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HomeMy WebLinkAbout10054_LHBPlant1_BAR_20090626Via Hand -Delivery June 26, 2009 Ms. Sharon Eckard NCDENR Division of Waste Management Brownfields Program 401 Oberlin Rd., Suite 150 Raleigh, NC 27605 Re: Response to Comments - Brownfield Phase II Site Assessment Report Piedmont Triad Council of Governments Brownfield Assessment Project Lexington Home Brands, Plant 1 Lexington, North Carolina, BF-96460406-0 H&H Job No. PTC-003 Dear Sharon: ti Hart & HAM LNVIRD- Hart & Hickman, PC 3334 Hillsborough Street Raleigh, NC 27607 919-847-4241 phone 919-847-4261fax www.harthickman.com On behalf of the Piedmont Triad Council of Governments, Hart & Hickman (H&H) is pleased to submit this Response to Comments on the Brownfield Phase II Site Assessment Report for the Lexington Home Brands Plant 1 Site in Lexington, North Carolina. Based upon comments from NCDENR review and our subsequent discussions, H&H has made appropriate edits to the following: • Signed and sealed report cover. • Page I of the Table of Contents due to formatting changes. • Report Pages 9 through 14 - Duplicate, matrix spike, and matrix spike duplicate samples were cross referenced with corresponding soil or groundwater samples. • Table 1 — Corrected total soil sample quantities. • Table 2 — Lithologic units were described, soil SRGs were revised to show correct limits, and exceedance of revised SRGs was addressed. • Table 4 — NCAC 2L Standard for Benzo(b)fluoranthene was revised to show the correct value. • Figure 8 — Revised to display data in correct units. • Appendix D — Expanded on field QA/QC. Mention of field audits. Thorough description of "H" laboratory data qualifier and data implications and discussion of SVOC laboratory reporting limits above NCDENR SRGs. The aforementioned report pages, tables, figure, and appendix are included as attachments to this letter and are designated with the notation: Revision 1. These revised pages should be placed into the original document. CHARLOTTE 704-586-0007 RALEIGH 919-847-4241 WWW.HARTHICKMAN.COM Sharon Eckard 6/26/2009 Page 2 Should you require additional information or have questions regarding this document please contact me at 919-723-2501 or via email at lmoretzkharthickman.com. Sincerely, Hart & Hickman, PC r;<4#'Ia'te C. M OAtV Leonard Moretz, PG Project Director/Branch Manager cc: Ms. Cindy Nolan, US EPA Mr. John Gray, City of Lexington City Manager Mr. Paul Kron, Piedmont Triad Council of Governments sAaaa-master projects\piedmont triad cog - ptc\ptc-003 brow field phase ii\bf phase ii report\response to comments letter.doc )AW Hdrt & llicknidn A Prof"sfonak Corporation Brownfield Phase II Site Assessment Report Revision 1 Former Lexington Home Brands -Plant 1 Lexington, North Carolina H&H Job No. PTC-003 June 26, 2009 W Hart & Hickman 333411illsborough St, Raleigh, NC 27607 919-847-4241 2923 South Tryon St. Suite 100 Charlotte, NC 28203 704-586-0007 REV 1 6/26/09 Brownfield Phase II Site Assessment Report Former Lexington Home Brands - Plant 1 Lexington, North Carolina H&H Job No. PTC-003 Table of Contents Section Page No. 1.0 Introduction and Background.......................................................................................................1 1.1 Site Conditions......................................................................................................................... 2 1.2 Recognized Environmental Conditions and Potential Environmental Concerns .................. 3 1.2.1 Study Area 1................................................................................ 3 1.2.2 Study Area 2................................................................................ 5 1.2.3 Study Area 3................................................................................ 5 2.0 Assessment Activities......................................................................................................................7 2.1 SAR Objectives.......................................................................................................................7 2.2 General Field Practices........................................................................................................... 7 2.3 Subsurface Utility Location.................................................................................................... 8 2.4 Soil Sampling.......................................................................................................................... 8 2.4.1 Study Area 1.............................................................................. 10 2.4.2 Study Area 2.............................................................................. 10 2.4.3 Study Area 3.............................................................................. 11 2.5 Monitoring Well Installation................................................................................................12 2.5.1 Study Area 1.............................................................................. 12 2.5.2 Study Area 2.............................................................................. 13 2.5.3 Study Area 3.............................................................................. 13 2.6 Ground Water Sampling.......................................................................................................13 2.7 Permanent Well Elevations Measurement...........................................................................14 3.0 Results of Assessment...................................................................................................................15 3.1 Data Review, Verification and Validation...........................................................................15 3.2 Site Geology and Hydrogeology..........................................................................................15 3.3 Soil Analytical Results..........................................................................................................16 3.3.1 Regulatory Screening Levels........................................................... 16 i Hart & Hickman, PC S:\AAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase II\BF Phase II Report\FINAL LHB Phase 11 SAR REV I doc REV 1 6/26/09 Each of the soil samples was assigned a unique name which included the sample location and depth. Thirty-seven (37) soil samples were submitted for laboratory analysis. Duplicate and matrix spike/matrix spike duplicate (MS/MSD) samples were retained to ensure Level II laboratory quality Assurance/Quality Control (QA/QC). Quality control samples and corresponding samples are listed below. • DUP 011309-A — SB-I (1') • DUP 011309-B — SB-2 (0-0.5') • DUP 011309-C — SB-35 (10-11') • DUP 011309-D — SB-12 (0-1') • DUP 011409-A — SB-I I (1') • MS/MSD — SB-20 (0-1') • MS/MSD-2 — SB-29 (14-15') A summary of the soil sample and analytical program is presented in Table 1. Results are presented in Table 2 and discussed in Section 3.3. Laboratory analyses were conducted by Prism Laboratories, Inc., a North Carolina -certified and Woman -owned Business Enterprise (WBE) analytical laboratory located in Charlotte, NC. Samples were placed into the appropriate containers, stored on ice in coolers, and submitted to the laboratory under standard chain -of -custody protocol. After soil sampling was completed, each of the DPT bore holes, except those borings converted to temporary or permanent monitoring wells were backfilled with soil and bentonite to surface grade and capped with concrete. Boring and monitoring well logs are provided in Appendix A. Investigation -derived waste was contained in 55-gallon UN1A steel drums temporarily stored onsite. A label indicating that the drum(s) are "on hold pending analysis" was affixed to the exterior of the drum(s) and the contents of the drum(s) "investigative derived waste — soils" was annotated along with the generation date(s) on the label. Analyses of the drummed material indicated the material was non -hazardous. The drums were transported and properly disposed at 9 Hart & Hickman, PC S:WAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IRBF Phase II Report\FINAL LHB Phase H SAR REV l.doc REV 1 6/26/09 an offsite permitted facility by Garco, Inc. on May 13, 2009. A copy of the waste profiles and Certificate of Disposal are provided in Appendix B. 2.4.1 Study Area 1 Soil borings installed within Study Area 1 included those designated as S13-1, S13-2, S13-3, S13-6, S13-7, SB-10, SB-11, S13-12, S13-13, SB-14, SB-15 and S13-17. Locations of these borings and wells are shown on Figure 3. All soil samples obtained for laboratory analysis in Study Area 1 were within 3 feet of surface grade due to the shallow ground water table encountered in this area. Soil samples from the three Study Areas were analyzed according to the plan presented in Table 1. S13-4 and S13-5 were advanced but soils were not sampled because ground water was encountered within 1/2 foot of surface grade. Soil was also not collected from S13-8 and S13-9 because of the shallow (less than 3' bgs) ground water level. These borings were proposed to evaluate unsaturated soil conditions at the bottom of the former 3,000 thinner overflow tank and the former 7,500 gallon naptha tank. However, due to the high water table, samples collected at the required depth would have been below the water table. In a January 13, 2008 conversation with Mr. Michael Rogers of the NC DENR UST Section, Winston Salem Regional Office, H&H was advised that collection of soil samples at these locations would not be necessary because the base of the former USTs were within saturated soils. Permanent monitoring wells MW-lA, 2A, 3A and 4A were installed within Study Area 1 and soil samples were obtained from each of these wells during their installation 2.4.2 Study Area 2 A single boring (SB-27) was installed in Study Area 2 to evaluate soil and ground water conditions at the location of the release from a former 550 gal gasoline UST (Figure 4). SB-27 was installed to a depth of 22 ft-bgs in the center of the former tank pit. A soil sample was retained from SB-27 at a depth of 8 to 9 ft-bgs, the anticipated bottom of the former tank pit, in 10 Hart & Hickman, PC S:WAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IRBF Phase II Report\FINAL LHB Phase H SAR REV l.doc REV 1 6/26/09 native soils. Boring SB-27 was advanced approximately 2 feet below the water table, to install a temporary monitoring well and obtain a ground water sample. Installation and sampling of the temporary well at this location is discussed in Section 2.5.2. 2.4.3 Study Area 3 Thirteen (13) soil borings (SB-28 to SB-40) were installed within Study Area 3 as shown on Figure 4. In accordance with the QAPP, soil samples within this area were generally obtained within 3 ft. of surface grade (with the exception of borings SB-28, SB-29 and SB-35). Samples SB-28 and 29 were obtained from depths of 14 to 15 ft. bgs, approximately 2 ft. below the estimated base depth of an abandoned fuel oil UST. Boring SB-29 was placed immediately downgradient of the former UST and extended to a depth of 20 ft. bgs to install a temporary monitoring well. Installation and sampling of the temporary well at this location is discussed in Section 2.5.3. Sample SB-35 was retained from 10 to 11 ft. bgs, approximately 2 ft. below the estimated base depth of two gasoline USTs which were removed in 1989. Boring SB-35 was extended to a depth of 20 ft-bgs to install a temporary monitoring well. Installation and sampling of the temporary well at this location is discussed in Section 2.5.3. Samples SB-36 and SB-37 were collected to assess potential impacts from two in -floor vaults/sumps in the former wood processing area. The former use of these features is unknown. These vaults/sumps were approximately eight feet long by four feet wide by two feet deep. The features were dry with no signs of staining or sludge. Samples were collected adjacent to and immediately beneath the bottom of the vaults/sumps. 11 Hart & Hickman, PC S:WAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IRBF Phase II Report\FINAL LHB Phase R SAR REV 1 doc REV 1 6/26/09 2.5 Monitoring Well Installation As specified in the QAPP, four (4) permanent ground water monitoring wells (MW-IA, MW- 2A, MW-3A and MW-4A) were installed to assess the shallow ground water within Study Area 1. In addition, soil borings SB-2, SB-4, SB-6, SB-7, SB-10, SB-14, SB-27, SB-29 and SB-35 were extended into the water table and completed as temporary monitoring wells. Both permanent and temporary wells were constructed in accordance with the QAPP, and North Carolina Administrative Code (NCAC), Chapter 15A, Subchapter 02C, Section .0108 (Standards of Construction: Wells Other Than Water Supply). After sampling, the temporary wells were abandoned in accordance with the above standard. Well Construction records for the installation of these wells are presented in Appendix C. Permanent monitoring well construction data are summarized in Table 3. Installation of permanent and temporary wells and sampling of ground water are discussed below. 2.5.1 Study Area 1 Within Study Area 1, four (4) permanent ground water monitoring wells (MW-IA, MW-2A, MW-3 A and MW-4A) were installed at the locations shown on Figure 3. Wells MW-IA, MW- 3A and MW-4A were each installed to 12 ft. bgs, while MW-2A was installed to 17 ft. bgs. Wells were installed after the collection of soil samples. Temporary wells were set in borings SB-2, SB-4, SB-6, SB-7, SB-10 and SB-14 (Figure 3). After collection of soil samples from these borings, each was extended (if necessary) to penetrate the water table at their location. Temporary wells were installed and constructed as outlined in the QAPP. Ground water sampling is discussed in Section 2.6. 12 Hart & Hickman, PC S:WAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IRBF Phase II Report\FINAL LHB Phase R SAR REV 1 doc REV 1 6/26/09 2.5.2 Study Area 2 Following collection of soil samples from boring SB-27 (Figure 4), the boring was extended to 22 ft. bgs and a temporary well was installed and constructed as outlined in the QAPP. Ground water sampling is discussed in Section 2.6. 2.5.3 Study Area 3 After collection of soil samples from borings SB-29 and SB-35 (Figure 4), the borings were extended to depths of 20 ft. and temporary wells were installed and constructed as outlined in the QAPP. Ground water sampling is discussed in Section 2.6. 2.6 Ground Water Sampling Ground water samples were collected from temporary wells installed in borings S13-2, SB-4, SB- 6, SB-7, SB-10, SB-14, SB-27, SB-29 and SB-35 on January 14, 2009. Samples were collected from permanent monitoring wells MW-IA, MW-2A, MW-3A and MW-4A, installed in Study Area 1 on January 23, 2009. Prior to sampling, the water level within the well was measured from ground surface (in the case of the temporary wells) or the top of the well casing (in the case of the permanent wells). Each well was purged and sampled in accordance with procedures outlined in the QAPP. Samples obtained from temporary wells SB-2, SB-4, SB-6, SB-7, SB-10 and SB-14 were submitted for analysis of VOCs, SVOCs and metals by EPA Methods 8260B, 8270C and 6010B/7471A, respectively. Samples obtained from temporary wells SB-27 and SB-35 were submitted for analysis of VOCs by EPA Method 8260B and VPH by the MADEP-VPH method. The sample obtained from SB-29 was submitted for analysis of SVOCs and EPH by EPA Method 8270C and the MADEP-EPH method, respectively. Samples from permanent wells MW-IA, MW-2A, MW-3A and MW-4A were submitted for analysis of VOCs, SVOCs and RCRA metals by EPA Methods 820613, 8270C and 13 Hart & Hickman, PC S:WAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IRBF Phase II Report\FINAL LHB Phase R SAR REV 1 doc REV 1 6/26/09 601013/7471A, respectively. In addition to these methods, the sample from MW-4A was also analyzed for pesticides using EPA Method 8081A. In accordance with the QAPP, duplicate, matrix spike and matrix spike duplicate samples were obtained from the temporary and/or permanent wells. Quality control samples and corresponding samples are listed below. • GW-DUP-012309 — MW4A • MS/MSD (1/14/09) — SB-35 • MS/MSD (1/23/09) — MW-3A Several monitoring wells installed during assessment of the former 550 gallon petroleum UST in Study Area 2 and were proposed in the QAPP to be sampled. However, field inspection revealed these wells had been permanently abandoned as part of the NFA granted for this UST. Therefore, these wells were not sampled as a part of the SA. Analytical data for the ground water samples are discussed in Section 3.4, and summarized in Table 4. 2.7 Permanent Well Elevations Measurement Relative elevations of each permanent well were established on January 23, 2009 utilizing a transit and stadia rod. A benchmark with an assumed elevation of 500.00 ft. was established at a random location on the site, and the relative elevation of each well was measured based on the assumed elevation of the benchmark. The relative elevation data were used to calculate ground water hydraulic gradient, based on water level elevations also obtained on January 23, 2009. Relative elevations are presented in Table 3. 14 Hart & Hickman, PC S:WAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IRBF Phase II Report\FINAL LHB Phase H SAR REV 1 doc Table 1 - Revision 1 Sample Summary Brownfield Phase II Site Assessment Former Lexington Home Brands - Plant 1 Lexington, North Carolina H&H Job No. PTC-003 Boring Location Depth Interval Sample Objective Lab Documentation ANALYSES VOCs EPA 8260B SVOCs EPA 8270C RCRA Metals EPA 6010B / 7471A MADEP EPH MADEP VPH Pesticides EPA 8081 Soil Samples: SB-1 0-l' Evaluation of Drainage Structures near ASTs Level II 1 1 1 0 0 0 SB-2 0-0.5' Evaluation of Drainage Structures near ASTs Level II 1 1 1 0 0 0 SB-3 0-l' Evaluation of Drainage Structures near ASTs Level II 1 1 1 0 0 0 SB-6 0-l' Evaluation of Bermed Area near Mixing Room Level II 1 1 1 0 0 0 SB-7 0-l' Evaluation of Bermed Area near Mixing Room Level II 1 1 0 0 0 0 SB-10 0-l' Evaluation of Bermed Area near AST Level II 1 1 1 0 0 0 SB-11 0-l' Evaluation of Bermed Area near AST Level II 0 0 0 1 1 1 0 SB-12 0-l' Evaluation of Boiler Room Floor Drains Level II 0 1 0 1 0 0 SB-13 1-1.75' Evaluation of Boiler Room Floor Drains Level II 0 1 0 1 0 0 SB-14 1-2' Evaluation of Downgrade Drainage Area Level II 1 1 1 0 0 0 SB-15 0-l' Evaluation of Air Blowdown Area Level II 1 1 1 0 0 0 SB-16 1-2' Evaluation of Former Hazardous Storage Pad Level II 1 1 1 0 0 0 SB-17 0-l' Evaluation of Downgrade Drainage Area Level II 1 1 1 0 0 0 SB-20 0-l' Evaluation of Former Finishing Plant Level II 1 1 0 0 0 1 SB-21 0-l' Evaluation of Former Finishing Plant Level Il 1 1 0 0 0 1 SB-22 0-l' Evaluation of Former Finishing Plant Level II 1 1 0 0 0 1 SB-23 0-l' Evaluation of Former Finishing Plant Level II 1 1 1 0 0 0 SB-23 2-3' Evaluation of Former Finishing Plant Level II 1 1 1 0 0 0 SB-24 0-l' Evaluation of Former Finishing Plant Level II 1 1 0 0 0 1 SB-27 8-9' Evaluation of Former Gasoline UST Area Level II 1 0 0 0 1 0 SB-28 14-15' Evaluation of Abandoned Fuel Oil UST Level II 0 1 0 1 0 0 SB-29 14-15' Evaluation of Abandoned Fuel Oil UST Level II 0 1 0 1 0 0 SB-30 2-3' Evaluation of Existing 1 OK Fuel Oil AST Level II 0 1 0 1 0 0 SB-31 2-3' Evaluation of Existing I OK Fuel Oil AST Level II 0 1 0 1 0 0 SB-32 2-3' Evaluation of Former Vehicle Storage Area Level II 1 1 0 0 0 0 SB-33 2-3' Evaluation of Former Vehicle Storage Area Level II 1 1 0 0 0 0 SB-34 2-3' Evaluation of Former Vehicle Storage Area Level II 1 1 0 0 0 0 SB-35 10-1 F Evaluation of Former Gasoline UST Area Level II 1 0 0 0 1 0 SB-36 2-3' Evaluation of Sumps Level II 1 1 0 0 0 0 SB-37 2-3' Evaluation of Sumps Level Il 1 1 0 0 0 0 SB-38 2-3' Evaluation of Existing 550 Gal ASTs Level II 0 1 0 1 0 0 SB-39 2-3' Evaluation of Former Vehicle Maintenance Shop Level II 1 1 0 0 0 0 SB-40 2-3' Evaluation of Former Vehicle Maintenance Shop Level II 1 1 0 0 0 0 MW-IA 1-2' "Upgradient" Well Location Level II 1 1 1 0 0 0 MW-2A 0-1' Evaluation of Area Downgradient of Paint Storage & Mixing Rooms, Hazardous Storage Pad Level II 1 1 1 0 0 0 MW-3A 0-l' Evaluation of Area Downgradient of Former Finishing Plant Level II 1 1 1 0 0 0 MW-4A 1-2' Evaluation of Area Downgradient of Former Finishing Plant Level II 1 1 1 0 0 0 Duplicate N/A Data Quality Assurance Level II 3 4 1 1 1 1 MS/MSD N/A Data Quality Assurance Level II 3 4 0 1 0 1 TOTALS: 35 42 16 10 4 6 Water Samples Sample Objective Lab Documentation ANALYSES VOCs EPA 8260B SVOCs EPA 8270C RCRA Metals EPA 6010B / 7471A MADEP EPH MADEP VPH Pesticides EPA 8081 SB-2 N/A Evaluation of Drainage Structures near ASTs Level II 1 1 1 0 0 0 SB-4 N/A Evaluation of Vaults/Sumps Level II 1 1 1 0 0 0 SB-6 N/A Evaluation of Bermed Area near Mixing Room Level II 1 1 1 0 0 0 SB-7 N/A Evaluation of Bermed Area near Mixing Room Level II 1 1 1 0 0 0 SB-10 N/A Evaluation of Bermed Area near AST Level II 1 1 1 0 0 0 SB-14 N/A Evaluation of Downgrade Drainage Area Level II 1 1 1 0 0 0 SB-27 N/A Evaluation of Former Gasoline UST Area Level II 1 0 0 0 1 0 SB-29 N/A Evaluation of Abandoned Fuel Oil UST Level II 0 1 0 1 0 0 SB-35 N/A Evaluation of Former Gasoline UST Area Level II 1 0 0 0 1 0 MW-IA N/A "Upgradient" Well Location Level II 1 1 1 0 0 0 MW-2A N/A Evaluation of Area Downgradient of Paint Storage & Mixing Rooms, Hazardous Storage Pad Level II 1 1 1 0 0 0 MW-3A N/A Evaluation of Area Downgradient of Former Finishing Plant Level II 1 1 1 0 0 1 MW-4A N/A Evaluation of Area Downgradient of Former Finishing Plant Level II 1 1 1 0 0 1 Trip Blank N/A Data Quality Assurance Level II 2 0 0 0 0 0 Duplicate N/A Data Quality Assurance Level II 1 1 1 0 0 1 MS/MSD N/A Data Quality Assurance Level II 2 1 1 0 1 1 TOTALS: 17 13 12 1 3 4 Notes: 1. VOCs = Volatile Organic Compounds 2. SVOCs = Semi -Volatile Organic Compounds 3. RCRA Metals Includes analysis by EPA Method 6010B for arsenic, barium, cadmium, chromium, lead, selenium and silver, as well as mercury by EPA Method 7471A 4. MADEP-EPH = Massachusetts Department of Environmental Protection - Extractable Petroleum Hydrocarbons 4. MADEP-VPH = Massachusetts Department of Environmental Protection - Volatile Petroleum Hydrocarbons SAAAA-Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase 11\13F Phase II Report\PTC-003 Phase II Tables Revised June 25, 2009 Page 1 of 1 Hart & Hickman, PC Table 2 - Revision 1 Summary Analytical Data - Soil Brownfield Phase II Site Assessment Former Lexington Home Brands - Plant 1 Lexington, North Carolina H&H Job No. PTC-003 Boring Location Area 1 Screening Levels Sample ID SB-1 SB-2 SB-3 SB-6 SB-7 SB-10 SB-11 SB-12 SB-13 SB-14 EPA RSL t NCDENR (Soils) Sample Depth (ft) 1' 0-0.5' 1' 1' 0-1' 1' 1' 0-1' 1-1.75 1-2' Z 0 r " a a q X56 U a Lithology Clayey Silt Clayey Silt Clayey Silt Silty Sand Clayey Sand Sandy Silt Sandy Silt Fine Sand Clayey Silt Sandy Silt Date Collected 1/14/2009 1/13/2009 1/14/2009 1/13/2009 1/13/2009 1/13/2009 1/14/2009 1/13/2009 1/14/2009 1/13/2009 Units rag/kg rr/k m m k m rag/kg rag/kg rag/kg mg/kg m Laboratory Parameters VOCs 8260B mg/kg 1,2,4-Trimeth lbenzene <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 67 280 13 1,2-Dichloroethane <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 0.45 2.2 0.45 1,2-Dichloro ro ane <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 0.93 4.7 0.93 1,3,5-Trimeth lbenzene 6.3 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 47 200 NS Acetone <1.5 <0.078 <0.057 <0.050 <0.048 <0.060 NA NA NA 0.045 61,000 610,000 12,000 Benzene <0.37 <0.0047 <0.0034 <0.0030 <0.0029 <0.0036 NA NA NA <0.0026 1.1 5.6 1.1 Chloroform <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 0.3 1.5 0.3 Eth lbenzene 1.6 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 5.7 1 29 5.7 ----- Isopropyl ether (IPE) <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 1,200 5,100 NS Iso ro lbenzene 3.1 <0.0078 <0.0057 <0.0050 0.024 <0.0060 NA NA NA <0.0043 2,200 11,000 310 m,p-Xylenes 1.3 <0.016 <0.011 <0.010 <0.0096 <0.012 NA NA NA <0.0086 4,500 19,000 440 ----- Methyl tert-butyl ether MTBE <0.37 <0.016 <0.011 <0.010 <0.0096 <0.012 NA NA NA <0.0086 39 190 39 n-Bu lbenzene 12 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 NS NS NS n-Pro lbenzene 12 <0.0078 <0.0057 <0.0050 0.0073 <0.0060 NA NA NA <0.0043 NS NS NS ----- Naphthalene 1.2 <0.016 <0.011 <0.010 <0.0096 <0.012 NA NA NA <0.0086 3.9 20 3.9 o-X lens <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 5,300 23,000 300 Iso ro ltoluene 2.7 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 NS NS NS sec-Bu lbenzene 4.3 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 NS NS NS ----- Styrene <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 6,500 38,000 1,000 tert-Bu lbenzene <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 NS NS NS Toluene <0.37 <0.0078 <0.0057 <0.0050 <0.0048 <0.0060 NA NA NA <0.0043 5,000 46,000 930 ----- Xylenes, totals 1.3 <0.016 <0.011 <0.010 <0.0096 <0.012 NA NA NA <0.0086 600 2,600 120 ----- SVOCs 8270C 2-Meth lna hthalene 2.5 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 310 4,100 62 Acena hthene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 3,400 33,000 680 Anthracene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 17,000 170,000 3,400 Benzo a anthracene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 0.15 2.1 0.15 Benzo a ene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 0.015 0.21 0.015 Benzo b fluoranthene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 0.15 2.1 0.15 Benzo ,h,i a lene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 NS NS NS Benzo k fluoranthene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 1.5 21 1.5 Bis 2-eth ]hex 1 hthalate <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA 0.55 <0.43 <0.37 35 120 35 Bu lbe 1 hthalate <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 260 910 260 Ch sene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 15 210 15 Di-n-bu 1 hthalate <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA 1 <0.37 <0.43 <0.37 6,100 1 62,000 1,200 Di-n-oc 1 hthalate <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 NS NS NS Dibenzo a,h anthracene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 0.015 0.21 0.015 Dibenzofuran <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 NS NS NS Fluoranthene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 2,300 22,000 460 Fluorene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 2,300 22,000 460 Indeno 1,2,3-cd rene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 0.15 2.1 0.15 ----- Naphthalene 1.8 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 3.9 20 3.9 Phenanthrene <0.52 <5.1 <0.41 <0.39 <0.40 <0.45 NA <0.37 <0.43 <0.37 NS NS NS Pyrene <0.52 <5.1 1 <0.41 <0.39 <0.40 <0.45 1 NA 1 <0.37 1 <0.43 <0.37 1,700 17,000 340 Metals 6010B Arsenic <0.79 15 1.6 <0.59 NA NA NA NA 3.0 0.39 1.6 4.4 1.6-180 Barium 270 35 220 91 NA 290 NA NA NA 130 15,000 190,000 3,000 4.1-420 Cadmium <0.39 0.4 <0.31 <0.30 NA <0.34 NA NA NA 0.52 70 810 14.0 0.54-5.8 Chromium 99 8.4 27 13 NA 12 NA NA NA 28 280 1400 24,000 2 - 150 Lead 6.5 20 23 5.5 NA 3.3 NA NA NA 84 400 800 400 7.2 - 52 Selenium 12 2.4 4.3 2.1 NA 6.9 NA NA NA 3.0 390 5,100 78 NS Silver <0.39 <0.39 0.31 <0.30 NA 0.36 NA NA NA 8.6 390 5100 78 NS Metals 7471A Mercury 0.044 <0.031 0.029 <0.024 NA <0.027 NA NA NA 0.32 6.7 28 1.3 0.02-0.16 MADEP-VPH C5-C8 Ali hatics NA NA NA NA NA NA <7.7 NA NA NA NS NS NS C9-Cl0 Aromatics NA NA NA NA NA NA <7.7 NA NA NA NS NS NS C9-C12 Ali hatics NA NA NA NA NA NA <7.7 NA NA NA NS NS NS MADEP-EPH Cl 1-C22 Aromatics NA NA NA NA NA NA <15 <11 <13 1 NA NS NS NS C19-06 Ali hatics NA NA NA NA NA NA <15 <11 <13 NA NS NS NS C9-C18 Ali hatics NA NA NA NA NA NA <15 <11 <13 NA NS NS NS Pesticides 8081A Organochloride Pesticides NA I NA I NA NA NA NA NA I NA NA NA NS NS NS ----- 1) EPA RSL = Environmental Protection Agency Regional Screening Levels for Chemical Contaminants at Super -fund Sites (September 2008) 2) NCDENR inactive Hazardous Sites Branch, Health Based Soil Remediation Goals, October, 2008, "Adapted from the 2008 USEPA Regional Screening Tables" 3) NC DENR Data Table, Background Metals in NC Soils and Groundwater, August 31, 2006 4) NS = Not Specified, BRL = Beneath Reporting Limit; NA = Not Analyzed 5) Combined O-, M- and P- Xylenes 6) Detections shown in Bold type 7) Shaded values exceed the NC DENR Health Based SRG for the compound shown Page 1 of 3 S:\A A -Master Projects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase IMF Phase II Ret,.&PTC-003 Phase It Tables Revised Jwe 25,2009 Hart & Hickman, PC Table 2 - Revision 1 Summary Analytical Data - Soil Brownfield Phase II Site Assessment Former Lexington Home Brands - Plant 1 Lexington, North Carolina H&H Job No. PTC-003 Boring Location AREA 1 AREA 2 Screening Levels Sample ID SB-16 SB-17 SB-20 SB-15 SB-21 SB-22 SB-23 SB-23 SB-24 MW-IA MW-2A MW-3A MW-4A SB-27 s EPA RSL t NCDENR (Soils) Sample Depth (ft) 2' 1' 0-1' 1' 0-1' 0-1' 0-1' 2-3' 1' 2' 1' 1' 2' 8-9' Lithology Silty Sand Silty Sand Sandy Clay Sandy Silt Coarse Sand Silty Clay Silty Sand Silty Sand Clayey Sand Sandy Silt Sandy Clay Sandy Clay Sandy Clay Sandy Silt C7 94 0 5n x M Date Collected 1/14/2009 1/14/2009 1/13/2009 1/14/2009 1/13/2009 1/13/2009 1/13/2009 1/13/2009 1/13/2009 1/12/2009 1/12/2009 1/12/2009 1/12/2009 1/13/2009 ro Units mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg mg kg x A Z Laboratory Parameters VOCs 8260B mg/kg 1 2 4-Trimeth lbenzene 0.024 0.0089 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.014 0.04 67 280 13 1 2-Dichloroethane <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 <0.0057 <0.0055 0.45 2.2 0.45 1 2-Dichloro ro ane <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 <0.0057 <0.0055 0.93 4.7 0.93 1 3 5-Trimedi lbenzene <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 <0.0057 0.0061 47 200 NS Acetone <0.062 0.27 <0.076 <0.0074 <0.056 <0.070 <0.064 <0.051 <0.054 <0.049 <0.041 <0.043 <0.057 <0.055 61,000 610,000 12,000 Benzene 0.1 0.0095 <0.0046 0.0054 <0.0034 <0.0042 <0.038 <0.0031 <0.0032 <0.0030 <0.0025 <0.0026 0.0055 0.013 1.1 5.6 1.1 Chloroform <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 <0.0057 <0.055 0.3 1.5 0.3 Eth lbenzene 0.021 0.01 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.0084 0.14 5.7 29 5.7 ----- Isopropyl ether IPE <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 1 <0.0043 <0.0057 <0.0055 1,200 5,100 NS Isopropylbenzene 0.059 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.18 0.037 2,200 11,000 310 ----- m,p-Xylenes 0.1 0.069 <0.015 <0.015 <0.011 <0.014 <0.013 <0.01 <0.011 <0.0099 <0.0082 <0.0086 0.059 0.028 4,500 19,000 440 ----- Methyl tert-butyl ether (MTBE) <0.012 <0.016 <0.015 <0.015 <0.011 <0.014 <0.013 <0.01 <0.011 <0.0099 <0.0082 <0.0086 <0.011 <0.011 39 190 39 n-Bu lbenzene <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.045 0.014 NS NS NS n-Pro lbenzene 0.014 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.081 0.13 NS NS NS ----- Naphthalene <0.012 <0.016 <0.015 <0.015 <0.011 <0.014 <0.013 <0.01 <0.011 <0.0099 <0.0082 <0.0086 5.9 0.049 3.9 20 3.9 o-X lens 0.017 1 0.014 <0.0076 <0.0074 1 <0.0056 <0.0070 <0.0064 <0.0051 1 <0.0054 <0.0049 <0.0041 <0.0043 0.0076 0.0094 1 5,300 23,000 300 Iso ro ltoluene <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 1 <0.0043 0.022 <0.0055 NS NS NS sec-Bu lbenzene <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.041 0.019 NS NS NS ----- Styrene <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 <0.0057 <0.0055 6,500 38,000 1,000 tert-Bu lbenzene <0.0062 <0.0081 <0.0076 <0.0074 <0.0056 <0.0070 <0.0064 <0.0051 <0.0054 <0.0049 <0.0041 <0.0043 0.012 <0.0055 NS NS NS Toluene 0.13 0.06 <0.0076 0.01 <0.0056 <0.0070 <0.0064 <0.0051 0.0085 <0.0049 <0.0041 <0.0043 0.025 0.077 5,000 46,000 930 X lenes,total' 0.117 0.114 <0.015 <0.015 <0.011 <0.014 <0.013 <0.01 <0.011 <0.0099 <0.0082 <0.0086 0.0666 0.0374 600 2,600 120 ----- SVOCs 8270C 2-Meth lna hthalene <0.42 <0.43 <0.41 <0.40 1.6 1 <0.39 <0.35 <0.37 1 <0.37 <0.42 <0.38 <0.38 <0.43 NA 1 310 4,100 62 Acena hthene <0.42 <0.43 <0.41 <0.40 2.0 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 3,400 33,000 680 Anthracene <0.42 <0.43 1 <0.41 <0.40 3.1 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 17,000 170,000 3,400 Benzo a anthracene <0.42 <0.43 1 <0.41 0.40 H 8.8 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 0.15 2.1 0.15 Benzo a ene <0.42 <0.43 <0.41 0.43 H 8.3 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 0.015 0.21 0.015 Benzo b fluoranthene <0.42 <0.43 <0.41 0.54 H 12 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 0.15 2.1 0.15 Benzo h i e lene <0.42 <0.43 <0.41 0.46 H 4.2 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA NS NS NS Benzo k fluoranthene <0.42 <0.43 <0.41 <0.40 3.4 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 1.5 21 1.5 Bis 2-eth lhex 1 hthalate <0.42 <0.43 15 1.9 H 190 5.3 7 0.45 130 <0.42 <0.38 <0.38 1.4 NA 35 120 35 Bu lben 1 hthalate <0.42 <0.43 <0.41 <0.40 <0.42 1 <0.39 <0.35 <0.37 1 0.4 <0.42 <0.38 <0.38 <0.43 NA 1 260 910 260 C sene <0.42 <0.43 <0.41 <0.40 8.5 1 <0.39 <0.35 <0.37 1 <0.37 <0.42 <0.38 1 <0.38 <0.43 NA 15 210 15 Di-n-bu 1 hthalate <0.42 <0.43 0.66 0.52 0.97 <0.39 0.45 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 6,100 62,000 1,200 Di-n-oc 1 hthalate <0.42 <0.43 1.7 <0.40 <0,42 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA NS NS NS Dibenzo a h anthracene <0.42 <0.43 <0.41 <0.40 1.1 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 0.015 0.21 0.015 Dibenzofuran <0.42 <0.43 <0.41 <0.40 2.0 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA NS NS NS Fluoranthene <0.42 <0.43 <0.41 0.57 24 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 2,300 22,000 460 Flumene <0.42 <0.43 <0.41 <0.40 1.9 <0.39 1 <0.35 <0.37 <0.37 1 <0.42 <0.38 <0.38 <0.43 NA 2,300 1 22,000 460 Indeno 1 2 3-cd ene <0.42 <0.43 <0.41 0.42 H 4.5 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 0.15 2.1 0.15 ----- Naphthalene <0.42 <0.43 <0.41 <0.40 6.1 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 3.9 20 3.9 Phenanthrene <0.42 <0.43 <0.41 0.43 23 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 1 <0.43 NA NS NS NS P ene <0.42 <0.43 <0.41 0.76 19 <0.39 <0.35 <0.37 <0.37 <0.42 <0.38 <0.38 <0.43 NA 1,700 17,000 340 Metals 6010B Arsenic 1.3 <0.65 NA 2.7 NA NA 2.9 <0.57 NA 0.76 1.8 1.0 2.4 NA 0.39 1.6 4.4 1.6-180 Barium 100 120 NA 130 NA NA 97 270 NA 520 85 43 68 NA 15,000 190,000 3,000 4.1420 Cadmium <0.32 <0.33 NA 0.4 NA NA <0.27 <0.28 NA <0.32 <0.29 <0.29 <0.33 NA 70 810 14.0 0.54-5.8 Chromium 31 36 NA 30 NA NA 19 <0.28 1 NA 50 24 24 46 NA 280 1400 24,000 2 - 150 Lead 10 5.3 NA 62 NA NA 21 5.2 NA 4.8 6.4 4.9 14 NA 400 800 400 7.2 - 52 Selenium 7.0 2.9 NA 5.7 NA NA 3 1.1 NA 4.6 3.0 3.6 13 NA 390 5100 78 NS Silver 0.41 <0.33 NA 3.1 NA NA 0.41 <0.28 NA 0.55 <0.29 0.38 1 0.58 NA 390 5100 78 NS Metals 7471A Mercury 0.085 <0.026 NA 0.1 NA NA 0.098 <0.023 NA <0.026 <0.023 <0.023 0.11 NA 6.7 28 1.3 0.02-0.16 MADEP-VPH C5-C8 Ali hatics NA NA NA NA NA NA NA NA NA NA NA NA NA <5.9 NS NS NS C9-C10 Aromatics NA NA NA NA NA NA NA NA NA NA NA NA NA <5.9 NS NS NS C9-C12 Ali hatics NA NA NA NA NA NA NA NA NA NA NA NA NA <5.9 NS NS NS MADEP-EPH Cll-C22Aromatics NA NA NA NA NA NA NA NA NA NA NA NA NA NA NS NS NS C19-C36Ali hatics NA NA NA NA NA NA NA NA NA NA NA NA NA NA NS NS NS C9-C18 Ali hatics NA NA NA NA NA NA NA NA NA NA NA NA NA NA NS NS NS Pesticides 8081A Organochloride Pesticides NA NA BRL NA BRL BRL NA NA BRL NA NA NA NA NA NS NS NS ----- 1) EPA RSL - Environmental Protection Agency Regional Screening Levels for Chemical Contaminants at Superfund Sites (September 2008) 2) NCDENR inactive Hazardous Sites Branch, Health Based Soil Remediation Goals, October, 2008, "Adapted from the 2008 USEPA Regional Screening Tables' 3) NC DENR Data Table, Background Metals in NC Soils and Groundwater, August 31, 2006 4) NS = Not Specified, BRL = Beneath Reporting Limit; NA =Not Analyzed 5) Combined O-, M- and P- Xylenes 6) Detections shown inBold type 7) Shaded values exceed the NC DENR Health Based SRG for the compound shown 8) Soils originating from SB-27 were only screened against the NCDENR Residential MSCC's (Not Shown) Page 2 of 3 S:\AAA-Master Prjects\Piedmont Triad COG - PTC\PTC-003 Brownfield Phase II\BF Phase II Rep.&PTC-003 Phase II Tables Revised June 25,2009 Hart& Hickman, PC Table 2 - Revision 1 Summary Analytical Data - Soil Brownfield Phase II Site Assessment Former Lexington Home Brands - Plant 1 Lexington, North Carolina H&H Job No. PTC-003 Boring Location Area 3 Screening Levels Sample ID SB-28 SB-29 SB-30 SB-31 SB-32 SB-33 SB-34 SB-35 SB-36 SB-37 SB-38 s SB-39 SB-40 EPA RSL NCDENR (Soils) Sample Depth (ft) 14-15' 14-15' 3' 3' 3' 3' 3' 10-11, 3' 3' 3' 3' 3' a o Lithology Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Sandy Silt Silty Sand Sandy Silt 7i� Date Collected 1/14/2009 1/13/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/13/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 0 q 5n u Units mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kgv Z Laboratory Parameters VOCs 8260B mg/kg 1 1 1-Trichloroethane NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 9,000 39,000 680 11-Dichloroethane NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 3.4 17 3.4 11-Dichloroethene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 250 1100 50 1 2 4-Trimedi lbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 67 280 13 12-Dichloroethane NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 0.45 2.2 0.45 1 2-Dichloro ro ane NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 0.93 4.7 0.93 1 3 5-Trimedi lbenzene NA NA NA NA <0.0055 <0.0049 1 <0.0062 <0.0078 <0.0056 1 <0.0049 NA <0.0057 1 <0.0049 47 200 NS Acetone NA NA NA NA <0.055 <0.049 <0.062 <0.078 <0.056 <0.049 NA <0.057 <0.049 61,000 610,000 12,000 Benzene NA NA NA NA <0.0033 <0.0030 <0.0037 <0.0047 <0.0033 <0.0029 NA <0.0034 <0.0030 1.1 5.6 1.1 Chloroform NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 0.3 1.5 0.3 Eth lbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 5.7 29 5.7 ----- Isopropyl ether IPE NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 1,200 5,100 NS Isopropylbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 2,200 11,000 310 ----- m,p-Xylenes NA NA NA NA <0.011 <0.0099 <0.012 <0.016 <0.011 <0.0098 NA <0.011 <0.0098 4,500 19,000 440 ----- Methyl tert-butyl ether MTBE NA NA NA NA <0.011 <0.0099 <0.012 <0.016 <0.011 <0.0098 NA <0.011 <0.0098 39 190 39 n-Butylbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 NS NS NS n-Propylbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 NS NS NS ----- Naphthalene NA NA NA NA <0.011 <0.0099 <0.012 <0.016 <0.011 <0.0098 NA <0.011 <0.0098 3.9 20 3.9 o-X lens NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 5,300 23,000 300 p-Isopropyltoluene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 NS NS NS sec-Butylbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 NS NS NS Styrene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 6,500 38,000 1,000 tert-Butylbenzene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 NS NS NS Toluene NA NA NA NA <0.0055 <0.0049 <0.0062 <0.0078 <0.0056 <0.0049 NA <0.0057 <0.0049 5,000 46,000 930 ----- X lens totals NA NA NA NA <0.011 <0.0099 <0.012 <0.016 <0.011 <0.0098 NA <0.0057 <0.0098 600 2,600 120 ----- SVOCs 8270C 2-Methyl ahthalene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 310 4,100 62 Acena hthene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 3,400 33,000 680 Anthracene <0.37 <0.37 <0.40 <0.41 1 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 1 <0.37 17,000 170,000 3,400 Benzo a anthracene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 1 <0.37 0.15 2.1 0.15 Benzo a rene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 0.015 0.21 0.015 Benzo fluoranthene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 0.15 2.1 0.15 Benzo h i e lene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 NS NS NS Benzo k fluoranthene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 1.5 21 1.5 Bis 2-eth ]hex 1 hthalate <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 35 120 35 Bu lbe l hthalate <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 260 910 260 C sene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 15 210 15 Di-n-bu 1 hthalate <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 6,100 62,000 1,200 Di-n-oc 1 hthalate <0.37 <0.37 <0.40 1 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 NS NS NS Dibenzo a h anthracene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 0.015 0.21 0.015 Dibenzofuran <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 NS NS NS Fluoranthene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 2,300 22,000 460 Fluorene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 2,300 22,000 460 Indeno 1 2 3-cd rene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 0.15 2.1 0.15 ---- Naphthalene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 1 <0.43 NA <0.45 <0.42 <0.39 <0.37 1 <0.37 3.9 20 3.9 Phenanthrene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 1 <0.37 NS NS NS ene <0.37 <0.37 <0.40 <0.41 <0.38 <1.9 <0.43 NA <0.45 <0.42 <0.39 <0.37 <0.37 1,700 17,000 340 Metals 6010B Arsenic NA NA NA NA NA NA NA NA NA NA NA NA NA 0.39 1.6 4.4 1.6-180 Barium NA NA NA NA NA NA NA NA NA NA NA NA NA 15,000 190,000 3 000 4.1-420 Cadmium NA NA NA NA NA NA NA NA NA NA NA NA NA 70 810 14.0 0.54-5.8 Chromium NA NA NA NA NA NA NA NA NA NA NA NA NA 280 1400 24 000 2- 150 Lead NA NA NA NA NA NA NA NA NA NA NA NA NA 400 800 400 7.2 - 52 Selenium NA NA NA NA NA NA NA NA NA NA NA NA NA 390 5100 78 NS Silver NA NA NA NA NA NA NA NA NA NA NA NA NA 390 5100 78 NS Metals 7471A Mercury NA NA NA NA NA NA NA NA NA NA NA NA NA 6.7 28 1.3 0.02-0.16 MADEP-VPH C5-C8 Ali hatics NA NA NA NA NA NA NA <7.6 NA NA NA NA NA NS NS NS C9-C10 Aromatics NA NA NA NA NA NA NA <7.6 NA NA NA NA NA NS NS NS C9-C12 Ali hatics NA NA NA NA NA NA NA <7.6 NA NA NA NA NA NS NS NS MADEP-EPH C I I -C22 Aromatics <11 <11 <12 <12 NA NA NA NA NA NA 42 NA NA NS NS NS C19-C36Ali hatics <11 <11 <12 <12 NA NA NA NA NA NA 42 NA NA NS NS NS C9-C18 Ali hatics <11 <11 <12 <12 NA NA NA NA NA NA <l2 NA NA NS NS NS Pesticides 8081A Or anochloride Pesticides NA NA NA NA NA NA NA NA NA NA NA NA NA NS NS NS 1) EPA RSL = Environmental Protection Agency Regional Screening Levels for Chemical Contaminants at Superfund Sites (September 2008) 2) NCDENR inactive Hazardous Sites Branch, Health Based Soil Remediation Goals, October, 2008, "Adapted from the 2008 USEPA Regional Screening Tables" 3) NC DENR Data Table, Background Metals in NC Soils and Groundwater, August 31, 2006 4) NS = Not Specified, BRL = Beneath Reporting Limit; NA = Not Analyzed 5) Combined 0-, M- and P- Xylenes 6) Detections shown inBold type 7) Shaded values exceed the NC DENR Hea&.ed SRG for the compound shown Page 3 of 3 8) Soils originating from SB-38 were only screened against the NCDENR Residential MSCC's (Not Shown) S:\AAA-Master Prgects\Pxe .nt Triad COG - PTC\PTC-003 Brownfield Phase II\BF Phase II Repon\PTC-003 Phase 11 Tables Revised June 25, 2009 Hart & Hickman, PC Table 4 - Revision 1 Summary of Analytical Data - Groundwater Brownfield Phase II Site Assessment Former Lexington Home Brands - Plant 1 Lexington, North Carolina H&H Job No. PTC-002 Sample Location Area 1 Area 2 Area 3 Area 1 - Permanent Wells Screening Levels Sample ID SB-2 SB4 SB-6 SB-7 SB-10 SB-14 SB-27 SR-29 SB-35 NM-lA MW-2A MW-3A MW-4A Target GW Date Collected 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/14/2009 1/23/2009 1/23/2009 1/23/2009 1/23/2009 NC DENR Federal Concentrations for Units N N N N N N N 2L Limit MCL Vapor Intrusion Range Laboratory Parameters VOCs 8260B µg L 1 1 1-Trichloroethane 1.2 <0.5 <5.0 <0.5 <0.5 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 <0.5 200 200 3,100 to 3,100 1 1-Dichloroethane 0.59 <0.5 <5.0 <0.5 <0.5 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 <0.5 70 NS 2,200 to 2,200 1 1-Dichloroethene 1.1 <0.5 <5.0 <0.5 1.6 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 <0.5 7 7 190 to 190 1 2,4-Trimeth lbenzene <1.0 <1.0 45 1.4 <1.0 <1.0 810 NA 1.3 <0.5 <0.5 <0.5 7.7 350 NS 1 2-Dichloroethane 7.8 <0.5 <5.0 <0.5 61 <0.5 25 NA <0.5 <0.5 <0.5 <0.5 <0.5 0.38 5 5 to 230 1 2-Dichloro ro ane <0.5 <0.5 <5.0 <0.5 0.97 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 <0.5 0.51 5 1 3 5-Trimeth (benzene <0.5 <0.5 22 0.9 <0.5 <0.5 230 NA <0.5 <0.5 <0.5 <0.5 3.2 350 NS Acetone <5.0 <5.0 130 20 <5.0 1000 <200 NA <5.0 <5.0 <5.0 <5.0 <5.0 700 NS Benzene 46 1 0.55 22 <0.5 11 3.7 1 4,800 NA 1 <0.5 <0.5 1 <0.5 <0.5 1 <0.5 1 5 5 to 140 Chloroform <0.5 <0.5 <5.0 <0.5 <0.5 <0.5 <20 NA 1.5 <0.5 <0.5 <0.5 <0.5 70 NS Eth lbenzene <0.5 <0.5 360 1.3 <0.5 <0.5 1,100 NA <0.5 <0.5 <0.5 <0.5 0.58 550 700 700 to 700 Isopropyl ether IPE 1.2 <0.5 <5.0 0.52 5.8 <0.5 71 NA <0.5 <0.5 <0.5 <0.5 <0.5 70 NS lsopropylberuene 1.3 1.4 47 8.0 <0.5 <0.5 83 NA <0.5 <0.5 <0.5 <0.5 3.8 70 NS m -X lens <1.0 <1.0 2,000 6.8 <1.0 <1.0 770 NA <1.0 <1.0 <1.0 <1.0 <1.0 530 NS Methyl tert-butyl ether MTBE 29 <0.5 <5.0 <0.5 2.5 <0.5 870 NA <0.5 <0.5 <0.5 <0.5 <0.5 200 NS 120,000 to 120,000 n-Bu lbenzene <1.0 <1.0 <10 <1.0 <1.0 <1.0 66 NA <1.0 <1.0 <1.0 <1.0 1.3 70 NS n-Pro lbenzene <0.5 <0.5 17 1.6 <0.5 <0.5 240 NA <0.5 <0.5 <0.5 <0.5 1.5 70 NS Naphthalene <2.0 1 <2.0 39 3.7 <2.0 <2.0 1 600 NA <2.0 1 <2.0 <2.0 <2.0 170 21 NS 150 to 150 o-X lens <0.5 1.2 200 2.7 <0.5 1.2 58 NA <0.5 <0.5 <0.5 <0.5 <0.5 530 NS -Iso ro ltoluene <0.5 <0.5 <5.0 <0.5 <0.5 <0.5 42 NA <0.5 <0.5 <0.5 <0.5 3.9 NS NS sec-Bu lbenzene <0.5 <0.5 10 1.1 <0.5 <0.5 49 NA <0.5 <0.5 <0.5 <0.5 0.86 70 NS Styrene <0.5 <0.5 10 <0.5 <0.5 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 <0.5 100 100 tert-Bu lbenzene <0.5 <0.5 <5.0 <0.5 <0.5 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 <0.5 70 NS Tetrachloroethenc <0.5 <0.5 <5.0 <0.5 <0.5 <0.5 <20 NA <0.5 <0.5 <0.5 <0.5 1.1 0.7 5 Toluene <0.5 2.6 30 1 25 1.4 25 77 NA 0.94 6.4 <0.5 0.71 0.56 1,000 1,000 1,500 to 1,500 Trichloroethene <0.5 <0.5 <5.0 <0.5 <0.5 <0.5 <20 NA <0.5 1 <0.5 <0.5 <0.5 1 0.51 2.8 5 Xylenes, total <1.0 1.2 0 9.5 <1.0 1.2 NA <1.0 <1.0 <1.0 <1.0 <1.0 530 10,000 NS SVOCs 8270C 2-Meth Ina hthalene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 14,d NS 3,300 to 3,300 Acena hthene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 29 80 NS NS Anthracenc <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 2100 NS NS Benzo a anthracene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 0.0479 NS NS Benzo a ene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 0.00479 0.2 NS Benzo b Fuoranthene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 0.0479 NS NS Benzo(g,h,i)perylene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 210 NS NS Benzo k Fuoranthene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 0.479 NS NS Bis 2-eth lhex I hthalate <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 2.5 6 NS Butylbenzylphthalatc <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 100 NS NS Chrysenc <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 4.79 NS NS Di-n-butylphthalatc <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 700 NS NS Di-n-octylphthalatc <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 140 NS NS Dibenzo a h anthracenc <10 <10 <11 <10 I <11 <10 NA <11 NA <10 <9.7 1 <10 <10 0.0047 1 NS NS Dibenzofuran <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 13 28 NS NS Fluoranthene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 280 NS NS Fluorene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 18 280 NS NS Indeno 1 2 3-cd ene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 0.0479 NS NS Naphthalene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 21 NS 150 to 150 Phenanthrene <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 15 210 NS NS Pyrenc <10 <10 <11 <10 <11 <10 NA <11 NA <10 <9.7 <10 <10 210 NS I NS Metals 6010B Arsenic <10 27 <10 <10 <10 NA NA NA <10 I <10 <10 <10 50 10 NS Barium 93 330 110 330 79 190 NA NA NA 140 48 55 210 2,000 2,000 NS Cadmium <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 NA NA NA <1 <1.0 <1 <1 1.75 5 NS Chromium <5.0 22 8.2 15 <5.0 <5.0 1 NA NA NA 10 <5.0 <5 <5 50 NS NS Lead <5.0 55 <5.0 <5.0 NA NA NA <5 <5.0 <5 <5 NS Selenium <20 <20 <20 <20 <20 <20 NA NA NA <20 <20 <20 <20 50 50 NS Silver <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 NA NA NA <5 <5 <5 <5 17.5 NS NS Metals 7471A Mercury <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NA NA NA <0.2 <0,2 1 <0.2 <0,2 1.05 2 NS MADEP-VPH C5-C8 Ali hatics NA NA NA NA NA NA 15,000 NA <50 NA NA NA NAIn C9-C10 Aromatics NA NA NA NA NA NA 840 NA <50 NA NA NA NA C9-C12 Ali hatics NA NA NA NA NA NA 4,100 NA <50 NA NA NA NA MADEP-EPH CI I-C22 Aromatics NA NA NA NA NA NA NA <100 NA NA NA NA NA C19-C36 Ali hatics NA NA NA NA NA NA NA <100 NA NA NA NA NA C9-C18 Ali hatics NA NA NA NA NA NA NA <100 NA NA NA NA NA Pesticides 8081A Organochloride Pesticides NA NA NA NA NA NA NA I NA NA NA NA BRL I BRL 1. NC DENR 2L Limit = Maximum Contaminant Concentration defined by North Carolina Administrative Code (NCAC) Title 15A, Subchapter 2L, Section .0202 (Water Quality Standards for Class GA Groundwater). 2. MCL = Maximum Contaminant Level 3. EPA RSL= US Environmental Protection Agency Regional Screening Levels for Chemical Contaminants at Superfund Sites (September, 2008) 4. Target groundwater concentration corresponding to target indoor air generic screening levels (EPA OSWER 2002); Low and high range for Risk=1x11)1x10-' and 1x10' 5. VOCa= Volatile Organic Compounds; SVOCs - Semi -volatile Organic Compounds; PAHs - Polynuclear Aromatic Hydrocarbons; NA - Not Analyzed; NS - Not Specified J = Estimated value - analyte detected at a concentraton less than the reporting limit and greater than or equal to the method detection limit. M = Surrogate recoveries or matrix spike recoveries were outside control limits due to suspected matrix interference. E= Estimated concentration greater than the instrument calibration range. The concentration is less than the reporting limit for a medium level analysis. BRL=Beneath Reporting Limit. 6. Shaded value indicates concentration in excess of 2L or Federal MCL screening level S:\A -Master Proiecls\Piedmont Triad COG - PTO( TC-003 Broomfield Phase II\BF Phase II Report\PTC-003 Phase II Tables Revised June 25, 2009 Hart & Hickman, PC SB-7 1,2,4-TMB 1.4 1,3,5-TMB 0.9 Acetone 20 Ethylbenzene 1.3 IPE 0.52 Isopropylbenzene 8.0 m,p-Xylenes 6.8 n-Propylbenzene 1.6 IN 3.7 o-Xylenes 2.7 sec-Bhylbenzene 1.1 Toluene 25 Xylenes, total 9.5 Barium 330 Chromium 15 Lead 29 SB-10 1,1-DCE 1.6 1,2-DCA 61 1,2-Dichloropropane 0.97 Benzene 11 IPE 5.8 MT 3E 2.5 Toluene 1.4 Arsenic 160 Barium 79 SB-14 Benzene 3.7 o-Xylenes 1.2 Toluene 25 Xylenes, total 1.2 Barium 190 MW 2A Barium 48 r� M W-4A 1,2,4-TMB 7.7 1,3,5-TMB 3.2 Ethylbenzene 0.58 lsopropylbenzene 3.8 u-Bhylbenzene 1.3 n-Propylbenzene 1.5 [Naphthalene 170 p-Isopropyltoluene sec-Bhylbenzene 0.86 Tetrachloroethene Toluene 0.56 Trichloroethene 0.51 2-Methylnaphthalene 65 Acenaphthene 29 Dibenzofuran 13 Fluorene 18 Phenanthrene 15 Barium 210 SB-2 Parking Lot 1,1,1-TCA 1.2 1,1-DCA 0.59 1,1-DCE 1.1 Retaininq Moll 1,2-DCA 7.8 Benzene 46 SB-1® SB-® ai ' g Wall/Berm IPE 1.2 Isopropylbenzene 1.3 t~ p MTBE 29 t W j 0 Barium 93 Q Z SB-16 O�'i SB-4 Former o STORAGE WAR # 8 Hazardous Waste o Benzene Isopropylbenzene 0.55 1.4 Storage Area Sg- o-Xylenes 1.2 SB-10 ump Toluene 2.6 etii-nin Wo lBerm o Xylenes, total 1.2 SB-4 AST Arsenic 27 Z k Barium 330 ® SB- 7 7 Chromium 22 _ 2 SB-6 ILead Retaining Wall/Berm LEGEND _ SB-6 m SB-14 1,2,4-TMB 45 O SOIL BORING RAMP LDOCKG RAMP 1,3,5-TMB 22 * TEMPORARY WELL Gate Acetone Benzene 130 PERMANENT WELL MW-1 A STUDY AREA # 1 Ethylbenzene 360 SSB-15 Fence W Isopropylbenzzne 47 2,000 NOTES AIR SLOWDOWN RAMP � Z nip-Xylenes n-Propylbenzene 17 Concentrations In ug L. MW-2A SB-17 Q Naphthalene 39 Shaded Values exceed NCDENR ® SB-20 o-X lens 200 2L Groundwater Standards sec-Butylbenzene 10 W Styrene 10 Toluene 30 Xylenes, total 2,200 FORMER FINISHING PLANT Barium 110 Chromnnn 82 Loading Dock /I TRANSFORMER PAD MW-3A MW � BLDG. 16 S. RAILROAD STREET / Lead 5 0 MW-1A Toluene 6.4 Barium 140 Chromium 10 APPROXIMATE 0 50 100 iiiiiiia SCALE IN FEET M W-3A 0.71 W E 55 GROUNDWATER ANALYTICAL DATA STUDY AREA 1 PROJECT PLANT 1 - LEXINGTON HOME BRANDS 411 S. SALISBURY STREET LEXINGTON, DAVIDSON COUNTY, NC Aplaft & iil{rimIRLL 3334 Hillsborough Street Raleigh, North Carolina 27607 A PaoFEssi- Coevoa - 919-847-4241(p) 919-847-4261(o DATE: 06/25/2009 REVISION NO. 1 JOB NO: PTC-003 FIGURE NO. 8 Appendix D Laboratory Analytical Data and Data Validation Summary Data Validation Summary In accordance with the December, 2008 Site QAPP, the field and laboratory analytical data were subjected to review, verification, and validation to ensure that the quality and validity of the data were acceptable for the stated data quality objectives. A discussion of the field data, laboratory data, and variations from the procedures outlined in the approved QAPP for the subject site is presented below. Field Procedures The field procedures for sampling, decontamination, calibration, chain -of -custody forms, etc. were followed in accordance with the QAPP procedures, with seven (7) exceptions: • The QAPP called for the sampling of five (5) existing monitoring wells within Study Area 2, associated with the former location of a 550 gallon gasoline UST from which a release was confirmed and later evaluated, independent of this Phase II SAR. It was discovered that these five wells had been abandoned prior to the initiation of Phase II Assessment activities; therefore, the wells were not sampled. • The QAPP called for the collection of samples from soil borings SB-8 and SB-9, associated with the former locations of a 3,000 gallon thinner UST (SB-8) and a 7,000 gallon naphtha UST (SB-9). As groundwater was found to be less than 3 feet (ft) beneath land surface (bls), the collection of these samples from their target samples depths (13-14 ft bls for SB-8 and 7-8 ft bls in SB-9) would have yielded samples in the saturated zone, and the data for the samples would have been of no value. For this reason, neither of these borings were completed. • The presence of groundwater at a shallow depth at the original intended location of boring SB-3 prompted the relocation of this boring adjacent to a drainage structure between borings SB-1 and SB-2. D-1 • The QAPP called for the sampling of soils at the locations of soil borings SB-4 and 5. Groundwater was encountered within 1 foot of surface grade in each of these borings, therefore soil samples were not obtained. • The QAPP called for the collection of samples from hand auger borings SB-18, 19, 25 and 26. Upon attempting to complete these borings, it was found that the crawl space of the former finishing plant was underlain by a concrete slab, therefore these samples were not obtained. • The QAPP also called for the collection of two (2) samples from hand auger borings SB- 20, 21, 22 and 24. Groundwater was found in each of these borings within 2 ft. of surface grade, therefore, only a single (shallow) soil sample was retained from these borings. • The locations of borings SB-36 and 37 (originally slated for completion near the southeastern portion of the wood processing area in Study Area 3) were altered to evaluate the locations of two vaults located within the building. These vaults were not identified during the Phase I ESA, as they had been covered with equipment and/or debris which have since been removed. A field audit was not performed due to the brevity and limited scope of sampling activities. Field audits were optional per the QAPP. D-2 Laboratory A review of the analytical laboratory data is provided below. • Samples shipped to Prism Laboratories associated with this project were received at the laboratory in good condition, within the proper temperature range, were properly preserved, and proper sample volumes were available for analysis. • Chain -of -custody protocol was properly maintained. • The requested laboratory analyses were performed by the laboratory on each sample. Ground Water Samples • The laboratory supplied trip blank samples to accompany all groundwater samples submitted for the performance of this project. Each trip blank sample was analyzed by EPA Method 8260B. Data for trip blank samples associated with this project did not indicate the presence of targeted compounds at levels above the method reporting limit. • No target compounds were reported above reporting limits in the method blanks for the ground water samples. • Laboratory control samples and matrix spike samples for the water analyses were within laboratory control limits. • For laboratory batch ID # Q38858, EPA Method 8270C groundwater analysis, the recovery for the matrix spike (MS) and matrix spike duplicate (MSD) samples associated with the compound pentachlorophenol were outside the control limits. The laboratory control sample (LCS) had acceptable recovery. The compound was not detected in any D-3 samples submitted within the sample batch at levels exceeding the method reporting limit. • For laboratory batch ID # Q38661, EPA Method 8270C groundwater analysis, the recovery for the matrix spike (MS) and matrix spike duplicate (MSD) samples associated with the compound pentachlorophenol were above the control limits. The laboratory control sample (LCS) had acceptable recovery. The compound was not detected in any samples submitted within the sample batch at levels exceeding the method reporting limit. • For laboratory batch ID # Q38641, EPA Method 7471A groundwater analysis, the recovery for the matrix spike (MS) and matrix spike duplicate (MSD) samples associated with the element mercury were outside the control limits. The laboratory control sample (LCS) had acceptable recovery. The compound was not detected in any samples within the sample batch at levels exceeding the method reporting limit. Soil Samples • No target compounds were reported above reporting limits in the method blanks for the soil sample analyses associated with this project. • Several compounds were reported with an "H" qualifier in the EPA 8270C analysis associated with sample SB-15. The "H" qualified indicates that the compounds were reported at estimated concentrations with a high bias. Analytes in this sample yielded results that were consistently higher than what was observed in internal standards (which produced area response below acceptable QC limits). Compounds detected in this sample may have otherwise been non -detect, because they were detected slightly above relative detection limits. Compounds benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, and indeno(1,2,3-cd)pyrene were detected slightly above detection limits, and were subsequently above relative SRGs. SRGs are less than detection limits for these compounds. • For laboratory batch ID # Q38605, EPA Methods 8260B and 8270C soils analysis, MS and MSDs were not available for reporting. LCS has acceptable recoveries for each method. • For laboratory batch ID # Q38578, MS for barium: The sample concentration was too high for recovery evaluation. • For laboratory batch ID # Q38578, MS for chromium: The MS and MSD recovery were outside the control limits. Matrix interference is suspected. Post digestion spike recovery (72%) is outside the acceptable limits (80-120%). • For laboratory batch ID # Q38578, MS for chromium: The MS and MSD recovery were outside the control limits. Matrix interference is suspected. • For laboratory batch ID # Q38578, MSD for chromium: MSD recovery was outside the control limits. • For laboratory batch ID # Q38578, MSD for lead: MSD recovery was outside the control limits. • For laboratory batch ID # Q38598, LCS for mercury: No MS/MSD with batch - LCS had acceptable recovery. • For laboratory batch ID # Q38673, MSD for mercury: MSD recovery was outside control limits. Serial dilution (5x) difference (25%) was greater than the control limit (10%). Post digestion spike recovery of 115% was well within acceptable control limits. Matrix interference suspected. D-5 • For laboratory batch ID # Q38630, Method Blank (MB) for chromium and lead: MB was greater than 1/2 the reporting limit, but samples are greater than 1 Ox the MB. • For laboratory batch ID # Q38630, MS for arsenic, barium, cadmium, lead, selenium and silver: MS recovery was outside the control limits. Matrix interference is suspected. • For laboratory batch ID # Q38630, MSD for arsenic, cadmium, chromium, lead, selenium and silver: MSD recovery was outside the control limits. Review of laboratory data revealed a disparity between laboratory reporting limits and NCDENR Health -Based SRGs in soil samples analyzed for SVOCs. The disparity arose directly from reporting limits being greater than SRGs. This is noteworthy because SVOCs may have been present in soil samples at concentrations above SRGs yet below reporting limits (non -detect). The compounds that fall within this range are benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, dibenzo(a,h)anthracene, and indeno(1,2,3-cd)pyrene. After review of the data and laboratory consultation, it was found that for SVOCs analyzed by EPA Method 8270, standard detection limits result from the sensitivity of laboratory equipment and are intrinsically greater than the SRGs in question. Reporting limits for SVOCs found in the following appendix are the lowest limits the analytical method and laboratory equipment could produce. Upon analytical data review, verification, and discussions with laboratory personnel, Hart & Hickman determines that these data are valid and useful for the purposes described in the QAPP. O