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HomeMy WebLinkAbout8606_Surry_Lined_MSWLF_June21GW_FID1619786_20211020DNLY ❑ Paper Report ❑ Electronic Data - Email CD (data loaded: Yes / No NC DENR Division of Waste Management - Solid Waste Doc/Event #: Environmental Monitoring Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646-"flail Service Center, Raleigh, NC 27699-1646. S�tid Waste:Monitoring Data Submittal Information -. Name of entity submitting data (laboratory, consultant, facility owner). Municipal Engineering Services Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl E-mail: jpfohl@mesco.com Facility name: Surry County Closed C&� and Closed MSW Landfill -Mt. Airy Facility Address: '237 Landfill Road �;Mt. �ciry, NC 27030 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring � Detection Monitoring T e of data submitted: (Check all that apply) X Groundwater monitoring data from monitoring wells X Groundwater monitoring data -from private water supply wells Leachate monitoring data X Surface water monitoring data Notification attached? Phone: (919)772-5393 Facility Permit # NC Landfill Rule (.0500 or .1600) 1600 ® Assessment Monitoring Methane gas monitoring data Corrective action data (specify} Other(specify) Actual sampling dates (e.g., October 2Q-24, 2006) I,June 23-25, 2021 Corrective Action MNA parameters on 7 wells I_ No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC ZL groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification - To the best of_my knowledge, the information reported and statements made on this data submittal and attachments aro true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. S.J. Zimmerman, P.G. Project Manager (919) 772-5393 Fac�RepresenQ Name (Print) Title (Area Code) Telephorre Number Signatlur/i V P.O. BOX 97, Garner, NC 27529 Facility Representative Address C-0281 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 o / Z,D � Date Affix NC Licensed/ Professional Geologist Seal ti toAft b os- Of to V to of P of of Nor -- '��ar� 11 I I � � / � 1 I 1 ! ' � 1 Senior Project Manager .com June 2021 Prepared for Surry County Lined Landfill Mt. Airy, North Carolina '- • :• 1• P�epa�ed by Municipal Engineering Services Company, P.A. • :• • Garner, North Carolina MESCO Project Number: G21031.0 �q,®��,;��,�R�t� t rrs �yP�,�� ., �� �_ - k '� '- J /�l r ,ti � p r } t �� ;� f_ _X � �,, � �� � .. - . _ �•..n. �_ �6�5-,� F,�= .«� N�UNICIPAI` ENGINEE.�ING S ER�I C ES C D Iyi P�►N�� P.�.� 68 SHIPWASH DRIVE, GAi7h1ER, NC 27529 • PH4IMiEi 9l �3-772�5393 P.O. Box 349} BOONE, NC 28607 -PHONES 8�8-262-i 767 Jonathan Pfohl Environmental Specialist juf�,mesco. com LICENSE NUMBER: C-02B� Introduction On behalf of Surry County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi - Annual Water Quality Monitoring Report for an event performed at the Surry County Lined Municipal Solid Waste Landfill (MSWLF) in the last Spring of 2021. NCDEQ Solid Waste Rules 15A NCAC 1313.1632 requires that Surry County provide this report to the SWS on a semi-annual basis. This report documents the quality of the ground and surface waters during a monitoring event performed between June 22-25, 2021. During this event one to two constituents were detected above allowable regulatory compliance levels in samples collected from MW-6R and MW-9S. Surface water samples did not contain constituents in levels above applicable 2B Standards. The leachate samples continue to contain a few contaminants but concentrations were low relative to Standards and published values. Background The Surry County Subtitle D lined MSWLF, permit #86-06, is located at 237 Landfill Road, Mount Airy, Surry County, North Carolina. The site location topographic map is depicted in the attached Sheet 1. The lined MSWLF is comprised of contiguous Phases 1-4 which are treated as a single unit in this report. Water quality at this facility has been monitored at least semi-annually since 1998 with all historical data reviewed in support of this report. This event was performed in accordance with the NC SWS rules/regulations as promulgated in 15ANCAC 13B and as a condition of the permit to operate. Assessment monitoring was initiated site -wide in response to detections of volatile organic compounds (VOCs) above allowable Standards in samples collected from MW-2, MW-6R and MW-9S in the spring of 2016. Assessment monitoring of MW-2, MW-6R and MW-9S and landfill gas monitoring of MGP-5 and MGP-12 continued during this event as approved by NCDEQ. An Alternative Source Demonstration Addendum (ASD-Add) which established Site Maximum Allowable Contaminate (SMAC) regulatory compliance levels for three metals (cadmium, cobalt, vanadium) was approved by the NCDEQ on April 20, 2020 (FID:1395468). As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water characterization. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedure MESCO personnel performed this sampling event using portable monitoring methodology in general accordance with the site -specific Water Quality Monitoring Plan dated July 12, 2018 (DIN:1234484) which was approved by the NC SWS on August 8, 2018 (DIN:1235187). Water samples were collected from 16 downgradient groundwater monitoring wells (MW-2, MW-3R, MW-4S, MW-4D, MW-5, MW-6R, MW-8, MW-9S, MW-9D, MW-10, MW-115, MW-11D, MW-12, MW-24, MW-25 and MW-26), one background well (MW-1), four downstream surface water locations (SW-4 , SWN-2, SW-C and SW-D), four upstream surface water points (SWN-1, SW-1, SW-2 and SW-3) and a raw leachate sample (LAGOON). Quality control (QC) measures included analysis of equipment blanks (EB) and field blanks (FB). MW-13 was not sampled since it was dry. Sampling locations are shown on the potentiometric map (Sheet 2). A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Submersible pumping methodology or bailing was utilized to purge the wells to a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from the Stoney Creek discharge feature at previously designated locations. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre -preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper C-O-C protocols within the specified hold times for each analysis. Field Parameter Data Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature, and turbidity. A summary of the field parameter data is presented as Table 3 and the field sampling data sheet is enclosed in Appendix A. Laboratory Results Pace Analytical Services, Inc. (PACE) performed the laboratory analysis of the water and leachate samples. Pace reported that their procedures conformed to the most current, applicable TNI/NELAC standards and their Quality Assurance Manual, where applicable, unless otherwise noted in the body of the laboratory report. Groundwater sample MW-6R was tested for mercury, and Appendix lI constituents, since Mercury was detected during the previous event. Assessment monitoring continued at MW-10 in response to benzene violations and was tested for constituents listed in 40 CFR 258 Appendix II and 1,4-dioxane. The other groundwater and surface water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4-dioxane. Untreated leachate was tested for the specific parameters required by the SWS which includes Appendix I constituents, phosphorous, BOD, COD, sulfide and nitrate. A sampling and analysis table summarizing the locations, constituents and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix B. Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value between the MDL and laboratory -established Reporting Limit (RL) is qualified by the laboratory as an estimated concentration hence qualified with a "J". Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. Table 5 summarizes constituents detected in groundwater, leachate and quality control samples compared to regulatory groundwater compliance standards which include Interim Maximum Allowable Concentrations (IMAC), Site Maximum Allowable Concentrations (SMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared with the NC Division of Water Resources "Surface Water Quality Standards, Criteria & Protected Values", modified July 26, 2021. Quality Control Samples Methylene chloride and zinc were detected in the quality control blanks (EB, FB). Since these constituents were not detected in any other samples above allowable levels the identified artifact contaminant is largely inconsequential. Groundwater Sample Exceedances Metals Total cobalt was detected in sample MW-9S at 78.1 ug/L which is above its SMAC of 11 ug/L. Volatile Organic Compounds The VOCs vinyl chloride 1.9 ug/L (2L=0.3 ug/L) and benzene 3 ug/L / (2L=1.0 ug/L), were detected in sample MW- 6R above their respective NC 2L Standard. Surface Water Samples Detected Above Standards Contaminants were not detected above established Surface Water Standards in NC 213, in any of the surface water samples associated with the lined landfill. Pa Leachate Samples Raw leachate samples contained concentrations of cobalt 56 ug/L above its SMAC Value 11 ug/L. Contaminant concentrations in leachate remain low relative to Standards applicable to ground and surface waters and values published from similar MSWLF's which is consistent with previous observations. Groundwater and Surface Water Characterization A potentiometric map of the uppermost aquifer constructed from groundwater elevation data recorded during this monitoring event is on Sheet 2. Groundwater flow rates and directions were calculated and are included in the hydrologic properties table (Table 7). Groundwater flow directions remain generally in a southerly direction towards the Ararat River with groundwater velocities calculated by the modified Darcy's equation varying considerably due to the anisotropic geologic conditions. Streams located within the facility boundaries were observed to be of moderate volume and flow with low turbidity. Findings Groundwater near MW-6R continues to be impacted with levels of benzene and vinyl chloride remaining within their historically identified range. MW-6R is located approximately 100 feet downgradient of the Phase 2 liner and within the compliance boundary. The portion of the aquifer impacted is believed to be small as evidenced by lack of detections in MW-8 located along the downgradient flow path. The active LFG extraction system has been expanded proximal to MW-6R and is expected to operate indefinitely which may mitigate potential groundwater impacts. Interpretation of results of surface water samples collected along Stoney Creek and the Ararat River, including those instituted directly downgradient of MW-6R, continue to indicate the local discharge features remain unimpaired. Samples collected from MW-9S continues to contain cobalt above allowable levels but remain within their their historically identified range. Cobalt is likely a product from dissolution from the soil in response to changes in the geochemistry from a past release. Benzene levels have fallen below NC 2L Standards in samples collected from MW-10. A low non -quantifiable concentration of mercury was the lone parameter detected in sample MW-10 which is listed in Appendix II but not also listed in Appendix I. MW-13 was damaged during Phase 4 construction. MW-13 was repaired and datum elevation resurveyed on October 5, 2020. Following construction of Phase 4 water levels have fallen and turbidity levels have risen in MW-13, when water is present. If MW-13 remains consistently dry or does not yield representative samples it should be replaced. Closing Water quality and LFG monitoring are scheduled to be performed again in fall of 2021. It is recommended that samples collected from MW-6R, MW-9S and MW-10 continue to be tested for Appendix II constituents annually with any detections targeted the following event. This marks the first event that waste has been placed in Phase 4, therefore prior to this event water quality data from MW-24 through MW-28 should be considered background. Sheets Topographic Map with Site Location Surry County Landfill, Mt. Airy fl 237 Landfill Road Mount Airy, NC 28621 Lat: 36-26-30.065 Long:-80-34-15.314 Northing:983356.18 Easting:1537885.48 0 Surry Co Property Line O Closed Unlined C&D Landfill O Closed Unlined Sanitary Landfill O Active Lined MSW Landfill SHEET 1 °so OWNED BY SURRY \ COUNTY >>oo wVVIIf-« MW-1 °= GWE=1065.42 OW4-6' o� R� - 1700 - LINED PHASE 4 j IN OPERATION / WASTE ENCOMPASSES <1 ACRE NE QUANDRANT 4 !)Wd_99'� MW--27 11 GWE=1010.55 -A /// / / MW_-26 GWE=970.44 MW-25 p 11=962.35 OW44D My ,0�0 W--24 '----- GW 41.07 � NOW OR FORMERLY OWNED BY JOHNNY COX OW4-7�- , yy - MW-28 GWE=1013.02 i V • i � / � \� 0 MWL-A INACTIVE LINED°- ° PHASE 1 / PTO 12/1 /98 100 � � 1 0 99 ACTIVE LFG EXTRACTION �.! ACTIVE LINED -� PHASE 2 PTO 11 /20/09 P2-11D v o� P2-11 S P-10 - _ - MW-12 - - -_ ---- GWE=944.11 \ P2-12 � M M GV � MW-11D*•MW-11S 940 GWE=933.26 GWE=938.22 n//W--10 - - GWE=942.74 g _ �MG � 30 • -- -- 920MW-9D* MW-9S GWE=917.12 GWE=917.78 ow 0-0-P4 ` OWN-� A�RAT VER , MW-13 GWE=<943.33 SW-2 (1000' FURTHER UPSTREAM) sw' I ) J� I I r � I / SW-3 II ' � A \ STONEY CREEK--------------- - - 950 - o , 110� SW-4 -- -,nc 105° GOON tk0 MW-4 Oj �G WE=934.63 MW--2 , � IMW-4D* GWE 922.9E � 93( yG WE=935.89 ' S • . y MW-3R . MW_5 SW-C GWE=925.10_2_� GWE=935.43 IIGP-5 m 0 'Jll W-6R VE=939.85 MW-6R MW--8 Vinyl Chloride- 1.9 ug/L GWE=912.13 SW Benzene- 3 ug/ ��. SWN-2 SO THE RN I�RO AD RA SW-D OWNED BY SURRY COUNTY CLOSED C&D OVER CLOSED MSW STOPPED RECEIVING C&D BEFORE JUNE 1, 2008 / STOPPED RECEIVING MSW BY JAN. 1, 1999 pROp FRTy<�N� P RTY LINE NOW OR FORMERLY OWNED BY SHAWNA SUMMERS LEGEND ---------------- ESTIMATED WASTE LIMITS UNLINED LANDFILL WASTE LIMITS OF LINED LANDFILL FACILITY OUTERMOST PROPERTY BOUNDARY TOPOGRAPHIC CONTOURS -EXISTING RELATIVE GROUNDWATER COMPLIANCE BOUNDARY RAILROAD o� OBSERVATION WELL nn� MONITORING WELL LANDFILL GAS MONITORING WELL ROADS STREAM/CREEK sw SURFACE WATER SAMPLING LOCATION 960 EQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOUR (June 21-22, 2021) GROUNDWATER POTENTIOMETRIC ELEVATION GWE = 941.66 POTENTIOMETRIC ELEVATION NOT USED FOR CONTOURING *M W- 1 _ I _ I GRAPE11C SCALE 200 o 100 200 400 ( IN FEET ) 800 SHEET 2 C7 Eyl Z � N t0 C` I IT N 0 0)>= � W W zm N Z ❑ a W o 00 �17 a 0) = a N 1�1 Z � N `� 0 U w W O N U 0 00 Co 2 C] Z N U Z J �ZW W Z Ln IIIU] <ZW Q w ❑ Z U (LW W ❑J m U 0 Z 1 1 En Q N ❑ m W EL =° rn ca a i U a CL 1� U = LU � 0 Q 0 � 0 CL W >- CIL Q CIL � � LU 0 m ? 0 SCALE: SEE SCALE BAR DATE: 10117121 DRWN. BY: J. PFOHL CHKD. BY: J.PFOHL PROJECT NUMBER G21025.0 DRAWING NO. SHEET NO. SHEET 2 1 OF 1 Tables Table 1 Groundwater Monitoring Well Construction Table June 21-23, 2021 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 8/14/98 2 68.5 53.5 15 Rock 1127.02 1124.23 1065.42 61.60 36.434494 -80.577989 MW-2 8/16/98 2 23.5 8.5 15 Rock 936.68 933.91 922.96 13.72 36.430833 -80.571161 MW-3R 12/2/98 2 20 5 15 Rock 930.00 928.15 925.10 4.90 36.430714 -80.571575 MW-4S 8/11/98 2 20 5 15 Saprolite 943.23 940.31 934.63 8.60 36.430853 -80.572400 MW-4D 8/11/98 2 45 35 10 Rock 942.80 940.31 935.89 6.91 36.430853 -80.572400 MW-5 8/18/98 2 47.5 32.5 15 Rock 977.93 971.57 935.43 42.50 36.430356 -80.572961 MW-6R 3/22/99 2 79 64 15 Fractured Rock 1004.75 1001.81 939.85 64.90 36.429958 -80.573508 MW-8 9/1/09 2 70.75 55.75 15 Fractured Rock 971.03 968.35 912.13 58.90 36.429283 -80.573453 MW-9S 6/16/06 2 42.28 27.28 15 Fractured Rock 952.83 949.75 917.78 35.05 36.429314 -80.574464 MW-9D 6/16/06 2 65.54 55.54 10 Competent Rock 952.47 949.49 917.12 35.35 36.429314 -80.574464 MW-10 6/16/06 2 47.13 27.13 20 Fractured Rock 970.24 967.35 942.74 27.50 36.429519 -80.575486 MW-11S 9/3/09 2 46.05 31.05 15 Competent Rock 969.09 965.95 938.22 30.87 36.430197 -80.577131 MW-11D 9/3/09 2 65.31 55.31 10 Competent Rock 965.38 962.38 933.28 32.10 36.430197 -80.577131 MW-12 9/4/09 2 65 50 15 Competent Rock 996.66 993.71 944.11 52.55 36.429831 -80.576750 MW-13 9/3/09 2 36.31 21.31 15 Fractured Rock 983.84 979.64 <943.33 Dry 36.430625 -80.578531 MW-24 1/27/15 2 38.78 28.78 10 Competent Rock 979.72 976.72 941.07 38.65 36.430707 -80.579134 1/24/15 2 71 56 15 Competent Rock 989.85 986.85 962.35 27.50 36.431058 -80.579869 1/25/15 2 45.26 30.26 15 Competent Rock 999.04 99604 97044 2860 36431476 -80580518 rW2 1/22/15 2 53.07 38.07 15 Competent Rock 1043.01 1040.01 1010.55 32.46 36.432314 -80.580081 1/28/15 1 2 1 80.48 1 65.48 1 15 1 Competent Rock 1 1077.41 1 1074.41 1 1012.27 1 65.14 1 36.433712 1 -80.575106 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) Slurry County Lined Landfill Page 1 of 1 Table 2 Field Observations of Monitoring Locations June 21-24, 2021 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked on Arrival & Departure Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears Effective Comments MW-1 Yes Yes Yes Yes Yes Yes Background Well MW-2 Yes Yes Yes Yes Yes Yes MW-3R Yes Yes Yes Yes Yes Yes MW-4S Yes Yes Yes Yes Yes Yes MW-4D Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes MW-6R Yes Yes Yes Yes Yes Yes County improved surface seal in September 2013 MW-8 Yes Yes Yes Yes Yes Yes MW-9S Yes Yes Yes Yes Yes Yes MW-9D Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11S Yes Yes Yes Yes Yes Yes MW-11D Yes Yes Yes Yes Yes Yes MW-12 Yes Yes Yes Yes Yes Yes MW-13 No Yes Yes Yes Yes ? Repaired by JR Lynch (Contractor). Dry MW-24 Yes Yes Yes Yes Yes Yes MW-25 Yes Yes Yes Yes Yes Yes MW-26 Yes Yes Yes Yes Yes Yes MW-27 Yes Yes Yes Yes Yes Yes MW-28 Yes Yes Yes Yes Yes Yes SW-1 Yes Moderate gage height & flow SW-2 Yes Moderate gage height & flow SW-3 Yes Moderate gage height & flow SWN-1 Yes Moderate gage height & flow SWN-2 Yes Moderate gage height & flow SW-C Yes Moderate gage height & flow SW-D Yes Moderate gage height & flow LAGOON Yes Yes Yes Sample from invert which is typical Any unusual field conditions, observations, or events: Phase 2 has an earthen berm built Win liner limits which may reduce any potential for overland flow from Phase 2. Paths leading to wells and around entire facility have been maintained by County. All are 4X4 accessible. Co performed well maintenance by pouring new concrete pads around several wells in the Fall of 2017. Slurry County Lined Landfill Page 1 of 1 Table 3 Hydrogeologic Properties at Monitoring Locations June 21-24, 2021 Parameter Depth to Water Water Elevation TOC Elevation Temp. pH Specific Conductance Hardness Methane Gas in Headspace Turbidity of Metal Sample Units ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm mg/L (%/Vol) (NTU) MW-1 61.60 1065.42 1127.02 15.0 6.13 67 NR NR 8.79 MW-2 13.72 922.96 936.68 .8 6.01 70 R NR 4.02 MW-3R 4.90 925.10 930.00 14.9 5.83 283 NR NR 12.10 MW-4S 8.60 934.63 943.23 15.0 5.64 41 NR NR 0.73 MW-4D 6.91 935.89 942.80 14.8 5.22 129 NR NR 9.36 MW-5 42.50 935.43 977.93 14.9 5.36 85 NR NR 4.06 MW-6R 64.90 939.85 1004.75 15.1 5.54 170 NR NR 2.21 MW-8 58.90 912.13 971.03 14.9 5.83 216 NR NR 1.45 MW-9S 35.05 917.78 952.83 14.8 5.66 163 NR NR 6.07 MW-9D 35.35 917.12 952.47 15.1 6.37 249 NR NR 19.4 MW-10 27.50 942.74 970.24 15.6 5.45 101 NR NR 13.8 MW-11S 30.87 938.22 969.09 15.4 5.21 128 NR NR 4.16 MW-11D 32.10 933.28 965.38 15.1 5.95 33 NR NR 97.3 MW-12 52.55 944.11 996.66 14.9 6.03 210 NR NR 3.71 MW-13 Dry <943.33 983.13 NR NR NR NR NR NR MLW-A NR NR 1095.51 NR NR NR NR NR NR MW-24 38.65 941.07 979.72 15.6 6.09 63 NR NR 6.31 MW-25 27.50 962.35 989.85 15.4 7.23 171 NR NR 8.65 MW-26 28.60 970.44 999.04 14.5 5.51 41 NR NR 14.9 MW-27 32.46 1010.55 1043.01 14.9 5.96 109 NR NR 15.3 MW-28 65.14 1012.27 1077.41 15.7 6.62 112 NR NR 6.11 Minimum 4.90 912.13 930.00 14.5 5.21 33 - - 0.73 Average 35.15 950.60 990.85 15.1 5.88 128 - - 12.5 Maximum 65.14 1065.42 1127.02 15.7 7.23 283 - - 97.3 SW-1 - - - NR NR NR 34.2 - 11.4 SW-2 - - - NR NR NR 51.3 - 8.63 SW-3 - - - NR NR NR 51.3 - 12.9 SW-4 - - - NR NR NR NR - NR SWN-1 - - - NR NR NR 34.2 - 6.06 SWN-2 - - - NR NR NR 34.2 - 8.13 SW-C - - - NR NR NR 17.1 - 4.21 SW-D - - - NR NR NR 34.2 - 7.14 Minimum - - - - - - 17.1 - 4.21 Average - - - - - - 36.6 - 8.35 Maximum - - - - - - 51.3 - 12.9 NR = No reading attempted btoc = Below top of casing amsl = Above mean sea level Surry County Lined Landfill Page 1 of 1 Table 4 Sampling and Analysis Summary June 22-25, 2021 • • ■ Appendix I & II = Lists from current 40 CFR 258 Surry County Lined Landfill Page 1 of 1 Table 5 Groundwater, Leachate and Quality Control Sample Detections June 22-25, 2021 Parameter Name MDL RL 2L Standard MCL I MW-1 MW-2 11VIW-311 MW-4S MW-4D MW-5 MW-6R I MW-8 I MW-9S MW-9D MW-10 MW-11S MW-11D MW-12 MW-24 MW-25 I MW-26 MW-27 MW-28 LAG00N1 EB I FB IMAC Value BG S S S S S S S S S S S S S S S S S S Leachate QC QC SMAC Value* Metals (Targeted 40CFR 258 Appendix 1) Antimony, total 3 5 1 6 4.4 J - Arsenic, total 4.7 10 10 10 8 J 5.4 J 5.1 J 5.8 J 5 J - Barium, total 3.5 5 700 2000 11.2 38.5 42.7 42.9 41 57.9 83.5 76.1 108 53.5 37.4 22.7 6.5 16.4 25.4 5 14.2 7.6 11.9 162 - Cadmium, total 0.4 1 8' 5 1.8 1.1 1.5 16.7 0.72 J 0.52 J 0.64 J 0.42 J 5.1 2.3 2.7 2.7 3.7 - Cobalt, total 3.6 5 11` NE 78.1 56 - Lead, total 4.5 5 15 15 4.6 J - Nickel, total 3.5 5 100 NE 4.8 J 8.6 6.1 - Selenium, total 4.7 10 20 1 50 1 1 6.8 J 5.3 J 1 9.2 J 5 J 5.2 J 1 5.4 J 5.3 J 6.4 J 6.4 - Thallium, total 0.05 1 0.28 2 0.061 J 0.091 J 0.11 J 0.062 J 0.39 J .052 J - Vanadium, total 3.9 5 27` NE 4 J 4 J 5 - Zinc, total 9.5 10 1000 NE 1 11.2 - VOCs (Targeted 40CFR 258 Appendix I and 1,4-Dioxane) 1,1-Dichloroethane 0.37 1 6 NE 1.7 0.79 J 4.4 J 1,2-Dichloroethane 0.32 1 0.4 5 0.34 J 1.1 2-Butanone (MEK) 4 5 4000 NE 27.3 Acetone 5.1 25 6000 NE 47.5 Benzene 0.34 1 1 5 0.64 J 3 (L) 0.59 J 0.74 J 0.58 J 2.1 Chloroethane 0.65 1 3000 NE 3 cis-1,2-Dichloroethene 0.38 1 70 70 1.5 1.3 1.1 2.1 10.4 5.4 0.53 J 0.79 J 0.58 J 1 Ethylbenzene 0.3 1 600 700 2.7 Methylene Chloride 2 5 5 5 2.4 J 2.1 J 2.1 J Toluene 0.48 1 600 1000 6.2 trans- 1,2-Dichloroethene 0.4 1 100 100 3.1 0.49 J 0.76 J Trichlorofluoromethane 0.3 1 2000 NE 0.56 J Vinyl chloride 0.39 1 0.03 2 1.9 (L) Xylene (Total) 0.34 1 500 10000 L 1 5.7 Targeted 40CFR 258 Appendix II) Mercury, total 0.12 0.2 1 2 - - - - 0.22 1 - I - 0.16 J - - - - - - - - Leachate Parameters BOD, 5 day 2000 2000 NE NE - - - - - - - - - - - - - 2630 - - Nitrate 5 40 NE NE - - - - - - - - - - - - - 20J - - COD 12500 25000 NE NE - - - - - - - - - - - - - 76800 - - pH 0.01 0.1 NE NE - - - - - - - - - - - - 6.4 - - Phosphorus 5 50 NE NE - - - - - - - - - - - - 0.046 J - Sulfate 500 1000 250000 NE - - - - - - - - - - - 34800 - - Notes: Units ug/L unless shown otherwise, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established. Bold Above RL and Established 2L/IMAC Std. (Regulatory compliance Standard) Above Established Federal MCL Drinking Water Std. (NOT a regulatory compliance Standard) BG= Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." 2L/IMAC/SMAC = NC 2L, IMAC and SMAC values recognized by the NC SWS as regulatory groundater Standards. 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 IMAC = Interim Maximum Allowable Concentration SMAC = Site Maximum Allwable Concentration. Approved by NC SWS via ASD April 1, 2020. MCL = Primary Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism. A definitive source of the detections was not determined as part of this report. Surry County Lined Landfill Page 1 of 1 Table 6 Surface Water Sample Detections June 25, 2021 Parameter Name MDL RL NC 2B STD EPA s NRWQC NC ISTV3 MCL" SWN-1 SWN-2 SW-4 SW-C SW-D Upstream Downstream Downstream Downstream Downstream Targeted 40CFR 258 Appendix I Barium, total 3.5 5 NE NE 21,000 12000 17.4 16.2 16.4 Hardness as CaCo3 (Field Measured) Hardness (mg/L) 17.1 17.1 NE NE NE I NE 34.2 34.2 34.2 17.1 Turbidity (Field Measured) Turbidit NTU 0.01 50 NE NE 6.06 8.13 7.14 4.20LL1 Notes: Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". Red Bold Above RL and Applicable Established 213 Std. Above Established Federal MCL Primary Drinking Water Std. MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." Receivina surface waters are Stonev Creek (12-72-12) and Ararat River 02-7244.5) Both Class C. 03040101 (8-Diait HUC). 1 NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes EPA NRWQC= EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health. Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses ' NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DW R staff for further information. MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes. Surry County Lined Landfill Page 1 of 1 Appendix A Field Sampling Parameter Data Sheet(s) M-Idp l � Englneer7u6 &r.w f caoow� j' 4.mn,NC OwugNC Project: Surry Co. Lined MSWLF, Ph 4 ( Samplers: Paage_1_of 1 Monitoring g Point Pure g Date Pure g Time Collect Date Collect Time Sampling Parameters Water Quality Parameters (Stabilized) Depth to Water (BTOP) Static Depth to Water (STOP) Collection Volume Purged (Gal) Sample Type Goes Dry During Purge Total Depth Measured as expected Total Depth Expected (ft btoc) Comments DO (mg/L) ORP pH Temp. © Specific Cond. (us/cm � CH4 Gas Vapors %/Vol ( ) MW-24 ' ��' S O rr 41.78 r � M W-25 j t% 5- r < -;�t 74.00 r7 � L. 7 1 MW-26 ; S , -3 0 o j3 N/ 48.26 M W-27 t `, S L' j %'.�` 3 L-i 1 C 56.07 16 i` ° i O 15,3 M W-28 ,.� - ? ` t/ 83.48 br 5, SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained - • • evirvalm �e.m.•q.m .. Co�pn..�m.q { �I Project: Surry Co Subtitle D Lined MSWLF Samplers: Page_1_of 2 Er t, -,-4 � c -� Sampling Parameters Water Quality Parameters (Stabilized) Depth to Water Depth to Water Volume Sample Goes Dry Total Depth Total DO Temp. Specific Hardness :� CH4 Gas Monitoring Purge Purge Collect Collect Point Date Time Date Time (STOP) (BTOP) Purged Type During Measured as Depth Expected Comments (mg/L) ORP pH © Cond. (us/cm (mg/L) ° 3 Vapors p L Static Collection Gal () Purge expected o (/o/Vol) MW-1 ) ! %t tom' Y 70.3 IL, 14 5. U 7 MW-2 e �-0, �' 26.74 7 , c MW-4S f .. a �, r) 7, 1',t 22.1'q IU, J MW-4D ® ', c-l�". ;t 43.1 MW-5 etas. 48.5 5:34 JLf,;. MW-6R ;�, t v �1 i, 81.3 5�:' t �, j 7C a MW-8 Y a L 1�}` 70.75 n' 'L4 -16 MW-9S' ; S? ' 42.28 I MW-9D i 65.54 MW-10 L ' 0 a s' _ 47.13 MW-11 S r ' " d , .^ 7 ' ? 46.05 MW-11 D %° �� � � .� � 3 l � 65.31 — S, C� l S, 7 a MW-12 t ': SS 65 _ 1:. � i `� 1 .7 MW-13 D ; -q 36.31 -- om- MLW-A 93.5 SW-D 4-/a y 30 - S t , LAGOON G. - SS B=Stainless Steel Baler, D S=Disposable Baler, P=low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Project: Surry Co Closed C&D over Closed MSWLF & Active Subtitle D Lined- Mt. Airy (5narea surrace vvarersi oarnpieIs. Monitoring Point Collect Date Collect Time Sampling Parameters Water i Quality Parameters (Stabilized) Visual Flow Rate Lab Parameters to be analyzed for Visual Guag e Ht. Sample Type Goes Dry D Durin 9 Pure Total Depth Measured as expected Comments DO (m9/L) ORP pH Temp. © Specific Cond. (us/cm Hardness m (g/L ) a = F- CH4 Gas Vapors (ppm) SW-1 SW-2 SW-3 — -- I — - - - L " SW-4� SW-566 SWN-1 I - -,G _ SWN-2 'R 3 - SWN-3 I - SWN-4- SW-C 0 I - - i i f,; - t4 � f SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Appendix B Laboratory Analysis Reports Chains of Custody lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 12, 2021 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 24, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace National - Mt. Juliet • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Accounts Payable, Municipal Engineering Services Jay Zimmerman, PG, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 91 laneAnalytical www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification M 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Lab ID Sample ID Matrix Date Collected Date Received 92546352001 MW-1 Water 06/23/2110:28 06/24/21 07:00 92546352002 MW-2 Water 06/23/21 09:06 06/24/21 07:00 92546352003 MW-3R Water 06/23/2109:12 06/24/21 07:00 92546352004 MW-4S Water 06/23/2109:16 06/24/21 07:00 92546352005 MW-41) Water 06/23/2109:22 06/24/21 07:00 92546352006 MW-5 Water 06/22/2116:18 06/24/21 07:00 92546352007 MW-6R Water 06/22/2116:21 06/24/21 07:00 92546352008 MW-8 Water 06/23/2108:48 06/24/21 07:00 92546352009 MW-9S Water 06/23/21 07:53 06/24/21 07:00 92546352010 MW-91) Water 06/23/2107:55 06/24/21 07:00 92546352011 MW-11S Water 06/23/2108:18 06/24/21 07:00 92546352012 MW-11D Water 06/23/2108:24 06/24/21 07:00 92546352013 MW-12 Water 06/23/2108:31 06/24/21 07:00 92546352014 MW-24 Water 06/22/21 12:05 06/24/21 07:00 92546352015 MW-25 Water 06/22/2113:10 06/24/21 07:00 92546352016 MW-26 Water 06/22/2113:30 06/24/21 07:00 92546352017 MW-27 Water 06/22/2113:40 06/24/21 07:00 92546352018 MW-28 Water 06/22/21 13:50 06/24/21 07:00 92546352019 LAGOON Water 06/23/2116:50 06/24/21 07:00 92546352020 MW-10 Water 06/23/2108:14 06/24/21 07:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co. Lined MSWLF 92546352 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92546352001 MW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352002 MW-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352003 MW-3R EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352004 MW-4S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352005 MW-41) EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352006 MW-5 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352007 MW-6R EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352008 MW-8 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352009 MW-9S EPA 601OD CBV, SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352010 MW-91) EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352011 MW-11S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352012 MW-11D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co. Lined MSWLF 92546352 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92546352013 MW-12 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352014 MW-24 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352015 MW-25 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352016 MW-26 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352017 MW-27 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352018 MW-28 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546352019 LAGOON EPA 601OD CBV, SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D SAS 51 PASI-C SM 521OB-2011 NFW 1 PASI-A EPA 9040C SMK 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 JP1 1 PASI-A 92546352020 MW-10 EPA 8151 JMB 4 PAN EPA 8081 B SEM 21 PASI-C EPA 8082A SEM 8 PASI-C EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8270E PKS 111 PASI-C EPA 8260D SAS 66 PASI-C SM 4500-S2D-2011 JP1 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Analytes Lab ID Sample ID Method Analysts Reported Laboratory PAN = Pace National - Mt. Juliet PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MWA Lab ID: 92546352001 Collected: 06/23/21 10:28 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/21 12:50 07/07/2122:55 7440-36-0 Arsenic 8.OJ ug/L 10.0 4.7 1 07/07/21 12:50 07/07/2122:55 7440-38-2 Barium 11.2 ug/L 5.0 3.5 1 07/07/21 12:50 07/07/2122:55 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/21 12:50 07/07/2122:55 7440-41-7 Cadmium 1.8 ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2122:55 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/21 12:50 07/07/2122:55 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/21 12:50 07/07/2122:55 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/21 12:50 07/07/2122:55 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/21 12:50 07/07/2122:55 7439-92-1 Nickel 4.8.1 ug/L 5.0 3.5 1 07/07/21 12:50 07/07/2122:55 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/21 12:50 07/07/2122:55 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/21 12:50 07/07/2122:55 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/21 12:50 07/07/2122:55 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/21 12:50 07/07/2122:55 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.061J ug/L 0.47 0.050 1 07/07/2113:25 07/07/2122:42 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 07:59 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 07:59 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 07:59 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 07:59 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 07:59 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 07:59 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 07:59 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 07:59 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 07:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 07:59 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 07:59 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 07:59 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 07:59 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 07:59 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 07:59 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 07:59 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 07:59 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 07:59 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 07:59 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 07:59 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 07:59 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 07:59 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 07:59 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 07:59 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 7 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-1 Lab ID: 92546352001 Collected: 06/23/21 10:28 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 07:59 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 07:59 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 07:59 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 07:59 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 07:59 10061-02-6 ND ug/L 150 38.7 1 06/25/21 07:59 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 07:59 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 07:59 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 07:59 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 07:59 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 07:59 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 07:59 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 07:59 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 07:59 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 07:59 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 07:59 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 07:59 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 07:59 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 07:59 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 07:59 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 07:59 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 07:59 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 07:59 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 07:59 1330-20-7 101 % 70-130 1 06/25/21 07:59 460-00-4 98 % 70-130 1 06/25/21 07:59 17060-07-0 99 % 70-130 1 06/25/21 07:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 8 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-2 Lab ID: 92546352002 Collected: 06/23/21 09:06 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:08 7440-36-0 Arsenic 5.4J ug/L 10.0 4.7 1 07/07/21 12:50 07/07/2123:08 7440-38-2 Barium 38.5 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:08 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:08 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:08 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:08 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:08 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:08 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:08 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:08 7440-02-0 Selenium 6.8.1 ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:08 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:08 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:08 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/07/2122:55 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 08:17 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 08:17 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 08:17 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 08:17 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 08:17 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 08:17 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 08:17 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 08:17 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 08:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 08:17 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 08:17 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 08:17 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 08:17 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 08:17 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 08:17 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 08:17 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 08:17 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 08:17 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 08:17 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 08:17 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 08:17 110-57-6 1,1-Dichloroethane 1.7 ug/L 1.0 0.37 1 06/25/21 08:17 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 08:17 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 08:17 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 9 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-2 Lab ID: 92546352002 Collected: 06/23/21 09:06 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.5 ug/L 1.0 0.38 1 06/25/21 08:17 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 08:17 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 08:17 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 08:17 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 08:17 10061-02-6 ND ug/L 150 38.7 1 06/25/21 08:17 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 08:17 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 08:17 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 08:17 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 08:17 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 08:17 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 08:17 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 08:17 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 08:17 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 08:17 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 08:17 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 08:17 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 08:17 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 08:17 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 08:17 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 08:17 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 08:17 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 08:17 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 08:17 1330-20-7 99 % 70-130 1 06/25/21 08:17 460-00-4 98 % 70-130 1 06/25/21 08:17 17060-07-0 98 % 70-130 1 06/25/21 08:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 10 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-3R Lab ID: 92546352003 Collected: 06/23/21 09:12 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:12 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:12 7440-38-2 Barium 42.7 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:12 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:12 7440-41-7 Cadmium 1.1 ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2123:12 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:12 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:12 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:12 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:12 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:12 7440-02-0 Selenium 5.3J ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:12 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:12 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:12 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:18 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 08:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 08:35 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 08:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 08:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 08:35 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 08:35 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 08:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 08:35 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 08:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 08:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 08:35 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 08:35 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 08:35 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 08:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 08:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 08:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 08:35 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 08:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 08:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 08:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 08:35 110-57-6 1,1-Dichloroethane 0.79J ug/L 1.0 0.37 1 06/25/21 08:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 08:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 08:35 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 11 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-3R Lab ID: 92546352003 Collected: 06/23/21 09:12 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.3 ug/L 1.0 0.38 1 06/25/21 08:35 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 08:35 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 08:35 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 08:35 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 08:35 10061-02-6 ND ug/L 150 38.7 1 06/25/21 08:35 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 08:35 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 08:35 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 08:35 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 08:35 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 08:35 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 08:35 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 08:35 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 08:35 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 08:35 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 08:35 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 08:35 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 08:35 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 08:35 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 08:35 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 08:35 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 08:35 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 08:35 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 08:35 1330-20-7 99 % 70-130 1 06/25/21 08:35 460-00-4 99 % 70-130 1 06/25/21 08:35 17060-07-0 99 % 70-130 1 06/25/21 08:35 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 12 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-4S Lab ID: 92546352004 Collected: 06/23/21 09:16 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:15 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:15 7440-38-2 Barium 42.9 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:15 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:15 7440-41-7 Cadmium 1.5 ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2123:15 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:15 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:15 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:15 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:15 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:15 7440-02-0 Selenium 9.2.1 ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:15 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:15 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:15 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:22 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 08:53 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 08:53 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 08:53 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 08:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 08:53 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 08:53 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 08:53 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 08:53 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 08:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 08:53 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 08:53 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 08:53 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 08:53 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 08:53 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 08:53 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 08:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 08:53 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 08:53 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 08:53 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 08:53 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 08:53 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 08:53 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 08:53 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 08:53 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 13 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-4S Lab ID: 92546352004 Collected: 06/23/21 09:16 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.1 ug/L 1.0 0.38 1 06/25/21 08:53 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 08:53 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 08:53 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 08:53 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 08:53 10061-02-6 ND ug/L 150 38.7 1 06/25/21 08:53 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 08:53 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 08:53 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 08:53 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 08:53 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 08:53 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 08:53 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 08:53 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 08:53 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 08:53 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 08:53 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 08:53 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 08:53 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 08:53 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 08:53 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 08:53 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 08:53 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 08:53 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 08:53 1330-20-7 101 % 70-130 1 06/25/21 08:53 460-00-4 97 % 70-130 1 06/25/21 08:53 17060-07-0 98 % 70-130 1 06/25/21 08:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 14 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-41) Lab ID: 92546352005 Collected: 06/23/21 09:22 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:25 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:25 7440-38-2 Barium 41.0 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:25 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:25 7440-41-7 Cadmium 16.7 ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2123:25 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:25 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:25 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:25 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:25 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:25 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:25 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:25 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:25 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:27 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 09:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 09:12 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 09:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 09:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 09:12 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 09:12 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 09:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 09:12 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 09:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 09:12 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 09:12 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 09:12 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 09:12 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 09:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 09:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 09:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 09:12 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 09:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 09:12 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 09:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 09:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 09:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 09:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 09:12 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 15 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-41) Lab ID: 92546352005 Collected: 06/23/21 09:22 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 09:12 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 09:12 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 09:12 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 09:12 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 09:12 10061-02-6 ND ug/L 150 38.7 1 06/25/21 09:12 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 09:12 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 09:12 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 09:12 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 09:12 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 09:12 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 09:12 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 09:12 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 09:12 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 09:12 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 09:12 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 09:12 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 09:12 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 09:12 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 09:12 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 09:12 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 09:12 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 09:12 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 09:12 1330-20-7 100 % 70-130 1 06/25/21 09:12 460-00-4 98 % 70-130 1 06/25/21 09:12 17060-07-0 99 % 70-130 1 06/25/21 09:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 16 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-5 Lab ID: 92546352006 Collected: 06/22/21 16:18 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:28 7440-36-0 Arsenic 5.1J ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:28 7440-38-2 Barium 57.9 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:28 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:28 7440-41-7 Cadmium 0.72J ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2123:28 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:28 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:28 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:28 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:28 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:28 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:28 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:28 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.0911 ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:32 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 09:30 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 09:30 107-13-1 Benzene 0.64J ug/L 1.0 0.34 1 06/25/21 09:30 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 09:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 09:30 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 09:30 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 09:30 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 09:30 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 09:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 09:30 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 09:30 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 09:30 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 09:30 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 09:30 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 09:30 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 09:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 09:30 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 09:30 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 09:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 09:30 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 09:30 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 09:30 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 09:30 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 09:30 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 17 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-5 Lab ID: 92546352006 Collected: 06/22/21 16:18 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.1 ug/L 1.0 0.38 1 06/25/21 09:30 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 09:30 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 09:30 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 09:30 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 09:30 10061-02-6 ND ug/L 150 38.7 1 06/25/21 09:30 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 09:30 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 09:30 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 09:30 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 09:30 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 09:30 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 09:30 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 09:30 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 09:30 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 09:30 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 09:30 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 09:30 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 09:30 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 09:30 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 09:30 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 09:30 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 09:30 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 09:30 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 09:30 1330-20-7 99 % 70-130 1 06/25/21 09:30 460-00-4 97 % 70-130 1 06/25/21 09:30 17060-07-0 97 % 70-130 1 06/25/21 09:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 18 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-6R Lab ID: 92546352007 Collected: 06/22/21 16:21 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:31 7440-36-0 Arsenic 5.8J ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:31 7440-38-2 Barium 83.5 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:31 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:31 7440-41-7 Cadmium 0.52J ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:31 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:31 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:31 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:31 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:31 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:31 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:31 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:31 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:31 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:31 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.11J ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:36 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 07/12/2021 05:48 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 0.22 ug/L 0.20 0.12 1 06/25/21 14:37 06/29/21 13:19 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 3.0 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 3.0 ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 5.1 1 06/25/21 09:48 67-64-1 1.8 1 06/25/21 09:48 107-13-1 0.34 1 06/25/21 09:48 71-43-2 0.47 1 06/25/21 09:48 74-97-5 0.31 1 06/25/21 09:48 75-27-4 0.34 1 06/25/21 09:48 75-25-2 1.7 1 06/25/21 09:48 74-83-9 4.0 1 06/25/21 09:48 78-93-3 0.73 1 06/25/21 09:48 75-15-0 0.33 1 06/25/21 09:48 56-23-5 0.28 1 06/25/21 09:48 108-90-7 0.65 1 06/25/21 09:48 75-00-3 1.6 1 06/25/21 09:48 67-66-3 0.54 1 06/25/21 09:48 74-87-3 0.34 1 06/25/21 09:48 96-12-8 0.36 1 06/25/21 09:48 124-48-1 0.27 1 06/25/21 09:48 106-93-4 0.39 1 06/25/21 09:48 74-95-3 0.34 1 06/25/21 09:48 95-50-1 0.33 1 06/25/21 09:48 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 19 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-6R Lab ID: 92546352007 Collected: 06/22/21 16:21 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.56 1 06/25/21 09:48 110-57-6 ND ug/L 1.0 0.37 1 06/25/21 09:48 75-34-3 0.34J ug/L 1.0 0.32 1 06/25/21 09:48 107-06-2 ND ug/L 1.0 0.35 1 06/25/21 09:48 75-35-4 10.4 ug/L 1.0 0.38 1 06/25/21 09:48 156-59-2 3.1 ug/L 1.0 0.40 1 06/25/21 09:48 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 09:48 78-87-5 N D ug/L 1.0 0.36 1 06/25/21 09:48 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 09:48 10061-02-6 ND ug/L 150 38.7 1 06/25/21 09:48 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 09:48 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 09:48 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 09:48 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 09:48 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 09:48 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 09:48 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 09:48 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 09:48 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 09:48 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 09:48 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 09:48 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 09:48 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 09:48 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 09:48 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 09:48 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 09:48 108-05-4 1.9 ug/L 1.0 0.39 1 06/25/21 09:48 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 09:48 1330-20-7 101 % 70-130 1 06/25/21 09:48 460-00-4 99 % 70-130 1 06/25/21 09:48 17060-07-0 98 % 70-130 1 06/25/21 09:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 20 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-8 Lab ID: 92546352008 Collected: 06/23/21 08:48 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:35 7440-36-0 Arsenic 5.OJ ug/L 10.0 4.7 1 07/07/21 12:50 07/07/2123:35 7440-38-2 Barium 76.1 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:35 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:35 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:35 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:35 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:35 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:35 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:35 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:35 7440-02-0 Selenium 5.0.1 ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:35 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:35 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:35 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.062J ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:50 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 10:06 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 10:06 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 10:06 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 10:06 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 10:06 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 10:06 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 10:06 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 10:06 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 10:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 10:06 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 10:06 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 10:06 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 10:06 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 10:06 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 10:06 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 10:06 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 10:06 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 10:06 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 10:06 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 10:06 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 10:06 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 10:06 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 10:06 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 10:06 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 21 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-8 Lab ID: 92546352008 Collected: 06/23/21 08:48 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 10:06 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 10:06 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 10:06 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 10:06 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 10:06 10061-02-6 ND ug/L 150 38.7 1 06/25/21 10:06 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 10:06 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 10:06 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 10:06 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 10:06 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 10:06 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 10:06 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 10:06 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 10:06 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 10:06 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 10:06 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 10:06 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 10:06 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 10:06 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 10:06 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 10:06 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 10:06 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 10:06 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 10:06 1330-20-7 100 % 70-130 1 06/25/21 10:06 460-00-4 97 % 70-130 1 06/25/21 10:06 17060-07-0 97 % 70-130 1 06/25/21 10:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 22 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-9S Lab ID: 92546352009 Collected: 06/23/21 07:53 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/21 12:50 07/07/2123:38 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/21 12:50 07/07/2123:38 7440-38-2 Barium 108 ug/L 5.0 3.5 1 07/07/21 12:50 07/07/2123:38 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/21 12:50 07/07/2123:38 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2123:38 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/21 12:50 07/07/2123:38 7440-47-3 Cobalt 78.1 ug/L 5.0 3.6 1 07/07/21 12:50 07/07/2123:38 7440-48-4 Copper ND ug/L 25.0 21.3 5 07/07/21 12:50 07/08/2112:32 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/21 12:50 07/07/2123:38 7439-92-1 Nickel 8.6 ug/L 5.0 3.5 1 07/07/21 12:50 07/07/2123:38 7440-02-0 Selenium 5.2J ug/L 10.0 4.7 1 07/07/21 12:50 07/07/2123:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/21 12:50 07/07/2123:38 7440-22-4 Tin ND ug/L 5.0 4.7 1 07/07/21 12:50 07/07/2123:38 7440-31-5 Vanadium 4.0.1 ug/L 5.0 3.9 1 07/07/21 12:50 07/07/2123:38 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/21 12:50 07/07/2123:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.39J ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:54 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 10:24 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 10:24 107-13-1 Benzene 0.591 ug/L 1.0 0.34 1 06/25/21 10:24 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 10:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 10:24 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 10:24 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 10:24 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 10:24 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 10:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 10:24 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 10:24 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 10:24 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 10:24 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 10:24 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 10:24 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 10:24 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 10:24 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 10:24 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 10:24 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 10:24 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 10:24 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 10:24 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 10:24 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. D3 v2 Page 23 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-9S Lab ID: 92546352009 Collected: 06/23/21 07:53 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.35 1 06/25/21 10:24 75-35-4 5.4 ug/L 1.0 0.38 1 06/25/21 10:24 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 10:24 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 10:24 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 10:24 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 10:24 10061-02-6 ND ug/L 150 38.7 1 06/25/21 10:24 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 10:24 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 10:24 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 10:24 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 10:24 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 10:24 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 10:24 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 10:24 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 10:24 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 10:24 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 10:24 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 10:24 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 10:24 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 10:24 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 10:24 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 10:24 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 10:24 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 10:24 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 10:24 1330-20-7 98 % 70-130 1 06/25/21 10:24 460-00-4 97 % 70-130 1 06/25/21 10:24 17060-07-0 99 % 70-130 1 06/25/21 10:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 24 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-91) Lab ID: 92546352010 Collected: 06/23/21 07:55 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:41 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:41 7440-38-2 Barium 53.5 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:41 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:41 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:41 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:41 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:41 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:41 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:41 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:41 7440-02-0 Selenium 5.4J ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:41 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:41 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:41 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:41 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/07/2123:59 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 10:43 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 10:43 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 10:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 10:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 10:43 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 10:43 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 10:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 10:43 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 10:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 10:43 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 10:43 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 10:43 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 10:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 10:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 10:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 10:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 10:43 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 10:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 10:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 10:43 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 10:43 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 10:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 10:43 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 10:43 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 25 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-91) Lab ID: 92546352010 Collected: 06/23/21 07:55 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.53J ug/L 1.0 0.38 1 06/25/21 10:43 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 10:43 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 10:43 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 10:43 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 10:43 10061-02-6 ND ug/L 150 38.7 1 06/25/21 10:43 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 10:43 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 10:43 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 10:43 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 10:43 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 10:43 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 10:43 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 10:43 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 10:43 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 10:43 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 10:43 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 10:43 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 10:43 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 10:43 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 10:43 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 10:43 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 10:43 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 10:43 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 10:43 1330-20-7 100 % 70-130 1 06/25/21 10:43 460-00-4 97 % 70-130 1 06/25/21 10:43 17060-07-0 98 % 70-130 1 06/25/21 10:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 26 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-11S Lab ID: 92546352011 Collected: 06/23/21 08:18 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:44 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:44 7440-38-2 Barium 22.7 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:44 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:44 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:44 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:44 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:44 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:44 7440-50-8 Lead 4.6.1 ug/L 5.0 4.5 1 07/07/21 12:50 07/07/2123:44 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:44 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:44 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:44 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:44 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:44 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:03 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 11:01 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 11:01 107-13-1 Benzene 0.58J ug/L 1.0 0.34 1 06/25/21 11:01 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 11:01 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 11:01 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 11:01 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 11:01 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 11:01 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 11:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 11:01 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 11:01 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 11:01 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 11:01 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 11:01 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 11:01 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 11:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 11:01 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 11:01 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 11:01 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 11:01 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 11:01 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 11:01 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 11:01 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 11:01 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 27 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-11S Lab ID: 92546352011 Collected: 06/23/21 08:18 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.58J ug/L 1.0 0.38 1 06/25/2111:01 156-59-2 0.49J ug/L 1.0 0.40 1 06/25/2111:01 156-60-5 ND ug/L 1.0 0.36 1 06/25/2111:01 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 11:01 10061-01-5 ND ug/L 1.0 0.36 1 06/25/2111:01 10061-02-6 ND ug/L 150 38.7 1 06/25/2111:01 123-91-1 ND ug/L 1.0 0.30 1 06/25/2111:01 100-41-4 ND ug/L 5.0 0.48 1 06/25/2111:01 591-78-6 ND ug/L 20.0 9.7 1 06/25/2111:01 74-88-4 ND ug/L 5.0 2.0 1 06/25/2111:01 75-09-2 ND ug/L 5.0 2.7 1 06/25/2111:01 108-10-1 ND ug/L 1.0 0.29 1 06/25/2111:01 100-42-5 ND ug/L 1.0 0.31 1 06/25/2111:01 630-20-6 ND ug/L 1.0 0.22 1 06/25/2111:01 79-34-5 ND ug/L 1.0 0.29 1 06/25/2111:01 127-18-4 ND ug/L 1.0 0.48 1 06/25/2111:01 108-88-3 ND ug/L 1.0 0.33 1 06/25/2111:01 71-55-6 ND ug/L 1.0 0.32 1 06/25/2111:01 79-00-5 ND ug/L 1.0 0.38 1 06/25/2111:01 79-01-6 ND ug/L 1.0 0.30 1 06/25/2111:01 75-69-4 ND ug/L 1.0 0.26 1 06/25/2111:01 96-18-4 ND ug/L 2.0 1.3 1 06/25/2111:01 108-05-4 ND ug/L 1.0 0.39 1 06/25/2111:01 75-01-4 ND ug/L 1.0 0.34 1 06/25/2111:01 1330-20-7 100 % 70-130 1 06/25/2111:01 460-00-4 98 % 70-130 1 06/25/2111:01 17060-07-0 98 % 70-130 1 06/25/2111:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 28 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-11D Lab ID: 92546352012 Collected: 06/23/21 08:24 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:48 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:48 7440-38-2 Barium 6.5 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:48 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:48 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:48 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:48 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:48 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:48 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:48 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:48 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:48 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:48 7440-22-4 Vanadium 4.0.1 ug/L 5.0 3.9 1 07/07/21 12:50 07/07/2123:48 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:48 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:08 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 11:19 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 11:19 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 11:19 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 11:19 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 11:19 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 11:19 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 11:19 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 11:19 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 11:19 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 11:19 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 11:19 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 11:19 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 11:19 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 11:19 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 11:19 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 11:19 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 11:19 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 11:19 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 11:19 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 11:19 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 11:19 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 11:19 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 11:19 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 11:19 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 29 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-11D Lab ID: 92546352012 Collected: 06/23/21 08:24 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 11:19 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 11:19 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 11:19 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 11:19 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 11:19 10061-02-6 ND ug/L 150 38.7 1 06/25/21 11:19 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 11:19 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 11:19 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 11:19 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 11:19 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 11:19 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 11:19 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 11:19 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 11:19 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 11:19 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 11:19 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 11:19 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 11:19 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 11:19 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 11:19 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 11:19 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 11:19 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 11:19 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 11:19 1330-20-7 99 % 70-130 1 06/25/21 11:19 460-00-4 99 % 70-130 1 06/25/21 11:19 17060-07-0 98 % 70-130 1 06/25/21 11:19 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 30 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-12 Lab ID: 92546352013 Collected: 06/23/21 08:31 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:51 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:51 7440-38-2 Barium 16.4 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:51 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:51 7440-41-7 Cadmium 0.42J ug/L 1.0 0.40 1 07/07/2112:50 07/07/2123:51 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:51 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:51 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:51 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:51 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:51 7440-02-0 Selenium 5.3J ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:51 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:51 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:51 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:51 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:12 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 11:37 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 11:37 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 11:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 11:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 11:37 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 11:37 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 11:37 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 11:37 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 11:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 11:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 11:37 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 11:37 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 11:37 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 11:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 11:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 11:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 11:37 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 11:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 11:37 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 11:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 11:37 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 11:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 11:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 11:37 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 31 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-12 Lab ID: 92546352013 Collected: 06/23/21 08:31 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 11:37 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 11:37 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 11:37 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 11:37 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 11:37 10061-02-6 ND ug/L 150 38.7 1 06/25/21 11:37 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 11:37 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 11:37 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 11:37 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 11:37 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 11:37 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 11:37 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 11:37 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 11:37 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 11:37 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 11:37 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 11:37 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 11:37 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 11:37 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 11:37 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 11:37 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 11:37 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 11:37 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 11:37 1330-20-7 100 % 70-130 1 06/25/21 11:37 460-00-4 98 % 70-130 1 06/25/21 11:37 17060-07-0 99 % 70-130 1 06/25/21 11:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 32 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-24 Lab ID: 92546352014 Collected: 06/22/21 12:05 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/07/2123:54 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:54 7440-38-2 Barium 25.4 ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:54 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/07/2123:54 7440-41-7 Cadmium 5.1 ug/L 1.0 0.40 1 07/07/21 12:50 07/07/2123:54 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/07/2123:54 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/07/2123:54 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/07/2123:54 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/07/2123:54 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/07/2123:54 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/07/2123:54 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/07/2123:54 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/07/2123:54 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/07/2123:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:26 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 11:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 11:55 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 11:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 11:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 11:55 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 11:55 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 11:55 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 11:55 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 11:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 11:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 11:55 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 11:55 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 11:55 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 11:55 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 11:55 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 11:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 11:55 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 11:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 11:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 11:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 11:55 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 11:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 11:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 11:55 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 33 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-24 Lab ID: 92546352014 Collected: 06/22/21 12:05 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 11:55 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 11:55 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 11:55 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 11:55 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 11:55 10061-02-6 ND ug/L 150 38.7 1 06/25/21 11:55 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 11:55 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 11:55 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 11:55 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 11:55 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 11:55 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 11:55 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 11:55 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 11:55 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 11:55 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 11:55 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 11:55 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 11:55 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 11:55 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 11:55 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 11:55 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 11:55 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 11:55 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 11:55 1330-20-7 101 % 70-130 1 06/25/21 11:55 460-00-4 97 % 70-130 1 06/25/21 11:55 17060-07-0 98 % 70-130 1 06/25/21 11:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 34 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-25 Lab ID: 92546352015 Collected: 06/22/21 13:10 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/08/2100:11 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:11 7440-38-2 Barium 5.0 ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:11 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/08/2100:11 7440-41-7 Cadmium 2.3 ug/L 1.0 0.40 1 07/07/2112:50 07/08/2100:11 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/08/2100:11 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/08/2100:11 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/08/2100:11 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/08/2100:11 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:11 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/08/2100:11 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/08/2100:11 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/08/2100:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:30 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 12:14 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 12:14 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 12:14 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 12:14 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 12:14 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 12:14 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 12:14 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 12:14 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 12:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 12:14 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 12:14 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 12:14 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 12:14 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 12:14 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 12:14 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 12:14 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 12:14 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 12:14 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 12:14 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 12:14 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 12:14 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 12:14 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 12:14 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 12:14 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 35 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-25 Lab ID: 92546352015 Collected: 06/22/21 13:10 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 12:14 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 12:14 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 12:14 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 12:14 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 12:14 10061-02-6 ND ug/L 150 38.7 1 06/25/21 12:14 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 12:14 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 12:14 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 12:14 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 12:14 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 12:14 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 12:14 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 12:14 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 12:14 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 12:14 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 12:14 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 12:14 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 12:14 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 12:14 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 12:14 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 12:14 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 12:14 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 12:14 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 12:14 1330-20-7 100 % 70-130 1 06/25/21 12:14 460-00-4 98 % 70-130 1 06/25/21 12:14 17060-07-0 98 % 70-130 1 06/25/21 12:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 36 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-26 Lab ID: 92546352016 Collected: 06/22/21 13:30 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/08/2100:14 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:14 7440-38-2 Barium 14.2 ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:14 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/08/2100:14 7440-41-7 Cadmium 2.7 ug/L 1.0 0.40 1 07/07/21 12:50 07/08/2100:14 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/08/2100:14 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/08/2100:14 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/08/2100:14 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/08/2100:14 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:14 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/08/2100:14 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/08/2100:14 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/08/2100:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:35 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 12:32 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 12:32 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 12:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 12:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 12:32 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 12:32 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 12:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 12:32 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 12:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 12:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 12:32 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 12:32 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 12:32 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 12:32 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 12:32 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 12:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 12:32 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 12:32 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 12:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 12:32 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 12:32 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 12:32 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 12:32 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 12:32 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 37 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-26 Lab ID: 92546352016 Collected: 06/22/21 13:30 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 12:32 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 12:32 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 12:32 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 12:32 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 12:32 10061-02-6 ND ug/L 150 38.7 1 06/25/21 12:32 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 12:32 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 12:32 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 12:32 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 12:32 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 12:32 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 12:32 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 12:32 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 12:32 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 12:32 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 12:32 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 12:32 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 12:32 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 12:32 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 12:32 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 12:32 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 12:32 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 12:32 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 12:32 1330-20-7 100 % 70-130 1 06/25/21 12:32 460-00-4 100 % 70-130 1 06/25/21 12:32 17060-07-0 99 % 70-130 1 06/25/21 12:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 38 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-27 Lab ID: 92546352017 Collected: 06/22/21 13:40 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/08/2100:17 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:17 7440-38-2 Barium 7.6 ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:17 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/08/2100:17 7440-41-7 Cadmium 2.7 ug/L 1.0 0.40 1 07/07/21 12:50 07/08/2100:17 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/08/2100:17 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/08/2100:17 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/08/2100:17 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/08/2100:17 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:17 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:17 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/08/2100:17 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/08/2100:17 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/08/2100:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:39 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 15:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 15:52 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 15:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 15:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 15:52 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 15:52 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 15:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 15:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 15:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 15:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 15:52 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 15:52 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 15:52 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 15:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 15:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 15:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 15:52 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 15:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 15:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 15:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 15:52 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 15:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 15:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 15:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. v2 Page 39 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-27 Lab ID: 92546352017 Collected: 06/22/21 13:40 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 15:52 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 15:52 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 15:52 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 15:52 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 15:52 10061-02-6 ND ug/L 150 38.7 1 06/25/21 15:52 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 15:52 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 15:52 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 15:52 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 15:52 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 15:52 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 15:52 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 15:52 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 15:52 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 15:52 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 15:52 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 15:52 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 15:52 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 15:52 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 15:52 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 15:52 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 15:52 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 15:52 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 15:52 1330-20-7 98 % 70-130 1 06/25/21 15:52 460-00-4 98 % 70-130 1 06/25/21 15:52 17060-07-0 98 % 70-130 1 06/25/21 15:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 40 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-28 Lab ID: 92546352018 Collected: 06/22/21 13:50 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/08/2100:20 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:20 7440-38-2 Barium 11.9 ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:20 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/08/2100:20 7440-41-7 Cadmium 3.7 ug/L 1.0 0.40 1 07/07/21 12:50 07/08/2100:20 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/08/2100:20 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/08/2100:20 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/08/2100:20 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/08/2100:20 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:20 7440-02-0 Selenium 6.4J ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:20 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/08/2100:20 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/08/2100:20 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/08/2100:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:44 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 16:26 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 16:26 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/25/21 16:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 16:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 16:26 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 16:26 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 16:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 16:26 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 16:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 16:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 16:26 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 16:26 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 16:26 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 16:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 16:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 16:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 16:26 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 16:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 16:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 16:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 16:26 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 16:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 16:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 16:26 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. IH,v1 v2 IH,v1 Page 41 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-28 Lab ID: 92546352018 Collected: 06/22/21 13:50 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/25/21 16:26 156-59-2 ND ug/L 1.0 0.40 1 06/25/21 16:26 156-60-5 ND ug/L 1.0 0.36 1 06/25/21 16:26 78-87-5 ND ug/L 1.0 0.36 1 06/25/21 16:26 10061-01-5 ND ug/L 1.0 0.36 1 06/25/21 16:26 10061-02-6 ND ug/L 150 38.7 1 06/25/21 16:26 123-91-1 ND ug/L 1.0 0.30 1 06/25/21 16:26 100-41-4 ND ug/L 5.0 0.48 1 06/25/21 16:26 591-78-6 ND ug/L 20.0 9.7 1 06/25/21 16:26 74-88-4 ND ug/L 5.0 2.0 1 06/25/21 16:26 75-09-2 ND ug/L 5.0 2.7 1 06/25/21 16:26 108-10-1 ND ug/L 1.0 0.29 1 06/25/21 16:26 100-42-5 ND ug/L 1.0 0.31 1 06/25/21 16:26 630-20-6 ND ug/L 1.0 0.22 1 06/25/21 16:26 79-34-5 ND ug/L 1.0 0.29 1 06/25/21 16:26 127-18-4 ND ug/L 1.0 0.48 1 06/25/21 16:26 108-88-3 ND ug/L 1.0 0.33 1 06/25/21 16:26 71-55-6 ND ug/L 1.0 0.32 1 06/25/21 16:26 79-00-5 ND ug/L 1.0 0.38 1 06/25/21 16:26 79-01-6 ND ug/L 1.0 0.30 1 06/25/21 16:26 75-69-4 ND ug/L 1.0 0.26 1 06/25/21 16:26 96-18-4 ND ug/L 2.0 1.3 1 06/25/21 16:26 108-05-4 ND ug/L 1.0 0.39 1 06/25/21 16:26 75-01-4 ND ug/L 1.0 0.34 1 06/25/21 16:26 1330-20-7 99 % 70-130 1 06/25/21 16:26 460-00-4 97 % 70-130 1 06/25/21 16:26 17060-07-0 98 % 70-130 1 06/25/21 16:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 42 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: LAGOON Lab ID: 92546352019 Collected: 06/23/21 16:50 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony 4AJ ug/L 5.0 3.0 1 07/07/21 12:50 07/08/2100:24 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/21 12:50 07/08/2100:24 7440-38-2 Barium 162 ug/L 5.0 3.5 1 07/07/21 12:50 07/08/2100:24 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/21 12:50 07/08/2100:24 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/07/21 12:50 07/08/2100:24 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/21 12:50 07/08/2100:24 7440-47-3 Cobalt 56.0 ug/L 5.0 3.6 1 07/07/21 12:50 07/08/2100:24 7440-48-4 Copper ND ug/L 25.0 21.3 5 07/07/21 12:50 07/08/2112:43 7440-50-8 D3 Lead ND ug/L 5.0 4.5 1 07/07/21 12:50 07/08/2100:24 7439-92-1 Nickel 6.1 ug/L 5.0 3.5 1 07/07/21 12:50 07/08/2100:24 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/21 12:50 07/08/2100:24 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/21 12:50 07/08/2100:24 7440-22-4 Vanadium 5.0 ug/L 5.0 3.9 1 07/07/21 12:50 07/08/2100:24 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/21 12:50 07/08/2100:24 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.052J ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:48 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 47.5 ug/L 25.0 5.1 1 06/25/21 12:28 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 12:28 107-13-1 Benzene 2.1 ug/L 1.0 0.34 1 06/25/21 12:28 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 12:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 12:28 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 12:28 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 12:28 74-83-9 2-Butanone (MEK) 27.3 ug/L 5.0 4.0 1 06/25/21 12:28 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 12:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 12:28 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 12:28 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 12:28 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 12:28 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 12:28 74-87-3 v2 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/25/21 12:28 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 12:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/25/21 12:28 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 12:28 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 12:28 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 12:28 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 12:28 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 12:28 75-34-3 1,2-Dichloroethane 1.1 ug/L 1.0 0.32 1 06/25/21 12:28 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 12:28 75-35-4 Date: 07/12/2021 05:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: LAGOON Lab ID: 92546352019 Collected: 06/23/21 16:50 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 5210B BOD, 5 day BOD, 5 day 9040 pH pH at 25 Degrees C 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 07/12/2021 05:48 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.0 ug/L 1.0 0.76J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 150 2.7 ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 2AJ ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.56J ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 5.7 ug/L 1.0 0.38 1 06/25/21 12:28 156-59-2 0.40 1 06/25/21 12:28 156-60-5 0.36 1 06/25/21 12:28 78-87-5 0.36 1 06/25/21 12:28 10061-01-5 0.36 1 06/25/21 12:28 10061-02-6 38.7 1 06/25/21 12:28 123-91-1 0.30 1 06/25/21 12:28 100-41-4 0.48 1 06/25/21 12:28 591-78-6 9.7 1 06/25/21 12:28 74-88-4 2.0 1 06/25/21 12:28 75-09-2 2.7 1 06/25/21 12:28 108-10-1 0.29 1 06/25/21 12:28 100-42-5 0.31 1 06/25/21 12:28 630-20-6 0.22 1 06/25/21 12:28 79-34-5 0.29 1 06/25/21 12:28 127-18-4 0.48 1 06/25/21 12:28 108-88-3 0.33 1 06/25/21 12:28 71-55-6 0.32 1 06/25/21 12:28 79-00-5 0.38 1 06/25/21 12:28 79-01-6 0.30 1 06/25/21 12:28 75-69-4 0.26 1 06/25/21 12:28 96-18-4 1.3 1 06/25/21 12:28 108-05-4 0.39 1 06/25/21 12:28 75-01-4 0.34 1 06/25/21 12:28 1330-20-7 94 % 70-130 94 % 70-130 105 % 70-130 Analytical Method: SM 521OB-2011 Pace Analytical Services -Asheville 2630 ug/L 2000 2000 Analytical Method: EPA 9040C Pace Analytical Services -Asheville 6.4 Std. Units 0.10 0.10 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 34800 ug/L 1000 500 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 20.OJ ug/L 40.0 10.0 1 06/25/21 12:28 460-00-4 1 06/25/21 12:28 17060-07-0 1 06/25/21 12:28 2037-26-5 li teI:If ��.7f ��i 9eI:7 [eIe=II:IBie1f ��i 9e193 BE! 1 07/04/21 15:57 1 06/26/21 01:26 14808-79-8 1 06/25/21 01:22 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3 Page 44 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: LAGOON Lab ID: 92546352019 Collected: 06/23/21 16:50 Received: 06/24/21 07:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.046J mg/L 0.050 0.025 1 07/08/2122:10 07/09/21 18:29 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 76800 ug/L 25000 12500 1 07/07/21 02:33 07/07/21 06:10 Date: 07/12/2021 05:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-10 Lab ID: 92546352020 Collected: 06/23/21 08:14 Received: 06/24/21 07:00 Matrix: Water Comments: • Chlorinated Acid Herbicides (GC) by Method 8151 - No extra bottles, cannot be re -extracted Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151 2,4-D 2,4,5-T 2,4,5-TP (Silvex) Surrogates 2,4-DCAA (S) 8081 OC Pesticides RVE Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 8082 GCS PCB RVE PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Surrogates Decachlorobiphenyl (S) Date: 07/12/2021 05:48 PM Analytical Method: EPA 8151 Preparation Method: 8151A Pace National - Mt. Juliet ND ug/L 2.00 0.547 1 06/27/2120:07 06/30/2102:41 94-75-7 LO ND ug/L 2.00 0.258 1 06/27/2120:07 06/30/2102:41 93-76-5 L0,R1 ND ug/L 2.00 0.335 1 06/27/2120:07 06/30/2102:41 93-72-1 L0,R1 16.6 % 14.0-158 1 06/27/2120:07 06/30/2102:41 19719-28-9 Analytical Method: EPA 8081 B Preparation Method: EPA 351 OC Pace Analytical Services - Charlotte ND ug/L 0.045 0.023 1 06/29/2116:56 06/30/2115:47 309-00-2 ND ug/L 0.045 0.023 1 06/29/2116:56 06/30/2115:47 319-84-6 ND ug/L 0.045 0.020 1 06/29/2116:56 06/30/2115:47 319-85-7 ND ug/L 0.045 0.017 1 06/29/2116:56 06/30/2115:47 319-86-8 ND ug/L 0.045 0.018 1 06/29/2116:56 06/30/2115:47 58-89-9 ND ug/L 0.45 0.19 1 06/29/2116:56 06/30/2115:47 57-74-9 ND ug/L 0.045 0.011 1 06/29/2116:56 06/30/2115:47 72-54-8 ND ug/L 0.045 0.014 1 06/29/2116:56 06/30/2115:47 72-55-9 ND ug/L 0.045 0.044 1 06/29/2116:56 06/30/2115:47 50-29-3 ND ug/L 0.045 0.012 1 06/29/2116:56 06/30/2115:47 60-57-1 R1 ND ug/L 0.045 0.013 1 06/29/2116:56 06/30/2115:47 959-98-8 ND ug/L 0.045 0.016 1 06/29/2116:56 06/30/2115:47 33213-65-9 ND ug/L 0.045 0.013 1 06/29/2116:56 06/30/2115:47 1031-07-8 ND ug/L 0.045 0.013 1 06/29/2116:56 06/30/2115:47 72-20-8 ND ug/L 0.045 0.025 1 06/29/2116:56 06/30/2115:47 7421-93-4 ND ug/L 0.045 0.033 1 06/29/2116:56 06/30/2115:47 76-44-8 ND ug/L 0.045 0.014 1 06/29/2116:56 06/30/2115:47 1024-57-3 ND ug/L 0.14 0.11 1 06/29/2116:56 06/30/2115:47 72-43-5 ND ug/L 0.45 0.25 1 06/29/2116:56 06/30/2115:47 8001-35-2 90 % 10-184 1 06/29/21 16:56 06/30/21 15:47 877-09-8 104 % 10-154 1 06/29/2116:56 06/30/2115:47 2051-24-3 Analytical Method: EPA 8082A Preparation Method: EPA 351 OC Pace Analytical Services - Charlotte ND ug/L 0.50 0.47 1 06/28/2107:24 06/30/2122:40 12674-11-2 ND ug/L 0.50 0.45 1 06/28/2107:24 06/30/2122:40 11104-28-2 ND ug/L 0.50 0.36 1 06/28/2107:24 06/30/2122:40 11141-16-5 ND ug/L 0.50 0.26 1 06/28/2107:24 06/30/2122:40 53469-21-9 ND ug/L 0.50 0.40 1 06/28/2107:24 06/30/2122:40 12672-29-6 ND ug/L 0.50 0.25 1 06/28/2107:24 06/30/2122:40 11097-69-1 ND ug/L 0.50 0.42 1 06/28/2107:24 06/30/2122:40 11096-82-5 64 % 10-181 1 06/28/2107:24 06/30/2122:40 2051-24-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-10 Lab ID: 92546352020 Collected: 06/23/21 08:14 Received: 06/24/21 07:00 Matrix: Water Comments: • Chlorinated Acid Herbicides (GC) by Method 8151 - No extra bottles, cannot be re -extracted Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/07/2112:50 07/08/2100:27 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:27 7440-38-2 Barium 37.4 ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:27 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/07/2112:50 07/08/2100:27 7440-41-7 Cadmium 0.64J ug/L 1.0 0.40 1 07/07/21 12:50 07/08/2100:27 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/07/2112:50 07/08/2100:27 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/07/2112:50 07/08/2100:27 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/07/2112:50 07/08/2100:27 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/07/2112:50 07/08/2100:27 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/07/2112:50 07/08/2100:27 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/07/2112:50 07/08/2100:27 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/07/2112:50 07/08/2100:27 7440-22-4 Tin ND ug/L 5.0 4.7 1 07/07/2112:50 07/08/2100:27 7440-31-5 Vanadium ND ug/L 5.0 3.9 1 07/07/2112:50 07/08/2100:27 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/07/2112:50 07/08/2100:27 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:25 07/08/2100:53 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 0.16J ug/L 0.20 0.12 1 06/25/2114:37 06/29/2113:21 7439-97-6 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Acenaphthene ND ug/L 8.3 1.7 1 06/30/21 07:08 07/01/21 13:34 83-32-9 Acenaphthylene ND ug/L 8.3 1.6 1 06/30/21 07:08 07/01/21 13:34 208-96-8 Acetophenone ND ug/L 8.3 1.2 1 06/30/21 07:08 07/01/21 13:34 98-86-2 2-Acetylaminofluorene ND ug/L 8.3 3.4 1 06/30/21 07:08 07/01/21 13:34 53-96-3 4-Aminobiphenyl ND ug/L 8.3 4.0 1 06/30/21 07:08 07/01/21 13:34 92-67-1 Anthracene ND ug/L 8.3 1.9 1 06/30/21 07:08 07/01/21 13:34 120-12-7 Benzo(a)anthracene ND ug/L 8.3 2.2 1 06/30/21 07:08 07/01/21 13:34 56-55-3 Benzo(a)pyrene ND ug/L 8.3 2.3 1 06/30/21 07:08 07/01/21 13:34 50-32-8 Benzo(b)fluoranthene ND ug/L 8.3 2.2 1 06/30/21 07:08 07/01/21 13:34 205-99-2 Benzo(g,h,i)perylene ND ug/L 8.3 2.4 1 06/30/21 07:08 07/01/21 13:34 191-24-2 Benzo(k)fluoranthene ND ug/L 8.3 2.3 1 06/30/21 07:08 07/01/21 13:34 207-08-9 Benzyl alcohol ND ug/L 16.7 2.4 1 06/30/21 07:08 07/01/21 13:34 100-51-6 4-Bromophenylphenyl ether ND ug/L 8.3 1.5 1 06/30/21 07:08 07/01/21 13:34 101-55-3 Butylbenzylphthalate ND ug/L 8.3 2.6 1 06/30/21 07:08 07/01/21 13:34 85-68-7 4-Chloro-3-methyl phenol ND ug/L 8.3 2.8 1 06/30/21 07:08 07/01/21 13:34 59-50-7 4-Chloroaniline ND ug/L 16.7 3.0 1 06/30/21 07:08 07/01/21 13:34 106-47-8 Chlorobenzilate ND ug/L 8.3 3.2 1 06/30/21 07:08 07/01/21 13:34 510-15-6 bis(2-Chloroethoxy)methane ND ug/L 8.3 1.5 1 06/30/21 07:08 07/01/21 13:34 111-91-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-10 Lab ID: 92546352020 Collected: 06/23/21 08:14 Received: 06/24/21 07:00 Matrix: Water Comments: • Chlorinated Acid Herbicides (GC) by Method 8151 - No extra bottles, cannot be re -extracted Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte bis(2-Chloroethyl) ether ND ug/L 8.3 1.6 1 06/30/21 07:08 07/01/21 13:34 111-44-4 2-Chloronaphthalene ND ug/L 8.3 1.4 1 06/30/21 07:08 07/01/21 13:34 91-58-7 2-Chlorophenol ND ug/L 8.3 1.0 1 06/30/21 07:08 07/01/21 13:34 95-57-8 4-Chlorophenylphenyl ether ND ug/L 8.3 1.7 1 06/30/21 07:08 07/01/21 13:34 7005-72-3 Chrysene ND ug/L 8.3 2.3 1 06/30/21 07:08 07/01/21 13:34 218-01-9 Diallate ND ug/L 8.3 2.8 1 06/30/21 07:08 07/01/21 13:34 2303-16-4 Dibenz(a,h)anthracene ND ug/L 8.3 2.5 1 06/30/21 07:08 07/01/21 13:34 53-70-3 Dibenzofuran ND ug/L 8.3 1.8 1 06/30/21 07:08 07/01/21 13:34 132-64-9 3,3'-Dichlorobenzidine ND ug/L 16.7 6.8 1 06/30/21 07:08 07/01/21 13:34 91-94-1 2,4-Dichlorophenol ND ug/L 8.3 1.2 1 06/30/21 07:08 07/01/21 13:34 120-83-2 2,6-Dichlorophenol ND ug/L 8.3 3.5 1 06/30/21 07:08 07/01/21 13:34 87-65-0 Diethylphthalate ND ug/L 8.3 1.7 1 06/30/21 07:08 07/01/21 13:34 84-66-2 Dimethoate ND ug/L 8.3 3.0 1 06/30/21 07:08 07/01/21 13:34 60-51-5 P-Dimethylaminoazobenzene ND ug/L 4.2 2.0 1 06/30/21 07:08 07/01/21 13:34 60-11-7 IL 7,12-Dimethylbenz(a)anthracene ND ug/L 8.3 2.5 1 06/30/21 07:08 07/01/21 13:34 57-97-6 3,3'-Dimethylbenzidine ND ug/L 41.7 25.9 1 06/30/21 07:08 07/01/21 13:34 119-93-7 IH 2,4-Dimethylphenol ND ug/L 8.3 1.4 1 06/30/21 07:08 07/01/21 13:34 105-67-9 Dimethylphthalate ND ug/L 8.3 1.8 1 06/30/21 07:08 07/01/21 13:34 131-11-3 Di-n-butylphthalate ND ug/L 8.3 1.8 1 06/30/21 07:08 07/01/21 13:34 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 16.7 2.8 1 06/30/21 07:08 07/01/21 13:34 534-52-1 1,3-Dinitrobenzene ND ug/L 8.3 3.1 1 06/30/21 07:08 07/01/21 13:34 99-65-0 2,4-Dinitrophenol ND ug/L 41.7 21.7 1 06/30/21 07:08 07/01/21 13:34 51-28-5 v1 2,4-Dinitrotoluene ND ug/L 8.3 1.4 1 06/30/21 07:08 07/01/21 13:34 121-14-2 2,6-Dinitrotoluene ND ug/L 8.3 1.4 1 06/30/21 07:08 07/01/21 13:34 606-20-2 Di-n-octylphthalate ND ug/L 8.3 3.3 1 06/30/21 07:08 07/01/21 13:34 117-84-0 v1 Diphenylamine ND ug/L 8.3 2.5 1 06/30/21 07:08 07/01/21 13:34 122-39-4 Disulfoton ND ug/L 8.3 3.9 1 06/30/21 07:08 07/01/21 13:34 298-04-4 bis(2- Ethyl hexyl)phthalate ND ug/L 5.0 3.1 1 06/30/21 07:08 07/01/21 13:34 117-81-7 Ethyl methanesulfonate ND ug/L 16.7 2.5 1 06/30/21 07:08 07/01/21 13:34 62-50-0 Famphur ND ug/L 8.3 5.1 1 06/30/21 07:08 07/01/21 13:34 52-85-7 IH Fluoranthene ND ug/L 8.3 1.8 1 06/30/21 07:08 07/01/21 13:34 206-44-0 Fluorene ND ug/L 8.3 1.7 1 06/30/21 07:08 07/01/21 13:34 86-73-7 Hexachlorobenzene ND ug/L 8.3 1.8 1 06/30/21 07:08 07/01/21 13:34 118-74-1 Hexachlorocyclopentadiene ND ug/L 8.3 1.3 1 06/30/21 07:08 07/01/21 13:34 77-47-4 Hexachloroethane ND ug/L 8.3 1.2 1 06/30/21 07:08 07/01/21 13:34 67-72-1 Hexachloropropene ND ug/L 8.3 5.9 1 06/30/21 07:08 07/01/21 13:34 1888-71-7 Indeno(1,2,3-cd)pyrene ND ug/L 8.3 2.4 1 06/30/21 07:08 07/01/21 13:34 193-39-5 Isodrin ND ug/L 8.3 2.3 1 06/30/21 07:08 07/01/21 13:34 465-73-6 Isophorone ND ug/L 8.3 1.4 1 06/30/21 07:08 07/01/21 13:34 78-59-1 Isosafrole ND ug/L 8.3 2.1 1 06/30/21 07:08 07/01/21 13:34 120-58-1 Kepone ND ug/L 16.7 11.8 1 06/30/21 07:08 07/01/21 13:34 143-50-0 Methapyrilene ND ug/L 41.7 14.2 1 06/30/21 07:08 07/01/21 13:34 91-80-5 IH 3-Methylcholanthrene ND ug/L 8.3 4.8 1 06/30/21 07:08 07/01/21 13:34 56-49-5 Methyl methanesulfonate ND ug/L 4.2 2.6 1 06/30/21 07:08 07/01/21 13:34 66-27-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-10 Lab ID: 92546352020 Collected: 06/23/21 08:14 Received: 06/24/21 07:00 Matrix: Water Comments: • Chlorinated Acid Herbicides (GC) by Method 8151 - No extra bottles, cannot be re -extracted Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 2-Methylnaphthalene ND ug/L 8.3 1.6 1 06/30/21 07:08 07/01/21 13:34 91-57-6 Methyl parathion ND ug/L 8.3 3.1 1 06/30/21 07:08 07/01/21 13:34 298-00-0 2-Methylphenol(o-Cresol) ND ug/L 8.3 1.6 1 06/30/21 07:08 07/01/21 13:34 95-48-7 3&4-Methyl phenol (m&p Cresol) ND ug/L 8.3 1.0 1 06/30/21 07:08 07/01/21 13:34 15831-10-4 1-Naphthalenamine ND ug/L 4.2 3.4 1 06/30/21 07:08 07/01/21 13:34 134-32-7 2-Naphthalenamine ND ug/L 8.3 4.5 1 06/30/21 07:08 07/01/21 13:34 91-59-8 1,4-Naphthoquinone ND ug/L 4.2 3.7 1 06/30/21 07:08 07/01/21 13:34 130-15-4 2-Nitroaniline ND ug/L 16.7 2.5 1 06/30/21 07:08 07/01/21 13:34 88-74-4 3-Nitroaniline ND ug/L 16.7 3.1 1 06/30/21 07:08 07/01/21 13:34 99-09-2 4-Nitroaniline ND ug/L 16.7 4.2 1 06/30/21 07:08 07/01/21 13:34 100-01-6 Nitrobenzene ND ug/L 8.3 1.6 1 06/30/21 07:08 07/01/21 13:34 98-95-3 2-Nitrophenol ND ug/L 8.3 1.2 1 06/30/21 07:08 07/01/21 13:34 88-75-5 4-Nitrophenol ND ug/L 41.7 5.5 1 06/30/21 07:08 07/01/21 13:34 100-02-7 5-Nitro-o-toluidine ND ug/L 8.3 3.2 1 06/30/21 07:08 07/01/21 13:34 99-55-8 N-Nitrosodiethylamine ND ug/L 8.3 1.9 1 06/30/21 07:08 07/01/21 13:34 55-18-5 N-Nitrosodimethylamine ND ug/L 8.3 1.6 1 06/30/21 07:08 07/01/21 13:34 62-75-9 N-Nitroso-di-n-butylamine ND ug/L 8.3 7.3 1 06/30/21 07:08 07/01/21 13:34 924-16-3 N-Nitroso-di-n-propylamine ND ug/L 8.3 1.1 1 06/30/21 07:08 07/01/21 13:34 621-64-7 N-Nitrosodiphenylamine ND ug/L 8.3 2.5 1 06/30/21 07:08 07/01/21 13:34 86-30-6 N-Nitrosomethylethylamine ND ug/L 8.3 6.2 1 06/30/21 07:08 07/01/21 13:34 10595-95-6 N-Nitrosopiperidine ND ug/L 8.3 2.1 1 06/30/21 07:08 07/01/21 13:34 100-75-4 N-Nitrosopyrrolidine ND ug/L 8.3 2.6 1 06/30/21 07:08 07/01/21 13:34 930-55-2 O,O,O-Triethylphosphorothioate ND ug/L 8.3 2.1 1 06/30/21 07:08 07/01/21 13:34 126-68-1 2,2'-Oxybis(1-chloropropane) ND ug/L 8.3 0.96 1 06/30/21 07:08 07/01/21 13:34 108-60-1 Parathion (Ethyl parathion) ND ug/L 8.3 3.2 1 06/30/21 07:08 07/01/21 13:34 56-38-2 Pentachlorobenzene ND ug/L 8.3 2.8 1 06/30/21 07:08 07/01/21 13:34 608-93-5 Pentachloronitrobenzene ND ug/L 8.3 2.7 1 06/30/21 07:08 07/01/21 13:34 82-68-8 Pentachlorophenol ND ug/L 16.7 3.1 1 06/30/21 07:08 07/01/21 13:34 87-86-5 Phenacetin ND ug/L 8.3 3.0 1 06/30/21 07:08 07/01/21 13:34 62-44-2 Phenanthrene ND ug/L 8.3 1.7 1 06/30/21 07:08 07/01/21 13:34 85-01-8 Phenol ND ug/L 8.3 1.1 1 06/30/21 07:08 07/01/21 13:34 108-95-2 p-Phenylenediamine ND ug/L 8.3 8.3 1 06/30/21 07:08 07/01/21 13:34 106-50-3 Phorate ND ug/L 8.3 3.0 1 06/30/21 07:08 07/01/21 13:34 298-02-2 Pronamide ND ug/L 8.3 2.6 1 06/30/21 07:08 07/01/21 13:34 23950-58-5 Pyrene ND ug/L 8.3 1.8 1 06/30/21 07:08 07/01/21 13:34 129-00-0 Safrole ND ug/L 8.3 1.9 1 06/30/21 07:08 07/01/21 13:34 94-59-7 1,2,4,5-Tetrachlorobenzene ND ug/L 8.3 3.7 1 06/30/21 07:08 07/01/21 13:34 95-94-3 2,3,4,6-Tetrachlorophenol ND ug/L 8.3 1.3 1 06/30/21 07:08 07/01/21 13:34 58-90-2 Thionazin ND ug/L 8.3 2.4 1 06/30/21 07:08 07/01/21 13:34 297-97-2 O-Toluidine ND ug/L 8.3 2.2 1 06/30/21 07:08 07/01/21 13:34 95-53-4 2,4,5-Trichlorophenol ND ug/L 8.3 1.2 1 06/30/21 07:08 07/01/21 13:34 95-95-4 2,4,6-Trichlorophenol ND ug/L 8.3 1.3 1 06/30/21 07:08 07/01/21 13:34 88-06-2 1,3,5-Trinitrobenzene ND ug/L 8.3 4.6 1 06/30/21 07:08 07/01/21 13:34 99-35-4 v1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-10 Lab ID: 92546352020 Collected: 06/23/21 08:14 Received: 06/24/21 07:00 Matrix: Water Comments: • Chlorinated Acid Herbicides (GC) by Method 8151 - No extra bottles, cannot be re -extracted Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E APP9 RV Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte Surrogates Nitrobenzene-d5 (S) 58 % 10-144 1 06/30/21 07:08 07/01/21 13:34 4165-60-0 2-Fluorobiphenyl (S) 55 % 10-130 1 06/30/21 07:08 07/01/21 13:34 321-60-8 Terphenyl-d14 (S) 79 % 34-163 1 06/30/21 07:08 07/01/21 13:34 1718-51-0 Phenol-d6 (S) 29 % 10-130 1 06/30/21 07:08 07/01/21 13:34 13127-88-3 2-Fluorophenol (S) 40 % 10-130 1 06/30/21 07:08 07/01/21 13:34 367-12-4 2,4,6-Tribromophenol (S) 64 % 10-144 1 06/30/21 07:08 07/01/21 13:34 118-79-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/25/21 12:45 67-64-1 Acetonitrile ND ug/L 50.0 24.8 1 06/25/21 12:45 75-05-8 Acrolein ND ug/L 10.0 8.5 1 06/25/21 12:45 107-02-8 Acrylonitrile ND ug/L 10.0 1.8 1 06/25/21 12:45 107-13-1 Allyl chloride ND ug/L 2.0 0.50 1 06/25/21 12:45 107-05-1 Benzene 0.74J ug/L 1.0 0.34 1 06/25/21 12:45 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/25/21 12:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/25/21 12:45 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/25/21 12:45 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/25/21 12:45 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/25/21 12:45 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/25/21 12:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/25/21 12:45 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/25/21 12:45 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/25/21 12:45 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/25/21 12:45 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/25/21 12:45 74-87-3 v2 Chloroprene ND ug/L 5.0 1.6 1 06/25/21 12:45 126-99-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/25/21 12:45 124-48-1 Dibromomethane ND ug/L 1.0 0.39 1 06/25/21 12:45 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/25/21 12:45 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/25/21 12:45 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/25/21 12:45 110-57-6 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 06/25/21 12:45 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/25/21 12:45 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/25/21 12:45 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/25/21 12:45 75-35-4 cis-1,2-Dichloroethene 0.79J ug/L 1.0 0.38 1 06/25/21 12:45 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 06/25/21 12:45 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 06/25/21 12:45 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 06/25/21 12:45 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 06/25/21 12:45 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 06/25/21 12:45 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/25/21 12:45 10061-01-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Sample: MW-10 Lab ID: 92546352020 Collected: 06/23/21 08:14 Received: 06/24/21 07:00 Matrix: Water Comments: • Chlorinated Acid Herbicides (GC) by Method 8151 - No extra bottles, cannot be re -extracted Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte trans- 1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/25/21 12:45 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 38.7 1 06/25/21 12:45 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 06/25/21 12:45 100-41-4 Ethyl methacrylate ND ug/L 1.0 0.28 1 06/25/21 12:45 97-63-2 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 06/25/21 12:45 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 06/25/21 12:45 591-78-6 lodomethane ND ug/L 20.0 9.7 1 06/25/21 12:45 74-88-4 Isobutanol ND ug/L 100 52.3 1 06/25/21 12:45 78-83-1 Methacrylonitrile ND ug/L 10.0 4.2 1 06/25/21 12:45 126-98-7 Methylene Chloride ND ug/L 5.0 2.0 1 06/25/21 12:45 75-09-2 Methyl methacrylate ND ug/L 2.0 0.32 1 06/25/21 12:45 80-62-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 2.7 1 06/25/21 12:45 108-10-1 Naphthalene ND ug/L 1.0 0.64 1 06/25/21 12:45 91-20-3 Propionitrile ND ug/L 20.0 3.6 1 06/25/21 12:45 107-12-0 Styrene ND ug/L 1.0 0.29 1 06/25/21 12:45 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 06/25/21 12:45 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 06/25/21 12:45 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 06/25/21 12:45 127-18-4 Toluene ND ug/L 1.0 0.48 1 06/25/21 12:45 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.81 1 06/25/21 12:45 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 06/25/21 12:45 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 06/25/21 12:45 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 06/25/21 12:45 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 06/25/21 12:45 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 06/25/21 12:45 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 06/25/21 12:45 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 06/25/21 12:45 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/25/21 12:45 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 06/25/21 12:45 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 06/25/21 12:45 460-00-4 1,2-Dichloroethane-d4 (S) 89 % 70-130 1 06/25/21 12:45 17060-07-0 Toluene-d8 (S) 106 % 70-130 1 06/25/21 12:45 2037-26-5 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 50.0 1 06/25/2106:12 18496-25-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 1694955 Analysis Method: EPA 8151 QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151 Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 92546352020 METHOD BLANK: R3674682-1 Matrix: Water Associated Lab Samples: 92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 2,4-D ug/L ND 2.00 0.547 06/29/21 12:12 2,4,5-T ug/L ND 2.00 0.258 06/29/21 12:12 2,4,5-TP (Silvex) ug/L ND 2.00 0.335 06/29/21 12:12 2,4-DCAA (S) % 8.1 14.0-158 06/29/21 12:12 SR LABORATORY CONTROL SAMPLE & LCSD: R3674682-2 R3674682-3 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 2,4-D ug/L 5.00 ND ND 0.00 0.00 50.0-120 0.00 20 LO 2,4,5-T ug/L 5.00 ND 0.296 0.00 5.92 54.0-120 200 20 L0,R1 2,4,5-TP (Silvex) ug/L 5.00 0.914 1.18 18.3 23.6 50.0-125 25.4 20 L0,R1 2,4-DCAA (S) % 22.2 29.6 14.0-158 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629680 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352007, 92546352020 METHOD BLANK: 3309244 Matrix: Water Associated Lab Samples: 92546352007, 92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 06/28/2115:32 LABORATORY CONTROL SAMPLE: 3309245 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.2 87 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3309246 3309247 MS MSD 92545594008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.3 96 93 75-125 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 631735 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018,92546352019,92546352020 METHOD BLANK: 3318724 Matrix: Water Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018,92546352019,92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 07/07/2122:49 Arsenic ug/L ND 10.0 4.7 07/07/2122:49 Barium ug/L ND 5.0 3.5 07/07/2122:49 Beryllium ug/L ND 1.0 0.70 07/07/2122:49 Cadmium ug/L ND 1.0 0.40 07/07/2122:49 Chromium ug/L ND 5.0 3.7 07/07/2122:49 Cobalt ug/L ND 5.0 3.6 07/07/2122:49 Copper ug/L ND 5.0 4.3 07/07/2122:49 Lead ug/L ND 5.0 4.5 07/07/2122:49 Nickel ug/L ND 5.0 3.5 07/07/2122:49 Selenium ug/L ND 10.0 4.7 07/07/2122:49 Silver ug/L ND 5.0 2.5 07/07/2122:49 Tin ug/L ND 5.0 4.7 07/07/2122:49 Vanadium ug/L ND 5.0 3.9 07/07/2122:49 Zinc ug/L ND 10.0 9.5 07/07/2122:49 LABORATORY CONTROL SAMPLE: Parameter 3318725 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 474 95 80-120 Arsenic ug/L 500 495 99 80-120 Barium ug/L 500 484 97 80-120 Beryllium ug/L 500 500 100 80-120 Cadmium ug/L 500 494 99 80-120 Chromium ug/L 500 530 106 80-120 Cobalt ug/L 500 471 94 80-120 Copper ug/L 500 508 102 80-120 Lead ug/L 500 477 95 80-120 Nickel ug/L 500 498 100 80-120 Selenium ug/L 500 457 91 80-120 Silver ug/L 250 251 100 80-120 Tin ug/L 500 481 96 80-120 Vanadium ug/L 500 514 103 80-120 Zinc ug/L 500 474 95 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92546352 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3318726 3318727 MS MSD 92546352001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 471 463 94 93 75-125 2 20 Arsenic ug/L 8.OJ 500 500 504 485 99 95 75-125 4 20 Barium ug/L 11.2 500 500 490 482 96 94 75-125 2 20 Beryllium ug/L ND 500 500 496 489 99 98 75-125 2 20 Cadmium ug/L 1.8 500 500 506 496 101 99 75-125 2 20 Chromium ug/L ND 500 500 535 528 107 106 75-125 1 20 Cobalt ug/L ND 500 500 472 461 94 92 75-125 2 20 Copper ug/L ND 500 500 499 494 100 99 75-125 1 20 Lead ug/L ND 500 500 480 472 96 94 75-125 2 20 Nickel ug/L 4.8J 500 500 505 495 100 98 75-125 2 20 Selenium ug/L ND 500 500 490 482 97 96 75-125 2 20 Silver ug/L ND 250 250 253 250 101 100 75-125 1 20 Tin ug/L ND 500 500 482 472 96 94 75-125 2 20 Vanadium ug/L ND 500 500 514 509 103 102 75-125 1 20 Zinc ug/L ND 500 500 494 484 98 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 631740 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018,92546352019,92546352020 METHOD BLANK: 3318731 Matrix: Water Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018,92546352019,92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 07/07/2122:33 LABORATORY CONTROL SAMPLE: 3318732 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 24.8 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3318733 3318734 MS MSD 92546352002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 24.6 24.4 98 98 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629501 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018 METHOD BLANK: 3308394 Matrix: Water Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/25/21 07:04 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/25/21 07:04 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/25/21 07:04 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/25/21 07:04 1,1-Dichloroethane ug/L ND 1.0 0.37 06/25/21 07:04 1,1-Dichloroethene ug/L ND 1.0 0.35 06/25/21 07:04 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/25/21 07:04 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/25/21 07:04 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 06/25/21 07:04 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/25/21 07:04 1,2-Dichloroethane ug/L ND 1.0 0.32 06/25/21 07:04 1,2-Dichloropropane ug/L ND 1.0 0.36 06/25/21 07:04 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/25/21 07:04 1,4-Dioxane (p-Dioxane) ug/L ND 150 38.7 06/25/21 07:04 2-Butanone (MEK) ug/L ND 5.0 4.0 06/25/21 07:04 2-Hexanone ug/L ND 5.0 0.48 06/25/21 07:04 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 06/25/21 07:04 Acetone ug/L ND 25.0 5.1 06/25/21 07:04 Acrylonitrile ug/L ND 10.0 1.8 06/25/21 07:04 Benzene ug/L ND 1.0 0.34 06/25/21 07:04 Bromochloromethane ug/L ND 1.0 0.47 06/25/21 07:04 Bromodichloromethane ug/L ND 1.0 0.31 06/25/21 07:04 Bromoform ug/L ND 1.0 0.34 06/25/21 07:04 Bromomethane ug/L ND 2.0 1.7 06/25/21 07:04 Carbon disulfide ug/L ND 2.0 0.73 06/25/21 07:04 Carbon tetrachloride ug/L ND 1.0 0.33 06/25/21 07:04 Chlorobenzene ug/L ND 1.0 0.28 06/25/21 07:04 Chloroethane ug/L ND 1.0 0.65 06/25/21 07:04 Chloroform ug/L ND 5.0 1.6 06/25/21 07:04 Chloromethane ug/L ND 1.0 0.54 06/25/21 07:04 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/25/21 07:04 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/25/21 07:04 Dibromochloromethane ug/L ND 1.0 0.36 06/25/21 07:04 Dibromomethane ug/L ND 1.0 0.39 06/25/21 07:04 Ethylbenzene ug/L ND 1.0 0.30 06/25/21 07:04 lodomethane ug/L ND 20.0 9.7 06/25/21 07:04 Methylene Chloride ug/L ND 5.0 2.0 06/25/21 07:04 v2 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 METHOD BLANK: 3308394 Matrix: Water Associated Lab Samples: 92546352001, 92546352002, 92546352003, 92546352004, 92546352005, 92546352006, 92546352007, 92546352008,92546352009,92546352010,92546352011,92546352012,92546352013,92546352014, 92546352015,92546352016,92546352017,92546352018 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Styrene ug/L ND 1.0 0.29 06/25/21 07:04 Tetrachloroethene ug/L ND 1.0 0.29 06/25/21 07:04 Toluene ug/L ND 1.0 0.48 06/25/21 07:04 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/25/21 07:04 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 06/25/21 07:04 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 06/25/21 07:04 Trichloroethene ug/L ND 1.0 0.38 06/25/21 07:04 Trichlorofluoromethane ug/L ND 1.0 0.30 06/25/21 07:04 Vinyl acetate ug/L ND 2.0 1.3 06/25/21 07:04 Vinyl chloride ug/L ND 1.0 0.39 06/25/21 07:04 v2 Xylene (Total) ug/L ND 1.0 0.34 06/25/21 07:04 1,2-Dichloroethane-d4 (S) % 98 70-130 06/25/21 07:04 4-Bromofluorobenzene (S) % 100 70-130 06/25/21 07:04 Toluene-d8 (S) % 98 70-130 06/25/21 07:04 LABORATORY CONTROL SAMPLE: Parameter 3308395 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.7 101 70-130 1,1,1-Trichloroethane ug/L 50 43.4 87 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.7 99 70-130 1,1,2-Trichloroethane ug/L 50 46.2 92 70-130 1,1-Dichloroethane ug/L 50 44.4 89 70-130 1,1-Dichloroethene ug/L 50 43.5 87 70-132 1,2,3-Trichloropropane ug/L 50 49.9 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.6 107 70-132 1,2-Dibromoethane (EDB) ug/L 50 51.1 102 70-130 1,2-Dichlorobenzene ug/L 50 50.2 100 70-130 1,2-Dichloroethane ug/L 50 43.3 87 70-130 1,2-Dichloropropane ug/L 50 45.5 91 70-130 1,4-Dichlorobenzene ug/L 50 50.7 101 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1010 101 70-137 2-Butanone (MEK) ug/L 100 86.5 86 70-133 2-Hexanone ug/L 100 91.3 91 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 90.6 91 70-130 Acetone ug/L 100 90.4 90 70-144 Acrylonitrile ug/L 250 218 87 70-130 Benzene ug/L 50 45.1 90 70-130 Bromochloromethane ug/L 50 48.2 96 70-130 Bromodichloromethane ug/L 50 45.3 91 70-130 Bromoform ug/L 50 51.2 102 70-131 Bromomethane ug/L 50 42.7 85 30-177 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: 3308395 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Carbon disulfide ug/L 50 43.0 86 70-133 Carbon tetrachloride ug/L 50 45.7 91 70-130 Chlorobenzene ug/L 50 50.0 100 70-130 Chloroethane ug/L 50 35.0 70 46-131 Chloroform ug/L 50 45.6 91 70-130 Chloromethane ug/L 50 37.0 74 49-130 v2 cis-1,2-Dichloroethene ug/L 50 44.1 88 70-130 cis-1,3-Dichloropropene ug/L 50 45.1 90 70-130 Dibromochloromethane ug/L 50 50.8 102 70-130 Dibromomethane ug/L 50 51.1 102 70-130 Ethylbenzene ug/L 50 48.7 97 70-130 lodomethane ug/L 100 82.2 82 47-140 v2 Methylene Chloride ug/L 50 40.8 82 68-130 Styrene ug/L 50 48.6 97 70-130 Tetrachloroethene ug/L 50 48.7 97 70-130 Toluene ug/L 50 46.0 92 70-130 trans-1,2-Dichloroethene ug/L 50 44.0 88 70-130 trans- 1,3-Dichloropropene ug/L 50 45.0 90 70-130 trans-1,4-Dichloro-2-butene ug/L 50 49.6 99 25-200 Trichloroethene ug/L 50 46.8 94 70-130 Trichlorofluoromethane ug/L 50 39.7 79 61-130 Vinyl acetate ug/L 100 95.0 95 70-140 Vinyl chloride ug/L 50 41.1 82 59-142 v2 Xylene (Total) ug/L 150 146 98 70-130 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308396 3308397 MS MSD 92546352018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.6 21.0 113 105 70-135 8 30 1,1,1-Trichloroethane ug/L ND 20 20 23.0 21.7 115 108 70-148 6 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.7 20.3 108 101 70-131 7 30 1,1,2-Trichloroethane ug/L ND 20 20 22.5 21.3 113 106 70-136 6 30 1,1-Dichloroethane ug/L ND 20 20 22.9 21.3 114 107 70-147 7 30 1,1-Dichloroethene ug/L ND 20 20 22.9 21.9 115 109 70-158 5 30 1,2,3-Trichloropropane ug/L ND 20 20 21.3 20.2 107 101 67-137 5 30 1,2-Dibromo-3- ug/L ND 20 20 22.6 20.6 113 103 69-136 9 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.4 20.8 107 104 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 21.6 20.1 108 100 70-133 8 30 1,2-Dichloroethane ug/L ND 20 20 21.4 20.2 107 101 67-138 6 30 1,2-Dichloropropane ug/L ND 20 20 21.7 21.6 109 108 70-138 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308396 3308397 MS MSD 92546352018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dichlorobenzene ug/L ND 20 20 21.7 19.8 109 99 70-133 9 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 435 451 109 113 69-146 4 30 2-Butanone (MEK) ug/L ND 40 40 47.0 44.4 117 111 61-147 6 30 2-Hexanone ug/L ND 40 40 44.9 42.3 112 106 67-139 6 30 4-Methyl-2-pentanone ug/L ND 40 40 44.5 42.2 111 106 67-136 5 30 (MIBK) Acetone ug/L ND 40 40 44.3 42.2 111 106 55-159 5 30 Acrylonitrile ug/L ND 100 100 114 107 114 107 68-140 6 30 Benzene ug/L ND 20 20 22.4 21.2 112 106 67-150 6 30 Bromochloromethane ug/L ND 20 20 23.6 21.3 118 106 70-146 11 30 Bromodichloromethane ug/L ND 20 20 22.3 21.3 111 107 70-138 4 30 Bromoform ug/L ND 20 20 22.6 21.7 113 109 57-138 4 30 Bromomethane ug/L ND 20 20 33.6 29.4 168 147 10-200 13 30 IH,v1 Carbon disulfide ug/L ND 20 20 23.0 22.0 115 110 70-152 5 30 Carbon tetrachloride ug/L ND 20 20 23.6 21.9 118 110 70-147 7 30 Chlorobenzene ug/L ND 20 20 22.4 21.1 112 105 70-137 6 30 Chloroethane ug/L ND 20 20 25.4 24.6 127 123 51-166 3 30 Chloroform ug/L ND 20 20 22.8 21.5 114 108 70-144 6 30 Chloromethane ug/L ND 20 20 24.7 23.3 124 116 24-161 6 30 cis-1,2-Dichloroethene ug/L ND 20 20 22.3 21.7 111 108 67-148 3 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.1 20.8 110 104 70-142 6 30 Dibromochloromethane ug/L ND 20 20 22.9 21.8 114 109 68-138 5 30 Dibromomethane ug/L ND 20 20 21.5 20.3 107 102 70-134 5 30 Ethylbenzene ug/L ND 20 20 22.4 20.8 112 104 68-143 7 30 lodomethane ug/L ND 40 40 34.8 33.6 84 81 20-161 4 30 v2 Methylene Chloride ug/L ND 20 20 22.0 21.0 110 105 64-148 5 30 Styrene ug/L ND 20 20 22.3 21.1 111 105 70-136 5 30 Tetrachloroethene ug/L ND 20 20 21.8 20.9 109 105 70-139 4 30 Toluene ug/L ND 20 20 22.5 21.0 112 105 47-157 7 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.3 22.1 116 111 70-149 5 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.6 21.0 113 105 70-138 7 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 26.0 23.4 130 117 31-145 10 30 IH,v1 Trichloroethene ug/L ND 20 20 22.0 21.0 110 105 70-149 5 30 Trichlorofluoromethane ug/L ND 20 20 22.5 20.9 112 105 61-154 7 30 Vinyl acetate ug/L ND 40 40 44.3 42.2 111 106 48-156 5 30 Vinyl chloride ug/L ND 20 20 24.2 22.5 121 113 55-172 7 30 Xylene (Total) ug/L ND 60 60 67.4 63.4 112 106 66-145 6 30 1,2-Dichloroethane-d4 (S) % 101 98 70-130 4-Bromofluorobenzene (S) % 101 99 70-130 Toluene-d8 (S) % 99 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629502 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546352019, 92546352020 METHOD BLANK: 3308398 Matrix: Water Associated Lab Samples: 92546352019, 92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/25/21 11:01 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/25/21 11:01 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/25/21 11:01 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/25/21 11:01 1,1-Dichloroethane ug/L ND 1.0 0.37 06/25/21 11:01 1,1-Dichloroethene ug/L ND 1.0 0.35 06/25/21 11:01 1,1-Dichloropropene ug/L ND 1.0 0.43 06/25/21 11:01 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 06/25/21 11:01 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/25/21 11:01 1,2,4-Trichlorobenzene ug/L ND 1.0 0.64 06/25/21 11:01 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/25/21 11:01 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 06/25/21 11:01 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/25/21 11:01 1,2-Dichloroethane ug/L ND 1.0 0.32 06/25/21 11:01 1,2-Dichloropropane ug/L ND 1.0 0.36 06/25/21 11:01 1,3-Dichloropropane ug/L ND 1.0 0.28 06/25/21 11:01 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/25/21 11:01 1,4-Dioxane (p-Dioxane) ug/L ND 150 38.7 06/25/21 11:01 2,2-Dichloropropane ug/L ND 1.0 0.39 06/25/21 11:01 2-Butanone (MEK) ug/L ND 5.0 4.0 06/25/21 11:01 2-Hexanone ug/L ND 5.0 0.48 06/25/21 11:01 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 06/25/21 11:01 Acetone ug/L ND 25.0 5.1 06/25/21 11:01 Acetonitrile ug/L ND 50.0 24.8 06/25/21 11:01 Acrolein ug/L ND 10.0 8.5 06/25/21 11:01 Acrylonitrile ug/L ND 10.0 1.8 06/25/21 11:01 Allyl chloride ug/L ND 2.0 0.50 06/25/21 11:01 Benzene ug/L ND 1.0 0.34 06/25/21 11:01 Bromochloromethane ug/L ND 1.0 0.47 06/25/21 11:01 Bromodichloromethane ug/L ND 1.0 0.31 06/25/21 11:01 Bromoform ug/L ND 1.0 0.34 06/25/21 11:01 Bromomethane ug/L ND 2.0 1.7 06/25/21 11:01 Carbon disulfide ug/L ND 2.0 0.73 06/25/21 11:01 Carbon tetrachloride ug/L ND 1.0 0.33 06/25/21 11:01 Chlorobenzene ug/L ND 1.0 0.28 06/25/21 11:01 Chloroethane ug/L ND 1.0 0.65 06/25/21 11:01 Chloroform ug/L ND 5.0 1.6 06/25/21 11:01 Chloromethane ug/L ND 1.0 0.54 06/25/21 11:01 v2 Chloroprene ug/L ND 5.0 1.6 06/25/21 11:01 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/25/21 11:01 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 METHOD BLANK: 3308398 Associated Lab Samples: 92546352019, 92546352020 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/25/21 11:01 Dibromochloromethane ug/L ND 1.0 0.36 06/25/21 11:01 Dibromomethane ug/L ND 1.0 0.39 06/25/21 11:01 Dichlorodifluoromethane ug/L ND 1.0 0.35 06/25/21 11:01 Ethyl methacrylate ug/L ND 1.0 0.28 06/25/21 11:01 Ethylbenzene ug/L ND 1.0 0.30 06/25/21 11:01 Hexachloro-1,3-butadiene ug/L ND 2.0 1.5 06/25/21 11:01 lodomethane ug/L ND 20.0 9.7 06/25/21 11:01 Isobutanol ug/L ND 100 52.3 06/25/21 11:01 Methacrylonitrile ug/L ND 10.0 4.2 06/25/21 11:01 Methyl methacrylate ug/L ND 2.0 0.32 06/25/21 11:01 Methylene Chloride ug/L ND 5.0 2.0 06/25/21 11:01 Naphthalene ug/L ND 1.0 0.64 06/25/21 11:01 Propionitrile ug/L ND 20.0 3.6 06/25/21 11:01 Styrene ug/L ND 1.0 0.29 06/25/21 11:01 Tetrachloroethene ug/L ND 1.0 0.29 06/25/21 11:01 Toluene ug/L ND 1.0 0.48 06/25/21 11:01 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/25/21 11:01 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 06/25/21 11:01 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 06/25/21 11:01 Trichloroethene ug/L ND 1.0 0.38 06/25/21 11:01 Trichlorofluoromethane ug/L ND 1.0 0.30 06/25/21 11:01 Vinyl acetate ug/L ND 2.0 1.3 06/25/21 11:01 Vinyl chloride ug/L ND 1.0 0.39 06/25/21 11:01 Xylene (Total) ug/L ND 1.0 0.34 06/25/21 11:01 1,2-Dichloroethane-d4 (S) % 92 70-130 06/25/21 11:01 4-Bromofluorobenzene (S) % 96 70-130 06/25/21 11:01 Toluene-d8 (S) % 105 70-130 06/25/21 11:01 LABORATORY CONTROL SAMPLE: Parameter 3308399 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.0 102 70-130 1,1,1-Trichloroethane ug/L 50 44.4 89 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.0 100 70-130 1,1,2-Trichloroethane ug/L 50 49.2 98 70-130 1,1-Dichloroethane ug/L 50 45.0 90 70-130 1,1-Dichloroethene ug/L 50 47.6 95 70-132 1,1-Dichloropropene ug/L 50 46.1 92 70-131 1,2,3-Trichlorobenzene ug/L 50 49.0 98 70-134 1,2,3-Trichloropropane ug/L 50 50.0 100 70-130 1,2,4-Trichlorobenzene ug/L 50 47.0 94 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.9 106 70-132 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: Parameter 3308399 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2-Dichlorobenzene ug/L 50 49.3 99 70-130 1,2-Dichloroethane ug/L 50 42.2 84 70-130 1,2-Dichloropropane ug/L 50 48.0 96 70-130 1,3-Dichloropropane ug/L 50 49.1 98 70-130 1,4-Dichlorobenzene ug/L 50 49.7 99 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1040 104 70-137 2,2-Dichloropropane ug/L 50 44.6 89 70-130 2-Butanone (MEK) ug/L 100 83.5 83 70-133 2-Hexanone ug/L 100 93.9 94 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 94.0 94 70-130 Acetone ug/L 100 88.1 88 70-144 Acetonitrile ug/L 500 422 84 68-134 Acrolein ug/L 250 233 93 32-200 Acrylonitrile ug/L 250 221 88 70-130 Allyl chloride ug/L 50 42.9 86 70-134 Benzene ug/L 50 47.7 95 70-130 Bromochloromethane ug/L 50 43.7 87 70-130 Bromodichloromethane ug/L 50 48.6 97 70-130 Bromoform ug/L 50 50.4 101 70-131 Bromomethane ug/L 50 51.2 102 30-177 Carbon disulfide ug/L 50 47.3 95 70-133 Carbon tetrachloride ug/L 50 49.7 99 70-130 Chlorobenzene ug/L 50 47.8 96 70-130 Chloroethane ug/L 50 58.6 117 46-131 Chloroform ug/L 50 44.5 89 70-130 Chloromethane ug/L 50 36.4 73 49-130 v3 Chloroprene ug/L 50 40.5 81 70-130 cis-1,2-Dichloroethene ug/L 50 42.6 85 70-130 cis-1,3-Dichloropropene ug/L 50 50.6 101 70-130 Dibromochloromethane ug/L 50 49.5 99 70-130 Dibromomethane ug/L 50 46.8 94 70-130 Dichlorodifluoromethane ug/L 50 42.1 84 52-134 Ethyl methacrylate ug/L 50 45.8 92 70-130 Ethylbenzene ug/L 50 47.2 94 70-130 Hexachloro-1,3-butadiene ug/L 50 51.4 103 70-131 lodomethane ug/L 100 104 104 47-140 Isobutanol ug/L 1000 780 78 62-136 Methacrylonitrile ug/L 500 415 83 70-130 Methyl methacrylate ug/L 50 45.0 90 70-130 Methylene Chloride ug/L 50 40.9 82 68-130 Naphthalene ug/L 50 49.6 99 70-133 Propionitrile ug/L 500 420 84 70-130 Styrene ug/L 50 48.5 97 70-130 Tetrachloroethene ug/L 50 48.4 97 70-130 Toluene ug/L 50 46.3 93 70-130 trans-1,2-Dichloroethene ug/L 50 47.0 94 70-130 trans- 1,3-Dichloropropene ug/L 50 50.2 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: 3308399 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers trans-1,4-Dichloro-2-butene ug/L 50 55.0 110 25-200 Trichloroethene ug/L 50 48.3 97 70-130 Trichlorofluoromethane ug/L 50 41.5 83 61-130 Vinyl acetate ug/L 100 90.8 91 70-140 Vinyl chloride ug/L 50 43.0 86 59-142 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 85 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308400 3308401 MS MSD 92546350001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.0 21.9 110 109 70-135 0 30 1,1,1-Trichloroethane ug/L ND 20 20 21.9 23.6 109 118 70-148 8 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.3 21.2 107 106 70-131 1 30 1,1,2-Trichloroethane ug/L ND 20 20 21.7 21.3 109 106 70-136 2 30 1,1-Dichloroethane ug/L 10.1 20 20 32.9 34.1 114 120 70-147 4 30 1,1-Dichloroethene ug/L ND 20 20 23.8 24.2 119 121 70-158 1 30 1,1-Dichloropropene ug/L ND 20 20 22.5 21.7 113 109 70-149 4 30 1,2,3-Trichlorobenzene ug/L ND 20 20 17.8 19.4 89 97 68-140 9 30 1,2,3-Trichooropropane ug/L ND 20 20 21.6 22.2 108 111 67-137 3 30 1,2,4-Trichlorobenzene ug/L ND 20 20 19.5 20.5 98 102 70-139 5 30 1,2-Dibromo-3- ug/L ND 20 20 21.2 19.7 106 98 69-136 8 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.2 22.5 111 112 70-137 1 30 1,2-Dichlorobenzene ug/L 0.62J 20 20 22.4 23.4 109 114 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 21.0 20.9 105 104 67-138 1 30 1,2-Dichloropropane ug/L ND 20 20 22.4 22.1 112 110 70-138 2 30 1,3-Dichloropropane ug/L ND 20 20 22.5 22.2 112 111 70-136 1 30 1,4-Dichlorobenzene ug/L ND 20 20 32.8 34.5 164 172 70-133 5 30 M1 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 461 429 115 107 69-146 7 30 2,2-Dichloropropane ug/L ND 20 20 19.9 20.9 99 104 52-155 5 30 2-Butanone (MEK) ug/L 6.2 40 40 45.2 48.1 97 105 61-147 6 30 2-Hexanone ug/L ND 40 40 35.8 36.3 89 91 67-139 2 30 4-Methyl-2-pentanone ug/L ND 40 40 39.9 37.3 97 91 67-136 7 30 (MIBK) Acetone ug/L ND 40 40 46.3 50.3 116 126 55-159 8 30 Acetonitrile ug/L ND 200 200 201 200 101 100 66-145 1 30 Acrolein ug/L ND 100 100 97.1 103 97 103 10-200 6 30 Acrylonitrile ug/L ND 100 100 105 104 105 104 68-140 1 30 Allyl chloride ug/L ND 20 20 21.1 21.9 105 109 70-147 4 30 Benzene ug/L 3.9 20 20 27.3 27.1 117 116 67-150 1 30 Bromochloromethane ug/L ND 20 20 21.0 21.2 105 106 70-146 1 30 Bromodichloromethane ug/L ND 20 20 21.7 21.8 108 109 70-138 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308400 3308401 MS MSD 92546350001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromoform ug/L ND 20 20 20.2 19.7 101 99 57-138 2 30 Bromomethane ug/L ND 20 20 23.7 24.2 119 121 10-200 2 30 Carbon disulfide ug/L ND 20 20 27.6 24.5 138 122 70-152 12 30 Carbon tetrachloride ug/L ND 20 20 24.2 23.4 121 117 70-147 3 30 Chlorobenzene ug/L 53.6 20 20 77.0 72.6 117 95 70-137 6 30 Chloroethane ug/L 4.3 20 20 30.7 29.3 132 125 51-166 5 30 Chloroform ug/L ND 20 20 23.8 21.9 119 110 70-144 8 30 Chloromethane ug/L ND 20 20 17.6 17.9 88 90 24-161 2 30 v3 Chloroprene ug/L ND 20 20 19.3 19.9 96 100 70-143 3 30 cis-1,2-Dichloroethene ug/L 14.8 20 20 36.7 37.2 110 112 67-148 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.2 21.0 106 105 70-142 1 30 Dibromochloromethane ug/L ND 20 20 20.7 21.1 103 105 68-138 2 30 Dibromomethane ug/L ND 20 20 21.4 21.0 107 105 70-134 2 30 Dichlorodifluoromethane ug/L ND 20 20 19.9 21.0 99 105 43-155 6 30 Ethyl methacrylate ug/L ND 20 20 19.8 19.2 99 96 70-137 3 30 Ethylbenzene ug/L 0.64J 20 20 23.4 22.8 114 111 68-143 2 30 Hexachloro-1,3-butadiene ug/L ND 20 20 19.9 21.6 100 108 62-151 8 30 lodomethane ug/L ND 40 40 45.8 52.7 115 132 20-161 14 30 Isobutanol ug/L ND 400 400 241 251 60 63 44-145 4 30 Methacrylonitrile ug/L ND 200 200 185 188 93 94 67-139 2 30 Methyl methacrylate ug/L ND 20 20 18.1 17.2 90 86 70-130 5 30 Methylene Chloride ug/L ND 20 20 20.6 22.6 95 105 64-148 9 30 Naphthalene ug/L 2.2 20 20 21.9 23.7 99 108 57-150 8 30 Propionitrile ug/L ND 200 200 187 188 94 94 70-138 0 30 Styrene ug/L ND 20 20 22.7 22.9 114 114 70-136 1 30 Tetrachloroethene ug/L ND 20 20 21.8 22.3 109 112 70-139 2 30 Toluene ug/L ND 20 20 22.6 22.0 110 108 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.0 23.5 115 117 70-149 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.0 19.9 105 99 70-138 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 18.0 17.4 90 87 31-145 4 30 Trichloroethene ug/L ND 20 20 22.3 22.4 112 112 70-149 0 30 Trichlorofluoromethane ug/L ND 20 20 21.7 21.8 108 109 61-154 1 30 Vinyl acetate ug/L ND 40 40 36.4 34.4 91 86 48-156 6 30 Vinyl chloride ug/L ND 20 20 23.3 23.9 117 120 55-172 3 30 Xylene (Total) ug/L 0.68J 60 60 70.0 69.9 115 115 66-145 0 30 1,2-Dichloroethane-d4 (S) % 88 93 70-130 4-Bromofluorobenzene (S) % 97 96 70-130 Toluene-d8 (S) % 98 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 630405 Analysis Method: EPA 8081 B QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546352020 METHOD BLANK: 3312334 Associated Lab Samples: 92546352020 Parameter 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC beta-BHC Chlordane (Technical) delta-BHC Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde gamma-BHC (Lindane) Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) Matrix: Water Units Blank Result Reporting Limit MDL Analyzed ug/L ND 0.050 0.012 06/30/21 17:19 ug/L ND 0.050 0.016 06/30/21 17:19 ug/L ND 0.050 0.048 06/30/21 17:19 ug/L ND 0.050 0.026 06/30/21 17:19 ug/L ND 0.050 0.026 06/30/21 17:19 ug/L ND 0.050 0.022 06/30/21 17:19 ug/L ND 0.50 0.21 06/30/21 17:19 ug/L ND 0.050 0.018 06/30/21 17:19 ug/L ND 0.050 0.013 06/30/21 17:19 ug/L ND 0.050 0.014 06/30/21 17:19 ug/L ND 0.050 0.017 06/30/21 17:19 ug/L ND 0.050 0.014 06/30/21 17:19 ug/L ND 0.050 0.014 06/30/21 17:19 ug/L ND 0.050 0.028 06/30/21 17:19 ug/L ND 0.050 0.020 06/30/21 17:19 ug/L ND 0.050 0.036 06/30/21 17:19 ug/L ND 0.050 0.015 06/30/21 17:19 ug/L ND 0.15 0.12 06/30/21 17:19 ug/L ND 0.50 0.27 06/30/21 17:19 % 66 10-154 06/30/21 17:19 % 51 10-184 06/30/21 17:19 LABORATORY CONTROL SAMPLE: 3312335 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD ug/L 0.25 0.20 82 45-158 4,4'-DDE ug/L 0.25 0.19 77 37-141 4,4'-DDT ug/L 0.25 0.15 59 52-160 Aldrin ug/L 0.25 0.12 48 10-130 alpha-BHC ug/L 0.25 0.17 68 37-139 beta-BHC ug/L 0.25 0.21 84 39-176 delta-BHC ug/L 0.25 0.12 49 39-144 Dieldrin ug/L 0.25 0.20 79 40-149 Endosulfan I ug/L 0.25 0.22 86 44-145 Endosulfan II ug/L 0.25 0.21 82 47-153 Endosulfan sulfate ug/L 0.25 0.20 82 48-159 Endrin ug/L 0.25 0.20 80 41-155 Endrin aldehyde ug/L 0.25 0.19 75 45-146 gamma-BHC (Lindane) ug/L 0.25 0.18 72 42-146 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: 3312335 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Heptachlor ug/L 0.25 0.13 52 23-135 Heptachlor epoxide ug/L 0.25 0.19 77 39-142 Methoxychlor ug/L 0.75 0.50 67 55-173 Decachlorobiphenyl (S) % 81 10-154 Tetrachloro-m-xylene (S) % 58 10-184 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3312336 3312337 MS MSD 92546352020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug/L ND 0.45 0.45 0.42 0.54 93 118 36-169 23 30 4,4'-DDE ug/L ND 0.45 0.45 0.42 0.55 92 122 31-154 28 30 4,4'-DDT ug/L ND 0.45 0.45 0.36 0.44 80 96 23-187 19 30 Aldrin ug/L ND 0.45 0.45 0.37 0.47 81 103 10-141 24 30 alpha-BHC ug/L ND 0.45 0.45 0.36 0.45 79 98 25-151 21 30 beta-BHC ug/L ND 0.45 0.45 0.53 0.60 116 132 30-188 14 30 delta-BHC ug/L ND 0.45 0.45 0.32 0.39 70 86 32-157 20 30 Dieldrin ug/L ND 0.45 0.45 0.40 0.55 88 121 24-165 32 30 R1 Endosulfan I ug/L ND 0.45 0.45 0.43 0.58 96 127 19-168 29 30 Endosulfan II ug/L ND 0.45 0.45 0.43 0.54 95 119 27-176 22 30 Endosulfan sulfate ug/L ND 0.45 0.45 0.45 0.54 98 119 31-174 19 30 Endrin ug/L ND 0.45 0.45 0.41 0.53 90 116 23-171 25 30 Endrin aldehyde ug/L ND 0.45 0.45 0.36 0.43 78 95 16-177 20 30 gamma-BHC (Lindane) ug/L ND 0.45 0.45 0.39 0.48 86 105 29-157 19 30 Heptachlor ug/L ND 0.45 0.45 0.35 0.45 77 98 11-149 23 30 Heptachlor epoxide ug/L ND 0.45 0.45 0.44 0.54 96 119 21-157 21 30 Methoxychlor ug/L ND 1.4 1.4 1.1 1.4 77 101 33-193 27 30 Decachlorobiphenyl (S) % 79 106 10-154 Tetrachloro-m-xylene (S) % 73 84 10-184 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629921 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546352020 METHOD BLANK: 3310141 Matrix: Water Associated Lab Samples: 92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.47 06/30/21 00:10 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.45 06/30/21 00:10 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.36 06/30/21 00:10 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.26 06/30/21 00:10 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.40 06/30/21 00:10 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.25 06/30/21 00:10 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.42 06/30/21 00:10 Decachlorobiphenyl (S) % 103 10-181 06/30/21 00:10 LABORATORY CONTROL SAMPLE: 3310142 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 4.9 99 41-137 PCB-1260 (Aroclor 1260) ug/L 5 4.7 93 42-156 Decachlorobiphenyl (S) % 95 10-181 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3310143 3310144 MS MSD 92546080011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 10 10 7.5 9.7 75 97 22-145 25 30 PCB-1260 (Aroclor 1260) ug/L ND 10 10 3.4 3.2 34 32 10-167 6 30 Decachlorobiphenyl (S) % 27 33 10-181 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 630391 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546352020 METHOD BLANK: 3312218 Associated Lab Samples: 92546352020 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 4.5 07/01/21 11:24 1,3,5-Trinitrobenzene ug/L ND 10.0 5.5 07/01/21 11:24 v1 1,3-Dinitrobenzene ug/L ND 10.0 3.8 07/01/21 11:24 1,4-Naphthoquinone ug/L ND 5.0 4.4 07/01/21 11:24 1-Naphthalenamine ug/L ND 5.0 4.1 07/01/21 11:24 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 1.2 07/01/21 11:24 2,3,4,6-Tetrachlorophenol ug/L ND 10.0 1.5 07/01/21 11:24 2,4,5-Trichlorophenol ug/L ND 10.0 1.4 07/01/21 11:24 2,4,6-Trichlorophenol ug/L ND 10.0 1.6 07/01/21 11:24 2,4-Dichlorophenol ug/L ND 10.0 1.4 07/01/21 11:24 2,4-Dimethylphenol ug/L ND 10.0 1.7 07/01/21 11:24 2,4-Dinitrophenol ug/L ND 50.0 26.0 07/01/21 11:24 v1 2,4-Dinitrotoluene ug/L ND 10.0 1.6 07/01/21 11:24 2,6-Dichlorophenol ug/L ND 10.0 4.2 07/01/21 11:24 2,6-Dinitrotoluene ug/L ND 10.0 1.7 07/01/21 11:24 2-Acetylaminofluorene ug/L ND 10.0 4.1 07/01/21 11:24 2-Chloronaphthalene ug/L ND 10.0 1.7 07/01/21 11:24 2-Chlorophenol ug/L ND 10.0 1.2 07/01/21 11:24 2-Methylnaphthalene ug/L ND 10.0 1.9 07/01/21 11:24 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.9 07/01/21 11:24 2-Naphthalenamine ug/L ND 10.0 5.4 07/01/21 11:24 2-Nitroaniline ug/L ND 20.0 3.0 07/01/21 11:24 2-Nitrophenol ug/L ND 10.0 1.4 07/01/21 11:24 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 1.2 07/01/21 11:24 3,3'-Dichlorobenzidine ug/L ND 20.0 8.1 07/01/21 11:24 3,3'-Dimethylbenzidine ug/L ND 50.0 31.1 07/01/21 11:24 IH 3-Methylcholanthrene ug/L ND 10.0 5.8 07/01/21 11:24 3-Nitroaniline ug/L ND 20.0 3.8 07/01/21 11:24 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 3.4 07/01/21 11:24 4-Aminobiphenyl ug/L ND 10.0 4.7 07/01/21 11:24 4-Bromophenylphenyl ether ug/L ND 10.0 1.8 07/01/21 11:24 4-ChIoro-3-methyl phenol ug/L ND 10.0 3.3 07/01/21 11:24 4-Chloroaniline ug/L ND 20.0 3.6 07/01/21 11:24 4-Chlorophenylphenyl ether ug/L ND 10.0 2.0 07/01/21 11:24 4-Nitroaniline ug/L ND 20.0 5.1 07/01/21 11:24 4-Nitrophenol ug/L ND 50.0 6.6 07/01/21 11:24 5-Nitro-o-toluidine ug/L ND 10.0 3.8 07/01/21 11:24 7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 3.0 07/01/21 11:24 Acenaphthene ug/L ND 10.0 2.0 07/01/21 11:24 Acenaphthylene ug/L ND 10.0 2.0 07/01/21 11:24 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 METHOD BLANK: 3312218 Associated Lab Samples: 92546352020 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Acetophenone ug/L ND 10.0 1.5 07/01/21 11:24 Anthracene ug/L ND 10.0 2.3 07/01/21 11:24 Benzo(a)anthracene ug/L ND 10.0 2.7 07/01/21 11:24 Benzo(a)pyrene ug/L ND 10.0 2.8 07/01/21 11:24 Benzo(b)fluoranthene ug/L ND 10.0 2.6 07/01/21 11:24 Benzo(g,h,i)perylene ug/L ND 10.0 2.8 07/01/21 11:24 Benzo(k)fluoranthene ug/L ND 10.0 2.7 07/01/21 11:24 Benzyl alcohol ug/L ND 20.0 2.9 07/01/21 11:24 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.8 07/01/21 11:24 bis(2-Chloroethyl) ether ug/L ND 10.0 1.9 07/01/21 11:24 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 3.7 07/01/21 11:24 Butylbenzylphthalate ug/L ND 10.0 3.1 07/01/21 11:24 Chlorobenzilate ug/L ND 10.0 3.8 07/01/21 11:24 Chrysene ug/L ND 10.0 2.8 07/01/21 11:24 Di-n-butylphthalate ug/L ND 10.0 2.2 07/01/21 11:24 Di-n-octylphthalate ug/L ND 10.0 3.9 07/01/21 11:24 Diallate ug/L ND 10.0 3.4 07/01/21 11:24 Dibenz(a,h)anthracene ug/L ND 10.0 3.0 07/01/21 11:24 Dibenzofuran ug/L ND 10.0 2.1 07/01/21 11:24 Diethylphthalate ug/L ND 10.0 2.0 07/01/21 11:24 Dimethoate ug/L ND 10.0 3.7 07/01/21 11:24 Dimethylphthalate ug/L ND 10.0 2.1 07/01/21 11:24 Diphenylamine ug/L ND 10.0 3.0 07/01/21 11:24 Disulfoton ug/L ND 10.0 4.6 07/01/21 11:24 Ethyl methanesulfonate ug/L ND 20.0 3.0 07/01/21 11:24 Famphur ug/L ND 10.0 6.1 07/01/21 11:24 Fluoranthene ug/L ND 10.0 2.2 07/01/21 11:24 Fluorene ug/L ND 10.0 2.1 07/01/21 11:24 Hexachlorobenzene ug/L ND 10.0 2.2 07/01/21 11:24 Hexachlorocyclopentadiene ug/L ND 10.0 1.6 07/01/21 11:24 Hexachloroethane ug/L ND 10.0 1.4 07/01/21 11:24 Hexachloropropene ug/L ND 10.0 7.0 07/01/21 11:24 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 2.9 07/01/21 11:24 Isodrin ug/L ND 10.0 2.8 07/01/21 11:24 Isophorone ug/L ND 10.0 1.7 07/01/21 11:24 Isosafrole ug/L ND 10.0 2.5 07/01/21 11:24 Kepone ug/L ND 20.0 14.1 07/01/21 11:24 Methapyrilene ug/L ND 50.0 17.0 07/01/21 11:24 Methyl methanesulfonate ug/L ND 5.0 3.1 07/01/21 11:24 Methyl parathion ug/L ND 10.0 3.7 07/01/21 11:24 N-Nitroso-di-n-butylamine ug/L ND 10.0 8.7 07/01/21 11:24 N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 07/01/21 11:24 N-Nitrosodiethylamine ug/L ND 10.0 2.3 07/01/21 11:24 N-Nitrosodimethylamine ug/L ND 10.0 1.9 07/01/21 11:24 N-Nitrosodiphenylamine ug/L ND 10.0 3.0 07/01/21 11:24 v1 IH IH Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 91 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 METHOD BLANK: 3312218 Associated Lab Samples: 92546352020 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers N-Nitrosomethylethylamine ug/L ND 10.0 7.5 07/01/21 11:24 N-Nitrosopiperidine ug/L ND 10.0 2.5 07/01/21 11:24 N-Nitrosopyrrolidine ug/L ND 10.0 3.1 07/01/21 11:24 Nitrobenzene ug/L ND 10.0 1.9 07/01/21 11:24 O,O,O-Triethylphosphorothioate ug/L ND 10.0 2.6 07/01/21 11:24 O-Toluidine ug/L ND 10.0 2.6 07/01/21 11:24 P-Dimethylaminoazobenzene ug/L ND 5.0 2.4 07/01/21 11:24 IL p-Phenylenediamine ug/L ND 10.0 10.0 07/01/21 11:24 Parathion (Ethyl parathion) ug/L ND 10.0 3.9 07/01/21 11:24 Pentachlorobenzene ug/L ND 10.0 3.4 07/01/21 11:24 Pentachloronitrobenzene ug/L ND 10.0 3.3 07/01/21 11:24 Pentachlorophenol ug/L ND 20.0 3.8 07/01/21 11:24 Phenacetin ug/L ND 10.0 3.6 07/01/21 11:24 Phenanthrene ug/L ND 10.0 2.0 07/01/21 11:24 Phenol ug/L ND 10.0 1.4 07/01/21 11:24 Phorate ug/L ND 10.0 3.6 07/01/21 11:24 Pronamide ug/L ND 10.0 3.1 07/01/21 11:24 Pyrene ug/L ND 10.0 2.2 07/01/21 11:24 Safrole ug/L ND 10.0 2.3 07/01/21 11:24 Thionazin ug/L ND 10.0 2.9 07/01/21 11:24 2,4,6-Tribromophenol (S) % 101 10-144 07/01/21 11:24 2-Fluorobiphenyl (S) % 88 10-130 07/01/21 11:24 2-Fluorophenol(S) % 70 10-130 07/01/21 11:24 Nitrobenzene-d5 (S) % 98 10-144 07/01/21 11:24 Phenol-d6 (S) % 53 10-130 07/01/21 11:24 Terphenyl-d14 (S) % 124 34-163 07/01/21 11:24 LABORATORY CONTROL SAMPLE: Parameter 3312219 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4,5-Tetrachlorobenzene ug/L 50 27.3 55 17-130 1,3,5-Trinitrobenzene ug/L 50 71.2 142 44-200 v1 1,3-Dinitrobenzene ug/L 50 59.3 119 39-159 1,4-Naphthoquinone ug/L 50 45.7 91 10-159 1-Naphthalenamine ug/L 50 49.4 99 10-130 2,2'-Oxybis(1-chloropropane) ug/L 50 51.7 103 28-130 2,3,4,6-Tetrachlorophenol ug/L 50 51.3 103 10-200 2,4,5-Trichlorophenol ug/L 50 50.7 101 35-130 2,4,6-Trichlorophenol ug/L 50 48.9 98 31-130 2,4-Dichlorophenol ug/L 50 49.5 99 35-130 2,4-Dimethylphenol ug/L 50 47.8 96 34-130 2,4-Dinitrophenol ug/L 250 303 121 10-153 v1 2,4-Dinitrotoluene ug/L 50 54.2 108 37-136 2,6-Dichlorophenol ug/L 50 50.7 101 31-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: Parameter 3312219 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 2,6-Dinitrotoluene ug/L 50 54.9 110 33-136 2-Acetylaminofluorene ug/L 50 38.5 77 19-181 2-Chloronaphthalene ug/L 50 37.4 75 26-130 2-Chlorophenol ug/L 50 46.3 93 37-130 2-Methylnaphthalene ug/L 50 37.9 76 29-130 2-Methylphenol(o-Cresol) ug/L 50 45.8 92 35-130 2-Naphthalenamine ug/L 50 48.5 97 10-136 2-Nitroaniline ug/L 100 106 106 37-130 2-Nitrophenol ug/L 50 49.9 100 32-130 3&4-Methyl phenol (m&p Cresol) ug/L 50 50.4 101 34-130 3,3'-Dichlorobenzidine ug/L 100 110 110 34-136 3,3'-Dimethylbenzidine ug/L 100 181 181 10-2001H 3-Methylcholanthrene ug/L 50 50.7 101 39-190 3-Nitroaniline ug/L 100 112 112 37-138 4,6-Dinitro-2-methyl phenol ug/L 100 118 118 21-157 4-Aminobiphenyl ug/L 50 43.7 87 17-137 4-Bromophenylphenyl ether ug/L 50 50.7 101 38-130 4-Chloro-3-methylphenol ug/L 100 105 105 37-130 4-Chloroaniline ug/L 100 100 100 38-130 4-Chlorophenylphenyl ether ug/L 50 46.9 94 33-130 4-Nitroaniline ug/L 100 111 111 42-137 4-Nitrophenol ug/L 250 196 78 10-130 5-Nitro-o-toluidine ug/L 50 62.5 125 39-170 7,12-Dimethylbenz(a)anthracene ug/L 50 56.5 113 33-139 Acenaphthene ug/L 50 44.6 89 33-130 Acenaphthylene ug/L 50 45.7 91 35-130 Acetophenone ug/L 50 52.8 106 36-130 Anthracene ug/L 50 50.3 101 48-130 Benzo(a)anthracene ug/L 50 55.2 110 48-137 Benzo(a)pyrene ug/L 50 55.4 111 49-138 Benzo(b)fluoranthene ug/L 50 60.6 121 52-138 Benzo(g,h,i)perylene ug/L 50 49.8 100 48-140 Benzo(k)fluoranthene ug/L 50 59.4 119 48-139 Benzyl alcohol ug/L 100 95.5 95 35-130 bis(2-Chloroethoxy)methane ug/L 50 51.9 104 34-130 bis(2-Chloroethyl) ether ug/L 50 52.6 105 36-130 bis(2-Ethylhexyl)phthalate ug/L 50 67.0 134 32-165 Butylbenzylphthalate ug/L 50 65.5 131 34-161 Chlorobenzilate ug/L 50 52.8 106 43-176 Chrysene ug/L 50 55.1 110 47-131 Di-n-butylphthalate ug/L 50 59.6 119 39-144 Di-n-octylphthalate ug/L 50 62.5 125 30-170 v1 Diallate ug/L 50 49.9 100 33-143 Dibenz(a,h)anthracene ug/L 50 51.6 103 49-138 Dibenzofuran ug/L 50 45.3 91 33-130 Diethylphthalate ug/L 50 55.4 111 38-131 Dimethoate ug/L 50 52.1 104 46-173 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 91 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: Parameter 3312219 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Dimethylphthalate ug/L 50 54.1 108 37-130 Diphenylamine ug/L 50 52.4 105 35-135 Disulfoton ug/L 50 43.9 88 34-139 Ethyl methanesulfonate ug/L 50 48.7 97 33-133 Famphur ug/L 100 68.7 69 10-1301H Fluoranthene ug/L 50 53.1 106 46-137 Fluorene ug/L 50 49.7 99 37-130 Hexachlorobenzene ug/L 50 47.9 96 38-130 Hexachlorocyclopentadiene ug/L 50 27.1 54 10-130 Hexachloroethane ug/L 50 30.3 61 14-130 Hexachloropropene ug/L 50 18.0 36 10-130 Indeno(1,2,3-cd)pyrene ug/L 50 51.7 103 41-130 Isodrin ug/L 50 48.2 96 36-139 Isophorone ug/L 50 52.6 105 33-130 Isosafrole ug/L 50 45.5 91 22-130 Kepone ug/L 100 49.7 50 10-130 Methapyrilene ug/L 50 17.2J 34 10-173IH Methyl methanesulfonate ug/L 50 45.5 91 33-130 Methyl parathion ug/L 50 62.8 126 39-200 N-Nitroso-di-n-butylamine ug/L 50 43.2 86 22-130 N-Nitroso-di-n-propylamine ug/L 50 55.3 111 36-130 N-Nitrosodiethylamine ug/L 50 51.4 103 23-136 N-Nitrosodimethylamine ug/L 50 42.0 84 34-130 N-Nitrosodiphenylamine ug/L 50 52.4 105 37-130 N-Nitrosomethylethylamine ug/L 50 49.5 99 18-137 N-Nitrosopiperidine ug/L 50 51.6 103 25-142 N-Nitrosopyrrolidine ug/L 50 53.2 106 24-146 Nitrobenzene ug/L 50 46.8 94 36-130 O,O,O-Triethylphosphorothioate ug/L 50 46.2 92 29-130 O-Toluidine ug/L 50 46.5 93 27-132 P-Dimethylaminoazobenzene ug/L 50 27.2 54 17-130IL p-Phenylenediamine ug/L ND Parathion (Ethyl parathion) ug/L 50 63.3 127 32-200 Pentachlorobenzene ug/L 50 37.0 74 27-130 Pentachloronitrobenzene ug/L 50 61.3 123 47-164 Pentachlorophenol ug/L 100 108 108 23-149 Phenacetin ug/L 50 58.7 117 44-181 Phenanthrene ug/L 50 51.2 102 44-130 Phenol ug/L 50 33.5 67 18-130 Phorate ug/L 50 51.3 103 18-183 Pronamide ug/L 50 55.4 111 45-163 Pyrene ug/L 50 56.7 113 47-134 Safrole ug/L 50 44.9 90 27-130 Thionazin ug/L 50 52.6 105 36-162 2,4,6-Tribromophenol (S) % 109 10-144 2-Fluorobiphenyl (S) % 87 10-130 2-Fluorophenol (S) % 72 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 LABORATORY CONTROL SAMPLE: 3312219 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrobenzene-d5 (S) % 99 10-144 Phenol-d6 (S) % 58 10-130 Terphenyl-d14 (S) % 119 34-163 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3312220 3312221 MS MSD 92545864011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 90.9 90.9 57.9 51.4 64 57 10-130 12 30 1,3,5-Trinitrobenzene ug/L ND 90.9 90.9 135 138 149 152 50-200 2 30 v1 1,3-Dinitrobenzene ug/L ND 90.9 90.9 116 113 127 124 43-161 2 30 1,4-Naphthoquinone ug/L ND 90.9 90.9 87.2 101 96 111 10-184 14 30 1-Naphthalenamine ug/L ND 90.9 90.9 111 94.3 122 104 10-130 16 30 2,2'-Oxybis(1- ug/L ND 90.9 90.9 85.0 80.4 94 88 12-142 6 30 chloropropane) 2,3,4,6-Tetrachlorophenol ug/L ND 90.9 90.9 52.4 100 58 110 10-198 63 30 R1 2,4,5-Trichlorophenol ug/L ND 90.9 90.9 71.1 96.0 78 106 10-143 30 30 2,4,6-Trichlorophenol ug/L ND 90.9 90.9 53.0 88.0 58 97 10-147 50 30 R1 2,4-Dichlorophenol ug/L ND 90.9 90.9 70.9 80.1 78 88 10-138 12 30 2,4-Dimethylphenol ug/L ND 90.9 90.9 78.9 81.3 87 89 25-130 3 30 2,4-Dinitrophenol ug/L ND 455 455 ND 581 7 128 10-165 30 M1,v1 2,4-Dinitrotoluene ug/L ND 90.9 90.9 105 104 116 115 29-148 1 30 2,6-Dichlorophenol ug/L ND 90.9 90.9 58.4 82.6 64 91 33-139 34 30 R1 2,6-Dinitrotoluene ug/L ND 90.9 90.9 102 104 113 114 26-146 1 30 2-Acetylam inofl uorene ug/L ND 90.9 90.9 71.5 70.2 79 77 27-172 2 30 2-Chloronaphthalene ug/L ND 90.9 90.9 68.5 67.5 75 74 11-130 1 30 2-Chlorophenol ug/L ND 90.9 90.9 67.5 72.5 74 80 10-133 7 30 2-Methyl naphthalene ug/L ND 90.9 90.9 66.4 63.9 73 70 13-130 4 30 2-Methyl phenol(o-Cresol) ug/L ND 90.9 90.9 72.9 72.4 80 80 20-130 1 30 2-Naphthalenamine ug/L ND 90.9 90.9 82.4 54.4 91 60 10-135 41 30 R1 2-Nitroaniline ug/L ND 182 182 194 203 107 111 24-136 5 30 2-Nitrophenol ug/L ND 90.9 90.9 71.6 81.6 79 90 10-153 13 30 3&4-Methylphenol(m&p ug/L ND 90.9 90.9 79.3 78.8 87 87 16-130 1 30 Cresol) 3,3'-Dichlorobenzidine ug/L ND 182 182 214 206 118 114 10-153 4 30 3,3'-Dimethylbenzidine ug/L ND 182 182 435 352 239 193 10-200 21 30 IH,M1 3-Methylcholanthrene ug/L ND 90.9 90.9 102 97.9 112 108 53-181 4 30 3-Nitroaniline ug/L ND 182 182 217 214 120 118 22-151 2 30 4,6-Dinitro-2-methylphenol ug/L ND 182 182 62.9 233 35 128 10-180 115 30 R1 4-Aminobiphenyl ug/L ND 90.9 90.9 118 84.4 129 93 10-139 33 30 R1 4-Bromophenylphenyl ether ug/L ND 90.9 90.9 95.4 98.3 105 108 25-130 3 30 4-Chloro-3-methylphenol ug/L ND 182 182 176 188 97 103 25-133 7 30 4-Chloroaniline ug/L ND 182 182 162 168 89 92 14-132 3 30 4-Chlorophenylphenyl ether ug/L ND 90.9 90.9 87.0 89.9 96 99 19-130 3 30 4-Nitroaniline ug/L ND 182 182 228 216 125 119 29-150 5 30 4-Nitrophenol ug/L ND 455 455 105 376 23 83 10-130 112 30 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3312220 MS 92545864011 Spike Parameter Units Result Conc. MSD Spike Conc. 3312221 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 5-Nitro-o-toluidine ug/L ND 90.9 90.9 127 120 140 132 48-163 6 30 7,12- ug/L ND 90.9 90.9 110 106 121 117 40-140 3 30 Dimethylbenz(a)anthracene Acenaphthene ug/L ND 90.9 90.9 80.0 82.1 88 90 16-130 3 30 Acenaphthylene ug/L ND 90.9 90.9 81.5 84.1 90 93 15-137 3 30 Acetophenone ug/L ND 90.9 90.9 85.7 83.1 94 91 28-130 3 30 Anthracene ug/L ND 90.9 90.9 97.1 97.8 107 108 37-136 1 30 Benzo(a)anth race ne ug/L ND 90.9 90.9 110 109 121 120 40-145 1 30 Benzo(a)pyrene ug/L ND 90.9 90.9 111 109 122 119 41-146 2 30 Benzo(b)fluoranthene ug/L ND 90.9 90.9 121 121 133 133 39-151 0 30 Benzo(g,h,i)perylene ug/L ND 90.9 90.9 101 102 111 113 40-147 2 30 Benzo(k)fluoranthene ug/L ND 90.9 90.9 117 118 129 129 40-146 1 30 Benzyl alcohol ug/L ND 182 182 153 153 84 84 25-130 0 30 bis(2- ug/L ND 90.9 90.9 81.7 83.9 90 92 23-130 3 30 Chloroethoxy)methane bis(2-Chloroethyl) ether ug/L ND 90.9 90.9 83.6 81.1 92 89 25-130 3 30 bis(2- Ethyl hexyl)phthalate ug/L ND 90.9 90.9 127 127 140 140 28-166 0 30 Butylbenzylphthalate ug/L ND 90.9 90.9 133 131 146 144 33-165 2 30 Chlorobenzilate ug/L ND 90.9 90.9 120 105 132 116 55-170 13 30 Chrysene ug/L ND 90.9 90.9 112 110 124 121 38-141 2 30 Di-n-butylphthalate ug/L ND 90.9 90.9 114 112 125 123 32-153 2 30 Di-n-octylphthalate ug/L ND 90.9 90.9 125 122 137 134 30-175 3 30 v1 Diallate ug/L ND 90.9 90.9 96.1 96.3 106 106 39-141 0 30 Dibenz(a,h)anthracene ug/L ND 90.9 90.9 101 100 111 110 39-148 0 30 Dibenzofuran ug/L ND 90.9 90.9 82.1 84.2 90 93 20-130 2 30 Diethylphthalate ug/L ND 90.9 90.9 109 106 120 117 28-142 3 30 Dimethoate ug/L ND 90.9 90.9 101 100 111 110 57-167 1 30 Dimethylphthalate ug/L ND 90.9 90.9 101 103 111 113 26-136 2 30 Diphenylamine ug/L ND 90.9 90.9 97.5 97.6 107 107 38-132 0 30 Disulfoton ug/L ND 90.9 90.9 88.5 86.4 97 95 40-140 2 30 Ethyl methanesulfonate ug/L ND 90.9 90.9 79.1 75.8 87 83 38-134 4 30 Famphur ug/L ND 182 182 85.9 116 47 64 10-130 30 30 IH Fluoranthene ug/L ND 90.9 90.9 103 101 113 111 39-143 2 30 Fluorene ug/L ND 90.9 90.9 92.3 93.9 102 103 24-132 2 30 Hexachlorobenzene ug/L ND 90.9 90.9 91.5 93.6 101 103 29-130 2 30 Hexachlorocyclopentadiene ug/L ND 90.9 90.9 47.3 46.4 52 51 10-130 2 30 Hexachloroethane ug/L ND 90.9 90.9 53.7 48.9 59 54 10-130 9 30 Hexachloropropene ug/L ND 90.9 90.9 42.9 35.4 47 39 10-130 19 30 Indeno(1,2,3-cd)pyrene ug/L ND 90.9 90.9 103 103 113 114 39-148 1 30 Isodrin ug/L ND 90.9 90.9 96.1 92.0 106 101 45-138 4 30 Isophorone ug/L ND 90.9 90.9 84.5 85.3 93 94 23-130 1 30 Isosafrole ug/L ND 90.9 90.9 79.2 77.8 87 86 25-130 2 30 Kepone ug/L ND 182 182 62.0 85.5 34 47 10-130 32 30 R1 Methapyrilene ug/L ND 90.9 90.9 129 54.5J 142 60 10-181 30 IH Methyl methanesulfonate ug/L ND 90.9 90.9 73.6 70.5 81 78 31-130 4 30 Methyl parathion ug/L ND 90.9 90.9 123 121 135 133 53-197 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3312220 3312221 MS MSD 92545864011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual N-Nitroso-di-n-butylamine ug/L ND 90.9 90.9 83.3 72.9 92 80 28-130 13 30 N-Nitroso-di-n-propylamine ug/L ND 90.9 90.9 88.1 86.6 97 95 25-130 2 30 N-Nitrosodiethylamine ug/L ND 90.9 90.9 84.0 78.6 92 86 29-132 7 30 N-Nitrosodimethylamine ug/L ND 90.9 90.9 67.3 66.7 74 73 22-130 1 30 N-Nitrosodiphenylamine ug/L ND 90.9 90.9 97.5 97.6 107 107 26-134 0 30 N-Nitrosomethylethylamine ug/L ND 90.9 90.9 77.9 78.8 86 87 24-133 1 30 N-Nitrosopiperidine ug/L ND 90.9 90.9 84.2 85.1 93 94 29-141 1 30 N-Nitrosopyrrolidine ug/L ND 90.9 90.9 87.9 89.3 97 98 29-140 2 30 Nitrobenzene ug/L ND 90.9 90.9 78.3 76.4 86 84 25-130 2 30 0,0,0- ug/L ND 90.9 90.9 76.7 73.9 84 81 30-130 4 30 Triethylphosphorothioate O-Toluidine ug/L ND 90.9 90.9 78.9 74.4 87 82 27-130 6 30 P- ug/L ND 90.9 90.9 56.2 53.9 62 59 20-130 4 30 IL Dimethylaminoazobenzene p-Phenylenediamine ug/L ND ND ND 30 Parathion (Ethyl parathion) ug/L ND 90.9 90.9 121 120 133 131 48-200 1 30 Pentachlorobenzene ug/L ND 90.9 90.9 73.7 70.1 81 77 23-130 5 30 Pentachloronitrobenzene ug/L ND 90.9 90.9 110 119 121 131 57-159 8 30 Pentachlorophenol ug/L ND 182 182 84.8 211 47 116 10-175 85 30 R1 Phenacetin ug/L ND 90.9 90.9 118 114 130 125 57-179 4 30 Phenanthrene ug/L ND 90.9 90.9 98.9 99.7 109 110 36-133 1 30 Phenol ug/L ND 90.9 90.9 51.4 52.8 57 58 10-130 3 30 Phorate ug/L ND 90.9 90.9 99.6 99.4 110 109 21-192 0 30 Pronamide ug/L ND 90.9 90.9 112 107 123 118 55-162 4 30 Pyrene ug/L ND 90.9 90.9 114 112 126 123 40-143 2 30 Safrole ug/L ND 90.9 90.9 75.8 73.3 83 81 25-130 3 30 Thionazin ug/L ND 90.9 90.9 103 102 113 112 50-157 1 30 2,4,6-Tribromophenol (S) % 89 112 10-144 2-Fluorobiphenyl (S) % 81 81 10-130 2-Fluorophenol (S) % 49 62 10-130 Nitrobenzene-d5 (S) % 87 86 10-144 Phenol-d6 (S) % 47 49 10-130 Terphenyl-d14 (S) % 131 128 34-163 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629542 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352020 METHOD BLANK: 3308490 Matrix: Water Associated Lab Samples: 92546352020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 06/25/2106:06 LABORATORY CONTROL SAMPLE: 3308491 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 526 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308492 3308493 MS MSD 92545478001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 533 547 103 106 80-120 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629539 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352019 METHOD BLANK: 3308478 Matrix: Water Associated Lab Samples: 92546352019 Blank Reporting Parameter Units Result Limit BOD, 5 day ug/L ND 2000 LABORATORY CONTROL SAMPLE: 3308480 Spike LCS Parameter Units Conc. Result BOD, 5 day ug/L 198000 197000 SAMPLE DUPLICATE: 3308481 92546352019 Dup Parameter Units Result Result BOD, 5 day ug/L 2630 2920 MDL Analyzed Qualifiers 2000 06/30/2102:15 LCS % Rec % Rec Limits Qualifiers 99 84.6-115 Max RPD RPD Qualifiers 10 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 631436 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352019 SAMPLE DUPLICATE: 3317413 92545931001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.0 6.7 5 10 D6,H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629647 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352019 METHOD BLANK: 3309102 Matrix: Water Associated Lab Samples: 92546352019 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 06/25/2122:18 LABORATORY CONTROL SAMPLE: 3309103 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 48300 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3309104 3309105 MS MSD 92546312002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 75.9 mg/L 50000 50000 114000 112000 75 73 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 629527 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352019 METHOD BLANK: 3308448 Associated Lab Samples: 92546352019 Parameter Units Nitrogen, Nitrate ug/L LABORATORY CONTROL SAMPLE: 3308449 Parameter Units Nitrogen, Nitrate ug/L Matrix: Water Blank Reporting Result Limit ND 40.0 Spike LCS Conc. Result 1500 1540 MDL Analyzed Qualifiers 10.0 06/25/2100:51 LCS % Rec % Rec Limits Qualifiers 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308450 3308451 MS MSD 92546306001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 0.11 mg/L 1500 1500 1620 1600 101 99 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3308452 3308453 MS MSD 92546191002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 0.37 mg/L 1500 1500 1840 1840 98 98 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 632271 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352019 METHOD BLANK: 3321487 Associated Lab Samples: 92546352019 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 3321488 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit ND 0.050 Spike LCS Conc. Result 2.5 2.5 MDL Analyzed Qualifiers 0.025 07/09/2118:28 LCS % Rec % Rec Limits Qualifiers 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3321489 3321490 MS MSD 92546352019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 0.046J 2.5 2.5 2.5 2.5 99 99 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3321491 3321492 MS MSD 92547039002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus mg/L 13.9 2.5 2.5 15.7 16.1 74 89 90-110 2 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 91 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 QC Batch: 631747 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546352019 METHOD BLANK: 3318741 Matrix: Water Associated Lab Samples: 92546352019 Blank Reporting Parameter Units Result Limit Chemical Oxygen Demand ug/L ND 25000 LABORATORY CONTROL SAMPLE: 3318742 Spike LCS Parameter Units Conc. Result Chemical Oxygen Demand ug/L 750000 759000 MDL Analyzed Qualifiers 12500 07/07/2106:10 LCS % Rec % Rec Limits Qualifiers 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3318743 3318744 MS MSD 92546336011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 104000 102000 104 102 90-110 2 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3318745 3318746 MS MSD 92546889001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 412 mg/L 100000 100000 521000 507000 109 95 90-110 3 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 91 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. SR Surrogate recovery was below laboratory control limits. Results may be biased low. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 84 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Co. Lined MSWLF 92546352 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92546352020 MW-10 8151A 1694955 EPA8151 1694955 92546352020 MW-10 EPA 3510C 630405 EPA 8081 B 630599 92546352020 MW-10 EPA 3510C 629921 EPA 8082A 630223 92546352001 MW-1 EPA 3010A 631735 EPA 6010D 631934 92546352002 MW-2 EPA 3010A 631735 EPA 6010D 631934 92546352003 MW-3R EPA 3010A 631735 EPA 6010D 631934 92546352004 MW-4S EPA 3010A 631735 EPA 6010D 631934 92546352005 MW-41) EPA 3010A 631735 EPA 6010D 631934 92546352006 MW-5 EPA 3010A 631735 EPA 6010D 631934 92546352007 MW-6R EPA 3010A 631735 EPA 6010D 631934 92546352008 MW-8 EPA 3010A 631735 EPA 6010D 631934 92546352009 MW-9S EPA 3010A 631735 EPA 6010D 631934 92546352010 MW-91) EPA 3010A 631735 EPA 6010D 631934 92546352011 MW-11S EPA 3010A 631735 EPA 6010D 631934 92546352012 MW-11 D EPA 3010A 631735 EPA 6010D 631934 92546352013 MW-12 EPA 3010A 631735 EPA 6010D 631934 92546352014 MW-24 EPA 3010A 631735 EPA 6010D 631934 92546352015 MW-25 EPA 3010A 631735 EPA 6010D 631934 92546352016 MW-26 EPA 3010A 631735 EPA 6010D 631934 92546352017 MW-27 EPA 3010A 631735 EPA 6010D 631934 92546352018 MW-28 EPA 3010A 631735 EPA 6010D 631934 92546352019 LAGOON EPA 3010A 631735 EPA 6010D 631934 92546352020 MW-10 EPA 3010A 631735 EPA 6010D 631934 92546352001 MW-1 EPA 3010A 631740 EPA 6020B 631928 92546352002 MW-2 EPA 3010A 631740 EPA 6020B 631928 92546352003 MW-3R EPA 3010A 631740 EPA 6020B 631928 92546352004 MW-4S EPA 3010A 631740 EPA 6020B 631928 92546352005 MW-41) EPA 3010A 631740 EPA 6020B 631928 92546352006 MW-5 EPA 3010A 631740 EPA 6020B 631928 92546352007 MW-6R EPA 3010A 631740 EPA 6020B 631928 92546352008 MW-8 EPA 3010A 631740 EPA 6020B 631928 92546352009 MW-9S EPA 3010A 631740 EPA 6020B 631928 92546352010 MW-91) EPA 3010A 631740 EPA 6020B 631928 92546352011 MW-11S EPA 3010A 631740 EPA 6020B 631928 92546352012 MW-11 D EPA 3010A 631740 EPA 6020B 631928 92546352013 MW-12 EPA 3010A 631740 EPA 6020B 631928 92546352014 MW-24 EPA 3010A 631740 EPA 6020B 631928 92546352015 MW-25 EPA 3010A 631740 EPA 6020B 631928 92546352016 MW-26 EPA 3010A 631740 EPA 6020B 631928 92546352017 MW-27 EPA 3010A 631740 EPA 6020B 631928 92546352018 MW-28 EPA 3010A 631740 EPA 6020B 631928 92546352019 LAGOON EPA 3010A 631740 EPA 6020B 631928 92546352020 MW-10 EPA 3010A 631740 EPA 6020B 631928 92546352007 MW-6R EPA 7470A 629680 EPA 7470A 629738 92546352020 MW-10 EPA 7470A 629680 EPA 7470A 629738 92546352020 MW-10 EPA 3510C 630391 EPA 8270E 630524 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:48 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 91 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Co. Lined MSWLF Pace Project No.: 92546352 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92546352001 MW-1 EPA 8260D 629501 92546352002 MW-2 EPA 8260D 629501 92546352003 MW-3R EPA 8260D 629501 92546352004 MW-4S EPA 8260D 629501 92546352005 MW-41) EPA 8260D 629501 92546352006 MW-5 EPA 8260D 629501 92546352007 MW-6R EPA 8260D 629501 92546352008 MW-8 EPA 8260D 629501 92546352009 MW-9S EPA 8260D 629501 92546352010 MW-91) EPA 8260D 629501 92546352011 MW-11S EPA 8260D 629501 92546352012 MW-11D EPA 8260D 629501 92546352013 MW-12 EPA 8260D 629501 92546352014 MW-24 EPA 8260D 629501 92546352015 MW-25 EPA 8260D 629501 92546352016 MW-26 EPA 8260D 629501 92546352017 MW-27 EPA 8260D 629501 92546352018 MW-28 EPA 8260D 629501 92546352019 LAGOON EPA 8260D 629502 92546352020 MW-10 EPA 8260D 629502 92546352020 MW-10 SM 4500-S2D-2011 629542 92546352019 LAGOON SM 521 OB-2011 629539 92546352019 LAGOON EPA 9040C 631436 92546352019 LAGOON EPA 300.0 Rev 2.1 1993 629647 92546352019 LAGOON EPA 353.2 Rev 2.0 1993 629527 92546352019 LAGOON EPA 365.1 Rev 2.0 1993 632271 92546352019 LAGOON SM 5220D-2011 631747 Date: 07/12/2021 05:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. SM 521 OB-2011 629565 EPA 365.1 Rev 2.0 1993 632296 SM 5220D-2011 631762 Page 86 of 91 Document Name: Document Revised: October 28, 2020 Sample Condition Upon Recelpt(SCUR) Page 1 of 2 27aAna1Xic#!--- Document No.: issuing Authority: F-CAR-CS-033-Rev,07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville N Raleigh❑ Mechanicsville❑ Atlanta[] Kernersville❑ WO#:92546352 111111111111111111111111 Custody Seal Present? ❑Yes 'ONo Seals Intact? ❑Yes J}JNo Data/initials.Aar-son.Examining-Content Packing Material: ❑bubble wrap %Bubble Bags ❑Norte ❑ Other Biological Tissue Frozen? Thermomet r: FlYes nNo ?RcN/A IR Gun ID: wet ❑eiue 92TO64 Type of Ice: Correction Factor: Cooler Temp: s O Add/Subtract(°C) -0.1 Cooler Temp Corrected (Tp USDA Regulated Sail( N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check mapsi? I—IYac I—iNn ❑None Temp should be abDve freezing to VC ❑samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, includine Hawaii and Puerto Rico)? rIYe5 nNo Comments/Discrepan : Chain of Custody Present? ayes ❑No ❑N/A 1. Samples Arrived within Hold Time? ®Yes ❑No ❑N/A 2. Short Hold Time Analysis (02 hr.)? 9yes ❑No ❑N/A 3. Rush Turn Around Time Requested? ❑Yes 9Na ❑N/A 4. Sufficient Volume? 91yes ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? Yes nYes ❑No ❑No ❑N/A [—]N/A 6. Containers Intact? Yes [:]No [—]N/A 7. Dissolved analysis: Samples Field Filtered? Yes ®No ❑N/A a. Sample Labels Match COC? Ii -Includes Date/Time/lo/Analysis Matrix: C3�es ❑No ❑N/A 9. Headspace in VOA Vials I>5-6mml? ❑Yes NNo ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Dyes 9No ONo ❑N/A [--]N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLLITION Person contacted: Project Manager SCURF Review: Date/Time: Lot ID of split containers: Date: Field Data Required? ❑Yes ❑No Project Manager SRF Review: Date: Page 87 of 91 Document Name: Document Revised: October 28, 2020 h 1 ace naly�rc Sam Ip a Condition Upon Receiy[ SCUR)_ Page 2 of 2 Document No.: Issuing Authority: r F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project # ' verified and within the acceptance range for preservation W6# : 92546352 samples. Exceptions: VOA, Coliform, TCC, Oil and Grease, DRO/8015 (water) ❑OC, LLHg **Botto.m_half_o.f_box_ls_to_list-number of_bottles PM: AMB Due Date: 07/09/21 CLIENT. 92-Municipal W v a z a Z Z u _ o v a 4 z a z n z v Z n z w N cr 2 m v w ci 2 u z = a a re CL Z r N v v Y a i a z ¢ Z Y x a z 4 ? v a 2 z m Ll n a a u O N ^'� z UW Z Oro r�o _ t7 a�i n = n — Or a v O 7 O N 2 a ? r^ _ a Z Z `n M l7 y u r° N ry _ w n ro } o fvi c U 7 V V a V V v C CJ x U !� C Oa M tj } w — � Ql D ro u n ro U V w v n a n V E a ¢ E o z z a ¢ 2 a x Y ° v a E ? a E a a a a a a a a E E a E a a IS a ry O 7 O > O } O a a a n a C v, a E E E a E E E E a `m v E ; E J E E E J 0 A E E E E E E U'lN 0 0 N N ey ,-e a ry riry 0 R Q Q , '0 O o p O Q a ri = 7 r4 N rrvi In z N rl rl M ,.y N M rn G M M vE 1 Er a M t7 ri N N N\ m CD a% Q) - 10. m m m a an a ca 6 m 0. M Q. m U' l7 .1 l7 Q C7 Q U' Q l7 Q l7 O } V' } I l7 0 O } Q. ut a LA m Q }NN O 1 2 V +} j I 3 v n 5 6 7 J g IN f I ) 10 J 11 V � ✓ 12 1 "1 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot 4 Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i-e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 88 of 91 Document Name; Document Revised: October 28, 2020 g 5ample Condition Upon Receipt MU j_ __ Page 2 of 2 Document No.: issuing Authority: j F-CAR-CS-033-Rev.07 pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Colifarm, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom_half_of_hoxis to lis.#_numb.er_of_battles_ project g 25 3 e Z z Z a u Z ? Z N z N Z iC I'il '7 A V 2 m Z i a w v x d v N W 2 a 2 m x a `, 2 °N' a e- z z ¢ v Z ? O m i' N N a v a v LA N A � ia. n n a O p x `—�° v n C w a d rn O Q ? ui M � x n S a > M C x = Q M a C L ? O Y'1 j c 7 N = S ¢ 4A n io a Z ,O u d •v, 4 tv y = •� U m eerrI� �' .^, n d u j to " .� '-+ •N W m a At ?� _ •« .0 a, S m A m v o a n E a E o ¢ 4 C C w y m ro € c E a - a a a a o a E a ¢ ¢ E a rev O 0 0 a a vi a a u J J J S J J J J Q J J J J V7 Q E E E d E E E E 0 m v E ; E J E � O N 0 J E E E J o o O = = E E ' .> E E In O v ,A ,n =' o c7 o n o o r1 N " N N rf N ,� N R y i ,M�, N f�V N Q � .� 7 VM z' N kU c't _ � kn IA Q S h S X Y .N-1 Q 7 7 as a a a Cr 0. �, r! eY M rl M en CM M 91 0 Q 'U IA F N M � l7 0 d CO m 6 m M m m m m m l7 Q l7 0 i0 W 0 U' �7 V' C? O � d a a. t, In W C Q Q Q ¢ L1 } } p } } y I m 4 } p 1N I ` v 2 { 3- \ I ' 4 NN\\ 5 \Nf 5 \1V 7 I � 8 J I XX � 10 \,s N\N 11 1z pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina OEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 89 of 91 m s mn n o m an N? CDto m m N A w ro r ITEiNik c_3 n m' a s Q z b 3 l o O w A v (WA X! (n D W a� O= 2. j e v m � m V m n> n 4 my 1 o and �N3 xv -P.m o C � (o J m w zed dwo 0 $"�19 M v 0 0 ;• v a n MT.� x a to U) �1 C to (D 2. fV/11 v �P n V 4 (D N 10�1oua � � o 51. rn n a x s o n C 0 m1 m m �O>�ON95 an m 0 C C ca A q O v MATRIX COaE (see valid codes to lot[) Y Z O Z c a 5 T y Ll 6) 0 G7 Q O O D Q 0 D O SAMPLETYPE (G=GRAB C=COMP) a o' 0 w O 0 In j>•' �`' D � O a �- zm z z Z LR z O n m s D m n ns > " v T z ra N G ` D r r- Z M ,Mm M p� ~ SAMPLE TEMP AT COLLECTION cn Ln cn Mof (n (n (n Ln (n (n cn POFCONTAINERS (TjC m m m m m m a 0 K N C Unpreserved C m a o v, o 0 0 a H2504 m c g m ' z 3 a n 3p t HNO3 r rq 3 o w w w w w w w w w w w w HIM � a � � m � NaOH a' 3 b m � Na25203 (D r° Methanol m Other co Analyses Test Y/N a x x x x x x x x x x VOCs-B260 App I z x x x x x x x x x x Metals-App I z Ox m w m a is x x x x x x x x x 1,4-Dioxane (NonSIM) z x VOCs$260 App 2 z x x Metals-App 2 (Includes Hg) z N x Pesticidas App 2 z a � c Hercbicides App 2 z x PCBs App 2 z z SVOC App z m x x I Cyanide 11 ITx z z c in ji _, -. W x Suttide TEMP in C � o � o ,K Recalved on Ice (YIN ) Q Q � Custody Sealed-�� t, IN '� 0 PA O Cooler (YIN) 6 C13 to Samples Intact N (YIN) `LH a n m = n D a) b O C FL C C N fA m O ro � v 1 0A c m ti! z-I � m m = N N 3 m O o r 3 � �3 m rt n io Page 90 of 91 m m m G) a o nr i u o co 00 a, cn A w ITEM# m _ 3 a y 3 OO m r O, In N tp N c. z ❑ m O w o c. 7 7 p S D r u:, n 'a ❑ 7` C1 a N 3 O x v oVN 1n1.� N l� 8o^� W m Y 3 o ❑ p m_ n ra m z ry .a ro oi' co mm 2. � n m r"• V N N \ o a rni`=ss rn Pe _ o n C-a n A yo➢�omv go m v m � a z Z O z 7 g PAATRIX CODE (see valid codes to left) p C b {p 1 c 3 �, 0 0 C) 0 0 Gl 0 G'J 0 0 1 SAMPLETYPE (G=GRAB C=COMP) ° x ❑ 1c m m o a y w -I _r Ln m m rn Uw n C t "� Cl VJ (? �'^ c-e Sri — 5_: m m Uri z ? 2 ce m z ➢ -rrt re 3 m rn m 0 0 o D z O L D ❑ y m r vJ r z p A > v `r SAMPLE TEMP AT COLLECTION A m m m m a o q rn o, n, N XOFCONTAINERS ^ n n a m gUrpreserved -c v D N m o �• m H2SO4 \ 1 it m z HNO3 _U air 3 m C HCI �. mNaOH 2 -o w n N �n Na2S203 re Methanol o Other p1 Analyses Test YIN m r (D � n VOCs-App I z o n m n x Metals-App I z m O � M7— - -x_ — — Turbtdily z m z e Q k 1.4-0ioxane(Non-SIM) z ODD z LJ`- COD z ^ a NITRATF. Z in, PHOSPHORUS z r x Ph z c A -r x Sulfate z 7 m u TEMP in O • C _ m o n a o .� Received on Ice i (YIN) m (v in o zv "•' C O �` C S O G> Custody Sealed - �] Cooler (YIN) U� z m [f] Samples Intact lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 12, 2021 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry MSWLF SWs Pace Project No.: 92546684 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 25, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Accounts Payable, Municipal Engineering Services Jay Zimmerman, PG, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r 0 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry MSWLF SWs Pace Project No.: 92546684 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 North Carolina Drinking Water Certification M 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry MSWLF SWs Pace Project No.: 92546684 Lab ID Sample ID Matrix Date Collected Date Received 92546684001 SW-1 Water 06/25/2108:10 06/25/2116:43 92546684002 SW-2 Water 06/25/2111:50 06/25/2116:43 92546684003 SW-3 Water 06/25/2107:55 06/25/2116:43 92546684004 SW-4 Water 06/25/2107:10 06/25/2116:43 92546684005 SWN-1 Water 06/25/2111:05 06/25/2116:43 92546684006 SWN-2 Water 06/25/2113:15 06/25/2116:43 92546684007 SW-C Water 06/25/2107:30 06/25/2116:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry MSWLF SWs Pace Project No.: 92546684 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92546684001 SW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546684002 SW-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546684003 SW-3 EPA 601OD SH1 14 PASI-A EPA 601 OD RDT 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546684004 SW-4 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546684005 SWN-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546684006 SWN-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D NSCQ 51 PASI-C 92546684007 SW-C EPA 8260D NSCQ 51 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-1 Lab ID: 92546684001 Collected: 06/25/21 08:10 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:04 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:04 7440-38-2 Barium 21.9 ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:04 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:04 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:04 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:04 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/08/2111:00 07/09/2100:04 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:04 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:04 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:04 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:04 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:04 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:04 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:04 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:27 07/08/2104:12 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/28/21 20:40 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/28/21 20:40 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/28/21 20:40 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/28/21 20:40 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/28/21 20:40 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/28/21 20:40 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/28/21 20:40 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/28/21 20:40 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/28/21 20:40 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/28/21 20:40 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/28/21 20:40 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/28/21 20:40 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/28/21 20:40 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/28/21 20:40 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/28/21 20:40 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/28/21 20:40 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/28/21 20:40 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/28/21 20:40 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/28/21 20:40 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/28/21 20:40 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/28/21 20:40 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/28/21 20:40 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/28/21 20:40 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/28/21 20:40 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 5 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-1 Lab ID: 92546684001 Collected: 06/25/21 08:10 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/28/21 20:40 156-59-2 ND ug/L 1.0 0.40 1 06/28/21 20:40 156-60-5 ND ug/L 1.0 0.36 1 06/28/21 20:40 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 20:40 10061-01-5 ND ug/L 1.0 0.36 1 06/28/21 20:40 10061-02-6 ND ug/L 150 38.7 1 06/28/21 20:40 123-91-1 ND ug/L 1.0 0.30 1 06/28/21 20:40 100-41-4 ND ug/L 5.0 0.48 1 06/28/21 20:40 591-78-6 v1 ND ug/L 20.0 9.7 1 06/28/21 20:40 74-88-4 ND ug/L 5.0 2.0 1 06/28/21 20:40 75-09-2 ND ug/L 5.0 2.7 1 06/28/21 20:40 108-10-1 ND ug/L 1.0 0.29 1 06/28/21 20:40 100-42-5 ND ug/L 1.0 0.31 1 06/28/21 20:40 630-20-6 ND ug/L 1.0 0.22 1 06/28/21 20:40 79-34-5 ND ug/L 1.0 0.29 1 06/28/21 20:40 127-18-4 ND ug/L 1.0 0.48 1 06/28/21 20:40 108-88-3 ND ug/L 1.0 0.33 1 06/28/21 20:40 71-55-6 ND ug/L 1.0 0.32 1 06/28/21 20:40 79-00-5 ND ug/L 1.0 0.38 1 06/28/21 20:40 79-01-6 ND ug/L 1.0 0.30 1 06/28/21 20:40 75-69-4 ND ug/L 1.0 0.26 1 06/28/21 20:40 96-18-4 ND ug/L 2.0 1.3 1 06/28/21 20:40 108-05-4 ND ug/L 1.0 0.39 1 06/28/21 20:40 75-01-4 ND ug/L 1.0 0.34 1 06/28/21 20:40 1330-20-7 100 % 70-130 1 06/28/21 20:40 460-00-4 103 % 70-130 1 06/28/21 20:40 17060-07-0 100 % 70-130 1 06/28/21 20:40 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-2 Lab ID: 92546684002 Collected: 06/25/21 11:50 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:08 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:08 7440-38-2 Barium 24.8 ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:08 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:08 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:08 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:08 7440-47-3 Cobalt 28.3 ug/L 5.0 3.6 1 07/08/21 11:00 07/09/2100:08 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:08 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:08 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:08 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:08 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:08 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:08 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:27 07/08/2104:17 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/28/21 20:58 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/28/21 20:58 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/28/21 20:58 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/28/21 20:58 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/28/21 20:58 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/28/21 20:58 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/28/21 20:58 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/28/21 20:58 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/28/21 20:58 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/28/21 20:58 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/28/21 20:58 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/28/21 20:58 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/28/21 20:58 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/28/21 20:58 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/28/21 20:58 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/28/21 20:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/28/21 20:58 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/28/21 20:58 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/28/21 20:58 95-50-1 1,4-Dichlorobenzene 0.33J ug/L 1.0 0.33 1 06/28/21 20:58 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/28/21 20:58 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/28/21 20:58 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/28/21 20:58 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/28/21 20:58 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 7 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-2 Lab ID: 92546684002 Collected: 06/25/21 11:50 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.9 ug/L 1.0 0.38 1 06/28/21 20:58 156-59-2 ND ug/L 1.0 0.40 1 06/28/21 20:58 156-60-5 ND ug/L 1.0 0.36 1 06/28/21 20:58 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 20:58 10061-01-5 ND ug/L 1.0 0.36 1 06/28/21 20:58 10061-02-6 ND ug/L 150 38.7 1 06/28/21 20:58 123-91-1 ND ug/L 1.0 0.30 1 06/28/21 20:58 100-41-4 ND ug/L 5.0 0.48 1 06/28/21 20:58 591-78-6 v1 ND ug/L 20.0 9.7 1 06/28/21 20:58 74-88-4 ND ug/L 5.0 2.0 1 06/28/21 20:58 75-09-2 ND ug/L 5.0 2.7 1 06/28/21 20:58 108-10-1 ND ug/L 1.0 0.29 1 06/28/21 20:58 100-42-5 ND ug/L 1.0 0.31 1 06/28/21 20:58 630-20-6 ND ug/L 1.0 0.22 1 06/28/21 20:58 79-34-5 ND ug/L 1.0 0.29 1 06/28/21 20:58 127-18-4 ND ug/L 1.0 0.48 1 06/28/21 20:58 108-88-3 ND ug/L 1.0 0.33 1 06/28/21 20:58 71-55-6 ND ug/L 1.0 0.32 1 06/28/21 20:58 79-00-5 ND ug/L 1.0 0.38 1 06/28/21 20:58 79-01-6 ND ug/L 1.0 0.30 1 06/28/21 20:58 75-69-4 ND ug/L 1.0 0.26 1 06/28/21 20:58 96-18-4 ND ug/L 2.0 1.3 1 06/28/21 20:58 108-05-4 1.0 ug/L 1.0 0.39 1 06/28/21 20:58 75-01-4 ND ug/L 1.0 0.34 1 06/28/21 20:58 1330-20-7 99 % 70-130 1 06/28/21 20:58 460-00-4 103 % 70-130 1 06/28/21 20:58 17060-07-0 99 % 70-130 1 06/28/21 20:58 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-3 Lab ID: 92546684003 Collected: 06/25/21 07:55 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:11 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:11 7440-38-2 Barium 45.3 ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:11 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:11 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:11 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:11 7440-47-3 Cobalt 27.5 ug/L 5.0 3.6 1 07/08/2111:00 07/09/2100:11 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:11 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:11 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:11 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:11 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:11 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:11 7440-66-6 6010 MET ICP, Lab Filtered Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony, Dissolved ND ug/L 5.0 3.0 1 07/09/21 16:45 07/10/21 15:58 7440-36-0 P4 Arsenic, Dissolved ND ug/L 10.0 4.7 1 07/09/21 16:45 07/10/21 15:58 7440-38-2 P4 Barium, Dissolved 39.6 ug/L 5.0 3.5 1 07/09/21 16:45 07/10/21 15:58 7440-39-3 P4 Beryllium, Dissolved ND ug/L 1.0 0.70 1 07/09/21 16:45 07/10/21 15:58 7440-41-7 P4 Cadmium, Dissolved ND ug/L 1.0 0.40 1 07/09/21 16:45 07/10/21 15:58 7440-43-9 P4 Chromium, Dissolved ND ug/L 5.0 3.7 1 07/09/21 16:45 07/10/21 15:58 7440-47-3 P4 Cobalt, Dissolved 23.5 ug/L 5.0 3.6 1 07/09/21 16:45 07/10/21 15:58 7440-48-4 P4 Copper, Dissolved ND ug/L 5.0 4.3 1 07/09/21 16:45 07/10/21 15:58 7440-50-8 P4 Lead, Dissolved ND ug/L 5.0 4.5 1 07/09/21 16:45 07/10/21 15:58 7439-92-1 P4 Nickel, Dissolved ND ug/L 5.0 3.5 1 07/09/21 16:45 07/10/21 15:58 7440-02-0 P4 Selenium, Dissolved ND ug/L 10.0 4.7 1 07/09/21 16:45 07/10/21 15:58 7782-49-2 P4 Silver, Dissolved ND ug/L 5.0 2.5 1 07/09/21 16:45 07/10/21 15:58 7440-22-4 P4 Thallium, Dissolved ND ug/L 10.0 8.1 1 07/09/21 16:45 07/10/21 15:58 7440-28-0 P4 Vanadium, Dissolved ND ug/L 5.0 3.9 1 07/09/21 16:45 07/10/21 15:58 7440-62-2 P4 Zinc, Dissolved ND ug/L 10.0 9.5 1 07/09/21 16:45 07/10/21 15:58 7440-66-6 P4 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.10J ug/L 0.47 0.050 1 07/07/2113:27 07/08/2104:21 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/28/2121:16 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/28/2121:16 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/28/2121:16 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/28/2121:16 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/28/2121:16 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/28/2121:16 75-25-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-3 Lab ID: 92546684003 Collected: 06/25/21 07:55 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 2.0 1.7 1 06/28/21 21:16 74-83-9 ND ug/L 5.0 4.0 1 06/28/21 21:16 78-93-3 ND ug/L 2.0 0.73 1 06/28/21 21:16 75-15-0 ND ug/L 1.0 0.33 1 06/28/21 21:16 56-23-5 ND ug/L 1.0 0.28 1 06/28/21 21:16 108-90-7 ND ug/L 1.0 0.65 1 06/28/21 21:16 75-00-3 IK ND ug/L 5.0 1.6 1 06/28/21 21:16 67-66-3 ND ug/L 1.0 0.54 1 06/28/21 21:16 74-87-3 ND ug/L 2.0 0.34 1 06/28/21 21:16 96-12-8 ND ug/L 1.0 0.36 1 06/28/21 21:16 124-48-1 ND ug/L 1.0 0.27 1 06/28/21 21:16 106-93-4 ND ug/L 1.0 0.39 1 06/28/21 21:16 74-95-3 ND ug/L 1.0 0.34 1 06/28/21 21:16 95-50-1 ND ug/L 1.0 0.33 1 06/28/21 21:16 106-46-7 ND ug/L 1.0 0.56 1 06/28/21 21:16 110-57-6 v1 ND ug/L 1.0 0.37 1 06/28/21 21:16 75-34-3 ND ug/L 1.0 0.32 1 06/28/21 21:16 107-06-2 ND ug/L 1.0 0.35 1 06/28/21 21:16 75-35-4 ND ug/L 1.0 0.38 1 06/28/21 21:16 156-59-2 ND ug/L 1.0 0.40 1 06/28/21 21:16 156-60-5 ND ug/L 1.0 0.36 1 06/28/21 21:16 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 21:16 10061-01-5 ND ug/L 1.0 0.36 1 06/28/21 21:16 10061-02-6 ND ug/L 150 38.7 1 06/28/21 21:16 123-91-1 ND ug/L 1.0 0.30 1 06/28/21 21:16 100-41-4 ND ug/L 5.0 0.48 1 06/28/21 21:16 591-78-6 v1 ND ug/L 20.0 9.7 1 06/28/21 21:16 74-88-4 ND ug/L 5.0 2.0 1 06/28/21 21:16 75-09-2 ND ug/L 5.0 2.7 1 06/28/21 21:16 108-10-1 ND ug/L 1.0 0.29 1 06/28/21 21:16 100-42-5 ND ug/L 1.0 0.31 1 06/28/21 21:16 630-20-6 ND ug/L 1.0 0.22 1 06/28/21 21:16 79-34-5 ND ug/L 1.0 0.29 1 06/28/21 21:16 127-18-4 ND ug/L 1.0 0.48 1 06/28/21 21:16 108-88-3 ND ug/L 1.0 0.33 1 06/28/21 21:16 71-55-6 ND ug/L 1.0 0.32 1 06/28/21 21:16 79-00-5 ND ug/L 1.0 0.38 1 06/28/21 21:16 79-01-6 ND ug/L 1.0 0.30 1 06/28/21 21:16 75-69-4 ND ug/L 1.0 0.26 1 06/28/21 21:16 96-18-4 ND ug/L 2.0 1.3 1 06/28/21 21:16 108-05-4 ND ug/L 1.0 0.39 1 06/28/21 21:16 75-01-4 ND ug/L 1.0 0.34 1 06/28/21 21:16 1330-20-7 98 % 70-130 1 06/28/21 21:16 460-00-4 100 % 70-130 1 06/28/21 21:16 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-3 Lab ID: 92546684003 Collected: 06/25/21 07:55 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Surrogates Toluene-d8 (S) 100 % 70-130 1 06/28/21 21:16 2037-26-5 Date: 07/12/2021 11:03 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-4 Lab ID: 92546684004 Collected: 06/25/21 07:10 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:14 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:14 7440-38-2 Barium 16.4 ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:14 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:14 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:14 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:14 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/08/2111:00 07/09/2100:14 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:14 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:14 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:14 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:14 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:14 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:27 07/08/2104:35 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/28/21 21:34 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/28/21 21:34 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/28/21 21:34 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/28/21 21:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/28/21 21:34 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/28/21 21:34 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/28/21 21:34 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/28/21 21:34 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/28/21 21:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/28/21 21:34 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/28/21 21:34 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/28/21 21:34 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/28/21 21:34 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/28/21 21:34 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/28/21 21:34 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/28/21 21:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/28/21 21:34 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/28/21 21:34 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/28/21 21:34 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/28/21 21:34 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/28/21 21:34 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/28/21 21:34 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/28/21 21:34 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/28/21 21:34 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 12 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-4 Lab ID: 92546684004 Collected: 06/25/21 07:10 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/28/21 21:34 156-59-2 ND ug/L 1.0 0.40 1 06/28/21 21:34 156-60-5 ND ug/L 1.0 0.36 1 06/28/21 21:34 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 21:34 10061-01-5 ND ug/L 1.0 0.36 1 06/28/21 21:34 10061-02-6 ND ug/L 150 38.7 1 06/28/21 21:34 123-91-1 ND ug/L 1.0 0.30 1 06/28/21 21:34 100-41-4 ND ug/L 5.0 0.48 1 06/28/21 21:34 591-78-6 v1 ND ug/L 20.0 9.7 1 06/28/21 21:34 74-88-4 ND ug/L 5.0 2.0 1 06/28/21 21:34 75-09-2 ND ug/L 5.0 2.7 1 06/28/21 21:34 108-10-1 ND ug/L 1.0 0.29 1 06/28/21 21:34 100-42-5 ND ug/L 1.0 0.31 1 06/28/21 21:34 630-20-6 ND ug/L 1.0 0.22 1 06/28/21 21:34 79-34-5 ND ug/L 1.0 0.29 1 06/28/21 21:34 127-18-4 ND ug/L 1.0 0.48 1 06/28/21 21:34 108-88-3 ND ug/L 1.0 0.33 1 06/28/21 21:34 71-55-6 ND ug/L 1.0 0.32 1 06/28/21 21:34 79-00-5 ND ug/L 1.0 0.38 1 06/28/21 21:34 79-01-6 ND ug/L 1.0 0.30 1 06/28/21 21:34 75-69-4 ND ug/L 1.0 0.26 1 06/28/21 21:34 96-18-4 ND ug/L 2.0 1.3 1 06/28/21 21:34 108-05-4 ND ug/L 1.0 0.39 1 06/28/21 21:34 75-01-4 ND ug/L 1.0 0.34 1 06/28/21 21:34 1330-20-7 99 % 70-130 1 06/28/21 21:34 460-00-4 102 % 70-130 1 06/28/21 21:34 17060-07-0 99 % 70-130 1 06/28/21 21:34 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SWN-1 Lab ID: 92546684005 Collected: 06/25/21 11:05 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:18 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:18 7440-38-2 Barium 17.4 ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:18 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:18 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:18 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:18 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/08/2111:00 07/09/2100:18 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:18 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:18 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:18 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:18 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:18 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:18 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:27 07/08/2104:39 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/28/21 21:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/28/21 21:52 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/28/21 21:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/28/21 21:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/28/21 21:52 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/28/21 21:52 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/28/21 21:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/28/21 21:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/28/21 21:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/28/21 21:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/28/21 21:52 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/28/21 21:52 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/28/21 21:52 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/28/21 21:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/28/21 21:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/28/21 21:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/28/21 21:52 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/28/21 21:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/28/21 21:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/28/21 21:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/28/21 21:52 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/28/21 21:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/28/21 21:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/28/21 21:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 14 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SWN-1 Lab ID: 92546684005 Collected: 06/25/21 11:05 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/28/21 21:52 156-59-2 ND ug/L 1.0 0.40 1 06/28/21 21:52 156-60-5 ND ug/L 1.0 0.36 1 06/28/21 21:52 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 21:52 10061-01-5 ND ug/L 1.0 0.36 1 06/28/21 21:52 10061-02-6 ND ug/L 150 38.7 1 06/28/21 21:52 123-91-1 ND ug/L 1.0 0.30 1 06/28/21 21:52 100-41-4 ND ug/L 5.0 0.48 1 06/28/21 21:52 591-78-6 v1 ND ug/L 20.0 9.7 1 06/28/21 21:52 74-88-4 ND ug/L 5.0 2.0 1 06/28/21 21:52 75-09-2 ND ug/L 5.0 2.7 1 06/28/21 21:52 108-10-1 ND ug/L 1.0 0.29 1 06/28/21 21:52 100-42-5 ND ug/L 1.0 0.31 1 06/28/21 21:52 630-20-6 ND ug/L 1.0 0.22 1 06/28/21 21:52 79-34-5 ND ug/L 1.0 0.29 1 06/28/21 21:52 127-18-4 ND ug/L 1.0 0.48 1 06/28/21 21:52 108-88-3 ND ug/L 1.0 0.33 1 06/28/21 21:52 71-55-6 ND ug/L 1.0 0.32 1 06/28/21 21:52 79-00-5 ND ug/L 1.0 0.38 1 06/28/21 21:52 79-01-6 ND ug/L 1.0 0.30 1 06/28/21 21:52 75-69-4 ND ug/L 1.0 0.26 1 06/28/21 21:52 96-18-4 ND ug/L 2.0 1.3 1 06/28/21 21:52 108-05-4 ND ug/L 1.0 0.39 1 06/28/21 21:52 75-01-4 ND ug/L 1.0 0.34 1 06/28/21 21:52 1330-20-7 100 % 70-130 1 06/28/21 21:52 460-00-4 101 % 70-130 1 06/28/21 21:52 17060-07-0 99 % 70-130 1 06/28/21 21:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SWN-2 Lab ID: 92546684006 Collected: 06/25/21 13:15 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:21 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:21 7440-38-2 Barium 16.2 ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:21 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:21 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/08/2111:00 07/09/2100:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:21 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:21 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:21 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:27 07/08/2104:44 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 06/28/21 22:10 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 06/28/21 22:10 107-13-1 Benzene ND ug/L 1.0 0.34 1 06/28/21 22:10 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 06/28/21 22:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/28/21 22:10 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/28/21 22:10 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/28/21 22:10 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 06/28/21 22:10 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 06/28/21 22:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/28/21 22:10 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/28/21 22:10 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/28/21 22:10 75-00-3 Chloroform ND ug/L 5.0 1.6 1 06/28/21 22:10 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/28/21 22:10 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/28/21 22:10 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/28/21 22:10 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 06/28/21 22:10 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/28/21 22:10 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/28/21 22:10 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/28/21 22:10 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 06/28/21 22:10 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/28/21 22:10 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/28/21 22:10 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/28/21 22:10 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 16 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SWN-2 Lab ID: 92546684006 Collected: 06/25/21 13:15 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 06/28/21 22:10 156-59-2 ND ug/L 1.0 0.40 1 06/28/21 22:10 156-60-5 ND ug/L 1.0 0.36 1 06/28/21 22:10 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 22:10 10061-01-5 ND ug/L 1.0 0.36 1 06/28/21 22:10 10061-02-6 ND ug/L 150 38.7 1 06/28/21 22:10 123-91-1 ND ug/L 1.0 0.30 1 06/28/21 22:10 100-41-4 ND ug/L 5.0 0.48 1 06/28/21 22:10 591-78-6 v1 ND ug/L 20.0 9.7 1 06/28/21 22:10 74-88-4 ND ug/L 5.0 2.0 1 06/28/21 22:10 75-09-2 ND ug/L 5.0 2.7 1 06/28/21 22:10 108-10-1 ND ug/L 1.0 0.29 1 06/28/21 22:10 100-42-5 ND ug/L 1.0 0.31 1 06/28/21 22:10 630-20-6 ND ug/L 1.0 0.22 1 06/28/21 22:10 79-34-5 ND ug/L 1.0 0.29 1 06/28/21 22:10 127-18-4 ND ug/L 1.0 0.48 1 06/28/21 22:10 108-88-3 ND ug/L 1.0 0.33 1 06/28/21 22:10 71-55-6 ND ug/L 1.0 0.32 1 06/28/21 22:10 79-00-5 ND ug/L 1.0 0.38 1 06/28/21 22:10 79-01-6 ND ug/L 1.0 0.30 1 06/28/21 22:10 75-69-4 ND ug/L 1.0 0.26 1 06/28/21 22:10 96-18-4 ND ug/L 2.0 1.3 1 06/28/21 22:10 108-05-4 ND ug/L 1.0 0.39 1 06/28/21 22:10 75-01-4 ND ug/L 1.0 0.34 1 06/28/21 22:10 1330-20-7 98 % 70-130 1 06/28/21 22:10 460-00-4 101 % 70-130 1 06/28/21 22:10 17060-07-0 99 % 70-130 1 06/28/21 22:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-C Lab ID: 92546684007 Collected: 06/25/21 07:30 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 07/12/2021 11:03 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 06/28/2122:28 67-64-1 ND ug/L 10.0 1.8 1 06/28/2122:28 107-13-1 ND ug/L 1.0 0.34 1 06/28/2122:28 71-43-2 ND ug/L 1.0 0.47 1 06/28/2122:28 74-97-5 ND ug/L 1.0 0.31 1 06/28/2122:28 75-27-4 ND ug/L 1.0 0.34 1 06/28/2122:28 75-25-2 ND ug/L 2.0 1.7 1 06/28/2122:28 74-83-9 ND ug/L 5.0 4.0 1 06/28/2122:28 78-93-3 ND ug/L 2.0 0.73 1 06/28/2122:28 75-15-0 ND ug/L 1.0 0.33 1 06/28/2122:28 56-23-5 ND ug/L 1.0 0.28 1 06/28/2122:28 108-90-7 ND ug/L 1.0 0.65 1 06/28/2122:28 75-00-3 ND ug/L 5.0 1.6 1 06/28/2122:28 67-66-3 ND ug/L 1.0 0.54 1 06/28/2122:28 74-87-3 ND ug/L 2.0 0.34 1 06/28/2122:28 96-12-8 ND ug/L 1.0 0.36 1 06/28/2122:28 124-48-1 ND ug/L 1.0 0.27 1 06/28/2122:28 106-93-4 ND ug/L 1.0 0.39 1 06/28/2122:28 74-95-3 ND ug/L 1.0 0.34 1 06/28/2122:28 95-50-1 ND ug/L 1.0 0.33 1 06/28/2122:28 106-46-7 ND ug/L 1.0 0.56 1 06/28/2122:28 110-57-6 ND ug/L 1.0 0.37 1 06/28/2122:28 75-34-3 ND ug/L 1.0 0.32 1 06/28/2122:28 107-06-2 ND ug/L 1.0 0.35 1 06/28/2122:28 75-35-4 ND ug/L 1.0 0.38 1 06/28/2122:28 156-59-2 ND ug/L 1.0 0.40 1 06/28/2122:28 156-60-5 ND ug/L 1.0 0.36 1 06/28/2122:28 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 22:28 10061-01-5 ND ug/L 1.0 0.36 1 06/28/2122:28 10061-02-6 ND ug/L 150 38.7 1 06/28/2122:28 123-91-1 ND ug/L 1.0 0.30 1 06/28/2122:28 100-41-4 ND ug/L 5.0 0.48 1 06/28/2122:28 591-78-6 ND ug/L 20.0 9.7 1 06/28/2122:28 74-88-4 ND ug/L 5.0 2.0 1 06/28/2122:28 75-09-2 ND ug/L 5.0 2.7 1 06/28/2122:28 108-10-1 ND ug/L 1.0 0.29 1 06/28/2122:28 100-42-5 ND ug/L 1.0 0.31 1 06/28/2122:28 630-20-6 ND ug/L 1.0 0.22 1 06/28/2122:28 79-34-5 ND ug/L 1.0 0.29 1 06/28/2122:28 127-18-4 ND ug/L 1.0 0.48 1 06/28/2122:28 108-88-3 ND ug/L 1.0 0.33 1 06/28/2122:28 71-55-6 ND ug/L 1.0 0.32 1 06/28/2122:28 79-00-5 ND ug/L 1.0 0.38 1 06/28/2122:28 79-01-6 ND ug/L 1.0 0.30 1 06/28/2122:28 75-69-4 ND ug/L 1.0 0.26 1 06/28/2122:28 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IN v1 v1 Page 18 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry MSWLF SWs Pace Project No.: 92546684 Sample: SW-C Parameters Lab ID: Results 92546684007 Units Collected: Report Limit 06/25/21 07:30 MDL DF Received: 06/25/21 16:43 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.3 1 06/28/21 22:28 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/28/21 22:28 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 06/28/21 22:28 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 06/28/21 22:28 460-00-4 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 06/28/21 22:28 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 06/28/21 22:28 2037-26-5 Date: 07/12/2021 11:03 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 QC Batch: 631987 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006 METHOD BLANK: 3320015 Matrix: Water Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 07/08/2123:19 Arsenic ug/L ND 10.0 4.7 07/08/2123:19 Barium ug/L ND 5.0 3.5 07/08/2123:19 Beryllium ug/L ND 1.0 0.70 07/08/2123:19 Cadmium ug/L ND 1.0 0.40 07/08/2123:19 Chromium ug/L ND 5.0 3.7 07/08/2123:19 Cobalt ug/L ND 5.0 3.6 07/08/2123:19 Copper ug/L ND 5.0 4.3 07/08/2123:19 Lead ug/L ND 5.0 4.5 07/08/2123:19 Nickel ug/L ND 5.0 3.5 07/08/2123:19 Selenium ug/L ND 10.0 4.7 07/08/2123:19 Silver ug/L ND 5.0 2.5 07/08/2123:19 Vanadium ug/L ND 5.0 3.9 07/08/2123:19 Zinc ug/L ND 10.0 9.5 07/08/2123:19 LABORATORY CONTROL SAMPLE: Parameter 3320016 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 493 99 80-120 Arsenic ug/L 500 476 95 80-120 Barium ug/L 500 487 97 80-120 Beryllium ug/L 500 492 98 80-120 Cadmium ug/L 500 490 98 80-120 Chromium ug/L 500 484 97 80-120 Cobalt ug/L 500 478 96 80-120 Copper ug/L 500 497 99 80-120 Lead ug/L 500 480 96 80-120 Nickel ug/L 500 487 97 80-120 Selenium ug/L 500 484 97 80-120 Silver ug/L 250 246 99 80-120 Vanadium ug/L 500 485 97 80-120 Zinc ug/L 500 489 98 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry MSWLF SWs 92546684 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3320017 3320018 MS MSD 92546523001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 4.9J 500 500 510 514 101 102 75-125 1 20 Arsenic ug/L <4.7 500 500 504 506 101 101 75-125 0 20 Barium ug/L 474 500 500 970 965 99 98 75-125 1 20 Beryllium ug/L <0.70 500 500 506 503 101 101 75-125 0 20 Cadmium ug/L <0.40 500 500 507 509 101 102 75-125 0 20 Chromium ug/L <3.7 500 500 486 495 97 99 75-125 2 20 Cobalt ug/L 4.8J 500 500 480 482 95 95 75-125 0 20 Copper ug/L 500 500 512 517 102 103 75-125 1 20 Lead ug/L <4.5 500 500 481 481 96 96 75-125 0 20 Nickel ug/L 5.3 500 500 485 486 96 96 75-125 0 20 Selenium ug/L <4.7 500 500 512 517 102 103 75-125 1 20 Silver ug/L <2.5 250 250 254 255 101 102 75-125 1 20 Vanadium ug/L <3.9 500 500 501 507 100 101 75-125 1 20 Zinc ug/L <9.5 500 500 497 498 99 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 QC Batch: 631994 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Filtered Diss. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546684003 METHOD BLANK: 3320032 Associated Lab Samples: 92546684003 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony, Dissolved ug/L ND 5.0 3.0 07/10/21 15:45 Arsenic, Dissolved ug/L ND 10.0 4.7 07/10/21 15:45 Barium, Dissolved ug/L ND 5.0 3.5 07/10/21 15:45 Beryllium, Dissolved ug/L ND 1.0 0.70 07/10/21 15:45 Cadmium, Dissolved ug/L ND 1.0 0.40 07/10/21 15:45 Chromium, Dissolved ug/L ND 5.0 3.7 07/10/21 15:45 Cobalt, Dissolved ug/L ND 5.0 3.6 07/10/21 15:45 Copper, Dissolved ug/L ND 5.0 4.3 07/10/21 15:45 Lead, Dissolved ug/L ND 5.0 4.5 07/10/21 15:45 Nickel, Dissolved ug/L ND 5.0 3.5 07/10/21 15:45 Selenium, Dissolved ug/L ND 10.0 4.7 07/10/21 15:45 Silver, Dissolved ug/L ND 5.0 2.5 07/10/21 15:45 Thallium, Dissolved ug/L ND 10.0 8.1 07/10/21 15:45 Vanadium, Dissolved ug/L ND 5.0 3.9 07/10/21 15:45 Zinc, Dissolved ug/L ND 10.0 9.5 07/10/21 15:45 LABORATORY CONTROL SAMPLE: Parameter 3320033 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony, Dissolved ug/L 500 433 87 80-120 Arsenic, Dissolved ug/L 500 419 84 80-120 Barium, Dissolved ug/L 500 436 87 80-120 Beryllium, Dissolved ug/L 500 434 87 80-120 Cadmium, Dissolved ug/L 500 440 88 80-120 Chromium, Dissolved ug/L 500 434 87 80-120 Cobalt, Dissolved ug/L 500 415 83 80-120 Copper, Dissolved ug/L 500 423 85 80-120 Lead, Dissolved ug/L 500 428 86 80-120 Nickel, Dissolved ug/L 500 436 87 80-120 Selenium, Dissolved ug/L 500 426 85 80-120 Silver, Dissolved ug/L 250 216 87 80-120 Thallium, Dissolved ug/L 500 418 84 80-120 Vanadium, Dissolved ug/L 500 432 86 80-120 Zinc, Dissolved ug/L 500 431 86 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3320034 3320035 MS MSD 92546684003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony, Dissolved ug/L ND 500 500 438 427 87 85 75-125 3 20 Arsenic, Dissolved ug/L ND 500 500 424 412 84 82 75-125 3 20 Barium, Dissolved ug/L 39.6 500 500 471 458 86 84 75-125 3 20 Beryllium, Dissolved ug/L ND 500 500 433 423 87 85 75-125 2 20 Cadmium, Dissolved ug/L ND 500 500 437 422 87 84 75-125 4 20 Chromium, Dissolved ug/L ND 500 500 429 420 86 84 75-125 2 20 Cobalt, Dissolved ug/L 23.5 500 500 435 424 82 80 75-125 3 20 Copper, Dissolved ug/L ND 500 500 427 417 85 83 75-125 2 20 Lead, Dissolved ug/L ND 500 500 423 410 84 82 75-125 3 20 Nickel, Dissolved ug/L ND 500 500 431 418 86 83 75-125 3 20 Selenium, Dissolved ug/L ND 500 500 429 417 86 83 75-125 3 20 Silver, Dissolved ug/L ND 250 250 218 211 87 84 75-125 3 20 Thallium, Dissolved ug/L ND 500 500 402 391 80 78 75-125 3 20 Vanadium, Dissolved ug/L ND 500 500 434 421 87 84 75-125 3 20 Zinc, Dissolved ug/L ND 500 500 431 418 86 83 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 QC Batch: 631772 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006 METHOD BLANK: 3318797 Matrix: Water Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 07/08/2103:40 LABORATORY CONTROL SAMPLE: 3318798 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 25.2 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3318799 3318800 MS MSD 92546678003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 25.5 25.2 102 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 QC Batch: 630139 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006, 92546684007 METHOD BLANK: 3311182 Matrix: Water Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006, 92546684007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/28/21 19:27 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/28/21 19:27 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/28/21 19:27 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/28/21 19:27 1,1-Dichloroethane ug/L ND 1.0 0.37 06/28/21 19:27 1,1-Dichloroethene ug/L ND 1.0 0.35 06/28/21 19:27 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/28/21 19:27 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/28/21 19:27 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 06/28/21 19:27 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/28/21 19:27 1,2-Dichloroethane ug/L ND 1.0 0.32 06/28/21 19:27 1,2-Dichloropropane ug/L ND 1.0 0.36 06/28/21 19:27 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/28/21 19:27 1,4-Dioxane (p-Dioxane) ug/L ND 150 38.7 06/28/21 19:27 2-Butanone (MEK) ug/L ND 5.0 4.0 06/28/21 19:27 2-Hexanone ug/L ND 5.0 0.48 06/28/21 19:27 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 06/28/21 19:27 Acetone ug/L ND 25.0 5.1 06/28/21 19:27 Acrylonitrile ug/L ND 10.0 1.8 06/28/21 19:27 Benzene ug/L ND 1.0 0.34 06/28/21 19:27 Bromochloromethane ug/L ND 1.0 0.47 06/28/21 19:27 Bromodichloromethane ug/L ND 1.0 0.31 06/28/21 19:27 Bromoform ug/L ND 1.0 0.34 06/28/21 19:27 Bromomethane ug/L ND 2.0 1.7 06/28/21 19:27 Carbon disulfide ug/L ND 2.0 0.73 06/28/21 19:27 Carbon tetrachloride ug/L ND 1.0 0.33 06/28/21 19:27 Chlorobenzene ug/L ND 1.0 0.28 06/28/21 19:27 Chloroethane ug/L ND 1.0 0.65 06/28/21 19:27 Chloroform ug/L ND 5.0 1.6 06/28/21 19:27 Chloromethane ug/L ND 1.0 0.54 06/28/21 19:27 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/28/21 19:27 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/28/21 19:27 Dibromochloromethane ug/L ND 1.0 0.36 06/28/21 19:27 Dibromomethane ug/L ND 1.0 0.39 06/28/21 19:27 Ethylbenzene ug/L ND 1.0 0.30 06/28/21 19:27 lodomethane ug/L ND 20.0 9.7 06/28/21 19:27 Methylene Chloride ug/L ND 5.0 2.0 06/28/21 19:27 Styrene ug/L ND 1.0 0.29 06/28/21 19:27 Tetrachloroethene ug/L ND 1.0 0.29 06/28/21 19:27 Toluene ug/L ND 1.0 0.48 06/28/21 19:27 v1 I:/ Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 METHOD BLANK: 3311182 Matrix: Water Associated Lab Samples: 92546684001, 92546684002, 92546684003, 92546684004, 92546684005, 92546684006, 92546684007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/28/21 19:27 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 06/28/21 19:27 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 06/28/21 19:27 v1 Trichloroethene ug/L ND 1.0 0.38 06/28/21 19:27 Trichlorofluoromethane ug/L ND 1.0 0.30 06/28/21 19:27 Vinyl acetate ug/L ND 2.0 1.3 06/28/21 19:27 Vinyl chloride ug/L ND 1.0 0.39 06/28/21 19:27 Xylene (Total) ug/L ND 1.0 0.34 06/28/21 19:27 1,2-Dichloroethane-d4 (S) % 103 70-130 06/28/21 19:27 4-Bromofluorobenzene (S) % 99 70-130 06/28/21 19:27 Toluene-d8 (S) % 99 70-130 06/28/21 19:27 LABORATORY CONTROL SAMPLE: Parameter 3311183 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.6 105 70-130 1,1,1-Trichloroethane ug/L 50 51.0 102 70-130 1,1,2,2-Tetrachloroethane ug/L 50 57.5 115 70-130 1,1,2-Trichloroethane ug/L 50 53.8 108 70-130 1,1-Dichloroethane ug/L 50 52.4 105 70-130 1,1-Dichloroethene ug/L 50 53.2 106 70-132 1,2,3-Trichloropropane ug/L 50 56.0 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 61.8 124 70-132 1,2-Dibromoethane (EDB) ug/L 50 54.2 108 70-130 1,2-Dichlorobenzene ug/L 50 54.8 110 70-130 1,2-Dichloroethane ug/L 50 49.3 99 70-130 1,2-Dichloropropane ug/L 50 53.2 106 70-130 1,4-Dichlorobenzene ug/L 50 56.1 112 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1280 128 70-137 2-Butanone (MEK) ug/L 100 123 123 70-133 2-Hexanone ug/L 100 125 125 70-130 v1 4-Methyl-2-pentanone (MIBK) ug/L 100 124 124 70-130 Acetone ug/L 100 110 110 70-144 Acrylonitrile ug/L 250 282 113 70-130 Benzene ug/L 50 51.8 104 70-130 Bromochloromethane ug/L 50 45.5 91 70-130 Bromodichloromethane ug/L 50 52.9 106 70-130 Bromoform ug/L 50 56.8 114 70-131 Bromomethane ug/L 50 50.5 101 30-177 Carbon disulfide ug/L 50 54.4 109 70-133 Carbon tetrachloride ug/L 50 51.5 103 70-130 Chlorobenzene ug/L 50 53.2 106 70-130 Chloroethane ug/L 50 37.3 75 46-131 IK Chloroform ug/L 50 53.2 106 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 LABORATORY CONTROL SAMPLE: Parameter 3311183 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 54.0 cis-1,2-Dichloroethene ug/L 50 52.5 cis-1,3-Dichloropropene ug/L 50 57.6 Dibromochloromethane ug/L 50 53.5 Dibromomethane ug/L 50 53.7 Ethylbenzene ug/L 50 52.7 lodomethane ug/L 100 104 Methylene Chloride ug/L 50 50.4 Styrene ug/L 50 54.9 Tetrachloroethene ug/L 50 50.5 Toluene ug/L 50 52.9 trans-1,2-Dichloroethene ug/L 50 53.2 trans- 1,3-Dichloropropene ug/L 50 57.7 trans-1,4-Dichloro-2-butene ug/L 50 77.9 Trichloroethene ug/L 50 53.5 Trichlorofluoromethane ug/L 50 48.3 Vinyl acetate ug/L 100 126 Vinyl chloride ug/L 50 52.2 Xylene (Total) ug/L 150 157 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 108 49-130 105 70-130 115 70-130 107 70-130 107 70-130 105 70-130 104 47-140 101 68-130 110 70-130 101 70-130 106 70-130 106 70-130 115 70-130 156 25-200 v1 107 70-130 97 61-130 126 70-140 104 59-142 105 70-130 93 70-130 99 70-130 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3311184 MS 92546693010 Spike Parameter Units Result Conc. MSD Spike Conc. 3311185 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.5 20.5 107 102 70-135 5 30 1,1,1-Trichloroethane ug/L ND 20 20 21.3 20.3 107 101 70-148 5 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.1 21.3 110 107 70-131 3 30 1,1,2-Trichloroethane ug/L ND 20 20 21.5 20.9 108 104 70-136 3 30 1,1-Dichloroethane ug/L ND 20 20 21.6 20.8 108 104 70-147 4 30 1,1-Dichloroethene ug/L ND 20 20 22.2 21.6 111 108 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 21.7 20.9 108 105 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 23.0 22.4 115 112 69-136 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.4 21.0 107 105 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 22.2 21.6 111 108 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 19.9 19.1 99 96 67-138 4 30 1,2-Dichloropropane ug/L ND 20 20 21.9 21.2 109 106 70-138 3 30 1,4-Dichlorobenzene ug/L ND 20 20 23.2 22.5 116 113 70-133 3 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 498 475 124 119 69-146 5 30 2-Butanone (MEK) ug/L ND 40 40 42.7 42.5 107 106 61-147 1 30 2-Hexanone ug/L ND 40 40 46.2 44.7 115 112 67-139 3 30 4-Methyl-2-pentanone ug/L ND 40 40 44.5 44.2 111 110 67-136 1 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 33 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry MSWLF SWs Pace Project No.: 92546684 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3311184 3311185 MS MSD 92546693010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 39.5 38.6 99 96 55-159 2 30 Acrylonitrile ug/L ND 100 100 107 103 107 103 68-140 4 30 Benzene ug/L ND 20 20 21.5 21.3 108 107 67-150 1 30 Bromochloromethane ug/L ND 20 20 19.8 19.7 99 98 70-146 1 30 Bromodichloromethane ug/L ND 20 20 21.0 20.8 105 104 70-138 1 30 Bromoform ug/L ND 20 20 21.4 21.0 107 105 57-138 2 30 Bromomethane ug/L ND 20 20 19.7 21.6 99 108 10-200 9 30 IH Carbon disulfide ug/L ND 20 20 22.6 22.1 113 110 70-152 2 30 Carbon tetrachloride ug/L ND 20 20 21.8 21.6 109 108 70-147 1 30 Chlorobenzene ug/L ND 20 20 22.5 21.8 112 109 70-137 3 30 Chloroethane ug/L ND 20 20 24.1 24.5 120 122 51-166 2 30 Chloroform ug/L ND 20 20 21.2 20.9 106 105 70-144 1 30 Chloromethane ug/L ND 20 20 18.1 18.0 91 90 24-161 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.4 20.6 107 103 67-148 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.0 22.3 115 112 70-142 3 30 Dibromochloromethane ug/L ND 20 20 21.3 20.4 107 102 68-138 4 30 Dibromomethane ug/L ND 20 20 22.0 21.2 110 106 70-134 4 30 Ethylbenzene ug/L ND 20 20 22.6 21.7 113 109 68-143 4 30 lodomethane ug/L ND 40 40 50.9 53.5 127 134 20-161 5 30 Methylene Chloride ug/L ND 20 20 20.4 19.8 102 99 64-148 3 30 Styrene ug/L ND 20 20 22.8 22.0 114 110 70-136 4 30 Tetrachloroethene ug/L ND 20 20 22.2 21.6 111 108 70-139 3 30 Toluene ug/L ND 20 20 21.9 21.5 109 108 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.0 21.4 110 107 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.3 22.1 112 111 70-138 1 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 23.3 23.1 116 115 31-145 1 30 IH,v1 Trichloroethene ug/L ND 20 20 22.3 22.1 111 111 70-149 1 30 Trichlorofluoromethane ug/L ND 20 20 21.1 20.5 106 103 61-154 3 30 Vinyl acetate ug/L ND 40 40 46.5 44.7 116 112 48-156 4 30 Vinyl chloride ug/L ND 20 20 21.8 21.3 109 107 55-172 2 30 Xylene (Total) ug/L ND 60 60 67.9 64.6 113 108 66-145 5 30 1,2-Dichloroethane-d4 (S) % 96 96 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8 (S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 33 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry MSWLF SWs Pace Project No.: 92546684 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. P4 Sample field preservation does not meet EPA or method recommendations for this analysis. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 11:03 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry MSWLF SWs 92546684 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92546684001 SW-1 EPA 3010A 631987 EPA 6010D 632207 92546684002 SW-2 EPA 3010A 631987 EPA 6010D 632207 92546684003 SW-3 EPA 3010A 631987 EPA 6010D 632207 92546684004 SW-4 EPA 3010A 631987 EPA 6010D 632207 92546684005 SWN-1 EPA 3010A 631987 EPA 6010D 632207 92546684006 SWN-2 EPA 3010A 631987 EPA 6010D 632207 92546684003 SW-3 EPA 3010A 631994 EPA 6010D 632545 92546684001 SW-1 EPA 3010A 631772 EPA 6020B 631953 92546684002 SW-2 EPA 3010A 631772 EPA 6020B 631953 92546684003 SW-3 EPA 3010A 631772 EPA 6020B 631953 92546684004 SW-4 EPA 3010A 631772 EPA 6020B 631953 92546684005 SWN-1 EPA 3010A 631772 EPA 6020B 631953 92546684006 SWN-2 EPA 3010A 631772 EPA 6020B 631953 92546684001 SW-1 EPA 8260D 630139 92546684002 SW-2 EPA 8260D 630139 92546684003 SW-3 EPA 8260D 630139 92546684004 SW-4 EPA 8260D 630139 92546684005 SWN-1 EPA 8260D 630139 92546684006 SWN-2 EPA 8260D 630139 92546684007 SW-C EPA 8260D 630139 Date: 07/12/2021 11:03 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 33 Document Name: Document Revised: October 28, 2020 r Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F•CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville [`%� Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample • Client Name: l Upon Receipt , , r , I Pro;ecttt WQ# : 92546684 ❑ Commercial [Pace ❑Other: 92545684 Custody Seal Present? ❑Yes �No Seals Intact? [:]Yes PNo a� Date%lnitials.Rerson-Examining.Gonten Packing Material: Q13ubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer: �t, ❑Yes [-]No ®N/A IR Gun ID: rJwet ❑Blue ❑None 92TO64 Type of Ice: Correction Factor: Cooler Temp: Add/Subtract (•C) _p i Temp should be above freezing to VC []Samples out of temp uiteria. Samples on ice, cooling process Cooler Temp Corrected (•C): �. has begun USDA Regulated Sail (,g N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source !internationally, F�Yes MNo including Hawaii and Puerto Ricol? ❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? plyes ❑ND ❑N/A 1. Samples Arrived within Hold Time? Yes QNO []N/A 2. Short Hold Time Analysis (c72 hr.)? ❑Yes JANo []N/A 3, Rush Turn Around Tlme Requested? ❑Yes [gNo ❑N/A 4. Sufficient Volume? [@Yes ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? [BYes Yes ❑No (:]No ❑N/A ❑N/A 6. Containers Intact? ®Yes [-]No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes nNo ❑N/A 8. Sample Labels Match COC? -Includes Date/Time/10/Analysis Matr+x: oyes YY ❑No [-]N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes nNo Cl NIA 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No []No JflN/A ON/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No Lot ID of solit containers: CLIENT NOTIFICATION/RESOLUTION Person contacted:-�1�Ol�l'±i} p�� I Date/Time: -{� tL� �— � " � _ Project Manager SCURF Review: _ IA:::m �L2 _ _ _ Date: -I — i _,a l Project Manager SRF Review: Date: Page 31 of 33 Document Name: Document Revised: October 28, 2020 �acena1—cd7- Sample Condition Upon Receipt(SCUR _ Pag F Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dethlorination is Project W�# ■92�����4 verified and within the acceptance range for preservation ■ samples. PM: RMB Due Date: 07/12/21 Exceptions: VOA, Califprm, TOC, Oil and Grease, DRO/BOIS (water) DOC, LLHg CLIENT: 92—Munic ipa 1 **Bottom_half_nfbox_is_to_list_numb.er_o.f-bottles_—_... _____.-___... _. I _ z .�lvlr _T _ .., �t" wry.. �� �_ _ __ _ �_ Z ry _ —aj_ _ �� _� Z m a m 'top a n i' v °� T a a = Z z a y M z Z c O i a ? = i' $ a w a)p �7 N m 0 = m Qu =O N ro m x a m a yy�� $ 2 ry .a 4 m ¢ z O uYi Mz 0 N a .> O v y C u u z LJ U t L U_ y N 2 Q_ U ut M c fn _, > �, v z V D W C - a •� a a � N 2 A a a m iT � b a o E u a E v a £ a E Q -o E v E ¢ E E o n x a 0 _J ¢ 0 ¢ `J a O d a y = m v� A a � E Q � c u m E J E J E J E d u E J E E E ro ¢ m ¢ m E o Q J E ' J E } E J E } J E = A V1 E J E J 4 J E V7 J E Q J E �n rl o N o «. Ln ri lob n �n .•+ yy _ , e N G O g O q Y = N N 6n N In N O Q O st a am a 1 J a a Z a N a U LL _ vs 4 2 H of d a% Y a Ln o 7 m m ca m Co m m m cc a m Q Q Q Q a 4 © ? ? 9 a m a m d m L7 Q V1 7 l7 0 1 A z 3 3 R t 3 5 13 \N\ 31 7 8 s 9 IO II 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot N Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 32 of 33 M T m G) a n A rn ITEM# a n m, N 9 a n = D j p 7 z y N (A m O w +l C7 O C - V ]O N y D IQ ED 0 EZ D S � � N 3 O m- O N d T w N m R o n y W O 7 �02. D r O c_ 0 m O O 2 �. 0 3 c 2 o a 0 0� T 71 co in z m` x co m y C 2 n m N x 'q sly s y n n C n o- a c o m o a m m c o A m o a m •- o a v o [` r Z p IAATRIX CODE (see valid codes to left) O o SAMPLE TYPE {G=GRAB C=COMP) J N a 0 D �. n — a .i w lv.ri",)� Vs � v r s[ n z Z m m _ 1 Z A z �. O Z D n f m rq v rn m 2 z o 6 N to 4 \ IT rn m >J m A z SAMPLE TEMP AT COLLECTION C m a w #Crr CONTAINERS 3 co s n 0 ' gUnpreserved v v 0 w o .. m o• ♦ a m H2SO4 a' m o_ n o it; m70 ? 5 0 a HNO3 0 3 w w w w w w w HCI m n n? \ NaOH � m — n n m Na25203 N ➢ D Methanol U3 m p Oliier . : ra Analyses Test YIN % 1 T c 4 r L x x x x x x VOCs-App 1 z n N N x x x Metals-App1 z D o mci A - _- idilq z vi Z c x x x 1.4-Oioxane (NON-SIM) t w ea � a W 1 < � z tow m zen A a TEMP in C a o •°2 iD D o d A Received on Ice (YIN) m n Custody Sealed C O Cooler (YIN) t � S 0 z to Samples Intacl (Y1N) Page 33 of 33 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 06, 2021 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 25, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, owa- .'ru Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Accounts Payable, Municipal Engineering Services Jay Zimmerman, PG, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Lab ID Sample ID 92546671001 SW-D SAMPLE SUMMARY Matrix Date Collected Date Received Water 06/25/2113:30 06/25/2116:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92546671001 SW-D EPA 8260D NSCQ 51 PASI-C PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Sample: SW-D Lab ID: 92546671001 Collected: 06/25/21 13:30 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 07/06/2021 10:35 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 06/28/2120:22 67-64-1 ND ug/L 10.0 1.8 1 06/28/2120:22 107-13-1 ND ug/L 1.0 0.34 1 06/28/2120:22 71-43-2 ND ug/L 1.0 0.47 1 06/28/2120:22 74-97-5 ND ug/L 1.0 0.31 1 06/28/2120:22 75-27-4 ND ug/L 1.0 0.34 1 06/28/2120:22 75-25-2 ND ug/L 2.0 1.7 1 06/28/2120:22 74-83-9 ND ug/L 5.0 4.0 1 06/28/2120:22 78-93-3 ND ug/L 2.0 0.73 1 06/28/2120:22 75-15-0 ND ug/L 1.0 0.33 1 06/28/2120:22 56-23-5 ND ug/L 1.0 0.28 1 06/28/2120:22 108-90-7 ND ug/L 1.0 0.65 1 06/28/2120:22 75-00-3 ND ug/L 5.0 1.6 1 06/28/2120:22 67-66-3 ND ug/L 1.0 0.54 1 06/28/2120:22 74-87-3 ND ug/L 2.0 0.34 1 06/28/2120:22 96-12-8 ND ug/L 1.0 0.36 1 06/28/2120:22 124-48-1 ND ug/L 1.0 0.27 1 06/28/2120:22 106-93-4 ND ug/L 1.0 0.39 1 06/28/2120:22 74-95-3 ND ug/L 1.0 0.34 1 06/28/2120:22 95-50-1 ND ug/L 1.0 0.33 1 06/28/2120:22 106-46-7 ND ug/L 1.0 0.56 1 06/28/2120:22 110-57-6 ND ug/L 1.0 0.37 1 06/28/2120:22 75-34-3 ND ug/L 1.0 0.32 1 06/28/2120:22 107-06-2 ND ug/L 1.0 0.35 1 06/28/2120:22 75-35-4 ND ug/L 1.0 0.38 1 06/28/2120:22 156-59-2 ND ug/L 1.0 0.40 1 06/28/2120:22 156-60-5 ND ug/L 1.0 0.36 1 06/28/2120:22 78-87-5 ND ug/L 1.0 0.36 1 06/28/21 20:22 10061-01-5 ND ug/L 1.0 0.36 1 06/28/2120:22 10061-02-6 ND ug/L 150 38.7 1 06/28/2120:22 123-91-1 ND ug/L 1.0 0.30 1 06/28/2120:22 100-41-4 ND ug/L 5.0 0.48 1 06/28/2120:22 591-78-6 ND ug/L 20.0 9.7 1 06/28/2120:22 74-88-4 ND ug/L 5.0 2.0 1 06/28/2120:22 75-09-2 ND ug/L 5.0 2.7 1 06/28/2120:22 108-10-1 ND ug/L 1.0 0.29 1 06/28/2120:22 100-42-5 ND ug/L 1.0 0.31 1 06/28/2120:22 630-20-6 ND ug/L 1.0 0.22 1 06/28/2120:22 79-34-5 ND ug/L 1.0 0.29 1 06/28/2120:22 127-18-4 ND ug/L 1.0 0.48 1 06/28/2120:22 108-88-3 ND ug/L 1.0 0.33 1 06/28/2120:22 71-55-6 ND ug/L 1.0 0.32 1 06/28/2120:22 79-00-5 ND ug/L 1.0 0.38 1 06/28/2120:22 79-01-6 ND ug/L 1.0 0.30 1 06/28/2120:22 75-69-4 ND ug/L 1.0 0.26 1 06/28/2120:22 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IN v1 v1 Page 5 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Sample: SW-D Parameters Lab ID: Results 92546671001 Units Collected: Report Limit 06/25/21 13:30 MDL DF Received: 06/25/21 16:43 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.3 1 06/28/21 20:22 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/28/21 20:22 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 06/28/21 20:22 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 06/28/21 20:22 460-00-4 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 06/28/21 20:22 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 06/28/21 20:22 2037-26-5 Date: 07/06/2021 10:35 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 15 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 QC Batch: 630139 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546671001 METHOD BLANK: 3311182 Associated Lab Samples: 92546671001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/28/21 19:27 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/28/21 19:27 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/28/21 19:27 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/28/21 19:27 1,1-Dichloroethane ug/L ND 1.0 0.37 06/28/21 19:27 1,1-Dichloroethene ug/L ND 1.0 0.35 06/28/21 19:27 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/28/21 19:27 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/28/21 19:27 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 06/28/21 19:27 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/28/21 19:27 1,2-Dichloroethane ug/L ND 1.0 0.32 06/28/21 19:27 1,2-Dichloropropane ug/L ND 1.0 0.36 06/28/21 19:27 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/28/21 19:27 1,4-Dioxane (p-Dioxane) ug/L ND 150 38.7 06/28/21 19:27 2-Butanone (MEK) ug/L ND 5.0 4.0 06/28/21 19:27 2-Hexanone ug/L ND 5.0 0.48 06/28/21 19:27 v1 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 06/28/21 19:27 Acetone ug/L ND 25.0 5.1 06/28/21 19:27 Acrylonitrile ug/L ND 10.0 1.8 06/28/21 19:27 Benzene ug/L ND 1.0 0.34 06/28/21 19:27 Bromochloromethane ug/L ND 1.0 0.47 06/28/21 19:27 Bromodichloromethane ug/L ND 1.0 0.31 06/28/21 19:27 Bromoform ug/L ND 1.0 0.34 06/28/21 19:27 Bromomethane ug/L ND 2.0 1.7 06/28/21 19:27 Carbon disulfide ug/L ND 2.0 0.73 06/28/21 19:27 Carbon tetrachloride ug/L ND 1.0 0.33 06/28/21 19:27 Chlorobenzene ug/L ND 1.0 0.28 06/28/21 19:27 Chloroethane ug/L ND 1.0 0.65 06/28/21 19:27 IK Chloroform ug/L ND 5.0 1.6 06/28/21 19:27 Chloromethane ug/L ND 1.0 0.54 06/28/21 19:27 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/28/21 19:27 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/28/21 19:27 Dibromochloromethane ug/L ND 1.0 0.36 06/28/21 19:27 Dibromomethane ug/L ND 1.0 0.39 06/28/21 19:27 Ethylbenzene ug/L ND 1.0 0.30 06/28/21 19:27 lodomethane ug/L ND 20.0 9.7 06/28/21 19:27 Methylene Chloride ug/L ND 5.0 2.0 06/28/21 19:27 Styrene ug/L ND 1.0 0.29 06/28/21 19:27 Tetrachloroethene ug/L ND 1.0 0.29 06/28/21 19:27 Toluene ug/L ND 1.0 0.48 06/28/21 19:27 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2021 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 15 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 METHOD BLANK: 3311182 Matrix: Water Associated Lab Samples: 92546671001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/28/21 19:27 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 06/28/21 19:27 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 06/28/21 19:27 v1 Trichloroethene ug/L ND 1.0 0.38 06/28/21 19:27 Trichlorofluoromethane ug/L ND 1.0 0.30 06/28/21 19:27 Vinyl acetate ug/L ND 2.0 1.3 06/28/21 19:27 Vinyl chloride ug/L ND 1.0 0.39 06/28/21 19:27 Xylene (Total) ug/L ND 1.0 0.34 06/28/21 19:27 1,2-Dichloroethane-d4 (S) % 103 70-130 06/28/21 19:27 4-Bromofluorobenzene (S) % 99 70-130 06/28/21 19:27 Toluene-d8 (S) % 99 70-130 06/28/21 19:27 LABORATORY CONTROL SAMPLE: 3311183 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.6 105 70-130 1,1,1-Trichloroethane ug/L 50 51.0 102 70-130 1,1,2,2-Tetrachloroethane ug/L 50 57.5 115 70-130 1,1,2-Trichloroethane ug/L 50 53.8 108 70-130 1,1-Dichloroethane ug/L 50 52.4 105 70-130 1,1-Dichloroethene ug/L 50 53.2 106 70-132 1,2,3-Trichloropropane ug/L 50 56.0 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 61.8 124 70-132 1,2-Dibromoethane (EDB) ug/L 50 54.2 108 70-130 1,2-Dichlorobenzene ug/L 50 54.8 110 70-130 1,2-Dichloroethane ug/L 50 49.3 99 70-130 1,2-Dichloropropane ug/L 50 53.2 106 70-130 1,4-Dichlorobenzene ug/L 50 56.1 112 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1280 128 70-137 2-Butanone (MEK) ug/L 100 123 123 70-133 2-Hexanone ug/L 100 125 125 70-130 v1 4-Methyl-2-pentanone (MIBK) ug/L 100 124 124 70-130 Acetone ug/L 100 110 110 70-144 Acrylonitrile ug/L 250 282 113 70-130 Benzene ug/L 50 51.8 104 70-130 Bromochloromethane ug/L 50 45.5 91 70-130 Bromodichloromethane ug/L 50 52.9 106 70-130 Bromoform ug/L 50 56.8 114 70-131 Bromomethane ug/L 50 50.5 101 30-177 Carbon disulfide ug/L 50 54.4 109 70-133 Carbon tetrachloride ug/L 50 51.5 103 70-130 Chlorobenzene ug/L 50 53.2 106 70-130 Chloroethane ug/L 50 37.3 75 46-131 IK Chloroform ug/L 50 53.2 106 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2021 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 15 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 LABORATORY CONTROL SAMPLE: Parameter 3311183 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 54.0 cis-1,2-Dichloroethene ug/L 50 52.5 cis-1,3-Dichloropropene ug/L 50 57.6 Dibromochloromethane ug/L 50 53.5 Dibromomethane ug/L 50 53.7 Ethylbenzene ug/L 50 52.7 lodomethane ug/L 100 104 Methylene Chloride ug/L 50 50.4 Styrene ug/L 50 54.9 Tetrachloroethene ug/L 50 50.5 Toluene ug/L 50 52.9 trans-1,2-Dichloroethene ug/L 50 53.2 trans- 1,3-Dichloropropene ug/L 50 57.7 trans-1,4-Dichloro-2-butene ug/L 50 77.9 Trichloroethene ug/L 50 53.5 Trichlorofluoromethane ug/L 50 48.3 Vinyl acetate ug/L 100 126 Vinyl chloride ug/L 50 52.2 Xylene (Total) ug/L 150 157 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 108 49-130 105 70-130 115 70-130 107 70-130 107 70-130 105 70-130 104 47-140 101 68-130 110 70-130 101 70-130 106 70-130 106 70-130 115 70-130 156 25-200 v1 107 70-130 97 61-130 126 70-140 104 59-142 105 70-130 93 70-130 99 70-130 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3311184 MS 92546693010 Spike Parameter Units Result Conc. MSD Spike Conc. 3311185 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.5 20.5 107 102 70-135 5 30 1,1,1-Trichloroethane ug/L ND 20 20 21.3 20.3 107 101 70-148 5 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.1 21.3 110 107 70-131 3 30 1,1,2-Trichloroethane ug/L ND 20 20 21.5 20.9 108 104 70-136 3 30 1,1-Dichloroethane ug/L ND 20 20 21.6 20.8 108 104 70-147 4 30 1,1-Dichloroethene ug/L ND 20 20 22.2 21.6 111 108 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 21.7 20.9 108 105 67-137 3 30 1,2-Dibromo-3- ug/L ND 20 20 23.0 22.4 115 112 69-136 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.4 21.0 107 105 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 22.2 21.6 111 108 70-133 3 30 1,2-Dichloroethane ug/L ND 20 20 19.9 19.1 99 96 67-138 4 30 1,2-Dichloropropane ug/L ND 20 20 21.9 21.2 109 106 70-138 3 30 1,4-Dichlorobenzene ug/L ND 20 20 23.2 22.5 116 113 70-133 3 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 498 475 124 119 69-146 5 30 2-Butanone (MEK) ug/L ND 40 40 42.7 42.5 107 106 61-147 1 30 2-Hexanone ug/L ND 40 40 46.2 44.7 115 112 67-139 3 30 4-Methyl-2-pentanone ug/L ND 40 40 44.5 44.2 111 110 67-136 1 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2021 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 15 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3311184 3311185 MS MSD 92546693010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 39.5 38.6 99 96 55-159 2 30 Acrylonitrile ug/L ND 100 100 107 103 107 103 68-140 4 30 Benzene ug/L ND 20 20 21.5 21.3 108 107 67-150 1 30 Bromochloromethane ug/L ND 20 20 19.8 19.7 99 98 70-146 1 30 Bromodichloromethane ug/L ND 20 20 21.0 20.8 105 104 70-138 1 30 Bromoform ug/L ND 20 20 21.4 21.0 107 105 57-138 2 30 Bromomethane ug/L ND 20 20 19.7 21.6 99 108 10-200 9 30 IH Carbon disulfide ug/L ND 20 20 22.6 22.1 113 110 70-152 2 30 Carbon tetrachloride ug/L ND 20 20 21.8 21.6 109 108 70-147 1 30 Chlorobenzene ug/L ND 20 20 22.5 21.8 112 109 70-137 3 30 Chloroethane ug/L ND 20 20 24.1 24.5 120 122 51-166 2 30 Chloroform ug/L ND 20 20 21.2 20.9 106 105 70-144 1 30 Chloromethane ug/L ND 20 20 18.1 18.0 91 90 24-161 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.4 20.6 107 103 67-148 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.0 22.3 115 112 70-142 3 30 Dibromochloromethane ug/L ND 20 20 21.3 20.4 107 102 68-138 4 30 Dibromomethane ug/L ND 20 20 22.0 21.2 110 106 70-134 4 30 Ethylbenzene ug/L ND 20 20 22.6 21.7 113 109 68-143 4 30 lodomethane ug/L ND 40 40 50.9 53.5 127 134 20-161 5 30 Methylene Chloride ug/L ND 20 20 20.4 19.8 102 99 64-148 3 30 Styrene ug/L ND 20 20 22.8 22.0 114 110 70-136 4 30 Tetrachloroethene ug/L ND 20 20 22.2 21.6 111 108 70-139 3 30 Toluene ug/L ND 20 20 21.9 21.5 109 108 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.0 21.4 110 107 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.3 22.1 112 111 70-138 1 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 23.3 23.1 116 115 31-145 1 30 IH,v1 Trichloroethene ug/L ND 20 20 22.3 22.1 111 111 70-149 1 30 Trichlorofluoromethane ug/L ND 20 20 21.1 20.5 106 103 61-154 3 30 Vinyl acetate ug/L ND 40 40 46.5 44.7 116 112 48-156 4 30 Vinyl chloride ug/L ND 20 20 21.8 21.3 109 107 55-172 2 30 Xylene (Total) ug/L ND 60 60 67.9 64.6 113 108 66-145 5 30 1,2-Dichloroethane-d4 (S) % 96 96 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8 (S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2021 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2021 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: SURRY CO. LINED MSWLF Pace Project No.: 92546671 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92546671001 SW-D EPA 8260D 630139 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2021 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 15 Document Name: Document Revised: October 28, 2020 Sample Condition Upon Recei t(SCUR) Page 1 of 2 / aCe-mwical Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Aden❑ Greenwood[] Huntersvifle Raleigh❑ Mechanicsville[] Atlanta❑ Kernersville❑ WO#:925466 1 1111111111111111111111 - 925 Custody Seal Present? ❑Yes gNo Seals Intact? Oyes gNo 46671 Date/Initiais.Rerson.EKamining Content ✓ Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer; *wet ❑glue ❑None ❑Yes ❑No ®N/A inIR Gun ID: 92TO64 Type of Ice: Correction Factor: Cooler Temp:Add/Subtract ('C) _0.1 Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('Cl: 5.7 has begun USDA Regulated Soil ( ® N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps♦? Did samples originate from a foreign source [internationally, Flyes nNo including Hawaii and Puerto Ricol? MYes FlNo Comments/Discrepancy: Chain of Custody Present? Jj§Yes [—]No []N/A 1. Samples Arrived within Hold Time? Yes ❑No ❑N/A 2. Short Hold Tlme Analysis (02 hr.)? ❑Yes IoNo ❑N/A 3. Rush Turn Around Time Requested? ❑Yes ZNo ❑N/A 4. Sufficient Volume? CgYes ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? ®Yes Y)Yes ❑No No ❑N/A ❑N/A 6. Containers Intact? Yes [:]No N/A 7. Dissolved analysis: Samples Field Filtered? Yes ONo N/A S. Sample Labels Match CDC? -Includes Date/Time/ID/Analysis Matrix: J %Yes I []No ❑N/A 9. Headspace in VOA Vials (?5-6mm17 ❑Yes MNo N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes NNo ®No ❑NIA NIA 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review- Date/Time: Date: Field Data Required? ❑Yes ❑No Project Manager SRF Review: Date: Page 13 of 15 Document Name: Document Revised: October 28, 2020 rtaalue�navt-cw� Sample Condition Upon Receipt(5CURj� Page 2 of 2 Document No.: Issuing Authority: F-CAA-CS-033-Rev.07 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions; VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **eofflom_half_atf_box_Is to list -number -of -bottles---- .__- -- Project # W0# ; 9254667 1 PM: AMB Due Date: 07/12/21 CLIENT: 92-Municipal, Z u u z a = = a v _ p " 0 d a a z a z n a n ai rr, ? 2 �_ - IJ ai 6 Q q O Q q V1 m 6i n C1 a v qq O a Ln (7 u " N N W a N S Q) e c 7 c a') C = N M l7 a _ _ `,� y E 2 ra ry Z L a O O a = c c a = ` a a roV a ; a v a E a E E ¢ a E a o ¢ O ¢ A IL ¢E c EiE E E E a E E E E v m v E ' E J E > _, E > J E > _, E -, a E J E E J E V1 E Q J E 0 r 0 � !; r1+ ut N ry Ln Ln = . O ry e `�rv' GIr a v 9 S an 0 ry 0 n 0 a ts 4.. a a 14 a.d 2 a N 0. U 4 LL �, 7 rl In S rl l7 T t7 wi l7 M V' �i df m l9 01 l7 T 0 d 0 Lh V7 S N p, ina, 0. D O to V' v, cc(am m m m m m 3 a d a a a a > > o > m a >N 1 \N�S\ N \NNs NN z 3 4 5 \�s N I 7 N L 10 11 12 PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot p Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 14 of 15 E�dweS O 7 z {NIM c � F N a Q N O eol uo p o J 2 pae�a=aa (NIA) eupoly0 Ienpi,sea u! m m m N 0 d"31 ro a Nr 9 a lJ1 U. m a elenns 9 8 � Hd � ` in Bj8JI!NLU f o a sruoydsoyd aoo N/A 1901 ses6leUV _a o Y m �` IaylO n loueyleW � nW N m u W £OZSZeN U HOaN is IOH as £ONH 3 a E @ O. bOSZH U G z O '6 p Peuaseidu0 C a am`m ayy w F 5 O U U (n ¢ U Q a a al $a3NIb1N0O d0 # j ¢ NOIlO3IIO0lVd W313ldVWS a uuj Lu w f � r .� z m q Q O m w w o w E z w w a Jl r r a J a w U r i F ^1 m 4 ..� w c } O L � m <L w S O c c'n p (dwoo=0 saaa=O) delta aldwds a # tt S tt S rr S rr S rr S tt 5 Wei OI sepOO NRA ees) 3003 )(WidW o a m w a a o � „Z# W J 3 U iT a o i IX ci a' a a s n �o'33daa3db✓� 3 C� U 3 N W ❑ C C = 12 W g � d c J � f1 o E E —r- W 3� �t4� Q a r Q 6 8 N E —� A! ry E Z Page 15 of •� n d v E _m c # W31i ti 00 T O r i`t M 47 t0 Iti 00 rn a �7 E a(01 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 12, 2021 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: SURRY BLANKS Pace Project No.: 92546678 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on June 25, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Accounts Payable, Municipal Engineering Services Jay Zimmerman, PG, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r 0 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: SURRY BLANKS Pace Project No.: 92546678 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: SURRY BLANKS Pace Project No.: 92546678 Lab ID Sample ID Matrix Date Collected Date Received 92546678001 EB Water 06/25/2114:09 06/25/2116:43 92546678002 FB Water 06/25/2114:12 06/25/2116:43 92546678003 EB-metals Water 06/25/2114:09 06/25/2116:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: SURRY BLANKS Pace Project No.: 92546678 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92546678001 EB EPA 8260D SAS 51 PASI-C 92546678002 FB EPA 8260D SAS 51 PASI-C 92546678003 EB-metals EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY BLANKS Pace Project No.: 92546678 Sample: EB Lab ID: 92546678001 Collected: 06/25/21 14:09 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 07/12/2021 05:20 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 06/29/2116:10 67-64-1 ND ug/L 10.0 1.8 1 06/29/2116:10 107-13-1 ND ug/L 1.0 0.34 1 06/29/2116:10 71-43-2 ND ug/L 1.0 0.47 1 06/29/2116:10 74-97-5 ND ug/L 1.0 0.31 1 06/29/2116:10 75-27-4 ND ug/L 1.0 0.34 1 06/29/2116:10 75-25-2 ND ug/L 2.0 1.7 1 06/29/2116:10 74-83-9 ND ug/L 5.0 4.0 1 06/29/2116:10 78-93-3 ND ug/L 2.0 0.73 1 06/29/2116:10 75-15-0 ND ug/L 1.0 0.33 1 06/29/2116:10 56-23-5 ND ug/L 1.0 0.28 1 06/29/2116:10 108-90-7 ND ug/L 1.0 0.65 1 06/29/2116:10 75-00-3 ND ug/L 5.0 1.6 1 06/29/2116:10 67-66-3 ND ug/L 1.0 0.54 1 06/29/2116:10 74-87-3 ND ug/L 2.0 0.34 1 06/29/2116:10 96-12-8 ND ug/L 1.0 0.36 1 06/29/2116:10 124-48-1 ND ug/L 1.0 0.27 1 06/29/2116:10 106-93-4 ND ug/L 1.0 0.39 1 06/29/2116:10 74-95-3 ND ug/L 1.0 0.34 1 06/29/2116:10 95-50-1 ND ug/L 1.0 0.33 1 06/29/2116:10 106-46-7 ND ug/L 1.0 0.56 1 06/29/2116:10 110-57-6 ND ug/L 1.0 0.37 1 06/29/2116:10 75-34-3 ND ug/L 1.0 0.32 1 06/29/2116:10 107-06-2 ND ug/L 1.0 0.35 1 06/29/2116:10 75-35-4 ND ug/L 1.0 0.38 1 06/29/2116:10 156-59-2 ND ug/L 1.0 0.40 1 06/29/2116:10 156-60-5 ND ug/L 1.0 0.36 1 06/29/2116:10 78-87-5 ND ug/L 1.0 0.36 1 06/29/21 16:10 10061-01-5 ND ug/L 1.0 0.36 1 06/29/2116:10 10061-02-6 ND ug/L 150 38.7 1 06/29/2116:10 123-91-1 ND ug/L 1.0 0.30 1 06/29/2116:10 100-41-4 ND ug/L 5.0 0.48 1 06/29/2116:10 591-78-6 ND ug/L 20.0 9.7 1 06/29/2116:10 74-88-4 2.1J ug/L 5.0 2.0 1 06/29/2116:10 75-09-2 ND ug/L 5.0 2.7 1 06/29/2116:10 108-10-1 ND ug/L 1.0 0.29 1 06/29/2116:10 100-42-5 ND ug/L 1.0 0.31 1 06/29/2116:10 630-20-6 ND ug/L 1.0 0.22 1 06/29/2116:10 79-34-5 ND ug/L 1.0 0.29 1 06/29/2116:10 127-18-4 ND ug/L 1.0 0.48 1 06/29/2116:10 108-88-3 ND ug/L 1.0 0.33 1 06/29/2116:10 71-55-6 ND ug/L 1.0 0.32 1 06/29/2116:10 79-00-5 ND ug/L 1.0 0.38 1 06/29/2116:10 79-01-6 ND ug/L 1.0 0.30 1 06/29/2116:10 75-69-4 ND ug/L 1.0 0.26 1 06/29/2116:10 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 5 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY BLANKS Pace Project No.: 92546678 Sample: EB Parameters Lab ID: Results 92546678001 Units Collected: Report Limit 06/25/21 14:09 MDL DF Received: 06/25/21 16:43 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.3 1 06/29/21 16:10 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/29/21 16:10 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 06/29/21 16:10 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 06/29/21 16:10 460-00-4 1,2-Dichloroethane-d4 (S) 116 % 70-130 1 06/29/21 16:10 17060-07-0 Toluene-d8 (S) 109 % 70-130 1 06/29/21 16:10 2037-26-5 Date: 07/12/2021 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY BLANKS Pace Project No.: 92546678 Sample: FB Lab ID: 92546678002 Collected: 06/25/21 14:12 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 07/12/2021 05:20 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 06/29/2116:28 67-64-1 ND ug/L 10.0 1.8 1 06/29/2116:28 107-13-1 ND ug/L 1.0 0.34 1 06/29/2116:28 71-43-2 ND ug/L 1.0 0.47 1 06/29/2116:28 74-97-5 ND ug/L 1.0 0.31 1 06/29/2116:28 75-27-4 ND ug/L 1.0 0.34 1 06/29/2116:28 75-25-2 ND ug/L 2.0 1.7 1 06/29/2116:28 74-83-9 ND ug/L 5.0 4.0 1 06/29/2116:28 78-93-3 ND ug/L 2.0 0.73 1 06/29/2116:28 75-15-0 ND ug/L 1.0 0.33 1 06/29/2116:28 56-23-5 ND ug/L 1.0 0.28 1 06/29/2116:28 108-90-7 ND ug/L 1.0 0.65 1 06/29/2116:28 75-00-3 ND ug/L 5.0 1.6 1 06/29/2116:28 67-66-3 ND ug/L 1.0 0.54 1 06/29/2116:28 74-87-3 ND ug/L 2.0 0.34 1 06/29/2116:28 96-12-8 ND ug/L 1.0 0.36 1 06/29/2116:28 124-48-1 ND ug/L 1.0 0.27 1 06/29/2116:28 106-93-4 ND ug/L 1.0 0.39 1 06/29/2116:28 74-95-3 ND ug/L 1.0 0.34 1 06/29/2116:28 95-50-1 ND ug/L 1.0 0.33 1 06/29/2116:28 106-46-7 ND ug/L 1.0 0.56 1 06/29/2116:28 110-57-6 ND ug/L 1.0 0.37 1 06/29/2116:28 75-34-3 ND ug/L 1.0 0.32 1 06/29/2116:28 107-06-2 ND ug/L 1.0 0.35 1 06/29/2116:28 75-35-4 ND ug/L 1.0 0.38 1 06/29/2116:28 156-59-2 ND ug/L 1.0 0.40 1 06/29/2116:28 156-60-5 ND ug/L 1.0 0.36 1 06/29/2116:28 78-87-5 ND ug/L 1.0 0.36 1 06/29/21 16:28 10061-01-5 ND ug/L 1.0 0.36 1 06/29/2116:28 10061-02-6 ND ug/L 150 38.7 1 06/29/2116:28 123-91-1 ND ug/L 1.0 0.30 1 06/29/2116:28 100-41-4 ND ug/L 5.0 0.48 1 06/29/2116:28 591-78-6 ND ug/L 20.0 9.7 1 06/29/2116:28 74-88-4 2.1J ug/L 5.0 2.0 1 06/29/2116:28 75-09-2 ND ug/L 5.0 2.7 1 06/29/2116:28 108-10-1 ND ug/L 1.0 0.29 1 06/29/2116:28 100-42-5 ND ug/L 1.0 0.31 1 06/29/2116:28 630-20-6 ND ug/L 1.0 0.22 1 06/29/2116:28 79-34-5 ND ug/L 1.0 0.29 1 06/29/2116:28 127-18-4 ND ug/L 1.0 0.48 1 06/29/2116:28 108-88-3 ND ug/L 1.0 0.33 1 06/29/2116:28 71-55-6 ND ug/L 1.0 0.32 1 06/29/2116:28 79-00-5 ND ug/L 1.0 0.38 1 06/29/2116:28 79-01-6 ND ug/L 1.0 0.30 1 06/29/2116:28 75-69-4 ND ug/L 1.0 0.26 1 06/29/2116:28 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CO Page 7 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY BLANKS Pace Project No.: 92546678 Sample: FB Parameters Lab ID: Results 92546678002 Units Collected: Report Limit 06/25/21 14:12 MDL DF Received: 06/25/21 16:43 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.3 1 06/29/21 16:28 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/29/21 16:28 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 06/29/21 16:28 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 06/29/21 16:28 460-00-4 1,2-Dichloroethane-d4 (S) 118 % 70-130 1 06/29/21 16:28 17060-07-0 Toluene-d8 (S) 104 % 70-130 1 06/29/21 16:28 2037-26-5 Date: 07/12/2021 05:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY BLANKS Pace Project No.: 92546678 Sample: EB-metals Lab ID: 92546678003 Collected: 06/25/21 14:09 Received: 06/25/21 16:43 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/08/2111:00 07/09/2100:01 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:01 7440-38-2 Barium ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:01 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/08/2111:00 07/09/2100:01 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/08/2111:00 07/09/2100:01 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/08/2111:00 07/09/2100:01 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/08/2111:00 07/09/2100:01 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/08/2111:00 07/09/2100:01 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/08/2111:00 07/09/2100:01 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/08/2111:00 07/09/2100:01 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/08/2111:00 07/09/2100:01 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/08/2111:00 07/09/2100:01 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/08/2111:00 07/09/2100:01 7440-62-2 Zinc 11.2 ug/L 10.0 9.5 1 07/08/2111:00 07/09/2100:01 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.47 0.050 1 07/07/2113:27 07/08/2103:50 7440-28-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY BLANKS Pace Project No.: 92546678 QC Batch: 631987 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546678003 METHOD BLANK: 3320015 Associated Lab Samples: 92546678003 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 07/08/2123:19 Arsenic ug/L ND 10.0 4.7 07/08/2123:19 Barium ug/L ND 5.0 3.5 07/08/2123:19 Beryllium ug/L ND 1.0 0.70 07/08/2123:19 Cadmium ug/L ND 1.0 0.40 07/08/2123:19 Chromium ug/L ND 5.0 3.7 07/08/2123:19 Cobalt ug/L ND 5.0 3.6 07/08/2123:19 Copper ug/L ND 5.0 4.3 07/08/2123:19 Lead ug/L ND 5.0 4.5 07/08/2123:19 Nickel ug/L ND 5.0 3.5 07/08/2123:19 Selenium ug/L ND 10.0 4.7 07/08/2123:19 Silver ug/L ND 5.0 2.5 07/08/2123:19 Vanadium ug/L ND 5.0 3.9 07/08/2123:19 Zinc ug/L ND 10.0 9.5 07/08/2123:19 LABORATORY CONTROL SAMPLE: Parameter 3320016 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 493 99 80-120 Arsenic ug/L 500 476 95 80-120 Barium ug/L 500 487 97 80-120 Beryllium ug/L 500 492 98 80-120 Cadmium ug/L 500 490 98 80-120 Chromium ug/L 500 484 97 80-120 Cobalt ug/L 500 478 96 80-120 Copper ug/L 500 497 99 80-120 Lead ug/L 500 480 96 80-120 Nickel ug/L 500 487 97 80-120 Selenium ug/L 500 484 97 80-120 Silver ug/L 250 246 99 80-120 Vanadium ug/L 500 485 97 80-120 Zinc ug/L 500 489 98 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: SURRY BLANKS 92546678 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3320017 3320018 MS MSD 92546523001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 4.9J 500 500 510 514 101 102 75-125 1 20 Arsenic ug/L <4.7 500 500 504 506 101 101 75-125 0 20 Barium ug/L 474 500 500 970 965 99 98 75-125 1 20 Beryllium ug/L <0.70 500 500 506 503 101 101 75-125 0 20 Cadmium ug/L <0.40 500 500 507 509 101 102 75-125 0 20 Chromium ug/L <3.7 500 500 486 495 97 99 75-125 2 20 Cobalt ug/L 4.8J 500 500 480 482 95 95 75-125 0 20 Copper ug/L 500 500 512 517 102 103 75-125 1 20 Lead ug/L <4.5 500 500 481 481 96 96 75-125 0 20 Nickel ug/L 5.3 500 500 485 486 96 96 75-125 0 20 Selenium ug/L <4.7 500 500 512 517 102 103 75-125 1 20 Silver ug/L <2.5 250 250 254 255 101 102 75-125 1 20 Vanadium ug/L <3.9 500 500 501 507 100 101 75-125 1 20 Zinc ug/L <9.5 500 500 497 498 99 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY BLANKS Pace Project No.: 92546678 QC Batch: 631772 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92546678003 METHOD BLANK: 3318797 Matrix: Water Associated Lab Samples: 92546678003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.47 0.050 07/08/2103:40 LABORATORY CONTROL SAMPLE: 3318798 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 25.2 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3318799 3318800 MS MSD 92546678003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 25.5 25.2 102 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY BLANKS Pace Project No.: 92546678 QC Batch: 630255 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92546678001, 92546678002 METHOD BLANK: 3311481 Associated Lab Samples: 92546678001, 92546678002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/29/21 11:30 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/29/21 11:30 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/29/21 11:30 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/29/21 11:30 1,1-Dichloroethane ug/L ND 1.0 0.37 06/29/21 11:30 1,1-Dichloroethene ug/L ND 1.0 0.35 06/29/21 11:30 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/29/21 11:30 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/29/21 11:30 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 06/29/21 11:30 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/29/21 11:30 1,2-Dichloroethane ug/L ND 1.0 0.32 06/29/21 11:30 1,2-Dichloropropane ug/L ND 1.0 0.36 06/29/21 11:30 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/29/21 11:30 1,4-Dioxane (p-Dioxane) ug/L ND 150 38.7 06/29/21 11:30 2-Butanone (MEK) ug/L ND 5.0 4.0 06/29/21 11:30 2-Hexanone ug/L ND 5.0 0.48 06/29/21 11:30 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 06/29/21 11:30 Acetone ug/L ND 25.0 5.1 06/29/21 11:30 Acrylonitrile ug/L ND 10.0 1.8 06/29/21 11:30 Benzene ug/L ND 1.0 0.34 06/29/21 11:30 Bromochloromethane ug/L ND 1.0 0.47 06/29/21 11:30 Bromodichloromethane ug/L ND 1.0 0.31 06/29/21 11:30 Bromoform ug/L ND 1.0 0.34 06/29/21 11:30 Bromomethane ug/L ND 2.0 1.7 06/29/21 11:30 Carbon disulfide ug/L ND 2.0 0.73 06/29/21 11:30 Carbon tetrachloride ug/L ND 1.0 0.33 06/29/21 11:30 Chlorobenzene ug/L ND 1.0 0.28 06/29/21 11:30 Chloroethane ug/L ND 1.0 0.65 06/29/21 11:30 Chloroform ug/L ND 5.0 1.6 06/29/21 11:30 Chloromethane ug/L ND 1.0 0.54 06/29/21 11:30 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/29/21 11:30 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/29/21 11:30 Dibromochloromethane ug/L ND 1.0 0.36 06/29/21 11:30 Dibromomethane ug/L ND 1.0 0.39 06/29/21 11:30 Ethylbenzene ug/L ND 1.0 0.30 06/29/21 11:30 lodomethane ug/L ND 20.0 9.7 06/29/21 11:30 Methylene Chloride ug/L ND 5.0 2.0 06/29/21 11:30 Styrene ug/L ND 1.0 0.29 06/29/21 11:30 Tetrachloroethene ug/L ND 1.0 0.29 06/29/21 11:30 Toluene ug/L ND 1.0 0.48 06/29/21 11:30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY BLANKS Pace Project No.: 92546678 METHOD BLANK: 3311481 Associated Lab Samples: 92546678001, 92546678002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/29/21 11:30 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 06/29/21 11:30 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 06/29/21 11:30 Trichloroethene ug/L ND 1.0 0.38 06/29/21 11:30 Trichlorofluoromethane ug/L ND 1.0 0.30 06/29/21 11:30 Vinyl acetate ug/L ND 2.0 1.3 06/29/21 11:30 Vinyl chloride ug/L ND 1.0 0.39 06/29/21 11:30 Xylene (Total) ug/L ND 1.0 0.34 06/29/21 11:30 1,2-Dichloroethane-d4 (S) % 111 70-130 06/29/21 11:30 4-Bromofluorobenzene (S) % 97 70-130 06/29/21 11:30 Toluene-d8 (S) % 107 70-130 06/29/21 11:30 LABORATORY CONTROL SAMPLE: 3311482 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 49.6 99 70-130 1,1,1-Trichloroethane ug/L 50 47.1 94 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.0 100 70-130 1,1,2-Trichloroethane ug/L 50 49.4 99 70-130 1,1-Dichloroethane ug/L 50 48.9 98 70-130 1,1-Dichloroethene ug/L 50 48.2 96 70-132 1,2,3-Trichloropropane ug/L 50 48.8 98 70-130 1,2-Dibromo-3-chloropropane ug/L 50 55.1 110 70-132 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 70-130 1,2-Dichlorobenzene ug/L 50 52.5 105 70-130 1,2-Dichloroethane ug/L 50 47.8 96 70-130 1,2-Dichloropropane ug/L 50 49.1 98 70-130 1,4-Dichlorobenzene ug/L 50 51.2 102 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1020 102 70-137 2-Butanone (MEK) ug/L 100 105 105 70-133 2-Hexanone ug/L 100 100 100 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 99.3 99 70-130 Acetone ug/L 100 107 107 70-144 Acrylonitrile ug/L 250 247 99 70-130 Benzene ug/L 50 47.2 94 70-130 Bromochloromethane ug/L 50 47.3 95 70-130 Bromodichloromethane ug/L 50 47.9 96 70-130 Bromoform ug/L 50 44.0 88 70-131 Bromomethane ug/L 50 55.2 110 30-177 Carbon disulfide ug/L 50 50.0 100 70-133 Carbon tetrachloride ug/L 50 47.2 94 70-130 Chlorobenzene ug/L 50 46.8 94 70-130 Chloroethane ug/L 50 62.8 126 46-131 Chloroform ug/L 50 46.4 93 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY BLANKS Pace Project No.: 92546678 LABORATORY CONTROL SAMPLE: Parameter 3311482 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 Methylene Chloride ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits 46.7 93 49-130 49.2 98 70-130 50.2 100 70-130 52.3 105 70-130 46.8 94 70-130 46.1 92 70-130 104 104 47-140 47.9 96 68-130 48.5 97 70-130 44.8 90 70-130 45.9 92 70-130 49.9 100 70-130 52.0 104 70-130 63.3 127 25-200 46.6 93 70-130 43.6 87 61-130 118 118 70-140 47.1 94 59-142 142 95 70-130 100 70-130 99 70-130 96 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3311483 MS 92546336011 Spike Parameter Units Result Conc. MSD Spike Conc. 3311484 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.1 20.9 106 104 70-135 1 30 1,1,1-Trichloroethane ug/L ND 20 20 22.6 22.5 113 112 70-148 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.5 23.0 112 115 70-131 2 30 1,1,2-Trichloroethane ug/L ND 20 20 21.7 20.9 109 105 70-136 4 30 1,1-Dichloroethane ug/L ND 20 20 24.5 23.3 123 116 70-147 5 30 1,1-Dichloroethene ug/L ND 20 20 23.5 25.3 117 127 70-158 8 30 1,2,3-Trichloropropane ug/L ND 20 20 22.9 23.3 115 116 67-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 21.7 20.1 109 100 69-136 8 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.4 22.5 107 112 70-137 5 30 1,2-Dichlorobenzene ug/L ND 20 20 21.3 22.1 106 110 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 22.8 22.7 114 113 67-138 0 30 1,2-Dichloropropane ug/L ND 20 20 22.7 22.8 113 114 70-138 1 30 1,4-Dichlorobenzene ug/L ND 20 20 21.5 21.7 108 109 70-133 1 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 409 442 102 110 69-146 8 30 2-Butanone (MEK) ug/L ND 40 40 50.9 48.9 127 122 61-147 4 30 2-Hexanone ug/L ND 40 40 42.0 44.0 105 110 67-139 5 30 4-Methyl-2-pentanone ug/L ND 40 40 42.7 45.2 107 113 67-136 6 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 21 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY BLANKS Pace Project No.: 92546678 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3311483 3311484 MS MSD 92546336011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 49.7 47.7 124 119 55-159 4 30 Acrylonitrile ug/L ND 100 100 122 116 122 116 68-140 5 30 Benzene ug/L ND 20 20 22.7 22.7 113 114 67-150 0 30 Bromochloromethane ug/L ND 20 20 21.5 20.8 107 104 70-146 3 30 Bromodichloromethane ug/L ND 20 20 20.8 20.9 104 105 70-138 0 30 Bromoform ug/L ND 20 20 17.2 17.6 86 88 57-138 2 30 Bromomethane ug/L ND 20 20 28.7 28.1 144 140 10-200 2 30 Carbon disulfide ug/L ND 20 20 24.6 24.3 123 122 70-152 1 30 Carbon tetrachloride ug/L ND 20 20 21.9 21.0 110 105 70-147 4 30 Chlorobenzene ug/L ND 20 20 20.8 22.2 104 111 70-137 6 30 Chloroethane ug/L ND 20 20 26.2 25.1 131 125 51-166 4 30 Chloroform ug/L ND 20 20 24.6 24.4 123 122 70-144 1 30 Chloromethane ug/L ND 20 20 22.9 23.7 114 118 24-161 4 30 cis-1,2-Dichloroethene ug/L ND 20 20 23.9 23.2 119 116 67-148 3 30 cis-1,3-Dichloropropene ug/L ND 20 20 20.9 21.4 105 107 70-142 2 30 Dibromochloromethane ug/L ND 20 20 20.5 21.3 102 106 68-138 4 30 Dibromomethane ug/L ND 20 20 19.9 20.5 99 102 70-134 3 30 Ethylbenzene ug/L ND 20 20 21.1 22.4 106 112 68-143 6 30 lodomethane ug/L ND 40 40 37.3 41.3 93 103 20-161 10 30 Methylene Chloride ug/L ND 20 20 23.2 22.6 116 113 64-148 2 30 Styrene ug/L ND 20 20 21.0 22.0 105 110 70-136 5 30 Tetrachloroethene ug/L ND 20 20 20.4 20.3 102 101 70-139 1 30 Toluene ug/L ND 20 20 21.8 22.3 109 112 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.6 23.9 123 119 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.1 21.8 105 109 70-138 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 21.2 22.4 106 112 31-145 5 30 Trichloroethene ug/L ND 20 20 20.4 21.8 102 109 70-149 6 30 Trichlorofluoromethane ug/L ND 20 20 21.1 22.6 106 113 61-154 7 30 Vinyl acetate ug/L ND 40 40 49.8 48.1 125 120 48-156 4 30 Vinyl chloride ug/L ND 20 20 24.2 24.0 121 120 55-172 1 30 Xylene (Total) ug/L ND 60 60 64.1 67.0 107 112 66-145 4 30 1,2-Dichloroethane-d4 (S) % 112 106 70-130 4-Bromofluorobenzene (S) % 97 100 70-130 Toluene-d8 (S) % 100 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: SURRY BLANKS Pace Project No.: 92546678 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS CO Result confirmed by second analysis. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 21 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: SURRY BLANKS 92546678 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92546678003 EB-metals EPA 3010A 631987 EPA 6010D 632207 92546678003 EB-metals EPA 3010A 631772 EPA 6020B 631953 92546678001 EB EPA 8260D 630255 92546678002 FB EPA 8260D 630255 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/12/2021 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 21 Document Name: Document Revised: October 28, 2020 Sample Condition Upon Receipt(SCUR) Page 1 of 2 aci3MafyticatLDocument No.: Issuing Authority F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ HuntersvilleIr"P11. Raleigh❑ Mechanicsville❑ Atlanta[] Kernersville❑ Name: Project # WO#:92546676 92546678 Custody Seal Present? Dyes 'J;4N0 Seals Intact? ❑Yes [gNo DateiGnilia Werson-Examining-Gontent Packing Material: ❑Bubble Wrap [RBubbie Bags [-]None ❑ other Biological Tissue Frozen? Thermometer: [-]Yes []No 19N/A Wet ❑9iue ❑None IR Gun ID: 921064 Type of ice: q Correction Factor Cooler Temp: Add/Subtract (°Ci _0 1 Temp should be above freezing to 6'C q ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): U.8 has begun USDA Regulated Sail ( ® N/A, water sample} Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source {internationally, l—IYes nNn Includrne Hawaii and Puerto Wcoi? FlYes 11No Comments/Discrepancy: Chain of Custody Present? blYes ❑No ❑N/A 1. Samples Arrived within Hold Time? 3yes ❑No ❑N/A 2. Short Hold Tlme Analysis <72 hr.i? ❑Yes IgNo ❑N/A 3. Rush Turn Around Time Requested? ❑Yes gNo ❑N/A 4. Sufficient Volume? 'Yes ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? ®Yes ®Yes [:)No ❑No [-]N/A ❑N/A 6. Containers Intact? ®Yes []No []N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes gNo [-]NIA B. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: 19Yes [:]No ❑N/A 9. Headspace in VOA Vials (>5-6mm)? [-]Yes ®No [I N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes []Yes ❑No []No 5gN/A N/A 11, j V � on IQ ,P�D, _ _ Lot ID of split containers: _ CLIENT NOTIFICATION/RESOLUTION need -to kia ye- Vla:, a 1p a !M aed _ -ror yne-W c- . OI +- rnn Go(- �Jo _ �n e� Qs need e d_fo r F:6 - - - - - - -- Person contacted: Fyo_y) La*yj b,e�--t _ Date/Time: U -aq Project Manager SCURF Review: — f t`" 6 Date: te -';'Cl —a 1 Project Manager SRF Review: Page 19 of 21 Document Name: Document Revised: October 28, 2020 Samule Condition Uoon ReceiotlISCURi I paEP 7 of 7 (ALjU"""y"°"" Document No.: F-CAR-CS-033•Rev.07 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg ** tom_halUoUbox_istoiist_number_of_botties _ Issuing Authority: Pace Carolinas quality Office Project ol# ; 92546678 p14: pM8 Due Date: 07/12A21 CLIENT: 92—Municipal j u u T V N = = N N Z Z Z = Z N Q \ Z ? �— Z N N 2 Y z Qtfa Q z a? O a v 2 di `fi m v x w m 4 z m ¢ ? n z u w N w b N o`c ii w Z O \ M z [y G 7 LI j C y 2 N Z M Dy u x n� S 4 0 a �n ut > ro a a z D z '^ « u tnn u N a 07 `a a y J E V 2 Z 7 T �t M >i v N `m a d a ro a a a m a ro a m a a E L 4 E ¢ M E E ¢ L r� a a O Q O a O a n �' W in a E a c .o 4 J J d J J J J Q J 7o N 'n sn E E E E E E E p mm E -u E E ' E E E ° N ° J E E E E E E Ln o o r u0 � - o «_ v gyp. S N Ln o O O O r-1 .i 1N 7 Ul H H IA N Z ,Ny N ,Ny U w'. •-I •% rl T ry ry IA �f O_ Q = F- � n1 u1 F� Q n a � a V. rl N M rl M ffi G� Q1 O� 6� d 'I> i11 N M 0 (7 m ar IL 0. 0. a $ U C7 U' aS to lJ L9 l7 t7 �7 O � a 0. � l7 to l7 m m m m m m m m a a a a a a e } c�� > > .n v, m a a o 1 l 3 4 5 6 7 S 9 10 11 12 J�s pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina OEHNR Certification Office (Le, Out of hold, incorrect preservative, out of temp, incorrect containers. Page 20 of 21 A v m G) n n N i m co .t m cn A w Iv ITEM# d, 3 3 w o (D H m T Co 03 m 0 z n O a sv cn O �2rm D CU n a O C-) a D Ca N 0 C O te'i l� CN'1 0 j is D I'1'I 0 p �. 0 r O C m �. 7 in yz n m N - 3 in o n - C c n o 0 m m r m m z MATRIX CODE {see valftl codes to [aft) z z j A r Q N P v SAMPLE TYPE (G=GRAB C=COMP) rn y 07 �4 D A 0 � N =r n }J 3 r m n o Gr m r y 71 0 2 XIN g ^ ❑ m p m p m p m Z z N to r r SAMPLE TEMP AT COLLECTION m � ' m � � z c � m m n o a a 9OF CONTAINERS m Q 3 Llnpraserved �y 3 m v o v o 0 r w Y o a H2SO4 m at m m HNO3 -U v @ .,� FiCI m NaOH m m n M Na2S203 m m Methanol � C. CDOthar c° < 'p con Analyses Test YIN r z ti VOCs-App 1 z ❑ a N N astsr Metals-App 1 z n � , 0 1,4-❑ioxane (NON-SIM) z m a y z 00 u n t� � Imo: ❑ N h T f 1'•r a { z 3 1J� m a N O E; C TEMP in C ' n m r o •Z i b 9 n 0 ^ Received on Ice (V!N) r- C rn 0 p 1 �1 T Custody Sealed; Cooler (YIN)" z rn Samples Intact � (YIN) 0 Page 21 of 21