QA/QC samples, including blind field duplicates, equipment blanks, field blanks,
and trip blanks were collected in general accordance with the Sampling Plan (Geosyntec,
2019a).
Upon sample collection, labelled and containerized samples were placed inside an
insulated sample cooler with ice. Prior to shipment of the samples to the laboratory, a
chain of custody form was completed identifying sample locations, sample identification
numbers, and specific laboratory analyses to be performed on the samples. Chain of
custody forms were signed by the field personnel relinquishing the samples to the courier
and were signed by the laboratory upon receipt of the cooler.
4.2.2 Grab Sampling Methods
Grab samples were collected from locations where temporal variability over the course
of one day was not expected. These locations include non-process wastewater only
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locations (Locations 6A, 6B, 24A, 24B, and 24C); select process wastewater only
locations (Locations 19A, 19B, and 23B); and the Sediment Basin South location
(Location 21A), as identified in Table 1 and shown on Figure 2. Location 23C-2 was
collected as a grab sample during the April/May 2021 event due to site construction but
was collected as a temporal composite for the June 2021 event and will continue to be
collected as a temporal composite moving forward.
4.2.3 Temporal Composite Sampling Methods
Temporal composite samples were collected during the bimonthly sampling events from
locations where variability was expected to potentially be significant within a short time
frame (e.g., one day). These locations, identified in Table 1 and shown on Figure 2,
include those within the site conveyance network and the intake and outfall locations,
since these locations can have highly variable dissolved and suspended constituent loads
over short time periods. Temporal composite samples were collected using a dedicated
Teledyne 6712C autosampler equipped with a rain gauge, high-density polyethelene
(HDPE) tubing, silicon tubing, and an HDPE sample reservoir. During dry sampling
events, autosamplers integrated water over a four-hour sample collection period. During
wet sampling events, the integration time on the autosamplers was set to correspond to
the duration of the storm event.
4.2.4 Wet Event Sampling Methods
The February 2021 event included a wet sampling event on February 18, 2021 and a dry
sampling event on February 19, 2021. Locations that contain stormwater (Locations 1, 2,
3, 4, 5, 7A, 7B, 7C, 9, 10, 10A, 11, 12, 13, 14, 15, 20, and 21A) were sampled on February
18, 2021 during a storm event. The storm event began on February 18, 2021 at 4:30 AM
and lasted through February 19, 2021 at 7:15 AM; a total of 2.01 inches of rainfall fell
during the storm event. Composite samples were collected over an approximately 8-hour
period. In accordance with the PFAS Characterization Sampling Plan (Geosyntec,
2019a), Locations 6A, 6B, 8, 18, 19A, 19B, 22, 23A, 23B, 24A, 24B, and 24C were
collected during dry weather after rainfall ended on February 19, 2021.
4.3 Laboratory Methods
Samples were analyzed for PFAS by the following methods:
 Table 3+ Laboratory Standard Operating Procedure (SOP); and
 EPA Method 537 Mod Laboratory SOP (EPA 537M).
PFAS reported under each of these methods are listed in Table 2.
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The February 2021 and June 2021 events were analyzed using the low-level Table 3+
SOP method, with minimum reporting limits range from 2 to 20 nanograms per liter
(ng/L). This is consistent with previous sampling conducted under paragraph 11. The
April/May 2021 event was analyzed using the high-level Table 3+ SOP method, with
higher minimum reporting limits ranging from 6.1 ng/L to 620 ng/L depending on the
compound and sample. Elevated reporting limits may potentially result in some analytes
being non-detect which would have otherwise been detected using the low-level Table
3+ SOP method.
Laboratory analyses were performed largely in accordance with the Sampling Plan
(Geosyntec, 2019a) and within the guidelines specified by the laboratory SOPs. The
collection frequency of field duplicates, matrix spike / matrix spike duplicates, trip
blanks, and equipment blanks was largely in accordance with the Sampling Plan
(Geosyntec, 2019a).
All data were reviewed using the Data Verification Module (DVM) within the LocusTM
Environmental Information Management (EIM) system, which is a commercial software
program used to manage data. Following the DVM process, a manual review of the data
was conducted. The data usability, in view of the project’s data quality objectives, was
assessed and the data were entered into the EIM system. Additional details regarding the
data review process are provided in Section 5.2.1.
5. ASSESSMENT OF PARAGRAPH 11(D) ONGOING SAMPLING
This section presents an assessment of the key observations during the first six (6) months
of Ongoing Sampling within the context of observations from the Initial Characterization
period. Observations in this section are based on total Table 3+ concentrations and total
EPA 537M concentrations. The remainder of this section discusses the presentation of
Table 3+ results and PFAS data observations.
5.1 Presentation of Results Table 3+ 17 Compounds
For clarity, the text and figures of this report describe the Table 3+ 17 compound sums
while both Table 3+ 17 compound and Table 3+ 20 compound sums are included in the
tables.
As reported in the Matrix Interference During Analysis of Table 3+ Compounds memorandum
(Geosyntec, 2020e), matrix interference studies conducted by the analytical laboratory
(TestAmerica, Sacramento) have shown that the quantitation of three compounds (R-
PSDA [formerly Byproduct 4], Hydrolyzed PSDA [formerly Byproduct 5], and R-EVE)
is inaccurate due to interferences by the sample matrix in both groundwater and surface
water. Given the matrix interference issues, Total Table 3+ PFAS concentrations are
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TR0807E 12 28-September-21
calculated and presented in the tables of this report in two ways: (i) summing over 17 of
the 20 Table 3+ compounds “Total Table 3+ (sum of 17 compounds)”, i.e., excluding
results of R-PSDA, Hydrolyzed PSDA, and R-EVE; and (ii) summing over 20 of the
Table 3+ compounds “Total Table 3+ (sum of 20 compounds)”. Expressing these data as
a range represents possible values of what these results might be without matrix
interferences. In other words, the sum of all 17 compounds is likely an underestimate of
the actual value while the sum of the 20 compounds is likely an overestimate of the actual
value.
5.2 Results - Semiannual Period (2021 Quarters 1 and 2)
This section describes the data quality, field parameter data, and investigative sample
results from the February, April/May, and June 2021 events. PFAS concentrations for all
sample locations in the February, April/May, and June 2021 events are provided in
Appendix A. Table 3 provides the total daily precipitation within the vicinity of the
Facility and the flow measured at Outfall 002 at the times of sampling events discussed
in this report. Field parameters recorded during the February, April/May, and June 2021
events are provided in Appendix B.
The observations and assessment described in this section are based on the following
figures:
 Figures 4A – 4F present time series plots for total Table 3+ concentrations. Each
time series plot displays the total Table 3+ concentrations observed during each
event of the Ongoing Sampling period at the intake river water at the Facility
(Location 1) and at other locations as grouped by sample location type described
in Section 2.2 (e.g., Stormwater, NCCW, etc.).
 Figures 5A and 5B display the distribution of concentrations total Table 3+ and
total EPA 537M concentration by location for all sampling locations, respectively.
Samples collected prior to January 2021 are displayed in gray to provide
comparison between the Ongoing Sampling period and the Initial
Characterization period.
 The analytical reporting limits associated with the February 2021, April/May
2021, and June 2021 event data were determined by the laboratories. As discussed
in Section 4.3, the Table 3+ reporting limits for April/May 2021 were higher than
previously analyzed samples. Appendix A lists the minimum reporting limits for
non-detected analytes and Figures 4A – 4F symbolizes the April/May event in
orange hatching to differentiate the higher reporting limits. The higher reporting
limits were considered acceptable for this event because all other events,
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TR0807E 13 28-September-21
including the prior nine events during the Initial Characterization Period and the
subsequent June 2021 event were analyzed with lower reporting limits.
TestAmerica analytical reports and the data review narrative whitebooks are provided in
Appendix C.
5.2.1 Data Quality
Data Management and Reporting
Chemours’s Analytical Data Quality Management team currently uses the EIM system
for management of analytical data, xyz Site coordinate data, and field parameter data.
Validation and qualification of data are performed by AECOM who maintains the EIM
system for the Chemours Fayetteville Site. Whitebooks consisting of the data review
narratives and the laboratory analytical reports produced by AECOM summarize the
findings of the DVM and manual review process.
QA/QC Samples
PFAS concentrations for all field QA/QC samples in the February 2021, April/May 2021,
and June 2021 events are reported in Appendix A. The following observations were noted
for the QA/QC samples:
 The relative percent difference (RPD) for field duplicate pairs in the February
2021, April/May 2021, and June 2021 events were generally less than 30% for all
PFAS. Where RPDs were greater than 30%, the reported results may be imprecise
and were J qualified, indicating the results are estimated.
 No PFAS were detected above the associated reporting limits in the February
2021, April/May 2021, and June 2021 Equipment Blanks, Trip Blanks, or Field
Blanks, except for the April/May 2021 equipment blank for the autosampler,
which had PS Acid detected at 2.1 ng/L.
5.2.2 Field Parameter Data
Field parameters recorded during the February, April/May, and June 2021 events are
provided in Appendix B for grab samples and temporal composite samples. Field
parameters were measured using a Horiba U-52 model. The water quality meter was
calibrated at the start of every sampling day.
For grab samples, field parameters were measured once prior to sampling using a flow
through cell. For temporal composite samples once during composite sampling and
collected directly from the water stream.
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Recorded field parameter data observed during the February, April/May, and June 2021
events are generally in accordance with expectations for the sample locations, with the
following exceptions.
 Most locations had recorded pH between 5 and 10. During the February 2021
sampling event, the combined influent to the WWTP (Location 22) had pH
greater than 10. During the April/May 2021 sampling event, DuPont process
wastewater – Plant 1 (Location 19A) had pH less than 5.
 Most locations had recorded dissolved oxygen between 5 and 11 milligrams per
liter. The Chemours PPA area stormwater discharge (Location 3) had the highest
dissolved oxygen measurement at 12.8 milligrams per liter during the February
2021 event.
 Most locations had recorded oxidation reduction potential (ORP) between 20 and
150 millivolts (mV). The DuPont process wastewater - Plant 1 (Location 19A)
had the lowest ORP reading at -11 mV during the April/May 2021 event. The
Kuraray laboratory process wastewater (Location 23C-2) had the highest ORP
reading at 223 mV during the April/May 2021 event suggesting greater contact
with atmospheric oxygen.
 Most locations had recorded turbidity between 0 and 200 nephelometric turbidity
unit (NTU). The combined Chemours Monomers/IXM NCCW and stormwater
discharge (Location 10A) and the WWTP combined influent (Location 22) had
turbidity measurements greater than 200 NTU during the April/May 2021 event
at 376 and 2,253 NTU, respectively.
5.3 Conveyance Network PFAS Data Observations
Observations from the first six months of the Ongoing Sampling period are generally
consistent with previous sampling events and further support the conclusions and
recommendations from the Paragraph 11(c) Final Quarterly Report (Geosyntec, 2020d).
A summary of observations from the first six months of Ongoing Sampling is provided
below.
 The intake river water at the facility (Location 1) continues to contain PFAS
before this water is used at the Facility. PFAS detected at Location 1 represent the
background level of PFAS at other sampling locations.
 Consistent with previous samples collected during the Initial Characterization
period, EPA 537M PFAS across all locations were similar to Location 1, the
intake river water at the Facility (Figure 5B). This continues to support: (1) the
Initial Characterization period conclusion that the site is not a significant
contributor of EPA 537M PFAS to Outfall 002, and (2) the Initial Characterization
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TR0807E 15 28-September-21
period recommendation of analyzing EPA 537M PFAS at Location 1 and
Location 20 (Outfall 002) only.
 The distribution of Table 3+ PFAS for sample locations during the Ongoing
Sampling Period was generally within the range observed from samples collected
in 2019 and 2020 (Figure 5A). Recent site work conducted to reduce PFAS
contributions to Outfall 002, including decommissioning of the Terracotta pipe
and collection and conveyance of stormwater from the Monomers/IXM area to
the stormwater treatment system, was completed in April 2021 and June 2021,
respectively. The impact of this site work in reducing PFAS contributions is
therefore not reflected in the samples collected during the first semiannual period
of Ongoing Sampling and will continue to be evaluated in future bimonthly
sampling events.
 Non-Chemours process wastewater locations (Locations 18, 19A, 19B, 23B, 23C-
1, 23C-2, and 23C-3) and NCCW only locations (Locations 6A, 6B, 24A, 24B,
and 24C) continue to have low PFAS concentrations, similar to or less than those
observed at the intake river water at the Facility (Figure 4A, Figure 4B, Figure
5A, Figure 5B). This supports replacing these locations with ongoing sampling of
the combined influent to the WWTP (Location 22), as recommended in the Final
Quarterly Report (Geosyntec, 2020d).
 Stormwater-only locations continue to show elevated concentrations compared to
the intake river water at the Facility (Location 1), with the highest concentrations
represented at the stormwater-only location in the Monomers/IXM area (Location
10) (Figure 4C). As of June 30, 2021, stormwater from the Monomers/IXM area
is now being collected and treated per CO Addendum paragraph 4(a).
 During the wet February 2021 event, locations comprising both stormwater and
non-process wastewater from the Monomers/IXM area (Locations 7C, 9, 10A,
and 15) showed elevated concentrations compared to the intake river water at the
Facility and other stormwater-NCCW locations (Figures 4D and 4F). Elevated
PFAS concentrations were also reflected in Outfall 002 (Location 20) in the
February 2021 event (Figure 4F). The SWTS was commissioned on June 30, 2021
and was not yet operational for this event; future wet events will evaluate the
effect of stormwater treatment from the Monomers/IXM area on PFAS
concentrations observed at Outfall 002.
 Locations 23A and 23B are no longer a source of PFAS to Outfall 002 because
the Terracotta pipe was decommissioned in April 2021. These locations were
therefore no longer accessible after the February 2021 event and have been
removed from the sampling program (Figure 4B, Figure 4E, Figure 6).
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TR0807E 16 28-September-21
 Locations 24A, 24B, and 24C have been removed from the sampling program
because they are no longer accessible due to the separation of stormwater and
NCCW in the Monomers/IXM area. These sources of water are planned to be
represented at a single point representing combined NCCW from the
Monomers/IXM area in future sampling events (Location 9A, Figure 6).
Based on these observations, the conclusions and recommendations drawn from the
Initial Characterization period are supported, as discussed below. Subsequent bimonthly
sampling during the remaining 18 months of the Ongoing Sampling period will provide
more information on the impact of recent site work on PFAS concentrations at Outfall
002.
6. SUMMARY AND RECOMMENDATIONS
Pursuant to Consent Order paragraph 11(d), this semiannual report summarizes results
and observations from the first three (3) bimonthly sampling events collected during the
Ongoing Sampling period. The objective of the Ongoing Sampling period is to continue
to characterize the concentrations of PFAS in the raw water intake, process wastewater,
non-process wastewater, and stormwater at the Facility.
Observations and trends from the Ongoing Sampling period continue to support the
findings from the Initial Characterization period. Results from the Ongoing Sampling
program support Initial Characterization findings including:
 The intake river water is a background source of PFAS;
 The site is not a significant contributor of EPA 537M PFAS to Outfall 002;
 Non-Chemours process wastewater and NCCW are not significant contributors of
Table 3+ PFAS to Outfall 002; and
 The primary sources of Table 3+ PFAS to Outfall 002 are stormwater-only
locations and locations comprising both stormwater and NCCW from the
Monomers/IXM area. The SWTS was commissioned on June 30, 2021 and is
expected to reduce PFAS concentrations at Outfall 002 with the treatment of
stormwater from the Monomers/IXM area.
Observations from the Ongoing Sampling period also continue to support the
recommendations to the sampling program that were made based on findings from the
Initial Characterization period. These recommendations are summarized based on current
site conditions as follows:
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TR0807E 17 28-September-21
 Continue analyzing EPA 537M at the intake river water at Location 1 and
Location 20 only;
 Replace Locations 9, 10, 10A with one new sample location representing the
combined NCCW at Location 9A;
 Replace the current locations representing inputs to the WWTP (Locations 6A,
6B, 18, 19A, 19B, 23C-1, 23C-2, and 23C-3) with ongoing sampling of the
WWTP influent (Location 22); and
 Replace stormwater-only Locations 2, 3, 4, and 5 with ongoing sampling of
downstream Location 7A.
Based on recent site work, the following locations no longer exist and have been removed
from the sampling program:
 Locations 23A and 23B no longer exist due to the decommissioning of the
Terracotta pipe; and
 Locations 24A, 24B, and 24C no longer exist due to the separation of stormwater
and NCCW for treatment of stormwater from the Monomers/IXM area.
Pursuant to paragraph 11(d), Chemours will continue to collect bimonthly samples to
characterize PFAS in the intake river water, process wastewater, non-process wastewater,
and stormwater at the Facility through December 2022. The proposed sampling locations
for the remainder of paragraph 11(d) are identified in Figure 6. Chemours requests
approval from DEQ to perform the Ongoing Sampling in accordance with these
recommendations by October 31, 2021. Results will continue to be reported semi-
annually, i.e. every-other quarter, within 90 days of the previous semiannual period. The
next semiannual report will be submitted within 90 days of the end Quarter 4, 2021.
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7. REFERENCES
Geosyntec, 2019a. PFAS Characterization Sampling Plan. May 6, 2019.
Geosyntec, 2019b. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Quarterly Report #1. July 31, 2019.
Geosyntec, 2019c. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Quarterly Report #2. October 31, 2019.
Geosyntec, 2019d. Assessment of HFPO-DA and PFMOAA in Outfall 002 Discharge
and Evaluation of Potential Control Options. August 2019.
Geosyntec, 2020a. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Quarterly Report #3. January 31, 2020.
Geosyntec, 2020b. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Quarterly Report #4. April 30, 2020.
Geosyntec, 2020c. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Quarterly Report #5. July 31, 2020.
Geosyntec, 2020d. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Initial Characterization - Final Quarterly Report. December 18, 2020.
Geosyntec, 2020e. Matrix Interference During Analysis of Table 3+ Compounds.
Chemours Fayetteville Works. July 31, 2020.
Geosyntec, 2021a. Characterization of PFAS in Process and Non-Process Wastewater
and Stormwater: Initial Characterization – Final Quarterly Report Addendum 1. May 28,
2021.
Geosyntec, 2021b. Stormwater Treatment System Sampling Plan. May 11, 2021.

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TABLES

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TABLE 1
SUMMARY OF SAMPLES COLLECTED
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
February
(Q1)
April/May1
(Q2)
June
(Q2)
Intake River
Water at
Facility
1 Discharge point of excess river water (i.e., water drawn from the Cape Fear River, but not used
as process water or NCCW) to characterize background levels of PFAS
Intake River Water at
Facility
Temporal
Composite YES YES YES
18 Kuraray process wastewater
Non-Chemours Process
Wastewater
Temporal
Composite YES YES YES
19A DuPont process wastewater, Plant 1
Non-Chemours Process
Wastewater Grab YES YES YES
19B DuPont process wastewater, Plant 2
Non-Chemours Process
Wastewater Grab YES YES YES
23B Kuraray laboratory process wastewater (prior to decommissioning of Terracotta pipe)Non-Chemours Process
Wastewater Grab YES NS2 NS2
23C-1 Kuraray SentryGlas process wastewater (at sump after decommissioning of Terracotta pipe)Non-Chemours Process
Wastewater
Temporal
Composite NS3 YES NS4
23C-2 Kuraray laboratory process wastewater (at sump after decommissioning of Terracottta pipe)Non-Chemours Process
Wastewater
Grab/Temporal
Composite5 NS3 YES YES
23C-3 Kuraray Trosifol process wastewater (at sump after decommissioing of Terracotta pipe)Non-Chemours Process
Wastewater
Temporal
Composite NS3 NS3 YES
6A Kuraray southern leased area NCCW discharge - Vacuum Condenser NCCW Grab YES YES YES
6B Kuraray southern leased area NCCW discharge - Resins Area NCCW Grab YES YES YES
24A Chemours Monomers IXM Vinyl Ethers South NCCW NCCW Grab YES YES YES
24B Chemours Monomers IXM Line 3 and Line 4 Extruder NCCW NCCW Grab YES YES YES
24C Chemours Monomers IXM Water Return Header NCCW NCCW Grab YES YES YES
2 Kuraray northern leased area stormwater discharge Stormwater
Temporal
Composite YES DRY DRY
3 Chemours PPA area stormwater discharge Stormwater
Temporal
Composite YES DRY DRY
4 Combined stormwater discharge from Kuraray northern leased area and Chemours PPA area Stormwater
Temporal
Composite YES DRY DRY
5 Kuraray southern leased area stormwater Stormwater Temporal
Composite YES DRY DRY
10 Chemours Monomers IXM area stormwater discharge Stormwater
Temporal
Composite YES DRY DRY
11 Stormwater discharge from portion of grassy field to north of decommissioned Chemours Teflon
area Stormwater Temporal
Composite YES DRY DRY
7A Combined stormwater and NCCW discharge from western portion of the Facility Stormwater-NCCW
Temporal
Composite YES YES YES
9 Chemours Monomers IXM NCCW and stormwater discharge including stormwater from Vinyl
Ethers South and Vinyl Ethers North Stormwater-NCCW Temporal
Composite YES YES NS6
10A Combined Chemours Monomers IXM NCCW and stormwater discharge Stormwater-NCCW
Temporal
Composite YES YES NS6
12 DuPont area southern drainage ditch stormwater discharge and NCCW Stormwater-NCCW
Temporal
Composite YES YES YES
13 DuPont area northern drainage ditch stormwater discharge and NCCW Stormwater-NCCW
Temporal
Composite YES DRY DRY
14 DuPont area southeast stormwater and NCCW discharge Stormwater-NCCW Temporal
Composite YES YES YES
15 Combined stormwater and NCCW discharge from eastern portion of the Facility Stormwater-NCCW
Temporal
Composite YES YES YES
21A Sediment Basin South Stormwater-NCCW Grab YES YES YES
21B Sediment Basin North Stormwater-NCCW Grab NS7 NS7 NS7
8 Outfall 001 treated non-Chemours process wastewater discharge to open channel to Outfall 002 Wastewater Treatment
Plant
Temporal
Composite YES YES YES
22 WWTP combined influent
Wastewater Treatment
Plant
Temporal
Composite YES YES YES
23A Kuraray northern leased area combined process wastewater and NCCW; open grate on Terracotta
pipe
Wastewater Treatment
Plant
Temporal
Composite YES NS8 NS8
7B Combined stormwater and NCCW discharge from western portion of the Facility and treated
discharge from WWTP
Combined Flows to
Outfall 002
Temporal
Composite YES YES YES
7C Combined stormwater and NCCW discharge from western portion of the Facility, the eastern
portion of the Facility, and the DuPont Area, and treated discharge from WWTP
Combined Flows to
Outfall 002
Temporal
Composite YES YES YES
20 Outfall 002 pipe to Cape Fear River upstream of sump Combined Flows to
Outfall 002
Temporal
Composite YES YES YES
Notes:
Sample Events
February 2021 event (Q1) - 18 and 19 February 2021
April/May 2021 event (Q2) - 26 and 29 April 2021 and 4 and 7 May 2021
June 2021 event (Q2) - 18 June 2021
4 - Location 23C-1 was not sampled in the June 2021 event because the location was offline on the day of sampling.
5 - Location 23C-2 was collected as a grab sample during the April/May 2021 event and as a temporal composite during the June 2021 event.
6 - Locations 9 and 10A were not sampled during the June 2021 event due to construction related to the separation of stormwater and NCCW in the Monomers IXM area.
7 - Location 21B was not sampled to date because this sediment pond was not in use at the time sampling.
8 - Location 23A was not sampled after the February 2021 event because the Terracotta pipe was decommissioned on April 21, 2021.
IXM - ion exchange membrane
NCCW - non-contact cooling water
NS - Not sampled
PFAS - per- and polyfluoroalkyl substances
PPA - polymer processing aid
WWTP - Wastewater treatment plant
Sample
Category Sample Location Description
1 - Samples collected in April 2021 and May 2021 are considered one sampling event, the April/May 2021 event. Sample locations were collected over multiple days due to construction related to the decommissioning of the Terracotta pipe
and separation of stormwater and NCCW in the Monomers IXM area.
Sample Category Sampling
Method
Non-Chemours
Process
Wastewater
Sample Included
in May 2019 PFAS
Characterization
Plan
Sample numbers refer to locations identified in Figures 2 and 3.
Sample Collected
2021
All temporal composite samples collected in dry weather were integrated over 4 hours. Temporal composite samples collected during the storm event in February 2021 were integrated over up to 8 hours to line up with the storm event.
Sample
Location
ID
NCCW
Stormwater
Stormwater-
NCCW
Wastewater
Treatment Plant
2 - Location 23B was not sampled during the April/May 2021 event and during the June 2021 event because the sample location was no longer in service after the decommissioning of the Terracotta pipe. The new sample location representing
this water source is Location 23C-2.
3 - Locations 23C-1, 23C-2, and 23C-3 were added to the sampling program as they came into services after the decommissioning of the Terracotta pipe.
Combined
Flows to Outfall
002
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TABLE 2
PFAS AND ASSOCIATED ANALYTICAL METHODS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
HFPO-DA* Hexafluoropropylene oxide dimer acid 13252-13-6 C6HF11O3
PEPA Perfluoro-2-ethoxypropionic acid 267239-61-2 C5HF9O3
PFECA-G Perfluoro-4-isopropoxybutanoic acid 801212-59-9 C12H9F9O3S
PFMOAA Perfluoro-2-methoxyacetic acid 674-13-5 C3HF5O3
PFO2HxA Perfluoro-3,5-dioxahexanoic acid 39492-88-1 C4HF7O4
PFO3OA Perfluoro-3,5,7-trioxaoctanoic acid 39492-89-2 C5HF9O5
PFO4DA Perfluoro-3,5,7,9-tetraoxadecanoic acid 39492-90-5 C6HF11O6
PMPA Perfluoro-2-methoxypropionic acid 13140-29-9 C4HF7O3
Hydro-EVE Acid 2,2,3,3-tetrafluoro-3-({1,1,1,2,3,3-hexafluoro-3-[(1,2,2,2-
tetrafluoroethyl)oxy]propan-2-yl}oxy)propionic acid 773804-62-9 C8H2F14O4
EVE Acid 2,2,3,3-tetrafluoro-3-({1,1,1,2,3,3-hexafluoro-3-[(1,2,2-
trifluoroethenyl)oxy]propan-2-yl}oxy)propionic acid 69087-46-3 C8HF13O4
PFECA B Perfluoro-3,6-dioxaheptanoic acid 151772-58-6 C5HF9O4
R-EVE Pentanoic acid, 4-(2-carboxy-1,1,2,2-tetrafluoroethoxy)-
2,2,3,3,4,5,5,5-octafluoro 2416366-22-6 C8H2F12O5
PFO5DA Perfluoro-3,5,7,9,11-pentaoxadodecanoic acid 39492-91-6 C7HF13O7
R-PSDA Pentanoic acid, 2,2,3,3,4,5,5,5-octafluoro-4-(1,1,2,2-tetrafluoro-
2-sulfoethoxy)2416366-18-0 C7H2F12O6S
R-PSDCA Ethanesulfonic acid, 1,1,2,2-tetrafluoro-2-[1,2,2,3,3-pentafluoro-
1-(trifluoromethyl)propoxy]2416366-21-5 C6H2F12O4S
Hydrolyzed PSDA Acetic acid, 2-fluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2-
tetrafluoro-2-sulfoethoxy)propoxy]2416366-19-1 C7H3F11O7S
NVHOS
1,1,2,2,4,5,5,5-heptafluoro-3-oxapentanesulfonic acid; or 2-
(1,2,2,2-ethoxy)tetrafluoroethanesulfonic acid; or 1-(1,1,2,2-
tetrafluoro-2-sulfoethoxy)-1,2,2,2-tetafluoroethane
1132933-86-8 C4H2F8O4S
PES Perfluoro-2-ethoxyethanesulfonic acid 113507-82-7 C4HF9O4S
PS Acid
Ethanesulfonic acid, 2-[1-[difluoro[(1,2,2-
trifluoroethenyl)oxy]methyl]-1,2,2,2-tetrafluoroethoxy]-1,1,2,2-
tetrafluoro
29311-67-9 C7HF13O5S
Hydro-PS Acid
Ethanesulfonic acid, 2-[1-[difluoro(1,2,2,2-
tetrafluoroethoxy)methyl]-1,2,2,2-tetrafluoroethoxy]-1,1,2,2-
tetrafluoro
749836-20-2 C7H2F14O5S
PFBA Perfluorobutanoic acid 375-22-4 C4HF7O2
PFDA Perfluorodecanoic acid 335-76-2 C10HF19O2
PFDoA Perfluorododecanoic acid 307-55-1 C12HF23O2
PFHpA Perfluoroheptanoic acid 375-85-9 C7HF13O2
PFNA Perfluorononanoic acid 375-95-1 C9HF17O2
PFOA Perfluorooctanoic acid 335-67-1 C8HF15O
PFHxA Perfluorohexanoic acid 307-24-4 C6HF11O2
PFPeA Perfluoropentanoic acid 2706-90-3 C5HF9O2
PFTeA Perfluorotetradecanoic acid 376-06-7 C14HF27O2
PFTriA Perfluorotridecanoic acid 72629-94-8 C13HF25O2
PFUnA Perfluoroundecanoic acid 2058-94-8 C11HF21O2
PFBS Perfluorobutanesulfonate 375-73-5 C4HF9SO
PFDS Perfluorodecanesulfonate 335-77-3 C10HF21O3S
PFHpS Perfluoroheptanesulfonic acid 375-92-8 C7HF15O3S
PFHxS Perfluorohexanesulfonic acid 355-46-4 C6HF13SO3
PFNS Perfluorononanesulfonate 68259-12-1 C9HF19O3S
PFOS Perfluorosulfonic acid 1763-23-1 C8HF17SO3
PFPeS Perfluoropentane sulfonic acid 2706-91-4 C5HF11O3S
10:2 FTS Fluorotelomer sulfonate 10:2 120226-60-0 C12H5F21O3
4:2 FTS Fluorotelomer sulfonate 4:2 757124-72-4 C6H5F9O3S
6:2 FTS Fluorotelomer sulfonate 6:2 27619-97-2 C8H5F13SO3
8:2 FTS Fluorotelomer sulfonate 8:2 39108-34-4 C10H5F17O3S
NEtFOSAA N-ethyl perfluorooctane sulfonamidoacetic acid 2991-50-6 C12H8F17NO4S
NEtPFOSA N-ethylperfluoro-1-octanesulfonamide 4151-50-2 C10H6F17NO2S
NEtPFOSAE N-ethyl perfluorooctane sulphonamidoethanol 1691-99-2 C12H10F17NO3S
NMeFOSAA N-methyl perfluorooctane sulfonamidoacetic acid 2355-31-9 C11H6F17NO4S
NMePFOSA N-methyl perfluoro-1-octanesulfonamide 31506-32-8 C9H4F17NO2S
NMePFOSAE N-methyl perfluorooctane sulfonamidoethanol 24448-09-7 C11H8F17NO3S
PFDOS Perfluorododecanesulfonic acid 79780-39-5 C12HF25O3S
PFHxDA Perfluorohexadecanoic acid 67905-19-5 C16HF31O2
PFODA Perfluorooctadecanoic acid 16517-11-6 C18HF35O2
PFOSA Perfluorooctane Sulfonamide 754-91-6 C8H2F17NO2S
F-53B Major F-53B Major 73606-19-6 C8HClF16O4S
F-53B Minor F-53B Minor 83329-89-9 C10HClF20O4S
ADONA 4,8-dioxa-3H-perfluorononanoate 958445-44-8 C7H2F12O4
NaDONA NaDONA EVS1361 --
DONA DONA 919005-14-4 --
Notes:
*HFPO-DA may also appear on the EPA Method 537 Mod analyte list
EPA - Environmental Protection Agency
PFAS - per- and polyfluoroalkyl substances
SOP - Standard Operating Procedure
Chemical Formula
EPA Method 537 Mod
CASN
Table 3+ Lab SOP
Analytical Method Common Name Chemical Name
TR0807E Page 1 of 1 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE 3
TOTAL DAILY PRECIPITATION - 2021 QUARTERS 1 AND 2
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Date Total Precipitation1
(inches)
Measured Outfall 002
Flow (MGD)
1/1/2021 0.46 18.0
1/2/2021 0.60 19.9
1/3/2021 0.31 17.4
1/4/2021 -- 17.1
1/5/2021 0.03 17.1
1/6/2021 0.01 16.7
1/7/2021 -- 18.0
1/8/2021 0.77 16.5
1/9/2021 0.01 15.9
1/10/2021 -- 15.6
1/11/2021 0.06 16.7
1/12/2021 0.45 15.8
1/13/2021 -- 13.6
1/14/2021 -- 14.3
1/15/2021 0.33 14.7
1/16/2021 0.01 15.0
1/17/2021 -- 12.4
1/18/2021 -- 16.7
1/19/2021 -- 16.3
1/20/2021 -- 15.9
1/21/2021 -- 17.1
1/22/2021 -- 16.6
1/23/2021 -- 16.6
1/24/2021 -- 16.1
1/25/2021 0.5 17.6
1/26/2021 0.31 17.7
1/27/2021 0.42 18.5
1/28/2021 0.42 16.9
1/29/2021 -- 17.7
1/30/2021 -- 15.6
1/31/2021 0.80 18.1
2/1/2021 -- 14.5
2/2/2021 -- 13.5
2/3/2021 -- 11.0
2/4/2021 -- 12.0
2/5/2021 0.17 12.0
2/6/2021 0.18 12.6
2/7/2021 0.25 9.2
2/8/2021 -- 10.0
2/9/2021 -- 9.9
2/10/2021 -- 8.9
2/11/2021 0.46 9.3
2/12/2021 0.32 10.4
2/13/2021 1.40 13.3
2/14/2021 0.65 9.9
2/15/2021 0.67 12.8
2/16/2021 0.02 11.2
2/17/2021 -- 10.9
2/18/2021 1.09 18.2
2/19/2021 0.92 8.5
2/20/2021 -- 11.3
2/21/2021 -- 10.4
TR0807E Page 1 of 4 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE 3
TOTAL DAILY PRECIPITATION - 2021 QUARTERS 1 AND 2
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Date Total Precipitation1
(inches)
Measured Outfall 002
Flow (MGD)
2/22/2021 0.21 10.6
2/23/2021 -- 10.6
2/24/2021 -- 11.1
2/25/2021 -- 11.3
2/26/2021 -- 8.6
2/27/2021 -- 7.8
2/28/2021 -- 7.7
3/1/2021 0.04 7.1
3/2/2021 -- 7.3
3/3/2021 0.09 7.9
3/4/2021 -- 8.0
3/5/2021 -- 7.8
3/6/2021 -- 7.6
3/7/2021 -- 7.4
3/8/2021 -- 7.6
3/9/2021 -- 8.0
3/10/2021 -- 7.7
3/11/2021 -- 8.8
3/12/2021 -- 7.6
3/13/2021 -- 7.4
3/14/2021 -- 7.8
3/15/2021 -- 7.7
3/16/2021 0.88 11.2
3/17/2021 0.03 7.8
3/18/2021 0.07 10.6
3/19/2021 0.07 10.6
3/20/2021 -- 11.2
3/21/2021 -- 10.1
3/22/2021 -- 10.5
3/23/2021 -- 10.9
3/24/2021 0.24 10.7
3/25/2021 0.01 10.6
3/26/2021 0.08 9.7
3/27/2021 -- 16.4
3/28/2021 0.26 17.7
3/29/2021 -- 18.5
3/30/2021 -- 18.1
3/31/2021 0.3 18.6
4/1/2021 0.05 15.9
4/2/2021 -- 18.4
4/3/2021 -- 18.4
4/4/2021 -- 18.4
4/5/2021 -- 17.5
4/6/2021 -- 18.6
4/7/2021 -- 18.7
4/8/2021 -- 18.6
4/9/2021 0.04 19.6
4/10/2021 0.68 19.7
4/11/2021 -- 18.0
4/12/2021 -- 18.6
4/13/2021 -- 18.7
4/14/2021 -- 18.7
4/15/2021 -- 19.2
4/16/2021 -- 18.6
TR0807E Page 2 of 4 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE 3
TOTAL DAILY PRECIPITATION - 2021 QUARTERS 1 AND 2
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Date Total Precipitation1
(inches)
Measured Outfall 002
Flow (MGD)
4/17/2021 -- 18.5
4/18/2021 -- 17.6
4/19/2021 -- 18.2
4/20/2021 -- 12.9
4/21/2021 -- 15.7
4/22/2021 -- 12.4
4/23/2021 -- 10.8
4/24/2021 0.27 11.5
4/25/2021 0.01 9.9
4/26/2021 -- 9.5
4/27/2021 -- 10.8
4/28/2021 -- 10.6
4/29/2021 -- 12.0
4/30/2021 -- 13.8
5/1/2021 -- 14.0
5/2/2021 -- 14.7
5/3/2021 0.11 14.5
5/4/2021 0.01 15.4
5/5/2021 -- 15.7
5/6/2021 -- 15.8
5/7/2021 0.83 2 18.3
5/8/2021 --2 16.8
5/9/2021 --2 11.9
5/10/2021 --2 12.3
5/11/2021 --2 10.4
5/12/2021 0.362 12.4
5/13/2021 --2 10.3
5/14/2021 --2 12.0
5/15/2021 --2 11.7
5/16/2021 --2 10.1
5/17/2021 --2 10.8
5/18/2021 --2 11.5
5/19/2021 --2 13.5
5/20/2021 --2 15.3
5/21/2021 --2 15.1
5/22/2021 --2 16.1
5/23/2021 --2 15.8
5/24/2021 --2 22.3
5/25/2021 --2 14.3
5/26/2021 --2 19.4
5/27/2021 --2 20.4
5/28/2021 0.06 19.7
5/29/2021 0.07 19.2
5/30/2021 0.01 16.2
5/31/2021 -- 16.8
6/1/2021 -- 15.4
6/2/2021 2.68 23.4
6/3/2021 1.47 17.6
6/4/2021 0.01 11.9
TR0807E Page 3 of 4 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE 3
TOTAL DAILY PRECIPITATION - 2021 QUARTERS 1 AND 2
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Date Total Precipitation1
(inches)
Measured Outfall 002
Flow (MGD)
6/5/2021 -- 9.4
6/6/2021 -- 10.1
6/7/2021 0.19 16.2
6/8/2021 0.01 18.1
6/9/2021 -- 19.2
6/10/2021 1.02 20.3
6/11/2021 0.15 25.5
6/12/2021 2.08 19.8
6/13/2021 -- 19.1
6/14/2021 -- 18.8
6/15/2021 -- 19.7
6/16/2021 -- 19.3
6/17/2021 -- 19.6
6/18/2021 -- 20.0
6/19/2021 -- 19.1
6/20/2021 0.84 20.2
6/21/2021 0.01 20.5
6/22/2021 0.24 19.2
6/23/2021 -- 21.2
6/24/2021 -- 17.1
6/25/2021 0.23 18.9
6/26/2021 0.01 19.3
6/27/2021 -- 18.1
6/28/2021 -- 18.8
6/29/2021 -- 17.4
6/30/2021 -- 17.9
Notes:
-- - below USGS measurement threshold
1. Precipitation data obtained from USGS rain gauge at W.O. Huske Dam.
MGD - million gallons per day
USGS - United States Geological Survey
72 hour period prior to sample collection date
Sample collection date
2. Gap in USGS rain gauge at W.O. Huske Dam from 7 to 27 May 2021 was
supplemented with meteorological data collected on Site.
TR0807E Page 4 of 4 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

FIGURES

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
")
")
")
Willis Creek
Old Outfall 002reviR raeF epaCOutfall 002
W.O. Huske Dam
Site River Water Intake
NC Highway 87Seep A
Seep B
Seep C
Seep D
G BCTributary1GeorgiaBranchCreek
Site Location Map
Figure
1Raleigh
1,000 0 1,000500 Feet
³
September 2021
Notes:1. The outline of Cape Fear River is approximate and is based on open data from ArcGIS Online and North Carolina Department ofEnvironmental Quality Online GIS (MajorHydro shapefile).2. Basemap sources: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GISUser Community
Chemours Fayetteville Works, North Carolina
Legend
")Site Features
Site Boundary
Nearby Tributary
Observed Seep (Natural Drainage)
Site Conveyance Network
Areas at Site
Wastewater Treatment Plant
Kuraray Trosifol®Leased AreaChemours Monomers/IXM
Chemours Polymer Processing Aid Area
DuPont Polyvinyl Fluoride Leased Area
Former DuPont PMDF Area
Kuraray SentryGlas® Leased Area
Power - Filtered andDemineralized WaterProduction
Kuraray Laboratory
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
")")
")")
")
")
")
")
")
")
!(
!(!(
!(
!(
!(
!(
!(!(
!(
!(
!(
!(
!(
!(
!(
!(
!(
!(6A 6B
19A19B
21A
21B
22
24B
24A
24C
1
2 3
4
5
7A
8
9
10
11
12
13
14
15
18
20
7B
7C
10A
Wastewater Treatment Plant Discharge DuPon t AreaWoodLinedTrench
Open C ha nn el to Outfa ll 002
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23A
Paragraph 11(d) Sample Locations
Prior to Stormwater Treatment System and Terracotta Pipe Activities
Chemours Fayetteville Works, North Carolina
Figure
2Raleigh
500 0 500250 Feet
³
September 2021
Notes:1. Intake River Water at Facility sample location represents background concentrationsof PFAS.2. Non-Chemours Process Wastewater sample locations represent process wastewaterfrom non-Chemours manufacturing areas.3. Non-Contact Cooling Water (NCCW) sample locations represent non-processwastewater from Kuraray and Chemours manufacturing areas.4. Stormwater sample locations represent stormwater only.5. Stormwater-NCCW sample locations represent both stormwater and non-processwastewater from throughout the Facility.6. Wastewater Treatment Plant sample locations represent process wastewater from non-Chemours manufacturing areas and non-process wastewater from throughout the Facility.7. Combined Flows to Outfall 002 represent process wastewater, non-processwastewater, and stormwater from throughout the Facility.8. Basemap Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/AirbusDS, USDA, USGS, AeroGRID, IGN, and the GIS User Community.
Ditch Type
Wood Lined Trench
Cooling Water Channel
Open Channel to Outfall 002
Other Connections
Pipe Connection to Facility
Wastewater Treatment Plant Discharge
DuPont Area
Grouted Pipe Section
Terracotta Pipe and Piping Connected to Terracotta Pipe
Legend
!(Temporal Composite Sample
")Grab Sample
Sample Location Category
Non-Chemours Process Wastewater
Intake River Water at Facility
Non-Contact Cooling Water (NCCW)
Stormwater
Combined Flows to Outfall 002
Wastewater Treatment Plant
Stormwater-NCCW
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
2222222222222222222222222222
!(
!(!(
!(
!(
!(
!(
!(!(
!(
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6A 6B
19A19B
21A
21B
22
23C-2
23C-3
23C-1
1
2 3
4
5
7A
8
9
10
11
12
13
14
15
18
20
7B
7C
10A
Wastewater Treatment Plant Discharge DuPon t AreaWoodLinedTrenchWoodLinedTrench
Open C ha nn el to Outfa ll 002
(dra ins to Cape Fear River)
Cooling Water Cha
n
n
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l Cape Fea
r
R
ive
r
Paragraph 11(d) Sample Locations After
Stormwater Treatment System and Terracotta Pipe Activities
Chemours Fayetteville Works, North Carolina
Figure
3Raleigh
500 0 500250 Feet
³
September 2021
Notes:1. Intake River Water at Facility sample location represents background concentrations of PFAS.2. Non-Chemours Process Wastewater sample locations represent process wastewater from non-Chemours manufacturing areas.3. Non-Contact Cooling Water (NCCW) sample locations represent non-process wastewater fromKuraray and Chemours manufacturing areas.4. Stormwater sample locations represent stormwater only.5. Stormwater-NCCW sample locations represent both stormwater and non-process wastewaterfrom throughout the Facility.6. Wastewater Treatment Plant sample locations represent process wastewater from non-Chemours manufacturing areas and non-process wastewater from throughout the Facility.7. Combined Flows to Outfall 002 represent process wastewater, non-process wastewater, andstormwater from throughout the Facility.8. Stormwater treatment system will be sampled up to four times per month under a separateprogram.9. Basemap Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA,USGS, AeroGRID, IGN, and the GIS User Community.
Legend
!(Temporal Composite Sample
")Grab Sample
Sample Location Category
Intake River Water at Facility
Non-Chemours Process Wastewater
Non-Contact Cooling Water (NCCW)
Stormwater
Stormwater-NCCW
Wastewater Treatment Plant
Combined Flows to Outfall 002
Other Features
Stormwater Treatment System (See Note 8)
Site Conveyance Network Ditch
Wood Lined Trench
Open Channel to Outfall 002
Wastewater Treatment Plant Discharge
DuPont Area
Stormwater Channel
Pipe to Convey Captured Stormwater to Stormwater Treatment System2 2
Other Connections
Combined Stormwater and Non-Contact Cooling Water Pipe
Process Sewer
Non-Contact Cooling Water Pipe
Decommissioned Pipe Section
!
!
!
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!
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!
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!
!
!
!Cape Fea
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DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Total Table 3+ Concentrations
Non-Chemours Process Wastewater
Chemours Fayetteville Works, North Carolina
Figure
4A
Raleigh September 2021
1
10
100
1,000
10,000
100,000
Location 1 Location 18 Location 19A Location 19B Location 23B Location 23C-
1
Location 23C-
2
Location 23C-
3Total Table 3+ Concentration (ng/L)February 2021 (Wet Event)April/May 2021 June 2021
Notes:
1. ng/L -nanograms per liter
2. Total Table 3+ 17 compoundsums presented.
3. Location 1 represents background concentrations. Other locations represent process wastewater from non-Chemours manufacturing areas. See Figures 2 and 3 for sample locations.4. April/May 2021 samples analyzed using high level method for Table 3+ PFAS and indicated by orange hatching.5. Location-Month combinations with no data indicate no sample was collected. Non-detect results, when they occur, are indicated on the graph with a note.Location 1 -Intake River Water at FacilityLocation 18 -Kuraray process wastewater Location 19A -DuPont process wastewater, Plant 1
Location 19B -DuPont process wastewater, Plant 2
Location 23B -Kuraray laboratory process wastewater (prior to decomissioning of Terracotta pipe)
Location 23C-1 -Kuraray SentryGlas process wastewater (at sump after decomissioning of Terracotta pipe)
Location 23C-2 -Kuraray laboratory process wastewater (at sump after decomissioning of Terracotta pipe)Location 23C-3 -Kuruary Trosifol process wastewater (at sump after decomissioning of Terracotta pipe)
Location no
longer exists due to site
work in 2021
Quarter 2
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Total Table 3+ Concentrations
Non-Contact Cooling Water
Chemours Fayetteville Works, North Carolina
Figure
4B
Raleigh September 2021
1
10
100
1,000
10,000
100,000
Location 1 Location 6A Location 6B Location 24A Location 24B Location 24CTotal Table 3+ Concentration (ng/L)February 2021 (Wet Event)April/May 2021 June 2021Notes:
1. ng/L -nanograms per liter
2. Total Table 3+ 17 compound sums presented.
3. Location 1 represents background concentrations. Other locations represent non-process wastewater from Kuraray and Chemours manufacturing areas. See Figures 2 and 3 for sample locations.4. April/May 2021 samples analyzed using high level method for Table 3+ PFAS and indicated by orange hatching.5. Sample analyzed at elevated reporting limit, results all non-detect.6. Location-Month combinations with no data indicate no sample was collected. Non-detect results, when they occur, are indicated on the graph with a note.Location 1 -Intake River Water at FacilityLocation 6A -Kuraray southern leased area non-process wastewater discharge -Vacuum Condenser
Location 6B -Kuraray southern leased area non-process wastewater discharge -Resins Area
Location 24A -Chemours Monomers Ion Exchange Materials (IXM) Vinyl Ethers South non-process wastewater
Location 24B -Chemours Monomers IXM Line 3 and Line 4 Extruder non-process wastewater
Location 24C -Chemours Monomers IXM Water Return Header non-process wastewater See Note 5Location no longer exists due to site
work in 2021
Quarter 2
Location no longer exists
due to site
work in 2021
Quarter 2
Location no longer exists
due to site
work in 2021
Quarter 2
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Total Table 3+ Concentrations
Stormwater
Chemours Fayetteville Works, North Carolina
Figure
4C
Raleigh September 2021
1
10
100
1,000
10,000
100,000
Location 1 Location 2 Location 3 Location 4 Location 5 Location 10 Location 11Total Table 3+ Concentration (ng/L)February 2021 (Wet Event)April/May 2021 June 2021Notes:1. ng/L -nanograms per liter2. Total Table 3+ 17 compound sums presented.3. Location 1 represents background concentrations. Other locations represent stormwater only. See Figures 2 and 3 for samplelocations.4. April/May 2021 samples analyzed using high level method for Table 3+ PFAS and indicated by orange hatching.
5. Location-Month combinations with no data indicate no sample was collected. Non-detect results, when they occur, are indicated
on the graph with a note.
Location 1 -Intake River Water at Facility
Location 2 -Kuraray southern leased area stormwater
Location 3 -Chemours Polymer Processing Aid (PPA) area stormwater dischargeLocation 4 -Combined stormwater from Kuraray norhtern leased area and Chemours PPA areaLocation 5 -Kuraray southern leased area stormwaterLocation 10 -Chemours Monomers Ion Exchange Materials (IXM) area storwater dischargeLocation 11 -Stormwater discharge from portion of grassy field to north of decommissioned Chemours Teflon area
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Total Table 3+ Concentrations
Stormwater-Non-Contact Cooling WaterChemours Fayetteville Works, North Carolina
Figure
4D
Raleigh September 2021
1
10
100
1,000
10,000
100,000
Location 1 Location 7A Location 9 Location 10A Location 12 Location 13 Location 14 Location 15 Location 21ATotal Table 3+ Concentration (ng/L)February 2021 (Wet Event)April/May 2021 June 2021
Notes:1. ng/L -nanograms per liter2. Total Table 3+ 17 compound sums presented.3. Location 1 represents background concentrations. Other locations represent both stormwater and non-process wastewater from throughout theFacility. See Figures 2 and 3 for sample locations.4. April/May 2021 samples analyzed using high level method for Table 3+ PFAS and indicated by orange hatching.5. Location-Month combinations with no data indicate no sample was collected. Non-detect results, when they occur, are indicated on the graph with anote.Location 1 -Intake River Water at FacilityLocation 7A -Combined stormwater and non-process wastewater discharge from western portion of the Facility
Location 9 -Combined non-process wastewater from Chemours Monomers Ion Exchange Materials (IXM) area and stormwater discharge from Vinyl
Ethers South and Vinyl Ethers North
Location 10A -Combined Chemours Monomers IXM non-process wastewater and stormwater discharge
Location 12 -DuPont area southern drainage ditch stormwater discharge and NCCW
Location 13 -DuPont area northern drainage ditch stormwater discharge and NCCW
Location 14 -DuPont area southeast stormwater and NCCW discharge Location 15 -Combined stormwater and NCCW discharge from eastern portion of the FacilityLocation 21A -Sediment Basin South
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Total Table 3+ Concentrations
Wastewater Treatment PlantChemours Fayetteville Works, North Carolina
Figure
4E
Raleigh September 2021
1
10
100
1,000
10,000
100,000
Location 1 Location 8 Location 22 Location 23ATotal Table 3+ Concentration (ng/L)February 2021 (Wet Event)April/May 2021 June 2021
Notes:1. ng/L -nanograms per liter2. Total Table 3+ 17 compound sums presented.3. Location 1 represents background concentrations. Other locations represent process wastewater from non-Chemours manufacturing areas and non-process wastewater from throughout the Facility. See Figures 2 and 3 for sample locations.
4. May/June 2020 value for Location 8 based on sample collected during dry weather in June 2020.
5. April/May 2021 samples analyzed using high level method for Table 3+ PFAS and indicated by orange hatching.
5. Location-Month combinations with no data indicate no sample was collected. Non-detect results, when they occur, are indicated
on the graph with a note.
Location 1 -Intake River Water at FacilityLocation 8 -Wastewater Treatment Plant (WWTP) EffluentLocaton 22 -WWTP InfluentLocation 23A -Terracotta Pipe
Location no
longer exists
due to sitework in 2021 Quarter 2
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Total Table 3+ Concentrations
Combined Flows to Outfall 002Chemours Fayetteville Works, North Carolina
Figure
4F
Raleigh September 2021
1
10
100
1,000
10,000
100,000
Location 1 Location 7B Location 7C Location 20Total Table 3+ Concentration (ng/L)February 2021 (Wet Event)April/May 2021 June 2021Notes:
1. ng/L -nanograms per liter
2. Total Table 3+ 17 compound sums presented.
3. Location 1 represents background concentrations. Other locations represent process wastewater, non-process wastewater, and
stormwater from throughout the Facility. See Figures 2 and 3 for sample locations.
4. April/May 2021 samples analyzed using high level method for Table 3+ PFAS and indicated by orange hatching.
5. Location-Month combinations with no data indicate no sample was collected. Non-detect results, when they occur, are indicatedon the graph with a note.Location 1 -Intake River Water at FacilityLocation 7B -Combined stormwater and non-process wastewater from western portion of the Facility and treated discharge from the wastewater treatment plant (WWTP)Location 7C -Combined stormwater and non-process wastewater from western portion of the Facility, the eastern portion of the Facility, and the DuPont Area, and treated discharge from WWTPLocation 20 -Outfall 002
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Distribution of Total Table 3+ Concentrations
Chemours Fayetteville Works, North Carolina
Figure
5A
Raleigh September 2021
Notes:
1.ng/L -nanograms per liter
2. Total Table 3+ 17 compoundsums presented.
3. The data presented includes all samples, including field duplicates, except for the April/May 2021 samples which had higher reporting limits.4. Gray data represent results from 2019 -2020 and are included in previous reports.
5. Locations C-1, C-2, and C-3 represent samples from Locations 23C-1, 23C-2, and 23C-3, respectively.
1
10
100
1,000
10,000
100,000
Total Table 3+ Concentration (ng/L)Location
1 18 19A 19B 23B C-1 C-2 C-3 6A 6B 24A 24B 24C 2 3 4 5 10 11 7A 9 10A 12 13 14 15 21A 8 22 23A 7B 7C 20
Intake River Water at Facility
Non-ChemoursProcess Wastewater Locations Non-Contact Cooling Water Locations Stormwater Locations Stormwater-Non-ContactCooling Water Locations WastewaterTreatment Plant Locations Combined Flows to Outfall 002
Intake River Water at Facility Stormwater-Non-Contact Cooling Water Locations
Non-Chemours Process Wastewater Locations Wastewater Treatment Plant Locations
Non-Contact Cooling Water Locations Combined Flows to Outfall 002 LocationsStormwater Locations 2019 -2020 Data
Location no longer exists due to Site work in 2021 Quarter 2
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Distribution of EPA Method 537 Mod Concentrations
Chemours Fayetteville Works, North Carolina
Figure
5B
Raleigh September 2021
Intake River Water at Facility Stormwater-Non-Contact Cooling Water Locations
Non-Chemours Process Wastewater Locations Wastewater Treatment Plant LocationsNon-Contact Cooling Water Locations Combined Flows to Outfall 002 LocationsStormwater Locations 2019 -2020 Data
Location no longer exists due to Site work in 2021 Quarter 2
Notes:
1.ng/L -nanograms per liter2. Total Table 3+ 20 compound sums presented.3. The data presented includes all samples, including field duplicates.4. Gray data represent results from 2019 -2020 and are included in previous reports.5. Locations C-1, C-2, and C-3 represent samples from Locations 23C-1, 23C-2, and 23C-3, respectively.
1
10
100
1,000
10,000
100,000
EPA Method 537 Mod Concentration (ng/L)Location
1 18 19A 19B 23B C-1 C-2 C-3 6A 6B 24A 24B 24C 2 3 4 5 10 11 7A 9 10A 12 13 14 15 21A 8 22 23A 7B 7C 20
Intake River Water at Facility
Non-ChemoursProcess Wastewater Locations Non-Contact Cooling Water Locations Stormwater Locations Stormwater-Non-ContactCooling Water Locations WastewaterTreatment Plant Locations
Combined Flows to Outfall
002
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
2222222222222222222222222222
")
")
!(
!(
!(!(
!(
!(
!(
!(
!(
!(
!(
!(!(
Wastewater Treatment Plant Discharge DuPon t AreaWoodLinedTrenchWoodLinedTrench
Open C ha nn el to Outfa ll 002
Stormw ater Channel
(dra ins to Cape Fear River)
21A
22 Cape Fea
r
R
ive
r
1
7A
8 11
12
13
14
15
20
7B
7C
10A
9A
Proposed Paragraph 11(d) Sample Locations
After June 2021
Chemours Fayetteville Works, North Carolina
Figure
6Raleigh
500 0 500250 Feet
³
September 2021
Legend
!(Temporal Composite Sample
")Grab Sample
Sample Location Category
Non-Chemours Process Wastewater
Intake River Water at Facility
Non-Contact Cooling Water (NCCW)
Stormwater
Combined Flows to Outfall 002
Wastewater Treatment Plant
Stormwater-NCCW
Note:Stormwater treatment system will be sampled up to four times per monthunder a separate program.
Other Features
Stormwater Treatment System (See Note)
Site Conveyance Network Ditch
Wood Lined Trench
Open Channel to Outfall 002
Wastewater Treatment Plant Discharge
DuPont Area
Stormwater Channel
Pipe to Convey Captured Stormwater to Stormwater Treatment System2 2
Other Connections
Combined Stormwater and Non-Contact Cooling Water Pipe
Non-Contact Cooling Water Pipe
Decommissioned Pipe Section
Process Sewer
!
!
!
"
!!Cape Fea
r
R
ive
r
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

APPENDIX A
Analytical Results – Paragraph 11(d)
Sampling Events

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID111123
Sampling Event February 2021 February 2021 April/May 2021 June 2021 February 2021 February 2021
Field Sample ID STW-LOC-1-8-021821 STW-LOC-1-8-021821-D STW-LOC-1-4-042921 STW-LOC-1-4-061821 STW-LOC-2-8-021821 STW-LOC-3-8-021821
Date Sampled 02/18/2021 02/18/2021 04/29/2021 06/18/2021 02/18/2021 02/18/2021
Analytical Laboratory TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
QA/QC -- Field Duplicate -- -- -- --
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid 4.8 4.8 34 J 12 460 14,000
PFMOAA 2.3 2.1 560 17 7.0 26
PFO2HxA 2.8 3.2 <27 8.4 29 34
PFO3OA <2.0 <2.0 <39 <2.0 6.5 12
PFO4DA <2.0 <2.0 <59 <2.0 3.2 4.5
PFO5DA <2.0 <2.0 <78 <2.0 3.5 4.0
PMPA 10 J <10 <620 27 58 34
PEPA <20 <20 <20 <20 <20 <20
PS Acid <2.0 <2.0 <20 <2.0 <2.0 <2.0
Hydro-PS Acid <2.0 <2.0 <6.1 <2.0 <2.0 <2.0
R-PSDA 2.4 J <2.0 <71 <2.0 11 J 14 J
Hydrolyzed PSDA <2.0 <2.0 <38 2.0 J 5.0 J 5.8 J
R-PSDCA <2.0 <2.0 <17 <2.0 <2.0 <2.0
NVHOS <2.0 <2.0 <15 2.3 <2.0 <2.0
EVE Acid <2.0 <2.0 <17 <2.0 <2.0 <2.0
Hydro-EVE Acid <2.0 <2.0 <14 <2.0 <2.0 <2.0
R-EVE <2.0 <2.0 <72 <2.0 3.6 J 3.4 J
PES <2.0 <2.0 <6.7 <2.0 <2.0 <2.0
PFECA B <2.0 <2.0 <27 <2.0 <2.0 <2.0
PFECA-G <2.0 UJ <2.0 <48 <2.0 <2.0 <2.0
Perfluoroheptanoic Acid1 <2.0 <2.0 3.5 J 6.2 <2.0 <2.0
Total Table 3+ (17 compounds)2,3 20 10 590 67 570 14000
Total Table 3+ (20 compounds)2 22 10 590 69 590 14000
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
11Cl-PF3OUdS <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <4.0 <4.0 <4.0 UJ <4.0 UJ <4.0 <4.0
6:2 Fluorotelomer sulfonate <5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0
9Cl-PF3ONS <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
DONA <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
N-ethyl perfluorooctane sulfonamidoacetic acid <5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0
N-ethylperfluoro-1-octanesulfonamide <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
N-methyl perfluoro-1-octanesulfonamide <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
N-methyl perfluorooctane sulfonamidoacetic acid <5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0
Perfluorobutane Sulfonic Acid <2.0 <2.0 3.5 J 5.0 J <2.0 <2.0
Perfluorobutanoic Acid <5.0 <5.0 <5.0 UJ 5.2 J <5.0 <5.0
Perfluorodecane Sulfonic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorodecanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorododecane sulfonic acid (PFDoS)<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorododecanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluoroheptane sulfonic acid (PFHpS)<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorohexadecanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorohexane Sulfonic Acid <2.0 <2.0 5.3 J 5.1 J <2.0 <2.0
Perfluorohexanoic Acid <2.0 <2.0 5.3 J 9.0 J <2.0 2.0
Perfluorononanesulfonic acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorononanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorooctadecanoic acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorooctane Sulfonamide <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluoropentane sulfonic acid (PFPeS)<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluoropentanoic Acid <2.0 <2.0 7.3 J 8.6 J <2.0 13
Perfluorotetradecanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluorotridecanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
Perfluoroundecanoic Acid <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0
PFOA <2.0 2.1 5.3 J 9.4 J 38 30
PFOS 3.0 3.0 9.0 J 10 J <2.0 41
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
TR0807E Page 1 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
4 5 6A 6A 6A 6B
February 2021 February 2021 February 2021 April/May 2021 June 2021 February 2021
STW-LOC-4-7.3-021821 STW-LOC-5-8-021821 STW-LOC-6A-021921 STW-LOC-6A-050421 STW-LOC-6A-061821 STW-LOC-6B-021921
02/18/2021 02/18/2021 02/19/2021 05/04/2021 06/18/2021 02/19/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
760 340 J 11 120 57 J <4.0
15 3.7 J <2.0 31 9.0 <2.0
15 11 J 10 42 12 <2.0
5.1 4.9 J <2.0 7.9 2.8 <2.0
2.2 2.2 J <2.0 2.3 <2.0 <2.0
<2.0 2.6 J <2.0 <2.0 <2.0 <2.0
<10 16 J 34 180 49 <10
<20 <20 UJ <20 52 <20 <20
<2.0 <2.0 UJ <2.0 <2.0 2.7 2.5
<2.0 <2.0 UJ <2.0 2.7 <2.0 <2.0
7.3 J 4.2 J 7.5 J 34 J <2.0 3.7 J
49 J <2.0 UJ <2.0 15 J 6.7 J 4.6 J
<2.0 <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 UJ <2.0 5.0 2.5 <2.0
<2.0 <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 UJ <2.0 14 J <2.0 <2.0
<2.0 <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 UJ <2.0 5.3 J 7.3 J <2.0
800 380 55 440 140 2.5
850 380 63 510 140 11
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<4.0 <4.0 UJ <4.0 <4.0 UJ <4.0 UJ <4.0
<5.0 <5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<5.0 <5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<5.0 <5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0
<2.0 <2.0 UJ <2.0 4.5 J 6.0 J <2.0
<5.0 <5.0 UJ <5.0 <5.0 UJ 10 J <5.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ 3.7 J <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 6.4 J 7.3 J <2.0
<2.0 <2.0 UJ <2.0 7.0 J 12 J <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ 4.1 J <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 8.1 J 11 J <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
<2.0 <2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0
3.0 <2.0 UJ 2.1 10 J 18 J <2.0
<2.0 <2.0 UJ 4.0 21 J 62 J <2.0
TR0807E Page 2 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
6B 7A 7A 7A 7B 7B
April/May 2021 February 2021 April/May 2021 June 2021 February 2021 April/May 2021
STW-LOC-6B-042921 STW-LOC-7A-8-021821 STW-LOC-7A-4-042921 STW-LOC-7A-4-061821 STW-LOC-7B-8-021821 STW-LOC-7B-4-042921
04/29/2021 02/18/2021 04/29/2021 06/18/2021 02/18/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
<2.0 650 61 J 12 620 58 J
<2.0 25 <80 10 110 <80
<2.0 13 <27 8.1 32 <27
<2.0 3.7 <39 <2.0 9.2 <39
<2.0 2.5 <59 <2.0 3.6 <59
<2.0 3.4 <78 <2.0 4.3 <78
<10 27 <620 26 29 <620
<20 <20 <20 <20 <20 <20
<2.0 2.5 <20 <2.0 2.4 <20
<2.0 2.3 <6.1 <2.0 3.4 <6.1
<2.0 23 J <71 <2.0 23 J <71
<2.0 4.4 J <38 2.1 J 25 J <38
<2.0 <2.0 <17 <2.0 <2.0 <17
<2.0 <2.0 <15 <2.0 2.5 <15
<2.0 <2.0 <17 <2.0 <2.0 <17
<2.0 <2.0 <14 <2.0 <2.0 <14
<2.0 4.6 J <72 <2.0 5.5 J <72
<2.0 <2.0 <6.7 <2.0 <2.0 <6.7
<2.0 <2.0 <27 <2.0 <2.0 <27
<2.0 <2.0 <48 <2.0 <2.0 <48
<2.0 <2.0 3.2 J 5.9 <2.0 3.0 J
ND 730 61 56 820 58
ND 760 61 58 870 58
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<4.0 UJ <4.0 <4.0 UJ <4.0 UJ <4.0 <4.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 3.9 J 5.2 J <2.0 3.4 J
<5.0 UJ 6.9 <5.0 UJ 5.3 J <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 5.4 J 6.1 J <2.0 5.4 J
<2.0 UJ <2.0 6.1 J 9.8 J <2.0 5.1 J
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ 2.5 8.0 J 9.3 J 3.1 8.0 J
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ 9.7 6.7 J 10 J 8.5 6.8 J
<2.0 UJ 3.3 11 J 15 J 3.0 12 J
TR0807E Page 3 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
7B 7C 7C 7C 8 8
June 2021 February 2021 April/May 2021 June 2021 February 2021 April/May 2021
STW-LOC-7B-4-061821 STW-LOC-7C-8-021821 STW-LOC-7C-4-042921 STW-LOC-7C-4-061821 STW-LOC-8-4-021921 STW-LOC-8-4-042921
06/18/2021 02/18/2021 04/29/2021 06/18/2021 02/19/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
18 4,800 62 J 35 230 200 J
14 140 12,000 11 130 300
9.9 110 <27 11 55 <27
2.2 43 <39 <2.0 13 <39
<2.0 22 <59 <2.0 5.5 <59
<2.0 24 <78 <2.0 7.3 <78
34 58 <620 39 13 <620
<20 24 <20 <20 <20 <20
<2.0 160 67 24 2.4 150
<2.0 25 <6.1 2.5 10 <6.1
<2.0 450 J <71 <2.0 <2.0 <71
7.9 J 270 J <38 69 J 32 J <38
<2.0 2.9 <17 <2.0 <2.0 <17
3.3 14 490 <2.0 7.3 <15
<2.0 51 <17 7.1 <2.0 <17
<2.0 6.5 <14 <2.0 <2.0 <14
<2.0 71 J <72 <2.0 <2.0 <72
<2.0 <2.0 <6.7 <2.0 <2.0 <6.7
<2.0 <2.0 <27 <2.0 <2.0 <27
<2.0 <2.0 <48 <2.0 <2.0 <48
6.6 4.1 3.3 J 6.3 2.2 2.9 J
80 5500 13000 130 470 650
88 6300 13000 200 510 650
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<4.0 UJ <4.0 <4.0 UJ <4.0 UJ <4.0 <4.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
5.1 J <2.0 3.8 J 5.5 J 2.2 2.4 J
5.8 J 7.9 <5.0 UJ 6.3 J <5.0 8.0 J
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
5.3 J <2.0 6.0 J 5.4 J <2.0 <2.0 UJ
10 J 2.1 6.6 J 11 J 4.0 5.7 J
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
10 J 22 7.4 J 10 J 5.5 15 J
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
9.1 J 8.8 6.5 J 10 J 3.3 3.1 J
14 J 3.2 12 J 15 J <2.0 <2.0 UJ
TR0807E Page 4 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
8 9 9 10 10A 10A
June 2021 February 2021 April/May 2021 February 2021 February 2021 April/May 2021
STW-LOC-8-4-061821 STW-LOC-9-8-021821 STW-LOC-9-4-042921 STW-LOC-10-8-021821 STW-LOC-10A-8-021821 STW-LOC-10A-4-042921
06/18/2021 02/18/2021 04/29/2021 02/18/2021 02/18/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
210 12,000 130 J 15,000 23,000 150 J
110 320 <80 4,200 1,200 <80
56 760 <27 1,200 760 <27
18 300 <39 450 310 <39
6.8 300 <59 460 290 <59
2.5 260 <78 260 190 <78
40 260 <620 330 240 <620
<20 97 <20 120 93 <20
<2.0 1,500 87 690 1,200 69
7.1 220 <6.1 140 180 <6.1
<2.0 860 J <71 170 J 570 J <71
39 J 1,100 J <38 160 J 740 J <38
<2.0 40 <17 11 34 <17
14 76 <15 79 69 <15
<2.0 460 35 66 380 29
2.3 69 <14 46 55 <14
<2.0 220 J <72 76 J 150 J <72
<2.0 <2.0 <6.7 <2.0 <2.0 <6.7
<2.0 <2.0 <27 <2.0 <2.0 <27
<2.0 <2.4 <48 <2.4 <2.4 <48
3.7 30 3.5 J 8.4 24 4.3 J
470 17000 250 23000 28000 250
510 19000 250 23000 29000 250
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<4.0 UJ <4.0 <4.0 UJ <4.0 <4.0 <4.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 <5.0 <5.0 UJ
3.1 J <2.0 3.5 J <2.0 <2.0 3.6 J
7.0 J 29 <5.0 UJ 27 27 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 6.0 J <2.0 <2.0 6.0 J
7.0 J 5.2 6.5 J 5.3 4.7 6.1 J
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ 4.8 <2.0 UJ 2.9 4.3 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
21 J 190 9.5 J 48 150 9.4 J
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
2.6 J 8.5 6.5 J 5.8 6.4 6.8 J
<2.0 UJ 3.5 13 J <2.0 3.2 12 J
TR0807E Page 5 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
11 12 12 13 14 14
February 2021 February 2021 April/May 2021 February 2021 February 2021 April/May 2021
STW-LOC-11-8-021821 STW-LOC-12-8-021821 STW-LOC-12-4-042921 STW-LOC-13-7.3-021821 STW-LOC-14-8-021821 STW-LOC-14-4-042921
02/18/2021 02/18/2021 04/29/2021 02/18/2021 02/18/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
3,400 160 46 J 2,100 50 44 J
340 <2.0 <80 130 <2.0 <80
240 16 <27 51 8.1 <27
60 3.3 <39 11 <2.0 <39
81 3.2 <59 7.6 <2.0 <59
44 2.8 <78 6.0 <2.0 <78
330 12 <620 110 20 670
130 <20 <20 27 <20 <20
17 <2.0 <20 6.8 <2.0 <20
36 <2.0 <6.1 9.2 <2.0 <6.1
150 J 14 J <71 28 J 11 J <71
110 J <2.0 <38 4.5 J <2.0 <38
12 <2.0 <17 <2.0 <2.0 <17
15 <2.0 <15 2.3 <2.0 <15
8.3 <2.0 <17 4.4 <2.0 <17
7.9 <2.0 <14 <2.0 <2.0 <14
64 J <2.0 <72 7.8 J <2.0 <72
<2.0 <2.0 <6.7 <2.0 <2.0 <6.7
<2.0 <2.0 <27 <2.0 <2.0 <27
<2.0 <2.0 <48 <2.0 <2.0 <48
3.2 <2.0 170 <2.0 <2.0 5.2 J
4700 200 46 2500 78 710
5000 210 46 2500 89 710
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ 2.0 <2.0 <2.0 UJ
<4.0 <4.0 <4.0 UJ <4.0 <4.0 <4.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 <2.0 <2.0 UJ 3.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 <2.0 5.5 J <2.0 <2.0 5.0 J
100 <5.0 <5.0 UJ 12 <5.0 5.3 J
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 7.5 J <2.0 <2.0 7.9 J
3.4 2.2 10 J <2.0 2.2 9.5 J
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
29 3.3 14 J 5.0 2.5 12 J
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 <2.0 <2.0 UJ
25 3.2 12 J <2.0 2.5 8.9 J
<2.0 5.9 23 J <2.0 5.0 14 J
TR0807E Page 6 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
14 15 15 15 18 18
June 2021 February 2021 April/May 2021 June 2021 February 2021 April/May 2021
STW-LOC-14-4-061821 STW-LOC-15-8-021821 STW-LOC-15-4-021921 STW-LOC-15-4-061821 STW-LOC-18-4-021921 STW-LOC-18-4-042921
06/18/2021 02/18/2021 04/29/2021 06/18/2021 02/19/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
12 J 22,000 200 J 72 50 10
17 610 <80 UJ 8.0 6.8 8.3 J
9.2 600 <27 UJ 11 16 7.3
<2.0 250 <39 UJ 3.3 3.8 <2.0
<2.0 170 <59 UJ <2.0 <2.0 <2.0
<2.0 160 <78 UJ <2.0 2.6 <2.0
19 180 77 J 37 29 10
<20 81 <20 UJ <20 <20 <20
<2.0 1,100 <20 UJ 79 <2.0 <2.0
<2.0 190 <6.1 UJ 5.8 <2.0 <2.0
<2.0 1,200 J <71 UJ 85 J 9.1 J <2.0
2.0 J 1,000 J <38 UJ 240 J 4.0 J <2.0
<2.0 33 <17 UJ <2.0 <2.0 <2.0
2.6 72 <15 UJ 3.5 <2.0 <2.0
<2.0 330 <17 UJ 22 <2.0 <2.0
<2.0 51 <14 UJ <2.0 <2.0 <2.0
<2.0 260 J <72 UJ 12 J 3.5 J <2.0
<2.0 <2.0 <6.7 UJ <2.0 <2.0 <2.0
<2.0 <2.0 <27 UJ <2.0 <2.0 <2.0
<2.0 <2.4 <48 UJ <2.0 <2.0 <2.0
5.4 23 3.5 J 6.1 <2.0 <2.0
60 26000 280 240 110 36
62 28000 280 580 120 36
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<4.0 UJ <4.0 <4.0 UJ <4.0 UJ <4.0 <4.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 5.2 J
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
4.7 J <2.0 3.2 J 5.6 J <2.0 <2.0 UJ
6.3 J 22 <5.0 UJ 5.4 J <5.0 <5.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
5.0 J <2.0 5.5 J 5.2 J <2.0 <2.0 UJ
7.8 J 3.9 5.5 J 10 J <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ 4.5 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
7.7 J 150 9.0 J 11 J <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
7.1 J 5.0 6.3 J 10 J <2.0 <2.0 UJ
11 J 3.0 11 J 15 J <2.0 <2.0 UJ
TR0807E Page 7 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
18 19A 19A 19A 19B 19B
June 2021 February 2021 April/May 2021 June 2021 February 2021 April/May 2021
STW-LOC-18-4-061821 STW-LOC-19A-021921 STW-LOC-19A-042921 STW-LOC-19A-061821 STW-LOC-19B-021921 STW-LOC-19B-042921
06/18/2021 02/19/2021 04/29/2021 06/18/2021 02/19/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
14 82 J 16 5.2 37 18 J
<2.0 3.4 16 4.2 <2.0 20 J
7.3 7.8 11 3.3 7.5 9.8 J
2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
18 21 27 17 22 39 J
<20 <20 <20 <20 <20 <20 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
3.4 J <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 2.9 <2.0 <2.0 UJ
41 110 70 30 67 87
45 110 70 30 67 87
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<4.0 UJ <4.0 <4.0 UJ <4.0 UJ <4.0 <4.0 UJ
<5.0 UJ 13 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ 3.4 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
6.9 J <5.0 UJ <5.0 UJ <5.0 UJ <5.0 <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ 2.1 J <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
3.3 J <2.0 UJ 2.2 J 2.0 J <2.0 2.2 J
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
3.2 J <2.0 UJ 3.2 J 2.3 J <2.0 3.0 J
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ
2.9 J <2.0 UJ 2.2 J <2.0 UJ <2.0 2.7 J
2.8 J <2.0 UJ 2.0 J <2.0 UJ <2.0 2.3 J
TR0807E Page 8 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
19B 20 20 20 20 21A
June 2021 February 2021 April/May 2021 April/May 2021 June 2021 February 2021
STW-LOC-19B-061821 STW-LOC-20-8-021821 STW-LOC-20-4-042921
STW-LOC-20-4-042921-
D STW-LOC-20-4-061821 STW-LOC-21A-021821
06/18/2021 02/18/2021 04/29/2021 04/29/2021 06/18/2021 02/18/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- Field Duplicate -- --
17 8,200 J 110 150 74 310
5.6 180 J <80 <80 5.8 13
9.4 230 J 57 J <27 12 7.2
<2.0 120 J <39 <39 2.8 <2.0
<2.0 80 J <59 <59 <2.0 <2.0
<2.0 77 J <78 <78 <2.0 3.6
69 120 J <620 <620 59 14
<20 54 J <20 <20 <20 <20
<2.0 190 J 37 33 44 5.2
<2.0 47 J <6.1 <6.1 4.1 <2.0
19 J 470 J <71 <71 68 J 7.1 J
5.4 J 300 J <38 <38 160 J <2.0
<2.0 6.3 J <17 <17 <2.0 <2.0
<2.0 19 J <15 <15 3.3 <2.0
<2.0 58 J <17 <17 8.4 <2.0
<2.0 11 J <14 <14 <2.0 <2.0
39 J 80 J <72 <72 11 J <2.0
<2.0 <2.0 UJ <6.7 <6.7 <2.0 <2.0
<2.0 <2.0 UJ <27 <27 <2.0 <2.0
<2.0 <2.0 UJ <48 <48 <2.0 <2.0
3.7 4.5 J 200 170 6.2 <2.0
100 9400 200 180 210 350
160 10000 200 180 450 360
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ <4.0
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0
3.4 J <2.0 UJ 3.3 J 3.0 J 5.3 J <2.0
5.7 J 11 J <5.0 UJ <5.0 UJ 6.2 J <5.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
2.3 J <2.0 UJ 5.8 J 5.1 J 5.5 J <2.0
7.4 J 2.0 J 5.0 J 5.8 J 10 J <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
8.1 J 30 J 8.4 J 8.1 J 11 J <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0
5.2 J 8.1 J 5.9 J 6.2 J 10 J <2.0
6.0 J 3.3 B 11 J 11 J 15 J 2.8
TR0807E Page 9 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
21A 21A 22 22 22 23A
April/May 2021 June 2021 February 2021 April/May 2021 June 2021 February 2021
STW-LOC-21A-042921 STW-LOC-21A-061821 STW-LOC-22-3-021921 STW-LOC-22-4-042921 STW-LOC-22-4-061821 STW-LOC-23A-4-021921
04/29/2021 06/18/2021 02/19/2021 04/29/2021 06/18/2021 02/19/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- -- -- --
87 58 250 J 160 J 120 2,900
37 6.1 88 <80 56 J 220
32 9.8 34 <27 22 51
6.2 2.4 8.7 <39 6.7 17
2.5 <2.0 5.3 <59 2.0 8.4
<2.0 <2.0 4.4 <78 <2.0 7.4
30 82 16 <620 13 J <31
<20 <20 <20 <20 <20 <20
<2.0 <2.0 42 <20 <2.0 880
2.3 <2.0 27 <6.1 5.8 36
27 J 7.6 J 13 J <71 16 J 30 J
13 J 3.5 J 270 J <38 110 J 500 J
<2.0 <2.0 <2.0 <17 <2.0 <2.0
5.2 <2.0 3.5 <15 3.5 5.1
<2.0 <2.0 <2.0 <17 <2.0 9.8
<2.0 <2.0 3.0 <14 2.0 5.8
4.4 J <2.0 <2.0 <72 18 J <3.6
<2.0 <2.0 <2.0 <6.7 <2.0 <2.0
<2.0 <2.0 <2.0 <27 <2.0 <2.0
<2.0 <2.0 <2.0 <48 <2.0 <2.4
4.1 6.0 J <25 UJ <2.0 UJ 2.7 J 2.2
200 160 480 160 230 4100
250 170 760 160 380 4700
<2.0 UJ <2.0 UJ <67 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <32 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <46 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <24 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <85 UJ <2.0 UJ <2.0 UJ <2.0
<4.0 UJ <4.0 UJ <140 UJ <4.0 UJ <4.0 UJ <4.0
<5.0 UJ <5.0 UJ <250 UJ <5.0 UJ <5.0 UJ <5.0
<2.0 UJ <2.0 UJ <24 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <40 UJ <2.0 UJ <2.0 UJ <2.0
<5.0 UJ <5.0 UJ <130 UJ <5.0 UJ <5.0 UJ 5.1
<2.0 UJ <2.0 UJ <87 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <43 UJ <2.0 UJ <2.0 UJ <2.0
<5.0 UJ <5.0 UJ <120 UJ <5.0 UJ <5.0 UJ <5.0
3.3 J 5.2 J <20 UJ <2.0 UJ <2.0 UJ <2.0
<5.0 UJ 6.4 J <240 UJ <5.0 UJ <5.0 UJ <5.0
<2.0 UJ <2.0 UJ <32 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <31 UJ <2.0 UJ <2.0 UJ 2.0
<2.0 UJ <2.0 UJ <97 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <55 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <19 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <89 UJ <2.0 UJ <2.0 UJ <2.0
6.2 J 4.7 J <57 UJ 2.5 J <2.0 UJ <2.0
5.7 J 11 J <58 UJ 3.0 J 5.5 J 3.1
<2.0 UJ <2.0 UJ <37 UJ <2.0 UJ <2.0 UJ <2.0
2.1 J <2.0 UJ <27 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <94 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <98 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <30 UJ <2.0 UJ <2.0 UJ <2.0
7.7 J 8.7 J <49 UJ 3.9 J 10 J 3.3
<2.0 UJ <2.0 UJ <73 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <130 UJ <2.0 UJ <2.0 UJ <2.0
<2.0 UJ <2.0 UJ <110 UJ <2.0 UJ <2.0 UJ <2.0
8.2 J 9.6 J <85 UJ 4.7 J 4.4 J 68
36 J 18 J <54 UJ 4.8 J 3.8 J 10
TR0807E Page 10 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
23B 23C-1 23C-1 23C-2 23C-2 23C-2
February 2021 April/May 2021 April/May 2021 April/May 2021 April/May 2021 April/May 2021
STW-LOC-23B-021921 STW-LOC-23C-1-050421
STW-LOC-23C-1-050421-
D STW-LOC-23C-2-042621 STW-LOC-23C-2-042621-
D STW-LOC-23C-2-042921
02/19/2021 05/04/2021 05/04/2021 04/26/2021 04/26/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- Field Duplicate -- Field Duplicate --
460 26 27 29 J 28 55
7.3 7.4 6.8 24 25 37
9.02020242430
2.2 4.5 4.5 3.4 3.7 5.1
<2.0 2.8 2.6 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
17 36 34 46 41 52
<20 <20 <20 <20 <20 <20
16 38 38 <2.0 <2.0 <2.0
<2.0 2.9 3.0 <2.0 <2.0 <2.0
6.6 J 15 J 18 J <2.0 8.6 J 12 J
15 J 130 J 150 J 7.9 J 7.9 J 15 J
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 5.2 5.5 4.3 4.7 4.2
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 3.1 2.8 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 3.7 J
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 4.8 4.1 4.3 3.9 J 3.0
510 150 140 130 130 180
530 290 310 140 140 210
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 6.2 J <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<4.0 <4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ
<5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 3.6 J 3.6 J 3.3 J 3.6 J 3.1 J
<5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 5.8 J 5.2 J 5.0 J 4.7 J 4.8 J
<2.0 6.0 J 6.2 J 6.3 J 6.2 J 5.2 J
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 7.3 J 7.5 J 6.9 J 6.9 J 7.1 J
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
38 15 J 15 J 7.5 J 6.3 J 6.5 J
8.0 13 J 13 J 14 J 13 J 11 J
TR0807E Page 11 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
23C-2 23C-2 23C-3 24A 24A 24A
June 2021 June 2021 June 2021 February 2021 April/May 2021 April/May 2021
STW-LOC-23C-2-4-
061821
STW-LOC-23C-2-4-
061821-D
STW-LOC-23C-3-4-
061821 STW-LOC-24A-021921 STW-LOC-24A-042921
STW-LOC-24A-042921-
D
06/18/2021 06/18/2021 06/18/2021 02/19/2021 04/29/2021 04/29/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- Field Duplicate -- -- -- Field Duplicate
15 15 14 13 39 J 42 J
7.6 7.8 2.4 <2.0 <80 UJ <80
9.7 8.9 6.4 10 <27 UJ <27
<2.0 <2.0 <2.0 <2.0 <39 UJ <39
<2.0 <2.0 <2.0 <2.0 <59 UJ <59
<2.0 <2.0 <2.0 <2.0 <78 UJ <78
26 J 33 J 24 <10 80 J <620
<20 <20 <20 <20 <20 UJ <20
<2.0 <2.0 <2.0 <2.0 <20 UJ 110 J
<2.0 <2.0 <2.0 <2.0 <6.1 UJ <6.1
<2.0 <2.0 <2.0 <2.0 <71 UJ <71
4.3 J 4.6 J 9.8 J <2.0 <38 UJ <38
<2.0 <2.0 <2.0 <2.0 <17 UJ <17
2.8 2.3 <2.0 <2.0 <15 UJ 42 J
<2.0 <2.0 <2.0 <2.0 <17 UJ <17
<2.0 <2.0 <2.0 <2.0 <14 UJ <14
<2.0 <2.0 <2.0 <2.0 <72 UJ <72
<2.0 <2.0 <2.0 <2.0 <6.7 UJ <6.7
<2.0 <2.0 <2.0 <2.0 <27 UJ <27
<2.0 <2.0 <2.0 <2.0 <48 UJ <48
7.8 7.0 2.6 <2.0 3.1 J 2.8 J
61 67 47 23 120 190
65 72 57 23 120 190
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<4.0 UJ <4.0 UJ <4.0 UJ <4.0 <4.0 UJ <4.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 <5.0 UJ <5.0 UJ
4.9 J 4.9 J 2.4 J <2.0 3.2 J 3.2 J
5.4 J 5.5 J <5.0 UJ <5.0 5.9 J 5.4 J
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
5.1 J 5.0 J 2.6 J <2.0 5.4 J 5.3 J
8.9 J 9.8 J 4.7 J <2.0 5.5 J 5.3 J
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
8.8 J 9.4 J 4.7 J <2.0 7.5 J 7.5 J
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 <2.0 UJ <2.0 UJ
8.3 J 8.9 J 4.6 J 2.1 5.4 J 5.7 J
14 J 14 J 6.3 J 4.0 10 J 9.3 J
TR0807E Page 12 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
24A 24B 24B 24B 24B 24B
June 2021 February 2021 February 2021 April/May 2021 June 2021 June 2021
STW-LOC-24A-061821 STW-LOC-24B-021921 STW-LOC-24B-021921-D STW-LOC-24B-042921 STW-LOC-24B-061821 STW-LOC-24B-061821-D
06/18/2021 02/19/2021 02/19/2021 04/29/2021 06/18/2021 06/18/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- Field Duplicate -- -- Field Duplicate
22 J 6.8 J 23 J 48 53 J 92 J
5.0 <2.0 <2.0 35 8.4 8.8
8.1 7.2 7.4 26 8.9 9.1
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
78 15 26 44 39 J 27 J
<20 <20 <20 <20 <20 <20
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
7.5 J <2.0 <2.0 14 J <2.0 <2.0
2.2 J <2.0 <2.0 11 J 2.2 J <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
2.1 <2.0 <2.0 5.2 2.7 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 3.6 J <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
5.9 <2.0 <2.0 3.6 5.6 J 7.6 J
110 29 56 160 80 140
120 29 56 190 82 140
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<4.0 UJ <4.0 <4.0 <4.0 UJ <4.0 UJ <4.0 UJ
<5.0 UJ <5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ
4.9 J <2.0 <2.0 3.5 J 5.1 J 4.9 J
8.1 J <5.0 <5.0 <5.0 UJ 5.6 J 6.1 J
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
4.7 J <2.0 <2.0 5.3 J 4.7 J 5.2 J
11 J <2.0 <2.0 5.9 J 9.6 J 9.5 J
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
9.9 J 2.1 <2.0 8.1 J 9.3 J 9.2 J
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ
8.9 J 2.0 2.2 6.3 J 9.0 J 8.9 J
14 J 3.6 3.4 11 J 14 J 14 J
TR0807E Page 13 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
24C 24C 24C TB TB TB
February 2021 April/May 2021 June 2021 February 2021 February 2021 April/May 2021
STW-LOC-24C-021921 STW-LOC-24C-042921 STW-LOC-24C-061821 STW-TB-021821 STW-LOC-TB-021921 STW-LOC-TB-042621
02/19/2021 04/29/2021 06/18/2021 02/18/2021 02/19/2021 04/26/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
-- -- -- Trip Blank Trip Blank Trip Blank
210 61 110 <4.0 <4.0 <2.0
<4.0 36 4.9 <2.0 <2.0 <2.0
26 27 7.3 <2.0 <2.0 <2.0
9.6 <2.0 <2.0 <2.0 <2.0 <2.0
<3.0 <2.0 <2.0 <2.0 <2.0 <2.0
<3.9 <2.0 <2.0 <2.0 <2.0 <2.0
64 44 49 <10 <10 <10
28 <20 <20 <20 <20 <20
1,000 10 2.3 <2.0 <2.0 <2.0
130 4.5 <2.0 <2.0 <2.0 <2.0
580 J 33 J 15 J <2.0 <2.0 <2.0
1,000 J 17 J 13 J <2.0 <2.0 <2.0
7.1 <2.0 <2.0 <2.0 <2.0 <2.0
160 5.0 2.1 <2.0 <2.0 <2.0
1,200 4.5 <2.0 <2.0 <2.0 <2.0
230 <2.0 <2.0 <2.0 <2.0 <2.0
100 J 5.3 J 2.2 J <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.4 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 3.4 5.5 <2.0 <2.0 <2.0
3100 190 180 ND ND ND
4700 250 210 ND ND ND
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<4.0 <4.0 UJ <4.0 UJ <4.0 <4.0 <4.0 UJ
<5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<5.0 <5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 UJ
<2.0 3.2 J 5.2 J <2.0 <2.0 <2.0 UJ
<5.0 <5.0 UJ 6.0 J <5.0 <5.0 <5.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 5.2 J 4.3 J <2.0 <2.0 <2.0 UJ
2.0 5.2 J 9.9 J <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
2.7 7.4 J 9.0 J <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
<2.0 <2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 UJ
2.4 6.1 J 7.6 J <2.0 <2.0 <2.0 UJ
3.7 8.9 J 10 J <2.0 <2.0 <2.0 UJ
TR0807E Page 14 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
TB TB EB EB EB EB
April/May 2021 April/May 2021 February 2021 February 2021 February 2021 February 2021
STW-LOC-TB-042921 STW-LOC-TB-050421
STW-LOC-EB-DR-
021821 STW-LOC-EB-IS-021821 STW-LOC-EB-DR-
021921 STW-LOC-EB-IS-021921
04/29/2021 05/04/2021 02/18/2021 02/18/2021 02/19/2021 02/19/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
Trip Blank Trip Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank
<2.0 <2.0 <4.0 <4.0 <4.0 <4.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<10 <10 <10 <10 <10 <10
<20 <20 <20 <20 <20 <20
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
ND ND ND ND ND ND
ND ND ND ND ND ND
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<4.0 UJ <4.0 UJ <4.0 <4.0 <4.0 <4.0
<5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 <5.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 <5.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 <5.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<5.0 UJ <5.0 UJ <5.0 <5.0 <5.0 <5.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 <2.0
<2.0 UJ <2.0 UJ <2.0 <2.0 <2.0 3.7
TR0807E Page 15 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
EB EB EB EB EB EB
April/May 2021 April/May 2021 April/May 2021 April/May 2021 June 2021 June 2021
STW-LOC-EB-042621 STW-LOC-EB-DR-
042921 STW-LOC-EB-IS-042921 STW-LOC-EB-DR-
050421
STW-LOC-EB-DR-
061821 STW-LOC-EB-IS-061821
04/26/2021 04/29/2021 04/29/2021 05/04/2021 06/18/2021 06/18/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<10 <10 <10 <10 <10 <10
<20 <20 <20 <20 <20 <20
<2.0 <2.0 2.1 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
ND ND 2.1 ND ND ND
ND ND 2.1 ND ND ND
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
TR0807E Page 16 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Table A1
ANALYTICAL RESULTS - 2021 Q1 AND Q2 SAMPLING EVENTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC, P.C.
Location ID
Sampling Event
Field Sample ID
Date Sampled
Analytical Laboratory
QA/QC
Table 3 + SOP (ng/ L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Perfluoroheptanoic Acid1
Total Table 3+ (17 compounds)2,3
Total Table 3+ (20 compounds)2
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluorohexadecanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Notes
Bold - Analyte detected above associated reporting limit.
ng/L - nanograms per liter
QA/QC - Quality assurance/ quality control
SOP - standard operating procedure
-- - No data reported
< - Analyte not detected above associated reporting limit.
ND - No Table 3+ compounds were detected above their
associated reporting limits.
1 - Perfluoroheptanoic acid is not included in the
calculation of Total Table 3+ (17 Compounds) or Total
Table 3+ (20 Compounds).
2 - Total Table 3+ was calculated including J qualified
data but not non-detect data. The total Table 3+ sum is
rounded to two significant figures.
3 - Total Table 3+ (17 Compounds) does not include R-
PSDA, Hydrolyzed PSDA and R-EVE.
B - Not detected substantially above the level reported in
the laboratory or field blanks.
J - Analyte detected. Reported value may not be accurate
or precise.
UJ – Analyte not detected. Reporting limit may not be
accurate or precise.
FBLK FBLK FBLK FBLK FBLK FBLK
February 2021 February 2021 April/May 2021 April/May 2021 April/May 2021 June 2021
STW-LOC-FB-021821 STW-LOC-FB-021921 STW-LOC-FB-042621 STW-LOC-FB-042921 STW-LOC-FB-050421 STW-LOC-FB-061821
02/18/2021 02/19/2021 04/26/2021 04/29/2021 05/04/2021 06/18/2021
TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica TestAmerica
Field Blank Field Blank Field Blank Field Blank Field Blank Field Blank
<4.0 <4.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<10 <10 <10 <10 <10 <10
<20 <20 <20 <20 <20 <20
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
<2.0 <2.0 <2.0 <2.0 <2.0 <2.0
ND ND ND ND ND ND
ND ND ND ND ND ND
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<4.0 <4.0 <4.0 UJ <4.0 UJ <4.0 UJ <4.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<5.0 <5.0 <5.0 UJ <5.0 UJ <5.0 UJ <5.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
<2.0 <2.0 <2.0 UJ <2.0 UJ <2.0 UJ <2.0 UJ
TR0807E Page 17 of 17 September 2021
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

APPENDIX B
Field Parameters

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE B1FIELD PARAMETERS - 2021 QUARTER 1 - FEBRUARY 2021 EVENTChemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC, P.C.LocationSampling MethodpH Temperature (°C)Specific Conductivity (mS/cm)Dissolved Oxygen (mg/L)ORP (mV)Turbidity (NTU)Observation at Sample Location1Temporal Composite8.27.50.0610.5361182Temporal Composite8.23.90.0611.346193Temporal Composite7.63.70.1212.875114Temporal Composite7.43.70.0212.61456Tubing disconnected between the 11th and the last aliquot. Total ISCO run time was 7.3 hours.5Temporal Composite7.93.20.0512.51851096AGrab7.87.20.0711.3208886BGrab6.8580.022.68797ATemporal Composite7.65.00.0411.7621047BTemporal Composite6.94.40.1011.81041187CTemporal Composite7.26.10.0711.6105988Temporal Composite7.69.40.949.7822Algal blooms noted. Total ISCO run time was 4 hours.9Temporal Composite7.78.70.0910.49412710Temporal Composite7.84.90.0211.0831510ATemporal Composite8.2120.209.6307511Temporal Composite8.25.40.0611.6706012Temporal Composite7.97.90.1010.1781913Temporal Composite7.25.20.0112.11044Missed first collection of first cycle due to no water. Total ISCO run time was 7.3 hours.14Temporal Composite7.8150.149.778615Temporal Composite7.15.50.0411.81047918Temporal Composite9.38.90.109.3515Total ISCO run time was 4 hours.19AGrab7.8310.084.46517419BGrab7.3290.096.6731620Temporal Composite7.46.50.0611.310188ISCO did not start properly, started upon arrival.21AGrab7.13.70.1012.41657822Temporal Composite11.1120.479.3-654Water had scum/solids/foam and was murkey with white water color and mixed odor. Total ISCO run time was 3 hours.23ATemporal Composite7.7100.149.3-31Total ISCO run time was 4 hours.23BGrab7.5130.129.590124AGrab7.3110.0810.21878224BGrab8.39.10.1611.1112024CGrab7.5170.1710.51433Notes:°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltNTU - nephelometric turbidity unitsORP - oxidation reduction potentialField parameters for the temporal composite samples were collected during sampling directly from the water stream only.TR0807EPage 1 of 1September 2021DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE B2FIELD PARAMETERS - 2021 QUARTER 2 - APRIL-MAY 2021 DRY EVENTChemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC, P.C.LocationSampling MethodpH Temperature (°C)Specific Conductivity (mS/cm)Dissolved Oxygen (mg/L)ORP (mV)Turbidity (NTU)Observation at Sample Location1 Temporal Composite 7.4 27 0.10 7.5 129 116A Grab 7.2 30 0.12 7.0 133 5Possibly some rust discoloration of water.6B Grab 8.3 35 0.21 3.0 21 07A Temporal Composite 7.9 29 0.10 7.1 40 97B Temporal Composite 7.7 30 0.12 8.0 108 117C Temporal Composite 7.8 30 0.11 7.5 129 118 Temporal Composite 7.9 27 0.72 8.5 40 1479 Temporal Composite 7.7 30 0.11 6.7 97 1010A Temporal Composite 7.4 30 0.11 8.6 13 37612 Temporal Composite 9.4 31 0.20 8.9 47 1014 Temporal Composite 9.2 37 0.17 6.9 27 515 Temporal Composite 7.7 31 0.09 6.9 129 1518 Temporal Composite 6.7 29 0.09 6.6 188 19419A Grab 4.3 38 1.45 1.8 -11 2219B Grab 8.4 39 0.30 5.5 41 420 Temporal Composite 8.3 29 0.10 8.0 109 1021A Grab 8.0 28 0.32 7.1 9 1922 Temporal Composite 9.0 32 0.13 5.6 59 2,25323C-1 Temporal Composite 7.3 28 0.14 7.7 136 323C-2 Grab 8.3 32 0.41 6.6 -10 323C-2 Grab 7.4 25 0.13 7.4 223 124A Grab 8.6 25 1.98 4.6 -5 624B Grab 5.6 23 1.68 0.9 20 024C Grab 8.6 25 0.51 6.0 14 0Notes:°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltNTU - nephelometric turbidity unitsORP - oxidation reduction potentialField parameters for the temporal composite samples were collected during sampling directly from the water stream only.TR0807EPage 1 of 1September 2021DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
TABLE B3FIELD PARAMETERS - 2021 QUARTER 2 - JUNE 2021 DRY EVENTChemours Fayetteville Works, North CarolinaGeosyntec Consultants of NC, P.C.LocationSampling MethodpH Temperature (°C)Specific Conductivity (mS/cm)Dissolved Oxygen (mg/L)ORP (mV)Turbidity (NTU)Observation at Sample Location1 Temporal Composite 7.6 27 0.14 6.9 108 96A Grab 8.0 30 0.14 7.0 50 266B Grab -- -- -- -- -- --No water coming out of designated sample pipe. Unable to get sample.7A Temporal Composite 8.0 31 0.15 6.6 76 97B Temporal Composite 8.0 31 0.19 7.1 72 97C Temporal Composite 8.2 31 0.34 6.8 58 178 Temporal Composite 7.9 22 1.02 7.1 101 612 Temporal Composite -- -- -- -- -- -- Location is dry.14 Temporal Composite 9.7 30 0.25 9.1 25 7 Significant algal blooms.15 Temporal Composite 7.9 31 0.19 6.6 62 1418 Temporal Composite 7.3 27 0.14 4.7 14 4419A Grab 7.6 38 0.08 5.4 31 2819B Grab 7.6 34 0.18 6.2 42 1720 Temporal Composite 8.3 30 0.19 7.8 36 821A Grab 7.5 34 0.18 6.3 65 822 Temporal Composite 8.8 30 0.25 5.5 29 4923C-2 Temporal Composite 7.8 32 0.17 6.6 41 623C-3 Temporal Composite 7.8 30 0.13 5.5 -9 2024A Grab 7.7 27 0.12 7.6 104 8Sample taken by Nafion personnel in barricade and classified area.24B Grab 7.6 35 0.17 6.5 63 924C Grab 7.8 35 0.17 6.4 63 9Notes:°C - degrees Celsiusmg/L - milligrams per litermS/cm - milliSiemens per centimetermV - millivoltNTU - nephelometric turbidity unitsORP - oxidation reduction potentialField parameters for the temporal composite samples were collected during sampling directly from the water stream only.TR0807EPage 1 of 1September 2021DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

APPENDIX C
Laboratory Reports and Data Review
Narrative Whitebooks

Laboratory reports are provided to NCDEQ
via the Shared OneDrive Folder

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review
Site: Chemours Fayetteville
Project: Stormwater Sampling 02/21
Project Reviewer: Bridget Gavaghan

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Sample Summary

* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank

Field Sample ID Lab Sample ID Sample Matrix Filtered Sample Date Sample Time Sample Purpose
STW-LOC-9-8-021821 320-70384-1 Surface Water N 02/18/2021 12:20 FS
STW-LOC-10-8-021821 320-70384-2 Surface Water N 02/18/2021 12:19 FS
STW-LOC-10A-8-021821 320-70384-3 Surface Water N 02/18/2021 12:19 FS
STW-LOC-11-8-021821 320-70384-4 Surface Water N 02/18/2021 14:50 FS
STW-LOC-12-8-021821 320-70384-5 Surface Water N 02/18/2021 12:19 FS
STW-LOC-13-7.3-021821 320-70384-6 Surface Water N 02/18/2021 12:19 FS
STW-LOC-24B-021921 320-70388-1 Surface Water N 02/19/2021 11:50 FS
STW-LOC-24B-021921-D 320-70388-2 Surface Water N 02/19/2021 11:50 DUP
STW-LOC-23A-4-021921 320-70388-3 Surface Water N 02/19/2021 13:40 FS
STW-LOC-8-4-021921 320-70388-4 Surface Water N 02/19/2021 14:47 FS
STW-LOC-18-4-021921 320-70388-5 Surface Water N 02/19/2021 14:12 FS
STW-LOC-6A-021921 320-70393-1 Surface Water N 02/19/2021 12:30 FS
STW-LOC-6B-021921 320-70393-2 Surface Water N 02/19/2021 13:00 FS
STW-LOC-19A-021921 320-70393-3 Surface Water N 02/19/2021 10:50 FS
STW-LOC-19B-021921 320-70393-4 Surface Water N 02/19/2021 10:55 FS
STW-LOC-23B-021921 320-70393-5 Surface Water N 02/19/2021 10:10 FS
STW-LOC-24A-021921 320-70393-6 Surface Water N 02/19/2021 11:45 FS
STW-LOC-24C-021921 320-70393-7 Surface Water N 02/19/2021 11:55 FS
STW-LOC-1-8-021821 320-70437-1 Surface Water N 02/18/2021 12:20 FS
STW-LOC-1-8-021821-D 320-70437-2 Surface Water N 02/18/2021 12:20 DUP
STW-LOC-FB-021821 320-70437-3 Blank Water N 02/18/2021 12:00 FB
STW-LOC-EB-IS-021821 320-70437-4 Blank Water N 02/18/2021 17:00 EB
STW-LOC-14-8-021821 320-70625-1 Surface Water N 02/18/2021 12:19 FS
STW-LOC-15-8-021821 320-70625-2 Surface Water N 02/18/2021 12:20 FS
STW-LOC-21A-021821 320-70625-3 Surface Water N 02/18/2021 11:00 FS
STW-TB-021821 320-70625-4 Blank Water N 02/18/2021 17:10 TB
STW-LOC-EB-DR-021821 320-70625-5 Blank Water N 02/18/2021 17:00 EB
STW-LOC-2-8-021821 320-70627-1 Surface Water N 02/18/2021 14:00 FS
STW-LOC-3-8-021821 320-70627-2 Surface Water N 02/18/2021 14:07 FS
STW-LOC-4-7.3-021821 320-70627-3 Surface Water N 02/18/2021 11:40 FS
STW-LOC-7A-8-021821 320-70627-4 Surface Water N 02/18/2021 12:20 FS
STW-LOC-7B-8-021821 320-70627-5 Surface Water N 02/18/2021 12:19 FS
STW-LOC-7C-8-021821 320-70627-6 Surface Water N 02/18/2021 12:16 FS
STW-LOC-5-8-021821 320-70807-1 Surface Water N 02/18/2021 15:30 FS
STW-LOC-20-8-021821 320-70807-2 Surface Water N 02/18/2021 18:24 FS
STW-LOC-22-3-021921 320-70807-3 Surface Water N 02/19/2021 14:25 FS
STW-LOC-EB-IS-021921 320-70807-4 Blank Water N 02/19/2021 12:15 EB
STW-LOC-EB-DR-021921 320-70807-5 Blank Water N 02/19/2021 12:10 EB
STW-LOC-TB-021921 320-70807-6 Blank Water N 02/19/2021 12:00 TB
STW-LOC-FB-021921 320-70807-7 Blank Water N 02/19/2021 11:00 FB
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Analytical Protocol

Lab Name Lab Method Parameter Category Sampling Program
Eurofins TestAmerica, Sacramento 537 Modified H.PFC_Trials Stormwater Sampling 2/21
Eurofins TestAmerica, Sacramento 537 Modified Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 2/21
Eurofins TestAmerica, Sacramento Cl. Spec. Table 3 Compound SOP Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 2/21
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review Checklist

Item Description Yes No*
Not
Applicable
(NA)*
DVM
Narrative
Report
Laboratory
Report
Exception
Report
(ER) #
A

Did samples meet laboratory acceptability
requirements upon receipt (i.e., intact, within
temperature, properly preserved, and no
headspace where applicable)?
X X
B
Were samples received by the laboratory in
agreement with the associated chain of
custody?
X X
C

Was the chain of custody properly
completed by the laboratory and/or field
team?
X

D Were samples prepped/analyzed by the
laboratory within method holding times? X X X
E
Were QA/QC criteria met by the laboratory
(method blanks, LCSs/LCSDs, MSs/MSDs,
PDSs, SDs, duplicates/replicates,
surrogates, total/dissolved
differences/RPDs, sample results within
0calibration range)?
X X X
F
Were detections in field/equipment/trip
blanks at levels not requiring sample data
qualification?
X X X
G Were all data usable and not R qualified? X
ER# Description

Other QA/QC Items to Note:

* See DVM Narrative Report, Lab Report, and/or ER # for further details as indicated.

The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process. Overall, the data is acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.

The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Data Verification Module (DVM)

The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™
database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and the
RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs

There are two qualifier fields in EIM:
Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This
qualifier may have many different meanings and can vary between labs and over time within the
same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.

Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory or field
blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.

If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

If the data has been validated by a third party, the field “Validated By” will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.).
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
DVM Narrative ReportContamination detected in equipment blank(s). Sample result does not differ significantly from the analyte concentration detected in the associatedequipment blank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2PFOS0.0033UG/L537 ModifiedB3535_PFC0.0020PQLPage 1 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19A-02192102/19/2021320-70393-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 2 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19A-02192102/19/2021320-70393-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-02192102/19/2021320-70393-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-02192102/19/2021320-70393-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-02192102/19/2021320-70393-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 3 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2PES0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFECA B0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFECA-G0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 4 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2PES0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFECA B0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFECA-G0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Hydrolyzed PSDA0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1R-PSDCA0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1R-EVE0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PEPA0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PS Acid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1EVE Acid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Hydro-PS Acid0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Hydro-EVE Acid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1NVHOS, Acid Form0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFECA-G0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PES0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFECA B0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 5 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-8-02182102/18/2021320-70437-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-8-02182102/18/2021320-70437-1PFECA-G0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-1-8-02182102/18/2021320-70437-1PFECA-G0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 6 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-8-02182102/18/2021320-70807-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-8-02182102/18/2021320-70807-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 7 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-3-02192102/19/2021320-70807-3Perfluorooctadecanoicacid0.094ug/L537 ModifiedUJ3535_PFC0.094PQLSTW-LOC-22-3-02192102/19/2021320-70807-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.085ug/L537 ModifiedUJ3535_PFC0.085PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PFOS0.054UG/L537 ModifiedUJ3535_PFC0.054PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluoroundecanoicAcid0.11UG/L537 ModifiedUJ3535_PFC0.11PQLSTW-LOC-22-3-02192102/19/2021320-70807-3N-methylperfluorooctanesulfonamidoacetic acid0.12UG/L537 ModifiedUJ3535_PFC0.12PQLSTW-LOC-22-3-02192102/19/2021320-70807-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.14ug/L537 ModifiedUJ3535_PFC0.14PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluoropentanoicAcid0.049UG/L537 ModifiedUJ3535_PFC0.049PQLSTW-LOC-22-3-02192102/19/2021320-70807-3Perfluoropentanesulfonic acid (PFPeS)0.030ug/L537 ModifiedUJ3535_PFC0.030PQLSTW-LOC-22-3-02192102/19/2021320-70807-36:2 Fluorotelomersulfonate0.25ug/L537 ModifiedUJ3535_PFC0.25PQLPage 8 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-22-3-02192102/19/2021320-70807-3N-ethylperfluorooctanesulfonamidoacetic acid0.13UG/L537 ModifiedUJ3535_PFC0.13PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorohexanoicAcid0.058UG/L537 ModifiedUJ3535_PFC0.058PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorododecanoicAcid0.055UG/L537 ModifiedUJ3535_PFC0.055PQLSTW-LOC-22-3-02192102/19/2021320-70807-3N-methyl perfluoro-1-octanesulfonamide0.043ug/L537 ModifiedUJ3535_PFC0.043PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PFOA0.085UG/L537 ModifiedUJ3535_PFC0.085PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorodecanoicAcid0.031UG/L537 ModifiedUJ3535_PFC0.031PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorodecaneSulfonic Acid0.032UG/L537 ModifiedUJ3535_PFC0.032PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorohexaneSulfonic Acid0.057UG/L537 ModifiedUJ3535_PFC0.057PQLSTW-LOC-22-3-02192102/19/2021320-70807-3Perfluorobutanoic Acid0.24UG/L537 ModifiedUJ3535_PFC0.24PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorobutaneSulfonic Acid0.020UG/L537 ModifiedUJ3535_PFC0.020PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluoroheptanoicAcid0.025UG/L537 ModifiedUJ3535_PFC0.025PQLSTW-LOC-22-3-02192102/19/2021320-70807-3Perfluoroheptanesulfonic acid (PFHpS)0.019ug/L537 ModifiedUJ3535_PFC0.019PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorononanoicAcid0.027UG/L537 ModifiedUJ3535_PFC0.027PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorotetradecanoicAcid0.073UG/L537 ModifiedUJ3535_PFC0.073PQLSTW-LOC-22-3-02192102/19/2021320-70807-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.046ug/L537 ModifiedUJ3535_PFC0.046PQLSTW-LOC-22-3-02192102/19/2021320-70807-3N-ethylperfluoro-1-octanesulfonamide0.087UG/L537 ModifiedUJ3535_PFC0.087PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorohexadecanoicAcid0.089ug/L537 ModifiedUJ3535_PFC0.089PQLSTW-LOC-22-3-02192102/19/2021320-70807-3Perfluorononanesulfonic acid0.037ug/L537 ModifiedUJ3535_PFC0.037PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorotridecanoicAcid0.13UG/L537 ModifiedUJ3535_PFC0.13PQLSTW-LOC-22-3-02192102/19/2021320-70807-3PerfluorooctaneSulfonamide0.098UG/L537 ModifiedUJ3535_PFC0.098PQLSTW-LOC-22-3-02192102/19/2021320-70807-39Cl-PF3ONS0.024ug/L537 ModifiedUJ3535_PFC0.024PQLPage 9 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-22-3-02192102/19/2021320-70807-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.024ug/L537 ModifiedUJ3535_PFC0.024PQLSTW-LOC-22-3-02192102/19/2021320-70807-311Cl-PF3OUdS0.032ug/L537 ModifiedUJ3535_PFC0.032PQLSTW-LOC-22-3-02192102/19/2021320-70807-3Perfluorododecanesulfonic acid (PFDoS)0.097ug/L537 ModifiedUJ3535_PFC0.097PQLSTW-LOC-22-3-02192102/19/2021320-70807-3DONA0.040ug/L537 ModifiedUJ3535_PFC0.040PQLSTW-LOC-5-8-02182102/18/2021320-70807-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-5-8-02182102/18/2021320-70807-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 10 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-3-02192102/19/2021320-70807-310:2 Fluorotelomersulfonate0.067ug/L537 ModifiedUJ3535_PFC0.067PQLSTW-LOC-5-8-02182102/18/2021320-70807-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 11 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-8-02182102/18/2021320-70437-1R-PSDA0.0024UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-1-8-02182102/18/2021320-70437-1R-PSDA0.0023UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 12 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-02192102/19/2021320-70388-1Hfpo Dimer Acid0.0068UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24B-021921-D02/19/2021320-70388-2Hfpo Dimer Acid0.023UG/L537 ModifiedJ3535_PFC0.0040PQLPage 13 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19A-02192102/19/2021320-70393-3Hfpo Dimer Acid0.082UG/L537 ModifiedJ3535_PFC0.0040PQLPage 14 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-02192102/19/2021320-70393-1R-PSDA0.0075UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-02192102/19/2021320-70393-2R-PSDA0.0037UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6B-02192102/19/2021320-70393-2Hydrolyzed PSDA0.0046UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7A-8-02182102/18/2021320-70627-4R-PSDA0.023UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7A-8-02182102/18/2021320-70627-4Hydrolyzed PSDA0.0044UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7A-8-02182102/18/2021320-70627-4R-EVE0.0046UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7B-8-02182102/18/2021320-70627-5R-PSDA0.023UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7B-8-02182102/18/2021320-70627-5Hydrolyzed PSDA0.025UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7B-8-02182102/18/2021320-70627-5R-EVE0.0055UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7C-8-02182102/18/2021320-70627-6R-PSDA0.45UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7C-8-02182102/18/2021320-70627-6Hydrolyzed PSDA0.27UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-7C-8-02182102/18/2021320-70627-6R-EVE0.071UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-8-4-02192102/19/2021320-70388-4Hydrolyzed PSDA0.032UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-9-8-02182102/18/2021320-70384-1R-PSDA0.86UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLSTW-LOC-9-8-02182102/18/2021320-70384-1Hydrolyzed PSDA1.1UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-9-8-02182102/18/2021320-70384-1R-EVE0.22UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0036PQLPage 15 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23A-4-02192102/19/2021320-70388-3R-PSDA0.030UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLSTW-LOC-23A-4-02192102/19/2021320-70388-3Hydrolyzed PSDA0.50UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23B-02192102/19/2021320-70393-5R-PSDA0.0066UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23B-02192102/19/2021320-70393-5Hydrolyzed PSDA0.015UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-02192102/19/2021320-70393-7R-PSDA0.58UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLSTW-LOC-24C-02192102/19/2021320-70393-7Hydrolyzed PSDA1.0UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-02192102/19/2021320-70393-7R-EVE0.10UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0036PQLSTW-LOC-3-8-02182102/18/2021320-70627-2R-PSDA0.014UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-3-8-02182102/18/2021320-70627-2Hydrolyzed PSDA0.0058UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-3-8-02182102/18/2021320-70627-2R-EVE0.0034UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-4-7.3-02182102/18/2021320-70627-3R-PSDA0.0073UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-4-7.3-02182102/18/2021320-70627-3Hydrolyzed PSDA0.049UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-02182102/18/2021320-70625-3R-PSDA0.0071UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-2-8-02182102/18/2021320-70627-1R-PSDA0.011UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-2-8-02182102/18/2021320-70627-1Hydrolyzed PSDA0.0050UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-2-8-02182102/18/2021320-70627-1R-EVE0.0036UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-10-8-02182102/18/2021320-70384-2R-PSDA0.17UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep0.0035PQLPage 16 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSOPSTW-LOC-10-8-02182102/18/2021320-70384-2Hydrolyzed PSDA0.16UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-10-8-02182102/18/2021320-70384-2R-EVE0.076UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0036PQLSTW-LOC-10A-8-02182102/18/2021320-70384-3R-PSDA0.57UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLSTW-LOC-10A-8-02182102/18/2021320-70384-3Hydrolyzed PSDA0.74UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-10A-8-02182102/18/2021320-70384-3R-EVE0.15UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0036PQLSTW-LOC-11-8-02182102/18/2021320-70384-4R-PSDA0.15UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-11-8-02182102/18/2021320-70384-4Hydrolyzed PSDA0.11UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-11-8-02182102/18/2021320-70384-4R-EVE0.064UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-12-8-02182102/18/2021320-70384-5R-PSDA0.014UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-13-7.3-02182102/18/2021320-70384-6R-PSDA0.028UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-13-7.3-02182102/18/2021320-70384-6Hydrolyzed PSDA0.0045UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-13-7.3-02182102/18/2021320-70384-6R-EVE0.0078UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-14-8-02182102/18/2021320-70625-1R-PSDA0.011UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-15-8-02182102/18/2021320-70625-2R-PSDA1.2UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0035PQLSTW-LOC-15-8-02182102/18/2021320-70625-2Hydrolyzed PSDA1.0UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-15-8-02182102/18/2021320-70625-2R-EVE0.26UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0036PQLPage 17 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-18-4-02192102/19/2021320-70388-5R-PSDA0.0091UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-18-4-02192102/19/2021320-70388-5Hydrolyzed PSDA0.0040UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-18-4-02192102/19/2021320-70388-5R-EVE0.0035UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2R-PSDA0.41UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hydrolyzed PSDA0.30UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2R-EVE0.067UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 18 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2NVHOS, Acid Form0.019UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hydro-PS Acid0.047ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hydro-EVE Acid0.011UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2EVE Acid0.058UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFMOAA0.18ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO2HxA0.23ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO3OA0.12ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO4DA0.080ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO5DA0.077ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2NVHOS, Salt Form0.019UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PS Acid0.19UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PEPA0.054UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PMPA0.12UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hfpo Dimer Acid8.2UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2R-PSDCA0.0063UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 19 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-5-8-02182102/18/2021320-70807-1PFMOAA0.0037ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1R-PSDA0.0042UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PMPA0.016UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFO2HxA0.011ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFO3OA0.0049ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFO4DA0.0022ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-5-8-02182102/18/2021320-70807-1PFO5DA0.0026ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2NVHOS, Acid Form0.013UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hydro-PS Acid0.032ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hydro-EVE Acid0.0082UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2EVE Acid0.043UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFMOAA0.17ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO2HxA0.17ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO3OA0.068ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO4DA0.051ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFO5DA0.053ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PS Acid0.13UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 20 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-8-02182102/18/2021320-70807-2PEPA0.034UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PMPA0.084UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-20-8-02182102/18/2021320-70807-2R-PSDA0.47UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hydrolyzed PSDA0.28UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2R-PSDCA0.0047UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2R-EVE0.080UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 21 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-8-02182102/18/2021320-70437-1PMPA0.010UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-1-8-02182102/18/2021320-70437-1PMPA0.010UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 22 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 2/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-22-3-02192102/19/2021320-70807-3Hfpo Dimer Acid0.25UG/L537 ModifiedJ3535_PFC0.15PQLSTW-LOC-5-8-02182102/18/2021320-70807-1Hfpo Dimer Acid0.34UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluoroheptanoicAcid0.0045UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Perfluorobutanoic Acid0.011UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PFOA0.0081UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluorohexanoicAcid0.0020UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2PerfluoropentanoicAcid0.030UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-8-02182102/18/2021320-70807-2Hfpo Dimer Acid6.6UG/L537 ModifiedJ3535_PFC0.075PQLPage 23 of 23DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review
Site: Chemours Fayetteville
Project: Stormwater Sampling 04/21
Project Reviewer: Bridget Gavaghan

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Sample Summary

* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank

Field Sample ID Lab Sample ID Sample Matrix Filtered Sample Date Sample Time Sample Purpose
STW-LOC-23C-2-042621 320-72886-1 Surface Water N 04/26/2021 15:45 FS
STW-LOC-23C-2-042621-D 320-72886-2 Surface Water N 04/26/2021 15:45 DUP
STW-LOC-FB-042621 320-72886-3 Blank Water N 04/26/2021 16:00 FB
STW-LOC-TB-042621 320-72886-4 Blank Water N 04/26/2021 16:30 TB
STW-LOC-EB-042621 320-72886-5 Blank Water N 04/26/2021 16:35 EB
STW-LOC-21A-042921 320-73130-1 Surface Water N 04/29/2021 11:15 FS
STW-LOC-6B-042921 320-73130-2 Surface Water N 04/29/2021 12:05 FS
STW-LOC-19A-042921 320-73130-3 Surface Water N 04/29/2021 12:25 FS
STW-LOC-19B-042921 320-73130-4 Surface Water N 04/29/2021 12:30 FS
STW-LOC-23C-2-042921 320-73130-5 Surface Water N 04/29/2021 15:05 FS
STW-LOC-24B-042921 320-73130-6 Surface Water N 04/29/2021 10:10 FS
STW-LOC-24C-042921 320-73130-7 Surface Water N 04/29/2021 10:18 FS
STW-LOC-EB-IS-042921 320-73133-1 Blank Water N 04/29/2021 15:00 EB
STW-LOC-EB-DR-042921 320-73133-2 Blank Water N 04/29/2021 15:05 EB
STW-LOC-TB-042921 320-73133-3 Blank Water N 04/29/2021 17:00 TB
STW-LOC-FB-042921 320-73133-4 Blank Water N 04/29/2021 15:10 FB
STW-LOC-20-4-042921 320-73133-5 Surface Water N 04/29/2021 16:23 FS
STW-LOC-20-4-042921-D 320-73133-6 Surface Water N 04/29/2021 16:23 DUP
STW-LOC-18-4-042921 320-73133-7 Surface Water N 04/29/2021 14:16 FS
STW-LOC-24A-042921 320-73135-1 Surface Water N 04/29/2021 10:50 FS
STW-LOC-24A-042921-D 320-73135-2 Surface Water N 04/29/2021 10:50 DUP
STW-LOC-15-4-021921 320-73135-3 Surface Water N 04/29/2021 16:54 FS
STW-LOC-1-4-042921 320-73136-1 Surface Water N 04/29/2021 14:30 FS
STW-LOC-7A-4-042921 320-73136-2 Surface Water N 04/29/2021 16:44 FS
STW-LOC-7B-4-042921 320-73136-3 Surface Water N 04/29/2021 16:56 FS
STW-LOC-7C-4-042921 320-73136-4 Surface Water N 04/29/2021 16:32 FS
STW-LOC-8-4-042921 320-73136-5 Surface Water N 04/29/2021 15:36 FS
STW-LOC-9-4-042921 320-73138-1 Surface Water N 04/29/2021 14:40 FS
STW-LOC-10A-4-042921 320-73138-2 Surface Water N 04/29/2021 15:00 FS
STW-LOC-12-4-042921 320-73138-3 Surface Water N 04/29/2021 15:53 FS
STW-LOC-14-4-042921 320-73138-4 Surface Water N 04/29/2021 16:01 FS
STW-LOC-22-4-042921 320-73138-5 Surface Water N 04/29/2021 15:26 FS
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Analytical Protocol

Lab Name Lab Method Parameter Category Sampling Program
Eurofins TestAmerica, Sacramento 537 Modified H.PFC_Trials STORMWATER SAMPLING 4/21
Eurofins TestAmerica, Sacramento 537 Modified Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 4/21
Eurofins TestAmerica, Sacramento Cl. Spec. Table 3 Compound SOP Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 4/21
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review Checklist

Item Description Yes No*
Not
Applicable
(NA)*
DVM
Narrative
Report
Laboratory
Report
Exception
Report
(ER) #
A

Did samples meet laboratory acceptability
requirements upon receipt (i.e., intact, within
temperature, properly preserved, and no
headspace where applicable)?
X
B
Were samples received by the laboratory in
agreement with the associated chain of
custody?
X X
C

Was the chain of custody properly
completed by the laboratory and/or field
team?
X
D Were samples prepped/analyzed by the
laboratory within method holding times? X X X
E
Were QA/QC criteria met by the laboratory
(method blanks, LCSs/LCSDs, MSs/MSDs,
PDSs, SDs, duplicates/replicates,
surrogates, total/dissolved
differences/RPDs, sample results within
calibration range)?
X X X
F
Were detections in field/equipment/trip
blanks at levels not requiring sample data
qualification?
X
G Were all data usable and not R qualified? X
ER# Description

Other QA/QC Items to Note:

* See DVM Narrative Report, Lab Report, and/or ER # for further details as indicated.

The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process. Overall, the data is acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.

The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Data Verification Module (DVM)

The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™
database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and the
RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs

There are two qualifier fields in EIM:
Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This
qualifier may have many different meanings and can vary between labs and over time within the
same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.

Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory or field
blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.

If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

If the data has been validated by a third party, the field “Validated By” will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.).
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
DVM Narrative ReportOnly one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-04292104/29/2021320-73130-4PES0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PFECA B0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4R-PSDA0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Hydrolyzed PSDA0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4R-PSDCA0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4R-EVE0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PEPA0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PS Acid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4EVE Acid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Hydro-PS Acid0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Hydro-EVE Acid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4NVHOS, Acid Form0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PFECA-G0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluoroheptanoicAcid0.0020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PFO3OA0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PFO4DA0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 1 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-04292104/29/2021320-73130-4PFO5DA0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 2 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-4-04292104/29/2021320-73136-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-1-4-04292104/29/2021320-73136-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-1-4-04292104/29/2021320-73136-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 3 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-10A-4-04292104/29/2021320-73138-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 4 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-32-(N-ethyl perfluoro-1-0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 5 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsoctanesulfonamido)-ethanolSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-12-4-04292104/29/2021320-73138-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-12-4-04292104/29/2021320-73138-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 6 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-04292104/29/2021320-73138-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-04292104/29/2021320-73138-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 7 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 8 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 9 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorobutanoic Acid(trial)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorononanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorodecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoroundecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorododecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3N-ethylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-3N-methylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorotetradecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorotridecanoicAcid (TRIAL)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-310:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-38:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-34:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3NEtPFOSAE (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3NMePFOSAE (trial)0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-15-4-02192104/29/2021320-73135-36:2 FTS (trial)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-02192104/29/2021320-73135-3DONA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3F-53B Major (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3F-53B Minor (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 10 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3NEtPFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3NMePFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFDS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFDoS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFHpS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFHxDA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorononanesulfonic acid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Perfluorooctadecanoicacid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFPeS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-710:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 11 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-18-4-04292104/29/2021320-73133-7Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-71H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-04292104/29/2021320-73133-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-79Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-71H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 12 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-18-4-04292104/29/2021320-73133-711Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-04292104/29/2021320-73133-7DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 13 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19A-04292104/29/2021320-73130-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorooctaneSulfonamide (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-04292104/29/2021320-73130-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-19A-04292104/29/2021320-73130-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-04292104/29/2021320-73130-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19B-04292104/29/2021320-73130-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19B-04292104/29/2021320-73130-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLPage 14 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-04292104/29/2021320-73130-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19B-04292104/29/2021320-73130-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 15 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-04292104/29/2021320-73133-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-04292104/29/2021320-73133-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 16 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-610:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLPage 17 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-4-042921-D04/29/2021320-73133-6Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-66:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-61H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-69Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-61H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-611Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 18 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-04292104/29/2021320-73130-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-21A-04292104/29/2021320-73130-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-04292104/29/2021320-73130-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 19 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-21A-04292104/29/2021320-73130-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-04292104/29/2021320-73130-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-04292104/29/2021320-73138-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-22-4-04292104/29/2021320-73138-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-04292104/29/2021320-73138-5N-ethylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 20 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacidSTW-LOC-22-4-04292104/29/2021320-73138-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 21 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-22-4-04292104/29/2021320-73138-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04262104/26/2021320-72886-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 22 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-04262104/26/2021320-72886-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2N-ethylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 23 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacidSTW-LOC-23C-2-042621-D04/26/2021320-72886-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 24 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 25 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-04292104/29/2021320-73130-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 26 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorobutanoic Acid(trial)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-1N-ethylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-1N-methylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 27 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacid (TRIAL)STW-LOC-24A-04292104/29/2021320-73135-1PerfluorotetradecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorotridecanoicAcid (TRIAL)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-110:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-18:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-14:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1NEtPFOSAE (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1NMePFOSAE (trial)0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24A-04292104/29/2021320-73135-16:2 FTS (trial)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-1DONA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1F-53B Major (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1F-53B Minor (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1NEtPFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1NMePFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFDS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFDoS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFHpS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFHxDA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorononanesulfonic acid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorooctadecanoicacid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFPeS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorononanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 28 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorodecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoroundecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorododecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorooctaneSulfonamide (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-042921-D04/29/2021320-73135-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 29 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-610:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-04292104/29/2021320-73130-6Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24B-04292104/29/2021320-73130-6Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-66:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLPage 30 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-04292104/29/2021320-73130-6N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-61H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-69Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-61H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-611Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-710:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 31 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-71H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-79Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-71H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-711Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-6B-04292104/29/2021320-73130-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 32 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6B-04292104/29/2021320-73130-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6B-04292104/29/2021320-73130-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 33 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6B-04292104/29/2021320-73130-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-04292104/29/2021320-73130-7Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-04292104/29/2021320-73130-7Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-76:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-04292104/29/2021320-73130-7N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-04292104/29/2021320-73130-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLPage 34 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7A-4-04292104/29/2021320-73136-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 35 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7A-4-04292104/29/2021320-73136-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7B-4-04292104/29/2021320-73136-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLPage 36 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7B-4-04292104/29/2021320-73136-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 37 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-04262104/26/2021320-72886-5Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-04262104/26/2021320-72886-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-04262104/26/2021320-72886-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-04262104/26/2021320-72886-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 38 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-04262104/26/2021320-72886-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 39 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 40 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-DR-04292104/29/2021320-73133-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-04292104/29/2021320-73133-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLPage 41 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 42 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-04292104/29/2021320-73133-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-04262104/26/2021320-72886-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04262104/26/2021320-72886-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04262104/26/2021320-72886-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 43 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 44 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-FB-04262104/26/2021320-72886-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04262104/26/2021320-72886-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-04292104/29/2021320-73133-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04292104/29/2021320-73133-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04292104/29/2021320-73133-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 45 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-04292104/29/2021320-73133-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-TB-04262104/26/2021320-72886-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 46 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-TB-04262104/26/2021320-72886-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04262104/26/2021320-72886-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04262104/26/2021320-72886-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 47 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-TB-04262104/26/2021320-72886-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04262104/26/2021320-72886-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-TB-04292104/29/2021320-73133-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3N-methylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 48 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacidSTW-LOC-TB-04292104/29/2021320-73133-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04292104/29/2021320-73133-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 49 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-TB-04292104/29/2021320-73133-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-04292104/29/2021320-73133-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 50 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7B-4-04292104/29/2021320-73136-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-04292104/29/2021320-73136-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 51 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7C-4-04292104/29/2021320-73136-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 52 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-8-4-04292104/29/2021320-73136-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-8-4-04292104/29/2021320-73136-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 53 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-8-4-04292104/29/2021320-73136-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-9-4-04292104/29/2021320-73138-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-9-4-04292104/29/2021320-73138-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 54 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3PES0.0067UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0067PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PES0.0067UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0067PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoroheptanoicAcid0.094UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.094PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoroheptanoicAcid0.094UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.094PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO2HxA0.027ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO2HxA0.027ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO3OA0.039ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.039PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO3OA0.039ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.039PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO4DA0.059ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.059PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO4DA0.059ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.059PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO5DA0.078ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.078PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFO5DA0.078ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.078PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFMOAA0.080ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.080PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFMOAA0.080ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.080PQLSTW-LOC-15-4-02192104/29/2021320-73135-3EVE Acid0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-15-4-02192104/29/2021320-73135-3EVE Acid0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hydro-PS Acid0.0061ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0061PQLPage 55 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3Hydro-PS Acid0.0061ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0061PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hydro-EVE Acid0.014UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.014PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hydro-EVE Acid0.014UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.014PQLSTW-LOC-15-4-02192104/29/2021320-73135-3NVHOS, Acid Form0.015UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLSTW-LOC-15-4-02192104/29/2021320-73135-3NVHOS, Acid Form0.015UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFECA-G0.048UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.048PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFECA-G0.048UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.048PQLSTW-LOC-15-4-02192104/29/2021320-73135-3R-PSDA0.071UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.071PQLSTW-LOC-15-4-02192104/29/2021320-73135-3R-PSDA0.071UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.071PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hydrolyzed PSDA0.038UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.038PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hydrolyzed PSDA0.038UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.038PQLSTW-LOC-15-4-02192104/29/2021320-73135-3R-PSDCA0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-15-4-02192104/29/2021320-73135-3R-PSDCA0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-15-4-02192104/29/2021320-73135-3R-EVE0.072UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.072PQLSTW-LOC-15-4-02192104/29/2021320-73135-3R-EVE0.072UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.072PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PEPA0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PEPA0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 56 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3PFECA B0.027UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFECA B0.027UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PS Acid0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PS Acid0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PES0.0067UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0067PQLSTW-LOC-24A-04292104/29/2021320-73135-1PES0.0067UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0067PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFECA B0.027UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFECA B0.027UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-24A-04292104/29/2021320-73135-1R-PSDA0.071UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.071PQLSTW-LOC-24A-04292104/29/2021320-73135-1R-PSDA0.071UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.071PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hydrolyzed PSDA0.038UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.038PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hydrolyzed PSDA0.038UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.038PQLSTW-LOC-24A-04292104/29/2021320-73135-1R-PSDCA0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-24A-04292104/29/2021320-73135-1R-PSDCA0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-24A-04292104/29/2021320-73135-1R-EVE0.072UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.072PQLSTW-LOC-24A-04292104/29/2021320-73135-1R-EVE0.072UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.072PQLSTW-LOC-24A-04292104/29/2021320-73135-1PEPA0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLPage 57 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-04292104/29/2021320-73135-1PEPA0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoroheptanoicAcid0.094UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.094PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoroheptanoicAcid0.094UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.094PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO2HxA0.027ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO2HxA0.027ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.027PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO3OA0.039ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.039PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO3OA0.039ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.039PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO4DA0.059ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.059PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO4DA0.059ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.059PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO5DA0.078ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.078PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFO5DA0.078ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.078PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFMOAA0.080ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.080PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFMOAA0.080ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.080PQLSTW-LOC-24A-04292104/29/2021320-73135-1EVE Acid0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-24A-04292104/29/2021320-73135-1EVE Acid0.017UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.017PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hydro-PS Acid0.0061ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0061PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hydro-PS Acid0.0061ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0061PQLPage 58 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-04292104/29/2021320-73135-1Hydro-EVE Acid0.014UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.014PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hydro-EVE Acid0.014UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.014PQLSTW-LOC-24A-04292104/29/2021320-73135-1NVHOS, Acid Form0.015UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLSTW-LOC-24A-04292104/29/2021320-73135-1NVHOS, Acid Form0.015UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.015PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFECA-G0.048UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.048PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFECA-G0.048UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.048PQLSTW-LOC-24A-04292104/29/2021320-73135-1PS Acid0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PS Acid0.020UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hfpo Dimer Acid (trial)0.081UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.081PQLPage 59 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-042921-D04/29/2021320-73135-2NVHOS, Acid Form0.042UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.015PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PS Acid0.11UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PMPA0.080UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24A-04292104/29/2021320-73135-1PMPA0.081UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2R-PSDA0.0086UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Hfpo Dimer Acid0.021UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Hfpo Dimer Acid0.029UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PFO2HxA0.057ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.027PQLPage 60 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-04292104/29/2021320-73130-4PFMOAA0.020ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PFO2HxA0.0098ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PMPA0.039UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-19B-04292104/29/2021320-73130-4Hfpo Dimer Acid0.018UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 61 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3Hfpo Dimer Acid (trial)0.20UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.081PQLPage 62 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24C-04292104/29/2021320-73130-7R-PSDA0.033UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7Hydrolyzed PSDA0.017UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7R-EVE0.0053UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6R-PSDA0.014UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6Hydrolyzed PSDA0.011UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6R-EVE0.0036UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5R-PSDA0.012UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Hydrolyzed PSDA0.015UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5R-EVE0.0037UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2Hydrolyzed PSDA0.0079UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1Hydrolyzed PSDA0.0079UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1R-PSDA0.027UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1Hydrolyzed PSDA0.013UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1R-EVE0.0044UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 63 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorobutaneSulfonic Acid0.0035UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluoroheptanoicAcid0.0035UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorohexaneSulfonic Acid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PFOA0.0065UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluorohexanoicAcid0.0065UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PerfluoropentanoicAcid0.0095UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1PFOS0.013UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PFOA0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-9-4-04292104/29/2021320-73138-1Hfpo Dimer Acid0.13UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Perfluorobutanoic Acid0.0080UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorobutaneSulfonic Acid0.0024UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluoroheptanoicAcid0.0029UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluorohexanoicAcid0.0057UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5PerfluoropentanoicAcid0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorobutaneSulfonic Acid0.0038UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluoroheptanoicAcid0.0033UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorohexaneSulfonic Acid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-04292104/29/2021320-73136-5Hfpo Dimer Acid0.20UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PFOA0.0065UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PFOS0.012UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluorohexanoicAcid0.0066UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4PerfluoropentanoicAcid0.0074UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorobutaneSulfonic Acid0.0034UG/L537 ModifiedJ3535_PFC0.0020PQLPage 64 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluoroheptanoicAcid0.0030UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorohexaneSulfonic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-04292104/29/2021320-73136-4Hfpo Dimer Acid0.062UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PFOA0.0068UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PFOS0.012UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluorohexanoicAcid0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3PerfluoropentanoicAcid0.0080UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorobutaneSulfonic Acid0.0039UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluoroheptanoicAcid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorohexaneSulfonic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-04292104/29/2021320-73136-3Hfpo Dimer Acid0.058UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PFOA0.0067UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluorohexanoicAcid0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2PerfluoropentanoicAcid0.0080UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorobutaneSulfonic Acid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluoroheptanoicAcid0.0029UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorohexaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PFOA0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluoropentanoicAcid0.0074UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PerfluorohexanoicAcid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-04292104/29/2021320-73130-7PFOS0.0089UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorobutaneSulfonic Acid0.0035UG/L537 ModifiedJ3535_PFC0.0020PQLPage 65 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-04292104/29/2021320-73130-6PerfluoroheptanoicAcid0.0030UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-04292104/29/2021320-73136-2Hfpo Dimer Acid0.061UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24C-04292104/29/2021320-73130-7Hfpo Dimer Acid0.052UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorohexaneSulfonic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PFOA0.0063UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluorohexanoicAcid0.0059UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PerfluoropentanoicAcid0.0081UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-04292104/29/2021320-73130-6Hfpo Dimer Acid0.041UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PFOA0.0057UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorohexaneSulfonic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Perfluorobutanoic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorobutaneSulfonic Acid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluoroheptanoicAcid0.0028UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluorohexanoicAcid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PerfluoropentanoicAcid0.0075UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2PFOS0.0093UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hfpo Dimer Acid (trial)0.039UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorobutaneSulfonic Acid (trial)0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorohexaneSulfonic Acid (trial)0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-042921-D04/29/2021320-73135-2Hfpo Dimer Acid0.042UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoropentanoicAcid (trial)0.0077UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorohexanoicAcid (trial)0.0056UG/L537 ModifiedJ3535_PFC0.0020PQLPage 66 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:STORMWATER SAMPLING 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoroheptanoicAcid (trial)0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorohexaneSulfonic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Perfluorobutanoic Acid0.0059UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorobutaneSulfonic Acid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoroheptanoicAcid0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFOA0.0054UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorobutaneSulfonic Acid0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluoroheptanoicAcid0.0025UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluorohexanoicAcid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFOS (trial)0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFOA (trial)0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PerfluoropentanoicAcid0.0075UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1PFOS0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorohexaneSulfonic Acid0.0048UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PFOA0.0065UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-04292104/29/2021320-73135-1Hfpo Dimer Acid0.039UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluorohexanoicAcid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PerfluoropentanoicAcid0.0071UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorobutaneSulfonic Acid0.0036UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluoroheptanoicAcid0.0039UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorohexaneSulfonic Acid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04292104/29/2021320-73130-5Hfpo Dimer Acid0.045UG/L537 ModifiedJ3535_PFC0.0040PQLPage 67 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PFOA0.0063UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluoropentanoicAcid0.0069UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PerfluorohexanoicAcid0.0062UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-042621-D04/26/2021320-72886-2PFOS0.013UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorobutaneSulfonic Acid0.0033UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluoroheptanoicAcid0.0033UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorohexaneSulfonic Acid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PFOA0.0075UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluorohexanoicAcid0.0063UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PerfluoropentanoicAcid0.0069UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-04262104/26/2021320-72886-1PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorohexaneSulfonic Acid0.0025UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PFOA0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PFOS0.0048UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluorohexanoicAcid0.0030UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5PerfluoropentanoicAcid0.0039UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorononanoicAcid0.0021UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorobutaneSulfonic Acid0.0033UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluoroheptanoicAcid0.0037UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-04292104/29/2021320-73138-5Hfpo Dimer Acid0.16UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorohexaneSulfonic Acid0.0062UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PFOA0.0082UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PerfluorohexanoicAcid0.0057UG/L537 ModifiedJ3535_PFC0.0020PQLPage 68 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-21A-04292104/29/2021320-73130-1PerfluoropentanoicAcid0.0077UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1PFOS0.036UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorobutaneSulfonic Acid0.0030UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluoroheptanoicAcid0.0030UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorohexaneSulfonic Acid0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PFOA0.0062UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-04292104/29/2021320-73130-1Hfpo Dimer Acid0.080UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluorohexanoicAcid0.0058UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6PerfluoropentanoicAcid0.0081UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-042921-D04/29/2021320-73133-6Hfpo Dimer Acid0.11UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorobutaneSulfonic Acid0.0033UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluoroheptanoicAcid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorohexaneSulfonic Acid0.0058UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PFOA0.0059UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluorohexanoicAcid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5PerfluoropentanoicAcid0.0084UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-04292104/29/2021320-73133-5Hfpo Dimer Acid0.099UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-19B-04292104/29/2021320-73130-4PFOA0.0027UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PFOA0.0022UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluorohexanoicAcid0.0022UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-04292104/29/2021320-73130-4PerfluoropentanoicAcid0.0030UG/L537 ModifiedJ3535_PFC0.0020PQLPage 69 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-04292104/29/2021320-73130-4PFOS0.0023UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluorohexanoicAcid0.0022UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PerfluoropentanoicAcid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-04292104/29/2021320-73130-3PFOS0.0020UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hfpo Dimer Acid (trial)0.12UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-19B-04292104/29/2021320-73130-4Hfpo Dimer Acid0.015UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-19A-04292104/29/2021320-73130-3Hfpo Dimer Acid0.014UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-18-4-04292104/29/2021320-73133-76:2 Fluorotelomersulfonate0.0052ug/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-18-4-04292104/29/2021320-73133-7Hfpo Dimer Acid0.010UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorobutaneSulfonic Acid (trial)0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorohexaneSulfonic Acid (trial)0.0056UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoropentanoicAcid (trial)0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorohexanoicAcid (trial)0.0057UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoroheptanoicAcid (trial)0.0036UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorobutaneSulfonic Acid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoroheptanoicAcid0.0035UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorohexaneSulfonic Acid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFOA0.0063UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PFOA0.0089UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluorohexanoicAcid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PerfluoropentanoicAcid0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PFOS (trial)0.011UG/L537 ModifiedJ3535_PFC0.0020PQLPage 70 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-02192104/29/2021320-73135-3PFOA (trial)0.0062UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3Hfpo Dimer Acid0.12UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorohexaneSulfonic Acid0.0079UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Perfluorobutanoic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorobutaneSulfonic Acid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluoroheptanoicAcid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluorohexanoicAcid0.0095UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PerfluoropentanoicAcid0.012UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorobutaneSulfonic Acid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluoroheptanoicAcid0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-04292104/29/2021320-73138-4Hfpo Dimer Acid0.044UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorohexaneSulfonic Acid0.0075UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PFOA0.012UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluorohexanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PerfluoropentanoicAcid0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3PFOS0.023UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorobutaneSulfonic Acid0.0036UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluoroheptanoicAcid0.0043UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-12-4-04292104/29/2021320-73138-3Hfpo Dimer Acid0.046UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorohexaneSulfonic Acid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PFOA0.0068UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluorohexanoicAcid0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLPage 71 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-10A-4-04292104/29/2021320-73138-2PerfluoropentanoicAcid0.0094UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2PFOS0.012UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorobutaneSulfonic Acid0.0035UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluoroheptanoicAcid0.0035UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-10A-4-04292104/29/2021320-73138-2Hfpo Dimer Acid0.15UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorohexaneSulfonic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PFOA0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluorohexanoicAcid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PerfluoropentanoicAcid0.0073UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1PFOS0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-04292104/29/2021320-73136-1Hfpo Dimer Acid0.034UG/L537 ModifiedJ3535_PFC0.0040PQLPage 72 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 4/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-18-4-04292104/29/2021320-73133-7PFMOAA0.0083ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PMPA0.077UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-15-4-02192104/29/2021320-73135-3PMPA0.079UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 73 of 73DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review
Site: Chemours Fayetteville
Project: Stormwater Sampling 5/21
Project Reviewer: Bridget Gavaghan

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Sample Summary

* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank

Field Sample ID Lab Sample ID Sample Matrix Filtered Sample Date Sample Time Sample Purpose
STW-LOC-6A-050421 320-73327-1 Surface Water N 05/04/2021 13:20 FS
STW-LOC-EB-DR-050421 320-73327-2 Blank Water N 05/04/2021 16:00 EB
STW-LOC-TB-050421 320-73327-3 Blank Water N 05/04/2021 17:00 TB
STW-LOC-FB-050421 320-73327-4 Blank Water N 05/04/2021 14:30 FB
STW-LOC-23C-1-050421 320-73327-5 Surface Water N 05/04/2021 14:10 FS
STW-LOC-23C-1-050421-D 320-73327-6 Surface Water N 05/04/2021 14:10 DUP
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Analytical Protocol

Lab Name Lab Method Parameter Category Sampling Program
Eurofins TestAmerica, Sacramento 537 Modified Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 5/21
Eurofins TestAmerica, Sacramento Cl. Spec. Table 3 Compound SOP Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 5/21
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review Checklist

Item Description Yes No*
Not
Applicable
(NA)*
DVM
Narrative
Report
Laboratory
Report
Exception
Report
(ER) #
A

Did samples meet laboratory acceptability
requirements upon receipt (i.e., intact, within
temperature, properly preserved, and no
headspace where applicable)?
X
B
Were samples received by the laboratory in
agreement with the associated chain of
custody?
X X
C

Was the chain of custody properly
completed by the laboratory and/or field
team?
X
D Were samples prepped/analyzed by the
laboratory within method holding times? X X X
E
Were QA/QC criteria met by the laboratory
(method blanks, LCSs/LCSDs, MSs/MSDs,
PDSs, SDs, duplicates/replicates,
surrogates, total/dissolved
differences/RPDs, sample results within
calibration range)?
X X X
F
Were detections in field/equipment/trip
blanks at levels not requiring sample data
qualification?
X
G Were all data usable and not R qualified? X
ER# Description

Other QA/QC Items to Note:

* See DVM Narrative Report, Lab Report, and/or ER # for further details as indicated.

The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process. Overall, the data is acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.

The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Data Verification Module (DVM)

The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™
database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and the
RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs

There are two qualifier fields in EIM:
Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This
qualifier may have many different meanings and can vary between labs and over time within the
same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.

Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory or field
blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.

If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

If the data has been validated by a third party, the field “Validated By” will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.).
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
DVM Narrative ReportThe preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-1-05042105/04/2021320-73327-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-05042105/04/2021320-73327-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 1 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-610:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-66:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 2 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-61H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-69Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-61H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-611Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 3 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 4 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-05042105/04/2021320-73327-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 5 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-DR-05042105/04/2021320-73327-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-05042105/04/2021320-73327-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-05042105/04/2021320-73327-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-05042105/04/2021320-73327-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 6 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-05042105/04/2021320-73327-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-TB-05042105/04/2021320-73327-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-32-(N-ethyl perfluoro-1-0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 7 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsoctanesulfonamido)-ethanolSTW-LOC-TB-05042105/04/2021320-73327-3PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-05042105/04/2021320-73327-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-05042105/04/2021320-73327-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 8 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-TB-05042105/04/2021320-73327-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6A-05042105/04/2021320-73327-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 9 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-05042105/04/2021320-73327-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6A-05042105/04/2021320-73327-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6A-05042105/04/2021320-73327-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6A-05042105/04/2021320-73327-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 10 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-1-05042105/04/2021320-73327-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0062ug/L537 ModifiedJ3535_PFC0.0020PQLPage 11 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-05042105/04/2021320-73327-1R-PSDA0.034UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1Hydrolyzed PSDA0.015UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1R-EVE0.014UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6R-PSDA0.018UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Hydrolyzed PSDA0.15UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5R-PSDA0.015UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5Hydrolyzed PSDA0.13UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 12 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorobutaneSulfonic Acid0.0045UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluoroheptanoicAcid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorohexaneSulfonic Acid0.0064UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PFOA0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluoropentanoicAcid0.0081UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PerfluorohexanoicAcid0.0070UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1PFOS0.021UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorobutaneSulfonic Acid0.0036UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluoroheptanoicAcid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorohexaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PFOA0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-05042105/04/2021320-73327-1Hfpo Dimer Acid0.054UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluorohexanoicAcid0.0062UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PerfluoropentanoicAcid0.0075UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6PFOS0.013UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorobutaneSulfonic Acid0.0036UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluoroheptanoicAcid0.0038UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorohexaneSulfonic Acid0.0058UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-050421-D05/04/2021320-73327-6Hfpo Dimer Acid0.026UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PFOA0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluoropentanoicAcid0.0073UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PerfluorohexanoicAcid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-1-05042105/04/2021320-73327-5PFOS0.013UG/L537 ModifiedJ3535_PFC0.0020PQLPage 13 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 5/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-1-05042105/04/2021320-73327-5Hfpo Dimer Acid0.024UG/L537 ModifiedJ3535_PFC0.0040PQLPage 14 of 14DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review
Site: Chemours Fayetteville
Project: Stormwater Sampling 6/21
Project Reviewer: Bridget Gavaghan

DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Sample Summary

* FS=Field Sample
DUP=Field Duplicate
FB=Field Blank
EB=Equipment Blank
TB=Trip Blank

Field Sample ID Lab Sample ID Sample Matrix Filtered Sample Date Sample Time Sample Purpose
STW-LOC-18-4-061821 320-75235-1 Surface Water N 06/18/2021 13:36 FS
STW-LOC-20-4-061821 320-75235-2 Surface Water N 06/18/2021 13:40 FS
STW-LOC-22-4-061821 320-75235-3 Surface Water N 06/18/2021 14:05 FS
STW-LOC-23C-3-4-061821 320-75235-4 Surface Water N 06/18/2021 14:50 FS
STW-LOC-EB-DR-061821 320-75235-5 Blank Water N 06/18/2021 15:10 EB
STW-LOC-EB-IS-061821 320-75235-6 Blank Water N 06/18/2021 15:05 EB
STW-LOC-1-4-061821 320-75241-1 Surface Water N 06/18/2021 13:50 FS
STW-LOC-7A-4-061821 320-75241-2 Surface Water N 06/18/2021 13:40 FS
STW-LOC-7B-4-061821 320-75241-3 Surface Water N 06/18/2021 13:40 FS
STW-LOC-7C-4-061821 320-75241-4 Surface Water N 06/18/2021 15:35 FS
STW-LOC-8-4-061821 320-75241-5 Surface Water N 06/18/2021 13:15 FS
STW-LOC-14-4-061821 320-75241-6 Surface Water N 06/18/2021 14:30 FS
STW-LOC-15-4-061821 320-75241-7 Surface Water N 06/18/2021 15:15 FS
STW-LOC-23C-2-4-061821 320-75242-1 Surface Water N 06/18/2021 15:00 FS
STW-LOC-23C-2-4-061821-D 320-75242-2 Surface Water N 06/18/2021 15:00 DUP
STW-LOC-24B-061821 320-75242-3 Surface Water N 06/18/2021 10:50 FS
STW-LOC-24B-061821-D 320-75242-4 Surface Water N 06/18/2021 10:50 DUP
STW-LOC-6A-061821 320-75245-1 Surface Water N 06/18/2021 15:10 FS
STW-LOC-19A-061821 320-75245-2 Surface Water N 06/18/2021 12:45 FS
STW-LOC-19B-061821 320-75245-3 Surface Water N 06/18/2021 12:48 FS
STW-LOC-21A-061821 320-75245-4 Surface Water N 06/18/2021 12:10 FS
STW-LOC-24A-061821 320-75245-5 Surface Water N 06/18/2021 13:55 FS
STW-LOC-24C-061821 320-75245-6 Surface Water N 06/18/2021 11:10 FS
STW-LOC-FB-061821 320-75245-7 Blank Water N 06/18/2021 15:00 FB
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Analytical Protocol

Lab Name Lab Method Parameter Category Sampling Program
Eurofins TestAmerica, Sacramento 537 Modified H.PFC_Trials Stormwater Sampling 6/21
Eurofins TestAmerica, Sacramento 537 Modified Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 6/21
Eurofins TestAmerica, Sacramento Cl. Spec. Table 3 Compound SOP Per- and Polyfluorinated Alkyl Substances
(PFAS)Stormwater Sampling 6/21
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

ADQM Data Review Checklist

Item Description Yes No*
Not
Applicable
(NA)*
DVM
Narrative
Report
Laboratory
Report
Exception
Report
(ER) #
A

Did samples meet laboratory acceptability
requirements upon receipt (i.e., intact, within
temperature, properly preserved, and no
headspace where applicable)?
X
B
Were samples received by the laboratory in
agreement with the associated chain of
custody?
X
C

Was the chain of custody properly
completed by the laboratory and/or field
team?
X
D Were samples prepped/analyzed by the
laboratory within method holding times? X X X
E
Were QA/QC criteria met by the laboratory
(method blanks, LCSs/LCSDs, MSs/MSDs,
PDSs, SDs, duplicates/replicates,
surrogates, total/dissolved
differences/RPDs, sample results within
calibration range)?
X X X
F
Were detections in field/equipment/trip
blanks at levels not requiring sample data
qualification?
X
G Were all data usable and not R qualified? X
ER# Description

Other QA/QC Items to Note:

* See DVM Narrative Report, Lab Report, and/or ER # for further details as indicated.

The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process. Overall, the data is acceptable for use without qualification, except as noted on the attached
DVM Narrative Report.

The lab reports due to a large page count are stored on a network shared drive and are available to be
posted on external shared drives, or on a flash drive.
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF

Data Verification Module (DVM)

The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™
database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike (MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample (LCS)/laboratory control sample duplicate (LCSD) recoveries and the
RPD between these spikes
• Surrogate spike recoveries for organic analyses
• Difference/RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference/percent difference between total and dissolved sample pairs

There are two qualifier fields in EIM:
Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This
qualifier may have many different meanings and can vary between labs and over time within the
same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.

Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the
usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory or field
blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the
DVM has not been run, the field will be blank.

If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

If the data has been validated by a third party, the field “Validated By” will be set to the validator (e.g.,
ESI for Environmental Standards, Inc.).
DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
DVM Narrative ReportThe preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-4-06182106/18/2021320-75241-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-1-4-06182106/18/2021320-75241-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-1-4-06182106/18/2021320-75241-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-1-4-06182106/18/2021320-75241-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 1 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-610:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-06182106/18/2021320-75241-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-66:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-14-4-06182106/18/2021320-75241-6N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 2 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-61H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-69Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-61H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-611Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-710:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 3 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-06182106/18/2021320-75241-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-76:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-06182106/18/2021320-75241-7N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-71H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-79Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-71H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 4 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-15-4-06182106/18/2021320-75241-711Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-06182106/18/2021320-75235-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-06182106/18/2021320-75235-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 5 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-18-4-06182106/18/2021320-75235-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-19A-06182106/18/2021320-75245-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2N-methylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 6 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacidSTW-LOC-19A-06182106/18/2021320-75245-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 7 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19A-06182106/18/2021320-75245-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19A-06182106/18/2021320-75245-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19B-06182106/18/2021320-75245-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19B-06182106/18/2021320-75245-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-19B-06182106/18/2021320-75245-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 8 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-06182106/18/2021320-75245-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 9 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-4-06182106/18/2021320-75235-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-20-4-06182106/18/2021320-75235-2N-ethylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 10 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacidSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-06182106/18/2021320-75245-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 11 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-21A-06182106/18/2021320-75245-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-06182106/18/2021320-75245-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-21A-06182106/18/2021320-75245-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 12 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-22-4-06182106/18/2021320-75235-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-06182106/18/2021320-75235-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 13 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-4-06182106/18/2021320-75242-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 14 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-4-06182106/18/2021320-75242-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorononanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorodecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluoroundecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorododecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1N-ethylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1N-methylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorotetradecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorotridecanoicAcid (TRIAL)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-110:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-18:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 15 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-4-06182106/18/2021320-75242-14:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1NEtPFOSAE (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1NMePFOSAE (trial)0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-16:2 FTS (trial)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1DONA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1F-53B Major (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1F-53B Minor (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1NEtPFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1NMePFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFDS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFDoS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFHpS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFHxDA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorononanesulfonic acid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorooctadecanoicacid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFPeS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorooctaneSulfonamide (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2N-methylperfluorooctane0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 16 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitssulfonamidoacetic acidSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 17 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 18 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-06182106/18/2021320-75245-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-06182106/18/2021320-75245-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLPage 19 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-06182106/18/2021320-75245-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24A-06182106/18/2021320-75245-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 20 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 21 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-06182106/18/2021320-75242-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorononanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorodecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoroundecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorododecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorooctaneSulfonamide (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3N-ethylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3N-methylperfluorooctanesulfonamidoacetic acid(TRIAL)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorotetradecanoicAcid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorotridecanoicAcid (TRIAL)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-310:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-38:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-34:2 FTS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 22 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-06182106/18/2021320-75242-3NEtPFOSAE (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3NMePFOSAE (trial)0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24B-06182106/18/2021320-75242-36:2 FTS (trial)0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3DONA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3F-53B Major (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3F-53B Minor (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3NEtPFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3NMePFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFDS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFDoS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFHpS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFHxDA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorononanesulfonic acid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorooctadecanoicacid (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFPeS (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-061821-D06/18/2021320-75242-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLPage 23 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-061821-D06/18/2021320-75242-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 24 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-061821-D06/18/2021320-75242-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-610:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-06182106/18/2021320-75245-6Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-24C-06182106/18/2021320-75245-6Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-66:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-06182106/18/2021320-75245-6N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-61H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 25 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-69Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-61H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-611Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-110:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6A-06182106/18/2021320-75245-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-6A-06182106/18/2021320-75245-1Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-16:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-6A-06182106/18/2021320-75245-1N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 26 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-19Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-111Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-210:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-22-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 27 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-21H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-29Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-21H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-211Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-310:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7A-4-06182106/18/2021320-75241-22-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-26:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 28 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-31H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-39Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-31H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-311Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 29 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-8-4-06182106/18/2021320-75241-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5N-methylperfluorooctanesulfonamidoacetic0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLPage 30 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsacidSTW-LOC-EB-DR-06182106/18/2021320-75235-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 31 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-DR-06182106/18/2021320-75235-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-DR-06182106/18/2021320-75235-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-610:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 32 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-IS-06182106/18/2021320-75235-66:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-61H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 33 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-EB-IS-06182106/18/2021320-75235-69Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-61H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-611Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-EB-IS-06182106/18/2021320-75235-6DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-710:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-06182106/18/2021320-75245-7Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-72-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-06182106/18/2021320-75245-72-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluoropentanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-76:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-06182106/18/2021320-75245-7N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorohexanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 34 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-FB-06182106/18/2021320-75245-7N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PFOA0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7Perfluorobutanoic Acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorobutaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluoroheptanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-71H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-79Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-71H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-711Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-FB-06182106/18/2021320-75245-7DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 35 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7B-4-06182106/18/2021320-75241-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-36:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorohexadecanoicAcid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 36 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7C-4-06182106/18/2021320-75241-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-06182106/18/2021320-75241-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-46:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLPage 37 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-8-4-06182106/18/2021320-75241-5PFOS0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5N-methylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-8-4-06182106/18/2021320-75241-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLSTW-LOC-8-4-06182106/18/2021320-75241-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-56:2 Fluorotelomersulfonate0.0050ug/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-8-4-06182106/18/2021320-75241-5N-ethylperfluorooctanesulfonamidoacetic acid0.0050UG/L537 ModifiedUJ3535_PFC0.0050PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorohexaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 38 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-06182106/18/2021320-75242-3Hydrolyzed PSDA0.0022UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Hydrolyzed PSDA0.0022UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Hydrolyzed PSDA0.0043UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Hydrolyzed PSDA0.0043UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 39 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluoroheptanoicAcid0.0076UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PMPA0.027UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Hfpo Dimer Acid0.082UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Hfpo Dimer Acid0.092UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoroheptanoicAcid0.0053UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoroheptanoicAcid0.0051UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PMPA0.039UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24B-06182106/18/2021320-75242-3PMPA0.039UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-24B-06182106/18/2021320-75242-3Hfpo Dimer Acid0.053UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PMPA0.033UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PMPA0.026UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PMPA0.021UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 40 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-06182106/18/2021320-75242-3Hfpo Dimer Acid (trial)0.053UG/L537 ModifiedJ3535_PFC0.0040PQLPage 41 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-6A-06182106/18/2021320-75245-1Hydrolyzed PSDA0.0067UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6R-PSDA0.015UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6Hydrolyzed PSDA0.013UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6R-EVE0.0022UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5R-PSDA0.0075UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5Hydrolyzed PSDA0.0022UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Hydrolyzed PSDA0.0098UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Hydrolyzed PSDA0.0046UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3R-PSDA0.016UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Hydrolyzed PSDA0.11UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3R-EVE0.018UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4R-PSDA0.0076UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Hydrolyzed PSDA0.0035UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2R-PSDA0.068UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Hydrolyzed PSDA0.16UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2R-EVE0.011UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 42 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
Uncertainty around the analysis of R-PSDA, Hydrolyzed PSDA and R-EVE; J-qualifier added to all detects in the data set, even if there was no matrixspike analyzed for that particular sample.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-19B-06182106/18/2021320-75245-3R-PSDA0.019UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3Hydrolyzed PSDA0.0054UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3R-EVE0.039UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Hydrolyzed PSDA0.0034UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 43 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-8-4-06182106/18/2021320-75241-5Perfluorobutanoic Acid0.0070UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorobutaneSulfonic Acid0.0031UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluoroheptanoicAcid0.0029UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PFOA0.0026UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PFOA0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluorohexanoicAcid0.0070UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5PerfluoropentanoicAcid0.021UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorohexaneSulfonic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4Perfluorobutanoic Acid0.0063UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorobutaneSulfonic Acid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluoroheptanoicAcid0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluorohexanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PerfluoropentanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-8-4-06182106/18/2021320-75241-5Hfpo Dimer Acid0.18UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4PFOS0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PFOA0.0091UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorohexaneSulfonic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Perfluorobutanoic Acid0.0058UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorobutaneSulfonic Acid0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluoroheptanoicAcid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluorohexanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3PerfluoropentanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7C-4-06182106/18/2021320-75241-4Hfpo Dimer Acid0.032UG/L537 ModifiedJ3535_PFC0.0040PQLPage 44 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-7B-4-06182106/18/2021320-75241-3PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PFOA0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorohexaneSulfonic Acid0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Perfluorobutanoic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorobutaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluoroheptanoicAcid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluorohexanoicAcid0.0098UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PerfluoropentanoicAcid0.0093UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7B-4-06182106/18/2021320-75241-3Hfpo Dimer Acid0.017UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2PFOS0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorononanoicAcid0.0041UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorohexaneSulfonic Acid0.0073UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1Perfluorobutanoic Acid0.010UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorobutaneSulfonic Acid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluoroheptanoicAcid0.0065UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-7A-4-06182106/18/2021320-75241-2Hfpo Dimer Acid0.011UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-6A-06182106/18/2021320-75245-1PFOA0.018UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorodecanoicAcid0.0037UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluorohexanoicAcid0.012UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PerfluoropentanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1PFOS0.062UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PFOA0.0076UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-6A-06182106/18/2021320-75245-1Hfpo Dimer Acid0.057UG/L537 ModifiedJ3535_PFC0.0040PQLPage 45 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorohexaneSulfonic Acid0.0043UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6Perfluorobutanoic Acid0.0060UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorobutaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluoroheptanoicAcid0.0044UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluorohexanoicAcid0.0099UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PerfluoropentanoicAcid0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6PFOS0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24C-06182106/18/2021320-75245-6Hfpo Dimer Acid0.11UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorohexaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4Perfluorobutanoic Acid0.0061UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorobutaneSulfonic Acid0.0049UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluoroheptanoicAcid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PFOA0.0089UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluorohexanoicAcid0.0095UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-061821-D06/18/2021320-75242-4PerfluoropentanoicAcid0.0092UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFOA0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorobutaneSulfonic Acid (trial)0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorohexaneSulfonic Acid (trial)0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorohexaneSulfonic Acid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorobutanoic Acid0.0056UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorobutaneSulfonic Acid0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoroheptanoicAcid0.0056UG/L537 ModifiedJ3535_PFC0.0020PQLPage 46 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-24B-06182106/18/2021320-75242-3PFOS (trial)0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFOA (trial)0.0093UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3Perfluorobutanoic Acid(trial)0.0056UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoropentanoicAcid (trial)0.0097UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorohexanoicAcid (trial)0.0095UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoroheptanoicAcid (trial)0.0058UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluorohexanoicAcid0.0096UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PerfluoropentanoicAcid0.0093UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24B-06182106/18/2021320-75242-3PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorohexaneSulfonic Acid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5Perfluorobutanoic Acid0.0081UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorobutaneSulfonic Acid0.0049UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluoroheptanoicAcid0.0059UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PFOA0.0089UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluoropentanoicAcid0.0099UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PerfluorohexanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorobutaneSulfonic Acid0.0024UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluoroheptanoicAcid0.0020UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-24A-06182106/18/2021320-75245-5Hfpo Dimer Acid0.022UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorohexaneSulfonic Acid0.0026UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PFOA0.0046UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluorohexanoicAcid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLPage 47 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PerfluoropentanoicAcid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4PFOS0.0063UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PFOA0.0089UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-3-4-06182106/18/2021320-75235-4Hfpo Dimer Acid0.013UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorohexaneSulfonic Acid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Perfluorobutanoic Acid0.0055UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorobutaneSulfonic Acid0.0049UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluoroheptanoicAcid0.0048UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluorohexanoicAcid0.0098UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PerfluoropentanoicAcid0.0094UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Hfpo Dimer Acid (trial)0.014UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-061821-D06/18/2021320-75242-2Hfpo Dimer Acid0.013UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorobutaneSulfonic Acid (trial)0.0045UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorohexaneSulfonic Acid (trial)0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorohexaneSulfonic Acid0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorobutanoic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorobutaneSulfonic Acid0.0049UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluoroheptanoicAcid0.0048UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFOA0.0083UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluoropentanoicAcid0.0088UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorohexanoicAcid0.0089UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFOS (trial)0.014UG/L537 ModifiedJ3535_PFC0.0020PQLPage 48 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFOA (trial)0.0080UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Perfluorobutanoic Acid(trial)0.0053UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluoropentanoicAcid (trial)0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluorohexanoicAcid (trial)0.0087UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PerfluoroheptanoicAcid (trial)0.0048UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PFOA0.0044UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-23C-2-4-06182106/18/2021320-75242-1Hfpo Dimer Acid0.014UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluoroheptanoicAcid0.0027UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluorohexanoicAcid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PerfluoropentanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PFOS0.0038UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorohexaneSulfonic Acid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Perfluorobutanoic Acid0.0064UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorobutaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluoroheptanoicAcid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PFOA0.0096UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluoropentanoicAcid0.0087UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4PerfluorohexanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3Hfpo Dimer Acid0.11UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-21A-06182106/18/2021320-75245-4PFOS0.018UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PFOA0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorohexaneSulfonic Acid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLPage 49 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-20-4-06182106/18/2021320-75235-2Perfluorobutanoic Acid0.0062UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorobutaneSulfonic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluoroheptanoicAcid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluorohexanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-21A-06182106/18/2021320-75245-4Hfpo Dimer Acid0.055UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PerfluoropentanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2PFOS0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorohexaneSulfonic Acid0.0023UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3Perfluorobutanoic Acid0.0057UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorobutaneSulfonic Acid0.0034UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluoroheptanoicAcid0.0037UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PFOA0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluoropentanoicAcid0.0081UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-20-4-06182106/18/2021320-75235-2Hfpo Dimer Acid0.074UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-19B-06182106/18/2021320-75245-3PerfluorohexanoicAcid0.0074UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3PFOS0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PFOA0.0029UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorohexanoicAcid0.0020UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19B-06182106/18/2021320-75245-3Hfpo Dimer Acid0.015UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluorohexadecanoicAcid0.0021ug/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-19A-06182106/18/2021320-75245-2PerfluoropentanoicAcid0.0023UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Perfluorobutanoic Acid0.0069UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluorohexanoicAcid0.0033UG/L537 ModifiedJ3535_PFC0.0020PQLPage 50 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-18-4-06182106/18/2021320-75235-1PerfluoropentanoicAcid0.0032UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1PFOS0.0028UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PFOA0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-18-4-06182106/18/2021320-75235-1Hfpo Dimer Acid0.012UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorohexaneSulfonic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Perfluorobutanoic Acid0.0054UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorobutaneSulfonic Acid0.0056UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluoroheptanoicAcid0.0055UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluorohexanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PerfluoropentanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7PFOS0.015UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PFOA0.0071UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-15-4-06182106/18/2021320-75241-7Hfpo Dimer Acid0.065UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorohexaneSulfonic Acid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Perfluorobutanoic Acid0.0063UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorobutaneSulfonic Acid0.0047UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluoroheptanoicAcid0.0037UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluorohexanoicAcid0.0078UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PerfluoropentanoicAcid0.0077UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6PFOS0.011UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PFOA0.0094UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-14-4-06182106/18/2021320-75241-6Hfpo Dimer Acid0.012UG/L537 ModifiedJ3535_PFC0.0040PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorohexaneSulfonic Acid0.0051UG/L537 ModifiedJ3535_PFC0.0020PQLPage 51 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The preparation hold time for this sample was exceeded by a factor of 2. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-1-4-06182106/18/2021320-75241-1Perfluorobutanoic Acid0.0052UG/L537 ModifiedJ3535_PFC0.0050PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorobutaneSulfonic Acid0.0050UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluoroheptanoicAcid0.0046UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluorohexanoicAcid0.0090UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PerfluoropentanoicAcid0.0086UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1PFOS0.010UG/L537 ModifiedJ3535_PFC0.0020PQLSTW-LOC-1-4-06182106/18/2021320-75241-1Hfpo Dimer Acid0.0094UG/L537 ModifiedJ3535_PFC0.0040PQLPage 52 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Stormwater Sampling 6/21AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsSTW-LOC-22-4-06182106/18/2021320-75235-3PFMOAA0.056ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLSTW-LOC-22-4-06182106/18/2021320-75235-3PMPA0.013UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.010PQLPage 53 of 53DocuSign Envelope ID: 9F06E5E5-B9D0-409B-8A8A-8D82E4596CEF