2021.04.21_Chemours VEN Report

Intended for
The Chemours Company – Fayetteville, North Carolina

Document type
Report

Date
April 2021

SOURCE EMISSIONS
TESTING OF THE VINYL
ETHERS NORTH CARBON
BED

Ramboll
7600 Morgan Road
Liverpool, NY 13090
USA

T 315-637-2234
F 315-637-2819
https://ramboll.com

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SOURCE EMISSIONS TESTING OF THE VINYL ETHERS NORTH
CARBON BED

Project name PFAS Emissions Testing
Project no. 1940100745
Recipient Christel Compton
Document type Report
Version 1
Date April 21, 2021
Prepared by Patrick Grady, Project Associate
Checked by David Ostaszewski, PE, Senior Managing Engineer

Ramboll
7600 Morgan Road
Liverpool, NY 13090
USA

T 315-637-2234
F 315-637-2819
https://ramboll.com

I\\Ramashfile01\RAM_Projects\Chemours.1088211\1940100745.Chemours-Fayettevill\Docs\Reports\VEN\VEN Final Report.Docx

________________________________
Patrick Grady
Project Associate
Ramboll

________________________________
David Ostaszewski, PE
Senior Managing Engineer
Ramboll

This report has been reviewed and to the best of our knowledge the report is complete, and the results presented herein are accurate, error free, legible, and representative of the actual emissions measured during testing.

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CONTENTS
1. Introduction and Background 3
Testing Objective 3
Emissions Testing Program Participants 3
2. Process Description 5
Process Description 5
Operating Conditions During Testing 5
3. Summary of Test Program 6
Test Program Summary 6
4. Sampling and Analytical Procedures 7
Test Methods 7
Sampling Locations 7
Gas Velocity and Volumetric Flow Rate 7
Oxygen and Carbon Dioxide Concentrations 8
Moisture Content 8
HFPO-DA Emissions 8
4.6.1 HFPO-DA Sample Train and Equipment Preparation 9
4.6.2 HFPO-DA Sample Train Recovery 9
5. Emissions Test Results 10
Emission Test Results 10
Discussion and Conclusion 10
6. Quality Assurance/Quality Control 11
Equipment Calibration 11
Equipment Leak Checks 11
Reagent Blanks and Field Blanks 12
Test Data and Report Review 12

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LIST OF TABLES
1. Summary of Emission Test Results
LIST OF APPENDICES
A. Process Operating Data
B. Schematic of the Test Locations
C. Field Data and Calculations
D. Laboratory Data
E. Equipment Calibration Data
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1. INTRODUCTION AND BACKGROUND
Ramboll Americas Engineering Solutions, Inc. (Ramboll) was retained by The Chemours Company
(Chemours) to conduct source emissions testing at its facility located in Fayetteville, North
Carolina. Ramboll has prepared the following test report summarizing the results of the testing
on behalf of Chemours.
Testing Objective

As provided in their Title V Air Permit, Chemours is required to evaluate hexafluoro-propylene
oxide-dimer acid (HFPO-DA) emissions from a carbon bed adsorber at the Fayetteville Works
facility. The objective of this test program was to collect field sample data from the inlet and
outlet to the carbon bed serving the Vinyl Ethers North (VEN) process area to determine carbon
bed replacement frequency.

The source emissions test program was performed on March 9, 2021. Messrs. Patrick Grady, Jeff
Sheldon, Antonio Anderson and Brian Goodhile and Ms. Samantha Waters of Ramboll conducted
the emissions testing. Ms. Christel Compton and Mr. Edward Vega coordinated process operations
with the emissions testing. There were no representatives from any of the regulatory agencies
present to observe the field test program.

This report presents a description of the sources tested, a summary of the scope of work
conducted, sampling methods used, QA/QC procedures, and emission test results. The following
section lists the testing program’s participants and their contact information.
Emissions Testing Program Participants

Facility

Name: The Chemours Company

Site Address: 22828 Hwy 87 W
Fayetteville, NC 28306

Contact: Christel E. Compton

e-mail: [e-mail]

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Source Testing Firm

Name: Ramboll

Address: 7600 Morgan Road
Liverpool, NY 13090

Contact: Patrick Grady

e-mail: [e-mail]

Sample Analysis Laboratory

Name: Eurofins TestAmerica, Knoxville

Address: 5815 Middlebrook Pike
Knoxville, Tennessee 37921

Contact: Courtney Adkins

e-mail: [e-mail]

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2. PROCESS DESCRIPTION
This section provides a description of the VEN process.
Process Description

VEN is part of the fluoromonomer area at the Fayetteville facility. This area produces
fluorocarbon compounds used to produce Chemours products, such as Nafion® Krytox® and
Viton®. Indoor air fugitive emissions from VEN are vented to a carbon bed which is then vented
to atmosphere through the Division Stack. Process emissions from VEN are directed to a thermal
oxidizer.
Operating Conditions During Testing

Source emissions testing was performed during normal operations of the VEN process. Facility
personnel monitored and recorded process operations during the testing. Copies of the operating
data were provided to Ramboll and are included in Appendix A of this report.

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3. SUMMARY OF TEST PROGRAM
This section provides a summary of the testing scope of work conducted. Test methods used
during the sampling program can be found in Section 4 of this report.
Test Program Summary

Emissions testing was conducted simultaneously at the inlet and outlet of the VEN carbon bed
and the Division Stack serving VEN in order to evaluate potential emissions and removal
efficiencies of HFPO-DA. The testing at each location was conducted in triplicate and each test
run was 96 minutes in duration. Results of the source emission testing are reported in units of
milligrams per dry standard cubic meter (mg/dscm) and pounds per hour (lb/hr).

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4. SAMPLING AND ANALYTICAL PROCEDURES
This section provides a description of the test methods that were utilized during the test
program.
Test Methods

The test procedures were conducted in accordance with the most recent updates to the United
States Environmental Protection Agency (USEPA) Reference Methods (RM) described in 40 CFR
60; Appendix A.

RM 1: Sample and velocity traverses for stationary sources
RM 2: Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)
RM 3: Determination of oxygen and carbon dioxide concentrations in emissions from
stationary sources
RM 4: Determination of moisture content in stationary sources
Modified 0010: Determination of PFAS emissions from stationary sources (modified)
Sampling Locations

The sampling ports at the 36-inch inside diameter (ID) carbon bed inlet duct are located
approximately 67 inches (1.9 diameters) downstream of a bend and approximately 61 inches
(1.7 diameters) upstream of another bend. Test ports in the 36-inch ID carbon bed outlet duct
are located approximately 58 inches (1.6 diameters) downstream of a bend and approximately
57 inches (1.6 diameters) upstream from another bend. A total of 12 traverse points were
sampled on each diameter during each test run for a total of 24 traverse points at each test
location. Traverse points were located in accordance with USEPA RM 1.

Test ports in the 34-inch ID Division Stack are located approximately 30 feet downstream (11
diameters) of a disturbance and approximately 9 feet (3.2 diameters) from the stack exit. In
accordance with USEPA RM 1, 6 traverse points were sampled on each diameter. Note that due to
limited access to one of the test ports sampling was only conducted on one diameter for each
test run at the Division Stack. Also, note that this test location is not part of the required
quarterly testing.

Schematics of the sample locations along with traverse point locations are provided in Appendix
A.
Gas Velocity and Volumetric Flow Rate

Velocity was evaluated from differential pressure measurements using a stainless-steel Type-S
pitot tube and oil manometer in accordance with USEPA RMs 1 and 2. These methods were
conducted in conjunction with each test run. Exhaust gas volumetric flow rate in units of dry
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standard cubic feet per minute (dscfm) were derived from velocity, temperature, molecular
weight, and moisture measurements. Compound mass emission rates (lb/hr) were calculated
using these volumetric flow rate data and compound concentrations.
Oxygen and Carbon Dioxide Concentrations

Concentrations of oxygen (O2) and carbon dioxide (CO2) were evaluated at both locations in
accordance with modified USEPA RM 3 procedures using a Fyrite® combustion analyzer. A grab
sample was collected and introduced into the Fyrite® for O2 and CO2 analysis.
Moisture Content

The moisture content of the sample trains was quantified utilizing procedures identified in USEPA
RM 4. A sample of gas was continuously collected from each traverse point using a dry gas meter
stack sampling system along with a series of impingers. The moisture content of the gas was
measured as a change in the volume of the water collected in each impinger solution and the
increased weight of the desiccant during the sampling period.
HFPO-DA Emissions

HFPO-DA emissions were evaluated in accordance with a modified USEPA Method 0010. The
sample train consisted of a stainless-steel nozzle attached directly to a heated borosilicate glass-
lined probe. The probe was connected directly to a heated borosilicate glass filter holder
containing a solvent-extracted glass fiber filter. In order to minimize possible thermal
degradation of the HFPO-DA, the probe and particulate filter were heated to just above stack
temperature to minimize water vapor condensation before the filter. The filter holder exit was
connected to a water-cooled coil condenser followed by a water-cooled sorbent module
containing approximately 40 grams of XAD-2 resin. The XAD-2 inlet temperature was monitored
to ensure that the module is maintained at a temperature below 20oC.

The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two
impingers each containing 100-ml of high purity deionized water. The water impingers were
followed by another condensate knockout impinger equipped with a second XAD-2 resin trap to
account for any sample breakthrough. The final impinger contained approximately 250 grams of
dry pre-weighed silica gel. The water impingers and condensate impingers were submerged in an
ice bath through the duration of the testing. The water in the ice bath was also used to circulate
around the coil condenser and the XAD-2 resin traps.

Exhaust gases were extracted from the sample locations isokinetically using a metering console
equipped with a vacuum pump, a calibrated orifice, oil manometer and probe/filter heat
controllers.
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4.6.1 HFPO-DA Sample Train and Equipment Preparation
Prior to conducting the field work the following procedures were conducted to prepare the field
sampling glassware and sample recovery tools.

1. Wash all glassware, brushes, and ancillary tools with low residue soap and hot water.
2. Rinse all glassware, brushes, and ancillary tools three (3) times with D.I. H20.
3. Bake glassware (with the exception of probe liners) at 450˚C for approximately 2 hours,
(XAD-2 resin tube glassware will be cleaned by Eurofins/TestAmerica by this same
procedure).
4. Solvent rinse three (3) times all glassware, brushes, and ancillary tools with the following
sequence of solvents: acetone, methylene chloride, hexane, and methanol.
5. Clean glassware and tools will be sealed in plastic bags or aluminum foil for transport to the
sampling site.
6. Squirt bottles will be new dedicated bottles of known history and dedicated to the D.I. Water
and methanol/ammonium hydroxide (MeOH/ 5% NH4OH) solvent contents. Squirt bottles will
be labelled with the solvent content it contains.
4.6.2 HFPO-DA Sample Train Recovery
Following completion of each test run, the sample probe, nozzle and front-half of the filter holder
were brushed and rinsed three times each with the MeOH/ 5% NH4OH solution (Container #1).
The glass fiber filter was removed from its housing and transferred to a polyethylene bottle
(Container #2). Any particulate matter and filter fibers which adhered to the filter holder and
gasket were also placed in Container #2. The XAD-2 resin trap was sealed, labelled and placed in
an iced sample cooler. The back-half of the filter holder, coil condenser condensate trap and
connecting glassware were rinsed with the same MeOH/ 5% NH4OH solution and placed in
Container #3.

The volume of water collected in the second and third impingers was measured for moisture
determinations and then placed in Container #4. Impingers #2 and #3 were then rinsed with the
MeOH/ 5% NH4OH solution and placed in Container #5. The second (breakthrough) XAD-2 resin
trap was sealed, labelled and placed in an iced sample cooler. The second condensate trap was
rinsed with the MeOH/ 5% NH4OH solution and placed in Container #5. The contents of the fifth
impinger were placed in its original container and weighed for moisture determinations.

Containers were sealed and labeled with the appropriate sample information. Samples remained
chilled until analysis. HFPO-DA analysis was conducted using liquid chromatography/dual mass
spectrometry (LC/MS/MS).

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5. EMISSIONS TEST RESULTS
A detailed summary of the test results is presented in Table 1 in the appendix. Supporting field
data and calculations can be found in Appendix C. The laboratory report is presented in Appendix
D. A brief discussion of the test results is presented below.
Emission Test Results

Table 1 presents a detailed summary of the HFPO-DA test results. HFPO-DA concentrations at the
carbon bed inlet ranged from 3.95E-01 mg/dscm to 3.72E+00 mg/dscm and averaged 1.54E+00
mg/dscm. Corresponding mass emissions of HFPO-DA ranged from 2.06E-02 lb/hr to 1.83E-01
lb/hr and averaged 7.63E-02 lb/hr.

Concentrations of HFPO-DA at the carbon bed outlet ranged from 2.19E-01 mg/dscm to 5.16E-01
mg/dscm and averaged 3.21E-01 mg/dscm. Mass emission rates of HFPO-DA from the carbon
bed outlet ranged from 1.20E-02 lb/hr to 2.97E-02 lb/hr and averaged 1.80E-02 lb/hr. The
resulting HFPO-DA removal efficiency of the VEN carbon bed averaged 76 percent.

A review of Table 1 indicates that HFPO-DA emissions at the carbon bed inlet dropped off
significantly during Runs 2 and 3. There were no sampling issues or leak check problems of the
sampling trains during any of the test runs. The decreased removal efficiency from the carbon
bed during Runs 2 and 3 can be attributed to the lower fugitive emissions during these test runs.
Discussion and Conclusion

There were no sampling or process operating problems encountered during the field testing that
impacted the test results. Therefore, all test data are believed to be representative of actual
emissions in evidence during the test program.

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6. QUALITY ASSURANCE/QUALITY CONTROL
QA/QC was based on the recommended QA/QC procedures of the various sampling and analytical
methods that were used for the test program. This section summarizes the pertinent QA/QC
procedures that were employed during the emissions testing program.
Equipment Calibration

An important aspect of pre-sampling preparations is the inspection and calibration of all
equipment planned to be used for the field effort. Equipment is inspected for proper operation
and durability prior to calibration. Calibration of equipment is conducted in accordance with the
procedures outlined in the USEPA document entitled "Quality Assurance Handbook for Air
Pollution Measurement Systems; Volume III—Stationary Source Specific Methods" (EPA-600/4-
77-027b). Equipment calibration is performed in accordance with USEPA guidelines and/or
manufacturer’s recommendations. Examples of the typical calibration requirements of the field
equipment being used are as follows:

• Pitot tubes (QA Handbook Section 3.1.2, pp. 1-13) - measured for appropriate spacing and
dimensions or calibrate in a wind tunnel. Rejection criteria given on the calibration sheet.
Post-test check - inspect for damage.
• Probe nozzles (QA Handbook Section 3.4.2, pg. 19) - make three measurements of the nozzle
ID (to the nearest 0.001 in.) using different diameters with a micrometer. Difference between
the high and low values should not exceed 0.004 in. Post-test check - inspect for damage.
• Thermocouples (QA Handbook Section 3.4.2, pp. 15-18) - verify against a mercury-in-glass
thermometer at two or more points including the anticipated measurement range. Acceptance
limits - impinger ±2°F; DGM ±5.4°F; stack ±1.5 percent of stack temperature.
• Dry gas meters (QA Handbook Section 3.4.2, pp. 1-12) - Dry gas meters are calibrated using
critical orifices. The procedure entails four runs using four separate critical orifices running at
an actual vacuum 1-2 in. greater than the theoretical critical vacuum. The minimum sample
volume required per orifice is 5 ft3. Meter boxes are calibrated annually and then verified by
use of the alternative USEPA RM 5 post-test calibration procedure. This procedure is
referenced as Approved Alternate Method ALT-009 (June 21, 1994) by USEPA’s Emission
Measurement Center. The average Y-value obtained by this method must be within 5% of the
initial Y-value.
Equipment Leak Checks

Pitot tube leak checks were conducted in accordance with USEPA RM 2. Leak checks were
conducted on the HFPO-DA sample trains prior to and following each test run in accordance with
the procedures outlined in USEPA RM 5, Sections 8.4.1 and 8.4.2.

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Reagent Blanks and Field Blanks

A field blank for the Modified USEPA RM 0010 sample train was collected as part of the test
program. The blank train was assembled and set-up near one of the carbon bed outlet test
locations and as close to the outlet sample train as possible. The blank train remained in place for
the duration of the sampling run. The blank train was heated to the same temperature as used
for the outlet sampling train, and the impinger portion of the train was iced down and chilled
water circulated through the coil condenser as described in SW-846 Method 0010. The blank train
was recovered in the same location, and by the same procedures as the actual sampling trains.

Additionally, a proof blank train rinse sample was collected one time during the sampling
campaign. The glassware components of the train received a thorough solvent rinse after
samples were recovered and put away for a sampling run. This secondary rinse was used to
prove that the sampling breakdown collection processes capture all HFPO-DA material, and
generally leave none of the target analytes uncaptured on the sample glassware. All sampling
train glassware parts, including brushes and other tools used, were thoroughly rinsed with MeOH
/ 5% NH4OH solution to evaluate the general rinsing efficiency of the sampling train recovery
process.

Reagent blanks of the diH2O used in the sample trains and MeOH/5% NH4OH solution used for
sample recovery were also submitted to the laboratory for analysis along with the field samples.
Note that the field blank train and proof blank were collected during sampling of the Vinyl Ethers
South carbon bed. Results of the field blank, proof blank and reagent blanks and are included
with the laboratory reports in Appendix D.
Test Data and Report Review

Test data input and emission calculations were double-checked for accuracy. The test results
were reviewed by senior personnel for reasonableness and accuracy. The final report was peer
reviewed by senior personnel and certified by the project manager.
Ramboll - Source Emissions Testing Of The Vinyl Ethers North Carbon Bed

TABLES

Table 1
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed
Fayetteville, North Carolina
Run Identification Run 1 Run 2 Run 3 Average Run 1 Run 2 Run 3 Average
Source ID:Carbon Bed Inlet Carbon Bed Outlet
Run Date 09Mar21 09Mar21 09Mar21 09Mar21 09Mar21 09Mar21Start/Stop Time 0852-1051 1135-1331 1436-1629 0852-1051 1135-1331 1436-1629
Exhaust Gas Conditions
Temperature (deg. F)82 91 95 89 87 97 101 95
Moisture (volume %)1.3 1.0 0.8 1.0 1.1 1.1 0.7 1.0
Oxygen (dry volume %)20.9 20.9 20.9 20.9 20.9 20.9 20.9 20.9
Carbon Dioxide (dry volume %)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Volumetric Flow Rateacfm 13,491 13,935 14,597 14,008 15,680 14,565 15,725 15,324
dscfm 13,107 13,375 13,927 13,470 15,348 13,996 15,043 14,796
HFPO - Dimer Acid
mg/dscm 3.72E+00 5.12E-01 3.95E-01 1.54E+00 5.16E-01 2.28E-01 2.19E-01 3.21E-01
lb/hr 1.83E-01 2.56E-02 2.06E-02 7.63E-02 2.97E-02 1.20E-02 1.23E-02 1.80E-02
Carbon Bed Removal Efficiency
percent 84 53 40 76
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APPENDIX A
PROCESS OPERATING DATA

Date 3/9/2021
Time
Stack Testing
VEN Product
VEN Precursor
VEN Condensation (HFPO)
VEN ABR
VEN Refining
Stripper Column Vent
PPVE
Burnout
1400 1500 1600
RUN 1: 0852-1051 RUN 2: 1135-1331 RUN 3: 1436-1629
800 900 1000 1100 1200 1300
Ramboll - Source Emissions Testing Of The Vinyl Ethers North Carbon Bed

APPENDIX B
SCHEMATICS OF THE TEST LOCATIONS

Crossectional Area Showing
Velocity Traverse Point Locations

Air Flow
67” 61” to
Carbon Bed

36”

Figure 1
Carbon Bed Inlet Sampling Location
Vinyl Ethers North
The Chemours Company
Fayetteville, North Carolina
Sample Traverse Point Locations for Circular Stacks
Facility:The Chemours Company
Source Identification:VEN Carbon Bed Inlet
Stack Diameter:36 inches
Sampling Locations: 1.9 diameters downstream
1.7 diameters upstream
Minimum Number of Traverse points
as specified by EPA Method 1: 24
Number of traverse points sampled: 24
Traverse Point Percent of Stack Diameter Distance in Inches
Number From Inside Wall From Inside Wall*
1 2.1 1.0
2 6.7 2.4
3 11.8 4.2
4 17.7 6.4
5 25.0 9.0
6 35.6 12.8
7 64.4 23.2
8 75.0 27.0
9 82.3 29.6
10 88.2 31.8
11 93.3 33.6
12 97.9 35.0
*Traverse points located within 1.00" to the stack wall for stacks having an inside diameter greater than
24" will be relocated as well as traverse points located within 0.50 inches to the stack wall on stacks
with a 24" ID or less to meet criteria.
C:\Stack\Field Spreadsheets\Method 1\Traverse_new.xlsx

Crossectional Area Showing
Velocity Traverse Point Locations

Air Flow
From Carbon Bed

58” 57”

36”

Figure 2
Carbon Bed Outlet Sampling Location
Vinyl Ethers North
The Chemours Company
Fayetteville, North Carolina
Sample Traverse Point Locations for Circular Stacks
Facility:The Chemours Company
Source Identification:VEN Carbon Bed Outlet
Stack Diameter:36 inches
Sampling Locations: 1.6 diameters downstream
1.6 diameters upstream
Minimum Number of Traverse points
as specified by EPA Method 1: 24
Number of traverse points sampled: 24
Traverse Point Percent of Stack Diameter Distance in Inches
Number From Inside Wall From Inside Wall*
1 2.1 1.0
2 6.7 2.4
3 11.8 4.2
4 17.7 6.4
5 25.0 9.0
6 35.6 12.8
7 64.4 23.2
8 75.0 27.0
9 82.3 29.6
10 88.2 31.8
11 93.3 33.6
12 97.9 35.0
*Traverse points located within 1.00" to the stack wall for stacks having an inside diameter greater than
24" will be relocated as well as traverse points located within 0.50 inches to the stack wall on stacks
with a 24" ID or less to meet criteria.
C:\Stack\Field Spreadsheets\Method 1\Traverse_new.xlsx
Ramboll - Source Emissions Testing Of The Vinyl Ethers North Carbon Bed

APPENDIX C
FIELD DATA AND CALCULATIONS

VEN Carbon Bed Inlet Field Test Data

Field Data SummaryThe Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed InletFayetteville, North Carolina
Run 1 Run 2 Run 3
Traverse Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT
Point Temp(F) P H in out Delta P Temp(F) P H in out Delta P Temp(F) P H in out Delta P
A1 74 0.21 0.67 47 45 0.4583 88 0.25 0.80 73 74 0.5000 93 0.25 0.80 80 76 0.50002750.20 0.64 50 46 0.4472 89 0.25 0.80 74 74 0.5000 93 0.25 0.80 80 76 0.50003770.28 0.90 53 47 0.5292 89 0.28 0.90 75 74 0.5292 93 0.25 0.80 81 76 0.50004800.30 0.96 55 48 0.5477 89 0.29 0.93 76 74 0.5385 93 0.30 0.96 81 78 0.54775810.31 0.99 57 49 0.5568 89 0.29 0.93 76 74 0.5385 94 0.30 0.96 81 78 0.54776810.32 1.02 59 50 0.5657 89 0.29 0.93 76 73 0.5385 95 0.34 1.09 81 78 0.58317810.36 1.15 60 51 0.6000 89 0.31 0.99 76 74 0.5568 95 0.38 1.22 81 78 0.61648820.40 1.28 63 56 0.6325 89 0.31 0.99 77 73 0.5568 95 0.35 1.12 81 77 0.59169820.41 1.31 63 56 0.6403 90 0.35 1.12 77 73 0.5916 95 0.38 1.22 80 77 0.616410820.41 1.31 66 56 0.6403 90 0.35 1.12 77 74 0.5916 95 0.40 1.28 80 77 0.6325
11 82 0.42 1.34 68 58 0.6481 90 0.39 1.25 78 74 0.6245 95 0.40 1.28 80 76 0.632512820.42 1.34 70 59 0.6481 90 0.39 1.25 78 74 0.6245 95 0.40 1.28 80 76 0.6325B1840.32 1.02 73 69 0.5657 91 0.34 1.09 76 76 0.5831 96 0.44 1.41 76 75 0.66332840.32 1.02 74 70 0.5657 91 0.34 1.09 77 76 0.5831 95 0.42 1.34 78 75 0.64813840.34 1.09 77 71 0.5831 91 0.37 1.18 79 76 0.6083 96 0.42 1.34 79 75 0.64814850.34 1.09 78 72 0.5831 92 0.40 1.28 79 76 0.6325 95 0.42 1.34 80 75 0.64815850.34 1.09 80 73 0.5831 92 0.42 1.34 80 77 0.6481 96 0.43 1.38 80 75 0.65576850.32 1.02 81 75 0.5657 92 0.42 1.34 81 77 0.6481 96 0.43 1.38 80 75 0.65577850.28 0.90 82 76 0.5292 92 0.33 1.06 81 77 0.5745 96 0.43 1.38 80 75 0.65578850.28 0.90 82 78 0.5292 92 0.30 0.96 82 78 0.5477 96 0.35 1.12 81 75 0.5916
9 85 0.25 0.80 83 78 0.5000 92 0.32 1.02 82 78 0.5657 95 0.35 1.12 81 75 0.591610860.25 0.80 82 78 0.5000 92 0.34 1.09 82 78 0.5831 95 0.35 1.12 81 75 0.591611860.26 0.83 82 78 0.5099 92 0.32 1.02 82 78 0.5657 95 0.33 1.05 81 75 0.574512860.27 0.86 81 79 0.5196 92 0.32 1.02 83 79 0.5657 96 0.33 1.05 81 75 0.57450.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000
0.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000Average820.32 1.01 69 63 0.5603 91 0.33 1.06 78 75 0.5748 95 0.36 1.16 80 76 0.6000
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Inlet_030921.xlsx\TestData.xls
Test Data Summary and Calculations
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed InletFayetteville, North Carolina
Parameter Run 1 Run 2 Run 3
Run Date 3/9/21 3/9/21 3/9/21Start/Stop Time 0852-1051 1135-1331 1436-1629
Duration of Run, Minutes 96 96 96
Ave. Nozzle Diameter, inches 0.243 0.243 0.243Pitot Calibration Factor, CF 0.84 0.84 0.84Meter Gamma 1.002 1.002 1.002
Meter Delta H, inches of H2O 1.6 1.6 1.6Stack Diameter, inches 36 36 36Rectangular Width, inches 0 0 0
Rectangular Length, inches 0 0 0
Stack Area, sq.ft.7.07 7.07 7.07Barometric Pressure, inches of Hg 30.5 30.5 30.5Static Pressure, inches of H2O -3.5 -3.5 -3.5
Dry Gas Meter Sample Volume, (VM)ft3Initial 927.572 985.086 44.759Final984.948 1042.671 105.524
Total Volume 57.188 57.444 60.55
Ave. Stack Temperature, Ts(F)82.5 90.5 94.9Ave. Meter Temperature, Tm(F)66.3 76.8 78.1Ave. Run Delta H, inches of H2O 1.01 1.06 1.16
Ave. Square Root of Delta P 0.5603 0.5748 0.6000
Moisture Data
Volume of water collected, mls 4.8 1.2 0.4
Silica Gel, grams 11 11.2 10
Total Collected, mls 15.8 12.4 10.4
ORSAT Data
%O2 20.90 20.90 20.90%CO2 0.0 0.0 0.0
%CO
Calculations
Vw(std), scf =0.744 0.584 0.490Vm(std), dscf =58.741 57.857 60.860Bws=0.013 0.010 0.008
Md=28.84 28.84 28.84Ms=28.70 28.73 28.75Vs, ft/sec =31.8 32.9 34.4
Qs, acfm =13,491 13,935 14,597
Qs(std), dscfm =13,107 13,375 13,927Isokinetic Sampling Rate, %102.5 98.9 99.9
Where:
An = area of the nozzleAs = area of the stackVw(std) = volume of water vapor in gas, standard conditions = 0.04707*Vlc
Vm(std) = vol. of gas sampled, standard conditions = 17.647 x Vm x gamma x [Pb + (dH/13.6)]/Tm(R)Bws = water vapor in gas stream, proportion by volume = Vw(std)/(Vm(std) + Vw(std))Md = molecular weight of stack gas, dry basis = (0.44 x%CO2) + (0.32 x%O2) + [0.28 x (%N2 + %CO)]
Ms = molecular weight of stack gas, wet basis = [Md x (1-Bws)] + (18.0 x Bws)
Vs = stack gas velocity = 85.49 x Cp x (avg. Sq.Rt. dP) x [Sq.Rt. (Ts(R))/(Ms x Ps)]Qs = stack gas flow rate = Vs x As x 60Qs(std) = stack gas flow rate, standard conditions = Qs x (1-Bws) x (528/(Ts(R)) x (Ps/29.92)
Isokinetic sampling rate = {(Ts(R)) x [(0.00267 x Vlc) + (Vm(std)/17.647)] x 100}/(Time x vs x Ps x An x60)
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Inlet_030921.xlsx\Summary Data.xls
Results SummaryThe Chemours Company - Fayetteville WorksVinyl Ethers North Carbon Bed InletFayetteville, North Carolina
Parameter:Run 1 Run 2 Run 3 Average
Mol. Wt. mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr
HFPO - Dimer Acid 330 6.19125 3.72E+00 2.71E-01 1.83E-01 0.83829 5.12E-01 3.73E-02 2.56E-02 0.68042 3.95E-01 2.88E-02 2.06E-02 2.57 1.54E+00 1.12E-01 7.63E-02
Where:Pollutant Emission Concentration:mg= total sample collected, milligramsmg/dscm = milligrams of pollutant per dry standard cubic meter sampled = (mg/dscf ) x (35.314 cubic feet/cubic meter) ppm = parts per million =((mg/dscm x 24.04 liters/mol)/mol.wt))
Pollutant Emission Rate:lb/hr = pounds of pollutant emitted per hour = mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Inlet_030921.xlsx\Other Lab Results.xls
Example Calculations
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed Inlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vm,a =Dry gas volume at actual conditions (acf)
Initial gas meter volume:
Final gas meter volume:
Difference:
Vm,std =Volume of dry gas at standard conditions (dscf)
=17.647x Vm, a x Gamma*[Pbar+(DeltaH/13.6)]/Tm(R)=17.647 x 0.000 x 1.002 x (30.50 + [ (1.600 /13.6)]/526
=58.741
Vl,c =Volume of water collected in impingers and silica gel (ml)
impinger catch (mls):5
silica gel (g)11.0
total:15.8
Vw,std =Volume of water vapor in gas at standard conditions (cu.ft.)
=(0.04707) x (Vl,c)
=0.04707 x 15.8
=0.744
Bwo =Proportion by volume of water vapor in gas stream
=Vw,std/(Vw,std+Vm,std)
=0.74 / (0.74 +58.741 )
=0.013
Ps =Stack gas static pressure (in. Hg)
=St/13.6
=-3.50 / 13.6=-0.257
Pa =Absolute stack gas pressure (in. Hg) =Ps+Pbar
=-0.257 +30.50
=30.24
MFD =Dry mole fraction of stack gas
=1-Bwo
=1 -
=0.987
Md =Dry molecular weight of stack gas (lb/lb-mol)
=(0.32 x %O2) + (0.44 x %CO2) + (0.28 x %N2)
=(0.32 x 20.90 )+(0.44 x 0.00 ) +(0.28 x 79.10 )
=28.84
Mw =Wet molecular weight of stack gas (lb/lb-mol)
=(Md) x (MFD) + (0.18) x (Bwo*100)
=28.84 x 0.987 + 0.18 x 1.25024
=28.70
0.013
927.572984.948
57.376
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Inlet_030921.xlsx\Example Page 5 of 6
Example Calculations
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed Inlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vs,avg =Average stack gas velocity (fps)
=Kp x (Cp) x (sqrt,deltaP) x sqrt((Ts + 460°R)/Mw*Pa))
=85.48 x 0.84 x 0.56 x sqrt (0.62 )
=31.8
A Cross sectional areas of stack (sq. ft)
=pi/4*d^2=3.00 ^2
=7.07
Qa Volumetric flow rate at actual conditions (acfm)
=(60)sec/min(A)(Vs, avg)
=60 x 7.0686 x 31.81
=13,490
Qstd Volumetric flow rate at standard conditions (scfm)
=Qa x (528/Ts,avg + 460) x Pa/29.92
=13,490 x (528 /542 ) x 1.011
=13,272
Qstd,dry Volumetric flow rate at dry standard conditions per minute(dscfm)
=Qstd x (1-Bwo)
=13,272 x 0.9875
=13,106
mg/dscm HFPO-DA concentration
=(mg/dscf) x 35.314 cu. ft./cu. meter
= (6.19 /58.74 ) x35.314
=3.72E+00
lb/hr HFPO-DA Mass Emission Rate
=mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
=6.19 /1,000 /[(453.59 ) / (58.74 )] x 13,107 x 60
=1.83E-01
3.14159/4 x
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Inlet_030921.xlsx\Example Page 6 of 6
DOCUMENT TITLE
Sample Train Recovery Data Sheet
Client The Chemours Co.Location Fayetteville, NC Source VEN Inlet Method Modified 0010 Date 3/9/2021
Run #1
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 852
Impinger #8
Run End Time 1051
Total Gain ml/gm
Recovery Technician PG
Run #2
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1135
Impinger #8
Run End Time 1331
Total Gain ml/gm
Recovery Technician PG
Run #3
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1436
Impinger #8
Run End Time 1629
Total Gain ml/gm
Recovery Technician PG
755.2 1.2
0.0
Final ml or gm Initial ml or gm Net Gain
446.8 446.0 0.8
769.4 769.4 0.0
740.6 739.2 1.4
500.4 499.0 1.4
856.4 845.4 11.0
756.4
0.0
15.8
Final ml or gm Initial ml or gm Net Gain
492.0 491.8 0.2
788.8 790.0 -1.2
785.8 786.0 -0.2
682.6 681.8 0.8
516.6 515.0 1.6
854.2 843.0 11.2
0.0
0.0
12.4
Final ml or gm Initial ml or gm Net Gain
449.0 448.2 0.8
772.0 774.2 -2.2
749.4 750.2 -0.8
760.0 759.6 0.4
502.8 500.6 2.2
866.2 856.2 10.0
10.4
0.0
0.0
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\App C\VEN_Inlet_Moisture.xls\VEN_Inlet_Moisture.xls

VEN Carbon Bed Outlet Field Test Data

Table 1
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed
Fayetteville, North Carolina
Run Identification Run 1 Run 2 Run 3 Average
Source ID:Carbon Bed Inlet
Run Date 09Mar21 09Mar21 09Mar21
Start/Stop Time 0852-1051 1135-1331 1436-1629
Exhaust Gas Conditions
Temperature (deg. F)87 97 101 95
Moisture (volume %)1.1 1.1 0.7 1.0
Oxygen (dry volume %)20.9 20.9 20.9 20.9
Carbon Dioxide (dry volume %)0.0 0.0 0.0 0.0
Volumetric Flow Rate
acfm 15,680 14,565 15,725 15,324
dscfm 15,348 13,996 15,043 14,796
HFPO - Dimer Acid
mg/dscm 5.16E-01 2.28E-01 2.19E-01 3.21E-01
lb/hr 2.97E-02 1.20E-02 1.23E-02 1.80E-02
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Outlet_030921.xlsx\Summary Table
Field Data SummaryThe Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed OutletFayetteville, North Carolina
Run 1 Run 2 Run 3
Traverse Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT
Point Temp(F) P H in out Delta P Temp(F) P H in out Delta P Temp(F) P H in out Delta P
A1 83 0.42 1.60 49 47 0.6481 95 0.21 0.78 67 68 0.4583 100 0.16 0.61 82 83 0.40002840.42 1.60 50 48 0.6481 95 0.21 0.78 68 67 0.4583 101 0.21 0.80 82 83 0.45833830.22 0.84 53 49 0.4690 95 0.22 0.83 69 67 0.4690 101 0.23 0.87 83 83 0.47964840.24 0.91 56 50 0.4899 96 0.25 0.95 71 67 0.5000 101 0.24 0.91 84 82 0.48995840.29 1.10 57 51 0.5385 96 0.25 0.95 72 67 0.5000 101 0.28 1.06 84 82 0.52926850.32 1.22 59 53 0.5657 96 0.30 1.14 72 67 0.5477 101 0.32 1.22 84 82 0.56577850.41 1.56 57 54 0.6403 93 0.33 1.25 73 67 0.5745 101 0.34 1.29 84 81 0.58318850.40 1.52 63 55 0.6325 96 0.35 1.33 73 67 0.5916 101 0.41 1.56 84 80 0.64039850.42 1.60 64 56 0.6481 96 0.37 1.41 74 67 0.6083 101 0.41 1.56 83 80 0.640310860.42 1.60 63 58 0.6481 96 0.37 1.41 74 67 0.6083 101 0.41 1.56 83 79 0.6403
11 86 0.42 1.60 67 59 0.6481 97 0.37 1.41 74 68 0.6083 101 0.41 1.56 83 79 0.640312860.42 1.60 68 60 0.6481 97 0.37 1.41 75 68 0.6083 101 0.41 1.56 83 79 0.6403B1880.60 2.28 70 66 0.7746 97 0.31 1.18 73 70 0.5568 102 0.38 1.33 78 77 0.61642880.60 2.28 70 66 0.7746 98 0.31 1.18 73 70 0.5568 102 0.38 1.33 80 77 0.61643880.55 2.09 73 67 0.7416 98 0.31 1.18 75 71 0.5568 101 0.40 1.52 81 77 0.63254890.68 2.58 75 68 0.8246 98 0.31 1.18 76 71 0.5568 101 0.41 1.56 80 77 0.64035890.65 2.47 76 68 0.8062 98 0.36 1.37 77 72 0.6000 101 0.58 2.20 83 78 0.76166890.65 2.47 77 70 0.8062 98 0.55 2.09 77 71 0.7416 101 0.65 2.47 81 77 0.80627890.59 2.24 77 70 0.7681 98 0.60 2.28 80 73 0.7746 101 0.67 2.55 82 78 0.81858900.42 1.60 78 71 0.6481 98 0.62 2.36 79 72 0.7874 102 0.67 2.55 85 78 0.8185
9 90 0.39 1.42 78 71 0.6245 98 0.62 2.36 83 75 0.7874 102 0.60 2.28 84 78 0.774610900.33 1.25 78 72 0.5745 98 0.49 1.87 84 75 0.7000 102 0.62 2.36 84 78 0.787411900.31 1.18 77 72 0.5568 98 0.41 1.56 85 76 0.6403 101 0.60 2.36 85 78 0.774612900.31 1.18 77 72 0.5568 98 0.41 1.56 86 77 0.6403 102 0.60 2.36 84 78 0.77460.0000 85 77 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000
0.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000Average870.44 1.66 67 61 0.6534 97 0.37 1.41 76 70 0.6013 101 0.43 1.64 83 79 0.6470
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Outlet_030921.xlsx\TestData.xls
Test Data Summary and Calculations
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed OutletFayetteville, North Carolina
Parameter Run 1 Run 2 Run 3
Run Date 3/9/21 3/9/21 3/9/21Start/Stop Time 0852-1051 1135-1331 1436-1629
Duration of Run, Minutes 96 96 96
Ave. Nozzle Diameter, inches 0.243 0.243 0.243Pitot Calibration Factor, CF 0.84 0.84 0.84Meter Gamma 0.991 0.991 0.991
Meter Delta H, inches of H2O 1.88 1.88 1.88Stack Diameter, inches 36 36 36Rectangular Width, inches 0 0 0
Rectangular Length, inches 0 0 0
Stack Area, sq.ft.7.07 7.07 7.07Barometric Pressure, inches of Hg 30.5 30.5 30.5Static Pressure, inches of H2O 2.3 2 2
Dry Gas Meter Sample Volume, (VM)ft3Initial 967.426 33.042 95.279Final1032.812 94.939 161.098
Total Volume 65.386 61.599 65.68
Ave. Stack Temperature, Ts(F)86.9 96.8 101.2Ave. Meter Temperature, Tm(F)64.3 73.0 81.0Ave. Run Delta H, inches of H2O 1.66 1.41 1.64
Ave. Square Root of Delta P 0.6534 0.6013 0.6470
Moisture Data
Volume of water collected, mls 3.6 1.8 -1.6
Silica Gel, grams 12 12.4 11.8
Total Collected, mls 15.6 14.2 10.2
ORSAT Data
%O2 20.90 20.90 20.90%CO2 0.0 0.0 0.0
%CO
Calculations
Vw(std), scf =0.734 0.668 0.480Vm(std), dscf =66.789 61.849 65.007Bws=0.011 0.011 0.007
Md=28.84 28.84 28.84Ms=28.72 28.72 28.76Vs, ft/sec =37.0 34.3 37.1
Qs, acfm =15,680 14,565 15,725
Qs(std), dscfm =15,348 13,996 15,043Isokinetic Sampling Rate, %99.5 101.0 98.8
Where:
An = area of the nozzleAs = area of the stackVw(std) = volume of water vapor in gas, standard conditions = 0.04707*Vlc
Vm(std) = vol. of gas sampled, standard conditions = 17.647 x Vm x gamma x [Pb + (dH/13.6)]/Tm(R)Bws = water vapor in gas stream, proportion by volume = Vw(std)/(Vm(std) + Vw(std))Md = molecular weight of stack gas, dry basis = (0.44 x%CO2) + (0.32 x%O2) + [0.28 x (%N2 + %CO)]
Ms = molecular weight of stack gas, wet basis = [Md x (1-Bws)] + (18.0 x Bws)
Vs = stack gas velocity = 85.49 x Cp x (avg. Sq.Rt. dP) x [Sq.Rt. (Ts(R))/(Ms x Ps)]Qs = stack gas flow rate = Vs x As x 60Qs(std) = stack gas flow rate, standard conditions = Qs x (1-Bws) x (528/(Ts(R)) x (Ps/29.92)
Isokinetic sampling rate = {(Ts(R)) x [(0.00267 x Vlc) + (Vm(std)/17.647)] x 100}/(Time x vs x Ps x An x60)
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Outlet_030921.xlsx\Summary Data.xls
Results SummaryThe Chemours Company - Fayetteville WorksVinyl Ethers North Carbon Bed OutletFayetteville, North Carolina
Parameter:Run 1 Run 2 Run 3 Average
Mol. Wt. mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr
HFPO - Dimer Acid 330 0.97633 5.16E-01 3.76E-02 2.97E-02 0.39931 2.28E-01 1.66E-02 1.20E-02 0.40345 2.19E-01 1.60E-02 1.23E-02 0.59 3.21E-01 2.34E-02 1.80E-02
Where:Pollutant Emission Concentration:mg= total sample collected, milligramsmg/dscm = milligrams of pollutant per dry standard cubic meter sampled = (mg/dscf ) x (35.314 cubic feet/cubic meter) ppm = parts per million =((mg/dscm x 24.04 liters/mol)/mol.wt))
Pollutant Emission Rate:lb/hr = pounds of pollutant emitted per hour = mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Outlet_030921.xlsx\Other Lab Results.xls
Example Calculations
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed Outlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vm,a =Dry gas volume at actual conditions (acf)
Initial gas meter volume:
Final gas meter volume:
Difference:
Vm,std =Volume of dry gas at standard conditions (dscf)
=17.647x Vm, a x Gamma*[Pbar+(DeltaH/13.6)]/Tm(R)=17.647 x 0.000 x 0.991 x (30.50 + [ (1.880 /13.6)]/524
=66.789
Vl,c =Volume of water collected in impingers and silica gel (ml)
impinger catch (mls):4
silica gel (g)12.0
total:15.6
Vw,std =Volume of water vapor in gas at standard conditions (cu.ft.)
=(0.04707) x (Vl,c)
=0.04707 x 15.6
=0.734
Bwo =Proportion by volume of water vapor in gas stream
=Vw,std/(Vw,std+Vm,std)
=0.73 / (0.73 +66.789 )
=0.011
Ps =Stack gas static pressure (in. Hg)
=St/13.6
=2.30 / 13.6=0.169
Pa =Absolute stack gas pressure (in. Hg) =Ps+Pbar
=0.169 +30.50
=30.67
MFD =Dry mole fraction of stack gas
=1-Bwo
=1 -
=0.989
Md =Dry molecular weight of stack gas (lb/lb-mol)
=(0.32 x %O2) + (0.44 x %CO2) + (0.28 x %N2)
=(0.32 x 20.90 )+(0.44 x 0.00 ) +(0.28 x 79.10 )
=28.84
Mw =Wet molecular weight of stack gas (lb/lb-mol)
=(Md) x (MFD) + (0.18) x (Bwo*100)
=28.84 x 0.989 + 0.18 x 1.08747
=28.72
0.011
967.4261032.812
65.386
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Outlet_030921.xlsx\Example Page 5 of 6
Example Calculations
The Chemours Company - Fayetteville Works
Vinyl Ethers North Carbon Bed Outlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vs,avg =Average stack gas velocity (fps)
=Kp x (Cp) x (sqrt,deltaP) x sqrt((Ts + 460°R)/Mw*Pa))
=85.48 x 0.84 x 0.65 x sqrt (0.62 )
=37.0
A Cross sectional areas of stack (sq. ft)
=pi/4*d^2=3.00 ^2
=7.07
Qa Volumetric flow rate at actual conditions (acfm)
=(60)sec/min(A)(Vs, avg)
=60 x 7.0686 x 36.97
=15,679
Qstd Volumetric flow rate at standard conditions (scfm)
=Qa x (528/Ts,avg + 460) x Pa/29.92
=15,679 x (528 /547 ) x 1.025
=15,516
Qstd,dry Volumetric flow rate at dry standard conditions per minute(dscfm)
=Qstd x (1-Bwo)
=15,516 x 0.9891
=15,347
mg/dscm HFPO-DA concentration
=(mg/dscf) x 35.314 cu. ft./cu. meter
= (0.98 /66.79 ) x35.314
=5.16E-01
lb/hr HFPO-DA Mass Emission Rate
=mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
=0.98 /1,000 /[(453.59 ) / (66.79 )] x 15,348 x 60
=2.97E-02
3.14159/4 x
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\VEN_Outlet_030921.xlsx\Example Page 6 of 6
DOCUMENT TITLE
Sample Train Recovery Data Sheet
Client The Chemours Co.Location Fayetteville, NC Source VEN Outlet Method Modified 0010 Date 3/9/2021
Run #1
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 852
Impinger #8
Run End Time 1051
Total Gain ml/gm
Recovery Technician PG
Run #2
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1135
Impinger #8
Run End Time 1331
Total Gain ml/gm
Recovery Technician PG
Run #3
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1436
Impinger #8
Run End Time 1629
Total Gain ml/gm
Recovery Technician PG
778.2 0.6
0.0
Final ml or gm Initial ml or gm Net Gain
467.4 466.6 0.8
740.4 740.2 0.2
785.2 784.8 0.4
530.4 528.8 1.6
857.4 845.4 12.0
778.8
0.0
15.6
Final ml or gm Initial ml or gm Net Gain
490.8 490.0 0.8
807.6 809.2 -1.6
811.2 811.4 -0.2
775.8 774.8 1.0
509.8 508.0 1.8
863.8 851.4 12.4
0.0
0.0
14.2
Final ml or gm Initial ml or gm Net Gain
466.8 467.2 -0.4
727.4 730.4 -3.0
780.6 781.4 -0.8
782.4 781.6 0.8
532.0 530.2 1.8
869.4 857.6 11.8
10.2
0.0
0.0
C:\Stack\Projects\Chemours\Fayetteville\March 2021\VEN Report\App C\VEN_Outlet_Moisture.xls\VEN_Outlet_Moisture.xls
Ramboll - Source Emissions Testing Of The Vinyl Ethers North Carbon Bed

APPENDIX D
LABORATORY DATA

VEN Carbon Bed Inlet Laboratory Data

ANALYTICAL REPORT
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike
Knoxville, TN 37921
Tel: [phone]
Laboratory Job ID: 140-22280-1
Client Project/Site: VEN Carbon Bed Inlet
For:
The Chemours Company FC, LLC
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, Delaware 19713
Attn: Michael Aucoin
Authorized for release by:
3/31/2021 9:52:59 AM
Courtney Adkins, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Laboratory Job ID: 140-22280-1
Page 2 of 25 Eurofins TestAmerica, Knoxville3/31/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
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Definitions/Glossary
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Qualifiers
LCMS
Qualifier Description
*+LCS and/or LCSD is outside acceptance limits, high biased.
Qualifier
*1 LCS/LCSD RPD exceeds control limits.
B Compound was found in the blank and sample.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Knoxville
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Case Narrative
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Job ID: 140-22280-1
Laboratory: Eurofins TestAmerica, Knoxville
Narrative
Job Narrative
140-22280-1
Sample Receipt
The samples were received on March 13, 2021 at 10:40 AM. The temperature of the cooler at receipt was 0.6º C.
LCMS
LC/MS/MS Sampling Train Preparation and Analysis: The sampling train components are extracted and analyzed for Per- and
Polyfluorinated Alkyl Substances (PFAS) using Eurofins TestAmerica Knoxville standard operating procedures KNOX-OP-0026 and
KNOX-LC-0007.
The sampling trains are prepared as four analytical fractions: The particulate filter and front half of the filter holder, nozzle and probe
solvent rinses are combined for one analytical fraction. The XAD-2 resin trap and back half of the filter holder, coil condenser and
connecting glassware solvent rinses are also combined as a separate analytical fraction. The condensate, impinger contents and their
related glassware DI water rinses make up the third analytical fraction. The breakthrough XAD module makes up the fourth analytical
fraction.
The filters and XAD components are spiked with isotope dilution internal standards and the components are extracted with
methanol/ammonium hydroxide by shaking for at least 18 hours. The extracts are concentrated to 10 mL and analyzed by HPLC/MS/MS.
The condensates are spiked with the isotope dilution internal standards and extracted using either Solid-Phase Extraction (SPE) or
diluting the water sample for analysis. Each extract at its final volume is 80:20 methanol:water
Sample results were calculated using the following equation:

Result, ηg/sample = (on-column concentration, ηg/mL) × (nominal final volume of extract (10 mL) / 1 sample) × DF × SF
Where:
DF = Instrument dilution factor
SF = Extraction Split Factor = (final volume of extract in the initial extraction batch / initial volume of extract in the “Split” batch)
For condensate, if less than the entire sample is extracted, the fraction of sample used replaces “1 sample”
Method 537 (modified): The method blank for preparation batch 140-47849 and 140-47874 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The Isotope Dilution Analyte (IDA) recovery associated with the following samples is below the method
recommended limit: (LCS 140-47734/2-B), (LCSD 140-47734/3-B) and (MB 140-47734/1-B). Generally, data quality is not considered
affected if the IDA signal-to-noise ratio is greater than 10:1.
Method 537 (modified): The method blank for preparation batch 140-47757 and 140-47785 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch
140-47734 and 140-47812 and analytical batch 140-48219 recovered outside control limits for the following analyte: HFPO-DA. This
analyte was biased high in the LCS/LCSD. The samples were consumed during the extraction process and therefore, the data have been
reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
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Client Sample Results
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Lab Sample ID: 140-22280-1Client Sample ID: D-1976,1977 VEN CARBON BED INLET R1
OTM-45 FH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 391 B 4.96 2.87 ug/Sample 03/15/21 14:51 03/27/21 20:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 92 25-150 03/15/21 14:51 03/27/21 20:10 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-2Client Sample ID: D-1978,1979,1981 VEN CARBON BED INLET
R1 OTM-45 BH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 5800 *+ *1 80.0 70.0 ug/Sample 03/15/21 06:58 03/28/21 10:54 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 106 25-150 03/15/21 06:58 03/28/21 10:54 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-3Client Sample ID: D-1980 VEN CARBON BED INLET R1
OTM-45 IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.244 B 0.0862 0.0142 ug/Sample 03/17/21 15:12 03/27/21 11:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 107 25-150 03/17/21 15:12 03/27/21 11:01 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-4Client Sample ID: D-1982 VEN CARBON BED INLET R1
OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0108 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 23:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 86 25-150 03/15/21 06:58 03/27/21 23:16 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Lab Sample ID: 140-22280-5Client Sample ID: D-1983,1984 VEN CARBON BED INLET R2
OTM-45 FH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 205 B 1.99 1.15 ug/Sample 03/15/21 14:51 03/27/21 20:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 100 25-150 03/15/21 14:51 03/27/21 20:18 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-6Client Sample ID: D-1985,1986,1988 VEN CARBON BED INLET
R2 OTM-45 BH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 633 *+ *1 16.0 14.0 ug/Sample 03/15/21 06:58 03/27/21 23:25 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 112 25-150 03/15/21 06:58 03/27/21 23:25 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-7Client Sample ID: D-1987 VEN CARBON BED INLET R2
OTM-45 IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.273 B 0.0965 0.0159 ug/Sample 03/17/21 15:12 03/27/21 11:09 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 106 25-150 03/17/21 15:12 03/27/21 11:09 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-8Client Sample ID: D-1989 VEN CARBON BED INLET R2
OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0138 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 23:33 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 89 25-150 03/15/21 06:58 03/27/21 23:33 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Lab Sample ID: 140-22280-9Client Sample ID: D-1990,1991 VEN CARBON BED INLET R3
OTM-45 FH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 107 B 1.00 0.580 ug/Sample 03/15/21 14:51 03/27/21 20:27 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 111 25-150 03/15/21 14:51 03/27/21 20:27 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-10Client Sample ID: D-1992,1993,1995 VEN CARBON BED INLET
R3 OTM-45 BH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 573 *+ *1 16.0 14.0 ug/Sample 03/15/21 06:58 03/27/21 23:51 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 105 25-150 03/15/21 06:58 03/27/21 23:51 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-11Client Sample ID: D-1994 VEN CARBON BED INLET R3
OTM-45 IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.409 B 0.0911 0.0150 ug/Sample 03/17/21 15:12 03/27/21 11:36 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 104 25-150 03/17/21 15:12 03/27/21 11:36 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22280-12Client Sample ID: D-1996 VEN CARBON BED INLET R3
OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0120 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/28/21 00:00 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 58 25-150 03/15/21 06:58 03/28/21 00:00 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
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Default Detection Limits
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep: None
0.00100HFPO-DA ug/Sample
Analyte UnitsMDLRL
0.000580
0.00160HFPO-DA ug/Sample0.00140
0.00200HFPO-DA ug/Sample0.000330
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Isotope Dilution Summary
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (25-150)
HFPODA
92140-22280-1
Percent Isotope Dilution Recovery (Acceptance Limits)
D-1976,1977 VEN CARBON BED INLET R1 OTM-45 FH
106140-22280-2 D-1978,1979,1981 VEN
CARBON BED INLET R1
OTM-45 BH
107140-22280-3 D-1980 VEN CARBON BED
INLET R1 OTM-45 IMPINGERS
1,2&3 COND
86140-22280-4 D-1982 VEN CARBON BED
INLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN
TUBE
100140-22280-5 D-1983,1984 VEN CARBON
BED INLET R2 OTM-45 FH
112140-22280-6 D-1985,1986,1988 VEN
CARBON BED INLET R2
OTM-45 BH
106140-22280-7 D-1987 VEN CARBON BED
INLET R2 OTM-45 IMPINGERS
1,2&3 COND
89140-22280-8 D-1989 VEN CARBON BED
INLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN
TUBE
111140-22280-9 D-1990,1991 VEN CARBON
BED INLET R3 OTM-45 FH
105140-22280-10 D-1992,1993,1995 VEN
CARBON BED INLET R3
OTM-45 BH
104140-22280-11 D-1994 VEN CARBON BED
INLET R3 OTM-45 IMPINGERS
1,2&3 COND
58140-22280-12 D-1996 VEN CARBON BED
INLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN
TUBE
43LCS 140-47734/2-B Lab Control Sample
88LCS 140-47757/2-B Lab Control Sample
109LCS 140-47849/2-B Lab Control Sample
33LCSD 140-47734/3-B Lab Control Sample Dup
95LCSD 140-47757/3-B Lab Control Sample Dup
108LCSD 140-47849/3-B Lab Control Sample Dup
64MB 140-47734/14-B Method Blank
45MB 140-47734/1-B Method Blank
92MB 140-47757/1-B Method Blank
101MB 140-47849/1-B Method Blank
Surrogate Legend
HFPODA = 13C3 HFPO-DA
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 140-47734/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 23:42 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 64 25-150 03/27/21 23:42 1
MB MB
Isotope Dilution
03/15/21 06:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47734/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 21:20 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 45 25-150 03/27/21 21:20 1
MB MB
Isotope Dilution
03/15/21 06:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47734/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
PFOA 0.0200 0.02027 ug/Sample 101 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
HFPO-DA 0.0200 0.02128 ug/Sample 106 60-140
13C3 HFPO-DA 25 -150
Isotope Dilution
43
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47734/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
PFOA 0.0200 0.02152 ug/Sample 108 60-140 6 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
HFPO-DA 0.0200 0.03810 *+ *1 ug/Sample 190 60-140 57 30
13C3 HFPO-DA 25 -150
Isotope Dilution
33
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47757/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47757
RL MDL
HFPO-DA 0.003180 0.00100 0.000580 ug/Sample 03/15/21 14:51 03/27/21 19:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 92 25-150 03/27/21 19:08 1
MB MB
Isotope Dilution
03/15/21 14:51
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47757/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47757
PFOA 0.0200 0.01985 ug/Sample 99 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
HFPO-DA 0.0200 0.02453 ug/Sample 123 60-140
13C3 HFPO-DA 25 -150
Isotope Dilution
88
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47757/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47757
PFOA 0.0200 0.01976 ug/Sample 99 60-140 0 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
HFPO-DA 0.0200 0.02526 ug/Sample 126 60-140 3 30
13C3 HFPO-DA 25 -150
Isotope Dilution
95
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47849/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 47849
RL MDL
HFPO-DA 0.001638 0.000500 0.0000825 ug/Sample 03/17/21 15:12 03/27/21 10:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 101 25-150 03/27/21 10:08 1
MB MB
Isotope Dilution
03/17/21 15:12
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47849/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 47849
HFPO-DA 0.0100 0.01169 ug/Sample 117 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
109
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47849/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 47849
HFPO-DA 0.0100 0.01195 ug/Sample 119 60-140 2 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
108
LCSD LCSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
LCMS
Prep Batch: 47734
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22280-2 D-1978,1979,1981 VEN CARBON BED INLET R1 OTM-45 BHTotal/NA
Air None140-22280-4 D-1982 VEN CARBON BED INLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22280-6 D-1985,1986,1988 VEN CARBON BED INLET R2 OTM-45 BHTotal/NA
Air None140-22280-8 D-1989 VEN CARBON BED INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22280-10 D-1992,1993,1995 VEN CARBON BED INLET R3 OTM-45 BHTotal/NA
Air None140-22280-12 D-1996 VEN CARBON BED INLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air NoneMB 140-47734/14-B Method Blank Total/NA
Air NoneMB 140-47734/1-B Method Blank Total/NA
Air NoneLCS 140-47734/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Prep Batch: 47757
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22280-1 D-1976,1977 VEN CARBON BED INLET R1 OTM-45 FHTotal/NA
Air None140-22280-5 D-1983,1984 VEN CARBON BED INLET R2 OTM-45 FHTotal/NA
Air None140-22280-9 D-1990,1991 VEN CARBON BED INLET R3 OTM-45 FHTotal/NA
Air NoneMB 140-47757/1-B Method Blank Total/NA
Air NoneLCS 140-47757/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47757/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 47785
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47757140-22280-1 D-1976,1977 VEN CARBON BED INLET R1 OTM-45 FHTotal/NA
Air Split 47757140-22280-5 D-1983,1984 VEN CARBON BED INLET R2 OTM-45 FHTotal/NA
Air Split 47757140-22280-9 D-1990,1991 VEN CARBON BED INLET R3 OTM-45 FHTotal/NA
Air Split 47757MB 140-47757/1-B Method Blank Total/NA
Air Split 47757LCS 140-47757/2-B Lab Control Sample Total/NA
Air Split 47757LCSD 140-47757/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 47812
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47734140-22280-2 D-1978,1979,1981 VEN CARBON BED INLET R1 OTM-45 BHTotal/NA
Air Split 47734140-22280-4 D-1982 VEN CARBON BED INLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734140-22280-6 D-1985,1986,1988 VEN CARBON BED INLET R2 OTM-45 BHTotal/NA
Air Split 47734140-22280-8 D-1989 VEN CARBON BED INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734140-22280-10 D-1992,1993,1995 VEN CARBON BED INLET R3 OTM-45 BHTotal/NA
Air Split 47734140-22280-12 D-1996 VEN CARBON BED INLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734MB 140-47734/14-B Method Blank Total/NA
Air Split 47734MB 140-47734/1-B Method Blank Total/NA
Air Split 47734LCS 140-47734/2-B Lab Control Sample Total/NA
Air Split 47734LCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Prep Batch: 47849
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22280-3 D-1980 VEN CARBON BED INLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22280-7 D-1987 VEN CARBON BED INLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22280-11 D-1994 VEN CARBON BED INLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air NoneMB 140-47849/1-B Method Blank Total/NA
Air NoneLCS 140-47849/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47849/3-B Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
LCMS
Cleanup Batch: 47874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47849140-22280-3 D-1980 VEN CARBON BED INLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 47849140-22280-7 D-1987 VEN CARBON BED INLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 47849140-22280-11 D-1994 VEN CARBON BED INLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 47849MB 140-47849/1-B Method Blank Total/NA
Air Split 47849LCS 140-47849/2-B Lab Control Sample Total/NA
Air Split 47849LCSD 140-47849/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)47874140-22280-3 D-1980 VEN CARBON BED INLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)47874140-22280-7 D-1987 VEN CARBON BED INLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)47874140-22280-11 D-1994 VEN CARBON BED INLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)47874MB 140-47849/1-B Method Blank Total/NA
Air 537 (modified)47874LCS 140-47849/2-B Lab Control Sample Total/NA
Air 537 (modified)47874LCSD 140-47849/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48218
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Dilution 47785140-22280-1 D-1976,1977 VEN CARBON BED INLET R1 OTM-45 FHTotal/NA
Air Dilution 47812140-22280-2 D-1978,1979,1981 VEN CARBON BED INLET R1 OTM-45 BHTotal/NA
Air Dilution 47785140-22280-5 D-1983,1984 VEN CARBON BED INLET R2 OTM-45 FHTotal/NA
Air Dilution 47812140-22280-6 D-1985,1986,1988 VEN CARBON BED INLET R2 OTM-45 BHTotal/NA
Air Dilution 47785140-22280-9 D-1990,1991 VEN CARBON BED INLET R3 OTM-45 FHTotal/NA
Air Dilution 47812140-22280-10 D-1992,1993,1995 VEN CARBON BED INLET R3 OTM-45 BHTotal/NA
Analysis Batch: 48219
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48218140-22280-1 D-1976,1977 VEN CARBON BED INLET R1 OTM-45 FHTotal/NA
Air 537 (modified)47812140-22280-4 D-1982 VEN CARBON BED INLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48218140-22280-5 D-1983,1984 VEN CARBON BED INLET R2 OTM-45 FHTotal/NA
Air 537 (modified)48218140-22280-6 D-1985,1986,1988 VEN CARBON BED INLET R2 OTM-45 BHTotal/NA
Air 537 (modified)47812140-22280-8 D-1989 VEN CARBON BED INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48218140-22280-9 D-1990,1991 VEN CARBON BED INLET R3 OTM-45 FHTotal/NA
Air 537 (modified)48218140-22280-10 D-1992,1993,1995 VEN CARBON BED INLET R3 OTM-45 BHTotal/NA
Air 537 (modified)47812140-22280-12 D-1996 VEN CARBON BED INLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)47812MB 140-47734/14-B Method Blank Total/NA
Air 537 (modified)47812MB 140-47734/1-B Method Blank Total/NA
Air 537 (modified)47785MB 140-47757/1-B Method Blank Total/NA
Air 537 (modified)47812LCS 140-47734/2-B Lab Control Sample Total/NA
Air 537 (modified)47785LCS 140-47757/2-B Lab Control Sample Total/NA
Air 537 (modified)47812LCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Air 537 (modified)47785LCSD 140-47757/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48223
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48218140-22280-2 D-1978,1979,1981 VEN CARBON BED INLET R1 OTM-45 BHTotal/NA
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Client Sample ID: D-1976,1977 VEN CARBON BED INLET R1
OTM-45 FH
Lab Sample ID: 140-22280-1
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 111 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 56 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 2 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 20:10 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1978,1979,1981 VEN CARBON BED INLET
R1 OTM-45 BH
Lab Sample ID: 140-22280-2
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 0.2 uL 10000 uL
Analysis 537 (modified)1 48223 03/28/21 10:54 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1980 VEN CARBON BED INLET R1
OTM-45 IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22280-3
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.0058
Sample
10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 11:01 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1982 VEN CARBON BED INLET R1
OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22280-4
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 23:16 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Client Sample ID: D-1983,1984 VEN CARBON BED INLET R2
OTM-45 FH
Lab Sample ID: 140-22280-5
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 135 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 68 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 20:18 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1985,1986,1988 VEN CARBON BED INLET
R2 OTM-45 BH
Lab Sample ID: 140-22280-6
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 1 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 23:25 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1987 VEN CARBON BED INLET R2
OTM-45 IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22280-7
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00518
Sample
10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 11:09 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1989 VEN CARBON BED INLET R2
OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22280-8
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 23:33 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Client Sample ID: D-1990,1991 VEN CARBON BED INLET R3
OTM-45 FH
Lab Sample ID: 140-22280-9
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 128 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 64 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 10 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 20:27 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1992,1993,1995 VEN CARBON BED INLET
R3 OTM-45 BH
Lab Sample ID: 140-22280-10
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 1 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 23:51 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1994 VEN CARBON BED INLET R3
OTM-45 IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22280-11
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00549
Sample
10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 11:36 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: D-1996 VEN CARBON BED INLET R3
OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22280-12
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/28/21 00:00 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Client Sample ID: Method Blank Lab Sample ID: MB 140-47734/14-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 23:42 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47734/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:20 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47757/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 19:08 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47849/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:08 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47734/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:29 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47757/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 19:17 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47849/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:17 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47734/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:37 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47757/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 19:26 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47849/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:25 JRC TAL KNXTotal/NA
LCAInstrument ID:
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 18 of 25 3/31/2021
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Accreditation/Certification Summary
Client: The Chemours Company FC, LLC Job ID: 140-22280-1
Project/Site: VEN Carbon Bed Inlet
Laboratory: Eurofins TestAmerica, Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
N/AAFCEE
ANAB Dept. of Defense ELAP L2311 02-13-22
ANAB Dept. of Energy L2311.01 02-13-22
ANAB ISO/IEC 17025 L2311 02-13-22
ANAB ISO/IEC 17025 L2311 02-14-22
Arkansas DEQ State 88-0688 06-17-21
California State 2423 06-30-22
Colorado State TN00009 02-28-21 *
Connecticut State PH-0223 09-30-21
Florida NELAP E87177 07-01-21
Georgia (DW)State 906 12-11-22
Hawaii State NA 12-11-21
Kansas NELAP E-10349 10-31-21
Kentucky (DW)State 90101 12-31-21
Louisiana NELAP 83979 06-30-21
Louisiana (DW)State LA019 12-31-21
Maryland State 277 03-31-22
Michigan State 9933 12-11-22
Nevada State TN00009 07-31-21
New Hampshire NELAP 299919 01-17-22
New Jersey NELAP TN001 07-01-21
New York NELAP 10781 04-01-21
North Carolina (DW)State 21705 07-31-21
North Carolina (WW/SW)State 64 12-31-21
Ohio VAP State CL0059 06-02-23
Oklahoma State 9415 08-31-21
Oregon NELAP TNI0189 01-01-22
Pennsylvania NELAP 68-00576 12-31-21
Tennessee State 02014 12-11-22
Texas NELAP T104704380-18-12 08-31-21
US Fish & Wildlife US Federal Programs 058448 07-31-21
USDA US Federal Programs P330-19-00236 08-20-22
Utah NELAP TN00009 07-31-21
Virginia NELAP 460176 09-14-21
Washington State C593 01-19-22
West Virginia (DW)State 9955C 01-02-22
West Virginia DEP State 345 05-01-21
Wisconsin State 998044300 08-31-21
Eurofins TestAmerica, Knoxville
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 19 of 25 3/31/2021
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Method Summary
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL KNX
NoneDilutionDilution and Re-fortification of Standards TAL KNX
TAL SOPNoneLeaching Procedure TAL KNX
TAL SOPNoneLeaching Procedure for Condensate TAL KNX
TAL SOPNoneLeaching Procedure for Filter TAL KNX
NoneSplitSource Air Split TAL KNX
Protocol References:
EPA = US Environmental Protection Agency
None = None
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 20 of 25 3/31/2021
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Sample Summary
Job ID: 140-22280-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Inlet
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-22280-1 D-1976,1977 VEN CARBON BED INLET R1
OTM-45 FH
Air 03/09/21 00:00 03/13/21 10:40
140-22280-2 D-1978,1979,1981 VEN CARBON BED INLET R1
OTM-45 BH
Air 03/09/21 00:00 03/13/21 10:40
140-22280-3 D-1980 VEN CARBON BED INLET R1 OTM-45
IMPINGERS 1,2&3 COND
Air 03/09/21 00:00 03/13/21 10:40
140-22280-4 D-1982 VEN CARBON BED INLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/09/21 00:00 03/13/21 10:40
140-22280-5 D-1983,1984 VEN CARBON BED INLET R2
OTM-45 FH
Air 03/09/21 00:00 03/13/21 10:40
140-22280-6 D-1985,1986,1988 VEN CARBON BED INLET R2
OTM-45 BH
Air 03/09/21 00:00 03/13/21 10:40
140-22280-7 D-1987 VEN CARBON BED INLET R2 OTM-45
IMPINGERS 1,2&3 COND
Air 03/09/21 00:00 03/13/21 10:40
140-22280-8 D-1989 VEN CARBON BED INLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/09/21 00:00 03/13/21 10:40
140-22280-9 D-1990,1991 VEN CARBON BED INLET R3
OTM-45 FH
Air 03/09/21 00:00 03/13/21 10:40
140-22280-10 D-1992,1993,1995 VEN CARBON BED INLET R3
OTM-45 BH
Air 03/09/21 00:00 03/13/21 10:40
140-22280-11 D-1994 VEN CARBON BED INLET R3 OTM-45
IMPINGERS 1,2&3 COND
Air 03/09/21 00:00 03/13/21 10:40
140-22280-12 D-1996 VEN CARBON BED INLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/09/21 00:00 03/13/21 10:40
Eurofins TestAmerica, Knoxville
Page 21 of 25 3/31/2021
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VEN Carbon Bed Outlet Laboratory Data

ANALYTICAL REPORT
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike
Knoxville, TN 37921
Tel: [phone]
Laboratory Job ID: 140-22278-1
Client Project/Site: VEN Carbon Bed Outlet
For:
The Chemours Company FC, LLC
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, Delaware 19713
Attn: Michael Aucoin
Authorized for release by:
3/31/2021 9:39:12 AM
Courtney Adkins, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Laboratory Job ID: 140-22278-1
Page 2 of 27 Eurofins TestAmerica, Knoxville3/31/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
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Definitions/Glossary
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Qualifiers
LCMS
Qualifier Description
*+LCS and/or LCSD is outside acceptance limits, high biased.
Qualifier
*1 LCS/LCSD RPD exceeds control limits.
B Compound was found in the blank and sample.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Knoxville
Page 3 of 27 3/31/2021
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Case Narrative
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Job ID: 140-22278-1
Laboratory: Eurofins TestAmerica, Knoxville
Narrative
Job Narrative
140-22278-1
Sample Receipt
The samples were received on March 13, 2021 at 10:40 AM. The temperature of the cooler at receipt was 1.4º C.
LCMS
LC/MS/MS Sampling Train Preparation and Analysis: The sampling train components are extracted and analyzed for Per- and
Polyfluorinated Alkyl Substances (PFAS) using Eurofins TestAmerica Knoxville standard operating procedures KNOX-OP-0026 and
KNOX-LC-0007.
The sampling trains are prepared as four analytical fractions: The particulate filter and front half of the filter holder, nozzle and probe
solvent rinses are combined for one analytical fraction. The XAD-2 resin trap and back half of the filter holder, coil condenser and
connecting glassware solvent rinses are also combined as a separate analytical fraction. The condensate, impinger contents and their
related glassware DI water rinses make up the third analytical fraction. The breakthrough XAD module makes up the fourth analytical
fraction.
The filters and XAD components are spiked with isotope dilution internal standards and the components are extracted with
methanol/ammonium hydroxide by shaking for at least 18 hours. The extracts are concentrated to 10 mL and analyzed by HPLC/MS/MS.
The condensates are spiked with the isotope dilution internal standards and extracted using either Solid-Phase Extraction (SPE) or
diluting the water sample for analysis. Each extract at its final volume is 80:20 methanol:water
Sample results were calculated using the following equation:

Result, ηg/sample = (on-column concentration, ηg/mL) × (nominal final volume of extract (10 mL) / 1 sample) × DF × SF
Where:
DF = Instrument dilution factor
SF = Extraction Split Factor = (final volume of extract in the initial extraction batch / initial volume of extract in the “Split” batch)
For condensate, if less than the entire sample is extracted, the fraction of sample used replaces “1 sample”
Method 537 (modified): The method blank for preparation batch 140-47849 and 140-47874 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported. All the samples have the
same level of contamination. Investigating the root cause. Checking the standards used in the preparation of the extracts.
Method 537 (modified): The Isotope Dilution Analyte (IDA) recovery associated with the following samples is below the method
recommended limit: (LCS 140-47734/2-B), (LCSD 140-47734/3-B) and (MB 140-47734/1-B). Generally, data quality is not considered
affected if the IDA signal-to-noise ratio is greater than 10:1.
Method 537 (modified): The method blank for preparation batch 140-47757 and 140-47785 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch
140-47734 and 140-47812 and analytical batch 140-48219 recovered outside control limits for HFPO-DA. The analyte was biased high in
the LCS/LCSD. The samples were consumed during the extraction process and therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins TestAmerica, KnoxvillePage 4 of 27 3/31/2021
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Client Sample Results
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Lab Sample ID: 140-22278-1Client Sample ID: Z-2560,2561 VEN CB OUTLET R1 OTM-45
FH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 134 B 1.20 0.695 ug/Sample 03/15/21 14:51 03/28/21 10:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 103 25-150 03/15/21 14:51 03/28/21 10:46 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-2Client Sample ID: Z-2562,2563,2565 VEN CB OUTLET R1
OTM-45 BH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 842 *+ *1 16.0 14.0 ug/Sample 03/15/21 06:58 03/27/21 21:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 95 25-150 03/15/21 06:58 03/27/21 21:55 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-3Client Sample ID: Z-2564 VEN CB OUTLET R1 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.278 B 0.0899 0.0148 ug/Sample 03/17/21 15:12 03/27/21 10:34 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 110 25-150 03/17/21 15:12 03/27/21 10:34 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-4Client Sample ID: Z-2566 VEN CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0491 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 22:04 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 89 25-150 03/15/21 06:58 03/27/21 22:04 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 5 of 27 3/31/2021
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Client Sample Results
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Lab Sample ID: 140-22278-5Client Sample ID: Z-2567,2568 VEN CB OUTLET R2 OTM-45
FH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 142 B 2.00 1.16 ug/Sample 03/15/21 14:51 03/27/21 19:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 100 25-150 03/15/21 14:51 03/27/21 19:52 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-6Client Sample ID: Z-2569,2570,2572 VEN CB OUTLET R2
OTM-45 BH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 257 *+ *1 3.20 2.80 ug/Sample 03/15/21 06:58 03/27/21 22:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 96 25-150 03/15/21 06:58 03/27/21 22:13 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-7Client Sample ID: Z-2571 VEN CB OUTLET R2 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.286 B 0.0992 0.0164 ug/Sample 03/17/21 15:12 03/27/21 10:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 106 25-150 03/17/21 15:12 03/27/21 10:43 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-8Client Sample ID: Z-2573 VEN CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0194 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 22:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 88 25-150 03/15/21 06:58 03/27/21 22:39 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 6 of 27 3/31/2021
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Client Sample Results
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Lab Sample ID: 140-22278-9Client Sample ID: Z-2574,2575 VEN CB OUTLET R3 OTM-45
FH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 159 B 1.98 1.15 ug/Sample 03/15/21 14:51 03/27/21 20:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 104 25-150 03/15/21 14:51 03/27/21 20:01 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-10Client Sample ID: Z-2576,2577,2579 VEN CB OUTLET R3
OTM-45 BH
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 244 *+ *1 3.20 2.80 ug/Sample 03/15/21 06:58 03/27/21 22:49 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 105 25-150 03/15/21 06:58 03/27/21 22:49 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-11Client Sample ID: Z-2578 VEN CB OUTLET R3 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.296 B 0.0865 0.0143 ug/Sample 03/17/21 15:12 03/27/21 10:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 105 25-150 03/17/21 15:12 03/27/21 10:52 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22278-12Client Sample ID: Z-2580 VEN CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.155 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 22:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 98 25-150 03/15/21 06:58 03/27/21 22:58 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Default Detection Limits
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep: None
0.00100HFPO-DA ug/Sample
Analyte UnitsMDLRL
0.000580
0.00160HFPO-DA ug/Sample0.00140
0.00200HFPO-DA ug/Sample0.000330
Eurofins TestAmerica, Knoxville
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Isotope Dilution Summary
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (25-150)
HFPODA
103140-22278-1
Percent Isotope Dilution Recovery (Acceptance Limits)
Z-2560,2561 VEN CB OUTLET R1 OTM-45 FH
95140-22278-2 Z-2562,2563,2565 VEN CB
OUTLET R1 OTM-45 BH
110140-22278-3 Z-2564 VEN CB OUTLET R1
OTM-45 IMPINGERS 1,2&3
COND
89140-22278-4 Z-2566 VEN CB OUTLET R1
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
100140-22278-5 Z-2567,2568 VEN CB OUTLET
R2 OTM-45 FH
96140-22278-6 Z-2569,2570,2572 VEN CB
OUTLET R2 OTM-45 BH
106140-22278-7 Z-2571 VEN CB OUTLET R2
OTM-45 IMPINGERS 1,2&3
COND
88140-22278-8 Z-2573 VEN CB OUTLET R2
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
104140-22278-9 Z-2574,2575 VEN CB OUTLET
R3 OTM-45 FH
105140-22278-10 Z-2576,2577,2579 VEN CB
OUTLET R3 OTM-45 BH
105140-22278-11 Z-2578 VEN CB OUTLET R3
OTM-45 IMPINGERS 1,2&3
COND
98140-22278-12 Z-2580 VEN CB OUTLET R3
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
43LCS 140-47734/2-B Lab Control Sample
88LCS 140-47757/2-B Lab Control Sample
109LCS 140-47849/2-B Lab Control Sample
33LCSD 140-47734/3-B Lab Control Sample Dup
95LCSD 140-47757/3-B Lab Control Sample Dup
108LCSD 140-47849/3-B Lab Control Sample Dup
45MB 140-47734/1-B Method Blank
92MB 140-47757/1-B Method Blank
101MB 140-47849/1-B Method Blank
Surrogate Legend
HFPODA = 13C3 HFPO-DA
Eurofins TestAmerica, Knoxville
Page 9 of 27 3/31/2021
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QC Sample Results
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 140-47734/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 21:20 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 45 25-150 03/27/21 21:20 1
MB MB
Isotope Dilution
03/15/21 06:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47734/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
HFPO-DA 0.0200 0.02128 ug/Sample 106 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
43
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47734/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
HFPO-DA 0.0200 0.03810 *+ *1 ug/Sample 190 60-140 57 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
33
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47757/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47757
RL MDL
HFPO-DA 0.003180 0.00100 0.000580 ug/Sample 03/15/21 14:51 03/27/21 19:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 92 25-150 03/27/21 19:08 1
MB MB
Isotope Dilution
03/15/21 14:51
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47757/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47757
HFPO-DA 0.0200 0.02453 ug/Sample 123 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
88
LCS LCS
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 10 of 27 3/31/2021
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QC Sample Results
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47757/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47757
HFPO-DA 0.0200 0.02526 ug/Sample 126 60-140 3 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
95
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47849/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 47849
RL MDL
HFPO-DA 0.001638 0.000500 0.0000825 ug/Sample 03/17/21 15:12 03/27/21 10:08 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 101 25-150 03/27/21 10:08 1
MB MB
Isotope Dilution
03/17/21 15:12
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47849/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 47849
HFPO-DA 0.0100 0.01169 ug/Sample 117 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
109
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47849/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 47849
HFPO-DA 0.0100 0.01195 ug/Sample 119 60-140 2 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
108
LCSD LCSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
LCMS
Prep Batch: 47734
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22278-2 Z-2562,2563,2565 VEN CB OUTLET R1 OTM-45 BHTotal/NA
Air None140-22278-4 Z-2566 VEN CB OUTLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22278-6 Z-2569,2570,2572 VEN CB OUTLET R2 OTM-45 BHTotal/NA
Air None140-22278-8 Z-2573 VEN CB OUTLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22278-10 Z-2576,2577,2579 VEN CB OUTLET R3 OTM-45 BHTotal/NA
Air None140-22278-12 Z-2580 VEN CB OUTLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air NoneMB 140-47734/1-B Method Blank Total/NA
Air NoneLCS 140-47734/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Prep Batch: 47757
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22278-1 Z-2560,2561 VEN CB OUTLET R1 OTM-45 FH Total/NA
Air None140-22278-5 Z-2567,2568 VEN CB OUTLET R2 OTM-45 FH Total/NA
Air None140-22278-9 Z-2574,2575 VEN CB OUTLET R3 OTM-45 FH Total/NA
Air NoneMB 140-47757/1-B Method Blank Total/NA
Air NoneLCS 140-47757/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47757/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 47785
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47757140-22278-1 Z-2560,2561 VEN CB OUTLET R1 OTM-45 FH Total/NA
Air Split 47757140-22278-5 Z-2567,2568 VEN CB OUTLET R2 OTM-45 FH Total/NA
Air Split 47757140-22278-9 Z-2574,2575 VEN CB OUTLET R3 OTM-45 FH Total/NA
Air Split 47757MB 140-47757/1-B Method Blank Total/NA
Air Split 47757LCS 140-47757/2-B Lab Control Sample Total/NA
Air Split 47757LCSD 140-47757/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 47812
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47734140-22278-2 Z-2562,2563,2565 VEN CB OUTLET R1 OTM-45 BHTotal/NA
Air Split 47734140-22278-4 Z-2566 VEN CB OUTLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734140-22278-6 Z-2569,2570,2572 VEN CB OUTLET R2 OTM-45 BHTotal/NA
Air Split 47734140-22278-8 Z-2573 VEN CB OUTLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734140-22278-10 Z-2576,2577,2579 VEN CB OUTLET R3 OTM-45 BHTotal/NA
Air Split 47734140-22278-12 Z-2580 VEN CB OUTLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734MB 140-47734/1-B Method Blank Total/NA
Air Split 47734LCS 140-47734/2-B Lab Control Sample Total/NA
Air Split 47734LCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Prep Batch: 47849
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22278-3 Z-2564 VEN CB OUTLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22278-7 Z-2571 VEN CB OUTLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22278-11 Z-2578 VEN CB OUTLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air NoneMB 140-47849/1-B Method Blank Total/NA
Air NoneLCS 140-47849/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47849/3-B Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
LCMS
Cleanup Batch: 47874
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47849140-22278-3 Z-2564 VEN CB OUTLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 47849140-22278-7 Z-2571 VEN CB OUTLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 47849140-22278-11 Z-2578 VEN CB OUTLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 47849MB 140-47849/1-B Method Blank Total/NA
Air Split 47849LCS 140-47849/2-B Lab Control Sample Total/NA
Air Split 47849LCSD 140-47849/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)47874140-22278-3 Z-2564 VEN CB OUTLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)47874140-22278-7 Z-2571 VEN CB OUTLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)47874140-22278-11 Z-2578 VEN CB OUTLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)47874MB 140-47849/1-B Method Blank Total/NA
Air 537 (modified)47874LCS 140-47849/2-B Lab Control Sample Total/NA
Air 537 (modified)47874LCSD 140-47849/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48218
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Dilution 47785140-22278-1 Z-2560,2561 VEN CB OUTLET R1 OTM-45 FH Total/NA
Air Dilution 47812140-22278-2 Z-2562,2563,2565 VEN CB OUTLET R1 OTM-45 BHTotal/NA
Air Dilution 47785140-22278-5 Z-2567,2568 VEN CB OUTLET R2 OTM-45 FH Total/NA
Air Dilution 47812140-22278-6 Z-2569,2570,2572 VEN CB OUTLET R2 OTM-45 BHTotal/NA
Air Dilution 47785140-22278-9 Z-2574,2575 VEN CB OUTLET R3 OTM-45 FH Total/NA
Air Dilution 47812140-22278-10 Z-2576,2577,2579 VEN CB OUTLET R3 OTM-45 BHTotal/NA
Analysis Batch: 48219
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48218140-22278-2 Z-2562,2563,2565 VEN CB OUTLET R1 OTM-45 BHTotal/NA
Air 537 (modified)47812140-22278-4 Z-2566 VEN CB OUTLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48218140-22278-5 Z-2567,2568 VEN CB OUTLET R2 OTM-45 FH Total/NA
Air 537 (modified)48218140-22278-6 Z-2569,2570,2572 VEN CB OUTLET R2 OTM-45 BHTotal/NA
Air 537 (modified)47812140-22278-8 Z-2573 VEN CB OUTLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48218140-22278-9 Z-2574,2575 VEN CB OUTLET R3 OTM-45 FH Total/NA
Air 537 (modified)48218140-22278-10 Z-2576,2577,2579 VEN CB OUTLET R3 OTM-45 BHTotal/NA
Air 537 (modified)47812140-22278-12 Z-2580 VEN CB OUTLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)47812MB 140-47734/1-B Method Blank Total/NA
Air 537 (modified)47785MB 140-47757/1-B Method Blank Total/NA
Air 537 (modified)47812LCS 140-47734/2-B Lab Control Sample Total/NA
Air 537 (modified)47785LCS 140-47757/2-B Lab Control Sample Total/NA
Air 537 (modified)47812LCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Air 537 (modified)47785LCSD 140-47757/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48223
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48218140-22278-1 Z-2560,2561 VEN CB OUTLET R1 OTM-45 FH Total/NA
Eurofins TestAmerica, Knoxville
Page 13 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Client Sample ID: Z-2560,2561 VEN CB OUTLET R1 OTM-45
FH
Lab Sample ID: 140-22278-1
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 115 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 48 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 10 uL 10000 uL
Analysis 537 (modified)1 48223 03/28/21 10:46 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2562,2563,2565 VEN CB OUTLET R1
OTM-45 BH
Lab Sample ID: 140-22278-2
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 1 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 21:55 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2564 VEN CB OUTLET R1 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22278-3
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00556
Sample
10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:34 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2566 VEN CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22278-4
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 22:04 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 14 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Client Sample ID: Z-2567,2568 VEN CB OUTLET R2 OTM-45
FH
Lab Sample ID: 140-22278-5
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 126 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 63 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 19:52 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2569,2570,2572 VEN CB OUTLET R2
OTM-45 BH
Lab Sample ID: 140-22278-6
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 22:13 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2571 VEN CB OUTLET R2 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22278-7
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00504
Sample
10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:43 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2573 VEN CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22278-8
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 22:39 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 15 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Client Sample ID: Z-2574,2575 VEN CB OUTLET R3 OTM-45
FH
Lab Sample ID: 140-22278-9
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 115 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 58 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 20:01 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2576,2577,2579 VEN CB OUTLET R3
OTM-45 BH
Lab Sample ID: 140-22278-10
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/27/21 22:49 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2578 VEN CB OUTLET R3 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22278-11
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00578
Sample
10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:52 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2580 VEN CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22278-12
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 22:58 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 16 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Client Sample ID: Method Blank Lab Sample ID: MB 140-47734/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:20 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47757/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 19:08 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47849/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:08 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47734/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:29 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47757/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 19:17 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 17 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47849/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:17 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47734/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:37 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47757/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 14:51 TAL KNX47757
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 47785 03/16/21 11:03 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 19:26 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47849/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/17/21 15:12 TAL KNX47849
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 47874 03/18/21 09:23 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 10:25 JRC TAL KNXTotal/NA
LCAInstrument ID:
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 18 of 27 3/31/2021
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Accreditation/Certification Summary
Client: The Chemours Company FC, LLC Job ID: 140-22278-1
Project/Site: VEN Carbon Bed Outlet
Laboratory: Eurofins TestAmerica, Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
N/AAFCEE
ANAB Dept. of Defense ELAP L2311 02-13-22
ANAB Dept. of Energy L2311.01 02-13-22
ANAB ISO/IEC 17025 L2311 02-13-22
ANAB ISO/IEC 17025 L2311 02-14-22
Arkansas DEQ State 88-0688 06-17-21
California State 2423 06-30-22
Colorado State TN00009 02-28-21 *
Connecticut State PH-0223 09-30-21
Florida NELAP E87177 07-01-21
Georgia (DW)State 906 12-11-22
Hawaii State NA 12-11-21
Kansas NELAP E-10349 10-31-21
Kentucky (DW)State 90101 12-31-21
Louisiana NELAP 83979 06-30-21
Louisiana (DW)State LA019 12-31-21
Maryland State 277 03-31-22
Michigan State 9933 12-11-22
Nevada State TN00009 07-31-21
New Hampshire NELAP 299919 01-17-22
New Jersey NELAP TN001 07-01-21
New York NELAP 10781 04-01-21
North Carolina (DW)State 21705 07-31-21
North Carolina (WW/SW)State 64 12-31-21
Ohio VAP State CL0059 06-02-23
Oklahoma State 9415 08-31-21
Oregon NELAP TNI0189 01-01-22
Pennsylvania NELAP 68-00576 12-31-21
Tennessee State 02014 12-11-22
Texas NELAP T104704380-18-12 08-31-21
US Fish & Wildlife US Federal Programs 058448 07-31-21
USDA US Federal Programs P330-19-00236 08-20-22
Utah NELAP TN00009 07-31-21
Virginia NELAP 460176 09-14-21
Washington State C593 01-19-22
West Virginia (DW)State 9955C 01-02-22
West Virginia DEP State 345 05-01-21
Wisconsin State 998044300 08-31-21
Eurofins TestAmerica, Knoxville
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 19 of 27 3/31/2021
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Method Summary
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL KNX
NoneDilutionDilution and Re-fortification of Standards TAL KNX
TAL SOPNoneLeaching Procedure TAL KNX
TAL SOPNoneLeaching Procedure for Condensate TAL KNX
TAL SOPNoneLeaching Procedure for Filter TAL KNX
NoneSplitSource Air Split TAL KNX
Protocol References:
EPA = US Environmental Protection Agency
None = None
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 20 of 27 3/31/2021
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Sample Summary
Job ID: 140-22278-1Client: The Chemours Company FC, LLC
Project/Site: VEN Carbon Bed Outlet
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-22278-1 Z-2560,2561 VEN CB OUTLET R1 OTM-45 FH Air 03/09/21 00:00 03/13/21 10:40
140-22278-2 Z-2562,2563,2565 VEN CB OUTLET R1 OTM-45
BH
Air 03/09/21 00:00 03/13/21 10:40
140-22278-3 Z-2564 VEN CB OUTLET R1 OTM-45 IMPINGERS
1,2&3 COND
Air 03/09/21 00:00 03/13/21 10:40
140-22278-4 Z-2566 VEN CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/09/21 00:00 03/13/21 10:40
140-22278-5 Z-2567,2568 VEN CB OUTLET R2 OTM-45 FH Air 03/09/21 00:00 03/13/21 10:40
140-22278-6 Z-2569,2570,2572 VEN CB OUTLET R2 OTM-45
BH
Air 03/09/21 00:00 03/13/21 10:40
140-22278-7 Z-2571 VEN CB OUTLET R2 OTM-45 IMPINGERS
1,2&3 COND
Air 03/09/21 00:00 03/13/21 10:40
140-22278-8 Z-2573 VEN CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/09/21 00:00 03/13/21 10:40
140-22278-9 Z-2574,2575 VEN CB OUTLET R3 OTM-45 FH Air 03/09/21 00:00 03/13/21 10:40
140-22278-10 Z-2576,2577,2579 VEN CB OUTLET R3 OTM-45
BH
Air 03/09/21 00:00 03/13/21 10:40
140-22278-11 Z-2578 VEN CB OUTLET R3 OTM-45 IMPINGERS
1,2&3 COND
Air 03/09/21 00:00 03/13/21 10:40
140-22278-12 Z-2580 VEN CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/09/21 00:00 03/13/21 10:40
Eurofins TestAmerica, Knoxville
Page 21 of 27 3/31/2021
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QA/QC Laboratory Data

ANALYTICAL REPORT
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike
Knoxville, TN 37921
Tel: [phone]
Laboratory Job ID: 140-22287-1
Client Project/Site: PPA Carbon Bed Field QC
For:
The Chemours Company FC, LLC
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, Delaware 19713
Attn: Michael Aucoin
Authorized for release by:
4/6/2021 1:21:45 PM
Courtney Adkins, Project Manager II
[phone]
[e-mail]
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Laboratory Job ID: 140-22287-1
Page 2 of 23 Eurofins TestAmerica, Knoxville4/6/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
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Definitions/Glossary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Qualifiers
LCMS
Qualifier Description
B Compound was found in the blank and sample.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Knoxville
Page 3 of 23 4/6/2021
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Case Narrative
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Job ID: 140-22287-1
Laboratory: Eurofins TestAmerica, Knoxville
Narrative
Job Narrative
140-22287-1
Receipt
The samples were received on 3/13/2021 10:40 AM. Unless otherwise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.6º C.
LCMS
LC/MS/MS Sampling Train Preparation and Analysis: The sampling train components are extracted and analyzed for Per- and
Polyfluorinated Alkyl Substances (PFAS) using Eurofins TestAmerica Knoxville standard operating procedures KNOX-OP-0026 and
KNOX-LC-0007.
The sampling trains are prepared as four analytical fractions: The particulate filter and front half of the filter holder, nozzle and probe
solvent rinses are combined for one analytical fraction. The XAD-2 resin trap and back half of the filter holder, coil condenser and
connecting glassware solvent rinses are also combined as a separate analytical fraction. The condensate, impinger contents and their
related glassware DI water rinses make up the third analytical fraction. The breakthrough XAD module makes up the fourth analytical
fraction.
The filters and XAD components are spiked with isotope dilution internal standards and the components are extracted with
methanol/ammonium hydroxide by shaking for at least 18 hours. The extracts are concentrated to 10 mL and analyzed by HPLC/MS/MS.
The condensates are spiked with the isotope dilution internal standards and extracted using either Solid-Phase Extraction (SPE) or
diluting the water sample for analysis. Each extract at its final volume is 80:20 methanol:water
Sample results were calculated using the following equation:

Result, ηg/sample = (on-column concentration, ηg/mL) × (nominal final volume of extract (10 mL) / 1 sample) × DF × SF
Where:
DF = Instrument dilution factor
SF = Extraction Split Factor = (final volume of extract in the initial extraction batch / initial volume of extract in the “Split” batch)
For condensate, if less than the entire sample is extracted, the fraction of sample used replaces “1 sample”
Method 537 (modified): The method blank for preparation batch 140-48003 and 140-48146 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The Isotope Dilution Analyte (IDA) recovery associated with the following sample is below the method
recommended limit: (LCS 140-47984/2-B). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than
10:1.
Method 537 (modified): The method blank for preparation batch 140-47984 and 140-48079 HFPO-DA above the reporting limit (RL). The
entire sample was consumed during analysis or extraction, therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins TestAmerica, KnoxvillePage 4 of 23 4/6/2021
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Detection Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Client Sample ID: T-1108,1109 QC OTM-45 PPA CB FH BT Lab Sample ID: 140-22287-1
HFPO-DA
RL
0.00100 ug/Sample
MDL
0.000580
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00386 537 (modified)
Client Sample ID: T-1110,1111,1113 QC OTM-45 PPA CB BH BT Lab Sample ID: 140-22287-2
No Detections.
Client Sample ID: T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Lab Sample ID: 140-22287-3
HFPO-DA
RL
0.000500 ug/Sample
MDL
0.0000825
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00133 537 (modified)
Client Sample ID: T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN TUBE BT
Lab Sample ID: 140-22287-4
No Detections.
Client Sample ID: T-1115 QC OTM-45 PPA CB DI WATER RB Lab Sample ID: 140-22287-5
HFPO-DA
RL
0.000500 ug/Sample
MDL
0.0000825
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00121 537 (modified)
Client Sample ID: T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Lab Sample ID: 140-22287-6
No Detections.
Client Sample ID: T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Lab Sample ID: 140-22287-7
No Detections.
Client Sample ID: A-7359 MEDIA CHECK XAD Lab Sample ID: 140-22287-8
No Detections.
Client Sample ID: A-7360 MEDIA CHECK FILTER Lab Sample ID: 140-22287-9
HFPO-DA
RL
0.00100 ug/Sample
MDL
0.000580
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00267 537 (modified)
Eurofins TestAmerica, Knoxville
This Detection Summary does not include radiochemical test results.
Page 5 of 23 4/6/2021
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Client Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Lab Sample ID: 140-22287-1Client Sample ID: T-1108,1109 QC OTM-45 PPA CB FH BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00386 B 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 11:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 96 25-150 03/22/21 14:10 03/28/21 11:13 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-2Client Sample ID: T-1110,1111,1113 QC OTM-45 PPA CB BH BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 21:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 80 25-150 03/23/21 14:37 04/01/21 21:44 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-3Client Sample ID: T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00133 B 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 14:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 108 25-150 03/23/21 05:53 03/27/21 14:23 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-4Client Sample ID: T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN TUBE BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 21:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 76 25-150 03/23/21 14:37 04/01/21 21:53 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-5Client Sample ID: T-1115 QC OTM-45 PPA CB DI WATER RB
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00121 B 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 14:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 111 25-150 03/23/21 05:53 03/27/21 14:32 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Lab Sample ID: 140-22287-6Client Sample ID: T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 22:02 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 91 25-150 03/23/21 14:37 04/01/21 22:02 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-7Client Sample ID: T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 22:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 87 25-150 03/23/21 14:37 04/01/21 22:11 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-8Client Sample ID: A-7359 MEDIA CHECK XAD
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 22:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 74 25-150 03/23/21 14:37 04/01/21 22:37 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-9Client Sample ID: A-7360 MEDIA CHECK FILTER
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00267 B 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 11:22 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 83 25-150 03/22/21 14:10 03/28/21 11:22 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Isotope Dilution Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (25-150)
HFPODA
96140-22287-1
Percent Isotope Dilution Recovery (Acceptance Limits)
T-1108,1109 QC OTM-45 PPA CB FH BT
80140-22287-2 T-1110,1111,1113 QC OTM-45
PPA CB BH BT
108140-22287-3 T-1112 QC OTM-45 PPA CB
IMPINGER 1,2&3 COND BT
76140-22287-4 T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN
TUBE BT
111140-22287-5 T-1115 QC OTM-45 PPA CB DI
WATER RB
91140-22287-6 T-1116 QC OTM-45 PPA CB
MEOH WITH 5% NH4OH RB
87140-22287-7 T-1117 QC OTM-45 PPA CB
COMBINED GLASSWARE
RINSES (MEOH/5% NH4OH) PB
74140-22287-8 A-7359 MEDIA CHECK XAD
83140-22287-9 A-7360 MEDIA CHECK FILTER
32LCS 140-47984/2-B Lab Control Sample
112LCS 140-48003/2-B Lab Control Sample
76LCS 140-48051/2-B Lab Control Sample
96LCSD 140-47984/3-B Lab Control Sample Dup
107LCSD 140-48003/3-B Lab Control Sample Dup
78LCSD 140-48051/3-B Lab Control Sample Dup
76MB 140-47984/14-B Method Blank
92MB 140-47984/1-B Method Blank
102MB 140-48003/14-B Method Blank
112MB 140-48003/1-B Method Blank
93MB 140-48051/1-B Method Blank
Surrogate Legend
HFPODA = 13C3 HFPO-DA
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 140-47984/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
RL MDL
HFPO-DA 0.002612 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 03:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 76 25-150 03/28/21 03:40 1
MB MB
Isotope Dilution
03/22/21 14:10
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47984/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
RL MDL
HFPO-DA 0.002562 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 01:28 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 92 25-150 03/28/21 01:28 1
MB MB
Isotope Dilution
03/22/21 14:10
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47984/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02413 ug/Sample 121 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
32
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47984/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02295 ug/Sample 115 60-140 5 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
96
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-48003/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
RL MDL
HFPO-DA 0.001372 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 13:57 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 102 25-150 03/27/21 13:57 1
MB MB
Isotope Dilution
03/23/21 05:53
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 140-48003/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
RL MDL
HFPO-DA 0.001514 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 11:45 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 112 25-150 03/27/21 11:45 1
MB MB
Isotope Dilution
03/23/21 05:53
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-48003/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01114 ug/Sample 111 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
112
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-48003/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01177 ug/Sample 118 60-140 6 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
107
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-48051/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 48051
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 21:18 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 93 25-150 04/01/21 21:18 1
MB MB
Isotope Dilution
03/23/21 14:37
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-48051/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 48051
HFPO-DA 0.0200 0.02171 ug/Sample 109 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
76
LCS LCS
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-48051/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 48051
HFPO-DA 0.0200 0.02091 ug/Sample 105 60-140 4 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
78
LCSD LCSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
LCMS
Prep Batch: 47984
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Total/NA
Air None140-22287-9 A-7360 MEDIA CHECK FILTER Total/NA
Air NoneMB 140-47984/14-B Method Blank Total/NA
Air NoneMB 140-47984/1-B Method Blank Total/NA
Air NoneLCS 140-47984/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Prep Batch: 48003
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3 COND BTTotal/NA
Air None140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Total/NA
Air NoneMB 140-48003/14-B Method Blank Total/NA
Air NoneMB 140-48003/1-B Method Blank Total/NA
Air NoneLCS 140-48003/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Prep Batch: 48051
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Total/NA
Air None140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH XAD-2 RESIN TUBE BTTotal/NA
Air None140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5% NH4OH RBTotal/NA
Air None140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED GLASSWARE RINSES (MEOH/5% NH4OH) PBTotal/NA
Air None140-22287-8 A-7359 MEDIA CHECK XAD Total/NA
Air NoneMB 140-48051/1-B Method Blank Total/NA
Air NoneLCS 140-48051/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-48051/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48079
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47984140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Total/NA
Air Split 47984140-22287-9 A-7360 MEDIA CHECK FILTER Total/NA
Air Split 47984MB 140-47984/14-B Method Blank Total/NA
Air Split 47984MB 140-47984/1-B Method Blank Total/NA
Air Split 47984LCS 140-47984/2-B Lab Control Sample Total/NA
Air Split 47984LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48146
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 48003140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3 COND BTTotal/NA
Air Split 48003140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Total/NA
Air Split 48003MB 140-48003/14-B Method Blank Total/NA
Air Split 48003MB 140-48003/1-B Method Blank Total/NA
Air Split 48003LCS 140-48003/2-B Lab Control Sample Total/NA
Air Split 48003LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3 COND BTTotal/NA
Air 537 (modified)48146140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Total/NA
Air 537 (modified)48146MB 140-48003/14-B Method Blank Total/NA
Air 537 (modified)48146MB 140-48003/1-B Method Blank Total/NA
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
LCMS (Continued)
Analysis Batch: 48210 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146LCS 140-48003/2-B Lab Control Sample Total/NA
Air 537 (modified)48146LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48219
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48079MB 140-47984/14-B Method Blank Total/NA
Air 537 (modified)48079MB 140-47984/1-B Method Blank Total/NA
Air 537 (modified)48079LCS 140-47984/2-B Lab Control Sample Total/NA
Air 537 (modified)48079LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48223
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48079140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Total/NA
Air 537 (modified)48079140-22287-9 A-7360 MEDIA CHECK FILTER Total/NA
Cleanup Batch: 48224
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 48051140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Total/NA
Air Split 48051140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH XAD-2 RESIN TUBE BTTotal/NA
Air Split 48051140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5% NH4OH RBTotal/NA
Air Split 48051140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED GLASSWARE RINSES (MEOH/5% NH4OH) PBTotal/NA
Air Split 48051140-22287-8 A-7359 MEDIA CHECK XAD Total/NA
Air Split 48051MB 140-48051/1-B Method Blank Total/NA
Air Split 48051LCS 140-48051/2-B Lab Control Sample Total/NA
Air Split 48051LCSD 140-48051/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48419
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48224140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Total/NA
Air 537 (modified)48224140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH XAD-2 RESIN TUBE BTTotal/NA
Air 537 (modified)48224140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5% NH4OH RBTotal/NA
Air 537 (modified)48224140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED GLASSWARE RINSES (MEOH/5% NH4OH) PBTotal/NA
Air 537 (modified)48224140-22287-8 A-7359 MEDIA CHECK XAD Total/NA
Air 537 (modified)48224MB 140-48051/1-B Method Blank Total/NA
Air 537 (modified)48224LCS 140-48051/2-B Lab Control Sample Total/NA
Air 537 (modified)48224LCSD 140-48051/3-B Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Client Sample ID: T-1108,1109 QC OTM-45 PPA CB FH BT Lab Sample ID: 140-22287-1
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48223 03/28/21 11:13 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1110,1111,1113 QC OTM-45 PPA CB BH BT Lab Sample ID: 140-22287-2
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 21:44 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Lab Sample ID: 140-22287-3
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 14:23 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN TUBE BT
Lab Sample ID: 140-22287-4
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 21:53 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1115 QC OTM-45 PPA CB DI WATER RB Lab Sample ID: 140-22287-5
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 14:32 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Client Sample ID: T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Lab Sample ID: 140-22287-6
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 22:02 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Lab Sample ID: 140-22287-7
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 22:11 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: A-7359 MEDIA CHECK XAD Lab Sample ID: 140-22287-8
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 22:37 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: A-7360 MEDIA CHECK FILTER Lab Sample ID: 140-22287-9
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48223 03/28/21 11:22 JRC TAL KNXTotal/NA
LCAInstrument ID:
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
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Accreditation/Certification Summary
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Laboratory: Eurofins TestAmerica, Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
N/AAFCEE
ANAB Dept. of Defense ELAP L2311 02-13-22
ANAB Dept. of Energy L2311.01 02-13-22
ANAB ISO/IEC 17025 L2311 02-13-22
ANAB ISO/IEC 17025 L2311 02-14-22
Arkansas DEQ State 88-0688 06-17-21
California State 2423 06-30-22
Colorado State TN00009 02-28-21 *
Connecticut State PH-0223 09-30-21
Florida NELAP E87177 07-01-21
Georgia (DW)State 906 12-11-22
Hawaii State NA 12-11-21
Kansas NELAP E-10349 10-31-21
Kentucky (DW)State 90101 12-31-21
Louisiana NELAP 83979 06-30-21
Louisiana (DW)State LA019 12-31-21
Maryland State 277 03-31-22
Michigan State 9933 12-11-22
Nevada State TN00009 07-31-21
New Hampshire NELAP 299919 01-17-22
New Jersey NELAP TN001 07-01-21
New York NELAP 10781 03-31-22
North Carolina (DW)State 21705 07-31-21
North Carolina (WW/SW)State 64 12-31-21
Ohio VAP State CL0059 06-02-23
Oklahoma State 9415 08-31-21
Oregon NELAP TNI0189 01-01-22
Pennsylvania NELAP 68-00576 12-31-21
Tennessee State 02014 12-11-22
Texas NELAP T104704380-18-12 08-31-21
US Fish & Wildlife US Federal Programs 058448 07-31-21
USDA US Federal Programs P330-19-00236 08-20-22
Utah NELAP TN00009 07-31-21
Virginia NELAP 460176 09-14-21
Washington State C593 01-19-22
West Virginia (DW)State 9955C 01-02-22
West Virginia DEP State 345 05-01-21
Wisconsin State 998044300 08-31-21
Eurofins TestAmerica, Knoxville
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
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Method Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL KNX
TAL SOPNoneLeaching Procedure TAL KNX
TAL SOPNoneLeaching Procedure for Condensate TAL KNX
TAL SOPNoneLeaching Procedure for Filter TAL KNX
NoneSplitSource Air Split TAL KNX
Protocol References:
EPA = US Environmental Protection Agency
None = None
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
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Sample Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Air 03/09/21 00:00 03/13/21 10:40
140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Air 03/09/21 00:00 03/13/21 10:40
140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Air 03/09/21 00:00 03/13/21 10:40
140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH
XAD-2 RESIN TUBE BT
Air 03/09/21 00:00 03/13/21 10:40
140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Air 03/09/21 00:00 03/13/21 10:40
140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Air 03/09/21 00:00 03/13/21 10:40
140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Air 03/09/21 00:00 03/13/21 10:40
140-22287-8 A-7359 MEDIA CHECK XAD Air 03/09/21 00:00 03/13/21 10:40
140-22287-9 A-7360 MEDIA CHECK FILTER Air 03/09/21 00:00 03/13/21 10:40
Eurofins TestAmerica, Knoxville
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Ramboll - Source Emissions Testing Of The Vinyl Ethers North Carbon Bed

APPENDIX E
EQUIPMENT CALIBRATION DATA

Pretest Equipment Calibration Data

METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES
1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.
2) Record barometric pressure before and after calibration procedure.
3) Run at tested vacuum (from Orifice Calibration Report), for a period of time
necessary to achieve a minimum total volume of 5 cubic feet.
4) Record data and information in the GREEN cells, YELLOW cells are calculated.
INITIAL FINAL AVG (Pbar)
DATE:2/10/2021 METER SERIAL #:MB3 BAROMETRIC PRESSURE (in Hg):30.38 30.38 30.38
METER PART #:CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to with other
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y orifices DH@
1 0.306 24 889.290 895.162 5.872 57 60 61 60 60 60.25 15.00 0.44 6.0587 6.1346 1.013 1.53
2 0.306
3 0.306
AVG = 1.013 1.06 1.35
1 0.4268 22.5 895.162 900.693 5.531 58 61 62 60 61 61 10.00 0.86 5.7045 5.6987 0.999 1.54
2 0.4268
3 0.4268
AVG = 0.999 -0.29 -0.20
1 0.4961 21.5 900.693 907.113 6.420 58 62 63 61 61 61.75 10.00 1.2 6.6172 6.6240 1.001 1.59
2 0.4961
3 0.4961
AVG = 1.001 -0.09 0.47
1 0.7131 19 907.113 916.371 9.258 58 63 65 61 62 62.75 10.00 2.6 9.5563 9.5215 0.996 1.67
2 0.7131
3 0.7131
AVG = 0.996 -0.56 -0.43
1 0.8358 17.5 916.371 927.180 10.809 58 65 67 62 63 64.25 10.00 3.6 11.1521 11.1598 1.001 1.68
2 0.8358
3 0.8358
AVG = 1.001 -0.12 0.44
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = 1.002
AVERAGE DH@ = 1.60
(1)=Net volume of gas sample passed through DGM, corrected to standard conditions
K1 =17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)
Tm =Absolute DGM avg. temperature (oR - English, oK - Metric) DH@ = 0.75 q DH Vm(std)
Vcr(std) Vm
(2)=Volume of gas sample passed through the critical orifice, corrected to standard conditions
Tamb =Absolute ambient temperature (oR - English, oK - Metric)
K' = Average K' factor from Critical Orifice Calibration
(3)=DGM calibration factor
11
26
31
16
18
ENVIRONMENTAL SUPPLY COMPANY
USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.
()2 ()
V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Initial Calibrations\Dry Gas Meters\2021\MB 3\MB 3 Initial Cal 02102021.xls
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES
1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.
2) Record barometric pressure before and after calibration procedure.
3) Run at tested vacuum (from Orifice Calibration Report), for a period of time
necessary to achieve a minimum total volume of 5 cubic feet.
4) Record data and information in the GREEN cells, YELLOW cells are calculated.
INITIAL FINAL AVG (Pbar)
DATE:1/11/2021 METER SERIAL #:MB 5 BAROMETRIC PRESSURE (in Hg):29.92 29.92 29.92
METER PART #:CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to with other
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y orifices DH@
1 0.306 23.5 606.287 614.284 7.997 64 65 66 67 66 66 20.00 0.51 8.0390 8.0016 0.995 1.80
2 0.306
3 0.306
AVG = 0.995 0.43 0.82
1 0.4268 22 614.297 619.908 5.611 65 66 67 66 66 66.25 10.00 1.05 5.6453 5.5749 0.988 1.91
2 0.4268
3 0.4268
AVG = 0.988 -0.36 0.02
1 0.4961 21 619.923 626.441 6.518 66 67 68 66 66 66.75 10.00 1.4 6.5572 6.4739 0.987 1.89
2 0.4961
3 0.4961
AVG = 0.987 -0.38 -0.02
1 0.7131 19 626.447 635.794 9.347 66 68 72 67 67 68.5 10.00 2.9 9.4065 9.3057 0.989 1.90
2 0.7131
3 0.7131
AVG = 0.989 -0.18 0.20
1 0.8358 17.5 635.813 646.695 10.882 67 71 74 68 69 70.5 10.00 4 10.9392 10.8965 0.996 1.90
2 0.8358
3 0.8358
AVG = 0.996 0.50 0.89
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = 0.991
AVERAGE DH@ = 1.88
(1)=Net volume of gas sample passed through DGM, corrected to standard conditions
K1 =17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)
Tm =Absolute DGM avg. temperature (oR - English, oK - Metric) DH@ = 0.75 q DH Vm(std)
Vcr(std) Vm
(2)=Volume of gas sample passed through the critical orifice, corrected to standard conditions
Tamb =Absolute ambient temperature (oR - English, oK - Metric)
K' = Average K' factor from Critical Orifice Calibration
(3)=DGM calibration factor
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USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.
()2 ()
V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Initial Calibrations\Dry Gas Meters\2021\MB 5\MB 5 Initial Cal 01112021.xls
Initial Oven Box Thermocouple Calibration
Reference Thermocouple Reference Thermocouple Reference ThermocoupleTemperature (oR)Temperature (oR)Temperature (oR)Temperature (oR)Temperature (oR)Temperature (oR)
OB-1 491.67 492.67 0.2%524.67 523.67 -0.2%671.67 673.67 0.3%SMilo 02/22/21
OB-2 491.67 492 0.1%530.67 531 0.1%671.67 672 0.0%SRW 03/02/21
OB-3 491.67 493 0.3%530.67 530 -0.1%671.67 671 -0.1%SRW 03/02/21
OB-4 491.67 493.67 0.4%524.67 524.67 0.0%671.67 670.67 -0.1%SMilo 02/22/21
OB-A 491.67 493 0.3%530.67 529 -0.3%671.67 673 0.2%SRW 03/02/21
OB-B 491.67 492 0.1%530.67 530 -0.1%671.67 672 0.0%SRW 03/02/21
OB-5 491.67 492 0.1%530.67 530 -0.1%671.67 670 -0.2%SRW 03/02/21
OB-C 491.67 492 0.1%530.67 529 -0.3%671.67 674 0.3%SRW 03/03/21
OB-6 491.67 493.67 0.4%524.67 525 0.1%671.67 669.67 -0.3%SMilo 02/22/21
OB-7 491.67 494.67 0.6%524.67 525 0.1%671.67 669.67 -0.3%SMilo 02/22/21
OB-E 491.67 492 0.1%530.67 529 -0.3%671.67 671.67 0.0%SRW 03/03/21
OB-10 491.67 492 0.1%530.67 531 0.1%671.67 670 -0.2%SRW 03/03/21
OB-11 491.67 495 0.7%530.67 532 0.3%671.67 672 0.0%SRW 03/03/21
OB-12 491.67 493 0.3%530.67 531 0.1%671.67 671 -0.1%SRW 03/03/21
Reference Thermocouple: Fluke S/N: 83450033 or S/N 90460057 traceable to the Untied States National Institute of Standards and Technology
*Acceptable Deviation: 1.5%
ID Number Ice Bath Ambient Hot Water Bath
Deviation*Deviation*Deviation*Technician Date
Performed
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\Copy of Init OB Cal 03032021.xls\2020
  DOCUMENT TITLEInitial Impinger Outlet Thermocouple CalibrationReference ThermocoupleReference ThermocoupleReference ThermocoupleTemperature (oRk)Temperature (oRk)Temperature (oRk)Temperature (oRk)Temperature (oRk)Temperature (oRk)IO-1 494.17 493.87 -0.1% 524.37 523.17 -0.2% 672.17 672.67 0.1% SM 03/16/21IO-2 493.67 493.87 0.0% 524.57 523.17 -0.3% 671.77 672.67 0.1% SM 03/16/21IO-3 493.57 493.87 0.1% 521.37 523.17 0.3% 671.77 672.67 0.1% SM 03/16/21IO-4 493.97 493.87 0.0% 524.37 523.17 -0.2% 671.17 672.67 0.2% SM 03/16/21IO-5 493.77 493.87 0.0% 524.07 523.17 -0.2% 672.37 672.67 0.0% SM 03/16/21IO-6 493.97 493.87 0.0% 522.97 523.17 0.0% 670.77 672.67 0.3% SM 03/16/21IO-7 493.17 493.87 0.1% 524.37 523.17 -0.2% 671.37 672.67 0.2% SM 03/16/21IO-8 494.37 493.87 -0.1% 523.67 523.17 -0.1% 670.37 672.67 0.3% SM 03/16/21IO-9IO-10 493.77 493.87 0.0% 524.27 523.17 -0.2% 671.27 672.67 0.2% SM 03/16/21IO-11 494.37 493.87 -0.1% 524.37 523.17 -0.2% 672.27 672.67 0.1% SM 03/16/21IO-12 493.77 493.87 0.0% 522.17 523.17 0.2% 671.47 672.67 0.2% SM 03/16/21IO-13SM 03/16/21IO-14 493.87 493.87 0.0% 524.37 523.17 -0.2% 670.87 672.67 0.3% SM 03/16/21IO-15 494.17 493.87 -0.1% 524.37 523.17 -0.2% 671.47 672.67 0.2% SM 03/16/21IO-16 494.37 493.87 -0.1% 524.37 523.17 -0.2% 671.07 672.67 0.2% SM 03/16/21IO-17 493.37 493.87 0.1% 522.17 670.97IO-18 494.17 493.87 -0.1% 524.37 523.17 -0.2% 671.27 672.67 0.2% SM 03/16/21IO-19 493.97 493.87 0.0% 524.77 523.17 -0.3% 672.97 672.67 0.0% SM 03/16/21Reference Thermocouple: Fluke S/N: 83450033 or S/N 90460057 traceable to the Untied States National Institute of Standards and Technology*Acceptable Deviation: 1.5%TechnicianDate PerformedID NumberIce Bath Ambient Hot Water BathDeviation* Deviation* Deviation*V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Initial Calibrations\Impinger Outlets\2021\2021 Init I.O. Cal.xlsx\2019
DOCUMENT TITLE Initial Sample Probe Calibration Form
Probe ID Date Technician
Is the Pitot Level and Perpindicular?Yes
Is There any Obstruction?No
Is the Pitot Damaged No
α1 (-10o = α1 = + 10o)1
α2 (-10o = α2 = + 10o)0
ß1 (-5o = ß1 = + 5o)1
ß2 (-5o = ß2 = + 5o)1
γ 1
Θ 0
z = A Tan γ (< 0.125")0.011
W = A Tan Θ (< 0.03125")0.0000
Dt (3/16 = Dt = 3/8")0.252
A 0.655
A/2Dt (1.05 = PA/Dt = 1.5)1.300
Source: Quality Assurance Handbook for Air Pollution Measurement
Systems: Volume III, Stationary Source-Specific Methods.
EPA/600/R-94/038c, September 30, 1994
Verification of "S" Type Pitot, Thermocouple and Nozzle Placement
Does X Exceed 0.75 inches?Yes
Does Y Exceed 3 inches?NA
Thermocouple Calibration
1 2 3 1 2 3 1 2 3Reference Temp 492 492 492 526 526 526 672 672 672
Thermocouple Temp 492 492 492 525 525 525 672 672 672
Difference (%)0.0 0.0 0.0 -0.2 -0.2 -0.2 0.0 0.0 0.0
Temperature values must be within 1.5% of reference temperature
I certify that the probe ID meets or exceeds all specifications, criteria and/or applicable design features and is herby assigned a pitot tube calibration factor CP of 0.84.
Certified By:Date:S. Waters 01/28/21
Ambient OR Boiling Water OR
S. Waters
P4-1/TC-7C
"S" Type Pitot Calibration
P4-1/TC-7C 01/28/21
Ice Bath OR
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\2021 Initial Probe Cal P4-1.xlsx\Initial
DOCUMENT TITLE
Initial Sample Probe Calibration Form
Probe ID Date Technician
Is the Pitot Level and Perpindicular?Yes
Is There any Obstruction?No
Is the Pitot Damaged No
a1 (-10o = a1 = + 10o)2
a2 (-10o = a2 = + 10o)1
ß1 (-5o = ß1 = + 5o)1
ß2 (-5o = ß2 = + 5o)1
g 1
Q 0
z = A Tan g (< 0.125")0.011
W = A Tan Q (< 0.03125")0.0000
Dt (3/16 = Dt = 3/8")0.251
A 0.650
A/2Dt (1.05 = PA/Dt = 1.5)1.295
Source: Quality Assurance Handbook for Air Pollution Measurement
Systems: Volume III, Stationary Source-Specific Methods.
EPA/600/R-94/038c, September 30, 1994
Verification of "S" Type Pitot, Thermocouple and Nozzle Placement
Does X Exceed 0.75 inches?Yes
Does Y Exceed 3 inches?NA
Thermocouple Calibration
1 2 3 1 2 3 1 2 3Reference Temp 492.3 492.3 492.3 533.4 533.4 533.4 671.5 671.5 671.5
Thermocouple Temp 492.9 492.8 492.8 532.7 532.6 532.7 673.1 673 673
Difference (%)0.1 0.1 0.1 -0.1 -0.1 -0.1 0.2 0.2 0.2
Temperature values must be within 1.5% of reference temperature
I certify that the probe ID meets or exceeds all specifications, criteria and/or applicable design features and is
herby assigned a pitot tube calibration factor CP of 0.84.
Certified By:Date:P. Grady 06/16/20
Ambient OR Boiling Water OR
P. Grady
P4-2/TC-5D
"S" Type Pitot Calibration
P4-2/TC-5D 06/16/20
Ice Bath OR
V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Initial Calibrations\Probes and Pitots\2020 Initial Cals\4'\2020 Initial Probe Cal P4-2.xlsx\Initial

Post Test Equipment Calibration Data

DOCUMENT TITLE
POST TEST DRY GAS METER CALIBRATION
INITIAL FINAL AVG (Pbar)
DATE:03/17/21 METER BOX #:3 BAROMETRIC PRESSURE (in Hg):29.99 29.99 29.99
TECHNICIAN:S.Milo CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y DH@
1
2
3
AVG =
1 0.4961 21 273.710 280.129 6.419 68 67 68 66 66 66.75 10.00 1.2 6.4695 6.4767 1.001 0.18 1.62
18 2 0.4961 21 280.129 287.222 7.093 68 68 69 67 67 67.75 11.00 1.2 7.1352 7.1244 0.998 -0.09 1.62
3 0.4961 21 287.222 293.667 6.445 70 69 70 67 68 68.5 10.00 1.2 6.4742 6.4645 0.999 -0.09 1.62
AVG = 0.999
1
2
3
AVG =
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =
PRE-DETERMINED DRY GAS METER CALIBRATION FACTOR, Y =
PERCENT DIFFERENCE =
0.999
1.002
-0.3
V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Post Test Calibrations\Meter Boxes\2021\MB 3\MB 3 Post Cal 03172021.xlsx\Sheet1
DOCUMENT TITLE
POST TEST DRY GAS METER CALIBRATION
INITIAL FINAL AVG (Pbar)
DATE:03/17/21 METER BOX #:5 BAROMETRIC PRESSURE (in Hg):29.99 29.99 29.99
TECHNICIAN:S. Milo CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y DH@
1
2
3
AVG =
1 0.4961 21 333.449 339.942 6.493 71 66 67 63 64 65 10.00 1.4 6.5691 6.4584 0.983 0.06 1.91
18 2 0.4961 21 339.942 346.462 6.520 71 67 70 64 65 66.5 10.00 1.4 6.5776 6.4584 0.982 -0.07 1.90
3 0.4961 21 346.462 352.996 6.534 72 70 71 66 67 68.5 10.00 1.4 6.5668 6.4523 0.983 0.00 1.90
AVG = 0.983
1
2
3
AVG =
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =
PRE-DETERMINED DRY GAS METER CALIBRATION FACTOR, Y =
PERCENT DIFFERENCE =
0.983
0.991
-0.9
V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Post Test Calibrations\Meter Boxes\2021\MB 5\MB 5 Post Cal 03172021.xlsx\Sheet1