12033-08-060_N Tryon St Brownfields_Annual GW Sampling Report_202102110

Terracon Consultants, Inc. 2701 Westport Road Charlotte, NC 28208
P 704-509-1777 F 704-509-1888 terracon.com
February 10, 2021

Ms. Carolyn Minnich
NC Brownfields Program
P: 704-661-0330
E: [e-mail]

Re: Report of Groundwater Sampling Activities and Request to Terminate Monitoring
North Tryon Commercial Brownfields (NCBP #12033-08-060)
2100-2229 North Tryon Street
Charlotte, Mecklenburg County, North Carolina
Terracon Project No. 71177699

Dear Ms. Minnich:

Terracon Consultants, Inc. (Terracon) is pleased to submit this report of groundwater sampling
activities conducted on behalf of Summit Avenue Northend, LLC at the North Tryon Commercial
Brownfields Property located at 2100-2229 North Tryon Street in Charlotte, North Carolina.
Terracon conducted the investigation in general accordance with our Supplement to Agreement
for Services, dated December 7, 2020.

Site Background
The North Tryon Commercial Brownfields Property includes an approximate 0.23-acre partially
paved vacant lot, identified in Mecklenburg County tax records as Parcel No. 07909304
(Figure 1). According to previous assessment activities associated with the Brownfields
investigation, a gasoline station and dry-cleaning facility previously operated on the subject parcel
from the 1940s until the 1970s. Site assessment activities conducted at the property have
indicated the presence of volatile organic compounds (VOCs) in soils, soil gas and groundwater.
In accordance with Paragraph 13.d. of the Brownfields Agreement (BFA), the monitoring well
located on the site must be sampled annually for five consecutive years, at which time a request
to terminate sampling may be submitted to the North Carolina Department of Environmental
Quality (NCDEQ). Groundwater sampling activities have been conducted at the site since
December 10, 2013.

Annual Groundwater Sampling
Terracon mobilized to the site on January 27, 2021 to conduct annual groundwater sampling
activities. A groundwater sample was collected from monitoring well MW-1 using low flow
techniques via a peristaltic and clean, new polyethylene tubing. Prior to sample collection, field
parameter readings of pH, oxidation reduction potential (ORP), specific conductivity, dissolved
oxygen, and temperature were recorded on groundwater sampling notes included in
Appendix A. The sample was collected after field parameters stabilized within a ten percent
variation for three consecutive readings at five-minute intervals. The sample was placed in clean
glassware, labeled, packed in an ice-filled cooler and transported with chain-of-custody
documentation to Pace Analytical (Pace) in Huntersville, North Carolina for laboratory analysis.
Groundwater Sampling Event and Request to Terminate Monitoring
North Tryon Site ■ Charlotte, North Carolina
February 10, 2021 ■ Terracon Project No. 71177699

Responsive ■ Resourceful ■ Reliable 2

The sample was analyzed for volatile organic compounds (VOCs) by EPA Method 8260 and semi-
volatile organic compounds (SVOCs) by EPA Method 8270. Analytical results are provided in the
attached laboratory analytical report located in Appendix B and are presented in Table 1 and on
Figure 2. The results are also summarized below.

◼ Tetrachloroethene (PCE; 569 micrograms per liter [µg/L]) and trichloroethene
(TCE; 12.9 µg/L) were detected above their respective NCAC 15A 2L
groundwater standards of 0.7 µg/L and 3 µg/L.
◼ cis-1,2-Dichloroethene (cis-1,2-DCE) was detected in at a concentration of 15.9
µg/L, below its NCAC 15A 2L groundwater standard.
◼ SVOCs were not detected above the laboratory reporting limits.
◼ Tetrachloroethene and trichloroethene also exceed their respective NCDEQ
residential and non-residential Groundwater Screening Levels (GWSLs).

Liquid wastes from the purging of the well were containerized and Terracon is currently
coordinating off-site disposal by Haz-Mat Environmental Services, LLC. A copy of the waste
manifest will be provided under separate cover.

Request to Terminate Requirement for Continued Annual Sampling
Eight groundwater sampling events have been conducted at the site since 2013. Between the
first and last sampling events, the concentrations of constituents of concern have decreased
significantly:

◼ cis-1,2-DCE: 141 µg/L to 15.9 µg/L;
◼ PCE: 2,280 µg/L to 569 µg/L; and
◼ TCE: 87.3 µg/L to 12.9 µg/L/.

The concentrations detected during this most recent January 2021 sampling event represent the
lowest levels of each of these compounds identified at the site since annual sampling began.
Terracon analyzed the historical trends of these constituents using the GSI Mann-Kendall
statistical toolkit for constituent trend analysis. According to the Mann-Kendall statistical analysis,
the concentrations of cis-1,2-DCE (100% confidence) and TCE (98.5% confidence) are
decreasing, while the concentrations of PCE are considered stable (71.9% confidence). The
results of the Mann-Kendall statistical analyses are provided in Figures 3, 4 and 5.

The purpose of the annual sampling has been to evaluate public health risk and determine the
potential need for additional actions beyond annual monitoring (e.g. mitigation). Following is the
public health rationale for terminating the ongoing groundwater monitoring:

• According to the Mecklenburg County Well Information System, there are no water
supply wells within 1,500 feet of the site. No surface water bodies are located within 500
Groundwater Sampling Event and Request to Terminate Monitoring
North Tryon Site ■ Charlotte, North Carolina
February 10, 2021 ■ Terracon Project No. 71177699

Responsive ■ Resourceful ■ Reliable 3

feet of the site. Land use at the site and down-gradient properties has remained
commercial/light-industrial since sampling began.
• Based on historical concentrations, the public health risk from the identified
concentrations is currently at its lowest level since 2013.
• Given the apparent downward concentration trends documented over the past eight
years and the GSI Mann-Kendall analyses, it appears highly unlikely that concentrations
of the constituents of concern will increase significantly in the future.
• After eight years of groundwater monitoring, NCDEQ has not required any action
in response to the identified concentrations of VOCs in groundwater. Thus, the
public health rationale for terminating sampling is that the sampling results over eight
years have not indicated a public health concern that required mitigation, and the
statistical analyses indicate the concentrations in groundwater are unlikely to materially
increase. Additional annual groundwater sampling would not generate data that would
be expected to impact future risk evaluations and management decisions. As such,
additional annual sampling events to continue to document groundwater concentrations
are not necessary moving forward unless redevelopment of the site is proposed that
would result in new potential receptors.

Based on the above, Summit Avenue Northend, LLC respectfully requests that the requirement
for further annual sampling of well MW-1 at the site be terminated. If you have any questions or
require additional information, please do not hesitate to contact us at 704-509-1777

Sincerely,
Terracon Consultants, Inc.

William O. Frazier, P.G. Christopher L. Corbitt, P.G.
Project Geologist Senior Geologist

Attachments Figure 1 – Site Location Map
Figure 2 – Groundwater Analytical Results (January 2021)
Figure 3 – cis-1,2-DCE Concentration vs. Time Trend Analysis
Figure 4 – PCE Concentration vs. Time Trend Analysis
Figure 5 – TCE Concentration vs. Time Trend Analysis
Table 1 – Groundwater Analytical Results
Appendix A – Groundwater Sample Collection Field Records
Appendix B – Laboratory Analytical Results – Pace Analytical
Figures

Site Location Map
North Tryon Site
2229 North Tryon Street
Charlotte, Mecklenburg County, NC
TOPOGRAPHIC MAP IMAGE COURTESY OF THE U.S. GEOLOGICAL SURVEY
QUADRANGLES INCLUDE: DERITA, NC (1/1/1993) and CHARLOTTE EAST, NC (1/1/1988).
2701 Westport Road
Charlotte, NC 28208
71177699
Project Manager:
Drawn by:
Checked by:
Approved by:
WOF
CLC
CLC
1”=2,000’
71177699
January 2021
Project No.
Scale:
File Name:
Date: 1
WOF Figure
APPROXIMATE
SITE BOUNDARY
71177699.2
Groundwater Analytical Results (January 2021)
North Tryon Site
2229 North Tryon Street
Charlotte, Mecklenburg County, NC
2701 Westport Road
Charlotte, NC
711777699
WOF
CLC
CLC
N.T.S.
January 2021
Scale:
2
FigureProject Manager:
Drawn by:
Checked by:
Approved by:
Project No.
File Name:
Date:
WOF
denotes approximate site boundary
approximate location of groundwater
monitoring well
GRAVEL
MW-1
Sample ID: MW-1
Groundwater Sample
8260 –cis-1,2-Dichloroethene: 15.9 µg/L
Tetrachloroethene: 569 µg/L
Trichloroethene: 12.9 µg/L
*Values above 2L Standards and non-
residential GWSL are in bold.
Figure 3
cis-1,2-DCE Concentration vs. Time Trend Analysis
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:µg/L
Sampling Point ID:MW-1
Sampling Sampling
Event Date
1 12/10/2013 141
2 12/18/14 82.1
3 07/11/16 52
4 12/14/16 34.5
5 01/05/18 33.3
6 01/23/19 30.5
7 01/27/20 27.4
8 01/27/21 15.9
9
10
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.55
Mann-Kendall Statistic (S):-21
Confidence Factor:100.0%
Concentration Trend:Decreasing
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
4..-- Indicates date not sampled/well non-existent.
5.The laboratory reporting limit was entered when the laboratory did not detect concentrations above the reporting limit.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
CIS-1,2-DCE CONCENTRATION (µg/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
02/09/21 71177699
North Tryon Site (BF ID: 12033-08-060)cis-1,2-DCE
Terracon
1
10
100
1000
04/12 08/13 12/14 05/16 09/17 02/19 06/20 10/21Concentration (µg/L)Sampling Date
MW-1
MW-1
Figure 4
PCE Concentration vs. Time Trend Analysis
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:µg/L
Sampling Point ID:MW-1
Sampling Sampling
Event Date
1 12/10/2013 2280
2 12/18/14 1,190
3 07/11/16 1,500
4 12/14/16 570
5 01/05/18 596
6 01/23/19 766
7 01/27/20 1,380
8 01/27/21 569
9
10
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.43
Mann-Kendall Statistic (S):-5
Confidence Factor:71.9%
Concentration Trend:Stable
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
4..-- Indicates date not sampled/well non-existent.
5.The laboratory reporting limit was entered when the laboratory did not detect concentrations above the reporting limit.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
PCE CONCENTRATION (µg/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
02/09/21 71177699
North Tryon Site (BF ID: 12033-08-060)PCE
Terracon
1
10
100
1000
10000
04/12 08/13 12/14 05/16 09/17 02/19 06/20 10/21Concentration (µg/L)Sampling Date
MW-1
MW-1
Figure 5
TCE Concentration vs. Time Trend Analysis
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:µg/L
Sampling Point ID:MW-1
Sampling Sampling
Event Date
1 12/10/2013 87.3
2 12/18/14 48.2
3 07/11/16 37
4 12/14/16 20.1
5 01/05/18 17.8
6 01/23/19 16.7
7 01/27/20 22.3
8 01/27/21 12.9
9
10
11
12
13
14
15
16
17
18
19
20
Coefficient of Variation:0.51
Mann-Kendall Statistic (S):-15
Confidence Factor:98.5%
Concentration Trend:Decreasing
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
4..-- Indicates date not sampled/well non-existent.
5.The laboratory reporting limit was entered when the laboratory did not detect concentrations above the reporting limit.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
TCE CONCENTRATION (µg/L)
GSI Environmental Inc., www.gsi-net.com
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
02/09/21 71177699
North Tryon Site (BF ID: 12033-08-060)TCE
Terracon
1
10
100
04/12 08/13 12/14 05/16 09/17 02/19 06/20 10/21Concentration (µg/L)Sampling Date
MW-1
MW-1
Table
Table 1
Groundwater Analytical Results
North Tryon Site
Brownfields ID: 12033-08-060
2229 North Tryon Street
Charlotte, Mecklenburg County, North Carolina
Terracon Project No. 71177699
Sample ID:
Screen Interval
(ft bgs):
Sample Date: 12/10/2013*12/18/2014*7/11/2016*01/23/2019 1/27/2021
Chloroform 70 8.1 36 ND <1 <5 <11.7 <9.4
cis-1,2-Dichloroethene 70 NS NS 141 82.1 52 30.5 15.9
trans-1,2-Dichloroethene 100 NS NS <1.0 <1.0 20 <5 <1.0
Tetrachloroethene 0.7 12 48 2,280 1,190 1,500 766 569
Toluene 600 3,800 16,000 ND <1 <5 2.9J <0.98
Trichloroethene 3 1 4.4 87.3 48.2 37 16.7 12.9
Notes:
Only detected compounds are shown.
Concentrations are reported in micrograms per liter (μg/L).
* = Labortory data obtained from Hart & Hickman Groundwater Monitoring Reports
2L Standard - North Carolina Administrative Code Subchapter 2L Groundwater Quality Standards (April 1, 2013).
Concentrations highlighted in gray exceed their respective 2L Standard
Concentrations highlighted in orange exceed their respective Non-Residential GWSL.
ND - Not Detected
NS - No Standard
GWSL - NCDEQ Division of Waste Management Vapor Intrusion Groundwater Screening Levels - Health-Based Ground Water Screening Levels, updated February 2018
<1<5
<1.0
Semi-Volatile Organic Compounds (EPA Method 8270)
Volatile Organic Compounds (EPA Method 8260)
33.3
596
17.8
<5 <1.3
<5
1,380
22.3
<2.3
27.4
No contaminants detected above the laboratory reporting limit or NCAC 2L GWQS
Analyte 2L Standard
01/05/2018
Residential
GWSL
Non-Residential
GWSL
12/14/2016
<5
34.5
570
20.1
0.77J
MW-1
25-30
01/27/2020
Appendix A
Appendix B
#=CL#
February 03, 2021
LIMS USE: FR - MCKHENZY WELCH
LIMS OBJECT ID: 92518792
92518792
Project:
Pace Project No.:
RE:
McKhenzy Welch
Terracon
2701 Westport Rd
Charlotte, NC 28208
N. TRYON BROWNFIELDS
Dear McKhenzy Welch:
Enclosed are the analytical results for sample(s) received by the laboratory on January 27, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
1(704)875-9092
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Lab ID Sample ID Matrix Date Collected Date Received
92518792001 MW-1 Water 01/27/21 12:15 01/27/21 13:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92518792001 MW-1 EPA 8270E 74 PASI-CPKS
EPA 8260D 63 PASI-CCL
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92518792001 MW-1
cis-1,2-Dichloroethene 15.9 ug/L 02/03/21 13:314.0EPA 8260D
Tetrachloroethene 569 ug/L 02/03/21 13:314.0EPA 8260D
Trichloroethene 12.9 ug/L 02/03/21 13:314.0EPA 8260D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 27
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Method:
Client:Terracon - Charlotte, NC
EPA 8270E
Date:February 03, 2021
Description:8270E RVE
General Information:
1 sample was analyzed for EPA 8270E by Pace Analytical Services Charlotte. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end ofthis report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3510C with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 595908
v1: The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated
samples may have a high bias.
• BLANK (Lab ID: 3142861)
• 2,2'-Oxybis(1-chloropropane)
• LCS (Lab ID: 3142862)
• 2,2'-Oxybis(1-chloropropane)
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 595908
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92510849021
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3142863)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Method:
Client:Terracon - Charlotte, NC
EPA 8270E
Date:February 03, 2021
Description:8270E RVE
QC Batch: 595908
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92510849021
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Benzoic Acid
• Hexachlorocyclopentadiene
• MSD (Lab ID: 3142864)
• Benzoic Acid
R1: RPD value was outside control limits.
• MSD (Lab ID: 3142864)
• 4,6-Dinitro-2-methylphenol
• 4-Nitrophenol
• Pentachlorophenol
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Method:
Client:Terracon - Charlotte, NC
EPA 8260D
Date:February 03, 2021
Description:8260D MSV Low Level
General Information:
1 sample was analyzed for EPA 8260D by Pace Analytical Services Charlotte. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end ofthis report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 596980
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92518792001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3148036)
• Chloroethane
• Chloromethane
• Dichlorodifluoromethane
• Trichlorofluoromethane
• Vinyl chloride
• MSD (Lab ID: 3148037)
• Chloroethane
• Chloromethane
• Dichlorodifluoromethane
• Trichlorofluoromethane
• Vinyl chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 27
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Method:
Client:Terracon - Charlotte, NC
EPA 8260D
Date:February 03, 2021
Description:8260D MSV Low Level
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Sample:MW-1 Lab ID:92518792001 Collected:01/27/21 12:15 Received:01/27/21 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Acenaphthene ND ug/L 01/28/21 16:33 83-32-901/28/21 09:0210.0 2.0 1
Acenaphthylene ND ug/L 01/28/21 16:33 208-96-801/28/21 09:0210.0 2.0 1
Aniline ND ug/L 01/28/21 16:33 62-53-301/28/21 09:0210.0 1.6 1
Anthracene ND ug/L 01/28/21 16:33 120-12-701/28/21 09:0210.0 2.3 1
Benzo(a)anthracene ND ug/L 01/28/21 16:33 56-55-301/28/21 09:0210.0 2.7 1
Benzo(a)pyrene ND ug/L 01/28/21 16:33 50-32-801/28/21 09:0210.0 2.8 1
Benzo(b)fluoranthene ND ug/L 01/28/21 16:33 205-99-201/28/21 09:0210.0 2.6 1
Benzo(g,h,i)perylene ND ug/L 01/28/21 16:33 191-24-201/28/21 09:0210.0 2.8 1
Benzo(k)fluoranthene ND ug/L 01/28/21 16:33 207-08-901/28/21 09:0210.0 2.7 1
Benzoic Acid ND ug/L 01/28/21 16:33 65-85-001/28/21 09:0250.0 3.4 1
Benzyl alcohol ND ug/L 01/28/21 16:33 100-51-601/28/21 09:0220.0 2.9 1
4-Bromophenylphenyl ether ND ug/L 01/28/21 16:33 101-55-301/28/21 09:0210.0 1.8 1
Butylbenzylphthalate ND ug/L 01/28/21 16:33 85-68-701/28/21 09:0210.0 3.1 1
4-Chloro-3-methylphenol ND ug/L 01/28/21 16:33 59-50-701/28/21 09:0210.0 3.3 1
4-Chloroaniline ND ug/L 01/28/21 16:33 106-47-801/28/21 09:0220.0 3.6 1
bis(2-Chloroethoxy)methane ND ug/L 01/28/21 16:33 111-91-101/28/21 09:0210.0 1.8 1
bis(2-Chloroethyl) ether ND ug/L 01/28/21 16:33 111-44-401/28/21 09:0210.0 1.9 1
2-Chloronaphthalene ND ug/L 01/28/21 16:33 91-58-701/28/21 09:0210.0 1.7 1
2-Chlorophenol ND ug/L 01/28/21 16:33 95-57-801/28/21 09:0210.0 1.2 1
4-Chlorophenylphenyl ether ND ug/L 01/28/21 16:33 7005-72-301/28/21 09:0210.0 2.0 1
Chrysene ND ug/L 01/28/21 16:33 218-01-901/28/21 09:0210.0 2.8 1
Dibenz(a,h)anthracene ND ug/L 01/28/21 16:33 53-70-301/28/21 09:0210.0 3.0 1
Dibenzofuran ND ug/L 01/28/21 16:33 132-64-901/28/21 09:0210.0 2.1 1
1,2-Dichlorobenzene ND ug/L 01/28/21 16:33 95-50-101/28/21 09:0210.0 1.8 1
1,3-Dichlorobenzene ND ug/L 01/28/21 16:33 541-73-101/28/21 09:0210.0 1.6 1
1,4-Dichlorobenzene ND ug/L 01/28/21 16:33 106-46-701/28/21 09:0210.0 1.7 1
3,3'-Dichlorobenzidine ND ug/L 01/28/21 16:33 91-94-101/28/21 09:0220.0 8.1 1
2,4-Dichlorophenol ND ug/L 01/28/21 16:33 120-83-201/28/21 09:0210.0 1.4 1
Diethylphthalate ND ug/L 01/28/21 16:33 84-66-201/28/21 09:0210.0 2.0 1
2,4-Dimethylphenol ND ug/L 01/28/21 16:33 105-67-901/28/21 09:0210.0 1.7 1
Dimethylphthalate ND ug/L 01/28/21 16:33 131-11-301/28/21 09:0210.0 2.1 1
Di-n-butylphthalate ND ug/L 01/28/21 16:33 84-74-201/28/21 09:0210.0 2.2 1
4,6-Dinitro-2-methylphenol ND ug/L 01/28/21 16:33 534-52-101/28/21 09:0220.0 3.4 1
2,4-Dinitrophenol ND ug/L 01/28/21 16:33 51-28-501/28/21 09:0250.0 26.0 1
2,4-Dinitrotoluene ND ug/L 01/28/21 16:33 121-14-201/28/21 09:0210.0 1.6 1
2,6-Dinitrotoluene ND ug/L 01/28/21 16:33 606-20-201/28/21 09:0210.0 1.7 1
Di-n-octylphthalate ND ug/L 01/28/21 16:33 117-84-001/28/21 09:0210.0 3.9 1
bis(2-Ethylhexyl)phthalate ND ug/L 01/28/21 16:33 117-81-701/28/21 09:026.0 3.7 1
Fluoranthene ND ug/L 01/28/21 16:33 206-44-001/28/21 09:0210.0 2.2 1
Fluorene ND ug/L 01/28/21 16:33 86-73-701/28/21 09:0210.0 2.1 1
Hexachloro-1,3-butadiene ND ug/L 01/28/21 16:33 87-68-301/28/21 09:0210.0 1.8 1
Hexachlorobenzene ND ug/L 01/28/21 16:33 118-74-101/28/21 09:0210.0 2.2 1
Hexachlorocyclopentadiene ND ug/L 01/28/21 16:33 77-47-401/28/21 09:0210.0 1.6 1
Hexachloroethane ND ug/L 01/28/21 16:33 67-72-101/28/21 09:0210.0 1.4 1
Indeno(1,2,3-cd)pyrene ND ug/L 01/28/21 16:33 193-39-501/28/21 09:0210.0 2.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
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[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Sample:MW-1 Lab ID:92518792001 Collected:01/27/21 12:15 Received:01/27/21 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
8270E RVE
Isophorone ND ug/L 01/28/21 16:33 78-59-101/28/21 09:0210.0 1.7 1
1-Methylnaphthalene ND ug/L 01/28/21 16:33 90-12-001/28/21 09:0210.0 2.0 1
2-Methylnaphthalene ND ug/L 01/28/21 16:33 91-57-601/28/21 09:0210.0 1.9 1
2-Methylphenol(o-Cresol)ND ug/L 01/28/21 16:33 95-48-701/28/21 09:0210.0 1.9 1
3&4-Methylphenol(m&p Cresol)ND ug/L 01/28/21 16:33 15831-10-401/28/21 09:0210.0 1.2 1
Naphthalene ND ug/L 01/28/21 16:33 91-20-301/28/21 09:0210.0 2.1 1
2-Nitroaniline ND ug/L 01/28/21 16:33 88-74-401/28/21 09:0220.0 3.0 1
3-Nitroaniline ND ug/L 01/28/21 16:33 99-09-201/28/21 09:0220.0 3.8 1
4-Nitroaniline ND ug/L 01/28/21 16:33 100-01-601/28/21 09:0220.0 5.1 1
Nitrobenzene ND ug/L 01/28/21 16:33 98-95-301/28/21 09:0210.0 1.9 1
2-Nitrophenol ND ug/L 01/28/21 16:33 88-75-501/28/21 09:0210.0 1.4 1
4-Nitrophenol ND ug/L 01/28/21 16:33 100-02-701/28/21 09:0250.0 6.6 1
N-Nitrosodimethylamine ND ug/L 01/28/21 16:33 62-75-901/28/21 09:0210.0 1.9 1
N-Nitroso-di-n-propylamine ND ug/L 01/28/21 16:33 621-64-701/28/21 09:0210.0 1.3 1
N-Nitrosodiphenylamine ND ug/L 01/28/21 16:33 86-30-601/28/21 09:0210.0 3.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 01/28/21 16:33 108-60-101/28/21 09:0210.0 1.2 1
Pentachlorophenol ND ug/L 01/28/21 16:33 87-86-501/28/21 09:0220.0 3.8 1
Phenanthrene ND ug/L 01/28/21 16:33 85-01-801/28/21 09:0210.0 2.0 1
Phenol ND ug/L 01/28/21 16:33 108-95-201/28/21 09:0210.0 1.4 1
Pyrene ND ug/L 01/28/21 16:33 129-00-001/28/21 09:0210.0 2.2 1
1,2,4-Trichlorobenzene ND ug/L 01/28/21 16:33 120-82-101/28/21 09:0210.0 1.7 1
2,4,5-Trichlorophenol ND ug/L 01/28/21 16:33 95-95-401/28/21 09:0210.0 1.4 1
2,4,6-Trichlorophenol ND ug/L 01/28/21 16:33 88-06-201/28/21 09:0210.0 1.6 1
Surrogates
Nitrobenzene-d5 (S)55 %01/28/21 16:33 4165-60-001/28/21 09:0210-144 1
2-Fluorobiphenyl (S)36 %01/28/21 16:33 321-60-801/28/21 09:0210-130 1
Terphenyl-d14 (S)115 %01/28/21 16:33 1718-51-001/28/21 09:0234-163 1
Phenol-d6 (S)23 %01/28/21 16:33 13127-88-301/28/21 09:0210-130 1
2-Fluorophenol (S)36 %01/28/21 16:33 367-12-401/28/21 09:0210-130 1
2,4,6-Tribromophenol (S)61 %01/28/21 16:33 118-79-601/28/21 09:0210-144 1
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Acetone ND ug/L 02/03/21 13:31 67-64-110024.7 4
Benzene ND ug/L 02/03/21 13:31 71-43-24.0 0.60 4
Bromobenzene ND ug/L 02/03/21 13:31 108-86-14.0 0.88 4
Bromochloromethane ND ug/L 02/03/21 13:31 74-97-54.0 1.4 4
Bromodichloromethane ND ug/L 02/03/21 13:31 75-27-44.0 1.0 4
Bromoform ND ug/L 02/03/21 13:31 75-25-24.0 2.5 4
Bromomethane ND ug/L 02/03/21 13:31 74-83-98.0 2.5 4
2-Butanone (MEK)ND ug/L 02/03/21 13:31 78-93-320.0 13.3 4
Carbon tetrachloride ND ug/L 02/03/21 13:31 56-23-54.0 0.90 4
Chlorobenzene ND ug/L 02/03/21 13:31 108-90-74.0 0.93 4
Chloroethane ND ug/L 02/03/21 13:31 75-00-3 M14.0 2.0 4
Chloroform ND ug/L 02/03/21 13:31 67-66-320.0 9.4 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Sample:MW-1 Lab ID:92518792001 Collected:01/27/21 12:15 Received:01/27/21 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Chloromethane ND ug/L 02/03/21 13:31 74-87-3 M14.0 1.6 4
2-Chlorotoluene ND ug/L 02/03/21 13:31 95-49-84.0 0.81 4
4-Chlorotoluene ND ug/L 02/03/21 13:31 106-43-44.0 0.82 4
1,2-Dibromo-3-chloropropane ND ug/L 02/03/21 13:31 96-12-820.0 1.0 4
Dibromochloromethane ND ug/L 02/03/21 13:31 124-48-14.0 1.7 4
1,2-Dibromoethane (EDB)ND ug/L 02/03/21 13:31 106-93-44.0 1.0 4
Dibromomethane ND ug/L 02/03/21 13:31 74-95-34.0 1.8 4
1,2-Dichlorobenzene ND ug/L 02/03/21 13:31 95-50-14.0 1.2 4
1,3-Dichlorobenzene ND ug/L 02/03/21 13:31 541-73-14.0 0.87 4
1,4-Dichlorobenzene ND ug/L 02/03/21 13:31 106-46-74.0 1.0 4
Dichlorodifluoromethane ND ug/L 02/03/21 13:31 75-71-8 M14.0 0.90 4
1,1-Dichloroethane ND ug/L 02/03/21 13:31 75-34-34.0 1.1 4
1,2-Dichloroethane ND ug/L 02/03/21 13:31 107-06-24.0 1.3 4
1,1-Dichloroethene ND ug/L 02/03/21 13:31 75-35-44.0 0.98 4
cis-1,2-Dichloroethene 15.9 ug/L 02/03/21 13:31 156-59-24.0 1.2 4
trans-1,2-Dichloroethene ND ug/L 02/03/21 13:31 156-60-54.0 1.0 4
1,2-Dichloropropane ND ug/L 02/03/21 13:31 78-87-54.0 0.75 4
1,3-Dichloropropane ND ug/L 02/03/21 13:31 142-28-94.0 0.63 4
2,2-Dichloropropane ND ug/L 02/03/21 13:31 594-20-74.0 1.1 4
1,1-Dichloropropene ND ug/L 02/03/21 13:31 563-58-64.0 0.85 4
cis-1,3-Dichloropropene ND ug/L 02/03/21 13:31 10061-01-54.0 1.2 4
trans-1,3-Dichloropropene ND ug/L 02/03/21 13:31 10061-02-64.0 1.2 4
Diisopropyl ether ND ug/L 02/03/21 13:31 108-20-34.0 0.87 4
Ethylbenzene ND ug/L 02/03/21 13:31 100-41-44.0 1.0 4
Hexachloro-1,3-butadiene ND ug/L 02/03/21 13:31 87-68-34.0 1.8 4
2-Hexanone ND ug/L 02/03/21 13:31 591-78-620.0 2.3 4
p-Isopropyltoluene ND ug/L 02/03/21 13:31 99-87-64.0 0.85 4
Methylene Chloride ND ug/L 02/03/21 13:31 75-09-220.0 14.8 4
4-Methyl-2-pentanone (MIBK)ND ug/L 02/03/21 13:31 108-10-120.0 18.1 4
Methyl-tert-butyl ether ND ug/L 02/03/21 13:31 1634-04-44.0 1.1 4
Naphthalene ND ug/L 02/03/21 13:31 91-20-34.0 1.4 4
Styrene ND ug/L 02/03/21 13:31 100-42-54.0 1.1 4
1,1,1,2-Tetrachloroethane ND ug/L 02/03/21 13:31 630-20-64.0 1.4 4
1,1,2,2-Tetrachloroethane ND ug/L 02/03/21 13:31 79-34-54.0 0.89 4
Tetrachloroethene 569 ug/L 02/03/21 13:31 127-18-44.0 0.65 4
Toluene ND ug/L 02/03/21 13:31 108-88-34.0 0.98 4
1,2,3-Trichlorobenzene ND ug/L 02/03/21 13:31 87-61-64.0 1.4 4
1,2,4-Trichlorobenzene ND ug/L 02/03/21 13:31 120-82-14.0 0.87 4
1,1,1-Trichloroethane ND ug/L 02/03/21 13:31 71-55-64.0 0.70 4
1,1,2-Trichloroethane ND ug/L 02/03/21 13:31 79-00-54.0 0.94 4
Trichloroethene 12.9 ug/L 02/03/21 13:31 79-01-64.0 0.88 4
Trichlorofluoromethane ND ug/L 02/03/21 13:31 75-69-4 M14.0 1.2 4
1,2,3-Trichloropropane ND ug/L 02/03/21 13:31 96-18-44.0 1.4 4
Vinyl acetate ND ug/L 02/03/21 13:31 108-05-48.0 5.8 4
Vinyl chloride ND ug/L 02/03/21 13:31 75-01-4 M14.0 0.97 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Sample:MW-1 Lab ID:92518792001 Collected:01/27/21 12:15 Received:01/27/21 13:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
8260D MSV Low Level
Xylene (Total)ND ug/L 02/03/21 13:31 1330-20-74.0 2.5 4
m&p-Xylene ND ug/L 02/03/21 13:31 179601-23-18.0 1.6 4
o-Xylene ND ug/L 02/03/21 13:31 95-47-64.0 0.88 4
Surrogates
4-Bromofluorobenzene (S)100 %02/03/21 13:31 460-00-470-130 4
1,2-Dichloroethane-d4 (S)94 %02/03/21 13:31 17060-07-070-130 4
Toluene-d8 (S)101 %02/03/21 13:31 2037-26-570-130 4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
596980
EPA 8260D
EPA 8260D
8260D MSV Low Level
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92518792001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3148034
Associated Lab Samples:92518792001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 1.0 02/03/21 11:400.34
1,1,1-Trichloroethane ug/L ND 1.0 02/03/21 11:400.18
1,1,2,2-Tetrachloroethane ug/L ND 1.0 02/03/21 11:400.22
1,1,2-Trichloroethane ug/L ND 1.0 02/03/21 11:400.24
1,1-Dichloroethane ug/L ND 1.0 02/03/21 11:400.27
1,1-Dichloroethene ug/L ND 1.0 02/03/21 11:400.24
1,1-Dichloropropene ug/L ND 1.0 02/03/21 11:400.21
1,2,3-Trichlorobenzene ug/L ND 1.0 02/03/21 11:400.34
1,2,3-Trichloropropane ug/L ND 1.0 02/03/21 11:400.35
1,2,4-Trichlorobenzene ug/L ND 1.0 02/03/21 11:400.22
1,2-Dibromo-3-chloropropane ug/L ND 5.0 02/03/21 11:400.26
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/03/21 11:400.26
1,2-Dichlorobenzene ug/L ND 1.0 02/03/21 11:400.29
1,2-Dichloroethane ug/L ND 1.0 02/03/21 11:400.34
1,2-Dichloropropane ug/L ND 1.0 02/03/21 11:400.19
1,3-Dichlorobenzene ug/L ND 1.0 02/03/21 11:400.22
1,3-Dichloropropane ug/L ND 1.0 02/03/21 11:400.16
1,4-Dichlorobenzene ug/L ND 1.0 02/03/21 11:400.26
2,2-Dichloropropane ug/L ND 1.0 02/03/21 11:400.27
2-Butanone (MEK)ug/L ND 5.0 02/03/21 11:403.3
2-Chlorotoluene ug/L ND 1.0 02/03/21 11:400.20
2-Hexanone ug/L ND 5.0 02/03/21 11:400.57
4-Chlorotoluene ug/L ND 1.0 02/03/21 11:400.20
4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 02/03/21 11:404.5
Acetone ug/L ND 25.0 02/03/21 11:406.2
Benzene ug/L ND 1.0 02/03/21 11:400.15
Bromobenzene ug/L ND 1.0 02/03/21 11:400.22
Bromochloromethane ug/L ND 1.0 02/03/21 11:400.34
Bromodichloromethane ug/L ND 1.0 02/03/21 11:400.26
Bromoform ug/L ND 1.0 02/03/21 11:400.62
Bromomethane ug/L ND 2.0 02/03/21 11:400.62
Carbon tetrachloride ug/L ND 1.0 02/03/21 11:400.22
Chlorobenzene ug/L ND 1.0 02/03/21 11:400.23
Chloroethane ug/L ND 1.0 02/03/21 11:400.49
Chloroform ug/L ND 5.0 02/03/21 11:402.3
Chloromethane ug/L ND 1.0 02/03/21 11:400.39
cis-1,2-Dichloroethene ug/L ND 1.0 02/03/21 11:400.29
cis-1,3-Dichloropropene ug/L ND 1.0 02/03/21 11:400.30
Dibromochloromethane ug/L ND 1.0 02/03/21 11:400.41
Dibromomethane ug/L ND 1.0 02/03/21 11:400.46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3148034
Associated Lab Samples:92518792001
Matrix:Water
AnalyzedMDL
Dichlorodifluoromethane ug/L ND 1.0 02/03/21 11:400.23
Diisopropyl ether ug/L ND 1.0 02/03/21 11:400.22
Ethylbenzene ug/L ND 1.0 02/03/21 11:400.26
Hexachloro-1,3-butadiene ug/L ND 1.0 02/03/21 11:400.44
m&p-Xylene ug/L ND 2.0 02/03/21 11:400.41
Methyl-tert-butyl ether ug/L ND 1.0 02/03/21 11:400.28
Methylene Chloride ug/L ND 5.0 02/03/21 11:403.7
Naphthalene ug/L ND 1.0 02/03/21 11:400.35
o-Xylene ug/L ND 1.0 02/03/21 11:400.22
p-Isopropyltoluene ug/L ND 1.0 02/03/21 11:400.21
Styrene ug/L ND 1.0 02/03/21 11:400.27
Tetrachloroethene ug/L ND 1.0 02/03/21 11:400.16
Toluene ug/L ND 1.0 02/03/21 11:400.24
trans-1,2-Dichloroethene ug/L ND 1.0 02/03/21 11:400.25
trans-1,3-Dichloropropene ug/L ND 1.0 02/03/21 11:400.31
Trichloroethene ug/L ND 1.0 02/03/21 11:400.22
Trichlorofluoromethane ug/L ND 1.0 02/03/21 11:400.31
Vinyl acetate ug/L ND 2.0 02/03/21 11:401.4
Vinyl chloride ug/L ND 1.0 02/03/21 11:400.24
Xylene (Total)ug/L ND 1.0 02/03/21 11:400.63
1,2-Dichloroethane-d4 (S)%98 70-130 02/03/21 11:40
4-Bromofluorobenzene (S)%101 70-130 02/03/21 11:40
Toluene-d8 (S)%101 70-130 02/03/21 11:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3148035LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.850 98 70-130
1,1,1-Trichloroethane ug/L 45.750 91 70-130
1,1,2,2-Tetrachloroethane ug/L 50.450 101 70-130
1,1,2-Trichloroethane ug/L 49.350 99 70-130
1,1-Dichloroethane ug/L 49.350 99 70-130
1,1-Dichloroethene ug/L 51.050 102 70-132
1,1-Dichloropropene ug/L 47.750 95 70-131
1,2,3-Trichlorobenzene ug/L 47.850 96 70-134
1,2,3-Trichloropropane ug/L 50.950 102 70-130
1,2,4-Trichlorobenzene ug/L 49.350 99 70-130
1,2-Dibromo-3-chloropropane ug/L 50.550 101 70-132
1,2-Dibromoethane (EDB)ug/L 48.250 96 70-130
1,2-Dichlorobenzene ug/L 47.950 96 70-130
1,2-Dichloroethane ug/L 47.250 94 70-130
1,2-Dichloropropane ug/L 51.050 102 70-130
1,3-Dichlorobenzene ug/L 48.050 96 70-130
1,3-Dichloropropane ug/L 49.150 98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
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Huntersville, NC 28078
[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3148035LABORATORY CONTROL SAMPLE:
LCSSpike
1,4-Dichlorobenzene ug/L 47.750 95 70-130
2,2-Dichloropropane ug/L 47.250 94 70-130
2-Butanone (MEK)ug/L 99.6100 100 70-133
2-Chlorotoluene ug/L 47.850 96 70-130
2-Hexanone ug/L 105100 105 70-130
4-Chlorotoluene ug/L 47.150 94 70-130
4-Methyl-2-pentanone (MIBK)ug/L 106100 106 70-130
Acetone ug/L 101100 101 70-144
Benzene ug/L 47.850 96 70-130
Bromobenzene ug/L 47.450 95 70-130
Bromochloromethane ug/L 48.250 96 70-130
Bromodichloromethane ug/L 48.050 96 70-130
Bromoform ug/L 53.150 106 70-131
Bromomethane ug/L 44.550 89 30-177
Carbon tetrachloride ug/L 48.050 96 70-130
Chlorobenzene ug/L 48.850 98 70-130
Chloroethane ug/L 42.350 85 46-131
Chloroform ug/L 47.050 94 70-130
Chloromethane ug/L 46.950 94 49-130
cis-1,2-Dichloroethene ug/L 47.450 95 70-130
cis-1,3-Dichloropropene ug/L 52.050 104 70-130
Dibromochloromethane ug/L 51.650 103 70-130
Dibromomethane ug/L 51.850 104 70-130
Dichlorodifluoromethane ug/L 43.750 87 52-134
Diisopropyl ether ug/L 48.550 97 70-131
Ethylbenzene ug/L 48.150 96 70-130
Hexachloro-1,3-butadiene ug/L 50.050 100 70-131
m&p-Xylene ug/L 96.1100 96 70-130
Methyl-tert-butyl ether ug/L 46.650 93 70-130
Methylene Chloride ug/L 49.950 100 68-130
Naphthalene ug/L 49.450 99 70-133
o-Xylene ug/L 49.050 98 70-130
p-Isopropyltoluene ug/L 46.850 94 70-130
Styrene ug/L 50.450 101 70-130
Tetrachloroethene ug/L 46.450 93 70-130
Toluene ug/L 48.050 96 70-130
trans-1,2-Dichloroethene ug/L 48.550 97 70-130
trans-1,3-Dichloropropene ug/L 52.050 104 70-130
Trichloroethene ug/L 48.050 96 70-130
Trichlorofluoromethane ug/L 44.150 88 61-130
Vinyl acetate ug/L 109100 109 70-140
Vinyl chloride ug/L 47.150 94 59-142
Xylene (Total)ug/L 145150 97 70-130
1,2-Dichloroethane-d4 (S)%96 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
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Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3148036MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92518792001
3148037
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 80 111 70-135117 5 3080ND88.6 93.4
1,1,1-Trichloroethane ug/L 80 98 70-148103 5 3080ND78.2 82.4
1,1,2,2-Tetrachloroethane ug/L 80 108 70-131118 9 3080ND86.1 94.2
1,1,2-Trichloroethane ug/L 80 108 70-136117 8 3080ND86.6 93.9
1,1-Dichloroethane ug/L 80 99 70-147103 3 3080ND79.5 82.1
1,1-Dichloroethene ug/L 80 75 70-15878 4 3080ND59.9 62.4
1,1-Dichloropropene ug/L 80 99 70-149105 6 3080ND79.4 84.0
1,2,3-Trichlorobenzene ug/L 80 112 68-140118 5 3080ND89.8 94.8
1,2,3-Trichloropropane ug/L 80 108 67-137118 8 3080ND86.8 94.5
1,2,4-Trichlorobenzene ug/L 80 115 70-139119 3 3080ND92.4 95.2
1,2-Dibromo-3-
chloropropane ug/L 80 105 69-136116 10 3080ND84.3 92.7
1,2-Dibromoethane (EDB)ug/L 80 105 70-137113 7 3080ND84.3 90.7
1,2-Dichlorobenzene ug/L 80 113 70-133119 5 3080ND90.8 95.1
1,2-Dichloroethane ug/L 80 101 67-138107 6 3080ND80.4 85.8
1,2-Dichloropropane ug/L 80 110 70-138119 8 3080ND87.8 95.3
1,3-Dichlorobenzene ug/L 80 113 70-133117 3 3080ND90.5 93.4
1,3-Dichloropropane ug/L 80 109 70-136115 5 3080ND87.3 92.0
1,4-Dichlorobenzene ug/L 80 112 70-133117 4 3080ND89.8 93.9
2,2-Dichloropropane ug/L 80 100 52-155105 4 3080ND80.0 83.7
2-Butanone (MEK)ug/L 160 100 61-147108 8 30160ND159172
2-Chlorotoluene ug/L 80 116 70-141121 5 3080ND92.6 96.9
2-Hexanone ug/L 160 111 67-139121 9 30160ND178194
4-Chlorotoluene ug/L 80 115 70-135117 1 3080ND92.3 93.3
4-Methyl-2-pentanone
(MIBK)ug/L 160 111 67-136119 7 30160ND178190
Acetone ug/L 160 97 55-159105 8 30160ND155167
Benzene ug/L 80 101 67-150107 6 3080ND81.0 85.7
Bromobenzene ug/L 80 112 70-134116 4 3080ND89.5 93.1
Bromochloromethane ug/L 80 100 70-146105 5 3080ND80.2 84.2
Bromodichloromethane ug/L 80 105 70-138113 8 3080ND83.7 90.7
Bromoform ug/L 80 104 57-138115 10 3080ND83.6 92.0
Bromomethane ug/L 80 48 10-20044 8 3080ND38.3 35.4
Carbon tetrachloride ug/L 80 103 70-147109 5 3080ND82.5 87.0
Chlorobenzene ug/L 80 112 70-137118 5 3080ND89.6 94.4
Chloroethane ug/L M1804651-16648 4 3080ND36.7 38.3
Chloroform ug/L 80 104 70-144109 5 3080ND83.3 87.6
Chloromethane ug/L M180824-1619 13 3080ND6.2 7.1
cis-1,2-Dichloroethene ug/L 80 102 67-148105 3 308015.9 97.2 99.7
cis-1,3-Dichloropropene ug/L 80 112 70-142119 6 3080ND89.7 94.9
Dibromochloromethane ug/L 80 110 68-138117 7 3080ND87.6 93.7
Dibromomethane ug/L 80 110 70-134118 7 3080ND88.0 94.2
Dichlorodifluoromethane ug/L M180043-1550 3080NDNDND
Diisopropyl ether ug/L 80 101 65-146107 6 3080ND80.4 85.2
Ethylbenzene ug/L 80 111 68-143118 6 3080ND88.9 94.5
Hexachloro-1,3-butadiene ug/L 80 117 62-151121 3 3080ND93.9 96.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3148036MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92518792001
3148037
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
m&p-Xylene ug/L 160 113 53-157117 4 30160ND181187
Methyl-tert-butyl ether ug/L 80 93 59-15699 6 3080ND74.1 79.0
Methylene Chloride ug/L 80 95 64-14899 5 3080ND75.7 79.5
Naphthalene ug/L 80 113 57-150120 7 3080ND90.0 96.4
o-Xylene ug/L 80 111 68-143119 6 3080ND89.0 94.8
p-Isopropyltoluene ug/L 80 114 70-141117 3 3080ND91.0 93.7
Styrene ug/L 80 112 70-136119 6 3080ND89.8 95.0
Tetrachloroethene ug/L 80 110 70-13997 2 3080569657647
Toluene ug/L 80 108 47-157114 6 3080ND86.0 91.3
trans-1,2-Dichloroethene ug/L 80 94 70-14997 4 3080ND75.0 77.7
trans-1,3-Dichloropropene ug/L 80 110 70-138119 8 3080ND87.9 94.9
Trichloroethene ug/L 80 105 70-149113 7 308012.9 96.9 104
Trichlorofluoromethane ug/L M1805161-15453 5 3080ND40.6 42.7
Vinyl acetate ug/L 160 109 48-156116 6 30160ND175185
Vinyl chloride ug/L M1801455-17214 5 3080ND11.0 11.6
Xylene (Total)ug/L 240 112 66-145118 4 30240ND270282
1,2-Dichloroethane-d4 (S)%95 70-13095
4-Bromofluorobenzene (S)%100 70-130100
Toluene-d8 (S)%100 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
595908
EPA 3510C
EPA 8270E
8270E Water MSSV RVE
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92518792001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3142861
Associated Lab Samples:92518792001
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 10.0 01/28/21 13:411.7
1,2-Dichlorobenzene ug/L ND 10.0 01/28/21 13:411.8
1,3-Dichlorobenzene ug/L ND 10.0 01/28/21 13:411.6
1,4-Dichlorobenzene ug/L ND 10.0 01/28/21 13:411.7
1-Methylnaphthalene ug/L ND 10.0 01/28/21 13:412.0
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 v101/28/21 13:411.2
2,4,5-Trichlorophenol ug/L ND 10.0 01/28/21 13:411.4
2,4,6-Trichlorophenol ug/L ND 10.0 01/28/21 13:411.6
2,4-Dichlorophenol ug/L ND 10.0 01/28/21 13:411.4
2,4-Dimethylphenol ug/L ND 10.0 01/28/21 13:411.7
2,4-Dinitrophenol ug/L ND 50.0 01/28/21 13:4126.0
2,4-Dinitrotoluene ug/L ND 10.0 01/28/21 13:411.6
2,6-Dinitrotoluene ug/L ND 10.0 01/28/21 13:411.7
2-Chloronaphthalene ug/L ND 10.0 01/28/21 13:411.7
2-Chlorophenol ug/L ND 10.0 01/28/21 13:411.2
2-Methylnaphthalene ug/L ND 10.0 01/28/21 13:411.9
2-Methylphenol(o-Cresol)ug/L ND 10.0 01/28/21 13:411.9
2-Nitroaniline ug/L ND 20.0 01/28/21 13:413.0
2-Nitrophenol ug/L ND 10.0 01/28/21 13:411.4
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 01/28/21 13:411.2
3,3'-Dichlorobenzidine ug/L ND 20.0 01/28/21 13:418.1
3-Nitroaniline ug/L ND 20.0 01/28/21 13:413.8
4,6-Dinitro-2-methylphenol ug/L ND 20.0 01/28/21 13:413.4
4-Bromophenylphenyl ether ug/L ND 10.0 01/28/21 13:411.8
4-Chloro-3-methylphenol ug/L ND 10.0 01/28/21 13:413.3
4-Chloroaniline ug/L ND 20.0 01/28/21 13:413.6
4-Chlorophenylphenyl ether ug/L ND 10.0 01/28/21 13:412.0
4-Nitroaniline ug/L ND 20.0 01/28/21 13:415.1
4-Nitrophenol ug/L ND 50.0 01/28/21 13:416.6
Acenaphthene ug/L ND 10.0 01/28/21 13:412.0
Acenaphthylene ug/L ND 10.0 01/28/21 13:412.0
Aniline ug/L ND 10.0 01/28/21 13:411.6
Anthracene ug/L ND 10.0 01/28/21 13:412.3
Benzo(a)anthracene ug/L ND 10.0 01/28/21 13:412.7
Benzo(a)pyrene ug/L ND 10.0 01/28/21 13:412.8
Benzo(b)fluoranthene ug/L ND 10.0 01/28/21 13:412.6
Benzo(g,h,i)perylene ug/L ND 10.0 01/28/21 13:412.8
Benzo(k)fluoranthene ug/L ND 10.0 01/28/21 13:412.7
Benzoic Acid ug/L ND 50.0 01/28/21 13:413.4
Benzyl alcohol ug/L ND 20.0 01/28/21 13:412.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3142861
Associated Lab Samples:92518792001
Matrix:Water
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/28/21 13:411.8
bis(2-Chloroethyl) ether ug/L ND 10.0 01/28/21 13:411.9
bis(2-Ethylhexyl)phthalate ug/L ND 6.0 01/28/21 13:413.7
Butylbenzylphthalate ug/L ND 10.0 01/28/21 13:413.1
Chrysene ug/L ND 10.0 01/28/21 13:412.8
Di-n-butylphthalate ug/L ND 10.0 01/28/21 13:412.2
Di-n-octylphthalate ug/L ND 10.0 01/28/21 13:413.9
Dibenz(a,h)anthracene ug/L ND 10.0 01/28/21 13:413.0
Dibenzofuran ug/L ND 10.0 01/28/21 13:412.1
Diethylphthalate ug/L ND 10.0 01/28/21 13:412.0
Dimethylphthalate ug/L ND 10.0 01/28/21 13:412.1
Fluoranthene ug/L ND 10.0 01/28/21 13:412.2
Fluorene ug/L ND 10.0 01/28/21 13:412.1
Hexachloro-1,3-butadiene ug/L ND 10.0 01/28/21 13:411.8
Hexachlorobenzene ug/L ND 10.0 01/28/21 13:412.2
Hexachlorocyclopentadiene ug/L ND 10.0 01/28/21 13:411.6
Hexachloroethane ug/L ND 10.0 01/28/21 13:411.4
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 01/28/21 13:412.9
Isophorone ug/L ND 10.0 01/28/21 13:411.7
N-Nitroso-di-n-propylamine ug/L ND 10.0 01/28/21 13:411.3
N-Nitrosodimethylamine ug/L ND 10.0 01/28/21 13:411.9
N-Nitrosodiphenylamine ug/L ND 10.0 01/28/21 13:413.0
Naphthalene ug/L ND 10.0 01/28/21 13:412.1
Nitrobenzene ug/L ND 10.0 01/28/21 13:411.9
Pentachlorophenol ug/L ND 20.0 01/28/21 13:413.8
Phenanthrene ug/L ND 10.0 01/28/21 13:412.0
Phenol ug/L ND 10.0 01/28/21 13:411.4
Pyrene ug/L ND 10.0 01/28/21 13:412.2
2,4,6-Tribromophenol (S)%76 10-144 01/28/21 13:41
2-Fluorobiphenyl (S)%59 10-130 01/28/21 13:41
2-Fluorophenol (S)%54 10-130 01/28/21 13:41
Nitrobenzene-d5 (S)%80 10-144 01/28/21 13:41
Phenol-d6 (S)%37 10-130 01/28/21 13:41
Terphenyl-d14 (S)%149 34-163 01/28/21 13:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3142862LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 27.350 55 18-130
1,2-Dichlorobenzene ug/L 27.950 56 20-130
1,3-Dichlorobenzene ug/L 25.850 52 18-130
1,4-Dichlorobenzene ug/L 27.850 56 18-130
1-Methylnaphthalene ug/L 29.850 60 29-130
2,2'-Oxybis(1-chloropropane)ug/L 35.9 v1507228-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3142862LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-Trichlorophenol ug/L 34.450 69 35-130
2,4,6-Trichlorophenol ug/L 33.250 66 31-130
2,4-Dichlorophenol ug/L 31.650 63 35-130
2,4-Dimethylphenol ug/L 34.650 69 34-130
2,4-Dinitrophenol ug/L 161250 64 10-153
2,4-Dinitrotoluene ug/L 41.250 82 37-136
2,6-Dinitrotoluene ug/L 38.850 78 33-136
2-Chloronaphthalene ug/L 33.450 67 26-130
2-Chlorophenol ug/L 32.150 64 37-130
2-Methylnaphthalene ug/L 30.850 62 29-130
2-Methylphenol(o-Cresol)ug/L 29.050 58 35-130
2-Nitroaniline ug/L 68.3100 68 37-130
2-Nitrophenol ug/L 34.150 68 32-130
3&4-Methylphenol(m&p Cresol)ug/L 26.350 53 34-130
3,3'-Dichlorobenzidine ug/L 73.1100 73 34-136
3-Nitroaniline ug/L 71.1100 71 37-138
4,6-Dinitro-2-methylphenol ug/L 78.6100 79 21-157
4-Bromophenylphenyl ether ug/L 37.750 75 38-130
4-Chloro-3-methylphenol ug/L 63.5100 63 37-130
4-Chloroaniline ug/L 60.1100 60 38-130
4-Chlorophenylphenyl ether ug/L 31.650 63 33-130
4-Nitroaniline ug/L 72.5100 73 42-137
4-Nitrophenol ug/L 104250 41 10-130
Acenaphthene ug/L 33.550 67 33-130
Acenaphthylene ug/L 34.350 69 35-130
Aniline ug/L 24.850 50 22-130
Anthracene ug/L 36.250 72 48-130
Benzo(a)anthracene ug/L 39.350 79 48-137
Benzo(a)pyrene ug/L 40.050 80 49-138
Benzo(b)fluoranthene ug/L 39.450 79 52-138
Benzo(g,h,i)perylene ug/L 41.150 82 48-140
Benzo(k)fluoranthene ug/L 42.250 84 48-139
Benzoic Acid ug/L 81.9250 33 10-130
Benzyl alcohol ug/L 54.2100 54 35-130
bis(2-Chloroethoxy)methane ug/L 30.850 62 34-130
bis(2-Chloroethyl) ether ug/L 32.850 66 36-130
bis(2-Ethylhexyl)phthalate ug/L 43.450 87 32-165
Butylbenzylphthalate ug/L 45.350 91 34-161
Chrysene ug/L 39.850 80 47-131
Di-n-butylphthalate ug/L 48.750 97 39-144
Di-n-octylphthalate ug/L 42.650 85 30-170
Dibenz(a,h)anthracene ug/L 40.050 80 49-138
Dibenzofuran ug/L 35.050 70 33-130
Diethylphthalate ug/L 39.050 78 38-131
Dimethylphthalate ug/L 36.650 73 37-130
Fluoranthene ug/L 39.350 79 46-137
Fluorene ug/L 34.750 69 37-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3142862LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachloro-1,3-butadiene ug/L 20.450 41 11-130
Hexachlorobenzene ug/L 36.950 74 38-130
Hexachlorocyclopentadiene ug/L 21.050 42 10-130
Hexachloroethane ug/L 22.350 45 14-130
Indeno(1,2,3-cd)pyrene ug/L 41.150 82 41-130
Isophorone ug/L 31.950 64 33-130
N-Nitroso-di-n-propylamine ug/L 31.950 64 36-130
N-Nitrosodimethylamine ug/L 28.350 57 34-130
N-Nitrosodiphenylamine ug/L 41.350 83 37-130
Naphthalene ug/L 31.950 64 30-130
Nitrobenzene ug/L 33.950 68 36-130
Pentachlorophenol ug/L 67.7100 68 23-149
Phenanthrene ug/L 40.150 80 44-130
Phenol ug/L 20.750 41 18-130
Pyrene ug/L 42.450 85 47-134
2,4,6-Tribromophenol (S)%76 10-144
2-Fluorobiphenyl (S)%61 10-130
2-Fluorophenol (S)%47 10-130
Nitrobenzene-d5 (S)%65 10-144
Phenol-d6 (S)%36 10-130
Terphenyl-d14 (S)%106 34-163
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3142863MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92510849021
3142864
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 50 14 10-13021 3050ND7.1J 10.3
1,2-Dichlorobenzene ug/L 50 15 10-13022 3050ND7.4J 11.1
1,3-Dichlorobenzene ug/L 50 13 10-13020 3050ND6.7J 10.2
1,4-Dichlorobenzene ug/L 50 15 10-13021 3050ND7.3J 10.7
1-Methylnaphthalene ug/L 50 17 10-13026 3050ND8.4J 12.8
2,2'-Oxybis(1-
chloropropane)
ug/L 50 34 12-14240 15 3050ND17.2 20.0
2,4,5-Trichlorophenol ug/L 50 67 10-14376 12 3050ND33.7 37.9
2,4,6-Trichlorophenol ug/L 50 63 10-14770 11 3050ND31.4 35.1
2,4-Dichlorophenol ug/L 50 63 10-13865 2 3050ND31.6 32.3
2,4-Dimethylphenol ug/L 50 67 25-13072 6 3050ND33.7 35.8
2,4-Dinitrophenol ug/L 250 14 10-16530 30250ND34.0J 73.8
2,4-Dinitrotoluene ug/L 50 43 29-14848 12 3050ND21.5 24.2
2,6-Dinitrotoluene ug/L 50 71 26-14671 1 3050ND35.4 35.7
2-Chloronaphthalene ug/L 50 18 11-13025 3050ND9.2J 12.5
2-Chlorophenol ug/L 50 58 10-13359 1 3050ND29.2 29.5
2-Methylnaphthalene ug/L 50 17 13-13027 3050ND8.6J 13.5
2-Methylphenol(o-Cresol)ug/L 50 66 20-13061 8 3050ND32.8 30.3
2-Nitroaniline ug/L 100 73 24-13675 2 30100ND73.5 74.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3142863MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92510849021
3142864
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2-Nitrophenol ug/L 50 65 10-15364 2 3050ND32.6 31.9
3&4-Methylphenol(m&p
Cresol)ug/L 50 62 16-13056 11 3050ND31.1 28.0
3,3'-Dichlorobenzidine ug/L 100 84 10-15387 4 30100ND83.5 86.9
3-Nitroaniline ug/L 100 77 22-15182 6 30100ND77.1 81.8
4,6-Dinitro-2-methylphenol ug/L R11004310-18069 47 30100ND42.8 68.9
4-Bromophenylphenyl ether ug/L 50 53 25-13061 13 3050ND26.7 30.6
4-Chloro-3-methylphenol ug/L 100 76 25-13375 1 30100ND76.0 75.2
4-Chloroaniline ug/L 100 55 14-13257 4 30100ND55.1 57.4
4-Chlorophenylphenyl ether ug/L 50 37 19-13043 15 3050ND18.6 21.7
4-Nitroaniline ug/L 100 83 29-15091 9 30100ND83.3 91.3
4-Nitrophenol ug/L R12502510-13044 54 30250ND63.5 110
Acenaphthene ug/L 50 26 16-13031 15 3050ND13.2 15.4
Acenaphthylene ug/L 50 29 15-13735 17 3050ND14.5 17.3
Aniline ug/L 50 37 10-13038 2 3050ND18.6 19.1
Anthracene ug/L 50 68 37-13673 6 3050ND34.1 36.3
Benzo(a)anthracene ug/L 50 84 40-14594 11 3050ND42.0 47.0
Benzo(a)pyrene ug/L 50 87 41-14695 9 3050ND43.7 47.7
Benzo(b)fluoranthene ug/L 50 86 39-15196 11 3050ND43.0 47.9
Benzo(g,h,i)perylene ug/L 50 89 40-14797 8 3050ND44.4 48.3
Benzo(k)fluoranthene ug/L 50 90 40-14698 9 3050ND44.9 48.9
Benzoic Acid ug/L M1250010-1300 30250NDNDND
Benzyl alcohol ug/L 100 57 25-13059 2 30100ND57.4 58.7
bis(2-
Chloroethoxy)methane
ug/L 50 59 23-13062 5 3050ND29.5 31.1
bis(2-Chloroethyl) ether ug/L 50 68 25-13069 1 3050ND34.2 34.6
bis(2-Ethylhexyl)phthalate ug/L 50 86 28-16695 10 3050ND42.9 47.4
Butylbenzylphthalate ug/L 50 92 33-165101 9 3050ND46.1 50.4
Chrysene ug/L 50 84 38-14195 12 3050ND42.2 47.4
Di-n-butylphthalate ug/L 50 92 32-15399 7 3050ND46.2 49.6
Di-n-octylphthalate ug/L 50 90 30-17592 2 3050ND45.1 45.9
Dibenz(a,h)anthracene ug/L 50 89 39-14897 8 3050ND44.7 48.5
Dibenzofuran ug/L 50 35 20-13041 16 3050ND17.3 20.3
Diethylphthalate ug/L 50 76 28-14278 3 3050ND38.0 39.2
Dimethylphthalate ug/L 50 68 26-13667 2 3050ND33.9 33.4
Fluoranthene ug/L 50 87 39-14394 8 3050ND43.4 46.9
Fluorene ug/L 50 42 24-13249 13 3050ND21.2 24.3
Hexachloro-1,3-butadiene ug/L 50 12 10-13018 3050ND5.8J 8.9J
Hexachlorobenzene ug/L 50 68 29-13069 2 3050ND33.9 34.6
Hexachlorocyclopentadiene ug/L M150810-13013 3050ND4.2J 6.3J
Hexachloroethane ug/L 50 13 10-13021 3050ND6.3J 10.5
Indeno(1,2,3-cd)pyrene ug/L 50 89 39-14896 7 3050ND44.4 47.8
Isophorone ug/L 50 58 23-13059 2 3050ND28.8 29.4
N-Nitroso-di-n-propylamine ug/L 50 57 25-13060 5 3050ND28.5 29.9
N-Nitrosodimethylamine ug/L 50 45 22-13039 14 3050ND22.7 19.7
N-Nitrosodiphenylamine ug/L 50 70 26-13475 7 3050ND35.2 37.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3142863MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92510849021
3142864
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Naphthalene ug/L 50 18 14-13032 3050ND9.2J 16.1
Nitrobenzene ug/L 50 50 25-13058 14 3050ND25.1 29.0
Pentachlorophenol ug/L R11006210-17590 38 30100ND61.6 90.1
Phenanthrene ug/L 50 70 36-13377 9 3050ND35.2 38.4
Phenol ug/L 50 37 10-13038 4 3050ND18.3 19.1
Pyrene ug/L 50 85 40-14396 12 3050ND42.4 47.8
2,4,6-Tribromophenol (S)%83 10-14498
2-Fluorobiphenyl (S)%38 10-13043
2-Fluorophenol (S)%48 10-13046
Nitrobenzene-d5 (S)%64 10-14470
Phenol-d6 (S)%39 10-13037
Terphenyl-d14 (S)%109 34-163131
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92518792
N. TRYON BROWNFIELDS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92518792001 595908 596076MW-1 EPA 3510C EPA 8270E
92518792001 596980MW-1 EPA 8260D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/03/2021 02:56 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 27
Page 27 of 27