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0201_Alexander_MSWLF_CDLF_December2020GW_FID1615835_20211004
Electronic Data - Email CD (data loaded: Yes / No NC DENR Division of Waste Management - Solid Waste NOUce: i his torm antl any mtormanon attacnetl to rt are "Nublic Kecortls" as tletinetl In NC Gene available for inspection and examination by any person upon request (NC General Statute 132-6). nnr./Fvant # Ins>rructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699A646. SolidWaste Monitorin al Information (laboratory, consultant, facility owner): Municipal Engineering Services Co., PA Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl Phone: (919)772-5393 E-mail: jpfohl@mesco.com NC Landfill Rute: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Alexander County Active C&D and 2500 Paynes Dairy Road 02-01 .1600 December 28-31, 2020 Closed Unlined MSWLF Taylorsville, NC 28681 Environmental Status: (Check all that apply) Initial/Background Monitoring ® Detection Monitoring 1X of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells 0 Lea chate -monitoring data n Ri irfare water mnnitnrinn rintn Assessment Monitoring QX Corrective Action Methane gas monitoring data Corrective action data (specify) MNA,Phyto. & LFG Extraction Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. 8X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furfnermore, I have attached complete nocation of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Benjamin Clawson, P.E. Senior Project Manager (919) 772-5393 Facili epresenta ' e N e (Print) Title (Area Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal ignature DateICA/�j/ P.O. Box 97, Garner, NC 27529 ?q�oFES$/o����� Facility Representative Address SEAL T C-0281• �033710 , NC PE Firm License Number (if applicable effective May 1, 2009) INVrw�'e�®�\� .,,. Revised 6/2009 f�/�� ��, ni I;F\\\� Semi -Annual Water Quality Monitoring Report with Corrective Action Update December 2020 Prepared for Alexander County Active Construction and Demolition Landfill Jonathan Pfohl Environmental Specialist jpfohl jwmesco.com Closed Unlined Landfill Taylorsville, North Carolina Permit No. 02-01 Prepared by Municipal Engineering Services Company, P.A. P.O. BOX 97 Garner, North Carolina MESCO Project Number: G20003.0 MUNICIPAL ENGINEERING �� SERVICES COMPANY P.A. 68 SHIPWASH DRIVE, GARNER, NC 27529 • PHONE: 919�772-5393 P.O, Box 349, BOONE, NC 28607 • PHONE: B28-262-1767 LICENRE NUMBER! C•D2B1 TABLE OF CONTENTS SECTION Introduction....................................................................................................................................................................................................................................................................................................................................Page 1 Background....................................................................................................................................................................................................................................................................................................................................._Page 1 SamplingProcedures........................................................................................................................................................................................................................................................................................................Page 2 FieldParameter Data........................................................................................................................................................................................................................................................................................................Page 2 LaboratoryResults.............................................................................................................................................................................................................................................................................................................._Page 2 QualityControl Samples..........................................................................................................................................................................................................................................................................................Page 3 GroundwaterSamples Detected Above Standards..........................................................................................................................................................................................................Page 3 SHEETS Topographic Map with Site Location................................................................. Single Event Potentiometric Map of Uppermost Aquifer FIGURES 1 2 VOC21, Exceedance Comparison Histograms............................................................................................................................................................................................................Figure 1 Total VOCs and Benzene Pre/Post Injection Comparison in AOC MW-26................................................................................................................Figure 2 Parameters in LFG Extraction Area Histograms (AOC MW-1B)...............................................................................................................................................Figure 3 TotalVOC Concentration Histograms.....................................................................................................................................................................................................................................Figure 4 TABLES GroundwaterMonitoring Well Construction Table....................................................................................................................................................................................................Table 1 FieldObservations of Monitoring Locations.........................................................................................................................................................................................................................Table 2 FieldParameter Data Summary................................................................................................................................................................................................................................................................_Table 3 Samplingand Analysis Summary ............................................................................................................................................................................................................................................................Table 4 Groundwaterand QC Sample Detections..................................................................................................................................................................................................................................Table 5 SurfaceWater Sample Detections............................................................................................................................................................................................................................................................Table 6 Hydrologic Properties at Monitoring Well Locations.............................................................................................................................................................................................Table 7 APPENDICIES FieldSampling Parameter Data Sheet(s)....................................................................................................................................................................................................................._Appendix A Laboratory Analysis Report and Chains of Custody..................................................................................................................................................................................Appendix B StatisticalAnalysis Calculations.................................................................................................................................................................................................................................................Appendix C Introduction On behalf of Alexander County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report with Corrective Action Update for an event performed at the Alexander County active construction and demolition (C&D) and closed municipal solid waste landfill (MSWLF) between December 28-31, 2020. NCDENR Solid Waste Rules 15A NCAC 13B.1632 requires that Alexander County provide this report to the NC Solid Waste Section (SWS) on a semi-annual basis. Laboratory analytical results indicate that samples collected from 19 wells contained between one and three constituents above regulatory compliance Standards. Metal detections are generally believed to originate from erosion of natural deposits. The source of VOCs is likely anthropogenic. VOC concentrations continue to decrease over time and distance. No constituents were detected in surface water samples above values listed in the NC 2B surface water Standards table. Corrective action to remediate VOCs in groundwater is ongoing within the four areas of concern (AOC) with updated information presented herein. A Corrective Action Evaluation Report (CAER) (DIN:27584) dated April 3, 2017 concluded groundwater quality has improved. The SWS approved that corrective action may continue as proposed and implementation of the contingency plan is not required. Background The Alexander County active C&D and closed MSWLF, is located at 2500 Paynes Dairy Road near Taylorsville North Carolina. The total waste footprint encompasses approximately 24 acres situated on 283 contiguous acres. The site location topographic map is depicted in the attached Sheet 1. The closed MSWLF ceased operation prior to 1998 and the C&D landfill continues operation on the eastern unit of the closed MSWLF. Both landfill areas are treated as a single unit in this report. Water quality has been monitored at this facility on at least a semi-annual basis since 1990. MESCO submitted two Assessment and Corrective Action (ACM) reports dated August 27, 2002 and April 11, 2008. MESCO then developed a Corrective Action Plan -Revision I (CAP -Rev 1) on February 6, 2009. In response to improved water quality and changing geochemical conditions the originally selected remediation approach was amended by MESCO in a Corrective Action Plan -Addendum (CAP -Add) dated December 20, 2010. Groundwater remediation efforts have been implemented at the four distinct areas of concern (AOCs) which are identified as MW-lB, MW-16, MW-24 and MW-26. Remediation technologies initiated to date with reference to their respective AOC include monitored natural attenuation (MNA) (MW-16, MW-24, MW-26), phytoremediation (MW-24), enhanced bioremediation via substrate injection (MW-26) and landfill gas (LFG) extraction (MW-1B). Following establishment of the two-year MNA baseline MESCO completed a CAER (DIN 13596) on March 22, 2011. Based on improved water quality conditions as demonstrated in the CAER the parameters and frequencies of future monitoring events were established by the SWS CAER review response (DIN 14150) dated June 16, 2011. A second CAP -Add was submitted by MESCO dated May 30, 2013 as requested by the SWS in a letter entitled Compliance Boundary (Relevant Point of Compliance) (DIN 18502) dated February 18, 2013. A Request for Appendix II Groundwater Monitoring Modification (DIN 20137) was submitted by MESCO dated November 8, 2013 which was subsequently approved by the SWS (DIN 20144) on November 13, 2013. A second CAER (DIN:27584) dated April 3, 2017 concluded that attenuation is occurring and no corrective actions other than what has already been initiated are planned at this time as approved by the NC SWS (DIN: 27678). 1 As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, corrective action update, ground/surface water characterization, and findings. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, time -series graph, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedures MESCO personnel performed this sampling event following the parameters and frequency established in the Water Quality Monitoring Plan (WQMP) dated August 11, 2016. The water quality monitoring program includes a combination of detection, assessment and corrective action monitoring with specifically defined analysis. Water samples were collected from all monitoring locations outlined in the CAP -Add and CAER with the exception of MW-lA; which has been chronically dry. Monitoring locations are depicted on the potentiometric map (Sheet 2). Sampling was performed per the protocols outlined in the WQMP. A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Submersible pumping or bailing was utilized to purge the wells a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from previously designated locations along discharge features. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre -preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper chain of custody (C-O-C) protocols and within the specified hold times for each analysis. Field Parameter Data Field parameters were recorded including depth to water, pH, specific conductance, temperature, oxidation reduction potential (ORP), dissolved oxygen (DO), hardness and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix A. Laboratory Results Pace Analytical Services Inc. (PACE) of Huntersville/Asheville, NC performed the laboratory analyses. Groundwater, surface water and quality control samples were tested for a mix of Appendix I parameters, mercury and MNA performance constituents as prescribed in the approved water quality monitoring plan. Water samples were analyzed to the Method Detection Limits (MDL) and reported to the Reporting Limit (RL) which are both established by the laboratory. Any value above the adjusted MDL and below the RL was flagged as a "j-qualifier" which the laboratory defines as an estimated concentration. Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. A sampling and analysis table summarizing the locations, laboratory, target analytes and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix B. 2 Quality Control Samples No constituents were detected in either of the quality control equipment and field blanks (EB, FB). Groundwater Samples Detected Above Standards Table 5 summarizes constituents detected in groundwater and QC samples compared to groundwater compliance standards which include Interim Maximum Allowable Concentrations (IMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal "Drinking Water Standard". Metals One to three total recoverable forms of metals were detected above their respective RL and NC 2L Standard/IMAC Value in samples collected from 17 wells as summarized below. Metals Detected in Groundwater Samples Above RL and NC 2L Standard/IMAC Values Cadmium Chromium Cobalt Mercury Vanadium 2L/IMAC 2 10 1 1 0.3 MW-1 5.7 MW-lB 42.1 3.5 MW-2 243 MW-3 17.5 MW-4R 183 MW-6 5.8 11 10.9 MW-9 200 MW-11 128 MW-12 2.1 47.8 MW-14 7.6 MW-15 154 2.2 MW-16 194 MW-17 15.6 MW-24 10.5 5.4 MW-26 93.9 MW-31 2.7 MW-33 7.6 Concentrations in ug/L 3 VOCs Benzene was detected above the RL and 2L Standard (1.0 ug/L) in samples collected from MW-3 (4.9), MW-5 (2.6), MW-7 (2), MW-11 (2.7), MW-12 (2.6), MW-15 (2.1) and MW-26 (1.5). 1,4- dichlorobenzene was found in sample MW-3 at 8 ug/L which is above the NC 2L Standard (6 ug/L). Vinyl chloride was detected in sample MW-7 at 2.3 ug/L which exceeds its NC 2L Standard (0.03 ug/L). A bar graph and table comparing the most recent levels of VOCs exceeding the 2L Standard compared to their respective maximum observed levels is presented on Figure 1. A site map depicting the spatial distribution of VOC concentrations exceeding the 2L Standard during this sampling event is shown in Sheet 2. Surface Water Samples Detected Above Standards Attached Table 6 summarizes constituents that were detected above the MDL compared to compliance values listed in the current version of the Division of Water Quality Surface Water Quality Tables. Cobalt was detected in sample SW-5 at 14.4 ug/L which is above the NC ISTV (4 ug/L). Groundwater and Surface Water Characterization At the landfill, groundwater flow direction generally mirrors topography, thus flow direction is from higher to lower elevations as shown on the potentiometric map included as Sheet 2. Locally, groundwater flow is expected to be generally westerly toward the Lower Little River, and southerly toward the Catawba River. Groundwater linear velocity rates calculated using modified Darcy's equation varied greatly and were slower in the upper bedrock fracture system than the less prominent regolith (Table 7). Streams at designated monitoring points were visually observed to be of normal seasonal volume, flow rate and low turbidity. Hydrogeologic parameters appear generally consistent with historical observations. Corrective Action Update Groundwater remediation continues to be implemented at the four AOCs designated in the CAP -Add. General background information and activities performed since the CAER and last semi-annual event are briefly presented in the following sections. MNA Analysis (ADCs MW-16, MW-24, MW-26) Semi-annual MNA monitoring of 14 wells for the full suite of SWS recommended parameters was initiated on June 30, 2009 and performed during four consecutive semi-annual events to establish a baseline per the CAP -Revision 1. The number of wells requiring MNA analysis was reduced to 10. The parameters and frequency were also amended per the SWS CAER review response (DIN 14150) dated June 16, 2011. MNA data collected during this event is presented on Table 5. Following an acquisition of a 15.7 acre parcel from Crescent Resources on March 3, 2011, extension of the eastern relative point of compliance downgradient of AOC MW-16 has been approved with conditions by the SWS on February 18, 2013 (DIN:18502). Recordation of Survey Plat titled Survey for Notice of Contaminated Site Alexander County Landfill and A Notice and SWS approved Declaration of Perpetual Land Use Restrictions for this parcel has remained at the Alexander County Register of Deeds Office since November 13, 2012. Alexander County purchased another 2.15 acre parcel that adjoins the NE 4 corner with deed recorded on 3/26/18 which effectively increases the relevant compliance boundary in a NE direction. The SWS approved CAP -Add and CAER (2017) clarifies that groundwater remediation of AOC MW-16 will remain as MNA, rather than other technologies described in the preceding CAP -Add. Phytoremediation (AOC MW-24) County personnel planted approximately 200 hybrid poplar trees over an approximate one acre area between MW-7 and MW-12 in May 2010 in an effort to phytoremediate groundwater in the MW-24 AOC. The County continued to maintain the fence -enclosed stand during this semi-annual period which included supplemental watering and eradication of competing vegetation. Total cumulative VOC concentrations in AOC MW-24 during this event have decreased 46% compared to its respective 2 year baseline established in 2010 and a statistical decreasing trend is evident. Assessment of the phytoremediation area which includes tree measurements and downloading groundwater fluctuation from dedicated transducers was performed by MESCO. The majority of the trees appear to be dying or have died; therefore, Alexander County should consider replanting trees. Enhanced Bioremediation via Substrate Injection (AOC MW-26) hi an attempt to remediate benzene as detected in MW-26, Bac-9 was injected 50 ft upgradient in IW-1 on February 17, 2011 following conditions in the Underground Injection Control (UIC) Permit WI0300160. The UIC permit was recently renewed and as directed by the UIC post -injection water quality monitoring of MW-3, MW-11, MW-26, MW-27 and MW-31 is required on a semi-annual basis. Benzene has risen above 2L Standards in MW-26 during this event. Contaminants remain within allowable levels at MW- 31 located along the MW-26 flow path beyond the compliance boundary. Most recent levels of total VOCs compared to the baseline established during the four events prior to injection exhibited a reduction both upgradient (-5%) and downgradient (40%) of the injection point. Most recently, total cumulative VOCs from all samples in AOC MW-26 decreased 13% and benzene concentrations fell 30% compared to the baseline averages established during the four events performed over the two years preceding the injection (Figure 2). Additional injections are not planned at this time. Landfill Gas Extraction (AOC MW-M) Three LFG extraction wells (MEW-1, MEW-2, MEW-3) were installed screening the majority of the vadose zone at the northern border of the closed landfill in the vicinity of the scalehouse. MEW-1 was installed on August 17, 2010 with MEW-2 and MEW-3 installed on October 20, 2010. Well control heads were plumbed to a header pipe by the County which was connected to a soil vacuum extraction (SVE) unit on July 5, 2012. An active LFG blower system pilot study was performed by MESCO between June 14, 2012 and July 12, 2012 to evaluate the effectiveness a vacuum would have on reducing levels of LFG in the soil which may remediate the low-level VOCs detected in groundwater hydraulically upgradient of the landfill. A comparison of LFG concentrations and pressures before and after vacuum start-up indicated the system is capable of eliminating LFG migration at all locations monitored within AOC MW-113. The active LFG Collection Control System (LFGCCS) has been in continuous operation since November 1, 2012 and been verified and documented by MESCO personnel on at least a quarterly basis to be mitigating LFG migration through the vadose at all locations monitored beyond the extraction wells. Improvement in groundwater quality has also been observed in response to implementation of the LFG extraction system as summarized below and shown on Figure 3. 5 Sheets Topographic Map with Site Location Alexander County Active C&D and Closed MSWLF 'rv��o ar.7e oevewr.r�f o�� -xe irvreRiov 2500 Paynes Dairy Road Taylorsville, NC 28681 Lat:35-15-18.7246 Long:-81-08-51.51.32 Northing:767009.09 Easting:1363506.43 tN rLANDFILL PROPERTY QUADRANGLELEGEND ROAD CLASSIFICATION Primary highway, Light -duty road, hard or hard surface .............. improved surface .... ___ Secondary highway, hard surface ............ Unimproved road..._________ 0 Interstate Route 0 U. S. Route O State Route 0 1/2 1 MILE SHEET 1 I -�\ \ \ I I I' / / \ 11 \ \\ -- ______= \ \ \\ \ \ I r // \ ', - ' /' ---- `\\`� \ `\ `\\\ \\ l I. 1\ 1 l I. ,/,', -___ \ `\\ \ \ \ \\ \ \ ) t I MW-20 W-19 1 I MW-1B I i , , , _ \\ \ \ \ \ \ \ \ \\ \ \ \ \ \ I ,/, , �I �,�----./--_ `\ \ \�\`� \ `� \\`\ `\ \\\\\\ `\ \ \ \� GWE=1008.78 GWE=1024.25,- ,' GWE=1046.31 ,,' ' MW-18 , -- \\\ -, \ \ \ \ \\ ,' , , , ' , , , / ♦ \ \ \ \ \ \ \\ \ \ I I \ \ I I 7 \ ♦ ••■ MW-1 + , / --- \ y ,ice' / , , , ,' / , , , MW-21 `\`� \ \ `� \`�\ `\1 I I I , I \\ I /--� ■ \'`i1 00fO♦•• GWE__ 104 ,' ` ,' `\ \ �� i ,' , / , , , , , , , , - , / ♦ \ -, -,\ \ \ \ \ , I I I 1 I \ \ ` I I , , Y ,-, �♦ + ♦♦ i -. \ /' .l.a� \\ \ -- Y�` //' - ,',i' /' ', ,'' ,' - ,/,, _, ♦♦ GWE=960.83 MW-17 \\\ \ \ \ \ , I , I I 1 1 I , ♦ 1- ♦ / ' / \\\ \ - / / 1 ♦v ,',',' ,', i �/ , ' ,'�,'' '� ,'/ �- - ' I ♦♦ GWE=978.70 I\ \ \ I 1 \ , "I I\\ , I \ \ ' rr ..�■ ��' ♦1 -� \ _1 v // \ -- � \ ♦♦♦ /,-,i,-,- /,�,�i' / / �� '' �,� ���:1 M M 1 1 \ \ \ \ \ \ , i - i \ 0- - - - - , J / / / , , , ,, - , i ' /'� -�, ♦ . • 1\ \ \ \ 11 \ ♦ \ \\ Y 1/ ♦• i' \ - _ MEW-3. iI (>� J ♦♦ ,, , 1,,, , _offirl, / /,/,' ,,� �,' �, �,I �/' ,', �,�,' �,�,�,- I ,.♦; - %''- Benzene - 2.1 Ug/1 \� \ `\`\ \\`\ l II \ II I I I _ -0 • �= � �;� ■'y•• 1 I i /,/ 11 ,/ "�,,-,,, �, ,,�� - �,'' �,��/�/ 1 , ,. \ \ \ I I 1 _ MEW-1 = __- l \ . ■' 1 I I % \ - - % i/ i /---�-,- i / / % / / / % /� / , ' , , '' - / / I ' MW-15 _ 1�'N`/I 1 \ \ l '------_--- I\ / \ / �"-- / , , ,' / , , , + / - / ! / ' / / \ L 1 11 f MEW-2 \ \ \--� \_ --_-_ - �'i'ii'/, �'�' �/,-5 �,,,'' ,' ,'/,','' ,' /' l , �l l /','_-__' GWE=1001.99 , ,,, ,/ 1 ) I -_ill \ \ — — -- -- \\ 11 /Ill _ ' ', ,, / // /, / '_%' p6p - -- 1 �� — — � _ \ (c-r� '' I i ♦ LFG VENTING SYSTEM -' -- ' / ' /' /,' /,' ,' / ,' ' MYY-22 / I ♦ I _ ___-_-_-__- ;,',' / -- I - >% ' \ \ I / l 1 I I 1 I ■ _---- ''i ��'//�� i��'/�,%i'i, GWE=944.86I 1 �'�� - \ l\\ --0` _I 1_�� / / \ -`_ , \\\\\ ' / / % / -__ ----- _ , ,/,/,,/ - _-- __ ------ _ __-_______--- /, ,/,,/ , , -/ ,' ♦♦ `-_ ` 1 \ -- \ I / \\` / / / / ■ -_____- _/,',','///,'I - ''/'', - \ ♦♦♦ �//! I I , / /� /-� \\ \+ \\ CLOSED --- _ \\ I /'/ ■ _______ ' �� i i / , ' ' '/ ♦♦ /'i r///� v / / '� \ \` -- MSWLF \\ \\ I I \ / / / / ■ ,, / / / � / / /// / / / />'-,',/ I i / / / / / , ,4 �p ,� 1 II/ l /, //,�/ / / \\- \ ' \\\ \� \`� GWE=935.21 ♦ MW-14 ! ., / lr ', /' ---- l l l I I , / // / ■ / / I , \ \\\ \ \ \ I ( / ! /r' -- �/ ,,r / cb� -- - II 11 I I // // / I ■ MW-2' 1 G WE-987.2- 1 -------- // // //\__ \\ \\ \\ \`\ \' \ �` / 1�, -, • _ / / �� I I I I l l / I� ■ / / \` \\`\ \ \\\\ \� -\ -- �` I ,/ //.1♦�+,/ /, /' / / / - / -- / / / / /// ____------ --' - 1\�I/I, ,\,) / I / // . I / / ///// I r--- ` ■ / / \\\\ \\`\\\- \---\ -�_� _ - ------ - / �, / / / / / 1/ / I I /,' I / 1 IIII I -, 11 ■ / ; / 11 `\ - `- - - -- - - - - - - __ rp\ \ \ ♦ ' --- _ / / / _,' i I , _ //„ /, I / I I Iq I 1 \ ■ __ __ _ __ _ _ _ `� MW-5 - ---;______ ' , / , ^_____-_ / // , �� r1 �/, , , / - ■ Benzene - 2.6 u /I rt / // ' / \"---\- - -`- ----- -7\�' /' ,' / �1 /, "/ / , // /I / !- ,,_-- ' ,,," I -�\ -__ ��I //l� li'/ / / / / l 11 g / / \ / / , / , �/ / -0 , ,,, / //LTA / / /^ - `-- --- \` / ' /' / / ' ,' - - , . 'T- , / CLOSED ,', , / �/ _-_ Ojp l ! ( / I I l I ■ / _ --\ - -- ,'/' /' /' , ,� /� .r-(`� / p� . Q MSWLF / / -- - MW-5/l / // , / r l lI 1 / / , / / , / / , , - ,, // / / , _//, , , / M / / / / I I 1 1 ■ 11 7 /' , _ _ _ � / / I (' /' /' /' ,' , , �' / " ' ' / _ / ! / / ■ MW-34 _ _ OR / , / // / ,/ /, // ,/ ,, „" -/ '/ / / ' / ( / , '// ' a- GWE=1014.36 / / / // I '' . / pr / / / // / l M GWE=1007.01 \ / / / / / / / / / // / / , / , / / / ,, �,�,C, /,///i//GO I I I 1 1 �, -_ /r/'L//' ,7/%r ! ! / /// / l l I ,/, / / / / I , / , , // M /,,// / , ,// r / / / .e I I ACTIVE C&D OVER /O,S ,,, ,o / , / / „ / , / I ) / O ,i'i'/ //// / / / / / / // ///�'i//,' / /, , cz /- ,1%, r/!� / \ \ MSW _ - - _ ,,. / ,/ w 16 / / // jl \\!I I I I I / // / / / / // / / !, //, / , ,�, , /,, \ \ / / GWE=1009.98 /, l I / l// l / / / / ',/r , / !' 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' li / / II \\ \\` \ \ \\ ` / / / ; /! / /,� / / / I 4 \ ,\ \\ \ ,1 1 1 , \ \ \ \ \ \ \ \ / . / r / g I- /I 1 r \ 1 I \ \ \ \ \ \ \ \ \, \ `\ --- --- --\ \`- \ ,,�, \\ ---''- /' /'/' / / M ♦ ♦ I / 1 / / / , 1 '1 y \\ \ \ \ / / // // , / / l \ 1 1 1 \ \ \\MW-12 1 I / Il „ l l I 1 \ - / / / / , I , ,, , III I I 1 \\ \ \ \ \ \ / r!,' /,/ /, / \ \ \ 1, 1 \ \ \ \ \ \ \ \ \ \ \ -- -- - -- \ \ \ ----- ,' / , / / / / / / • ♦♦ - J / / / / / C- ,� , , , l I l I Ly III 1 \ \ \ \ \ \ \ \ ic< I'` / / // / / / / / \ 1 \ \ \ 1 1 1 1 \ \ \\ \ \ \\ `� ` \ - -- - -- `\ `\ ----------- ,/,, / / / / / / I / /GWE=958.94 44 - I I /\ 1 / 1 ./ / / I I / \ -- '/' ,',i' /1 1 I I I 1 / r , \ \ \ \� \ \ ♦ `--- _ / / // / / / / SW-5 \ \ 1 \ \ \ \ \ \ \ \ - -\-- - - \ -- - , / / / / / / (' * I ♦• I I \ / / - / , I I I I , \ 1♦ \ \ O ' , / / , // / / \ 1 1 1 , 1 \ \ \ \ \ ` \ \\` ` \ `\ - -- `.�-- -_J--------- , / I I I I MW-12D 1 ♦♦•♦ / / \/ / ,, \\ / / �' , 1�,^ I 1 I / d11 t 1 I 1 \ ♦\\ \ \ \ \� ` ` - / /' '/i' / �1 I 1 I I \ \ \ \, \ \\ \ - -� -- - / l l l I I 1 - ♦I� ♦ ,' /' / 1 1 , I I 1 ✓ \ \O \ \ r / ' % / / % j \ 1 1 I I 1 \\ \\ \\ \\ \- \ ( J I I . ,, i , , I I 11 Q7-1 1 1 'f \ \ \ \ \ \ ,' / / / / / 1 1 I \\ \ \ \\� N \ \ \\ \ - - \ 1 \ GWE=952.27 \ -- Ell / /_ , ,, V d I 1 = 1 I \ \ \ \ \ I 1 I \ \ I \ \ \ \ \ \ \ \ \ -- -_ __ --11 -- l. INNER \\`\ `\ --- --- \ �1 - \ \\ \ \� -- - \\/ ,i !!� ,/ �♦ ZO o O I I ■ I \ \ \ \ I 1 / / / I 1 1 I 1 I I \\ \\\ \ \ \, - -__ -ii�-- - - `\`\, \`\-----------------`\ `\ \\ ` \\\\ \ \ \\yl\ \\ \ \ - - - --/ // !/ / i - - I I 1 I / j y1A`,R \ \ \ \\ \\ \\ \I 1 I / / j / , / // , 1 1 1 1 I I I I I I I I I I \ \ - \ \ \ . ! I //- P I /i---- --_ I I I \ I I ♦ \ \ \\ 1 I I I ,, / / // /, , I I I j 1 I \\` ` \\ \ ---------- -\ `\\ \\ - - - ! I b ---- -- ----- \ I 11 I I I I 1 1 - \ \ \ \ \ \I \ I 1 ! ; I I I I I I I I I I ' II I I \ \ - \ \ \ \ \ \ \ \ - I. I I I 11 \\\ \ 1 I I I / / / / /// , I I I I I 1 __ 1 I I III I' \\ I / / / I I / / / /-I I I I I I I \ \ / / I I I I I I \ I / / // // / 1 1 I I \ \ \ \------_- - \ \\`\\ \ - --- -- ` ` \ \ -\ \ ` \ \ \ \ ` `\ �= - ` / M ('��----- I 1 I I I I I / I I I • •�� 1 1 1 I 1 I I \ \ \ \ , I I I I / / / / / 1 / I I I 1 I , I , 1 1 \\ \ `\ `\ -` `� \ \\ \ - \ 1 / -- r ,-- I I I I I 11/ \ 11 I • •• I I 1\\\ \ I 11 / / / 1 I I I I I -- -� -\ `., 11 \ \\ \\ \ ----` `, / GWE=971.31 _ 1 , J iyL. I • III III I I \ \ \ \\\ I I I / / / I I I / I I I 1 I \ \ \ \ \ .....� ........ . 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I \ I \ \ \ \ CONTOURS (DECEMBER28-30, 2020) ,_--;;----_-\ - I--,/-- -J___ ,I \ \\ \\ 11 \ \ \\\\ \ \\ \\ \ \\ \ 1 I \ \ 11, I \ \ \ \ \ , \I \ -\ ,,, 1 I l ! �I, i\\ //>� i I I I I l I ,'/,/ / / //� III o�� \,\`- \- - /% \, \, \ \ r I I \ \ \ \ \ I I I \ \ \ / / ` / //// I 1 GROUNDWATER POTENTIOMETRIC ELEVATION ---\ `--_ ---- _----- \ I I I I , \ \ \ \ , \ \ \ \ \ \ \I \ \\ \ 1 I \ \ \ ,\\ 1\ \\\, , \\ \\ , \\\ \\ \ /, I I I I I �I\I \� , �\ --' ��/ / / ,, , 1 I I 1 1 III ,,-' / ! / / , Ili _ !! _ , GWE=974.6 --- _ / I I I 1 \ \ \ I\ \ \ \\\I\\ \\\I I \ \\ \ 1 \ \ // / I I I I -r>^ --, ,/ r, I I 1 1I II I I ( / / / /� // /// III -_,_ \\ %// - 1 \ *NOTE: DEEP WELLS NOT USED FOR CONTOURS - '' _ ' / l I 1 I I 1 1 I \ \ \ \ \ \ \ \ \I \ \ \ \ \ ` ` 1 1 `\ ` / / I 1 I ) y ,/ r , , I I 1 I I I I I ( / , / / / / I I 11 , ;;/, , /, \ _--- \ `\ -' ---- - ' / / / I I , I , , \ I I \ \ \ , \\ I\ \ \ \ \ \ 1 I I \ \--J I I I l `-_ - / / r I I 1 I I I I 1 1 \, / �_- = I /, / / / ,-- -- / I 1 I \ \ \ \ . \ \ \\\' dl \ \ \ \ \ , I 1 I I 1 1 \ , I I -�J / / \ , ' I I , / / / /, / 11�==- _ __ , , ----� \ \ --- /, / / / / / / I I 1 1 \ \ 1 1 \I \I \ \\ I \\ \�\\\ - \ ) / I I I I 1 \___I I I I I I // /-, - I I I / / / / L==='___- \ '/ / , / - \ \ / ! / / / I I I 1 \ L n l \ \ , I 1 I I I I l I I \ 1 1 I I I / / ` - _ / / / / / 1 I I 1 I I I I \I \\ Ill l __ zL) I I l \ � , ' „ ' / , \ / I I I / I // 1, \_', ' , / ' / --\ \ \ \ �/ _---- / / / / 1 1 1 1 1 \ \ 1 \ I \\ 111 �\ I \ \ ` / l l 1 / I 1 I / / l l IKtiY1 I / ,/ / / �, I 1 I I I I 1 1 1 \ I I I / I III �_ __--; I I ` �,,' , , ;/ , / , I I LFG PASSIVE VENTING SYSTEM---- \\ -_� _--' / / / / / // ' / I I I I \\ 1 \\\ I 1/ I I I I I I I l l\` I 1 I / / / I I 11 I \ \ I I 1 I I 1r� II \ ' "/'/ //i", l l I I \\ I\ \ \ _ -- ,/ / / / / / / 0,/ /' ,/1 ,/ I I I I \, \ , \ I1,1 11 \, 11 `l 1 / I I l I 1 I I I l / --- I I I \ 1 ,'Y1y / / / I I I I I I I \ 1 \ I (� I III IIII f I = \ \ \\ \ � ' , /' / / / 1 ! j l --\ \ / I 1 1 111 / I I I / /� \ I 111 / / / II I'll I 1 \ \ , '' \ \ \ __--- , / / / , / �, / / , / I I I I I 1 111 \ (` III I I I I I I I 1 / \ 1 \ 1 I �,, I'll / I 1 \ -- , , I 1 I I III \ \\ --_/ / ' ' / / / / / / PHYTOREMEDIATION AREA ��-.111, \ \ \\ \\--,'�,----------- ,,' // /r / / ,\O, ,/ / // / I I 1, 1, 1 1'1 I 1�1111\\11 III 1 q' l ' k,_ 1 ' 1 IIII, 1 , ' `),' '- ' 1 I 1 I I 1 \ \ \ I I l 1 I I 1 f i n\ \\I \ \ ` / / ,/ , / /'/l 7 "Qa -�'�4 1 1 1 \ II IIII \ I I II I I 11 I / \\ l iX' ' 1 1 1 \ \ 1 1 1 1 1 1 :-_ :' /// // / �'\\ \ \ , / . ! , ! , / I II I I,I III I 1 \I1 IIII 1 II / / / \ \ \\ \\\ \ \\ -y- /� III 1l,C 1 \ , \ \ \,\, IIII 1 I111 I \\ \\\ -__-' ,', !/r, /,// \ \\ 1 \ \ \ ,' ,'-----------' / / /' / / / / , , I / I I I I I II 1 1111 I I I I I O I I I / / \ \ (- / I t \ 1 \ I I I ill' 1 I \ \` `\ / ' / / / / // / // \\ \ , ,-- / , / / / / ,, ,, // / / 1 II, �I I, '11' 111 I I 1 f I 1 / I I / I / I l - \ \ \ \ \ \ \ / II 1 11 \ I \ ` 1 1 I I 1 I I II '\\ \ \\\-- ��� , / r/// /// -- \ \ , I \ \ ---- ,- ,' ' ' / / I / I I I III III I I I III 1 I / I \ \ \ \ \ I r I 1 1 1 1 I \ \ \ \ \ \ \------! / I / / / I I I, I I I i - / I \\ ♦ _'--- ,' ,' ' / / /' ' ,',' / I I I / I IIIf Iff1 '11I II I III I I / I I , \ \ \ +9\ \\\� \ I \111 I \ \ \ \ / / ///I 11 I IIII 1\\\ `� ------ / //// /%''/ ''''''' ---- , -� -- // / / /, , i / II I IIII 1 1 11 1 I I 1 I I \�\\ V' \ I \ \ \ \ , i l l / I 1 If 1 \\\ --- �� /'/ /i // I \ \\11 F / I l I I \ I \ I \ \ \ / I I I 1- \ ---'-, / / / \' \\ \\ \ sF --- /, ���,, ��, /, / /// / / //% 11 f Illf II IIII 1 I I I I I I 1 - - 1 1 I 1\ \\\\ n \\\\1 / , ) \ \ \ \ \ \\� �\ _-- i % l l I I I ' \\\ ,-,'// // / / ,' / / / / , / l I I r I I I I I - / I I \ \ \ 1 /1 - ___ / l l Ill I I \\\ \ k ! IIII \\\\ `--% �/� _ \ �,'� ' ,/I I /','/'-__ ' // / /I/ Illl/IIII\ IIII IIII I III I I I I I I I \ , I\\\\\ \ I,1 I�1//11 1 \\\1\\ \\\\� \ -----`--- ,/ //,/ /II I1111, \\\ / 4r ///'// // / , / , I - , /I I \ , / / I 1 1 \ \ I \ , 1 ! // ,, ,, ,,' ,, , / ,/ / ! /,, _��, ,, / / / l 1111 l I II I I \ 1 111 1 I I 1 1 1 I I I 1 \ I , \ , \ \ t , I I f 1 \� \ \\ \ ----------' ,/' / !/ 111 l , I11 IIII _ \ \\ \--'' // / /// / / / II I I \\ \\ .,4Q / , _ , / / _ _ , / , / I I 11 \ 1 11 1 I \ \ 1 I lI/ \ \\ \ -\�----_ // /, Ir \ ,- / 11 I 1 \ \ -� -- _�'_,'-, / / /,,' ,, ,�, ,/ // / / / ,,-___' ��',/ / / / I llI 111 / 11\, ,111 IIII \ 1 1 1 I I I 1 \\ 1 t 1 , \ \ 1 1 , 111// 1 \ I \ ` ---- ,''/ / / // / \ ` / // / / /// / / / / 1 1 \ \\-_---''' ' / / , 1 I ,- ,' ,'--'-- ' /' '' i / --- - II I I l l 11 I 11 I, - , It , 1\ \\ \ \ 1 I I IGRAPHIC SCALE I j I I ' \ \ \ \` ` -------------_-_�_ ,% / / I \ \-- , j / %//1 / , 1 / 1 I \ 1 11 I \ \ I t I / \ \ /, , / / -, / / / / _ I , / I I \\ \ ♦ - , , // \ \ \� \ - ---- I I I , 1 ' , , ,'' ' / / / / / ' --- _ - , �' / / / //I / 1 \1 1 1 1 1 1 1 1 1 \ \ \ \ I I I I I 1 11 I f � \ \ \ \ \ - _-------' � ,' / 1 `\ �' / / \ \ - - _ _ \ l ",� , , 1 / / / . / r,' _ �', - , 11 I / n 1 I I I I 1 1 \ \ \ 1 I I I I I \ \ \ / / I c / / - -_l0 _ 1 I I 1 \ , / / , ,'' ,, , / , , /, -_ , lI 11 1/ l \\ 1 I 1 1 1 1 \\ \ 1 1 I I I I 1 I I I�� \ \\ \\ `\ \`---_-__-------- ,///// I I I , ---'' / \ `\ - QQ = = j 1 / , / � , , _ � I �1 1 1 I \ \ `\ I I / I I 1 I I �i \ \ \ _ _ _ / I - / / / // / / 100 0 50 100 200 \ -_------- 1 I I ,I I I \ I / , _ -- , / / /, , �% �, �, , 1, IIII 1, j1 11\ I I \ \ 1 \ \ \ - / / it I \\ \ \\ \ \ `-- --__ --'' ' ' / /,/ / //// I I , t / / // / -_-`_ ----- � l l 1 I I I � \ r / ,' ,' ,, , / / /, �'� l 1 I r 1 1 I \ \ \ \ 1 \ \ -- / / / , � I ll I I J11 III \\ \ \ \- -_ --_ ----- �/ / , /, / / / � / / / / / / ` _ I / / I 1 I 1 1 \ \ , / / / / /, / , / // 1 / \1 ail 11 \ \ - / / I I IIII //// II 1 I \\ \\ \` - - , / / // //// / I /, / - - J I 1 1 ,1 \ \ I\\ ( ,' �� ,,/' // / ,'/ / ,, /1 / 1 III I\ \ \\\ \ \ \ - , / I \ \ ---- / // 111 I l I , / / / / \ \ \ , / !' , , / I I I1 , 11 \ \ --__ ! I / I IIII I f (/ I 1 1 I \` \ \` \ -__ '-----------, ', /, , / , / /, \i ! I l / / . l / I 1 1 \ I \ \ \ \\L \I ('/' ,' i ,'/ / / /, - ,' // �,,/// lI I I I\' jj1 1\\ \ \ \ \ \ \ \ -- / / 1 I f \ \\ ` \\- - _ ,, /, !, //// /,.1" / /// / //// /! / / / / ,1 \ \\\ \�9 \\( ,,, /,// , e_ r! ��, /, 111111111\\\ \\\\ \ \ - / / I I II Illl\\\\\\\ \\\ \\--_ --_ /' // / /// / 19 ■ q M M Z III N � `° L� i IL <` N W>1111111111111111 Q1 � 6 N W Lj ZU N Z Z 0W^ aoco 0 (B a rn a N ° 1�1 Z 2 N V,� � � U U W W O N U t0 CO m 2 L3U Z N Z) Z J � W Z Z W m Z QL9 W 0 [] IL W W °J M U _ 0 I Z:] a/ 3 M X M � W =° 2 to rn a ko F1)� Z O� ~ INNERINNER oft u J LL O J LLI � � I- o 0 z 'a' °ZS z � O = J z OCC J v O 1'� '^ Q V v♦ Q v Z) Z c) Q 2 F► CC Z O J �I Z v dc Q Lu Q t� V O Q J V U-j u- Z Q Q o IL U � O /;� I N N w ru W I C) a � Q � O m Q V) z O CL � Z U Z uj � Q w W Z U � m iI z � � uj ~ a SCALE: AS SHOWN DATE: 212121 DRWN. BY. J. PFOHL 400 CHKD. BY. PROJECT NUMBER G20004.0 -W-(1J ! / / % / / ( \1 1 \\ \ \\ O\\I� ' � / / % ` I__ -- \ \ \ , / 1 \ \ - i, I 1 1111 \\\\ \ 1 \ \ \ -__-------' / / / r ' „ f ' %I ( IN FEET ) \h._ / , \ \ \ \ \ ( , / , /, / / \ \\\( \/ 1 \\IIII \\1\ \ \ `\ \ \ -\ --\ / I / I I \ \ // /// // //// //// \ \- / / / \ \ I \ \ \ \ \ \ \ , / \ -- --- ♦ \ `\\\ \\\' I11111\\ \ \I \ \ \ \ \ `\ -\ `-'' -/ 1 I \ \ \ 1 I 1 1 IIII 1 1 1 \ \ \ -\ _-_ / / / /// // / /// / //// DRAWING NO. SHEET NO. O/O/ \ \ ♦ \ / / / / / I I I \ \ \ \ I , \ \ \ \ \ \ ( --- -- - \ \ \ \ \ \ \ \ \ 1 I, \ \ \ \ \ \ \ ----'' -,/ \ 1 I 1 I 1 I I 1 I I I 1 1 I \\ -- - -\ ------------- / / / / / / / / / \ \` //// I I\\\ \\\ \\\\ \\\` -\- \\\\\ 1 \\ I\\\ \\\\ , SHEET 2 I / I / / / / / �' �-CI-C.w-A.cs� 1 \ \ \ \ \ I \ \ \ \ \ \ \`\ - -- -- -\ \ell 1 1 11 \ \\ \\\ `\ \ \ \\ \\ �-------------- ` 1 1 1 I III 1 1 1 1 `\ ` - -_ -_ ' / / //// / / / / /// / / /! 1 / \ \ - - - \ I \ \\\ \ \ \ \ \\ `\ \ \ t I 1 1 1 I I I IIII I I \ \\ \- -- - --- , / /// / /, / \ /// / / / /,! // / SHEET 2 1 OF 1 Figures Figure 1 VOC 2L Exceedance Comparisons Histograms VOCs >2L Std (December 2020 Compared to Maximum) 10 a 1 s J m 6 4 2 0 ■ BENZENE Max ■ 1,4-DCB Max ■ VCM Dec-2020 BENZENE Dec-2020 1,4-DCB Dec-2020 ■ \ Parameter Name 2L Std. MW-3 MW-5 MW-7 MW-11 MW-12 MW-15 MW-26 -20 a c-20 Max Dec-20 Max Benzene 1 2 6.7 1.5 3.2 Vinyl Chloride 0.03 77717! 1,4-Dichlorobenzene 6 8 Maximum=Highest ever reported (1995 through Dec. 2020) J 6 3 4 2 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 2 Total VOCs and Benzene Concentrations Pre/Post Injection Comparison in AOC MW-26 June 30, 2009 - December 31, 2020 Cumulative VOCs �roEO k Oman 1uwJ 0u1vJ1 0MN-11 0AtN36 - pMMJ 1-1 Benzene Total VOCs & Benzene Concentrations Pre/Post Injection Comparison in AOC MW-26 Hydraulic June 2009 (ug/L) Dec. 2009 (ug/L) July 2010 (ug/L) Dec. 2010 (ug/L) Average of Four Events Preceding Injection (ug/L) Total Cumulative VOCs Benzene Gradient In Relation to Injection Well (IW-1) Well ID All VOCs Benzene All VOCs Benzene All VOCs Benzene All VOCs Benzene All VOCs Benzene Dec 2020 (ug/L) Change (ug/L) Change % Dec 2020 (ug/L) Change (ug/L) Change Up MW-3 61.66 8.10 43.03 7.20 31.50 6.00 37.04 6.10 43.31 6.85 24.29 19.02 -44 4.90 -1.95 -28 Up MW-11 53.28 5.00 46.25 4.50 40.81 5.90 43.20 4.20 45.89 4.90 69.25 23.37 51 2.70 -2.20 -45 Up MW-27 23.70 0.00 20.20 0.00 24.60 0.00 28.00 0.00 24.13 0.00 14.20 -9.93 -41 0.00 0.00 0 Subtotal Upgradient 138.64 13.10 109.48 11.70 96.91 11.90 108.24 10.30 113.32 11.75 107.74 -5.58 -5 7.60 -4.15 -35 Down MW-26 39.40 1 1.40 20.00 1 1.40 39.50 1 3.20 30.75 1 1.60 32.41 1 1.90 15.94 1 -16.47 -51 1 1.50 1 -0.40 21 Down MW-31 0.00 1 0.00 0.00 1 0.00 0.00 1 0.00 4.61 1 0.00 1.15 1 0.00 4.15 1 3.00 260 1 0.45 1 0.45 100 Subtotal Downgradient 39.40 1.40 20.00 1 1.40 39.50 1 3.20 35.36 1 1.60 33.57 1 1.90 20.09 1 -13.48 -40 1 1.95 0.05 3 Up&Down Gradient Total 178.04 14.50 129.48 13.10 136.41 15.10 143.60 11.90 146.88 13.65 127.83 -19.05 -13 9.55 -4.10 -30 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 3 Histograms of Parameters in LFG Extraction Area (AOC-MW 1 B) dissolved Met"a"e ire Grou"dwater s J 6 py S E 4 3 2 1 O O.9=71 �0�� �,�'"'� �tio` �,�A �,��� oy� oy� 01� �,�^ O1� �1$ �1`b O•�� �.�� �.LO �'L� Benzene Cumulative VOCs O REDUCTION SINCE LFG EXTRACTION BEGAN WELL ID DISSOLVED METHANE BENZENE TOTAL VOCS N N N MW-1 -97 -92 -96 LMW-1 B -99 -98 -93 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 4 Total VOC Concentrations Histograms Baseline (June 24, 2009-December 9, 2010) Compared to December 2020 35 30 25 J rn 20 TOTAL VOC(s) BASELINE AVERAGE COMPARED TO DECEMBER 2020 MW-1B MW-16 MW-26 MW-24 UNDESIGNATED SITEWIDE AREA OF CONCERN ■ BASELINE AVERAGE ■ DEC.2 AOC ID WELL ID TOTAL VOC(s) BASELINE AVERAGE (June 2009- Dec. 2010) (ug/I) TOTAL VOC(s) LATEST DEC 2020 (ug/I) DIFFERENCE BETWEEN LATEST AND BASELINE (ug/L) DIFFERENCE BETWEEN LATEST AND BASELINE ( /D) STATISTICAL TREND'Between June 2009 - Dec. 2020 MW-1 27.86 2.14 -25.72 -93 . Downward MW-1A NS NS NS NS HNo TrendH MW-1 B MW-1 B 17.31 1.27 -16.04 -93 �Downward� MW-18 0.00 0.00 0.00 0 HNo TrendH MW-19 3.48 0.00 -3.48 -100 HNo TrendH AOC AVG 12.16 0.85 -11.31 -93 �Downward� MW-5 19.84 18.81 -1.03 -5 TUpwardT MW-10 3.24 1.80 -1.44 -44 HNo TrendH MW-16 45.06 0.00 -45.06 -100 �Downward. MW-16 MW-32 0.00 0.00 0.00 0 HNo TrendH MW-33 4.40 0.00 -4.40 -100 HNo TrendH MW-34 0.30 1.97 1.67 560 HNo TrendH AOC AVG 12.14 3.76 -8.38 -69 �Downward� MW-6 0.00 0.00 0.00 0 HNo TrendH MW-7 15.27 8.60 -3.67 -44 . Downward MW-12 34.39 21.10 -13.29 -38 . Downward MW-24 MW-12D 1.00 0.00 -1.00 -100 HNo TrendH MW-13 1.59 0.00 -1.59 -100 HNo TrendH MW-24 3.18 0.43 -2.75 -86 . Downward MW-25 0.00 0.00 0.00 0 HNo TrendH AOC AVG 7.92 4.30 -3.61 -46 �Downward� MW-3 45.47 24.29 -35.27 -47 �Downward� MW-11 47.84 69.25 21.41 45 �Downward� MW-26 MW-26 32.41 15.94 -16.47 -51 HNo TrendH MW-27 24.32 14.20 -10.12 -41 �Downward� MW-31 1.15 4.15 3.00 260 HNo TrendH AOC AVG 30.24 25.57 -4.67 -15 . Downward MW-2 30.99 0.00 -30.99 -100 HNo TrendH MW-4R 26.73 4.33 -22.40 -84 �Downward� MW-9 19.55 13.22 -6.33 -32 �Downward� MW-14 17.81 0.00 -17.81 -100 "No TrendH Undesignated MW-15 13.38 53.93 40.55 303 HNo TrendH (No MW-17 10.55 1.30 -9.25 -87 HNo TrendH Remediation) MW-20 0.69 0.00 -0.69 -100 HNo TrendH MW-21 0.77 0.00 -0.77 -100 HNo TrendH MW-22 2.70 0.00 -2.70 -100 HNo TrendH MW-23 0.68 0.00 -0.68 -100 HNo TrendH AOC AVG 12.39 7.28 -5.11 -41 . Downward ALL WELLS ALL WELLS AVG 14.58 8.02 -8.53 -45 . Downward NS = Not sampled since dry = Statistical trend analysis of all events between June 2009 and December 2020 via Mann Kendall Trend Analysis at both a 90 % or 95 % Confidence Level. Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Tables Table 1 Groundwater Monitoring Well Construction Table December 28-31, 2020 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of Casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 9/14/90 2 40.00 25.00 15 Soil & Rock 1080.54 1077.98 1047.15 33.39 35.8389 -81.1478 MWAA 9/30/94 2 47.50 32.50 15 Soil & Rock 1085.32 1083.28 NR NR 35.8389 -81.1478 MWAB 5/21/03 2 61.00 46.00 15 Rock 1082.56 1079.56 1046.31 36.25 35.8391 -81.1478 MW-2 9/6/90 2 30.00 15.00 15 Soil 1004.48 1002.28 987.27 17.21 35.8376 -81.1524 MW-3 9/19/90 2 33.00 13.00 20 Soil & Rock 1024.73 1024.23 999.17 25.56 35.8365 -81.1503 MW-4R 9/30/94 2 20.50 5.50 15 Soil & Rock 1012.64 1008.54 999.37 13.27 35.8366 -81.1479 MW-5 9/16/94 2 48.80 33.80 15 Soil & Rock 1051.26 1049.01 1014.36 36.90 35.8373 -81.1465 MW-6 9/29/94 2 41.00 26.00 15 Rock 1010.79 1008.29 986.89 23.90 35.8369 -81.1364 MW-7 9/29/94 2 53.00 38.00 15 Rock 1009.24 1005.84 972.89 36.35 35.8364 -81.1522 MW-9 10/24/00 2 31.50 16.50 15 Rock 996.27 993.76 986.17 10.10 35.8361 -81.1481 MW-10 10/25/00 2 91.00 76.00 15 Rock 1040.80 1037.83 1005.40 35.40 35.8366 -81.1469 MW-11 10/24/00 2 56.00 41.00 15 Rock 1011.96 1008.98 974.75 37.21 35.8359 -81.1505 MW-12 10/23/00 2 66.50 51.50 15 Soil 1007.35 1004.46 958.94 48.41 35.3577 -81.1525 MW-12D 6/9/00 2 100.00 90.00 10 Rock 1008.46 1006.03 952.27 56.19 35.3577 -81.1525 MW-13 10/25/00 2 60.50 45.50 15 Rock 1004.56 1001.63 971.11 33.45 35.8368 -81.1532 MW-14 10/26/00 2 40.50 25.50 15 Soil & Rock 997.44 994.06 965.75 31.69 35.8376 -81.1525 MW-15 10/25/00 2 35.00 20.00 15 Soil & Rock 1023.44 1020.81 1001.99 21.45 35.8385 -81.1508 MW-16 12/20/07 2 40.25 25.25 15 Rock 1037.56 1034.94 1009.98 27.58 35.8371 -81.1465 MW-17 6/10/03 2 22.30 7.30 15 Rock 991.16 988.36 978.70 12.46 35.8386 -81.1511 MW-18 12/19/07 2 56.70 41.70 15 Rock 1084.33 1081.52 1039.58 44.75 35.8392 -81.1467 MW-19 12/20/07 2 63.92 48.92 15 Rock 1071.48 1068.67 1024.25 47.23 35.8391 -81.1487 MW-20 12/20/07 2 63.55 48.55 15 Rock 1046.92 1044.19 1008.78 38.14 35.8391 -81.1502 MW-21 12/19/07 2 41.05 26.05 15 Rock 990.00 987.08 960.83 29.17 35.8386 -81.1514 MW-22 12/19/07 2 18.12 8.12 10 Rock 958.97 956.21 944.86 14.11 35.8381 -81.1524 MW-23 12/19/07 2 21.54 6.54 15 Soil 950.48 947.83 935.21 15.27 35.8376 -81.1529 MW-24 12/20/07 2 35.35 20.35 15 Soil 974.04 971.29 946.31 27.73 35.8356 -81.1533 MW-25 12/19/07 2 44.48 29.48 15 Rock 981.93 979.93 958.66 23.27 35.8353 -81.1528 MW-26 12/20/07 2 49.80 34.80 15 Rock 990.69 988.08 971.30 19.39 35.8354 -81.1504 MW-27 12/20/07 2 49.82 34.82 15 Rock 992.19 989.19 976.56 15.63 35.8356 -81.1493 MW-31 8/16/10 2 32.56 17.56 15 Soil 985.42 982.42 970.15 15.27 35.8348 -81.1506 MW-32 8/16/10 2 42.70 27.7 15 Rock 1025.26 1022.26 994.11 31.15 35.8361 -81.1469 MW-33 4/27/13 2 21.38 6.38 15 PWR 1007.40 1004.40 996.19 11.21 35.8367 -81.1462 MW-34 4/27/13 2 21.19 6.19 15 PWR 1014.60 1011.60 1007.01 7.59 35.8373 -81.1459 IW-1 2/14/11 4 52.44 37.44 15 Rock 990.44 987.44 NR NR 35,8356 -81.1504 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) PWR = partially weathered rock Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 2 Field Observations of Monitoring Locations December 28-31, 2020 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked Tagged Hinge/Hasp Operational or Labeled Concrete Surface Pad Effective Comments MW-1 Yes Yes Yes Yes No Yes MW-1A No Yes Yes Yes Yes Yes Not Sampled. Dry which is typical MW-1 B Yes Yes Yes Yes Yes Yes MW-2 Yes Yes Yes Yes Yes Yes MW-3 Yes Yes Yes Yes Yes Yes MW-4R Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes Case previously repaired datum may have changed MW-6 Yes Yes Yes Yes Yes Yes MW-7 Yes Yes Yes Yes Yes Yes Black particles in purge water MW-9 Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11 Yes Yes Yes Yes Yes Yes Purge water foamy MW-12 Yes Yes Yes Yes Yes Yes MW-12D Yes Yes Yes Yes Yes Yes MW-13 Yes Yes Yes Yes Yes Yes MW-14 Yes Yes Yes Yes Yes Yes MW-15 Yes Yes Yes Yes Yes Yes MW-16 Yes Yes Yes Yes Yes Yes MW-17 Yes Yes Yes No Yes Yes Well case hinge broken off MW-18 Yes Yes Yes Yes Yes Yes MW-19 Yes Yes Yes Yes Yes Yes MW-20 Yes Yes Yes Yes Yes Yes MW-21 Yes Yes Yes Yes Yes Yes MW-22 Yes Yes Yes Yes Yes Yes Pad slightly cracked MW-23 Yes Yes Yes Yes Yes Yes MW-24 Yes Yes Yes Yes Yes Yes MW-25 Yes Yes Yes Yes Yes Yes MW-26 Yes Yes Yes Yes Yes Yes MW-27 Yes Yes Yes Yes Yes Yes MW-31 Yes Yes Yes Yes Yes Yes MW-32 Yes Yes Yes Yes Yes Yes Pad covered MW-33 Yes Yes Yes Yes Yes Yes MW-34 Yes Yes Yes Yes Yes Yes IW-1 Yes Yes Yes Yes Yes Yes Injection well. Not sampled this event. SW-3 Yes - - - - - Moderate gage height and flow rate SW-4R Yes - - - - - Moderate gage height and flow rate SW-5 Yes - - - - - Moderate gage height and flow rate SW-6 Yes - - - - - Moderate qaqe height and flow rate Any unusual field conditions, observations, or events: LFG extraction system operating in AOC MW-1 B which is typical. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 3 Field Parameter Data Summary December 28-31, 2020 Parameter Water Depth Water Elevation TOC Elevation Temp. ORP DO pH Specific Conductance Hardness mg/L Turbidity of Metal Sample NTU Units ft (btoc) ft (amsl) ft (amsl) C mV mg/L SU umhos/cm MW-1 33.39 1047.15 1080.54 16.3 NR NR 6.83 362 NR 11.4 MW-1B 36.25 1046.31 1082.56 15.8 NR NR 6.64 40 NR 2.95 MW-2 17.21 987.27 1004.48 15.9 NR NR 6.31 64 NR 3.47 MW-3 25.56 999.17 1024.73 17.2 NR NR 6.73 327 NR 8.72 MW-4R 13.27 999.37 1012.64 17.0 NR NR 7.01 450 NR 48.2 MW-5 36.90 1014.36 1051.26 14.9 -110 1.1 6.85 190 NR 8.48 MW-6 23.90 986.89 1010.79 15.0 -65 1.3 6.47 39 NR 7.9 MW-7 36.35 972.89 1009.24 15.9 NR NR 6.41 534 NR 20.7 MW-9 10.10 986.17 996.27 16.1 NR NR 7.11 569 NR 7.87 MW-10 35.40 1005.40 1040.80 14.0 NR NR 7.36 483 NR 6.35 MW-11 37.21 974.75 1011.96 16.5 -16 1.5 6.08 731 NR 21.7 MW-12 48.41 958.94 1007.35 15.2 -101 0.6 6.76 338 NR 17.2 MW-12D 56.19 952.27 1008.46 14.8 -11 0.4 7.27 817 NR 71.7 MW-13 33.45 971.11 1004.56 14.0 NR NR 6.40 104 NR 2.46 MW-14 31.69 965.75 997.44 15.2 NR NR 6.13 49 NR 12.60 MW-15 21.45 1001.99 1023.44 15.8 NR NR 5.91 72 NR 2.1 MW-16 27.58 1009.98 1037.56 14.5 -9 1.3 6.36 140 NR 0.56 MW-17 12.46 978.70 991.16 14.8 NR NR 5.89 62 NR 1.52 MW-18 44.75 1039.58 1084.33 13.5 NR NR 7.07 19 NR 2.01 MW-19 47.23 1024.25 1071.48 15.5 NR NR 6.55 219 NR 4.97 MW -20 38.14 1008.78 1046.92 14.1 NR NR 6.66 52 NR 1.39 MW-21 29.17 960.83 990.00 14.8 NR NR 6.04 40 NR 1.46 MW-22 14.11 944.86 958.97 14.8 NR NR 6.46 35 NR 4.89 MW-23 15.27 935.21 950.48 14.8 NR NR 6.18 59 NR 6.59 MW-24 27.73 946.31 974.04 14.8 -15 2.5 7.05 116 NR 40.8 MW-25 23.27 958.66 981.93 14.8 -103 2.1 6.89 53 NR 4.29 MW-26 19.39 971.30 990.69 16.5 -85 0.9 6.72 273 NR 26.2 MW-27 15.63 976.56 992.19 17.2 -210 3.6 7.47 152 NR 1.63 MW-31 15.27 970.15 985.42 15.1 -28 4.8 6.20 138 NR 1.4 MW-32 31.15 994.11 1025.256 14.6 NR NR 7.45 61 NR 2.01 MW-33 11.21 996.19 1007.40 15.0 NR NR 6.01 33 NR 0.33 MW-34 7.59 1007.01 1014.60 14.1 NR NR 7.34 45 NR 0.24 IW-1 NR NR 990.44 NR NR NR NR NR NR NR Minimum 7.59 935.21 950.48 13.5 -210 0.4 5.89 19 NR 0.24 Average 27.40 987.26 1013.92 15.3 -68 1.8 6.64 208 NR 11.1 Maximum 56.19 1047.15 1084.33 17.2 -9 4.8 7.47 817 NR 71.7 SW-3 - - - 9.5 NR NR 6.89 114 60 5.46 SW-4R - - - 9.1 NR NR 7.31 87 40 5.06 SW-5 - - - 9.3 NR NR 7.51 93 40 2.96 SW-6 - - - 9.2 NR NR 7.11 76 20 3.29 Minimum - - - 9.1 NR NR 6.89 76 20 2.96 Average - - - 9.3 NR NR 7.21 93 40 4.19 Maximum - - - 9.5 NR NR 7.51 114 60 5.46 NR = No Reading Attempted Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 4 Sampling and Analysis Summary December 28-31, 2020 App. I Other App II MNA Parameters Field Parameters 0 > o o rn p o O x0 L N U y .E c6_ +�+ w :2 O U LL C W cL6 d E C -a > M d 7 O am W Y 5 Z O O O o �' m co L 0 2 n Q U m U H U Co L Z H 2 0 U 0-1 i— O O 0 O r 0 o W O (0CD(.0N CDCDoD 0 CD�j m O O M N O � CO O O m m LWL N L :� L :� L :� L L .4). L - d 0- 0- N o CeS 0) Y W W -0 W W -0 Y U M (n to M N LO M M -0 -0 -0 -0 -0 a -0 Method m J i w � u- u- u- LL LL chi) u�i can can iL iL MW-1 x x x x x x x x x MWAA Not sampled since dry which is typical of this well MW-1 B x x x x x x x x x MW-2 x x x x x x x x MW-3 MW-4R x x x x x x x MW-5 x x x x x x x x x x MW-6 x x x x x x x x x x x MW-7 MW-9 x x x x x x x MW-10 x x x x x x x MW-11 x x x x x x x x x x x x x x x x x x MW-12 x x x x x x x x x x x x x x x x x x MW-12D x x x x x x x x x x x x x x x x x x MW-13 x x x x x x x MW-14 x x x x x x x MW-15 x x x x x x x x MW-16 x x x x x x x x x MW-17 x x x x x x x x x MW-18 x x x x x x x x x MW-19 x x x x x x x MW-20 x x x x x x x MW-21 x x x x x x x x x MW-22 x x x x x x x MW-23 x x x x x x x MW-24 x x x x x x x x x x x x x x x x x x MW-25 x x x x x x x x x x MW-26 x x x x x x x x x x x x x x x x x x MW-27 x x x x x x x x x x MW-31 x x x x x x x x x x x x x x x x x x MW-32 x x x x x x x MW-33 x x x x x x x MW-34 x x x x x x x SW-3 x x x x x x x x SW-4R x x x x x x x x SW-5 x x x x x x x x SW-6 x x x x x x x x EB x x x FB x x App I & II = Appendix I & II constituents listed in current 40 CFR 258 Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 5 Groundwater and Quality Control Sample Detections December 29-31, 2020 2L STANDARD MW-18 MW-1 MW-1B MW-2 MW-3 MW-4R MW-5 MW-6 MW-7 MW-9 MW-10 MW-11 MW-12 MW-12D MW-13 MW-14 MW-15 MW-16 MW-17 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-31 MW-32 MW-33 MW-34 EB FIB Parameter Name MDL RL IMAC VALUE MCL BG S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S QC QC Metals (Targeted 40CFR 258 Appendix I & Mercury) Antimonv, total 3 5 1 6 3.1 J Barium, total 3.5 5 700 2000 6.9 25.1 39.3 26.1 54.9 75.8 51 64.2 6.7 195 7.6 185 130 11.8 11.3 34 74.3 56.7 63 24.4 47.6 30.4 46.2 24.2 118 56.6 72.3 55 105 4.6 J 19 23.6 Cadmium, total 0.4 1 2 5 0.83 J 0.43 J 5.8 (N► 0.6 J 0.59 J 1.6 2.1 (N► 2 1.5 0.45 J 0.54 J 0.52 J 1.2 0.74 J 2.7 (NJ 1 0.74 J Chromium, total 3.7 5 10 100 11 (N) 7.4 8.1 10.5 (N) 4 J Cobalt, total 3.6 5 1 NE 5.7 (N► 42.1 (N► 243 (N) 17.5 (N► 183 (N► 10.9 (N► 200 (N) 128 (NJ 47.8 (N) 7.6 (NJ 154 194 15.6 (NJ 4.4 J 93.9 (NJ 7.6 (N) Copper, total 4.3 5 1000 1300 51 6.3 5.4 4.5 J 5.3 4.6 J 7 5.1 Mercury, total 0.12 0.2 1 2 3.5 W -- -- 0.16 J -- -- -- -- 2.2 -- 0.24 -- -- -- -- -- Nickel, total 3.5 5 100 NE 4.8 J 5.8 8.2 4.2 J 5.6 71.9 18 7.9 4.3 J 3.9 J 6.9 6.3 10.5 8.6 9 Silver, total 2.5 5 20 NE 5.3 6.2 4.1 J Thallium, total 0.05 0.1 0.28 2 0.072 J 0.19 0.073 J 0.13 0.058 J 0.12 0.084 0.12 0.061 J 0.096 J 0.057 J 0.069 J 0.052 J 0.052 J Vanadium, total 3.9 5 0.3 NE 3.9 J 5.4(Nl Zinc, total 9.5 10 1000 NE 21.1 9.9 J 11.3 12.8 14.1 1 52.4 19.2 11.9 10.9 VOCs (Targeted 40CFR 258 Appendix 1) 1,1-Dichloroethane 0.27 1 6 NE 3 0.78 J 0.38 J 0.58 J 0.94 J 0.87 J 1,2-Dichlorobenzene 0.29 1 20 NE 0.79 J 0.35 J 1,2-Dichloropropane 0.19 1 0.6 5 0.28 J 1,4-Dichlorobenzene 0.26 1 6 75 1.7 0.84 J 8 W 1.3 1.2 0.98 J 1.1 5.2 6 0.66 J 3.5 1.5 Acetone 6.2 25 6000 NE 47.9 43.4 Benzene 0.15 1 1 5 0.44 J 4.9 (L1 0.3 J 2.6 (L1 2 (L1 0.44 J 2.7 (L1 2.6 (L1 2.1 1.5 (L1 0.45 J Chlorobenzene 0.23 1 50 100 1.6 0.43 J 0.37 J 0.85 J 0.51 J 1.7 2 0.94 J 0.4 J Chloroethane 0.49 1 3000 NE 0.54 J 0.69 J 1 0.71 J cis-1,2-Dichloroethene 0.29 1 70 70 0.43 J 3.5 2.3 10.8 1.3 10.1 1.8 11.4 8.2 5.2 1.3 0.43 J 1 10 14.2 1.8 1.1 Ethylbenzene 0.26 1 600 1.3 Toluene 0.24 1 600 0.56 J 0.39 J Trichloroethene 0.22 1 3 dOO 0.56 J 0.72 JVinyl chloride 0.24 1 0.03 2.3 (L) Xylene (Total) 0.63 1 500 3.1 MNA Performance Parameters Alkalinity 5000 5000 NE NE -- 293000 94700 439000 27800 189000 43100 Chloride 500 1000 250000 NE -- -- -- -- -- -- -- -- -- -- -- 92500 36700 75800 -- -- -- -- -- -- -- -- -- -- 16800 -- 34600 22300 COD 125000 250000 NE NE 86500 18900 J 18900 J 30200 32400 <12500 Iron, ferrous 84 500 NE NE -- -- -- -- -- -- -- -- -- -- -- 59700 14600 950 -- -- -- -- -- -- -- -- -- -- -- 27600 -- -- -- -- -- -- Methane 3.4 10 NE NE 946 8.1 J -- -- -- 6320 -- 11900 7600 2970 -- -- -- 823 180 -- -- 3.8 J -- -- 5.2 J 2430 226 Turbidity 0.16 1 NE NE 2.01 11.4 2.95 3.47 8.72 48.2 8.48 7.9 20.7 7.87 6.35 21.7 17.2 71.7 2.46 12.6 2.1 0.56 1.52 4.97 1.39 1.46 4.89 6.59 40.8 4.29 26.2 1.63 1.4 2.01 0.33 J 0.24 J Nitrate as N 10 40 NE NE -- -- -- -- -- -- -- -- -- -- -- 57.9 24.4 J 18.2 J -- -- -- -- -- -- -- -- -- -- 337 -- <10 626 Sulfate 500 1000 250000 NE -- -- -- -- -- -- -- -- -- -- -- 2070 3810 744 J -- -- -- -- -- -- -- -- -- -- 2870 4330 836 J Sulfide 50 100 NE NE 91.3 J <50 <50 <250 <50 95.8 J TOC 500 1000 NE I NE I I I I I I 1 1 11200 1 3080 1 3290738 J 1 1 2740 1 1 17 Notes: Units ug/L unless shown otherwise, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established. Bold Above RL and Established 21JIMAC/ recognized by NC SWS as regulatory groundwater Standard Highlighted Above Established MCL Drinking Water Std. (No regulatory significance) BG = Background Well Sample, S = Seminal Well Sample MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit defined by Pace laboratory as 'The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 IMAC = Interim Maximum Allowable Concentration MCL = Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism. A definitive source of the detections was not determined as part of this report. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 6 Surface Water Sample Detections December 30-31, 2020 Parameter Name MDL NC 2B STD' EPA NRWQCZ NC ISTV3 a MCL SW-3 SW-4R SW-5 SW-6 Downstream Downstream Downstream Downstream Targeted 40CFR 258 Appendix I & 1,4-Dioxane Barium, total 3.5 NE NE 21,000 2000 36.8 34.4 23.8 18 Cobalt, total 3.6 NE NE 4 NE 14.4 cis-1,2-Dichloroethene 0.29 NE NE 720 1300 0.59 J Hardness as CaCo3 (Field Measured) Hardness m /L 20 NE NE NE I NE 1 60 40 40 40 Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". Red Bold Above 2B Std. Above Established Federal MCL Primary Drinking Water Std. Receiving surface water is Catawba River (11-(67)) Class WS-IV 03040102 (8-Digit HUC). NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes. 2 EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health. Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses s NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DWR staff for further information. NC PV for barium fresh water All waters (Class C),All waters Fresh & Salt (Class C & SC) ° MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 7 Hydrogeologic Proporties at Monitoring Well Locations December 28-31, 2020 Monitoring Well Hydraulic Conductivity cm/sec ( ) Effective Porosity (% ) Hydraulic Gradient ft/ft ( ) Average Linear Velocity Rate ft/ r ( y) Flow Direction Depth to Groundwater ft BTOC ( ) Groundwater Pot levati on etric Elevation (ft amsl) Screened Interval Lithology MW-2 3.70E-06 28 0.63 9 S54E 17.21 987.27 UC MW-12 n/a 28 0.04 n/a N80W 48.41 958.94 UC MW-16 8.72E-04 17 0.06 312 S28E 27.58 1009.98 UC MW-17 n/a 17 0.25 n/a S45E 12.46 978.70 UC MW-21 3.77E-03 28 0.29 3980 S31 E 29.17 960.83 UC MW-22 6.04E-04 28 0.18 399 S57E 14.11 944.86 UC MW-23 9.83E-04 28 0.22 793 S33E 15.27 935.21 UC MW-24 1.33E-02 28 0.09 4636 N74W 27.73 946.31 UC MW-31 n/a 28 0.09 n/a S85W 15.27 970.15 UC MW-33 n/a 28 0.06 n/a S32E 11.21 996.19 UC MW-34 n/a 28 0.02 n/a S50E 7.59 1007.01 UC Minimum 3.70E-06 17 0.02 9 7.59 935.21 - Average 3.26E-03 26 0.17 1688 20.55 972.31 - Maximum 1.33E-02 28 0.63 4636 - 48.41 1009.98 - MW-1 5.60E-05 10 0.13 75 N36W 33.39 1047.15 UC/UBR MW-3 3.90E-06 10 0.16 7 S18W 25.56 999.17 UC/UBR MW-4R 4.90E-04 10 0.09 441 S21 W 13.27 999.37 UC/UBR MW-5 6.40E-05 28 0.06 15 S35E 36.90 1014.36 UC/UBR MW-14 n/a 10 0.45 n/a S44E 31.69 965.75 UC/UBR MW-15 n/a 10 0.03 n/a S46E 21.45 1001.99 UC/UBR Minimum 3.90E-06 10 0.03 7 13.27 965.75 - Average 1.53E-04 13 0.16 134 27.04 1004.63 - Maximum 4.90E-04 28 0.45 441 36.90 1047.15 - MW-1 B n/a 10 0.08 n/a N38W 36.25 1046.31 UBR MW-6 2.40E-05 10 0.12 29 N84W 26.27 986.89 UBR MW-7 1.60E-06 10 0.18 3 S13W 36.35 972.89 UBR MW-9 n/a 10 0.07 n/a S49E 10.10 986.17 UBR MW-11 n/a 10 0.10 n/a S35W 37.21 974.75 UBR MW-13 n/a 10 0.22 n/a S84W 33.45 971.11 UBR MW-19 1.92E-06 10 0.09 2 S55E 47.23 1024.25 UBR MW-20 5.49E-05 10 0.06 37 S47W 38.14 1008.78 UBR MW-25 5.41 E-05 10 0.04 22 S69W 23.27 958.66 UBR MW-26 1.16E-04 10 0.11 131 S72W 19.39 971.30 UBR MW-27 2.83E-05 10 0.07 21 S08W 15.63 976.56 UBR MW-32 n/a 10 0.07 n/a S09E 31.15 994.11 UBR Minimum 1.60E-06 10 0.04 2 10.10 958.66 - Average 4.01 E-05 10 0.10 35 29.54 989.31 - Maximum 1.16E-04 10 0.22 131 47.23 1046.31 - MW-10 n/a 10 0.05 n/a S13E 35.40 1005.40 LBR MW-12D n/a 10 n/a n/a n/a 56.19 952.27 LBR MW-18 1.19E-04 10 0.09 n/a N04W 44.75 1039.58 LBR Minimum 1.19E-04 10 0.05 - 35.40 952.27 - Average 1.19E-04 10 0.07 - 45.45 999.08 - Maximum 1.19E-04 10 0.09 56.19 1039.58 - NOTE: Values for hydraulic conductivity obtained from GAI Consultants Sampling Report (April, 1995) & MESCO ACM Report (2008). Average Linear Groundwater Velocities calculated only for UC & UBR wells with hydraulic conductivity values. UC = Unconfined/saprolite; UBR = Upper Bedrock fracture system; LBR = Lower Bedrock fracture system. Wells screened in LBR not utilized for flow directions/gradients. Hydrologic Gradient calculated from potentiometrc elevations recorded on December 28-30, 2020. Flow rate (Q) calculated via modified Darcy's equation: K= hydraulic conductivity ny K A n e = effective porosity �g dh= head difference d1= horizontal distance Alexander County Active C&D and Closed MSWLF Page 1 of 1 Appendix A Field Sampling Parameter Data Sheet(s) :� M Iclpal /J u����'- Nn6lnecAinF Sa.mpli►ng Data Sheet "" "'" � ��" r cn nc ...,.-- ..:. n �..rc Project: Alexander Co Closed MSWLF &Active C&� LF Samplers: Page__1_of 2 E. Lambert Sampling Parameters Water Quality Parameters Depth to Depth to CH4 Monitoring Purge Purge Water Sample Sample STOP Volume Goes S ecific Point Date Time (BTOP) Date Time Sample purged STm eie DuDr ng Comments Depth (m92) (m9�) ORP pH TeO p' Cond. (m9S) ? Vapors (us/cm � m Pre -Purge Time (Gal) Yp purge Expected (pp ) MW-1 i �,r , � � � `� � � , � � � 40 - .. � � y� .. � ` .a .�_a,.a�. .�_ 48.5 � , MW-1A MW-1B �� �� -� _ - � �. 61 �{ MW-2 '� �� �� � r �'`� � , 30 � a � � MW-3 � _ � g� 33 � � MW-4R ���� ���� �� s ��'� ", 21.5 � � r MW-5 I � � � 42 �'' - ��``� �; � � � �, - ,��: MW-6 '� 1 � ' i �, i �,I � 54 � �` �"� MW-7 � .��� i , � � �� MW-9 Q ' :� � �in� � '. a �'' tir"'�� 31.5 � ( � �� � � e.- 91 �� ��� ,� MW-10 i � z F �� `� `� ,� MW-11 � ���=��i �=� -� � '1 56 i ,— 1� �� 66.5 %. W-12 � �'� � � M �`�' 102,5 � � i r MW-12D MW-13 -= I r� � _ 60.5 ' 40.5 xti �� ?,,. y'1 MW-14 J u i MW-16 d �,�"� � r � � ,�' 40.25 "' _ �' `% — 22.3 MW-17 r � � _�. � , 9 '� � - 56.7 � ,� MW-18 � � � ":�, � � v, �' �: - �w 63.92 3` � ��� 1 � f; MW-19 '`� � �= Comments � " s €� "a '� ��'� c � ,. � -�.< �_ SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low how Pump, PO=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained �:% _.. _. S�.�p(inc� Data Sheet InI MunlclpPl /11L W.81nw+ine x....e.. �� ..rmn... .�/�w�,an�w.�eu+. 'of_2 Project:Alexander Co Closed MSWLF &Active C&D LF Samplers: Page_2 E. Lambert Sampling Parameters Water Quality Parameters Depth to Depth to Monitoring Purge Purge Water Sample S<�mple Water Goes Point Date Time (BTOP) Date Time (BTOP) Volume Sample Dry Total CO2 DO S ecific P Hard- �' CH4 Sample Pur ed 9 Comments Depth ORP pH Temp. Cond. Hess :o Gas Pre -Purge (Gal) T e YP During Expected (mg/I) (mg/L,) © � Vapors `,�.r Time Purge (us/cm (mg/L) � MW-20 - � � h, �. r �� � � ��.:� 63.55 `� j � _ j MW-21 � , x , .� � � 41.05 — , MW-22 '� �+' , � `�,' 18.12 �v, --� _ MW-23 ���' 4 � � � as � > u � ��' '� ?_1.54 _ MW-24 ���,.� � �� , � .:,"d m�'_ ��R '� =�. ,n '� � 35.35 �� _ �� MW-25 ) �' � �� � � � e � MW-26 J ) � '� = � a MW-27 9� �;'~� ��� � �° _ .�. � i,, � , �, 49.82 �� � ,� , _ �? `'' ���. � � � MW-31 � R� r� `�: ;� , k. ''� � ski 32.56 � �� _ -� _ �� MW-33 �� ,' `�� � �',� v � � �` �" �y,�` 21.38 f.�.-�. ,��. _ _ �' �: MW-34 �. f , �� � , ��� 21.19 _ �„�� SW-4R - � - - � _ - - - ��� ��� .t�� � $� �ti - SW-5 - _ - - SW-6 - - � .� - _ _ - EB `% i� - - - _ _ FB - - - � ;` `�� - - - - - - - - - - - - - - Comments SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Appendix B Laboratory Analysis Reports Chains of Custody lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 January 12, 2021 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory between December 30, 2020 and December 31, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, a*a- `uru Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Lab ID Sample ID Matrix Date Collected Date Received 92514193001 MW-11 Water 12/29/20 15:39 12/30/20 09:20 92514193002 MW-12D Water 12/29/20 15:57 12/30/20 09:20 92514193003 MW-24 Water 12/29/20 16:06 12/30/20 09:20 92514193004 MW-26 Water 12/29/20 14:55 12/30/20 09:20 92514193005 MW-31 Water 12/29/20 14:58 12/30/20 09:20 92514193006 MW-12 Water 12/29/20 15:50 12/30/20 09:20 92514193007 MW-16 Water 12/29/20 13:27 12/30/20 09:20 92514193008 MW-33 Water 12/29/20 13:16 12/30/20 09:20 92514193009 MW-34 Water 12/29/20 13:08 12/30/20 09:20 92514193010 MW-10 Water 12/30/2013:52 12/31/20 13:11 92514193011 MW-13 Water 12/30/20 09:05 12/31/20 13:11 92514193012 MW-14 Water 12/30/20 09:15 12/31/20 13:11 92514193013 MW-19 Water 12/30/2015:38 12/31/20 13:11 92514193014 MW-20 Water 12/31/20 09:10 12/31/20 13:11 92514193015 MW-22 Water 12/31/20 08:40 12/31/20 13:11 92514193016 MW-23 Water 12/31/20 08:17 12/31/20 13:11 92514193017 MW-32 Water 12/30/2013:48 12/31/20 13:11 92514193018 SW-3 Water 12/30/2014:30 12/31/20 13:11 92514193019 SW-4R Water 12/31/20 08:28 12/31/20 13:11 92514193020 SW-5 Water 12/30/2012:02 12/31/20 13:11 92514193021 SW-6 Water 12/30/2013:38 12/31/20 13:11 92514193022 MW-4R Water 12/30/2014:14 12/31/20 13:11 92514193023 MW-7 Water 12/31/20 09:18 12/31/20 13:11 92514193024 MW-9 Water 12/30/2014:20 12/31/20 13:11 92514193025 MW-3 Water 12/31/20 09:25 12/31/20 13:11 92514193026 EB Water 12/31/20 09:43 12/31/20 13:11 92514193027 FB Water 12/31/20 09:46 12/31/20 13:11 92514193028 MW-6 Water 12/30/20 09:09 12/31/20 13:11 92514193029 MW-17 Water 12/31/20 08:59 12/31/20 13:11 92514193030 MW-18 Water 12/30/2015:45 12/31/20 13:11 92514193031 MW-21 Water 12/31/20 08:46 12/31/20 13:11 92514193032 MW-1 Water 12/31/20 09:32 12/31/20 13:11 92514193033 MW-1B Water 12/30/2015:33 12/31/20 13:11 92514193034 MW-2 Water 12/30/20 09:28 12/31/20 13:11 92514193035 MW-15 Water 12/31/20 09:08 12/31/20 13:11 92514193036 MW-25 Water 12/30/20 08:55 12/31/20 13:11 92514193037 MW-27 Water 12/30/2014:47 12/31/20 13:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Lab ID Sample ID Matrix Date Collected Date Received 92514193038 MW-5 Water 12/30/2013:31 12/31/2013:11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: ALEXANDER LF-SWS 92514193 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92514193001 MW-11 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 RED 1 PASI-A SM 4500-S2D-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 CJL 1 PASI-A SM 5220D-2011 JP1 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92514193002 MW-12D RSK 175 Modified MAD 1 PASI-C EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 RED 1 PASI-A SM 4500-S2D-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 CJL 1 PASI-A SM 5220D-2011 JP1 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92514193003 MW-24 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 RED 1 PASI-A SM 4500-S2D-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 CJL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 5220D-2011 JP1 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92514193004 MW-26 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 RED 1 PASI-A SM 4500-S2D-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 CJL 1 PASI-A SM 5220D-2011 JP1 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92514193005 MW-31 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 RED 1 PASI-A SM 4500-S2D-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 CJL 1 PASI-A SM 5220D-2011 JP1 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92514193006 MW-12 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 RED 1 PASI-A SM 4500-S2D-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 CJL 1 PASI-A SM 5220D-2011 JP1 1 PASI-A SM 531OB-2011 JLH 1 PASI-A 92514193007 MW-16 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A 92514193008 MW-33 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A 92514193009 MW-34 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C SM 213OB-2011 NFW 1 PASI-A 92514193010 MW-10 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193011 MW-13 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193012 MW-14 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193013 MW-19 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193014 MW-20 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193015 MW-22 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193016 MW-23 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D CL 51 PASI-C 92514193017 MW-32 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193018 SW-3 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193019 SW-4R EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193020 SW-5 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193021 SW-6 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193022 MW-4R EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92514193023 MW-7 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193024 MW-9 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193025 MW-3 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193026 EB EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193027 FB EPA 8260D PM1 51 PASI-C 92514193028 MW-6 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: ALEXANDER LF-SWS 92514193 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92514193029 MW-17 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92514193030 MW-18 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92514193031 MW-21 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92514193032 MW-1 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193033 MW-1B RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92514193034 MW-2 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92514193035 MW-15 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D PM1 51 PASI-C 92514193036 MW-25 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D PM1 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92514193037 MW-27 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C 92514193038 MW-5 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA8260D PM1 51 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-11 Lab ID: 92514193001 Collected: 12/29/20 15:39 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 11900 ug/L 10.0 3.4 1 12/30/2016:44 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2102:30 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2102:30 7440-38-2 Barium 185 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2102:30 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2102:30 7440-41-7 Cadmium 1.6 ug/L 1.0 0.40 1 01/08/2101:37 01/11/2102:30 7440-43-9 Chromium 8.1 ug/L 5.0 3.7 1 01/08/2101:37 01/11/2102:30 7440-47-3 Cobalt 128 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2102:30 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2102:30 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2102:30 7439-92-1 Nickel 18.0 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 02:30 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2102:30 7782-49-2 Silver 6.2 ug/L 5.0 2.5 1 01/08/2101:37 01/11/2102:30 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2102:30 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2102:30 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.058J ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:33 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 47.9 ug/L 25.0 ND ug/L 10.0 2.7 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 1.7 ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.35J ug/L 1.0 5.2 ug/L 1.0 6.2 1 12/31/20 00:15 67-64-1 0.90 1 12/31/20 00:15 107-13-1 0.15 1 12/31/20 00:15 71-43-2 0.34 1 12/31/20 00:15 74-97-5 0.26 1 12/31/20 00:15 75-27-4 0.62 1 12/31/20 00:15 75-25-2 0.62 1 12/31/20 00:15 74-83-9 3.3 1 12/31/20 00:15 78-93-3 0.40 1 12/31/20 00:15 75-15-0 0.22 1 12/31/20 00:15 56-23-5 0.23 1 12/31/20 00:15 108-90-7 0.49 1 12/31/20 00:15 75-00-3 2.3 1 12/31/20 00:15 67-66-3 0.39 1 12/31/20 00:15 74-87-3 0.26 1 12/31/20 00:15 96-12-8 0.41 1 12/31/20 00:15 124-48-1 0.26 1 12/31/20 00:15 106-93-4 0.46 1 12/31/20 00:15 74-95-3 0.29 1 12/31/20 00:15 95-50-1 0.26 1 12/31/20 00:15 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-11 Lab ID: 92514193001 Collected: 12/29/20 15:39 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/31/20 00:15 110-57-6 ND ug/L 1.0 0.27 1 12/31/20 00:15 75-34-3 ND ug/L 1.0 0.34 1 12/31/20 00:15 107-06-2 ND ug/L 1.0 0.24 1 12/31/20 00:15 75-35-4 11.4 ug/L 1.0 0.29 1 12/31/20 00:15 156-59-2 ND ug/L 1.0 0.25 1 12/31/20 00:15 156-60-5 ND ug/L 1.0 0.19 1 12/31/20 00:15 78-87-5 ND ug/L 1.0 0.30 1 12/31/20 00:15 10061-01-5 ND ug/L 1.0 0.31 1 12/31/20 00:15 10061-02-6 ND ug/L 150 56.2 1 12/31/20 00:15 123-91-1 ND ug/L 1.0 0.26 1 12/31/20 00:15 100-41-4 ND ug/L 5.0 0.57 1 12/31/20 00:15 591-78-6 ND ug/L 20.0 12.5 1 12/31/20 00:15 74-88-4 v2 ND ug/L 5.0 3.7 1 12/31/20 00:15 75-09-2 ND ug/L 5.0 4.5 1 12/31/20 00:15 108-10-1 ND ug/L 1.0 0.27 1 12/31/20 00:15 100-42-5 ND ug/L 1.0 0.34 1 12/31/20 00:15 630-20-6 ND ug/L 1.0 0.22 1 12/31/20 00:15 79-34-5 ND ug/L 1.0 0.16 1 12/31/20 00:15 127-18-4 ND ug/L 1.0 0.24 1 12/31/20 00:15 108-88-3 ND ug/L 1.0 0.18 1 12/31/20 00:15 71-55-6 ND ug/L 1.0 0.24 1 12/31/20 00:15 79-00-5 ND ug/L 1.0 0.22 1 12/31/20 00:15 79-01-6 ND ug/L 1.0 0.31 1 12/31/20 00:15 75-69-4 ND ug/L 1.0 0.35 1 12/31/20 00:15 96-18-4 ND ug/L 2.0 1.4 1 12/31/20 00:15 108-05-4 N D ug/L 1.0 0.24 1 12/31/20 00:15 75-01-4 ND ug/L 1.0 0.63 1 12/31/20 00:15 1330-20-7 99 % 70-130 1 12/31/20 00:15 460-00-4 108 % 70-130 1 12/31/20 00:15 17060-07-0 104 % 70-130 1 12/31/20 00:15 2037-26-5 Analytical Method: SM 213OB-2011 Pace Analytical Services -Asheville 21.7 NTU 1.0 0.16 1 12/31/20 06:12 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 293000 ug/L 5000 5000 1 01/04/21 22:00 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 59.7 mg/L 12.5 2.1 25 01/04/2120:05 H3,N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-11 Lab ID: 92514193001 Collected: 12/29/20 15:39 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 4500 Chloride Chloride 5220D COD Chemical Oxygen Demand 531013 TOC Total Organic Carbon Date: 01/12/2021 11:33 AM 91.3J ug/L 100 50.0 1 01/05/2112:47 18496-25-8 M1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 2070 ug/L 1000 500 1 01/01/2100:26 14808-79-8 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 57.9 ug/L 40.0 10.0 1 12/31 /20 00:38 14797-55-8 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville 92500 ug/L 5000 2500 5 01/07/2120:03 16887-00-6 Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville 86500 ug/L 25000 12500 1 01/07/2102:35 01/07/2107:24 Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville 11200 ug/L 1000 500 1 01/04/21 14:52 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1,R1 Page 13 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-12D Lab ID: 92514193002 Collected: 12/29/20 15:57 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 2970 ug/L 10.0 3.4 1 12/30/2016:59 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/10/2117:59 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/10/2117:59 7440-38-2 Barium 11.8 ug/L 5.0 3.5 1 01/08/2101:37 01/10/2117:59 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/10/2117:59 7440-41-7 Cadmium 2.0 ug/L 1.0 0.40 1 01/08/2101:37 01/10/2117:59 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/10/2117:59 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/10/2117:59 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/10/2117:59 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/10/2117:59 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/10/2117:59 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/10/2117:59 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/10/2117:59 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/10/2117:59 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/10/2117:59 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 01/07/2101:35 01/07/2123:50 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 12/31/20 00:33 67-64-1 0.90 1 12/31/20 00:33 107-13-1 0.15 1 12/31/20 00:33 71-43-2 0.34 1 12/31/20 00:33 74-97-5 0.26 1 12/31/20 00:33 75-27-4 0.62 1 12/31/20 00:33 75-25-2 0.62 1 12/31/20 00:33 74-83-9 3.3 1 12/31/20 00:33 78-93-3 0.40 1 12/31/20 00:33 75-15-0 0.22 1 12/31/20 00:33 56-23-5 0.23 1 12/31/20 00:33 108-90-7 0.49 1 12/31/20 00:33 75-00-3 2.3 1 12/31/20 00:33 67-66-3 0.39 1 12/31/20 00:33 74-87-3 0.26 1 12/31/20 00:33 96-12-8 0.41 1 12/31/20 00:33 124-48-1 0.26 1 12/31/20 00:33 106-93-4 0.46 1 12/31/20 00:33 74-95-3 0.29 1 12/31/20 00:33 95-50-1 0.26 1 12/31/20 00:33 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-12D Lab ID: 92514193002 Collected: 12/29/20 15:57 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/31/20 00:33 110-57-6 ND ug/L 1.0 0.27 1 12/31/20 00:33 75-34-3 ND ug/L 1.0 0.34 1 12/31/20 00:33 107-06-2 ND ug/L 1.0 0.24 1 12/31/20 00:33 75-35-4 ND ug/L 1.0 0.29 1 12/31/20 00:33 156-59-2 ND ug/L 1.0 0.25 1 12/31/20 00:33 156-60-5 ND ug/L 1.0 0.19 1 12/31/20 00:33 78-87-5 ND ug/L 1.0 0.30 1 12/31/20 00:33 10061-01-5 ND ug/L 1.0 0.31 1 12/31/20 00:33 10061-02-6 ND ug/L 150 56.2 1 12/31/20 00:33 123-91-1 ND ug/L 1.0 0.26 1 12/31/20 00:33 100-41-4 ND ug/L 5.0 0.57 1 12/31/20 00:33 591-78-6 ND ug/L 20.0 12.5 1 12/31/20 00:33 74-88-4 v2 ND ug/L 5.0 3.7 1 12/31/20 00:33 75-09-2 ND ug/L 5.0 4.5 1 12/31/20 00:33 108-10-1 ND ug/L 1.0 0.27 1 12/31/20 00:33 100-42-5 ND ug/L 1.0 0.34 1 12/31/20 00:33 630-20-6 ND ug/L 1.0 0.22 1 12/31/20 00:33 79-34-5 ND ug/L 1.0 0.16 1 12/31/20 00:33 127-18-4 ND ug/L 1.0 0.24 1 12/31/20 00:33 108-88-3 ND ug/L 1.0 0.18 1 12/31/20 00:33 71-55-6 ND ug/L 1.0 0.24 1 12/31/20 00:33 79-00-5 ND ug/L 1.0 0.22 1 12/31/20 00:33 79-01-6 ND ug/L 1.0 0.31 1 12/31/20 00:33 75-69-4 ND ug/L 1.0 0.35 1 12/31/20 00:33 96-18-4 ND ug/L 2.0 1.4 1 12/31/20 00:33 108-05-4 N D ug/L 1.0 0.24 1 12/31/20 00:33 75-01-4 ND ug/L 1.0 0.63 1 12/31/20 00:33 1330-20-7 98 % 70-130 1 12/31/20 00:33 460-00-4 110 % 70-130 1 12/31/20 00:33 17060-07-0 102 % 70-130 1 12/31/20 00:33 2037-26-5 Analytical Method: SM 213OB-2011 Pace Analytical Services -Asheville 71.7 NTU 1.0 0.16 1 12/31/20 06:16 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 439000 ug/L 5000 5000 1 01/04/21 22:10 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 0.95 mg/L 0.50 0.084 1 01/04/2119:05 H3,N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-12D Lab ID: 92514193002 Collected: 12/29/20 15:57 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 50.0 1 01/05/2112:49 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 744J ug/L 1000 500 1 01/01/21 00:41 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 18.2J ug/L 40.0 10.0 1 12/31/20 00:45 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 75800 ug/L 2000 1000 2 01/07/2119:56 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 18900J ug/L 25000 12500 1 01/07/21 02:35 01/07/21 07:38 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 3290 ug/L 1000 500 1 01/04/21 16:19 7440-44-0 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-24 Lab ID: 92514193003 Collected: 12/29/20 16:06 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 5.2J ug/L 10.0 3.4 1 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM 12/30/2017:14 74-82-8 C8 ND ug/L 5.0 3.0 1 01/08/21 01:37 01/11/21 02:33 7440-36-0 ND ug/L 10.0 4.7 1 01/08/21 01:37 01/11/21 02:33 7440-38-2 118 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 02:33 7440-39-3 ND ug/L 1.0 0.70 1 01/08/21 01:37 01/11/21 02:33 7440-41-7 0.52J ug/L 1.0 0.40 1 01/08/21 01:37 01/11/21 02:33 7440-43-9 10.5 ug/L 5.0 3.7 1 01/08/21 01:37 01/11/21 02:33 7440-47-3 4.4J ug/L 5.0 3.6 1 01/08/21 01:37 01/11/21 02:33 7440-48-4 4.6J ug/L 5.0 4.3 1 01/08/21 01:37 01/11/21 02:33 7440-50-8 ND ug/L 5.0 4.5 1 01/08/21 01:37 01/11/21 02:33 7439-92-1 6.3 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 02:33 7440-02-0 ND ug/L 10.0 4.7 1 01/08/21 01:37 01/11/21 02:33 7782-49-2 ND ug/L 5.0 2.5 1 01/08/21 01:37 01/11/21 02:33 7440-22-4 5.4 ug/L 5.0 3.9 1 01/08/21 01:37 01/11/21 02:33 7440-62-2 19.2 ug/L 10.0 9.5 1 01/08/21 01:37 01/11/21 02:33 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.096J ug/L 0.10 0.050 1 01/07/2101:35 01/07/2123:54 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 12/30/20 21:33 67-64-1 0.90 1 12/30/20 21:33 107-13-1 0.15 1 12/30/20 21:33 71-43-2 0.34 1 12/30/20 21:33 74-97-5 0.26 1 12/30/20 21:33 75-27-4 0.62 1 12/30/20 21:33 75-25-2 0.62 1 12/30/20 21:33 74-83-9 3.3 1 12/30/20 21:33 78-93-3 0.40 1 12/30/20 21:33 75-15-0 0.22 1 12/30/20 21:33 56-23-5 0.23 1 12/30/20 21:33 108-90-7 0.49 1 12/30/20 21:33 75-00-3 2.3 1 12/30/20 21:33 67-66-3 0.39 1 12/30/20 21:33 74-87-3 0.26 1 12/30/20 21:33 96-12-8 0.41 1 12/30/20 21:33 124-48-1 0.26 1 12/30/20 21:33 106-93-4 0.46 1 12/30/20 21:33 74-95-3 0.29 1 12/30/20 21:33 95-50-1 0.26 1 12/30/20 21:33 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v3 Page 17 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-24 Lab ID: 92514193003 Collected: 12/29/20 16:06 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/30/20 21:33 110-57-6 ND ug/L 1.0 0.27 1 12/30/20 21:33 75-34-3 ND ug/L 1.0 0.34 1 12/30/20 21:33 107-06-2 ND ug/L 1.0 0.24 1 12/30/20 21:33 75-35-4 0.43.1 ug/L 1.0 0.29 1 12/30/20 21:33 156-59-2 ND ug/L 1.0 0.25 1 12/30/20 21:33 156-60-5 ND ug/L 1.0 0.19 1 12/30/20 21:33 78-87-5 N D ug/L 1.0 0.30 1 12/30/20 21:33 10061-01-5 ND ug/L 1.0 0.31 1 12/30/20 21:33 10061-02-6 ND ug/L 150 56.2 1 12/30/20 21:33 123-91-1 ND ug/L 1.0 0.26 1 12/30/20 21:33 100-41-4 ND ug/L 5.0 0.57 1 12/30/20 21:33 591-78-6 ND ug/L 20.0 12.5 1 12/30/20 21:33 74-88-4 v2 ND ug/L 5.0 3.7 1 12/30/20 21:33 75-09-2 ND ug/L 5.0 4.5 1 12/30/20 21:33 108-10-1 ND ug/L 1.0 0.27 1 12/30/20 21:33 100-42-5 ND ug/L 1.0 0.34 1 12/30/20 21:33 630-20-6 ND ug/L 1.0 0.22 1 12/30/20 21:33 79-34-5 ND ug/L 1.0 0.16 1 12/30/20 21:33 127-18-4 ND ug/L 1.0 0.24 1 12/30/20 21:33 108-88-3 ND ug/L 1.0 0.18 1 12/30/20 21:33 71-55-6 ND ug/L 1.0 0.24 1 12/30/20 21:33 79-00-5 ND ug/L 1.0 0.22 1 12/30/20 21:33 79-01-6 ND ug/L 1.0 0.31 1 12/30/20 21:33 75-69-4 ND ug/L 1.0 0.35 1 12/30/20 21:33 96-18-4 ND ug/L 2.0 1.4 1 12/30/20 21:33 108-05-4 ND ug/L 1.0 0.24 1 12/30/20 21:33 75-01-4 v3 ND ug/L 1.0 0.63 1 12/30/20 21:33 1330-20-7 101 % 70-130 1 12/30/20 21:33 460-00-4 107 % 70-130 1 12/30/20 21:33 17060-07-0 103 % 70-130 1 12/30/20 21:33 2037-26-5 Analytical Method: SM 213OB-2011 Pace Analytical Services -Asheville 40.8 NTU 1.0 0.16 1 12/31/20 06:18 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 27800 ug/L 5000 5000 1 01/04/21 22:20 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 01/04/2119:05 H3,N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-24 Lab ID: 92514193003 Collected: 12/29/20 16:06 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 4500 Chloride Chloride 5220D COD Chemical Oxygen Demand 531013 TOC Total Organic Carbon Date: 01/12/2021 11:33 AM ND ug/L 500 250 5 01/05/2113:15 18496-25-8 D3 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 2870 ug/L 1000 500 1 01/01/21 00:56 14808-79-8 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 337 ug/L 40.0 10.0 1 12/31 /20 00:47 14797-55-8 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville 16800 ug/L 1000 500 1 01/07/2119:56 16887-00-6 Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville 30200 ug/L 25000 12500 1 01/07/2102:35 01/07/2107:42 Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville 738J ug/L 1000 500 1 01/04/21 16:39 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-26 Lab ID: 92514193004 Collected: 12/29/20 14:55 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 2430 ug/L 10.0 3.4 1 12/30/2017:30 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2102:46 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2102:46 7440-38-2 Barium 72.3 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2102:46 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2102:46 7440-41-7 Cadmium 1.2 ug/L 1.0 0.40 1 01/08/2101:37 01/11/2102:46 7440-43-9 Chromium 4.OJ ug/L 5.0 3.7 1 01/08/2101:37 01/11/2102:46 7440-47-3 Cobalt 93.9 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2102:46 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2102:46 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2102:46 7439-92-1 Nickel 10.5 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2102:46 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2102:46 7782-49-2 Silver 4.1J ug/L 5.0 2.5 1 01/08/2101:37 01/11/2102:46 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2102:46 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2102:46 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.069J ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:09 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 1.5 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 0.94J ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 3.5 ug/L 1.0 6.2 1 12/30/20 23:39 67-64-1 0.90 1 12/30/20 23:39 107-13-1 0.15 1 12/30/20 23:39 71-43-2 0.34 1 12/30/20 23:39 74-97-5 0.26 1 12/30/20 23:39 75-27-4 0.62 1 12/30/20 23:39 75-25-2 0.62 1 12/30/20 23:39 74-83-9 3.3 1 12/30/20 23:39 78-93-3 0.40 1 12/30/20 23:39 75-15-0 0.22 1 12/30/20 23:39 56-23-5 0.23 1 12/30/20 23:39 108-90-7 0.49 1 12/30/20 23:39 75-00-3 2.3 1 12/30/20 23:39 67-66-3 0.39 1 12/30/20 23:39 74-87-3 0.26 1 12/30/20 23:39 96-12-8 0.41 1 12/30/20 23:39 124-48-1 0.26 1 12/30/20 23:39 106-93-4 0.46 1 12/30/20 23:39 74-95-3 0.29 1 12/30/20 23:39 95-50-1 0.26 1 12/30/20 23:39 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-26 Lab ID: 92514193004 Collected: 12/29/20 14:55 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/30/20 23:39 110-57-6 ND ug/L 1.0 0.27 1 12/30/20 23:39 75-34-3 ND ug/L 1.0 0.34 1 12/30/20 23:39 107-06-2 ND ug/L 1.0 0.24 1 12/30/20 23:39 75-35-4 10 ug/L 1.0 0.29 1 12/30/20 23:39 156-59-2 ND ug/L 1.0 0.25 1 12/30/20 23:39 156-60-5 ND ug/L 1.0 0.19 1 12/30/20 23:39 78-87-5 ND ug/L 1.0 0.30 1 12/30/20 23:39 10061-01-5 ND ug/L 1.0 0.31 1 12/30/20 23:39 10061-02-6 ND ug/L 150 56.2 1 12/30/20 23:39 123-91-1 ND ug/L 1.0 0.26 1 12/30/20 23:39 100-41-4 ND ug/L 5.0 0.57 1 12/30/20 23:39 591-78-6 ND ug/L 20.0 12.5 1 12/30/20 23:39 74-88-4 v2 ND ug/L 5.0 3.7 1 12/30/20 23:39 75-09-2 ND ug/L 5.0 4.5 1 12/30/20 23:39 108-10-1 ND ug/L 1.0 0.27 1 12/30/20 23:39 100-42-5 ND ug/L 1.0 0.34 1 12/30/20 23:39 630-20-6 ND ug/L 1.0 0.22 1 12/30/20 23:39 79-34-5 ND ug/L 1.0 0.16 1 12/30/20 23:39 127-18-4 ND ug/L 1.0 0.24 1 12/30/20 23:39 108-88-3 ND ug/L 1.0 0.18 1 12/30/20 23:39 71-55-6 ND ug/L 1.0 0.24 1 12/30/20 23:39 79-00-5 ND ug/L 1.0 0.22 1 12/30/20 23:39 79-01-6 ND ug/L 1.0 0.31 1 12/30/20 23:39 75-69-4 ND ug/L 1.0 0.35 1 12/30/20 23:39 96-18-4 ND ug/L 2.0 1.4 1 12/30/20 23:39 108-05-4 ND ug/L 1.0 0.24 1 12/30/20 23:39 75-01-4 ND ug/L 1.0 0.63 1 12/30/20 23:39 1330-20-7 99 % 70-130 1 12/30/20 23:39 460-00-4 112 % 70-130 1 12/30/20 23:39 17060-07-0 103 % 70-130 1 12/30/20 23:39 2037-26-5 Analytical Method: SM 213OB-2011 Pace Analytical Services -Asheville 26.2 NTU 1.0 0.16 1 12/31/20 06:07 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 189000 ug/L 5000 5000 1 01/04/21 22:27 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 27.6 mg/L 12.5 2.1 25 01/04/2120:02 H3,N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-26 Lab ID: 92514193004 Collected: 12/29/20 14:55 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 50.0 1 01/05/2112:51 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 4330 ug/L 1000 500 1 01/02/2112:28 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND ug/L 40.0 10.0 1 12/31/20 00:32 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 34600 ug/L 1000 500 1 01/07/2120:01 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 32400 ug/L 25000 12500 1 01/07/21 02:35 01/07/21 07:43 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 2740 ug/L 1000 500 1 01/04/21 16:54 7440-44-0 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-31 Lab ID: 92514193005 Collected: 12/29/20 14:58 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 226 ug/L 10.0 3.4 1 12/30/2017:45 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2102:49 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2102:49 7440-38-2 Barium 105 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2102:49 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2102:49 7440-41-7 Cadmium 2.7 ug/L 1.0 0.40 1 01/08/2101:37 01/11/2102:49 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2102:49 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2102:49 7440-48-4 Copper 7.0 ug/L 5.0 4.3 1 01/08/2101:37 01/11/2102:49 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2102:49 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2102:49 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2102:49 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2102:49 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2102:49 7440-62-2 Zinc 11.9 ug/L 10.0 9.5 1 01/08/2101:37 01/11/2102:49 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.052J ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:13 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 0.45J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 0.40J ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.5 ug/L 1.0 6.2 1 12/30/20 23:57 67-64-1 0.90 1 12/30/20 23:57 107-13-1 0.15 1 12/30/20 23:57 71-43-2 0.34 1 12/30/20 23:57 74-97-5 0.26 1 12/30/20 23:57 75-27-4 0.62 1 12/30/20 23:57 75-25-2 0.62 1 12/30/20 23:57 74-83-9 3.3 1 12/30/20 23:57 78-93-3 0.40 1 12/30/20 23:57 75-15-0 0.22 1 12/30/20 23:57 56-23-5 0.23 1 12/30/20 23:57 108-90-7 0.49 1 12/30/20 23:57 75-00-3 2.3 1 12/30/20 23:57 67-66-3 0.39 1 12/30/20 23:57 74-87-3 0.26 1 12/30/20 23:57 96-12-8 0.41 1 12/30/20 23:57 124-48-1 0.26 1 12/30/20 23:57 106-93-4 0.46 1 12/30/20 23:57 74-95-3 0.29 1 12/30/20 23:57 95-50-1 0.26 1 12/30/20 23:57 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-31 Lab ID: 92514193005 Collected: 12/29/20 14:58 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/30/20 23:57 110-57-6 ND ug/L 1.0 0.27 1 12/30/20 23:57 75-34-3 ND ug/L 1.0 0.34 1 12/30/20 23:57 107-06-2 ND ug/L 1.0 0.24 1 12/30/20 23:57 75-35-4 1.8 ug/L 1.0 0.29 1 12/30/20 23:57 156-59-2 ND ug/L 1.0 0.25 1 12/30/20 23:57 156-60-5 ND ug/L 1.0 0.19 1 12/30/20 23:57 78-87-5 ND ug/L 1.0 0.30 1 12/30/20 23:57 10061-01-5 ND ug/L 1.0 0.31 1 12/30/20 23:57 10061-02-6 ND ug/L 150 56.2 1 12/30/20 23:57 123-91-1 ND ug/L 1.0 0.26 1 12/30/20 23:57 100-41-4 ND ug/L 5.0 0.57 1 12/30/20 23:57 591-78-6 ND ug/L 20.0 12.5 1 12/30/20 23:57 74-88-4 v2 ND ug/L 5.0 3.7 1 12/30/20 23:57 75-09-2 ND ug/L 5.0 4.5 1 12/30/20 23:57 108-10-1 ND ug/L 1.0 0.27 1 12/30/20 23:57 100-42-5 ND ug/L 1.0 0.34 1 12/30/20 23:57 630-20-6 ND ug/L 1.0 0.22 1 12/30/20 23:57 79-34-5 ND ug/L 1.0 0.16 1 12/30/20 23:57 127-18-4 ND ug/L 1.0 0.24 1 12/30/20 23:57 108-88-3 ND ug/L 1.0 0.18 1 12/30/20 23:57 71-55-6 ND ug/L 1.0 0.24 1 12/30/20 23:57 79-00-5 ND ug/L 1.0 0.22 1 12/30/20 23:57 79-01-6 ND ug/L 1.0 0.31 1 12/30/20 23:57 75-69-4 ND ug/L 1.0 0.35 1 12/30/20 23:57 96-18-4 ND ug/L 2.0 1.4 1 12/30/20 23:57 108-05-4 ND ug/L 1.0 0.24 1 12/30/20 23:57 75-01-4 ND ug/L 1.0 0.63 1 12/30/20 23:57 1330-20-7 101 % 70-130 1 12/30/20 23:57 460-00-4 108 % 70-130 1 12/30/20 23:57 17060-07-0 104 % 70-130 1 12/30/20 23:57 2037-26-5 Analytical Method: SM 213OB-2011 Pace Analytical Services -Asheville 1.4 NTU 1.0 0.16 1 12/31/20 06:10 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 43100 ug/L 5000 5000 1 01/04/21 22:43 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 01/04/2119:01 H3,N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-31 Lab ID: 92514193005 Collected: 12/29/20 14:58 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide 95.8J ug/L 100 50.0 1 01/05/2112:52 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 836J ug/L 1000 500 1 01/02/2113:16 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 626 ug/L 40.0 10.0 1 12/31/20 00:33 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 22300 ug/L 1000 500 1 01/07/2120:01 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand ND ug/L 25000 12500 1 01/07/21 02:35 01/07/21 07:43 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1760 ug/L 1000 500 1 01/04/21 17:11 7440-44-0 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-12 Lab ID: 92514193006 Collected: 12/29/20 15:50 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 7600 ug/L 10.0 3.4 1 12/30/2018:00 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:05 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:05 7440-38-2 Barium 130 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:05 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:05 7440-41-7 Cadmium 2.1 ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:05 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:05 7440-47-3 Cobalt 47.8 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:05 7440-48-4 Copper 5.4 ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:05 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:05 7439-92-1 Nickel 7.9 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 03:05 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:05 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:05 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:05 7440-62-2 Zinc 52.4 ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:05 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.12 ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:17 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 2.6 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 2.0 ug/L 1.0 1.0 ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.0 ug/L 1.0 6.2 1 12/30/20 23:21 67-64-1 0.90 1 12/30/20 23:21 107-13-1 0.15 1 12/30/20 23:21 71-43-2 0.34 1 12/30/20 23:21 74-97-5 0.26 1 12/30/20 23:21 75-27-4 0.62 1 12/30/20 23:21 75-25-2 0.62 1 12/30/20 23:21 74-83-9 3.3 1 12/30/20 23:21 78-93-3 0.40 1 12/30/20 23:21 75-15-0 0.22 1 12/30/20 23:21 56-23-5 0.23 1 12/30/20 23:21 108-90-7 0.49 1 12/30/20 23:21 75-00-3 2.3 1 12/30/20 23:21 67-66-3 0.39 1 12/30/20 23:21 74-87-3 0.26 1 12/30/20 23:21 96-12-8 0.41 1 12/30/20 23:21 124-48-1 0.26 1 12/30/20 23:21 106-93-4 0.46 1 12/30/20 23:21 74-95-3 0.29 1 12/30/20 23:21 95-50-1 0.26 1 12/30/20 23:21 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-12 Lab ID: 92514193006 Collected: 12/29/20 15:50 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/30/20 23:21 110-57-6 0.58.1 ug/L 1.0 0.27 1 12/30/20 23:21 75-34-3 ND ug/L 1.0 0.34 1 12/30/20 23:21 107-06-2 ND ug/L 1.0 0.24 1 12/30/20 23:21 75-35-4 8.2 ug/L 1.0 0.29 1 12/30/20 23:21 156-59-2 ND ug/L 1.0 0.25 1 12/30/20 23:21 156-60-5 ND ug/L 1.0 0.19 1 12/30/20 23:21 78-87-5 N D ug/L 1.0 0.30 1 12/30/20 23:21 10061-01-5 ND ug/L 1.0 0.31 1 12/30/20 23:21 10061-02-6 ND ug/L 150 56.2 1 12/30/20 23:21 123-91-1 ND ug/L 1.0 0.26 1 12/30/20 23:21 100-41-4 ND ug/L 5.0 0.57 1 12/30/20 23:21 591-78-6 ND ug/L 20.0 12.5 1 12/30/20 23:21 74-88-4 v2 ND ug/L 5.0 3.7 1 12/30/20 23:21 75-09-2 ND ug/L 5.0 4.5 1 12/30/20 23:21 108-10-1 ND ug/L 1.0 0.27 1 12/30/20 23:21 100-42-5 ND ug/L 1.0 0.34 1 12/30/20 23:21 630-20-6 ND ug/L 1.0 0.22 1 12/30/20 23:21 79-34-5 ND ug/L 1.0 0.16 1 12/30/20 23:21 127-18-4 ND ug/L 1.0 0.24 1 12/30/20 23:21 108-88-3 ND ug/L 1.0 0.18 1 12/30/20 23:21 71-55-6 ND ug/L 1.0 0.24 1 12/30/20 23:21 79-00-5 0.72J ug/L 1.0 0.22 1 12/30/20 23:21 79-01-6 ND ug/L 1.0 0.31 1 12/30/20 23:21 75-69-4 ND ug/L 1.0 0.35 1 12/30/20 23:21 96-18-4 ND ug/L 2.0 1.4 1 12/30/20 23:21 108-05-4 ND ug/L 1.0 0.24 1 12/30/20 23:21 75-01-4 ND ug/L 1.0 0.63 1 12/30/20 23:21 1330-20-7 99 % 70-130 1 12/30/20 23:21 460-00-4 110 % 70-130 1 12/30/20 23:21 17060-07-0 105 % 70-130 1 12/30/20 23:21 2037-26-5 Analytical Method: SM 213OB-2011 Pace Analytical Services -Asheville 17.2 NTU 1.0 0.16 1 12/31/20 06:14 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 94700 ug/L 5000 5000 1 01/04/21 22:52 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 14.6 mg/L 5.0 0.84 10 01/04/2119:51 H3,N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-12 Lab ID: 92514193006 Collected: 12/29/20 15:50 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville Sulfide ND ug/L 100 50.0 1 01/05/2112:52 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 3810 ug/L 1000 500 1 01/02/2113:32 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 24AJ ug/L 40.0 10.0 1 12/31/20 00:44 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 36700 ug/L 1000 500 1 01/07/2120:02 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 18900J ug/L 25000 12500 1 01/07/21 02:35 01/07/21 07:43 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 3080 ug/L 1000 500 1 01/04/21 17:35 7440-44-0 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-16 Lab ID: 92514193007 Collected: 12/29/20 13:27 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 823 ug/L 10.0 3.4 1 12/30/2018:15 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:09 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:09 7440-38-2 Barium 56.7 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:09 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:09 7440-41-7 Cadmium 0.45J ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:09 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:09 7440-47-3 Cobalt 194 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:09 7440-48-4 Copper 4.5J ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:09 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:09 7439-92-1 Nickel 6.9 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 03:09 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:09 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:09 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:09 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:09 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.12 ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:21 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 12/31/20 00:51 67-64-1 0.90 1 12/31/20 00:51 107-13-1 0.15 1 12/31/20 00:51 71-43-2 0.34 1 12/31/20 00:51 74-97-5 0.26 1 12/31/20 00:51 75-27-4 0.62 1 12/31/20 00:51 75-25-2 0.62 1 12/31/20 00:51 74-83-9 3.3 1 12/31/20 00:51 78-93-3 0.40 1 12/31/20 00:51 75-15-0 0.22 1 12/31/20 00:51 56-23-5 0.23 1 12/31/20 00:51 108-90-7 0.49 1 12/31/20 00:51 75-00-3 2.3 1 12/31/20 00:51 67-66-3 0.39 1 12/31/20 00:51 74-87-3 0.26 1 12/31/20 00:51 96-12-8 0.41 1 12/31/20 00:51 124-48-1 0.26 1 12/31/20 00:51 106-93-4 0.46 1 12/31/20 00:51 74-95-3 0.29 1 12/31/20 00:51 95-50-1 0.26 1 12/31/20 00:51 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-16 Lab ID: 92514193007 Collected: 12/29/20 13:27 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 12/31/20 00:51 110-57-6 ND ug/L 1.0 0.27 1 12/31/20 00:51 75-34-3 ND ug/L 1.0 0.34 1 12/31/20 00:51 107-06-2 ND ug/L 1.0 0.24 1 12/31/20 00:51 75-35-4 ND ug/L 1.0 0.29 1 12/31/20 00:51 156-59-2 ND ug/L 1.0 0.25 1 12/31/20 00:51 156-60-5 ND ug/L 1.0 0.19 1 12/31/20 00:51 78-87-5 ND ug/L 1.0 0.30 1 12/31/20 00:51 10061-01-5 ND ug/L 1.0 0.31 1 12/31/20 00:51 10061-02-6 ND ug/L 150 56.2 1 12/31/20 00:51 123-91-1 ND ug/L 1.0 0.26 1 12/31/20 00:51 100-41-4 ND ug/L 5.0 0.57 1 12/31/20 00:51 591-78-6 ND ug/L 20.0 12.5 1 12/31/20 00:51 74-88-4 ND ug/L 5.0 3.7 1 12/31/20 00:51 75-09-2 ND ug/L 5.0 4.5 1 12/31/20 00:51 108-10-1 ND ug/L 1.0 0.27 1 12/31/20 00:51 100-42-5 ND ug/L 1.0 0.34 1 12/31/20 00:51 630-20-6 ND ug/L 1.0 0.22 1 12/31/20 00:51 79-34-5 ND ug/L 1.0 0.16 1 12/31/20 00:51 127-18-4 ND ug/L 1.0 0.24 1 12/31/20 00:51 108-88-3 ND ug/L 1.0 0.18 1 12/31/20 00:51 71-55-6 ND ug/L 1.0 0.24 1 12/31/20 00:51 79-00-5 ND ug/L 1.0 0.22 1 12/31/20 00:51 79-01-6 ND ug/L 1.0 0.31 1 12/31/20 00:51 75-69-4 ND ug/L 1.0 0.35 1 12/31/20 00:51 96-18-4 ND ug/L 2.0 1.4 1 12/31/20 00:51 108-05-4 ND ug/L 1.0 0.24 1 12/31/20 00:51 75-01-4 ND ug/L 1.0 0.63 1 12/31/20 00:51 1330-20-7 101 % 70-130 1 12/31/20 00:51 460-00-4 109 % 70-130 1 12/31/20 00:51 17060-07-0 105 % 70-130 1 12/31/20 00:51 2037-26-5 Analytical Method: SM 2130B-2011 Pace Analytical Services -Asheville 0.56J NTU 1.0 0.16 1 12/31/20 06:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 30 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-33 Lab ID: 92514193008 Collected: 12/29/20 13:16 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:12 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:12 7440-38-2 Barium 19.0 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:12 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:12 7440-41-7 Cadmium 1.0 ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:12 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:12 7440-47-3 Cobalt 7.6 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:12 7440-48-4 Copper 5.1 ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:12 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:12 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:12 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:12 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:12 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:12 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:25 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 12/30/20 21:51 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 12/30/20 21:51 107-13-1 Benzene ND ug/L 1.0 0.15 1 12/30/20 21:51 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 12/30/20 21:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 12/30/20 21:51 75-27-4 Bromoform ND ug/L 1.0 0.62 1 12/30/20 21:51 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 12/30/20 21:51 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 12/30/20 21:51 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 12/30/20 21:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 12/30/20 21:51 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/30/20 21:51 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 12/30/20 21:51 75-00-3 Chloroform ND ug/L 5.0 2.3 1 12/30/20 21:51 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 12/30/20 21:51 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 12/30/20 21:51 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 12/30/20 21:51 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 12/30/20 21:51 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 12/30/20 21:51 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 12/30/20 21:51 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 12/30/20 21:51 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 12/30/20 21:51 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 12/30/20 21:51 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 12/30/20 21:51 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 12/30/20 21:51 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-33 Lab ID: 92514193008 Collected: 12/29/20 13:16 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 12/30/20 21:51 156-59-2 ND ug/L 1.0 0.25 1 12/30/20 21:51 156-60-5 ND ug/L 1.0 0.19 1 12/30/20 21:51 78-87-5 ND ug/L 1.0 0.30 1 12/30/20 21:51 10061-01-5 ND ug/L 1.0 0.31 1 12/30/20 21:51 10061-02-6 ND ug/L 150 56.2 1 12/30/20 21:51 123-91-1 ND ug/L 1.0 0.26 1 12/30/20 21:51 100-41-4 ND ug/L 5.0 0.57 1 12/30/20 21:51 591-78-6 ND ug/L 20.0 12.5 1 12/30/20 21:51 74-88-4 v2 ND ug/L 5.0 3.7 1 12/30/20 21:51 75-09-2 ND ug/L 5.0 4.5 1 12/30/20 21:51 108-10-1 ND ug/L 1.0 0.27 1 12/30/20 21:51 100-42-5 ND ug/L 1.0 0.34 1 12/30/20 21:51 630-20-6 ND ug/L 1.0 0.22 1 12/30/20 21:51 79-34-5 ND ug/L 1.0 0.16 1 12/30/20 21:51 127-18-4 ND ug/L 1.0 0.24 1 12/30/20 21:51 108-88-3 ND ug/L 1.0 0.18 1 12/30/20 21:51 71-55-6 ND ug/L 1.0 0.24 1 12/30/20 21:51 79-00-5 ND ug/L 1.0 0.22 1 12/30/20 21:51 79-01-6 ND ug/L 1.0 0.31 1 12/30/20 21:51 75-69-4 ND ug/L 1.0 0.35 1 12/30/20 21:51 96-18-4 ND ug/L 2.0 1.4 1 12/30/20 21:51 108-05-4 ND ug/L 1.0 0.24 1 12/30/20 21:51 75-01-4 ND ug/L 1.0 0.63 1 12/30/20 21:51 1330-20-7 101 % 70-130 1 12/30/20 21:51 460-00-4 107 % 70-130 1 12/30/20 21:51 17060-07-0 104 % 70-130 1 12/30/20 21:51 2037-26-5 Analytical Method: SM 2130B-2011 Pace Analytical Services -Asheville 0.33J NTU 1.0 0.16 1 12/31/20 06:02 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-34 Lab ID: 92514193009 Collected: 12/29/20 13:08 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:15 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:15 7440-38-2 Barium 23.6 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:15 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:15 7440-41-7 Cadmium 0.74J ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:15 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:15 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:15 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:15 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:15 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:15 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:15 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:15 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:15 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:29 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 12/30/20 22:09 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 12/30/20 22:09 107-13-1 Benzene ND ug/L 1.0 0.15 1 12/30/20 22:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 12/30/20 22:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 12/30/20 22:09 75-27-4 Bromoform ND ug/L 1.0 0.62 1 12/30/20 22:09 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 12/30/20 22:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 12/30/20 22:09 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 12/30/20 22:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 12/30/20 22:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/30/20 22:09 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 12/30/20 22:09 75-00-3 Chloroform ND ug/L 5.0 2.3 1 12/30/20 22:09 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 12/30/20 22:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 12/30/20 22:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 12/30/20 22:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 12/30/20 22:09 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 12/30/20 22:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 12/30/20 22:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 12/30/20 22:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 12/30/20 22:09 110-57-6 1,1-Dichloroethane 0.87J ug/L 1.0 0.27 1 12/30/20 22:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 12/30/20 22:09 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 12/30/20 22:09 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-34 Lab ID: 92514193009 Collected: 12/29/20 13:08 Received: 12/30/20 09:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2130B Turbidity Turbidity Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.1 ug/L 1.0 0.29 1 12/30/20 22:09 156-59-2 ND ug/L 1.0 0.25 1 12/30/20 22:09 156-60-5 ND ug/L 1.0 0.19 1 12/30/20 22:09 78-87-5 ND ug/L 1.0 0.30 1 12/30/20 22:09 10061-01-5 ND ug/L 1.0 0.31 1 12/30/20 22:09 10061-02-6 ND ug/L 150 56.2 1 12/30/20 22:09 123-91-1 ND ug/L 1.0 0.26 1 12/30/20 22:09 100-41-4 ND ug/L 5.0 0.57 1 12/30/20 22:09 591-78-6 ND ug/L 20.0 12.5 1 12/30/20 22:09 74-88-4 v2 ND ug/L 5.0 3.7 1 12/30/20 22:09 75-09-2 ND ug/L 5.0 4.5 1 12/30/20 22:09 108-10-1 ND ug/L 1.0 0.27 1 12/30/20 22:09 100-42-5 ND ug/L 1.0 0.34 1 12/30/20 22:09 630-20-6 ND ug/L 1.0 0.22 1 12/30/20 22:09 79-34-5 ND ug/L 1.0 0.16 1 12/30/20 22:09 127-18-4 ND ug/L 1.0 0.24 1 12/30/20 22:09 108-88-3 ND ug/L 1.0 0.18 1 12/30/20 22:09 71-55-6 ND ug/L 1.0 0.24 1 12/30/20 22:09 79-00-5 ND ug/L 1.0 0.22 1 12/30/20 22:09 79-01-6 ND ug/L 1.0 0.31 1 12/30/20 22:09 75-69-4 ND ug/L 1.0 0.35 1 12/30/20 22:09 96-18-4 ND ug/L 2.0 1.4 1 12/30/20 22:09 108-05-4 ND ug/L 1.0 0.24 1 12/30/20 22:09 75-01-4 ND ug/L 1.0 0.63 1 12/30/20 22:09 1330-20-7 99 % 70-130 1 12/30/20 22:09 460-00-4 111 % 70-130 1 12/30/20 22:09 17060-07-0 104 % 70-130 1 12/30/20 22:09 2037-26-5 Analytical Method: SM 2130B-2011 Pace Analytical Services -Asheville 0.24J NTU 1.0 0.16 1 12/31/20 05:59 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-10 Lab ID: 92514193010 Collected: 12/30/20 13:52 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:19 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:19 7440-38-2 Barium 7.6 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:19 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:19 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:19 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:19 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:19 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:19 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:19 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:19 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:19 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:19 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:19 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/07/2101:35 01/08/2100:37 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 17:50 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 17:50 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 17:50 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 17:50 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 17:50 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 17:50 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 17:50 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 17:50 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 17:50 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 17:50 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 17:50 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 17:50 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 17:50 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 17:50 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 17:50 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 17:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 17:50 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 17:50 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 17:50 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 17:50 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 17:50 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 17:50 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 17:50 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 17:50 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 35 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-10 Lab ID: 92514193010 Collected: 12/30/20 13:52 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.8 ug/L 1.0 0.29 1 01/04/2117:50 156-59-2 ND ug/L 1.0 0.25 1 01/04/2117:50 156-60-5 ND ug/L 1.0 0.19 1 01/04/2117:50 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 17:50 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 17:50 10061-02-6 ND ug/L 150 56.2 1 01/04/2117:50 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 17:50 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 17:50 591-78-6 ND ug/L 20.0 12.5 1 01/04/2117:50 74-88-4 ND ug/L 5.0 3.7 1 01/04/2117:50 75-09-2 ND ug/L 5.0 4.5 1 01/04/2117:50 108-10-1 ND ug/L 1.0 0.27 1 01/04/2117:50 100-42-5 ND ug/L 1.0 0.34 1 01/04/2117:50 630-20-6 ND ug/L 1.0 0.22 1 01/04/2117:50 79-34-5 ND ug/L 1.0 0.16 1 01/04/2117:50 127-18-4 ND ug/L 1.0 0.24 1 01/04/2117:50 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 17:50 71-55-6 ND ug/L 1.0 0.24 1 01/04/2117:50 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 17:50 79-01-6 ND ug/L 1.0 0.31 1 01/04/2117:50 75-69-4 ND ug/L 1.0 0.35 1 01/04/2117:50 96-18-4 ND ug/L 2.0 1.4 1 01/04/2117:50 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 17:50 75-01-4 ND ug/L 1.0 0.63 1 01/04/2117:50 1330-20-7 102 % 70-130 1 01/04/2117:50 460-00-4 123 % 70-130 1 01/04/2117:50 17060-07-0 102 % 70-130 1 01/04/2117:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-13 Lab ID: 92514193011 Collected: 12/30/20 09:05 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:22 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:22 7440-38-2 Barium 11.3 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:22 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:22 7440-41-7 Cadmium 1.5 ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:22 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:22 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:22 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:22 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:22 7439-92-1 Nickel 4.3.1 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 03:22 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:22 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:22 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:22 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:22 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/08/2123:31 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 18:08 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 18:08 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 18:08 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 18:08 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 18:08 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 18:08 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 18:08 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 18:08 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 18:08 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 18:08 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 18:08 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 18:08 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 18:08 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 18:08 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 18:08 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 18:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 18:08 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 18:08 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 18:08 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 18:08 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 18:08 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 18:08 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 18:08 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 18:08 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 37 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-13 Lab ID: 92514193011 Collected: 12/30/20 09:05 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2118:08 156-59-2 ND ug/L 1.0 0.25 1 01/04/2118:08 156-60-5 ND ug/L 1.0 0.19 1 01/04/2118:08 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 18:08 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 18:08 10061-02-6 ND ug/L 150 56.2 1 01/04/2118:08 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 18:08 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 18:08 591-78-6 ND ug/L 20.0 12.5 1 01/04/2118:08 74-88-4 ND ug/L 5.0 3.7 1 01/04/2118:08 75-09-2 ND ug/L 5.0 4.5 1 01/04/2118:08 108-10-1 ND ug/L 1.0 0.27 1 01/04/2118:08 100-42-5 ND ug/L 1.0 0.34 1 01/04/2118:08 630-20-6 ND ug/L 1.0 0.22 1 01/04/2118:08 79-34-5 ND ug/L 1.0 0.16 1 01/04/2118:08 127-18-4 ND ug/L 1.0 0.24 1 01/04/2118:08 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 18:08 71-55-6 ND ug/L 1.0 0.24 1 01/04/2118:08 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 18:08 79-01-6 ND ug/L 1.0 0.31 1 01/04/2118:08 75-69-4 ND ug/L 1.0 0.35 1 01/04/2118:08 96-18-4 ND ug/L 2.0 1.4 1 01/04/2118:08 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 18:08 75-01-4 ND ug/L 1.0 0.63 1 01/04/2118:08 1330-20-7 101 % 70-130 1 01/04/2118:08 460-00-4 122 % 70-130 1 01/04/2118:08 17060-07-0 102 % 70-130 1 01/04/2118:08 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-14 Lab ID: 92514193012 Collected: 12/30/20 09:15 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:25 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:25 7440-38-2 Barium 34.0 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:25 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:25 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:25 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:25 7440-47-3 Cobalt 7.6 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:25 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:25 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:25 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:25 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:25 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:25 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:25 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:10 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 21:27 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 21:27 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 21:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 21:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 21:27 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 21:27 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 21:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 21:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 21:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 21:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 21:27 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 21:27 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 21:27 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 21:27 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 21:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 21:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 21:27 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 21:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 21:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 21:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 21:27 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 21:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 21:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 21:27 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 39 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-14 Lab ID: 92514193012 Collected: 12/30/20 09:15 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2121:27 156-59-2 ND ug/L 1.0 0.25 1 01/04/2121:27 156-60-5 ND ug/L 1.0 0.19 1 01/04/2121:27 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 21:27 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 21:27 10061-02-6 ND ug/L 150 56.2 1 01/04/2121:27 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 21:27 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 21:27 591-78-6 ND ug/L 20.0 12.5 1 01/04/2121:27 74-88-4 ND ug/L 5.0 3.7 1 01/04/2121:27 75-09-2 ND ug/L 5.0 4.5 1 01/04/2121:27 108-10-1 ND ug/L 1.0 0.27 1 01/04/2121:27 100-42-5 ND ug/L 1.0 0.34 1 01/04/2121:27 630-20-6 ND ug/L 1.0 0.22 1 01/04/2121:27 79-34-5 ND ug/L 1.0 0.16 1 01/04/2121:27 127-18-4 ND ug/L 1.0 0.24 1 01/04/2121:27 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 21:27 71-55-6 ND ug/L 1.0 0.24 1 01/04/2121:27 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 21:27 79-01-6 ND ug/L 1.0 0.31 1 01/04/2121:27 75-69-4 ND ug/L 1.0 0.35 1 01/04/2121:27 96-18-4 ND ug/L 2.0 1.4 1 01/04/2121:27 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 21:27 75-01-4 ND ug/L 1.0 0.63 1 01/04/2121:27 1330-20-7 103 % 70-130 1 01/04/2121:27 460-00-4 110 % 70-130 1 01/04/2121:27 17060-07-0 102 % 70-130 1 01/04/2121:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IH Page 40 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-19 Lab ID: 92514193013 Collected: 12/30/20 15:38 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:28 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:28 7440-38-2 Barium 24.4 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:28 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:28 7440-41-7 Cadmium 0.54J ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:28 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:28 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:28 7440-48-4 Copper 5.3 ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:28 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:28 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:28 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:28 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:28 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:14 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 18:26 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 18:26 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 18:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 18:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 18:26 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 18:26 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 18:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 18:26 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 18:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 18:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 18:26 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 18:26 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 18:26 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 18:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 18:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 18:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 18:26 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 18:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 18:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 18:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 18:26 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 18:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 18:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 18:26 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 41 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-19 Lab ID: 92514193013 Collected: 12/30/20 15:38 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2118:26 156-59-2 ND ug/L 1.0 0.25 1 01/04/2118:26 156-60-5 ND ug/L 1.0 0.19 1 01/04/2118:26 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 18:26 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 18:26 10061-02-6 ND ug/L 150 56.2 1 01/04/2118:26 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 18:26 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 18:26 591-78-6 ND ug/L 20.0 12.5 1 01/04/2118:26 74-88-4 ND ug/L 5.0 3.7 1 01/04/2118:26 75-09-2 ND ug/L 5.0 4.5 1 01/04/2118:26 108-10-1 ND ug/L 1.0 0.27 1 01/04/2118:26 100-42-5 ND ug/L 1.0 0.34 1 01/04/2118:26 630-20-6 ND ug/L 1.0 0.22 1 01/04/2118:26 79-34-5 ND ug/L 1.0 0.16 1 01/04/2118:26 127-18-4 ND ug/L 1.0 0.24 1 01/04/2118:26 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 18:26 71-55-6 ND ug/L 1.0 0.24 1 01/04/2118:26 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 18:26 79-01-6 ND ug/L 1.0 0.31 1 01/04/2118:26 75-69-4 ND ug/L 1.0 0.35 1 01/04/2118:26 96-18-4 ND ug/L 2.0 1.4 1 01/04/2118:26 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 18:26 75-01-4 ND ug/L 1.0 0.63 1 01/04/2118:26 1330-20-7 100 % 70-130 1 01/04/2118:26 460-00-4 119 % 70-130 1 01/04/2118:26 17060-07-0 100 % 70-130 1 01/04/2118:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-20 Lab ID: 92514193014 Collected: 12/31/20 09:10 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:31 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:31 7440-38-2 Barium 47.6 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:31 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:31 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:31 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:31 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:31 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:31 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:31 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:31 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:31 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:31 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:31 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:31 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:18 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/05/21 20:43 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/05/21 20:43 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/05/21 20:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/05/21 20:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/05/21 20:43 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/05/21 20:43 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/05/21 20:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/05/21 20:43 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/05/21 20:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/05/21 20:43 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/05/21 20:43 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/05/21 20:43 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/05/21 20:43 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/05/21 20:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/05/21 20:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/05/21 20:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/05/21 20:43 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/05/21 20:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/05/21 20:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/05/21 20:43 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/05/21 20:43 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/05/21 20:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/05/21 20:43 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/05/21 20:43 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. v2 v2 Page 43 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-20 Lab ID: 92514193014 Collected: 12/31/20 09:10 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/05/2120:43 156-59-2 ND ug/L 1.0 0.25 1 01/05/2120:43 156-60-5 ND ug/L 1.0 0.19 1 01/05/2120:43 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 20:43 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 20:43 10061-02-6 ND ug/L 150 56.2 1 01/05/2120:43 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 20:43 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 20:43 591-78-6 ND ug/L 20.0 12.5 1 01/05/2120:43 74-88-4 ND ug/L 5.0 3.7 1 01/05/2120:43 75-09-2 ND ug/L 5.0 4.5 1 01/05/2120:43 108-10-1 ND ug/L 1.0 0.27 1 01/05/2120:43 100-42-5 ND ug/L 1.0 0.34 1 01/05/2120:43 630-20-6 ND ug/L 1.0 0.22 1 01/05/2120:43 79-34-5 ND ug/L 1.0 0.16 1 01/05/2120:43 127-18-4 ND ug/L 1.0 0.24 1 01/05/2120:43 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 20:43 71-55-6 ND ug/L 1.0 0.24 1 01/05/2120:43 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 20:43 79-01-6 ND ug/L 1.0 0.31 1 01/05/2120:43 75-69-4 ND ug/L 1.0 0.35 1 01/05/2120:43 96-18-4 ND ug/L 2.0 1.4 1 01/05/2120:43 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 20:43 75-01-4 ND ug/L 1.0 0.63 1 01/05/2120:43 1330-20-7 102 % 70-130 1 01/05/2120:43 460-00-4 111 % 70-130 1 01/05/2120:43 17060-07-0 102 % 70-130 1 01/05/2120:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-22 Lab ID: 92514193015 Collected: 12/31/20 08:40 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:35 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:35 7440-38-2 Barium 46.2 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:35 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:35 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:35 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:35 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:35 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:35 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:35 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:35 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:35 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:35 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:35 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:22 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 17:32 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 17:32 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 17:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 17:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 17:32 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 17:32 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 17:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 17:32 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 17:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 17:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 17:32 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 17:32 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 17:32 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 17:32 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 17:32 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 17:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 17:32 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 17:32 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 17:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 17:32 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 17:32 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 17:32 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 17:32 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 17:32 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 45 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-22 Lab ID: 92514193015 Collected: 12/31/20 08:40 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2117:32 156-59-2 ND ug/L 1.0 0.25 1 01/04/2117:32 156-60-5 ND ug/L 1.0 0.19 1 01/04/2117:32 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 17:32 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 17:32 10061-02-6 ND ug/L 150 56.2 1 01/04/2117:32 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 17:32 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 17:32 591-78-6 ND ug/L 20.0 12.5 1 01/04/2117:32 74-88-4 ND ug/L 5.0 3.7 1 01/04/2117:32 75-09-2 ND ug/L 5.0 4.5 1 01/04/2117:32 108-10-1 ND ug/L 1.0 0.27 1 01/04/2117:32 100-42-5 ND ug/L 1.0 0.34 1 01/04/2117:32 630-20-6 ND ug/L 1.0 0.22 1 01/04/2117:32 79-34-5 ND ug/L 1.0 0.16 1 01/04/2117:32 127-18-4 ND ug/L 1.0 0.24 1 01/04/2117:32 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 17:32 71-55-6 ND ug/L 1.0 0.24 1 01/04/2117:32 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 17:32 79-01-6 ND ug/L 1.0 0.31 1 01/04/2117:32 75-69-4 ND ug/L 1.0 0.35 1 01/04/2117:32 96-18-4 ND ug/L 2.0 1.4 1 01/04/2117:32 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 17:32 75-01-4 ND ug/L 1.0 0.63 1 01/04/2117:32 1330-20-7 101 % 70-130 1 01/04/2117:32 460-00-4 124 % 70-130 1 01/04/2117:32 17060-07-0 102 % 70-130 1 01/04/2117:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-23 Lab ID: 92514193016 Collected: 12/31/20 08:17 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:44 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:44 7440-38-2 Barium 24.2 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:44 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:44 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:44 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:44 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:44 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:44 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:44 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:44 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:44 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:44 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:44 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:44 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:26 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 17:14 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 17:14 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 17:14 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 17:14 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 17:14 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 17:14 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 17:14 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 17:14 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 17:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 17:14 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 17:14 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 17:14 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 17:14 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 17:14 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 17:14 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 17:14 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 17:14 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 17:14 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 17:14 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 17:14 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 17:14 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 17:14 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 17:14 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 17:14 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 47 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-23 Lab ID: 92514193016 Collected: 12/31/20 08:17 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2117:14 156-59-2 ND ug/L 1.0 0.25 1 01/04/2117:14 156-60-5 ND ug/L 1.0 0.19 1 01/04/2117:14 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 17:14 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 17:14 10061-02-6 ND ug/L 150 56.2 1 01/04/2117:14 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 17:14 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 17:14 591-78-6 ND ug/L 20.0 12.5 1 01/04/2117:14 74-88-4 ND ug/L 5.0 3.7 1 01/04/2117:14 75-09-2 ND ug/L 5.0 4.5 1 01/04/2117:14 108-10-1 ND ug/L 1.0 0.27 1 01/04/2117:14 100-42-5 ND ug/L 1.0 0.34 1 01/04/2117:14 630-20-6 ND ug/L 1.0 0.22 1 01/04/2117:14 79-34-5 ND ug/L 1.0 0.16 1 01/04/2117:14 127-18-4 ND ug/L 1.0 0.24 1 01/04/2117:14 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 17:14 71-55-6 ND ug/L 1.0 0.24 1 01/04/2117:14 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 17:14 79-01-6 ND ug/L 1.0 0.31 1 01/04/2117:14 75-69-4 ND ug/L 1.0 0.35 1 01/04/2117:14 96-18-4 ND ug/L 2.0 1.4 1 01/04/2117:14 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 17:14 75-01-4 ND ug/L 1.0 0.63 1 01/04/2117:14 1330-20-7 100 % 70-130 1 01/04/2117:14 460-00-4 123 % 70-130 1 01/04/2117:14 17060-07-0 101 % 70-130 1 01/04/2117:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-32 Lab ID: 92514193017 Collected: 12/30/20 13:48 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:48 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:48 7440-38-2 Barium 4.6J ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:48 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:48 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:48 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:48 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:48 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:48 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:48 7439-92-1 Nickel 9.0 ug/L 5.0 3.5 1 01/08/21 01:37 01/11/21 03:48 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:48 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:48 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:48 7440-62-2 Zinc 10.9 ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:48 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:37 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 16:56 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 16:56 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 16:56 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 16:56 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 16:56 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 16:56 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 16:56 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 16:56 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 16:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 16:56 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 16:56 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 16:56 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 16:56 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 16:56 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 16:56 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 16:56 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 16:56 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 16:56 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 16:56 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 16:56 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 16:56 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 16:56 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 16:56 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 16:56 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 49 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-32 Lab ID: 92514193017 Collected: 12/30/20 13:48 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2116:56 156-59-2 ND ug/L 1.0 0.25 1 01/04/2116:56 156-60-5 ND ug/L 1.0 0.19 1 01/04/2116:56 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 16:56 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 16:56 10061-02-6 ND ug/L 150 56.2 1 01/04/2116:56 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 16:56 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 16:56 591-78-6 ND ug/L 20.0 12.5 1 01/04/2116:56 74-88-4 ND ug/L 5.0 3.7 1 01/04/2116:56 75-09-2 ND ug/L 5.0 4.5 1 01/04/2116:56 108-10-1 ND ug/L 1.0 0.27 1 01/04/2116:56 100-42-5 ND ug/L 1.0 0.34 1 01/04/2116:56 630-20-6 ND ug/L 1.0 0.22 1 01/04/2116:56 79-34-5 ND ug/L 1.0 0.16 1 01/04/2116:56 127-18-4 ND ug/L 1.0 0.24 1 01/04/2116:56 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 16:56 71-55-6 ND ug/L 1.0 0.24 1 01/04/2116:56 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 16:56 79-01-6 ND ug/L 1.0 0.31 1 01/04/2116:56 75-69-4 ND ug/L 1.0 0.35 1 01/04/2116:56 96-18-4 ND ug/L 2.0 1.4 1 01/04/2116:56 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 16:56 75-01-4 ND ug/L 1.0 0.63 1 01/04/2116:56 1330-20-7 102 % 70-130 1 01/04/2116:56 460-00-4 122 % 70-130 1 01/04/2116:56 17060-07-0 102 % 70-130 1 01/04/2116:56 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-3 Lab ID: 92514193018 Collected: 12/30/20 14:30 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:51 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:51 7440-38-2 Barium 36.8 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:51 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:51 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:51 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:51 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:51 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:51 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:51 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:51 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:51 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:51 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:51 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:51 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:41 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 16:38 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 16:38 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 16:38 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 16:38 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 16:38 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 16:38 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 16:38 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 16:38 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 16:38 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 16:38 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 16:38 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 16:38 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 16:38 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 16:38 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 16:38 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 16:38 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 16:38 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 16:38 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 16:38 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 16:38 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 16:38 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 16:38 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 16:38 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 16:38 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 51 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-3 Lab ID: 92514193018 Collected: 12/30/20 14:30 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2116:38 156-59-2 ND ug/L 1.0 0.25 1 01/04/2116:38 156-60-5 ND ug/L 1.0 0.19 1 01/04/2116:38 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 16:38 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 16:38 10061-02-6 ND ug/L 150 56.2 1 01/04/2116:38 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 16:38 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 16:38 591-78-6 ND ug/L 20.0 12.5 1 01/04/2116:38 74-88-4 ND ug/L 5.0 3.7 1 01/04/2116:38 75-09-2 ND ug/L 5.0 4.5 1 01/04/2116:38 108-10-1 ND ug/L 1.0 0.27 1 01/04/2116:38 100-42-5 ND ug/L 1.0 0.34 1 01/04/2116:38 630-20-6 ND ug/L 1.0 0.22 1 01/04/2116:38 79-34-5 ND ug/L 1.0 0.16 1 01/04/2116:38 127-18-4 ND ug/L 1.0 0.24 1 01/04/2116:38 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 16:38 71-55-6 ND ug/L 1.0 0.24 1 01/04/2116:38 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 16:38 79-01-6 ND ug/L 1.0 0.31 1 01/04/2116:38 75-69-4 ND ug/L 1.0 0.35 1 01/04/2116:38 96-18-4 ND ug/L 2.0 1.4 1 01/04/2116:38 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 16:38 75-01-4 ND ug/L 1.0 0.63 1 01/04/2116:38 1330-20-7 100 % 70-130 1 01/04/2116:38 460-00-4 124 % 70-130 1 01/04/2116:38 17060-07-0 104 % 70-130 1 01/04/2116:38 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-4R Lab ID: 92514193019 Collected: 12/31/20 08:28 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:54 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:54 7440-38-2 Barium 34.4 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:54 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:54 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:54 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:54 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:54 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:54 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:54 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:54 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:54 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:54 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:54 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:45 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 16:20 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 16:20 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 16:20 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 16:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 16:20 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 16:20 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 16:20 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 16:20 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 16:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 16:20 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 16:20 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 16:20 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 16:20 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 16:20 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 16:20 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 16:20 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 16:20 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 16:20 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 16:20 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 16:20 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 16:20 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 16:20 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 16:20 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 16:20 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 53 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-4R Lab ID: 92514193019 Collected: 12/31/20 08:28 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2116:20 156-59-2 ND ug/L 1.0 0.25 1 01/04/2116:20 156-60-5 ND ug/L 1.0 0.19 1 01/04/2116:20 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 16:20 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 16:20 10061-02-6 ND ug/L 150 56.2 1 01/04/2116:20 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 16:20 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 16:20 591-78-6 ND ug/L 20.0 12.5 1 01/04/2116:20 74-88-4 ND ug/L 5.0 3.7 1 01/04/2116:20 75-09-2 ND ug/L 5.0 4.5 1 01/04/2116:20 108-10-1 ND ug/L 1.0 0.27 1 01/04/2116:20 100-42-5 ND ug/L 1.0 0.34 1 01/04/2116:20 630-20-6 ND ug/L 1.0 0.22 1 01/04/2116:20 79-34-5 ND ug/L 1.0 0.16 1 01/04/2116:20 127-18-4 ND ug/L 1.0 0.24 1 01/04/2116:20 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 16:20 71-55-6 ND ug/L 1.0 0.24 1 01/04/2116:20 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 16:20 79-01-6 ND ug/L 1.0 0.31 1 01/04/2116:20 75-69-4 ND ug/L 1.0 0.35 1 01/04/2116:20 96-18-4 ND ug/L 2.0 1.4 1 01/04/2116:20 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 16:20 75-01-4 ND ug/L 1.0 0.63 1 01/04/2116:20 1330-20-7 101 % 70-130 1 01/04/2116:20 460-00-4 123 % 70-130 1 01/04/2116:20 17060-07-0 101 % 70-130 1 01/04/2116:20 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-5 Lab ID: 92514193020 Collected: 12/30/20 12:02 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2103:57 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:57 7440-38-2 Barium 23.8 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:57 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2103:57 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2103:57 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2103:57 7440-47-3 Cobalt 14.4 ug/L 5.0 3.6 1 01/08/2101:37 01/11/2103:57 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2103:57 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2103:57 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2103:57 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2103:57 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2103:57 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2103:57 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2103:57 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:49 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 20:15 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 20:15 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 20:15 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 20:15 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 20:15 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 20:15 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 20:15 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 20:15 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 20:15 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 20:15 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 20:15 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 20:15 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 20:15 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 20:15 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 20:15 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 20:15 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 20:15 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 20:15 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 20:15 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 20:15 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 20:15 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 20:15 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 20:15 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 20:15 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 55 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-5 Lab ID: 92514193020 Collected: 12/30/20 12:02 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.591 ug/L 1.0 0.29 1 01/04/2120:15 156-59-2 ND ug/L 1.0 0.25 1 01/04/2120:15 156-60-5 ND ug/L 1.0 0.19 1 01/04/2120:15 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 20:15 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 20:15 10061-02-6 ND ug/L 150 56.2 1 01/04/2120:15 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 20:15 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 20:15 591-78-6 ND ug/L 20.0 12.5 1 01/04/2120:15 74-88-4 ND ug/L 5.0 3.7 1 01/04/2120:15 75-09-2 ND ug/L 5.0 4.5 1 01/04/2120:15 108-10-1 ND ug/L 1.0 0.27 1 01/04/2120:15 100-42-5 ND ug/L 1.0 0.34 1 01/04/2120:15 630-20-6 ND ug/L 1.0 0.22 1 01/04/2120:15 79-34-5 ND ug/L 1.0 0.16 1 01/04/2120:15 127-18-4 ND ug/L 1.0 0.24 1 01/04/2120:15 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 20:15 71-55-6 ND ug/L 1.0 0.24 1 01/04/2120:15 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 20:15 79-01-6 ND ug/L 1.0 0.31 1 01/04/2120:15 75-69-4 ND ug/L 1.0 0.35 1 01/04/2120:15 96-18-4 ND ug/L 2.0 1.4 1 01/04/2120:15 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 20:15 75-01-4 ND ug/L 1.0 0.63 1 01/04/2120:15 1330-20-7 99 % 70-130 1 01/04/2120:15 460-00-4 111 % 70-130 1 01/04/2120:15 17060-07-0 101 % 70-130 1 01/04/2120:15 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-6 Lab ID: 92514193021 Collected: 12/30/20 13:38 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/08/2101:37 01/11/2104:00 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2104:00 7440-38-2 Barium 18.0 ug/L 5.0 3.5 1 01/08/2101:37 01/11/2104:00 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/08/2101:37 01/11/2104:00 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/08/2101:37 01/11/2104:00 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/08/2101:37 01/11/2104:00 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/08/2101:37 01/11/2104:00 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/08/2101:37 01/11/2104:00 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/08/2101:37 01/11/2104:00 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/08/2101:37 01/11/2104:00 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/08/2101:37 01/11/2104:00 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/08/2101:37 01/11/2104:00 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/08/2101:37 01/11/2104:00 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/08/2101:37 01/11/2104:00 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/08/2101:05 01/09/2100:53 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 19:57 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 19:57 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/04/21 19:57 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 19:57 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 19:57 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 19:57 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 19:57 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 19:57 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 19:57 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 19:57 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/04/21 19:57 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 19:57 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 19:57 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 19:57 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 19:57 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 19:57 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 19:57 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 19:57 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 19:57 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/04/21 19:57 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 19:57 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 19:57 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 19:57 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 19:57 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 57 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: SW-6 Lab ID: 92514193021 Collected: 12/30/20 13:38 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/04/2119:57 156-59-2 ND ug/L 1.0 0.25 1 01/04/2119:57 156-60-5 ND ug/L 1.0 0.19 1 01/04/2119:57 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 19:57 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 19:57 10061-02-6 ND ug/L 150 56.2 1 01/04/2119:57 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 19:57 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 19:57 591-78-6 ND ug/L 20.0 12.5 1 01/04/2119:57 74-88-4 ND ug/L 5.0 3.7 1 01/04/2119:57 75-09-2 ND ug/L 5.0 4.5 1 01/04/2119:57 108-10-1 ND ug/L 1.0 0.27 1 01/04/2119:57 100-42-5 ND ug/L 1.0 0.34 1 01/04/2119:57 630-20-6 ND ug/L 1.0 0.22 1 01/04/2119:57 79-34-5 ND ug/L 1.0 0.16 1 01/04/2119:57 127-18-4 ND ug/L 1.0 0.24 1 01/04/2119:57 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 19:57 71-55-6 ND ug/L 1.0 0.24 1 01/04/2119:57 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 19:57 79-01-6 ND ug/L 1.0 0.31 1 01/04/2119:57 75-69-4 ND ug/L 1.0 0.35 1 01/04/2119:57 96-18-4 ND ug/L 2.0 1.4 1 01/04/2119:57 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 19:57 75-01-4 ND ug/L 1.0 0.63 1 01/04/2119:57 1330-20-7 101 % 70-130 1 01/04/2119:57 460-00-4 113 % 70-130 1 01/04/2119:57 17060-07-0 101 % 70-130 1 01/04/2119:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-4R Lab ID: 92514193022 Collected: 12/30/20 14:14 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:13 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:13 7440-38-2 Barium 75.8 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:13 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:13 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:13 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:13 7440-47-3 Cobalt 183 ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:13 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:13 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:13 7439-92-1 Nickel 4.2J ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:13 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:13 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:13 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:13 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:13 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:06 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/04/21 19:39 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/04/21 19:39 107-13-1 Benzene 0.30J ug/L 1.0 0.15 1 01/04/21 19:39 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/04/21 19:39 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/04/21 19:39 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/04/21 19:39 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/04/21 19:39 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/04/21 19:39 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/04/21 19:39 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/04/21 19:39 56-23-5 Chlorobenzene 0.43J ug/L 1.0 0.23 1 01/04/21 19:39 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/04/21 19:39 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/04/21 19:39 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/04/21 19:39 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/04/21 19:39 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/04/21 19:39 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/04/21 19:39 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/04/21 19:39 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/04/21 19:39 95-50-1 1,4-Dichlorobenzene 1.3 ug/L 1.0 0.26 1 01/04/21 19:39 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/04/21 19:39 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/04/21 19:39 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/04/21 19:39 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/04/21 19:39 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. IK v1 Page 59 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-4R Lab ID: 92514193022 Collected: 12/30/20 14:14 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.3 ug/L 1.0 0.29 1 01/04/2119:39 156-59-2 ND ug/L 1.0 0.25 1 01/04/2119:39 156-60-5 ND ug/L 1.0 0.19 1 01/04/2119:39 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 19:39 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 19:39 10061-02-6 ND ug/L 150 56.2 1 01/04/2119:39 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 19:39 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 19:39 591-78-6 ND ug/L 20.0 12.5 1 01/04/2119:39 74-88-4 ND ug/L 5.0 3.7 1 01/04/2119:39 75-09-2 ND ug/L 5.0 4.5 1 01/04/2119:39 108-10-1 ND ug/L 1.0 0.27 1 01/04/2119:39 100-42-5 ND ug/L 1.0 0.34 1 01/04/2119:39 630-20-6 ND ug/L 1.0 0.22 1 01/04/2119:39 79-34-5 ND ug/L 1.0 0.16 1 01/04/2119:39 127-18-4 ND ug/L 1.0 0.24 1 01/04/2119:39 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 19:39 71-55-6 ND ug/L 1.0 0.24 1 01/04/2119:39 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 19:39 79-01-6 ND ug/L 1.0 0.31 1 01/04/2119:39 75-69-4 ND ug/L 1.0 0.35 1 01/04/2119:39 96-18-4 ND ug/L 2.0 1.4 1 01/04/2119:39 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 19:39 75-01-4 ND ug/L 1.0 0.63 1 01/04/2119:39 1330-20-7 100 % 70-130 1 01/04/2119:39 460-00-4 114 % 70-130 1 01/04/2119:39 17060-07-0 101 % 70-130 1 01/04/2119:39 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-7 Lab ID: 92514193023 Collected: 12/31/20 09:18 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:26 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:26 7440-38-2 Barium 6.7 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:26 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:26 7440-41-7 Cadmium 0.60J ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:26 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:26 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:26 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:26 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:26 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:26 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:26 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:26 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:26 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:26 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:10 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/05/21 21:37 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/05/21 21:37 107-13-1 Benzene 2.0 ug/L 1.0 0.15 1 01/05/21 21:37 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/05/21 21:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/05/21 21:37 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/05/21 21:37 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/05/21 21:37 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/05/21 21:37 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/05/21 21:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/05/21 21:37 56-23-5 Chlorobenzene 0.85J ug/L 1.0 0.23 1 01/05/21 21:37 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/05/21 21:37 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/05/21 21:37 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/05/21 21:37 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/05/21 21:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/05/21 21:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/05/21 21:37 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/05/21 21:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/05/21 21:37 95-50-1 1,4-Dichlorobenzene 0.981 ug/L 1.0 0.26 1 01/05/21 21:37 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/05/21 21:37 110-57-6 1,1-Dichloroethane 0.78J ug/L 1.0 0.27 1 01/05/21 21:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/05/21 21:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/05/21 21:37 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. v2 v2 Page 61 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-7 Lab ID: 92514193023 Collected: 12/31/20 09:18 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.3 ug/L 1.0 0.29 1 01/05/2121:37 156-59-2 ND ug/L 1.0 0.25 1 01/05/2121:37 156-60-5 ND ug/L 1.0 0.19 1 01/05/2121:37 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 21:37 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 21:37 10061-02-6 ND ug/L 150 56.2 1 01/05/2121:37 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 21:37 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 21:37 591-78-6 ND ug/L 20.0 12.5 1 01/05/2121:37 74-88-4 ND ug/L 5.0 3.7 1 01/05/2121:37 75-09-2 ND ug/L 5.0 4.5 1 01/05/2121:37 108-10-1 ND ug/L 1.0 0.27 1 01/05/2121:37 100-42-5 ND ug/L 1.0 0.34 1 01/05/2121:37 630-20-6 ND ug/L 1.0 0.22 1 01/05/2121:37 79-34-5 ND ug/L 1.0 0.16 1 01/05/2121:37 127-18-4 0.39J ug/L 1.0 0.24 1 01/05/2121:37 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 21:37 71-55-6 ND ug/L 1.0 0.24 1 01/05/2121:37 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 21:37 79-01-6 ND ug/L 1.0 0.31 1 01/05/2121:37 75-69-4 ND ug/L 1.0 0.35 1 01/05/2121:37 96-18-4 ND ug/L 2.0 1.4 1 01/05/2121:37 108-05-4 2.3 ug/L 1.0 0.24 1 01/05/2121:37 75-01-4 ND ug/L 1.0 0.63 1 01/05/2121:37 1330-20-7 102 % 70-130 1 01/05/2121:37 460-00-4 110 % 70-130 1 01/05/2121:37 17060-07-0 104 % 70-130 1 01/05/2121:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-9 Lab ID: 92514193024 Collected: 12/30/20 14:20 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony 3.1J ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:29 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:29 7440-38-2 Barium 195 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:29 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:29 7440-41-7 Cadmium 0.591 ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:29 7440-43-9 Chromium 7.4 ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:29 7440-47-3 Cobalt 200 ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:29 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:29 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:29 7439-92-1 Nickel 71.9 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:29 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:29 7782-49-2 Silver 5.3 ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:29 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:29 7440-62-2 Zinc 14.1 ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:29 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.13 ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:37 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/05/21 21:19 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/05/21 21:19 107-13-1 Benzene 0.44J ug/L 1.0 0.15 1 01/05/21 21:19 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/05/21 21:19 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/05/21 21:19 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/05/21 21:19 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/05/21 21:19 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/05/21 21:19 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/05/21 21:19 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/05/21 21:19 56-23-5 Chlorobenzene 0.51J ug/L 1.0 0.23 1 01/05/21 21:19 108-90-7 Chloroethane 0.69J ug/L 1.0 0.49 1 01/05/21 21:19 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/05/21 21:19 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/05/21 21:19 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/05/21 21:19 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/05/21 21:19 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/05/21 21:19 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/05/21 21:19 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/05/21 21:19 95-50-1 1,4-Dichlorobenzene 1.1 ug/L 1.0 0.26 1 01/05/21 21:19 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/05/21 21:19 110-57-6 1,1-Dichloroethane 0.38J ug/L 1.0 0.27 1 01/05/21 21:19 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/05/21 21:19 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/05/21 21:19 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. v2 v2 Page 63 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-9 Lab ID: 92514193024 Collected: 12/30/20 14:20 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 10.1 ug/L 1.0 0.29 1 01/05/2121:19 156-59-2 ND ug/L 1.0 0.25 1 01/05/2121:19 156-60-5 ND ug/L 1.0 0.19 1 01/05/2121:19 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 21:19 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 21:19 10061-02-6 ND ug/L 150 56.2 1 01/05/2121:19 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 21:19 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 21:19 591-78-6 ND ug/L 20.0 12.5 1 01/05/2121:19 74-88-4 ND ug/L 5.0 3.7 1 01/05/2121:19 75-09-2 ND ug/L 5.0 4.5 1 01/05/2121:19 108-10-1 ND ug/L 1.0 0.27 1 01/05/2121:19 100-42-5 ND ug/L 1.0 0.34 1 01/05/2121:19 630-20-6 ND ug/L 1.0 0.22 1 01/05/2121:19 79-34-5 ND ug/L 1.0 0.16 1 01/05/2121:19 127-18-4 ND ug/L 1.0 0.24 1 01/05/2121:19 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 21:19 71-55-6 ND ug/L 1.0 0.24 1 01/05/2121:19 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 21:19 79-01-6 ND ug/L 1.0 0.31 1 01/05/2121:19 75-69-4 ND ug/L 1.0 0.35 1 01/05/2121:19 96-18-4 ND ug/L 2.0 1.4 1 01/05/2121:19 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 21:19 75-01-4 ND ug/L 1.0 0.63 1 01/05/2121:19 1330-20-7 100 % 70-130 1 01/05/2121:19 460-00-4 109 % 70-130 1 01/05/2121:19 17060-07-0 104 % 70-130 1 01/05/2121:19 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 64 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-3 Lab ID: 92514193025 Collected: 12/31/20 09:25 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:39 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:39 7440-38-2 Barium 54.9 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:39 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:39 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:39 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:39 7440-47-3 Cobalt 17.5 ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:39 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:39 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:39 7439-92-1 Nickel 8.2 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:39 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:39 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:39 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:39 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:39 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:41 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/05/21 21:01 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/05/21 21:01 107-13-1 Benzene 4.9 ug/L 1.0 0.15 1 01/05/21 21:01 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/05/21 21:01 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/05/21 21:01 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/05/21 21:01 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/05/21 21:01 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/05/21 21:01 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/05/21 21:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/05/21 21:01 56-23-5 Chlorobenzene 1.6 ug/L 1.0 0.23 1 01/05/21 21:01 108-90-7 Chloroethane 0.54J ug/L 1.0 0.49 1 01/05/21 21:01 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/05/21 21:01 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/05/21 21:01 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/05/21 21:01 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/05/21 21:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/05/21 21:01 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/05/21 21:01 74-95-3 1,2-Dichlorobenzene 0.79J ug/L 1.0 0.29 1 01/05/21 21:01 95-50-1 1,4-Dichlorobenzene 8.0 ug/L 1.0 0.26 1 01/05/21 21:01 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/05/21 21:01 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/05/21 21:01 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/05/21 21:01 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/05/21 21:01 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. v2 v2 Page 65 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-3 Lab ID: 92514193025 Collected: 12/31/20 09:25 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 3.5 ug/L 1.0 0.29 1 01/05/2121:01 156-59-2 ND ug/L 1.0 0.25 1 01/05/2121:01 156-60-5 ND ug/L 1.0 0.19 1 01/05/2121:01 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 21:01 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 21:01 10061-02-6 ND ug/L 150 56.2 1 01/05/2121:01 123-91-1 1.3 ug/L 1.0 0.26 1 01/05/2121:01 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 21:01 591-78-6 ND ug/L 20.0 12.5 1 01/05/2121:01 74-88-4 ND ug/L 5.0 3.7 1 01/05/2121:01 75-09-2 ND ug/L 5.0 4.5 1 01/05/2121:01 108-10-1 ND ug/L 1.0 0.27 1 01/05/2121:01 100-42-5 ND ug/L 1.0 0.34 1 01/05/2121:01 630-20-6 ND ug/L 1.0 0.22 1 01/05/2121:01 79-34-5 ND ug/L 1.0 0.16 1 01/05/2121:01 127-18-4 0.56J ug/L 1.0 0.24 1 01/05/2121:01 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 21:01 71-55-6 ND ug/L 1.0 0.24 1 01/05/2121:01 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 21:01 79-01-6 ND ug/L 1.0 0.31 1 01/05/2121:01 75-69-4 ND ug/L 1.0 0.35 1 01/05/2121:01 96-18-4 ND ug/L 2.0 1.4 1 01/05/2121:01 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 21:01 75-01-4 3.1 ug/L 1.0 0.63 1 01/05/2121:01 1330-20-7 103 % 70-130 1 01/05/2121:01 460-00-4 111 % 70-130 1 01/05/2121:01 17060-07-0 102 % 70-130 1 01/05/2121:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: EB Lab ID: 92514193026 Collected: 12/31/20 09:43 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:42 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:42 7440-38-2 Barium ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:42 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:42 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:42 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:42 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:42 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:42 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:42 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:42 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:42 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:42 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:42 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:42 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:45 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 01/05/21 16:29 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 01/05/21 16:29 107-13-1 Benzene ND ug/L 1.0 0.15 1 01/05/21 16:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 01/05/21 16:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 01/05/21 16:29 75-27-4 Bromoform ND ug/L 1.0 0.62 1 01/05/21 16:29 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 01/05/21 16:29 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 01/05/21 16:29 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 01/05/21 16:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 01/05/21 16:29 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/05/21 16:29 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 01/05/21 16:29 75-00-3 Chloroform ND ug/L 5.0 2.3 1 01/05/21 16:29 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 01/05/21 16:29 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 01/05/21 16:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 01/05/21 16:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 01/05/21 16:29 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 01/05/21 16:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 01/05/21 16:29 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 01/05/21 16:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 01/05/21 16:29 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 01/05/21 16:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 01/05/21 16:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 01/05/21 16:29 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. v2 v2 Page 67 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: EB Lab ID: 92514193026 Collected: 12/31/20 09:43 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 01/05/2116:29 156-59-2 ND ug/L 1.0 0.25 1 01/05/2116:29 156-60-5 ND ug/L 1.0 0.19 1 01/05/2116:29 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 16:29 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 16:29 10061-02-6 ND ug/L 150 56.2 1 01/05/2116:29 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 16:29 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 16:29 591-78-6 ND ug/L 20.0 12.5 1 01/05/2116:29 74-88-4 ND ug/L 5.0 3.7 1 01/05/2116:29 75-09-2 ND ug/L 5.0 4.5 1 01/05/2116:29 108-10-1 ND ug/L 1.0 0.27 1 01/05/2116:29 100-42-5 ND ug/L 1.0 0.34 1 01/05/2116:29 630-20-6 ND ug/L 1.0 0.22 1 01/05/2116:29 79-34-5 ND ug/L 1.0 0.16 1 01/05/2116:29 127-18-4 ND ug/L 1.0 0.24 1 01/05/2116:29 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 16:29 71-55-6 ND ug/L 1.0 0.24 1 01/05/2116:29 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 16:29 79-01-6 ND ug/L 1.0 0.31 1 01/05/2116:29 75-69-4 ND ug/L 1.0 0.35 1 01/05/2116:29 96-18-4 ND ug/L 2.0 1.4 1 01/05/2116:29 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 16:29 75-01-4 ND ug/L 1.0 0.63 1 01/05/2116:29 1330-20-7 97 % 70-130 1 01/05/2116:29 460-00-4 111 % 70-130 1 01/05/2116:29 17060-07-0 103 % 70-130 1 01/05/2116:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 68 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: FB Lab ID: 92514193027 Collected: 12/31/20 09:46 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 6.2 1 01/05/2116:48 67-64-1 ND ug/L 10.0 0.90 1 01/05/2116:48 107-13-1 ND ug/L 1.0 0.15 1 01 /05/21 16:48 71-43-2 ND ug/L 1.0 0.34 1 01/05/2116:48 74-97-5 ND ug/L 1.0 0.26 1 01/05/2116:48 75-27-4 ND ug/L 1.0 0.62 1 01/05/2116:48 75-25-2 ND ug/L 2.0 0.62 1 01/05/2116:48 74-83-9 ND ug/L 5.0 3.3 1 01/05/2116:48 78-93-3 ND ug/L 2.0 0.40 1 01/05/2116:48 75-15-0 ND ug/L 1.0 0.22 1 01/05/2116:48 56-23-5 ND ug/L 1.0 0.23 1 01/05/2116:48 108-90-7 ND ug/L 1.0 0.49 1 01/05/2116:48 75-00-3 ND ug/L 5.0 2.3 1 01/05/2116:48 67-66-3 ND ug/L 1.0 0.39 1 01/05/2116:48 74-87-3 ND ug/L 5.0 0.26 1 01/05/2116:48 96-12-8 ND ug/L 1.0 0.41 1 01/05/2116:48 124-48-1 ND ug/L 1.0 0.26 1 01/05/2116:48 106-93-4 ND ug/L 1.0 0.46 1 01/05/2116:48 74-95-3 ND ug/L 1.0 0.29 1 01/05/2116:48 95-50-1 ND ug/L 1.0 0.26 1 01/05/2116:48 106-46-7 ND ug/L 1.0 0.54 1 01/05/2116:48 110-57-6 ND ug/L 1.0 0.27 1 01/05/2116:48 75-34-3 ND ug/L 1.0 0.34 1 01/05/2116:48 107-06-2 ND ug/L 1.0 0.24 1 01/05/2116:48 75-35-4 ND ug/L 1.0 0.29 1 01/05/2116:48 156-59-2 ND ug/L 1.0 0.25 1 01/05/2116:48 156-60-5 ND ug/L 1.0 0.19 1 01/05/2116:48 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 16:48 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 16:48 10061-02-6 ND ug/L 150 56.2 1 01/05/2116:48 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 16:48 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 16:48 591-78-6 ND ug/L 20.0 12.5 1 01/05/2116:48 74-88-4 ND ug/L 5.0 3.7 1 01/05/2116:48 75-09-2 ND ug/L 5.0 4.5 1 01/05/2116:48 108-10-1 ND ug/L 1.0 0.27 1 01/05/2116:48 100-42-5 ND ug/L 1.0 0.34 1 01/05/2116:48 630-20-6 ND ug/L 1.0 0.22 1 01/05/2116:48 79-34-5 ND ug/L 1.0 0.16 1 01/05/2116:48 127-18-4 ND ug/L 1.0 0.24 1 01/05/2116:48 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 16:48 71-55-6 ND ug/L 1.0 0.24 1 01/05/2116:48 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 16:48 79-01-6 ND ug/L 1.0 0.31 1 01/05/2116:48 75-69-4 ND ug/L 1.0 0.35 1 01/05/2116:48 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 69 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: FB Parameters Lab ID: Results 92514193027 Units Collected: Report Limit 12/31/20 09:46 MDL DF Received: 12/31/20 13:11 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.4 1 01/05/21 16:48 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 01/05/21 16:48 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 01/05/21 16:48 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 01/05/21 16:48 460-00-4 1,2-Dichloroethane-d4 (S) 111 % 70-130 1 01/05/21 16:48 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 01/05/21 16:48 2037-26-5 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 70 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-6 Lab ID: 92514193028 Collected: 12/30/20 09:09 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane ND ug/L 10.0 3.4 1 01/06/2113:44 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:46 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:46 7440-38-2 Barium 64.2 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:46 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:46 7440-41-7 Cadmium 5.8 ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:46 7440-43-9 Chromium 11.0 ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:46 7440-47-3 Cobalt 10.9 ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:46 7440-48-4 Copper 6.3 ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:46 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:46 7439-92-1 Nickel 5.6 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:46 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:46 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:46 7440-22-4 Vanadium 3.9J ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:46 7440-62-2 Zinc 12.8 ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:46 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.073J ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:49 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 0.16J ug/L 0.20 0.12 1 01/05/2110:54 01/05/2115:31 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 01/04/21 21:09 67-64-1 0.90 1 01/04/21 21:09 107-13-1 0.15 1 01/04/21 21:09 71-43-2 0.34 1 01/04/21 21:09 74-97-5 0.26 1 01/04/21 21:09 75-27-4 0.62 1 01/04/21 21:09 75-25-2 0.62 1 01/04/21 21:09 74-83-9 3.3 1 01/04/21 21:09 78-93-3 0.40 1 01/04/21 21:09 75-15-0 0.22 1 01/04/21 21:09 56-23-5 0.23 1 01/04/21 21:09 108-90-7 0.49 1 01/04/21 21:09 75-00-3 2.3 1 01/04/21 21:09 67-66-3 0.39 1 01/04/21 21:09 74-87-3 0.26 1 01/04/21 21:09 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK Page 71 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-6 Lab ID: 92514193028 Collected: 12/30/20 09:09 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 01/04/2121:09 124-48-1 ND ug/L 1.0 0.26 1 01/04/2121:09 106-93-4 ND ug/L 1.0 0.46 1 01/04/2121:09 74-95-3 ND ug/L 1.0 0.29 1 01/04/2121:09 95-50-1 ND ug/L 1.0 0.26 1 01/04/2121:09 106-46-7 ND ug/L 1.0 0.54 1 01/04/2121:09 110-57-6 v1 ND ug/L 1.0 0.27 1 01/04/2121:09 75-34-3 ND ug/L 1.0 0.34 1 01/04/2121:09 107-06-2 ND ug/L 1.0 0.24 1 01/04/2121:09 75-35-4 ND ug/L 1.0 0.29 1 01/04/2121:09 156-59-2 ND ug/L 1.0 0.25 1 01/04/2121:09 156-60-5 ND ug/L 1.0 0.19 1 01/04/2121:09 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 21:09 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 21:09 10061-02-6 ND ug/L 150 56.2 1 01/04/2121:09 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 21:09 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 21:09 591-78-6 ND ug/L 20.0 12.5 1 01/04/2121:09 74-88-4 ND ug/L 5.0 3.7 1 01/04/2121:09 75-09-2 ND ug/L 5.0 4.5 1 01/04/2121:09 108-10-1 ND ug/L 1.0 0.27 1 01/04/2121:09 100-42-5 ND ug/L 1.0 0.34 1 01/04/2121:09 630-20-6 ND ug/L 1.0 0.22 1 01/04/2121:09 79-34-5 ND ug/L 1.0 0.16 1 01/04/2121:09 127-18-4 ND ug/L 1.0 0.24 1 01/04/2121:09 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 21:09 71-55-6 ND ug/L 1.0 0.24 1 01/04/2121:09 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 21:09 79-01-6 ND ug/L 1.0 0.31 1 01/04/2121:09 75-69-4 ND ug/L 1.0 0.35 1 01/04/2121:09 96-18-4 ND ug/L 2.0 1.4 1 01/04/2121:09 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 21:09 75-01-4 ND ug/L 1.0 0.63 1 01/04/2121:09 1330-20-7 102 % 70-130 1 01/04/2121:09 460-00-4 110 % 70-130 1 01/04/2121:09 17060-07-0 100 % 70-130 1 01/04/2121:09 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 72 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-17 Lab ID: 92514193029 Collected: 12/31/20 08:59 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 180 ug/L 10.0 3.4 1 01/06/2113:59 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:49 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:49 7440-38-2 Barium 63.0 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:49 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:49 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:49 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:49 7440-47-3 Cobalt 15.6 ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:49 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:49 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:49 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:49 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:49 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:49 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:49 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:49 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.061J ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:52 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 0.24 ug/L 0.20 0.12 1 01/05/2110:54 01/05/2115:43 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 01/04/21 20:33 67-64-1 0.90 1 01/04/21 20:33 107-13-1 0.15 1 01/04/21 20:33 71-43-2 0.34 1 01/04/21 20:33 74-97-5 0.26 1 01/04/21 20:33 75-27-4 0.62 1 01/04/21 20:33 75-25-2 0.62 1 01/04/21 20:33 74-83-9 3.3 1 01/04/21 20:33 78-93-3 0.40 1 01/04/21 20:33 75-15-0 0.22 1 01/04/21 20:33 56-23-5 0.23 1 01/04/21 20:33 108-90-7 0.49 1 01/04/21 20:33 75-00-3 2.3 1 01/04/21 20:33 67-66-3 0.39 1 01/04/21 20:33 74-87-3 0.26 1 01/04/21 20:33 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK Page 73 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-17 Lab ID: 92514193029 Collected: 12/31/20 08:59 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 01/04/2120:33 124-48-1 ND ug/L 1.0 0.26 1 01/04/2120:33 106-93-4 ND ug/L 1.0 0.46 1 01/04/2120:33 74-95-3 ND ug/L 1.0 0.29 1 01/04/2120:33 95-50-1 ND ug/L 1.0 0.26 1 01/04/2120:33 106-46-7 ND ug/L 1.0 0.54 1 01/04/2120:33 110-57-6 v1 ND ug/L 1.0 0.27 1 01/04/2120:33 75-34-3 ND ug/L 1.0 0.34 1 01/04/2120:33 107-06-2 ND ug/L 1.0 0.24 1 01/04/2120:33 75-35-4 1.3 ug/L 1.0 0.29 1 01/04/2120:33 156-59-2 ND ug/L 1.0 0.25 1 01/04/2120:33 156-60-5 ND ug/L 1.0 0.19 1 01/04/2120:33 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 20:33 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 20:33 10061-02-6 ND ug/L 150 56.2 1 01/04/2120:33 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 20:33 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 20:33 591-78-6 ND ug/L 20.0 12.5 1 01/04/2120:33 74-88-4 ND ug/L 5.0 3.7 1 01/04/2120:33 75-09-2 ND ug/L 5.0 4.5 1 01/04/2120:33 108-10-1 ND ug/L 1.0 0.27 1 01/04/2120:33 100-42-5 ND ug/L 1.0 0.34 1 01/04/2120:33 630-20-6 ND ug/L 1.0 0.22 1 01/04/2120:33 79-34-5 ND ug/L 1.0 0.16 1 01/04/2120:33 127-18-4 ND ug/L 1.0 0.24 1 01/04/2120:33 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 20:33 71-55-6 ND ug/L 1.0 0.24 1 01/04/2120:33 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 20:33 79-01-6 ND ug/L 1.0 0.31 1 01/04/2120:33 75-69-4 ND ug/L 1.0 0.35 1 01/04/2120:33 96-18-4 ND ug/L 2.0 1.4 1 01/04/2120:33 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 20:33 75-01-4 ND ug/L 1.0 0.63 1 01/04/2120:33 1330-20-7 101 % 70-130 1 01/04/2120:33 460-00-4 109 % 70-130 1 01/04/2120:33 17060-07-0 101 % 70-130 1 01/04/2120:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 74 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-18 Lab ID: 92514193030 Collected: 12/30/20 15:45 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane ND ug/L 10.0 3.4 1 01/06/2114:15 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:52 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:52 7440-38-2 Barium 6.9 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:52 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:52 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:52 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:52 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:52 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:52 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:52 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:52 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:52 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:52 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:52 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:52 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2100:56 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 01 /05/21 10:54 01 /05/21 15:46 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 01/04/21 19:21 67-64-1 0.90 1 01/04/21 19:21 107-13-1 0.15 1 01/04/21 19:21 71-43-2 0.34 1 01/04/21 19:21 74-97-5 0.26 1 01/04/21 19:21 75-27-4 0.62 1 01/04/21 19:21 75-25-2 0.62 1 01/04/21 19:21 74-83-9 3.3 1 01/04/21 19:21 78-93-3 0.40 1 01/04/21 19:21 75-15-0 0.22 1 01/04/21 19:21 56-23-5 0.23 1 01/04/21 19:21 108-90-7 0.49 1 01/04/21 19:21 75-00-3 2.3 1 01/04/21 19:21 67-66-3 0.39 1 01/04/21 19:21 74-87-3 0.26 1 01/04/21 19:21 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK Page 75 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-18 Lab ID: 92514193030 Collected: 12/30/20 15:45 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 01/04/2119:21 124-48-1 ND ug/L 1.0 0.26 1 01/04/2119:21 106-93-4 ND ug/L 1.0 0.46 1 01/04/2119:21 74-95-3 ND ug/L 1.0 0.29 1 01/04/2119:21 95-50-1 ND ug/L 1.0 0.26 1 01/04/2119:21 106-46-7 ND ug/L 1.0 0.54 1 01/04/2119:21 110-57-6 v1 ND ug/L 1.0 0.27 1 01/04/2119:21 75-34-3 ND ug/L 1.0 0.34 1 01/04/2119:21 107-06-2 ND ug/L 1.0 0.24 1 01/04/2119:21 75-35-4 ND ug/L 1.0 0.29 1 01/04/2119:21 156-59-2 ND ug/L 1.0 0.25 1 01/04/2119:21 156-60-5 ND ug/L 1.0 0.19 1 01/04/2119:21 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 19:21 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 19:21 10061-02-6 ND ug/L 150 56.2 1 01/04/2119:21 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 19:21 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 19:21 591-78-6 ND ug/L 20.0 12.5 1 01/04/2119:21 74-88-4 ND ug/L 5.0 3.7 1 01/04/2119:21 75-09-2 ND ug/L 5.0 4.5 1 01/04/2119:21 108-10-1 ND ug/L 1.0 0.27 1 01/04/2119:21 100-42-5 ND ug/L 1.0 0.34 1 01/04/2119:21 630-20-6 ND ug/L 1.0 0.22 1 01/04/2119:21 79-34-5 ND ug/L 1.0 0.16 1 01/04/2119:21 127-18-4 ND ug/L 1.0 0.24 1 01/04/2119:21 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 19:21 71-55-6 ND ug/L 1.0 0.24 1 01/04/2119:21 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 19:21 79-01-6 ND ug/L 1.0 0.31 1 01/04/2119:21 75-69-4 ND ug/L 1.0 0.35 1 01/04/2119:21 96-18-4 ND ug/L 2.0 1.4 1 01/04/2119:21 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 19:21 75-01-4 ND ug/L 1.0 0.63 1 01/04/2119:21 1330-20-7 101 % 70-130 1 01/04/2119:21 460-00-4 114 % 70-130 1 01/04/2119:21 17060-07-0 100 % 70-130 1 01/04/2119:21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 76 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-21 Lab ID: 92514193031 Collected: 12/31/20 08:46 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 3.8J ug/L 10.0 3.4 1 01/06/2114:30 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:55 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:55 7440-38-2 Barium 30.4 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:55 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:55 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:55 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:55 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:55 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:55 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:55 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:55 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:55 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:55 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:55 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:55 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:08 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 01 /05/21 10:54 01 /05/21 15:48 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 01/04/21 19:03 67-64-1 0.90 1 01/04/21 19:03 107-13-1 0.15 1 01/04/21 19:03 71-43-2 0.34 1 01/04/21 19:03 74-97-5 0.26 1 01/04/21 19:03 75-27-4 0.62 1 01/04/21 19:03 75-25-2 0.62 1 01/04/21 19:03 74-83-9 3.3 1 01/04/21 19:03 78-93-3 0.40 1 01/04/21 19:03 75-15-0 0.22 1 01/04/21 19:03 56-23-5 0.23 1 01/04/21 19:03 108-90-7 0.49 1 01/04/21 19:03 75-00-3 2.3 1 01/04/21 19:03 67-66-3 0.39 1 01/04/21 19:03 74-87-3 0.26 1 01/04/21 19:03 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK Page 77 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-21 Lab ID: 92514193031 Collected: 12/31/20 08:46 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 01/04/2119:03 124-48-1 ND ug/L 1.0 0.26 1 01/04/2119:03 106-93-4 ND ug/L 1.0 0.46 1 01/04/2119:03 74-95-3 ND ug/L 1.0 0.29 1 01/04/2119:03 95-50-1 ND ug/L 1.0 0.26 1 01/04/2119:03 106-46-7 ND ug/L 1.0 0.54 1 01/04/2119:03 110-57-6 v1 ND ug/L 1.0 0.27 1 01/04/2119:03 75-34-3 ND ug/L 1.0 0.34 1 01/04/2119:03 107-06-2 ND ug/L 1.0 0.24 1 01/04/2119:03 75-35-4 ND ug/L 1.0 0.29 1 01/04/2119:03 156-59-2 ND ug/L 1.0 0.25 1 01/04/2119:03 156-60-5 ND ug/L 1.0 0.19 1 01/04/2119:03 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 19:03 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 19:03 10061-02-6 ND ug/L 150 56.2 1 01/04/2119:03 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 19:03 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 19:03 591-78-6 ND ug/L 20.0 12.5 1 01/04/2119:03 74-88-4 ND ug/L 5.0 3.7 1 01/04/2119:03 75-09-2 ND ug/L 5.0 4.5 1 01/04/2119:03 108-10-1 ND ug/L 1.0 0.27 1 01/04/2119:03 100-42-5 ND ug/L 1.0 0.34 1 01/04/2119:03 630-20-6 ND ug/L 1.0 0.22 1 01/04/2119:03 79-34-5 ND ug/L 1.0 0.16 1 01/04/2119:03 127-18-4 ND ug/L 1.0 0.24 1 01/04/2119:03 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 19:03 71-55-6 ND ug/L 1.0 0.24 1 01/04/2119:03 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 19:03 79-01-6 ND ug/L 1.0 0.31 1 01/04/2119:03 75-69-4 ND ug/L 1.0 0.35 1 01/04/2119:03 96-18-4 ND ug/L 2.0 1.4 1 01/04/2119:03 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 19:03 75-01-4 ND ug/L 1.0 0.63 1 01/04/2119:03 1330-20-7 98 % 70-130 1 01/04/2119:03 460-00-4 117 % 70-130 1 01/04/2119:03 17060-07-0 100 % 70-130 1 01/04/2119:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 78 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MWA Lab ID: 92514193032 Collected: 12/31/20 09:32 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 946 ug/L 10.0 3.4 1 01/06/2114:45 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/10/2123:59 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:59 7440-38-2 Barium 25.1 ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:59 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/10/2123:59 7440-41-7 Cadmium 0.83J ug/L 1.0 0.40 1 01/09/2102:10 01/10/2123:59 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/10/2123:59 7440-47-3 Cobalt 5.7 ug/L 5.0 3.6 1 01/09/2102:10 01/10/2123:59 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/10/2123:59 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/10/2123:59 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/10/2123:59 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/10/2123:59 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/10/2123:59 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/10/2123:59 7440-62-2 Zinc 21.1 ug/L 10.0 9.5 1 01/09/2102:10 01/10/2123:59 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:12 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 01/05/21 10:54 01/05/21 15:50 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 0.44J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 01/05/21 21:55 67-64-1 0.90 1 01/05/21 21:55 107-13-1 0.15 1 01/05/21 21:55 71-43-2 0.34 1 01/05/21 21:55 74-97-5 0.26 1 01/05/21 21:55 75-27-4 0.62 1 01/05/21 21:55 75-25-2 0.62 1 01/05/21 21:55 74-83-9 3.3 1 01/05/21 21:55 78-93-3 0.40 1 01/05/21 21:55 75-15-0 v2 0.22 1 01/05/21 21:55 56-23-5 0.23 1 01/05/21 21:55 108-90-7 0.49 1 01/05/21 21:55 75-00-3 2.3 1 01/05/21 21:55 67-66-3 0.39 1 01/05/21 21:55 74-87-3 v2 0.26 1 01/05/21 21:55 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 79 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-1 Lab ID: 92514193032 Collected: 12/31/20 09:32 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 01/05/2121:55 124-48-1 ND ug/L 1.0 0.26 1 01/05/2121:55 106-93-4 ND ug/L 1.0 0.46 1 01/05/2121:55 74-95-3 ND ug/L 1.0 0.29 1 01/05/2121:55 95-50-1 1.7 ug/L 1.0 0.26 1 01/05/2121:55 106-46-7 ND ug/L 1.0 0.54 1 01/05/2121:55 110-57-6 ND ug/L 1.0 0.27 1 01/05/2121:55 75-34-3 ND ug/L 1.0 0.34 1 01/05/2121:55 107-06-2 ND ug/L 1.0 0.24 1 01/05/2121:55 75-35-4 ND ug/L 1.0 0.29 1 01/05/2121:55 156-59-2 ND ug/L 1.0 0.25 1 01/05/2121:55 156-60-5 ND ug/L 1.0 0.19 1 01/05/2121:55 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 21:55 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 21:55 10061-02-6 ND ug/L 150 56.2 1 01/05/2121:55 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 21:55 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 21:55 591-78-6 ND ug/L 20.0 12.5 1 01/05/2121:55 74-88-4 ND ug/L 5.0 3.7 1 01/05/2121:55 75-09-2 ND ug/L 5.0 4.5 1 01/05/2121:55 108-10-1 ND ug/L 1.0 0.27 1 01/05/2121:55 100-42-5 ND ug/L 1.0 0.34 1 01/05/2121:55 630-20-6 ND ug/L 1.0 0.22 1 01/05/2121:55 79-34-5 ND ug/L 1.0 0.16 1 01/05/2121:55 127-18-4 ND ug/L 1.0 0.24 1 01/05/2121:55 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 21:55 71-55-6 ND ug/L 1.0 0.24 1 01/05/2121:55 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 21:55 79-01-6 ND ug/L 1.0 0.31 1 01/05/2121:55 75-69-4 ND ug/L 1.0 0.35 1 01/05/2121:55 96-18-4 ND ug/L 2.0 1.4 1 01/05/2121:55 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 21:55 75-01-4 ND ug/L 1.0 0.63 1 01/05/2121:55 1330-20-7 101 % 70-130 1 01/05/2121:55 460-00-4 107 % 70-130 1 01/05/2121:55 17060-07-0 106 % 70-130 1 01/05/2121:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 80 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MWAB Lab ID: 92514193033 Collected: 12/30/20 15:33 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 8.1J ug/L 10.0 3.4 1 01/06/2115:01 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/11/2100:02 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:02 7440-38-2 Barium 39.3 ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:02 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/11/2100:02 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/11/2100:02 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/11/2100:02 7440-47-3 Cobalt 42.1 ug/L 5.0 3.6 1 01/09/2102:10 01/11/2100:02 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/11/2100:02 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/11/2100:02 7439-92-1 Nickel 4.8J ug/L 5.0 3.5 1 01/09/21 02:10 01/11/21 00:02 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:02 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/11/2100:02 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/11/2100:02 7440-62-2 Zinc 9.91 ug/L 10.0 9.5 1 01/09/2102:10 01/11/2100:02 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.072J ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:16 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 3.5 ug/L 0.20 0.12 1 01/05/2110:54 01/05/2115:53 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 01/04/21 18:45 67-64-1 0.90 1 01/04/21 18:45 107-13-1 0.15 1 01/04/21 18:45 71-43-2 0.34 1 01/04/21 18:45 74-97-5 0.26 1 01/04/21 18:45 75-27-4 0.62 1 01/04/21 18:45 75-25-2 0.62 1 01/04/21 18:45 74-83-9 3.3 1 01/04/21 18:45 78-93-3 0.40 1 01/04/21 18:45 75-15-0 0.22 1 01/04/21 18:45 56-23-5 0.23 1 01/04/21 18:45 108-90-7 0.49 1 01/04/21 18:45 75-00-3 2.3 1 01/04/21 18:45 67-66-3 0.39 1 01/04/21 18:45 74-87-3 0.26 1 01/04/21 18:45 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK Page 81 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-113 Lab ID: 92514193033 Collected: 12/30/20 15:33 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 01/04/2118:45 124-48-1 ND ug/L 1.0 0.26 1 01/04/2118:45 106-93-4 ND ug/L 1.0 0.46 1 01/04/2118:45 74-95-3 ND ug/L 1.0 0.29 1 01/04/2118:45 95-50-1 0.84J ug/L 1.0 0.26 1 01/04/2118:45 106-46-7 ND ug/L 1.0 0.54 1 01/04/2118:45 110-57-6 v1 ND ug/L 1.0 0.27 1 01/04/2118:45 75-34-3 ND ug/L 1.0 0.34 1 01/04/2118:45 107-06-2 ND ug/L 1.0 0.24 1 01/04/2118:45 75-35-4 0.43J ug/L 1.0 0.29 1 01/04/2118:45 156-59-2 ND ug/L 1.0 0.25 1 01/04/2118:45 156-60-5 ND ug/L 1.0 0.19 1 01/04/2118:45 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 18:45 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 18:45 10061-02-6 ND ug/L 150 56.2 1 01/04/2118:45 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 18:45 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 18:45 591-78-6 ND ug/L 20.0 12.5 1 01/04/2118:45 74-88-4 ND ug/L 5.0 3.7 1 01/04/2118:45 75-09-2 ND ug/L 5.0 4.5 1 01/04/2118:45 108-10-1 ND ug/L 1.0 0.27 1 01/04/2118:45 100-42-5 ND ug/L 1.0 0.34 1 01/04/2118:45 630-20-6 ND ug/L 1.0 0.22 1 01/04/2118:45 79-34-5 ND ug/L 1.0 0.16 1 01/04/2118:45 127-18-4 ND ug/L 1.0 0.24 1 01/04/2118:45 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 18:45 71-55-6 ND ug/L 1.0 0.24 1 01/04/2118:45 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 18:45 79-01-6 ND ug/L 1.0 0.31 1 01/04/2118:45 75-69-4 ND ug/L 1.0 0.35 1 01/04/2118:45 96-18-4 ND ug/L 2.0 1.4 1 01/04/2118:45 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 18:45 75-01-4 ND ug/L 1.0 0.63 1 01/04/2118:45 1330-20-7 100 % 70-130 1 01/04/2118:45 460-00-4 118 % 70-130 1 01/04/2118:45 17060-07-0 100 % 70-130 1 01/04/2118:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 82 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-2 Lab ID: 92514193034 Collected: 12/30/20 09:28 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/21 02:10 01/11/21 00:05 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/21 02:10 01/11/21 00:05 7440-38-2 Barium 26.1 ug/L 5.0 3.5 1 01/09/21 02:10 01/11/21 00:05 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/21 02:10 01/11/21 00:05 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/21 02:10 01/11/21 00:05 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/21 02:10 01/11/21 00:05 7440-47-3 Cobalt 243 ug/L 5.0 3.6 1 01/09/21 02:10 01/11/21 00:05 7440-48-4 Copper 5.OJ ug/L 5.0 4.3 1 01/09/21 02:10 01/11/21 00:05 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/21 02:10 01/11/21 00:05 7439-92-1 Nickel 5.8 ug/L 5.0 3.5 1 01/09/21 02:10 01/11/21 00:05 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/21 02:10 01/11/21 00:05 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/21 02:10 01/11/21 00:05 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/21 02:10 01/11/21 00:05 7440-62-2 Zinc 11.3 ug/L 10.0 9.5 1 01/09/21 02:10 01/11/21 00:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.19 ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:20 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville ND ug/L 0.20 0.12 1 01/05/2110:54 01/05/2115:55 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 01/04/21 20:51 67-64-1 0.90 1 01/04/21 20:51 107-13-1 0.15 1 01/04/21 20:51 71-43-2 0.34 1 01/04/21 20:51 74-97-5 0.26 1 01/04/21 20:51 75-27-4 0.62 1 01/04/21 20:51 75-25-2 0.62 1 01/04/21 20:51 74-83-9 3.3 1 01/04/21 20:51 78-93-3 0.40 1 01/04/21 20:51 75-15-0 0.22 1 01/04/21 20:51 56-23-5 0.23 1 01/04/21 20:51 108-90-7 0.49 1 01/04/21 20:51 75-00-3 2.3 1 01/04/21 20:51 67-66-3 0.39 1 01/04/21 20:51 74-87-3 0.26 1 01/04/21 20:51 96-12-8 0.41 1 01/04/21 20:51 124-48-1 0.26 1 01/04/21 20:51 106-93-4 0.46 1 01/04/21 20:51 74-95-3 0.29 1 01/04/21 20:51 95-50-1 0.26 1 01/04/21 20:51 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK Page 83 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-2 Lab ID: 92514193034 Collected: 12/30/20 09:28 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 01/04/2120:51 110-57-6 v1 ND ug/L 1.0 0.27 1 01/04/2120:51 75-34-3 ND ug/L 1.0 0.34 1 01/04/2120:51 107-06-2 ND ug/L 1.0 0.24 1 01/04/2120:51 75-35-4 ND ug/L 1.0 0.29 1 01/04/2120:51 156-59-2 ND ug/L 1.0 0.25 1 01/04/2120:51 156-60-5 ND ug/L 1.0 0.19 1 01/04/2120:51 78-87-5 ND ug/L 1.0 0.30 1 01 /04/21 20:51 10061-01-5 ND ug/L 1.0 0.31 1 01 /04/21 20:51 10061-02-6 ND ug/L 150 56.2 1 01/04/2120:51 123-91-1 ND ug/L 1.0 0.26 1 01 /04/21 20:51 100-41-4 ND ug/L 5.0 0.57 1 01 /04/21 20:51 591-78-6 ND ug/L 20.0 12.5 1 01/04/2120:51 74-88-4 ND ug/L 5.0 3.7 1 01/04/2120:51 75-09-2 ND ug/L 5.0 4.5 1 01/04/2120:51 108-10-1 ND ug/L 1.0 0.27 1 01/04/2120:51 100-42-5 ND ug/L 1.0 0.34 1 01/04/2120:51 630-20-6 ND ug/L 1.0 0.22 1 01/04/2120:51 79-34-5 ND ug/L 1.0 0.16 1 01/04/2120:51 127-18-4 ND ug/L 1.0 0.24 1 01/04/2120:51 108-88-3 ND ug/L 1.0 0.18 1 01 /04/21 20:51 71-55-6 ND ug/L 1.0 0.24 1 01/04/2120:51 79-00-5 ND ug/L 1.0 0.22 1 01 /04/21 20:51 79-01-6 ND ug/L 1.0 0.31 1 01/04/2120:51 75-69-4 ND ug/L 1.0 0.35 1 01/04/2120:51 96-18-4 ND ug/L 2.0 1.4 1 01/04/2120:51 108-05-4 ND ug/L 1.0 0.24 1 01 /04/21 20:51 75-01-4 ND ug/L 1.0 0.63 1 01/04/2120:51 1330-20-7 101 % 70-130 1 01/04/2120:51 460-00-4 110 % 70-130 1 01/04/2120:51 17060-07-0 100 % 70-130 1 01/04/2120:51 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 84 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-15 Lab ID: 92514193035 Collected: 12/31/20 09:08 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/11/2100:08 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:08 7440-38-2 Barium 74.3 ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:08 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/11/2100:08 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/11/2100:08 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/11/2100:08 7440-47-3 Cobalt 154 ug/L 5.0 3.6 1 01/09/2102:10 01/11/2100:08 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/11/2100:08 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/11/2100:08 7439-92-1 Nickel 3.9.1 ug/L 5.0 3.5 1 01/09/21 02:10 01/11/21 00:08 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:08 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/11/2100:08 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/11/2100:08 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/11/2100:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.084J ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:23 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 2.2 ug/L 0.20 0.12 1 01/05/2110:54 01/05/2115:58 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 43.4 ug/L 25.0 ND ug/L 10.0 2.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 0.71J ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.66J ug/L 1.0 6.2 1 01/05/21 22:13 67-64-1 0.90 1 01/05/21 22:13 107-13-1 0.15 1 01/05/21 22:13 71-43-2 0.34 1 01/05/21 22:13 74-97-5 0.26 1 01/05/21 22:13 75-27-4 0.62 1 01/05/21 22:13 75-25-2 0.62 1 01/05/21 22:13 74-83-9 3.3 1 01/05/21 22:13 78-93-3 0.40 1 01/05/21 22:13 75-15-0 0.22 1 01/05/21 22:13 56-23-5 0.23 1 01/05/21 22:13 108-90-7 0.49 1 01/05/21 22:13 75-00-3 2.3 1 01/05/21 22:13 67-66-3 0.39 1 01/05/21 22:13 74-87-3 0.26 1 01/05/21 22:13 96-12-8 0.41 1 01/05/21 22:13 124-48-1 0.26 1 01/05/21 22:13 106-93-4 0.46 1 01/05/21 22:13 74-95-3 0.29 1 01/05/21 22:13 95-50-1 0.26 1 01/05/21 22:13 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 85 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-15 Lab ID: 92514193035 Collected: 12/31/20 09:08 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 01/05/2122:13 110-57-6 0.94J ug/L 1.0 0.27 1 01/05/2122:13 75-34-3 ND ug/L 1.0 0.34 1 01/05/2122:13 107-06-2 ND ug/L 1.0 0.24 1 01/05/2122:13 75-35-4 5.2 ug/L 1.0 0.29 1 01/05/2122:13 156-59-2 ND ug/L 1.0 0.25 1 01/05/2122:13 156-60-5 ND ug/L 1.0 0.19 1 01/05/2122:13 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 22:13 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 22:13 10061-02-6 ND ug/L 150 56.2 1 01/05/2122:13 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 22:13 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 22:13 591-78-6 ND ug/L 20.0 12.5 1 01/05/2122:13 74-88-4 ND ug/L 5.0 3.7 1 01/05/2122:13 75-09-2 ND ug/L 5.0 4.5 1 01/05/2122:13 108-10-1 ND ug/L 1.0 0.27 1 01/05/2122:13 100-42-5 ND ug/L 1.0 0.34 1 01/05/2122:13 630-20-6 ND ug/L 1.0 0.22 1 01/05/2122:13 79-34-5 ND ug/L 1.0 0.16 1 01/05/2122:13 127-18-4 ND ug/L 1.0 0.24 1 01/05/2122:13 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 22:13 71-55-6 ND ug/L 1.0 0.24 1 01/05/2122:13 79-00-5 0.92J ug/L 1.0 0.22 1 01/05/21 22:13 79-01-6 ND ug/L 1.0 0.31 1 01/05/2122:13 75-69-4 ND ug/L 1.0 0.35 1 01/05/2122:13 96-18-4 ND ug/L 2.0 1.4 1 01/05/2122:13 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 22:13 75-01-4 ND ug/L 1.0 0.63 1 01/05/2122:13 1330-20-7 99 % 70-130 1 01/05/2122:13 460-00-4 110 % 70-130 1 01/05/2122:13 17060-07-0 105 % 70-130 1 01/05/2122:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 86 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-25 Lab ID: 92514193036 Collected: 12/30/20 08:55 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane ND ug/L 10.0 3.4 1 01/06/2115:16 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/11/2100:18 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:18 7440-38-2 Barium 56.6 ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:18 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/11/2100:18 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 01/09/2102:10 01/11/2100:18 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/11/2100:18 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/11/2100:18 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/11/2100:18 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/11/2100:18 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:18 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:18 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/11/2100:18 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/11/2100:18 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/11/2100:18 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.057J ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:27 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 01/05/2123:08 67-64-1 0.90 1 01 /05/21 23:08 107-13-1 0.15 1 01 /05/21 23:08 71-43-2 0.34 1 01 /05/21 23:08 74-97-5 0.26 1 01 /05/21 23:08 75-27-4 0.62 1 01 /05/21 23:08 75-25-2 0.62 1 01 /05/21 23:08 74-83-9 3.3 1 01 /05/21 23:08 78-93-3 0.40 1 01/05/2123:08 75-15-0 0.22 1 01 /05/21 23:08 56-23-5 0.23 1 01 /05/21 23:08 108-90-7 0.49 1 01 /05/21 23:08 75-00-3 2.3 1 01 /05/21 23:08 67-66-3 0.39 1 01 /05/21 23:08 74-87-3 0.26 1 01/05/2123:08 96-12-8 0.41 1 01 /05/21 23:08 124-48-1 0.26 1 01 /05/21 23:08 106-93-4 0.46 1 01 /05/21 23:08 74-95-3 0.29 1 01/05/2123:08 95-50-1 0.26 1 01 /05/21 23:08 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 87 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-25 Lab ID: 92514193036 Collected: 12/30/20 08:55 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 01/05/2123:08 110-57-6 ND ug/L 1.0 0.27 1 01/05/2123:08 75-34-3 ND ug/L 1.0 0.34 1 01/05/2123:08 107-06-2 ND ug/L 1.0 0.24 1 01/05/2123:08 75-35-4 ND ug/L 1.0 0.29 1 01/05/2123:08 156-59-2 ND ug/L 1.0 0.25 1 01/05/2123:08 156-60-5 ND ug/L 1.0 0.19 1 01/05/2123:08 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 23:08 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 23:08 10061-02-6 ND ug/L 150 56.2 1 01/05/2123:08 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 23:08 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 23:08 591-78-6 ND ug/L 20.0 12.5 1 01/05/2123:08 74-88-4 ND ug/L 5.0 3.7 1 01/05/2123:08 75-09-2 ND ug/L 5.0 4.5 1 01/05/2123:08 108-10-1 ND ug/L 1.0 0.27 1 01/05/2123:08 100-42-5 ND ug/L 1.0 0.34 1 01/05/2123:08 630-20-6 ND ug/L 1.0 0.22 1 01/05/2123:08 79-34-5 ND ug/L 1.0 0.16 1 01/05/2123:08 127-18-4 ND ug/L 1.0 0.24 1 01/05/2123:08 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 23:08 71-55-6 ND ug/L 1.0 0.24 1 01/05/2123:08 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 23:08 79-01-6 ND ug/L 1.0 0.31 1 01/05/2123:08 75-69-4 ND ug/L 1.0 0.35 1 01/05/2123:08 96-18-4 ND ug/L 2.0 1.4 1 01/05/2123:08 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 23:08 75-01-4 ND ug/L 1.0 0.63 1 01/05/2123:08 1330-20-7 97 % 70-130 1 01/05/2123:08 460-00-4 108 % 70-130 1 01/05/2123:08 17060-07-0 104 % 70-130 1 01/05/2123:08 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 88 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-27 Lab ID: 92514193037 Collected: 12/30/20 14:47 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane ND ug/L 10.0 3.4 1 01/06/2115:31 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/11/2100:21 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:21 7440-38-2 Barium 55.0 ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/11/2100:21 7440-41-7 Cadmium 0.74J ug/L 1.0 0.40 1 01/09/2102:10 01/11/2100:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/11/2100:21 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/11/2100:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/11/2100:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/11/2100:21 7439-92-1 Nickel 8.6 ug/L 5.0 3.5 1 01/09/21 02:10 01/11/21 00:21 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/11/2100:21 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/11/2100:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/11/2100:21 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.052J ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:31 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 01/05/21 22:50 67-64-1 0.90 1 01/05/21 22:50 107-13-1 0.15 1 01/05/21 22:50 71-43-2 0.34 1 01/05/21 22:50 74-97-5 0.26 1 01/05/21 22:50 75-27-4 0.62 1 01/05/21 22:50 75-25-2 0.62 1 01/05/21 22:50 74-83-9 3.3 1 01/05/21 22:50 78-93-3 0.40 1 01/05/21 22:50 75-15-0 0.22 1 01/05/21 22:50 56-23-5 0.23 1 01/05/21 22:50 108-90-7 0.49 1 01/05/21 22:50 75-00-3 2.3 1 01/05/21 22:50 67-66-3 0.39 1 01/05/21 22:50 74-87-3 0.26 1 01/05/21 22:50 96-12-8 0.41 1 01/05/21 22:50 124-48-1 0.26 1 01/05/21 22:50 106-93-4 0.46 1 01/05/21 22:50 74-95-3 0.29 1 01/05/21 22:50 95-50-1 0.26 1 01/05/21 22:50 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 89 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-27 Lab ID: 92514193037 Collected: 12/30/20 14:47 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 01/05/2122:50 110-57-6 ND ug/L 1.0 0.27 1 01/05/2122:50 75-34-3 ND ug/L 1.0 0.34 1 01/05/2122:50 107-06-2 ND ug/L 1.0 0.24 1 01/05/2122:50 75-35-4 14.2 ug/L 1.0 0.29 1 01/05/2122:50 156-59-2 ND ug/L 1.0 0.25 1 01/05/2122:50 156-60-5 ND ug/L 1.0 0.19 1 01/05/2122:50 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 22:50 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 22:50 10061-02-6 ND ug/L 150 56.2 1 01/05/2122:50 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 22:50 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 22:50 591-78-6 ND ug/L 20.0 12.5 1 01/05/2122:50 74-88-4 ND ug/L 5.0 3.7 1 01/05/2122:50 75-09-2 ND ug/L 5.0 4.5 1 01/05/2122:50 108-10-1 ND ug/L 1.0 0.27 1 01/05/2122:50 100-42-5 ND ug/L 1.0 0.34 1 01/05/2122:50 630-20-6 ND ug/L 1.0 0.22 1 01/05/2122:50 79-34-5 ND ug/L 1.0 0.16 1 01/05/2122:50 127-18-4 ND ug/L 1.0 0.24 1 01/05/2122:50 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 22:50 71-55-6 ND ug/L 1.0 0.24 1 01/05/2122:50 79-00-5 ND ug/L 1.0 0.22 1 01 /05/21 22:50 79-01-6 ND ug/L 1.0 0.31 1 01/05/2122:50 75-69-4 ND ug/L 1.0 0.35 1 01/05/2122:50 96-18-4 ND ug/L 2.0 1.4 1 01/05/2122:50 108-05-4 ND ug/L 1.0 0.24 1 01 /05/21 22:50 75-01-4 ND ug/L 1.0 0.63 1 01/05/2122:50 1330-20-7 98 % 70-130 1 01/05/2122:50 460-00-4 107 % 70-130 1 01/05/2122:50 17060-07-0 104 % 70-130 1 01/05/2122:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 90 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-5 Lab ID: 92514193038 Collected: 12/30/20 13:31 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 6320 ug/L 10.0 3.4 1 01/06/2115:46 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 01/09/2102:10 01/11/2100:24 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:24 7440-38-2 Barium 51.0 ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:24 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 01/09/2102:10 01/11/2100:24 7440-41-7 Cadmium 0.43J ug/L 1.0 0.40 1 01/09/2102:10 01/11/2100:24 7440-43-9 Chromium ND ug/L 5.0 3.7 1 01/09/2102:10 01/11/2100:24 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 01/09/2102:10 01/11/2100:24 7440-48-4 Copper ND ug/L 5.0 4.3 1 01/09/2102:10 01/11/2100:24 7440-50-8 Lead ND ug/L 5.0 4.5 1 01/09/2102:10 01/11/2100:24 7439-92-1 Nickel ND ug/L 5.0 3.5 1 01/09/2102:10 01/11/2100:24 7440-02-0 Selenium ND ug/L 10.0 4.7 1 01/09/2102:10 01/11/2100:24 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/09/2102:10 01/11/2100:24 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 01/09/2102:10 01/11/2100:24 7440-62-2 Zinc ND ug/L 10.0 9.5 1 01/09/2102:10 01/11/2100:24 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/12/2021 11:33 AM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 01/09/2102:03 01/12/2101:35 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 2.6 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 0.37J ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.2 ug/L 1.0 6.2 1 01/05/21 22:32 67-64-1 0.90 1 01/05/21 22:32 107-13-1 0.15 1 01/05/21 22:32 71-43-2 0.34 1 01/05/21 22:32 74-97-5 0.26 1 01/05/21 22:32 75-27-4 0.62 1 01/05/21 22:32 75-25-2 0.62 1 01/05/21 22:32 74-83-9 3.3 1 01/05/21 22:32 78-93-3 0.40 1 01/05/21 22:32 75-15-0 0.22 1 01/05/21 22:32 56-23-5 0.23 1 01/05/21 22:32 108-90-7 0.49 1 01/05/21 22:32 75-00-3 2.3 1 01/05/21 22:32 67-66-3 0.39 1 01/05/21 22:32 74-87-3 0.26 1 01/05/21 22:32 96-12-8 0.41 1 01/05/21 22:32 124-48-1 0.26 1 01/05/21 22:32 106-93-4 0.46 1 01/05/21 22:32 74-95-3 0.29 1 01/05/21 22:32 95-50-1 0.26 1 01/05/21 22:32 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 v2 Page 91 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Sample: MW-5 Lab ID: 92514193038 Collected: 12/30/20 13:31 Received: 12/31/20 13:11 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/12/2021 11:33 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 01/05/2122:32 110-57-6 3.0 ug/L 1.0 0.27 1 01/05/2122:32 75-34-3 ND ug/L 1.0 0.34 1 01/05/2122:32 107-06-2 ND ug/L 1.0 0.24 1 01/05/2122:32 75-35-4 10.8 ug/L 1.0 0.29 1 01/05/2122:32 156-59-2 ND ug/L 1.0 0.25 1 01/05/2122:32 156-60-5 0.28J ug/L 1.0 0.19 1 01/05/2122:32 78-87-5 ND ug/L 1.0 0.30 1 01 /05/21 22:32 10061-01-5 ND ug/L 1.0 0.31 1 01 /05/21 22:32 10061-02-6 ND ug/L 150 56.2 1 01/05/2122:32 123-91-1 ND ug/L 1.0 0.26 1 01 /05/21 22:32 100-41-4 ND ug/L 5.0 0.57 1 01 /05/21 22:32 591-78-6 ND ug/L 20.0 12.5 1 01/05/2122:32 74-88-4 ND ug/L 5.0 3.7 1 01/05/2122:32 75-09-2 ND ug/L 5.0 4.5 1 01/05/2122:32 108-10-1 ND ug/L 1.0 0.27 1 01/05/2122:32 100-42-5 ND ug/L 1.0 0.34 1 01/05/2122:32 630-20-6 ND ug/L 1.0 0.22 1 01/05/2122:32 79-34-5 ND ug/L 1.0 0.16 1 01/05/2122:32 127-18-4 ND ug/L 1.0 0.24 1 01/05/2122:32 108-88-3 ND ug/L 1.0 0.18 1 01 /05/21 22:32 71-55-6 ND ug/L 1.0 0.24 1 01/05/2122:32 79-00-5 0.56J ug/L 1.0 0.22 1 01/05/21 22:32 79-01-6 ND ug/L 1.0 0.31 1 01/05/2122:32 75-69-4 ND ug/L 1.0 0.35 1 01/05/2122:32 96-18-4 ND ug/L 2.0 1.4 1 01/05/2122:32 108-05-4 N D ug/L 1.0 0.24 1 01 /05/21 22:32 75-01-4 ND ug/L 1.0 0.63 1 01/05/2122:32 1330-20-7 99 % 70-130 1 01/05/2122:32 460-00-4 107 % 70-130 1 01/05/2122:32 17060-07-0 103 % 70-130 1 01/05/2122:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 92 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590125 Analysis Method: RSK 175 Modified QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007 METHOD BLANK: 3116314 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 10.0 3.4 12/30/2013:56 LABORATORY CONTROL SAMPLE: 3116315 Parameter Units Methane ug/L MATRIX SPIKE SAMPLE: 3122211 Parameter Units Methane ug/L Spike LCS LCS Conc. Result % Rec 396 429 108 92514193005 Spike MS Result Conc. Result 226 396 503 SAMPLE DUPLICATE: 3122210 92514193003 Dup Parameter Units Result Result Methane ug/L 5.2J ND % Rec Limits Qualifiers 70-130 MS % Rec % Rec Limits Qualifiers 70 70-130 Max RPD RPD Qualifiers 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 93 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590991 Analysis Method: RSK 175 Modified QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92514193028,92514193029,92514193030,92514193031,92514193032,92514193033,92514193036, 92514193037,92514193038 METHOD BLANK: 3119973 Matrix: Water Associated Lab Samples: 92514193028,92514193029,92514193030,92514193031,92514193032,92514193033,92514193036, 92514193037,92514193038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 10.0 3.4 01/06/2113:29 LABORATORY CONTROL SAMPLE: 3119974 Parameter Units Methane ug/L MATRIX SPIKE SAMPLE: 3122226 Parameter Units Methane ug/L SAMPLE DUPLICATE: 3122225 Parameter Units Methane ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 396 446 113 70-130 92514193029 Spike MS Result Conc. Result 180 396 517 MS % Rec % Rec Limits Qualifiers 85 70-130 92514193028 Dup Max Result Result RPD RPD Qualifiers ND ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 94 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590686 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193028,92514193029,92514193030,92514193031,92514193032,92514193033,92514193034, 92514193035 METHOD BLANK: 3118484 Matrix: Water Associated Lab Samples: 92514193028,92514193029,92514193030,92514193031,92514193032,92514193033,92514193034, 92514193035 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 01/05/2115:27 LABORATORY CONTROL SAMPLE: 3118485 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.2 88 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3118486 3118487 MS MSD 92514193028 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.16J 2.5 2.5 2.3 2.4 87 88 75-125 1 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 95 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591416 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193002 METHOD BLANK: 3122333 Associated Lab Samples: 92514193002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 01/10/2117:30 Arsenic ug/L ND 10.0 4.7 01/10/2117:30 Barium ug/L ND 5.0 3.5 01/10/2117:30 Beryllium ug/L ND 1.0 0.70 01/10/2117:30 Cadmium ug/L ND 1.0 0.40 01/10/2117:30 Chromium ug/L ND 5.0 3.7 01/10/2117:30 Cobalt ug/L ND 5.0 3.6 01/10/2117:30 Copper ug/L ND 5.0 4.3 01/10/2117:30 Lead ug/L ND 5.0 4.5 01/10/2117:30 Nickel ug/L ND 5.0 3.5 01/10/2117:30 Selenium ug/L ND 10.0 4.7 01/10/2117:30 Silver ug/L ND 5.0 2.5 01/10/2117:30 Vanadium ug/L ND 5.0 3.9 01/10/2117:30 Zinc ug/L ND 10.0 9.5 01/10/2117:30 LABORATORY CONTROL SAMPLE: Parameter 3122334 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 486 97 80-120 Arsenic ug/L 500 473 95 80-120 Barium ug/L 500 479 96 80-120 Beryllium ug/L 500 486 97 80-120 Cadmium ug/L 500 482 96 80-120 Chromium ug/L 500 482 96 80-120 Cobalt ug/L 500 490 98 80-120 Copper ug/L 500 497 99 80-120 Lead ug/L 500 481 96 80-120 Nickel ug/L 500 487 97 80-120 Selenium ug/L 500 472 94 80-120 Silver ug/L 250 243 97 80-120 Vanadium ug/L 500 480 96 80-120 Zinc ug/L 500 476 95 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 96 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: ALEXANDER LF-SWS 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3122335 3122336 MS MSD 92514178001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 12.8 500 500 508 516 99 101 75-125 2 20 Arsenic ug/L 17.0 500 500 516 517 100 100 75-125 0 20 Barium ug/L 471 500 500 944 963 94 98 75-125 2 20 Beryllium ug/L ND 500 500 495 500 99 100 75-125 1 20 Cadmium ug/L ND 500 500 493 500 98 100 75-125 2 20 Chromium ug/L 24.4 500 500 506 512 96 98 75-125 1 20 Cobalt ug/L 11.6 500 500 482 490 94 96 75-125 1 20 Copper ug/L 5.5 500 500 514 522 102 103 75-125 2 20 Lead ug/L ND 500 500 460 466 92 93 75-125 1 20 Nickel ug/L 57.3 500 500 515 524 92 93 75-125 2 20 Selenium ug/L ND 500 500 484 498 97 100 75-125 3 20 Silver ug/L ND 250 250 254 258 101 102 75-125 2 20 Vanadium ug/L 6.8 500 500 499 507 98 100 75-125 2 20 Zinc ug/L 12.7 500 500 483 489 94 95 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 97 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591417 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008, 92514193009,92514193010,92514193011,92514193012,92514193013,92514193014,92514193015, 92514193016,92514193017,92514193018,92514193019,92514193020,92514193021 METHOD BLANK: 3122337 Matrix: Water Associated Lab Samples: 92514193001, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008, 92514193009,92514193010,92514193011,92514193012,92514193013,92514193014,92514193015, 92514193016,92514193017,92514193018,92514193019,92514193020,92514193021 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 01/11/2102:24 Arsenic ug/L ND 10.0 4.7 01/11/2102:24 Barium ug/L ND 5.0 3.5 01/11/2102:24 Beryllium ug/L ND 1.0 0.70 01/11/2102:24 Cadmium ug/L ND 1.0 0.40 01/11/2102:24 Chromium ug/L ND 5.0 3.7 01/11/2102:24 Cobalt ug/L ND 5.0 3.6 01/11/2102:24 Copper ug/L ND 5.0 4.3 01/11/2102:24 Lead ug/L ND 5.0 4.5 01 /11 /21 02:24 Nickel ug/L ND 5.0 3.5 01/11/2102:24 Selenium ug/L ND 10.0 4.7 01/11/2102:24 Silver ug/L ND 5.0 2.5 01/11/2102:24 Vanadium ug/L ND 5.0 3.9 01/11/2102:24 Zinc ug/L ND 10.0 9.5 01/11/2102:24 LABORATORY CONTROL SAMPLE: Parameter 3122338 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 474 95 80-120 Arsenic ug/L 500 470 94 80-120 Barium ug/L 500 491 98 80-120 Beryllium ug/L 500 491 98 80-120 Cadmium ug/L 500 485 97 80-120 Chromium ug/L 500 504 101 80-120 Cobalt ug/L 500 466 93 80-120 Copper ug/L 500 489 98 80-120 Lead ug/L 500 457 91 80-120 Nickel ug/L 500 488 98 80-120 Selenium ug/L 500 457 91 80-120 Silver ug/L 250 242 97 80-120 Vanadium ug/L 500 481 96 80-120 Zinc ug/L 500 462 92 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 98 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: ALEXANDER LF-SWS 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3122339 3122340 MS MSD 92514193003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 449 458 90 92 75-125 2 20 Arsenic ug/L ND 500 500 460 471 92 94 75-125 2 20 Barium ug/L 118 500 500 609 622 98 101 75-125 2 20 Beryllium ug/L ND 500 500 485 494 97 99 75-125 2 20 Cadmium ug/L 0.52J 500 500 481 494 96 99 75-125 3 20 Chromium ug/L 10.5 500 500 516 523 101 102 75-125 1 20 Cobalt ug/L 4AJ 500 500 459 471 91 93 75-125 2 20 Copper ug/L 4.6J 500 500 488 494 97 98 75-125 1 20 Lead ug/L ND 500 500 449 458 90 91 75-125 2 20 Nickel ug/L 6.3 500 500 486 496 96 98 75-125 2 20 Selenium ug/L ND 500 500 476 482 95 96 75-125 1 20 Silver ug/L ND 250 250 245 247 98 99 75-125 1 20 Vanadium ug/L 5.4 500 500 486 491 96 97 75-125 1 20 Zinc ug/L 19.2 500 500 481 491 92 94 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 99 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591658 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193022, 92514193023, 92514193024, 92514193025, 92514193026, 92514193028, 92514193029, 92514193030, 92514193031, 92514193032, 92514193033, 92514193034, 92514193035, 92514193036, 92514193037,92514193038 METHOD BLANK: 3123875 Matrix: Water Associated Lab Samples: 92514193022, 92514193023, 92514193024, 92514193025, 92514193026, 92514193028, 92514193029, 92514193030, 92514193031, 92514193032, 92514193033, 92514193034, 92514193035, 92514193036, 92514193037.92514193038 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Lead ug/L Nickel ug/L Selenium ug/L Silver ug/L Vanadium ug/L Zinc ug/L Blank Result Reporting Limit MDL Analyzed Qualifiers ND 5.0 3.0 01/10/2123:07 ND 10.0 4.7 01/10/2123:07 ND 5.0 3.5 01/10/2123:07 ND 1.0 0.70 01/10/2123:07 ND 1.0 0.40 01/10/2123:07 ND 5.0 3.7 01/10/2123:07 ND 5.0 3.6 01/10/2123:07 ND 5.0 4.3 01/10/2123:07 ND 5.0 4.5 01/10/2123:07 ND 5.0 3.5 01/10/2123:07 ND 10.0 4.7 01/10/2123:07 ND 5.0 2.5 01/10/2123:07 ND 5.0 3.9 01/10/2123:07 ND 10.0 9.5 01/10/2123:07 LABORATORY CONTROL SAMPLE: Parameter 3123876 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 478 96 80-120 Arsenic ug/L 500 468 94 80-120 Barium ug/L 500 498 100 80-120 Beryllium ug/L 500 498 100 80-120 Cadmium ug/L 500 488 98 80-120 Chromium ug/L 500 511 102 80-120 Cobalt ug/L 500 474 95 80-120 Copper ug/L 500 501 100 80-120 Lead ug/L 500 465 93 80-120 Nickel ug/L 500 494 99 80-120 Selenium ug/L 500 466 93 80-120 Silver ug/L 250 248 99 80-120 Vanadium ug/L 500 490 98 80-120 Zinc ug/L 500 469 94 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 100 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: ALEXANDER LF-SWS 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3123877 3123878 MS MSD 92514193022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 491 494 98 99 75-125 0 20 Arsenic ug/L ND 500 500 487 490 97 98 75-125 1 20 Barium ug/L 75.8 500 500 575 579 100 101 75-125 1 20 Beryllium ug/L ND 500 500 503 508 101 102 75-125 1 20 Cadmium ug/L ND 500 500 510 514 102 103 75-125 1 20 Chromium ug/L ND 500 500 522 532 104 106 75-125 2 20 Cobalt ug/L 183 500 500 667 665 97 96 75-125 0 20 Copper ug/L ND 500 500 509 516 101 103 75-125 1 20 Lead ug/L ND 500 500 472 475 94 95 75-125 1 20 Nickel ug/L 4.2J 500 500 507 510 101 101 75-125 1 20 Selenium ug/L ND 500 500 494 494 99 99 75-125 0 20 Silver ug/L ND 250 250 254 260 101 103 75-125 2 20 Vanadium ug/L ND 500 500 494 504 99 101 75-125 2 20 Zinc ug/L ND 500 500 487 488 97 98 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 101 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591106 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009,92514193010 METHOD BLANK: 3120783 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009,92514193010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 01/08/2113:22 LABORATORY CONTROL SAMPLE: 3120784 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3120785 3120786 MS MSD 92514178001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.3 10.6 103 106 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 102 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591418 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193011,92514193012,92514193013,92514193014,92514193015,92514193016,92514193017, 92514193018,92514193019,92514193020,92514193021 METHOD BLANK: 3122341 Matrix: Water Associated Lab Samples: 92514193011,92514193012,92514193013,92514193014,92514193015,92514193016,92514193017, 92514193018,92514193019,92514193020,92514193021 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 01/08/2123:24 LABORATORY CONTROL SAMPLE: 3122342 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3122343 3122344 MS MSD 92514193011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.8 9.6 98 96 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 103 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591660 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193022, 92514193023, 92514193024, 92514193025, 92514193026, 92514193028, 92514193029, 92514193030, 92514193031, 92514193032, 92514193033, 92514193034, 92514193035, 92514193036, 92514193037,92514193038 METHOD BLANK: 3123883 Matrix: Water Associated Lab Samples: 92514193022, 92514193023, 92514193024, 92514193025, 92514193026, 92514193028, 92514193029, 92514193030, 92514193031, 92514193032, 92514193033, 92514193034, 92514193035, 92514193036, 92514193037,92514193038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 01/11/2123:58 LABORATORY CONTROL SAMPLE: 3123884 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.2 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3123885 3123886 MS MSD 92514193023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.6 10.3 106 103 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 104 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590071 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009 METHOD BLANK: 3115952 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/30/20 20:57 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/30/20 20:57 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/30/20 20:57 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/30/20 20:57 1,1-Dichloroethane ug/L ND 1.0 0.27 12/30/20 20:57 1,1-Dichloroethene ug/L ND 1.0 0.24 12/30/20 20:57 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/30/20 20:57 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/30/20 20:57 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/30/20 20:57 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/30/20 20:57 1,2-Dichloroethane ug/L ND 1.0 0.34 12/30/20 20:57 1,2-Dichloropropane ug/L ND 1.0 0.19 12/30/20 20:57 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/30/20 20:57 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/30/20 20:57 2-Butanone (MEK) ug/L ND 5.0 3.3 12/30/20 20:57 2-Hexanone ug/L ND 5.0 0.57 12/30/20 20:57 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/30/20 20:57 Acetone ug/L ND 25.0 6.2 12/30/20 20:57 Acrylonitrile ug/L ND 10.0 0.90 12/30/20 20:57 Benzene ug/L ND 1.0 0.15 12/30/20 20:57 Bromochloromethane ug/L ND 1.0 0.34 12/30/20 20:57 Bromodichloromethane ug/L ND 1.0 0.26 12/30/20 20:57 Bromoform ug/L ND 1.0 0.62 12/30/20 20:57 Bromomethane ug/L ND 2.0 0.62 12/30/20 20:57 Carbon disulfide ug/L ND 2.0 0.40 12/30/20 20:57 Carbon tetrachloride ug/L ND 1.0 0.22 12/30/20 20:57 Chlorobenzene ug/L ND 1.0 0.23 12/30/20 20:57 Chloroethane ug/L ND 1.0 0.49 12/30/20 20:57 Chloroform ug/L ND 5.0 2.3 12/30/20 20:57 Chloromethane ug/L ND 1.0 0.39 12/30/20 20:57 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/30/20 20:57 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/30/20 20:57 Dibromochloromethane ug/L ND 1.0 0.41 12/30/20 20:57 Dibromomethane ug/L ND 1.0 0.46 12/30/20 20:57 Ethylbenzene ug/L ND 1.0 0.26 12/30/20 20:57 lodomethane ug/L ND 20.0 12.5 12/30/20 20:57 v2 Methylene Chloride ug/L ND 5.0 3.7 12/30/20 20:57 Styrene ug/L ND 1.0 0.27 12/30/20 20:57 Tetrachloroethene ug/L ND 1.0 0.16 12/30/20 20:57 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 105 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 METHOD BLANK: 3115952 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 12/30/20 20:57 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/30/20 20:57 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/30/20 20:57 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/30/20 20:57 Trichloroethene ug/L ND 1.0 0.22 12/30/20 20:57 Trichlorofluoromethane ug/L ND 1.0 0.31 12/30/20 20:57 Vinyl acetate ug/L ND 2.0 1.4 12/30/20 20:57 Vinyl chloride ug/L ND 1.0 0.24 12/30/20 20:57 Xylene (Total) ug/L ND 1.0 0.63 12/30/20 20:57 1,2-Dichloroethane-d4 (S) % 108 70-130 12/30/20 20:57 4-Bromofluorobenzene (S) % 99 70-130 12/30/20 20:57 Toluene-d8 (S) % 104 70-130 12/30/20 20:57 LABORATORY CONTROL SAMPLE: Parameter 3115953 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 48.5 97 70-130 1,1,1-Trichloroethane ug/L 50 47.6 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.0 100 70-130 1,1,2-Trichloroethane ug/L 50 49.1 98 70-130 1,1-Dichloroethane ug/L 50 48.6 97 70-130 1,1-Dichloroethene ug/L 50 50.0 100 70-132 1,2,3-Trichloropropane ug/L 50 49.9 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.0 102 70-132 1,2-Dibromoethane (EDB) ug/L 50 48.9 98 70-130 1,2-Dichlorobenzene ug/L 50 50.9 102 70-130 1,2-Dichloroethane ug/L 50 47.6 95 70-130 1,2-Dichloropropane ug/L 50 50.6 101 70-130 1,4-Dichlorobenzene ug/L 50 49.5 99 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1050 105 70-137 2-Butanone (MEK) ug/L 100 103 103 70-133 2-Hexanone ug/L 100 102 102 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 101 101 70-130 Acetone ug/L 100 102 102 70-144 Acrylonitrile ug/L 250 245 98 70-130 Benzene ug/L 50 48.7 97 70-130 Bromochloromethane ug/L 50 49.9 100 70-130 Bromodichloromethane ug/L 50 49.5 99 70-130 Bromoform ug/L 50 50.1 100 70-131 Bromomethane ug/L 50 52.1 104 30-177 Carbon disulfide ug/L 50 49.7 99 70-133 Carbon tetrachloride ug/L 50 48.7 97 70-130 Chlorobenzene ug/L 50 48.4 97 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 106 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 LABORATORY CONTROL SAMPLE: Parameter 3115953 Units Spike Conc. LCS LCS Result % Rec Chloroethane ug/L 50 60.8 Chloroform ug/L 50 48.9 Chloromethane ug/L 50 41.5 cis-1,2-Dichloroethene ug/L 50 48.6 cis-1,3-Dichloropropene ug/L 50 53.8 Dibromochloromethane ug/L 50 50.0 Dibromomethane ug/L 50 50.6 Ethylbenzene ug/L 50 49.4 lodomethane ug/L 100 90.5 Methylene Chloride ug/L 50 45.9 Styrene ug/L 50 51.4 Tetrachloroethene ug/L 50 46.7 Toluene ug/L 50 48.4 trans-1,2-Dichloroethene ug/L 50 49.4 trans- 1,3-Dichloropropene ug/L 50 51.6 trans-1,4-Dichloro-2-butene ug/L 50 59.3 Trichloroethene ug/L 50 49.9 Trichlorofluoromethane ug/L 50 46.2 Vinyl acetate ug/L 100 111 Vinyl chloride ug/L 50 41.0 Xylene (Total) ug/L 150 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 122 46-131 98 70-130 83 49-130 97 70-130 108 70-130 100 70-130 101 70-130 99 70-130 91 47-140 v3 92 68-130 103 70-130 93 70-130 97 70-130 99 70-130 103 70-130 119 25-200 100 70-130 92 61-130 111 70-140 82 59-142 100 70-130 96 70-130 103 70-130 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3115954 MS 92514193003 Spike Parameter Units Result Conc. MSD Spike Conc. 3115955 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.2 20.9 101 105 70-135 3 30 1,1,1-Trichloroethane ug/L ND 20 20 20.6 21.1 103 106 70-148 3 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.0 21.3 100 107 70-131 6 30 1,1,2-Trichloroethane ug/L ND 20 20 20.5 21.1 103 105 70-136 3 30 1,1-Dichloroethane ug/L ND 20 20 20.6 20.9 103 105 70-147 2 30 1,1-Dichloroethene ug/L ND 20 20 20.6 21.1 103 106 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 19.2 20.5 96 103 67-137 7 30 1,2-Dibromo-3- ug/L ND 20 20 20.8 22.2 104 111 69-136 6 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.6 21.5 103 108 70-137 5 30 1,2-Dichlorobenzene ug/L ND 20 20 22.2 21.1 111 105 70-133 5 30 1,2-Dichloroethane ug/L ND 20 20 20.4 21.9 102 109 67-138 7 30 1,2-Dichloropropane ug/L ND 20 20 21.4 21.5 107 107 70-138 0 30 1,4-Dichlorobenzene ug/L ND 20 20 20.9 20.1 105 101 70-133 4 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 414 441 103 110 69-146 6 30 2-Butanone (MEK) ug/L ND 40 40 40.9 45.3 102 113 61-147 10 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 107 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3115954 3115955 MS MSD 92514193003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2-Hexanone ug/L ND 40 40 38.6 41.9 96 105 67-139 8 30 4-Methyl-2-pentanone ug/L ND 40 40 39.0 40.3 98 101 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 40.3 41.7 101 104 55-159 3 30 Acrylonitrile ug/L ND 100 100 99.3 104 99 104 68-140 4 30 Benzene ug/L ND 20 20 21.2 20.9 106 104 67-150 1 30 Bromochloromethane ug/L ND 20 20 22.2 22.3 111 111 70-146 0 30 Bromodichloromethane ug/L ND 20 20 20.3 20.7 101 103 70-138 2 30 Bromoform ug/L ND 20 20 19.9 20.4 99 102 57-138 3 30 Bromomethane ug/L ND 20 20 21.1 21.9 105 109 10-200 4 30 Carbon disulfide ug/L ND 20 20 19.7 19.8 98 99 70-152 1 30 Carbon tetrachloride ug/L ND 20 20 21.4 21.6 107 108 70-147 1 30 Chlorobenzene ug/L ND 20 20 20.3 20.7 102 103 70-137 2 30 Chloroethane ug/L ND 20 20 19.3 19.1 96 96 51-166 1 30 Chloroform ug/L ND 20 20 21.4 21.6 107 108 70-144 1 30 Chloromethane ug/L ND 20 20 17.2 16.9 86 85 24-161 1 30 v3 cis-1,2-Dichloroethene ug/L 0.43J 20 20 20.2 21.4 99 105 67-148 6 30 cis-1,3-Dichloropropene ug/L ND 20 20 20.9 21.8 105 109 70-142 4 30 Dibromochloromethane ug/L ND 20 20 20.7 21.3 103 107 68-138 3 30 Dibromomethane ug/L ND 20 20 21.4 21.8 107 109 70-134 1 30 Ethylbenzene ug/L ND 20 20 20.5 20.7 103 104 68-143 1 30 lodomethane ug/L ND 40 40 48.6 45.7 121 114 20-161 6 30 Methylene Chloride ug/L ND 20 20 19.3 19.6 96 98 64-148 2 30 Styrene ug/L ND 20 20 20.6 21.0 103 105 70-136 2 30 Tetrachloroethene ug/L ND 20 20 19.6 19.8 98 99 70-139 1 30 Toluene ug/L ND 20 20 20.4 20.3 102 102 47-157 0 30 trans-1,2-Dichloroethene ug/L ND 20 20 20.1 21.1 100 105 70-149 5 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.1 21.2 100 106 70-138 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 18.9 20.5 95 102 31-145 8 30 Trichloroethene ug/L ND 20 20 21.6 20.3 108 102 70-149 6 30 Trichlorofluoromethane ug/L ND 20 20 18.1 18.2 90 91 61-154 1 30 Vinyl acetate ug/L ND 40 40 38.8 40.1 97 100 48-156 3 30 Vinyl chloride ug/L ND 20 20 17.6 18.0 88 90 55-172 2 30 v3 Xylene (Total) ug/L ND 60 60 62.3 63.7 104 106 66-145 2 30 1,2-Dichloroethane-d4 (S) % 104 104 70-130 4-Bromofluorobenzene (S) % 99 102 70-130 Toluene-d8 (S) % 100 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 108 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590527 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92514193010,92514193011,92514193012,92514193013,92514193015,92514193016,92514193017, 92514193018,92514193019,92514193020,92514193021,92514193022,92514193028,92514193029, 92514193030,92514193031,92514193033,92514193034 METHOD BLANK: 3117936 Matrix: Water Associated Lab Samples: 92514193010,92514193011,92514193012,92514193013,92514193015,92514193016,92514193017, 92514193018,92514193019,92514193020,92514193021,92514193022,92514193028,92514193029, 92514193030,92514193031,92514193033,92514193034 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 01/04/21 11:12 1,1,1-Trichloroethane ug/L ND 1.0 0.18 01/04/21 11:12 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 01/04/21 11:12 1,1,2-Trichloroethane ug/L ND 1.0 0.24 01/04/21 11:12 1,1-Dichloroethane ug/L ND 1.0 0.27 01/04/21 11:12 1,1-Dichloroethene ug/L ND 1.0 0.24 01/04/21 11:12 1,2,3-Trichloropropane ug/L ND 1.0 0.35 01/04/21 11:12 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 01/04/21 11:12 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 01/04/21 11:12 1,2-Dichlorobenzene ug/L ND 1.0 0.29 01/04/21 11:12 1,2-Dichloroethane ug/L ND 1.0 0.34 01/04/21 11:12 1,2-Dichloropropane ug/L ND 1.0 0.19 01/04/21 11:12 1,4-Dichlorobenzene ug/L ND 1.0 0.26 01/04/21 11:12 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 01/04/21 11:12 2-Butanone (MEK) ug/L ND 5.0 3.3 01/04/21 11:12 2-Hexanone ug/L ND 5.0 0.57 01/04/21 11:12 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 01/04/21 11:12 Acetone ug/L ND 25.0 6.2 01/04/21 11:12 Acrylonitrile ug/L ND 10.0 0.90 01/04/21 11:12 Benzene ug/L ND 1.0 0.15 01/04/21 11:12 Bromochloromethane ug/L ND 1.0 0.34 01/04/21 11:12 Bromodichloromethane ug/L ND 1.0 0.26 01/04/21 11:12 Bromoform ug/L ND 1.0 0.62 01/04/21 11:12 Bromomethane ug/L ND 2.0 0.62 01/04/21 11:12 Carbon disulfide ug/L ND 2.0 0.40 01/04/21 11:12 Carbon tetrachloride ug/L ND 1.0 0.22 01/04/21 11:12 Chlorobenzene ug/L ND 1.0 0.23 01/04/21 11:12 Chloroethane ug/L ND 1.0 0.49 01/04/21 11:12 Chloroform ug/L ND 5.0 2.3 01/04/21 11:12 Chloromethane ug/L ND 1.0 0.39 01/04/21 11:12 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 01/04/21 11:12 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 01/04/21 11:12 Dibromochloromethane ug/L ND 1.0 0.41 01/04/21 11:12 Dibromomethane ug/L ND 1.0 0.46 01/04/21 11:12 Ethylbenzene ug/L ND 1.0 0.26 01/04/21 11:12 lodomethane ug/L ND 20.0 12.5 01/04/21 11:12 Methylene Chloride ug/L ND 5.0 3.7 01/04/21 11:12 13 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 109 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 METHOD BLANK: 3117936 Matrix: Water Associated Lab Samples: 92514193010,92514193011,92514193012,92514193013,92514193015,92514193016,92514193017, 92514193018,92514193019,92514193020,92514193021,92514193022,92514193028,92514193029, 92514193030,92514193031,92514193033,92514193034 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Styrene ug/L ND 1.0 0.27 01/04/21 11:12 Tetrachloroethene ug/L ND 1.0 0.16 01/04/21 11:12 Toluene ug/L ND 1.0 0.24 01/04/21 11:12 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 01/04/21 11:12 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 01/04/21 11:12 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 01/04/21 11:12 v1 Trichloroethene ug/L ND 1.0 0.22 01/04/21 11:12 Trichlorofluoromethane ug/L ND 1.0 0.31 01/04/21 11:12 Vinyl acetate ug/L ND 2.0 1.4 01/04/21 11:12 Vinyl chloride ug/L ND 1.0 0.24 01/04/21 11:12 Xylene (Total) ug/L ND 1.0 0.63 01/04/21 11:12 1,2-Dichloroethane-d4 (S) % 117 70-130 01/04/21 11:12 4-Bromofluorobenzene (S) % 101 70-130 01/04/21 11:12 Toluene-d8 (S) % 101 70-130 01/04/21 11:12 LABORATORY CONTROL SAMPLE: Parameter 3117937 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.3 101 70-130 1,1,1-Trichloroethane ug/L 50 50.5 101 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.3 97 70-130 1,1,2-Trichloroethane ug/L 50 48.1 96 70-130 1,1-Dichloroethane ug/L 50 48.5 97 70-130 1,1-Dichloroethene ug/L 50 51.2 102 70-132 1,2,3-Trichloropropane ug/L 50 49.5 99 70-130 1,2-Dibromo-3-chloropropane ug/L 50 58.5 117 70-132 1,2-Dibromoethane (EDB) ug/L 50 50.4 101 70-130 1,2-Dichlorobenzene ug/L 50 49.8 100 70-130 1,2-Dichloroethane ug/L 50 51.1 102 70-130 1,2-Dichloropropane ug/L 50 47.8 96 70-130 1,4-Dichlorobenzene ug/L 50 48.3 97 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1120 112 70-137 2-Butanone (MEK) ug/L 100 110 110 70-133 2-Hexanone ug/L 100 113 113 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 105 105 70-130 Acetone ug/L 100 123 123 70-144 Acrylonitrile ug/L 250 268 107 70-130 Benzene ug/L 50 46.0 92 70-130 Bromochloromethane ug/L 50 53.7 107 70-130 Bromodichloromethane ug/L 50 49.0 98 70-130 Bromoform ug/L 50 50.9 102 70-131 Bromomethane ug/L 50 57.3 115 30-177lK Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 110 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 LABORATORY CONTROL SAMPLE: 3117937 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Carbon disulfide ug/L 50 50.4 101 70-133 Carbon tetrachloride ug/L 50 49.3 99 70-130 Chlorobenzene ug/L 50 46.3 93 70-130 Chloroethane ug/L 50 44.9 90 46-131 Chloroform ug/L 50 51.6 103 70-130 Chloromethane ug/L 50 45.6 91 49-130 cis-1,2-Dichloroethene ug/L 50 48.5 97 70-130 cis-1,3-Dichloropropene ug/L 50 52.5 105 70-130 Dibromochloromethane ug/L 50 52.9 106 70-130 Dibromomethane ug/L 50 51.5 103 70-130 Ethylbenzene ug/L 50 45.6 91 70-130 lodomethane ug/L 100 99.6 100 47-140 Methylene Chloride ug/L 50 47.3 95 68-130 Styrene ug/L 50 46.0 92 70-130 Tetrachloroethene ug/L 50 44.2 88 70-130 Toluene ug/L 50 47.5 95 70-130 trans-1,2-Dichloroethene ug/L 50 49.2 98 70-130 trans- 1,3-Dichloropropene ug/L 50 55.1 110 70-130 trans-1,4-Dichloro-2-butene ug/L 50 77.0 154 25-200 v1 Trichloroethene ug/L 50 45.9 92 70-130 Trichlorofluoromethane ug/L 50 46.3 93 61-130 Vinyl acetate ug/L 100 118 118 70-140 Vinyl chloride ug/L 50 41.8 84 59-142 Xylene (Total) ug/L 150 141 94 70-130 1,2-Dichloroethane-d4 (S) % 115 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117938 3117939 MS MSD 92514193012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.2 21.8 111 109 70-135 2 30 1,1,1-Trichloroethane ug/L ND 20 20 23.6 21.8 118 109 70-148 8 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.2 22.3 116 112 70-131 4 30 1,1,2-Trichloroethane ug/L ND 20 20 23.2 21.9 116 110 70-136 6 30 1,1-Dichloroethane ug/L ND 20 20 23.9 23.2 119 116 70-147 3 30 1,1-Dichloroethene ug/L ND 20 20 25.1 24.1 125 121 70-158 4 30 1,2,3-Trichloropropane ug/L ND 20 20 21.6 22.0 108 110 67-137 2 30 1,2-Dibromo-3- ug/L ND 20 20 24.8 24.9 124 124 69-136 0 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 22.9 22.5 114 113 70-137 1 30 1,2-Dichlorobenzene ug/L ND 20 20 24.3 22.4 121 112 70-133 8 30 1,2-Dichloroethane ug/L ND 20 20 21.0 19.8 105 99 67-138 6 30 1,2-Dichloropropane ug/L ND 20 20 24.5 24.5 123 122 70-138 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 111 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117938 3117939 MS MSD 92514193012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dichlorobenzene ug/L ND 20 20 23.2 22.7 116 113 70-133 2 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 437 427 109 107 69-146 2 30 2-Butanone (MEK) ug/L ND 40 40 49.1 47.5 123 119 61-147 3 30 2-Hexanone ug/L ND 40 40 47.0 46.2 117 116 67-139 2 30 4-Methyl-2-pentanone ug/L ND 40 40 46.7 46.1 117 115 67-136 1 30 (MIBK) Acetone ug/L ND 40 40 42.8 43.1 107 108 55-159 1 30 Acrylonitrile ug/L ND 100 100 121 124 121 124 68-140 3 30 Benzene ug/L ND 20 20 23.9 23.7 120 118 67-150 1 30 Bromochloromethane ug/L ND 20 20 23.9 22.8 119 114 70-146 5 30 Bromodichloromethane ug/L ND 20 20 23.0 22.1 115 110 70-138 4 30 Bromoform ug/L ND 20 20 22.1 21.5 111 108 57-138 3 30 Bromomethane ug/L ND 20 20 19.5 18.1 98 91 10-200 7 30 Carbon disulfide ug/L ND 20 20 26.2 25.1 131 125 70-152 4 30 Carbon tetrachloride ug/L ND 20 20 21.7 20.9 109 104 70-147 4 30 Chlorobenzene ug/L ND 20 20 23.9 24.1 119 121 70-137 1 30 Chloroethane ug/L ND 20 20 19.9 18.7 99 93 51-166 6 30 Chloroform ug/L ND 20 20 22.7 22.1 114 110 70-144 3 30 Chloromethane ug/L ND 20 20 21.2 20.1 106 101 24-161 5 30 cis-1,2-Dichloroethene ug/L ND 20 20 24.4 24.4 122 122 67-148 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.4 22.5 117 113 70-142 4 30 Dibromochloromethane ug/L ND 20 20 22.8 22.0 114 110 68-138 4 30 Dibromomethane ug/L ND 20 20 22.8 21.7 114 108 70-134 5 30 Ethylbenzene ug/L ND 20 20 23.4 22.8 117 114 68-143 3 30 lodomethane ug/L ND 40 40 39.4 39.8 99 99 20-161 1 30 Methylene Chloride ug/L ND 20 20 24.0 22.8 120 114 64-148 5 30 Styrene ug/L ND 20 20 23.8 23.6 119 118 70-136 1 30 Tetrachloroethene ug/L ND 20 20 22.7 23.0 113 115 70-139 2 30 Toluene ug/L ND 20 20 24.2 23.2 121 116 47-157 4 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.8 23.4 119 117 70-149 2 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.7 22.8 118 114 70-138 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 20.5 19.6 102 98 31-145 4 30 Trichloroethene ug/L ND 20 20 25.4 25.2 127 126 70-149 1 30 Trichlorofluoromethane ug/L ND 20 20 18.7 18.1 93 90 61-154 3 30 Vinyl acetate ug/L ND 40 40 51.1 48.1 128 120 48-156 6 30 IH Vinyl chloride ug/L ND 20 20 20.9 20.2 105 101 55-172 4 30 Xylene (Total) ug/L ND 60 60 69.9 68.8 116 115 66-145 2 30 1,2-Dichloroethane-d4 (S) % 92 89 70-130 4-Bromofluorobenzene (S) % 98 100 70-130 Toluene-d8 (S) % 101 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 112 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590533 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92514193014,92514193023,92514193024,92514193025,92514193032,92514193035,92514193036, 92514193037,92514193038 METHOD BLANK: 3117961 Matrix: Water Associated Lab Samples: 92514193014,92514193023,92514193024,92514193025,92514193032,92514193035,92514193036, 92514193037,92514193038 Parameter Units Blank Result Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 01/05/21 14:04 1,1,1-Trichloroethane ug/L ND 1.0 0.18 01/05/21 14:04 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 01/05/21 14:04 1,1,2-Trichloroethane ug/L ND 1.0 0.24 01/05/21 14:04 1,1-Dichloroethane ug/L ND 1.0 0.27 01/05/21 14:04 1,1-Dichloroethene ug/L ND 1.0 0.24 01/05/21 14:04 1,2,3-Trichloropropane ug/L ND 1.0 0.35 01/05/21 14:04 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 01/05/21 14:04 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 01/05/21 14:04 1,2-Dichlorobenzene ug/L ND 1.0 0.29 01/05/21 14:04 1,2-Dichloroethane ug/L ND 1.0 0.34 01/05/21 14:04 1,2-Dichloropropane ug/L ND 1.0 0.19 01/05/21 14:04 1,4-Dichlorobenzene ug/L ND 1.0 0.26 01/05/21 14:04 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 01/05/21 14:04 2-Butanone (MEK) ug/L ND 5.0 3.3 01/05/21 14:04 2-Hexanone ug/L ND 5.0 0.57 01/05/21 14:04 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 01/05/21 14:04 Acetone ug/L ND 25.0 6.2 01/05/21 14:04 Acrylonitrile ug/L ND 10.0 0.90 01/05/21 14:04 Benzene ug/L ND 1.0 0.15 01/05/21 14:04 Bromochloromethane ug/L ND 1.0 0.34 01/05/21 14:04 Bromodichloromethane ug/L ND 1.0 0.26 01/05/21 14:04 Bromoform ug/L ND 1.0 0.62 01/05/21 14:04 Bromomethane ug/L ND 2.0 0.62 01/05/21 14:04 Carbon disulfide ug/L ND 2.0 0.40 01/05/21 14:04 Carbon tetrachloride ug/L ND 1.0 0.22 01/05/21 14:04 Chlorobenzene ug/L ND 1.0 0.23 01/05/21 14:04 Chloroethane ug/L ND 1.0 0.49 01/05/21 14:04 Chloroform ug/L ND 5.0 2.3 01/05/21 14:04 Chloromethane ug/L ND 1.0 0.39 01/05/21 14:04 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 01/05/21 14:04 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 01/05/21 14:04 Dibromochloromethane ug/L ND 1.0 0.41 01/05/21 14:04 Dibromomethane ug/L ND 1.0 0.46 01/05/21 14:04 Ethylbenzene ug/L ND 1.0 0.26 01/05/21 14:04 lodomethane ug/L ND 20.0 12.5 01/05/21 14:04 Methylene Chloride ug/L ND 5.0 3.7 01/05/21 14:04 Styrene ug/L ND 1.0 0.27 01/05/21 14:04 Tetrachloroethene ug/L ND 1.0 0.16 01/05/21 14:04 v2 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 113 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 METHOD BLANK: 3117961 Matrix: Water Associated Lab Samples: 92514193014, 92514193023, 92514193024, 92514193025, 92514193032, 92514193035, 92514193036, 92514193037,92514193038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 01/05/21 14:04 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 01/05/21 14:04 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 01/05/21 14:04 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 01/05/21 14:04 Trichloroethene ug/L ND 1.0 0.22 01/05/21 14:04 Trichlorofluoromethane ug/L ND 1.0 0.31 01/05/21 14:04 Vinyl acetate ug/L ND 2.0 1.4 01/05/21 14:04 Vinyl chloride ug/L ND 1.0 0.24 01/05/21 14:04 Xylene (Total) ug/L ND 1.0 0.63 01/05/21 14:04 1,2-Dichloroethane-d4 (S) % 107 70-130 01/05/21 14:04 4-Bromofluorobenzene (S) % 102 70-130 01/05/21 14:04 Toluene-d8 (S) % 103 70-130 01/05/21 14:04 LABORATORY CONTROL SAMPLE: Parameter 3117962 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.4 101 70-130 1,1,1-Trichloroethane ug/L 50 46.3 93 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.3 101 70-130 1,1,2-Trichloroethane ug/L 50 50.5 101 70-130 1,1-Dichloroethane ug/L 50 46.4 93 70-130 1,1-Dichloroethene ug/L 50 45.0 90 70-132 1,2,3-Trichloropropane ug/L 50 50.1 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 56.2 112 70-132 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 70-130 1,2-Dichlorobenzene ug/L 50 53.2 106 70-130 1,2-Dichloroethane ug/L 50 48.1 96 70-130 1,2-Dichloropropane ug/L 50 49.5 99 70-130 1,4-Dichlorobenzene ug/L 50 50.0 100 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1030 103 70-137 2-Butanone (MEK) ug/L 100 97.8 98 70-133 2-Hexanone ug/L 100 99.6 100 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 96.7 97 70-130 Acetone ug/L 100 95.2 95 70-144 Acrylonitrile ug/L 250 235 94 70-130 Benzene ug/L 50 46.7 93 70-130 Bromochloromethane ug/L 50 50.7 101 70-130 Bromodichloromethane ug/L 50 49.5 99 70-130 Bromoform ug/L 50 54.6 109 70-131 Bromomethane ug/L 50 46.4 93 30-177 Carbon disulfide ug/L 50 44.7 89 70-133 v3 Carbon tetrachloride ug/L 50 47.3 95 70-130 Chlorobenzene ug/L 50 49.4 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 114 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 LABORATORY CONTROL SAMPLE: Parameter 3117962 Units Spike Conc. LCS LCS Result % Rec Chloroethane ug/L 50 55.9 Chloroform ug/L 50 47.9 Chloromethane ug/L 50 36.9 cis-1,2-Dichloroethene ug/L 50 47.2 cis-1,3-Dichloropropene ug/L 50 52.4 Dibromochloromethane ug/L 50 54.0 Dibromomethane ug/L 50 52.3 Ethylbenzene ug/L 50 48.6 lodomethane ug/L 100 87.3 Methylene Chloride ug/L 50 43.7 Styrene ug/L 50 52.9 Tetrachloroethene ug/L 50 47.3 Toluene ug/L 50 47.5 trans-1,2-Dichloroethene ug/L 50 46.3 trans- 1,3-Dichloropropene ug/L 50 52.0 trans-1,4-Dichloro-2-butene ug/L 50 52.7 Trichloroethene ug/L 50 49.8 Trichlorofluoromethane ug/L 50 39.6 Vinyl acetate ug/L 100 104 Vinyl chloride ug/L 50 36.6 Xylene (Total) ug/L 150 151 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 112 46-131 96 70-130 74 49-130 v3 94 70-130 105 70-130 108 70-130 105 70-130 97 70-130 87 47-140 87 68-130 106 70-130 95 70-130 95 70-130 93 70-130 104 70-130 105 25-200 100 70-130 79 61-130 104 70-140 73 59-142 101 70-130 93 70-130 99 70-130 97 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117963 MS 92514193014 Spike Parameter Units Result Conc. MSD Spike Conc. 3117964 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.2 20.4 106 102 70-135 4 30 1,1,1-Trichloroethane ug/L ND 20 20 22.2 19.5 111 98 70-148 13 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.8 18.5 109 93 70-131 16 30 1,1,2-Trichloroethane ug/L ND 20 20 22.1 19.8 111 99 70-136 11 30 1,1-Dichloroethane ug/L ND 20 20 22.6 20.1 113 100 70-147 12 30 1,1-Dichloroethene ug/L ND 20 20 23.7 20.1 119 100 70-158 17 30 1,2,3-Trichloropropane ug/L ND 20 20 20.8 18.3 104 91 67-137 13 30 1,2-Dibromo-3- ug/L ND 20 20 21.2 17.4 106 87 69-136 20 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.0 18.8 105 94 70-137 11 30 1,2-Dichlorobenzene ug/L ND 20 20 22.9 19.2 114 96 70-133 18 30 1,2-Dichloroethane ug/L ND 20 20 21.7 18.4 109 92 67-138 16 30 1,2-Dichloropropane ug/L ND 20 20 22.9 19.3 114 97 70-138 17 30 1,4-Dichlorobenzene ug/L ND 20 20 22.3 19.7 111 99 70-133 12 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 354 339 89 85 69-146 5 30 2-Butanone (MEK) ug/L ND 40 40 42.3 35.2 106 88 61-147 18 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 115 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117963 3117964 MS MSD 92514193014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2-Hexanone ug/L ND 40 40 43.2 35.3 108 88 67-139 20 30 4-Methyl-2-pentanone ug/L ND 40 40 43.2 35.3 108 88 67-136 20 30 (MIBK) Acetone ug/L ND 40 40 41.2 34.2 103 85 55-159 19 30 Acrylonitrile ug/L ND 100 100 106 89.7 106 90 68-140 17 30 Benzene ug/L ND 20 20 21.9 19.3 110 96 67-150 13 30 Bromochloromethane ug/L ND 20 20 23.2 19.2 116 96 70-146 19 30 Bromodichloromethane ug/L ND 20 20 21.6 19.5 108 97 70-138 11 30 Bromoform ug/L ND 20 20 21.1 18.5 106 92 57-138 13 30 Bromomethane ug/L ND 20 20 19.2 16.7 96 83 10-200 14 30 Carbon disulfide ug/L ND 20 20 23.4 20.7 117 103 70-152 12 30 Carbon tetrachloride ug/L ND 20 20 22.9 19.8 115 99 70-147 15 30 Chlorobenzene ug/L ND 20 20 22.5 20.2 113 101 70-137 11 30 Chloroethane ug/L ND 20 20 20.2 19.8 101 99 51-166 2 30 Chloroform ug/L ND 20 20 22.6 19.6 113 98 70-144 14 30 Chloromethane ug/L ND 20 20 16.1 14.3 81 71 24-161 12 30 cis-1,2-Dichloroethene ug/L ND 20 20 22.1 18.8 110 94 67-148 16 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.7 19.4 114 97 70-142 16 30 Dibromochloromethane ug/L ND 20 20 22.1 19.2 111 96 68-138 14 30 Dibromomethane ug/L ND 20 20 22.4 19.2 112 96 70-134 16 30 Ethylbenzene ug/L ND 20 20 21.8 19.8 109 99 68-143 10 30 lodomethane ug/L ND 40 40 51.2 47.6 128 119 20-161 7 30 Methylene Chloride ug/L ND 20 20 21.6 18.8 108 94 64-148 14 30 Styrene ug/L ND 20 20 21.3 19.0 107 95 70-136 11 30 Tetrachloroethene ug/L ND 20 20 21.0 20.1 105 100 70-139 4 30 Toluene ug/L ND 20 20 22.5 19.5 112 97 47-157 14 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.8 19.7 114 99 70-149 14 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.3 19.1 111 95 70-138 15 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.1 15.4 86 77 31-145 11 30 Trichloroethene ug/L ND 20 20 23.2 20.3 116 101 70-149 14 30 Trichlorofluoromethane ug/L ND 20 20 19.9 17.8 99 89 61-154 11 30 Vinyl acetate ug/L ND 40 40 45.1 37.1 113 93 48-156 19 30 Vinyl chloride ug/L ND 20 20 18.7 16.0 94 80 55-172 16 30 Xylene (Total) ug/L ND 60 60 65.5 59.8 109 100 66-145 9 30 1,2-Dichloroethane-d4 (S) % 96 95 70-130 4-Bromofluorobenzene (S) % 99 105 70-130 Toluene-d8 (S) % 99 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 116 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590659 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92514193026, 92514193027 METHOD BLANK: 3118391 Associated Lab Samples: 92514193026, 92514193027 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 01/05/21 14:23 1,1,1-Trichloroethane ug/L ND 1.0 0.18 01/05/21 14:23 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 01/05/21 14:23 1,1,2-Trichloroethane ug/L ND 1.0 0.24 01/05/21 14:23 1,1-Dichloroethane ug/L ND 1.0 0.27 01/05/21 14:23 1,1-Dichloroethene ug/L ND 1.0 0.24 01/05/21 14:23 1,2,3-Trichloropropane ug/L ND 1.0 0.35 01/05/21 14:23 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 01/05/21 14:23 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 01/05/21 14:23 1,2-Dichlorobenzene ug/L ND 1.0 0.29 01/05/21 14:23 1,2-Dichloroethane ug/L ND 1.0 0.34 01/05/21 14:23 1,2-Dichloropropane ug/L ND 1.0 0.19 01/05/21 14:23 1,4-Dichlorobenzene ug/L ND 1.0 0.26 01/05/21 14:23 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 01/05/21 14:23 2-Butanone (MEK) ug/L ND 5.0 3.3 01/05/21 14:23 2-Hexanone ug/L ND 5.0 0.57 01/05/21 14:23 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 01/05/21 14:23 Acetone ug/L ND 25.0 6.2 01/05/21 14:23 Acrylonitrile ug/L ND 10.0 0.90 01/05/21 14:23 Benzene ug/L ND 1.0 0.15 01/05/21 14:23 Bromochloromethane ug/L ND 1.0 0.34 01/05/21 14:23 Bromodichloromethane ug/L ND 1.0 0.26 01/05/21 14:23 Bromoform ug/L ND 1.0 0.62 01/05/21 14:23 Bromomethane ug/L ND 2.0 0.62 01/05/21 14:23 Carbon disulfide ug/L ND 2.0 0.40 01/05/21 14:23 v2 Carbon tetrachloride ug/L ND 1.0 0.22 01/05/21 14:23 Chlorobenzene ug/L ND 1.0 0.23 01/05/21 14:23 Chloroethane ug/L ND 1.0 0.49 01/05/21 14:23 Chloroform ug/L ND 5.0 2.3 01/05/21 14:23 Chloromethane ug/L ND 1.0 0.39 01/05/21 14:23 v2 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 01/05/21 14:23 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 01/05/21 14:23 Dibromochloromethane ug/L ND 1.0 0.41 01/05/21 14:23 Dibromomethane ug/L ND 1.0 0.46 01/05/21 14:23 Ethylbenzene ug/L ND 1.0 0.26 01/05/21 14:23 lodomethane ug/L ND 20.0 12.5 01/05/21 14:23 Methylene Chloride ug/L ND 5.0 3.7 01/05/21 14:23 Styrene ug/L ND 1.0 0.27 01/05/21 14:23 Tetrachloroethene ug/L ND 1.0 0.16 01/05/21 14:23 Toluene ug/L ND 1.0 0.24 01/05/21 14:23 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 117 of 150 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 METHOD BLANK: 3118391 Matrix: Water Associated Lab Samples: 92514193026, 92514193027 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 01/05/21 14:23 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 01/05/21 14:23 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 01/05/21 14:23 Trichloroethene ug/L ND 1.0 0.22 01/05/21 14:23 Trichlorofluoromethane ug/L ND 1.0 0.31 01/05/21 14:23 Vinyl acetate ug/L ND 2.0 1.4 01/05/21 14:23 Vinyl chloride ug/L ND 1.0 0.24 01/05/21 14:23 Xylene (Total) ug/L ND 1.0 0.63 01/05/21 14:23 1,2-Dichloroethane-d4 (S) % 109 70-130 01/05/21 14:23 4-Bromofluorobenzene (S) % 96 70-130 01/05/21 14:23 Toluene-d8 (S) % 105 70-130 01/05/21 14:23 LABORATORY CONTROL SAMPLE: 3118392 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.7 105 70-130 1,1,1-Trichloroethane ug/L 50 47.8 96 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.4 101 70-130 1,1,2-Trichloroethane ug/L 50 51.5 103 70-130 1,1-Dichloroethane ug/L 50 47.8 96 70-130 1,1-Dichloroethene ug/L 50 47.4 95 70-132 1,2,3-Trichloropropane ug/L 50 49.9 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.7 107 70-132 1,2-Dibromoethane (EDB) ug/L 50 52.5 105 70-130 1,2-Dichlorobenzene ug/L 50 51.7 103 70-130 1,2-Dichloroethane ug/L 50 47.6 95 70-130 1,2-Dichloropropane ug/L 50 49.4 99 70-130 1,4-Dichlorobenzene ug/L 50 50.2 100 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 1050 105 70-137 2-Butanone (MEK) ug/L 100 98.1 98 70-133 2-Hexanone ug/L 100 100 100 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 98.1 98 70-130 Acetone ug/L 100 96.3 96 70-144 Acrylonitrile ug/L 250 234 93 70-130 Benzene ug/L 50 48.5 97 70-130 Bromochloromethane ug/L 50 52.2 104 70-130 Bromodichloromethane ug/L 50 49.9 100 70-130 Bromoform ug/L 50 56.0 112 70-131 Bromomethane ug/L 50 47.7 95 30-177 Carbon disulfide ug/L 50 46.6 93 70-133 v3 Carbon tetrachloride ug/L 50 49.4 99 70-130 Chlorobenzene ug/L 50 51.2 102 70-130 Chloroethane ug/L 50 57.8 116 46-131 Chloroform ug/L 50 49.1 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 118 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 LABORATORY CONTROL SAMPLE: Parameter 3118392 Units Spike Conc. LCS LCS Result % Rec Chloromethane ug/L 50 38.5 cis-1,2-Dichloroethene ug/L 50 47.3 cis-1,3-Dichloropropene ug/L 50 53.1 Dibromochloromethane ug/L 50 54.9 Dibromomethane ug/L 50 53.7 Ethylbenzene ug/L 50 50.6 lodomethane ug/L 100 94.6 Methylene Chloride ug/L 50 44.3 Styrene ug/L 50 54.3 Tetrachloroethene ug/L 50 50.4 Toluene ug/L 50 49.1 trans-1,2-Dichloroethene ug/L 50 47.0 trans- 1,3-Dichloropropene ug/L 50 52.2 trans-1,4-Dichloro-2-butene ug/L 50 53.4 Trichloroethene ug/L 50 52.0 Trichlorofluoromethane ug/L 50 41.4 Vinyl acetate ug/L 100 104 Vinyl chloride ug/L 50 39.0 Xylene (Total) ug/L 150 154 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % % Rec Limits Qualifiers 77 49-130 v3 95 70-130 106 70-130 110 70-130 107 70-130 101 70-130 95 47-140 89 68-130 109 70-130 101 70-130 98 70-130 94 70-130 104 70-130 107 25-200 104 70-130 83 61-130 104 70-140 78 59-142 103 70-130 90 70-130 101 70-130 97 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3118393 MS 92514373017 Spike Parameter Units Result Conc. MSD Spike Conc. 3118394 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.8 20.8 109 104 70-135 5 30 1,1,1-Trichloroethane ug/L ND 20 20 21.9 21.8 110 109 70-148 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.3 19.4 102 97 70-131 5 30 1,1,2-Trichloroethane ug/L ND 20 20 20.9 20.0 104 100 70-136 4 30 1,1-Dichloroethane ug/L ND 20 20 21.9 21.9 109 110 70-147 0 30 1,1-Dichloroethene ug/L ND 20 20 23.3 22.7 116 113 70-158 3 30 1,2,3-Trichloropropane ug/L ND 20 20 20.7 19.5 104 97 67-137 6 30 1,2-Dibromo-3- ug/L ND 20 20 20.0 19.0 100 95 69-136 5 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.6 20.2 103 101 70-137 2 30 1,2-Dichlorobenzene ug/L ND 20 20 21.1 21.0 105 105 70-133 1 30 1,2-Dichloroethane ug/L ND 20 20 20.4 20.5 102 103 67-138 1 30 1,2-Dichloropropane ug/L ND 20 20 21.6 21.0 108 105 70-138 3 30 1,4-Dichlorobenzene ug/L ND 20 20 21.0 20.8 105 104 70-133 1 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 335 378 84 95 69-146 12 30 2-Butanone (MEK) ug/L ND 40 40 41.3 39.7 103 99 61-147 4 30 2-Hexanone ug/L ND 40 40 40.7 38.7 102 97 67-139 5 30 4-Methyl-2-pentanone ug/L ND 40 40 40.5 38.3 101 96 67-136 6 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 119 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3118393 3118394 MS MSD 92514373017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 39.6 38.8 99 97 55-159 2 30 Acrylonitrile ug/L ND 100 100 100 97.0 100 97 68-140 4 30 Benzene ug/L ND 20 20 21.4 21.0 107 105 67-150 2 30 Bromochloromethane ug/L ND 20 20 22.0 22.0 110 110 70-146 0 30 Bromodichloromethane ug/L ND 20 20 20.7 20.2 104 101 70-138 3 30 Bromoform ug/L ND 20 20 20.2 19.2 101 96 57-138 5 30 Bromomethane ug/L ND 20 20 15.4 17.3 77 86 10-200 12 30 Carbon disulfide ug/L ND 20 20 23.7 22.9 119 115 70-152 3 30 Carbon tetrachloride ug/L ND 20 20 22.1 21.8 111 109 70-147 2 30 Chlorobenzene ug/L ND 20 20 22.3 20.9 112 105 70-137 6 30 Chloroethane ug/L ND 20 20 20.5 22.1 103 111 51-166 7 30 Chloroform ug/L ND 20 20 21.8 20.4 109 102 70-144 7 30 Chloromethane ug/L ND 20 20 15.1 15.5 76 77 24-161 2 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.2 20.9 106 105 67-148 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.0 20.8 110 104 70-142 5 30 Dibromochloromethane ug/L ND 20 20 20.8 19.9 104 100 68-138 4 30 Dibromomethane ug/L ND 20 20 21.9 20.6 109 103 70-134 6 30 Ethylbenzene ug/L ND 20 20 22.0 21.0 110 105 68-143 5 30 lodomethane ug/L ND 40 40 34.3 46.3 86 116 20-161 30 30 Methylene Chloride ug/L ND 20 20 20.9 20.5 104 103 64-148 2 30 Styrene ug/L ND 20 20 22.0 21.7 110 108 70-136 2 30 Tetrachloroethene ug/L ND 20 20 21.1 20.6 106 103 70-139 3 30 Toluene ug/L ND 20 20 21.3 20.8 106 104 47-157 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 22.1 21.4 110 107 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.3 20.6 107 103 70-138 3 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 17.2 14.8 86 74 31-145 15 30 Trichloroethene ug/L ND 20 20 22.0 21.5 110 107 70-149 2 30 Trichlorofluoromethane ug/L ND 20 20 19.3 19.3 97 97 61-154 0 30 Vinyl acetate ug/L ND 40 40 43.2 41.4 108 103 48-156 4 30 Vinyl chloride ug/L ND 20 20 17.6 17.8 88 89 55-172 1 30 Xylene (Total) ug/L ND 60 60 65.7 63.3 110 106 66-145 4 30 1,2-Dichloroethane-d4 (S) % 99 95 70-130 4-Bromofluorobenzene (S) % 101 101 70-130 Toluene-d8 (S) % 98 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 120 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590186 Analysis Method: SM 213OB-2011 QC Batch Method: SM 213OB-2011 Analysis Description: 2130E Turbidity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009 METHOD BLANK: 3116486 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006, 92514193007, 92514193008,92514193009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Turbidity NTU ND 1.0 0.16 12/31/20 05:56 LABORATORY CONTROL SAMPLE: 3116487 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Turbidity NTU 10 10.0 100 90-110 SAMPLE DUPLICATE: 3116488 92514193009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Turbidity NTU 0.24J 0.24J 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 121 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590417 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 METHOD BLANK: 3117467 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 5000 01/04/21 19:16 LABORATORY CONTROL SAMPLE: 3117468 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 54000 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117469 3117470 MS MSD 92514006007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 31.2 mg/L 50000 50000 82500 82300 103 102 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117471 3117472 MS MSD 92513924001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 436 mg/L 50000 50000 485000 472000 99 74 80-120 3 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 122 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590543 Analysis Method: SM 3500-Fe B-2011 QC Batch Method: SM 3500-Fe B-2011 Analysis Description: Iron, Ferrous Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 METHOD BLANK: 3117982 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron, Ferrous mg/L ND 0.50 0.084 01/04/21 18:56 N2 LABORATORY CONTROL SAMPLE: 3117983 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron, Ferrous mg/L 1.5 1.5 102 90-110 N2 SAMPLE DUPLICATE: 3117984 92514193004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Iron, Ferrous mg/L 27.6 26.6 4 10 H3,N2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 123 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590622 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 METHOD BLANK: 3118217 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 01/05/2112:45 LABORATORY CONTROL SAMPLE: 3118218 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 528 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3118219 3118220 MS MSD 92514193001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L 91.3J 500 500 278 278 37 37 80-120 0 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3118225 3118226 MS MSD 35600730004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L 0.089J 500 500 599 599 102 102 80-120 0 10 H3 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 124 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590246 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003 METHOD BLANK: 3116825 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 12/31/2017:25 LABORATORY CONTROL SAMPLE: 3116826 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 48300 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3116827 3116828 MS MSD 92514093002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 139 mg/L 50000 50000 187000 185000 95 91 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3116829 3116830 MS MSD 92513921001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 22.6 mg/L 50000 50000 75500 76500 106 108 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 125 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590361 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193004, 92514193005, 92514193006 METHOD BLANK: 3117323 Matrix: Water Associated Lab Samples: 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 01/02/2111:56 LABORATORY CONTROL SAMPLE: 3117324 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 47100 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117325 3117326 MS MSD 92514193004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 4330 50000 50000 55900 57300 103 106 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 126 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590169 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193004, 92514193005 METHOD BLANK: 3116447 Matrix: Water Associated Lab Samples: 92514193004, 92514193005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 12/31/20 00:02 LABORATORY CONTROL SAMPLE: 3116448 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1540 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3116449 3116450 MS MSD 92514329003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L ND 1500 1500 1500 1500 100 100 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3116451 3116452 MS MSD 92514325005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L ND 1500 1500 1490 1520 99 102 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 127 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590170 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193006 METHOD BLANK: 3116453 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 12/31/20 00:35 LABORATORY CONTROL SAMPLE: 3116454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1500 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3116455 3116456 MS MSD 92514193001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 57.9 1500 1500 943 921 59 58 90-110 2 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3116457 3116458 MS MSD 92514238001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 31.3 mg/L 1500 1500 42700 34400 762 211 90-110 21 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 128 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590828 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 METHOD BLANK: 3119325 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 01/07/2119:51 LABORATORY CONTROL SAMPLE: 3119326 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 20000 20300 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3119339 3119340 MS MSD 92514193003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 16800 10000 10000 27100 27000 103 102 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 129 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591109 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 METHOD BLANK: 3120790 Matrix: Water Associated Lab Samples: 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 01/07/21 07:31 LABORATORY CONTROL SAMPLE: 3120820 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 758000 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3120792 3120793 MS MSD 92513971002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 59.5 mg/L 100000 100000 165000 174000 106 115 90-110 5 3 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3120794 3120795 MS MSD 92513971004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 82.0 mg/L 100000 100000 123000 134000 41 52 90-110 9 3 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 130 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 591110 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001 METHOD BLANK: 3120796 Matrix: Water Associated Lab Samples: 92514193001 Blank Reporting Parameter Units Result Limit Chemical Oxygen Demand ug/L ND 25000 LABORATORY CONTROL SAMPLE: 3120821 Spike LCS Parameter Units Conc. Result Chemical Oxygen Demand ug/L 750000 760000 MDL Analyzed Qualifiers 12500 01 /07/21 07:22 LCS % Rec % Rec Limits Qualifiers 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3120798 3120799 MS MSD 92514311003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 114000 118000 104 108 90-110 4 3 R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3120800 3120801 MS MSD 92514193001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 86500 100000 100000 233000 244000 146 158 90-110 5 3 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 131 of 150 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: ALEXANDER LF-SWS Pace Project No.: 92514193 QC Batch: 590414 Analysis Method: SM 531 OB-2011 QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 METHOD BLANK: 3117453 Matrix: Water Associated Lab Samples: 92514193001, 92514193002, 92514193003, 92514193004, 92514193005, 92514193006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Organic Carbon ug/L ND 1000 500 01/04/21 14:02 LABORATORY CONTROL SAMPLE: 3117454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon ug/L 25000 23900 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3117455 3117456 MS MSD 92514193001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Total Organic Carbon ug/L 11200 25000 25000 34400 35500 93 97 90-110 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 132 of 150 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALIFIERS Project: ALEXANDER LF-SWS Pace Project No.: 92514193 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS C8 Result may be biased high due to carryover from previously analyzed sample. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H3 Sample was received or analysis requested beyond the recognized method holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 133 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92514193001 MW-11 RSK 175 Modified 590125 92514193002 MW-12D RSK 175 Modified 590125 92514193003 MW-24 RSK 175 Modified 590125 92514193004 MW-26 RSK 175 Modified 590125 92514193005 MW-31 RSK 175 Modified 590125 92514193006 MW-12 RSK 175 Modified 590125 92514193007 MW-16 RSK 175 Modified 590125 92514193028 MW-6 RSK 175 Modified 590991 92514193029 MW-17 RSK 175 Modified 590991 92514193030 MW-18 RSK 175 Modified 590991 92514193031 MW-21 RSK 175 Modified 590991 92514193032 MW-1 RSK 175 Modified 590991 92514193033 MWA B RSK 175 Modified 590991 92514193036 MW-25 RSK 175 Modified 590991 92514193037 MW-27 RSK 175 Modified 590991 92514193038 MW-5 RSK 175 Modified 590991 92514193001 MW-11 EPA 3010A 591417 EPA 6010D 591444 92514193002 MW-12D EPA 3010A 591416 EPA 6010D 591430 92514193003 MW-24 EPA 3010A 591417 EPA 6010D 591444 92514193004 MW-26 EPA 3010A 591417 EPA 6010D 591444 92514193005 MW-31 EPA 3010A 591417 EPA 6010D 591444 92514193006 MW-12 EPA 3010A 591417 EPA 6010D 591444 92514193007 MW-16 EPA 3010A 591417 EPA 6010D 591444 92514193008 MW-33 EPA 3010A 591417 EPA 6010D 591444 92514193009 MW-34 EPA 3010A 591417 EPA 6010D 591444 92514193010 MW-10 EPA 3010A 591417 EPA 6010D 591444 92514193011 MW-13 EPA 3010A 591417 EPA 6010D 591444 92514193012 MW-14 EPA 3010A 591417 EPA 6010D 591444 92514193013 MW-19 EPA 3010A 591417 EPA 6010D 591444 92514193014 MW-20 EPA 3010A 591417 EPA 6010D 591444 92514193015 MW-22 EPA 3010A 591417 EPA 6010D 591444 92514193016 MW-23 EPA 3010A 591417 EPA 6010D 591444 92514193017 MW-32 EPA 3010A 591417 EPA 6010D 591444 92514193018 SW-3 EPA 3010A 591417 EPA 6010D 591444 92514193019 SW-4R EPA 3010A 591417 EPA 6010D 591444 92514193020 SW-5 EPA 3010A 591417 EPA 6010D 591444 92514193021 SW-6 EPA 3010A 591417 EPA 6010D 591444 92514193022 MW-4R EPA 3010A 591658 EPA 6010D 591684 92514193023 MW-7 EPA 3010A 591658 EPA 6010D 591684 92514193024 MW-9 EPA 3010A 591658 EPA 6010D 591684 92514193025 MW-3 EPA 3010A 591658 EPA 6010D 591684 92514193026 EB EPA 3010A 591658 EPA 6010D 591684 92514193028 MW-6 EPA 3010A 591658 EPA 6010D 591684 92514193029 MW-17 EPA 3010A 591658 EPA 6010D 591684 92514193030 MW-18 EPA 3010A 591658 EPA 6010D 591684 92514193031 MW-21 EPA 3010A 591658 EPA 6010D 591684 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 134 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92514193032 MW-1 EPA 3010A 591658 EPA 6010D 591684 92514193033 MWA B EPA 3010A 591658 EPA 6010D 591684 92514193034 MW-2 EPA 3010A 591658 EPA 6010D 591684 92514193035 MW-15 EPA 3010A 591658 EPA 6010D 591684 92514193036 MW-25 EPA 3010A 591658 EPA 6010D 591684 92514193037 MW-27 EPA 3010A 591658 EPA 6010D 591684 92514193038 MW-5 EPA 3010A 591658 EPA 6010D 591684 92514193001 MW-11 EPA 3010A 591106 EPA 6020B 591125 92514193002 MW-12D EPA 3010A 591106 EPA 6020B 591125 92514193003 MW-24 EPA 3010A 591106 EPA 6020B 591125 92514193004 MW-26 EPA 3010A 591106 EPA 6020B 591125 92514193005 MW-31 EPA 3010A 591106 EPA 6020B 591125 92514193006 MW-12 EPA 3010A 591106 EPA 6020B 591125 92514193007 MW-16 EPA 3010A 591106 EPA 6020B 591125 92514193008 MW-33 EPA 3010A 591106 EPA 6020B 591125 92514193009 MW-34 EPA 3010A 591106 EPA 6020B 591125 92514193010 MW-10 EPA 3010A 591106 EPA 6020B 591125 92514193011 MW-13 EPA 3010A 591418 EPA 6020B 591429 92514193012 MW-14 EPA 3010A 591418 EPA 6020B 591429 92514193013 MW-19 EPA 3010A 591418 EPA 6020B 591429 92514193014 MW-20 EPA 3010A 591418 EPA 6020B 591429 92514193015 MW-22 EPA 3010A 591418 EPA 6020B 591429 92514193016 MW-23 EPA 3010A 591418 EPA 6020B 591429 92514193017 MW-32 EPA 3010A 591418 EPA 6020B 591429 92514193018 SW-3 EPA 3010A 591418 EPA 6020B 591429 92514193019 SW-4R EPA 3010A 591418 EPA 6020B 591429 92514193020 SW-5 EPA 3010A 591418 EPA 6020B 591429 92514193021 SW-6 EPA 3010A 591418 EPA 6020B 591429 92514193022 MW-4R EPA 3010A 591660 EPA 6020B 591683 92514193023 MW-7 EPA 3010A 591660 EPA 6020B 591683 92514193024 MW-9 EPA 3010A 591660 EPA 6020B 591683 92514193025 MW-3 EPA 3010A 591660 EPA 6020B 591683 92514193026 EB EPA 3010A 591660 EPA 6020B 591683 92514193028 MW-6 EPA 3010A 591660 EPA 6020B 591683 92514193029 MW-17 EPA 3010A 591660 EPA 6020B 591683 92514193030 MW-18 EPA 3010A 591660 EPA 6020B 591683 92514193031 MW-21 EPA 3010A 591660 EPA 6020B 591683 92514193032 MW-1 EPA 3010A 591660 EPA 6020B 591683 92514193033 MWA B EPA 3010A 591660 EPA 6020B 591683 92514193034 MW-2 EPA 3010A 591660 EPA 6020B 591683 92514193035 MW-15 EPA 3010A 591660 EPA 6020B 591683 92514193036 MW-25 EPA 3010A 591660 EPA 6020B 591683 92514193037 MW-27 EPA 3010A 591660 EPA 6020B 591683 92514193038 MW-5 EPA 3010A 591660 EPA 6020B 591683 92514193028 MW-6 EPA 7470A 590686 EPA 7470A 590719 92514193029 MW-17 EPA 7470A 590686 EPA 7470A 590719 92514193030 MW-18 EPA 7470A 590686 EPA 7470A 590719 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Page 135 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92514193031 MW-21 EPA 7470A 590686 EPA 7470A 590719 92514193032 MW-1 EPA 7470A 590686 EPA 7470A 590719 92514193033 MWA B EPA 7470A 590686 EPA 7470A 590719 92514193034 MW-2 EPA 7470A 590686 EPA 7470A 590719 92514193035 MW-15 EPA 7470A 590686 EPA 7470A 590719 92514193001 MW-11 EPA 8260D 590071 92514193002 MW-12D EPA 8260D 590071 92514193003 MW-24 EPA 8260D 590071 92514193004 MW-26 EPA 8260D 590071 92514193005 MW-31 EPA 8260D 590071 92514193006 MW-12 EPA 8260D 590071 92514193007 MW-16 EPA 8260D 590071 92514193008 MW-33 EPA 8260D 590071 92514193009 MW-34 EPA 8260D 590071 92514193010 MW-10 EPA 8260D 590527 92514193011 MW-13 EPA 8260D 590527 92514193012 MW-14 EPA 8260D 590527 92514193013 MW-19 EPA 8260D 590527 92514193014 MW-20 EPA 8260D 590533 92514193015 MW-22 EPA 8260D 590527 92514193016 MW-23 EPA 8260D 590527 92514193017 MW-32 EPA 8260D 590527 92514193018 SW-3 EPA 8260D 590527 92514193019 SW-4R EPA 8260D 590527 92514193020 SW-5 EPA 8260D 590527 92514193021 SW-6 EPA 8260D 590527 92514193022 MW-4R EPA 8260D 590527 92514193023 MW-7 EPA 8260D 590533 92514193024 MW-9 EPA 8260D 590533 92514193025 MW-3 EPA 8260D 590533 92514193026 EB EPA 8260D 590659 92514193027 FB EPA 8260D 590659 92514193028 MW-6 EPA 8260D 590527 92514193029 MW-17 EPA 8260D 590527 92514193030 MW-18 EPA 8260D 590527 92514193031 MW-21 EPA 8260D 590527 92514193032 MW-1 EPA 8260D 590533 92514193033 MW-1 B EPA 8260D 590527 92514193034 MW-2 EPA 8260D 590527 92514193035 MW-15 EPA 8260D 590533 92514193036 MW-25 EPA 8260D 590533 92514193037 MW-27 EPA 8260D 590533 92514193038 MW-5 EPA 8260D 590533 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 136 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: ALEXANDER LF-SWS Pace Project No.: 92514193 Lab ID Sample ID QC Batch Method QC Batch 92514193001 MW-11 SM 2130B-2011 590186 92514193002 MW-12D SM 2130B-2011 590186 92514193003 MW-24 SM 2130B-2011 590186 92514193004 MW-26 SM 2130B-2011 590186 92514193005 MW-31 SM 2130B-2011 590186 92514193006 MW-12 SM 2130B-2011 590186 92514193007 MW-16 SM 2130B-2011 590186 92514193008 MW-33 SM 2130B-2011 590186 92514193009 MW-34 SM 2130B-2011 590186 92514193001 MW-11 SM 2320B-2011 590417 92514193002 MW-12D SM 2320B-2011 590417 92514193003 MW-24 SM 2320B-2011 590417 92514193004 MW-26 SM 2320B-2011 590417 92514193005 MW-31 SM 2320B-2011 590417 92514193006 MW-12 SM 2320B-2011 590417 92514193001 MW-11 SM 3500-Fe B-2011 590543 92514193002 MW-12D SM 3500-Fe B-2011 590543 92514193003 MW-24 SM 3500-Fe B-2011 590543 92514193004 MW-26 SM 3500-Fe B-2011 590543 92514193005 MW-31 SM 3500-Fe B-2011 590543 92514193006 MW-12 SM 3500-Fe B-2011 590543 92514193001 MW-11 SM 4500-S2D-2011 590622 92514193002 MW-12D SM 4500-S2D-2011 590622 92514193003 MW-24 SM 4500-S2D-2011 590622 92514193004 MW-26 SM 4500-S2D-2011 590622 92514193005 MW-31 SM 4500-S2D-2011 590622 92514193006 MW-12 SM 4500-S2D-2011 590622 92514193001 MW-11 EPA 300.0 Rev 2.1 1993 590246 92514193002 MW-12D EPA 300.0 Rev 2.1 1993 590246 92514193003 MW-24 EPA 300.0 Rev 2.1 1993 590246 92514193004 MW-26 EPA 300.0 Rev 2.1 1993 590361 92514193005 MW-31 EPA 300.0 Rev 2.1 1993 590361 92514193006 MW-12 EPA 300.0 Rev 2.1 1993 590361 92514193001 MW-11 EPA 353.2 Rev 2.0 1993 590170 92514193002 MW-12D EPA 353.2 Rev 2.0 1993 590170 92514193003 MW-24 EPA 353.2 Rev 2.0 1993 590170 92514193004 MW-26 EPA 353.2 Rev 2.0 1993 590169 92514193005 MW-31 EPA 353.2 Rev 2.0 1993 590169 92514193006 MW-12 EPA 353.2 Rev 2.0 1993 590170 92514193001 MW-11 SM 4500-CI-E-2011 590828 92514193002 MW-12D SM 4500-CI-E-2011 590828 92514193003 MW-24 SM 4500-CI-E-2011 590828 92514193004 MW-26 SM 4500-CI-E-2011 590828 92514193005 MW-31 SM 4500-CI-E-2011 590828 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /12/2021 11:33 AM without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 137 of 150 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: ALEXANDER LF-SWS 92514193 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92514193006 MW-12 SM 4500-CI-E-2011 590828 92514193001 MW-11 SM 5220D-2011 591110 SM 5220D-2011 591141 92514193002 MW-12D SM 5220D-2011 591109 SM 5220D-2011 591142 92514193003 MW-24 SM 5220D-2011 591109 SM 5220D-2011 591142 92514193004 MW-26 SM 5220D-2011 591109 SM 5220D-2011 591142 92514193005 MW-31 SM 5220D-2011 591109 SM 5220D-2011 591142 92514193006 MW-12 SM 5220D-2011 591109 SM 5220D-2011 591142 92514193001 MW-11 SM 5310B-2011 590414 92514193002 MW-12D SM 5310B-2011 590414 92514193003 MW-24 SM 5310B-2011 590414 92514193004 MW-26 SM 5310B-2011 590414 92514193005 MW-31 SM 5310B-2011 590414 92514193006 MW-12 SM 5310B-2011 590414 Date: 01/12/2021 11:33 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 138 of 150 Document Name: OocumentRevised:October 28, 2020 Sample Condition Upon Receipt[SCURI Page 1 of 2 aceAnalyticalJ Document No.: Issuing Authority: F-CAR-CS-033-RevPace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville� Raleigh[] Mechanicsville[] Atlanta❑ Kernersville❑ SampleClient Name: +,I Upon Project ft: W O# ` QQ J25 1 41 9 V Courier: ❑Fed Ex Dups SIPS ❑Client ❑ Commercial Pace []Other: 9T61A193 Custody Seal Present? Des , j'No seals Intact? Des 19No Date/Initials Person Examining Contents: + � �n '�� �-�-► j Packing Material: []Bubble Wrap ttPubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermorn ter: []Yes []NO -pN/A i !!i Gun to.-92Tab4 Type of Ice: Wet ❑alue ❑None l -+� Corr/Shun: Factor Cooler Temp; Add/Subtract (°C) -0.1 Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples an ice, cooling process Cooler Temp Corrected ('Cl- { . I ISZ] Eras begun USDA Regulated Sail i W/A, water sampie y Did samples originate in a quarantine zone within the United States: CA, NY, or SC (Check maps)? Did samples originate from a foreign source (internationally, FlYes 11N❑ inciudine Hawaii and Puano Riro1) MYas FIN. Comments/DI sere p a n cy: Chain of Custody Present? toyes ❑Na QNJA 1. Samples Arrived within Hold Time? Kyes QNo N/A 2. Short Hold Tlme Anal ysis <72 hr.)? a Yes [ONO ❑N/A 3, Rush Turn Around Time Requested ❑yes i&O ❑N/A 4, Sufficient Volume? 15yes No ❑N/A 5. Correct Containers Used? -Pace Containers Used? -ftes yes ONO CINo tjN/A 0 N/A 6. Container5lntact? Yes QNu ❑N/A 7. Dissolved analysis: Samples field Filtered? ❑yes Flo N/A a. Sample Labels Match COC7 -Includes Date/Time/ID/Analysis Matrix; Oes �� t ❑Na ❑N/A 9, Headspace in VOA Vials (>5-6mm)? Yes tNu ❑NIA 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes Yes ®N❑ Dba ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes ❑No Lot ID of split containers: CLIENT NOTIFICATION/RESOLt1TION I S W iLI I \10 DYl Person contacted: Jt I 0J -V I P gate/Time: Project Manager SCURF Review: i1t n 6 Date: I ,/— y3'o-- -7'0 W Project Manager SRF Review: �M� Date: 1 LU`w- Page 139 of 150 Document !Name: Document Revised: October 28, 2020 Sample Condition Upon Receipt(SCUR) I Page 2 of 2 ��acemalytical' Document No., Issuing Authority: F-CAR-CS-033-Hev.07 I Pace Carolinas Quality Office *Cheek mark top half of box if pH and/or dechlorina#ion is verified and within the acceptance range for preservation samples. Exceptlons: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, tLHg **8ottom half of box is to list number of mottles Project # WO# . J25 14 1 J3 PM: AMB Clue Date- 01/14/21 CLIENT: 92—Municipal A a a Z vv GJ 7 EL E 7 a m ? a a `1 7 u a E 7 m ? ro c, 61 c a E a m v a 4 `m ' 6 co v a N d E LA CO v a 2 y a E Z a m 2 Z 0^ m Z u FL E fJ a m ? �° z E Ll a m a N �_ 3 u W c a m ►i t7 a V v = r/ t7 a a Z ci a o Lm 3 M i7 a v a N = E `m J .-i l7 a v = 2 Q E Ln M t7 ¢ ¢ S Q E o N m Q M U' a a ❑ E = Q1 L7 a 2 a O E T l7 c ¢ D E 41 L'J a v x a D E a O, l7 o Y N x �; a 5 x Q t7 � L7 Y a x a `� 4 ; n E 0. vti G cn E W in {�' -� r= t7i N z m a z t 111 l71 3 r{ 'N� "N� �. 9 �� t �• v; i 10 11 I2 pH Adjustment Log for Preserved Samples Sample Id Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot d adjusted I added Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this Form will he Pent to the Nefth Carolina DEHNR Certification Office i;i.e Out of hold, incorrect preservative, out of temp, incorrect contalners. Page 140 of 150 .,,. ... .. R m '° z rn G) a d a n ITEM # 3 a 3 3 m w n c b m sg �n rn 13 o. C c a t ❑ T N 7, v v n � °a MATRIX CODE (500 valld codes m IeR) SANIPLEnPE (G=GRAB C=COMP) •g Y y m � m W r T N — � m 0 cT � L " rn a Z z S7 ni rn w m m I Z SLz n m � � SAMPLE TEMP AT COLLECTION M m a # of CONTAINERS Unpresemd a a �' o .. HZSGA m x rn r! HNO3 u jm }i HCI ro 4 Naos f ir' Na25203 N f, F� � Methanol Other ,;',AdAIy,Bes Test YIN l N >t x x Yt X x x st ?t 7c x ]X App I VOC App I Metals u� � �• x x x x x x .Y x x x X Y Turbidity x x Alkalinity, Sulfate, Chlofide j I';,T x x Sulfdo I.. x x COD ,,•��, - �-y x x Ferrous Iron, Nitrate x x x. x Mercury x x x x x x MOM no ? I �T1 TEMP in C I I C7 '3 ; Residual Chlorine (YIN) k ri.� .,•'Y' '' Received on i Re 'i A 1. (YIN) I• CuMody y \ Cooler }' _ 01 U s' � V Sa npkes f� Intact .a IYIN1 fi r3o � sa °z o � o O CL C NW a, --I r 0 G ❑ O a 1: r = a1 age 141 of 150 N N N' tv ::'. s 4M N s 0. -• ITEM # n m 3 '�'• v y n01 r90 m � ' r7 � a a •Ak a � m 3 P�� s ' n: i Nv ¢ "C1 4• v r` �+ N m 2 1 as 9 L O �� m 0 �0 MATRIX CODE (aB7 4lNd Wdaa to IaR) l� 1P SAMPLE TYPE (G=GRAB C=COMP) '•'�. Y 3 rn 1 r N y W m O 2 ;U m rn a rn rn en N Q N .A a i a m SAMPLE TEMP AT COLLECTION . IV 4 -a $ 3 C1 a 9 W OF CONTAINERS rYV Llnpreserved r? via 3. 2 o 7 H2SO4 m !? HNO3 HCI @ m o w m Napes Na2S203 {" Melhanol • ::y ' '• Other 0 „i,: ll'IX Analyses Test YIN. x x X x x k x x x St App I VOC 1 ' x X x x Ix x x x N N App I Malals �. r $ x X x x AlkelHly, Sullale, Chloride x x sulrae x x x x TOG Ir r a` x x x x COD �. _ x x x X Ferrous Iran, Nllretaid Mercury i X x x x ac x Methane y m; TEMP In G. Residual Chlorine (YIN)' ceived on Ice (YIN) j � usudy = { Sealed Cooler IN J + Samples M Page 142 of 150 w Sample Condition Upon Receipt(SCUR) Page 1 of 2 y c7C�A�Ir�fytlCc71 Document No.: Issuing Authority: F-CAR-CS•033-Rev.07 Pace Carolinas Quality office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlanta[] Kernersville❑ . SampleC11ent Mama: on I Project win# . 92514193 Courier: ❑Fed Ex -ram❑UPS ❑USPS ❑Client PM. AMB Due Date: 01/14/Z1 ❑ Commercial ❑Pace []Other: CLIENT: 92-Muni e i pa l o Date/Initials Person Examining Contents: .+ ' Packing Material: ]Bubble Wrap ❑Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer: ❑Wet ❑Blue ❑None []YES ❑NO ❑N/A iR Bun lb: 92T664 Type of Ice: Correction Factor: Cooler Temp: Add/Subtract (°C) -0, I Temp should be above freezing to VC ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): hashegun egu lated 5 yr , water samp e Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? aid samplesoriginate from a fare iga source ontematIonaIIV, ❑lYes MNo including Hawaii and Puerto Rico)? FlYes FINo Comments/Discrepancy: Chain of Custody Present? ❑Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? []Yes ❑No ❑N/A 2. Short Hold Time Analysis (472 hr.)? ❑Yes ❑No ❑N/A 3. Rush Turn Around Time kequested? ❑Yes ONO N/A 4. Sufficient Volume? ElYes QN0 []N/A 5.. Correct Containers Used? -Pace Containers Used? Des Elves ONO No ❑N/A UNIA 6. Containers Intact? ElIQs No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ❑N/A 8. Sample Labels Match COC7 -Includes Date/Time/ID/Analysis Matrix: ❑Yes [-]NO ❑N/A 9, Headspace in VOA Vials (>5-6mmi? Dyes ❑No N/A 10. Trip Blank Present? Trip Blan k Custo dy Seals Present? []Yes Yes ❑No ONO ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No CLIENT NOTIFICATION/fiESOLUTION Person contacted: Date/Time; Lot iD of split containers: Project Manager SCURF Review: l�J� Date: Project Manager 5RF Review: f 1 Date: _k Page 143 of 150 Sam ie Condition Upon Recei riCraAnalyticcirt Document No.: PlF•CAR•CS-033-Rev.07 - --Page-2 of 2 Issuing Authority; Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles Project WO# ' 9Z514193 PM: AMB Due Date: 01/14/21 CLIENT: 82-Municipal m 7 c 7 ri 7 a�i e p� = O S rxi x Z n ro d 7 Y = ❑ m ry S Q 2 m �EE d d ry ° p6 ? r& m $ j a ¢ nr x U a w S a m UL VA y a i' a V a my 9 a u a a 1 N a S! y a E ¢ ¢ E a -0 E Q Q E o ni a a ❑ 7 a Q a D a '" n E vn a E V `� r E EN 1 E Ln 1 E �. E N o N E u, N E LA n_ yy 7 w = H m` = .••1 E 0 rM v ti rl E E o N M �J 8 E 7 E P E V E m S w ro 3 .m.. E n .N•, E o N E y0y� fV E 0 0 f��l a ❑ 7 �J VI 2 ril �'r. 7 N a S M 7 s Y % F. W A m a m 6 m 6 m 0. m R m m 0. m 3 a a a a a a a a o 7 go-0. � h R rA a a a 2 ! � 11 a N\N I I \d s ,I l N\\N I 9 \N\it 10N\ \N\ I I Ll H— \d 12 N\,�\N —� �J pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Tlme preservation adjusted Amount of Preservative added Lot o Note: Whenever there is a discrepancy affecting NoFth Carolina compliance samples, a copy or Erns form win oe sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 144 of 150 n r- 'Jarnpie �onnufon upon necespQ.5LUnl nalDocument No.. F-CAR-CS-033•Rev.07 *Check mark top half of box if pH and/or dechlori nation is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Coilfarrn, TOC, Clll and Grease, RRO/8015 (water) DOC, LLdHg "Bottom half of box is to list number of bottles T-i%t t OF Issuing Authority Para r�rnfinac niiality nfficp WO#:92514193 Pal: RM$ Due Date: 01/14/21 CLIENT: 92-Municipal 4. ? z a ¢ a p u ¢ n is b ? v 2 v Y x a m x w ry a 2 z p a °N a a p a mD ¢ a _ Y v x n - v p m a rn Q = z Y ti z N ri ° a 91 v a c a c a r d a n`rtr z a m e a ❑ n ry p E x ,.. ❑ ri 2 a m v LA x d ry x a c r a C x = z N z T S J N 6 6n. G 2 d 40 a u u u Y M a. a a a a a- a E E E a E ¢ ri ❑ ❑ ❑ O a a a ¢ u E J E J E J E eL J E J E J E J E ti ¢ `m ¢ m a `m J E > E > > E 7 E n ; N ° J E J E E J E N E a n H a 3 ,r n ry = M N 17 6 ❑ a a ❑ a t. ++ a N 0 4 p O .Ni m m m 0 m m m m m � a a a a a a ❑ n L7 a ❑ > > owl N 4 7 G 1 2 3 4 5 fi 7 8 9 10 11 12 N :�S: pH Adjustment Log for Preserved Samples Sample I❑ Type of Preservative pR upon receipt Date preservation adjusted Time presereatian Amount of PreservaSive Lot p adjusted added Note: Whenever there is a discrepancy attecting North Carolina compliance samples, a copy or tots Corm wfn ae se4tio the Barth Carolina dEHNR Certification Office (Le. Out of hold, incorrect preservative, out of temp, incorrect containers - Page 145 of 150 adrnple LMIUMvn r,rpvn Me4,erllrtJuln ace�naiytical Document No.: F-CAR-CS-033-Rev.07 "Check mark top half of box if pFI and/or dechbrination is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Cvliform, TOC, Oil and Grease, DROj8015 (water) DOC, I.LHg "Bottom -half of box is to list number of bottles L r drCcuk c Issuing Authority: Pace Carolinas Quality Office WO#:92514193 PM: AMB Due Datot 01/14/21 CLIENT: 92-Municipal p m al d a v "4 v �. ~ ^ a. 2 y 2 n v V 2 Z Y v O Rt rj ? m m v ei m 2 n ro a ° w v u M. 2 " ¢ Y M a z x v D a m a Q a ow N p z x m w ¢ ON ❑ Z m ❑ z m `- N n a y a [ X = z ry Z C ] lJ = z 2 ¢ N a a a 4 a a ro a a ¢ E a E ¢ ,p ni ¢ O O Q Q Q O Q a y r� A ro 0. Wea F E E Q E m E E a E m 'j _m E E E E v J E Q t N aK 6n r4 ❑❑ d ul ry O v? ry N _ — '_ a Ln i7 Q ❑ Q 4 N v❑i N N Q Q ❑ N q d• m 0. @ a CO a m a. rb a. m a M a to a CM¢ ¢ a ¢ Q a Q O W > L7 > O 7 > a N 0. N a R7 Q v7 > l7 0 2 \\NN 4 \ \\\N 5 \ .. .. NN \d \\\ I I . 11 N\ 7 \� - I I \N N \�\\N N I I \N N \NN�s N\ I N\ 10 N \N I NN 11 \ N�s 12 �, _LN PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Arne unt of Preservative Lot # adjusted added Nate: Whenever there is a discrepancy affecting North Carolina Compliance samples, a copy ❑i im1 , rnrrn win 4etent to the North Carolina QEHNR Certification Office (i.e. out of hold, incorrect preservative, out of temp, incorrect containers. Page 146 of 150 4 m m a o C f0 fb V T LTr A W N ITtrm # m m= 3 a m m 3 's w In m a Y n � O IO D7 v O1 N A W Q P m 1 LL p �a�a m [D [A �- rr 0 � m 3?2 � w ❑-. $ M i er 3 G V A K w a N N r v v n A s yy en�4j iAyGPM MATRI%COPE (sae slid codes to left) SAMPLE TYPE (G=GRAB C=COMP) m 1 m • a .. m � n T N t N 4 1 I rn M o r + 5 x x Y Q m c m m m C sn z ° ° a Y ~ o VI a (n 1 g m �- SAMPLE TEMP AT COLLECTION gam+ 4 3 d OF CONTAINERS eA ; 3 a A Unpreserved H2SO4 HNO3 m m HCI 2 Q Y NaOH m Na2$203 ry r) '1 Methanol a Other a Analyses Teat YIN X x Ix x x x Ix Ix 'x x X App I VOC a r X x x x x x 1>1 ?< x x App I Metals m (a 3 3c., • - 5i"r' 9f ;.• X X ., x x. Turbldi?y 10 m r x x Alkalinity, Sulfate, Chloride c x K. Sulfide x x TOC N •�� v.; X COD N Yi Ferrous Iran, Nitrate 5 L� X x x x Mercury f X x X x x Melhane m TEMP in C N Y r= n a ResidualChlorine (YIN) Received an Ice 4 9 (YIN) .. 3 . �' > J r ;,, _ Custody Sealed _ Cooler I 0 (YINI I Ltd I C> ti iA Samples 1 IrIN4 (Y1N) a W 0 Page 147 of 150 x 3 M a O o a w i`v � .. o m ao Gr in a w ITEM # 3 � � N V 1 W N � � ' 1 . N -W+ W [Nn N N W ❑ N N ❑ � HY � � oG � � V1 3 �' N b � L N q2 -2rn m Q x a p R ` NDA omvr�n R c o 4 ^¢ MATRIX CODE (sea valid codas to leaf RO SAMPLETYPE (G=GRAB C-COMP) Y m 18 3 v � y � a _i m 10 y A m n p a °x m d —I m rn n _ C7 m m m 7 A n v a n z Z 9 nu Y m b —C N ❑ T F SAMPLETEMPAT COLLEC=MN y m [ a OF CONTAINERS a m m m a C 3 v -0 JO N m Unpreserved 5® Hxsoa IT x ° 0 ❑ HNO3 # m R y 0 J= _ 1 ' HCI rD 3 fl v $ NaOH D > �— Na2S203 w K rn Methanol f � 11 Z. � other 4 n r. _ Analyses Test YIN co m � � App I VOC < 1 x ?z x x x x x x x x ac x App I Metals .Q LA oc x x x x Turbidity y ?c x x x Alkalinily, Sulfale, Chloride_ ❑ x x x >i sulirde O �n n N x x x k TOC o 1. S - x >i x COD c (� �f aE x x Ferrous Iron, Nitrate ry r^p r* a ! X Mercury n Melhane [ TEMP in C A y Residual Chlorine (YIN) 9 iu Received on �.> i ce'.(YIN) W _ �1 J 0 Cu-9tDdy , --- Sealed l Cooler YIN �1J Samples InlactIL n (YIN) Page 148 of 150 p -U m n ;a H � m. 3�� N ffr A w ro O Ip N as . r.+ ti V T u+ ITEM # � 3 O H N 7 a-- `2`C- a I cn L a V S a. = O �0n M O c tr 0 N m N C 7 N 8 ¢2 f% �or��omao R a O 0 # ro q o a to ❑ v 3 � S� Sa S� `r� $a $a r{ $� r MATRIX CODE [aee valid codas Iv lag) # •� pz SAMPLE TYPE (G=GRAB C=COMP} �t o T � 7 m � m y � � H ro v a Q G1 Z m A g m M m I o m =r n m A IT," m = n a g a m 3 N C5 a m m 71 r I C7 A SAMPLE TEMP AT COLLECTION y #DPDNTAINERS om , a IL C 3 Unpreserved o R $ a . '� _0Q ❑ � m g� � 5 i V m H2SO4 m HNO3 # m G7 r� HCi 0 0 CID "� y } NeDH m C Na28203 w ° K In Methanol m 1 � m i Other a �m y Analyses Test YIN x x x x x k k K x >c ?c x AFA I VOC m a x x ?c ?c x k k x 7a ?c ?c k APP I Metals N k..- 7� -. - x Y. X Turbldily- = ID n y N rt a Alkalinity, Suffate, Chloride 3 Sulfide a c (�} m_ m = — 1 i ~� TOC a COD Ferrous Iran, Nilmto x x x Mercury x x x Methane _ ro v m •2 TEMP �n C m Residual Chlcrfne IYINj Reoaived on Ice a ro Q Cr a m w c. Sealed a — Cooler 0 YIN y ]� (YIN) Page 149 of 150 A 00 N It pi AAA A W N s C N OWO -4 izl:nrl # `n x n y ❑ m 3 /o N 8 m g a 3 a n m ❑ - .. M = B rJ R 9�ju4 A 7l D 2 m z ni '° g o a IN o 1 �n _ MATRIA CODE (sea valid codes to lan) S SAMPLE TYPE (G=GRAB Cy OMP) m y W m U) — 7 n r " N 0 N 5 m x T A z r a n o c w x Y m m m rn x � i i 4 a m SAMPLE 7 EM PAT COLLECTION m rn N . [ v v 'a Y Y a CK CONTAINERS 0 1 v rJ O m 3 VnpreseMd [` rn m m44 H2SO4 HNO3 � m 0 HCl m N v � w NaOH m C 1 ➢ n m m m N82S203 y Methanol Ocher ' °p� a Analyses Test YIN �5 x x AppIVOC x App I Metals a a N 8 M 3 Turbidily C Sulfate, Chloride aAlkalinily, Sulfide TOC Coo Ferrous Iron, Nilrate Mercury C/a Methane 4` 1 A � D LD TEMP in C en g � n R w a N Residual Chlorine (YINy Received an Ice v a a a (YIN) �i Q { n u8o y Sealed ]� Cooler YIN x N Samples Intact (YiN) in a m = 0a 3 a Z o r C c rn ui m ..i n G r � 0a a� m M a ID r N art N 0 g_ v � e4 r4l. m 'm `C Page 150 of 150 Appendix C Statistical Analyses Calculations Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-16) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 36.8 84.83 -48.03 0 1 33.76 84.83 -51.07 0 2 41.36 84.83 -43.47 0 3 35.7 84.83 -49.13 0 4 44.37 84.83 -40.46 0 5 32.61 84.83 -52.22 0 6 42.67 84.83 -42.16 0 7 32.08 84.83 -52.75 0 8 21.71 84.83 -63.12 0 9 17.19 84.83 -67.64 0 10 16.35 84.83 -68.48 0 11 21.87 84.83 -62.96 0 12 13.66 84.83 -71.17 0 13 8.45 84.83 -76.38 0 14 13.51 84.83 -71.32 0 15 8.35 84.83 -76.48 0 16 10.26 84.83 -74.57 0 17 7.2 84.83 -77.63 0 18 2.31 84.83 -82.52 0 19 6.28 84.83 -78.55 0 20 4.84 84.83 -79.99 0 21 3.75 84.83 -81.08 0 22 0.85 84.83 -83.98 0 23 33.76 36.8 -3.04 0 24 41.36 36.8 4.56 1 24 35.7 36.8 -1.1 1 25 44.37 36.8 7.57 2 25 32.61 36.8 -4.19 2 26 42.67 36.8 5.87 3 26 32.08 36.8 -4.72 3 27 21.71 36.8 -15.09 3 28 17.19 36.8 -19.61 3 29 16.35 36.8 -20.45 3 30 21.87 36.8 -14.93 3 31 13.66 36.8 -23.14 3 32 8.45 36.8 -28.35 3 33 13.51 36.8 -23.29 3 34 8.35 36.8 -28.45 3 35 10.26 36.8 -26.54 3 36 7.2 36.8 -29.6 3 37 2.31 36.8 -34.49 3 38 6.28 36.8 -30.52 3 39 4.84 36.8 -31.96 3 40 3.75 36.8 -33.05 3 41 0.85 36.8 -35.95 3 42 41.36 33.76 7.6 4 42 35.7 33.76 1.94 5 42 44.37 33.76 10.61 6 42 32.61 33.76 -1.15 6 43 42.67 33.76 8.91 7 43 32.08 33.76 -1.68 7 44 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 1 Alexander Co CDLF over MSWLF Cumulative VOCs 21.71 33.76 -12.05 7 45 17.19 33.76 -16.57 7 46 16.35 33.76 -17.41 7 47 21.87 33.76 -11.89 7 48 13.66 33.76 -20.1 7 49 8.45 33.76 -25.31 7 50 13.51 33.76 -20.25 7 51 8.35 33.76 -25.41 7 52 10.26 33.76 -23.5 7 53 7.2 33.76 -26.56 7 54 2.31 33.76 -31.45 7 55 6.28 33.76 -27.48 7 56 4.84 33.76 -28.92 7 57 3.75 33.76 -30.01 7 58 0.85 33.76 -32.91 7 59 35.7 41.36 -5.66 7 60 44.37 41.36 3.01 8 60 32.61 41.36 -8.75 8 61 42.67 41.36 1.31 9 61 32.08 41.36 -9.28 9 62 21.71 41.36 -19.65 9 63 17.19 41.36 -24.17 9 64 16.35 41.36 -25.01 9 65 21.87 41.36 -19.49 9 66 13.66 41.36 -27.7 9 67 8.45 41.36 -32.91 9 68 13.51 41.36 -27.85 9 69 8.35 41.36 -33.01 9 70 10.26 41.36 -31.1 9 71 7.2 41.36 -34.16 9 72 2.31 41.36 -39.05 9 73 6.28 41.36 -35.08 9 74 4.84 41.36 -36.52 9 75 3.75 41.36 -37.61 9 76 0.85 41.36 -40.51 9 77 44.37 35.7 8.67 10 77 32.61 35.7 -3.09 10 78 42.67 35.7 6.97 11 78 32.08 35.7 -3.62 11 79 21.71 35.7 -13.99 11 80 17.19 35.7 -18.51 11 81 16.35 35.7 -19.35 11 82 21.87 35.7 -13.83 11 83 13.66 35.7 -22.04 11 84 8.45 35.7 -27.25 11 85 13.51 35.7 -22.19 11 86 8.35 35.7 -27.35 11 87 10.26 35.7 -25.44 11 88 7.2 35.7 -28.5 11 89 2.31 35.7 -33.39 11 90 6.28 35.7 -29.42 11 91 4.84 35.7 -30.86 11 92 3.75 35.7 -31.95 11 93 0.85 35.7 -34.85 11 94 32.61 44.37 -11.76 11 95 42.67 44.37 -1.7 11 96 32.08 44.37 -12.29 11 97 21.71 44.37 -22.66 11 98 17.19 44.37 -27.18 11 99 16.35 44.37 -28.02 11 100 21.87 44.37 -22.5 11 101 13.66 44.37 -30.71 11 102 8.45 44.37 -35.92 11 103 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 2 Alexander Co CDLF over MSWLF Cumulative VOCs 13.51 44.37 -30.86 11 104 8.35 44.37 -36.02 11 105 10.26 44.37 -34.11 11 106 7.2 44.37 -37.17 11 107 2.31 44.37 -42.06 11 108 6.28 44.37 -38.09 11 109 4.84 44.37 -39.53 11 110 3.75 44.37 -40.62 11 111 0.85 44.37 -43.52 11 112 42.67 32.61 10.06 12 112 32.08 32.61 -0.53 12 113 21.71 32.61 -10.9 12 114 17.19 32.61 -15.42 12 115 16.35 32.61 -16.26 12 116 21.87 32.61 -10.74 12 117 13.66 32.61 -18.95 12 118 8.45 32.61 -24.16 12 119 13.51 32.61 -19.1 12 120 8.35 32.61 -24.26 12 121 10.26 32.61 -22.35 12 122 7.2 32.61 -25.41 12 123 2.31 32.61 -30.3 12 124 6.28 32.61 -26.33 12 125 4.84 32.61 -27.77 12 126 3.75 32.61 -28.86 12 127 0.85 32.61 -31.76 12 128 32.08 42.67 -10.59 12 129 21.71 42.67 -20.96 12 130 17.19 42.67 -25.48 12 131 16.35 42.67 -26.32 12 132 21.87 42.67 -20.8 12 133 13.66 42.67 -29.01 12 134 8.45 42.67 -34.22 12 135 13.51 42.67 -29.16 12 136 8.35 42.67 -34.32 12 137 10.26 42.67 -32.41 12 138 7.2 42.67 -35.47 12 139 2.31 42.67 -40.36 12 140 6.28 42.67 -36.39 12 141 4.84 42.67 -37.83 12 142 3.75 42.67 -38.92 12 143 0.85 42.67 -41.82 12 144 21.71 32.08 -10.37 12 145 17.19 32.08 -14.89 12 146 16.35 32.08 -15.73 12 147 21.87 32.08 -10.21 12 148 13.66 32.08 -18.42 12 149 8.45 32.08 -23.63 12 150 13.51 32.08 -18.57 12 151 8.35 32.08 -23.73 12 152 10.26 32.08 -21.82 12 153 7.2 32.08 -24.88 12 154 2.31 32.08 -29.77 12 155 6.28 32.08 -25.8 12 156 4.84 32.08 -27.24 12 157 3.75 32.08 -28.33 12 158 0.85 32.08 -31.23 12 159 17.19 21.71 -4.52 12 160 16.35 21.71 -5.36 12 161 21.87 21.71 0.16 13 161 13.66 21.71 -8.05 13 162 8.45 21.71 -13.26 13 163 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 3 Alexander Co CDLF over MSWLF Cumulative VOCs 13.51 21.71 -8.2 13 164 8.35 21.71 -13.36 13 165 10.26 21.71 -11.45 13 166 7.2 21.71 -14.51 13 167 2.31 21.71 -19.4 13 168 6.28 21.71 -15.43 13 169 4.84 21.71 -16.87 13 170 3.75 21.71 -17.96 13 171 0.85 21.71 -20.86 13 172 16.35 17.19 -0.84 13 173 21.87 17.19 4.68 14 173 13.66 17.19 -3.53 14 174 8.45 17.19 -8.74 14 175 13.51 17.19 -3.68 14 176 8.35 17.19 -8.84 14 177 10.26 17.19 -6.93 14 178 7.2 17.19 -9.99 14 179 2.31 17.19 -14.88 14 180 6.28 17.19 -10.91 14 181 4.84 17.19 -12.35 14 182 3.75 17.19 -13.44 14 183 0.85 17.19 -16.34 14 184 21.87 16.35 5.52 15 184 13.66 16.35 -2.69 15 185 8.45 16.35 -7.9 15 186 13.51 16.35 -2.84 15 187 8.35 16.35 -8 15 188 10.26 16.35 -6.09 15 189 7.2 16.35 -9.15 15 190 2.31 16.35 -14.04 15 191 6.28 16.35 -10.07 15 192 4.84 16.35 -11.51 15 193 3.75 16.35 -12.6 15 194 0.85 16.35 -15.5 15 195 13.66 21.87 -8.21 15 196 8.45 21.87 -13.42 15 197 13.51 21.87 -8.36 15 198 8.35 21.87 -13.52 15 199 10.26 21.87 -11.61 15 200 7.2 21.87 -14.67 15 201 2.31 21.87 -19.56 15 202 6.28 21.87 -15.59 15 203 4.84 21.87 -17.03 15 204 3.75 21.87 -18.12 15 205 0.85 21.87 -21.02 15 206 8.45 13.66 -5.21 15 207 13.51 13.66 -0.15 15 208 8.35 13.66 -5.31 15 209 10.26 13.66 -3.4 15 210 7.2 13.66 -6.46 15 211 2.31 13.66 -11.35 15 212 6.28 13.66 -7.38 15 213 4.84 13.66 -8.82 15 214 3.75 13.66 -9.91 15 215 0.85 13.66 -12.81 15 216 13.51 8.45 5.06 16 216 8.35 8.45 -0.1 16 217 10.26 8.45 1.81 17 217 7.2 8.45 -1.25 17 218 2.31 8.45 -6.14 17 219 6.28 8.45 -2.17 17 220 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 4 Alexander Co CDLF over MSWLF Cumulative VOCs 4.84 8.45 -3.61 17 221 3.75 8.45 -4.7 17 222 0.85 8.45 -7.6 17 223 8.35 13.51 -5.16 17 224 10.26 13.51 -3.25 17 225 7.2 13.51 -6.31 17 226 2.31 13.51 -11.2 17 227 6.28 13.51 -7.23 17 228 4.84 13.51 -8.67 17 229 3.75 13.51 -9.76 17 230 0.85 13.51 -12.66 17 231 10.26 8.35 1.91 18 231 7.2 8.35 -1.15 18 232 2.31 8.35 -6.04 18 233 6.28 8.35 -2.07 18 234 4.84 8.35 -3.51 18 235 3.75 8.35 -4.6 18 236 0.85 8.35 -7.5 18 237 7.2 10.26 -3.06 18 238 2.31 10.26 -7.95 18 239 6.28 10.26 -3.98 18 240 4.84 10.26 -5.42 18 241 3.75 10.26 -6.51 18 242 0.85 10.26 -9.41 18 243 2.31 7.2 -4.89 18 244 6.28 7.2 -0.92 18 245 4.84 7.2 -2.36 18 246 3.75 7.2 -3.45 18 247 0.85 7.2 -6.35 18 248 6.28 2.31 3.97 19 248 4.84 2.31 2.53 20 248 3.75 2.31 1.44 21 248 0.85 2.31 -1.46 21 249 4.84 6.28 -1.44 21 250 3.75 6.28 -2.53 21 251 0.85 6.28 -5.43 21 252 3.75 4.84 -1.09 21 253 0.85 4.84 -3.99 21 254 0.85 3.75 -2.9 21 255 S Statistic = 21 - 255 = -234 Tied GroulValue Members Time Period 6/24/2009 12/15/2009 7/7/2010 12/8/2010 6/28/2011 12/13/2011 6/12/2012 12/10/2012 6/25/2013 12/16/2013 6/24/2014 Observations 1 1 1 1 1 1 1 1 1 1 1 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 5 Alexander Cc CDLF over MSWLF Cumulative VOCs 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 12/29/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 29256 b = 109296 c = 1104 Group Variance = 1625.33 Z-Score=-5.77943 Comparison Level at 95% confidence level =-1.65463 (downward trend) Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 6 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-16) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 58.96 74.55 -15.59 0 1 63.2 74.55 -11.35 0 2 75.84 74.55 1.29 1 2 70.57 74.55 -3.98 1 3 79.21 74.55 4.66 2 3 62.32 74.55 -12.23 2 4 59.16 74.55 -15.39 2 5 69.08 74.55 -5.47 2 6 58.34 74.55 -16.21 2 7 71.17 74.55 -3.38 2 8 89.27 74.55 14.72 3 8 76.95 74.55 2.4 4 8 67.17 74.55 -7.38 4 9 74.17 74.55 -0.38 4 10 72.75 74.55 -1.8 4 11 55.67 74.55 -18.88 4 12 50.36 74.55 -24.19 4 13 58.09 74.55 -16.46 4 14 49.71 74.55 -24.84 4 15 63.46 74.55 -11.09 4 16 56.66 74.55 -17.89 4 17 38.96 74.55 -35.59 4 18 3.76 74.55 -70.79 4 19 63.2 58.96 4.24 5 19 75.84 58.96 16.88 6 19 70.57 58.96 11.61 7 19 79.21 58.96 20.25 8 19 62.32 58.96 3.36 9 19 59.16 58.96 0.2 10 19 69.08 58.96 10.12 11 19 58.34 58.96 -0.62 11 20 71.17 58.96 12.21 12 20 89.27 58.96 30.31 13 20 76.95 58.96 17.99 14 20 67.17 58.96 8.21 15 20 74.17 58.96 15.21 16 20 72.75 58.96 13.79 17 20 55.67 58.96 -3.29 17 21 50.36 58.96 -8.6 17 22 58.09 58.96 -0.87 17 23 49.71 58.96 -9.25 17 24 63.46 58.96 4.5 18 24 56.66 58.96 -2.3 18 25 38.96 58.96 -20 18 26 3.76 58.96 -55.2 18 27 75.84 63.2 12.64 19 27 70.57 63.2 7.37 20 27 79.21 63.2 16.01 21 27 62.32 63.2 -0.88 21 28 59.16 63.2 -4.04 21 29 69.08 63.2 5.88 22 29 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 7 Alexander Co CDLF over MSWLF Cumulative VOCs 58.34 63.2 -4.86 22 30 71.17 63.2 7.97 23 30 89.27 63.2 26.07 24 30 76.95 63.2 13.75 25 30 67.17 63.2 3.97 26 30 74.17 63.2 10.97 27 30 72.75 63.2 9.55 28 30 55.67 63.2 -7.53 28 31 50.36 63.2 -12.84 28 32 58.09 63.2 -5.11 28 33 49.71 63.2 -13.49 28 34 63.46 63.2 0.26 29 34 56.66 63.2 -6.54 29 35 38.96 63.2 -24.24 29 36 3.76 63.2 -59.44 29 37 70.57 75.84 -5.27 29 38 79.21 75.84 3.37 30 38 62.32 75.84 -13.52 30 39 59.16 75.84 -16.68 30 40 69.08 75.84 -6.76 30 41 58.34 75.84 -17.5 30 42 71.17 75.84 -4.67 30 43 89.27 75.84 13.43 31 43 76.95 75.84 1.11 32 43 67.17 75.84 -8.67 32 44 74.17 75.84 -1.67 32 45 72.75 75.84 -3.09 32 46 55.67 75.84 -20.17 32 47 50.36 75.84 -25.48 32 48 58.09 75.84 -17.75 32 49 49.71 75.84 -26.13 32 50 63.46 75.84 -12.38 32 51 56.66 75.84 -19.18 32 52 38.96 75.84 -36.88 32 53 3.76 75.84 -72.08 32 54 79.21 70.57 8.64 33 54 62.32 70.57 -8.25 33 55 59.16 70.57 -11.41 33 56 69.08 70.57 -1.49 33 57 58.34 70.57 -12.23 33 58 71.17 70.57 0.6 34 58 89.27 70.57 18.7 35 58 76.95 70.57 6.38 36 58 67.17 70.57 -3.4 36 59 74.17 70.57 3.6 37 59 72.75 70.57 2.18 38 59 55.67 70.57 -14.9 38 60 50.36 70.57 -20.21 38 61 58.09 70.57 -12.48 38 62 49.71 70.57 -20.86 38 63 63.46 70.57 -7.11 38 64 56.66 70.57 -13.91 38 65 38.96 70.57 -31.61 38 66 3.76 70.57 -66.81 38 67 62.32 79.21 -16.89 38 68 59.16 79.21 -20.05 38 69 69.08 79.21 -10.13 38 70 58.34 79.21 -20.87 38 71 71.17 79.21 -8.04 38 72 89.27 79.21 10.06 39 72 76.95 79.21 -2.26 39 73 67.17 79.21 -12.04 39 74 74.17 79.21 -5.04 39 75 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 8 Alexander Co CDLF over MSWLF Cumulative VOCs 72.75 79.21 -6.46 39 76 55.67 79.21 -23.54 39 77 50.36 79.21 -28.85 39 78 58.09 79.21 -21.12 39 79 49.71 79.21 -29.5 39 80 63.46 79.21 -15.75 39 81 56.66 79.21 -22.55 39 82 38.96 79.21 -40.25 39 83 3.76 79.21 -75.45 39 84 59.16 62.32 -3.16 39 85 69.08 62.32 6.76 40 85 58.34 62.32 -3.98 40 86 71.17 62.32 8.85 41 86 89.27 62.32 26.95 42 86 76.95 62.32 14.63 43 86 67.17 62.32 4.85 44 86 74.17 62.32 11.85 45 86 72.75 62.32 10.43 46 86 55.67 62.32 -6.65 46 87 50.36 62.32 -11.96 46 88 58.09 62.32 -4.23 46 89 49.71 62.32 -12.61 46 90 63.46 62.32 1.14 47 90 56.66 62.32 -5.66 47 91 38.96 62.32 -23.36 47 92 3.76 62.32 -58.56 47 93 69.08 59.16 9.92 48 93 58.34 59.16 -0.82 48 94 71.17 59.16 12.01 49 94 89.27 59.16 30.11 50 94 76.95 59.16 17.79 51 94 67.17 59.16 8.01 52 94 74.17 59.16 15.01 53 94 72.75 59.16 13.59 54 94 55.67 59.16 -3.49 54 95 50.36 59.16 -8.8 54 96 58.09 59.16 -1.07 54 97 49.71 59.16 -9.45 54 98 63.46 59.16 4.3 55 98 56.66 59.16 -2.5 55 99 38.96 59.16 -20.2 55 100 3.76 59.16 -55.4 55 101 58.34 69.08 -10.74 55 102 71.17 69.08 2.09 56 102 89.27 69.08 20.19 57 102 76.95 69.08 7.87 58 102 67.17 69.08 -1.91 58 103 74.17 69.08 5.09 59 103 72.75 69.08 3.67 60 103 55.67 69.08 -13.41 60 104 50.36 69.08 -18.72 60 105 58.09 69.08 -10.99 60 106 49.71 69.08 -19.37 60 107 63.46 69.08 -5.62 60 108 56.66 69.08 -12.42 60 109 38.96 69.08 -30.12 60 110 3.76 69.08 -65.32 60 111 71.17 58.34 12.83 61 111 89.27 58.34 30.93 62 111 76.95 58.34 18.61 63 111 67.17 58.34 8.83 64 111 74.17 58.34 15.83 65 111 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 9 Alexander Co CDLF over MSWLF Cumulative VOCs 72.75 58.34 14.41 66 111 55.67 58.34 -2.67 66 112 50.36 58.34 -7.98 66 113 58.09 58.34 -0.25 66 114 49.71 58.34 -8.63 66 115 63.46 58.34 5.12 67 115 56.66 58.34 -1.68 67 116 38.96 58.34 -19.38 67 117 3.76 58.34 -54.58 67 118 89.27 71.17 18.1 68 118 76.95 71.17 5.78 69 118 67.17 71.17 -4 69 119 74.17 71.17 3 70 119 72.75 71.17 1.58 71 119 55.67 71.17 -15.5 71 120 50.36 71.17 -20.81 71 121 58.09 71.17 -13.08 71 122 49.71 71.17 -21.46 71 123 63.46 71.17 -7.71 71 124 56.66 71.17 -14.51 71 125 38.96 71.17 -32.21 71 126 3.76 71.17 -67.41 71 127 76.95 89.27 -12.32 71 128 67.17 89.27 -22.1 71 129 74.17 89.27 -15.1 71 130 72.75 89.27 -16.52 71 131 55.67 89.27 -33.6 71 132 50.36 89.27 -38.91 71 133 58.09 89.27 -31.18 71 134 49.71 89.27 -39.56 71 135 63.46 89.27 -25.81 71 136 56.66 89.27 -32.61 71 137 38.96 89.27 -50.31 71 138 3.76 89.27 -85.51 71 139 67.17 76.95 -9.78 71 140 74.17 76.95 -2.78 71 141 72.75 76.95 -4.2 71 142 55.67 76.95 -21.28 71 143 50.36 76.95 -26.59 71 144 58.09 76.95 -18.86 71 145 49.71 76.95 -27.24 71 146 63.46 76.95 -13.49 71 147 56.66 76.95 -20.29 71 148 38.96 76.95 -37.99 71 149 3.76 76.95 -73.19 71 150 74.17 67.17 7 72 150 72.75 67.17 5.58 73 150 55.67 67.17 -11.5 73 151 50.36 67.17 -16.81 73 152 58.09 67.17 -9.08 73 153 49.71 67.17 -17.46 73 154 63.46 67.17 -3.71 73 155 56.66 67.17 -10.51 73 156 38.96 67.17 -28.21 73 157 3.76 67.17 -63.41 73 158 72.75 74.17 -1.42 73 159 55.67 74.17 -18.5 73 160 50.36 74.17 -23.81 73 161 58.09 74.17 -16.08 73 162 49.71 74.17 -24.46 73 163 63.46 74.17 -10.71 73 164 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 10 Alexander Co CDLF over MSWLF Cumulative VOCs 56.66 74.17 -17.51 73 165 38.96 74.17 -35.21 73 166 3.76 74.17 -70.41 73 167 55.67 72.75 -17.08 73 168 50.36 72.75 -22.39 73 169 58.09 72.75 -14.66 73 170 49.71 72.75 -23.04 73 171 63.46 72.75 -9.29 73 172 56.66 72.75 -16.09 73 173 38.96 72.75 -33.79 73 174 3.76 72.75 -68.99 73 175 50.36 55.67 -5.31 73 176 58.09 55.67 2.42 74 176 49.71 55.67 -5.96 74 177 63.46 55.67 7.79 75 177 56.66 55.67 0.99 76 177 38.96 55.67 -16.71 76 178 3.76 55.67 -51.91 76 179 58.09 50.36 7.73 77 179 49.71 50.36 -0.65 77 180 63.46 50.36 13.1 78 180 56.66 50.36 6.3 79 180 38.96 50.36 -11.4 79 181 3.76 50.36 -46.6 79 182 49.71 58.09 -8.38 79 183 63.46 58.09 5.37 80 183 56.66 58.09 -1.43 80 184 38.96 58.09 -19.13 80 185 3.76 58.09 -54.33 80 186 63.46 49.71 13.75 81 186 56.66 49.71 6.95 82 186 38.96 49.71 -10.75 82 187 3.76 49.71 -45.95 82 188 56.66 63.46 -6.8 82 189 38.96 63.46 -24.5 82 190 3.76 63.46 -59.7 82 191 38.96 56.66 -17.7 82 192 3.76 56.66 -52.9 82 193 3.76 38.96 -35.2 82 194 S Statistic = 82 - 194 = -112 Tied GroulValue Members Time Period 6/24/2009 12/15/2009 7/7/2010 12/8/2010 6/28/2011 12/13/2011 6/12/2012 12/10/2012 6/25/2013 12/16/2013 6/24/2014 Observations 1 1 1 1 1 1 1 1 1 1 1 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 11 Alexander Cc CDLF over MSWLF Cumulative VOCs 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 12/29/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 29256 b = 109296 c = 1104 Group Variance = 1625.33 Z-Score=-2.75329 Comparison Level at 95% confidence level =-1.65463 (downward trend) Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 12 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-24) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 43 63.53 -20.53 0 1 32.22 63.53 -31.31 0 2 76.57 63.53 13.04 1 2 51.69 63.53 -11.84 1 3 68.44 63.53 4.91 2 3 55.065 63.53 -8.465 2 4 61.89 63.53 -1.64 2 5 58.98 63.53 -4.55 2 6 49.41 63.53 -14.12 2 7 62.79 63.53 -0.74 2 8 54.44 63.53 -9.09 2 9 60.12 63.53 -3.41 2 10 40.99 63.53 -22.54 2 11 32.385 63.53 -31.145 2 12 53.78 63.53 -9.75 2 13 45.88 63.53 -17.65 2 14 42.54 63.53 -20.99 2 15 23.82 63.53 -39.71 2 16 19.82 63.53 -43.71 2 17 17.85 63.53 -45.68 2 18 37.48 63.53 -26.05 2 19 21.58 63.53 -41.95 2 20 4.3 63.53 -59.23 2 21 32.22 43 -10.78 2 22 76.57 43 33.57 3 22 51.69 43 8.69 4 22 68.44 43 25.44 5 22 55.065 43 12.065 6 22 61.89 43 18.89 7 22 58.98 43 15.98 8 22 49.41 43 6.41 9 22 62.79 43 19.79 10 22 54.44 43 11.44 11 22 60.12 43 17.12 12 22 40.99 43 -2.01 12 23 32.385 43 -10.615 12 24 53.78 43 10.78 13 24 45.88 43 2.88 14 24 42.54 43 -0.46 14 25 23.82 43 -19.18 14 26 19.82 43 -23.18 14 27 17.85 43 -25.15 14 28 37.48 43 -5.52 14 29 21.58 43 -21.42 14 30 4.3 43 -38.7 14 31 76.57 32.22 44.35 15 31 51.69 32.22 19.47 16 31 68.44 32.22 36.22 17 31 55.065 32.22 22.845 18 31 61.89 32.22 29.67 19 31 58.98 32.22 26.76 20 31 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 13 Alexander Co CDLF over MSWLF Cumulative VOCs 49.41 32.22 17.19 21 31 62.79 32.22 30.57 22 31 54.44 32.22 22.22 23 31 60.12 32.22 27.9 24 31 40.99 32.22 8.77 25 31 32.385 32.22 0.165 26 31 53.78 32.22 21.56 27 31 45.88 32.22 13.66 28 31 42.54 32.22 10.32 29 31 23.82 32.22 -8.4 29 32 19.82 32.22 -12.4 29 33 17.85 32.22 -14.37 29 34 37.48 32.22 5.26 30 34 21.58 32.22 -10.64 30 35 4.3 32.22 -27.92 30 36 51.69 76.57 -24.88 30 37 68.44 76.57 -8.13 30 38 55.065 76.57 -21.505 30 39 61.89 76.57 -14.68 30 40 58.98 76.57 -17.59 30 41 49.41 76.57 -27.16 30 42 62.79 76.57 -13.78 30 43 54.44 76.57 -22.13 30 44 60.12 76.57 -16.45 30 45 40.99 76.57 -35.58 30 46 32.385 76.57 -44.185 30 47 53.78 76.57 -22.79 30 48 45.88 76.57 -30.69 30 49 42.54 76.57 -34.03 30 50 23.82 76.57 -52.75 30 51 19.82 76.57 -56.75 30 52 17.85 76.57 -58.72 30 53 37.48 76.57 -39.09 30 54 21.58 76.57 -54.99 30 55 4.3 76.57 -72.27 30 56 68.44 51.69 16.75 31 56 55.065 51.69 3.375 32 56 61.89 51.69 10.2 33 56 58.98 51.69 7.29 34 56 49.41 51.69 -2.28 34 57 62.79 51.69 11.1 35 57 54.44 51.69 2.75 36 57 60.12 51.69 8.43 37 57 40.99 51.69 -10.7 37 58 32.385 51.69 -19.305 37 59 53.78 51.69 2.09 38 59 45.88 51.69 -5.81 38 60 42.54 51.69 -9.15 38 61 23.82 51.69 -27.87 38 62 19.82 51.69 -31.87 38 63 17.85 51.69 -33.84 38 64 37.48 51.69 -14.21 38 65 21.58 51.69 -30.11 38 66 4.3 51.69 -47.39 38 67 55.065 68.44 -13.375 38 68 61.89 68.44 -6.55 38 69 58.98 68.44 -9.46 38 70 49.41 68.44 -19.03 38 71 62.79 68.44 -5.65 38 72 54.44 68.44 -14 38 73 60.12 68.44 -8.32 38 74 40.99 68.44 -27.45 38 75 32.385 68.44 -36.055 38 76 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 14 Alexander Co CDLF over MSWLF Cumulative VOCs 53.78 68.44 -14.66 38 77 45.88 68.44 -22.56 38 78 42.54 68.44 -25.9 38 79 23.82 68.44 -44.62 38 80 19.82 68.44 -48.62 38 81 17.85 68.44 -50.59 38 82 37.48 68.44 -30.96 38 83 21.58 68.44 -46.86 38 84 4.3 68.44 -64.14 38 85 61.89 55.065 6.825 39 85 58.98 55.065 3.915 40 85 49.41 55.065 -5.655 40 86 62.79 55.065 7.725 41 86 54.44 55.065 -0.625 41 87 60.12 55.065 5.055 42 87 40.99 55.065 -14.075 42 88 32.385 55.065 -22.68 42 89 53.78 55.065 -1.285 42 90 45.88 55.065 -9.185 42 91 42.54 55.065 -12.525 42 92 23.82 55.065 -31.245 42 93 19.82 55.065 -35.245 42 94 17.85 55.065 -37.215 42 95 37.48 55.065 -17.585 42 96 21.58 55.065 -33.485 42 97 4.3 55.065 -50.765 42 98 58.98 61.89 -2.91 42 99 49.41 61.89 -12.48 42 100 62.79 61.89 0.9 43 100 54.44 61.89 -7.45 43 101 60.12 61.89 -1.77 43 102 40.99 61.89 -20.9 43 103 32.385 61.89 -29.505 43 104 53.78 61.89 -8.11 43 105 45.88 61.89 -16.01 43 106 42.54 61.89 -19.35 43 107 23.82 61.89 -38.07 43 108 19.82 61.89 -42.07 43 109 17.85 61.89 -44.04 43 110 37.48 61.89 -24.41 43 111 21.58 61.89 -40.31 43 112 4.3 61.89 -57.59 43 113 49.41 58.98 -9.57 43 114 62.79 58.98 3.81 44 114 54.44 58.98 -4.54 44 115 60.12 58.98 1.14 45 115 40.99 58.98 -17.99 45 116 32.385 58.98 -26.595 45 117 53.78 58.98 -5.2 45 118 45.88 58.98 -13.1 45 119 42.54 58.98 -16.44 45 120 23.82 58.98 -35.16 45 121 19.82 58.98 -39.16 45 122 17.85 58.98 -41.13 45 123 37.48 58.98 -21.5 45 124 21.58 58.98 -37.4 45 125 4.3 58.98 -54.68 45 126 62.79 49.41 13.38 46 126 54.44 49.41 5.03 47 126 60.12 49.41 10.71 48 126 40.99 49.41 -8.42 48 127 32.385 49.41 -17.025 48 128 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 15 Alexander Co CDLF over MSWLF Cumulative VOCs 53.78 49.41 4.37 49 128 45.88 49.41 -3.53 49 129 42.54 49.41 -6.87 49 130 23.82 49.41 -25.59 49 131 19.82 49.41 -29.59 49 132 17.85 49.41 -31.56 49 133 37.48 49.41 -11.93 49 134 21.58 49.41 -27.83 49 135 4.3 49.41 -45.11 49 136 54.44 62.79 -8.35 49 137 60.12 62.79 -2.67 49 138 40.99 62.79 -21.8 49 139 32.385 62.79 -30.405 49 140 53.78 62.79 -9.01 49 141 45.88 62.79 -16.91 49 142 42.54 62.79 -20.25 49 143 23.82 62.79 -38.97 49 144 19.82 62.79 -42.97 49 145 17.85 62.79 -44.94 49 146 37.48 62.79 -25.31 49 147 21.58 62.79 -41.21 49 148 4.3 62.79 -58.49 49 149 60.12 54.44 5.68 50 149 40.99 54.44 -13.45 50 150 32.385 54.44 -22.055 50 151 53.78 54.44 -0.66 50 152 45.88 54.44 -8.56 50 153 42.54 54.44 -11.9 50 154 23.82 54.44 -30.62 50 155 19.82 54.44 -34.62 50 156 17.85 54.44 -36.59 50 157 37.48 54.44 -16.96 50 158 21.58 54.44 -32.86 50 159 4.3 54.44 -50.14 50 160 40.99 60.12 -19.13 50 161 32.385 60.12 -27.735 50 162 53.78 60.12 -6.34 50 163 45.88 60.12 -14.24 50 164 42.54 60.12 -17.58 50 165 23.82 60.12 -36.3 50 166 19.82 60.12 -40.3 50 167 17.85 60.12 -42.27 50 168 37.48 60.12 -22.64 50 169 21.58 60.12 -38.54 50 170 4.3 60.12 -55.82 50 171 32.385 40.99 -8.605 50 172 53.78 40.99 12.79 51 172 45.88 40.99 4.89 52 172 42.54 40.99 1.55 53 172 23.82 40.99 -17.17 53 173 19.82 40.99 -21.17 53 174 17.85 40.99 -23.14 53 175 37.48 40.99 -3.51 53 176 21.58 40.99 -19.41 53 177 4.3 40.99 -36.69 53 178 53.78 32.385 21.395 54 178 45.88 32.385 13.495 55 178 42.54 32.385 10.155 56 178 23.82 32.385 -8.565 56 179 19.82 32.385 -12.565 56 180 17.85 32.385 -14.535 56 181 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 16 Alexander Co CDLF over MSWLF Cumulative VOCs 37.48 32.385 5.095 57 181 21.58 32.385 -10.805 57 182 4.3 32.385 -28.085 57 183 45.88 53.78 -7.9 57 184 42.54 53.78 -11.24 57 185 23.82 53.78 -29.96 57 186 19.82 53.78 -33.96 57 187 17.85 53.78 -35.93 57 188 37.48 53.78 -16.3 57 189 21.58 53.78 -32.2 57 190 4.3 53.78 -49.48 57 191 42.54 45.88 -3.34 57 192 23.82 45.88 -22.06 57 193 19.82 45.88 -26.06 57 194 17.85 45.88 -28.03 57 195 37.48 45.88 -8.4 57 196 21.58 45.88 -24.3 57 197 4.3 45.88 -41.58 57 198 23.82 42.54 -18.72 57 199 19.82 42.54 -22.72 57 200 17.85 42.54 -24.69 57 201 37.48 42.54 -5.06 57 202 21.58 42.54 -20.96 57 203 4.3 42.54 -38.24 57 204 19.82 23.82 -4 57 205 17.85 23.82 -5.97 57 206 37.48 23.82 13.66 58 206 21.58 23.82 -2.24 58 207 4.3 23.82 -19.52 58 208 17.85 19.82 -1.97 58 209 37.48 19.82 17.66 59 209 21.58 19.82 1.76 60 209 4.3 19.82 -15.52 60 210 37.48 17.85 19.63 61 210 21.58 17.85 3.73 62 210 4.3 17.85 -13.55 62 211 21.58 37.48 -15.9 62 212 4.3 37.48 -33.18 62 213 4.3 21.58 -17.28 62 214 S Statistic = 62 - 214 = -152 Tied GroulValue Members Time Period 6/24/2009 12/15/2009 7/7/2010 12/8/2010 6/28/2011 12/13/2011 6/12/2012 12/10/2012 6/25/2013 12/16/2013 6/24/2014 Observations 1 1 1 1 1 1 1 1 1 1 1 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 17 Alexander Cc CDLF over MSWLF Cumulative VOCs 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 12/29/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 29256 b = 109296 c = 1104 Group Variance = 1625.33 Z-Score =-3.74546 Comparison Level at 95% confidence level =-1.65463 (downward trend) Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 18 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-26) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 129.48 178.04 -48.56 0 1 136.41 178.04 -41.63 0 2 160.84 178.04 -17.2 0 3 137.92 178.04 -40.12 0 4 124.62 178.04 -53.42 0 5 112.2 178.04 -65.84 0 6 128.11 178.04 -49.93 0 7 112.47 178.04 -65.57 0 8 95.58 178.04 -82.46 0 9 128.48 178.04 -49.56 0 10 133.23 178.04 -44.81 0 11 134.77 178.04 -43.27 0 12 69.28 178.04 -108.76 0 13 105.42 178.04 -72.62 0 14 106.75 178.04 -71.29 0 15 72.54 178.04 -105.5 0 16 94.62 178.04 -83.42 0 17 91.51 178.04 -86.53 0 18 60 178.04 -118.04 0 19 69.25 178.04 -108.79 0 20 56.74 178.04 -121.3 0 21 61.48 178.04 -116.56 0 22 25.57 178.04 -152.47 0 23 136.41 129.48 6.93 1 23 160.84 129.48 31.36 2 23 137.92 129.48 8.44 3 23 124.62 129.48 -4.86 3 24 112.2 129.48 -17.28 3 25 128.11 129.48 -1.37 3 26 112.47 129.48 -17.01 3 27 95.58 129.48 -33.9 3 28 128.48 129.48 -1 3 29 133.23 129.48 3.75 4 29 134.77 129.48 5.29 5 29 69.28 129.48 -60.2 5 30 105.42 129.48 -24.06 5 31 106.75 129.48 -22.73 5 32 72.54 129.48 -56.94 5 33 94.62 129.48 -34.86 5 34 91.51 129.48 -37.97 5 35 60 129.48 -69.48 5 36 69.25 129.48 -60.23 5 37 56.74 129.48 -72.74 5 38 61.48 129.48 -68 5 39 25.57 129.48 -103.91 5 40 160.84 136.41 24.43 6 40 137.92 136.41 1.51 7 40 124.62 136.41 -11.79 7 41 112.2 136.41 -24.21 7 42 128.11 136.41 -8.3 7 43 112.47 136.41 -23.94 7 44 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 19 Alexander Co CDLF over MSWLF Cumulative VOCs 95.58 136.41 -40.83 7 45 128.48 136.41 -7.93 7 46 133.23 136.41 -3.18 7 47 134.77 136.41 -1.64 7 48 69.28 136.41 -67.13 7 49 105.42 136.41 -30.99 7 50 106.75 136.41 -29.66 7 51 72.54 136.41 -63.87 7 52 94.62 136.41 -41.79 7 53 91.51 136.41 -44.9 7 54 60 136.41 -76.41 7 55 69.25 136.41 -67.16 7 56 56.74 136.41 -79.67 7 57 61.48 136.41 -74.93 7 58 25.57 136.41 -110.84 7 59 137.92 160.84 -22.92 7 60 124.62 160.84 -36.22 7 61 112.2 160.84 -48.64 7 62 128.11 160.84 -32.73 7 63 112.47 160.84 -48.37 7 64 95.58 160.84 -65.26 7 65 128.48 160.84 -32.36 7 66 133.23 160.84 -27.61 7 67 134.77 160.84 -26.07 7 68 69.28 160.84 -91.56 7 69 105.42 160.84 -55.42 7 70 106.75 160.84 -54.09 7 71 72.54 160.84 -88.3 7 72 94.62 160.84 -66.22 7 73 91.51 160.84 -69.33 7 74 60 160.84 -100.84 7 75 69.25 160.84 -91.59 7 76 56.74 160.84 -104.1 7 77 61.48 160.84 -99.36 7 78 25.57 160.84 -135.27 7 79 124.62 137.92 -13.3 7 80 112.2 137.92 -25.72 7 81 128.11 137.92 -9.81 7 82 112.47 137.92 -25.45 7 83 95.58 137.92 -42.34 7 84 128.48 137.92 -9.44 7 85 133.23 137.92 -4.69 7 86 134.77 137.92 -3.15 7 87 69.28 137.92 -68.64 7 88 105.42 137.92 -32.5 7 89 106.75 137.92 -31.17 7 90 72.54 137.92 -65.38 7 91 94.62 137.92 -43.3 7 92 91.51 137.92 -46.41 7 93 60 137.92 -77.92 7 94 69.25 137.92 -68.67 7 95 56.74 137.92 -81.18 7 96 61.48 137.92 -76.44 7 97 25.57 137.92 -112.35 7 98 112.2 124.62 -12.42 7 99 128.11 124.62 3.49 8 99 112.47 124.62 -12.15 8 100 95.58 124.62 -29.04 8 101 128.48 124.62 3.86 9 101 133.23 124.62 8.61 10 101 134.77 124.62 10.15 11 101 69.28 124.62 -55.34 11 102 105.42 124.62 -19.2 11 103 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 20 Alexander Co CDLF over MSWLF Cumulative VOCs 106.75 124.62 -17.87 11 104 72.54 124.62 -52.08 11 105 94.62 124.62 -30 11 106 91.51 124.62 -33.11 11 107 60 124.62 -64.62 11 108 69.25 124.62 -55.37 11 109 56.74 124.62 -67.88 11 110 61.48 124.62 -63.14 11 111 25.57 124.62 -99.05 11 112 128.11 112.2 15.91 12 112 112.47 112.2 0.27 13 112 95.58 112.2 -16.62 13 113 128.48 112.2 16.28 14 113 133.23 112.2 21.03 15 113 134.77 112.2 22.57 16 113 69.28 112.2 -42.92 16 114 105.42 112.2 -6.78 16 115 106.75 112.2 -5.45 16 116 72.54 112.2 -39.66 16 117 94.62 112.2 -17.58 16 118 91.51 112.2 -20.69 16 119 60 112.2 -52.2 16 120 69.25 112.2 -42.95 16 121 56.74 112.2 -55.46 16 122 61.48 112.2 -50.72 16 123 25.57 112.2 -86.63 16 124 112.47 128.11 -15.64 16 125 95.58 128.11 -32.53 16 126 128.48 128.11 0.37 17 126 133.23 128.11 5.12 18 126 134.77 128.11 6.66 19 126 69.28 128.11 -58.83 19 127 105.42 128.11 -22.69 19 128 106.75 128.11 -21.36 19 129 72.54 128.11 -55.57 19 130 94.62 128.11 -33.49 19 131 91.51 128.11 -36.6 19 132 60 128.11 -68.11 19 133 69.25 128.11 -58.86 19 134 56.74 128.11 -71.37 19 135 61.48 128.11 -66.63 19 136 25.57 128.11 -102.54 19 137 95.58 112.47 -16.89 19 138 128.48 112.47 16.01 20 138 133.23 112.47 20.76 21 138 134.77 112.47 22.3 22 138 69.28 112.47 -43.19 22 139 105.42 112.47 -7.05 22 140 106.75 112.47 -5.72 22 141 72.54 112.47 -39.93 22 142 94.62 112.47 -17.85 22 143 91.51 112.47 -20.96 22 144 60 112.47 -52.47 22 145 69.25 112.47 -43.22 22 146 56.74 112.47 -55.73 22 147 61.48 112.47 -50.99 22 148 25.57 112.47 -86.9 22 149 128.48 95.58 32.9 23 149 133.23 95.58 37.65 24 149 134.77 95.58 39.19 25 149 69.28 95.58 -26.3 25 150 105.42 95.58 9.84 26 150 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 21 Alexander Co CDLF over MSWLF Cumulative VOCs 106.75 95.58 11.17 27 150 72.54 95.58 -23.04 27 151 94.62 95.58 -0.96 27 152 91.51 95.58 -4.07 27 153 60 95.58 -35.58 27 154 69.25 95.58 -26.33 27 155 56.74 95.58 -38.84 27 156 61.48 95.58 -34.1 27 157 25.57 95.58 -70.01 27 158 133.23 128.48 4.75 28 158 134.77 128.48 6.29 29 158 69.28 128.48 -59.2 29 159 105.42 128.48 -23.06 29 160 106.75 128.48 -21.73 29 161 72.54 128.48 -55.94 29 162 94.62 128.48 -33.86 29 163 91.51 128.48 -36.97 29 164 60 128.48 -68.48 29 165 69.25 128.48 -59.23 29 166 56.74 128.48 -71.74 29 167 61.48 128.48 -67 29 168 25.57 128.48 -102.91 29 169 134.77 133.23 1.54 30 169 69.28 133.23 -63.95 30 170 105.42 133.23 -27.81 30 171 106.75 133.23 -26.48 30 172 72.54 133.23 -60.69 30 173 94.62 133.23 -38.61 30 174 91.51 133.23 -41.72 30 175 60 133.23 -73.23 30 176 69.25 133.23 -63.98 30 177 56.74 133.23 -76.49 30 178 61.48 133.23 -71.75 30 179 25.57 133.23 -107.66 30 180 69.28 134.77 -65.49 30 181 105.42 134.77 -29.35 30 182 106.75 134.77 -28.02 30 183 72.54 134.77 -62.23 30 184 94.62 134.77 -40.15 30 185 91.51 134.77 -43.26 30 186 60 134.77 -74.77 30 187 69.25 134.77 -65.52 30 188 56.74 134.77 -78.03 30 189 61.48 134.77 -73.29 30 190 25.57 134.77 -109.2 30 191 105.42 69.28 36.14 31 191 106.75 69.28 37.47 32 191 72.54 69.28 3.26 33 191 94.62 69.28 25.34 34 191 91.51 69.28 22.23 35 191 60 69.28 -9.28 35 192 69.25 69.28 -0.03 35 193 56.74 69.28 -12.54 35 194 61.48 69.28 -7.8 35 195 25.57 69.28 -43.71 35 196 106.75 105.42 1.33 36 196 72.54 105.42 -32.88 36 197 94.62 105.42 -10.8 36 198 91.51 105.42 -13.91 36 199 60 105.42 -45.42 36 200 69.25 105.42 -36.17 36 201 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 22 Alexander Co CDLF over MSWLF Cumulative VOCs 56.74 105.42 -48.68 36 202 61.48 105.42 -43.94 36 203 25.57 105.42 -79.85 36 204 72.54 106.75 -34.21 36 205 94.62 106.75 -12.13 36 206 91.51 106.75 -15.24 36 207 60 106.75 -46.75 36 208 69.25 106.75 -37.5 36 209 56.74 106.75 -50.01 36 210 61.48 106.75 -45.27 36 211 25.57 106.75 -81.18 36 212 94.62 72.54 22.08 37 212 91.51 72.54 18.97 38 212 60 72.54 -12.54 38 213 69.25 72.54 -3.29 38 214 56.74 72.54 -15.8 38 215 61.48 72.54 -11.06 38 216 25.57 72.54 -46.97 38 217 91.51 94.62 -3.11 38 218 60 94.62 -34.62 38 219 69.25 94.62 -25.37 38 220 56.74 94.62 -37.88 38 221 61.48 94.62 -33.14 38 222 25.57 94.62 -69.05 38 223 60 91.51 -31.51 38 224 69.25 91.51 -22.26 38 225 56.74 91.51 -34.77 38 226 61.48 91.51 -30.03 38 227 25.57 91.51 -65.94 38 228 69.25 60 9.25 39 228 56.74 60 -3.26 39 229 61.48 60 1.48 40 229 25.57 60 -34.43 40 230 56.74 69.25 -12.51 40 231 61.48 69.25 -7.77 40 232 25.57 69.25 -43.68 40 233 61.48 56.74 4.74 41 233 25.57 56.74 -31.17 41 234 25.57 61.48 -35.91 41 235 S Statistic = 41 - 235 = -194 Tied GroulValue Members Time Period 6/24/2009 12/15/2009 7/7/2010 12/8/2010 6/28/2011 12/13/2011 6/12/2012 12/10/2012 6/25/2013 12/16/2013 6/24/2014 Observations 1 1 1 1 1 1 1 1 1 1 1 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 23 Alexander Cc CDLF over MSWLF Cumulative VOCs 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 12/29/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 29256 b = 109296 c = 1104 Group Variance = 1625.33 Z-Score=-4.78725 Comparison Level at 95% confidence level =-1.65463 (downward trend) Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 24 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (UNDGNTD) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 66.57 161.23 -94.66 0 1 93 161.23 -68.23 0 2 180.22 161.23 18.99 1 2 99.9 161.23 -61.33 1 3 145.94 161.23 -15.29 1 4 94.55 161.23 -66.68 1 5 109.63 161.23 -51.6 1 6 118.06 161.23 -43.17 1 7 98.06 161.23 -63.17 1 8 89.36 161.23 -71.87 1 9 116.46 161.23 -44.77 1 10 93.51 161.23 -67.72 1 11 44.28 161.23 -116.95 1 12 83.59 161.23 -77.64 1 13 75.37 161.23 -85.86 1 14 69.51 161.23 -91.72 1 15 109.38 161.23 -51.85 1 16 58.09 161.23 -103.14 1 17 89.59 161.23 -71.64 1 18 78.62 161.23 -82.61 1 19 21.54 161.23 -139.69 1 20 61.83 161.23 -99.4 1 21 7.28 161.23 -153.95 1 22 93 66.57 26.43 2 22 180.22 66.57 113.65 3 22 99.9 66.57 33.33 4 22 145.94 66.57 79.37 5 22 94.55 66.57 27.98 6 22 109.63 66.57 43.06 7 22 118.06 66.57 51.49 8 22 98.06 66.57 31.49 9 22 89.36 66.57 22.79 10 22 116.46 66.57 49.89 11 22 93.51 66.57 26.94 12 22 44.28 66.57 -22.29 12 23 83.59 66.57 17.02 13 23 75.37 66.57 8.8 14 23 69.51 66.57 2.94 15 23 109.38 66.57 42.81 16 23 58.09 66.57 -8.48 16 24 89.59 66.57 23.02 17 24 78.62 66.57 12.05 18 24 21.54 66.57 -45.03 18 25 61.83 66.57 -4.74 18 26 7.28 66.57 -59.29 18 27 180.22 93 87.22 19 27 99.9 93 6.9 20 27 145.94 93 52.94 21 27 94.55 93 1.55 22 27 109.63 93 16.63 23 27 118.06 93 25.06 24 27 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 25 Alexander Co CDLF over MSWLF Cumulative VOCs 98.06 93 5.06 25 27 89.36 93 -3.64 25 28 116.46 93 23.46 26 28 93.51 93 0.51 27 28 44.28 93 -48.72 27 29 83.59 93 -9.41 27 30 75.37 93 -17.63 27 31 69.51 93 -23.49 27 32 109.38 93 16.38 28 32 58.09 93 -34.91 28 33 89.59 93 -3.41 28 34 78.62 93 -14.38 28 35 21.54 93 -71.46 28 36 61.83 93 -31.17 28 37 7.28 93 -85.72 28 38 99.9 180.22 -80.32 28 39 145.94 180.22 -34.28 28 40 94.55 180.22 -85.67 28 41 109.63 180.22 -70.59 28 42 118.06 180.22 -62.16 28 43 98.06 180.22 -82.16 28 44 89.36 180.22 -90.86 28 45 116.46 180.22 -63.76 28 46 93.51 180.22 -86.71 28 47 44.28 180.22 -135.94 28 48 83.59 180.22 -96.63 28 49 75.37 180.22 -104.85 28 50 69.51 180.22 -110.71 28 51 109.38 180.22 -70.84 28 52 58.09 180.22 -122.13 28 53 89.59 180.22 -90.63 28 54 78.62 180.22 -101.6 28 55 21.54 180.22 -158.68 28 56 61.83 180.22 -118.39 28 57 7.28 180.22 -172.94 28 58 145.94 99.9 46.04 29 58 94.55 99.9 -5.35 29 59 109.63 99.9 9.73 30 59 118.06 99.9 18.16 31 59 98.06 99.9 -1.84 31 60 89.36 99.9 -10.54 31 61 116.46 99.9 16.56 32 61 93.51 99.9 -6.39 32 62 44.28 99.9 -55.62 32 63 83.59 99.9 -16.31 32 64 75.37 99.9 -24.53 32 65 69.51 99.9 -30.39 32 66 109.38 99.9 9.48 33 66 58.09 99.9 -41.81 33 67 89.59 99.9 -10.31 33 68 78.62 99.9 -21.28 33 69 21.54 99.9 -78.36 33 70 61.83 99.9 -38.07 33 71 7.28 99.9 -92.62 33 72 94.55 145.94 -51.39 33 73 109.63 145.94 -36.31 33 74 118.06 145.94 -27.88 33 75 98.06 145.94 -47.88 33 76 89.36 145.94 -56.58 33 77 116.46 145.94 -29.48 33 78 93.51 145.94 -52.43 33 79 44.28 145.94 -101.66 33 80 83.59 145.94 -62.35 33 81 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 26 Alexander Co CDLF over MSWLF Cumulative VOCs 75.37 145.94 -70.57 33 82 69.51 145.94 -76.43 33 83 109.38 145.94 -36.56 33 84 58.09 145.94 -87.85 33 85 89.59 145.94 -56.35 33 86 78.62 145.94 -67.32 33 87 21.54 145.94 -124.4 33 88 61.83 145.94 -84.11 33 89 7.28 145.94 -138.66 33 90 109.63 94.55 15.08 34 90 118.06 94.55 23.51 35 90 98.06 94.55 3.51 36 90 89.36 94.55 -5.19 36 91 116.46 94.55 21.91 37 91 93.51 94.55 -1.04 37 92 44.28 94.55 -50.27 37 93 83.59 94.55 -10.96 37 94 75.37 94.55 -19.18 37 95 69.51 94.55 -25.04 37 96 109.38 94.55 14.83 38 96 58.09 94.55 -36.46 38 97 89.59 94.55 -4.96 38 98 78.62 94.55 -15.93 38 99 21.54 94.55 -73.01 38 100 61.83 94.55 -32.72 38 101 7.28 94.55 -87.27 38 102 118.06 109.63 8.43 39 102 98.06 109.63 -11.57 39 103 89.36 109.63 -20.27 39 104 116.46 109.63 6.83 40 104 93.51 109.63 -16.12 40 105 44.28 109.63 -65.35 40 106 83.59 109.63 -26.04 40 107 75.37 109.63 -34.26 40 108 69.51 109.63 -40.12 40 109 109.38 109.63 -0.25 40 110 58.09 109.63 -51.54 40 111 89.59 109.63 -20.04 40 112 78.62 109.63 -31.01 40 113 21.54 109.63 -88.09 40 114 61.83 109.63 -47.8 40 115 7.28 109.63 -102.35 40 116 98.06 118.06 -20 40 117 89.36 118.06 -28.7 40 118 116.46 118.06 -1.6 40 119 93.51 118.06 -24.55 40 120 44.28 118.06 -73.78 40 121 83.59 118.06 -34.47 40 122 75.37 118.06 -42.69 40 123 69.51 118.06 -48.55 40 124 109.38 118.06 -8.68 40 125 58.09 118.06 -59.97 40 126 89.59 118.06 -28.47 40 127 78.62 118.06 -39.44 40 128 21.54 118.06 -96.52 40 129 61.83 118.06 -56.23 40 130 7.28 118.06 -110.78 40 131 89.36 98.06 -8.7 40 132 116.46 98.06 18.4 41 132 93.51 98.06 -4.55 41 133 44.28 98.06 -53.78 41 134 83.59 98.06 -14.47 41 135 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 27 Alexander Co CDLF over MSWLF Cumulative VOCs 75.37 98.06 -22.69 41 136 69.51 98.06 -28.55 41 137 109.38 98.06 11.32 42 137 58.09 98.06 -39.97 42 138 89.59 98.06 -8.47 42 139 78.62 98.06 -19.44 42 140 21.54 98.06 -76.52 42 141 61.83 98.06 -36.23 42 142 7.28 98.06 -90.78 42 143 116.46 89.36 27.1 43 143 93.51 89.36 4.15 44 143 44.28 89.36 -45.08 44 144 83.59 89.36 -5.77 44 145 75.37 89.36 -13.99 44 146 69.51 89.36 -19.85 44 147 109.38 89.36 20.02 45 147 58.09 89.36 -31.27 45 148 89.59 89.36 0.23 46 148 78.62 89.36 -10.74 46 149 21.54 89.36 -67.82 46 150 61.83 89.36 -27.53 46 151 7.28 89.36 -82.08 46 152 93.51 116.46 -22.95 46 153 44.28 116.46 -72.18 46 154 83.59 116.46 -32.87 46 155 75.37 116.46 -41.09 46 156 69.51 116.46 -46.95 46 157 109.38 116.46 -7.08 46 158 58.09 116.46 -58.37 46 159 89.59 116.46 -26.87 46 160 78.62 116.46 -37.84 46 161 21.54 116.46 -94.92 46 162 61.83 116.46 -54.63 46 163 7.28 116.46 -109.18 46 164 44.28 93.51 -49.23 46 165 83.59 93.51 -9.92 46 166 75.37 93.51 -18.14 46 167 69.51 93.51 -24 46 168 109.38 93.51 15.87 47 168 58.09 93.51 -35.42 47 169 89.59 93.51 -3.92 47 170 78.62 93.51 -14.89 47 171 21.54 93.51 -71.97 47 172 61.83 93.51 -31.68 47 173 7.28 93.51 -86.23 47 174 83.59 44.28 39.31 48 174 75.37 44.28 31.09 49 174 69.51 44.28 25.23 50 174 109.38 44.28 65.1 51 174 58.09 44.28 13.81 52 174 89.59 44.28 45.31 53 174 78.62 44.28 34.34 54 174 21.54 44.28 -22.74 54 175 61.83 44.28 17.55 55 175 7.28 44.28 -37 55 176 75.37 83.59 -8.22 55 177 69.51 83.59 -14.08 55 178 109.38 83.59 25.79 56 178 58.09 83.59 -25.5 56 179 89.59 83.59 6 57 179 78.62 83.59 -4.97 57 180 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 28 Alexander Co CDLF over MSWLF Cumulative VOCs 21.54 83.59 -62.05 57 181 61.83 83.59 -21.76 57 182 7.28 83.59 -76.31 57 183 69.51 75.37 -5.86 57 184 109.38 75.37 34.01 58 184 58.09 75.37 -17.28 58 185 89.59 75.37 14.22 59 185 78.62 75.37 3.25 60 185 21.54 75.37 -53.83 60 186 61.83 75.37 -13.54 60 187 7.28 75.37 -68.09 60 188 109.38 69.51 39.87 61 188 58.09 69.51 -11.42 61 189 89.59 69.51 20.08 62 189 78.62 69.51 9.11 63 189 21.54 69.51 -47.97 63 190 61.83 69.51 -7.68 63 191 7.28 69.51 -62.23 63 192 58.09 109.38 -51.29 63 193 89.59 109.38 -19.79 63 194 78.62 109.38 -30.76 63 195 21.54 109.38 -87.84 63 196 61.83 109.38 -47.55 63 197 7.28 109.38 -102.1 63 198 89.59 58.09 31.5 64 198 78.62 58.09 20.53 65 198 21.54 58.09 -36.55 65 199 61.83 58.09 3.74 66 199 7.28 58.09 -50.81 66 200 78.62 89.59 -10.97 66 201 21.54 89.59 -68.05 66 202 61.83 89.59 -27.76 66 203 7.28 89.59 -82.31 66 204 21.54 78.62 -57.08 66 205 61.83 78.62 -16.79 66 206 7.28 78.62 -71.34 66 207 61.83 21.54 40.29 67 207 7.28 21.54 -14.26 67 208 7.28 61.83 -54.55 67 209 S Statistic = 67 - 209 = -142 Tied GroulValue Members Time Period 6/24/2009 12/15/2009 7/7/2010 12/8/2010 6/28/2011 12/13/2011 6/12/2012 12/10/2012 6/25/2013 12/16/2013 6/24/2014 Observations 1 1 1 1 1 1 1 1 1 1 1 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 29 Alexander Cc CDLF over MSWLF Cumulative VOCs 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 12/29/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 29256 b = 109296 c = 1104 Group Variance = 1625.33 Z-Score =-3.49742 Comparison Level at 95% confidence level =-1.65463 (downward trend) Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 30