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HomeMy WebLinkAbout24008_Selles Bagwell_Brownfields Assessment Report_20210406 i S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx Brownfields Assessment Report Selles Bagwell Brownfields Property S. Tryon Street and Distribution Street Charlotte, North Carolina Brownfields Project ID: 24008-20-060 H&H Job No. PRO-011 Table of Contents Section Page No. 1.0 Introduction ............................................................................................................................ 1  1.1 Background ........................................................................................................................... 2  1.2 Previous Environmental Assessments .................................................................................. 3  1.3 Brownfields Program Eligibility .......................................................................................... 4  2.0 Brownfields Assessment Activities ....................................................................................... 6  2.1 Utility Clearance ................................................................................................................... 6  2.2 Permitting Activities ............................................................................................................. 7  2.3 Soil Assessment Activities ................................................................................................... 7  2.4 Soil Analytical Results .......................................................................................................... 9  2.5 Groundwater Assessment ................................................................................................... 10  2.6 Groundwater Sample Results .............................................................................................. 12  2.7 Soil Vapor Assessment ....................................................................................................... 13  2.8 Soil Vapor Sample Results .................................................................................................. 15  2.9 Quality Assurance/Quality Control ..................................................................................... 15  3.0 Risk Calculations ................................................................................................................. 17  3.1 Groundwater Risk Calculations ........................................................................................... 17  3.2 Vapor Risk Calculations ...................................................................................................... 17  4.0 Summary and Conclusions ................................................................................................. 18  ii S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx List of Tables Table 1 Summary of Soil Analytical Results Table 2 Summary of Temporary Well Construction Table 3 Summary of Groundwater Analytical Results and Risk Calculations Table 4 Summary of Vapor Analytical Results and Risk Calculations List of Figures Figure 1 Site Location Map Figure 2 Site Map Figure 3 Sample Location Map Figure 4 Groundwater Elevation Contour Map List of Appendices Appendix A Boring Logs Appendix B Laboratory Analytical Report Appendix C Risk Calculations 1 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx Brownfields Assessment Report Selles Bagwell Brownfields Property S. Tryon Street and Distribution Street Charlotte, North Carolina Brownfields Project ID: 24008-20-060 H&H Job No. PRO-011 1.0 Introduction On behalf of FHN 2301 South Tryon, LLC c/o The Providence Group, Hart & Hickman, PC (H&H) has prepared this Brownfields Assessment Report to document soil, groundwater, and vapor sampling activities conducted at the Selles Bagwell Brownfields property located south of the intersection of S. Tryon Street and Dunavant Street in Charlotte, Mecklenburg County, North Carolina (Site). The Site is in the North Carolina Department of Environmental Quality (DEQ) Brownfields Program (ID# 24008-20-060). A Site location map is provided as Figure 1. The Site consists of the following six (6) contiguous parcels of land that total approximately 4.07 acres:  Parcel #12104301 (2301 S. Tryon Street) – a 0.455-acre industrial property developed with a 4,500-square ft office/warehouse building constructed in 1984 and most recently occupied by Kelly & McArdle Construction;  Parcel #12104302 (2311 S. Tryon Street) – a 0.563-acre industrial property developed with a 13,000-square ft office/warehouse building constructed in 1967 and currently occupied by Best Tile;  Parcel #12104303 (2321 S. Tryon Street) – a 1.088-acre industrial property developed with an 8,900-square ft office/warehouse building constructed in 1959 and currently occupied by Interstate Electric;  Parcel #12104304 (2405 S. Tryon Street) – a 0.497-acre industrial property developed with a 9,000-square ft duplex office/warehouse building constructed in 1976 and currently unoccupied; 2 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx  Parcel #12104319 (2300 Distribution Street) – a 0.661-acre industrial property developed with a 15,508-square ft office/warehouse building constructed in 1966 and currently occupied by World of Stone; and  Parcel # 12104317 (2322-2324 Distribution Street) – a 0.808-acre industrial property developed with an 11,370-square ft duplex warehouse building constructed in 1964 and currently occupied by Charlotte Grill (2324-A) and Pet Wants: Urban Feed Store (2324-B). The remaining portions of the Site consist are developed with a diesel aboveground storage tank (AST) and dispenser located at Interstate Electric, asphalt paved parking areas and access drives, landscaped and naturally vegetated areas, and chain-link fencing. A Site map is provided as Figure 2. 1.1 Background Prior to the development of the on-Site structures listed above, the Site was agricultural land in the earliest historical resource reviewed, a 1938 aerial photograph. Historically, the parcels that comprise the Site were developed as follows:  2301 S. Tryon Street – was developed with Standard Memorial and Beasley Coal in the 1930s, and a single-family residence in the 1940s through the 1960s. In the 1960s, the residence was razed, and the parcel consisted of vacant land until the 1980s. Currently, the parcel is developed with an industrial office/warehouse constructed in 1988.  2311 S. Tryon St. – is currently developed with an industrial office/warehouse (former mill) constructed in the 1960s. Selles Bagwell formerly occupied the mill.  2321 S. Tryon St. – is currently developed with an industrial office/warehouse constructed in the 1950s. 3 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx  2405 S. Tryon St. – is currently developed with an industrial office/warehouse constructed in the early 1980s.  2300 Distribution St. – is currently developed with an industrial office/warehouse in the late 1960s. The warehouse was occupied by Chase Brass C Copper Inc; a distributing company in the late 1960s, Gable Sales; a manufacturer agent company from the mid-170s through the mid-1980s, Arlo Specialty Metals Inc, a tool supplier in the late 1980s-early 1990s, and World of Stone Fabricators from the late 1990s to present.  2322-2324 Distribution Street – is currently developed with an 11,370-square ft warehouse building constructed in 1964. The warehouse building has been occupied by Mutual Distributing Co., a beer and wine distributor from the late 1960s to mid-1970s, Maaco Industries, Inc., an industrial machinery and equipment design/fabrication/installation company, and SGF Inc. in the 1980s, Chem Clean Inc., a janitorial supplies company from the late-1980s to early 2000s, Interior Constructors in the 1990s, Five Suns Inc. in the late 1990s, Power Trane Corp. in the 2000s, Southend Imports LLC, an auto service company from the 2000s to 2010s, AVS Custom Iron Works in 2010, DJ Distributing and a woodshop in the late 2010s, and Charlotte Grill and Pet Wants-Urban Feed Store from late 2010s to the present. 1.2 Previous Environmental Assessments H&H conducted a Phase II ESA at 2300 Distribution Street in December 2019, which included the collection of groundwater and sub-slab vapor samples for laboratory analysis. The assessment activities were conducted to assess the potential for impact to the subject Site from historical Site operations, upgradient contaminant sources, and evaluate potential risks associated with future Site development, including the potential for vapor intrusion. Two temporary monitoring wells were installed and sampled on the eastern and northern portions of the parcel. Results of groundwater sampling activities identified trichloroethylene (TCE) and tetrachloroethylene (PCE; reported as an estimated J-flag value) in the groundwater sample 4 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx collected from TMW-1 (located in the eastern portion of the parcel) at concentrations above NCAC 2L Groundwater Quality Standards (2L Standards). The semi-volatile organic compound (SVOC), bis(2-ethylhexyl)phthalate was detected in the TMW-2 (located in the northern portion of the parcel) groundwater sample; however, at a concentration below the 2L Standard. To further evaluate the detected compounds, H&H input the concentrations of the compounds detected in the groundwater samples into the DEQ Risk Calculator. Risk calculator results for the groundwater sample collected in the eastern portion of the parcel (TMW-1) indicated an unacceptable risk for vapor intrusion if that portion of the parcel is developed in the future for residential use. H&H also installed and sampled two (2) sub-slab vapor monitoring points (SS-1 and SS-2) located in the southern and northern portions of the World of Stone building. Results of sub-slab vapor sampling activities conducted within the existing Site building did not identify the potential for vapor intrusion above acceptable levels under a residential or non-residential use scenario. 1.3 Brownfields Program Eligibility The Site originally consisted of five of the parcels mentioned above and had received a letter of eligibility (LOE) from DEQ for entry into the Brownfields Program on July 2, 2020. During an initial Site meeting and follow-up email correspondence, the DEQ Brownfields Project Manager, Mr. Cody Cannon requested that additional soil, groundwater, soil gas, and sub-slab soil vapor sampling be completed to evaluate current environmental conditions of the five Site parcels. During this time, the Providence Group was in the process of purchasing a 0.808-acre industrial property (Parcel #12104317; 2322-2324 Distribution Street) located adjacent to, and south of the Selles Bagwell Brownfields property. This property is referred to as the Charlotte Grill property. Therefore, soil, groundwater, and sub-slab vapor assessment activities were also proposed for the additional parcel in the Brownfields Assessment Work Plan dated December 17, 2020. The DEQ Brownfields Program provided work plan approval via a letter dated December 20, 2020. The additional parcel was included in a revised Brownfields property application affidavit dated 5 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx January 19, 2021, and the DEQ Brownfields Program issued an amended letter of eligibility dated February 5, 2021 adding the parcel to the Selles Bagwell Brownfields property. A summary of our soil, groundwater, and vapor assessment activities conducted in accordance with the approved DEQ Brownfields Work Plan is provided in the following section. 6 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx 2.0 Brownfields Assessment Activities On December 22 and 23, 2020, and January 4 and 21, 2021, H&H conducted Brownfields assessment activities at the Site. The Brownfields assessment activities included the collection of five (5) soil samples from eight (8) soil borings, the collection of five (5) groundwater samples, the collection of one (1) soil gas sample, and the collection of eight (8) sub-slab vapor samples. The assessment activities were performed in general accordance with the DEQ Inactive Hazardous Sites Branch (IHSB) Guidelines for Assessment and Cleanup (Guidelines) dated January 2020, the DEQ Division of Waste Management (DWM) Vapor Intrusion Guidance dated March 2018, and the most recent version of the U.S. Environmental Protection Agency (EPA) Region IV Science and Ecosystem Support Division (SESD) Field Branches Quality System and Technical Procedures guidance, and the DEQ-approved Work Plan. 2.1 Utility Clearance Prior to conducting Brownfields assessment activities, H&H contacted North Carolina 811 One- Call, the public utility locating service, to mark subsurface utilities at the Site. H&H also contracted with a private utility locator, Integrated Scanning Solutions (ISS), to screen the proposed boring locations for subgrade utilities using ground-penetrating radar (GPR) and electromagnetic methods. In addition, a decontaminated hand auger was advanced to a depth of approximately five ft below ground surface (bgs) at each proposed boring location to further clear the borings of potential subsurface utilities. 7 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx 2.2 Permitting Activities In accordance with Mecklenburg County regulations, H&H obtained a Subsurface Investigation Permit (SIP) from the Mecklenburg County Land Use and Environmental Services Agency (LUESA) prior to beginning groundwater assessment activities. After sampling was completed, the SIP was closed out by submitting well abandonment records to LUESA. 2.3 Soil Assessment Activities H&H contracted with MidSouth Environmental (MidSouth), a North Carolina licensed driller to advance soil borings in DEQ Brownfields requested locations to further evaluate soil conditions at the Site:  One (1) soil boring (SB-1) was advanced adjacent to the existing diesel AST fueling system located on the Interstate Electric property (2321 S. Tryon Street) to a depth of 5 ft below the ground surface (bgs) for the collection of a grab sample.  One (1) soil boring (SB-2) was advanced in the former underground storage tank (UST) basin located on the Interstate Electric property (2321 S. Tryon Street) to a depth of 10 ft bgs for the collection of a grab sample.  Four (4) soil borings (SB-3A to SB-3D) were advanced in an area of a former coal pile previously located on the former Kelly & McArdle property (2301 S. Tryon Street) to a depth of 3 ft bgs for the collection of a grab/composite sample.  One (1) soil boring (SB-4) was advanced within the Charlotte Grill's warehouse (2324-A Distribution Street) adjacent to a former in-ground hydraulic automobile lift to a depth of 12 ft bgs.  One (1) soil boring (SB-5) was advanced adjacent to the Charlotte Grill’s loading dock (2324-A Distribution Street) to a depth of 6 ft bgs. 8 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx At each boring location, continuous soil samples were collected by a decontaminated hand auger and/or utilizing a direct-push technology (DPT) drill with a decontaminated five ft long Macro- Core® sampler with disposable acetate liners. Continuous soil samples were logged for lithological description and field screened to indicate potential impacts by observation for staining, odors, and the presence of organic vapors using a calibrated photoionization detector (PID). Soil boring logs are included in Appendix A. With the exception of a slightly elevated PID reading of 37.4 parts per million (ppm) collected from 0.5-1.5 ft bgs in soil boring SB-1, elevated PID readings were not encountered during boring advancement. Due to the lack of elevated PID readings, soil samples were collected from the remaining borings from a depth interval where impacts were most likely to be encountered.  SB-1 – adjacent to an existing diesel fuel dispenser located on the Interstate Electric property (2321 S. Tryon Street) collected from a depth interval of 0.5 to 1.5 ft bgs.  SB-2 – in the former underground storage tank (UST) basin located on the Interstate Electric property (2321 S. Tryon Street) collected from a depth interval of 10 to 12 ft bgs.  SB-3 – in an area of a former coal pile previously located on the former Kelly & McArdle property (2301 S. Tryon Street); one grab sample was collected from SB-3C from 1 to 2 ft bgs and soil from a depth interval from 1 to 2 ft bgs was collected from SB-3A through SB-3D and was composited in the field.  SB-4 – adjacent and below the bottom of a former in-ground hydraulic automobile lift located in Charlotte Grill’s warehouse (2324-A Distribution Street) from 10 to 12 ft bgs.  SB-5 - adjacent to the Charlotte Grill's loading dock (2324-A Distribution Street) collected from 0.5-1.5 ft bgs. Soil samples selected for laboratory analysis were collected directly into laboratory supplied glassware, labeled with the sample identification, date, time, and requested analyses, and placed in a laboratory supplied cooler with ice. The samples were delivered to Waypoint Analytical (Waypoint), a North Carolina certified laboratory under standard chain of custody protocols. The SB-1, SB-2, SB-4, and SB-5 soil samples were submitted for analysis of volatile organic 9 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx compounds (VOCs) by EPA Method 8260, SVOCs by EPA Method 8270, and Resource Conservation and Recovery Act (RCRA) metals plus hexavalent chromium by EPA Methods 6020/7471/7199. The RCRA metals include arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver. One grab soil sample was collected from soil boring SB-3C, since it exhibited the greatest evidence of impact (e.g., highest PID reading of 3.1 ppm) and was submitted for analysis of VOCs by EPA Method 8260. The remaining soil collected from borings SB-3A through SB-3D from the 1-2 ft bgs intervals was composited in the field and submitted to the lab for analysis of SVOCs by EPA Method 8270 and RCRA metals plus hexavalent chromium by EPA Methods 6020/7471/7199. The soil boring locations were estimated (horizontal and vertical elevations) using a sub-meter GPS unit. Upon completion of the soil sampling activities, H&H directed the drilling contractor to abandon the borings with bentonite and/or grout. 2.4 Soil Analytical Results Laboratory analytical results were compared to DEQ Protection of Groundwater, Residential, and Industrial/Commercial Preliminary Soil Remediation Goals (PSRGs) dated January 2021 and published naturally occurring background metals concentrations in North Carolina soils as described in Elements in North American Soils by Dragun and Chekiri, dated 2005. A discussion of the laboratory analytical results for the Brownfields assessment soil samples is provided below, and a summary of the laboratory analytical data is provided in Table 1. The laboratory analytical data report and chain of custody record are included in Appendix B. VOCs Acetone and methylene chloride, common laboratory contaminants, were detected above laboratory detection limits in SB-2, SB-3 and SB-4, and SB-4, respectively. However, the detections were detected below Protection of Groundwater, Residential, and Industrial/Commercial PSRGs. 10 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx Metals As expected, several metals were detected at concentrations above laboratory detection limits. Selenium was detected in the soil samples collected from SB-3 and SB-4 at concentrations of 2.3 milligram/kilogram (mg/kg) and 3.3 mg/kg, respectively, above the Protection of Groundwater PSRG of 2.1 mg/kg, and the regional background concentration of 0.42 mg/kg. In addition, arsenic was detected in each soil sample above the Residential PSRG. However, the arsenic concentrations were within the range of naturally occurring background concentrations (Dagun and Chekiri, 2005). SVOCs None of the soil samples had detections of SVOCs above laboratory detection limits. 2.5 Groundwater Assessment H&H contracted with MidSouth to install five (5) temporary monitoring wells at the following on- Site locations:  One (1) temporary monitoring well (TW-3) was advanced in the former UST basin located on the Interstate Electric property (2321 S. Tryon Street) and encountered boring refusal at an approximate depth of 15 ft bgs.  One (1) temporary monitoring well (TW-4) was advanced in the southern portion of the Site on the Interstate Electric property (2321 S. Tryon Street) to an approximate depth of 17 ft bgs.  One (1) temporary monitoring well (TW-5) was advanced downgradient of the existing diesel AST fueling system located on the Interstate Electric property (2321 S. Tryon Street) to an approximate depth of 14 ft bgs.  One temporary monitoring well (TW-6) was advanced at a location in the upgradient northern corner of the Site on the former Kelly & McArdle property (2301 S. Tryon Street) and encountered boring refusal at an approximate depth of 14 ft bgs. 11 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx  One (1) temporary monitoring well (TW-7) was advanced in the northern portion of the property at a location downgradient of the PCE release identified adjacent to the World of Stone parcel to a depth of 14 ft bgs. The temporary monitoring well borings were initially advanced using a decontaminated hand auger and further advanced utilizing a direct-push technology (DPT) drill rig with a decontaminated five ft long Macro-Core® sampler with disposable acetate liners to depths below the water table. During boring advancement, H&H collected continuous soil samples from each soil boring, logged lithology, and field screened the samples for the presence of staining, odors, and volatile organic vapors utilizing a calibrated PID. Temporary monitoring well boring logs are included in Appendix A. The temporary monitoring wells were constructed using 1-inch diameter PVC riser. Due to boring refusal, TMW-3 and TW-6 were constructed with a 5 ft section of PVC screen set to bracket the water table, and TMW-4, TW-5, and TW-7 were constructed with 10 ft sections of PVC screen set to bracket the water table. A filter sand pack was installed from the bottom of each well boring to approximately 2 ft above the well screens, and a bentonite seal was installed above the filter sand pack. Well construction details are provided in Table 2. Upon completion of temporary monitoring well installation activities, the temporary monitoring wells were allowed to equilibrate to static conditions, and a decontaminated electronic water level indicator was used to measure the depth of the groundwater relative to the ground surface. Water level information is provided on Table 2. Prior to sampling, H&H developed the temporary monitoring wells by removing at least three well volumes using a peristaltic pump. Once three well volumes were removed, the temporary wells were purged using low flow methods until field parameters of temperature, pH, specific conductivity, and oxidation-reduction potential (ORP) stabilized and turbidity was measured at or less than 10 Nephelometric Turbidity Units (NTUs). While developing temporary monitoring wells TW-4 and TW-7, turbidity was not measured below 10 NTUs. Therefore, due to the elevated 12 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx turbidity readings, H&H collected filtered and unfiltered samples for RCRA metals from TM-4 and TW-7. Groundwater sampling forms are included in Appendix A. Following stabilization of field parameters, groundwater samples were collected using low-flow sampling techniques and the “soda straw” sampling method for VOCs. The groundwater samples were then placed in a laboratory supplied cooler, iced, and shipped under standard chain of custody protocol to Waypoint for analysis of VOCs by EPA Method 8260, SVOCs by EPA Method 8270, and RCRA Metals by EPA Methods 6020/7471. The RCRA metals include arsenic, barium cadmium, chromium, lead, mercury, selenium, and silver. Following sampling activities, the temporary monitoring wells were abandoned, and the ground surface locations were patched to match pre-drilling conditions. 2.6 Groundwater Sample Results Groundwater sample analytical results were compared to 2L Standards and the DEQ DWM residential and non-residential vapor intrusion Ground Water Screening Levels (GWSLs). Analytical results of the groundwater samples collected from the temporary monitoring wells are summarized in Table 3, and the laboratory analytical report is contained in Appendix B. According to the laboratory results, vinyl chloride was detected in TW-4 (32 micrograms per liter [µg/L]) and TW-5 (2.2 µg/L) at concentrations above the 2L Standard of 0.3 µg/L and the residential vapor intrusion GWSL of 0.15 µg/L. In addition, 1,4-dioxane was detected at estimated concentrations (J -value) of 25 J µg/L and 19 J µg/L, respectively, above the 2L Standard (0.7 µg/L). Other VOC constituents were detected above laboratory detection limits, however, were detected below 2L Standards and GWSLs. As expected, metal constituents were detected in the groundwater samples, however the concentrations were below 2L Standards and GWSLs. Furthermore, SVOCs, were detected below laboratory detection limits in all of the collected groundwater samples. 13 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx 2.7 Soil Vapor Assessment On December 23, 2020, one soil gas vapor point (SG-1) was advanced in the eastern portion of the Site adjacent to the former TW-1 temporary monitoring well (installed during previous Phase II ESA activities) located on the World of Stone property (2300 Distribution Street) to an approximate depth of 5 ft bgs. The soil gas point was installed using a decontaminated hand auger with a 6-inch 0.010-inch stainless steel screen set at the base of the boring connected to the surface with ¼-inch Teflon tubing. The annular space was filled with filter sand followed by a hydrated bentonite seal to prevent short-circuiting of air from the surface. Using a syringe, the sample point was purged of a minimum of three times the volume of the annular space plus the tubing volume. During previous Phase II ESA sampling activities, H&H installed two permanent sub-slab vapor points (SS-1 and SS-2) at locations in the World of Stone warehouse (2300 Distribution Street). In addition to re-sampling SS-1 and SS-2, H&H installed and sampled six (6) additional sub-slab vapor points (SS-3 to SS-8) at the following on-Site locations:  One sub-slab vapor point (SS-3) was advanced in the concrete floor of the Best Tile warehouse (2311 S. Tryon Street).  One sub-slab vapor point (SS-4) was advanced in the concrete floor of the Interstate Electric warehouse (2321 S. Tryon Street).  One sub-slab vapor point (SS-5) was advanced in the concrete floor of the vacant warehouse (2405 S. Tryon Street).  One sub-slab vapor point (SS-6) was advanced in the concrete floor of the former Kelly & McArdle warehouse (2301 S. Tryon Street).  One (1) sub-slab vapor point (SS-7) was advanced in the concrete floor of Charlotte Grill's warehouse (2324-A Distribution Street).  One (1) sub-slab vapor point (SS-8) was advanced in the concrete floor of Pet Wants: Urban Feed Store (2324-B Distribution Street) warehouse. 14 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx For each sub-slab vapor sample point, an initial 1 ½-inch diameter hole was drilled into the concrete slab to a depth of approximately 1 ¾ inches using a hammer drill. Then, a drill guide was placed in the hole, and a hammer drill, equipped with a 5/8-inch diameter bit, was utilized to advance the borehole through the concrete slab and approximately 6 inches into the underlying soil to form a void. Following concrete borehole advancement, loose cuttings were removed using a bottle brush and HEPA vacuum. A Vapor Pin™ assembly (brass sampling point and silicone sleeve) was then placed and seated in the drilled hole by tapping the Vapor Pin assembly using an installation/extraction tool and a "dead blow" hammer. The sampling points were installed as flush-mounted points, and a protective cap was placed on the Vapor Pin sampling barb fitting. Following installment, each sample point was purged of a minimum of three times the volume of the annular space plus the tubing volume using a syringe. Prior to collecting the vapor samples, leak checks were completed for the soil gas sample point, SG-1, and the soil vapor sample points, SS-1 through SS-8. The leak checks were performed prior to collecting the vapor samples by first placing a shroud over each sample point, filling the shroud with helium gas, and using a field helium gas detector to verify that the shroud was saturated with helium gas. Then, the sample points were purged using a syringe and a three-way valve to collect purged vapor into a Tedlar® bag. The purged vapor was subsequently analyzed using a helium gas detector to ensure that helium concentrations were less than 10% of the helium concentrations in the shroud. Following a successful leak check, the soil gas and the sub-slab vapor samples were collected using one-liter Summa® canisters. Shut-in leak tests were performed on each Summa canister and sampling train prior to sampling. The Summa® canisters were connected to the Vapor Pin via Teflon® tubing. The Summa® canisters will be allowed to fill slowly (less than 200 milliliters per minute [mL/min]) using an airflow regulator. Prior to and after the samples were collected, vacuum in the canisters were measured using a laboratory-supplied vacuum gauge and recorded by sampling personnel. The vacuum pressure in each Summa canister upon completion of the 15 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx sampling event was between three and six inches of mercury. The laboratory was also instructed to use reporting limits that are below applicable DEQ screening levels for the VOCs to the extent possible. Following sample collection, the Summa® canisters were delivered under standard chain-of- custody protocols to Waypoint, a nationally accredited air laboratory for analysis of VOCs by EPA Method TO-15. The starting and ending vacuum in each canister were recorded on the sample chain-of-custody. Upon receipt of the samples, the laboratory recorded the final received vacuum pressure for each Summa canister. 2.8 Soil Vapor Sample Results Numerous trace levels of VOCs were detected in the soil gas and sub-slab vapor samples, which is typical of such datasets. According to the results, benzene was detected in soil gas SG-1 (52 micrograms per cubic meter [µg/m3]) above the DWM Residential Sub-Slab and Exterior Soil Gas Screening Level of 12 µg/m3. In addition, TCE was detected in soil gas point SG-1 at a concentration of 1,400 µg/m3 above the DWM Residential and Non-Residential Sub-Slab and Exterior Soil Gas Screening Levels of 14 µg/m3 and 180 µg/m3. A summary of soil gas and sub- slab vapor detections are provided in Table 4. The laboratory analytical reports are included in Appendix B. 2.9 Quality Assurance/Quality Control H&H utilized standard quality assurance/quality control (QA/QC) processes during the Brownfields assessment activities. Non-dedicated sampling equipment, including DPT tooling, the water level meter, and the hand auger were decontaminated using Liquinox® detergent and deionized water prior to and between each sampling location. H&H and MidSouth wore nitrile gloves while handling samples. Soil samples were collected in laboratory-provided containers and placed on ice immediately upon collection. 16 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx In addition, for QA/QC purposes, H&H collected one duplicate soil sample from soil boring SB- 1 (0.5-1.5), one duplicate groundwater sample from TW-6, and one duplicate vapor sample from SG-1. The duplicate samples were sampled for the same compounds as the parent samples. The duplicate samples' results are provided in Tables 1, 3, and 4 and indicate good analytical repeatability for the duplicate samples. 17 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx 3.0 Risk Calculations To further evaluate the detected compounds in the groundwater and vapor samples, H&H input the concentrations of the detected compounds into the DEQ Risk Calculator (January 2021 Version) to calculate cumulative potential carcinogenic and non-carcinogenic risks. The screening levels are based upon a lifetime incremental cancer risk (LICR) of 1 x 10-6 for potential carcinogenic effects and a hazard index (HI) of 0.2 for potential non-carcinogenic effects. Vapor intrusion mitigation for occupied residential and commercial structures is not typically considered unless the LICR exceeds 1 x 10-4 and/or the HI exceeds 1. Based on future Site redevelopment plans, the Site may be utilized for residential and commercial purposes, therefore, calculations were run for both residential and non-residential exposure scenarios. 3.1 Groundwater Risk Calculations The calculated LICR for a residence for groundwater sample TW-4 (2.2 x 10 -4) was above the acceptable risk range of 1 x10-4 to 1 x 10-6. The calculated LICRs for a residence and a non- residential worker for the remaining groundwater samples were within or below the acceptable risk range of 1 x10-4 to 1 x 10-6 and the calculated HIs were less than 1 from the constituents detected in the groundwater samples. 3.2 Vapor Risk Calculations The calculated LICRs for a resident and a non-residential worker were within or below the acceptable risk range of 1 x10-4 to 1 x 10-6 for the constituents detected in the vapor samples collected from SG-1 (eastern portion of the Site) in January 2021. However, for a residential and non-residential exposure scenario, the calculated HI exceeds the acceptable level of 1 in the SG-1 sample location (20 and 1.6, respectively). 18 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx 4.0 Summary and Conclusions H&H has completed Brownfields assessment activities at the Selles Bagwell Brownfields property located south of the intersection of S. Tryon Street and Dunavant Street in Charlotte, Mecklenburg County, North Carolina. The purpose of the assessment was to provide additional assessment activities to 1) further assess data gaps identified during the project kick-off meeting and 2) assess the recently added parcel, which included further assessment of soil, groundwater, soil gas, and sub-slab vapor. The assessment activities included the collection of five (5) soil samples from eight (8) soil borings, the collection of five (5) groundwater samples, the collection of one (1) soil gas sample, and the collection of eight (8) sub-slab vapor samples. The work was conducted in accordance with the DEQ-approved work plan. A summary of the soil, groundwater, and vapor assessment results is provided below.  Acetone and methylene chloride, common laboratory contaminants, were detected above laboratory detection limits in soil samples from SB-2, SB-3, and SB-4, and SB-4, respectively. However, the detections were below Protection of Groundwater, Residential, and Industrial/Commercial PSRGs.  Selenium was detected in the soil samples collected from SB-3 and SB-4 at concentrations of 2.3 mg/kg and 3.3 mg/kg, respectively, above the Protection of Groundwater PSRG of 2.1 mg/kg, and the regional background concentration of 0.42 mg/kg. In addition, arsenic was detected in each soil sample above the Residential PSRG. However, the concentrations detected were within the range of naturally occurring background concentrations (Dagun and Chekiri, 2005).  Vinyl chloride was detected in TW-4 (32 µg/L) and TW-5 (2.2 µg/L) above the 2L Standard and residential vapor intrusion GWSL. In addition, 1,4-dioxane was detected at estimated concentrations (J -value) of 25 J µg/L and 19 J µg/L, respectively, above the 2L Standard of 0.7 µg/L. 19 S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\BF Assessment Report\Report\Brownfields Assessment Report - Selles Bagwell Brownfields Property.docx  Other VOC constituents and metal constituents were detected above laboratory detection limits however were detected below 2L Standards and GWSLs.  None of the soil samples or groundwater samples had detections of SVOCs above laboratory detection limits.  Benzene was detected in the soil gas sample, SG-1 (52 µg/m3) above the DWM Residential Sub-Slab and Exterior Soil Gas Screening Level of 12 µg/m3. In addition, TCE was detected in soil gas point SG-1 at a concentration of 1,400 µg/m3, which is above the DWM Residential and Non-Residential Sub-Slab and Exterior Soil Gas Screening Levels of 14 µg/m3 and 180 µg/m3.  The calculated LICR under a residential land use associated with groundwater sample TW-4 (2.2 x 10 -4) was above the acceptable risk range of 1 x10-4 to 1 x 10-6.  The calculated HI exceeds the acceptable level of 1 for SG-1 (20 and 1.6, respectively) under both a residential and non-residential exposure scenario. Tables Table 1Summary of Soil Analytical ResultsSelles Bagwell Brownfields PropertyBrownfields Project ID: 24008-20-060S. Tryon St and Distribution St.Charlotte, North CarolinaH&H Job No. PRO-0112301 S. Tryon St.Former Kelly & McArdleFormer UST Former Coal PileFormer Subgrade LiftAdjacent to a Loading DockSample IDSB-1 Dup SB-2 SB-3 SB-4 SB-5Date Collected12/23/2020 12/23/2020 12/23/2020 12/23/2020 12/23/2020 12/23/2020Sample TypeGrab Grab GrabGrab/Composite3Grab GrabDepth (ft)0.5-1.5 0.5-1.5 10-12 1-2 10-12 0.5-1.5VOCs (8260B/5035A)Acetone<0.0011 <0.00100.031 0.0011 0.035<0.001725 12,000 140,000-- --Methylene Chloride<0.00068 <0.00066 <0.0010 <0.000690.0075<0.00110.025 58 650-- --SVOCs (8270E)BRL BRL BRLBRL BRL BRL-- -- -- -- --RCRA Metals (6020B/7471B/7196A)Arsenic 1.4<0.111.2 11 1.7 1.75.8 0.68 3 1.0-18 4.8Barium 21 31 45 170 160 50580 3,100 47,000 50-1,000 356Cadmium<0.048 <0.048 <0.046 <0.046 <0.045 <0.0493 7.5 110 1.0-10 4.3Hexavalent Chromium<0.20 <0.190.67 1.7<0.18 <0.203.8 0.31 6.5 7.0-300 65Trivalent Chromium 262222.33 51.3140 57 360,000 23,000 350,000 NE NEChromium (Total)26 22 23 53 140 57NE NE NE NE NELead 11 11 7.1 78 10 13270 400 800 ND-50 16Mercury<0.020 <0.019 <0.019 <0.018 <0.018 <0.0201 2.3 9.7 0.03-0.52 0.121Selenium 1.4 1.3<0.282.3 3.31.72.1 78 1,200 <0.1-0.8 0.42Silver<0.0660.94<0.063 <0.063 <0.062 <0.0683.4 78 1,200 ND-5.0 NENotes:Units are milligram/kilogram (mg/kg)1) NC Department of Environmental Quality (DEQ) Preliminary Soil Remediation Goals (PSRG) dated January 20213) SB-3 is a composite of four soil borings (SB-3A through SB-3D) collected from a depth of 1-2 ft. VOCs were collected as a grab sample from sample SB-3C from a depth of 1-2 ft.Method number follows parameter in parenthesisOnly constituents detected in at least SB = Soil BoringDup = Duplicate; Dup collected from SB-1 soil boringVOCs = volatile organic compounds; SVOCs = semi volatile organic compounds; RCRA = Resource Conservation and Recovery Act BRL = Below Report Limits; NE = Not Established; '-- = Not ApplicableJ = estimated value between the laboratory detection limit and the laboratory reporting limitCCVH = CCV result is above control limits but within method parameters. Result is considered estimated.< = below laboratory method detection limitDiesel ASTSample Location2321 S. Tryon St. 2322/2324 Distribution St. 2) Range and mean values of background metals for North Carolina soils taken from Elements in North American Soils by Drugan and Chekiri, 2005.DEQ Brownfields Screening Levels1Interstate Electric Charlotte GrillRegional Background Metals in Soil2MeanResidential PSRGsProtection of Groundwater PSRGsIndustrial/ Commercial PSRGsRangeS:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\Tables\PRO_011 Tables4/5/2021Table 1Hart & Hickman, PC Table 2Summary of Temporary Well ConstructionSelles Bagwell Brownfields PropertyBrownfields Project ID: 24008-20-060S. Tryon St and Distribution St.Charlotte, North CarolinaH&H Job No. PRO-011Well IDDate InstalledScreened ZoneTOC Elevation (ft)Total Depth (ft below TOC)Screen Length (ft)Static Depth to Groundwater (ft below TOC)Groundwater Elevation (ft below TOC)TMW-1 11/22/2019SoilNM 20 5-20 8.6 NMTMW-2 11/22/2019SoilNM 24 4-24 8.48 NMTW-3 12/23/2020Soil 98.9915 5-155.49 87.75TW-4 1/4/2021Soil 93.7217 7-176.37 87.35TW-5 1/4/2021Soil 96.3114 4-145.69 90.62TW-6 12/23/2020Soil 105.1314 9-1410.58 94.55TW-7 12/23/2020Soil 96.0714 4-145.33 90.74Notes:TW = temporary monitoring well; TOC = top of casing; ft = feet; NM = Not MeasuredElevations are approximate and are referenced to an arbitrary datum of 100 ft using a permanent landmark as a reference pointDepth to groundwater measurements from temporary monitoring wells TMW-1 and TMW-2 were collected on November 22, 2019 and groundwater measurements from temporary monitoring wells TW-3 through TW-7 were collected on January 21, 2021.S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\Tables\PRO_011 Tables4/5/2021Table 2 (Page 1 of 1) Hart & Hickman, PC Table 3Summary of Groundwater Analytical ResultsSelles Bagwell Brownfields PropertyBrownfields Project ID: 24008-20-060S. Tryon St and Distribution St.Charlotte, North CarolinaH&H Job No. PRO-0112322/2324 Distribution St.Charlotte GrillEastern Portion of the SiteNortheastern Portion of the SiteFormer UST BasinSouthern Portion of the SiteDiesel ASTDowngradient - Southeastern Portion of the SiteSample IDTMW-1 TMW-2 TW-3 TW-4 TW-5 TW-6 DUP-2 TW-7Date11/22/2019 11/22/2019 1/6/2021 1/6/2021 1/6/2021 1/6/2021 1/6/2021 1/6/2021VOCs (8260B) µg/LAcetone<6.2 <6.22.1 J 4.1 J 1.3 J 1.4 J 1.2 J 2.4 J 4.1 J 6,000 4,500,000 19,000,000Chloroethane<0.49 <0.49 <0.222.1<0.22 <0.22 <0.22 <0.222.1 3,000 4,600 19,0001,1-Dichloroethane<0.27 <0.27 <0.0832.3 2.0<0.083 <0.083 <0.0832.3 6 7.6 331,2-Dichloroethane<0.34 <0.34 <0.066 <0.066 <0.066 <0.0660.25 J <0.0660.25 J 0.4 2.2 9.81,1-Dichloroethylene<0.24 <0.24 <0.0830.87 3.6<0.083 <0.083 <0.0833.6 350 39 160cis-1,2-Dichloroethylene1.6<0.29 <0.0560.78 0.98<0.056 <0.056 <0.0561.6 70 NE NE1,4-DioxaneNA NA <1425 J 19 J<14 <14 <1425 J3 2,900 12,000Hexachloro-1,3-butadiene0.62 J<0.44 NA NA NA NA NA NA NA-- -- --Methyl-tert-butyl ether (MTBE)0.35 J<0.28 <0.042 <0.042 <0.042 <0.042 <0.0420.30 J 0.30 J 20 450 2,000Tetrachloroethylene0.80 J<0.16 <0.098 <0.098 <0.098 <0.0980.28 J<0.0980.80 J0.7 12 48Toluene<0.24 <0.24 <0.0440.24 J<0.044 <0.044 <0.044 <0.0440.24 J 600 3,800 16,000Trichloroethylene97.1<0.22 <0.0782.3<0.078 <0.078 <0.078 <0.07897.13 1 4.4Vinyl chloride<0.24 <0.24 <0.09732 2.2<0.097 <0.097 <0.097320.3 0.15 2.5SVOCs (8270E) µg/Lbis(2-Ethylhexyl)phthalate<2.12.4 J<3.9 <3.9 <3.9 <3.9 <3.7 <3.9 NA-- -- --RCRA Metals (6020B/7470A) µg/LArsenicNA NA0.84 J 0.58 J 0.55 J 0.34 J 0.31 J 4.8 JFiltered ArsenicNA NANA0.25 JNA NA NA4.0BariumNA NA100 130 160 58 59 130Filtered BariumNA NANA130NA NA NA120CadmiumNA NA<0.16 <0.16 <0.16 <0.16 <0.16 <0.16Filtered CadmiumNA NANA <0.16 NA NA NA <0.16ChromiumNA NA2.4 7.2 2.0 1.4 J 0.94 J 4.1Filtered ChromiumNA NANA<0.79NA NA NA1.1 JLeadNA NA1.4 4.2 0.67 J<0.26 <0.266.9Filtered LeadNA NANA1.7NA NA NA <0.26MercuryNA NA0.034 J<0.034 <0.034 <0.0340.038 J<0.034Filtered MercuryNA NANA <0.034 NA NA NA <0.034SeleniumNA NA<0.74 <0.74 <0.740.83 J 1.1 J<0.74Filtered SeleniumNA NANA <0.74 NA NA NA <0.74SilverNA NA<0.11 <0.11 <0.11 <0.11 <0.11 <0.11Filtered SilverNA NANA <0.11 NA NA NA <0.11Cumulative Risks - ResidentCarcinogenic RiskNC NC NC NC NC NC NC NC 3.0E-04-- -- --Non-Carcinogenic Hazard IndexNC NC NC NC NC NC NC NC 1.9E+01 -- -- --Cumulative Risks - Non-Resident WorkerCarcinogenic RiskNC NC NC NC NC NC NC NC 2.6E-05 -- -- --Non-Carcinogenic Hazard IndexNC NC NC NC NC NC NC NC 4.6E+00 -- -- --Notes:1) North Carolina 15A NCAC 02L Groundwater Standards (NC 2L Standards) dated April 20132) North Carolina Residential Vapor Intrusion Groundwater Screening Levels (GWSL) dated February 2018.Bold values exceed NC 2L Standardsitalicized values exceed NC Residential Vapor Intrusion GWSLsyellow highlighted values exceed NC Non-Residential Vapor Intrusion GWSLsunderlined values exceed acceptable Carcinogenic Riskgreen highlighted values exceed acceptable Non-Carcinogenic Hazard Index Method detection limits are shown above for non-detectionsGroundwater samples collected in November 2019 were analyzed by Pace Analytical Services, LLC of Huntersville, NC. Groundwater samples collected in January 2021 were analyzed by Waypoint Analytical of Charlotte, NC.Constituents detected in at least one sample are shown above; refer to the laboratory report Method number follows parameter in parenthesisµg/L = micrograms/literVOCs = volatile organic compounds; SVOCs = semi volatile organic compounds; RCRA = Resource Conservation and Recovery ActTW= temporary monitoring wellJ = estimated concentrations above the adjusted method detection limit and below the adjusted reporting limitBRL = Below Reporting Limits; '-- = not applicable; NE = Not Established; NC = Not Calculated NENENENENENENENENENENENENENE2010154.8 J160--7.26.91.1 J--0.038 J700212010 NENC Non-Residential Vapor Intrusion GWSLNC Residential Vapor Intrusion GWSL Sample Location2321 S. Tryon St.Upgradient - Northern Portion of the Site2301 S. Tryon St. Worst-Case Scenario2300 Distribution St.NC 2L StandardsNEWorld of Stone Interstate Electric Former Kelly & McArdleS:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\Tables\PRO_011 Tables4/5/2021Table 3Hart & Hickman, PC Table 4Summary of Vapor Analytical Results and Risk CalculationsSelles Bagwell Brownfields PropertyBrownfields Project ID: 24008-20-060S. Tryon St and Distribution St.Charlotte, North CarolinaH&H Job No. PRO-0112311 S. Tryon St. 2321 S. Tryon St. 2405 S. Tryon St. 2301 S. Tryon St. Best Tile Interstate Electric Vacant Warehouse Former Kelly & McArdleSample IDSG-1DUP-3SS-3 SS-4 SS-5 SS-6 SS-7 SS-8Date1/4/2021 1/4/2021 11/22/2019 1/4/202111/22/20191/4/2021 1/4/2021 1/4/2021 1/4/2021 1/4/2021 1/4/2021 1/4/2021Acetone 9.2 7.362299.224 6.0 7.2 53 16 7.0 9.5220,000 2,700,000Benzene52 522.4<0.16<0.62<0.16 <0.16 <0.16 <0.16 <0.16 <0.16 <0.1612 160Methyl Ethyl Ketone (2-Butanone) 3.1 2.8 J5.6 J1.52.7 J1.7 1.0 J 0.74 J 4.7 1.5 0.83 J 0.94 J35,000 440,000Carbon disulfide 880 830<0.461.8 J2.33.1 J 2.6 J 2.7 J 3.5 J 3.1 J 2.2 J 1.9 J4,900 61,000Chloroethane 7.5 7.8<0.55<0.38<0.49<0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.3870,000 880,000Chloroform<0.52 <0.52<0.411.5 J0.45 J1.6 J<0.26 <0.26 <0.26 <0.26 <0.26 <0.264.1 53Cyclohexane 21 22<0.74<0.87<0.67<0.87 <0.872.3 J 4.2<0.876.4 2.5 J42,000 530,000Dichlorodifluoromethane 2.9 J 2.9 J1.6 J3.12.13.3 3.7 3.3 5.6 3.2 3.1 3.1700 8,8001,1-Dichloroethane 2.4 J 2.3 J<0.47<0.47<0.43<0.47 <0.47 <0.47 <0.47 <0.47 <0.47 <0.4758 7701,1-Dichloroethylene 81 80<0.58<0.41<0.52<0.41 <0.41 <0.41 <0.41 <0.41 <0.41 <0.411,400 18,000cis-1,2-Dichloroethylene 42 42<0.46<0.52<0.42<0.52 <0.52 <0.52 <0.52 <0.52 <0.52 <0.52NE NEtrans-1,2-Dichloroethylene 81 81<0.60<0.48<0.54<0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48NE NEEthylbenzene 5.0 5.10.82 J<0.19<0.58<0.195.1<0.191.5 J 1.5<0.19 <0.1937 4904-Ethyltolunene<0.26 <0.262.8 J<0.26<1.1<0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26Heptane 26 27<0.80 <0.19 <0.72 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.192,800 35,000Hexane 37 361.5 J<0.250.85 J<0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.254,900 61,000Isopropyl alcohol<0.334.0 J<0.293.5 J<0.274.2 J 5.7 5.4 12 4.2 J 8.9 7.71,400 18,000Methylene Chloride 4.3 2.6 J14.31.910.62.1 2.2<0.396.7 2.2 5.9 6.93,400 53,000Methyl Isobutyl Ketone<0.51 <0.51 <1.1 <0.26 <0.98 <0.26 <0.26 <0.265.8<0.264.6 4.621,000 260,000Styrene<0.30 <0.306.85.10.67 J<0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.157,000 88,000Tetrachloroethylene (PCE) 14 141.4 J<0.44<0.60<0.44 <0.44 <0.44 <0.44 <0.444.9 3.1 J280 3,500Toluene 90 881.4 J<0.75<0.67<0.75 <0.75 <0.752.3 1.4 J 0.87 J 2.335,000 440,0001,1,1-Trichloroethane<0.58 <0.58 <0.65 <0.29 <0.59 <0.2913 3.7<0.29 <0.29 <0.29 <0.2935,000 440,000Trichloroethylene (TCE)1,4001,300<0.53<0.27<0.48<0.27 <0.27 <0.27 <0.27 <0.278.7 4.114 180Trichlorofluoromethane<0.87 <0.876.6<0.430.96 J<0.432.0 J<0.432.2 J 2.0 J 1.9 J 1.2 JNE NE1,2,4-Trimethylbenzene 11 1115<2.51.1 J<2.5 <2.5 <2.55.5<2.5 <2.5 <2.5420 5,3001,3,5-Trimethylbenzene<0.26 <0.266.1<0.26<0.76<0.26 <0.26 <0.26 <0.26 <0.26 <0.26 <0.26Vinyl chloride 4.4 4.4<0.26<0.29<0.24<0.29 <0.29 <0.29 <0.29 <0.29 <0.29 <0.295.6 280m,p-Xylenes 15 152.2J<0.38<1.3<0.3840<0.385.1 J 1.8 J<0.38 <0.38700 8,800o-Xylene 4.3 4.61.1 J<0.18<0.65<0.1815<0.181.9 J<0.18 <0.18 <0.18700 8,800Xylenes (Total) 19.3 19.6 3.3 J<0.38<1.3<0.3855<0.387 J 1.8 J<0.38 <0.38700 8,800Cumulative Risks - ResidentCarcinogenic Risk 2.3E-07 3.7E-07 1.1E-07 3.9E-07 1.4E-07 0.0E+00 4.2E-08 4.1E-08 5.6E-07 2.7E-07 -- --Non-Carcinogenic Hazard Index 1.3E-02 2.2E-03 1.9E-03 2.3E-03 1.8E-02 1.9E-03 8.7E-03 2.4E-03 1.3E-01 6.4E-02 -- --Cumulative Risks - Non-Resident WorkerCarcinogenic Risk 1.7E-08 2.8E-08 8.5E-09 3.0E-08 1.0E-08 0.0E+00 3.1E-09 3.1E-09 3.0E-08 1.4E-08 -- --Non-Carcinogenic Hazard Index 1.0E-03 1.7E-04 1.5E-04 1.8E-04 1.4E-03 1.5E-04 6.9E-04 1.9E-04 1.0E-02 5.1E-03 -- --Notes:2) DEQ DWM Non-Residential Sub-slab and Exterior SGSLs dated January 2021.Concentrations are reported in micrograms per cubic meter (µg/m3).Only compounds detected in at least one sample shown above.Bold values exceed Residential SGSLs Underlined values exceed Non-Residential SGSLs or acceptable risksNE = Not Established; -- = Not ApplicableTarget Lifetime Incremental Cancer Risk (LICR) = 1x10-4Target Hazard Index (HI) = 11.6E+005.0E-062.0E+019.3E-05<0.26 = less than laboratory method detection limits1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Sub-slab and Exterior Soil Gas Screening Levels (SGSLs) dated January 2021.J = Compound detected above laboratory method detection limit, but below laboratory reporting limit; and therefore reported value is an estimated value.World of Stone Sample Location2300 Distribution St.Residential Vapor Intrusion Screening LevelsNon-Residential Vapor Intrusion Screening Levels2322/2324 Distribution St.SS-1 SS-2Charlotte Grill CompanyS:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment\Tables\PRO_011 Tables4/5/2021Table 5Hart & Hickman, PC Figures USGS The National Map: National Boundaries Dataset, 3DEP ElevationProgram, Geographic Names Information System, National HydrographyDataset, National Land Cover Database, National Structures Dataset,and National Transportation Dataset; USGS Global Ecosystems; U.S.Census Bureau TIGER/Line data; USFS Road Data; Natural Earth Data;U.S. Department of State Humanitarian Information Unit; and NOAANational Centers for Environmental Information, U.S. Coastal ReliefModel. Data refreshed May, 2020. SITE LOCATION MAP SELLES BAGWELL BROWNFIELDS PROPERTYSOUTH TRYON STREET AND DISTRIBUTION STREETCHARLOTTE, NORTH CAROLINA DATE: 12-28-20 JOB NO: PRO-011 REVISION NO: 0 FIGURE. 1 2923 South Tryon Street - Suite 100Charlotte, North Carolina 28203704-586-0007 (p) 704-586-0373 (f)License # C-1269 / # C-245 Geology TITLE PROJECT 0 2,000 4,000 SCALE IN FEET Path: \\HHFS01\Redirectedfolders\sperry\My Documents\ArcGIS\PROJECTS\PRO-011\Figure 1.mxdN U.S.G.S. QUADRANGLE MAP CHARLOTTE EAST, NORTH CAROLINA 2013 QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) SITE REVISION NO. 0 JOB NO. PRO-011 DATE: 1-5-21 FIGURE NO. 2 SELLES BAGWELL BROWNFIELDS PROPERTY S. TRYON STREET & DISTRIBUTION STREET CHARLOTTE, NORTH CAROLINA SITE MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY CHAIN-LINK FENCING PAD-MOUNTED TRANSFORMER POLE-MOUNTED TRANSFORMER DUMPSTER WASTEWATER RECYCLING SYSTEM WASTE OIL 55-GALLON DRUMS FORMER SUBGRADE LIFT ABOVEGROUND GASOLINE TANK AREA OF FORMER GASOLINE STORAGE TANK FUEL PUMP SEWER LIFT STATION 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology HUB SOUTH END APARTMENTS (2115-2205 DUNAVANT ST.) D UN A V A N T S T R E E T VACANT INDUSTRIAL BUILDING (2301 DISTRIBUTION ST.) CHARLOTTE GRILL CO. (2324 DISTRIBUTION ST.) INTERSTATE ELECTRIC COMPANY (2321 S. TRYON ST.) BEST TILE CHARLOTTE (2311 S. TRYON ST.) KELLY MCARDLE CONSTRUCTION (2301 S. TRYON ST.)DISTRIBUTION STREETS. TRYON STREETWARE HOUSE OFFICES LOBBYLO A D I N G AR E A LO A D I N G LO A D I N G VACANT LIGHT INDUSTRIAL BUILDING (2405-2411 S. TRYON ST.) PET WANT: THE URBAN FEED (2324 B DISTRIBUTION ST.) GRIER INTERIORS (2326 DISTRIBUTION ST.) AAMCO TRANSMISSION & TOTAL CAR CARE (2413 S. TRYON ST.) O F F I C E S ST O R A G E / W A R E H O U S E RESIDENTIAL RESIDENTIAL B R O O K H I L L R O A D FORMER LOCATION OF STOCKPILED SOIL CONTAINMENT NOTES: 1.BASE DATA AND AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS, 2020. ADDITIONAL PARCEL WORLD STONE FABRICATORS INC (2300 DISTRIBUTION ST.)S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment Activtities\Figures\Site Map.dwg, Fig 2, 1/5/2021 12:34:32 PM, sperry REVISION NO. 0 JOB NO. PRO-011 DATE: 12-29-20 FIGURE NO. 3 SELLES BAGWELL BROWNFIELDS PROPERTY S. TRYON STREET & DISTRIBUTION STREET CHARLOTTE, NORTH CAROLINA SAMPLE LOCATION MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY CHAIN-LINK FENCING PAD-MOUNTED TRANSFORMER POLE-MOUNTED TRANSFORMER DUMPSTER WASTEWATER RECYCLING SYSTEM WASTE OIL 55-GALLON DRUMS FORMER SUBGRADE LIFT ABOVEGROUND GASOLINE TANK AREA OF FORMER GASOLINE STORAGE TANK FUEL PUMP SEWER LIFT STATION SOIL SAMPLE LOCATION TEMPORARY MONITORING WELL LOCATION PHASE II ESA TEMPORARY MONITORING WELL INSTALLED AND SAMPLED IN NOVEMBER 2019 CO-LOCATED SOIL BORING AND TEMPORARY MONITORING WELL LOCATION SOIL GAS SAMPLE LOCATION SUB-SLAB VAPOR POINT LOCATION HUB SOUTH END APARTMENTS (2115-2205 DUNAVANT ST.) D UN A V A N T S T R E E T VACANT INDUSTRIAL BUILDING (2301 DISTRIBUTION ST.) CHARLOTTE GRILL CO. (2324 DISTRIBUTION ST.) INTERSTATE ELECTRIC COMPANY (2321 S. TRYON ST.) BEST TILE CHARLOTTE (2311 S. TRYON ST.) KELLY MCARDLE CONSTRUCTION (2301 S. TRYON ST.)DISTRIBUTION STREETS. TRYON STREETWARE HOUSE OFFICES LOBBYLO A D I N G AR E A LO A D I N G LO A D I N G 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology RESIDENTIAL RESIDENTIAL ST O R A G E / W A R E H O U S E O F F I C E S AAMCO TRANSMISSION & TOTAL CAR CARE (2413 S. TRYON ST.) GRIER INTERIORS (2326 DISTRIBUTION ST.) PET WANT: THE URBAN FEED (2324 B DISTRIBUTION ST.) VACANT LIGHT INDUSTRIAL BUILDING (2405-2411 S. TRYON ST.) B R O O K H I L L R O A D FORMER LOCATION OF STOCKPILED SOIL CONTAINMENT NOTES: 1.BASE DATA AND AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS, 2020. SB-1 SB-3D SB-3A SB-3B SB-3C TW-5 TW-4 SS-8 SS-7 SS-3 SS-4 SB-5 SB-4 SB-2/TW-3 SG-1 SS-2 SS-1 TW-1 TW-2 TW-6 TW-7 SS-6 SS-5 ADDITIONAL PARCEL WORLD STONE FABRICATORS INC (2300 DISTRIBUTION ST.)S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment Activtities\Figures\Site Map.dwg, Fig 3, 1/5/2021 12:35:28 PM, sperry D UN A V A N T S T R E E T CHARLOTTE GRILL CO. (2324 DISTRIBUTION ST.) INTERSTATE ELECTRIC COMPANY (2321 S. TRYON ST.) BEST TILE CHARLOTTE (2311 S. TRYON ST.) KELLY MCARDLE CONSTRUCTION (2301 S. TRYON ST.)DISTRIBUTION STREETS. TRYON STREETWAREHOUSE OFFICES LOBBYLO A D I N G AR E A LO A D I N G TW-5 TW-4 SB-2/TW-3 TW-1 TW-2 TW-6 TW-7 LO A D I N G ST O R A G E / W A R E H O U S E O F F I C E S PET WANT: THE URBAN FEED (2324 B DISTRIBUTION ST.) VACANT LIGHT INDUSTRIAL BUILDING (2405-2411 S. TRYON ST.) B R O O K H I L L R O A D FORMER LOCATION OF STOCKPILED SOIL CONTAINMENT ADDITIONAL PARCEL WORLD STONE FABRICATORS INC (2300 DISTRIBUTION ST.) 94 94 92 ? ? ? ? ????90 88 88 90 (94.55) (90.62) (87.75) (87.35) (90.74) REVISION NO. 0 JOB NO. PRO-011 DATE: 2-10-21 FIGURE NO. 4 SELLES BAGWELL BROWNFIELDS PROPERTY S. TRYON STREET & DISTRIBUTION STREET CHARLOTTE, NORTH CAROLINA GROUNDWATER ELEVATION CONTOUR MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY CHAIN-LINK FENCING TEMPORARY MONITORING WELL LOCATION PHASE II ESA TEMPORARY MONITORING WELL INSTALLED AND SAMPLED IN NOVEMBER 2019 CO-LOCATED SOIL BORING AND TEMPORARY MONITORING WELL LOCATION GROUNDWATER ELEVATION (FT) GROUNDWATER ELEVATION CONTOUR (FT) (DASHED WHERE INFERRED) INFERRED GROUNDWATER FLOW DIRECTION 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology NOTES: 1.BASE DATA AND AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS, 2020. 88 (90.74)S:\AAA-Master Projects\Providence Group Capital (PRO)\PRO-011 S Tryon & Distribution Street - Brownfields\Brownfields Assessment Activtities\Figures\Site Map.dwg, Fig 4, 2/10/2021 3:53:11 PM, SVincent Appendix A Boring Logs and Field Forms NOTES: Hole precleared to 5.0' on 11/22/19. generated using GroundLogs.online Client: Project: Address: Providence Group PRO.006 2300 Distribution Street, Charlotte,NC WELL LOG Well No. Page: TW-1 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 11/22/19 11/22/19 Nate Reel Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 20.0 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: 1.0 0.040 Sch 40 PVC Sch 40 PVC Slotted Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Lean CLAY (CL); mostly clay, medium plasticity, stiff, moist, dark brown (3') Lean CLAY (CL); mostly clay, medium plasticity, stiff, moist, light brown (4') Lean CLAY (CL); mostly clay, medium plasticity, stiff, moist, light brown with dark grey (5') Lean CLAY (CL); mostly clay, medium plasticity, stiff, moist, light brown with grey blue streaks (7') Lean CLAY (CL); mostly clay, medium plasticity, stiff, moist, light grey and tan (8') Lean CLAY (CL); mostly clay, medium plasticity, medium stiff, moist, light brown with dark brown streaks (9') Lean CLAY (CL); mostly clay, medium plasticity, medium stiff, moist, light brown and tan with PWR (12') Poorly graded GRAVEL with sand (GP); some fine-coarse grained gravel, some medium-coarse sand, medium dense, moist, light grey and white PWR (14') SILT with sand (ML); little fine-coarse gravel, little fine-medium sand, mostly silt, nonplastic, soft, moist, light brown (18') Poorly graded GRAVEL with sand (GP); little fine-coarse grained gravel, little fine-medium sand, few silt, medium dense, moist, reddish brown PWR 0.0 0.0 0.0 0.0 0.0 0.1 0.2 0.1 0.0 0.6 0 5 10 15 20 Mid Atlantic DPT Geoprobe Don Warren 4.25 NA NA 8.60 NA NA 20.0 NA (20') Boring terminated NOTES: Hole precleared to 5.0' on 11/22/19. generated using GroundLogs.online Client: Project: Address: Providence Group PRO.006 2300 Distribution Street, Charlotte,NC WELL LOG Well No. Page: TW-2 1 of 2 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 11/22/19 11/22/19 Nate Reel Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 24.0 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: 1.0 0.040 Sch 40 PVC Sch 40 PVC Slotted Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Lean CLAY (CL); mostly clay, medium plasticity, medium stiff, moist, dark reddish (3') SILT (ML); mostly silt, little clay, low plasticity, medium stiff, moist, orangish brown (5') Lean CLAY (CL); little silt, mostly clay, medium plasticity, medium stiff, moist, light orange and tan (8') Lean CLAY (CL); mostly clay, medium plasticity, medium stiff, moist, light brown and tan (14') Lean CLAY (CL); little silt, mostly clay, medium plasticity, medium stiff, moist, brownish orange (17') Lean CLAY (CL); little silt, mostly clay, medium plasticity, medium stiff, moist, orangish brown 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0 5 10 15 20 Mid Atlantic DPT Geoprobe Don Warren 4.25 NA NA 8.48 NA NA 24.0 NA NOTES: Hole precleared to 5.0' on 11/22/19. generated using GroundLogs.online Client: Project: Address: Providence Group PRO.006 2300 Distribution Street, Charlotte,NC WELL LOG Well No. Page: TW-2 2 of 2 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 11/22/19 11/22/19 Nate Reel Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 24.0 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: 1.0 0.040 Sch 40 PVC Sch 40 PVC Slotted Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)20 25 30 35 40 (17') Lean CLAY (CL); little silt, mostly clay, medium plasticity, medium stiff, moist, orangish brown (23') Poorly graded GRAVEL with sand (GP); some fine-coarse grained gravel, little fine-medium sand, few silt, medium dense, wet, light grey and white PWR (24') Boring terminated 0.0 0.0 20 25 30 35 40 Mid Atlantic DPT Geoprobe Don Warren 4.25 NA NA 8.48 NA NA 24.0 NA NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-1 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 5.0 3.25 Grab DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 GR 1.00 (0') Asphalt (0.5') SILT (ML); some silt, some clay, stiff, moist, light reddish-brown (3') SILT (ML); some clay, soft, moist, brown (5') Boring terminated 102.4 37.4 6.7 8.9 5.6 SB-1(0.5-1.5) 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 12/22/2020 by MidSouth using hand auger. generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC WELL LOG Well No. Page: SB-2/TW-3 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Direct Push Geoprobe 54DT Don Warren Ayla Homer Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 15.5 3.25 Direct Push Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Type: 15.5 1.0 0.001 Sch 40 PVC PVC Prepack Bent. Chips Pre-pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 DP 2.00 (0') Sandy SILT (ML); soft, moist, gray (2') No Recovery (6.5') SILT (ML); some clay, soft, wet, pale gray (8') SILT (ML); trace fine-medium sand, trace clay, soft, moist, pale brown (10') SILT (ML); some clay, medium stiff, moist, light reddish-brown (12') Sandy SILT (ML); some clay, soft, saturated, brown (14') Sandy SILT (ML); very stiff, dry, light reddish-brown (15.5') Boring terminated 1.8 1.1 1.7 2.5 2.9 SB-2(10-12) 0 5 10 15 20 NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-3A 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 3.0 3.25 Other DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 OT 1.00 (0') SILT (ML); little fine-medium sand, trace clay, soft, moist, light reddish-brown (3') Boring terminated 2.5 2.2 2.9 SB-3(1-2) 0 5 10 15 20 NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-3B 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 3.0 3.25 Other DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 OT 1.00 (0') SILT (ML); little fine-medium sand, trace clay, soft, moist, light reddish-brown (3') Boring terminated 2.2 1.3 2.5 SB-3(1-2) 0 5 10 15 20 NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-3C 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 3.0 3.25 Other DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 OT 1.00 (0') SILT (ML); little fine-medium sand, trace clay, soft, moist, light reddish-brown (3') Boring terminated 2.8 3.1 3.0 SB-3(1-2) 0 5 10 15 20 NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-3D 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 3.0 3.25 Other DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 OT 1.00 (0') SILT (ML); trace clay, soft, moist, light reddish-brown (0.5') SILT (ML); little fine-medium sand, trace clay, soft, moist, light reddish-brown (3') Boring terminated 1.7 2.7 2.6 SB-3(1-2) 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 12/22/2020 by MidSouth using hand auger. generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-4 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Direct Push Geoprobe 45DT Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 12.0 3.25 Direct Push DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 DP 2.00 (0') Concrete (0.5') SILT (ML); trace fine-medium sand, stiff, moist, reddish-brown (6') SILT (ML); trace fine-medium sand, stiff, moist, gray (7') SILT (ML); trace fine-medium sand, medium stiff, moist, brown (10') SILT (ML); trace fine-medium sand, some clay, stiff, moist, gray (11') Well-graded SAND with silt (SW-SM); medium dense, moist, gray (12') Boring terminated 3.9 3.4 3.7 3.8 3.6 3.1 2.6 2.2 1.3 SB-4(10-12) 0 5 10 15 20 NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC BORING LOG Boring No. Page: SB-5 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Ground Surface Elev. (ft): Location (X,Y): 6.0 3.25 Grab DEPTH (ft)LITHOLOGYWATER LEVELBORINGCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 GR 1.00 (0') SILT (ML); trace fine-medium sand, some clay, soft, moist, reddish-brown (4') SILT (ML); some clay, soft, moist, gray (6') Boring terminated 4.0 2.8 3.2 3.8 3.6 2.3 SB-5(0.5-1.5) 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 12/22/2020 by MidSouth using hand auger. generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC WELL LOG Well No. Page: TW-4 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Direct Push Geoprobe 54DT Don Warren Ayla Homer Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 17.0 3.25 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Type: 17.0 1.0 0.001 Sch 40 PVC PVC Prepack Bent. Chips Pre-pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Asphalt (1') SILT (ML); trace fine sand, medium stiff, moist, reddish-brown (2') SILT (ML); trace fine-medium sand, trace clay, medium stiff, moist, reddish-brown (4') Sandy SILT (ML); soft, moist, pale brown (7') SILT (ML); some clay, stiff, moist, reddish-brown (8') SILT (ML); some clay, soft, moist, dark gray (10') Sandy SILT (ML); soft, saturated, gray (12') Sandy SILT (ML); soft, saturated, gray (13') SILT (ML); some fine-medium sand, stiff, dry, dark gray (15') SILT (ML); some fine-medium sand, stiff, dry, light reddish-brown (15.5') Sandy SILT (ML); soft, saturated, light reddish-brown (16.5') Sandy SILT (ML); soft, dry, light reddish-brown (17') Boring terminated 0.1 0.3 0.7 1.5 1.6 1.5 1.0 1.0 1.2 0 5 10 15 20 NOTES: Hole precleared to 5' on 12/22/2020 by MidSouth using hand auger. generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC WELL LOG Well No. Page: TW-5 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Direct Push Geoprobe 54DT Don Warren Ayla Homer Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 13.5 3.25 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Type: 13.5 1.0 0.001 Sch 40 PVC PVC Prepack Bent. Chips Pre-pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Asphalt (0.5') SILT (ML); some clay, medium stiff, dry, light reddish-brown (6') SILT (ML); trace fine sand, some clay, soft, moist, light reddish-brown (8') Sandy SILT (ML); trace clay, soft, moist, gray (9.5') Silty SAND (SM); trace clay, loose, moist, gray (11.5') Silty SAND (SM); trace clay, loose, saturated, gray (13.5') Boring terminated 3.7 2.6 4.9 4.7 4.4 4.2 3.3 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 12/22/2020 by MidSouth using hand auger. generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC WELL LOG Well No. Page: TW-6 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Direct Push Geoprobe 54DT Don Warren Ayla Homer Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 15.5 3.25 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Type: 15.0 1.0 0.001 Sch 40 PVC Sch 40 PVC Slotted Bent. Chips Pre-Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') Concrete (0.5') Well-graded GRAVEL (GW); gray (1') SILT with sand (ML); trace coarse gravel, medium stiff, dry, dark brown (2') SILT (ML); medium stiff, dry, light brown (4.5') SILT (ML); very stiff, dry, gray (6.5') SILT (ML); very stiff, dry, pale gray (7.5') Sandy SILT (ML); very stiff, dry, pale gray (10') SILT (ML); soft, dry, light reddish-brown (12') SILT (ML); trace clay, medium stiff, dry, gray (14') SILT (ML); trace clay, medium stiff, moist, light reddish-brown (15.5') Boring terminated 0.3 1.4 0.3 1.4 1.7 1.0 1.2 1.3 0 5 10 15 20 NOTES: Hole precleared to 5.0' on 12/22/2020 by MidSouth using hand auger. generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC WELL LOG Well No. Page: TW-7 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Direct Push Geoprobe 54DT Don Warren Ayla Homer Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 16.0 3.25 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Type: 16.0 1.0 0.001 Sch 40 PVC PVC Prepack Bent. Chips Pre-pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') SILT (ML); some clay, stiff, dry, reddish-brown (2.5') SILT (ML); some clay, stiff, dry, yellowish-brown (4') SILT with sand (ML); soft, dry, dark gray (6') Lean CLAY (CL); some silt, medium plasticity, soft, saturated, brown (9.5') Sandy SILT (ML); soft, saturated, gray (12') Sandy SILT (ML); soft, saturated, brown (13') Sandy SILT (ML); soft, saturated, gray (14') Sandy SILT (ML); stiff, moist, gray (15.5') SILT (ML); some clay, very stiff, dry, light reddish-brown (16') Boring terminated 2.5 2.8 3.0 3.8 3.7 3.1 3.3 3.3 0 5 10 15 20 NOTES: generated using GroundLogs.online Client: Project: Address: Providence Group PRO-011 2301 South Tryon Street, Charlotte,NC WELL LOG Well No. Page: SG-1 1 of 1 Drilling Start Date: Drilling End Date: Drilling Company: Drilling Method: Drilling Equipment: Driller: Logged By: 12/22/2020 12/22/2020 MidSouth Other Hand Auger Don Warren Kyle McGuire Boring Depth (ft): Boring Diameter (in): Sampling Method(s): DTW During Drilling (ft): DTW After Drilling (ft): Top of Casing Elev. (ft): Location (X,Y): 5.0 3.25 Well Depth (ft): Well Diameter (in): Screen Slot (in): Riser Material: Screen Material: Seal Material(s): Filter Pack: 5.0 Other Bent. Chips Sand Pack DEPTH (ft)LITHOLOGYWATER LEVELWELLCOMPLETIONCOLLECT Sample TypeTimeBlow CountsRecovery (ft)SOIL/ROCK VISUAL DESCRIPTION MEASURE PID (ppm)Lab SampleDEPTH (ft)0 5 10 15 20 (0') SILT with sand (ML); soft, dry, yellowish-brown (4') SILT with sand (ML); soft, dry, gray (5') Boring terminated 0 5 10 15 20 Appendix B Laboratory Reports This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Case Narrative 1/15/21 13:29 Hart & Hickman (Charlotte) Matt Ingalls 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PRO-011 Lab Submittal Date: 01/06/2021 Work Order: 1010111 Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL Senior Project Manager Angela D. Overcash Data Qualifiers Key Reference: D RPD value outside of the control limits. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L Parameter reported with possible low bias. LCS recovery below the QC limit. M Matrix spike outside of the control limits. SR Surrogate recovery outside of the QC limits. Method Detection LimitMDL Below Reporting LimitBRL Relative Percent DifferenceRPD *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 45 Sample Receipt Summary 01/15/2021 Work Order: 1010111 Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received 1010111-01 01/05/21 10:00TW-4 01/06/21 11:52Water 1010111-02 01/05/21 8:00TW-5 01/06/21 11:52Water 1010111-03 01/04/21 10:35TW-6 01/06/21 11:52Water 1010111-04 01/05/21 11:00TW-7 01/06/21 11:52Water 1010111-05 01/04/21 9:30TW-3 01/06/21 11:52Water 1010111-06 01/04/21 0:00DUP-2 01/06/21 11:52Water 1010111-07 01/05/21 10:00TW-4 (Filtered)01/06/21 11:52Water 1010111-08 01/05/21 11:00TW-7 (Filtered)01/06/21 11:52Water Samples were received in good condition at 4.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 45 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 1010111 01/15/2021 Summary of Detections 0.58 J ug/L1010111-01 TW-4 Arsenic 6020B 130 ug/L1010111-01 TW-4 Barium 6020B 7.2 ug/L1010111-01 TW-4 Chromium 6020B 4.2 ug/L1010111-01 TW-4 Lead 6020B 2.3 ug/L1010111-01 TW-4 1,1-Dichloroethane 8260D 0.87 ug/L1010111-01 TW-4 1,1-Dichloroethylene 8260D 25 J ug/L1010111-01 TW-4 1,4-Dioxane 8260D 4.1 J ug/L1010111-01 TW-4 Acetone 8260D 2.1 ug/L1010111-01 TW-4 Chloroethane 8260D 0.78 ug/L1010111-01 TW-4 cis-1,2-Dichloroethylene 8260D 0.24 J ug/L1010111-01 TW-4 Toluene 8260D 2.3 ug/L1010111-01 TW-4 Trichloroethylene 8260D 32 ug/L1010111-01 TW-4 Vinyl chloride 8260D 0.55 J ug/L1010111-02 TW-5 Arsenic 6020B 160 ug/L1010111-02 TW-5 Barium 6020B 2.0 ug/L1010111-02 TW-5 Chromium 6020B 0.67 J ug/L1010111-02 TW-5 Lead 6020B 2.0 ug/L1010111-02 TW-5 1,1-Dichloroethane 8260D 3.6 ug/L1010111-02 TW-5 1,1-Dichloroethylene 8260D 19 J ug/L1010111-02 TW-5 1,4-Dioxane 8260D 1.3 J ug/L1010111-02 TW-5 Acetone 8260D 0.98 ug/L1010111-02 TW-5 cis-1,2-Dichloroethylene 8260D 2.2 ug/L1010111-02 TW-5 Vinyl chloride 8260D 0.34 J ug/L1010111-03 TW-6 Arsenic 6020B 58 ug/L1010111-03 TW-6 Barium 6020B 1.4 J ug/L1010111-03 TW-6 Chromium 6020B 0.83 J ug/L1010111-03 TW-6 Selenium 6020B 1.4 J ug/L1010111-03 TW-6 Acetone 8260D 4.8 ug/L1010111-04 TW-7 Arsenic 6020B 130 ug/L1010111-04 TW-7 Barium 6020B 4.1 ug/L1010111-04 TW-7 Chromium 6020B 6.9 ug/L1010111-04 TW-7 Lead 6020B 2.4 J ug/L1010111-04 TW-7 Acetone 8260D 0.30 J ug/L1010111-04 TW-7 Methyl-tert-Butyl Ether 8260D 0.000034 J mg/L1010111-05 TW-3 Mercury 7470A 0.84 J ug/L1010111-05 TW-3 Arsenic 6020B 100 ug/L1010111-05 TW-3 Barium 6020B 2.4 ug/L1010111-05 TW-3 Chromium 6020B 1.4 ug/L1010111-05 TW-3 Lead 6020B 2.1 J ug/L1010111-05 TW-3 Acetone 8260D 0.000038 J mg/L1010111-06 DUP-2 Mercury 7470A 0.31 J ug/L1010111-06 DUP-2 Arsenic 6020B 59 ug/L1010111-06 DUP-2 Barium 6020B 0.94 J ug/L1010111-06 DUP-2 Chromium 6020B This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 45 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 1010111 01/15/2021 Summary of Detections 1.1 J ug/L1010111-06 DUP-2 Selenium 6020B 0.25 J ug/L1010111-06 DUP-2 1,2-Dichloroethane 8260D 1.2 J ug/L1010111-06 DUP-2 Acetone 8260D 0.28 J ug/L1010111-06 DUP-2 Tetrachloroethylene 8260D 0.25 J ug/L1010111-07 TW-4 (Filtered)Arsenic 6020B 130 ug/L1010111-07 TW-4 (Filtered)Barium 6020B 1.7 ug/L1010111-07 TW-4 (Filtered)Lead 6020B 4.0 ug/L1010111-08 TW-7 (Filtered)Arsenic 6020B 120 ug/L1010111-08 TW-7 (Filtered)Barium 6020B 1.1 J ug/L1010111-08 TW-7 (Filtered)Chromium 6020B This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-4 Sample ID: 1010111-01 Work Order: 1010111 Time Collected: 01/05/21 10:00 Time Submitted: 01/06/21 11:52 Semivolatile Organic Compounds by GC/MS 8270E P1A04971101/8/21 19:20 JMVug/L 0.841,1’-Biphenyl BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.12,3,4,6-Tetrachlorophenol BDL 8270E P1A04971211/8/21 19:20 JMVug/L 3.82,4,5-Trichlorophenol BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.72,4,6-Trichlorophenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.82,4-Dichlorophenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 5.12,4-Dimethylphenol BDL 8270E P1A04971521/8/21 19:20 JMVug/L 122,4-Dinitrophenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.42,4-Dinitrotoluene BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.12,6-Dinitrotoluene BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.92-Chloronaphthalene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.82-Chlorophenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.22-Methylnaphthalene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.52-Methylphenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.22-Nitroaniline BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.72-Nitrophenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.13,3’-Dichlorobenzidine BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.63/4-Methylphenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 3.93-Nitroaniline BDL 8270E P1A04971521/8/21 19:20 JMVug/L 124,6-Dinitro-2-methylphenol BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.64-Bromophenyl phenyl ether BDL 8270E P1A04971101/8/21 19:20 JMVug/L 3.14-Chloro-3-methylphenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 3.64-Chloroaniline BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.94-Chlorophenyl phenyl ether BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.34-Nitroaniline BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.74-Nitrophenol BDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.80AcenaphtheneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 0.62AcenaphthyleneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 3.5AcetophenoneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.49AnthraceneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.2AtrazineBDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.4BenzaldehydeBDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.78Benzo(a)anthracene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.46Benzo(a)pyrene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.91Benzo(b)fluoranthene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.0Benzo(g,h,i)perylene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.85Benzo(k)fluoranthene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.0bis(2-Chloroethoxy)methane BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.7Bis(2-Chloroethyl)ether BDL 8270E P1A04971101/8/21 19:20 JMVug/L 2.9Bis(2-chloroisopropyl)ether BDL 8270E P1A04971101/8/21 19:20 JMVug/L 3.9Bis(2-Ethylhexyl)phthalate BDL 8270E P1A04971101/8/21 19:20 JMVug/L 3.1Butyl benzyl phthalate BDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.6CaprolactamBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-4 Sample ID: 1010111-01 Work Order: 1010111 Time Collected: 01/05/21 10:00 Time Submitted: 01/06/21 11:52 8270E P1A04971211/8/21 19:20 JMVug/L 4.3CarbazoleBDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.0ChryseneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 1.6Dibenzo(a,h)anthracene BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.4DibenzofuranBDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.4Diethyl phthalate BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.2Dimethyl phthalate BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.5Di-n-butyl phthalate BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.7Di-n-octyl phthalate BDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.59FluorantheneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.48FluoreneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.0HexachlorobenzeneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.7HexachlorobutadieneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 7.6HexachlorocyclopentadieneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 3.9HexachloroethaneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.78Indeno(1,2,3-cd)pyrene BDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.3IsophoroneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.3NaphthaleneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 4.0NitrobenzeneBDL 8270E P1A04971211/8/21 19:20 JMVug/L 3.4N-Nitroso-di-n-propylamine BDL 8270E P1A04971211/8/21 19:20 JMVug/L 4.6N-Nitrosodiphenylamine BDL 8270E P1A04971521/8/21 19:20 JMVug/L 11PentachlorophenolBDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.42PhenanthreneBDL 8270E P1A04971101/8/21 19:20 JMVug/L 1.5PhenolBDL 8270E P1A04971101/8/21 19:20 JMVug/L 0.70PyreneBDL Surrogate Recovery Control Limits 43-140107 %2,4,6-Tribromophenol 44-11981 %2-Fluorobiphenyl 19-11941 %2-Fluorophenol 44-12071 %Nitrobenzene-d5 11-5230 %Phenol-d5 50-13486 %Terphenyl-d14 Total Metals 7470A P1A051410.00020 1/8/21 15:04 EDVmg/L 0.000034MercuryBDL 6020B P1A049911.0 1/12/21 15:25 JABJug/L 0.17Arsenic0.58 6020B P1A049912.0 1/12/21 15:25 JABug/L 0.81Barium130 6020B P1A049911.0 1/12/21 15:25 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 15:25 JABug/L 0.79Chromium7.2 6020B P1A049911.0 1/12/21 15:25 JABug/L 0.26Lead4.2 6020B P1A049915.0 1/12/21 15:25 JABug/L 0.74SeleniumBDL 6020B P1A049911.0 1/12/21 15:25 JABug/L 0.11SilverBDL Volatile Organic Compounds by GC/MS 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0611,1,1-Trichloroethane BDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-4 Sample ID: 1010111-01 Work Order: 1010111 Time Collected: 01/05/21 10:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0361,1,2,2-Tetrachloroethane BDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0661,1,2-Trichloroethane BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0831,1-Dichloroethane 2.3 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0831,1-Dichloroethylene 0.87 8260D P1A054012.0 1/8/21 14:01 JLBug/L 0.401,2,3-Trichlorobenzene BDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.131,2,4-Trichlorobenzene BDL 8260D P1A054012.0 1/8/21 14:01 JLBug/L 0.171,2-Dibromo-3-chloropropane BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0511,2-Dibromoethane BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0761,2-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0661,2-Dichloroethane BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.111,2-Dichloropropane BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0541,3-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.0501,4-Dichlorobenzene BDL 8260D P1A054011501/8/21 14:01 JLBJug/L 141,4-Dioxane 25 8260D P1A054015.0 1/8/21 14:01 JLBJug/L 0.31Acetone4.1 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.048BenzeneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.14BromochloromethaneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.062BromodichloromethaneBDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.040BromoformBDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.18BromomethaneBDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 0.075Carbon disulfide BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.11Carbon Tetrachloride BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.062ChlorobenzeneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.22Chloroethane2.1 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.076ChloroformBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.079ChloromethaneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.056cis-1,2-Dichloroethylene 0.78 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.079cis-1,3-Dichloropropylene BDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.95CyclohexaneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.081DibromochloromethaneBDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 0.11DichlorodifluoromethaneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.061EthylbenzeneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.054Isopropylbenzene (Cumene)BDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.12m,p-Xylenes BDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 1.0Methyl Acetate BDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 0.065Methyl Butyl Ketone (2-Hexanone)BDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 0.94MethylcyclohexaneBDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 0.24Methyl Ethyl Ketone (2-Butanone)BDL 8260D P1A054015.0 1/8/21 14:01 JLBug/L 1.0Methyl Isobutyl Ketone BDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.083Methylene Chloride BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.042Methyl-tert-Butyl Ether BDL 8260D P1A054011.0 1/8/21 14:01 JLBug/L 0.30NaphthaleneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-4 Sample ID: 1010111-01 Work Order: 1010111 Time Collected: 01/05/21 10:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.044o-Xylene BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.047StyreneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.098TetrachloroethyleneBDL 8260D P1A054010.50 1/8/21 14:01 JLBJug/L 0.044Toluene0.24 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.094trans-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.070trans-1,3-Dichloropropylene BDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.078Trichloroethylene2.3 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.062TrichlorofluoromethaneBDL 8260D P1A054010.50 1/8/21 14:01 JLBug/L 0.097Vinyl chloride 32 8260D P1A054011.5 1/8/21 14:01 JLBug/L 0.15Xylenes, total BDL Surrogate Recovery Control Limits 80-12497 %4-Bromofluorobenzene 75-129101 %Dibromofluoromethane 77-12396 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-5 Sample ID: 1010111-02 Work Order: 1010111 Time Collected: 01/05/21 08:00 Time Submitted: 01/06/21 11:52 Semivolatile Organic Compounds by GC/MS 8270E P1A04971111/8/21 19:42 JMVug/L 0.851,1’-Biphenyl BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.22,3,4,6-Tetrachlorophenol BDL 8270E P1A04971211/8/21 19:42 JMVug/L 3.82,4,5-Trichlorophenol BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.82,4,6-Trichlorophenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.82,4-Dichlorophenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 5.12,4-Dimethylphenol BDL 8270E P1A04971531/8/21 19:42 JMVug/L 122,4-Dinitrophenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.42,4-Dinitrotoluene BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.12,6-Dinitrotoluene BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.92-Chloronaphthalene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.92-Chlorophenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.32-Methylnaphthalene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.62-Methylphenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.32-Nitroaniline BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.72-Nitrophenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.13,3’-Dichlorobenzidine BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.63/4-Methylphenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.03-Nitroaniline BDL 8270E P1A04971531/8/21 19:42 JMVug/L 124,6-Dinitro-2-methylphenol BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.64-Bromophenyl phenyl ether BDL 8270E P1A04971111/8/21 19:42 JMVug/L 3.14-Chloro-3-methylphenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 3.74-Chloroaniline BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.94-Chlorophenyl phenyl ether BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.44-Nitroaniline BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.74-Nitrophenol BDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.80AcenaphtheneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 0.63AcenaphthyleneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 3.5AcetophenoneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.50AnthraceneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.2AtrazineBDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.5BenzaldehydeBDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.78Benzo(a)anthracene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.47Benzo(a)pyrene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.92Benzo(b)fluoranthene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.0Benzo(g,h,i)perylene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.85Benzo(k)fluoranthene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.0bis(2-Chloroethoxy)methane BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.7Bis(2-Chloroethyl)ether BDL 8270E P1A04971111/8/21 19:42 JMVug/L 2.9Bis(2-chloroisopropyl)ether BDL 8270E P1A04971111/8/21 19:42 JMVug/L 3.9Bis(2-Ethylhexyl)phthalate BDL 8270E P1A04971111/8/21 19:42 JMVug/L 3.1Butyl benzyl phthalate BDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.7CaprolactamBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-5 Sample ID: 1010111-02 Work Order: 1010111 Time Collected: 01/05/21 08:00 Time Submitted: 01/06/21 11:52 8270E P1A04971211/8/21 19:42 JMVug/L 4.3CarbazoleBDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.0ChryseneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 1.6Dibenzo(a,h)anthracene BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.4DibenzofuranBDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.4Diethyl phthalate BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.3Dimethyl phthalate BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.5Di-n-butyl phthalate BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.7Di-n-octyl phthalate BDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.60FluorantheneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.48FluoreneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.1HexachlorobenzeneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.7HexachlorobutadieneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 7.6HexachlorocyclopentadieneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 3.9HexachloroethaneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.79Indeno(1,2,3-cd)pyrene BDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.3IsophoroneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.3NaphthaleneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 4.1NitrobenzeneBDL 8270E P1A04971211/8/21 19:42 JMVug/L 3.4N-Nitroso-di-n-propylamine BDL 8270E P1A04971211/8/21 19:42 JMVug/L 4.7N-Nitrosodiphenylamine BDL 8270E P1A04971531/8/21 19:42 JMVug/L 11PentachlorophenolBDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.43PhenanthreneBDL 8270E P1A04971111/8/21 19:42 JMVug/L 1.5PhenolBDL 8270E P1A04971111/8/21 19:42 JMVug/L 0.71PyreneBDL Surrogate Recovery Control Limits 43-140114 %2,4,6-Tribromophenol 44-11986 %2-Fluorobiphenyl 19-11945 %2-Fluorophenol 44-12076 %Nitrobenzene-d5 11-5232 %Phenol-d5 50-13494 %Terphenyl-d14 Total Metals 7470A P1A051410.00020 1/8/21 15:08 EDVmg/L 0.000034MercuryBDL 6020B P1A049911.0 1/12/21 15:05 JABJug/L 0.17Arsenic0.55 6020B P1A049912.0 1/12/21 15:05 JABug/L 0.81Barium160 6020B P1A049911.0 1/12/21 15:05 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 15:05 JABug/L 0.79Chromium2.0 6020B P1A049911.0 1/12/21 15:05 JABJug/L 0.26Lead0.67 6020B P1A049915.0 1/12/21 15:05 JABug/L 0.74SeleniumBDL 6020B P1A049911.0 1/12/21 15:05 JABug/L 0.11SilverBDL Volatile Organic Compounds by GC/MS 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0611,1,1-Trichloroethane BDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-5 Sample ID: 1010111-02 Work Order: 1010111 Time Collected: 01/05/21 08:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0361,1,2,2-Tetrachloroethane BDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0661,1,2-Trichloroethane BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0831,1-Dichloroethane 2.0 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0831,1-Dichloroethylene 3.6 8260D P1A054012.0 1/8/21 14:25 JLBug/L 0.401,2,3-Trichlorobenzene BDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.131,2,4-Trichlorobenzene BDL 8260D P1A054012.0 1/8/21 14:25 JLBug/L 0.171,2-Dibromo-3-chloropropane BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0511,2-Dibromoethane BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0761,2-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0661,2-Dichloroethane BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.111,2-Dichloropropane BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0541,3-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.0501,4-Dichlorobenzene BDL 8260D P1A054011501/8/21 14:25 JLBJug/L 141,4-Dioxane 19 8260D P1A054015.0 1/8/21 14:25 JLBJug/L 0.31Acetone1.3 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.048BenzeneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.14BromochloromethaneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.062BromodichloromethaneBDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.040BromoformBDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.18BromomethaneBDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 0.075Carbon disulfide BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.11Carbon Tetrachloride BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.062ChlorobenzeneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.22ChloroethaneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.076ChloroformBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.079ChloromethaneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.056cis-1,2-Dichloroethylene 0.98 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.079cis-1,3-Dichloropropylene BDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.95CyclohexaneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.081DibromochloromethaneBDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 0.11DichlorodifluoromethaneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.061EthylbenzeneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.054Isopropylbenzene (Cumene)BDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.12m,p-Xylenes BDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 1.0Methyl Acetate BDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 0.065Methyl Butyl Ketone (2-Hexanone)BDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 0.94MethylcyclohexaneBDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 0.24Methyl Ethyl Ketone (2-Butanone)BDL 8260D P1A054015.0 1/8/21 14:25 JLBug/L 1.0Methyl Isobutyl Ketone BDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.083Methylene Chloride BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.042Methyl-tert-Butyl Ether BDL 8260D P1A054011.0 1/8/21 14:25 JLBug/L 0.30NaphthaleneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-5 Sample ID: 1010111-02 Work Order: 1010111 Time Collected: 01/05/21 08:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.044o-Xylene BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.047StyreneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.098TetrachloroethyleneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.044TolueneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.094trans-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.070trans-1,3-Dichloropropylene BDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.078TrichloroethyleneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.062TrichlorofluoromethaneBDL 8260D P1A054010.50 1/8/21 14:25 JLBug/L 0.097Vinyl chloride 2.2 8260D P1A054011.5 1/8/21 14:25 JLBug/L 0.15Xylenes, total BDL Surrogate Recovery Control Limits 80-12496 %4-Bromofluorobenzene 75-129100 %Dibromofluoromethane 77-12395 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-6 Sample ID: 1010111-03 Work Order: 1010111 Time Collected: 01/04/21 10:35 Time Submitted: 01/06/21 11:52 Semivolatile Organic Compounds by GC/MS 8270E P1A04971111/8/21 20:05 JMVug/L 0.851,1’-Biphenyl BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.22,3,4,6-Tetrachlorophenol BDL 8270E P1A04971211/8/21 20:05 JMVug/L 3.82,4,5-Trichlorophenol BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.82,4,6-Trichlorophenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.82,4-Dichlorophenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 5.12,4-Dimethylphenol BDL 8270E P1A04971531/8/21 20:05 JMVug/L 122,4-Dinitrophenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.42,4-Dinitrotoluene BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.12,6-Dinitrotoluene BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.92-Chloronaphthalene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.92-Chlorophenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.32-Methylnaphthalene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.62-Methylphenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.32-Nitroaniline BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.72-Nitrophenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.13,3’-Dichlorobenzidine BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.63/4-Methylphenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.03-Nitroaniline BDL 8270E P1A04971531/8/21 20:05 JMVug/L 124,6-Dinitro-2-methylphenol BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.64-Bromophenyl phenyl ether BDL 8270E P1A04971111/8/21 20:05 JMVug/L 3.14-Chloro-3-methylphenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 3.74-Chloroaniline BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.94-Chlorophenyl phenyl ether BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.44-Nitroaniline BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.74-Nitrophenol BDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.80AcenaphtheneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 0.63AcenaphthyleneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 3.5AcetophenoneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.50AnthraceneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.2AtrazineBDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.5BenzaldehydeBDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.78Benzo(a)anthracene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.47Benzo(a)pyrene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.92Benzo(b)fluoranthene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.0Benzo(g,h,i)perylene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.85Benzo(k)fluoranthene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.0bis(2-Chloroethoxy)methane BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.7Bis(2-Chloroethyl)ether BDL 8270E P1A04971111/8/21 20:05 JMVug/L 2.9Bis(2-chloroisopropyl)ether BDL 8270E P1A04971111/8/21 20:05 JMVug/L 3.9Bis(2-Ethylhexyl)phthalate BDL 8270E P1A04971111/8/21 20:05 JMVug/L 3.1Butyl benzyl phthalate BDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.7CaprolactamBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-6 Sample ID: 1010111-03 Work Order: 1010111 Time Collected: 01/04/21 10:35 Time Submitted: 01/06/21 11:52 8270E P1A04971211/8/21 20:05 JMVug/L 4.3CarbazoleBDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.0ChryseneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 1.6Dibenzo(a,h)anthracene BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.4DibenzofuranBDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.4Diethyl phthalate BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.3Dimethyl phthalate BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.5Di-n-butyl phthalate BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.7Di-n-octyl phthalate BDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.60FluorantheneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.48FluoreneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.1HexachlorobenzeneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.7HexachlorobutadieneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 7.6HexachlorocyclopentadieneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 3.9HexachloroethaneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.79Indeno(1,2,3-cd)pyrene BDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.3IsophoroneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.3NaphthaleneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 4.1NitrobenzeneBDL 8270E P1A04971211/8/21 20:05 JMVug/L 3.4N-Nitroso-di-n-propylamine BDL 8270E P1A04971211/8/21 20:05 JMVug/L 4.7N-Nitrosodiphenylamine BDL 8270E P1A04971531/8/21 20:05 JMVug/L 11PentachlorophenolBDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.43PhenanthreneBDL 8270E P1A04971111/8/21 20:05 JMVug/L 1.5PhenolBDL 8270E P1A04971111/8/21 20:05 JMVug/L 0.71PyreneBDL Surrogate Recovery Control Limits 43-140106 %2,4,6-Tribromophenol 44-11980 %2-Fluorobiphenyl 19-11943 %2-Fluorophenol 44-12071 %Nitrobenzene-d5 11-5230 %Phenol-d5 50-13490 %Terphenyl-d14 Total Metals 7470A P1A051410.00020 1/8/21 15:19 EDVmg/L 0.000034MercuryBDL 6020B P1A049911.0 1/12/21 15:31 JABJug/L 0.17Arsenic0.34 6020B P1A049912.0 1/12/21 15:31 JABug/L 0.81Barium58 6020B P1A049911.0 1/12/21 15:31 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 15:31 JABJug/L 0.79Chromium1.4 6020B P1A049911.0 1/12/21 15:31 JABug/L 0.26LeadBDL 6020B P1A049915.0 1/12/21 15:31 JABJug/L 0.74Selenium0.83 6020B P1A049911.0 1/12/21 15:31 JABug/L 0.11SilverBDL Volatile Organic Compounds by GC/MS 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0611,1,1-Trichloroethane BDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-6 Sample ID: 1010111-03 Work Order: 1010111 Time Collected: 01/04/21 10:35 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0361,1,2,2-Tetrachloroethane BDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0661,1,2-Trichloroethane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0831,1-Dichloroethane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0831,1-Dichloroethylene BDL 8260D P1A054012.0 1/8/21 14:48 JLBug/L 0.401,2,3-Trichlorobenzene BDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.131,2,4-Trichlorobenzene BDL 8260D P1A054012.0 1/8/21 14:48 JLBug/L 0.171,2-Dibromo-3-chloropropane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0511,2-Dibromoethane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0761,2-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0661,2-Dichloroethane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.111,2-Dichloropropane BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0541,3-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.0501,4-Dichlorobenzene BDL 8260D P1A054011501/8/21 14:48 JLBug/L 141,4-Dioxane BDL 8260D P1A054015.0 1/8/21 14:48 JLBJug/L 0.31Acetone1.4 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.048BenzeneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.14BromochloromethaneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.062BromodichloromethaneBDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.040BromoformBDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.18BromomethaneBDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 0.075Carbon disulfide BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.11Carbon Tetrachloride BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.062ChlorobenzeneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.22ChloroethaneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.076ChloroformBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.079ChloromethaneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.056cis-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.079cis-1,3-Dichloropropylene BDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.95CyclohexaneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.081DibromochloromethaneBDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 0.11DichlorodifluoromethaneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.061EthylbenzeneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.054Isopropylbenzene (Cumene)BDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.12m,p-Xylenes BDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 1.0Methyl Acetate BDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 0.065Methyl Butyl Ketone (2-Hexanone)BDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 0.94MethylcyclohexaneBDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 0.24Methyl Ethyl Ketone (2-Butanone)BDL 8260D P1A054015.0 1/8/21 14:48 JLBug/L 1.0Methyl Isobutyl Ketone BDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.083Methylene Chloride BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.042Methyl-tert-Butyl Ether BDL 8260D P1A054011.0 1/8/21 14:48 JLBug/L 0.30NaphthaleneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-6 Sample ID: 1010111-03 Work Order: 1010111 Time Collected: 01/04/21 10:35 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.044o-Xylene BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.047StyreneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.098TetrachloroethyleneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.044TolueneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.094trans-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.070trans-1,3-Dichloropropylene BDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.078TrichloroethyleneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.062TrichlorofluoromethaneBDL 8260D P1A054010.50 1/8/21 14:48 JLBug/L 0.097Vinyl chloride BDL 8260D P1A054011.5 1/8/21 14:48 JLBug/L 0.15Xylenes, total BDL Surrogate Recovery Control Limits 80-12495 %4-Bromofluorobenzene 75-129102 %Dibromofluoromethane 77-12395 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-7 Sample ID: 1010111-04 Work Order: 1010111 Time Collected: 01/05/21 11:00 Time Submitted: 01/06/21 11:52 Semivolatile Organic Compounds by GC/MS 8270E P1A04971111/8/21 20:27 JMVug/L 0.851,1’-Biphenyl BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.22,3,4,6-Tetrachlorophenol BDL 8270E P1A04971211/8/21 20:27 JMVug/L 3.82,4,5-Trichlorophenol BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.82,4,6-Trichlorophenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.82,4-Dichlorophenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 5.12,4-Dimethylphenol BDL 8270E P1A04971531/8/21 20:27 JMVug/L 122,4-Dinitrophenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.42,4-Dinitrotoluene BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.12,6-Dinitrotoluene BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.92-Chloronaphthalene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.92-Chlorophenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.32-Methylnaphthalene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.62-Methylphenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.32-Nitroaniline BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.72-Nitrophenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.13,3’-Dichlorobenzidine BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.63/4-Methylphenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.03-Nitroaniline BDL 8270E P1A04971531/8/21 20:27 JMVug/L 124,6-Dinitro-2-methylphenol BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.64-Bromophenyl phenyl ether BDL 8270E P1A04971111/8/21 20:27 JMVug/L 3.14-Chloro-3-methylphenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 3.74-Chloroaniline BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.94-Chlorophenyl phenyl ether BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.44-Nitroaniline BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.74-Nitrophenol BDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.80AcenaphtheneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 0.63AcenaphthyleneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 3.5AcetophenoneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.50AnthraceneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.2AtrazineBDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.5BenzaldehydeBDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.78Benzo(a)anthracene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.47Benzo(a)pyrene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.92Benzo(b)fluoranthene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.0Benzo(g,h,i)perylene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.85Benzo(k)fluoranthene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.0bis(2-Chloroethoxy)methane BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.7Bis(2-Chloroethyl)ether BDL 8270E P1A04971111/8/21 20:27 JMVug/L 2.9Bis(2-chloroisopropyl)ether BDL 8270E P1A04971111/8/21 20:27 JMVug/L 3.9Bis(2-Ethylhexyl)phthalate BDL 8270E P1A04971111/8/21 20:27 JMVug/L 3.1Butyl benzyl phthalate BDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.7CaprolactamBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-7 Sample ID: 1010111-04 Work Order: 1010111 Time Collected: 01/05/21 11:00 Time Submitted: 01/06/21 11:52 8270E P1A04971211/8/21 20:27 JMVug/L 4.3CarbazoleBDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.0ChryseneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 1.6Dibenzo(a,h)anthracene BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.4DibenzofuranBDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.4Diethyl phthalate BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.3Dimethyl phthalate BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.5Di-n-butyl phthalate BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.7Di-n-octyl phthalate BDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.60FluorantheneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.48FluoreneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.1HexachlorobenzeneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.7HexachlorobutadieneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 7.6HexachlorocyclopentadieneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 3.9HexachloroethaneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.79Indeno(1,2,3-cd)pyrene BDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.3IsophoroneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.3NaphthaleneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 4.1NitrobenzeneBDL 8270E P1A04971211/8/21 20:27 JMVug/L 3.4N-Nitroso-di-n-propylamine BDL 8270E P1A04971211/8/21 20:27 JMVug/L 4.7N-Nitrosodiphenylamine BDL 8270E P1A04971531/8/21 20:27 JMVug/L 11PentachlorophenolBDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.43PhenanthreneBDL 8270E P1A04971111/8/21 20:27 JMVug/L 1.5PhenolBDL 8270E P1A04971111/8/21 20:27 JMVug/L 0.71PyreneBDL Surrogate Recovery Control Limits 43-140105 %2,4,6-Tribromophenol 44-11979 %2-Fluorobiphenyl 19-11939 %2-Fluorophenol 44-12067 %Nitrobenzene-d5 11-5231 %Phenol-d5 50-13489 %Terphenyl-d14 Total Metals 7470A P1A051410.00020 1/8/21 15:23 EDVmg/L 0.000034MercuryBDL 6020B P1A049911.0 1/12/21 17:34 JABug/L 0.17Arsenic4.8 6020B P1A049912.0 1/12/21 17:34 JABug/L 0.81Barium130 6020B P1A049911.0 1/12/21 17:34 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 17:34 JABug/L 0.79Chromium4.1 6020B P1A049911.0 1/12/21 17:34 JABug/L 0.26Lead6.9 6020B P1A049915.0 1/12/21 17:34 JABug/L 0.74SeleniumBDL 6020B P1A049911.0 1/12/21 17:34 JABug/L 0.11SilverBDL Volatile Organic Compounds by GC/MS 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0611,1,1-Trichloroethane BDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-7 Sample ID: 1010111-04 Work Order: 1010111 Time Collected: 01/05/21 11:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0361,1,2,2-Tetrachloroethane BDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0661,1,2-Trichloroethane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0831,1-Dichloroethane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0831,1-Dichloroethylene BDL 8260D P1A054012.0 1/8/21 15:12 JLBug/L 0.401,2,3-Trichlorobenzene BDL 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.131,2,4-Trichlorobenzene BDL 8260D P1A054012.0 1/8/21 15:12 JLBug/L 0.171,2-Dibromo-3-chloropropane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0511,2-Dibromoethane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0761,2-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0661,2-Dichloroethane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.111,2-Dichloropropane BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0541,3-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.0501,4-Dichlorobenzene BDL 8260D P1A054011501/8/21 15:12 JLBug/L 141,4-Dioxane BDL 8260D P1A054015.0 1/8/21 15:12 JLBJug/L 0.31Acetone2.4 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.048BenzeneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.14BromochloromethaneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.062BromodichloromethaneBDL 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.040BromoformBDL 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.18BromomethaneBDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 0.075Carbon disulfide BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.11Carbon Tetrachloride BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.062ChlorobenzeneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.22ChloroethaneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.076ChloroformBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.079ChloromethaneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.056cis-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.079cis-1,3-Dichloropropylene BDL 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.95CyclohexaneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.081DibromochloromethaneBDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 0.11DichlorodifluoromethaneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.061EthylbenzeneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.054Isopropylbenzene (Cumene)BDL 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.12m,p-Xylenes BDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 1.0Methyl Acetate BDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 0.065Methyl Butyl Ketone (2-Hexanone)BDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 0.94MethylcyclohexaneBDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 0.24Methyl Ethyl Ketone (2-Butanone)BDL 8260D P1A054015.0 1/8/21 15:12 JLBug/L 1.0Methyl Isobutyl Ketone BDL 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.083Methylene Chloride BDL 8260D P1A054010.50 1/8/21 15:12 JLBJug/L 0.042Methyl-tert-Butyl Ether 0.30 8260D P1A054011.0 1/8/21 15:12 JLBug/L 0.30NaphthaleneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-7 Sample ID: 1010111-04 Work Order: 1010111 Time Collected: 01/05/21 11:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.044o-Xylene BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.047StyreneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.098TetrachloroethyleneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.044TolueneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.094trans-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.070trans-1,3-Dichloropropylene BDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.078TrichloroethyleneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.062TrichlorofluoromethaneBDL 8260D P1A054010.50 1/8/21 15:12 JLBug/L 0.097Vinyl chloride BDL 8260D P1A054011.5 1/8/21 15:12 JLBug/L 0.15Xylenes, total BDL Surrogate Recovery Control Limits 80-12498 %4-Bromofluorobenzene 75-129102 %Dibromofluoromethane 77-12396 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-3 Sample ID: 1010111-05 Work Order: 1010111 Time Collected: 01/04/21 09:30 Time Submitted: 01/06/21 11:52 Semivolatile Organic Compounds by GC/MS 8270E P1A04971101/8/21 20:50 JMVug/L 0.841,1’-Biphenyl BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.12,3,4,6-Tetrachlorophenol BDL 8270E P1A04971211/8/21 20:50 JMVug/L 3.82,4,5-Trichlorophenol BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.72,4,6-Trichlorophenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.82,4-Dichlorophenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 5.12,4-Dimethylphenol BDL 8270E P1A04971521/8/21 20:50 JMVug/L 122,4-Dinitrophenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.42,4-Dinitrotoluene BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.12,6-Dinitrotoluene BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.92-Chloronaphthalene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.82-Chlorophenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.22-Methylnaphthalene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.52-Methylphenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.22-Nitroaniline BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.72-Nitrophenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.13,3’-Dichlorobenzidine BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.63/4-Methylphenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 3.93-Nitroaniline BDL 8270E P1A04971521/8/21 20:50 JMVug/L 124,6-Dinitro-2-methylphenol BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.64-Bromophenyl phenyl ether BDL 8270E P1A04971101/8/21 20:50 JMVug/L 3.14-Chloro-3-methylphenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 3.64-Chloroaniline BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.94-Chlorophenyl phenyl ether BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.34-Nitroaniline BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.74-Nitrophenol BDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.80AcenaphtheneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 0.62AcenaphthyleneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 3.5AcetophenoneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.49AnthraceneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.2AtrazineBDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.4BenzaldehydeBDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.78Benzo(a)anthracene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.46Benzo(a)pyrene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.91Benzo(b)fluoranthene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.0Benzo(g,h,i)perylene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.85Benzo(k)fluoranthene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.0bis(2-Chloroethoxy)methane BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.7Bis(2-Chloroethyl)ether BDL 8270E P1A04971101/8/21 20:50 JMVug/L 2.9Bis(2-chloroisopropyl)ether BDL 8270E P1A04971101/8/21 20:50 JMVug/L 3.9Bis(2-Ethylhexyl)phthalate BDL 8270E P1A04971101/8/21 20:50 JMVug/L 3.1Butyl benzyl phthalate BDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.6CaprolactamBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-3 Sample ID: 1010111-05 Work Order: 1010111 Time Collected: 01/04/21 09:30 Time Submitted: 01/06/21 11:52 8270E P1A04971211/8/21 20:50 JMVug/L 4.3CarbazoleBDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.0ChryseneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 1.6Dibenzo(a,h)anthracene BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.4DibenzofuranBDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.4Diethyl phthalate BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.2Dimethyl phthalate BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.5Di-n-butyl phthalate BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.7Di-n-octyl phthalate BDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.59FluorantheneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.48FluoreneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.0HexachlorobenzeneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.7HexachlorobutadieneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 7.6HexachlorocyclopentadieneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 3.9HexachloroethaneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.78Indeno(1,2,3-cd)pyrene BDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.3IsophoroneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.3NaphthaleneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 4.0NitrobenzeneBDL 8270E P1A04971211/8/21 20:50 JMVug/L 3.4N-Nitroso-di-n-propylamine BDL 8270E P1A04971211/8/21 20:50 JMVug/L 4.6N-Nitrosodiphenylamine BDL 8270E P1A04971521/8/21 20:50 JMVug/L 11PentachlorophenolBDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.42PhenanthreneBDL 8270E P1A04971101/8/21 20:50 JMVug/L 1.5PhenolBDL 8270E P1A04971101/8/21 20:50 JMVug/L 0.70PyreneBDL Surrogate Recovery Control Limits 43-14093 %2,4,6-Tribromophenol 44-11971 %2-Fluorobiphenyl 19-11939 %2-Fluorophenol 44-12064 %Nitrobenzene-d5 11-5229 %Phenol-d5 50-13481 %Terphenyl-d14 Total Metals 7470A P1A051410.00020 1/8/21 15:27 EDVJmg/L 0.000034Mercury0.000034 6020B P1A049911.0 1/12/21 15:44 JABJug/L 0.17Arsenic0.84 6020B P1A049912.0 1/12/21 15:44 JABug/L 0.81Barium100 6020B P1A049911.0 1/12/21 15:44 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 15:44 JABug/L 0.79Chromium2.4 6020B P1A049911.0 1/12/21 15:44 JABug/L 0.26Lead1.4 6020B P1A049915.0 1/12/21 15:44 JABug/L 0.74SeleniumBDL 6020B P1A049911.0 1/12/21 15:44 JABug/L 0.11SilverBDL Volatile Organic Compounds by GC/MS 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0611,1,1-Trichloroethane BDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-3 Sample ID: 1010111-05 Work Order: 1010111 Time Collected: 01/04/21 09:30 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0361,1,2,2-Tetrachloroethane BDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0661,1,2-Trichloroethane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0831,1-Dichloroethane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0831,1-Dichloroethylene BDL 8260D P1A054012.0 1/8/21 15:35 JLBug/L 0.401,2,3-Trichlorobenzene BDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.131,2,4-Trichlorobenzene BDL 8260D P1A054012.0 1/8/21 15:35 JLBug/L 0.171,2-Dibromo-3-chloropropane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0511,2-Dibromoethane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0761,2-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0661,2-Dichloroethane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.111,2-Dichloropropane BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0541,3-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.0501,4-Dichlorobenzene BDL 8260D P1A054011501/8/21 15:35 JLBug/L 141,4-Dioxane BDL 8260D P1A054015.0 1/8/21 15:35 JLBJug/L 0.31Acetone2.1 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.048BenzeneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.14BromochloromethaneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.062BromodichloromethaneBDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.040BromoformBDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.18BromomethaneBDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 0.075Carbon disulfide BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.11Carbon Tetrachloride BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.062ChlorobenzeneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.22ChloroethaneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.076ChloroformBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.079ChloromethaneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.056cis-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.079cis-1,3-Dichloropropylene BDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.95CyclohexaneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.081DibromochloromethaneBDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 0.11DichlorodifluoromethaneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.061EthylbenzeneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.054Isopropylbenzene (Cumene)BDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.12m,p-Xylenes BDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 1.0Methyl Acetate BDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 0.065Methyl Butyl Ketone (2-Hexanone)BDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 0.94MethylcyclohexaneBDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 0.24Methyl Ethyl Ketone (2-Butanone)BDL 8260D P1A054015.0 1/8/21 15:35 JLBug/L 1.0Methyl Isobutyl Ketone BDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.083Methylene Chloride BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.042Methyl-tert-Butyl Ether BDL 8260D P1A054011.0 1/8/21 15:35 JLBug/L 0.30NaphthaleneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-3 Sample ID: 1010111-05 Work Order: 1010111 Time Collected: 01/04/21 09:30 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.044o-Xylene BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.047StyreneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.098TetrachloroethyleneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.044TolueneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.094trans-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.070trans-1,3-Dichloropropylene BDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.078TrichloroethyleneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.062TrichlorofluoromethaneBDL 8260D P1A054010.50 1/8/21 15:35 JLBug/L 0.097Vinyl chloride BDL 8260D P1A054011.5 1/8/21 15:35 JLBug/L 0.15Xylenes, total BDL Surrogate Recovery Control Limits 80-12498 %4-Bromofluorobenzene 75-129102 %Dibromofluoromethane 77-12394 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: DUP-2 Sample ID: 1010111-06 Work Order: 1010111 Time Collected: 01/04/21 00:00 Time Submitted: 01/06/21 11:52 Semivolatile Organic Compounds by GC/MS 8270E P1A04971101/8/21 21:12 JMVug/L 0.811,1’-Biphenyl BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.02,3,4,6-Tetrachlorophenol BDL 8270E P1A04971201/8/21 21:12 JMVug/L 3.62,4,5-Trichlorophenol BDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.52,4,6-Trichlorophenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.62,4-Dichlorophenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.92,4-Dimethylphenol BDL 8270E P1A04971501/8/21 21:12 JMVug/L 122,4-Dinitrophenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.22,4-Dinitrotoluene BDL 8270E P1A04971201/8/21 21:12 JMVug/L 3.92,6-Dinitrotoluene BDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.72-Chloronaphthalene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.72-Chlorophenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 1.22-Methylnaphthalene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.42-Methylphenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.12-Nitroaniline BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.62-Nitrophenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.93,3’-Dichlorobenzidine BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.53/4-Methylphenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.83-Nitroaniline BDL 8270E P1A04971501/8/21 21:12 JMVug/L 114,6-Dinitro-2-methylphenol BDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.44-Bromophenyl phenyl ether BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.94-Chloro-3-methylphenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.54-Chloroaniline BDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.74-Chlorophenyl phenyl ether BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.14-Nitroaniline BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.64-Nitrophenol BDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.76AcenaphtheneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 0.60AcenaphthyleneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 3.4AcetophenoneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.47AnthraceneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 1.1AtrazineBDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.4BenzaldehydeBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.74Benzo(a)anthracene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.44Benzo(a)pyrene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.87Benzo(b)fluoranthene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.98Benzo(g,h,i)perylene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.81Benzo(k)fluoranthene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.8bis(2-Chloroethoxy)methane BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.6Bis(2-Chloroethyl)ether BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.8Bis(2-chloroisopropyl)ether BDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.7Bis(2-Ethylhexyl)phthalate BDL 8270E P1A04971101/8/21 21:12 JMVug/L 2.9Butyl benzyl phthalate BDL 8270E P1A04971101/8/21 21:12 JMVug/L 1.6CaprolactamBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: DUP-2 Sample ID: 1010111-06 Work Order: 1010111 Time Collected: 01/04/21 00:00 Time Submitted: 01/06/21 11:52 8270E P1A04971201/8/21 21:12 JMVug/L 4.1CarbazoleBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.98ChryseneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 1.6Dibenzo(a,h)anthracene BDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.2DibenzofuranBDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.2Diethyl phthalate BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.1Dimethyl phthalate BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.3Di-n-butyl phthalate BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.5Di-n-octyl phthalate BDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.57FluorantheneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.46FluoreneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 3.9HexachlorobenzeneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.5HexachlorobutadieneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 7.3HexachlorocyclopentadieneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.7HexachloroethaneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.75Indeno(1,2,3-cd)pyrene BDL 8270E P1A04971101/8/21 21:12 JMVug/L 4.1IsophoroneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 1.3NaphthaleneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 3.8NitrobenzeneBDL 8270E P1A04971201/8/21 21:12 JMVug/L 3.3N-Nitroso-di-n-propylamine BDL 8270E P1A04971201/8/21 21:12 JMVug/L 4.4N-Nitrosodiphenylamine BDL 8270E P1A04971501/8/21 21:12 JMVug/L 11PentachlorophenolBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.40PhenanthreneBDL 8270E P1A04971101/8/21 21:12 JMVug/L 1.4PhenolBDL 8270E P1A04971101/8/21 21:12 JMVug/L 0.67PyreneBDL Surrogate Recovery Control Limits 43-14089 %2,4,6-Tribromophenol 44-11965 %2-Fluorobiphenyl 19-11937 %2-Fluorophenol 44-12061 %Nitrobenzene-d5 11-5226 %Phenol-d5 50-13476 %Terphenyl-d14 Total Metals 7470A P1A051410.00020 1/8/21 14:52 EDVJmg/L 0.000034Mercury0.000038 6020B P1A049911.0 1/12/21 15:51 JABJug/L 0.17Arsenic0.31 6020B P1A049912.0 1/12/21 15:51 JABug/L 0.81Barium59 6020B P1A049911.0 1/12/21 15:51 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 15:51 JABJug/L 0.79Chromium0.94 6020B P1A049911.0 1/12/21 15:51 JABug/L 0.26LeadBDL 6020B P1A049915.0 1/12/21 15:51 JABJug/L 0.74Selenium1.1 6020B P1A049911.0 1/12/21 15:51 JABug/L 0.11SilverBDL Volatile Organic Compounds by GC/MS 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0611,1,1-Trichloroethane BDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: DUP-2 Sample ID: 1010111-06 Work Order: 1010111 Time Collected: 01/04/21 00:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0361,1,2,2-Tetrachloroethane BDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0661,1,2-Trichloroethane BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0831,1-Dichloroethane BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0831,1-Dichloroethylene BDL 8260D P1A054012.0 1/8/21 15:59 JLBug/L 0.401,2,3-Trichlorobenzene BDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.131,2,4-Trichlorobenzene BDL 8260D P1A054012.0 1/8/21 15:59 JLBug/L 0.171,2-Dibromo-3-chloropropane BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0511,2-Dibromoethane BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0761,2-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 15:59 JLBJug/L 0.0661,2-Dichloroethane 0.25 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.111,2-Dichloropropane BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0541,3-Dichlorobenzene BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.0501,4-Dichlorobenzene BDL 8260D P1A054011501/8/21 15:59 JLBug/L 141,4-Dioxane BDL 8260D P1A054015.0 1/8/21 15:59 JLBJug/L 0.31Acetone1.2 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.048BenzeneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.14BromochloromethaneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.062BromodichloromethaneBDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.040BromoformBDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.18BromomethaneBDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 0.075Carbon disulfide BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.11Carbon Tetrachloride BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.062ChlorobenzeneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.22ChloroethaneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.076ChloroformBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.079ChloromethaneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.056cis-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.079cis-1,3-Dichloropropylene BDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.95CyclohexaneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.081DibromochloromethaneBDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 0.11DichlorodifluoromethaneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.061EthylbenzeneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.054Isopropylbenzene (Cumene)BDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.12m,p-Xylenes BDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 1.0Methyl Acetate BDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 0.065Methyl Butyl Ketone (2-Hexanone)BDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 0.94MethylcyclohexaneBDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 0.24Methyl Ethyl Ketone (2-Butanone)BDL 8260D P1A054015.0 1/8/21 15:59 JLBug/L 1.0Methyl Isobutyl Ketone BDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.083Methylene Chloride BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.042Methyl-tert-Butyl Ether BDL 8260D P1A054011.0 1/8/21 15:59 JLBug/L 0.30NaphthaleneBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: DUP-2 Sample ID: 1010111-06 Work Order: 1010111 Time Collected: 01/04/21 00:00 Time Submitted: 01/06/21 11:52 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.044o-Xylene BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.047StyreneBDL 8260D P1A054010.50 1/8/21 15:59 JLBJug/L 0.098Tetrachloroethylene0.28 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.044TolueneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.094trans-1,2-Dichloroethylene BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.070trans-1,3-Dichloropropylene BDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.078TrichloroethyleneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.062TrichlorofluoromethaneBDL 8260D P1A054010.50 1/8/21 15:59 JLBug/L 0.097Vinyl chloride BDL 8260D P1A054011.5 1/8/21 15:59 JLBug/L 0.15Xylenes, total BDL Surrogate Recovery Control Limits 80-12499 %4-Bromofluorobenzene 75-129102 %Dibromofluoromethane 77-12396 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-4 (Filtered) Sample ID: 1010111-07 Work Order: 1010111 Time Collected: 01/05/21 10:00 Time Submitted: 01/06/21 11:52 Total Metals 7470A P1A051410.00020 1/8/21 15:31 EDVmg/L 0.000034MercuryBDL 6020B P1A049911.0 1/13/21 13:43 JABJug/L 0.17Arsenic0.25 6020B P1A049912.0 1/13/21 13:43 JABug/L 0.81Barium130 6020B P1A049911.0 1/13/21 13:43 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/13/21 13:43 JABug/L 0.79ChromiumBDL 6020B P1A049911.0 1/13/21 13:43 JABug/L 0.26Lead1.7 6020B P1A049915.0 1/13/21 13:43 JABug/L 0.74SeleniumBDL 6020B P1A049911.0 1/13/21 13:43 JABug/L 0.11SilverBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 45 Laboratory Report 01/15/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: TW-7 (Filtered) Sample ID: 1010111-08 Work Order: 1010111 Time Collected: 01/05/21 11:00 Time Submitted: 01/06/21 11:52 Total Metals 7470A P1A051410.00020 1/8/21 15:34 EDVmg/L 0.000034MercuryBDL 6020B P1A049911.0 1/12/21 15:38 JABug/L 0.17Arsenic4.0 6020B P1A049912.0 1/12/21 15:38 JABug/L 0.81Barium120 6020B P1A049911.0 1/12/21 15:38 JABug/L 0.16CadmiumBDL 6020B P1A049912.0 1/12/21 15:38 JABJug/L 0.79Chromium1.1 6020B P1A049911.0 1/12/21 15:38 JABug/L 0.26LeadBDL 6020B P1A049915.0 1/12/21 15:38 JABug/L 0.74SeleniumBDL 6020B P1A049911.0 1/12/21 15:38 JABug/L 0.11SilverBDL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0540 - SM6200 B Blank (P1A0540-BLK1)Prepared & Analyzed: 01/08/21 1,1,1-Trichloroethane ug/LBRL0.50 1,1,2,2-Tetrachloroethane ug/LBRL0.50 1,1,2-Trichloro-1,2,2-trifluoroethane ug/LBRL5.0 1,1,2-Trichloroethane ug/LBRL0.50 1,1-Dichloroethane ug/LBRL0.50 1,1-Dichloroethylene ug/LBRL0.50 1,2,3-Trichlorobenzene ug/LBRL2.0 1,2,4-Trichlorobenzene ug/LBRL1.0 1,2-Dibromo-3-chloropropane ug/LBRL2.0 1,2-Dibromoethane ug/LBRL0.50 1,2-Dichlorobenzene ug/LBRL0.50 1,2-Dichloroethane ug/LBRL0.50 1,2-Dichloropropane ug/LBRL0.50 1,3-Dichlorobenzene ug/LBRL0.50 1,4-Dichlorobenzene ug/LBRL0.50 1,4-Dioxane ug/LBRL150 Acetone ug/LBRL5.0 Benzene ug/LBRL0.50 Bromochloromethane ug/LBRL0.50 Bromodichloromethane ug/LBRL0.50 Bromoform ug/LBRL1.0 Bromomethane ug/LBRL1.0 Carbon disulfide ug/LBRL5.0 Carbon Tetrachloride ug/LBRL0.50 Chlorobenzene ug/LBRL0.50 Chloroethane ug/LBRL0.50 Chloroform ug/LBRL0.50 Chloromethane ug/LBRL0.50 cis-1,2-Dichloroethylene ug/LBRL0.50 cis-1,3-Dichloropropylene ug/LBRL0.50 Cyclohexane ug/LBRL1.0 Dibromochloromethane ug/LBRL0.50 Dichlorodifluoromethane ug/LBRL5.0 Ethylbenzene ug/LBRL0.50 Isopropylbenzene (Cumene)ug/LBRL0.50 m,p-Xylenes ug/LBRL1.0 Methyl Acetate ug/LBRL5.0 Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0 Methylcyclohexane ug/LBRL5.0 Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0 Methyl Isobutyl Ketone ug/LBRL5.0 Methylene Chloride ug/LBRL1.0 Methyl-tert-Butyl Ether ug/LBRL0.50 Naphthalene ug/LBRL1.0 o-Xylene ug/LBRL0.50 Styrene ug/LBRL0.50 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0540 - SM6200 B Blank (P1A0540-BLK1)Prepared & Analyzed: 01/08/21 Tetrachloroethylene ug/LBRL0.50 Toluene ug/LBRL0.50 trans-1,2-Dichloroethylene ug/LBRL0.50 trans-1,3-Dichloropropylene ug/LBRL0.50 Trichloroethylene ug/LBRL0.50 Trichlorofluoromethane ug/LBRL0.50 Vinyl chloride ug/LBRL0.50 Xylenes, total ug/LBRL1.5 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9648.0 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10251.0 ug/L 50.00 77-123Surrogate: Toluene-d8 9647.9 LCS (P1A0540-BS1)Prepared & Analyzed: 01/08/21 1,1,1-Trichloroethane ug/L21.8 0.50 20.00 75-136109 1,1,2,2-Tetrachloroethane ug/L19.6 0.50 20.00 62-12798 1,1,2-Trichloro-1,2,2-trifluoroethane ug/L22.4 5.0 20.00 70-130112 1,1,2-Trichloroethane ug/L21.1 0.50 20.00 70-140106 1,1-Dichloroethane ug/L21.8 0.50 20.00 78-130109 1,1-Dichloroethylene ug/L21.8 0.50 20.00 70-154109 1,2,3-Trichlorobenzene ug/L20.2 2.0 20.00 58-144101 1,2,4-Trichlorobenzene ug/L21.0 1.0 20.00 66-139105 1,2-Dibromo-3-chloropropane ug/L19.9 2.0 20.00 63-13499 1,2-Dibromoethane ug/L20.3 0.50 20.00 77-135102 1,2-Dichlorobenzene ug/L20.5 0.50 20.00 78-128103 1,2-Dichloroethane ug/L21.1 0.50 20.00 68-131105 1,2-Dichloropropane ug/L21.4 0.50 20.00 77-130107 1,3-Dichlorobenzene ug/L20.7 0.50 20.00 77-125104 1,4-Dichlorobenzene ug/L20.9 0.50 20.00 75-126104 1,4-Dioxane ug/L177 150 200.0 70-13089 Acetone ug/L32.2 5.0 40.00 40-16680 Benzene ug/L21.6 0.50 20.00 77-128108 Bromochloromethane ug/L21.8 0.50 20.00 78-135109 Bromodichloromethane ug/L22.0 0.50 20.00 76-138110 Bromoform ug/L21.1 1.0 20.00 71-135106 Bromomethane ug/L21.6 1.0 20.00 41-168108 Carbon disulfide ug/L21.5 5.0 20.00 59-135108 Carbon Tetrachloride ug/L21.8 0.50 20.00 72-142109 Chlorobenzene ug/L21.0 0.50 20.00 78-119105 Chloroethane ug/L20.2 0.50 20.00 57-142101 Chloroform ug/L21.2 0.50 20.00 77-130106 Chloromethane ug/L21.5 0.50 20.00 47-145108 cis-1,2-Dichloroethylene ug/L21.7 0.50 20.00 76-141108 cis-1,3-Dichloropropylene ug/L21.6 0.50 20.00 65-140108 Cyclohexane ug/L21.9 1.0 20.00 70-130109 Dibromochloromethane ug/L20.8 0.50 20.00 75-134104 Dichlorodifluoromethane ug/L23.6 5.0 20.00 28-163118 Ethylbenzene ug/L20.7 0.50 20.00 80-127103 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0540 - SM6200 B LCS (P1A0540-BS1)Prepared & Analyzed: 01/08/21 Isopropylbenzene (Cumene)ug/L21.2 0.50 20.00 70-130106 m,p-Xylenes ug/L43.1 1.0 40.00 77-133108 Methyl Acetate ug/L18.9 5.0 20.00 70-13095 Methyl Butyl Ketone (2-Hexanone)ug/L19.2 5.0 20.00 64-13796 Methylcyclohexane ug/L20.4 5.0 20.00 70-130102 Methyl Ethyl Ketone (2-Butanone)ug/L19.1 5.0 20.00 71-13496 Methyl Isobutyl Ketone ug/L19.8 5.0 20.00 69-13499 Methylene Chloride ug/L21.2 1.0 20.00 73-131106 Methyl-tert-Butyl Ether ug/L20.9 0.50 20.00 68-135104 Naphthalene ug/L18.6 1.0 20.00 64-13693 o-Xylene ug/L20.9 0.50 20.00 78-128105 Styrene ug/L21.2 0.50 20.00 78-129106 Tetrachloroethylene ug/L20.7 0.50 20.00 80-129103 Toluene ug/L21.3 0.50 20.00 76-131107 trans-1,2-Dichloroethylene ug/L21.6 0.50 20.00 76-135108 trans-1,3-Dichloropropylene ug/L21.5 0.50 20.00 67-140108 Trichloroethylene ug/L22.2 0.50 20.00 77-133111 Trichlorofluoromethane ug/L21.2 0.50 20.00 62-148106 Vinyl chloride ug/L21.5 0.50 20.00 57-141108 Xylenes, total ug/L64.0 1.5 60.00 77-133107 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 10049.8 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10150.4 ug/L 50.00 77-123Surrogate: Toluene-d8 9748.5 LCS Dup (P1A0540-BSD1)Prepared & Analyzed: 01/08/21 1,1,1-Trichloroethane ug/L20.4 0.50 20.00 2075-136102 7 1,1,2,2-Tetrachloroethane ug/L19.2 0.50 20.00 2062-12796 2 1,1,2-Trichloro-1,2,2-trifluoroethane ug/L21.1 5.0 20.00 2070-130105 6 1,1,2-Trichloroethane ug/L20.4 0.50 20.00 2070-140102 3 1,1-Dichloroethane ug/L20.7 0.50 20.00 2078-130103 5 1,1-Dichloroethylene ug/L20.6 0.50 20.00 2070-154103 6 1,2,3-Trichlorobenzene ug/L19.8 2.0 20.00 2058-14499 2 1,2,4-Trichlorobenzene ug/L20.0 1.0 20.00 2066-139100 5 1,2-Dibromo-3-chloropropane ug/L19.4 2.0 20.00 2063-13497 2 1,2-Dibromoethane ug/L20.2 0.50 20.00 2077-135101 0.7 1,2-Dichlorobenzene ug/L19.6 0.50 20.00 2078-12898 4 1,2-Dichloroethane ug/L20.3 0.50 20.00 2068-131102 4 1,2-Dichloropropane ug/L20.7 0.50 20.00 2077-130104 3 1,3-Dichlorobenzene ug/L20.2 0.50 20.00 2077-125101 3 1,4-Dichlorobenzene ug/L19.9 0.50 20.00 2075-126100 5 1,4-Dioxane ug/L179 150 200.0 2070-13089 0.8 Acetone ug/L42.2 5.0 40.00 20 D40-166105 27 Benzene ug/L20.6 0.50 20.00 2077-128103 5 Bromochloromethane ug/L21.1 0.50 20.00 2078-135105 4 Bromodichloromethane ug/L20.6 0.50 20.00 2076-138103 6 Bromoform ug/L20.9 1.0 20.00 2071-135104 1 Bromomethane ug/L21.7 1.0 20.00 2041-168109 0.6 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0540 - SM6200 B LCS Dup (P1A0540-BSD1)Prepared & Analyzed: 01/08/21 Carbon disulfide ug/L20.5 5.0 20.00 2059-135103 5 Carbon Tetrachloride ug/L20.4 0.50 20.00 2072-142102 7 Chlorobenzene ug/L20.2 0.50 20.00 2078-119101 3 Chloroethane ug/L19.0 0.50 20.00 2057-14295 6 Chloroform ug/L20.2 0.50 20.00 2077-130101 5 Chloromethane ug/L20.8 0.50 20.00 2047-145104 3 cis-1,2-Dichloroethylene ug/L20.7 0.50 20.00 2076-141104 5 cis-1,3-Dichloropropylene ug/L21.1 0.50 20.00 2065-140106 2 Cyclohexane ug/L20.4 1.0 20.00 2070-130102 7 Dibromochloromethane ug/L20.4 0.50 20.00 2075-134102 2 Dichlorodifluoromethane ug/L22.1 5.0 20.00 2028-163110 7 Ethylbenzene ug/L19.7 0.50 20.00 2080-12798 5 Isopropylbenzene (Cumene)ug/L20.0 0.50 20.00 2070-130100 5 m,p-Xylenes ug/L42.1 1.0 40.00 2077-133105 2 Methyl Acetate ug/L19.1 5.0 20.00 2070-13095 0.7 Methyl Butyl Ketone (2-Hexanone)ug/L22.1 5.0 20.00 2064-137110 14 Methylcyclohexane ug/L19.1 5.0 20.00 2070-13096 7 Methyl Ethyl Ketone (2-Butanone)ug/L20.2 5.0 20.00 2071-134101 5 Methyl Isobutyl Ketone ug/L19.6 5.0 20.00 2069-13498 1 Methylene Chloride ug/L20.7 1.0 20.00 2073-131104 2 Methyl-tert-Butyl Ether ug/L20.4 0.50 20.00 2068-135102 2 Naphthalene ug/L17.6 1.0 20.00 2064-13688 5 o-Xylene ug/L20.2 0.50 20.00 2078-128101 4 Styrene ug/L20.4 0.50 20.00 2078-129102 4 Tetrachloroethylene ug/L19.9 0.50 20.00 2080-129100 4 Toluene ug/L20.2 0.50 20.00 2076-131101 6 trans-1,2-Dichloroethylene ug/L20.3 0.50 20.00 2076-135102 6 trans-1,3-Dichloropropylene ug/L20.8 0.50 20.00 2067-140104 3 Trichloroethylene ug/L20.6 0.50 20.00 2077-133103 8 Trichlorofluoromethane ug/L19.7 0.50 20.00 2062-14898 7 Vinyl chloride ug/L20.6 0.50 20.00 2057-141103 5 Xylenes, total ug/L62.2 1.5 60.00 2077-133104 3 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9849.1 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10049.9 ug/L 50.00 77-123Surrogate: Toluene-d8 9648.2 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS Blank (P1A0497-BLK1)Prepared: 01/07/21 Analyzed: 01/08/21 1,1’-Biphenyl ug/LBRL10 2,3,4,6-Tetrachlorophenol ug/LBRL10 2,4,5-Trichlorophenol ug/LBRL20 2,4,6-Trichlorophenol ug/LBRL20 2,4-Dichlorophenol ug/LBRL10 2,4-Dimethylphenol ug/LBRL10 2,4-Dinitrophenol ug/LBRL50 2,4-Dinitrotoluene ug/LBRL10 2,6-Dinitrotoluene ug/LBRL20 2-Chloronaphthalene ug/LBRL20 2-Chlorophenol ug/LBRL10 2-Methylnaphthalene ug/LBRL10 2-Methylphenol ug/LBRL10 2-Nitroaniline ug/LBRL10 2-Nitrophenol ug/LBRL10 3,3’-Dichlorobenzidine ug/LBRL10 3/4-Methylphenol ug/LBRL10 3-Nitroaniline ug/LBRL10 4,6-Dinitro-2-methylphenol ug/LBRL50 4-Bromophenyl phenyl ether ug/LBRL20 4-Chloro-3-methylphenol ug/LBRL10 4-Chloroaniline ug/LBRL10 4-Chlorophenyl phenyl ether ug/LBRL20 4-Nitroaniline ug/LBRL10 4-Nitrophenol ug/LBRL10 Acenaphthene ug/LBRL10 Acenaphthylene ug/LBRL20 Acetophenone ug/LBRL20 Anthracene ug/LBRL10 Atrazine ug/LBRL10 Benzaldehyde ug/LBRL10 Benzo(a)anthracene ug/LBRL10 Benzo(a)pyrene ug/LBRL10 Benzo(b)fluoranthene ug/LBRL10 Benzo(g,h,i)perylene ug/LBRL10 Benzo(k)fluoranthene ug/LBRL10 bis(2-Chloroethoxy)methane ug/LBRL10 Bis(2-Chloroethyl)ether ug/LBRL10 Bis(2-chloroisopropyl)ether ug/LBRL10 Bis(2-Ethylhexyl)phthalate ug/LBRL10 Butyl benzyl phthalate ug/LBRL10 Caprolactam ug/LBRL10 Carbazole ug/LBRL20 Chrysene ug/LBRL10 Dibenzo(a,h)anthracene ug/LBRL20 Dibenzofuran ug/LBRL20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS Blank (P1A0497-BLK1)Prepared: 01/07/21 Analyzed: 01/08/21 Diethyl phthalate ug/LBRL20 Dimethyl phthalate ug/LBRL10 Di-n-butyl phthalate ug/LBRL10 Di-n-octyl phthalate ug/LBRL10 Fluoranthene ug/LBRL10 Fluorene ug/LBRL10 Hexachlorobenzene ug/LBRL20 Hexachlorobutadiene ug/LBRL20 Hexachlorocyclopentadiene ug/LBRL20 Hexachloroethane ug/LBRL10 Indeno(1,2,3-cd)pyrene ug/LBRL10 Isophorone ug/LBRL10 Naphthalene ug/LBRL10 Nitrobenzene ug/LBRL10 N-Nitroso-di-n-propylamine ug/LBRL20 N-Nitrosodiphenylamine ug/LBRL20 Pentachlorophenol ug/LBRL50 Phenanthrene ug/LBRL10 Phenol ug/LBRL10 Pyrene ug/LBRL10 ug/L 100.0 43-140Surrogate: 2,4,6-Tribromophenol 104104 ug/L 50.00 44-119Surrogate: 2-Fluorobiphenyl 7436.8 ug/L 100.0 19-119Surrogate: 2-Fluorophenol 3434.5 ug/L 50.00 44-120Surrogate: Nitrobenzene-d5 6231.0 ug/L 100.0 11-52Surrogate: Phenol-d5 2524.6 ug/L 50.00 50-134Surrogate: Terphenyl-d14 9447.2 LCS (P1A0497-BS1)Prepared: 01/07/21 Analyzed: 01/08/21 2,4,5-Trichlorophenol ug/L37.1 20 50.00 53-12374 2,4,6-Trichlorophenol ug/L34.2 20 50.00 50-12568 2,4-Dichlorophenol ug/L30.5 10 50.00 47-12161 2,4-Dimethylphenol ug/L32.2 10 50.00 31-12464 2,4-Dinitrophenol ug/L24.9 50 50.00 J23-14350 2,4-Dinitrotoluene ug/L42.6 10 50.00 57-12885 2,6-Dinitrotoluene ug/L40.4 20 50.00 57-12481 2-Chloronaphthalene ug/L28.6 20 50.00 40-11657 2-Chlorophenol ug/L23.2 10 50.00 38-11746 2-Methylnaphthalene ug/L24.7 10 50.00 40-12149 2-Methylphenol ug/L23.9 10 50.00 30-11748 2-Nitroaniline ug/L37.0 10 50.00 55-12774 2-Nitrophenol ug/L26.7 10 50.00 47-12353 3,3’-Dichlorobenzidine ug/L47.1 10 50.00 27-12994 3/4-Methylphenol ug/L20.5 10 50.00 29-11041 3-Nitroaniline ug/L40.8 10 50.00 41-12882 4,6-Dinitro-2-methylphenol ug/L33.9 50 50.00 J44-13768 4-Bromophenyl phenyl ether ug/L40.3 20 50.00 55-12481 4-Chloro-3-methylphenol ug/L36.6 10 50.00 52-11973 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS LCS (P1A0497-BS1)Prepared: 01/07/21 Analyzed: 01/08/21 4-Chloroaniline ug/L34.2 10 50.00 33-11768 4-Chlorophenyl phenyl ether ug/L35.0 20 50.00 53-12170 4-Nitroaniline ug/L41.4 10 50.00 45-13583 4-Nitrophenol ug/L13.4 10 50.00 10-7727 Acenaphthene ug/L31.6 10 50.00 47-12263 Acenaphthylene ug/L34.0 20 50.00 41-13068 Acetophenone ug/L26.5 20 50.00 46-11853 Anthracene ug/L41.7 10 50.00 57-12383 Benzo(a)anthracene ug/L41.0 10 50.00 58-12582 Benzo(a)pyrene ug/L54.1 10 50.00 54-128108 Benzo(b)fluoranthene ug/L45.6 10 50.00 53-13191 Benzo(g,h,i)perylene ug/L44.4 10 50.00 50-13489 Benzo(k)fluoranthene ug/L41.2 10 50.00 57-12982 bis(2-Chloroethoxy)methane ug/L28.7 10 50.00 48-12057 Bis(2-Chloroethyl)ether ug/L21.9 10 50.00 43-11844 Bis(2-chloroisopropyl)ether ug/L20.6 10 50.00 37-13041 Bis(2-Ethylhexyl)phthalate ug/L47.5 10 50.00 55-13595 Butyl benzyl phthalate ug/L42.8 10 50.00 53-13486 Carbazole ug/L43.4 20 50.00 60-12287 Chrysene ug/L39.8 10 50.00 59-12380 Dibenzo(a,h)anthracene ug/L30.5 20 50.00 51-13461 Dibenzofuran ug/L34.7 20 50.00 53-11869 Diethyl phthalate ug/L39.4 20 50.00 56-12579 Dimethyl phthalate ug/L38.1 10 50.00 45-12776 Di-n-butyl phthalate ug/L45.4 10 50.00 59-12791 Di-n-octyl phthalate ug/L46.5 10 50.00 51-14093 Fluoranthene ug/L42.2 10 50.00 57-12884 Fluorene ug/L36.6 10 50.00 52-12473 Hexachlorobenzene ug/L42.0 20 50.00 53-12584 Hexachlorobutadiene ug/L21.3 20 50.00 22-12443 Hexachlorocyclopentadiene ug/L17.5 20 50.00 J32-11735 Hexachloroethane ug/L16.6 10 50.00 21-11533 Indeno(1,2,3-cd)pyrene ug/L42.4 10 50.00 52-13485 Isophorone ug/L25.7 10 50.00 42-12451 Naphthalene ug/L21.3 10 50.00 40-12143 Nitrobenzene ug/L23.8 10 50.00 45-12148 N-Nitroso-di-n-propylamine ug/L28.5 20 50.00 49-11957 N-Nitrosodiphenylamine ug/L44.2 20 50.00 51-12388 Pentachlorophenol ug/L40.6 50 50.00 J35-13881 Phenanthrene ug/L40.3 10 50.00 59-12081 Phenol ug/L11.8 10 50.00 12-5824 Pyrene ug/L43.2 10 50.00 57-12686 ug/L 100.0 43-140Surrogate: 2,4,6-Tribromophenol 8585.4 ug/L 50.00 44-119Surrogate: 2-Fluorobiphenyl 6030.1 ug/L 100.0 19-119Surrogate: 2-Fluorophenol 2827.8 ug/L 50.00 44-120Surrogate: Nitrobenzene-d5 4723.6 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS LCS (P1A0497-BS1)Prepared: 01/07/21 Analyzed: 01/08/21 ug/L 100.0 11-52Surrogate: Phenol-d5 2020.3 ug/L 50.00 50-134Surrogate: Terphenyl-d14 7236.2 LCS (P1A0497-BS2)LPrepared: 01/07/21 Analyzed: 01/08/21 1,1’-Biphenyl ug/L34.4 10 100.0 49-11534 2,3,4,6-Tetrachlorophenol ug/L56.2 10 100.0 50-12856 Atrazine ug/L45.4 10 100.0 44-14245 Benzaldehyde ug/L28.6 10 100.0 35-11529 Caprolactam ug/L10.2 10 100.0 35-11510 ug/L 100.0 43-140Surrogate: 2,4,6-Tribromophenol 9797.1 ug/L 50.00 44-119Surrogate: 2-Fluorobiphenyl 7135.6 ug/L 100.0 19-119Surrogate: 2-Fluorophenol 4141.4 ug/L 50.00 44-120Surrogate: Nitrobenzene-d5 6733.7 ug/L 100.0 11-52Surrogate: Phenol-d5 2727.3 ug/L 50.00 50-134Surrogate: Terphenyl-d14 8040.0 Matrix Spike (P1A0497-MS1)Prepared: 01/07/21 Analyzed: 01/08/21 Source: 1010111-01 2,4,5-Trichlorophenol ug/L52.4 20 50.00 BRL 53-123105 2,4,6-Trichlorophenol ug/L49.7 20 50.00 BRL 50-12599 2,4-Dichlorophenol ug/L47.2 10 50.00 BRL 47-12194 2,4-Dimethylphenol ug/L49.8 10 50.00 BRL 31-124100 2,4-Dinitrophenol ug/L41.8 50 50.00 BRL J23-14384 2,4-Dinitrotoluene ug/L58.5 10 50.00 BRL 57-128117 2,6-Dinitrotoluene ug/L54.7 20 50.00 BRL 57-124109 2-Chloronaphthalene ug/L42.3 20 50.00 BRL 40-11685 2-Chlorophenol ug/L40.6 10 50.00 BRL 38-11781 2-Methylnaphthalene ug/L38.8 10 50.00 BRL 40-12178 2-Methylphenol ug/L42.0 10 50.00 BRL 30-11784 2-Nitroaniline ug/L50.7 10 50.00 BRL 55-127101 2-Nitrophenol ug/L47.9 10 50.00 BRL 47-12396 3,3’-Dichlorobenzidine ug/L58.7 10 50.00 BRL 27-129117 3/4-Methylphenol ug/L37.5 10 50.00 BRL 29-11075 3-Nitroaniline ug/L54.0 10 50.00 BRL 41-128108 4,6-Dinitro-2-methylphenol ug/L47.2 50 50.00 BRL J44-13794 4-Bromophenyl phenyl ether ug/L54.5 20 50.00 BRL 55-124109 4-Chloro-3-methylphenol ug/L51.7 10 50.00 BRL 52-119103 4-Chloroaniline ug/L46.4 10 50.00 BRL 33-11793 4-Chlorophenyl phenyl ether ug/L49.2 20 50.00 BRL 53-12198 4-Nitroaniline ug/L54.1 10 50.00 BRL 45-135108 4-Nitrophenol ug/L31.8 10 50.00 BRL 10-10564 Acenaphthene ug/L45.4 10 50.00 BRL 47-12291 Acenaphthylene ug/L48.4 20 50.00 BRL 41-13097 Acetophenone ug/L42.9 20 50.00 BRL 46-11886 Anthracene ug/L57.1 10 50.00 BRL 57-123114 Benzo(a)anthracene ug/L55.1 10 50.00 BRL 58-125110 Benzo(a)pyrene ug/L69.7 10 50.00 BRL M54-128139 Benzo(b)fluoranthene ug/L59.7 10 50.00 BRL 53-131119 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS Matrix Spike (P1A0497-MS1)Prepared: 01/07/21 Analyzed: 01/08/21 Source: 1010111-01 Benzo(g,h,i)perylene ug/L58.3 10 50.00 BRL 50-134117 Benzo(k)fluoranthene ug/L57.1 10 50.00 BRL 57-129114 bis(2-Chloroethoxy)methane ug/L44.6 10 50.00 BRL 48-12089 Bis(2-Chloroethyl)ether ug/L42.5 10 50.00 BRL 43-11885 Bis(2-chloroisopropyl)ether ug/L37.4 10 50.00 BRL 37-13075 Bis(2-Ethylhexyl)phthalate ug/L65.1 10 50.00 BRL 55-135130 Butyl benzyl phthalate ug/L55.7 10 50.00 BRL 53-134111 Carbazole ug/L56.2 20 50.00 BRL 60-122112 Chrysene ug/L53.7 10 50.00 BRL 59-123107 Dibenzo(a,h)anthracene ug/L40.5 20 50.00 BRL 51-13481 Dibenzofuran ug/L48.5 20 50.00 BRL 53-11897 Diethyl phthalate ug/L52.5 20 50.00 BRL 56-125105 Dimethyl phthalate ug/L52.6 10 50.00 BRL 45-127105 Di-n-butyl phthalate ug/L61.7 10 50.00 BRL 59-127123 Di-n-octyl phthalate ug/L61.2 10 50.00 BRL 51-140122 Fluoranthene ug/L57.1 10 50.00 BRL 57-128114 Fluorene ug/L51.2 10 50.00 BRL 52-124102 Hexachlorobenzene ug/L55.3 20 50.00 BRL 53-125111 Hexachlorobutadiene ug/L38.1 20 50.00 BRL 22-12476 Hexachlorocyclopentadiene ug/L31.4 20 50.00 BRL 26-12263 Hexachloroethane ug/L31.1 10 50.00 BRL 21-11562 Indeno(1,2,3-cd)pyrene ug/L56.4 10 50.00 BRL 52-134113 Isophorone ug/L38.7 10 50.00 BRL 42-12477 Naphthalene ug/L38.8 10 50.00 BRL 40-12178 Nitrobenzene ug/L41.6 10 50.00 BRL 45-12183 N-Nitroso-di-n-propylamine ug/L44.8 20 50.00 BRL 49-11990 N-Nitrosodiphenylamine ug/L60.4 20 50.00 BRL 51-123121 Pentachlorophenol ug/L58.0 50 50.00 BRL 35-138116 Phenanthrene ug/L52.8 10 50.00 BRL 59-120106 Phenol ug/L27.3 10 50.00 BRL 10-6855 Pyrene ug/L58.4 10 50.00 BRL 57-126117 ug/L 100.0 43-140Surrogate: 2,4,6-Tribromophenol 123123 ug/L 50.00 44-119Surrogate: 2-Fluorobiphenyl 8944.6 ug/L 100.0 19-119Surrogate: 2-Fluorophenol 6161.4 ug/L 50.00 44-120Surrogate: Nitrobenzene-d5 8140.3 ug/L 100.0 11-52Surrogate: Phenol-d5 5049.9 ug/L 50.00 50-134Surrogate: Terphenyl-d14 9447.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS Matrix Spike Dup (P1A0497-MSD1)Prepared: 01/07/21 Analyzed: 01/08/21 Source: 1010111-01 2,4,5-Trichlorophenol ug/L49.7 20 50.00 BRL 5053-12399 5 2,4,6-Trichlorophenol ug/L46.7 20 50.00 BRL 5050-12593 6 2,4-Dichlorophenol ug/L43.9 10 50.00 BRL 5047-12188 7 2,4-Dimethylphenol ug/L46.5 10 50.00 BRL 5031-12493 7 2,4-Dinitrophenol ug/L35.4 50 50.00 BRL 50 J23-14371 17 2,4-Dinitrotoluene ug/L55.1 10 50.00 BRL 5057-128110 6 2,6-Dinitrotoluene ug/L51.3 20 50.00 BRL 5057-124103 6 2-Chloronaphthalene ug/L41.2 20 50.00 BRL 5040-11682 3 2-Chlorophenol ug/L37.0 10 50.00 BRL 5038-11774 9 2-Methylnaphthalene ug/L37.0 10 50.00 BRL 5040-12174 5 2-Methylphenol ug/L37.8 10 50.00 BRL 5030-11776 11 2-Nitroaniline ug/L47.8 10 50.00 BRL 5055-12796 6 2-Nitrophenol ug/L43.1 10 50.00 BRL 5047-12386 11 3,3’-Dichlorobenzidine ug/L54.2 10 50.00 BRL 5027-129108 8 3/4-Methylphenol ug/L36.0 10 50.00 BRL 5029-11072 4 3-Nitroaniline ug/L50.0 10 50.00 BRL 5041-128100 8 4,6-Dinitro-2-methylphenol ug/L44.3 50 50.00 BRL 50 J44-13789 6 4-Bromophenyl phenyl ether ug/L52.6 20 50.00 BRL 5055-124105 3 4-Chloro-3-methylphenol ug/L47.6 10 50.00 BRL 5052-11995 8 4-Chloroaniline ug/L37.5 10 50.00 BRL 5033-11775 21 4-Chlorophenyl phenyl ether ug/L46.5 20 50.00 BRL 5053-12193 6 4-Nitroaniline ug/L50.1 10 50.00 BRL 5045-135100 8 4-Nitrophenol ug/L32.3 10 50.00 BRL 5010-10565 2 Acenaphthene ug/L43.2 10 50.00 BRL 5047-12286 5 Acenaphthylene ug/L46.4 20 50.00 BRL 5041-13093 4 Acetophenone ug/L39.6 20 50.00 BRL 5046-11879 8 Anthracene ug/L53.7 10 50.00 BRL 5057-123107 6 Benzo(a)anthracene ug/L49.9 10 50.00 BRL 5058-125100 10 Benzo(a)pyrene ug/L64.6 10 50.00 BRL 50 M54-128129 8 Benzo(b)fluoranthene ug/L55.2 10 50.00 BRL 5053-131110 8 Benzo(g,h,i)perylene ug/L54.6 10 50.00 BRL 5050-134109 7 Benzo(k)fluoranthene ug/L52.3 10 50.00 BRL 5057-129105 9 bis(2-Chloroethoxy)methane ug/L41.4 10 50.00 BRL 5048-12083 8 Bis(2-Chloroethyl)ether ug/L38.6 10 50.00 BRL 5043-11877 10 Bis(2-chloroisopropyl)ether ug/L34.0 10 50.00 BRL 5037-13068 9 Bis(2-Ethylhexyl)phthalate ug/L57.8 10 50.00 BRL 5055-135116 12 Butyl benzyl phthalate ug/L52.2 10 50.00 BRL 5053-134104 6 Carbazole ug/L52.3 20 50.00 BRL 5060-122105 7 Chrysene ug/L48.5 10 50.00 BRL 5059-12397 10 Dibenzo(a,h)anthracene ug/L37.0 20 50.00 BRL 5051-13474 9 Dibenzofuran ug/L46.4 20 50.00 BRL 5053-11893 4 Diethyl phthalate ug/L48.6 20 50.00 BRL 5056-12597 8 Dimethyl phthalate ug/L49.6 10 50.00 BRL 5045-12799 6 Di-n-butyl phthalate ug/L56.5 10 50.00 BRL 5059-127113 9 Di-n-octyl phthalate ug/L57.1 10 50.00 BRL 5051-140114 7 Fluoranthene ug/L52.6 10 50.00 BRL 5057-128105 8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P1A0497 - 3510C MS Matrix Spike Dup (P1A0497-MSD1)Prepared: 01/07/21 Analyzed: 01/08/21 Source: 1010111-01 Fluorene ug/L48.5 10 50.00 BRL 5052-12497 5 Hexachlorobenzene ug/L53.1 20 50.00 BRL 5053-125106 4 Hexachlorobutadiene ug/L35.6 20 50.00 BRL 5022-12471 7 Hexachlorocyclopentadiene ug/L28.5 20 50.00 BRL 5026-12257 10 Hexachloroethane ug/L28.4 10 50.00 BRL 5021-11557 9 Indeno(1,2,3-cd)pyrene ug/L52.1 10 50.00 BRL 5052-134104 8 Isophorone ug/L35.4 10 50.00 BRL 5042-12471 9 Naphthalene ug/L35.7 10 50.00 BRL 5040-12171 8 Nitrobenzene ug/L38.2 10 50.00 BRL 5045-12176 8 N-Nitroso-di-n-propylamine ug/L42.0 20 50.00 BRL 5049-11984 6 N-Nitrosodiphenylamine ug/L57.9 20 50.00 BRL 5051-123116 4 Pentachlorophenol ug/L51.7 50 50.00 BRL 5035-138103 11 Phenanthrene ug/L50.0 10 50.00 BRL 5059-120100 5 Phenol ug/L27.4 10 50.00 BRL 5010-6855 0.4 Pyrene ug/L53.1 10 50.00 BRL 5057-126106 10 ug/L 100.0 43-140Surrogate: 2,4,6-Tribromophenol 110110 ug/L 50.00 44-119Surrogate: 2-Fluorobiphenyl 8241.0 ug/L 100.0 19-119Surrogate: 2-Fluorophenol 5958.9 ug/L 50.00 44-120Surrogate: Nitrobenzene-d5 7436.8 ug/L 100.0 SR11-52Surrogate: Phenol-d5 5453.9 ug/L 50.00 50-134Surrogate: Terphenyl-d14 8441.9 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Total Metals - Quality Control Batch P1A0499 - 3005A Blank (P1A0499-BLK1)Prepared: 01/07/21 Analyzed: 01/12/21 Arsenic ug/LBRL1.0 Barium ug/LBRL2.0 Cadmium ug/LBRL1.0 Chromium ug/LBRL2.0 Lead ug/LBRL1.0 Selenium ug/LBRL5.0 Silver ug/LBRL1.0 LCS (P1A0499-BS1)Prepared: 01/07/21 Analyzed: 01/12/21 Arsenic ug/L92.9 1.0 100.0 80-12093 Barium ug/L96.1 2.0 100.0 80-12096 Cadmium ug/L96.4 1.0 100.0 80-12096 Chromium ug/L1022.0 100.0 80-120102 Lead ug/L1001.0 100.0 80-120100 Selenium ug/L95.5 5.0 100.0 80-12095 Silver ug/L97.8 1.0 100.0 80-12098 Matrix Spike (P1A0499-MS1)Prepared: 01/07/21 Analyzed: 01/12/21 Source: 1010111-02 Arsenic ug/L93.5 1.0 100.0 0.547 75-12593 Barium ug/L2602.0 100.0 162 75-12599 Cadmium ug/L1011.0 100.0 BRL 75-125101 Chromium ug/L1012.0 100.0 1.99 75-12599 Lead ug/L1011.0 100.0 0.670 75-125100 Selenium ug/L93.9 5.0 100.0 BRL 75-12594 Silver ug/L1011.0 100.0 BRL 75-125101 Matrix Spike Dup (P1A0499-MSD1)Prepared: 01/07/21 Analyzed: 01/12/21 Source: 1010111-02 Arsenic ug/L93.9 1.0 100.0 0.547 2075-12593 0.4 Barium ug/L2592.0 100.0 162 2075-12597 0.4 Cadmium ug/L1011.0 100.0 BRL 2075-125101 0.3 Chromium ug/L1032.0 100.0 1.99 2075-125101 2 Lead ug/L1011.0 100.0 0.670 2075-125100 0.2 Selenium ug/L94.7 5.0 100.0 BRL 2075-12595 0.9 Silver ug/L1001.0 100.0 BRL 2075-125100 0.7 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 45 1/15/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010111 Time Submitted: 1/6/2021 11:52:00AM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Total Metals - Quality Control Batch P1A0499 - 3005A Post Spike (P1A0499-PS1)Prepared: 01/07/21 Analyzed: 01/12/21 Source: 1010111-02 Arsenic ug/L90.6 100.0 0.547 80-12090 Barium ug/L248 100.0 162 80-12086 Cadmium ug/L96.6 100.0 0.0550 80-12097 Chromium ug/L101 100.0 1.99 80-12099 Lead ug/L96.4 100.0 0.670 80-12096 Selenium ug/L94.1 100.0 -0.00800 80-12094 Silver ug/L91.6 100.0 0.0400 80-12092 Batch P1A0514 - 7470A Blank (P1A0514-BLK1)Prepared & Analyzed: 01/08/21 Mercury mg/LBRL0.00020 LCS (P1A0514-BS1)Prepared & Analyzed: 01/08/21 Mercury mg/L0.00925 0.00020 0.009375 80-12099 Matrix Spike (P1A0514-MS1)Prepared & Analyzed: 01/08/21 Source: 1010111-06 Mercury mg/L0.00881 0.00020 0.009375 0.0000378 80-12094 Matrix Spike Dup (P1A0514-MSD1)Prepared & Analyzed: 01/08/21 Source: 1010111-06 Mercury mg/L0.00874 0.00020 0.009375 0.0000378 2080-12093 0.7 Post Spike (P1A0514-PS1)Prepared & Analyzed: 01/08/21 Source: 1010111-06 Mercury ug/L4.75 5.000 0.0352 85-11594 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 45 Sample Extraction Data Prep Method: 3510C MS Lab Number Batch Date/TimeInitialFinal P1A04971010111-01 01/07/21 8:309601mL mL P1A04971010111-02 01/07/21 8:309501mL mL P1A04971010111-03 01/07/21 8:309501mL mL P1A04971010111-04 01/07/21 8:309501mL mL P1A04971010111-05 01/07/21 8:309601mL mL P1A04971010111-06 01/07/21 8:301000 1mL mL Prep Method: 3005A Lab Number Batch Date/TimeInitialFinal P1A04991010111-01 01/07/21 8:1050 50mL mL P1A04991010111-02 01/07/21 8:1050 50mL mL P1A04991010111-03 01/07/21 8:1050 50mL mL P1A04991010111-04 01/07/21 8:1050 50mL mL P1A04991010111-05 01/07/21 8:1050 50mL mL P1A04991010111-06 01/07/21 8:1050 50mL mL P1A04991010111-07 01/07/21 8:1050 50mL mL P1A04991010111-08 01/07/21 8:1050 50mL mL Prep Method: 7470A Lab Number Batch Date/TimeInitialFinal P1A05141010111-01 01/08/21 10:5320 30mL mL P1A05141010111-02 01/08/21 10:5320 30mL mL P1A05141010111-03 01/08/21 10:5320 30mL mL P1A05141010111-04 01/08/21 10:5320 30mL mL P1A05141010111-05 01/08/21 10:5320 30mL mL P1A05141010111-06 01/08/21 10:5320 30mL mL P1A05141010111-07 01/08/21 10:5320 30mL mL P1A05141010111-08 01/08/21 10:5320 30mL mL Prep Method: SM6200 B Lab Number Batch Date/TimeInitialFinal P1A05401010111-01 01/08/21 10:0010 10mL mL P1A05401010111-02 01/08/21 10:0010 10mL mL P1A05401010111-03 01/08/21 10:0010 10mL mL P1A05401010111-04 01/08/21 10:0010 10mL mL P1A05401010111-05 01/08/21 10:0010 10mL mL P1A05401010111-06 01/08/21 10:0010 10mL mL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 45 Page 45 of 45 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Case Narrative 1/4/21 14:00 Hart & Hickman (Charlotte) Matt Ingalls 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PRO-011 Lab Submittal Date: 12/23/2020 Work Order: 0120388 Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL Senior Project Manager Angela D. Overcash Data Qualifiers Key Reference: A ECCV failed low. Samples were re-analyzed with confirming results. Initial data reported. Aa Surrogate failed low. Sample was re-prepped with confirming results. Sample matrix suspected. Initial data reported. CCVH CCV result is above control limits but within method parameters. Result is considered estimated. D RPD value outside of the control limits. M Matrix spike outside of the control limits. Method Detection LimitMDL Below Reporting LimitBRL Relative Percent DifferenceRPD *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 55 Sample Receipt Summary 01/04/2021 Work Order: 0120388 Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received 0120388-01 12/22/20 15:30SB-1 (0.5-1.5)12/23/20 12:38Solid 0120388-02 12/22/20 11:15SB-2 (10-12)12/23/20 12:38Solid 0120388-03 12/22/20 16:30SB-3 (1-2)12/23/20 12:38Solid 0120388-04 12/22/20 16:00SB-4 (10-12)12/23/20 12:38Solid 0120388-05 12/22/20 14:00SB-5 (0.5-1.5)12/23/20 12:38Solid 0120388-06 12/22/20 0:00Dup 12/23/20 12:38Solid 0120388-07 12/22/20 0:00Trip Blank 12/23/20 12:38Water Samples were received in good condition at 3.9 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 55 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 0120388 01/04/2021 Summary of Detections 1.4 mg/kg dry0120388-01 SB-1 (0.5-1.5)Arsenic *6020B 21 mg/kg dry0120388-01 SB-1 (0.5-1.5)Barium *6020B 26 mg/kg dry0120388-01 SB-1 (0.5-1.5)Chromium *6020B 11 mg/kg dry0120388-01 SB-1 (0.5-1.5)Lead *6020B 1.4 mg/kg dry0120388-01 SB-1 (0.5-1.5)Selenium *6020B 0.67 mg/kg dry0120388-02 SB-2 (10-12)Hexavalent Chromium *7196A 1.2 mg/kg dry0120388-02 SB-2 (10-12)Arsenic *6020B 45 mg/kg dry0120388-02 SB-2 (10-12)Barium *6020B 23 mg/kg dry0120388-02 SB-2 (10-12)Chromium *6020B 7.1 mg/kg dry0120388-02 SB-2 (10-12)Lead *6020B 0.031 CCVH mg/kg dry0120388-02 SB-2 (10-12)Acetone *8260D 1.7 mg/kg dry0120388-03 SB-3 (1-2)Hexavalent Chromium *7196A 11 mg/kg dry0120388-03 SB-3 (1-2)Arsenic *6020B 170 mg/kg dry0120388-03 SB-3 (1-2)Barium *6020B 53 mg/kg dry0120388-03 SB-3 (1-2)Chromium *6020B 78 mg/kg dry0120388-03 SB-3 (1-2)Lead *6020B 2.3 mg/kg dry0120388-03 SB-3 (1-2)Selenium *6020B 1.7 mg/kg dry0120388-04 SB-4 (10-12)Arsenic *6020B 160 mg/kg dry0120388-04 SB-4 (10-12)Barium *6020B 140 mg/kg dry0120388-04 SB-4 (10-12)Chromium *6020B 10 mg/kg dry0120388-04 SB-4 (10-12)Lead *6020B 3.3 mg/kg dry0120388-04 SB-4 (10-12)Selenium *6020B 0.035 CCVH mg/kg dry0120388-04 SB-4 (10-12)Acetone *8260D 0.0075 mg/kg dry0120388-04 SB-4 (10-12)Methylene Chloride *8260D 1.7 mg/kg dry0120388-05 SB-5 (0.5-1.5)Arsenic *6020B 50 mg/kg dry0120388-05 SB-5 (0.5-1.5)Barium *6020B 57 mg/kg dry0120388-05 SB-5 (0.5-1.5)Chromium *6020B 13 mg/kg dry0120388-05 SB-5 (0.5-1.5)Lead *6020B 1.7 mg/kg dry0120388-05 SB-5 (0.5-1.5)Selenium *6020B 31 mg/kg dry0120388-06 Dup Barium *6020B 22 mg/kg dry0120388-06 Dup Chromium *6020B 11 mg/kg dry0120388-06 Dup Lead *6020B 1.3 mg/kg dry0120388-06 Dup Selenium *6020B 0.94 mg/kg dry0120388-06 Dup Silver *6020B This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-1 (0.5-1.5) Sample ID: 0120388-01 Work Order: 0120388 Time Collected: 12/22/20 15:30 Time Submitted: 12/23/20 12:38 General Chemistry Parameters *SM2540 G P0L051010.100 12/28/20 14:25 SLS% by Weight 0.100% Solids 76.9 Organochlorine Pesticides by GC/ECD *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.00254,4’-DDD BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.00274,4’-DDE BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.00204,4’-DDT BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0024AldrinBRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0016alpha-BHC BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0025cis-Chlordane BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0026beta-BHC BRL *8081B P0L049310.066 12/28/20 13:43 NMBmg/kg dry 0.013ChlordaneBRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0016delta-BHC BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0028DieldrinBRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0024Endosulfan I BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.0023Endosulfan II BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.0024Endosulfan Sulfate BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.0025EndrinBRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.0028Endrin Aldehyde BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.0024Endrin Ketone BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0017gamma-BHC BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0022trans-Chlordane BRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0018HeptachlorBRL *8081B P0L049310.0066 12/28/20 13:43 NMBmg/kg dry 0.0024Heptachlor Epoxide BRL *8081B P0L049310.0066 12/28/20 13:43 NMBAmg/kg dry 0.0035MethoxychlorBRL *8081B P0L049310.066 12/28/20 13:43 NMBAmg/kg dry 0.013ToxapheneBRL Surrogate Recovery Control Limits 26-20434 %Decachlorobiphenyl 40-16298 %Tetrachloro-m-xylene Semivolatile Organic Compounds by GC/MS *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.121,1’-Biphenyl BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.262,3,4,6-Tetrachlorophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.182,4,5-Trichlorophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.212,4,6-Trichlorophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.172,4-Dichlorophenol BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.182,4-Dimethylphenol BRL *8270E P0L050912.0 12/30/20 0:29 JMVmg/kg dry 0.512,4-Dinitrophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.232,4-Dinitrotoluene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.232,6-Dinitrotoluene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.212-Chloronaphthalene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.172-Chlorophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0172-Methylnaphthalene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.172-Methylphenol BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-1 (0.5-1.5) Sample ID: 0120388-01 Work Order: 0120388 Time Collected: 12/22/20 15:30 Time Submitted: 12/23/20 12:38 *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.192-Nitroaniline BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.152-Nitrophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.173,3’-Dichlorobenzidine BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.193/4-Methylphenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.163-Nitroaniline BRL *8270E P0L050912.0 12/30/20 0:29 JMVmg/kg dry 0.484,6-Dinitro-2-methylphenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.204-Bromophenyl phenyl ether BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.174-Chloro-3-methylphenol BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.114-Chloroaniline BRL *8270E P0L050911.3 12/30/20 0:29 JMVmg/kg dry 0.274-Chlorophenyl phenyl ether BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.144-Nitroaniline BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.224-Nitrophenol BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.020AcenaphtheneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.017AcenaphthyleneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.21AcetophenoneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0096AnthraceneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.11AtrazineBRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.076BenzaldehydeBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.010Benzo(a)anthracene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0078Benzo(a)pyrene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0080Benzo(b)fluoranthene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0086Benzo(g,h,i)perylene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0092Benzo(k)fluoranthene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.17bis(2-Chloroethoxy)methane BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.14Bis(2-Chloroethyl)ether BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.16Bis(2-chloroisopropyl)ether BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.20Bis(2-Ethylhexyl)phthalate BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.15Butyl benzyl phthalate BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.16CaprolactamBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.20CarbazoleBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.010ChryseneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.025Dibenzo(a,h)anthracene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.23DibenzofuranBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.22Diethyl phthalate BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.21Dimethyl phthalate BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.22Di-n-butyl phthalate BRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.23Di-n-octyl phthalate BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0099FluorantheneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.015FluoreneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.19HexachlorobenzeneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.20HexachlorobutadieneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.30HexachlorocyclopentadieneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.14HexachloroethaneBRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-1 (0.5-1.5) Sample ID: 0120388-01 Work Order: 0120388 Time Collected: 12/22/20 15:30 Time Submitted: 12/23/20 12:38 *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.025Indeno(1,2,3-cd)pyrene BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.19IsophoroneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.018NaphthaleneBRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.18NitrobenzeneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.20N-Nitroso-di-n-propylamine BRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.24N-Nitrosodiphenylamine BRL *8270E P0L050911.3 12/30/20 0:29 JMVmg/kg dry 0.56PentachlorophenolBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.0095PhenanthreneBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.14PhenolBRL *8270E P0L050910.87 12/30/20 0:29 JMVmg/kg dry 0.013PyreneBRL *8270E P0L050910.44 12/30/20 0:29 JMVmg/kg dry 0.083PyridineBRL Surrogate Recovery Control Limits 37-131102 %2,4,6-Tribromophenol 47-13087 %2-Fluorobiphenyl 44-11784 %2-Fluorophenol 45-12173 %Nitrobenzene-d5 37-12782 %Phenol-d5 38-13590 %Terphenyl-d14 Total Metals *7196A P0L050610.52 12/29/20 12:18 BMSmg/kg dry 0.20Hexavalent Chromium BRL *7471B P0L057110.065 12/31/20 13:57 EDVmg/kg dry 0.020MercuryBRL *6020B P0L0565101.3 12/31/20 16:56 JABmg/kg dry 0.11Arsenic1.4 *6020B P0L0565101312/31/20 16:56 JABmg/kg dry 0.47Barium21 *6020B P0L0565100.65 12/31/20 16:56 JABmg/kg dry 0.048CadmiumBRL *6020B P0L0565101.3 12/31/20 16:56 JABmg/kg dry 0.31Chromium26 *6020B P0L0565101.3 12/31/20 16:56 JABmg/kg dry 0.099Lead11 *6020B P0L0565101.3 12/31/20 16:56 JABmg/kg dry 0.30Selenium1.4 *6020B P0L0565100.65 12/31/20 16:56 JABmg/kg dry 0.066SilverBRL Volatile Organic Compounds by GC/MS *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000621,1,1-Trichloroethane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000311,1,2,2-Tetrachloroethane BRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.000741,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000461,1,2-Trichloroethane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000761,1-Dichloroethane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000771,1-Dichloroethylene BRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.000601,2,3-Trichlorobenzene BRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.000401,2,4-Trichlorobenzene BRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.000531,2-Dibromo-3-chloropropane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000381,2-Dibromoethane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000471,2-Dichlorobenzene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000501,2-Dichloroethane BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000631,2-Dichloropropane BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-1 (0.5-1.5) Sample ID: 0120388-01 Work Order: 0120388 Time Collected: 12/22/20 15:30 Time Submitted: 12/23/20 12:38 *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000521,3-Dichlorobenzene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.000531,4-Dichlorobenzene BRL *8260D P0L052210.084 12/29/20 16:21 JLBmg/kg dry 0.0121,4-Dioxane BRL *8260D P0L052210.017 12/29/20 16:21 JLBCCVHmg/kg dry 0.0011AcetoneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00066BenzeneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00069BromochloromethaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00040BromodichloromethaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00033BromoformBRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.0021BromomethaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00072Carbon disulfide BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00083Carbon Tetrachloride BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00066ChlorobenzeneBRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.00080ChloroethaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00052ChloroformBRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.0013ChloromethaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00066cis-1,2-Dichloroethylene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00042cis-1,3-Dichloropropylene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00051CyclohexaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00028DibromochloromethaneBRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.0012DichlorodifluoromethaneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00063EthylbenzeneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00049Isopropylbenzene (Cumene)BRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.0011m,p-Xylenes BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00039Methyl Acetate BRL *8260D P0L052210.017 12/29/20 16:21 JLBmg/kg dry 0.00029Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00025MethylcyclohexaneBRL *8260D P0L052210.017 12/29/20 16:21 JLBCCVHmg/kg dry 0.00099Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L052210.017 12/29/20 16:21 JLBmg/kg dry 0.00034Methyl Isobutyl Ketone BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00068Methylene Chloride BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00059Methyl-tert-Butyl Ether BRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.00043NaphthaleneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00045o-Xylene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00041StyreneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00076TetrachloroethyleneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00067TolueneBRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00081trans-1,2-Dichloroethylene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00036trans-1,3-Dichloropropylene BRL *8260D P0L052210.0042 12/29/20 16:21 JLBmg/kg dry 0.00082TrichloroethyleneBRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.0011TrichlorofluoromethaneBRL *8260D P0L052210.0084 12/29/20 16:21 JLBmg/kg dry 0.00083Vinyl chloride BRL *8260D P0L052210.013 12/29/20 16:21 JLBmg/kg dry 0.0015Xylenes, total BRL Surrogate Recovery Control Limits 70-130107 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-1 (0.5-1.5) Sample ID: 0120388-01 Work Order: 0120388 Time Collected: 12/22/20 15:30 Time Submitted: 12/23/20 12:38 84-123109 %Dibromofluoromethane 76-129101 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-2 (10-12) Sample ID: 0120388-02 Work Order: 0120388 Time Collected: 12/22/20 11:15 Time Submitted: 12/23/20 12:38 General Chemistry Parameters *SM2540 G P0L055910.100 12/31/20 10:50 EDV% by Weight 0.100% Solids 80.8 Organochlorine Pesticides by GC/ECD *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.00244,4’-DDD BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.00264,4’-DDE BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.00194,4’-DDT BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0023AldrinBRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0015alpha-BHC BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0023cis-Chlordane BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0025beta-BHC BRL *8081B P0L049310.063 12/28/20 13:55 NMBmg/kg dry 0.012ChlordaneBRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0016delta-BHC BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0026DieldrinBRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0022Endosulfan I BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.0022Endosulfan II BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.0023Endosulfan Sulfate BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.0024EndrinBRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.0027Endrin Aldehyde BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.0023Endrin Ketone BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0016gamma-BHC BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0021trans-Chlordane BRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0017HeptachlorBRL *8081B P0L049310.0063 12/28/20 13:55 NMBmg/kg dry 0.0022Heptachlor Epoxide BRL *8081B P0L049310.0063 12/28/20 13:55 NMBAmg/kg dry 0.0033MethoxychlorBRL *8081B P0L049310.063 12/28/20 13:55 NMBAmg/kg dry 0.013ToxapheneBRL Surrogate Recovery Control Limits 26-20436 %Decachlorobiphenyl 40-162104 %Tetrachloro-m-xylene Semivolatile Organic Compounds by GC/MS *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.111,1’-Biphenyl BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.242,3,4,6-Tetrachlorophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.182,4,5-Trichlorophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.202,4,6-Trichlorophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.162,4-Dichlorophenol BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.172,4-Dimethylphenol BRL *8270E P0L050911.9 12/29/20 21:06 JMVmg/kg dry 0.492,4-Dinitrophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.222,4-Dinitrotoluene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.212,6-Dinitrotoluene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.202-Chloronaphthalene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.162-Chlorophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0162-Methylnaphthalene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.162-Methylphenol BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-2 (10-12) Sample ID: 0120388-02 Work Order: 0120388 Time Collected: 12/22/20 11:15 Time Submitted: 12/23/20 12:38 *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.182-Nitroaniline BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.142-Nitrophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.163,3’-Dichlorobenzidine BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.183/4-Methylphenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.163-Nitroaniline BRL *8270E P0L050911.9 12/29/20 21:06 JMVmg/kg dry 0.464,6-Dinitro-2-methylphenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.194-Bromophenyl phenyl ether BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.164-Chloro-3-methylphenol BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.104-Chloroaniline BRL *8270E P0L050911.3 12/29/20 21:06 JMVmg/kg dry 0.254-Chlorophenyl phenyl ether BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.134-Nitroaniline BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.204-Nitrophenol BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.019AcenaphtheneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.016AcenaphthyleneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.20AcetophenoneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0092AnthraceneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.10AtrazineBRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.072BenzaldehydeBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0099Benzo(a)anthracene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0074Benzo(a)pyrene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0077Benzo(b)fluoranthene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0082Benzo(g,h,i)perylene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0088Benzo(k)fluoranthene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.16bis(2-Chloroethoxy)methane BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.13Bis(2-Chloroethyl)ether BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.15Bis(2-chloroisopropyl)ether BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.19Bis(2-Ethylhexyl)phthalate BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.14Butyl benzyl phthalate BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.15CaprolactamBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.19CarbazoleBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0098ChryseneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.024Dibenzo(a,h)anthracene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.22DibenzofuranBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.21Diethyl phthalate BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.20Dimethyl phthalate BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.21Di-n-butyl phthalate BRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.21Di-n-octyl phthalate BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0094FluorantheneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.014FluoreneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.18HexachlorobenzeneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.19HexachlorobutadieneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.28HexachlorocyclopentadieneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.13HexachloroethaneBRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-2 (10-12) Sample ID: 0120388-02 Work Order: 0120388 Time Collected: 12/22/20 11:15 Time Submitted: 12/23/20 12:38 *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.023Indeno(1,2,3-cd)pyrene BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.18IsophoroneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.018NaphthaleneBRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.18NitrobenzeneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.19N-Nitroso-di-n-propylamine BRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.23N-Nitrosodiphenylamine BRL *8270E P0L050911.3 12/29/20 21:06 JMVmg/kg dry 0.53PentachlorophenolBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.0090PhenanthreneBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.14PhenolBRL *8270E P0L050910.83 12/29/20 21:06 JMVmg/kg dry 0.012PyreneBRL *8270E P0L050910.41 12/29/20 21:06 JMVmg/kg dry 0.079PyridineBRL Surrogate Recovery Control Limits 37-13194 %2,4,6-Tribromophenol 47-13082 %2-Fluorobiphenyl 44-11781 %2-Fluorophenol 45-12170 %Nitrobenzene-d5 37-12778 %Phenol-d5 38-13585 %Terphenyl-d14 Total Metals *7196A P0L050610.49 12/29/20 12:18 BMSmg/kg dry 0.19Hexavalent Chromium 0.67 *7471B P0L057110.062 12/31/20 14:11 EDVmg/kg dry 0.019MercuryBRL *6020B P0L0565101.2 12/31/20 16:37 JABmg/kg dry 0.10Arsenic1.2 *6020B P0L0565101212/31/20 16:37 JABmg/kg dry 0.45Barium45 *6020B P0L0565100.62 12/31/20 16:37 JABmg/kg dry 0.046CadmiumBRL *6020B P0L0565101.2 12/31/20 16:37 JABmg/kg dry 0.30Chromium23 *6020B P0L0565101.2 12/31/20 16:37 JABmg/kg dry 0.094Lead7.1 *6020B P0L0565101.2 12/31/20 16:37 JABmg/kg dry 0.28SeleniumBRL *6020B P0L0565100.62 12/31/20 16:37 JABmg/kg dry 0.063SilverBRL Volatile Organic Compounds by GC/MS *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000911,1,1-Trichloroethane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000451,1,2,2-Tetrachloroethane BRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.00111,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000671,1,2-Trichloroethane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00111,1-Dichloroethane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00111,1-Dichloroethylene BRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.000891,2,3-Trichlorobenzene BRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.000591,2,4-Trichlorobenzene BRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.000781,2-Dibromo-3-chloropropane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000551,2-Dibromoethane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000691,2-Dichlorobenzene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000741,2-Dichloroethane BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000931,2-Dichloropropane BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-2 (10-12) Sample ID: 0120388-02 Work Order: 0120388 Time Collected: 12/22/20 11:15 Time Submitted: 12/23/20 12:38 *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000771,3-Dichlorobenzene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.000781,4-Dichlorobenzene BRL *8260D P0L052210.12 12/29/20 16:51 JLBmg/kg dry 0.0171,4-Dioxane BRL *8260D P0L052210.025 12/29/20 16:51 JLBCCVHmg/kg dry 0.0016Acetone0.031 *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00096BenzeneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0010BromochloromethaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00059BromodichloromethaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00048BromoformBRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0030BromomethaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0011Carbon disulfide BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0012Carbon Tetrachloride BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00097ChlorobenzeneBRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0012ChloroethaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00076ChloroformBRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0019ChloromethaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00097cis-1,2-Dichloroethylene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00061cis-1,3-Dichloropropylene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00075CyclohexaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00041DibromochloromethaneBRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0017DichlorodifluoromethaneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00093EthylbenzeneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00072Isopropylbenzene (Cumene)BRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0016m,p-Xylenes BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00057Methyl Acetate BRL *8260D P0L052210.025 12/29/20 16:51 JLBmg/kg dry 0.00043Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00036MethylcyclohexaneBRL *8260D P0L052210.025 12/29/20 16:51 JLBCCVHmg/kg dry 0.0014Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L052210.025 12/29/20 16:51 JLBmg/kg dry 0.00050Methyl Isobutyl Ketone BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0010Methylene Chloride BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00087Methyl-tert-Butyl Ether BRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.00062NaphthaleneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00066o-Xylene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00060StyreneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0011TetrachloroethyleneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00098TolueneBRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0012trans-1,2-Dichloroethylene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.00053trans-1,3-Dichloropropylene BRL *8260D P0L052210.0062 12/29/20 16:51 JLBmg/kg dry 0.0012TrichloroethyleneBRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0017TrichlorofluoromethaneBRL *8260D P0L052210.012 12/29/20 16:51 JLBmg/kg dry 0.0012Vinyl chloride BRL *8260D P0L052210.019 12/29/20 16:51 JLBmg/kg dry 0.0022Xylenes, total BRL Surrogate Recovery Control Limits 70-130109 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-2 (10-12) Sample ID: 0120388-02 Work Order: 0120388 Time Collected: 12/22/20 11:15 Time Submitted: 12/23/20 12:38 84-123108 %Dibromofluoromethane 76-12999 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-3 (1-2) Sample ID: 0120388-03 Work Order: 0120388 Time Collected: 12/22/20 16:30 Time Submitted: 12/23/20 12:38 General Chemistry Parameters *SM2540 G P0L055910.100 12/31/20 10:50 EDV% by Weight 0.100% Solids 81.2 Organochlorine Pesticides by GC/ECD *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.00234,4’-DDD BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.00254,4’-DDE BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.00194,4’-DDT BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0023AldrinBRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0014alpha-BHC BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0023cis-Chlordane BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0024beta-BHC BRL *8081B P0L049310.061 12/28/20 14:08 NMBmg/kg dry 0.012ChlordaneBRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0015delta-BHC BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0026DieldrinBRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0022Endosulfan I BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.0021Endosulfan II BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.0022Endosulfan Sulfate BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.0024EndrinBRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.0026Endrin Aldehyde BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.0023Endrin Ketone BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0015gamma-BHC BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0021trans-Chlordane BRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0017HeptachlorBRL *8081B P0L049310.0061 12/28/20 14:08 NMBmg/kg dry 0.0022Heptachlor Epoxide BRL *8081B P0L049310.0061 12/28/20 14:08 NMBAmg/kg dry 0.0032MethoxychlorBRL *8081B P0L049310.061 12/28/20 14:08 NMBAmg/kg dry 0.012ToxapheneBRL Surrogate Recovery Control Limits 26-20440 %Decachlorobiphenyl 40-16297 %Tetrachloro-m-xylene Semivolatile Organic Compounds by GC/MS *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.111,1’-Biphenyl BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.242,3,4,6-Tetrachlorophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.172,4,5-Trichlorophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.202,4,6-Trichlorophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.162,4-Dichlorophenol BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.172,4-Dimethylphenol BRL *8270E P0L050911.8 12/29/20 21:28 JMVmg/kg dry 0.472,4-Dinitrophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.212,4-Dinitrotoluene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.212,6-Dinitrotoluene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.202-Chloronaphthalene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.152-Chlorophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0162-Methylnaphthalene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.152-Methylphenol BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-3 (1-2) Sample ID: 0120388-03 Work Order: 0120388 Time Collected: 12/22/20 16:30 Time Submitted: 12/23/20 12:38 *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.172-Nitroaniline BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.132-Nitrophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.163,3’-Dichlorobenzidine BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.173/4-Methylphenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.153-Nitroaniline BRL *8270E P0L050911.8 12/29/20 21:28 JMVmg/kg dry 0.444,6-Dinitro-2-methylphenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.194-Bromophenyl phenyl ether BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.154-Chloro-3-methylphenol BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.0984-Chloroaniline BRL *8270E P0L050911.2 12/29/20 21:28 JMVmg/kg dry 0.254-Chlorophenyl phenyl ether BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.134-Nitroaniline BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.204-Nitrophenol BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.018AcenaphtheneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.016AcenaphthyleneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.20AcetophenoneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0089AnthraceneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.099AtrazineBRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.070BenzaldehydeBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0096Benzo(a)anthracene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0072Benzo(a)pyrene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0074Benzo(b)fluoranthene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0079Benzo(g,h,i)perylene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0085Benzo(k)fluoranthene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.15bis(2-Chloroethoxy)methane BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.13Bis(2-Chloroethyl)ether BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.14Bis(2-chloroisopropyl)ether BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.18Bis(2-Ethylhexyl)phthalate BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.14Butyl benzyl phthalate BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.15CaprolactamBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.19CarbazoleBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0095ChryseneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.023Dibenzo(a,h)anthracene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.22DibenzofuranBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.21Diethyl phthalate BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.19Dimethyl phthalate BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.20Di-n-butyl phthalate BRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.21Di-n-octyl phthalate BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0092FluorantheneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.014FluoreneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.18HexachlorobenzeneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.18HexachlorobutadieneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.28HexachlorocyclopentadieneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.13HexachloroethaneBRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-3 (1-2) Sample ID: 0120388-03 Work Order: 0120388 Time Collected: 12/22/20 16:30 Time Submitted: 12/23/20 12:38 *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.023Indeno(1,2,3-cd)pyrene BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.17IsophoroneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.017NaphthaleneBRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.17NitrobenzeneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.19N-Nitroso-di-n-propylamine BRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.22N-Nitrosodiphenylamine BRL *8270E P0L050911.2 12/29/20 21:28 JMVmg/kg dry 0.51PentachlorophenolBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.0088PhenanthreneBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.13PhenolBRL *8270E P0L050910.81 12/29/20 21:28 JMVmg/kg dry 0.012PyreneBRL *8270E P0L050910.40 12/29/20 21:28 JMVmg/kg dry 0.077PyridineBRL Surrogate Recovery Control Limits 37-13199 %2,4,6-Tribromophenol 47-13084 %2-Fluorobiphenyl 44-11783 %2-Fluorophenol 45-12176 %Nitrobenzene-d5 37-12782 %Phenol-d5 38-13589 %Terphenyl-d14 Total Metals *7196A P0L050610.49 12/29/20 12:18 BMSmg/kg dry 0.18Hexavalent Chromium 1.7 *7471B P0L057110.062 12/31/20 14:15 EDVmg/kg dry 0.018MercuryBRL *6020B P0L0565101.2 12/31/20 17:03 JABmg/kg dry 0.10Arsenic11 *6020B P0L0565101212/31/20 17:03 JABmg/kg dry 0.44Barium170 *6020B P0L0565100.62 12/31/20 17:03 JABmg/kg dry 0.046CadmiumBRL *6020B P0L0565101.2 12/31/20 17:03 JABmg/kg dry 0.30Chromium53 *6020B P0L0565101.2 12/31/20 17:03 JABmg/kg dry 0.094Lead78 *6020B P0L0565101.2 12/31/20 17:03 JABmg/kg dry 0.28Selenium2.3 *6020B P0L0565100.62 12/31/20 17:03 JABmg/kg dry 0.063SilverBRL Volatile Organic Compounds by GC/MS *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000631,1,1-Trichloroethane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000311,1,2,2-Tetrachloroethane BRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.000751,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000461,1,2-Trichloroethane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000771,1-Dichloroethane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000791,1-Dichloroethylene BRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.000611,2,3-Trichlorobenzene BRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.000411,2,4-Trichlorobenzene BRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.000541,2-Dibromo-3-chloropropane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000381,2-Dibromoethane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000481,2-Dichlorobenzene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000511,2-Dichloroethane BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000651,2-Dichloropropane BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-3 (1-2) Sample ID: 0120388-03 Work Order: 0120388 Time Collected: 12/22/20 16:30 Time Submitted: 12/23/20 12:38 *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000531,3-Dichlorobenzene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.000541,4-Dichlorobenzene BRL *8260D P0L052210.086 12/29/20 17:21 JLBmg/kg dry 0.0121,4-Dioxane BRL *8260D P0L052210.017 12/29/20 17:21 JLBCCVHmg/kg dry 0.0011AcetoneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00067BenzeneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00071BromochloromethaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00041BromodichloromethaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00033BromoformBRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.0021BromomethaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00074Carbon disulfide BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00084Carbon Tetrachloride BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00067ChlorobenzeneBRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.00082ChloroethaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00053ChloroformBRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.0013ChloromethaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00067cis-1,2-Dichloroethylene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00042cis-1,3-Dichloropropylene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00052CyclohexaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00029DibromochloromethaneBRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.0012DichlorodifluoromethaneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00065EthylbenzeneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00050Isopropylbenzene (Cumene)BRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.0011m,p-Xylenes BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00040Methyl Acetate BRL *8260D P0L052210.017 12/29/20 17:21 JLBmg/kg dry 0.00030Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00025MethylcyclohexaneBRL *8260D P0L052210.017 12/29/20 17:21 JLBCCVHmg/kg dry 0.0010Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L052210.017 12/29/20 17:21 JLBmg/kg dry 0.00035Methyl Isobutyl Ketone BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00069Methylene Chloride BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00060Methyl-tert-Butyl Ether BRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.00043NaphthaleneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00046o-Xylene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00042StyreneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00078TetrachloroethyleneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00068TolueneBRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00082trans-1,2-Dichloroethylene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00037trans-1,3-Dichloropropylene BRL *8260D P0L052210.0043 12/29/20 17:21 JLBmg/kg dry 0.00083TrichloroethyleneBRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.0012TrichlorofluoromethaneBRL *8260D P0L052210.0086 12/29/20 17:21 JLBmg/kg dry 0.00085Vinyl chloride BRL *8260D P0L052210.013 12/29/20 17:21 JLBmg/kg dry 0.0015Xylenes, total BRL Surrogate Recovery Control Limits 70-130110 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-3 (1-2) Sample ID: 0120388-03 Work Order: 0120388 Time Collected: 12/22/20 16:30 Time Submitted: 12/23/20 12:38 84-123106 %Dibromofluoromethane 76-129100 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-4 (10-12) Sample ID: 0120388-04 Work Order: 0120388 Time Collected: 12/22/20 16:00 Time Submitted: 12/23/20 12:38 General Chemistry Parameters *SM2540 G P0L055910.100 12/31/20 10:50 EDV% by Weight 0.100% Solids 82.4 Organochlorine Pesticides by GC/ECD *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.00234,4’-DDD BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.00254,4’-DDE BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.00194,4’-DDT BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0023AldrinBRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0014alpha-BHC BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0023cis-Chlordane BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0024beta-BHC BRL *8081B P0L049310.061 12/28/20 14:20 NMBmg/kg dry 0.012ChlordaneBRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0015delta-BHC BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0026DieldrinBRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0022Endosulfan I BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.0021Endosulfan II BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.0022Endosulfan Sulfate BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.0024EndrinBRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.0026Endrin Aldehyde BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.0023Endrin Ketone BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0015gamma-BHC BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0021trans-Chlordane BRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0017HeptachlorBRL *8081B P0L049310.0061 12/28/20 14:20 NMBmg/kg dry 0.0022Heptachlor Epoxide BRL *8081B P0L049310.0061 12/28/20 14:20 NMBAmg/kg dry 0.0032MethoxychlorBRL *8081B P0L049310.061 12/28/20 14:20 NMBAmg/kg dry 0.012ToxapheneBRL Surrogate Recovery Control Limits 26-20431 %Decachlorobiphenyl 40-16297 %Tetrachloro-m-xylene Semivolatile Organic Compounds by GC/MS *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.111,1’-Biphenyl BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.242,3,4,6-Tetrachlorophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.172,4,5-Trichlorophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.192,4,6-Trichlorophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.162,4-Dichlorophenol BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.172,4-Dimethylphenol BRL *8270E P0L050911.8 12/29/20 21:51 JMVmg/kg dry 0.472,4-Dinitrophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.212,4-Dinitrotoluene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.212,6-Dinitrotoluene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.202-Chloronaphthalene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.152-Chlorophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0162-Methylnaphthalene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.152-Methylphenol BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-4 (10-12) Sample ID: 0120388-04 Work Order: 0120388 Time Collected: 12/22/20 16:00 Time Submitted: 12/23/20 12:38 *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.172-Nitroaniline BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.132-Nitrophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.163,3’-Dichlorobenzidine BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.173/4-Methylphenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.153-Nitroaniline BRL *8270E P0L050911.8 12/29/20 21:51 JMVmg/kg dry 0.444,6-Dinitro-2-methylphenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.194-Bromophenyl phenyl ether BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.154-Chloro-3-methylphenol BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.0974-Chloroaniline BRL *8270E P0L050911.2 12/29/20 21:51 JMVmg/kg dry 0.254-Chlorophenyl phenyl ether BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.134-Nitroaniline BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.204-Nitrophenol BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.018AcenaphtheneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.016AcenaphthyleneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.19AcetophenoneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0089AnthraceneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.099AtrazineBRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.070BenzaldehydeBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0096Benzo(a)anthracene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0072Benzo(a)pyrene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0074Benzo(b)fluoranthene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0079Benzo(g,h,i)perylene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0085Benzo(k)fluoranthene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.15bis(2-Chloroethoxy)methane BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.13Bis(2-Chloroethyl)ether BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.14Bis(2-chloroisopropyl)ether BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.18Bis(2-Ethylhexyl)phthalate BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.14Butyl benzyl phthalate BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.15CaprolactamBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.19CarbazoleBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0095ChryseneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.023Dibenzo(a,h)anthracene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.22DibenzofuranBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.21Diethyl phthalate BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.19Dimethyl phthalate BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.20Di-n-butyl phthalate BRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.21Di-n-octyl phthalate BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0091FluorantheneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.014FluoreneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.18HexachlorobenzeneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.18HexachlorobutadieneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.28HexachlorocyclopentadieneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.13HexachloroethaneBRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-4 (10-12) Sample ID: 0120388-04 Work Order: 0120388 Time Collected: 12/22/20 16:00 Time Submitted: 12/23/20 12:38 *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.023Indeno(1,2,3-cd)pyrene BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.17IsophoroneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.017NaphthaleneBRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.17NitrobenzeneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.19N-Nitroso-di-n-propylamine BRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.22N-Nitrosodiphenylamine BRL *8270E P0L050911.2 12/29/20 21:51 JMVmg/kg dry 0.51PentachlorophenolBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.0088PhenanthreneBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.13PhenolBRL *8270E P0L050910.80 12/29/20 21:51 JMVmg/kg dry 0.012PyreneBRL *8270E P0L050910.40 12/29/20 21:51 JMVmg/kg dry 0.077PyridineBRL Surrogate Recovery Control Limits 37-131100 %2,4,6-Tribromophenol 47-13084 %2-Fluorobiphenyl 44-11786 %2-Fluorophenol 45-12176 %Nitrobenzene-d5 37-12783 %Phenol-d5 38-13591 %Terphenyl-d14 Total Metals *7196A P0L050610.49 12/29/20 12:18 BMSmg/kg dry 0.18Hexavalent Chromium BRL *7471B P0L057110.061 12/31/20 14:20 EDVmg/kg dry 0.018MercuryBRL *6020B P0L0565101.2 12/31/20 17:10 JABmg/kg dry 0.10Arsenic1.7 *6020B P0L0565101212/31/20 17:10 JABmg/kg dry 0.44Barium160 *6020B P0L0565100.61 12/31/20 17:10 JABmg/kg dry 0.045CadmiumBRL *6020B P0L0565101.2 12/31/20 17:10 JABmg/kg dry 0.29Chromium140 *6020B P0L0565101.2 12/31/20 17:10 JABmg/kg dry 0.092Lead10 *6020B P0L0565101.2 12/31/20 17:10 JABmg/kg dry 0.28Selenium3.3 *6020B P0L0565100.61 12/31/20 17:10 JABmg/kg dry 0.062SilverBRL Volatile Organic Compounds by GC/MS *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000891,1,1-Trichloroethane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000441,1,2,2-Tetrachloroethane BRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.00111,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000661,1,2-Trichloroethane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00111,1-Dichloroethane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00111,1-Dichloroethylene BRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.000871,2,3-Trichlorobenzene BRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.000581,2,4-Trichlorobenzene BRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.000771,2-Dibromo-3-chloropropane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000541,2-Dibromoethane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000681,2-Dichlorobenzene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000721,2-Dichloroethane BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000911,2-Dichloropropane BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-4 (10-12) Sample ID: 0120388-04 Work Order: 0120388 Time Collected: 12/22/20 16:00 Time Submitted: 12/23/20 12:38 *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000761,3-Dichlorobenzene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.000771,4-Dichlorobenzene BRL *8260D P0L052210.12 12/29/20 17:51 JLBmg/kg dry 0.0171,4-Dioxane BRL *8260D P0L052210.024 12/29/20 17:51 JLBCCVHmg/kg dry 0.0015Acetone0.035 *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00095BenzeneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.0010BromochloromethaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00058BromodichloromethaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00047BromoformBRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0030BromomethaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.0010Carbon disulfide BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.0012Carbon Tetrachloride BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00095ChlorobenzeneBRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0012ChloroethaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00074ChloroformBRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0018ChloromethaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00095cis-1,2-Dichloroethylene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00060cis-1,3-Dichloropropylene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00074CyclohexaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00041DibromochloromethaneBRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0017DichlorodifluoromethaneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00091EthylbenzeneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00071Isopropylbenzene (Cumene)BRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0016m,p-Xylenes BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00056Methyl Acetate BRL *8260D P0L052210.024 12/29/20 17:51 JLBmg/kg dry 0.00042Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00036MethylcyclohexaneBRL *8260D P0L052210.024 12/29/20 17:51 JLBCCVHmg/kg dry 0.0014Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L052210.024 12/29/20 17:51 JLBmg/kg dry 0.00050Methyl Isobutyl Ketone BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00098Methylene Chloride 0.0075 *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00085Methyl-tert-Butyl Ether BRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.00061NaphthaleneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00065o-Xylene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00059StyreneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.0011TetrachloroethyleneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00097TolueneBRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.0012trans-1,2-Dichloroethylene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.00052trans-1,3-Dichloropropylene BRL *8260D P0L052210.0061 12/29/20 17:51 JLBmg/kg dry 0.0012TrichloroethyleneBRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0016TrichlorofluoromethaneBRL *8260D P0L052210.012 12/29/20 17:51 JLBmg/kg dry 0.0012Vinyl chloride BRL *8260D P0L052210.018 12/29/20 17:51 JLBmg/kg dry 0.0022Xylenes, total BRL Surrogate Recovery Control Limits 70-130110 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-4 (10-12) Sample ID: 0120388-04 Work Order: 0120388 Time Collected: 12/22/20 16:00 Time Submitted: 12/23/20 12:38 84-123106 %Dibromofluoromethane 76-129100 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-5 (0.5-1.5) Sample ID: 0120388-05 Work Order: 0120388 Time Collected: 12/22/20 14:00 Time Submitted: 12/23/20 12:38 General Chemistry Parameters *SM2540 G P0L055910.100 12/31/20 10:50 EDV% by Weight 0.100% Solids 75.1 Organochlorine Pesticides by GC/ECD *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.00254,4’-DDD BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.00274,4’-DDE BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.00204,4’-DDT BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0024AldrinBRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0016alpha-BHC BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0025cis-Chlordane BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0026beta-BHC BRL *8081B P0L049310.066 12/28/20 14:32 NMBmg/kg dry 0.013ChlordaneBRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0017delta-BHC BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0028DieldrinBRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0024Endosulfan I BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.0023Endosulfan II BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.0024Endosulfan Sulfate BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.0026EndrinBRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.0028Endrin Aldehyde BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.0024Endrin Ketone BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0017gamma-BHC BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0022trans-Chlordane BRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0018HeptachlorBRL *8081B P0L049310.0066 12/28/20 14:32 NMBmg/kg dry 0.0024Heptachlor Epoxide BRL *8081B P0L049310.0066 12/28/20 14:32 NMBAmg/kg dry 0.0035MethoxychlorBRL *8081B P0L049310.066 12/28/20 14:32 NMBAmg/kg dry 0.013ToxapheneBRL Surrogate Recovery Control Limits 26-20434 %Decachlorobiphenyl 40-162102 %Tetrachloro-m-xylene Semivolatile Organic Compounds by GC/MS *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.121,1’-Biphenyl BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.262,3,4,6-Tetrachlorophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.192,4,5-Trichlorophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.212,4,6-Trichlorophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.172,4-Dichlorophenol BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.182,4-Dimethylphenol BRL *8270E P0L050912.0 12/30/20 0:06 JMVmg/kg dry 0.512,4-Dinitrophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.232,4-Dinitrotoluene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.232,6-Dinitrotoluene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.212-Chloronaphthalene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.172-Chlorophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0172-Methylnaphthalene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.172-Methylphenol BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-5 (0.5-1.5) Sample ID: 0120388-05 Work Order: 0120388 Time Collected: 12/22/20 14:00 Time Submitted: 12/23/20 12:38 *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.192-Nitroaniline BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.152-Nitrophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.173,3’-Dichlorobenzidine BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.193/4-Methylphenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.173-Nitroaniline BRL *8270E P0L050912.0 12/30/20 0:06 JMVmg/kg dry 0.484,6-Dinitro-2-methylphenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.204-Bromophenyl phenyl ether BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.174-Chloro-3-methylphenol BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.114-Chloroaniline BRL *8270E P0L050911.3 12/30/20 0:06 JMVmg/kg dry 0.274-Chlorophenyl phenyl ether BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.144-Nitroaniline BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.224-Nitrophenol BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.020AcenaphtheneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.017AcenaphthyleneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.21AcetophenoneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0096AnthraceneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.11AtrazineBRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.076BenzaldehydeBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.010Benzo(a)anthracene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0078Benzo(a)pyrene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0081Benzo(b)fluoranthene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0086Benzo(g,h,i)perylene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0093Benzo(k)fluoranthene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.17bis(2-Chloroethoxy)methane BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.14Bis(2-Chloroethyl)ether BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.16Bis(2-chloroisopropyl)ether BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.20Bis(2-Ethylhexyl)phthalate BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.15Butyl benzyl phthalate BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.16CaprolactamBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.20CarbazoleBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.010ChryseneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.025Dibenzo(a,h)anthracene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.24DibenzofuranBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.22Diethyl phthalate BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.21Dimethyl phthalate BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.22Di-n-butyl phthalate BRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.23Di-n-octyl phthalate BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0099FluorantheneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.015FluoreneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.19HexachlorobenzeneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.20HexachlorobutadieneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.30HexachlorocyclopentadieneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.14HexachloroethaneBRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-5 (0.5-1.5) Sample ID: 0120388-05 Work Order: 0120388 Time Collected: 12/22/20 14:00 Time Submitted: 12/23/20 12:38 *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.025Indeno(1,2,3-cd)pyrene BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.19IsophoroneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.019NaphthaleneBRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.19NitrobenzeneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.20N-Nitroso-di-n-propylamine BRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.24N-Nitrosodiphenylamine BRL *8270E P0L050911.3 12/30/20 0:06 JMVmg/kg dry 0.56PentachlorophenolBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.0095PhenanthreneBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.14PhenolBRL *8270E P0L050910.87 12/30/20 0:06 JMVmg/kg dry 0.013PyreneBRL *8270E P0L050910.44 12/30/20 0:06 JMVmg/kg dry 0.083PyridineBRL Surrogate Recovery Control Limits 37-13195 %2,4,6-Tribromophenol 47-13085 %2-Fluorobiphenyl 44-11784 %2-Fluorophenol 45-12173 %Nitrobenzene-d5 37-12781 %Phenol-d5 38-13587 %Terphenyl-d14 Total Metals *7196A P0L050610.53 12/29/20 12:18 BMSmg/kg dry 0.20Hexavalent Chromium BRL *7471B P0L057110.067 12/31/20 14:24 EDVmg/kg dry 0.020MercuryBRL *6020B P0L0565101.3 12/31/20 17:16 JABmg/kg dry 0.11Arsenic1.7 *6020B P0L0565101312/31/20 17:16 JABmg/kg dry 0.48Barium50 *6020B P0L0565100.67 12/31/20 17:16 JABmg/kg dry 0.049CadmiumBRL *6020B P0L0565101.3 12/31/20 17:16 JABmg/kg dry 0.32Chromium57 *6020B P0L0565101.3 12/31/20 17:16 JABmg/kg dry 0.10Lead13 *6020B P0L0565101.3 12/31/20 17:16 JABmg/kg dry 0.31Selenium1.7 *6020B P0L0565100.67 12/31/20 17:16 JABmg/kg dry 0.068SilverBRL Volatile Organic Compounds by GC/MS *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000981,1,1-Trichloroethane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000481,1,2,2-Tetrachloroethane BRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.00121,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000721,1,2-Trichloroethane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00121,1-Dichloroethane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00121,1-Dichloroethylene BRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.000951,2,3-Trichlorobenzene BRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.000641,2,4-Trichlorobenzene BRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.000841,2-Dibromo-3-chloropropane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000601,2-Dibromoethane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000741,2-Dichlorobenzene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000791,2-Dichloroethane BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00101,2-Dichloropropane BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-5 (0.5-1.5) Sample ID: 0120388-05 Work Order: 0120388 Time Collected: 12/22/20 14:00 Time Submitted: 12/23/20 12:38 *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000831,3-Dichlorobenzene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.000841,4-Dichlorobenzene BRL *8260D P0L052210.13 12/29/20 18:22 JLBmg/kg dry 0.0181,4-Dioxane BRL *8260D P0L052210.027 12/29/20 18:22 JLBCCVHmg/kg dry 0.0017AcetoneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0010BenzeneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0011BromochloromethaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00063BromodichloromethaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00052BromoformBRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0033BromomethaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0011Carbon disulfide BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0013Carbon Tetrachloride BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0010ChlorobenzeneBRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0013ChloroethaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00081ChloroformBRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0020ChloromethaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0010cis-1,2-Dichloroethylene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00066cis-1,3-Dichloropropylene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00081CyclohexaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00045DibromochloromethaneBRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0019DichlorodifluoromethaneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0010EthylbenzeneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00077Isopropylbenzene (Cumene)BRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0017m,p-Xylenes BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00062Methyl Acetate BRL *8260D P0L052210.027 12/29/20 18:22 JLBmg/kg dry 0.00046Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00039MethylcyclohexaneBRL *8260D P0L052210.027 12/29/20 18:22 JLBCCVHmg/kg dry 0.0016Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L052210.027 12/29/20 18:22 JLBmg/kg dry 0.00054Methyl Isobutyl Ketone BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0011Methylene Chloride BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00093Methyl-tert-Butyl Ether BRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.00067NaphthaleneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00071o-Xylene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00065StyreneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0012TetrachloroethyleneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0011TolueneBRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0013trans-1,2-Dichloroethylene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.00057trans-1,3-Dichloropropylene BRL *8260D P0L052210.0067 12/29/20 18:22 JLBmg/kg dry 0.0013TrichloroethyleneBRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0018TrichlorofluoromethaneBRL *8260D P0L052210.013 12/29/20 18:22 JLBmg/kg dry 0.0013Vinyl chloride BRL *8260D P0L052210.020 12/29/20 18:22 JLBmg/kg dry 0.0024Xylenes, total BRL Surrogate Recovery Control Limits 70-130114 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: SB-5 (0.5-1.5) Sample ID: 0120388-05 Work Order: 0120388 Time Collected: 12/22/20 14:00 Time Submitted: 12/23/20 12:38 84-123107 %Dibromofluoromethane 76-129101 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: Dup Sample ID: 0120388-06 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 General Chemistry Parameters *SM2540 G P0L055910.100 12/31/20 10:50 EDV% by Weight 0.100% Solids 77.8 Organochlorine Pesticides by GC/ECD *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.00244,4’-DDD BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.00264,4’-DDE BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.00194,4’-DDT BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0023AldrinBRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0015alpha-BHC BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0024cis-Chlordane BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0025beta-BHC BRL *8081B P0L049310.064 12/28/20 14:44 NMBmg/kg dry 0.012ChlordaneBRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0016delta-BHC BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0027DieldrinBRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0023Endosulfan I BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.0022Endosulfan II BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.0023Endosulfan Sulfate BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.0024EndrinBRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.0027Endrin Aldehyde BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.0023Endrin Ketone BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0016gamma-BHC BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0021trans-Chlordane BRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0017HeptachlorBRL *8081B P0L049310.0064 12/28/20 14:44 NMBmg/kg dry 0.0023Heptachlor Epoxide BRL *8081B P0L049310.0064 12/28/20 14:44 NMBAmg/kg dry 0.0034MethoxychlorBRL *8081B P0L049310.064 12/28/20 14:44 NMBAmg/kg dry 0.013ToxapheneBRL Surrogate Recovery Control Limits 26-20425 %Decachlorobiphenyl Aa 40-16299 %Tetrachloro-m-xylene Semivolatile Organic Compounds by GC/MS *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.121,1’-Biphenyl BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.252,3,4,6-Tetrachlorophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.182,4,5-Trichlorophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.212,4,6-Trichlorophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.172,4-Dichlorophenol BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.182,4-Dimethylphenol BRL *8270E P0L050912.0 12/30/20 0:51 JMVmg/kg dry 0.512,4-Dinitrophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.232,4-Dinitrotoluene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.222,6-Dinitrotoluene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.212-Chloronaphthalene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.162-Chlorophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0172-Methylnaphthalene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.162-Methylphenol BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: Dup Sample ID: 0120388-06 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.192-Nitroaniline BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.142-Nitrophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.173,3’-Dichlorobenzidine BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.193/4-Methylphenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.163-Nitroaniline BRL *8270E P0L050912.0 12/30/20 0:51 JMVmg/kg dry 0.484,6-Dinitro-2-methylphenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.204-Bromophenyl phenyl ether BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.164-Chloro-3-methylphenol BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.104-Chloroaniline BRL *8270E P0L050911.3 12/30/20 0:51 JMVmg/kg dry 0.264-Chlorophenyl phenyl ether BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.134-Nitroaniline BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.214-Nitrophenol BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.020AcenaphtheneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.017AcenaphthyleneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.21AcetophenoneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0095AnthraceneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.11AtrazineBRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.075BenzaldehydeBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.010Benzo(a)anthracene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0077Benzo(a)pyrene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0080Benzo(b)fluoranthene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0085Benzo(g,h,i)perylene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0091Benzo(k)fluoranthene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.16bis(2-Chloroethoxy)methane BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.14Bis(2-Chloroethyl)ether BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.15Bis(2-chloroisopropyl)ether BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.19Bis(2-Ethylhexyl)phthalate BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.15Butyl benzyl phthalate BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.16CaprolactamBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.20CarbazoleBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.010ChryseneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.025Dibenzo(a,h)anthracene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.23DibenzofuranBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.22Diethyl phthalate BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.21Dimethyl phthalate BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.21Di-n-butyl phthalate BRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.22Di-n-octyl phthalate BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0098FluorantheneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.015FluoreneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.19HexachlorobenzeneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.19HexachlorobutadieneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.30HexachlorocyclopentadieneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.14HexachloroethaneBRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: Dup Sample ID: 0120388-06 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.024Indeno(1,2,3-cd)pyrene BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.19IsophoroneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.018NaphthaleneBRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.18NitrobenzeneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.20N-Nitroso-di-n-propylamine BRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.24N-Nitrosodiphenylamine BRL *8270E P0L050911.3 12/30/20 0:51 JMVmg/kg dry 0.55PentachlorophenolBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.0094PhenanthreneBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.14PhenolBRL *8270E P0L050910.86 12/30/20 0:51 JMVmg/kg dry 0.013PyreneBRL *8270E P0L050910.43 12/30/20 0:51 JMVmg/kg dry 0.082PyridineBRL Surrogate Recovery Control Limits 37-13195 %2,4,6-Tribromophenol 47-13084 %2-Fluorobiphenyl 44-11782 %2-Fluorophenol 45-12169 %Nitrobenzene-d5 37-12780 %Phenol-d5 38-13585 %Terphenyl-d14 Total Metals *7196A P0L050610.51 12/29/20 12:18 BMSmg/kg dry 0.19Hexavalent Chromium BRL *7471B P0L057110.064 12/31/20 14:38 EDVmg/kg dry 0.019MercuryBRL *6020B P0L0565101.3 12/31/20 17:23 JABmg/kg dry 0.11ArsenicBRL *6020B P0L0565101312/31/20 17:23 JABmg/kg dry 0.46Barium31 *6020B P0L0565100.64 12/31/20 17:23 JABmg/kg dry 0.048CadmiumBRL *6020B P0L0565101.3 12/31/20 17:23 JABmg/kg dry 0.31Chromium22 *6020B P0L0565101.3 12/31/20 17:23 JABmg/kg dry 0.098Lead11 *6020B P0L0565101.3 12/31/20 17:23 JABmg/kg dry 0.30Selenium1.3 *6020B P0L0565100.64 12/31/20 17:23 JABmg/kg dry 0.066Silver0.94 Volatile Organic Compounds by GC/MS *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000601,1,1-Trichloroethane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000291,1,2,2-Tetrachloroethane BRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.000711,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000441,1,2-Trichloroethane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000731,1-Dichloroethane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000741,1-Dichloroethylene BRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.000581,2,3-Trichlorobenzene BRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.000391,2,4-Trichlorobenzene BRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.000511,2-Dibromo-3-chloropropane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000361,2-Dibromoethane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000451,2-Dichlorobenzene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000481,2-Dichloroethane BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000611,2-Dichloropropane BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: Dup Sample ID: 0120388-06 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000501,3-Dichlorobenzene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.000511,4-Dichlorobenzene BRL *8260D P0L052210.081 12/29/20 18:52 JLBmg/kg dry 0.0111,4-Dioxane BRL *8260D P0L052210.016 12/29/20 18:52 JLBCCVHmg/kg dry 0.0010AcetoneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00063BenzeneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00067BromochloromethaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00038BromodichloromethaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00031BromoformBRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.0020BromomethaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00070Carbon disulfide BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00080Carbon Tetrachloride BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00063ChlorobenzeneBRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.00077ChloroethaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00050ChloroformBRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.0012ChloromethaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00064cis-1,2-Dichloroethylene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00040cis-1,3-Dichloropropylene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00049CyclohexaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00027DibromochloromethaneBRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.0011DichlorodifluoromethaneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00061EthylbenzeneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00047Isopropylbenzene (Cumene)BRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.0010m,p-Xylenes BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00038Methyl Acetate BRL *8260D P0L052210.016 12/29/20 18:52 JLBmg/kg dry 0.00028Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00024MethylcyclohexaneBRL *8260D P0L052210.016 12/29/20 18:52 JLBCCVHmg/kg dry 0.00095Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L052210.016 12/29/20 18:52 JLBmg/kg dry 0.00033Methyl Isobutyl Ketone BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00066Methylene Chloride BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00057Methyl-tert-Butyl Ether BRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.00041NaphthaleneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00043o-Xylene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00039StyreneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00073TetrachloroethyleneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00064TolueneBRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00078trans-1,2-Dichloroethylene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00035trans-1,3-Dichloropropylene BRL *8260D P0L052210.0041 12/29/20 18:52 JLBmg/kg dry 0.00079TrichloroethyleneBRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.0011TrichlorofluoromethaneBRL *8260D P0L052210.0081 12/29/20 18:52 JLBmg/kg dry 0.00080Vinyl chloride BRL *8260D P0L052210.012 12/29/20 18:52 JLBmg/kg dry 0.0015Xylenes, total BRL Surrogate Recovery Control Limits 70-130112 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Solid Client Sample ID: Dup Sample ID: 0120388-06 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 84-123111 %Dibromofluoromethane 76-129101 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: Trip Blank Sample ID: 0120388-07 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 Volatile Organic Compounds by GC/MS *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0611,1,1-Trichloroethane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0361,1,2,2-Tetrachloroethane BRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.961,1,2-Trichloro-1,2,2-trifluoroethane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0661,1,2-Trichloroethane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0831,1-Dichloroethane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0831,1-Dichloroethylene BRL *8260D P0L048812.0 12/27/20 16:41 ANGug/L 0.401,2,3-Trichlorobenzene BRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.131,2,4-Trichlorobenzene BRL *8260D P0L048812.0 12/27/20 16:41 ANGug/L 0.171,2-Dibromo-3-chloropropane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0511,2-Dibromoethane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0761,2-Dichlorobenzene BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0661,2-Dichloroethane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.111,2-Dichloropropane BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0541,3-Dichlorobenzene BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.0501,4-Dichlorobenzene BRL *8260D P0L0488115012/27/20 16:41 ANGug/L 141,4-Dioxane BRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.31AcetoneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.048BenzeneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.14BromochloromethaneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.062BromodichloromethaneBRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.040BromoformBRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.18BromomethaneBRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.075Carbon disulfide BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.11Carbon Tetrachloride BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.062ChlorobenzeneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.22ChloroethaneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.076ChloroformBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.079ChloromethaneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.056cis-1,2-Dichloroethylene BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.079cis-1,3-Dichloropropylene BRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.95CyclohexaneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.081DibromochloromethaneBRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.11DichlorodifluoromethaneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.061EthylbenzeneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.054Isopropylbenzene (Cumene)BRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.12m,p-Xylenes BRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 1.0Methyl Acetate BRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.065Methyl Butyl Ketone (2-Hexanone)BRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.94MethylcyclohexaneBRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 0.24Methyl Ethyl Ketone (2-Butanone)BRL *8260D P0L048815.0 12/27/20 16:41 ANGug/L 1.0Methyl Isobutyl Ketone BRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.083Methylene Chloride BRL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 55 Laboratory Report 01/04/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Water Client Sample ID: Trip Blank Sample ID: 0120388-07 Work Order: 0120388 Time Collected: 12/22/20 00:00 Time Submitted: 12/23/20 12:38 *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.042Methyl-tert-Butyl Ether BRL *8260D P0L048811.0 12/27/20 16:41 ANGug/L 0.30NaphthaleneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.044o-Xylene BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.047StyreneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.098TetrachloroethyleneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.044TolueneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.094trans-1,2-Dichloroethylene BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.070trans-1,3-Dichloropropylene BRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.078TrichloroethyleneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.062TrichlorofluoromethaneBRL *8260D P0L048810.50 12/27/20 16:41 ANGug/L 0.097Vinyl chloride BRL *8260D P0L048811.5 12/27/20 16:41 ANGug/L 0.15Xylenes, total BRL Surrogate Recovery Control Limits 80-12496 %4-Bromofluorobenzene 75-129105 %Dibromofluoromethane 77-12381 %Toluene-d8 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0488 - 5030B Blank (P0L0488-BLK1)Prepared & Analyzed: 12/27/20 1,1,1-Trichloroethane ug/LBRL0.50 1,1,2,2-Tetrachloroethane ug/LBRL0.50 1,1,2-Trichloro-1,2,2-trifluoroethane ug/LBRL5.0 1,1,2-Trichloroethane ug/LBRL0.50 1,1-Dichloroethane ug/LBRL0.50 1,1-Dichloroethylene ug/LBRL0.50 1,2,3-Trichlorobenzene ug/LBRL2.0 1,2,4-Trichlorobenzene ug/LBRL1.0 1,2-Dibromo-3-chloropropane ug/LBRL2.0 1,2-Dibromoethane ug/LBRL0.50 1,2-Dichlorobenzene ug/LBRL0.50 1,2-Dichloroethane ug/LBRL0.50 1,2-Dichloropropane ug/LBRL0.50 1,3-Dichlorobenzene ug/LBRL0.50 1,4-Dichlorobenzene ug/LBRL0.50 1,4-Dioxane ug/LBRL150 Acetone ug/LBRL5.0 Benzene ug/LBRL0.50 Bromochloromethane ug/LBRL0.50 Bromodichloromethane ug/LBRL0.50 Bromoform ug/LBRL1.0 Bromomethane ug/LBRL1.0 Carbon disulfide ug/LBRL5.0 Carbon Tetrachloride ug/LBRL0.50 Chlorobenzene ug/LBRL0.50 Chloroethane ug/LBRL0.50 Chloroform ug/LBRL0.50 Chloromethane ug/LBRL0.50 cis-1,2-Dichloroethylene ug/LBRL0.50 cis-1,3-Dichloropropylene ug/LBRL0.50 Cyclohexane ug/LBRL1.0 Dibromochloromethane ug/LBRL0.50 Dichlorodifluoromethane ug/LBRL5.0 Ethylbenzene ug/LBRL0.50 Isopropylbenzene (Cumene)ug/LBRL0.50 m,p-Xylenes ug/LBRL1.0 Methyl Acetate ug/LBRL5.0 Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0 Methylcyclohexane ug/LBRL5.0 Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0 Methyl Isobutyl Ketone ug/LBRL5.0 Methylene Chloride ug/LBRL1.0 Methyl-tert-Butyl Ether ug/LBRL0.50 Naphthalene ug/LBRL1.0 o-Xylene ug/LBRL0.50 Styrene ug/LBRL0.50 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0488 - 5030B Blank (P0L0488-BLK1)Prepared & Analyzed: 12/27/20 Tetrachloroethylene ug/LBRL0.50 Toluene ug/LBRL0.50 trans-1,2-Dichloroethylene ug/LBRL0.50 trans-1,3-Dichloropropylene ug/LBRL0.50 Trichloroethylene ug/LBRL0.50 Trichlorofluoromethane ug/LBRL0.50 Vinyl chloride ug/LBRL0.50 Xylenes, total ug/LBRL1.5 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9647.8 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10251.0 ug/L 50.00 77-123Surrogate: Toluene-d8 8140.7 LCS (P0L0488-BS1)Prepared & Analyzed: 12/27/20 1,1,1-Trichloroethane ug/L21.7 0.50 20.00 75-136108 1,1,2,2-Tetrachloroethane ug/L17.5 0.50 20.00 62-12787 1,1,2-Trichloro-1,2,2-trifluoroethane ug/L20.9 5.0 20.00 70-130105 1,1,2-Trichloroethane ug/L23.5 0.50 20.00 70-140117 1,1-Dichloroethane ug/L21.4 0.50 20.00 78-130107 1,1-Dichloroethylene ug/L20.2 0.50 20.00 70-154101 1,2,3-Trichlorobenzene ug/L20.6 2.0 20.00 58-144103 1,2,4-Trichlorobenzene ug/L18.8 1.0 20.00 66-13994 1,2-Dibromo-3-chloropropane ug/L17.4 2.0 20.00 63-13487 1,2-Dibromoethane ug/L18.8 0.50 20.00 77-13594 1,2-Dichlorobenzene ug/L17.3 0.50 20.00 78-12886 1,2-Dichloroethane ug/L22.9 0.50 20.00 68-131115 1,2-Dichloropropane ug/L22.2 0.50 20.00 77-130111 1,3-Dichlorobenzene ug/L17.3 0.50 20.00 77-12587 1,4-Dichlorobenzene ug/L17.6 0.50 20.00 75-12688 1,4-Dioxane ug/L198 150 200.0 70-13099 Acetone ug/L42.8 5.0 40.00 40-166107 Benzene ug/L21.5 0.50 20.00 77-128107 Bromochloromethane ug/L23.3 0.50 20.00 78-135117 Bromodichloromethane ug/L23.1 0.50 20.00 76-138115 Bromoform ug/L18.5 1.0 20.00 71-13593 Bromomethane ug/L17.4 1.0 20.00 41-16887 Carbon disulfide ug/L18.7 5.0 20.00 59-13594 Carbon Tetrachloride ug/L21.9 0.50 20.00 72-142109 Chlorobenzene ug/L17.9 0.50 20.00 78-11990 Chloroethane ug/L19.7 0.50 20.00 57-14299 Chloroform ug/L21.5 0.50 20.00 77-130107 Chloromethane ug/L18.6 0.50 20.00 47-14593 cis-1,2-Dichloroethylene ug/L21.7 0.50 20.00 76-141108 cis-1,3-Dichloropropylene ug/L22.8 0.50 20.00 65-140114 Cyclohexane ug/L22.3 1.0 20.00 70-130112 Dibromochloromethane ug/L18.5 0.50 20.00 75-13492 Dichlorodifluoromethane ug/L24.1 5.0 20.00 28-163121 Ethylbenzene ug/L17.5 0.50 20.00 80-12788 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0488 - 5030B LCS (P0L0488-BS1)Prepared & Analyzed: 12/27/20 Isopropylbenzene (Cumene)ug/L17.3 0.50 20.00 70-13087 m,p-Xylenes ug/L37.3 1.0 40.00 77-13393 Methyl Acetate ug/L24.9 5.0 20.00 70-130124 Methyl Butyl Ketone (2-Hexanone)ug/L18.9 5.0 20.00 64-13795 Methylcyclohexane ug/L21.3 5.0 20.00 70-130107 Methyl Ethyl Ketone (2-Butanone)ug/L23.4 5.0 20.00 71-134117 Methyl Isobutyl Ketone ug/L23.9 5.0 20.00 69-134120 Methylene Chloride ug/L22.2 1.0 20.00 73-131111 Methyl-tert-Butyl Ether ug/L24.0 0.50 20.00 68-135120 Naphthalene ug/L18.4 1.0 20.00 64-13692 o-Xylene ug/L18.1 0.50 20.00 78-12891 Styrene ug/L18.3 0.50 20.00 78-12992 Tetrachloroethylene ug/L17.5 0.50 20.00 80-12988 Toluene ug/L21.2 0.50 20.00 76-131106 trans-1,2-Dichloroethylene ug/L20.6 0.50 20.00 76-135103 trans-1,3-Dichloropropylene ug/L23.5 0.50 20.00 67-140118 Trichloroethylene ug/L21.6 0.50 20.00 77-133108 Trichlorofluoromethane ug/L20.5 0.50 20.00 62-148102 Vinyl chloride ug/L18.4 0.50 20.00 57-14192 Xylenes, total ug/L55.4 1.5 60.00 77-13392 ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9849.0 ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10351.3 ug/L 50.00 77-123Surrogate: Toluene-d8 8240.8 Batch P0L0522 - 5035 Blank (P0L0522-BLK1)Prepared & Analyzed: 12/29/20 1,1,1-Trichloroethane mg/kg wetBRL0.0050 1,1,2,2-Tetrachloroethane mg/kg wetBRL0.0050 1,1,2-Trichloro-1,2,2-trifluoroethane mg/kg wetBRL0.010 1,1,2-Trichloroethane mg/kg wetBRL0.0050 1,1-Dichloroethane mg/kg wetBRL0.0050 1,1-Dichloroethylene mg/kg wetBRL0.0050 1,2,3-Trichlorobenzene mg/kg wetBRL0.010 1,2,4-Trichlorobenzene mg/kg wetBRL0.010 1,2-Dibromo-3-chloropropane mg/kg wetBRL0.010 1,2-Dibromoethane mg/kg wetBRL0.0050 1,2-Dichlorobenzene mg/kg wetBRL0.0050 1,2-Dichloroethane mg/kg wetBRL0.0050 1,2-Dichloropropane mg/kg wetBRL0.0050 1,3-Dichlorobenzene mg/kg wetBRL0.0050 1,4-Dichlorobenzene mg/kg wetBRL0.0050 1,4-Dioxane mg/kg wetBRL0.10 Acetone mg/kg wetBRL0.020 Benzene mg/kg wetBRL0.0050 Bromochloromethane mg/kg wetBRL0.0050 Bromodichloromethane mg/kg wetBRL0.0050 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0522 - 5035 Blank (P0L0522-BLK1)Prepared & Analyzed: 12/29/20 Bromoform mg/kg wetBRL0.0050 Bromomethane mg/kg wetBRL0.010 Carbon disulfide mg/kg wetBRL0.0050 Carbon Tetrachloride mg/kg wetBRL0.0050 Chlorobenzene mg/kg wetBRL0.0050 Chloroethane mg/kg wetBRL0.010 Chloroform mg/kg wetBRL0.0050 Chloromethane mg/kg wetBRL0.010 cis-1,2-Dichloroethylene mg/kg wetBRL0.0050 cis-1,3-Dichloropropylene mg/kg wetBRL0.0050 Cyclohexane mg/kg wetBRL0.0050 Dibromochloromethane mg/kg wetBRL0.0050 Dichlorodifluoromethane mg/kg wetBRL0.010 Ethylbenzene mg/kg wetBRL0.0050 Isopropylbenzene (Cumene)mg/kg wetBRL0.0050 m,p-Xylenes mg/kg wetBRL0.010 Methyl Acetate mg/kg wetBRL0.0050 Methyl Butyl Ketone (2-Hexanone)mg/kg wetBRL0.020 Methylcyclohexane mg/kg wetBRL0.0050 Methyl Ethyl Ketone (2-Butanone)mg/kg wetBRL0.020 Methyl Isobutyl Ketone mg/kg wetBRL0.020 Methylene Chloride mg/kg wetBRL0.0050 Methyl-tert-Butyl Ether mg/kg wetBRL0.0050 Naphthalene mg/kg wetBRL0.010 o-Xylene mg/kg wetBRL0.0050 Styrene mg/kg wetBRL0.0050 Tetrachloroethylene mg/kg wetBRL0.0050 Toluene mg/kg wetBRL0.0050 trans-1,2-Dichloroethylene mg/kg wetBRL0.0050 trans-1,3-Dichloropropylene mg/kg wetBRL0.0050 Trichloroethylene mg/kg wetBRL0.0050 Trichlorofluoromethane mg/kg wetBRL0.010 Vinyl chloride mg/kg wetBRL0.010 Xylenes, total mg/kg wetBRL0.015 ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 10954.3 ug/L 50.00 84-123Surrogate: Dibromofluoromethane 10652.8 ug/L 50.00 76-129Surrogate: Toluene-d8 10150.5 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0522 - 5035 LCS (P0L0522-BS1)Prepared & Analyzed: 12/29/20 1,1,1-Trichloroethane mg/kg wet0.0564 0.0050 0.05000 67-131113 1,1,2,2-Tetrachloroethane mg/kg wet0.0546 0.0050 0.05000 56-126109 1,1,2-Trichloro-1,2,2-trifluoroethane mg/kg wet0.0565 0.010 0.05000 70-130113 1,1,2-Trichloroethane mg/kg wet0.0533 0.0050 0.05000 70-133107 1,1-Dichloroethane mg/kg wet0.0542 0.0050 0.05000 74-127108 1,1-Dichloroethylene mg/kg wet0.0560 0.0050 0.05000 67-149112 1,2,3-Trichlorobenzene mg/kg wet0.0567 0.010 0.05000 68-130113 1,2,4-Trichlorobenzene mg/kg wet0.0581 0.010 0.05000 66-125116 1,2-Dibromo-3-chloropropane mg/kg wet0.0596 0.010 0.05000 55-157119 1,2-Dibromoethane mg/kg wet0.0533 0.0050 0.05000 70-132107 1,2-Dichlorobenzene mg/kg wet0.0548 0.0050 0.05000 72-123110 1,2-Dichloroethane mg/kg wet0.0534 0.0050 0.05000 68-128107 1,2-Dichloropropane mg/kg wet0.0552 0.0050 0.05000 73-130110 1,3-Dichlorobenzene mg/kg wet0.0548 0.0050 0.05000 71-120110 1,4-Dichlorobenzene mg/kg wet0.0549 0.0050 0.05000 71-123110 1,4-Dioxane mg/kg wet0.538 0.10 0.5000 70-130108 Acetone mg/kg wet0.141 0.020 0.1000 29-198141 Benzene mg/kg wet0.0532 0.0050 0.05000 74-127106 Bromochloromethane mg/kg wet0.0544 0.0050 0.05000 72-134109 Bromodichloromethane mg/kg wet0.0553 0.0050 0.05000 75-122111 Bromoform mg/kg wet0.0564 0.0050 0.05000 66-135113 Bromomethane mg/kg wet0.0505 0.010 0.05000 20-180101 Carbon disulfide mg/kg wet0.0525 0.0050 0.05000 61-129105 Carbon Tetrachloride mg/kg wet0.0584 0.0050 0.05000 64-143117 Chlorobenzene mg/kg wet0.0522 0.0050 0.05000 74-118104 Chloroethane mg/kg wet0.0604 0.010 0.05000 33-149121 Chloroform mg/kg wet0.0538 0.0050 0.05000 73-127108 Chloromethane mg/kg wet0.0525 0.010 0.05000 45-143105 cis-1,2-Dichloroethylene mg/kg wet0.0549 0.0050 0.05000 76-134110 cis-1,3-Dichloropropylene mg/kg wet0.0571 0.0050 0.05000 71-125114 Cyclohexane mg/kg wet0.0558 0.0050 0.05000 70-130112 Dibromochloromethane mg/kg wet0.0550 0.0050 0.05000 73-122110 Dichlorodifluoromethane mg/kg wet0.0610 0.010 0.05000 26-146122 Ethylbenzene mg/kg wet0.0536 0.0050 0.05000 74-128107 Isopropylbenzene (Cumene)mg/kg wet0.0569 0.0050 0.05000 68-126114 m,p-Xylenes mg/kg wet0.109 0.010 0.1000 75-124109 Methyl Acetate mg/kg wet0.0542 0.0050 0.05000 70-130108 Methyl Butyl Ketone (2-Hexanone)mg/kg wet0.0646 0.020 0.05000 61-157129 Methylcyclohexane mg/kg wet0.0561 0.0050 0.05000 70-130112 Methyl Ethyl Ketone (2-Butanone)mg/kg wet0.0644 0.020 0.05000 63-149129 Methyl Isobutyl Ketone mg/kg wet0.0574 0.020 0.05000 57-162115 Methylene Chloride mg/kg wet0.0504 0.0050 0.05000 74-129101 Methyl-tert-Butyl Ether mg/kg wet0.0547 0.0050 0.05000 70-130109 Naphthalene mg/kg wet0.0592 0.010 0.05000 57-157118 o-Xylene mg/kg wet0.0540 0.0050 0.05000 74-126108 Styrene mg/kg wet0.0552 0.0050 0.05000 77-121110 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P0L0522 - 5035 LCS (P0L0522-BS1)Prepared & Analyzed: 12/29/20 Tetrachloroethylene mg/kg wet0.0547 0.0050 0.05000 68-130109 Toluene mg/kg wet0.0530 0.0050 0.05000 71-129106 trans-1,2-Dichloroethylene mg/kg wet0.0558 0.0050 0.05000 73-132112 trans-1,3-Dichloropropylene mg/kg wet0.0578 0.0050 0.05000 68-123116 Trichloroethylene mg/kg wet0.0550 0.0050 0.05000 75-133110 Trichlorofluoromethane mg/kg wet0.0512 0.010 0.05000 44-146102 Vinyl chloride mg/kg wet0.0548 0.010 0.05000 48-147110 Xylenes, total mg/kg wet0.163 0.015 0.1500 74-126109 ug/L 50.00 70-130Surrogate: 4-Bromofluorobenzene 10753.4 ug/L 50.00 84-123Surrogate: Dibromofluoromethane 10250.8 ug/L 50.00 76-129Surrogate: Toluene-d8 9949.3 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P0L0509 - 3546 Blank (P0L0509-BLK1)Prepared: 12/28/20 Analyzed: 12/29/20 1,1’-Biphenyl mg/kg wetBRL0.33 2,3,4,6-Tetrachlorophenol mg/kg wetBRL0.33 2,4,5-Trichlorophenol mg/kg wetBRL0.65 2,4,6-Trichlorophenol mg/kg wetBRL0.65 2,4-Dichlorophenol mg/kg wetBRL0.65 2,4-Dimethylphenol mg/kg wetBRL0.33 2,4-Dinitrophenol mg/kg wetBRL1.5 2,4-Dinitrotoluene mg/kg wetBRL0.65 2,6-Dinitrotoluene mg/kg wetBRL0.65 2-Chloronaphthalene mg/kg wetBRL0.65 2-Chlorophenol mg/kg wetBRL0.65 2-Methylnaphthalene mg/kg wetBRL0.65 2-Methylphenol mg/kg wetBRL0.65 2-Nitroaniline mg/kg wetBRL0.65 2-Nitrophenol mg/kg wetBRL0.65 3,3’-Dichlorobenzidine mg/kg wetBRL0.65 3/4-Methylphenol mg/kg wetBRL0.65 3-Nitroaniline mg/kg wetBRL0.65 4,6-Dinitro-2-methylphenol mg/kg wetBRL1.5 4-Bromophenyl phenyl ether mg/kg wetBRL0.65 4-Chloro-3-methylphenol mg/kg wetBRL0.65 4-Chloroaniline mg/kg wetBRL0.33 4-Chlorophenyl phenyl ether mg/kg wetBRL0.99 4-Nitroaniline mg/kg wetBRL0.33 4-Nitrophenol mg/kg wetBRL0.65 Acenaphthene mg/kg wetBRL0.65 Acenaphthylene mg/kg wetBRL0.65 Acetophenone mg/kg wetBRL0.65 Anthracene mg/kg wetBRL0.65 Atrazine mg/kg wetBRL0.65 Benzaldehyde mg/kg wetBRL0.33 Benzo(a)anthracene mg/kg wetBRL0.65 Benzo(a)pyrene mg/kg wetBRL0.65 Benzo(b)fluoranthene mg/kg wetBRL0.65 Benzo(g,h,i)perylene mg/kg wetBRL0.65 Benzo(k)fluoranthene mg/kg wetBRL0.65 bis(2-Chloroethoxy)methane mg/kg wetBRL0.65 Bis(2-Chloroethyl)ether mg/kg wetBRL0.65 Bis(2-chloroisopropyl)ether mg/kg wetBRL0.33 Bis(2-Ethylhexyl)phthalate mg/kg wetBRL0.65 Butyl benzyl phthalate mg/kg wetBRL0.33 Caprolactam mg/kg wetBRL0.65 Carbazole mg/kg wetBRL0.65 Chrysene mg/kg wetBRL0.65 Dibenzo(a,h)anthracene mg/kg wetBRL0.65 Dibenzofuran mg/kg wetBRL0.65 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P0L0509 - 3546 Blank (P0L0509-BLK1)Prepared: 12/28/20 Analyzed: 12/29/20 Diethyl phthalate mg/kg wetBRL0.65 Dimethyl phthalate mg/kg wetBRL0.65 Di-n-butyl phthalate mg/kg wetBRL0.65 Di-n-octyl phthalate mg/kg wetBRL0.33 Fluoranthene mg/kg wetBRL0.65 Fluorene mg/kg wetBRL0.65 Hexachlorobenzene mg/kg wetBRL0.65 Hexachlorobutadiene mg/kg wetBRL0.65 Hexachlorocyclopentadiene mg/kg wetBRL0.65 Hexachloroethane mg/kg wetBRL0.65 Indeno(1,2,3-cd)pyrene mg/kg wetBRL0.65 Isophorone mg/kg wetBRL0.65 Naphthalene mg/kg wetBRL0.65 Nitrobenzene mg/kg wetBRL0.33 N-Nitroso-di-n-propylamine mg/kg wetBRL0.65 N-Nitrosodiphenylamine mg/kg wetBRL0.65 Pentachlorophenol mg/kg wetBRL0.99 Phenanthrene mg/kg wetBRL0.65 Phenol mg/kg wetBRL0.65 Pyrene mg/kg wetBRL0.65 Pyridine mg/kg wetBRL0.33 mg/kg wet 3.284 37-131Surrogate: 2,4,6-Tribromophenol 1063.47 mg/kg wet 1.642 47-130Surrogate: 2-Fluorobiphenyl 1031.70 mg/kg wet 3.284 44-117Surrogate: 2-Fluorophenol 1043.41 mg/kg wet 1.642 45-121Surrogate: Nitrobenzene-d5 911.49 mg/kg wet 3.284 37-127Surrogate: Phenol-d5 1013.31 mg/kg wet 1.642 38-135Surrogate: Terphenyl-d14 1061.74 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P0L0509 - 3546 LCS (P0L0509-BS1)Prepared: 12/28/20 Analyzed: 12/29/20 2,4,5-Trichlorophenol mg/kg wet1.56 0.67 1.691 41-12492 2,4,6-Trichlorophenol mg/kg wet1.54 0.67 1.691 39-12691 2,4-Dichlorophenol mg/kg wet1.37 0.67 1.691 40-12281 2,4-Dimethylphenol mg/kg wet1.33 0.33 1.691 30-12779 2,4-Dinitrophenol mg/kg wet1.14 1.5 1.691 27-12967 2,4-Dinitrotoluene mg/kg wet1.73 0.67 1.691 48-126103 2,6-Dinitrotoluene mg/kg wet1.81 0.67 1.691 46-124107 2-Chloronaphthalene mg/kg wet1.52 0.67 1.691 41-11490 2-Chlorophenol mg/kg wet1.46 0.67 1.691 34-12186 2-Methylnaphthalene mg/kg wet1.31 0.67 1.691 38-12277 2-Methylphenol mg/kg wet1.42 0.67 1.691 32-12284 2-Nitroaniline mg/kg wet1.55 0.67 1.691 44-12792 2-Nitrophenol mg/kg wet1.38 0.67 1.691 36-12382 3,3’-Dichlorobenzidine mg/kg wet1.58 0.67 1.691 22-12194 3/4-Methylphenol mg/kg wet1.33 0.67 1.691 34-11978 3-Nitroaniline mg/kg wet1.44 0.67 1.691 33-11985 4,6-Dinitro-2-methylphenol mg/kg wet1.36 1.5 1.691 29-13281 4-Bromophenyl phenyl ether mg/kg wet1.63 0.67 1.691 46-12496 4-Chloro-3-methylphenol mg/kg wet1.42 0.67 1.691 45-12284 4-Chloroaniline mg/kg wet1.04 0.33 1.691 17-10661 4-Chlorophenyl phenyl ether mg/kg wet1.54 1.0 1.691 45-12191 4-Nitroaniline mg/kg wet1.47 0.33 1.691 63-14787 4-Nitrophenol mg/kg wet1.58 0.67 1.691 30-13293 Acenaphthene mg/kg wet1.48 0.67 1.691 40-12387 Acenaphthylene mg/kg wet1.61 0.67 1.691 32-13295 Acetophenone mg/kg wet0.929 0.67 1.691 33-11555 Anthracene mg/kg wet1.64 0.67 1.691 47-12397 Benzo(a)anthracene mg/kg wet1.69 0.67 1.691 49-126100 Benzo(a)pyrene mg/kg wet2.09 0.67 1.691 45-129124 Benzo(b)fluoranthene mg/kg wet1.74 0.67 1.691 45-132103 Benzo(g,h,i)perylene mg/kg wet1.76 0.67 1.691 43-134104 Benzo(k)fluoranthene mg/kg wet1.66 0.67 1.691 47-13298 bis(2-Chloroethoxy)methane mg/kg wet1.25 0.67 1.691 36-12174 Bis(2-Chloroethyl)ether mg/kg wet1.42 0.67 1.691 31-12084 Bis(2-chloroisopropyl)ether mg/kg wet1.23 0.33 1.691 33-13173 Bis(2-Ethylhexyl)phthalate mg/kg wet2.01 0.67 1.691 51-133119 Butyl benzyl phthalate mg/kg wet1.84 0.33 1.691 48-132109 Carbazole mg/kg wet1.65 0.67 1.691 50-12398 Chrysene mg/kg wet1.74 0.67 1.691 50-124103 Dibenzo(a,h)anthracene mg/kg wet1.76 0.67 1.691 45-134104 Dibenzofuran mg/kg wet1.54 0.67 1.691 44-12091 Diethyl phthalate mg/kg wet1.56 0.67 1.691 50-12493 Dimethyl phthalate mg/kg wet1.57 0.67 1.691 48-12493 Di-n-butyl phthalate mg/kg wet1.80 0.67 1.691 51-128106 Di-n-octyl phthalate mg/kg wet1.82 0.33 1.691 45-140108 Fluoranthene mg/kg wet1.69 0.67 1.691 50-127100 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Semivolatile Organic Compounds by GC/MS - Quality Control Batch P0L0509 - 3546 LCS (P0L0509-BS1)Prepared: 12/28/20 Analyzed: 12/29/20 Fluorene mg/kg wet1.58 0.67 1.691 43-12593 Hexachlorobenzene mg/kg wet1.67 0.67 1.691 45-12299 Hexachlorobutadiene mg/kg wet1.41 0.67 1.691 32-12384 Hexachlorocyclopentadiene mg/kg wet1.19 0.67 1.691 32-11771 Hexachloroethane mg/kg wet1.31 0.67 1.691 28-11777 Indeno(1,2,3-cd)pyrene mg/kg wet1.71 0.67 1.691 45-133101 Isophorone mg/kg wet0.585 0.67 1.691 30-12235 Naphthalene mg/kg wet1.28 0.67 1.691 35-12376 Nitrobenzene mg/kg wet1.18 0.33 1.691 34-12270 N-Nitroso-di-n-propylamine mg/kg wet1.38 0.67 1.691 36-12082 N-Nitrosodiphenylamine mg/kg wet1.88 0.67 1.691 38-127111 Pentachlorophenol mg/kg wet1.88 1.0 1.691 25-133111 Phenanthrene mg/kg wet1.60 0.67 1.691 50-12195 Phenol mg/kg wet1.39 0.67 1.691 34-12182 Pyrene mg/kg wet1.81 0.67 1.691 47-127107 Pyridine mg/kg wet0.837 0.33 1.691 10-6049 mg/kg wet 3.383 37-131Surrogate: 2,4,6-Tribromophenol 1033.49 mg/kg wet 1.691 47-130Surrogate: 2-Fluorobiphenyl 861.45 mg/kg wet 3.383 44-117Surrogate: 2-Fluorophenol 862.93 mg/kg wet 1.691 45-121Surrogate: Nitrobenzene-d5 671.14 mg/kg wet 3.383 37-127Surrogate: Phenol-d5 832.80 mg/kg wet 1.691 38-135Surrogate: Terphenyl-d14 941.59 LCS (P0L0509-BS2)Prepared: 12/28/20 Analyzed: 12/29/20 1,1’-Biphenyl mg/kg wet1.50 0.33 1.663 40-11790 2,3,4,6-Tetrachlorophenol mg/kg wet1.67 0.33 1.663 44-125100 Atrazine mg/kg wet1.63 0.66 1.663 47-12798 Benzaldehyde mg/kg wet1.27 0.33 1.663 35-11577 Caprolactam mg/kg wet1.50 0.66 1.663 46-11790 Pyridine mg/kg wetBRL0.33 10-60 mg/kg wet 3.326 37-131Surrogate: 2,4,6-Tribromophenol 1003.31 mg/kg wet 1.663 47-130Surrogate: 2-Fluorobiphenyl 901.49 mg/kg wet 3.326 44-117Surrogate: 2-Fluorophenol 902.99 mg/kg wet 1.663 45-121Surrogate: Nitrobenzene-d5 771.29 mg/kg wet 3.326 37-127Surrogate: Phenol-d5 862.87 mg/kg wet 1.663 38-135Surrogate: Terphenyl-d14 921.54 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 45 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Organochlorine Pesticides by GC/ECD - Quality Control Batch P0L0493 - 3546 Blank (P0L0493-BLK1)Prepared & Analyzed: 12/28/20 4,4’-DDD mg/kg wetBRL0.0051 4,4’-DDE mg/kg wetBRL0.0051 4,4’-DDT mg/kg wetBRL0.0051 Aldrin mg/kg wetBRL0.0051 alpha-BHC mg/kg wetBRL0.0051 cis-Chlordane mg/kg wetBRL0.0051 beta-BHC mg/kg wetBRL0.0051 Chlordane mg/kg wetBRL0.051 delta-BHC mg/kg wetBRL0.0051 Dieldrin mg/kg wetBRL0.0051 Endosulfan I mg/kg wetBRL0.0051 Endosulfan II mg/kg wetBRL0.0051 Endosulfan Sulfate mg/kg wetBRL0.0051 Endrin mg/kg wetBRL0.0051 Endrin Aldehyde mg/kg wetBRL0.0051 Endrin Ketone mg/kg wetBRL0.0051 gamma-BHC mg/kg wetBRL0.0051 trans-Chlordane mg/kg wetBRL0.0051 Heptachlor mg/kg wetBRL0.0051 Heptachlor Epoxide mg/kg wetBRL0.0051 Methoxychlor mg/kg wetBRL0.0051 Toxaphene mg/kg wetBRL0.051 mg/kg wet 0.03370 26-204Surrogate: Decachlorobiphenyl 650.0219 mg/kg wet 0.03370 40-162Surrogate: Tetrachloro-m-xylene 970.0327 LCS (P0L0493-BS1)Prepared & Analyzed: 12/28/20 4,4’-DDD mg/kg wet0.0204 0.0050 0.03341 56-13961 4,4’-DDE mg/kg wet0.0207 0.0050 0.03341 56-13462 4,4’-DDT mg/kg wet0.0207 0.0050 0.03341 50-14562 Aldrin mg/kg wet0.0197 0.0050 0.03341 45-13659 alpha-BHC mg/kg wet0.0210 0.0050 0.03341 45-13763 cis-Chlordane mg/kg wet0.0200 0.0050 0.03341 54-13360 beta-BHC mg/kg wet0.0204 0.0050 0.03341 50-13661 delta-BHC mg/kg wet0.0207 0.0050 0.03341 47-13962 Dieldrin mg/kg wet0.0207 0.0050 0.03341 56-13662 Endosulfan I mg/kg wet0.0204 0.0050 0.03341 53-13261 Endosulfan II mg/kg wet0.0207 0.0050 0.03341 53-13462 Endosulfan Sulfate mg/kg wet0.0194 0.0050 0.03341 55-13658 Endrin mg/kg wet0.0204 0.0050 0.03341 57-14061 Endrin Aldehyde mg/kg wet0.0194 0.0050 0.03341 35-13758 Endrin Ketone mg/kg wet0.0200 0.0050 0.03341 55-13660 gamma-BHC mg/kg wet0.0207 0.0050 0.03341 49-13562 trans-Chlordane mg/kg wet0.0197 0.0050 0.03341 53-13559 Heptachlor mg/kg wet0.0204 0.0050 0.03341 47-13661 Heptachlor Epoxide mg/kg wet0.0200 0.0050 0.03341 52-13660 Methoxychlor mg/kg wet0.0194 0.0050 0.03341 52-14358 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 46 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Organochlorine Pesticides by GC/ECD - Quality Control Batch P0L0493 - 3546 LCS (P0L0493-BS1)Prepared & Analyzed: 12/28/20 mg/kg wet 0.03341 26-204Surrogate: Decachlorobiphenyl 680.0227 mg/kg wet 0.03341 40-162Surrogate: Tetrachloro-m-xylene 1050.0351 LCS (P0L0493-BS2)Prepared & Analyzed: 12/28/20 Chlordane mg/kg wet0.206 0.050 0.3341 43-14962 mg/kg wet 0.03341 26-204Surrogate: Decachlorobiphenyl 780.0261 mg/kg wet 0.03341 40-162Surrogate: Tetrachloro-m-xylene 1070.0358 LCS (P0L0493-BS3)Prepared & Analyzed: 12/28/20 Toxaphene mg/kg wet0.257 0.050 0.3306 33-14178 mg/kg wet 0.03306 26-204Surrogate: Decachlorobiphenyl 760.0251 mg/kg wet 0.03306 40-162Surrogate: Tetrachloro-m-xylene 1000.0331 Matrix Spike (P0L0493-MS1)Prepared & Analyzed: 12/28/20 Source: 0120388-01 4,4’-DDD mg/kg dry0.0207 0.0065 0.04322 BRL M56-13948 4,4’-DDE mg/kg dry0.0238 0.0065 0.04322 BRL M56-13455 4,4’-DDT mg/kg dry0.0203 0.0065 0.04322 BRL M50-14547 Aldrin mg/kg dry0.0259 0.0065 0.04322 BRL 45-13660 alpha-BHC mg/kg dry0.0255 0.0065 0.04322 BRL 45-13759 cis-Chlordane mg/kg dry0.0233 0.0065 0.04322 BRL 54-13354 beta-BHC mg/kg dry0.0324 0.0065 0.04322 BRL 50-13675 delta-BHC mg/kg dry0.0233 0.0065 0.04322 BRL 47-13954 Dieldrin mg/kg dry0.0233 0.0065 0.04322 BRL M56-13654 Endosulfan I mg/kg dry0.0233 0.0065 0.04322 BRL 53-13254 Endosulfan II mg/kg dry0.0203 0.0065 0.04322 BRL M53-13447 Endosulfan Sulfate mg/kg dry0.0169 0.0065 0.04322 BRL M55-13639 Endrin mg/kg dry0.0233 0.0065 0.04322 BRL M57-14054 Endrin Aldehyde mg/kg dry0.0173 0.0065 0.04322 BRL 35-13740 Endrin Ketone mg/kg dry0.0169 0.0065 0.04322 BRL M55-13639 gamma-BHC mg/kg dry0.0251 0.0065 0.04322 BRL 49-13558 trans-Chlordane mg/kg dry0.0229 0.0065 0.04322 BRL 53-13553 Heptachlor mg/kg dry0.0242 0.0065 0.04322 BRL 47-13656 Heptachlor Epoxide mg/kg dry0.0246 0.0065 0.04322 BRL 52-13657 Methoxychlor mg/kg dry0.0169 0.0065 0.04322 BRL M52-14339 mg/kg dry 0.04322 26-204Surrogate: Decachlorobiphenyl 370.0160 mg/kg dry 0.04322 40-162Surrogate: Tetrachloro-m-xylene 920.0398 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 47 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Organochlorine Pesticides by GC/ECD - Quality Control Batch P0L0493 - 3546 Matrix Spike Dup (P0L0493-MSD1)Prepared & Analyzed: 12/28/20 Source: 0120388-01 4,4’-DDD mg/kg dry0.0213 0.0065 0.04347 BRL 29 M56-13949 3 4,4’-DDE mg/kg dry0.0261 0.0065 0.04347 BRL 3656-13460 9 4,4’-DDT mg/kg dry0.0204 0.0065 0.04347 BRL 38 M50-14547 0.6 Aldrin mg/kg dry0.0296 0.0065 0.04347 BRL 2945-13668 13 alpha-BHC mg/kg dry0.0300 0.0065 0.04347 BRL 2445-13769 16 cis-Chlordane mg/kg dry0.0256 0.0065 0.04347 BRL 2554-13359 9 beta-BHC mg/kg dry0.0400 0.0065 0.04347 BRL 17 D50-13692 21 delta-BHC mg/kg dry0.0278 0.0065 0.04347 BRL 1847-13964 18 Dieldrin mg/kg dry0.0261 0.0065 0.04347 BRL 3056-13660 11 Endosulfan I mg/kg dry0.0261 0.0065 0.04347 BRL 3253-13260 11 Endosulfan II mg/kg dry0.0217 0.0065 0.04347 BRL 20 M53-13450 7 Endosulfan Sulfate mg/kg dry0.0183 0.0065 0.04347 BRL 24 M55-13642 8 Endrin mg/kg dry0.0252 0.0065 0.04347 BRL 2157-14058 8 Endrin Aldehyde mg/kg dry0.0183 0.0065 0.04347 BRL 3535-13742 5 Endrin Ketone mg/kg dry0.0170 0.0065 0.04347 BRL 18 M55-13639 0.6 gamma-BHC mg/kg dry0.0300 0.0065 0.04347 BRL 2249-13569 18 trans-Chlordane mg/kg dry0.0248 0.0065 0.04347 BRL 2753-13557 8 Heptachlor mg/kg dry0.0304 0.0065 0.04347 BRL 2747-13670 23 Heptachlor Epoxide mg/kg dry0.0278 0.0065 0.04347 BRL 1852-13664 12 Methoxychlor mg/kg dry0.0174 0.0065 0.04347 BRL 30 M52-14340 3 mg/kg dry 0.04347 26-204Surrogate: Decachlorobiphenyl 360.0156 mg/kg dry 0.04347 40-162Surrogate: Tetrachloro-m-xylene 1050.0456 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 48 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Total Metals - Quality Control Batch P0L0506 - 3060A Blank (P0L0506-BLK1)Prepared: 12/28/20 Analyzed: 12/29/20 Hexavalent Chromium mg/kg wetBRL0.40 LCS (P0L0506-BS1)Prepared: 12/28/20 Analyzed: 12/29/20 Hexavalent Chromium mg/kg wet16.7 0.40 16.00 80-120105 Batch P0L0565 - 3050B Blank (P0L0565-BLK1)Prepared & Analyzed: 12/31/20 Arsenic mg/kg wetBRL1.0 Barium mg/kg wetBRL10 Cadmium mg/kg wetBRL0.50 Chromium mg/kg wetBRL1.0 Lead mg/kg wetBRL1.0 Selenium mg/kg wetBRL1.0 Silver mg/kg wetBRL0.50 LCS (P0L0565-BS1)Prepared & Analyzed: 12/31/20 Arsenic mg/kg wet11.8 1.0 12.50 80-12095 Barium mg/kg wet12.4 10 12.50 80-120100 Cadmium mg/kg wet12.3 0.50 12.50 80-12098 Chromium mg/kg wet11.9 1.0 12.50 80-12095 Lead mg/kg wet12.3 1.0 12.50 80-12098 Selenium mg/kg wet12.1 1.0 12.50 80-12097 Silver mg/kg wet4.83 0.50 5.000 80-12097 Matrix Spike (P0L0565-MS1)Prepared & Analyzed: 12/31/20 Source: 0120388-02 Arsenic mg/kg dry12.6 1.2 15.47 1.21 M75-12574 Barium mg/kg dry66.7 12 15.46 44.7 M75-125142 Cadmium mg/kg dry15.6 0.62 15.46 BRL 75-125101 Chromium mg/kg dry43.0 1.2 15.47 23.1 M75-125128 Lead mg/kg dry22.9 1.2 15.47 7.07 75-125102 Selenium mg/kg dry15.3 1.2 15.46 1.07 75-12592 Silver mg/kg dry5.90 0.62 6.186 BRL 75-12595 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 49 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Total Metals - Quality Control Batch P0L0565 - 3050B Matrix Spike Dup (P0L0565-MSD1)Prepared & Analyzed: 12/31/20 Source: 0120388-02 Arsenic mg/kg dry12.4 1.2 15.47 1.21 20 M75-12573 2 Barium mg/kg dry66.8 12 15.46 44.7 20 M75-125143 0.1 Cadmium mg/kg dry15.0 0.62 15.46 BRL 2075-12597 4 Chromium mg/kg dry42.8 1.2 15.47 23.1 20 M75-125127 0.4 Lead mg/kg dry21.8 1.2 15.47 7.07 2075-12595 5 Selenium mg/kg dry14.7 1.2 15.46 1.07 2075-12588 4 Silver mg/kg dry5.82 0.62 6.186 BRL 2075-12594 1 Post Spike (P0L0565-PS1)Prepared & Analyzed: 12/31/20 Source: 0120388-02 Arsenic ug/L99.1 100.0 3.92 80-12095 Barium ug/L239 100.0 145 80-12094 Cadmium ug/L98.9 100.0 0.0190 80-12099 Chromium ug/L173 100.0 74.7 80-12098 Lead ug/L119 100.0 22.9 80-12096 Selenium ug/L106 100.0 3.47 80-120102 Silver ug/L96.5 100.0 0.0360 80-12097 Batch P0L0571 - 7471B Blank (P0L0571-BLK1)Prepared & Analyzed: 12/31/20 Mercury mg/kg wetBRL0.050 LCS (P0L0571-BS1)Prepared & Analyzed: 12/31/20 Mercury mg/kg wet0.413 0.050 0.4167 80-12099 Matrix Spike (P0L0571-MS1)Prepared & Analyzed: 12/31/20 Source: 0120388-01 Mercury mg/kg dry0.556 0.065 0.5421 BRL 80-120103 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 50 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Total Metals - Quality Control Batch P0L0571 - 7471B Matrix Spike Dup (P0L0571-MSD1)Prepared & Analyzed: 12/31/20 Source: 0120388-01 Mercury mg/kg dry0.563 0.065 0.5421 BRL 2080-120104 1 Post Spike (P0L0571-PS1)Prepared & Analyzed: 12/31/20 Source: 0120388-01 Mercury ug/L4.77 5.000 0.137 85-11593 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 51 of 55 1/4/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 0120388 Time Submitted: 12/23/2020 12:38:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control Batch P0L0559 - Solids, Dry Weight Duplicate (P0L0559-DUP1)Prepared: 12/30/20 Analyzed: 12/31/20 Source: 0120388-02 % Solids % by Weight82.0 0.100 80.8 201 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 52 of 55 Sample Extraction Data Prep Method: Solids, Dry Weight Lab Number Batch Date/TimeInitialFinal P0L05100120388-01 12/28/20 14:2530 30g g P0L05590120388-02 12/30/20 15:1730 30g g P0L05590120388-03 12/30/20 15:1730 30g g P0L05590120388-04 12/30/20 15:1730 30g g P0L05590120388-05 12/30/20 15:1730 30g g P0L05590120388-06 12/30/20 15:1730 30g g Prep Method: 3546 Lab Number Batch Date/TimeInitialFinal P0L04930120388-01 12/28/20 8:4029.57 10g mL P0L04930120388-02 12/28/20 8:4029.55 10g mL P0L04930120388-03 12/28/20 8:4030.07 10g mL P0L04930120388-04 12/28/20 8:4029.67 10g mL P0L04930120388-05 12/28/20 8:4030.05 10g mL P0L04930120388-06 12/28/20 8:4030.34 10g mL Prep Method: 3546 Lab Number Batch Date/TimeInitialFinal P0L05090120388-01 12/28/20 13:3529.58 1g mL P0L05090120388-02 12/28/20 13:3529.59 1g mL P0L05090120388-03 12/28/20 13:3530.26 1g mL P0L05090120388-04 12/28/20 13:3529.92 1g mL P0L05090120388-05 12/28/20 13:3530.22 1g mL P0L05090120388-06 12/28/20 13:3529.52 1g mL Prep Method: 3050B Lab Number Batch Date/TimeInitialFinal P0L05650120388-01 12/31/20 8:482 50g mL P0L05650120388-02 12/31/20 8:482 50g mL P0L05650120388-03 12/31/20 8:482 50g mL P0L05650120388-04 12/31/20 8:482 50g mL P0L05650120388-05 12/31/20 8:482 50g mL P0L05650120388-06 12/31/20 8:482 50g mL Prep Method: 3060A Lab Number Batch Date/TimeInitialFinal P0L05060120388-01 12/28/20 13:192.5 100g mL P0L05060120388-02 12/28/20 13:192.5 100g mL P0L05060120388-03 12/28/20 13:192.5 100g mL P0L05060120388-04 12/28/20 13:192.5 100g mL P0L05060120388-05 12/28/20 13:192.5 100g mL P0L05060120388-06 12/28/20 13:192.5 100g mL Prep Method: 7471B Lab Number Batch Date/TimeInitialFinal P0L05710120388-01 12/31/20 11:230.6 50g mL P0L05710120388-02 12/31/20 11:230.6 50g mL P0L05710120388-03 12/31/20 11:230.6 50g mL P0L05710120388-04 12/31/20 11:230.6 50g mL P0L05710120388-05 12/31/20 11:230.6 50g mL P0L05710120388-06 12/31/20 11:230.6 50g mL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 53 of 55 Sample Extraction Data Prep Method: 5030B Lab Number Batch Date/TimeInitialFinal P0L04880120388-07 12/27/20 13:3010 10mL mL Prep Method: 5035 Lab Number Batch Date/TimeInitialFinal P0L05220120388-01 12/29/20 9:077.71 5g mL P0L05220120388-02 12/29/20 9:075 5g mL P0L05220120388-03 12/29/20 9:077.17 5g mL P0L05220120388-04 12/29/20 9:075 5g mL P0L05220120388-05 12/29/20 9:075 5g mL P0L05220120388-06 12/29/20 9:077.93 5g mL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 54 of 55 Page 55 of 55 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Case Narrative 1/8/21 15:46 Hart & Hickman (Charlotte) Matt Ingalls 2923 South Tryon St. Ste 100 Charlotte, NC 28203 Project: PRO-011 Lab Submittal Date: 01/04/2021 Work Order: 1010090 Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL Senior Project Manager Angela D. Overcash Data Qualifiers Key Reference: J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). Method Detection LimitMDL Below Reporting LimitBRL Relative Percent DifferenceRPD *Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 32 Sample Receipt Summary 01/08/2021 Work Order: 1010090 Client Sample ID MatrixLab Sample ID Date/Time Sampled Date/Time Received 1010090-01 01/04/21 11:55SS-8 01/04/21 16:00Air 1010090-02 01/04/21 12:35SS-7 01/04/21 16:00Air 1010090-03 01/04/21 14:10SS-5 01/04/21 16:00Air 1010090-04 01/04/21 9:05SS-4 01/04/21 16:00Air 1010090-05 01/04/21 9:50SS-3 01/04/21 16:00Air 1010090-06 01/04/21 11:15SS-1 01/04/21 16:00Air 1010090-07 01/04/21 13:25SS-6 01/04/21 16:00Air 1010090-08 01/04/21 10:40SS-2 01/04/21 16:00Air 1010090-09 01/04/21 14:45SG-1 01/04/21 16:00Air 1010090-10 01/04/21 14:45DUP-3 01/04/21 16:00Air Samples were received in good condition at 6.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 32 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 1010090 01/08/2021 Summary of Detections 9.5 ug/m‡ Air1010090-01 SS-8 Acetone TO-15 1.9 J ug/m‡ Air1010090-01 SS-8 Carbon disulfide TO-15 2.5 J ug/m‡ Air1010090-01 SS-8 Cyclohexane TO-15 3.1 ug/m‡ Air1010090-01 SS-8 Dichlorodifluoromethane TO-15 7.7 ug/m‡ Air1010090-01 SS-8 Isopropyl alcohol TO-15 0.94 J ug/m‡ Air1010090-01 SS-8 Methyl Ethyl Ketone (2-Butanone)TO-15 4.6 ug/m‡ Air1010090-01 SS-8 Methyl Isobutyl Ketone TO-15 6.9 ug/m‡ Air1010090-01 SS-8 Methylene Chloride TO-15 3.1 J ug/m‡ Air1010090-01 SS-8 Tetrachloroethylene TO-15 2.3 ug/m‡ Air1010090-01 SS-8 Toluene TO-15 4.1 ug/m‡ Air1010090-01 SS-8 Trichloroethylene TO-15 1.2 J ug/m‡ Air1010090-01 SS-8 Trichlorofluoromethane TO-15 7.0 ug/m‡ Air1010090-02 SS-7 Acetone TO-15 2.2 J ug/m‡ Air1010090-02 SS-7 Carbon disulfide TO-15 6.4 ug/m‡ Air1010090-02 SS-7 Cyclohexane TO-15 3.1 ug/m‡ Air1010090-02 SS-7 Dichlorodifluoromethane TO-15 8.9 ug/m‡ Air1010090-02 SS-7 Isopropyl alcohol TO-15 0.83 J ug/m‡ Air1010090-02 SS-7 Methyl Ethyl Ketone (2-Butanone)TO-15 4.6 ug/m‡ Air1010090-02 SS-7 Methyl Isobutyl Ketone TO-15 5.9 ug/m‡ Air1010090-02 SS-7 Methylene Chloride TO-15 4.9 ug/m‡ Air1010090-02 SS-7 Tetrachloroethylene TO-15 0.87 J ug/m‡ Air1010090-02 SS-7 Toluene TO-15 8.7 ug/m‡ Air1010090-02 SS-7 Trichloroethylene TO-15 1.9 J ug/m‡ Air1010090-02 SS-7 Trichlorofluoromethane TO-15 5.5 ug/m‡ Air1010090-03 SS-5 1,2,4-Trimethylbenzene TO-15 53 ug/m‡ Air1010090-03 SS-5 Acetone TO-15 3.5 J ug/m‡ Air1010090-03 SS-5 Carbon disulfide TO-15 4.2 ug/m‡ Air1010090-03 SS-5 Cyclohexane TO-15 5.6 ug/m‡ Air1010090-03 SS-5 Dichlorodifluoromethane TO-15 1.5 J ug/m‡ Air1010090-03 SS-5 Ethylbenzene TO-15 12 ug/m‡ Air1010090-03 SS-5 Isopropyl alcohol TO-15 5.1 J ug/m‡ Air1010090-03 SS-5 m,p-Xylenes TO-15 4.7 ug/m‡ Air1010090-03 SS-5 Methyl Ethyl Ketone (2-Butanone)TO-15 5.8 ug/m‡ Air1010090-03 SS-5 Methyl Isobutyl Ketone TO-15 6.7 ug/m‡ Air1010090-03 SS-5 Methylene Chloride TO-15 1.9 J ug/m‡ Air1010090-03 SS-5 o-Xylene TO-15 2.3 ug/m‡ Air1010090-03 SS-5 Toluene TO-15 2.2 J ug/m‡ Air1010090-03 SS-5 Trichlorofluoromethane TO-15 3.7 ug/m‡ Air1010090-04 SS-4 1,1,1-Trichloroethane TO-15 7.2 ug/m‡ Air1010090-04 SS-4 Acetone TO-15 2.7 J ug/m‡ Air1010090-04 SS-4 Carbon disulfide TO-15 2.3 J ug/m‡ Air1010090-04 SS-4 Cyclohexane TO-15 3.3 ug/m‡ Air1010090-04 SS-4 Dichlorodifluoromethane TO-15 5.4 ug/m‡ Air1010090-04 SS-4 Isopropyl alcohol TO-15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 32 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 1010090 01/08/2021 Summary of Detections 0.74 J ug/m‡ Air1010090-04 SS-4 Methyl Ethyl Ketone (2-Butanone)TO-15 13 ug/m‡ Air1010090-05 SS-3 1,1,1-Trichloroethane TO-15 6.0 ug/m‡ Air1010090-05 SS-3 Acetone TO-15 2.6 J ug/m‡ Air1010090-05 SS-3 Carbon disulfide TO-15 3.7 ug/m‡ Air1010090-05 SS-3 Dichlorodifluoromethane TO-15 5.1 ug/m‡ Air1010090-05 SS-3 Ethylbenzene TO-15 5.7 ug/m‡ Air1010090-05 SS-3 Isopropyl alcohol TO-15 40 ug/m‡ Air1010090-05 SS-3 m,p-Xylenes TO-15 1.0 J ug/m‡ Air1010090-05 SS-3 Methyl Ethyl Ketone (2-Butanone)TO-15 2.2 ug/m‡ Air1010090-05 SS-3 Methylene Chloride TO-15 15 ug/m‡ Air1010090-05 SS-3 o-Xylene TO-15 2.0 J ug/m‡ Air1010090-05 SS-3 Trichlorofluoromethane TO-15 29 ug/m‡ Air1010090-06 SS-1 Acetone TO-15 1.8 J ug/m‡ Air1010090-06 SS-1 Carbon disulfide TO-15 1.5 J ug/m‡ Air1010090-06 SS-1 Chloroform TO-15 3.1 ug/m‡ Air1010090-06 SS-1 Dichlorodifluoromethane TO-15 3.5 J ug/m‡ Air1010090-06 SS-1 Isopropyl alcohol TO-15 1.5 ug/m‡ Air1010090-06 SS-1 Methyl Ethyl Ketone (2-Butanone)TO-15 1.9 ug/m‡ Air1010090-06 SS-1 Methylene Chloride TO-15 5.1 ug/m‡ Air1010090-06 SS-1 Styrene TO-15 16 ug/m‡ Air1010090-07 SS-6 Acetone TO-15 3.1 J ug/m‡ Air1010090-07 SS-6 Carbon disulfide TO-15 3.2 ug/m‡ Air1010090-07 SS-6 Dichlorodifluoromethane TO-15 4.2 J ug/m‡ Air1010090-07 SS-6 Isopropyl alcohol TO-15 1.8 J ug/m‡ Air1010090-07 SS-6 m,p-Xylenes TO-15 1.5 ug/m‡ Air1010090-07 SS-6 Methyl Ethyl Ketone (2-Butanone)TO-15 2.2 ug/m‡ Air1010090-07 SS-6 Methylene Chloride TO-15 1.4 J ug/m‡ Air1010090-07 SS-6 Toluene TO-15 2.0 J ug/m‡ Air1010090-07 SS-6 Trichlorofluoromethane TO-15 24 ug/m‡ Air1010090-08 SS-2 Acetone TO-15 3.1 J ug/m‡ Air1010090-08 SS-2 Carbon disulfide TO-15 1.6 J ug/m‡ Air1010090-08 SS-2 Chloroform TO-15 3.3 ug/m‡ Air1010090-08 SS-2 Dichlorodifluoromethane TO-15 4.2 J ug/m‡ Air1010090-08 SS-2 Isopropyl alcohol TO-15 1.7 ug/m‡ Air1010090-08 SS-2 Methyl Ethyl Ketone (2-Butanone)TO-15 2.1 ug/m‡ Air1010090-08 SS-2 Methylene Chloride TO-15 2.4 J ug/m‡ Air1010090-09 SG-1 1,1-Dichloroethane TO-15 81 ug/m‡ Air1010090-09 SG-1 1,1-Dichloroethylene TO-15 11 ug/m‡ Air1010090-09 SG-1 1,2,4-Trimethylbenzene TO-15 9.2 ug/m‡ Air1010090-09 SG-1 Acetone TO-15 52 ug/m‡ Air1010090-09 SG-1 Benzene TO-15 880 ug/m‡ Air1010090-09 SG-1 Carbon disulfide TO-15 7.5 ug/m‡ Air1010090-09 SG-1 Chloroethane TO-15 42 ug/m‡ Air1010090-09 SG-1 cis-1,2-Dichloroethylene TO-15 21 ug/m‡ Air1010090-09 SG-1 Cyclohexane TO-15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 32 Client ID ResultParameterMethod UnitsWaypoint ID Work Order: 1010090 01/08/2021 Summary of Detections 2.9 J ug/m‡ Air1010090-09 SG-1 Dichlorodifluoromethane TO-15 5.0 ug/m‡ Air1010090-09 SG-1 Ethylbenzene TO-15 26 ug/m‡ Air1010090-09 SG-1 Heptane TO-15 37 ug/m‡ Air1010090-09 SG-1 Hexane TO-15 15 ug/m‡ Air1010090-09 SG-1 m,p-Xylenes TO-15 3.1 ug/m‡ Air1010090-09 SG-1 Methyl Ethyl Ketone (2-Butanone)TO-15 4.3 ug/m‡ Air1010090-09 SG-1 Methylene Chloride TO-15 4.3 ug/m‡ Air1010090-09 SG-1 o-Xylene TO-15 14 ug/m‡ Air1010090-09 SG-1 Tetrachloroethylene TO-15 90 ug/m‡ Air1010090-09 SG-1 Toluene TO-15 81 ug/m‡ Air1010090-09 SG-1 trans-1,2-Dichloroethylene TO-15 1400 ug/m‡ Air1010090-09 SG-1 Trichloroethylene TO-15 4.4 ug/m‡ Air1010090-09 SG-1 Vinyl chloride TO-15 2.3 J ug/m‡ Air1010090-10 DUP-3 1,1-Dichloroethane TO-15 80 ug/m‡ Air1010090-10 DUP-3 1,1-Dichloroethylene TO-15 11 ug/m‡ Air1010090-10 DUP-3 1,2,4-Trimethylbenzene TO-15 7.3 ug/m‡ Air1010090-10 DUP-3 Acetone TO-15 52 ug/m‡ Air1010090-10 DUP-3 Benzene TO-15 830 ug/m‡ Air1010090-10 DUP-3 Carbon disulfide TO-15 7.8 ug/m‡ Air1010090-10 DUP-3 Chloroethane TO-15 42 ug/m‡ Air1010090-10 DUP-3 cis-1,2-Dichloroethylene TO-15 22 ug/m‡ Air1010090-10 DUP-3 Cyclohexane TO-15 2.9 J ug/m‡ Air1010090-10 DUP-3 Dichlorodifluoromethane TO-15 5.1 ug/m‡ Air1010090-10 DUP-3 Ethylbenzene TO-15 27 ug/m‡ Air1010090-10 DUP-3 Heptane TO-15 36 ug/m‡ Air1010090-10 DUP-3 Hexane TO-15 4.0 J ug/m‡ Air1010090-10 DUP-3 Isopropyl alcohol TO-15 15 ug/m‡ Air1010090-10 DUP-3 m,p-Xylenes TO-15 2.8 J ug/m‡ Air1010090-10 DUP-3 Methyl Ethyl Ketone (2-Butanone)TO-15 2.6 J ug/m‡ Air1010090-10 DUP-3 Methylene Chloride TO-15 4.6 ug/m‡ Air1010090-10 DUP-3 o-Xylene TO-15 14 ug/m‡ Air1010090-10 DUP-3 Tetrachloroethylene TO-15 88 ug/m‡ Air1010090-10 DUP-3 Toluene TO-15 81 ug/m‡ Air1010090-10 DUP-3 trans-1,2-Dichloroethylene TO-15 1300 ug/m‡ Air1010090-10 DUP-3 Trichloroethylene TO-15 4.4 ug/m‡ Air1010090-10 DUP-3 Vinyl chloride TO-15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-8 Sample ID: 1010090-01 Work Order: 1010090 Time Collected: 01/04/21 11:55 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 16:06 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A050513.4 1/7/21 16:06 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 16:06 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 16:06 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 16:06 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 16:06 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 16:06 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 16:06 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 16:06 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 16:06 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 16:06 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 16:06 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 16:06 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 16:06 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 16:06 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 16:06 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 16:06 CBMug/m‡ Air 0.59Acetone9.5 TO-15 P1A050511.6 1/7/21 16:06 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 16:06 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 16:06 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 16:06 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 16:06 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 16:06 CBMJug/m‡ Air 1.6Carbon disulfide 1.9 TO-15 P1A050513.1 1/7/21 16:06 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 16:06 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 16:06 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 16:06 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A050511.0 1/7/21 16:06 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 16:06 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 16:06 CBMJug/m‡ Air 0.87Cyclohexane2.5 TO-15 P1A050514.3 1/7/21 16:06 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 16:06 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.1 TO-15 P1A050511.8 1/7/21 16:06 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 16:06 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 16:06 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 16:06 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 16:06 CBMug/m‡ Air 0.17Isopropyl alcohol 7.7 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-8 Sample ID: 1010090-01 Work Order: 1010090 Time Collected: 01/04/21 11:55 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 16:06 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 16:06 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)0.94 TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone 4.6 TO-15 P1A050511.7 1/7/21 16:06 CBMug/m‡ Air 0.39Methylene Chloride 6.9 TO-15 P1A050511.8 1/7/21 16:06 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 16:06 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 16:06 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A050510.86 1/7/21 16:06 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 16:06 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 16:06 CBMJug/m‡ Air 0.44Tetrachloroethylene3.1 TO-15 P1A050511.5 1/7/21 16:06 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 16:06 CBMug/m‡ Air 0.75Toluene2.3 TO-15 P1A050512.0 1/7/21 16:06 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 16:06 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 16:06 CBMug/m‡ Air 0.27Trichloroethylene4.1 TO-15 P1A050512.8 1/7/21 16:06 CBMJug/m‡ Air 0.43Trichlorofluoromethane1.2 TO-15 P1A050511.8 1/7/21 16:06 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 16:06 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13085 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-7 Sample ID: 1010090-02 Work Order: 1010090 Time Collected: 01/04/21 12:35 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 16:58 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A050513.4 1/7/21 16:58 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 16:58 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 16:58 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 16:58 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 16:58 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 16:58 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 16:58 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 16:58 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 16:58 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 16:58 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 16:58 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 16:58 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 16:58 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 16:58 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 16:58 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 16:58 CBMug/m‡ Air 0.59Acetone7.0 TO-15 P1A050511.6 1/7/21 16:58 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 16:58 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 16:58 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 16:58 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 16:58 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 16:58 CBMJug/m‡ Air 1.6Carbon disulfide 2.2 TO-15 P1A050513.1 1/7/21 16:58 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 16:58 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 16:58 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 16:58 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A050511.0 1/7/21 16:58 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 16:58 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 16:58 CBMug/m‡ Air 0.87Cyclohexane6.4 TO-15 P1A050514.3 1/7/21 16:58 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 16:58 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.1 TO-15 P1A050511.8 1/7/21 16:58 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 16:58 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 16:58 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 16:58 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 16:58 CBMug/m‡ Air 0.17Isopropyl alcohol 8.9 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-7 Sample ID: 1010090-02 Work Order: 1010090 Time Collected: 01/04/21 12:35 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 16:58 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 16:58 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)0.83 TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone 4.6 TO-15 P1A050511.7 1/7/21 16:58 CBMug/m‡ Air 0.39Methylene Chloride 5.9 TO-15 P1A050511.8 1/7/21 16:58 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 16:58 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 16:58 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A050510.86 1/7/21 16:58 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 16:58 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 16:58 CBMug/m‡ Air 0.44Tetrachloroethylene4.9 TO-15 P1A050511.5 1/7/21 16:58 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 16:58 CBMJug/m‡ Air 0.75Toluene0.87 TO-15 P1A050512.0 1/7/21 16:58 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 16:58 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 16:58 CBMug/m‡ Air 0.27Trichloroethylene8.7 TO-15 P1A050512.8 1/7/21 16:58 CBMJug/m‡ Air 0.43Trichlorofluoromethane1.9 TO-15 P1A050511.8 1/7/21 16:58 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 16:58 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13083 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-5 Sample ID: 1010090-03 Work Order: 1010090 Time Collected: 01/04/21 14:10 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 17:53 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A050513.4 1/7/21 17:53 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 17:53 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 17:53 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 17:53 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 17:53 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene 5.5 TO-15 P1A050513.8 1/7/21 17:53 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 17:53 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 17:53 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 17:53 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 17:53 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 17:53 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 17:53 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 17:53 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 17:53 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 17:53 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 17:53 CBMug/m‡ Air 0.59Acetone53 TO-15 P1A050511.6 1/7/21 17:53 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 17:53 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 17:53 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 17:53 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 17:53 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 17:53 CBMJug/m‡ Air 1.6Carbon disulfide 3.5 TO-15 P1A050513.1 1/7/21 17:53 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 17:53 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 17:53 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 17:53 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A050511.0 1/7/21 17:53 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 17:53 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 17:53 CBMug/m‡ Air 0.87Cyclohexane4.2 TO-15 P1A050514.3 1/7/21 17:53 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 17:53 CBMug/m‡ Air 0.41Dichlorodifluoromethane5.6 TO-15 P1A050511.8 1/7/21 17:53 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 17:53 CBMJug/m‡ Air 0.19Ethylbenzene1.5 TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 17:53 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 17:53 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 17:53 CBMug/m‡ Air 0.17Isopropyl alcohol 12 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-5 Sample ID: 1010090-03 Work Order: 1010090 Time Collected: 01/04/21 14:10 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 17:53 CBMJug/m‡ Air 0.38m,p-Xylenes 5.1 TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 17:53 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)4.7 TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone 5.8 TO-15 P1A050511.7 1/7/21 17:53 CBMug/m‡ Air 0.39Methylene Chloride 6.7 TO-15 P1A050511.8 1/7/21 17:53 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 17:53 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 17:53 CBMJug/m‡ Air 0.18o-Xylene 1.9 TO-15 P1A050510.86 1/7/21 17:53 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 17:53 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 17:53 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A050511.5 1/7/21 17:53 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 17:53 CBMug/m‡ Air 0.75Toluene2.3 TO-15 P1A050512.0 1/7/21 17:53 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 17:53 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 17:53 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A050512.8 1/7/21 17:53 CBMJug/m‡ Air 0.43Trichlorofluoromethane2.2 TO-15 P1A050511.8 1/7/21 17:53 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 17:53 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13086 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-4 Sample ID: 1010090-04 Work Order: 1010090 Time Collected: 01/04/21 09:05 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 18:46 CBMug/m‡ Air 0.291,1,1-Trichloroethane 3.7 TO-15 P1A050513.4 1/7/21 18:46 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 18:46 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 18:46 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 18:46 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 18:46 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 18:46 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 18:46 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 18:46 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 18:46 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 18:46 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 18:46 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 18:46 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 18:46 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 18:46 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 18:46 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 18:46 CBMug/m‡ Air 0.59Acetone7.2 TO-15 P1A050511.6 1/7/21 18:46 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 18:46 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 18:46 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 18:46 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 18:46 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 18:46 CBMJug/m‡ Air 1.6Carbon disulfide 2.7 TO-15 P1A050513.1 1/7/21 18:46 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 18:46 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 18:46 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 18:46 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A050511.0 1/7/21 18:46 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 18:46 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 18:46 CBMJug/m‡ Air 0.87Cyclohexane2.3 TO-15 P1A050514.3 1/7/21 18:46 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 18:46 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.3 TO-15 P1A050511.8 1/7/21 18:46 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 18:46 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 18:46 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 18:46 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 18:46 CBMug/m‡ Air 0.17Isopropyl alcohol 5.4 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-4 Sample ID: 1010090-04 Work Order: 1010090 Time Collected: 01/04/21 09:05 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 18:46 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 18:46 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)0.74 TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P1A050511.7 1/7/21 18:46 CBMug/m‡ Air 0.39Methylene Chloride BDL TO-15 P1A050511.8 1/7/21 18:46 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 18:46 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 18:46 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A050510.86 1/7/21 18:46 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 18:46 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 18:46 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A050511.5 1/7/21 18:46 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 18:46 CBMug/m‡ Air 0.75TolueneBDL TO-15 P1A050512.0 1/7/21 18:46 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 18:46 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 18:46 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A050512.8 1/7/21 18:46 CBMug/m‡ Air 0.43TrichlorofluoromethaneBDL TO-15 P1A050511.8 1/7/21 18:46 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 18:46 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13085 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-3 Sample ID: 1010090-05 Work Order: 1010090 Time Collected: 01/04/21 09:50 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 19:39 CBMug/m‡ Air 0.291,1,1-Trichloroethane 13 TO-15 P1A050513.4 1/7/21 19:39 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 19:39 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 19:39 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 19:39 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 19:39 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 19:39 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 19:39 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 19:39 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 19:39 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 19:39 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 19:39 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 19:39 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 19:39 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 19:39 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 19:39 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 19:39 CBMug/m‡ Air 0.59Acetone6.0 TO-15 P1A050511.6 1/7/21 19:39 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 19:39 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 19:39 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 19:39 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 19:39 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 19:39 CBMJug/m‡ Air 1.6Carbon disulfide 2.6 TO-15 P1A050513.1 1/7/21 19:39 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 19:39 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 19:39 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 19:39 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A050511.0 1/7/21 19:39 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 19:39 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 19:39 CBMug/m‡ Air 0.87CyclohexaneBDL TO-15 P1A050514.3 1/7/21 19:39 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 19:39 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.7 TO-15 P1A050511.8 1/7/21 19:39 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 19:39 CBMug/m‡ Air 0.19Ethylbenzene5.1 TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 19:39 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 19:39 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 19:39 CBMug/m‡ Air 0.17Isopropyl alcohol 5.7 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-3 Sample ID: 1010090-05 Work Order: 1010090 Time Collected: 01/04/21 09:50 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 19:39 CBMug/m‡ Air 0.38m,p-Xylenes 40 TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 19:39 CBMJug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.0 TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P1A050511.7 1/7/21 19:39 CBMug/m‡ Air 0.39Methylene Chloride 2.2 TO-15 P1A050511.8 1/7/21 19:39 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 19:39 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 19:39 CBMug/m‡ Air 0.18o-Xylene 15 TO-15 P1A050510.86 1/7/21 19:39 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 19:39 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 19:39 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A050511.5 1/7/21 19:39 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 19:39 CBMug/m‡ Air 0.75TolueneBDL TO-15 P1A050512.0 1/7/21 19:39 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 19:39 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 19:39 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A050512.8 1/7/21 19:39 CBMJug/m‡ Air 0.43Trichlorofluoromethane2.0 TO-15 P1A050511.8 1/7/21 19:39 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 19:39 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13092 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-1 Sample ID: 1010090-06 Work Order: 1010090 Time Collected: 01/04/21 11:15 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 20:31 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A050513.4 1/7/21 20:31 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 20:31 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 20:31 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 20:31 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 20:31 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 20:31 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 20:31 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 20:31 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 20:31 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 20:31 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 20:31 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 20:31 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 20:31 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 20:31 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 20:31 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 20:31 CBMug/m‡ Air 0.59Acetone29 TO-15 P1A050511.6 1/7/21 20:31 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 20:31 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 20:31 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 20:31 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 20:31 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 20:31 CBMJug/m‡ Air 1.6Carbon disulfide 1.8 TO-15 P1A050513.1 1/7/21 20:31 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 20:31 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 20:31 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 20:31 CBMJug/m‡ Air 0.26Chloroform1.5 TO-15 P1A050511.0 1/7/21 20:31 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 20:31 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 20:31 CBMug/m‡ Air 0.87CyclohexaneBDL TO-15 P1A050514.3 1/7/21 20:31 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 20:31 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.1 TO-15 P1A050511.8 1/7/21 20:31 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 20:31 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 20:31 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 20:31 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 20:31 CBMJug/m‡ Air 0.17Isopropyl alcohol 3.5 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-1 Sample ID: 1010090-06 Work Order: 1010090 Time Collected: 01/04/21 11:15 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 20:31 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 20:31 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.5 TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P1A050511.7 1/7/21 20:31 CBMug/m‡ Air 0.39Methylene Chloride 1.9 TO-15 P1A050511.8 1/7/21 20:31 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 20:31 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 20:31 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A050510.86 1/7/21 20:31 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 20:31 CBMug/m‡ Air 0.15Styrene5.1 TO-15 P1A050513.4 1/7/21 20:31 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A050511.5 1/7/21 20:31 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 20:31 CBMug/m‡ Air 0.75TolueneBDL TO-15 P1A050512.0 1/7/21 20:31 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 20:31 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 20:31 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A050512.8 1/7/21 20:31 CBMug/m‡ Air 0.43TrichlorofluoromethaneBDL TO-15 P1A050511.8 1/7/21 20:31 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 20:31 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13089 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-6 Sample ID: 1010090-07 Work Order: 1010090 Time Collected: 01/04/21 13:25 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 21:24 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A050513.4 1/7/21 21:24 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 21:24 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 21:24 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 21:24 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 21:24 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 21:24 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 21:24 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 21:24 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 21:24 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 21:24 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 21:24 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 21:24 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 21:24 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 21:24 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 21:24 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 21:24 CBMug/m‡ Air 0.59Acetone16 TO-15 P1A050511.6 1/7/21 21:24 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 21:24 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 21:24 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 21:24 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 21:24 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 21:24 CBMJug/m‡ Air 1.6Carbon disulfide 3.1 TO-15 P1A050513.1 1/7/21 21:24 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 21:24 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 21:24 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 21:24 CBMug/m‡ Air 0.26ChloroformBDL TO-15 P1A050511.0 1/7/21 21:24 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 21:24 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 21:24 CBMug/m‡ Air 0.87CyclohexaneBDL TO-15 P1A050514.3 1/7/21 21:24 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 21:24 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.2 TO-15 P1A050511.8 1/7/21 21:24 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 21:24 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 21:24 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 21:24 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 21:24 CBMJug/m‡ Air 0.17Isopropyl alcohol 4.2 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-6 Sample ID: 1010090-07 Work Order: 1010090 Time Collected: 01/04/21 13:25 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 21:24 CBMJug/m‡ Air 0.38m,p-Xylenes 1.8 TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 21:24 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.5 TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P1A050511.7 1/7/21 21:24 CBMug/m‡ Air 0.39Methylene Chloride 2.2 TO-15 P1A050511.8 1/7/21 21:24 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 21:24 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 21:24 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A050510.86 1/7/21 21:24 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 21:24 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 21:24 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A050511.5 1/7/21 21:24 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 21:24 CBMJug/m‡ Air 0.75Toluene1.4 TO-15 P1A050512.0 1/7/21 21:24 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 21:24 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 21:24 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A050512.8 1/7/21 21:24 CBMJug/m‡ Air 0.43Trichlorofluoromethane2.0 TO-15 P1A050511.8 1/7/21 21:24 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 21:24 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13090 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-2 Sample ID: 1010090-08 Work Order: 1010090 Time Collected: 01/04/21 10:40 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050512.7 1/7/21 22:16 CBMug/m‡ Air 0.291,1,1-Trichloroethane BDL TO-15 P1A050513.4 1/7/21 22:16 CBMug/m‡ Air 0.281,1,2,2-Tetrachloroethane BDL TO-15 P1A050513.8 1/7/21 22:16 CBMug/m‡ Air 0.531,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050512.7 1/7/21 22:16 CBMug/m‡ Air 0.351,1,2-Trichloroethane BDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.471,1-Dichloroethane BDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.411,1-Dichloroethylene BDL TO-15 P1A050513.7 1/7/21 22:16 CBMug/m‡ Air 0.251,2,4-Trichlorobenzene BDL TO-15 P1A050512.5 1/7/21 22:16 CBMug/m‡ Air 0.291,2,4-Trimethylbenzene BDL TO-15 P1A050513.8 1/7/21 22:16 CBMug/m‡ Air 0.611,2-Dibromoethane BDL TO-15 P1A050513.0 1/7/21 22:16 CBMug/m‡ Air 0.481,2-Dichlorobenzene BDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.221,2-Dichloroethane BDL TO-15 P1A050512.3 1/7/21 22:16 CBMug/m‡ Air 0.401,2-Dichloropropane BDL TO-15 P1A050513.5 1/7/21 22:16 CBMug/m‡ Air 0.621,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050512.5 1/7/21 22:16 CBMug/m‡ Air 0.261,3,5-Trimethylbenzene BDL TO-15 P1A050511.1 1/7/21 22:16 CBMug/m‡ Air 0.191,3-Butadiene BDL TO-15 P1A050513.0 1/7/21 22:16 CBMug/m‡ Air 0.211,3-Dichlorobenzene BDL TO-15 P1A050513.0 1/7/21 22:16 CBMug/m‡ Air 0.251,4-Dichlorobenzene BDL TO-15 P1A050511.8 1/7/21 22:16 CBMug/m‡ Air 0.101,4-Dioxane BDL TO-15 P1A050512.5 1/7/21 22:16 CBMug/m‡ Air 0.264-Ethyltoluene BDL TO-15 P1A050512.4 1/7/21 22:16 CBMug/m‡ Air 0.59Acetone24 TO-15 P1A050511.6 1/7/21 22:16 CBMug/m‡ Air 0.16BenzeneBDL TO-15 P1A050512.6 1/7/21 22:16 CBMug/m‡ Air 0.20Benzyl chloride BDL TO-15 P1A050513.4 1/7/21 22:16 CBMug/m‡ Air 0.26BromodichloromethaneBDL TO-15 P1A050515.2 1/7/21 22:16 CBMug/m‡ Air 0.45BromoformBDL TO-15 P1A050511.9 1/7/21 22:16 CBMug/m‡ Air 0.32BromomethaneBDL TO-15 P1A050516.2 1/7/21 22:16 CBMJug/m‡ Air 1.6Carbon disulfide 3.1 TO-15 P1A050513.1 1/7/21 22:16 CBMug/m‡ Air 0.24Carbon Tetrachloride BDL TO-15 P1A050512.3 1/7/21 22:16 CBMug/m‡ Air 0.17ChlorobenzeneBDL TO-15 P1A050511.3 1/7/21 22:16 CBMug/m‡ Air 0.38ChloroethaneBDL TO-15 P1A050512.4 1/7/21 22:16 CBMJug/m‡ Air 0.26Chloroform1.6 TO-15 P1A050511.0 1/7/21 22:16 CBMug/m‡ Air 0.26ChloromethaneBDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.52cis-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 22:16 CBMug/m‡ Air 0.16cis-1,3-Dichloropropylene BDL TO-15 P1A050513.4 1/7/21 22:16 CBMug/m‡ Air 0.87CyclohexaneBDL TO-15 P1A050514.3 1/7/21 22:16 CBMug/m‡ Air 0.48DibromochloromethaneBDL TO-15 P1A050512.5 1/7/21 22:16 CBMug/m‡ Air 0.41Dichlorodifluoromethane3.3 TO-15 P1A050511.8 1/7/21 22:16 CBMug/m‡ Air 0.25Ethyl Acetate BDL TO-15 P1A050512.2 1/7/21 22:16 CBMug/m‡ Air 0.19EthylbenzeneBDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.19HeptaneBDL TO-15 P1A050515.3 1/7/21 22:16 CBMug/m‡ Air 0.43HexachlorobutadieneBDL TO-15 P1A050511.8 1/7/21 22:16 CBMug/m‡ Air 0.25HexaneBDL TO-15 P1A050514.9 1/7/21 22:16 CBMJug/m‡ Air 0.17Isopropyl alcohol 4.2 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SS-2 Sample ID: 1010090-08 Work Order: 1010090 Time Collected: 01/04/21 10:40 Time Submitted: 01/04/21 16:00 TO-15 P1A050515.6 1/7/21 22:16 CBMug/m‡ Air 0.38m,p-Xylenes BDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.26Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050511.5 1/7/21 22:16 CBMug/m‡ Air 0.30Methyl Ethyl Ketone (2-Butanone)1.7 TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.26Methyl Isobutyl Ketone BDL TO-15 P1A050511.7 1/7/21 22:16 CBMug/m‡ Air 0.39Methylene Chloride 2.1 TO-15 P1A050511.8 1/7/21 22:16 CBMug/m‡ Air 0.21Methyl-tert-Butyl Ether BDL TO-15 P1A050512.6 1/7/21 22:16 CBMug/m‡ Air 1.0NaphthaleneBDL TO-15 P1A050512.2 1/7/21 22:16 CBMug/m‡ Air 0.18o-Xylene BDL TO-15 P1A050510.86 1/7/21 22:16 CBMug/m‡ Air 0.14PropyleneBDL TO-15 P1A050512.1 1/7/21 22:16 CBMug/m‡ Air 0.15StyreneBDL TO-15 P1A050513.4 1/7/21 22:16 CBMug/m‡ Air 0.44TetrachloroethyleneBDL TO-15 P1A050511.5 1/7/21 22:16 CBMug/m‡ Air 0.21TetrahydrofuranBDL TO-15 P1A050511.9 1/7/21 22:16 CBMug/m‡ Air 0.75TolueneBDL TO-15 P1A050512.0 1/7/21 22:16 CBMug/m‡ Air 0.48trans-1,2-Dichloroethylene BDL TO-15 P1A050512.3 1/7/21 22:16 CBMug/m‡ Air 0.17trans-1,3-Dichloropropylene BDL TO-15 P1A050512.7 1/7/21 22:16 CBMug/m‡ Air 0.27TrichloroethyleneBDL TO-15 P1A050512.8 1/7/21 22:16 CBMug/m‡ Air 0.43TrichlorofluoromethaneBDL TO-15 P1A050511.8 1/7/21 22:16 CBMug/m‡ Air 0.25Vinyl acetate BDL TO-15 P1A050511.3 1/7/21 22:16 CBMug/m‡ Air 0.29Vinyl chloride BDL Surrogate Recovery Control Limits 70-13086 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SG-1 Sample ID: 1010090-09 Work Order: 1010090 Time Collected: 01/04/21 14:45 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050525.5 1/7/21 23:01 CBMug/m‡ Air 0.581,1,1-Trichloroethane BDL TO-15 P1A050526.9 1/7/21 23:01 CBMug/m‡ Air 0.561,1,2,2-Tetrachloroethane BDL TO-15 P1A050527.7 1/7/21 23:01 CBMug/m‡ Air 1.11,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050525.5 1/7/21 23:01 CBMug/m‡ Air 0.711,1,2-Trichloroethane BDL TO-15 P1A050524.0 1/7/21 23:01 CBMJug/m‡ Air 0.951,1-Dichloroethane 2.4 TO-15 P1A050524.0 1/7/21 23:01 CBMug/m‡ Air 0.821,1-Dichloroethylene 81 TO-15 P1A050527.4 1/7/21 23:01 CBMug/m‡ Air 0.501,2,4-Trichlorobenzene BDL TO-15 P1A050524.9 1/7/21 23:01 CBMug/m‡ Air 0.591,2,4-Trimethylbenzene 11 TO-15 P1A050527.7 1/7/21 23:01 CBMug/m‡ Air 1.21,2-Dibromoethane BDL TO-15 P1A050526.0 1/7/21 23:01 CBMug/m‡ Air 0.971,2-Dichlorobenzene BDL TO-15 P1A050524.0 1/7/21 23:01 CBMug/m‡ Air 0.441,2-Dichloroethane BDL TO-15 P1A050524.6 1/7/21 23:01 CBMug/m‡ Air 0.801,2-Dichloropropane BDL TO-15 P1A050527.0 1/7/21 23:01 CBMug/m‡ Air 1.21,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050524.9 1/7/21 23:01 CBMug/m‡ Air 0.521,3,5-Trimethylbenzene BDL TO-15 P1A050522.2 1/7/21 23:01 CBMug/m‡ Air 0.391,3-Butadiene BDL TO-15 P1A050526.0 1/7/21 23:01 CBMug/m‡ Air 0.431,3-Dichlorobenzene BDL TO-15 P1A050526.0 1/7/21 23:01 CBMug/m‡ Air 0.511,4-Dichlorobenzene BDL TO-15 P1A050523.6 1/7/21 23:01 CBMug/m‡ Air 0.201,4-Dioxane BDL TO-15 P1A050524.9 1/7/21 23:01 CBMug/m‡ Air 0.534-Ethyltoluene BDL TO-15 P1A050524.8 1/7/21 23:01 CBMug/m‡ Air 1.2Acetone9.2 TO-15 P1A050523.2 1/7/21 23:01 CBMug/m‡ Air 0.32Benzene52 TO-15 P1A050525.2 1/7/21 23:01 CBMug/m‡ Air 0.40Benzyl chloride BDL TO-15 P1A050526.7 1/7/21 23:01 CBMug/m‡ Air 0.51BromodichloromethaneBDL TO-15 P1A05052101/7/21 23:01 CBMug/m‡ Air 0.90BromoformBDL TO-15 P1A050523.9 1/7/21 23:01 CBMug/m‡ Air 0.64BromomethaneBDL TO-15 P1A0505201201/6/21 2:48 CBMug/m‡ Air 31Carbon disulfide 880 TO-15 P1A050526.3 1/7/21 23:01 CBMug/m‡ Air 0.48Carbon Tetrachloride BDL TO-15 P1A050524.6 1/7/21 23:01 CBMug/m‡ Air 0.33ChlorobenzeneBDL TO-15 P1A050522.6 1/7/21 23:01 CBMug/m‡ Air 0.77Chloroethane7.5 TO-15 P1A050524.9 1/7/21 23:01 CBMug/m‡ Air 0.52ChloroformBDL TO-15 P1A050522.1 1/7/21 23:01 CBMug/m‡ Air 0.53ChloromethaneBDL TO-15 P1A050524.0 1/7/21 23:01 CBMug/m‡ Air 1.0cis-1,2-Dichloroethylene 42 TO-15 P1A050524.5 1/7/21 23:01 CBMug/m‡ Air 0.32cis-1,3-Dichloropropylene BDL TO-15 P1A050526.9 1/7/21 23:01 CBMug/m‡ Air 1.7Cyclohexane21 TO-15 P1A050528.5 1/7/21 23:01 CBMug/m‡ Air 0.96DibromochloromethaneBDL TO-15 P1A050524.9 1/7/21 23:01 CBMJug/m‡ Air 0.82Dichlorodifluoromethane2.9 TO-15 P1A050523.6 1/7/21 23:01 CBMug/m‡ Air 0.50Ethyl Acetate BDL TO-15 P1A050524.3 1/7/21 23:01 CBMug/m‡ Air 0.38Ethylbenzene5.0 TO-15 P1A050524.1 1/7/21 23:01 CBMug/m‡ Air 0.39Heptane26 TO-15 P1A05052111/7/21 23:01 CBMug/m‡ Air 0.85HexachlorobutadieneBDL TO-15 P1A050523.5 1/7/21 23:01 CBMug/m‡ Air 0.51Hexane37 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: SG-1 Sample ID: 1010090-09 Work Order: 1010090 Time Collected: 01/04/21 14:45 Time Submitted: 01/04/21 16:00 TO-15 P1A050529.8 1/7/21 23:01 CBMug/m‡ Air 0.33Isopropyl alcohol BDL TO-15 P1A05052111/7/21 23:01 CBMug/m‡ Air 0.77m,p-Xylenes 15 TO-15 P1A050524.1 1/7/21 23:01 CBMug/m‡ Air 0.51Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050522.9 1/7/21 23:01 CBMug/m‡ Air 0.60Methyl Ethyl Ketone (2-Butanone)3.1 TO-15 P1A050524.1 1/7/21 23:01 CBMug/m‡ Air 0.51Methyl Isobutyl Ketone BDL TO-15 P1A050523.5 1/7/21 23:01 CBMug/m‡ Air 0.77Methylene Chloride 4.3 TO-15 P1A050523.6 1/7/21 23:01 CBMug/m‡ Air 0.41Methyl-tert-Butyl Ether BDL TO-15 P1A050525.2 1/7/21 23:01 CBMug/m‡ Air 2.1NaphthaleneBDL TO-15 P1A050524.3 1/7/21 23:01 CBMug/m‡ Air 0.37o-Xylene 4.3 TO-15 P1A050521.7 1/7/21 23:01 CBMug/m‡ Air 0.28PropyleneBDL TO-15 P1A050524.3 1/7/21 23:01 CBMug/m‡ Air 0.30StyreneBDL TO-15 P1A050526.8 1/7/21 23:01 CBMug/m‡ Air 0.88Tetrachloroethylene14 TO-15 P1A050522.9 1/7/21 23:01 CBMug/m‡ Air 0.42TetrahydrofuranBDL TO-15 P1A050523.8 1/7/21 23:01 CBMug/m‡ Air 1.5Toluene90 TO-15 P1A050524.0 1/7/21 23:01 CBMug/m‡ Air 0.96trans-1,2-Dichloroethylene 81 TO-15 P1A050524.5 1/7/21 23:01 CBMug/m‡ Air 0.35trans-1,3-Dichloropropylene BDL TO-15 P1A050520541/6/21 2:48 CBMug/m‡ Air 5.5Trichloroethylene1400 TO-15 P1A050525.6 1/7/21 23:01 CBMug/m‡ Air 0.87TrichlorofluoromethaneBDL TO-15 P1A050523.5 1/7/21 23:01 CBMug/m‡ Air 0.51Vinyl acetate BDL TO-15 P1A050522.6 1/7/21 23:01 CBMug/m‡ Air 0.57Vinyl chloride 4.4 Surrogate Recovery Control Limits 70-13090 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: DUP-3 Sample ID: 1010090-10 Work Order: 1010090 Time Collected: 01/04/21 14:45 Time Submitted: 01/04/21 16:00 Volatile Organic Compounds by GC/MS TO-15 P1A050525.5 1/7/21 23:45 CBMug/m‡ Air 0.581,1,1-Trichloroethane BDL TO-15 P1A050526.9 1/7/21 23:45 CBMug/m‡ Air 0.561,1,2,2-Tetrachloroethane BDL TO-15 P1A050527.7 1/7/21 23:45 CBMug/m‡ Air 1.11,1,2-Trichloro-1,2,2-trifluoroethane BDL TO-15 P1A050525.5 1/7/21 23:45 CBMug/m‡ Air 0.711,1,2-Trichloroethane BDL TO-15 P1A050524.0 1/7/21 23:45 CBMJug/m‡ Air 0.951,1-Dichloroethane 2.3 TO-15 P1A050524.0 1/7/21 23:45 CBMug/m‡ Air 0.821,1-Dichloroethylene 80 TO-15 P1A050527.4 1/7/21 23:45 CBMug/m‡ Air 0.501,2,4-Trichlorobenzene BDL TO-15 P1A050524.9 1/7/21 23:45 CBMug/m‡ Air 0.591,2,4-Trimethylbenzene 11 TO-15 P1A050527.7 1/7/21 23:45 CBMug/m‡ Air 1.21,2-Dibromoethane BDL TO-15 P1A050526.0 1/7/21 23:45 CBMug/m‡ Air 0.971,2-Dichlorobenzene BDL TO-15 P1A050524.0 1/7/21 23:45 CBMug/m‡ Air 0.441,2-Dichloroethane BDL TO-15 P1A050524.6 1/7/21 23:45 CBMug/m‡ Air 0.801,2-Dichloropropane BDL TO-15 P1A050527.0 1/7/21 23:45 CBMug/m‡ Air 1.21,2-Dichloro-1,1,2,2-tetrafluoroethane BDL TO-15 P1A050524.9 1/7/21 23:45 CBMug/m‡ Air 0.521,3,5-Trimethylbenzene BDL TO-15 P1A050522.2 1/7/21 23:45 CBMug/m‡ Air 0.391,3-Butadiene BDL TO-15 P1A050526.0 1/7/21 23:45 CBMug/m‡ Air 0.431,3-Dichlorobenzene BDL TO-15 P1A050526.0 1/7/21 23:45 CBMug/m‡ Air 0.511,4-Dichlorobenzene BDL TO-15 P1A050523.6 1/7/21 23:45 CBMug/m‡ Air 0.201,4-Dioxane BDL TO-15 P1A050524.9 1/7/21 23:45 CBMug/m‡ Air 0.534-Ethyltoluene BDL TO-15 P1A050524.8 1/7/21 23:45 CBMug/m‡ Air 1.2Acetone7.3 TO-15 P1A050523.2 1/7/21 23:45 CBMug/m‡ Air 0.32Benzene52 TO-15 P1A050525.2 1/7/21 23:45 CBMug/m‡ Air 0.40Benzyl chloride BDL TO-15 P1A050526.7 1/7/21 23:45 CBMug/m‡ Air 0.51BromodichloromethaneBDL TO-15 P1A05052101/7/21 23:45 CBMug/m‡ Air 0.90BromoformBDL TO-15 P1A050523.9 1/7/21 23:45 CBMug/m‡ Air 0.64BromomethaneBDL TO-15 P1A0505201201/6/21 3:27 CBMug/m‡ Air 31Carbon disulfide 830 TO-15 P1A050526.3 1/7/21 23:45 CBMug/m‡ Air 0.48Carbon Tetrachloride BDL TO-15 P1A050524.6 1/7/21 23:45 CBMug/m‡ Air 0.33ChlorobenzeneBDL TO-15 P1A050522.6 1/7/21 23:45 CBMug/m‡ Air 0.77Chloroethane7.8 TO-15 P1A050524.9 1/7/21 23:45 CBMug/m‡ Air 0.52ChloroformBDL TO-15 P1A050522.1 1/7/21 23:45 CBMug/m‡ Air 0.53ChloromethaneBDL TO-15 P1A050524.0 1/7/21 23:45 CBMug/m‡ Air 1.0cis-1,2-Dichloroethylene 42 TO-15 P1A050524.5 1/7/21 23:45 CBMug/m‡ Air 0.32cis-1,3-Dichloropropylene BDL TO-15 P1A050526.9 1/7/21 23:45 CBMug/m‡ Air 1.7Cyclohexane22 TO-15 P1A050528.5 1/7/21 23:45 CBMug/m‡ Air 0.96DibromochloromethaneBDL TO-15 P1A050524.9 1/7/21 23:45 CBMJug/m‡ Air 0.82Dichlorodifluoromethane2.9 TO-15 P1A050523.6 1/7/21 23:45 CBMug/m‡ Air 0.50Ethyl Acetate BDL TO-15 P1A050524.3 1/7/21 23:45 CBMug/m‡ Air 0.38Ethylbenzene5.1 TO-15 P1A050524.1 1/7/21 23:45 CBMug/m‡ Air 0.39Heptane27 TO-15 P1A05052111/7/21 23:45 CBMug/m‡ Air 0.85HexachlorobutadieneBDL TO-15 P1A050523.5 1/7/21 23:45 CBMug/m‡ Air 0.51Hexane36 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 32 Laboratory Report 01/08/2021 ResultParameter Batch ID Report Limit Analysis Date/Time MethodDilution Factor Units MDL Analyst 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Sample Matrix: Air Client Sample ID: DUP-3 Sample ID: 1010090-10 Work Order: 1010090 Time Collected: 01/04/21 14:45 Time Submitted: 01/04/21 16:00 TO-15 P1A050529.8 1/7/21 23:45 CBMJug/m‡ Air 0.33Isopropyl alcohol 4.0 TO-15 P1A05052111/7/21 23:45 CBMug/m‡ Air 0.77m,p-Xylenes 15 TO-15 P1A050524.1 1/7/21 23:45 CBMug/m‡ Air 0.51Methyl Butyl Ketone (2-Hexanone)BDL TO-15 P1A050522.9 1/7/21 23:45 CBMJug/m‡ Air 0.60Methyl Ethyl Ketone (2-Butanone)2.8 TO-15 P1A050524.1 1/7/21 23:45 CBMug/m‡ Air 0.51Methyl Isobutyl Ketone BDL TO-15 P1A050523.5 1/7/21 23:45 CBMJug/m‡ Air 0.77Methylene Chloride 2.6 TO-15 P1A050523.6 1/7/21 23:45 CBMug/m‡ Air 0.41Methyl-tert-Butyl Ether BDL TO-15 P1A050525.2 1/7/21 23:45 CBMug/m‡ Air 2.1NaphthaleneBDL TO-15 P1A050524.3 1/7/21 23:45 CBMug/m‡ Air 0.37o-Xylene 4.6 TO-15 P1A050521.7 1/7/21 23:45 CBMug/m‡ Air 0.28PropyleneBDL TO-15 P1A050524.3 1/7/21 23:45 CBMug/m‡ Air 0.30StyreneBDL TO-15 P1A050526.8 1/7/21 23:45 CBMug/m‡ Air 0.88Tetrachloroethylene14 TO-15 P1A050522.9 1/7/21 23:45 CBMug/m‡ Air 0.42TetrahydrofuranBDL TO-15 P1A050523.8 1/7/21 23:45 CBMug/m‡ Air 1.5Toluene88 TO-15 P1A050524.0 1/7/21 23:45 CBMug/m‡ Air 0.96trans-1,2-Dichloroethylene 81 TO-15 P1A050524.5 1/7/21 23:45 CBMug/m‡ Air 0.35trans-1,3-Dichloropropylene BDL TO-15 P1A050520541/6/21 3:27 CBMug/m‡ Air 5.5Trichloroethylene1300 TO-15 P1A050525.6 1/7/21 23:45 CBMug/m‡ Air 0.87TrichlorofluoromethaneBDL TO-15 P1A050523.5 1/7/21 23:45 CBMug/m‡ Air 0.51Vinyl acetate BDL TO-15 P1A050522.6 1/7/21 23:45 CBMug/m‡ Air 0.57Vinyl chloride 4.4 Surrogate Recovery Control Limits 70-13089 %4-Bromofluorobenzene This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 32 1/8/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010090 Time Submitted: 1/4/2021 4:00:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0505 - NO PREP VOA Blank (P1A0505-BLK1)Prepared & Analyzed: 01/07/21 1,1,1-Trichloroethane ug/m‡ AirBRL2.7 1,1,2,2-Tetrachloroethane ug/m‡ AirBRL3.4 1,1,2-Trichloro-1,2,2-trifluoroethane ug/m‡ AirBRL3.8 1,1,2-Trichloroethane ug/m‡ AirBRL2.7 1,1-Dichloroethane ug/m‡ AirBRL2.0 1,1-Dichloroethylene ug/m‡ AirBRL2.0 1,2,4-Trichlorobenzene ug/m‡ AirBRL3.7 1,2,4-Trimethylbenzene ug/m‡ AirBRL2.5 1,2-Dibromoethane ug/m‡ AirBRL3.8 1,2-Dichlorobenzene ug/m‡ AirBRL3.0 1,2-Dichloroethane ug/m‡ AirBRL2.0 1,2-Dichloropropane ug/m‡ AirBRL2.3 1,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m‡ AirBRL3.5 1,3,5-Trimethylbenzene ug/m‡ AirBRL2.5 1,3-Butadiene ug/m‡ AirBRL1.1 1,3-Dichlorobenzene ug/m‡ AirBRL3.0 1,4-Dichlorobenzene ug/m‡ AirBRL3.0 1,4-Dioxane ug/m‡ AirBRL1.8 4-Ethyltoluene ug/m‡ AirBRL2.5 Acetone ug/m‡ AirBRL2.4 Benzene ug/m‡ AirBRL1.6 Benzyl chloride ug/m‡ AirBRL2.6 Bromodichloromethane ug/m‡ AirBRL3.4 Bromoform ug/m‡ AirBRL5.2 Bromomethane ug/m‡ AirBRL1.9 Carbon disulfide ug/m‡ AirBRL6.2 Carbon Tetrachloride ug/m‡ AirBRL3.1 Chlorobenzene ug/m‡ AirBRL2.3 Chloroethane ug/m‡ AirBRL1.3 Chloroform ug/m‡ AirBRL2.4 Chloromethane ug/m‡ AirBRL1.0 cis-1,2-Dichloroethylene ug/m‡ AirBRL2.0 cis-1,3-Dichloropropylene ug/m‡ AirBRL2.3 Cyclohexane ug/m‡ AirBRL3.4 Dibromochloromethane ug/m‡ AirBRL4.3 Dichlorodifluoromethane ug/m‡ AirBRL2.5 Ethyl Acetate ug/m‡ AirBRL1.8 Ethylbenzene ug/m‡ AirBRL2.2 Heptane ug/m‡ AirBRL2.0 Hexachlorobutadiene ug/m‡ AirBRL5.3 Hexane ug/m‡ AirBRL1.8 Isopropyl alcohol ug/m‡ AirBRL4.9 m,p-Xylenes ug/m‡ AirBRL5.6 Methyl Butyl Ketone (2-Hexanone)ug/m‡ AirBRL2.0 Methyl Ethyl Ketone (2-Butanone)ug/m‡ AirBRL1.5 Methyl Isobutyl Ketone ug/m‡ AirBRL2.0 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 32 1/8/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010090 Time Submitted: 1/4/2021 4:00:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0505 - NO PREP VOA Blank (P1A0505-BLK1)Prepared & Analyzed: 01/07/21 Methylene Chloride ug/m‡ AirBRL1.7 Methyl-tert-Butyl Ether ug/m‡ AirBRL1.8 Naphthalene ug/m‡ AirBRL2.6 o-Xylene ug/m‡ AirBRL2.2 Propylene ug/m‡ AirBRL0.86 Styrene ug/m‡ AirBRL2.1 Tetrachloroethylene ug/m‡ AirBRL3.4 Tetrahydrofuran ug/m‡ AirBRL1.5 Toluene ug/m‡ AirBRL1.9 trans-1,2-Dichloroethylene ug/m‡ AirBRL2.0 trans-1,3-Dichloropropylene ug/m‡ AirBRL2.3 Trichloroethylene ug/m‡ AirBRL2.7 Trichlorofluoromethane ug/m‡ AirBRL2.8 Vinyl acetate ug/m‡ AirBRL1.8 Vinyl chloride ug/m‡ AirBRL1.3 ppbv 5.000 70-130Surrogate: 4-Bromofluorobenzene 884.38 LCS (P1A0505-BS1)Prepared & Analyzed: 01/07/21 1,1,1-Trichloroethane ug/m‡ Air25.5 2.7 27.28 70-13093 1,1,2,2-Tetrachloroethane ug/m‡ Air37.3 3.4 34.33 70-130109 1,1,2-Trichloro-1,2,2-trifluoroethane ug/m‡ Air38.9 3.8 38.32 70-130102 1,1,2-Trichloroethane ug/m‡ Air27.3 2.7 27.28 70-130100 1,1-Dichloroethane ug/m‡ Air20.8 2.0 20.24 70-130103 1,1-Dichloroethylene ug/m‡ Air20.2 2.0 19.82 70-130102 1,2,4-Trichlorobenzene ug/m‡ Air43.6 3.7 37.11 70-130118 1,2,4-Trimethylbenzene ug/m‡ Air22.6 2.5 24.58 70-13092 1,2-Dibromoethane ug/m‡ Air38.9 3.8 38.42 70-130101 1,2-Dichlorobenzene ug/m‡ Air30.2 3.0 30.06 70-130100 1,2-Dichloroethane ug/m‡ Air19.2 2.0 20.24 70-13095 1,2-Dichloropropane ug/m‡ Air21.7 2.3 23.11 70-13094 1,2-Dichloro-1,1,2,2-tetrafluoroethane ug/m‡ Air34.5 3.5 34.95 70-13099 1,3,5-Trimethylbenzene ug/m‡ Air27.7 2.5 24.58 70-130113 1,3-Butadiene ug/m‡ Air10.5 1.1 11.06 70-13095 1,3-Dichlorobenzene ug/m‡ Air29.6 3.0 30.06 70-13098 1,4-Dichlorobenzene ug/m‡ Air28.4 3.0 30.06 70-13094 1,4-Dioxane ug/m‡ Air18.0 1.8 18.02 70-130100 4-Ethyltoluene ug/m‡ Air22.4 2.5 24.58 70-13091 Acetone ug/m‡ Air11.9 2.4 11.88 70-130100 Benzene ug/m‡ Air14.9 1.6 15.97 70-13093 Benzyl chloride ug/m‡ Air26.9 2.6 25.89 70-130104 Bromodichloromethane ug/m‡ Air31.9 3.4 33.50 70-13095 Bromoform ug/m‡ Air52.3 5.2 51.69 70-130101 Bromomethane ug/m‡ Air20.3 1.9 19.42 70-130105 Carbon disulfide ug/m‡ Air16.7 6.2 15.57 70-130107 Carbon Tetrachloride ug/m‡ Air29.3 3.1 31.46 70-13093 Chlorobenzene ug/m‡ Air23.4 2.3 23.02 70-130102 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 32 1/8/21 Level II QC Report 2923 South Tryon St. Ste 100 Project: PRO-011Hart & Hickman (Charlotte) Charlotte, NC 28203 Attn: Matt Ingalls Work Order: 1010090 Time Submitted: 1/4/2021 4:00:00PM Result Limit Reporting Units Level Spike Result Source %REC %REC Limits RPD RPD Limit Notes Analyte Volatile Organic Compounds by GC/MS - Quality Control Batch P1A0505 - NO PREP VOA LCS (P1A0505-BS1)Prepared & Analyzed: 01/07/21 Chloroethane ug/m‡ Air13.7 1.3 13.19 70-130104 Chloroform ug/m‡ Air23.7 2.4 24.41 70-13097 Chloromethane ug/m‡ Air10.7 1.0 10.33 70-130103 cis-1,2-Dichloroethylene ug/m‡ Air20.5 2.0 19.82 70-130104 cis-1,3-Dichloropropylene ug/m‡ Air21.7 2.3 22.69 70-13096 Cyclohexane ug/m‡ Air14.7 3.4 17.21 70-13085 Dibromochloromethane ug/m‡ Air43.2 4.3 42.60 70-130101 Dichlorodifluoromethane ug/m‡ Air25.2 2.5 24.73 70-130102 Ethyl Acetate ug/m‡ Air18.4 1.8 18.02 70-130102 Ethylbenzene ug/m‡ Air22.0 2.2 21.71 70-130101 Heptane ug/m‡ Air20.7 2.0 20.49 70-130101 Hexachlorobutadiene ug/m‡ Air59.4 5.3 53.33 70-130111 Hexane ug/m‡ Air18.1 1.8 17.62 70-130103 Isopropyl alcohol ug/m‡ Air11.9 4.9 12.29 70-13097 m,p-Xylenes ug/m‡ Air61.0 5.6 56.49 70-130108 Methyl Butyl Ketone (2-Hexanone)ug/m‡ Air21.5 2.0 20.48 70-130105 Methyl Ethyl Ketone (2-Butanone)ug/m‡ Air15.1 1.5 14.75 70-130102 Methyl Isobutyl Ketone ug/m‡ Air19.4 2.0 20.48 70-13095 Methylene Chloride ug/m‡ Air18.0 1.7 17.37 70-130103 Methyl-tert-Butyl Ether ug/m‡ Air17.4 1.8 18.03 70-13097 Naphthalene ug/m‡ Air27.8 2.6 26.21 64-136106 o-Xylene ug/m‡ Air24.8 2.2 21.71 70-130114 Propylene ug/m‡ Air8.59 0.86 8.605 70-130100 Styrene ug/m‡ Air19.1 2.1 21.30 70-13090 Tetrachloroethylene ug/m‡ Air32.4 3.4 33.91 70-13095 Tetrahydrofuran ug/m‡ Air13.8 1.5 14.75 70-13094 Toluene ug/m‡ Air17.9 1.9 18.84 70-13095 trans-1,2-Dichloroethylene ug/m‡ Air19.9 2.0 19.82 70-130100 trans-1,3-Dichloropropylene ug/m‡ Air21.7 2.3 22.69 70-13096 Trichloroethylene ug/m‡ Air26.0 2.7 26.87 70-13097 Trichlorofluoromethane ug/m‡ Air27.9 2.8 28.09 70-13099 Vinyl acetate ug/m‡ Air17.6 1.8 17.61 70-130100 Vinyl chloride ug/m‡ Air13.1 1.3 12.78 70-130103 ppbv 5.000 70-130Surrogate: 4-Bromofluorobenzene 1035.16 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 32 Sample Extraction Data Prep Method: NO PREP VOA Lab Number Batch Date/TimeInitialFinal P1A05051010090-01 01/07/21 9:00250 250mL mL P1A05051010090-02 01/07/21 9:00250 250mL mL P1A05051010090-03 01/07/21 9:00250 250mL mL P1A05051010090-04 01/07/21 9:00250 250mL mL P1A05051010090-05 01/07/21 9:00250 250mL mL P1A05051010090-06 01/07/21 9:00250 250mL mL P1A05051010090-07 01/07/21 9:00250 250mL mL P1A05051010090-08 01/07/21 9:00250 250mL mL P1A05051010090-09 01/05/21 15:00250 250mL mL P1A05051010090-09 01/05/21 15:00250 250mL mL P1A05051010090-10 01/05/21 15:00250 250mL mL P1A05051010090-10 01/05/21 15:00250 250mL mL This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 32 Page 30 of 32 Page 31 of 32 Page 32 of 32 Appendix C Risk Calculations Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls Worst Case Groundwater North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: Worst Case Groundwater Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: Worst Case Groundwater Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: Worst Case Groundwater Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Worst Case Groundwater Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: Worst Case Groundwater Description of Exposure Point Concentration Selection: NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations Exposure Point Concentration (ug/L)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier)Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 4.1 67-64-1 Acetone ug/L4.8 7440-38-2 Arsenic, Inorganic ug/L1607440-39-3 Barium ug/L7.2 16065-83-1 Chromium(III), Insoluble Salts ug/L2.3 75-34-3 Dichloroethane, 1,1-ug/L0.25 107-06-2 Dichloroethane, 1,2-ug/L3.6 75-35-4 Dichloroethylene, 1,1-ug/L0.98 156-59-2 Dichloroethylene, cis-1,2-ug/L25123-91-1 Dioxane, 1,4-ug/L2.1 75-00-3 Ethyl Chloride (Chloroethane)ug/L6.9 7439-92-1 ~Lead and Compounds ug/L0.038 7439-97-6 ~Mercury (elemental)ug/L0.3 1634-04-4 Methyl tert-Butyl Ether (MTBE)ug/L1.1 7782-49-2 Selenium ug/L0.28 127-18-4 Tetrachloroethylene ug/L0.24 108-88-3 Toluene ug/L2.3 79-01-6 Trichloroethylene ug/L3275-01-4 Vinyl Chloride ug/L Input Form 2B Groundwater Exposure Point Concentration Table Exposure point concentrations reflect maximum detection in site groundwater during Jnauary 6, 2021 groundwater sampling event. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: Worst Case Groundwater Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air 2.2E-04 8.6E-01 YES Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air 1.3E-05 2.0E-01 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: Worst Case Groundwater CAS #Chemical Name:Groundwater Concentration(ug/L) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient67-64-1 Acetone 4.1 -6.5E+03 1.8E-077440-38-2 Arsenic, Inorganic 4.8 6.5E-04 3.1E-037440-39-3 Barium 160 -1.0E-0116065-83-1 Chromium(III), Insoluble Salts 7.2 -- 75-34-3 Dichloroethane, 1,1-2.3 1.8E+00 -3.0E-07107-06-2 Dichloroethane, 1,2-0.25 1.1E-01 1.5E+00 1.1E-07 1.7E-0375-35-4 Dichloroethylene, 1,1-3.6 -4.2E+01 1.8E-02 156-59-2 Dichloroethylene, cis-1,2-0.98 --123-91-1 Dioxane, 1,4-25 5.6E-01 6.3E+00 8.7E-09 1.6E-0475-00-3 Ethyl Chloride (Chloroethane)2.1 -2.1E+03 9.1E-057439-92-1 ~Lead and Compounds 6.9 --7439-97-6 ~Mercury (elemental)0.038 -6.3E-02 4.3E-021634-04-4 Methyl tert-Butyl Ether (MTBE)0.3 1.1E+01 6.3E+02 6.7E-10 2.3E-067782-49-2 Selenium 1.1 -4.2E+00127-18-4 Tetrachloroethylene 0.28 1.1E+01 8.3E+00 1.9E-08 4.9E-03108-88-3 Toluene 0.24 -1.0E+03 1.2E-0579-01-6 Trichloroethylene 2.3 4.8E-01 4.2E-01 1.9E-06 4.4E-0175-01-4 Vinyl Chloride 32 1.7E-01 2.1E+01 2.2E-04 3.5E-01 Cumulative:2.2E-04 8.6E-01 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3A Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: Worst Case Groundwater CAS #Chemical Name:Groundwater Concentration(ug/L) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 4.1 0.005866721 -2.7E+04 4.3E-08 7440-38-2 Arsenic, Inorganic 4.8 2.9E-03 1.3E-02 7440-39-3 Barium 160 -4.4E-01 16065-83-1 Chromium(III), Insoluble Salts 7.2 -- 75-34-3 Dichloroethane, 1,1-2.3 0.52845462 7.7E+00 -6.9E-08 107-06-2 Dichloroethane, 1,2-0.25 0.012060507 4.7E-01 6.1E+00 2.6E-08 3.9E-04 75-35-4 Dichloroethylene, 1,1-3.6 3.841373671 -1.8E+02 4.4E-03 156-59-2 Dichloroethylene, cis-1,2-0.98 0.163466885 -- 123-91-1 Dioxane, 1,4-25 0.004905969 2.5E+00 2.6E+01 2.0E-09 3.7E-05 75-00-3 Ethyl Chloride (Chloroethane)2.1 0.952984464 -8.8E+03 2.2E-05 7439-92-1 ~Lead and Compounds 6.9 -- 7439-97-6 ~Mercury (elemental)0.038 0.013376 -2.6E-01 1.0E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE)0.3 0.007199509 4.7E+01 2.6E+03 1.5E-10 5.5E-07 7782-49-2 Selenium 1.1 -1.8E+01 127-18-4 Tetrachloroethylene 0.28 0.202616517 4.7E+01 3.5E+01 4.3E-09 1.2E-03 108-88-3 Toluene 0.24 0.065151267 -4.4E+03 3.0E-06 79-01-6 Trichloroethylene 2.3 0.926206051 3.0E+00 1.8E+00 3.1E-07 1.1E-01 75-01-4 Vinyl Chloride 32 36.36958299 2.8E+00 8.8E+01 1.3E-05 8.3E-02 Cumulative:1.3E-05 2.0E-01 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3D Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SG-1 / DUP-3 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SG-1 / DUP-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SG-1 / DUP-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SG-1 / DUP-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SG-1 / DUP-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SG-1 / DUP-3 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 9.2 67-64-1 Acetone ug/m3 52 71-43-2 Benzene ug/m3 880 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 22 110-82-7 Cyclohexane ug/m3 2.9 75-71-8 Dichlorodifluoromethane ug/m3 2.4 75-34-3 Dichloroethane, 1,1-ug/m3 81 75-35-4 Dichloroethylene, 1,1-ug/m3 42 156-59-2 Dichloroethylene, cis-1,2-ug/m3 81 156-60-5 Dichloroethylene, trans-1,2-ug/m3 7.8 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 5.1 100-41-4 Ethylbenzene ug/m3 27 142-82-5 Heptane, N-ug/m3 37 110-54-3 Hexane, N-ug/m3 4 67-63-0 Isopropanol ug/m3 3.1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 4.3 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 14 127-18-4 Tetrachloroethylene ug/m3 90 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 1400 79-01-6 Trichloroethylene ug/m3 0 75-69-4 Trichlorofluoromethane ug/m3 11 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 4.4 75-01-4 Vinyl Chloride ug/m3 15 108-38-3 Xylene, m-ug/m3 4.6 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on highest detection between sample SG-1 and its duplicate sample DUP-3. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SG-1 / DUP-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 9.3E-05 2.0E+01 YES Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.0E-06 1.6E+00 YES Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SG-1 / DUP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 9.2 0.276 -6.5E+03 8.5E-06 71-43-2 Benzene 52 1.56 3.6E-01 6.3E+00 4.3E-06 5.0E-02 75-15-0 Carbon Disulfide 880 26.4 -1.5E+02 3.6E-02 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 22 0.66 -1.3E+03 1.1E-04 75-71-8 Dichlorodifluoromethane 2.9 0.087 -2.1E+01 8.3E-04 75-34-3 Dichloroethane, 1,1-2.4 0.072 1.8E+00 -4.1E-08 75-35-4 Dichloroethylene, 1,1-81 2.43 -4.2E+01 1.2E-02 156-59-2 Dichloroethylene, cis-1,2-42 1.26 -- 156-60-5 Dichloroethylene, trans-1,2-81 2.43 -8.3E+00 5.8E-02 75-00-3 Ethyl Chloride (Chloroethane)7.8 0.234 -2.1E+03 2.2E-05 100-41-4 Ethylbenzene 5.1 0.153 1.1E+00 2.1E+02 1.4E-07 1.5E-04 142-82-5 Heptane, N-27 0.81 -8.3E+01 1.9E-03 110-54-3 Hexane, N-37 1.11 -1.5E+02 1.5E-03 67-63-0 Isopropanol 4 0.12 -4.2E+01 5.8E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)3.1 0.093 -1.0E+03 1.8E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 4.3 0.129 1.0E+02 1.3E+02 1.3E-09 2.1E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 14 0.42 1.1E+01 8.3E+00 3.9E-08 1.0E-02 108-88-3 Toluene 90 2.7 -1.0E+03 5.2E-04 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 1400 42 4.8E-01 4.2E-01 8.8E-05 2.0E+0175-69-4 Trichlorofluoromethane 0 0 -- 95-63-6 Trimethylbenzene, 1,2,4-11 0.33 -1.3E+01 5.3E-03 75-01-4 Vinyl Chloride 4.4 0.132 1.7E-01 2.1E+01 7.9E-07 1.3E-03 108-38-3 Xylene, m-15 0.45 -2.1E+01 4.3E-03 95-47-6 Xylene, o-4.6 0.138 -2.1E+01 1.3E-03 Cumulative:9.3E-05 2.0E+01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SG-1 / DUP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 9.2 0.092 -2.7E+04 6.8E-07 71-43-2 Benzene 52 0.52 1.6E+00 2.6E+01 3.3E-07 4.0E-03 75-15-0 Carbon Disulfide 880 8.8 -6.1E+02 2.9E-03 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 22 0.22 -5.3E+03 8.4E-06 75-71-8 Dichlorodifluoromethane 2.9 0.029 -8.8E+01 6.6E-0575-34-3 Dichloroethane, 1,1-2.4 0.024 7.7E+00 -3.1E-0975-35-4 Dichloroethylene, 1,1-81 0.81 -1.8E+02 9.2E-04156-59-2 Dichloroethylene, cis-1,2-42 0.42 --156-60-5 Dichloroethylene, trans-1,2-81 0.81 -3.5E+01 4.6E-03 75-00-3 Ethyl Chloride (Chloroethane)7.8 0.078 -8.8E+03 1.8E-06 100-41-4 Ethylbenzene 5.1 0.051 4.9E+00 8.8E+02 1.0E-08 1.2E-05 142-82-5 Heptane, N-27 0.27 -3.5E+02 1.5E-04 110-54-3 Hexane, N-37 0.37 -6.1E+02 1.2E-04 67-63-0 Isopropanol 4 0.04 -1.8E+02 4.6E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)3.1 0.031 -4.4E+03 1.4E-06108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -2.6E+03 0.0E+0075-09-2 Methylene Chloride 4.3 0.043 1.2E+03 5.3E+02 3.5E-11 1.6E-05 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 14 0.14 4.7E+01 3.5E+01 3.0E-09 8.0E-04 108-88-3 Toluene 90 0.9 -4.4E+03 4.1E-05 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 1400 14 3.0E+00 1.8E+00 4.7E-06 1.6E+0075-69-4 Trichlorofluoromethane 0 0 --95-63-6 Trimethylbenzene, 1,2,4-11 0.11 -5.3E+01 4.2E-0475-01-4 Vinyl Chloride 4.4 0.044 2.8E+00 8.8E+01 1.6E-08 1.0E-04 108-38-3 Xylene, m-15 0.15 -8.8E+01 3.4E-04 95-47-6 Xylene, o-4.6 0.046 -8.8E+01 1.1E-04 Cumulative:5.0E-06 1.6E+00 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls SS-1 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-1 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SS-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-1 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 29 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 1.8 75-15-0 Carbon Disulfide ug/m3 1.5 67-66-3 Chloroform ug/m3 0 110-82-7 Cyclohexane ug/m3 3.1 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 0 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 3.5 67-63-0 Isopropanol ug/m3 1.5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 1.9 75-09-2 Methylene Chloride ug/m3 5.1 100-42-5 Styrene ug/m3 0 127-18-4 Tetrachloroethylene ug/m3 0 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 0 79-01-6 Trichloroethylene ug/m3 0 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 0 108-38-3 Xylene, m-ug/m3 0 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-1. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.7E-07 2.2E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.8E-08 1.7E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 29 0.87 -6.5E+03 2.7E-05 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 1.8 0.054 -1.5E+02 7.4E-05 67-66-3 Chloroform 1.5 0.045 1.2E-01 2.0E+01 3.7E-07 4.4E-04 110-82-7 Cyclohexane 0 0 -1.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.1 0.093 -2.1E+01 8.9E-04 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 1.1E+00 2.1E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 3.5 0.105 -4.2E+01 5.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.5 0.045 -1.0E+03 8.6E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 1.9 0.057 1.0E+02 1.3E+02 5.6E-10 9.1E-05 100-42-5 Styrene 5.1 0.153 -2.1E+02 1.5E-04 127-18-4 Tetrachloroethylene 0 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -1.0E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 0 0 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -2.1E+01 0.0E+00 95-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00 Cumulative:3.7E-07 2.2E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 29 0.29 -2.7E+04 2.1E-06 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 1.8 0.018 -6.1E+02 5.9E-06 67-66-3 Chloroform 1.5 0.015 5.3E-01 8.6E+01 2.8E-08 3.5E-05 110-82-7 Cyclohexane 0 0 -5.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.1 0.031 -8.8E+01 7.1E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 4.9E+00 8.8E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 3.5 0.035 -1.8E+02 4.0E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)1.5 0.015 -4.4E+03 6.8E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -2.6E+03 0.0E+0075-09-2 Methylene Chloride 1.9 0.019 1.2E+03 5.3E+02 1.5E-11 7.2E-06 100-42-5 Styrene 5.1 0.051 -8.8E+02 1.2E-05 127-18-4 Tetrachloroethylene 0 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -4.4E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+0075-69-4 Trichlorofluoromethane 0 0 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -8.8E+01 0.0E+00 95-47-6 Xylene, o-0 0 -8.8E+01 0.0E+00 Cumulative:2.8E-08 1.7E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-2 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-2 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-2 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-2 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-2 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-2 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 24 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 3.1 75-15-0 Carbon Disulfide ug/m3 1.6 67-66-3 Chloroform ug/m3 0 110-82-7 Cyclohexane ug/m3 3.3 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 0 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 4.2 67-63-0 Isopropanol ug/m3 1.7 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2.1 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 0 127-18-4 Tetrachloroethylene ug/m3 0 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 0 79-01-6 Trichloroethylene ug/m3 0 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 0 108-38-3 Xylene, m-ug/m3 0 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-2. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-2 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.9E-07 2.3E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.0E-08 1.8E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-2 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 24 0.72 -6.5E+03 2.2E-05 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 3.1 0.093 -1.5E+02 1.3E-04 67-66-3 Chloroform 1.6 0.048 1.2E-01 2.0E+01 3.9E-07 4.7E-04 110-82-7 Cyclohexane 0 0 -1.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.3 0.099 -2.1E+01 9.5E-04 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 1.1E+00 2.1E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 4.2 0.126 -4.2E+01 6.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.7 0.051 -1.0E+03 9.8E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 2.1 0.063 1.0E+02 1.3E+02 6.2E-10 1.0E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -1.0E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 0 0 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -2.1E+01 0.0E+00 95-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00 Cumulative:3.9E-07 2.3E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-2 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 24 0.24 -2.7E+04 1.8E-06 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 3.1 0.031 -6.1E+02 1.0E-05 67-66-3 Chloroform 1.6 0.016 5.3E-01 8.6E+01 3.0E-08 3.7E-05 110-82-7 Cyclohexane 0 0 -5.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.3 0.033 -8.8E+01 7.5E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 4.9E+00 8.8E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 4.2 0.042 -1.8E+02 4.8E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)1.7 0.017 -4.4E+03 7.8E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -2.6E+03 0.0E+0075-09-2 Methylene Chloride 2.1 0.021 1.2E+03 5.3E+02 1.7E-11 8.0E-06 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -4.4E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+0075-69-4 Trichlorofluoromethane 0 0 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -8.8E+01 0.0E+00 95-47-6 Xylene, o-0 0 -8.8E+01 0.0E+00 Cumulative:3.0E-08 1.8E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-3 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-3 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 6 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 2.6 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 0 110-82-7 Cyclohexane ug/m3 3.7 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 5.1 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 5.7 67-63-0 Isopropanol ug/m3 1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2.2 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 0 127-18-4 Tetrachloroethylene ug/m3 0 108-88-3 Toluene ug/m3 13 71-55-6 Trichloroethane, 1,1,1-ug/m3 0 79-01-6 Trichloroethylene ug/m3 2 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 40 108-38-3 Xylene, m-ug/m3 15 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-3. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.4E-07 1.8E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.0E-08 1.4E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 6 0.18 -6.5E+03 5.6E-06 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 2.6 0.078 -1.5E+02 1.1E-04 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 0 0 -1.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.7 0.111 -2.1E+01 1.1E-03 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 5.1 0.153 1.1E+00 2.1E+02 1.4E-07 1.5E-04 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 5.7 0.171 -4.2E+01 8.2E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1 0.03 -1.0E+03 5.8E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 2.2 0.066 1.0E+02 1.3E+02 6.5E-10 1.1E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -1.0E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-13 0.39 -1.0E+03 7.5E-05 79-01-6 Trichloroethylene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 2 0.06 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-40 1.2 -2.1E+01 1.2E-02 95-47-6 Xylene, o-15 0.45 -2.1E+01 4.3E-03 Cumulative:1.4E-07 1.8E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 6 0.06 -2.7E+04 4.4E-07 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 2.6 0.026 -6.1E+02 8.5E-06 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 0 0 -5.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.7 0.037 -8.8E+01 8.4E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 5.1 0.051 4.9E+00 8.8E+02 1.0E-08 1.2E-05 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 5.7 0.057 -1.8E+02 6.5E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)1 0.01 -4.4E+03 4.6E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -2.6E+03 0.0E+0075-09-2 Methylene Chloride 2.2 0.022 1.2E+03 5.3E+02 1.8E-11 8.4E-06 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -4.4E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-13 0.13 -4.4E+03 5.9E-06 79-01-6 Trichloroethylene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+0075-69-4 Trichlorofluoromethane 2 0.02 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-40 0.4 -8.8E+01 9.1E-04 95-47-6 Xylene, o-15 0.15 -8.8E+01 3.4E-04 Cumulative:1.0E-08 1.4E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-4 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-4 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-4 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-4 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-4 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-4 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 7.2 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 2.7 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 2.3 110-82-7 Cyclohexane ug/m3 3.3 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 0 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 5.4 67-63-0 Isopropanol ug/m3 0.74 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 0 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 0 127-18-4 Tetrachloroethylene ug/m3 0 108-88-3 Toluene ug/m3 3.7 71-55-6 Trichloroethane, 1,1,1-ug/m3 0 79-01-6 Trichloroethylene ug/m3 0 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 0 108-38-3 Xylene, m-ug/m3 0 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-4. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-4 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 0.0E+00 1.9E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 0.0E+00 1.5E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 7.2 0.216 -6.5E+03 6.7E-06 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 2.7 0.081 -1.5E+02 1.1E-04 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 2.3 0.069 -1.3E+03 1.1E-05 75-71-8 Dichlorodifluoromethane 3.3 0.099 -2.1E+01 9.5E-04 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 1.1E+00 2.1E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 5.4 0.162 -4.2E+01 7.8E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.74 0.0222 -1.0E+03 4.3E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 0 0 1.0E+02 1.3E+02 0.0E+00 0.0E+00 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -1.0E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-3.7 0.111 -1.0E+03 2.1E-05 79-01-6 Trichloroethylene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 0 0 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -2.1E+01 0.0E+00 95-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00 Cumulative:0.0E+00 1.9E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 7.2 0.072 -2.7E+04 5.3E-07 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 2.7 0.027 -6.1E+02 8.8E-06 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 2.3 0.023 -5.3E+03 8.8E-07 75-71-8 Dichlorodifluoromethane 3.3 0.033 -8.8E+01 7.5E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 4.9E+00 8.8E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 5.4 0.054 -1.8E+02 6.2E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)0.74 0.0074 -4.4E+03 3.4E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -2.6E+03 0.0E+0075-09-2 Methylene Chloride 0 0 1.2E+03 5.3E+02 0.0E+00 0.0E+00 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 0 0 -4.4E+03 0.0E+00 71-55-6 Trichloroethane, 1,1,1-3.7 0.037 -4.4E+03 1.7E-06 79-01-6 Trichloroethylene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+0075-69-4 Trichlorofluoromethane 0 0 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -8.8E+01 0.0E+00 95-47-6 Xylene, o-0 0 -8.8E+01 0.0E+00 Cumulative:0.0E+00 1.5E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-5 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-5 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-5 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-5 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-5 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-5 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 53 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 3.5 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 4.2 110-82-7 Cyclohexane ug/m3 5.6 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 1.5 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 12 67-63-0 Isopropanol ug/m3 4.7 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 5.8 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 6.7 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 0 127-18-4 Tetrachloroethylene ug/m3 2.3 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 0 79-01-6 Trichloroethylene ug/m3 2.2 75-69-4 Trichlorofluoromethane ug/m3 5.5 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 5.1 108-38-3 Xylene, m-ug/m3 1.9 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-5. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-5 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.2E-08 8.7E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.1E-09 6.9E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 53 1.59 -6.5E+03 4.9E-05 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 3.5 0.105 -1.5E+02 1.4E-04 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 4.2 0.126 -1.3E+03 2.0E-05 75-71-8 Dichlorodifluoromethane 5.6 0.168 -2.1E+01 1.6E-03 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 1.5 0.045 1.1E+00 2.1E+02 4.0E-08 4.3E-05 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 12 0.36 -4.2E+01 1.7E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)4.7 0.141 -1.0E+03 2.7E-05 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)5.8 0.174 -6.3E+02 5.6E-05 75-09-2 Methylene Chloride 6.7 0.201 1.0E+02 1.3E+02 2.0E-09 3.2E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 2.3 0.069 -1.0E+03 1.3E-05 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 2.2 0.066 -- 95-63-6 Trimethylbenzene, 1,2,4-5.5 0.165 -1.3E+01 2.6E-03 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-5.1 0.153 -2.1E+01 1.5E-03 95-47-6 Xylene, o-1.9 0.057 -2.1E+01 5.5E-04 Cumulative:4.2E-08 8.7E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 53 0.53 -2.7E+04 3.9E-06 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 3.5 0.035 -6.1E+02 1.1E-05 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 4.2 0.042 -5.3E+03 1.6E-06 75-71-8 Dichlorodifluoromethane 5.6 0.056 -8.8E+01 1.3E-0475-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 1.5 0.015 4.9E+00 8.8E+02 3.1E-09 3.4E-06 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 12 0.12 -1.8E+02 1.4E-0478-93-3 Methyl Ethyl Ketone (2-Butanone)4.7 0.047 -4.4E+03 2.1E-06108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)5.8 0.058 -2.6E+03 4.4E-0675-09-2 Methylene Chloride 6.7 0.067 1.2E+03 5.3E+02 5.5E-11 2.5E-05 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 2.3 0.023 -4.4E+03 1.1E-06 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+0075-69-4 Trichlorofluoromethane 2.2 0.022 --95-63-6 Trimethylbenzene, 1,2,4-5.5 0.055 -5.3E+01 2.1E-0475-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-5.1 0.051 -8.8E+01 1.2E-04 95-47-6 Xylene, o-1.9 0.019 -8.8E+01 4.3E-05 Cumulative:3.1E-09 6.9E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-6 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-6 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-6 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-6 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-6 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-6 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 16 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 3.1 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 0 110-82-7 Cyclohexane ug/m3 3.2 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 1.5 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 4.2 67-63-0 Isopropanol ug/m3 1.5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 2.2 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 0 127-18-4 Tetrachloroethylene ug/m3 1.4 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 0 79-01-6 Trichloroethylene ug/m3 2 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 1.8 108-38-3 Xylene, m-ug/m3 0 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-6. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.1E-08 2.4E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.1E-09 1.9E-04 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 16 0.48 -6.5E+03 1.5E-05 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 3.1 0.093 -1.5E+02 1.3E-04 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 0 0 -1.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.2 0.096 -2.1E+01 9.2E-04 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 1.5 0.045 1.1E+00 2.1E+02 4.0E-08 4.3E-05 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 4.2 0.126 -4.2E+01 6.0E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)1.5 0.045 -1.0E+03 8.6E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -6.3E+02 0.0E+00 75-09-2 Methylene Chloride 2.2 0.066 1.0E+02 1.3E+02 6.5E-10 1.1E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 1.1E+01 8.3E+00 0.0E+00 0.0E+00 108-88-3 Toluene 1.4 0.042 -1.0E+03 8.1E-06 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 4.8E-01 4.2E-01 0.0E+00 0.0E+00 75-69-4 Trichlorofluoromethane 2 0.06 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-1.8 0.054 -2.1E+01 5.2E-04 95-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00 Cumulative:4.1E-08 2.4E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 16 0.16 -2.7E+04 1.2E-06 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 3.1 0.031 -6.1E+02 1.0E-05 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 0 0 -5.3E+03 0.0E+00 75-71-8 Dichlorodifluoromethane 3.2 0.032 -8.8E+01 7.3E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 1.5 0.015 4.9E+00 8.8E+02 3.1E-09 3.4E-06 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 4.2 0.042 -1.8E+02 4.8E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)1.5 0.015 -4.4E+03 6.8E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)0 0 -2.6E+03 0.0E+0075-09-2 Methylene Chloride 2.2 0.022 1.2E+03 5.3E+02 1.8E-11 8.4E-06 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 0 0 4.7E+01 3.5E+01 0.0E+00 0.0E+00 108-88-3 Toluene 1.4 0.014 -4.4E+03 6.4E-07 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 0 0 3.0E+00 1.8E+00 0.0E+00 0.0E+0075-69-4 Trichlorofluoromethane 2 0.02 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-1.8 0.018 -8.8E+01 4.1E-05 95-47-6 Xylene, o-0 0 -8.8E+01 0.0E+00 Cumulative:3.1E-09 1.9E-04 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: SS-7 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-7 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-7 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: SS-7 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-7 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-7 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 7 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 2.2 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 6.4 110-82-7 Cyclohexane ug/m3 3.1 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 0 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 8.9 67-63-0 Isopropanol ug/m3 0.83 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 4.6 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 5.9 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 4.9 127-18-4 Tetrachloroethylene ug/m3 0.87 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 8.7 79-01-6 Trichloroethylene ug/m3 1.9 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 0 108-38-3 Xylene, m-ug/m3 0 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-7. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-7 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 5.6E-07 1.3E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.0E-08 1.0E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-7 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 7 0.21 -6.5E+03 6.5E-06 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 2.2 0.066 -1.5E+02 9.0E-05 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 6.4 0.192 -1.3E+03 3.1E-05 75-71-8 Dichlorodifluoromethane 3.1 0.093 -2.1E+01 8.9E-04 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 1.1E+00 2.1E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 8.9 0.267 -4.2E+01 1.3E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.83 0.0249 -1.0E+03 4.8E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.6 0.138 -6.3E+02 4.4E-05 75-09-2 Methylene Chloride 5.9 0.177 1.0E+02 1.3E+02 1.7E-09 2.8E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 4.9 0.147 1.1E+01 8.3E+00 1.4E-08 3.5E-03 108-88-3 Toluene 0.87 0.0261 -1.0E+03 5.0E-06 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 8.7 0.261 4.8E-01 4.2E-01 5.5E-07 1.3E-01 75-69-4 Trichlorofluoromethane 1.9 0.057 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -2.1E+01 0.0E+00 95-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00 Cumulative:5.6E-07 1.3E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-7 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 7 0.07 -2.7E+04 5.2E-07 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 2.2 0.022 -6.1E+02 7.2E-06 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 6.4 0.064 -5.3E+03 2.4E-06 75-71-8 Dichlorodifluoromethane 3.1 0.031 -8.8E+01 7.1E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 4.9E+00 8.8E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 8.9 0.089 -1.8E+02 1.0E-0478-93-3 Methyl Ethyl Ketone (2-Butanone)0.83 0.0083 -4.4E+03 3.8E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.6 0.046 -2.6E+03 3.5E-0675-09-2 Methylene Chloride 5.9 0.059 1.2E+03 5.3E+02 4.8E-11 2.2E-05 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 4.9 0.049 4.7E+01 3.5E+01 1.0E-09 2.8E-04 108-88-3 Toluene 0.87 0.0087 -4.4E+03 4.0E-07 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 8.7 0.087 3.0E+00 1.8E+00 2.9E-08 9.9E-0375-69-4 Trichlorofluoromethane 1.9 0.019 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -8.8E+01 0.0E+00 95-47-6 Xylene, o-0 0 -8.8E+01 0.0E+00 Cumulative:3.0E-08 1.0E-02 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls SS-8 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-8 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-8 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: SS-8 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: SS-8 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021 Basis: November 2020 EPA RSL TableSite ID: 24008-20-060 Exposure Unit ID: SS-8 Description of Exposure Point Concentration Selection: Exposure Point Concentration (ug/m3)Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 9.5 67-64-1 Acetone ug/m3 0 71-43-2 Benzene ug/m3 1.9 75-15-0 Carbon Disulfide ug/m3 0 67-66-3 Chloroform ug/m3 2.5 110-82-7 Cyclohexane ug/m3 3.1 75-71-8 Dichlorodifluoromethane ug/m3 0 75-34-3 Dichloroethane, 1,1-ug/m3 0 75-35-4 Dichloroethylene, 1,1-ug/m3 0 156-59-2 Dichloroethylene, cis-1,2-ug/m3 0 156-60-5 Dichloroethylene, trans-1,2-ug/m3 0 75-00-3 Ethyl Chloride (Chloroethane)ug/m3 0 100-41-4 Ethylbenzene ug/m3 0 142-82-5 Heptane, N-ug/m3 0 110-54-3 Hexane, N-ug/m3 7.7 67-63-0 Isopropanol ug/m3 0.94 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 4.6 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)ug/m3 6.9 75-09-2 Methylene Chloride ug/m3 0 100-42-5 Styrene ug/m3 3.1 127-18-4 Tetrachloroethylene ug/m3 2.3 108-88-3 Toluene ug/m3 0 71-55-6 Trichloroethane, 1,1,1-ug/m3 4.1 79-01-6 Trichloroethylene ug/m3 1.2 75-69-4 Trichlorofluoromethane ug/m3 0 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 0 75-01-4 Vinyl Chloride ug/m3 0 108-38-3 Xylene, m-ug/m3 0 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table Exposure Point Concentrations based on detections in sample SS-8. Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculations North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-8 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.7E-07 6.4E-02 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.4E-08 5.1E-03 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-8 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 9.5 0.285 -6.5E+03 8.8E-06 71-43-2 Benzene 0 0 3.6E-01 6.3E+00 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 1.9 0.057 -1.5E+02 7.8E-05 67-66-3 Chloroform 0 0 1.2E-01 2.0E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 2.5 0.075 -1.3E+03 1.2E-05 75-71-8 Dichlorodifluoromethane 3.1 0.093 -2.1E+01 8.9E-04 75-34-3 Dichloroethane, 1,1-0 0 1.8E+00 -0.0E+00 75-35-4 Dichloroethylene, 1,1-0 0 -4.2E+01 0.0E+00 156-59-2 Dichloroethylene, cis-1,2-0 0 -- 156-60-5 Dichloroethylene, trans-1,2-0 0 -8.3E+00 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -2.1E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 1.1E+00 2.1E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -8.3E+01 0.0E+00 110-54-3 Hexane, N-0 0 -1.5E+02 0.0E+00 67-63-0 Isopropanol 7.7 0.231 -4.2E+01 1.1E-03 78-93-3 Methyl Ethyl Ketone (2-Butanone)0.94 0.0282 -1.0E+03 5.4E-06 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.6 0.138 -6.3E+02 4.4E-05 75-09-2 Methylene Chloride 6.9 0.207 1.0E+02 1.3E+02 2.0E-09 3.3E-04 100-42-5 Styrene 0 0 -2.1E+02 0.0E+00 127-18-4 Tetrachloroethylene 3.1 0.093 1.1E+01 8.3E+00 8.6E-09 2.2E-03 108-88-3 Toluene 2.3 0.069 -1.0E+03 1.3E-05 71-55-6 Trichloroethane, 1,1,1-0 0 -1.0E+03 0.0E+00 79-01-6 Trichloroethylene 4.1 0.123 4.8E-01 4.2E-01 2.6E-07 5.9E-02 75-69-4 Trichlorofluoromethane 1.2 0.036 -- 95-63-6 Trimethylbenzene, 1,2,4-0 0 -1.3E+01 0.0E+00 75-01-4 Vinyl Chloride 0 0 1.7E-01 2.1E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -2.1E+01 0.0E+00 95-47-6 Xylene, o-0 0 -2.1E+01 0.0E+00 Cumulative:2.7E-07 6.4E-02 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Soil Gas to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: SS-8 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 9.5 0.095 -2.7E+04 7.0E-07 71-43-2 Benzene 0 0 1.6E+00 2.6E+01 0.0E+00 0.0E+00 75-15-0 Carbon Disulfide 1.9 0.019 -6.1E+02 6.2E-06 67-66-3 Chloroform 0 0 5.3E-01 8.6E+01 0.0E+00 0.0E+00 110-82-7 Cyclohexane 2.5 0.025 -5.3E+03 9.5E-07 75-71-8 Dichlorodifluoromethane 3.1 0.031 -8.8E+01 7.1E-0575-34-3 Dichloroethane, 1,1-0 0 7.7E+00 -0.0E+0075-35-4 Dichloroethylene, 1,1-0 0 -1.8E+02 0.0E+00156-59-2 Dichloroethylene, cis-1,2-0 0 --156-60-5 Dichloroethylene, trans-1,2-0 0 -3.5E+01 0.0E+00 75-00-3 Ethyl Chloride (Chloroethane)0 0 -8.8E+03 0.0E+00 100-41-4 Ethylbenzene 0 0 4.9E+00 8.8E+02 0.0E+00 0.0E+00 142-82-5 Heptane, N-0 0 -3.5E+02 0.0E+00 110-54-3 Hexane, N-0 0 -6.1E+02 0.0E+00 67-63-0 Isopropanol 7.7 0.077 -1.8E+02 8.8E-0578-93-3 Methyl Ethyl Ketone (2-Butanone)0.94 0.0094 -4.4E+03 4.3E-07108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)4.6 0.046 -2.6E+03 3.5E-0675-09-2 Methylene Chloride 6.9 0.069 1.2E+03 5.3E+02 5.6E-11 2.6E-05 100-42-5 Styrene 0 0 -8.8E+02 0.0E+00 127-18-4 Tetrachloroethylene 3.1 0.031 4.7E+01 3.5E+01 6.6E-10 1.8E-04 108-88-3 Toluene 2.3 0.023 -4.4E+03 1.1E-06 71-55-6 Trichloroethane, 1,1,1-0 0 -4.4E+03 0.0E+00 79-01-6 Trichloroethylene 4.1 0.041 3.0E+00 1.8E+00 1.4E-08 4.7E-0375-69-4 Trichlorofluoromethane 1.2 0.012 --95-63-6 Trimethylbenzene, 1,2,4-0 0 -5.3E+01 0.0E+0075-01-4 Vinyl Chloride 0 0 2.8E+00 8.8E+01 0.0E+00 0.0E+00 108-38-3 Xylene, m-0 0 -8.8E+01 0.0E+00 95-47-6 Xylene, o-0 0 -8.8E+01 0.0E+00 Cumulative:1.4E-08 5.1E-03 All concentrations are in ug/m3 Output Form 3E Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls TW-3 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-3 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: TW-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: TW-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24008-20-060Exposure Unit ID: TW-3Description of Exposure Point Concentration Selection:NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculationsExposure Point Concentration (ug/L)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion2.1 67-64-1 Acetone ug/L0.84 7440-38-2 Arsenic, Inorganic ug/L100 7440-39-3 Bariumug/L2.4 16065-83-1 Chromium(III), Insoluble Salts ug/L1.4 7439-92-1 ~Lead and Compounds ug/L0.034 7439-97-6 ~Mercury (elemental) ug/LInput Form 2BGroundwater Exposure Point Concentration TableExposure point concentrations reflect maximum detection in site groundwater during Jnauary 6, 2021 groundwater sampling event.North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air 0.0E+00 3.8E-02 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air 0.0E+00 9.1E-03 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060Exposure Unit ID: TW-3 CAS # Chemical Name: Groundwater Concentration(ug/L) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 2.1 - 6.5E+03 9.3E-087440-38-2 Arsenic, Inorganic 0.84 6.5E-04 3.1E-037440-39-3 Barium 100 - 1.0E-0116065-83-1 Chromium(III), Insoluble Salts 2.4 - -75-34-3 Dichloroethane, 1,1- 1.8E+00 -107-06-2 Dichloroethane, 1,2- 1.1E-01 1.5E+0075-35-4 Dichloroethylene, 1,1- - 4.2E+01156-59-2 Dichloroethylene, cis-1,2- - -123-91-1 Dioxane, 1,4- 5.6E-01 6.3E+0075-00-3 Ethyl Chloride (Chloroethane) - 2.1E+03 7439-92-1 ~Lead and Compounds 1.4 - -7439-97-6 ~Mercury (elemental) 0.034 - 6.3E-02 3.8E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE) 1.1E+01 6.3E+027782-49-2 Selenium - 4.2E+00 127-18-4 Tetrachloroethylene 1.1E+01 8.3E+00108-88-3 Toluene - 1.0E+03 79-01-6 Trichloroethylene 4.8E-01 4.2E-0175-01-4 Vinyl Chloride 1.7E-01 2.1E+01 Cumulative: 0.0E+00 3.8E-02 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3A Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-3 CAS # Chemical Name: Groundwater Concentration (ug/L) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 2.1 0.003004906 - 2.7E+04 2.2E-087440-38-2 Arsenic, Inorganic 0.84 2.9E-03 1.3E-027440-39-3 Barium 100 - 4.4E-0116065-83-1 Chromium(III), Insoluble Salts 2.4 - - 75-34-3 Dichloroethane, 1,1- 7.7E+00 - 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 75-35-4 Dichloroethylene, 1,1- - 1.8E+02 156-59-2 Dichloroethylene, cis-1,2- - - 123-91-1 Dioxane, 1,4- 2.5E+00 2.6E+01 75-00-3 Ethyl Chloride (Chloroethane) - 8.8E+037439-92-1 ~Lead and Compounds 1.4 - -7439-97-6 ~Mercury (elemental) 0.034 0.011968 - 2.6E-01 9.1E-03 1634-04-4 Methyl tert-Butyl Ether (MTBE) 4.7E+01 2.6E+03 7782-49-2 Selenium - 1.8E+01 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene - 4.4E+03 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-01-4 Vinyl Chloride 2.8E+00 8.8E+01 Cumulative: 0.0E+00 9.1E-03 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3D Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls TW-4 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-4 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-4 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: TW-4 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: TW-4 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24008-20-060Exposure Unit ID: TW-4Description of Exposure Point Concentration Selection:NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculationsExposure Point Concentration (ug/L)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion4.1 67-64-1 Acetone ug/L0.58 7440-38-2 Arsenic, Inorganic ug/L130 7440-39-3 Bariumug/L7.2 16065-83-1 Chromium(III), Insoluble Salts ug/L2.3 75-34-3 Dichloroethane, 1,1- ug/L0.87 75-35-4 Dichloroethylene, 1,1- ug/L0.78 156-59-2 Dichloroethylene, cis-1,2- ug/L25 123-91-1 Dioxane, 1,4- ug/L2.1 75-00-3 Ethyl Chloride (Chloroethane) ug/L4.2 7439-92-1 ~Lead and Compounds ug/L0.24 108-88-3 Toluene ug/L2.3 79-01-6 Trichloroethylene ug/L32 75-01-4 Vinyl Chloride ug/LInput Form 2BGroundwater Exposure Point Concentration TableExposure point concentrations reflect maximum detection in site groundwater during Jnauary 6, 2021 groundwater sampling event.North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-4 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air 2.2E-04 8.0E-01 YES Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air 1.3E-05 1.9E-01 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060Exposure Unit ID: TW-4 CAS # Chemical Name: Groundwater Concentration(ug/L) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 4.1 - 6.5E+03 1.8E-077440-38-2 Arsenic, Inorganic 0.58 6.5E-04 3.1E-037440-39-3 Barium 130 - 1.0E-0116065-83-1 Chromium(III), Insoluble Salts 7.2 - -75-34-3 Dichloroethane, 1,1- 2.3 1.8E+00 - 3.0E-07107-06-2 Dichloroethane, 1,2- 1.1E-01 1.5E+0075-35-4 Dichloroethylene, 1,1- 0.87 - 4.2E+01 4.5E-03156-59-2 Dichloroethylene, cis-1,2- 0.78 - -123-91-1 Dioxane, 1,4- 25 5.6E-01 6.3E+00 8.7E-09 1.6E-0475-00-3 Ethyl Chloride (Chloroethane) 2.1 - 2.1E+03 9.1E-05 7439-92-1 ~Lead and Compounds 4.2 - -7439-97-6 ~Mercury (elemental) - 6.3E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE) 1.1E+01 6.3E+027782-49-2 Selenium - 4.2E+00 127-18-4 Tetrachloroethylene 1.1E+01 8.3E+00108-88-3 Toluene 0.24 - 1.0E+03 1.2E-05 79-01-6 Trichloroethylene 2.3 4.8E-01 4.2E-01 1.9E-06 4.4E-0175-01-4 Vinyl Chloride 32 1.7E-01 2.1E+01 2.2E-04 3.5E-01 Cumulative:2.2E-04 8.0E-01 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3A Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-4 CAS # Chemical Name: Groundwater Concentration (ug/L) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 4.1 0.005866721 - 2.7E+04 4.3E-087440-38-2 Arsenic, Inorganic 0.58 2.9E-03 1.3E-027440-39-3 Barium 130 - 4.4E-0116065-83-1 Chromium(III), Insoluble Salts 7.2 - - 75-34-3 Dichloroethane, 1,1- 2.3 0.52845462 7.7E+00 - 6.9E-08 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 75-35-4 Dichloroethylene, 1,1- 0.87 0.928331971 - 1.8E+02 1.1E-03 156-59-2 Dichloroethylene, cis-1,2- 0.78 0.130106296 - - 123-91-1 Dioxane, 1,4- 25 0.004905969 2.5E+00 2.6E+01 2.0E-09 3.7E-05 75-00-3 Ethyl Chloride (Chloroethane) 2.1 0.952984464 - 8.8E+03 2.2E-057439-92-1 ~Lead and Compounds 4.2 - -7439-97-6 ~Mercury (elemental) - 2.6E-01 1634-04-4 Methyl tert-Butyl Ether (MTBE) 4.7E+01 2.6E+03 7782-49-2 Selenium - 1.8E+01 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene 0.24 0.065151267 - 4.4E+03 3.0E-06 79-01-6 Trichloroethylene 2.3 0.926206051 3.0E+00 1.8E+00 3.1E-07 1.1E-01 75-01-4 Vinyl Chloride 32 36.36958299 2.8E+00 8.8E+01 1.3E-05 8.3E-02 Cumulative: 1.3E-05 1.9E-01 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3D Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls TW-5 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-5 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: TW-5 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: TW-5 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24008-20-060Exposure Unit ID: TW-5Description of Exposure Point Concentration Selection:NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculationsExposure Point Concentration (ug/L)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion1.3 67-64-1 Acetone ug/L0.55 7440-38-2 Arsenic, Inorganic ug/L160 7440-39-3 Bariumug/L2 16065-83-1 Chromium(III), Insoluble Salts ug/L2 75-34-3 Dichloroethane, 1,1- ug/L3.6 75-35-4 Dichloroethylene, 1,1- ug/L0.98 156-59-2 Dichloroethylene, cis-1,2- ug/L19 123-91-1 Dioxane, 1,4- ug/L0.67 7439-92-1 ~Lead and Compounds ug/L2.2 75-01-4 Vinyl Chloride ug/LInput Form 2BGroundwater Exposure Point Concentration TableExposure point concentrations reflect maximum detection in site groundwater during Jnauary 6, 2021 groundwater sampling event.North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-5 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air 1.5E-05 4.3E-02 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air 9.6E-07 1.0E-02 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060Exposure Unit ID: TW-5 CAS # Chemical Name: Groundwater Concentration(ug/L) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 1.3 - 6.5E+03 5.8E-087440-38-2 Arsenic, Inorganic 0.55 6.5E-04 3.1E-037440-39-3 Barium 160 - 1.0E-0116065-83-1 Chromium(III), Insoluble Salts 2 - -75-34-3 Dichloroethane, 1,1- 2 1.8E+00 - 2.6E-07107-06-2 Dichloroethane, 1,2- 1.1E-01 1.5E+0075-35-4 Dichloroethylene, 1,1- 3.6 - 4.2E+01 1.8E-02156-59-2 Dichloroethylene, cis-1,2- 0.98 - -123-91-1 Dioxane, 1,4- 19 5.6E-01 6.3E+00 6.6E-09 1.2E-0475-00-3 Ethyl Chloride (Chloroethane) - 2.1E+03 7439-92-1 ~Lead and Compounds 0.67 - -7439-97-6 ~Mercury (elemental) - 6.3E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE) 1.1E+01 6.3E+027782-49-2 Selenium - 4.2E+00 127-18-4 Tetrachloroethylene 1.1E+01 8.3E+00108-88-3 Toluene - 1.0E+03 79-01-6 Trichloroethylene 4.8E-01 4.2E-0175-01-4 Vinyl Chloride 2.2 1.7E-01 2.1E+01 1.5E-05 2.4E-02 Cumulative: 1.5E-05 4.3E-02 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3A Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-5 CAS # Chemical Name: Groundwater Concentration (ug/L) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 1.3 0.00186018 - 2.7E+04 1.4E-087440-38-2 Arsenic, Inorganic 0.55 2.9E-03 1.3E-027440-39-3 Barium 160 - 4.4E-0116065-83-1 Chromium(III), Insoluble Salts 2 - - 75-34-3 Dichloroethane, 1,1- 2 0.459525756 7.7E+00 - 6.0E-08 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 75-35-4 Dichloroethylene, 1,1- 3.6 3.841373671 - 1.8E+02 4.4E-03 156-59-2 Dichloroethylene, cis-1,2- 0.98 0.163466885 - - 123-91-1 Dioxane, 1,4- 19 0.003728536 2.5E+00 2.6E+01 1.5E-09 2.8E-05 75-00-3 Ethyl Chloride (Chloroethane) - 8.8E+037439-92-1 ~Lead and Compounds 0.67 - -7439-97-6 ~Mercury (elemental) - 2.6E-01 1634-04-4 Methyl tert-Butyl Ether (MTBE) 4.7E+01 2.6E+03 7782-49-2 Selenium - 1.8E+01 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene - 4.4E+03 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-01-4 Vinyl Chloride 2.2 2.500408831 2.8E+00 8.8E+01 9.0E-07 5.7E-03 Cumulative: 9.6E-07 1.0E-02 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3D Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: TW-6 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-6 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: TW-6 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: TW-6 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24008-20-060Exposure Unit ID: TW-6Description of Exposure Point Concentration Selection:NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculationsExposure Point Concentration (ug/L)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion1.4 67-64-1 Acetone ug/L0.34 7440-38-2 Arsenic, Inorganic ug/L59 7440-39-3 Bariumug/L1.4 16065-83-1 Chromium(III), Insoluble Salts ug/L0.25 107-06-2 Dichloroethane, 1,2- ug/L0.038 7439-97-6 ~Mercury (elemental) ug/L1.1 7782-49-2 Selenium ug/L0.28 127-18-4 Tetrachloroethylene ug/LInput Form 2BGroundwater Exposure Point Concentration TableExposure point concentrations reflect maximum detection in site groundwater during Jnauary 6, 2021 groundwater sampling event.North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air 1.3E-07 4.9E-02 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air 3.0E-08 1.2E-02 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060Exposure Unit ID: TW-6 CAS # Chemical Name: Groundwater Concentration(ug/L) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 1.4 - 6.5E+03 6.2E-087440-38-2 Arsenic, Inorganic 0.34 6.5E-04 3.1E-037440-39-3 Barium 59 - 1.0E-0116065-83-1 Chromium(III), Insoluble Salts 1.4 - -75-34-3 Dichloroethane, 1,1- 1.8E+00 -107-06-2 Dichloroethane, 1,2- 0.25 1.1E-01 1.5E+00 1.1E-07 1.7E-0375-35-4 Dichloroethylene, 1,1- - 4.2E+01156-59-2 Dichloroethylene, cis-1,2- - -123-91-1 Dioxane, 1,4- 5.6E-01 6.3E+0075-00-3 Ethyl Chloride (Chloroethane) - 2.1E+03 7439-92-1 ~Lead and Compounds - -7439-97-6 ~Mercury (elemental) 0.038 - 6.3E-02 4.3E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE) 1.1E+01 6.3E+027782-49-2 Selenium 1.1 - 4.2E+00 127-18-4 Tetrachloroethylene 0.28 1.1E+01 8.3E+00 1.9E-08 4.9E-03108-88-3 Toluene - 1.0E+03 79-01-6 Trichloroethylene 4.8E-01 4.2E-0175-01-4 Vinyl Chloride 1.7E-01 2.1E+01 Cumulative: 1.3E-07 4.9E-02 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3A Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-6 CAS # Chemical Name: Groundwater Concentration (ug/L) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 1.4 0.002003271 - 2.7E+04 1.5E-087440-38-2 Arsenic, Inorganic 0.34 2.9E-03 1.3E-027440-39-3 Barium 59 - 4.4E-0116065-83-1 Chromium(III), Insoluble Salts 1.4 - - 75-34-3 Dichloroethane, 1,1- 7.7E+00 - 107-06-2 Dichloroethane, 1,2- 0.25 0.012060507 4.7E-01 6.1E+00 2.6E-08 3.9E-04 75-35-4 Dichloroethylene, 1,1- - 1.8E+02 156-59-2 Dichloroethylene, cis-1,2- - - 123-91-1 Dioxane, 1,4- 2.5E+00 2.6E+01 75-00-3 Ethyl Chloride (Chloroethane) - 8.8E+037439-92-1 ~Lead and Compounds - -7439-97-6 ~Mercury (elemental) 0.038 0.013376 - 2.6E-01 1.0E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE) 4.7E+01 2.6E+03 7782-49-2 Selenium 1.1 - 1.8E+01 127-18-4 Tetrachloroethylene 0.28 0.202616517 4.7E+01 3.5E+01 4.3E-09 1.2E-03 108-88-3 Toluene - 4.4E+03 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-01-4 Vinyl Chloride 2.8E+00 8.8E+01 Cumulative: 3.0E-08 1.2E-02 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3D Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/25/2021 Prepared By:Ayla Homer Hart & Hickman Matt Ingalls TW-7 North Carolina Department of Environmental Quality Risk Calculator Selles Bagwell Brownfields Property S. Tryon St. and Distribution St. Brownfields 24008-20-060 January 2021 November 2020 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-7 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: TW-7 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: TW-7 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: January 2021Basis: November 2020 EPA RSL TableSite ID: 24008-20-060Exposure Unit ID: TW-7Description of Exposure Point Concentration Selection:NOTE: If the chemical list is changed from a prior calculator run, remember to select "See All Chemicals" on the data output sheet or newly added chemicals will not be included in risk calculationsExposure Point Concentration (ug/L)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion2.4 67-64-1 Acetone ug/L4.8 7440-38-2 Arsenic, Inorganic ug/L130 7440-39-3 Bariumug/L4.1 16065-83-1 Chromium(III), Insoluble Salts ug/L6.9 7439-92-1 ~Lead and Compounds ug/L0.3 1634-04-4 Methyl tert-Butyl Ether (MTBE) ug/LInput Form 2BGroundwater Exposure Point Concentration TableExposure point concentrations reflect maximum detection in site groundwater during Jnauary 6, 2021 groundwater sampling event.North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-7 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air 6.7E-10 2.4E-06 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Groundwater to Indoor Air 1.5E-10 5.7E-07 NO Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not calculated DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060Exposure Unit ID: TW-7 CAS # Chemical Name: Groundwater Concentration(ug/L) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 2.4 - 6.5E+03 1.1E-077440-38-2 Arsenic, Inorganic 4.8 6.5E-04 3.1E-037440-39-3 Barium 130 - 1.0E-0116065-83-1 Chromium(III), Insoluble Salts 4.1 - -75-34-3 Dichloroethane, 1,1- 1.8E+00 -107-06-2 Dichloroethane, 1,2- 1.1E-01 1.5E+0075-35-4 Dichloroethylene, 1,1- - 4.2E+01156-59-2 Dichloroethylene, cis-1,2- - -123-91-1 Dioxane, 1,4- 5.6E-01 6.3E+0075-00-3 Ethyl Chloride (Chloroethane) - 2.1E+03 7439-92-1 ~Lead and Compounds 6.9 - -7439-97-6 ~Mercury (elemental) - 6.3E-02 1634-04-4 Methyl tert-Butyl Ether (MTBE) 0.3 1.1E+01 6.3E+02 6.7E-10 2.3E-067782-49-2 Selenium - 4.2E+00 127-18-4 Tetrachloroethylene 1.1E+01 8.3E+00108-88-3 Toluene - 1.0E+03 79-01-6 Trichloroethylene 4.8E-01 4.2E-0175-01-4 Vinyl Chloride 1.7E-01 2.1E+01 Cumulative: 6.7E-10 2.4E-06 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3A Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Non-Residential Worker Groundwater to Indoor Air Version Date: January 2021 Basis: November 2020 EPA RSL Table Site ID: 24008-20-060 Exposure Unit ID: TW-7 CAS # Chemical Name: Groundwater Concentration (ug/L) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non-Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 2.4 0.003434178 - 2.7E+04 2.5E-087440-38-2 Arsenic, Inorganic 4.8 2.9E-03 1.3E-027440-39-3 Barium 130 - 4.4E-0116065-83-1 Chromium(III), Insoluble Salts 4.1 - - 75-34-3 Dichloroethane, 1,1- 7.7E+00 - 107-06-2 Dichloroethane, 1,2- 4.7E-01 6.1E+00 75-35-4 Dichloroethylene, 1,1- - 1.8E+02 156-59-2 Dichloroethylene, cis-1,2- - - 123-91-1 Dioxane, 1,4- 2.5E+00 2.6E+01 75-00-3 Ethyl Chloride (Chloroethane) - 8.8E+037439-92-1 ~Lead and Compounds 6.9 - -7439-97-6 ~Mercury (elemental) - 2.6E-01 1634-04-4 Methyl tert-Butyl Ether (MTBE) 0.3 0.007199509 4.7E+01 2.6E+03 1.5E-10 5.5E-07 7782-49-2 Selenium - 1.8E+01 127-18-4 Tetrachloroethylene 4.7E+01 3.5E+01 108-88-3 Toluene - 4.4E+03 79-01-6 Trichloroethylene 3.0E+00 1.8E+00 75-01-4 Vinyl Chloride 2.8E+00 8.8E+01 Cumulative: 1.5E-10 5.7E-07 Groundwater concentrations are in ug/L. Air concentrations are in ug/m3. Output Form 3D Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator