HomeMy WebLinkAbout5603_ROSCANS_1999Ca
April6, 1999
Collins &Aikman
Collins & Alkman Products Co.
701 McCullough Drive
P.O. Box 32665
Charlotte, NC 28232
(704)547-8500
Ms. Cheryl Marks
North Carolina Department of
Environment and Natural Resources
Division of Waste management
Solid Waste Section
401 Oberlin Road, Suite 150
Raleigh, N.C. 27605
Re: Groundwater Monitoring
Industrial Landfill Permit #56-03
Dear Ms. Marks:
This letter addresses issues raised in your letter dated December 16, 1998. The information and
attachments are arranged in the order of your letter. We provide this information so that you may
complete the process of reviewing our landfill groundwater monitoring system.
Waste Stream
The landfill is a monofill facility for the exclusive use of Collins & Aikman. Since the start of
operations in 1981, only waste automotive carpet trimmings from our Old Fort, NC plant have been
accepted for disposal. There are no other materials or wastes disposed of at this landfill.
The waste stream consists of trimmings from carpet molding operations. The carpets are constructed
using a variety of mostly inert man made fibers and backings. All waste from carpet operations that
have value as fuel (19.8%) or recycling (47.7%) are used as such. The balance is disposed of in our
landfill.
Drawines
We understand the full set of drawings submitted was not passed on to you for review. Sheet 2, which
you have, is an enlarged view of Phase 3. The West End of the site does not show on this sheet.
Enclosed is a copy of Sheet 1, which is a full site plan showing all the surface water sampling points and
wells that make up our monitoring system.
Background Water Ouality
Well number MW-lA is located near the highest topography on the site and is far up -gradient to all
landfill operations past and present. Analysis of this well gives us a good indication of background
levels for the parameters tested. Barium and cadmium have both been detected in this well at levels
slightly exceeding groundwater standards. These results have previously been reported to the division
and are summarized in the attached table. There are no known potential off -site influences to the area
groundwater.
\\SSDDIF01\ENGLIB\LITTLE\gw onitocdoc
Formaldehyde Analysis
Two types of automotive carpet are processed at our Old Fort plant. Tufted carpet manufactured at our
Albemarle plant receives an extruded elastomeric such as polyethylene or EVA on the back at Old Fort
to provide a tuft -lock. The tufted carpet is then trimmed, cut, and molded. Tufted carpet processed at
Old Fort has no latex coating.
Non -woven carpet backed with latex for fiber -lock is manufactured at our Montgomery plant in Troy,
NC and then processed at the Old Fort plant. This processing may consist of molding and trimming or
assembly. The latex applied at Montgomery may contain trace amounts (less than 10 ppm) of
formaldehyde in the compounded product delivered from Reichhold Chemical, our supplier. Reichhold
states that formaldehyde is not an additive in the formulation, but is present in trace amounts in the
ingredients used in the formulation. The non -woven carpet is oven cured at approximately 320OF after
coating in a continuous process. Trace amounts of any VOCs such as formaldehyde would be expected
to volatilize in this process.
Given our processes and the trace amounts involved it is very unlikely that there is any formaldehyde in
the product when it arrives at Old Fort. Likewise, the same would be true for any waste from the
molding processes at Old Fort.
We believe there is no justification for going to the expense of testing the site groundwater for
formaldehyde. We request that the requirement be withdrawn. A letter from Reichhold Chemical and
MSDSs for the latex backcoatings used on our automotive carpets are enclosed for your review.
TCLP Analysis
TCLP analyses were performed by Industrial and Environmental Analysts, Inc. in June 1996. The
results were BQL for all parameters in all segments of the analysis. A copy of the report was previously
submitted to James Coffey on June 27, 1996. A duplicate copy is enclosed for your review.
Modeline
Collins & Aikman is landfilling a waste that is basically inert and for which TCLP data shows no
leechable listed components. After eighteen years of site use, sampling to date has shown no significant
issues or impact to the site groundwater. Detectable parameters are near background levels. Given all
the information available, we question the need for modeling and request the requirement be withdrawn.
We trust the above information is sufficient to complete your review of our groundwater monitoring
system. Should you need additional information, please give me a call at 704-548-2200 in Charlotte.
Sincerely,
COLLINS &&AAHCMAN PRODUCTS CO.
AAA e G o- 7
David N. Little
Corporate Engineering
ASSDD1 FOnENGLIBUTTLBgw onitondoc
cc: J. Davis — Old Fort
S. Laton — Old Fort
G. Miller - Albemarle
C. Moore - Corporate
File: Old Fort, Landfill Permit
Groundwater Analysis Summary 0310211999 M66 Sheet
Old Fort Landfill NC Permit #56.03
Notes:
1. Sampling parameters are for 8 RCRA metals, pH, temperature, and conductivity.
2. Detection levels are shown only where the parameters were dedected, i.e. any level greater than non -detect.
3. Detected levels exceeding N.C. State groundwater (Title 15A: 02L.0200) limits are highlighted with a border.
Parameter
Method
Units
State Limit
Sampling Points / Detection Levels
MW to
MW 2
MW 3
MW 4 I
SW 1 I
SW 2
SW 3
SW 4
Ground
Water
Date Sampled: 5/15197
NIA
feet
48.63
11.03
16.3
13.45
Depth to Water
Specific Conductivity
NIA
umhos/cm2
30
90
100
30
Temperature
NIA
Deg. C
14
16
16
14
pH
N/A
6.7
6.6
5.8
5.5
Barium
6010A
mg/L
2.OD0
0.067
0.038
0.089
0.066
0.014
0.019
0.63
0.35
Chromium
7191
mg/L
0.050
0.004
-
Cobalt
7201
mg/L
0.004
0.004
-
0.032
0.013
Copper
6010A
mg/L
1.000
0.011
-
-
-
-
-
Vanadium
7811
mg/L
0.009
-
-
0.006
Zinc
6010A
mg/L
2.100
0.038
0.011
0.013
-
-
-
0.12
0.029
Landfill Volatiles
8260
ug/L
-
-
-
-
-
-
-
Date Sampled: 4/21198
N/A
feet
47.25
11.5
15.05
12.35
-
-
Depth to Water
Specific Conductivity
N/A
umhos/cm2
15
75
68
22
29
26
Temperature
NIA
Deg. C
16
15
14
14
14
14
pH
NIA
5.6
6.2
5.3
5.2
6.8
6.7
3.7
2.2
Barium
200.7
mg/L
2.000
-
0.6
-
-
-
Cadmium
200.7
mg/L
0.005
-
Chromium
200.7
mg/L
0.050
-
Lead
200.7
mg/L
0.015
-
-
Silver
200.7
mg/L
0.018
-
-
Arsenic
206.2
mg/L
0.050
-
-
Mercury
245.1
mg/L
0.0011
-
Selenium
270.2
mglL
0.050
-
-
Date Sampled: 10/5I98
N/A
feet
49.35
11.29
17.17
13.68
-
Depth to Water
Specific Conductivity
N/A
umhos/cm
-
76
80
22
33
35
Temperature
N/A
Deg. C
13
13
13
14
17
17
pH
N/A
5.7
6.5
5.6
5.0
6.6
6.6
2.2
2.9
Barium
EPA
mg/L
2.000
0.33
1.7
-
0.01
-
Cadmium
200.7
mg/L
0.005
-
-
-
-
-
Chromium
200.7
mg/L
0.050
-
-
0.1
Lead
200.7
mg/L
0.015
-
-
-
-
-
-
Silver
200.7
mg/L
0.018
-
-
-
-
Arsenic
206.2
mg/L
0.050
-
-
-
-
-
Mercury
245.1
mg/L
0.0011
-
-
-
-
Selenium
270.2
mg/L
0.050
-
-
-
-
-
-
Date Sampled:
N/A
feet
Depth to Water
Specific Conductivity
N/A
umhos/cm
Temperature
N/A
Deg. C
pH
N/A
Barium
EPA
mg/L
2.000
Cadmium
200.7
mg/L
0.005
Chromium
200.7
mg/L
0.050
Lead
200.7
mg/L
0.015
Silver
200.7
mg/L
0.018
Arsenic
206.2
mg/L
0.050
Mercury
245.1
mg/L
0.0011
Selenium
270.2
mg/L
0.050
Wellrpt.123
REICHROLD
Corporate Headquarters
P.O. Box 13582
Research Triangle Park, NC 27709-3582
April 1,1999
Mr. David Little
Collins and Aikman Products
PO Box 32665
Charlotte, NC 28232
Dear Mr. Little:
This letter is In response to your inquiry concerning the free formaldehyde content of
Tylac® 99836-00, Tylac® 99819-01 and Tylac 0 99855-00.
Based on our current manufacturing formulation for both of these products, we have
calculated that the amount of Intentionally added formaldehyde Is less than 10 parts
per million in both products. However, these values are based on the amount of
formaldehyde added to compounds used to manufacture the carpet backing latex.
Formaldehyde is a volatile compound and the amount found in the finished carpet will
be significantly lower due to the following activities:
1. Reirhhold's processing of the latex.
2. C&Ns manufacture of the carpet and drying of the latex.
3. C&A's high temperature molding of the carpet into trunk liners.
For these reasons, we don't believe that there would be measurable amounts of
formaldehyde remaining in trunk liner trimmings.
Very truly yours,
4 - �t�
Patrick McKelvey
Product Safety & Compliance
Reichhold, Inc,
Tel: (919) 990-7500
Fax: (919) 990-7711
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
1 :chhold Chemicals, Inc.
.O. Box 13562 ALL CAL EMERGENCIES
Research Triangle Park, NC 27709 1-800-424-9300
ssue Da o - -9 7 Page 1
SECTION I - PRODUCT IDENTIFICATION
NSDS Number; 00028863
Trade Name: TYLAC(R) 99855-00
Product Class: S;nthetic Rubber Laces
C.A.S. Number: Mixture
HMIS Rating: Health = 1 Fire = 0 Reactivity = 0
SECTION II - INGREDIENTS
Maximum Exposure
Ingredients CAB Content Limits
Polymer solids Proprietary 28.0 % None assigned
Clay unknova 31.0 % None assigned
Water 7732-18-5 41.0 % None assigned
SECTION III - PHYSICAL DATA
Boiling Point: >212 Deg. F Vapor Density: Heavier than Air.
volatile %: 40 - 42 by Weight. specific Gray. 1.14
Evap. Rate: slaver than n-Butyl Acetate.
Appearance: White liquid, ammonlacal odor.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flammability Class: N/A Flash Point: N/A LEL
-EXT32M rTSHING MEDIA:
water, carbon dioxide, or dry chemical.
-SPECIAL FIREr:TGHTING PROCEDURES*.
Firefighters and othera exposed to vapors or products of
combustion should Wear self-contained breathing apparatus.
-UNUSUAL FIRS & EXPLOSION HAZARDS:
None xnovn.
SECTION V - HEALTH HAZARD DATA
-PERMISSIBLE EXPOSURE LEM;
There is no OSHA PEL or ACGIH
solids in this product.
-EFFECTS OF OVEREXPOSURE:
Sm. This material may cause
prolonged or repeated contact.
naDLMION: Excessive exposure
cause irritation of eyes, nose
(Cont.)
TLV established for the polymer
skin irritation or rash upon
to vapors or spray mists can
and throat.
JUmERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
Raichhold chemicals, Eac.
P.O. Box 13582 ALL CE MICAL EKE
Research Triangle Park, NO 27709 1-800-424-9300
50028863
Issue Date: 08-12-97 Page 2
SECTION V - $SALTS sAMD DATA (cont.)
-EFFECTS OF OVZRExPOSURE: (coat.)
EYES: This material may be an eye irritant.
-FIRST AID:
SKIN: Wash with soap and water immediately.
EYES: Flush with large quantities of water for 15 minutes and
seek medical attention.
INGFBTICm. If ingested call a physician at once.
-PRIORY ROUTE(S) OF ENTRY:
Inhalation of vapors (especially if sprayed or heated).
-TOXICOLOGICAL INFORMATION:
This product does mot contain 0.1% or more of any substance
listed as a carcinogen by NTP, IARC or OSHA.
SECTION VI - REACTIPITY DATA
STABILITY: [ ] Unstable (x) Stable
HAZARDOUS POLYNERIZATION: L ] my occur EX] will not occur
-INCCNPATIBIL=Y:
None known.
-CMMITIONS TO AVOID:
Beep from freezing.
-HAZARDOUS DEPOSITION PRODUCTS:
Under severe thermal degradation - low -molecular -weight organic
compounds will be formed.
SECTION VII - SPILL OR LEAK PROCEDURES
-STEPS TO BE MKEH IN CASE Pa1wLm IS RELEASED OR SPILLED:
clean up with water before allowing to dry. Sodium chloride can
be sprinkled on the spill, which may coagulate the latex and
facilitate cleaning with water. Place coagulated waste in a
closed container. pear protective equipment during cleanup.
-WASTE DISPOSAL lUvMOD:
At this time, this material or its containers would not be
considered hazardous wastes as defined tinder the federal
RCIiA regulations (40 CFR 261) if discarded. care should be
taken to ensure that the material or its containers are disposed
of in an approved facility in accordance with current federal,
state, and local regulations.
For further information, contact your state or local solid waste
agency or the United states Enviro moutal Agency's RCRA
hotline (800-424-9346 or 202-382-3000).
MATERIAL SAFETY DATA SMET
Information Telephone No. (800) 275-6353
Re-chhold chemicals, Inc.
P.O. Box 13562
Research Triangle Park, NC 27709
ALL rREKICAL EMERGENCIES
1-800-424-9300
Issue Date. 08-12-97 Page 3
SECTION Vill - SPECIAL PROTECTION INPOMWICK
-RESPIRATORY PROTECTION:
Not generally required during normal use and handling
The need for respiratory protection should be evaluated if
this material is sprayed or heated in poorly Ventilated areas.
-VENTILATION:
General ventilation is recommended during normal use.
Local ventilation may be required during certain operations
to prevent inhalation of vapors.
-PROTECTIVE GLOVES:
Chemical -resistant nitrile, neoprene or rubber gloves as needed
to prevent akin contact.
-EYE PROTECTION:
Wear face shield or chemical goggles as needed to prevent eye
contact.
-OTHER PROPSCTIVE EQuIPNSNT:
Wear protective clothing as needed to prevent skin contact.
Eye wash station and safety shover should be available.
SECTION IY - SPECIAL PRECAUTION$
-PRECAUTIONS TO BE TAKEN 337 HANDLING AND STORING:
Avoid prolonged or repeated inhalation of heated vapors or
prolongedor rep
ay es. ated skin contact. away from heat
flame. Avoid
-OTHER PRECADTIGNS:
Consult product bulletin prior to using this material.
SECTION X - SUPPLEMENTAL INFORMATION
-REGULATORY INWORK&TIOI:
None.
-SARA B WHMEEA HAZARD CLASSIFICATIONS:
This material is not categorised as a hazardous substance as
defined by SARA Title III regulations (40 CFR 370).
CANADIAN MaS CLASSIFICATION: NOT WHHIS HAZARDOUS
-SARA SECTION 313 LISTED INGREDIENTS:
This material does not contain any substance which is subject
to the reporting requirements of 40 CFR 372.
-DOT PROPER SHIPPING NAME:
NOT RJWJJ BD BY DOT - ENR
-MSDS DREpARATTON INFO2MATION:
PREPARED BY: Product Safety i Compliance Department
Research Triangle ParX, North Carolina 27709
(919) 990-7500
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
Reichhold Chemicals, Inc.
P.O. BOY 13582
Research Triangle Park, NC 27709
Issue Date: 08-12-97
ELL CHElQCAL EKERG'ENCIES
1-800-424-9300
Page
L YiY C^
Reiehhold's knowledge as of the data hereof; however, Reichhold makes no
representation as to its completeness or accuracy. Customers are encouraged
to make their owa determination as to the suitability of this product for
their purpose prior to use. Reicbhold disclaims responsibility to damages of
any kind resulting from the use of this information. THERE ARE NO VMRRA TIES
OR ttuaoF MMTIONS, MMESS OR 111PLIED, INCLUDIM THOSE OF NERCHADMILITy OR
FITNESS FOR E PARTICULAR PURPOSE WITH RESPECT To THIS INFOA2MTION OR TO THE
PRODUCT IT DESCRIBES.
Reichhold, Inc.
P.O. Box 13562
Research Triangle
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-9353
Park, NC 27709
ALL CHEMICAL EMERGENCIES
1-800-424-9300
a..
Effective ate: 07-24-98 Page
x xxs.csc�sa.■cx:xc.■cxsa.r.cxas..caxs....cxas..ccxa■■Rcscxa.r...xaa.....xxa....a
SECTION I - PRODUCT IDENTIFICATION
MSDS Number: 99819-01
Trade Name: TYLAC(R) 99819-01
Product Class: Synthetic Rubber Latex
C.A.B. Number: Mixture
HMIS Rating: Health . 1 Fire . 0 Reactivity . 0
r....■scs.0.scxs...ssca...caxaac.cc¢xs■■.cc=x..rr...xa........ac.......axxm...
SECTION II - INGREDIENTS
Maximum Exposure
Ingredients CAB $ Content Limits
Modified Styrene-Butadiene Polymer Proprietary 31.0 % None assigned
Clay Un)mown 16.0 % None assigned
Water 7732-18-5 52.0 % None assigned
s. o..■•c_-c r.r o .cxx�......acxr...a.cads.....xxc�.■c.u.coxas.....sssxac......
SECTION III - PHYSICAL DATA
Boiling Point: 212 Deg. F. Vapor Density: Heavier than Air.
Volatile %: 52 - 54 by weight. Specific Grav: 1.00
Evap. Rate: Slower than n-Butyl Acetate.
Appearance: White liquid with slight ammonical odor.
a xxaxxsar u.r•cocas..r...axxacsr..■nca�xxas.....Qa��xaa........caxxasa....s.ca-
SECTION IV - FIR$ AND EXPLOSION HAZARD DATA
Flammability Claus: N/A Flash Point: N/A LEL
-EXTINGUISHING MEDIA:
Water, carbon dioxide, or dry chemical.
-SPECIAL FIREFIGHTING PROCEDURESt
Firefighters and others exposed to vapor® or products of
combustion should wear self-contained breathing apparatus.
-UNUSUAL FIRE & EXPLOSION HAZARDS:
None Xnown.
..asaxxxxa.. car uaxcsrsr....sxxr......mscxxc.cLAcac.xeaa......cesxxxas...a xxxx
SECTION V YEALTH EFA,TARD DATA
-PERMISSIBLE EXPOSURE LEVEL:
There is no OSHA PEL or ACGIH
butadiene styrene polymer.
-EFFECTS OF OVEREXPOSUREt
SKIN: This material may cause
prolonged or repeated contact.
INFAIATIONt Excessive exposure
cause irritation of eyes, nose
(cont.)
TLV established for modified
skin irritation or rash upon
to vapors or spray mists can
and throat.
Raichhold, Inc.
P.O. Box 13582
Ragearch Triangle
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
Park, NC 27709
ALL CHEMICAL EMERGENCIES
1-800-424-9300
,%WW
M9DS ME
er: -
Effective Date: 07-24-98
Page 2
■4�xil.i¢■s.iCiis■lair.■Sisii¢SlsiiSiiiCCiisi¢ass.i�ss.ssis....CCs...s�l..s¢�3.
SECTION V - HEALTH HAZARD DATA (coast.)
-EFFECTS OF OVEREXPOSURE: (cunt.)
EYES: Thin material may be an eye irritant.
-FIRST AID:
SKIN: Wash with soap and water immediately.
EYES: Flush with large quantities of water for 15 minutes and
seek medical attention.
INGESTION: If ingested call a physician at once.
-PRIMARY ROUTE(S) OF ENTRY:
Inhalation of vapors (especially if sprayed or heated).
-TOXICOLOGICAL INFORMATION:
This product does not contain 0.1% or more of any substance
listed as a carcinogen by NTP, IARC or OSHA.
L'Cass.si¢xiii..sicxsis...ssss...........
SECTION VI - REACTIVITY DATA
STABILITY: [ J Unstable [xJ Stable
HAZARDOUS POLYMERIZATION: [ J May occur (xJ Will not occur
-INCOMPATIBILITY:
None known.
-CONDITIONS TO AVOID:
Keep from freezing.
ZARDOUS DECOMPOSITION PRODUCTS:
Under severe thera:al degradation - low -molecular -weight organic
compounds will be formed.
.....i6 ii i■ -i . iJ s .p.-f� r i S l s¢¢-i 31..
SECTION VII - SPILL OR LEAK PROCEDURES
-STEPS TO BE TAB IN CASE MATERIAL IS RELEASED OR SPILLED:
Clean up with water before allowing to dry. Sodium chloride can
be sprinkled on the sill, which say coagulate the latex and
facilitate cleaning with water. Place coagulated waste in a
closed container. Wear protective equipment during cleanup.
-WASTE DISPOSAL METHOD:
At this time, this material or its containers would not be
considered hazardous wastes as defined under the federal
RCRA regulations (40 CFR 261) if discarded. Care should be
taken to ensure that the material or its containers are disposed
of in an approved facility in accordance with current federal,
state, and local regulations.
For further information, contact your state or local solid waste
agency or the United States Environmental Agency's RCRA
hotline (800-424-9346 or 202-382-3000). •>
•s
Reichhold, Inc.
P.O. Box 13582
R-%earch Triangle
Lqle
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
Park, NC 27709
ALL CHEMICAL EMERGENCIES
1-800-424-9300
mbi.) t Numoer; yytllJ-Ul
Effective Date: 07-24-98 Page 3
o....ca...acc.a..rcr.■..ace...eea....eca.....eo...r...eCa ....a �ma.....cca..
SECTION VIII - SPECIAL PROTECTION INFORMATION
-RESPIRATORY PROTECTION:
Not generally required during normal use and handling.
The teed for respiratory protection should be evaluated if
this material is sprayed or heated in poorly ventilated areas.
-VENTILATION:
General ventilation is reccesended during normal use.
Local ventilation may be required during.certain operations
to prevent inhalation of vapors.
-PROTECTIVE GLOVES:
Chemical -resistant nitrile, neoprene or rubber gloves as needed
to prevent skin contact.
-EYE PROTECTION:
Wear face shield or chemical goggles as needed to prevent eye
contact.
-OTHER PROTECTIVE EQUIPMENT:
Wear protective clothing as needed to prevent akin contact.
Eye wash station and safety shower should be available.
......act...........oat.......accost.o....ccdcmos..�ascc�coc..r.r.....acaa:.r
SECTION IX - SPECIAL PRECAUTIONS
-PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Avoid prolonged or repeated inhalation of heated vapors or
�. spray mists. Keep away from heat or open flame. Avoid
prolonged or repeated skin contact.
-OTHER PRECAUTIONS:
Consult product bulletin prior to using this material.
.......see__a............caa...r.......eo-aa.......... u..eo�cos...........raca
SECTION X - SUPPLEMENTAL INFORMATION
None.
-SARA & WHMIS HAZARD CLASSIFICATIONS:
This material is not categorized as a hazardous substance as
defined by SARA Title III regulations (40 CFR 370).
CANADIM WSMIS CLASSIFICATION: NOT WHM:LS,IXZARD0US
-SARA SECTION 313 LISTED INGREDIENTS:
This material does not contain any substance wh-tch is subject
to the reporting requirements of 40 CM :V72.
-DOT PROPER SHIPPING NAME:
NOT REGULATED BY DOT - HMR
-MSDS PREPARATION INFORMATION:
PREPARED BY: Product Safety Ccciplience Department
Research Triangle Park, North Carolina 27709
(919) 990-7500 -
MATERIAL SAFETY DATA SHEET
Reichhold, Inc. Information Telephone No. (800) 275-6353
P.O. Box 13582 ALL CHEMICAL EMERGENCIES
Rpeearch Triangle Park, NC 27709 1-800-424-9300
V
m�u� numoer: Effective Date: 07-24-98 99tl19-01 Page 4
New
This informatiori is provided good faiths correct to the est o
Reichhold's knowledge as of the date hereofy however, Reichhold makes no
representation as to its corpleteness or accuracy. Customers are encouraged
to make their own determination as to the suitability of this product for
their purpose prior to use. Reichhold dieclai= responsibility to damages of
any kind resulting from the use of this information. THERE ARE NO WARRANTIES
OR REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDMM THOSE OF MEROWTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE
PRODUCT IT DESCRIBES.
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
Reichhold Che=icals, Inc.
P.O. Box 13582 ALL CHEMICAL EMERGENCIES
P--;earch Triangle Park, NC 27709 1-800-424-9300
1 ue Dater
arr.v.. usasxsaaay.r.aauevaayssxxxaavarsav¢vas:=asuasvwaeaasaao u...a s. o...
SECTION I - PRODUCT IDENTIFICATION
MSDS Numbers 90022387
Trade Name: TYLAC(R) 99936-00
Product Claess Modified Styrene Acrylonitrile copolymer
C.A.S. Numbers Mixture
HMIS Rating: Health - 1 Fire - 0 Reactivity = 0
exxxx:..r...r a vasaaaxasao■.r..r.r■roams:-ss o ra...ruasasxx..... uaaeaxaaa...
SECTION II - INGREDIENTS
Ingredients
Maximum Exposure
CAS k Content Limits
Polymer solids
Proprietary
31.0 %
None assigned
Clay
Unknown
26.0 %
None assigned
Water
7732-18-5
43.0 %
None assigned
rum---ass.o........r.rsss...assasaasaxasa...r..r.rsrss.ssxxxxxxx.r.ss.s.sasass
SECTION III - PHYSICAL
DATA
Boiling Points >212 Deg. F. Vapor Density: Heavier than Air.
volatile $: 42-44 by weight. Specific Grays 1.14
Evap. Rate: Slower than n-Butyl Acetate.
Appearances Black liquid with slight ammonical odor.
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SECTION IV - FIRE AND EXPLOSION HAZARD DATA
?tdssmiability Class: N/A Flash Point: Not Applicable LEL : N/A
-EXTINGUISHING MEDIA:
Water, carbon dioxide, or dry chemical.
-SPECIAL FIREFIGHTING PROCEDURES:
Firefighters and ethers exposed to vapors or products of
combustion should wear self-contained breathing apparatus.
-UNUSUAL FIRE & EXPLOSION HAZARDS:
None Known.
u¢xxxxxs¢v.v....r..a......... r.... r..s.rssssssszsaaxaasass...........
srs.axxas
SECTION V. HEALTH HAZARD DATA
-PERMISSIBLE EXPOSURE LEVEL;
There is no OSHA PEL or ACGIH
solids in this product.
-EFFECTS OF OVEREXPOSURE:
SKIN: This material may cause
prolonged or repeated contact.
INHALATIONS Excessive exposure
cause irritation of eyes, nose
(Cont.)
TLV established for the polymer
skin irritation or rash upon
to vaaore.or spray mists can
and throat.
MATERIAL SAFETY DATA SHEET
Information Telephone No. (800) 275-6353
Reichhold Chemnicals, Inc.
P.O. Box 13582
F search Triangle Park, NC 27709
ALL CHEMICAL EMERGENCIES
1-800-424-9300
er:
I®sue Date: 04-22-96 Page 2
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SECTION V - HEALTH HAZARD DATA (cunt.)
-EFFECTS OF OVEREXPOSURE: (cont.)
EYES: This material may be an eye irritant.
-FIRST AID:
SKIN: Wash with soap and water immediately.
EYES: Flush with large quantities of water for 15 minutes and
seek medical attention.
INGESTION: If ingested call a physician at once.
-PRIMARY ROUTES) OF ENTRY:
Inhalation of vapors (especially if sprayed or heated).
-TOXICOLOGICAL INFORMATION:
This product does not contain 0.1% or more of any substance
listed as a carcinogen by NTP, IARC or OSHA.
z..zzwccecwcs.■szeceewwws..wwwwwwwwcwwwwcwewwccwwww■ed�sewwweeewwwe■■wwawwimaaa
SECTION VI - REACTIVITY DATA
STABILITY: [ ] Unstable [x) Stable
HAZARDOUS POLYMERIZATION: [ ] May occur [x] Will not occur
-INCOMPATIBILITY:
None known.
-CONDITIONS TO AVOID:
Keep from freezing.
-wk7ARDOUS DECOMPOSITION PRODUCTS:
Under severe thermal degradation - low -molecular -weight organic
compounds will be formed.
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SECTION VII - SPILL OR LF,AR PROCEDURES
-STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Clean up with water before allowing to dry. Sodium chloride can
be sprinkled on the spill, which may coagulate the latex and
facilitate cleaning with water. Place coagulated waste in a
closed container. wear protective equipment during cleanup.
-WASTE DISPOSAL METHOD:
At this time, this material or its containers would not be
considered hazardous wastes as defined under the federal
RCRA regulations (40 CFR 261) if discardmd. Care should be
taken to ensure that the material or its containers are disposed
of in an approved facility in accordance with current federal,
state, and local regulations.
For further information, contact your state or local solid waste
agency or the United States Environmental Agency's RCRA
hotline (800-424-9346 or 202-382-3000). -
MATERIAL SAFETY DATA SHEET
Inforaatian Telephone No. (800) 275-6353
Reichhold Chemicals, Inc.
P.O. Box 13582 ALL CHEMICAL EMERGENCIES
F search Triangle Park, NC 27709 1-800-424-9300
a..
Issue Date: 04-22-96 art 8
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SECTION VIII - SPECIAL PROTECTION INFORMATION
-RESPIRATORY pROTECTIONt
Not generally required during normal use and handling.
The need for respiratory protection should be evaluated if
this material is sprayed or heated in poorly ventilated areas.
-VENTILATION:
General ventilation is reccamAnded during normal use.
Local ventilation ray be required during certain operations
to prevent inhalation of vapors.
-PROTECTIVE GLOVES:
Chemical -resistant nitrile, neoprene or rubber gloves required.
-EYE PROTECTION:
wear face shield or chemical goggles.
-OTHER PROTECTIVE EQUIPMENT:
Wear protective clothing to prevent skin contact.
Eye wash station and safety shower should be available.
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SECTION IX - SPECIAL pRECASJTIONS
-PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Avoid prolonged or repeated inhalation of heated vapors or
spray mints. Keep away from heat or open flame. Avoid
prolonged or repeated skin contact.
iER PRECAUTIONS:
L' Consult product bulletin prior to using this material.
•..a cca..o.ea..rsscas.sccz...czawr.rxssr.sscaar...wca..ssssczw..sazzsrsssaswr
SECTION X - SUPPLEMENTAL YNFORMATION
-REGULATORY INFORMATION:
None.
-SARA & WHMIS HAZARD CLASSIFICATIONS:
This material is not categorized as a hazardous substance as
defined by SARA Title III regulations (40 CFR 370).
CANADIAN wMIIS CLASSIFICATION: Not WHMIS Hazardous
-SARA SECTION 313 LISTED INGREDIENTS:
This material does not contain any substance which is subject
to the reporting requirements of 40 CFR 372.
-DOT PROPER SHIPPING NAME:
NOT REGULATED BY DOT - HMR
-MSDS PREPARATION INFORMATION:
PREPARED PYt Product Safety & Compliance Department
Research Triangle Park, North Carolina 27709
(919) 990-7500
MAR 2 19%
MATERIAL SHEET
InforuationTeleep e N.80) 275-6353
Reichhold Chemicals, Inc.
P.O. BOX 13582 ALL CHEMICAL E mGENCIES
P-search Triangle Park, NC 27709 1-600-424-9300
Issue Date: 04-22-96 erg
Page 4
Reichhold's knowledge as of the date hereof; however, Reichhold makes no
representation as to its cc=qpleteness or accuracy. Customers are encouraged
to make their own determination as to the suitability of this product for
their purpose prior to use. Reichhold disclaims responsibility to damages of
any kind resulting from the use of this information. THERE ARE NO WARRANTIES
OR REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE
PRODUCT IT DESCRIBES.
Collins & Aikman
Collins & Aikman Products Co.
701 McCullough Drive
P.O. Box 32665
Charlotte, NC 28232
J. D. MOOPE (704) 547-8500
June 27, 1996
Mr. James Coffey
NC Department of Environment, Health, & Natural Resources
Division of Solid Waste Management
Post Office Box 27687
Raleigh, NC 27611
RE: Collins & Aikman Carpet Landfill
Old Fort, McDowell County, Permit No. 56-03
Dear Mr. Coffey:
Writer's Direct Dial
704-548-2030
FAX 704-548-1098
As required by July 1, 1996, attached are the following items which should allow
Collins & Aikman to maintain compliance with the North Carolina Solid Waste
Management rules under 15A NCAC 13B:
1. Carpet Waste TCLP Data
2. Groundwater Compliance Boundary Proposal
3. Water Quality Monitoring Plan
4. Groundwater Modeling Plan
Should you have any questions or need additional information, please do not
hesitate to contact me.
Sincerely
Collins & Aikman Products Co.
UJ D. Moore
Utilities & Environmental Manager
JDM/tgs
Attachments
cc: J. Davis - OF
G. Miller - ALB
Q:\M00RE\LANDFILL.0F
COLLINS & AIKMAN
TCU DATA
WASTE - Representative Samples of all
Automotive Carpet Trim Landfilled
SAMPLE 1 - Moldable Nonwoven
SAMPLE 2 -Barrier Bach
SAMPLE 3 - Polyback
QWDORETOVER
industrial & Environmental Analysts,
TCLP REGULATED
SASE/NEUTRAL/ACID EXTRACTABLES SW-846
IEA Project Number%
IEA Sample Number:
client Name:
client Project I.D.:
Sample Identifications
Matrix:
TCLP Extraction Date:
Number compound
2283-001
9606054
collins & Aikman
Carpet REH
QC Blank(SVB444)
Water
N/A
Inc. (IEA)
METHOD 8270
Date Received: N/A
Date Sampled: N/A
Date Extracted: 06/19/96
Date Analyzed: 06/20/96
Analysis By: Dixon
Dilution Factorsl.0
N.C.
Regulatory Quantitation
Level Limit
(mg/L) (mg/L)
Results
concentration
(mg/L)
1
1,4-Dichlorobenzene
0.7S
0.010
BQL
2
2,4-Dinitrotoluene
0.013
0.010
SQL
3
itexachlorobutadieno
0.05
0.010
BQL
4
Hexachloroethane
0.30
0.010
BQL
5
Total cresol
20
0.010
BQL
6
Hitrobenzene
0.20
0.010
BQL
7
Pentachlorophenol
10
0.050
BQL
B
Pyridine
0.50
0.010
BQL
9
2,4,S-Trichlorophonol
40
0.010
BQL
10
2,4,6-Trichlorophenol
0.20
0.010
SQL
11
Sexachlorobenzene
0.013
0.010
BQL
Comments:
Sample specific quantitation limits may be calculated by multiplying
the quantitation limit by the dilution factor.
BQL Below Quantitation Limit
N/A not A licable
PP
Corresponding Samples: TCLPb17, 9606058-01,-01SPR, -02, -03
Filename: 0620407
FORM N.C. TcLP-8270R Rev. 081892
Industrial & Environmental Analysts,
TCLP REGULATED
BASE/NEUTRAL/ACID EXTRACTABLES SW-846
IEA Project Number:
IEA Sample Number:
Client Name:
Client Project I.D.:
Sample Identification:
Matrix:
TCLP Extraction Date:
Number Compound
2283-001
9606054
Collins & Aikman
Carpet REM
Method Blank(TCLP617)
Leachate
06/14/96
Inc. (IEA)
METHOD 8270
Date Received: N/A
Date Sampled: N/A
Date Extracted: 06/19/96
Date Analyzed: 06/20/96
Analysis By: Dixon
Dilution Factor:1.0
N.C.
Regulatory Quantitation
Level Limit
(mg/L) (mg/L)
Results
Concentration
(mg/L)
1
1,4-Dichlorobenzene
0.75
0.010
0.010
BQL
BQL
2
2,4-Dinitr0toluene
0.013 •.-
0.010
BQL
3
Hexachlorobutadiene
0.05
0.010
BQL
4
Hexachloroethane
0.30
0.010
BQL
5
Total Cresol
20
0.20
0.010
BQL
6
Nitrobenzene
10
0.05o
BQL
7
Pentachlorophenol
0.50
0.010
BQL
B
9
Pyridine
2,4,5-Triehlorophenol
40
0.010
BQL
10
2,4,6-Trichlorophenol
0.20
0.010
0.010
BQL
BQL
11
Hexachlorobenzene
0.013
Comments:
Sample specific quantitation limits may be calculated by multiplying
the quantitation limit by the dilution factor.
BQL a Below quantitation Limit
N/A = Net Applicable
Corresponding Samplea: 9606054-01, -02, -03
FORM N.C. TCLP-8270R Rev. 081892
Industrial & Environmental Analysts,
TCLP REGULATED
BASE/NEUTRAL/ACID EXTRACTABLES SW-846
IEA Project Numbers
IEA Sample Numbers
Client Name:
Client Project Z.D.:
Sample Identification:
Matrix:
TCLP Extraction Date:
Number Compound
2283-001
9606054-01
Collins & Ai)®an
Carpet REM
Moldable Nonwoven
Leachate
06/14/96 -
Inc. (IEA)
METHOD 8270
Date Received: 06/04/96
Date Sampleds 06/03/96
Date Extracted: 06/19/96
Date Analyzed: 06/21/96
Analysis By: Van Lars
Dilution Factor:l.0
N.C.
Regulatory Quantitation
Level Limit
(mg/L) (mg/L)
Results
Concentration
(mg/L)
1
1,4-Dichlorobenzene
0.010
BQL
2
2,4-Dinitrotoluene
00015
0.010
BQL
3
Hexachlorobutadisna
0.05
0.010 -
BQL
4
Hexachloroethane
0.30
0.010
BQL
5
Total Cr6e01
20
0.010
BQL
6
Nitrobenzene
0.20
0.010
0.050
BQL
BQL
7
Pentachlorophenol
10
8
Pyridine
0.50
0.010
BQL
9
2,4,5-Trichlorophenol
40
0.010
BQL
10
2,4,6-Trichlorophenol
0.20
0.010
BQL
11
Hexachlorobenzene
0.013
0.010
BQL
comments:
Sample specific quantLtation limits may
the quantitation limit by the dilution
BQL . Below Quantitation Limit
FORM N.C. TCLP-8270R Rev. 081892
be calculated by multiplying
factor.
Industrial & Environmental Analysts,
TCLP REGULATED
BASE/NEUTRAL/ACID EXTRACTASLES SW-846
IEA Project Number:
IEA Sample Number:
Client Name:
Client Project I.D.:
Sample Identification:
Matrix:
TCLP Extraction Date:
Number Compound
2283-001
9606054-02
Collins & Aikman
Carpet REM
Barrier Back
Leachate
06/14/96
Inc. (IEA)
METHOD 8210
Date Received: 06/04/96
Date Sampled: 06/03/96
Date Extracted: 06/19/96
Date Analyzed: 06/21/96
Analysis By: Van Lare
Dilution ractor:1.0
N.C.
Regulatory Quantitation
Level Limit
(mg/L) (mg/L)
Results
concentration
(mg/L)
1
1,4-Dichlorobenzene
0.75
0.010
0.010
BQL
BQL
2
2,4-Dinitrotoluene
0.013
0.010
BQL
3
Hexachlorobutadiene
0.05
0.010
BQL
4
Hexachloroethane
0.30
0.010
BQL
5
Total Creeol
20
0 20
0.010
BQL
6
Nitrobenzene
10
0.050
BQL
7
Pentachlorophenol
0.50
0.010
BQL
B
9
Pyridine
2,4,5-Trichlorophenol
40
0.010
BQL
BQL
10
2,4,6-Trichlorophenol
0.010
0.010
BQL
11
Hexachlorobenzene
00.20
Comments:
Sample specific quantitation limits may
the quantitation limit by the dilution
BQL = Below Quantitation Limit
FORM N.C. TCLP-827OR Rev. OB1892
be calculated by multiplying
factor.
Industrial 6 Environmental Analysts,
TCLP REGULATED
BASE/NEUTRAL/ACID EXTRACTABLES SW-846
IEA Project Number:
IEA Sample Number:
Cliont Name:
client Project T.D.:
Sample Identification:
Matrix:
TCLP Extraction Date:
Number compound
2283-001
9606054-03
Collins 6 Aikman
Carpet REM
Polyback
Leachate
06/14/96
Inc. (IEA)
METHOD 9270
Date Received: 06/04/96
Date sampled: 06/03/96
Date Extracted: 06/19/96
Date Analyzed: 06/21/96
Analysis By: Van Lare
Dilution Factor: 2.0
N.C.
Regulatory quantitation
Level Limit
(mg/L) (mg/L)
Results
concentration
(mg/L)
0.75
0.010
BQL
1
1,4-Dichlorobenzene
0.013
0.010
BQL
2
2,4-Dinitrotoluene
0.010
BQL
3
Hexachlorobutndiene
0.05
0.010
BQL
4
Hexachloroethane
0.30
0.010
BQL
5
Total Cresol
20
0.20
0.010
BQL
6
Nitrobenzene
10
0.050
BQL
7
Pentachlorophenol
0.50
0.010
BQL
8
Pyridine
40
0.010
BQL
9
2,4,5-Trichlorophenol
0.010
BQL
10
2,4,6-Trichlorophenol
0 20
0.010
BQL
11
Hexachlorobenzene
0.013
comments:
Sample specific quantitation limits may be calculated by multiplying
the quantitation limit by the dilution factor.
BQL = Below Quantitation Limit
Sample was diluted due to the high concentration of non -target compounds present
FORM N.C. TCLP-827OR Rev. 061892
IEA Project No.:
IEA Sample ID:
Date Extracted:
Date Analyzed:
COMPOUND
Industrial 6 Environmental Analysts, Inc. (IEA)
TCLP SEMIVOLATILE MATRIX SPIKE
2283-001
96060S4-0lsPK
06/19/96
06/24/96
Pyridine
1,4-Dichlorobenzene
Total Cresol
Hexachloroethans
Nitrobenzene
Hexachlorobutadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2,4-Di.nitrotoluene
Nexachlorobenzene
Pentachlorophenol
QUAION
SAMPLE
MS
%
LIMIT
LIMIT
CONCENTRATION
REC �
(mB/L)
(m9/L)
0.010
HQL
63
70
0.010
SQL
7S
0.010
SOL
64
0.010
BQL
72
0.010
HQL
72
0.010
BQL
67
0.010
g7
0.010
HQL
67
0.010
BQL
66
0.010
BQL
9
0.050
H QL
comments:
BQL - Below Quantitation Limit
FORM TWASEMMA Rev. 041291
industrial & Environmental Analysta, Inc. (IEA)
Level 2 Metals Results Report
TCLP METALS REGULATED
IEA Project 4: 2253 001
Matrix: EACEATE
rrn Sample #: 960605401
Client Name: Collins &
AikmaA
6104/96
Date Received: 06/04/96
client Proj.
I.D.: CARPET REM
Date Sampled: 06/03/96
06/14/96
Sample
I.D.: M0.LDAHLE
NONWOVEN
TCLP ExtraCtiOn:
N.C.
Regulatory
Quant
Result
Date Date
IEA
Prep
Batch
Level
Limit
( ug/1)
Prepared Analyzed Analyst
Run
Parameter
Method
500
50.0
BQL
06/19/96 06/19/96 JDJ
R6 09 0
06199601E
ARSENIC
SW846 6010
10000
1000
SQL
06/19/96 06/19/96 JDJ
R6090
06199601P
BARIUM
sw846 6018
100
10.0
SQL
06/19/96 06/19/96 JDJ
R6090
06199601P
CADXIUM
Sw846 6010
500
50.0
BQL
06/19/96 06/19/96 JDJ
R6090
06199601E
C8ROKIUM
SW846 6010
500
50.0
BQL
06/19/96 06/19/96 JDJ
R6090
06199601P
LEAD
Sw846 6010
20
2.00
SQL
06/20/96 06/21/96 PW
R6108
06209601E
MERCURY
Sw846 7470
R
500
50.0
BQL
06/19/96 06/19/96 JDJ
R6090
06199601P
SILVE
sw846 6010
Comments:
Industrial & Environmental Analysts, Inc. (IEA)
Level 2 Metals Results Report
TCLP METALS REGULATED
IEA Project $: 2283 001
Matrix:
LEACSATE
ILA Sample t: 960605402
client Nam-: Collins s Aikman
Date Received: 06/04/96
client Proj.
S.D.: CARPET REM
Date Sampled: 06/03/96
06/14/96
Sample
I.D.: BARRIER BACK
TCLP Extraction:
N.C.
Regulatory
Quant
Result
Date
Date
ILA
Prep
Parameter
Method
Level
Limit
( ug/1)
Prepared
Analyzed Analyst
Run
Batch
ARSENIC
SW846 6010
500
50.0
BQL
06/19/96
06/19/96 JDJ
R6090
06199601P
BARIUM
SW846 6010
10000
1000
BQL
06/19/96
06/19/96 :WJ
R6090
R609a
06199601P
06199601P
CADMIUM
SW846 6010
100
10.0
BQL
06/19/96
06/19/96
06/19/96 JDJ
06/19/96 JDJ
R6090
06199601P
CMROMIdx
SW846 6010
500
500
50.0
50.0
BQL
BQL
06/19/96
06/19/96 JDJ
R6 09 0
06199601P
LEAD
SW846 6010
20
2.00
BQL
06/20/96
06/21/96 PW
R6109
06209601H
MERCURY
Sw^846 7470
7740
100
10.0
SQL
06/19/96
06/19/96 MLB
R6077
06199601F
SELENIUM
SWe46
500
50.0
BQL
06/19/96
06/19/96 JDJ
R6090
06199601E
SILVER
5w846 6010
Comments:
Iadustrial & Environmental Analysts, Ino. (IEA)
Level 2 Metale Results Report
TCLP METALS REGULATED
IEA Project $: 2283 001
IEA Sample is 960605403 Matrix: LEACSAT£
client Name: Collins E. Aikman Date Received:
06/04/96
/96
client Proj. S.D.: CARPET REM Date Sampled;
Sample I.D.: POLYBACK TCLP Extraction: 06/14/96
N.C.
Regulatory Quant Result Date Date IEA Prep
Parameter Method Level Limit ( ug/1) Prepared Analyzed Analyst Run Batch
ARSENIC
SW846
6010
500
50.0
BQL
06/19/96
06/19/96
JDJ
BARIUM
SwB46
6010
10000
1000
SQL
06/19/96
06/19/96
JDJ
CADMIUM
SW846
6010
100
10.0
BQL
06/19/96
06/19/96
JDJ
CHROMSUM
sw B46
6010
500
50.0
BQL
06/19/96
06/19/96
JDJ
LEAD
SW846
6010
500
50.0
BQL
06/19/96
06/19/96
JDJ
MERCURY
SW846
7470
20
2.00
BQL
06/20/96
06/21/96
PW
SELENIUM
SW846
7740
100
10.0
BQL
06/19/96
06/19/96
MLB
SILVER
SW846
6010
500
50.0
BQL
06/19/96
06/19/96
JDJ
Comments.
R6090 06199601P
R6090 06199601E
R6090 06199601P
R6090 06199601E
R6090 06199601P
R6108 06209601H
R6077 06199601E
R6090 06199601E
industrial 6 Environmental Analysts, Inc. (IEA)
Level 2 Metals Results Report
PREPARATION BLANKS
ILA Project 0 2283 001
Matrix: LEACEATE
Client Name: Collins s ALkman
client Proj. I.D.: CARPET REM
Sample Number: PBW 06199601E
Quant Result Date Date IEA Prep
parameter Method Limit (ug/l ) Prepared Analyzed Analyst Run Hatch
SELENIUM sw846 7740 10.0 BQL 06/19/96 06/19/96 MLA R5077 06199601E
corresponding samples:
960605401, 960605402, 960605403
Comments:
Industrial 6 Environmental Analysts, Ino. (IEA)
Level 2 Metals Results Report
PREPARATION BLANKS
IEA Project 4: 2283 001
MatriX: LEACEATE
Client D7ame: Collins 6
Alkman
Client Proj. I.D.: CARPET REM
Sample Number: PEW 06199601"
Quant
Result
Date
Date
IEA
Prop
Limit
(ug/1 )
Prepared
Analyzed
Analyst
Run
Batch
Parameter Method
ARSENIC SW846 6010
50.0
BQL
06/19/96
06/19/96
06/19/96
JDJ
JDJ
R6090
R6090
06199601P
06199601P
BARIUM SW846 6010
1000
BQL
06/19/96
06/19/96
06/19/96
TDJ
R6090
06199601P
C ADMIUM SW846 6010
10.0
BQL
SQL
06/19/96
06/19/96
JDJ
R6090
06199601E
CADMIUMH SW846 6010
50.0
50.0
BOL
06/19/96
061
Lr-AD SW846 6010
BQL
06/19/99
06/19/96
JDJ
R6090
06199601P
SILVER sW846 6010
50.0
Corresponding samples:
960605401, 960605402,
960628004
Comments:
960605403, 960628001, 960628002, 960628003,
Industrial E Environmental Analysts, Inc. (IEA)
Level 2 Metals Results Report
PREPARATION BLANKS
IEA Project #: 2283 001
matrix: LEACgATE
Client Name: Collins 6 Ai}�an
Lient Proj. Z.D.: CARPET REM
Sample Number: PBW 06209601E
Quant
arameter method Limit
Result Date Date IEA Prep
(ug/l ) Prepared Anal;-ed_Analyst Run Batch
ERCURY SW846 7470 2.00 SQL 06/20/96 06/21/96 PW
corresponding Samples:
605403, 960628001, 960626002, 96062800 ,
960605401, 960605402, 960
960628004
Comments:
R6108 06209601E
industrial 6 Environmental Analysts, Inc. (IEA)
Level 2 metals Results Report
PREPARATION BLANKS
IEA Project 4: 2283 001
Matrix: LEACHATE
Client Name: .Collins 6 Ai =n
Client Proj. I.D.: CARPET REM
Sample Number: TB617 06199601E
guant Result Date Date IEA Prep
Parameter method Limit (ug/l ) prepared Analyzed Analyst Run Batch
SELENIUM SW846 7740 10.0 SQL 06/19/96 06/19/96 ME R6077 06199601F
corresponding Samples:
960605401, 960605402, 960605403
Comments:
Industrial 6 Environmental Analysts, Inc. (SEA)
Level 2 Metals Results Report
PREPARATION BLANKS
IEA Project #: 2283 001
MatriX: LEACHATE
Client Name: Collins 8 AikZan
Client Proj. I.D.: CARPET REM
Sample Number: TB617 06199601?
Quant Result Date Date IEA Prep
Parameter Method Limit (ug/1 ) Prepared Analyzed Analyst Run Batch
ARSENIC
SW846
6010
50.0
339L
06/19/96
06/19/96
JD-7
R6090
R6090
06199so1P
06199601P
BARIUM
SW846
6010
1000
BQL
06/19/96
06/19/96
06/19/96
06/19/96
JDJ
JDJ
R6090
06199601P
cADMiuM
SW846
6010
10.0
50.0
BQL
BQL
06/19/96
06/19/96
JDJ
R6 09 0
06199601P
CHROMIUM
SW846
6010
50.0
SQL
06/19/96
06/19/96
JDJ
R6090
06199601P
*,Ep,D
SW846
6010
BQL
06/19/96
06/19/96
JDJ
R6090
06199601P
SILVER
SW846
6010
50.0
Corresponding Samples:
960605401, 960605402,
960628004
Comments:
960605403, 960628001, 960628002, 960628003,
Industrial a Environmental Analysts, Inc. (TEA)
Level 2 Metals Results Report
PREPARATION BLANKS
TEA project #r: 2283 001
matrix; LEACIMTE
Client Name: Collins 6 Ai)Onan
client Proj. T.D.: CARPET REM
Sample Number: TB617 06209601H
Quant Result Date Date IEA Prep
Parameter Method Limit (ug/l ) Prepared Analyzed Analyst Run Batch
y,ERCURy sw646 7470 2.00 BQL 06/20/96 06/21/96 PW
corresponding samples:
960605481, 960605402, 960605403, 960628001, 960628002, 960628003,
960628004
coamients :
R6108 06209601H
Industrial s Environmental analysts, Inc. (IFIL)
Level 2 Metals Reeultc Report
MATRIX SPIRE RESULTS
IEA project $:
2283
001
IEA Sample $:
960605402
Matrix:
LEACEATE
Matrix Spike
Results
( u4/1)
Spike
Date
Samp
SA
SR
SSR
%RCY
Analyzed
Run
Run
parameter
Method
556.
BQL
437.
78.6
06/19/96
R6090
R6090
ARSENIC
sw846
6010
11100
SQL
9130
82.1
06/19/96
R6090
R6090
BARIUM
SW846
6010
111.
BQL
88.2
79.3
06/19/96
R6090
R6090
CADMIUM
SW846
6010
556,
SQL
429.
77.2
06/19/96
R6090
R6090
CEROMIUM
SW846
6010
SQL
412.
74.2
06/19/96
R6090
R6090
LEAD
SW846
6010
556.
20.0
BQL
11.4
53.0
06/21/96
R6108
R6108
MERCURY
Sw846
7470
111.
SOL
64.4
76.0
06/19/96
R6077
R6077
SELENIUM
Sw846
7740
556.
BQL
444.
79.9
06/19/96
R6090
R6090
SILVER
SW846
6010
2R = ((SSR - SR) / SA) * 100
corresponding Samples'
960605401, 960605402, 960605403, 960628001, 960626002, 960628003,
960628004
Comments:
Yutg, inc.
industrial
TCLp/2FMEnvironmental
GC/MSI(IEA)
PORGEABLES
SW-846 METHOD 8240
IF
A Project Numbers
IEA Sample Number;
Client Name;
Client Project I.D.;
Sample Identifications
Matrix;
TCLP Extraction Date;
Number
1
2
3
4
5
6
7
8
9
10
Compound
2253-001
9606054-01
Collins G &L3amn
Carpet Rem
Moldable Nonwoven
Leachate
06/14/96
N.C.
Regulatory
Level
(mg/L)
Data Received% 06/04/96
Date Sampled: 06/03/96
Data Analyzadz 06/25/96
Analysis Byz Moore
Dilution Pactorz 2.5
QuantitationResults
Limit concentration
(mg/L) (mg/L)
0.05
0.010
BQL
Benzene
20
0.020
BQL
2-r05
Carbbonon tetrachloride
e
0.
0.010
BQL
BQL
10
0.010
Chlorobenzene
0.60
0.010
BQL
Chloroform
0.05
0.010
BQL
1,2-Dichloroethane
0.07
0.010
BQL
1,1-Dichloroethene
0.07
0.010
BQL
Tetrachloroethene
0.010
BQL
Trichloroethene
0.05
0.020
BQL
Vinyl chloride
0.02
Comments:
Samplespecificquern ittbyiton heldilutionimits yfactorbe calculated by multiplying
the qu i
BQL = Below Quantitation Limit
Sample diluted to prevent execs give foam while purging.
FORM NC-TS24R Rev. 041895
Industrial & Environmentai Analysts, Inc. (SEA)
TCLP/EHE REGULATED GC/MS PURGEABLES
sw-846 METHOD 8240
IEA Project Number:
IEA sample Number:
client Name:
client Project I.D.:
sample identification:
Matrix:
TCLP Extraction Date:
Number
1
2
3
4
5
6
7
8
9
10
compound
2283-001
9606054-02
Collins & Aikman
carpet Rem
Barrier Back
Leachate
06/14/96
N.C.
Regulatory
Level
(mg/L)
Date Received:
06/04/96
Date Sampled:
06/03/96
Date Analyzed:
06/25/96
Analysis By:
Moore
Dilution Factors i.o
Quantitation
Results
Limit
Concentration
(mg/L)
(mg/L)
0.05
0.010
BQL
Benzene
20
0.020
BQL
2-Butanone
Carbon tetrachloride
0.05
0.010
BQL
BQL
10
0.010
Chlorobenzene
0.60
0.010
SQL
Chloroform
0.05
0.010
BQL
1,2-DLchloroethane
0.07
0.030
BQL
1,1-Dichloroethene
0.010
BQL
Tetrachloroethene
0.07
0.010
BQL
Trichloroethene
0.05
0.020
BQL
Vinyl chloride
0.02
Comments:
Sample specific quantitation limits may be calculated by multiplying
the guantitation limit by the dilution factor.
BQL =' Below Quantitation Limit
FORM NC-T824R Rev. 041895
ystaf 'no*
IndustTCLP/ZHEnREGULATEDaGC/MS IPDRGEABLES ( )
SW-846 METHOD 8240
IEA Project Numbers
IEA sample Number:
Client Name:
Client project I.D.:
Sample Identification:
Matrix:
TCLP Extraction Dates
Number Compound
2283-001
9606054-03
Collins 4 Ai3cman
Carpet Rem
polyback
Leachate
06/14/96
N.C.
Regulatory
Level
(mg/L)
Data Received: 06/04/96
Date Sampled: 06/03/96
Date Analyzed: 06/25/96
Analysis By: Moore.
Dilution Factors 5.0
QuantitationResults
Limit Concentration
(mg/L) (mg/L)
0.05
0.010
BQL
l
Benzene
20
0.020
BQL
2
3
2-Butanone
Carbon tetrachloride
0.05
0.010
BQL
BQL
10
0.010
4
chlorobenzene
0.60
0.010
BQL
5
Chloroform
0,05
0.010
BQL
6
1,2-Dichloroethane
0 07
0.010
BQL
7
1,1-Dichloroethene
0.010
BQL
g
Tetrachloroethens
0.07
0.010
BQL
9
Trichloroethene
0.0
0.010
BQL
10
Vinyl chloride
0.05
Comments:
Sample specific quantitatiolimits may
yon fbe calculated by multiplying
the quantitation limit by the
dilutBQL . Below Quantitation Limit
sample diluted to prevent excessive foam while purging-
FORM NC-T824R Rev. 041895
Industrial & Environmental Analyste, Inc. (IEA)
TCLP/ZEES REGULATED GCIMS PURGEABLES
SW-846 METHOD 8240
IEA Project Numbers
IEA Sample Number:
Client Name:
client Project I.D.:
Sample Identification:
Matrix:
TCLP Extraction Date:
Number
1
2
3
4
5
6
7
8
9
10
Compound
2283-001
960640S-01
Collins B AiEman
Carpet Rem
ZHE. BLK 771
Leachate
06/14/96
N.C.
Regulatory
Level
(mg/L)
Date ROCeived: N/A
Date Sampled: N/A
Date Analyzed: 06/20/96
Analysis By: Moore 1.0
Dilution Factor:
Quantitation Results
Limit Concentration
(mg/L) (mg/L)
0.05
0.010
BQL
Benzene
20
0.020
BQL
2-Butanone
Carbon tetrachloride
0.05
0.010
BQL
BQL
10
0.010
Chlorobenzene
0.60
0.010
QL
Chloroform
p.05
0.010BQL
1,2-Dichloroethane
0.010
BQL
1,1-D1chloroethene
0.0
0.010
BQL
Tetrachloroethene
0.07
0.010
BQL
Trichloroethene
0.05
0.020
BQL
Vinyl chloride
0.02
comments:
Sample specific guantitatiolimits may
the quantitation limit by the
diluton
BQL _ Below Quantitation Limit
N/A a Not Applicable
Correeponding.Samploei 9606054-01, 02,
Filename: 0620111
FORM NC-T824R Rev. 041895
be calculated by multiplying
factor.
03
Industrial & Environmental Analysts, Inc. (IEA)
TCLP/SHE REGULATED GC/MS PDRGEABLES
SW-846 METHOD 8240
IEA project Number:
IEA Sample Number:
client Names
Client Project I.D.:
sample Identification:
Matrix:
TCLP Extraction Dates
Number Compound
2283-001
9606054
Collins & Aikman
carpet Rem
QC Blank (VBL&SY)
Water
N/A
N.C.
Regulatory
Leval
(mg/L)
Date Received: N/A
Date Sampled: N/A
Date Analyzed: 06/25/96
Analysis By: Moore
Dilution Factor: 1.0
Quantitation Results
Limit Concentration
(mg/L) ' (mg/L)
0.05
0.010
BQL
1
Benzene
20
0.020
BQL
2
3
2-Butanone
Carbon tetrachloride
0.05
0.010
BQL
BQL
10
0.010
4
Chlorobenzens
0.60
0.010
BQL
5
Chloroform
0.05
0.010
BQL
6
1,2-DLchloroethane
0.07
0.010
BQL
7
1,1-Dichloroethene
0.010
BQL
e
Tetrachloroethene
0.07
0.010
BQL
9
Trichloroethene
0.05
0.020
BQL
10
vinyl chloride
0.02
Comments:
sample specific quantitation limits may be calculated by multiplying
the quantitation limit by the dilution factor.
BQL Below Quantitation Limit
N/A Not Applicable
Corresponding samples: 9606054-01, 02
Filename: 0625502
FORM NC-T824R Rev. 041895
Ysto, inc.
IndustTCLP/ZHEnREG�TEDaGC/MSIPDRGEABLES (IEA)
sw-846 METHOD 8240
IEA project Number:
IEA Sample Number:
Client Names
Client Project I.D.:
Sample Identification:
Matrix:
TCLP Extraction Date:
Number Compound
2283-DO1
9606054
Collins a Aikman
Carpet Rem
QC Blank (VBLKKB)
water
N/A
N.C.
Regulatory
Level
(mg/L)
Date Received: N/A
Date Sampled: N/A
Date Analyzed: 06/25/96
Analysis By: Moore
Dilution Factor: 1.0
quantitation Results
Limit Concentration
(mg/L) (mg/L)
0.05
0.010
BQL
1
Benzene
20
o.020
BQL
2
3
2-Butanone
Carbon tetrachloride
0•05
0.010
BQL
BQL
0.010
4
chlorobenzene
0. 60
0.010
BQL
5
Chloroform
0.60
0.010
BQL
6
1,2-D ichloroethane
0.07
0.010
BQL
7
1,1-Dichloroethene
0.010
BQL
e
Tetrachloroethene
0.07
0.010
BQL
9
Trichloroethene
0.05
0.02
0.020
BQL
10
Vinyl chloride
Comments:
Sample Specific quantitation limits may
the quantitation limit by the dilution
BQL Below Quantitation Limit
N/A Not Applicable
Corresponding Samples: 9606054-03
Filename: 062sK02
FORM NC-T824R Rev. 041895
be calculated by multiplying
factor.
Industrial & Environmental Analyeta, Inc. (IEA)
TCLP/ZAE REGULATED GC/MS PURGEABLES
SW-646 METHOD 8240
IEA Project Number:
SEA Sample Number:
Client Name:
client Project I.D.:
Sample Identifications
Matrix:
TCLP Extraction Dates
Number Compound
2283-001
9606054
Collins & Aikman
Carpet Rem
QC Blank (V13L&5Z)
water
N/A
1
Benzene
2
2-Butanone
3
carbon tetrachloride
4
Chlorobenzene
5
chloroform
6
1,2-Dichloroathane
7
1,1-Dichloroethene
8
Tetrachloroethene
9
Trichloroethene
10
vinyl chloride
N.C.
Regulatory
Level
(mg/L)
Date Received: N/A
Date Sampled: N/A
Date Analyzed: 06/25/96
Analysis Sys Collins
Dilution Factors 1.0
Quantitation Results
Limit Concentration
(mg/L) (mg/L)
0.05
0.010
BQL
20
0.020
BQL
0.05
0.010
BQL
10
0.010
BQL
0.60
0.010
BQL
0.05
0.010
BQL
0.07
0.010
BQL
0.07
0.010
BQL
0.05
0.010
BQL
0.02
0.020
BQL
comments:
Sample specific quantitation limits may
the quantitation limit by the dilution
BQL Below Quantitation Limit
N/A a Not Applicable
corresponding Samples: 9606054-OILS
Filename: 0625E03
FORK NC-TS24R Rev. 041895
be calculated by multiplying
factor.
Industrial & Environmental Analysts, Inc. (IEA)
TCLP/ZHE REGULATED GC/MS PURGEABLES
SW-946 METHOD 8240
IEA project Number:
IEA sample Number=
Client Name:
Client Project I.D.:
Sample Identifications
Matrix:
TCLP Extraction Date:
Number compound
2283-001
9606054
Colline 6 Aikman
Carpet Rem
QC Blank (VBLKTF)
Water
N/A
1
Benzene
2
3
2-Butanone
carbon tetrachloride
4
chlorobenzene
5
chloroform
6
1,2-Dichloroethane
7
1,1-Dichloroethene
8
Tetrachloroethene
9
Trichloroethene
10
Vinyl chloride
N.C.
Regulatory
Level
(mg/L)
Date Received: N/A
Date Sampled: N/A
Date Analyzedx 06/20/96
Analysis Bys Moore i.o
Dilution Factor:
Quantitation Results
Limit Concentration
(mg/L) (mg/L)
0.05
0.010
BQL
20
0.020
BQL
0.05
0.010
BQL
10
0.010
BQL
0.60
0.010
BQL
0.05
0.010
BQL
0.07
0.010
BQL
0.07
0.010
BQL
0.05
0.010
BQL
0.02
0.020
BQL
co=eats:
sample specific quantitation limits may
the gyantitation limit by the dilution
BQL . Below Quantitation Limit
N/A - Not Applicable
corresponding sample" ZHE BLK 771
Filename: 0620104
FORM Nc-T824R Rev. 041895
be calculated by multiplying
factor.
IndustrialTaEnvironmental hnalRIXSPII� Inc. (IEA)
IEA Project No.:
IEA Sample -ID:
sample Identification:
Analysis Date:
Benzene
2-Butanone
Carbon tetrachloride
Chlorobenzene
chloroform
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroathene
vinyl chloride
Comments:
2263-001
9606054-OILS
Moldable Nonwoven
06/26/96
QOANTITATION SAMPLE
LIMIT CONCENTRATION
(mg/L) (mg/L) REC #
0.010
BQL
66
75
0.020
BQL
>100
0.010
BQL
92
0.010
BQL
90
0.010
BQL
BS
0.010
BQL
93
0.010
BQL
90
0.010
BQL
90
0.010
BQL
92
0.020
BQL
BQL . Below Quantitation Limit
Corresponding Samples: 9606054-01, 02, 03
FORM TWAVOLMA Rev. 051691
NC DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES
Division of Solid Waste Management
Solid Waste Section
SOLID WASTE MANAGEMENT FACILITY EVALUATION REPORT
Type of Facility Pewit I Canty
Name of Facility Location
Date of Last Evaluation
1. Penit Conditions Followed Yes No N/A
A_ Specific Condition(s) Violated
11. Operational Requirements Followed Yes No
15A N.C. Admin. Code 13B Section
A. Specific Violations) by number and letter.
III. Other Violations of Rule or Law
IV. Evaluator's Conrnts
V. Contination Page Required? Yes _No Receiving Signature
Evaluation Date Solid Waste Section "
DEHNR 3793 (Part I White: Facility Part II Canary: Central Office Part III Pink: Regional Office)
Solid Waste Section (Review 7/94)
NC DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES
Division of Solid Haste Nanagarent
Solid taste Section
SOLID WASTE NANAGE)ENT FACILITY EVALUATION REPORT
Type of Facility Permit 9 County.
Name of Facility Location
Date of Last Evaluation
I. Permit Conditions Followed Yes No N/A
A. Specific Condition(s) Violated
II. Operational Requirements Followed Yes No
15A N.C. Admin. Code 13B Section
A. Specific Violations) by maber and letter.
III. Other Violations of Rule or Law
IV. Evaluator's
V. Contimation Page Re¢niredT _Yes _No Receiving signature
Evaluation Date Solid Haste Section
DEHNR 3793 (Part I White; Facility Part II Canary: Central Office Part III Pink: Regional Office)
Solid haste Section (Review 7/94)