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HomeMy WebLinkAbout1201_Burke_KirkseyDrive_MSWLF_May21GW_FID1606516_20210831IIENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. E-mail: vburbach@jlabellapc.com Phone: (336) 323-0092 Facility name: Facility Address: Facility Permit # Burke Co. - Kirksey Dr. Landfill Kirksey Drive 12-01 Morganton, NC NC Landfill Rule: Actual sampling dates (e.g., (.0500 or. 1600) October 20-24, 2006) .0500 May 3-4, 2021 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring a Detection Monitoring ❑ Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach. Ph.D., P.G. Technical Consultant (336) 323-0092 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1. 2009) Revised 6/2009 -a Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal mc - �- �349 � �GqN NESS.�'.�°�. LaBeRa Powered by partnership. August 19, 2021 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Via Email: jaclynne.drummond@ncdenr.gov RE: May 2021 Semiannual Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2212740 Dear Ms. Drummond: Please find the attached May 2021 Semiannual Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the May 2021 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form and the laboratory EDD's. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide them upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure cc: Brian Tart, Mark Delehant, Burke County 12-D Oak Branch Drive Greensboro, NC 27407 I P (336) 323-0092 www.LabeLLapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 2868o 4 BURKE �Gngzpo K NTH CA Submitted by: LaBella Associates (Joyce Engineering) 12-D Oak Branch Drive Greensboro, NC 27407 (336) 323-00g2 NC License No. C-0782 LaBeRa Powered by partnership. MAY 2021 SEMIANNUAL WATER QUALITY MONITORING REPORT KIRKSEY DRIVE LANDFILL Permit No. 12-01 AUGUST 2021 PROJECT NO. 2212740 May 2021 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................................................. 1 1.1 Site Information................................................................................................................ 1 1.2 Site Geology........................................................................................................................1 1.3 Regulatory Status............................................................................................................... 2 2.0 FACILITY MONITORING PROGRAM................................................................................ 2 2.1 Groundwater Monitoring Program.................................................................................... 2 2.2 Surface Water Monitoring Program.................................................................................. 2 3.0 May 2021 SEMIANNUAL SAMPLING EVENT................................................................. 3 3.1 Field Work...........................................................................................................................3 3.2 Laboratory Analysis and Quality Control........................................................................... 4 4.0 HYDROGEOLOGY........................................................................................................... 4 5.0 DATA ANALYSIS.............................................................................................................. 5 5.1 Analytical Results and Comparison to Standards............................................................ 5 5.1.1 Groundwater............................................................................................................5 5.1.2 Surface Water.......................................................................................................... 6 7.0 REFERENCES.................................................................................................................7 Burke County - Kirksey Drive Landfill, Permit No. 12-01 La Bella Associates May 2021 Semiannual Water Quality Monitoring Report August 2021 May 2021 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 Groundwater Elevations (May 2021) Table 2 Hydraulic Gradients and Velocities (May 2021) Table 3 Detected Constituents (May 2021) Table 4 Exceedances of Standards (May 2021) Table 5 Field Parameters (May 2021) Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map (May 2021) Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of Inner Piedmont Belt rocks were mostly sedimentary (greywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 1 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Well MW-1 was damaged and has not been able to be sampled since June 2017. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (feet) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points (SMP-1, SMP-2, and SMP-3) comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply WS-IV. All surface water monitoring points are monitored semiannually for the NC Appendix I list of constituents plus 1,4-dioxane. Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 2 Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 May 2021 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On May 3-4, 2021, personnel from LaBella visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Monitoring well MW-1 is damaged and was not able to be monitored during this sampling event. This well should be evaluated for repair or replacement. Depth - to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the May 2021 monitoring event can be found in Table 1. Monitoring wells were purged using either disposable bailers, or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field data logs are included in Appendix 1. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a cooler. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the May 2021 monitoring event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity and recorded in the site log book. Immediately Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 3 after sample collection, the samples were placed on ice in a laboratory -provided cooler. Field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The May 2021 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory in good condition, properly preserved, at proper temperature, and within analysis hold times. The sampling data report was received from Pace Analytical Services on May 27, 2021. In addition to samples collected for compliance monitoring at the Kirksey Drive Landfill, a Field Blank was collected by LaBella personnel as part of the sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs only, and both were analyzed for 1,4-dioxane. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC2L), NC Interim Maximum Allowable Concentrations (IMACs), 15A NCAC 2B Surface Water Standards (NC2B), or NC In -stream Target Values (ISTV); and • Detections that are above historical levels. Review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report August 2021 4 Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in May 2021, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the May 2021 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.044 to 0.082, with an average of approximately 0.057. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = K1/ne. Where: V = average linear velocity; K = hydraulic conductivity; i = horizontal hydraulic gradient; and ne = effective porosity. The mean of hydraulic conductivities from slug -tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 262 to 492 feet/year, with an average flow velocity of approximately 341 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. 5.0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the May 2021 monitoring event are listed in Table 3. Results with quantified concentrations above Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 5 their respective NC21- or IMAC are presented in Table 4. Field parameter data from the May 2021 event are summarized in Table 5. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2), and historical groundwater field parameters can be found in Appendix 2 (Table A2-3). During the May 2021 monitoring event, the constituents detected at quantified concentrations above the MRL in the groundwater samples included: barium (MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, MW-6S); chromium (MW-5); cobalt (MW-2, MW-3S, MW-5); copper (MW-5); lead (MW-5); nickel (MW-2, MW-3D, MW-5); vanadium (MW-2, MW-4, MW-5); zinc (MW-4, MW-5);1,4-dichlorobenzene (MW-2, MW-3D, MW-3S); 2-butanone (MW-2); 4-methyl-2-pentanone (MW-2); acetone (MW-2); benzene (MW-2, MW-3S, MW-3D); chlorobenzene (MW-2, MW-3D, MW-3S); ethylbenzene (MW-2); toluene (MW-2); xylene (MW-2, MW-3S); 1,1-dichloroethene (MW-3D); cis-1,2-dichloroethene (MW-3D, MW-4); tetrachloroethene (MW-3D); trichloroethene (MW-3D); vinyl chloride (MW-3D); and 1,4-dioxane; (MW-2, MW-3S, MW-3D). The constituents detected at quantified concentrations in exceedance of their respective NC21- or IMAC during the May 2021 sampling event include: barium (MW-2); cobalt (MW-2, MW-3S, MW-5); vanadium (MW-2, MW-4, MW-5); benzene (MW-2, MW-3S, MW-3D); tetrachloroethene (MW-3D); trichloroethene (MW-3D); 1,4-dichlorobenzene (MW-2, MW-3S); 4-methyl-2-pentanone (MW-2); 1,4-dioxane (MW-2, MW-3S, MW-3D); and vinyl chloride (MW-3D). In general, these results are consistent with historical data for the site, except for cobalt in MW-5, which was a first-time exceedance (Appendix 2, Table A2-2). 5.1.2 Surface Water Constituents detected in the surface water during the May 2021 monitoring event are presented in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A2-4), and historical surface water field parameters can be found in Appendix 2 (Table A2-5). Barium and vanadium were the only constituents detected in any of the surface water samples during the May 2021 sampling event. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC2B Standards or ISTV for class WS-IV waters during this sampling event. 6.0 CONCLUSION The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 6 landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for November 2021. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, P. 119 RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. Burke County - Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2021 Semiannual Water Quality Monitoring Report. August 2021 7 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 Groundwater Elevations (May 2021) Hydraulic Gradients and Velocities (May 2021) Detected Constituents (May 2021) Exceedances of Standards (May 2021) Field Parameters (May 2021) TABLE 1: Groundwater Elevations (May 2021) Location TOC Elevation (Ft-AMSL) Depth to Groundwater (Ft-BTOC) Lithology Well Depth (Ft-BTOC) Groundwater Elevation (Ft-AMSL) MW-1 1119.82 --- Saprolite 35.65 --- MW-2 1077.23 25.61 Saprolite 45.70 1051.62 MW-3S 1022.76 5.55 Bedrock 26.69 1017.21 MW-3D 1021.90 0.00 Bedrock 78.40 1021.90 MW-4 1054.99 17.61 Saprolite 29.50 1037.38 MW-5 1137.43 32.35 Saprolite 49.80 1105.08 MW-6S 1065.00 9.65 Bedrock 25.00 1055.35 MW-6D 1065.00 11.33 Saprolite 60.00 1053.67 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level Water Levels measured May 3-4, 2021 --- = well damaged, not sampled. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 TABLE 2: Hydraulic Gradients and Velocities (May 2021) Water Levels Measured: May 3-4, 2021 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION GROUNDWATER ELEVATION (feet) HORIZONTAL GRADIENT ► HYDRAULIC CONDUCTIVITY K (feet/day) EFFECTIVE POROSITY n LINEAR VELOCITY V (feet/year) 1100 11 972 NW 0.0823 3.28E+00 0.20 492 1020 1080 12 1,112 NE 0.0450 3.28E+00 0.20 269 1030 1080 13 914 NE 0.0438 3.28E+00 0.20 262 1040 AVERAGE: 0.0570 AVERAGE: 341 Notes: The mean of K estimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1) . Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: Detected Constituents (May 2021) SAMPLE ID PARAMETER RESULT METHOD MDL MRL STANDARD SOURCE UNITS SAMPLE DATE Groundwater Antimony 3.0 J EPA 6010D 3 5 1 IMAC pg/L Barium 1190 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 95.4 EPA 6010D 3.6 5 1 IMAC pg/L Nickel 14.4 EPA 6010D 3.5 5 100 NC 2L pg/L Toluene 6.8 EPA 8260D 2.4 5 600 NC 2L pg/L Vanadium 7.3 EPA 6010D 3.9 5 0.3 IMAC pg/L 1,2-Dichlorobenzene 1.7 J EPA 8260D 1.7 5 20 NC 2L I pg/L 1,4-Dichlorobenzene 38.4 EPA 8260D 1.7 5 6 NC 2L pg/L MW-2 1,4-Dioxane (p-Dioxane) 187 EPA 8260D Mod. 4.3 10 3 NC 2L pg/L 5/3/2021 2-Butanone (MEK) 1190 EPA 8260D 19.8 25 4000 NC 2L pg/L 2-Hexanone 6.4 J EPA 8260D 2.4 25 40 IMAC pg/L 4-Methyl-2-pentanone (MIBK) 616 EPA 8260D 13.6 25 100 IMAC pg/L Acetone 1160 EPA 8260D 25.6 125 6000 NC 2L pg/L Benzene 9.7 EPA 8260D 1.7 5 1 NC 2L I pg/L Chlorobenzene 22.1 EPA 8260D 1.4 5 50 NC 2L pg/L Ethylbenzene 20.3 EPA 8260D 1.5 5 600 NC 2L pg/L Xylene (Total) 51.5 EPA 8260D 1.7 5 500 NC 2L pg/L Barium 201 EPA 6010D 3.5 5 700 NC 2L pg/L Nickel 26.9 EPA 6010D 3.5 5 100 NC 2L pg/L 1,1-Dichloroethane 5.8 EPA 8260D 0.37 1 6 NC 2L pg/L 1,2-Dichloropropane 0.63 J EPA 8260D 0.36 1 1 20 NC 2L pg/L 1,4-Dichlorobenzene 3.9 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 110 EPA 8260D Mod. 1.7 4 3 NC 2L pg/L MW-3D Benzene 1.6 EPA 8260D 0.34 1 1 NC 2L pg/L 5/4/2021 Chlorobenzene 8.7 EPA 8260D 0.28 1 50 NC 2L pg/L cis-1,2-Dichloroethene 21.3 EPA 8260D 0.38 1 70 NC 2L pg/L Tetrachloroethene 8.7 EPA 8260D 0.29 1 0.7 NC 2L pg/L Trichloroethene 6.2 EPA 8260D 0.38 1 1 3 NC 2L pg/L Vinyl chloride 1.1 EPA 8260D 0.39 1 0.03 NC 2L pg/L Barium 478 EPA 6010D 3.5 5 700 NC 2L pg/L Cobalt 13.7 EPA 6010D 3.6 5 1 IMAC pg/L 1,2-Dichlorobenzene 0.66 J EPA 8260D 0.34 1 20 NC 2L pg/L 1,4-Dichlorobenzene 10.4 EPA 8260D 0.33 1 6 NC 2L pg/L MW-3S 1,4-Dioxane (p-Dioxane) 41.5 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L 5/4/2021 Benzene 3.6 EPA 8260D 0.34 1 1 1 NC 2L pg/L Chlorobenzene 35.9 EPA 8260D 0.28 1 50 NC 2L pg/L Xylene (Total) 9.5 EPA 8260D 0.34 1 500 NC 2L pg/L Barium 91.2 EPA 6010D 3.5 5 700 NC 2L pg/L Thallium 0.058 J EPA 6020B 0.05 1 0.2 IMAC pg/L MW-4 Vanadium 7.9 EPA 6010D 3.9 5 0.3 IMAC pg/L 5/4/2021 Zinc 10.6 EPA 6010D 9.5 10 1000 NC 2L pg/L cis-1,2-Dichloroethene 2.1 EPA 8260D 0.38 1 70 NC 2L pg/L Barium 121 EPA 6010D 3.5 5 700 NC 2L pg/L Chromium 8.0 EPA 6010D 3.7 5 10 NC 2L pg/L Cobalt 8.7 EPA 6010D 3.6 5 1 IMAC pg/L Copper 6.2 EPA 6010D 4.3 5 1000 NC 2L pg/L MW-5 Lead 10.4 EPA 6010D 4.5 5 15 NC 2L pg/L 5/4/2021 Nickel 5.6 EPA 6010D 3.5 5 100 NC 2L pg/L Thallium 0.67 J EPA 6020B 0.05 1 1 0.2 IMAC I pg/L Vanadium 19.4 EPA 6010D 3.9 5 0.3 IMAC pg/L Zinc 34.6 EPA 6010D 9.5 10 1000 NC 2L pg/L MW-6D Barium 13.4 EPA 6010D 3.5 5 700 NC 2L pg/L 5/3/2021 MW-6S Barium 26.5 EPA 6010D 3.5 5 700 NC 2L pg/L 5/4/2021 Surface Water Barium 34.1 EPA 6010D 3.5 5 1000 NC 02B pg/L SW-1 Vanadium 5.4 EPA 6010D 3.9 5 NS pg/L 5/4/2021 2 Barium 38.6 EPA 6010D 3.5 5 1000 NC 02B pg/L SW Vanadium 6.4 EPA 6010D 3.9 5 NS pg/L 5/4/2021 Barium 36.1 EPA 6010D 3.5 5 1000 NC 02B pg/L SW-3 Vanadium 5.7 EPA 6010D 3.9 5 NS pg/L 5/4/2021 Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit J = Estimated concentration below the MRL B = Blank-qualilfied data due to detections in equipment, trip, or method blanks. NO = Not detected above the MDL Bold = quantified detections above the Standard NC2L = NC Groundwater Standard frme 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) NC2B = NC Surface Water Standard from15A NCAC 2B (Note that NC213 for some metals is hardness -dependant.) ISTV = NC In -Stream Target Values NS = No Standard Burke Co. - Kirksey Dr. Landfill LaBella Associates Permit # 12-01 TABLE 4: Exceedances of Standards (May 2021) SAMPLE ID-7- PARAMETER RESULT METHOD MDL MRL STANDARD SOURCE UNITS SAMPLE DATE Groundwater MW-2 Barium 1190 EPA 6010D 3.5 5 700 NC 2L pg/L 5/3/2021 Cobalt 95.4 EPA 6010D 3.6 5 1 IMAC pg/L Vanadium 7.3 EPA 6010D 3.9 5 0.3 IMAC pg/L 1,4-Dichlorobenzene 38.4 EPA 8260D 1.7 5 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 187 EPA 8260D Mod. 4.3 10 3 NC 2L pg/L 4-Methyl-2-pentanone (MIBK) 616 EPA 8260D 13.6 25 100 IMAC pg/L Benzene 9.7 EPA 8260D 1.7 5 1 NC 2L pg/L MW-3D 1,4-Dioxane (p-Dioxane) 110 EPA 8260D Mod. 1.7 4 3 NC 2L pg/L 5/4/2021 Benzene 1.6 EPA 8260D 0.34 1 1 NC 2L pg/L Tetrachloroethene 8.7 EPA 8260D 0.29 1 0.7 NC 2L pg/L Trichloroethene 6.2 EPA 8260D 0.38 1 3 NC 2L pg/L Vinyl chloride 1.1 EPA 8260D 0.39 1 0.03 NC 2L pg/L MW-3S Cobalt 13.7 EPA 6010D 3.6 5 1 IMAC pg/L 5/4/2021 1,4-Dichlorobenzene 10.4 EPA 8260D 0.33 1 6 NC 2L pg/L 1,4-Dioxane (p-Dioxane) 41.5 EPA 8260D Mod. 0.86 2 3 NC 2L pg/L Benzene 3.6 EPA 8260D 0.34 1 1 NC 2L pg/L MW-4 Vanadium 7.9 EPA 6010D 3.9 5 0.3 IMAC pg/L 5/4/2021 MW-5 Cobalt 8.7 EPA 6010D 3.6 5 1 IMAC pg/L 5/4/2021 Vanadium 19.4 EPA 6010D 3.9 5 0.3 IMAC L Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit J = Estimated concentration below the MRL B = Blank-qualilfied data due to detections in equipment, trip, or method blanks. NC2L = NC Groundwater Standard frme 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) NC2B = NC Surface Water Standard from15A NCAC 2B (Note that NC213 for some metals is hardness -dependant.) ISTV = NC In -Stream Target Values Burke Co. Kirksey Dr. Landfill Permit # 12-01 LaBella Associates TABLE 5: Field Parameters (May 2021) Parameter Units Sample Date GW Upgradient Groundwater Downgradient Surface Water MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D SW-1 SW-2 SW-3 Well Depth Ft. 5/4/2021 NS 45.70 26.69 78.40 29.50 49.80 25.00 60.00 -- pH S.U. 5/4/2021 NS 5.84 5.96 5.96 6.45 7.22 6.32 5.76 6.93 6.62 6.76 Temperature °C 5/4/2021 NS 16.9 14.9 76.4 15.6 16.2 13.8 15.6 16.2 16.2 16.5 Conductivity PS/cm 5/4/2021 NS 1506 593 632 67.0 43.9 45.2 74.2 61.1 54.0 79.8 Dissolved Oxygen mg/L 5/4/2021 NS 1.37 1.97 1.22 7.06 10.32 9.07 0.98 9.35 8.79 7.62 Oxidation Reduction Potential my 5/4/2021 NS 40.4 60.8 194.8 98.3 164.7 127.5 109.6 30.1 43.9 4.7 Turbidity NTU 5/4/2021 NS 8.74 8.0 4.02 30.10 91.6 20.40 5.25 47.40 77.90 47.40 Static Water Level Ft. 5/4/2021 NS 25.61 1 5.55 1 0.00 1 17.61 1 32.35 1 9.65 1 11.33 - - - Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units Ft = feet NS = Not sampled due to broken casing Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map ------ tj 16V 1000 CP APPROXIMATE LOCATION OF PROPERTY LINE i---------- rx X, IF lef' 44,0 .10410 ISSUED FOR: 03 LaBeRa GROUNDWATER MONITORING REPORT Powered by partnership. DRAWING NAME: DRAWN BY: DATE: PROJECT NO.: SITE LOCATION MAP RVVH 02/27/19 2192621 2211 WEST MEADOW'VIEW ROAD GREENSBORO, N.C. 27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: KIRKSEY DRIVE LANDFILL 1 labellapc.com (D 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\Pwgs\Drawhgs—rui­nt\8URKE\GW EVENT MAPS\, SITE LOCATION MAP KIRKSEY DRIVE 2020.4wg DRAWING Drawing 1 Groundwater Potentiometric Surface Map (May 2021) LaBella Powered by partnership. 2211 WEST NSBORO, NC 27407 SUITE 101 GRE I I \ \ C \ (336) 323-0092 label lapc.com LIMITS OF WASTE (TYP) — — — — — — LIMITS OF WASTE ��� �/ / e-�� \ 'M 2 \ \ \ F— T —*40— �i�/ 051.62 \ L �� MW 3D MW-3S / _— \MPSMP-3 0 021.90 17.2� ©2021 LaBelle Associates 104 0 KIRKSEY DRIVE / \ \ I LANDFILL BURKE COUNTY, NORTH CAROLINA woo- 501 MNN6S 1055.35 105SSS 67 M1- \ / - // / / \ GRAPHIC SCALE / r`1 i W O8 7700 --0 XO�p / J 1060 0 150 510300 600 (FEET) NOTES LEGEND 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. NO DATE DESCRIPTION R,sai es 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING ROAD 2• GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. PROJECT NUMBER: 2192621.00 EXISTING 20' TOPOGRAPHIC CONTOUR APPROXIMATE LIMITS OF WASTE 3. STATIC WATER LEVELS WERE MEASURED ON MAY 3-4, 2021. DRAWN BY RH REVIEWED BY: 1 080 — — — — — GROUNDWATER SURFACE CONTOUR [FEET CENTERLINE OF STREAM GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION 4. EW ISSUED FOR GROUNDWATER REPORT DATE osmizl BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, ABOVE MEAN SEA LEVEL (AMSL)] - MW-5 COMPLIANCE WELL LOCATION AND TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. DRAWING NAME: IDENTIFICATION WITH STATIC WATER — — PROPERTY LINE ELEV LEVEL ELEVATION (FEET AMSL) GROUNDWATER FLOW PATHWAY USED TO FLOW PATH LENGTH SURFACE MONITORING POINT LOCATION PERMIT N0.12-01 CALCULATE HYDRAULIC GRADIENT O SW-2 AND IDENTIFICATION GROUNDWATER POTENTIOMETRIC SEGMENT USED FOR GRADIENT CALCULATION Q LF OMAY SURFACE MAP 3-4, 2021 1 1,1 Q 112 LF DRAWING NUMBER'. 13 914 LF 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data Appendix 1 Field Logs and Laboratory Analytical Reports DATE: SLaI� �� LaBella GROUNDWATER SAMPLING LOG Project Name: ��W V �� Project No. /Task No.: ��3 Go Well ID:Sampler(s): Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl Depth to Wall 2 inches • 401 feet feet O feet [DTB-DTW] _-gallons gallons —l-gallons gallons Gallons Time Temp (°C) pH Cond. (US/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials 1�S-4- 1.61 ter, S i�_p , 3 fa, - lto--k- Mo <-,�q 3,tq- 1Nq 15,-q a . a 3:� �' Date of sample: Before Sampling Lel J I M-AA�A �a I I 1 11 Comments(weather conditions, odor, color, 'silt, /etc.): . , yy__ I& ►�,i ', -4 s - Signature: k i , Date: S1-:'OL / QA/QC Sign Off: Date:f�71 �� Q_. LaBetLa DATE: 151 M e1- GROUND WATER SAMPLING LOG Project Name: %` uSf t.� Project No. /Task No.: 02300, 00/co Well ID: KAW - 35 Sampler(s): 4AAt441 4'C"Wy&��t Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with: 2 inches _ feet °�'�• �� feet Oil • I N feet [DTB-DTW] 3 ° gallons / gallons = p� gallons lid . gallons Other: Other: Depth to Water before Sampling: s feet Gallons Time Temp (°C) pH Cond. (us/cm) Dis.02 mg/L ORP my Turb. - (ntu) Initials Iq I,5,10 6,as &q+ J.mot lv�y 3r V 23 IS• � �. a4 \p�J�l IL W P4, 3 q-1i7 tom. cb-a 1q tq �, aq (��s 1� u,s I& s )210, �- Lo - go -6q ls'q Date of sample: S" y Before Sampling �( (l.��G� S 1�0 �Q �,q�- �Q� g�CSv Comments (weather conditions, odor, color, silt, etc.): Signature: k. 4,, Iw Date: �l�l QA/QC Sign Off: EI. U441v____ Date: � '3 � LaBelLa DATE: GROUND WATER SAMPLING LOG Project Name: hi tot' � Project No. /Task No.:,) 6-0/0� Well ID: Sampler(s): itJhr�C Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl 2 inches feet 7B. LAD feet 48*40 feet [DTB-DTW] gallons gallons gallons 3B, 31 gallons Depth to Water before Sampling: ' feet Gallons Time Temp (°C) pH Cond. (US/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials © 1 110A J�( & 1Y L. t9q- A33.1 &c, k-i-- 12,Iq- �3 lc�• s� S�- Coat 3,111 PaW.s (a44Y S_q 632- u, cad- PM-3 -3- 312> gco 1&.N <-.qU S y 1, ga- �qe , b�f, oa- Date of sample: Before Sampling C Comments (weather conditions, odor, color, silt, etc.): � Signature: k Date: QA/QC Sign Off: Laz Lr Date: � � � La Bella DATE: GROUND WATER SAMPLING LOG Project Name: ba"- ki (VsN Project No. /Task No.: -2a023 D ()e0_o /o a Well ID: " Sampler(s): K'f4 � lee""Wkikw— I Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): — Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches F+ W feet R� feet l� feet [DTB-DTW] gallons gallons RJR gallons S gallons Depth to Water before Sampling: 06AQ) feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials sty s� lay-� q •a3 �u sv,a- ka- ) �u3 � Q>(o V�;_• O' 95. igL f ' i4S_, 40 G, 0 9- 0%0 S'- 6'qq a 5, �d�-- Date of sample:• Before Sampling Comments (weather conditions, odor, color, silt, etc.): ,ww � bo�� Signature: Date: QA/QC Sign Off: Date: DATE: S3 a" LaBetLa GROUND WATER SAMPLING LOG Project Name: ffiAtL ki r k5&Project No. /Task No.:,2,2W300.001p.L_) Well ID:Sampler(s): K`T.tc -0 Lc it Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: For THREE Well Volumes: Actual Amount Purged, Purged with: Sampled with: Depth to Water before WCT X 0.163 WCT X 0.653 WV X 3 wiled: 2 inches Z.35- feet feet �S feet [DTB-DTW] = oh. c3y gallons pling: 32iy-+ feet gallons gallons gallons Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials O �y�l lam. s: 3 l 3 !�-t, � a�[), + 1(0,1 ke Li2, N S 2-2- PS-, 8 1-q T 10A r GOO q,1 I !�- 0 S 0 qt s a�-q,R Date of sample: Before Sampling —402 �. 7)�. Lf3A 10.2z I ,::T cib (p Comments (weather conditions, odor, color, silt, etc.): Signature:V.Date: QA/QC Sign Off: �� Date: 0..-, LaBe[La DATE: GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: - a3C0oop Well ID: KAW- Sampler(s): _k'�4q Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches q, ( feet feet feet [DTB-DTW] _ gallons _ gallons _ s gallons - S gallons Depth to Water before Sampling: 7-7?7 feet Gallons Time Temp (°C) pH Cond. (US/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials 0 1q,-3 5-1i�Z 4u, / /au, a- 3 Q.!6 ss1-,6 lqq10 +_sa qj- Date of sample: Before Sampling js' 3. t .Z L.l� 9� �- %o2t Comments (weather conditions, odor, color, silt, etc.): -- �4Q's Perk,- Signature: Date: IS- /P-6 .0-'l QA/QC Sign Off: _ (►�A/r� Date: �/ �r DATE: � � L� f3�ll� GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: �0300- 00�C`f2 Well ID: yv, CO'Sampler(s): Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl 2 inches j f ,?z -feet feet 0- feet [DTB-DTW] gallons -gallons gallons P13,4' gallons Depth to Water before Sampling: -- —T feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mWL ORP my Turb. (ntu) Initials �s.Q.> (�_,U Date of sample: Before Sampling 5, �¢nA JalC Comments (weather conditions, odor, color, silt, a c.): ft `� IQ Signature: W- t4 " Dater / QA/QC Sign Off: Date:��7��� P.-. LaBe La DATE: 5-Nk, LEACHATE MONITORING LOG Project Name: VVJ41C, kJAAYJ Project/Task No.: aka d93 00` 00A0 Sample Point ID:, c -4 Sampler(s): •Q-SOV I e'. G� Location: U psfiYCAgvL TVXVt Field Parameters: Time of Sampling: S pH: q 3 Temperature: rr(°C) Conductivity: l2 (US/cm) Turbidity: �/j�-� (ntu) Dissolved Oxygen G •r3� (mg/L) Oxidation -Reduction Potential 30A (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): ummary/Sketch of Sam ling Location � v1cAge. Signature: k. CzAzd_ QA/QC Sign Off: flj3�&eluw 'y/,kobn Date: , Date: '6-PI DATE: J P,..-. LaBe La ,l J� LEACHATE MONITORING LOG Project Name: �Vilt—)ctI*Sr4 Project/Task No.: Opt 0;pool), 0v10Q Sample Point ID: Sw'g­ Sampler(s): k,, &+c — 4&W 6 Location: UipAt h 6- �W-3 ha&v- �AW ­R-QaD Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential to, &3�- 6504i!EK ( o C) SA V (US/cm) -TI-4q (ntu) (m€`✓L) (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): 40`s Reu n . ��4'Mrw ('21 tA -Aar Signature: R QA/QC Sign Off: Summary/Sketch of Sampling Location ZOO) .5-/ >0 A*-1 Date: Vj7/Q DATE:571 �'L LaBetta LEACHATE MONITORING LOG Project Name: Vi V j! Project/Task No.: �290QQO, 00/02 Sample Point ID:A Sw�Sampler(s):_ k.j"f-Ir/�! Location:. _ _ _ WjY ]�I/�Ul� __3 !+ 3D Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential b•q'lco Ito T (0 C) 7q, 5 (US/cm) LIT.Y (ntu) q,4- (mg/L) (mv) mple Description (weather conditions, odor, color, silt, etc.): Summary/Sketch o on 00/i W3 :4 �D Signature:_ k • aca� Date: -o-PoL�( QA/QC Sign Off: L Date: VJ 121 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 27, 2021 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on May 05, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, /7j"4w' Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Kandice Estes, Labella Associates Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Lab ID Sample ID Matrix Date Collected Date Received 92536878001 1201-MW2 Water 05/03/2117:12 05/05/21 11:00 92536878002 1201-MW3S Water 05/04/21 08:34 05/05/21 11:00 92536878003 1201-MW3D Water 05/04/2108:10 05/05/21 11:00 92536878004 1201-MW4 Water 05/04/21 09:25 05/05/21 11:00 92536878005 1201-MW5 Water 05/04/21 07:02 05/05/21 11:00 92536878006 1201-MW6S Water 05/04/21 09:35 05/05/21 11:00 92536878007 1201-MW6D Water 05/03/2115:58 05/05/21 11:00 92536878008 1201-SW1 Water 05/04/2109:15 05/05/21 11:00 92536878009 1201-SW2 Water 05/04/21 08:55 05/05/21 11:00 92536878010 1201-SW3 Water 05/04/2108:47 05/05/21 11:00 92536878011 1201-Field Blank Water 05/04/21 09:40 05/05/21 11:00 92536878012 1201-Trip Blank Water 05/04/21 09:40 05/05/21 11:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co - Kirksey Drive LF 92536878 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92536878001 1201-MW2 EPA 6010D KQ, SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D PM1 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878002 1201-MW3S EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878003 1201-MW31) EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878004 1201-MW4 EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878005 1201-MW5 EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878006 1201-MW6S EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878007 1201-MW6D EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878008 1201-SW1 EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878009 1201-SW2 EPA 6010D SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878010 1201-SW3 EPA 6010D KQ, SH1 14 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 6020E CRW 1 PASI-A EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878011 1201-Field Blank EPA 6010D KQ, SH1 14 PASI-A EPA 6020E CRW 1 PASI-A EPA 8260D PM1 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92536878012 1201-Trip Blank EPA 8260D BSH 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 92536878001 1201-MW2 EPA 6010D Antimony 3.OJ ug/L 5.0 05/20/21 08:02 EPA 6010D Barium 1190 ug/L 5.0 05/20/21 08:02 EPA 6010D Cobalt 95.4 ug/L 5.0 05/20/21 08:02 EPA 6010D Nickel 14.4 ug/L 5.0 05/20/21 08:02 EPA 6010D Vanadium 7.3 ug/L 5.0 05/20/21 08:02 EPA 8260D Acetone 1160 ug/L 125 05/10/21 18:08 EPA 8260D Benzene 9.7 ug/L 5.0 05/10/21 18:08 EPA 8260D 2-Butanone (MEK) 1190 ug/L 25.0 05/10/21 18:08 EPA 8260D Chlorobenzene 22.1 ug/L 5.0 05/10/21 18:08 EPA 8260D 1,2-Dichlorobenzene 1.7J ug/L 5.0 05/10/21 18:08 EPA 8260D 1,4-Dichlorobenzene 38.4 ug/L 5.0 05/10/21 18:08 EPA 8260D Ethylbenzene 20.3 ug/L 5.0 05/10/21 18:08 EPA 8260D 2-Hexanone 6AJ ug/L 25.0 05/10/21 18:08 EPA 8260D 4-Methyl-2-pentanone (MIBK) 616 ug/L 25.0 05/10/21 18:08 EPA 8260D Toluene 6.8 ug/L 5.0 05/10/21 18:08 EPA 8260D Xylene (Total) 51.5 ug/L 5.0 05/10/21 18:08 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 187 ug/L 10.0 05/05/21 17:48 92536878002 1201-MW3S EPA 6010D Barium 478 ug/L 5.0 05/20/21 08:06 EPA 6010D Cobalt 13.7 ug/L 5.0 05/20/21 08:06 EPA 8260D Benzene 3.6 ug/L 1.0 05/07/21 06:12 EPA 8260D Chlorobenzene 35.9 ug/L 1.0 05/07/21 06:12 EPA 8260D 1,2-Dichlorobenzene 0.66J ug/L 1.0 05/07/21 06:12 EPA 8260D 1,4-Dichlorobenzene 10.4 ug/L 1.0 05/07/21 06:12 EPA 8260D Xylene (Total) 9.5 ug/L 1.0 05/07/21 06:12 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 41.5 ug/L 2.0 05/05/21 17:29 92536878003 1201-MW3D EPA 6010D Barium 201 ug/L 5.0 05/20/21 08:09 EPA 6010D Nickel 26.9 ug/L 5.0 05/20/21 08:09 EPA 8260D Benzene 1.6 ug/L 1.0 05/07/21 05:54 EPA 8260D Chlorobenzene 8.7 ug/L 1.0 05/07/21 05:54 EPA 8260D 1,4-Dichlorobenzene 3.9 ug/L 1.0 05/07/21 05:54 EPA 8260D 1,1-Dichloroethane 5.8 ug/L 1.0 05/07/21 05:54 EPA 8260D cis-1,2-Dichloroethene 21.3 ug/L 1.0 05/07/21 05:54 EPA 8260D 1,2-Dichloropropane 0.63J ug/L 1.0 05/07/21 05:54 EPA 8260D Tetrachloroethene 8.7 ug/L 1.0 05/07/21 05:54 EPA 8260D Trichloroethene 6.2 ug/L 1.0 05/07/21 05:54 EPA 8260D Vinyl chloride 1.1 ug/L 1.0 05/07/21 05:54 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 110 ug/L 4.0 05/05/21 18:06 92536878004 1201-MW4 EPA 6010D Barium 91.2 ug/L 5.0 05/20/21 08:12 EPA 6010D Vanadium 7.9 ug/L 5.0 05/20/21 08:12 EPA 6010D Zinc 10.6 ug/L 10.0 05/20/21 08:12 EPA 6020B Thallium 0.058J ug/L 1.0 05/24/21 23:43 EPA 8260D cis-1,2-Dichloroethene 2.1 ug/L 1.0 05/07/2105:36 REPORT OF LABORATORY ANALYSIS M1 M1 Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co - Kirksey Drive LF 92536878 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92536878005 1201-MW5 EPA 601 OD Barium 121 ug/L 5.0 05/20/21 08:15 EPA 601 OD Chromium 8.0 ug/L 5.0 05/20/21 08:15 EPA 601 OD Cobalt 8.7 ug/L 5.0 05/20/21 08:15 EPA 601 OD Copper 6.2 ug/L 5.0 05/20/21 08:15 EPA 601 OD Lead 10.4 ug/L 5.0 05/20/21 08:15 EPA 601 OD Nickel 5.6 ug/L 5.0 05/20/21 08:15 EPA 601 OD Vanadium 19.4 ug/L 5.0 05/20/21 08:15 EPA 601 OD Zinc 34.6 ug/L 10.0 05/20/21 08:15 EPA 6020B Thallium 0.67J ug/L 1.0 05/24/21 23:48 92536878006 1201-MW6S EPA 601 OD Barium 26.5 ug/L 5.0 05/20/21 08:19 92536878007 1201-MW6D EPA 601 OD Barium 13.4 ug/L 5.0 05/20/21 08:22 92536878008 1201-SW1 EPA 601 OD Barium 34.1 ug/L 5.0 05/20/21 08:25 EPA 601 OD Vanadium 5.4 ug/L 5.0 05/20/21 08:25 92536878009 1201-SW2 EPA 601 OD Barium 38.6 ug/L 5.0 05/20/21 08:28 EPA 601 OD Vanadium 6.4 ug/L 5.0 05/20/21 08:28 92536878010 1201-SW3 EPA 601 OD Barium 36.1 ug/L 5.0 05/20/21 08:38 EPA 601 OD Vanadium 5.7 ug/L 5.0 05/20/21 08:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW2 Lab ID: 92536878001 Collected: 05/03/21 17:12 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony 3.OJ ug/L 5.0 3.0 1 05/19/21 11:44 05/20/2108:02 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/21 11:44 05/20/2108:02 7440-38-2 Barium 1190 ug/L 5.0 3.5 1 05/19/21 11:44 05/20/2108:02 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/21 11:44 05/20/2108:02 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/21 11:44 05/20/2108:02 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/21 11:44 05/20/2108:02 7440-47-3 Cobalt 95.4 ug/L 5.0 3.6 1 05/19/21 11:44 05/20/2108:02 7440-48-4 Copper ND ug/L 25.0 21.3 5 05/19/21 11:44 05/20/2112:51 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/21 11:44 05/20/2108:02 7439-92-1 Nickel 14.4 ug/L 5.0 3.5 1 05/19/21 11:44 05/20/2108:02 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/21 11:44 05/20/2108:02 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/21 11:44 05/20/2108:02 7440-22-4 Vanadium 7.3 ug/L 5.0 3.9 1 05/19/21 11:44 05/20/2108:02 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/21 11:44 05/20/2108:02 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:01 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 1160 ug/L 125 25.6 5 05/10/21 18:08 67-64-1 M1 Acrylonitrile ND ug/L 50.0 9.2 5 05/10/21 18:08 107-13-1 Benzene 9.7 ug/L 5.0 1.7 5 05/10/21 18:08 71-43-2 Bromochloromethane ND ug/L 5.0 2.3 5 05/10/21 18:08 74-97-5 Bromodichloromethane ND ug/L 5.0 1.5 5 05/10/21 18:08 75-27-4 Bromoform ND ug/L 5.0 1.7 5 05/10/21 18:08 75-25-2 Bromomethane ND ug/L 10.0 8.3 5 05/10/21 18:08 74-83-9 IK 2-Butanone (MEK) 1190 ug/L 25.0 19.8 5 05/10/21 18:08 78-93-3 M1 Carbon disulfide ND ug/L 10.0 3.6 5 05/10/21 18:08 75-15-0 Carbon tetrachloride ND ug/L 5.0 1.7 5 05/10/21 18:08 56-23-5 Chlorobenzene 22.1 ug/L 5.0 1.4 5 05/10/21 18:08 108-90-7 Chloroethane ND ug/L 5.0 3.2 5 05/10/21 18:08 75-00-3 Chloroform ND ug/L 25.0 7.8 5 05/10/21 18:08 67-66-3 Chloromethane ND ug/L 5.0 2.7 5 05/10/21 18:08 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 10.0 1.7 5 05/10/21 18:08 96-12-8 Dibromochloromethane ND ug/L 5.0 1.8 5 05/10/21 18:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1.4 5 05/10/21 18:08 106-93-4 Dibromomethane ND ug/L 5.0 2.0 5 05/10/21 18:08 74-95-3 1,2-Dichlorobenzene 1.7J ug/L 5.0 1.7 5 05/10/21 18:08 95-50-1 1,4-Dichlorobenzene 38.4 ug/L 5.0 1.7 5 05/10/21 18:08 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 5.0 2.8 5 05/10/21 18:08 110-57-6 1,1-Dichloroethane ND ug/L 5.0 1.8 5 05/10/21 18:08 75-34-3 1,2-Dichloroethane ND ug/L 5.0 1.6 5 05/10/21 18:08 107-06-2 1,1-Dichloroethene ND ug/L 5.0 1.7 5 05/10/21 18:08 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW2 Lab ID: 92536878001 Collected: 05/03/21 17:12 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 1.9 5 05/10/21 18:08 156-59-2 ND ug/L 5.0 2.0 5 05/10/21 18:08 156-60-5 ND ug/L 5.0 1.8 5 05/10/21 18:08 78-87-5 ND ug/L 5.0 1.8 5 05/10/21 18:08 10061-01-5 ND ug/L 5.0 1.8 5 05/10/21 18:08 10061-02-6 20.3 ug/L 5.0 1.5 5 05/10/21 18:08 100-41-4 6.4J ug/L 25.0 2.4 5 05/10/21 18:08 591-78-6 ND ug/L 100 48.6 5 05/10/21 18:08 74-88-4 ND ug/L 25.0 9.8 5 05/10/21 18:08 75-09-2 616 ug/L 25.0 13.6 5 05/10/21 18:08 108-10-1 ND ug/L 5.0 1.5 5 05/10/21 18:08 100-42-5 ND ug/L 5.0 1.6 5 05/10/21 18:08 630-20-6 ND ug/L 5.0 1.1 5 05/10/21 18:08 79-34-5 ND ug/L 5.0 1.5 5 05/10/21 18:08 127-18-4 6.8 ug/L 5.0 2.4 5 05/10/21 18:08 108-88-3 ND ug/L 5.0 1.7 5 05/10/21 18:08 71-55-6 ND ug/L 5.0 1.6 5 05/10/21 18:08 79-00-5 ND ug/L 5.0 1.9 5 05/10/21 18:08 79-01-6 ND ug/L 5.0 1.5 5 05/10/21 18:08 75-69-4 ND ug/L 5.0 1.3 5 05/10/21 18:08 96-18-4 ND ug/L 10.0 6.6 5 05/10/21 18:08 108-05-4 ND ug/L 5.0 1.9 5 05/10/21 18:08 75-01-4 51.5 ug/L 5.0 1.7 5 05/10/21 18:08 1330-20-7 99 % 70-130 5 05/10/21 18:08 460-00-4 101 % 70-130 5 05/10/21 18:08 17060-07-0 101 % 70-130 5 05/10/21 18:08 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 187 ug/L 10.0 4.3 5 05/05/2117:48 123-91-1 90 % 70-130 5 05/05/2117:48 17060-07-0 107 % 66-133 5 05/05/21 17:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW3S Lab ID: 92536878002 Collected: 05/04/21 08:34 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:06 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:06 7440-38-2 Barium 478 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:06 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:06 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:06 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:06 7440-47-3 Cobalt 13.7 ug/L 5.0 3.6 1 05/19/21 11:44 05/20/2108:06 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:06 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:06 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:06 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:06 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:06 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/19/2111:44 05/20/2108:06 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2108:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:24 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 06:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 06:12 107-13-1 Benzene 3.6 ug/L 1.0 0.34 1 05/07/21 06:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 06:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 06:12 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 06:12 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 06:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 06:12 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 06:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 06:12 56-23-5 Chlorobenzene 35.9 ug/L 1.0 0.28 1 05/07/21 06:12 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 06:12 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 06:12 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 06:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 06:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 06:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 06:12 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 06:12 74-95-3 1,2-Dichlorobenzene 0.66J ug/L 1.0 0.34 1 05/07/21 06:12 95-50-1 1,4-Dichlorobenzene 10.4 ug/L 1.0 0.33 1 05/07/21 06:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 06:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 06:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 06:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 06:12 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW3S Lab ID: 92536878002 Collected: 05/04/21 08:34 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 06:12 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 06:12 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 06:12 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 06:12 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 06:12 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 06:12 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 06:12 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 06:12 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 06:12 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 06:12 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 06:12 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 06:12 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 06:12 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 06:12 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 06:12 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 06:12 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 06:12 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 06:12 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 06:12 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 06:12 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 06:12 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 06:12 75-01-4 9.5 ug/L 1.0 0.34 1 05/07/21 06:12 1330-20-7 97 % 70-130 1 05/07/21 06:12 460-00-4 100 % 70-130 1 05/07/21 06:12 17060-07-0 100 % 70-130 1 05/07/21 06:12 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 41.5 ug/L 2.0 0.86 1 05/05/2117:29 123-91-1 87 % 70-130 1 05/05/2117:29 17060-07-0 108 % 66-133 1 05/05/21 17:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW3D Lab ID: 92536878003 Collected: 05/04/21 08:10 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:09 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:09 7440-38-2 Barium 201 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:09 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:09 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:09 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:09 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:09 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:09 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:09 7439-92-1 Nickel 26.9 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:09 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:09 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:09 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/19/2111:44 05/20/2108:09 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2108:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:29 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 05:54 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 05:54 107-13-1 Benzene 1.6 ug/L 1.0 0.34 1 05/07/21 05:54 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 05:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 05:54 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 05:54 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 05:54 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 05:54 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 05:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 05:54 56-23-5 Chlorobenzene 8.7 ug/L 1.0 0.28 1 05/07/21 05:54 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 05:54 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 05:54 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 05:54 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 05:54 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 05:54 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 05:54 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 05:54 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 05:54 95-50-1 1,4-Dichlorobenzene 3.9 ug/L 1.0 0.33 1 05/07/21 05:54 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 05:54 110-57-6 1,1-Dichloroethane 5.8 ug/L 1.0 0.37 1 05/07/21 05:54 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 05:54 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 05:54 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW3D Lab ID: 92536878003 Collected: 05/04/21 08:10 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 21.3 ug/L 1.0 0.38 1 05/07/21 05:54 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 05:54 156-60-5 0.63J ug/L 1.0 0.36 1 05/07/21 05:54 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 05:54 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 05:54 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 05:54 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 05:54 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 05:54 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 05:54 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 05:54 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 05:54 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 05:54 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 05:54 79-34-5 8.7 ug/L 1.0 0.29 1 05/07/21 05:54 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 05:54 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 05:54 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 05:54 79-00-5 6.2 ug/L 1.0 0.38 1 05/07/21 05:54 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 05:54 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 05:54 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 05:54 108-05-4 1.1 ug/L 1.0 0.39 1 05/07/21 05:54 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 05:54 1330-20-7 99 % 70-130 1 05/07/21 05:54 460-00-4 102 % 70-130 1 05/07/21 05:54 17060-07-0 100 % 70-130 1 05/07/21 05:54 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 110 ug/L 4.0 1.7 2 05/05/2118:06 123-91-1 94 % 70-130 2 05/05/2118:06 17060-07-0 108 % 66-133 2 05/05/21 18:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW4 Lab ID: 92536878004 Collected: 05/04/21 09:25 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/21 11:44 05/20/2108:12 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/21 11:44 05/20/2108:12 7440-38-2 Barium 91.2 ug/L 5.0 3.5 1 05/19/21 11:44 05/20/2108:12 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/21 11:44 05/20/2108:12 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/21 11:44 05/20/2108:12 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/21 11:44 05/20/2108:12 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/21 11:44 05/20/2108:12 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/21 11:44 05/20/2108:12 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/21 11:44 05/20/2108:12 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/21 11:44 05/20/2108:12 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/21 11:44 05/20/2108:12 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/21 11:44 05/20/2108:12 7440-22-4 Vanadium 7.9 ug/L 5.0 3.9 1 05/19/21 11:44 05/20/2108:12 7440-62-2 Zinc 10.6 ug/L 10.0 9.5 1 05/19/21 11:44 05/20/2108:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.058J ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:43 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 05:36 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 05:36 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 05:36 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 05:36 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 05:36 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 05:36 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 05:36 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 05:36 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 05:36 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 05:36 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 05:36 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 05:36 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 05:36 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 05:36 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 05:36 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 05:36 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 05:36 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 05:36 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 05:36 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 05:36 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 05:36 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 05:36 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 05:36 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 05:36 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW4 Lab ID: 92536878004 Collected: 05/04/21 09:25 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.1 ug/L 1.0 0.38 1 05/07/21 05:36 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 05:36 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 05:36 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 05:36 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 05:36 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 05:36 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 05:36 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 05:36 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 05:36 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 05:36 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 05:36 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 05:36 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 05:36 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 05:36 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 05:36 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 05:36 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 05:36 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 05:36 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 05:36 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 05:36 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 05:36 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 05:36 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 05:36 1330-20-7 96 % 70-130 1 05/07/21 05:36 460-00-4 102 % 70-130 1 05/07/21 05:36 17060-07-0 100 % 70-130 1 05/07/21 05:36 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2116:52 123-91-1 105 % 70-130 1 05/05/2116:52 17060-07-0 90 % 66-133 1 05/05/21 16:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW5 Lab ID: 92536878005 Collected: 05/04/21 07:02 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/21 11:44 05/20/2108:15 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/21 11:44 05/20/2108:15 7440-38-2 Barium 121 ug/L 5.0 3.5 1 05/19/21 11:44 05/20/2108:15 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/21 11:44 05/20/2108:15 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/21 11:44 05/20/2108:15 7440-43-9 Chromium 8.0 ug/L 5.0 3.7 1 05/19/21 11:44 05/20/2108:15 7440-47-3 Cobalt 8.7 ug/L 5.0 3.6 1 05/19/21 11:44 05/20/2108:15 7440-48-4 Copper 6.2 ug/L 5.0 4.3 1 05/19/21 11:44 05/20/2108:15 7440-50-8 Lead 10.4 ug/L 5.0 4.5 1 05/19/21 11:44 05/20/2108:15 7439-92-1 Nickel 5.6 ug/L 5.0 3.5 1 05/19/21 11:44 05/20/2108:15 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/21 11:44 05/20/2108:15 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/21 11:44 05/20/2108:15 7440-22-4 Vanadium 19.4 ug/L 5.0 3.9 1 05/19/21 11:44 05/20/2108:15 7440-62-2 Zinc 34.6 ug/L 10.0 9.5 1 05/19/21 11:44 05/20/2108:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.67J ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:48 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 05:17 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 05:17 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 05:17 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 05:17 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 05:17 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 05:17 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 05:17 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 05:17 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 05:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 05:17 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 05:17 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 05:17 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 05:17 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 05:17 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 05:17 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 05:17 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 05:17 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 05:17 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 05:17 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 05:17 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 05:17 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 05:17 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 05:17 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 05:17 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW5 Lab ID: 92536878005 Collected: 05/04/21 07:02 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 05:17 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 05:17 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 05:17 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 05:17 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 05:17 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 05:17 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 05:17 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 05:17 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 05:17 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 05:17 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 05:17 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 05:17 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 05:17 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 05:17 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 05:17 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 05:17 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 05:17 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 05:17 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 05:17 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 05:17 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 05:17 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 05:17 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 05:17 1330-20-7 97 % 70-130 1 05/07/21 05:17 460-00-4 101 % 70-130 1 05/07/21 05:17 17060-07-0 100 % 70-130 1 05/07/21 05:17 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2117:12 123-91-1 106 % 70-130 1 05/05/2117:12 17060-07-0 91 % 66-133 1 05/05/21 17:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW6S Lab ID: 92536878006 Collected: 05/04/21 09:35 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:19 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:19 7440-38-2 Barium 26.5 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:19 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:19 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:19 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:19 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:19 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:19 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:19 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:19 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:19 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:19 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/19/2111:44 05/20/2108:19 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2108:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:53 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 21:27 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 21:27 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 21:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 21:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 21:27 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 21:27 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 21:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 21:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 21:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 21:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 21:27 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 21:27 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 21:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 21:27 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 21:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 21:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 21:27 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 21:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 21:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 21:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 21:27 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 21:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 21:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 21:27 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. v2 v1 Page 18 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW6S Lab ID: 92536878006 Collected: 05/04/21 09:35 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 21:27 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 21:27 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 21:27 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 21:27 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 21:27 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 21:27 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 21:27 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 21:27 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 21:27 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 21:27 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 21:27 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 21:27 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 21:27 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 21:27 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 21:27 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 21:27 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 21:27 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 21:27 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 21:27 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 21:27 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 21:27 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 21:27 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 21:27 1330-20-7 96 % 70-130 1 05/07/21 21:27 460-00-4 104 % 70-130 1 05/07/21 21:27 17060-07-0 100 % 70-130 1 05/07/21 21:27 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2117:31 123-91-1 105 % 70-130 1 05/05/2117:31 17060-07-0 90 % 66-133 1 05/05/2117:31 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW6D Lab ID: 92536878007 Collected: 05/03/21 15:58 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:22 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:22 7440-38-2 Barium 13.4 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:22 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:22 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:22 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:22 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:22 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:22 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:22 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:22 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:22 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:22 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/19/2111:44 05/20/2108:22 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2108:22 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/24/2123:57 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 07:43 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 07:43 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 07:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 07:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 07:43 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 07:43 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 07:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 07:43 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 07:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 07:43 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 07:43 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 07:43 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 07:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 07:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 07:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 07:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 07:43 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 07:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 07:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 07:43 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 07:43 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 07:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 07:43 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 07:43 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-MW6D Lab ID: 92536878007 Collected: 05/03/21 15:58 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 07:43 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 07:43 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 07:43 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 07:43 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 07:43 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 07:43 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 07:43 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 07:43 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 07:43 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 07:43 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 07:43 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 07:43 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 07:43 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 07:43 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 07:43 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 07:43 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 07:43 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 07:43 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 07:43 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 07:43 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 07:43 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 07:43 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 07:43 1330-20-7 101 % 70-130 1 05/07/21 07:43 460-00-4 104 % 70-130 1 05/07/21 07:43 17060-07-0 101 % 70-130 1 05/07/21 07:43 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2117:51 123-91-1 107 % 70-130 1 05/05/2117:51 17060-07-0 91 % 66-133 1 05/05/2117:51 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-SW1 Lab ID: 92536878008 Collected: 05/04/21 09:15 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:25 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:25 7440-38-2 Barium 34.1 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:25 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:25 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:25 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:25 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:25 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:25 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:25 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:25 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:25 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:25 7440-22-4 Vanadium 5.4 ug/L 5.0 3.9 1 05/19/21 11:44 05/20/2108:25 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2108:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/25/2100:02 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 02:34 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 02:34 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 02:34 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 02:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 02:34 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 02:34 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 02:34 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 02:34 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 02:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 02:34 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 02:34 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 02:34 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 02:34 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 02:34 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 02:34 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 02:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 02:34 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 02:34 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 02:34 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 02:34 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 02:34 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 02:34 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 02:34 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 02:34 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-SW1 Lab ID: 92536878008 Collected: 05/04/21 09:15 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 02:34 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 02:34 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 02:34 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 02:34 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 02:34 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 02:34 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 02:34 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 02:34 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 02:34 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 02:34 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 02:34 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 02:34 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 02:34 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 02:34 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 02:34 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 02:34 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 02:34 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 02:34 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 02:34 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 02:34 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 02:34 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 02:34 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 02:34 1330-20-7 100 % 70-130 1 05/07/21 02:34 460-00-4 100 % 70-130 1 05/07/21 02:34 17060-07-0 102 % 70-130 1 05/07/21 02:34 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2118:10 123-91-1 108 % 70-130 1 05/05/2118:10 17060-07-0 91 % 66-133 1 05/05/21 18:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-SW2 Lab ID: 92536878009 Collected: 05/04/21 08:55 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:28 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:28 7440-38-2 Barium 38.6 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:28 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:28 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:28 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:28 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:28 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:28 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:28 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:28 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:28 7440-22-4 Vanadium 6.4 ug/L 5.0 3.9 1 05/19/21 11:44 05/20/2108:28 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2108:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/25/2100:07 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 02:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 02:52 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 02:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 02:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 02:52 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 02:52 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 02:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 02:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 02:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 02:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 02:52 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 02:52 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 02:52 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 02:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 02:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 02:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 02:52 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 02:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 02:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 02:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 02:52 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 02:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 02:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 02:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-SW2 Lab ID: 92536878009 Collected: 05/04/21 08:55 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 02:52 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 02:52 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 02:52 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 02:52 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 02:52 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 02:52 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 02:52 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 02:52 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 02:52 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 02:52 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 02:52 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 02:52 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 02:52 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 02:52 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 02:52 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 02:52 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 02:52 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 02:52 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 02:52 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 02:52 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 02:52 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 02:52 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 02:52 1330-20-7 98 % 70-130 1 05/07/21 02:52 460-00-4 101 % 70-130 1 05/07/21 02:52 17060-07-0 102 % 70-130 1 05/07/21 02:52 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2118:30 123-91-1 104 % 70-130 1 05/05/2118:30 17060-07-0 89 % 66-133 1 05/05/21 18:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-SW3 Lab ID: 92536878010 Collected: 05/04/21 08:47 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:38 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:38 7440-38-2 Barium 36.1 ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:38 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:38 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:38 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:38 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:38 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:38 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:38 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:38 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:38 7440-22-4 Vanadium 5.7 ug/L 5.0 3.9 1 05/19/21 11:44 05/20/2108:38 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2112:55 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/25/2100:11 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/07/21 03:28 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/07/21 03:28 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/07/21 03:28 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/07/21 03:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/07/21 03:28 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/07/21 03:28 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/07/21 03:28 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/07/21 03:28 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/07/21 03:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/07/21 03:28 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/07/21 03:28 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/07/21 03:28 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/07/21 03:28 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/07/21 03:28 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/07/21 03:28 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/07/21 03:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/07/21 03:28 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/07/21 03:28 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/07/21 03:28 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/07/21 03:28 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/07/21 03:28 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/07/21 03:28 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/07/21 03:28 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/07/21 03:28 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-SW3 Lab ID: 92536878010 Collected: 05/04/21 08:47 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/07/21 03:28 156-59-2 ND ug/L 1.0 0.40 1 05/07/21 03:28 156-60-5 ND ug/L 1.0 0.36 1 05/07/21 03:28 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 03:28 10061-01-5 ND ug/L 1.0 0.36 1 05/07/21 03:28 10061-02-6 ND ug/L 1.0 0.30 1 05/07/21 03:28 100-41-4 ND ug/L 5.0 0.48 1 05/07/21 03:28 591-78-6 ND ug/L 20.0 9.7 1 05/07/21 03:28 74-88-4 ND ug/L 5.0 2.0 1 05/07/21 03:28 75-09-2 ND ug/L 5.0 2.7 1 05/07/21 03:28 108-10-1 ND ug/L 1.0 0.29 1 05/07/21 03:28 100-42-5 ND ug/L 1.0 0.31 1 05/07/21 03:28 630-20-6 ND ug/L 1.0 0.22 1 05/07/21 03:28 79-34-5 ND ug/L 1.0 0.29 1 05/07/21 03:28 127-18-4 ND ug/L 1.0 0.48 1 05/07/21 03:28 108-88-3 ND ug/L 1.0 0.33 1 05/07/21 03:28 71-55-6 ND ug/L 1.0 0.32 1 05/07/21 03:28 79-00-5 ND ug/L 1.0 0.38 1 05/07/21 03:28 79-01-6 ND ug/L 1.0 0.30 1 05/07/21 03:28 75-69-4 ND ug/L 1.0 0.26 1 05/07/21 03:28 96-18-4 ND ug/L 2.0 1.3 1 05/07/21 03:28 108-05-4 ND ug/L 1.0 0.39 1 05/07/21 03:28 75-01-4 ND ug/L 1.0 0.34 1 05/07/21 03:28 1330-20-7 96 % 70-130 1 05/07/21 03:28 460-00-4 103 % 70-130 1 05/07/21 03:28 17060-07-0 100 % 70-130 1 05/07/21 03:28 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2118:49 123-91-1 106 % 70-130 1 05/05/2118:49 17060-07-0 90 % 66-133 1 05/05/21 18:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-Field Blank Lab ID: 92536878011 Collected: 05/04/21 09:40 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 05/19/2111:44 05/20/2108:41 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:41 7440-38-2 Barium ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:41 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 05/19/2111:44 05/20/2108:41 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 05/19/2111:44 05/20/2108:41 7440-43-9 Chromium ND ug/L 5.0 3.7 1 05/19/2111:44 05/20/2108:41 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 05/19/2111:44 05/20/2108:41 7440-48-4 Copper ND ug/L 5.0 4.3 1 05/19/2111:44 05/20/2108:41 7440-50-8 Lead ND ug/L 5.0 4.5 1 05/19/2111:44 05/20/2108:41 7439-92-1 Nickel ND ug/L 5.0 3.5 1 05/19/2111:44 05/20/2108:41 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/19/2111:44 05/20/2108:41 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/19/2111:44 05/20/2108:41 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 05/19/2111:44 05/20/2108:41 7440-62-2 Zinc ND ug/L 10.0 9.5 1 05/19/2111:44 05/20/2112:58 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 1.0 0.050 1 05/21/2115:17 05/25/2100:16 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 05/10/21 12:26 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 05/10/21 12:26 107-13-1 Benzene ND ug/L 1.0 0.34 1 05/10/21 12:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 05/10/21 12:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 05/10/21 12:26 75-27-4 Bromoform ND ug/L 1.0 0.34 1 05/10/21 12:26 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 05/10/21 12:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 05/10/21 12:26 78-93-3 Carbon disulfide ND ug/L 2.0 0.73 1 05/10/21 12:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 05/10/21 12:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 05/10/21 12:26 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 05/10/21 12:26 75-00-3 Chloroform ND ug/L 5.0 1.6 1 05/10/21 12:26 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 05/10/21 12:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 05/10/21 12:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 05/10/21 12:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 05/10/21 12:26 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 05/10/21 12:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 05/10/21 12:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 05/10/21 12:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 05/10/21 12:26 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 05/10/21 12:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 05/10/21 12:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 05/10/21 12:26 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. IK Page 28 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-Field Blank Lab ID: 92536878011 Collected: 05/04/21 09:40 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.38 1 05/10/21 12:26 156-59-2 ND ug/L 1.0 0.40 1 05/10/21 12:26 156-60-5 ND ug/L 1.0 0.36 1 05/10/21 12:26 78-87-5 ND ug/L 1.0 0.36 1 05/10/21 12:26 10061-01-5 ND ug/L 1.0 0.36 1 05/10/21 12:26 10061-02-6 ND ug/L 1.0 0.30 1 05/10/21 12:26 100-41-4 ND ug/L 5.0 0.48 1 05/10/21 12:26 591-78-6 ND ug/L 20.0 9.7 1 05/10/21 12:26 74-88-4 ND ug/L 5.0 2.0 1 05/10/21 12:26 75-09-2 ND ug/L 5.0 2.7 1 05/10/21 12:26 108-10-1 ND ug/L 1.0 0.29 1 05/10/21 12:26 100-42-5 ND ug/L 1.0 0.31 1 05/10/21 12:26 630-20-6 ND ug/L 1.0 0.22 1 05/10/21 12:26 79-34-5 ND ug/L 1.0 0.29 1 05/10/21 12:26 127-18-4 ND ug/L 1.0 0.48 1 05/10/21 12:26 108-88-3 ND ug/L 1.0 0.33 1 05/10/21 12:26 71-55-6 ND ug/L 1.0 0.32 1 05/10/21 12:26 79-00-5 ND ug/L 1.0 0.38 1 05/10/21 12:26 79-01-6 ND ug/L 1.0 0.30 1 05/10/21 12:26 75-69-4 ND ug/L 1.0 0.26 1 05/10/21 12:26 96-18-4 ND ug/L 2.0 1.3 1 05/10/21 12:26 108-05-4 ND ug/L 1.0 0.39 1 05/10/21 12:26 75-01-4 ND ug/L 1.0 0.34 1 05/10/21 12:26 1330-20-7 100 % 70-130 1 05/10/21 12:26 460-00-4 103 % 70-130 1 05/10/21 12:26 17060-07-0 97 % 70-130 1 05/10/21 12:26 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 0.86 1 05/05/2115:54 123-91-1 107 % 70-130 1 05/05/2115:54 17060-07-0 91 % 66-133 1 05/05/21 15:54 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-Trip Blank Lab ID: 92536878012 Collected: 05/04/21 09:40 Received: 05/05/21 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 05/27/2021 02:54 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 05/07/2101:58 67-64-1 ND ug/L 10.0 1.8 1 05/07/2101:58 107-13-1 ND ug/L 1.0 0.34 1 05/07/2101:58 71-43-2 ND ug/L 1.0 0.47 1 05/07/2101:58 74-97-5 ND ug/L 1.0 0.31 1 05/07/2101:58 75-27-4 ND ug/L 1.0 0.34 1 05/07/2101:58 75-25-2 ND ug/L 2.0 1.7 1 05/07/2101:58 74-83-9 ND ug/L 5.0 4.0 1 05/07/2101:58 78-93-3 ND ug/L 2.0 0.73 1 05/07/2101:58 75-15-0 ND ug/L 1.0 0.33 1 05/07/2101:58 56-23-5 ND ug/L 1.0 0.28 1 05/07/2101:58 108-90-7 ND ug/L 1.0 0.65 1 05/07/2101:58 75-00-3 ND ug/L 5.0 1.6 1 05/07/2101:58 67-66-3 ND ug/L 1.0 0.54 1 05/07/2101:58 74-87-3 ND ug/L 2.0 0.34 1 05/07/2101:58 96-12-8 ND ug/L 1.0 0.36 1 05/07/2101:58 124-48-1 ND ug/L 1.0 0.27 1 05/07/2101:58 106-93-4 ND ug/L 1.0 0.39 1 05/07/2101:58 74-95-3 ND ug/L 1.0 0.34 1 05/07/2101:58 95-50-1 ND ug/L 1.0 0.33 1 05/07/2101:58 106-46-7 ND ug/L 1.0 0.56 1 05/07/2101:58 110-57-6 ND ug/L 1.0 0.37 1 05/07/2101:58 75-34-3 ND ug/L 1.0 0.32 1 05/07/2101:58 107-06-2 ND ug/L 1.0 0.35 1 05/07/2101:58 75-35-4 ND ug/L 1.0 0.38 1 05/07/2101:58 156-59-2 ND ug/L 1.0 0.40 1 05/07/2101:58 156-60-5 ND ug/L 1.0 0.36 1 05/07/2101:58 78-87-5 ND ug/L 1.0 0.36 1 05/07/21 01:58 10061-01-5 ND ug/L 1.0 0.36 1 05/07/2101:58 10061-02-6 ND ug/L 1.0 0.30 1 05/07/2101:58 100-41-4 ND ug/L 5.0 0.48 1 05/07/2101:58 591-78-6 ND ug/L 20.0 9.7 1 05/07/2101:58 74-88-4 ND ug/L 5.0 2.0 1 05/07/2101:58 75-09-2 ND ug/L 5.0 2.7 1 05/07/2101:58 108-10-1 ND ug/L 1.0 0.29 1 05/07/2101:58 100-42-5 ND ug/L 1.0 0.31 1 05/07/2101:58 630-20-6 ND ug/L 1.0 0.22 1 05/07/2101:58 79-34-5 ND ug/L 1.0 0.29 1 05/07/2101:58 127-18-4 ND ug/L 1.0 0.48 1 05/07/2101:58 108-88-3 ND ug/L 1.0 0.33 1 05/07/2101:58 71-55-6 ND ug/L 1.0 0.32 1 05/07/2101:58 79-00-5 ND ug/L 1.0 0.38 1 05/07/2101:58 79-01-6 ND ug/L 1.0 0.30 1 05/07/2101:58 75-69-4 ND ug/L 1.0 0.26 1 05/07/2101:58 96-18-4 ND ug/L 2.0 1.3 1 05/07/2101:58 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Sample: 1201-Trip Blank Parameters Lab ID: 92536878012 Collected: Report Results Units Limit 05/04/21 09:40 MDL DF Received: 05/05/21 11:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 05/07/21 01:58 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 05/07/21 01:58 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 05/07/21 01:58 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 05/07/21 01:58 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 05/07/21 01:58 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 05/05/21 16:13 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 107 % 70-130 1 05/05/21 16:13 17060-07-0 Toluene-d8 (S) 91 % 66-133 1 05/05/21 16:13 2037-26-5 Date: 05/27/2021 02:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 621106 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92536878001, 92536878002, 92536878003, 92536878004, 92536878005, 92536878006, 92536878007, 92536878008,92536878009,92536878010,92536878011 METHOD BLANK: 3267866 Matrix: Water Associated Lab Samples: 92536878001, 92536878002, 92536878003, 92536878004, 92536878005, 92536878006, 92536878007, 92536878008,92536878009,92536878010,92536878011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 05/20/2107:24 Arsenic ug/L ND 10.0 4.7 05/20/2107:24 Barium ug/L ND 5.0 3.5 05/20/2107:24 Beryllium ug/L ND 1.0 0.70 05/20/2107:24 Cadmium ug/L ND 1.0 0.40 05/20/2107:24 Chromium ug/L ND 5.0 3.7 05/20/2107:24 Cobalt ug/L ND 5.0 3.6 05/20/2107:24 Copper ug/L ND 5.0 4.3 05/20/2107:24 Lead ug/L ND 5.0 4.5 05/20/2107:24 Nickel ug/L ND 5.0 3.5 05/20/2107:24 Selenium ug/L ND 10.0 4.7 05/20/2107:24 Silver ug/L ND 5.0 2.5 05/20/2107:24 Vanadium ug/L ND 5.0 3.9 05/20/2107:24 Zinc ug/L ND 10.0 9.5 05/20/2107:24 LABORATORY CONTROL SAMPLE: 3267867 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 423 85 80-120 Arsenic ug/L 500 404 81 80-120 Barium ug/L 500 427 85 80-120 Beryllium ug/L 500 425 85 80-120 Cadmium ug/L 500 424 85 80-120 Chromium ug/L 500 420 84 80-120 Cobalt ug/L 500 418 84 80-120 Copper ug/L 500 421 84 80-120 Lead ug/L 500 424 85 80-120 Nickel ug/L 500 424 85 80-120 Selenium ug/L 500 412 82 80-120 Silver ug/L 250 213 85 80-120 Vanadium ug/L 500 418 84 80-120 Zinc ug/L 500 439 88 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Burke Co - Kirksey Drive LF 92536878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3267868 3267869 MS MSD 92536074002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 478 491 95 98 75-125 3 20 Arsenic ug/L ND 500 500 474 487 95 97 75-125 3 20 Barium ug/L 216 500 500 699 714 97 100 75-125 2 20 Beryllium ug/L ND 500 500 488 497 98 99 75-125 2 20 Cadmium ug/L ND 500 500 486 497 97 99 75-125 2 20 Chromium ug/L 170 500 500 632 651 92 96 75-125 3 20 Cobalt ug/L ND 500 500 460 472 92 94 75-125 2 20 Copper ug/L ND 500 500 482 495 95 98 75-125 3 20 Lead ug/L ND 500 500 474 485 94 97 75-125 2 20 Nickel ug/L 7.9 500 500 474 486 93 96 75-125 2 20 Selenium ug/L ND 500 500 486 497 97 99 75-125 2 20 Silver ug/L ND 250 250 239 245 96 98 75-125 2 20 Vanadium ug/L 9.6 500 500 486 503 95 99 75-125 3 20 Zinc ug/L ND 500 500 505 516 99 101 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 622153 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92536878001, 92536878002, 92536878003, 92536878004, 92536878005, 92536878006, 92536878007, 92536878008,92536878009,92536878010,92536878011 METHOD BLANK: 3273536 Matrix: Water Associated Lab Samples: 92536878001, 92536878002, 92536878003, 92536878004, 92536878005, 92536878006, 92536878007, 92536878008,92536878009,92536878010,92536878011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 1.0 0.050 05/24/2122:51 LABORATORY CONTROL SAMPLE: 3273537 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 25 23.7 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3273538 3273539 MS MSD 92536878001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 25 25 24.7 24.4 99 98 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 618464 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92536878002, 92536878003, 92536878004, 92536878005, 92536878008, 92536878009, 92536878010, 92536878012 METHOD BLANK: 3254066 Matrix: Water Associated Lab Samples: 92536878002, 92536878003, 92536878004, 92536878005, 92536878008, 92536878009, 92536878010, 92536878012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/07/21 00:27 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/07/21 00:27 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/07/21 00:27 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/07/21 00:27 1,1-Dichloroethane ug/L ND 1.0 0.37 05/07/21 00:27 1,1-Dichloroethene ug/L ND 1.0 0.35 05/07/21 00:27 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/07/21 00:27 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/07/21 00:27 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/07/21 00:27 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/07/21 00:27 1,2-Dichloroethane ug/L ND 1.0 0.32 05/07/21 00:27 1,2-Dichloropropane ug/L ND 1.0 0.36 05/07/21 00:27 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/07/21 00:27 2-Butanone (MEK) ug/L ND 5.0 4.0 05/07/21 00:27 2-Hexanone ug/L ND 5.0 0.48 05/07/21 00:27 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/07/21 00:27 Acetone ug/L ND 25.0 5.1 05/07/21 00:27 Acrylonitrile ug/L ND 10.0 1.8 05/07/21 00:27 Benzene ug/L ND 1.0 0.34 05/07/21 00:27 Bromochloromethane ug/L ND 1.0 0.47 05/07/21 00:27 Bromodichloromethane ug/L ND 1.0 0.31 05/07/21 00:27 Bromoform ug/L ND 1.0 0.34 05/07/21 00:27 Bromomethane ug/L ND 2.0 1.7 05/07/21 00:27 Carbon disulfide ug/L ND 2.0 0.73 05/07/21 00:27 Carbon tetrachloride ug/L ND 1.0 0.33 05/07/21 00:27 Chlorobenzene ug/L ND 1.0 0.28 05/07/21 00:27 Chloroethane ug/L ND 1.0 0.65 05/07/21 00:27 Chloroform ug/L ND 5.0 1.6 05/07/21 00:27 Chloromethane ug/L ND 1.0 0.54 05/07/21 00:27 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/07/21 00:27 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/07/21 00:27 Dibromochloromethane ug/L ND 1.0 0.36 05/07/21 00:27 Dibromomethane ug/L ND 1.0 0.39 05/07/21 00:27 Ethylbenzene ug/L ND 1.0 0.30 05/07/21 00:27 lodomethane ug/L ND 20.0 9.7 05/07/21 00:27 Methylene Chloride ug/L ND 5.0 2.0 05/07/21 00:27 Styrene ug/L ND 1.0 0.29 05/07/21 00:27 Tetrachloroethene ug/L ND 1.0 0.29 05/07/21 00:27 Toluene ug/L ND 1.0 0.48 05/07/21 00:27 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 METHOD BLANK: 3254066 Matrix: Water Associated Lab Samples: 92536878002, 92536878003, 92536878004, 92536878005, 92536878008, 92536878009, 92536878010, 92536878012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/07/21 00:27 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/07/21 00:27 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 05/07/21 00:27 Trichloroethene ug/L ND 1.0 0.38 05/07/21 00:27 Trichlorofluoromethane ug/L ND 1.0 0.30 05/07/21 00:27 Vinyl acetate ug/L ND 2.0 1.3 05/07/21 00:27 Vinyl chloride ug/L ND 1.0 0.39 05/07/21 00:27 Xylene (Total) ug/L ND 1.0 0.34 05/07/21 00:27 1,2-Dichloroethane-d4 (S) % 99 70-130 05/07/21 00:27 4-Bromofluorobenzene (S) % 101 70-130 05/07/21 00:27 Toluene-d8 (S) % 100 70-130 05/07/21 00:27 LABORATORY CONTROL SAMPLE: 3254067 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 52.8 106 70-130 1,1,1-Trichloroethane ug/L 50 50.0 100 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.2 104 70-130 1,1,2-Trichloroethane ug/L 50 49.7 99 70-130 1,1-Dichloroethane ug/L 50 54.4 109 70-130 1,1-Dichloroethene ug/L 50 53.5 107 70-132 1,2,3-Trichloropropane ug/L 50 50.6 101 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.9 104 70-132 1,2-Dibromoethane (EDB) ug/L 50 52.1 104 70-130 1,2-Dichlorobenzene ug/L 50 46.4 93 70-130 1,2-Dichloroethane ug/L 50 48.5 97 70-130 1,2-Dichloropropane ug/L 50 51.2 102 70-130 1,4-Dichlorobenzene ug/L 50 48.2 96 70-130 2-Butanone (MEK) ug/L 100 110 110 70-133 2-Hexanone ug/L 100 109 109 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 107 107 70-130 Acetone ug/L 100 98.5 98 70-144 Acrylonitrile ug/L 250 275 110 70-130 Benzene ug/L 50 50.5 101 70-130 Bromochloromethane ug/L 50 50.1 100 70-130 Bromodichloromethane ug/L 50 52.6 105 70-130 Bromoform ug/L 50 53.2 106 70-131 Bromomethane ug/L 50 43.8 88 30-177 Carbon disulfide ug/L 50 52.5 105 70-133 Carbon tetrachloride ug/L 50 50.7 101 70-130 Chlorobenzene ug/L 50 50.7 101 70-130 Chloroethane ug/L 50 54.1 108 46-131 Chloroform ug/L 50 49.8 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 LABORATORY CONTROL SAMPLE: Parameter 3254067 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Chloromethane ug/L 50 52.2 104 49-130 cis-1,2-Dichloroethene ug/L 50 51.5 103 70-130 cis-1,3-Dichloropropene ug/L 50 53.0 106 70-130 Dibromochloromethane ug/L 50 53.7 107 70-130 Dibromomethane ug/L 50 49.2 98 70-130 Ethylbenzene ug/L 50 51.8 104 70-130 lodomethane ug/L 100 103 103 47-140 Methylene Chloride ug/L 50 51.4 103 68-130 Styrene ug/L 50 53.7 107 70-130 Tetrachloroethene ug/L 50 47.2 94 70-130 Toluene ug/L 50 49.6 99 70-130 trans-1,2-Dichloroethene ug/L 50 53.3 107 70-130 trans- 1,3-Dichloropropene ug/L 50 51.8 104 70-130 trans-1,4-Dichloro-2-butene ug/L 50 62.2 124 25-200 Trichloroethene ug/L 50 50.9 102 70-130 Trichlorofluoromethane ug/L 50 46.2 92 61-130 Vinyl acetate ug/L 100 116 116 70-140 Vinyl chloride ug/L 50 54.1 108 59-142 Xylene (Total) ug/L 150 151 101 70-130 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8(S) % 101 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3254068 MS 92536882003 Spike Parameter Units Result Conc. MSD Spike Conc. 3254069 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.9 24.8 115 124 70-135 8 30 1,1,1-Trichloroethane ug/L ND 20 20 22.6 24.8 113 124 70-148 9 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.4 23.6 112 118 70-131 5 30 1,1,2-Trichloroethane ug/L ND 20 20 22.1 24.2 111 121 70-136 9 30 1,1-Dichloroethane ug/L ND 20 20 24.3 26.7 122 133 70-147 9 30 1,1-Dichloroethene ug/L ND 20 20 25.3 26.7 126 133 70-158 5 30 1,2,3-Trichloropropane ug/L ND 20 20 22.0 22.9 110 114 67-137 4 30 1,2-Dibromo-3- ug/L ND 20 20 21.1 21.0 105 105 69-136 0 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 23.2 24.0 116 120 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 21.2 22.2 106 111 70-133 5 30 1,2-Dichloroethane ug/L ND 20 20 21.9 24.2 110 121 67-138 10 30 1,2-Dichloropropane ug/L ND 20 20 23.6 25.3 118 127 70-138 7 30 1,4-Dichlorobenzene ug/L 3.6 20 20 25.8 26.7 111 115 70-133 3 30 2-Butanone (MEK) ug/L ND 40 40 45.5 47.0 114 118 61-147 3 30 2-Hexanone ug/L ND 40 40 45.6 47.7 114 119 67-139 4 30 4-Methyl-2-pentanone ug/L ND 40 40 44.1 45.4 110 114 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 47.1 51.1 118 128 55-159 8 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 05/27/2021 02:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3254068 3254069 MS MSD 92536882003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acrylonitrile ug/L ND 100 100 115 127 115 127 68-140 10 30 Benzene ug/L 0.67J 20 20 23.4 25.1 114 122 67-150 7 30 Bromochloromethane ug/L ND 20 20 22.7 25.6 114 128 70-146 12 30 Bromodichloromethane ug/L ND 20 20 22.4 24.6 112 123 70-138 9 30 Bromoform ug/L ND 20 20 20.8 23.0 104 115 57-138 10 30 Bromomethane ug/L ND 20 20 21.6 23.8 108 119 10-200 10 30 v3 Carbon disulfide ug/L ND 20 20 23.5 25.6 117 128 70-152 8 30 Carbon tetrachloride ug/L ND 20 20 22.1 25.2 111 126 70-147 13 30 Chlorobenzene ug/L 0.76J 20 20 23.4 25.0 113 121 70-137 7 30 Chloroethane ug/L ND 20 20 27.3 28.0 136 140 51-166 3 30 Chloroform ug/L ND 20 20 22.1 26.4 111 132 70-144 18 30 Chloromethane ug/L ND 20 20 22.2 24.9 111 125 24-161 11 30 cis-1,2-Dichloroethene ug/L 10.1 20 20 33.0 36.2 115 131 67-148 9 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.2 25.1 116 126 70-142 8 30 Dibromochloromethane ug/L ND 20 20 23.0 24.5 115 123 68-138 6 30 Dibromomethane ug/L ND 20 20 21.1 22.1 106 111 70-134 5 30 Ethylbenzene ug/L ND 20 20 23.3 24.5 116 122 68-143 5 30 lodomethane ug/L ND 40 40 45.5 52.8 114 132 20-161 15 30 Methylene Chloride ug/L ND 20 20 23.2 25.5 116 127 64-148 9 30 Styrene ug/L ND 20 20 23.0 24.8 115 124 70-136 7 30 Tetrachloroethene ug/L ND 20 20 20.6 22.6 103 113 70-139 9 30 Toluene ug/L ND 20 20 22.1 24.0 110 120 47-157 8 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.6 25.9 118 129 70-149 9 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.3 24.2 112 121 70-138 8 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 23.1 24.4 116 122 31-145 5 30 v1 Trichloroethene ug/L ND 20 20 23.0 24.3 115 122 70-149 5 30 Trichlorofluoromethane ug/L ND 20 20 21.7 24.7 109 124 61-154 13 30 Vinyl acetate ug/L ND 40 40 49.1 52.3 123 131 48-156 6 30 Vinyl chloride ug/L ND 20 20 23.5 26.0 118 130 55-172 10 30 Xylene (Total) ug/L ND 60 60 67.8 73.0 113 122 66-145 7 30 1,2-Dichloroethane-d4 (S) % 101 101 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8 (S) % 100 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 618468 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92536878007 METHOD BLANK: 3254081 Associated Lab Samples: 92536878007 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/07/21 00:45 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/07/21 00:45 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/07/21 00:45 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/07/21 00:45 1,1-Dichloroethane ug/L ND 1.0 0.37 05/07/21 00:45 1,1-Dichloroethene ug/L ND 1.0 0.35 05/07/21 00:45 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/07/21 00:45 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/07/21 00:45 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/07/21 00:45 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/07/21 00:45 1,2-Dichloroethane ug/L ND 1.0 0.32 05/07/21 00:45 1,2-Dichloropropane ug/L ND 1.0 0.36 05/07/21 00:45 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/07/21 00:45 2-Butanone (MEK) ug/L ND 5.0 4.0 05/07/21 00:45 2-Hexanone ug/L ND 5.0 0.48 05/07/21 00:45 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/07/21 00:45 Acetone ug/L ND 25.0 5.1 05/07/21 00:45 Acrylonitrile ug/L ND 10.0 1.8 05/07/21 00:45 Benzene ug/L ND 1.0 0.34 05/07/21 00:45 Bromochloromethane ug/L ND 1.0 0.47 05/07/21 00:45 Bromodichloromethane ug/L ND 1.0 0.31 05/07/21 00:45 Bromoform ug/L ND 1.0 0.34 05/07/21 00:45 Bromomethane ug/L ND 2.0 1.7 05/07/21 00:45 Carbon disulfide ug/L ND 2.0 0.73 05/07/21 00:45 Carbon tetrachloride ug/L ND 1.0 0.33 05/07/21 00:45 Chlorobenzene ug/L ND 1.0 0.28 05/07/21 00:45 Chloroethane ug/L ND 1.0 0.65 05/07/21 00:45 Chloroform ug/L ND 5.0 1.6 05/07/21 00:45 Chloromethane ug/L ND 1.0 0.54 05/07/21 00:45 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/07/21 00:45 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/07/21 00:45 Dibromochloromethane ug/L ND 1.0 0.36 05/07/21 00:45 Dibromomethane ug/L ND 1.0 0.39 05/07/21 00:45 Ethylbenzene ug/L ND 1.0 0.30 05/07/21 00:45 lodomethane ug/L ND 20.0 9.7 05/07/21 00:45 Methylene Chloride ug/L ND 5.0 2.0 05/07/21 00:45 Styrene ug/L ND 1.0 0.29 05/07/21 00:45 Tetrachloroethene ug/L ND 1.0 0.29 05/07/21 00:45 Toluene ug/L ND 1.0 0.48 05/07/21 00:45 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/07/21 00:45 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 METHOD BLANK: 3254081 Associated Lab Samples: 92536878007 Parameter Units Matrix: Blank Result Water Reporting Limit MDL trans- 1,3-Dichloropropene ug/L ND 1.0 trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 Analyzed 0.36 05/07/21 00:45 0.56 05/07/21 00:45 0.38 05/07/21 00:45 0.30 05/07/21 00:45 1.3 05/07/21 00:45 0.39 05/07/21 00:45 0.34 05/07/21 00:45 05/07/21 00:45 05/07/21 00:45 05/07/21 00:45 LABORATORY CONTROL SAMPLE: Parameter 3254082 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.0 106 70-130 1,1,1-Trichloroethane ug/L 50 49.2 98 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.2 100 70-130 1,1,2-Trichloroethane ug/L 50 49.7 99 70-130 1,1-Dichloroethane ug/L 50 52.2 104 70-130 1,1-Dichloroethene ug/L 50 52.6 105 70-132 1,2,3-Trichloropropane ug/L 50 51.3 103 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.3 103 70-132 1,2-Dibromoethane (EDB) ug/L 50 51.1 102 70-130 1,2-Dichlorobenzene ug/L 50 46.6 93 70-130 1,2-Dichloroethane ug/L 50 48.0 96 70-130 1,2-Dichloropropane ug/L 50 52.0 104 70-130 1,4-Dichlorobenzene ug/L 50 47.9 96 70-130 2-Butanone (MEK) ug/L 100 105 105 70-133 2-Hexanone ug/L 100 110 110 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 107 107 70-130 Acetone ug/L 100 97.6 98 70-144 Acrylonitrile ug/L 250 274 110 70-130 Benzene ug/L 50 49.4 99 70-130 Bromochloromethane ug/L 50 49.2 98 70-130 Bromodichloromethane ug/L 50 50.6 101 70-130 Bromoform ug/L 50 51.7 103 70-131 Bromomethane ug/L 50 45.6 91 30-177 Carbon disulfide ug/L 50 50.5 101 70-133 Carbon tetrachloride ug/L 50 49.6 99 70-130 Chlorobenzene ug/L 50 51.0 102 70-130 Chloroethane ug/L 50 48.9 98 46-131 Chloroform ug/L 50 51.3 103 70-130 Chloromethane ug/L 50 49.4 99 49-130 cis-1,2-Dichloroethene ug/L 50 50.5 101 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 LABORATORY CONTROL SAMPLE: Parameter 3254082 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 52.1 104 70-130 Dibromochloromethane ug/L 50 53.8 108 70-130 Dibromomethane ug/L 50 48.8 98 70-130 Ethylbenzene ug/L 50 50.8 102 70-130 lodomethane ug/L 100 99.0 99 47-140 Methylene Chloride ug/L 50 49.8 100 68-130 Styrene ug/L 50 53.6 107 70-130 Tetrachloroethene ug/L 50 48.6 97 70-130 Toluene ug/L 50 49.5 99 70-130 trans-1,2-Dichloroethene ug/L 50 50.6 101 70-130 trans- 1,3-Dichloropropene ug/L 50 50.3 101 70-130 trans-1,4-Dichloro-2-butene ug/L 50 61.8 124 25-200 Trichloroethene ug/L 50 48.6 97 70-130 Trichlorofluoromethane ug/L 50 44.4 89 61-130 Vinyl acetate ug/L 100 113 113 70-140 Vinyl chloride ug/L 50 51.3 103 59-142 Xylene (Total) ug/L 150 151 101 70-130 1,2-Dichloroethane-d4 (S) % 92 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 100 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3254083 MS 92536506002 Spike Parameter Units Result Conc. MSD Spike Conc. 3254084 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.2 21.8 116 109 70-135 6 30 1,1,1-Trichloroethane ug/L ND 20 20 23.6 22.8 118 114 70-148 4 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.5 21.1 113 106 70-131 6 30 1,1,2-Trichloroethane ug/L ND 20 20 22.0 22.2 110 111 70-136 1 30 1,1-Dichloroethane ug/L ND 20 20 25.2 24.5 126 122 70-147 3 30 1,1-Dichloroethene ug/L ND 20 20 25.4 24.5 127 123 70-158 4 30 1,2,3-Trichloropropane ug/L ND 20 20 21.4 20.5 107 102 67-137 4 30 1,2-Dibromo-3- ug/L ND 20 20 22.5 20.8 112 104 69-136 8 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.9 21.1 110 105 70-137 4 30 1,2-Dichlorobenzene ug/L ND 20 20 21.3 20.3 107 101 70-133 5 30 1,2-Dichloroethane ug/L ND 20 20 22.5 22.9 112 114 67-138 2 30 1,2-Dichloropropane ug/L ND 20 20 23.4 22.5 117 113 70-138 4 30 1,4-Dichlorobenzene ug/L ND 20 20 22.0 21.3 110 107 70-133 3 30 2-Butanone (MEK) ug/L ND 40 40 43.7 46.8 109 117 61-147 7 30 2-Hexanone ug/L ND 40 40 45.0 43.5 112 109 67-139 3 30 4-Methyl-2-pentanone ug/L ND 40 40 44.9 43.6 112 109 67-136 3 30 (MIBK) Acetone ug/L ND 40 40 41.3 43.4 103 108 55-159 5 30 Acrylonitrile ug/L ND 100 100 119 121 119 121 68-140 2 30 Benzene ug/L ND 20 20 23.3 22.3 116 111 67-150 4 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3254083 MS 92536506002 Spike Parameter Units Result Conc. MSD Spike Conc. 3254084 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 23.6 23.2 118 116 70-146 2 30 Bromodichloromethane ug/L ND 20 20 23.1 22.9 116 114 70-138 1 30 Bromoform ug/L ND 20 20 21.1 19.8 105 99 57-138 6 30 Bromomethane ug/L ND 20 20 24.8 23.8 124 119 10-200 4 30 v3 Carbon disulfide ug/L ND 20 20 24.3 24.6 121 123 70-152 1 30 Carbon tetrachloride ug/L ND 20 20 23.1 22.8 115 114 70-147 1 30 Chlorobenzene ug/L ND 20 20 22.9 21.7 114 109 70-137 5 30 Chloroethane ug/L ND 20 20 27.4 27.2 137 136 51-166 0 30 Chloroform ug/L ND 20 20 25.2 25.2 126 126 70-144 0 30 Chloromethane ug/L ND 20 20 24.3 22.3 121 112 24-161 8 30 cis-1,2-Dichloroethene ug/L ND 20 20 24.5 22.5 122 113 67-148 8 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.0 23.0 115 115 70-142 0 30 Dibromochloromethane ug/L ND 20 20 23.0 21.5 115 108 68-138 6 30 Dibromomethane ug/L ND 20 20 21.5 21.4 107 107 70-134 0 30 Ethylbenzene ug/L ND 20 20 23.2 22.7 116 114 68-143 2 30 lodomethane ug/L ND 40 40 49.6 49.3 124 123 20-161 1 30 Methylene Chloride ug/L ND 20 20 23.5 23.3 117 117 64-148 1 30 Styrene ug/L ND 20 20 23.3 21.7 117 109 70-136 7 30 Tetrachloroethene ug/L ND 20 20 21.2 20.7 106 103 70-139 2 30 Toluene ug/L ND 20 20 22.5 22.6 113 113 47-157 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 24.4 24.5 122 123 70-149 0 30 trans-1,3-Dichloropropene ug/L ND 20 20 23.2 22.0 116 110 70-138 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 23.4 23.0 117 115 31-145 2 30 v1 Trichloroethene ug/L ND 20 20 23.0 22.9 115 114 70-149 1 30 Trichlorofluoromethane ug/L ND 20 20 22.5 21.5 112 107 61-154 4 30 Vinyl acetate ug/L ND 40 40 49.7 49.1 124 123 48-156 1 30 Vinyl chloride ug/L ND 20 20 25.2 24.3 126 121 55-172 4 30 Xylene (Total) ug/L ND 60 60 69.0 65.8 115 110 66-145 5 30 1,2-Dichloroethane-d4 (S) % 98 106 70-130 4-Bromofluorobenzene (S) % 95 98 70-130 Toluene-d8 (S) % 99 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 618941 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92536878006 METHOD BLANK: 3256612 Associated Lab Samples: 92536878006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/07/21 15:06 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/07/21 15:06 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/07/21 15:06 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/07/21 15:06 1,1-Dichloroethane ug/L ND 1.0 0.37 05/07/21 15:06 1,1-Dichloroethene ug/L ND 1.0 0.35 05/07/21 15:06 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/07/21 15:06 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/07/21 15:06 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/07/21 15:06 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/07/21 15:06 1,2-Dichloroethane ug/L ND 1.0 0.32 05/07/21 15:06 1,2-Dichloropropane ug/L ND 1.0 0.36 05/07/21 15:06 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/07/21 15:06 2-Butanone (MEK) ug/L ND 5.0 4.0 05/07/21 15:06 2-Hexanone ug/L ND 5.0 0.48 05/07/21 15:06 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/07/21 15:06 Acetone ug/L ND 25.0 5.1 05/07/21 15:06 Acrylonitrile ug/L ND 10.0 1.8 05/07/21 15:06 Benzene ug/L ND 1.0 0.34 05/07/21 15:06 Bromochloromethane ug/L ND 1.0 0.47 05/07/21 15:06 Bromodichloromethane ug/L ND 1.0 0.31 05/07/21 15:06 Bromoform ug/L ND 1.0 0.34 05/07/21 15:06 Bromomethane ug/L ND 2.0 1.7 05/07/21 15:06 v2 Carbon disulfide ug/L ND 2.0 0.73 05/07/21 15:06 Carbon tetrachloride ug/L ND 1.0 0.33 05/07/21 15:06 Chlorobenzene ug/L ND 1.0 0.28 05/07/21 15:06 Chloroethane ug/L ND 1.0 0.65 05/07/21 15:06 Chloroform ug/L ND 5.0 1.6 05/07/21 15:06 Chloromethane ug/L ND 1.0 0.54 05/07/21 15:06 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/07/21 15:06 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/07/21 15:06 Dibromochloromethane ug/L ND 1.0 0.36 05/07/21 15:06 Dibromomethane ug/L ND 1.0 0.39 05/07/21 15:06 Ethylbenzene ug/L ND 1.0 0.30 05/07/21 15:06 lodomethane ug/L ND 20.0 9.7 05/07/21 15:06 Methylene Chloride ug/L ND 5.0 2.0 05/07/21 15:06 Styrene ug/L ND 1.0 0.29 05/07/21 15:06 Tetrachloroethene ug/L ND 1.0 0.29 05/07/21 15:06 Toluene ug/L ND 1.0 0.48 05/07/21 15:06 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/07/21 15:06 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 METHOD BLANK: 3256612 Associated Lab Samples: 92536878006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/07/21 15:06 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 05/07/21 15:06 v1 Trichloroethene ug/L ND 1.0 0.38 05/07/21 15:06 Trichlorofluoromethane ug/L ND 1.0 0.30 05/07/21 15:06 Vinyl acetate ug/L ND 2.0 1.3 05/07/21 15:06 Vinyl chloride ug/L ND 1.0 0.39 05/07/21 15:06 Xylene (Total) ug/L ND 1.0 0.34 05/07/21 15:06 1,2-Dichloroethane-d4 (S) % 102 70-130 05/07/21 15:06 4-Bromofluorobenzene (S) % 98 70-130 05/07/21 15:06 Toluene-d8 (S) % 100 70-130 05/07/21 15:06 LABORATORY CONTROL SAMPLE: Parameter 3256613 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.9 108 70-130 1,1,1-Trichloroethane ug/L 50 51.0 102 70-130 1,1,2,2-Tetrachloroethane ug/L 50 54.0 108 70-130 1,1,2-Trichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethane ug/L 50 54.2 108 70-130 1,1-Dichloroethene ug/L 50 53.4 107 70-132 1,2,3-Trichloropropane ug/L 50 53.3 107 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.3 105 70-132 1,2-Dibromoethane (EDB) ug/L 50 54.1 108 70-130 1,2-Dichlorobenzene ug/L 50 48.9 98 70-130 1,2-Dichloroethane ug/L 50 52.0 104 70-130 1,2-Dichloropropane ug/L 50 52.6 105 70-130 1,4-Dichlorobenzene ug/L 50 50.2 100 70-130 2-Butanone (MEK) ug/L 100 112 112 70-133 2-Hexanone ug/L 100 112 112 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 108 108 70-130 Acetone ug/L 100 106 106 70-144 Acrylonitrile ug/L 250 282 113 70-130 Benzene ug/L 50 50.9 102 70-130 Bromochloromethane ug/L 50 51.0 102 70-130 Bromodichloromethane ug/L 50 53.2 106 70-130 Bromoform ug/L 50 53.2 106 70-131 Bromomethane ug/L 50 30.7 61 30-177 v2 Carbon disulfide ug/L 50 51.5 103 70-133 Carbon tetrachloride ug/L 50 50.4 101 70-130 Chlorobenzene ug/L 50 52.9 106 70-130 Chloroethane ug/L 50 46.9 94 46-131 Chloroform ug/L 50 53.8 108 70-130 Chloromethane ug/L 50 45.9 92 49-130 cis-1,2-Dichloroethene ug/L 50 53.2 106 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 58 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 LABORATORY CONTROL SAMPLE: Parameter 3256613 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 54.4 109 70-130 Dibromochloromethane ug/L 50 55.2 110 70-130 Dibromomethane ug/L 50 50.3 101 70-130 Ethylbenzene ug/L 50 52.1 104 70-130 lodomethane ug/L 100 95.4 95 47-140 Methylene Chloride ug/L 50 50.8 102 68-130 Styrene ug/L 50 54.3 109 70-130 Tetrachloroethene ug/L 50 47.0 94 70-130 Toluene ug/L 50 50.7 101 70-130 trans-1,2-Dichloroethene ug/L 50 52.9 106 70-130 trans- 1,3-Dichloropropene ug/L 50 54.5 109 70-130 trans-1,4-Dichloro-2-butene ug/L 50 67.4 135 25-200 v1 Trichloroethene ug/L 50 50.3 101 70-130 Trichlorofluoromethane ug/L 50 44.3 89 61-130 Vinyl acetate ug/L 100 115 115 70-140 Vinyl chloride ug/L 50 51.2 102 59-142 Xylene (Total) ug/L 150 156 104 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8(S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3256614 MS 92537215016 Spike Parameter Units Result Conc. MSD Spike Conc. 3256615 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.9 21.8 104 109 70-135 4 30 1,1,1-Trichloroethane ug/L ND 20 20 23.6 22.5 118 113 70-148 5 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.7 21.6 109 108 70-131 1 30 1,1,2-Trichloroethane ug/L ND 20 20 21.1 21.2 106 106 70-136 1 30 1,1-Dichloroethane ug/L ND 20 20 26.1 26.3 130 131 70-147 1 30 1,1-Dichloroethene ug/L ND 20 20 26.8 25.8 134 129 70-158 4 30 1,2,3-Trichloropropane ug/L ND 20 20 21.6 21.4 108 107 67-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 19.3 18.5 97 93 69-136 4 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.2 21.0 106 105 70-137 1 30 1,2-Dichlorobenzene ug/L ND 20 20 19.7 19.7 98 99 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 23.9 23.1 120 116 67-138 3 30 1,2-Dichloropropane ug/L ND 20 20 23.5 22.4 118 112 70-138 5 30 1,4-Dichlorobenzene ug/L ND 20 20 20.7 20.4 104 102 70-133 2 30 2-Butanone (MEK) ug/L ND 40 40 49.6 48.5 124 121 61-147 2 30 2-Hexanone ug/L ND 40 40 43.5 43.4 109 108 67-139 0 30 4-Methyl-2-pentanone ug/L ND 40 40 44.4 44.5 111 111 67-136 0 30 (MIBK) Acetone ug/L ND 40 40 44.7 44.5 112 111 55-159 0 30 Acrylonitrile ug/L ND 100 100 125 125 125 125 68-140 0 30 Benzene ug/L ND 20 20 22.5 21.8 113 109 67-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3256614 MS 92537215016 Spike Parameter Units Result Conc. MSD Spike Conc. 3256615 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 20 20 25.1 23.6 125 118 70-146 6 30 Bromodichloromethane ug/L ND 20 20 22.1 22.3 110 112 70-138 1 30 Bromoform ug/L ND 20 20 19.7 19.1 99 95 57-138 3 30 Bromomethane ug/L ND 20 20 22.1 20.8 110 104 10-200 6 30 Carbon disulfide ug/L ND 20 20 26.1 25.5 130 128 70-152 2 30 Carbon tetrachloride ug/L ND 20 20 22.3 22.3 111 111 70-147 0 30 Chlorobenzene ug/L ND 20 20 21.8 21.6 109 108 70-137 1 30 Chloroethane ug/L ND 20 20 27.0 27.1 135 136 51-166 1 30 Chloroform ug/L ND 20 20 25.1 24.7 125 124 70-144 2 30 Chloromethane ug/L ND 20 20 23.2 22.6 116 113 24-161 3 30 cis-1,2-Dichloroethene ug/L ND 20 20 25.3 23.9 126 119 67-148 6 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.9 22.6 114 113 70-142 1 30 Dibromochloromethane ug/L ND 20 20 22.0 21.2 110 106 68-138 3 30 Dibromomethane ug/L ND 20 20 20.5 19.7 103 98 70-134 4 30 Ethylbenzene ug/L ND 20 20 22.4 22.1 112 110 68-143 1 30 lodomethane ug/L ND 40 40 48.4 46.3 121 116 20-161 4 30 Methylene Chloride ug/L ND 20 20 24.5 23.4 123 117 64-148 5 30 Styrene ug/L ND 20 20 21.8 21.8 109 109 70-136 0 30 Tetrachloroethene ug/L ND 20 20 20.0 18.9 100 95 70-139 5 30 Toluene ug/L ND 20 20 21.8 21.9 109 109 47-157 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 25.5 23.5 127 117 70-149 8 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.4 22.0 112 110 70-138 2 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 23.2 22.8 116 114 31-145 2 30 Trichloroethene ug/L ND 20 20 21.1 20.9 105 105 70-149 1 30 Trichlorofluoromethane ug/L ND 20 20 20.4 20.6 102 103 61-154 1 30 Vinyl acetate ug/L ND 40 40 51.4 49.7 128 124 48-156 3 30 Vinyl chloride ug/L ND 20 20 24.4 24.1 122 120 55-172 1 30 Xylene (Total) ug/L ND 60 60 65.9 63.7 110 106 66-145 3 30 1,2-Dichloroethane-d4 (S) % 108 112 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8 (S) % 102 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 618980 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92536878001, 92536878011 METHOD BLANK: 3256859 Associated Lab Samples: 92536878001, 92536878011 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 05/10/21 12:08 1,1,1-Trichloroethane ug/L ND 1.0 0.33 05/10/21 12:08 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/10/21 12:08 1,1,2-Trichloroethane ug/L ND 1.0 0.32 05/10/21 12:08 1,1-Dichloroethane ug/L ND 1.0 0.37 05/10/21 12:08 1,1-Dichloroethene ug/L ND 1.0 0.35 05/10/21 12:08 1,2,3-Trichloropropane ug/L ND 1.0 0.26 05/10/21 12:08 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 05/10/21 12:08 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 05/10/21 12:08 1,2-Dichlorobenzene ug/L ND 1.0 0.34 05/10/21 12:08 1,2-Dichloroethane ug/L ND 1.0 0.32 05/10/21 12:08 1,2-Dichloropropane ug/L ND 1.0 0.36 05/10/21 12:08 1,4-Dichlorobenzene ug/L ND 1.0 0.33 05/10/21 12:08 2-Butanone (MEK) ug/L ND 5.0 4.0 05/10/21 12:08 2-Hexanone ug/L ND 5.0 0.48 05/10/21 12:08 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 05/10/21 12:08 Acetone ug/L ND 25.0 5.1 05/10/21 12:08 Acrylonitrile ug/L ND 10.0 1.8 05/10/21 12:08 Benzene ug/L ND 1.0 0.34 05/10/21 12:08 Bromochloromethane ug/L ND 1.0 0.47 05/10/21 12:08 Bromodichloromethane ug/L ND 1.0 0.31 05/10/21 12:08 Bromoform ug/L ND 1.0 0.34 05/10/21 12:08 Bromomethane ug/L ND 2.0 1.7 05/10/21 12:08 Carbon disulfide ug/L ND 2.0 0.73 05/10/21 12:08 Carbon tetrachloride ug/L ND 1.0 0.33 05/10/21 12:08 Chlorobenzene ug/L ND 1.0 0.28 05/10/21 12:08 Chloroethane ug/L ND 1.0 0.65 05/10/21 12:08 Chloroform ug/L ND 5.0 1.6 05/10/21 12:08 Chloromethane ug/L ND 1.0 0.54 05/10/21 12:08 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 05/10/21 12:08 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 05/10/21 12:08 Dibromochloromethane ug/L ND 1.0 0.36 05/10/21 12:08 Dibromomethane ug/L ND 1.0 0.39 05/10/21 12:08 Ethylbenzene ug/L ND 1.0 0.30 05/10/21 12:08 lodomethane ug/L ND 20.0 9.7 05/10/21 12:08 Methylene Chloride ug/L ND 5.0 2.0 05/10/21 12:08 Styrene ug/L ND 1.0 0.29 05/10/21 12:08 Tetrachloroethene ug/L ND 1.0 0.29 05/10/21 12:08 Toluene ug/L ND 1.0 0.48 05/10/21 12:08 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 05/10/21 12:08 IK Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 METHOD BLANK: 3256859 Associated Lab Samples: 92536878001, 92536878011 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 05/10/21 12:08 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 05/10/21 12:08 Trichloroethene ug/L ND 1.0 0.38 05/10/21 12:08 Trichlorofluoromethane ug/L ND 1.0 0.30 05/10/21 12:08 Vinyl acetate ug/L ND 2.0 1.3 05/10/21 12:08 Vinyl chloride ug/L ND 1.0 0.39 05/10/21 12:08 Xylene (Total) ug/L ND 1.0 0.34 05/10/21 12:08 1,2-Dichloroethane-d4 (S) % 102 70-130 05/10/21 12:08 4-Bromofluorobenzene (S) % 93 70-130 05/10/21 12:08 Toluene-d8 (S) % 99 70-130 05/10/21 12:08 LABORATORY CONTROL SAMPLE: Parameter 3256860 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.9 102 70-130 1,1,1-Trichloroethane ug/L 50 49.8 100 70-130 1,1,2,2-Tetrachloroethane ug/L 50 51.4 103 70-130 1,1,2-Trichloroethane ug/L 50 51.1 102 70-130 1,1-Dichloroethane ug/L 50 51.6 103 70-130 1,1-Dichloroethene ug/L 50 51.2 102 70-132 1,2,3-Trichloropropane ug/L 50 50.5 101 70-130 1,2-Dibromo-3-chloropropane ug/L 50 55.8 112 70-132 1,2-Dibromoethane (EDB) ug/L 50 50.4 101 70-130 1,2-Dichlorobenzene ug/L 50 49.2 98 70-130 1,2-Dichloroethane ug/L 50 49.2 98 70-130 1,2-Dichloropropane ug/L 50 52.2 104 70-130 1,4-Dichlorobenzene ug/L 50 50.4 101 70-130 2-Butanone (MEK) ug/L 100 107 107 70-133 2-Hexanone ug/L 100 108 108 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 109 109 70-130 Acetone ug/L 100 118 118 70-144 Acrylonitrile ug/L 250 297 119 70-130 Benzene ug/L 50 51.5 103 70-130 Bromochloromethane ug/L 50 52.3 105 70-130 Bromodichloromethane ug/L 50 50.5 101 70-130 Bromoform ug/L 50 51.2 102 70-131 Bromomethane ug/L 50 46.1 92 30-177lK Carbon disulfide ug/L 50 54.9 110 70-133 Carbon tetrachloride ug/L 50 50.5 101 70-130 Chlorobenzene ug/L 50 50.1 100 70-130 Chloroethane ug/L 50 51.6 103 46-131 Chloroform ug/L 50 52.4 105 70-130 Chloromethane ug/L 50 48.8 98 49-130 cis-1,2-Dichloroethene ug/L 50 51.3 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 LABORATORY CONTROL SAMPLE: Parameter 3256860 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 53.7 107 70-130 Dibromochloromethane ug/L 50 50.8 102 70-130 Dibromomethane ug/L 50 51.1 102 70-130 Ethylbenzene ug/L 50 50.4 101 70-130 lodomethane ug/L 100 107 107 47-140 Methylene Chloride ug/L 50 49.8 100 68-130 Styrene ug/L 50 51.5 103 70-130 Tetrachloroethene ug/L 50 47.2 94 70-130 Toluene ug/L 50 51.0 102 70-130 trans-1,2-Dichloroethene ug/L 50 53.3 107 70-130 trans- 1,3-Dichloropropene ug/L 50 52.8 106 70-130 trans-1,4-Dichloro-2-butene ug/L 50 66.1 132 25-200 Trichloroethene ug/L 50 50.6 101 70-130 Trichlorofluoromethane ug/L 50 42.8 86 61-130 Vinyl acetate ug/L 100 118 118 70-140 Vinyl chloride ug/L 50 46.6 93 59-142 Xylene (Total) ug/L 150 151 101 70-130 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 103 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3256861 MS 92536878001 Spike Parameter Units Result Conc. MSD Spike Conc. 3256862 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 100 100 107 106 107 106 70-135 1 30 1,1,1-Trichloroethane ug/L ND 100 100 114 112 114 112 70-148 2 30 1,1,2,2-Tetrachloroethane ug/L ND 100 100 111 110 111 110 70-131 1 30 1,1,2-Trichloroethane ug/L ND 100 100 104 102 104 102 70-136 2 30 1,1-Dichloroethane ug/L ND 100 100 122 121 122 121 70-147 1 30 1,1-Dichloroethene ug/L ND 100 100 114 110 114 110 70-158 4 30 1,2,3-Trichloropropane ug/L ND 100 100 91.6 90.9 92 91 67-137 1 30 1,2-Dibromo-3- ug/L ND 100 100 110 108 110 108 69-136 1 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 100 100 104 105 104 105 70-137 1 30 1,2-Dichlorobenzene ug/L 1.7J 100 100 106 103 104 101 70-133 3 30 1,2-Dichloroethane ug/L ND 100 100 110 107 110 107 67-138 3 30 1,2-Dichloropropane ug/L ND 100 100 118 115 118 115 70-138 3 30 1,4-Dichlorobenzene ug/L 38.4 100 100 143 135 104 97 70-133 5 30 2-Butanone (MEK) ug/L 1190 200 200 1540 1510 174 157 61-147 2 30 M1 2-Hexanone ug/L 6AJ 200 200 218 216 106 105 67-139 1 30 4-Methyl-2-pentanone ug/L 616 200 200 800 782 92 83 67-136 2 30 (MIBK) Acetone ug/L 1160 200 200 1540 1520 191 179 55-159 2 30 M1 Acrylonitrile ug/L ND 500 500 680 677 136 135 68-140 1 30 Benzene ug/L 9.7 100 100 127 123 117 113 67-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3256861 MS 92536878001 Spike Parameter Units Result Conc. MSD Spike Conc. 3256862 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Bromochloromethane ug/L ND 100 100 121 117 121 117 70-146 3 30 Bromodichloromethane ug/L ND 100 100 106 104 106 104 70-138 2 30 Bromoform ug/L ND 100 100 99.1 97.7 99 98 57-138 1 30 Bromomethane ug/L ND 100 100 125 111 125 111 10-200 12 30 IK Carbon disulfide ug/L ND 100 100 112 106 112 106 70-152 5 30 Carbon tetrachloride ug/L ND 100 100 111 110 111 110 70-147 1 30 Chlorobenzene ug/L 22.1 100 100 131 128 109 106 70-137 2 30 Chloroethane ug/L ND 100 100 129 124 129 124 51-166 4 30 Chloroform ug/L ND 100 100 122 118 122 118 70-144 3 30 Chloromethane ug/L ND 100 100 116 114 116 114 24-161 2 30 cis-1,2-Dichloroethene ug/L ND 100 100 120 117 120 117 67-148 3 30 cis-1,3-Dichloropropene ug/L ND 100 100 83.1 81.2 83 81 70-142 2 30 Dibromochloromethane ug/L ND 100 100 105 105 105 105 68-138 0 30 Dibromomethane ug/L ND 100 100 108 106 108 106 70-134 2 30 Ethylbenzene ug/L 20.3 100 100 128 126 108 105 68-143 2 30 lodomethane ug/L ND 200 200 175 202 88 101 20-161 14 30 Methylene Chloride ug/L ND 100 100 90.6 86.9 91 87 64-148 4 30 Styrene ug/L ND 100 100 106 104 106 104 70-136 2 30 Tetrachloroethene ug/L ND 100 100 101 98.0 101 98 70-139 3 30 Toluene ug/L 6.8 100 100 111 108 104 101 47-157 3 30 trans-1,2-Dichloroethene ug/L ND 100 100 118 114 118 114 70-149 3 30 trans-1,3-Dichloropropene ug/L ND 100 100 81.5 79.1 81 79 70-138 3 30 trans-1,4-Dichloro-2-butene ug/L ND 100 100 74.2 77.3 74 77 31-145 4 30 Trichloroethene ug/L ND 100 100 111 107 111 107 70-149 4 30 Trichlorofluoromethane ug/L ND 100 100 103 98.5 103 99 61-154 4 30 Vinyl acetate ug/L ND 200 200 195 192 98 96 48-156 2 30 Vinyl chloride ug/L ND 100 100 118 114 118 114 55-172 3 30 Xylene (Total) ug/L 51.5 300 300 373 365 107 105 66-145 2 30 1,2-Dichloroethane-d4 (S) % 100 99 70-130 4-Bromofluorobenzene (S) % 103 103 70-130 Toluene-d8 (S) % 96 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 618360 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92536878004, 92536878005, 92536878006, 92536878007, 92536878008, 92536878009, 92536878010, 92536878011,92536878012 METHOD BLANK: 3253398 Matrix: Water Associated Lab Samples: 92536878004, 92536878005, 92536878006, 92536878007, 92536878008, 92536878009, 92536878010, 92536878011,92536878012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 05/05/21 11:01 1,2-Dichloroethane-d4 (S) % 107 70-130 05/05/21 11:01 Toluene-d8 (S) % 92 66-133 05/05/21 11:01 LABORATORY CONTROL SAMPLE: 3253399 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 19.9 99 70-130 1,2-Dichloroethane-d4 (S) % 105 70-130 Toluene-d8 (S) % 92 66-133 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3253400 3253401 MS MSD 92536572004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 2.1 20 20 22.0 22.0 100 100 64-141 0 30 1,2-Dichloroethane-d4 (S) % 109 107 70-130 30 Toluene-d8 (S) % 92 91 66-133 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 QC Batch: 618462 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92536878001, 92536878002, 92536878003 METHOD BLANK: 3254032 Matrix: Water Associated Lab Samples: 92536878001, 92536878002, 92536878003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 05/05/21 11:34 1,2-Dichloroethane-d4 (S) % 86 70-130 05/05/21 11:34 Toluene-d8 (S) % 108 66-133 05/05/21 11:34 LABORATORY CONTROL SAMPLE: 3254033 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.1 96 70-130 1,2-Dichloroethane-d4 (S) % 87 70-130 Toluene-d8(S) % 110 66-133 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3254040 3254041 MS MSD 92536882001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 20.2 20.6 101 103 64-141 2 30 1,2-Dichloroethane-d4 (S) % 94 94 70-130 30 Toluene-d8 (S) % 110 111 66-133 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 58 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Burke Co - Kirksey Drive LF 92536878 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92536878001 1201-MW2 EPA 3010A 621106 EPA6010D 621542 92536878002 1201-MW3S EPA 3010A 621106 EPA6010D 621542 92536878003 1201-MW3D EPA 3010A 621106 EPA6010D 621542 92536878004 1201-MW4 EPA 3010A 621106 EPA6010D 621542 92536878005 1201-MW5 EPA 3010A 621106 EPA6010D 621542 92536878006 1201-MW6S EPA 3010A 621106 EPA6010D 621542 92536878007 1201-MW6D EPA 3010A 621106 EPA6010D 621542 92536878008 1201-SW1 EPA 3010A 621106 EPA6010D 621542 92536878009 1201-SW2 EPA 3010A 621106 EPA6010D 621542 92536878010 1201-SW3 EPA 3010A 621106 EPA6010D 621542 92536878011 1201-Field Blank EPA 3010A 621106 EPA6010D 621542 92536878001 1201-MW2 EPA 3010A 622153 EPA 6020B 622203 92536878002 1201-MW3S EPA 3010A 622153 EPA 6020B 622203 92536878003 1201-MW3D EPA 3010A 622153 EPA 6020B 622203 92536878004 1201-MW4 EPA 3010A 622153 EPA 6020B 622203 92536878005 1201-MW5 EPA 3010A 622153 EPA 6020B 622203 92536878006 1201-MW6S EPA 3010A 622153 EPA 6020B 622203 92536878007 1201-MW6D EPA 3010A 622153 EPA 6020B 622203 92536878008 1201-SW1 EPA 3010A 622153 EPA 6020B 622203 92536878009 1201-SW2 EPA 3010A 622153 EPA 6020B 622203 92536878010 1201-SW3 EPA 3010A 622153 EPA 6020B 622203 92536878011 1201-Field Blank EPA 3010A 622153 EPA 6020B 622203 92536878001 1201-MW2 EPA 8260D 618980 92536878002 1201-MW3S EPA 8260D 618464 92536878003 1201-MW3D EPA 8260D 618464 92536878004 1201-MW4 EPA 8260D 618464 92536878005 1201-MW5 EPA 8260D 618464 92536878006 1201-MW6S EPA 8260D 618941 92536878007 1201-MW6D EPA 8260D 618468 92536878008 1201-SW1 EPA 8260D 618464 92536878009 1201-SW2 EPA 8260D 618464 92536878010 1201-SW3 EPA 8260D 618464 92536878011 1201-Field Blank EPA 8260D 618980 92536878012 1201-Trip Blank EPA 8260D 618464 92536878001 1201-MW2 EPA 8260D Mod. 618462 92536878002 1201-MW3S EPA 8260D Mod. 618462 92536878003 1201-MW3D EPA 8260D Mod. 618462 92536878004 1201-MW4 EPA 8260D Mod. 618360 92536878005 1201-MW5 EPA 8260D Mod. 618360 92536878006 1201-MW6S EPA 8260D Mod. 618360 92536878007 1201-MW6D EPA 8260D Mod. 618360 92536878008 1201-SW1 EPA 8260D Mod. 618360 92536878009 1201-SW2 EPA 8260D Mod. 618360 92536878010 1201-SW3 EPA 8260D Mod. 618360 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/27/2021 02:54 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co - Kirksey Drive LF Pace Project No.: 92536878 Lab ID 92536878011 92536878012 Sample ID 1201-Field Blank 1201-Trip Blank Date: 05/27/2021 02:54 PM QC Batch Method QC Batch EPA 8260D Mod. 618360 EPA 8260D Mod. 618360 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 55 of 58 Document Name: Document Revised: October 28, 2020 r ceAf]c7ly ical Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: ;' F-CAR-05-033•Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh []Mechanicsville[]Atlanta[]Kernersviile❑ Sample Condition Client Name; Oof O25368 t o Upon Receipt-- project #W : ❑ Commercial ❑Pace Custody Seal Present? ❑Yes 1__4Na III III till 111 11 al 11 oil 8253587E o I5 L r !� Date/Initials Person Examining Contents: ✓ Packing Material: []Bubble Wrap S8ubble Bags ❑None ❑ Other Biological Tissue Frozen? Therm meter; y 1 CT © ]Net ❑8tue ❑None []Yes ❑Noq/A Gun ID: Type of Ice: Correction Factor; Cooler Temp: Add/Subtract VQ O.0°C Temp should be above freezing to VC [Sarnples out of temp criteria. Samples an ice, cooling process Cooler Temp Corrected (°C). 1 hasoegun USDA Regulated Sail (T54V/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign sourc 'nternationally, r--i.._-tea _ inrluriinv Hawaii and Puerto Ricol? I�Yes No [JOther: Seals Intact? ❑Yes u• Comments/Discrepancy: Chain of Custody Present? []NO ❑NIA I. Samples Arrived within Hold Time? �Pes ❑NO ❑N/A 2. Short Hold Time Analysis (02 hr,)? ❑Yes ­©Q ❑NIA 3. Rush Turn Around Time Requested? ❑Yes [-]N/A 4. 5ufficientVolume? s []No ❑N/A 5. Correct Containers Used? -Pace Containers Used? —134rs ❑No s ❑No ❑N/A ❑NIA 6. Containers Intact? es ONO ❑N/A 7. Dissolved analysis: Samples Field Filtered? [—]Yes ❑No _f5#4�A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: s ❑No ` f ❑N/A 9. Headspace in VOA Vials (>S•6mm)? ❑Yes "'Sau []N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? Yes ❑No s []No ❑N/A []N/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑NO Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: project Manager SCURF Review; Date/Time: Date: .t Manager SRF Review: Date: Page 56 of 58 �!�AceAnalyfical' Document Name: Sample Condition Upon Recei, Document No.: F-CAR-05.033-Rev.07 'Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Co(iform, TOC, Oil and Grease, DRO/8015 {water) DOC, LtHg "Bottom half of box is to list number of bottles Document Revised: October 28, 2020 t(SCUR) Page 2 of 2 Issuing Authority: Pace Carolinas Quality Office Project # WO# : 92536878 PM: NMG Due Date: 05/19/21 CLIENT: 92—Joyce Eng W - is a C rL J vEi d m U 2 °� m 0. C 0 a J o 4 m a i7 is C C a J E Ln a. m Z v i N I d A d v r-1 a m N S a v 0 N = ii J E a m N Y n m a z T c J E N o Z m Q Z N a J E a. En u N A y a = 0 Z a J E N a m v C r`o ro U in C C 'u a 2 a C E Q `5 W rr 0 Q v o. U T QJ E Q a; rf ri to Q z `U ci?i m a C E ¢ J of N m to N = a v 0 0 N E Q u rl r� to 4 N y a q iA N S E 4 J E N m t9 Q z -"' U z a E Q O N 0 m U Q = 2 ---' d t7 J E C1 S? G 2 rn N q o 7 E 4It 61 l7 } Q Q O J E Q1 'D } z C O 4m d > E 7 2 Q Y m 0 YS « a Q C } = Z ,y, , 'L i a N a \ } rp Z N io a N J E N a ? d n d E N a yi C T Os O N 2 2 me a J E o N d. m 1 aN a C 4 J E H O 4 Q C u E d ] z 7 w C. E Q E a Cr O 1 - - - - - AN- X" 1 6 7 8 X, N \\\I 9 l 10 k 11 I � 12 I INN pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: whenever there is a discrepancy arsectrng North Carolina compliance samples, a copy or tins rorm will De sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 57 of 58 > ; �aceAralytica! CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Required Client Information: Required Project Information: Invoice Information:E e : 1 Of 1 Company: LaBella Associates Report To- Van Burbach Attention. Lecia Jones Address: 2211 West Meadowview Rd Copy To: Miguel Vazquez Company Name: LaBella Associates Greensboro, NC 27407 Address, 1604 Ownby Lane, Richmond, VA 23220 Reguli tory Agency Email To: yburbach@labell-apC.com Purchase Order No, 2202300.00.02 Pace Quote Reference: Phone, (336) 323-0092 IFax Client Project ID: Burke Co. - Kirksey Drive LF Pace Project Manager: Nicole Gasiorowski Statt 1 Location Requested Due DatcrrAT' 10 Da Default Container Order Number Pace Profile #: 2186 Norl I Carolina Re uested Analysis Filtered Y!N � a Z_ CODE o COLLECTED = Preservatives raaTRix Dnnking water DW m U o Water WT Waste Watet YM 4 n z SAMPLE ID Ptoducl 50i11Saud P sL i m �_ START END u tl0 D rn m O '} OVI OL ¢ w W One Character per boa. w:P. wP a z a to x x (A-Z, 0-9 -} All Other OT V U # Sample Ids must be unique 1S x w J o O a a o a W a q_ = O rn t t Q¢¢ � uai DATE TIME DATE TIME w = 5 as 2 z z O Z Z v I.JS�U U 1 T2MIM443. WT G 1 -7 X x X. 2 1201-MW2 WT GR X X X 3 1201-MW3S WT G S Y. X X Q 4 1201-MW3D WT G 5 u L '• 7 X X X 6 1201-MW4 WT G Z�' �� "� X X X 6 1201-MW5 WT G ' X X X (�(� 7 1201-MW6S WT G 16 �' 1 X X X $ 1201-MWSD WT G??' L7 ? X X X XOCY 9 12D1-SW1 WT G 5 lb X� X X X L� 10 1201-SW2 WT G S I1 X X X L1� 11 1201-Sw3 WT G x X x 12 1201-Field Blank ,D +13 X X X O A 11201-Trip Blank 90D/ X X ADDITIONAL COMMENTS RELINQUISHED BY! AFFILIATION DATE TIME ACCEPTED BY 1 AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE m m PRI Par eeof AM L L s - � c� o 02 ru z T} c v 'm y o m F a N SI U PL p.4T S d: o' n N Ln tb O_ (n 00 Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Location Background Downgradient MW-1 MW-2 MW-3S MW-313 MW-4 MW-5 MW-6S MW-61D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 27-May-08 1085.56 1049.57 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 4-Nov-19 1089.96 1051.23 1016.22 1022.76 1036.09 1101.77 1054.90 1053.09 6-May-20 - 1051.23 1017.08 1022.76 1036.09 1101.77 1055.25 1053.38 9-Nov-20 - 1051.08 1016.18 1022.76 1036.31 1102.20 1055.16 1053.30 4-May-21 - 1051.62 1016.35 1022.76 1037.38 1105.08 1055.35 1053.67 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level All depths measured in feet below TOC. MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 damaged approx. June 2017 Burke County, Kirksey Drive Landfill Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 pg/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 pg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA 6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND IMAC = 1 pg/L (8/1/10) 4-Dec-18 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 3.0 5.0 NS 3 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC2L = 10 pg/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC2L = 2,000 pg/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC2L = 700 pg/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 NS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1,050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1,210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1,060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1,040 388 167 82.0 J 28.0 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 NS 1,470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 NS 1,240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 NS 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 NS 1,160 507 205 82.0 27.1 42.6 12.8 ND 6-May-19 EPA 6010D 2.5 5 NS 1,040 454 181 82.6 37.5 43.7 12.2 ND 5-Nov-19 EPA 6010D 2.5 5 NS 1,370 448 219 130 46.5 35.6 17.0 --- 6-May-20 EPA 6010D 3.5 5 NS 1,160 486 194 71.2 55.4 27.2 12.8 --- 9-Nov-20 EPA 6010D 3.5 5 NS 1,390 489 200 75.3 36.6 30.0 13.9 ND 4-May-21 EPA 6010D 3.5 5 NS 1,190 478 201 91.2 121 26.5 13.4 ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.10 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND IMAC = 4 pg/L (10/23/07) 4-Dec-18 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.2 1.0 NS ND ND ND ND 0.23 J ND ND --- 6-May-20 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 1.75 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC2L = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 NS 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 NS 2.0 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 0.4 1.0 NS ND 0.51 J ND ND ND ND ND --- 9-Nov-20 EPA 6010D 0.4 1.0 NS ND ND 0.62 J 0.58 J ND ND ND ND 4-May-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NC2L = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 NS ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 NS 2.5 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 1.0 5.0 NS ND ND ND 5.9 1.8 J ND ND --- 6-May-20 EPA 6O1OD 3.7 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O1OD 3.7 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 3.7 5.0 NS ND ND ND ND 8 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 pg/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 pg/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA 6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 114 11.0 ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS 102 20.2 ND ND ND 4.2 J ND ND IMAC = 1 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 107 14.4 ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.1 5.0 NS 119 12.3 ND 1.6 J 1.3 J ND ND --- 6-May-20 EPA 6010D 3.6 5.0 NS 106 16.8 ND ND ND ND ND --- 9-Nov-20 EPA 6010D 3.6 5.0 NS 122 14.2 ND ND ND ND ND ND 4-May-21 EPA 6010D 3.6 5.0 NS 95.4 13.7 ND ND 8.7 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND NS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 8.3 5.8 3.2 J ND 3.1 J ND ND ND 5-Nov-19 EPA 6010D 2.1 5.0 NS 3.3 J ND ND 4.6 J ND ND ND --- 6-May-20 EPA 6010D 4.3 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 4.3 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.3 5.0 NS ND ND ND ND 6.2 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC2L = 15 pg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 NS 4.9 J 3.2 J ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 1.6 5.0 NS 5.2 2.0 J ND ND ND ND ND --- 6-May-20 EPA 6O1OD 4.5 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O1OD 4.5 5.0 NS 9.3 ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 4.5 5.0 NS ND ND ND ND 10.4 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC21L = 100 pg/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND NS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 NS 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 NS 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 NS 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 14.5 4.4 J 25.7 3.0 J ND ND ND ND 5-Nov-19 EPA 6010D 0.9 5.0 NS 16.8 3.3 J 28.7 2.4 J 1.0 J ND ND --- 6-May-20 EPA 6010D 3.5 5.0 NS 14.4 5.4 24.1 ND ND ND ND --- 9-Nov-20 EPA 6010D 3.5 5.0 NS 21.7 4.9 J 27.1 ND ND ND ND ND 4-May-21 EPA 6010D 3.5 5.0 NS 14.4 ND 26.9 ND 5.6 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC2L = 20 pg/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6O1OD 4.7 10.0 NS 9.2 J ND ND ND 7.2 J ND ND --- 9-Nov-20 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 4.7 10.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC2L = 17.5 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC2L = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6O1OD 2.5 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 pg/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 pg/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND {4.8) J ND ND 4.0 {ND) J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 6020B 0.0 5.5 NS ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 6020B 0.03 0.1 NS ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 NS ND ND ND ND ND ND ND ND IMAC = 0.2 pg/L (10/1/10) 4-Dec-18 EPA 6020B 0.06 0.1 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6020B 0.06 0.1 NS ND ND ND ND 0.087 J ND ND ND 5-Nov-19 EPA 6020B 0.06 0.1 NS ND ND 0.061 J 0.060 J 0.16 ND ND --- 6-May-20 EPA 6020B 0.12 0.2 NS ND ND ND ND 0.20 ND ND --- Resample -> 16-Jul-20 EPA 6020B 0.12 0.2 NS NS NS NS NS ND NS NS --- 9-Nov-20 EPA 6020B 0.05 0.1 NS ND ND ND ND 0.11 ND ND ND 4-May-21 EPA 6020B 0.05 1 NS ND ND ND 0.058 J 0.67 J ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND NS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13.0 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 NS 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 NS 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 NS 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND IMAC = 0.3 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS ND 3.0 J ND 6.0 ND ND ND ND Resample --> 8-Feb-19 EPA 6010D 2.5 5.0 NS --- --- --- ND --- --- --- --- 6-May-19 EPA 6010D 2.5 5.0 NS 4.1 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 NS 5.3 1.8 J ND 10.0 3.8 J ND ND --- Resample --> 23-Jan-20 EPA 6010D 1.3 5.0 NS 5.1 --- --- 2.3 J --- --- --- --- 6-May-20 EPA 6010D 3.9 5.0 NS ND ND ND ND 7.2 ND ND --- Resample --> 16-Jul-20 EPA 6010D 3.9 5.0 NS NS NS NS NS ND NS NS --- 9-Nov-20 EPA 6010D 3.9 5.0 NS --- 9.5 ND ND ND ND ND ND Resample --> 27-Jan-21 EPA 6010D 3.9 5.0 NS --- ND --- --- --- --- --- --- 4-May-21 EPA 6010D 3.9 5.0 NS 7.3 ND ND 7.9 19.4 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NC2L = 1,050 pg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC2L = 1,000 pg/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 NS ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 NS ND 5.9 J ND ND 7.5 J ND 7.6 J ND 5-Nov-19 EPA 6O1OD 3.9 10.0 NS ND ND ND 15.4 7.5 J ND 7.0 J --- 6-May-20 EPA 6O1OD 9.5 10.0 NS ND ND ND ND 12.6 ND ND --- 9-Nov-20 EPA 6O1OD 9.5 10.0 NS ND 14.7 ND ND ND ND ND ND 4-May-21 EPA 6O1OD 9.5 10.0 NS ND ND ND 10.6 34.6 ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC2L = 700 pg/L (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC2L = 6,000 pg/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 NS ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA 8260 10.0 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 10.0 100 NS 484 ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 8.2 25 NS 299 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 NS 105 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 6.2 25 NS 255 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 6.2 25 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 25.6 125 NS 1160 M ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC2L = 1 pg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 NS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 NS 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 NS 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 NS 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 NS 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 NS 10.4 4.6 1.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 NS 8.3 3.4 1.3 ND ND ND ND --- 6-May-20 EPA 8260D 0.15 1.0 NS 9.6 3.7 1.4 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.15 1.0 NS 10.4 3.5 1.4 ND ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 NS 9.7 3.6 1.6 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 17 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC2L = 700 pWL (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 1.2 2 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.8 10 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.4 2 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 826OD 0.4 2 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.4 2 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 3.6 10 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA 8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA 8260 0.23 3.0 NS 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 NS 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 NS 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 826OB 0.23 1.0 NS 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA 826OD 0.53 1.0 NS 26.6 36.4 8.7 ND ND ND ND ND 5-Nov-19 EPA 826OD 0.23 1.0 NS 22.5 32.7 7.5 ND ND 0.28 J ND --- 6-May-20 EPA 826OD 0.23 1.0 NS 26.7 32.3 8.2 ND ND ND ND --- 9-Nov-20 EPA 826OD 0.23 1.0 NS 24.7 32.7 8.0 ND ND ND ND ND 4-May-21 EPA 826OD 0.28 1.0 NS 22.1 35.9 8.7 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 2,800 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC2L = 3,000 pg/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J NS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.54 10.0 NS ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.54 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.54 10.0 NS ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.54 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.52 1.0 NS ND 1.8 0.56 J ND ND ND ND ND 5-Nov-19 EPA 8260D 0.49 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.49 1.0 NS ND 1.6 ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.49 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 3.20 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC21L = 70 pg/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA 8260 0.14 5.0 NS ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA 8260 0.14 5.0 NS ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA 8260 0.14 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.14 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.58 1.0 NS ND ND ND ND ND 0.67 J ND ND 5-Nov-19 EPA 826OD 2.30 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 826OD 2.30 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 2.30 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 7.80 25.0 NS ND ND ND ND ND ND ND ND Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC21L = 2.6 pg/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC21L = 3 pg/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 NS 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA 8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.11 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.38 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.39 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 826OD 0.39 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.39 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 2.70 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC2L = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC2L = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J NS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 NS 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 NS 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 NS 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.30 1.0 NS 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA 826OD 0.49 1.0 NS 2.4 0.88 J ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.29 1.0 NS 2.2 0.6 J ND ND ND ND ND --- 6-May-20 EPA 826OD 0.29 1.0 NS 2.2 0.64 J ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.29 1.0 NS 2.2 0.62 J ND ND ND ND ND ND 4-May-21 EPA 826OD 1.70 5.0 NS 1.7 J 0.66 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC2L = 1.4 pg/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC2L = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 NS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 NS 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 NS 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 NS 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 8260B 0.33 1.0 NS 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 NS 47.3 14.6 4.8 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 NS 38.6 10.7 4.2 0.48 J ND ND ND --- 6-May-20 EPA 8260D 0.26 1.0 NS 39.0 10.7 4.1 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.26 1.0 NS 37.7 10.9 3.9 ND ND ND ND ND 4-May-21 EPA 8260D 0.33 1.0 NS 38.4 10.4 3.9 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC2L = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J NS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 NS 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 NS 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 NS ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 NS 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA 8260D 0.41 1.0 NS 0.68 J ND 6.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.27 1.0 NS 0.57 J 0.43 J 4.7 1.5 ND ND ND --- 6-May-20 EPA 8260D 0.27 1.0 NS 0.61 J ND 4.8 0.48 J ND ND ND --- 9-Nov-20 EPA 8260D 0.27 1.0 NS ND ND 5.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.80 5.0 NS ND ND 5.8 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 24 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC2L = 0.4 pg/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.24 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.67 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.34 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 826OD 0.34 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.34 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 1.60 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 25 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC2L = 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 2L = 350 pg/L (04/01/2013) 11-Jun-13 0.56 5.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.56 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.72 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 826OD 0.24 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 1.70 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B Mod. 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND NC 2L = 3 pg/L 6-May-19 EPA 8260D Mod. 5.8 10 NS 218 57.0 128 2.4 ND ND ND ND 5-Nov-19 EPA 8260D Mod. 1.2 2 3.0 236 36.4 269 2.7 ND ND ND --- 6-May-20 EPA 8260D Mod. 5.8 10 NS 213 33.3 111 ND ND ND ND --- 9-Nov-20 EPA 8260D Mod. 1.2 2 NS 260 49.6 114 ND ND ND ND ND 4-May-21 EPA 8260D Mod. 0.9 2 NS 187 41.5 110 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 27 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J NS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 NS 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 NS 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 NS ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 826OB 0.19 1.0 NS 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA 826OD 0.66 1.0 NS ND ND 18.7 1.2 ND ND ND ND 5-Nov-19 EPA 826OD 0.29 1.0 NS 0.33 J ND 14.6 J 8.0 ND ND ND --- 6-May-20 EPA 826OD 0.29 1.0 NS 0.41 J ND 16.4 2.6 ND ND ND --- 9-Nov-20 EPA 826OD 0.29 1.0 NS ND ND 21.2 3.5 ND ND ND ND 4-May-21 EPA 826OD 1.90 5.0 NS ND ND 21.3 2.1 ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC2L = 100 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J NS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.49 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.46 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.25 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.00 5.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NC2L = 0.51 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC2L = 0.6 pg/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA 8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 NS ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 NS ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 NS ND ND 0.87 J ND ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 NS ND ND 0.84 J ND ND ND ND --- 9-Nov-20 EPA 8260D 0.19 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 NS ND ND 0.63 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC2L = 550 pg/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC2L = 600 pg/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 NS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 NS 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 NS 10.5 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 NS 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.45 1.0 NS 24.1 ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.26 1.0 NS 12.1 ND ND ND ND ND ND --- 6-May-20 EPA 826OD 0.26 1.0 NS 17.0 ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.26 1.0 NS 10.9 ND ND ND ND ND ND ND 4-May-21 EPA 826OD 0.30 1.0 NS 20.3 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS = 280 pg/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.46 50.0 NS 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.46 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.89 5.0 NS 8.0 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.40 25.0 NS 6.4 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks lodomethane 11-Jun-13 0.32 10.0 ND ND ND NS ND 7.4 J ND ND ND NC2L = NE pg/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.32 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 3.10 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 12.50 20.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 826OD 12.50 20.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 12.50 20.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 48.60 100.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 4.6 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC21- = 5 pg/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.97 1.0 NS ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA 8260 0.97 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.97 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.97 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 NS ND ND 0.63 J ND ND ND ND ND 5-Nov-19 EPA 8260D 3.70 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 3.70 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 3.70 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 9.80 25.0 NS ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC2L = 4,200 pg/L (10/23/07) 28-Nov-07 NR 100 18.0 J ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC2L = 4,000 pg/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.96 100 NS 268 ND ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.96 5 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 3.20 5 NS 448 ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 3.30 5 NS 14.8 ND ND ND ND ND ND --- 6-May-20 EPA 826OD 3.30 5 NS 222 ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 3.30 5 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 826OD 19.80 25 NS 1190 M1 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.33 100 NS 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.33 5 NS 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.86 5 NS 311 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 4.50 5 NS 11.2 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 4.50 5 NS 187 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 4.50 5 NS 7.0 ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.70 5 NS 616.0 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC2L = 0.7 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND NS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA 8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 NS ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 NS ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 NS ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 NS ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 NS ND ND 11.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 NS ND ND 6.5 1.8 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 NS ND ND 8.1 0.69 J ND ND ND --- 9-Nov-20 EPA 8260D 0.16 1.0 NS ND ND 8.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.50 5.0 NS ND ND 8.7 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC2L = 600 pg/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 NS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND --- 2-May-16 EPA 8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 NS 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 NS 1.1 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 NS 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.26 1.0 NS 0.91 J ND ND ND ND ND ND ND 6-May-19 EPA 826OD 0.31 1.0 NS 4.8 ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.24 1.0 NS 1.1 ND ND ND ND ND ND --- 6-May-20 EPA 826OD 0.24 1.0 NS 2.5 ND ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.24 1.0 NS 0.90 J ND ND ND ND ND ND ND 4-May-21 EPA 826OD 0.48 1.0 NS 6.80 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC2L = 2.8 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC2L = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND NS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA 8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA 8260 0.47 1.0 NS ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA 8260 0.47 1.0 NS ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 NS ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 NS ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 NS ND ND 5.9 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 NS ND ND 4.8 0.72 J ND ND ND --- 6-May-20 EPA 8260D 0.22 1.0 NS ND ND 5.0 ND ND ND ND --- 9-Nov-20 EPA 8260D 0.22 1.0 NS ND ND 5.4 ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 6.2 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC21- = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC21- = 0.03 pg/L (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND NS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 NS ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.62 1.0 NS ND ND 1.1 ND ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 NS ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 NS ND ND 1.2 ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.4 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND 0.88 J ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 1.10 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC21- = 530 pg/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC21- = 500 pg/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 NS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA 8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA 8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 NS 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 NS 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 NS 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 826OB 0.66 1.0 NS 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA 826OD 1.50 2.0 NS 55.8 17.7 ND ND ND ND ND ND 5-Nov-19 EPA 826OD 0.63 1.0 NS 22.3 14.3 ND ND ND ND ND --- 6-May-20 EPA 826OD 0.63 1.0 NS 34.0 15.1 ND ND ND ND ND --- 9-Nov-20 EPA 826OD 0.63 1.0 NS 20.8 15.0 ND ND ND ND ND ND 4-May-21 EPA 826OD 0.34 1.0 NS 51.5 9.5 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 42 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND NS ND ND ND ND ND GWPS = 0.6 pg/L (10/23/07) 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.58 2.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.29 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.59 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the SWS for constituents with no listed NC2L standard (no longer used). IMAC = Interim Maximum Allowable Concentration. Bold values are greater than the NC2L, GWPS, or IMAC. NA = No data available. NR = Not reported. NI = Not installed. NE = Not established. NS = Not sampled. Dry = Insufficient water column to sample. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 42 of 42 Labella Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Well Depth [ft] 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25 °C) 11-Jun-13 233.1 1168.0 847 -- 56.9 14.2 62.8 74.1 [MS/CM] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 - 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 - 2185.0 920 875 99 25 97 114 14-May-18 1658.0 1117 923 131 22.2 118 59 4-Dec-18 1604.0 776 661 70 48 64.3 92.8 Resample--> 8-Feb-19 - -- -- 55.9 - -- -- 6-May-19 1923 916 792 59.6 23.3 50.6 85.6 Resample--> 23-Jul-19 - -- 1454 -- - -- -- 4-Nov-19 - 2225 831 853 92.1 18.3 59.3 90 6-May-20 - 2226 913 842 59 19.2 80.4 101.5 Resample--> 16-Jul-20 - - -- -- -- 16.6 -- -- 9-Nov-20 - 2044 803 752 72.8 15.8 53.5 88.5 Resample--> 27-Jan-21 - - 757 -- -- - -- -- 4-May-21 - 1506.0 593 632.0 67.0 43.9 45.2 74.2 pH 11-Jun-13 5.9 6.1 6.36 -- 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 - 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 - 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 - 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 - 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample--> 8-Feb-19 - - -- -- 5.64 - -- -- 6-May-19 - 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample--> 23-Jul-19 - - -- 6.00 -- - -- -- 4-Nov-19 - 5.64 5.94 6.15 5.43 5.49 5.28 5.54 6-May-20 - 6 6.35 6.59 5.66 5.47 5.8 6.44 Resample--> 16-Jul-20 - -- -- -- -- 5.55 -- -- 9-Nov-20 - 6.11 6.37 6.19 5.44 5.50 5.88 6.16 Resample--> 27-Jan-21 - - 6.65 -- -- - -- -- 4-May-21 - 5.8 5.96 6.0 6.5 7.2 6.3 5.76 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 1 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Temperature 11-Jun-13 17.0 17.4 15.2 -- 15.9 16.4 14 15.4 1° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 15.3 14.6 13.9 14 14 13.3 14.5 Resample--> 8-Feb-19 -- -- -- 15.2 -- -- -- 6-May-19 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample--> 23-Jul-19 -- -- 17.3 -- -- -- -- 4-Nov-19 - 15.1 13 16.4 14.7 15.3 16.4 16.4 6-May-20 16 16 16.7 14.6 16 13.3 14.2 Resample--> 16-Jul-20 -- -- -- -- 20.9 -- -- 9-Nov-20 17.0 17.4 16.6 15.9 16.2 17.5 15.1 Resample-> 27-Jan-21 -- 15.1 -- -- -- -- -- 4-May-21 16.9 14.9 16.4 15.6 16.1 13.8 15.6 Dissolved Oxygen 6-May-19 0.92 3.59 1.09 5.18 5.73 5.44 2.13 [mg/L] 23-Jul-19 -- -- 0.91 -- -- -- -- 4-Nov-19 1.63 1.85 4.39 3.99 4.36 3.55 2.89 6-May-20 5.06 4.71 5.14 6.7 1.85 5.74 4.33 Resample--> 16-Jul-20 -- -- -- -- 7.37 -- -- 9-Nov-20 1.65 1.29 1.21 3.66 9.03 6.00 1.19 Resample--> 27-Jan-21 -- 1.68 -- -- -- -- -- 4-May-21 1.4 1.97 1.2 7.1 10.3 9.07 0.98 Oxidation Reduction Potential 6-May-19 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mv] 23-Jul-19 -- -- 210.5 -- -- -- -- 4-Nov-19 33.3 85.4 180.3 199 146.4 208.3 -81.6 6-May-20 218.2 272.5 323 192.5 300.9 192 201.5 Resample--> 16-Jul-20 -- -- -- -- 282.3 -- -- 9-Nov-20 0.6 -24.7 1.4 199.9 202.3 230.1 63.1 Resample--> 27-Jan-21 -- -22.8 -- -- -- -- -- 4-May-21 40.4 60.8 194.8 98.3 164.7 127.5 109.6 Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 2 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Turbidity 11-Jun-13 27.4 4.50 3.65 -- 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 - 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 - 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 - 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 - 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample--> 8-Feb-19 - - -- -- 7.96 - -- -- 6-May-19 - 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample--> 23-Jul-19 - - -- 3.12 -- - -- -- 4-Nov-19 - 4.79 9 3.01 35.17 41.15 8.49 30.39 6-May-20 - 8.25 8.12 12.17 97.58 356.5 79.08 3.74 Resample--> 16-Jul-20 - - -- -- -- 13.23 -- -- 9-Nov-20 - 6.18 14.0 6.26 8.57 11.4 4.82 8.84 Resample--> 27-Jan-21 - - 8.5 -- -- - -- -- 4-May-21 - 8.7 8 4.0 30.1 91.6 20.4 5.25 Notes: °C= degrees Centigrade mg/L = milligrams per liter S.U.= Standard Units mV = millivolts pS = microSemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 3 of 3 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC2B = 10 pg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 ND ND 5.2 J ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.7 10.0 ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2,000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10.0 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.50 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.20 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.80 J NC2B = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.30 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.70 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 EPA 6010 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 EPA 6010 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 EPA 6010 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 EPA 6010 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 EPA 6010 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 EPA 6010 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 EPA 6010 2.5 100 38.1 J 38.0 J 301 2.50 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 EPA 6010 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 EPA 6O1OD 2.5 5 33.1 32.0 267 ND 6-May-19 EPA 6O1OD 2.5 5 26.4 26.2 239 ND 5-Nov-19 EPA 6O1OD 2.5 5 34.5 35.9 34.8 --- 6-May-20 EPA 6O1OD 3.5 5 31.9 28.7 32.3 --- 9-Nov-20 EPA 6O1OD 3.5 5 34.0 33.7 32.0 ND 4-May-21 EPA 6O1OD 3.5 5 34.1 38.6 36.1 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 pg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND Dry NA 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND NS ND 26-Jun-17 EPA 6010 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 0.5 1.0 ND ND ND ND 6-May-19 EPA 6O1OD 0.5 1.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 0.5 1.0 ND ND ND --- 6-May-20 EPA 6O1OD 0.4 1.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 0.4 1.0 ND ND ND ND 4-May-21 EPA 6O1OD 0.4 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.00 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC2B = 20 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.3 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.3 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 2.8 J ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 4.4 J ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.7 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.7 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.7 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC213 = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 6 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND 9.6 J NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 3.6 J ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 4.2 J ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.6 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.6 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.6 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC2B = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.4 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.0 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.3 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.3 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.3 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 4.1 J ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 ND N D 4.6 B 2.2 J NC213 = 25 pg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 EPA 6010 5.0 50.0 ND ND 10.4 J ND 19-May-15 EPA 6010 2.5 50.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 50.0 ND ND 5.1 J ND 2-May-16 EPA 6010 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 EPA 6010 2.5 50.0 ND ND INS ND 26-Jun-17 EPA 6010 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 EPA 6010 2.5 50.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND 5.9 ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND 6.3 ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 3.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC213 = 5 pg/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 ND ND ND ND 6-May-19 EPA 6O1OD 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND --- 6-May-20 EPA 6O1OD 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 4.7 10.0 ND ND ND ND 4-May-21 EPA 6O1OD 4.7 10.0 ND ND ND ND Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC213 = 0.06 pg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 2.5 5.0 ND ND ND --- 6-May-20 EPA 6O1OD 2.5 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 2.5 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Thallium 4-Dec-18 EPA 6O2OB 0.1 0.1 ND ND 0.077 J --- 6-May-19 EPA 6O2OB 0.1 0.1 ND ND 0.11 ND 5-Nov-19 EPA 6O2OB 0.1 0.1 ND ND ND --- 6-May-20 EPA 6O2OB 0.1 0.1 ND ND ND --- 9-Nov-20 EPA 6O2OB 0.1 0.1 ND ND ND ND 4-May-21 EPA 6O2OB 0.1 1.0 ND ND ND ND Vanadium 19-Nov-03 NR 40.0 62.00 56.00 60.00 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NC2B = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 25.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 25.0 ND ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 EPA 6010 2.5 25.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 1.3 5.0 1.4 J 1.5 J 1.5 J --- 6-May-20 EPA 6O1OD 3.9 5.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 3.9 5.0 ND ND ND ND 4-May-21 EPA 6O1OD 3.9 5.0 5.40 6.40 5.70 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND 10.3 ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND 18.0 ND 19-May-15 EPA 6010 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND N D 15.7 B 7.2 J 2-May-16 EPA 6010 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 EPA 6010 5.0 10.0 ND 8.0 J NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6O1OD 5.0 10.0 ND ND 7.4 J ND 6-May-19 EPA 6O1OD 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6O1OD 5.0 10.0 ND ND ND --- 6-May-20 EPA 6O1OD 9.5 10.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 9.5 10.0 ND ND ND ND 4-May-21 EPA 6O1OD 9.5 10.0 ND ND ND ND Beryllium 5-Nov-19 EPA 6O1OD 0.2 1.0 ND 0.24 J ND --- 6-May-20 EPA 6O1OD 0.7 1.0 ND ND ND --- 9-Nov-20 EPA 6O1OD 0.7 1.0 ND ND ND ND 4-May-21 EPA 6O1OD 0.7 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks ORGANICS Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 EPA 8260 10.0 100 ND ND 17.6 J ND 21-Oct-14 EPA 8260 10.0 100 ND ND ND ND 19-May-15 EPA 8260 10.0 100 ND ND Dry NA 7-Dec-15 EPA 8260 10.0 100 ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 ND ND NS ND 26-Jun-17 EPA 8260 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 EPA 8260 10.0 100 ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 ND ND ND ND 6-May-19 EPA 8260D 8.2 25 ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 ND ND ND --- 6-May-20 EPA 8260D 6.2 25 ND ND ND ND 9-Nov-20 EPA 8260D 6.2 25 ND ND ND ND 4-May-21 EPA 8260D 5.1 25 ND ND ND ND Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 pg/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.25 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.25 1.0 ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.15 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.15 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 EPA 8260 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 EPA 8260 0.29 10.0 ND ND 0.41 J ND 19-May-15 EPA 8260 0.29 10.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.29 10.0 ND ND ND ND 2-May-16 EPA 8260 0.29 10.0 ND ND ND ND 12-Dec-16 EPA 8260 0.29 10.0 ND ND NS ND 26-Jun-17 EPA 8260 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 EPA 8260 0.29 10.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.29 2.0 ND ND ND ND 6-May-19 EPA 826OD 0.95 2.0 ND ND 1.5 J ND 5-Nov-19 EPA 826OD 0.62 2.0 ND ND ND --- 6-May-20 EPA 826OD 0.62 2.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.62 2.0 ND ND ND ND 4-May-21 EPA 826OD 1.70 2.0 ND ND ND ND Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 EPA 8260 0.23 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.23 3.0 ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND ND NS ND 26-Jun-17 EPA 8260 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.23 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.53 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.23 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.23 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.23 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.28 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.11 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 ND ND 0.19 J ND 19-May-15 EPA 8260 0.11 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.11 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.38 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.39 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.39 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.39 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.54 1.0 ND ND ND ND 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.30 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.30 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.49 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.29 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.29 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.33 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.33 1.0 ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.33 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.58 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.26 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.26 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.26 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.33 1.0 ND ND ND ND 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NC2B = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.32 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.32 5.0 ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.32 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.41 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.27 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.27 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.27 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.37 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 J NC2B = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.19 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.19 5.0 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.27 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.19 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 ND ND ND ND 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B 1.90 2.0 ND ND 10.5 ND 6-May-19 EPA 8260D 1.20 2.0 ND ND 7.6 ND 5-Nov-19 EPA 8260D 1.20 2.0 ND ND ND --- 6-May-20 EPA 8260D 1.20 2.0 ND ND ND ND 9-Nov-20 EPA 8260D 1.20 2.0 ND ND ND ND 4-May-21 EPA 8260D 0.86 2.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC2B = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.46 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.16 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.29 1.0 ND ND ND ND Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.47 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.22 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.22 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS NS ND NC213 = 0.025 pg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.62 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.24 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.39 1.0 ND ND ND ND Hardness, Total (SM 2340B) 6-May-20 EPA 6010D 131.00 662.0 25,300 22,600 25,100 --- Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; SWSL for December 2006 - 2017, and MRL 2017-present.). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC213 = 15A NCAC 2B Surface Water Standards. Dry = Surface water point was considered to be dry and no sample collected. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. Bold values are greater than the NC213. NA = No data available. NR = Not reported. NS = Not sampled. NE = Not established. Burke County, Kirksey Drive Landfil Permit No. 12-01 Page 18 of 18 Labella Associates TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25 °C) 11-Jun-13 54.4 63.2 655 [MS/CM] 29-Oct-13 78.2 67.8 -- 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 -- 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 -- 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 4-Nov-19 78 92.4 80.9 6-May-20 77.0 76.8 76.8 9-Nov-20 68.4 69.6 74.5 4-May-21 61.1 54 79.8 pH 11-Jun-13 7.8 8.25 7.81 [S.U.] 29-Oct-13 7.2 6.85 -- 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 -- 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 6.60 6.98 7.92 4-Nov-19 6.60 6.78 6.63 6-May-20 7.5 7.43 7.43 9-Nov-20 6.32 7.09 7.18 4-May-21 6.93 6.62 6.76 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 1 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-Oct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 -- 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 4-Nov-19 10.0 7 10.6 10.7 6-May-20 14.4 17.2 17.2 9-Nov-20 16.2 17.1 17.1 4-May-21 16.2 16.2 16.5 Dissolved Oxygen 6-May-19 5.89 6.14 5.93 (mg/L) 4-Nov-19 7.23 6.56 7.27 6-May-20 5.2 4.89 4.89 9-Nov-20 7.86 7.82 6.65 4-May-21 9.35 8.79 7.62 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 (mV) 4-Nov-19 147.6 43.4 99.9 6-May-20 326.9 214 214 9-Nov-20 219.9 37.8 7.1 4-May-21 30.1 43.9 4.7 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 -- 5-May-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 -- 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 -- 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 4-Nov-19 11.6 10.4 10.0 6-May-20 15.6 15.6 15.6 9-Nov-20 7.5 9.13 9.24 4-May-21 47.4 77.90 47.40 Notes: °C= degrees Centigrade S.U.= Standard Units my = millivolts pS/cm = microSemens per centimeter NTU = Nephelometric Turbidity Units mg/L- milligrams per liter Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 2 of 2