2021.04.21_Chemours PPA Report

Intended for
The Chemours Company – Fayetteville, North Carolina

Document type
Report

Date
April 2021

SOURCE EMISSIONS
TESTING OF THE
POLYMER PROCESS AID
CARBON BED

Ramboll
7600 Morgan Road
Liverpool, NY 13090
USA

T 315-637-2234
F 315-637-2819
https://ramboll.com

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SOURCE EMISSIONS TESTING OF THE POLYMER PROCESS AID
CARBON BED

Project name PFAS Emissions Testing
Project no. 1088211\1940100745
Recipient Christel Compton
Document type Source Emission Test Report
Version 1
Date April 21, 2021
Prepared by Patrick Grady, Project Associate
Checked by David Ostaszewski, PE, Senior Managing Engineer

Ramboll
7600 Morgan Road
Liverpool, NY 13090
USA

T 315-637-2234
F 315-637-2819
https://ramboll.com

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________________________________
Patrick Grady
Project Associate
Ramboll

________________________________
David Ostaszewski, PE
Senior Managing Engineer
Ramboll

This report has been reviewed and to the best of our knowledge the report is complete, and the results presented herein are accurate, error free, legible, and representative of the actual emissions measured during testing.

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CONTENTS
1. Introduction and Background 3
Testing Objective 3
Emissions Testing Program Participants 3
2. Process Description 5
Process Description 5
Operating Conditions During Testing 5
3. Summary of Test Program 6
Test Program Summary 6
4. Sampling and Analytical Procedures 7
Test Methods 7
Sampling Locations 7
Gas Velocity and Volumetric Flow Rate 7
Oxygen and Carbon Dioxide Concentrations 7
Moisture Content 8
HFPO-DA Emissions 8
4.6.1 HFPO-DA Sample Train and Equipment Preparation 8
4.6.2 HFPO-DA Sample Train Recovery 9
5. Emissions Test Results 10
Emission Test Results 10
Discussion and Conclusion 10
6. Quality Assurance/Quality Control 11
Equipment Calibration 11
Equipment Leak Checks 11
Reagent Blanks and Field Blanks 11
Test Data and Report Review 12

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LIST OF TABLES
1. Summary of Emission Test Results
LIST OF APPENDICES
A. Process Operating Data
B. Schematic of the Test Locations
C. Field Data and Calculations
D. Laboratory Data
E. Equipment Calibration Data

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1. INTRODUCTION AND BACKGROUND
Ramboll Americas Engineering Solutions, Inc. (Ramboll) was retained by The Chemours Company
(Chemours) to conduct source emissions testing at its facility located in Fayetteville, North
Carolina. Ramboll has prepared the following test report summarizing the results of the testing
on behalf of Chemours.
Testing Objective

As provided in their Title V Air Permit, Chemours is required to evaluate hexafluoro-propylene
oxide-dimer acid (HFPO-DA) emissions from a carbon bed adsorber at the Fayetteville Works
facility. The objective of this test program was to collect field sample data from the inlet and
outlet to the carbon bed serving the Polymer Process Aid (PPA) area to determine carbon bed
replacement frequency.

The source emissions test program was performed on March 11, 2021. Messrs. Patrick Grady,
Jeff Sheldon, Brian Goodhile, Antonio Anderson and Ms. Samantha Waters of Ramboll conducted
the emissions testing. Ms. Christel Compton and Mr. Edward Vega coordinated process operations
with the emissions testing. There were no representatives from any of the regulatory agencies
present to observe the field test program.

This report presents a description of the sources tested, a summary of the scope of work
conducted, sampling methods used, QA/QC procedures, and emission test results. The following
section lists the testing program’s participants and their contact information.
Emissions Testing Program Participants

Facility

Name: The Chemours Company

Site Address: 22828 Hwy 87 W
Fayetteville, NC 28306

Contact: Christel E. Compton

e-mail: [e-mail]

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Source Testing Firm

Name: Ramboll

Address: 7600 Morgan Road
Liverpool, NY 13090

Contact: Patrick Grady

e-mail: [e-mail]

Sample Analysis Laboratory

Name: Eurofins/TestAmerica, Knoxville

Address: 5815 Middlebrook Pike
Knoxville, Tennessee 37921

Contact: Courtney Adkins

e-mail: [e-mail]

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2. PROCESS DESCRIPTION
This section provides a description of the PPA process.
Process Description

The PPA facility produces surfactants used to produce fluoropolymer products, such as Teflon®
at other Chemours facilities, as well as sales to outside producers of fluoropolymers.
Process streams are vented to a caustic wet scrubber (ACD-A1), a carbon bed and exhausted
through a process stack (AEP-A1). The process inside the building is under negative pressure and
the building air is vented to the carbon bed and the process stack (AEP-A1).
Operating Conditions During Testing

Source emissions testing was performed during normal operations of the PPA process. Facility
personnel monitored and recorded process operations during the testing. These operating data
were provided to Ramboll and are included in Appendix A of this report.

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3. SUMMARY OF TEST PROGRAM
This section provides a summary of the testing scope of work conducted. Test methods used
during the sampling program can be found in Section 4 of this report.
Test Program Summary

Emissions testing was conducted simultaneously at the inlet and outlet of the PPA carbon bed in
order to evaluate potential emissions and removal efficiencies of HFPO-DA. The testing at each
location was conducted in triplicate and each test run was 96 minutes in duration. Results of the
source emission testing are reported in units of milligrams per dry standard cubic meter
(mg/dscm) and pounds per hour (lb/hr).

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4. SAMPLING AND ANALYTICAL PROCEDURES
This section provides a description of the test methods that were utilized during the test
program.
Test Methods

The test procedures were conducted in accordance with the most recent updates to the United
States Environmental Protection Agency (USEPA) Reference Methods (RM) described in 40 CFR
60; Appendix A.

RM 1: Sample and velocity traverses for stationary sources
RM 2: Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)
RM 3: Determination of oxygen and carbon dioxide concentrations in emissions from
stationary sources
RM 4: Determination of moisture content in stationary sources
Modified 0010: Determination of PFAS emissions from stationary sources (modified)
Sampling Locations

The sampling ports at the 34-inch inside diameter (ID) carbon bed inlet duct are located
approximately 60 inches (1.8 diameters) downstream of a bend and approximately 42 inches
(1.2 diameters) upstream of the carbon bed. Test ports in the 30-inch ID carbon bed outlet stack
are located approximately 12 feet (4.8 diameters) downstream of the nearest disturbance and
approximately 30 feet (12 diameters) upstream from the stack exit. A total of 12 traverse points
were sampled on each diameter during each test run for a total of 24 traverse points. Traverse
points were located in accordance with USEPA RM 1. Schematics of the sample locations along
with traverse point locations are provided in Appendix B.
Gas Velocity and Volumetric Flow Rate

Velocity was evaluated from differential pressure measurements using a stainless-steel Type-S
pitot tube and oil manometer in accordance with USEPA RMs 1 and 2. These methods were
conducted in conjunction with each test run. Exhaust gas volumetric flow rate in units of dry
standard cubic feet per minute (dscfm) were derived from velocity, temperature, molecular
weight, and moisture measurements. Pollutant mass emission rates (lb/hr) were calculated using
these volumetric flow rate data and pollutant concentrations.
Oxygen and Carbon Dioxide Concentrations

Concentrations of oxygen (O2) and carbon dioxide (CO2) were evaluated at both locations in
accordance with modified USEPA RM 3 procedures using a Fyrite® combustion analyzer. A grab
sample was collected and introduced into the Fyrite® for O2 and CO2 analysis.

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Moisture Content

The moisture content of the sample trains was quantified utilizing procedures identified in USEPA
RM 4. A sample of gas was continuously collected from each traverse point using a dry gas meter
stack sampling system along with a series of impingers. The moisture content of the gas was
measured as a change in the volume of the water collected in each impinger solution and the
increased weight of the desiccant during the sampling period.
HFPO-DA Emissions

HFPO-DA emissions were evaluated in accordance with a modified USEPA Method 0010. The
sample train consisted of a glass nozzle attached directly to a heated borosilicate glass-lined
probe. The probe was connected directly to a heated borosilicate glass filter holder containing a
solvent-extracted glass fiber filter. In order to minimize possible thermal degradation of the
HFPO-DA, the probe and particulate filter were heated to just above stack temperature to
minimize water vapor condensation before the filter. The filter holder exit was connected to a
water-cooled coil condenser followed by a water-cooled sorbent module containing approximately
40 grams of XAD-2 resin. The XAD-2 inlet temperature was monitored to ensure that the module
is maintained at a temperature below 20oC.

The XAD-2 resin trap was followed by a condensate knockout impinger and a series of two
impingers each containing 100-ml of high purity deionized water. The water impingers were
followed by another condensate knockout impinger equipped with a second XAD-2 resin trap to
account for any sample breakthrough. The final impinger contained approximately 250 grams of
dry pre-weighed silica gel. The water impingers and condensate impingers were submerged in an
ice bath through the duration of the testing. The water in the ice bath was also used to circulate
around the coil condenser and the XAD-2 resin traps.

Exhaust gases were extracted from the sample locations isokinetically using a metering console
equipped with a vacuum pump, a calibrated orifice, oil manometer and probe/filter heat
controllers.
4.6.1 HFPO-DA Sample Train and Equipment Preparation
Prior to conducting the field work the following procedures were conducted to prepare the field
sampling glassware and sample recovery tools.

1. Wash all glassware, brushes, and ancillary tools with low residue soap and hot water.
2. Rinse all glassware, brushes, and ancillary tools three (3) times with D.I. H20.
3. Bake glassware (with the exception of probe liners) at 450˚C for approximately 2 hours,
(XAD-2 resin tube glassware will be cleaned by Eurofins/TestAmerica by this same procedure). 4. Solvent rinse three (3) times all glassware, brushes, and ancillary tools with the following
sequence of solvents: acetone, methylene chloride, hexane, and methanol.
5. Clean glassware and tools will be sealed in plastic bags or aluminum foil for transport to the
sampling site.
6. Squirt bottles will be new dedicated bottles of known history and dedicated to the D.I. Water
and methanol/ammonium hydroxide (MeOH/ 5% NH4OH) solvent contents. Squirt bottles will
be labelled with the solvent content it contains.
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4.6.2 HFPO-DA Sample Train Recovery
Following completion of each test run, the sample probe, nozzle and front-half of the filter holder
were brushed and rinsed three times each with the MeOH/ 5% NH4OH solution (Container #1).
The glass fiber filter was removed from its housing and transferred to a polyethylene bottle
(Container #2). Any particulate matter and filter fibers which adhered to the filter holder and
gasket were also placed in Container #2. The XAD-2 resin trap was sealed, labelled and placed in
an iced sample cooler. The back-half of the filter holder, coil condenser condensate trap and
connecting glassware were rinsed with the same MeOH/ 5% NH4OH solution and placed in
Container #3.

The volume of water collected in the second and third impingers was measured for moisture
determinations and then placed in Container #4. Impingers #2 and #3 were then rinsed with the
MeOH/ 5% NH4OH solution and placed in Container #5. The second (breakthrough) XAD-2 resin
trap was sealed, labelled and placed in an iced sample cooler. The second condensate trap was
rinsed with the MeOH/ 5% NH4OH solution and placed in Container #5. The contents of the fifth
impinger were placed in its original container and weighed for moisture determinations.

Containers were labeled with the appropriate sample information. Samples remained chilled until
analysis. HFPO-DA analysis was conducted using liquid chromatography/dual mass spectrometry
(LC/MS/MS).

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5. EMISSIONS TEST RESULTS
A detailed summary of the test results is presented in Table 1 in the appendix. Supporting field
data and calculations can be found in Appendix C. The laboratory report is presented in Appendix
D. A brief discussion of the test results is presented below.
Emission Test Results

Table 1 presents a detailed summary of the HFPO-DA test results. HFPO-DA concentrations at the
carbon bed inlet ranged from 9.94E-02 mg/dscm to 1.19E-01 mg/dscm and averaged 1.10E-01
mg/dscm. Corresponding mass emissions of HFPO-DA ranged from 5.07E-03 lb/hr to 6.08E-03
lb/hr and averaged 5.67E-03 lb/hr.

Concentrations of HFPO-DA at the carbon bed outlet ranged from 2.02E-03 mg/dscm to 4.13E-02
mg/dscm and averaged 3.06E-03 mg/dscm. Mass emission rates of HFPO-DA from the carbon
bed outlet ranged from 8.10E-05 lb/hr to 1.68E-04 lb/hr and averaged 1.23E-04 lb/hr. The
resulting HFPO-DA removal efficiency of the PPA carbon bed ranged from 97 percent to 98
percent and averaged 98 percent.

Note that for test Run 3 HFPO-DA emissions were calculated without including the analytical data
for the breakthrough XAD module. It is believed there was contamination on the breakthrough
XAD module from Run 3 at the carbon bed outlet. A review of the analytical reports confirms
that, with the exception of Run 3 at the carbon bed outlet, the highest concentration of HFPO-DA
is captured in the front-half of the sampling train and then descending through the back-half and
condenser portion (impingers) of the sample train. All test runs were conducted on the same day
and a review of production data indicates there was no change or upset in the process during the
testing. The carbon bed currently only controls PPA indoor air fugitives and there were no leaks
during the testing. Therefore, it is believed that the contamination of the breakthrough XAD
module did not come from the carbon bed outlet.
Discussion and Conclusion

There were no process operating or sampling problems encountered during the field testing that
impacted the test results. Therefore, all test data are believed to be representative of actual
emissions in evidence during the test program.

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6. QUALITY ASSURANCE/QUALITY CONTROL
QA/QC was based on the recommended QA/QC procedures of the various sampling and analytical
methods that were used for the test program. This section summarizes the pertinent QA/QC
procedures that were employed during the emissions testing program.
Equipment Calibration

An important aspect of pre-sampling preparations is the inspection and calibration of all
equipment planned to be used for the field effort. Equipment is inspected for proper operation
and durability prior to calibration. Calibration of equipment is conducted in accordance with the
procedures outlined in the USEPA document entitled "Quality Assurance Handbook for Air
Pollution Measurement Systems; Volume III—Stationary Source Specific Methods" (EPA-600/4-
77-027b). Equipment calibration is performed in accordance with USEPA guidelines and/or
manufacturer’s recommendations. Examples of the typical calibration requirements of the field
equipment being used are as follows:

• Pitot tubes (QA Handbook Section 3.1.2, pp. 1-13) - measured for appropriate spacing and
dimensions or calibrate in a wind tunnel. Rejection criteria given on the calibration sheet.
Post-test check - inspect for damage.
• Probe nozzles (QA Handbook Section 3.4.2, pg. 19) - make three measurements of the nozzle
ID (to the nearest 0.001 in.) using different diameters with a micrometer. Difference between
the high and low values should not exceed 0.004 in. Post-test check - inspect for damage.
• Thermocouples (QA Handbook Section 3.4.2, pp. 15-18) - verify against a mercury-in-glass
thermometer at two or more points including the anticipated measurement range. Acceptance
limits - impinger ±2°F; DGM ±5.4°F; stack ±1.5 percent of stack temperature.
• Dry gas meters (QA Handbook Section 3.4.2, pp. 1-12) - Dry gas meters are calibrated using
critical orifices. The procedure entails four runs using four separate critical orifices running at
an actual vacuum 1-2 in. greater than the theoretical critical vacuum. The minimum sample
volume required per orifice is 5 ft3. Meter boxes are calibrated annually and then verified by
use of the alternative USEPA RM 5 post-test calibration procedure. This procedure is
referenced as Approved Alternate Method ALT-009 (June 21, 1994) by USEPA’s Emission
Measurement Center. The average Y-value obtained by this method must be within 5% of the
initial Y-value.
Equipment Leak Checks

Pitot tube leak checks were conducted in accordance with USEPA RM 2. Leak checks were
conducted on the HFPO-DA sample trains prior to and following each test run in accordance with
the procedures outlined in USEPA RM 5, Sections 8.4.1 and 8.4.2.
Reagent Blanks and Field Blanks

A field blank for the Modified USEPA RM 0010 sample train was collected as part of the test
program. The blank train was assembled and set-up near one of the carbon bed outlet test
locations and as close to the outlet sample train as possible. The blank train remained in place for
the duration of the sampling run. The blank train was heated to the same temperature as used
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for the outlet sampling train, and the impinger portion of the train was iced down and chilled
water circulated through the coil condenser as described in SW-846 Method 0010. The blank train
was recovered in the same location, and by the same procedures as the actual sampling trains.

Additionally, a proof blank train rinse sample was collected one time during the sampling
campaign. The glassware components of the train received a thorough solvent rinse after
samples were recovered and put away for a sampling run. This secondary rinse was used to
prove that the sampling breakdown collection processes capture all HFPO-DA material, and
generally leave none of the target analytes uncaptured on the sample glassware. All sampling
train glassware parts, including brushes and other tools used, were thoroughly rinsed with MeOH
/ 5% NH4OH solution to evaluate the general rinsing efficiency of the sampling train recovery
process.

Reagent blanks of the diH2O used in the sample trains and MeOH/5% NH4OH solution used for
sample recovery were also submitted to the laboratory for analysis along with the field samples.
Note that the field blank train and proof blank was collected during sampling of the Vinyl Ethers
South carbon bed. Results of the field blank, proof blank and reagent blanks and are included
with the laboratory reports in Appendix D.
Test Data and Report Review

Test data input and emission calculations were double-checked for accuracy. The test results
were reviewed by senior personnel for reasonableness and accuracy. The final report was peer
reviewed by senior personnel and certified by the project manager.
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TABLES

Table 1
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed
Fayetteville, North Carolina
Run Identification Run 1 Run 2 Run 3 Average Run 1 Run 2 Run 3 Average
Source ID:Carbon Bed Inlet Carbon Bed Outlet
Run Date 11Mar21 11Mar21 11Mar21 11Mar21 11Mar21 11Mar21Start/Stop Time 0919-1107 1137-1322 1343-1527 0919-1107 1137-1322 1343-1527
Exhaust Gas Conditions
Temperature (deg. F)73 76 79 76 82 83 84 83
Moisture (volume %)1.1 1.2 1.1 1.1 1.2 1.1 1.1 1.1
Oxygen (dry volume %)20.9 20.9 20.9 20.9 20.9 20.9 20.9 20.9
Carbon Dioxide (dry volume %)0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
Volumetric Flow Rateacfm 13,690 14,098 13,827 13,872 10,936 10,921 10,908 10,922
dscfm 13,622 13,914 13,599 13,712 10,780 10,745 10,714 10,747
HFPO - Dimer Acid
mg/dscm 1.19E-01 1.13E-01 9.94E-02 1.10E-01 4.17E-03 2.98E-03 2.02E-03 3.06E-03
lb/hr 6.08E-03 5.88E-03 5.07E-03 5.67E-03 1.68E-04 1.20E-04 8.10E-05 1.23E-04
Carbon Bed Removal Efficiency
percent 97 98 98 98
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APPENDIX A
PROCESS OPERATING DATA

Date 3/11/2021
Time
Stack Testing
A/F column Feed Rate (pounds per hour)
903 Distillation (pounds per hour)
DAF ISO Venting
Charging water to Hyd - venting
Charging Sulfuric acid - venting
Hydrolysis - Wash Tank pressure Transfer to Hydrolysis X X X X X X
Hydrolysis - Phase Settle X X X
Vap heels pressure transfer X
Vap cycle X X X X X X X X X X X X X X X X X X
Rec Tk to 903 Fd Tk Press Xfer (added to process 4/2020 )X X X X
Venting after press tran from North/South Acid tank to Hyd X X
DAF tran to Hyd - venting during transferXX
Hydrolysis - transfer to Waste Acid Trailer X X
Wash Tk to Vaporizer pressure transfer (new 8-2019)
Scrubber Recirculation Flow (gpm)
Scrubber dp (inwc)-0.7 -0.5 -0.5
38 38 38
1500
RUN1: 0919-1107 RUN 2 1137-1322 RUN3: 1343-1527
900 1000 1100 1200 1300 1400
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APPENDIX B
SCHEMATICS OF THE TEST LOCATIONS

Crossectional Area Showing
Velocity Traverse Point Locations

~60”
34”

~42”

Air Flow

Figure 1
Carbon Bed Inlet Sampling Location
Polymer Process Aid
The Chemours Company
Fayetteville, North Carolina

Carbon Bed
Sample Traverse Point Locations for Circular Stacks
Facility:The Chemours Company
Source Identification:PPA Carbon Bed inlet
Stack Diameter:34 inches
Sampling Locations: 1.8 diameters downstream
1.2 diameters upstream
Minimum Number of Traverse points
as specified by EPA Method 1: 24
Number of traverse points sampled: 24
Traverse Point Percent of Stack Diameter Distance in Inches
Number From Inside Wall From Inside Wall*
1 2.1 1.0
2 6.7 2.3
3 11.8 4.0
4 17.7 6.0
5 25.0 8.5
6 35.6 12.1
7 64.4 21.9
8 75.0 25.5
9 82.3 28.0
10 88.2 30.0
11 93.3 31.7
12 97.9 34.0
*Traverse points located within 1.00" to the stack wall for stacks having an inside diameter greater than
24" will be relocated as well as traverse points located within 0.50 inches to the stack wall on stacks
with a 24" ID or less to meet criteria.
C:\Stack\Field Spreadsheets\Method 1\Traverse_new.xlsx

Crossectional Area Showing
Velocity Traverse Point Locations

~32’
30”

~12’

Air Flow

Figure 2
Carbon Bed Outlet Sampling Location
Polymer Process Aid
The Chemours Company
Fayetteville, North Carolina

ID Fan
Sample Traverse Point Locations for Circular Stacks
Facility:The Chemours Company
Source Identification:PPA Carbon Bed Outlet
Stack Diameter:30 inches
Sampling Locations: 4.8 diameters downstream
12 diameters upstream
Minimum Number of Traverse points
as specified by EPA Method 1: 24
Number of traverse points sampled: 24
Traverse Point Percent of Stack Diameter Distance in Inches
Number From Inside Wall From Inside Wall*
1 2.1 1.0
2 6.7 2.0
3 11.8 3.5
4 17.7 5.3
5 25.0 7.5
6 35.6 10.7
7 64.4 19.3
8 75.0 22.5
9 82.3 24.7
10 88.2 26.5
11 93.3 28.0
12 97.9 29.0
*Traverse points located within 1.00" to the stack wall for stacks having an inside diameter greater than
24" will be relocated as well as traverse points located within 0.50 inches to the stack wall on stacks
with a 24" ID or less to meet criteria.
C:\Stack\Field Spreadsheets\Method 1\Traverse_new.xlsx
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APPENDIX C
FIELD DATA AND CALCULATIONS

PPA Carbon Bed Inlet Field Test Data

Field Data SummaryThe Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed InletFayetteville, North Carolina
Run 1 Run 2 Run 3
Traverse Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT
Point Temp(F) P H in out Delta P Temp(F) P H in out Delta P Temp(F) P H in out Delta P
A1 71 0.50 1.65 66 65 0.7071 76 0.56 1.85 77 75 0.7483 77 0.55 1.82 81 79 0.74162720.59 1.95 67 65 0.7681 76 0.56 1.85 78 75 0.7483 79 0.55 1.82 83 79 0.74163720.59 1.95 69 68 0.7681 76 0.56 1.85 79 75 0.7483 79 0.55 1.82 84 79 0.74164730.58 1.91 71 66 0.7616 76 0.53 1.75 80 75 0.7280 79 0.55 1.82 85 79 0.74165720.56 1.85 73 67 0.7483 76 0.53 1.75 81 76 0.7280 79 0.53 1.75 86 79 0.72806720.51 1.68 74 67 0.7141 76 0.51 1.68 82 76 0.7141 79 0.50 1.65 86 80 0.70717720.47 1.55 75 67 0.6856 76 0.50 1.65 83 76 0.7071 79 0.38 1.25 86 80 0.61648720.35 1.16 76 68 0.5916 76 0.48 1.58 83 76 0.6928 79 0.35 1.16 85 80 0.59169720.34 1.12 77 69 0.5831 76 0.47 1.55 84 77 0.6856 78 0.31 1.02 87 80 0.556810710.29 0.96 77 69 0.5385 76 0.40 1.32 84 77 0.6325 78 0.23 0.76 86 80 0.4796
11 70 0.22 0.73 78 70 0.4690 76 0.24 0.79 84 77 0.4899 77 0.23 0.76 86 80 0.479612690.22 0.73 78 71 0.4690 74 0.24 0.79 83 77 0.4899 77 0.23 0.76 86 81 0.4796B1730.51 1.68 76 72 0.7141 77 0.58 1.91 81 77 0.7616 79 0.55 1.82 84 81 0.74162740.51 1.68 77 72 0.7141 77 0.58 1.91 82 77 0.7616 80 0.55 1.82 85 81 0.74163740.50 1.65 78 72 0.7071 77 0.58 1.91 83 78 0.7616 79 0.55 1.82 86 81 0.74164740.49 1.62 80 73 0.7000 77 0.55 1.82 83 78 0.7416 79 0.54 1.78 86 81 0.73485740.48 1.58 80 73 0.6928 77 0.54 1.78 84 78 0.7348 79 0.54 1.78 87 81 0.73486740.47 1.55 81 73 0.6856 77 0.52 1.72 85 78 0.7211 79 0.49 1.62 86 81 0.70007740.47 1.55 82 74 0.6856 77 0.37 1.22 85 78 0.6083 80 0.48 1.58 87 81 0.69288740.45 1.49 82 74 0.6708 77 0.37 1.22 85 78 0.6083 80 0.46 1.52 88 81 0.6782
9 74 0.44 1.45 82 74 0.6633 77 0.32 1.06 85 79 0.5657 80 0.46 1.52 88 81 0.678210730.23 0.76 82 75 0.4796 77 0.25 0.83 85 79 0.5000 80 0.26 0.86 88 81 0.509911720.23 0.76 81 75 0.4796 75 0.25 0.83 84 79 0.5000 78 0.24 0.79 87 81 0.489912720.23 0.76 81 75 0.4796 76 0.25 0.83 84 79 0.5000 78 0.24 0.79 86 81 0.48990.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000
0.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000Average730.43 1.41 77 71 0.6449 76 0.45 1.48 83 77 0.6616 79 0.43 1.42 86 80 0.6474
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Inlet_031121.xlsx\TestData.xls
Test Data Summary and Calculations
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed InletFayetteville, North Carolina
Parameter Run 1 Run 2 Run 3
Run Date 3/11/21 3/11/21 3/11/21Start/Stop Time 0919-1107 1137-1322 1343-1527
Duration of Run, Minutes 96 96 96
Ave. Nozzle Diameter, inches 0.243 0.243 0.243Pitot Calibration Factor, CF 0.84 0.84 0.84Meter Gamma 0.983 0.983 0.983
Meter Delta H, inches of H2O 1.71 1.71 1.71Stack Diameter, inches 34 34 34Rectangular Width, inches 0 0 0
Rectangular Length, inches 0 0 0
Stack Area, sq.ft.6.30 6.30 6.30Barometric Pressure, inches of Hg 30.48 30.48 30.48Static Pressure, inches of H2O -1.6 -1.6 -1.7
Dry Gas Meter Sample Volume, (VM)ft3Initial 595.047 660.775 727.995Final660.632 727.731 793.633
Total Volume 65.585 66.956 65.638
Ave. Stack Temperature, Ts(F)72.5 76.3 78.8Ave. Meter Temperature, Tm(F)73.7 79.9 83.1Ave. Run Delta H, inches of H2O 1.41 1.48 1.42
Ave. Square Root of Delta P 0.6449 0.6616 0.6474
Moisture Data
Volume of water collected, mls 3 4 2.8
Silica Gel, grams 12.6 13.2 12
Total Collected, mls 15.6 17.2 14.8
ORSAT Data
%O2 20.90 20.90 20.90%CO2 0.0 0.0 0.0
%CO
Calculations
Vw(std), scf =0.734 0.810 0.697Vm(std), dscf =65.197 65.808 64.125Bws=0.011 0.012 0.011
Md=28.84 28.84 28.84Ms=28.72 28.70 28.72Vs, ft/sec =36.2 37.3 36.6
Qs, acfm =13,690 14,098 13,827
Qs(std), dscfm =13,622 13,914 13,599Isokinetic Sampling Rate, %97.6 96.5 96.2
Where:
An = area of the nozzleAs = area of the stackVw(std) = volume of water vapor in gas, standard conditions = 0.04707*Vlc
Vm(std) = vol. of gas sampled, standard conditions = 17.647 x Vm x gamma x [Pb + (dH/13.6)]/Tm(R)Bws = water vapor in gas stream, proportion by volume = Vw(std)/(Vm(std) + Vw(std))Md = molecular weight of stack gas, dry basis = (0.44 x%CO2) + (0.32 x%O2) + [0.28 x (%N2 + %CO)]
Ms = molecular weight of stack gas, wet basis = [Md x (1-Bws)] + (18.0 x Bws)
Vs = stack gas velocity = 85.49 x Cp x (avg. Sq.Rt. dP) x [Sq.Rt. (Ts(R))/(Ms x Ps)]Qs = stack gas flow rate = Vs x As x 60Qs(std) = stack gas flow rate, standard conditions = Qs x (1-Bws) x (528/(Ts(R)) x (Ps/29.92)
Isokinetic sampling rate = {(Ts(R)) x [(0.00267 x Vlc) + (Vm(std)/17.647)] x 100}/(Time x vs x Ps x An x60)
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Inlet_031121.xlsx\Summary Data.xls
Results SummaryThe Chemours Company - Fayetteville WorksPolymer Process Aid Carbon Bed InletFayetteville, North Carolina
Parameter:Run 1 Run 2 Run 3 Average
Mol. Wt. mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr
HFPO - Dimer Acid 330 0.21993 1.19E-01 8.68E-03 6.08E-03 0.21008 1.13E-01 8.21E-03 5.88E-03 0.18058 9.94E-02 7.24E-03 5.07E-03 0.20 1.10E-01 8.04E-03 5.67E-03
Where:Pollutant Emission Concentration:mg= total sample collected, milligramsmg/dscm = milligrams of pollutant per dry standard cubic meter sampled = (mg/dscf ) x (35.314 cubic feet/cubic meter) ppm = parts per million =((mg/dscm x 24.04 liters/mol)/mol.wt))
Pollutant Emission Rate:lb/hr = pounds of pollutant emitted per hour = mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Inlet_031121.xlsx\Other Lab Results.xls
Example Calculations
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed Inlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vm,a =Dry gas volume at actual conditions (acf)
Initial gas meter volume:
Final gas meter volume:
Difference:
Vm,std =Volume of dry gas at standard conditions (dscf)
=17.647x Vm, a x Gamma*[Pbar+(DeltaH/13.6)]/Tm(R)=17.647 x 0.000 x 0.983 x (30.48 + [ (1.710 /13.6)]/534
=65.197
Vl,c =Volume of water collected in impingers and silica gel (ml)
impinger catch (mls):3
silica gel (g)12.6
total:15.6
Vw,std =Volume of water vapor in gas at standard conditions (cu.ft.)
=(0.04707) x (Vl,c)
=0.04707 x 15.6
=0.734
Bwo =Proportion by volume of water vapor in gas stream
=Vw,std/(Vw,std+Vm,std)
=0.73 / (0.73 +65.197 )
=0.011
Ps =Stack gas static pressure (in. Hg)
=St/13.6
=-1.60 / 13.6=-0.118
Pa =Absolute stack gas pressure (in. Hg) =Ps+Pbar
=-0.118 +30.48
=30.36
MFD =Dry mole fraction of stack gas
=1-Bwo
=1 -
=0.989
Md =Dry molecular weight of stack gas (lb/lb-mol)
=(0.32 x %O2) + (0.44 x %CO2) + (0.28 x %N2)
=(0.32 x 20.90 )+(0.44 x 0.00 ) +(0.28 x 79.10 )
=28.84
Mw =Wet molecular weight of stack gas (lb/lb-mol)
=(Md) x (MFD) + (0.18) x (Bwo*100)
=28.84 x 0.989 + 0.18 x 1.11372
=28.72
0.011
595.047660.632
65.585
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Inlet_031121.xlsx\Example Page 5 of 6
Example Calculations
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed Inlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vs,avg =Average stack gas velocity (fps)
=Kp x (Cp) x (sqrt,deltaP) x sqrt((Ts + 460°R)/Mw*Pa))
=85.48 x 0.84 x 0.64 x sqrt (0.61 )
=36.2
A Cross sectional areas of stack (sq. ft)
=pi/4*d^2=2.83 ^2
=6.30
Qa Volumetric flow rate at actual conditions (acfm)
=(60)sec/min(A)(Vs, avg)
=60 x 6.3050 x 36.19
=13,689
Qstd Volumetric flow rate at standard conditions (scfm)
=Qa x (528/Ts,avg + 460) x Pa/29.92
=13,689 x (528 /533 ) x 1.015
=13,774
Qstd,dry Volumetric flow rate at dry standard conditions per minute(dscfm)
=Qstd x (1-Bwo)
=13,774 x 0.9889
=13,621
mg/dscm HFPO-DA concentration
=(mg/dscf) x 35.314 cu. ft./cu. meter
= (0.220 /65.20 ) x35.314
=1.19E-01
lb/hr HFPO-DA Mass Emission Rate
=mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
=0.220 /1,000 /[(453.59 ) / (65.20 )] x 13,622 x 60
=6.08E-03
3.14159/4 x
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Inlet_031121.xlsx\Example Page 6 of 6
DOCUMENT TITLE
Sample Train Recovery Data Sheet
Client The Chemours Co.Location Fayetteville, NC Source PPA Inlet Method Modified 0010 Date 3/11/2021
Run #1
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 919
Impinger #8
Run End Time 1107
Total Gain ml/gm
Recovery Technician PG
Run #2
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1137
Impinger #8
Run End Time 1322
Total Gain ml/gm
Recovery Technician PG
Run #3
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1343
Impinger #8
Run End Time 1527
Total Gain ml/gm
Recovery Technician PG
790.4 1.4
0.0
Final ml or gm Initial ml or gm Net Gain
493.2 492.6 0.6
686.8 687.2 -0.4
787.4 787.8 -0.4
517.6 515.8 1.8
866.6 854.0 12.6
791.8
0.0
15.6
Final ml or gm Initial ml or gm Net Gain
447.6 447.0 0.6
781.0 782.4 -1.4
766.6 766.4 0.2
772.2 770.4 1.8
502.2 499.4 2.8
879.0 865.8 13.2
0.0
0.0
17.2
Final ml or gm Initial ml or gm Net Gain
493.4 493.0 0.4
698.4 698.6 -0.2
793.6 793.2 0.4
802.2 801.4 0.8
517.2 515.8 1.4
843.6 831.6 12.0
14.8
0.0
0.0
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App C\PPA_Inlet_Moisture.xls\PPA_Inlet_Moisture.xls

PPA Carbon Bed Outlet Field Test Data

Field Data SummaryThe Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed OutletFayetteville, North Carolina
Run 1 Run 2 Run 3
Traverse Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT Stack Delta Delta Tm(F)SQRT
Point Temp(F) P H in out Delta P Temp(F) P H in out Delta P Temp(F) P H in out Delta P
A1 78 0.18 0.54 63 61 0.4243 83 0.34 1.02 79 78 0.5831 84 0.20 0.60 82 81 0.44722780.20 0.60 63 62 0.4472 83 0.34 1.02 81 77 0.5831 84 0.20 0.60 83 81 0.44723800.36 1.08 65 62 0.6000 83 0.38 1.14 83 77 0.6164 84 0.35 1.05 85 81 0.59164810.41 1.23 68 62 0.6403 83 0.45 1.35 84 78 0.6708 84 0.38 1.14 87 81 0.61645810.41 1.23 70 63 0.6403 83 0.45 1.35 85 78 0.6708 84 0.42 1.26 88 81 0.64816810.45 1.35 72 64 0.6708 83 0.47 1.41 86 78 0.6856 84 0.42 1.26 89 81 0.64817810.50 1.50 75 65 0.7071 83 0.50 1.50 87 79 0.7071 84 0.50 1.50 89 82 0.70718810.52 1.56 77 66 0.7211 83 0.47 1.41 87 79 0.6856 84 0.50 1.50 90 82 0.70719820.50 1.50 79 68 0.7071 83 0.49 1.47 88 79 0.7000 84 0.50 1.50 91 82 0.707110810.50 1.50 80 68 0.7071 83 0.49 1.47 87 80 0.7000 84 0.50 1.50 91 83 0.7071
11 81 0.50 1.50 82 69 0.7071 84 0.49 1.47 87 80 0.7000 84 0.50 1.50 91 83 0.707112820.50 1.50 83 70 0.7071 84 0.47 1.41 87 80 0.6856 84 0.50 1.50 91 83 0.7071B1830.32 0.96 78 73 0.5657 80 0.17 0.54 83 80 0.4123 85 0.34 0.54 85 83 0.58312820.34 1.02 82 73 0.5831 83 0.30 0.90 84 80 0.5477 85 0.40 1.20 88 84 0.63253820.39 1.17 84 74 0.6245 84 0.40 1.20 84 80 0.6325 84 0.42 1.26 89 84 0.64814830.45 1.35 85 74 0.6708 84 0.40 1.20 85 80 0.6325 84 0.42 1.26 91 84 0.64815830.48 1.44 87 75 0.6928 83 0.44 1.32 86 80 0.6633 84 0.46 1.38 90 84 0.67826830.50 1.50 85 76 0.7071 84 0.48 1.44 86 80 0.6928 85 0.46 1.38 91 84 0.67827840.52 1.56 85 76 0.7211 84 0.50 1.50 86 80 0.7071 84 0.49 1.47 92 84 0.70008840.52 1.56 85 76 0.7211 83 0.49 1.47 88 80 0.7000 84 0.49 1.47 92 84 0.7000
9 84 0.52 1.56 85 76 0.7211 83 0.49 1.47 87 80 0.7000 83 0.50 1.50 91 84 0.707110840.50 1.50 85 76 0.7071 84 0.49 1.47 87 81 0.7000 83 0.50 1.50 91 84 0.707111840.50 1.50 85 77 0.7071 83 0.49 1.47 88 81 0.7000 84 0.50 1.50 91 84 0.707112830.50 1.50 85 77 0.7071 83 0.48 1.44 88 81 0.6928 83 0.50 1.50 91 84 0.70710.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000
0.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.00000.0000 0.0000 0.0000Average820.44 1.32 79 70 0.6587 83 0.44 1.31 86 79 0.6570 84 0.44 1.29 89 83 0.6557
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Outlet_031121.xlsx\TestData.xls
Test Data Summary and Calculations
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed OutletFayetteville, North Carolina
Parameter Run 1 Run 2 Run 3
Run Date 3/11/21 3/11/21 3/11/21Start/Stop Time 0919-1107 1137-1322 1343-1527
Duration of Run, Minutes 96 96 96
Ave. Nozzle Diameter, inches 0.243 0.243 0.243Pitot Calibration Factor, CF 0.84 0.84 0.84Meter Gamma 0.968 0.968 0.968
Meter Delta H, inches of H2O 1.56 1.56 1.56Stack Diameter, inches 30 30 30Rectangular Width, inches 0 0 0
Rectangular Length, inches 0 0 0
Stack Area, sq.ft.4.91 4.91 4.91Barometric Pressure, inches of Hg 30.48 30.48 30.48Static Pressure, inches of H2O 2 2 2
Dry Gas Meter Sample Volume, (VM)ft3Initial 577.244 645.462 713.984Final645.176 713.603 782.432
Total Volume 67.932 68.141 68.448
Ave. Stack Temperature, Ts(F)81.9 83.2 84.0Ave. Meter Temperature, Tm(F)74.4 82.5 86.0Ave. Run Delta H, inches of H2O 1.32 1.31 1.29
Ave. Square Root of Delta P 0.6587 0.6570 0.6557
Moisture Data
Volume of water collected, mls 3.6 2.4 4.6
Silica Gel, grams 13 13.4 11.4
Total Collected, mls 16.6 15.8 16.0
ORSAT Data
%O2 20.90 20.90 20.90%CO2 0.0 0.0 0.0
%CO
Calculations
Vw(std), scf =0.781 0.744 0.753Vm(std), dscf =66.398 65.608 65.477Bws=0.012 0.011 0.011
Md=28.84 28.84 28.84Ms=28.71 28.71 28.71Vs, ft/sec =37.1 37.1 37.0
Qs, acfm =10,936 10,921 10,908
Qs(std), dscfm =10,780 10,745 10,714Isokinetic Sampling Rate, %97.8 96.9 97.0
Where:
An = area of the nozzleAs = area of the stackVw(std) = volume of water vapor in gas, standard conditions = 0.04707*Vlc
Vm(std) = vol. of gas sampled, standard conditions = 17.647 x Vm x gamma x [Pb + (dH/13.6)]/Tm(R)Bws = water vapor in gas stream, proportion by volume = Vw(std)/(Vm(std) + Vw(std))Md = molecular weight of stack gas, dry basis = (0.44 x%CO2) + (0.32 x%O2) + [0.28 x (%N2 + %CO)]
Ms = molecular weight of stack gas, wet basis = [Md x (1-Bws)] + (18.0 x Bws)
Vs = stack gas velocity = 85.49 x Cp x (avg. Sq.Rt. dP) x [Sq.Rt. (Ts(R))/(Ms x Ps)]Qs = stack gas flow rate = Vs x As x 60Qs(std) = stack gas flow rate, standard conditions = Qs x (1-Bws) x (528/(Ts(R)) x (Ps/29.92)
Isokinetic sampling rate = {(Ts(R)) x [(0.00267 x Vlc) + (Vm(std)/17.647)] x 100}/(Time x vs x Ps x An x60)
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Outlet_031121.xlsx\Summary Data.xls
Results SummaryThe Chemours Company - Fayetteville WorksPolymer Process Aid Carbon Bed OutletFayetteville, North Carolina
Parameter:Run 1 Run 2 Run 3 Average
Mol. Wt. mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr mg mg/dscm ppm lb/hr
HFPO - Dimer Acid 330 0.00783 4.17E-03 3.04E-04 1.68E-04 0.00554 2.98E-03 2.17E-04 1.20E-04 0.00374 2.02E-03 1.47E-04 8.10E-05 0.01 3.06E-03 2.23E-04 1.23E-04
Where:Pollutant Emission Concentration:mg= total sample collected, milligramsmg/dscm = milligrams of pollutant per dry standard cubic meter sampled = (mg/dscf ) x (35.314 cubic feet/cubic meter) ppm = parts per million =((mg/dscm x 24.04 liters/mol)/mol.wt))
Pollutant Emission Rate:lb/hr = pounds of pollutant emitted per hour = mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Outlet_031121.xlsx\Other Lab Results.xls
Example Calculations
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed Outlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vm,a =Dry gas volume at actual conditions (acf)
Initial gas meter volume:
Final gas meter volume:
Difference:
Vm,std =Volume of dry gas at standard conditions (dscf)
=17.647x Vm, a x Gamma*[Pbar+(DeltaH/13.6)]/Tm(R)=17.647 x 0.000 x 0.968 x (30.48 + [ (1.560 /13.6)]/534
=66.398
Vl,c =Volume of water collected in impingers and silica gel (ml)
impinger catch (mls):4
silica gel (g)13.0
total:16.6
Vw,std =Volume of water vapor in gas at standard conditions (cu.ft.)
=(0.04707) x (Vl,c)
=0.04707 x 16.6
=0.781
Bwo =Proportion by volume of water vapor in gas stream
=Vw,std/(Vw,std+Vm,std)
=0.78 / (0.78 +66.398 )
=0.012
Ps =Stack gas static pressure (in. Hg)
=St/13.6
=2.00 / 13.6=0.147
Pa =Absolute stack gas pressure (in. Hg) =Ps+Pbar
=0.147 +30.48
=30.63
MFD =Dry mole fraction of stack gas
=1-Bwo
=1 -
=0.988
Md =Dry molecular weight of stack gas (lb/lb-mol)
=(0.32 x %O2) + (0.44 x %CO2) + (0.28 x %N2)
=(0.32 x 20.90 )+(0.44 x 0.00 ) +(0.28 x 79.10 )
=28.84
Mw =Wet molecular weight of stack gas (lb/lb-mol)
=(Md) x (MFD) + (0.18) x (Bwo*100)
=28.84 x 0.988 + 0.18 x 1.1631
=28.71
0.012
577.244645.176
67.932
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Outlet_031121.xlsx\Example Page 5 of 6
Example Calculations
The Chemours Company - Fayetteville Works
Polymer Process Aid Carbon Bed Outlet
Fayetteville, North Carolina
Note: Values are shown for example purposes only.
Vs,avg =Average stack gas velocity (fps)
=Kp x (Cp) x (sqrt,deltaP) x sqrt((Ts + 460°R)/Mw*Pa))
=85.48 x 0.84 x 0.66 x sqrt (0.62 )
=37.1
A Cross sectional areas of stack (sq. ft)
=pi/4*d^2=2.50 ^2
=4.91
Qa Volumetric flow rate at actual conditions (acfm)
=(60)sec/min(A)(Vs, avg)
=60 x 4.9087 x 37.13
=10,935
Qstd Volumetric flow rate at standard conditions (scfm)
=Qa x (528/Ts,avg + 460) x Pa/29.92
=10,935 x (528 /542 ) x 1.024
=10,906
Qstd,dry Volumetric flow rate at dry standard conditions per minute(dscfm)
=Qstd x (1-Bwo)
=10,906 x 0.9884
=10,779
mg/dscm HFPO-DA concentration
=(mg/dscf) x 35.314 cu. ft./cu. meter
= (0.008 /66.40 ) x35.314
=4.17E-03
lb/hr HFPO-DA Mass Emission Rate
=mg/1000/[(453.59 g/lb)/(dscf)] x dscfm x 60 min/hr
=0.008 /1,000 /[(453.59 ) / (66.40 )] x 10,780 x 60
=1.68E-04
3.14159/4 x
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\PPA_Outlet_031121.xlsx\Example Page 6 of 6
DOCUMENT TITLE
Sample Train Recovery Data Sheet
Client The Chemours Co.Location Fayetteville, NC Source PPA Outlet Method Modified 0010 Date 3/11/2021
Run #1
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 919
Impinger #8
Run End Time 1107
Total Gain ml/gm
Recovery Technician PG
Run #2
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1137
Impinger #8
Run End Time 1322
Total Gain ml/gm
Recovery Technician PG
Run #3
Filter #1
Impinger #1
Impinger #2 Filter #2
Impinger #3
Impinger #4 Filter #3
Impinger #5
Impinger #6
Impinger #7 Run Start Time 1343
Impinger #8
Run End Time 1527
Total Gain ml/gm
Recovery Technician PG
757.2 1.2
0.0
Final ml or gm Initial ml or gm Net Gain
492.2 491.4 0.8
803.2 803.0 0.2
793.4 793.6 -0.2
510.4 508.8 1.6
876.8 863.8 13.0
758.4
0.0
16.6
Final ml or gm Initial ml or gm Net Gain
467.8 468.0 -0.2
802.8 803.6 -0.8
813.0 811.8 1.2
772.6 771.6 1.0
531.2 530.0 1.2
892.8 879.4 13.4
0.0
0.0
15.8
Final ml or gm Initial ml or gm Net Gain
493.0 492.0 1.0
807.0 806.8 0.2
798.6 797.8 0.8
757.0 756.0 1.0
510.8 509.2 1.6
824.0 812.6 11.4
16.0
0.0
0.0
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App C\PPA_Outlet_Moisture.xls\PPA_Outlet_Moisture.xls
Ramboll - Source Emissions Testing of the Polymer Process Aid Carbon Bed

APPENDIX D
LABORATORY DATA

PPA Carbon Bed Inlet Laboratory Data

ANALYTICAL REPORT
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike
Knoxville, TN 37921
Tel: [phone]
Laboratory Job ID: 140-22281-1
Client Project/Site: PPA Carbon Bed Inlet
For:
The Chemours Company FC, LLC
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, Delaware 19713
Attn: Michael Aucoin
Authorized for release by:
3/31/2021 10:17:37 AM
Courtney Adkins, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Laboratory Job ID: 140-22281-1
Page 2 of 27 Eurofins TestAmerica, Knoxville3/31/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
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Definitions/Glossary
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Qualifiers
LCMS
Qualifier Description
*+LCS and/or LCSD is outside acceptance limits, high biased.
Qualifier
*1 LCS/LCSD RPD exceeds control limits.
*5-Isotope dilution analyte is outside acceptance limits, low biased.
B Compound was found in the blank and sample.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Knoxville
Page 3 of 27 3/31/2021
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Case Narrative
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Job ID: 140-22281-1
Laboratory: Eurofins TestAmerica, Knoxville
Narrative
Job Narrative
140-22281-1
Sample Receipt
The samples were received on March 13, 2021 at 10:40 AM. The temperature of the cooler at receipt was 0.8º C.
LCMS
LC/MS/MS Sampling Train Preparation and Analysis: The sampling train components are extracted and analyzed for Per- and
Polyfluorinated Alkyl Substances (PFAS) using Eurofins TestAmerica Knoxville standard operating procedures KNOX-OP-0026 and
KNOX-LC-0007.
The sampling trains are prepared as four analytical fractions: The particulate filter and front half of the filter holder, nozzle and probe
solvent rinses are combined for one analytical fraction. The XAD-2 resin trap and back half of the filter holder, coil condenser and
connecting glassware solvent rinses are also combined as a separate analytical fraction. The condensate, impinger contents and their
related glassware DI water rinses make up the third analytical fraction. The breakthrough XAD module makes up the fourth analytical
fraction.
The filters and XAD components are spiked with isotope dilution internal standards and the components are extracted with
methanol/ammonium hydroxide by shaking for at least 18 hours. The extracts are concentrated to 10 mL and analyzed by HPLC/MS/MS.
The condensates are spiked with the isotope dilution internal standards and extracted using either Solid-Phase Extraction (SPE) or
diluting the water sample for analysis. Each extract at its final volume is 80:20 methanol:water
Sample results were calculated using the following equation:

Result, ηg/sample = (on-column concentration, ηg/mL) × (nominal final volume of extract (10 mL) / 1 sample) × DF × SF
Where:
DF = Instrument dilution factor
SF = Extraction Split Factor = (final volume of extract in the initial extraction batch / initial volume of extract in the “Split” batch)
For condensate, if less than the entire sample is extracted, the fraction of sample used replaces “1 sample”
Method 537 (modified): The method blank for preparation batch 140-48003 and 140-48146 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The Isotope Dilution Analyte (IDA) recovery associated with the following samples is below the method
recommended limit: Z-2648 PPA CB INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBE (140-22281-8), (LCS 140-47734/2-B),
(LCS 140-47984/2-B), (LCSD 140-47734/3-B) and (MB 140-47734/1-B). Generally, data quality is not considered affected if the IDA
signal-to-noise ratio is greater than 10:1.
Method 537 (modified): The method blank for preparation batch 140-47984 and 140-48079 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch
140-47734 and 140-47812 and analytical batch 140-48219 recovered outside control limits for the following analyte: HFPO-DA. This
analyte was biased high in the LCS/LCSD. The samples were consumed during the extraction process and therefore, the data have been
reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins TestAmerica, KnoxvillePage 4 of 27 3/31/2021
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Client Sample Results
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Lab Sample ID: 140-22281-1Client Sample ID: Z-2635,2636 PPA CB INLET R1 OTM-45 FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 193 B 1.99 1.15 ug/Sample 03/22/21 14:10 03/28/21 01:54 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 106 25-150 03/22/21 14:10 03/28/21 01:54 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-2Client Sample ID: Z-2637,2638,2640 PPA CB INLET R1 OTM-45
BH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 26.6 *+ *1 0.800 0.700 ug/Sample 03/15/21 06:58 03/28/21 00:26 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 103 25-150 03/15/21 06:58 03/28/21 00:26 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-3Client Sample ID: Z-2639 PPA CB INLET R1 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.324 B 0.0988 0.0163 ug/Sample 03/23/21 05:53 03/27/21 12:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 113 25-150 03/23/21 05:53 03/27/21 12:11 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-4Client Sample ID: Z-2641 PPA CB INLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0104 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/28/21 00:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 90 25-150 03/15/21 06:58 03/28/21 00:35 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-5Client Sample ID: Z-2642,2643 PPA CB INLET R2 OTM-45 FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 193 B 2.00 1.16 ug/Sample 03/22/21 14:10 03/28/21 02:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Knoxville
Page 5 of 27 3/31/2021
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Client Sample Results
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Lab Sample ID: 140-22281-5Client Sample ID: Z-2642,2643 PPA CB INLET R2 OTM-45 FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
13C3 HFPO-DA 106 25-150 03/22/21 14:10 03/28/21 02:21 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-6Client Sample ID: Z-2644,2645,2647 PPA CB INLET R2 OTM-45
BH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 16.7 *+ *1 0.800 0.700 ug/Sample 03/15/21 06:58 03/28/21 00:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 109 25-150 03/15/21 06:58 03/28/21 00:44 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-7Client Sample ID: Z-2646 PPA CB INLET R2 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.356 B 0.0975 0.0161 ug/Sample 03/23/21 05:53 03/27/21 12:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 108 25-150 03/23/21 05:53 03/27/21 12:20 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-8Client Sample ID: Z-2648 PPA CB INLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0190 *+ *1 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/28/21 00:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 22 *5-25-150 03/15/21 06:58 03/28/21 00:53 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-9Client Sample ID: Z-2649,2650 PPA CB INLET R3 OTM-45 FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 171 B 1.98 1.15 ug/Sample 03/22/21 14:10 03/28/21 02:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 106 25-150 03/22/21 14:10 03/28/21 02:29 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 6 of 27 3/31/2021
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Client Sample Results
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Lab Sample ID: 140-22281-10Client Sample ID: Z-2651,2652,2654 PPA CB INLET R3 OTM-45
BH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 8.84 *+ *1 0.800 0.700 ug/Sample 03/15/21 06:58 03/28/21 01:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 101 25-150 03/15/21 06:58 03/28/21 01:01 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-11Client Sample ID: Z-2653 PPA CB INLET R3 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.314 B 0.105 0.0173 ug/Sample 03/23/21 05:53 03/27/21 12:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 111 25-150 03/23/21 05:53 03/27/21 12:29 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22281-12Client Sample ID: Z-2655 PPA CB INLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.421 *+ *1 0.00800 0.00700 ug/Sample 03/15/21 06:58 03/28/21 12:47 5
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 98 25-150 03/15/21 06:58 03/28/21 12:47 5
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Default Detection Limits
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep: None
0.00100HFPO-DA ug/Sample
Analyte UnitsMDLRL
0.000580
0.00160HFPO-DA ug/Sample0.00140
0.00200HFPO-DA ug/Sample0.000330
Eurofins TestAmerica, Knoxville
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Isotope Dilution Summary
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (25-150)
HFPODA
106140-22281-1
Percent Isotope Dilution Recovery (Acceptance Limits)
Z-2635,2636 PPA CB INLET R1 OTM-45 FH
103140-22281-2 Z-2637,2638,2640 PPA CB
INLET R1 OTM-45 BH
113140-22281-3 Z-2639 PPA CB INLET R1
OTM-45 IMPINGERS 1,2&3
COND
90140-22281-4 Z-2641 PPA CB INLET R1
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
106140-22281-5 Z-2642,2643 PPA CB INLET R2
OTM-45 FH
109140-22281-6 Z-2644,2645,2647 PPA CB
INLET R2 OTM-45 BH
108140-22281-7 Z-2646 PPA CB INLET R2
OTM-45 IMPINGERS 1,2&3
COND
22 *5-140-22281-8 Z-2648 PPA CB INLET R2
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
106140-22281-9 Z-2649,2650 PPA CB INLET R3
OTM-45 FH
101140-22281-10 Z-2651,2652,2654 PPA CB
INLET R3 OTM-45 BH
111140-22281-11 Z-2653 PPA CB INLET R3
OTM-45 IMPINGERS 1,2&3
COND
98140-22281-12 Z-2655 PPA CB INLET R3
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
43LCS 140-47734/2-B Lab Control Sample
32LCS 140-47984/2-B Lab Control Sample
112LCS 140-48003/2-B Lab Control Sample
33LCSD 140-47734/3-B Lab Control Sample Dup
96LCSD 140-47984/3-B Lab Control Sample Dup
107LCSD 140-48003/3-B Lab Control Sample Dup
64MB 140-47734/14-B Method Blank
45MB 140-47734/1-B Method Blank
92MB 140-47984/1-B Method Blank
112MB 140-48003/1-B Method Blank
Surrogate Legend
HFPODA = 13C3 HFPO-DA
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 140-47734/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 23:42 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 64 25-150 03/27/21 23:42 1
MB MB
Isotope Dilution
03/15/21 06:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47734/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/15/21 06:58 03/27/21 21:20 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 45 25-150 03/27/21 21:20 1
MB MB
Isotope Dilution
03/15/21 06:58
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47734/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
HFPO-DA 0.0200 0.02128 ug/Sample 106 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
43
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47734/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47734
HFPO-DA 0.0200 0.03810 *+ *1 ug/Sample 190 60-140 57 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
33
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47984/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
RL MDL
HFPO-DA 0.002562 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 01:28 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 92 25-150 03/28/21 01:28 1
MB MB
Isotope Dilution
03/22/21 14:10
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47984/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02413 ug/Sample 121 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
32
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47984/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02295 ug/Sample 115 60-140 5 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
96
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-48003/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
RL MDL
HFPO-DA 0.001514 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 11:45 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 112 25-150 03/27/21 11:45 1
MB MB
Isotope Dilution
03/23/21 05:53
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-48003/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01114 ug/Sample 111 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
112
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-48003/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01177 ug/Sample 118 60-140 6 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
107
LCSD LCSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
LCMS
Prep Batch: 47734
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22281-2 Z-2637,2638,2640 PPA CB INLET R1 OTM-45 BH Total/NA
Air None140-22281-4 Z-2641 PPA CB INLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22281-6 Z-2644,2645,2647 PPA CB INLET R2 OTM-45 BH Total/NA
Air None140-22281-8 Z-2648 PPA CB INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22281-10 Z-2651,2652,2654 PPA CB INLET R3 OTM-45 BH Total/NA
Air None140-22281-12 Z-2655 PPA CB INLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air NoneMB 140-47734/14-B Method Blank Total/NA
Air NoneMB 140-47734/1-B Method Blank Total/NA
Air NoneLCS 140-47734/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 47812
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47734140-22281-2 Z-2637,2638,2640 PPA CB INLET R1 OTM-45 BH Total/NA
Air Split 47734140-22281-4 Z-2641 PPA CB INLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734140-22281-6 Z-2644,2645,2647 PPA CB INLET R2 OTM-45 BH Total/NA
Air Split 47734140-22281-8 Z-2648 PPA CB INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734140-22281-10 Z-2651,2652,2654 PPA CB INLET R3 OTM-45 BH Total/NA
Air Split 47734140-22281-12 Z-2655 PPA CB INLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47734MB 140-47734/14-B Method Blank Total/NA
Air Split 47734MB 140-47734/1-B Method Blank Total/NA
Air Split 47734LCS 140-47734/2-B Lab Control Sample Total/NA
Air Split 47734LCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Prep Batch: 47984
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22281-1 Z-2635,2636 PPA CB INLET R1 OTM-45 FH Total/NA
Air None140-22281-5 Z-2642,2643 PPA CB INLET R2 OTM-45 FH Total/NA
Air None140-22281-9 Z-2649,2650 PPA CB INLET R3 OTM-45 FH Total/NA
Air NoneMB 140-47984/1-B Method Blank Total/NA
Air NoneLCS 140-47984/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Prep Batch: 48003
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22281-3 Z-2639 PPA CB INLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22281-7 Z-2646 PPA CB INLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22281-11 Z-2653 PPA CB INLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air NoneMB 140-48003/1-B Method Blank Total/NA
Air NoneLCS 140-48003/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48079
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47984140-22281-1 Z-2635,2636 PPA CB INLET R1 OTM-45 FH Total/NA
Air Split 47984140-22281-5 Z-2642,2643 PPA CB INLET R2 OTM-45 FH Total/NA
Air Split 47984140-22281-9 Z-2649,2650 PPA CB INLET R3 OTM-45 FH Total/NA
Air Split 47984MB 140-47984/1-B Method Blank Total/NA
Air Split 47984LCS 140-47984/2-B Lab Control Sample Total/NA
Air Split 47984LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
LCMS
Cleanup Batch: 48146
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 48003140-22281-3 Z-2639 PPA CB INLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 48003140-22281-7 Z-2646 PPA CB INLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 48003140-22281-11 Z-2653 PPA CB INLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 48003MB 140-48003/1-B Method Blank Total/NA
Air Split 48003LCS 140-48003/2-B Lab Control Sample Total/NA
Air Split 48003LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146140-22281-3 Z-2639 PPA CB INLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)48146140-22281-7 Z-2646 PPA CB INLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)48146140-22281-11 Z-2653 PPA CB INLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)48146MB 140-48003/1-B Method Blank Total/NA
Air 537 (modified)48146LCS 140-48003/2-B Lab Control Sample Total/NA
Air 537 (modified)48146LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48218
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Dilution 48079140-22281-1 Z-2635,2636 PPA CB INLET R1 OTM-45 FH Total/NA
Air Dilution 47812140-22281-2 Z-2637,2638,2640 PPA CB INLET R1 OTM-45 BH Total/NA
Air Dilution 48079140-22281-5 Z-2642,2643 PPA CB INLET R2 OTM-45 FH Total/NA
Air Dilution 47812140-22281-6 Z-2644,2645,2647 PPA CB INLET R2 OTM-45 BH Total/NA
Air Dilution 48079140-22281-9 Z-2649,2650 PPA CB INLET R3 OTM-45 FH Total/NA
Air Dilution 47812140-22281-10 Z-2651,2652,2654 PPA CB INLET R3 OTM-45 BH Total/NA
Analysis Batch: 48219
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48218140-22281-1 Z-2635,2636 PPA CB INLET R1 OTM-45 FH Total/NA
Air 537 (modified)48218140-22281-2 Z-2637,2638,2640 PPA CB INLET R1 OTM-45 BH Total/NA
Air 537 (modified)47812140-22281-4 Z-2641 PPA CB INLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48218140-22281-5 Z-2642,2643 PPA CB INLET R2 OTM-45 FH Total/NA
Air 537 (modified)48218140-22281-6 Z-2644,2645,2647 PPA CB INLET R2 OTM-45 BH Total/NA
Air 537 (modified)47812140-22281-8 Z-2648 PPA CB INLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48218140-22281-9 Z-2649,2650 PPA CB INLET R3 OTM-45 FH Total/NA
Air 537 (modified)48218140-22281-10 Z-2651,2652,2654 PPA CB INLET R3 OTM-45 BH Total/NA
Air 537 (modified)47812MB 140-47734/14-B Method Blank Total/NA
Air 537 (modified)47812MB 140-47734/1-B Method Blank Total/NA
Air 537 (modified)48079MB 140-47984/1-B Method Blank Total/NA
Air 537 (modified)47812LCS 140-47734/2-B Lab Control Sample Total/NA
Air 537 (modified)48079LCS 140-47984/2-B Lab Control Sample Total/NA
Air 537 (modified)47812LCSD 140-47734/3-B Lab Control Sample Dup Total/NA
Air 537 (modified)48079LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48223
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)47812140-22281-12 Z-2655 PPA CB INLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Client Sample ID: Z-2635,2636 PPA CB INLET R1 OTM-45 FH Lab Sample ID: 140-22281-1
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 133 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 67 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 01:54 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2637,2638,2640 PPA CB INLET R1 OTM-45
BH
Lab Sample ID: 140-22281-2
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 20 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 00:26 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2639 PPA CB INLET R1 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22281-3
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00506
Sample
10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 12:11 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2641 PPA CB INLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22281-4
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/28/21 00:35 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 14 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Client Sample ID: Z-2642,2643 PPA CB INLET R2 OTM-45 FH Lab Sample ID: 140-22281-5
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 90 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 45 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 02:21 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2644,2645,2647 PPA CB INLET R2 OTM-45
BH
Lab Sample ID: 140-22281-6
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 20 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 00:44 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2646 PPA CB INLET R2 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22281-7
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00513
Sample
10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 12:20 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2648 PPA CB INLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22281-8
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/28/21 00:53 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 15 of 27 3/31/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Client Sample ID: Z-2649,2650 PPA CB INLET R3 OTM-45 FH Lab Sample ID: 140-22281-9
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 103 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 52 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 5 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 02:29 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2651,2652,2654 PPA CB INLET R3 OTM-45
BH
Lab Sample ID: 140-22281-10
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 20 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 01:01 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2653 PPA CB INLET R3 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22281-11
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00476
Sample
10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 12:29 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Z-2655 PPA CB INLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22281-12
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)5 48223 03/28/21 12:47 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Client Sample ID: Method Blank Lab Sample ID: MB 140-47734/14-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 23:42 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47734/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:20 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-47984/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/28/21 01:28 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Method Blank Lab Sample ID: MB 140-48003/1-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 11:45 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47734/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:29 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-47984/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/28/21 01:37 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-48003/2-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 11:54 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47734/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/15/21 06:58 TAL KNX47734
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 47812 03/17/21 08:03 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48219 03/27/21 21:37 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-47984/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48219 03/28/21 01:45 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 140-48003/3-B
Matrix: AirDate Collected: N/A
Date Received: N/A
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 12:02 JRC TAL KNXTotal/NA
LCAInstrument ID:
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 18 of 27 3/31/2021
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Accreditation/Certification Summary
Client: The Chemours Company FC, LLC Job ID: 140-22281-1
Project/Site: PPA Carbon Bed Inlet
Laboratory: Eurofins TestAmerica, Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
N/AAFCEE
ANAB Dept. of Defense ELAP L2311 02-13-22
ANAB Dept. of Energy L2311.01 02-13-22
ANAB ISO/IEC 17025 L2311 02-13-22
ANAB ISO/IEC 17025 L2311 02-14-22
Arkansas DEQ State 88-0688 06-17-21
California State 2423 06-30-22
Colorado State TN00009 02-28-21 *
Connecticut State PH-0223 09-30-21
Florida NELAP E87177 07-01-21
Georgia (DW)State 906 12-11-22
Hawaii State NA 12-11-21
Kansas NELAP E-10349 10-31-21
Kentucky (DW)State 90101 12-31-21
Louisiana NELAP 83979 06-30-21
Louisiana (DW)State LA019 12-31-21
Maryland State 277 03-31-22
Michigan State 9933 12-11-22
Nevada State TN00009 07-31-21
New Hampshire NELAP 299919 01-17-22
New Jersey NELAP TN001 07-01-21
New York NELAP 10781 04-01-21
North Carolina (DW)State 21705 07-31-21
North Carolina (WW/SW)State 64 12-31-21
Ohio VAP State CL0059 06-02-23
Oklahoma State 9415 08-31-21
Oregon NELAP TNI0189 01-01-22
Pennsylvania NELAP 68-00576 12-31-21
Tennessee State 02014 12-11-22
Texas NELAP T104704380-18-12 08-31-21
US Fish & Wildlife US Federal Programs 058448 07-31-21
USDA US Federal Programs P330-19-00236 08-20-22
Utah NELAP TN00009 07-31-21
Virginia NELAP 460176 09-14-21
Washington State C593 01-19-22
West Virginia (DW)State 9955C 01-02-22
West Virginia DEP State 345 05-01-21
Wisconsin State 998044300 08-31-21
Eurofins TestAmerica, Knoxville
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 19 of 27 3/31/2021
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Method Summary
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL KNX
NoneDilutionDilution and Re-fortification of Standards TAL KNX
TAL SOPNoneLeaching Procedure TAL KNX
TAL SOPNoneLeaching Procedure for Condensate TAL KNX
TAL SOPNoneLeaching Procedure for Filter TAL KNX
NoneSplitSource Air Split TAL KNX
Protocol References:
EPA = US Environmental Protection Agency
None = None
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 20 of 27 3/31/2021
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Sample Summary
Job ID: 140-22281-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Inlet
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-22281-1 Z-2635,2636 PPA CB INLET R1 OTM-45 FH Air 03/11/21 00:00 03/13/21 10:40
140-22281-2 Z-2637,2638,2640 PPA CB INLET R1 OTM-45 BH Air 03/11/21 00:00 03/13/21 10:40
140-22281-3 Z-2639 PPA CB INLET R1 OTM-45 IMPINGERS
1,2&3 COND
Air 03/11/21 00:00 03/13/21 10:40
140-22281-4 Z-2641 PPA CB INLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/11/21 00:00 03/13/21 10:40
140-22281-5 Z-2642,2643 PPA CB INLET R2 OTM-45 FH Air 03/11/21 00:00 03/13/21 10:40
140-22281-6 Z-2644,2645,2647 PPA CB INLET R2 OTM-45 BH Air 03/11/21 00:00 03/13/21 10:40
140-22281-7 Z-2646 PPA CB INLET R2 OTM-45 IMPINGERS
1,2&3 COND
Air 03/11/21 00:00 03/13/21 10:40
140-22281-8 Z-2648 PPA CB INLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/11/21 00:00 03/13/21 10:40
140-22281-9 Z-2649,2650 PPA CB INLET R3 OTM-45 FH Air 03/11/21 00:00 03/13/21 10:40
140-22281-10 Z-2651,2652,2654 PPA CB INLET R3 OTM-45 BH Air 03/11/21 00:00 03/13/21 10:40
140-22281-11 Z-2653 PPA CB INLET R3 OTM-45 IMPINGERS
1,2&3 COND
Air 03/11/21 00:00 03/13/21 10:40
140-22281-12 Z-2655 PPA CB INLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/11/21 00:00 03/13/21 10:40
Eurofins TestAmerica, Knoxville
Page 21 of 27 3/31/2021
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PPA Carbon Bed Outlet Laboratory Data

ANALYTICAL REPORT
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike
Knoxville, TN 37921
Tel: [phone]
Laboratory Job ID: 140-22283-1
Client Project/Site: PPA Carbon Bed Outlet
For:
The Chemours Company FC, LLC
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, Delaware 19713
Attn: Michael Aucoin
Authorized for release by:
4/6/2021 1:18:42 PM
Courtney Adkins, Project Manager II
[phone]
[e-mail]
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Laboratory Job ID: 140-22283-1
Page 2 of 26 Eurofins TestAmerica, Knoxville4/6/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .20
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21
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Definitions/Glossary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Qualifiers
LCMS
Qualifier Description
B Compound was found in the blank and sample.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Knoxville
Page 3 of 26 4/6/2021
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Case Narrative
Client: The Chemours Company FC, LLC Job ID: 140-22283-1
Project/Site: PPA Carbon Bed Outlet
Job ID: 140-22283-1
Laboratory: Eurofins TestAmerica, Knoxville
Narrative
Job Narrative
140-22283-1
Sample Receipt
The samples were received on 3/13/2021 10:40 AM. Unless otherwise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 0.4º C.
LCMS
LC/MS/MS Sampling Train Preparation and Analysis: The sampling train components are extracted and analyzed for Per- and
Polyfluorinated Alkyl Substances (PFAS) using Eurofins TestAmerica Knoxville standard operating procedures KNOX-OP-0026 and
KNOX-LC-0007.
The sampling trains are prepared as four analytical fractions: The particulate filter and front half of the filter holder, nozzle and probe
solvent rinses are combined for one analytical fraction. The XAD-2 resin trap and back half of the filter holder, coil condenser and
connecting glassware solvent rinses are also combined as a separate analytical fraction. The condensate, impinger contents and their
related glassware DI water rinses make up the third analytical fraction. The breakthrough XAD module makes up the fourth analytical
fraction.
The filters and XAD components are spiked with isotope dilution internal standards and the components are extracted with
methanol/ammonium hydroxide by shaking for at least 18 hours. The extracts are concentrated to 10 mL and analyzed by HPLC/MS/MS.
The condensates are spiked with the isotope dilution internal standards and extracted using either Solid-Phase Extraction (SPE) or
diluting the water sample for analysis. Each extract at its final volume is 80:20 methanol:water
Sample results were calculated using the following equation:

Result, ηg/sample = (on-column concentration, ηg/mL) × (nominal final volume of extract (10 mL) / 1 sample) × DF × SF
Where:
DF = Instrument dilution factor
SF = Extraction Split Factor = (final volume of extract in the initial extraction batch / initial volume of extract in the “Split” batch)
For condensate, if less than the entire sample is extracted, the fraction of sample used replaces “1 sample”
Method 537 (modified): The method blank for preparation batch 140-48003 and 140-48146 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The Isotope Dilution Analyte (IDA) recovery associated with the following sample is below the method
recommended limit: (LCS 140-47984/2-B). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than
10:1.
Method 537 (modified): The method blank for preparation batch 140-47984 and 140-48079 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The method blank for preparation batch 140-47947 and 140-48222 contained HFPO-DA above the reporting limit
(RL). Most client samples are not 10X the method blank contamination. The entire sample was consumed during analysis or extraction,
therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins TestAmerica, KnoxvillePage 4 of 26 4/6/2021
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Detection Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Client Sample ID: Q-1958,1959 PPA CB OUTLET R1 OTM-45
FH
Lab Sample ID: 140-22283-1
HFPO-DA
RL
0.100 ug/Sample
MDL
0.0580
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B6.21 537 (modified)
Client Sample ID: Q-1960,1961,1963 PPA CB OUTLET R1
OTM-45 BH
Lab Sample ID: 140-22283-2
HFPO-DA
RL
0.0160 ug/Sample
MDL
0.0140
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10B1.31 537 (modified)
Client Sample ID: Q-1962 PPA CB OUTLET R1 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22283-3
HFPO-DA
RL
0.0899 ug/Sample
MDL
0.0148
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.296 537 (modified)
Client Sample ID: Q-1964 PPA CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22283-4
HFPO-DA
RL
0.00160 ug/Sample
MDL
0.00140
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.0175 537 (modified)
Client Sample ID: Q-1965,1966 PPA CB OUTLET R2 OTM-45
FH
Lab Sample ID: 140-22283-5
HFPO-DA
RL
0.0991 ug/Sample
MDL
0.0575
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B4.02 537 (modified)
Client Sample ID: Q-1967,1968,1970 PPA CB OUTLET R2
OTM-45 BH
Lab Sample ID: 140-22283-6
HFPO-DA
RL
0.0160 ug/Sample
MDL
0.0140
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA10B1.13 537 (modified)
Client Sample ID: Q-1969 PPA CB OUTLET R2 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22283-7
HFPO-DA
RL
0.111 ug/Sample
MDL
0.0184
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.365 537 (modified)
Client Sample ID: Q-1971 PPA CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22283-8
HFPO-DA
RL
0.00160 ug/Sample
MDL
0.00140
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.0224 537 (modified)
Client Sample ID: Q-1972,1973 PPA CB OUTLET R3 OTM-45
FH
Lab Sample ID: 140-22283-9
HFPO-DA
RL
0.100 ug/Sample
MDL
0.0580
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B2.68 537 (modified)
Eurofins TestAmerica, Knoxville
This Detection Summary does not include radiochemical test results.
Page 5 of 26 4/6/2021
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Detection Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Client Sample ID: Q-1974,1975,1977 PPA CB OUTLET R3
OTM-45 BH
Lab Sample ID: 140-22283-10
HFPO-DA
RL
0.00800 ug/Sample
MDL
0.00700
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA5B0.710 537 (modified)
Client Sample ID: Q-1976 PPA CB OUTLET R3 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22283-11
HFPO-DA
RL
0.0899 ug/Sample
MDL
0.0148
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.333 537 (modified)
Client Sample ID: Q-1978 PPA CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22283-12
HFPO-DA
RL
0.00160 ug/Sample
MDL
0.00140
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.0192 537 (modified)
Eurofins TestAmerica, Knoxville
This Detection Summary does not include radiochemical test results.
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Client Sample Results
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Lab Sample ID: 140-22283-1Client Sample ID: Q-1958,1959 PPA CB OUTLET R1 OTM-45
FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 6.21 B 0.100 0.0580 ug/Sample 03/22/21 14:10 03/28/21 03:05 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 101 25-150 03/22/21 14:10 03/28/21 03:05 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-2Client Sample ID: Q-1960,1961,1963 PPA CB OUTLET R1
OTM-45 BH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 1.31 B 0.0160 0.0140 ug/Sample 03/22/21 09:12 04/02/21 13:44 10
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 98 25-150 03/22/21 09:12 04/02/21 13:44 10
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-3Client Sample ID: Q-1962 PPA CB OUTLET R1 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.296 B 0.0899 0.0148 ug/Sample 03/23/21 05:53 03/27/21 13:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 102 25-150 03/23/21 05:53 03/27/21 13:21 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-4Client Sample ID: Q-1964 PPA CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0175 B 0.00160 0.00140 ug/Sample 03/22/21 09:12 04/01/21 19:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 82 25-150 03/22/21 09:12 04/01/21 19:06 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 7 of 26 4/6/2021
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Client Sample Results
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Lab Sample ID: 140-22283-5Client Sample ID: Q-1965,1966 PPA CB OUTLET R2 OTM-45
FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 4.02 B 0.0991 0.0575 ug/Sample 03/22/21 14:10 03/28/21 03:14 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 108 25-150 03/22/21 14:10 03/28/21 03:14 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-6Client Sample ID: Q-1967,1968,1970 PPA CB OUTLET R2
OTM-45 BH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 1.13 B 0.0160 0.0140 ug/Sample 03/22/21 09:12 04/02/21 15:14 10
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 98 25-150 03/22/21 09:12 04/02/21 15:14 10
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-7Client Sample ID: Q-1969 PPA CB OUTLET R2 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.365 B 0.111 0.0184 ug/Sample 03/23/21 05:53 03/27/21 13:30 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 107 25-150 03/23/21 05:53 03/27/21 13:30 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-8Client Sample ID: Q-1971 PPA CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0224 B 0.00160 0.00140 ug/Sample 03/22/21 09:12 04/01/21 19:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 84 25-150 03/22/21 09:12 04/01/21 19:24 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 8 of 26 4/6/2021
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Client Sample Results
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Lab Sample ID: 140-22283-9Client Sample ID: Q-1972,1973 PPA CB OUTLET R3 OTM-45
FH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 2.68 B 0.100 0.0580 ug/Sample 03/22/21 14:10 03/28/21 03:22 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 110 25-150 03/22/21 14:10 03/28/21 03:22 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-10Client Sample ID: Q-1974,1975,1977 PPA CB OUTLET R3
OTM-45 BH
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.710 B 0.00800 0.00700 ug/Sample 03/22/21 09:12 04/02/21 14:01 5
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 96 25-150 03/22/21 09:12 04/02/21 14:01 5
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-11Client Sample ID: Q-1976 PPA CB OUTLET R3 OTM-45
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.333 B 0.0899 0.0148 ug/Sample 03/23/21 05:53 03/27/21 13:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 102 25-150 03/23/21 05:53 03/27/21 13:39 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22283-12Client Sample ID: Q-1978 PPA CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.0192 B 0.00160 0.00140 ug/Sample 03/22/21 09:12 04/01/21 19:50 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 85 25-150 03/22/21 09:12 04/01/21 19:50 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Isotope Dilution Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (25-150)
HFPODA
101140-22283-1
Percent Isotope Dilution Recovery (Acceptance Limits)
Q-1958,1959 PPA CB OUTLET R1 OTM-45 FH
98140-22283-2 Q-1960,1961,1963 PPA CB
OUTLET R1 OTM-45 BH
102140-22283-3 Q-1962 PPA CB OUTLET R1
OTM-45 IMPINGERS 1,2&3
COND
82140-22283-4 Q-1964 PPA CB OUTLET R1
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
108140-22283-5 Q-1965,1966 PPA CB OUTLET
R2 OTM-45 FH
98140-22283-6 Q-1967,1968,1970 PPA CB
OUTLET R2 OTM-45 BH
107140-22283-7 Q-1969 PPA CB OUTLET R2
OTM-45 IMPINGERS 1,2&3
COND
84140-22283-8 Q-1971 PPA CB OUTLET R2
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
110140-22283-9 Q-1972,1973 PPA CB OUTLET
R3 OTM-45 FH
96140-22283-10 Q-1974,1975,1977 PPA CB
OUTLET R3 OTM-45 BH
102140-22283-11 Q-1976 PPA CB OUTLET R3
OTM-45 IMPINGERS 1,2&3
COND
85140-22283-12 Q-1978 PPA CB OUTLET R3
OTM-45 BREAKTHROUGH
XAD-2 RESIN TUBE
83LCS 140-47947/2-B Lab Control Sample
32LCS 140-47984/2-B Lab Control Sample
112LCS 140-48003/2-B Lab Control Sample
60LCSD 140-47947/3-B Lab Control Sample Dup
96LCSD 140-47984/3-B Lab Control Sample Dup
107LCSD 140-48003/3-B Lab Control Sample Dup
75MB 140-47947/14-B Method Blank
89MB 140-47947/1-B Method Blank
92MB 140-47984/1-B Method Blank
112MB 140-48003/1-B Method Blank
Surrogate Legend
HFPODA = 13C3 HFPO-DA
Eurofins TestAmerica, Knoxville
Page 10 of 26 4/6/2021
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QC Sample Results
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 140-47947/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 47947
RL MDL
HFPO-DA 0.002401 0.00160 0.00140 ug/Sample 03/22/21 09:12 04/01/21 19:32 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 75 25-150 04/01/21 19:32 1
MB MB
Isotope Dilution
03/22/21 09:12
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47947/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 47947
RL MDL
HFPO-DA 0.003211 0.00160 0.00140 ug/Sample 03/22/21 09:12 04/01/21 17:20 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 89 25-150 04/01/21 17:20 1
MB MB
Isotope Dilution
03/22/21 09:12
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47947/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 47947
HFPO-DA 0.0200 0.02402 ug/Sample 120 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
83
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47947/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 47947
HFPO-DA 0.0200 0.02278 ug/Sample 114 60-140 5 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
60
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47984/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
RL MDL
HFPO-DA 0.002562 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 01:28 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 92 25-150 03/28/21 01:28 1
MB MB
Isotope Dilution
03/22/21 14:10
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 11 of 26 4/6/2021
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QC Sample Results
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47984/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02413 ug/Sample 121 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
32
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47984/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02295 ug/Sample 115 60-140 5 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
96
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-48003/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
RL MDL
HFPO-DA 0.001514 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 11:45 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 112 25-150 03/27/21 11:45 1
MB MB
Isotope Dilution
03/23/21 05:53
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-48003/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01114 ug/Sample 111 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
112
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-48003/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01177 ug/Sample 118 60-140 6 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
107
LCSD LCSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 12 of 26 4/6/2021
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QC Association Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
LCMS
Prep Batch: 47947
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22283-2 Q-1960,1961,1963 PPA CB OUTLET R1 OTM-45 BHTotal/NA
Air None140-22283-4 Q-1964 PPA CB OUTLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22283-6 Q-1967,1968,1970 PPA CB OUTLET R2 OTM-45 BHTotal/NA
Air None140-22283-8 Q-1971 PPA CB OUTLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-22283-10 Q-1974,1975,1977 PPA CB OUTLET R3 OTM-45 BHTotal/NA
Air None140-22283-12 Q-1978 PPA CB OUTLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air NoneMB 140-47947/14-B Method Blank Total/NA
Air NoneMB 140-47947/1-B Method Blank Total/NA
Air NoneLCS 140-47947/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47947/3-B Lab Control Sample Dup Total/NA
Prep Batch: 47984
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22283-1 Q-1958,1959 PPA CB OUTLET R1 OTM-45 FH Total/NA
Air None140-22283-5 Q-1965,1966 PPA CB OUTLET R2 OTM-45 FH Total/NA
Air None140-22283-9 Q-1972,1973 PPA CB OUTLET R3 OTM-45 FH Total/NA
Air NoneMB 140-47984/1-B Method Blank Total/NA
Air NoneLCS 140-47984/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Prep Batch: 48003
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22283-3 Q-1962 PPA CB OUTLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22283-7 Q-1969 PPA CB OUTLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-22283-11 Q-1976 PPA CB OUTLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air NoneMB 140-48003/1-B Method Blank Total/NA
Air NoneLCS 140-48003/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48079
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47984140-22283-1 Q-1958,1959 PPA CB OUTLET R1 OTM-45 FH Total/NA
Air Split 47984140-22283-5 Q-1965,1966 PPA CB OUTLET R2 OTM-45 FH Total/NA
Air Split 47984140-22283-9 Q-1972,1973 PPA CB OUTLET R3 OTM-45 FH Total/NA
Air Split 47984MB 140-47984/1-B Method Blank Total/NA
Air Split 47984LCS 140-47984/2-B Lab Control Sample Total/NA
Air Split 47984LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48146
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 48003140-22283-3 Q-1962 PPA CB OUTLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 48003140-22283-7 Q-1969 PPA CB OUTLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 48003140-22283-11 Q-1976 PPA CB OUTLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air Split 48003MB 140-48003/1-B Method Blank Total/NA
Air Split 48003LCS 140-48003/2-B Lab Control Sample Total/NA
Air Split 48003LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146140-22283-3 Q-1962 PPA CB OUTLET R1 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)48146140-22283-7 Q-1969 PPA CB OUTLET R2 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
LCMS (Continued)
Analysis Batch: 48210 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146140-22283-11 Q-1976 PPA CB OUTLET R3 OTM-45 IMPINGERS 1,2&3 CONDTotal/NA
Air 537 (modified)48146MB 140-48003/1-B Method Blank Total/NA
Air 537 (modified)48146LCS 140-48003/2-B Lab Control Sample Total/NA
Air 537 (modified)48146LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48218
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Dilution 48079140-22283-1 Q-1958,1959 PPA CB OUTLET R1 OTM-45 FH Total/NA
Air Dilution 48079140-22283-5 Q-1965,1966 PPA CB OUTLET R2 OTM-45 FH Total/NA
Air Dilution 48079140-22283-9 Q-1972,1973 PPA CB OUTLET R3 OTM-45 FH Total/NA
Analysis Batch: 48219
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48218140-22283-1 Q-1958,1959 PPA CB OUTLET R1 OTM-45 FH Total/NA
Air 537 (modified)48218140-22283-5 Q-1965,1966 PPA CB OUTLET R2 OTM-45 FH Total/NA
Air 537 (modified)48218140-22283-9 Q-1972,1973 PPA CB OUTLET R3 OTM-45 FH Total/NA
Air 537 (modified)48079MB 140-47984/1-B Method Blank Total/NA
Air 537 (modified)48079LCS 140-47984/2-B Lab Control Sample Total/NA
Air 537 (modified)48079LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48222
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47947140-22283-2 Q-1960,1961,1963 PPA CB OUTLET R1 OTM-45 BHTotal/NA
Air Split 47947140-22283-4 Q-1964 PPA CB OUTLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47947140-22283-6 Q-1967,1968,1970 PPA CB OUTLET R2 OTM-45 BHTotal/NA
Air Split 47947140-22283-8 Q-1971 PPA CB OUTLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47947140-22283-10 Q-1974,1975,1977 PPA CB OUTLET R3 OTM-45 BHTotal/NA
Air Split 47947140-22283-12 Q-1978 PPA CB OUTLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air Split 47947MB 140-47947/14-B Method Blank Total/NA
Air Split 47947MB 140-47947/1-B Method Blank Total/NA
Air Split 47947LCS 140-47947/2-B Lab Control Sample Total/NA
Air Split 47947LCSD 140-47947/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48419
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48222140-22283-4 Q-1964 PPA CB OUTLET R1 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48222140-22283-8 Q-1971 PPA CB OUTLET R2 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48222140-22283-12 Q-1978 PPA CB OUTLET R3 OTM-45 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 537 (modified)48222MB 140-47947/14-B Method Blank Total/NA
Air 537 (modified)48222MB 140-47947/1-B Method Blank Total/NA
Air 537 (modified)48222LCS 140-47947/2-B Lab Control Sample Total/NA
Air 537 (modified)48222LCSD 140-47947/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48462
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48222140-22283-2 Q-1960,1961,1963 PPA CB OUTLET R1 OTM-45 BHTotal/NA
Air 537 (modified)48222140-22283-6 Q-1967,1968,1970 PPA CB OUTLET R2 OTM-45 BHTotal/NA
Air 537 (modified)48222140-22283-10 Q-1974,1975,1977 PPA CB OUTLET R3 OTM-45 BHTotal/NA
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22283-1
Project/Site: PPA Carbon Bed Outlet
Client Sample ID: Q-1958,1959 PPA CB OUTLET R1 OTM-45
FH
Lab Sample ID: 140-22283-1
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 72 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 36 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 100 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 03:05 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1960,1961,1963 PPA CB OUTLET R1
OTM-45 BH
Lab Sample ID: 140-22283-2
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 09:12 TAL KNX47947
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48222 03/28/21 06:44 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)10 48462 04/02/21 13:44 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1962 PPA CB OUTLET R1 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22283-3
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00556
Sample
10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 13:21 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1964 PPA CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22283-4
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 09:12 TAL KNX47947
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48222 03/28/21 06:44 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 19:06 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22283-1
Project/Site: PPA Carbon Bed Outlet
Client Sample ID: Q-1965,1966 PPA CB OUTLET R2 OTM-45
FH
Lab Sample ID: 140-22283-5
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 109 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 55 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 100 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 03:14 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1967,1968,1970 PPA CB OUTLET R2
OTM-45 BH
Lab Sample ID: 140-22283-6
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 09:12 TAL KNX47947
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48222 03/28/21 06:44 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)10 48462 04/02/21 15:14 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1969 PPA CB OUTLET R2 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22283-7
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00449
Sample
10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 13:30 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1971 PPA CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22283-8
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 09:12 TAL KNX47947
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48222 03/28/21 06:44 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 19:24 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
Page 16 of 26 4/6/2021
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22283-1
Project/Site: PPA Carbon Bed Outlet
Client Sample ID: Q-1972,1973 PPA CB OUTLET R3 OTM-45
FH
Lab Sample ID: 140-22283-9
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 142 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 71 mL 10 mL
Cleanup Dilution 48218 03/27/21 05:30 JRC TAL KNXTotal/NA 100 uL 10000 uL
Analysis 537 (modified)1 48219 03/28/21 03:22 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1974,1975,1977 PPA CB OUTLET R3
OTM-45 BH
Lab Sample ID: 140-22283-10
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 09:12 TAL KNX47947
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48222 03/28/21 06:44 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)5 48462 04/02/21 14:01 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1976 PPA CB OUTLET R3 OTM-45
IMPINGERS 1,2&3 COND
Lab Sample ID: 140-22283-11
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 0.00556
Sample
10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 13:39 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: Q-1978 PPA CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Lab Sample ID: 140-22283-12
Matrix: AirDate Collected: 03/11/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 09:12 TAL KNX47947
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48222 03/28/21 06:44 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 19:50 JRC TAL KNXTotal/NA
LCAInstrument ID:
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
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Accreditation/Certification Summary
Client: The Chemours Company FC, LLC Job ID: 140-22283-1
Project/Site: PPA Carbon Bed Outlet
Laboratory: Eurofins TestAmerica, Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
N/AAFCEE
ANAB Dept. of Defense ELAP L2311 02-13-22
ANAB Dept. of Energy L2311.01 02-13-22
ANAB ISO/IEC 17025 L2311 02-13-22
ANAB ISO/IEC 17025 L2311 02-14-22
Arkansas DEQ State 88-0688 06-17-21
California State 2423 06-30-22
Colorado State TN00009 02-28-21 *
Connecticut State PH-0223 09-30-21
Florida NELAP E87177 07-01-21
Georgia (DW)State 906 12-11-22
Hawaii State NA 12-11-21
Kansas NELAP E-10349 10-31-21
Kentucky (DW)State 90101 12-31-21
Louisiana NELAP 83979 06-30-21
Louisiana (DW)State LA019 12-31-21
Maryland State 277 03-31-22
Michigan State 9933 12-11-22
Nevada State TN00009 07-31-21
New Hampshire NELAP 299919 01-17-22
New Jersey NELAP TN001 07-01-21
New York NELAP 10781 03-31-22
North Carolina (DW)State 21705 07-31-21
North Carolina (WW/SW)State 64 12-31-21
Ohio VAP State CL0059 06-02-23
Oklahoma State 9415 08-31-21
Oregon NELAP TNI0189 01-01-22
Pennsylvania NELAP 68-00576 12-31-21
Tennessee State 02014 12-11-22
Texas NELAP T104704380-18-12 08-31-21
US Fish & Wildlife US Federal Programs 058448 07-31-21
USDA US Federal Programs P330-19-00236 08-20-22
Utah NELAP TN00009 07-31-21
Virginia NELAP 460176 09-14-21
Washington State C593 01-19-22
West Virginia (DW)State 9955C 01-02-22
West Virginia DEP State 345 05-01-21
Wisconsin State 998044300 08-31-21
Eurofins TestAmerica, Knoxville
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 18 of 26 4/6/2021
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Method Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL KNX
NoneDilutionDilution and Re-fortification of Standards TAL KNX
TAL SOPNoneLeaching Procedure TAL KNX
TAL SOPNoneLeaching Procedure for Condensate TAL KNX
TAL SOPNoneLeaching Procedure for Filter TAL KNX
NoneSplitSource Air Split TAL KNX
Protocol References:
EPA = US Environmental Protection Agency
None = None
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
Page 19 of 26 4/6/2021
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Sample Summary
Job ID: 140-22283-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Outlet
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-22283-1 Q-1958,1959 PPA CB OUTLET R1 OTM-45 FH Air 03/11/21 00:00 03/13/21 10:40
140-22283-2 Q-1960,1961,1963 PPA CB OUTLET R1 OTM-45
BH
Air 03/11/21 00:00 03/13/21 10:40
140-22283-3 Q-1962 PPA CB OUTLET R1 OTM-45 IMPINGERS
1,2&3 COND
Air 03/11/21 00:00 03/13/21 10:40
140-22283-4 Q-1964 PPA CB OUTLET R1 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/11/21 00:00 03/13/21 10:40
140-22283-5 Q-1965,1966 PPA CB OUTLET R2 OTM-45 FH Air 03/11/21 00:00 03/13/21 10:40
140-22283-6 Q-1967,1968,1970 PPA CB OUTLET R2 OTM-45
BH
Air 03/11/21 00:00 03/13/21 10:40
140-22283-7 Q-1969 PPA CB OUTLET R2 OTM-45 IMPINGERS
1,2&3 COND
Air 03/11/21 00:00 03/13/21 10:40
140-22283-8 Q-1971 PPA CB OUTLET R2 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/11/21 00:00 03/13/21 10:40
140-22283-9 Q-1972,1973 PPA CB OUTLET R3 OTM-45 FH Air 03/11/21 00:00 03/13/21 10:40
140-22283-10 Q-1974,1975,1977 PPA CB OUTLET R3 OTM-45
BH
Air 03/11/21 00:00 03/13/21 10:40
140-22283-11 Q-1976 PPA CB OUTLET R3 OTM-45 IMPINGERS
1,2&3 COND
Air 03/11/21 00:00 03/13/21 10:40
140-22283-12 Q-1978 PPA CB OUTLET R3 OTM-45
BREAKTHROUGH XAD-2 RESIN TUBE
Air 03/11/21 00:00 03/13/21 10:40
Eurofins TestAmerica, Knoxville
Page 20 of 26 4/6/2021
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QA/QC Laboratory Data

ANALYTICAL REPORT
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike
Knoxville, TN 37921
Tel: [phone]
Laboratory Job ID: 140-22287-1
Client Project/Site: PPA Carbon Bed Field QC
For:
The Chemours Company FC, LLC
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, Delaware 19713
Attn: Michael Aucoin
Authorized for release by:
4/6/2021 1:21:45 PM
Courtney Adkins, Project Manager II
[phone]
[e-mail]
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Laboratory Job ID: 140-22287-1
Page 2 of 23 Eurofins TestAmerica, Knoxville4/6/2021
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .2
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .16
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .19
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Definitions/Glossary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Qualifiers
LCMS
Qualifier Description
B Compound was found in the blank and sample.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Eurofins TestAmerica, Knoxville
Page 3 of 23 4/6/2021
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Case Narrative
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Job ID: 140-22287-1
Laboratory: Eurofins TestAmerica, Knoxville
Narrative
Job Narrative
140-22287-1
Receipt
The samples were received on 3/13/2021 10:40 AM. Unless otherwise noted below, the samples arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.6º C.
LCMS
LC/MS/MS Sampling Train Preparation and Analysis: The sampling train components are extracted and analyzed for Per- and
Polyfluorinated Alkyl Substances (PFAS) using Eurofins TestAmerica Knoxville standard operating procedures KNOX-OP-0026 and
KNOX-LC-0007.
The sampling trains are prepared as four analytical fractions: The particulate filter and front half of the filter holder, nozzle and probe
solvent rinses are combined for one analytical fraction. The XAD-2 resin trap and back half of the filter holder, coil condenser and
connecting glassware solvent rinses are also combined as a separate analytical fraction. The condensate, impinger contents and their
related glassware DI water rinses make up the third analytical fraction. The breakthrough XAD module makes up the fourth analytical
fraction.
The filters and XAD components are spiked with isotope dilution internal standards and the components are extracted with
methanol/ammonium hydroxide by shaking for at least 18 hours. The extracts are concentrated to 10 mL and analyzed by HPLC/MS/MS.
The condensates are spiked with the isotope dilution internal standards and extracted using either Solid-Phase Extraction (SPE) or
diluting the water sample for analysis. Each extract at its final volume is 80:20 methanol:water
Sample results were calculated using the following equation:

Result, ηg/sample = (on-column concentration, ηg/mL) × (nominal final volume of extract (10 mL) / 1 sample) × DF × SF
Where:
DF = Instrument dilution factor
SF = Extraction Split Factor = (final volume of extract in the initial extraction batch / initial volume of extract in the “Split” batch)
For condensate, if less than the entire sample is extracted, the fraction of sample used replaces “1 sample”
Method 537 (modified): The method blank for preparation batch 140-48003 and 140-48146 contained HFPO-DA above the reporting limit
(RL). The entire sample was consumed during analysis or extraction, therefore, the data have been reported.
Method 537 (modified): The Isotope Dilution Analyte (IDA) recovery associated with the following sample is below the method
recommended limit: (LCS 140-47984/2-B). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than
10:1.
Method 537 (modified): The method blank for preparation batch 140-47984 and 140-48079 HFPO-DA above the reporting limit (RL). The
entire sample was consumed during analysis or extraction, therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins TestAmerica, KnoxvillePage 4 of 23 4/6/2021
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Detection Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Client Sample ID: T-1108,1109 QC OTM-45 PPA CB FH BT Lab Sample ID: 140-22287-1
HFPO-DA
RL
0.00100 ug/Sample
MDL
0.000580
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00386 537 (modified)
Client Sample ID: T-1110,1111,1113 QC OTM-45 PPA CB BH BT Lab Sample ID: 140-22287-2
No Detections.
Client Sample ID: T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Lab Sample ID: 140-22287-3
HFPO-DA
RL
0.000500 ug/Sample
MDL
0.0000825
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00133 537 (modified)
Client Sample ID: T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN TUBE BT
Lab Sample ID: 140-22287-4
No Detections.
Client Sample ID: T-1115 QC OTM-45 PPA CB DI WATER RB Lab Sample ID: 140-22287-5
HFPO-DA
RL
0.000500 ug/Sample
MDL
0.0000825
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00121 537 (modified)
Client Sample ID: T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Lab Sample ID: 140-22287-6
No Detections.
Client Sample ID: T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Lab Sample ID: 140-22287-7
No Detections.
Client Sample ID: A-7359 MEDIA CHECK XAD Lab Sample ID: 140-22287-8
No Detections.
Client Sample ID: A-7360 MEDIA CHECK FILTER Lab Sample ID: 140-22287-9
HFPO-DA
RL
0.00100 ug/Sample
MDL
0.000580
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1B0.00267 537 (modified)
Eurofins TestAmerica, Knoxville
This Detection Summary does not include radiochemical test results.
Page 5 of 23 4/6/2021
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Client Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Lab Sample ID: 140-22287-1Client Sample ID: T-1108,1109 QC OTM-45 PPA CB FH BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00386 B 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 11:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 96 25-150 03/22/21 14:10 03/28/21 11:13 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-2Client Sample ID: T-1110,1111,1113 QC OTM-45 PPA CB BH BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 21:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 80 25-150 03/23/21 14:37 04/01/21 21:44 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-3Client Sample ID: T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00133 B 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 14:23 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 108 25-150 03/23/21 05:53 03/27/21 14:23 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-4Client Sample ID: T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN TUBE BT
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 21:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 76 25-150 03/23/21 14:37 04/01/21 21:53 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-5Client Sample ID: T-1115 QC OTM-45 PPA CB DI WATER RB
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00121 B 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 14:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 111 25-150 03/23/21 05:53 03/27/21 14:32 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
Page 6 of 23 4/6/2021
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Client Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Lab Sample ID: 140-22287-6Client Sample ID: T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 22:02 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 91 25-150 03/23/21 14:37 04/01/21 22:02 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-7Client Sample ID: T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 22:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 87 25-150 03/23/21 14:37 04/01/21 22:11 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-8Client Sample ID: A-7359 MEDIA CHECK XAD
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 22:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 74 25-150 03/23/21 14:37 04/01/21 22:37 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-22287-9Client Sample ID: A-7360 MEDIA CHECK FILTER
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Sample Container: Air Train
Method: 537 (modified) - Fluorinated Alkyl Substances
RL MDL
HFPO-DA 0.00267 B 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 11:22 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 83 25-150 03/22/21 14:10 03/28/21 11:22 1
Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Isotope Dilution Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances
Prep Type: Total/NAMatrix: Air
Lab Sample ID Client Sample ID (25-150)
HFPODA
96140-22287-1
Percent Isotope Dilution Recovery (Acceptance Limits)
T-1108,1109 QC OTM-45 PPA CB FH BT
80140-22287-2 T-1110,1111,1113 QC OTM-45
PPA CB BH BT
108140-22287-3 T-1112 QC OTM-45 PPA CB
IMPINGER 1,2&3 COND BT
76140-22287-4 T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN
TUBE BT
111140-22287-5 T-1115 QC OTM-45 PPA CB DI
WATER RB
91140-22287-6 T-1116 QC OTM-45 PPA CB
MEOH WITH 5% NH4OH RB
87140-22287-7 T-1117 QC OTM-45 PPA CB
COMBINED GLASSWARE
RINSES (MEOH/5% NH4OH) PB
74140-22287-8 A-7359 MEDIA CHECK XAD
83140-22287-9 A-7360 MEDIA CHECK FILTER
32LCS 140-47984/2-B Lab Control Sample
112LCS 140-48003/2-B Lab Control Sample
76LCS 140-48051/2-B Lab Control Sample
96LCSD 140-47984/3-B Lab Control Sample Dup
107LCSD 140-48003/3-B Lab Control Sample Dup
78LCSD 140-48051/3-B Lab Control Sample Dup
76MB 140-47984/14-B Method Blank
92MB 140-47984/1-B Method Blank
102MB 140-48003/14-B Method Blank
112MB 140-48003/1-B Method Blank
93MB 140-48051/1-B Method Blank
Surrogate Legend
HFPODA = 13C3 HFPO-DA
Eurofins TestAmerica, Knoxville
Page 8 of 23 4/6/2021
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QC Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances
Client Sample ID: Method BlankLab Sample ID: MB 140-47984/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
RL MDL
HFPO-DA 0.002612 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 03:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 76 25-150 03/28/21 03:40 1
MB MB
Isotope Dilution
03/22/21 14:10
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-47984/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
RL MDL
HFPO-DA 0.002562 0.00100 0.000580 ug/Sample 03/22/21 14:10 03/28/21 01:28 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 92 25-150 03/28/21 01:28 1
MB MB
Isotope Dilution
03/22/21 14:10
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-47984/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02413 ug/Sample 121 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
32
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-47984/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48219 Prep Batch: 47984
HFPO-DA 0.0200 0.02295 ug/Sample 115 60-140 5 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
96
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-48003/14-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
RL MDL
HFPO-DA 0.001372 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 13:57 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 102 25-150 03/27/21 13:57 1
MB MB
Isotope Dilution
03/23/21 05:53
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 140-48003/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
RL MDL
HFPO-DA 0.001514 0.000500 0.0000825 ug/Sample 03/23/21 05:53 03/27/21 11:45 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 112 25-150 03/27/21 11:45 1
MB MB
Isotope Dilution
03/23/21 05:53
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-48003/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01114 ug/Sample 111 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
112
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-48003/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48210 Prep Batch: 48003
HFPO-DA 0.0100 0.01177 ug/Sample 118 60-140 6 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
107
LCSD LCSD
Qualifier Limits%Recovery
Client Sample ID: Method BlankLab Sample ID: MB 140-48051/1-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 48051
RL MDL
HFPO-DA ND 0.00160 0.00140 ug/Sample 03/23/21 14:37 04/01/21 21:18 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
13C3 HFPO-DA 93 25-150 04/01/21 21:18 1
MB MB
Isotope Dilution
03/23/21 14:37
Dil FacPrepared AnalyzedQualifier Limits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 140-48051/2-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 48051
HFPO-DA 0.0200 0.02171 ug/Sample 109 60-140
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
13C3 HFPO-DA 25 -150
Isotope Dilution
76
LCS LCS
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Sample Results
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method: 537 (modified) - Fluorinated Alkyl Substances (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 140-48051/3-B
Matrix: Air Prep Type: Total/NA
Analysis Batch: 48419 Prep Batch: 48051
HFPO-DA 0.0200 0.02091 ug/Sample 105 60-140 4 30
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
13C3 HFPO-DA 25 -150
Isotope Dilution
78
LCSD LCSD
Qualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
LCMS
Prep Batch: 47984
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Total/NA
Air None140-22287-9 A-7360 MEDIA CHECK FILTER Total/NA
Air NoneMB 140-47984/14-B Method Blank Total/NA
Air NoneMB 140-47984/1-B Method Blank Total/NA
Air NoneLCS 140-47984/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Prep Batch: 48003
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3 COND BTTotal/NA
Air None140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Total/NA
Air NoneMB 140-48003/14-B Method Blank Total/NA
Air NoneMB 140-48003/1-B Method Blank Total/NA
Air NoneLCS 140-48003/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Prep Batch: 48051
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Total/NA
Air None140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH XAD-2 RESIN TUBE BTTotal/NA
Air None140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5% NH4OH RBTotal/NA
Air None140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED GLASSWARE RINSES (MEOH/5% NH4OH) PBTotal/NA
Air None140-22287-8 A-7359 MEDIA CHECK XAD Total/NA
Air NoneMB 140-48051/1-B Method Blank Total/NA
Air NoneLCS 140-48051/2-B Lab Control Sample Total/NA
Air NoneLCSD 140-48051/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48079
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 47984140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Total/NA
Air Split 47984140-22287-9 A-7360 MEDIA CHECK FILTER Total/NA
Air Split 47984MB 140-47984/14-B Method Blank Total/NA
Air Split 47984MB 140-47984/1-B Method Blank Total/NA
Air Split 47984LCS 140-47984/2-B Lab Control Sample Total/NA
Air Split 47984LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Cleanup Batch: 48146
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 48003140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3 COND BTTotal/NA
Air Split 48003140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Total/NA
Air Split 48003MB 140-48003/14-B Method Blank Total/NA
Air Split 48003MB 140-48003/1-B Method Blank Total/NA
Air Split 48003LCS 140-48003/2-B Lab Control Sample Total/NA
Air Split 48003LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3 COND BTTotal/NA
Air 537 (modified)48146140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Total/NA
Air 537 (modified)48146MB 140-48003/14-B Method Blank Total/NA
Air 537 (modified)48146MB 140-48003/1-B Method Blank Total/NA
Eurofins TestAmerica, Knoxville
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QC Association Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
LCMS (Continued)
Analysis Batch: 48210 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48146LCS 140-48003/2-B Lab Control Sample Total/NA
Air 537 (modified)48146LCSD 140-48003/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48219
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48079MB 140-47984/14-B Method Blank Total/NA
Air 537 (modified)48079MB 140-47984/1-B Method Blank Total/NA
Air 537 (modified)48079LCS 140-47984/2-B Lab Control Sample Total/NA
Air 537 (modified)48079LCSD 140-47984/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48223
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48079140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Total/NA
Air 537 (modified)48079140-22287-9 A-7360 MEDIA CHECK FILTER Total/NA
Cleanup Batch: 48224
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air Split 48051140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Total/NA
Air Split 48051140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH XAD-2 RESIN TUBE BTTotal/NA
Air Split 48051140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5% NH4OH RBTotal/NA
Air Split 48051140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED GLASSWARE RINSES (MEOH/5% NH4OH) PBTotal/NA
Air Split 48051140-22287-8 A-7359 MEDIA CHECK XAD Total/NA
Air Split 48051MB 140-48051/1-B Method Blank Total/NA
Air Split 48051LCS 140-48051/2-B Lab Control Sample Total/NA
Air Split 48051LCSD 140-48051/3-B Lab Control Sample Dup Total/NA
Analysis Batch: 48419
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 537 (modified)48224140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Total/NA
Air 537 (modified)48224140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH XAD-2 RESIN TUBE BTTotal/NA
Air 537 (modified)48224140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5% NH4OH RBTotal/NA
Air 537 (modified)48224140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED GLASSWARE RINSES (MEOH/5% NH4OH) PBTotal/NA
Air 537 (modified)48224140-22287-8 A-7359 MEDIA CHECK XAD Total/NA
Air 537 (modified)48224MB 140-48051/1-B Method Blank Total/NA
Air 537 (modified)48224LCS 140-48051/2-B Lab Control Sample Total/NA
Air 537 (modified)48224LCSD 140-48051/3-B Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Client Sample ID: T-1108,1109 QC OTM-45 PPA CB FH BT Lab Sample ID: 140-22287-1
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48223 03/28/21 11:13 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1110,1111,1113 QC OTM-45 PPA CB BH BT Lab Sample ID: 140-22287-2
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 21:44 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Lab Sample ID: 140-22287-3
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 14:23 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1114 QC OTM-45 PPA CB
BREAKTHROUGH XAD-2 RESIN TUBE BT
Lab Sample ID: 140-22287-4
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 21:53 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1115 QC OTM-45 PPA CB DI WATER RB Lab Sample ID: 140-22287-5
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 05:53 TAL KNX48003
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 10 mL
Cleanup Split 48146 03/25/21 13:57 DWS TAL KNXTotal/NA 10 mL 10 mL
Analysis 537 (modified)1 48210 03/27/21 14:32 JRC TAL KNXTotal/NA
LCAInstrument ID:
Eurofins TestAmerica, Knoxville
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Lab Chronicle
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Client Sample ID: T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Lab Sample ID: 140-22287-6
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 22:02 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Lab Sample ID: 140-22287-7
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 22:11 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: A-7359 MEDIA CHECK XAD Lab Sample ID: 140-22287-8
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/23/21 14:37 TAL KNX48051
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 360 mL
Cleanup Split 48224 03/28/21 10:17 DWS TAL KNXTotal/NA 180 mL 10 mL
Analysis 537 (modified)1 48419 04/01/21 22:37 JRC TAL KNXTotal/NA
LCAInstrument ID:
Client Sample ID: A-7360 MEDIA CHECK FILTER Lab Sample ID: 140-22287-9
Matrix: AirDate Collected: 03/09/21 00:00
Date Received: 03/13/21 10:40
Prep None DWS03/22/21 14:10 TAL KNX47984
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 1 Sample 50 mL
Cleanup Split 48079 03/24/21 09:23 DWS TAL KNXTotal/NA 25 mL 10 mL
Analysis 537 (modified)1 48223 03/28/21 11:22 JRC TAL KNXTotal/NA
LCAInstrument ID:
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
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Accreditation/Certification Summary
Client: The Chemours Company FC, LLC Job ID: 140-22287-1
Project/Site: PPA Carbon Bed Field QC
Laboratory: Eurofins TestAmerica, Knoxville
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program Identification Number Expiration Date
N/AAFCEE
ANAB Dept. of Defense ELAP L2311 02-13-22
ANAB Dept. of Energy L2311.01 02-13-22
ANAB ISO/IEC 17025 L2311 02-13-22
ANAB ISO/IEC 17025 L2311 02-14-22
Arkansas DEQ State 88-0688 06-17-21
California State 2423 06-30-22
Colorado State TN00009 02-28-21 *
Connecticut State PH-0223 09-30-21
Florida NELAP E87177 07-01-21
Georgia (DW)State 906 12-11-22
Hawaii State NA 12-11-21
Kansas NELAP E-10349 10-31-21
Kentucky (DW)State 90101 12-31-21
Louisiana NELAP 83979 06-30-21
Louisiana (DW)State LA019 12-31-21
Maryland State 277 03-31-22
Michigan State 9933 12-11-22
Nevada State TN00009 07-31-21
New Hampshire NELAP 299919 01-17-22
New Jersey NELAP TN001 07-01-21
New York NELAP 10781 03-31-22
North Carolina (DW)State 21705 07-31-21
North Carolina (WW/SW)State 64 12-31-21
Ohio VAP State CL0059 06-02-23
Oklahoma State 9415 08-31-21
Oregon NELAP TNI0189 01-01-22
Pennsylvania NELAP 68-00576 12-31-21
Tennessee State 02014 12-11-22
Texas NELAP T104704380-18-12 08-31-21
US Fish & Wildlife US Federal Programs 058448 07-31-21
USDA US Federal Programs P330-19-00236 08-20-22
Utah NELAP TN00009 07-31-21
Virginia NELAP 460176 09-14-21
Washington State C593 01-19-22
West Virginia (DW)State 9955C 01-02-22
West Virginia DEP State 345 05-01-21
Wisconsin State 998044300 08-31-21
Eurofins TestAmerica, Knoxville
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 16 of 23 4/6/2021
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Method Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Method Method Description LaboratoryProtocol
EPA537 (modified) Fluorinated Alkyl Substances TAL KNX
TAL SOPNoneLeaching Procedure TAL KNX
TAL SOPNoneLeaching Procedure for Condensate TAL KNX
TAL SOPNoneLeaching Procedure for Filter TAL KNX
NoneSplitSource Air Split TAL KNX
Protocol References:
EPA = US Environmental Protection Agency
None = None
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
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Sample Summary
Job ID: 140-22287-1Client: The Chemours Company FC, LLC
Project/Site: PPA Carbon Bed Field QC
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-22287-1 T-1108,1109 QC OTM-45 PPA CB FH BT Air 03/09/21 00:00 03/13/21 10:40
140-22287-2 T-1110,1111,1113 QC OTM-45 PPA CB BH BT Air 03/09/21 00:00 03/13/21 10:40
140-22287-3 T-1112 QC OTM-45 PPA CB IMPINGER 1,2&3
COND BT
Air 03/09/21 00:00 03/13/21 10:40
140-22287-4 T-1114 QC OTM-45 PPA CB BREAKTHROUGH
XAD-2 RESIN TUBE BT
Air 03/09/21 00:00 03/13/21 10:40
140-22287-5 T-1115 QC OTM-45 PPA CB DI WATER RB Air 03/09/21 00:00 03/13/21 10:40
140-22287-6 T-1116 QC OTM-45 PPA CB MEOH WITH 5%
NH4OH RB
Air 03/09/21 00:00 03/13/21 10:40
140-22287-7 T-1117 QC OTM-45 PPA CB COMBINED
GLASSWARE RINSES (MEOH/5% NH4OH) PB
Air 03/09/21 00:00 03/13/21 10:40
140-22287-8 A-7359 MEDIA CHECK XAD Air 03/09/21 00:00 03/13/21 10:40
140-22287-9 A-7360 MEDIA CHECK FILTER Air 03/09/21 00:00 03/13/21 10:40
Eurofins TestAmerica, Knoxville
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Ramboll - Source Emissions Testing of the Polymer Process Aid Carbon Bed

APPENDIX E
EQUIPMENT CALIBRATION DATA

Pretest Equipment Calibration Data

METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES
1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.
2) Record barometric pressure before and after calibration procedure.
3) Run at tested vacuum (from Orifice Calibration Report), for a period of time
necessary to achieve a minimum total volume of 5 cubic feet.
4) Record data and information in the GREEN cells, YELLOW cells are calculated.
INITIAL FINAL AVG (Pbar)
DATE:1/8/2021 METER SERIAL #:MB 8 BAROMETRIC PRESSURE (in Hg):30.05 30.05 30.05
METER PART #:CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM ∆H (1)(2)(3)to with other
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIAL FINAL INITIAL FINAL AVG θ (in H2O)Vm (STD)Vcr (STD)Y Average Y orifices ∆H@
1 0.306 .0 0
2 0.306 23 297.964 306.208 8.244 78 77 78 76 77 77 20.00 0.43 8.1511 7.9310 0.973 1.52
3 0.306 .0 0
AVG = 0.973 0.74 1.23
1 0.4268 .0 0
2 0.4268 22 306.212 312.009 5.797 79 78 79 77 78 78 10.00 0.84 5.7267 5.5259 0.965 1.53
3 0.4268 .0 0
AVG = 0.965 -0.10 0.39
1 0.4961 .0 0
2 0.4961 21 312.016 319.456 7.440 80 79 80 78 78 78.75 11.00 1.1 7.3442 7.0589 0.961 1.48
3 0.4961 .0 0
AVG = 0.961 -0.49 -0.20
1 0.7131 .0 0
2 0.7131 18 319.485 329.159 9.674 81 79 82 78 79 79.5 10.00 2.5 9.5688 9.2155 0.963 1.64
3 0.7131 .0 0
AVG = 0.963 -0.29 0.20
1 0.8358 .0 0
2 0.8358 17 329.170 340.453 11.283 82 81 84 79 79 80.75 10.00 3.4 11.1588 10.7912 0.967 1.62
3 0.8358 .0 0
AVG = 0.967 0.13 0.62
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = 0.966
AVERAGE ∆H@ = 1.56
(1)=Net volume of gas sample passed through DGM, corrected to standard conditions
K1 =17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)
Tm =Absolute DGM avg. temperature (oR - English, oK - Metric) ∆H@ = 0.75 θ ∆H Vm(std)
Vcr(std) Vm
(2)=Volume of gas sample passed through the critical orifice, corrected to standard conditions
Tamb =Absolute ambient temperature (oR - English, oK - Metric)
K' = Average K' factor from Critical Orifice Calibration
(3)=DGM calibration factor
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ENVIRONMENTAL SUPPLY COMPANY
USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.
()2 ()
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\MB 8 Initial Cal 01072021.xls
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES
1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.
2) Record barometric pressure before and after calibration procedure.
3) Run at tested vacuum (from Orifice Calibration Report), for a period of time
necessary to achieve a minimum total volume of 5 cubic feet.
4) Record data and information in the GREEN cells, YELLOW cells are calculated.
INITIAL FINAL AVG (Pbar)
DATE:1/12/2021 METER SERIAL #:MB10 BAROMETRIC PRESSURE (in Hg):29.83 29.83 29.83
METER PART #:CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to with other
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y orifices DH@
1 0.306
2 0.306 23 259.927 267.844 7.917 67 71 70 71 70 70.5 19.50 0.45 7.8662 7.7559 0.986 1.59
3 0.306
AVG = 0.986 0.28 0.29
1 0.4268
2 0.4268 22.5 267.844 273.473 5.629 66 70 70 71 70 70.25 10.00 0.89 5.6015 5.5528 0.991 1.62
3 0.4268
AVG = 0.991 0.82 0.83
1 0.4961 21
2 0.4961 198.213 204.754 6.541 66 66 67 66 66 66.25 10.00 1.3 6.5652 6.4544 0.983 1.76
3 0.4961
AVG = 0.983 -0.01 0.36
1 0.7131
2 0.7131 19 221.925 231.311 9.386 75 70 72 68 69 69.75 10.00 2.7 9.3907 9.1993 0.980 1.80
3 0.7131
AVG = 0.980 -0.36 0.38
1 0.8358
2 0.8358 18 280.055 291.180 11.125 66 70 72 70 70 70.5 10.00 3.7 11.1420 10.8740 0.976 1.76
3 0.8358
AVG = 0.976 -0.74 -0.37
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y = 0.983
AVERAGE DH@ = 1.71
(1)=Net volume of gas sample passed through DGM, corrected to standard conditions
K1 =17.64 oR/in. Hg (English), 0.3858 oK/mm Hg (Metric)
Tm =Absolute DGM avg. temperature (oR - English, oK - Metric) DH@ = 0.75 q DH Vm(std)
Vcr(std) Vm
(2)=Volume of gas sample passed through the critical orifice, corrected to standard conditions
Tamb =Absolute ambient temperature (oR - English, oK - Metric)
K' = Average K' factor from Critical Orifice Calibration
(3)=DGM calibration factor
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USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:The following equations are used to calculate the standard volumes of air passed through the DGM, Vm (std), and the critical orifice, Vcr (std), and the DGM calibration factor, Y. These equations are automatically calculated in the spreadsheet above.
()2 ()
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\MB 10 Initial Cal 01122021.xls
Initial Oven Box Thermocouple Calibration
Reference Thermocouple Reference Thermocouple Reference ThermocoupleTemperature (oR)Temperature (oR)Temperature (oR)Temperature (oR)Temperature (oR)Temperature (oR)
OB-1 491.67 492.67 0.2%524.67 523.67 -0.2%671.67 673.67 0.3%SMilo 02/22/21
OB-2 491.67 492 0.1%530.67 531 0.1%671.67 672 0.0%SRW 03/02/21
OB-3 491.67 493 0.3%530.67 530 -0.1%671.67 671 -0.1%SRW 03/02/21
OB-4 491.67 493.67 0.4%524.67 524.67 0.0%671.67 670.67 -0.1%SMilo 02/22/21
OB-A 491.67 493 0.3%530.67 529 -0.3%671.67 673 0.2%SRW 03/02/21
OB-B 491.67 492 0.1%530.67 530 -0.1%671.67 672 0.0%SRW 03/02/21
OB-5 491.67 492 0.1%530.67 530 -0.1%671.67 670 -0.2%SRW 03/02/21
OB-C 491.67 492 0.1%530.67 529 -0.3%671.67 674 0.3%SRW 03/03/21
OB-6 491.67 493.67 0.4%524.67 525 0.1%671.67 669.67 -0.3%SMilo 02/22/21
OB-7 491.67 494.67 0.6%524.67 525 0.1%671.67 669.67 -0.3%SMilo 02/22/21
OB-E 491.67 492 0.1%530.67 529 -0.3%671.67 671.67 0.0%SRW 03/03/21
OB-10 491.67 492 0.1%530.67 531 0.1%671.67 670 -0.2%SRW 03/03/21
OB-11 491.67 495 0.7%530.67 532 0.3%671.67 672 0.0%SRW 03/03/21
OB-12 491.67 493 0.3%530.67 531 0.1%671.67 671 -0.1%SRW 03/03/21
Reference Thermocouple: Fluke S/N: 83450033 or S/N 90460057 traceable to the Untied States National Institute of Standards and Technology
*Acceptable Deviation: 1.5%
ID Number Ice Bath Ambient Hot Water Bath
Deviation*Deviation*Deviation*Technician Date
Performed
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\Copy of Init OB Cal 03032021.xls\2020
  DOCUMENT TITLEInitial Impinger Outlet Thermocouple CalibrationReference ThermocoupleReference ThermocoupleReference ThermocoupleTemperature (oRk)Temperature (oRk)Temperature (oRk)Temperature (oRk)Temperature (oRk)Temperature (oRk)IO-1 494.17 493.87 -0.1% 524.37 523.17 -0.2% 672.17 672.67 0.1% SM 03/16/21IO-2 493.67 493.87 0.0% 524.57 523.17 -0.3% 671.77 672.67 0.1% SM 03/16/21IO-3 493.57 493.87 0.1% 521.37 523.17 0.3% 671.77 672.67 0.1% SM 03/16/21IO-4 493.97 493.87 0.0% 524.37 523.17 -0.2% 671.17 672.67 0.2% SM 03/16/21IO-5 493.77 493.87 0.0% 524.07 523.17 -0.2% 672.37 672.67 0.0% SM 03/16/21IO-6 493.97 493.87 0.0% 522.97 523.17 0.0% 670.77 672.67 0.3% SM 03/16/21IO-7 493.17 493.87 0.1% 524.37 523.17 -0.2% 671.37 672.67 0.2% SM 03/16/21IO-8 494.37 493.87 -0.1% 523.67 523.17 -0.1% 670.37 672.67 0.3% SM 03/16/21IO-9IO-10 493.77 493.87 0.0% 524.27 523.17 -0.2% 671.27 672.67 0.2% SM 03/16/21IO-11 494.37 493.87 -0.1% 524.37 523.17 -0.2% 672.27 672.67 0.1% SM 03/16/21IO-12 493.77 493.87 0.0% 522.17 523.17 0.2% 671.47 672.67 0.2% SM 03/16/21IO-13SM 03/16/21IO-14 493.87 493.87 0.0% 524.37 523.17 -0.2% 670.87 672.67 0.3% SM 03/16/21IO-15 494.17 493.87 -0.1% 524.37 523.17 -0.2% 671.47 672.67 0.2% SM 03/16/21IO-16 494.37 493.87 -0.1% 524.37 523.17 -0.2% 671.07 672.67 0.2% SM 03/16/21IO-17 493.37 493.87 0.1% 522.17 670.97IO-18 494.17 493.87 -0.1% 524.37 523.17 -0.2% 671.27 672.67 0.2% SM 03/16/21IO-19 493.97 493.87 0.0% 524.77 523.17 -0.3% 672.97 672.67 0.0% SM 03/16/21Reference Thermocouple: Fluke S/N: 83450033 or S/N 90460057 traceable to the Untied States National Institute of Standards and Technology*Acceptable Deviation: 1.5%TechnicianDate PerformedID NumberIce Bath Ambient Hot Water BathDeviation* Deviation* Deviation*V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Initial Calibrations\Impinger Outlets\2021\2021 Init I.O. Cal.xlsx\2019
DOCUMENT TITLE Initial Sample Probe Calibration Form
Probe ID Date Technician
Is the Pitot Level and Perpindicular?Yes
Is There any Obstruction?No
Is the Pitot Damaged No
α1 (-10o = α1 = + 10o)1
α2 (-10o = α2 = + 10o)0
ß1 (-5o = ß1 = + 5o)1
ß2 (-5o = ß2 = + 5o)1
γ 1
Θ 0
z = A Tan γ (< 0.125")0.011
W = A Tan Θ (< 0.03125")0.0000
Dt (3/16 = Dt = 3/8")0.252
A 0.655
A/2Dt (1.05 = PA/Dt = 1.5)1.300
Source: Quality Assurance Handbook for Air Pollution Measurement
Systems: Volume III, Stationary Source-Specific Methods.
EPA/600/R-94/038c, September 30, 1994
Verification of "S" Type Pitot, Thermocouple and Nozzle Placement
Does X Exceed 0.75 inches?Yes
Does Y Exceed 3 inches?NA
Thermocouple Calibration
1 2 3 1 2 3 1 2 3Reference Temp 492 492 492 526 526 526 672 672 672
Thermocouple Temp 492 492 492 525 525 525 672 672 672
Difference (%)0.0 0.0 0.0 -0.2 -0.2 -0.2 0.0 0.0 0.0
Temperature values must be within 1.5% of reference temperature
I certify that the probe ID meets or exceeds all specifications, criteria and/or applicable design features and is herby assigned a pitot tube calibration factor CP of 0.84.
Certified By:Date:S. Waters 01/28/21
Ambient OR Boiling Water OR
S. Waters
P4-1/TC-7C
"S" Type Pitot Calibration
P4-1/TC-7C 01/28/21
Ice Bath OR
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\2021 Initial Probe Cal P4-1.xlsx\Initial
DOCUMENT TITLE
Initial Sample Probe Calibration Form
Probe ID Date Technician
Is the Pitot Level and Perpindicular?Yes
Is There any Obstruction?No
Is the Pitot Damaged No
a1 (-10o = a1 = + 10o)2
a2 (-10o = a2 = + 10o)1
ß1 (-5o = ß1 = + 5o)1
ß2 (-5o = ß2 = + 5o)1
g 1
Q 0
z = A Tan g (< 0.125")0.011
W = A Tan Q (< 0.03125")0.0000
Dt (3/16 = Dt = 3/8")0.251
A 0.650
A/2Dt (1.05 = PA/Dt = 1.5)1.295
Source: Quality Assurance Handbook for Air Pollution Measurement
Systems: Volume III, Stationary Source-Specific Methods.
EPA/600/R-94/038c, September 30, 1994
Verification of "S" Type Pitot, Thermocouple and Nozzle Placement
Does X Exceed 0.75 inches?Yes
Does Y Exceed 3 inches?NA
Thermocouple Calibration
1 2 3 1 2 3 1 2 3Reference Temp 492.3 492.3 492.3 533.4 533.4 533.4 671.5 671.5 671.5
Thermocouple Temp 492.9 492.8 492.8 532.7 532.6 532.7 673.1 673 673
Difference (%)0.1 0.1 0.1 -0.1 -0.1 -0.1 0.2 0.2 0.2
Temperature values must be within 1.5% of reference temperature
I certify that the probe ID meets or exceeds all specifications, criteria and/or applicable design features and is
herby assigned a pitot tube calibration factor CP of 0.84.
Certified By:Date:P. Grady 06/16/20
Ambient OR Boiling Water OR
P. Grady
P4-2/TC-5D
"S" Type Pitot Calibration
P4-2/TC-5D 06/16/20
Ice Bath OR
V:\Office-Ops\ENV\Div01\Source Testing\Equipment Calibration Data\Initial Calibrations\Probes and Pitots\2020 Initial Cals\4'\2020 Initial Probe Cal P4-2.xlsx\Initial

Post Test Equipment Calibration Data

DOCUMENT TITLE
POST TEST DRY GAS METER CALIBRATION
INITIAL FINAL AVG (Pbar)
DATE:03/17/21 METER BOX #:8 BAROMETRIC PRESSURE (in Hg):30.13 30.13 30.13
TECHNICIAN:S. Waters CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y DH@
1
2
3
AVG =
1 0.4961 22 782.817 789.520 6.703 65 69 69 69 69 69 10.00 1.1 6.7566 6.5255 0.966 -0.10 1.46
18 2 0.4961 22 789.520 796.215 6.695 65 69 68 69 69 68.75 10.00 1.1 6.7518 6.5255 0.966 -0.03 1.47
3 0.4961 22 796.215 802.896 6.681 65 68 68 69 69 68.5 10.00 1.1 6.7408 6.5255 0.968 0.13 1.47
AVG = 0.967
1
2
3
AVG =
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =
PRE-DETERMINED DRY GAS METER CALIBRATION FACTOR, Y =
Procedure:
1) Select three critical orifices to calibrate the dry gas meter which bracket the expected operating range.
2) Record barometric pressure before and after calibration procedure.
3) Run at tested vacuum (from Orifice Calibration Report), for a period of time
necessary to achieve a minimum total volume of 5 cubic feet.
4) Record readings in outlined boxes below, other columns are automatically calculated.
PERCENT DIFFERENCE =
0.967
0.975
-0.8
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\MB 8 Post Cal 03172021.xlsx\Sheet1
DOCUMENT TITLE
POST TEST DRY GAS METER CALIBRATION
INITIAL FINAL AVG (Pbar)
DATE:03/17/21 METER BOX #:10 BAROMETRIC PRESSURE (in Hg):30.05 30.05 30.05
TECHNICIAN:S. Milo CRITICAL ORIFICE SET SERIAL #:1393
K'TESTED TEMPERATURES °F ELAPSED Y % Diff
FACTOR VACUUM DGM READINGS (FT3)AMBIENT DGM INLET DGM OUTLET DGM TIME (MIN)DGM DH (1)(2)(3)to
ORIFICE #RUN #(AVG)(in Hg)INITIAL FINAL NET (Vm)INITIALFINALINITIALFINAL AVG q (in H2O)Vm (STD)Vcr (STD)Y Average Y DH@
1
2
3
AVG =
1 0.7131 19 796.328 805.802 9.474 67 68 69 68 68 68.25 10.00 2.7 9.5753 9.3372 0.975 0.04 1.76
26 2 0.7131 19 805.802 815.296 9.494 68 69 70 69 69 69.25 10.00 2.7 9.5774 9.3284 0.974 -0.08 1.76
3 0.7131 19 815.296 824.793 9.497 68 70 71 69 70 70 10.00 2.7 9.5668 9.3284 0.975 0.03 1.76
AVG = 0.975
1
2
3
AVG =
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y =
PRE-DETERMINED DRY GAS METER CALIBRATION FACTOR, Y =
PERCENT DIFFERENCE =
0.975
0.983
-0.8
C:\Stack\Projects\Chemours\Fayetteville\March 2021\PPA Report\App E\MB 10 Post Cal 03172021.xlsx\Sheet1